Process for depositing hard coating in a nozzle orifice

DOEpatents

Flynn, Paul L.; Giammarise, Anthony W.

1991-01-01

The present invention is directed to a process for coating the interior surfaces of an orifice in a substrate that forms a slurry fuel injection nozzle. In a specific embodiment, the nozzle is part of a fuel injection system for metering a coal-water slurry into a large, medium-speed, multi-cylinder diesel engine. In order to retard erosion of the orifice, the substrate is placed in a chemical vapor deposition (CVD) reaction chamber. A reaction gas is passed into the chamber at a gas temperature below its reaction temperature and is directed through the orifice in the substrate. The gas reaction temperature is a temperature at and above which the reaction gas deposits as a coating, and the reaction gas is of a composition whereby improved resistance toerosion by flow of the particulates in the slurry fuel is imparted by the deposited coating. Only the portion of the substrate in proximity to the orifice to be coated is selectively heated to at least the gas reaction temperature for effecting coating of the orifice's interior surfaces by the vapor deposited coating formed from the reaction gas.

Microdevice having interior cavity with high aspect ratio surface features and associated methods of manufacture and use

DOEpatents

Morales, Alfredo M.

2002-01-01

A microdevice having interior cavity with high aspect ratio features and ultrasmooth surfaces, and associated method of manufacture and use is described. An LIGA-produced shaped bit is used to contour polish the surface of a sacrificial mandrel. The contoured sacrificial mandrel is subsequently coated with a structural material and the mandrel removed to produce microdevices having micrometer-sized surface features and sub-micrometer RMS surface roughness.

Methods and systems to thermally protect fuel nozzles in combustion systems

DOEpatents

Helmick, David Andrew; Johnson, Thomas Edward; York, William David; Lacy, Benjamin Paul

2013-12-17

A method of assembling a gas turbine engine is provided. The method includes coupling a combustor in flow communication with a compressor such that the combustor receives at least some of the air discharged by the compressor. A fuel nozzle assembly is coupled to the combustor and includes at least one fuel nozzle that includes a plurality of interior surfaces, wherein a thermal barrier coating is applied across at least one of the plurality of interior surfaces to facilitate shielding the interior surfaces from combustion gases.

Method for Waterproofing Ceramic Materials

NASA Technical Reports Server (NTRS)

Cagliostro, Domenick E. (Inventor); Hsu, Ming-Ta S. (Inventor)

1998-01-01

Hygroscopic ceramic materials which are difficult to waterproof with a silane, substituted silane or silazane waterproofing agent, such as an alumina containing fibrous, flexible and porous, fibrous ceramic insulation used on a reentry space vehicle, are rendered easy to waterproof if the interior porous surface of the ceramic is first coated with a thin coating of silica. The silica coating is achieved by coating the interior surface of the ceramic with a silica precursor converting the precursor to silica either in-situ or by oxidative pyrolysis and then applying the waterproofing agent to the silica coated ceramic. The silica precursor comprises almost any suitable silicon containing material such as a silane, silicone, siloxane, silazane and the like applied by solution, vapor deposition and the like. If the waterproofing is removed by e.g., burning, the silica remains and the ceramic is easily rewaterproofed. An alumina containing TABI insulation which absorbs more that five times its weight of water, absorbs less than 10 wt. % water after being waterproofed according to the method of the invention.

Apparatus and process for depositing hard coating in a nozzle orifice

DOEpatents

Flynn, P.L.; Giammarise, A.W.

1994-12-20

The present invention is directed to a process for coating the interior surfaces of an orifice in a substrate that forms a slurry fuel injection nozzle. In a specific embodiment, the nozzle is part of a fuel injection system for metering a coal-water slurry into a large, medium-speed, multi-cylinder diesel engine. In order to retard erosion of the orifice, the substrate is placed in a chemical vapor deposition (CVD) reaction chamber. A reaction gas is passed into the chamber at a gas temperature below its reaction temperature and is directed through the orifice in the substrate. The gas reaction temperature is a temperature at and above which the reaction gas deposits as a coating, and the reaction gas is of a composition whereby improved resistance to erosion by flow of the particulates in the slurry fuel is imparted by the deposited coating. Only the portion of the substrate in proximity to the orifice to be coated is selectively heated to at least the gas reaction temperature for effecting coating of the orifice's interior surfaces by the vapor deposited coating formed from the reaction gas. 2 figures.

Method of melting metals to reduce contamination from crucibles

DOEpatents

Banker, John G.; Wigginton, Hubert L.

1977-01-01

Contamination of metals from crucible materials during melting operations is reduced by coating the interior surface of the crucible with a ceramic non-reactive with the metallic charge and disposing a metal liner formed from a portion of the metallic charge within the coated crucible. The liner protects the ceramic coating during loading of the remainder of the charge and expands against the ceramic coating during heat-up to aid in sintering the coating.

Hot spot detection system for vanes or blades of a combustion turbine

DOEpatents

Twerdochlib, Michael

1999-01-01

This invention includes a detection system that can determine if a turbine component, such as a turbine vane or blade, has exceeded a critical temperature, such as a melting point, along any point along the entire surface of the vane or blade. This system can be employed in a conventional combustion turbine having a compressor, a combustor and a turbine section. Included within this system is a chemical coating disposed along the entire interior surface of a vane or blade and a closed loop cooling system that circulates a coolant through the interior of the vane or blade. If the temperature of the vane or blade exceeds a critical temperature, the chemical coating will be expelled from the vane or blade into the coolant. Since while traversing the closed loop cooling system the coolant passes through a detector, the presence of the chemical coating in the coolant will be sensed by the system. If the chemical coating is detected, this indicates that the vane or blade has exceeded a critical temperature.

Corrosion-Resistant Roof with Integrated Photovoltaic Power System

DTIC Science & Technology

2014-02-01

Figure 9. The panels are coated with a PVDF organic coating on the external facing surface and polyester enamel on the interior-facing surface. The high...1 no scribe No evidence of blistering, cracking , peeling or delaminating #2 scribe No evidence of blistering, cracking , peeling or delaminating...3 scribe No evidence of blistering, cracking , peeling or delaminating #4 scribe No evidence of blistering, cracking , peeling or delaminating

Black Molecular Adsorber Coatings for Spaceflight Applications

NASA Technical Reports Server (NTRS)

Abraham, Nithin Susan; Hasegawa, Mark Makoto; Straka, Sharon A.

2014-01-01

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

Black molecular adsorber coatings for spaceflight applications

NASA Astrophysics Data System (ADS)

Abraham, Nithin S.; Hasegawa, Mark M.; Straka, Sharon A.

2014-09-01

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

7 CFR 3201.71 - Interior paints and coatings.

Code of Federal Regulations, 2014 CFR

2014-01-01

... procurement applies are: (i) Interior latex and waterborne alkyd paints and coatings. (ii) Interior oil-based...) Interior latex and waterborne alkyd paints and coatings—20 percent. (2) Interior oil-based and solventborne... 7 Agriculture 15 2014-01-01 2014-01-01 false Interior paints and coatings. 3201.71 Section 3201.71...

7 CFR 3201.71 - Interior paints and coatings.

Code of Federal Regulations, 2013 CFR

2013-01-01

... procurement applies are: (i) Interior latex and waterborne alkyd paints and coatings. (ii) Interior oil-based...) Interior latex and waterborne alkyd paints and coatings—20 percent. (2) Interior oil-based and solventborne... 7 Agriculture 15 2013-01-01 2013-01-01 false Interior paints and coatings. 3201.71 Section 3201.71...

7 CFR 3201.71 - Interior paints and coatings.

Code of Federal Regulations, 2012 CFR

2012-01-01

... procurement applies are: (i) Interior latex and waterborne alkyd paints and coatings. (ii) Interior oil-based...) Interior latex and waterborne alkyd paints and coatings—20 percent. (2) Interior oil-based and solventborne... 7 Agriculture 15 2012-01-01 2012-01-01 false Interior paints and coatings. 3201.71 Section 3201.71...

76 FR 4534 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Adoption of Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-26

... interior panels, exterior siding, and tileboard. A typical flat wood coating facility applies stains and..., Volatile Organic Compounds from Specific Processes. This action affects facilities that apply stains and... these emission limits: lb VOC per gallon material (grams Surface coatings, inks, or adhesives applied to...

Hot spot detection system for vanes or blades of a combustion turbine

DOEpatents

Twerdochlib, M.

1999-02-02

This invention includes a detection system that can determine if a turbine component, such as a turbine vane or blade, has exceeded a critical temperature, such as a melting point, along any point along the entire surface of the vane or blade. This system can be employed in a conventional combustion turbine having a compressor, a combustor and a turbine section. Included within this system is a chemical coating disposed along the entire interior surface of a vane or blade and a closed loop cooling system that circulates a coolant through the interior of the vane or blade. If the temperature of the vane or blade exceeds a critical temperature, the chemical coating will be expelled from the vane or blade into the coolant. Since while traversing the closed loop cooling system the coolant passes through a detector, the presence of the chemical coating in the coolant will be sensed by the system. If the chemical coating is detected, this indicates that the vane or blade has exceeded a critical temperature. 5 figs.

Method for sealing remote leaks in an enclosure using an aerosol

DOEpatents

Modera, Mark P.; Carrie, Francois R.

1999-01-01

The invention is a method and device for sealing leaks remotely by means of injecting a previously prepared aerosol into the enclosure being sealed according to a particular sealing efficiency defined by the product of a penetration efficiency and a particle deposition efficiency. By using different limits in the relationship between penetration efficiency and flowrate, the same method according the invention can be used for coating the inside of an enclosure. Specifically the invention is a method and device for preparing, transporting, and depositing a solid phase aerosol to the interior surface of the enclosure relating particle size, particle carrier flow rate, and pressure differential, so that particles deposited there can bridge and substantially seal each leak, with out providing a substantial coating at inside surfaces of the enclosure other than the leak. The particle size and flow parameters can be adjusted to coat the interior of the enclosure (duct) without substantial plugging of the leaks depending on how the particle size and flowrate relationships are chosen.

Mechanical properties of anodized coatings over molten aluminum alloy

DOE PAGES

Grillet, Anne M.; Gorby, Allen D.; Trujillo, Steven M.; ...

2007-10-22

A method to measure interfacial mechanical properties at high temperatures and in a controlled atmosphere has been developed to study anodized aluminum surface coatings at temperatures where the interior aluminum alloy is molten. This is the first time that the coating strength has been studied under these conditions. In this study, we have investigated the effects of ambient atmosphere, temperature, and surface finish on coating strength for samples of aluminum alloy 7075. Surprisingly, the effective Young's modulus or strength of the coating when tested in air was twice as high as when samples were tested in an inert nitrogen ormore » argon atmosphere. Additionally, the effective Young's modulus of the anodized coating increased with temperature in an air atmosphere but was independent of temperature in an inert atmosphere. The effect of surface finish was also examined. Sandblasting the surface prior to anodization was found to increase the strength of the anodized coating with the greatest enhancement noted for a nitrogen atmosphere. Lastly, machining marks were not found to significantly affect the strength.« less

Self-assembled Monolayer Mediated Surface Environment Modification of Poly(vinylpyrrolidone)-Coated Hollow Au-Ag Nanoshells for Enhanced Loading of Hydrophobic Drug and Efficient Multimodal Therapy.

PubMed

Jang, Hongje; Kim, Dong-Eun; Min, Dal-Hee

2015-06-17

Hollow Au-Ag bimetallic nanoshell possessing hydrophobic interior space and hydrophilic exterior surface was prepared and its application as a chemo-thermo-gene therapeutic agent based on its high payload of multiple drugs having different water solubility was demonstrated. The multifunctional drug delivery system is based on the hydrophobic interior created by the self-assembled monolayer (SAM) of hexanethiol onto the inner surface of the hollow metallic nanoshells whereas the outer surface was mostly coated by hydrophilic biocompatible polymer. The nanoshells having surface environment modified by hexanethiol SAMs provided high capacity both for hydrophilic DNAzyme (Dz) to induce gene silencing and for hydrophobic SN38 (7-ethyl-10-hydroxycamptothecin), anticancer drug. The release of the loaded Dz and SN38 was independently triggered by an acidic environment and by photothermal temperature elevation upon irradiation, respectively. The chemo-thermo-gene multitherapy based on the present nanoshells having modified surface environment showed high efficacy in quantitative cell-based assays using Huh7 human liver cell containing hepatitis C viral NS3 gene replicon RNA.

Polysulfide Anchoring Mechanism Revealed by Atomic Layer Deposition of V2O5 and Sulfur-Filled Carbon Nanotubes for Lithium-Sulfur Batteries.

PubMed

Carter, Rachel; Oakes, Landon; Muralidharan, Nitin; Cohn, Adam P; Douglas, Anna; Pint, Cary L

2017-03-01

Despite the promise of surface engineering to address the challenge of polysulfide shuttling in sulfur-carbon composite cathodes, melt infiltration techniques limit mechanistic studies correlating engineered surfaces and polysulfide anchoring. Here, we present a controlled experimental demonstration of polysulfide anchoring using vapor phase isothermal processing to fill the interior of carbon nanotubes (CNTs) after assembly into binder-free electrodes and atomic layer deposition (ALD) coating of polar V 2 O 5 anchoring layers on the CNT surfaces. The ultrathin submonolayer V 2 O 5 coating on the CNT exterior surface balances the adverse effect of polysulfide shuttling with the necessity for high sulfur utilization due to binding sites near the conductive CNT surface. The sulfur loaded into the CNT interior provides a spatially separated control volume enabling high sulfur loading with direct sulfur-CNT electrical contact for efficient sulfur conversion. By controlling ALD coating thickness, high initial discharge capacity of 1209 mAh/g S at 0.1 C and exceptional cycling at 0.2 C with 87% capacity retention after 100 cycles and 73% at 450 cycles is achieved and correlated to an optimal V 2 O 5 anchoring layer thickness. This provides experimental evidence that surface engineering approaches can be effective to overcome polysulfide shuttling by controlled design of molecular-scale building blocks for efficient binder free lithium sulfur battery cathodes.

Use of New Industrial Coatings for the U.S. Navy Waterfront Structures

DTIC Science & Technology

2008-12-01

utilized as a coating for the interior and exterior of piping systems, which either are located in harsh environments or are transporting substances with...typical application process, a separate set of test Table 7. MCU Coating Systems (SSPC SP 10 Surfaces) (5). SystelD CoatiIli System A Zinc -rich urethane...urethane/MID & AI-filled Urethane/MIO-filled urethane 315/315/314 336/336/336 340/340/336 ~ Micaceous iron oxide. \\) Aluminum. C Zinc . 12 as well as an

Use Of New Industrial Coatings for the U.S. Navy Waterfront Structures

DTIC Science & Technology

2008-01-01

as a coating for the interior and exterior of piping systems, which either are located in harsh environments or are transporting substances with...SSPC SP 10 Surfaces) (5). SyslCm Coating Sys\\~m A Zinc -rich urethane/MIOa·filled urethane/urethane 314/315/314 B Zinc -rich urethane/MIO-filled...urethanc/MIO-urethane 336/3361336 C Zinc -rich urethancl1vfiO & Alb-fined urethaneiMIO-fiIled 337/3401336 ,1 MicaceQus iron oxide. b Aluminum. urethane

Structure, composition and morphology of bioactive titanate layer on porous titanium surfaces

NASA Astrophysics Data System (ADS)

Li, Jinshan; Wang, Xiaohua; Hu, Rui; Kou, Hongchao

2014-07-01

A bioactive coating was produced on pore surfaces of porous titanium samples by an amendatory alkali-heat treatment method. Porous titanium was prepared by powder metallurgy and its porosity and average size were 45% and 135 μm, respectively. Coating morphology, coating structure and phase constituents were examined by SEM, XPS and XRD. It was found that a micro-network structure with sizes of <200 nm mainly composed of bioactive sodium titanate and rutile phases of TiO2 covered the interior and exterior of porous titanium cells, and redundant Ca ion was detected in the titanate layer. The concentration distribution of Ti, O, Ca and Na in the coating showed a compositional gradient from the intermediate layer toward the outer surface. These compositional gradients indicate that the coating bonded to Ti substrate without a distinct interface. After immersion into the SBF solution for 3 days, a bone-like carbonate-hydroxylapatite showing a good biocompatibility was detected on the coating surface. And the redundant Ca advanced the bioactivity of the coating. Thus, the present modification is expected to allow the use of the bioactive porous titanium as artificial bones even under load-bearing conditions.

Flow conditioner for fuel injector for combustor and method for low-NO.sub.x combustor

DOEpatents

Dutta, Partha; Smith, Kenneth O.; Ritz, Frank J.

2013-09-10

An injector for a gas turbine combustor including a catalyst coated surface forming a passage for feed gas flow and a channel for oxidant gas flow establishing an axial gas flow through a flow conditioner disposed at least partially within an inner wall of the injector. The flow conditioner includes a length with an interior passage opening into upstream and downstream ends for passage of the axial gas flow. An interior diameter of the interior passage smoothly reduces and then increases from upstream to downstream ends.

Atomic to Nanoscale Investigation of Functionalities of Al2O3 Coating Layer on Cathode for Enhanced Battery Performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Pengfei; Zheng, Jianming; Zhang, Xiaofeng

2016-01-06

Surface coating of cathode has been identified as an effective approach for enhancing the capacity retention of layered structure cathode. However, the underlying operating mechanism of such a thin layer of coating, in terms of surface chemical functionality and capacity retention, remains unclear. In this work, we use aberration corrected scanning transmission electron microscopy and high efficient spectroscopy to probe the delicate functioning mechanism of Al2O3 coating layer on Li1.2Ni0.2Mn0.6O2 cathode. We discovered that in terms of surface chemical function, the Al2O3 coating suppresses the side reaction between cathode and the electrolyte upon the battery cycling. At the same time,more » the Al2O3 coating layer also eliminates the chemical reduction of Mn from the cathode particle surface, therefore avoiding the dissolution of the reduced Mn into the electrolyte. In terms of structural stability, we found that the Al2O3 coating layer can mitigate the layer to spinel phase transformation, which otherwise will initiate from the particle surface and propagate towards the interior of the particle with the progression of the battery cycling. The atomic to nanoscale effects of the coating layer observed here provide insight for optimized design of coating layer on cathode to enhance the battery properties.« less

Surface and Bulk Characteristics of Cesium Iodide (CsI) coated Carbon (C) Fibers for High Power Microwave (HPM) Field Emission Cathodes

NASA Astrophysics Data System (ADS)

Vlahos, Vasilios; Morgan, Dane; Booske, John H.; Shiffler, Don

2008-11-01

CsI coated C fibers [1] are promising field emission cathodes for HPM applications. Ab initio computational modeling has shown that atomically-thin CsI coatings reduce the work function of C substrates by a surface dipole mechanism [2]. Characterization measurements of the composition and morphology of the CsI-coated C fibers are underway for determining the properties and characteristics of the following important regions of the fiber: (i) the surface on the tip of the fiber where the majority of electron emission is believed to occur, (ii) the surface covering the body of the fiber and its role on the emission properties of the system, and (iii) the interior volume of the fiber and its effects on the CsI surface re-supply process and rate. The results will be interpreted in terms of surface electronic properties and theoretical electron emission models. [1]D. Shiffler, et al., Phys. Plasmas 11 (2004) 1680. [2]V.Vlahos et al., Appl. Phys. Lett. 91 (2007) 144102.

Atomic to Nanoscale Investigation of Functionalities of an Al2O3 Coating Layer on a Cathode for Enhanced Battery Performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Pengfei; Zheng, Jianming; Zhang, Xiaofeng

2016-02-09

Surface coating has been identified as an effective approach for enhancing the capacity retention of layered structure cathode. However, the underlying operating mechanism of such a thin coating layer, in terms of surface chemical functionality and capacity retention, remains unclear. In this work, we use aberration-corrected scanning transmission electron microscopy and high-efficiency spectroscopy to probe the delicate functioning mechanism of an Al2O3 coating layer on a Li1.2Ni0.2Mn0.6O2 cathode. We discovered that in terms of surface chemical function, the Al2O3 coating suppresses the side reaction between the cathode and the electrolyte during battery cycling. At the same time, the Al2O3 coatingmore » layer also eliminates the chemical reduction of Mn from the cathode particle surface, therefore preventing the dissolution of the reduced Mn into the electrolyte. In terms of structural stability, we found that the Al2O3 coating layer can mitigate the layer to spinel phase transformation, which otherwise will be initiated from the particle surface and propagate toward the interior of the particle with the progression of battery cycling. The atomic to nanoscale effects of the coating layer observed here provide insight into the optimized design of a coating layer on a cathode to enhance the battery properties.« less

Method for making a non-extractable stationary phase of polymer within a capillary column

DOEpatents

Springston, Stephen R.

1990-01-01

A method for coating interior capillary column surfaces, or packing material of a packed column, used for gas chromatography, with a stationary polymer phase that is cross-linked by exposing it to a low-temperature plasma that is uniformly distributed over the column or packing material for a predetermined period of time to effect the desired degree of cross-linking of the coating.

Effect of atomic layer deposition coatings on the surface structure of anodic aluminum oxide membranes.

PubMed

Xiong, Guang; Elam, Jeffrey W; Feng, Hao; Han, Catherine Y; Wang, Hsien-Hau; Iton, Lennox E; Curtiss, Larry A; Pellin, Michael J; Kung, Mayfair; Kung, Harold; Stair, Peter C

2005-07-28

Anodic aluminum oxide (AAO) membranes were characterized by UV Raman and FT-IR spectroscopies before and after coating the entire surface (including the interior pore walls) of the AAO membranes by atomic layer deposition (ALD). UV Raman reveals the presence of aluminum oxalate in bulk AAO, both before and after ALD coating with Al2O3, because of acid anion incorporation during the anodization process used to produce AAO membranes. The aluminum oxalate in AAO exhibits remarkable thermal stability, not totally decomposing in air until exposed to a temperature >900 degrees C. ALD was used to cover the surface of AAO with either Al2O3 or TiO2. Uncoated AAO have FT-IR spectra with two separate types of OH stretches that can be assigned to isolated OH groups and hydrogen-bonded surface OH groups, respectively. In contrast, AAO surfaces coated by ALD with Al2O3 display a single, broad band of hydrogen-bonded OH groups. AAO substrates coated with TiO2 show a more complicated behavior. UV Raman results show that very thin TiO2 coatings (1 nm) are not stable upon annealing to 500 degrees C. In contrast, thicker coatings can totally cover the contaminated alumina surface and are stable at temperatures in excess of 500 degrees C.

Method for making a non-extractable stationary phase of polymer within a capillary column

DOEpatents

Springston, S.R.

1990-10-30

A method is described for coating interior capillary column surfaces, or packing material of a packed column, used for gas chromatography, with a stationary polymer phase that is cross-linked by exposing it to a low-temperature plasma that is uniformly distributed over the column or packing material for a predetermined period of time to effect the desired degree of cross-linking of the coating. 7 figs.

Timescales and mechanisms of formation of amorphous silica coatings on fresh basalts at Kīlauea Volcano, Hawai'i

NASA Astrophysics Data System (ADS)

Chemtob, Steven M.; Rossman, George R.

2014-10-01

Young basalts from Kīlauea Volcano, Hawai'i, frequently feature opaque surface coatings, 1-80 μm thick, composed of amorphous silica and Fe-Ti oxides. These coatings are the product of interaction of the basaltic surface with volcanically-derived acidic fluids. Previous workers have identified these coatings in a variety of contexts on Hawai'i, but the timescales of coating development, coating growth rates, and factors controlling lateral coating heterogeneity were largely unconstrained. We sampled and analyzed young lava flows (of varying ages, from hours to ~ 40 years) along Kīlauea's southwest and east rift zones to characterize variation in silica coating properties across the landscape. Coating thickness varies as a function of flow age, flow surface type, and proximity to acid sources like local fissure vents and regional plumes emitted from Kīlauea Caldera and Pu'u Ō'ō. Silica coatings that form in immediate proximity to acid sources are more chemically pure than those forming in higher pH environments, which contain significant Al and Fe. Incipient siliceous alteration was observed on basalt surfaces as young as 8 days old, but periods of a year or more are required to develop contiguous coatings with obvious opaque coloration. Inferred coating growth rates vary with environmental conditions but were typically 1-5 μm/year. Coatings form preferentially on flow surfaces with glassy outer layers, such as spatter ramparts, volcanic bombs, and dense pahoehoe breakouts, due to glass strain weakening during cooling. Microtextural evidence suggests that the silica coatings form both by in situ dissolution-reprecipitation and by deposition of silica mobilized in solution. Thin films of water, acidified by contact with volcanic vapors, dissolved near-surface basalt, then precipitated amorphous silica in place, mobilizing more soluble cations. Additional silica was transported to and deposited on the surface by silica-bearing altering fluids derived from the basalt interior.

PROCESS FOR PRODUCTION OF URANIUM

DOEpatents

Crawford, J.W.C.

1959-09-29

A process is described for the production of uranium by the autothermic reduction of an anhydrous uranium halide with an alkaline earth metal, preferably magnesium One feature is the initial reduction step which is brought about by locally bringing to reaction temperature a portion of a mixture of the reactants in an open reaction vessel having in contact with the mixture a lining of substantial thickness composed of calcium fluoride. The lining is prepared by coating the interior surface with a plastic mixture of calcium fluoride and water and subsequently heating the coating in situ until at last the exposed surface is substantially anhydrous.

Mach 6 electroformed nickel nozzle refurbishment: FNAS investigation of ultra-smooth surfaces

NASA Technical Reports Server (NTRS)

Rood, Robert; Griffith, Charles; Engelhaupt, Darell; Cernosek, John

1992-01-01

The task objective has been to apply a coating of nickel-phosphorous alloy to a laminar flow wind tunnel nozzle by catalytic deposition and then polish and inspect the inside surface using optical device processes. The surface of the nozzle was coated with a nickel-phosphorous alloy of sufficient hardness and corrosion resistance to improve the durability. Due to plating defects that were clearly process related and not inherent, the final polished part was less than the desired quality. Surface finishing processes and lapping media were identified which produced a submicron surface finish on the interior plated surface. Defects apparently manifested by the first plating attempt were repaired using a small brush plating process demonstrating that individual small defects can be repaired. Measurement and analysis by profilometry demonstrated that quantitative control of the surface can be achieved.

40 CFR 59.405 - Container labeling requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... this section that applies to the coating.) (i) Immersion in water, wastewater, or chemical solutions (aqueous and nonaqueous solutions), or chronic exposure of interior surfaces to moisture condensation; (ii... chemical mixtures or solutions; (iii) Repeated exposure to temperatures above 120 °C (250 °F); (iv...

Mesoporous metal oxide microsphere electrode compositions and their methods of making

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parans Paranthaman, Mariappan; Bi, Zhonghe; Bridges, Craig A.

Compositions and methods of making are provided for treated mesoporous metal oxide microspheres electrodes. The compositions include microspheres with an average diameter between about 200 nanometers and about 10 micrometers and mesopores on the surface and interior of the microspheres. The methods of making include forming a mesoporous metal oxide microsphere composition and treating the mesoporous metal oxide microspheres by at least annealing in a reducing atmosphere, doping with an aliovalent element, and coating with a coating composition.

46 CFR 160.026-3 - Container.

Code of Federal Regulations, 2012 CFR

2012-10-01

... on the outside. The can shall be made of 1.25-pound coating coke tin-plate throughout, with not less.... The interior of the container shall be uncoated, except for the tin-plating required by paragraph (a) of this section. In addition to the tin-plating, the exterior surfaces of the container, including...

46 CFR 160.026-3 - Container.

Code of Federal Regulations, 2010 CFR

2010-10-01

... on the outside. The can shall be made of 1.25-pound coating coke tin-plate throughout, with not less.... The interior of the container shall be uncoated, except for the tin-plating required by paragraph (a) of this section. In addition to the tin-plating, the exterior surfaces of the container, including...

46 CFR 160.026-3 - Container.

Code of Federal Regulations, 2014 CFR

2014-10-01

... on the outside. The can shall be made of 1.25-pound coating coke tin-plate throughout, with not less.... The interior of the container shall be uncoated, except for the tin-plating required by paragraph (a) of this section. In addition to the tin-plating, the exterior surfaces of the container, including...

46 CFR 160.026-3 - Container.

Code of Federal Regulations, 2011 CFR

2011-10-01

... on the outside. The can shall be made of 1.25-pound coating coke tin-plate throughout, with not less.... The interior of the container shall be uncoated, except for the tin-plating required by paragraph (a) of this section. In addition to the tin-plating, the exterior surfaces of the container, including...

46 CFR 160.026-3 - Container.

Code of Federal Regulations, 2013 CFR

2013-10-01

... on the outside. The can shall be made of 1.25-pound coating coke tin-plate throughout, with not less.... The interior of the container shall be uncoated, except for the tin-plating required by paragraph (a) of this section. In addition to the tin-plating, the exterior surfaces of the container, including...

Preparation and characterization of hydroxyapatite-coated iron oxide particles by spray-drying technique.

PubMed

Donadel, Karina; Felisberto, Marcos D V; Laranjeira, Mauro C M

2009-06-01

Magnetic particles of iron oxide have been increasingly used in medical diagnosis by magnetic resonance imaging and in cancer therapies involving targeted drug delivery and magnetic hyperthermia. In this study we report the preparation and characterization of iron oxide particles coated with bioceramic hydroxyapatite by spray-drying. The iron oxide magnetic particles (IOMP) were coated with hydroxyapatite (HAp) by spray-drying using two IOMP/HAp ratios (0.7 and 3.2). The magnetic particles were characterized by way of scanning electronic microscopy, energy dispersive X-ray, X-ray diffraction, Fourier transformed infrared spectroscopy, flame atomic absorption spectrometry,vibrating sample magnetometry and particle size distribution (laser diffraction). The surface morphology of the coated samples is different from that of the iron oxide due to formation of hydroxyapatite coating. From an EDX analysis, it was verified that the surface of the coated magnetic particles is composed only of HAp, while the interior containsiron oxide and a few layers of HAp as expected. The results showed that spray-drying technique is an efficient and relatively inexpensive method for forming spherical particles with a core/shell structure.

Inexpensive Method for Coating the Interior of Silica Growth Ampoules with Pyrolytic Boron Nitride

NASA Technical Reports Server (NTRS)

Wang, Jianbin; Regel, Liya L.; Wilcox, William R.

2003-01-01

An inexpensive method was developed for coating the interior of silica ampoules with hexagonal boron nitride. An aqueous solution of boric acid was used to coat the ampoule prior to drying in a vacuum at 200 C. This coating was converted to transparent boron nitride by heating in ammonia at 1000 C. Coated ampoules were used to achieve detached solidification of indium antimonide on earth.

Ablation properties of inorganic filler modified benzoxazine composite coating irradiated by high-intensity continuous laser

NASA Astrophysics Data System (ADS)

Xu, Feng; Ma, Zhuang; Li, Hezhang; Gao, Lihong; Wang, Fuchi

2017-05-01

Benzoxazine resin with good heat resistance, low combustion heat release and high char yield is a promising thermosetting resin. Meanwhile, research shows that the inorganic filler can effectively improve the thermodynamic property of the resin. It makes that the inorganic filler modified benzoxazine may have a potential application in laser ablation. The benzoxazine coating with and without inorganic filler ammonium polyphosphate, melamine and pentaerythritol (P-BOZ and BOZ) were prepared by brush and thermal curing method. The ablation properties of these coatings irradiated by high-intensity laser were investigated. The scanning electron microscope, Raman spectroscopy and thermal gravimetric analysis were used to characterize the micrographs, carbon layer structure and thermodynamic property of the sample. Results show that the composite coating has excellent thermal protective properties. The back temperature of 20 wt% P-BOZ coating under different parameter laser power (1000W/cm2, 5s; 1000W/cm2, 10s) are 40% lower than these of the BOZ coating and the 20 wt% P-BOZ has higher mass ablation rate. In the surface layer of the irradiated area, dense carbon layer is produced which reduces the absorb of the laser energy of the interior. In the interior of the sample, a large number of closed bell shaped holes are generated which are beneficial to obstruct the heat conduction.

Silk-regulated hierarchical hollow magnetite/carbon nanocomposite spheroids for lithium-ion battery anodes.

PubMed

Sheng, Weiqin; Zhu, Guobin; Kaplan, David L; Cao, Chuanbao; Zhu, Hesun; Lu, Qiang

2015-03-20

Hierarchical olive-like structured carbon-Fe3O4 nanocomposite particles composed of a hollow interior and a carbon coated surface are prepared by a facile, silk protein-assisted hydrothermal method. Silk nanofibers as templates and carbon precursors first regulate the formation of hollow Fe2O3 microspheres and then they are converted into carbon by a reduction process into Fe3O4. This process significantly simplifies the fabrication and carbon coating processes to form complex hollow structures. When tested as anode materials for lithium-ion batteries, these hollow carbon-coated particles exhibit high capacity (900 mAh g(-1)), excellent cycle stability (180 cycles) and rate performance due to their unique hierarchical hollow structure and carbon coating.

New and Improved Methods for Monitoring Air Quality and the Terrestrial Environment

DTIC Science & Technology

1999-06-01

SECTION 6 3 of 5 Working Copy: New and Improved Methods for Biomonitoring, 1998 Annual Report Propolis . The material used by bees to seal cracks...in the hive, reinforce comb walls, and create a smooth coating over interior surfaces. Propolis is made up of plant resins collected by bees. Pupae

Hydrophobizing coatings for cultural heritage. A detailed study of resin/stone surface interaction

NASA Astrophysics Data System (ADS)

Fermo, P.; Cappelletti, G.; Cozzi, N.; Padeletti, G.; Kaciulis, S.; Brucale, M.; Merlini, M.

2014-07-01

Conservation of historical buildings is an important issue and the environmental conditions seriously affect the monument's stones. The protection of cultural heritage buildings and monuments by surface treatment with polymers is a common practice due to their ability to form a protective layer on the monument's surface as well as to control the transport of different fluids from the surface to the monument's interior. In this work, three different substrates were used: Carrara marble, Botticino limestone, and Angera stone. A commercially available Si-based resin (Alpha®SI30) was used as protective agent to improve the hydrophobicity features of the different tested materials. The surface properties of the coating and the relative interaction with the adopted stones were studied using different techniques such as contact angle measurements, electron microscope coupled with an energy dispersive spectrometer, X-ray photoelectron spectroscopy, atomic force microscopy, and attenuated total reflection infrared spectroscopy.

Arraying of intact liposomes into chemically functionalized microwells.

PubMed

Kalyankar, Nikhil D; Sharma, Manoj K; Vaidya, Shyam V; Calhoun, David; Maldarelli, Charles; Couzis, Alexander; Gilchrist, Lane

2006-06-06

Here, we describe a protocol to bind individual, intact phospholipid bilayer liposomes, which are on the order of 1 microm in diameter, in microwells etched in a regular array on a silicon oxide substrate. The diameter of the wells is on the order of the liposome diameter, so only one liposome is located in each well. The background of the silicon oxide surface is functionalized with a PEG oligomer using the contact printing of a PEG silane to present a surface that resists the adsorption of proteins, lipid material, and liposomes. The interiors of the wells are functionalized with an aminosilane to facilitate the conjugation of biotin, which is then bound to Neutravidin. The avidin-coated well interiors bind the liposomes whose surfaces contain biotinylated lipids. The specific binding of the liposomes to the surface using the biotin-avidin linkage, together with the resistant nature of the background and the physical confinement of the wells, allows the liposomes to remain intact and to not unravel, rupture, and fuse onto the surface. We demonstrate this intact arraying using confocal laser scanning microscopy of fluorophores specifically tagging the microwells, the lipid bilayer, and the aqueous interior of the liposome.

Mercury (Hg) and lead (Pb) in interior and exterior New Orleans house paint films.

PubMed

Mielke, Howard W; Gonzales, Chris

2008-06-01

Pre-1992, latex paint was formulated with mercury (Hg) as phenylmercuric acetate (PMA). Hg vaporizes reducing its content, and lead (Pb) is stable and remains unchanged. The objective of this study is to describe the content of Hg and Pb in existing paint coatings. Forty paint chip samples were collected from both interior and exterior surfaces of homes in metropolitan New Orleans and analyzed for Hg and Pb. The median Hg in exterior paints is 26.9 mg kg(-1) (0.8-214.0) compared with 7.1 mg kg(-1) (0.03-39.2) for interior paints. The median Pb content is 76603 mg kg(-1) (464-317151) and 416 mg kg(-1) (24-63313) respectively, for exterior and interior paints. The Spearman correlation coefficients for Hg and Pb are -0.312 (P=0.13) and -0.471 (P=0.07) respectively, in exterior and interior samples. Hg and Pb vary independently with each other in paint films. Median Hg in exterior paints is four times larger than for interior paints. Median Pb in exterior paints is 184 times larger than interior paints. The Pb and Hg content in exterior and interior paint chips are significantly different (Mann-Whitney Rank Sum Test, P0.001 and P=0.006, respectively). Only 1 of the 25 exterior paints contained less than the current 5000 mg kg(-1) US standard for Pb, the criteria for exemption from the power-sanding restrictions of the New Orleans Lead Ordinance. Prior to banning PMA in paint, Hg poisonings presented as acrodynia were reported for children living in homes freshly painted with latex paint. Because of the affinity of Hg and Pb for sulfur-containing amino acid proteins, their presence in paint coatings poses an increased hazard when released as dust.

Anodizing of High Electrically Stressed Components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flores, P.; Henderson, D. J.; Good, D. E.

2013-06-01

Anodizing creates an aluminum oxide coating that penetrates into the surface as well as builds above the surface of aluminum creating a very hard ceramic-type coating with good dielectric properties. Over time and use, the electrical carrying components (or spools in this case) experience electrical breakdown, yielding undesirable x-ray dosages or failure. The spool is located in the high vacuum region of a rod pinch diode section of an x-ray producing machine. Machine operators have recorded decreases in x-ray dosages over numerous shots using the reusable spool component, and re-anodizing the interior surface of the spool does not provide themore » expected improvement. A machine operation subject matter expert coated the anodized surface with diffusion pump oil to eliminate electrical breakdown as a temporary fix. It is known that an anodized surface is very porous, and it is because of this porosity that the surface may trap air that becomes a catalyst for electrical breakdown. In this paper we present a solution of mitigating electrical breakdown by oiling. We will also present results of surface anodizing improvements achieved by surface finish preparation and surface sealing. We conclude that oiling the anodized surface and using anodized hot dip sealing processes will have similar results.« less

Surface chemical analysis and ab initio investigations of CsI coated C fiber cathodes for high power microwave sources

NASA Astrophysics Data System (ADS)

Vlahos, Vasilios; Morgan, Dane; LaCour, Matthew; Golby, Ken; Shiffler, Don; Booske, John H.

2010-02-01

CsI coated C fiber cathodes are promising electron emitters utilized in field emission applications. Ab initio calculations, in conjunction with experimental investigations on CsI-spray coated C fiber cathodes, were performed in order to better understand the origin of the low turn-on E-field obtained, as compared to uncoated C fibers. One possible mechanism for lowering the turn-on E-field is surface dipole layers reducing the work function. Ab initio modeling revealed that surface monolayers of Cs, CsI, Cs2O, and CsO are all capable of producing low work function C fiber cathodes (1 eV<Φ<1.5 eV), yielding a reduction in the turn-on E-field by as much as ten times, when compared to the bare fiber. Although a CsI-containing aqueous solution is spray deposited on the C fiber surface, energy dispersive x-ray spectroscopy and scanning auger microscopy measurements show coabsorption of Cs and I into the fiber interior and Cs and O on the fiber surface, with no surface I. It is therefore proposed that a cesium oxide (CsxOy) surface coating is responsible, at least in part, for the low turn E-field and superior emission characteristics of this type of fiber cathode. This CsxOy layer could be formed during preconditioning heating. CsxOy surface layers cannot only lower the fiber work function by the formation of surface dipoles (if they are thin enough) but may also enhance surface emission through their ability to emit secondary electrons due to a process of grazing electron impact. These multiple electron emission processes may explain the reported 10-100 fold reduction in the turn-on E-field of coated C fibers.

Method and device for producing and delivering an aerosol for remote sealing and coating

DOEpatents

Modera, M.P.; Carrie, F.R.

1996-06-04

The invention is a method and device for sealing leaks remotely by means of injecting a previously prepared aerosol into the enclosure being sealed. Specifically the invention is a method and device for preparing, transporting, and depositing and solid phase aerosol to the interior surface of the enclosure. 1 fig.

INTERIOR VIEW, LOOKING WEST, WITH PIPE BEING SPRAYED WITH ZINC ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR VIEW, LOOKING WEST, WITH PIPE BEING SPRAYED WITH ZINC COATING. - United States Pipe & Foundry Company Plant, Coating, Painting, Lining & Packaging Building, 2023 St. Louis Avenue at I-20/59, Bessemer, Jefferson County, AL

Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

DOEpatents

Wrenn, Jr., George E.; Lewis, Jr., John

1984-01-01

The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

DOEpatents

Wrenn, G.E. Jr.; Lewis, J. Jr.

1982-09-29

The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

Wear Resistance Enhancement of Ti-6Al-4 V Alloy by Applying Zr-Modified Silicide Coatings

NASA Astrophysics Data System (ADS)

Li, Xuan; Hu, Guangzhong; Tian, Jin; Tian, Wei; Xie, Wenling; Li, Xiulan

2018-03-01

Zr-modified silicide coatings were prepared on Ti-6Al-4 V alloy by pack cementation process to enhance its wear resistance. The microstructure and wear properties of the substrate and the coatings were comparatively investigated using GCr15 and Al2O3 as the counterparts under different sliding loads. The obtained Zr-modified silicide coating had a multilayer structure, consisting of a thick (Ti, X)Si2 (X represents Al, Zr and V elements) outer layer, a TiSi middle layer and a Ti5Si4 + Ti5Si3 inner layer. The micro-hardness of the coating was much higher than the substrate and displayed a decrease tendency from the coating surface to the interior. Sliding against either GCr15 or Al2O3 balls, the coatings showed superior anti-friction property to the Ti-6Al-4 V alloy, as confirmed by its much lower wear rate under each employed sliding condition.

Clamshell microwave cavities having a superconductive coating

DOEpatents

Cooke, D. Wayne; Arendt, Paul N.; Piel, Helmut

1994-01-01

A microwave cavity including a pair of opposing clamshell halves, such halves comprised of a metal selected from the group consisting of silver, copper, or a silver-based alloy, wherein the cavity is further characterized as exhibiting a dominant TE.sub.011 mode is provided together with an embodiment wherein the interior concave surfaces of the clamshell halves are coated with a superconductive material. In the case of copper clamshell halves, the microwave cavity has a Q-value of about 1.2.times.10.sup.5 as measured at a temperature of 10K and a frequency of 10 GHz.

FINISHING FABRICATED METAL PRODUCTS WITH ...

EPA Pesticide Factsheets

This report provides a technical and economic evaluation of a polyester powder coating system applied to the exterior and interior surfaces of metal boxes fabricated for the telephone and cable industries. This evaluation summarized many of the requirements and benefits of a clean technology that effectively eliminates the use of hazardous solvents and prevents the generation of volatile organic emissions and hazardous solid waste. publish information

Beam Tests of Diamond-Like Carbon Coating for Mitigation of Electron Cloud

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eldred, Jeffrey; Backfish, Michael; Kato, Shigeki

Electron cloud beam instabilities are an important consideration in virtually all high-energy particle accelerators and could pose a formidable challenge to forthcoming high-intensity accelerator upgrades. Our results evaluate the efficacy of a diamond-like carbon (DLC) coating for the mitigation of electron in the Fermilab Main Injector. The interior surface of the beampipe conditions in response to electron bombardment from the electron cloud and we track the change in electron cloud flux over time in the DLC coated beampipe and uncoated stainless steel beampipe. The electron flux is measured by retarding field analyzers placed in a field-free region of the Mainmore » Injector. We find the DLC coating reduces the electron cloud signal to roughly 2\\% of that measured in the uncoated stainless steel beampipe.« less

High color fidelity thin film multilayer systems for head-up display use

NASA Astrophysics Data System (ADS)

Tsou, Yi-Jen D.; Ho, Fang C.

1996-09-01

Head-up display is gaining increasing access in automotive vehicles for indication and position/navigation purposes. An optical combiner, which allows the driver to receive image information from outside and inside of the automobile, is the essential part of this display device. Two multilayer thin film combiner coating systems with distinctive polarization selectivity and broad band spectral neutrality are discussed. One of the coating systems was designed to be located at the lower portion of the windshield. The coating reduced the exterior glare by approximately 45% and provided about 70% average see-through transmittance in addition to the interior information display. The other coating system was designed to be integrated with the sunshield located at the upper portion of the windshield. The coating reflected the interior information display while reducing direct sunlight penetration to 25%. Color fidelity for both interior and exterior images were maintained in both systems. This facilitated the display of full-color maps. Both coating systems were absorptionless and environmentally durable. Designs, fabrication, and performance of these coating systems are addressed.

Effects Investigated of Ambient High-Temperature Exposure on Alumina-Titania High-Emittance Surfaces for Solar Dynamic Systems

NASA Technical Reports Server (NTRS)

deGroh, Kim K.; Smith, Daniela C.

1999-01-01

Solar-dynamic space power systems require durable, high-emittance surfaces on a number of critical components, such as heat receiver interior surfaces and parasitic load radiator (PLR) elements. An alumina-titania coating, which has been evaluated for solar-dynamic heat receiver canister applications, has been chosen for a PLR application (an electrical sink for excess power from the turboalternator/compressor) because of its demonstrated high emittance and high-temperature durability in vacuum. Under high vacuum conditions (+/- 10(exp -6) torr), the alumina-titania coating was found to be durable at temperatures of 1520 F (827 C) for approx. 2700 hours with no degradation in optical properties. This coating has been successfully applied to the 2-kW solar-dynamic ground test demonstrator at the NASA Lewis Research Center, to the 500 thermal-energy-storage containment canisters inside the heat receiver and to the PLR radiator. The solar-dynamic demonstrator has successfully operated for over 800 hours in Lewis large thermal/vacuum space environment facility, demonstrating the feasibility of solar-dynamic power generation for space applications.

Bioinspired anchoring AgNPs onto micro-nanoporous TiO2 orthopedic coatings: Trap-killing of bacteria, surface-regulated osteoblast functions and host responses.

PubMed

Jia, Zhaojun; Xiu, Peng; Li, Ming; Xu, Xuchen; Shi, Yuying; Cheng, Yan; Wei, Shicheng; Zheng, Yufeng; Xi, Tingfei; Cai, Hong; Liu, Zhongjun

2016-01-01

The therapeutic applications of silver nanoparticles (AgNPs) against biomedical device-associated infections (BAI), by local delivery, are encountered with risks of detachment, instability and nanotoxicity in physiological milieus. To firmly anchor AgNPs onto modified biomaterial surfaces through tight physicochemical interactions would potentially relieve these concerns. Herein, we present a strategy for hierarchical TiO2/Ag coating, in an attempt to endow medical titanium (Ti) with anticorrosion and antibacterial properties whilst maintaining normal biological functions. In brief, by harnessing the adhesion and reactivity of bioinspired polydopamine, silver nanoparticles were easily immobilized onto peripheral surface and incorporated into interior cavity of a micro/nanoporous TiO2 ceramic coating in situ grown from template Ti. The resulting coating protected the substrate well from corrosion and gave a sustained release of Ag(+) up to 28 d. An interesting germicidal effect, termed "trap-killing", was observed against Staphylococcus aureus strain. The multiple osteoblast responses, i.e. adherence, spreading, proliferation, and differentiation, were retained normal or promoted, via a putative surface-initiated self-regulation mechanism. After subcutaneous implantation for a month, the coated specimens elicited minimal, comparable inflammatory responses relative to the control. Moreover, this simple and safe functionalization strategy manifested a good degree of flexibility towards three-dimensional sophisticated objects. Expectedly, it can become a prospective bench to bedside solution to current challenges facing orthopedics. Copyright © 2015 Elsevier Ltd. All rights reserved.

Development of Scaffolds for Light Harvesting and Photocatalysis from the Coat Protein of Tobacco Mosaic Virus

NASA Astrophysics Data System (ADS)

Dedeo, Michel Toussaint

The utility of a previously developed TMV-based light harvesting system has been dramatically expanded through the introduction of reactive handles for the site-specific modification of the interior and exterior surfaces. Further experiments to reengineer the coat protein have produced structures with unique, unexpected, and useful assembly properties that complement the newly available surface modifications. Energy transfer from chromophores in the RNA channel of self-assembled TMV structures to the exterior was made possible by conjugation of acceptor dyes and porphyrins to the N-terminus. By repositioning the N-terminus to the pore through circular permutation, this process was repeated to create structures that mimic the light harvesting 1 complex of photosynthetic bacteria. To study and improve upon natural photosynthesis, closely packed chromophore arrays and gold nanoparticles were tethered to the pore of stabilized TMV disks through introduction of a uniquely reactive lysine. Finally, a dimeric TMV coat protein was produced to control the distribution and arrangement of synthetic groups with synergistic activity.

Axial static mixer

DOEpatents

Sandrock, H.E.

1982-05-06

Static axial mixing apparatus includes a plurality of channels, forming flow paths of different dimensions. The axial mixer includes a flow adjusting device for adjustable selective control of flow resistance of various flow paths in order to provide substantially identical flows through the various channels, thereby reducing nonuniform coating of interior surfaces of the channels. The flow adjusting device may include diaphragm valves, and may further include a pressure regulating system therefor.

Note: a novel vacuum ultraviolet light source assembly with aluminum-coated electrodes for enhancing the ionization efficiency of photoionization mass spectrometry.

PubMed

Zhu, Zhixiang; Wang, Jian; Qiu, Keqing; Liu, Chengyuan; Qi, Fei; Pan, Yang

2014-04-01

A novel vacuum ultraviolet (VUV) light source assembly (VUVLSA) for enhancing the ionization efficiency of photoionization mass spectrometer has been described. The VUVLSA composes of a Krypton lamp and a pair of disk electrodes with circular center cavities. The two interior surfaces that face the photoionization region were aluminum-coated. VUV light can be reflected back and forth in the photoionization region between the electrodes, thus the photoionization efficiency can be greatly enhanced. The performances of two different shaped electrodes, the coated double flat electrodes (DFE), and double conical electrodes, were studied. We showed that the signal amplification of coated DFE is around 4 times higher than that of uncoated electrodes without VUV light reflection. The relationship between the pressure of ionization chamber and mass signal enhancement has also been studied.

An investigation of the curing process for moisture-crosslinkable polyethylene used in cable coating extrusion

NASA Astrophysics Data System (ADS)

Cantor, Kirk Martin

1998-12-01

Moisture-crosslinkable polyethylene used in the extrusion coating of electrical cable has many advantages over other polymer systems used for crosslinked cable coating. However, one of its major drawbacks is the long cure times required. The purpose of this study was to describe how curing takes place in cable systems using moisture-crosslinkable polyethylene, with an ultimate goal of gaining insight into how cure times might be reduced. Crosslinking was investigated with an emphasis on how the curing reaction proceeds through the coating, using analyses to characterize processing conditions and resulting mechanical and structural properties. In the design of the study, material compounds were varied as were curing conditions. Cable coatings were sectioned by position through the coating thickness and characterized using several techniques. Mechanical, thermal, and structural properties of the polymer coating were measured. A significant finding from the study was that the degree of cure was highest at positions in the coating closest to the conductor. Because this was opposite to what was expected, an investigation into the cause of this finding was pursued. It was found that during cure at elevated temperature, the inside surface of the coating remains at a generally higher temperature than the outside surface. This provides a more favorable cure condition for positions in the coating closest to the conductor. Based on the results of this study, a list of suggested follow-up studies is provided at the end of the dissertation. One proposal for investigating reduced cure times involves providing heat to the interior of the cable during cure.

Investigation of the potential antimicrobial efficacy of sealants used in HVAC systems.

PubMed

Foarde, K K; VanOsdell, D W; Menetrez, M Y

2001-08-01

Recent experiments confirm field experience that duct cleaning alone may not provide adequate protection from regrowth of fungal contamination on fiberglass duct liner (FGDL). Current recommendations for remediation of fungally contaminated fiberglass duct materials specify complete removal of the materials. But removal of contaminated materials can be extremely expensive. Therefore, a common practice in the duct-cleaning industry is the postcleaning use of antimicrobial surface coatings with the implication that they may contain or limit regrowth. Little information is available on the efficacy of these treatments. This paper describes a study to evaluate whether three commercially available antimicrobial coatings, placed on a cleaned surface that 1 year previously had been actively growing microorganisms, would be able to prevent regrowth. The three coatings contained different active antimicrobial compounds. All three of the coatings were designed for use on heating, ventilation, and air conditioning (HVAC) system components or interior surfaces of lined and unlined duct systems. Coating I was a polyacrylate copolymer containing zinc oxide and borates. Coating II was an acrylic coating containing decabromodiphenyl oxide and antimony trioxide. Coating III was an acrylic primer containing a phosphated quaternary amine complex. The study included field and laboratory assessments. The three treatments were evaluated in an uncontrolled field setting in an actual duct system. The laboratory study broadened the field study to include a range of humidities under controlled conditions. Both static and dynamic chamber laboratory experiments were performed. The results showed that two of the three antimicrobial coatings limited the regrowth of fungal contamination, at least in the short term (the 3-month time span of the study); the third did not. Before use in the field, testing of the efficacy of antimicrobial coatings under realistic use conditions is recommended because antimicrobials have different baseline activities and interact differently with the substrate that contains them and their local environment.

Fire performance of fiber board coated with nano kaolin-clay film

Treesearch

Zhijia Liu; John F. Hunt; Zhiyong Cai

2013-01-01

Fiberboard is a common interior material used both in China and the United States of America. The increase in demand for interior materials has raised concerns regarding combustibility of the materials. The pyrolysis characteristics of fiber, phenolic resin (PF), and nano kaolin-clay (NK) were investigated using thermogravimetry. The fire performances of samples coated...

Effects of Stone-Wales and vacancy defects in atomic-scale friction on defective graphite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Xiao-Yu; Key Laboratory of Hubei Province for Water Jet Theory and New Technology, Wuhan University, Wuhan 430072; Wu, RunNi

2014-05-05

Graphite is an excellent solid lubricant for surface coating, but its performance is significantly weakened by the vacancy or Stone-Wales (SW) defect. This study uses molecular dynamics simulations to explore the frictional behavior of a diamond tip sliding over a graphite which contains a single defect or stacked defects. Our results suggest that the friction on defective graphite shows a strong dependence on defect location and type. The 5-7-7-5 structure of SW defect results in an effectively negative slope of friction. For defective graphite containing a defect in the surface, adding a single vacancy in the interior layer will decreasemore » the friction coefficients, while setting a SW defect in the interior layer may increase the friction coefficients. Our obtained results may provide useful information for understanding the atomic-scale friction properties of defective graphite.« less

Temperature Distributions in Semitransparent Coatings: A Special Two-Flux Solution

NASA Technical Reports Server (NTRS)

Siegel, Robert; Spuckler, Charles M.

1995-01-01

Radiative transfer is analyzed in a semitransparent coating on an opaque substrate and in a semitransparent layer for evaluating thermal protection behavior and ceramic component performance in high temperature applications. Some ceramics are partially transparent for radiative transfer, and at high temperatures internal emission and reflections affect their thermal performance. The behavior is examined for a ceramic component for which interior cooling is not provided. Two conditions are considered: (1) the layer is heated by penetration of radiation from hot surroundings while its external surface is simultaneously film cooled by convection, and (2) the surface is heated by convection while the semitransparent material cools from within by radiant emission leaving through the surface. By using the two-flux method, which has been found to yield good accuracy in previous studies, a special solution is obtained for these conditions. The analytical result includes isotropic scattering and requires only an integration to obtain the temperature distribution within the semitransparent material. Illustrative results are given to demonstrate the nature of the thermal behavior.

Applying a tapered electrode on a porous ceramic support tube by masking a band inside the tube and drawing in electrode material from the outside of the tube by suction

DOEpatents

Vasilow, T.R.; Zymboly, G.E.

1991-12-17

An electrode is deposited on a support by providing a porous ceramic support tube having an open end and closed end; masking at least one circumferential interior band inside the tube; evacuating air from the tube by an evacuation system, to provide a permeability gradient between the masked part and unmasked part of the tube; applying a liquid dispersion of solid electrode particles to the outside surface of the support tube, where liquid flows through the wall, forming a uniform coating over the unmasked support part and a tapered coating over the masked part. 2 figures.

Diffusion mechanisms in chemical vapor-deposited iridium coated on chemical vapor-deposited rhenium

NASA Technical Reports Server (NTRS)

Hamilton, J. C.; Yang, N. Y. C.; Clift, W. M.; Boehme, D. R.; Mccarty, K. F.; Franklin, J. E.

1992-01-01

Radiation-cooled rocket thruster chambers have been developed which use CVD Re coated with CVD Ir on the interior surface that is exposed to hot combustion gases. The Ir serves as an oxidation barrier which protects the structural integrity-maintaining Re at elevated temperatures. The diffusion kinetics of CVD materials at elevated temperatures is presently studied with a view to the prediction and extension of these thrusters' performance limits. Line scans for Ir and Re were fit on the basis of a diffusion model, in order to extract relevant diffusion constants; the fastest diffusion process is grain-boundary diffusion, where Re diffuses down grain boundaries in the Ir overlayer.

Micro-mapping Meteorite Surfaces on Mars using Microscopic Imager Mosaics — A Tool for Unraveling Weathering History at Meridiani Planum

NASA Astrophysics Data System (ADS)

Ashley, J. W.; Herkenhoff, K. E.; Golombek, M. P.; Johnson, J. R.

2012-12-01

Meteorites found on Mars provide valuable insights into martian surface processes. During the course of Mars Exploration Rover (MER) extended missions, Spirit and Opportunity have identified 17 confirmed and candidate meteorites on Mars, most of which are irons. The iron meteorites exhibit morphologies and coatings that communicate complex post-fall exposure histories relevant to an understanding of climate near the martian equator [1-4]. Both chemical and mechanical weathering effects are represented. Among the more significant of these are: 1) cm-scale hollowing, 2) surficial rounding, 3) mass excavation/dissolution and removal, 4) differential etching of kamacite plates and taenite lamellae, revealing Widmanstätten patterns, 5) discontinuous iron oxide coatings, and 6) the effects of cavernous weathering, which often penetrate to rock interiors. Determining the nature, magnitude, and timing of each process and its associated features is a complex problem that will be aided by laboratory experiments, image processing, and careful surface evaluation. Because some features appear to superpose others in ways analogous to stratigraphic relationships, Microscopic Imager (MI) mosaics are useful for sketching "geologic maps" of meteorite surfaces. Employing the techniques of conventional planetary mapping [5], each map was drafted manually using full-resolution MI mosaics and Adobe Photoshop software. Units were selected to represent the oxide coating, dust-coated surfaces, sand-coated surfaces, taenite lamellae, and uncoated metal. Also included are areas in shadow, and regions of blooming caused by specular reflection of metal. Regmaglypt rim crests are presented as lineations. As with stratigraphic relationships, noting embayments and other cross-cutting relationships assists with establishing the relative timing for observed weathering effects. In addition to suggesting alternating sequences of wind and water exposure [1], patterns in oxide coating occurrence show evidence that coating deposition (interpreted as a result of water interaction) was geologically recent: Because the margins of many oxide coating deposits are concentric to and slightly removed from regmaglypt rim crests, the latest cycle is interpreted as a time of coating removal, not deposition, with these topographic high points representing zones of greatest erosional attack. Assuming the oxide coating has a low to moderate hardness, this observation implies relative geologic youth for the coating. However, it is unknown whether oxide deposits are stable or actively eroded by free basaltic sand grains [e.g., 6] in the modern epoch. The high science return from ongoing meteorite studies at MER landing sites supports their consideration if meteorites are also encountered by the Mars Science Laboratory Curiosity rover in Gale Crater.

[The use of structural proximal tibial allografts coated with human albumin in treating extensive periprosthetic knee-joint bone deficiency and averting late complications. Case report].

PubMed

Klára, Tamás; Csönge, Lajos; Janositz, Gábor; Pap, Károly; Lacza, Zsombor

2015-01-11

The authors report the history of a 74-year-old patient who underwent surgical treatment for segmental knee-joint periprosthetic bone loss using structural proximal tibial allografts coated with serum albumin. Successful treatment of late complications which occurred in the postoperative period is also described. The authors emphasize that bone replacement with allografts is a physiological process that enables the stable positioning of the implant and the reconstruction of the soft tissues, the replacement of extensive bone loss, and also it is a less expensive operation. It has been already confirmed that treatment of lyophilised allografts with albumin improves the ability of bone marrow-derived mesenchymal stem cells to adhere and proliferate the surface of the allografts, penetrate the pores and reach deeper layers of the graft. Earlier studies have shown osteoblast activity on the surface and interior of the graft.

Mesoporous metal oxide microsphere electrode compositions and their methods of making

DOEpatents

Parans Paranthaman, Mariappan; Bi, Zhonghe; Bridges, Craig A; Brown, Gilbert M

2014-12-16

Compositions and methods of making are provided for treated mesoporous metal oxide microspheres electrodes. The compositions comprise (a) microspheres with an average diameter between 200 nanometers (nm) and 10 micrometers (.mu.m); (b) mesopores on the surface and interior of the microspheres, wherein the mesopores have an average diameter between 1 nm and 50 nm and the microspheres have a surface area between 50 m.sup.2/g and 500 m.sup.2/g, and wherein the composition has an electrical conductivity of at least 1.times.10.sup.-7 S/cm at 25.degree. C. and 60 MPa. The methods of making comprise forming a mesoporous metal oxide microsphere composition and treating the mesoporous metal oxide microspheres by at least one method selected from the group consisting of: (i) annealing in a reducing atmosphere, (ii) doping with an aliovalent element, and (iii) coating with a coating composition.

77 FR 41337 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Control Technique...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-13

... following definitions: Adhesion primer, aerosol coating product, air-dried coating, baked coating, dip... coatings..... 0.85 7.1. Automotive/Transportation Parts High bake coatings Flexible primer 0.46 3.8. Non....3. Interior colorcoat 0.49 4.1. Exterior colorcoat 0.55 4.6. Low bake/air dried coatings-exterior...

40 CFR 52.1100 - Original identification of plan section.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Coating, Interior Sheet Drum Lining). (i) Incorporation by reference. (A) Revisions to COMAR 10.18.21.10... paper and plastic parts coating, including definitions for the terms fountain, letterpress printing... coating, and the addition of definitions for the terms sheet-fed paper coating and ultraviolet curable...

Liquid Coatings for Reducing Corrosion of Steel in Concrete

NASA Technical Reports Server (NTRS)

MacDowell, Louis G.; Curran, Joseph

2003-01-01

Inorganic coating materials are being developed to slow or stop corrosion of reinforcing steel members inside concrete structures. It is much simpler and easier to use these coating materials than it is to use conventional corrosion-inhibiting systems based on impressed electric currents. Unlike impressed electrical corrosion-inhibiting systems, these coatings do not require continuous consumption of electrical power and maintenance of power-supply equipment. Whereas some conventional systems involve the use of expensive arc-spray equipment to apply the metallic zinc used as the sacrificial anode material, the developmental coatings can be applied by use of ordinary paint sprayers. A coating material of the type under development is formulated as a liquid containing blended metallic particles and/or moisture-attracting compounds. The liquid mixture is sprayed onto a concrete structure. Experiments have shown that even though such a coat resides on the exterior surface, it generates a protective galvanic current that flows to the interior reinforcing steel members. By effectively transferring the corrosion process from the steel reinforcement to the exterior coating, the protective current slows or stops corrosion of the embedded steel. Specific formulations have been found to meet depolarization criteria of the National Association of Corrosion Engineers (NACE) for complete protection of steel reinforcing bars ("rebar") embedded in concrete.

Solar Selective Coatings Prepared From Thin-Film Molecular Mixtures and Evaluated

NASA Technical Reports Server (NTRS)

Jaworske, Don A.

2003-01-01

Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling molecular mixing during ion-beam sputter deposition, researchers can tailor the solar selective coatings to have the combined properties of high solar absorptance and low infrared emittance. On orbit, these combined properties simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. The solar selective coatings are envisioned for use on minisatellites, for applications where solar energy is used to power heat engines or to heat remote regions in the interior of the spacecraft. Such systems may be useful for various missions, particularly those to middle Earth orbit. Sunlight must be concentrated by a factor of 100 or more to achieve the desired heat inlet operating temperature. At lower concentration factors, the temperature of the heat inlet surface of the heat engine is too low for efficient operation, and at high concentration factors, cavity type heat receivers become attractive. The an artist's concept of a heat engine, with the annular heat absorbing surface near the focus of the concentrator coated with a solar selective coating is shown. In this artist's concept, the heat absorbing surface powers a small Stirling convertor. The astronaut's gloved hand is provided for scale. Several thin-film molecular mixtures have been prepared and evaluated to date, including mixtures of aluminum and aluminum oxide, nickel and aluminum oxide, titanium and aluminum oxide, and platinum and aluminum oxide. For example, a 2400- Angstrom thick mixture of titanium and aluminum oxide was found to have a solar absorptance of 0.93 and an infrared emittance of 0.06. On the basis of tests performed under flowing nitrogen at temperatures as high as 680 C, the coating appeared to be durable at elevated temperatures. Additional durability testing is planned, including exposure to atomic oxygen, vacuum ultraviolet radiation, and high-energy electrons.

Cold cathode vacuum discharge tube

DOEpatents

Boettcher, Gordon E.

1998-01-01

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

Evaluation of interior and exterior latex paints : final report.

DOT National Transportation Integrated Search

1979-10-01

The wood panels that have only one coat of paint over bare wood and one coat of paint over primed wood are continuing to show sighs of deterioration. The wood panels that have two coats of paint over bare wood and two coats of paint over primed wood ...

New Life for Miss Liberty

NASA Technical Reports Server (NTRS)

1985-01-01

Corrosion protection for the Statue of Liberty's interior structure is provided by a coating called IC 531, manufactured by Inorganic Coatings, Inc. The coating was developed by Goddard to protect structures at KSC. Inorganic Coatings has an exclusive to this high ratio potassium silicate formula. The coating is water based, nontoxic, nonflammable, and bonds to steel in 30 minutes. Tests on a variety of coated structures have been very positive.

Safer Pleasure Boats

NASA Technical Reports Server (NTRS)

1976-01-01

'Flamarest' coating developed by Avco Corporation for NASA to protect fuel lines and tanks is sprayed on the interior of polyester boat hull in commercial application. About 30 mils of the coating prevented structural damage to hull during test in which a 13 minute interior gasoline fire was started. An unprotected hull would begin to burn in 30 seconds. Same material applied as tape to wrap fuel lines effectively insulates hose when charred while also reducing spread of flame.

Design of barrier coatings on kink-resistant peripheral nerve conduits

PubMed Central

Clements, Basak Acan; Bushman, Jared; Murthy, N Sanjeeva; Ezra, Mindy; Pastore, Christopher M; Kohn, Joachim

2016-01-01

Here, we report on the design of braided peripheral nerve conduits with barrier coatings. Braiding of extruded polymer fibers generates nerve conduits with excellent mechanical properties, high flexibility, and significant kink-resistance. However, braiding also results in variable levels of porosity in the conduit wall, which can lead to the infiltration of fibrous tissue into the interior of the conduit. This problem can be controlled by the application of secondary barrier coatings. Using a critical size defect in a rat sciatic nerve model, the importance of controlling the porosity of the nerve conduit walls was explored. Braided conduits without barrier coatings allowed cellular infiltration that limited nerve recovery. Several types of secondary barrier coatings were tested in animal studies, including (1) electrospinning a layer of polymer fibers onto the surface of the conduit and (2) coating the conduit with a cross-linked hyaluronic acid-based hydrogel. Sixteen weeks after implantation, hyaluronic acid-coated conduits had higher axonal density, displayed higher muscle weight, and better electrophysiological signal recovery than uncoated conduits or conduits having an electrospun layer of polymer fibers. This study indicates that braiding is a promising method of fabrication to improve the mechanical properties of peripheral nerve conduits and demonstrates the need to control the porosity of the conduit wall to optimize functional nerve recovery. PMID:26977288

The Fate and Effects of Crude Oil Spilled on Subarctic Permafrost Terrain in Interior Alaska,

DTIC Science & Technology

1980-12-01

and Poker Creek, al soils are acidic , generally about pH 4 (Troth et guarding against inadvertent oil (ontamination al 1975, Riegeretal 1972) I2 - IV...of root mediately adjacent to surface oil. Deciduous nutrient uptake, 2) coating of the roots by a leaves turned brown and abscised before ever...Although spruce in the upper 2 m of the winter foliage became chlorotic, turned brown, and spill began dropping needles by mid-June, the abscised

Cold cathode vacuum discharge tube

DOEpatents

Boettcher, G.E.

1998-03-10

A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

Cold cathode vacuum discharge tube

DOEpatents

Boettcher, G.E.

1998-04-14

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

Sensory and Emotional Perception of Wooden Surfaces through Fingertip Touch

PubMed Central

Bhatta, Shiv R.; Tiippana, Kaisa; Vahtikari, Katja; Hughes, Mark; Kyttä, Marketta

2017-01-01

Previous studies on tactile experiences have investigated a wide range of material surfaces across various skin sites of the human body in self-touch or other touch modes. Here, we investigate whether the sensory and emotional aspects of touch are related when evaluating wooden surfaces using fingertips in the absence of other sensory modalities. Twenty participants evaluated eight different pine and oak wood surfaces, using sensory and emotional touch descriptors, through the lateral motion of active fingertip exploration. The data showed that natural and smooth wood surfaces were perceived more positively in emotional touch than coated surfaces. We highlight the importance of preserving the naturalness of the surface texture in the process of wood-surface treatment so as to improve positive touch experiences, as well as avoid negative ones. We argue that the results may offer possibilities in the design of wood-based interior products with a view to improving consumer touch experiences. PMID:28348541

Selecting the swimming mechanisms of colloidal particles: bubble propulsion versus self-diffusiophoresis.

PubMed

Wang, Sijia; Wu, Ning

2014-04-01

Bubble propulsion and self-diffusiophoresis are two common mechanisms that can drive autonomous motion of microparticles in hydrogen peroxide. Although microtubular particles, when coated with platinum in their interior concave surfaces, can propel due to the formation and release of bubbles from one end, the convex Janus particles usually do not generate any visible bubble. They move primarily due to the self-diffusiophoresis. Coincidentally, the platinum films on those particles were typically coated by physical evaporation. In this paper, we use a simple chemical deposition method to make platinum-polystyrene Janus dimers. Surprisingly, those particles are propelled by periodic growth and collapse of bubbles on the platinum-coated lobes. We find that both high catalytic activity and rough surface are necessary to change the propulsion mode from self-diffusiophoresis to bubble propulsion. Our Janus dimers, with combined geometric and interfacial anisotropy, also exhibit distinctive motions at the respective stages of bubble growth and collapse, which differ by 5-6 orders of magnitude in time. Our study not only provides insight into the link between self-diffusiophoresis and bubble propulsion but also reveals the intriguing impacts of the combined geometric and interfacial anisotropy on self-propulsion of particles.

Method for making a microporous membrane

NASA Technical Reports Server (NTRS)

Gavalas, Lillian Susan (Inventor)

2013-01-01

A method for making a microporous membrane comprises the steps of: providing a plurality of carbon nanotubes having a hollow interior diameter of 20 Angstroms or less; sonicating the plurality of carbon nanotubes utilizing a solution comprising deionized, distilled water and a surfactant that coats at least one of the plurality of carbon nanotubes; collecting the coated carbon nanotubes; forming a matrix that supports the plurality of carbon nanotubes; embedding the coated carbon nanotubes into the matrix; rinsing the coated nanotubes to remove at least a portion of the surfactant; curing the nanotube-matrix assembly; and cutting the nanotube-matrix assembly to a particular thickness so as to open the ends of the embedded nanotubes. The hollow interiors of the plurality of embedded carbon nanotubes comprise the pores of the microporous membrane.

Inverse design of a proper number, shapes, sizes, and locations of coolant flow passages

NASA Technical Reports Server (NTRS)

Dulikravich, George S.

1992-01-01

During the past several years we have developed an inverse method that allows a thermal cooling system designer to determine proper sizes, shapes, and locations of coolant passages (holes) in, say, an internally cooled turbine blade, a scram jet strut, a rocket chamber wall, etc. Using this method the designer can enforce a desired heat flux distribution on the hot outer surface of the object, while simultaneously enforcing desired temperature distributions on the same hot outer surface as well as on the cooled interior surfaces of each of the coolant passages. This constitutes an over-specified problem which is solved by allowing the number, sizes, locations and shapes of the holes to adjust iteratively until the final internally cooled configuration satisfies the over-specified surface thermal conditions and the governing equation for the steady temperature field. The problem is solved by minimizing an error function expressing the difference between the specified and the computed hot surface heat fluxes. The temperature field analysis was performed using our highly accurate boundary integral element code with linearly varying temperature along straight surface panels. Examples of the inverse design applied to internally cooled turbine blades and scram jet struts (coated and non-coated) having circular and non-circular coolant flow passages will be shown.

Elucidation of bacteria found in car interiors and strategies to reduce the presence of potential pathogens.

PubMed

Stephenson, Rachel E; Gutierrez, Daniel; Peters, Cindy; Nichols, Mark; Boles, Blaise R

2014-01-01

The human microbiome is influenced by a number of factors, including environmental exposure to microbes. Because many humans spend a large amount of time in built environments, it can be expected that the microbial ecology of these environments will influence the human microbiome. In an attempt to further understand the microbial ecology of built environments, the microbiota of car interiors was analyzed using culture dependent and culture independent methods. While it was found that the number and type of bacteria varied widely among the cars and sites tested, Staphylococcus and Propionibacterium were nearly always the dominant genera found at the locations sampled. Because Staphylococcus is of particular concern to human health, the characteristics of this genus found in car interiors were investigated. Staphylococcus epidermidis, S. aureus, and S. warnerii were the most prevalent staphylococcal species found, and 22.6% of S. aureus strains isolated from shared community vehicles were resistant to methicillin. The reduction in the prevalence of pathogenic bacteria in cars by using silver-based antimicrobial surface coatings was also evaluated. Coatings containing 5% silver ion additives were applied to steering wheels, placed in cars for five months and were found to eliminate the presence of culturable pathogenic bacteria recovered from these sites relative to controls. Together, these results provide new insight into the microbiota found in an important built environment, the automobile, and potential strategies for controlling the presence of human pathogens.

Elucidation of bacteria found in car interiors and strategies to reduce the presence of potential pathogens

PubMed Central

Stephenson, Rachel E.; Gutierrez, Daniel; Peters, Cindy; Nichols, Mark; Boles, Blaise R.

2014-01-01

The human microbiome is influenced by a number of factors, including environmental exposure to microbes. Because many humans spend a large amount of time in built environments, it can be expected that the microbial ecology of these environments will influence the human microbiome. In an attempt to further understand the microbial ecology of built environments, the microbiota of car interiors was analyzed using culture dependent and culture independent methods. While it was found that the number and type of bacteria varied widely among the cars and sites tested, Staphylococcus and Propionibacterium were nearly always the dominant genera found at the locations sampled. Because Staphylococcus is of particular concern to human health, the characteristics of this genus found in car interiors were investigated. Staphylococcus epidermidis, S. aureus, and S. warnerii were the most prevalent staphylococcal species found, and 22.6% of S. aureus strains isolated from shared community vehicles were resistant to methicillin. The reduction in the prevalence of pathogenic bacteria in cars by using silver-based antimicrobial surface coatings was also evaluated. Coatings containing 5% silver ion additives were applied to steering wheels, placed in cars for five months and were found to eliminate the presence of culturable pathogenic bacteria recovered from these sites relative to controls. Together, these results provide new insight into the microbiota found in an important built environment, the automobile, and potential strategies for controlling the presence of human pathogens. PMID:24564823

Water alteration of rocks and soils on Mars at the Spirit rover site in Gusev crater

USGS Publications Warehouse

Haskin, L.A.; Wang, A.; Jolliff, B.L.; McSween, H.Y.; Clark, B. C.; Des Marais, D.J.; McLennan, S.M.; Tosca, N.J.; Hurowitz, J.A.; Farmer, J.D.; Yen, A.; Squyres, S. W.; Arvidson, R. E.; Klingelhofer, G.; Schroder, C.; De Souza, P.A.; Ming, D. W.; Gellert, Ralf; Zipfel, J.; Brückner, J.; Bell, J.F.; Herkenhoff, K.; Christensen, P.R.; Ruff, S.; Blaney, D.; Gorevan, S.; Cabrol, N.A.; Crumpler, L.; Grant, J.; Soderblom, L.

2005-01-01

Gusev crater was selected as the landing site for the Spirit rover because of the possibility that it once held a lake. Thus one of the rover's tasks was to search for evidence of lake sediments. However, the plains at the landing site were found to be covered by a regolith composed of olivine-rich basaltic rock and wind-blown 'global' dust. The analyses of three rock interiors exposed by the rock abrasion tool showed that they are similar to one another, consistent with having originated from a common lava flow. Here we report the investigation of soils, rock coatings and rock interiors by the Spirit rover from sol (martian day) 1 to sol 156, from its landing site to the base of the Columbia hills. The physical and chemical characteristics of the materials analysed provide evidence for limited but unequivocal interaction between water and the volcanic rocks of the Gusev plains. This evidence includes the softness of rock interiors that contain anomalously high concentrations of sulphur, chlorine and bromine relative to terrestrial basalts and martian meteorites; sulphur, chlorine and ferric iron enrichments in multilayer coatings on the light-toned rock Mazatzal; high bromine concentration in filled vugs and veins within the plains basalts; positive correlations between magnesium, sulphur and other salt components in trench soils; and decoupling of sulphur, chlorine and bromine concentrations in trench soils compared to Gusev surface soils, indicating chemical mobility and separation.

Field-to-laboratory analysis of clay wall coatings as passive removal materials for ozone in buildings.

PubMed

Darling, E; Corsi, R L

2017-05-01

Ozone reacts readily with many indoor materials, as well as with compounds in indoor air. These reactions lead to lower indoor than outdoor ozone concentrations when outdoor air is the major contributor to indoor ozone. However, the products of indoor ozone reactions may be irritating or harmful to building occupants. While active technologies exist to reduce indoor ozone concentrations (i.e, in-duct filtration using activated carbon), they can be cost-prohibitive for some and/or infeasible for dwellings that do not have heating, ventilating, and air-conditioning systems. In this study, the potential for passive reduction of indoor ozone by two different clay-based interior surface coatings was explored. These coatings were exposed to occupied residential indoor environments and tested bimonthly in environmental chambers for quantification of ozone reaction probabilities and reaction product emission rates over a 6-month period. Results indicate that clay-based coatings may be effective as passive removal materials, with relatively low by-product emission rates that decay rapidly within 2 months. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Bisphenol diglycidyl ethers and bisphenol A and their hydrolysis in drinking water.

PubMed

Lane, R F; Adams, C D; Randtke, S J; Carter, R E

2015-04-01

Epoxy coatings are commonly used to protect the interior (and exterior) surfaces of water mains and storage tanks and can be used on the interior surfaces of water pipes in homes, hospitals, hotels, and other buildings. Common major components of epoxies include bisphenols, such as bisphenol A (BPA) or bisphenol F (BPF), and their reactive prepolymers, bisphenol A diglycidyl ether (BADGE) and bisphenol F diglycidyl ether (BFDGE), respectively. There currently are health concerns about the safety of BPA and BPF due to known estrogenic effects. Determination of key bisphenol leachates, development of a hydrolysis model, and identification of stable hydrolysis products will aid in assessment of human bisphenol exposure through ingestion of drinking water. Liquid chromatography/mass spectrometry (LC/MS/MS) was used for quantitation of key analytes, and a pseudo-first order kinetic approach was used for modeling. In fill-and-dump studies on epoxy-coated pipe specimens, BADGE and a BPA-like compound were identified as leachates. The BADGE hydrolysis model predicts BADGE half-lives at pH 7 and 15, 25, 35, and 40 °C to be 11, 4.6, 2.0, and 1.4 days respectively; the BFDGE half-life was 5 days at pH 7 and 25 °C. The two identified BADGE hydrolysis products are BADGE-H2O and BADGE 2H2O, with BADGE 2H2O being the final end product under the conditions studied. Copyright © 2015 Elsevier Ltd. All rights reserved.

Applying a tapered electrode on a porous ceramic support tube by masking a band inside the tube and drawing in electrode material from the outside of the tube by suction

DOEpatents

Vasilow, Theodore R.; Zymboly, Gregory E.

1991-01-01

An electrode is deposited on a support by providing a porous ceramic support tube (10) having an open end (14) and closed end (16); masking at least one circumferential interior band (18 and 18') inside the tube; evacuating air from the tube by an evacuation system (30), to provide a permeability gradient between the masked part (18 and 18') and unmasked part (20) of the tube; applying a liquid dispersion of solid electrode particles to the outside surface of the support tube, where liquid flows through the wall, forming a uniform coating (42) over the unmasked support part (20) and a tapered coating over the masked part (18 and 18').

Atomic Layer Deposition for Coating of High Aspect Ratio TiO2 Nanotube Layers

PubMed Central

2016-01-01

We present an optimized approach for the deposition of Al2O3 (as a model secondary material) coating into high aspect ratio (≈180) anodic TiO2 nanotube layers using the atomic layer deposition (ALD) process. In order to study the influence of the diffusion of the Al2O3 precursors on the resulting coating thickness, ALD processes with different exposure times (i.e., 0.5, 2, 5, and 10 s) of the trimethylaluminum (TMA) precursor were performed. Uniform coating of the nanotube interiors was achieved with longer exposure times (5 and 10 s), as verified by detailed scanning electron microscopy analysis. Quartz crystal microbalance measurements were used to monitor the deposition process and its particular features due to the tube diameter gradient. Finally, theoretical calculations were performed to calculate the minimum precursor exposure time to attain uniform coating. Theoretical values on the diffusion regime matched with the experimental results and helped to obtain valuable information for further optimization of ALD coating processes. The presented approach provides a straightforward solution toward the development of many novel devices, based on a high surface area interface between TiO2 nanotubes and a secondary material (such as Al2O3). PMID:27643411

40 CFR 63.4081 - Am I subject to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... appliance parts and products; (2) Preparation of a coating for application (e.g., mixing in thinners and..., spray guns or dip tanks; (4) Application of porcelain enamel, powder coating, and asphalt interior...) Cleaning of equipment used in coating operations (e.g., application equipment, hangers, racks); (7) Storage...

Effects of Ambient High Temperature Exposure on Alumina-Titania High Emittance Surfaces for Solar Dynamic Systems

NASA Technical Reports Server (NTRS)

deGroh, Kim K.; Smith, Daniela C.; Wheeler, Donald R.; MacLachlam, Brian J.

1998-01-01

Solar dynamic (SD) space power systems require durable, high emittance surfaces on a number of critical components, such as heat receiver interior surfaces and parasitic load radiator (PLR) elements. To enhance surface characteristics, an alumina-titania coating has been applied to 500 heat receiver thermal energy containment canisters and the PLR of NASA Lewis Research Center's (LeRC) 2 kW SD ground test demonstrator (GTD). The alumina-titania coating was chosen because it had been found to maintain its high emittance under vacuum (less than or equal to 10(exp -6) torr) at high temperatures (1457 F (827 C)) for an extended period (approximately 2,700 hours). However, preflight verification of SD systems components, such as the PLR require operation at ambient pressure and high temperatures. Therefore, the purpose of this research was to evaluate the durability of the alumina-titania coating at high temperature in air. Fifteen of sixteen alumina-titania coated Incoloy samples were exposed to high temperatures (600 F (316 C) to l500 F (816 C)) for various durations (2 to 32 hours). Samples, were characterized prior to and after heat treatment for reflectance, solar absorptance, room temperature emittance and emittance at 1,200 F (649 C). Samples were also examined to detect physical defects and to determine surface chemistry using optical microscopy, scanning electron microscopy operated with an energy dispersive spectroscopy (EDS) system, and x ray photoelectron spectroscopy (XPS). Visual examination of the heat-treated samples showed a whitening of samples exposed to temperatures of 1,000 F (538 C) and above. Correspondingly, the optical properties of these samples had degraded. A sample exposed to 1,500 F (816 C) for 24 hours had whitened and the thermal emittance at 1,200 F (649 C) had decreased from the non-heat treated value of 0.94 to 0.62. The coating on this sample had become embrittled with spalling off the substrate noticeable at several locations. Based on this research it is recommended that preflight testing of SD components with alumina-titania coatings be restricted to temperatures no greater than 600 F (316 C) in air to avoid optical degradation. Moreover, components with the alumina-titania coating are likely to experience optical property degradation with direct atomic oxygen exposure in space.

Morphogenesis of mimivirus and its viral factories: an atomic force microscopy study of infected cells.

PubMed

Kuznetsov, Yuri G; Klose, Thomas; Rossmann, Michael; McPherson, Alexander

2013-10-01

Amoebas infected with mimivirus were disrupted at sequential stages of virus production and were visualized by atomic force microscopy. The development of virus factories proceeded over 3 to 4 h postinfection and resulted from the coalescence of 0.5- to 2-μm vesicles, possibly bearing nucleic acid, derived from either the nuclear membrane or the closely associated rough endoplasmic reticulum. Virus factories actively producing virus capsids on their surfaces were imaged, and this allowed the morphogenesis of the capsids to be delineated. The first feature to appear on a virus factory surface when a new capsid is born is the center of a stargate, which is a pentameric protein oligomer. As the arms of the stargate grow from the pentamer, a rough disk the diameter of a capsid thickens around it. This marks the initial emergence of a protein-coated membrane vesicle. The capsid self-assembles on the vesicle. Hillocks capped by different pentameric proteins spontaneously appear on the emerging vesicle at positions that are ultimately occupied by 5-fold icosahedral vertices. A lattice of coat protein nucleates at each of the 5-fold vertices, but not at the stargate, and then spreads outward from the vertices over the surface, merging seamlessly to complete the icosahedral capsid. Filling with DNA and associated proteins occurs by the transfer of nucleic acid from the interior of the virus factory into the nearly completed capsids. The portal, through which the DNA enters, is sealed by a plug of protein having a diameter of about 40 nm. A layer of integument protein that anchors the surface fibers is acquired by the passage of capsids through a membrane enriched in the protein. The coating of surface fibers is similarly acquired when the integument protein-coated capsids pass through a second membrane that has a forest of surface fibers embedded on one side.

Morphogenesis of Mimivirus and Its Viral Factories: an Atomic Force Microscopy Study of Infected Cells

PubMed Central

Kuznetsov, Yuri G.; Klose, Thomas; Rossmann, Michael

2013-01-01

Amoebas infected with mimivirus were disrupted at sequential stages of virus production and were visualized by atomic force microscopy. The development of virus factories proceeded over 3 to 4 h postinfection and resulted from the coalescence of 0.5- to 2-μm vesicles, possibly bearing nucleic acid, derived from either the nuclear membrane or the closely associated rough endoplasmic reticulum. Virus factories actively producing virus capsids on their surfaces were imaged, and this allowed the morphogenesis of the capsids to be delineated. The first feature to appear on a virus factory surface when a new capsid is born is the center of a stargate, which is a pentameric protein oligomer. As the arms of the stargate grow from the pentamer, a rough disk the diameter of a capsid thickens around it. This marks the initial emergence of a protein-coated membrane vesicle. The capsid self-assembles on the vesicle. Hillocks capped by different pentameric proteins spontaneously appear on the emerging vesicle at positions that are ultimately occupied by 5-fold icosahedral vertices. A lattice of coat protein nucleates at each of the 5-fold vertices, but not at the stargate, and then spreads outward from the vertices over the surface, merging seamlessly to complete the icosahedral capsid. Filling with DNA and associated proteins occurs by the transfer of nucleic acid from the interior of the virus factory into the nearly completed capsids. The portal, through which the DNA enters, is sealed by a plug of protein having a diameter of about 40 nm. A layer of integument protein that anchors the surface fibers is acquired by the passage of capsids through a membrane enriched in the protein. The coating of surface fibers is similarly acquired when the integument protein-coated capsids pass through a second membrane that has a forest of surface fibers embedded on one side. PMID:23926353

Closet in room #17, bunkhouse, second floor interior. Originally a ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Closet in room #17, bunkhouse, second floor interior. Originally a shelf and coat hooks, this was modified with a drawer and door, enclosing the open closet. - Sespe Ranch, Bunkhouse, 2896 Telegraph Road, Fillmore, Ventura County, CA

Scatter Measurements Made With Ultraviolet Light

NASA Astrophysics Data System (ADS)

Anthon, Erik W.

1985-09-01

The quality of optical surfaces is generally evaluated by how much light (normally visible light) is scattered by the surface. Most optical glasses and many coating materials are completely opaque to ultraviolet light (253.7 nm). Ultraviolet light tends to scatter much more than visible light. Scatter measurements made with ultraviolet light are therefore very sensitive and the scatter from second surfaces and from the interior (bulk) of the optical material is eliminated by the opacity. A novel scattermeter that operates with ultraviolet light has been developed. The construction and operation of this scattermeter will be described. Cleaning soon becomes the limiting factor when measuring the surfaces with very low level of scatter. Sensitivity to repeated cleaning has been investigated. Different surfaces are compared and uniformity of surfaces is measured by mapping a surface area with an x-y stage. Polished glass surfaces generally have much higher scatter than natural glass surfaces (fire polished, drawn or floated surfaces). Very low scatter levels have been found on thin drawn glass.

Analysis of the EM scattering from arbitrary open-ended waveguide cavities using axial Gaussian Beam tracking

NASA Technical Reports Server (NTRS)

Burkholder, R. J.; Pathak, P. H.

1988-01-01

The electromagnetic (EM) scattering from a planar termination located inside relatively arbitrarily shaped open-ended waveguide cavities with smoothly curved interior walls is analyzed using a Gaussian Beam (GB) expansion of the incident plane wave fields in the open end. The cavities under consideration may contain perfectly-conducting interior walls with or without a thin layer of material coating, or the walls may be characterized by an impedance boundary condition. In the present approach, the GB's are tracked only to the termination of the waveguide cavity via beam reflections from interior waveguide cavity walls. The Gaussian beams are tracked approximately only along their beam axes; this approximation which remains valid for relatively well focussed beams assumes that an incident GB gives rise to a reflected GB with parameters related to the incident beam and the radius of curvature of the wall. It is found that this approximation breaks down for GB's which come close to grazing a convex surface and when the width of the incident beam is comparable to the radius of curvature of the surface. The expansion of the fields at the open end depend on the incidence angle only through the expansion coefficients, so the GB's need to be tracked through the waveguide cavity only once for a wide range of incidence angles. At the termination, the sum of all the GB's are integrated using a result developed from a generalized reciprocity principle, to give the fields scattered from the interior of the cavity. The rim edge at the open end of the cavity is assumed to be sharp and the external scattering from the rim is added separately using Geometrical Theory of Diffraction. The results based on the present approach are compared with solutions based on the hybrid asymptotic modal method. The agreement is found to be very good for cavities made up of planar surfaces, and also for cavities with curved surfaces which are not too long with respect to their width.

Ion beam methods applied to interior ballistic studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niler, A.

1981-04-01

High temperature, pressure and velocity gases produced during the interior ballistic cycle of a gun firing are responsible for considerable damage to the steel surfaces of a gun bore. This damage is studied by exposing steel samples to the erosive flows of burning propellant gases in a modified 37mm gun chamber where pressures of 200 MPa and flame temperatures of 3000/sup 0/K are typical. Ion beam methods are used to characterize the composition of the steel surfaces by combined nuclear reaction (NR) and elastic backscattering (EBS) analysis and thin layer activation (TLA) is used to measure surface wear rates. Combinedmore » fits to the EBS and NR distributions yield concentrations and depth profiles of carbon, nitrogen and oxygen as well as iron and other heavier elements. Hydrogen concentrations have also been measured on some of the samples. The results of these experiments show the presence of two different erosion mechanisms. In one, the surface is softened by thermo-chemical processes prior to removal by the shear forces of the gas flow while in the other surface layer melting occurs prior to removal. TLA using the /sup 56/Fe(p,n)/sup 56/Co reaction has been used to measure wear from a 20 mm barrel and is being instrumented for larger barrels. EBS is being used to characterize the interfaces between steel substrates and coatings designed to reduce erosion.« less

77 FR 14564 - Information Collection Request Sent to the Office of Management and Budget (OMB) for Approval...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-12

...; Approval Procedures for Nontoxic Shot and Shot Coatings AGENCY: Fish and Wildlife Service, Interior. ACTION... Number: 1018-0067. Title: Approval Procedures for Nontoxic Shot and Shot Coatings, 50 CFR 20.134. Service... Respondents: Businesses that produce and/or market approved nontoxic shot types or nontoxic shot coatings...

Conformal Coating Strategy Comprising N-doped Carbon and Conventional Graphene for Achieving Ultrahigh Power and Cyclability of LiFePO4.

PubMed

Zhang, Kan; Lee, Jeong-Taik; Li, Ping; Kang, Byoungwoo; Kim, Jung Hyun; Yi, Gi-Ra; Park, Jong Hyeok

2015-10-14

Surface carbon coating to improve the inherent poor electrical conductivity of lithium iron phosphate (LiFePO4, LFP) has been considered as most efficient strategy. Here, we also report one of the conventional methods for LFP but exhibiting a specific capacity beyond the theoretical value, ultrahigh rate performance, and excellent long-term cyclability: the specific capacity is 171.9 mAh/g (70 μm-thick electrode with ∼10 mg/cm(2) loading mass) at 0.1 C (17 mA/g) and retains 143.7 mAh/g at 10 C (1.7 A/g) and 95.8% of initial capacity at 10 C after 1000 cycles. It was found that the interior conformal N-C coating enhances the intrinsic conductivity of LFP nanorods (LFP NR) and the exterior reduced graphene oxide coating acts as an electrically conducting secondary network to electrically connect the entire electrode. The great electron transport mutually promoted with shorten Li diffusion length on (010) facet exposed LFP NR represents the highest specific capacity value recorded to date at 10 C and ultralong-term cyclability. This conformal carbon coating approach can be a promising strategy for the commercialization of LFP cathode in lithium ion batteries.

Stair and entry room, bunkhouse, first floor interior. Door from ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Stair and entry room, bunkhouse, first floor interior. Door from entry hall leads to toilets and bathing rooms. A coat and hat rack is on each side of the door. - Sespe Ranch, Bunkhouse, 2896 Telegraph Road, Fillmore, Ventura County, CA

Characterization of large-pore polymeric supports for use in perfusion biochromatography.

PubMed

Whitney, D; McCoy, M; Gordon, N; Afeyan, N

1998-05-22

Perfusion chromatography is uniquely characterized by the flow of a portion of the column eluent directly through the resin in the packed bed. The benefits of this phenomenon and some of the properties of perfusive resins have been described before, and can be summarized as enhanced mass transport to interior binding sites. Here we extend the understanding of this phenomenon by comparing resins with different pore size distributions. Resins are chosen to give approximately the same specific pore volumes (as shown in the characterization section) but the varying contribution of large pores is used to control the amount of liquid flowing through the beads. POROS R1 has the largest contribution of throughpores, and therefore the greatest intraparticle flow. POROS R2 has a lower contribution of throughpores, and a higher surface area coming from a greater population of diffusive pores, but still shows significant mass transport enhancements relative to a purely diffusive control. Oligo R3 is dominated by a high population of diffusive pores, and is used comparatively as a non-perfusive resin. Although the pore size distribution can be engineered to control mass transport rates, the resulting surface area is not the only means by which binding capacity can be controlled. Surface coatings are employed to increase binding capacity without fundamentally altering the mass transport properties. Models are used to describe the amount of flow transecting the beads, and comparisons of coated resins to uncoated (polystyrene) resins leads to the conclusion that these coatings do not obstruct the throughpore structures. This is an important conclusion since the binding capacity of the coated product, in some cases, is shown to be over 10-fold higher than the precursor polystyrene scaffold (i.e., POROS R1 or POROS R2).

Thermal performance of a Concrete Cool Roof under different climatic conditions of Mexico

DOE PAGES

Hernández-Pérez, I.; Álvarez, G.; Gilbert, H.; ...

2014-11-27

A cool roof is an ordinary roof with a reflective coating on the exterior surface which has a high solar reflectance and high thermal emittance. These properties let the roof keep a lower temperature than a standard roof under the same conditions. In this work, the thermal performance of a concrete roof with and without insulation and with two colors has been analyzed using the finite volume method. The boundary conditions of the external roof surface were taken from hourly averaged climatic data of four cities. For the internal surface, it is considered that the building is air-conditioned and themore » inside air has a constant temperature. The interior surface temperature and the heat flux rates into the roofs were obtained for two consecutive days in order to assess the benefits of a cool roofs in different climates.« less

Dry Sintered Metal Coating of Halloysite Nanotubes

DOE PAGES

Nicholson, James C.; Weisman, Jeffery A.; Boyer, Christen J.; ...

2016-09-19

Halloysite nanotubes (HNTs) are a naturally-occurring aluminosilicate whose dimensions measure microns in length and tens of nanometers in diameter. Bonding defects between the alumina and silica lead to net negative and positive charges on the exterior and interior lumen, respectively. HNTs have been shown to enhance the material properties of polymer matrices and enable the sustained release of loaded chemicals, drugs, and growth factors. Due to the net charges, these nanotubes can also be readily coated in layered-depositions using the HNT exterior lumen’s net negative charge as the basis for assembly. These coatings are primarily done through wet chemical processes,more » the majority of which are limited in their use of desired chemicals, due to the polarity of the halloysite. Furthermore, this restriction in the type of chemicals used often requires the use of more toxic chemicals in place of greener options, and typically necessitates the use of a significantly longer chemical process to achieve the desired coating. In this study, we show that HNTs can be coated with metal acetylacetonates—compounds primarily employed in the synthesis of nanoparticles, as metal catalysts, and as NMR shift reagents—through a dry sintering process. This method was capable of thermally decaying the metal acetylacetonate, resulting in a free positively-charged metal ion that readily bonded to the negatively-charged HNT exterior, resulting in metallic coatings forming on the HNT surface. Our coating method may enable greater deposition of coated material onto these nanotubes as required for a desired application. Moreover, the use of chemical processes using toxic chemicals is not required, thus eliminating exposure« less

Adhesive coated electrical apparatus having sublimable protective covering and an assembly method

DOEpatents

Wootton, Roy E.

1982-01-01

Electrical apparatus including an enclosure, an electrode disposed within the enclosure, and supports for insulatably supporting the electrode within the enclosure has a permanently sticky adhesive material which is disposed on the interior surface of the outer enclosure. A high-vapor-pressure sublimable material is disposed on the permanently sticky adhesive material, with the sublimable material capable of subliming away in the presence of a vacuum. The presence of the sublimable material enables the apparatus to be non-sticky during assembly and handling operations, while being rendered sticky upon commissioning of the apparatus.

Modeling of gun barrel surface erosion: Historic perspective

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buckingham, A.C.

1996-08-01

Results and interpretations of numerical simulations of some dominant processes influencing gun barrel propellant combustion and flow-induced erosion are presented. Results include modeled influences of erosion reduction techniques such as solid additives, vapor phase chemical modifications, and alteration of surface solid composition through use of thin coatings. Precedents and historical perspective are provided with predictions from traditional interior ballistics compared to computer simulations. Accelerating reactive combustion flow, multiphase and multicomponent transport, flow-to-surface thermal/momentum/phase change/gas-surface chemical exchanges, surface and micro-depth subsurface heating/stress/composition evolution and their roles in inducing surface cracking, spall, ablation, melting, and vaporization are considered. Recognition is given tomore » cyclic effects of previous firing history on material preconditioning. Current perspective and outlook for future are based on results of a US Army-LLNL erosion research program covering 7 y in late 1970s. This is supplemented by more recent research on hypervelocity electromagnetic projectile launchers.« less

The application of bioactive compounds from the food industry to control mold growth in indoor waterborne coatings.

PubMed

Bellotti, N; Salvatore, L; Deyá, C; Del Panno, M T; del Amo, B; Romagnoli, R

2013-04-01

Microbial growth in indoor environments creates health problems, especially in people with asthma; approximately 80% of these patients are allergic to mold. Antimicrobial coatings are formulated to generate surfaces that are easy to clean and may also incorporate active agents, commonly called biocides, which inhibit microbial colonization, subsequent growth and bio-deterioration of the substrates. Some research lines seek to replace traditional organometallic and organochlorines biocides with environmentally acceptable ones. The aim of this research was, primarily, to explore the possible application of different compounds used in food industry like preservatives to be used as antimicrobial additives for antimicrobial coatings. Four biocides were tested against two different ambient molds isolated from an interior painted wall (Chaetomium globosum and Alternaria alternate). The selected biocides were zinc salicylate, zinc benzoate, calcium benzoate and potassium sorbate. The resulting paints were subjected to biological and physical tests (viscosity, hiding power, humidity absorption and biocides leaching rate). Bioassays revealed that zinc benzoate and zinc salicylate resulted active against both fungi. Copyright © 2012 Elsevier B.V. All rights reserved.

MOLDS FOR CASTING PLUTONIUM

DOEpatents

Anderson, J.W.; Miley, F.; Pritchard, W.C.

1962-02-27

A coated mold for casting plutonium comprises a mold base portion of a material which remains solid and stable at temperatures as high as the pouring temperature of the metal to be cast and having a thin coating of the order of 0.005 inch thick on the interior thereof. The coating is composed of finely divided calcium fluoride having a particle size of about 149 microns. (AEC)

Optimum Design Parameters of Box Window DSF Office at Different Glazing Types under Sub Interval of Intermediate Sky Conditions (20-40 klux)

NASA Astrophysics Data System (ADS)

Elayeb, O. K.; Alghoul, M. A.; Sopian, K.; Khrita, N. G.

2017-11-01

Despite Double skin façade (DSF) buildings are widely deployed worldwide, daylighting strategy is not commonly incorporated in these buildings compare to other strategies. Therefore, further theoretical and experimental studies would lead to adopting daylighting strategy in DSF office buildings. The aim of this study is to investigate the daylighting performance of office building at different design parameters of box window DSF using different glazing types under sub interval of intermediate sky conditions (20-40) klux using the (IES VE) simulation tool from Integrated Environmental Solutions - Virtual Environment. The implemented design parameters are window wall ratio (WWR) of internal façade (10-100) %, cavity depth (CD) of DSF (1-2.5) m and different glazing types. The glazing types were selected from the list available in the (IES VE) simulation tool. After series of evaluations, bronze tinted coating (STOPSOL) is implemented for the exterior façade while clear float, clear reflective coating (STOPSOL), grey and brown tinted coating (Anti-sun float) and blue coating tinted (SUNCOOL float) are implemented for the interior façade. In this paper, several evaluation parameters are used to quantify the optimum design parameters that would balance the daylighting requirements of a box window DSF office versus sky conditions range (20-40) klux. The optimum design parameters of DSF office building obtained under different glazing types are highlighted as follows. When using bronze tinted coating (STOPSOL) for the exterior façade, the glazing types of interior façade that showed superior daylighting performance of DSF office at (CD of 1.0m with WWR of 70%), (CD of 1.5m with WWR of 70%), (CD of 2.0m with WWR of 70%) and (CD of 2.0m with WWR of 70%) are grey tinted coating (Anti-sun float), clear reflective coating (STOPSOL), brown tinted coating (Anti-sun float), and clear float glazing respectively. Blue Coating tinted (SUNCOOL float) of interior façade glazing failed to meet outstanding daylighting performance at any cavity depth.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nicholson, James C.; Weisman, Jeffery A.; Boyer, Christen J.

Halloysite nanotubes (HNTs) are a naturally-occurring aluminosilicate whose dimensions measure microns in length and tens of nanometers in diameter. Bonding defects between the alumina and silica lead to net negative and positive charges on the exterior and interior lumen, respectively. HNTs have been shown to enhance the material properties of polymer matrices and enable the sustained release of loaded chemicals, drugs, and growth factors. Due to the net charges, these nanotubes can also be readily coated in layered-depositions using the HNT exterior lumen’s net negative charge as the basis for assembly. These coatings are primarily done through wet chemical processes,more » the majority of which are limited in their use of desired chemicals, due to the polarity of the halloysite. Furthermore, this restriction in the type of chemicals used often requires the use of more toxic chemicals in place of greener options, and typically necessitates the use of a significantly longer chemical process to achieve the desired coating. In this study, we show that HNTs can be coated with metal acetylacetonates—compounds primarily employed in the synthesis of nanoparticles, as metal catalysts, and as NMR shift reagents—through a dry sintering process. This method was capable of thermally decaying the metal acetylacetonate, resulting in a free positively-charged metal ion that readily bonded to the negatively-charged HNT exterior, resulting in metallic coatings forming on the HNT surface. Our coating method may enable greater deposition of coated material onto these nanotubes as required for a desired application. Moreover, the use of chemical processes using toxic chemicals is not required, thus eliminating exposure« less

Adsorption mechanism of an antimicrobial peptide on carbonaceous surfaces: A molecular dynamics study

NASA Astrophysics Data System (ADS)

Roccatano, Danilo; Sarukhanyan, Edita; Zangi, Ronen

2017-02-01

Peptides are versatile molecules with applications spanning from biotechnology to nanomedicine. They exhibit a good capability to unbundle carbon nanotubes (CNT) by improving their solubility in water. Furthermore, they are a powerful drug delivery system since they can easily be uptaken by living cells, and their high surface-to-volume ratio facilitates the adsorption of molecules of different natures. Therefore, understanding the interaction mechanism between peptides and CNT is important for designing novel therapeutical agents. In this paper, the mechanisms of the adsorption of antimicrobial peptide Cecropin A-Magainin 2 (CA-MA) on a graphene nanosheet (GNS) and on an ultra-short single-walled CNT are characterized using molecular dynamics simulations. The results show that the peptide coats both GNS and CNT surfaces through preferential contacts with aromatic side chains. The peptide packs compactly on the carbon surfaces where the polar and functionalizable Lys side chains protrude into the bulk solvent. It is shown that the adsorption is strongly correlated to the loss of the peptide helical structure. In the case of the CNT, the outer surface is significantly more accessible for adsorption. Nevertheless when the outer surface is already covered by other peptides, a spontaneous diffusion, via the amidated C-terminus into the interior of the CNT, was observed within 150 ns of simulation time. We found that this spontaneous insertion into the CNT interior can be controlled by the polarity of the entrance rim. For the positively charged CA-MA peptide studied, hydrogenated and fluorinated rims, respectively, hinder and promote the insertion.

A simple circular-polarized antenna: Circular waveguide horn coated with lossy magnetic material

NASA Technical Reports Server (NTRS)

Lee, C. S.; Lee, S. W.; Justice, D. W.

1986-01-01

A circular waveguide horn coated with a lossy material in its interior wall can be used as an alternative to a corrugated waveguide for radiating a circularly polarized (CP) field. To achieve good CP radiation, the diameter of the structure must be larger than the free-space wavelength, and the coating material must be sufficiently lossy and magnetic. This device is cheaper and lighter in weight than the corrugated one.

A Purchasing Agent’s Guide to Buying Paints and Coatings

DTIC Science & Technology

1993-03-01

taken to topside systems , where an inorganic zinc silicate is often used as the corrosion preventa- tive primer. then topcoats such as alkyds , vinyls...interior coaling systems or as topcoats for exterior applications. Alkyd coatings are economical and easy to apply. They do, however, operate as a barrier...combined with alkyd technology to produce a hybrid coating which embodies some of the desirable quali- ties of both. These include reduced drying times

Electronically transparent graphene replicas of diatoms: a new technique for the investigation of frustule morphology

PubMed Central

Pan, Zhengwei; Lerch, Sarah J. L.; Xu, Liang; Li, Xufan; Chuang, Yen-Jun; Howe, Jane Y.; Mahurin, Shannon M.; Dai, Sheng; Hildebrand, Mark

2014-01-01

The morphogenesis of the silica cell walls (called frustules) of unicellular algae known as diatoms is one of the most intriguing mysteries of the diatoms. To study frustule morphogenesis, optical, electron and atomic force microscopy has been extensively used to reveal the frustule morphology. However, since silica frustules are opaque, past observations were limited to outer and fracture surfaces, restricting observations of interior structures. Here we show that opaque silica frustules can be converted into electronically transparent graphene replicas, fabricated using chemical vapor deposition of methane. Chemical vapor deposition creates a continuous graphene coating preserving the frustule's shape and fine, complicated internal features. Subsequent dissolution of the silica with hydrofluoric acid yields a free-standing replica of the internal and external native frustule morphologies. Electron microscopy renders these graphene replicas highly transparent, revealing previously unobserved, complex, three-dimensional, interior frustule structures, which lend new insights into the investigation of frustule morphogenesis. PMID:25135739

77 FR 39983 - Migratory Bird Hunting; Application for Approval of Fluoropolymeric Shot Coatings as Nontoxic for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-06

... of Fluoropolymeric Shot Coatings as Nontoxic for Waterfowl Hunting AGENCY: Fish and Wildlife Service, Interior. ACTION: Notice of application for nontoxic shot approval. SUMMARY: We, the U.S. Fish and Wildlife Service, announce that Spectra Shot, LLC, of Lafayette, Louisiana, has applied for approval of steel shot...

Investigation of the Degradation Mechanisms of Particulate Reinforced Epoxy Coatings and Zinc-Rich Coatings Under an Erosion and Corrosion Environment for Oil and Gas Industry Applications

NASA Astrophysics Data System (ADS)

Wang, Dailin

During oil and gas production and transportation, the presence of an oil-sand slurry, together with the presence of CO2, H2S, oxygen, and seawater, create an erosive/abrasive and corrosive environment for the interior surfaces of undersea pipelines transporting oil and gas from offshore platforms. Erosion/wear and corrosion are often synergic processes leading to a much greater material loss of pipeline cross-section than that caused by each individual process alone. Both organic coatings and metallic sacrificial coatings have been widely employed to provide protection to the pipeline steels against corrosion through barrier protection and cathodic protection, and these protection mechanisms have been well studied. However, coating performance under the synergic processes of erosion/wear and corrosion have been much less researched and coating degradation mechanisms when erosion/wear and corrosion are both going on has not been well elucidated. In the work presented in this dissertation, steel panels coated with filler reinforced epoxy coatings and carbon nanotubes (CNTs) reinforced zinc-rich coatings have been evaluated under erosion/wear followed by an exposure to a corrosive environment. Electrochemical tests and material characterization methods have been applied to study the degradation mechanisms of the coatings during the tests and coating degradation mechanisms have been proposed. While organic coatings with a lower amount of filler particles provided better protection in a corrosive environment alone and in solid particle impingement erosion testing alone, organic coatings with a higher amount of filler particles showed better performance during wear testing alone. A higher amount of filler particles was also beneficial in providing protection against wear and corrosion environment, and erosion and corrosion environment. Coating thickness played a significant role in the barrier properties of the coatings under both erosion and corrosion tests. When the organic coatings were exposed to a corrosive environment with presence of H2S, thicker coatings provided better protection regardless of the amount and types of filler particles present in the coatings. For zinc-rich coatings, coatings with CNTs provided better barrier protection for the steel substrate than traditional zinc-rich coatings in a corrosive environment alone. However, the CNTs-filled zinc-rich epoxy coatings did not provide adequate protection when the coated specimens were exposed to erosion and corrosion.

Method and system for treating an interior surface of a workpiece using a charged particle beam

DOEpatents

Swenson, David Richard

2007-05-23

A method and system of treating an interior surface on an internal cavity of a workpiece using a charged particle beam. A beam deflector surface of a beam deflector is placed within the internal cavity of the workpiece and is used to redirect the charged particle beam toward the interior surface to treat the interior surface.

Compositions of Spherules and Rock Surfaces at Meridiani

NASA Technical Reports Server (NTRS)

Mittlefehldt, David W.; Jolliff, B. L.; Clark, B. C.; Gellert, R.

2007-01-01

The Alpha Particle X-ray Spectrometers (APXS) on the Mars Exploration Rovers (MER) have proven extremely valuable for analyzing rocks and soils on the surface of Mars. The precision of their compositional measurements has been shown to be phenomenal through analyses of the compositionally very uniform Meridiani soils. Through combined use of the rock abrasion tool (RAT) and the analytical instruments on the in-situ deployment device (IDD), analyses of the interiors of fine-grained and texturally uniform rocks with surfaces ground flat have been made under conditions that are nearly ideal for this mode of analysis. The APXS has also been used frequently to analyze materials whose characteristics, surface morphologies, and sample-detector geometries are less than ideal, but the analyses of which are nonetheless very useful for understanding the makeup of the target materials. Such targets include undisturbed rocks with irregular and sometimes coated surfaces and mixed targets such as soils that include fine-grained components as well as coarse grains and pieces of rocks. Such target materials include the well known hematite-rich concretions, referred to as blueberries because of their multispectral color, size, and mode of occurrence. In addition to non-ideal target geometry, such mixed materials also present a heterogeneous target in terms of density. These irregularities violate the assumptions commonly associated with analyses done in the laboratory to achieve the highest possible accuracy. Here we acknowledge the irregularities and we examine the inferences drawn from specific chemical trends obtained on imperfect targets in light of one of the potential pitfalls of natural materials on the surface of Mars, namely thin dust coatings.

Feed gas contaminant control in ion transport membrane systems

DOEpatents

Carolan, Michael Francis [Allentown, PA; Minford, Eric [Laurys Station, PA; Waldron, William Emil [Whitehall, PA

2009-07-07

Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

Preparation of silica-coated poly(styrene-co-4-vinylpyridine) particles and hollow particles.

PubMed

Zou, Hua; Wu, Shishan; Shen, Jian

2008-09-16

This paper presents a novel method for preparation of polymer-silica colloidal nanocomposites based on emulsion polymerization and subsequent sol-gel nanocoating process. The polystyrene latex particles bearing basic groups on their surfaces were successfully synthesized through emulsion polymerization using 4-vinylpyridine (4VP) as a functional comonomer and polyvinylpyrrolidone (PVP) as a surfactant. A series of poly(styrene-co-4-vinylpyridine)/SiO2 nanocomposite particles with smooth or rough core-shell morphology were obtained through the coating process. The poly(styrene-co-4-vinylpyridine) particles could be dissolved subsequently or simultaneously during the sol-gel coating process to form hollow particles. The effects of the amount of 4VP, PVP, NH(4)OH, and tetraethoxysilane (TEOS) on both the nanocomposite particles and hollow particles were investigated. Transmission electron microscopy showed that the morphology of the nanocomposite particles and hollow particles was strongly influenced by the initial feed of the comonomer 4VP and the coupling agent PVP. The conditions to obtain all hollow particles were also studied. Thermogravimetric analysis and energy dispersive X-ray spectroscopy analyses indicated that the interiors of hollow particles were not really "hollow".

The Influence of the Inner Topology of Cooling Units on the Performance of Automotive Exhaust-Based Thermoelectric Generators

NASA Astrophysics Data System (ADS)

Zhu, D. C.; Su, C. Q.; Deng, Y. D.; Wang, Y. P.; Liu, X.

2017-11-01

Automotive exhaust-based thermoelectric generators are currently a hot topic in energy recovery. The waste heat of automotive exhaust gas can be converted into electricity by means of thermoelectric modules. Generally, inserting fins into the cooling unit contributes to enhancing the heat transfer for a higher power output. However, the introduction of fins will result in a pressure drop in the cooling system. In current research, in order to enhance the heat transfer and avoid a large pressure drop, a cooling unit with cylindrical grooves on the interior surface was proposed. To evaluate the performance of the cylindrical grooves, different inner topologies, including a smooth interior surface,a smooth interior surface with inserted fins and an interior surface with cylindrical grooves, were compared. The results revealed that compared with the smooth interior surface, the smooth interior surface with inserted fins and the interior surface with cylindrical grooves both enhanced the heat transfer, but the interior surface with cylindrical grooves obtained a lower pressure drop. To improve the performance of the cylindrical grooves, different groove-depth ratios were tried, and the results showed that a groove-depth ratio of 0.081 could provide the best overall performance.

The Influence of the Inner Topology of Cooling Units on the Performance of Automotive Exhaust-Based Thermoelectric Generators

NASA Astrophysics Data System (ADS)

Zhu, D. C.; Su, C. Q.; Deng, Y. D.; Wang, Y. P.; Liu, X.

2018-06-01

Automotive exhaust-based thermoelectric generators are currently a hot topic in energy recovery. The waste heat of automotive exhaust gas can be converted into electricity by means of thermoelectric modules. Generally, inserting fins into the cooling unit contributes to enhancing the heat transfer for a higher power output. However, the introduction of fins will result in a pressure drop in the cooling system. In current research, in order to enhance the heat transfer and avoid a large pressure drop, a cooling unit with cylindrical grooves on the interior surface was proposed. To evaluate the performance of the cylindrical grooves, different inner topologies, including a smooth interior surface,a smooth interior surface with inserted fins and an interior surface with cylindrical grooves, were compared. The results revealed that compared with the smooth interior surface, the smooth interior surface with inserted fins and the interior surface with cylindrical grooves both enhanced the heat transfer, but the interior surface with cylindrical grooves obtained a lower pressure drop. To improve the performance of the cylindrical grooves, different groove-depth ratios were tried, and the results showed that a groove-depth ratio of 0.081 could provide the best overall performance.

Microscopic observations of osteoblast growth on micro-arc oxidized β titanium

NASA Astrophysics Data System (ADS)

Chen, Hsien-Te; Chung, Chi-Jen; Yang, Tsai-Ching; Tang, Chin-Hsin; He, Ju-Liang

2013-02-01

Titanium alloys are widely used in orthopedic and dental implants, owing to their excellent physical properties and biocompatibility. By using the micro-arc oxidation (MAO), we generated anatase-rich (A-TiO2) and rutile-rich (R-TiO2) titanium dioxide coatings, individually on β-Ti alloy, in which the latter achieved an enhanced in vitro and in vivo performance. Thoroughly elucidating how the osteoblasts interact with TiO2 coatings is of worthwhile interest. This study adopts the focused ion beam (FIB) to section off the TiO2 coated samples for further scanning electron microscope (SEM) and transmission electron microscope (TEM) observation. The detailed crystal structures of the TiO2 coated specimens are also characterized. Experimental results indicate osteoblasts adhered more tenaciously and grew conformably with more lamellipodia extent on the R-TiO2 specimen than on the A-TiO2 and raw β-Ti specimens. FIB/SEM cross-sectional images of the cell/TiO2 interface revealed micro gaps between the cell membrane and contact surface of A-TiO2 specimen, while it was not found on the R-TiO2 specimen. Additionally, the number of adhered and proliferated cells on the R-TiO2 specimen was visually greater than the others. Closely examining EDS line scans and elemental mappings of the FIB/TEM cross-sectional images of the cell/TiO2 interface reveals both the cell body and interior space of the TiO2 coating contain nitrogen and sulfur (the biological elements in cell). This finding supports the assumption that osteoblast can grow into the porous structure of TiO2 coatings and demonstrating that the R-TiO2 coating formed by MAO serves the best for β-Ti alloys as orthopedic and dental implants.

Devices and methods for managing noncombustible gasses in nuclear power plants

DOEpatents

Marquino, Wayne; Moen, Stephan C; Wachowiak, Richard M; Gels, John L; Diaz-Quiroz, Jesus; Burns, Jr., John C

2014-12-23

Systems passively eliminate noncondensable gasses from facilities susceptible to damage from combustion of built-up noncondensable gasses, such as H2 and O2 in nuclear power plants, without the need for external power and/or moving parts. Systems include catalyst plates installed in a lower header of the Passive Containment Cooling System (PCCS) condenser, a catalyst packing member, and/or a catalyst coating on an interior surface of a condensation tube of the PCCS condenser or an annular outlet of the PCCS condenser. Structures may have surfaces or hydrophobic elements that inhibit water formation and promote contact with the noncondensable gas. Noncondensable gasses in a nuclear power plant are eliminated by installing and using the systems individually or in combination. An operating pressure of the PCCS condenser may be increased to facilitate recombination of noncondensable gasses therein.

Devices and methods for managing noncondensable gasses in nuclear power plants

DOEpatents

Marquino, Wayne; Moen, Stephan C.; Wachowiak, Richard M.; Gels, John L.; Diaz-Quiroz, Jesus; Burns, Jr., John C.

2016-11-15

Systems passively eliminate noncondensable gasses from facilities susceptible to damage from combustion of built-up noncondensable gasses, such as H2 and O2 in nuclear power plants, without the need for external power and/or moving parts. Systems include catalyst plates installed in a lower header of the Passive Containment Cooling System (PCCS) condenser, a catalyst packing member, and/or a catalyst coating on an interior surface of a condensation tube of the PCCS condenser or an annular outlet of the PCCS condenser. Structures may have surfaces or hydrophobic elements that inhibit water formation and promote contact with the noncondensable gas. Noncondensable gasses in a nuclear power plant are eliminated by installing and using the systems individually or in combination. An operating pressure of the PCCS condenser may be increased to facilitate recombination of noncondensable gasses therein.

Intra-particle migration of mercury in granular polysulfide-rubber-coated activated carbon (PSR-AC)

PubMed Central

Kim, Eun-Ah; Masue-Slowey, Yoko; Fendorf, Scott; Luthy, Richard G.

2011-01-01

The depth profile of mercuric ion after the reaction with polysulfide-rubber-coated activated carbon (PSR-AC) was investigated using micro-x-ray fluorescence (μ-XRF) imaging techniques and mathematical modeling. The μ-XRF results revealed that mercury was concentrated at 0~100 μm from the exterior of the particle after three months of treatment with PSR-AC in 10 ppm HgCl2 aqueous solution. The μ-X-ray absorption near edge spectroscopic (μ-XANES) analyses indicated HgS as a major mercury species, and suggested that the intra-particle mercury transport involved a chemical reaction with PSR polymer. An intra-particle mass transfer model was developed based on either a Langmuir sorption isotherm with liquid phase diffusion (Langmuir model) or a kinetic sorption with surface diffusion (kinetic sorption model). The Langmuir model predicted the general trend of mercury diffusion, although at a slower rate than observed from the μ-XRF map. A kinetic sorption model suggested faster mercury transport, which overestimated the movement of mercuric ions through an exchange reaction between the fast and slow reaction sites. Both μ-XRF and mathematical modeling results suggest mercury removal occurs not only at the outer surface of the PSR-AC particle but also at some interior regions due to a large PSR surface area within an AC particle. PMID:22133913

Sol-gel derived ceramic electrolyte films on porous substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kueper, T.W.

1992-05-01

A process for the deposition of sol-gel derived thin films on porous substrates has been developed; such films should be useful for solid oxide fuel cells and related applications. Yttria-stabilized zirconia films have been formed from metal alkoxide starting solutions. Dense films have been deposited on metal substrates and ceramic substrates, both dense and porous, through dip-coating and spin-coating techniques, followed by a heat treatment in air. X-ray diffraction has been used to determine the crystalline phases formed and the extent of reactions with various substrates which may be encountered in gas/gas devices. Surface coatings have been successfully applied tomore » porous substrates through the control of substrate pore size and deposition parameters. Wetting of the substrate pores by the coating solution is discussed, and conditions are defined for which films can be deposited over the pores without filling the interiors of the pores. Shrinkage cracking was encountered in films thicker than a critical value, which depended on the sol-gel process parameters and on the substrate characteristics. Local discontinuities were also observed in films which were thinner than a critical value which depended on the substrate pore size. A theoretical discussion of cracking mechanisms is presented for both types of cracking, and the conditions necessary for successful thin formation are defined. The applicability of these film gas/gas devices is discussed.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roberts, III, Herbert Chidsey; Meschter, Peter Joel

A turbomachine component includes a body having an exterior surface and an interior surface, an internal cavity defined by the interior surface, and a reactivity neutralizing member arranged within the internal cavity. The reactivity neutralizing member is configured and disposed to neutralize turbomachine combustion products on the interior surface of the body.

Analysis of selected materials flown on interior locations of the Long Duration Exposure Facility

NASA Technical Reports Server (NTRS)

Smith, H. A.; Nelson, K. M.; Eash, D.; Pippin, H. G.

1994-01-01

This report documents the post-flight condition of selected hardware taken from interior locations on the Long Duration Exposure Facility (LDEF). This hardware was generally in excellent condition. Outgassing data is presented for heat shrink tubing and fiberglass composite shims. Variation in total mass loss (TML) values for heat shrink tubing were correlated with location. Nylon grommets were evaluated for mechanical integrity; slight embrittlement was observed for flight specimens. Multi-layer insulation blankets, wire bundles, and paints in non-exposed interior locations were all in visibly good condition. Silicon-containing contaminant films were observed on silver-coated hex nuts at the space- and Earth-end interior locations.

Basaltic rocks analyzed by the Spirit Rover in Gusev Crater.

PubMed

McSween, H Y; Arvidson, R E; Bell, J F; Blaney, D; Cabrol, N A; Christensen, P R; Clark, B C; Crisp, J A; Crumpler, L S; Des Marais, D J; Farmer, J D; Gellert, R; Ghosh, A; Gorevan, S; Graff, T; Grant, J; Haskin, L A; Herkenhoff, K E; Johnson, J R; Jolliff, B L; Klingelhoefer, G; Knudson, A T; McLennan, S; Milam, K A; Moersch, J E; Morris, R V; Rieder, R; Ruff, S W; De Souza, P A; Squyres, S W; Wänke, H; Wang, A; Wyatt, M B; Yen, A; Zipfel, J

2004-08-06

The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini-Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain

Basaltic rocks analyzed by the Spirit rover in Gusev crater

USGS Publications Warehouse

McSween, H.Y.; Arvidson, R. E.; Bell, J.F.; Blaney, D.; Cabrol, N.A.; Christensen, P.R.; Clark, B. C.; Crisp, J.A.; Crumpler, L.S.; Des Marias, D.J.; Farmer, J.D.; Gellert, Ralf; Ghosh, A.; Gorevan, S.; Graff, T.; Grant, J.; Haskin, L.A.; Herkenhoff, K. E.; Johnson, J. R.; Jolliff, B.L.; Klingelhoefer, G.; Knudson, A.T.; McLennan, S.; Milam, K.A.; Moersch, J.E.; Morris, R.V.; Rieder, R.; Ruff, S.W.; De Souza, P.A.; Squyres, S. W.; Wanke, H.; Wang, A.; Wyatt, M.B.; Yen, A.; Zipfel, J.

2004-01-01

The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini-Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain ???25% megacrysts. Chemical analyses of rocks by the Alpha Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. Mo??ssbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. These basalts extend the known range of rock compositions composing the martian crust.

Basaltic rocks analyzed by the Spirit Rover in Gusev Crater

NASA Technical Reports Server (NTRS)

McSween, H. Y.; Arvidson, R. E.; Bell, J. F., III; Blaney, D.; Cabrol, N. A.; Christensen, P. R.; Clark, B. C.; Crisp, J. A.; Crumpler, L. S.; DesMarais, D. J.;

High resolution non-contact interior profilometer

DOEpatents

Piltch, Martin S.; Patterson, R. Alan; Leeches, Gerald W.; Nierop, John Van; Teti, John J.

2001-01-01

Apparatus and method for inspecting the interior surfaces of devices such as vessels having a single entry port. Laser energy is launched into the vessel, and the light reflected from the interior surfaces is interfered with reference laser energy to produce an interference pattern. This interference pattern is analyzed to reveal information about the condition of the interior surfaces of the device inspected.

Gelatin Nano-coating for Inhibiting Surface Crystallization of Amorphous Drugs.

PubMed

Teerakapibal, Rattavut; Gui, Yue; Yu, Lian

2018-01-05

Inhibit the fast surface crystallization of amorphous drugs with gelatin nano-coatings. The free surface of amorphous films of indomethacin or nifedipine was coated by a gelatin solution (type A or B) and dried. The coating's effect on surface crystallization was evaluated. Coating thickness was estimated from mass change after coating. For indomethacin (weak acid, pK a  = 4.5), a gelatin coating of either type deposited at pH 5 and 10 inhibited its fast surface crystal growth. The coating thickness was 20 ± 10 nm. A gelatin coating deposited at pH 3, however, provided no protective effect. These results suggest that an effective gelatin coating does not require that the drug and the polymer have opposite charges. The ineffective pH 3 coating might reflect the poor wetting of indomethacin's neutral, hydrophobic surface by the coating solution. For nifedipine (weak base, pK a  = 2.6), a gelatin coating of either type deposited at pH 5 inhibited its fast surface crystal growth. Gelatin nano-coatings can be conveniently applied to amorphous drugs from solution to inhibit fast surface crystallization. Unlike strong polyelectrolyte coatings, a protective gelatin coating does not require strict pairing of opposite charges. This could make gelatin coating a versatile, pharmaceutically acceptable coating for stabilizing amorphous drugs.

Chemical Composition of Ceramic Tile Glazes

NASA Astrophysics Data System (ADS)

Anufrik, S. S.; Kurian, N. N.; Zhukova, I. I.; Znosko, K. F.; Belkov, M. V.

2016-11-01

We have carried out laser emission and x-ray fluorescence spectral analysis of glaze before and after its application to ceramic tile produced by Keramin JSC (Belarus). We have studied the internal microstructure of the ceramic samples. It was established that on the surface and within the bulk interior of all the samples, there are micropores of sizes ranging from a few micrometers to tens of micrometers and microcracks as long as several hundred micrometers. The presence of micropores on the surface of the ceramic tile leads to an increase in the water absorption level and a decrease in frost resistance. It was found that a decrease in the surface tension of ceramic tile coatings is promoted by substitution of sodium by potassium, silica by boric anhydride, magnesium and barium by calcium, CaO by sodium oxide, and SiO2 by chromium oxide. We carried out a comparative analysis of the chemical composition of glaze samples using S4 Pioneer and ElvaX x-ray fluorescence spectrometers and also an LIBS laser emission analyzer.

Stack configurations for tubular solid oxide fuel cells

DOEpatents

Armstrong, Timothy R.; Trammell, Michael P.; Marasco, Joseph A.

2010-08-31

A fuel cell unit includes an array of solid oxide fuel cell tubes having porous metallic exterior surfaces, interior fuel cell layers, and interior surfaces, each of the tubes having at least one open end; and, at least one header in operable communication with the array of solid oxide fuel cell tubes for directing a first reactive gas into contact with the porous metallic exterior surfaces and for directing a second reactive gas into contact with the interior surfaces, the header further including at least one busbar disposed in electrical contact with at least one surface selected from the group consisting of the porous metallic exterior surfaces and the interior surfaces.

Effects of High-Temperature Annealing in Air on Hi-Nicalon Fiber-Reinforced Celsian Matrix Composites

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.

2008-01-01

BN/SiC-coated Hi-Nicalon fiber-reinforced celsian matrix composites (CMC) were annealed for 100 h in air at various temperatures to 1200 C, followed by flexural strength measurements at room temperature. Values of yield stress and strain, ultimate strength, and composite modulus remain almost unchanged for samples annealed up to 1100 C. A thin porous layer formed on the surface of the 1100 C annealed sample and its density decreased from 3.09 to 2.90 g/cu cm. The specimen annealed at 1200 C gained 0.43 wt%, was severely deformed, and was covered with a porous layer of thick shiny glaze which could be easily peeled off. Some gas bubbles were also present on the surface. This surface layer consisted of elongated crystals of monoclinic celsian and some amorphous phase(s). The fibers in this surface ply of the CMC had broken into small pieces. The fiber-matrix interface strength was characterized through fiber push-in technique. Values of debond stress, alpha(sub d), and frictional sliding stress, tau(sub f), for the as-fabricated CMC were 0.31+/-0.14 GPa and 10.4+/-3.1 MPa, respectively. These values compared with 0.53+/-0.47 GPa and 8.33+/-1.72 MPa for the fibers in the interior of the 1200 C annealed sample, indicating hardly any change in fiber-matrix interface strength. The effects of thermal aging on microstructure were investigated using scanning electron microscopy. Only the surface ply of the 1200 C annealed specimens had degraded from oxidation whereas the bulk interior part of the CMC was unaffected. A mechanism is proposed explaining the various steps involved during the degradation of the CMC on annealing in air at 1200 C.

Design for Corrosion Control of Potable Water Distribution Systems

DTIC Science & Technology

1975-02-01

acrylics , vinyls, PVA latex or an acrylic latex, silicone alkyds , and zinc-rich primer systems. A zinc-rich primed coating system has a number of...some of the better weathering topcoats include the acrylics , silicone alkyds , and vinyl acrylics . 5.3.1.3 Interior Protection. The interiors of steel...alcohol (Methanol, wood alcohol). Alkali -- Caustic, such as sodium hydroxide, lye, etc. Alkyd plastics -- Plastics based on resins composed

Study of organic ablative thermal-protection coating for solid rocket motor

NASA Astrophysics Data System (ADS)

Hua, Zenggong

1992-06-01

A study is conducted to find a new interior thermal-protection material that possesses good thermal-protection performance and simple manufacturing possibilities. Quartz powder and Cr2O3 are investigated using epoxy resin as a binder and Al2O3 as the burning inhibitor. Results indicate that the developed thermal-protection coating is suitable as ablative insulation material for solid rocket motors.

Method of making sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells

DOEpatents

Isenberg, Arnold O.

1989-01-01

An electrochemical apparatus is made containing an exterior electorde bonded to the exterior of a tubular, solid, oxygen ion conducting electrolyte where the electrolyte is also in contact with an interior electrode, said exterior electrode comprising particles of an electronic conductor contacting the electrolyte, where a ceramic metal oxide coating partially surrounds the particles and is bonded to the electrolyte, and where a coating of an ionic-electronic conductive material is attached to the ceramic metal oxide coating and to the exposed portions of the particles.

Sulfur tolerant composite cermet electrodes for solid oxide electrochemical cells

DOEpatents

Isenberg, Arnold O.

1987-01-01

An electrochemical apparatus is made containing an exterior electrode bonded to the exterior of a tubular, solid, oxygen ion conducting electrolyte where the electrolyte is also in contact with an interior electrode, said exterior electrode comprising particles of an electronic conductor contacting the electrolyte, where a ceramic metal oxide coating partially surrounds the particles and is bonded to the electrolyte, and where a coating of an ionic-electronic conductive material is attached to the ceramic metal oxide coating and to the exposed portions of the particles.

Fluid injection microvalve

DOEpatents

Renzi, Ronald F.

2005-11-22

A microvalve for extracting small volume samples into analytical devices, e.g., high pressure liquid chromatography (HPLC) column, includes: a first body having a first interior surface and two or more outlet ports at the first interior surface that are in fluid communication with two or more first channels; a second body having a second interior surface and two or more inlet ports at the second interior surface that are in fluid communication with two or more second channels wherein the outlet ports of the first body are coaxial with the corresponding inlet ports of the second body such that there are at least two sets of coaxial port outlets and port inlets; a plate member, which has a substantially planar first mating surface and a substantially planar second mating surface, that is slidably positioned between the first interior surface and the second interior surface wherein the plate member has at least one aperture that traverses the height of the plate member, and wherein the aperture can be positioned to be coaxial with any of the at least two sets of coaxial port outlets and port inlets; and means for securing the first surface of the first body against the first mating surface and for securing the second surface of the second body against the second mating surface.

Electron microscopy and computed microtomography studies of in vivo implanted mini-TL dosimeters.

PubMed

Strand, S E; Strandh, M; Spanne, P

1993-01-01

The need for direct methods of measuring the absorbed dose in vivo increases for systemic radiation therapy, and in more sophisticated methodologies developed for radioimmunotherapy. One method suggested is the use of mini-thermoluminescent dosimeters (TLD). Recent reports indicate a marked loss of signal when the dosimeters are used in vivo. We investigated the exterior surface of the dosimeters with scanning electron microscopy and the interior dosimeter volume with computed microtomography. The results show that the dosimeters initially have crystals uniformly embedded in the teflon matrix, with some of them directly exposed to the environment. After incubation in gel, holes appear in the dosimeter matrix where the crystals should have been. The computed microtomographic images show that crystals remain in the interior of the matrix, producing the remaining signal. We conclude that these dosimeters should be very carefully handled, and for practical use of mini-TLDs in vivo the dosimeters should be calibrated in equivalent milieus. An alternative solution to the problem of decreased TL efficiency, would be to coat the dosimeters with a thin layer, of Teflon, or other suitable material.

Protective coating for alumina-silicon carbide whisker composites

DOEpatents

Tiegs, Terry N.

1989-01-01

Ceramic composites formed of an alumina matrix reinforced with silicon carbide whiskers homogenously dispersed therein are provided with a protective coating for preventing fracture strength degradation of the composite by oxidation during exposure to high temperatures in oxygen-containing atmospheres. The coating prevents oxidation of the silicon carbide whiskers within the matrix by sealing off the exterior of the matrix so as to prevent oxygen transport into the interior of the matrix. The coating is formed of mullite or mullite plus silicon oxide and alumina and is formed in place by heating the composite in air to a temperature greater than 1200.degree. C. This coating is less than about 100 microns thick and adequately protects the underlying composite from fracture strength degradation due to oxidation.

Friction surfaced Stellite6 coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid, E-mail: khalidrafi@gmail.com

2012-08-15

Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material formore » friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.« less

75 FR 60271 - Technical Amendments 2010

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-29

... Part VI Department of the Interior Office of Surface Mining Reclamation and Enforcement 30 CFR... INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Parts 740, 761, 773, 795, 816, 817...: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Final rule. SUMMARY: We, the...

Controlled, sustained release of proteins via an injectable, mineral-coated microsphere delivery vehicle

NASA Astrophysics Data System (ADS)

Franklin-Ford, Travelle

Hydroxyapatite interfaces have demonstrated strong protein binding and protein selection from a passing solution and can serve as a biocompatible carrier for controlled protein delivery. Hydroxyapatite is a major component of long bones and tooth enamel and is the most stable of all calcium phosphate isoforms in aqueous solutions at physiologic pH, providing a sensitive chromatographic mechanism for separating proteins. Here we describe an approach to create a synthetic hydroxyapatite coating through a biomimetic, heterogeneous nucleation from a modified simulated body fluid--supersaturated with calcium and phosphate ions on the surface of injectable polymer microspheres. We are able to bind and release bioactive growth factors into a variety of in vitro and in vivo conditions, demonstrating the functionality and advantage of the biomaterial. Creating a hydroxyapatite layer on the Poly(D,L-lactide-co-glycolide) (PLG) microsphere surface, avails the microsphere interior for another application that will not compete with protein binding and release. Encapsulating an imaging agent within the aqueous phase of the emulsion provides a visual reference for the injectable therapy upon microsphere fabrication. Another advantage of this system is that the mineral coating and subsequent protein binding is not compromised by the encapsulated imaging agent. This dual function delivery vehicle is not only advantageous for spatial tracking therapeutic applications, but also determining the longevity of the delivery vehicle once injected. In the broader sense, providing a mechanism to image and track our temporally controlled, sustained delivery system gives more evidence to support the effects of released protein on in vivo responses (bioactivity) and locate microspheres within different biological systems.

Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys

DOEpatents

Park, J.H.

1998-06-23

A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. 2 figs.

Characterization of red mud-epoxy intumescent char using surface imaging and micro analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arogundade, A. I., E-mail: ajiunolorioba@gmail.com; Megat-Yusoff, P. S. M., E-mail: puteris@petronas.com.my; Faiz, A.

In this study, red mud (RM), an oxide waste was proposed as reinforcing, synergistic filler for the traditional epoxy intumescent coating (IC). 5.5 wt% of acid-modified and unmodified red mud were introduced into the basic intumescent formulation of ammonium polyphosphate (APP), pentaerythritol (PER) and melamine (MEL). In order to predict effect of modification on its suitability, Field emission electron scanning microscopy and Fourier transform infra red were used to obtain detailed characteristics such as the cell size, pore distribution, homogeneity and chemical composition of the red mud-epoxy carbonaceous char. Both acid-modified and unmodified RM-filled ICs produced chars with smaller andmore » more closely packed cells compared to chars from the unfilled coating. Both coating types had hard carbonaceous metal phosphate coverings that could act as heat barriers. The unmodified red mud was found to be antagonistic to the intumescent action with an expansion of only 2 times the initial thickness. The leached, low iron-red mud produced an expansion of 15 times the initial thickness, but possessed a hollow interior. From these findings, it may be deduced that while acid leaching of red mud may improve intumescent expansion, it would be necessary to optimize the percent filler loading to improve residual mass.« less

Layer-by-layer polyelectrolyte-polyester hybrid microcapsules for encapsulation and delivery of hydrophobic drugs.

PubMed

Luo, Rongcong; Venkatraman, Subbu S; Neu, Björn

2013-07-08

A two-step process is developed to form layer-by-layer (LbL) polyelectrolyte microcapsules, which are able to encapsulate and deliver hydrophobic drugs. Spherical porous calcium carbonate (CaCO3) microparticles were used as templates and coated with a poly(lactic acid-co-glycolic acid) (PLGA) layer containing hydrophobic compounds via an in situ precipitation gelling process. PLGA layers that precipitated from N-methyl-2-pyrrolidone (NMP) had a lower loading and smoother surface than those precipitated from acetone. The difference may be due to different viscosities and solvent exchange dynamics. In the second step, the successful coating of multilayer polyelectrolytes poly(allylamine hydrochloride) (PAH) and poly(styrene sulfonate) (PSS) onto the PLGA coated CaCO3 microparticles was confirmed with AFM and ζ-potential studies. The release of a model hydrophobic drug, ibuprofen, from these hybrid microcapsules with different numbers of PAH/PSS layers was investigated. It was found that the release of ibuprofen decreases with increasing layer numbers demonstrating the possibility to control the release of ibuprofen with these novel hybrid microcapsules. Besides loading of hydrophobic drugs, the interior of these microcapsules can also be loaded with hydrophilic compounds and functional nanoparticles as demonstrated by loading with Fe3O4 nanoparticles, forming magnetically responsive dual drug releasing carriers.

Exploring Asteroid Interiors: The Deep Interior Mission Concept

NASA Technical Reports Server (NTRS)

Asphaug, E.; Belton, M. J. S.; Cangahuala, A.; Keith, L.; Klaasen, K.; McFadden, L.; Neumann, G.; Ostro, S. J.; Reinert, R.; Safaeinili, A.

2003-01-01

Deep Interior is a mission to determine the geophysical properties of near-Earth objects, including the first volumetric image of the interior of an asteroid. Radio reflection tomography will image the 3D distribution of complex dielectric properties within the 1 km rendezvous target and hence map structural, density or compositional variations. Laser altimetry and visible imaging will provide high-resolution surface topography. Smart surface pods culminating in blast experiments, imaged by the high frame rate camera and scanned by lidar, will characterize active mechanical behavior and structure of surface materials, expose unweathered surface for NIR analysis, and may enable some characterization of bulk seismic response. Multiple flybys en route to this target will characterize a diversity of asteroids, probing their interiors with non-tomographic radar reflectance experiments. Deep Interior is a natural follow-up to the NEARShoemaker mission and will provide essential guidance for future in situ asteroid and comet exploration. While our goal is to learn the interior geology of small bodies and how their surfaces behave, the resulting science will enable pragmatic technologies required of hazard mitigation and resource utilization.

Particle Characterization for a Protein Drug Product Stored in Pre-Filled Syringes Using Micro-Flow Imaging, Archimedes, and Quartz Crystal Microbalance with Dissipation.

PubMed

Zheng, Songyan; Puri, Aastha; Li, Jinjiang; Jaiswal, Archana; Adams, Monica

2017-01-01

Micro-flow imaging (MFI) has been used for formulation development for analyzing sub-visible particles. Archimedes, a novel technique for analyzing sub-micron particles, has been considered as an orthogonal method to currently existing techniques. This study utilized these two techniques to investigate the effectiveness of polysorbate (PS-80) in mitigating the particle formation of a therapeutic protein formulation stored in silicone oil-coated pre-filled syringes. The results indicated that PS-80 prevented the formation of both protein and silicone oil particles. In the case of protein particles, PS-80 might involve in the interactions with the hydrophobic patches of protein, air bubbles, and the stressed surfaces of silicone oil-coated pre-filled syringes. Such interactions played a role in mitigating the formation of protein particles. Subsequently, quartz crystal microbalance with dissipation (QCM-D) was utilized to characterize the interactions associated with silicone oil, protein, and PS-80 in the solutions. Based on QCM-D results, we proposed that PS-80 likely formed a layer on the interior surfaces of syringes. As a result, the adsorbed PS-80 might block the leakage of silicone oil from the surfaces to solution so that the silicone oil particles were mitigated at the presence of PS-80. Overall, this study demonstrated the necessary of utilizing these three techniques cooperatively in order to better understand the interfacial role of PS-80 in mitigating the formation of protein and silicone oil particles.

Amino Acid Analyses of Acid Hydrolysates in Desert Varnish

NASA Technical Reports Server (NTRS)

Perry, Randall S.; Staley, James T.; Dworkin, Jason P.; Engel, Mike

2001-01-01

There has long been a debate as to whether rock varnish deposits are microbially mediated or are deposited by inorganic processes. Varnished rocks are found throughout the world primarily in arid and semi-arid regions. The varnish coats are typically up to 200 microns thick and are composed of clays and alternating layers enriched in manganese and iron oxides. The individual layers range in thickness from 1 micron to greater than 10 microns and may continue laterally for more than a 100 microns. Overlapping botryoidal structures are visible in thin section and scanning electron micrographs. The coatings also include small amounts of organic mater and detrital grains. Amino-acid hydrolysates offer a means of assessing the organic composition of rock varnish collected from the Sonoran Desert, near Phoenix, AZ. Chromatographic analyses of hydrolysates from powdered samples of rock varnish suggest that the interior of rock varnish is relatively enriched in amino acids and specifically in d-alanine and glutamic acid. Peptidoglycan (murein) is the main structural component of gram-positive bacterial cell walls. The d-enantiomer of alanine and glutamic acid are specific to peptidoglycan and are consequently an indicator for the presence of bacteria. D-alanine is also found in teichoic acid which is only found in gram-positive bacteria. Several researchers have cultured bacteria from the surface of rock varnish and most have been gram-positive, suggesting that gram-positive bacteria are intimately associated with varnish coatings and may play a role in the formation of varnish coatings.

Surface and Internal Structure of Pristine Presolar Silicon Carbide

NASA Technical Reports Server (NTRS)

Stroud, Rhonda, M.; Bernatowicz, Thomas J.

2005-01-01

Silicon carbide is the most well-studied type of presolar grain. Isotope measurements of thousands [1,2] and structural data from over 500 individual grains have been reported [3]. The isotope data indicate that approximately 98% originated in asymptotic giant branch stars and 2% in supernovae. Although tens of different polytypes of SiC are known to form synthetically, only two polytypes have been reported for presolar grains. Daulton et al. [3] found that for SiC grains isolated from Murchison by acid treatments, 79.4% are 3C cubic beta-SiC, 2.7% are 2H hexagonal alpha-SiC, 17.1% are intergrowths of and , and 0.9% are heavily disordered. They report that the occurrence of only the and polytypes is consistent with the observed range of condensation temperatures of circumstellar dust for carbon stars. Further constraint on the formation and subsequent alteration of the grains can be obtained from studies of the surfaces and interior structure of grains in pristine form, i.e., prepared without acid treatments [4,5]. The acid treatments remove surface coatings, produce etch pits around defect sites and could remove some subgrains. Surface oxides have been predicted by theoretical modeling as a survival mechanism for SiC grains exposed to the hot oxidizing solar nebula [6]. Scanning electron microscopy studies of pristine SiC shows some evidence for the existence of oxide and organic coatings [4]. We report herein on transmission electron microscopy studies of the surface and internal structure of two pristine SiC grains, including definitive evidence of an oxide rim on one grain, and the presence of internal TiC and AlN grains.

Opal-based photonic crystal with double photonic bandgap structure

NASA Astrophysics Data System (ADS)

Romanov, S. G.; Yates, H. M.; Pemble, M. E.; DeLa Rue, R. M.

2000-09-01

The interior surfaces of one part of a piece of artificial opal have been coated with GaP so that the remaining part of the opal crystal remains empty, thus forming a photonic heterostructure. Two Bragg resonances have been observed in the optical transmission and reflectance spectra. These two resonances were found to behave differently with changes in the polarization of the incident light and the angle of propagation of the light with respect to the (111) planes of opal. Depolarization of the light was observed to occur most effectively at frequencies within the stop-bands, apparently due to the re-coupling of the propagating electromagnetic wave to a different system of eigenmodes when it crosses the interface separating two parts of the double photonic crystal.

Corrosion prevention of magnesium surfaces via surface conversion treatments using ionic liquids

DOEpatents

Qu, Jun; Luo, Huimin

2016-09-06

A method for conversion coating a magnesium-containing surface, the method comprising contacting the magnesium-containing surface with an ionic liquid compound under conditions that result in decomposition of the ionic liquid compound to produce a conversion coated magnesium-containing surface having a substantially improved corrosion resistance relative to the magnesium-containing surface before said conversion coating. Also described are the resulting conversion-coated magnesium-containing surface, as well as mechanical components and devices containing the conversion-coated magnesium-containing surface.

Electrocurtain coating process for coating solar mirrors

DOEpatents

Kabagambe, Benjamin; Boyd, Donald W.; Buchanan, Michael J.; Kelly, Patrick; Kutilek, Luke A.; McCamy, James W.; McPheron, Douglas A.; Orosz, Gary R.; Limbacher, Raymond D.

2013-10-15

An electrically conductive protective coating or film is provided over the surface of a reflective coating of a solar mirror by flowing or directing a cation containing liquid and an anion containing liquid onto the conductive surface. The cation and the anion containing liquids are spaced from, and preferably out of contact with one another on the surface of the reflective coating as an electric current is moved through the anion containing liquid, the conductive surface between the liquids and the cation containing liquid to coat the conductive surface with the electrically conductive coating.

Method of creating a controlled interior surface configuration of passages within a substrate

DOEpatents

Dembowski, Peter V.; Schilke, Peter W.

1983-01-01

A method of creating a controlled interior surface configuration of passages within a substrate, particularly cooling passages of nozzles or buckets of a gas turbine, involves the hot isostatic pressing of a leachable passage insert whose surface carries the female image of the desired interior surface configuration inside the substrate followed by leaching of the insert from the substrate.

Activation of Osteoblastic Function on Titanium Surface with Titanium-Doped Hydroxyapatite Nanoparticle Coating: An In Vitro Study.

PubMed

Nakazawa, Masahiro; Yamada, Masahiro; Wakamura, Masato; Egusa, Hiroshi; Sakurai, Kaoru

Titanium-doped hydroxyapatite (TiHA) nanoparticles contain titanium atoms in the hydroxyapatite lattice, which can physicochemically functionalize the titanium surface without modification of the surface topography. This study aimed to evaluate the physicochemical properties of machined or microroughened titanium surfaces coated with TiHA nanoparticles and the functions of osteoblasts cultured on them. Titanium disks with commercially available surface topography, such as machined or sandblasted, large-grit, and acid-etched (SLA) surfaces, were coated with TiHA. The disks with original or TiHA-coated surfaces were evaluated in topography, wettability, and chemical composition. Osteoblastic cells from rat femurs were cultured on the disks and evaluated in proliferation and differentiation. TiHA coating changed from hydrophobicity to hydrophilicity on both machined and SLA surfaces. Calcium and phosphate atoms were detected all over the surface with TiHA coating regardless of the surface topography. However, the considerable change in the inherent surface topographies was not observed on both types of surfaces after TiHA coating. Osteoblastic proliferative activity at day 4 was increased by TiHA coating on both types of surfaces. TiHA coating did not enhance expressions of bone matrix-related genes such as osteocalcin, osteopontin, bone sialoprotein, alkaline phosphatase, and collagen I. However, depositions of collagen, osteocalcin, and calcium in the culture at days 7 and 20 were increased on both types of surface topographies with TiHA coating. TiHA coating enhanced extracellular matrix formation on smooth and microroughened titanium surfaces by increasing osteoblastic proliferative activity without the deterioration of differentiation through hydrophilic and chemical functionalization.

Biological Response of Human Bone Marrow-Derived Mesenchymal Stem Cells to Commercial Tantalum Coatings with Microscale and Nanoscale Surface Topographies

NASA Astrophysics Data System (ADS)

Skoog, Shelby A.; Kumar, Girish; Goering, Peter L.; Williams, Brian; Stiglich, Jack; Narayan, Roger J.

2016-06-01

Tantalum is a promising orthopaedic implant coating material due to its robust mechanical properties, corrosion resistance, and excellent biocompatibility. Previous studies have demonstrated improved biocompatibility and tissue integration of surface-treated tantalum coatings compared to untreated tantalum. Surface modification of tantalum coatings with biologically inspired microscale and nanoscale features may be used to evoke optimal tissue responses. The goal of this study was to evaluate commercial tantalum coatings with nanoscale, sub-microscale, and microscale surface topographies for orthopaedic and dental applications using human bone marrow-derived mesenchymal stem cells (hBMSCs). Tantalum coatings with different microscale and nanoscale surface topographies were fabricated using a diffusion process or chemical vapor deposition. Biological evaluation of the tantalum coatings using hBMSCs showed that tantalum coatings promote cellular adhesion and growth. Furthermore, hBMSC adhesion to the tantalum coatings was dependent on surface feature characteristics, with enhanced cell adhesion on sub-micrometer- and micrometer-sized surface topographies compared to hybrid nano-/microstructures. Nanostructured and microstructured tantalum coatings should be further evaluated to optimize the surface coating features to promote osteogenesis and enhance osseointegration of tantalum-based orthopaedic implants.

Antimicrobial Silk Ocular Drug Delivery Implant for Chronic Posterior Segment Diseases

DTIC Science & Technology

2016-06-01

antibody bevacizumab. The device was covalently coated with the antibacterial polymer HMPE1 to protect against biofilm formation and the transmission of harmful bacterial to the interior of the ocular chamber.

Hot gas path component trailing edge having near wall cooling features

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lacy, Benjamin Paul; Kottilingam, Srikanth Chandrudu; Miranda, Carlos Miguel

A hot gas path component includes a substrate having an outer surface and an inner surface. The inner surface defines an interior space. The outer surface defines a pressure side surface and a suction side surface. The pressure and suction side surfaces are joined together at a leading edge and at a trailing edge. A first cooling passage is formed in the suction side surface of the substrate. It is coupled in flow communication to the interior space. A second cooling passage, separate from the first cooling passage, is formed in the pressure side surface. The second cooling passage ismore » coupled in flow communication to the interior space. A cover is disposed over at least a portion of the first and second cooling passages. The interior space channels a cooling fluid to the first and second cooling passages, which channel the cooling fluid therethrough to remove heat from the component.« less

Electrical contact arrangement for a coating process

DOEpatents

Kabagambe, Benjamin; McCamy, James W; Boyd, Donald W

2013-09-17

A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

The sea urchin egg jelly coat consists of globular glycoproteins bound to a fibrous fucan superstructure.

PubMed

Bonnell, B S; Keller, S H; Vacquier, V D; Chandler, D E

1994-03-01

Intact egg jelly (EJ) coats surrounding eggs of the sea urchin Strongylocentrotus purpuratus were visualized in stereo images of platinum replicas produced by the quick-freeze, deep-etch, rotary-shadowing technique. The hydrated EJ coat forms an extensive fibrous network that makes contact with the vitelline layer at the egg surface. Fibers are decorated along their length with particles, particle density being highest in the interior regions of the coat. The macromolecular components making up the EJ network were visualized by rotary-shadowing of mica-adsorbed EJ samples. Whole EJ coats solubilized in pH 5 sea-water and spread on the mica surface consist of complex networks of branching fibers decorated with large patches of amorphous material. As we have previously shown (Keller and Vacquier, 1994), EJ boiled in a dissolution buffer containing SDS and beta-mercaptoethanol and applied to a Sephacryl-500 gel filtration column can be separated into three fractions: a 380-kDa fucose sulfate polymer (FSP), which elutes in the void volume, and two column-included fractions consisting of intermediate (300 kDa) and low-molecular-weight (30- to 138-kDa) glycoproteins. Rotary-shadowing of the FSP fraction reveals branched fibrous components similar in appearance to that of solubilized whole EJ but devoid of any particulate decoration. In contrast, intermediate- and low-molecular-weight EJ components are strictly globular in appearance but are distinguishable on the basis of size. Ion-exchange purification of whole EJ yields two glycoproteins, of 82 and 138 kDa, having AR-inducing activity (Keller and Vacquier, 1994). Platinum replication shows these active components to be small spherical molecules about 8 nm in diameter. The above fractionation scheme requires harsh dissociation conditions. Indeed, if EJ is not boiled in SDS buffer before fractionation, the 300-kDa fraction and the FSP appear together in the void volume. Rotary-shadowing of this complex reveals a multistranded polymer, decorated with glycoproteins at specific kink points. Taken together, our data suggest that the EJ network is composed of a fucose sulfate polymer superstructure to which glycoproteins are bound.

Double-chimera proteins to enhance recruitment of endothelial cells and their progenitor cells.

PubMed

Behjati, M; Kazemi, M; Hashemi, M; Zarkesh-Esfahanai, S H; Bahrami, E; Hashemi-Beni, B; Ahmadi, R

2013-08-20

Enhanced attraction of selective vascular reparative cells is of great importance in order to increase vascular patency after endovascular treatments. We aimed to evaluate efficient attachment of endothelial cells and their progenitors on surfaces coated with mixture of specific antibodies, L-selectin and VE-cadherin, with prohibited platelet attachment. The most efficient conditions for coating of L-selectin-Fc chimera and VE-cadherin-Fc chimera proteins were first determined by protein coating on ELISA plates. The whole processes were repeated on titanium substrates, which are commonly used to coat stents. Endothelial progenitor cells (EPCs) and human umbilical vein endothelial cells (HUVECs) were isolated and characterized by flow cytometry. Cell attachment, growth, proliferation, viability and surface cytotoxicity were evaluated using nuclear staining and MTT assay. Platelet and cell attachment were evaluated using scanning electron microscopy. Optimal concentration of each protein for surface coating was 50 ng/ml. The efficacy of protein coating was both heat and pH independent. Calcium ions had significant impact on simultaneous dual-protein coating (P<0.05). Coating stability data revealed more than one year stability for these coated proteins at 4°C. L-selectin and VE-cadherin (ratio of 50:50) coated surface showed highest EPC and HUVEC attachment, viability and proliferation compared to single protein coated and non-coated titanium surfaces (P<0.05). This double coated surface did not show any cytotoxic effect. Surfaces coated with L-selectin and VE-cadherin are friendly surface for EPC and endothelial cell attachment with less platelet attachment. These desirable factors make the L-selectin and VE-cadherin coated surfaces perfect candidate endovascular device. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

Method of coating metal surfaces to form protective metal coating thereon

DOEpatents

Krikorian, Oscar H.; Curtis, Paul G.

1992-01-01

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

Method of coating metal surfaces to form protective metal coating thereon

DOEpatents

Krikorian, O.H.; Curtis, P.G.

1992-03-31

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

Effect of surface topological structure and chemical modification of flame sprayed aluminum coatings on the colonization of Cylindrotheca closterium on their surfaces

NASA Astrophysics Data System (ADS)

Chen, Xiuyong; He, Xiaoyan; Suo, Xinkun; Huang, Jing; Gong, Yongfeng; Liu, Yi; Li, Hua

2016-12-01

Biofouling is one of the major problems for the coatings used for protecting marine infrastructures during their long-term services. Regulation in surface structure and local chemistry is usually the key for adjusting antifouling performances of the coatings. In this study, flame sprayed multi-layered aluminum coatings with micropatterned surfaces were constructed and the effects of their surface structure and chemistry on the settlement of typical marine diatoms were investigated. Micropatterned topographical morphology of the coatings was constructed by employing steel mesh as a shielding plate during the coating deposition. A silicone elastomer layer for sealing and interconnection was further brush-coated on the micropatterned coatings. Additional surface modification was made using zwitterionic molecules via DOPA linkage. The surface-modified coatings resist effectively colonization of Cylindrotheca closterium. This is explained by the quantitative examination of a simplified conditioning layer that deteriorated adsorption of bovine calf serum proteins on the zwitterionic molecule-treated samples is revealed. The colonization behaviors of the marine diatoms are markedly influenced by the micropatterned topographical morphology. Either the surface micropatterning or the surface modification by zwitterionic molecules enhances antimicrobial ability of the coatings. However, the combined micropatterned structure and zwitterionic modification do not show synergistic effect. The results give insight into anti-corrosion/fouling applications of the modified aluminum coatings in the marine environment.

On crack growth in molar teeth from contact on the inclined occlusal surface.

PubMed

Chai, Herzl

2015-04-01

Extracted human molar teeth are indented by hard balls laid at the central fossa, sectioned, and their interior examined for damage. Contact on the fissured enamel coat generally occurs on three distinct spots. The main forms of damage are radial cracks growing from the DEJ to the occlusal surface and median radial and cylindrical cracks growing from a contact spot to the DEJ. For large balls failure by edge chipping near a cusp apex may occur. The median cracks tend to run unstably to the DEJ upon reaching the middle part of the enamel coat. The corresponding load, PFM, and the load needed to initiate radial cracks at the DEJ, PFR, are taken to signal crown failure. The mean values of PFM and PFR are on the order of 1000N. A conical bilayer model defined by thickness d, inclination angle θ, failure stress σF and toughness KC of the enamel coat is developed to assess crown failure. The analytical predictions for PFR and PFM agree well with the tests. The results indicate that enamel thickness is so designed as to ensure that PFR and PFM just exceed the maximum bite force under normal conditions while the choice of θ seems to reflect a compromise between needs to resist crown failure and break hard food particles. Both PFR and PFM are greatly reduced with reducing d, which points to the danger posed by tooth wear. The analytical expressions for PFR and PFM may also apply to other multi-cusp mammalian or prosthetic molar crowns. Cone cracking, suppressed in the anisotropic tooth enamel, may be an important failure mode in prosthetic crowns. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of the Cold-Sprayed Aluminum Coating-Substrate Interface Morphology on Bond Strength for Aircraft Repair Application

NASA Astrophysics Data System (ADS)

Blochet, Quentin; Delloro, Francesco; N'Guyen, Franck; Jeulin, Dominique; Borit, François; Jeandin, Michel

2017-04-01

This article is dealing with the effects of surface preparation of the substrate on aluminum cold-sprayed coating bond strength. Different sets of AA2024-T3 specimens have been coated with pure Al 1050 feedstock powder, using a conventional cold spray coating technique. The sets were grit-blasted (GB) before coating. The study focuses on substrate surface topography evolution before coating and coating-substrate interface morphology after coating. To study coating adhesion by LASAT® technique for each set, specimens with and without preceding GB treatment were tested in load-controlled conditions. Then, several techniques were used to evaluate the effects of substrate surface treatment on the final coating mechanical properties. Irregularities induced by the GB treatment modify significantly the interface morphology. Results showed that particle anchoring was improved dramatically by the presence of craters. The substrate surface was characterized by numerous anchors. Numerical simulation results exhibited the increasing deformation of particle onto the grit-blasted surface. In addition, results showed a strong relationship between the coating-substrate bond strength on the deposited material and surface preparation.

Antibacterial isoeugenol coating on stainless steel and polyethylene surfaces prevents biofilm growth.

PubMed

Nielsen, C K; Subbiahdoss, G; Zeng, G; Salmi, Z; Kjems, J; Mygind, T; Snabe, T; Meyer, R L

2018-01-01

Pathogenic bacteria can spread between individuals or between food items via the surfaces they share. Limiting the survival of pathogens on surfaces, therefore, presents an opportunity to limit at least one route of how pathogens spread. In this study, we propose that a simple coating with the essential oil isoeugenol can be used to circumvent the problem of bacterial transfer via surfaces. Two commonly used materials, stainless steel and polyethylene, were coated by physical adsorption, and the coatings were characterized by Raman spectroscopy, atomic force microscopy and water contact angle measurements. We quantified and visualized the colonization of coated and uncoated surfaces by three bacteria: Staphylococcus aureus, Listeria monocytogenes and Pseudomonas fluorescens. No viable cells were detected on surfaces coated with isoeugenol. The isoeugenol coating prepared with simple adsorption proved effective in preventing biofilm formation on stainless steel and polyethylene surfaces. The result was caused by the antibacterial effect of isoeugenol, as the coating did not diminish the adhesive properties of the surface. Our study demonstrates that a simple isoeugenol coating can prevent biofilm formation of S. aureus, L. monocytogenes and P. fluorescens on two commonly used surfaces. © 2017 The Society for Applied Microbiology.

Numerical methods for analyzing electromagnetic scattering

NASA Technical Reports Server (NTRS)

Lee, S. W.; Lo, Y. T.; Chuang, S. L.; Lee, C. S.

1985-01-01

Attenuation properties of the normal modes in an overmoded waveguide coated with a lossy material were analyzed. It is found that the low-order modes, can be significantly attenuated even with a thin layer of coating if the coating material is not too lossy. A thinner layer of coating is required for large attenuation of the low-order modes if the coating material is magnetic rather than dielectric. The Radar Cross Section (RCS) from an uncoated circular guide terminated by a perfect electric conductor was calculated and compared with available experimental data. It is confirmed that the interior irradiation contributes to the RCS. The equivalent-current method based on the geometrical theory of diffraction (GTD) was chosen for the calculation of the contribution from the rim diffraction. The RCS reduction from a coated circular guide terminated by a PEC are planned schemes for the experiments are included. The waveguide coated with a lossy magnetic material is suggested as a substitute for the corrugated waveguide.

Nanocrystalline films for gas-reactive applications

DOEpatents

Eastman, Jeffrey A.; Thompson, Loren J.

2004-02-17

A gas sensor for detection of oxidizing and reducing gases, including O.sub.2, CO.sub.2, CO, and H.sub.2, monitors the partial pressure of a gas to be detected by measuring the temperature rise of an oxide-thin-film-coated metallic line in response to an applied electrical current. For a fixed input power, the temperature rise of the metallic line is inversely proportional to the thermal conductivity of the oxide coating. The oxide coating contains multi-valent cation species that change their valence, and hence the oxygen stoichiometry of the coating, in response to changes in the partial pressure of the detected gas. Since the thermal conductivity of the coating is dependent on its oxygen stoichiometry, the temperature rise of the metallic line depends on the partial pressure of the detected gas. Nanocrystalline (<100 nm grain size) oxide coatings yield faster sensor response times than conventional larger-grained coatings due to faster oxygen diffusion along grain boundaries rather than through grain interiors.

Effect of surface roughness of hydroxyapatite-coated titanium on the bone-implant interface shear strength.

PubMed

Hayashi, K; Inadome, T; Tsumura, H; Nakashima, Y; Sugioka, Y

1994-11-01

We have investigated the bone-implant interface shear strength of hydroxyapatite (HA)-coated Ti-6Al-4V (HA-coating A) (roughness average, Ra = 3.4 +/- 0.5 microns) and HA-coated Ti-6Al-4V with a rougher surface (HA-coating B) (Ra = 8.4 +/- 1.8 microns). There was no significant difference between HA-coating A and HA-coating B implants with respect to the bone-implant interface shear strength as determined in push-out tests using the transcortical model in adult dogs. The bone-implant interface shear strength of bead-coated porous Ti-6Al-4V was significantly greater than that of both HA-coating A and HA-coating B implants. The failure site, as determined by scanning electron microscopy, was the coating-substrate interface, not the coating-bone interface. This indicates a need to protect the HA coating from the direct shear forces. HA coating enhances early bone growth into the porous surface of the implant. Long-term fixation should depend on bone anchoring to this porous surface. Hydroxyapatite coatings must be developed which do not obstruct the pores of the surface of the implant.

Modeling Radiation Effectiveness for Inactivation of Bacillus Spores

DTIC Science & Technology

2015-09-17

are the exosporium, the spore coat, the outer membrane, the cortex, the germ cell wall, the inner membrane, and the core. These are illustrated in...small amounts of carbohydrates and lipids. The 6 coat acts as the spore’s first line of defense against some chemical infiltration such as lytic enzymes...the spore as water makes up 48-57 percent of the cortex [2]. Immediately interior to the cortex is the germ cell wall which is also a peptidoglycan

A polymeric fastener can easily functionalize liposome surfaces with gadolinium for enhanced magnetic resonance imaging.

PubMed

Smith, Cartney E; Shkumatov, Artem; Withers, Sarah G; Yang, Binxia; Glockner, James F; Misra, Sanjay; Roy, Edward J; Wong, Chun-Ho; Zimmerman, Steven C; Kong, Hyunjoon

2013-11-26

Common methods of loading magnetic resonance imaging (MRI) contrast agents into nanoparticles often suffer from challenges related to particle formation, complex chemical modification/purification steps, and reduced contrast efficiency. This study presents a simple, yet advanced process to address these issues by loading gadolinium, an MRI contrast agent, exclusively on a liposome surface using a polymeric fastener. The fastener, so named for its ability to physically link the two functional components together, consisted of chitosan substituted with diethylenetriaminepentaacetic acid (DTPA) to chelate gadolinium, as well as octadecyl chains to stabilize the modified chitosan on the liposome surface. The assembly strategy, mimicking the mechanisms by which viruses and proteins naturally anchor to a cell, provided greater T1 relaxivity than liposomes loaded with gadolinium in both the interior and outer leaflet. Gadolinium-coated liposomes were ultimately evaluated in vivo using murine ischemia models to highlight the diagnostic capability of the system. Taken together, this process decouples particle assembly and functionalization and, therefore, has considerable potential to enhance imaging quality while alleviating many of the difficulties associated with multifunctional particle fabrication.

Preparation of Ultrahigh Molecular Weight Polyethylene/Graphene Nanocomposite In situ Polymerization via Spherical and Sandwich Structure Graphene/Sio2 Support

NASA Astrophysics Data System (ADS)

Su, Enqi; Gao, Wensheng; Hu, Xinjun; Zhang, Caicai; Zhu, Bochao; Jia, Junji; Huang, Anping; Bai, Yongxiao

2018-04-01

Reduced graphene oxide/SiO2 (RGO/SiO2) serving as a novel spherical support for Ziegler-Natta (Z-N) catalyst is reported. The surface and interior of the support has a porous architecture formed by RGO/SiO2 sandwich structure. The sandwich structure is like a brick wall coated with a graphene layer of concreted as skeleton which could withstand external pressures and endow the structure with higher support stabilities. After loading the Z-N catalyst, the active components anchor on the surface and internal pores of the supports. When the ethylene molecules meet the active centers, the molecular chains grow from the surface and internal catalytic sites in a regular and well-organized way. And the process of the nascent molecular chains filled in the sandwich structure polymerization could ensure the graphene disperse uniformly in the polymer matrix. Compared with traditional methods, the porous spherical graphene support of this strategy has far more advantages and could maintain an intrinsic graphene performance in the nanocomposites.

A Polymeric Fastener can Easily Functionalize Liposome Surfaces with Gadolinium for Enhanced Magnetic Resonance Imaging

PubMed Central

Smith, Cartney E.; Shkumatov, Artem; Withers, Sarah G.; Glockner, James F.; Misra, Sanjay; Roy, Edward J.; Wong, Chun-Ho; Zimmerman, Steven C.; Kong, Hyunjoon

2013-01-01

Common methods of loading magnetic resonance imaging (MRI) contrast agents into nanoparticles often suffer from challenges related to particle formation, complex chemical modification/purification steps, and reduced contrast efficiency. This study presents a simple, yet advanced process to address these issues by loading gadolinium, an MRI contrast agent, exclusively on a liposome surface using a polymeric fastener. The fastener, so named for its ability to physically link the two functional components together, consisted of chitosan substituted with diethylenetriaminepentaacetic acid (DTPA) to chelate gadolinium, as well as octadecyl chains to stabilize the modified chitosan on the liposome surface. The assembly strategy, mimicking the mechanisms by which viruses and proteins naturally anchor to a cell, provided greater T1 relaxivity than liposomes loaded with gadolinium in both the interior and outer leaflet. Gadolinium-coated liposomes were ultimately evaluated in vivo using murine ischemia models to highlight the diagnostic capability of the system. Taken together, this process decouples particle assembly and functionalization, and therefore has considerable potential to enhance imaging quality while alleviating many of the difficulties associated with multifunctional particle fabrication. PMID:24083377

Characterization of in situ synthesized TiB 2 reinforcements in iron-based composite coating

NASA Astrophysics Data System (ADS)

Zhang, Panpan; Wang, Xibao; Guo, Lijie; Cai, Lijuan; Sun, Hongling

2011-12-01

TiB2 reinforced iron-based composite coatings can be fabricated on the mild steel substrate with a powder mixture of Ti and B4C by plasma transferred arc (PTA) powder surfacing process. Characterizations of the TiB2 reinforcements in the coated surface were investigated in this paper. The experimental work enables the following findings to be obtained: (i) acicular shaped and blocky formed TiB2 phases could be synthesized in situ using PTA powder surfacing process in the iron-based composite coating. (ii) Gradient distributions of TiB2 reinforcements appeared in the composite coating from both the vertical and horizontal direction of the coating's cross-section. Significant changes of the size, shape and volume fraction for TiB2 particles appeared in different regions of the surface coating, due to the effects of the dilution rate and mass density. (iii) Values of coating dilution could have profound impacts on the characterization of TiB2 reinforcements in the coated surfaces. With the increase of coating dilution, TiB2 grain tends to be acicular shaped at the edge of the surface coating, while it remains to be granular formed in the center of the composite coating.

Method for smoothing the surface of a protective coating

DOEpatents

Sangeeta, D.; Johnson, Curtis Alan; Nelson, Warren Arthur

2001-01-01

A method for smoothing the surface of a ceramic-based protective coating which exhibits roughness is disclosed. The method includes the steps of applying a ceramic-based slurry or gel coating to the protective coating surface; heating the slurry/gel coating to remove volatile material; and then further heating the slurry/gel coating to cure the coating and bond it to the underlying protective coating. The slurry/gel coating is often based on yttria-stabilized zirconia, and precursors of an oxide matrix. Related articles of manufacture are also described.

Degradation of nonmodified and rhodium modified aluminide coating deposited on CMSX 4 superalloy.

PubMed

Zagula-Yavorska, Maryana; Wierzbińska, Małgorzata; Gancarczyk, Kamil; Sieniawski, Jan

2016-07-01

The Ni-base superalloy CMSX 4 used in the turbine blades of aircraft engines was coated with rhodium layer (0.5-μm thick). Next coated CMSX 4 superalloy was aluminized by the CVD method. The rhodium modified aluminide coating and nonmodified aluminide coating were oxidized at 1100°C at the air atmosphere. The rhodium modified aluminide coating showed about twice better oxidation resistance than the nonmodified one. The spallation equal 62% of the total area was observed on the surface of the nonmodified coating whereas only 36% spallation area was observed on the surface of the rhodium modified aluminide coating after the oxidation test. The oxide layer formed on the surface of the nonmodified coating was composed of nonprotective (Ni,Cr)Al2 O4 and (Ni,Cr)O phases. Aluminium in the coating reacts with oxygen, forming a protective α-Al2 O3 oxide on the surface of the rhodium modified aluminide coating. When the oxide cracks and spalls due to oxidation, additional aluminium from the coating diffuses to the surface to form the oxide. The presence of protective Al2 O3 oxide on the surface of the rhodium modified aluminide coating slows coating degradation. Therefore, rhodium modified aluminide coating has better oxidation resistance than the nonmodified one. © 2016 The Authors Journal of Microscopy © 2016 Royal Microscopical Society.

Preparation of magnetic core mesoporous shell microspheres with C18-modified interior pore-walls for fast extraction and analysis of phthalates in water samples.

PubMed

Li, Zhongbo; Huang, Danni; Fu, Chinfai; Wei, Biwen; Yu, Wenjia; Deng, Chunhui; Zhang, Xiangmin

2011-09-16

In this study, core-shell magnetic mesoporous microspheres with C18-functionalized interior pore-walls were synthesized through coating Fe(3)O(4) microspheres with a mesoporous inorganic-organic hybrid layer with a n-octadecyltriethoxysilane (C18TES) and tetraethyl orthosilicate (TEOS) as the silica source and cetyltrimethylammonia bromide (CTAB) as a template. The obtained C18-functionalized Fe(3)O(4)@mSiO(2) microspheres possess numerous C18 groups anchored in the interior pore-walls, large surface area (274.7 m(2)/g, high magnetization (40.8 emu/g) and superparamagnetism, uniform mesopores (4.1 nm), which makes them ideal absorbents for simple, fast, and efficient extraction and enrichment of hydrophobic organic compounds in water samples. Several kinds of phthalates were used as the model hydrophobic organic compounds to systematically evaluate the performance of the C18-functionalized Fe(3)O(4)@mSiO(2) microspheres in extracting hydrophobic molecules by using a gas chromatography-mass spectrometry. Various parameters, including eluting solvent, the amounts of absorbents, extraction time and elution time were optimized. Hydrophobic extraction was performed in the interior pore of magnetic mesoporous microspheres, and the materials had the anti-interference ability to macromolecular proteins, which was also investigated in the work. Under the optimized conditions, C18-functionalized Fe(3)O(4)@mSiO(2) microspheres were successfully used to analyze the real water samples. The results indicated that this novel method was fast, convenient and efficient for the target compounds and could avoid being interfered by macromolecules. Copyright © 2011 Elsevier B.V. All rights reserved.

40 CFR 63.5743 - What standards must I meet for aluminum recreational boat surface coating operations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... aluminum recreational boat surface coating operations? 63.5743 Section 63.5743 Protection of Environment... Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5743 What standards must I meet for aluminum recreational boat surface coating operations? (a) For...

Laser surface modification of Yttria Stabilized Zirconia (YSZ) thermal barrier coating on AISI H13 tool steel substrate

NASA Astrophysics Data System (ADS)

Reza, M. S.; Aqida, S. N.; Ismail, I.

2018-03-01

This paper presents laser surface modification of plasma sprayed yttria stabilized zirconia (YSZ) coating to seal porosity defect. Laser surface modification on plasma sprayed YSZ was conducted using 300W JK300HPS Nd: YAG laser at different operating parameters. Parameters varied were laser power and pulse frequency with constant residence time. The coating thickness was measured using IM7000 inverted optical microscope and surface roughness was analysed using two-dimensional Mitutoyo Surface Roughness Tester. Surface roughness of laser surface modification of YSZ H-13 tool steel decreased significantly with increasing laser power and decreasing pulse frequency. The re-melted YSZ coating showed higher hardness properties compared to as-sprayed coating surface. These findings were significant to enhance thermal barrier coating surface integrity for dies in semi-solid processing.

Development of a protective decorative fire resistant low smoke emitting, thermally stable coating material

NASA Technical Reports Server (NTRS)

1976-01-01

The development of suitable electrocoatings and subsequent application to nonconductive substrates are discussed. Substrates investigated were plastics or resin-treated materials such as FX-resin (phenolic-type resin) impregnated fiberglass mat, polyphenylene sulfide, polyether sulfone and polyimide-impregnated unidirectional fiberglass. Efforts were aimed at formulating a fire-resistant, low smoke emitting, thermally stable, easily cleaned coating material. The coating is to be used for covering substrate panels, such as aluminum, silicate foam, polymeric structural entities, etc., all of which are applied in the aircraft cabin interior and thus subject to the spillages, scuffing, spotting and the general contaminants which prevail in aircraft passenger compartments.

Fiber optic probe for light scattering measurements

DOEpatents

Nave, Stanley E.; Livingston, Ronald R.; Prather, William S.

1995-01-01

A fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman-scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Fiber optic probe for light scattering measurements

DOEpatents

Nave, S.E.; Livingston, R.R.; Prather, W.S.

1993-01-01

This invention is comprised of a fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman- scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Peptide-controlled access to the interior surface of empty virus nanoparticles.

PubMed

Sainsbury, Frank; Saunders, Keith; Aljabali, Alaa A A; Evans, David J; Lomonossoff, George P

2011-11-04

The structure of Cowpea mosaic virus (CPMV) is known to high resolution, thereby enabling the rational use of the particles in diverse applications, from vaccine design to nanotechnology. A recently devised method for the production of empty virus-like particles (eVLPs) has opened up new possibilities for CPMV capsid-based technologies, such as internal mineralisation of the particle. We have investigated the role of the carboxyl (C) terminus of the small coat (S) protein in controlling access to the interior of CPMV eVLPs by determining the efficiency of internal mineralisation. The presence of the C-terminal 24-amino acid peptide of the S protein was found to inhibit internal mineralisation, an effect that could be eliminated by enzymatic removal of this region. We have also demonstrated the amenability of the C terminus to genetic modification. Substitution with six histidine residues generated stable particles and facilitated external mineralisation by cobalt. These findings demonstrate consistent internal and external mineralisation of CPMV, and will aid the further exploration and development of the use of eVLPs for bionanotechnological and medical applications. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Neutron star Interior Composition Explorer (NICER)

NASA Image and Video Library

2017-12-08

A photo taken during the NICER range-of-motion test at NASA’s Goddard Space Flight Center shows the photographer’s reflection in the mirror-like radiator surface of the detector plate. Teflon-coated silver tape is used to keep NICER’s detectors cool. The Neutron star Interior Composition Explorer (NICER) is a NASA Explorer Mission of Opportunity dedicated to studying the extraordinary environments — strong gravity, ultra-dense matter, and the most powerful magnetic fields in the universe — embodied by neutron stars. An attached payload aboard the International Space Station, NICER will deploy an instrument with unique capabilities for timing and spectroscopy of fast X-ray brightness fluctuations. The embedded Station Explorer for X-ray Timing and Navigation Technology demonstration (SEXTANT) will use NICER data to validate, for the first time in space, technology that exploits pulsars as natural navigation beacons. Credit: NASA/Goddard/ Keith Gendreau NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Oceanus: A New Frontiers orbiter to study Titan's potential habitability

NASA Astrophysics Data System (ADS)

Sotin, Christophe; Hayes, Alex; Malaska, Michael; Nimmo, Francis; Trainer, Melissa; Tortora, Paolo

2017-04-01

The New Frontiers 4 AO includes the theme "Ocean Worlds (Titan and/or Enceladus)" focused on the search for signs of extant life and/or characterizing the potential habitability of Titan and/or Enceladus. The Cassini has demonstrated that Titan is an organic world of two oceans: surface hydrocarbon seas [1,2] that cover part of the north polar region and a deep water ocean [3] that decouples the outer ice crust from an inner core likely composed of hydrated silicates [4]. Oceanus is an orbiter that would follow up on Cassini's amazing discoveries and assess Titan's habitability by following the organics through the methanologic cycle and assessing ex-change processes between the atmosphere, surface, and subsurface. Titan's reduced nitrogen-rich atmosphere operates as an organic factory [5] where heavy organic molecules are produced by a series of reations starting by the photolysis of methane [6,7]. The mass spectrometer will perform high-resolution in situ measurements of the organic material over a large mass range and at different altitudes. It will provide the information required to determine (i) the processes at work to form the heavy molecules, (ii) the functional group pattern of large molecules providing information on their composition. These organics coat Titan's surface and are moved around through a complex source-to-sink sediment transport system analogous to surface processes here on Earth. Titan's 90-95 K surface temperature at 1.5 bar surface pressure permit me-thane and ethane to condense out of the atmosphere and flow as liquids on the surface. As a result, Titan's methane-based hydrologic system produces a rich set of geologic features (dunes, river net-works, polar lakes/seas, etc.). Cassini's observations of this rich geomorphology is hindered by kilometer-scale resolution. Oceanus will take ad-vantage of a narrow atmospheric window at 5 µm to acquire 25 m/pixel (< 100 m resolution) images of Titan diverse surface [8]. The presence of 40Ar, a product of the decay of 40K contained in the silicate core, and methane whose origin is still controversial argue for ex-change processes between the interior and the atmosphere. Like we see here on Earth, these processes will be chronicled in the interaction between geological features on Titan's surface. Oceanus will investigate specific features identified by Cassini as potential candidates for cryvolcanism, impact, and tectonic processes that could facilitate exchange with the interior. Acknowledgments: This work has been per-formed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. References: [1] Stofan E.R. et al. (2007) Nature. [2] Sotin C. et al. (2012) Icarus. [3] Iess L. et al. (2012) Science. [4] Castillo-Rogez J.C. and Lunine J.I. (2010) Geophys. Res. Lett. [5] Coates A.J. et al. (2007) Geophys. Res. Let. [6] Lavvas P. et al. (2008) Planet. Space Sci. [7] Yung Y.L. et al. (1984) Astrophys. J. [8] Sotin C. et al. (2005) Nature.

43 CFR 4.1383 - Hearing.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 43 Public Lands: Interior 1 2014-10-01 2014-10-01 false Hearing. 4.1383 Section 4.1383 Public Lands: Interior Office of the Secretary of the Interior DEPARTMENT HEARINGS AND APPEALS PROCEDURES Special Rules Applicable to Surface Coal Mining Hearings and Appeals Review of Office of Surface Mining...

The Nonrandom Distribution of Interior Landforms for 100-km Diameter Craters on Mercury Suggests Regional Variations in Near-Surface Mechanical Properties

NASA Astrophysics Data System (ADS)

Herrick, R. R.

2018-05-01

There is great diversity of appearance in the interiors of 100-km diameter craters. The spatial distribution of interior landforms is clustered and nonrandom, but does not clearly correlate with Mercury's surface geology patterns.

43 CFR 4.1383 - Hearing.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 43 Public Lands: Interior 1 2010-10-01 2010-10-01 false Hearing. 4.1383 Section 4.1383 Public Lands: Interior Office of the Secretary of the Interior DEPARTMENT HEARINGS AND APPEALS PROCEDURES Special Rules Applicable to Surface Coal Mining Hearings and Appeals Review of Office of Surface Mining...

Tribological performance of quaternary CrSiCN coatings under dry and lubricated conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lorenzo-Martin, C.; Ajayi, O.; Erdemir, A.

This paper presents an experimental study of friction and wear performance of quaternary CrSiCN coatings deposited on a hardened H-13 steel substrate by a plasma enhanced magnetron sputtering (PEMS) technique. Friction and wear tests were conducted with a reciprocating line contact between a hardened 4370 steel roller and coated and uncoated flat specimens under dry and lubricated conditions. The effects of coating thickness (1, 3.5 and 7.5 μm) on the mechanical properties, friction and wear performance were also assessed. In dry sliding, the friction of coated surfaces was about the same as for uncoated surfaces, except for the 1-μm coating,more » which had higher friction. Friction for coated surfaces under lubricated contact was in general higher than for uncoated surfaces. There was no measurable wear on any of the coated surfaces, under either dry or lubricated conditions. However, wear was higher on the steel roller counterface sliding against the coated surfaces, with the amount of wear proportional to the mating coating thickness. The effectiveness of formulated lubricant additives was also modified by the coating, resulting in major effects on friction and wear behavior. Finally, this reduction in lubricant additive efficacy is due to the fact that the additives were designed and optimized for ferrous surfaces.« less

Tribological performance of quaternary CrSiCN coatings under dry and lubricated conditions

DOE PAGES

Lorenzo-Martin, C.; Ajayi, O.; Erdemir, A.; ...

2017-06-15

This paper presents an experimental study of friction and wear performance of quaternary CrSiCN coatings deposited on a hardened H-13 steel substrate by a plasma enhanced magnetron sputtering (PEMS) technique. Friction and wear tests were conducted with a reciprocating line contact between a hardened 4370 steel roller and coated and uncoated flat specimens under dry and lubricated conditions. The effects of coating thickness (1, 3.5 and 7.5 μm) on the mechanical properties, friction and wear performance were also assessed. In dry sliding, the friction of coated surfaces was about the same as for uncoated surfaces, except for the 1-μm coating,more » which had higher friction. Friction for coated surfaces under lubricated contact was in general higher than for uncoated surfaces. There was no measurable wear on any of the coated surfaces, under either dry or lubricated conditions. However, wear was higher on the steel roller counterface sliding against the coated surfaces, with the amount of wear proportional to the mating coating thickness. The effectiveness of formulated lubricant additives was also modified by the coating, resulting in major effects on friction and wear behavior. Finally, this reduction in lubricant additive efficacy is due to the fact that the additives were designed and optimized for ferrous surfaces.« less

Comparison of self-cleaning properties of three titania coatings on float glass

NASA Astrophysics Data System (ADS)

Piispanen, Minna; Hupa, Leena

2011-11-01

This work compares the self-cleaning properties of experimental TiO2 and TiO2-Ag coatings on float glass with a commercial self-cleaning glass. In the experimental surfaces, TiO2 coating was applied to float glass via the sol-gel route, while TiO2-Ag coating was applied by the liquid flame spray method, which deposits TiO2-Ag composite nanoparticles on the surface. The effect of the coatings on the surface wettability and the activation time for achieving hydrophilicity was studied through water contact angle as a function of exposure time to UV light. The surface morphology was investigated by using scanning electron microscopy (SEM) and confocal optical microscopy. The photocatalytic activity of the coatings was examined with methylene blue and stearic acid degradation tests. Finally, the soil attachment to the surfaces was tested with a sebum-based model soil. The sol-gel TiO2 coating became superhydrophilic within a few hours, while the activation time needed for the commercial titania coated glass was several days. The surface with the TiO2-Ag nanoparticles did not show any marked changes in the water contact angle. The commercial titania coated and the sol-gel TiO2 surfaces showed self-cleaning properties and clearly lower attachment of soil than the uncoated and TiO2-Ag coated surfaces. The difference in the interaction of the surfaces with the organic contaminants was assumed to depend mainly on differences in the thickness of the coatings.

Cathodic Polarization Coats Titanium Based Implant Materials with Enamel Matrix Derivate (EMD)

PubMed Central

Frank, Matthias J.; Walter, Martin S.; Rubert, Marina; Thiede, Bernd; Monjo, Marta; Reseland, Janne E.; Haugen, Håvard J.; Lyngstadaas, Ståle Petter

2014-01-01

The idea of a bioactive surface coating that enhances bone healing and bone growth is a strong focus of on-going research for bone implant materials. Enamel matrix derivate (EMD) is well documented to support bone regeneration and activates growth of mesenchymal tissues. Thus, it is a prime candidate for coating of existing implant surfaces. The aim of this study was to show that cathodic polarization can be used for coating commercially available implant surfaces with an immobilized but functional and bio-available surface layer of EMD. After coating, XPS revealed EMD-related bindings on the surface while SIMS showed incorporation of EMD into the surface. The hydride layer of the original surface could be activated for coating in an integrated one-step process that did not require any pre-treatment of the surface. SEM images showed nano-spheres and nano-rods on coated surfaces that were EMD-related. Moreover, the surface roughness remained unchanged after coating, as it was shown by optical profilometry. The mass peaks observed in the matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF MS) analysis confirmed the integrity of EMD after coating. Assessment of the bioavailability suggested that the modified surfaces were active for osteoblast like MC3M3-E1 cells in showing enhanced Coll-1 gene expression and ALP activity. PMID:28788564

Osseointegrated dental implants produced via microwave processing

NASA Astrophysics Data System (ADS)

Kutty, Muralithran G.

This research is a comprehensive effort to develop osseointegrated dental implants via microwave processing. A net-shape microwave sintering procedure was employed to fabricate dental implants. Commercial pure titanium powders (-100, -200 and -325 mesh sizes) were used in this work. This process eliminates the need for machining of implants and prevents contamination. The idea was to take advantage of the peculiar way microwave couple with metallic powders, i.e. generating heat in the interior of the sample and dissipating it away through the surface. The desired features for an implant, a dense core with surface pores, is not possible via conventional sintering. Coating with hydroxyapatite via electrodeposition and chemical combustion vapor deposition was also attempted to further enhance the bioactivity of this layer. Surface roughness and area were measured using a non-contact surface profilometer to further describe the unique surface. In-vitro studies, conducted using osteoblast cells extracted from neonatal rat calvarial, showed improved cell growth on all the uncoated porous samples. However, the highest cell growth was observed on the -200 mesh size samples. The higher surface area of the -200 mesh samples is attributed to this observation. This work was able to identify the processing parameters for titanium in microwave and establishes the importance of surface area as a key parameter for cell growth on porous surfaces as compared to surface roughness.

Transverse electromagnetic horn antenna with resistively-loaded exterior surfaces

DOEpatents

Aurand, John F.

1999-01-01

An improved transverse electromagnetic (TEM) horn antenna comprises a resistive loading material on the exterior surfaces of the antenna plates. The resistive loading material attenuates or inhibits currents on the exterior surfaces of the TEM horn antenna. The exterior electromagnetic fields are of opposite polarity in comparison to the primary and desired interior electromagnetic field, thus inherently cause partial cancellation of the interior wave upon radiation or upon reception. Reducing the exterior fields increases the radiation efficiency of the antenna by reducing the cancellation of the primary interior field (supported by the interior surface currents). This increases the transmit gain and receive sensitivity of the TEM horn antenna, as well as improving the transient (time-domain) response.

Scratch and wear behaviour of plasma sprayed nano ceramics bilayer Al2O3-13 wt%TiO2/hydroxyapatite coated on medical grade titanium substrates in SBF environment

NASA Astrophysics Data System (ADS)

Palanivelu, R.; Ruban Kumar, A.

2014-10-01

Among the various coating techniques, plasma spray coating is an efficient technique to protect the metal surface from the various surface problems like wear and corrosion. The aim of this present work is to design and produce a bilayer coating on the non- toxic commercially pure titanium (denoted as CP-Ti) implant substrate in order to improve the biocompatibility and surface properties. To achieve that, Al2O3-13 wt%TiO2 (AT13) and hydroxyapatite (HAP) were coated on CP-Ti implant substrate using plasma spray coating technique. Further, the coated substrates were subjected to various characterization techniques. The crystallite size of coated HAP and its morphological studies were carried out using X-ray diffractometer (XRD) and scanning electron microscopy (SEM) respectively. The wear test on the bilayer (AT13/HAP) coated CP-Ti implant surface was conducted using ball-on-disc tester under SBF environment at 37 °C, in order to determine the wear rate and the coefficient of friction. The adhesion strength of the bilayer coated surface was evaluated by micro scratch tester under the ramp load conditions with load range of 14-20 N. The above said studies were repeated on the single layer coated HAP and AT13 implant surfaces. The results reveal that the bilayer (AT13/HAP) coated CP-Ti surface has the improved wear rate, coefficient of friction in compared to single layer coated HAP and AT13 surfaces.

Respiratory Mechanics and Gas Exchange: The Effect of Surfactants

NASA Astrophysics Data System (ADS)

Jbaily, Abdulrahman; Szeri, Andrew J.

2017-11-01

The purpose of the lung is to exchange gases, primarily oxygen and carbon dioxide, between the atmosphere and the circulatory system. To enable this exchange, the airways in the lungs terminate in some 300 million alveoli that provide adequate surface area for transport. During breathing, work must be done to stretch various tissues to accommodate a greater volume of gas. Considerable work must also be done to expand the liquid lining (hypophase) that coats the interior surfaces of the alveoli. This is enabled by a surface active lipo-protein complex, known as pulmonary surfactant, that modifies the surface tension at the hypophase-air interface. Surfactants also serve as physical barriers that modify the rate of gas transfer across interfaces. We develop a mathematical model to study the action of pulmonary surfactant and its determinative contributions to breathing. The model is used to explore the influence of surfactants on alveolar mechanics and on gas exchange: it relates the work of respiration at the level of the alveolus to the gas exchange rate through the changing influence of pulmonary surfactant over the breathing cycle. This work is motivated by a need to develop improved surfactant replacement therapies to treat serious medical conditions.

[Surface modification of dental alumina ceramic with silica coating].

PubMed

Xie, Hai-Feng; Zhang, Fei-Min; Wang, Xiao-Zu; Xia, Yang

2006-12-01

To make silica coating through sol-gel process, and to evaluate the wettability of dental alumina ceramic with or without coating. Silica coating was prepared with colloidal silica sol on In-Ceram alumina ceramic surface which had been treated with air particle abrasion. Coating gel after heat treatment was observed with atomic force microscope (AFM), and was analyzed by infrared spectrum (IR) with gel without sintered as control. Contact angles of oleic acid to be finished, sandblasted and coated ceramic surface of were measured. AFM pictures showed that some parts of nano-particles in coating gel conglomerated after heat treatment. It can be seen from the IR picture that bending vibration absorption kurtosis of Si-OH also vanished after heat treatment. Among contact angles of three treated surface, the ones on polished surface were the biggest (P = 0.000, P = 0.000), and sandblasting+silica coating surface the smallest (P = 0.000, P = 0.003). Silica coating can be made with sol-gel process successfully. Heat treatment may reinforce Si-O-Si net structure of coating gel. Wettability of dental alumina ceramic with silica coating is higher than with sandblasting and polishing.

40 CFR 745.63 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., but not limited to, certain window, floor, and stair surfaces. Impact surface means an interior or.... Interior window sill means the portion of the horizontal window ledge that protrudes into the interior of... based on the equation [60+(3*100)+(4*110)]/(1+3+4). Window trough means, for a typical double-hung...

Spectral force analysis using atomic force microscopy reveals the importance of surface heterogeneity in bacterial and colloid adhesion to engineered surfaces.

PubMed

Ma, Huilian; Winslow, Charles J; Logan, Bruce E

2008-04-01

Coatings developed to reduce biofouling of engineered surfaces do not always perform as expected based on their native properties. One reason is that a relatively small number of highly adhesive sites, or the heterogeneity of the coated surface, may control the overall response of the system to initial bacterial deposition. It is shown here using an approach we call spectral force analysis (SFA), based on force volume imaging of the surface with atomic force microscopy, that the behavior of surfaces and coatings can be better understood relative to bacterial adhesion. The application of vapor deposited TiO(2) metal oxide increased bacterial and colloid adhesion, but coating the surface with silica oxide reduced adhesion in a manner consistent with SFA based on analysis of the "stickiest" sites. Application of a TiO(2)-based paint to a surface produced a relatively non-fouling surface. Addition of a hydrophilic layer coating to this surface should have decreased fouling. However, it was observed that this coating actually increased fouling. Using SFA it was shown that the reason for the increased adhesion of bacteria and particles to the hydrophilic layer was that the surface produced by this coating was highly heterogeneous, resulting in a small number of sites that created a stickier surface. These results show that while it is important to manufacture surfaces with coatings that are relatively non-adhesive to bacteria, it is also essential that these coatings have a highly uniform surface chemistry.

A Novel Hybrid Ultramicrotomy/FIB-SEM Technique: Preparation of Serial Electron-Transparent Thin Sections of a Hayabusa Grain

NASA Technical Reports Server (NTRS)

Berger, Eve L.; Keller, Lindsay P.

2014-01-01

The Japanese space agency's (JAXA) Hayabusa mission returned the first particulate samples (typically <100micron) from the surface of an asteroid (25143 Itokawa). These precious samples provide important insights into early Solar System processes, but their sizes pose tremendous challenges to coordinated analysis using a variety of nano- and micro-beam techniques. The ability to glean maximal information from individual particles has become increasingly important and depends critically on sample preparation. We developed a hybrid technique combining traditional ultramicrotomy with focused ion beam (FIB) techniques, allowing for more thorough in situ investigations of grain surfaces and interiors. Using this method, we increase the number of FIB-prepared sections that can be recovered from a particle with dimensions on the order of tens of microns. These sections can be subsequently analyzed using a variety of analytical techniques. Particle RA-QD02-0211 is a approx. 40×40×20 micron particle from Itokawa containing olivine and Fe sulfides. It was embedded in low viscosity epoxy and partly sectioned to a depth of approx 10 micron; sections are placed on Cu grids with thin amorphous films for transmission electron microscope (TEM) analyses. With the sample surface partly exposed, the epoxy bullet is trimmed to a height of approx. 5mm to accommodate the allowable dimensions for FIB work (FEI Quanta 600 3D dual beam FIB-SEM). Using a diamond trim knife, the epoxy surrounding the grain is removed on 3 sides (to within a few microns of the grain); the depth of material removed extends well below the bottom of the particle. The sample is attached to an SEM pin mount, the epoxy coated with conductive paint, and the entire assembly coated with approx. 40nm of carbon to eliminate sample charging during FIB work. A protective carbon cap is placed according to the plan for the 15 FIB sections. The central 'spine' of the cap runs perpendicular to the front of the sample, and the 'ribs' protruding from either side run parallel. Each rib indicates the location of a planned FIB section, and the spine contains the final two planned sections. We use a cap with a 4 micron-wide spine and 2micron-wide ribs that have ?3.5 micron of space between them (narrower cuts result in too much re-deposition of material inside the trenches). Using a 30kV, 3nA ion-beam we expose the front surface of the grain and commence milling trenches between sections. Rather than using the typical C-cut to prepare the sample for lift-out, an L-cut is used instead, leaving the sample connected by an interior tab. tab. Sections are lifted out, attached to TEM grids and thinned to electron transparency. TEM analyses show that our hybrid technique preserves both interior and edge features, including surface modifications from exposure to the space environment, such as damaged rims that form in response to solar wind implantation effects and adhering grains. In addition, the FIB sections provide larger areas that are free of fractures and chatter effects in comparison to the microtome thin sections, thus enabling more accurate measurements of solar flare particle track densities that are used to determine the surface exposure age of the particles.

Thin Refractory Films on Fused Silica Crucibles

DTIC Science & Technology

1988-07-01

9 4.1.4 Iridium 11 4.1.5 Boron Nitride (BN) 11 4.2 Adherence Testing 13 4.3 Metallography 13 5.0 Conclusions and Recommendations 16 Accession For...Chamber 4 2. Schematic of Crucible Coating Apparatus (SiC, NbN, and TiB 2) 6 3. Schematic of CVD Apparatus for Iridium 7 4. Schematic of Apparatus for...ultrahigh-purity coatings of silicon carbide (SiC), niobium nitride (NbN), titanium diboride (TiB2), iridium , and boron nitride (BN) onto the interior

Mechanical Properties of Degraded PMR-15 Resin

NASA Technical Reports Server (NTRS)

Tsuji, Luis C.

2000-01-01

Thermo-oxidative aging produces a nonuniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hr. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and coefficient of thermal expansion (CTE) of nitrogen aged specimens were measured directly. The nitrogen-aged specimens were assumed to have the same properties as the interior material in the air-aged specimens. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

40 CFR 63.5752 - How do I calculate the organic HAP content of aluminum recreational boat surface coatings?

Code of Federal Regulations, 2013 CFR

2013-07-01

... content of aluminum recreational boat surface coatings? 63.5752 Section 63.5752 Protection of Environment... Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5752 How do I calculate the organic HAP content of aluminum recreational boat surface coatings? (a) Use...

40 CFR 63.5752 - How do I calculate the organic HAP content of aluminum recreational boat surface coatings?

Code of Federal Regulations, 2014 CFR

2014-07-01

... content of aluminum recreational boat surface coatings? 63.5752 Section 63.5752 Protection of Environment... Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5752 How do I calculate the organic HAP content of aluminum recreational boat surface coatings? (a) Use...

40 CFR 63.5752 - How do I calculate the organic HAP content of aluminum recreational boat surface coatings?

Code of Federal Regulations, 2012 CFR

2012-07-01

... content of aluminum recreational boat surface coatings? 63.5752 Section 63.5752 Protection of Environment... Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5752 How do I calculate the organic HAP content of aluminum recreational boat surface coatings? (a) Use...

Coating formulation and method for refinishing the surface of surface-damaged graphite articles

DOEpatents

Ardary, Z.L.; Benton, S.T.

1987-07-08

The described development is directed to a coating formulation for filling surface irregularities in graphite articles such as molds, crucibles, and matched die sets used in high-temperature metallurgical operations. The coating formulation of the present invention is formed of carbon black flour, thermosetting resin and a solvent for the resin. In affixing the coating to the article, the solvent is evaporated, the resin cured to bond the coating to the surface of the article and then pyrolyzed to convert the resin to carbon. Upon completion of the pyrolysis step, the coating is shaped and polished to provide the article with a surface restoration that is essentially similar to the original or desired surface finish without the irregularity.

Coating formulation and method for refinishing the surface of surface-damaged graphite articles

DOEpatents

Ardary, Zane L.; Benton, Samuel T.

1988-01-01

The described development is directed to a coating formulation for filling surface irregularities in graphite articles such as molds, crucibles, and matched die sets used in high-temperature metallurgical operations. The coating formulation of the present invention is formed of carbon black flour, thermosetting resin and a solvent for the resin. In affixing the coating to the article, the solvent is evaporated, the resin cured to bond the coating to the surface of the article and then pyrolyzed to convert the resin to carbon. Upon completion of the pyrolysis step, the coating is shaped and polished to provide the article with a surface restoration that is essentially similar to the original or desired surface finish without the irregularity.

Coating formulation and method for refinishing the surface of surface-damaged graphite articles

DOEpatents

Ardary, Z.L.; Benton, S.T.

1988-11-22

The described development is directed to a coating formulation for filling surface irregularities in graphite articles such as molds, crucibles, and matched die sets used in high-temperature metallurgical operations. The coating formulation of the present invention is formed of carbon black flour, thermosetting resin and a solvent for the resin. In affixing the coating to the article, the solvent is evaporated, the resin cured to bond the coating to the surface of the article and then pyrolyzed to convert the resin to carbon. Upon completion of the pyrolysis step, the coating is shaped and polished to provide the article with a surface restoration that is essentially similar to the original or desired surface finish without the irregularity.

14 CFR 29.853 - Compartment interiors.

Code of Federal Regulations, 2010 CFR

2010-01-01

... towels, paper, or waste must be at least fire-resistant and must have means for containing possible fires... AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Design and Construction Fire Protection § 29.853... and nondecorative coated fabrics, leather, trays and galley furnishings, electrical conduit, thermal...

76 FR 38992 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Update to Materials...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-05

... Definitions 5/24/10 12/28/10, 75 FR 81555... Addition of four new definitions: Exterior panels, interior panels, flat wood panel coating, and tileboard. See Part III of the IBR document. * * * * * * Part E...

Antimicrobial and osteogenic properties of a hydrophilic-modified nanoscale hydroxyapatite coating on titanium.

PubMed

Murakami, Asuka; Arimoto, Takafumi; Suzuki, Dai; Iwai-Yoshida, Misato; Otsuka, Fukunaga; Shibata, Yo; Igarashi, Takeshi; Kamijo, Ryutaro; Miyazaki, Takashi

2012-04-01

Hydroxyapatite (HA)-coated titanium (Ti) is commonly used for implantable medical devices. This study examined in vitro osteoblast gene expression and antimicrobial activity against early and late colonizers of supra-gingival plaque on nanoscale HA-coated Ti prepared by discharge in a physiological buffered solution. The HA-coated Ti surface showed super-hydrophilicity, whereas the densely sintered HA and Ti surfaces alone showed lower hydrophilicity. The sintered HA and HA-coated Ti surfaces enhanced osteoblast phenotypes in comparison with the bare Ti surface. The HA-coated Ti enabled antimicrobial activity against early colonizers of supra-gingival plaques, namely Streptococcus mitis and Streptococcus gordonii. Such antimicrobial activity may be caused by the surface hydrophilicity, thereby leading to a repulsion force between the HA-coated Ti surface and the bacterial cell membranes. On the contrary, the sintered HA sample was susceptible to infection of microorganisms. Thus, hydrophilic-modified HA-coated Ti may have potential for use in implantable medical devices. From the Clinical Editor: This study establishes that Hydroxyapatite (HA)-coated titanium (Ti) surface of implanted devices may result in an optimal microenvironment to control and prevent infections and may have potential future clinical applications. Copyright © 2012 Elsevier Inc. All rights reserved.

Involvement of vesicle coat material in casein secretion and surface regeneration

PubMed Central

1976-01-01

The ultrastructure of the apical zone of lactating rat mammary epithelial cells was studied with emphasis on vesicle coat structures. Typical 40-60 nm ID "coated vesicles" were abundant, frequently associated with the internal filamentous plasma membrane coat or in direct continuity with secretory vesicles (SV) or plasma membrane proper. Bristle coats partially or totally covered membranes of secretory vesicles identified by their casein micelle content. This coat survived SV isolation. Exocytotic fusion of SV membranes and release of the casein micelles was observed. Frequently, regularly arranged bristle coat structures were identified in those regions of the plasma membrane that were involved in exocytotic processes. Both coated and uncoated surfaces of the casein-containing vesicles, as well as typical "coated vesicles", were frequently associated with microtubules and/or microfilaments. We suggest that coat materials of vesicles are related or identical to components of the internal coat of the surface membrane and that new plasma membrane and associated internal coat is produced concomitantly by fusion and integration of bristle coat moieties. Postexocytotic association of secreted casein micelles with the cell surface, mediated by finely filamentous extensions, provided a marker for the integrated vesicle membrane. An arrangement of SV with the inner surface of the plasma membrane is described which is characterized by regularly spaced, heabily stained membrane to membrane cross-bridges (pre-exocytotic attachment plaques). Such membrane-interconnecting elements may represent a form of coat structure important to recognition and interaction of membrane surfaces. PMID:1254641

Sector-based VOCs emission factors and source profiles for the surface coating industry in the Pearl River Delta region of China.

PubMed

Zhong, Zhuangmin; Sha, Qing'e; Zheng, Junyu; Yuan, Zibing; Gao, Zongjiang; Ou, Jiamin; Zheng, Zhuoyun; Li, Cheng; Huang, Zhijiong

2017-04-01

Accurate depiction of VOCs emission characteristics is essential for the formulation of VOCs control strategies. As one of the continuous efforts in improving VOCs emission characterization in the Pearl River Delta (PRD) region, this study targeted on surface coating industry, the most important VOCs emission sources in the PRD. Sectors in analysis included shipbuilding coating, wood furniture coating, metal surface coating, plastic surface coating, automobile coating and fabric surface coating. Sector-based field measurement was conducted to characterize VOCs emission factors and source profiles in the PRD. It was found that the raw material-based VOCs emission factors for these six sectors ranged from 0.34 to 0.58kg VOCs per kg of raw materials (kg·kg -1 ) while the emission factors based on the production yield varied from 0.59kg to 13.72t VOCs for each production manufactured. VOCs emission factors of surface coating industry were therefore preferably calculated based on raw materials with low uncertainties. Source profiles differed greatly among different sectors. Aromatic was the largest group for shipbuilding coating, wood furniture coating, metal surface coating and automobile coating while the oxygenated VOCs (OVOCs) were the most abundant in the plastic and fabric surface coating sectors. The major species of aromatic VOCs in each of these six sectors were similar, mainly toluene and m/p-xylene, while the OVOCs varied among the different sectors. VOCs profiles in the three processes of auto industry, i.e., auto coating, auto drying and auto repairing, also showed large variations. The major species in these sectors in the PRD were similar with other places but the proportions of individual compounds were different. Some special components were also detected in the PRD region. This study highlighted the importance of updating local source profiles in a comprehensive and timely manner. Copyright © 2016 Elsevier B.V. All rights reserved.

Surface topographical effects on the structural growth of thick sputtered metal and alloy coatings

NASA Technical Reports Server (NTRS)

Spalvins, T.; Brainard, W. A.

1974-01-01

Thick sputtered S-Monel, silver, and 304 stainless steel coatings were deposited on mica and metal substrates with various surface finishes to investigate the structural growth of the coating by scanning electron microscopy. The geometry and the surface structure of the nodules are characterized. Compositional changes within the coating were analyzed by X-ray dispersion microscopy. Defects in the surface finish (i.e., scratches, inclusions, etc.) act as preferential nucleation sites and form isolated and complex nodules and various surface overgrowths in the coating. The nodule boundaries are very vulnerable to chemical etching and these nodules do not disappear after full annealing. Further, they have undesirable effects on mechanical properties; cracks are initiated at the nodules when the coating is stressed by mechanical forces. These effects are illustrated by micrographs. Nodular growth within a coating can be minimized or eliminated by reducing the surface roughness.

Surface Characteristics of Silicon Nanowires/Nanowalls Subjected to Octadecyltrichlorosilane Deposition and n-octadecane Coating

PubMed Central

Yilbas, Bekir Sami; Salhi, Billel; Yousaf, Muhammad Rizwan; Al-Sulaiman, Fahad; Ali, Haider; Al-Aqeeli, Nasser

2016-01-01

In this study, nanowires/nanowalls were generated on a silicon wafer through a chemical etching method. Octadecyltrichlorosilane (OTS) was deposited onto the nanowire/nanowall surfaces to alter their hydrophobicity. The hydrophobic characteristics of the surfaces were further modified via a 1.5-μm-thick layer of n-octadecane coating on the OTS-deposited surface. The hydrophobic characteristics of the resulting surfaces were assessed using the sessile water droplet method. Scratch and ultraviolet (UV)-visible reflectivity tests were conducted to measure the friction coefficient and reflectivity of the surfaces. The nanowires formed were normal to the surface and uniformly extended 10.5 μm to the wafer surface. The OTS coating enhanced the hydrophobic state of the surface, and the water contact angle increased from 27° to 165°. The n-octadecane coating formed on the OTS-deposited nanowires/nanowalls altered the hydrophobic state of the surface. This study provides the first demonstration that the surface wetting characteristics change from hydrophobic to hydrophilic after melting of the n-octadecane coating. In addition, this change is reversible; i.e., the hydrophilic surface becomes hydrophobic after the n-octadecane coating solidifies at the surface, and the process again occurs in the opposite direction after the n-octadecane coating melts. PMID:27934970

Trailing edge cooling using angled impingement on surface enhanced with cast chevron arrangements

DOEpatents

Lee, Ching-Pang; Heneveld, Benjamin E.; Brown, Glenn E.; Klinger, Jill

2015-05-26

A gas turbine engine component, including: a pressure side (12) having an interior surface (34); a suction side (14) having an interior surface (36); a trailing edge portion (30); and a plurality of suction side and pressure side impingement orifices (24) disposed in the trailing edge portion (30). Each suction side impingement orifice is configured to direct an impingement jet (48) at an acute angle (52) onto a target area (60) that encompasses a tip (140) of a chevron (122) within a chevron arrangement (120) formed in the suction side interior surface. Each pressure side impingement orifice is configured to direct an impingement jet at an acute angle onto an elongated target area that encompasses a tip of a chevron within a chevron arrangement formed in the pressure side interior surface.

Scattered Atomic Oxygen Effects on Spacecraft Materials

NASA Technical Reports Server (NTRS)

Banks, Bruce A.; Miller, Sharon K. R.; deGroh, Kim K.; Demko, Rikako

2003-01-01

Low Earth orbital (LEO) atomic oxygen cannot only erode the external surfaces of polymers on spacecraft, but can cause degradation of surfaces internal to components on the spacecraft where openings to the space environment exist. Although atomic oxygen attack on internal or interior surfaces may not have direct exposure to the LEO atomic oxygen flux scattered impingement can have serious degradation effects where sensitive interior surfaces are present. The effects of atomic oxygen erosion of polymer interior to an aperture on a spacecraft is simulated using Monte Carlo computational techniques. A 2-dimensional model is used to provide quantitative indications of the attenuation of atomic oxygen flux as a function of distance into a parallel walled cavity. The degree of erosion re1ative is compared between the various interior locations and the external surface of a LEO spacecraft.

Atomic Oxygen Effects on Spacecraft Materials

NASA Technical Reports Server (NTRS)

Banks, Bruce A.; Miller, Sharon K. R.; deGroh, Kim K.; Demko, Rikako

2003-01-01

Low Earth orbital (LEO) atomic oxygen cannot only erode the external surfaces of polymers on spacecraft, but can cause degradation of surfaces internal to components on the spacecraft where openings to the space environment exist. Although atomic oxygen attack on internal or interior surfaces may not have direct exposure to the LEO atomic oxygen flux, scattered impingement can have can have serious degradation effects where sensitive interior surfaces are present. The effects of atomic oxygen erosion of polymers interior to an aperture on a spacecraft is simulated using Monte Carlo computational techniques. A 2-dimensional model is used to provide quantitative indications of the attenuation of atomic oxygen flux as a function of distance into a parallel walled cavity. The degree of erosion relative is compared between the various interior locations and the external surface of an LEO spacecraft.

Temperature sensitive surfaces and methods of making same

DOEpatents

Liang, Liang [Richland, WA; Rieke, Peter C [Pasco, WA; Alford, Kentin L [Pasco, WA

2002-09-10

Poly-n-isopropylacrylamide surface coatings demonstrate the useful property of being able to switch charateristics depending upon temperature. More specifically, these coatings switch from being hydrophilic at low temperature to hydrophobic at high temperature. Research has been conducted for many years to better characterize and control the properties of temperature sensitive coatings. The present invention provides novel temperature sensitive coatings on articles and novel methods of making temperature sensitive coatings that are disposed on the surfaces of various articles. These novel coatings contain the reaction products of n-isopropylacrylamide and are characterized by their properties such as advancing contact angles. Numerous other characteristics such as coating thickness, surface roughness, and hydrophilic-to-hydrophobic transition temperatures are also described. The present invention includes articles having temperature-sensitve coatings with improved properties as well as improved methods for forming temperature sensitive coatings.

Sputtered protective coatings for die casting dies

NASA Technical Reports Server (NTRS)

Mirtich, M. J.; Nieh, C.-Y.; Wallace, J. F.

1981-01-01

Three experimental research designs investigating candidate materials and processes involved in protective die surface coating procedures by sputter deposition, using ion beam technologies, are discussed. Various pre-test results show that none of the coatings remained completely intact for 15,000 test cycles. The longest lifetime was observed for coatings such as tungsten, platinum, and molybdenum which reduced thermal fatigue, but exhibited oxidation and suppressed crack initiation only as long as the coating did not fracture. Final test results confirmed earlier findings and coatings with Pt and W proved to be the candidate materials to be used on a die surface to increase die life. In the W-coated specimens, which remained intact on the surface after thermal fatigue testing, no oxidation was found under the coating, although a few cracks formed on the surface where the coating broke down. Further research is planned.

Concept for Hydrogen-Impregnated Nanofiber/Photovoltaic Cargo Stowage System

NASA Technical Reports Server (NTRS)

Kennedy, Kriss J.; Toups, Larry David; Howard, Robert L.; Poffenberger, Jaso Eric

2012-01-01

A stowage system was conceived that consists of collapsible, reconfigurable stowage bags, rigid polyethylene or metal inserts, stainless-steel hooks, flexible photovoltaic materials, and webbing curtains that provide power generation, thermal stabilization, impact resistance, work/sleeping surfaces, and radiation protection to spaceflight hardware and crew members. Providing materials to the Lunar surface is costly from both a mass and a volume standpoint. Most of the materials that will be transferred to other planets or celestial bodies will not be returned to the Earth. In developing a plan to reconfigure pressurized logistics modules, it was determined that there was a requirement to be able to utilize the interior volume of these modules and transform them from Logistics Modules to Storage/Living Quarters. Logistics-to-living must re-utilize stowage bags and the structures that support them to construct living spaces, partitions, furniture, protective shelters from solar particle events, galactic cosmic radiation, and workspaces. In addition to reusing these logistics items for development of the interior living spaces, these items could also be reused outside the habitable volumes to build berms that protect assets from secondary blast ejecta, to define pathways, to stabilize high traffic areas, to protect against dust contamination, to secure assets to mobility elements, to provide thermal protection, and to create other types of protective shelters for surface experiments. Unique features of this innovation include hydrogen-impregnated nano fibers encapsulated in a polyethelyne coating that act as radiation shielding, flexible solar collection cells that can be connected together with cells from other bags via the webbing walls to create a solar array, and the ability to reconfigure each bag to satisfy multiple needs.

Chitosan/titanium dioxide nanocomposite coatings: Rheological behavior and surface application to cellulosic paper.

PubMed

Tang, Yanjun; Hu, Xiulan; Zhang, Xinqi; Guo, Daliang; Zhang, Junhua; Kong, Fangong

2016-10-20

Incorporation of nanofillers into a polymeric matrix has received much attention as a route to reinforced polymer nanocomposites. In the present work, an environmentally friendly chitosan (CTS)/titanium dioxide (TiO2) nanocomposite coating was designed/prepared and subsequently employed for imparting antibacterium and improved mechanical properties to cellulosic paper via surface coating. Effect of TiO2 nanoparticle loadings on the rheological behavior of nanocomposite coatings was investigated. Surface application of CTS/TiO2 nanocomposite coatings to cellulosic paper was performed, and the antibacterial activity and mechanical properties of surface-coated cellulosic paper were examined. Results showed that the increased TiO2 nanoparticle loadings decreased the viscosity and dynamic viscoelasticity of the as-prepared coatings, and improved the antibacterial activity and mechanical properties of surface-coated cellulosic paper. The optimum loading of TiO2 nanoparticles was identified at 10%. This work suggested that CTS/TiO2 nanocomposite coatings may have the potential to be used as a promising antibacterial protective coating for paper packaging. Copyright © 2016 Elsevier Ltd. All rights reserved.

The 15 cm diameter ion thruster research

NASA Technical Reports Server (NTRS)

Wilbur, P. J.

1974-01-01

The startup reliability of a 15 cm diameter mercury bombardment ion thruster which employs a pulsed high voltage tickler electrode on the main and neutralizer cathodes is examined. Startup of the thruster is achieved 100% of the time on the main cathode and 98.7% of the time on the neutralizer cathode over a 3640 cycle test. The thruster was started from a 20 C initial condition and operated for an hour at a 600 mA beam current. An energy efficiency of 75% and a propellant utilization efficiency of 77% was achieved over the complete cycle. The effect of a single cusp magnetic field thruster length on its performance is discussed. Guidelines are formulated for the shaping of magnetic field lines in thrusters. A model describing double ion production in mercury discharges is presented. The production route is shown to occur through the single ionic ground state. Photographs of the interior of an operating-hollow cathode are presented. A cathode spot is shown to be present if the cathode is free of low work-function surfaces. The spot is observed if a low work-function oxide coating is applied to the cathode insert. Results show that low work-function oxide coatings tend to migrate during thruster operation.

Superamphiphobic Surfaces Prepared by Coating Multifunctional Nanofluids.

PubMed

Esmaeilzadeh, Pouriya; Sadeghi, Mohammad Taghi; Bahramian, Alireza; Fakhroueian, Zahra; Zarbakhsh, Ali

2016-11-23

Construction of surfaces with the capability of repelling both water and oil is a challenging issue. We report the superamphiphobic properties of mineral surfaces coated with nanofluids based on synthesized Co-doped and Ce-doped Barium Strontium Titanate (CoBST and CeBST) nanoparticles and fluorochemicals of trichloro(1H,1H,2H,2H-perfluorooctyl)silane (PFOS) and polytetrafluoroethylene (PTFE). Coating surfaces with these nanofluids provides both oil (with surface tensions as low as 23 mN/m) and water repellency. Liquids with high surface tension (such as water and ethylene glycol) roll off the coated surface without tilting. A water drop released from 8 mm above the coated surface undergoes first a lateral displacement from its trajectory and shape deformation, striking the surface after 23 ms, bouncing and rolling off freely. These multifunctional coating nanofluids impart properties of self-cleaning. Applications include coating surfaces where cleanliness is paramount such as in hospitals and domestic environments as well as the maintenance of building facades and protection of public monuments from weathering. These superamphiphobic-doped nanofluids have thermal stability up to 180 °C; novel industrial applications include within fracking and the elimination of condensate blockage in gas reservoirs.

Surface-independent antibacterial coating using silver nanoparticle-generating engineered mussel glue.

PubMed

Jo, Yun Kee; Seo, Jeong Hyun; Choi, Bong-Hyuk; Kim, Bum Jin; Shin, Hwa Hui; Hwang, Byeong Hee; Cha, Hyung Joon

2014-11-26

During implant surgeries, antibacterial agents are needed to prevent bacterial infections, which can cause the formation of biofilms between implanted materials and tissue. Mussel adhesive proteins (MAPs) derived from marine mussels are bioadhesives that show strong adhesion and coating ability on various surfaces even in wet environment. Here, we proposed a novel surface-independent antibacterial coating strategy based on the fusion of MAP to a silver-binding peptide, which can synthesize silver nanoparticles having broad antibacterial activity. This sticky recombinant fusion protein enabled the efficient coating on target surface and the easy generation of silver nanoparticles on the coated-surface under mild condition. The biosynthesized silver nanoparticles showed excellent antibacterial efficacy against both Gram-positive and Gram-negative bacteria and also revealed good cytocompatibility with mammalian cells. In this coating strategy, MAP-silver binding peptide fusion proteins provide hybrid environment incorporating inorganic silver nanoparticle and simultaneously mediate the interaction of silver nanoparticle with surroundings. Moreover, the silver nanoparticles were fully synthesized on various surfaces including metal, plastic, and glass by a simple, surface-independent coating manner, and they were also successfully synthesized on a nanofiber surface fabricated by electrospinning of the fusion protein. Thus, this facile surface-independent silver nanoparticle-generating antibacterial coating has great potential to be used for the prevention of bacterial infection in diverse biomedical fields.

Surface properties of semi-synthetic enteric coating films: Opportunities to develop bio-based enteric coating films for colon- targeted delivery

USDA-ARS?s Scientific Manuscript database

This study investigated the surface properties of the semi-synthetic enteric coating materials for potential colon- targeted bioactive delivery. The enteric coating materials were produced by combining nanoscale resistant starch, pectin, and carboxymethylcellulose. The surface properties of the co...

Ceramic coatings on smooth surfaces

NASA Technical Reports Server (NTRS)

Miller, R. A. (Inventor); Brindley, W. J. (Inventor); Rouge, C. J. (Inventor)

1991-01-01

A metallic coating is plasma sprayed onto a smooth surface of a metal alloy substitute or on a bond coating. An initial thin ceramic layer is low pressure sprayed onto the smooth surface of the substrate or bond coating. Another ceramic layer is atmospheric plasma sprayed onto the initial ceramic layer.

77 FR 67024 - Notice of Proposed Information Collection

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-08

... procedures and requirements for terminating jurisdiction of surface coal mining and reclamation operations... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Notice...

76 FR 50708 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-16

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing. SUMMARY: We, the Office of Surface Mining Reclamation...

77 FR 21807 - Notice of Proposed Information Collection

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-11

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Notice... of Surface Mining Reclamation and Enforcement (OSM) is announcing its intention to request approval...

76 FR 12857 - Montana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-09

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 926... of Surface Mining Reclamation and Enforcement, Interior. ACTION: Final rule; approval of amendment... the Surface Mining Control and Reclamation Act of 1977 (``SMCRA'' or ``the Act''). Montana proposed...

78 FR 11617 - Pennsylvania Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-19

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 938... Surface Mining Reclamation and Enforcement (OSM), Interior. ACTION: Proposed rule; reopening of comment... regulatory program (the ``Pennsylvania program'') under the Surface Mining Control and Reclamation Act of...

Fabrication of robust hydrogel coatings on polydimethylsiloxane substrates using micropillar anchor structures with chemical surface modification.

PubMed

Zhang, Hongbin; Bian, Chao; Jackson, John K; Khademolhosseini, Farzad; Burt, Helen M; Chiao, Mu

2014-06-25

A durable hydrophilic and protein-resistant surface of polydimethylsiloxane (PDMS) based devices is desirable in many biomedical applications such as implantable and microfluidic devices. This paper describes a stable antifouling hydrogel coating on PDMS surfaces. The coating method combines chemical modification and surface microstructure fabrication of PDMS substrates. Three-(trimethoxysilyl)propyl methacrylates containing C═C groups were used to modify PDMS surfaces with micropillar array structures fabricated by a replica molding method. The micropillar structures increase the surface area of PDMS surfaces, which facilitates secure bonding with a hydrogel coating compared to flat PMDS surfaces. The adhesion properties of the hydrogel coating on PDMS substrates were characterized using bending, stretching and water immersion tests. Long-term hydrophilic stability (maintaining a contact angle of 55° for a month) and a low protein adsorption property (35 ng/cm(2) of adsorbed BSA-FITC) of the hydrogel coated PDMS were demonstrated. This coating method is suitable for PDMS modification with most crosslinkable polymers containing C═C groups, which can be useful for improving the anti-biofouling performance of PDMS-based biomedical microdevices.

Development of a special purpose spacecraft interior coating, phase 1

NASA Technical Reports Server (NTRS)

Bartoszek, E. J.; Nannelli, P.

1975-01-01

Coating formulations were developed consisting of latex blends of fluorocarbon polymers, acrylic resins, stabilizers, modifiers, other additives, and a variety of inorganic pigments. Suitable latex primers were also developed from an acrylic latex base. The formulations dried to touch in about one hour and were fully dry in about twenty-four hours under normal room temperature and humidity conditions. The resulting coatings displayed good optical and mechanical properties, including excellent bonding to (pre-treated) substrates. In addition, the preferred compositions were found to be self-extinguishing when applied to nonflammable substrates and could meet the offgassing requirements specified by NASA for the intended application. Improvements are needed in abrasion resistance and hardness.

Surface characterization of an energetic material, pentaerythritoltetranitrate (PETN), having a thin coating achieved through a starved addition microencapsulation technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Worley, C.M.

The objective of this research was to: (1) determine the nature of a thin coating on an explosive material which was applied using a starved addition microencapsulation technique, (2) understand the coating/crystal bond, and (3) investigate the wettability/adhesion of plastic/solvent combinations using the coating process. The coating used in this work was a Firestone Plastic Company copolymer (FPC-461) of vinylchloride/trifluorochloroethylene in a 1.5/1.0 weight ratio. The energetic explosive examined was pentaerythritoltetranitrate (PETN). The coating process used was starved addition followed by a solvent evaporation technique. Surface analytical studies, completed for characterization of the coating process, show (1) evidence that themore » polymer coating is present, but not continuous, over the surface of PETN; (2) the average thickness of the polymer coating is between 16-32 A and greater than 44 A, respectively, for 0.5 and 20 wt % coated PETN; (3) no changes in surface chemistry of the polymer or the explosive material following microencapsulation; and (4) the presence of explosive material on the surface of 0.5 wt % FPC-461 coated explosives. 5 refs., 15 figs., 6 tabs.« less

A boundary integral equation method using auxiliary interior surface approach for acoustic radiation and scattering in two dimensions.

PubMed

Yang, S A

2002-10-01

This paper presents an effective solution method for predicting acoustic radiation and scattering fields in two dimensions. The difficulty of the fictitious characteristic frequency is overcome by incorporating an auxiliary interior surface that satisfies certain boundary condition into the body surface. This process gives rise to a set of uniquely solvable boundary integral equations. Distributing monopoles with unknown strengths over the body and interior surfaces yields the simple source formulation. The modified boundary integral equations are further transformed to ordinary ones that contain nonsingular kernels only. This implementation allows direct application of standard quadrature formulas over the entire integration domain; that is, the collocation points are exactly the positions at which the integration points are located. Selecting the interior surface is an easy task. Moreover, only a few corresponding interior nodal points are sufficient for the computation. Numerical calculations consist of the acoustic radiation and scattering by acoustically hard elliptic and rectangular cylinders. Comparisons with analytical solutions are made. Numerical results demonstrate the efficiency and accuracy of the current solution method.

Effect of triangular texture on the tribological performance of die steel with TiN coatings under lubricated sliding condition

NASA Astrophysics Data System (ADS)

Chen, Ping; Xiang, Xin; Shao, Tianmin; La, Yingqian; Li, Junling

2016-12-01

The friction and wear of stamping die surface can affect the service life of stamping die and the quality of stamping products. Surface texturing and surface coating have been widely used to improve the tribological performance of mechanical components. This study experimentally investigated the effect of triangular surface texture on the friction and wear properties of the die steel substrate with TiN coatings under oil lubrication. TiN coatings were deposited on a die steel (50Cr) substrate through a multi-arc ion deposition system, and then triangular surface texturing was fabricated by a laser surface texturing. The friction and wear test was conducted by a UMT-3 pin-on-disk tribometer under different sliding speeds and different applied loads, respectively. The adhesion test was performed to evaluate the effectiveness of triangular texturing on the interfacial bonding strength between the TiN coating and the die steel substrate. Results show that the combination method of surface texturing process and surface coating process has excellent tribological properties (the lowest frictional coefficient and wear volume), compared with the single texturing process or the single coating process. The tribological performance is improved resulting from the high hardness and low elastic modulus of TiN coatings, and the generation of hydrodynamic pressure, function of micro-trap for wear debris and micro-reservoirs for lubricating oil of the triangular surface texture. In addition, the coating bonding strength of the texturing sample is 3.63 MPa, higher than that of the single coating sample (3.48 MPa), but the mechanisms remain to be further researched.

Dosimetric effects of polyethylene glycol surface coatings on gold nanoparticle radiosensitization

NASA Astrophysics Data System (ADS)

Koger, B.; Kirkby, C.

2017-11-01

One of the main appeals of using gold nanoparticles (GNPs) as radiosensitizers is that their surface coatings can be altered to manipulate their pharmacokinetic properties. However, Monte Carlo studies of GNP dosimetry tend to neglect these coatings, potentially changing the dosimetric results. This study quantifies the dosimetric effects of including a polyethylene glycol (PEG) surface coating on GNPs over both nanoscopic and microscopic ranges. Two dosimetric scales were explored using PENELOPE Monte Carlo simulations. In microscopic simulations, 500-1000 GNPs, with and without coatings, were placed in cavities of side lengths 0.8-4 µm, and the reduction of dose deposited to surrounding medium within these volumes due to the coating was quantified. Including PEG surface coatings of up to 20 nm thickness resulted in reductions of up to 7.5%, 4.0%, and 2.0% for GNP diameters of 10, 20, and 50 nm, respectively. Nanoscopic simulations observed the dose falloff in the first 500 nm surrounding a single GNP both with and without surface coatings of various thicknesses. Over the first 500 nm surrounding a single GNP, the presence of a PEG surface coating reduced dose by 5-26%, 8-28%, 8-30%, and 8-34% for 2, 10, 20, and 50 nm diameter GNPs, respectively, for various energies and coating thicknesses. Reductions in dose enhancement due to the inclusion of a GNP surface coating are non-negligible and should be taken into consideration when investigating GNP dose enhancement. Further studies should be carried out to investigate the biological effects of these coatings.

Flexible Interior-Impression-Molding Tray

NASA Technical Reports Server (NTRS)

Anders, Jeffrey E.

1991-01-01

Device used inside combustion chamber of complicated shape for nondestructive evaluation of qualities of welds, including such features as offset, warping, misalignment of parts, and dropthrough. Includes flexible polypropylene tray trimmed to fit desired interior surface contour. Two neodymium boron magnets and inflatable bladder attached to tray. Tray and putty inserted in cavity to make mold of interior surface.

The relationship between substrate morphology and biological performances of nano-silver-loaded dopamine coatings on titanium surfaces

PubMed Central

Zhang, Weibo; Wang, Shuang; Ge, Shaohua; Ji, Ping

2018-01-01

Biomedical device-associated infection (BAI) and lack of osseointegration are the main causes of implant failure. Therefore, it is imperative for implants not only to depress microbial activity and biofilm colonization but also to prompt osteoblast functions and osseointegration. As part of the coating development for implants, the interest of in vitro studies on the interaction between implant substrate morphology and the coating's biological performances is growing. In this study, by harnessing the adhesion and reactivity of bioinspired polydopamine, nano-silver was successfully anchored onto micro/nanoporous as well as smooth titanium surfaces to analyse the effect of substrate morphology on biological performances of the coatings. Compared with the smooth surface, a small size of nano-silver and high silver content was found on the micro/nanoporous surface. More mineralization happened on the coating on the micro/nanoporous structure than on the smooth surface, which led to a more rapid decrease of silver release from the micro/nanoporous surface. Antimicrobial tests indicated that both surfaces with resulting coating inhibit microbial colonization on them and growth around them, indicating that the coating eliminates the shortcoming of the porous structure which render the implant extremely susceptible to BAI. Besides, the multiple osteoblast responses of nano-silver-loaded dopamine coatings on both surfaces, i.e. attachment, proliferation and differentiation, have deteriorated, however the mineralized surfaces of these coatings stimulated osteoblast proliferation and differentiation, especially for the micro/nanoporous surface. Therefore, nano-silver-loaded dopamine coatings on micro/nanoporous substratum may not only reduce the risk of infection but also facilitate mineralization during the early post-operative period and then promote osseointegration owing to the good osteoblast-biocompatibility of the mineralized surface. These results clearly highlight the influence of the substrate morphology on the biological performances of implant coating. PMID:29765680

Method of measuring metal coating adhesion

DOEpatents

Roper, J.R.

A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

Method of measuring metal coating adhesion

DOEpatents

Roper, John R.

1985-01-01

A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

Thin film heater for removable volatile protecting coatings.

PubMed

Karim, Abid

2013-01-01

Freshly coated aluminum mirrors have excellent reflectivity at far ultraviolet wavelengths. However, reflectivity rapidly degrades when the mirror surfaces are exposed to atmosphere. In order to avoid this problem, freshly coated aluminum surface can be protected by over-coating of a removable volatile protecting coating. This protecting coating can be re-evaporated by controlled heating or by some other methods when required. This type of removable coating has immediate application in UV space astronomy. The purpose of this paper is to demonstrate the feasibility of re-evaporation of removable volatile Zn protecting coating using a NiCr thin film heater without affecting the reflection properties of Al mirror surfaces.

Surface topographical effects on the structural growth of thick sputtered metal and alloy coatings

NASA Technical Reports Server (NTRS)

Spalvins, T.; Brainard, W. A.

1974-01-01

Thick sputtered S-Monel, silver, and 304 stainless steel coatings were deposited on mica and metal substrates with various surface finishes to investigate the structural growth of the coating by scanning electron microscopy. The geometry and the surface structure of the nodules are characterized. Compositional changes within the coating were analyzed by X-ray dispersion miscroscopy. Defects in the surface finish act as preferential nucleation sites and form isolated and complex nodules and various surface overgrowths in the coating. The nodule boundaries are very vulnerable to chemical etching, and these nodules do not disappear after full annealing. Further, they have undesirable effects on mechanical properties; cracks are initiated at the nodules when the coating is stressed by mechanical forces.

Effect of surface topography on structural growth of thick sputtered films

NASA Technical Reports Server (NTRS)

Spalvins, T.; Brainard, W. A.

1974-01-01

Primarily thick sputtered S-Monel, silver, and 304 stainless steel coatings were deposited on mica, glass, and metal substrates with various surface finishes to investigate the structural growth of the coating by scanning electron microscopy. Compositional changes within the coating were analyzed by X-ray dispersion microscopy. Defects in the surface finish act as preferential nucleation sites and form isolated and complex nodules and various surface overgrowths in the coating. These nodules do not disappear after full annealing. Further, they have undesirable effects on mechanial properties; cracks are initiated at the nodules when the coating is stressed by mechanical forces. These effects are illustrated by micrographs. Nodular growth within a coating can be minimized or eliminated by reducing the surface roughness.

Effect of photocatalytic and hydrophobic coatings on brewery surface microorganisms.

PubMed

Priha, O; Laakso, J; Tapani, K; Levänen, E; Kolari, M; Mäntylä, T; Storgårds, E

2011-11-01

The aim of this study was to determine whether process hygiene in the beverage industry could be improved by applying new coating techniques to process surfaces. Photocatalytic titanium dioxide (TiO(2)) and hydrophobic coatings applied to stainless steel with or without added antimicrobial compounds were studied in laboratory attachment tests and in a 15-month process study. No clear reductions in numbers of attached microbes were obtained with photocatalytic coatings, except for coatings to which silver had been added. These TiO(2)+Ag coatings reduced microbial coverage in laboratory studies and in some process samples. Hydrophobic coatings reduced the area coverage of microorganisms in 4-h laboratory studies but did not affect colony counts in laboratory or process studies. The surfaces had changed from hydrophobic into hydrophilic during the process study. The coatings did not mechanically fully withstand process conditions; part of the hydrophobic coatings had peeled off, most of the precipitated Ag had dissolved, and some of the TiO(2) coatings were damaged. In conclusion, functional coatings have potential for reducing microbial loads on beverage industry surfaces, but these coatings need further development.

Corrosion behavior of HVOF coated sheets

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Abdul-Aleem, B. J.; Khalid, M.

2003-12-01

High velocity oxygen-fuel (HVOF) thermal spray coating finds application in industry due to its superior resistance to corrosion and thermal loading. In the HVOF process, the metallic powders at elevated temperature are sprayed at supersonic speed onto a substrate material. The powder granules sprayed impact onto each other, forming a mechanical bonding across the coating layer. In most of the cases, the distances among the particles (powder granules sprayed) are not the same, which in turn results in inhomogeneous structure across the coating layer. Moreover, the rate of oxidation of the powder granules during the spraying process varies. Consequently, the electrochemical response of the coating layer surfaces next to the base material and free to atmosphere differs. In the current study, the electrochemical response of a coating sheet formed during HVOF thermal spraying was investigated. NiCrMoNb alloy (similar to Inconel 625) wass used for the powder granules. Thermal spraying was carried out onto a smooth surface of stainless steel workpiece (without grid blasting), and later the coating layer was removed from the surface to obtain the coating sheet for the electrochemical tests. It was found that the corrosion rate of the smooth surface (surface next to the stainless steel surface before its removal) is considerably larger than that corresponding to the rough surface (free surface) of the coating sheet, and no specific patterns were observed for the pit sites.

Surface Coating of Gypsum-Based Molds for Maxillofacial Prosthetic Silicone Elastomeric Material: The Surface Topography.

PubMed

Khalaf, Salah; Ariffin, Zaihan; Husein, Adam; Reza, Fazal

2015-07-01

This study aimed to compare the surface roughness of maxillofacial silicone elastomers fabricated in noncoated and coated gypsum materials. This study was also conducted to characterize the silicone elastomer specimens after surfaces were modified. A gypsum mold was coated with clear acrylic spray. The coated mold was then used to produce modified silicone experimental specimens (n = 35). The surface roughness of the modified silicone elastomers was compared with that of the control specimens, which were prepared by conventional flasking methods (n = 35). An atomic force microscope (AFM) was used for surface roughness measurement of silicone elastomer (unmodified and modified), and a scanning electron microscope (SEM) was used to evaluate the topographic conditions of coated and noncoated gypsum and silicone elastomer specimens (unmodified and modified) groups. After the gypsum molds were characterized, the fabricated silicone elastomers molded on noncoated and coated gypsum materials were evaluated further. Energy-dispersive X-ray spectroscopy (EDX) analysis of gypsum materials (noncoated and coated) and silicone elastomer specimens (unmodified and modified) was performed to evaluate the elemental changes after coating was conducted. Independent t test was used to analyze the differences in the surface roughness of unmodified and modified silicone at a significance level of p < 0.05. Roughness was significantly reduced in the silicone elastomers processed against coated gypsum materials (p < 0.001). The AFM and SEM analysis results showed evident differences in surface smoothness. EDX data further revealed the presence of the desired chemical components on the surface layer of unmodified and modified silicone elastomers. Silicone elastomers with lower surface roughness of maxillofacial prostheses can be obtained simply by coating a gypsum mold. © 2014 by the American College of Prosthodontists.

Near-infrared squaraine dyes for fluorescence enhanced surface assay

PubMed Central

Matveeva, Evgenia G.; Terpetschnig, Ewald A.; Stevens, Megan; Patsenker, Leonid; Kolosova, Olga S.; Gryczynski, Zygmunt; Gryczynski, Ignacy

2009-01-01

Commercially available, near-infrared fluorescent squaraine dyes (Seta-635 and Seta-670) were covalently bound to antibodies and employed insurface enhanced immunoassay. From fluorescence intensity and lifetime changes determined for a surface which had been coated with silver nanoparticles as well as a non-coated glass surface, both labelled compounds exhibited a 15 to 20-fold enhancement of fluorescence on the silver coated surface compared to that achieved on the non-coated surface. In addition, the fluorescence lifetime changes drastically for both labels in the case of silver-coated surfaces. The fluorescence signal enhancement obtained for the two dyes was greater than that previously recorded for Rhodamine Red-X and AlexaFluor-647 labels. PMID:20046935

77 FR 8144 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-14

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Final rule; approval of amendment. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM), are approving three...

76 FR 44357 - Notice of Proposed Information Collection

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-25

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior Department... Reduction Act of 1995, the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing its...

76 FR 79213 - Notice of Proposed Information Collection

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-21

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Notice... 1995, the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing that the information...

77 FR 58147 - Action Subject to Intergovernmental Review

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-19

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Action Subject to Intergovernmental Review AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Notice. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement, are notifying the public that we...

76 FR 78312 - Action Subject to Intergovernmental Review

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-16

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Action Subject to Intergovernmental Review AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Notice. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement, are notifying the public that we...

Advances in microreaction technology for portable fuel cell applications: Wall coating of thin catalytic films in microreactors

NASA Astrophysics Data System (ADS)

Bravo Bersano, Jaime Cristian

This research has focused on the need to coat microreactor systems composed of channels in the micron size range of 100 to 1000 mum. The experimental procedures and learning are outlined in terms of slurry and surface preparation requirements which are detailed in the experimental section. This system is motivated and applied to micro methanol steam reformers. Thus, a detailed discussion on the driving motivation is given in the introduction. The low temperatures required for steam-reforming of methanol ˜ 493°K (220°C) make it possible to utilize the reformate as a feed to the fuel cell anode. The group of catalysts that shows the highest activity for methanol steam reforming (SR) at low temperature has composition of CuO/ZnO/Al 2O3, which is also the catalyst used for methanol synthesis. Steam reforming of methanol is a highly endothermic process. Conventional reactor configurations, such as a packed bed reactor, operate in a heat transfer limited mode for this reaction. Using catalyst in packed bed form for portable devices is also not convenient due to high pressure drop and possible channeling of gases in addition to poor heat transfer. A wall-coated catalyst represents a superior geometry since it provides lower pressure drop and ease of manufacturing. Due to their small size, microreactors are especially suited for endothermic reactions whose reactivity depends on the rate of heat input. A brief review on microreaction technology is given with a comprehensive survey for catalyst integration into microreactors for catalytic heterogeneous gas phase reactions. The strength of this research is the model that was developed to coat the interior of micron sized capillaries with coats of CuO/ZnO/Al2O 3 slurries as thick as 25 mum in the dry state. The details of the model are given in terms Taylor's theory and Rayleigh's theory. A model is presented that can predict the coat thickness based on experimental conditions The model combines Taylor's experimental work with Lord Rayleigh's instability theory for annular coatings. The model presented serves as a design tool for microreactor design. The model can also estimate the maximum coat thickness possible for a given system. The results are presented in graphical format in the Microchannel Coating Model chapter.

40 CFR 63.5755 - How do I demonstrate compliance with the aluminum recreational boat surface coating spray gun...

Code of Federal Regulations, 2013 CFR

2013-07-01

... the aluminum recreational boat surface coating spray gun cleaning work practice standards? 63.5755... recreational boat surface coating spray gun cleaning work practice standards? You must demonstrate compliance with the aluminum coating spray gun cleaning work practice standards by meeting the requirements of...

40 CFR 63.5755 - How do I demonstrate compliance with the aluminum recreational boat surface coating spray gun...

Code of Federal Regulations, 2012 CFR

2012-07-01

... the aluminum recreational boat surface coating spray gun cleaning work practice standards? 63.5755... recreational boat surface coating spray gun cleaning work practice standards? You must demonstrate compliance with the aluminum coating spray gun cleaning work practice standards by meeting the requirements of...

40 CFR 63.5755 - How do I demonstrate compliance with the aluminum recreational boat surface coating spray gun...

Code of Federal Regulations, 2014 CFR

2014-07-01

... the aluminum recreational boat surface coating spray gun cleaning work practice standards? 63.5755... recreational boat surface coating spray gun cleaning work practice standards? You must demonstrate compliance with the aluminum coating spray gun cleaning work practice standards by meeting the requirements of...

40 CFR 63.5755 - How do I demonstrate compliance with the aluminum recreational boat surface coating spray gun...

Code of Federal Regulations, 2011 CFR

2011-07-01

... the aluminum recreational boat surface coating spray gun cleaning work practice standards? 63.5755... surface coating spray gun cleaning work practice standards? You must demonstrate compliance with the aluminum coating spray gun cleaning work practice standards by meeting the requirements of paragraph (a) or...

40 CFR 63.5755 - How do I demonstrate compliance with the aluminum recreational boat surface coating spray gun...

Code of Federal Regulations, 2010 CFR

2010-07-01

... the aluminum recreational boat surface coating spray gun cleaning work practice standards? 63.5755... surface coating spray gun cleaning work practice standards? You must demonstrate compliance with the aluminum coating spray gun cleaning work practice standards by meeting the requirements of paragraph (a) or...

40 CFR 63.5746 - How do I demonstrate compliance with the emission limits for aluminum wipedown solvents and...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) to determine the density of each aluminum surface coating and wipedown solvent. (d) Compliance is... Hazardous Air Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating... of solids per liter of coating, or volume fraction) of each aluminum surface coating, including...

Chlorine-rich plasma polymer coating for the prevention of attachment of pathogenic fungal cells onto materials surfaces

NASA Astrophysics Data System (ADS)

Lamont-Friedrich, Stephanie J.; Michl, Thomas D.; Giles, Carla; Griesser, Hans J.; Coad, Bryan R.

2016-07-01

The attachment of pathogenic fungal cells onto materials surfaces, which is often followed by biofilm formation, causes adverse consequences in a wide range of areas. Here we have investigated the ability of thin film coatings from chlorinated molecules to deter fungal colonization of solid materials by contact killing of fungal cells reaching the surface of the coating. Coatings were deposited onto various substrate materials via plasma polymerization, which is a substrate-independent process widely used for industrial coating applications, using 1,1,2-trichloroethane as the process vapour. XPS surface analysis showed that the coatings were characterized by a highly chlorinated hydrocarbon polymer nature, with only a very small amount of oxygen incorporated. The activity of these coatings against human fungal pathogens was quantified using a recently developed, modified yeast assay and excellent antifungal activity was observed against Candida albicans and Candida glabrata. Plasma polymer surface coatings derived from chlorinated hydrocarbon molecules may therefore offer a promising solution to preventing yeast and mould biofilm formation on materials surfaces, for applications such as air conditioners, biomedical devices, food processing equipment, and others.

Reactive polymer coatings: A robust platform towards sophisticated surface engineering for biotechnology

NASA Astrophysics Data System (ADS)

Chen, Hsien-Yeh

Functionalized poly(p-xylylenes) or so-called reactive polymers can be synthesized via chemical vapor deposition (CVD) polymerization. The resulting ultra-thin coatings are pinhole-free and can be conformally deposited to a wide range of substrates and materials. More importantly, the equipped functional groups can served as anchoring sites for tailoring the surface properties, making these reactive coatings a robust platform that can deal with sophisticated challenges faced in biointerfaces. In this work presented herein, surface coatings presenting various functional groups were prepared by CVD process. Such surfaces include aldehyde-functionalized coating to precisely immobilize saccharide molecules onto well-defined areas and alkyne-functionalized coating to click azide-modified molecules via Huisgen 1,3-dipolar cycloaddition reaction. Moreover, CVD copolymerization has been conducted to prepare multifunctional coatings and their specific functions were demonstrated by the immobilization of biotin and NHS-ester molecules. By using a photodefinable coating, polyethylene oxides were immobilized onto a wide range of substrates through photo-immobilization. Spatially controlled protein resistant properties were characterized by selective adsorption of fibrinogen and bovine serum albumin as model systems. Alternatively, surface initiator coatings were used for polymer graftings of polyethylene glycol) methyl ether methacrylate, and the resultant protein- and cell- resistant properties were characterized by adsorption of kinesin motor proteins, fibrinogen, and murine fibroblasts (NIH3T3). Accessibility of reactive coatings within confined microgeometries was systematically studied, and the preparation of homogeneous polymer thin films within the inner surface of microchannels was demonstrated. Moreover, these advanced coatings were applied to develop a dry adhesion process for microfluidic devices. This process provides (i) excellent bonding strength, (ii) extended storage time prior to bonding, and (iii) well-defined surface functionalities for subsequent surface modifications. Finally, we have also prepared surface microstructures and surface patterns using reactive coatings via photopatterning, projection lithography, supramolecular nanostamping (SuNS), and vapor-assisted micropatterning in replica structures (VAMPIR). These patterning techniques can be complimentarily used and provide access to precisely confined microenvironments on flat and curved geometries. Reactive coatings provide a technology platform that creates active, long-term control and may lead to improved mimicry of biological systems for effective bio-functional modifications.

Apparatus and method for measuring the thickness of a coating

DOEpatents

Carlson, Nancy M.; Johnson, John A.; Tow, David M.; Walter, John B

2002-01-01

An apparatus and method for measuring the thickness of a coating adhered to a substrate. An electromagnetic acoustic transducer is used to induce surface waves into the coating. The surface waves have a selected frequency and a fixed wavelength. Interpolation is used to determine the frequency of surface waves that propagate through the coating with the least attenuation. The phase velocity of the surface waves having this frequency is then calculated. The phase velocity is compared to known phase velocity/thickness tables to determine the thickness of the coating.

40 CFR 60.461 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... coil. Coating application station means that portion of the metal coil surface coating operation where.... Finish coat operation means the coating application station, curing oven, and quench station used to... operation means the application system used to apply an organic coating to the surface of any continuous...

Fabrication of the superhydrophobic surface on aluminum alloy by anodizing and polymeric coating

NASA Astrophysics Data System (ADS)

Liu, Wenyong; Luo, Yuting; Sun, Linyu; Wu, Ruomei; Jiang, Haiyun; Liu, Yuejun

2013-01-01

We reported the preparation of the superhydrophobic surface on aluminum alloy via anodizing and polymeric coating. Both the different anodizing processes and different polymeric coatings of aluminum alloy were investigated. The effects of different anodizing conditions, such as electrolyte concentration, anodization time and current on the superhydrophobic surface were discussed. The results showed that a good superhydrophobic surface was facilely fabricated by polypropylene (PP) coating after anodizing. The optimum conditions for anodizing were determined by orthogonal experiments. When the concentration of oxalic acid was 10 g/L, the concentration of NaCl was 1.25 g/L, anodization time was 40 min, and anodization current was 0.4 A, the best superhydrophobic surface on aluminum alloy with the contact angle (CA) of 162° and the sliding angle of 2° was obtained. On the other hand, the different polymeric coatings, such as polystyrene (PS), polypropylene (PP) and polypropylene grafting maleic anhydride (PP-g-MAH) were used to coat the aluminum alloy surface after anodizing. The results showed that the superhydrophobicity was most excellent by coating PP, while the duration of the hydrophobic surface was poor. By modifying the surface with the silane coupling agent before PP coating, the duration of the superhydrophobic surface was improved. The morphologies of the superhydrophobic surface were further confirmed by optical microscope (OM) and scanning electron microscope (SEM). Combined with the material of PP with the low surface free energy, the micro/nano-structures of the surface resulted in the superhydrophobicity of the aluminum alloy surface.

Physical, metabolic and developmental functions of the seed coat

PubMed Central

Radchuk, Volodymyr; Borisjuk, Ljudmilla

2014-01-01

The conventional understanding of the role of the seed coat is that it provides a protective layer for the developing zygote. Recent data show that the picture is more nuanced. The seed coat certainly represents a first line of defense against adverse external factors, but it also acts as channel for transmitting environmental cues to the interior of the seed. The latter function primes the seed to adjust its metabolism in response to changes in its external environment. The purpose of this review is to provide the reader with a comprehensive view of the structure and functionality of the seed coat, and to expose its hidden interaction with both the endosperm and embryo. Any breeding and/or biotechnology intervention seeking to increase seed size or modify seed features will have to consider the implications on this tripartite interaction. PMID:25346737

Hybrid Physical Chemical Vapor Deposition of Magnesium Diboride Inside 3.9 GHz Mock Cavities

DOE PAGES

Lee, Namhoon; Withanage, Wenura K.; Tan, Teng; ...

2016-12-21

Magnesium diboride (MgB 2) is considered a candidate for the next generation superconducting radio frequency (SRF) cavities due to its higher critical temperature T c (40 K) and increased superheating field (H sh) compared to other conventional superconductors. These properties can lead to reduced BCS surface resistance (R BCS S) and residual resistance (R res), according to theoretical studies, and enhanced accelerating field (E acc) values. Here, we investigated the possibility of coating the inner surface of a 3.9 GHz SRF cavity with MgB 2 by using a hybrid physical-vapor deposition (HPCVD) system designed for this purpose. To simulate themore » actual 3.9 GHz SRF cavity, we also employed a stainless steel mock cavity for the study. The film qualities were characterized on small substrates that were placed at the selected positions within the cavity. MgB 2 films on stainless steel foils, niobium pieces, and SiC substrates showed transition temperatures in the range of 30-38 K with a c-axis-oriented crystallinity observed for films grown on SiC substrates. Dielectric resonator measurements at 18 GHz resulted in a quality factor of over 30 000 for the MgB 2 film grown on a SiC substrate. Furthermore, by employing the HPCVD technique, a uniform film was achieved across the cavity interior, demonstrating the feasibility of HPCVD for MgB 2 coatings for SRF cavities.« less

Hybrid Physical Chemical Vapor Deposition of Magnesium Diboride Inside 3.9 GHz Mock Cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Namhoon; Withanage, Wenura K.; Tan, Teng

Magnesium diboride (MgB 2) is considered a candidate for the next generation superconducting radio frequency (SRF) cavities due to its higher critical temperature T c (40 K) and increased superheating field (H sh) compared to other conventional superconductors. These properties can lead to reduced BCS surface resistance (R BCS S) and residual resistance (R res), according to theoretical studies, and enhanced accelerating field (E acc) values. Here, we investigated the possibility of coating the inner surface of a 3.9 GHz SRF cavity with MgB 2 by using a hybrid physical-vapor deposition (HPCVD) system designed for this purpose. To simulate themore » actual 3.9 GHz SRF cavity, we also employed a stainless steel mock cavity for the study. The film qualities were characterized on small substrates that were placed at the selected positions within the cavity. MgB 2 films on stainless steel foils, niobium pieces, and SiC substrates showed transition temperatures in the range of 30-38 K with a c-axis-oriented crystallinity observed for films grown on SiC substrates. Dielectric resonator measurements at 18 GHz resulted in a quality factor of over 30 000 for the MgB 2 film grown on a SiC substrate. Furthermore, by employing the HPCVD technique, a uniform film was achieved across the cavity interior, demonstrating the feasibility of HPCVD for MgB 2 coatings for SRF cavities.« less

Study on influence of Surface roughness of Ni-Al2O3 nano composite coating and evaluation of wear characteristics

NASA Astrophysics Data System (ADS)

Raghavendra, C. R.; Basavarajappa, S.; Sogalad, Irappa

2018-02-01

Electrodeposition is one of the most technologically feasible and economically superior techniques for producing metallic coating. The advancement in the application of nano particles has grabbed the attention in all fields of engineering. In this present study an attempt has been made on the Ni-Al2O3nano particle composite coating on aluminium substrate by electrodeposition process. The aluminium surface requires a specific pre-treatment for better adherence of coating. In light of this a thin zinc layer is coated on the aluminium substrate by electroless process. In addition to this surface roughness is an important parameter for any coating method and material. In this work Ni-Al2O3 composite coating were successfully coated by varying the process parameters such as bath temperature, current density and particle loading. The experimentation was performed using central composite design based 20 trials of experiments. The effect of process parameters and surface roughness before and after coating is analyzed on wear rate and coating thickness. The results shown a better wear resistance of Ni-Al2O3 composite electrodeposited coating compared to Ni coating. The particle loading and interaction effect of current density with temperature has greater significant effect on wear rate. The surface roughness is significantly affected the wear behaviour and thickness of coating.

Hydrophobic Surface Modification of Silk Fabric Using Plasma-Polymerized Hmdso

NASA Astrophysics Data System (ADS)

Rani, K. Vinisha; Chandwani, Nisha; Kikani, Purvi; Nema, S. K.; Sarma, Arun Kumar; Sarma, Bornali

In this work, we study the hydrophobic properties of silk fabrics by deposition of plasma-polymerized (pp) hexamethyldisiloxane (HMDSO) using low-pressure plasma-enhanced chemical vapor deposition. Recently, hydrophobic properties are under active research in textile industry. The effects of coating time and power on the HMDSO-coated silk fabrics are investigated. Water contact angle of pp-HMDSO-coated silk fabric surface is measured as a function of power and coating time. Fabric surface shows an enhancement in hydrophobicity after coating. Attenuated total reflectance-Fourier transform infrared spectroscopy reveals the surface chemistry, and scanning electron microscopy shows the surface morphology of the uncoated and HMDSO-coated fabrics, respectively. In the case of uncoated fabric, water droplet absorbs swiftly, whereas in the case of HMDSO-coated fabric, water droplet remains on the fabric surface with a maximum contact angle of 140∘. The HMDSO-deposited silk surface is found to be durable after detergent washing. Common stains such as ink, tea, milk, turmeric and orange juice are tested on the surface of both fabrics. In HMDSO-coated fabrics, all the stains are bedded like ball droplet. In order to study the self-cleaning property, the fabric is tilted to 45∘ angle; stain droplets easily roll off from the fabric.

Influence of viscoelastic property on laser-generated surface acoustic waves in coating-substrate systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun Hongxiang; Faculty of Science, Jiangsu University, Zhenjiang 212013; Zhang Shuyi

2011-04-01

Taking account of the viscoelasticity of materials, the pulsed laser generation of surface acoustic waves in coating-substrate systems has been investigated quantitatively by using the finite element method. The displacement spectra of the surface acoustic waves have been calculated in frequency domain for different coating-substrate systems, in which the viscoelastic properties of the coatings and substrates are considered separately. Meanwhile, the temporal displacement waveforms have been obtained by applying inverse fast Fourier transforms. The numerical results of the normal surface displacements are presented for different configurations: a single plate, a slow coating on a fast substrate, and a fast coatingmore » on a slow substrate. The influences of the viscoelastic properties of the coating and the substrate on the attenuation of the surface acoustic waves have been studied. In addition, the influence of the coating thickness on the attenuation of the surface acoustic waves has been also investigated in detail.« less

Anti-icing properties of superhydrophobic ZnO/PDMS composite coating

NASA Astrophysics Data System (ADS)

Yang, Chao; Wang, Fajun; Li, Wen; Ou, Junfei; Li, Changquan; Amirfazli, Alidad

2016-01-01

We present the excellent anti-icing performance for a superhydrophobic coating surface based on ZnO/polydimethylsiloxane (ZnO/PDMS) composite. The superhydrophobic ZnO/PDMS coating surface was prepared by a facile solution mixing, drop coating, room-temperature curing and surface abrading procedure. The superhydrophobic ZnO/PDMS composite coating possesses a water contact angle of 159.5° and a water sliding angle of 8.3° at room temperature (5 °C). The anti-icing properties of the superhydrophobic coating were investigated by continuously dropping cold-water droplets (about 0 °C) onto the pre-cooled surface using a home-made apparatus. The sample was placed at different tilting angle (0° and 10°) and pre-cooled to various temperatures (-5, -10 and -15 °C) prior to measure. The pure Al surface was also studied for comparison. It was found that icing accretion on the surface could be reduced apparently because the water droplets merged together and slid away from the superhydrophobic surface at all of the measuring temperatures when the surface is horizontally placed. In addition, water droplet slid away completely from the superhydrophobic surface at -5 and -10 °C when the surface is tilted at 10°, which demonstrates its excellent anti-icing properties at these temperatures. When the temperature decreased to -15 °C, though ice accretion on the tilted superhydrophobic coating surface could not be avoided absolutely, the amount of ice formed on the surface is very small, which indicated that the coating surface with superhydrophobicity could significantly reduce ice accumulation on the surface at very low temperature (-15 °C). Importantly, the sample is also stable against repeated icing/deicing cycles. More meaningfully, once the superhydrophobic surface is damaged, it can be repaired easily and rapidly.

Surface characterization of colloidal-sol gel derived biphasic HA/FA coatings.

PubMed

Cheng, Kui; Zhang, Sam; Weng, Wenjian

2007-10-01

Hydroxyapatite (HA) powders are ultrasonically dispersed in the precursor of fluoridated hydroxyapatite (FHA) or fluorapatite (FA) to form a "colloidal sol". HA/FA biphasic coatings are prepared on Ti6Al4V substrate via dip coating, 150 degrees C drying and 600 degrees C firing. The coatings show homogenous distribution of HA particles in the FA matrix. The relative phase proportion can be tailored by the amount of HA in the colloidal sol. The surfaces of the coatings consist of two kinds of distinct domains: HA and FA, resulting in a compositionally heterogeneous surface. The biphasic coating surface becomes increasingly rougher with HA powders, from around 200 nm of pure FA to 400-600 nm in Ra of biphasic coatings. The rougher biphasic HA/FA surfaces with chemically controllable domains will favor cell attachment, apatite layer deposition and necessary dissolution in clinical applications.

Modification of implant material surface properties by means of oxide nano-structured coatings deposition

NASA Astrophysics Data System (ADS)

Safonov, Vladimir; Zykova, Anna; Smolik, Jerzy; Rogowska, Renata; Lukyanchenko, Vladimir; Kolesnikov, Dmitrii

2014-08-01

The deposition of functional coatings on the metal surface of artificial joints is an effective way of enhancing joint tribological characteristics. It is well-known that nanostructured oxide coatings have specific properties advantageous for future implant applications. In the present study, we measured the high hardness parameters, the adhesion strength and the low friction coefficient of the oxide magnetron sputtered coatings. The corrosion test results show that the oxide coating deposition had improved the corrosion resistance by a factor of ten for both stainless steel and titanium alloy substrates. Moreover, the hydrophilic nature of coated surfaces in comparison with the metal ones was investigated in the tensiometric tests. The surfaces with nanostructured oxide coatings demonstrated improved biocompatibility for in vitro and in vivo tests, attributed to the high dielectric constants and the high values of the surface free energy parameters.

Surface characteristics of a novel hydroxyapatite-coated dental implant

PubMed Central

Jung, Ui-Won; Hwang, Ji-Wan; Choi, Da-Yae; Hu, Kyung-Seok; Kwon, Mi-Kyung; Choi, Seong-Ho

2012-01-01

Purpose This study evaluated the surface characteristics and bond strength produced using a novel technique for coating hydroxyapatite (HA) onto titanium implants. Methods HA was coated on the titanium implant surface using a super-high-speed (SHS) blasting method with highly purified HA. The coating was performed at a low temperature, unlike conventional HA coating methods. Coating thickness was measured. The novel HA-coated disc was fabricated. X-ray diffraction analysis was performed directly on the disc to evaluate crystallinity. Four novel HA-coated discs and four resorbable blast medium (RBM) discs were prepared. Their surface roughnesses and areas were measured. Five puretitanium, RBM-treated, and novel HA-coated discs were prepared. Contact angle was measured. Two-way analysis of variance and the post-hoc Scheffe's test were used to analyze differences between the groups, with those with a probability of P<0.05 considered to be statistically significant. To evaluate exfoliation of the coating layer, 7 sites on the mandibles from 7 mongrel dogs were used. Other sites were used for another research project. In total, seven novel HA-coated implants were placed 2 months after extraction of premolars according to the manufacturer's instructions. The dogs were sacrificed 8 weeks after implant surgery. Implants were removed using a ratchet driver. The surface of the retrieved implants was evaluated microscopically. Results A uniform HA coating layer was formed on the titanium implants with no deformation of the RBM titanium surface microtexture when an SHS blasting method was used. Conclusions These HA-coated implants exhibited increased roughness, crystallinity, and wettability when compared with RBM implants. PMID:22586524

30 CFR 301.1 - Cross reference.

Code of Federal Regulations, 2010 CFR

2010-07-01

... within the jurisdiction of administrative law judges and the Interior Board of Surface Mining and... Resources BOARD OF SURFACE MINING AND RECLAMATION APPEALS, DEPARTMENT OF THE INTERIOR PROCEDURES UNDER SURFACE MINING CONTROL AND RECLAMATION ACT OF 1977 § 301.1 Cross reference. For special rules applicable...

77 FR 16260 - Notice of Proposed Information Collection for 1029-0035

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-20

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection for 1029-0035 AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior..., the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing that the information...

75 FR 22723 - Stream Protection Rule; Environmental Impact Statement

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-30

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Parts 780... of Surface Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; notice of intent to prepare an environmental impact statement. SUMMARY: We, the Office of Surface Mining Reclamation and...

Process for sensing defects on a smooth cylindrical interior surface in tubing

DOEpatents

Dutton, G. Wayne

1987-11-17

The cylindrical interior surface of small diameter metal tubing is optically inspected to determine surface roughness by passing a slightly divergent light beam to illuminate the entire interior surface of the tubing. Impingement of the input light beam components on any rough spots on the interior surface generates forward and backward scattered radiation components. The forward scattered components can be measured by blocking direct and specular radiation components exiting the tubing while allowing the forward scattered radiation to travel past the blocking location. Collecting optics are employed to converge the forward scattered radiation onto a photodetector generating a signal indicative of surface roughness. In the back scattered mode, back scattered radiation exiting the tubing through the entrance opening is reflected 90.degree. by a beam splitter towards collecting optics and a photodetector. Alternatively, back scattered radiation can be transmitted through a fiber optic bundle towards the collecting optics. The input light beam can be supplied through a white light fiber optic bundle mounted coaxial with the first bundle.

Process for sensing defects on a smooth cylindrical interior surface in tubing

DOEpatents

Dutton, G.W.

1987-11-17

The cylindrical interior surface of small diameter metal tubing is optically inspected to determine surface roughness by passing a slightly divergent light beam to illuminate the entire interior surface of the tubing. Impingement of the input light beam components on any rough spots on the interior surface generates forward and backward scattered radiation components. The forward scattered components can be measured by blocking direct and specular radiation components exiting the tubing while allowing the forward scattered radiation to travel past the blocking location. Collecting optics are employed to converge the forward scattered radiation onto a photodetector generating a signal indicative of surface roughness. In the back scattered mode, back scattered radiation exiting the tubing through the entrance opening is reflected 90[degree] by a beam splitter towards collecting optics and a photodetector. Alternatively, back scattered radiation can be transmitted through a fiber optic bundle towards the collecting optics. The input light beam can be supplied through a white light fiber optic bundle mounted coaxial with the first bundle. 6 figs.

GCMS investigation of volatile compounds in green coffee affected by potato taste defect and the Antestia bug.

PubMed

Jackels, Susan C; Marshall, Eric E; Omaiye, Angelica G; Gianan, Robert L; Lee, Fabrice T; Jackels, Charles F

2014-10-22

Potato taste defect (PTD) is a flavor defect in East African coffee associated with Antestiopsis orbitalis feeding and 3-isopropyl-2-methoxypyrazine (IPMP) in the coffee. To elucidate the manifestation of PTD, surface and interior volatile compounds of PTD and non-PTD green coffees were sampled by headspace solid phase microextraction and analyzed by gas chromatography mass spectrometry. Principal component analysis of the chromatographic data revealed a profile of surface volatiles distinguishing PTD from non-PTD coffees dominated by tridecane, dodecane, and tetradecane. While not detected in surface volatiles, IPMP was found in interior volatiles of PTD coffee. Desiccated antestia bugs were analyzed by GCMS, revealing that the three most prevalent volatiles were tridecane, dodecane, and tetradecane, as was found in the surface profile PTD coffee. Coffee having visible insect damage exhibited both a PTD surface volatile profile and IPMP in interior volatiles, supporting the hypothesis linking antestia bug feeding activity with PTD profile compounds on the surface and IPMP in the interior of the beans.

Enhanced heat transfer surface for cast-in-bump-covered cooling surfaces and methods of enhancing heat transfer

DOEpatents

Chiu, Rong-Shi Paul; Hasz, Wayne Charles; Johnson, Robert Alan; Lee, Ching-Pang; Abuaf, Nesim

2002-01-01

An annular turbine shroud separates a hot gas path from a cooling plenum containing a cooling medium. Bumps are cast in the surface on the cooling side of the shroud. A surface coating overlies the cooling side surface of the shroud, including the bumps, and contains cooling enhancement material. The surface area ratio of the cooling side of the shroud with the bumps and coating is in excess of a surface area ratio of the cooling side surface with bumps without the coating to afford increased heat transfer across the element relative to the heat transfer across the element without the coating.

Inhibiting surface crystallization of amorphous indomethacin by nanocoating.

PubMed

Wu, Tian; Sun, Ye; Li, Ning; de Villiers, Melgardt M; Yu, Lian

2007-04-24

An amorphous solid (glass) may crystallize faster at the surface than through the bulk, making surface crystallization a mechanism of failure for amorphous pharmaceuticals and other materials. An ultrathin coating of gold or polyelectrolytes inhibited the surface crystallization of amorphous indomethacin (IMC), an anti-inflammatory drug and model organic glass. The gold coating (10 nm) was deposited by sputtering, and the polyelectrolyte coating (3-20 nm) was deposited by an electrostatic layer-by-layer assembly of cationic poly(dimethyldiallyl ammonium chloride) (PDDA) and anionic sodium poly(styrenesulfonate) (PSS) in aqueous solution. The coating also inhibited the growth of existing crystals. The inhibition was strong even with one layer of PDDA. The polyelectrolyte coating still permitted fast dissolution of amorphous IMC and improved its wetting and flow. The finding supports the view that the surface crystallization of amorphous IMC is enabled by the mobility of a thin layer of surface molecules, and this mobility can be suppressed by a coating of only a few nanometers. This technique may be used to stabilize amorphous drugs prone to surface crystallization, with the aqueous coating process especially suitable for drugs of low aqueous solubility.

In Vitro Biocompatibility of Si Alloyed Multi-Principal Element Carbide Coatings

PubMed Central

Vladescu, Alina; Titorencu, Irina; Dekhtyar, Yuri; Jinga, Victor; Pruna, Vasile; Balaceanu, Mihai; Dinu, Mihaela; Pana, Iulian; Vendina, Viktorija

2016-01-01

In the current study, we have examined the possibility to improve the biocompatibility of the (TiZrNbTaHf)C through replacement of either Ti or Ta by Si. The coatings were deposited on Si and 316L stainless steel substrates by magnetron sputtering in an Ar+CH4 mixed atmosphere and were examined for elemental composition, chemical bonds, surface topography, surface electrical charge and biocompatible characteristics. The net surface charge was evaluated at nano and macroscopic scale by measuring the electrical potential and work function, respectively. The biocompatible tests comprised determination of cell viability and cell attachment to the coated surface. The deposited coatings had C/(metal+Si) ratios close to unity, while a mixture of metallic carbide, free-carbon and oxidized species formed on the film surface. The coatings’ surfaces were smooth and no influence of surface roughness on electrical charge or biocompatibility was found. The biocompatible characteristics correlated well with the electrical potential/work function, suggesting a significant role of surface charge in improving biocompatibility, particularly cell attachment to coating's surface. Replacement of either Ti or Ta by Si in the (TiZrNbTaHf)C coating led to an enhanced surface electrical charge, as well as to superior biocompatible properties, with best results for the (TiZrNbSiHf)C coating. PMID:27571361

High wear resistance of femoral components coated with titanium nitride: a retrieval analysis.

PubMed

Fabry, Christian; Zietz, Carmen; Baumann, Axel; Ehall, Reinhard; Bader, Rainer

2017-05-20

The objective of this study was to evaluate the in vivo wear resistance of cobalt-chromium femoral components coated with titanium nitride (TiN). Our null hypothesis was that the surface damage and the thickness of the TiN coating do not correlate with the time in vivo. Twenty-five TiN-coated bicondylar femoral retrievals with a mean implantation period of 30.7 ± 11.7 months were subjected to an objective surface damage analysis with a semi-quantitative assessment method. A visual examination of scratches, indentations, notches and coating breakthroughs of the surfaces was performed. The roughness and the coating thickness of the TiN coating were evaluated in the main articulation regions. Narrow scratches and indentations in the range of low flexion angles on the retrieval surfaces were the most common modes of damage. There was no evidence of delamination on the articulation surface but rather at the bottom of isolated severe indentations or notches. An analysis of three retrievals revealed a coating breakthrough in the patellofemoral joint region, resulting from patella maltracking and a dislocation. The arithmetical mean roughness of the TiN surface slightly increased with the implantation period. In contrast, the maximum peak height of the roughness profile was reduced at the condyles of the retrieved components in comparison with new, unused surfaces. No significant association between the coating thickness and implantation period was determined. Moreover, the measured values were retained in the range of the initial coating thickness even after several years of in vivo service. As was demonstrated by the results of this study, the surface damage to the TiN coating did not deteriorate with the implantation period. The calculated damage scores and the measured coating thickness in particular both confirmed that the TiN coating provides low wear rates. Our findings support the use of wear-resistant TiN-coated components in total knee arthroplasty with the objective of reducing the risk of aseptic loosening. However, in terms of TiN-coated femoral components, particular attention should be paid to a correct patellar tracking in order to avoid wear propagation at the implant.

Coating thickness affects surface stress measurement of brush electro-plating nickel coating using Rayleigh wave approach.

PubMed

Liu, Bin; Dong, Shiyun; Xu, Binshi; He, Peng

2012-09-01

A surface ultrasonic wave approach was presented for measuring surface stress of brush electro-plating nickel coating specimen, and the influence of coating thickness on surface stress measurement was discussed. In this research, two Rayleigh wave transducers with 5MHz frequency were employed to collect Rayleigh wave signals of coating specimen with different static tensile stresses and different coating thickness. The difference in time of flight between two Rayleigh wave signals was determined based on normalized cross correlation function. The influence of stress on propagation velocity of Rayleigh wave and the relationship between the difference in time of flight and tensile stress that corresponded to different coating thickness were discussed. Results indicate that inhomogeneous deformation of coating affects the relationship between the difference in time of flight and tensile stress, velocity of Rayleigh wave propagating in coating specimen increases with coating thickness increasing, and the variation rate reduces of difference in time of flight with tensile stress increasing as coating thickness increases. Copyright © 2012 Elsevier B.V. All rights reserved.

Lotus Dust Mitigation Coating and Molecular Adsorber Coating

NASA Technical Reports Server (NTRS)

O'Connor, Kenneth M.; Abraham, Nithin S.

2015-01-01

NASA Goddard Space Flight Center has developed two unique coating formulations that will keep surfaces clean and sanitary and contain contaminants.The Lotus Dust Mitigation Coating, modeled after the self-cleaning, water-repellant lotus leaf, disallows buildup of dust, dirt, water, and more on surfaces. This coating, has been successfully tested on painted, aluminum, glass, silica, and some composite surfaces, could aid in keeping medical assets clean.The Molecular Adsorber Coating is a zeolite-based, sprayable molecular adsorber coating, designed to prevent outgassing in materials in vacuums. The coating works well to adsorb volatiles and contaminates in manufacturing and processing, such as in pharmaceutical production. The addition of a biocide would also aid in controlling bacteria levels.

40 CFR 63.5746 - How do I demonstrate compliance with the emission limits for aluminum wipedown solvents and...

Code of Federal Regulations, 2014 CFR

2014-07-01

...) to determine the density of each aluminum surface coating and wipedown solvent. (d) Compliance is... Surface Coating Operations § 63.5746 How do I demonstrate compliance with the emission limits for aluminum... (liters of solids per liter of coating, or volume fraction) of each aluminum surface coating, including...

40 CFR 63.5746 - How do I demonstrate compliance with the emission limits for aluminum wipedown solvents and...

Code of Federal Regulations, 2013 CFR

2013-07-01

...) to determine the density of each aluminum surface coating and wipedown solvent. (d) Compliance is... Surface Coating Operations § 63.5746 How do I demonstrate compliance with the emission limits for aluminum... (liters of solids per liter of coating, or volume fraction) of each aluminum surface coating, including...

The biological response to laser-aided direct metal-coated Titanium alloy (Ti6Al4V)

PubMed Central

Shin, T.; Lim, D.; Kim, Y. S.; Kim, S. C.; Jo, W. L.

2018-01-01

Objectives Laser-engineered net shaping (LENS) of coated surfaces can overcome the limitations of conventional coating technologies. We compared the in vitro biological response with a titanium plasma spray (TPS)-coated titanium alloy (Ti6Al4V) surface with that of a Ti6Al4V surface coated with titanium using direct metal fabrication (DMF) with 3D printing technologies. Methods The in vitro ability of human osteoblasts to adhere to TPS-coated Ti6Al4V was compared with DMF-coating. Scanning electron microscopy (SEM) was used to assess the structure and morphology of the surfaces. Biological and morphological responses to human osteoblast cell lines were then examined by measuring cell proliferation, alkaline phosphatase activity, actin filaments, and RUNX2 gene expression. Results Morphological assessment of the cells after six hours of incubation using SEM showed that the TPS- and DMF-coated surfaces were largely covered with lamellipodia from the osteoblasts. Cell adhesion appeared similar in both groups. The differences in the rates of cell proliferation and alkaline phosphatase activities were not statistically significant. Conclusions The DMF coating applied using metal 3D printing is similar to the TPS coating, which is the most common coating process used for bone ingrowth. The DMF method provided an acceptable surface structure and a viable biological surface. Moreover, this method is automatable and less complex than plasma spraying. Cite this article: T. Shin, D. Lim, Y. S. Kim, S. C. Kim, W. L. Jo, Y. W. Lim. The biological response to laser-aided direct metal-coated Titanium alloy (Ti6Al4V). Bone Joint Res 2018;7:357–361. DOI: 10.1302/2046-3758.75.BJR-2017-0222.R1. PMID:29922456

Ultrasound assisted deposition of silica coatings on titanium

NASA Astrophysics Data System (ADS)

Kaş, Recep; Ertaş, Fatma Sinem; Birer, Özgür

2012-10-01

We present a novel ultrasound assisted method for silica coating of titanium surfaces. The coatings are formed by “smashing” silica nanoparticles onto activated titanium surface in solution using intense ultrasonic field. Homogeneous silica coatings are formed by deposition of dense multiple layers of silica nanoparticles. Since the nanoparticles also grow during the reaction, the layers of the coatings have smaller particles on the substrate and larger particles towards the surface. The thickness of the coatings can be controlled with several experimental parameters. Silica layers with thickness over 200 nm are readily obtained.

Amphiphilic polymer based on fluoroalkyl and PEG side chains for fouling release coating

NASA Astrophysics Data System (ADS)

Cong, W. W.; Wang, K.; Yu, X. Y.; Zhang, H. Q.; Lv, Z.; Gui, T. J.

2017-12-01

Under static conditions, fouling release coating could not express good release property to marine organisms. Amphiphilic polymer with mixture of fluorinated monomer and short side group of polyethylene glycol (PEG) was synthesized. And also we studied the ability of amphiphilic polymer to influence the surface properties and how it controlled the adhesion of marine organisms to coated surfaces. By incorporating fluorinated monomer and PEG side chain into the polymer, the effect of incorporating both polar and non-polar groups on fouling-release coating could be studied. The dry surface was characterized by three-dimensional digital microscopy and scanning electron microscopy (SEM), and the morphology of the amphiphilic fouling release coating showed just like flaky petal. The amphiphilic polymer in fouling release coating tended to reconstruct in water, and the ability was examined by static contact angle, which was smaller than the PDMS (polydimethylsiloxane) fouling release coating. Also surface energy was calculated by three solvents, and surface energy of amphiphilic fouling release coating was higher than that of the PDMS fouling release coating. To understand more about its fouling release property, seawater exposure method was adopted in gulf of Qingdao port. Fewer diatoms Navicula were found in biofilm after using amphiphilic fouling release coating. In general, coating containing both PEG and fluorinated side chain possessed certain fouling release property.

Process for manufacture of inertial confinement fusion targets and resulting product

DOEpatents

Masnari, Nino A.; Rensel, Walter B.; Robinson, Merrill G.; Solomon, David E.; Wise, Kensall D.; Wuttke, Gilbert H.

1982-01-01

An ICF target comprising a spherical pellet of fusion fuel surrounded by a concentric shell; and a process for manufacturing the same which includes the steps of forming hemispheric shells of a silicon or other substrate material, adhering the shell segments to each other with a fuel pellet contained concentrically therein, then separating the individual targets from the parent substrate. Formation of hemispheric cavities by deposition or coating of a mold substrate is also described. Coatings or membranes may also be applied to the interior of the hemispheric segments prior to joining.

From Coating to Dopant: How the Transition Metal Composition Affects Alumina Coatings on Ni-Rich Cathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Binghong; Key, Baris; Lapidus, Saul H.

Surface alumina coatings have been shown to be an effective way to improve the stability and cyclability of cathode materials. However, a detailed understanding of the relationship between the surface coatings and the bulk layered oxides is needed to better define the critical cathode–electrolyte interface. In this work, we systematically studied the effect of the composition of Ni-rich LiNi xMn yCo 1–x–yO 2 (NMC) on the surface alumina coatings. Changing cathode composition from LiNi 0.5Mn 0.3Co 0.2O 2 (NMC532) to LiNi 0.6Mn 0.2Co 0.2O 2 (NMC622) and LiNi 0.8Mn 0.1Co 0.1O 2 (NMC811) was found to facilitate the diffusion ofmore » surface alumina into the bulk after high-temperature annealing. By use of a variety of spectroscopic techniques, Al was seen to have a high bulk compatibility with higher Ni/Co content, and low bulk compatibility was associated with Mn in the transition metal layer. It was also noted that the cathode composition affected the observed morphology and surface chemistry of the coated material, which has an effect on electrochemical cycling. The presence of a high surface Li concentration and strong alumina diffusion into the bulk led to a smoother surface coating on NMC811 with no excess alumina aggregated on the surface. Structural characterization of pristine NMC particles also suggests surface Co segregation, which may act to mediate the diffusion of the Al from the surface to the bulk. The diffusion of Al into the bulk was found to be detrimental to the protection function of surface coatings leading to poor overall cyclability, indicating the importance of compatibility between surface coatings and bulk oxides on the electrochemical performance of coated cathode materials.In conclusion, these results are important in developing a better coating method for synthesis of next-generation cathode materials for lithium-ion batteries.« less

From Coating to Dopant: How the Transition Metal Composition Affects Alumina Coatings on Ni-Rich Cathodes

DOE PAGES

Han, Binghong; Key, Baris; Lapidus, Saul H.; ...

2017-11-01

Surface alumina coatings have been shown to be an effective way to improve the stability and cyclability of cathode materials. However, a detailed understanding of the relationship between the surface coatings and the bulk layered oxides is needed to better define the critical cathode–electrolyte interface. In this work, we systematically studied the effect of the composition of Ni-rich LiNi xMn yCo 1–x–yO 2 (NMC) on the surface alumina coatings. Changing cathode composition from LiNi 0.5Mn 0.3Co 0.2O 2 (NMC532) to LiNi 0.6Mn 0.2Co 0.2O 2 (NMC622) and LiNi 0.8Mn 0.1Co 0.1O 2 (NMC811) was found to facilitate the diffusion ofmore » surface alumina into the bulk after high-temperature annealing. By use of a variety of spectroscopic techniques, Al was seen to have a high bulk compatibility with higher Ni/Co content, and low bulk compatibility was associated with Mn in the transition metal layer. It was also noted that the cathode composition affected the observed morphology and surface chemistry of the coated material, which has an effect on electrochemical cycling. The presence of a high surface Li concentration and strong alumina diffusion into the bulk led to a smoother surface coating on NMC811 with no excess alumina aggregated on the surface. Structural characterization of pristine NMC particles also suggests surface Co segregation, which may act to mediate the diffusion of the Al from the surface to the bulk. The diffusion of Al into the bulk was found to be detrimental to the protection function of surface coatings leading to poor overall cyclability, indicating the importance of compatibility between surface coatings and bulk oxides on the electrochemical performance of coated cathode materials.In conclusion, these results are important in developing a better coating method for synthesis of next-generation cathode materials for lithium-ion batteries.« less

"Effect of nano-filled surface coating agent on fluoride release from conventional glass ionomer cement: an in vitro trial".

PubMed

Tiwari, S; Nandlal, B

2013-01-01

To overcome the drawbacks of glass ionomer cement of sensitivity to initial desiccation and moisture contamination the use of surface coating agent is recommended. The search in this area led to invent of use of nanofillers in surface coating agent, but its effect on fluoride release is not clear. The aim of this study is to evaluate and compare the fluoride release from conventional glass ionomer cement with and without surface coating agent. This in vitro study comprised of total 80 samples (40 samples of each with and without surface coating). Specimens were prepared, G coat plus was applied and light cured. Fluoride release of the sample was measured every 24 h for 7 days and weekly from 7th to 21 st day using Sension4 pH/ISE/MV Meter. Descriptive Statistics, Repeated Measure ANOVA, Paired Sample t-test, Independent Sample t-test, Scheffe post hoc test. Mean values clearly reveal a significant decrease in the fluoride release from day 1 to day 21 for both groups. Non-coated group released significantly more fluoride than surface coated group (P<0.001). It can be concluded that nanofilled surface coating agent will reduce the amount of fluoride released into oral environment as compared to non-coated group and at the same time releasing fluoride into surrounding cavity walls to create zones of inhibition into the cavity floor to help internal remineralization.

Efficient removal of crystal violet using Fe3O4-coated biochar: the role of the Fe3O4 nanoparticles and modeling study their adsorption behavior

NASA Astrophysics Data System (ADS)

Sun, Pengfei; Hui, Cai; Azim Khan, Rashid; Du, Jingting; Zhang, Qichun; Zhao, Yu-Hua

2015-07-01

Biochar shows great promise for use in adsorbing pollutants. However, a process for enhancing its adsorption capacity and re-collection efficiency is yet to be further developed. Hence, in this study, we developed a type of biochar coated with magnetic Fe3O4 nanoparticles (i.e., magnetic biochar (MBC)) and assessed its use for crystal violet (CV) adsorption as well as its recycling potential. The coating of Fe3O4 nanoparticles, which was not only on the surface, but also in the interior of biochar, performed two functions. Firstly, it produced a saturation magnetization of 61.48 emu/g, which enabled the biochar being efficiently re-collected using a magnet. Secondly, it significantly enhanced the adsorption capacity of the biochar (from 80.36 to 99.19 mg/g). The adsorption capacity of the MBC was determined to be the largest by so far (349.40 mg/g) for an initial CV concentration of 400 mg/L, pH of 6.0, and temperature of 40 °C, and the adsorption capacity of re-collected MBC was 73.31 mg/g. The adsorption of CV by the MBC was found to be a spontaneous and endothermic physical process in which the intraparticle diffusion was the limiting step. These findings inspire us to use other similar materials to tackle the menace of pollutions.

Scanning electron microscope investigation of the structural growth in thick sputtered coatings

NASA Technical Reports Server (NTRS)

Spalvins, T.

1975-01-01

Sputtered S-Monel, silver, and 304 stainless steel coatings and molybdenum disulfide coatings were deposited on mica and metal substrates with various surface finishes to investigate the structural growth of the coating by scanning electron microscopy. The geometry and the surface morphology of the nodules are characterized. Compositional changes within the coating were analyzed by energy dispersive X-ray analysis. Defects in the surface finish act as preferential nucleation sites and form isolated overlapping and complex nodules and various unusual surface overgrowths on the coating. The nodule boundaries are very vulnerable to chemical etching and these nodules do not disappear after full annealing. Further, they have undesirable effects on mechanical properties; cracks are initiated at the nodules when the coating is stressed by mechanical forces.

76 FR 12852 - Louisiana Regulatory Program/Abandoned Mine Land Reclamation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-09

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 918... Reclamation Plan AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Final rule; approval of amendment. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM), are...

75 FR 60373 - Louisiana Regulatory Program/Abandoned Mine Land Reclamation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-30

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 918... Reclamation Plan AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule... of Surface Mining Reclamation and Enforcement (OSM), are announcing receipt of a proposed amendment...

77 FR 16259 - Notice of Proposed Information Collection for 1029-0059

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-20

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement Notice of Proposed Information Collection for 1029-0059 AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior..., the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing its intention to request...

The influence of repellent coatings on surface free energy of glass plate and cotton fabric

NASA Astrophysics Data System (ADS)

Černe, Lidija; Simončič, Barbara; Željko, Matjaž

2008-08-01

The aim of this research was to determine the influence of chemical finishes on the surface properties of glass plate, considered as a model homogeneous smooth surface and cotton fabric as a non-ideal heterogeneous rough surface. Microscopic slides and 100% cotton fabric in plain weave were coated with fluorocarbon polymers (FCP), paraffin waxes with zirconium salts (PWZ), methylolmelamine derivatives (MMD), polysiloxanes with side alkyldimethylammonium groups (PSAAC) and aminofunctional polysiloxanes (AFPS). From the goniometer contact angle measurements of different liquids, the surface free energy of the coated glass plates was calculated according to approaches by Owens-Wendt-Kaelble, Wu, van Oss-Chaudhury-Good, and Li-Neumann-Kwok. The results showed that all the coatings decreased the surface free energy of the substrate, which was also influenced by the liquid combination and the theoretical approach used. In spite of the fact that the liquid contact angles were much higher on the coated fabric samples than on glass plates and resulted in the lower values of work of adhesion, a very good correlation between the coatings deposited on both substrates was obtained. The presence of repellent coatings FCP, PWZ and MMD converted the solid surface from polar to highly apolar by masking the functional groups of glass and cellulose. PSAAC and AFPS coatings did not decrease the solid surface free energy to such an extent as the former three coatings due to their monopolar character.

Photocatalytic activity of titania coatings synthesised by a combined laser/sol–gel technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adraider, Y.; Pang, Y.X., E-mail: F6098038@tees.ac.uk; Nabhani, F.

2014-06-01

Highlights: • Sol–gel method was used to prepare titania coatings. • Titania thin films were coated on substrate surface by dip coating. • Fibre laser was employed to irradiate the titania coated surfaces. • Photocatalytic efficiency of titania coatings was significantly improved after laser processing. - Abstract: Titania coatings were prepared using sol–gel method and then applied on the substrate surface by dip coating. Fibre laser (λ = 1064 nm) in continuous wave mode was used to irradiate the titania coated surfaces at different specific energies. The ATR-FTIR, XRD, SEM, EDS and contact angle measurement were employed to analyse surfacemore » morphology, phase composition and crystalline structure of laser-irradiated titania coatings, whilst the photocatalytic activity was evaluated by measuring the decomposition of methylene blue (MB) after exposure to the visible light for various illumination times. Results showed that the laser-irradiated titania coatings demonstrate significant different composition and microstructure in comparison with the as-coated from the same sol–gel titania. Photocatalytic efficiency of titania coatings was significantly improved after laser processing. The photocatalytic activity of laser-irradiated titania coatings was higher than that of the as-coated titania. The titania coating processed at laser specific energy of 6.5 J/mm{sup 2} exhibited the highest photocatalytic activity among all titania samples.« less

"Electroless" E-Coating for Magnesium Alloys

NASA Astrophysics Data System (ADS)

Song, Guang-Ling

By utilizing the unique electrochemistry of Mg, a thin organic film can rapidly be deposited on the surface of a Mg alloy by dipping the Mg alloy in a cathodic E-coating bath solution without applying a current or potential. The self-deposited coating is selectively formed on Mg alloy surfaces. Although the "electroless" E-coating pre-film is relatively thin, it can offer sufficient corrosion protection for Mg alloys in a chloride-containing environment. The stability of the film can be significantly improved after curing. The corrosion resistance of the substrate Mg alloy has an important effect on the corrosion protection performance of the coating. The coating is more protective on a corrosion resistant Mg alloy than on a non-corrosion resistant Mg substrate. The coating protection performance is also influenced by the substrate surface condition or pre-treatment process. Wet cleaning + heat-treatment may be a cost-effective surface preparation/treatment for the "electroless" E-coating in industrial applications.

Aluminium Electroplating on Steel from a Fused Bromide Electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prabhat Tripathy; Laura Wurth; Eric Dufek

A quaternary bromide bath (LiBr-KBr-CsBr-AlBr3) was used to electro-coat aluminium on steel substrates. The electrolyte was prepared by the addition of AlBr3 into the eutectic LiBr-KBr-CsBr melt. A smooth, thick, adherent and shiny aluminium coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminium coverage. Both salt immersion and open circuit potential measurement suggest that the coatings did display good corrosion-resistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminium coating inmore » preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminium coating on both ferrous and non-ferrous metals, including complex surfaces/geometries.« less

Self-cleaning antimicrobial surfaces by bio-enabled growth of SnO2 coatings on glass

NASA Astrophysics Data System (ADS)

André, Rute; Natalio, Filipe; Tahir, Muhammad Nawaz; Berger, Rüdiger; Tremel, Wolfgang

2013-03-01

Conventional vapor-deposition techniques for coatings require sophisticated equipment and/or high-temperature resistant substrates. Therefore bio-inspired techniques for the fabrication of inorganic coatings have been developed in recent years. Inspired by the biology behind the formation of the intricate skeletons of diatoms orchestrated by a class of cationic polyamines (silaffins) we have used surface-bound spermine, a naturally occurring polyamine, to promote the fast deposition of homogeneous, thin and transparent biomimetic SnO2 coatings on glass surfaces. The bio-enabled SnO2 film is highly photoactive, i.e. it generates superoxide radicals (O2&z.rad;-) upon sunlight exposure resulting in a strong degradation of organic contaminants and a strong antimicrobial activity. Upon illumination the biomimetic SnO2 coating exhibits a switchable amphiphilic behavior, which - in combination with its photoactivity - creates a self-cleaning surface. The intrinsic self-cleaning properties could lead to the development of new protective, antifouling coatings on various substrates.Conventional vapor-deposition techniques for coatings require sophisticated equipment and/or high-temperature resistant substrates. Therefore bio-inspired techniques for the fabrication of inorganic coatings have been developed in recent years. Inspired by the biology behind the formation of the intricate skeletons of diatoms orchestrated by a class of cationic polyamines (silaffins) we have used surface-bound spermine, a naturally occurring polyamine, to promote the fast deposition of homogeneous, thin and transparent biomimetic SnO2 coatings on glass surfaces. The bio-enabled SnO2 film is highly photoactive, i.e. it generates superoxide radicals (O2&z.rad;-) upon sunlight exposure resulting in a strong degradation of organic contaminants and a strong antimicrobial activity. Upon illumination the biomimetic SnO2 coating exhibits a switchable amphiphilic behavior, which - in combination with its photoactivity - creates a self-cleaning surface. The intrinsic self-cleaning properties could lead to the development of new protective, antifouling coatings on various substrates. Electronic supplementary information (ESI) available: (1) QCM measurement of SnO2 deposition on spermine functionalized silica-based sensors, (2) scheme of the surface functionalization procedure, (3) FTIR-ATR analysis of polyamine (spermine) functionalized glass surfaces, (4) FITC staining of amine groups on glass surfaces, (5) AFM height analysis of bare, spermine coated and SnO2 coated glass slides, (6) SEM micrograph of a spermine functionalized SnO2 coated glass slide, (7) XPS analysis of SnO2 coated surfaces, (8) kinetic profile of rhodamine B degradation with spermine/SnO2, (9) control experiments for the photodegradation of rhodamine B, (10) comparison with commercial SnO2 catalyst, (11) incubation of non-functionalized glass surfaces with E. coli, and (12) incubation of SnO2 coated glass surfaces with E. coli. See DOI: 10.1039/c3nr00007a

Porous Organic Nanolayers for Coating of Solid-state Devices

PubMed Central

2011-01-01

Background Highly hydrophobic surfaces can have very low surface energy and such low surface energy biological interfaces can be obtained using fluorinated coatings on surfaces. Deposition of biocompatible organic films on solid-state surfaces is attained with techniques like plasma polymerization, biomineralization and chemical vapor deposition. All these require special equipment or harsh chemicals. This paper presents a simple vapor-phase approach to directly coat solid-state surfaces with biocompatible films without any harsh chemical or plasma treatment. Hydrophilic and hydrophobic monomers were used for reaction and deposition of nanolayer films. The monomers were characterized and showed a very consistent coating of 3D micropore structures. Results The coating showed nano-textured surface morphology which can aid cell growth and provide rich molecular functionalization. The surface properties of the obtained film were regulated by varying monomer concentrations, reaction time and the vacuum pressure in a simple reaction chamber. Films were characterized by contact angle analysis for surface energy and with profilometer to measure the thickness. Fourier Transform Infrared Spectroscopy (FTIR) analysis revealed the chemical composition of the coated films. Variations in the FTIR results with respect to different concentrations of monomers showed the chemical composition of the resulting films. Conclusion The presented approach of vapor-phase coating of solid-state structures is important and applicable in many areas of bio-nano interface development. The exposure of coatings to the solutions of different pH showed the stability of the coatings in chemical surroundings. The organic nanocoating of films can be used in bio-implants and many medical devices. PMID:21569579

Influence of pretreatment on the surface characteristics of PLLA fibers and subsequent hydroxyapatite coating.

PubMed

Peng, F; Olson, J R; Shaw, M T; Wei, M

2009-01-01

A fibrous precursor for bone repair composites was made by coating poly(L-lactide) (PLLA) fibers with hydroxyapatite (HA) using a biomimetic method. To enhance the bonding between the HA coating and the PLLA fiber, PLLA fibers were etched with either sodium hydroxide or sodium hypochlorite to generate carboxyl groups on fiber surfaces. The experiments were designed to determine the influence of etching on the fiber surface morphology and chemistry as well as the subsequent HA coating on the etched fiber surfaces. It was found that the etching pretreatment increased the roughness as well as the hydrophilicity of fibers, indicating that hydrolysis of PLLA chains had taken place on fiber surfaces. The etching pretreatment also promoted HA coating formation by introducing thicker coating on the surface of fibers with a longer etching time, a higher etching concentration, or with NaOCl as the etching agent. A mechanism of surface hydrolysis and oxidation of PLLA was proposed. (c) 2008 Wiley Periodicals, Inc.

Methods for making deposited films with improved microstructures

DOEpatents

Patten, James W.; Moss, Ronald W.; McClanahan, Edwin D.

1982-01-01

Methods for improving microstructures of line-of-sight deposited films are described. Columnar growth defects ordinarily produced by geometrical shadowing during deposition of such films are eliminated without resorting to post-deposition thermal or mechanical treatments. The native, as-deposited coating qualities, including homogeneity, fine grain size, and high coating-to-substrate adherence, can thus be retained. The preferred method includes the steps of emitting material from a source toward a substrate to deposit a coating non-uniformly on the substrate surface, removing a portion of the coating uniformly over the surface, again depositing material onto the surface, but from a different direction, and repeating the foregoing steps. The quality of line-of-sight deposited films such as those produced by sputtering, progressively deteriorates as the angle of incidence between the flux and the surface becomes increasingly acute. Depositing non-uniformly, so that the coating becomes progressively thinner as quality deteriorates, followed by uniformly removing some of the coating, such as by resputtering, eliminates the poor quality portions, leaving only high quality portions of the coating. Subsequently sputtering from a different direction applies a high quality coating to other regions of the surface. Such steps can be performed either simultaneously or sequentially to apply coatings of a uniformly high quality, closed microstructure to three-dimensional or larger planar surfaces.

Deposited films with improved microstructures

DOEpatents

Patten, James W.; Moss, Ronald W.; McClanahan, Edwin D.

1984-01-01

Methods for improving microstructures of line-of-sight deposited films are described. Columnar growth defects ordinarily produced by geometrical shadowing during deposition of such films are eliminated without resorting to post-deposition thermal or mechanical treatments. The native, as-deposited coating qualities, including homogeneity, fine grain size, and high coating-to-substrate adherence, can thus be retained. The preferred method includes the steps of emitting material from a source toward a substrate to deposit a coating non-uniformly on the substrate surface, removing a portion of the coating uniformly over the surface, again depositing material onto the surface, but from a different direction, and repeating the foregoing steps. The quality of line-of-sight deposited films such as those produced by sputtering, progressively deteriorates as the angle of incidence between the flux and the surface becomes increasingly acute. Depositing non-uniformly, so that the coating becomes progressively thinner as quality deteriorates, followed by uniformly removing some of the coating, such as by resputtering, eliminates the poor quality portions, leaving only high quality portions of the coating. Subsequently sputtering from a different direction applies a high quality coating to other regions of the surface. Such steps can be performed either simultaneously or sequentially to apply coatings of a uniformly high quality, closed microstructure to three-dimensional or large planar surfaces.

[Study of Interaction between Fluorinated Coating Glass and the Medicines].

PubMed

Kawano, Yayoi; Otsu, Saki; Bamba, Takao; Hanawa, Takehisa

2017-11-01

 The adsorption of active pharmaceutical ingredients on the surface of medical devices such as polyvinl chloride, ethylene-vinyl acetate copolymer and glass often prevent the acuurate dose of drug. At dispensing of pharmaceuticals, mètre glass (MG) has been widely used for dispensing syrup. When measuring the viscous syrup, it often takes long time to dispense the accurate volume due to their adhesiveness on the glass surface. In this study, we investigate the adhesion of various syrups to MG made with uncoated glass or glass with a strongly hydrophobic silicone or fluorinated coating in terms of the following formulation parameters: viscosity, surface tension, contact angle, and surface free energy. The contact angles for syrups on the coated glass surfaces were significantly higher than those on the uncoated glass surface. In addition, the relationship between surface tension and contact angle was examined. We found that the contact angle was independent of surface tension for the uncoated glass, while it increased with increasing surface tension for the coated glasses. These results can be explained as follows: the silicone or fluorinated coatings inhibit the hydrogen bonding that usually takes place between water and silanol and siloxane groups at glass surfaces. The coatings reduced the surface free energy and increased the hydrophobicity of the glass, reduced its wettability by the syrups, and thus reduced the adhesion loss for the syrups. It was considered that as for the hydrophobic action, properties of matter of sample influence the coated device by coating in order that it is reinforced.

Multiple Fatigue Failure Behaviors and Long-Life Prediction Approach of Carburized Cr-Ni Steel with Variable Stress Ratio

PubMed Central

Deng, Hailong; Li, Wei; Zhao, Hongqiao; Sakai, Tatsuo

2017-01-01

Axial loading tests with stress ratios R of −1, 0 and 0.3 were performed to examine the fatigue failure behavior of a carburized Cr-Ni steel in the long-life regime from 104 to 108 cycles. Results show that this steel represents continuously descending S-N characteristics with interior inclusion-induced failure under R = −1, whereas it shows duplex S-N characteristics with surface defect-induced failure and interior inclusion-induced failure under R = 0 and 0.3. The increasing tension eliminates the effect of compressive residual stress and promotes crack initiation from the surface or interior defects in the carburized layer. The FGA (fine granular area) formation greatly depends on the number of loading cycles, but can be inhibited by decreasing the compressive stress. Based on the evaluation of the stress intensity factor at the crack tip, the surface and interior failures in the short life regime can be characterized by the crack growth process, while the interior failure with the FGA in the long life regime can be characterized by the crack initiation process. In view of the good agreement between predicted and experimental results, the proposed approach can be well utilized to predict fatigue lives associated with interior inclusion-FGA-fisheye induced failure, interior inclusion-fisheye induced failure, and surface defect induced failure. PMID:28906454

Effects of Laser Re-melting on the Corrosion Properties of HVOF Coatings

NASA Astrophysics Data System (ADS)

Yilbas, B. S.; Toor, I. H.; Patel, F.; Baig, M. A.

2013-05-01

HVOF coating of Inconel 625 powder on carbon steel is carried out. Laser melting of the resulting coating is realized to improve coating structural integrity. Morphological and microstructural changes are examined in the coating prior and after laser treatment process using scanning electron microscopy, energy dispersive spectroscopy, and x-ray diffraction (XRD). The residual stress developed is measured on the surface vicinity of the laser-treated coating using the XRD technique. The corrosion resistance of the laser-treated and untreated coating surfaces is measured, incorporating the potentiodynamic tests in 0.5 M NaCl aqueous solution. It is found that laser treatment reduces the pores and produces cellular structures with different sizes and orientations in the coating. Laser-controlled melting improves the corrosion resistance of the coating surface.

Coatings and Surface Treatments for Reusable Entry Systems

NASA Technical Reports Server (NTRS)

Johnson, Sylvia M.

2016-01-01

This talk outlines work in coatings for TPS done at NASA Ames. coatings and surface treatments on reusable TPS are critical for controlling the behavior of the materials. coatings discussed include RCG, TUFI and HETC. TUFROc is also discussed.

Robust Hydrophobic Surfaces from Suspension HVOF Thermal Sprayed Rare-Earth Oxide Ceramics Coatings.

PubMed

Bai, M; Kazi, H; Zhang, X; Liu, J; Hussain, T

2018-05-03

This study has presented an efficient coating method, namely suspension high velocity oxy-fuel (SHVOF) thermal spraying, to produce large super-hydrophobic ceramic surfaces with a unique micro- and nano-scale hierarchical structures to mimic natural super-hydrophobic surfaces. CeO 2 was selected as coatings material, one of a group of rare-earth oxide (REO) ceramics that have recently been found to exhibit intrinsic hydrophobicity, even after exposure to high temperatures and abrasive wear. Robust hydrophobic REO ceramic surfaces were obtained from the deposition of thin CeO 2 coatings (3-5 μm) using an aqueous suspension with a solid concentration of 30 wt.% sub-micron CeO 2 particles (50-200 nm) on a selection of metallic substrates. It was found that the coatings' hydrophobicity, microstructure, surface morphology, and deposition efficiency were all determined by the metallic substrates underneath. More importantly, it was demonstrated that the near super-hydrophobicity of SHVOF sprayed CeO 2 coatings was achieved not only by the intrinsic hydrophobicity of REO but also their unique hierarchically structure. In addition, the coatings' surface hydrophobicity was sensitive to the O/Ce ratio, which could explain the 'delayed' hydrophobicity of REO coatings.

76 FR 76104 - Arkansas Regulatory Program and Abandoned Mine Land Reclamation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-06

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 904... Reclamation Plan AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation and...

77 FR 55430 - Arkansas Regulatory Program and Abandoned Mine Land Reclamation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-10

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 904... Reclamation Plan AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation and...

78 FR 41421 - Notice of Proposed Information Collection; Request for Comments

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-10

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement [S1D1S SS08011000... Collection; Request for Comments AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior..., the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing its intention to request...

78 FR 66381 - Notice of Proposed Information Collection; Request for Comments

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-05

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement [S1D1S SS08011000... Collection; Request for Comments AGENCY: Office of Surface Mining Reclamation and Enforcement, Interior..., the Office of Surface Mining Reclamation and Enforcement (OSM) is announcing that the information...

Robust and thermal-healing superhydrophobic surfaces by spin-coating of polydimethylsiloxane.

PubMed

Long, Mengying; Peng, Shan; Deng, Wanshun; Yang, Xiaojun; Miao, Kai; Wen, Ni; Miao, Xinrui; Deng, Wenli

2017-12-15

Superhydrophobic surfaces easily lose their excellent water-repellency after damages, which limit their broad applications in practice. Thus, the fabrication of superhydrophobic surfaces with excellent durability and thermal healing should be taken into consideration. In this work, robust superhydrophobic surfaces with thermal healing were successfully fabricated by spin-coating method. To achieve superhydrophobicity, cost-less and fluoride-free polydimethylsiloxane (PDMS) was spin-coated on rough aluminum substrates. After being spin-coated for one cycle, the superhydrophobic PDMS coated hierarchical aluminum (PDMS-H-Al) surfaces showed excellent tolerance to various chemical and mechanical damages in lab, and outdoor damages for 90days. When the PDMS-H-Al surfaces underwent severe damages such as oil contamination (peanut oil with high boiling point) or sandpaper abrasion (500g of force for 60cm), their superhydrophobicity would lose. Interestingly, through a heating process, cyclic oligomers generating from the partially decomposed PDMS acted as low-surface-energy substance on the damaged rough surfaces, leading to the recovery of superhydrophobicity. The relationship between the spin-coating cycles and surface wettability was also investigated. This paper provides a facile, fluoride-free and efficient method to fabricate superhydrophobic surfaces with thermal healing. Copyright © 2017. Published by Elsevier Inc.

Multiphase Combustion of Metalized Nanocomposite Energetic Materials

DTIC Science & Technology

2014-12-19

Materials, Energy & Fuels (01 2011) Eric Nixon, Michelle Pantoya, Ganapathy Sivakumar, Ashwin Vijayasai, Tim Dallas. Superhydrophobic Coatings for... Superhydrophobic Coatings for Nanoenergetic Material Combustion, Surface Coatings and Technology205, 5103-5108, 2011. 4. Dikici, B., Shaw, B...A., Dallas, T., Superhydrophobic Coatings for Nanoenergetic Material Combustion, Surface Coatings and Technology 205, 5103-5108, 2011. (3

SURFACE-COATING-FREE MATERIALS WORKSHOP SUMMARY REPORT

EPA Science Inventory

The report documents a pollution prevention workshop that explored the concenpt of surface-coating-free materials (SCFMs) and the potential impact of this type of amterial on volatile organic compound (VOC) and air toxic emissions from surface coating operations. he report summar...

Carbon-based nanostructured surfaces for enhanced phase-change cooling

NASA Astrophysics Data System (ADS)

Selvaraj Kousalya, Arun

To maintain acceptable device temperatures in the new generation of electronic devices under development for high-power applications, conventional liquid cooling schemes will likely be superseded by multi-phase cooling solutions to provide substantial enhancement to the cooling capability. The central theme of the current work is to investigate the two-phase thermal performance of carbon-based nanostructured coatings in passive and pumped liquid-vapor phase-change cooling schemes. Quantification of the critical parameters that influence thermal performance of the carbon nanostructured boiling surfaces presented herein will lead to improved understanding of the underlying evaporative and boiling mechanisms in such surfaces. A flow boiling experimental facility is developed to generate consistent and accurate heat transfer performance curves with degassed and deionized water as the working fluid. New means of boiling heat transfer enhancement by altering surface characteristics such as surface energy and wettability through light-surface interactions is explored in this work. In this regard, carbon nanotube (CNT) coatings are exposed to low-intensity irradiation emitted from a light emitting diode and the subcooled flow boiling performance is compared against a non-irradiated CNT-coated copper surface. A considerable reduction in surface superheat and enhancement in average heat transfer coefficient is observed. In another work involving CNTs, the thermal performance of CNT-integrated sintered wick structures is evaluated in a passively cooled vapor chamber. A physical vapor deposition process is used to coat the CNTs with varying thicknesses of copper to promote surface wetting with the working fluid, water. Thermal performance of the bare sintered copper powder sample and the copper-functionalized CNT-coated sintered copper powder wick samples is compared using an experimental facility that simulates the capillary fluid feeding conditions of a vapor chamber. Nanostructured samples having a thicker copper coating provided a considerable increase in dryout heat flux while maintaining lower surface superheat temperatures compared to a bare sintered powder sample; this enhancement is attributed primarily to the improved surface wettability. Dynamic contact angle measurements are conducted to quantitatively compare the surface wetting trends for varying copper coating thicknesses and confirm the increase in hydrophilicity with increasing coating thickness. The second and relatively new carbon nanostructured coating, carbon nanotubes decorated with graphitic nanopetals, are used as a template to manufacture boiling surfaces with heterogeneous wettability. Heat transfer surfaces with parallel alternating superhydrophobic and superhydrophilic stripes are fabricated by a combination of oxygen plasma treatment, Teflon coating and shadow masking. Such composite wetting surfaces exhibit enhanced flow-boiling performance compared to homogeneous wetting surfaces. Flow visualization studies elucidate the physical differences in nucleate boiling mechanisms between the different heterogeneous wetting surfaces. The third and the final carbon nanomaterial, graphene, is examined as an oxidation barrier coating for liquid and liquid-vapor phase-change cooling systems. Forced convection heat transfer experiments on bare and graphene-coated copper surfaces reveal nearly identical liquid-phase and two-phase thermal performance for the two surfaces. Surface analysis after thermal testing indicates significant oxide formation on the entire surface of the bare copper substrate; however, oxidation is observed only along the grain boundaries of the graphene-coated substrate. Results suggest that few-layer graphene can act as a protective layer even under vigorous flow boiling conditions, indicating a broad application space of few-layer graphene as an ultra-thin oxidation barrier coating.

Lunar and Planetary Science XXXV: Mars: Surface Coatings, Mineralogy, and Surface Properties

NASA Technical Reports Server (NTRS)

2004-01-01

The session "Mars: Surface Coatings, Mineralogy, and Surface Properties" contained the following reports:High-Silica Rock Coatings: TES Surface-Type 2 and Chemical Weathering on Mars; Old Desert Varnish-like Coatings and Young Breccias at the Mars Pathfinder Landing Site; Analyses of IR-Stealthy and Coated Surface Materials: A Comparison of LIBS and Reflectance Spectra and Their Application to Mars Surface Exploration; Contrasting Interpretations of TES Spectra of the 2003 Rover:Opportunity-Landing Site: Hematite Coatings and Gray Hematite; A New Hematite Formation Mechanism for Mars; Geomorphic and Diagenetic Analogs to Hematite Regions on Mars: Examples from Jurassic Sandstones of Southern Utah, USA; The Geologic Record of Early Mars: A Layered, Cratered, and "Valley-"ed: Volume; A Simple Approach to Estimating Surface Emissivity with THEMIS; A Large Scale Topographic Correction for THEMIS Data; Thermophysical Properties of Meridiani Planum, Mars; Thermophysical and Spectral Properties of Gusev, the MER-Spirit Landing Site on Mars; Determining Water Content of Geologic Materials Using Reflectance Spectroscopy; and Global Mapping of Martian Bound Water at 6.1 Microns Based on TES Data: Seasonal Hydration.

Corrosion resistant solar mirror

DOEpatents

Medwick, Paul A.; Abbott, Edward E.

2016-07-19

A reflective article includes a transparent substrate having a first major surface and a second major surface. A base coat is formed over at least a portion of the second major surface. A primary reflective coating having at least one metallic layer is formed over at least a portion of the base coat. A protective coating is formed over at least a portion of the primary reflective coating. The article further includes a solar cell and an anode, with the solar cell connected to the metallic layer and the anode.

Inorganic Surface Coating with Fast Wetting-Dewetting Transitions for Liquid Manipulations.

PubMed

Yang, Yajie; Zhang, Liaoliao; Wang, Jue; Wang, Xinwei; Duan, Libing; Wang, Nan; Xiao, Fajun; Xie, Yanbo; Zhao, Jianlin

2018-06-06

Liquid manipulation is a fundamental issue for microfluidics and miniaturized sensors. Fast wetting-state transitions by optical methods have proven being efficient for liquid manipulations by organic surface coatings, however rarely been achieved by using inorganic coatings. Here, we report a fast optical-induced wetting-state transition surface achieved by inorganic coating, enabling tens of second transitions for a wetting-dewetting cycle, shortened from an hour, as typically reported. Here, we demonstrate a gravity-driven microfluidic reactor and switch it to a mixer after a second-step exposure in a minimum of within 80 s of UV exposure. The fast wetting-dewetting transition surfaces enable the fast switchable or erasable smart surfaces for water collection, miniature chemical reaction, or sensing systems by using inorganic surface coatings.

Surface spins disorder in uncoated and SiO2 coated maghemite nanoparticles

NASA Astrophysics Data System (ADS)

Zeb, F.; Nadeem, K.; Shah, S. Kamran Ali; Kamran, M.; Gul, I. Hussain; Ali, L.

2017-05-01

We studied the surface spins disorder in uncoated and silica (SiO2) coated maghemite (γ-Fe2O3) nanoparticles using temperature and time dependent magnetization. The average crystallite size for SiO2 coated and uncoated nanoparticles was about 12 and 29 nm, respectively. Scanning electron microscopy (SEM) showed that the nanoparticles are spherical in shape and well separated. Temperature scans of zero field cooled (ZFC)/field cooled (FC) magnetization measurements showed lower average blocking temperature (TB) for SiO2 coated maghemite nanoparticles as compared to uncoated nanoparticles. The saturation magnetization (Ms) of SiO2 coated maghemite nanoparticles was also lower than the uncoated nanoparticles and is attributed to smaller average crystallite size of SiO2 coated nanoparticles. For saturation magnetization vs. temperature data, Bloch's law (M(T)= M(0).(1- BTb)) was fitted well for both uncoated and SiO2 coated nanoparticles and yields: B =3×10-7 K-b, b=2.22 and B=0.0127 K-b, b=0.57 for uncoated and SiO2 coated nanoparticles, respectively. Higher value of B for SiO2 coated nanoparticles depicts decrease in exchange coupling due to enhanced surface spins disorder (broken surface bonds) as compared to uncoated nanoparticles. The Bloch's exponent b was decreased for SiO2 coated nanoparticles which is due to their smaller average crystallite size or finite size effects. Furthermore, a sharp increase of coercivity at low temperatures (<25 K) was observed for SiO2 coated nanoparticles which is also due to contribution of increased surface anisotropy or frozen surface spins in these smaller nanoparticles. The FC magnetic relaxation data was fitted to stretched exponential law which revealed slower magnetic relaxation for SiO2 coated nanoparticles. All these measurements revealed smaller average crystallite size and enhanced surface spins disorder in SiO2 coated nanoparticles than in uncoated γ-Fe2O3 nanoparticles.

MAPs/bFGF-PLGA microsphere composite-coated titanium surfaces promote increased adhesion and proliferation of fibroblasts.

PubMed

Wang, Zhongshan; Wu, Guofeng; Bai, Shizhu; Feng, Zhihong; Dong, Yan; Zhou, Jian; Qin, Haiyan; Zhao, Yimin

2014-06-01

Infection and epithelial downgrowth are two major problems with maxillofacial transcutaneous implants, and both are mainly due to lack of stable closure of soft tissues at transcutaneous sites. Fibroblasts have been shown to play a key role in the formation of biological seals. In this work, titanium (Ti) model surfaces were coated with mussel adhesive proteins (MAPs) utilizing its unique adhesion ability on diverse inorganic and organic surfaces in wet environments. Prepared basic fibroblast growth factor (bFGF)-poly(lactic-co-glycolic acid) (PLGA) microspheres can be easily synthesized and combined onto MAPs-coated Ti surfaces, due to the negative surface charges of microspheres in aqueous solution, which is in contrast to the positive charges of MAPs. Titanium model surfaces were divided into three groups. Group A: MAPs/bFGF-PLGA microspheres composite-coated Ti surfaces. Group B: MAPs-coated Ti surfaces. Group C: uncoated Ti surfaces. The effects of coated Ti surfaces on adhesion of fibroblasts, cytoskeletal organization, proliferation, and extracellular matrix (ECM)-related gene expressions were examined. The results revealed increased adhesion (P < 0.05), enhanced actin cytoskeletal organization, and up-regulated ECM-related gene expressions in groups A and B compared with group C. Increased proliferation of fibroblasts during five days of incubation was observed in group A compared with groups B and C (P < 0.05). Collectively, the results from this in vitro study demonstrated that MAPs/bFGF-PLGA microspheres composite-coated Ti surfaces had the ability to increase fibroblast functionality. In addition, MAPs/bFGF-PLGA microsphere composite-coated Ti surfaces should be studied further as a method of promoting formation of stable biological seals around transcutaneous sites.

Consolidation of Surface Coatings by Friction Stir Techniques

DTIC Science & Technology

2010-09-01

alloy samples were plasma sprayed with a Titanium-Nickel-Chrome coating or a Titanium coating. Single and multiple pass experiments were performed...based coatings onto the Aluminum alloy surface. Results showed that the most successful results were accomplished using a flat, pinless tool, with...properties. Aluminum alloy samples were plasma sprayed with a Titanium-Nickel-Chrome coating or a Titanium coating. Single and multiple pass experiments

Antibacterial and anticancer PDMS surface for mammalian cell growth using the Chinese herb extract paeonol(4-methoxy-2-hydroxyacetophenone)

NASA Astrophysics Data System (ADS)

Jiao, Jiajia; Sun, Lili; Guo, Zaiyu; Hou, Sen; Holyst, Robert; Lu, Yun; Feng, Xizeng

2016-12-01

Polydimethylsiloxane (PDMS) is widely used as a cell culture platform to produce micro- and nano-technology based microdevices. However, the native PDMS surface is not suitable for cell adhesion and is always subject to bacterial pollution and cancer cell invasion. Coating the PDMS surface with antibacterial or anticancer materials often causes considerable harm to the non-cancer mammalian cells on it. We have developed a method to fabricate a biocompatible PDMS surface which not only promotes non-cancer mammalian cell growth but also has antibacterial and anticancer activities, by coating the PDMS surface with a Chinese herb extract, paeonol. Coating changes the wettability and the elemental composition of the PDMS surface. Molecular dynamic simulation indicates that the absorption of paeonol onto the PDMS surface is an energy favourable process. The paeonol-coated PDMS surface exhibits good antibacterial activity against both Gram-positive and Gram-negative bacteria. Moreover considerable antibacterial activity is maintained after the coated surface is rinsed or incubated in water. The coated PDMS surface inhibits bacterial growth on the contact surface and promotes non-cancer mammalian cell growth with low cell toxicity; meanwhile the growth of cancer cells is significantly inhibited. Our study will potentially guide PDMS surface modification approaches to produce biomedical devices.

Investigation of dynamic characteristics of a rotor system with surface coatings

NASA Astrophysics Data System (ADS)

Yang, Yang; Cao, Dengqing; Wang, Deyou

2017-02-01

A Jeffcott rotor system with surface coatings capable of describing the mechanical vibration resulting from unbalance and rub-impact is formulated in this article. A contact force model proposed recently to describe the impact force between the disc and casing with coatings is employed to do the dynamic analysis for the rotor system with rubbing fault. Due to the variation of penetration, the contact force model is correspondingly modified. Meanwhile, the Coulomb friction model is applied to simulate the friction characteristics. Then, the case study of rub-impact with surface coatings is simulated by the Runge-Kutta method, in which a linear interpolation method is adopted to predict the rubbing instant. Moreover, the dynamic characteristics of the rotor system with surface coatings are analyzed in terms of bifurcation plot, waveform, whirl orbit, Poincaré map and spectrum plot. And the effects of the hardness of surface coatings on the response are investigated as well. Finally, compared with the classical models, the modified contact force model is shown to be more suitable to solve the rub-impact of aero-engine with surface coatings.

Testing and Optimization of Electrically Conductive Spacecraft Coatings

NASA Technical Reports Server (NTRS)

Mell, R. J.; Wertz, G. E.; Edwards, D. L. (Technical Monitor)

2001-01-01

This is the final report discussing the work done for the Space Environments and Effects (SEE) Program. It discusses test chamber design, coating research, and test results on electrically thermal control coatings. These thermal control coatings are being developed to have several orders of magnitude higher electrical conductivity than most available thermal control coatings. Most current coatings tend to have a range in surface resistivity from 1,011 to 1,013 ohms/sq. Historically, spacecraft have had thermal control surfaces composed of dielectric materials of either polymers (paints and metalized films) or glasses (ceramic paints and optical solar reflectors). Very seldom has the thermal control surface of a spacecraft been a metal where the surface would be intrinsically electrically conductive. The poor thermal optical properties of most metals have, in most cases, stopped them from being used as a thermal control surface. Metals low infrared emittance (generally considered poor for thermal control surfaces) and/or solar absorptance, have resulted in the use of various dielectric coatings or films being applied over the substrate materials in order to obtain the required optical properties.

Numerical methods for analyzing electromagnetic scattering

NASA Technical Reports Server (NTRS)

Lee, S. W.; Lo, Y. T.; Chuang, S. L.; Lee, C. S.

1985-01-01

Numerical methods to analyze electromagnetic scattering are presented. The dispersions and attenuations of the normal modes in a circular waveguide coated with lossy material were completely analyzed. The radar cross section (RCS) from a circular waveguide coated with lossy material was calculated. The following is observed: (1) the interior irradiation contributes to the RCS much more than does the rim diffraction; (2) at low frequency, the RCS from the circular waveguide terminated by a perfect electric conductor (PEC) can be reduced more than 13 dB down with a coating thickness less than 1% of the radius using the best lossy material available in a 6 radius-long cylinder; (3) at high frequency, a modal separation between the highly attenuated and the lowly attenuated modes is evident if the coating material is too lossy, however, a large RCS reduction can be achieved for a small incident angle with a thin layer of coating. It is found that the waveguide coated with a lossy magnetic material can be used as a substitute for a corrugated waveguide to produce a circularly polarized radiation yield.

Tribology of nitrided-coated steel-a review

NASA Astrophysics Data System (ADS)

Bhaskar, Santosh V.; Kudal, Hari N.

2017-01-01

Surface engineering such as surface treatment, coating, and surface modification are employed to increase surface hardness, minimize adhesion, and hence, to reduce friction and improve resistance to wear. To have optimal tribological performance of Physical Vapor Deposition (PVD) hard coating to the substrate materials, pretreatment of the substrate materials is always advisable to avoid plastic deformation of the substrate, which may result in eventual coating failure. The surface treatment results in hardening of the substrate and increase in load support effect. Many approaches aim to improve the adhesion of the coatings onto the substrate and nitriding is the one of the best suitable options for the same. In addition to tribological properties, nitriding leads to improved corrosion resistance. Often corrosion resistance is better than that obtainable with other surface engineering processes such as hard-chrome and nickel plating. Ability of this layer to withstand thermal stresses gives stability which extends the surface life of tools and other components exposed to heat. Most importantly, the nitrogen picked-up by the diffusion layer increases the rotating-bending fatigue strength in components. The present article reviews mainly the tribological advancement of different nitrided-coated steels based on the types of coatings, structure, and the tribo-testing parameters, in recent years.

Thermal certification tests of Orbiter Thermal Protection System tiles coated with KSC coating slurries

NASA Technical Reports Server (NTRS)

Milhoan, James D.; Pham, Vuong T.; Sherborne, William D.

1993-01-01

Thermal tests of Orbiter thermal protection system (TPS) tiles, which were coated with borosilicate glass slurries fabricated at Kennedy Space Center (KSC), were performed in the Radiant Heat Test Facility and the Atmospheric Reentry Materials & Structures Evaluation Facility at Johnson Space Center to verify tile coating integrity after exposure to multiple entry simulation cycles in both radiant and convective heating environments. Eight high temperature reusable surface insulation (HRSI) tiles and six low temperature reusable surface insulation (LRSI) tiles were subjected to 25 cycles of radiant heat at peaked surface temperatures of 2300 F and 1200 F, respectively. For the LRSI tiles, an additional cycle at peaked surface temperature of 2100 F was performed. There was no coating crack on any of the HRSI specimens. However, there were eight small coating cracks (less than 2 inches long) on two of the six LRSI tiles on the 26th cycle. There was practically no change on the surface reflectivity, physical dimensions, or weight of any of the test specimens. There was no observable thermal-chemical degradation of the coating either. For the convective heat test, eight HRSI tiles were tested for five cycles at a surface temperature of 2300 F. There was no thermal-induced coating crack on any of the test specimens, almost no change on the surface reflectivity, and no observable thermal-chemical degradation with an exception of minor slumping of the coating under painted TPS identification numbers. The tests demonstrated that KSC's TPS slurries and coating processes meet the Orbiter's thermal specification requirements.

Superhydrophobic ceramic coating: Fabrication by solution precursor plasma spray and investigation of wetting behavior.

PubMed

Xu, Pengyun; Coyle, Thomas W; Pershin, Larry; Mostaghimi, Javad

2018-08-01

Superhydrophobic surfaces are often created by fabricating suitable surface structures from low-surface-energy organic materials using processes that are not suitable for large-scale fabrication. Rare earth oxides (REO) exhibit hydrophobic behavior that is unusual among oxides. Solution precursor plasma spray (SPPS) deposition is a rapid, one-step process that can produce ceramic coatings with fine scale columnar structures. Manipulation of the structure of REO coatings through variation in deposition conditions may allow the wetting behavior to be controlled. Yb 2 O 3 coatings were fabricated via SPPS. Coating structure was investigated by scanning electron microscopy, digital optical microscopy, and x-ray diffraction. The static water contact angle and roll-off angle were measured, and the dynamic impact of water droplets on the coating surface recorded. Superhydrophobic behavior was observed; the best coating exhibited a water contact angle of ∼163°, a roll-off angle of ∼6°, and complete droplet rebound behavior. All coatings were crystalline Yb 2 O 3 , with a nano-scale roughness superimposed on a micron-scale columnar structure. The wetting behaviors of coatings deposited at different standoff distances were correlated with the coating microstructures and surface topographies. The self-cleaning, water flushing and water jetting tests were conducted and further demonstrated the excellent and durable hydrophobicity of the coatings. Copyright © 2018 Elsevier Inc. All rights reserved.

Bioinspired, roughness-induced, water and oil super-philic and super-phobic coatings prepared by adaptable layer-by-layer technique

PubMed Central

Brown, Philip S.; Bhushan, Bharat

2015-01-01

Coatings with specific surface wetting properties are of interest for anti-fouling, anti-fogging, anti-icing, self-cleaning, anti-smudge, and oil-water separation applications. Many previous bioinspired surfaces are of limited use due to a lack of mechanical durability. Here, a layer-by-layer technique is utilized to create coatings with four combinations of water and oil repellency and affinity. An adapted layer-by-layer approach is tailored to yield specific surface properties, resulting in a durable, functional coating. This technique provides necessary flexibility to improve substrate adhesion combined with desirable surface chemistry. Polyelectrolyte binder, SiO2 nanoparticles, and silane or fluorosurfactant layers are deposited, combining surface roughness and necessary chemistry to result in four different coatings: superhydrophilic/superoleophilic, superhydrophobic/superoleophilic, superhydrophobic/superoleophobic, and superhydrophilic/superoleophobic. The superoleophobic coatings display hexadecane contact angles >150° with tilt angles <5°, whilst the superhydrophobic coatings display water contact angles >160° with tilt angles <2°. One coating combines both oleophobic and hydrophobic properties, whilst others mix and match oil and water repellency and affinity. Coating durability was examined through the use of micro/macrowear experiments. These coatings display transparency acceptable for some applications. Fabrication via this novel combination of techniques results in durable, functional coatings displaying improved performance compared to existing work where either durability or functionality is compromised. PMID:26353971

Natural cellulose fiber as substrate for supercapacitor.

PubMed

Gui, Zhe; Zhu, Hongli; Gillette, Eleanor; Han, Xiaogang; Rubloff, Gary W; Hu, Liangbing; Lee, Sang Bok

2013-07-23

Cellulose fibers with porous structure and electrolyte absorption properties are considered to be a good potential substrate for the deposition of energy material for energy storage devices. Unlike traditional substrates, such as gold or stainless steel, paper prepared from cellulose fibers in this study not only functions as a substrate with large surface area but also acts as an interior electrolyte reservoir, where electrolyte can be absorbed much in the cellulose fibers and is ready to diffuse into an energy storage material. We demonstrated the value of this internal electrolyte reservoir by comparing a series of hierarchical hybrid supercapacitor electrodes based on homemade cellulose paper or polyester textile integrated with carbon nanotubes (CNTs) by simple solution dip and electrodeposited with MnO2. Atomic layer deposition of Al2O3 onto the fiber surface was used to limit electrolyte absorption into the fibers for comparison. Configurations designed with different numbers of ion diffusion pathways were compared to show that cellulose fibers in paper can act as a good interior electrolyte reservoir and provide an effective pathway for ion transport facilitation. Further optimization using an additional CNT coating resulted in an electrode of paper/CNTs/MnO2/CNTs, which has dual ion diffusion and electron transfer pathways and demonstrated superior supercapacitive performance. This paper highlights the merits of the mesoporous cellulose fibers as substrates for supercapacitor electrodes, in which the water-swelling effect of the cellulose fibers can absorb electrolyte, and the mesoporous internal structure of the fibers can provide channels for ions to diffuse to the electrochemical energy storage materials.

Compositional evidence regarding the origins of rims on Semarkona chondrules

USGS Publications Warehouse

Grossman, J.N.; Wasson, J.T.

1987-01-01

The compositions of the interiors and abraded surfaces of 7 chondrules from Semarkona (LL3.0) were measured by neutron activation analysis. For nonvolatile elements, the lithophile and siderophile element abundance patterns in the surfaces are generally similar to those in the corresponding interiors. Siderophile and chalcophile concentrations are much higher in the surfaces, whereas lithophile concentrations are similar in both fractions. Most of the similarities in lithophile patterns and some of the similarities in siderophile patterns between surfaces and interiors may reflect incomplete separation of the fractions in the laboratory, but for 3 or 4 chondrules the siderophile resemblance is inherent, implying that the surface and interior metal formed from a single precursor assemblage. Metal and sulfide-rich chondrule rims probably formed when droplets of these phases that migrated to the chondrule surface during melting were reheated and incorporated into matrix-like material that had accreted onto the surface. The moderately-volatile to volatile elements K, As and Zn tend to be enriched in the surfaces compared with other elements of similar mineral affinity; both enrichments and depletions are observed for other moderately volatile elements. A small fraction of chondrules experienced fractional evaporation while they were molten. ?? 1987.

Evaluation of Thermal Control Coatings for Flexible Ceramic Thermal Protection Systems

NASA Technical Reports Server (NTRS)

Kourtides, Demetrius; Carroll, Carol; Smith, Dane; Guzinski, Mike; Marschall, Jochen; Pallix, Joan; Ridge, Jerry; Tran, Duoc

1997-01-01

This report summarizes the evaluation and testing of high emissivity protective coatings applied to flexible insulations for the Reusable Launch Vehicle technology program. Ceramic coatings were evaluated for their thermal properties, durability, and potential for reuse. One of the major goals was to determine the mechanism by which these coated blanket surfaces become brittle and try to modify the coatings to reduce or eliminate embrittlement. Coatings were prepared from colloidal silica with a small percentage of either SiC or SiB6 as the emissivity agent. These coatings are referred to as gray C-9 and protective ceramic coating (PCC), respectively. The colloidal solutions were either brushed or sprayed onto advanced flexible reusable surface insulation blankets. The blankets were instrumented with thermocouples and exposed to reentry heating conditions in the Ames Aeroheating Arc Jet Facility. Post-test samples were then characterized through impact testing, emissivity measurements, chemical analysis, and observation of changes in surface morphology. The results show that both coatings performed well in arc jet tests with backface temperatures slightly lower for the PCC coating than with gray C-9. Impact testing showed that the least extensive surface destruction was experienced on blankets with lower areal density coatings.

Improvement of Interaction in a Composite Structure by Using a Sol-Gel Functional Coating on Carbon Fibers.

PubMed

Szczurek, Anna; Barcikowski, Michał; Leluk, Karol; Babiarczuk, Bartosz; Kaleta, Jerzy; Krzak, Justyna

2017-08-25

The modification of carbon fibers for improving adhesion between fibers and an epoxy resin in composite materials has become the focus of attention. In this work the carbon fiber coating process has been devised in a way preventing the stiffening and clumping of fibers. To improve interactions between coated fibers and a resin in composites, four types of silica coatings with different organic functional groups (3-aminopropyl-coating 1, 3-mercaptopropyl-coating 2, 2-(3,4-epoxycyclohexyl) ethyl-coating 3, methyl-coating 4) were obtained. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to distinguish the changes of a carbon fibers surface after coating deposition. The thickness of the obtained coatings, including the diversity of thickness, was determined by transmission electron microscopy (TEM). The increase in surface free energy (SFE) of modified fibers, including the distinction between the polar and dispersive parts, was examined by wettability measurements using a tensometric test. The developed coating preparation process allowed to cover fibers separately with nanoscale silica layers, which changed their morphology. The introduction of organic functional groups resulted in surface free energy changes, especially an increase in specific polar surface energy components.

Improvement of Interaction in a Composite Structure by Using a Sol-Gel Functional Coating on Carbon Fibers

PubMed Central

Barcikowski, Michał; Leluk, Karol; Babiarczuk, Bartosz; Kaleta, Jerzy

2017-01-01

The modification of carbon fibers for improving adhesion between fibers and an epoxy resin in composite materials has become the focus of attention. In this work the carbon fiber coating process has been devised in a way preventing the stiffening and clumping of fibers. To improve interactions between coated fibers and a resin in composites, four types of silica coatings with different organic functional groups (3-aminopropyl–coating 1, 3-mercaptopropyl–coating 2, 2-(3,4-epoxycyclohexyl) ethyl–coating 3, methyl–coating 4) were obtained. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to distinguish the changes of a carbon fibers surface after coating deposition. The thickness of the obtained coatings, including the diversity of thickness, was determined by transmission electron microscopy (TEM). The increase in surface free energy (SFE) of modified fibers, including the distinction between the polar and dispersive parts, was examined by wettability measurements using a tensometric test. The developed coating preparation process allowed to cover fibers separately with nanoscale silica layers, which changed their morphology. The introduction of organic functional groups resulted in surface free energy changes, especially an increase in specific polar surface energy components. PMID:28841187

Fabrication of Porous Ag/TiO2/Au Coatings with Excellent Multipactor Suppression

PubMed Central

Wu, Duoduo; Ma, Jianzhong; Bao, Yan; Cui, Wanzhao; Hu, Tiancun; Yang, Jing; Bai, Yuanrui

2017-01-01

Porous Ag/TiO2/Au coatings with excellent multipactor suppression were prepared by fabrication of porous Ag surface through two-step wet chemical etching, synthesis of TiO2 coatings by electroless-plating-like solution deposition and deposition of Au coatings via electroless plating. Porous structure of Ag surface, TiO2 coatings on porous Ag surface and Au coatings on porous Ag/TiO2 surface were verified by field-emission scanning electron microscopy, the composition and crystal type of TiO2 coatings was characterized by X-ray photoelectron spectroscopy and X-ray diffraction. Secondary electron yield (SEY) measurement was used to monitor the SEY coefficient of the porous Ag coatings and Ag/TiO2/Au coatings. The as-obtained porous Ag coatings were proved exhibiting low SEY below 1.2, and the process was highly reproducible. In addition, the porous Ag/TiO2/Au coatings showed excellent multipactor suppression with the SEY 1.23 and good environmental stability. It is worth mentioning that the whole preparation process is simple and feasible, which would provide a promising application in RF devices. PMID:28281546

Effects of hydroxyapatite/Zr and bioglass/Zr coatings on morphology and corrosion behaviour of Rex-734 alloy.

PubMed

Say, Y; Aksakal, B

2016-06-01

To improve corrosion resistance of metallic implant surfaces, Rex-734 alloy was coated with two different bio-ceramics; single-Hydroxyapatite (HA), double-HA/Zirconia(Zr) and double-Bioglass (BG)/Zr by using sol-gel method. Porous surface morphologies at low crack density were obtained after coating and sintering processes. Corrosion characteristics of coatings were determined by Open circuit potential and Potentiodynamic polarization measurements during corrosion tests. Hardness and adhesion strength of coating layers were measured and their surface morphologies before and after corrosion were characterized by scanning electron microscope (SEM), XRD and EDX. Through the SEM analysis, it was observed that corrosion caused degradation and sphere-like formations appeared with dimples on the coated surfaces. The coated substrates that exhibit high crack density, the corrosion was more effective by disturbing and transmitting through the coating layer, produced CrO3 and Cr3O8 oxide formation. It was found that the addition of Zr provided an increase in adhesion strength and corrosion resistance of the coatings. However, BG/Zr coatings had lower adhesion strength than the HA/Zr coatings, but showed higher corrosion resistance.

Assessment of Runoff Toxicity from Coated Surfaces

EPA Science Inventory

Presented in this paper are results from a field and laboratory study of the potential runoff toxicity from coated surfaces. The study results qualified and quantified the types and concentrations of pollutants in runoff from surfaces sealed with a variety of products. Coatings a...

Porous polymer coatings on metal microneedles for enhanced drug delivery

NASA Astrophysics Data System (ADS)

Ullah, Asad; Kim, Chul Min; Kim, Gyu Man

2018-04-01

We present a simple method to coat microneedles (MNs) uniformly with a porous polymer (PLGA) that can deliver drugs at high rates. Stainless steel (SS) MNs of high mechanical strength were coated with a thin porous polymer layer to enhance their delivery rates. Additionally, to improve the interfacial adhesion between the polymer and MNs, the MN surface was modified by plasma treatment followed by dip coating with polyethyleneimine, a polymer with repeating amine units. The average failure load (the minimum force sufficient for detaching the polymer layer from the surface of SS) recorded for the modified surface coating was 25 N, whereas it was 2.2 N for the non-modified surface. Calcein dye was successfully delivered into porcine skin to a depth of 750 µm by the porous polymer-coated MNs, demonstrating that the developed MNs can pierce skin easily without deformation of MNs; additional skin penetration tests confirmed this finding. For visual comparison, rhodamine B dye was delivered using porous-coated and non-coated MNs in gelatin gel which showed that delivery with porous-coated MNs penetrate deeper when compared with non-coated MNs. Finally, lidocaine and rhodamine B dye were delivered in phosphate-buffered saline (PBS) medium by porous polymer-coated and non-coated MNs. For rhodamine B, drug delivery with the porous-coated MNs was five times higher than that with the non-coated MNs, whereas 25 times more lidocaine was delivered by the porous-coated MNs compared with the non-coated MNs.

Design Considerations for an OPAC Workstation: An Introduction to Specifications and a Model Configuration.

ERIC Educational Resources Information Center

Martin, Ron G.

1989-01-01

Describes guidelines for an online public access catalog (OPAC) workstation that will support the terminal, printer, and other peripherals. Workstation dimensions, lighting, wire management, printer and paper, acoustical treatment, seating, storage for books and coats, wastebasket, and interior decoration are addressed. Flexibility and simplicity…

40 CFR 63.4081 - Am I subject to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... source or group of stationary sources located within a contiguous area and under common control that... sources located within a contiguous area and under common control that is not a major source. (b) The..., spray guns or dip tanks; (4) Application of porcelain enamel, powder coating, and asphalt interior...

40 CFR 63.4081 - Am I subject to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... source or group of stationary sources located within a contiguous area and under common control that... sources located within a contiguous area and under common control that is not a major source. (b) The..., spray guns or dip tanks; (4) Application of porcelain enamel, powder coating, and asphalt interior...

40 CFR 63.4081 - Am I subject to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... source or group of stationary sources located within a contiguous area and under common control that... sources located within a contiguous area and under common control that is not a major source. (b) The..., spray guns or dip tanks; (4) Application of porcelain enamel, powder coating, and asphalt interior...

Synergistic Effects of a Calcium Phosphate/Fibronectin Coating on the Adhesion of Periodontal Ligament Stem Cells Onto Decellularized Dental Root Surfaces.

PubMed

Lee, Jung-Seok; Kim, Hyun-Suk; Park, So-Yon; Kim, Tae-Wan; Jung, Jae-Suk; Lee, Jong-Bin; Kim, Chang-Sung

2015-01-01

This study aimed to enhance the attachment of periodontal ligament stem cells (PDLSCs) onto the decellularized dental root surface using surface coating with fibronectin and/or calcium phosphate (CaP) and to evaluate the activity of PDLSCs attached to a coated dental root surface following tooth replantation. PDLSCs were isolated from five dogs, and the other dental roots were used as a scaffold for carrying PDLSCs and then assigned to one of four groups according to whether their surface was coated with CaP, fibronectin, CaP/fibronectin, or left uncoated (control). Fibronectin increased the adhesion of PDLSCs onto dental root surfaces compared to both the control and CaP-coated groups, and simultaneous surface coating with CaP and fibronectin significantly accelerated and increased PDLSC adhesion compared to the fibronectin-only group. On in vivo tooth replantation, functionally oriented periodontal new attachment was observed on the CaP/fibronectin-coated dental roots to which autologous PDLSCs had adhered, while in the control condition, dental root replantation was associated only with root resorption and ankylosis along the entire root length. CaP and fibronectin synergistically enhanced the attachment of PDLSCs onto dental root surfaces, and autologous PDLSCs could produce de novo periodontal new attachment in an experimental in vivo model.

The Otto Aufranc Award: enhanced biocompatibility of stainless steel implants by titanium coating and microarc oxidation.

PubMed

Lim, Young Wook; Kwon, Soon Yong; Sun, Doo Hoon; Kim, Yong Sik

2011-02-01

Stainless steel is one of the most widely used biomaterials for internal fixation devices, but is not used in cementless arthroplasty implants because a stable oxide layer essential for biocompatibility cannot be formed on the surface. We applied a Ti electron beam coating, to form oxide layer on the stainless steel surface. To form a thicker oxide layer, we used a microarc oxidation process on the surface of Ti coated stainless steel. Modification of the surface using Ti electron beam coating and microarc oxidation could improve the ability of stainless steel implants to osseointegrate. The ability of cells to adhere to grit-blasted, titanium-coated, microarc-oxidated stainless steel in vitro was compared with that of two different types of surface modifications, machined and titanium-coated, and microarc-oxidated. We performed energy-dispersive x-ray spectroscopy and scanning electron microscopy investigations to assess the chemical composition and structure of the stainless steel surfaces and cell morphology. The biologic responses of an osteoblastlike cell line (SaOS-2) were examined by measuring proliferation (cell proliferation assay), differentiation (alkaline phosphatase activity), and attraction ability (cell migration assay). Cell proliferation, alkaline phosphatase activity, migration, and adhesion were increased in the grit-blasted, titanium-coated, microarc-oxidated group compared to the two other groups. Osteoblastlike cells on the grit-blasted, titanium-coated, microarc-oxidated surface were strongly adhered, and proliferated well compared to those on the other surfaces. The surface modifications we used (grit blasting, titanium coating, microarc oxidation) enhanced the biocompatibility (proliferation and migration of osteoblastlike cells) of stainless steel. This process is not unique to stainless steel; it can be applied to many metals to improve their biocompatibility, thus allowing a broad range of materials to be used for cementless implants.

Processing and Characterization of Nanoparticle Coatings for Quartz Crystal Microbalance Measurements

PubMed Central

Torrey, Jessica D.; Kirschling, Teresa L.; Greenlee, Lauren F.

2015-01-01

The quartz-crystal microbalance is a sensitive and versatile tool for measuring adsorption of a variety of compounds (e.g. small molecules, polymers, biomolecules, nanoparticles and cells) to surfaces. While the technique has traditionally been used for measuring adsorption to flat surfaces and thin ridged films, it can also be extended to study adsorption to nanoparticle surfaces when the nanoparticles are fixed to the crystal surface. The sensitivity and accuracy of the measurement depend on the users’ ability to reproducibly prepare a thin uniform nanoparticle coating. This study evaluated four coating techniques, including spin coating, spray coating, drop casting, and electrophoretic deposition, for two unique particle chemistries [nanoscale zero valent iron (nZVI) and titanium dioxide (TiO2)] to produce uniform and reproducible nanoparticle coatings for real-time quartz-crystal microbalance measurements. Uniform TiO2 coatings were produced from a 50 mg/mL methanol suspension via spin coating. Nanoscale zero-valent iron was best applied by spray coating a low concentration 1.0 mg/mL suspended in methanol. The application of multiple coatings, rather than an increase in the suspension concentration, was the best method to increase the mass of nanoparticles on the crystal surface while maintaining coating uniformity. An upper mass threshold was determined to be approximately 96 µg/cm2; above this mass, coatings no longer maintained their uniform rigid characteristic, and a low signal to noise ratio resulted in loss of measurable signal from crystal resonances above the fundamental. PMID:26958434

Aesthetic coatings for concrete bridge components

NASA Astrophysics Data System (ADS)

Kriha, Brent R.

This thesis evaluated the durability and aesthetic performance of coating systems for utilization in concrete bridge applications. The principle objectives of this thesis were: 1) Identify aesthetic coating systems appropriate for concrete bridge applications; 2) Evaluate the performance of the selected systems through a laboratory testing regimen; 3) Develop guidelines for coating selection, surface preparation, and application. A series of site visits to various bridges throughout the State of Wisconsin provided insight into the performance of common coating systems and allowed problematic structural details to be identified. To aid in the selection of appropriate coating systems, questionnaires were distributed to coating manufacturers, bridge contractors, and various DOT offices to identify high performing coating systems and best practices for surface preparation and application. These efforts supplemented a literature review investigating recent publications related to formulation, selection, surface preparation, application, and performance evaluation of coating materials.

Tribology and Microstructure of PS212 with a Cr2O3 Seal Coat

NASA Technical Reports Server (NTRS)

Sliney, Harold E.; Benoy, Patricia A.; Korenyi-Both, Andras; Dellacorte, Christopher

1994-01-01

PS212 is a plasma sprayed metal bonding chrome carbide coating with solid lubricant additives which has lubricating properties at temperatures up to about 900 deg C. The coating is diamond ground to achieve an acceptable tribological surface. But, as with many plasma spray coatings, PS212 is not fully-dense. In this study, a chromium oxide base seal coating is used in an attempt to seal any porosity that is open to the surface of the PS212 coating, and to study the effect of the sealant on the tribological properties of PS212. The results indicate that the seal coating reduces friction and wear when it is applied and then diamond ground leaving a thin layer of seal coating which fills in the surface pits of the PS212 coating.

Superconductive wire

DOEpatents

Korzekwa, David A.; Bingert, John F.; Peterson, Dean E.; Sheinberg, Haskell

1995-01-01

A superconductive article is made by inserting a rigid mandrel into an internal cavity of a first metallic tube, said tube having an interior surface and an exterior surface, said interior surface defining the interior cavity, forming a layer of a superconductive material or superconductive precursor upon the exterior surface of said first metallic tube, machining the layer of superconductive material or superconductive precursor to a predetermined diameter to form an intermediate article configured for insertion into a second metallic tube having an interior diameter corresponding to the predetermined diameter, inserting the machined intermediate article into a second metallic tube having an internal diameter corresponding to the predetermined diameter of the intermediate article to form a composite intermediate article, reducing or ironing the composite intermediate article to a predetermined cross-sectional diameter, and sintering the reduced or ironed composite intermediate article at temperatures and for time sufficient for the superconductive material or superconductive precursor to exhibit superconductivity.

Superconductive wire

DOEpatents

Korzekwa, D.A.; Bingert, J.F.; Peterson, D.E.; Sheinberg, H.

1995-07-18

A superconductive article is made by inserting a rigid mandrel into an internal cavity of a first metallic tube, said tube having an interior surface and an exterior surface, said interior surface defining the interior cavity, forming a layer of a superconductive material or superconductive precursor upon the exterior surface of said first metallic tube, machining the layer of superconductive material or superconductive precursor to a predetermined diameter to form an intermediate article configured for insertion into a second metallic tube having an interior diameter corresponding to the predetermined diameter, inserting the machined intermediate article into a second metallic tube having an internal diameter corresponding to the predetermined diameter of the intermediate article to form a composite intermediate article, reducing or ironing the composite intermediate article to a predetermined cross-sectional diameter, and sintering the reduced or ironed composite intermediate article at temperatures and for time sufficient for the superconductive material or superconductive precursor to exhibit superconductivity. 2 figs.

Inspection of the interior surface of cylindrical vessels using optic fiber shearography

NASA Astrophysics Data System (ADS)

Liu, Bin; Wei, Quan; Tu, Jun; Arola, Dwayne D.; Zhang, Dongsheng

2017-09-01

In this study, a shearography system integrated with a coherent fiber-optic illumination and a fiber-optic imaging bundle is presented to inspect the quality of the interior surface of a cylindrical vessel for safety purposes. The specific optical arrangement is designed for the inspection of a certain area at a small working distance. The optical arrangement of the system was assembled and an aluminum honeycomb sample was evaluated to demonstrate the capability of the system. The important relationship between the image quality and the working distance, as well as the field of view, is discussed. The system has been applied for the inspection of the interior surface of a cylindrical vessel. The experimental results suggest that the shearography system integrated with optical and image fibers can effectively minimize the size of the inspection device and be capable of evaluating the interior surface of cylindrical structures.

Dynamic recrystallization in friction surfaced austenitic stainless steel coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puli, Ramesh, E-mail: rameshpuli2000@gmail.com; Janaki Ram, G.D.

2012-12-15

Friction surfacing involves complex thermo-mechanical phenomena. In this study, the nature of dynamic recrystallization in friction surfaced austenitic stainless steel AISI 316L coatings was investigated using electron backscattered diffraction and transmission electron microscopy. The results show that the alloy 316L undergoes discontinuous dynamic recrystallization under conditions of moderate Zener-Hollomon parameter during friction surfacing. - Highlights: Black-Right-Pointing-Pointer Dynamic recrystallization in alloy 316L friction surfaced coatings is examined. Black-Right-Pointing-Pointer Friction surfacing leads to discontinuous dynamic recrystallization in alloy 316L. Black-Right-Pointing-Pointer Strain rates in friction surfacing exceed 400 s{sup -1}. Black-Right-Pointing-Pointer Estimated grain size matches well with experimental observations in 316L coatings.

Reduced chemical warfare agent sorption in polyurethane-painted surfaces via plasma-enhanced chemical vapor deposition of perfluoroalkanes.

PubMed

Gordon, Wesley O; Peterson, Gregory W; Durke, Erin M

2015-04-01

Perfluoralkalation via plasma chemical vapor deposition has been used to improve hydrophobicity of surfaces. We have investigated this technique to improve the resistance of commercial polyurethane coatings to chemicals, such as chemical warfare agents. The reported results indicate the surface treatment minimizes the spread of agent droplets and the sorption of agent into the coating. The improvement in resistance is likely due to reduction of the coating's surface free energy via fluorine incorporation, but may also have contributing effects from surface morphology changes. The data indicates that plasma-based surface modifications may have utility in improving chemical resistance of commercial coatings.

Monte Carlo simulations of ABC stacked kagome lattice films

NASA Astrophysics Data System (ADS)

Yerzhakov, H. V.; Plumer, M. L.; Whitehead, J. P.

2016-05-01

Properties of films of geometrically frustrated ABC stacked antiferromagnetic kagome layers are examined using Metropolis Monte Carlo simulations. The impact of having an easy-axis anisotropy on the surface layers and cubic anisotropy in the interior layers is explored. The spin structure at the surface is shown to be different from that of the bulk 3D fcc system, where surface axial anisotropy tends to align spins along the surface [1 1 1] normal axis. This alignment then propagates only weakly to the interior layers through exchange coupling. Results are shown for the specific heat, magnetization and sub-lattice order parameters for both surface and interior spins in three and six layer films as a function of increasing axial surface anisotropy. Relevance to the exchange bias phenomenon in IrMn3 films is discussed.

Spray shadowing for stress relief and mechanical locking in thick protective coatings

DOEpatents

Hollis, Kendall [Los Alamos, NM; Bartram, Brian [Los Alamos, NM

2007-05-22

A method for applying a protective coating on an article, comprising the following steps: selecting an article with a surface for applying a coating thickness; creating undercut grooves on the article, where the grooves depend beneath the surface to a bottom portion with the grooves having an upper width on the surface and a lower width on the bottom portion connected by side walls, where at least one of the side walls connects the upper width and the lower width to form an undercut angle with the surface less than 90.degree.; and, applying the protective coating onto the article to fill the undercut grooves and cover the surface, thereby forming weak paths within the protective coating.

Antimicrobial peptide coatings for hydroxyapatite: electrostatic and covalent attachment of antimicrobial peptides to surfaces

PubMed Central

Townsend, Leigh; Williams, Richard L.; Anuforom, Olachi; Berwick, Matthew R.; Halstead, Fenella; Hughes, Erik; Stamboulis, Artemis; Oppenheim, Beryl; Gough, Julie; Grover, Liam; Scott, Robert A. H.; Webber, Mark; Peacock, Anna F. A.; Belli, Antonio; Logan, Ann

2017-01-01

The interface between implanted devices and their host tissue is complex and is often optimized for maximal integration and cell adhesion. However, this also gives a surface suitable for bacterial colonization. We have developed a novel method of modifying the surface at the material–tissue interface with an antimicrobial peptide (AMP) coating to allow cell attachment while inhibiting bacterial colonization. The technology reported here is a dual AMP coating. The dual coating consists of AMPs covalently bonded to the hydroxyapatite surface, followed by deposition of electrostatically bound AMPs. The dual approach gives an efficacious coating which is stable for over 12 months and can prevent colonization of the surface by both Gram-positive and Gram-negative bacteria. PMID:28077764

Temperature measurement involving nanostructured thermal barrier coating using a multiwavelength pyrometer

NASA Technical Reports Server (NTRS)

Ng, Daniel

1996-01-01

It has been reported that erroneous results were obtained when a conventional pyrometer was used to measure the surface temperature of turbine engine components. Temperatures discrepancies were observed in components which were identical, except that one had its measured surface covered by a nanostructured thermal barrier coating (TBC) whereas the other component's surface was not so coated. These components were placed in an identical environment, receiving identical heat fluxes. A pyrometer measured the TBC covered surface hundreds degrees lower. These coatings were about 25 (mu)m thick, consisting of hundreds of layers of finer structures. The TBC's had very low thermal conductivity, heat flux calculations indicated that the temperatures of the coated surface should exhibit much higher temperature than the uncoated surface. Because these coatings were transparent to radiation from the visible to the infrared region, the temperatures measured by the pyrometer should be the temperature of the covered surface. Turbo components' performance and service life depend critically on the temperatures that it would experience; it is therefore important to know accurately and confidently the real surface temperature. Out of these concerns, an investigation into the measurement of nanostructured material surface temperature was carried out.

Effect of coating on properties of esthetic orthodontic nickel-titanium wires.

PubMed

Iijima, Masahiro; Muguruma, Takeshi; Brantley, William; Choe, Han-Cheol; Nakagaki, Susumu; Alapati, Satish B; Mizoguchi, Itaru

2012-03-01

To determine the effect of coating on the properties of two esthetic orthodontic nickel-titanium wires. Woowa (polymer coating; Dany Harvest) and BioForce High Aesthetic Archwire (metal coating; Dentsply GAC) with cross-section dimensions of 0.016 × 0.022 inches were selected. Noncoated posterior regions of the anterior-coated Woowa and uncoated Sentalloy were used for comparison. Nominal coating compositions were determined by x-ray fluorescence (JSX-3200, JOEL). Cross-sectioned and external surfaces were observed with a scanning electron microscope (SEM; SSX-550, Shimadzu) and an atomic force microscope (SPM-9500J2, Shimadzu). A three-point bending test (12-mm span) was carried out using a universal testing machine (EZ Test, Shimadzu). Hardness and elastic modulus of external and cross-sectioned surfaces were obtained by nanoindentation (ENT-1100a, Elionix; n  =  10). Coatings on Woowa and BioForce High Aesthetic Archwire contained 41% silver and 14% gold, respectively. The coating thickness on Woowa was approximately 10 µm, and the coating thickness on BioForce High Aesthetic Archwire was much smaller. The surfaces of both coated wires were rougher than the noncoated wires. Woowa showed a higher mean unloading force than the noncoated Woowa, although BioForce High Aesthetic Archwire showed a lower mean unloading force than Sentalloy. While cross-sectional surfaces of all wires had similar hardness and elastic modulus, values for the external surface of Woowa were smaller than for the other wires. The coating processes for Woowa and BioForce High Aesthetic Archwire influence bending behavior and surface morphology.

Coating Reduces Ice Adhesion

NASA Technical Reports Server (NTRS)

Smith, Trent; Prince, Michael; DwWeese, Charles; Curtis, Leslie

2008-01-01

The Shuttle Ice Liberation Coating (SILC) has been developed to reduce the adhesion of ice to surfaces on the space shuttle. SILC, when coated on a surface (foam, metal, epoxy primer, polymer surfaces), will reduce the adhesion of ice by as much as 90 percent as compared to the corresponding uncoated surface. This innovation is a durable coating that can withstand several cycles of ice growth and removal without loss of anti-adhesion properties. SILC is made of a binder composed of varying weight percents of siloxane(s), ethyl alcohol, ethyl sulfate, isopropyl alcohol, and of fine-particle polytetrafluoroethylene (PTFE). The combination of these components produces a coating with significantly improved weathering characteristics over the siloxane system alone. In some cases, the coating will delay ice formation and can reduce the amount of ice formed. SILC is not an ice prevention coating, but the very high water contact angle (greater than 140 ) causes water to readily run off the surface. This coating was designed for use at temperatures near -170 F (-112 C). Ice adhesion tests performed at temperatures from -170 to 20 F (-112 to -7 C) show that SILC is a very effective ice release coating. SILC can be left as applied (opaque) or buffed off until the surface appears clear. Energy dispersive spectroscopy (EDS) and x-ray photoelectron spectroscopy (XPS) data show that the coating is still present after buffing to transparency. This means SILC can be used to prevent ice adhesion even when coating windows or other objects, or items that require transmission of optical light. Car windshields are kept cleaner and SILC effectively mitigates rain and snow under driving conditions.

Selected fretting-wear-resistant coatings for titanium - 6-percent-aluminum - 4-percent-vanadium alloy

NASA Technical Reports Server (NTRS)

Bill, R. C.

1976-01-01

A titanium - 6-percent-aluminum - 4-percent-vanadium alloy (Ti-6Al-4V) was subjected to fretting-wear exposures against uncoated Ti-6Al-4V as a baseline and against various coatings and surface treatments applied to Ti-6Al-4V. The coatings evaluated included plasma-sprayed tungsten carbide with 12 percent cobalt, aluminum oxide with 13 percent titanium oxide, chromium oxide, and aluminum bronze with 10 percent aromatic polyester; polymer-bonded polyimide, polyimide with graphite fluoride, polyimide with molybdenum disulfide (MoS2), and methyl phenyl silicone bonded MoS2, preoxidation surface treatment, a nitride surface treatment, and a sputtered MoS2 coating. Results of wear measurements on both the coated and uncoated surfaces after 300,000 fretting cycles indicated that the polyimide coating was the most wear resistant and caused the least wear to the uncoated mating surface.

Large-scale, thick, self-assembled, nacre-mimetic brick-walls as fire barrier coatings on textiles

NASA Astrophysics Data System (ADS)

Das, Paramita; Thomas, Helga; Moeller, Martin; Walther, Andreas

2017-01-01

Highly loaded polymer/clay nanocomposites with layered structures are emerging as robust fire retardant surface coatings. However, time-intensive sequential deposition processes, e.g. layer-by-layer strategies, hinders obtaining large coating thicknesses and complicates an implementation into existing technologies. Here, we demonstrate a single-step, water-borne approach to prepare thick, self-assembling, hybrid fire barrier coatings of sodium carboxymethyl cellulose (CMC)/montmorillonite (MTM) with well-defined, bioinspired brick-wall nanostructure, and showcase their application on textile. The coating thickness on the textile is tailored using different concentrations of CMC/MTM (1-5 wt%) in the coating bath. While lower concentrations impart conformal coatings of fibers, thicker continuous coatings are obtained on the textile surface from highest concentration. Comprehensive fire barrier and fire retardancy tests elucidate the increasing fire barrier and retardancy properties with increasing coating thickness. The materials are free of halogen and heavy metal atoms, and are sourced from sustainable and partly even renewable building blocks. We further introduce an amphiphobic surface modification on the coating to impart oil and water repellency, as well as self-cleaning features. Hence, our study presents a generic, environmentally friendly, scalable, and one-pot coating approach that can be introduced into existing technologies to prepare bioinspired, thick, fire barrier nanocomposite coatings on diverse surfaces.

EVALUATION OF TOXICS IN RUNOFF FROM COATED SURFACES

EPA Science Inventory

Presented in this paper are results from a field and laboratory study of the potential runoff toxicity from coated surfaces. The study results qualified and quantified the types and concentrations of pollutants in runoff from surfaces sealed with a variety of products. Coatings a...

Surface Coating of Plastic Parts for Business Machines (Industrial Surface Coating): New Source Performance Standards (NSPS)

EPA Pesticide Factsheets

Learn more about the new source performance standards (NSPS) for surface coating of plastic parts for business machines by reading the rule summary and history and finding the code of federal regulations as well as related rules.

Ion-plasma protective coatings for gas-turbine engine blades

NASA Astrophysics Data System (ADS)

Kablov, E. N.; Muboyadzhyan, S. A.; Budinovskii, S. A.; Lutsenko, A. N.

2007-10-01

Evaporated, diffusion, and evaporation—diffusion protective and hardening multicomponent ionplasma coatings for turbine and compressor blades and other gas-turbine engine parts are considered. The processes of ion surface treatment (ion etching and ion saturation of a surface in the metallic plasma of a vacuum arc) and commercial equipment for the deposition of coatings and ion surface treatment are analyzed. The specific features of the ion-plasma coatings deposited from the metallic plasma of a vacuum arc are described, and the effect of the ion energy on the phase composition of the coatings and the processes occurring in the surface layer of an article to be treated are discussed. Some properties of ion-plasma coatings designed for various purposes are presented. The ion surface saturation of articles made from structural materials is shown to change the structural and phase states of their surfaces and, correspondingly, the related properties of these materials (i.e., their heat resistance, corrosion resistance, fatigue strength, and so on).

Cellulose nanomaterials emulsion coatings for controlling physiological activity, modifying surface morphology, and enhancing storability of postharvest bananas (Musa acuminate).

PubMed

Deng, Zilong; Jung, Jooyeoun; Simonsen, John; Zhao, Yanyun

2017-10-01

Cellulose nanomaterials (CNs)-incorporated emulsion coatings with improved moisture barrier, wettability and surface adhesion onto fruit surfaces were developed for controlling postharvest physiological activity and enhancing storability of bananas during ambient storage. Cellulose nanofiber (CNF)-based emulsion coating (CNFC: 0.3% CNF/1% oleic acid/1% sucrose ester fatty acid (w/w wet base)) had low contact angle, high spread coefficient onto banana surfaces, and lower surface tension (ST, 25.4mN/m) than the critical ST (35.2mN/m) of banana peels, and exhibited good wettability onto banana surfaces. CNFC coating delayed the ethylene biosynthesis pathway and reduced ethylene and CO 2 production, thus delaying fruit ripening. As the result, CNFC coating minimized chlorophyll degradation, weight loss, and firmness of bananas while ensuring the properly fruit ripening during 10d of ambient storage. This study demonstrated the effectiveness of CNF based emulsion coatings for improving the storability of postharvest bananas. Copyright © 2017 Elsevier Ltd. All rights reserved.

Electrically atomised formulations of timolol maleate for direct and on-demand ocular lens coatings.

PubMed

Mehta, Prina; Al-Kinani, Ali A; Haj-Ahmad, Rita; Arshad, Muhammad Sohail; Chang, Ming-Wei; Alany, Raid G; Ahmad, Zeeshan

2017-10-01

Advances in nanotechnology have enabled solutions for challenging drug delivery targets. While the eye presents numerous emerging opportunities for delivery, analysis and sensing; issues persist for conventional applications. This includes liquid phase formulation localisation on the ocular surface once administered as formulated eye-drops; with the vast majority of dosage (>90%) escaping from the administered site due to tear production and various drainage mechanisms. The work presented here demonstrates a single needle electrohydrodynamic (EHD) engineering process to nano-coat (as an on demand and controllable fiber depositing method) the surface of multiple contact lenses rendering formulations to be stationary on the lens and at the bio-interface. The coating process was operational based on ejected droplet charge and glaucoma drug timolol maleate (TM) was used to demonstrate surface coating optimisation, bio-surface permeation properties (flux, using a bovine model) and various kinetic models thereafter. Polymers PVP, PNIPAM and PVP:PNIPAM (50:50%w/w) were used to encapsulate the active. Nano-fibrous and particulate samples were characterised using SEM, FTIR, DSC and TGA to confirm structural and thermal stability of surface coated formulations. More than 52% of nano-structured coatings (for all formulations) were <200nm in diameter. In vitro studies show coatings to exhibit biphasic release profiles; an initial burst release followed by sustained release; with TM-loaded PNIPAM coating releasing most drug after 24h (89.8%). Kinetic modelling (Higuchi, Korsmeyer-Peppas) was indicative of quasi-Fickian diffusion whilst biological evaluation demonstrates adequate ocular tolerability. Results from permeation studies indicate coated lenses are ideal to reduce dosing regimen, which in turn will reduce systemic drug absorption. Florescent microscopy demonstrated probe and probe embedded coating behaviour from lens surface in vitro. The multiple lens surface coating method demonstrates sustained drug release yielding promising results; suggesting both novel device and method to enhance drug activity at the eyes surface which will reduce formulation drainage. Crown Copyright © 2017. Published by Elsevier B.V. All rights reserved.

Effects of piston surface treatments on performance and emissions of a methanol-fueled, direct injection, stratified charge engine

NASA Astrophysics Data System (ADS)

West, B.; Green, J. B.

1994-07-01

The purpose of this study was to investigate the effects of thermal barrier coatings and/or surface treatments on the performance and emissions of a methanol-fueled, direct-injection, stratified-charge (DISC) engine. A Ricardo Hydra Mark III engine was used for this work and in previous experiments at Oak Ridge National Laboratory (ORNL). The primary focus of the study was to examine the effects of various piston insert surface treatments on hydrocarbon (HC) and oxides of nitrogen (NO(x)) emissions. Previous studies have shown that engines of this class have a tendency to perform poorly at low loads and have high unburned fuel emissions. A blank aluminum piston was modified to employ removable piston bowl inserts. Four different inserts were tested in the experiment: aluminum, stainless steel with a 1.27-mm (0.050-in.) air gap (to act as a thermal barrier), and two stainless steel/air-gap inserts with coatings. Two stainless steel inserts were dimensionally modified to account for the coating thickness (1.27-mm) and coated identically with partially stabilized zirconia (PSZ). One of the coated inserts then had an additional seal-coat applied. The coated inserts were otherwise identical to the stainless steel/air-gap insert (i.e., they employed the same 1.27-mm air gap). Thermal barrier coatings were employed in an attempt to increase combustion chamber surface temperatures, thereby reducing wall quenching and promoting more complete combustion of the fuel in the quench zone. The seal-coat was applied to the zirconia to reduce the surface porosity; previous research suggested that despite the possibly higher surface temperatures obtainable with a ceramic coating, the high surface area of a plasma-sprayed coating may actually allow fuel to adhere to the surface and increase the unburned fuel emissions and fuel consumption.

Quantitation of Surface Coating on Nanoparticles Using Thermogravimetric Analysis.

PubMed

Dongargaonkar, Alpana A; Clogston, Jeffrey D

2018-01-01

Nanoparticles are critical components in nanomedicine and nanotherapeutic applications. Some nanoparticles, such as metallic nanoparticles, consist of a surface coating or surface modification to aid in its dispersion and stability. This surface coating may affect the behavior of nanoparticles in a biological environment, thus it is important to measure. Thermogravimetric analysis (TGA) can be used to determine the amount of coating on the surface of the nanoparticle. TGA experiments run under inert atmosphere can also be used to determine residual metal content present in the sample. In this chapter, the TGA technique and experimental method are described.

Mechanical Properties of Degraded PMR-15 Resin

NASA Technical Reports Server (NTRS)

Tsuji, Luis C.; McManus, Hugh L.; Bowles, Kenneth J.

1998-01-01

Thermo-oxidative aging produces a non-uniform degradation state in PMR-15 resin. A surface layer, usually attributed to oxidative degradation, forms. This surface layer has different properties from the inner material. A set of material tests was designed to separate the properties of the oxidized surface layer from the properties of interior material. Test specimens were aged at 316 C in either air or nitrogen, for durations of up to 800 hours. The thickness of the oxidized surface layer in air aged specimens, and the shrinkage and Coefficient of Thermal Expansion (CTE) of nitrogen aged specimens were measured directly. Four-point-bend tests were performed to determine modulus of both the oxidized surface layer and the interior material. Bimaterial strip specimens consisting of oxidized surface material and unoxidized interior material were constructed and used to determine surface layer shrinkage and CTE. Results confirm that the surface layer and core materials have substantially different properties.

Gear Performance Improved by Coating

NASA Technical Reports Server (NTRS)

Krantz, Timothy L.

2004-01-01

Gears, bearings, and other mechanical elements transmit loads through contacting surfaces. Even if properly designed, manufactured, installed, and maintained, gears and bearings will eventually fail because of the fatigue of the working surfaces. Economical means for extending the fatigue lives of gears and bearings are highly desired, and coatings offer the opportunity to engineer surfaces to extend the fatigue lives of mechanical components. A tungsten-containing diamondlike-carbon coating exhibiting high hardness, low friction, and good toughness was evaluated for application to spur gears. Fatigue testing was done at the NASA Glenn Research Center on both uncoated and coated spur gears. The results showed that the coating extended the surface fatigue lives of the gears by a factor of about 5 relative to the uncoated gears. For the experiments, a lot of spur test gears made from AISI 9310 gear steel were case-carburized and ground to aerospace specifications. The geometries of the 28-tooth, 8-pitch gears were verified as meeting American Gear Manufacturing Association (AGMA) quality class 12. One-half of the gears were randomly selected for coating. The method of coating was selected to achieve desired adherence, toughness, hardness, and low-friction characteristics. First the gears to be coated were prepared by blasting (vapor honing) with Al2O3 particles and cleaning. Then, the gears were provided with a thin adhesion layer of elemental chromium followed by magnetron sputtering of the outer coating consisting of carbon (70 at.%), hydrogen (15 at.%), tungsten (12 at.%), and nickel (3 at.%) (atomic percent at the surface). In total, the coating thickness was about 2.5 to 3 microns. As compared with the steel substrate, the coated surface was harder by a factor of about 2 and had a smaller elastic modulus. All gears were tested using a 5-centistoke synthetic oil, a 10,000-rpm rotation speed, and a hertzian contact stress of at least 1.7 GPa (250 ksi). Tests were run until either surface fatigue occurred or 300 million stress cycles were completed. Tests were run using either a pair of uncoated gears or a pair of coated gears (coated gears mated with uncoated gears were not evaluated). The fatigue test results, shown on Weibull coordinates in the graph, demonstrate that the coating provided substantially longer fatigue lives even though some of the coated gears endured larger stresses. The increase in fatigue life was a factor of about 5 and the statistical confidence for the improvement is high (greater than 99 percent). Examination of the tested gears revealed substantial reductions of total wear for coated gears in comparison to uncoated gears. The coated gear surface topography changed with running, with localized areas of the tooth surface becoming smoother with running. Theories explaining how coatings can extend gear fatigue lives are research topics for coating, tribology, and fatigue specialists. This work was done as a partnership between NASA, the U.S. Army Research Laboratory, United Technologies Research Corporation, and Sikorsky Aircraft.

Surface protection coating material for controlling the decay of major construction stone

NASA Astrophysics Data System (ADS)

Arun, T.; Ray, D. K.; Gupta, V. P.; Panda, S. S.; Sahoo, P. K.; Ghosh, Jaydip; Sengupta, Pranesh; Satyam, P. V.

2017-05-01

Degradation of the building stones are creating instability in the old building and monuments which is to be protected. To investigate the characteristics of such a stones used for the construction in eastern India, we have collected the khondalite stones. The microstructural and elemental composition analysis of the khondalite stones are analyzed by using SEM, EDX and PIXE trace elemental analysis. We have prepared surface protection coating material with graphene oxide and cobalt ferrite as a base material along with other residuals. The prepared coating materials is coated on the galvanized iron substrate for further characterization. The surface morphology characteristics of the coating material is analyzed by SEM and AFM. The corrosion resistance characteristics of the prepared coating material is studied by the electrochemical impedance spectroscopy. The results suggests that the prepared coating material can be used as a surface protection materials to control the self-destruction of khondalite stones.

Aluminum electroplating on steel from a fused bromide electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek

A quaternary bromide bath (LiBr–KBr–CsBr–AlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBr–KBr–CsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating inmore » preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.« less

Method for adhering a coating to a substrate structure

DOEpatents

Taxacher, Glenn Curtis; Crespo, Andres Garcia; Roberts, III, Herbert Chidsey

2015-02-17

A method for adhering a coating to a substrate structure comprises selecting a substrate structure having an outer surface oriented substantially parallel to a direction of radial stress, modifying the outer surface to provide a textured region having steps to adhere a coating thereto, and applying a coating to extend over at least a portion of the textured region, wherein the steps are oriented substantially perpendicular to the direction of radial stress to resist deformation of the coating relative to the substrate structure. A rotating component comprises a substrate structure having an outer surface oriented substantially parallel to a direction of radial stress. The outer surface defines a textured region having steps to adhere a coating thereto, and a coating extends over at least a portion of the textured region. The steps are oriented substantially perpendicular to the direction of radial stress to resist creep.

Surface Cracking and Interface Reaction Associated Delamination Failure of Thermal and Environmental Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dong-Ming; Choi, Sung R.; Eldridge, Jeffrey I.; Lee, Kang N.; Miller, Robert A.

2003-01-01

In this paper, surface cracking and interface reactions of a BSAS coating and a multi-layer ZrO2-8wt%Y2O3 and mullite/BSAS/Si thermal and environmental barrier coating system on SiC/SiC ceramic matrix composites were characterized after long-term combined laser thermal gradient and furnace cyclic tests in a water vapor containing environment. The surface cracking was analyzed based on the coating thermal gradient sintering behavior and thermal expansion mismatch stress characteristics under the thermal cyclic conditions. The interface reactions, which were largely enhanced by the coating surface cracking in the water vapor environment, were investigated in detail, and the reaction phases were identified for the coating system after the long-term exposure. The accelerated coating delamination failure was attributed to the increased delamination driving force under the thermal gradient cyclic loading and the reduced interface adhesion due to the detrimental interface reactions.

Surface Cracking and Interface Reaction Associated Delamination Failure of Thermal and Environmental Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Choi, Sung R.; Eldridge, Jeffrey I.; Lee, Kang N.; Miller, Robert A.

2003-01-01

In this paper, surface cracking and interface reactions of a BSAS coating and a multi-layer ZTO2-8wt%Y2O3 and mullite/BSAS/Si thermal and environmental barrier coating system on SiC/SiC ceramic matrix composites were characterized after long-term combined laser thermal gradient and furnace cyclic tests in a water vapor containing environment. The surface cracking was analyzed based on the coating thermal gradient sintering behavior and thermal expansion mismatch stress characteristics under the thermal cyclic conditions. The interface reactions, which were largely enhanced by the coating surface cracking in the water vapor environment, were investigated in detail, and the reaction phases were identified for the coating system after the long- term exposure. The accelerated coating delamination failure was attributed to the increased delamination driving force under the thermal gradient cyclic loading and the reduced interface adhesion due to the detrimental interface reactions.

Control of surface topography in biomimetic calcium phosphate coatings.

PubMed

Costa, Daniel O; Allo, Bedilu A; Klassen, Robert; Hutter, Jeffrey L; Dixon, S Jeffrey; Rizkalla, Amin S

2012-02-28

The behavior of cells responsible for bone formation, osseointegration, and bone bonding in vivo are governed by both the surface chemistry and topography of scaffold matrices. Bone-like apatite coatings represent a promising method to improve the osteoconductivity and bonding of synthetic scaffold materials to mineralized tissues for regenerative procedures in orthopedics and dentistry. Polycaprolactone (PCL) films were coated with calcium phosphates (CaP) by incubation in simulated body fluid (SBF). We investigated the effect of SBF ion concentration and soaking time on the surface properties of the resulting apatite coatings. CaP coatings were examined by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectrometry (FTIR), and energy dispersive X-ray spectrometry (EDX). Young's modulus (E(s)) was determined by nanoindentation, and surface roughness was assessed by atomic force microscopy (AFM) and mechanical stylus profilometry. CaP such as carbonate-substituted apatite were deposited onto PCL films. SEM and AFM images of the apatite coatings revealed an increase in topographical complexity and surface roughness with increasing ion concentration of SBF solutions. Young's moduli (E(s)) of various CaP coatings were not significantly different, regardless of the CaP phase or surface roughness. Thus, SBF with high ion concentrations may be used to coat synthetic polymers with CaP layers of different surface topography and roughness to improve the osteoconductivity and bone-bonding ability of the scaffold. © 2012 American Chemical Society

Undercutting of defects in thin film protective coatings on polymer surfaces exposed to atomic oxygen

NASA Technical Reports Server (NTRS)

Rutledge, Sharon K.; Mihelcic, Judith A.

1989-01-01

Protection for polymeric surfaces is needed to make them durable in the low Earth orbital environment, where oxidation by atomic oxygen is the predominant failure mechanism. Thin film coatings of oxides such as silicon dioxide are viable candidates to provide this protection, but concern has been voiced over the ability of these coatings to protect when defects are present in the coating due to surface anomalies occurring during the deposition process, handling, or micrometeoroid and debris bombardment in low Earth orbit. When a defected coating protecting a polymer substrate is exposed to atomic oxygen, the defect provides a pathway to the underlying polymer allowing oxidation and subsequent undercutting to occur. Defect undercutting was studied for sputter deposited coatings of silicon dioxide on polyimide Kapton. Preliminary results indicate that undercutting may be limited as long as the coating remains intact with the substrate. Therefore, coatings may not need to be defect free to give protection to the underlying surface.

In situ ice and structure thickness monitoring using integrated and flexible ultrasonic transducers

NASA Astrophysics Data System (ADS)

Liu, Q.; Wu, K.-T.; Kobayashi, M.; Jen, C.-K.; Mrad, N.

2008-08-01

Two types of ultrasonic sensors are presented for in situ capability development of ice detection and structure thickness measurement. These piezoelectric film based sensors have been fabricated by a sol-gel spray technique for aircraft environments and for temperatures ranging from -80 to 100 °C. In one sensor type, piezoelectric films of thickness greater than 40 µm are deposited directly onto the interior of a 1.3 mm thick aluminum (Al) alloy control surface (stabilizer) of an aircraft wing structure as integrated ultrasonic transducers (UTs). In the other sensor type, piezoelectric films are coated onto a 50 µm thick polyimide membrane as flexible UTs. These were subsequently glued onto similar locations at the same control surfaces. In situ monitoring of stabilizer outer skin thickness was performed. Ice build-up ranging from a fraction of 1 mm to less than 1.5 mm was also detected on a 3 mm thick Al plate. Measurements using these ultrasonic sensors agreed well with those obtained by a micrometer. Tradeoffs of these two approaches are presented.

Medical implants and methods of making medical implants

DOEpatents

Shaw, Wendy J; Yonker, Clement R; Fulton, John L; Tarasevich, Barbara J; McClain, James B; Taylor, Doug

2014-09-16

A medical implant device having a substrate with an oxidized surface and a silane derivative coating covalently bonded to the oxidized surface. A bioactive agent is covalently bonded to the silane derivative coating. An implantable stent device including a stent core having an oxidized surface with a layer of silane derivative covalently bonded thereto. A spacer layer comprising polyethylene glycol (PEG) is covalently bonded to the layer of silane derivative and a protein is covalently bonded to the PEG. A method of making a medical implant device including providing a substrate having a surface, oxidizing the surface and reacting with derivitized silane to form a silane coating covalently bonded to the surface. A bioactive agent is then covalently bonded to the silane coating. In particular instances, an additional coating of bio-absorbable polymer and/or pharmaceutical agent is deposited over the bioactive agent.

Method and coating composition for protecting and decontaminating surfaces

DOEpatents

Overhold, D C; Peterson, M D

1959-03-10

A protective coating useful in the decontamination of surfaces exposed to radioactive substances is described. This coating is placed on the surface before use and is soluble in water, allowing its easy removal in the event decontamination becomes necessary. Suitable coating compositions may be prepared by mixing a water soluble carbohydrate such as sucrose or dextrin, together with a hygroscopic agent such as calcium chloride or zinc chloride.

METHOD AND COATING COMPOSITION FOR PROTECTING AND DECONTAMINATING SURFACES

DOEpatents

Overhold, D.C.; Peterson, M.D.

1959-03-10

A protective coating useful in the decontamination of surfaces exposed to radioactive substances is presented. This coating is placed on the surface before use and is soluble in waters allowing its easy removal in the event decontamination becomes necessary. Suitable coating compositions may be prepared by mixing a water soluble carbohydrate such as sucrose or dextrin, together with a hygroscopic agent such as calcium chloride or zinc chloride.

Bioactive glass-chitosan composite coatings on PEEK: Effects of surface wettability and roughness on the interfacial fracture resistance and in vitro cell response

NASA Astrophysics Data System (ADS)

Hong, Wei; Guo, Fangwei; Chen, Jianwei; Wang, Xin; Zhao, Xiaofeng; Xiao, Ping

2018-05-01

To improve the osteointegration of polyetheretherketone (PEEK) spinal fusions, the 45S5 bioactive glass® (BG)-chitosan (CH) composite was used to coat the PEEK by a dip-coating method at room temperature. A robust bonding between the BG-CH composite coating and the PEEK was achieved by a combined surface treatment of sand blasting and acid etching. The effects of surface wettability and surface roughness on the adhesion of the BG-CH composite coating were characterized by fracture resistance (Gc), respectively, measured by four-point bending tests. Compared with the surface polar energy (wettability), the surface roughness (>3 μm) played a more important role for the increase in Gc values by means of crack shielding effect under the mixed mode stress. The maximum adhesion strength (σ) of the coatings on the modified PEEK measured by the tensile pull-off test was about 5.73 MPa. The in vitro biocompatibilities of PEEK, including cell adhesion, cell proliferation, differentiation, and bioactivity in the stimulated body fluid (SBF), were enhanced by the presence of BG-CH composite coatings, which also suggested that this composite coating method could provide an effective solution for the weak PEEK-bone integration.

76 FR 64047 - Montana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-17

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 926... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and... amendment to the Montana regulatory program (hereinafter, the ``Montana program'') under the Surface Mining...

76 FR 36040 - Wyoming Regulatory Program

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2011-06-21

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78 FR 16204 - Wyoming Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-14

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76 FR 80310 - Wyoming Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-23

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 950... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and... amendment to the Wyoming regulatory program (hereinafter, the ``Wyoming program'') under the Surface Mining...

76 FR 67635 - Alaska Regulatory Program

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2011-11-02

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 902... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and... amendment to the Alaska regulatory program (hereinafter, the ``Alaska program'') under the Surface Mining...

76 FR 64045 - Montana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-17

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 926... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and... amendment to the Montana regulatory program (hereinafter, the ``Montana program'') under the Surface Mining...

76 FR 76111 - Montana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

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77 FR 25874 - Pennsylvania Regulatory Program

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2012-05-02

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 938... Mining Reclamation and Enforcement (OSM), Interior. ACTION: Final rule; removal of required amendment... regulatory program (the ``Pennsylvania program'') regulations under the Surface Mining Control and...

77 FR 1430 - Maryland Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-10

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 920... Mining Reclamation and Enforcement (OSM), Interior. ACTION: Proposed rule; extension of the comment... the Maryland regulatory program (the ``Maryland program'') under the Surface Mining Control and...

Liners for ion transport membrane systems

DOEpatents

Carolan, Michael Francis; Miller, Christopher Francis

2010-08-10

Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and (d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.

43 CFR 23.13 - Consultation.

Code of Federal Regulations, 2010 CFR

2010-10-01

... Lands: Interior Office of the Secretary of the Interior SURFACE EXPLORATION, MINING AND RECLAMATION OF... jurisdiction of an agency other than the Department of the Interior or under the jurisdiction of a bureau of the Department of the Interior other than the Bureau of Land Management, the mining supervisor or the...

A preliminary report on a novel electrospray technique for nanoparticle based biomedical implants coating: precision electrospraying.

PubMed

Kumbar, Sangamesh G; Bhattacharyya, Subhabrata; Sethuraman, Swaminathan; Laurencin, Cato T

2007-04-01

The compatibility and biological efficacy of biomedical implants can be enhanced by coating their surface with appropriate agents. For predictable functioning of implants in situ, it is often desirable to obtain an extremely uniform coating thickness without effects on component dimensions or functions. Conventional coating techniques require rigorous processing conditions and often have limited adhesion and composition properties. In the present study, the authors report a novel precision electrospraying technique that allows both degradable and nondegradable coatings to be placed. Thin metallic slabs, springs, and biodegradable sintered microsphere scaffolds were coated with poly(lactide-co-glycolide) (PLAGA) using this technique. The effects of process parameters such as coating material concentration and applied voltage were studied using PLAGA and poly(ethylene glycol) coatings. Morphologies of coated surfaces were qualitatively characterized by scanning electron microscopy. Qualitative observations suggested that the coatings were composed of particles of various size/shape and agglomerates with different porous architectures. PLAGA coatings of uniform thickness were observed on all surfaces. Spherical nanoparticle poly(ethylene glycol) coatings (462-930 nm) were observed at all concentrations studied. This study found that the precision electrospraying technique is elegant, rapid, and reproducible with precise control over coating thickness (mum to mm) and is a useful alternative method for surface modification of biomedical implants. (c) 2006 Wiley Periodicals, Inc.

Interface activation and surface characteristics of Ti/TiN/HA coated sintered stainless steels

NASA Astrophysics Data System (ADS)

Choe, Han-Cheol; Ko, Yeong-Mu

2006-02-01

Interface activation and surface characteristics of Ti/TiN/HA film coated sintered stainless steels (SSS) have been investigated by electrochemical and biocompatibility tests. HA (hydroxyapatite), Ti, and Ti/TiN film coatings were applied using electron-beam deposition method (EB-PVD). Ti, Ti/TiN, and Ti/TiN/HA film coated surfaces and layers were investigated by SEM and XPS. The coated films showed micro-columnar structure, and Ti/TiN/HA films were denser than Ti or HA-only film. The corrosion resistance of the HA coating was similar to that of Ti/TiN/HA film coating when Cu content reached 4 wt.%, but the corrosion resistance of the HA coating decreased when Cu content increased from 4 wt.% in 0.9% NaCl solution. Therefore, HA-only coating could ensure corrosion resistance when Cu content does not exceed 4 wt.%. The results of biocompatibility tests of SSS on dogs showed that bone formation and biocompatibility were favorable when Cu content did not exceed 4 wt.%. The biocompatibility with bone was generally favorable in Ti/TiN/HA film coating and HA-only coating, while bone formation was somewhat faster for the HA film coated surface than for the Ti/TiN/HA film coating. Also, good cell growth and osseointegration without toxicity were observed.

A Novel Method for Depositing Precious Metal Films on Difficult Surfaces

NASA Technical Reports Server (NTRS)

Veitch, L. C.; Phillip, W. H.

1994-01-01

A guanidine-based vehicle was developed to deposit precious metal coatings on surfaces known to be difficult to coat. To demonstrate this method, a platinum coating was deposited on alumina fibers using a guanidine-platinum solution. X-ray diffraction confirmed that the only species present in the coating was platinum and that all of the carbon species had been removed upon heat treatment. SEM results showed that some porosity was present but that the coatings uniformly covered the fiber surface and adhered well to the finer.

Inducement of a spontaneously wrinkled polydimethylsiloxane surface and its potential as a cell culture substrate.

PubMed

Kim, Da Som; Lee, Ho Won; Lee, Jong Hyun; Kwon, Hyuck Gi; Lee, Sang Wook; Han, Seung Jin; Jeong, Ok Chan

2018-06-18

Spontaneous wrinkling of a polydimethylsiloxane (PDMS) surface was induced by repeated thermal shrinkage of liquid PDMS coated onto a cured PDMS layer. We investigated and evaluated the potential of the resulting surface as a cell culture substrate by monitoring the viability, spreading area, and proliferation rate of MG-63 cells cultured on native, wrinkled, and poly-L-lysine (PLL)-coated PDMS surfaces. Cells seeded on the wrinkled and PLL-coated PDMS surfaces spread and adhered better than those on native surfaces. The numbers of attached cells growing on wrinkled and PLL-coated PDMS surfaces were higher than those of cells on a native PDMS surface. The spreading area of cells on the wrinkled surface was similar to that of cells on the PLL-coated surface, and was much larger than that on native PDMS. The proliferation rate of cells on the wrinkled surface was more than double that of cells on native PDMS. Reverse-transcription polymerase chain reaction (RT-PCR) analysis of integrin mRNA expression showed that cells on the wrinkled surface were more tightly attached due to higher expression of the protein than exhibited in cells on native PDMS. Thus, the novel findings of this study are that the induction of a wrinkled PDMS surface through a simple curing process produces a suitable cell culture substrate without need of surface modification, and that its effectiveness is comparable to that of a PLL-coated PDMS surface. Copyright © 2018 Elsevier B.V. All rights reserved.

Antibacterial properties of nano-silver coated PEEK prepared through magnetron sputtering.

PubMed

Liu, Xiuju; Gan, Kang; Liu, Hong; Song, Xiaoqing; Chen, Tianjie; Liu, Chenchen

2017-09-01

We aimed to investigate the cytotoxicity and antibacterial properties of nano-silver-coated polyetheretherketone (PEEK) produced through magnetron sputtering and provide a theoretical basis for its use in clinical applications. The surfaces of PEEKs were coated with nano-silver at varying thicknesses (3, 6, 9, and 12nm) through magnetron sputtering technology. The resulting coated PEEK samples were classified into the following groups according to the thickness of the nano-silver coating: PEEK-3 (3nm), PEEK-6 (6nm), PEEK-9 (9nm), PEEK-12 (12nm), and PEEK control group. The surface microstructure and composition of each sample were observed by scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy dispersive spectrum (EDS) analysis. The water contact angle of each sample was then measured by contact angle meters. A cell counting kit (CCK-8) was used to analyze the cytotoxicity of the mouse fibroblast cells (L929) in the coated groups (n=5) and group test samples (n=6), negative control (polyethylene, PE) (n=6), and positive control group (phenol) (n=6). The antibacterial properties of the samples were tested by co-culturing Streptococcus mutans and Straphylococcus aureus. The bacteria that adhered to the surface of samples were observed by SEM. The antibacterial adhesion ability of each sample was then evaluated. SEM and AFM analysis results showed that the surfaces of control group samples were smooth but compact. Homogeneous silver nano-particles (AgNPs) and nano-silver coating were uniformly distributed on the surface of the coated group samples. Compared with the control samples, the nano-silver coated samples had a significant increase in surface roughness (P<0.05) as the thickness of their nano-silver coating increased. EDS analysis showed that not only C and O but also Ag were present on the surface of the coated samples. Moreover, the water contact angle of modified samples significantly increased after nano-silver coating modification (P<0.01). CCK-8 cytotoxicity test results showed that coated samples did not exhibit cytotoxicity. The antibacterial experimental results showed that the nano-silver coating can significantly improve the antibacterial activity and bacterial adhesion ability of the PEEK samples. The compact and homogeneous nano-silver coating was successfully prepared on the surface of PEEK through magnetron sputtering. The nano-silver coated PEEKs demonstrated enhanced antibacterial activities and bacterial adhesion abilities and had no cytotoxic effects. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

The Role of Zinc Layer During Wetting of Aluminium on Zinc-coated Steel in Laser Brazing and Welding

NASA Astrophysics Data System (ADS)

Gatzen, M.; Radel, T.; Thomy, C.; Vollertsen, F.

The zinc layer of zinc-coated steel is known to be a crucial factor for the spreading of liquid aluminium on the coated surface. For industrial brazing and welding processes these zinc-coatings enable a fluxless joining between aluminium and steel in many cases. Yet, the reason for the beneficial effect of the zinc to the wetting process is not completely understood. Fundamental investigations on the wetting behaviour of single aluminium droplets on different zinc-coated steel surfaces have revealed a distinct difference between coated surfaces at room temperature and at elevated temperature regarding the influence of different coating thicknesses. In this paper the case of continuous laser brazing and welding processes of aluminium and commercial galvanized zinc-coated steel sheets are presented. It is shown that in the case of bead-on-plate laser beam brazing, the coating thickness has a measureable effect on the resulting wetting angle and length but does not have a significant impact in case of overlap laser beam welding. This might be linked to different heat transfer conditions. The results also strongly indicate that proper initialbreakup of oxide layers is still required to accomplish good wetting on zinc-coated surfaces.

Laser damage initiation and growth of antireflection coated S-FAP crystal surfaces prepared by pitch lap and magnetorheological finishing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stolz, C J; Menapace, J A; Schaffers, K I

Antireflection (AR) coatings typically damage at the interface between the substrate and coating. Therefore the substrate finishing technology can have an impact on the laser resistance of the coating. For this study, AR coatings were deposited on Yb:S-FAP [Yb{sup 3+}:Sr{sub 5}(PO{sub 4}){sub 3}F] crystals that received a final polish by both conventional pitch lap finishing as well as magnetorheological finishing (MRF). SEM images of the damage morphology reveals laser damage originates at scratches and at substrate coating interfacial absorbing defects. Previous damage stability tests on multilayer mirror coatings and bare surfaces revealed damage growth can occur at fluences below themore » initiation fluence. The results from this study suggest the opposite trend for AR coatings. Investigation of unstable HR and uncoated surface damage morphologies reveals significant radial cracking that is not apparent with AR damage due to AR delamination from the coated surface with few apparent cracks at the damage boundary. Damage stability tests show that coated Yb:S-FAP crystals can operate at 1057 nm at fluences around 20 J/cm{sup 2} at 10 ns; almost twice the initiation damage threshold.« less

Improvement of arthroscopic cartilage stiffness probe using amorphous diamond coating.

PubMed

Töyräs, Juha; Korhonen, Rami K; Voutilainen, Tanja; Jurvelin, Jukka S; Lappalainen, Reijo

2005-04-01

During arthroscopic evaluation of articular cartilage unstable contact and even slipping of the measurement instrument on the tissue surface may degrade the reproducibility of the measurement. The main aim of the present study was to achieve more stable contact by controlling the friction between articular cartilage surface and the arthroscopic cartilage stiffness probe (Artscan 200, Artscan Oy, Helsinki, Finland) using amorphous diamond (AD) coating. In order to obtain surfaces with different average roughnesses (R(a)), polished stainless steel disks were coated with AD by using the filtered pulsed arc-discharge (FPAD) method. Dynamic coefficient of friction (mu) between the articular cartilage (n = 8) and the coated plates along one non-coated plate was then determined. The friction between AD and cartilage could be controlled over a wide range (mu = 0.027-0.728, p < 0.05, Wilcoxon test) by altering the roughness. Possible deterioration of cartilage was investigated by measuring surface roughness after friction tests and comparing it with the roughness of the adjacent, untested samples (n = 8). Importantly, even testing with the roughest AD (R(a) = 1250 nm) did not damage articular surface. On the basis of the friction measurements, a proper AD coating was selected for the stiffness probe. The performance of coated and non-coated probe was compared by measuring bovine osteochondral samples (n = 22) with both instruments. The reproducibility of the stiffness measurements was significantly better with the AD-coated probe (CV% = 4.7) than with the uncoated probe (CV% = 8.2). To conclude, AD coating can be used to safely control dynamic friction with articular surface. Sufficient friction between articular surface and reference plate of the arthroscopic probe improves significantly reproducibility of the stiffness measurements. (c) 2005 Wiley Periodicals, Inc.

Metallurgical coatings and thin films; Proceedings of the International Conference, 18th, San Diego, CA, Apr. 22-26, 1991. Vols. 1 & 2

NASA Technical Reports Server (NTRS)

Mcguire, Gary E. (Editor); Mcintyre, Dale C. (Editor); Hofmann, Siegfried (Editor)

1991-01-01

A conference on metallurgical coatings and thin films produced papers in the areas of coatings for use at high temperatures; hard coatings and deposition technologies; diamonds and related materials; tribological coatings/surface modifications; thin films for microelectronics and high temperature superconductors; optical coatings, film characterization, magneto-optics, and guided waves; and methods for characterizing films and modified surfaces.

Blanch Resistant and Thermal Barrier NiAl Coating Systems for Advanced Copper Alloys

NASA Technical Reports Server (NTRS)

Raj, Sai V. (Inventor)

2005-01-01

A method of forming an environmental resistant thermal barrier coating on a copper alloy is disclosed. The steps include cleansing a surface of a copper alloy, depositing a bond coat on the cleansed surface of the copper alloy, depositing a NiAl top coat on the bond coat and consolidating the bond coat and the NiAl top coat to form the thermal barrier coating. The bond coat may be a nickel layer or a layer composed of at least one of copper and chromium-copper alloy and either the bond coat or the NiAl top coat or both may be deposited using a low pressure or vacuum plasma spray.

Duty cycle dependent chemical structure and wettability of RF pulsed plasma copolymers of acrylic acid and octafluorocyclobutane

NASA Astrophysics Data System (ADS)

Muzammil, I.; Li, Y. P.; Li, X. Y.; Lei, M. K.

2018-04-01

Octafluorocyclobutane and acrylic acid (C4F8-co-AA) plasma copolymer coatings are deposited using a pulsed wave (PW) radio frequency (RF) plasma on low density polyethylene (LDPE). The influence of duty cycle in pulsed process with the monomer feed rate on the surface chemistry and wettability of C4F8-co-AA plasma polymer coatings is studied. The concentration of the carboxylic acid (hydrophilic) groups increase, and that of fluorocarbon (hydrophobic) groups decrease by lowering the duty cycle. The combined effect of surface chemistry and surface morphology of the RF pulsed plasma copolymer coatings causes tunable surface wettability and surface adhesion. The gradual emergence of hydrophilic contents leads to surface heterogeneity by lowering duty cycle causing an increased surface adhesion in hydrophobic coatings. The C4F8-co-AA plasma polymer coatings on the nanotextured surfaces are tuned from repulsive superhydrophobicity to adhesive superhydrophobicity, and further to superhydrophilicity by adjusting the duty cycles with the monomer feed rates.

Composite neutron absorbing coatings for nuclear criticality control

DOEpatents

Wright, Richard N.; Swank, W. David; Mizia, Ronald E.

2005-07-19

Thermal neutron absorbing composite coating materials and methods of applying such coating materials to spent nuclear fuel storage systems are provided. A composite neutron absorbing coating applied to a substrate surface includes a neutron absorbing layer overlying at least a portion of the substrate surface, and a corrosion resistant top coat layer overlying at least a portion of the neutron absorbing layer. An optional bond coat layer can be formed on the substrate surface prior to forming the neutron absorbing layer. The neutron absorbing layer can include a neutron absorbing material, such as gadolinium oxide or gadolinium phosphate, dispersed in a metal alloy matrix. The coating layers may be formed by a plasma spray process or a high velocity oxygen fuel process.

Ultrasonic cleaning of interior surfaces

DOEpatents

MacKenzie, D.; Odell, C.

1994-03-01

An ultrasonic cleaning apparatus is described for cleaning the interior surfaces of tubes. The apparatus includes an ultrasonic generator and reflector each coupled to opposing ends of the open-ended, fluid-filled tube. Fluid-tight couplings seal the reflector and generator to the tube, preventing leakage of fluid from the interior of the tube. The reflector and generator are operatively connected to actuators, whereby the distance between them can be varied. When the distance is changed, the frequency of the sound waves is simultaneously adjusted to maintain the resonant frequency of the tube so that a standing wave is formed in the tube, the nodes of which are moved axially to cause cavitation along the length of the tube. Cavitation maximizes mechanical disruption and agitation of the fluid, dislodging foreign material from the interior surface. 3 figures.

Ultrasonic cleaning of interior surfaces

DOEpatents

Odell, D. MacKenzie C.

1996-01-01

An ultrasonic cleaning method for cleaning the interior surfaces of tubes. The method uses an ultrasonic generator and reflector each coupled to opposing ends of the open-ended, fluid-filled tube. Fluid-tight couplings seal the reflector and generator to the tube, preventing leakage of fluid from the interior of the tube. The reflector and generator are operatively connected to actuators, whereby the distance between them can be varied. When the distance is changed, the frequency of the sound waves is simultaneously adjusted to maintain the resonant frequency of the tube so that a standing wave is formed in the tube, the nodes of which are moved axially to cause cavitation along the length of the tube. Cavitation maximizes mechanical disruption and agitation of the fluid, dislodging foreign material from the interior surface.

Ultrasonic cleaning of interior surfaces

DOEpatents

Odell, D. MacKenzie C.

1994-01-01

An ultrasonic cleaning apparatus for cleaning the interior surfaces of tubes. The apparatus includes an ultrasonic generator and reflector each coupled to opposing ends of the open-ended, fluid-filled tube. Fluid-tight couplings seal the reflector and generator to the tube, preventing leakage of fluid from the interior of the tube. The reflector and generator are operatively connected to actuators, whereby the distance between them can be varied. When the distance is changed, the frequency of the sound waves is simultaneously adjusted to maintain the resonant frequency of the tube so that a standing wave is formed in the tube, the nodes of which are moved axially to cause cavitation along the length of the tube. Cavitation maximizes mechanical disruption and agitation of the fluid, dislodging foreign material from the interior surface.

Effects of Coating Materials and Processing Conditions on Flow Enhancement of Cohesive Acetaminophen Powders by High-Shear Processing With Pharmaceutical Lubricants.

PubMed

Wei, Guoguang; Mangal, Sharad; Denman, John; Gengenbach, Thomas; Lee Bonar, Kevin; Khan, Rubayat I; Qu, Li; Li, Tonglei; Zhou, Qi Tony

2017-10-01

This study has investigated the surface coating efficiency and powder flow improvement of a model cohesive acetaminophen powder by high-shear processing with pharmaceutical lubricants through 2 common equipment, conical comil and high-shear mixer. Effects of coating materials and processing parameters on powder flow and surface coating coverage were evaluated. Both Carr's index and shear cell data indicated that processing with the lubricants using comil or high-shear mixer substantially improved the flow of the cohesive acetaminophen powder. Flow improvement was most pronounced for those processed with 1% wt/wt magnesium stearate, from "cohesive" for the V-blended sample to "easy flowing" for the optimally coated sample. Qualitative and quantitative characterizations demonstrated a greater degree of surface coverage for high-shear mixing compared with comilling; nevertheless, flow properties of the samples at the corresponding optimized conditions were comparable between 2 techniques. Scanning electron microscopy images demonstrated different coating mechanisms with magnesium stearate or l-leucine (magnesium stearate forms a coating layer and leucine coating increases surface roughness). Furthermore, surface coating with hydrophobic magnesium stearate did not retard the dissolution kinetics of acetaminophen. Future studies are warranted to evaluate tableting behavior of such dry-coated pharmaceutical powders. Copyright © 2017 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Silver/hydroxyapatite composite coatings on porous titanium surfaces by sol-gel method.

PubMed

Qu, Jie; Lu, Xiong; Li, Dan; Ding, Yonghui; Leng, Yang; Weng, Jie; Qu, Shuxin; Feng, Bo; Watari, Fumio

2011-04-01

Hydroxyapatite (HA) coatings loaded with nanosilver particles is an attractive method to impart the HA coating with antibacterial properties. Producing Ag/HA coatings on porous Ti substrates have been an arduous job since commonly used line-of-sight techniques are not able to deposit uniform coatings on the inner pore surfaces of the porous Ti. In this study, porous Ti scaffolds with high porosity and interconnected structures were prepared by polymer impregnating method. A sol-gel process was used to produce uniform Ag/HA composite coatings on the surfaces of porous Ti substrates. Ca(NO(3) )(2) ·4H(2) O and P(2) O(5) in an ethyl alcohol based system was selected to prepare the sol, which ensured the homogeneous distribution of Ag in the sol. The characterization revealed that silver particles uniformly distributed in the coatings without agglomeration. High antibacterial ratio (>95%), against E. coli and S. albus was expressed by the silver-containing coatings (Ag/HA 0.8 and 1.6 wt %). The biocompatibility of the Ag/HA 0.8 surfaces was as good as that of pure HA surface, as revealed by culturing osteoblasts on them. The results indicated that Ag/HA 0.8 had the good balance between the biocompatibility and antibacterial properties of the coatings. Copyright © 2011 Wiley Periodicals, Inc.

Stable superhydrophilic coating on superhydrophobic porous media by functionalized nanoparticles

NASA Astrophysics Data System (ADS)

Khazaei, Masoud; Taghi Sadeghi, Mohammad; Sadat Hosseini, Marzieh

2018-01-01

In this study, the hydrophilicity property of TiO2 nano-coating was improved by zinc acetate-assisted sol-gel method. The stable superhydrophilic coating was fabricated on a superhydrophobic mineral rock surface. The wettability of surface before and after coating was characterized by contact angle measurements. The n-heptane and water droplet contact angle was 0° and 168° respectively, so the untreated rock was superhydrophobic. After nano-treatment, the n-heptane and water contact angle changed to 172° and 0° respectively, so the superhydrophilic coating was formed on the superhydrophobic surface. The thermal, mechanical and salinity stability of the fabricated coatings was investigated. The coatings had high thermal and salinity stability; they also had moderate mechanical stability that was evaluated by abrasion test. The morphology and composition of synthesized nanoparticles were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy and x-ray diffraction (XRD) analyses. Characterization of the coated surfaces was conducted by SEM and XRD analyses. Applications of these nano-coatings include surfaces where cleanliness is paramount such as in hospitals as well as the protection of public monuments and building facades from weathering. Novel industrial application includes wettability alteration of oil wet carbonate rock for enhanced oil recovery.

Flow accelerated organic coating degradation

NASA Astrophysics Data System (ADS)

Zhou, Qixin

Applying organic coatings is a common and the most cost effective way to protect metallic objects and structures from corrosion. Water entry into coating-metal interface is usually the main cause for the deterioration of organic coatings, which leads to coating delamination and underfilm corrosion. Recently, flowing fluids over sample surface have received attention due to their capability to accelerate material degradation. A plethora of works has focused on the flow induced metal corrosion, while few studies have investigated the flow accelerated organic coating degradation. Flowing fluids above coating surface affect corrosion by enhancing the water transport and abrading the surface due to fluid shear. Hence, it is of great importance to understand the influence of flowing fluids on the degradation of corrosion protective organic coatings. In this study, a pigmented marine coating and several clear coatings were exposed to the laminar flow and stationary immersion. The laminar flow was pressure driven and confined in a flow channel. A 3.5 wt% sodium chloride solution and pure water was employed as the working fluid with a variety of flow rates. The corrosion protective properties of organic coatings were monitored inline by Electrochemical Impedance Spectroscopy (EIS) measurement. Equivalent circuit models were employed to interpret the EIS spectra. The time evolution of coating resistance and capacitance obtained from the model was studied to demonstrate the coating degradation. Thickness, gloss, and other topography characterizations were conducted to facilitate the assessment of the corrosion. The working fluids were characterized by Fourier Transform Infrared Spectrometer (FTIR) and conductivity measurement. The influence of flow rate, fluid shear, fluid composition, and other effects in the coating degradation were investigated. We conclude that flowing fluid on the coating surface accelerates the transport of water, oxygen, and ions into the coating, as well as promotes the migration of coating materials from the coating into the working fluid, where coatings experience more severe deterioration in their barrier property under flowing conditions. Pure water has shown to be a much more aggressive working fluid than electrolyte solutions. The flowing fluid over the coating surface could be used as an effective acceleration method.

Influence of Surface Tension and Surface Shear on Final Coat Thickness in Jet-Stripped Continuous Coating of Sheet Materials.

DTIC Science & Technology

1983-11-01

galvanising industry, this pressure distribution is created by blowing a thin high-speed air jet onto the coated steel sheet, just after it emerges from the...if that free surface possesses curvature and non-zero surface tension, the internal pressure will differ from that in the jet. In the galvanising

Electromagnetic properties of material coated surfaces

NASA Technical Reports Server (NTRS)

Beard, L.; Berrie, J.; Burkholder, R.; Dominek, A.; Walton, E.; Wang, N.

1989-01-01

The electromagnetic properties of material coated conducting surfaces were investigated. The coating geometries consist of uniform layers over a planar surface, irregularly shaped formations near edges and randomly positioned, electrically small, irregularly shaped formations over a surface. Techniques to measure the scattered field and constitutive parameters from these geometries were studied. The significance of the scattered field from these geometries warrants further study.

Refinement of Promising Coating Compositions for Directionally Cast Eutectics

NASA Technical Reports Server (NTRS)

Strangman, T. E.; Felten, E. J.; Benden, R. S.

1976-01-01

The successful application of high creep strength, directionally solidified gamma/gamma prime-delta (Ni-19.7Cb-6Cr-2.5Al) eutectic superalloy turbine blades requires the development of suitable coatings for airfoil, root and internal blade surfaces. In order to improve coatings for the gamma/gamma prime-delta alloy, the current investigation had the goals of (1) refining promising coating compositions for directionally solidified eutectics, (2) evaluating the effects of coating/ substrate interactions on the mechanical properties of the alloy, and (3) evaluating diffusion aluminide coatings for internal surfaces. Burner rig cyclic oxidation, furnace cyclic hot corrosion, ductility, and thermal fatigue tests indicated that NiCrAlY+Pt(63 to 127 micron Ni-18Cr-12Al-0.3Y + 6 micron Pt) and NiCrAlY(63 to 127 micron Ni-18Cr-12Al-0.3Y) coatings are capable of protecting high temperature gas path surfaces of eutectic alloy airfoils. Burner rig (Mach 0.37) testing indicated that the useful coating life of the 127 micron thick coatings exceeded 1000 hours at 1366 K (2000 deg F). Isothermal fatigue and furnance hot corrosion tests indicated that 63 micron NiCrAlY, NiCrAlY + Pt and platinum modified diffusion aluminide (Pt + Al) coating systems are capable of protecting the relatively cooler surfaces of the blade root. Finally, a gas phase coating process was evaluated for diffusion aluminizing internal surfaces and cooling holes of air-cooled gamma/gamma prime-delta turbine blades.

Vapor deposition on doublet airfoil substrates: Control of coating thickness and microstructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu

Gas jet assisted vapor deposition processes for depositing coatings are conducted at higher pressures than conventional physical vapor deposition methods, and have shown promise for coating complex shaped substrates including those with non-line-of-sight (NLS) regions on their surface. These regions typically receive vapor atoms at a lower rate and with a wider incident angular distribution than substrate regions in line-of-sight (LS) of the vapor source. To investigate the coating of such substrates, the thickness and microstructure variation along the inner (curved) surfaces of a model doublet airfoil containing both LS and NLS regions has been investigated. Results from atomistic simulationsmore » and experiments confirm that the coating's thickness is thinner in flux-shadowed regions than in other regions for all the coating processes investigated. They also indicated that the coatings columnar microstructure and pore volume fraction vary with surface location through the LS to NLS transition zone. A substrate rotation strategy for optimizing the thickness over the entire doublet airfoil surface was investigated, and led to the identification of a process that resulted in only small variation of coating thickness, columnar growth angle, and pore volume fraction on all doublet airfoil surfaces.« less

Metal organic chemical vapor deposition of environmental barrier coatings for the inhibition of solid deposit formation from heated jet fuel

NASA Astrophysics Data System (ADS)

Mohan, Arun Ram

Solid deposit formation from jet fuel compromises the fuel handling system of an aviation turbine engine and increases the maintenance downtime of an aircraft. The deposit formation process depends upon the composition of the fuel, the nature of metal surfaces that come in contact with the heated fuel and the operating conditions of the engine. The objective of the study is to investigate the effect of substrate surfaces on the amount and nature of solid deposits in the intermediate regime where both autoxidation and pyrolysis play an important role in deposit formation. A particular focus has been directed to examining the effectiveness of barrier coatings produced by metal organic chemical vapor deposition (MOCVD) on metal surfaces for inhibiting the solid deposit formation from jet fuel degradation. In the first part of the experimental study, a commercial Jet-A sample was stressed in a flow reactor on seven different metal surfaces: AISI316, AISI 321, AISI 304, AISI 347, Inconel 600, Inconel 718, Inconel 750X and FecrAlloy. Examination of deposits by thermal and microscopic analysis shows that the solid deposit formation is influenced by the interaction of organosulfur compounds and autoxidation products with the metal surfaces. The nature of metal sulfides was predicted by Fe-Ni-S ternary phase diagram. Thermal stressing on uncoated surfaces produced coke deposits with varying degree of structural order. They are hydrogen-rich and structurally disordered deposits, spherulitic deposits, small carbon particles with relatively ordered structures and large platelets of ordered carbon structures formed by metal catalysis. In the second part of the study, environmental barrier coatings were deposited on tube surfaces to inhibit solid deposit formation from the heated fuel. A new CVD system was configured by the proper choice of components for mass flow, pressure and temperature control in the reactor. A bubbler was designed to deliver the precursor into the reactor for the deposition of metal and metal oxide functional coatings by MOCVD. Alumina was chosen as a candidate for metal oxide coating because of its thermal and phase stability. Platinum was chosen as a candidate to utilize the oxygen spillover process to maintain a self-cleaning surface by oxidizing the deposits formed during thermal stressing. Two metal organic precursors, aluminum trisecondary butoxide and aluminum acetylacetonate, were used as precursors to coat tubes of varying diameters. The morphology and uniformity of the coatings were characterized by electron microscopy and energy-dispersive x-ray spectroscopy. The coating was characterized by x-ray photoelectron spectroscopy to obtain the surface chemical composition. This is the first study conducted to examine the application of MOCVD to coat internal surfaces of tubes with varying diameters. In the third part of the study, the metal oxide coatings, alumina from aluminum acetylacetonate, alumina from aluminum trisecondary butoxide, zirconia from zirconium acetylacetonate, tantalum oxide from tantalum pentaethoxide and the metal coating, platinum from platinum acetylacetonate were deposited by MOCVD on AISI304. The chemical composition and the surface acidity of the coatings were characterized by x-ray photoelectron spectroscopy. The morphology of the coatings was characterized by electron microscopy. The coated substrates were tested in the presence of heated Jet-A in a flow reactor to evaluate their effectiveness in inhibiting the solid deposit formation. All coatings inhibited the formation of metal sulfides and the carbonaceous solid deposits formed by metal catalysis. The coatings also delayed the accumulation of solid carbonaceous deposits. In particular, it has been confirmed that the surface acidity of the metal oxide coatings affects the formation of carbonaceous deposits. Bimolecular addition reactions promoted by the Bronsted acid sites appear to lead to the formation of carbonaceous solid deposits depending on the surface acidity of the coatings. In the last part of the study, the residual carbon was incorporated in the zirconia coating by deposition with and without oxygen. As carbon surface is less active towards coke deposition, presence of residual carbon in the coating was expected to reduce its activity towards carbon deposition. The residual carbon in the coating was characterized by Raman spectroscopy and thermal analysis. However, it has been observed that residual carbon in the coating beyond a certain concentration compromises the integrity of the coating during the process of cooling the substrate from deposition temperature to room temperature. It has been found that residual carbon in the zirconia coating does not appear to affect the activity of the surface towards carbon deposition.

Wettability of Y2O3: A Relative Analysis of Thermally Oxidized, Reactively Sputtered and Template Assisted Nanostructured Coatings

PubMed Central

Barshilia, Harish C.; Chaudhary, Archana; Kumar, Praveen; Manikandanath, Natarajan T.

2012-01-01

The wettability of reactively sputtered Y2O3, thermally oxidized Y-Y2O3 and Cd-CdO template assisted Y2O3 coatings has been studied. The wettability of as-deposited Y2O3 coatings was determined by contact angle measurements. The water contact angles for reactively sputtered, thermally oxidized and template assisted Y2O3 nanostructured coatings were 99°, 117° and 155°, respectively. The average surface roughness values of reactively sputtered, thermally oxidized and template assisted Y2O3 coatings were determined by using atomic force microscopy and the corresponding values were 3, 11 and 180 nm, respectively. The low contact angle of the sputter deposited Y2O3 and thermally oxidized Y-Y2O3 coatings is attributed to a densely packed nano-grain like microstructure without any void space, leading to low surface roughness. A water droplet on such surfaces is mostly in contact with a solid surface relative to a void space, leading to a hydrophobic surface (low contact angle). Surface roughness is a crucial factor for the fabrication of a superhydrophobic surface. For Y2O3 coatings, the surface roughness was improved by depositing a thin film of Y2O3 on the Cd-CdO template (average roughness = 178 nm), which resulted in a contact angle greater than 150°. The work of adhesion of water was very high for the reactively sputtered Y2O3 (54 mJ/m2) and thermally oxidized Y-Y2O3 coatings (43 mJ/m2) compared to the Cd-CdO template assisted Y2O3 coating (7 mJ/m2). PMID:28348296

Composite pipe to metal joint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leslie, James C.; Leslie, II, James C.; Heard, James

A method for making a metal to composite tube joint including selecting an elongated interior fitting constructed with an exterior barrel, reduced in exterior diameter to form a distally facing annular shoulder and then projecting still further distally to form an interior sleeve having a radially outwardly facing bonding surface. Selecting an elongated metal outer sleeve formed proximally with a collar constructed for receipt over the barrel and increased in interior diameter and projecting distally to form an exterior sleeve having a radially inwardly facing bonding surface cooperating with the first bonding surface to form an annulus receiving an extremitymore » of a composite tube and a bond bonding the extremity of the tube to the bonding surfaces.« less

40 CFR 63.3890 - What emission limits must I meet?

Code of Federal Regulations, 2013 CFR

2013-07-01

...) National Emission Standards for Hazardous Air Pollutants for Surface Coating of Miscellaneous Metal Parts... each 12-month compliance period. (c) If your facility's surface coating operations meet the... alternatives in paragraph (c)(1) or (2) of this section. (1) If the general use or magnet wire surface coating...

40 CFR 63.3890 - What emission limits must I meet?

Code of Federal Regulations, 2014 CFR

2014-07-01

...) National Emission Standards for Hazardous Air Pollutants for Surface Coating of Miscellaneous Metal Parts... each 12-month compliance period. (c) If your facility's surface coating operations meet the... alternatives in paragraph (c)(1) or (2) of this section. (1) If the general use or magnet wire surface coating...

40 CFR 63.3890 - What emission limits must I meet?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Hazardous Air Pollutants for Surface Coating of Miscellaneous Metal Parts and Products... surface coating operations meet the applicability criteria of more than one of the subcategory emission.... (1) If the general use or magnet wire surface coating operations subject to only one of the emission...

Ultrathin Hydrophobic Coatings Obtained on Polyethylene Terephthalate Materials in Supercritical Carbon Dioxide with Co-Solvents

NASA Astrophysics Data System (ADS)

Kumeeva, T. Yu.; Prorokova, N. P.

2018-02-01

The surface properties of ultradisperse polytetrafluoroethylene coatings on polyethylene terephthalate materials modified in a supercritical carbon dioxide medium with co-solvent additions (aliphatic alcohols) were analyzed. An atomic force microscopy study revealed the peculiarities of the morphology of the hydrophobic coatings formed in the presence of co-solvents. The contribution of the co-solvents to the formation of the surface layer with a low surface energy was evaluated from the surface energy components of the modified polyester material. The stability of the coatings against dry friction was analyzed.

Antimicrobial peptide coatings for hydroxyapatite: electrostatic and covalent attachment of antimicrobial peptides to surfaces.

PubMed

Townsend, Leigh; Williams, Richard L; Anuforom, Olachi; Berwick, Matthew R; Halstead, Fenella; Hughes, Erik; Stamboulis, Artemis; Oppenheim, Beryl; Gough, Julie; Grover, Liam; Scott, Robert A H; Webber, Mark; Peacock, Anna F A; Belli, Antonio; Logan, Ann; de Cogan, Felicity

2017-01-01

The interface between implanted devices and their host tissue is complex and is often optimized for maximal integration and cell adhesion. However, this also gives a surface suitable for bacterial colonization. We have developed a novel method of modifying the surface at the material-tissue interface with an antimicrobial peptide (AMP) coating to allow cell attachment while inhibiting bacterial colonization. The technology reported here is a dual AMP coating. The dual coating consists of AMPs covalently bonded to the hydroxyapatite surface, followed by deposition of electrostatically bound AMPs. The dual approach gives an efficacious coating which is stable for over 12 months and can prevent colonization of the surface by both Gram-positive and Gram-negative bacteria. © 2017 The Author(s).

Interaction between the compact tori and coated stainless-steel samples

NASA Astrophysics Data System (ADS)

Rohollahi, A.; Khatir, S.; Xiao, C.; Hirose, A.

2017-02-01

The surface damages due to the transient heat load and particle fluxes on the surface of the coated stainless-steel (SS) samples have been investigated. University of Saskatchewan compact torus injector has been used to inject the high heat load and the particle flux on the surface of stainless samples with three different types of coatings. The type 1 samples were made from a SS plate coated by tungsten. The other two samples had additional films of either nickel (type 2) or chromium (type 3) on the type 1 samples. The vacuum plasma spray technique has been applied for the coating of the samples. Surface cracking and melting have been observed on the surface after the samples were impacted by many high-speed and dense plasmoids.

Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

DOE PAGES

Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; ...

2014-09-01

Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introducemore » sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.« less

Lubricant-Infused Nanoparticulate Coatings Assembled by Layer-by-Layer Deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sunny, S; Vogel, N; Howell, C

2014-09-01

Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introducemore » sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. The LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.« less

Surface tension and negative pressure interior of a non-singular ‘black hole’

NASA Astrophysics Data System (ADS)

Mazur, Pawel O.; Mottola, Emil

2015-11-01

The constant density interior Schwarzschild solution for a static, spherically symmetric collapsed star has a divergent pressure when its radius R≤slant \\frac{9}{8}{R}s=\\frac{9}{4}{GM}. We show that this divergence is integrable, and induces a non-isotropic transverse stress with a finite redshifted surface tension on a spherical surface of radius {R}0=3R\\sqrt{1-\\frac{8}{9}\\frac{R }{{R}s}}. For r\\lt {R}0 the interior Schwarzschild solution exhibits negative pressure. When R={R}s, the surface is localized at the Schwarzschild radius itself, {R}0={R}s, and the solution has constant negative pressure p=-\\bar{ρ } everywhere in the interior r\\lt {R}s, thereby describing a gravitational condensate star, a fully collapsed non-singular state already inherent in and predicted by classical general relativity. The redshifted surface tension of the condensate star surface is given by {τ }s={{Δ }}κ /8π G, where {{Δ }}κ ={κ }+-{κ }-=2{κ }+=1/{R}s is the difference of equal and opposite surface gravities between the exterior and interior Schwarzschild solutions. The First Law, {{d}}M={{d}}{E}V+{τ }s {{d}}A is recognized as a purely mechanical classical relation at zero temperature and zero entropy, describing the volume energy and surface energy change respectively. The Schwarzschild time t of such a non-singular gravitational condensate star is a global time, fully consistent with unitary time evolution in quantum theory. A clear observational test of gravitational condensate stars with a physical surface versus black holes is the discrete surface modes of oscillation which should be detectable by their gravitational wave signatures.

Influence of epoxy, polytetrafluoroethylene (PTFE) and rhodium surface coatings on surface roughness, nano-mechanical properties and biofilm adhesion of nickel titanium (Ni-Ti) archwires

NASA Astrophysics Data System (ADS)

Asiry, Moshabab A.; AlShahrani, Ibrahim; Almoammar, Salem; Durgesh, Bangalore H.; Kheraif, Abdulaziz A. Al; Hashem, Mohamed I.

2018-02-01

Aim. To investigate the effect of epoxy, polytetrafluoroethylene (PTFE) and rhodium surface coatings on surface roughness, nano-mechanical properties and biofilm adhesion of nickel titanium (Ni-Ti) archwires Methods. Three different coated (Epoxy, polytetrafluoroethylene (PTFE) and rhodium) and one uncoated Ni-Ti archwires were evaluated in the present study. Surface roughness (Ra) was assessed using a non-contact surface profilometer. The mechanical properties (nano-hardness and elastic modulus) were measured using a nanoindenter. Bacterial adhesion assays were performed using Streptococcus mutans (MS) and streptococcus sobrinus (SS) in an in-vitro set up. The data obtained were analyzed using analyses of variance, Tukey’s post hoc test and Pearson’s correlation coefficient test. Result. The highest Ra values (1.29 ± 0.49) were obtained for epoxy coated wires and lowest Ra values (0.29 ± 0.16) were obtained for the uncoated wires. No significant differences in the Ra values were observed between the rhodium coated and uncoated archwires (P > 0.05). The highest nano-hardness (3.72 ± 0.24) and elastic modulus values (61.15 ± 2.59) were obtained for uncoated archwires and the lowest nano-hardness (0.18 ± 0.10) and elastic modulus values (4.84 ± 0.65) were observed for epoxy coated archwires. No significant differences in nano-hardness and elastic modulus values were observed between the coated archwires (P > 0.05). The adhesion of Streptococcus mutans (MS) to the wires was significantly greater than that of streptococcus sobrinus (SS). The epoxy coated wires demonstrated an increased adhesion of MS and SS and the uncoated wires demonstrated decreased biofilm adhesion. The Spearman correlation test showed that MS and SS adhesion was positively correlated with the surface roughness of the wires. Conclusion. The different surface coatings significantly influence the roughness, nano-mechanical properties and biofilm adhesion parameters of the archwires. The evaluated parameters were most influenced by epoxy coating followed by PTFE and rhodium coating. A positive correlation was detected between surface roughness and biofilm adhesion.

77 FR 58056 - Mississippi Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-19

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 924... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM...

77 FR 34890 - Oklahoma Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-12

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 936... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

75 FR 60371 - Alabama Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-30

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 901... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

77 FR 41680 - Indiana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-16

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 914... Mining Reclamation and Enforcement, Interior. ACTION: Final rule; approval of amendment. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM), are approving amendments to the Indiana...

77 FR 25949 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-02

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

76 FR 76109 - Colorado Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-06

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 906... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; reopening and extension of public...'') under the Surface Mining Control and Reclamation Act of 1977 (``SMCRA'' or ``the Act''). Colorado...

77 FR 66574 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-06

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

77 FR 18149 - Montana Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-27

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 926... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; reopening and extension of public... receipt of Montana's response to the Office of Surface Mining Reclamation and Enforcement's (OSM) November...

77 FR 24661 - North Dakota Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-25

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 934... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and... Surface Mining Control and Reclamation Act of 1977 (``SMCRA'' or ``the Act''). North Dakota proposes...

76 FR 23522 - Oklahoma Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-27

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 936... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM...

75 FR 21534 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-26

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

77 FR 34892 - Utah Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-12

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 944... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

77 FR 18738 - Texas Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-28

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 943... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

76 FR 9700 - Alabama Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-22

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 901... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; public comment period and opportunity for public hearing on proposed amendment. SUMMARY: We, the Office of Surface Mining Reclamation...

Interior car noise created by textured pavement surfaces : final report.

DOT National Transportation Integrated Search

1975-01-01

Because of widespread concern about the effect of textured pavement surfaces on interior car noise, sound pressure levels (SPL) were measured inside a test vehicle as it traversed 21 pavements with various textures. A linear regression analysis run o...

77 FR 40796 - Wyoming Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-11

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 950... Mining Reclamation and Enforcement, Interior. ACTION: Final rule. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM), are removing a disapproval codified in OSM regulations...

77 FR 34894 - Wyoming Regulatory Program

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-12

... DEPARTMENT OF THE INTERIOR Office of Surface Mining Reclamation and Enforcement 30 CFR Part 950... Mining Reclamation and Enforcement, Interior. ACTION: Proposed rule; withdrawal. SUMMARY: We, the Office of Surface Mining Reclamation and Enforcement (OSM), are announcing the withdrawal of a proposed rule...

Water-Based Assembly of Polymer-Metal Organic Framework (MOF) Functional Coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

De, Souvik; Nandasiri, Manjula I.; Schaef, Herbert T.

Metal organic frameworks (MOFs) have gained tremendous attention for their porosity, size selectivity, and structural diversity. There is a need for MOF-based coatings, particularly in applications such as separations, electronics and energy; yet forming thin, functional, conformal coatings is prohibitive because MOFs exist as a powder. Layer-by- layer assembly, a versatile thin film coating approach, offers a unique solution to this problem, but this approach requires MOFs that are water-dispersible and bear a surface charge. Here, we address these issues by examining water-based dispersions of MIL-101(Cr) that facilitate the formation of robust polymer-MOF hybrid coatings. Specifically, the substrate to bemore » coated is alternately exposed to an aqueous solution of poly(styrene sulfonate) and dispersion MIL-101(Cr), yielding linear film growth and coatings with a MOF content as high as 77 wt%.This approach is surface-agnostic, in which the coating is successfully applied to silicon, glass, flexible plastic, and even cotton fabric, conformally coating individual fibers. In contrast, prior attempts at forming MOF-coatings were severely limited to a handful of surfaces, required harsh chemical treatment, and were not conformal. The approach presented here unambiguously confirms that MOFs can be conformally coated onto complex and unusual surfaces, opening the door for a wide variety of applications.« less

Alzheimer's disease: An acquired neurodegenerative laminopathy.

PubMed

Frost, Bess

2016-05-03

The nucleus is typically depicted as a sphere encircled by a smooth surface of nuclear envelope. For most cell types, this depiction is accurate. In other cell types and in some pathological conditions, however, the smooth nuclear exterior is interrupted by tubular invaginations of the nuclear envelope, often referred to as a "nucleoplasmic reticulum," into the deep nuclear interior. We have recently reported a significant expansion of the nucleoplasmic reticulum in postmortem human Alzheimer's disease brain tissue. We found that dysfunction of the nucleoskeleton, a lamin-rich meshwork that coats the inner nuclear membrane and associated invaginations, is causal for Alzheimer's disease-related neurodegeneration in vivo. Additionally, we demonstrated that proper function of the nucleoskeleton is required for survival of adult neurons and maintaining genomic architecture. Here, we elaborate on the significance of these findings in regard to pathological states and physiological aging, and discuss cellular causes and consequences of nuclear envelope invagination.

40 CFR 60.461 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... in subpart A of this part. Coating means any organic material that is applied to the surface of metal... operation means the application system used to apply an organic coating to the surface of any continuous... of coating solids, of volatile organic compounds (VOC's) in a coating. (b) All symbols used in this...

40 CFR 60.461 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... in subpart A of this part. Coating means any organic material that is applied to the surface of metal... operation means the application system used to apply an organic coating to the surface of any continuous... of coating solids, of volatile organic compounds (VOC's) in a coating. (b) All symbols used in this...

40 CFR 60.461 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... in subpart A of this part. Coating means any organic material that is applied to the surface of metal... operation means the application system used to apply an organic coating to the surface of any continuous... of coating solids, of volatile organic compounds (VOC's) in a coating. (b) All symbols used in this...

40 CFR 60.461 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... in subpart A of this part. Coating means any organic material that is applied to the surface of metal... operation means the application system used to apply an organic coating to the surface of any continuous... of coating solids, of volatile organic compounds (VOC's) in a coating. (b) All symbols used in this...

Bioactivity and biocompatibility of hydroxyapatite-based bioceramic coatings on zirconium by plasma electrolytic oxidation.

PubMed

Aktuğ, Salim Levent; Durdu, Salih; Yalçın, Emine; Çavuşoğlu, Kültigin; Usta, Metin

2017-02-01

In the present work, hydroxyapatite (HAP)-based plasma electrolytic oxide (PEO) coatings were produced on zirconium at different current densities in a solution containing calcium acetate and β-calcium glycerophosphate by a single step. The phase structure, surface morphology, functional groups, thickness and roughness of the coatings were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), eddy current method and surface profilometer, respectively. The phases of cubic-zirconia, calcium zirconate and HAP were detected by XRD. The amount of HAP and calcium zirconate increased with increasing current density. The surface of the coatings was very porous and rough. Moreover, bioactivity and biocompatibility of the coatings were analyzed in vitro immersion simulated body fluid (SBF) and MTT (3-(4,5-dimethyl thiazol-2yl)-2,5-diphenyl tetrazolium bromide) assay, hemolysis assay and bacterial formation. The apatite-forming ability of the coatings was evaluated after immersion in SBF up to 28days. After immersion, the bioactivity of HAP-based coatings on zirconium was greater than the ones of uncoated zirconium and zirconium oxide-based surface. The bioactivity of PEO surface on zirconium was significantly improved under SBF conditions. The bacterial adhesion of the coatings decreased with increasing current density. The bacterial adhesion of the coating produced at 0.370A/cm 2 was minimum compared to uncoated zirconium coated at 0.260 and 0.292A/cm 2 . The hemocompatibility of HAP-based surfaces was improved by PEO. The cell attachment and proliferation of the PEO coatings were better than the one of uncoated zirconium according to MTT assay results. Copyright © 2016 Elsevier B.V. All rights reserved.

Patterned structures of graphene and graphitic carbon and methods for their manufacture

DOEpatents

Polsky, Ronen; Xiao, Xiaoyin; Burckel, David Bruce; Wheeler, David R.; Brozik, Susan M.; Beechem, Thomas Edwin

2017-01-03

A patterned graphene or graphitic body is produced by providing a three-dimensionally patterned carbonaceous body; coating the body with a catalytic metal whereby is formed a coating having an inner surface proximal the body and an outer surface distal the body; and annealing the coated body under time and temperature conditions effective to form a graphene or graphitic layer on the outer surface of the catalytic metal coating.

Patterned structures of graphene and graphitic carbon and methods for their manufacture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Polsky, Ronen; Xiao, Xiaoyin; Burckel, David Bruce

A patterned graphene or graphitic body is produced by providing a three-dimensionally patterned carbonaceous body; coating the body with a catalytic metal whereby is formed a coating having an inner surface proximal the body and an outer surface distal the body; and annealing the coated body under time and temperature conditions effective to form a graphene or graphitic layer on the outer surface of the catalytic metal coating.

Effects of copper-plasma deposition on weathering properties of wood surfaces

NASA Astrophysics Data System (ADS)

Gascón-Garrido, P.; Mainusch, N.; Militz, H.; Viöl, W.; Mai, C.

2016-03-01

Thin layers of copper micro-particles were deposited on the surfaces of Scots pine (Pinus sylvestris L.) micro-veneers using atmospheric pressure plasma to improve the resistance of the surfaces to weathering. Three different loadings of copper were established. Micro-veneers were exposed to artificial weathering in a QUV weathering tester for 0, 24, 48, 96 and 144 h following the standard EN 927-6 [1]. Mass losses after each exposure showed significant differences between copper coated and untreated micro-veneers. Tensile strength was assessed at zero span (z-strength) and finite span (f-strength) under dry conditions (20 °C, 65% RH). During 48 h, micro-veneers lost their z-strength progressively. In contrast, copper coating at highest loading imparts a photo-protective effect to wood micro-veneers during 144 h exhibiting z-strength retention of 95%. F-strength losses were similar in all copper treated and untreated micro-veneers up to 96 h. However, after 144 h, copper coated micro-veneers at highest loading showed significantly greater strength retention of 56%, while untreated micro-veneers exhibited only 38%. Infrared spectroscopy suggested that copper coating does not stabilize lignin. Inductively Coupled Plasma revealed that micro-veneers coated with the highest loading exhibited the lowest percentage of copper loss. Blue stain resistance of copper coated Scots pine following the guidelines of EN 152 [2] was performed. Additional test with different position of the coated surface was also assessed. Copper coating reduced fungal growth when coated surface is exposed in contact with vermiculite. Spores of Aureobasidium pullulans were not able to germinate on the copper coated surface positioned uppermost.

Carbon nanotube-coating accelerated cell adhesion and proliferation on poly (L-lactide)

NASA Astrophysics Data System (ADS)

Hirata, Eri; Akasaka, Tsukasa; Uo, Motohiro; Takita, Hiroko; Watari, Fumio; Yokoyama, Atsuro

2012-12-01

The surface of a polylactic acid (PLLA) was coated multiwalled carbon nanotubes (MWCNTs) in order to improve the surface properties. In addition, its surface characteristics and cell culturing properties were examined. Whole surface of PLLA was homogeneously covered by MWCNTs maintained a unique tubular structure. MWCNT-coated PLLA showed remarkable higher wettability than uncoated PLLA. Human osteosarcoma cell line (Saos2) adhered well on the CNT-coated PLLA whereas there are few cells attached on the uncoated PLLA at 2 h after seeding. The number of the cells on uncoated PLLA was still smaller than on the MWCNT-coated PLLA at 1 and 3 days. Moreover, The DNA content in the cells attached to the MWCNT-coated PLLA was significantly higher than that on the uncoated PLLA (p < 0.05) at 1 and 3 days. There was no significant difference between the scaffolds for ALP activity normalized by DNA content at both term (p > 0.1). Therefore MWCNT-coating on PLLA improved the surface wettability and initial cell attachment at early stage.

Broadband angle-independent antireflection coatings on nanostructured light trapping solar cells

NASA Astrophysics Data System (ADS)

Vázquez-Guardado, Abraham; Boroumand, Javaneh; Franklin, Daniel; Chanda, Debashis

2018-03-01

Backscattering from nanostructured surfaces greatly diminishes the efficacy of light trapping solar cells. While the analytical design of broadband, angle-independent antireflection coatings on nanostructured surfaces proved inefficient, numerical optimization proves a viable alternative. Here, we numerically design and experimentally verify the performance of single and bilayer antireflection coatings on a 2D hexagonal diffractive light trapping pattern on crystalline silicon substrates. Three well-known antireflection coatings, aluminum oxide, silicon nitride, and silicon oxide, which also double as high-quality surface passivation materials, are studied in the 400-1000 nm band. By varying thickness and conformity, the optimal parameters that minimize the broadband total reflectance (specular and scattering) from the nanostructured surface are obtained. The design results in a single-layer antireflection coating with normal-angle wavelength-integrated reflectance below 4% and a bilayer antireflection coating demonstrating reflection down to 1.5%. We show experimentally an angle-averaged reflectance of ˜5.2 % up to 60° incident angle from the optimized bilayer antireflection-coated nanostructured surface, paving the path toward practical implementation of the light trapping solar cells.

Fouling-release coatings prepared from alpha,omega-dihydroxypoly(dimethylsiloxane) cross-linked with (heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane.

PubMed

Berglin, Mattias; Wynne, Kenneth J; Gatenholm, Paul

2003-01-15

Surface properties of pristine and water-aged polymeric films made of alpha,omega-dihydroxypoly(dimethylsiloxane) (PDMS) cross-linked with (heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane (FTEOS17) or tetraethoxysilane (TEOS) were investigated. The FTEOS17-cured coatings showed stable advancing and receding contact angles over a period of 3 months of water exposure, compared to a 70 degrees decrease in receding contact angle for the TEOS-cured coatings. After immersion in water, hydroxyl groups were detected on the TEOS-cured coatings with attenuated total reflection infrared spectroscopy (ATR-FT/IR). Tapping-mode atomic force microscopy (TM-AFM) on pristine FTEOS17-cured coatings showed surfaces topologies ranging from smooth and featureless to topologically complex, depending on FTEOS17 concentration. The fluorinated coatings showed a stable surface morphology after water immersion, which we believe is due to the formation of a fluorinated siliceous phase that prevented the surface reconstruction, water penetration, and hydrolysis. The smooth pristine TEOS-cured coatings showed an increased roughness with cracks and erosion pits present on the surface after water immersion.

Preparation and Characterisation of Hydroxyapatite Coatings on Nanotubular TiO2 Surface Obtained by Sol-Gel Process.

PubMed

Shin, Jin-Ho; Kim, Jung-Hwa; Koh, Jeong-Tae; Lim, Hyun-Pil; Oh, Gye-Jeong; Lee, Seok-Woo; Lee, Kwang-Min; Yun, Kwi-Dug; Park, Sang-Won

2015-08-01

Hydroxyapatite (HA) coating on titanium dioxide (TiO2) nanotubular surface has been developed to complement the defects of both TiO2 and HA. A sol-gel processing technique was used to coat HA on TiO2 nanotubular surface. All the titanium discs were blasted with resorbable blast media (RBM). RBM-blasted Ti surface, anodized Ti surface, and sol-gel HA coating on the anodized Ti surface were prepared. The characteristics of samples were observed using scanning electron microscopy and X-ray photoemission spectroscopy. Biologic responses were evaluated with human osteosarcoma MG63 cells in vitro. The top of the TiO2 nanotubes was not completely covered by HA particles when the coating time was less than 60 sec. It was demonstrated the sol-gel derived HA film was well-crystallized and this enhanced biologic responses in early stage cell response.

Research of Adhesion Bonds Between Gas-Thermal Coating and Pre-Modified Base

NASA Astrophysics Data System (ADS)

Kovalevskaya, Z.; Zaitsev, K.; Klimenov, V.

2016-08-01

Nature of adhesive bonds between gas-thermal nickel alloy coating and carbon steel base was examined using laser profilometry, optical metallography, transmission and scanning electron microscopy. The steel surface was plastically pre-deformed by an ultrasonic tool. Proved that ultrasound pre-treatment modifies the steel surface. Increase of dislocation density and formation of sub micro-structure are base elements of surface modification. While using high-speed gas-flame, plasma and detonation modes of coatings, surface activation occurs and durable adhesion is formed. Ultrasonic pre-treatment of base material is effective when sprayed particles and base material interact through physical-chemical bond formation. Before applying high-speed gas flame and plasma sprayed coatings, authors recommend ultrasonic pretreatment, which creates periodic wavy topography with a stroke of 250 microns on the steel surface. Before applying detonation sprayed coatings, authors recommend ultrasound pretreatment that create modified surface with a uniform micro-topography.