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Sample records for coherent co2 dial

  1. 2-Micron Laser Transmitter for Coherent CO2 DIAL Measurement

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Bai, Yingxin; Yu, Jirong

    2009-01-01

    Carbon dioxide (CO2) has been recognized as one of the most important greenhouse gases. It is essential for the study of global warming to accurately measure the CO2 concentration in the atmosphere and continuously record its variation. A high repetition rate, highly efficient, Q-switched 2-micron laser system as the transmitter of a coherent differential absorption lidar for CO2 measurement has been developed in NASA Langley Research Center. This laser system is capable of making a vertical profiling of CO2 from ground and column measurement of CO2 from air and space-borne platform. The transmitter is a master-slave laser system. The master laser operates in a single frequency, either on-line or off-line of a selected CO2 absorption line. The slave laser is a Q-switched ring-cavity Ho:YLF laser which is pumped by a Tm:fiber laser. The repetition rate can be adjusted from a few hundred Hz to 10 kHz. The injection seeding success rate is from 99.4% to 99.95%. For 1 kHz operation, the output pulse energy is 5.5mJ with the pulse length of 50 ns. The optical-to-optical efficiency is 39% when the pump power is 14.5W. A Ho:YLF laser operating in the range of 2.05 micrometers can be tuned over several characteristic lines of CO2 absorption. Experimentally, a diode pumped Ho:Tm:YLF laser has been successfully used as the transmitter of coherent differential absorption lidar for the measurement of CO2 with a repetition rate of 5 Hz and pulse energy of 75 mJ. For coherent detection, high repetition rate is required for speckle averaging to obtain highly precise measurements. However, a diode pumped Ho:Tm:YLF laser can not operate in high repetition rate due to the large heat loading and up-conversion. A Tm:fiber laser pumped Ho:YLF laser with low heat loading can operate in high repetition rate. A theoretical model has been established to simulate the performance of Tm:fiber laser pumped Ho:YLF lasers. For continuous wave (CW) operation, high pump intensity with small beam

  2. High Repetition Rate Pulsed 2-Micron Laser Transmitter for Coherent CO2 DIAL Measurement

    NASA Technical Reports Server (NTRS)

    Singh, Uprendra N.; Bai, Yingxin; Yu, Jirong; Petros, Mulugeta; Petzar, Paul J.; Trieu, Bo C.; Lee, Hyung

    2009-01-01

    A high repetition rate, highly efficient, Q-switched 2-micron laser system as the transmitter of a coherent differential absorption lidar for CO2 measurement has been developed at NASA Langley Research Center. Such a laser transmitter is a master-slave laser system. The master laser operates in a single frequency, either on-line or off-line of a selected CO2 absorption line. The slave laser is a Q-switched ring-cavity Ho:YLF laser which is pumped by a Tm:fiber laser. The repetition rate can be adjusted from a few hundred Hz to 10 kHz. The injection seeding success rate is from 99.4% to 99.95%. For 1 kHz operation, the output pulse energy is 5.5mJ with the pulse length of approximately 50 ns. The optical-to-optical efficiency is 39% when the pump power is 14.5W. The measured standard deviation of the laser frequency jitter is about 3 MHz.

  3. 2-μm Coherent DIAL for CO2, H2O and Wind Field Profiling in the Lower Atmosphere: Instrumentation and Results

    NASA Astrophysics Data System (ADS)

    Gibert, Fabien; Edouart, Dimitri; Cénac, Claire; Pellegrino, Jessica; Le Mounier, Florian; Dumas, Arnaud

    2016-06-01

    We report on 2-μm coherent differential absorption lidar (CDIAL) measurements of carbon dioxide (CO2), water vapour (H2O) absorption and wind field profiling in the atmospheric boundary layer. The CDIAL uses a Tm:fiber pumped, single longitudinal mode Q-switched seeded Ho:YLF laser and a fibercoupled coherent detection. The laser operates at a pulse repetition frequency of 2 kHz and emits an output energy of 10 mJ with a pulse width of 40 ns (FWHM). Experimental horizontal and vertical range-resolved measurements were made in the atmospheric boundary layer and compared to colocated in-situ sensor data.

  4. III-V Compound Detectors for CO2 DIAL Measurements

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Abedin, M. Nurul; Sulima, Oleg V.; Ismail, Syed; Singh, Upendra N.

    2005-01-01

    Profiling of atmospheric carbon dioxide (CO2) is important for understanding the natural carbon cycle on Earth and its influence on global warming and climate change. Differential absorption lidar is a powerful remote sensing technique used for profiling and monitoring atmospheric constituents. Recently there has been an interest to apply this technique, at the 2 m wavelength, for investigating atmospheric CO2. This drives the need for high quality detectors at this wavelength. Although 2 m detectors are commercially available, the quest for a better detector is still on. The detector performance, regarding quantum efficiency, gain and associated noise, affects the DIAL signal-to-noise ratio and background signal, thereby influencing the instrument sensitivity and dynamic range. Detectors based on the III-V based compound materials shows a strong potential for such application. In this paper the detector requirements for a long range CO2 DIAL profiles will be discussed. These requirements were compared to newly developed III-V compound infrared detectors. The performance of ternary InGaSb pn junction devices will be presented using different substrates, as well as quaternary InGaAsSb npn structure. The performance study was based on experimental characterization of the devices dark current, spectral response, gain and noise. The final results are compared to the current state-of-the-art InGaAs technology. Npn phototransistor structure showed the best performance, regarding the internal gain and therefore the device signal-to-noise ratio. 2-micrometers detectivity as high as 3.9 x 10(exp 11) cmHz(sup 1/2)/W was obtained at a temperature of -20 C and 4 V bias voltage. This corresponds to a responsivity of 2650 A/W with about 60% quantum efficiency.

  5. Frequency-agile CO2 DIAL for environmental monitoring

    NASA Astrophysics Data System (ADS)

    Carr, Lewis W.; Fletcher, Leland; Crittenden, Max; Carlisle, Clinton B.; Gotoff, Steve W.; Reyes, Felix; D'Amico, Francis

    1994-06-01

    SRI International has designed and developed a fully automated frequency-agile CO2 DIAL (differential absorption lidar) system. The system sensor head consists of a single, frequency- agile, CO2, TEA laser; a 10-inch receiver telescope, a liquid-nitrogen-cooled HgCdTe detector; and a transmit energy monitor. The sensor head and its auxiliary equipment (including the data acquisition and processing system, laser power supply, and water cooler) are mounted in a Grumman-Olson 11-ft step van. The self-contained, mobile system can be used to detect and quantify many volatile organic compounds (VOCs) at parts per million sensitivities over open-path ranges to 5 km. Characterization and demonstration of the system is ongoing. However, data collected on benzene, toluene, xylene, methanol, ethyl acetate, acetic anhydride, and other VOCs will be described herein. The system could be used by industry and government agencies in stand-off monitoring to map VOC emission sources and transport patterns into surrounding communities. A single mobile system could be used for several locations to verify compliance with environmental regulations such as the 1990 Clean Air Act Amendments.

  6. Characteristics of direct detection 1.6μm CO2 DIAL with OPG transmitter

    NASA Astrophysics Data System (ADS)

    Nagasawa, C.; Shibata, Y.; Abo, M.

    2015-12-01

    In recent years, there have been significant advances in a QPM nonlinear optical frequency conversion efficienfy. The QPM condition is produced to use periodically poled ferroelectric crystals. An optical parametric oscillator (OPO), amplifier (OPA), and generator (OPG) devices are widely recognized as versatile coherent tunable spectroscopic sources. Many applications of PPLN-parametric radiation sources, such as laser remote sensing and molecular spectroscopy, require broadly tunable and narrow linewidth operation in the infrared region. We developed an optical parametric oscillator (OPO) transmitter for the first 1.6 μm CO2 DIAL. In order to improve the measurement accuracy of CO2 profiles, development of high power and wavelength stabilized laser system has been conducted. We have developed a new high-power 1.6 μm laser transmitter based on a parametric master oscillator-power amplifier (MOPA) system pumped by a LD-pumped Q-switched Nd:YAG laser which has the injection seed laser locked to the iodine absorption line. The master oscillator is the OPG transmitter and the amplifier is the OPA transmitter. Since the OPO transmitter has a cavity mirror, running the system without mode hopping requires complex control of cavity length. By contrast, the OPG transmitter has no cavity mirror, so there is no need to control cavity length. We report detail characteristics of the direct detection 1.6 μm CO2 DIAL with the OPG transmitter. Moreover, we report the technique of the simultaneously measurement temperature profiles with the CO2 concentration profiles using a CO2 absorption profile because of improvement of measurement accuracy of the CO2 concentration. This work was financially supported by the System Development Program for Advanced Measurement and Analysis of the Japan Science and Technology Agency.

  7. A new frontier in CO2 flux measurements using a highly portable DIAL laser system

    PubMed Central

    Queiβer, Manuel; Granieri, Domenico; Burton, Mike

    2016-01-01

    Volcanic CO2 emissions play a key role in the geological carbon cycle, and monitoring of volcanic CO2 fluxes helps to forecast eruptions. The quantification of CO2 fluxes is challenging due to rapid dilution of magmatic CO2 in CO2-rich ambient air and the diffuse nature of many emissions, leading to large uncertainties in the global magmatic CO2 flux inventory. Here, we report measurements using a new DIAL laser remote sensing system for volcanic CO2 (CO2DIAL). Two sites in the volcanic zone of Campi Flegrei (Italy) were scanned, yielding CO2 path-amount profiles used to compute fluxes. Our results reveal a relatively high CO2 flux from Campi Flegrei, consistent with an increasing trend. Unlike previous methods, the CO2DIAL is able to measure integrated CO2 path-amounts at distances up to 2000 m using virtually any solid surface as a reflector, whilst also being highly portable. This opens a new frontier in quantification of geological and anthropogenic CO2 fluxes. PMID:27652775

  8. A compact high repetition rate CO2 coherent Doppler lidar

    NASA Technical Reports Server (NTRS)

    Alejandro, S.; Frelin, R.; Dix, B.; Mcnicholl, P.

    1992-01-01

    As part of its program to develop coherent heterodyne detection lidar technology for space, airborne, and ground based applications, the Optical Environment Division of the USAF's Phillips Laboratory developed a compact coherent CO2 TEA lidar system. Although originally conceived as a high altitude balloon borne system, the lidar is presently integrated into a trailer for ground based field measurements of aerosols and wind fields. In this role, it will also serve as a testbed for signal acquisition and processing development for planned future airborne and space based solid state lidar systems. The system has also found significance in new areas of interest to the Air Force such as cloud studies and coherent Differential Absorption Lidar (DIAL) systems.

  9. Development and Evaluation of a High Sensitivity DIAL System for Profiling Atmospheric CO2

    NASA Technical Reports Server (NTRS)

    Ismail, Syed; Koch, Grady J.; Refaat, Tamer F.; Abedin, M. N.; Yu, Jirong; Singh, Upendra N.

    2008-01-01

    A ground-based 2-micron Differential Absorption Lidar (DIAL) CO2 profiling system for atmospheric boundary layer studies and validation of space-based CO2 sensors is being developed and tested at NASA Langley Research Center as part of the NASA Instrument Incubator Program. To capture the variability of CO2 in the lower troposphere a precision of 1-2 ppm of CO2 (less than 0.5%) with 0.5 to 1 km vertical resolution from near surface to free troposphere (4-5 km) is one of the goals of this program. In addition, a 1% (3 ppm) absolute accuracy with a 1 km resolution over 0.5 km to free troposphere (4-5 km) is also a goal of the program. This DIAL system leverages 2-micron laser technology developed under NASA's Laser Risk Reduction Program (LRRP) and other NASA programs to develop new solid-state laser technology that provides high pulse energy, tunable, wavelength-stabilized, and double-pulsed lasers that are operable over pre-selected temperature insensitive strong CO2 absorption lines suitable for profiling of lower tropospheric CO2. It also incorporates new high quantum efficiency, high gain, and relatively low noise phototransistors, and a new receiver/signal processor system to achieve high precision DIAL measurements. This presentation describes the capabilities of this system for atmospheric CO2 and aerosol profiling. Examples of atmospheric measurements in the lidar and DIAL mode will be presented.

  10. InGaAsSb Detectors Characterization for 2-Micron CO2 Lidar/DIAL Applications

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Abedin, M. Nurul; Koch, Grady J.; Singh, Upendra N.

    2003-01-01

    Recent interest in monitoring atmospheric CO2 focuses attention on infrared remote sensing using the 2-micron lidar/differential absorption lidar (DIAL) technique. Quantum detectors are critical components in this technique, and many research efforts concentrate on developing such devices for the 2-micron wavelength. Characterization results of InGaAsSb quantum detectors for the 2-micron wavelength range are presented, including experimental setup and procedure. Detectors are prototype devices manufactured by using separate absorption and multiplication (SAM) structures. Characterization experiments include V-I measurements, spectral response and its variation with bias voltage and temperature, noise measurements, noise-equivalent-power (NEP) and detectivity calculations, and signal-to-noise ratio (SNR) estimation. A slight increase in the output signal occurred with increased bias voltage and was associated with a noise level increase. Cooling down the detectors reduces noise and shifts the cutoff wavelength to shorter values. Further improvement in the design and manufacturing process, by increasing the device gain and lowering its noise level, is necessary to meet the required CO2 lidar/DIAL specifications.

  11. InGaAsSb Detectors' Characterization for 2-Micron CO2 Lidar/DIAL Applications

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Abedin, M. Nurul; Koch, Grady J.; Singh, Upendra N.

    2003-01-01

    Recent interest in monitoring atmospheric CO2 focuses attention on infrared remote sensing using the 2-micron lidar/differential absorption lidar (DIAL) technique. Quantum detectors are critical components in this technique, and many research efforts concentrate on developing such devices for the 2-micron wavelength. Characterization results of InGaAsSb quantum detectors for the 2-micron wavelength range are presented, including experimental setup and procedure. Detectors are prototype devices manufactured by using separate absorption and multiplication (SAM) structures. Characterization experiments include V-I measurements, spectral response and its variation with bias voltage and temperature, noise measurements, noise-equivalent-power (NEP) and detectivity calculations, and signal-to-noise ratio (SNR) estimation. A slight increase in the output signal occurred with increased bias voltage and was associated with a noise level increase. Cooling down the detectors reduces noise and shifts the cutoff wavelength to shorter values. Further improvement in the design and manufacturing process, by increasing the device gain and lowering its noise level, is necessary to meet the required CO2 lidar/DIAL specifications.

  12. On-line wavelength calibration of pulsed laser for CO2 DIAL sensing

    NASA Astrophysics Data System (ADS)

    Han, Ge; Gong, Wei; Lin, Hong; Ma, Xin; Xiang, Chengzhi

    2014-12-01

    Accurate on-line wavelength calibration is a crucial procedure for sensing atmospheric CO2 using the DIAL technique. Drastic fluctuations in the intensity of a pulsed laser pose a great challenge for accurate on-line wavelength determination and stabilization, resulting in CO2 retrievals lacking the desired accuracy for global climate change and carbon cycle research. To tackle this problem, a two-stage wavelength calibration method based on Voigt fitting was proposed in this work. Simulation analysis demonstrated that the proposed method is superior to the conventional method and provides wavelength calibration results with an accuracy of 0.1 pm when the noise level does not exceed than 5 %. This conclusion was confirmed through experiments with real signals. Furthermore, simulation analysis revealed that the proposed method could yield results with an accuracy of 0.1 pm by increasing the number of sample points, even for signals with noise levels of up to 20 %. This is a promising feature that could facilitate the development of DIAL systems without gas cells.

  13. Measurement of Lower-Atmospheric CO2 Concentration Distribution Using a Compact 1.6 μm DIAL

    NASA Astrophysics Data System (ADS)

    Shibata, Yasukuni; Nagasawa, Chikao; Abo, Makoto

    2016-06-01

    Knowledge of present carbon sources and sinks including their spatial distribution and their variation in time is one of the essential information for predicting future CO2 atmospheric concentration levels. The differential absorption lidar (DIAL) is expected to measure atmospheric CO2 profiles in the atmospheric boundary layer and lower troposphere from a ground platform. We have succeeded to develop a compact 1.6 μm DIAL system for measuring CO2 concentration profiles in the lower atmosphere. This 1.6 μm DIAL system consists of the optical parametric generator (OPG) transmitter that excited by the LD pumped Nd:YAG laser with high repetition rate and the receiving optics that included the near-infrared photomultiplier tube operating at the analog mode and a 25 cm telescope. CO2 concentration profiles were obtained up to 2.5 km altitude.

  14. DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2 lasers

    NASA Technical Reports Server (NTRS)

    Brockman, P.; Hess, R. V.; Staton, L. D.; Bair, C. H.

    1980-01-01

    Atmospheric trace constituent measurements with higher vertical resolution than attainable with passive radiometers are discussed. Infrared differential absorption lidar (DIAL), which depends on Mie scattering from aerosols, has special advantages for tropospheric and lower stratospheric applications and has great potential importance for measurements from shuttle and aircraft. Differential absorption lidar data reduction involves comparing large amplitude signals which have small differences. The accuracy of the trace constituent concentration inferred from DIAL measurements depends strongly on the errors in determining the amplitude of the signals. Thus, the commonly used SNR expression (signal divided by noise in the absence of signal) is not adequate to describe DIAL measurement accuracy and must be replaced by an expression which includes the random coherent (speckle) noise within the signal. A comprehensive DIAL computer algorithm is modified to include heterodyne detection and speckle noise. Examples for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system are given.

  15. Development of a Coherent Differential Absorption Lidar for Range Resolved Atmospheric CO2 Measurements

    NASA Technical Reports Server (NTRS)

    Yu, Jirong; Petros, Mulgueta; Chen, Songsheng; Bai, Yingxin; Petzar, Paul J.; Trieu, Bo. C.; Koch, Grady J.; Beyon, Jeffery J.; Singh, Upendra N.

    2010-01-01

    A pulsed, 2-m coherent Differential Absorption Lidar (DIAL) / Integrated Path Differential Absorption (IPDA) transceiver, developed under the Laser Risk Reduction Program (LRRP) at NASA, is integrated into a fully functional lidar instrument. This instrument will measure atmospheric CO2 profiles (by DIAL) initially from a ground platform, and then be prepared for aircraft installation to measure the atmospheric CO2 column densities in the atmospheric boundary layer (ABL) and lower troposphere. The airborne prototype CO2 lidar can measure atmospheric CO2 column density in a range bin of 1km with better than 1.5% precision at horizontal resolution of less than 50km. It can provide the image of the pooling of CO2 in lowlying areas and performs nighttime mass balance measurements at landscape scale. This sensor is unique in its capability to study the vertical ABL-free troposphere exchange of CO2 directly. It will allow the investigators to pursue subsequent in science-driven deployments, and provides a unique tool for Active Sensing of CO2 Emissions over Night, Days, and Seasons (ASCENDS) validation that was strongly advocated in the recent ASCENDS Workshop.

  16. Direct Detection 1.6?m DIAL / Doppler Lidar for Measurements of CO2 Concentration and Wind Profiles (Invited)

    NASA Astrophysics Data System (ADS)

    Shibata, Y.; Nagasawa, C.; Abo, M.

    2013-12-01

    Knowledge of present carbon sources and sinks including their spatial distribution and their variation in time is one of the essential information for predicting future CO2 atmospheric concentration levels. Moreover, wind information is an important parameter for transport simulations and inverse estimation of surface CO2 flux. The differential absorption lidar (DIAL) and the Doppler wind lidar with the range resolution is expected to measure atmospheric CO2 profiles and wind profiles in the atmospheric boundary layer and lower troposphere from a ground platform. We have succeeded to develop a scanning 1.6 μm DIAL and incoherent Doppler lidar system for simultaneously measuring CO2 concentration and wind speed profiles. Our 1.6 μm DIAL system consists of the Optical Parametric Generator (OPG) transmitter that excited by the LD pumped Nd: YAG laser with high repetition rate (500 Hz) and the receiving optics that included the near-infrared photomultiplier tube with high quantum efficiency operating at the photon counting mode, a fiber Bragg grating (FBG) filter to detect a Doppler shift, and a 25 cm telescope [1] [2]. We had developed an optical parametric oscillator (OPO) system for 1.6 μm CO2 DIAL[3]. To achieve continuous tuning of the resonant OPO output without mode hopping, it is necessary to vary the OPO cavity length synchronously with the seed-frequency. On the other hand, the OPG does not require a cavity and instead rely on sufficient conversion efficiency to be obtained with a single pass through the crystal. The single-frequency oscillation of the OPG was achieved by injection seeding. The CO2-DIAL was operated with the range-height indicator (RHI) mode, and the 2-D measurement provided inhomogeneity in the boundary layer. Vertical CO2 concentration profiles and wind profiles were also measured simultaneously. The elevation angle was fixed at 52 deg and CO2 concentration profiles were obtained up to 1 km altitude with 200 m height resolution. Vertical

  17. Effect of spectral time-lag correlation coefficient and signal averaging on airborne CO2 DIAL measurements

    NASA Astrophysics Data System (ADS)

    Ben-David, Avishai; Vanderbeek, Richard G.; Gotoff, Steven W.; D'Amico, Francis M.

    1997-10-01

    The effects of flight geometry, signal averaging and time- lag correlation coefficient on airborne CO2 dial lidar measurements are shown in simulations and field measurements. These factors have implications for multi- vapor measurements and also for measuring a shingle vapor with a wide absorption spectra for which one would like to make DIAL measurements at many wavelengths across the absorption spectra of the gas. Thus it is of interest to know how many wavelengths and how many groups of wavelengths can be used effectively in DIAL measurements. Our data indicate that for our lidar about 80 wavelengths can be used for DIAL measurements of a stationary vapor. The lidar signal is composed of fluctuations with three time scales: a very short time scale due to system noise which is faster than the data acquisition sampling rate of the receiver, a medium time scale due to atmospheric turbulence, and a long time scale due to slow atmospheric transmission drift from aerosol in homogeneities. The decorrelation time scale of fluctuations for airborne lidar measurements depends on the flight geometry.

  18. Wave optics simulation of atmospheric turbulence and reflective speckle effects in CO2 differential absorption lidar (DIAL)

    NASA Astrophysics Data System (ADS)

    Nelson, Douglas H.; Petrin, Roger R.; MacKerrow, Edward P.; Schmitt, Mark J.; Quick, Charles R., Jr.; Zardecki, Andrew; Porch, William M.; Whitehead, Michael C.; Walters, Donald L.

    1998-09-01

    The measurement sensitivity of CO2 differential absorption LIDAR (DIAL) can be affected by a number of different processes. We will address the interaction of two of these processes: effects due to beam propagation through atmospheric turbulence and effects due to reflective speckle. Atmospheric turbulence affects the beam distribution of energy and phase on target. These effects include beam spreading, beam wander and scintillation which can result in increased shot-to-shot signal noise. In addition, reflective speckle alone has a major impact on the sensitivity of CO2 DIAL. The interaction of atmospheric turbulence and reflective speckle is of great importance in the performance of a DIAL system. A Huygens-Fresnel wave optics propagation code has previously been developed at the Naval Postgraduate School that models the effects of atmospheric turbulence as propagation through a series of phase screens with appropriate atmospheric statistical characteristics. This code has been modified to include the effects of reflective speckle. The performance of this modified code with respect to the combined effects of atmospheric turbulence and reflective speckle is examined. Results are compared with a combination of experimental data and analytical models.

  19. Atmospheric correlation time measurements using coherent CO2 lidar

    NASA Technical Reports Server (NTRS)

    Ancellet, G. M.; Menzies, R. T.

    1986-01-01

    A pulsed TEA-CO2 lidar with coherent detection was used to measure the correlation time of backscatter from an ensemble of atmospheric aerosol particles which are illuminated by the pulsed radiation. The correlation time of the backscatter return signal is important in studies of atmospheric turbulence and its effects on optical propagation and backscatter. If the temporal coherence of the pulse is large enough, then the temporal coherence of the return signal is dominated by the turbulence and shear for a variety of interesting atmospheric conditions. Various techniques for correlation time measurement are discussed and evaluated.

  20. A Ground-Based 2-Micron DIAL System to Profile Tropospheric CO2 and Aerosol Distributions for Atmospheric Studies

    NASA Technical Reports Server (NTRS)

    Ismail, Syed; Koch, Grady; Abedin, Nurul; Refaat, Tamer; Rubio, Manuel; Davis, Kenneth; Miller, Charles; Singh, Upendra

    2006-01-01

    System will operate at a temperature insensitive CO2 line (2050.967 nm) with side-line tuning and off-set locking. Demonstrated an order of magnitude improvement in laser line locking needed for high precision measurements, side-line operation, and simultaneously double pulsing and line locking. Detector testing of phototransistor has demonstrated sensitivity to aerosol features over long distances in the atmosphere and resolve features approx. 100m. Optical systems that collect light onto small area detectors work well. Receiver optical designs are being optimized and data acquisition systems developed. CO2 line parameter characterization in progress In situ sensor calibration in progress for validation of DIAL CO2 system.

  1. Observation of vertcal CO2 concentration profiles in the lower-atmosphere using a compact direct detection 1.6 μm DIAL

    NASA Astrophysics Data System (ADS)

    Nagasawa, C.; Shibata, Y.; Abo, M.

    2015-12-01

    Knowledge of present carbon sources and sinks including their spatial profile and their variation in time is one of the essential informations for predicting future CO2 atmospheric concentration levels. Moewover, for the detailed analysis of forest carbon dynamics and CO2 fluxes of urban area, the CO2 concentration measurement techniques with high spatial and temporal resolution are required in the lower atmosphere. A differential absorption lidar (DIAL) is expected to measure atmospheric CO2 concentration profiles in the atmospheric boundary layer from a ground platform. We have succeeded to develop a compact direct detection 1.6 μm DIAL system for measuring CO2 concentration profiles in the lower atmosphere. This DIAL system consists of the optical parametric generator (OPG) transmitter that excited by the LD pumped Nd:YAG laser with high repetition rate and the receiving optics that included the near-infrared photomultiplier tube operating at the analog mode and the 25 cm telescope. We have succeeded in observing the daytime temporal change of vertical CO2 concentration profiles for the range from 0.25 to 2.5 km with integration time of 30 minutes and range resolution of 300 m. This compact direct detection CO2 DIAL is usefull for the estimation of CO2 flux. This work was financially supported by the System Development Program for Advanced Measurement and Analysis of the Japan Science and Technology Agency.

  2. Coherent differential absorption lidar measurements of CO2.

    PubMed

    Koch, Grady J; Barnes, Bruce W; Petros, Mulugeta; Beyon, Jeffrey Y; Amzajerdian, Farzin; Yu, Jirong; Davis, Richard E; Ismail, Syed; Vay, Stephanie; Kavaya, Michael J; Singh, Upendra N

    2004-09-10

    A differential absorption lidar has been built to measure CO2 concentration in the atmosphere. The transmitter is a pulsed single-frequency Ho:Tm:YLF laser at a 2.05-microm wavelength. A coherent heterodyne receiver was used to achieve sensitive detection, with the additional capability for wind profiling by a Doppler technique. Signal processing includes an algorithm for power measurement of a heterodyne signal. Results show a precision of the CO2 concentration measurement of 1%-2% 1sigma standard deviation over column lengths ranging from 1.2 to 2.8 km by an average of 1000 pulse pairs. A preliminary assessment of instrument sensitivity was made with an 8-h-long measurement set, along with correlative measurements with an in situ sensor, to determine that a CO2 trend could be detected.

  3. SF 6 leak detection of high-voltage installations using TEA-CO 2 laser-based DIAL

    NASA Astrophysics Data System (ADS)

    Kariminezhad, Hasan; Parvin, Parviz; Borna, Fazel; Bavali, Ali

    2010-04-01

    SF 6 is known as an effective insulator due to its high dielectric strength. Because of this property, it is vastly used in the sealed high-voltage (HV) installations and compact electrical distribution sites. Since then, sensing of SF 6 leakage takes significant environmental and economical advantages due to its high greenhouse effect. Here, we have quantitatively shown that our homemade differential absorption lidar (DIAL), using a pair of pulsed CO 2 lasers, enables us to detect efficiently remote SF 6 effluent up to ppm level. Moreover, the instantaneous spatial distribution of SF 6 emission were recorded at various meteorological conditions to indicate that SF 6 molecules are reluctant to diffuse quickly, willing to accumulate over the ground at definite location. The lidar attenuation and backscattering coefficients were determined for three typical meteorological conditions based on the best fitting using the least-square method. In addition, according to the spectral response, the remote isotopic identification of the abundant 32SF 6 and rare 34SF 6 species were done using dual tunable TEA-CO 2 lasers. Logarithmic derivative and Klett inversion approximations were subsequently used to determine SF 6 concentration based on DIAL equation.

  4. Flight tests of a range-resolved airborne dial with two min-tea CO2 lasers

    NASA Technical Reports Server (NTRS)

    Itabe, T.; Ishizu, M.; Aruga, T.; Igarashi, T.; Asai, K.

    1986-01-01

    It is important to measure regional distributions of ozone concentrations in a short time for understanding a mechanism of photo-chemical smog development. An airborne Differential Absorption Lidar (DIAL) system with two low-power mini-TEA CO2 lasers was developed for measuring three-dimensional distributions of ozone in the lower troposphere. The CO2 DIAL is a nadir-looking system and is designed to measure ozone profiles between ground and airplane by using atmospheric aerosols as a distributed radar target. First flight test with a single laser were conducted in February 1985 over the Tokyo area. The system was operated at an altitude of 5000 ft. Results of the first flight tests show that the height profiles of the received power in the boundary layer were different between over land and ocean. The received power has to be inverted to an expression of a single optical parameter to see real aerosol distributions. Inversion of the lidar signal to the aerosol extinction was performed by using Klett's solution.

  5. A direct detection 1.6μm DIAL with three wavelengths for high accuracy measurements of vertical CO2 concentration and temperature profiles

    NASA Astrophysics Data System (ADS)

    Shibata, Yasukuni; Nagasawa, Chikao; Abo, Makoto

    2013-10-01

    The accurate vertical CO2 profiles in the troposphere are highly desirable in the inverse techniques to improve quantification and understanding of the global budget of CO2 and also global climate changes. Moreover, wind information is an important parameter for transport simulations and inverse estimation of surface CO2 flux. A differential absorption lidar (DIAL) is an attractive method for obtaining vertical CO2 profiles and we have developed an 1.6μm DIAL system to perform simultaneous measurements of CO2 concentration, atmospheric temperature profile and wind profile. The absorption cross sections of gas and air density depends on atmospheric temperature and pressure. Then precise temperature and pressure profiles are necessary for accurate CO2 mixing ratio measurement by DIAL. Laser beams of three wavelengths around a CO2 absorption line are transmitted alternately to the atmosphere for simultaneous measurements of CO2 concentration and temperature. The receiving optics include the near-infrared photomultiplier tube and a fiber Bragg grating (FBG) filter to detect a Doppler shift.

  6. Ground return signal simulation and retrieval algorithm of spaceborne integrated path DIAL for CO2 measurements

    NASA Astrophysics Data System (ADS)

    Liu, Bing-Yi; Wang, Jun-Yang; Liu, Zhi-Shen

    2014-11-01

    Spaceborne integrated path differential absorption (IPDA) lidar is an active-detection system which is able to perform global CO2 measurement with high accuracy of 1ppmv at day and night over ground and clouds. To evaluate the detection performance of the system, simulation of the ground return signal and retrieval algorithm for CO2 concentration are presented in this paper. Ground return signals of spaceborne IPDA lidar under various ground surface reflectivity and atmospheric aerosol optical depths are simulated using given system parameters, standard atmosphere profiles and HITRAN database, which can be used as reference for determining system parameters. The simulated signals are further applied to the research on retrieval algorithm for CO2 concentration. The column-weighted dry air mixing ratio of CO2 denoted by XCO2 is obtained. As the deviations of XCO2 between the initial values for simulation and the results from retrieval algorithm are within the expected error ranges, it is proved that the simulation and retrieval algorithm are reliable.

  7. Solid-state Raman frequency converters for CO2-DIAL systems at 1.6 μm

    NASA Astrophysics Data System (ADS)

    Rhee, Hanjo; Lisinetskii, Victor; Kaminskii, Alexander A.; Eichler, Hans-Joachim

    2009-09-01

    Measurement of the three-dimensional distribution of atmospheric trace gases, especially CO2, is an important factor to improve the accuracy of climate models and to understand the global effects of the greenhouse effect. This can be achieved by differential absorption Lidar (DIAL). The absorption spectrum of CO2 features several suitable absorption lines for a ground-based or air-borne DIAL system working at wavelengths between 1.57 μm and 1.61 μm. An appropriate laser transmitter must emit laser pulses with pulse energies of more than 10 mJ and pulse duration in the nanosecond range. For high spectral purity the bandwidth is required to be less than 60 MHz. OPOs and Er-doped solid-state lasers emit around 1.6 μm, but we describe here alternatively Nd:YAG and Nd:glass laser systems with Raman converters. The use of stimulated Raman scattering in crystalline and ceramic materials is a possibility to shift the wavelength of existing lasers depending on the size of the Raman shift. After the investigation of a large number of Raman-active materials some of them could be identified as promising candidates for the conversion of typical Nd:YAG emission wavelengths, including LiNH2C6H4SO3•H2O, Ba(NO3)2, Li2SO4•H2O, Y(HCOO)3•2H2O, β-BBO and diamond. Our experiments with Ba(NO3)2 showed that the choice of the material should not be restricted to those with an adequate first order Stokes Raman line position, but also second or third order Raman shift should be considered. Development of Raman frequency converters for high pulse energies concentrates on linear and folded resonator designs and seeded Raman amplifiers using the Raman material as a direct amplifier. With Ba(NO3)2 pulse energy up to 116 mJ and 42 % quantum efficiency at the third Stokes wavelength with 1599 nm has been demonstrated. High power operation at 5 W with compensation of thermal lensing was achieved.

  8. DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2lasers

    NASA Technical Reports Server (NTRS)

    Brockman, P.; Hess, R. V.; Staton, L. D.; Bair, C. H.

    1980-01-01

    A parametric analysis of DIAL sensitivity with heterodyne detection is presented and comparisons with direct detection are discussed. Examples are given for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system. Results indicate that maximum sensitivity at minimum laser energy per measurement requires multiple pulse operation with the energy per pulse selected so that the measured photon rate is approximately equal to the detector IF bandwidth. Measurement sensitivities can be maximized and interference effects minimized by fine adjustment of measurement frequencies using the tunability of high pressure lasers. The use of rare isotope lasers minimizes loss due to CO2 atmospheric absorption.

  9. Characteristics of the OPG System USIG Quasiphase-Matched Nonlinear Crystals for 1.6 μm CO2 Dial

    NASA Astrophysics Data System (ADS)

    Shibata, Yasukuni; Nagasawa, Chikao; Abo, Makoto

    2016-06-01

    We have developed a direct detection 1.6 μm differential absorption lidar (DIAL) technique to perform range-resolved measurements of vertical CO2 concentration profiles in the atmosphere. Our 1.6 μm DIAL system consists of the optical parametric generator (OPG) and amplifier (OPA) transmitter that excited by the LD pumped Nd:YAG laser with high repetition rate (500 Hz). The OPG system consists of a quasi-phase-matched (QPM) crystal and does not need a cavity. The output power of the OPA system is 6 mJ, the full width at half maximum (FWHM) of the spectrum is about 280 MHz and spectrum purity is 91.0 +- 0.2 ~ 0.5%. CO2 concentration error from fluctuation of the spectrum purity is 0.3% at 6 km altitude and 0.4 % at 10 km altitude.

  10. In-cell measurements of smoke backscattering coefficients using a CO2 laser system for application to lidar-dial forest fire detection

    NASA Astrophysics Data System (ADS)

    Bellecci, Carlo; Gaudio, Pasquale; Gelfusa, Michela; Lo Feudo, Teresa; Murari, Andrea; Richetta, Maria; de Leo, Leonerdo

    2010-12-01

    In the lidar-dial method, the amount of the water vapor present in the smoke of the vegetable fuel is detected to reduce the number of false alarms. We report the measurements of the smoke backscattering coefficients for the CO2 laser lines 10R20 and 10R18 as determined in an absorption cell for two different vegetable fuels (eucalyptus and conifer). These experimental backscattering coefficients enable us to determine the error to be associated to the water vapor measurements when the traditional first-order approximation is assumed. We find that this first-order approximation is valid for combustion rates as low as 100 g/s.

  11. Differential Absorption Lidar (DIAL) in Alberta: A New Remote Sensing Tool for Wide Area Measurement of Particulates, CO2, and CH4 Emissions from Energy Extraction and Production Sites

    NASA Astrophysics Data System (ADS)

    Wojcik, M.; Lemon, R.; Crowther, B. G.; Valupadas, P.; Fu, L.; Yang, Z.; Huda, Q.; Leung, B.; Chambers, A.

    2014-12-01

    Alberta Environmental Monitoring, Evaluation and Reporting Agency (AEMERA) in cooperation with the Space Dynamics Laboratory (SDL) of Utah State University, have developed a mobile DIAL sensor designed specifically for particle, CO2 and CH4 emissions measurement. Rapid expansion of the oil and gas industry in Alberta, including the oil sands, has challenged the Alberta Government to keep pace in its efforts to monitor and mitigate the environmental impacts of development. The limitations of current monitoring systems has pushed the provincial government to seek out advanced sensing technologies such as differential absorption lidar (DIAL) to help assess the impact of energy development and industrial operations. This instrument is housed inside a 36' trailer and can be quickly staged and used to characterize source emissions and to locate fugitive leaks. DIAL is capable of measuring concentrations for carbon dioxide (CO2) and methane (CH4) at ranges of up to 3 km with a spatial resolution of 1.5 m. DIAL can map both CO2 and CH4, as well as particulate matter (PM) in a linear fashion; by scanning the laser beam in both azimuth and elevation, DIAL can create images of emissions concentrations and ultimately can be used to determine emission factors, locate fugitive leaks, assess plume dispersion and confirm air dispersion modeling. The DIAL system has been deployed at a landfill, a coal-fired power plant, and an oil sands production area. A system overview of the DIAL instrument and recent results will be discussed.

  12. 315mJ, 2-micrometers Double-Pulsed Coherent Differential Absorption Lidar Transmitter for Atmospheric CO2 Sensing

    NASA Technical Reports Server (NTRS)

    Yu, Jirong; Trieu, Bo; Bai, Yingxin; Koch, Grady; Chen, Songsheng; Petzar, Paul; Singh, Upendra N.; Kavaya, Michael J.; Beyon, Jeffrey

    2010-01-01

    The design of a double pulsed, injection seeded, 2-micrometer compact coherent Differential absorption Lidar (DIAL) transmitter for CO2 sensing is presented. This system is hardened for ground and airborne applications. The design architecture includes three continuous wave lasers which provide controlled on and off line seeding, injection seeded power oscillator and a single amplifier operating in double pass configuration. As the derivative a coherent Doppler wind lidar, this instrument has the added benefit of providing wind information. The active laser material used for this application is a Ho: Tm:YLF crystal operates at the eye-safe wavelength. The 3-meter long folded ring resonator produces energy of 130-mJ (90/40) with a temporal pulse length around 220 nanoseconds and 530 nanosecond pulses for on and off lines respectively. The separation between the two pulses is on the order of 200 microseconds. The line width is in the order of 2.5MHz and the beam quality has an M(sup 2) of 1.1 times diffraction limited beam. A final output energy for a pair of both on and off pulses as high as 315 mJ (190/125) at a repetition rate of 10 Hz is achieved. The operating temperature is set around 20 C for the pump diode lasers and 10 C for the rod. Since the laser design has to meet high-energy as well as high beam quality requirements, close attention is paid to the laser head design to avoid thermal distortion in the rod. A side-pumped configuration is used and heat is removed uniformly by passing coolant through a tube slightly larger than the rod to reduce thermal gradient. This paper also discusses the advantage of using a long upper laser level life time laser crystal for DIAL application. In addition issues related to injection seeding with two different frequencies to achieve a transform limited line width will be presented.

  13. Application of a CO2 dial system for infrared detection of forest fire and reduction of false alarm

    NASA Astrophysics Data System (ADS)

    Bellecci, C.; Francucci, M.; Gaudio, P.; Gelfusa, M.; Martellucci, S.; Richetta, M.; Lo Feudo, T.

    2007-04-01

    Forest fires can be the cause of serious environmental and economic damages. For this reason considerable effort has been directed toward forest protection and fire fighting. The means traditionally used for early fire detection mainly consist in human observers dispersed over forest regions. A significant improvement in early warning capabilities could be obtained by using automatic detection apparatus. In order to early detect small forest fires and minimize false alarms, the use of a lidar system and dial technique will be considered. A first evaluation of the lowest detectable concentration will be estimated by numerical simulation. The theoretical model will also be used to get the capability of the dial system to control wooded areas. Fixing the burning rate for several fuels, the maximum range of detection will be evaluated. Finally results of simulations will be reported.

  14. The Mobile Atmospheric Pollutant Mapping (MAPM) System - A coherent CO2, DIAL system

    NASA Technical Reports Server (NTRS)

    Grant, William B.

    1989-01-01

    The hardware for the Mobile Atmospheric Pollutant Mapping System is described. Measurement results using the hardware are reported along with absorption coefficients and measurement sensitivities for a number of molecular species. The factor that limit measurement accuracy and range are considered.

  15. A tunable coherent CO2 lidar for measurements of atmospheric aerosol backscatter and attenuation

    NASA Technical Reports Server (NTRS)

    Menzies, R. T.

    1983-01-01

    A coherent laser radar system using a grating-tunable, injection-locked TEA-CO2 transmitter is being used to measure the altitude dependence of atmospheric aerosol backscatter and attenuation at a variety of CO2 laser wavelengths in the 9-11 micron region. Injection control of the TEA-CO2 laser allows one to obtain Single-Longitudinal-Mode (SLM) pulses which will follow the frequency of the injected radiation if the TEA laser cavity length is adjusted so that a cavity resonance is in proximity with the injected signal frequency, and if various additional conditions are satisfied. Requirements for generation of SLM pulses in this manner from a TEA CO2 laser with an unstable resonator cavity will be discussed. Procedures used for quantitative range-gated measurements of aerosol backscatter and attenuation will also be discussed.

  16. High power CO2 coherent ladar haven't quit the stage of military affairs

    NASA Astrophysics Data System (ADS)

    Zhang, Heyong

    2015-05-01

    The invention of the laser in 1960 created the possibility of using a source of coherent light as a transmitter for a laser radar (ladar). Coherent ladar shares many of the basic features of more common microwave radars. However, it is the extremely short operating wavelength of lasers that introduces new military applications, especially in the area of missile identification, space target tracking, remote rang finding, camouflage discrimination and toxic agent detection. Therefore, the most popular application field such as laser imaging and ranging were focused on CO2 laser in the last few decades. But during the development of solid state and fiber laser, some people said that the CO2 laser will be disappeared and will be replaced by the solid and fiber laser in the field of military and industry. The coherent CO2 laser radar will have the same destiny in the field of military affairs. However, to my opinion, the high power CO2 laser will be the most important laser source for laser radar and countermeasure in the future.

  17. Dual-Pump Coherent Anti-Stokes Raman Scattering Temperature and CO2 Concentration Measurements

    NASA Technical Reports Server (NTRS)

    Lucht, Robert P.; Velur-Natarajan, Viswanathan; Carter, Campbell D.; Grinstead, Keith D., Jr.; Gord, James R.; Danehy, Paul M.; Fiechtner, G. J.; Farrow, Roger L.

    2003-01-01

    Measurements of temperature and CO2 concentration using dual-pump coherent anti-Stokes Raman scattering, (CARS) are described. The measurements were performed in laboratory flames,in a room-temperature gas cell, and on an engine test stand at the U.S. Air Force Research Laboratory, Wright-Patterson Air Force Base. A modeless dye laser, a single-mode Nd:YAG laser, and an unintensified back-illuminated charge-coupled device digital camera were used for these measurements. The CARS measurements were performed on a single-laser-shot basis. The standard deviations of the temperatures and CO2 mole fractions determined from single-shot dual-pump CARS spectra in steady laminar propane/air flames were approximately 2 and 10% of the mean values of approximately 2000 K and 0.10, respectively. The precision and accuracy of single-shot temperature measurements obtained from the nitrogen part of the dual-pump CARS system were investigated in detail in near-adiabatic hydrogen/air/CO2 flames. The precision of the CARS temperature measurements was found to be comparable to the best results reported in the literature for conventional two-laser, single-pump CARS. The application of dual-pump CARS for single-shot measurements in a swirl-stabilized combustor fueled with JP-8 was also demonstrated.

  18. The influence of biomass energy consumption on CO2 emissions: a wavelet coherence approach.

    PubMed

    Bilgili, Faik; Öztürk, İlhan; Koçak, Emrah; Bulut, Ümit; Pamuk, Yalçın; Muğaloğlu, Erhan; Bağlıtaş, Hayriye H

    2016-10-01

    In terms of today, one may argue, throughout observations from energy literature papers, that (i) one of the main contributors of the global warming is carbon dioxide emissions, (ii) the fossil fuel energy usage greatly contributes to the carbon dioxide emissions, and (iii) the simulations from energy models attract the attention of policy makers to renewable energy as alternative energy source to mitigate the carbon dioxide emissions. Although there appears to be intensive renewable energy works in the related literature regarding renewables' efficiency/impact on environmental quality, a researcher might still need to follow further studies to review the significance of renewables in the environment since (i) the existing seminal papers employ time series models and/or panel data models or some other statistical observation to detect the role of renewables in the environment and (ii) existing papers consider mostly aggregated renewable energy source rather than examining the major component(s) of aggregated renewables. This paper attempted to examine clearly the impact of biomass on carbon dioxide emissions in detail through time series and frequency analyses. Hence, the paper follows wavelet coherence analyses. The data covers the US monthly observations ranging from 1984:1 to 2015 for the variables of total energy carbon dioxide emissions, biomass energy consumption, coal consumption, petroleum consumption, and natural gas consumption. The paper thus, throughout wavelet coherence and wavelet partial coherence analyses, observes frequency properties as well as time series properties of relevant variables to reveal the possible significant influence of biomass usage on the emissions in the USA in both the short-term and the long-term cycles. The paper also reveals, finally, that the biomass consumption mitigates CO2 emissions in the long run cycles after the year 2005 in the USA.

  19. The influence of biomass energy consumption on CO2 emissions: a wavelet coherence approach.

    PubMed

    Bilgili, Faik; Öztürk, İlhan; Koçak, Emrah; Bulut, Ümit; Pamuk, Yalçın; Muğaloğlu, Erhan; Bağlıtaş, Hayriye H

    2016-10-01

    In terms of today, one may argue, throughout observations from energy literature papers, that (i) one of the main contributors of the global warming is carbon dioxide emissions, (ii) the fossil fuel energy usage greatly contributes to the carbon dioxide emissions, and (iii) the simulations from energy models attract the attention of policy makers to renewable energy as alternative energy source to mitigate the carbon dioxide emissions. Although there appears to be intensive renewable energy works in the related literature regarding renewables' efficiency/impact on environmental quality, a researcher might still need to follow further studies to review the significance of renewables in the environment since (i) the existing seminal papers employ time series models and/or panel data models or some other statistical observation to detect the role of renewables in the environment and (ii) existing papers consider mostly aggregated renewable energy source rather than examining the major component(s) of aggregated renewables. This paper attempted to examine clearly the impact of biomass on carbon dioxide emissions in detail through time series and frequency analyses. Hence, the paper follows wavelet coherence analyses. The data covers the US monthly observations ranging from 1984:1 to 2015 for the variables of total energy carbon dioxide emissions, biomass energy consumption, coal consumption, petroleum consumption, and natural gas consumption. The paper thus, throughout wavelet coherence and wavelet partial coherence analyses, observes frequency properties as well as time series properties of relevant variables to reveal the possible significant influence of biomass usage on the emissions in the USA in both the short-term and the long-term cycles. The paper also reveals, finally, that the biomass consumption mitigates CO2 emissions in the long run cycles after the year 2005 in the USA. PMID:27335019

  20. Design of Control Software for a High-Speed Coherent Doppler Lidar System for CO2 Measurement

    NASA Technical Reports Server (NTRS)

    Vanvalkenburg, Randal L.; Beyon, Jeffrey Y.; Koch, Grady J.; Yu, Jirong; Singh, Upendra N.; Kavaya, Michael J.

    2010-01-01

    The design of the software for a 2-micron coherent high-speed Doppler lidar system for CO2 measurement at NASA Langley Research Center is discussed in this paper. The specific strategy and design topology to meet the requirements of the system are reviewed. In order to attain the high-speed digitization of the different types of signals to be sampled on multiple channels, a carefully planned design of the control software is imperative. Samples of digitized data from each channel and their roles in data analysis post processing are also presented. Several challenges of extremely-fast, high volume data acquisition are discussed. The software must check the validity of each lidar return as well as other monitoring channel data in real-time. For such high-speed data acquisition systems, the software is a key component that enables the entire scope of CO2 measurement studies using commercially available system components.

  1. Diagnostics of a capillary discharge of a CO2 waveguide laser by coherent anti-Stokes Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Vakhterov, A. A.; Iliukhin, A. A.; Konev, Iu. B.; Lipatov, N. I.; Pashinin, P. P.

    1985-01-01

    Experimental results are reported from coherent anti-Stokes Raman spectroscopy (CARS) diagnostic studies of capillary discharge in the CO2:N2:He = 1:1:8 working mixture of a CO2 waveguide laser. The CARS scans were used to characterize the translational temperature of the gas and the vibrational temperatures of the discharge plasma components. The data are vital for identifying anharmonic states which reduce the laser power and working mixture lifetime. Data are furnished on the translational temperature and vibrational temperature as functions of the capillary radius. CARS is concluded to be a valid technique for studying the distribution of pump power among the degrees of freedom of the working mixture components, even when dissociation is occurring.

  2. In situ backscatter measurements over Pacific Ocean using two coherent focused CO2 lidars

    NASA Astrophysics Data System (ADS)

    Rothermel, Jeffry; Jones, William D.; Srivastava, Vandana; Jarzembski, Maurice; Hampton, Diana

    Preliminary results of CS lidar measurements over the Pacific Ocean using two CO2 Doppler lidars operating at 9.1 and 10.6 microns are presented. SNR calculations during real-time and postprocessing were performed using a multistep signal search and signal power estimation algorithm optimized for weak signal conditions. Typical aersol structure observed in the troposphere was found to consist of a boundary layer, a cloud-pumped layer, and a clean background layer; backscatter from cloud-free air was found to vary over three to four orders of magnitude or more.

  3. Energy Measurement Studies for CO2 Measurement with a Coherent Doppler Lidar System

    NASA Technical Reports Server (NTRS)

    Beyon, Jeffrey Y.; Koch, Grady J.; Vanvalkenburg, Randal L.; Yu, Jirong; Singh, Upendra N.; Kavaya, Michael J.

    2010-01-01

    The accurate measurement of energy in the application of lidar system for CO2 measurement is critical. Different techniques of energy estimation in the online and offline pulses are investigated for post processing of lidar returns. The cornerstone of the techniques is the accurate estimation of the spectrum of lidar signal and background noise. Since the background noise is not the ideal white Gaussian noise, simple average level estimation of noise level is not well fit in the energy estimation of lidar signal and noise. A brief review of the methods is presented in this paper.

  4. Simultaneous and time-resolved temperature and relative CO2-N2 and O2-CO2-N2 concentration measurements with pure rotational coherent anti-Stokes Raman scattering for pressures as great as 5 MPa

    SciTech Connect

    Schenk, Martin; Seeger, Thomas; Leipertz, Alfred

    2005-09-10

    Pure rotational coherent anti-Stokes Raman-scattering (CARS) measurements have been performed in binary CO2-N2 and ternary CO2-O2-N2 mixtures in a temperature range between 300 and 773 K and pressures from 0.1 to 5 MPa to prove its potential for simultaneous single-shot thermometry and multispecies concentration measurements. In pressurized systems the CO2 component has a strong spectral influence on the pure rotational CARS spectra. Because of this dominance, pure rotational CARS proves to be a sensitive tool to measure in high-pressure combustion systems and the relative CO2-N2 concentration in the lower temperature range simultaneously with the temperature and the relative O2-N2 concentration. The evaluation of the spectra utilized a least-sum-squared differences fit of the spectral shape, weighted either constantly or inversely with respect to the normalized signal intensity. The results of the simultaneous temperature and relative CO2-N2 and O2-CO2-N2 concentration measurements provided a good accuracy and precision both in temperature and in concentrations. Because of the strong increase in the relative spectral contribution of CO2 with rising pressure, the precision of the CO2 concentration determination is in general significantly improved toward higher pressures, thus also clearly enhancing the CO2 detectability. The influence of temperature, O2 and CO2 concentration, pressure, and the evaluation techniques employed on both the accuracy and the precision is explained as well as their cross dependencies. The influence and limitations of the approximations used to model the CO2 molecule are discussed.

  5. Can CO2 Turbulent Flux Be Measured by Lidar? A Preliminary Study

    NASA Technical Reports Server (NTRS)

    Gilbert, Fabien; Koch, Grady; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Flamant, Pierre H.; Singh, Upendra N.

    2011-01-01

    The vertical profiling ofCO2 turbulent fluxes in the atmospheric boundary layer (ABL) is investigated using a coherent differential absorption lidar (CDIAL) operated nearby a tall tower in Wisconsin during June 2007. A CDIAL can perform simultaneous range-resolved CO2 DIAL and velocity measurements. The lidar eddy covariance technique is presented. The aims of the study are (i) an assessment of performance and current limitation of available CDIAL for CO2 turbulent fluxes and (ii) the derivation of instrument specifications to build a future CDIAL to perform accurate range-resolved CO2 fluxes. Experimental lidar CO2 mixing ratio and vertical velocity profiles are successfully compared with in situ sensors measurements. Time and space integral scales of turbulence in the ABL are addressed that result in limitation for time averaging and range accumulation. A first attempt to infer CO2 fluxes using an eddy covariance technique with currently available 2-mm CDIAL dataset is reported.

  6. Side-line tunable laser transmitter for differential absorption lidar measurements of CO2: design and application to atmospheric measurements

    NASA Astrophysics Data System (ADS)

    Koch, Grady J.; Beyon, Jeffrey Y.; Gibert, Fabien; Barnes, Bruce W.; Ismail, Syed; Petros, Mulugeta; Petzar, Paul J.; Yu, Jirong; Modlin, Edward A.; Davis, Kenneth J.; Singh, Upendra N.

    2008-03-01

    A 2 μm wavelength, 90 mJ, 5 Hz pulsed Ho laser is described with wavelength control to precisely tune and lock the wavelength at a desired offset up to 2.9 GHz from the center of a CO2 absorption line. Once detuned from the line center the laser wavelength is actively locked to keep the wavelength within 1.9 MHz standard deviation about the setpoint. This wavelength control allows optimization of the optical depth for a differential absorption lidar (DIAL) measuring atmospheric CO2 concentrations. The laser transmitter has been coupled with a coherent heterodyne receiver for measurements of CO2 concentration using aerosol backscatter; wind and aerosols are also measured with the same lidar and provide useful additional information on atmospheric structure. Range-resolved CO2 measurements were made with <2.4% standard deviation using 500 m range bins and 6.7 min⁡ (1000 pulse pairs) integration time. Measurement of a horizontal column showed a precision of the CO2 concentration to <0.7% standard deviation using a 30 min⁡ (4500 pulse pairs) integration time, and comparison with a collocated in situ sensor showed the DIAL to measure the same trend of a diurnal variation and to detect shorter time scale CO2 perturbations. For vertical column measurements the lidar was setup at the WLEF tall tower site in Wisconsin to provide meteorological profiles and to compare the DIAL measurements with the in situ sensors distributed on the tower up to 396 m height. Assuming the DIAL column measurement extending from 153 m altitude to 1353 m altitude should agree with the tower in situ sensor at 396 m altitude, there was a 7.9 ppm rms difference between the DIAL and the in situ sensor using a 30 min⁡ rolling average on the DIAL measurement.

  7. A Two Micron Coherent Differential Absorption Lidar Development

    NASA Technical Reports Server (NTRS)

    Yu, Jirong; Petros, Mulugeta; Chen, Songsheng; Bai, Yingxin; Petzar, Paul J.; Trieu, Bo C.; Koch, Grady J.; Beyon, Jeffrey Y.; VanValkenburg, Randal L.; Kavaya, Michael J.; Singh, Upendra N.

    2010-01-01

    A pulsed, 2-micron coherent Differential Absorption Lidar (DIAL)/Integrated Path Differential Absorption (IPDA) transceiver, developed under the Laser Risk Reduction Program (LRRP) at NASA, is integrated into a fully functional lidar instrument. This instrument measures atmospheric CO2 profiles (by DIAL) from a ground platform. It allows the investigators to pursue subsequent in science-driven deployments, and provides a unique tool for Active Sensing of CO2 Emissions over Night, Days, and Seasons (ASCENDS) validation that was strongly advocated in the recent ASCENDS Workshop. Keywords: Differential Absorption Lidar, Near Infrared Laser,

  8. Coherent laser radar at 2 microns using solid-state lasers

    NASA Technical Reports Server (NTRS)

    Henderson, Sammy W.; Suni, Paul J. M.; Hale, Charley P.; Hannon, Stephen M.; Magee, James R.; Bruns, Dale L.; Yuen, Eric H.

    1993-01-01

    Coherent laser radar systems using 2-micron Tm- and Tm, Ho-doped solid-state lasers are useful for the remote range-resolved measurement of atmospheric winds, aerosol backscatter, and DIAL measurements of atmospheric water vapor and CO2 concentrations. Recent measurements made with a 2-micron coherent laser radar system, advances in the laser technology, and atmospheric propagation effects on 2-micron coherent lidar performance are described.

  9. Rock formation characterization for CO2-EOR and carbon geosequestration; 3D seismic amplitude and coherency anomalies, Wellington Field, Kansas, USA

    USGS Publications Warehouse

    Ohl, D.; Raef, A.; Watnef, L.; Bhattacharya, S.

    2011-01-01

    In this paper, we present a workflow for a Mississipian carbonates characterization case-study integrating post-stack seismic attributes, well-logs porosities, and seismic modeling to explore relating changes in small-scale "lithofacies" properties and/or sub-seismic resolution faulting to key amplitude and coherency 3D seismic attributes. The main objective of this study is to put emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2-EOR in preparation for future carbon geosequestration in a depleting reservoir and a deep saline aquifer. The extracted 3D seismic coherency attribute indicated anomalous features that can be interpreted as a lithofacies change or a sub-seismic resolution faulting. A 2D finite difference modeling has been undertaken to understand and potentially build discriminant attributes to map structural and/or lithofacies anomalies of interest especially when embarking upon CO2-EOR and/or carbon sequestration monitoring and management projects. ?? 2011 Society of Exploration Geophysicists.

  10. Time-resolved CO2 thermometry for pressures as great as 5 MPa by use of pure rotational coherent anti-Stokes Raman scattering

    SciTech Connect

    Schenk, Martin; Seeger, Thomas; Leipertz, Alfred

    2005-11-01

    Pure rotational coherent anti-Stokes Raman scattering measurements of pure CO2 have been performed in a temperature range from 300 to 773 K and for pressure from 0.1 to 5 MPa for the purpose of time-resolved CO2 thermometry. Particular emphasis was put on the comparison of several linewidth approximations to model the experimental spectra. Generally good agreement of the temperature mean values with the thermocouple reference has been found for all models over almost the whole pressure and temperature range investigated. The standard deviations, which increased with temperature, were comparable with or better than the results gained for single-shot measurements of pure N2 or O2-N2 mixtures. Yet for high particle densities close to the critical point of CO2 the limitation of the models became obvious, owing to the strongly increased influence of motional narrowing effects. The characteristics of these effects have been demonstrated by measurements even closer to the critical conditions.

  11. Investigation of Acid-Etched CO2 Laser Ablated Enamel Surfaces Using Polarization Sensitive Optical Coherence Tomography

    PubMed Central

    Nahm, Byung J.; Kang, Hobin; Chan, Kenneth; Fried, Daniel

    2012-01-01

    A carbon dioxide laser operating at the highly absorbed wavelength of 9.3μm with a pulse duration of 10–15μs is ideally suited for caries removal and caries prevention. The enamel thermally modified by the laser has enhanced resistance to acid dissolution. This is an obvious advantage for caries prevention; however, it is often necessary to etch the enamel surface to increase adhesion to composite restorative materials and such surfaces may be more resistant to etching. The purpose of the study was to non-destructively measure the susceptibility of laser-ablated enamel surfaces to acid dissolution before and after acid-etching using Polarization Sensitive Optical Coherence Tomography (PS-OCT). PS-OCT was used to acquire images of bovine enamel surfaces after exposure to laser irradiation at ablative fluence, acid-etching, and a surface softened dissolution model. The integrated reflectivity from lesion and the lesion depth were measured using PS-OCT. Samples were also sectioned for examination by Polarized Light Microscopy (PLM). PS-OCT images showed that acid-etching greatly accelerated the formation of subsurface lesions on both laser-irradiated and non-irradiated surfaces (P<0.05). A 37.5% phosphoric acid etch removed the laser modified enamel layer after 5–10 seconds. PMID:23539418

  12. Investigation of acid-etched CO2 laser ablated enamel surfaces using polarization sensitive optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Nahm, Byung J.; Kang, Hobin; Chan, Kenneth; Fried, Daniel

    2012-01-01

    A carbon dioxide laser operating at the highly absorbed wavelength of 9.3μm with a pulse duration of 10-15μs is ideally suited for caries removal and caries prevention. The enamel thermally modified by the laser has enhanced resistance to acid dissolution. This is an obvious advantage for caries prevention; however, it is often necessary to etch the enamel surface to increase adhesion to composite restorative materials and such surfaces may be more resistant to etching. The purpose of the study was to non-destructively measure the susceptibility of laser-ablated enamel surfaces to acid dissolution before and after acid-etching using Polarization Sensitive Optical Coherence Tomography (PS-OCT). PS-OCT was used to acquire images of bovine enamel surfaces after exposure to laser irradiation at ablative fluence, acid-etching, and a surface softened dissolution model. The integrated reflectivity from lesion and the lesion depth were measured using PS-OCT. Samples were also sectioned for examination by Polarized Light Microscopy (PLM). PS-OCT images showed that acid-etching greatly accelerated the formation of subsurface lesions on both laser-irradiated and non-irradiated surfaces (P<0.05). A 37.5% phosphoric acid etch removed the laser modified enamel layer after 5-10 seconds.

  13. Differential Absorption Measurements of Atmospheric Water Vapor with a Coherent Lidar at 2050.532 nm

    NASA Technical Reports Server (NTRS)

    Koch, Grady J.; Dharamsi, Amin; Davis, Richard E.; Petros, Mulugeta; McCarthy, John C.

    1999-01-01

    Wind and water vapor are two major factors driving the Earth's atmospheric circulation, and direct measurement of these factors is needed for better understanding of basic atmospheric science, weather forecasting, and climate studies. Coherent lidar has proved to be a valuable tool for Doppler profiling of wind fields, and differential absorption lidar (DIAL) has shown its effectiveness in profiling water vapor. These two lidar techniques are generally considered distinctly different, but this paper explores an experimental combination of the Doppler and DIAL techniques for measuring both wind and water vapor with an eye-safe wavelength based on a solid-state laser material. Researchers have analyzed and demonstrated coherent DIAL water vapor measurements at 10 micrometers wavelength based on CO2 lasers. The hope of the research presented here is that the 2 gm wavelength in a holmium or thulium-based laser may offer smaller packaging and more rugged operation that the CO2-based approach. Researchers have extensively modeled 2 um coherent lasers for water vapor profiling, but no published demonstration is known. Studies have also been made, and results published on the Doppler portion, of a Nd:YAG-based coherent DIAL operating at 1.12 micrometers. Eye-safety of the 1.12 micrometer wavelength may be a concern, whereas the longer 2 micrometer and 10 micrometer systems allow a high level of eyesafety.

  14. FY05 FM Dial Summary Report

    SciTech Connect

    Harper, Warren W.; Strasburg, Jana D.; Golovich, Elizabeth C.; Thompson, Jason S.; Stewart, Timothy L.; Batdorf, Michael T.

    2005-12-01

    Pacific Northwest National Laboratory's Infrared Sensors team is focused on developing methods for standoff detection of nuclear proliferation. In FY05, PNNL continued the development of the FM DIAL (frequency-modulated differential absorption LIDAR) experiment. Additional improvements to the FM DIAL trailer provided greater stability during field campaigns which made it easier to explore new locations for field campaigns. In addition to the Hanford Townsite, successful experiments were conducted at the Marine Science Laboratory in Sequim, WA and the Nevada Test Site located outside Las Vegas, NV. The range of chemicals that can be detected by FM DIAL has also increased. Prior to FY05, distributed feedback quantum cascade lasers (DFB-QCL) were used in the FM DIAL experiments. With these lasers, only simple chemicals with narrow (1-2 cm-1) absorption spectra, such as CO2 and N2O, could be detected. Fabry-Perot (FP) QC lasers have much broader spectra (20-40 cm-1) which allows for the detection of larger chemicals and a wider array of chemicals that can be detected. A FP-QCL has been characterized and used during initial studies detecting DMMP (dimethyl methylphosphonate).

  15. Differential absorption lidar for volcanic CO(2) sensing tested in an unstable atmosphere.

    PubMed

    Queisser, Manuel; Burton, Mike; Fiorani, Luca

    2015-03-01

    Motivated by the need for an extremely durable and portable instrument to quantify volcanic CO(2) we have produced a corresponding differential absorption lidar (DIAL). It was tested on a volcano (Vulcano, Italy), sensing a non-uniform volcanic CO(2) signal under turbulent atmospheric conditions. The measured CO(2) mixing ratio trend agrees qualitatively well but quantitatively poorly with a reference CO(2) measurement. The disagreement is not in line with the precision of the DIAL determined under conditions that largely exclude atmospheric effects. We show evidence that the disagreement is mainly due to atmospheric turbulence. We conclude that excluding noise associated with atmospheric turbulence, as commonly done in precision analysis of DIAL instruments, may largely underestimate the error of measured CO(2) concentrations in turbulent atmospheric conditions. Implications for volcanic CO(2) sensing with DIAL are outlined.

  16. Differential absorption lidar for volcanic CO(2) sensing tested in an unstable atmosphere.

    PubMed

    Queisser, Manuel; Burton, Mike; Fiorani, Luca

    2015-03-01

    Motivated by the need for an extremely durable and portable instrument to quantify volcanic CO(2) we have produced a corresponding differential absorption lidar (DIAL). It was tested on a volcano (Vulcano, Italy), sensing a non-uniform volcanic CO(2) signal under turbulent atmospheric conditions. The measured CO(2) mixing ratio trend agrees qualitatively well but quantitatively poorly with a reference CO(2) measurement. The disagreement is not in line with the precision of the DIAL determined under conditions that largely exclude atmospheric effects. We show evidence that the disagreement is mainly due to atmospheric turbulence. We conclude that excluding noise associated with atmospheric turbulence, as commonly done in precision analysis of DIAL instruments, may largely underestimate the error of measured CO(2) concentrations in turbulent atmospheric conditions. Implications for volcanic CO(2) sensing with DIAL are outlined. PMID:25836880

  17. IR DIAL performance modeling

    SciTech Connect

    Sharlemann, E.T.

    1994-07-01

    We are developing a DIAL performance model for CALIOPE at LLNL. The intent of the model is to provide quick and interactive parameter sensitivity calculations with immediate graphical output. A brief overview of the features of the performance model is given, along with an example of performance calculations for a non-CALIOPE application.

  18. Computer Simulation of Global Profiles of Carbon Dioxide Using a Pulsed, 2-Micron, Coherent-Detection, Column-Content DIAL System

    NASA Technical Reports Server (NTRS)

    Kavaya, Michael J.; Singh, Upendra N.; Koch, Grady J.; Yu, Jirong; Frehlich, Rod G.

    2009-01-01

    We present preliminary results of computer simulations of the error in measuring carbon dioxide mixing ratio profiles from earth orbit. The simulated sensor is a pulsed, 2-micron, coherent-detection lidar alternately operating on at least two wavelengths. The simulated geometry is a nadir viewing lidar measuring the column content signal. Atmospheric absorption is modeled using FASCODE3P software with the HITRAN 2004 absorption line data base. Lidar shot accumulation is employed up to the horizontal resolution limit. Horizontal resolutions of 50, 100, and 200 km are shown. Assuming a 400 km spacecraft orbit, the horizontal resolutions correspond to measurement times of about 7, 14, and 28 s. We simulate laser pulse-pair repetition frequencies from 1 Hz to 100 kHz. The range of shot accumulation is 7 to 2.8 million pulse-pairs. The resultant error is shown as a function of horizontal resolution, laser pulse-pair repetition frequency, and laser pulse energy. The effect of different on and off pulse energies is explored. The results are compared to simulation results of others and to demonstrated 2-micron operating points at NASA Langley.

  19. Preliminary DIAL model

    SciTech Connect

    Gentry, S.; Taylor, J.; Stephenson, D.

    1994-06-01

    A unique end-to-end LIDAR sensor model has been developed supporting the concept development stage of the CALIOPE UV DIAL and UV laser-induced-fluorescence (LIF) efforts. The model focuses on preserving the temporal and spectral nature of signals as they pass through the atmosphere, are collected by the optics, detected by the sensor, and processed by the sensor electronics and algorithms. This is done by developing accurate component sub-models with realistic inputs and outputs, as well as internal noise sources and operating parameters. These sub-models are then configured using data-flow diagrams to operate together to reflect the performance of the entire DIAL system. This modeling philosophy allows the developer to have a realistic indication of the nature of signals throughout the system and to design components and processing in a realistic environment. Current component models include atmospheric absorption and scattering losses, plume absorption and scattering losses, background, telescope and optical filter models, PMT (photomultiplier tube) with realistic noise sources, amplifier operation and noise, A/D converter operation, noise and distortion, pulse averaging, and DIAL computation. Preliminary results of the model will be presented indicating the expected model operation depicting the October field test at the NTS spill test facility. Indications will be given concerning near-term upgrades to the model.

  20. Radium dial workers

    SciTech Connect

    Rowland, R.E.; Lucas, H.F. Jr.

    1982-01-01

    The population of radium dial workers who were exposed to radium 30 to 50 years ago are currently being followed by the Center for Human Radiobiology at the Argonne National Laboratory. It is not clear that radium has induced additional malignancies in this population, other than the well-known bone sarcomas and head carcinomas, but elevated incidence rates for multiple myeloma and cancers of the colon, rectum, stomach, and breast suggest that radium might be involved. Continued follow-up of this population may resolve these questions. Finally, the question of the effect of fetal irradiation on the offspring of these women remains to be resolved. No evidence exists to suggest that any effects have occurred, but there is no question that a chronic irradiation of the developing fetus did take place. No formal follow-up of these children has yet been initiated.

  1. CO2-Neutral Fuels

    NASA Astrophysics Data System (ADS)

    Goede, Adelbert; van de Sanden, Richard

    2016-06-01

    Mimicking the biogeochemical cycle of System Earth, synthetic hydrocarbon fuels are produced from recycled CO2 and H2O powered by renewable energy. Recapturing CO2 after use closes the carbon cycle, rendering the fuel cycle CO2 neutral. Non-equilibrium molecular CO2 vibrations are key to high energy efficiency.

  2. Advances in High Energy Solid-State 2-micron Laser Transmitter Development for Ground and Airborne Wind and CO2 Measurements

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Yu, Jirong; Petros, Mulugeta; Chen, Songsheng; Kavaya, Michael J.; Trieu, Bo; Bai, Yingxin; Petzar, Paul; Modlin, Edward A.; Koch, Grady; Beyon, Jeffrey

    2010-01-01

    Sustained research efforts at NASA Langley Research Center (LaRC) during last fifteen years have resulted in a significant advancement in 2-micron diode-pumped, solid-state laser transmitter for wind and carbon dioxide measurement from ground, air and space-borne platform. Solid-state 2-micron laser is a key subsystem for a coherent Doppler lidar that measures the horizontal and vertical wind velocities with high precision and resolution. The same laser, after a few modifications, can also be used in a Differential Absorption Lidar (DIAL) system for measuring atmospheric CO2 concentration profiles. Researchers at NASA Langley Research Center have developed a compact, flight capable, high energy, injection seeded, 2-micron laser transmitter for ground and airborne wind and carbon dioxide measurements. It is capable of producing 250 mJ at 10 Hz by an oscillator and one amplifier. This compact laser transmitter was integrated into a mobile trailer based coherent Doppler wind and CO2 DIAL system and was deployed during field measurement campaigns. This paper will give an overview of 2-micron solid-state laser technology development and discuss results from recent ground-based field measurements.

  3. Wavelength measurement of tunable TEA CO2 laser

    NASA Astrophysics Data System (ADS)

    Qu, Yanchen; Ren, Deming; Hu, Xiaoyong; Liu, Fengmei; Zhang, Lili; Chen, Chunyu

    2005-01-01

    Due to their interesting physical and chemical parameters, tunable transversely excited atmospheric-pressure(TEA) CO2 lasers are widely utilized in scientific and industrial applications. The CO2 differential absorption lidar (DIAL) is an effective tool for remote measurement of pollutant gaseous concentration of the atmosphere over large areas. Many pollutant gases have strong absorption lines within the spectral range of CO2 laser wavelength tuning. In addition, the radiation of CO2 laser is well distributed in the atmosphere, coinciding with the "transparency window" of the atmosphere. Therefore the wavelength tunable TEA CO2 laser is an ideal optical source for DIAL. Most existing instruments for measuring the laser wavelength are only suitable for the measurement of continuous wave and stable frequency output. With the attempt of measuring the wavelength of pulsed TEA CO2 laser, an experimental setup is established which consists of two main portions, namely auto-scanning grating monochromator as the color dispersion system and Boxcar integrator. In the experiment of tuning TEA CO2 laser, the wavelength of CO2 laser is observed and measured by means of integrating method. The accuracy of measurement in the mid-infrared region attains 1nm.

  4. Profiling tropospheric water vapour with a coherent infrared differential absorption lidar: a sensitivity analysis

    NASA Astrophysics Data System (ADS)

    Baron, Philippe; Ishii, Shoken; Mizutani, Kohei; Itabe, Toshikazu; Yasui, Motoaki

    2012-11-01

    In the last decade the precision of coherent Doppler differential absorption lidar (DIAL) has been greatly improved in near and middle infra-red domains for measuring greenhouse gases such as CO2, CH4 and winds. The National Institute of Information and Communications Technology (NICT, Japan) has developed and is operating a CO2 and wind measuring ground-based coherent DIAL at 2.05 μm (4878 cm-1). The application of this technology from space is now considered. In this analysis we study the use of the NICT DIAL for profiling tropospheric water vapour from space. We present the methodology to select the spectral lines and summarized the results of the selected lines between 4000 and 7000 cm-1. The choice of the frequency offset, the pulse energy and repetition frequency are discussed. Retrieval simulations from the line at 4580 cm-1 (2.18 μm) suitable for the boundary layer and the stronger one at 5621 cm-1 (1.78 μm) for sounding the boundary layer and the middle troposphere, are shown.

  5. Development of a 2-micron Pulsed Differential Absorption Lidar for Atmospheric CO2 Concentration Measurement by Direct Detection Technique

    NASA Astrophysics Data System (ADS)

    Yu, J.; Singh, U. N.; Petros, M.; Bai, Y.

    2011-12-01

    Researchers at NASA Langley Research Center are developing a 2-micron Pulsed Differential Absorption Lidar instrument for ground and airborne measurements via direct detection method. This instrument will provide an alternate approach to measure atmospheric CO2 concentrations with significant advantages. A high energy pulsed approach provides high-precision measurement capbility by having high signal-to-noise level and unambiguously eliminates the contamination from aerosols and clouds that can bias the IPDA measurement. A key component of the CO2 DIAL system, transceiver, is an existing, airborne ready, robust hardware which can provide 250mJ at 10Hz with double pulse format specifically designed for DIAL instrument. The exact wavelengths of the transceiver are controlled by well defined CW seed laser source to provide the required injection source for generating on-and-off line wavelength pulses sequentially. The compact, rugged, highly reliable transceiver is based on the unique Ho:Tm:YLF high-energy 2-micron pulsed laser technology. All the optical mounts are custom designed and have space heritage. They are designed to be adjustable and lockable and hardened to withstand vibrations that can occur in airborne operation. For the direct detection lidar application, a large primary mirror size is preferred. A 14 inch diameter telescope will be developed for this program. The CO2 DIAL/IPDA system requires many electronic functions to operate. These include diode, RF, seed laser, and PZT drivers; injection seeding detection and control; detector power supplies; and analog inputs to sample various sensors. Under NASA Laser Risk Reduction Program (LRRP), a control unit Compact Laser Electronics (CLE), is developed for the controlling the coherent wind lidar transceiver. Significant modifications and additions are needed to update it for CO2 lidar controls. The data acquisition system was built for ground CO2 measurement demonstration. The software will be updated for

  6. CO2 -Responsive polymers.

    PubMed

    Lin, Shaojian; Theato, Patrick

    2013-07-25

    This Review focuses on the recent progress in the area of CO2 -responsive polymers and provides detailed descriptions of these existing examples. CO2 -responsive polymers can be categorized into three types based on their CO2 -responsive groups: amidine, amine, and carboxyl groups. Compared with traditional temperature, pH, or light stimuli-responsive polymers, CO2 -responsive polymers provide the advantage to use CO2 as a "green" trigger as well as to capture CO2 directly from air. In addition, the current challenges of CO2 -responsive polymers are discussed and the different solution methods are compared. Noteworthy, CO2 -responsive polymers are considered to have a prosperous future in various scientific areas.

  7. CO2 laser modeling

    NASA Technical Reports Server (NTRS)

    Johnson, Barry

    1992-01-01

    The topics covered include the following: (1) CO2 laser kinetics modeling; (2) gas lifetimes in pulsed CO2 lasers; (3) frequency chirp and laser pulse spectral analysis; (4) LAWS A' Design Study; and (5) discharge circuit components for LAWS. The appendices include LAWS Memos, computer modeling of pulsed CO2 lasers for lidar applications, discharge circuit considerations for pulsed CO2 lidars, and presentation made at the Code RC Review.

  8. Dial Access Libraries; Their Use and Utility

    ERIC Educational Resources Information Center

    Pearson, Karl M.; Bloch, Alice D.

    1974-01-01

    Medical dial access libraries (DALs) are an innovative information service for health professionals. This report is an evaluation of the general value, effectiveness, and efficiency of the dial access services. (Author/PG)

  9. Field Testing of a Two-Micron DIAL System for Profiling Atmospheric Carbon Dioxide

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Ismail, Syed; Koch, Grady J.; Diaz, Liza; Davis, Ken; Rubio, Manuel

    2010-01-01

    A 2-m DIAL system has been developed at NASA Langley Research Center through the NASA Instrument Incubator Program. The system utilizes a tunable 2-m pulsed laser and an IR phototransistor for the transmitter and the receiver, respectively. The system targets the CO2 absorption line R22 in the 2.05-m band. Field experiments were conducted at West Branch, Iowa, for evaluating the system for CO2 measurement by comparison with in-situ sensors. The CO2 in-situ sensors were located on the NOAA's WBI tower at 31, 99 and 379 m altitudes, besides the NOAA s aircraft was sampling at higher altitudes. Preliminary results demonstrated the capabilities of the DIAL system in profiling atmospheric CO2 using the 2-m wavelength. Results of these experiments will be presented and discussed.

  10. DIAL remotely sensed ethylene: featuring ozone-ethylene dynamics and correlation in presence of NOx

    NASA Astrophysics Data System (ADS)

    Gasmi, Taieb; Alonso, C. G.; Gonzalez Urena, Angel

    2003-12-01

    Ethylene has been monitored with a single-ended CO2-TEA laser-based DIAL system using a topographic target. The direct correlation between ozone concentration and ethylene/NOx ratio were demonstrated. Our work brings an additional confirmation of concurrent VOC/NOx and NOx-limited regimes in the generation of excess ozone.

  11. Proposal to Simultaneously Profile Wind and CO2 on Earth and Mars With 2-micron Pulsed Lidar Technologies

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Koch, Grady J.; Kavaya, Michael J.; Amzajerdian, Farzin; Ismail, Syed; Emmitt, David

    2005-01-01

    2-micron lidar technology has been in use and under continued improvement for many years toward wind measurements. But the 2-micron wavelength region is also rich in absorption lines of CO2 (and H2O to a lesser extent) that can be exploited with the differential absorption lidar (DIAL) technique to make species concentration measurements. A coherent detection receiver offers the possibility of making combined wind and DIAL measurements with wind derived from frequency shift of the backscatter spectrum and species concentration derived from power of the backscatter spectrum. A combined wind and CO2 measurement capability is of interest for applications on both Earth and Mars. CO2 measurements in the Earth atmosphere are of importance to studies of the global carbon cycle. Data on vertically-resolved CO2 profiles over large geographical observations areas are of particular interest that could potentially be made by deploying a lidar on an aircraft or satellite. By combining CO2 concentration with wind measurements an even more useful data product could be obtained in the calculation of CO2 flux. A challenge to lidar in this application is that CO2 concentration measurements must be made with a high level of precision and accuracy to better than 1%. The Martian atmosphere also presents wind and CO2 measurement problems that could be met with a combined DIAL/Doppler lidar. CO2 concentration in this scenario would be used to calculate atmospheric density since the Martian atmosphere is composed of 95% CO2. The lack of measurements of Mars atmospheric density in the 30-60 km range, dust storm formation and movements, and horizontal wind patterns in the 0-20 km range pose significant risks to aerocapture, and entry, descent, and landing of future robotic and human Mars missions. Systematic measurement of the Mars atmospheric density and winds will be required over several Mars years, supplemented with day-of-entry operational measurements. To date, there have been 5

  12. Development and Field Testing of a Continuously Operating CO2 Lidar Profiling System

    NASA Astrophysics Data System (ADS)

    Ismail, S.; Refaat, T.; Koch, G. J.; Davis, K.; Abedin, N. M.; Rubio, M. A.; Singh, U. N.

    2009-05-01

    A ground-based 2-micron DIAL system for profiling atmospheric CO2 was developed at NASA Langley Research Center (LaRC) under the NASA Instrument Incubator Program. This system leverages 2-micron laser technology developed under a number of NASA programs to develop new solid-state YLF laser technology that provides high pulse energy, tunable, wavelength-stabilized, and double-pulsed lasers that are operable over pre-selected temperature insensitive strong CO2 absorption lines suitable for profiling of lower tropospheric CO2. It also incorporates new high quantum efficiency, high gain, and relatively low noise phototransistors, and a new receiver/signal processor system to achieve high precision DIAL measurements. The DIAL system was integrated and tested at LaRC, and then incorporated in a field experiment for evaluation. The field experiment was conducted during June-July 2008, at West Branch, Iowa, which is located at the center of a domain rich in complementary CO2 measurements. The objective of the experiment was to evaluate the accuracy and precision of the system and its ability to distinguish contents between boundary layer and free troposphere. Therefore, the experiment was co-located with other CO2 measurement setups that aid the evaluation. These setups include NOAA WBI tower with in-situ CO2 sampling sensors at 31, 99 and 379 m altitudes; NOAA airborne CO2 profiling; and radiosondes for atmospheric temperature, pressure and relative humidity profiling at the site. The lidar operations included daytime CO2 measurements to sense the well-mixed atmospheric boundary layer and overlying troposphere; day-to-night and night-to-day transitions; and night observations to capture CO2 mixing ratio differences within the boundary layer. Measurements included atmospheric CO2 spatial and temporal profiles as well as column measurements using high altitude clouds. Examples of CO2 DIAL system capability and measurements from the field experiment will be presented.

  13. A pulsed CO2 Doppler lidar for boundary layer monitoring

    NASA Technical Reports Server (NTRS)

    Pearson, Guy N.

    1992-01-01

    A monostatic, master oscillator power amplifier (MOPA), CO2 pulsed Doppler lidar was constructed and tested. The system is compact (120 x 60 cm), operates at high pulse repetition rates (greater than 1 kHz) and is intended for simultaneous Doppler/Differential Absorption Lidar (DIAL) monitoring of the planetary boundary layer. Details of the system design, hard target calibrations, and aerosol returns are presented.

  14. CO2 blood test

    MedlinePlus

    Bicarbonate test; HCO3-; Carbon dioxide test; TCO2; Total CO2; CO2 test - serum ... Many medicines can interfere with blood test results. Your health care provider will tell you if you need to stop taking any medicines before you have this test. DO ...

  15. Outsourcing CO2 Emissions

    NASA Astrophysics Data System (ADS)

    Davis, S. J.; Caldeira, K. G.

    2009-12-01

    CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with consumption of goods and services in each country. This consumption-based emissions inventory differs from the production-based inventory because of imports and exports of goods and services that, either directly or indirectly, involved CO2 emissions. Using the latest available data and reasonable assumptions regarding trans-shipment of embodied carbon through third-party countries, we developed a global consumption-based CO2 emissions inventory and have calculated associated consumption-based energy and carbon intensities. We find that, in 2004, 24% of CO2 emissions are effectively outsourced to other countries, with much of the developed world outsourcing CO2 emissions to emerging markets, principally China. Some wealthy countries, including Switzerland and Sweden, outsource over half of their consumption-based emissions, with many northern Europeans outsourcing more than three tons of emissions per person per year. The United States is both a big importer and exporter of emissions embodied in trade, outsourcing >2.6 tons of CO2 per person and at the same time as >2.0 tons of CO2 per person are outsourced to the United States. These large flows indicate that CO2 emissions embodied in trade must be taken into consideration when considering responsibility for increasing atmospheric greenhouse gas concentrations.

  16. Synthetic Array Heterodyne Detection: Developments within the Caliope CO{sub 2} DIAL Program

    SciTech Connect

    Rehse, S.J.; Strauss, E.M.

    1995-09-01

    A new technique, Synthetic Array Heterodyne Detection, offers a wider field of view and improved signal to noise for coherent DIAL systems by reducing speckle interference. We have implemented a synthetic multi-pixel array using a CO{sub 2} laser on a single element HgCdTe photodiode.

  17. Assesment of dial data collection and analysis techniques

    NASA Technical Reports Server (NTRS)

    Browell, E. V.; Woods, P. T.

    1986-01-01

    The key issues in all areas of Differential Absorption Lidar (DIAL) data collection and analysis techniques were examined. This included consideration of the practical and theoretical limitations of DIAL and the range of possible DIAL measurements.

  18. Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) Aircraft Measurements of CO2

    NASA Technical Reports Server (NTRS)

    Christensen, Lance E.; Spiers, Gary D.; Menzies, Robert T.; Jacob, Joseph C.; Hyon, Jason

    2011-01-01

    The Jet Propulsion Laboratory Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) utilizes Integrated Path Differential Absorption (IPDA) at 2.05 microns to obtain CO2 column mixing ratios weighted heavily in the boundary layer. CO2LAS employs a coherent detection receiver and continuous-wave Th:Ho:YLF laser transmitters with output powers around 100 milliwatts. An offset frequency-locking scheme coupled to an absolute frequency reference enables the frequencies of the online and offline lasers to be held to within 200 kHz of desired values. We describe results from 2009 field campaigns when CO2LAS flew on the Twin Otter. We also describe spectroscopic studies aimed at uncovering potential biases in lidar CO2 retrievals at 2.05 microns.

  19. Development of Double and Triple-Pulsed 2-micron IPDA Lidars for Column CO2 Measurements

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Yu, Jirong; Petros, Mulugeta; Refaat, Tamer F.; Remus, Ruben G.; Reithmaier, Karl

    2015-01-01

    Carbon dioxide (CO2) is an important greenhouse gas that significantly contributes to the carbon cycle and globalradiation budget on Earth. CO2 role on Earth’s climate is complicated due to different interactions with various climatecomponents that include the atmosphere, the biosphere and the hydrosphere. Although extensive worldwide efforts formonitoring atmospheric CO2 through various techniques, including in-situ and passive sensors, are taking place highuncertainties exist in quantifying CO2 sources and sinks. These uncertainties are mainly due to insufficient spatial andtemporal mapping of the gas. Therefore it is required to have more rapid and accurate CO2 monitoring with higheruniform coverage and higher resolution. CO2 DIAL operating in the 2-µm band offer better near-surface CO2measurement sensitivity due to the intrinsically stronger absorption lines. For more than 15 years, NASA LangleyResearch Center (LaRC) contributed in developing several 2-?m CO2 DIAL systems and technologies. This paperfocuses on the current development of the airborne double-pulsed and triple-pulsed 2-?m CO2 integrated pathdifferential absorption (IPDA) lidar system at NASA LaRC. This includes the IPDA system development andintegration. Results from ground and airborne CO2 IPDA testing will be presented. The potential of scaling suchtechnology to a space mission will be addressed.

  20. Data and Information Access Link (DIAL)

    NASA Astrophysics Data System (ADS)

    Suresh, R.; Di, L.; McDonald, K.

    2001-05-01

    The Data and Information Access Link (DIAL) is a web based package of software tools for geospatial data storage, visualization and distribution. The DIAL software provides a web based easy to use software solution to small data producers to organize and distribute remote sensing data and metadata. DIAL system can handle heterogeneous types of remote sensing and field campaign data for Earth science applications. DIAL works with image data, grid, swath, and tabular, multidimensional array and point data. The DIAL system supports NASA's Earth Observing System and Data and Information System (EOSDIS) data standards HDF- EOS, Hierarchical Data Format (HDF), and network Common Data Format (netCDF). Data format translators are also available between HDF-EOS and Arc-Info, Geo-tiff, and shape formats. DIAL software works with data from the EOS Terra, LANDSAT 7, TRMM, SeaWiFS missions and many other types of legacy data from NASA. DIAL software is freely available for users. DIAL features: Catalog services: Spatial, temporal, and parameter-based search; Catalog search at inventory and directory levels; Automatic creation of metadata catalog; Supports ODBC/JDBC compatible databases for storing metadata/catalog; User-friendly Java search interface with query preview. Data services: On-line access to data and metadata; Single- and multi-granule subsetting and sub sampling based on array coordinates or record numbers; Single- and multi-granule sub setting and sub sampling based on geographic/map coordinates and physical parameters; Browse and dynamic/interactive visualization of data; Animation of time series or multi dimensional data; Interactive color composites of multi-spectral data; Overlay of coastal and political boundaries; On-line downloading of data in multiple formats; X-Y plotting for non-image data. DIAL can work as a standalone application or in a distributed environment. DIAL is integrated with NASA's Earth Science Data Gateway (EDG) providing support for the

  1. CO2-neutral fuels

    NASA Astrophysics Data System (ADS)

    Goede, A. P. H.

    2015-08-01

    The need for storage of renewable energy (RE) generated by photovoltaic, concentrated solar and wind arises from the fact that supply and demand are ill-matched both geographically and temporarily. This already causes problems of overcapacity and grid congestion in countries where the fraction of RE exceeds the 20% level. A system approach is needed, which focusses not only on the energy source, but includes conversion, storage, transport, distribution, use and, last but not least, the recycling of waste. Furthermore, there is a need for more flexibility in the energy system, rather than relying on electrification, integration with other energy systems, for example the gas network, would yield a system less vulnerable to failure and better adapted to requirements. For example, long-term large-scale storage of electrical energy is limited by capacity, yet needed to cover weekly to seasonal demand. This limitation can be overcome by coupling the electricity net to the gas system, considering the fact that the Dutch gas network alone has a storage capacity of 552 TWh, sufficient to cover the entire EU energy demand for over a month. This lecture explores energy storage in chemicals bonds. The focus is on chemicals other than hydrogen, taking advantage of the higher volumetric energy density of hydrocarbons, in this case methane, which has an approximate 3.5 times higher volumetric energy density. More importantly, it allows the ready use of existing gas infrastructure for energy storage, transport and distribution. Intermittent wind electricity generated is converted into synthetic methane, the Power to Gas (P2G) scheme, by splitting feedstock CO2 and H2O into synthesis gas, a mixture of CO and H2. Syngas plays a central role in the synthesis of a range of hydrocarbon products, including methane, diesel and dimethyl ether. The splitting is accomplished by innovative means; plasmolysis and high-temperature solid oxygen electrolysis. A CO2-neutral fuel cycle is

  2. Combined 2-micron Dial and Doppler Lidar: Application to the Atmosphere of Earth or Mars

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Koch, Grady J.; Ismail, Syed; Kavaya, Michael; Yu, Jirong; Wood, Sidney A.; Emmitt, G. David

    2006-01-01

    A concept is explored for combining the Doppler and DIAL techniques into a single, multifunctional instrument. Wind, CO2 concentration, and aerosol density can all be measured. Technology to build this instrument is described, including the demonstration of a prototype lidar. Applications are described for use in the Earth science. The atmosphere of Mars can also be studied, and results from a recently-developed simulation model of performance in the Martian atmosphere are presented.

  3. Advanced 2-micron Solid-state Laser for Wind and CO2 Lidar Applications

    NASA Technical Reports Server (NTRS)

    Yu, Jirong; Trieu, Bo C.; Petros, Mulugeta; Bai, Yingxin; Petzar, Paul J.; Koch, Grady J.; Singh, Upendra N.; Kavaya, Michael J.

    2006-01-01

    Significant advancements in the 2-micron laser development have been made recently. Solid-state 2-micron laser is a key subsystem for a coherent Doppler lidar that measures the horizontal and vertical wind velocities with high precision and resolution. The same laser, after a few modifications, can also be used in a Differential Absorption Lidar (DIAL) system for measuring atmospheric CO2 concentration profiles. The world record 2-micron laser energy is demonstrated with an oscillator and two amplifiers system. It generates more than one joule per pulse energy with excellent beam quality. Based on the successful demonstration of a fully conductive cooled oscillator by using heat pipe technology, an improved fully conductively cooled 2-micron amplifier was designed, manufactured and integrated. It virtually eliminates the running coolant to increase the overall system efficiency and reliability. In addition to technology development and demonstration, a compact and engineering hardened 2-micron laser is under development. It is capable of producing 250 mJ at 10 Hz by an oscillator and one amplifier. This compact laser is expected to be integrated to a lidar system and take field measurements. The recent achievements push forward the readiness of such a laser system for space lidar applications. This paper will review the developments of the state-of-the-art solid-state 2-micron laser.

  4. Direct measurements of collisionally broadened Raman linewidths of CO2 S-branch transitions

    NASA Astrophysics Data System (ADS)

    Roy, Sukesh; Hsu, Paul S.; Jiang, Naibo; Gord, Joseph R.; Kulatilaka, Waruna D.; Stauffer, Hans U.; Gord, James R.

    2013-01-01

    We report direct measurements of S-branch Raman-coherence lifetimes of CO2 resulting from CO2-CO2 and CO2-N2 collisions by employing time-resolved picosecond coherent anti-Stokes Raman scattering spectroscopy. The S-branch (ΔJ = +2) transitions of CO2 with rotational quantum number J = 0-52 were simultaneously excited using a broadband (˜5 nm) laser pulse with a full-width-at-half-maximum duration of ˜115 ps. The coherence lifetimes of CO2 for a pressure range of 0.05-1 atm were measured directly by probing the rotational coherence with a nearly transform-limited, 90-ps-long laser pulse. These directly measured Raman-coherence lifetimes, when converted to collisional linewidth broadening coefficients, differ from the previously reported broadening coefficients extracted from frequency-domain rotational Raman and infrared-absorption spectra and from theoretical calculations by 7%-25%.

  5. On-Line Wavelength Calibration of Pulsed Laser for CO2 Differential Absorption LIDAR

    NASA Astrophysics Data System (ADS)

    Xiang, Chengzhi; Ma, Xin; Han, Ge; Liang, Ailin; Gong, Wei

    2016-06-01

    Differential absorption lidar (DIAL) remote sensing is a promising technology for atmospheric CO2 detection. However, stringent wavelength accuracy and stability are required in DIAL system. Accurate on-line wavelength calibration is a crucial procedure for retrieving atmospheric CO2 concentration using the DIAL, particularly when pulsed lasers are adopted in the system. Large fluctuations in the intensities of a pulsed laser pose a great challenge for accurate on-line wavelength calibration. In this paper, a wavelength calibration strategy based on multi-wavelength scanning (MWS) was proposed for accurate on-line wavelength calibration of a pulsed laser for CO2 detection. The MWS conducted segmented sampling across the CO2 absorption line with appropriate number of points and range of widths by using a tunable laser. Complete absorption line of CO2 can be obtained through a curve fitting. Then, the on-line wavelength can be easily found at the peak of the absorption line. Furthermore, another algorithm called the energy matching was introduced in the MWS to eliminate the backlash error of tunable lasers during the process of on-line wavelength calibration. Finally, a series of tests was conducted to elevate the calibration precision of MWS. Analysis of tests demonstrated that the MWS proposed in this paper could calibrate the on-line wavelength of pulsed laser accurately and steadily.

  6. CO2 laser preionisation

    NASA Technical Reports Server (NTRS)

    Spiers, Gary D.

    1991-01-01

    The final report for work done during the reporting period of January 25, 1990 to January 24, 1991 is presented. A literature survey was conducted to identify the required parameters for effective preionization in TEA CO2 lasers and the methods and techniques for characterizing preionizers are reviewed. A numerical model of the LP-140 cavity was used to determine the cause of the transverse mode stability improvement obtained when the cavity was lengthened. The measurement of the voltage and current discharge pulses on the LP-140 were obtained and their subsequent analysis resulted in an explanation for the low efficiency of the laser. An assortment of items relating to the development of high-voltage power supplies is also provided. A program for analyzing the frequency chirp data files obtained with the HP time and frequency analyzer is included. A program to calculate the theoretical LIMP chirp is also included and a comparison between experiment and theory is made. A program for calculating the CO2 linewidth and its dependence on gas composition and pressure is presented. The program also calculates the number of axial modes under the FWHM of the line for a given resonator length. A graphical plot of the results is plotted.

  7. Development of a Pulsed 2-micron Laser Transmitter for CO2 Sensing from Space

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Yu, Jirong; Bai, Yingxin; Petros, Mulugeta; Menzies, Robert T.

    2011-01-01

    NASA Langley Research Center (LaRC), in collaboration with NASA Jet Propulsion Laboratory (JPL), is engaged in the development and demonstration of a highly efficient, versatile, 2-micron pulsed laser that can be used in a pulsed Differential Absorption Lidar (DIAL)/Integrated Path Differential Absorption (IPDA) instrument to make precise, high-resolution CO2 measurements to investigate sources, sinks, and fluxes of CO2. This laser transmitter will feature performance characteristics needed for an ASCENDS system that will be capable of delivering the CO2 measurement precision required by the Earth Science Decadal Survey (DS).

  8. CO2 Laser Market

    NASA Astrophysics Data System (ADS)

    Simonsson, Samuel

    1989-03-01

    It gives me a great deal of pleasure to introduce our final speaker of this morning's session for two reasons: First of all, his company has been very much in the news not only in our own community but in the pages of Wall Street Journal and in the world economic press. And, secondly, we would like to welcome him to our shores. He is a temporary resident of the United States, for a few months, forsaking his home in Germany to come here and help with the start up of a new company which we believe, probably, ranks #1 as the world supplier of CO2 lasers now, through the combination of former Spectra Physics Industrial Laser Division and Rofin-Sinar GMBH. Samuel Simonsson is the Chairman of the Board of Rofin-Sinar, Inc., here in the U.S. and managing director of Rofin-Sinar GMBH. It is a pleasure to welcome him.

  9. Optimization of A 2-Micron Laser Frequency Stabilization System for a Double-Pulse CO2 Differential Absorption Lidar

    NASA Technical Reports Server (NTRS)

    Chen, Songsheng; Yu, Jirong; Bai, Yingsin; Koch, Grady; Petros, Mulugeta; Trieu, Bo; Petzar, Paul; Singh, Upendra N.; Kavaya, Michael J.; Beyon, Jeffrey

    2010-01-01

    A carbon dioxide (CO2) Differential Absorption Lidar (DIAL) for accurate CO2 concentration measurement requires a frequency locking system to achieve high frequency locking precision and stability. We describe the frequency locking system utilizing Frequency Modulation (FM), Phase Sensitive Detection (PSD), and Proportional Integration Derivative (PID) feedback servo loop, and report the optimization of the sensitivity of the system for the feed back loop based on the characteristics of a variable path-length CO2 gas cell. The CO2 gas cell is characterized with HITRAN database (2004). The method can be applied for any other frequency locking systems referring to gas absorption line.

  10. Ar + CO2 and He + CO2 Plasmas in ASTRAL

    NASA Astrophysics Data System (ADS)

    Boivin, R. F.; Gardner, A.; Munoz, J.; Kamar, O.; Loch, S.

    2007-11-01

    Spectroscopy study of the ASTRAL helicon plasma source running Ar + CO2 and He + CO2 gas mixes is presented. ASTRAL produces plasmas with the following parameters: ne = 10^10 - 10^13 cm-3, Te = 2 - 10 eV and Ti = 0.03 - 0.5 eV, B-field <= 1.3 kGauss, rf power <= 2 kWatt. A 0.33 m scanning monochromator is used for this study. Using Ar + CO2 gas mixes, very different plasmas are observed as the concentration of CO2 is changed. At low CO2 concentration, the bluish plasma is essentially atomic and argon transitions dominate the spectra. Weak C I and O I lines are present in the 750 - 1000 nm range. At higher CO2 concentration, the plasma becomes essentially molecular and is characterized by intense, white plasma columns. Here, spectra are filled with molecular bands (CO2, CO2^+, CO and CO^+). Limited molecular dissociative excitation processes associated with the production of C I and O I emission are also observed. On the other hand, He + CO2 plasmas are different. Here, rf matches are only possible at low CO2 concentration. Under these conditions, the spectra are characterized by strong C I and O I transitions with little or no molecular bands. Strong dissociative processes observed in these plasmas can be link to the high Te associated with He plasmas. An analysis of the spectra with possible scientific and industrial applications will be presented.

  11. Mid-wave infrared DIAL noise phenomenology

    SciTech Connect

    Magnotta, F., Morris, J.R., Neuman, W.A., Scharlemann, E.T.

    1997-07-23

    LLNL has utilized optical parametric oscillator technology to develop and field a rapidly-tunable mid-wave infrared (MWIR) DIAL system. The system can be tuned at up to 1 KHz over the 3.3-3.8 micron spectral region, where hydrogen-bond stretching modes provide spectroscopic signatures for a wide variety of chemicals. We have fielded the DIAL system on the LLNL site with targets at horizontal ranges of up to 2 km. We have collected data on noise levels and correlations and their dependences on range, turbulence, and receiver aperture size. In this paper we describe some of the implications of this data for MWIR DIAL phenomenology. In particular, the interplay of turbulence and speckle to produce the observed noise fluctuations at short ranges (<500 m) is presented.

  12. Advanced Atmospheric Water Vapor DIAL Detection System

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Elsayed-Ali, Hani E.; DeYoung, Russell J. (Technical Monitor)

    2000-01-01

    Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface. This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto a small Printed Circuit Board (PCB) with minimal weight and power consumption. Comparing its measurements to an existing DIAL system for aerosol and water vapor profiling validated the detection system.

  13. Narrow Line-width, High-energy, 2-micron Laser for Coherent Wind Lidar

    NASA Astrophysics Data System (ADS)

    Singh, U.; Yu, J.

    2 micron solid-state lasers are the primary choice for coherent Doppler wind detection. As wind lidars, they are used for wake vortex and clear air turbulence detection providing air transport safety. In addition, 2 micron lasers are one of the candidates for CO2 detection lidars. The rich CO2 absorption line around 2 micron, combined with the long upper state lifetime, has made Ho based 2 micron lasers a viable candidate for CO2 sensing DIAL instrument. As a transmitter for a coherent wind lidar, this laser has stringent spectral line width and beam quality requirements. The laser architecture is composed of a seed laser, a ring oscillator, and a double pass amplifier. The seed laser is a single longitudinal mode with a line width of 13 KHz. The 100mJ class oscillator is stretched to 3 meters to accommodate the line-width requirement without compromising the range resolution of the instrument. The amplifier is double passed to produce greater than 300mJ energy. This system is hardened for ground as well as airborne applications.

  14. Is CO2 ice permanent?

    NASA Technical Reports Server (NTRS)

    Lindner, Bernhard Lee

    1992-01-01

    Carbon dioxide ice has been inferred to exist at the south pole in summertime, but Earth based measurements in 1969 of water vapor in the Martian atmosphere suggest that all CO2 ice sublined from the southern polar cap and exposed underlying water ice. This implies that the observed summertime CO2 ice is of recent origin. It appears possible to construct an energy balance model that maintains seasonal CO2 ice at the south pole year round and still reasonably simulates the polar cap regression and atmospheric pressure data. This implies that the CO2 ice observed in the summertime south polar cap could be seasonal in origin, and that minor changes in climate could cause CO2 ice to completely vanish, as would appear to have happened in 1969. However, further research remains before it is certain whether the CO2 ice observed in the summertime south polar cap is seasonal or is part of a permanent reservoir.

  15. India Co2 Emissions

    NASA Astrophysics Data System (ADS)

    Sharan, S.; Diffenbaugh, N. S.

    2010-12-01

    created a balance in between the “developed” and developing countries. If India was producing the same amounts of emissions per capita as the it would have a total of 20 billion metric tons of CO2 emissions annually.

  16. Co2 geological sequestration

    SciTech Connect

    Xu, Tianfu

    2004-11-18

    Human activities are increasingly altering the Earth's climate. A particular concern is that atmospheric concentrations of carbon dioxide (CO{sub 2}) may be rising fast because of increased industrialization. CO{sub 2} is a so-called ''greenhouse gas'' that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO{sub 2} will make the arctic warmer, which would melt glaciers and raise sea levels. Evidence suggests that climate change may already have begun to affect ecosystems and wildlife around the world. Some animal species are moving from one habitat to another to adapt to warmer temperatures. Future warming is likely to exceed the ability of many species to migrate or adjust. Human production of CO{sub 2} from fossil fuels (such as at coal-fired power plants) is not likely to slow down soon. It is urgent to find somewhere besides the atmosphere to put these increased levels of CO{sub 2}. Sequestration in the ocean and in soils and forests are possibilities, but another option, sequestration in geological formations, may also be an important solution. Such formations could include depleted oil and gas reservoirs, unmineable coal seams, and deep saline aquifers. In many cases, injection of CO2 into a geological formation can enhance the recovery of hydrocarbons, providing value-added byproducts that can offset the cost of CO{sub 2} capture and sequestration. Before CO{sub 2} gas can be sequestered from power plants and other point sources, it must be captured. CO{sub 2} is also routinely separated and captured as a by-product from industrial processes such as synthetic ammonia production, H{sub 2} production, and limestone calcination. Then CO{sub 2} must be compressed into liquid form and transported to the geological sequestration site. Many power plants and other large emitters of CO{sub 2} are located near geological formations that are amenable to CO{sub 2} sequestration.

  17. 47 CFR 51.215 - Dialing parity: Cost recovery.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 3 2013-10-01 2013-10-01 false Dialing parity: Cost recovery. 51.215 Section... (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.215 Dialing parity: Cost recovery. (a) A LEC may recover the incremental costs necessary for the implementation of toll dialing...

  18. 47 CFR 51.213 - Toll dialing parity implementation plans.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 3 2013-10-01 2013-10-01 false Toll dialing parity implementation plans. 51... parity implementation plans. (a) A LEC must file a plan for providing intraLATA toll dialing parity... dialing parity within a state until the implementation plan has been approved by the appropriate...

  19. 47 CFR 51.213 - Toll dialing parity implementation plans.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 3 2012-10-01 2012-10-01 false Toll dialing parity implementation plans. 51... parity implementation plans. (a) A LEC must file a plan for providing intraLATA toll dialing parity... dialing parity within a state until the implementation plan has been approved by the appropriate...

  20. 47 CFR 51.215 - Dialing parity: Cost recovery.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Dialing parity: Cost recovery. 51.215 Section... (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.215 Dialing parity: Cost recovery. (a) A LEC may recover the incremental costs necessary for the implementation of toll dialing...

  1. 47 CFR 51.213 - Toll dialing parity implementation plans.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Toll dialing parity implementation plans. 51... parity implementation plans. (a) A LEC must file a plan for providing intraLATA toll dialing parity... dialing parity within a state until the implementation plan has been approved by the appropriate...

  2. 47 CFR 51.215 - Dialing parity: Cost recovery.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 3 2014-10-01 2014-10-01 false Dialing parity: Cost recovery. 51.215 Section... (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.215 Dialing parity: Cost recovery. (a) A LEC may recover the incremental costs necessary for the implementation of toll dialing...

  3. 47 CFR 51.209 - Toll dialing parity.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 3 2012-10-01 2012-10-01 false Toll dialing parity. 51.209 Section 51.209... Obligations of All Local Exchange Carriers § 51.209 Toll dialing parity. (a) A LEC shall implement throughout each state in which it offers telephone exchange service intraLATA and interLATA toll dialing...

  4. 47 CFR 51.209 - Toll dialing parity.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Toll dialing parity. 51.209 Section 51.209... Obligations of All Local Exchange Carriers § 51.209 Toll dialing parity. (a) A LEC shall implement throughout each state in which it offers telephone exchange service intraLATA and interLATA toll dialing...

  5. 47 CFR 51.209 - Toll dialing parity.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 3 2014-10-01 2014-10-01 false Toll dialing parity. 51.209 Section 51.209... Obligations of All Local Exchange Carriers § 51.209 Toll dialing parity. (a) A LEC shall implement throughout each state in which it offers telephone exchange service intraLATA and interLATA toll dialing...

  6. 47 CFR 51.205 - Dialing parity: General.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 3 2012-10-01 2012-10-01 false Dialing parity: General. 51.205 Section 51.205... Obligations of All Local Exchange Carriers § 51.205 Dialing parity: General. A local exchange carrier (LEC) shall provide local and toll dialing parity to competing providers of telephone exchange service...

  7. 47 CFR 51.213 - Toll dialing parity implementation plans.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 3 2014-10-01 2014-10-01 false Toll dialing parity implementation plans. 51... parity implementation plans. (a) A LEC must file a plan for providing intraLATA toll dialing parity... dialing parity within a state until the implementation plan has been approved by the appropriate...

  8. 47 CFR 51.205 - Dialing parity: General.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Dialing parity: General. 51.205 Section 51.205... Obligations of All Local Exchange Carriers § 51.205 Dialing parity: General. A local exchange carrier (LEC) shall provide local and toll dialing parity to competing providers of telephone exchange service...

  9. 47 CFR 51.215 - Dialing parity: Cost recovery.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Dialing parity: Cost recovery. 51.215 Section... (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.215 Dialing parity: Cost recovery. (a) A LEC may recover the incremental costs necessary for the implementation of toll dialing...

  10. 47 CFR 51.205 - Dialing parity: General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 3 2013-10-01 2013-10-01 false Dialing parity: General. 51.205 Section 51.205... Obligations of All Local Exchange Carriers § 51.205 Dialing parity: General. A local exchange carrier (LEC) shall provide local and toll dialing parity to competing providers of telephone exchange service...

  11. 47 CFR 51.213 - Toll dialing parity implementation plans.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Toll dialing parity implementation plans. 51... parity implementation plans. (a) A LEC must file a plan for providing intraLATA toll dialing parity... dialing parity within a state until the implementation plan has been approved by the appropriate...

  12. 47 CFR 51.209 - Toll dialing parity.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 3 2013-10-01 2013-10-01 false Toll dialing parity. 51.209 Section 51.209... Obligations of All Local Exchange Carriers § 51.209 Toll dialing parity. (a) A LEC shall implement throughout each state in which it offers telephone exchange service intraLATA and interLATA toll dialing...

  13. 47 CFR 51.205 - Dialing parity: General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Dialing parity: General. 51.205 Section 51.205... Obligations of All Local Exchange Carriers § 51.205 Dialing parity: General. A local exchange carrier (LEC) shall provide local and toll dialing parity to competing providers of telephone exchange service...

  14. 47 CFR 51.215 - Dialing parity: Cost recovery.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 3 2012-10-01 2012-10-01 false Dialing parity: Cost recovery. 51.215 Section... (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.215 Dialing parity: Cost recovery. (a) A LEC may recover the incremental costs necessary for the implementation of toll dialing...

  15. 47 CFR 51.209 - Toll dialing parity.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Toll dialing parity. 51.209 Section 51.209... Obligations of All Local Exchange Carriers § 51.209 Toll dialing parity. (a) A LEC shall implement throughout each state in which it offers telephone exchange service intraLATA and interLATA toll dialing...

  16. 47 CFR 51.205 - Dialing parity: General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 3 2014-10-01 2014-10-01 false Dialing parity: General. 51.205 Section 51.205... Obligations of All Local Exchange Carriers § 51.205 Dialing parity: General. A local exchange carrier (LEC) shall provide local and toll dialing parity to competing providers of telephone exchange service...

  17. A Preliminary Study of CO2 Flux Measurements by Lidar

    NASA Technical Reports Server (NTRS)

    Gibert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, T.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

    2008-01-01

    A mechanistic understanding of the global carbon cycle requires quantification of terrestrial ecosystem CO2 fluxes at regional scales. In this paper, we analyze the potential of a Doppler DIAL system to make flux measurements of atmospheric CO2 using the eddy-covariance and boundary layer budget methods and present results from a ground based experiment. The goal of this study is to put CO2 flux point measurements in a mesoscale context. In June 2007, a field experiment combining a 2-m Doppler Heterodyne Differential Absorption Lidar (HDIAL) and in-situ sensors of a 447-m tall tower (WLEF) took place in Wisconsin. The HDIAL measures simultaneously: 1) CO2 mixing ratio, 2) atmosphere structure via aerosol backscatter and 3) radial velocity. We demonstrate how to synthesize these data into regional flux estimates. Lidar-inferred fluxes are compared with eddy-covariance fluxes obtained in-situ at 396m AGL from the tower. In cases where the lidar was not yet able to measure the fluxes with acceptable precision, we discuss possible modifications to improve system performance.

  18. CO2 interaction with geomaterials.

    SciTech Connect

    Guthrie, George D.; Al-Saidi, Wissam A.; Jordan, Kenneth D.; Voora, Vamsee, K.; Romanov, Vyacheslav N.; Lopano, Christina L; Myshakin, Eugene M.; Hur, Tae Bong; Warzinski, Robert P.; Lynn, Ronald J.; Howard, Bret H.; Cygan, Randall Timothy

    2010-09-01

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas No.3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2

  19. Development of tunable high pressure CO2 laser for lidar measurements of pollutants and wind velocities

    NASA Technical Reports Server (NTRS)

    Levine, J. S.; Guerra, M.; Javan, A.

    1980-01-01

    The problem of laser energy extraction at a tunable monochromatic frequency from an energetic high pressure CO2 pulsed laser plasma, for application to remote sensing of atmospheric pollutants by Differential Absorption Lidar (DIAL) and of wind velocities by Doppler Lidar, was investigated. The energy extraction principle analyzed is based on transient injection locking (TIL) at a tunable frequency. Several critical experiments for high gain power amplification by TIL are presented.

  20. Development of Laser, Detector, and Receiver Systems for an Atmospheric CO2 Lidar Profiling System

    NASA Technical Reports Server (NTRS)

    Ismail, Syed; Koch, Grady; Abedin, Nurul; Refaat, Tamer; Rubio, Manuel; Singh, Upendra

    2008-01-01

    A ground-based Differential Absorption Lidar (DIAL) is being developed with the capability to measure range-resolved and column amounts of atmospheric CO2. This system is also capable of providing high-resolution aerosol profiles and cloud distributions. It is being developed as part of the NASA Earth Science Technology Office s Instrument Incubator Program. This three year program involves the design, development, evaluation, and fielding of a ground-based CO2 profiling system. At the end of a three-year development this instrument is expected to be capable of making measurements in the lower troposphere and boundary layer where the sources and sinks of CO2 are located. It will be a valuable tool in the validation of NASA Orbiting Carbon Observatory (OCO) measurements of column CO2 and suitable for deployment in the North American Carbon Program (NACP) regional intensive field campaigns. The system can also be used as a test-bed for the evaluation of lidar technologies for space-application. This DIAL system leverages 2-micron laser technology developed under a number of NASA programs to develop new solid-state laser technology that provides high pulse energy, tunable, wavelength-stabilized, and double-pulsed lasers that are operable over pre-selected temperature insensitive strong CO2 absorption lines suitable for profiling of lower tropospheric CO2. It also incorporates new high quantum efficiency, high gain, and relatively low noise phototransistors, and a new receiver/signal processor system to achieve high precision DIAL measurements.

  1. Convergent Cenozoic CO2 history

    NASA Astrophysics Data System (ADS)

    Royer, D. L.; Beerling, D. J.

    2011-12-01

    The quality and quantity of Cenozoic CO2 records have increased significantly in the last decade. Gains in quality have come primarily from a fuller accounting of confounding factors; examples include soil respiration rates in the pedogenic carbonate method, alkalinity and seawater δ11B in the boron method, and cell size in the alkenone phytoplankton method. Previously, variability across Cenozoic CO2 estimates in a given time period sometimes exceeded an order of magnitude, but through these improvements variability has been reduced to a factor of two or less. Further improvements in the record can probably be facilitated by more robust quantification of statistical error, generation of CO2 estimates at single locations from multiple methods, and cross-calibration with Pleistocene ice-core CO2 records (Beerling & Royer, 2011, Nature Geoscience 4: 418-420). An improved Cenozoic CO2 record offers opportunities for better understanding Earth system processes. We provide one example related to climate sensitivity. We find a significant relationship between CO2 radiative forcing and global temperature during the Cenozoic, even after accounting for forcings related to solar evolution and paleogeographic changes. Although the calculations are based on simple assumptions and should be taken as provisional, the mean Cenozoic climate sensitivity (3 °C or higher per CO2 doubling) is similar to or higher than calculations for the present-day (~3 °C per CO2 doubling).

  2. Leaves: Elevated CO2 levels

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Burning fossil fuels and land use changes such as deforestation and urbanization have led to a dramatic rise in the concentration of carbon dioxide (CO2) in the atmosphere since the onset of the Industrial Revolution. The highly dilute CO2 from the atmosphere enters plant leaves where it is concentr...

  3. CO2 Sequestration short course

    SciTech Connect

    DePaolo, Donald J.; Cole, David R; Navrotsky, Alexandra; Bourg, Ian C

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  4. Turbulent CO2 Flux Measurements by Lidar: Length Scales, Results and Comparison with In-Situ Sensors

    NASA Technical Reports Server (NTRS)

    Gilbert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

    2009-01-01

    The vertical CO2 flux in the atmospheric boundary layer (ABL) is investigated with a Doppler differential absorption lidar (DIAL). The instrument was operated next to the WLEF instrumented tall tower in Park Falls, Wisconsin during three days and nights in June 2007. Profiles of turbulent CO2 mixing ratio and vertical velocity fluctuations are measured by in-situ sensors and Doppler DIAL. Time and space scales of turbulence are precisely defined in the ABL. The eddy-covariance method is applied to calculate turbulent CO2 flux both by lidar and in-situ sensors. We show preliminary mean lidar CO2 flux measurements in the ABL with a time and space resolution of 6 h and 1500 m respectively. The flux instrumental errors decrease linearly with the standard deviation of the CO2 data, as expected. Although turbulent fluctuations of CO2 are negligible with respect to the mean (0.1 %), we show that the eddy-covariance method can provide 2-h, 150-m range resolved CO2 flux estimates as long as the CO2 mixing ratio instrumental error is no greater than 10 ppm and the vertical velocity error is lower than the natural fluctuations over a time resolution of 10 s.

  5. New ground-based lidar enables volcanic CO2 flux measurements.

    PubMed

    Aiuppa, Alessandro; Fiorani, Luca; Santoro, Simone; Parracino, Stefano; Nuvoli, Marcello; Chiodini, Giovanni; Minopoli, Carmine; Tamburello, Giancarlo

    2015-09-01

    There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2-the most reliable gas precursor to an eruption-has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest.

  6. New ground-based lidar enables volcanic CO2 flux measurements.

    PubMed

    Aiuppa, Alessandro; Fiorani, Luca; Santoro, Simone; Parracino, Stefano; Nuvoli, Marcello; Chiodini, Giovanni; Minopoli, Carmine; Tamburello, Giancarlo

    2015-01-01

    There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2-the most reliable gas precursor to an eruption-has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest. PMID:26324399

  7. New ground-based lidar enables volcanic CO2 flux measurements

    PubMed Central

    Aiuppa, Alessandro; Fiorani, Luca; Santoro, Simone; Parracino, Stefano; Nuvoli, Marcello; Chiodini, Giovanni; Minopoli, Carmine; Tamburello, Giancarlo

    2015-01-01

    There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2—the most reliable gas precursor to an eruption—has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest. PMID:26324399

  8. Tuning the dials of Synthetic Biology

    PubMed Central

    Arpino, James A. J.; Hancock, Edward J.; Anderson, James; Barahona, Mauricio; Stan, Guy-Bart V.; Polizzi, Karen

    2013-01-01

    Synthetic Biology is the ‘Engineering of Biology’ – it aims to use a forward-engineering design cycle based on specifications, modelling, analysis, experimental implementation, testing and validation to modify natural or design new, synthetic biology systems so that they behave in a predictable fashion. Motivated by the need for truly plug-and-play synthetic biological components, we present a comprehensive review of ways in which the various parts of a biological system can be modified systematically. In particular, we review the list of ‘dials’ that are available to the designer and discuss how they can be modelled, tuned and implemented. The dials are categorized according to whether they operate at the global, transcriptional, translational or post-translational level and the resolution that they operate at. We end this review with a discussion on the relative advantages and disadvantages of some dials over others. PMID:23704788

  9. Airborne water vapor DIAL system development

    NASA Technical Reports Server (NTRS)

    Higdon, Noah S.; Browell, Edward V.; Ponsardin, Patrick; Grossmann, Benoist E.

    1990-01-01

    A differential absorption lidar (DIAL) system developed at NASA Langley Research Center for the remote measurement of atmospheric H2O and aerosols from an aircraft is briefly discussed. This DIAL system utilizes a Nd:YAG laser-pumped dye laser as the off-line transmitter and a narrowband, tunable Alexandrite laser as the on-line transmitter. A 1-m monochromator and a multipass absorption cell are used to position the on-line laser to the center of the H2O line. The receiver system has a 14-in. diameter, f/7 Celestron telescope to collect the backscattered laser light and focus in into the detector optics. Return signals are converted to electrical signals by the optical detector and are digitalized and stored on magnetic tape. The results of fligh tests of the system are shown.

  10. Correlation of DIAL Ozone Observations with Lightning

    NASA Technical Reports Server (NTRS)

    Peterson, Harold S.; Kuang, Shi; Koshak, William J.; Newchurch, Mike

    2014-01-01

    The purpose of this project is to see whether ozone maxima measured by the DIfferential Absorption Lidar (DIAL) instrument in Huntsville, AL may be traced back to lightning events occurring 24-48 hours beforehand. The methodology is to start with lidar measurements of ozone from DIAL. The HYbrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model is then used to determine the origin of these ozone maxima 24-48 hours prior. Data from the National Lightning Detection Network (NLDN) are used to examine the presence/absence of lightning along the trajectory. This type of analysis suggests that lightning-produced NOx may be responsible for some of the ozone maxima over Huntsville.

  11. Correlation of DIAL Ozone Observations with Lightning

    NASA Technical Reports Server (NTRS)

    Peterson, Harold; Kuang, Shi; Koshak, William; Newchurch, Michael

    2013-01-01

    The purpose of this project is to see whether ozone maxima measured by the DIfferential Absorption Lidar (DIAL) instrument in Huntsville, AL may be traced back to lightning events occurring 24- 48 hours beforehand. The methodology is to start with lidar measurements of ozone from DIAL as well as ozonesonde measurements. The HYbrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model is then used to determine the origin of these ozone maxima 24-48 hours prior. Data from the National Lightning Detection Network (NLDN) are used to examine the presence/absence of lightning along the trajectory. This type of analysis suggests that lightning-produced NOx may be responsible for some of the ozone maxima over Huntsville.

  12. D0 Cryogenic Auto Dialing Alarm System

    SciTech Connect

    Markely, D.; /Fermilab

    1992-08-03

    The Automatic Dialing system purchased by D0 is intended to help make the D0 cryogenic system operate unattended by cryogenic operating personnel. The auto dialer is completely programmable and is voice synthesized. The auto dialer was purchased with 32 bistable inputs, but is expandable to 64 bistable inputs with the purchase of more electronic cards at an approximate cost of $260 per card (8 bistable inputs). The auto dialer also has the capability for analog inputs, analog outputs, and bistable outputs none of which D0 uses or intends to use. The auto dialer can be called on its operating phone line to describe current alarms with the proper password. The Auto Dialer can dial lab extensions, lab pagers, and any number outside the lab. It cannot dial a long distance pager. The auto dialer monitors alarms and alarm conditions via the T1565 PLC, upon an alarm condition it initiates a phone calling sequence of preprogrammed lists with assigned priorities. When someone is reached, the auto dialer describes the individual alarm it is calling for, by a preprogrammed set of words for that individual alarm, spoken by a female voice. The called person then has a chance to acknowledge the alarm over the telephone, if the alarm is not acknowledged the auto dialer will disconnect and call the next person on the list. The auto dialer will continue to cycle through the list until it is acknowledged, reset, or the alarm condition no longer exists.

  13. Lidar/DIAL detection of bomb factories

    NASA Astrophysics Data System (ADS)

    Fiorani, Luca; Puiu, Adriana; Rosa, Olga; Palucci, Antonio

    2013-10-01

    One of the aims of the project BONAS (BOmb factory detection by Networks of Advanced Sensors) is to develop a lidar/DIAL (differential absorption lidar) to detect precursors employed in the manufacturing of improvised explosive devices (IEDs). At first, a spectroscopic study has been carried out: the infrared (IR) gas phase spectrum of acetone, one of the more important IED precursors, has been procured from available databases and checked with cell measurements. Then, the feasibility of a lidar/DIAL for the detection of acetone vapors has been shown in laboratory, simulating the experimental conditions of a field campaign. Eventually, having in mind measurements in a real scenario, an interferent study has been performed, looking for all known compounds that share with acetone IR absorption in the spectral band selected for its detection. Possible interfering species were investigated, simulating both urban and industrial atmospheres and limits of acetone detection in both environments were identified. This study confirmed that a lidar/DIAL can detect low concentration of acetone at considerable distances.

  14. Potential of satellite CO2 data to infer CO2 fluxes, using atmospheric inversion: influence of data uncertainty correlations

    NASA Astrophysics Data System (ADS)

    Montandon, V.; Peylin, P.; Bousquet, P.; Ciais, P.; Breon, F.-M.

    2003-04-01

    Knowledge of present surface sources and sinks of atmospheric CO2 is crucial to quantify the future man-induced green-house effect. Measurements of radiation from space potentially offer denser samplings of CO2 column amount, both in time and space than in situ measurements. This could allow in turn to decrease the uncertainties of CO2 flux estimates, depending on the achievable precision of CO2 retrievals from space, and on the removal of any spatially coherent bias. In the framework of the COCO project, shaped to take advantage of the sooncoming or present satellite missions, we enriched some investigations about the satellite observations potential to improve the atmospheric CO2 sinks and sources knowledge. Our particular study dealt with the introduction of spatial correlations between the individual measurement errors of CO2 column amount, to inverstigate possible coherent biases between satellite data. One year of pseudo-data was generated according to the CARBOSAT project instrumental and orbital characteristics. These individual data were then grouped month by month onto the grid of the LMDZ transport model. The classical independance assumption made in all priors study about the measurement errors lead to a large decrease of the final satellite data uncertainty. However, spatially coherent bias would bring correlated data uncertainties, a feature that would largely affect the results. We quantified here the influence of these correlations on the retrieved CO2 flux uncertainties. Several transport model grids (regular / non regular) were used to aggregate the individual measurements, and their influence is also discussed. Such results could also be applied to other reactive chemical species like CH4, CO, ...

  15. Design and development of a compact lidar/DIAL system for aerial surveillance of urban areas

    NASA Astrophysics Data System (ADS)

    Gaudio, P.; Gelfusa, M.; Malizia, A.; Richetta, M.; Antonucci, A.; Ventura, P.; Murari, A.; Vega, J.

    2013-10-01

    Recently surveying large areas in an automatic way, for early detection of harmful chemical agents, has become a strategic objective of defence and public health organisations. The Lidar-Dial techniques are widely recognized as a cost-effective alternative to monitor large portions of the atmosphere but, up to now, they have been mainly deployed as ground based stations. The design reported in this paper concerns the development of a Lidar-Dial system compact enough to be carried by a small airplane and capable of detecting sudden releases in air of harmful and/or polluting substances. The proposed approach consists of continuous monitoring of the area under surveillance with a Lidar type measurement. Once a significant increase in the density of backscattering substances is revealed, it is intended to switch to the Dial technique to identify the released chemicals and to determine its concentration. In this paper, the design of the proposed system is described and the simulations carried out to determine its performances are reported. For the Lidar measurements, commercially available Nd- YAG laser sources have already been tested and their performances, in combination with avalanche photodiodes, have been experimentally verified to meet the required specifications. With regard to the DIAL measurements, new compact CO2 laser sources are being investigated. The most promising candidate presents an energy per pulse of about 50 mJ typical, sufficient for a range of at least 500m. The laser also provides the so called "agile tuning" option that allows to quickly tune the wavelength. To guarantee continuous, automatic surveying of large areas, innovative solutions are required for the data acquisition, self monitoring of the system and data analysis. The results of the design, the simulations and some preliminary tests illustrate the potential of the chosen, integrated approach.

  16. CO2 Sequestration Crosswell Monitoring

    NASA Astrophysics Data System (ADS)

    Morency, C.; Luo, Y.; Tromp, J.

    2010-12-01

    Geologic sequestration of CO2, a green house gas, represents an effort to reduce the large amount of CO2 generated as a by-product of fossil fuels combustion and emitted into the atmosphere. This process of sequestration involves CO2 storage deep underground into highly permeable porous media sealed by caprock. "4D seismics" is a natural non-intrusive monitoring technique which involves 3D time-lapse seismic surveys. The success of monitoring CO2 movement relies upon a proper description of the physics of the problem. We realize time-lapse migrations comparing acoustic, elastic (with or without Gassmann's formulae), and poroelastic simulations of 4D seismic imaging. This approach highlights the influence of using different physical theories on interpreting seismic data, and, more importantly, on extracting the CO2 signature from the seismic wave field. We investigate various types of inversions using (1) P-wave traveltimes, (2) P- & S-wave traveltimes and (3) P- & S-wave traveltimes and amplitudes. Simulations are performed using a spectral-element method, and finite-frequency sensitivity kernels, used in the non-linear iterative inversions, are calculated based on an adjoint method. Biot's equations are implemented in the forward and adjoint simulations to account for poroelastic effects.

  17. ACCURACY OF CO2 SENSORS

    SciTech Connect

    Fisk, William J.; Faulkner, David; Sullivan, Douglas P.

    2008-10-01

    Are the carbon dioxide (CO2) sensors in your demand controlled ventilation systems sufficiently accurate? The data from these sensors are used to automatically modulate minimum rates of outdoor air ventilation. The goal is to keep ventilation rates at or above design requirements while adjusting the ventilation rate with changes in occupancy in order to save energy. Studies of energy savings from demand controlled ventilation and of the relationship of indoor CO2 concentrations with health and work performance provide a strong rationale for use of indoor CO2 data to control minimum ventilation rates1-7. However, this strategy will only be effective if, in practice, the CO2 sensors have a reasonable accuracy. The objective of this study was; therefore, to determine if CO2 sensor performance, in practice, is generally acceptable or problematic. This article provides a summary of study methods and findings ? additional details are available in a paper in the proceedings of the ASHRAE IAQ?2007 Conference8.

  18. Airborne 2-Micron Double-Pulsed Integrated Path Differential Absorption Lidar for Column CO2 Measurement

    NASA Technical Reports Server (NTRS)

    Singh, Upendra N.; Yu, Jirong; Petros, Mulugeta; Refaat, Tamer F.; Remus, Ruben G.; Fay, James J.; Reithmaier, Karl

    2014-01-01

    Double-pulse 2-micron lasers have been demonstrated with energy as high as 600 millijouls and up to 10 Hz repetition rate. The two laser pulses are separated by 200 microseconds and can be tuned and locked separately. Applying double-pulse laser in DIAL system enhances the CO2 measurement capability by increasing the overlap of the sampled volume between the on-line and off-line. To avoid detection complicity, integrated path differential absorption (IPDA) lidar provides higher signal-to-noise ratio measurement compared to conventional range-resolved DIAL. Rather than weak atmospheric scattering returns, IPDA rely on the much stronger hard target returns that is best suited for airborne platforms. In addition, the IPDA technique measures the total integrated column content from the instrument to the hard target but with weighting that can be tuned by the transmitter. Therefore, the transmitter could be tuned to weight the column measurement to the surface for optimum CO2 interaction studies or up to the free troposphere for optimum transport studies. Currently, NASA LaRC is developing and integrating a double-Pulsed 2-micron direct detection IPDA lidar for CO2 column measurement from an airborne platform. The presentation will describe the development of the 2-micron IPDA lidar system and present the airborne measurement of column CO2 and will compare to in-situ measurement for various ground target of different reflectivity.

  19. Update on CO2 emissions

    SciTech Connect

    Friedingstein, P.; Houghton, R.A.; Marland, Gregg; Hackler, J.; Boden, Thomas A; Conway, T.J.; Canadell, J.G.; Raupach, Mike; Ciais, Philippe; Le Quere, Corrine

    2010-12-01

    Emissions of CO2 are the main contributor to anthropogenic climate change. Here we present updated information on their present and near-future estimates. We calculate that global CO2 emissions from fossil fuel burning decreased by 1.3% in 2009 owing to the global financial and economic crisis that started in 2008; this is half the decrease anticipated a year ago1. If economic growth proceeds as expected2, emissions are projected to increase by more than 3% in 2010, approaching the high emissions growth rates that were observed from 2000 to 20081, 3, 4. We estimate that recent CO2 emissions from deforestation and other land-use changes (LUCs) have declined compared with the 1990s, primarily because of reduced rates of deforestation in the tropics5 and a smaller contribution owing to forest regrowth elsewhere.

  20. The CO2nnect activities

    NASA Astrophysics Data System (ADS)

    Eugenia, Marcu

    2014-05-01

    Climate change is one of the biggest challenges we face today. A first step is the understanding the problem, more exactly what is the challenge and the differences people can make. Pupils need a wide competencies to meet the challenges of sustainable development - including climate change. The CO2nnect activities are designed to support learning which can provide pupils the abilities, skills, attitudes and awareness as well as knowledge and understanding of the issues. The project "Together for a clean and healthy world" is part of "The Global Educational Campaign CO2nnect- CO2 on the way to school" and it was held in our school in the period between February and October 2009. It contained a variety of curricular and extra-curricular activities, adapted to students aged from 11 to 15. These activities aimed to develop in students the necessary skills to understanding man's active role in improving the quality of the environment, putting an end to its degrading process and to reducing the effects of climate changes caused by the human intervention in nature, including transport- a source of CO2 pollution. The activity which I propose can be easily adapted to a wide range of age groups and linked to the curricula of many subjects: - Investigate CO2 emissions from travel to school -Share the findings using an international database -Compare and discuss CO2 emissions -Submit questions to a climate- and transport expert -Partner with other schools -Meet with people in your community to discuss emissions from transport Intended learning outcomes for pupils who participate in the CO2nnect campaign are: Understanding of the interconnected mobility- and climate change issue climate change, its causes and consequences greenhouse-gas emissions from transport and mobility the interlinking of social, environmental, cultural and economic aspects of the local transport system how individual choices and participation can contribute to creating a more sustainable development

  1. Automated alexandrite transmitter for airborne DIAL experiments

    NASA Technical Reports Server (NTRS)

    Degnan, John J.

    1988-01-01

    An account is given of the performance characteristics and development status of an automated dual alexandrite laser transmitter that is to be carried aloft by NASA's ER-2 research aircraft for water vapor DIAL experiments; these efforts are part of NASA's Lidar Atmospheric Sensing Experiment (LASE). The LASE transmitter encompasses control unit, thermal unit, and two lamp driver unit subsystems. Major reductions in system size and weight relative to commercially available alexandrite lasers were necessary; a total weight of only 330 lbs has been achieved. Attention is given to subsystem flight test results.

  2. Reducing cement's CO2 footprint

    USGS Publications Warehouse

    van Oss, Hendrik G.

    2011-01-01

    The manufacturing process for Portland cement causes high levels of greenhouse gas emissions. However, environmental impacts can be reduced by using more energy-efficient kilns and replacing fossil energy with alternative fuels. Although carbon capture and new cements with less CO2 emission are still in the experimental phase, all these innovations can help develop a cleaner cement industry.

  3. Development of a laser remote sensing instrument to measure sub-aerial volcanic CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Queisser, Manuel; Burton, Mike

    2016-04-01

    A thorough quantification of volcanic CO2 fluxes would lead to an enhanced understanding of the role of volcanoes in the geological carbon cycle. This would enable a more subtle understanding of human impact on that cycle. Furthermore, variations in volcanic CO2 emissions are a key to understanding volcanic processes such as eruption phenomenology. However, measuring fluxes of volcanic CO2 is challenging as volcanic CO2 concentrations are modest compared with the ambient CO2 concentration (~400 ppm) . Volcanic CO2 quickly dilutes with the background air. For Mt. Etna (Italy), for instance, 1000 m downwind from the crater, dispersion modelling yields a signal of ~4 ppm only. It is for this reason that many magmatic CO2 concentration measurements focus on in situ techniques, such as direct sampling Giggenbach bottles, chemical sensors, IR absorption spectrometers or mass spectrometers. However, emission rates are highly variable in time and space. Point measurements fail to account for this variability. Inferring 1-D or 2-D gas concentration profiles, necessary to estimate gas fluxes, from point measurements may thus lead to erroneous flux estimations. Moreover, in situ probing is time consuming and, since many volcanoes emit toxic gases and are dangerous as mountains, may raise safety concerns. In addition, degassing is often diffuse and spatially extended, which makes a measurement approach with spatial coverage desirable. There are techniques that allow to indirectly retrieve CO2 fluxes from correlated SO2 concentrations and fluxes. However, they still rely on point measurements of CO2 and are prone to errors of SO2 fluxes due to light dilution and depend on blue sky conditions. Here, we present a new remote sensing instrument, developed with the ERC project CO2Volc, which measures 1-D column amounts of CO2 in the atmosphere with sufficient sensitivity to reveal the contribution of magmatic CO2. Based on differential absorption LIDAR (DIAL) the instrument measures

  4. Excitation of CO2/+/ by electron impact on CO2

    NASA Technical Reports Server (NTRS)

    Mentall, J. E.; Coplan, M. A.; Kushlis, R. J.

    1973-01-01

    Consideration of a discrepancy concerning the correct value of the cross section for excitation of the CO2(+) B state by electron impact on CO2. It is suggested that the reason for the disparate results obtained by various authors for the B state can be traced to a calibration error due to scattered light. In particular, the tungsten filament lamps used in the experiments cited have very low intensity at wavelengths below 3000 A where the B state emissions occur, so that even a small amount of scattered light in the spectrometer will produce a large error in the measured cross section. In a remeasurement of the cross section for excitation of the B state at an energy of 150 eV it was found that at 2900 A the scattered light signal, if uncorrected for, would introduce an error of about 50%.

  5. 47 CFR 51.207 - Local dialing parity.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Local dialing parity. 51.207 Section 51.207 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.207 Local dialing parity. A LEC shall permit...

  6. 47 CFR 51.207 - Local dialing parity.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Local dialing parity. 51.207 Section 51.207 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.207 Local dialing parity. A LEC shall permit...

  7. 47 CFR 51.207 - Local dialing parity.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 3 2012-10-01 2012-10-01 false Local dialing parity. 51.207 Section 51.207 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.207 Local dialing parity. A LEC shall permit...

  8. 47 CFR 51.207 - Local dialing parity.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 3 2014-10-01 2014-10-01 false Local dialing parity. 51.207 Section 51.207 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.207 Local dialing parity. A LEC shall permit...

  9. 47 CFR 51.207 - Local dialing parity.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 3 2013-10-01 2013-10-01 false Local dialing parity. 51.207 Section 51.207 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) INTERCONNECTION Obligations of All Local Exchange Carriers § 51.207 Local dialing parity. A LEC shall permit...

  10. High pulse repetition frequency, multiple wavelength, pulsed CO2 lidar system for atmospheric transmission and target reflectance measurements

    NASA Astrophysics Data System (ADS)

    Ben-David, Avishai; Emery, Silvio L.; Gotoff, Steven W.; D'Amico, Francis M.

    1992-07-01

    A multiple wavelength, pulsed CO2 lidar system operating at a pulse repetition frequency of 200 Hz and permitting the random selection of CO2 laser wavelengths for each laser pulse is presented. This system was employed to measure target reflectance and atmospheric transmission by using laser pulse bursts consisting of groups with as many as 16 different wavelengths at a repetition rate of 12 Hz. The wavelength tuning mechanism of the transversely excited atmospheric laser consists of a stationary grating and a flat mirror controlled by a galvanometer. Multiple wavelength, differential absorption lidar (DIAL) measurements reduce the effects of differential target reflectance and molecular absorption interference. Examples of multiwavelength DIAL detection for ammonia and water vapor show the dynamic interaction between these two trace gases. Target reflectance measurements for maple trees in winter and autumn are presented.

  11. High pulse repetition frequency, multiple wavelength, pulsed CO(2) lidar system for atmospheric transmission and target reflectance measurements.

    PubMed

    Ben-David, A; Emery, S L; Gotoff, S W; D'Amico, F M

    1992-07-20

    A multiple wavelength, pulsed CO(2) lidar system operating at a pulse repetition frequency of 200 Hz and permitting the random selection of CO(2) laser wavelengths for each laser pulse is presented. This system was employed to measure target reflectance and atmospheric transmission by using laser pulse bursts consisting of groups with as many as 16 different wavelengths at a repetition rate of 12 Hz. The wavelength tuning mechanism of the transversely excited atmospheric laser consists of a stationary grating and a flat mirror controlled by a galvanometer. Multiple wavelength, differential absorption lidar (DIAL) measurements reduce the effects of differential target reflectance and molecular absorption interference. Examples of multiwavelength DIAL detection for ammonia and water vapor show the dynamic interaction between these two trace gases. Target reflectance measurements for maple trees in winter and autumn are presented. PMID:20725406

  12. CO2 Acquisition Membrane (CAM)

    NASA Technical Reports Server (NTRS)

    Mason, Larry W.; Way, J. Douglas; Vlasse, Marcus

    2003-01-01

    The objective of CAM is to develop, test, and analyze thin film membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The membranes are targeted toward In Situ Resource Utilization (ISRU) applications that will operate in extraterrestrial environments and support future unmanned and human space missions. A primary application is the Sabatier Electrolysis process that uses Mars atmosphere CO2 as raw material for producing water, oxygen, and methane for rocket fuel and habitat support. Other applications include use as an inlet filter to collect and concentrate Mars atmospheric argon and nitrogen gases for habitat pressurization, and to remove CO2 from breathing gases in Closed Environment Life Support Systems (CELSS). CAM membrane materials include crystalline faujasite (FAU) zeolite and rubbery polymers such as silicone rubber (PDMS) that have been shown in the literature and via molecular simulation to favor adsorption and permeation of CO2 over nitrogen and argon. Pure gas permeation tests using commercial PDMS membranes have shown that both CO2 permeance and the separation factor relative to other gases increase as the temperature decreases, and low (Delta)P(Sub CO2) favors higher separation factors. The ideal CO2/N2 separation factor increases from 7.5 to 17.5 as temperature decreases from 22 C to -30 C. For gas mixtures containing CO2, N2, and Ar, plasticization decreased the separation factors from 4.5 to 6 over the same temperature range. We currently synthesize and test our own Na(+) FAU zeolite membranes using standard formulations and secondary growth methods on porous alumina. Preliminary tests with a Na(+) FAU membrane at 22 C show a He/SF6 ideal separation factor of 62, exceeding the Knudsen diffusion selectivity by an order of magnitude. This shows that the membrane is relatively free from large defects and associated non-selective (viscous flow) transport

  13. Estimation of continuous anthropogenic CO2 using CO2, CO, δ13C(CO2) and Δ14C(CO2)

    NASA Astrophysics Data System (ADS)

    Vardag, S. N.; Gerbig, C.; Janssens-Maenhout, G.; Levin, I.

    2015-07-01

    We investigate different methods for estimating anthropogenic CO2 using modelled continuous atmospheric concentrations of CO2 alone, as well as CO2 in combination with the surrogate tracers CO, δ13C(CO2) and Δ14C(CO2). These methods are applied at three hypothetical stations representing rural, urban and polluted conditions. We find that independent of the tracer used, an observation-based estimate of continuous anthropogenic CO2 is not feasible at rural measurement sites due to the low signal to noise ratio of anthropogenic CO2 estimates at such settings. At urban and polluted sites, potential future continuous Δ14C(CO2) measurements with a precision of 5 ‰ or better are most promising for anthropogenic CO2 determination (precision ca. 10-20%), but the insensitivity against CO2 contributions from biofuel emissions may reduce its accuracy in the future. Other tracers, such as δ13C(CO2) and CO could provide an accurate and already available alternative if all CO2 sources in the catchment area are well characterized with respect to their isotopic signature and CO to anthropogenic CO2 ratio. We suggest a strategy for calibrating these source characteristics on an annual basis using precise Δ14C(CO2) measurements on grab samples. The precision of anthropogenic CO2 determination using δ13C(CO2) is largely determined by the measurement precision of δ13C(CO2) and CO2. The precision when using the CO-method is mainly limited by the variation of natural CO sources and CO sinks. At present, continuous anthropogenic CO2 could be determined using the tracers δ13C(CO2) and/or CO with a precision of about 30 %, a mean bias of about 10 % and without significant diurnal discrepancies. This allows significant improvement, validation and bias reduction of highly resolved emission inventories using atmospheric observation and regional modelling.

  14. Surface Condensation of CO2 onto Kaolinite

    SciTech Connect

    Schaef, Herbert T.; Glezakou, Vassiliki Alexandra; Owen, Antionette T.; Ramprasad, Sudhir; Martin, Paul F.; McGrail, B. Peter

    2014-02-11

    The fundamental adsorption behavior of gaseous and supercritical carbon dioxide (CO2) onto poorly crystalline kaolinite (KGa-2) at conditions relevant to geologic sequestration has been investigated using a quartz crystal microbalance (QCM) and density functional theory (DFT) methods. The QCM data indicated linear adsorption of CO2 (0-0.3 mmol CO2/g KGa-2) onto the kaolinite surface up through the gaseous state (0.186 g/cm3). However in the supercritical region, CO2 adsorption increases dramatically, reaching a peak (0.9-1.0 mmol CO2/g KGa-2) near 0.43 g/cm3, before declining rapidly to surface adsorption values equivalent or below gaseous CO2. This adsorption profile was not observed with He or N2. Comparative density functional studies of CO2 interactions with kaolinite surface models rule out CO2 intercalation and confirm that surface adsorption is favored up to approximately 0.35 g/cm3 of CO2, showing distorted T-shaped CO2-CO2 clustering, typical of supercritical CO2 aggregation over the surface as the density increases. Beyond this point, the adsorption energy gain for any additional CO2 becomes less than the CO2 interaction energy (~0.2 eV) in the supercritical medium resulting in overall desorption of CO2 from the kaolinite surface.

  15. Multiplex CARS for simultaneous measurement of temperature and CO2 and H2 concentrations in a combustion environment

    NASA Astrophysics Data System (ADS)

    Singh, J. P.; Yueh, F. Y.

    1991-05-01

    Simultaneous temperature and CO2 concentration measurements with multiplex coherent anti-Stokes Raman scattering (CARS) spectra of CO2 were performed. CARS spectra of pure CO2 and various mixtures of CO2 and N2 in a furnace were recorded at various temperatures to test the computer code that simulates CO2 CARS spectra using recent spectroscopic constants. The temperatures obtained from the CO2 CARS spectra were in good agreement with thermocouple temperature measurements. However, the CO2 concentrations cannot be accurately extracted from these spectra. H2 pure rotational lines S(4) and S(5) were found in the CO2 CARS spectra of a hydrocarbon flame. CARS spectra of preanalyzed mixtures of N2, CO2, and H2 in a furnace were recorded to investigate the feasibility of inferring the H2 concentration from these spectra.

  16. Sorption enhanced CO2 methanation.

    PubMed

    Borgschulte, Andreas; Gallandat, Noris; Probst, Benjamin; Suter, Riccardo; Callini, Elsa; Ferri, Davide; Arroyo, Yadira; Erni, Rolf; Geerlings, Hans; Züttel, Andreas

    2013-06-28

    The transformation from the fatuous consumption of fossil energy towards a sustainable energy circle is most easily marketable by not changing the underlying energy carrier but generating it from renewable energy. Hydrocarbons can be principally produced from renewable hydrogen and carbon dioxide collected by biomass. However, research is needed to increase the energetic and economic efficiency of the process. We demonstrate the enhancement of CO2 methanation by sorption enhanced catalysis. The preparation and catalytic activity of sorption catalysts based on Ni particles in zeolites is reported. The functioning of the sorption catalysis is discussed together with the determination of the reaction mechanism, providing implications for new ways in catalysis. PMID:23673365

  17. Preliminary results of a lidar-dial integrated system for the automatic detection of atmospheric pollutants

    NASA Astrophysics Data System (ADS)

    Gaudio, P.; Gelfusa, M.; Richetta, M.

    2012-11-01

    In the last decades, atmospheric pollution in urban and industrial areas has become a major concern of both developed and developing countries. In this context, surveying relative large areas in an automatic way is an increasing common objective of public health organisations. The Lidar-Dial techniques are widely recognized as a cost-effective approach to monitor large portions of the atmosphere and, for example, they have been successful applied to the early detection of forest fire. The studies and preliminary results reported in this paper concern the development of an integrated Lidar-Dial system able to detect sudden releases in air of harmful and polluting substances. The propose approach consists of continuous monitoring of the area under surveillance with a Lidar type measurement (by means of a low cost system). Once a significant increase in the density of a pollutant is revealed, the Dial technique is used to identify the released chemicals. In this paper, the specifications of the proposed station are discussed. The most stringent requirement is the need for a very compact system with a range of at least 600-700 m. Of course, the optical wavelengths must be in an absolute eye-safe range for humans. A conceptual design of the entire system is described and the most important characteristic of the main elements are provided. In particular the capability of the envisaged laser sources, Nd:YAG and CO2 lasers, to provide the necessary quality of the measurements is carefully assessed. Since the detection of dangerous substances must be performed in an automatic way, the monitoring station will be equipped with an adequate set of control and communication devices for independent autonomous operation. The results of the first preliminary tests illustrate the potential of the chosen approach.

  18. Atmospheric CO2 Reconstructions from Polar Ice: What Do High-Resolution CO2 Records and δ13CO2 Analyses Tell Us about Past Climate and Global Carbon Cycle Processes?

    NASA Astrophysics Data System (ADS)

    Schmitt, J.; Eggleston, S.; Marcott, S. A.; Brook, E.; Chappellaz, J. A.; Köhler, P.; Joos, F.; Fischer, H.

    2014-12-01

    Today, a monitoring network measures atmospheric CO2 at high temporal and spatial resolution. Atmospheric transport models then calculate regional CO2 source and sink fluxes. Prior to this instrumental period, archived air, firn air, and air trapped in polar ice are the only direct atmospheric archives to reconstruct past CO2 changes. Only ice from Antarctica allows reliable CO2 measurements, either from classical ice cores or outcropping ice, while Greenland records are subject to in situ production. They provide high-resolution and high-precision CO2 reconstructions up to 800,000 years back in time. Ice core records have revealed an intimate connection between CO2 variations and major changes in Earth's climate and have fundamentally shaped the community's view of the global carbon cycle. Knowing the concentration of past atmospheric CO2 and the other greenhouse gases is key to provide the radiative forcing for climate simulations. Ice core reconstructions broadly fulfilled this task. On the contrary, we are far from a coherent understanding of the mechanisms driving these changes. Analyzing phase relations between CO2, other ice-core derived species, and proxies from marine sediment cores allow for the identification of factors likely responsible for the observed CO2 changes. Specifically, the strength of the Atlantic overturning circulation and Southern Ocean upwelling are thought to be key players. However, the observed CO2 changes cannot uniquely be related to a specific process. Here, stable carbon isotope analysis on CO2 extracted from ice provides additional constraints as any process leads to isotope fractionation of the reservoir. Analytical progress during the last decade affords us with a growing data set on this long-awaited parameter. This presentation provides a state-of-the-art overview on ice-based CO2 and its carbon isotopic signature focusing both on the long-term orbital changes as well as rapid changes documented during the last deglaciation.

  19. Fire hazards and CO2 laser resurfacing.

    PubMed

    Wald, D; Michelow, B J; Guyuron, B; Gibb, A A

    1998-01-01

    The purpose of this study was to investigate the fire risk of laser resurfacing in the presence of supplemental oxygen. This study aims at defining safety parameters of variables such as laser energy level, oxygen flow rate, and "oxygen to laser target distance" when oxygen is delivered through a nasal cannula or nasopharyngeal tube. The typical operating room environment was simulated in the laboratory using the Yucatan minipig animal model. The energy source was a Coherent Ultrapulse CO2 laser. It was found that combustion did not occur at laser settings of 500 mJ, 50 W, 100 kHz, and a density of 5, used in conjunction with an oxygen flow rate of 6 liter/minute with the target area as close as 0.5 cm to the oxygen delivery. A total of 400 computer pattern generator treatments were delivered using this energy setting without observation of any combustion (p < 0.001). This provides evidence that while using even somewhat high laser settings and oxygen flow rate, laser induced fires can be avoided. We conclude that use of the laser in the presence of oxygen is safe, provided the target area is free of combustible fuels. Despite this assurance, laser mishaps are serious because they lead to both morbidity and mortality. It is our recommendation that close attention be constantly paid to all details, thus reducing the hazard potential of laser energy on local factors in an oxygen-rich environment. PMID:9427936

  20. Passive CO2 concentration in higher plants.

    PubMed

    Sage, Rowan F; Khoshravesh, Roxana

    2016-06-01

    Photorespiratory limitations on C3 photosynthesis are substantial in warm, low CO2 conditions. To compensate, certain plants evolved mechanisms to actively concentrate CO2 around Rubisco using ATP-supported CO2 pumps such as C4 photosynthesis. Plants can also passively accumulate CO2 without additional ATP expenditure by localizing the release of photorespired and respired CO2 around Rubisco that is diffusively isolated from peripheral air spaces. Passive accumulation of photorespired CO2 occurs when glycine decarboxylase is localized to vascular sheath cells in what is termed C2 photosynthesis, and through forming sheaths of chloroplasts around the periphery of mesophyll cells. The peripheral sheaths require photorespired CO2 to re-enter chloroplasts where it can be refixed. Passive accumulation of respiratory CO2 is common in organs such as stems, fruits and flowers, due to abundant heterotrophic tissues and high diffusive resistance along the organ periphery. Chloroplasts within these organs are able to exploit this high CO2 to reduce photorespiration. CO2 concentration can also be enhanced passively by channeling respired CO2 from roots and rhizomes into photosynthetic cells of stems and leaves via lacunae, aerenchyma and the xylem stream. Through passive CO2 concentration, C3 species likely improved their carbon economy and maintained fitness during episodes of low atmospheric CO2.

  1. Selection of an averaging technique by simulation study of a DIAL system for toxic agents monitoring

    NASA Astrophysics Data System (ADS)

    Dudeja, Jai Paul; Jindal, Mukesh Kumar; Veerabuthiran, S.

    2007-10-01

    Differential Absorption Lidar (DIAL) is a very effective technique for standoff detection of various toxic agents in the atmosphere. The Lidar backscattered signal received usually has poor signal to noise (SNR) ratio. In order to improve the SNR, statistical averaging over a number of laser pulses is employed. The aim of the present work is to select a particular statistical averaging technique, which is most suitable in removing the noise in Lidar return signals. The DIAL system considered here uses laser transmitters based on OPO based (2-5 μm) and TEA CO2 (9-11μm) lasers. Eight commonly used chemical warfare agents including five nerve agents and three blister agents have been considered here as examples of toxic agents. A Graphical User Interface (GUI) software has been developed in LabVIEW to simulate return signals mixed with the expected noise levels. A toxic agent cloud with a given thickness and concentration has been assumed to be detected in the ambient atmospheric conditions at various ranges up to 5 Km. Data for 200 pulses per agent was stored in the computer memory. Various known statistical averaging techniques were used and number concentrations of particular agent have been computed and compared with ideal Lidar return signal values. This exercise was repeated for all the eight agents and based on the results obtained; the most suitable averaging technique has been selected.

  2. Frequency agile OPO-based transmitters for multiwavelength DIAL

    SciTech Connect

    Velsko, S.P.; Ruggiero, A.; Herman, M.

    1996-09-01

    We describe a first generation mid-infrared transmitter with pulse to pulse frequency agility and both wide and narrow band capability. This transmitter was used to make multicomponent Differential Absorption LIDAR (DIAL) measurements in the field.

  3. Frequency agile OPO-based transmitters for multiwavelength DIAL

    SciTech Connect

    Velsko, S.P.; Ruggiero, A.; Herman, M.

    1996-09-01

    We describe a first generation mid-infrared transmitter with pulse-to- pulse frequency agility and both wide and narrow band capability. This transmitter was used to make multicomponent DIAL measurements in the field.

  4. Educational Materials Development in Primary Science: Dial Thermometer Instructional Unit

    ERIC Educational Resources Information Center

    Franks, Frank L.; Huff, Roger

    1976-01-01

    Described in the fourth of a series of articles dealing with primary science instructional materials for visually handicapped students, is a field test (with 61 Ss in grades 2 to 4) of a dial thermometer instructional unit. (IM)

  5. 18. OPERATOR'S SIDE OF 48' MILL STAND SHOWING DIALS, VERTICAL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    18. OPERATOR'S SIDE OF 48' MILL STAND SHOWING DIALS, VERTICAL ROLL SCREWDOWN, AND VIEW THROUGH HOUSING TO PINION STAND. Martin Stupich, Photographer, 1989. - U.S. Steel Homestead Works, 48" Plate Mill, Along Monongahela River, Homestead, Allegheny County, PA

  6. Optical properties of heusler alloys Co2FeSi, Co2FeAl, Co2CrAl, and Co2CrGa

    NASA Astrophysics Data System (ADS)

    Shreder, E. I.; Svyazhin, A. D.; Belozerova, K. A.

    2013-11-01

    The results of an investigation of optical properties and the calculations of the electronic structure of Co2FeSi, Co2FeAl, Co2CrAl, and Co2CrGa Heusler alloys are presented. The main focus of our attention is the study of the spectral dependence of the real part (ɛ1) and imaginary part (ɛ2) of the dielectric constant in the range of wavelengths λ = 0.3-13 μm using the ellipsometric method. An anomalous behavior of the optical conductivity σ(ω) has been found in the infrared range in the Co2CrAl and Co2CrGa alloys, which differs substantially from that in the Co2FeSi and Co2FeAl alloys. The results obtained are discussed based on the calculations of the electronic structure.

  7. Setting up a mobile Lidar (DIAL) system for detecting chemical warfare agents

    NASA Astrophysics Data System (ADS)

    Kavosh Tehrani, M.; Mohammad, M. Malek; Jaafari, E.; Mobashery, A.

    2015-03-01

    The mobile light detection and ranging DIAL system of Malek Ashtar University of Technology has been developed for the detection of chemical warfare agents whose absorption wavelengths are in the range of 9.2-10.8 μm tunable CO2 lasers of the system. In this paper, this system is first described and then ammonia detection is analyzed experimentally. Also, experimental results of detecting a sarin agent simulant, dimethyl-methyl phosphonate (DMMP), are presented. The power levels received from different ranges to detect specific concentrations of NH3 and DMMP have been measured and debated. The primary test results with a 150 ns clipped pulse width by passive pinhole plasma shutter indicate that the system is capable of monitoring several species of pollutants in the range of about 1 km, with a 20 m spatial and 2 min temporal resolution.

  8. Advanced Detector and Waveform Digitizer for Water Vapor DIAL Systems

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Luck, William S., Jr.; DeYoung, Russell J.

    1998-01-01

    Measurement of atmospheric water vapor has become a major requirement for understanding moist-air processes. Differential absorption lidar (DIAL) is a technique best suited for the measurement of atmospheric water vapor. NASA Langley Research Center is continually developing improved DIAL systems. One aspect of current development is focused on the enhancement of a DIAL receiver by applying state-of-the-art technology in building a new compact detection system that will be placed directly on the DIAL receiver telescope. The newly developed detection system has the capability of being digitally interfaced with a simple personal computer, using a discrete input/output interface. This has the potential of transmitting digital data over relatively long distances instead of analog signals, which greatly reduces measurement noise. In this paper, we discuss some results from the new compact water vapor DIAL detection system which includes a silicon based avalanche photodiode (APD) detector, a 14-bit, 10-MHz waveform digitizer, a microcontroller and other auxiliary electronics. All of which are contained on a small printed-circuit-board. This will significantly reduce the weight and volume over the current CAMAC system and eventually will be used in a water vapor DIAL system on an unpiloted atmospheric vehicle (UAV) aircraft, or alternatively on an orbiting spacecraft.

  9. CO2 mitigation via accelerated limestone weathering

    USGS Publications Warehouse

    Rau, G.H.; Knauss, K.G.; Langer, W.H.; Caldeira, K.

    2004-01-01

    The climate and environmental impacts of the current, carbon-intensive energy usage demands that effective and practical energy alternatives and CO2 mitigation strategies be found. A discussion on CO2 mitigation via accelerated limestone weathering covers limestone and seawater availability and cost; reaction rates and densities; effectiveness in CO2 sequestration; and environmental impacts and benefits.

  10. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect

    Davis, K J; Richardson, S J; Miles, N L

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within ± 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than ± 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than ± 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2-3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute

  11. Comparison of 2 micron Ho and 10 micron CO2 lidar for atmospheric backscatter and Doppler windshear detection

    NASA Technical Reports Server (NTRS)

    Killinger, Dennis

    1991-01-01

    The development of eye-safe, solid-state Lidar systems is discussed, with an emphasis on Coherent Doppler Lidar for Atmospheric Wind Measurements. The following subject areas are covered: tunable Ho DIAL (Differential Absorption Lidar)/lidar atmospheric measurements; atmospheric turbulence measurements and detector arrays; diurnal measurements of C(sub n)(sup 2) for KSC lidar measurements; and development of single-frequency Ho laser/lidar.

  12. Structurally simple complexes of CO2.

    PubMed

    Murphy, Luke J; Robertson, Katherine N; Kemp, Richard A; Tuononen, Heikki M; Clyburne, Jason A C

    2015-03-01

    The ability to bind CO2 through the formation of low-energy, easily-broken, bonds could prove invaluable in a variety of chemical contexts. For example, weak bonds to CO2 would greatly decrease the cost of the energy-intensive sorbent-regeneration step common to most carbon capture technologies. Furthermore, exploration of this field could lead to the discovery of novel CO2 chemistry. Reduction of complexed carbon dioxide might generate chemical feedstocks for the preparation of value-added products, particularly transportation fuels or fuel precursors. Implementation on a large scale could help to drastically reduce CO2 concentrations in the atmosphere. However, literature examples of weakly bonded complexes of CO2 are relatively few and true coordination complexes to a 'naked' CO2 fragment are nearly unheard of. In this review article, a variety of complexes of CO2 featuring diverse binding modes and reactivity will be examined. Topics covered include: (A) inclusion complexes of CO2 in porous materials. (B) Zwitterionic carbamates produced from the reaction of CO2 with polyamines. (C) Carbamate salts produced from reaction of CO2 with two equivalents of an amine. (D) Insertion products of CO2 into acid-base adducts (e.g., metal complexes). (E) Lewis acid-base activated CO2, such as frustrated Lewis pair complexes. (F) Simple base-CO2 adducts, wherein the base-CO2 bond is the only interaction formed. Complexes in the last category are of particular interest, and include imidazol-2-carboxylates (N-heterocyclic carbene adducts of CO2) as well as a few other examples that lie outside NHC chemistry.

  13. Forest succession at elevated CO2

    SciTech Connect

    Clark, James S.; Schlesinger, William H.

    2002-02-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response.

  14. Isotopic CO2 Instrumentation for UAV Measurements

    NASA Astrophysics Data System (ADS)

    Gomez, A.; Silver, J.

    2013-12-01

    Carbon dioxide is the largest component of anthroprogenic green house gas emissions. Knowing atmospheric 13CO2/12CO2 ratios precisely is important for understanding biogenic and anthroprogenic sources and sinks for carbon. Instrumentation mounted on UAV aircraft would enable important spatial isotopic CO2 information. However, current isotopic CO2 instrumentation have unfavorable attributes for UAV use, such as high power requirements, high cost, high weight, and large size. Here we present the early development of a compact isotopic CO2 instrument that is designed to nullify effects of pressure, temperature and moisture, and will ultimately be suitable for UAV deployment.

  15. Storing CO2 underground shows promising results

    NASA Astrophysics Data System (ADS)

    Zweigel, Peter; Gale, John

    Long-term underground storage of CO2 is an important element in concepts to reduce atmospheric CO2 emissions as the use of fossil fuels continues. The first results of a multinational research project evaluating the injection of CO2 into a saline aquifer in the North Sea are validating this method of CO2 reduction, and are serving to further define the research needed to develop the technology for large-scale applicability. Reducing the emission of substances that have potentially harmful effects on global climate— for example, CO2—has become a central issue of environmental policy at least since the 1997 Kyoto conference on climate change.

  16. Aminosilicone solvents for CO(2) capture.

    PubMed

    Perry, Robert J; Grocela-Rocha, Teresa A; O'Brien, Michael J; Genovese, Sarah; Wood, Benjamin R; Lewis, Larry N; Lam, Hubert; Soloveichik, Grigorii; Rubinsztajn, Malgorzata; Kniajanski, Sergei; Draper, Sam; Enick, Robert M; Johnson, J Karl; Xie, Hong-bin; Tapriyal, Deepak

    2010-08-23

    This work describes the first report of the use of an aminosilicone solvent mix for the capture of CO(2). To maintain a liquid state, a hydroxyether co-solvent was employed which allowed enhanced physisorption of CO(2) in the solvent mixture. Regeneration of the capture solvent system was demonstrated over 6 cycles and absorption isotherms indicate a 25-50 % increase in dynamic CO(2) capacity over 30 % MEA. In addition, proof of concept for continuous CO(2) absorption was verified. Additionally, modeling to predict heats of reaction of aminosilicone solvents with CO(2) was in good agreement with experimental results.

  17. Selecting CO2 Sources for CO2 Utilization by Environmental-Merit-Order Curves.

    PubMed

    von der Assen, Niklas; Müller, Leonard J; Steingrube, Annette; Voll, Philip; Bardow, André

    2016-02-01

    Capture and utilization of CO2 as alternative carbon feedstock for fuels, chemicals, and materials aims at reducing greenhouse gas emissions and fossil resource use. For capture of CO2, a large variety of CO2 sources exists. Since they emit much more CO2 than the expected demand for CO2 utilization, the environmentally most favorable CO2 sources should be selected. For this purpose, we introduce the environmental-merit-order (EMO) curve to rank CO2 sources according to their environmental impacts over the available CO2 supply. To determine the environmental impacts of CO2 capture, compression and transport, we conducted a comprehensive literature study for the energy demands of CO2 supply, and constructed a database for CO2 sources in Europe. Mapping these CO2 sources reveals that CO2 transport distances are usually small. Thus, neglecting transport in a first step, we find that environmental impacts are minimized by capturing CO2 first from chemical plants and natural gas processing, then from paper mills, power plants, and iron and steel plants. In a second step, we computed regional EMO curves considering transport and country-specific impacts for energy supply. Building upon regional EMO curves, we identify favorable locations for CO2 utilization with lowest environmental impacts of CO2 supply, so-called CO2 oases.

  18. Selecting CO2 Sources for CO2 Utilization by Environmental-Merit-Order Curves.

    PubMed

    von der Assen, Niklas; Müller, Leonard J; Steingrube, Annette; Voll, Philip; Bardow, André

    2016-02-01

    Capture and utilization of CO2 as alternative carbon feedstock for fuels, chemicals, and materials aims at reducing greenhouse gas emissions and fossil resource use. For capture of CO2, a large variety of CO2 sources exists. Since they emit much more CO2 than the expected demand for CO2 utilization, the environmentally most favorable CO2 sources should be selected. For this purpose, we introduce the environmental-merit-order (EMO) curve to rank CO2 sources according to their environmental impacts over the available CO2 supply. To determine the environmental impacts of CO2 capture, compression and transport, we conducted a comprehensive literature study for the energy demands of CO2 supply, and constructed a database for CO2 sources in Europe. Mapping these CO2 sources reveals that CO2 transport distances are usually small. Thus, neglecting transport in a first step, we find that environmental impacts are minimized by capturing CO2 first from chemical plants and natural gas processing, then from paper mills, power plants, and iron and steel plants. In a second step, we computed regional EMO curves considering transport and country-specific impacts for energy supply. Building upon regional EMO curves, we identify favorable locations for CO2 utilization with lowest environmental impacts of CO2 supply, so-called CO2 oases. PMID:26752014

  19. Residual CO2 trapping in Indiana limestone.

    PubMed

    El-Maghraby, Rehab M; Blunt, Martin J

    2013-01-01

    We performed core flooding experiments on Indiana limestone using the porous plate method to measure the amount of trapped CO(2) at a temperature of 50 °C and two pressures: 4.2 and 9 MPa. Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a sacrificial core. Porosity and permeability tests conducted before and after 884 h of continuous core flooding confirmed negligible dissolution. A trapping curve for supercritical (sc)CO(2) in Indiana showing the relationship between the initial and residual CO(2) saturations was measured and compared with that of gaseous CO(2). The results were also compared with scCO(2) trapping in Berea sandstone at the same conditions. A scCO(2) residual trapping end point of 23.7% was observed, indicating slightly less trapping of scCO(2) in Indiana carbonates than in Berea sandstone. There is less trapping for gaseous CO(2) (end point of 18.8%). The system appears to be more water-wet under scCO(2) conditions, which is different from the trend observed in Berea; we hypothesize that this is due to the greater concentration of Ca(2+) in brine at higher pressure. Our work indicates that capillary trapping could contribute to the immobilization of CO(2) in carbonate aquifers.

  20. Microbial Growth under Supercritical CO2

    PubMed Central

    Peet, Kyle C.; Freedman, Adam J. E.; Hernandez, Hector H.; Britto, Vanya; Boreham, Chris; Ajo-Franklin, Jonathan B.

    2015-01-01

    Growth of microorganisms in environments containing CO2 above its critical point is unexpected due to a combination of deleterious effects, including cytoplasmic acidification and membrane destabilization. Thus, supercritical CO2 (scCO2) is generally regarded as a sterilizing agent. We report isolation of bacteria from three sites targeted for geologic carbon dioxide sequestration (GCS) that are capable of growth in pressurized bioreactors containing scCO2. Analysis of 16S rRNA genes from scCO2 enrichment cultures revealed microbial assemblages of varied complexity, including representatives of the genus Bacillus. Propagation of enrichment cultures under scCO2 headspace led to isolation of six strains corresponding to Bacillus cereus, Bacillus subterraneus, Bacillus amyloliquefaciens, Bacillus safensis, and Bacillus megaterium. Isolates are spore-forming, facultative anaerobes and capable of germination and growth under an scCO2 headspace. In addition to these isolates, several Bacillus type strains grew under scCO2, suggesting that this may be a shared feature of spore-forming Bacillus spp. Our results provide direct evidence of microbial activity at the interface between scCO2 and an aqueous phase. Since microbial activity can influence the key mechanisms for permanent storage of sequestered CO2 (i.e., structural, residual, solubility, and mineral trapping), our work suggests that during GCS microorganisms may grow and catalyze biological reactions that influence the fate and transport of CO2 in the deep subsurface. PMID:25681188

  1. Radium dial watches, a potentially hazardous legacy?

    PubMed

    Gillmore, Gavin K; Crockett, Robin; Denman, Tony; Flowers, Alan; Harris, Richard

    2012-09-15

    This study re-examines the risk to health from radium ((226)Ra) dial watches. Ambient dose equivalent rates have been measured for fifteen pocket watches giving results of up to 30 μSv h(-1) at a distance of 2 cm taken with a series 1000 mini-rad from the front face (arithmetic mean ambient dose equivalent for pocket watches being 13.2 μSv h(-1)). A pocket compass gave rise to a similar ambient dose equivalent rate, of 20 μSv h(-1), to the pocket watches, with its cover open. Eighteen wristwatches have also been assessed, but their dose rates are generally much lower (the arithmetic mean being 3.0 μSv h(-1)), although the highest ambient dose equivalent rate noted was 20 μSv h(-1). A phantom experiment using a TLD suggested an effective dose equivalent of 2.2 mSv/y from a 1 μCi (37 kBq) radium dial worn for 16 h/day throughout the year (dose rate 0.375 μSv h(-1)). For this condition we estimated maximum skin dose for our pocket watches as 16 mSv per year, with effective doses of 5.1 mSv and 1.169 mSv when worn in vest and trouser pockets respectively. This assumes exposure from the back of the watch which is generally around 60-67% of that from the front. The maximum skin dose from a wristwatch was 14 mSv, with 4.2 mSv effective dose in vest pocket. Radium ((226)Ra) decays to the radioactive gas radon ((222)Rn), and atmospheric radon concentration measurements taken around a pocket watch in a small sealed glass sphere recorded 18,728 B qm(-3). All watches were placed in a room with a RAD7 real-time radon detector. Radon concentration average was 259±9 Bq m(-3) over 16 h, compared to background average over 24h of 1.02 Bq m(-3). Over 6 weeks highs of the order of 2000 Bq m(-3) were routinely recorded when the heating/ventilation system in the room was operating at reduced rates, peaking at over 3000 Bq m(-3) on several occasions. Estimates of the activity of (226)Ra in the watches ranged from 0.063 to 1.063 μCi (2.31 to 39.31 kBq) for pocket watches and

  2. Fourier Transform Microwave Spectra of CO{2}-ETHYLENE Sulfide, CO{2}-ETHYLENE Oxide and CO{2}-PROPYLENE Oxide Complexes

    NASA Astrophysics Data System (ADS)

    Orita, Yukari; Kawashima, Yoshiyuki; Hirota, Eizi

    2010-06-01

    We have previously examined the difference in roles of O and S in structure and dynamics of the CO-ethylene oxide (EO) and CO-ethylene sulfide (ES) complexes. We have extended the investigation to CO{2}-EO and CO{2}-ES for comparison. We have also observed the CO{2}-propylene oxide (PO) complex, which is an important intermediate in the reaction of PO with CO{2} leading to polycarbonate. Both a-type and b-type transitions were observed for the CO{2}-EO and CO{2}-ES, but no c-type transitions were observed at all. We also detected the {34}S and {13}C isotopic species in natural abundance and the species containing {18}OCO and C{18}O% {2}, which were synthesized by burning paper in an {18}O{2} and{% 16}O{2} mixture. By analyzing the observed spectra we concluded the CO{2} moiety of CO{2}-EO and CO{2}-ES located in a plane % prependicular to the three-membered ring and bisecting the COC or CSC angle of EO or ES, respectively, as in the case of CO-EO and CO-ES complexes. An % ab initio MO calculation at the level of MP2/6-311G(d, p) yielded an optimized structure in good agreement with the experimental result. We have derived from the observed spectra the distance, the stretching force constant, and the binding energy of the bonds between the constituents of the CO{2}-EO and CO{2}-ES complexes and have found that the distances of the two complexes were shorter by 0.2Å than those in CO-EO and CO-ES, respectively, and that the intermolecular bonds were two times stronger in the CO{2} complexes than in the corresponding CO complexes. We have concluded from the observed spectra that the CO{2} moiety in CO{2}-PO is located on the PO three-membered ring plane opposite to the methyl group. The constituents in CO{2}-PO were more weakly bound than those in CO{2}-EO and CO{2}-ES. S. Sato, Y. Kawashima, Y. Tatamitani, and E. Hirota, 63rd International Symposium on Molecular Spectroscopy, WF05 (2008).

  3. Exogenously produced CO2 doubles the CO2 efflux from three north temperate lakes

    NASA Astrophysics Data System (ADS)

    Wilkinson, Grace M.; Buelo, Cal D.; Cole, Jonathan J.; Pace, Michael L.

    2016-03-01

    It is well established that lakes are typically sources of CO2 to the atmosphere. However, it remains unclear what portion of CO2 efflux is from endogenously processed organic carbon or from exogenously produced CO2 transported into lakes. We estimated high-frequency CO2 and O2 efflux from three north temperate lakes in summer to determine the proportion of the total CO2 efflux that was exogenously produced. Two of the lakes were amended with nutrients to experimentally enhance endogenous CO2 uptake. In the unfertilized lake, 50% of CO2 efflux was from exogenous sources and hydrology had a large influence on efflux. In the fertilized lakes, endogenous CO2 efflux was negative (into the lake) yet exogenous CO2 made the lakes net sources of CO2 to the atmosphere. Shifts in hydrologic regimes and nutrient loading have the potential to change whether small lakes act primarily as reactors or vents in the watershed.

  4. Energyless CO2 Absorption, Generation, and Fixation Using Atmospheric CO2.

    PubMed

    Inagaki, Fuyuhiko; Okada, Yasuhiko; Matsumoto, Chiaki; Yamada, Masayuki; Nakazawa, Kenta; Mukai, Chisato

    2016-01-01

    From an economic and ecological perspective, the efficient utilization of atmospheric CO2 as a carbon resource should be a much more important goal than reducing CO2 emissions. However, no strategy to harvest CO2 using atmospheric CO2 at room temperature currently exists, which is presumably due to the extremely low concentration of CO2 in ambient air (approximately 400 ppm=0.04 vol%). We discovered that monoethanolamine (MEA) and its derivatives efficiently absorbed atmospheric CO2 without requiring an energy source. We also found that the absorbed CO2 could be easily liberated with acid. Furthermore, a novel CO2 generator enabled us to synthesize a high value-added material (i.e., 2-oxazolidinone derivatives based on the metal catalyzed CO2-fixation at room temperature) from atmospheric CO2.

  5. CO2 transport over complex terrain

    USGS Publications Warehouse

    Sun, Jielun; Burns, Sean P.; Delany, A.C.; Oncley, S.P.; Turnipseed, A.A.; Stephens, B.B.; Lenschow, D.H.; LeMone, M.A.; Monson, Russell K.; Anderson, D.E.

    2007-01-01

    CO2 transport processes relevant for estimating net ecosystem exchange (NEE) at the Niwot Ridge AmeriFlux site in the front range of the Rocky Mountains, Colorado, USA, were investigated during a pilot experiment. We found that cold, moist, and CO2-rich air was transported downslope at night and upslope in the early morning at this forest site situated on a ???5% east-facing slope. We found that CO2 advection dominated the total CO2 transport in the NEE estimate at night although there are large uncertainties because of partial cancellation of horizontal and vertical advection. The horizontal CO2 advection captured not only the CO2 loss at night, but also the CO2 uptake during daytime. We found that horizontal CO2 advection was significant even during daytime especially when turbulent mixing was not significant, such as in early morning and evening transition periods and within the canopy. Similar processes can occur anywhere regardless of whether flow is generated by orography, synoptic pressure gradients, or surface heterogeneity as long as CO2 concentration is not well mixed by turbulence. The long-term net effect of all the CO2 budget terms on estimates of NEE needs to be investigated. ?? 2007 Elsevier B.V. All rights reserved.

  6. Pseudo-data Inversions of California CO2 Fluxes Combining Tower Measurements of CO2 and 14CO2 with OCO2 Column CO2 Retrievals

    NASA Astrophysics Data System (ADS)

    Fischer, M. L.; Jeong, S.; Bagley, J.; Frankenberg, C.; Parazoo, N.; Keeling, R. F.; Graven, H. D.

    2014-12-01

    The majority (~ 80 %) of California's greenhouse gas (GHG) emissions are likely CO2 produced by fossil fuel combustion (ffCO2). While bottom-up estimates of State-annual total ffCO2 emissions are expected to be accurate to ~ 5-10% (68% confidence), net CO2 exchange at smaller spatial and temporal scales (and emissions of other GHGs) are likely less certain. Here, we report initial results of a Carbon Monitoring System (CMS) pseudo-data inversion study combining simulated total and radiocarbon CO2 sampling from a 10-site ground-based tower network with OCO2 satellite column CO2 retrievals. Fossil and biosphere CO2 signals are computed for tower and OCO2 observations across urban and rural areas of California including the South Coast Air Basin (SoCAB), Central Valley, and San Francisco Bay Area using the WRF-STILT transport model simulations coupled with prior fluxes from VULCAN (ffCO2) and CASA (bioCO2) fluxes respectively. Nominal uncertainties are assigned to the prior ffCO2 fluxes and estimated for the model-measurement differences including WRF and STILT model uncertainties and background subtraction. Reductions in posterior uncertainties for regional ffCO2 emissions are estimated for the tower pseudo-data using Bayesian inversions for monthly periods in multiple seasons. Ongoing work will include incorporation of OCO2 pseudo-data to estimate additional uncertainty reductions obtained for ffCO2 and bioCO2 exchange signals across California's urban and rural regions.

  7. 2.5 MHz Line-Width High-energy, 2 Micrometer Coherent Wind Lidar Transmitter

    NASA Technical Reports Server (NTRS)

    Petros, Mulugeta; Yu, Jirong; Trieu, Bo; Bai, Yingxin; Petzar, Paul; Singh, Upendra N.; Reithmaier, Karl

    2007-01-01

    2 micron solid-state lasers are the primary choice for coherent Doppler wind detection. As wind lidars, they are used for wake vortex and clear air turbulence detection providing air transport safety. In addition, 2 micron lasers are one of the candidates for CO2 detection lidars. The rich CO2 absorption line around 2 micron, combined with the long upper state life of time, has made Ho based 2 micron lasers a viable candidate for CO2 sensing DIAL instrument. The design and fabrication of a compact coherent laser radar transmitter for Troposphere wind sensing is under way. This system is hardened for ground as well as airborne applications. As a transmitter for a coherent wind lidar, this laser has stringent spectral line width and beam quality requirements. Although the absolute wavelength does not have to be fixed for wind detection, to maximize return signal, the output wavelength should avoid atmospheric CO2 and H2O absorption lines. The base line laser material is Ho:Tm:LuLF which is an isomorph of Ho:Tm:YLF. LuLF produces 20% more output power than Ho:Tm:YLF. In these materials the Tm absorption cross-section, the Ho emission cross-section, the Tm to Ho energy transfer parameters and the Ho (sup 5) I (sub 7) radiative life time are all identical. However, the improved performance of the LuLF is attributed to the lower thermal population in the (sup 5) I (sub 8) manifold. It also provides higher normal mode to Q-switch conversion than YLF at high pump energy indicating a lower up-conversion. The laser architecture is composed of a seed laser, a ring oscillator, and a double pass amplifier. The seed laser is a single longitudinal mode with a line width of 13 KHz. The 100mJ class oscillator is stretched to 3 meters to accommodate the line-width requirement without compromising the range resolution of the instrument. The amplifier is double passed to produce greater than 300mJ energy.

  8. CO2 sequestration: Storage capacity guideline needed

    USGS Publications Warehouse

    Frailey, S.M.; Finley, R.J.; Hickman, T.S.

    2006-01-01

    Petroleum reserves are classified for the assessment of available supplies by governmental agencies, management of business processes for achieving exploration and production efficiency, and documentation of the value of reserves and resources in financial statements. Up to the present however, the storage capacity determinations made by some organizations in the initial CO2 resource assessment are incorrect technically. New publications should thus cover differences in mineral adsorption of CO2 and dissolution of CO2 in various brine waters.

  9. R&D100: CO2 Memzyme

    SciTech Connect

    Rempe, Susan; Brinker, Jeff; Jiang, Ying-Bing; Vanegas, Juan

    2015-11-19

    By combining a water droplet loaded with CO2 enzymes in an ultrathin nanopore on a flexible substrate, researchers at Sandia National Laboratories realized the first technology that meets and exceeds DOE targets for cost-effective CO2 capture. When compared with the nearest membrane competitor, this technology delivers a three times permeation rate, twenty times higher selectivity, and ten time lower fabrication cost. The CO2 Memzyme has the potential to remove 90% of CO2 emissions and is forecasted to save the U.S. coal industry $90 billion a year compared to conventional technology.

  10. CO2 capture in different carbon materials.

    PubMed

    Jiménez, Vicente; Ramírez-Lucas, Ana; Díaz, José Antonio; Sánchez, Paula; Romero, Amaya

    2012-07-01

    In this work, the CO(2) capture capacity of different types of carbon nanofibers (platelet, fishbone, and ribbon) and amorphous carbon have been measured at 26 °C as at different pressures. The results showed that the more graphitic carbon materials adsorbed less CO(2) than more amorphous materials. Then, the aim was to improve the CO(2) adsorption capacity of the carbon materials by increasing the porosity during the chemical activation process. After chemical activation process, the amorphous carbon and platelet CNFs increased the CO(2) adsorption capacity 1.6 times, whereas fishbone and ribbon CNFs increased their CO(2) adsorption capacity 1.1 and 8.2 times, respectively. This increase of CO(2) adsorption capacity after chemical activation was due to an increase of BET surface area and pore volume in all carbon materials. Finally, the CO(2) adsorption isotherms showed that activated amorphous carbon exhibited the best CO(2) capture capacity with 72.0 wt % of CO(2) at 26 °C and 8 bar.

  11. CO2 MITIGATION VIA ACCELERATED LIMESTONE WEATHERING

    SciTech Connect

    Rau, G H; Knauss, K G; Langer, W H; Caldeira, K G

    2004-02-27

    The climate and environmental impacts of our current, carbon-intensive energy usage demands that effective and practical energy alternatives and CO2 mitigation strategies be found. As part of this effort, various means of capturing and storing CO2 generated from fossil-fuel-based energy production are being investigated. One of the proposed methods involves a geochemistry-based capture and sequestration process that hydrates point-source, waste CO2 with water to produce a carbonic acid solution. This in turn is reacted and neutralized with limestone, thus converting the original CO2 gas to calcium bicarbonate in solution, the overall reaction being:

  12. CO2 Interaction with Geomaterials (Invited)

    NASA Astrophysics Data System (ADS)

    Romanov, V.; Howard, B. H.; Lynn, R. J.; Warzinski, R. P.; Hur, T.; Myshakin, E. M.; Lopano, C. L.; Voora, V. K.; Al-Saidi, W. A.; Jordan, K. D.; Cygan, R. T.; Guthrie, G. D.

    2010-12-01

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas #3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or “geopolymer”) theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2

  13. CALIOPE airborne CO{sub 2} DIAL (CACDI) system design

    SciTech Connect

    Mietz, D.; Archuleta, B.; Archuleta, J.

    1997-09-01

    Los Alamos National Laboratory is currently developing an airborne CO{sub 2} Differential Absorption Lidar (DIAL) system based on second generation technology demonstrated last summer at NTS. The CALIOPE Airborne CO{sub 2} DIAL (CACDI) system requirements have been compiled based on the mission objectives and SONDIAL model trade studies. Subsystem designs have been developed based on flow down from these system requirements, as well as experience gained from second generation ground tests and N-ABLE (Non-proliferation AirBorne Lidar Experiments) airborne experiments. This paper presents the CACDI mission objectives, system requirements, the current subsystem design, and provides an overview of the airborne experimental plan.

  14. A Method for Measuring Subcanopy CO2 Advection

    NASA Astrophysics Data System (ADS)

    Staebler, R. M.; Fitzjarrald, D. R.

    2004-12-01

    Underestimation of nocturnal CO2 respiration under calm conditions remains an unsolved problem at many forest flux stations, and several groups are currently investigating the direct measurement of horizontal advection of CO2. This presentation will describe a systematic, relatively low-cost methodology developed to determine whether horizontal mean transport of CO2 accounts for the missing CO2 at the Harvard Forest (Petersham, MA). This methodology includes the characterization of subcanopy motions, determining the appropriate size of the subcanopy network required to make the measurements, developing a method of integrating the measurements in the vertical, and determining the required averaging time. Measurements were conducted over 4 years and produced data for 310 nights covering all seasons. Subcanopy flows were decoupled from the flows aloft 75% of the time. Conditions conducive to the generation of negative buoyancy near the forest floor, necessary for drainage flows to develop, were given in 92% of all nights. The occurrence of nocturnal drainage flows correlated well with "missing flux" problems ("deficit nights"), prompting us to propose an improvement on the commonly used friction velocity criterion (which requires u* to be larger than some empirical cut-off for the eddy fluxes to be considered credible). The "negative buoyancy forcing fraction", i.e. negative buoyancy as a fraction of the sum of the dynamic driving forces, can be shown to predict deficit nights significantly better than the u* cut-off. The appropriate horizontal size of the network of wind and CO2 sensors at the Harvard Forest was shown to be on the order of 100 m, ensuring that sensors were generally observing coherent processes on this scale or larger and thus displaying some correlation. Horizontal transport of CO2 was found to be restricted to the bottom ~10 m of the forest, facilitating the development of a method of integrating the horizontal CO2 gradients in the vertical

  15. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect

    Cordatos, Harry

    2010-11-08

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  16. Capturing CO2 via reactions in nanopores.

    SciTech Connect

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team members expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  17. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect

    Cordatos, Harry

    2010-03-01

    Project overview provides background on carbonic anhydrase transport mechanism for CO2 in the human body and proposed approach for ARPA-E project to create a synthetic enzyme analogue and utilize it in a membrane for CO2 capture from flue gas.

  18. Evasion of CO2 Injected into the Ocean in the Context of CO2 Stabilization

    NASA Astrophysics Data System (ADS)

    Kheshgi, H. S.

    2002-05-01

    The injection captured CO2 into the deep ocean is one potential option for sequestering CO2 from the atmosphere. Aspects of this potential option include cost, effects on the marine environment and the eventual evasion of injected CO2 to the atmosphere. Estimates of evasion are considered in the context of long-term scenarios for future CO2 emissions, including illustrative cases leading to stabilization of CO2 concentration at various levels. Ocean carbon cycle model results are used to illustrate how the timing of evasion of injected CO2 fits with current conceptions of the timing of future changes in atmospheric CO2 concentration. Of course, some CO2 emissions would be immediately incurred from the effort required to capture, transport and inject CO2. Modeled residence time for CO2 injected into the deep ocean exceeds the 100 year time scale usually considered in scenarios for future emissions, and the potential impacts of climate change. Illustrative cases leading monotonically to constant CO2 concentration have been highlighted by the Intergovernmental Panel on Climate Change to give guidance on possible timing of emission reductions that may be required to stabilize CO2 concentrations at various levels. For cases considered, significant modeled evasion does not occur until long after CO2 emissions have reached a maximum and begun to decline. Illustrative cases can also lead to a maximum in CO2 concentration followed by a decline to lower, possibly constant, concentrations. In such cases, injection of emissions into the deep ocean leads to lower maximum CO2 concentrations, with less effect on concentrations later on in time. Alternative illustrative cases leading to stabilization of CO2 concentration provide a perspective to view evasion of injected CO2 in relation to emissions from technologies in the distant future.

  19. Geophysical monitoring technology for CO2 sequestration

    NASA Astrophysics Data System (ADS)

    Ma, Jin-Feng; Li, Lin; Wang, Hao-Fan; Tan, Ming-You; Cui, Shi-Ling; Zhang, Yun-Yin; Qu, Zhi-Peng; Jia, Ling-Yun; Zhang, Shu-Hai

    2016-06-01

    Geophysical techniques play key roles in the measuring, monitoring, and verifying the safety of CO2 sequestration and in identifying the efficiency of CO2-enhanced oil recovery. Although geophysical monitoring techniques for CO2 sequestration have grown out of conventional oil and gas geophysical exploration techniques, it takes a long time to conduct geophysical monitoring, and there are many barriers and challenges. In this paper, with the initial objective of performing CO2 sequestration, we studied the geophysical tasks associated with evaluating geological storage sites and monitoring CO2 sequestration. Based on our review of the scope of geophysical monitoring techniques and our experience in domestic and international carbon capture and sequestration projects, we analyzed the inherent difficulties and our experiences in geophysical monitoring techniques, especially, with respect to 4D seismic acquisition, processing, and interpretation.

  20. Zinc depolarized electrochemical CO2 concentration

    NASA Technical Reports Server (NTRS)

    Woods, R. R.; Marshall, R. D.; Schubert, F. H.

    1975-01-01

    Two zinc depolarized electrochemical carbon dioxide concentrator concepts were analytically and experimentally evaluated for portable life support system carbon dioxide (CO2) removal application. The first concept, referred to as the zinc hydrogen generator electrochemical depolarized CO2 concentrator, uses a ZHG to generate hydrogen for direct use in an EDC. The second concept, referred to as the zinc/electrochemical depolarized concentrator, uses a standard EDC cell construction modified for use with the Zn anode. The Zn anode is consumed and subsequently regenerated, thereby eliminating the need to supply H2 to the EDC for the CO2 removal process. The evaluation was based primarily on an analytical evaluation of the two ZnDCs at projected end item performance and hardware design levels. Both ZnDC concepts for PLSS CO2 removal application were found to be noncompetitive in both total equivalent launch weight and individual extravehicular activity mission volume when compared to other candidate regenerable PLSS CO2 scrubbers.

  1. Venting of CO2 at Enceladus’ Surface

    NASA Astrophysics Data System (ADS)

    Matson, Dennis L.; Davies, Ashley G.; Johnson, Torrence V.; Combe, Jean-Philippe; McCord, Tom B.; Radebaugh, Jani

    2015-11-01

    Enceladus has CO2 surface deposits in its South Polar Region that have been recently mapped by J.-P. Combe et al. (2015 AGU Fall Meeting). Assuming that these are CO2 frost, we show how they can be formed. We use an ocean-water circulation model [1] that specifies pressure gradients that drive water to the surface from a relatively gas-rich, subsurface ocean. We now examine the movement of CO2 to the surface; formation of shallow CO2 gas pockets in the ice; and the venting of CO2, when at least some of the gas freezes to form frost. If the local heat flow is known (cf. [2]), then the depths of the corresponding gas pockets can be calculated. References: [1] Matson et al. (2012) Icarus, 221, 53-62. [2] Howett et al. (2011) J. Geophys. Res. 116, E03003. Acknowledgements: AGD thanks the NASA OPR Program for support.

  2. The ins and outs of CO2.

    PubMed

    Raven, John A; Beardall, John

    2016-01-01

    It is difficult to distinguish influx and efflux of inorganic C in photosynthesizing tissues; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases. Some irreversible carboxylases use CO2; others use HCO3(-). The relative role of permeation through the lipid bilayer versus movement through CO2-selective membrane proteins in the downhill, non-energized, movement of CO2 is not clear. Passive permeation explains most CO2 entry, including terrestrial and aquatic organisms with C3 physiology and biochemistry, terrestrial C4 plants and all crassulacean acid metabolism (CAM) plants, as well as being part of some mechanisms of HCO3(-) use in CO2 concentrating mechanism (CCM) function, although further work is needed to test the mechanism in some cases. However, there is some evidence of active CO2 influx at the plasmalemma of algae. HCO3(-) active influx at the plasmalemma underlies all cyanobacterial and some algal CCMs. HCO3(-) can also enter some algal chloroplasts, probably as part of a CCM. The high intracellular CO2 and HCO3(-) pools consequent upon CCMs result in leakage involving CO2, and occasionally HCO3(-). Leakage from cyanobacterial and microalgal CCMs involves up to half, but sometimes more, of the gross inorganic C entering in the CCM; leakage from terrestrial C4 plants is lower in most environments. Little is known of leakage from other organisms with CCMs, though given the leakage better-examined organisms, leakage occurs and increases the energetic cost of net carbon assimilation.

  3. Silvering substrates after CO2 snow cleaning

    NASA Astrophysics Data System (ADS)

    Zito, Richard R.

    2005-09-01

    There have been some questions in the astronomical community concerning the quality of silver coatings deposited on substrates that have been cleaned with carbon dioxide snow. These questions center around the possible existence of carbonate ions left behind on the substrate by CO2. Such carbonate ions could react with deposited silver to produce insoluble silver carbonate, thereby reducing film adhesion and reflectivity. Carbonate ions could be produced from CO2 via the following mechanism. First, during CO2 snow cleaning, a small amount of moisture can condense on a surface. This is especially true if the jet of CO2 is allowed to dwell on one spot. CO2 gas can dissolve in this moisture, producing carbonic acid, which can undergo two acid dissociations to form carbonate ions. In reality, it is highly unlikely that charged carbonate ions will remain stable on a substrate for very long. As condensed water evaporates, Le Chatelier's principle will shift the equilibrium of the chain of reactions that produced carbonate back to CO2 gas. Furthermore, the hydration of CO2 reaction of CO2 with H20) is an extremely slow process, and the total dehydrogenation of carbonic acid is not favored. Living tissues that must carry out the equilibration of carbonic acid and CO2 use the enzyme carbonic anhydrase to speed up the reaction by a factor of one million. But no such enzymatic action is present on a clean mirror substrate. In short, the worst case analysis presented below shows that the ratio of silver atoms to carbonate radicals must be at least 500 million to one. The results of chemical tests presented here support this view. Furthermore, film lift-off tests, also presented in this report, show that silver film adhesion to fused silica substrates is actually enhanced by CO2 snow cleaning.

  4. The ins and outs of CO2

    PubMed Central

    Raven, John A.; Beardall, John

    2016-01-01

    It is difficult to distinguish influx and efflux of inorganic C in photosynthesizing tissues; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases. Some irreversible carboxylases use CO2; others use HCO3 –. The relative role of permeation through the lipid bilayer versus movement through CO2-selective membrane proteins in the downhill, non-energized, movement of CO2 is not clear. Passive permeation explains most CO2 entry, including terrestrial and aquatic organisms with C3 physiology and biochemistry, terrestrial C4 plants and all crassulacean acid metabolism (CAM) plants, as well as being part of some mechanisms of HCO3 – use in CO2 concentrating mechanism (CCM) function, although further work is needed to test the mechanism in some cases. However, there is some evidence of active CO2 influx at the plasmalemma of algae. HCO3 – active influx at the plasmalemma underlies all cyanobacterial and some algal CCMs. HCO3 – can also enter some algal chloroplasts, probably as part of a CCM. The high intracellular CO2 and HCO3 – pools consequent upon CCMs result in leakage involving CO2, and occasionally HCO3 –. Leakage from cyanobacterial and microalgal CCMs involves up to half, but sometimes more, of the gross inorganic C entering in the CCM; leakage from terrestrial C4 plants is lower in most environments. Little is known of leakage from other organisms with CCMs, though given the leakage better-examined organisms, leakage occurs and increases the energetic cost of net carbon assimilation. PMID:26466660

  5. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

    SciTech Connect

    Lewicki, J.L.; Hilley, G.E.; Dobeck, L.; Spangler, L.

    2009-09-01

    A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.

  6. External radiation doses received by female radium dial painters

    SciTech Connect

    Rowland, R.E.; Lucas, H.F.; Schlenker, R.A.

    1988-01-01

    While almost all the studies of the dial painters have concentrated on their internally deposited radium, the dial painters also received an external dose from the gamma rays emitted by radium and its daughter products. Each painter worked with a container of paint containing radium in front of her, and a collection of finished dials beside her. Each work station then was a radiation source, and each painter in the room was irradiated by her own sources of radium in front of her, by the radium on every other work station in the room, and by the radium contamination on the floors and desks. Each day that a painter worked she would have received a dose from these external sources which was unrelated to her internally deposited radium, but dependent on her work place. It is the purpose of this study to estimate the external dose in the work place, to determine the dose received from these external sources for each female dial painter from the length of time she worked, and to examine the relationship between external dose and the causes of death.

  7. MediDial cards: a quick win for service improvement

    PubMed Central

    Davies, Mike; Panchal, Sonia

    2014-01-01

    One of the key roles of a junior doctor is co-ordinating the care of their patients and communicating with different departments or specialties within the hospital. To do this, junior doctors often spend a lot of time on a daily basis contacting the hospital switchboard in order to locate a required bleep/extension/fax number, or trying to navigate an intranet based directory which can be difficult to use. We aimed to improve this task for junior doctors as a pilot project for engaging junior doctors in service improvement. Our multi-disciplinary team, led by junior doctors and with the support of the Trust, produced and implemented lanyard (MediDial) cards containing common and relevant (fax, bleep, and extension) numbers for use by junior doctors. Through the introduction of our MediDial cards we not only reduced the frequency junior doctors needed to contact the switchboard on a daily basis, but also the length of time spent waiting to speak to an operator. The MediDial cards were also found to be time saving and more useful than the previous intranet based database. Since the introduction of the MediDial cards, the project has been rolled out across the Trust and presented at Grand Rounds as an example of junior doctor led service improvement, aiming to encourage trainees to engage with quality improvement projects. PMID:26734285

  8. Airborne Dial Remote Sensing of the Arctic Ozone Layer

    NASA Technical Reports Server (NTRS)

    Wirth, Martin; Renger, Wolfgang; Ehret, Gerhard

    1992-01-01

    A combined ozone and aerosol LIDAR was developed at the Institute of Physics of the Atmosphere at the DLR in Oberpfaffenhofen. It is an airborne version, that, based on the DIAL-principle, permits the recording of two-dimensional ozone profiles. This presentation will focus on the ozone-part; the aerosol subsection will be treated later.

  9. CO2 Accounting and Risk Analysis for CO2 Sequestration at Enhanced Oil Recovery Sites.

    PubMed

    Dai, Zhenxue; Viswanathan, Hari; Middleton, Richard; Pan, Feng; Ampomah, William; Yang, Changbing; Jia, Wei; Xiao, Ting; Lee, Si-Yong; McPherson, Brian; Balch, Robert; Grigg, Reid; White, Mark

    2016-07-19

    Using CO2 in enhanced oil recovery (CO2-EOR) is a promising technology for emissions management because CO2-EOR can dramatically reduce sequestration costs in the absence of emissions policies that include incentives for carbon capture and storage. This study develops a multiscale statistical framework to perform CO2 accounting and risk analysis in an EOR environment at the Farnsworth Unit (FWU), Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil/gas-water flow and transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major risk metrics: CO2/water injection/production rates, cumulative net CO2 storage, cumulative oil/gas productions, and CO2 breakthrough time. The median and confidence intervals are estimated for quantifying uncertainty ranges of the risk metrics. A response-surface-based economic model has been derived to calculate the CO2-EOR profitability for the FWU site with a current oil price, which suggests that approximately 31% of the 1000 realizations can be profitable. If government carbon-tax credits are available, or the oil price goes up or CO2 capture and operating expenses reduce, more realizations would be profitable. The results from this study provide valuable insights for understanding CO2 storage potential and the corresponding environmental and economic risks of commercial-scale CO2-sequestration in depleted reservoirs.

  10. CO2 Accounting and Risk Analysis for CO2 Sequestration at Enhanced Oil Recovery Sites.

    PubMed

    Dai, Zhenxue; Viswanathan, Hari; Middleton, Richard; Pan, Feng; Ampomah, William; Yang, Changbing; Jia, Wei; Xiao, Ting; Lee, Si-Yong; McPherson, Brian; Balch, Robert; Grigg, Reid; White, Mark

    2016-07-19

    Using CO2 in enhanced oil recovery (CO2-EOR) is a promising technology for emissions management because CO2-EOR can dramatically reduce sequestration costs in the absence of emissions policies that include incentives for carbon capture and storage. This study develops a multiscale statistical framework to perform CO2 accounting and risk analysis in an EOR environment at the Farnsworth Unit (FWU), Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil/gas-water flow and transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major risk metrics: CO2/water injection/production rates, cumulative net CO2 storage, cumulative oil/gas productions, and CO2 breakthrough time. The median and confidence intervals are estimated for quantifying uncertainty ranges of the risk metrics. A response-surface-based economic model has been derived to calculate the CO2-EOR profitability for the FWU site with a current oil price, which suggests that approximately 31% of the 1000 realizations can be profitable. If government carbon-tax credits are available, or the oil price goes up or CO2 capture and operating expenses reduce, more realizations would be profitable. The results from this study provide valuable insights for understanding CO2 storage potential and the corresponding environmental and economic risks of commercial-scale CO2-sequestration in depleted reservoirs. PMID:27362472

  11. CO2 deserts: implications of existing CO2 supply limitations for carbon management.

    PubMed

    Middleton, Richard S; Clarens, Andres F; Liu, Xiaowei; Bielicki, Jeffrey M; Levine, Jonathan S

    2014-10-01

    Efforts to mitigate the impacts of climate change will require deep reductions in anthropogenic CO2 emissions on the scale of gigatonnes per year. CO2 capture and utilization and/or storage technologies are a class of approaches that can substantially reduce CO2 emissions. Even though examples of this approach, such as CO2-enhanced oil recovery, are already being practiced on a scale >0.05 Gt/year, little attention has been focused on the supply of CO2 for these projects. Here, facility-scale data newly collected by the U.S. Environmental Protection Agency was processed to produce the first comprehensive map of CO2 sources from industrial sectors currently supplying CO2 in the United States. Collectively these sources produce 0.16 Gt/year, but the data reveal the presence of large areas without access to CO2 at an industrially relevant scale (>25 kt/year). Even though some facilities with the capability to capture CO2 are not doing so and in some regions pipeline networks are being built to link CO2 sources and sinks, much of the country exists in "CO2 deserts". A life cycle analysis of the sources reveals that the predominant source of CO2, dedicated wells, has the largest carbon footprint further confounding prospects for rational carbon management strategies.

  12. Engineered yeast for enhanced CO2 mineralization†

    PubMed Central

    Barbero, Roberto; Carnelli, Lino; Simon, Anna; Kao, Albert; Monforte, Alessandra d’Arminio; Riccò, Moreno; Bianchi, Daniele; Belcher, Angela

    2014-01-01

    In this work, a biologically catalyzed CO2 mineralization process for the capture of CO2 from point sources was designed, constructed at a laboratory scale, and, using standard chemical process scale-up protocols, was modeled and evaluated at an industrial scale. A yeast display system in Saccharomyces cerevisae was used to screen several carbonic anhydrase isoforms and mineralization peptides for their impact on CO2 hydration, CaCO3 mineralization, and particle settling rate. Enhanced rates for each of these steps in the CaCO3 mineralization process were confirmed using quantitative techniques in lab-scale measurements. The effect of these enhanced rates on the CO2 capture cost in an industrial scale CO2 mineralization process using coal fly ash as the CaO source was evaluated. The model predicts a process using bCA2- yeast and fly ash is ~10% more cost effective per ton of CO2 captured than a process with no biological molecules, a savings not realized by wild-type yeast and high-temperature stable recombinant CA2 alone or in combination. The levelized cost of electricity for a power plant using this process was calculated and scenarios in which this process compares favorably to CO2 capture by MEA absorption process are presented. PMID:25289021

  13. Glacial CO2 Cycles: A Composite Scenario

    NASA Astrophysics Data System (ADS)

    Broecker, W. S.

    2015-12-01

    There are three main contributors to the glacial drawdown of atmospheric CO2 content: starvation of the supply of carbon to the ocean-atmosphere reservoir, excess CO2 storage in the deep sea, and surface-ocean cooling. In this talk, I explore a scenario in which all three play significant roles. Key to this scenario is the assumption that deep ocean storage is related to the extent of nutrient stratification of the deep Atlantic. The stronger this stratification, the larger the storage of respiration CO2. Further, it is my contention that the link between Milankovitch insolation cycles and climate is reorganizations of the ocean's thermohaline circulation leading to changes in the deep ocean's CO2 storage. If this is the case, the deep Atlantic d13C record kept in benthic foraminifera shells tells us that deep ocean CO2 storage follows Northern Hemisphere summer insolation cycles and thus lacks the downward ramp so prominent in the records of sea level, benthic 18O and CO2. Rather, the ramp is created by the damping of planetary CO2 emissions during glacial time intervals. As it is premature to present a specific scenario, I provide an example as to how these three contributors might be combined. As their magnitudes and shapes remain largely unconstrained, the intent of this exercise is to provoke creative thinking.

  14. Estimating lake-atmosphere CO2 exchange

    USGS Publications Warehouse

    Anderson, D.E.; Striegl, R.G.; Stannard, D.I.; Michmerhuizen, C.M.; McConnaughey, T.A.; LaBaugh, J.W.

    1999-01-01

    Lake-atmosphere CO2 flux was directly measured above a small, woodland lake using the eddy covariance technique and compared with fluxes deduced from changes in measured lake-water CO2 storage and with flux predictions from boundary-layer and surface-renewal models. Over a 3-yr period, lake-atmosphere exchanges of CO2 were measured over 5 weeks in spring, summer, and fall. Observed springtime CO2 efflux was large (2.3-2.7 ??mol m-2 s-1) immediately after lake-thaw. That efflux decreased exponentially with time to less than 0.2 ??mol m-2 s-1 within 2 weeks. Substantial interannual variability was found in the magnitudes of springtime efflux, surface water CO2 concentrations, lake CO2 storage, and meteorological conditions. Summertime measurements show a weak diurnal trend with a small average downward flux (-0.17 ??mol m-2 s-1) to the lake's surface, while late fall flux was trendless and smaller (-0.0021 ??mol m-2 s-1). Large springtime efflux afforded an opportunity to make direct measurement of lake-atmosphere fluxes well above the detection limits of eddy covariance instruments, facilitating the testing of different gas flux methodologies and air-water gas-transfer models. Although there was an overall agreement in fluxes determined by eddy covariance and those calculated from lake-water storage change in CO2, agreement was inconsistent between eddy covariance flux measurements and fluxes predicted by boundary-layer and surface-renewal models. Comparison of measured and modeled transfer velocities for CO2, along with measured and modeled cumulative CO2 flux, indicates that in most instances the surface-renewal model underpredicts actual flux. Greater underestimates were found with comparisons involving homogeneous boundary-layer models. No physical mechanism responsible for the inconsistencies was identified by analyzing coincidentally measured environmental variables.

  15. Regenerable Sorbent for CO2 Removal

    NASA Technical Reports Server (NTRS)

    Alptekin, Gokhan; Jayaraman, Ambal

    2013-01-01

    A durable, high-capacity regenerable sorbent can remove CO2 from the breathing loop under a Martian atmosphere. The system design allows near-ambient temperature operation, needs only a small temperature swing, and sorbent regeneration takes place at or above 8 torr, eliminating the potential for Martian atmosphere to leak into the regeneration bed and into the breathing loop. The physical adsorbent can be used in a metabolic, heat-driven TSA system to remove CO2 from the breathing loop of the astronaut and reject it to the Martian atmosphere. Two (or more) alternating sorbent beds continuously scrub and reject CO2 from the spacesuit ventilation loop. The sorbent beds are cycled, alternately absorbing CO2 from the vent loop and rejecting the adsorbed material into the environment at a high CO2 partial pressure (above 8 torr). The system does not need to run the adsorber at cryogenic temperatures, and uses a much smaller temperature swing. The sorbent removes CO2 via a weak chemical interaction. The interaction is strong enough to enable CO2 adsorption even at 3 to 7.6 torr. However, because the interaction between the surface adsorption sites and the CO2 is relatively weak, the heat input needed to regenerate the sorbent is much lower than that for chemical absorbents. The sorbent developed in this project could potentially find use in a large commercial market in the removal of CO2 emissions from coal-fired power plants, if regulations are put in place to curb carbon emissions from power plants.

  16. Geological factors affecting CO2 plume distribution

    USGS Publications Warehouse

    Frailey, S.M.; Leetaru, H.

    2009-01-01

    Understanding the lateral extent of a CO2 plume has important implications with regards to buying/leasing pore volume rights, defining the area of review for an injection permit, determining the extent of an MMV plan, and managing basin-scale sequestration from multiple injection sites. The vertical and lateral distribution of CO2 has implications with regards to estimating CO2 storage volume at a specific site and the pore pressure below the caprock. Geologic and flow characteristics such as effective permeability and porosity, capillary pressure, lateral and vertical permeability anisotropy, geologic structure, and thickness all influence and affect the plume distribution to varying degrees. Depending on the variations in these parameters one may dominate the shape and size of the plume. Additionally, these parameters do not necessarily act independently. A comparison of viscous and gravity forces will determine the degree of vertical and lateral flow. However, this is dependent on formation thickness. For example in a thick zone with injection near the base, the CO2 moves radially from the well but will slow at greater radii and vertical movement will dominate. Generally the CO2 plume will not appreciably move laterally until the caprock or a relatively low permeability interval is contacted by the CO2. Conversely, in a relatively thin zone with the injection interval over nearly the entire zone, near the wellbore the CO2 will be distributed over the entire vertical component and will move laterally much further with minimal vertical movement. Assuming no geologic structure, injecting into a thin zone or into a thick zone immediately under a caprock will result in a larger plume size. With a geologic structure such as an anticline, CO2 plume size may be restricted and injection immediately below the caprock may have less lateral plume growth because the structure will induce downward vertical movement of the CO2 until the outer edge of the plume reaches a spill

  17. Natural Analog for Geologic Storage of CO2: CO2 accumulation in China

    NASA Astrophysics Data System (ADS)

    Liu, L.; Xu, T.; Liu, N.; Zhou, B.

    2012-12-01

    Natural accumulations of CO2 are potential analogues of CO2 geological storage that can provide useful information on the behaviour of supercritical CO2 in reservoirs. Natural CO2 accumulations are common across Northeast China, and, although they occur in a wide variety of geological settings, their distribution is principally controlled by the Mesozoic-Cenozoic rift basins and associated Quaternary volcanism. High CO2 concentrations (>60 CO2%) in natural gas reservoirs are usually related to volcanism and magmatism, and possesses mantle-genetic origin. CO2 reservoirs consist of sandstone, volcanic rocks and carbonate rocks with the buried depth from 2000-3000 m. Dawsonite is recognized in almost all of the CO2-bearing basin, which has been proved to share the same carbon source with CO2 in the reservoirs in Songliao basin, Hailaer basin and Donghai basin. Petrographic data show that dawsonite is abundant in feldspar- rich sandstone, volcanic rock fragment-rich sandstones and tuff. In some cases, high percentage of dawsonite cement constitutes a diagenetic seal, which occurs in the reservoir-mudstone caprock and prevents upward leakage of CO2. Besides dawsonite, mantle-genetic CO2 flux leads to the formation of calcite, ankerite and siderite. The statistics of porosity and permeability measured from the dawsonite-bearing sandstone and dawsonite-absent sandstone with the almost same burial depth in Songliao basin show that the mantle-genetic CO2 flux result in lower reservoir quality, suggesting that mineral trapping for CO2 is significant. Chemical analyses of formation water in Songliao basin and Hailaer basin indicate that the concentrations of TDS, HCO3-,CO32-, Mg2+,Ca2+ and Na+ + K+ in dawsonite-bearing sandstone are higher than that in dawsonite-absent sandstone. Distribution of CO2 and dawsonite is constrainted by the regional caprocks in the Songliao basin. The charging time of the mantle-genetic CO2 in China dates from 50 to 25 Ma.

  18. Atmospheric CO2 Removal by Enhancing Weathering

    NASA Astrophysics Data System (ADS)

    Koster van Groos, A. F.; Schuiling, R. D.

    2014-12-01

    The increase of the CO2 content in the atmosphere by the release of anthropogenic CO2 may be addressed by the enhancement of weathering at the surface of the earth. The average emission of mantle-derived CO2 through volcanism is ~0.3 Gt/year (109 ton/year). Considering the ~3.000 Gt of CO2 present in the atmosphere, the residence time of CO2 in the earth's atmosphere is ~10,000 years. Because the vast proportion of carbon in biomass is recycled through the atmosphere, CO2 is continuously removed by a series of weathering reactions of silicate minerals and stored in calcium and magnesium carbonates. The addition of anthropogenic CO2 from fossil fuel and cement production, which currently exceeds 35 Gt/year and dwarfs the natural production 100-fold, cannot be compensated by current rates of weathering, and atmospheric CO2 levels are rising rapidly. To address this increase in CO2 levels, weathering rates would have to be accelerated on a commensurate scale. Olivine ((Mg,Fe)2SiO4) is the most reactive silicate mineral in the weathering process. This mineral is the major constituent in relatively common ultramafic rocks such as dunites (olivine content > 90%). To consume the current total annual anthropogenic release of CO2, using a simplified weathering reaction (Mg2SiO4 + 4CO2 + 4H2O --> 2 Mg2+ + 4HCO3- + H4SiO4) would require ~30 Gt/year or ~8-9 km3/year of dunite. This is a large volume; it is about double the total amount of ore and gravel currently mined (~ 17 Gt/year). To mine and crush these rocks to <100 μm costs ~ 8/ton. The transport and distribution over the earth's surface involves additional costs, that may reach 2-5/ton. Thus, the cost of remediation for the release of anthropogenic CO2 is 300-400 billion/year. This compares to a 2014 global GDP of ~80 trillion. Because weathering reactions require the presence of water and proceed more rapidly at higher temperatures, the preferred environments to enhance weathering are the wet tropics. From a socio

  19. The Oceanic Sink for Anthropogenic CO2

    SciTech Connect

    Sabine, Chris; Feely, R. A.; Gruber, N.; Key, Robert; Lee, K.; Bullister, J.L.; Wanninkhof, R.; Wong, C. S.; Wallace, D.W.R.; Tilbrook, B.; Millero, F. J.; Peng, T.-H.; Kozyr, Alexander; Ono, Tsueno

    2004-01-01

    Using inorganic carbon measurements from an international survey effort in the 1990s and a tracer-based separation technique, we estimate a global oceanic anthropogenic carbon dioxide (CO2) sink for the period from 1800 to 1994 of 118 19 petagrams of carbon. The oceanic sink accounts for ~48% of the total fossil-fuel and cement-manufacturing emissions, implying that the terrestrial biosphere was a net source of CO2 to the atmosphere of about 39 28 petagrams of carbon for this period. The current fraction of total anthropogenic CO2 emissions stored in the ocean appears to be about one-third of the long-term potential.

  20. The oceanic sink for anthropogenic CO2.

    PubMed

    Sabine, Christopher L; Feely, Richard A; Gruber, Nicolas; Key, Robert M; Lee, Kitack; Bullister, John L; Wanninkhof, Rik; Wong, C S; Wallace, Douglas W R; Tilbrook, Bronte; Millero, Frank J; Peng, Tsung-Hung; Kozyr, Alexander; Ono, Tsueno; Rios, Aida F

    2004-07-16

    Using inorganic carbon measurements from an international survey effort in the 1990s and a tracer-based separation technique, we estimate a global oceanic anthropogenic carbon dioxide (CO2) sink for the period from 1800 to 1994 of 118 +/- 19 petagrams of carbon. The oceanic sink accounts for approximately 48% of the total fossil-fuel and cement-manufacturing emissions, implying that the terrestrial biosphere was a net source of CO2 to the atmosphere of about 39 +/- 28 petagrams of carbon for this period. The current fraction of total anthropogenic CO2 emissions stored in the ocean appears to be about one-third of the long-term potential.

  1. CO2 Sensing and CO2 Regulation of Stomatal Conductance: Advances and Open Questions.

    PubMed

    Engineer, Cawas B; Hashimoto-Sugimoto, Mimi; Negi, Juntaro; Israelsson-Nordström, Maria; Azoulay-Shemer, Tamar; Rappel, Wouter-Jan; Iba, Koh; Schroeder, Julian I

    2016-01-01

    Guard cells form epidermal stomatal gas-exchange valves in plants and regulate the aperture of stomatal pores in response to changes in the carbon dioxide (CO2) concentration ([CO2]) in leaves. Moreover, the development of stomata is repressed by elevated CO2 in diverse plant species. Evidence suggests that plants can sense [CO2] changes via guard cells and via mesophyll tissues in mediating stomatal movements. We review new discoveries and open questions on mechanisms mediating CO2-regulated stomatal movements and CO2 modulation of stomatal development, which together function in the CO2 regulation of stomatal conductance and gas exchange in plants. Research in this area is timely in light of the necessity of selecting and developing crop cultivars that perform better in a shifting climate. PMID:26482956

  2. Translucent CO2 ice on Mars ?

    NASA Astrophysics Data System (ADS)

    Schmidt, Frederic; Andrieu, Francois; Douté, Sylvain; Schmitt, Bernard

    2016-10-01

    The Martian climate is driven by the condensation/sublimation of CO2 representing 95% of the atmosphere. Many active surface features (such dark spot, dark flows), have been potentially linked to CO2 exchange. Understanding the surface/atmosphere interactions is a major issue, for both atmospheric but also surface science. This study aims at estimating the physical properties of the seasonal CO2 ice deposits. Are these deposits granular or compact? What is the thickness of the ice? How much impurities are included within the ice? These questions have been highly debated in the literature, in particular the presence of a translucent slab ice, the link with the H2O cycle. In particular the cold jet geyser model requires translucent CO2 ice. We use radiative transfer models to simulate spectroscopic data from the CRISM instrument and perform an inversion to estimate model's parameters though time. We then discuss the consistency of the results with other datasets.

  3. 2-μm high-power multiple-frequency single-mode Q-switched Ho:YLF laser for DIAL application

    NASA Astrophysics Data System (ADS)

    Gibert, Fabien; Edouart, Dimitri; Cénac, Claire; Le Mounier, Florian

    2014-09-01

    We report on the development and the demonstration of a two-wavelength single-frequency laser oscillator based on Ho:YLF crystal. This laser is especially suitable for application as a transmitter in differential absorption lidar (DIAL)/integrated path differential absorption (IPDA) measurements of atmospheric carbon dioxide (CO2) using the R30 CO2 absorption line at 2,050.967 nm. The oscillator consists in a fiber-coupled and free-space solid-state hybrid system and can be used in high-energy middle-rate or moderate-energy high-rate configurations. The latter produced On and Off sequentially single-frequency laser pulses with 13 mJ of energy at a repetition rate of 2 kHz and pulse duration of 42 ns. The pulse energy and frequency stabilities are specially documented in free-running, single-frequency and two-frequency seeding single-mode operations. Standard deviation is 7.7 % for pulse energy and 2 MHz for frequency stability for the two-wavelength seeding operation. Allan variance plot shows that frequency fluctuations are reduced below 70 kHz for 10 s of averaging which is suitable for accurate CO2 DIAL or IPDA measurements.

  4. How secure is subsurface CO2 storage? Controls on leakage in natural CO2 reservoirs

    NASA Astrophysics Data System (ADS)

    Miocic, Johannes; Gilfillan, Stuart; McDermott, Christopher; Haszeldine, Stuart

    2014-05-01

    Carbon Capture and Storage (CCS) is the only industrial scale technology available to directly reduce carbon dioxide (CO2) emissions from fossil fuelled power plants and large industrial point sources to the atmosphere. The technology includes the capture of CO2 at the source and transport to subsurface storage sites, such as depleted hydrocarbon reservoirs or saline aquifers, where it is injected and stored for long periods of time. To have an impact on the greenhouse gas emissions it is crucial that there is no or only a very low amount of leakage of CO2 from the storage sites to shallow aquifers or the surface. CO2 occurs naturally in reservoirs in the subsurface and has often been stored for millions of years without any leakage incidents. However, in some cases CO2 migrates from the reservoir to the surface. Both leaking and non-leaking natural CO2 reservoirs offer insights into the long-term behaviour of CO2 in the subsurface and on the mechanisms that lead to either leakage or retention of CO2. Here we present the results of a study on leakage mechanisms of natural CO2 reservoirs worldwide. We compiled a global dataset of 49 well described natural CO2 reservoirs of which six are leaking CO2 to the surface, 40 retain CO2 in the subsurface and for three reservoirs the evidence is inconclusive. Likelihood of leakage of CO2 from a reservoir to the surface is governed by the state of CO2 (supercritical vs. gaseous) and the pressure in the reservoir and the direct overburden. Reservoirs with gaseous CO2 is more prone to leak CO2 than reservoirs with dense supercritical CO2. If the reservoir pressure is close to or higher than the least principal stress leakage is likely to occur while reservoirs with pressures close to hydrostatic pressure and below 1200 m depth do not leak. Additionally, a positive pressure gradient from the reservoir into the caprock averts leakage of CO2 into the caprock. Leakage of CO2 occurs in all cases along a fault zone, indicating that

  5. Study on CO2 global recycling system.

    PubMed

    Takeuchi, M; Sakamoto, Y; Niwa, S

    2001-09-28

    In order to assist in finding ways to mitigate CO2 emission and to slow the depletion of fossil fuels we have established and evaluated a representative system, which consists of three technologies developed in our laboratory. These technologies were in CO2 recovery, hydrogen production and methanol synthesis and in addition we established the necessary supporting systems. Analysis of outline designs of the large scale renewable energy power generation system and this system and energy input for building plant, energy input for running plant has been conducted based on a case using this system for a 1000-MW coal fired power plant, followed by an evaluation of the material balance and energy balance. The results are as follows. Energy efficiency is 34%, the CO2 reduction rate is 41%, the balance ratio of the energy and CO2 of the system is 2.2 and 1.8, respectively, on the assumption that the primary renewable energy is solar thermal power generation, the stationary CO2 emission source is a coal-fired power plant and the generation efficiency of the methanol power plant is 60%. By adopting the system, 3.7 million tons of CO2 can be recovered, approximately 2.7 million tons of methanol can be produced, and 15.4 billion kWh of electricity can be generated per year. Compared to generating all electrical power using only coal, approximately 2.6 million tons of coal per year can be saved and approximately 2.15 million tons of CO2 emission can be reduced. Therefore, it is clearly revealed that this system would be effective to reduce CO2 emissions and to utilize renewable energy.

  6. Trapping atmospheric CO2 with gold.

    PubMed

    Collado, Alba; Gómez-Suárez, Adrián; Webb, Paul B; Kruger, Hedi; Bühl, Michael; Cordes, David B; Slawin, Alexandra M Z; Nolan, Steven P

    2014-10-01

    The ability of gold-hydroxides to fix CO2 is reported. [Au(IPr)(OH)] and [{Au(IPr)}2(μ-OH)][BF4] react with atmospheric CO2 to form the trigold carbonate complex [{Au(IPr)}3(μ(3)-CO3)][BF4]. Reactivity studies revealed that this complex behaves as two basic and one cationic Au centres, and that it is catalytically active. DFT calculations and kinetic experiments have been carried out.

  7. On the Vertical Gradient in CO2

    NASA Astrophysics Data System (ADS)

    Stine, A. R.; Fung, I. Y.

    2008-12-01

    Attempts to constrain surface fluxes of carbon from atmospheric measurements of carbon dioxide have primarily focused on surface boundary layer measurements, because information about surface fluxes is least diluted close to the locations where the fluxes occur. However, errors in model ventilation of air in the vertical can be misinterpreted as local surface fluxes. Satellites which measure column integrated CO2 are expected to represent a major advance in part because they observe the entire atmospheric column. Recent work has highlighted the fact that vertical gradients in carbon concentrations can give us information about where vertical mixing errors are likely to be misinterpreted as local surface fluxes, but passive tracer evidence suggests that models that capture vertical profiles on the ocean do poorly on the land (and vice versa), suggesting that the problem of correctly treating vertical mixing in inverse studies is more fundamental than picking the "best" model. We consider observations of the vertical gradient in CO2 from aircrafts and from a comparison of satellites that observe in the near infrared (which observe the column integrated CO2 field) and the thermal infrared (which observe the upper troposphere). We evaluate the feasibility of using these satellites for determining the vertical gradient in CO2. We examine how observations of the vertical gradient of CO2 allow us to differentiate the imprint of vertical mixing and the imprint in surface fluxes on the observed field of atmospheric CO2.

  8. Advanced CO2 Removal and Reduction System

    NASA Technical Reports Server (NTRS)

    Alptekin, Gokhan; Dubovik, Margarita; Copeland, Robert J.

    2011-01-01

    An advanced system for removing CO2 and H2O from cabin air, reducing the CO2, and returning the resulting O2 to the air is less massive than is a prior system that includes two assemblies . one for removal and one for reduction. Also, in this system, unlike in the prior system, there is no need to compress and temporarily store CO2. In this present system, removal and reduction take place within a single assembly, wherein removal is effected by use of an alkali sorbent and reduction is effected using a supply of H2 and Ru catalyst, by means of the Sabatier reaction, which is CO2 + 4H2 CH4 + O2. The assembly contains two fixed-bed reactors operating in alternation: At first, air is blown through the first bed, which absorbs CO2 and H2O. Once the first bed is saturated with CO2 and H2O, the flow of air is diverted through the second bed and the first bed is regenerated by supplying it with H2 for the Sabatier reaction. Initially, the H2 is heated to provide heat for the regeneration reaction, which is endothermic. In the later stages of regeneration, the Sabatier reaction, which is exothermic, supplies the heat for regeneration.

  9. The overlooked tropical oceanic CO2 sink

    NASA Astrophysics Data System (ADS)

    Ibánhez, J. Severino P.; Araujo, Moacyr; Lefèvre, Nathalie

    2016-04-01

    The intense rainfall in the tropical Atlantic spatially overlaps with the spread of the Amazon plume. Based on remote-sensed sea surface salinity and rainfall, we removed the contribution of rainfall to the apparent Amazon plume area, thus refining the quantification of its extension (0.84 ± 0.06 × 106 km2 to 0.89 ± 0.06 × 106 km2). Despite the previous overestimation of the Amazon plume area due to the influence of rainfall (>16%), our calculated annual CO2 flux based on rainfall-corrected sea surface CO2 fugacity confirms that the Amazon River plume is an atmospheric CO2 sink of global importance (-7.61 ± 1.01 to -7.85 ± 1.02 Tg C yr-1). Yet we show that current sea-air CO2 flux assessments for the tropical Atlantic could be overestimated in about 10% by neglecting the CO2 sink associated to the Amazon plume. Thus, including the Amazon plume, the sea-air CO2 exchange for the tropical Atlantic is estimated to be 81.1 ± 1.1 to 81.5 ± 1.1 Tg C yr-1.

  10. Density of aqueous solutions of CO2

    SciTech Connect

    Garcia, Julio E.

    2001-10-10

    In this report, we present a numerical representation for the partial molar volume of CO2 in water and the calculation of the corresponding aqueous solution density. The motivation behind this work is related to the importance of having accurate representations for aqueous phase properties in the numerical simulation of carbon dioxide disposal into aquifers as well as in geothermal applications. According to reported experimental data the density of aqueous solutions of CO2 can be as much as 2-3% higher than pure water density. This density variation might produce an influence on the groundwater flow regime. For instance, in geologic sequestration of CO2, convective transport mixing might occur when, several years after injection of carbon dioxide has stopped, the CO2-rich gas phase is concentrated at the top of the formation, just below an overlaying caprock. In this particular case the heavier CO2 saturated water will flow downward and will be replaced by water with a lesser CO2 content.

  11. CO2 Acquisition Membrane (CAM) Project

    NASA Technical Reports Server (NTRS)

    Mason, Larry W.

    2003-01-01

    The CO2 Acquisition Membrane (CAM) project was performed to develop, test, and analyze thin film membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The membranes developed in this project are targeted toward In Situ Resource Utilization (ISRU) applications, such as In Situ Propellant Production (ISPP) and In Situ Consumables Production (ISCP). These membrane materials may be used in a variety of ISRU systems, for example as the atmospheric inlet filter for an ISPP process to enhance the concentration of CO2 for use as a reactant gas, to passively separate argon and nitrogen trace gases from CO2 for habitat pressurization, to provide a system for removal of CO2 from breathing gases in a closed environment, or within a process stream to selectively separate CO2 from other gaseous components. The membranes identified and developed for CAM were evaluated for use in candidate ISRU processes and other gas separation applications, and will help to lay the foundation for future unmanned sample return and human space missions. CAM is a cooperative project split among three institutions: Lockheed Martin Astronautics (LMA), the Colorado School of Mines (CSM), and Marshall Space Flight Center (MSFC).

  12. Investigating 14CO2 chamber methodologies

    NASA Astrophysics Data System (ADS)

    Egan, J. E.; Phillips, C. L.; Nickerson, N. R.; Risk, D. A.

    2012-12-01

    The radiogenic isotope of carbon (14C) is an exceptionally useful tool in studying soil respired CO2, providing information about soil turnover rates, depths of production and the biological sources of production through partitioning. Unfortunately, little work has been done to thoroughly investigate the possibility of inherent biases in the current measurement techniques for 14CO2, caused by disturbances to the soil's natural diffusive regime, because of high costs and sampling logistics. Our aim in this study is to investigate the degree of bias present in the current sampling methodologies using a numerical model and laboratory calibration device. Four chamber techniques were tested numerically with varying fraction modern of production, δ13C of production, collar lengths, flux rates and diffusivities. Two of the chambers were then tested on the lab calibration device. One of these chambers, Iso-FD, has recently been tested for its use as a 13CO2 chamber and it does not induce gas transport fractionation biases present in other 13CO2 sampling methodologies. We then implemented it in the field to test its application as a 14CO2 chamber because of its excellent performance as a 13CO2chamber. Presented here are the results from the numerical modeling experiment, the laboratory calibration experiment and preliminary field results from the Iso-FD chamber.

  13. CO2 cooling in terrestrial planet thermospheres

    NASA Technical Reports Server (NTRS)

    Bougher, S. W.; Hunten, D. M.; Roble, R. G.

    1994-01-01

    We examine the recent progress in the debate on the CO2-O relaxation rate, its temperature dependence, and its corresponding impact on the thermospheric heat budgets of Venus, Earth, and Mars. This comparative approach provides the broadest range of conditions under which a common CO2-O relaxation rate should provide consistent results. New global mean calculations are presented for the heat budgets of these three planets using large CO2-O relaxation rates that have been inferred recently from Earth CO2 radiance measurements and laboratory studies. Results indicate that available Venus and Mars data constrain the CO2-O relaxation rate to be 2-4 x 10(exp -12)/cu cm/s at 300 K. For Venus, this strong cooling serves as an effective thermostat that gives rise to a small variation of thermospheric temperatures over the solar cycle, just as observed. Conversely, CO2 cooling does not appear to be dominant in the dayside heat budget of the Mars thermosphere over most of the solar cycle. For the Earth, this strong cooling implies that the lower thermosphere does not typically require significant eddy diffusion or heat conduction. However, global-scale dynamics or an additional heating mechanism may be needed to restore calculated temperatures to observed values when relaxation rates exceeding 2 x 10(exp -12)/cu cm/s are employed.

  14. Range-resolved frequency-agile CO2 lidar measurements of smokestack vapor effluents

    NASA Astrophysics Data System (ADS)

    D'Amico, Francis M.; Vanderbeek, Richard G.; Warren, Russell E.

    1999-11-01

    Range-resolved lidar measurements of chemical vapor output from a smokestack were conducted using a moderate-power (100 millijoules per pulse) frequency-agile CO2 differential absorption lidar (DIAL) system. A 70-foot non-industrial smokestack, erected for the purpose of studying effluent emissions, was used in the experiment. These measurements were conducted for the purpose of obtaining real data to support development of advanced chemical and biological (CB) range- resolved vapor detection algorithms. Plume transmission measurements were made using natural atmospheric backscatter from points at the mouth of the stack and several positions downwind. Controlled releases of triethyl-phosphate (TEP), dimethyl-methylphosphonate (DMMP), and sulfur-hexaflouride (SF6) were performed. Test methodology and experimental results are presented. Effective application of ground-based lidar to the monitoring of smokestack effluents, without the use of fixed targets, is discussed.

  15. Will atmospheric CO2 concentration continue to increase if anthropogenic CO2 emissions cease?

    NASA Astrophysics Data System (ADS)

    MacDougall, A. H.; Eby, M.; Weaver, A. J.

    2013-12-01

    If anthropogenic CO2 emissions were to suddenly cease, the evolution of the atmospheric CO2 concentration would depend on the magnitude and sign of natural carbon sources and sinks. Experiments using Earth system models indicate that overall carbon sinks would dominate. However, these models have typically neglected the permafrost carbon pool, which has the potential to introduce an additional terrestrial source of carbon to the atmosphere. Here we use the University of Victoria Earth System Climate Model, which has recently been expanded to include permafrost carbon stocks and exchanges with the atmosphere. In a scenario of zeroed CO2 and sulphate aerosol emissions, we assess whether the warming induced by specified constant concentrations of non-CO2 greenhouse gases could slow the CO2 decline following zero emissions, or even reverse this trend and cause CO2 to increase over time. We find that a radiative forcing from non-CO2 gases of approximately 0.6 W m-2 results in a near balance of CO2 emissions from the terrestrial biosphere and uptake of CO2 by the oceans, resulting in near-constant atmospheric CO2 concentrations for at least a century after emissions are eliminated. At higher values of non-CO2 radiative forcing, CO2 concentrations increase over time, regardless of when emissions cease during the 21st century. Given that the present-day radiative forcing from non-CO2 greenhouse gases is about 0.95 W m-2, our results suggest that if we were to eliminate all CO2 and aerosols emissions without also decreasing non-CO2 greenhouse gas emissions, CO2 levels would increase over time, resulting in a small increase in climate warming. The sudden and total cessation of anthropogenic CO2 emissions is an unlikely future scenario. However, such cessation experiments provide a useful method for evaluating the relative strength of the terrestrial and oceanic carbon cycle feedbacks in the presence of forcing from non-CO2 greenhouse gasses.

  16. Global CO2 simulation using GOSAT-based surface CO2 flux estimates

    NASA Astrophysics Data System (ADS)

    Takagi, H.; Oda, T.; Saito, M.; Valsala, V.; Belikov, D.; Saeki, T.; Saito, R.; Morino, I.; Uchino, O.; Yoshida, Y.; Yokota, Y.; Bril, A.; Oshchepkov, S.; Andres, R. J.; Maksyutov, S.

    2012-04-01

    Investigating the distribution and temporal variability of surface CO2 fluxes is an active research topic in the field of contemporary carbon cycle dynamics. The technique central to this effort is atmospheric inverse modeling with which surface CO2 fluxes are estimated by making corrections to a priori flux estimates such that mismatches between model-predicted and observed CO2 concentrations are minimized. Past investigations were carried out by utilizing CO2 measurements collected in global networks of surface-based monitoring sites. Now, datasets of column-averaged CO2 dry air mole fraction (XCO2) retrieved from spectral soundings collected by GOSAT are available for complementing the surface-based CO2 observations. These space-based XCO2 data are expected to enhance the spatiotemporal coverage of the existing surface observation network and thus reduce uncertainty associated with the surface flux estimates. We estimated monthly CO2 fluxes in 64 sub-continental regions from a subset of the surface-based GLOBALVIEW CO2 data and the GOSAT FTS SWIR Level 2 XCO2 retrievals. We further simulated CO2 concentrations in 3-D model space using the surface flux estimates obtained. In this presentation, we report the result of a comparison between the simulated CO2 concentrations and independent surface observations. As part of an effort in inter-comparing GOSAT-based surface CO2 flux estimates, we also look at results yielded with XCO2 data retrieved with the PPDF-DOAS algorithm and those made available by the NASA Atmospheric CO2 Observations from Space team. For this study, we used version 08.1 of the National Institute for Environmental Studies atmospheric transport model, which was driven by the Japan Meteorological Agency's JCDAS wind analysis data. The CO2 forward simulations were performed on 2.5° × 2.5° horizontal grids at 32 vertical levels between the surface and the top of the atmosphere. The a priori flux dataset used was comprised of the sum of four

  17. Progress in coherent laser radar

    NASA Technical Reports Server (NTRS)

    Vaughan, J. M.

    1986-01-01

    Considerable progress with coherent laser radar has been made over the last few years, most notably perhaps in the available range of high performance devices and components and the confidence with which systems may now be taken into the field for prolonged periods of operation. Some of this increasing maturity was evident at the 3rd Topical Meeting on Coherent Laser Radar: Technology and Applications. Topics included in discussions were: mesoscale wind fields, nocturnal valley drainage and clear air down bursts; airborne Doppler lidar studies and comparison of ground and airborne wind measurement; wind measurement over the sea for comparison with satellite borne microwave sensors; transport of wake vortices at airfield; coherent DIAL methods; a newly assembled Nd-YAG coherent lidar system; backscatter profiles in the atmosphere and wavelength dependence over the 9 to 11 micrometer region; beam propagation; rock and soil classification with an airborne 4-laser system; technology of a global wind profiling system; target calibration; ranging and imaging with coherent pulsed and CW system; signal fluctuations and speckle. Some of these activities are briefly reviewed.

  18. Primary, secondary, and tertiary amines for CO2 capture: designing for mesoporous CO2 adsorbents.

    PubMed

    Ko, Young Gun; Shin, Seung Su; Choi, Ung Su

    2011-09-15

    CO(2) emissions, from fossil-fuel-burning power plants, the breathing, etc., influence the global worming on large scale and the man's work efficiency on small scale. The reversible capture of CO(2) is a prominent feature of CO(2) organic-inorganic hybrid adsorbent to sequester CO(2). Herein, (3-aminopropyl) trimethoxysilane (APTMS), [3-(methylamino)propyl] trimethoxysilane (MAPTMS), and [3-(diethylamino) propyl] trimethoxysilane (DEAPTMS) are immobilized on highly ordered mesoporous silicas (SBA-15) to catch CO(2) as primary, secondary, and tertiary aminosilica adsorbents. X-ray photoelectron spectroscopy was used to analyze the immobilized APTMS, MAPTMS, and DEAPTMS on the SBA-15. We report an interesting discovery that the CO(2) adsorption and desorption on the adsorbent depend on the amine type of the aminosilica adsorbent. The adsorbed CO(2) was easily desorbed from the adsorbent with the low energy consumption in the order of tertiary, secondary, and primary amino-adsorbents while the adsorption amount and the bonding-affinity increased in the reverse order. The effectiveness of amino-functionalized (1(o), 2(o), and 3(o) amines) SBA-15s as a CO(2) capturing agent was investigated in terms of adsorption capacity, adsorption-desorption kinetics, and thermodynamics. This work demonstrates apt amine types to catch CO(2) and regenerate the adsorbent, which may open new avenues to designing "CO(2) basket". PMID:21708387

  19. Commitment accounting for CO2 emissions

    NASA Astrophysics Data System (ADS)

    Davis, S. J.; Socolow, R. H.

    2013-12-01

    Long-lived energy infrastructure that burns fossil fuels represents a multi-decade 'commitment' to emit CO2. Today's global power sector, alone, represents hundreds of billions of tons of still unrealized 'committed emissions' of CO2. And every year, substantial new commitments to future emissions are made, as new power plants are built. The socioeconomic inertia of these commitments is a major barrier to climate change mitigation. Here, we quantify these annual commitments by a bottom-up analysis of all power plants commissioned between 1950 and 2011; assigning emission commitments to the year when each generator came on line. We find, assuming 40-year commitments, that the global commitment to future emissions from the world's generators in 2011 (the most recent year in our analysis) was 318 Gt CO2, of which 216 Gt CO2 were commitments from the world's coal-fired generators and 134 Gt CO2 were commitments from China's generators. Annual new global commitments exceeded 15 Gt CO2 per year in every year since 2000. Moreover, between 2005-2010 (the latest year of available emissions data), new global commitments were more than twice as large as actual emissions from all power plants. Country-specific ratios of new committed emissions to actual emissions, averaged over 1990-2010 were 4.1 for China, 2.6 for India, 0.9 for the EU, and 0.6 for the US. We urge that the reporting of annual CO2 emissions, already widely institutionalized, be augmented by 'commitment accounting' which makes these future emissions salient. Annual committed emissions and annual emissions of primary power infrastructure. New committed emissions (light green) have grown from approximately 4 Gt CO2 per year in 1960 to roughly 10 Gt CO2 per year between 1970-1995, and then to more than 15 Gt CO2 per year since 2000. Throughout this period, new committed emissions have exceeded annual emissions (blue curve, source: IEA). Although the commitments made 30-40 years ago have largely been realized (dark

  20. Precursory volcanic CO2 signals from space

    NASA Astrophysics Data System (ADS)

    Schwandner, Florian M.; Carn, Simon A.; Kataoka, Fumie; Kuze, Akihiko; Shiomi, Kei; Goto, Naoki

    2016-04-01

    Identification of earliest signals heralding volcanic unrest benefits from the unambiguous detection of precursors that reflect deviation of magmatic systems from metastable background activity. Ascent and emplacement of new basaltic magma at depth may precede eruptions by weeks to months. Transient localized carbon dioxide (CO2) emissions stemming from exsolution from depressurized magma are expected, and have been observed weeks to months ahead of magmatic surface activity. Detecting such CO2 precursors by continuous ground-based monitoring operations is unfortunately not a widely implemented method yet, save a handful of volcanoes. Detecting CO2 emissions from space offers obvious advantages - however it is technologically challenging, not the least due to the increasing atmospheric burden of CO2, against which a surface emission signal is hard to discern. In a multi-year project, we have investigated the feasibility of space-borne detection of pre-eruptive volcanic CO2 passive degassing signals using observations from the Greenhouse Gas Observing SATellite (GOSAT). Since 2010, we have observed over 40 active volcanoes from space using GOSAT's special target mode. Over 72% of targets experienced at least one eruption over that time period, demonstrating the potential utility of space-borne CO2 observations in non-imaging target-mode (point source monitoring mode). While many eruption precursors don't produce large enough CO2 signals to exceed space-borne detection thresholds of current satellite sensors, some of our observations have nevertheless already shown significant positive anomalies preceding eruptions at basaltic volcanoes. In 2014, NASA launched its first satellite dedicated to atmospheric CO2 observation, the Orbiting Carbon Observatory (OCO-2). Its observation strategy differs from the single-shot GOSAT instrument. At the expense of GOSAT's fast time series capability (3-day repeat cycle, vs. 16 for OCO-2), its 8-footprint continuous swath can slice

  1. Exercise carbon dioxide (CO2) retention with inhaled CO2 and breathing resistance.

    PubMed

    Shykoff, Barbara E; Warkander, Dan E

    2012-01-01

    Combined effects on respiratory minute ventilation (VE)--and thus, on end-tidal carbon dioxide partial pressure (P(ET)CO2)--of breathing resistance and elevated inspired carbon dioxide (CO2) had not been determined during heavy exercise. In this Institutional Review Board-approved, dry, sea-level study, 12 subjects in each of three phases exercised to exhaustion at 85% peak oxygen uptake while V(E) and P(ET)CO2 were measured. Participants inhaled 0%, 1%, 2% or 3% CO2 in air, or 0% or 2% CO2 in oxygen, with or without breathing resistance, mimicking the U.S. Navy's MK 16 rebreather underwater breathing apparatus (UBA). Compared to air baseline (0% inspired CO2 in air without resistance): (1) Oxygen decreased baseline V(E) (p < 0.01); (2) Inspired CO2 increased V(E) and P(ET)CO2 (p < 0.01); (3) Resistance decreased V(E) (p < 0.01); (4) Inspired CO2 with resistance elevated P(ET)CO2 (p < 0.01). In air, V(E) did not change from that with resistance alone. In oxygen, V(E) returned to oxygen baseline. End-exercise P(ET)CO2 exceeded 60 Torr (8.0 kPa) in three tests. Subjects identified hypercapnia poorly. Results support dual optimization of arterial carbon dioxide partial pressure and respiratory effort. Because elevated CO2 may not increase V(E) if breathing resistance and VE are high, rebreather UBA safety requires very low inspired CO2.

  2. Fingerprinting captured CO2 using natural tracers: Determining CO2 fate and proving ownership

    NASA Astrophysics Data System (ADS)

    Flude, Stephanie; Gilfillan, Stuart; Johnston, Gareth; Stuart, Finlay; Haszeldine, Stuart

    2016-04-01

    In the long term, captured CO2 will most likely be stored in large saline formations and it is highly likely that CO2 from multiple operators will be injected into a single saline formation. Understanding CO2 behavior within the reservoir is vital for making operational decisions and often uses geochemical techniques. Furthermore, in the event of a CO2 leak, being able to identify the owner of the CO2 is of vital importance in terms of liability and remediation. Addition of geochemical tracers to the CO2 stream is an effective way of tagging the CO2 from different power stations, but may become prohibitively expensive at large scale storage sites. Here we present results from a project assessing whether the natural isotopic composition (C, O and noble gas isotopes) of captured CO2 is sufficient to distinguish CO2 captured using different technologies and from different fuel sources, from likely baseline conditions. Results include analytical measurements of CO2 captured from a number of different CO2 capture plants and a comprehensive literature review of the known and hypothetical isotopic compositions of captured CO2 and baseline conditions. Key findings from the literature review suggest that the carbon isotope composition will be most strongly controlled by that of the feedstock, but significant fractionation is possible during the capture process; oxygen isotopes are likely to be controlled by the isotopic composition of any water used in either the industrial process or the capture technology; and noble gases concentrations will likely be controlled by the capture technique employed. Preliminary analytical results are in agreement with these predictions. Comparison with summaries of likely storage reservoir baseline and shallow or surface leakage reservoir baseline data suggests that C-isotopes are likely to be valuable tracers of CO2 in the storage reservoir, while noble gases may be particularly valuable as tracers of potential leakage.

  3. Advanced CO2 Removal Technology Development

    NASA Technical Reports Server (NTRS)

    Finn, John E.; Verma, Sunita; Forrest, Kindall; LeVan, M. Douglas

    2001-01-01

    The Advanced CO2 Removal Technical Task Agreement covers three active areas of research and development. These include a study of the economic viability of a hybrid membrane/adsorption CO2 removal system, sorbent materials development, and construction of a database of adsorption properties of important fixed gases on several adsorbent material that may be used in CO2 removal systems. The membrane/adsorption CO2 removal system was proposed as a possible way to reduce the energy consumption of the four-bed molecular sieve system now in use. Much of the energy used by the 4BMS is used to desorb water removed in the device s desiccant beds. These beds might be replaced by a desiccating membrane that moves the water from [he incoming stream directly into the outlet stream. The approach may allow the CO2 removal beds to operate at a lower temperature. A comparison between models of the 4BMS and hybrid systems is underway at Vanderbilt University. NASA Ames Research Center has been investigating a Ag-exchanged zeolites as a possible improvement over currently used Ca and Na zeolites for CO2 removal. Silver ions will complex with n:-bonds in hydrocarbons such as ethylene, giving remarkably improved selectivity for adsorption of those materials. Bonds with n: character are also present in carbon oxides. NASA Ames is also continuing to build a database for adsorption isotherms of CO2, N2, O2, CH4, and Ar on a variety of sorbents. This information is useful for analysis of existing hardware and design of new processes.

  4. Photolytic production of CO2 on Iapetus

    NASA Astrophysics Data System (ADS)

    Palmer, Eric; Brown, R. H.

    2008-09-01

    Carbon Dioxide has been detected on the surface of Iapetus by Cassini's VIMS instrument at the 4.26 micron band. This CO2 is concentrated on the equatorial leading side, where we also see an abundance of dark material. The residence time of free CO2 on the surface of Iapetus is very short, thus the CO2 is unlikely to be in the form of frost; it is more likely that the CO2 is tightly bound in the form of complexed molecules. We explore the possibility of photolytically generating CO2 from a mixture of the carbon rich material and water ice that matches the expected composition of the dark material on Iapetus' surface. An ice regolith was created with flash frozen water that was crushed into sub-millimeter shards and mixed with amorphous 13C. The regolith was placed in a vacuum chamber with a surface area of 10 cm2 and a thickness of 2 cm and exposed to UV light from a deuterium lamp with peaks of flux centered around 121 and 160 nm. Temperatures were varied between 60 and 130K at a pressure of 10-8 torr. Both CO and CO2 were produced by photolytic reactions and detected by a mass spectrometer. Applying these results to Iapetus, Jeans escape calculations show that CO2 generated by photolysis will remain gravitationally bound to Iapetus for between 100 and 200 years, ballistically scattering across the surface until it is sequestered in a polar cold trap or escapes to space. The average particle will interact with the surface more than 1000 times before escaping unless interactions with surface grains causes it to become complexed, such as adsorption. We are continuing to evaluate the photochemistry for this simulated Iapetus surface using a Nicolet IR spectrometer to identify all the products generated and estimate the associated production rate.

  5. CO(2) Fixation in Opuntia Roots.

    PubMed

    Ting, I P; Dugger, W M

    1966-03-01

    Nonautotrophic CO(2) metabolism in Opuntia echinocarpa roots was studied with techniques of manometry and radiometry. The roots were grown in a one-quarter strength nutrient solution for several days; the distal 2 cm was used for physiological studies. The roots assimilated significant quantities of (14)CO(2) and appeared to show a crassulacean-type acid metabolism with respect to quality and quantity. Most of the (14)C activity was associated with the distal portion of the elongating root indicating correlation with metabolic activity. The (14)CO(2) assimilation was comparable to a crassulacean leaf succulent, but 3 times greater than that found for stem tissue of the same Opuntia species.The rates of O(2) and CO(2) exchange and estimated CO(2) fixation were 180, 123, and 57 mul/g per hour. A respiratory quotient of 0.66 was found.The products of (14)CO(2) fixation were similar in most respects to reported experiments with leaf succulents. Equilibration of the predominant malic acid with isocitric, succinic, and fumaric acids was not evident. The latter observation was interpreted as metabolic isolation of the fixation products rather than poor citric acid cycle activity.A rapid turnover of the fixed (14)CO(2) was measured by following decarboxlyation kinetics and by product analysis after a postincubation period. The first order rate constant for the steady state release was 4.4 x 10(-3) min(-1) with a half-time of 157.5 minutes. Amino acids decayed at a more rapid rate than organic acids.

  6. Carbon Dioxide Clusters: (CO_2)_6 to (CO_2)13

    NASA Astrophysics Data System (ADS)

    McKellar, A. R. W.; Oliaee, J. Norooz; Dehghany, M.; Moazzen-Ahmadi, N.

    2011-06-01

    We recenty reported assignments of specific infrared bands in the CO_2 νb{3} region (˜2350 wn) to (CO_2)_6, (CO_2)_7, (CO_2)_9, (CO_2)10, (CO_2)11, (CO_2)12, and (CO_2)13. Spectra are obtained by direct absorption using a rapid-scan tuneable diode laser spectrometer to probe a pulsed supersonic slit-jet expansion and assignments are facilitated by recent calculations of Takeuchi based on the Murthy potential. (CO_2)_6 is a symmetric top with S_6 point group symmetry which can be thought of as a stack of two planar cyclic trimers. (CO_2)13 is also an S_6 symmetric top, and consists of a single CO_2 monomer surrounded by an slightly distorted icosahedral cage. The remaining clusters are asymmetric tops without symmetry. Here we report additional CO_2 cluster results. Calculations based on the SAPT-s potential indicate that the structure of (CO_2)10 may be slightly different from that given by Takeuchi/Murthy. An additional band is observed for each of (CO_2)13 and (CO_2)10. A feature observed at 2378.2 wn is assigned as a (CO_2)_6 parallel combination band involving the sum of a fundamental and a low-lying intermolecular vibration. Most significantly, two bands are assigned to a second isomer of (CO_2)_6. This is also a symmetric top, but now with S_4 symmetry. The two symmetric hexamer isomers observed spectroscopically correspond well with the lowest energy structures given by both the SAPT-s and Murthy intermolecular potentials. [1] J. Norooz Oliaee, M. Dehgany, N. Moazzen-Ahmadi, and A.R.W. McKellar, Phys. Chem. Chem. Phys. 13, 1297 (2011). [2] H. Takeuchi, J. Phys. Chem. A 107, 5703 (2008); C.S. Murthy, S.F. O'Shea, and I.R. McDonald, Mol. Phys. 50, 531 (1983). [3] R. Bukowski, J. Sadlej, B. Jeziorski, P. Jankowski, K. Szalewicz, S.A. Kucharski, H.L. Williams, and B.M. Rice, J. Chem. Phys. 110, 3785 (1999)

  7. Tunable diode laser absorption spectroscopy on 2.05 μm for the CO2 concentration measurement

    NASA Astrophysics Data System (ADS)

    Pranovich, Alina; Divoky, Martin; Prochazka, Ivan; Mocek, Tomas

    2015-05-01

    An experimental setup for the CO2 concentration measurement operating at 2.05 μm in pulsed mode and its characterization are presented. The system consists of a light source, which is a tunable laser diode operating in pulse mode. The initial radiation from the diode laser is divided into two parts: the first part of the beam is directed to a retro reflector, and the second part is used for diode output power monitoring. The receiving system consists of a focusing optic and a photodiode. The absorption is determined by comparing the intensities of the detected light on wavelengths absorbed and not absorbed by CO2 molecules. The prospects of the system change to a differential absorption lidar (DIAL) with a parametric generator as a light source that increases precision and range of generated wavelengths up to 10 μm are outlined.

  8. CO2 and CO Simulations and Their Source Signature Indicated by CO/CO2

    NASA Technical Reports Server (NTRS)

    Kawa, Randy; Huisheng, Bian

    2004-01-01

    Three years (2000-2002) atmospheric CO2 and CO fields are simulated by a Chemistry Transport Model driven by the assimilated meteorological fields from GEOS-4. The simulated CO2 and CO are evaluated by measurements from surface (CMDL), satellite (MOPITT/CO), and aircraft. The model-observation comparisons indicate reasonable agreement in both source and remote regions, and in the lower and upper troposphere. The simulation also captures the seasonality of CO2 and CO variations. The ratios of CO/CO2 are analyzed over different representative regions to identify the source signature, since the anthropogenic CO comes fiom the same combustion processes as CO2. This work enables us to improve satellite inversion estimates of CO2 sources and sinks by simultaneously using satellite CO measurement.

  9. DIAL: A Platform for real-time Laboratory Surveillance

    PubMed Central

    Mukhi, Shamir N; May-Hadford, Jennifer; Plitt, Sabrina; Preiksaitis, Jutta; Lee, Bonita

    2010-01-01

    Laboratory information systems fulfill many of the requirements for individual result management within a public health laboratory. However, access to the systems by data users, timely data extraction, integration, and data analysis are difficult tasks. These difficulties are further complicated by often having multiple laboratory results for specific analytes or related analytes per specimen tested as part of complex laboratory algorithms requiring specialized expertise for result interpretation. We describe DIAL, (Data Integration for Alberta Laboratories), a platform allowing laboratory data to be extracted, interpreted, collated and analyzed in near real-time using secure web based technology, which is adapted from CNPHI’s Canadian Early Warning System (CEWS) technology. The development of DIAL represents a major technical advancement in the public health information management domain, building capacity for laboratory based surveillance. PMID:23569594

  10. Early detection of small forest fire by dial technique

    NASA Astrophysics Data System (ADS)

    Bellecci, C.; Francucci, M.; Gaudio, P.; Gelfusa, M.; Martellucci, S.; Richetta, M.

    2005-10-01

    Forest fires can be the cause of serious environmental and economic damages. For this reason considerable effort has been directed toward forest protection and fire fighting. The means traditionally used for early fire detection mainly consist in human observers dispersed over forest regions. A significant improvement in early warning capabilities could be obtained by using automatic detection apparatus. In order to early detect small forest fires, the use of a dial system will be considered. A first evaluation of the lowest detectable concentration will be estimated by a numerical simulation. The theoretical model will be used also to get the capacities of a dial system in fire surveillance of wooded areas. Fixing the burning rate for several fuels, the maximum range of detection will be evaluated. The results of these simulations will be reported in the paper.

  11. Monitoring of near surface CO2

    NASA Astrophysics Data System (ADS)

    Faber, E.; Möller, I.; Teschner, M.; Poggenburg, J.; Spickenbom, K.; Schulz, H. J.

    2009-04-01

    Monitoring of near surface CO2 ECKHARD FABER1, INGO MÖLLER1, MANFRED TESCHNER1, JÜRGEN POGGENBURG1, KAI SPICKENBOM1, HANS-MARTIN SCHULZ1,2 1Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Stilleweg 2, D-30655 Hannover, e.faber@bgr.de 2present adress: GeoForschungsZentrum Potsdam (GFZ), Telegrafenberg, D-14473 Potsdam Underground gas storage and sequestration of carbon dioxide is one of the methods to reduce the input of antropogenic CO2 into the atmosphere and its greenhouse effect. Storage of CO2 is planned in depleted reservoirs, in aquifers and in salt caverns. Storage sites must have very small leakage rates to safely store the CO2 for centuries. Thus, a careful investigation and site selection is crucial. However, any leakage of CO2 to the surface is potentially dangerous for humans and environment. Therefore, instruments and systems for the detection of any CO2 escaping the storage sites and reaching the atmosphere have to be developed. Systems to monitor gases in deep wells, groundwater and surface sediments for leaking CO2 are developed, tested and are contnuously improved. Our group is mainly analysing CO2 in shallow (down to 3 m) soil samples using automatically operating monitoring systems. The systems are equipped with sensors to measure CO2 (and other gases) concentrations and other environmental parameters (atmospheric pressure, ambient and soil temperatures, etc.). Data are measured in short intervals (minute to subminute), are stored locally and are transferred by telemetrical systems into the BGR laboratory (Weinlich et al., 2006). In addition to soil gases monitoring systems technical equipment is available for continuous underwater gas flow measurements. Several of those monitoring systems are installed in different areas like Czech Republic, Austria, Italy and Germany. To detect any leaking gas from a sequestration site after CO2 injection, the naturally existing CO2 concentration (before injection) must be known. Thus, the natural

  12. CO2 flux estimation accuracy evaluation of Global and Regional atmospheric CO2 mission concepts

    NASA Astrophysics Data System (ADS)

    Lee, M.; Miller, C.; Weidner, R. J.; Duren, R. M.; Sander, S.; Eldering, A.

    2012-12-01

    We developed an observing system simulation experiment (OSSE) framework to evaluate mission-science-return quantitatively as a function of instrument payload, observation frequency, orbit, and sampling strategy for space-based remote sensing. The OSSE framework integrates GEOSChem and its adjoint system to perform forward/inverse modeling of the simulated measurements. During 2011-2012, we extended the OSSE framework to evaluate CO2 mission concepts in collaboration with the NASA's carbon monitoring system (CMS) flux pilot project team. In this paper, we employ the OSSE framework to analyze the science impact of multiple, simultaneous space-based column CO2 observations from simulated combinations of GOSAT, OCO-2, OCO-3, and a geo-stationary mission concept (GEOFTS). The OSSE process involved generating a CO2 concentration forecast, sampling the CO2 field at the appropriate time and location for each satellite sensor, incorporating realistic cloud climatologies to generate accurate clear-sky viewing statistics, retrieving CO2 profile simulaton in the presence of measurement noise, and finally assimilating the simulated column CO2 retrievals to estimate CO2 fluxes and flux uncertainty reductions. The OSSE process was applied over one-year-long mission period (2009/Jan - 2009/Dec) and the CO2 flux estimation error was analyzed to compute the probability density function (PDF) of CO2 flux estimation-error-reduction. The global OSSEs were performed in 2deg x 2.5 deg spatial resolution with the monthly-average CO2 flux estimation-error-reduction as the science-impact metric. Regional OSSEs were performed in 0.5 deg by 0.666 deg over N. America and the weekly average of the CO2 flux estimation-error-reduction was employed as the science-impact metric. We discuss the results and the projected performance of planned and potential space-based CO2 observing systems.

  13. Direct Copolymerization of CO2 and Diols.

    PubMed

    Tamura, Masazumi; Ito, Kazuki; Honda, Masayoshi; Nakagawa, Yoshinao; Sugimoto, Hiroshi; Tomishige, Keiichi

    2016-01-01

    Direct polymerization of CO2 and diols is promising as a simple and environmental-benign method in place of conventional processes using high-cost and/or hazardous reagents such as phosgene, carbon monoxide and epoxides, however, there are no reports on the direct method due to the inertness of CO2 and severe equilibrium limitation of the reaction. Herein, we firstly substantiate the direct copolymerization of CO2 and diols using CeO2 catalyst and 2-cyanopyridine promotor, providing the alternating cooligomers in high diol-based yield (up to 99%) and selectivity (up to >99%). This catalyst system is applicable to various diols including linear C4-C10 α,ω-diols to provide high yields of the corresponding cooligomers, which cannot be obtained by well-known methods such as copolymerization of CO2 and cyclic ethers and ring-opening polymerization of cyclic carbonates. This process provides us a facile synthesis method for versatile polycarbonates from various diols and CO2 owing to simplicity of diols modification. PMID:27075987

  14. The supply chain of CO2 emissions

    PubMed Central

    Davis, Steven J.; Peters, Glen P.; Caldeira, Ken

    2011-01-01

    CO2 emissions from the burning of fossil fuels are conventionally attributed to the country where the emissions are produced (i.e., where the fuels are burned). However, these production-based accounts represent a single point in the value chain of fossil fuels, which may have been extracted elsewhere and may be used to provide goods or services to consumers elsewhere. We present a consistent set of carbon inventories that spans the full supply chain of global CO2 emissions, finding that 10.2 billion tons CO2 or 37% of global emissions are from fossil fuels traded internationally and an additional 6.4 billion tons CO2 or 23% of global emissions are embodied in traded goods. Our results reveal vulnerabilities and benefits related to current patterns of energy use that are relevant to climate and energy policy. In particular, if a consistent and unavoidable price were imposed on CO2 emissions somewhere along the supply chain, then all of the parties along the supply chain would seek to impose that price to generate revenue from taxes collected or permits sold. The geographical concentration of carbon-based fuels and relatively small number of parties involved in extracting and refining those fuels suggest that regulation at the wellhead, mine mouth, or refinery might minimize transaction costs as well as opportunities for leakage. PMID:22006314

  15. Direct CO2-Methanation of flue gas

    NASA Astrophysics Data System (ADS)

    Müller, Klaus; Fleige, Michael; Rachow, Fabian; Israel, Johannes; Schmeißer, Dieter

    2013-04-01

    Already discovered by Paul Sabatier in 1902 the Hydrogenation according to CO2 + 4H2 ->CH4 + 2H2O nowadays is discussed in the course of the "Power-to-Gas" approach to utilize excess energy from renewable electricity generation in times of oversupply of electricity. We investigate the behavior of this process in a simulated flue gas atmosphere of conventional base load power plants, which could be used as constant sources of the reactant CO2. In relation to an approach related to carbon capture and cycling, the conversion of CO2 directly from the flue gas of a conventional power plant is a new aspect and has several advantages: The conversion of CO2 into methane could be integrated directly into the combustion process. Even older power plants could be upgraded and used as a possible source for CO2, in the same sense as the amine cleaning of flue gas, as a post combustion process. Further, waste heat of the power plant could be used as process energy for the catalytic reaction. Therefore the influence of different flue gas compositions such as varying contents of nitrogen and residual oxygen are tested in a laboratory scale. The heterogeneous catalysis process is investigated with regard to conversion rates, yield and selectivity and long-term stability of the Ni-catalyst. Also the influence of typical contaminations like SO2 is investigated and will be presented.

  16. Direct Copolymerization of CO2 and Diols

    PubMed Central

    Tamura, Masazumi; Ito, Kazuki; Honda, Masayoshi; Nakagawa, Yoshinao; Sugimoto, Hiroshi; Tomishige, Keiichi

    2016-01-01

    Direct polymerization of CO2 and diols is promising as a simple and environmental-benign method in place of conventional processes using high-cost and/or hazardous reagents such as phosgene, carbon monoxide and epoxides, however, there are no reports on the direct method due to the inertness of CO2 and severe equilibrium limitation of the reaction. Herein, we firstly substantiate the direct copolymerization of CO2 and diols using CeO2 catalyst and 2-cyanopyridine promotor, providing the alternating cooligomers in high diol-based yield (up to 99%) and selectivity (up to >99%). This catalyst system is applicable to various diols including linear C4-C10 α,ω-diols to provide high yields of the corresponding cooligomers, which cannot be obtained by well-known methods such as copolymerization of CO2 and cyclic ethers and ring-opening polymerization of cyclic carbonates. This process provides us a facile synthesis method for versatile polycarbonates from various diols and CO2 owing to simplicity of diols modification. PMID:27075987

  17. Atmospheric CO2 stabilization and ocean acidification

    NASA Astrophysics Data System (ADS)

    Cao, Long; Caldeira, Ken

    2008-10-01

    We use a coupled climate/carbon-cycle model to examine the consequences of stabilizing atmospheric CO2 at different levels for ocean chemistry. Our simulations show the potential for major damage to at least some ocean ecosystems at atmospheric CO2 stabilization levels as low as 450 ppm. Before the industrial revolution, more than 98% of corals reefs were surrounded by waters that were >3.5 times saturated with respect to their skeleton materials (aragonite). If atmospheric CO2 is stabilized at 450 ppm only 8% of existing coral reefs will be surrounded by water with this saturation level. Also at this CO2 level 7% of the ocean South of 60°S will become undersaturated with respect to aragonite, and parts of the high latitude ocean will experience a decrease in pH by more than 0.2 units. Results presented here provide an independent and additional basis for choosing targets of atmospheric CO2 stabilization levels.

  18. Direct Copolymerization of CO2 and Diols

    NASA Astrophysics Data System (ADS)

    Tamura, Masazumi; Ito, Kazuki; Honda, Masayoshi; Nakagawa, Yoshinao; Sugimoto, Hiroshi; Tomishige, Keiichi

    2016-04-01

    Direct polymerization of CO2 and diols is promising as a simple and environmental-benign method in place of conventional processes using high-cost and/or hazardous reagents such as phosgene, carbon monoxide and epoxides, however, there are no reports on the direct method due to the inertness of CO2 and severe equilibrium limitation of the reaction. Herein, we firstly substantiate the direct copolymerization of CO2 and diols using CeO2 catalyst and 2-cyanopyridine promotor, providing the alternating cooligomers in high diol-based yield (up to 99%) and selectivity (up to >99%). This catalyst system is applicable to various diols including linear C4-C10 α,ω-diols to provide high yields of the corresponding cooligomers, which cannot be obtained by well-known methods such as copolymerization of CO2 and cyclic ethers and ring-opening polymerization of cyclic carbonates. This process provides us a facile synthesis method for versatile polycarbonates from various diols and CO2 owing to simplicity of diols modification.

  19. CO2-Binding-Organic-Liquids-Enhanced CO2 Capture using Polarity-Swing-Assisted Regeneration

    SciTech Connect

    Zhang, Jian; Kutnyakov, Igor; Koech, Phillip K.; Zwoster, Andy; Howard, Chris; Zheng, Feng; Freeman, Charles J.; Heldebrant, David J.

    2013-01-01

    A new solvent-based CO2 capture process couples the unique attributes of non-aqueous, CO2-binding organic liquids (CO2BOLs) with the newly discovered polarity-swing-assisted regeneration (PSAR) process that is unique to switchable ionic liquids. Laboratory measurements with PSAR indicate the ability to achieve a regeneration effect at 75°C comparable to that at 120°C using thermal regeneration only. Initial measurements also indicate that the kinetic behavior of CO2 release is also improved with PSAR. Abstract cleared PNWD-SA-9743

  20. Light-duty vehicle CO2 targets consistent with 450 ppm CO2 stabilization.

    PubMed

    Winkler, Sandra L; Wallington, Timothy J; Maas, Heiko; Hass, Heinz

    2014-06-01

    We present a global analysis of CO2 emission reductions from the light-duty vehicle (LDV) fleet consistent with stabilization of atmospheric CO2 concentration at 450 ppm. The CO2 emission reductions are described by g CO2/km emission targets for average new light-duty vehicles on a tank-to-wheel basis between 2010 and 2050 that we call CO2 glide paths. The analysis accounts for growth of the vehicle fleet, changing patterns in driving distance, regional availability of biofuels, and the changing composition of fossil fuels. New light-duty vehicle fuel economy and CO2 regulations in the U.S. through 2025 and in the EU through 2020 are broadly consistent with the CO2 glide paths. The glide path is at the upper end of the discussed 2025 EU range of 68-78 g CO2/km. The proposed China regulation for 2020 is more stringent than the glide path, while the 2017 Brazil regulation is less stringent. Existing regulations through 2025 are broadly consistent with the light-duty vehicle sector contributing to stabilizing CO2 at approximately 450 ppm. The glide paths provide long-term guidance for LDV powertrain/fuel development. PMID:24798684

  1. Surface CO2 leakage during the first shallow subsurface CO2release experiment

    SciTech Connect

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2007-09-15

    A new field facility was used to study CO2 migrationprocesses and test techniques to detect and quantify potential CO2leakage from geologic storage sites. For 10 days starting 9 July 2007,and for seven days starting 5 August 2007, 0.1 and 0.3 t CO2 d-1,respectively, were released from a ~;100-m long, sub-water table (~;2.5-mdepth) horizontal well. The spatio-temporal evolution of leakage wasmapped through repeated grid measurements of soil CO2 flux (FCO2). Thesurface leakage onset, approach to steady state, and post-release declinematched model predictions closely. Modeling suggested that minimal CO2was taken up by groundwater through dissolution, and CO2 spread out ontop of the water table. FCO2 spatial patterns were related to well designand soil physical properties. Estimates of total CO2 discharge along withsoil respiration and leakage discharge highlight the influence ofbackground CO2 flux variations on detection of CO2 leakagesignals.

  2. Efficient 1.6 Micron Laser Source for Methane DIAL

    NASA Technical Reports Server (NTRS)

    Shuman, Timothy; Burnham, Ralph; Nehrir, Amin R.; Ismail, Syed; Hair, Johnathan W.

    2013-01-01

    Methane is a potent greenhouse gas and on a per molecule basis has a warming influence 72 times that of carbon dioxide over a 20 year horizon. Therefore, it is important to look at near term radiative effects due to methane to develop mitigation strategies to counteract global warming trends via ground and airborne based measurements systems. These systems require the development of a time-resolved DIAL capability using a narrow-line laser source allowing observation of atmospheric methane on local, regional and global scales. In this work, a demonstrated and efficient nonlinear conversion scheme meeting the performance requirements of a deployable methane DIAL system is presented. By combining a single frequency 1064 nm pump source and a seeded KTP OPO more than 5 mJ of 1.6 µm pulse energy is generated with conversion efficiencies in excess of 20%. Even without active cavity control instrument limited linewidths (50 pm) were achieved with an estimated spectral purity of 95%. Tunable operation over 400 pm (limited by the tuning range of the seed laser) was also demonstrated. This source demonstrated the critical needs for a methane DIAL system motivating additional development of the technology.

  3. Indoor radon and lung cancer in radium-dial workers

    SciTech Connect

    Neuberger, J.S.; Rundo, J.

    1996-12-31

    Internally deposited radium has long been known to have tumorigenic effects in the form of sarcomas of the bone and carcinomas of the paranasal sinuses and mastoid air cells. However, radium-dial workers were also exposed to radiation hazards other than that occurring from ingestion of the radium paint, namely, external gamma radiation and elevated concentrations of airborne radon. Uranium miners were also exposed to high concentrations of radon in the 1950s and later and numerous cases of lung cancer have occurred in that population. However, unlike the atmosphere in the uranium mines, the air in the dial painting plants was probably rather clean and perhaps not much different from the air in many houses. In view of the current concern over the possibility of lung cancer in the general population being caused by radon (progeny) in houses, it is important to examine the mortality due to this usually fatal disease in the dial workers and to attempt to relate it to their exposure to radon, to the extent that is possible.

  4. Indoor radon and lung cancer in the radium dial workers

    SciTech Connect

    Neuberger, J.S.; Rundo, J.

    1996-12-31

    Internally deposited radium has long been known to have tumorigenic effects in the form of sarcomas of the bone and carcinomas of the paranasal sinuses and mastoid air cells. However, the radium dial workers were also exposed to radiation hazards other than that occurring from ingestion of the radium paint, viz., external gamma radiation and elevated concentrations of airborne radon. The uranium miners were also exposed to high concentrations of radon in the 1950s and later, and numerous cases of lung cancer have occurred in that population. However, unlike the atmosphere in the uranium mines, the air in the dial painting plants was probably rather clean and perhaps not much different from the air in many houses. In view of the current concern over the possibility of lung cancer fin the general population being caused by radon (progeny) in houses, it is important to examine the mortality due to this usually fatal disease in the dial workers and to attempt to relate it to their exposure to radon, to the extent that this is possible.

  5. Oxygen isotope fractionation in stratospheric CO2

    NASA Technical Reports Server (NTRS)

    Thiemens, M. H.; Jackson, T.; Mauersberger, K.; Schueler, B.; Morton, J.

    1991-01-01

    A new cryogenic collection system has been flown on board a balloon gondola to obtain separate samples of ozone and carbon dioxide without entrapping major atmospheric gases. Precision laboratory isotopic analysis of CO2 samples collected between 26 and 35.5 km show a mass-independent enrichment in both O-17 and O-18 of about 11 per mil above tropospheric values. Ozone enrichment in its heavy isotopes was 9 to 16 percent in O3-50 and 8 to 11 percent in O3-49, respectively (Schueler et al., 1990). A mechanism to explain the isotope enrichment in CO2 has been recently proposed by Yung et al. (1991). The model is based on the isotope exchange between CO2 and O3 via O(1D), resulting in a transfer of the ozone isotope enrichment to carbon dioxide. Predicted enrichment and measured values agree well.

  6. CO2 mitigation via accelerated limestone weathering

    USGS Publications Warehouse

    Rau, G.H.; Knauss, K.G.; Langer, W.H.; Caldeira, K.

    2004-01-01

    Accelerated weathering of limestone (AWL: CO22+ + CaCO3 + H2O ??? Ca2+ + 2HCO3- as a low-tech, inexpensive, high-capacity, environmentally-friendly CO2 capture and sequestration technology was evaluated. With access to seawater and limestone being essential to this approach, significant limestone resources were close to most CO2-emitting power plants along the coastal US. Waste fines, representing > 20% of current US crushed limestone production (> 109 tons/yr), could be used as an inexpensive source of AWL carbonate. AWL end-solution disposal in the ocean would significantly reduce effects on ocean pH and carbonate chemistry relative to those caused by direct atmospheric or ocean CO2 disposal. Indeed, the increase in ocean Ca2+ and bicarbonate offered by AWL should enhance growth of corals and other calcifying marine organisms.

  7. Sequestration of CO2 by concrete carbonation.

    PubMed

    Galan, Isabel; Andrade, Carmen; Mora, Pedro; Sanjuan, Miguel A

    2010-04-15

    Carbonation of reinforced concrete is one of the causes of corrosion, but it is also a way to sequester CO2. The characteristics of the concrete cover should ensure alkaline protection for the steel bars but should also be able to combine CO2 to a certain depth. This work attempts to advance the knowledge of the carbon footprint of cement. As it is one of the most commonly used materials worldwide, it is very important to assess its impact on the environment. In order to quantify the capacity of cement based materials to combine CO2 by means of the reaction with hydrated phases to produce calcium carbonate, Thermogravimetry and the phenolphthalein indicator have been used to characterize several cement pastes and concretes exposed to different environments. The combined effect of the main variables involved in this process is discussed. The moisture content of the concrete seems to be the most influential parameter. PMID:20225850

  8. Geophysical monitoring of near surface CO2 injection at Svelvik - Learnings from the CO2FieldLab experiments.

    NASA Astrophysics Data System (ADS)

    Querendez, Etor; Romdhane, Anouar; Jordan, Michael; Eliasson, Peder; Grimstad, Alv-Arne

    2014-05-01

    A CO2 migration field laboratory for testing monitoring methods and tools has been established in the glaciofluvial-glaciomarine Holocene deposits of the Svelvik ridge, near Oslo (Norway). At the site, feasibility, sensitivity, acquisition geometry and usefulness of various surface and subsurface monitoring tools are investigated during controlled CO2 injection experiments. In a first stage, a shallow CO2 injection experiment was conducted in September 2011. Approximately 1700 kg of CO2 was injected at 18 m depth below surface in an unconsolidated sand formation. The objectives of this experiment were to (i) detect and, where possible, quantify migrated CO2 concentrations at the surface and very shallow subsurface, (ii) evaluate the sensitivity of the monitoring tools and (iii) study the impact of the vadose zone on observed measurements. Results showed that all deployed monitoring tools (for surface and near-surface gas monitoring, subsurface water monitoring and subsurface geophysical monitoring) where able to detect the presence of CO2 even though the CO2 plume did not migrate vertically as expected in what was thought to be an homogeneous unconsolidated sand structure. The upper part of the site revealed to be more heterogeneous than expected, mainly due to the highly variable lamination and channelling of the morainic sediments and to the presence of pebble and cobble beds sporadically showing throughout the deposits. Building on the learnings from the 18m depth injection experiment, a second experiment is being planned for a deeper injection, at a depth of 65m. Re-processing of the appraisal 2D multi-channel seismic with state-of-the-art processing techniques, like Linear Radon coherent and random noise attenuation and Full Waveform Inversion followed by pre-stack depth migration, corroborate the presence of heterogeneities at the near surface. Based on the re-interpreted seismic sections, a more realistic 3D geomodel, where the complex topography of the site

  9. CO2 Orbital Trends in Comets

    NASA Astrophysics Data System (ADS)

    Kelley, Michael; Bodewits, Dennis; Feaga, Lori; Knight, Matthew; McKay, Adam; Snodgrass, Colin; Wooden, Diane

    2016-08-01

    Carbon dioxide is a primary volatile in comet nuclei, and potentially a major contributor to comet activity (i.e., the process of mass loss). However, CO2 cannot be observed directly from the ground, and past surveys of this molecule in comets were limited to space-borne snapshot observations. This situation limits our understanding of the behavior of CO2 in comets, and its role in driving comet mass loss. To address this deficiency, we were awarded a Cy11 Spitzer program designed to quantify the production rate of CO2 on >month-long timescales for 21 comets. We request an additional 269~hr in Cy13 to complete the Spitzer portion of our survey, and to add three more comets (46P/Wirtanen and 2 Target of Opportunity Oort cloud comets). Our survey is designed to probe the orbital trends of CO2 production in the comet population. We aim to: 1) examine the role of CO2 in the persistent post-perihelion activity observed in Jupiter-family comets; 2) measure the seasonal variations of CO2/H2O as a proxy for nucleus heterogeneity, when possible; 3) search for orbital trends sensitive to cumulative insolation as a proxy for nucleus layering; and 4) examine how Oort cloud comets evolve by comparing dynamically new and old targets. The final data set will allow us to investigate the effects of heating on the evolution of comets, if nucleus structures can be inferred through activity, and set the stage for JWST investigations into comet activity and composition.

  10. Why capture CO2 from the atmosphere?

    PubMed

    Keith, David W

    2009-09-25

    Air capture is an industrial process for capturing CO2 from ambient air; it is one of an emerging set of technologies for CO2 removal that includes geological storage of biotic carbon and the acceleration of geochemical weathering. Although air capture will cost more than capture from power plants when both are operated under the same economic conditions, air capture allows one to apply industrial economies of scale to small and mobile emission sources and enables a partial decoupling of carbon capture from the energy infrastructure, advantages that may compensate for the intrinsic difficulty of capturing carbon from the air.

  11. Why Capture CO2 from the Atmosphere?

    NASA Astrophysics Data System (ADS)

    Keith, David W.

    2009-09-01

    Air capture is an industrial process for capturing CO2 from ambient air; it is one of an emerging set of technologies for CO2 removal that includes geological storage of biotic carbon and the acceleration of geochemical weathering. Although air capture will cost more than capture from power plants when both are operated under the same economic conditions, air capture allows one to apply industrial economies of scale to small and mobile emission sources and enables a partial decoupling of carbon capture from the energy infrastructure, advantages that may compensate for the intrinsic difficulty of capturing carbon from the air.

  12. CO2 Acquisition Membrane (CAM) Project

    NASA Technical Reports Server (NTRS)

    Mason, L. W.; Way, J. D.; Vlasse, M.

    2001-01-01

    The CO2 Acquisition Membrane (CAM) project will develop, test, and analyze membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The CAM technology will enable passive separation of these gases, allow energy efficient acquisition and purification of these important resources, and lay the foundation for future unmanned sample return and human space missions. The CAM membranes are targeted toward In Situ Resource Utilization (ISRU) applications, such as In Situ Propellant Production (ISPP) and In Situ Consumables Production (ISCP).

  13. CO2 laser cutting of natural granite

    NASA Astrophysics Data System (ADS)

    Riveiro, A.; Mejías, A.; Soto, R.; Quintero, F.; del Val, J.; Boutinguiza, M.; Lusquiños, F.; Pardo, J.; Pou, J.

    2016-01-01

    Commercial black granite boards (trade name: "Zimbabwe black granite") 10 mm thick, were successfully cut by a 3.5 kW CO2 laser source. Cutting quality, in terms of kerf width and roughness of the cut wall, was assessed by means of statistically planned experiments. No chemical modification of the material in the cutting walls was detected by the laser beam action. Costs associated to the process were calculated, and the main factors affecting them were identified. Results reported here demonstrate that cutting granite boards could be a new application of CO2 laser cutting machines provided a supersonic nozzle is used.

  14. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  15. Selective Oxytrifluoromethylation of Allylamines with CO2.

    PubMed

    Ye, Jian-Heng; Song, Lei; Zhou, Wen-Jun; Ju, Tao; Yin, Zhu-Bao; Yan, Si-Shun; Zhang, Zhen; Li, Jing; Yu, Da-Gang

    2016-08-16

    Reported is the first oxy-trifluoromethylation of allylamines with carbon dioxide (CO2 ) using copper catalysis, thus leading to important CF3 -containing 2-oxazolidones. It is also the first time CO2 , a nontoxic and easily available greenhouse gas, has been used to tune the difunctionalization of alkenes from amino- to oxy-trifluoromethylation. Of particular note, this multicomponent reaction is highly chemo-, regio-, and diastereoselective under redox-neutral and mild reaction conditions. Moreover, these reactions feature good functional-group tolerance, broad substrate scope, easy scalability and facile product diversification. The important products could also be formed with either spirocycles or two adjacent tetrasubstituted carbon centers. PMID:27411560

  16. Leak Path Development in CO2 Wells

    NASA Astrophysics Data System (ADS)

    Torsater, M.; Todorovic, J.; Opedal, N.; Lavrov, A.

    2014-12-01

    Wells have in numerous scientific works been denoted the "weak link" of safe and cost-efficient CO2 Capture and Storage (CCS). Whether they are active or abandoned, all wells are man-made intrusions into the storage reservoir with sealing abilities depending on degradable materials like steel and cement. If dense CO2 is allowed to expand (e.g. due to leakage) it will cool down its surroundings and cause strong thermal and mechanical loading on the wellbore. In addition, CO2 reacts chemically with rock, cement and steel. To ensure long-term underground containment, it is therefore necessary to study how, why, where and when leakage occurs along CO2wells. If cement bonding to rock or casing is poor, leak paths can form already during drilling and completion of the well. In the present work, we have mapped the bonding quality of cement-rock and cement-steel interfaces - and measured their resistance towards CO2 flow. This involved a large experimental matrix including different rocks, steels, cement types and well fluids. The bonding qualities were measured on composite cores using micro computed tomography (µ-CT), and CO2 was flooded through the samples to determine leakage rates. These were further compared to numerical simulations of leakage through the digitalized µ-CT core data, and CO2chemical interactions with the materials were mapped using electron microscopy. We also present a new laboratory set-up for measuring how well integrity is affected by downhole temperature variations - and we showcase some initial results. Our work concludes that leak path development in CO2 wells depends critically on the drilling fluids and presflushes/spacers chosen already during drilling and completion of a well. Fluid films residing on rock and casing surfaces strongly degrade the quality of cement bonding. The operation of the well is also important, as even slight thermal cycling (between 10°C and 95°C on casing) leads to significant de-bonding of the annular cement.

  17. High Power and Frequency-Agile Optical Parametric Oscillators for Airborne DIAL Measurements of CH4 and H2O

    NASA Astrophysics Data System (ADS)

    Nehrir, A. R.; Shuman, T.; Chuang, T.; Hair, J. W.; Refaat, T. F.; Ismail, S.; Kooi, S. A.; Notari, A.

    2014-12-01

    Atmospheric methane (CH4) has the second largest radiative forcing of the long-lived greenhouse gasses (GHG) after carbon dioxide. However, methane's much shorter atmospheric lifetime and much stronger warming potential make its radiative forcing equivalent to that for CO2 over a 20-year time horizon which makes CH4 a particularly attractive target for mitigation strategies. Similar to CH4, water vapor (H2O) is the most dominant of the short-lived GHG in the atmosphere and plays a key role in many atmospheric processes. Atmospheric H2O concentrations span over four orders of magnitude from the planetary boundary layer where high impact weather initiates to lower levels in the upper troposphere and lower stratosphere (UTLS) where water vapor has significant and long term impacts on the Earth's radiation budget. NASA Langley has fostered the technology development with Fibertek, Inc. to develop frequency agile and high power (> 3 W) pulsed lasers using similar architectures in the 1645 nm and 935 nm spectral bands for DIAL measurements of CH4 and H2O, respectively. Both systems utilize high power 1 kHz pulse repetition frequency Nd:YAG lasers to generate high power laser emission at the desired wavelength via optical parametric oscillators (OPO). The CH4 OPO, currently in its final build stage in a SBIR Phase II program has demonstrated >2 W average power with injection seeding from a distributed feedback (DFB) laser during risk reduction experiments. The H2O OPO has demonstrated high power operation (>2 W) during the SBIR Phase I program while being injection seeded with a DFB laser, and is currently funded via an SBIR Phase II to build a robust system for future integration into an airborne water vapor DIAL system capable of profiling from the boundary layer up to the UTLS. Both systems have demonstrated operation with active OPO wavelength control to allow for optimization of the DIAL measurements for operation at different altitudes and geographic regions. An

  18. Crystallization of CO2 ice and the absence of amorphous CO2 ice in space

    PubMed Central

    Escribano, Rafael M.; Muñoz Caro, Guillermo M.; Cruz-Diaz, Gustavo A.; Rodríguez-Lazcano, Yamilet; Maté, Belén

    2013-01-01

    Carbon dioxide (CO2) is one of the most relevant and abundant species in astrophysical and atmospheric media. In particular, CO2 ice is present in several solar system bodies, as well as in interstellar and circumstellar ice mantles. The amount of CO2 in ice mantles and the presence of pure CO2 ice are significant indicators of the temperature history of dust in protostars. It is therefore important to know if CO2 is mixed with other molecules in the ice matrix or segregated and whether it is present in an amorphous or crystalline form. We apply a multidisciplinary approach involving IR spectroscopy in the laboratory, theoretical modeling of solid structures, and comparison with astronomical observations. We generate an unprecedented highly amorphous CO2 ice and study its crystallization both by thermal annealing and by slow accumulation of monolayers from the gas phase under an ultrahigh vacuum. Structural changes are followed by IR spectroscopy. We also devise theoretical models to reproduce different CO2 ice structures. We detect a preferential in-plane orientation of some vibrational modes of crystalline CO2. We identify the IR features of amorphous CO2 ice, and, in particular, we provide a theoretical explanation for a band at 2,328 cm−1 that dominates the spectrum of the amorphous phase and disappears when the crystallization is complete. Our results allow us to rule out the presence of pure and amorphous CO2 ice in space based on the observations available so far, supporting our current view of the evolution of CO2 ice. PMID:23858474

  19. TES/Aura L2 Carbon Dioxide (CO2) Nadir (TL2CO2N)

    Atmospheric Science Data Center

    2015-01-30

    TES/Aura L2 Carbon Dioxide (CO2) Nadir (TL2CO2N) News:  TES News ... L2 Platform:  TES/Aura L2 Carbon Dioxide Spatial Coverage:  5.2 x 8.5 km nadir ... Subset Data: TES Order Tool Parameters:  Carbon Dioxide Order Data:  Reverb:   Order Data ...

  20. TES/Aura L2 Carbon Dioxide (CO2) Nadir (TL2CO2NS)

    Atmospheric Science Data Center

    2015-01-30

    TES/Aura L2 Carbon Dioxide (CO2) Nadir (TL2CO2NS) News:  TES News ... L2 Platform:  TES/Aura L2 Carbon Dioxide Spatial Coverage:  5.3 x 8.5 km nadir ... Subset Data: TES Order Tool Parameters:  Carbon Dioxide Order Data:  Reverb:   Order Data ...

  1. Correction of Doppler-broadened Rayleigh backscattering effects in H2O dial measurements

    NASA Technical Reports Server (NTRS)

    Ansmann, A.; Bosenberg, J.

    1986-01-01

    A general method of solutions for treating effects of Doppler-broadened Rayleigh backscattering in H2O Differential Absorption Lidar (DIAL) measurements are described and discussed. Errors in vertical DIAL measuremtns caused by this laser line broadening effect can be very large and, therfore, this effect has to be accounted for accurately. To analyze and correct effects of Doppler-broadened Rayleigh backscattering in DIAL experiments, a generalized DIAL approximation was derived starting from a lidar equation, which includes Doppler broadening. To evaluate the accuracy of H2O DIAL measurements, computer simulations were performed. It was concluded that correction of Doppler broadened Rayleigh backscattering is possible with good accuracy in most cases of tropospheric H2O DIAL measurements, but great care has to be taken when layers with steep gradients of Mie backscattering like clouds or inversion layers are present.

  2. CO2 dispersion modelling over Paris region within the CO2-MEGAPARIS project

    NASA Astrophysics Data System (ADS)

    Lac, C.; Donnelly, R. P.; Masson, V.; Pal, S.; Donier, S.; Queguiner, S.; Tanguy, G.; Ammoura, L.; Xueref-Remy, I.

    2012-10-01

    Accurate simulation of the spatial and temporal variability of tracer mixing ratios over urban areas is challenging, but essential in order to utilize CO2 measurements in an atmospheric inverse framework to better estimate regional CO2 fluxes. This study investigates the ability of a high-resolution model to simulate meteorological and CO2 fields around Paris agglomeration, during the March field campaign of the CO2-MEGAPARIS project. The mesoscale atmospheric model Meso-NH, running at 2 km horizontal resolution, is coupled with the Town-Energy Balance (TEB) urban canopy scheme and with the Interactions between Soil, Biosphere and Atmosphere CO2-reactive (ISBA-A-gs) surface scheme, allowing a full interaction of CO2 between the surface and the atmosphere. Statistical scores show a good representation of the Urban Heat Island (UHI) and urban-rural contrasts. Boundary layer heights (BLH) at urban, sub-urban and rural sites are well captured, especially the onset time of the BLH increase and its growth rate in the morning, that are essential for tall tower CO2 observatories. Only nocturnal BLH at sub-urban sites are slightly underestimated a few nights, with a bias less than 50 m. At Eiffel tower, the observed spikes of CO2 maxima occur every morning exactly at the time at which the Atmospheric Boundary Layer (ABL) growth reaches the measurement height. The timing of the CO2 cycle is well captured by the model, with only small biases on CO2 concentrations, mainly linked to the misrepresentation of anthropogenic emissions, as the Eiffel site is at the heart of trafic emission sources. At sub-urban ground stations, CO2 measurements exhibit maxima at the beginning and at the end of each night, when the ABL is fully contracted, with a very strong spatio-temporal variability. The CO2 cycle at these sites is generally well reproduced by the model, even if some biases on the nocturnal maxima appear in the Paris plume parly due to small errors on the vertical transport, or in

  3. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  4. CO2 adsorption isotherm on clay minerals and the CO2 accessibility into the clay interlayer

    NASA Astrophysics Data System (ADS)

    Gensterblum, Yves; Bertier, Pieter; Busch, Andreas; Rother, Gernot; Krooß, Bernhard

    2013-04-01

    Large-scale CO2 storage in porous rock formations at 1-3 km depth is seen as a global warming mitigation strategy. In this process, CO2 is separated from the flue gas of coal or gas power plants, compressed, and pumped into porous subsurface reservoirs with overlying caprocks (seals). Good seals are mechanically and chemically stable caprocks with low porosity and permeability. They prevent leakage of buoyant CO2 from the reservoir. Caprocks are generally comprised of thick layers of shale, and thus mainly consist of clay minerals. These clays can be affected by CO2-induced processes, such as swelling or dissolution. The interactions of CO2 with clay minerals in shales are at present poorly understood. Sorption measurements in combination scattering techniques could provide fundamental insight into the mechanisms governing CO2-clay interaction. Volumetric sorption techniques have assessed the sorption of supercritical CO2 onto coal (Gensterblum et al., 2010; Gensterblum et al., 2009), porous silica (Rother et al., 2012a) and clays as a means of exploring the potential of large-scale storage of anthropogenic CO2 in geological reservoirs (Busch et al., 2008). On different clay minerals and shales, positive values of excess sorption were measured at gas pressures up to 6 MPa, where the interfacial fluid is assumed to be denser than the bulk fluid. However, zero and negative values were obtained at higher densities, which suggests the adsorbed fluid becomes equal to and eventually less dense than the corresponding bulk fluid, or that the clay minerals expand on CO2 charging. Using a combination of neutron diffraction and excess sorption measurements, we recently deduced the interlayer density of scCO2 in Na-montmorillonite clay in its single-layer hydration state (Rother et al., 2012b), and confirmed its low density, as well as the expansion of the basal spacings. We performed neutron diffraction experiments at the FRMII diffractometer on smectite, kaolinite and illite

  5. Extraction of lipids from microalgae using CO2-expanded methanol and liquid CO2.

    PubMed

    Paudel, Ashok; Jessop, Michael J; Stubbins, Spencer H; Champagne, Pascale; Jessop, Philip G

    2015-05-01

    The use of CO2-expanded methanol (cxMeOH) and liquid carbon dioxide (lCO2) is proposed to extract lipids from Botryococcus braunii. When compressed CO2 dissolves in methanol, the solvent expands in volume, decreases in polarity and so increases in its selectivity for biodiesel desirable lipids. Solid phase extraction of the algal extract showed that the cxMeOH extracted 21 mg of biodiesel desirable lipids per mL of organic solvent compared to 3mg/mL using either neat methanol or chloroform/methanol mixture. The non-polar lCO2 showed a high affinity for non-polar lipids. Using lCO2, it is possible to extract up to 10% neutral lipids relative to the mass of dry algae. Unlike extractions using conventional solvents, these new methods require little to no volatile, flammable, or chlorinated organic solvents.

  6. Stereotactic CO2 laser therapy for hydrocephalus

    NASA Astrophysics Data System (ADS)

    Kozodoy-Pins, Rebecca L.; Harrington, James A.; Zazanis, George A.; Nosko, Michael G.; Lehman, Richard M.

    1994-05-01

    A new fiber-optic delivery system for CO2 radiation has been used to successfully treat non-communicating hydrocephalus. This system consists of a hollow sapphire waveguide employed in the lumen of a stereotactically-guided neuroendoscope. CO2 gas flows through the bore of the hollow waveguide, creating a path for the laser beam through the cerebrospinal fluid (CSF). This delivery system has the advantages of both visualization and guided CO2 laser radiation without the same 4.3 mm diameter scope. Several patients with hydrocephalus were treated with this new system. The laser was used to create a passage in the floor of the ventricle to allow the flow of CSF from the ventricles to the sub-arachnoid space. Initial postoperative results demonstrated a relief of the clinical symptoms. Long-term results will indicate if this type of therapy will be superior to the use of implanted silicone shunts. Since CO2 laser radiation at 10.6 micrometers is strongly absorbed by the water in tissue and CSF, damage to tissue surrounding the lesion with each laser pulse is limited. The accuracy and safety of this technique may prove it to be an advantageous therapy for obstructive hydrocephalus.

  7. 76 FR 43489 - Deferral for CO2

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-20

    ... dioxide CO 2 e carbon dioxide equivalents EO Executive Order EPA U.S. Environmental Protection Agency FR... as the Tailoring Rule; 75 FR 31514), setting thresholds for GHG emissions that define when permits... bioenergy and other biogenic sources (75 FR 41173). The purpose of this CFI was to request comment...

  8. Photoemission study of SmCo2

    NASA Astrophysics Data System (ADS)

    Kang, J.-S.; Yang, C. J.; Lee, Y. P.; Olson, C. G.; Cho, E.-J.; Oh, S.-J.; Anderson, R. O.; Liu, L. Z.; Park, J.-H.; Allen, J. W.; Ellis, W. P.

    1993-10-01

    The electronic structure of SmCo2 is investigated with photoemission spectroscopy (PES). All the PES spectra are consistent in showing that the bulk Sm ions are trivalent, but that the surface has divalent Sm ions and is probably inhomogeneously mixed valent. Both the Sm 4f valence band and Sm 3d core level PES spectra are found to be substantially broader than those of Sm metal. The observed larger linewidths for SmCo2, as compared to those of pure Sm metal, suggest a larger lifetime broadening, probably due to an increased number of valence-band electrons, and a larger 4f hybridization, mainly to Co 3d states. Weak satellite structures are observed in the Co 3d valence band and Co 2p core level PES spectra, indicating Co 3d correlation effects. The comparison of the experimental valence-band PES spectrum with the theoretical Co 3d projected local density of states also suggests that Co 3d correlation effects in SmCo2 are non-negligible.

  9. CO2 laser used in cosmetology

    NASA Astrophysics Data System (ADS)

    Su, Chenglie

    1993-03-01

    Cases of various kinds of warts, nevi, papillomas, skin angiomas, ephilises, skin vegetation, scars and brandy noses were vaporized and solidified with a 2.5 - 8 W low power CO2 laser with an overall satisfaction rate up to 99.8% and the satisfaction rate for one time 92%.

  10. CO 2 laser surgery in hemophilia treatment.

    PubMed

    Santos-Dias, A

    1992-08-01

    The use of CO 2 laser surgery between 1985 and 1991 in South Africa and Portugal for treatment of disorders in patients with mild to moderate cases of hemophilia A is discussed. Six cases of oral procedures and excision of skin tumors performed during this period are reported. In most of the cases of mild hemophilia no pre- or postoperative infusion of Factor VIII or desmopressin (DDAVP) was required. In some cases of moderate hemophilia, patients were infused with desmopressin (0.3 mug/kg body weight) and were treated postoperatively with the use of nasal desmopressin spray (150 mug to each nostril for four weeks following surgery). Factor VIII levels were measured before surgery. Follow up of four weeks was uneventful. The mean average power of the CO 2 laser was 20 W continuous and the pulse duration was 0.1 s for ablational procedures. For dermatologic procedures, a flexible plastic CO 2 laser hollow fiber was used (Flexilase, Sharplan, Allandale, NJ). We concluded that CO 2 laser surgery for hemophiliacs has a confirmed place in modern laser technology provided the standard precautions are taken and facilities are available.

  11. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  12. Uncooled receivers for CO2 laser radiation

    NASA Astrophysics Data System (ADS)

    Granovskii, A. B.; Iakovlev, V. A.

    1986-01-01

    Published data on low-inertia, uncooled, single-element and matrix-type radiation receivers that have a high degree of reliability and are immune from interference from various external sources are systematically summarized. Three basic types of receivers are examined: photonic receivers, thermal receivers, and receivers based on wave interaction. Principal attention is given to the CO2 laser radiation receiver.

  13. Blackbody-pumped CO2 laser experiment

    NASA Astrophysics Data System (ADS)

    Christiansen, W. H.; Insuik, R. J.

    1983-07-01

    Thermal radiation from a high temperature oven was used as an optical pump to achieve lasing from CO2 mixtures. Laser output as a function of blackbody temperature and gas conditions is described. This achievement represents the first blackbody cavity pumped laser and has potential for solar pumping. Previously announced in STAR as N83-10420

  14. Bosch CO2 Reduction System Development

    NASA Technical Reports Server (NTRS)

    Holmes, R. F.; King, C. D.; Keller, E. E.

    1976-01-01

    Development of a Bosch process CO2 reduction unit was continued, and, by means of hardware modifications, the performance was substantially improved. Benefits of the hardware upgrading were demonstrated by extensive unit operation and data acquisition in the laboratory. This work was accomplished on a cold seal configuration of the Bosch unit.

  15. CO2 laser in stapes surgery

    NASA Astrophysics Data System (ADS)

    Jovanovic, Sergije; Schoenfeld, Uwe; Berghaus, Andreas; Fischer, R.; Scherer, Hans H.

    1993-07-01

    Stapedotomy is not only one of the most successful interventions in otology but also one of the most dangerous for the inner ear. To reduce the risk of damaging middle and inner ear structures through manipulations with conventional instruments, the CO2 laser beam is used for perforating the footplate and removing the suprastructures. This non-contact technique aims at precise and controlled management of middle ear structures. Consideration is given to the impact of experimental data on the clinical application of the CO2 laser in stapes surgery. The discussion covers the advantages and disadvantages with regard to optical and tissue-related properties and points out possible dangers to the inner ear. Our experimental and clinical experience is taken as a basis for examining the surgical technique and the varying demands made on the laser beam in treating the stapedial tendon, crura and footplate. Attention is called to the need for additional instruments. Effective energy parameters for CO2 laser stapedeotomy are evaluated for different lasers. Application of the CO2 laser contributes towards optimization of this high-precision intervention and promises to reduce the incidence of inner ear damages in large numbers of cases. This technique appears useful particularly in difficult anatomic situations and, above all, for revisional operations.

  16. Artificial photosynthesis - CO2 towards methanol

    NASA Astrophysics Data System (ADS)

    Nazimek, D.; Czech, B.

    2011-03-01

    The new insight into the problem of carbon dioxide utilization into valuable compound - methanol and then its transformation into fuel is presented. Because the highly endothermic requirements of the reaction of CO2 hydrogenation a photocatalytic route is applied. Combining of the two reactions: water splitting and CO2 hydrogenation using H2O as a source of hydrogen at the same time and place are proposed. The studies over modified TiO2 catalysts supported on Al2O3 were conducted in a self-designed circulated photocatalytic reaction system under at room temperature and constant pressure. Experimental results indicated that the highest yield of the photoreduction of CO2 with H2O were obtained using TiO2 with the active anatase phase modified by Ru and WO3 addition. The conversion was very high - almost 97% of CO2 was transformed mainly into methanol (14%vol.) and into small amount of formic and acetic acid and ester.

  17. Agriculture waste and rising CO2

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Currently, there are many uncertainties concerning agriculture’s role in global environmental change including the effects of rising atmospheric CO2 concentration. A viable and stable world food supply depends on productive agricultural systems, but environmental concerns within agriculture have to...

  18. Laser Sounder for Measuring Atmospheric CO2 Concentrations: Progress Toward Ascends

    NASA Technical Reports Server (NTRS)

    Abshire, J. B.; Kawa, S. R.; Riris, H.; Allan, G. R.; Sun, X.; Stephen, M. A.; Wilson, E.; Burris, J. F.; Mao, J.

    2008-01-01

    the on and off-line singnals via the DIAL technique. We used pulsed laser signals, photon counting detectors, and time gating to isolate the laser returns from the surface, and to reject photons scattered from thin clouds and aerosols. High signal-to-noise ratios are required and the CO2 estimates can be sensitive to small drifts or other errors in the instrument, so the absorption estimates need to be quite stable for hours. We have constructed a breadboard version of the CO2 sensor that uses a low power fiber laser and a 20 cm diameter telescope. We have used it to make measurements of CO2 absorption in the laboratory and over 200-m to 2-km long open horizontal paths. These have been done in several sessions extending over multiple days, which allows us to assess the measurement stability and to compare absorption variations to readings from an external in situ CO2 sensor. We have also calculated characteristics of the technique for space including its expected measurement performance for different modulation types, and have performed an initial space mission accommodation study. We sill describe these results in the presentation.

  19. CO2 acquisition in Chlamydomonas acidophila is influenced mainly by CO2, not phosphorus, availability.

    PubMed

    Spijkerman, Elly; Stojkovic, Slobodanka; Beardall, John

    2014-09-01

    The extremophilic green microalga Chlamydomonas acidophila grows in very acidic waters (pH 2.3-3.4), where CO2 is the sole inorganic carbon source. Previous work has revealed that the species can accumulate inorganic carbon (Ci) and exhibits high affinity CO2 utilization under low-CO2 (air-equilibrium) conditions, similar to organisms with an active CO2 concentrating mechanism (CCM), whereas both processes are down-regulated under high CO2 (4.5 % CO2) conditions. Responses of this species to phosphorus (Pi)-limited conditions suggested a contrasting regulation of the CCM characteristics. Therefore, we measured external carbonic anhydrase (CAext) activities and protein expression (CAH1), the internal pH, Ci accumulation, and CO2-utilization in cells adapted to high or low CO2 under Pi-replete and Pi-limited conditions. Results reveal that C. acidophila expressed CAext activity and expressed a protein cross-reacting with CAH1 (the CAext from Chlamydomonas reinhardtii). Although the function of this CA remains unclear, CAext activity and high affinity CO2 utilization were the highest under low CO2 conditions. C. acidophila accumulated Ci and expressed the CAH1 protein under all conditions tested, and C. reinhardtii also contained substantial amounts of CAH1 protein under Pi-limitation. In conclusion, Ci utilization is optimized in C. acidophila under ecologically relevant conditions, which may enable optimal survival in its extreme Ci- and Pi-limited habitat. The exact physiological and biochemical acclimation remains to be further studied.

  20. Isolation of microorganisms from CO2 sequestration sites through enrichments under high pCO2

    NASA Astrophysics Data System (ADS)

    Peet, K. C.; Freedman, A. J.; Boreham, C.; Thompson, J. R.

    2012-12-01

    Carbon Capture and Storage (CCS) in geologic formations has the potential to reduce greenhouse gas emissions from fossil fuel processing and combustion. However, little is known about the effects that CO2 may have on biological activity in deep earth environments. To understand microorganisms associated with these environments, we have developed a simple high-pressure enrichment methodology to cultivate organisms capable of growth under supercritical CO2 (scCO2). Growth media targeting different subsurface functional metabolic groups is added to sterilized 316 stainless steel tubing sealed with quarter turn plug valves values and pressurized to 120-136 atm using a helium-padded CO2 tank, followed by incubation at 37 °C to achieve the scCO2 state. Repeated passages of crushed subsurface rock samples and growth media under supercritical CO2 headspaces are assessed for growth via microscopic enumeration. We have utilized this method to survey sandstone cores for microbes capable of growth under scCO2 from two different geologic sites targeted for carbon sequestration activities. Reproducible growth of microbial biomass under high pCO2 has been sustained from each site. Cell morphologies consist of primarily 1-2 μm rods and oval spores, with densities from 1E5-1E7 cells per ml of culture. We have purified and characterized a bacterial strain most closely related to Bacillus subterraneus (99% 16S rRNA identity) capable of growth under scCO2. Preliminary physiological characterization of this strain indicates it is a spore-forming facultative anaerobe able to grow in 0.5 to 50 ppt salinity. Genome sequencing and analysis currently in progress will help reveal genetic mechanisms of acclimation to high pCO2 conditions associated with geologic carbon sequestration.

  1. Vadose Zone Remediation of CO2 Leakage from Geologic CO2 Storage Sites

    SciTech Connect

    Zhang, Yingqi; Oldenburg, Curtis M.; Benson, Sally M.

    2004-03-03

    In the unlikely event that CO2 leakage from deep geologic CO2 sequestration sites reaches the vadose zone, remediation measures for removing the CO2 gas plume may have to be undertaken. Carbon dioxide leakage plumes are similar in many ways to volatile organic compound (VOC) vapor plumes, and the same remediation approaches are applicable. We present here numerical simulation results of passive and active remediation strategies for CO2 leakage plumes in the vadose zone. The starting time for the remediation scenarios is assumed to be after a steady-state CO2 leakage plume is established in the vadose zone, and the source of this plume has been cut off. We consider first passive remediation, both with and without barometric pumping. Next, we consider active methods involving extraction wells in both vertical and horizontal configurations. To compare the effectiveness of the various remediation strategies, we define a half-life of the CO2 plume as a convenient measure of the CO2 removal rate. For CO2 removal by passive remediation approaches such as barometric pumping, thicker vadose zones generally require longer remediation times. However, for the case of a thin vadose zone where a significant fraction of the CO2 plume mass resides within the high liquid saturation region near the water table, the half-life of the CO2 plume without barometric pumping is longer than for somewhat thicker vadose zones. As for active strategies, results show that a combination of horizontal and vertical wells is the most effective among the strategies investigated, as the performance of commonly used multiple vertical wells was not investigated.

  2. Sustained effects of atmospheric [CO2] and nitrogen availability on forest soil CO2 efflux.

    PubMed

    Oishi, A Christopher; Palmroth, Sari; Johnsen, Kurt H; McCarthy, Heather R; Oren, Ram

    2014-04-01

    Soil CO2 efflux (Fsoil ) is the largest source of carbon from forests and reflects primary productivity as well as how carbon is allocated within forest ecosystems. Through early stages of stand development, both elevated [CO2] and availability of soil nitrogen (N; sum of mineralization, deposition, and fixation) have been shown to increase gross primary productivity, but the long-term effects of these factors on Fsoil are less clear. Expanding on previous studies at the Duke Free-Air CO2 Enrichment (FACE) site, we quantified the effects of elevated [CO2] and N fertilization on Fsoil using daily measurements from automated chambers over 10 years. Consistent with previous results, compared to ambient unfertilized plots, annual Fsoil increased under elevated [CO2] (ca. 17%) and decreased with N (ca. 21%). N fertilization under elevated [CO2] reduced Fsoil to values similar to untreated plots. Over the study period, base respiration rates increased with leaf productivity, but declined after productivity saturated. Despite treatment-induced differences in aboveground biomass, soil temperature and water content were similar among treatments. Interannually, low soil water content decreased annual Fsoil from potential values - estimated based on temperature alone assuming nonlimiting soil water content - by ca. 0.7% per 1.0% reduction in relative extractable water. This effect was only slightly ameliorated by elevated [CO2]. Variability in soil N availability among plots accounted for the spatial variability in Fsoil , showing a decrease of ca. 114 g C m(-2) yr(-1) per 1 g m(-2) increase in soil N availability, with consistently higher Fsoil in elevated [CO2] plots ca. 127 g C per 100 ppm [CO2] over the +200 ppm enrichment. Altogether, reflecting increased belowground carbon partitioning in response to greater plant nutritional needs, the effects of elevated [CO2] and N fertilization on Fsoil in this stand are sustained beyond the early stages of stand development and

  3. The Role of the CO2 Laser and Fractional CO2 Laser in Dermatology

    PubMed Central

    Omi, Tokuya; Numano, Kayoko

    2014-01-01

    Background: Tremendous advances have been made in the medical application of the laser in the past few decades. Many diseases in the dermatological field are now indications for laser treatment that qualify for reimbursement by many national health insurance systems. Among laser types, the carbon dioxide (CO2) laser remains an important system for the dermatologist. Rationale: The lasers used in photosurgery have wavelengths that differ according to their intended use and are of various types, but the CO2 laser is one of the most widely used lasers in the dermatology field. With its wavelength in the mid-infrared at 10,600 nm, CO2 laser energy is wellabsorbed in water. As skin contains a very high water percentage, this makes the CO2 laser ideal for precise, safe ablation with good hemostasis. In addition to its efficacy in ablating benign raised lesions, the CO2 laser has been reported to be effective in the field of esthetic dermatology in the revision of acne scars as well as in photorejuvenation. With the addition of fractionation of the beam of energy into myriad microbeams, the fractional CO2 laser has offered a bridge between the frankly full ablative indications and the nonablative skin rejuvenation systems of the 2000s in the rejuvenation of photoaged skin on and off the face. Conclusions: The CO2 laser remains an efficient, precise and safe system for the dermatologist. Technological advances in CO2 laser construction have meant smaller spot sizes and greater precision for laser surgery, and more flexibility in tip sizes and protocols for fractional CO2 laser treatment. The range of dermatological applications of the CO2 laser is expected to continue to increase in the future. PMID:24771971

  4. Modelling the Martian CO2 Ice Clouds

    NASA Astrophysics Data System (ADS)

    Listowski, Constantino; Määttänen, A.; Montmessin, F.; Lefèvre, F.

    2012-10-01

    Martian CO2 ice cloud formation represents a rare phenomenon in the Solar System: the condensation of the main component of the atmosphere. Moreover, on Mars, condensation occurs in a rarefied atmosphere (large Knudsen numbers, Kn) that limits the growth efficiency. These clouds form in the polar winter troposphere and in the mesosphere near the equator. CO2 ice cloud modeling has turned out to be challenging: recent efforts (e.g. [1]) fail in explaining typical small sizes (80 nm-130 nm) observed for mesospheric clouds [2]. Supercold pockets (T<< Tcond), which appear to be common in the mesosphere [3],might be exclusively responsible of the formation of such clouds, as a consequence of gravity waves propagating throughout the atmosphere [4]. In order to understand by modeling the effect CO2 clouds could have on the Martian climate, one needs to properly predict the crystal sizes, and so the growth rates involved. We will show that Earth microphysical crystal growth models, which deal with the condensation of trace gases, are misleading when transposed for CO2 cloud formation: they overestimate the growth rates at high saturation ratios. On the other hand, an approach based on the continuum regime (small Kn), corrected to account for the free molecular regime (high Kn) remains efficient. We present our new approach for modelling the growth of Martian CO2 cloud crystals, investigated with a 1D-microphysical model. [1] Colaprete, A., et al., (2008) PSS, 56, 150C [2] Montmessin, F., et al., (2006) Icarus, 183, 403-410 [3] Montmessin at al., (2011) mamo, 404-405 [4] Spiga, A., et al., (2012), GRL, 39, L02201 [5] Wood, S. E., (1999), Ph.D. thesis, UCLA [6] Young, J. B., J. Geophys. Res., 36, 294-2956, 1993

  5. CO2 Orbital Trends in Comets

    NASA Astrophysics Data System (ADS)

    Kelley, Michael; Feaga, Lori; Bodewits, Dennis; McKay, Adam; Snodgrass, Colin; Wooden, Diane

    2014-12-01

    Spacecraft missions to comets return a treasure trove of details of their targets, e.g., the Rosetta mission to comet 67P/Churyumov-Gerasimenko, the Deep Impact experiment at comet 9P/Tempel 1, or even the flyby of C/2013 A1 (Siding Spring) at Mars. Yet, missions are rare, the diversity of comets is large, few comets are easily accessible, and comet flybys essentially return snapshots of their target nuclei. Thus, telescopic observations are necessary to place the mission data within the context of each comet's long-term behavior, and to further connect mission results to the comet population as a whole. We propose a large Cycle 11 project to study the long-term activity of past and potential future mission targets, and select bright Oort cloud comets to infer comet nucleus properties, which would otherwise require flyby missions. In the classical comet model, cometary mass loss is driven by the sublimation of water ice. However, recent discoveries suggest that the more volatile CO and CO2 ices are the likely drivers of some comet active regions. Surprisingly, CO2 drove most of the activity of comet Hartley 2 at only 1 AU from the Sun where vigorous water ice sublimation would be expected to dominate. Currently, little is known about the role of CO2 in comet activity because telluric absorptions prohibit monitoring from the ground. In our Cycle 11 project, we will study the CO2 activity of our targets through IRAC photometry. In conjunction with prior observations of CO2 and CO, as well as future data sets (JWST) and ongoing Earth-based projects led by members of our team, we will investigate both long-term activity trends in our target comets, with a particular goal to ascertain the connections between each comet's coma and nucleus.

  6. CO2 dispersion modelling over Paris region within the CO2-MEGAPARIS project

    NASA Astrophysics Data System (ADS)

    Lac, C.; Donnelly, R. P.; Masson, V.; Pal, S.; Riette, S.; Donier, S.; Queguiner, S.; Tanguy, G.; Ammoura, L.; Xueref-Remy, I.

    2013-05-01

    Accurate simulation of the spatial and temporal variability of tracer mixing ratios over urban areas is a challenging and interesting task needed to be performed in order to utilise CO2 measurements in an atmospheric inverse framework and to better estimate regional CO2 fluxes. This study investigates the ability of a high-resolution model to simulate meteorological and CO2 fields around Paris agglomeration during the March field campaign of the CO2-MEGAPARIS project. The mesoscale atmospheric model Meso-NH, running at 2 km horizontal resolution, is coupled with the Town Energy Balance (TEB) urban canopy scheme and with the Interactions between Soil, Biosphere and Atmosphere CO2-reactive (ISBA-A-gs) surface scheme, allowing a full interaction of CO2 modelling between the surface and the atmosphere. Statistical scores show a good representation of the urban heat island (UHI) with stronger urban-rural contrasts on temperature at night than during the day by up to 7 °C. Boundary layer heights (BLH) have been evaluated on urban, suburban and rural sites during the campaign, and also on a suburban site over 1 yr. The diurnal cycles of the BLH are well captured, especially the onset time of the BLH increase and its growth rate in the morning, which are essential for tall tower CO2 observatories. The main discrepancy is a small negative bias over urban and suburban sites during nighttime (respectively 45 m and 5 m), leading to a few overestimations of nocturnal CO2 mixing ratios at suburban sites and a bias of +5 ppm. The diurnal CO2 cycle is generally well captured for all the sites. At the Eiffel tower, the observed spikes of CO2 maxima occur every morning exactly at the time at which the atmospheric boundary layer (ABL) growth reaches the measurement height. At suburban ground stations, CO2 measurements exhibit maxima at the beginning and at the end of each night, when the ABL is fully contracted, with a strong spatio-temporal variability. A sensitivity test without

  7. Interactions between reducing CO2 emissions, CO2 removal and solar radiation management.

    PubMed

    Vaughan, Naomi E; Lenton, Timothy M

    2012-09-13

    We use a simple carbon cycle-climate model to investigate the interactions between a selection of idealized scenarios of mitigated carbon dioxide emissions, carbon dioxide removal (CDR) and solar radiation management (SRM). Two CO(2) emissions trajectories differ by a 15-year delay in the start of mitigation activity. SRM is modelled as a reduction in incoming solar radiation that fully compensates the radiative forcing due to changes in atmospheric CO(2) concentration. Two CDR scenarios remove 300 PgC by afforestation (added to vegetation and soil) or 1000 PgC by bioenergy with carbon capture and storage (removed from system). Our results show that delaying the start of mitigation activity could be very costly in terms of the CDR activity needed later to limit atmospheric CO(2) concentration (and corresponding global warming) to a given level. Avoiding a 15-year delay in the start of mitigation activity is more effective at reducing atmospheric CO(2) concentrations than all but the maximum type of CDR interventions. The effects of applying SRM and CDR together are additive, and this shows most clearly for atmospheric CO(2) concentration. SRM causes a significant reduction in atmospheric CO(2) concentration due to increased carbon storage by the terrestrial biosphere, especially soils. However, SRM has to be maintained for many centuries to avoid rapid increases in temperature and corresponding increases in atmospheric CO(2) concentration due to loss of carbon from the land.

  8. CO2-helium and CO2-neon mixtures at high pressures.

    PubMed

    Mallick, B; Ninet, S; Le Marchand, G; Munsch, P; Datchi, F

    2013-01-28

    The properties of mixtures of carbon dioxide with helium or neon have been investigated as a function of CO(2) concentration and pressure up to 30 GPa at room temperature. The binary phase diagrams of these mixtures are determined over the full range of CO(2) concentrations using visual observations and Raman scattering measurements. Both diagrams are of eutectic type, with a fluid-fluid miscibility gap for CO(2) concentrations in the range [5, 75] mol. % for He and [8, 55] mol. % for Ne, and a complete separation between the two components in the solid phase. The absence of alloys or stoichiometric compounds for these two binary systems is consistent with the Hume-Rothery rules of hard sphere mixtures. The Raman spectra and x-ray diffraction patterns of solid CO(2) embedded in He or Ne for various initial concentrations have been measured up to 30 GPa and 12 GPa, respectively. The frequencies of the Raman modes and the volume of solid phase I are identical, within error bars, to those reported for 100% CO(2) samples, thus confirming the total immiscibility of CO(2) with He and Ne in the solid phase. These results demonstrate the possibility to perform high-pressure experiments on solid CO(2) under (quasi-)hydrostatic conditions using He or Ne as pressure transmitting medium.

  9. Root-derived CO2 efflux via xylem stream rivals soil CO2 efflux.

    SciTech Connect

    Aubrey, Doug, P.; Teskey, Robert, O.

    2009-07-01

    • Respiration consumes a large portion of annual gross primary productivity in forest ecosystems and is dominated by belowground metabolism. Here, we present evidence of a previously unaccounted for internal CO2 flux of large magnitude from tree roots through stems. If this pattern is shown to persist over time and in other forests, it suggests that belowground respiration has been grossly underestimated. • Using an experimental Populus deltoides plantation as a model system, we tested the hypothesis that a substantial portion of the CO2 released from belowground autotrophic respiration remains within tree root systems and is transported aboveground through the xylem stream rather than diffusing into the soil atmosphere. • On a daily basis, the amount of CO2 that moved upward from the root system into the stem via the xylem stream (0.26 mol CO2 m-2 d-1) rivalled that which diffused from the soil surface to the atmosphere (0.27 mol CO2 m-2 d-1). We estimated that twice the amount of CO2 derived from belowground autotrophic respiration entered the xylem stream as diffused into the soil environment. • Our observations indicate that belowground autotrophic respiration consumes substantially more carbohydrates than previously recognized and challenge the paradigm that all root-respired CO2 diffuses into the soil atmosphere.

  10. Geochemical Interaction of Middle Bakken Reservoir Rock and CO2 during CO2-Based Fracturing

    NASA Astrophysics Data System (ADS)

    Nicot, J. P.; Lu, J.; Mickler, P. J.; Ribeiro, L. H.; Darvari, R.

    2015-12-01

    This study was conducted to investigate the effects of geochemical interactions when CO2 is used to create the fractures necessary to produce hydrocarbons from low-permeability Middle Bakken sandstone. The primary objectives are to: (1) identify and understand the geochemical reactions related to CO2-based fracturing, and (2) assess potential changes of reservoir property. Three autoclave experiments were conducted at reservoir conditions exposing middle Bakken core fragments to supercritical CO2 (sc-CO2) only and to CO2-saturated synthetic brine. Ion-milled core samples were examined before and after the reaction experiments using scanning electron microscope, which enabled us to image the reaction surface in extreme details and unambiguously identify mineral dissolution and precipitation. The most significant changes in the reacted rock samples exposed to the CO2-saturated brine is dissolution of the carbonate minerals, particularly calcite which displays severely corrosion. Dolomite grains were corroded to a lesser degree. Quartz and feldspars remained intact and some pyrite framboids underwent slight dissolution. Additionally, small amount of calcite precipitation took place as indicated by numerous small calcite crystals formed at the reaction surface and in the pores. The aqueous solution composition changes confirm these petrographic observations with increase in Ca and Mg and associated minor elements and very slight increase in Fe and sulfate. When exposed to sc-CO2 only, changes observed include etching of calcite grain surface and precipitation of salt crystals (halite and anhydrite) due to evaporation of residual pore water into the sc-CO2 phase. Dolomite and feldspars remained intact and pyrite grains were slightly altered. Mercury intrusion capillary pressure tests on reacted and unreacted samples shows an increase in porosity when an aqueous phase is present but no overall porosity change caused by sc-CO2. It also suggests an increase in permeability

  11. The Relationship Between CO2 Levels and CO2 Related Symptoms Reported on the ISS

    NASA Technical Reports Server (NTRS)

    VanBaalen, M.; Law, J.; Foy, M.; Wear, M. L.; Mason, S.; Mendez, C.; Meyers, V.

    2014-01-01

    Medical Operations, Toxicology, and the Lifetime Surveillance of Astronaut Health collaborated to assess the association of CO2 levels on board the International Space Station and USOS crew reported symptoms inflight, i.e. headache and vision changes. Private Medical Conference (PMC) documents and the weekly Space Medicine Operations Team (SMOT) Notes were used to provide a robust data set of inflight medical events. All events and non-events were documented independent of CO2 levels and other potential contributors. Average (arithmetic mean) and single point maximum ppCO2 was calculated for the 24 hours and 7 days prior to the PMC or SMOT date and time provided by LSAH. Observations falling within the first 7 days of flight (147) were removed from the datasets analyzed to avoid confounding with Space Adaptation Syndrome. The final analysis was based on 1716 observations. For headache, 46 headaches were observed. CO2 level, age at launch, time inflight, and data source were all significantly associated with headache. In particular, for each 1 mmHg increase in CO2, the odds of a crewmember reporting a headache doubled. For vision changes, 29 reports of vision changes were observed. These observations were not found to be statistically associated with CO2 levels as analyzed. While the incidence of headache has was not high (3%), headaches may be an indicator of underlying increases in intracranial pressure, which may result likely from the synergy between CO2-induced cerebral vasodilatation and decreased venous drainage in microgravity. Vision changes were inconsistently reported and as a result did not align appropriately with the CO2 levels. Further analysis is needed. Our results support ongoing efforts to lower the CO2 exposure limits in spacecraft.

  12. Range Resolved CO2 Atmospheric Backscattering Measurements Using Fiber Lasers and RZPN Code Modulation

    NASA Technical Reports Server (NTRS)

    Burris, John

    2011-01-01

    We report the use of a return-to- zero (RZPN) pseudo noise modulation technique for making range resolved measurements of CO2 within the planetary boundary layer (PBL) using commercial, off-the-shelf, components. Conventional, range resolved, DIAL measurements require laser pulse widths that are significantly shorter than the desired spatial resolution and necessitate using pulses whose temporal spacing is such that scattered returns from only a single pulse are observed by the receiver at any one time (for the PBL pulse separations must be greater than approximately 20 microseconds). This imposes significant operational limitations when using currently available fiber lasers because of the resulting low duty cycle (less than approximately 0.0005) and consequent low average laser output power. The RZPN modulation technique enables a fiber laser to operate at much higher duty cycles (approaching 0.04) thereby more effectively utilizing the amplifier's output. This increases the counts received by approximately two orders of magnitude. Our approach involves employing two distributed feedback lasers (DFB), each modulated by a different RPZN code, whose outputs are then amplified by a CW fiber amplifier. One laser is tuned to a CO2 absorption line; the other operates offline thereby permitting the simultaneous acquisition of both on and offline signals using independent RZPN codes. This minimizes the impact of atmospheric turbulence on the measurement. The on and offline signals are retrieved by deconvolving the return signal using the appropriate kernels.

  13. COMPONENTS OF LASER SYSTEMS AND PROCESSES OCCURRING IN THEM: Properties of an array of phase-locked CO2 lasers

    NASA Astrophysics Data System (ADS)

    Kachurin, O. R.; Lebedev, F. V.; Napartovich, A. P.

    1988-09-01

    An experimental investigation was made of the emission characteristics of a coherently operating array of waveguide CO2 lasers. The lasers were phase locked by self-reproduction of periodic light fields. Three supermodes of the array were found to exist, an investigation was made of the radiation power distribution over the aperture as a function of the active medium pumping level, and the efficiency in the coherent lasing regime was determined.

  14. CO2 mineralization-bridge between storage and utilization of CO2.

    PubMed

    Geerlings, Hans; Zevenhoven, Ron

    2013-01-01

    CO2 mineralization comprises a chemical reaction between suitable minerals and the greenhouse gas carbon dioxide. The CO2 is effectively sequestered as a carbonate, which is stable on geological timescales. In addition, the variety of materials that can be produced through mineralization could find applications in the marketplace, which makes implementation of the technology more attractive. In this article, we review recent developments and assess the current status of the CO2 mineralization field. In an outlook, we briefly describe a few mineralization routes, which upon further development have the potential to be implemented on a large scale.

  15. Effects of CO2 on stomatal conductance: do stomata open at very high CO2 concentrations?

    NASA Technical Reports Server (NTRS)

    Wheeler, R. M.; Mackowiak, C. L.; Yorio, N. C.; Sager, J. C.

    1999-01-01

    Potato and wheat plants were grown for 50 d at 400, 1000 and 10000 micromoles mol-1 carbon dioxide (CO2). and sweetpotato and soybean were grown at 1000 micromoles mol-1 CO2 in controlled environment chambers to study stomatal conductance and plant water use. Lighting was provided with fluorescent lamps as a 12 h photoperiod with 300 micromoles m-2 s-1 PAR. Mid-day stomatal conductances for potato were greatest at 400 and 10000 micromoles mol-1 and least at 1000 micromoles mol-1 CO2. Mid-day conductances for wheat were greatest at 400 micromoles mol-1 and least at 1000 and 10000 micromoles mol-1 CO2. Mid-dark period conductances for potato were significantly greater at 10000 micromoles mol-1 than at 400 or 1000 micromoles mol-1, whereas dark conductance for wheat was similar in all CO2 treatments. Temporarily changing the CO2 concentration from the native 1000 micromoles mol-1 to 400 micromoles mol-1 increased mid-day conductance for all species, while temporarily changing from 1000 to 10000 micromoles mol-1 also increased conductance for potato and sweetpotato. Temporarily changing the dark period CO2 from 1000 to 10000 micromoles mol-1 increased conductance for potato, soybean and sweetpotato. In all cases, the stomatal responses were reversible, i.e. conductances returned to original rates following temporary changes in CO2 concentration. Canopy water use for potato was greatest at 10000, intermediate at 400, and least at 1000 micromoles mol-1 CO2, whereas canopy water use for wheat was greatest at 400 and similar at 1000 and 10000 micromoles mol-1 CO2. Elevated CO2 treatments (i.e. 1000 and 10000 micromoles mol-1) resulted in increased plant biomass for both wheat and potato relative to 400 micromoles mol-1, and no injurious effects were apparent from the 10000 micromoles mol-1 treatment. Results indicate that super-elevated CO2 (i.e. 10000 micromoles mol-1) can increase stomatal conductance in some species, particularly during the dark period, resulting in

  16. Development of an Airborne Micropulse Water Vapor DIAL

    NASA Astrophysics Data System (ADS)

    Nehrir, A. R.; Ismail, S.

    2012-12-01

    Water vapor plays a key role in many atmospheric processes affecting both weather and climate. Airborne measurements of tropospheric water vapor profiles have been a longstanding observational need to not only the active remote sensing community but also to the meteorological, weather forecasting, and climate/radiation science communities. Microscale measurements of tropospheric water vapor are important for enhancing near term meteorological forecasting capabilities while mesoscale and synopticscale measurements can lead to an enhanced understanding of the complex coupled feedback mechanisms between water vapor, temperature, aerosols, and clouds. To realize tropospheric measurements of water vapor profiles over the microscale-synopticscale areas of meteorological interest, a compact and cost effective airborne micropulse differential absorption lidar (DIAL) is being investigated using newly emerging semiconductor based laser technology. Ground based micropulse DIAL (MPD) measurements of tropospheric water vapor and aerosol profiles up to 6 km and 15 km, respectively, have been previously demonstrated using an all semiconductor based laser transmitter. The DIAL transmitter utilizes a master oscillator power amplifier (MOPA) configuration where two semiconductor seed lasers are used to seed a single pass traveling wave tapered semiconductor optical amplifier (TSOA), producing up to 7μJ pulse energies over a 1 μs pulse duration at a 10 kHz pulse repetition frequency (PRF). Intercomparisons between the ground based instrument measurements and radiosonde profiles demonstrating the MPD performance under varying atmospheric conditions will be presented. Work is currently ongoing to expand upon the ground based MPD concept and to develop a compact and cost effective system capable of deployment on a mid-low altitude aircraft such as the NASA Langley B200 King Air. Initial lab experiments show that a two-three fold increase in the laser energy compared to the ground

  17. Raman-shifted dye laser for water vapor DIAL measurements.

    PubMed

    Grossmann, B E; Singh, U N; Higdon, N S; Cotnoir, L J; Wilkerson, T D; Browell, E V

    1987-05-01

    For improved DIAL measurements of water vapor in the upper troposphere or lower stratosphere, we have generated narrowband (~0.03-cm(-1)) laser radiation at 720- and 940-nm wavelengths by stimulated Raman scattering (SRS) using the narrow linewidth (~0.02-cm(-1)) output of a Nd:YAG-pumped dye laser. For a hydrogen pressure of 350 psi, the first Stokes conversion efficiencies to 940 nm were 20% and 35% when using a conventional and waveguide Raman cell, respectively. We measured the linewidth of the first Stokes line at high cell pressures and inferred collisional broadening coefficients that agree well with those previously measured in spontaneous Raman scattering.

  18. Raman-shifted dye laser for water vapor DIAL measurements

    NASA Technical Reports Server (NTRS)

    Grossmann, B. E.; Singh, U. N.; Cotnoir, L. J.; Wilkerson, T. D.; Higdon, N. S.; Browell, E. V.

    1987-01-01

    For improved DIAL measurements of water vapor in the upper troposphere or lower stratosphere, narrowband (about 0.03/cm) laser radiation at 720- and 940-nm wavelengths was generated by stimulated Raman scattering (SRS), using the narrow linewidth (about 0.02/cm) output of a Nd:YAG-pumped dye laser. For a hydrogen pressure of 350 psi, the first Stokes conversion efficiencies to 940 nm were 20 percent and 35 percent, when using a conventional and waveguide Raman cell, respectively. The linewidth of the first Stokes line at high cell pressures, and the inferred collisional broadening coefficients, agree well with those previously measured in spontaneous Raman scattering.

  19. Appendix E: FM-DIAL Preliminary Detection Sensitivity Measurements

    SciTech Connect

    Harper, Warren W.; Sheen, David M.; Schultz, John F.

    2002-05-09

    This update briefly reports new measurements and analysis that are used to determine the noise equivalent absorbance for the FM-DIAL (frequency modulation – differential absorption light detection and ranging) system. The modeling work that is performed in parallel with the LIDAR experiments provides a useful benchmark to predict the performance of an experimental setup, and a detection sensitivity to strive to realize. Often, the theoretical performance is difficult to obtain experimentally, but with careful design experiments can come close to being limited by fundamental noise sources.

  20. CO2 Impacts on the Martian Atmosphere

    NASA Astrophysics Data System (ADS)

    Kelley, Michael; Bauer, James; Bodewits, Dennis; Farnham, Tony; Stevenson, Rachel; Yelle, Roger

    2014-09-01

    The dynamically new comet C/2013 A1 (Siding Spring) will pass Mars at the extremely close distance of 140,000 km on 2014 Oct 19. This encounter is unique---a record close approach to a planet with spacecraft that can observe its passage---and currently, all 5 Mars orbiters have plans to observe the comet and/or its effects on the planet. Gas from the comet's coma is expected to collide with the Martian atmosphere, altering the abundances of some species and producing significant heating, inflating the upper atmosphere. We propose DDT observations with Spitzer/IRAC to measure the comet's CO2+CO coma (observing window Oct 30 - Nov 20), to use these measurements to derive the coma's CO2 density at Mars during the closest approach, and to aid the interpretation of any observed effects or changes in the Martian atmosphere.

  1. Ultraviolet photoionization in CO2 TEA lasers

    NASA Astrophysics Data System (ADS)

    Scott, S. J.; Smith, A. L. S.

    1988-07-01

    The effects of gas composition and spark parameters on the UV emission in CO2 TEA laser gas mixtures were investigated together with the nature of photoionization process and the photoelectron-loss mechanism. A linear relationship was found between N2 concentration and photoionization (with no such dependence on C concentration, from CO and CO2), but the increases in photoionization that could be effected by optimizing the spark discharge circuit parameters were much higher than those produced by changes in gas composition. UV emission was directly proportional to the amount of stored electrical energy in the spark-discharge circuit and to the cube of the peak current produced in the spark by the discharge of this energy. Photoionization was also found to be proportional to the spark electrode gap. It was found that free-space sparks gave a considerably broader emission pattern than a surface-guided notched spark.

  2. Increasing CO2 threatens human nutrition.

    PubMed

    Myers, Samuel S; Zanobetti, Antonella; Kloog, Itai; Huybers, Peter; Leakey, Andrew D B; Bloom, Arnold J; Carlisle, Eli; Dietterich, Lee H; Fitzgerald, Glenn; Hasegawa, Toshihiro; Holbrook, N Michele; Nelson, Randall L; Ottman, Michael J; Raboy, Victor; Sakai, Hidemitsu; Sartor, Karla A; Schwartz, Joel; Seneweera, Saman; Tausz, Michael; Usui, Yasuhiro

    2014-06-01

    Dietary deficiencies of zinc and iron are a substantial global public health problem. An estimated two billion people suffer these deficiencies, causing a loss of 63 million life-years annually. Most of these people depend on C3 grains and legumes as their primary dietary source of zinc and iron. Here we report that C3 grains and legumes have lower concentrations of zinc and iron when grown under field conditions at the elevated atmospheric CO2 concentration predicted for the middle of this century. C3 crops other than legumes also have lower concentrations of protein, whereas C4 crops seem to be less affected. Differences between cultivars of a single crop suggest that breeding for decreased sensitivity to atmospheric CO2 concentration could partly address these new challenges to global health. PMID:24805231

  3. Increasing CO2 threatens human nutrition.

    PubMed

    Myers, Samuel S; Zanobetti, Antonella; Kloog, Itai; Huybers, Peter; Leakey, Andrew D B; Bloom, Arnold J; Carlisle, Eli; Dietterich, Lee H; Fitzgerald, Glenn; Hasegawa, Toshihiro; Holbrook, N Michele; Nelson, Randall L; Ottman, Michael J; Raboy, Victor; Sakai, Hidemitsu; Sartor, Karla A; Schwartz, Joel; Seneweera, Saman; Tausz, Michael; Usui, Yasuhiro

    2014-06-01

    Dietary deficiencies of zinc and iron are a substantial global public health problem. An estimated two billion people suffer these deficiencies, causing a loss of 63 million life-years annually. Most of these people depend on C3 grains and legumes as their primary dietary source of zinc and iron. Here we report that C3 grains and legumes have lower concentrations of zinc and iron when grown under field conditions at the elevated atmospheric CO2 concentration predicted for the middle of this century. C3 crops other than legumes also have lower concentrations of protein, whereas C4 crops seem to be less affected. Differences between cultivars of a single crop suggest that breeding for decreased sensitivity to atmospheric CO2 concentration could partly address these new challenges to global health.

  4. Innovative Energy Strategies for CO2 Stabilization

    NASA Astrophysics Data System (ADS)

    Watts, Robert G.

    2002-08-01

    Many of the world's climate scientists believe that the build-up of heat-trapping CO2 in the atmosphere will lead to global warming unless we burn less fossil fuels. At the same time, energy must be supplied in increasing amounts for the developing world to continue its growth. This work discusses the feasibility of increasingly efficient energy use and the potential for supplying energy from sources that do not introduce CO2. The book analyzes the prospects for Earth-based renewables: solar, wind, biomass, hydroelectricity, geothermal and ocean energy. It then discusses nuclear fission and fusion, and the relatively new idea of harvesting solar energy on satellites or lunar bases. It will be essential reading for all those interested in energy issues.

  5. Synthesis, characterization and performance of single-component CO2-binding organic liquids (CO2BOL) for post combustion CO2 capture

    SciTech Connect

    Koech, Phillip K.; Heldebrant, David J.; Rainbolt, James E.; Zheng, Feng; Smurthwaite, Tricia D.

    2010-03-31

    Carbon dioxide (CO2) emission to the atmosphere will increase significantly with the shift to coal powered plants for energy generation. This increase in CO2 emission will contribute to climate change. There is need to capture and sequester large amounts of CO2 emitted from these coal power plants in order to mitigate the environmental effects. Here we report the synthesis, characterization and system performance of multiple third generation CO2 binding organic liquids (CO2BOLs) as a solvent system for post combustion gas capture. Alkanolguanidines and alkanolamidines are single component CO2BOLs that reversibly bind CO2 chemically as liquid zwitterionic amidinium / guanidinium alkylcarbonates. Three different alkanolguanidines and alkanolamidines were synthesized and studied for CO2 capacity and binding energetics. Solvent performance of these three CO2BOLs was evaluated by batch-wise CO2 uptake and release over multiple cycles. Synthesis of CO2BOLs, characterization, CO2 uptake, selectivity towards CO2 as well as solvent tolerance to water will be discussed.

  6. Pulpotomies with CO2 laser in dogs

    NASA Astrophysics Data System (ADS)

    Figueiredo, Jose A. P.; Chavantes, Maria C.; Gioso, Marco A.; Pesce, Hildeberto F.; Jatene, Adib D.

    1995-05-01

    The aim of this study was to evaluate the clinical aspects of dental pulps submitted to shallow pulpotomy followed by CO2 laser radiation at five different procedures. For this purpose, initially 66 dogs' teeth were opened and about 2 or 3 mm of coronal dental pulp was removed. Continuous irrigation with saline solution was implemented. The teeth were randomly divided into 6 groups of 11 each. After cessation of bleeding, in group I, CO2 laser (Xanar-20, USA) was irradiated for 1 second at a power of 5 watts; in group II, 2 seconds at 3 watts; in Group III, 2 seconds at 5 watts; in Group IV, 1 second at 3 watts; in Group V, a continuous mode at 3 watts; Group VI served as a control, with no laser irradiation. The results showed no clinical differences between the 3 W and 5 W powers. Time period of irradiation exposition influenced definitively the clinical appearance of the dental pulps. Groups I and IV (1 second) were unable to stop the bleeding, which persisted over 15 minutes for all teeth. This may be due to the intense heat generated by CO2 laser, causing vasodilatation. Groups II and III displayed a similar appearance, but bleeding stopped in about 10 minutes. Group V (continuous mode) had no bleeding after irradiation, but a plasma-like liquid would come out for almost 2 minutes. When comparing to the control (Group VI), all the pulps would assume a jelly-like aspect, with black granulated tissue on the surface, covering totally the pulps of Group V and partially the other groups. The histological results will be discussed in a further study. From the data obtained, it seems that CO2 laser irradiation for pulpotomies should be done in a continuous mode, for clinical convenience in terms of time taken and effective irradiation.

  7. Controls on the CO2 seasonal cycle

    NASA Technical Reports Server (NTRS)

    Pollack, J. B.; Forget, F.; Haberle, Robert M.; Schaeffer, J.; Lee, H.

    1993-01-01

    Surface pressure measurement performed by the Viking landers show substantial variations in pressure on seasonal timescales that are characterized by two local minima and two local maxima. These variations have widely been attributed to the seasonal condensation and sublimation of CO2 in the two polar regions. It has been somewhat of a surprise that the amplitude of the minimum and maximum that is dominated by the CO2 cycle in the north was much weaker than the corresponding amplitude of the south-dominated extrema. Another surprise was that the seasonal pressure cycle during years 2 and 3 of the Viking mission was so similar to that for year 1, despite the occurrence of two global dust storms during year 1 and none during years 2 and 3. An energy balance model that incorporates dynamical factors from general circulation model (GCM) runs in which the atmospheric dust opacity and seasonal date were systematically varied was used to model the observed seasonal pressure variations. The energy balance takes account of the following processes in determining the rates of CO2 condensation and sublimation at each longitudinal and latitudinal grid point: solar radiation, infrared radiation from the atmosphere and surface, subsurface heat conduction, and atmospheric heat advection. Condensation rates are calculated both at the surface and in the atmosphere. In addition, the energy balance model also incorporates information from the GCM runs on seasonal redistribution of surface pressure across the globe. Estimates of surface temperature of the seasonal CO2 caps were used to define the infrared radiative losses from the seasonal polar caps. The seasonal pressure variations measured at the Viking lander sites were closely reproduced.

  8. CO2 laser cold cathode research results

    NASA Technical Reports Server (NTRS)

    Hochuli, U.

    1973-01-01

    The construction and processing of four test lasers are discussed, and the test results are assessed. Tests show that the best performance was obtained from cathodes made from internally oxidized Ag-Cu alloys or pure Cu. Due to the cold cathode technology developments, sealed-off 1 w CO2 lasers with gas volumes of only 50 cu cm were duplicated, and have performed satisfactorily for more than 6000 hours.

  9. Continuous CO2 extractor and methods

    SciTech Connect

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  10. Aerosol extinction measurements with CO2-lidar

    NASA Technical Reports Server (NTRS)

    Hagard, Arne; Persson, Rolf

    1992-01-01

    With the aim to develop a model for infrared extinction due to aerosols in slant paths in the lower atmosphere we perform measurements with a CO2-lidar. Earlier measurements with a transmissometer along horizontal paths have been used to develop relations between aerosol extinction and meteorological parameters. With the lidar measurements we hope to develop corresponding relations for altitude profiles of the aerosol extinction in the infrared. An important application is prediction of detection range for infrared imaging systems.

  11. Aridity under conditions of increased CO2

    NASA Astrophysics Data System (ADS)

    Greve, Peter; Roderick, Micheal L.; Seneviratne, Sonia I.

    2016-04-01

    A string of recent of studies led to the wide-held assumption that aridity will increase under conditions of increasing atmospheric CO2 concentrations and associated global warming. Such results generally build upon analyses of changes in the 'aridity index' (the ratio of potential evaporation to precipitation) and can be described as a direct thermodynamic effect on atmospheric water demand due to increasing temperatures. However, there is widespread evidence that contradicts the 'warmer is more arid' interpretation, leading to the 'global aridity paradox' (Roderick et al. 2015, WRR). Here we provide a comprehensive assessment of modeled changes in a broad set of dryness metrics (primarily based on a range of measures of water availability) over a large range of realistic atmospheric CO2 concentrations. We use an ensemble of simulations from of state-of-the-art climate models to analyse both equilibrium climate experiments and transient historical simulations and future projections. Our results show that dryness is, under conditions of increasing atmospheric CO2 concentrations and related global warming, generally decreasing at global scales. At regional scales we do, however, identify areas that undergo changes towards drier conditions, located primarily in subtropical climate regions and the Amazon Basin. Nonetheless, the majority of regions, especially in tropical and mid- to northern high latitudes areas, display wetting conditions in a warming world. Our results contradict previous findings and highlight the need to comprehensively assess all aspects of changes in hydroclimatological conditions at the land surface. Roderick, M. L., P. Greve, and G. D. Farquhar (2015), On the assessment of aridity with changes in atmospheric CO2, Water Resour. Res., 51, 5450-5463

  12. Breadboard CO2 and humidity control system

    NASA Technical Reports Server (NTRS)

    Boehm, A. M.

    1976-01-01

    A regenerable CO2 and humidity control system is being developed for potential use on shuttle as an alternate to the baseline lithium hydroxide (LiOH)/condensing heat exchanger system. The system utilizes a sorbent material, designated HS-C, to adsorb CO2 and water vapor from the cabin atmosphere. The material is regenerated by exposing it to space vacuum. A half-size breadboard system, utilizing a flight representative HS-C canister, was designed, built, and performance tested to shuttle requirements for total CO2 and total humidity removal. The use of a new chemical matrix material allowed significant optimization of the system design by packing the HS-C chemical into the core of a heat exchanger which is manifolded to form two separate and distinct beds. Breadboard system performance was proven by parametric testing and simulated mission testing over the full range of shuttle crew sizes and metabolic loadings. Vacuum desorption testing demonstrated considerable savings in previously projected shuttle vacuum duct sizing.

  13. Phase conjugation with CO 2 lasers

    NASA Astrophysics Data System (ADS)

    Klingenberg, H. H.; Riede, W.; Hall, Th.

    1995-01-01

    A TEA CO 2 laser was used for the investigation of four-wave mixing (4WM) processes in sulfur hexafluoride (SF 6), an organic solvent (toluene), and III/V semiconductor wafers (InSb, InAs). The relevant involved grating mechanisms were probed by the 4WM technique. It was found that the decay times of the corresponding built-up transient gratings in the various nonlinear media differ by approximately six orders of magnitude. Furthermore, simulations of a phase conjugates mirror (PCM) were carried out by solving the Kirchhoff-Fresnel integral equations by complex conjugating the spatial field distribution at the PCM. Applying this technique an efficient production of low divergence high energy CO 2 laser pulses generated from a 4WM master oscillator/power amplifier (MOPA) scheme was predictable. For the modelling a large volume e-beam controlled CO 2 amplifier was placed along the signal beam. The optical homogeneity of the laser gas was disturbed by shock waves and by the laser-induced medium perturbation (LIMP) effect. The disturbing influence of both effects on the optical quality of the output radiation will be shown.

  14. Towards Overhauser DNP in supercritical CO2

    NASA Astrophysics Data System (ADS)

    van Meerten, S. G. J.; Tayler, M. C. D.; Kentgens, A. P. M.; van Bentum, P. J. M.

    2016-06-01

    Overhauser Dynamic Nuclear Polarization (ODNP) is a well known technique to improve NMR sensitivity in the liquid state, where the large polarization of an electron spin is transferred to a nucleus of interest by cross-relaxation. The efficiency of the Overhauser mechanism for dipolar interactions depends critically on fast local translational dynamics at the timescale of the inverse electron Larmor frequency. The maximum polarization enhancement that can be achieved for 1H at high magnetic fields benefits from a low viscosity solvent. In this paper we investigate the option to use supercritical CO2 as a solvent for Overhauser DNP. We have investigated the diffusion constants and longitudinal nuclear relaxation rates of toluene in high pressure CO2. The change in 1H T1 by addition of TEMPO radical was analyzed to determine the Overhauser cross-relaxation in such a mixture, and is compared with calculations based on the Force Free Hard Sphere (FFHS) model. By analyzing the relaxation data within this model we find translational correlation times in the range of 2-4 ps, depending on temperature, pressure and toluene concentration. Such short correlation times may be instrumental for future Overhauser DNP applications at high magnetic fields, as are commonly used in NMR. Preliminary DNP experiments have been performed at 3.4 T on high pressure superheated water and model systems such as toluene in high pressure CO2.

  15. Low-Power CO2 Compression Technology

    NASA Technical Reports Server (NTRS)

    Finn, John E.; Sridhar, K. R.; Kliss, Mark (Technical Monitor)

    1998-01-01

    Presently, the most feasible processes for extracting oxygen from the Martian atmosphere either require or are much more efficient if the atmospheric CO2 feed is provided at pressures well above the Martian ambient. Electrical power for performing the desired compression is likely to be an extremely limited resource on the Mars surface. Even if "cheap" nuclear power is available at a central site/launch facility where rocket propellent and oxidant are manufactured, life support applications needing oxygen production capabilities, such as rovers, portable life support, and remote or independent exploration stations, will benefit from extremely low-power atmospheric compression technology, such as the one discussed here. Our experiments show the potential of one very low-power approach to performing CO2 compression that uses the Mars diurnal temperature cycle to drive a heat engine. The 1 kg compressor has been tested over an extended period in a Mars environmental simulation chamber that mimics the composition, pressure, and temperature cycles that can occur on the Martian surface. The simple design, which has very few moving parts and can easily be scaled to larger or smaller sizes, produces a CO2 stream at a rate of 100 g/ day at a quality and pressure suitable for a variety of oxygen production processes.

  16. Towards Overhauser DNP in supercritical CO2.

    PubMed

    van Meerten, S G J; Tayler, M C D; Kentgens, A P M; van Bentum, P J M

    2016-06-01

    Overhauser Dynamic Nuclear Polarization (ODNP) is a well known technique to improve NMR sensitivity in the liquid state, where the large polarization of an electron spin is transferred to a nucleus of interest by cross-relaxation. The efficiency of the Overhauser mechanism for dipolar interactions depends critically on fast local translational dynamics at the timescale of the inverse electron Larmor frequency. The maximum polarization enhancement that can be achieved for (1)H at high magnetic fields benefits from a low viscosity solvent. In this paper we investigate the option to use supercritical CO2 as a solvent for Overhauser DNP. We have investigated the diffusion constants and longitudinal nuclear relaxation rates of toluene in high pressure CO2. The change in (1)H T1 by addition of TEMPO radical was analyzed to determine the Overhauser cross-relaxation in such a mixture, and is compared with calculations based on the Force Free Hard Sphere (FFHS) model. By analyzing the relaxation data within this model we find translational correlation times in the range of 2-4ps, depending on temperature, pressure and toluene concentration. Such short correlation times may be instrumental for future Overhauser DNP applications at high magnetic fields, as are commonly used in NMR. Preliminary DNP experiments have been performed at 3.4T on high pressure superheated water and model systems such as toluene in high pressure CO2.

  17. Biosequestration of atmospheric CO2 and flue gas-containing CO2 by microalgae.

    PubMed

    Cheah, Wai Yan; Show, Pau Loke; Chang, Jo-Shu; Ling, Tau Chuan; Juan, Joon Ching

    2015-05-01

    The unceasing rise of greenhouse gas emission has led to global warming and climate change. Global concern on this phenomenon has put forward the microalgal-based CO2 sequestration aiming to sequester carbon back to the biosphere, ultimately reducing greenhouse effects. Microalgae have recently gained enormous attention worldwide, to be the valuable feedstock for renewable energy production, due to their high growth rates, high lipid productivities and the ability to sequester carbon. The photosynthetic process of microalgae uses atmospheric CO2 and CO2 from flue gases, to synthesize nutrients for their growth. In this review article, we will primarily discuss the efficiency of CO2 biosequestration by microalgae species, factors influencing microalgal biomass productions, microalgal cultivation systems, the potential and limitations of using flue gas for microalgal cultivation as well as the bio-refinery approach of microalgal biomass.

  18. Integration of the electrochemical depolorized CO2 concentrator with the Bosch CO2 reduction subsystem

    NASA Technical Reports Server (NTRS)

    Schubert, F. H.; Wynveen, R. A.; Hallick, T. M.

    1976-01-01

    Regenerative processes for the revitalization of spacecraft atmospheres require an Oxygen Reclamation System (ORS) for the collection of carbon dioxide and water vapor and the recovery of oxygen from these metabolic products. Three life support subsystems uniquely qualified to form such an ORS are an Electrochemical CO2 Depolarized Concentrator (EDC), a CO2 Reduction Subsystem (BRS) and a Water Electrolysis Subsystem (WES). A program to develop and test the interface hardware and control concepts necessary for integrated operation of a four man capacity EDC with a four man capacity BRS was successfully completed. The control concept implemented proved successful in operating the EDC with the BRS for both constant CO2 loading as well as variable CO2 loading, based on a repetitive mission profile of the Space Station Prototype (SSP).

  19. Combined CO2-philicity and Ordered Mesoporosity for Highly Selective CO2 Capture at High Temperatures.

    PubMed

    Lee, Ji Hoon; Lee, Hyeon Jeong; Lim, Soo Yeon; Kim, Byung Gon; Choi, Jang Wook

    2015-06-10

    Various dry sorbents have been lately introduced as promising media to capture carbon dioxide (CO2). However, it is still desirable to further improve their performance in diverse aspects, and high temperature selectivity of CO2 over other gases is clearly one of them. Here, we report a co-assembly approach to turn nonporous melamine resin to a highly ordered mesoporous polymeric network (space group: Im3̅m) containing high nitrogen content (∼18 at%). This mesoporous network shows anomalously increasing CO2/N2 selectivity with temperature rise, with the selectivity at 323 K reaching 117 (Henry method). This selectivity behavior is attributed to a combined effect of the high nitrogen content allowing for high binding affinity with CO2 and well-defined mesopores (2.5-2.9 nm) accelerating release of N2 with temperature rise. The given orthogonal approach suggests a new direction in designing dry sorbents with excellent selectivities at high temperatures. PMID:26000786

  20. Biosequestration of atmospheric CO2 and flue gas-containing CO2 by microalgae.

    PubMed

    Cheah, Wai Yan; Show, Pau Loke; Chang, Jo-Shu; Ling, Tau Chuan; Juan, Joon Ching

    2015-05-01

    The unceasing rise of greenhouse gas emission has led to global warming and climate change. Global concern on this phenomenon has put forward the microalgal-based CO2 sequestration aiming to sequester carbon back to the biosphere, ultimately reducing greenhouse effects. Microalgae have recently gained enormous attention worldwide, to be the valuable feedstock for renewable energy production, due to their high growth rates, high lipid productivities and the ability to sequester carbon. The photosynthetic process of microalgae uses atmospheric CO2 and CO2 from flue gases, to synthesize nutrients for their growth. In this review article, we will primarily discuss the efficiency of CO2 biosequestration by microalgae species, factors influencing microalgal biomass productions, microalgal cultivation systems, the potential and limitations of using flue gas for microalgal cultivation as well as the bio-refinery approach of microalgal biomass. PMID:25497054

  1. 46 CFR 108.433 - Quantity of CO2: General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Quantity of CO2: General. 108.433 Section 108.433... Quantity of CO2: General. Each CO2 system must have enough gas to meet the quantity requirements of § 108.439 for the space requiring the greatest amount of CO2....

  2. 46 CFR 108.433 - Quantity of CO2: General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Quantity of CO2: General. 108.433 Section 108.433... Quantity of CO2: General. Each CO2 system must have enough gas to meet the quantity requirements of § 108.439 for the space requiring the greatest amount of CO2....

  3. Anthropogenic point and area source CO2 plume measurements: Implications for spaceborne CO2 sensor design

    NASA Astrophysics Data System (ADS)

    Andrews, A. E.; Ryerson, T. B.; Peischl, J.; Parrish, D. D.; Trainer, M.; Tans, P. P.

    2011-12-01

    Anthropogenic point and area source CO2 plume measurements: Implications for spaceborne CO2 sensor design A. Andrews, T. Ryerson, J. Peischl, D. Parrish, M. Trainer, P. Tans An extensive dataset of CO2 concentrations including enhancements in point and area source plumes is available from in situ measurements collected using the NOAA P-3 and NCAR Electra research aircraft during seven major field projects from 1999 through 2010. Research flights sampled emission plumes from coal-, oil-, and natural gas-fired electric utility power plants, industrial facilities, and urban areas. Plume sampling often included horizontal transects at several altitudes and multiple distances downwind. CO2 data from crosswind transects upwind and downwind, coupled with ancillary measurements of co-emitted nitric oxide, nitrogen dioxide and sulfur dioxide, along with plume location, and wind speed and direction permit unambiguous attribution and quantification of atmospheric plumes from individual sources. Certain point sources were revisited on multiple flights over the course of 1-2 month long field projects and on successive field projects spanning several years. Sampling occurred primarily in the summertime, daytime continental boundary layer, with some plume studies performed after dark and in the spring, fall, and winter seasons. The data provide rigorously calibrated, measurement-based constraints on the expected range of atmospheric CO2 plume enhancements that can be used to assess satellite sensor concepts. Crosswind near-field (~5 km) transects in the summer daytime mixed-layer downwind of the strongest point sources were characterized by peak plume CO2 mixing ratio enhancements >100 ppm above background for the 100-m spatial averages reported from the moving aircraft. On many flights, the aircraft tracked such emissions plumes beyond 150 km downwind, or up to 10 hours of transport time, until plume enhancements were indistinguishable from background variability in CO2

  4. Development of a Coherent Lidar for Aiding Precision Soft Landing on Planetary Bodies

    NASA Technical Reports Server (NTRS)

    Amzajerdian, Farzin; Pierrottet, Diego; Tolson, Robert H.; Powell, Richard W.; Davidson, John B.; Peri, Frank

    2005-01-01

    Coherent lidar can play a critical role in future planetary exploration missions by providing key guidance, navigation, and control (GNC) data necessary for navigating planetary landers to the pre-selected site and achieving autonomous safe soft-landing. Although the landing accuracy has steadily improved over time to approximately 35 km for the recent Mars Exploration Rovers due to better approach navigation, a drastically different guidance, navigation and control concept is required to meet future mission requirements. For example, future rovers will require better than 6 km landing accuracy for Mars and better than 1 km for the Moon plus maneuvering capability to avoid hazardous terrain features. For this purpose, an all-fiber coherent lidar is being developed to address the call for advancement of entry, descent, and landing technologies. This lidar will be capable of providing precision range to the ground and approach velocity data, and in the case of landing on Mars, it will also measure the atmospheric wind and density. The lidar obtains high resolution range information from a frequency modulated-continuous wave (FM-CW) laser beam whose instantaneous frequency varies linearly with time, and the ground vector velocity is directly extracted from the Doppler frequency shift. Utilizing the high concentration of aerosols in the Mars atmosphere (approx. two order of magnitude higher than the Earth), the lidar can measure wind velocity with a few watts of optical power. Operating in 1.57 micron wavelength regime, the lidar can use the differential absorption (DIAL) technique to measure the average CO2 concentration along the laser beam using, that is directly proportional to the Martian atmospheric density. Employing fiber optics components allows for the lidar multi-functional operation while facilitating a highly efficient, compact and reliable design suitable for integration into a spacecraft with limited mass, size, and power resources.

  5. TES/Aura L2 Carbon Dioxide (CO2) Lite Nadir (TL2CO2LN)

    Atmospheric Science Data Center

    2015-06-24

    TES/Aura L2 Carbon Dioxide (CO2) Lite Nadir (TL2CO2LN) News:  TES News ... L2 Instrument:  TES/Aura L2 Carbon Dioxide Spatial Coverage:  5.3 km nadir Spatial ... OPeNDAP Access:  OPeNDAP Parameters:  Carbon Dioxide Order Data:  Reverb:   Order Data ...

  6. Infrared spectroscopy of Mg-CO2 and Al-CO2 complexes in helium nanodroplets

    NASA Astrophysics Data System (ADS)

    Thomas, Brandon J.; Harruff-Miller, Barbara A.; Bunker, Christopher E.; Lewis, William K.

    2015-05-01

    The catalytic reduction of CO2 to produce hydrocarbon fuels is a topic that has gained significant attention. Development of efficient catalysts is a key enabler to such approaches, and metal-based catalysts have shown promise towards this goal. The development of a fundamental understanding of the interactions between CO2 molecules and metal atoms is expected to offer insight into the chemistry that occurs at the active site of such catalysts. In the current study, we utilize helium droplet methods to assemble complexes composed of a CO2 molecule and a Mg or Al atom. High-resolution infrared (IR) spectroscopy and optically selected mass spectrometry are used to probe the structure and binding of the complexes, and the experimental observations are compared with theoretical results determined from ab initio calculations. In both the Mg-CO2 and Al-CO2 systems, two IR bands are obtained: one assigned to a linear isomer and the other assigned to a T-shaped isomer. In the case of the Mg-CO2 complexes, the vibrational frequencies and rotational constants associated with the two isomers are in good agreement with theoretical values. In the case of the Al-CO2 complexes, the vibrational frequencies agree with theoretical predictions; however, the bands from both structural isomers exhibit significant homogeneous broadening sufficient to completely obscure the rotational structure of the bands. The broadening is consistent with an upper state lifetime of 2.7 ps for the linear isomer and 1.8 ps for the T-shaped isomer. The short lifetime is tentatively attributed to a prompt photo-induced chemical reaction between the CO2 molecule and the Al atom comprising the complex.

  7. Low pCO2 Air-Polarized CO2 Concentrator Development

    NASA Technical Reports Server (NTRS)

    Schubert, Franz H.

    1997-01-01

    Life Systems completed a Ground-based Space Station Experiment Development Study Program which verifies through testing the performance and applicability of the electrochemical Air-Polarized Carbon Dioxide Concentrator (APC) process technology for space missions requiring low (i.e., less than 3 mm Hg) CO2 partial pressure (pCO2) in the cabin atmosphere. Required test hardware was developed and testing was accomplished at an approximate one-person capacity CO2 removal level. Initially, two five-cell electrochemical modules using flight-like 0.5 sq ft cell hardware were tested individually, following by their testing at the integrated APC system level. Testing verified previously projected performance and established a database for sizing of APC systems. A four person capacity APC system was sized and compared with four candidate CO2 removal systems. At its weight of 252 lb, a volume of 7 cu ft and a power consumption of 566 W while operating at 2.2 mm Hg pCO2, the APC was surpassed only by an Electrochemical Depolarized CO2 Concentrator (EDC) (operating with H2), when compared on a total equivalent basis.

  8. CO2-Responsive Polymer-Functionalized Au Nanoparticles for CO2 Sensor.

    PubMed

    Ma, Ying; Promthaveepong, Kittithat; Li, Nan

    2016-08-16

    Metallic nanoparticles (NPs) coated with stimuli-responsive polymers (SRPs) exhibit tunable optical properties responding to external stimuli and show promising sensing applications. We present a new CO2-responsive polymer, poly(N-(3-amidino)-aniline) (PNAAN), coated gold NPs (AuNPs) synthesized by directly reducing HAuCl4 with a CO2-responsive monomer N-(3-amidino)-aniline (NAAN). The amidine group of PNAAN can be protonated into a hydrophilic amidinium group by dissolved CO2 (dCO2). This induces the PNAAN to swell and detach from the AuNP surface, resulting in AuNP aggregation and color change. By monitoring the UV absorbance change of AuNPs, a sensitive dCO2 sensor with a linear range of 0.0132 to 0.1584 hPa and a limit of detection (LOD) of 0.0024 hPa is developed. This method shows dramatic improvement in sensitivity and convenience of sample preparation compared with the previously reported dCO2 sensor. PMID:27459645

  9. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  10. CO2-Responsive Polymer-Functionalized Au Nanoparticles for CO2 Sensor.

    PubMed

    Ma, Ying; Promthaveepong, Kittithat; Li, Nan

    2016-08-16

    Metallic nanoparticles (NPs) coated with stimuli-responsive polymers (SRPs) exhibit tunable optical properties responding to external stimuli and show promising sensing applications. We present a new CO2-responsive polymer, poly(N-(3-amidino)-aniline) (PNAAN), coated gold NPs (AuNPs) synthesized by directly reducing HAuCl4 with a CO2-responsive monomer N-(3-amidino)-aniline (NAAN). The amidine group of PNAAN can be protonated into a hydrophilic amidinium group by dissolved CO2 (dCO2). This induces the PNAAN to swell and detach from the AuNP surface, resulting in AuNP aggregation and color change. By monitoring the UV absorbance change of AuNPs, a sensitive dCO2 sensor with a linear range of 0.0132 to 0.1584 hPa and a limit of detection (LOD) of 0.0024 hPa is developed. This method shows dramatic improvement in sensitivity and convenience of sample preparation compared with the previously reported dCO2 sensor.

  11. CO2 Sequestration within Spent Oil Shale

    NASA Astrophysics Data System (ADS)

    Foster, H.; Worrall, F.; Gluyas, J.; Morgan, C.; Fraser, J.

    2013-12-01

    Worldwide deposits of oil shales are thought to represent ~3 trillion barrels of oil. Jordanian oil shale deposits are extensive and of high quality, and could represent 100 billion barrels of oil, leading to much interest and activity in the development of these deposits. The exploitation of oil shales has raised a number of environmental concerns including: land use, waste disposal, water consumption, and greenhouse gas emissions. The dry retorting of oil shales can overcome a number of the environmental impacts, but this leaves concerns over management of spent oil shale and CO2 production. In this study we propose that the spent oil shale can be used to sequester CO2 from the retorting process. Here we show that by conducting experiments using high pressure reaction facilities, we can achieve successful carbonation of spent oil shale. High pressure reactor facilities in the Department of Earth Sciences, Durham University, are capable of reacting solids with a range of fluids up to 15 MPa and 350°C, being specially designed for research with supercritical fluids. Jordanian spent oil shale was reacted with high pressure CO2 in order to assess whether there is potential for sequestration. Fresh and reacted materials were then examined by: Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Thermogravimetric Analysis (TGA), X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) methods. Jordanian spent oil shale was found to sequester up to 5.8 wt % CO2, on reacting under supercritical conditions, which is 90% of the theoretical carbonation. Jordanian spent oil shale is composed of a large proportion of CaCO3, which on retorting decomposes, forming CaSO4 and Ca-oxides which are the focus of carbonation reactions. A factorially designed experiment was used to test different factors on the extent of carbonation, including: pressure; temperature; duration; and the water content. Analysis of Variance (ANOVA) techniques were then used to determine the significance of

  12. Process-dependent residual trapping of CO2 in sandstone

    NASA Astrophysics Data System (ADS)

    Zuo, Lin; Benson, Sally M.

    2014-04-01

    This paper demonstrates that the nature and extent of residual CO2 trapping depend on the process by which the CO2 phase is introduced into the rock. We compare residual trapping of CO2 in Berea Sandstone by imbibing water into a core containing either exsolved CO2 or CO2 introduced by drainage. X-ray computed tomography measurements are used to map the spatial distribution of CO2 preimbibition and postimbibition. Unlike during drainage where the CO2 distribution is strongly influenced by the heterogeneity of the rock, the distribution of exsolved CO2 is comparatively uniform. Postimbibition, the CO2 distribution retained the essential features for both the exsolved and drainage cases, but twice as much residual trapping is observed for exsolved CO2 even with similar preimbibition gas saturations. Residually trapped exsolved gas also disproportionately reduced water relative permeability. Development of process-dependent parameterization will help better manage subsurface flow processes and unlock benefits from gas exsolution.

  13. Occupational exposure to dial painters and assemblers of radioluminous timepieces.

    PubMed

    Simpson, R E; Shuman, F G; Moghissi, A A; Blackburn, J A; Bailey, E D

    1983-05-01

    An evaluation of available personnel monitoring data and radium body burden records of dial painters handling an annual average of 1.5 Ci of radium indicates that they received an average of about 2 rem/person whole body exposure, 3 rem to the lungs from radon inhalation and 0.2 rad to the bone from radium body burdens. Among groups of similar workers handling tritium in Texas plants, the highest occupational exposures were about 160 mrem annually per person received by refinishers of tritium dial timepieces and back-lit watch assemblers. Based upon scenarios of exposures to 147Pm, repairers of timepieces containing 147Pm receive about 4.4 X 10(-4) mrem/person/yr whole body dose equivalent. The amounts that they process are in the microcurie range. Although the trend is away from the use of radium as a luminizing activator, there are indications that it is still used in timepieces even as tritium and 147Pm are increasingly being used for this purpose.

  14. 75 FR 33821 - Section 8 Random Digit Dialing Fair Market Rent Surveys

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-15

    ... URBAN DEVELOPMENT Section 8 Random Digit Dialing Fair Market Rent Surveys AGENCY: Office of the Chief... provides HUD with a fast, inexpensive way to estimate Section 8 Fair Market Rents (FMRs) in areas not... lists the following information: Title of Proposal: Section 8 Random Digit Dialing Fair Market...

  15. Alexandrite laser characterization and airborne lidar developments for water vapor DIAL measurements

    NASA Technical Reports Server (NTRS)

    Ponsardin, P.; Higdon, N. S.; Grossmann, B. E.; Browell, E. V.

    1991-01-01

    The spectral characteristics of an Alexandrite laser used for making water vapor DIAL measurements have been evaluated. The optical servo-system used to lock the laser wavelength on a water vapor absorption line is described. A brief description of the DIAL system is given and the data obtained with this lidar during flight tests in March 1990 are also presented.

  16. Calculus, Radio Dials and the Straight-Line Frequency Variable Capacitor

    ERIC Educational Resources Information Center

    Boyadzhiev, Khristo N.

    2010-01-01

    Most often radio dials of analogue radios are not uniformly graded; the frequencies are cramped on the left side or on the right side. This makes tuning more difficult. Why are dials made this way? We shall see here that simple calculus can help understand this problem and solve it. (Contains 7 figures.)

  17. The Werkendam natural CO2 accumulation: An analogue for CO2 storage in depleted oil reservoirs

    NASA Astrophysics Data System (ADS)

    Bertier, Pieter; Busch, Andreas; Hangx, Suzanne; Kampman, Niko; Nover, Georg; Stanjek, Helge; Weniger, Philipp

    2015-04-01

    The Werkendam natural CO2 accumulation is hosted in the Röt (Early Triassic) sandstone of the West Netherlands Basin, at a depth of 2.8 km, about 20 km south-east of Rotterdam (NL). This reservoir, in a fault-bound structure, was oil-filled prior to charging with magmatic CO2 in the early Cretaceous. It therefore offers a unique opportunity to study long-term CO2-water-rock interactions in the presence of oil. This contribution will present the results of a detailed mineralogical and geochemical characterisation of core sections from the Werkendam CO2 reservoir and an adjacent, stratigraphically equivalent aquifer. X-ray diffraction combined with X-ray fluorescence spectrometry revealed that the reservoir samples contain substantially more feldspar and more barite and siderite than those from the aquifer, while the latter have higher hematite contents. These differences are attributed to the effects hydrocarbons and related fluids on diagenesis in the closed system of the CO2 reservoir versus the open-system of the aquifer. Petrophysical analyses yielded overall higher and more anisotropic permeability for the reservoir samples, while the porosity is overall not significantly different from that of their aquifer equivalents. The differences are most pronounced in coarse-grained sandstones. These have low anhydrite contents and contain traces of calcite, while all other analyzed samples contain abundant anhydrite, dolomite/ankerite and siderite, but no calcite. Detailed petrography revealed mm-sized zones of excessive primary porosity. These are attributed to CO2-induced dissolution of precompactional, grain-replacive anhydrite cement. Diagenetic dolomite/ankerite crystals are covered by anhedral, epitaxial ankerite, separated from the crystals by bitumen coats. Since these carbonates were oil-wet before CO2-charging, the overgrowths are interpreted to have grown after CO2-charging. Their anhedral habit suggests growth in a 2-phase water-CO2 system. Isotopic

  18. Method for tracing simulated CO2 leak in terrestrial environment with a 13CO2 tracer

    NASA Astrophysics Data System (ADS)

    Moni, Christophe; Rasse, Daniel

    2013-04-01

    Facilities for the geological storage of carbon dioxide (CO2) as part of carbon capture and storage (CCS) schemes will be designed to prevent any leakage from the defined 'storage complex'. However, developing regulations and guidance throughout the world (e.g. the EC Directive and the USEPA Vulnerability Evaluation Framework) recognize the importance of assessing the potential for environmental impacts from CO2 storage. RISCS, a European (FP7) project, aims to improve understanding of those impacts that could plausibly occur in the hypothetical case that unexpected leakage occurs. As part of the RISCS project the potential impacts that an unexpected CO2 leaks might have on a cropland ecosystems was investigated. A CO2 exposure field experiment based on CO2 injection at 85 cm depth under an oats culture was designed. To facilitate the characterization of the simulated leaking zone the gas used for injection was produced from natural gas and had a δ13C of -46‰. The aim of the present communication is to depict how the injected gas was traced within the soil-vegetation-atmosphere continuum using 13CO2 continuous cavity ring-down spectrometry (CRDS). Four subsurface experimental injection plots (6m x 3m) were set up. In order to test the effects of different intensity of leakage, the field experiment was designed as to create a longitudinal CO2 gradient for each plot. For this purpose gas supply pipes were inserted at one extremity of each plot at the base of a 45 cm thick layer of sand buried 40 cm below the surface under the clayey plough layer of Norwegian moraine soils. Soil CO2 concentration and isotopic signature were punctually recorded: 1) in the soil at 20 cm depth at 6 positions distributed on the central transect, 2) at the surface following a (50x50 cm) grid sampling pattern, and 3) in the canopy atmosphere at 10, 20, 30 cm along three longitudinal transects (seven sampling point per transect). Soil CO2 fluxes and isotopic signature were finally

  19. Influence of Rayleigh-Doppler broadening on the selection of H2O dial system parameters

    NASA Technical Reports Server (NTRS)

    Ismail, S.; Browell, E. V.

    1986-01-01

    Computer simulations have enabled the performance of a H2O Differential Absorption Lidar (DIAL) system to be studied by spectrally analyzing the forward propagating and backscattered laser energy. The simulations were done for a high altitude (21 km) DIAL system operating in a nadir-viewing mode. The influence of Rayleigh Doppler broadening on DIAL measurement accuracies were evaluated and show that the Rayleigh broadening influence, which can be corrected to first order in regions free of large aerosol gradients, reduces the sensitivity of DIAL H2O measurement errors in the upper tropospheric region. The ability to correct the Rayleigh broadening and the selection of H2O DIAL parameters when all the systematic effects are combined, were discussed.

  20. The Use of a Pseudo Noise Code for DIAL Lidar

    NASA Astrophysics Data System (ADS)

    Burris, J.; Sun, X.; Abshire, J. B.

    2010-12-01

    Retrievals of CO2 profiles within the planetary boundary layer (PBL) are required to understand CO2 transport over regional scales and for validating the future space borne CO2 remote sensing instrument, such as the CO2 Laser Sounder, for the ASCENDS mission. We report the use of a return-to- zero (RZ) pseudo noise (PN) code modulation technique for making range resolved measurements of CO2 within the PBL using commercial, off-the-shelf, components. Conventional, range resolved, measurements require laser pulse widths that are shorter than the desired spatial resolution and have pulse spacing such that returns from only a single pulse are observed by the receiver at one time (for the PBL pulse separations must be >~2000m). This imposes a serious limitation when using available fiber lasers because of the resulting low duty cycle (<0.001) and consequent low average laser output power. RZ PN code modulation enables a fiber laser to operate at much higher duty cycles (approaching 0.1) thereby more effectively utilizing the amplifier’s output. This results in an increase in received counts by approximately two orders of magnitude. The approach involves employing two, back to back, CW fiber amplifiers seeded at the appropriate on and offline CO2 wavelengths (~1572 nm) using distributed feedback diode lasers modulated by a PN code at rates significantly above 1 megahertz. An assessment of the technique, discussions of measurement precision and error sources as well as preliminary data will be presented.

  1. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  2. [Laryngomalacia treated with CO2 laser].

    PubMed

    Larsen, Dalia Gustaityté; Berg, Jette Scheby; Illum, Peter

    2010-07-01

    Laryngomalacia is the most common laryngeal anomaly which causes inspiratory stridor in newborns. The disease is usually self-limiting and resolves before the age of two years. We present a case of severe laryngomalacia with feeding disorder and airway obstruction which needed surgical management--supraglottoplasty. The shortened aryepiglottic folds were incised using CO(2) laser and jet ventilation. The patient was observed at the hospital for one week after surgery and discharged. Four weeks after treatment, the patient was free of airway obstruction and feeding problems. PMID:20594541

  3. Atmospheric CO2 from fossil plant cuticles.

    PubMed

    Kerp, Hans

    2002-01-01

    Plants respond to changes in atmospheric carbon dioxide levels by regulating the number of stomata in their leaves. In his reconstruction of a continuous, 300-million-year record of atmospheric CO2, Retallack bases his curve on stomatal counts of fossil plant cuticles taken from published micrographs. However, the preservation of cuticles from Permian times is generally too fragmentary for the stomatal index to be reliably determined, the micrographs used could have biased the results, and there are important errors in the supplementary data - all of which cast doubt on the Permian part of Retallack's record.

  4. Recent advances in CO2 laser catalysts

    NASA Technical Reports Server (NTRS)

    Upchurch, B. T.; Schryer, D. R.; Brown, K. G.; Kielin, E. J.; Hoflund, G. B.; Gardner, S. D.

    1991-01-01

    This paper discusses several recent advances in CO2 laser catalysts including comparisons of the activity of Au/MnO2 to Pt/SnO2 catalysts with possible explanations for observed differences. The catalysts are compared for the effect of test gas composition, pretreatment temperature, isotopic integrity, long term activity, and gold loading effects on the Au/MnO2 catalyst activity. Tests conducted to date include both long-term tests of up to six months continuous operation and short-term tests of one week or more that include isotopic integrity testing.

  5. Pulsed Airborne Lidar Measurements of Atmospheric CO2 Column Absorption and Line Shapes from 3-13 km Altitudes

    NASA Technical Reports Server (NTRS)

    Abshire, James; Riris, Haris; Allan, Graham; Weaver, Clark; Mao, Jianping; Sun, Xiaoli; Hasselbrack, William

    2010-01-01

    We have developed a pulsed lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's planned ASCENDS space mission. Our technique uses two pulsed laser transmitters allowing simultaneous measurement of a CO2 absorption line in the 1570 nm band, O2 extinction in the Oxygen A-band and surface height and backscatter. The lidar measures the energy and time of flight of the laser echoes reflected from the atmosphere and surface. The lasers are rapidly and precisely stepped in wavelength across the CO2 line and an O2 line region during the measurement. The direct detection receiver uses a telescope and photon counting detectors, and measures the background light and energies of the laser echoes from the surface along with scattering from any aerosols in the path. The gas extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on- and off- line signals via the DIAL technique. Time gating is used to isolate the laser echo signals from the surface, and to reject laser photons scattered in the atmosphere. The time of flight of the laser pulses are also used to estimate the height of the scattering surface and to identify cases of mixed cloud and ground scattering. We have developed an airborne lidar to demonstrate the CO2 measurement from the NASA Glenn Lear-25 aircraft. The airborne lidar steps the pulsed laser's wavelength across the selected CO2 line with 20 steps per scan. The line scan rate is 450 Hz, the laser pulse widths are 1 usec, and laser pulse energy is 24 uJ. The time resolved laser backscatter is collected by a 20 cm telescope, detected by a photomultiplier and is recorded by a photon counting system. We made initial airborne measurements on flights during fall 2008. Laser backscatter and absorption measurements were made over a variety of land and water surfaces and through thin clouds. The atmospheric CO2 column measurements using the 1572.33 nm CO2 lines. Two flights were made above the

  6. Disentangling the effects of CO2 and short-lived climate forcer mitigation.

    PubMed

    Rogelj, Joeri; Schaeffer, Michiel; Meinshausen, Malte; Shindell, Drew T; Hare, William; Klimont, Zbigniew; Velders, Guus J M; Amann, Markus; Schellnhuber, Hans Joachim

    2014-11-18

    Anthropogenic global warming is driven by emissions of a wide variety of radiative forcers ranging from very short-lived climate forcers (SLCFs), like black carbon, to very long-lived, like CO2. These species are often released from common sources and are therefore intricately linked. However, for reasons of simplification, this CO2-SLCF linkage was often disregarded in long-term projections of earlier studies. Here we explicitly account for CO2-SLCF linkages and show that the short- and long-term climate effects of many SLCF measures consistently become smaller in scenarios that keep warming to below 2 °C relative to preindustrial levels. Although long-term mitigation of methane and hydrofluorocarbons are integral parts of 2 °C scenarios, early action on these species mainly influences near-term temperatures and brings small benefits for limiting maximum warming relative to comparable reductions taking place later. Furthermore, we find that maximum 21st-century warming in 2 °C-consistent scenarios is largely unaffected by additional black-carbon-related measures because key emission sources are already phased-out through CO2 mitigation. Our study demonstrates the importance of coherently considering CO2-SLCF coevolutions. Failing to do so leads to strongly and consistently overestimating the effect of SLCF measures in climate stabilization scenarios. Our results reinforce that SLCF measures are to be considered complementary rather than a substitute for early and stringent CO2 mitigation. Near-term SLCF measures do not allow for more time for CO2 mitigation. We disentangle and resolve the distinct benefits across different species and therewith facilitate an integrated strategy for mitigating both short and long-term climate change. PMID:25368182

  7. Disentangling the effects of CO2 and short-lived climate forcer mitigation.

    PubMed

    Rogelj, Joeri; Schaeffer, Michiel; Meinshausen, Malte; Shindell, Drew T; Hare, William; Klimont, Zbigniew; Velders, Guus J M; Amann, Markus; Schellnhuber, Hans Joachim

    2014-11-18

    Anthropogenic global warming is driven by emissions of a wide variety of radiative forcers ranging from very short-lived climate forcers (SLCFs), like black carbon, to very long-lived, like CO2. These species are often released from common sources and are therefore intricately linked. However, for reasons of simplification, this CO2-SLCF linkage was often disregarded in long-term projections of earlier studies. Here we explicitly account for CO2-SLCF linkages and show that the short- and long-term climate effects of many SLCF measures consistently become smaller in scenarios that keep warming to below 2 °C relative to preindustrial levels. Although long-term mitigation of methane and hydrofluorocarbons are integral parts of 2 °C scenarios, early action on these species mainly influences near-term temperatures and brings small benefits for limiting maximum warming relative to comparable reductions taking place later. Furthermore, we find that maximum 21st-century warming in 2 °C-consistent scenarios is largely unaffected by additional black-carbon-related measures because key emission sources are already phased-out through CO2 mitigation. Our study demonstrates the importance of coherently considering CO2-SLCF coevolutions. Failing to do so leads to strongly and consistently overestimating the effect of SLCF measures in climate stabilization scenarios. Our results reinforce that SLCF measures are to be considered complementary rather than a substitute for early and stringent CO2 mitigation. Near-term SLCF measures do not allow for more time for CO2 mitigation. We disentangle and resolve the distinct benefits across different species and therewith facilitate an integrated strategy for mitigating both short and long-term climate change.

  8. Electron Attachment to CO2 Embedded in Superfluid He Droplets

    PubMed Central

    2014-01-01

    Electron attachment to CO2 embedded in superfluid He droplets leads to ionic complexes of the form (CO2)n– and (CO2)nO– and, at much lower intensities, He containing ions of the form Hem(CO2)nO–. At low energies (<5 eV), predominantly the non-decomposed complexes (CO2)n– are formed via two resonance contributions, similar to electron attachment to pristine CO2 clusters. The significantly different shapes and relative resonance positions, however, indicate particular quenching and mediation processes in CO2@He. A series of further resonances in the energy range up to 67 eV can be assigned to electronic excitation of He and capture of the inelastically scattered electron generating (CO2)n– and two additional processes where an intermediately formed He* leads to the nonstoichiometric anions (CO2)nO–. PMID:24818738

  9. The Field-Laboratory for CO2 Storage 'CO2SINK

    NASA Astrophysics Data System (ADS)

    Würdemann, Hilke; Möller, Fabian; Kühn, Michael; Borm, Günter; Schilling, Frank R.

    2010-05-01

    The first European onshore geological CO2 storage project in a saline aquifer CO2SINK is designed as a field size experiment to better understand in situ storage processes and to test various monitoring techniques. This EU project is run by 18 partners from universities, research institutes and industry out of 9 European countries (www.co2sink.org). The CO2 is injected into Upper Triassic sandstones (Stuttgart Formation) of a double-anticline at a depth of 650 m. The Stuttgart Formation represents a flu vial environment comprised of sandstone channels and silty to muddy deposits. The anticline forms a classical multibarrier system: The first caprock is a playa type mudstone of the Weser and Arnstadt formations directly overlying the Stuttgart formation. Laboratory tests revealed permeabilities in a µDarcy-range. The second main caprock is a tertiary clay, the so-called Rupelton. To determine the maximum injection pressure modified leak-off tests (without fracturing the caprock) were performed resulting in values around 120 bar. Due to safety standards the pressure threshold is set to 82 bar until more experience on the reservoir behaviour is available. The sealing property of the secondary cap rock is well known from decades of natural gas storage operations at the testing site and was the basis for the permission to operate the CO2 storage by the mining authority. Undisturbed, initial reservoir conditions are 35 °C and 62 bar. The initial reservoir fluid is highly saline with about 235 g/l total dissolved solids primarily composed of sodium chloride with notable amounts of calcium chloride. The initial pH value is 6.6. Hydraulic tests as well as laboratory tests revealed a permeability between 50 and 100 mDarcy for the sand channels of the storage formation. Within twenty months of storage operation, about 30,000 t of CO2 have been injected. Spreading of the CO2 plume is monitored by a broad range of geophysical techniques. The injection well and the two

  10. Wheat response to CO2 enrichment: CO2 exchanges transpiration and mineral uptakes

    NASA Technical Reports Server (NTRS)

    Andre, M.; Ducloux, H.; Richaud, C.

    1986-01-01

    When simulating canopies planted in varied densities, researchers were able to demonstrate that increase of dry matter production by enhancing CO2 quickly becomes independant of increase of leaf area, especially above leaf area index of 2; dry matter gain results mainly from photosynthesis stimulation per unit of surface (primary CO2 effect). When crop density is low (the plants remaining alone a longer time), the effects of increasing leaf surface (tillering, leaf elongation here, branching for other plants etc.) was noticeable and dry matter simulation factor reached 1.65. This area effect decreased when canopy was closed in, as the effect of different surfaces no longer worked. The stimulation of photosynthesis reached to the primary CO2 effect. The accumulation in dry matter which was fast during that phase made the original weight advantage more and more neglectible. Comparison with short term measurements showed that first order long term effect of CO2 in wheat is predictible with short term experiment, from the effect of CO2 on photosynthesis measured on reference sample.

  11. Soil air CO2 concentration as an integrative parameter of soil structure

    NASA Astrophysics Data System (ADS)

    Ebeling, Corinna; Gaertig, Thorsten; Fründ, Heinz-Christian

    2015-04-01

    soil CO2-measuring apparatus based on NDIR technology. Ex situ determination of gas diffusivity indicate comparable results: There are significant differences in gas diffusivity between the wheel track of the 8-year-old skidding track and the reference soil, but no significant differences between the 18-year-old wheel track and the reference soil. Considering the parameter bulk density, no coherent results are delivered. Apparently, soil CO2 concentration is a suitable indicator of soil aeration deficiency and consequently soil compaction and structure regeneration. In further studies, soil compaction and regeneration of acidic silty soils and loamy sandy soils will be investigated using both CO2 logger and established soil physical parameters to validate this method.

  12. Public Acceptance for Geological CO2-Storage

    NASA Astrophysics Data System (ADS)

    Schilling, F.; Ossing, F.; Würdemann, H.; Co2SINK Team

    2009-04-01

    Public acceptance is one of the fundamental prerequisites for geological CO2 storage. In highly populated areas like central Europe, especially in the vicinity of metropolitan areas like Berlin, underground operations are in the focus of the people living next to the site, the media, and politics. To gain acceptance, all these groups - the people in the neighbourhood, journalists, and authorities - need to be confident of the security of the planned storage operation as well as the long term security of storage. A very important point is to show that the technical risks of CO2 storage can be managed with the help of a proper short and long term monitoring concept, as well as appropriate mitigation technologies e.g adequate abandonment procedures for leaking wells. To better explain the possible risks examples for leakage scenarios help the public to assess and to accept the technical risks of CO2 storage. At Ketzin we tried the following approach that can be summed up on the basis: Always tell the truth! This might be self-evident but it has to be stressed that credibility is of vital importance. Suspiciousness and distrust are best friends of fear. Undefined fear seems to be the major risk in public acceptance of geological CO2-storage. Misinformation and missing communication further enhance the denial of geological CO2 storage. When we started to plan and establish the Ketzin storage site, we ensured a forward directed communication. Offensive information activities, an information centre on site, active media politics and open information about the activities taking place are basics. Some of the measures were: - information of the competent authorities through meetings (mayor, governmental authorities) - information of the local public, e.g. hearings (while also inviting local, regional and nation wide media) - we always treated the local people and press first! - organizing of bigger events to inform the public on site, e.g. start of drilling activities (open

  13. Uncertainty in gridded CO2 emissions estimates

    NASA Astrophysics Data System (ADS)

    Hogue, Susannah; Marland, Eric; Andres, Robert J.; Marland, Gregg; Woodard, Dawn

    2016-05-01

    We are interested in the spatial distribution of fossil-fuel-related emissions of CO2 for both geochemical and geopolitical reasons, but it is important to understand the uncertainty that exists in spatially explicit emissions estimates. Working from one of the widely used gridded data sets of CO2 emissions, we examine the elements of uncertainty, focusing on gridded data for the United States at the scale of 1° latitude by 1° longitude. Uncertainty is introduced in the magnitude of total United States emissions, the magnitude and location of large point sources, the magnitude and distribution of non-point sources, and from the use of proxy data to characterize emissions. For the United States, we develop estimates of the contribution of each component of uncertainty. At 1° resolution, in most grid cells, the largest contribution to uncertainty comes from how well the distribution of the proxy (in this case population density) represents the distribution of emissions. In other grid cells, the magnitude and location of large point sources make the major contribution to uncertainty. Uncertainty in population density can be important where a large gradient in population density occurs near a grid cell boundary. Uncertainty is strongly scale-dependent with uncertainty increasing as grid size decreases. Uncertainty for our data set with 1° grid cells for the United States is typically on the order of ±150%, but this is perhaps not excessive in a data set where emissions per grid cell vary over 8 orders of magnitude.

  14. Biomimetic CO2 Sequestration: Cation Sources

    NASA Astrophysics Data System (ADS)

    Bond, G. M.; Stringer, J.; Medina, M.; McPherson, B.; Wellman, T.; Lichtner, P. C.; Abel, A.

    2001-12-01

    Conversion of CO2 to solid carbonates offers the possibility of a safe, stable product for long-term carbon sequestration. Naturally occurring carbonate minerals already comprise a massive carbon reservoir that has existed for millions of years. Large quantities of these carbonate minerals are of biogenic origin. We have demonstrated proof of principle for a novel biomimetic approach to carbon sequestration, which uses a natural catalyst, the enzyme carbonic anhydrase, to accelerate the formation of bicarbonate ions in aqueous solution. In the presence of suitable cations, this can then be precipitated out in carbonate form. One of the issues we are now addressing is the selection of suitable sources of cations. Along with seawater, and waste brines from desalination operations, brines from deep saline aquifers offer an attractive possibility. In this context, it is important to understand the effects of brine flow on geologic media, both during brine extraction and during possible reinjection of bicarbonate-enriched brines. We have used numerical simulations to evaluate and compare the effects of supercritical CO2 flow to the effects of bicarbonate solution flow on geologic media. Specifically, we examined diagenetic changes and time-scales of these changes associated with flow of the two different fluids. For these simulations we assembled and applied a model of reactive transport, including coupled groundwater flow, heat flow, and relevant geochemical reactions. Simulations have been conducted for laboratory-scale models, with the intention that these results will be used for calibration of and upscaling to larger-scale hydrogeologic models.

  15. Reducing CO2 from shipping - do non-CO2 effects matter?

    NASA Astrophysics Data System (ADS)

    Eide, M. S.; Dalsøren, S. B.; Endresen, Ø.; Samset, B.; Myhre, G.; Fuglestvedt, J.; Berntsen, T.

    2013-04-01

    Shipping is a growing sector in the global economy, and it contributions to global CO2 emissions are expected to increase. CO2 emissions from the world shipping fleet will likely be regulated in the near future, and studies have shown that significant emission reductions can be achieved at low cost. Regulations are being discussed for both existing ships as well as for future additions to the fleet. In this study a plausible CO2 emission reduction inventory is constructed for the cargo fleet existing in 2010, as well as for container ships, bulk ships and tankers separately. In the reduction inventories, CO2 emissions are reduced by 25-32% relative to baseline by applying 15 technical and operational emission reduction measures in accordance with a ship-type-specific cost-effectiveness criterion, and 9 other emission compounds are changed as a technical implication of reducing CO2. The overall climate and environmental effects of the changes to all 10 emission components in the reduction inventory are assessed using a chemical transport model, radiative forcing (RF) models and a simple climate model. We find substantial environmental and health benefits with up to 5% reduction in surface ozone levels, 15% reductions in surface sulfate and 10% reductions in wet deposition of sulfate in certain regions exposed to heavy ship traffic. The major ship types show distinctly different contributions in specific locations. For instance, the container fleet contributes 50% of the sulfate decline on the west coast of North America. The global radiative forcing from a 1 yr emission equal to the difference between baseline and reduction inventory shows an initial strong positive forcing from non-CO2 compounds. This warming effect is due to reduced cooling by aerosols and methane. After approximately 25 yr, the non-CO2 forcing is balanced by the CO2 forcing. For the global mean temperature change, we find a shift from warming to cooling after approximately 60 yr. The major ship

  16. Longitudinally Excited CO2 Laser with Short Laser Pulse like TEA CO2 Laser

    NASA Astrophysics Data System (ADS)

    Uno, Kazuyuki; Nakamura, Kenshi; Goto, Tatsumi; Jitsuno, Takahisa

    2009-11-01

    We have developed a longitudinally excited CO2 laser with a short laser pulse similar to that of TEA and Q-switched CO2 lasers. A capacitor transfer circuit with a low shunt resistance provided rapid discharge and a sharp spike pulse with a short pulse tail. Specifically, a circuit with a resistance of 10 M Ω provided a spike pulse width of 103.3 ns and a pulse tail length of 61.9 μs, whereas a circuit with a shunt resistance of 100 Ω provided a laser pulse with a spike pulse width of 96.3 ns and a pulse tail length of 17.2 μs. The laser pulses from this longitudinally excited CO2 laser were used for processing a human tooth without carbonization and for glass marking without cracks.

  17. Estimation of continuous anthropogenic CO2: model-based evaluation of CO2, CO, δ13C(CO2) and Δ14C(CO2) tracer methods

    NASA Astrophysics Data System (ADS)

    Vardag, S. N.; Gerbig, C.; Janssens-Maenhout, G.; Levin, I.

    2015-11-01

    We investigate different methods for estimating anthropogenic CO2 using modeled continuous atmospheric concentrations of CO2 alone, as well as CO2 in combination with the surrogate tracers CO, δ13C(CO2) and Δ14C(CO2). These methods are applied at three hypothetical stations representing rural, urban and polluted conditions. We find that, independent of the tracer used, an observation-based estimate of continuous anthropogenic CO2 is not yet feasible at rural measurement sites due to the low signal-to-noise ratio of anthropogenic CO2 estimates at such settings. The tracers δ13C(CO2) and CO provide an accurate possibility to determine anthropogenic CO2 continuously, only if all CO2 sources in the catchment area are well characterized or calibrated with respect to their isotopic signature and CO to anthropogenic CO2 ratio. We test different calibration strategies for the mean isotopic signature and CO to CO2 ratio using precise Δ14C(CO2) measurements on monthly integrated as well as on grab samples. For δ13C(CO2), a calibration with annually averaged 14C(CO2) grab samples is most promising, since integrated sampling introduces large biases into anthropogenic CO2 estimates. For CO, these biases are smaller. The precision of continuous anthropogenic CO2 determination using δ13C(CO2) depends on measurement precision of δ13C(CO2) and CO2, while the CO method is mainly limited by the variation in natural CO sources and sinks. At present, continuous anthropogenic CO2 could be determined using the tracers δ13C(CO2) and/or CO with a precision of about 30 %, a mean bias of about 10 % and without significant diurnal discrepancies. Hypothetical future measurements of continuous Δ14C(CO2) with a precision of 5 ‰ are promising for anthropogenic CO2 determination (precision ca. 10-20 %) but are not yet available. The investigated tracer-based approaches open the door to improving, validating and reducing biases of highly resolved emission inventories using atmospheric

  18. CO2 in the MLT: Constraining the CO2(υ2)-O Quenching Rate Coefficient.

    NASA Astrophysics Data System (ADS)

    Dawkins, E. C. M.; Kutepov, A. A.; Feofilov, A.; Janches, D.

    2015-12-01

    Carbon dioxide plays an important role in the terrestrial atmosphere, with infrared emission in the 15 μm CO2 band (I15μm) providing the dominant cooling mechanism in the mesosphere/lower thermosphere (MLT) region via interaction with atomic O. This CO2(υ2)-O quenching rate coefficient is poorly understood and current estimates vary by a factor 3-4, with a significant discrepancy between laboratory measurements and those provided by satellite remote sensing. However, the true value of this rate coefficient is of vital importance in understanding both the energetics of the MLT region and for temperatures retrievals from measurements of I15μm. This work builds upon and extends an existing methodology developed by Feofilov et al. (2012) who used TIMED/SABER satellite instrument data to retrieve the CO2(υ2)-O quenching rate coefficient using a synergy of atmospheric and ground-based lidar temperature measurements. Using the SABER overflights of the Fort Collins (CO) lidar, these authors derived the altitude variation of the CO2(υ2)-O quenching rate. The latter demonstrated deficiency of the current non-LTE model of the 15 μm CO2 emission which obviously misses some so far unknown mechanisms of non-thermal excitation of the CO2(υ2) vibrations. Current work involves several other lidar locations and is aimed at assessing whether there is a spatio-temporal variability component to this rate coefficient, and what this could reveal about these additional energy sources and sinks in the real atmosphere that are currently not accounted for in the non-LTE model.

  19. Frequency stabilization in injection controlled pulsed CO2 lasers

    NASA Technical Reports Server (NTRS)

    Menzies, Robert T.; Ancellet, Gerard M.

    1987-01-01

    Longitudinal mode selection by injection has been demonstrated as a viable technique for tailoring a TEA-CO2 laser with pulse energies of a Joule or greater to fit the requirements of a coherent lidar transmitter. Once reliable generation of single-longitudinal-mode (SLM) pulses is obtained, one can study the intrapulse frequency variation and attempt to determine the sources of frequency sweeping, or chirp. These sources include the effect of the decaying plasma, the thermal gradient due to the energy dissipation associated with the laser mechanism itself, and the pressure shift of the center frequency of the laser transition. The use of the positive-branch unstable resonator as an efficient means of coupling a discharge with transverse spatial dimensions of the order of centimeters to an optical cavity mode introduces another concern: namely, what can be done to emphasize transverse mode discrimination in an unstable resonator cavity while maintaining high coupling efficiency. These issues are briefly discussed in the paper, and representative experimental examples are included.

  20. Raman-shifted dye laser for water vapor DIAL measurements

    SciTech Connect

    Grossmann, B.E.; Singh, U.N.; Higdon, N.S.; Cotnoir, L.J.; Wilkerson, T.D.; Browell, E.V.

    1987-05-01

    For improved DIAL measurements of water vapor in the upper troposphere or lower stratosphere, we have generated narrowband (--0.03-cm/sup -1/) laser radiation at 720- and 940-nm wavelengths by stimulated Raman scattering (SRS) using the narrow linewidth (--0.02-cm/sup -1/) output of a Nd:YAG-pumped dye laser. For a hydrogen pressure of 350 psi, the first Stokes conversion efficiencies to 940 nm were 20% and 35% when using a conventional and waveguide Raman cell, respectively. We measured the linewidth of the first Stokes line at high cell pressures and inferred collisional broadening coefficients that agree well with those previously measured in spontaneous Raman scattering.

  1. Statistical evaluation and modeling of Internet dial-up traffic

    NASA Astrophysics Data System (ADS)

    Faerber, Johannes; Bodamer, Stefan; Charzinski, Joachim

    1999-08-01

    In times of Internet access being a popular consumer applications even for `normal' residential users, some telephone exchanges are congested by customers using modem or ISDN dial-up connections to their Internet Service Providers. In order to estimate the number of additional lines and switching capacity required in an exchange or a trunk group, Internet access traffic must be characterized in terms of holding time and call interarrival time distributions. In this paper, we analyze log files tracing the usage of the central ISDN access line pool at University of Stuttgart for a period of six months. Mathematical distributions are fitted to the measured data and the fit quality is evaluated with respect to the blocking probability caused by the synthetic traffic in a multiple server loss system. We show how the synthetic traffic model scales with the number of subscribers and how the model could be applied to compute economy of scale results for Internet access trunks or access servers.

  2. Diode laser based water vapor DIAL using modulated pulse technique

    NASA Astrophysics Data System (ADS)

    Pham, Phong Le Hoai; Abo, Makoto

    2014-11-01

    In this paper, we propose a diode laser based differential absorption lidar (DIAL) for measuring lower-tropospheric water vapor profile using the modulated pulse technique. The transmitter is based on single-mode diode laser and tapered semiconductor optical amplifier with a peak power of 10W around 800nm absorption band, and the receiver telescope diameter is 35cm. The selected wavelengths are compared to referenced wavelengths in terms of random error and systematic errors. The key component of modulated pulse technique, a macropulse, is generated with a repetition rate of 10 kHz, and the modulation within the macropulse is coded according to a pseudorandom sequence with 100ns chip width. As a result, we evaluate both single pulse modulation and pseudorandom coded pulse modulation technique. The water vapor profiles conducted from these modulation techniques are compared to the real observation data in summer in Japan.

  3. Carbon Dioxide Exchanges in Leaves. I. Discrimination Between 14CO2 and 12CO2 in Photosynthesis 1

    PubMed Central

    Yemm, E. W.; Bidwell, R. G. S.

    1969-01-01

    In order to measure CO2 exchange reactions by leaves using isotopes of CO2, it is necessary to know precisely the discrimination against 14CO2 by leaves. Earlier determinations of discrimination are at variance, and may be inaccurate because of assumptions made about the rate of photorespiration. Maize leaves evolve little or no CO2 in light, and so provide suitable material for this measurement. Discrimination against 14CO2 in photosynthesis by maize leaves is almost precisely the same as in CO2 absorption by NaOH solution, amounting to 2.1 and 2.0% respectively. The agreement between these values and their close approximation to the relative rates of diffusion of 12CO2 and 14CO2, calculated from Graham's law, shows that diffusion into the leaf is primarily responsible for discrimination against 14CO2 in photosynthesis. PMID:16657206

  4. Interface characteristics in Co2MnSi/Ag/Co2MnSi trilayer

    NASA Astrophysics Data System (ADS)

    Li, Yang; Chen, Hong; Wang, Guangzhao; Yuan, Hongkuan

    2016-05-01

    Interface characteristics of Co2MnSi/Ag/Co2MnSi trilayer have been investigated by means of first-principles. The most likely interface is formed by connecting MnSi-termination to the bridge site between two Ag atoms. As annealed at high temperature, the formation of interface DO3 disorder is most energetically favorable. The spin polarization is reduced by both the interface itself and interface disorder due to the interface state occurs in the minority-spin gap. As a result, the magneto-resistance ratio has a sharp drop based on the estimation of a simplified modeling.

  5. Alexandrite laser transmitter development for airborne water vapor DIAL measurements

    NASA Technical Reports Server (NTRS)

    Chyba, Thomas H.; Ponsardin, Patrick; Higdon, Noah S.; DeYoung, Russell J.; Browell, Edward V.

    1995-01-01

    In the DIAL technique, the water vapor concentration profile is determined by analyzing the lidar backscatter signals for laser wavelengths tuned 'on' and 'off' a water vapor absorption line. Desired characteristics of the on-line transmitted laser beam include: pulse energy greater than or equal to 100 mJ, high-resolution tuning capability (uncertainty less than 0.25 pm), good spectral stability (jitter less than 0.5 pm about the mean), and high spectral purity (greater than 99 percent). The off-line laser is generally detuned less than 100 pm away from the water vapor line. Its spectral requirements are much less stringent. In our past research, we developed and demonstrated the airborne DIAL technique for water vapor measurements in the 720-nm spectral region using a system based on an alexandrite laser as the transmitter for the on-line wavelength and a Nd:YAG laser-pumped dye laser for the off-line wavelength. This off-line laser has been replaced by a second alexandrite laser. Diode lasers are used to injection seed both lasers for frequency and linewidth control. This eliminates the need for the two intracavity etalons utilized in our previous alexandrite laser and thereby greatly reduces the risk of optical damage. Consequently, the transmitted pulse energy can be substantially increased, resulting in greater measurement range, higher data density, and increased measurement precision. In this paper, we describe the diode injection seed source, the two alexandrite lasers, and the device used to line lock the on-line seed source to the water vapor absorption feature.

  6. The spectroscopic foundation of CO2 climate forcing

    NASA Astrophysics Data System (ADS)

    Mlynczak, M. G.; Daniels, T.; Kratz, D. P.; Collins, W.; Feldman, D.; Lawler, J. E.; Anderson, L. W.; Fahey, D. W.; Hunt, L. A.

    2015-12-01

    The radiative forcing (RF) of carbon dioxide (CO2) is the leading contribution to climate change from anthropogenic activities. Calculating CO2 RF requires detailed knowledge of spectral line parameters and lineshape functions for thousands of infrared absorption lines. A reliable spectroscopic characterization of CO2 forcing is therefore a critical input to scientific and policy-oriented assessments of present climate and future climate change. Our study is partly motivated by a recent assertion that CO2 RF values, and hence predictions of climate sensitivity to elevated CO2, have a significant high bias because the CO2 spectroscopic parameters being used are incorrect. Our results show that CO2 RF in a variety of atmospheres is remarkably insensitive to known uncertainties in the three main CO2 spectroscopic parameters: the line strengths, half widths, and line shapes. We demonstrate that this is due largely to the definition of CO2 RF, which is the difference between the CO2 longwave net flux at the tropopause for doubled CO2 concentrations from the preindustrial era. We also assess the effects of sub-Lorentzian wings of CO2 lines and find that the computed RF is largely insensitive to the spectral lineshape function. Overall, the spectroscopic uncertainty in present-day CO2 RF is less than a few percent. Our study highlights the basics and subtleties of RF calculations, addressing interests of the expert and non-expert.

  7. Visible Dayglows of the CO2 Planets

    NASA Astrophysics Data System (ADS)

    Slanger, T. G.; Kalogerakis, K.; Romanescu, C.; Lee, L. C.; Ahmed, M.; Wilson, K. R.

    2009-12-01

    Spacecraft instrumentation typically favors the UV and IR portions of the optical spectrum over the visible. As a result, there are questions that have not been answered about excited state production in various environments, including the atmospheres of the CO2 planets. For example, there are almost no oxygen green and red line measurements of Mars and Venus, and in particular, the possibility of CO emission in the Martian dayglow has not been investigated. The same holds for Venus, but dayglow Venus measurements are very difficult because of solar scattering from the clouds. CO2 photodissociation below 108 nm leads to production of the CO(a-X) Cameron bands, a well-known feature of the Mars dayglow, seen by the Mariner spacecraft [Barth et al., 1971] and by SPICAM on Mars Express [Simon et al., 2009]. However, there are three nearby CO triplet states that lie somewhat higher than the CO(a) state, the upper level of the Cameron bands, and these have fully allowed visible and IR transitions that can populate CO(a). Thus, the observed Cameron bands are the sum of the emission from the direct photodissociation process and the cascading emission [Judge and Lee, 1973]. In order to evaluate the relative contributions of each, we have performed laboratory experiments on CO2 photodissociation in the appropriate spectral region, utilizing synchrotron radiation from the Berkeley Advanced Light Source (ALS) in the 11-14 eV range. We measured the Cameron band emission at 180 260 nm, and the visible/IR emission from the triplet transitions. We could only make measurements down to 850 nm in the IR, but fortunately were able to avail ourselves of other data [Burke et al., 1996] to extend the useful range to 1.4 microns. This is very important, because the strongest bands lie in the IR. Spectra of the UV dayglow of Mars were first obtained by the Mariner probes, and it was determined [Conway, 1981] that the Cameron bands have an extremely high rotational temperature, several

  8. Geophysical Implications of Enceladus' CO2 Frost

    NASA Astrophysics Data System (ADS)

    Matson, D.; Davies, A. G.; Johnson, T. V.; Castillo, J. C.; Lunine, J. I.

    2013-12-01

    CO2 frost has been reported on the surface of Enceladus [1]. We suggest that the frost originated from shallow gas pockets below the surface. These pockets are a natural consequence of the ocean water circulation hypothesis [2]. They are different from the plume chambers [3] and would constitute a previously unrecognized structure in the surface. The oceanic circulation uses gas bubbles to make seawater buoyant and bring up water, chemicals, and heat from a warm ocean at depth [2]. The ocean water rises through the icy crust and near the surface it spreads out laterally beneath a relatively thin ice cap, following the pattern indicated by the thermal anomalies identified in Cassini data [4,5]. Topography on the bottom of this cap ice is conducive to the formation of gas pockets. As the ocean water flows horizontally, the gas bubbles in it continue to rise vertically. Even though their vertical migration may be slow and even if the flow is relatively turbulent, some bubbles reach recesses in the bottom of the ice cap and, over time, pop and form gas pockets. The gas pockets are envisioned as being ruptured by the regular fissuring of ice in the South Polar Region. Hurford et al. [6] have modelled the tidally controlled openings of rifts in the SPR. If one of these rifts reaches a gas pocket, CO2 gas may come to the surface. The tortuosity and other properties of its route will determine if it vents as a seep or a jet. If enough gas is vented and the molecules in the transient cloud have many collisions, some of them will be scattered to the surface and freeze. It was noted by Brown, et al. [1] that the frost deposits may not be permanent and that an active replenishment processes might be necessary. Studies of CO2 frost on Iapetus suggest that migration can be significant [7]. This work was performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. al., Science 311, 1425-1428, 2006. [2] Matson D. L. et al., Icarus 221, 53

  9. Enhanced Molecular Sieve CO2 Removal Evaluation

    NASA Technical Reports Server (NTRS)

    Rose, Susan; ElSherif, Dina; MacKnight, Allen

    1996-01-01

    The objective of this research is to quantitatively characterize the performance of two major types of molecular sieves for two-bed regenerative carbon dioxide removal at the conditions compatible with both a spacesuit and station application. One sorbent is a zeolite-based molecular sieve that has been substantially improved over the materials used in Skylab. The second sorbent is a recently developed carbon-based molecular sieve. Both molecular sieves offer the potential of high payoff for future manned missions by reducing system complexity, weight (including consumables), and power consumption in comparison with competing concepts. The research reported here provides the technical data required to improve CO2 removal systems for regenerative life support systems for future IVA and EVA missions.

  10. Atmospheric effects on CO2 laser propagation

    NASA Technical Reports Server (NTRS)

    Murty, S. S. R.; Bilbro, J. W.

    1978-01-01

    An investigation was made of the losses encountered in the propagation of CO2 laser radiation through the atmosphere, particularly as it applies to the NASA/Marshall Space Flight Center Pulsed Laser Doppler System. As such it addresses three major areas associated with signal loss: molecular absorption, refractive index changes in a turbulent environment, and aerosol absorption and scattering. In particular, the molecular absorption coefficients of carbon dioxide, water vapor, and nitrous oxide are calculated for various laser lines in the region of 10.6 mu m as a function of various pressures and temperatures. The current status in the physics of low-energy laser propagation through a turbulent atmosphere is presented together with the analysis and evaluation of the associated heterodyne signal power loss. Finally, aerosol backscatter and extinction coefficients are calculated for various aerosol distributions and the results incorporated into the signal-to-noise ratio equation for the Marshall Space Flight Center system.

  11. CO2 laser therapy of rhinophyma

    NASA Astrophysics Data System (ADS)

    Voigt, Peggy; Jovanovic, Sergije; Sedlmaier, Benedikt W.

    2000-06-01

    Laser treatment of skin changes has become common practice in recent years. High absorption of the CO2 laser wavelength in water is responsible for its low penetration dpt in biological tissue. Shortening the tissue exposure time minimizes thermic side effects of laser radiation such as carbonization and coagulation. This can be achieved with scanner systems that move the focused laser beam over a defined area by microprocessor-controlled rapidly rotating mirrors. This enables controlled and reliable removal of certain dermal lesions, particularly hypertrophic scars, scars after common acne, wrinkles and rhinophyma. Laser ablation of rhinophyma is a stress-minimizing procedure for the surgeon and the patient, since it is nearly bloodless and can be performed under local anaesthesia. Cosmetically favorable reepithelization of the lasered surfaces is achieved within a very short period of time.

  12. Spaceborne CO2 laser communications systems

    NASA Technical Reports Server (NTRS)

    Mcelroy, J. H.; Mcavoy, N.; Johnson, E. H.; Goodwin, F. E.; Peyton, B. J.

    1975-01-01

    Projections of the growth of earth-sensing systems for the latter half of the 1980's show a data transmission requirement of 300 Mbps and above. Mission constraints and objectives lead to the conclusion that the most efficient technique to return the data from the sensing satellite to a ground station is through a geosynchronous data relay satellite. Of the two links that are involved (sensing satellite to relay satellite and relay satellite to ground), a laser system is most attractive for the space-to-space link. The development of CO2 laser systems for space-to-space applications is discussed with the completion of a 300 Mpbs data relay receiver and its modification into a transceiver. The technology and state-of-the-art of such systems are described in detail.

  13. CO2 Sequestration and Recycle by Photosynthesis

    SciTech Connect

    Steven S.C. Chuang

    2004-02-01

    Visible light-photocatalysis could provide a cost-effective route to recycle CO2 to useful chemicals or fuels. Research is planned to study the reactivity of adsorbates, their role in the photosynthesis reaction, and their relation to the nature of surface sites during photosynthesis of methanol and hydrocarbons from CO{sub 2}/H{sub 2}O. The year two research focus catalyst screening and IR studies. Key research results show Pd/TiO2 exhibits the highest activity for hydrocarbon synthesis from photocatalytic reactions. The in situ IR could successfully monitor the adsorbate hydrocarbon species on Cu/TiO2. Year III research will focus on developing a better understanding of the key factors which control the catalyst activity.

  14. Sealing glass ampoules with CO2 lasers.

    PubMed

    Jiao, Junke; Wang, Xinbing; Tang, Wenlong

    2008-12-10

    Glass ampoules were always sealed by melting in the presence of a flame to create closures. Some poisonous gases were generated in this sealing process that pollute the injection drug and are physically harmful. In this study, CO(2) lasers were proposed for sealing glass ampoules. Because of the clean noncontact sealing process with lasers, there was nearly no pollution of the injection drug. To study in detail the principle of this sealing process, a mathematical model was put forward, and the temperature and the thermal stress field around the ampoule's neck were calculated by ANSYS software. Through experimental study, 1 ml and 5 ml ampoules were sealed successfully by a dual-laser-beam method. The results show that a laser source is an ideal heat source for sealing glass ampoules. PMID:19079460

  15. Bosch CO2 Reduction System Development

    NASA Technical Reports Server (NTRS)

    Holmes, R. F.; King, C. D.; Keller, E. E.

    1975-01-01

    Refinements in the design of a Bosch CO2 reduction unit for spacecraft O2 production are described. Sealing of the vacuum insulation jacket was simplified so that high vacuum and high insulation performance are easily maintained. The device includes a relatively simple concentric shell recuperative heat exchanger which operates at approximately 95% temperature effectiveness and helps lower power consumption. The influence of reactor temperature, pressure, and recycle gas composition on power consumption was investigated. In general, precise control is not required since power consumption is not very sensitive to moderate variations of these parameters near their optimum values. There are two process rate control modes which match flow rate to process demand. Catalyst conditioning, support, and packing pattern developments assure consistent starts, reduced energy consumption, and extended cartridge life. Operation levels for four or five men were maintained with overall power input values of 50 to 60 watts per man.

  16. Sealing glass ampoules with CO2 lasers.

    PubMed

    Jiao, Junke; Wang, Xinbing; Tang, Wenlong

    2008-12-10

    Glass ampoules were always sealed by melting in the presence of a flame to create closures. Some poisonous gases were generated in this sealing process that pollute the injection drug and are physically harmful. In this study, CO(2) lasers were proposed for sealing glass ampoules. Because of the clean noncontact sealing process with lasers, there was nearly no pollution of the injection drug. To study in detail the principle of this sealing process, a mathematical model was put forward, and the temperature and the thermal stress field around the ampoule's neck were calculated by ANSYS software. Through experimental study, 1 ml and 5 ml ampoules were sealed successfully by a dual-laser-beam method. The results show that a laser source is an ideal heat source for sealing glass ampoules.

  17. Uncertainty in gridded CO2 emissions estimates

    DOE PAGES

    Hogue, Susannah; Marland, Eric; Andres, Robert J.; Marland, Gregg; Woodard, Dawn

    2016-05-19

    We are interested in the spatial distribution of fossil-fuel-related emissions of CO2 for both geochemical and geopolitical reasons, but it is important to understand the uncertainty that exists in spatially explicit emissions estimates. Working from one of the widely used gridded data sets of CO2 emissions, we examine the elements of uncertainty, focusing on gridded data for the United States at the scale of 1° latitude by 1° longitude. Uncertainty is introduced in the magnitude of total United States emissions, the magnitude and location of large point sources, the magnitude and distribution of non-point sources, and from the use ofmore » proxy data to characterize emissions. For the United States, we develop estimates of the contribution of each component of uncertainty. At 1° resolution, in most grid cells, the largest contribution to uncertainty comes from how well the distribution of the proxy (in this case population density) represents the distribution of emissions. In other grid cells, the magnitude and location of large point sources make the major contribution to uncertainty. Uncertainty in population density can be important where a large gradient in population density occurs near a grid cell boundary. Uncertainty is strongly scale-dependent with uncertainty increasing as grid size decreases. In conclusion, uncertainty for our data set with 1° grid cells for the United States is typically on the order of ±150%, but this is perhaps not excessive in a data set where emissions per grid cell vary over 8 orders of magnitude.« less

  18. CO2 laser milling of hard tissue

    NASA Astrophysics Data System (ADS)

    Werner, Martin; Ivanenko, Mikhail; Harbecke, Daniela; Klasing, Manfred; Steigerwald, Hendrik; Hering, Peter

    2007-02-01

    Drilling of bone and tooth tissue belongs to recurrent medical procedures (screw- and pin-bores, bores for implant inserting, trepanation etc.). Small round bores can be in general quickly produced with mechanical drills. Problems arise however by angled drilling, by the necessity to fulfill the drilling without damaging of sensitive soft tissue beneath the bone, or by the attempt to mill precisely noncircular small cavities. We present investigations on laser hard tissue "milling", which can be advantageous for solving these problems. The "milling" is done with a CO2 laser (10.6 μm) with pulse duration of 50 - 100 μs, combined with a PC-controlled galvanic beam scanner and with a fine water-spray, which helps to avoid thermal side-effects. The damaging of underlying soft tissue can be prevented through control of the optical or acoustical ablation signal. The ablation of hard tissue is accompanied with a strong glowing, which is absent during the laser beam action on soft tissue. The acoustic signals from the diverse tissue types exhibit distinct differences in the spectral composition. Also computer image analysis could be a useful tool to control the operation. Laser "milling" of noncircular cavities with 1 - 4 mm width and about 10 mm depth is particularly interesting for dental implantology. In ex-vivo investigations we found conditions for fast laser "milling" of the cavities without thermal damage and with minimal tapering. It included exploration of different filling patterns (concentric rings, crosshatch, parallel lines and their combinations), definition of maximal pulse duration, repetition rate and laser power, optimal position of the spray. The optimized results give evidences for the applicability of the CO2 laser for biologically tolerable "milling" of deep cavities in the hard tissue.

  19. Framework for Assessing Biogenic CO2 Emissions from Stationary Sources

    EPA Science Inventory

    This revision of the 2011 report, Accounting Framework for Biogenic CO2 Emissions from Stationary Sources, evaluates biogenic CO2 emissions from stationary sources, including a detailed study of the scientific and technical issues associated with assessing biogenic carbon dioxide...

  20. Widespread Low-Latitude Diurnal CO2 Frost on Mars

    NASA Astrophysics Data System (ADS)

    Piqueux, S.; Kleinböhl, A.; Hayne, P. O.; Heavens, N. G.; Kass, D. M.; McCleese, D. J.; Schofield, J. T.; Shirley, J. H.

    2016-09-01

    We map and characterize MCS nighttime surface temperature observations consistent with the occurrence of CO2 frost on Mars. Low-latitude nighttime CO2 frost is widespread, with potential implications for the physical nature of the surface layer.

  1. The Use of a Pseudo Noise Code for DIAL Lidar

    NASA Technical Reports Server (NTRS)

    Burris, John F.

    2010-01-01

    Retrievals of CO2 profiles within the planetary boundary layer (PBL) are required to understand CO2 transport over regional scales and for validating the future space borne CO2 remote sensing instrument, such as the CO2 Laser Sounder, for the ASCENDS mission, We report the use of a return-to-zero (RZ) pseudo noise (PN) code modulation technique for making range resolved measurements of CO2 within the PBL using commercial, off-the-shelf, components. Conventional, range resolved, measurements require laser pulse widths that are s#rorter than the desired spatial resolution and have pulse spacing such that returns from only a single pulse are observed by the receiver at one time (for the PBL pulse separations must be greater than approximately 2000m). This imposes a serious limitation when using available fiber lasers because of the resulting low duty cycle (less than 0.001) and consequent low average laser output power. RZ PN code modulation enables a fiber laser to operate at much higher duty cycles (approaching 0.1) thereby more effectively utilizing the amplifier's output. This results in an increase in received counts by approximately two orders of magnitude. The approach involves employing two, back to back, CW fiber amplifiers seeded at the appropriate on and offline CO2 wavelengths (approximately 1572 nm) using distributed feedback diode lasers modulated by a PN code at rates significantly above 1 megahertz. An assessment of the technique, discussions of measurement precision and error sources as well as preliminary data will be presented.

  2. SOLUBILITY OF ORGANIC BIOCIDES IN SUPERCRITICAL CO2 AND CO2+ COSOLVENT MIXTURES

    EPA Science Inventory

    Solubilities of four organic biocides in supercritical carbon dioxide (Sc-CO2) were measured using a dynamic flowr apparatus over a pressure range of 10 to 30 MPa and temperature of 35-80 degrees C. The biocides studied were: Amical-48 (diiodomethyl p-tolyl sulfone), chlorothalo...

  3. Industrial CO2 Removal: CO2 Capture from Ambient Air and Geological Sequestration

    SciTech Connect

    Dooley, James J.

    2011-06-08

    This abstract and its accompanying presentation will provide an overview of two distinct industrial processes for removing carbon dioxide (CO2) from the atmosphere as a means of addressing anthropogenic climate change. The first of these is carbon dioxide capture and storage (CCS) coupled with large scale biomass production (hereafter referred to as bioCCS). The second is CO2 capture from ambient air via industrial systems (hereafter referred to as direct air capture (DAC)). In both systems, the captured CO2 would be injected into deep geologic formations so as to isolate it from the atmosphere. The technical literature is clear that both of these technologies are technically feasible as of today (IPCC, 2005; Keith, 2009; Lackner, 2009; Luckow et al., 2010; Ranjan and Herzog, 2011). What is uncertain is the relative cost of these industrial ambient-air CO2 removal systems when compared to other emissions mitigation measures, the ultimate timing and scale of their deployment, and the resolution of potential site specific constraints that would impact their ultimate commercial deployment.

  4. Assessment of CO2 flux measurements in different soil types

    NASA Astrophysics Data System (ADS)

    Xia, L.; Szlavecz, K.; Musaloiu, R.; Cupchup, J.; Pitz, S.

    2008-12-01

    Accurate measurements of soil CO2 efflux are extraordinarily challenging due to the very properties of CO2 transport in a porous medium of soil. The most commonly used method today is the chamber method, which provides direct measurements of CO2 efflux at the soil surface, but it can not measure the soil CO2 flux continuously. In order to develop new measurement methods in soil CO2 efflux, small solid-state CO2 sensors have been used to continuously to monitor soil CO2 profiles by burying these sensors at different soil depths. Using this method we compared soil CO2 efflux of four different soil types: forests soil, grassland soil (collected in Maryland) commercial potting soil and pure sand as control. CO2 concentration varied between 500 ppm in sand and 8000 ppm in forest soil at depth 12 cm. CO2 flux had the following order: Forest (0.3~0.4 mg CO2 m-2 s-1), potting soil (0.1~0.14 mg CO2 m-2 s-1 ), grassland (0.03~0.05 mg CO2 m-2 s-1), sand ( 0 mg CO2 m-2 s-1 ). Exponential relationship between temperature and CO2 flux was established for forest soil and potting soil only. Leaf litter, often thick layer in many terrestrial ecosystems and a significant source of CO2 production, is not part of the of the diffusivity models. We are currently conducting experiments which include the effect of leaf litter and soil invertebrates into soil respiration.

  5. [Effects of plastic film mulching on soil CO2 efflux and CO2 concentration in an oasis cotton field].

    PubMed

    Yu, Yong-xiang; Zhao, Cheng-yi; Jia, Hong-tao; Yu, Bo; Zhou, Tian-he; Yang, Yu-guang; Zhao, Hua

    2015-01-01

    A field study was conducted to compare soil CO2 efflux and CO2 concentration between mulched and non-mulched cotton fields by using closed chamber method and diffusion chamber technique. Soil CO2 efflux and CO2 concentration exhibited a similar seasonal pattern, decreasing from July to October. Mulched field had a lower soil CO2 efflux but a higher CO2 concentration, compared to those of non-mulched fields. Over the measurement period, cumulative CO2 efflux was 1871.95 kg C . hm-2 for mulched field and 2032.81 kg C . hm-2 for non-mulched field. Soil CO2 concentration was higher in mulched field (ranging from 5137 to 25945 µL . L-1) than in non- mulched field (ranging from 2165 to 23986 µL . L-1). The correlation coefficients between soil CO2 concentrations at different depths and soil CO2 effluxes were 0.60 to 0.73 and 0.57 to 0.75 for the mulched and non-mulched fields, indicating that soil CO2 concentration played a crucial role in soil CO2 emission. The Q10 values were 2.77 and 2.48 for the mulched and non-mulched fields, respectively, suggesting that CO2 efflux in mulched field was more sensitive to the temperature.

  6. CO2-adapted legumes ameliorate but do not prevent the negative effect of elevated CO2 on nitrogen fixation

    NASA Astrophysics Data System (ADS)

    Newton, P.; Bowatte, S.; Lieffering, M.; Li, F.

    2015-12-01

    The response of biological nitrogen fixation (BNF) to climate and elevated CO2 (eCO2) is a key uncertainty in modelling C cycle projections. In addition, as BNF provides 50% of the nitrogen (N) input to agricultural production and as ecosystem responses to eCO2 are strongly influenced by N availability then the eCO2 impact on BNF is central to modelling legume-based system responses to climate change. Greater photoassimilate production under eCO2 should lead to enhanced BNF and this response is a feature of ecosystem models thus providing the N inputs necessary to provide continuing stimulation of NPP. FACE experiments provide a 'realistic' environment for eCO2 studies; however, even if run for multiple years, they still may not capture adaptation to eCO2 particularly in ecosystems dominated by perennial species. We tested the effect of eCO2 on BNF and the potential importance of adaption by growing legumes that had been exposed to high or ambient CO2 concentrations at a natural CO2 spring in a long-running (16 year) FACE experiment on grassland. BNF was significantly lower under eCO2 but the reduction was less marked where plants had originated in a high CO2 environment. An ecosystem model run with reduced BNF proved a better fit to the experimental data for the FACE experiment than where BNF was enhanced or unchanged under eCO2.

  7. Development of Field-deployable Diode-laser-based Water Vapor Dial

    NASA Astrophysics Data System (ADS)

    Pham Le Hoai, Phong; Abo, Makoto; Sakai, Tetsu

    2016-06-01

    In this paper, a field-deployable diode-laser-based differential absorption lidar (DIAL) has been developed for lower-tropospheric water vapor observation in Tokyo, Japan. A photoacoustic cell is used for spectroscopy experiment around absorption peaks of 829.022 nm and 829.054 nm. The water vapor density extracted from the observational data agrees with the referenced radiosonde data. Furthermore, we applied modulated pulse technique for DIAL transmitter. It enables DIAL to measure water vapor profile for both low and high altitude regions.

  8. Lipid accumulation and CO2 utilization of Nannochloropsis oculata in response to CO2 aeration.

    PubMed

    Chiu, Sheng-Yi; Kao, Chien-Ya; Tsai, Ming-Ta; Ong, Seow-Chin; Chen, Chiun-Hsun; Lin, Chih-Sheng

    2009-01-01

    In order to produce microalgal lipids that can be transformed to biodiesel fuel, effects of concentration of CO(2) aeration on the biomass production and lipid accumulation of Nannochloropsis oculata in a semicontinuous culture were investigated in this study. Lipid content of N. oculata cells at different growth phases was also explored. The results showed that the lipid accumulation from logarithmic phase to stationary phase of N. oculata NCTU-3 was significantly increased from 30.8% to 50.4%. In the microalgal cultures aerated with 2%, 5%, 10% and 15% CO(2), the maximal biomass and lipid productivity in the semicontinuous system were 0.480 and 0.142 g L(-1)d(-1) with 2% CO(2) aeration, respectively. Even the N. oculata NCTU-3 cultured in the semicontinuous system aerated with 15% CO(2), the biomass and lipid productivity could reach to 0.372 and 0.084 g L(-1)d(-1), respectively. In the comparison of productive efficiencies, the semicontinuous system was operated with two culture approaches over 12d. The biomass and lipid productivity of N. oculata NCTU-3 were 0.497 and 0.151 g L(-1)d(-1) in one-day replacement (half broth was replaced each day), and were 0.296 and 0.121 g L(-1)d(-1) in three-day replacement (three fifth broth was replaced every 3d), respectively. To optimize the condition for long-term biomass and lipid yield from N. oculata NCTU-3, this microalga was suggested to grow in the semicontinuous system aerated with 2% CO(2) and operated by one-day replacement. PMID:18722767

  9. Lipid accumulation and CO2 utilization of Nannochloropsis oculata in response to CO2 aeration.

    PubMed

    Chiu, Sheng-Yi; Kao, Chien-Ya; Tsai, Ming-Ta; Ong, Seow-Chin; Chen, Chiun-Hsun; Lin, Chih-Sheng

    2009-01-01

    In order to produce microalgal lipids that can be transformed to biodiesel fuel, effects of concentration of CO(2) aeration on the biomass production and lipid accumulation of Nannochloropsis oculata in a semicontinuous culture were investigated in this study. Lipid content of N. oculata cells at different growth phases was also explored. The results showed that the lipid accumulation from logarithmic phase to stationary phase of N. oculata NCTU-3 was significantly increased from 30.8% to 50.4%. In the microalgal cultures aerated with 2%, 5%, 10% and 15% CO(2), the maximal biomass and lipid productivity in the semicontinuous system were 0.480 and 0.142 g L(-1)d(-1) with 2% CO(2) aeration, respectively. Even the N. oculata NCTU-3 cultured in the semicontinuous system aerated with 15% CO(2), the biomass and lipid productivity could reach to 0.372 and 0.084 g L(-1)d(-1), respectively. In the comparison of productive efficiencies, the semicontinuous system was operated with two culture approaches over 12d. The biomass and lipid productivity of N. oculata NCTU-3 were 0.497 and 0.151 g L(-1)d(-1) in one-day replacement (half broth was replaced each day), and were 0.296 and 0.121 g L(-1)d(-1) in three-day replacement (three fifth broth was replaced every 3d), respectively. To optimize the condition for long-term biomass and lipid yield from N. oculata NCTU-3, this microalga was suggested to grow in the semicontinuous system aerated with 2% CO(2) and operated by one-day replacement.

  10. SUBSURFACE PROPERTY RIGHTS: IMPLICATIONS FOR GEOLOGIC CO2 STORAGE

    EPA Science Inventory

    The paper discusses subsurface property rights as they apply to geologic sequestration (GS) of carbon dioxide (CO2). GS projects inject captured CO2 into deep (greater than ~1 km) geologic formations for the explicit purpose of avoiding atmospheric emission of CO2. Because of the...

  11. SUBSURFACE PROPERTY RIGHTS: IMPLICATIONS FOR GEOLOGIC CO2 SEQUESTRATION (PRESENTATION)

    EPA Science Inventory

    The paper discusses subsurface property rights as they apply to geologic sequestration (GS) of carbon dioxide (CO2). GS projects inject captured CO2 into deep (greater than ~1 km) geologic formations for the explicit purpose of avoiding atmospheric emission of CO2. Because of the...

  12. 46 CFR 108.451 - CO2 storage.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false CO2 storage. 108.451 Section 108.451 Shipping COAST... Fire Extinguishing Systems Fixed Carbon Dioxide Fire Extinguishing Systems § 108.451 CO2 storage. (a) Except as provided in paragraph (b) of this section, each cylinder of a CO2 system must be outside...

  13. 46 CFR 108.451 - CO2 storage.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false CO2 storage. 108.451 Section 108.451 Shipping COAST... Fire Extinguishing Systems Fixed Carbon Dioxide Fire Extinguishing Systems § 108.451 CO2 storage. (a) Except as provided in paragraph (b) of this section, each cylinder of a CO2 system must be outside...

  14. 46 CFR 108.451 - CO2 storage.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false CO2 storage. 108.451 Section 108.451 Shipping COAST... Fire Extinguishing Systems Fixed Carbon Dioxide Fire Extinguishing Systems § 108.451 CO2 storage. (a) Except as provided in paragraph (b) of this section, each cylinder of a CO2 system must be outside...

  15. Activation of CO2 by phosphinoamide hafnium complexes.

    PubMed

    Sgro, Michael J; Stephan, Douglas W

    2013-04-01

    Hf-phosphinoamide cation complexes behave as metal-based frustrated Lewis pairs and bind one or two equivalent of CO2 and in as well can activate CO2 in a bimetallic fashion to give a pseudo-tetrahedral P2CO2 fragment linking two Hf centres.

  16. 40 CFR 98.423 - Calculating CO2 supply.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.423 Calculating CO2 supply. (a) Except... process units that capture a CO2 stream and either measure it after segregation or do not segregate the... = Flow meter. (ii) For facilities with production process units that capture a CO2 stream and measure...

  17. Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect

    Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.; Zheng, Feng

    2010-11-10

    Current chemical CO2 scrubbing technology is primarily aqueous alkanolamine based. These systems rapidly bind CO2 (forming water-soluble carbamate and bicarbonate salts) however, the process has serious disadvantages. The concentration of monoethanolamine rarely exceeds 30 wt % due to the corrosive nature of the solution, and this reduces the maximum CO2 volumetric (≤108 g/L) and gravimetric capacity (≤7 wt%) of the CO2 scrubber. The ≤30 wt % loading of ethanolamine also means that a large excess of water must be pumped and heated during CO2 capture and release, and this greatly increases the energy requirements especially considering the high specific heat of water (4 j/g-1K-1). Our approach is to switch to organic systems that chemically bind CO2 as liquid alkylcarbonate salts. Our CO2-binding organic liquids have higher CO2 solubility, lower specific heats, potential for less corrosion and lower binding energies for CO2 than aqueous systems. CO2BOLs also reversibly bind and release mixed sulfur oxides. Furthermore the CO2BOL system can be direct solvent replacements for any solvent based CO2 capture systems because they are commercially available reagents and because they are fluids they would not require extensive process re-engineering.

  18. 40 CFR 98.423 - Calculating CO2 supply.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.423 Calculating CO2 supply. (a) Except... process units that capture a CO2 stream and either measure it after segregation or do not segregate the... = Flow meter. (ii) For facilities with production process units that capture a CO2 stream and measure...

  19. Experimental investigation of CO2 condensation process using cryogen

    NASA Astrophysics Data System (ADS)

    Lee, Cheonkyu; Yoo, Junghyun; Lee, Jisung; Park, Hana; Jeong, Sangkwon

    2014-01-01

    Carbon dioxide (CO2) is one of the dominant gas molecules that causes greenhouse effect, i.e. global warming. Numerous studies have been carried out to regulate the emission of CO2 to reduce greenhouse gas. The liquid CO2 is a convenient form of transportation compared to high-pressurized gaseous CO2. Therefore, the direct liquefaction mechanism of CO2 at low temperature draws technical attention recently. In particular, cold thermal energy of Liquefied Natural Gas (LNG) could be a candidate to condense gaseous CO2, especially in the LNG powered ship. In this paper, the detailed direct condensation process of CO2 using LN2 with intermittent solidification is investigated. Pressurized CO2 at 600 kPa is directly liquefied in a vessel by liquid nitrogen which is supplied into the coiled tube heat exchanger inside the CO2 vessel. The heat exchanger temperature is controlled from 130 K to 205 K to regulate the solidification and sublimation of CO2 by duty control with cryogenic solenoid valve. The characteristics of CO2 condensation process with cryogen are analyzed from the measurement results. The results show that the solidification causes the significant degradation of CO2 condensation heat transfer. Finally, the condensation rate with and without solidification is compared.

  20. 40 CFR 98.423 - Calculating CO2 supply.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... section. (1) For each mass flow meter, you shall calculate quarterly the mass of CO2 in a CO2 stream in... stream in metric tons by multiplying the volumetric flow by the concentration and density data, according..., or density of the whole CO2 stream for flow meter u (metric tons per standard cubic meter) if...

  1. SUBSURFACE PROPERTY RIGHTS: IMPLICATIONS FOR GEOLOGIC CO2 SEQUESTRATION

    EPA Science Inventory

    The chapter discusses subsurface property rights as they apply to geologic sequestration (GS) of carbon dioxide (CO2). GS projects inject captured CO2 into deep (greater than ~1 km) geologic formations for the explicit purpose of avoiding atmospheric emission of CO2. Because of t...

  2. Life cycle investigation of CO2 recovery and sequestration.

    PubMed

    Khoo, Hsien H; Tan, Reginald B H

    2006-06-15

    The Life Cycle Assessment of four CO2 recoverytechnologies, combined with nine CO2 sequestration systems, serves to expand the debate of CO2 mitigation methods beyond a single issue-prevention of global warming-to a wider range of environmental concerns: resource depletion, acidic and toxic gases, wastes, etc, so that the overall, and unexpected, environmental impacts may be revealed.

  3. 40 CFR 98.473 - Calculating CO2 received.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Equation UU-1 of this section. You must collect these data quarterly. Mass flow and concentration data... CO2 at standard conditions, according to Equation UU-2 of this section. You must collect these data... specified in Equation UU-3 of this section. ER01DE10.186 where: CO2 = Total net annual mass of CO2...

  4. 40 CFR 98.473 - Calculating CO2 received.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Equation UU-1 of this section. You must collect these data quarterly. Mass flow and concentration data... CO2 at standard conditions, according to Equation UU-2 of this section. You must collect these data... specified in Equation UU-3 of this section. ER01DE10.186 where: CO2 = Total net annual mass of CO2...

  5. 40 CFR 98.473 - Calculating CO2 received.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Equation UU-1 of this section. You must collect these data quarterly. Mass flow and concentration data... CO2 at standard conditions, according to Equation UU-2 of this section. You must collect these data... specified in Equation UU-3 of this section. ER01DE10.186 Where: CO2 = Total net annual mass of CO2...

  6. 40 CFR 98.473 - Calculating CO2 received.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Equation UU-1 of this section. You must collect these data quarterly. Mass flow and concentration data... CO2 at standard conditions, according to Equation UU-2 of this section. You must collect these data... specified in Equation UU-3 of this section. ER01DE10.186 where: CO2 = Total net annual mass of CO2...

  7. Life cycle investigation of CO2 recovery and sequestration.

    PubMed

    Khoo, Hsien H; Tan, Reginald B H

    2006-06-15

    The Life Cycle Assessment of four CO2 recoverytechnologies, combined with nine CO2 sequestration systems, serves to expand the debate of CO2 mitigation methods beyond a single issue-prevention of global warming-to a wider range of environmental concerns: resource depletion, acidic and toxic gases, wastes, etc, so that the overall, and unexpected, environmental impacts may be revealed. PMID:16830576

  8. Viability and metal reduction of Shewanella oneidensis MR-1 under CO2 stress: implications for ecological effects of CO2 leakage from geologic CO2 sequestration.

    PubMed

    Wu, Bing; Shao, Hongbo; Wang, Zhipeng; Hu, Yandi; Tang, Yinjie J; Jun, Young-Shin

    2010-12-01

    To study potential ecological impacts of CO(2) leakage to shallow groundwater and soil/sediments from geologic CO(2) sequestration (GCS) sites, this work investigated the viability and metal reduction of Shewanella oneidensis MR-1 under CO(2) stress. While MR-1 could grow under high-pressure nitrogen gas (500 psi), the mix of 1% CO(2) with N(2) at total pressures of 15 or 150 psi significantly suppressed the growth of MR-1, compared to the N(2) control. When CO(2) partial pressures were over 15 psi, the growth of MR-1 stopped. The reduced bacterial viability was consistent with the pH decrease and cellular membrane damage under high pressure CO(2). After exposure to 150 psi CO(2) for 5 h, no viable cells survived, the cellular contents were released, and microscopy images confirmed significant cell structure deformation. However, after a relatively short exposure (25 min) to 150 psi CO(2), MR-1 could fully recover their growth within 24 h after the stress was removed, and the reduction of MnO(2) by MR-1 was observed right after the stress was removed. Furthermore, MR-1 survived better if the cells were aggregated rather than suspended, or if pH buffering minerals, such as calcite, were present. To predict the cell viability under different CO(2) pressures and exposure times, a two-parameter mathematical model was developed.

  9. Sensory Transduction of the CO2 Response of Guard Cells

    SciTech Connect

    Dr. Eduardo Zeiger

    2003-06-30

    Stomata have a key role in the regulation of gas exchange and intercellular CO2 concentrations of leaves. Guard cells sense internal and external signals in the leaf environment and transduce these signals into osmoregulatory processes that control stomatal apertures. This research proposal addresses the characterization of the sensory transduction of the CO2 signal in guard cells. Recent studies have shown that in Vicia leaves kept at constant light and temperature in a growth chamber, changes in ambient CO2 concentrations cause large changes in guard cell zeaxanthin that are linear with CO2-dependent changes in stomatal apertures. Research proposed here will test the hypothesis that zeaxanthin function as a transducer of CO2 signals in guard cells. Three central aspects of this hypothesis will be investigated: CO2 sensing by the carboxylation reaction of Rubisco in the guard cell chloroplast, which would modulate zeaxanthin concentrations via changes in lumen pH; transduction of the CO2 signal by zeaxanthin via a transducing cascade that controls guard cell osmoregulation; and blue light dependence of the CO2 signal transduction by zeaxanthin, required for the formation of an isomeric form of zeaxanthin that is physiologically active as a transducer. The role of Rubisco in CO2 sensing will be investigated in experiments characterizing the stomatal response to CO2 in the Arabidopsis mutants R100 and rca-, which have reduced rates of Rubisco-dependent carboxylation. The role of zeaxanthin as a CO2 transducer will be studied in npq1, a zeaxanthin-less mutant. The blue light-dependence of CO2 sensing will be studied in experiments characterizing the stomatal response to CO2 under red light. Arabidopsis mutants will also be used in further studies of an acclimation of the stomatal response to CO2, and a possible role of the xanthophyll cycle of the guard cell chloroplast in acclimations of the stomatal response to CO2. Studies on the osmoregulatory role of sucrose in

  10. Application of the CO2-PENS risk analysis tool to the Rock Springs Uplift, Wyoming

    USGS Publications Warehouse

    Stauffer, P.H.; Pawar, R.J.; Surdam, R.C.; Jiao, Z.; Deng, H.; Lettelier, B.C.; Viswanathan, H.S.; Sanzo, D.L.; Keating, G.N.

    2011-01-01

    We describe preliminary application of the CO2-PENS performance and risk analysis tool to a planned geologic CO2 sequestration demonstration project in the Rock Springs Uplift (RSU), located in south western Wyoming. We use data from the RSU to populate CO2-PENS, an evolving system-level modeling tool developed at Los Alamos National Laboratory. This tool has been designed to generate performance and risk assessment calculations for the geologic sequestration of carbon dioxide. Our approach follows Systems Analysis logic and includes estimates of uncertainty in model parameters and Monte-Carlo simulations that lead to probabilistic results. Probabilistic results provide decision makers with a range in the likelihood of different outcomes. Herein we present results from a newly implemented approach in CO 2-PENS that captures site-specific spatially coherent details such as topography on the reservoir/cap-rock interface, changes in saturation and pressure during injection, and dip on overlying aquifers that may be impacted by leakage upward through wellbores and faults. We present simulations of CO 2 injection under different uncertainty distributions for hypothetical leaking wells and faults. Although results are preliminary and to be used only for demonstration of the approach, future results of the risk analysis will form the basis for a discussion on methods to reduce uncertainty in the risk calculations. Additionally, we present ideas on using the model to help locate monitoring equipment to detect potential leaks. By maintaining site-specific details in the CO2-PENS analysis we provide a tool that allows more logical presentations to stakeholders in the region. ?? 2011 Published by Elsevier Ltd.

  11. CO2 Fixation into Novel CO2 Storage Materials Composed of 1,2-Ethanediamine and Ethylene Glycol Derivatives.

    PubMed

    Zhao, Tianxiang; Guo, Bo; Han, Limin; Zhu, Ning; Gao, Fei; Li, Qiang; Li, Lihua; Zhang, Jianbin

    2015-07-20

    A new CO2 fixation process into solid CO2 -storage materials (CO2 SMs) under mild conditions has been developed. The novel application of amine-glycol systems to the capture, storage, and utilization of CO2 with readily available 1,2-ethanediamine (EDA) and ethylene glycol derivatives (EGs) was demonstrated. Typically, the CO2 SMs were isolated in 28.9-47.5 % yields, followed by extensive characterization using (13) C NMR, XRD, and FTIR. We found that especially the resulting poly-ethylene-glycol-300-based CO2 SM (PCO2 SM) product could be processed into stable tablets for CO2 storage; the aqueous PCO2 SM solution exhibited remarkable CO2 capturing and releasing capabilities after multiple cycles. Most importantly, the EDA and PEG 300 released from PCO2 SM were found to act as facilitative surfactants for the multiple preparation of CaCO3 microparticles with nano-layer structure.

  12. Shuttle Coherent Atmospheric Lidar Experiment (SCALE)

    NASA Technical Reports Server (NTRS)

    Bilbro, J.; Beranek, R.; Fitzjarrald, D.; Mabry, J.

    1987-01-01

    The results of a study to design and accommodate a simplified version of a coherent lidar system capable of performing tropospheric wind measurements are outlined. The following topics are addressed: system sensitivity, orbital analysis, science experiments, preliminary system design, accommodations, and the space qualification of a 2J CO2 laser.

  13. Determining CO2 storage potential during miscible CO2 enhanced oil recovery: Noble gas and stable isotope tracers

    USGS Publications Warehouse

    Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter; Drake, Ronald; McCray, John E.

    2016-01-01

    Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination

  14. CO2 storage capacity estimation: Methodology and gaps

    USGS Publications Warehouse

    Bachu, S.; Bonijoly, D.; Bradshaw, J.; Burruss, R.; Holloway, S.; Christensen, N.P.; Mathiassen, O.M.

    2007-01-01

    Implementation of CO2 capture and geological storage (CCGS) technology at the scale needed to achieve a significant and meaningful reduction in CO2 emissions requires knowledge of the available CO2 storage capacity. CO2 storage capacity assessments may be conducted at various scales-in decreasing order of size and increasing order of resolution: country, basin, regional, local and site-specific. Estimation of the CO2 storage capacity in depleted oil and gas reservoirs is straightforward and is based on recoverable reserves, reservoir properties and in situ CO2 characteristics. In the case of CO2-EOR, the CO2 storage capacity can be roughly evaluated on the basis of worldwide field experience or more accurately through numerical simulations. Determination of the theoretical CO2 storage capacity in coal beds is based on coal thickness and CO2 adsorption isotherms, and recovery and completion factors. Evaluation of the CO2 storage capacity in deep saline aquifers is very complex because four trapping mechanisms that act at different rates are involved and, at times, all mechanisms may be operating simultaneously. The level of detail and resolution required in the data make reliable and accurate estimation of CO2 storage capacity in deep saline aquifers practical only at the local and site-specific scales. This paper follows a previous one on issues and development of standards for CO2 storage capacity estimation, and provides a clear set of definitions and methodologies for the assessment of CO2 storage capacity in geological media. Notwithstanding the defined methodologies suggested for estimating CO2 storage capacity, major challenges lie ahead because of lack of data, particularly for coal beds and deep saline aquifers, lack of knowledge about the coefficients that reduce storage capacity from theoretical to effective and to practical, and lack of knowledge about the interplay between various trapping mechanisms at work in deep saline aquifers. ?? 2007 Elsevier Ltd

  15. On the proportionality between global temperature change and cumulative CO2 emissions during periods of net negative CO2 emissions

    NASA Astrophysics Data System (ADS)

    Zickfeld, Kirsten; MacDougall, Andrew H.; Damon Matthews, H.

    2016-05-01

    Recent research has demonstrated that global mean surface air warming is approximately proportional to cumulative CO2 emissions. This proportional relationship has received considerable attention, as it allows one to calculate the cumulative CO2 emissions (‘carbon budget’) compatible with temperature targets and is a useful measure for model inter-comparison. Here we use an Earth system model to explore whether this relationship persists during periods of net negative CO2 emissions. Negative CO2 emissions are required in the majority of emissions scenarios limiting global warming to 2 °C above pre-industrial, with emissions becoming net negative in the second half of this century in several scenarios. We find that for model simulations with a symmetric 1% per year increase and decrease in atmospheric CO2, the temperature change (ΔT) versus cumulative CO2 emissions (CE) relationship is nonlinear during periods of net negative emissions, owing to the lagged response of the deep ocean to previously increasing atmospheric CO2. When corrected for this lagged response, or if the CO2 decline is applied after the system has equilibrated with the previous CO2 increase, the ΔT versus CE relationship is close to linear during periods of net negative CO2 emissions. A proportionality constant—the transient climate response to cumulative carbon emissions (TCRE)- can therefore be calculated for both positive and net negative CO2 emission periods. We find that in simulations with a symmetric 1% per year increase and decrease in atmospheric CO2 the TCRE is larger on the upward than on the downward CO2 trajectory, suggesting that positive CO2 emissions are more effective at warming than negative emissions are at subsequently cooling. We also find that the cooling effectiveness of negative CO2 emissions decreases if applied at higher atmospheric CO2 concentrations.

  16. CO2 (dry ice) cleaning system

    NASA Technical Reports Server (NTRS)

    Barnett, Donald M.

    1995-01-01

    Tomco Equipment Company has participated in the dry ice (solid carbon dioxide, CO2) cleaning industry for over ten years as a pioneer in the manufacturer of high density, dry ice cleaning pellet production equipment. For over four years Tomco high density pelletizers have been available to the dry ice cleaning industry. Approximately one year ago Tomco introduced the DI-250, a new dry ice blast unit making Tomco a single source supplier for sublimable media, particle blast, cleaning systems. This new blast unit is an all pneumatic, single discharge hose device. It meters the insertion of 1/8 inch diameter (or smaller), high density, dry ice pellets into a high pressure, propellant gas stream. The dry ice and propellant streams are controlled and mixed from the blast cabinet. From there the mixture is transported to the nozzle where the pellets are accelerated to an appropriate blasting velocity. When directed to impact upon a target area, these dry ice pellets have sufficient energy to effectively remove most surface coatings through dry, abrasive contact. The meta-stable, dry ice pellets used for CO2 cleaning, while labeled 'high density,' are less dense than alternate, abrasive, particle blast media. In addition, after contacting the target surface, they return to their equilibrium condition: a superheated gas state. Most currently used grit blasting media are silicon dioxide based, which possess a sharp tetrahedral molecular structure. Silicon dioxide crystal structures will always produce smaller sharp-edged replicas of the original crystal upon fracture. Larger, softer dry ice pellets do not share the same sharp-edged crystalline structures as their non-sublimable counterparts when broken. In fact, upon contact with the target surface, dry ice pellets will plastically deform and break apart. As such, dry ice cleaning is less harmful to sensitive substrates, workers and the environment than chemical or abrasive cleaning systems. Dry ice cleaning system

  17. CO2 (dry ice) cleaning system

    NASA Astrophysics Data System (ADS)

    Barnett, Donald M.

    1995-03-01

    Tomco Equipment Company has participated in the dry ice (solid carbon dioxide, CO2) cleaning industry for over ten years as a pioneer in the manufacturer of high density, dry ice cleaning pellet production equipment. For over four years Tomco high density pelletizers have been available to the dry ice cleaning industry. Approximately one year ago Tomco introduced the DI-250, a new dry ice blast unit making Tomco a single source supplier for sublimable media, particle blast, cleaning systems. This new blast unit is an all pneumatic, single discharge hose device. It meters the insertion of 1/8 inch diameter (or smaller), high density, dry ice pellets into a high pressure, propellant gas stream. The dry ice and propellant streams are controlled and mixed from the blast cabinet. From there the mixture is transported to the nozzle where the pellets are accelerated to an appropriate blasting velocity. When directed to impact upon a target area, these dry ice pellets have sufficient energy to effectively remove most surface coatings through dry, abrasive contact. The meta-stable, dry ice pellets used for CO2 cleaning, while labeled 'high density,' are less dense than alternate, abrasive, particle blast media. In addition, after contacting the target surface, they return to their equilibrium condition: a superheated gas state. Most currently used grit blasting media are silicon dioxide based, which possess a sharp tetrahedral molecular structure. Silicon dioxide crystal structures will always produce smaller sharp-edged replicas of the original crystal upon fracture. Larger, softer dry ice pellets do not share the same sharp-edged crystalline structures as their non-sublimable counterparts when broken. In fact, upon contact with the target surface, dry ice pellets will plastically deform and break apart. As such, dry ice cleaning is less harmful to sensitive substrates, workers and the environment than chemical or abrasive cleaning systems. Dry ice cleaning system

  18. Coherent detectors

    NASA Astrophysics Data System (ADS)

    Lawrence, C. R.; Church, S.; Gaier, T.; Lai, R.; Ruf, C.; Wollack, E.

    2009-03-01

    Coherent systems offer significant advantages in simplicity, testability, control of systematics, and cost. Although quantum noise sets the fundamental limit to their performance at high frequencies, recent breakthroughs suggest that near-quantum-limited noise up to 150 or even 200 GHz could be realized within a few years. If the demands of component separation can be met with frequencies below 200 GHz, coherent systems will be strong competitors for a space CMB polarization mission. The rapid development of digital correlator capability now makes space interferometers with many hundreds of elements possible. Given the advantages of coherent interferometers in suppressing systematic effects, such systems deserve serious study.

  19. A CO2 concentration gradient facility for testing CO2 enrichment and soil effects on grassland ecosystem function

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Continuing increases in atmospheric CO2 concentrations mandate techniques for examining impacts on terrestrial ecosystems. Most experiments examine only two or a few levels of CO2 concentration and a single soil type, but if CO2 can be varied as a gradient from subambient to superambient concentra...

  20. Linear operating region in the ozone dial photon counting system

    NASA Technical Reports Server (NTRS)

    Andrawis, Madeleine

    1995-01-01

    Ozone is a relatively unstable molecule found in Earth's atmosphere. An ozone molecule is made up of three atoms of oxygen. Depending on where ozone resides, it can protect or harm life on Earth. High in the atmosphere, about 15 miles up, ozone acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. Without this shield, we would be more susceptible to skin cancer, cataracts, and impaired immune systems. Closer to Earth, in the air we breathe, ozone is a harmful pollutant that causes damage to lung tissue and plants. Since the early 1980's, airborne lidar systems have been used for making measurements of ozone. The differential absorption lidar (DIAL) technique is used in the remote measurement of O3. This system allows the O3 to be measured as function of the range in the atmosphere. Two frequency-doubled Nd:YAG lasers are used to pump tunable dye lasers. The lasers are operating at 289 nm for the DIAL on-line wavelength of O3, and the other one is operated at 300 nm for the off-line wavelength. The DIAL wavelengths are produced in sequential laser pulses with a time separation of 300 micro s. The backscattered laser energy is collected by telescopes and measured using photon counting systems. The photon counting system measures the light signal by making use of the photon nature of light. The output pulse from the Photo-Multiplier Tube (PE), caused by a photon striking the PMT photo-cathode, is amplified and passed to a pulse height discriminator. The peak value of the pulse is compared to a reference voltage (discrimination level). If the pulse amplitude exceeds the discrimination level, the discriminator generates a standard pulse which is counted by the digital counter. Non-linearity in the system is caused by the overlapping of pulses and the finite response time of the electronics. At low count rates one expects the system to register one event for each output pulse from the PMT corresponding to a photon incident upon the

  1. Coherence current, coherence vortex, and the conservation law of coherence.

    PubMed

    Wang, Wei; Takeda, Mitsuo

    2006-06-01

    Introducing scalar and vector densities for a mutual coherence function, we present a new conservation law for optical coherence of scalar wave fields in the form of a continuity equation. This coherence conservation law provides new insights into topological phenomena for the complex coherence function. Some properties related to the newly introduced coherence vector density, such as a circulating coherence current associated with a coherence vortex, are investigated both theoretically and experimentally for the first time.

  2. Designing photoresist systems for CO2-based microlithography

    NASA Astrophysics Data System (ADS)

    Flowers, Devin; Hoggan, Erik N.; Carbonell, Ruben G.; DeSimone, Joseph M.

    2002-07-01

    Carbon dioxide (CO2) based microlithography (dry microlithography) represents an immense opportunity for the semiconductor industry to keep pace with Moore's Law while reducing its environmental impact. Currently, rinsing <130nm developed images with supercritical CO2 is the only method which can prevent image collapse at this resolution. In this article, we will discuss CO2's ability to improve lithographic performance as we demonstrate its potential to replace the most solvent intensive steps of the microlithography process; spin coating, developing, and stripping. During these steps, semiconductor manufacturers produce vast amounts of organic and aqueous waste, which are detrimental to our ecosystem. However, before CO2 can replace conventional solvents, photoresist systems must be designed and synthesized to be compatible with CO2. These photoresists must be soluble in liquid CO2 to insure that uniform thin-films can be produced by spin coating while maintaining characteristics of conventional resist systems such as low absorbance, high sensitivity, solubility contrast, good resolution, and etch resistance. Using our CO2 compatible resist system, we will show the ability of CO2 to spin coat uniform thin-films which (after exposing and PEB) can be developed using scCO2 to produce lithography features that may be stripped in CO2. Thus, revealing the enormous potential of CO2 to provide the microlithography industry an opportunity to escape its water and organic solvent dependence.

  3. Comparison of ozone profiles obtained with NIES DIAL and SAGE II measurements

    NASA Technical Reports Server (NTRS)

    Nakane, Hideaki; Sasano, Yasuhiro; Hayashida-Amano, Sachiko; Sugimoto, Nobuo; Matsui, Ichiro; Minato, Atsushi; Mccormick, M. P.

    1993-01-01

    Ozone profiles obtained with the Differential Absorption Lidar (DIAL) system at the National Institute for Environmental Studies (NIES) (Tsukuba, Japan) were compared with data provided by the satellite sensor SAGE II. The SAGE II data were selected based on criteria of spatial and temporal differences between the DIAL and the SAGE II measurements: five degrees in latitude and 15 degrees in longitude, within a latitudinal band from 31 deg to 41 deg N, and within one, three and five days after or before the DIAL measurements. Results show very good agreement for the individual and the zonal-mean profiles. The average mean difference between the DIAL and the SAGE II measurements over the altitudes 15-50 km was about 10 percent.

  4. Correlative Stratospheric Ozone Measurements with the Airborne UV DIAL System during TOTE/VOTE

    NASA Technical Reports Server (NTRS)

    Grant, William B.; Fenn, Marta A.; Browell, Edward V.; McGee, Thomas J.; Singh, Upendra N.; Gross, Michael R.; McDermid, I. Stuart; Froidevaux, Lucien; Wang, Pi-Huang

    1998-01-01

    The airborne UV differential absorption lidar (DIAL) system participated in the Tropical Ozone Transport Experiment/Vortex Ozone Transport Experiment (TOTE/VOTE) in late 1995/early 1996. This mission afforded the opportunity to compare the DIAL system's stratospheric ozone measuring capability with other remote-sensing instruments through correlative measurements over a latitude range from the tropics to the Arctic. These instruments included ground-based DIAL and space-based stratospheric instruments: HALOE; MLS; and SAGE II. The ozone profiles generally agreed within random error estimates for the various instruments in the middle of the profiles in the tropics, but regions of significant systematic differences, especially near or below the tropopause or at the higher altitudes were also found. The comparisons strongly suggest that the airborne UV DIAL system can play a valuable role as a mobile lower-stratospheric ozone validation instrument.

  5. Observational constraints on the global atmospheric CO2 budget

    NASA Technical Reports Server (NTRS)

    Tans, Pieter P.; Fung, Inez Y.; Takahashi, Taro

    1990-01-01

    Observed atmospheric concentrations of CO2 and data on the partial pressures of CO2 in surface ocean waters are combined to identify globally significant sources and sinks of CO2. The atmospheric data are compared with boundary layer concentrations calculated with the transport fields generated by a general circulation model (GCM) for specified source-sink distributions. In the model the observed north-south atmospheric concentration gradient can be maintained only if sinks for CO2 are greater in the Northern than in the Southern Hemisphere. The observed differences between the partial pressure of CO2 in the surface waters of the Northern Hemisphere and the atmosphere are too small for the oceans to be the major sink of fossil fuel CO2. Therefore, a large amount of the CO2 is apparently absorbed on the continents by terrestrial ecosystems.

  6. Economics show CO2 EOR potential in central Kansas

    USGS Publications Warehouse

    Dubois, M.K.; Byrnes, A.P.; Pancake, R.E.; Willhite, G.P.; Schoeling, L.G.

    2000-01-01

    Carbon dioxide (CO2) enhanced oil recovery (EOR) may be the key to recovering hundreds of millions of bbl of trapped oil from the mature fields in central Kansas. Preliminary economic analysis indicates that CO2 EOR should provide an internal rate of return (IRR) greater than 20%, before income tax, assuming oil sells for $20/bbl, CO2 costs $1/Mcf, and gross utilization is 10 Mcf of CO2/bbl of oil recovered. If the CO2 cost is reduced to $0.75/Mcf, an oil price of $17/bbl yields an IRR of 20%. Reservoir and economic modeling indicates that IRR is most sensitive to oil price and CO2 cost. A project requires a minimum recovery of 1,500 net bbl/acre (about 1 million net bbl/1-mile section) under a best-case scenario. Less important variables to the economics are capital costs and non-CO2 related lease operating expenses.

  7. Halloysite Nanotubes Capturing Isotope Selective Atmospheric CO2

    NASA Astrophysics Data System (ADS)

    Jana, Subhra; Das, Sankar; Ghosh, Chiranjit; Maity, Abhijit; Pradhan, Manik

    2015-03-01

    With the aim to capture and subsequent selective trapping of CO2, a nanocomposite has been developed through selective modification of the outer surface of the halloysite nanotubes (HNTs) with an organosilane to make the nanocomposite a novel solid-phase adsorbent to adsorb CO2 from the atmosphere at standard ambient temperature and pressure. The preferential adsorption of three major abundant isotopes of CO2 (12C16O2, 13C16O2, and 12C16O18O) from the ambient air by amine functionalized HNTs has been explored using an optical cavity-enhanced integrated cavity output spectroscopy. CO2 adsorption/desorption cycling measurements demonstrate that the adsorbent can be regenerated at relatively low temperature and thus, recycled repeatedly to capture atmospheric CO2. The amine grafted halloysite shows excellent stability even in oxidative environments and has high efficacy of CO2 capture, introducing a new route to the adsorption of isotope selective atmospheric CO2.

  8. A centrifuge CO2 pellet cleaning system

    NASA Technical Reports Server (NTRS)

    Foster, C. A.; Fisher, P. W.; Nelson, W. D.; Schechter, D. E.

    1995-01-01

    An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

  9. CO2 Budget and Rectification Airborne Study

    NASA Technical Reports Server (NTRS)

    Grainger, C. A.

    2004-01-01

    The main purpose of this award was to supply a platform for the airborne measurements of gases associated with the CO2 Budget and Regional Airborne Study (COBRA). The original program was to consist of three field programs: the first was to be in 1999, the second in 2000, and the third in 2001. At the end of the second field program, it was agreed that the science could better be served by making the measurements in northern Brazil, rather than in North America. The final North American program would be postponed until after two field programs in Brazil. A substantial amount of effort was diverted into making plans and preparations for the Brazil field programs. The Brazil field programs were originally scheduled to take place in the Fall of 2002 and Spring of 2003. Carrying out the field program in Brazil was going to logistically much more involved than a program in the US. Shipping of equipment, customs, and site preparations required work to begin many months prior to the actual measurement program. Permission to fly in that country was also not trivial and indeed proved to be a major obstacle. When we were not able to get permission to fly in Brazil for the 2002 portion of the experiment, the program was pushed back to 2003. When permission by the Brazilian government was not given in time for a Spring of 2003 field program, the experiment was postponed again to begin in the Fall of 2003.

  10. CO2 laser welding fused silica.

    SciTech Connect

    Reed, Scott T.; MacCallum, Danny O'Neill; Knorovsky, Gerald Albert

    2005-08-01

    The feasibility of laser welding of fused silica (aka quartz) has been demonstrated recently by others. An application requiring hermetic sealing of a thin, pressure-bearing quartz diaphragm to a thicker frame led us to explore this technique. We found that laser welding techniques normally used for metallic parts caused scorching and uneven melting. Contrary to standard practices (near focus, high travel speed, high power density), successful welds in fused silica required a broad heat source applied over a large area under a slow rotation to gradually heat the glass through the annealing, softening and finally working temperatures. Furthermore, good mechanical contact between the parts to be joined played an even more important role in this process than in typical metallic joints. A 50 W CO2 laser with 4 f.l. ZnSe2 lens and rotary head was used to weld 0.425 OD, 0.006-0.010 thick, disks to 0.500 OD tubing with 0.125 walls. Several joint geometries and beam orientations were investigated. Temperature profiles were measured and compared to an FEM thermal model. We will discuss the effects of laser power, travel speed, number of passes, joint geometry and part thicknesses on achieving hermeticity and cosmetically-acceptable joints.

  11. Plywood Inlays Thourgh CO2 Laser Cutting

    NASA Astrophysics Data System (ADS)

    Pires, Margarida C.; Araujo, J. L.; Teixeira, M. Ribau; Rodrigues, F. Carvalho

    1989-07-01

    Furniture with inlays is rather expensive. This is so on two accounts: Firstly, furniture with inlays is generally manufactured with solid wood.Secondly,wood carving and figure cutting are both time consuming and they produce a high rate of rejections. To add to it all the cutting and carving of minute figures requires an outstanding craftmanship. In fact the craftman is in most instance the artist and also the manufacturer. While desiring that the high artistic level is maintained in the industry the search for new method to produce inlays for furniture in not son expensive materials and to produce them in a repetitive and flexible way laser cutting of plywood was found to be quite suitable. This paper presents the charts for CO2 laser cutting of both positive and negatives in several types of plywood. The main problem is not so much the cutting of the positive and negatives pieces but to be able to cut the piece in a way that the fitting is done without any problems caused by the ever present charring effect, which takes palce at the edges of the cut pieces. To minimise this aspect positive and negative pieces have to be cut under stringent focusing conditions and with slight different scales. The condittions for our machine are presented.

  12. Ionic mechanisms of central CO2 chemosensitivity

    PubMed Central

    Chernov, Mykyta M.; Erlichman, Joseph S.; Leiter, J.C.

    2010-01-01

    A comparative analysis of chemosensory systems in invertebrates and vertebrates reveals that different animals use similar strategies when sensing CO2 to control respiration. A variety of animals possess neurons that respond to changes in pH. These respiratory chemoreceptor neurons seem to rely largely on pH-dependent inhibition of potassium channels, but the channels do not appear to be uniquely adapted to detect pH. The ‘chemosensory’ potassium channels identified thus far are widely distributed, common potassium channels. The pH-sensitivity is a common feature of the channels whether the channels are in chemosensory neurons or not. Thus, the pattern of synaptic connectivity and the mix of potassium channels expressed seem to determine whether a neuron is chemosensory or not, rather than any special adaptation of a channel for pH-sensitivity. Moreover, there are often multiple pH-sensitive channels in each chemosensory neuron. These ionic mechanisms may, however, be only part of the chemosensory process, and pH-dependent modulation of synaptic activity seems to contribute to central chemosensitivity as well. In addition, the exploration of the mechanisms of pH-dependent modulation of ion channel activity in chemosensory cells is incomplete: additional mechanisms of pH modulation of channel activity may be found, and addition conductances, other than potassium channels, may participate in the chemosensory process. PMID:20380898

  13. A centrifuge CO2 pellet cleaning system

    NASA Astrophysics Data System (ADS)

    Foster, C. A.; Fisher, P. W.; Nelson, W. D.; Schechter, D. E.

    1995-03-01

    An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

  14. CO2 measurements for IAQ analysis.

    PubMed

    Woodcock, R C

    2000-05-01

    These examples illustrate the utility of carbon dioxide measurements as a diagnostic tool for indoor air quality. Carbon dioxide is sometimes said to be an unreliable indicator because of uneven mixing. However, even though mixing does occur slowly in very still air, in nearly all cases there is enough air movement that mixing is not a misleading factor for diagnostic purposes. Measurements do have to be recorded with enough context for proper interpretation. For example, to distinguish between the effects of natural and mechanical ventilation. Or to understand how the results are affected by the number of people in the building and what they are doing. Or how they relate to the nature and layout of the HVAC system and how it is adjusted or intended to be used. Carbon dioxide measurements say little about how healthy an indoor environment is. But they can tell a great deal about how comfortable it is and, with good observation, can give important clues as to where to look for factors that may be affecting health. The interaction of subjective and objective elements in the interpretation of CO2 measurements makes them a fascinating and powerful tool in the hands of a careful investigator.

  15. CO2 Condensation Models for Mars

    NASA Technical Reports Server (NTRS)

    Colaprete, A.; Haberle, R.

    2004-01-01

    During the polar night in both hemispheres of Mars, regions of low thermal emission, frequently referred to as "cold spots", have been observed by Mariner 9, Viking and Mars Global Surveyor (MGS) spacecraft. These cold spots vary in time and appear to be associated with topographic features suggesting that they are the result of a spectral-emission effect due to surface accumulation of fine-grained frost or snow. Presented here are simulations of the Martian polar night using the NASA Ames General Circulation Cloud Model. This cloud model incorporates all the microphysical processes of carbon dioxide cloud formation, including nucleation, condensation and sedimentation and is coupled to a surface frost scheme that includes both direct surface condensation and precipitation. Using this cloud model we simulate the Mars polar nights and compare model results to observations from the Thermal Emission Spectrometer (TES) and the Mars Orbiter Laser Altimeter (MOLA). Model predictions of "cold spots" compare well with TES observations of low emissivity regions, both spatially and as a function of season. The model predicted frequency of CO2 cloud formation also agrees well with MOLA observations of polar night cloud echoes. Together the simulations and observations in the North indicate a distinct shift in atmospheric state centered about Ls 270 which we believe may be associated with the strength of the polar vortex.

  16. CO2-PENS: A CO2 Sequestration Systems Model Supporting Risk-Based Decisions

    NASA Astrophysics Data System (ADS)

    Stauffer, P. H.; Viswanathan, H. S.; Guthrie, G. D.; Pawar, R. J.; Kaszuba, J. P.; Carey, J. W.; Lichtner, P. C.; Ziock, H. J.; Dubey, M. K.; Olsen, S. C.; Chipera, S. J.; Fessenden-Rahn, J. E.

    2005-12-01

    The Zero Emissions Research and Technology (ZERT) project at the Los Alamos National Laboratory is studying the injection of CO2 into geologic repositories. We are formulating the problem as science based decision framework that can address issues of risk, cost, and technical requirements at all stages of the sequestration process. The framework is implemented in a system model that is capable of performing stochastic simulations to address uncertainty in different geologic sequestration scenarios, including injection into poorly characterized brine aquifers. Processes level laboratory experiments, field experiments, modeling, economic data, and risk theory are used to support the system level model that will be the basis for decision making. The current system model, CO2-PENS, is already proving to be useful in showing complex interactions between the different components of the framework. The system model also provides a consistent platform to document decisions made during the site selection, implementation, and closure periods.

  17. Ozone Radiative Feedback in Global Warming Simulations with CO2 and non-CO2 Forcings

    NASA Astrophysics Data System (ADS)

    Ponater, M.; Rieger, V.; Dietmüller, S.

    2015-12-01

    It has been found that ozone radiative feedback acts to reduce the climate sensitivity in global warming simulations including interactive atmospheric chemistry, if the radiative forcing origins from CO2 increase. The effect can be traced to a negative feedback from stratospheric ozone changes and it is amplified by a reduced positive feedback from stratospheric water vapor.These findings cannot be simply transferred to simulations in which the warming is driven by a non-CO2 radiative forcing. Using a perturbation of surface NOx and CO emissions as an example, we demonstrate that a tropospheric ozone feedback may have significant impacts on physical feedbacks. These interactions can act to an extent that the effect of a negative ozone feedback can be reversed by changes in other feedbacks, thus increasing the climate sensitivity instead of reducing it. We also address some conceptual issues showing up as chemical feedbacks are added to set of physical feedbacks in simulation with interactive chemistry.

  18. Interpenetrating Metal-Metalloporphyrin Framework for Selective CO2 Uptake and Chemical Transformation of CO2.

    PubMed

    Gao, Wen-Yang; Tsai, Chen-Yen; Wojtas, Lukasz; Thiounn, Timmy; Lin, Chu-Chieh; Ma, Shengqian

    2016-08-01

    Herein we report a robust primitive cubic (pcu)-topology metal-metalloporphyrin framework (MMPF), MMPF-18, which was constructed from a ubiquitous secondary building unit of a tetranuclear zinc cluster, Zn4(μ4-O)(-COO)6, and a linear organic linker of 5,15-bis(4-carboxyphenyl)porphyrin (H2bcpp). The strong π-π stacking from porphyrins and the lengthy H2bcpp ligand affords a 4-fold-interpenetrating network along with reduced void spaces and confined narrow channels. Thereby, MMPF-18 presents segmented pores and high-density metalloporphyrin centers for selective CO2 uptake over CH4 and size-selective chemical transformation of CO2 with epoxides forming cyclic carbonates under ambient conditions. PMID:27337152

  19. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect

    2010-07-01

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATK’s design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  20. Use of sediment CO2 by submersed rooted plants

    PubMed Central

    Winkel, Anders; Borum, Jens

    2009-01-01

    Background and Aims Submersed plants have different strategies to overcome inorganic carbon limitation. It is generally assumed that only small rosette species (isoetids) are able to utilize the high sediment CO2 availability. The present study examined to what extent five species of submersed freshwater plants with different morphology and growth characteristics (Lobelia dortmanna, Lilaeopsis macloviana, Ludwigia repens, Vallisneria americana and Hydrocotyle verticillata) are able to support photosynthesis supplied by uptake of CO2 from the sediment. Methods Gross photosynthesis was measured in two-compartment split chambers with low inorganic carbon availability in leaf compartments and variable CO2 availability (0 to >8 mmol L−1) in root compartments. Photosynthetic rates based on root-supplied CO2 were compared with maximum rates obtained at saturating leaf CO2 availability, and 14C experiments were conducted for two species to localize bottlenecks for utilization of sediment CO2. Key Results All species except Hydrocotyle were able to use sediment CO2, however, with variable efficiency, and with the isoetid, Lobelia, as clearly the most effective and the elodeid, Ludwigia, as the least efficient. At a water column CO2 concentration in equilibrium with air, Lobelia, Lilaeopsis and Vallisneria covered >75% of their CO2 requirements by sediment uptake, and sediment CO2 contributed substantially to photosynthesis at water CO2 concentrations up to 1000 µmol L−1. For all species except Ludwigia, the shoot to root ratio on an areal basis was the single factor best explaining variability in the importance of sediment CO2. For Ludwigia, diffusion barriers limited uptake or transport from roots to stems and transport from stems to leaves. Conclusions Submersed plants other than isoetids can utilize sediment CO2, and small and medium sized elodeids with high root to shoot area in particular may benefit substantially from uptake of sediment CO2 in low alkaline lakes

  1. Atmospheric measurement of point source fossil CO2 emissions

    NASA Astrophysics Data System (ADS)

    Turnbull, J. C.; Keller, E. D.; Baisden, T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2014-05-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m above ground level. We also determined the surface CO2ff content averaged over several weeks from the 14C content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~ one week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14C sampling strategies.

  2. A Multi-scale Approach for CO2 Accounting and Risk Analysis in CO2 Enhanced Oil Recovery Sites

    NASA Astrophysics Data System (ADS)

    Dai, Z.; Viswanathan, H. S.; Middleton, R. S.; Pan, F.; Ampomah, W.; Yang, C.; Jia, W.; Lee, S. Y.; McPherson, B. J. O. L.; Grigg, R.; White, M. D.

    2015-12-01

    Using carbon dioxide in enhanced oil recovery (CO2-EOR) is a promising technology for emissions management because CO2-EOR can dramatically reduce carbon sequestration costs in the absence of greenhouse gas emissions policies that include incentives for carbon capture and storage. This study develops a multi-scale approach to perform CO2 accounting and risk analysis for understanding CO2 storage potential within an EOR environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and transport in the Marrow formation are conducted for global sensitivity and statistical analysis of the major risk metrics: CO2 injection rate, CO2 first breakthrough time, CO2 production rate, cumulative net CO2 storage, cumulative oil and CH4 production, and water injection and production rates. A global sensitivity analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/CH4 recovery rates. The well spacing (the distance between the injection and production wells) and the sequence of alternating CO2 and water injection are the major operational parameters for designing an effective five-spot CO2-EOR pattern. The response surface analysis shows that net CO2 injection rate increases with the increasing reservoir thickness, permeability, and porosity. The oil/CH4 production rates are positively correlated to reservoir permeability, porosity and thickness, but negatively correlated to the initial water saturation. The mean and confidence intervals are estimated for quantifying the uncertainty ranges of the risk metrics. The results from this study provide useful insights for understanding the CO2 storage potential and the corresponding risks of commercial-scale CO2-EOR fields.

  3. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    SciTech Connect

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  4. Monitoring and Modeling CO2 Dynamics in the Vadose Zone near an Abandoned Historic Oil Well: Implications for Detecting CO2 Leakage at Geological CO2 Sequestration Sites

    NASA Astrophysics Data System (ADS)

    Yang, C.; Romanak, K.; Hovorka, S.; Reedy, R. C.; Trevino, R.; Scanlon, B. R.

    2010-12-01

    Soil-gas monitoring is proposed for detecting CO2 leakage at geological CO2 sequestration sites. At the Cranfield oil field, about 25 km east of Natchez, Mississippi, an integrated near-surface monitoring program is being implemented where supercritical CO2 is being injected for enhanced oil recovery (EOR). The purpose of the study is to understand how natural factors may affect soil CO2 monitoring at geologic carbon storage sites. A near-surface observatory, constructed on an engineered well pad near a 1950’s era open pit and plugged and abandoned well, was used to monitor atmospheric parameters such as air temperature, relative humility, barometric pressure, wind speed and direction, solar radiation, and precipitation. Soil temperature, soil CO2 concentrations, water content, and matric potential were also monitored at various depths to a maximum of 5 m in the vadose zone. The integrated monitoring system was installed in September 2009 and continued collecting data each half hour for about 240 days. CO2 concentrations measured at 1.5 m depth are about two times that of atmospheric CO2 concentrations and show daily fluctuations. However, CO2 concentrations measured at 3 m depth decreased from 11% in November 2009 to 9% in January 2010, then gradually increased to 10.5% in June 2010. There should be no CO2 contribution from root respiration because the engineered pad is bare of vegetation. Monitored CO2 in the vadose zone at this site most likely is derived from oxidation of methane with a suspected source related to the 1950’s era plugged and abandoned well. A 1-D numerical model was also used to simulate variably saturated water flow, CO2 transport, CH4 oxidation for understanding mechanisms that dominate CO2 transport at this site. Results of this study suggest that CO2 transport in the vadose zone is very complicated and can be affected by many factors including precipitation, barometric pressure, soil temperature, oxidation of methane, and therefore may

  5. Effects of elevated CO2 concentrations on denitrifying and nitrifying popualtions at terrestrial CO2 leakeage analogous sites

    NASA Astrophysics Data System (ADS)

    Christine, Dictor Marie; Catherine, Joulian; Valerie, Laperche; Stephanie, Coulon; Dominique, Breeze

    2010-05-01

    CO2 capture and geological storage (CCS) is recognized to be an important option for carbon abatement in Europe. One of the risks of CCS is the leakage from storage site. A laboratory was conducted on soil samples sampled near-surface from a CO2 leakage analogous site (Latera, Italy) in order to evaluate the impact of an elevated soil CO2 concentration on terrestrial bacterial ecosystems form near surface terrestrial environments and to determine a potential bacterial indicator of CO2 leakage from storage site. Surveys were conducted along a 50m long transect across the vent centre, providing a spectrum of CO2 flux rates, soil gas concentrations and compositions (Beaubien et al., 2007). A bacterial diversity studies, performed by CE-SSCP technique, on a soil profile with increasing CO2 soil concentrations (from 0.3% to 100%) showed that a change on bacterial diversity was noted when CO2 concentration was above 50 % of CO2. From this result, 3 soil samples were taken at 70 cm depth in 3 distinct zones (background soil CO2 content, soil CO2 content of 20% and soil CO2 content of 50%). Then theses soil samples were incubated under closed jars flushed with different air atmospheres (20, 50 and 90 % of CO2) during 18 months. At initial, 3, 6, 12 and 18 months, some soil samples were collected in order to estimate the denitrifying, nitrifying activities as a function of CO2 concentration content and times. Theses enzymatic activities were chosen because one occurs under anaerobic conditions (denitrification) and the other occurs under aerobic conditions (nitrification). Both of them were involved in the nitrogen cycle and are major actors of soil function and groundwater quality preservation. Metabolic diversity using BIOLOG Ecoplates was determined on every soil samples. Physico-chemical parameters (e.g. pH, bulk chemistry, mineralogy) were analyzed to have some information about the evolution of the soil during the incubation with increasing soil CO2 concentrations

  6. The Wettability of Shale by CO2 and Its Impact on Geologic CO2 Sequestration

    NASA Astrophysics Data System (ADS)

    Guiltinan, E. J.; Cardenas, M. B.; Espinoza, D. N.; Yoon, H.; Dewers, T. A.

    2015-12-01

    The geologic sequestration of CO2 is widely considered as a potential solution for decreasing anthropogenic atmospheric CO2 emissions. Wettability of fluids within reservoir materials is a critical factor in determining the efficiency of structural and residual trapping, two major mechanisms of geologic sequestration. Individual reservoir minerals are often targeted for wettability studies. Current practice applies these results, recorded under laboratory conditions, to in-situ reservoir rock; however the wide variety of measured contact angles reported in the literature calls this practice into question. To address these issues and to study the wettability of shale caprock, resedimentation techniques are employed. These techniques allow for the creation of synthetic shales with controlled, homogeneous mineralogies. In addition, the systematic variation of the mineralogy allows for the characterization of shale wettability as a function of mineralogical composition. A novel design has been developed and used to conduct wettability experiments at reservoir conditions using high resolution X-ray computer tomography. Using this technique the wettability of resedimented shales and natural shales are compared at different reservoir conditions. Next, Lattice Boltzmann modelling methods are used to simulate capillary entry pressure into a shale capillary. Adhesion parameters along the wall are tuned to the results of the synthetic shales and heterogeneity is incorporated to estimate the capillary entry pressure into a natural shale. Understanding the mineralogical components of shale wetting allows for the prediction of capillary entry pressure based on shale mineralogy which can be used to help select secure CO2 storage sites.

  7. Ambient CO2, fish behaviour and altered GABAergic neurotransmission: exploring the mechanism of CO2-altered behaviour by taking a hypercapnia dweller down to low CO2 levels.

    PubMed

    Regan, Matthew D; Turko, Andy J; Heras, Joseph; Andersen, Mads Kuhlmann; Lefevre, Sjannie; Wang, Tobias; Bayley, Mark; Brauner, Colin J; Huong, Do Thi Thanh; Phuong, Nguyen Thanh; Nilsson, Göran E

    2016-01-01

    Recent studies suggest that projected rises of aquatic CO2 levels cause acid-base regulatory responses in fishes that lead to altered GABAergic neurotransmission and disrupted behaviour, threatening fitness and population survival. It is thought that changes in Cl(-) and HCO3 (-) gradients across neural membranes interfere with the function of GABA-gated anion channels (GABAA receptors). So far, such alterations have been revealed experimentally by exposing species living in low-CO2 environments, like many oceanic habitats, to high levels of CO2 (hypercapnia). To examine the generality of this phenomenon, we set out to study the opposite situation, hypothesizing that fishes living in typically hypercapnic environments also display behavioural alterations if exposed to low CO2 levels. This would indicate that ion regulation in the fish brain is fine-tuned to the prevailing CO2 conditions. We quantified pH regulatory variables and behavioural responses of Pangasianodon hypophthalmus, a fish native to the hypercapnic Mekong River, acclimated to high-CO2 (3.1 kPa) or low-CO2 (0.04 kPa) water. We found that brain and blood pH was actively regulated and that the low-CO2 fish displayed significantly higher activity levels, which were reduced after treatment with gabazine, a GABAA receptor blocker. This indicates an involvement of the GABAA receptor and altered Cl(-) and HCO3 (-) ion gradients. Indeed, Goldman calculations suggest that low levels of environmental CO2 may cause significant changes in neural ion gradients in P. hypophthalmus. Taken together, the results suggest that brain ion regulation in fishes is fine-tuned to the prevailing ambient CO2 conditions and is prone to disruption if these conditions change. PMID:26739687

  8. Ambient CO2, fish behaviour and altered GABAergic neurotransmission: exploring the mechanism of CO2-altered behaviour by taking a hypercapnia dweller down to low CO2 levels.

    PubMed

    Regan, Matthew D; Turko, Andy J; Heras, Joseph; Andersen, Mads Kuhlmann; Lefevre, Sjannie; Wang, Tobias; Bayley, Mark; Brauner, Colin J; Huong, Do Thi Thanh; Phuong, Nguyen Thanh; Nilsson, Göran E

    2016-01-01

    Recent studies suggest that projected rises of aquatic CO2 levels cause acid-base regulatory responses in fishes that lead to altered GABAergic neurotransmission and disrupted behaviour, threatening fitness and population survival. It is thought that changes in Cl(-) and HCO3 (-) gradients across neural membranes interfere with the function of GABA-gated anion channels (GABAA receptors). So far, such alterations have been revealed experimentally by exposing species living in low-CO2 environments, like many oceanic habitats, to high levels of CO2 (hypercapnia). To examine the generality of this phenomenon, we set out to study the opposite situation, hypothesizing that fishes living in typically hypercapnic environments also display behavioural alterations if exposed to low CO2 levels. This would indicate that ion regulation in the fish brain is fine-tuned to the prevailing CO2 conditions. We quantified pH regulatory variables and behavioural responses of Pangasianodon hypophthalmus, a fish native to the hypercapnic Mekong River, acclimated to high-CO2 (3.1 kPa) or low-CO2 (0.04 kPa) water. We found that brain and blood pH was actively regulated and that the low-CO2 fish displayed significantly higher activity levels, which were reduced after treatment with gabazine, a GABAA receptor blocker. This indicates an involvement of the GABAA receptor and altered Cl(-) and HCO3 (-) ion gradients. Indeed, Goldman calculations suggest that low levels of environmental CO2 may cause significant changes in neural ion gradients in P. hypophthalmus. Taken together, the results suggest that brain ion regulation in fishes is fine-tuned to the prevailing ambient CO2 conditions and is prone to disruption if these conditions change.

  9. Stem girdling affects the quantity of CO2 transported in xylem as well as CO2 efflux from soil.

    PubMed

    Bloemen, Jasper; Agneessens, Laura; Van Meulebroek, Lieven; Aubrey, Doug P; McGuire, Mary Anne; Teskey, Robert O; Steppe, Kathy

    2014-02-01

    There is recent clear evidence that an important fraction of root-respired CO2 is transported upward in the transpiration stream in tree stems rather than fluxing to the soil. In this study, we aimed to quantify the contribution of root-respired CO2 to both soil CO2 efflux and xylem CO2 transport by manipulating the autotrophic component of belowground respiration. We compared soil CO2 efflux and the flux of root-respired CO2 transported in the transpiration stream in girdled and nongirdled 9-yr-old oak trees (Quercus robur) to assess the impact of a change in the autotrophic component of belowground respiration on both CO2 fluxes. Stem girdling decreased xylem CO2 concentration, indicating that belowground respiration contributes to the aboveground transport of internal CO2 . Girdling also decreased soil CO2 efflux. These results confirmed that root respiration contributes to xylem CO2 transport and that failure to account for this flux results in inaccurate estimates of belowground respiration when efflux-based methods are used. This research adds to the growing body of evidence that efflux-based measurements of belowground respiration underestimate autotrophic contributions.

  10. Development of a stable MnCo2O4 cocatalyst for photocatalytic CO2 reduction with visible light.

    PubMed

    Wang, Sibo; Hou, Yidong; Wang, Xinchen

    2015-02-25

    The synthesis of uniform MnCo2O4 microspheres and their cooperation with a visible light harvester to achieve efficient photocatalytic CO2 reduction under ambient conditions are reported here. The MnCo2O4 materials were prepared by a facile two-step solvothermal-calcination method and were characterized by XRD, SEM, TEM, EDX, XPS, elemental mapping, and N2 adsorption measurements. By using the MnCo2O4 microspheres as a heterogeneous cocatalyst, the photocatalytic performance of the CO2-to-CO conversion catalysis was remarkably enhanced, and no decrease in the promotional effect of the cocatalyst was observed after repeatedly operating the reaction for six cycles. (13)CO2 isotope tracer experiments verified that the CO product originated from the CO2 reactant. The effect of synthetic conditions and various reaction parameters on the photocatalytic activity of the system were investigated and optimized. The stability of the MnCo2O4 cocatalyst in the CO2 reduction system was confirmed by several techniques. Moreover, a possible mechanism for MnCo2O4-cocatalyzed CO2 photoreduction catalysis is proposed. PMID:25646682

  11. Development of a stable MnCo2O4 cocatalyst for photocatalytic CO2 reduction with visible light.

    PubMed

    Wang, Sibo; Hou, Yidong; Wang, Xinchen

    2015-02-25

    The synthesis of uniform MnCo2O4 microspheres and their cooperation with a visible light harvester to achieve efficient photocatalytic CO2 reduction under ambient conditions are reported here. The MnCo2O4 materials were prepared by a facile two-step solvothermal-calcination method and were characterized by XRD, SEM, TEM, EDX, XPS, elemental mapping, and N2 adsorption measurements. By using the MnCo2O4 microspheres as a heterogeneous cocatalyst, the photocatalytic performance of the CO2-to-CO conversion catalysis was remarkably enhanced, and no decrease in the promotional effect of the cocatalyst was observed after repeatedly operating the reaction for six cycles. (13)CO2 isotope tracer experiments verified that the CO product originated from the CO2 reactant. The effect of synthetic conditions and various reaction parameters on the photocatalytic activity of the system were investigated and optimized. The stability of the MnCo2O4 cocatalyst in the CO2 reduction system was confirmed by several techniques. Moreover, a possible mechanism for MnCo2O4-cocatalyzed CO2 photoreduction catalysis is proposed.

  12. Survival times of pre-1950 US women radium dial workers

    SciTech Connect

    Stehney, A.F.

    1994-05-01

    Survival times of US women radium dial workers to the end of 1989 were examined by life table methods. Included were 1301 women rust employed before 1930 and 1242 first employed in 1930-1949. Expected numbers of deaths were estimated from age- and time-specific death rates for US white females. In the early group, 85 deaths from the well-known radium-induced cancers - bone sarcomas and head carcinomas - were observed, but only 724 deaths from aH other causes were observed vs 755 expected. Life shortening ({plus_minus}S.E.) of 1.8 {plus_minus}0.5 y compared to the general population of US white females was calculated from the time distribution of all deaths in the pre-1930 group. In the 1930--1949 group, 350 deaths were observed vs 343 expected and no bone sarcomas or head carcinomas occurred. Among women who survived at least 2 y after rust measurement of body radium, a significant excess of observed vs expected deaths was found only for radium intakes greater than 1.85 MBq of {sup 226}Ra + {sup 228}Ra, and no trend of deaths or reduction of life expectancy was found with length of employment.

  13. Development of a Compact, Ground-Based Ozone DIAL System

    NASA Technical Reports Server (NTRS)

    Chyba, T. H.; Zenker, T.; McCray, C. L.; Lee, H. R.; Thomas, B.; Elivert, R.; Higdon, N. Scott; Richter, D. A.; Fishman, J.

    1998-01-01

    We are developing a portable, eye-safe, ground-based ozone lidar instrument specialized for ozone differential absorption lidar (DIAL) measurements in the troposphere. This prototype instrument is intended to operate at remote field sites and to serve as the basic unit for future monitoring projects requiring multi-instrument networks, such as that proposed for the Global Tropospheric Ozone Project (GTOP). GTOP is currently being formulated by a scientific panel of the International Global Atmospheric Chemistry Project to meet its goal to better understand the processes that control the global distribution of tropospheric ozone. In order for the lidar to be widely deployed in networks, it must be fairly easy to use and maintain as well as being cost-competitive with ground station launching ozone sondes which operate several times a day. To achieve these goals, emphasis is placed upon the incorporation of: (1) all-solid state transmitters which can reliably produce 20-40 mJ pulses; (2) a highly efficient, narrow-bandpass receiver; (3) dual analog and photon-counting detector channels; and (4) flexible, user-friendly control software.

  14. Flight tests of the Digital Integrated Automatic Landing System (DIALS)

    NASA Technical Reports Server (NTRS)

    Halyo, N.

    1984-01-01

    The design, development, implementation and flight tests of the Digital Integrated Automatic Landing System (DIALS) are discussed. The system was implemented and flight tested on the Transport Systems Research Vehicle (TSRV), a Boeing 737-100. The design uses modern optimal control methods. The direct digital design obtained uses a 10 Hz rate for the sampling of sensors and the control commands. The basic structure of the control law consists of a steady state Kalman filter followed by a control gain matrix. The sensor information used includes Microwave Landing System (MLS) position, attitude, calibrated airspeed, and body accelerations. The phases of the final approach considered are localized and steep glideslope capture (which may be performed simultaneously or independently), localizer and glideslope track, crab/decrab, and flare to touchdown. The system can capture, track, and flare from conventional, as well as steep, glideslopes ranging from 2.5 deg to 5.5 deg. All of the modes of the control law including the Kalman filters were implemented on the TSRV flight computers which use fixed point arithmetic with 16 bit words. The implementation considerations are described as well as an analysis of the flight test results.

  15. Sequestering CO2 in the Built Environment

    NASA Astrophysics Data System (ADS)

    Constantz, B. R.

    2009-12-01

    Calera’s Carbonate Mineralization by Aqueous Precipitation (CMAP) technology with beneficial reuse has been called, “game-changing” by Carl Pope, Director of the Sierra Club. Calera offers a solution to the scale of the carbon problem. By capturing carbon into the built environment through carbonate mineralization, Calera provides a sound and cost-effective alternative to Geologic Sequestration and Terrestrial Sequestration. The CMAP technology permanently converts carbon dioxide into a mineral form that can be stored above ground, or used as a building material. The process produces a suite of carbonate-containing minerals of various polymorphic forms. Calera product can be substituted into blends with ordinary Portland cements and used as aggregate to produce concrete with reduced carbon, carbon neutral, or carbon negative footprints. For each ton of product produced, approximately half a ton of carbon dioxide can be sequestered using the Calera process. Coal and natural gas are composed of predominately istopically light carbon, as the carbon in the fuel is plant-derived. Thus, power plant CO2 emissions have relatively low δ13C values.The carbon species throughout the CMAP process are identified through measuring the inorganic carbon content, δ13C values of the dissolved carbonate species, and the product carbonate minerals. Measuring δ13C allows for tracking the flue gas CO2 throughout the capture process. Initial analysis of the capture of propane flue gas (δ13C ˜ -25 ‰) with seawater (δ13C ˜ -10 ‰) and industrial brucite tailings from a retired magnesium oxide plant in Moss Landing, CA (δ13C ˜ -7 ‰ from residual calcite) produced carbonate mineral products with a δ13C value of ˜ -20 ‰. This isotopically light carbon, transformed from flue gas to stable carbonate minerals, can be transferred and tracked through the capture process, and finally to the built environment. CMAP provides an economical solution to global warming by producing

  16. A relationship between dissolved CO2 and the non-volatile chemistry of rainwater.

    NASA Astrophysics Data System (ADS)

    Durham, Brian; Pfrang, Christian

    2016-04-01

    Measurements of a volatile acid component in UK rainwater in 2009 implicated CO2, and speculated `a concentrating mechanism (that) could mean that this weakly soluble molecule is recycled at a faster rate than inferred by its Henry's Law constant'. Last year's EGU Presentation 2015-3386 confirmed that the `saturated CO2 content (of UK rainwater) is insignificant, the bulk transport being the volatile component'. However the atmospheric capture mechanism remains enigmatic. For pure water, improved temperature control has discounted the predicted upturn in the Henry coefficient for 450Pa CO2 as the temperature approached freezing point (http://presentations.copernicus.org/EGU2015-3386_presentation.pptx), and the focus has therefore turned to rainwater chemistry. For a mid-range sample the Henry value was: • significantly higher than pure water at 20'C; • but decreasing with lower temperatures. The higher Henry constant might suggest that, as an acid anhydride, CO2 is subject to selective capture where cloud water is alkaline (terrestrial dust or marine aerosol). Analysis has however shown no simple relationship between [CO2]aq and either acidity or conductivity of the carrier water. Seeking therefore a coherent distribution, stripped CO2 was plotted against Δ[H+], from which this paper presents a tight wedge-shaped distribution of 263 UK rain/snow events. The inference is that [CO2]aq is not related directly to [H+], but possibly to Group 1 and 2 cations from marine aerosol that are buffering the cloud water acidity. By contrast, the unexpected decrease in CO2 yield with lower temperatures proved to be an artefact of a progressively slower rate of de-gassing, cooler samples still equilibrating after 100 minutes. An ultrasound stripper is therefore being developed to speed the Henry measurements, and for reproducibility it is proposed to dilute a proprietary `standard Atlantic sea water' to a representative range of conductivities, to be called `standard

  17. Continuous soil respiration at the Prairie Heating and Elevated CO2 site using forced diffusion chambers

    NASA Astrophysics Data System (ADS)

    Pendall, E.; Brennan, A. L.; Risk, D. A.; Carrillo, Y.

    2012-12-01

    chamber method, at least during the growing season when fluxes were above 0.5 umol m-2 s-1. Preliminary evaluation of timeseries data revealed strong coherence at 24-hours and immediate responses to precipitation events. On average, soil and microbial respiration rates were lowest from the warmed plots and highest from ambient plots. Microbial respiration rates in plant-free plots were generally 25 to 75 percent lower than soil respiration rates. Quantification of temperature sensitivity and moisture responses is underway, as is evaluation of the stability of calibration of the NDIR sensors and the diffusivity coefficients of the chambers. This research contributes to understanding the utility and limitations of deploying soil CO2 sensor networks to help inform ecosystem process models.

  18. Simulation of the Performances of WIND, an Airborne CO2 Lidar

    NASA Technical Reports Server (NTRS)

    Oh, D.; Dabas, A.; Lieutaud, F.; Loth, C.; Flamant, P. H.

    1992-01-01

    An airborne Doppler coherent lidar is under development as a joint project between France and Germany. The instrument is designed around CO2 laser technology, heterodyne detection, and a conical scanning of the line-of-site. The 10 micron domain is suitable for long range measurements due to the maturity of the technology and because it corresponds to an atmospheric window. The objectives of WIND are twofold: (1) to conduct mesoscale scientific studies in particular over oceanic and inhomogeneous terrain areas; and (2) to support the Earth-orbiting wind lidar projects.

  19. Volumetrics of CO2 storage in deep saline formations.

    PubMed

    Steele-MacInnis, Matthew; Capobianco, Ryan M; Dilmore, Robert; Goodman, Angela; Guthrie, George; Rimstidt, J Donald; Bodnar, Robert J

    2013-01-01

    Concern about the role of greenhouse gases in global climate change has generated interest in sequestering CO(2) from fossil-fuel combustion in deep saline formations. Pore space in these formations is initially filled with brine, and space to accommodate injected CO(2) must be generated by displacing brine, and to a lesser extent by compression of brine and rock. The formation volume required to store a given mass of CO(2) depends on the storage mechanism. We compare the equilibrium volumetric requirements of three end-member processes: CO(2) stored as a supercritical fluid (structural or stratigraphic trapping); CO(2) dissolved in pre-existing brine (solubility trapping); and CO(2) solubility enhanced by dissolution of calcite. For typical storage conditions, storing CO(2) by solubility trapping reduces the volume required to store the same amount of CO(2) by structural or stratigraphic trapping by about 50%. Accessibility of CO(2) to brine determines which storage mechanism (structural/stratigraphic versus solubility) dominates at a given time, which is a critical factor in evaluating CO(2) volumetric requirements and long-term storage security.

  20. Volumetrics of CO2 storage in deep saline formations.

    PubMed

    Steele-MacInnis, Matthew; Capobianco, Ryan M; Dilmore, Robert; Goodman, Angela; Guthrie, George; Rimstidt, J Donald; Bodnar, Robert J

    2013-01-01

    Concern about the role of greenhouse gases in global climate change has generated interest in sequestering CO(2) from fossil-fuel combustion in deep saline formations. Pore space in these formations is initially filled with brine, and space to accommodate injected CO(2) must be generated by displacing brine, and to a lesser extent by compression of brine and rock. The formation volume required to store a given mass of CO(2) depends on the storage mechanism. We compare the equilibrium volumetric requirements of three end-member processes: CO(2) stored as a supercritical fluid (structural or stratigraphic trapping); CO(2) dissolved in pre-existing brine (solubility trapping); and CO(2) solubility enhanced by dissolution of calcite. For typical storage conditions, storing CO(2) by solubility trapping reduces the volume required to store the same amount of CO(2) by structural or stratigraphic trapping by about 50%. Accessibility of CO(2) to brine determines which storage mechanism (structural/stratigraphic versus solubility) dominates at a given time, which is a critical factor in evaluating CO(2) volumetric requirements and long-term storage security. PMID:22916959

  1. Polyurethane Foam-Based Ultramicroporous Carbons for CO2 Capture.

    PubMed

    Ge, Chao; Song, Jian; Qin, Zhangfeng; Wang, Jianguo; Fan, Weibin

    2016-07-27

    A series of sustainable porous carbon materials were prepared from waste polyurethane foam and investigated for capture of CO2. The effects of preparation conditions, such as precarbonization, KOH to carbon precursor weight ratio, and activation temperature, on the porous structure and CO2 adsorption properties were studied for the purpose of controlling pore sizes and nitrogen content and developing high-performance materials for capture of CO2. The sample prepared at optimum conditions shows CO2 adsorption capacities of 6.67 and 4.33 mmol·g(-1) at 0 and 25 °C under 1 bar, respectively, which are comparable to those of the best reported porous carbons prepared from waste materials. The HCl treatment experiment reveals that about 80% of CO2 adsorption capacity arises from physical adsorption, while the other 20% is due to the chemical adsorption originated from the interaction of basic N groups and CO2 molecules. The relationship between CO2 uptake and pore size at different temperatures indicates that the micropores with pore size smaller than 0.86 and 0.70 nm play a dominant role in the CO2 adsorption at 0 and 25 °C, respectively. It was found that the obtained carbon materials exhibited high recyclability and high selectivity to adsorption of CO2 from the CO2 and N2 mixture. PMID:27376177

  2. Bubble nucleation in polymer–CO2 mixtures.

    PubMed

    Xu, Xiaofei; Cristancho, Diego E; Costeux, Stéphane; Wang, Zhen-Gang

    2013-10-28

    We combine density-functional theory with the string method to calculate the minimum free energy path of bubble nucleation in two polymer–CO2 mixture systems, poly(methyl methacrylate) (PMMA)–CO2 and polystyrene (PS)–CO2. Nucleation is initiated by saturating the polymer liquid with high pressure CO2 and subsequently reducing the pressure to ambient condition. Below a critical temperature (Tc), we find that there is a discontinuous drop in the nucleation barrier as a function of increased initial CO2 pressure (P0), as a result of an underlying metastable transition from a CO2-rich-vapor phase to a CO2-rich-liquid phase. The nucleation barrier is generally higher for PS–CO2 than for PMMA–CO2 under the same temperature and pressure conditions, and both higher temperature and higher initial pressure are required to lower the nucleation barrier for PS–CO2 to experimentally relevant ranges. Classical nucleation theory completely fails to capture the structural features of the bubble nucleus and severely underestimates the nucleation barrier. PMID:26029777

  3. Sequestration of Dissolved CO2 in the Oriskany Formation

    SciTech Connect

    Dilmore, R.M.; Allen, D.E.; McCarthy-Jones, J.R.; Hedges, S.W.; Soong, Yee

    2008-04-15

    Experiments were conducted to determine the solubility of CO2 in a natural brine solution of the Oriskany formation under elevated temperature and pressure conditions. These data were collected at temperatures of 22 and 75 °C and pressures between 100 and 450 bar. Experimentally determined data were compared with CO2 solubility predictions using a model developed by Duan and Sun (Chem. Geol. 2003, 193, 257-271). Model results compare well with Oriskany brine CO2 solubility data collected experimentally, suggesting that the Duan and Sun model is a reliable tool for estimating solution CO2 capacity in high salinity aquifers in the temperature and pressure range evaluated. The capacity for the Oriskany formation to sequester dissolved CO2 was calculated using results of the solubility models, estimation of the density of CO2 saturated brine, and available geographic information system (GIS) information on the formation depth and thickness. Results indicate that the Oriskany formation can hold approximately 0.36 gigatonnes of dissolved CO2 if the full basin is considered. When only the region where supercritical CO2 can exist (temperatures greater than 31° C and pressures greater than 74 bar) is considered, the capacity of the Oriskany formation to sequester dissolved CO2 is 0.31 gigatonnes. The capacity estimate considering the potential to sequester free-phase supercritical CO2 if brine were displaced from formation pore space is 8.8 gigatonnes in the Oriskany formation.

  4. Common Freshwater Cyanobacteria Grow in 100% CO2

    NASA Astrophysics Data System (ADS)

    Thomas, David J.; Sullivan, Shannon L.; Price, Amanda L.; Zimmerman, Shawn M.

    2005-02-01

    Cyanobacteria and similar organisms produced most of the oxygen found in Earth's atmosphere, which implies that early photosynthetic organisms would have lived in an atmosphere that was rich in CO2 and poor in O2. We investigated the tolerance of several cyanobacteria to very high (>20 kPa) concentrations of atmospheric CO2. Cultures of Synechococcus PCC7942, Synechocystis PCC7942, Plectonema boryanum, and Anabaena sp. were grown in liquid culture sparged with CO2-enriched air. All four strains grew when transferred from ambient CO2 to 20 kPa partial pressure of CO2 (pCO2), but none of them tolerated direct transfer to 40 kPa pCO2. Synechococcus and Anabaena survived 101 kPa (100%) pCO2 when pressure was gradually increased by 15 kPa per day, and Plectonema actively grew under these conditions. All four strains grew in an anoxic atmosphere of 5 kPa pCO2 in N2. Strains that were sensitive to high CO2 were also sensitive to low initial pH (pH 5-6). However, low pH in itself was not sufficient to prevent growth. Although mechanisms of damage and survival are still under investigation, we have shown that modern cyanobacteria can survive under Earth's primordial conditions and that cyanobacteria-like organisms could have flourished under conditions on early Mars, which probably had an atmosphere similar to early Earth's.

  5. Enhanced CO2 Dissolution in Heterogeneous Porous Media

    NASA Astrophysics Data System (ADS)

    Daniels, K.; Neufeld, J. A.; Bickle, M. J.; Hallworth, M. A.

    2014-12-01

    Long-term and secure geological storage of CO2 through technologies such as Carbon Capture and Storage (CCS) within reservoirs is seen as a technological means to reduce anthropogenic CO2 emissions. The long-term viability of this technology is reliant on the structural and secondary trapping of supercritical CO2 within heterogeneous reservoirs. Secondary trapping, primarily through the dissolution of CO2 into ambient reservoir brine to produce a denser fluid, is capable of retaining CO2 in the subsurface and thus reducing the risks of storage. To model secondary trapping we need to understand how the flow of CO2 through heterogeneous reservoir rocks enhances dissolution of supercritical CO2 in reservoir brines. Here we experimentally investigate the dissolution of CO2 in reservoir brines in layered, heterogeneous geological formations. Using analogue experiments, designed to approximate an enhanced oil recovery (EOR) setting, the processes of mixing, dispersion and dissolution are examined. These are compared against test results from non-layered, homogeneous porous media experiments. We find that heterogeneities significantly enhance mixing, particularly between adjacent porous layers. During fluid propagation, pore-scale viscous fingers grow and retreat, thereby providing an increased surface area between the flow and the ambient reservoir fluid. This enhanced mixing is predicted to substantially increase the dissolution of CO2 in reservoir brines. Both permeability and viscosity differences are found to have a significant effect on the interface between the two fluids, and therefore the likely amount of dissolution of CO2.

  6. Buoyant dispersal of CO2 during geological storage

    NASA Astrophysics Data System (ADS)

    Hesse, M. A.; Woods, A. W.

    2010-01-01

    Carbon capture and storage is currently the only technology that may allow significant reductions in CO2 emissions from large point sources. Seismic images of geological CO2 storage show the rise of CO2 is influenced by horizontal shales. The buoyant CO2 spreads beneath impermeable barriers until a gap allows its upward migration. The large number and small scale of these barriers makes the prediction of the CO2 migration path and hence the magnitude of CO2 trapping very challenging. We show that steady buoyancy dominated flows in complex geometries can be modeled as a cascade of flux partitioning events. This approach allows the analysis of two-dimensional plume dispersal from a horizontal injection well. We show that the plume spreads laterally with height y above the source according to (y/h)1/2 L, where L is the width of the shales and h is their vertical separation. The fluid volume below successive shale layers, and therefore the magnitude of trapped CO2, increase as (y/h)5/4 above the source, so that every additional layer of barriers traps more CO2 than the one below. Upscaling small scale flow barriers by reducing the vertical permeability, common in numerical simulations of CO2 storage, does not capture the dispersion and trapping of the CO2 plume by the flow barriers.

  7. Drilling and production - Economics show CO2 EOR potential

    USGS Publications Warehouse

    Dubois, M.K.; Byrnes, A.P.

    2000-01-01

    CO2 EOR may be the key to recovering hundreds of millions of bbl of trapped oil from the mature fields in central Kansas. A simple model aided in assessing the economics of CO2 EOR for central Kansas and the Midcontinent. The model used CO2 Prophet, a DOE freeware reservoir numerical simulation program, to determine reservoir performance, including injected and produced fluid rates, and CO2 utilization. Economic parameters, e.g., oil price, CO2 costs, capital costs, net revenue interest, production taxes, and lease operating expenses, are typical for anticipated conditions in the region and present price climate. Preliminary economic analysis shows that CO2 EOR should give an internal rate of return (IRR) > 20%, before income tax, assuming oil sells for $20/bbl, CO2 costs $1/million cu ft, and gross utilization is 10 million cu ft of CO2/bbl of oil recovered. If the CO2 is reduced to $0.75/million cu ft, an oil price of $17/bbl yields an IRR of 20%. Reservoir and economic modeling shows that IRR is most sensitive to oil price and CO2 cost.

  8. Bubble nucleation in polymer–CO2 mixtures.

    PubMed

    Xu, Xiaofei; Cristancho, Diego E; Costeux, Stéphane; Wang, Zhen-Gang

    2013-10-28

    We combine density-functional theory with the string method to calculate the minimum free energy path of bubble nucleation in two polymer–CO2 mixture systems, poly(methyl methacrylate) (PMMA)–CO2 and polystyrene (PS)–CO2. Nucleation is initiated by saturating the polymer liquid with high pressure CO2 and subsequently reducing the pressure to ambient condition. Below a critical temperature (Tc), we find that there is a discontinuous drop in the nucleation barrier as a function of increased initial CO2 pressure (P0), as a result of an underlying metastable transition from a CO2-rich-vapor phase to a CO2-rich-liquid phase. The nucleation barrier is generally higher for PS–CO2 than for PMMA–CO2 under the same temperature and pressure conditions, and both higher temperature and higher initial pressure are required to lower the nucleation barrier for PS–CO2 to experimentally relevant ranges. Classical nucleation theory completely fails to capture the structural features of the bubble nucleus and severely underestimates the nucleation barrier.

  9. Common freshwater cyanobacteria grow in 100% CO2.

    PubMed

    Thomas, David J; Sullivan, Shannon L; Price, Amanda L; Zimmerman, Shawn M

    2005-02-01

    Cyanobacteria and similar organisms produced most of the oxygen found in Earth's atmosphere, which implies that early photosynthetic organisms would have lived in an atmosphere that was rich in CO2 and poor in O2. We investigated the tolerance of several cyanobacteria to very high (>20 kPa) concentrations of atmospheric CO2. Cultures of Synechococcus PCC7942, Synechocystis PCC7942, Plectonema boryanum, and Anabaena sp. were grown in liquid culture sparged with CO2-enriched air. All four strains grew when transferred from ambient CO2 to 20 kPa partial pressure of CO2 (pCO2), but none of them tolerated direct transfer to 40 kPa pCO2. Synechococcus and Anabaena survived 101 kPa (100%) pCO2 when pressure was gradually increased by 15 kPa per day, and Plectonema actively grew under these conditions. All four strains grew in an anoxic atmosphere of 5 kPa pCO2 in N2. Strains that were sensitive to high CO2 were also sensitive to low initial pH (pH 5-6). However, low pH in itself was not sufficient to prevent growth. Although mechanisms of damage and survival are still under investigation, we have shown that modern cyanobacteria can survive under Earth's primordial conditions and that cyanobacteria-like organisms could have flourished under conditions on early Mars, which probably had an atmosphere similar to early Earth's. PMID:15711170

  10. System-level modeling for geological storage of CO2

    SciTech Connect

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-04-24

    One way to reduce the effects of anthropogenic greenhousegases on climate is to inject carbon dioxide (CO2) from industrialsources into deep geological formations such as brine formations ordepleted oil or gas reservoirs. Research has and is being conducted toimprove understanding of factors affecting particular aspects ofgeological CO2 storage, such as performance, capacity, and health, safetyand environmental (HSE) issues, as well as to lower the cost of CO2capture and related processes. However, there has been less emphasis todate on system-level analyses of geological CO2 storage that considergeological, economic, and environmental issues by linking detailedrepresentations of engineering components and associated economic models.The objective of this study is to develop a system-level model forgeological CO2 storage, including CO2 capture and separation,compression, pipeline transportation to the storage site, and CO2injection. Within our system model we are incorporating detailedreservoir simulations of CO2 injection and potential leakage withassociated HSE effects. The platform of the system-level modelingisGoldSim [GoldSim, 2006]. The application of the system model is focusedon evaluating the feasibility of carbon sequestration with enhanced gasrecovery (CSEGR) in the Rio Vista region of California. The reservoirsimulations are performed using a special module of the TOUGH2 simulator,EOS7C, for multicomponent gas mixtures of methane and CO2 or methane andnitrogen. Using this approach, the economic benefits of enhanced gasrecovery can be directly weighed against the costs, risks, and benefitsof CO2 injection.

  11. Processes affecting the CO2 concentrations measured in Greenland ice

    NASA Astrophysics Data System (ADS)

    Anklin, Martin; Barnola, Jean-Marc; Schwander, Jakob; Stauffer, Bernhard; Raynaud, Dominique

    1995-09-01

    Detailed CO2 measurements on ice cores from Greenland and Antarctica show different mean CO2 concentrations for samples at the same gas age. The deviation between Antarctic and Greenland CO2 records raises up to 20 ppmv during the last millennium. Based on the present knowledge of the global carbon cycle we can exclude such a high mean interhemispheric difference of the CO2 concentration between high northern and southern latitudes. Diffusive mixing of the air in the firn smoothes out short term variations of the atmospheric CO2 Concentration. Nevertheless, we observe short term CO2 variations in Greenland ice in the range of 10 20 ppmv, which cannot represent atmospheric CO2 variations. Due to the low temperature at Summit, meltlayers can be excluded for most of the ice and they cannot account for the frequent anomalous short term CO2 variations and the elevated mean CO2 concentration in the Greenland ice. In this work we give some clues, that in situ production of CO2 in Greenland ice could build up excess CO2 after pore close of. Possible chemical reactions are the oxidation of organic carbon and the reaction between acidity and carbonate. We conclude that the carbonate-acidity reaction is the most probable process to explain the excess CO2 in the bubbles. The reaction could take place in very small liquid-like veins in cold ice, where the mobility of impurities is higher than in the ice lattice. At present, there exists no technique to measure the carbonate concentration in the ice directly. However, a comparison of CO2 analyses performed with a dry- and a wet-extraction technique allows to estimate the carbonate content of the ice. This estimate indicates a carbonate concentration in Greenland ice of about 0.4±0.2µmol/l and a much lower concentration in Antarctic ice.

  12. Waste benefits of CO2 policies in Japan.

    PubMed

    Gielen, D J; Moriguchi, Y

    2002-02-01

    A linear programming model REAP (Regional Environmental strategy Analysis Program) has been developed for the analysis of the consequences of a CO2 tax for petrochemical products such as plastics (CO2, carbon dioxide, is the most important greenhouse gas). Special attention has been paid to the impacts on waste management. The results suggest that a 10,000 Y t(-1) CO2 tax would result in a significant reduction of CO2 emissions in the petrochemical life cycle, ranging from 40 Mt in 2015 to 70 Mt CO2 in later decades (more than 50% emission reduction). Waste quantities will be reduced simultaneously. The CO2 tax results in an 18% reduction of plastic waste weight in 2015 (3 Mt waste). Lower tax levels that may be politically more acceptable would result in proportionally lower environmental benefits. CO2 benefits and waste benefits of a CO2 tax are of equal importance in policy terms. Apart from changes in waste volume, CO2 taxes would affect the cost-effectiveness of waste handling technologies. Energy recovery in industrial kilns may replace conventional waste incineration. Recycling constitutes half of the total waste treatment. Given these results, current investments in new incineration capacity may suffer from insufficient waste availability during the next two decades in case CO2 taxes are introduced. A third effect of a CO2 tax is a significant increase of waste transportation. The results show that this increase is concentrated in the central part of Honshu (Kinki, Chubu & Kanto). Such transportation can result in new local environmental impacts that should be analysed in more detail. Given the strong impact of CO2 taxes on waste quantities and waste treatment it is recommended to co-ordinate CO2 policies and solid waste policies.

  13. Waste benefits of CO2 policies in Japan.

    PubMed

    Gielen, D J; Moriguchi, Y

    2002-02-01

    A linear programming model REAP (Regional Environmental strategy Analysis Program) has been developed for the analysis of the consequences of a CO2 tax for petrochemical products such as plastics (CO2, carbon dioxide, is the most important greenhouse gas). Special attention has been paid to the impacts on waste management. The results suggest that a 10,000 Y t(-1) CO2 tax would result in a significant reduction of CO2 emissions in the petrochemical life cycle, ranging from 40 Mt in 2015 to 70 Mt CO2 in later decades (more than 50% emission reduction). Waste quantities will be reduced simultaneously. The CO2 tax results in an 18% reduction of plastic waste weight in 2015 (3 Mt waste). Lower tax levels that may be politically more acceptable would result in proportionally lower environmental benefits. CO2 benefits and waste benefits of a CO2 tax are of equal importance in policy terms. Apart from changes in waste volume, CO2 taxes would affect the cost-effectiveness of waste handling technologies. Energy recovery in industrial kilns may replace conventional waste incineration. Recycling constitutes half of the total waste treatment. Given these results, current investments in new incineration capacity may suffer from insufficient waste availability during the next two decades in case CO2 taxes are introduced. A third effect of a CO2 tax is a significant increase of waste transportation. The results show that this increase is concentrated in the central part of Honshu (Kinki, Chubu & Kanto). Such transportation can result in new local environmental impacts that should be analysed in more detail. Given the strong impact of CO2 taxes on waste quantities and waste treatment it is recommended to co-ordinate CO2 policies and solid waste policies. PMID:12020092

  14. Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species

    SciTech Connect

    Nassar, Ray; Jones, DBA; Suntharalingam, P; Chen, j.; Andres, Robert Joseph; Wecht, K. J.; Yantosca, R. M.; Kulawik, SS; Bowman, K; Worden, JR; Machida, T; Matsueda, H

    2010-01-01

    The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure

  15. Multispecies transmitter for DIAL sensing of atmospheric water vapour, methane and carbon dioxide in the 2 μm region

    NASA Astrophysics Data System (ADS)

    Mammez, Dominique; Cadiou, Erwan; Dherbecourt, Jean-Baptiste; Raybaut, Myriam; Melkonian, Jean-Michel; Godard, Antoine; Gorju, Guillaume; Pelon, Jacques; Lefebvre, Michel

    2015-10-01

    Integrated-path differential absorption lidar (IPDIAL) is an attractive technique to monitor greenhouse gases from space. For that purpose, suitable absorption lines have been identified as good candidates around 2.05 μm for CO2, 2.29 μm for CH4, and 2.06 μm for H2O. In this context, we have developed a high energy transmitter around 2 μm based on frequency conversion in a nested cavity doubly resonant optical parametric oscillator (NesCOPO) followed by high energy parametric amplification. This master oscillator power amplifier (MOPA) architecture enables the generation of tunable single-frequency high energy nanosecond pulses (tens of mJ) suitable for atmospheric DIAL applications. Moreover, taking advantage of the wide spectral coverage capability of the NesCOPO, we demonstrate the potential for this single emitter to address the aforementioned spectral lines, without the use of additional seeding devices. The emitter provides energies up to 20 mJ for the signal waves in the vicinity of CO2 and H2O lines, and 16 mJ at 2290 nm for the CH4 line. By implementing a control loop based on a wavemeter frequency measurement, the signal fluctuations can be maintained below 1 MHz rms for 10 s averaging time. Finally, from optical heterodyne analysis of the beat note between our emitter and a stabilized laser diode, the optical parametric source linewidth was estimated to be better than 60 MHz (Full width at half maximum).

  16. Improved speckle statistics in coherent differential absorption lidar with in-fiber wavelength multiplexing.

    PubMed

    Ridley, K D; Pearson, G N; Harris, M

    2001-04-20

    Remote detection of gaseous pollutants and other atmospheric constituents can be achieved with differential absorption lidar (DIAL) methods. The technique relies on the transmission of two or more laser wavelengths and exploits absorption features in the target gas by measuring the ratio of their detected powers to determine gas concentration. A common mode of operation is when the transmitter and receiver are collocated, and the absorption is measured over a return trip by a randomly scattering topographic target. Hence, in coherent DIAL, speckle fluctuation leads to a large uncertainty in the detected powers unless the signal is averaged over multiple correlation times, i.e., over many independent speckles. We examine a continuous-wave coherent DIAL