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Sample records for combustion byproducts technical

  1. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  2. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  3. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  4. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F

  5. Minimization of combustion by-products: Characteristics of hazardous waste

    SciTech Connect

    Lee, C.C.; Huffman, G.L.

    1990-11-01

    It has been well recognized that, although there are many potential solid waste treatment technologies, none are as universally applicable as incineration for the treatment of the many types of waste which are governed by the many different Federal laws and State regulations. However, incinerators may release trace amounts of unwanted combustion by-products, particularly if the incinerators are not well designed or properly operated. Control of emissions of combustion by-products (CBPs) is one of the major technical and sociological issues surrounding the implementation of incineration as a waste treatment alternative. Much of this is due to the lack of detailed knowledge about CBPs. The Clean Air Act Amendment is emphasizing the control of toxic air pollutants from all combustion sources; some of these pollutants are CBPs. CBPs include: (1) unburned principal organic hazardous constituents (POHCs); (2) products of incomplete combustion (PICs); (3) metals emissions; and (4) residuals/ashes. The Paper is a part of a series of writings on the subject of the CBP issue from EPA's Risk Reduction Engineering Laboratory in Cincinnati, Ohio. It specifically addresses the aspect of hazardous waste characteristics. The main objective of the series is to compare combustion by-products from all combustion sources including fossil fuel combustion and waste incineration, which hopefully will serve as an initial step in the eventual minimization of the release of CBPs to the environment.

  6. Coal combustion byproducts and environmental issues

    SciTech Connect

    Sajwan, K.S.; Twardowska, I.; Punshon, T.; Alva, A.K.

    2006-07-01

    The book addresses the major implications and critical issues surrounding coal combustion products and their impact upon the environment. It provides essential information for scientists conducting research on coal and coal combustion products, but also serves as a valuable reference for a wide variety of researchers and other professionals in the energy industry and in the fields of public health, engineering, and environmental sciences.

  7. Minimization of combustion by-products: Toxic metal emissions

    SciTech Connect

    Lee, C.C.; Huffman, G.L.

    1991-12-01

    Incinerators may release trace amounts of unwanted combustion by-products (CBPs), particularly if the incinerators are not well designed or properly operated. The Clean Air Act Amendment is emphasizing the control of toxic air pollutants from all combustion and process sources; some of these pollutants are CBPs. CBPs include: (1) unburned principal organic hazardous constituents (POHCs); (2) products of incomplete combustion (PICs); (3) metal emissions; (4) residuals/ashes; and (5) acid gases. This Paper is a part of a series of writings on the subject of the CBP issue from EPA's Risk Reduction Engineering Laboratory in Cincinnati, Ohio and is one of the first metal emission papers in the series. It specifically addresses the aspect of potential toxic metal emissions from combustion/incineration processes.

  8. Toxic combustion by-products: Generation, separation, cleansing, containment

    SciTech Connect

    Kephart, W.; Eger, K.; Angelo, F.; Clemens, M.K.

    1995-12-31

    Focus of this paper is on diagnosis, control, and containment of potentially toxic combustion byproducts when mixed wastes are treated at elevated temperatures. Such byproducts fall into several categories: acid gases, particulates, metals, organics. Radionuclides are treated as a subset of metals, while organics are divided into two subclasses: products of incomplete combustion, and principal organic hazardous constituents. An extended flue gas cleaning system is described which can be used to contain potentially toxic organic emissions and recycle the hazrdous materials for further treatment; it uses oxygen rather than air to reduce total quantities of emissions, improve efficiency of oxidation, and minimize NOx emissions. Flue gas recycling is used for cooling and for containing all potentially toxic emissions. Three thermal treatment unit operations are used in series for more effective process control; three emission separation and containment unit operations are also used in series in the toxic emission containment system. Real time diagnostic hardware/software are used. Provision is made for automatic storage, separation of hazardous materials, commodity regeneration, and recycling of potentially harmful constituents. The greenhouse gas CO2 is recovered and not emitted to the atmosphere.

  9. UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS

    SciTech Connect

    J.Y. Hwang; X. Huang; M.G. McKimpson; R.E. Tieder; A.M. Hein; J.M. Gillis; D.C. Popko; K.L. Paxton; Z. Li; X. Liu; X. Song; R.I. Kramer

    1998-12-01

    Low NO{sub x} combustion practices are critical for reducing NO{sub x} emissions from power plants. These low NO{sub x} combustion practices, however, generate high residual carbon contents in the fly ash produced. These high carbon contents threaten utilization of this combustion by-product. This research has successfully developed a separation technology to render fly ash into useful, quality-controlled materials. This technology offers great flexibility and has been shown to be applicable to all of the fly ashes tested (more than 10). The separated materials can be utilized in traditional fly ash applications, such as cement and concrete, as well as in nontraditional applications such as plastic fillers, metal matrix composites, refractories, and carbon adsorbents. Technologies to use beneficiated fly ash in these applications are being successfully developed. In the future, we will continue to refine the separation and utilization technologies to expand the utilization of fly ash. The disposal of more than 31 million tons of fly ash per year is an important environmental issue. With continued development, it will be possible to increase economic, energy and environmental benefits by re-directing more of this fly ash into useful materials.

  10. Sandia Combustion Research: Technical review

    SciTech Connect

    1995-07-01

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  11. Synthesis of zeolite phases from combustion by-products.

    PubMed

    Pimraksa, Kedsarin; Chindaprasirt, Prinya; Setthaya, Naruemon

    2010-12-01

    Synthesis of zeolites from combustion by-products, including fly ash, bottom ash and rice husk ash, was studied. A molar ratio of SiO2/Al2O3 of 1.5 was used for the syntheses. Refluxing and hydrothermal methods were also used for synthesis for comparison. The reaction temperatures of refluxing and hydrothermal methods were 100 degrees C and 130 degrees C, respectively. Sodalite, phillipsite-K, and zeolite P1 with analcime were obtained when fly ash, bottom ash and rice husk ash were used as starting materials, respectively. With rice husk ash as a starting material, zeolite P1 was produced. This result had advantages over previous studies as there was no prior activation required for the synthesis. The concentrations and types of alkaline used in the synthesis also determined the zeolite type. The different zeolites obtained from three systems were measured for specific surface area and pore size by using BET and Hg-porosimetry, respectively. Ammonium exchange capacities of the synthesised powders containing zeolites, sodalite, zeolite P1 and phillipsite-K were 38.5, 65.0 and 154.7 meq 100 g(-1), respectively.

  12. Aerovalve pulse combustion: Technical note

    SciTech Connect

    Richards, G.A.; Gemmen, R.S.; Narayanaswami, L.

    1994-07-01

    The authors present a mathematical model and an experimental investigation of aerodynamically valved pulse combustion. The model uses a control-volume approach to solve conservation laws in several regions of a pulse combustor. Mixing between the fresh charge and combustion products is modeled as a two-step process, with the mixing occurring slowly for a specified eddy time during each cycle, and then changing to a higher rate. Results of model simulations demonstrate that eddy time plays a significant role in determining the frequency and amplitude of combustion oscillation. The authors show that short eddy times produce steady, rather than pulsating, combustion. And they show that changes to the mixing process alter the temperature-species history of combustion gases in a manner that could prevent or promote the formation of nitrogen oxides, depending on specific mixing rates. The relatively simple control-volume approach used in this model allows rapid investigation of a wide range of geometric and operating parameters, and also defines characteristic length and time scales relevant to aerovalve pulse combustion. Experimental measurements compare favorably to model predictions. The authors place particular emphasis on time-averaged pressure differences through the combustor, which act as an indicator of pressure gain performance. They investigate both operating conditions and combustor geometry, and they show that a complex interaction between the inlet and exit flows of a combustor makes it difficult to produce general correlations among the various parameters. They use a scaling rule to produce a combustor geometry capable of producing pressure gain.

  13. DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect

    Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

    2003-09-30

    The increasing role of coal as a source of energy in the 21st century will demand environmental and cost-effective strategies for the use of coal combustion by-products (CCBPs), mainly unburned carbon in fly ash. Unburned carbon is nowadays regarded as a waste product and its fate is mainly disposal, due to the present lack of efficient routes for its utilization. However, unburned carbon is a potential precursor for the production of adsorbent carbons, since it has gone through a devolatilization process while in the combustor, and therefore, only requires to be activated. Accordingly, the principal objective of this work was to characterize and utilize the unburned carbon in fly ash for the production of activated carbons. The unburned carbon samples were collected from different combustion systems, including pulverized utility boilers, a utility cyclone, a stoker, and a fluidized bed combustor. LOI (loss-on-ignition), proximate, ultimate, and petrographic analyses were conducted, and the surface areas of the samples were characterized by N2 adsorption isotherms at 77K. The LOIs of the unburned carbon samples varied between 21.79-84.52%. The proximate analyses showed that all the samples had very low moisture contents (0.17 to 3.39 wt %), while the volatile matter contents varied between 0.45 to 24.82 wt%. The elemental analyses show that all the unburned carbon samples consist mainly of carbon with very little hydrogen, nitrogen, sulfur and oxygen In addition, the potential use of unburned carbon as precursor for activated carbon (AC) was investigated. Activated carbons with specific surface area up to 1075m{sup 2}/g were produced from the unburned carbon. The porosity of the resultant activated carbons was related to the properties of the unburned carbon feedstock and the activation conditions used. It was found that not all the unburned carbon samples are equally suited for activation, and furthermore, their potential as activated carbons precursors could be

  14. The origin, fate, and health effects of combustion by-products: a research framework.

    PubMed Central

    Avakian, Maureen D; Dellinger, Barry; Fiedler, Heidelore; Gullet, Brian; Koshland, Catherine; Marklund, Stellan; Oberdörster, Günter; Safe, Stephen; Sarofim, Adel; Smith, Kirk R; Schwartz, David; Suk, William A

    2002-01-01

    Incomplete combustion processes can emit organic pollutants, metals, and fine particles. Combustion by-products represent global human and environmental health challenges that are relevant not only in heavily industrialized nations, but also in developing nations where up to 90% of rural households rely on unprocessed biomass fuels for cooking, warmth, and light. These issues were addressed at the Seventh International Congress on Combustion By-Products, which convened 4-6 June 2001 in Research Triangle Park, North Carolina. This congress included a diverse group of multidisciplinary researchers and practitioners who discussed recent developments and future goals in the control of combustion by-products and their effects of exposure on human and ecologic health. Participants recommended that interdisciplinary, coordinated research efforts should be focused to capitalize on the important potential synergisms between efforts to reduce the adverse human health effects linked to exposures to combustion by-products and broader efforts to reduce greenhouse gas emissions and save energy through efficiency. In this article we summarize the principal findings and recommendations for research focus and direction. PMID:12417488

  15. THE USE OF A PRB TO TREAT GROUNDWATER IMPACTED BY COAL-COMBUSTION BY-PRODUCTS

    EPA Science Inventory

    The burning of coal for the production of electricity generates combustion by-products such as boiler bottom ash and fly ash. These ashes have the potential to release arsenic (As), boron (B), chromium (Cr), molybdenum (Mo), selenium (Se), vanadium (V), and zinc (Zn) to the envi...

  16. Land application of coal combustion by-products: Use in agriculture and land reclamation. Final report

    SciTech Connect

    Horn, M.E.

    1995-06-01

    Land application of coal combustion by-products (CCBP) can prove beneficial for a number of reasons. The data presented in this survey provide a basis for optimizing the rates and timing of CCBP applications, selecting proper target soils and crops, and minimizing adverse effects on soil properties, plant responses, and groundwater quality.

  17. Assessment of combustion of oil shale refinery by-products in a TP-101 boiler

    NASA Astrophysics Data System (ADS)

    Sidorkin, V. T.; Tugov, A. N.; Vereshchetin, V. A.; Mel'nikov, D. A.

    2015-04-01

    The most cost-efficient method for utilization of the oil shale refinery by-products, viz., the retort gas and the shale gasoline, for power generation is combustion of these products in power-generating oil shale-fired boilers. Calculation studies carried out at the Estonian electric power plant in Narva, an enterprise of EESTI ENERGIA, have shown that recycling of the flue gases in the furnace of a TP-101 boiler enables an increase in the portion of the oil shale refinery by-products burned in the boiler from the current 7% to 40%. Recycling of the flue gases is aimed at maintaining the temperatures in the furnace at a level characteristic of combustion of oil shale and reducing the nitric oxide concentration in the retort gas burners' flame. The degree of the flue gas recycling depends on the percentage of the burnt oil shale refinery by-products in the total heat generation and increases with the increasing percentage. For the threshold value of 40% under the rated conditions, the flue gas recycling accounts for 10%. A complete changeover of the boiler to combustion of only the retort gas in place of the oil shale does not seem to be possible, since this will necessitate major modification to the TP-101 boiler heating surfaces. Considering the obtained results, as a pilot project, one boiler furnace was modified by installing six retort gas burners and a flue gas recycling system.

  18. Advanced Combustion and Emission Control Technical Team Roadmap

    SciTech Connect

    2013-06-01

    The Advanced Combustion and Emission Control (ACEC) Technical Team is focused on removing technical barriers to the commercialization of advanced, high-efficiency, emission-compliant internal combustion (IC) engines for light-duty vehicle powertrains (i.e., passenger car, minivan, SUV, and pickup trucks).

  19. Use of coal combustion byproducts in biosolids stabilization: The N-Viro process

    SciTech Connect

    Logan, T.J.

    1999-07-01

    The patented N-Viro process for alkaline stabilization of municipal sewage sludge (biosolids) is a 10-year old technology that utilizes a variety of alkaline byproducts. These include cement kiln dust, lime kiln dust, flue gas desulfurization (FGD) byproducts, fluidized-bed coal combustion ashes, and Class C and F fly ashes. The alkaline byproducts are used in the N-Viro process to raise pH ({gt}12), produce heat (52--62 C) and increase solids content of the biosolids (50--65% solids). Typical operations use a blend of reactive (produces heat) and non-reactive byproducts in the process, with selection of materials being driven by local availability and cost. There are 38 N-Viro facilities in the US, Canada, Australia, the UK, and Belgium, with the majority in the eastern US. Of these, 15 use coal combustion byproducts (CCBs) on a regular basis. These facilities process more than 250,000 dry tons of biosolids a year, utilize about 125,000 tons of CCBs annually, and produce more than 1,000,000 tons of the resulting product, N-Viro Soil, per year. The use of CCBs is expected to increase dramatically in the next few years. N-Viro Soil, regulated by US EPA as an EQ biosolids, is marketed and distributed as agricultural lime, fertilizer, and as a soil substitute for reclamation and horticulture. This paper discusses the properties of alkaline materials that are required in the N-Viro process, compares those properties to that of various CCBs, and discusses the potential benefit to coal-burning power plants of recycling CCBs to beneficial uses rather than disposal.

  20. Report: Combustion Byproducts and Their Health Effects: Summary of the 10th International Congress

    PubMed Central

    Dellinger, Barry; D'Alessio, Antonio; D'Anna, Andrea; Ciajolo, Anna; Gullett, Brian; Henry, Heather; Keener, Mel; Lighty, JoAnn; Lomnicki, Slawomir; Lucas, Donald; Oberdörster, Günter; Pitea, Demetrio; Suk, William; Sarofim, Adel; Smith, Kirk R.; Stoeger, Tobias; Tolbert, Paige; Wyzga, Ron; Zimmermann, Ralf

    2008-01-01

    Abstract The 10th International Congress on Combustion Byproducts and their Health Effects was held in Ischia, Italy, from June 17–20, 2007. It is sponsored by the US NIEHS, NSF, Coalition for Responsible Waste Incineration (CRWI), and Electric Power Research Institute (EPRI). The congress focused on: the origin, characterization, and health impacts of combustion-generated fine and ultrafine particles; emissions of mercury and dioxins, and the development/application of novel analytical/diagnostic tools. The consensus of the discussion was that particle-associated organics, metals, and persistent free radicals (PFRs) produced by combustion sources are the likely source of the observed health impacts of airborne PM rather than simple physical irritation of the particles. Ultrafine particle-induced oxidative stress is a likely progenitor of the observed health impacts, but important biological and chemical details and possible catalytic cycles remain unresolved. Other key conclusions were: (1) In urban settings, 70% of airborne fine particles are a result of combustion emissions and 50% are due to primary emissions from combustion sources, (2) In addition to soot, combustion produces one, possibly two, classes of nanoparticles with mean diameters of ~10 nm and ~1 nm. (3) The most common metrics used to describe particle toxicity, viz. surface area, sulfate concentration, total carbon, and organic carbon, cannot fully explain observed health impacts, (4) Metals contained in combustion-generated ultrafine and fine particles mediate formation of toxic air pollutants such as PCDD/F and PFRs. (5) The combination of metal-containing nanoparticles, organic carbon compounds, and PFRs can lead to a cycle generating oxidative stress in exposed organisms. PMID:22476005

  1. Electricity from coal and utilization of coal combustion by-products

    SciTech Connect

    Demirbas, A.

    2008-07-01

    Most electricity in the world is conventionally generated using coal, oil, natural gas, nuclear energy, or hydropower. Due to environmental concerns, there is a growing interest in alternative energy sources for heat and electricity production. The major by-products obtained from coal combustion are fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) materials. The solid wastes produced in coal-fired power plants create problems for both power-generating industries and environmentalists. The coal fly ash and bottom ash samples may be used as cementitious materials.

  2. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-07-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, and a discussion of these is not repeated here. Rather, this report discusses the technical progress made during the period April 1 - June 30, 1995. A final topical report on the SEEC, Inc. demonstration of its technology for the transporting of coal combustion residues was completed during the quarter, although final printing of the report was accomplished early in July, 1995. The SEEC technology involves the use of Collapsible Intermodal Containers (CIC`s) developed by SEEC, and the transportation of such containers - filled with fly ash or other coal combustion residues - on rail coal cars or other transportation means. Copies of the final topical report, entitled {open_quotes}The Development and Testing of Collapsible Intermodal Containers for the Handling and Transport of Coal Combustion Residues{close_quotes} were furnished to the Morgantown Energy Technology Center. The Rapid Aging Test colums were placed in operation during the quarter. This test is to determine the long-term reaction of both the pneumatic and hydraulic mixtures to brine as a leaching material, and simulates the conditions that will be encountered in the actual underground placement of the coal combustion residues mixtures. The tests will continue for about one year.

  3. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect

    J.A. Withum; J.E. Locke; S.C. Tseng

    2005-03-01

    There is concern that mercury (Hg) in coal combustion by-products might be emitted into the environment during processing to other products or after the disposal/landfill of these by-products. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications and may result in additional, costly disposal regulations. In this program, CONSOL conducted a comprehensive sampling and analytical program to include ash, flue gas desulfurization (FGD) sludge, and coal combustion by-products. This work is necessary to help identify potential problems and solutions important to energy production from fossil fuels. The program objective was to evaluate the potential for mercury emissions by leaching or volatilization, to determine if mercury enters the water surrounding an active FGD disposal site and an active fly ash slurry impoundment site, and to provide data that will allow a scientific assessment of the issue. Toxicity Characteristic Leaching Procedure (TCLP) test results showed that mercury did not leach from coal, bottom ash, fly ash, spray dryer/fabric filter ash or forced oxidation gypsum (FOG) in amounts leading to concentrations greater than the detection limit of the TCLP method (1.0 ng/mL). Mercury was detected at very low concentrations in acidic leachates from all of the fixated and more than half of the unfixated FGD sludge samples, and one of the synthetic aggregate samples. Mercury was not detected in leachates from any sample when deionized water (DI water) was the leaching solution. Mercury did not leach from electrostatic precipitator (ESP) fly ash samples collected during activated carbon injection for mercury control in amounts greater than the detection limit of the TCLP method (1.0 ng/mL). Volatilization tests could not detect mercury loss from fly ash, spray dryer/fabric filter ash, unfixated FGD sludge, or forced oxidation gypsum; the mercury concentration of these samples all increased, possibly due to

  4. Technical Report: Rayleigh Scattering Combustion Diagnostic

    SciTech Connect

    Adams, Wyatt; Hecht, Ethan

    2015-07-29

    A laser Rayleigh scattering (LRS) temperature diagnostic was developed over 8 weeks with the goal of studying oxy-combustion of pulverized coal char in high temperature reaction environments with high concentrations of carbon dioxide. Algorithms were developed to analyze data collected from the optical diagnostic system and convert the information to temperature measurements. When completed, the diagnostic will allow for the kinetic gasification rates of the oxy-combustion reaction to be obtained, which was previously not possible since the high concentrations of high temperature CO2 consumed thermocouples that were used to measure flame temperatures inside the flow reactor where the combustion and gasification reactions occur. These kinetic rates are important for studying oxycombustion processes suitable for application as sustainable energy solutions.

  5. DETERMINING BACKGROUND EXPOSURE TO PETROLEUM AND COMBUSTION BY-PRODUCTS: COMPARISON OF MID-WESTERN AND MID-ATLANTIC REGIONS

    EPA Science Inventory

    Regional background levels of exposure to fish from petroleum and combustion by-products were determined for the state of Ohio and the mid-Atlantic region. Exposures were measured using bile metabolites that fluoresce at 290/335 nm for naphthalene(NAPH)-type compounds and at 380...

  6. COMPARISON OF MID-WESTERN AND MID-ATLANTIC REGIONS EXPOSURE CRITERIA FOR PETROLEUM AND COMBUSTION BY-PRODUCTS

    EPA Science Inventory

    Regional background levels of exposure to fish from petroleum and combustion by-products were determined for the state of Ohio (mid-Western) and the mid-Atlantic region. Exposures were measured using bile metabolites that fluoresce at 290/335 nm for naphthalene (NAPH)-type compou...

  7. PILOT-SCALE STUDIES ON THE EFFECT OF BROMINE ADDITION ON THE EMISSIONS OF CHLORINATED ORGANIC COMBUSTION BY-PRODUCTS

    EPA Science Inventory

    The paper reports on a study to evaluate organic combustion by-product emissions while feeding varying amounts of bromine (Br) and chlorine (Cl) into a pilot-scale incinerator burning surrogate waste materials. (NOTE: Adding brominated organic compounds to a pilot-scale incinerat...

  8. Coal slurry solids/coal fluidized bed combustion by-product mixtures as plant growth media

    USGS Publications Warehouse

    Darmody, R.G.; Green, W.P.; Dreher, G.B.

    1998-01-01

    Fine-textured, pyritic waste produced by coal cleaning is stored in slurry settling ponds that eventually require reclamation. Conventionally, reclamation involves covering the dewatered coal slurry solids (CSS) with 1.3 m of soil to allow plant growth and prevent acid generation by pyrite oxidation. This study was conducted to determine the feasiblity of a less costly reclamation approach that would eliminate the soil cover and allow direct seeding of plants into amended CSS materials. Potential acidity of the CSS would be neutralized by additions of fluidized-bed combustion by-product (FBCB), an alkaline by-product of coal combustion. The experiment involved two sources of CSS and FBCB materials from Illinois. Birdsfoot trefoil (Lotus corniculatus L.), tall fescue (Festuca arundinacea Schreb.), and sweet clover (Melilotus officinalis (L.) Lam.) were seeded in the greenhouse into pots containing mixtures of the materials. CSS-1 had a high CaCO3:FeS2 ratio and needed no FBCB added to compensate for its potential acidity. CSS-2 was mixed with the FBCB materials to neutralize potential acidity (labeled Mix A and B). Initial pH was 5.6, 8.8, and 9.2 for the CSS-1, Mix A, and Mix B materials, respectively. At the end of the 70-day experiment, pH was 5.9 for all mixtures. Tall fescue and sweet clover grew well in all the treatments, but birdsfoot trefoil had poor emergence and survival. Elevated tissue levels of B, Cd, and Se were found in some plants. Salinity, low moisture holding capacity, and potentially phytotoxic B may limit the efficacy of this reclamation method.

  9. Landslide remediation on Ohio State Route 83 using clean coal combustion by-products

    SciTech Connect

    Payette, R.; Chen, X.Y.; Wolfe, W.; Beeghly, J.

    1995-12-31

    In the present work, a flue gas desulfurization (FGD) by-product was used to reconstruct the failed portion of a highway embankment. The construction process and the stability of the repaired embankment are examined. State Route 83 in Cumberland, Ohio has been damaged by a slow moving slide which has forced the Ohio Department of Transportation to repair the roadway several times. In the most recent repair FGD by-products obtained from American Electric Power`s Tidd PFBC plant were used to construct a wall through the failure plane to prevent further slippage. In order to evaluate the utility of using coal combustion by-products in this type of highway project the site was divided into three test sections. In the first repair section, natural soil removed form the slide area was recompacted and replaced according to standard ODOT construction practices. In the second section the natural soil was field mixed with the Tidd PFBC ash in approximately equal proportions. The third section was all Tidd ash. The three test sections were capped by a layer of compacted Tidd ash or crushed stone to provide a wearing surface to allow ODOT to open the roadway before applying a permanent asphalt surface. Measurement of slope movement as well as water levels and quality have begun at the site in order to evaluate long term project performance. The completion of this project should lead to increased acceptance of FGD materials in construction projects. Monetary savings will be realized in avoiding some of the disposal costs for the waste, as well as in the reduced reliance on alternative engineering materials.

  10. Use of coal combustion by-products for solidification/stabilization of hazardous wastes

    SciTech Connect

    Hassett, D.J.; Pflughoeft-Hassett, D.F.

    1997-05-01

    Five low-rank coal combustion fly ash samples extensively characterized in previous projects were used as a pool of candidate materials for potential use as waste stabilization agents. Two of these fly ash samples were selected because ettringite formed in the solid in long-term leaching experiments, and an associated reduction in leachate concentration of at least one trace element was noted for each sample. The stabilization experiments were designed to evaluate the removal of relatively high concentrations of boron and selenium from a simulated wastewater. Sulfate was added as one variable in order to determine if high concentrations of sulfate would impact the ability of the ettringite to include trace elements in its structure. The following conclusions can be drawn from the information obtained in this research: CCBs (coal combustion by-products) can be useful in the chemical fixation of potentially hazardous trace elements; indication of ettringite formation alone is not adequate for selecting a CCB for waste stabilization applications; moderate sulfate concentrations do not promote or inhibit trace element sorption; ettringite formation mechanisms may impact trace element fixation and need to be elucidated; laboratory demonstration of the CCB with the stabilization process being proposed is necessary to verify the efficacy of the material and process; and the final waste form must be evaluated prior to management according to the required regulatory procedures.

  11. Solid by-products of coal combustion: Fly ash as a source of industrial minerals

    SciTech Connect

    Bhagwat, S.B.; Rapp, D.M.; Bukowski, J.M.

    1996-12-31

    Fly ash is one of the most important by-products of coal combustion. It is a complex mix of cenospheres, reactive glasses, magnetite and carbon, in addition to minor quantities of other minerals. Fly ash components are determined by the type of coal, the combustion technology, material collection system and the temperature of combustion. The changing mix of coal burned in power plants is increasingly making the fly ash characteristics independent of the locally mined coal. Fly ash is thus becoming a raw material independent of the existence of a local coal mining industry. Currently, about 65 million tons of fly ash are generated annually in the United States. This is equivalent to the crushed stone production of such highly industrialized states as Illinois. Only about twenty percent of the total fly ash are currently used, mostly in low value applications such as road building materials and concrete additions. The fly ash currently represents an environmental and financial liability to electric utilities. The increasingly competitive and boundaryless electricity market in the US increases the incentive to look at fly ash in terms of its individual components and recognize their potential as industrial minerals in the production of value added materials. For example, zeolites and other adsorbents could be produced from reactive glasses, magnetite could be used in pigments and ferrite manufacture, activated carbon could serve in pollution control and cenospheres could be used to make lightweight ceramics. If one begins to look at fly ash as a source of industrial minerals and not as a waste product, this change in perspective could turn a financial and environmental liability into an economic opportunity.

  12. Combustion By-Products and their Health Effects - Combustion Engineering and Global Health in the 21st Century: Issues and Challenges

    PubMed Central

    Lomnicki, Slawo; Gullett, Brian; Stöger, Tobias; Kennedy, Ian; Diaz, Jim; Dugas, Tammy R.; Varner, Kurt; Carlin, Danielle; Dellinger, Barry; Cormier, Stephania A.

    2014-01-01

    The 13th International Congress on Combustion By-Products and their Health Effects was held in New Orleans, Louisiana from May 15–18, 2013. The congress, sponsored by the Superfund Research Program, National Institute of Environmental Health Sciences, and National Science Foundation, brought together international academic and government researchers, engineers, scientists and policymakers. With industrial growth, increased power needs and generation and coal consumption and their concomitant emissions, pernicious health effects associated with exposures to these emissions are on the rise. This congress provides a unique platform for interdisciplinary exchange and discussion of these topics. The formation, conversion, control and health effects of combustion by-products, including particulate matter and associated heavy metals, persistent organic pollutants and environmentally persistent free radicals, were discussed during the congress. This review will summarize and discuss the implications of the data presented. PMID:24434722

  13. Structural and thermal behavior of coal combustion and gasification by-products

    SciTech Connect

    Valimbe, P.S.; Malhotra, V.M.; Banerjee, D.

    1995-12-31

    We have initiated studies which attempt to convert coal combustion and coal gasification by-products into high-value composite materials. However, before conversion strategies can be put in place, the raw materials must be characterized. Therefore, we undertook systematic microscopy and spectroscopy measurements on PCC fly ash, FBC fly ash, FBC spent bed ash, and scrubber sludge. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure does not exactly match either conventional gypsum or hannebachite. SEM images indicate that unlike PCC fly ash particles, which are mainly spherical, the FBC fly ash and FBC spent bed ash particles are irregularly shaped and show considerable fusion. FBC fly ashes are mainly composed of anhydrite, lime, portlandite, calcite, hematite, magnetite and various glass phases. The DTA and DSC data suggest that the PCC fly ash is thermally stable up to 1100{degrees}C. However, this is not the case for FBC residue.

  14. Effects of water treatment residuals and coal combustion byproduct amendments on properties of a sandy soil and impact on crop production – A pot experiment

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Byproducts of coal combustion (such as fly ash: FA), livestock industry (such as chicken manure: CM, or animal manure, etc), or water treatment residuals (such as sewage sludge: SS, or incinerated sewage sludge: ISS) can be used as amendments to agricultural soils, provided that these byproducts (ap...

  15. Evaluation of a sequential extraction process used for determining mercury binding mechanisms to coal combustion byproducts.

    PubMed

    Noel, James D; Biswas, Pratim; Giammar, Daniel E

    2007-07-01

    Leaching of mercury from coal combustion byproducts is a concern because of the toxicity of mercury. Leachability of mercury can be assessed by using sequential extraction procedures. Sequential extraction procedures are commonly used to determine the speciation and mobility of trace metals in solid samples and are designed to differentiate among metals bound by different mechanisms and to different solid phases. This study evaluated the selectivity and effectiveness of a sequential extraction process used to determine mercury binding mechanisms to various materials. A six-step sequential extraction process was applied to laboratory-synthesized materials with known mercury concentrations and binding mechanisms. These materials were calcite, hematite, goethite, and titanium dioxide. Fly ash from a full-scale power plant was also investigated. The concentrations of mercury were measured using inductively coupled plasma (ICP) mass spectrometry, whereas the major elements were measured by ICP atomic emission spectrometry. The materials were characterized by X-ray powder diffraction and scanning electron microscopy with energy dispersive spectroscopy. The sequential extraction procedure provided information about the solid phases with which mercury was associated in the solid sample. The procedure effectively extracted mercury from the target phases. The procedure was generally selective in extracting mercury. However, some steps in the procedure extracted mercury from nontarget phases, and others resulted in mercury redistribution. Iron from hematite and goethite was only leached in the reducible and residual extraction steps. Some mercury associated with goethite was extracted in the ion exchangeable step, whereas mercury associated with hematite was extracted almost entirely in the residual step. Calcium in calcite and mercury associated with calcite were primarily removed in the acid-soluble extraction step. Titanium in titanium dioxide and mercury adsorbed onto

  16. Environmental impact of a coal combustion-desulphurisation plant: abatement capacity of desulphurisation process and environmental characterisation of combustion by-products.

    PubMed

    Alvarez-Ayuso, E; Querol, X; Tomás, A

    2006-12-01

    The fate of trace elements in a combustion power plant equipped with a wet limestone flue gas desulphurisation (FGD) installation was studied in order to evaluate its emission abatement capacity. With this aim representative samples of feed coal, boiler slag, fly ash, limestone, FGD gypsum and FGD process water and wastewater were analysed for major and trace elements using the following techniques: inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-atomic emission spectrometry (ICP-AES), ion chromatography (IC), ion selective electrode (ISE) and atomic absorption spectroscopy (AAS). Mass balances were established allowing to determine the element partitioning behaviour. It was found that, together with S, Hg, Cl, F, Se and As were those elements entering in the FGD plant primarily as gaseous species. The abatement capacity of the FGD plant for such elements offered values ranged from 96% to 100% for As, Cl, F, S and Se, and about 60% for Hg. The environmental characterisation of combustion by-products (boiler slag, fly ash and FGD gypsum) were also established according to the Council Decision 2003/33/EC on waste disposal. To this end, water leaching tests (EN-12457-4) were performed, analysing the elements with environmental concern by means of the aforementioned techniques. According to the leaching behaviour of combustion by-products studied, these could be disposed of in landfills for non-hazardous wastes.

  17. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    SciTech Connect

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31

    The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being

  18. Landslide remediation on Ohio State Route 83 using clean coal combustion by-products

    SciTech Connect

    Payette, R.; Chen, Xi You; Wolfe, W.; Beeghly, J.

    1995-12-31

    The disposal of flue gas desulfurization (FGD) by-products has become a major concern as issues of emission cleansing and landfill costs continue to rise. Laboratory tests conducted at the Ohio State University have shown that dry FGD by-products possess certain engineering properties that have proven desirable in a number of construction uses. As a follow on to the laboratory program, a field investigation into engineering uses of dry FGD wastes was initiated. In the present work, an FGD by-product was used to reconstruct the failed portion of a highway embankment. The construction process and the stability of the repaired embankment are examined.

  19. Technical evaluation: pressurized fluidized-bed combustion technology

    SciTech Connect

    Miller, S A; Vogel, G J; Gehl, S M; Hanway, Jr, J E; Henry, R F; Parker, K M; Smyk, E B; Swift, W M; Podolski, W F

    1982-04-01

    The technology of pressurized fluidized-bed combustion, particularly in its application to a coal-burning combined-cycle plant, is evaluated by examining the technical status of advanced-concept plant components - boiler system (combustor, air-handling and air-injection equipment, and heat exchangers); solids handling, injection, and ejection system; hot-gas cleanup equipment; instrumentation/control system; and the gas turbine - along with materials of plant construction. Environmental performance as well as energy efficiency are examined, and economic considerations are reviewed briefly. The evaluation concludes with a broad survey of the principal related research and development programs in the United States and other countries, a foreview of the most likely technological developments, and a summary of unresolved technical issues and problems.

  20. U.S. Department of Energy projects involving the use of coal combustion by-products in mining applications

    SciTech Connect

    Aljoe, W.W.; Renninger, S.

    1999-07-01

    The onset of utility deregulation now makes it apparent that coal combustion by-product (CCB) utilization is one key area that may help utilities better manage their available resources. Because current utilization rates of CCB's are relatively low, the US Department of Energy is actively co-sponsoring a variety of CCB utilization projects, along with projects that seek to characterize the by-products resulting from newly-developed technologies for coal combustion, gasification, or flue gas cleanup. Mining applications represent a potential high-volume market for CCB's, with beneficial uses that include the prevention or control of acid mine drainage, surface subsidence over underground mines, and reclamation of acidic surface mine spoils. Future applications may include the development of CCB-based construction materials for use in mining and the selective backfilling of CCB's to increase underground coal mine extraction rates. The goal of these projects is to demonstrate that CCB's are of significant value when used in mining applications, and that CCB utilization in mines represents more than just a cheaper alternative to landfill disposal.

  1. Methanol production with elemental phosphorus byproduct gas: technical and economic feasibility

    SciTech Connect

    Lyke, S.E.; Moore, R.H.

    1981-01-01

    The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol production appears to be technically feasible. The Battelle Process shows a definite but relatively small economic advantage over conventional methanol manufacture based on natural gas alone. The process would be economically feasible only where natural gas supply and methanol market conditions at a phosphorus plant are not significantly less favorable than at competing methanol plants. If off-gas streams from two or more phosphorus plants could be combined, production of methanol using only offgas might also be economically feasible. The North American methanol market, however, does not seem likely to require another new methanol project until after 1990. The off-gas cleanup, compression, and phosphorus-recovery system could be used to produce a CO-rich stream that could be economically attractive for production of several other chemicals besides methanol.

  2. Water Quality and Geochemical Modeling of Water at an Abandoned Coal Mine Reclaimed With Coal Combustion By-Products

    USGS Publications Warehouse

    Haefner, Ralph J.

    2002-01-01

    An abandoned coal mine in eastern Ohio was reclaimed with 125 tons per acre of pressurized fluidized bed combustion (PFBC) by-product. Water quality at the site (known as the Fleming site) was monitored for 7 years after reclamation; samples included water from soil-suction lysimeters (interstitial water), wells, and spring sites established downgradient of the application area. This report presents a summary of data collected at the Fleming site during the period September 1994 through June 2001. Additionally, results of geochemical modeling are included in this report to evaluate the potential fate of elements derived from the PFBC by-product. Chemical analyses of samples of interstitial waters within the PFBC by-product application area indicated elevated levels of pH and specific conductance and elevated concentrations of boron, calcium, chloride, fluoride, magnesium, potassium, strontium, and sulfate compared to water samples collected in a control area where traditional reclamation methods were used. Magnesium-to-calcium (Mg:Ca) mole ratios and sulfur-isotope ratios were used to trace the PFBC by-product leachate and showed that little, if any, leachate reached ground water. Concentrations of most constituents in interstitial waters in the application-area decreased during the seven sampling rounds and approached background concentrations observed in the control area; however, median pH in the application area remained above 6, indicating that some acid-neutralizing capacity was still present. Although notable changes in water quality were observed in interstitial waters during the study period, quality of ground water and spring water remained poor. Water from the Fleming site was not potable, given exceedances of primary and secondary Maximum Contaminant Levels (MCLs) for inorganic constituents in drinking water set by the U.S. Environmental Protection Agency. Only fluoride and sulfate, which were found in higher concentrations in application

  3. Marketable products from gypsum, a coal combustion byproduct derived from a wet flue gas desulfurization process

    SciTech Connect

    Chou, M.I.M.; Ghiassi, K.; Lytle, J.M.; Chou, S.J.; Banerjee, D.D.

    1998-07-01

    For two years the authors have been developing a process to produce two marketable products, ammonium sulfate fertilizer and precipitated calcium carbonate (PCC), from wet limestone flue gas desulfurization (FGD) by-product gypsum. Phase 1 of the project focused on the process for converting FGD-gypsum to ammonium sulfate fertilizer with PCC produced as a by-product during the conversion. Early cost estimates suggested that the process was economically feasible when granular size ammonium sulfate crystals were produced. However, sale of the by-product PCC for high-value commercial application could further improve the economics of the process. The results of their evaluation of the market potential of the PCC by-product are reported in this paper. The most significant attributes of carbonate fillers that determine their usefulness in industry are particle size (i.e, fineness) and shape, whiteness (brightness), and mineralogical and chemical purity. The PCC produced from the FGD dypsum obtained from the Abbott Power Plant at the University of Illinois Urbana-Champaign campus are pure calcite with a CaCO{sub 3} content greater than 98%, 3% higher than the minimum requirement of 95%. However, the size, shape, and brightness of the PCC particles are suitable only for certain applications. Impurities in the gypsum from Abbott power plant influence the whiteness of the PCC products. Test results suggested that, to obtain gypsum that is pure enough to produce a high whiteness PCC for high value commercial applications, limestone with minimum color impurities should be used during the FGD process. Alternatively, purification procedures to obtain the desired whiteness of the FGD-gypsum can be used. Further improvement in the overall qualities of the PCC products should lead to a product that is adequate for high-value paper applications.

  4. Marketable products from gypsum, a coal combustion byproduct derived from a wet flue gas desulfurization process

    SciTech Connect

    Chou, M.I.M.; Ghiassi, K.; Lytle, J.M.; Chou, S.J.; Banerjee, D.D.

    1998-04-01

    For two years the authors have been developing a process to produce two marketable products, ammonium sulfate fertilizer and precipitated calcium carbonate (PCC), from wet limestone flue gas desulfurization (FGD) by-product gypsum. Phase I of the project focused on the process for converting FGD-gypsum to ammonium sulfate fertilizer with PCC produced as a by-product during the conversion. Early cost estimates suggested that the process was economically feasible when granular size ammonium sulfate crystals were produced. However, sale of the by-product PCC for high-value commercial application could further improve the economics of the process. The results of our evaluation of the market potential of the PCC by-product are reported in this paper. The most significant attributes of carbonate fillers that determine their usefulness in industry are particle size (i.e. fineness) and shape, whiteness (brightness), and mineralogical and chemical purity. The PCC produced from the FGD gypsum obtained from the Abbott Power Plant at the University of Illinois Urbana-Champaign campus are pure calcite with a CaCO{sub 3} content greater than 98%, 3% higher than the minimum requirement of 95%. However, the size, shape, and brightness of the PCC particles are suitable only for certain applications. Impurities in the gypsum from Abbott power plant influence the whiteness of the PCC products. Test results suggested that, to obtain gypsum that is pure enough to produce a high whiteness PCC for high value commercial applications, limestone with minimum color impurities should be used during the FGD process. Alternatively, purification procedures to obtain the desired whiteness of the FGD-gypsum can be used. Further improvement in the overall qualities of the PCC products should lead to a product that is adequate for high-value paper applications.

  5. Study of mercury in by-products from a Dutch co-combustion power station.

    PubMed

    Rallo, Manuela; Lopez-Anton, M Antonia; Meij, Ruud; Perry, Ron; Maroto-Valer, M Mercedes

    2010-02-15

    Fly ashes and gypsum are one of the main wastes produced in coal-fired power stations which may be sent to landfills for their disposal. In this work, leaching and speciation of mercury in fly ashes and gypsum from a modern co-combustion power plant equipped with a selective catalytic reduction (SCR) unit in the Netherlands were studied. The mercury leachable contents were checked against different regulations, including Dutch, German and the Council Directive 2003/33/EC. The speciation of mercury in coal combustion products is essential not only to determine the risk when the wastes are finally disposed but also to understand the behaviour of mercury during combustion and therefore to select the appropriate mercury removal technology. A temperature-programmed decomposition technique was used in order to identify and quantify which mercury species are associated with coal combustion products. The main mercury species identified in fly ash samples was mercury sulphate, whereas in the gypsum sample the mercury present was mercury chloride. The quantitative mercury results carried out using the thermal desorption method may be considered accurate. The results obtained show that fly ash and gypsum samples from this power plant can be acceptable at landfills as a non-hazardous waste.

  6. DURABILITY EVALUATION AND PRODUCTION OF MANUFACTURED AGGREGATES FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect

    M. M. Wu

    2005-02-01

    Under the cooperative agreement with DOE, the Research and Development Department of CONSOL Energy (CONSOL R&D), teamed with Universal Aggregates, LLC, to conduct a systematic study of the durability of aggregates manufactured using a variety of flue gas desulfurization (FGD), fluidized-bed combustion (FBC) and fly ash specimens with different chemical and physical properties and under different freeze/thaw, wet/dry and long-term natural weathering conditions. The objectives of the study are to establish the relationships among the durability and characteristics of FGD material, FBC ash and fly ash, and to identify the causes of durability problems, and, ultimately, to increase the utilization of FGD material, FBC ash and fly ash as a construction material. Manufactured aggregates made from FGD material, FBC ash and fly ash, and products made from those manufactured aggregates were used in the study. The project is divided into the following activities: sample collection and characterization; characterization and preparation of manufactured aggregates; determination of durability characteristics of manufactured aggregates; preparation and determination of durability characteristics of manufactured aggregate products; and data evaluation and reporting.

  7. Speciation and Attenuation of Arsenic and Selenium at Coal Combustion By-Product Management Facilities

    SciTech Connect

    K. Ladwig; B. Hensel; D. Wallschlager; L. Lee; I Murarka

    2005-10-19

    Field leachate samples are being collected from coal combustion product (CCP) management sites from several geographic locations in the United States to provide broad characterization of major and trace constituents in the leachate. In addition, speciation of arsenic, selenium, chromium, and mercury in the leachates is being determined. Through 2003, 35 samples were collected at 14 sites representing a variety of CCP types, management approaches, and source coals. Samples have been collected from leachate wells, leachate collection systems, drive-point piezometers, lysimeters, the ash/water interface at impoundments, impoundment outfalls and inlets, and seeps. Additional sampling at 23 sites has been conducted in 2004 or is planned for 2005. First-year results suggest distinct differences in the chemical composition of leachate from landfills and impoundments, and from bituminous and subbituminous coals. Concentrations of most constituents were generally higher in landfill leachate than in impoundment leachate. Sulfate, sodium, aluminum, molybdenum, vanadium, cadmium, mercury and selenium concentrations were higher in leachates for ash from subbituminous source coal. Calcium, boron, lithium, strontium, arsenic, antimony, and nickel were higher for ash from bituminous source coal. These variations will be explored in more detail when additional data from the 2004 and 2005 samples become available.

  8. Speciation and Attenuation of Arsenic and Selenium at Coal Combustion By-Product Management Facilities

    SciTech Connect

    K. Ladwig

    2005-12-31

    The overall objective of this project was to evaluate the impact of key constituents captured from power plant air streams (principally arsenic and selenium) on the disposal and utilization of coal combustion products (CCPs). Specific objectives of the project were: (1) to develop a comprehensive database of field leachate concentrations at a wide range of CCP management sites, including speciation of arsenic and selenium, and low-detection limit analyses for mercury; (2) to perform detailed evaluations of the release and attenuation of arsenic species at three CCP sites; and (3) to perform detailed evaluations of the release and attenuation of selenium species at three CCP sites. Each of these objectives was accomplished using a combination of field sampling and laboratory analysis and experimentation. All of the methods used and results obtained are contained in this report. For ease of use, the report is subdivided into three parts. Volume 1 contains methods and results for the field leachate characterization. Volume 2 contains methods and results for arsenic adsorption. Volume 3 contains methods and results for selenium adsorption.

  9. THE USE OF COAL COMBUSTION BY-PRODUCTS FOR IN SITU TREATMENT OF ACID MINE DRAINAGE

    SciTech Connect

    Geoffrey A. Canty; Jess W. Everett

    2004-09-30

    In 1994 a demonstration project was undertaken to investigate the effectiveness of using CCBs for the in situ treatment of acidic mine water. Actual injection of alkaline material was performed in 1997 with initial positive results; however, the amount of alkalinity added to the system was limited and resulted in short duration treatment. In 1999, a CBRC grant was awarded to further investigate the effectiveness of alkaline injection technology (AIT). Funds were released in fall 2001. In December 2001, 2500 tons of fluidized bed combustion (FBC) ash were injected into the wells used in the 1997 injection project. Post injection monitoring continued for 24 months. During this period the mine chemistry had gone through a series of chemical changes that manifested as stages or ''treatment phases.'' The mine system appeared to be in the midst of reestablishing equilibrium with the partial pressure of mine headspace. Alkalinity and pH appeared to be gradually increasing during this transition. As of December 2003, the pH and alkalinity were roughly 7.3 and 65 ppm, respectively. Metal concentrations were significantly lower than pre-injection levels, but iron and manganese concentrations appeared to be gradually increasing (roughly 30 ppm and 1.25 ppm, respectively). Aluminum, nickel, and zinc were less than pre-injection concentrations and did not appear to be increasing (roughly

  10. Performance and mechanism on a high durable silica alumina based cementitious material composed of coal refuse and coal combustion byproducts

    NASA Astrophysics Data System (ADS)

    Yao, Yuan

    Coal refuse and combustion byproducts as industrial solid waste stockpiles have become great threats to the environment. Recycling is one practical solution to utilize this huge amount of solid waste through activation as substitute for ordinary Portland cement. The central goal of this dissertation is to investigate and develop a new silica-alumina based cementitious material largely using coal refuse as a constituent that will be ideal for durable construction, mine backfill, mine sealing and waste disposal stabilization applications. This new material is an environment-friendly alternative to ordinary Portland cement. The main constituents of the new material are coal refuse and other coal wastes including coal sludge and coal combustion products (CCPs). Compared with conventional cement production, successful development of this new technology could potentially save energy and reduce greenhouse gas emissions, recycle vast amount of coal wastes, and significantly reduce production cost. A systematic research has been conducted to seek for an optimal solution for enhancing pozzolanic reactivity of the relatively inert solid waste-coal refuse in order to improve the utilization efficiency and economy benefit for construction and building materials. The results show that thermal activation temperature ranging from 20°C to 950°C significantly increases the workability and pozzolanic property of the coal refuse. The optimal activation condition is between 700°C to 800°C within a period of 30 to 60 minutes. Microanalysis illustrates that the improved pozzolanic reactivity contributes to the generated amorphous materials from parts of inert aluminosilicate minerals by destroying the crystallize structure during the thermal activation. In the coal refuse, kaolinite begins to transfer into metakaol in at 550°C, the chlorite minerals disappear at 750°C, and muscovite 2M1 gradually dehydroxylates to muscovite HT. Furthermore, this research examines the environmental

  11. Passive treatment of acid mine drainage using coal combustion by-products and spent mushroom substrate: Results of column study

    SciTech Connect

    Crisp, T.E.; Nairn, R.W.; Strevett, K.A.; Everett, J.

    1998-12-31

    A column study was conducted to evaluate the feasibility of using of coal combustion by-products (CCB) as alkaline materials in a field scale downflow constructed wetlands for acid mine drainage treatment. Five columns (15.24 cm in diameter and 91.44 cm high) were constructed and filled with a combination of spent mushroom substrate (SMS) and one of three alkaline materials (limestone, hydrated fly ash, or fluidized bed ash). The five mixtures utilized were 10% fluidized bed ash/40% limestone (FBA/LS), 10% fluidized bed ash (FBA), 50% limestone (LS), 50% hydrated fly ash (HFA),m and 50% sieved (>1.5 cm) hydrated fly ash (S. HFA) with the remainder as SMS on a w/w basis. Column received synthetic acid mine drainage containing: 400 mg/L iron, 59 mg/L aluminum, 11 mg/L manganese, 50% mg/L magnesium, 40 mg/L calcium, and 1200 mg/L sulfate for 5 months. Anoxic conditions in the influent reservoirs were maintained by a positive nitrogen pressure head. Flow rates of 2.0 mL/minute to each column were maintained by a multichannel peristaltic pump. For all columns, effluent acidity concentrations were less than influent acidity concentration (877{sup {minus}}30, n = 75f). Mean effluent acidity concentrations were 241 mg/L (FBA/LS), 186 mg/L (FBA), 419 mg/L (LS), {minus}28.5 mg/L (HFA), and 351 mg/L (S. HFA), respectively. While all column produced measurable alkalinity, only the HFA column produced a net alkaline discharge. The results of these column studies are applicable to the design and sizing of innovative field scale systems using alkaline-rich CCB`s.

  12. RESIDENTIAL WOOD COMBUSTION TECHNOLOGY REVIEW VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    This report gives results of a review of the current state-of-the-art of residential wood combustion (RWC). The key environmental parameter of concern was the air emission of particles. The technological status of all major RWC categories -- cordwood stoves, fireplaces, masonry h...

  13. Technical support for the Ohio Clean Coal Technology Program. Volume 2, Baseline of knowledge concerning process modification opportunities, research needs, by-product market potential, and regulatory requirements: Final report

    SciTech Connect

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L.

    1989-08-28

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LR1 and comprises two volumes. Volume 1 presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume 2 consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  14. 14th congress of combustion by-products and their health effects-origin, fate, and health effects of combustion-related air pollutants in the coming era of bio-based energy sources.

    PubMed

    Weidemann, Eva; Andersson, Patrik L; Bidleman, Terry; Boman, Christoffer; Carlin, Danielle J; Collina, Elena; Cormier, Stephania A; Gouveia-Figueira, Sandra C; Gullett, Brian K; Johansson, Christer; Lucas, Donald; Lundin, Lisa; Lundstedt, Staffan; Marklund, Stellan; Nording, Malin L; Ortuño, Nuria; Sallam, Asmaa A; Schmidt, Florian M; Jansson, Stina

    2016-04-01

    The 14th International Congress on Combustion By-Products and Their Health Effects was held in Umeå, Sweden from June 14th to 17th, 2015. The Congress, mainly sponsored by the National Institute of Environmental Health Sciences Superfund Research Program and the Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning, focused on the "Origin, fate and health effects of combustion-related air pollutants in the coming era of bio-based energy sources". The international delegates included academic and government researchers, engineers, scientists, policymakers and representatives of industrial partners. The Congress provided a unique forum for the discussion of scientific advances in this research area since it addressed in combination the health-related issues and the environmental implications of combustion by-products. The scientific outcomes of the Congress included the consensus opinions that: (a) there is a correlation between human exposure to particulate matter and increased cardiac and respiratory morbidity and mortality; (b) because currently available data does not support the assessment of differences in health outcomes between biomass smoke and other particulates in outdoor air, the potential human health and environmental impacts of emerging air-pollution sources must be addressed. Assessment will require the development of new approaches to characterize combustion emissions through advanced sampling and analytical methods. The Congress also concluded the need for better and more sustainable e-waste management and improved policies, usage and disposal methods for materials containing flame retardants.

  15. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The purpose of this letter is to notify you that the Department of Energy Office of Fossil Energy's Innovations for Existing Plants Program has been zeroed out in the President's Fiscal Year (FY) 2008 budget.

  16. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The overall objective of this research effort was to provide a potentially commercial thermal treatment of fly ash to decrease the interaction between fly ash and the surfactants used to entrain air in concrete when fly ash replaces a portion of the Portland cement in oncrete. The thermal treatment resulting from this research effort, and described in this report, fulfill the above objective. This report describes the thermal treatment developed and applies the treatment to six different fly ashes subsequently used to prepare concrete test cylinders hat show little or no difference in compressibility when compared to concrete test cylinders prepared using untreated fly ash.

  17. UNDERGROUNG PLACEMENT OF COAL PROCESSING WASTE AND COAL COMBUSTION BY-PRODUCTS BASED PASTE BACKFILL FOR ENHANCED MINING ECONOMICS

    SciTech Connect

    Y.P. Chugh; D. Biswas; D. Deb

    2002-06-01

    This project has successfully demonstrated that the extraction ratio in a room-and-pillar panel at an Illinois mine can be increased from the current value of approximately 56% to about 64%, with backfilling done from the surface upon completion of all mining activities. This was achieved without significant ground control problems due to the increased extraction ratio. The mined-out areas were backfilled from the surface with gob, coal combustion by-products (CCBs), and fine coal processing waste (FCPW)-based paste backfill containing 65%-70% solids to minimize short-term and long-term surface deformations risk. This concept has the potential to increase mine productivity, reduce mining costs, manage large volumes of CCBs beneficially, and improve the miner's health, safety, and environment. Two injection holes were drilled over the demonstration panel to inject the paste backfill. Backfilling was started on August 11, 1999 through the first borehole. About 9,293 tons of paste backfill were injected through this borehole with a maximum flow distance of 300-ft underground. On September 27, 2000, backfilling operation was resumed through the second borehole with a mixture of F ash and FBC ash. A high-speed auger mixer (new technology) was used to mix solids with water. About 6,000 tons of paste backfill were injected underground through this hole. Underground backfilling using the ''Groutnet'' flow model was simulated. Studies indicate that grout flow over 300-foot distance is possible. Approximately 13,000 tons of grout may be pumped through a single hole. The effect of backfilling on the stability of the mine workings was analyzed using SIUPANEL.3D computer program and further verified using finite element analysis techniques. Stiffness of the backfill mix is most critical for enhancing the stability of mine workings. Mine openings do not have to be completely backfilled to enhance their stability. Backfill height of about 50% of the seam height is adequate to

  18. WOOD PRODUCTS IN THE WASTE STREAM: CHARACTERIZATION AND COMBUSTION EMISSIONS - VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report gives results of a study of technical, public policy, and regulatory issues that affect the processing and combustion of waste wood for fuel. (NOTE: Waste wood is wood that is separated from a solid-waste stream, processed into a uniform-sized product, and reused for o...

  19. Technical advances and new opportunities for fluidized bed combustion

    SciTech Connect

    Alliston, M.G.; Kokko, A.; Martin, B.G.; Olofsson, J.

    1997-12-31

    This paper outlines opportunities for new circulating fluidized bed (CFB) boilers, technical considerations in selecting a fluidized bed boiler, and CFB boiler configuration types and sizes. New opportunities for CFBs include fuel opportunities from coke, mine mouth coals, and waste products, and boiler application opportunities in industrial cogeneration, repowering, and developing nations. Technical considerations discussed for boiler selection are fuel flexibility and environmental aspects. Three boiler configurations are briefly described: (1) water-cooled cyclone with water-cooled loopseal, (2) integral cylindrical cyclone and loopseal, and (3) Cylindrical multi-inlet cyclone. CFB scale-up is also briefly discussed. 3 refs., 3 figs.

  20. Origin and Health Impacts of Emissions of Toxic By-Products and Fine Particles from Combustion and Thermal Treatment of Hazardous Wastes and Materials

    PubMed Central

    Cormier, Stephania A.; Lomnicki, Slawo; Backes, Wayne; Dellinger, Barry

    2006-01-01

    High-temperature, controlled incineration and thermal treatment of contaminated soils, sediments, and wastes at Superfund sites are often preferred methods of remediation of contaminated sites under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 and related legislation. Although these methods may be executed safely, formation of toxic combustion or reaction by-products is still a cause of concern. Emissions of polycyclic aromatic hydrocarbons (PAHs); chlorinated hydrocarbons (CHCs), including polychlorinated dibenzo-p-dioxins and dibenzofurans; and toxic metals (e.g., chromium VI) have historically been the focus of combustion and health effects research. However, fine particulate matter (PM) and ultrafine PM, which have been documented to be related to cardiovascular disease, pulmonary disease, and cancer, have more recently become the focus of research. Fine PM and ultrafine PM are effective delivery agents for PAHs, CHCs, and toxic metals. In addition, it has recently been realized that brominated hydrocarbons (including brominated/chlorinated dioxins), redox-active metals, and redox-active persistent free radicals are also associated with PM emissions from combustion and thermal processes. In this article, we discuss the origin of each of these classes of pollutants, the nature of their association with combustion-generated PM, and the mechanisms of their known and potential health impacts. PMID:16759977

  1. PILOT-SCALE STUDIES ON THE EFFECT OF BROMINE ADDITION ON THE EMISSIONS OF CHLORINATED ORGANIC COMBUSTION BY-PRODUCTS

    EPA Science Inventory

    The addition of brominated organic compounds to the feed of a pilot-scale incinerator burning chlorinated waste has been found previously, under some circumstances, to enhance emissions of volatile and semivolatile organic chlorinated products of incomplete combustion (PiCs) incl...

  2. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  3. Barriers to the increased utilization of coal combustion/desulfurization by-products by government and commercial sectors - Update 1998

    SciTech Connect

    Pflughoeft-Hassett, D.F.; Sondreal, E.A.; Steadman, E.N.; Eylands, K.E.; Dockter, B.A.

    1999-07-01

    The following conclusions are drawn from the information presented in this report: (1) Joint efforts by industry and government focused on meeting RTC recommendations for reduction/removal of barriers have met with some success. The most notable of these are the changes in regulations related to CCB utilization by individual states. Regionally or nationally consistent state regulation of CCB utilization would further reduce regulatory barriers. (2) Technology changes will continue to be driven by the CAAA, and emission control technologies are expected to continue to impact the type and properties of CCBs generated. As a result, continued RD and D will be needed to learn how to utilize new and changing CCBs in environmentally safe, technically sound, and economically advantageous ways. Clean coal technology CCBs offer a new challenge because of the high volumes expected to be generated and the different characteristics of these CCBs compared to those of conventional CCBs. (3) Industry and government have developed the RD and D infrastructure to address the technical aspects of developing and testing new CCB utilization applications, but this work as well as constant quality control/quality assurance testing needs to be continued to address both industry wide issues and issues related to specific materials, regions, or users. (4) Concerns raised by environmental groups and the public will continue to provide environmental and technical challenges to the CCB industry. It is anticipated that the use of CCBs in mining applications, agriculture, structural fills, and other land applications will continue to be controversial and will require case-by-case technical and environmental information to be developed. The best use of this information will be in the development of generic regulations specifically addressing the use of CCBs in these different types of CCB applications. (5) The development of federal procurement guidelines under Executive Order 12873 titled

  4. Analysis of markets for coal combustion by-products use in agriculture and land reclamation. Summary report of four regional marketing studies, Final report

    SciTech Connect

    Horn, M.E.

    1993-12-01

    Marketing studies in four US regions assessed the factors affecting the land application of coal combustion by-products (CCBP) as soil physical and chemical amendments. These studies were conducted under the sponsorship of the Electric Power Research Institute with additional support by utilities located in the Northeast, Southeast, Midwest, and Southwest regions of the United States, namely the Empire State Electric Energy Research Corporation (ESEERCO); Southern Company Services, Inc.; Union Electric Company; and Houston Lighting and Power Company. The Texas Municipal Power Agency also provided information and insight into CCBP disposal in Texas, thus contributing to the regional assessment of CCBP use in agriculture and reclamation in the Southwest. These case studies centered on CCBP from specific power plants and the potential for land application in regions around the plants. The studies provide estimates of (1) the types of CCBP usage possible in each region, (2) potential volumes of CCBP that could be applied, and (3) the value of CCBP as soil amendments based on increased yields or reduced commercial lime and fertilizer usage. Finally, the studies help identify steps necessary to enhance the use of CCBP as soil amendments. These steps include performing further research on the yield response of specific crops and soils to CCBP and addressing regulations that act as barriers to CCBP use.

  5. MARKET ASSESSMENT AND TECHNICAL FEASIBILITY STUDY OF PRESSURIZED FLUIDIZED BED COMBUSTION ASH USE

    SciTech Connect

    A.E. Bland; T.H. Brown

    1997-04-01

    Western Research Institute, in conjunction with the Electric Power Research Institute, Foster Wheeler International, Inc. and the US Department of Energy, has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for PFBC ashes. Ashes from the Foster Wheeler Energia Oy pilot-scale circulating PFBC tests in Karhula, Finland, combusting (1) low-sulfur subbituminous and (2) high-sulfur bituminous coal, and ash from the AEP's high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at WR1. The technical feasibility study examined the use of PFBC ash in construction-related applications, including its use as a cementing material in concrete and use in cement manufacturing, fill and embankment materials, soil stabilization agent, and use in synthetic aggregate production. Testing was also conducted to determine the technical feasibility of PFBC ash as a soil amendment for acidic and sodic problem soils and spoils encountered in agricultural and reclamation applications. The results of the technical feasibility testing indicated the following conclusions. PFBC ash does not meet the chemical requirements as a pozzolan for cement replacement. However, it does appear that potential may exist for its use in cement production as a pozzolan and/or as a set retardant. PFBC ash shows relatively high strength development, low expansion, and low permeability properties that make its use in fills and embankments promising. Testing has also indicated that PFBC ash, when mixed with low amounts of lime, develops high strengths, suitable for soil stabilization applications and synthetic aggregate production. Synthetic aggregate produced from PFBC ash is capable of meeting ASTM/AASHTO specifications for many construction applications. The residual calcium carbonate and calcium sulfate in the PFE3C ash has been shown to be of value in

  6. [Pulsed atmospheric fluidized bed combustion (PAFBC)]. Technical progress report, May--July 1988

    SciTech Connect

    Not Available

    1988-10-01

    This first Quarterly Technical Progress Report presents the results of work accomplished during the period April 19 through July 24,1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. the program scope consisted of two tasks; the first was to establish preliminary feasibility by the use of theoretical and state-of-the-art information. This task was completed during the first quarter of the contract period and a topical report entitled, ``Pulsed Atmospheric Fluidized Bed combustion (PAFBC) - Preliminary Feasibility Study`` was prepared as a ``decision point to proceed`` deliverable in accordance with the terms of the contract. This first quarterly progress report therefore covers the contract activities subsequent to the approval of the feasibility study and the decision to proceed with the Task 2 effort. As the initial quarterly technical progress report, this document includes a subsection on background which will be omitted in subsequent reports. All effort during this period was devoted to the design and analysis of the PAFBC. Design drawings were prepared and fabrication and procurement initiated. Quotations were evaluated and a fabrication contract awarded. A site adjacent to the MTCI building was chosen for the installation of the PAFBC. Some ancillary components were purchased, renovated, and tested. Some delays in delivery of components have resulted in some schedule delay. It is anticipated that the program pace will accelerate as soon as parts are received and installation and assembly are initiated. 10 figs.,1 tab.

  7. Utilization of coal combustion by-products in mine reclamation and agriculture -- A summary of selected U.S. Department of Energy projects

    SciTech Connect

    Aljoe, W.W.

    1998-12-31

    Most solid coal combustion by-products (CCBs) such as fly ash, bottom ash, and flue gas desulfurization (FGD) sludge are currently disposed of in slurry ponds or landfills. While these practices may continue to be the most economical alternatives for some utilities, increasingly stringent environmental regulations and public opposition to new landfill construction are forcing many utilities to explore alternative uses for CCBs. Some alternative uses have proven to be very profitable, such as the sale of fly ash for use in cement and the production of wallboard from FGD sludge. However, in many cases such uses are not economically feasible because the physical or chemical characteristics of the CCBs are not suitable and/or the market price of the processed, recycled CCB is not competitive. Therefore, there is a need to find alternative, environmentally friendly uses for large volumes of CCBs that do not require tight quality specifications or extensive processing by the utility. To date, mine reclamation and agricultural applications appear to be the most attractive high-volume utilization methods, but the actual costs and environmental benefits of these practices need to be demonstrated and documented before the industry and regulatory agencies can accept them routinely as viable alternatives to landfilling. This paper summarizes the results of various completed and ongoing projects sponsored or cosponsored by the US Department of Energy that have been directed toward the demonstration of CCB use in mine reclamation and agriculture. Important benefits of these demonstrations include the mitigation of underground mine subsidence, abatement of acid mine drainage, increased productivity from highwall mines, improvement of mine soil productivity, inexpensive substitution for agricultural lime in growth of selected crops, and increased efficiency of cattle feeding via structural stabilization of feedlots.

  8. Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use

    SciTech Connect

    Bland, A.E.; Brown, T.H.

    1996-12-31

    Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

  9. Combustion

    NASA Technical Reports Server (NTRS)

    Bulzan, Dan

    2007-01-01

    An overview of the emissions related research being conducted as part of the Fundamental Aeronautics Subsonics Fixed Wing Project is presented. The overview includes project metrics, milestones, and descriptions of major research areas. The overview also includes information on some of the emissions research being conducted under NASA Research Announcements. Objective: Development of comprehensive detailed and reduced kinetic mechanisms of jet fuels for chemically-reacting flow modeling. Scientific Challenges: 1) Developing experimental facilities capable of handling higher hydrocarbons and providing benchmark combustion data. 2) Determining and understanding ignition and combustion characteristics, such as laminar flame speeds, extinction stretch rates, and autoignition delays, of jet fuels and hydrocarbons relevant to jet surrogates. 3) Developing comprehensive kinetic models for jet fuels.

  10. Fundamental characterization of alternate fuel effects in continuous combustion systems. Summary technical progress report, August 15, 1978-January 31, 1980

    SciTech Connect

    Blazowski, W.S.; Edelman, R.B.; Wong, E.

    1980-02-27

    The overall objective of this contract is to assist in the development of fuel-flexible combustion systems for gas turbines as well as Rankine and Stirling cycle engines. The primary emphasis of the program is on liquid hydrocarbons produced from non-petroleum resources. Fuel-flexible combustion systems will provide for more rapid transition of these alternative fuels into important future energy utilization centers (especially utility power generation with the combined cycle gas turbine). The specific technical objectives of the program are: (a) develop an improved understanding of relationships between alternative fuel properties and continuous combustion system effects, and (b) provide analytical modeling/correlation capabilities to be used as design aids for development of fuel-tolerant combustion systems. This is the second major report of the program. Key experimental findings during this reporting period concern stirred combustor soot production during operation at controlled temperature conditions, soot production as a function of combustor residence time, an improved measurement technique for total hydrocarbons and initial stirred combustor results of fuel nitrogen conversion. While the results to be presented concern a stirred combustor which utilizes premixed fuel vapor/oxidant mixtures, a new combustor which combusts liquid fuel injected into the reactor as a spray has been developed and will be described. Analytical program progress includes the development of new quasiglobal models of soot formation and assessment of needs for other submodel development.

  11. Management of dry flue gas desulfurization by-products in underground mines. Technical progress report, 1 January--31 March 1994

    SciTech Connect

    Chugh, Y.P.; Esling, S.; Ghafoori, N.; Honaker, R.; Paul, B.; Sevim, H.; Thomasson, E.

    1994-04-01

    Southern Illinois University at Carbondale will develop and demonstrate several technologies for the handling and transport of dry coal combustion residues and for the underground placement in abandoned coal mines and assess associated environmental impacts. Although parts of the Residue Characterization portion of the program were delayed because residue samples were not obtained, other parts of the program are proceeding on schedule. The delays in obtaining residue samples were primarily caused by adverse weather conditions, the shut-down of one unit at the City Water, Light, and Power Company Plant for routing maintenance and problems due to conflicting schedules of utility and program personnel. However, by the end of the quarter most residue samples had been obtained, and the residue characterization studies were under way. Progress is described for five studies: environmental assessment and geotechnical stability and subsidence impacts; residue characterization; physico-chemical characterization of residues; identification and assessment of handling/transportation systems for FGD residues; and residue handling and transport.

  12. SITE PROGRAM EVALUATION OF THE SONOTECH PULSE COMBUSTION BURNER TECHNOLOGY - TECHNICAL RESULTS

    EPA Science Inventory

    A series of demonstration tests was performed at the Environmental Protection Agency's (EPA's) Incineration Research Facility (IRF) under the Superfund Innovative Technology Evaluation (SITE) program. These tests, twelve in all, evaluated a pulse combustion burner technology dev...

  13. Combustion characterization of coals for industrial applications. Final technical report, January 1, 1981-May 29, 1985

    SciTech Connect

    Nsakala, N.; Patel, R.L.; Lao, T.C.

    1985-03-01

    In-depth fundamental information was obtained from a two-inch inner diameter laminar flow reactor referred to as the Drop Tube Furnace System (DTFS). This information consists of the following: (1) pyrolysis kinetic characteristics of four coals of various rank (Texas lignite, Montana subbituminous, Alabama high volatile bituminous, and Pennsylvania anthracite); and (2) combustion kinetic studies of chars produced from the foregoing parent coals. A number of standard ASTM and special in-house bench scale tests were also performed on the coals and chars prepared therefrom to characterize their physicochemical properties. The pilot scale (500,000 Btu/hr) Controlled Mixing History Furnace (CMHF) was used to determine the effect of staged combustion on NO/sub x/ emissions control from an overall combustion performance of the Alabama high volatile bituminous coal. The quantitative fundamental data developed from this study indicate significant differences in coal/char chemical, physical, and reactivity characteristics, which should be useful to those interested in modeling coal combustion and pyrolysis processes. These results underscore the fact that coal selection is one of the keys governing a successful coal conversion/utilization process. The combustion kinetic information obtained on the high volatile bituminous coal has been used in conjunction with combustion engineering's proprietary mathematical models to predict the combustion performance of this coal in the Controlled Mixing History Furnace. Comparison of the predicted data with the experimental results shows a virtually one-to-one scale-up from the DTFS to the CMHF. These data should provide vital information to designers in the area of carbon burnout and NO/sub x/ reduction for large scale coal utilization applications. 31 refs., 28 figs., 17 tabs.

  14. 10 CFR 35.75 - Release of individuals containing unsealed byproduct material or implants containing byproduct...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 1 2013-01-01 2013-01-01 false Release of individuals containing unsealed byproduct material or implants containing byproduct material. 35.75 Section 35.75 Energy NUCLEAR REGULATORY COMMISSION MEDICAL USE OF BYPRODUCT MATERIAL General Technical Requirements § 35.75 Release of...

  15. 10 CFR 35.75 - Release of individuals containing unsealed byproduct material or implants containing byproduct...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 1 2014-01-01 2014-01-01 false Release of individuals containing unsealed byproduct material or implants containing byproduct material. 35.75 Section 35.75 Energy NUCLEAR REGULATORY COMMISSION MEDICAL USE OF BYPRODUCT MATERIAL General Technical Requirements § 35.75 Release of...

  16. 10 CFR 35.75 - Release of individuals containing unsealed byproduct material or implants containing byproduct...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 1 2011-01-01 2011-01-01 false Release of individuals containing unsealed byproduct material or implants containing byproduct material. 35.75 Section 35.75 Energy NUCLEAR REGULATORY COMMISSION MEDICAL USE OF BYPRODUCT MATERIAL General Technical Requirements § 35.75 Release of...

  17. 10 CFR 35.75 - Release of individuals containing unsealed byproduct material or implants containing byproduct...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 1 2012-01-01 2012-01-01 false Release of individuals containing unsealed byproduct material or implants containing byproduct material. 35.75 Section 35.75 Energy NUCLEAR REGULATORY COMMISSION MEDICAL USE OF BYPRODUCT MATERIAL General Technical Requirements § 35.75 Release of...

  18. Proceedings of the sixth international conference on fluidized bed combustion. Volume II. Technical sessions

    SciTech Connect

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. The papers covered recent developments in atmospheric and pressurized fluidized-bed combustion, especially the design, operation and control of pilot and demonstration plants. The cleanup of combustion products and the erosion, corrosion and fouling of gas turbines was emphasized also. Fifty-five papers from Volume 2 of the proceedings have been entered individually into EDB and ERA; five papers had been entered previously from other sources. (LTN)

  19. Production of Jet Fuels from Coal Derived Liquids. Volume 7. GPGP Jet Fuels Production Program. Evaluation of Technical Uncertainties for Producing Jet Fuels from Liquid By-Products of the Great Plains Gasification Plant

    DTIC Science & Technology

    1989-01-01

    AFWAL-TR-87-2042 VOLUME VII PRODUCTION OF JET FUELS FROM COAL DERIVED LIQUIDS I VOLUME VII -- GPGP JET FUELS PRODUCTION PROGRAM -- EVALUATION OF o...from Coal Derived Liquids, Vol VII - GPGP Jet Fuels Production Program - Evaluation of Technical Uncertainties for Producing Jet Fuels from Liquid By...potential of jet fuel production from the liquid by-product streams produced by the gasification of lignite at the Great Plains Gasification Plant ( GPGP

  20. CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

  1. Combustion properties of coal-char blends: No{sub x} emission characteristics. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect

    Rostam-Abadi, M.; Khan, L.; Smoot, L.D.; Germane, G.J.; Eatough, C.N.; Honea, F.

    1993-05-01

    Tests under pulverized coal combustion conditions suggest that NO{sub x} formed during release of volatile matter far exceed NO{sub x} formed during combustion of the resulting char. This is attributed to char/NO{sub x} interactions by both direct reduction of NO, by carbon and char-catalyzed reduction by CO. This implies combustion of char not only produces substantially lower No{sub x} but the presence of char in the flame during initial stages of combustion may potentially provide catalytic activity for reduction of NO{sub x} produced from volatile nitrogen. The goal of the project is to determine if the concept of NO{sub x} reduction by char/NO{sub x} interactions, while maintaining a high combustion efficiency by co-firing coal with char, is a technically feasible way to reduce NO{sub x} emissions. Char samples will be prepared in a continuous rotary tube kiln under mild gasification conditions. Combustion testing will be conducted with the coal and coal-char blends in a combustor located at BYU. The effect of coal/char ratio, formation characteristics, ignition characteristics, flame stability, and combustion efficiency will be determined. Physical and chemical properties of the fuels will be measured to help explain combustion and emission characteristics of fuels.

  2. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Smeenk, J.L.

    1995-04-01

    Experiments performed support the hypothesis that a reducing atmosphere during fluidized bed coal combustion contributes to the formation of agglomerates. Reducing conditions are imposed by controlling the amount of combustion air supplied to the combustor, 50% of theoretical in these experiments. These localized reducing conditions may arise from either poor lateral bed mixing or oxygen-starved conditions due to the coal feed locations. Deviations from steady-state operating conditions in bed pressure drop may be used to detect agglomerate formation. Interpretation of the bed pressure drop was made more straightforward by employing a moving average difference method. During steady-state operation, the difference between the moving point averages should be close to zero, within {plus_minus}0.03 inches of water. Instability within the combustor, experienced once agglomerates begin to form, can be recognized as larger deviations from zero, on the magnitude of {plus_minus}0.15 inches of water.

  3. Pyrite thermochemistry, ash agglomeration, and char fragmentation during pulverized coal combustion. Final technical report

    SciTech Connect

    Akan-Etuk, A.; Diaz, R.; Niksa, S.

    1991-10-01

    The objective of the present work is to introduce an experimental program that will eventually lead to time-resolved iron ash composition over the technological operating domain. The preceding literature survey suggests two important stipulations on any such experimental program. The first stipulation is that good control must be established over the operating conditions, to accurately quantify their effects. The other is that data must be obtained rapidly, to thoroughly cover the important operating domain. This work presents a series of studies that has characterized the desulfurization of pyrite during the early stages of combustion. An experimental system was established and used to monitor the effects of oxygen, temperature, and residence time on the evolution of condensed phase products of the combustion of pure pyrite. (VC)

  4. Proceedings of the sixth international conference on fluidized bed combustion. Volume III. Technical sessions

    SciTech Connect

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. Forty-five papers from Vol. III of the proceedings have been entered individually into EDB and ERA. Two papers had been entered previously from other sources. (LTN)

  5. Pulsed atmospheric fluidized bed combustion. Technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-05-01

    During this first quarter, a lab-scale water-cooled pulse combustor was designed, fabricated, and integrated with old pilot-scale PAFBC test systems. Characterization tests on this pulse combustor firing different kinds of fuel -- natural gas, pulverized coal and fine coal -- were conducted (without fluidized bed operation) for the purpose of finalizing PAFBC full-scale design. Steady-state tests were performed. Heat transfer performance and combustion efficiency of a coal-fired pulse combustor were evaluated.

  6. Combustion and emissions characterization of pelletized coal fuels. [Quarterly] technical report, March 1--May 31, 1993

    SciTech Connect

    Rajan, S.

    1993-09-01

    Pelletization of coal offers a means of utilizing coal fines which otherwise would be difficult to use. Other advantages of coal pelletization include: (a) utilization of low grade fuels such as preparation plant waste, (b) impregnation of pellets with calcium carbonate or calcium hydroxide sorbent for efficient sulfur removal, and (c) utilization of coal fines of low quality in combination with different types of binders. The objective of this project is to investigate the carbon conversion efficiency and SO{sub 2} and NO{sub x} emissions from combusting pelletized coal fuels made from preparation plant waste streams using both limestone and calcium hydroxide as sorbent and cornstarch and gasification tar as binders. The combustion performance of these pelletized fuels is compared with equivalent data from a reference run-of-mine coal. Six different samples of coal pellets have been secured from ISGS researchers. Combustion and emissions characterization of these pellets in the laboratory scale 4-inch diameter circulating fluidized bed have been performed on some of the pellet samples. The pellets burn readily, and provide good bed temperature control. Preliminary results show good carbon conversion efficiencies. Oxides of nitrogen emissions are quite low and sulfur dioxide emissions are as good as or lower than those from a representative run-of-mine coal.

  7. Coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    1995-08-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. This includes new installations and those existing installations that were originally designed for oil or gas firing. The data generated by these projects must be sufficient for private-sector decisions on the feasibility of using coal as the fuel of choice. This work should also provide incentives for the private sector to continue and expand the development, demonstration, and application of these combustion systems. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications is being developed under contract DE-AC22-91PC91161 as part of this DOE development program. The current contract represents the third phase of a three-phase development program. Phase I of the program addressed the technical and economic feasibility of the process, and was initiated in 1987 and completed 1989. Phase II was initiated in 1989 and completed in 1990. During Phase II of the development, design improvements were made to critical components and the test program addressed the performance of the process using several different feedstocks. Phase III of the program was initiated September 1991 and is scheduled for completion in 1994. The Phase III research effort is being focused on the development of a process heater system to be used for producing value-added vitrified glass products from boiler/incinerator ashes and selected industrial wastes.

  8. A Novel High-Heat Transfer Low-NO{sub x} Natural Gas Combustion System. Final Technical Report

    SciTech Connect

    Abbasi, H.

    2004-01-01

    A novel high-heat transfer low NO(sub x) natural gas combustion system. The objectives of this program are to research, develop, test, and commercialize a novel high-heat transfer low-NO{sub x} natural gas combustion system for oxygen-, oxygen-enriched air, and air-fired furnaces. This technology will improve the process efficiency (productivity and product quality) and the energy efficiency of high-temperature industrial furnaces by at least 20%. GTI's high-heat transfer burner has applications in high-temperature air, oxygen-enriched air, and oxygen furnaces used in the glass, metals, cement, and other industries. Development work in this program is focused on using this burner to improve the energy efficiency and productivity of glass melting furnaces that are major industrial energy consumers. The following specific project objectives are defined to provide a means of achieving the overall project objectives. (1) Identify topics to be covered, problems requiring attention, equipment to be used in the program, and test plans to be followed in Phase II and Phase III. (2) Use existing codes to develop models of gas combustion and soot nucleation and growth as well as a thermodynamic and parametric description of furnace heat transfer issues. (3) Conduct a parametric study to confirm the increase in process and energy efficiency. (4) Design and fabricate a high-heat transfer low-NOx natural gas burners for laboratory, pilot- and demonstration-scale tests. (5) Test the high-heat transfer burner in one of GTI's laboratory-scale high-temperature furnaces. (6) Design and demonstrate the high-heat transfer burner on GTI's unique pilot-scale glass tank simulator. (7) Complete one long term demonstration test of this burner technology on an Owens Corning full-scale industrial glass melting furnace. (8) Prepare an Industrial Adoption Plan. This Plan will be updated in each program Phase as additional information becomes available. The Plan will include technical and

  9. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.D.

    1993-04-01

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed boilers is in progress. Preliminary results indicate that at least five boilers were experiencing some form of bed material agglomeration. In these instances it was observed that large particles were forming within the bed which were larger that the feed. Four operators could confirm that the larger bed particles had formed due to bed particles sticking together or agglomerating. Deposit formation was reported at nine sites with these deposits being found most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Examples of these agglomerates and deposits have been received from five of the surveyed facilities. Also during this quarter, a bulk sample of Illinois No. 6 coal was obtained from the Fossil Energy Program at Ames Laboratory here at Iowa State University and prepared for combustion tests. This sample was first ground to a top-size of 3/8`` using a jaw crusher then a size fraction of 3/8`` {times} 8 (US mesh) was then obtained by sieving using a Gilson Test-Master. This size fraction was selected for the preliminary laboratory-scale experiments designed to simulate the dense bed conditions that exist in the bottom of CFB combustors. To ensure uniformity of fuel composition among combustion runs, the sized coal was riffled using, a cone and long row method and stored in bags for each experiment. During this quarter additional modifications were made to achieve better control of fluidization regimes and to aid in monitoring the hydrodynamic and chemical conditions within the reactor.

  10. Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect

    Crelling, J.C.

    1993-12-31

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

  11. Bed material agglomeration during fluidized bed combustion. Technical progress report, September 30, 1992--December 31, 1992

    SciTech Connect

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  12. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  13. Coal combustion under conditions of blast furnace injection. Technical report, March 1, 1994--May 31, 1994

    SciTech Connect

    Crelling, J.C.

    1994-09-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This proposal is a follow-up to one funded for the 1992-93 period. It is intended to complete the study already underway with the Armco Inc. Steel Company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals for such use. During this quarter samples of two feed coals and the IBCSP 112 (Herrin No. 6) were prepared for reactivity testing and compared to blast furnace coke, and char fines taken from an active blast furnace. As the initial part of a broad reactivity analysis program, these same samples were also analyzed on a thermogravimetric analyzer (TGA) to determine their combustion and reactivity properties.

  14. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  15. Combustion and emissions characterization of pelletized coal fuels. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect

    Rajan, S.

    1993-05-01

    The aim of this project is to demonstrate that sorbent-containing coal pellets made from low grade coal or coal wastes are viable clean burning fuels, and to compare their performance with that of standard run-of-mine coal. Fuels to be investigated are: (a) carbonated pellets containing calcium hydroxide sorbent, (b) coal fines-limestone pellets with cornstarch as binder, (c) pellets made from preparation plant recovered coal containing limestone sorbent and gasification tar as binder, and (d) a standard run-of-mine Illinois seam coal. The fuels will be tested in a laboratory scale 411 diameter circulating fluidized bed combustor. Progress this quarter has centered on the development of a hydraulic press based pellet mill capable of the high compaction pressures necessary to produce the gasification tar containing pellets outlined in (c) above. Limited quantities of the pellets have been made, and the process is being fine tuned before proceeding into the production mode. Tests show that the moisture content of the coal is an important parameter that needs to be fixed within narrow limits for a given coal and binder combination to produce acceptable pellets. Combustion tests with these pellet fuels and the standard coal are scheduled for the next quarter.

  16. Combustion Fundamentals Research

    NASA Technical Reports Server (NTRS)

    1983-01-01

    Increased emphasis is placed on fundamental and generic research at Lewis Research Center with less systems development efforts. This is especially true in combustion research, where the study of combustion fundamentals has grown significantly in order to better address the perceived long term technical needs of the aerospace industry. The main thrusts for this combustion fundamentals program area are as follows: analytical models of combustion processes, model verification experiments, fundamental combustion experiments, and advanced numeric techniques.

  17. Development and testing of commercial-scale, coal-fired combustion systems, Phase 3. Technical progress report, October 1990--December 1990

    SciTech Connect

    Not Available

    1990-12-31

    The US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired equipment.

  18. Studying the effectiveness of activated carbon R95 respirators in reducing the inhalation of combustion by-products in Hanoi, Vietnam: a demonstration study

    PubMed Central

    2012-01-01

    Background Urban air pollution is an increasing health problem, particularly in Asia, where the combustion of fossil fuels has increased rapidly as a result of industrialization and socio-economic development. The adverse health impacts of urban air pollution are well established, but less is known about effective intervention strategies. In this demonstration study we set out to establish methods to assess whether wearing an R95 activated carbon respirator could reduce intake of polycyclic aromatic hydrocarbons (PAH) in street workers in Hanoi, Vietnam. Methods In this demonstration study we performed a cross-over study in which non-smoking participants that worked at least 4 hours per day on the street in Hanoi were randomly allocated to specific respirator wearing sequences for a duration of 2 weeks. Urines were collected after each period, i.e. twice per week, at the end of the working day to measure hydroxy PAHs (OH-PAH) using gas chromatography/high resolution mass spectrometry. The primary endpoint was the urinary concentration of 1-hydroxypyrene (1-OHP). Results Forty-four participants (54.5% male, median age 40 years) were enrolled with the majority being motorbike taxi drivers (38.6%) or street vendors (34.1%). The baseline creatinine corrected urinary level for 1-OHP was much higher than other international comparisons: 1020 ng/g creatinine (IQR: 604–1551). Wearing a R95 mask had no significant effect on 1-OHP levels: estimated multiplicative effect 1.0 (95% CI: 0.92-1.09) or other OH-PAHs, except 1-hydroxynaphthalene (1-OHN): 0.86 (95% CI: 0.11-0.96). Conclusions High levels of urine OH-PAHs were found in Hanoi street workers. No effect was seen on urine OH-PAH levels by wearing R95 particulate respirators in an area of high urban air pollution, except for 1-OHN. A lack of effect may be de to gaseous phase PAHs that were not filtered efficiently by the respirator. The high levels of urinary OH-PAHs found, urges for effective interventions. Trial

  19. Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, December 1, 1979-February 29, 1980

    SciTech Connect

    Garg, D; Givens, E N; Clinton, J H; Tarrer, A R; Guin, J A; Curtis, C W; Huang, S M

    1980-03-01

    This report describes work done in study of the role of coal minerals and by-product metallic wastes in coal liquefaction. Samples of Elkhorn No. 3 coal (Letcher County, Kentucky), Robena pyrite and several minerals and metallic by-product waste were acquired. The thermal behavior of various minerals and metallic by-product wastes was evaluated by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the presence of hydrogen, nitrogen and air. The coal process development unit was operated for 220 hours to obtain baseline data and provide information on the catalytic activity of Robena pyrite in solvent hydrogenation and coal liquefaction. We established that the base line reaction conditions to evaluate the activity of the various minerals, metallic wastes and by-products will be a tubing-bomb reactor of 46.3 ml volume at a reaction temperature of 450/sup 0/C for reaction times of 60 minutes. The reduced pyrite, Robena pyrite and Siniola Mexico pyrite were found to give similar product distribution and coal conversion. The oil production in the cases of reduced pyrite and pyrite was 4 times higher than that of no-catalyst run. Iron oxide (Fe/sub 2/O/sub 3/) was shown to give slightly higher coal conversion and oil production that pyrites and reduced pyrite. Presulfided Co-Mo-Al was found to give the highest coal conversion and oil production. The increase in oil production in the case of Co-Mo-Al was due to the conversion of both asphaltenes and preasphaltenes.

  20. DEVELOPMENT AND DEMONSTRATION OF A PILOT SCALE FACILITY FOR FABRICATION AND MARKETING OF LIGHTWEIGHT-COAL COMBUSTION BYPRODUCTS-BASED SUPPORTS AND MINE VENTILATION BLOCKS FOR UNDERGROUND MINES

    SciTech Connect

    Yoginder P. Chugh

    2002-10-01

    The overall goal of this program was to develop a pilot scale facility, and design, fabricate, and market CCBs-based lightweight blocks for mine ventilation control devices, and engineered crib elements and posts for use as artificial supports in underground mines to replace similar wooden elements. This specific project was undertaken to (1) design a pilot scale facility to develop and demonstrate commercial production techniques, and (2) provide technical and marketing support to Fly Lite, Inc to operate the pilot scale facility. Fly Lite, Inc is a joint venture company of the three industrial cooperators who were involved in research into the development of CCBs-based structural materials. The Fly-Lite pilot scale facility is located in McLeansboro, Illinois. Lightweight blocks for use in ventilation stoppings in underground mines have been successfully produced and marketed by the pilot-scale facility. To date, over 16,000 lightweight blocks (30-40 pcf) have been sold to the mining industry. Additionally, a smaller width (6-inch) full-density block was developed in August-September 2002 at the request of a mining company. An application has been submitted to Mine Safety and Health Administration for the developed block approval for use in mines. Commercialization of cribs and posts has also been accomplished. Two generations of cribs have been developed and demonstrated in the field. MSHA designated them suitable for use in mines. To date, over 2,000 crib elements have been sold to mines in Illinois. Two generations of posts were also demonstrated in the field and designated as suitable for use in mines by MSHA. Negotiations are currently underway with a mine in Illinois to market about 1,000 posts per year based on a field demonstration in their mine. It is estimated that 4-5 million tons CCBs (F-fly ash or FBC fly ash) may be utilized if the developed products can be commercially implemented in U.S. coal and non-coal mines.

  1. Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, 1 March 1980-31 May 1980

    SciTech Connect

    Garg, D; Schweighardt, F K; Givens, E N; Clinton, J H; Tarrer, A R; Guin, J A; Curtis, C W; Huang, S M

    1980-06-01

    This report describes work done in a study of the role of coal minerals and by-product metallic wastes in coal liquefaction. The thermal behavior of various minerals and metallic by-product wastes was evaluated by thermal gravimetric analysis and differential thermal analysis in the presence of hydrogen, nitrogen, and air. The CPDU was operated for 220 hours to obtain baseline data and provide information on the catalytic activity of Robena pyrite in solvent hydrogenation and coal liquefaction. A number of minerals were screened for catalytic activity toward coal liquefaction in a tubing-bomb reactor. The catalytic activity of the minerals was assessed by comparing the product distributions both in the presence of minerals and their absence. The use of a Bronson Sonifier was initiated in March to accelerate and improve the solvent separation technique. The addition of lime to the reaction mixture practically killed the liquefaction reaction. The addition of dolomite, rutile, illite, quartz, zircon, and calcite to the reaction mixture showed no significant improvement over that of a no additive run. The addition of zinc oxide and ilmenite showed slight improvement. Robena pyrite and Co-Mo-Al showed significant improvement in coal conversion and production of benzene solubles and gases. Iron oxide (Fe/sub 2/O/sub 3/) gave the highest conversion of coal and production of benzene solubles among all the minerals tested so far.

  2. By-Product Feeds

    Technology Transfer Automated Retrieval System (TEKTRAN)

    By-product feeds are generated from the production of food, fiber, and bio-energy products for human consumption. They include plant feedstuffs such as hulls, stalks, peels, and oil seed meals, and animal by-products such as blood meal, fats, bone meal, or processed organ meats. Some feed by-product...

  3. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect

    Chou, C.L.; Hackley, K.C.; Donnals, G.L.; Cao, J.; Ruch, R.R.; Pan, W.P.; Shao, D.

    1992-08-01

    The goal of this project is to study the evolution of gaseous sulfur and chlorine species during temperature-controlled pyrolysis and combustion and their effect on boiler corrosion. We have been developing two techniques for determining the gas evolution profiles of sulfur and chlorine during coal pyrolysis and combustion. First, using a pyrolysis-combustion system in combination with a quadrupole gas analyzer, the evolution of sulfur dioxide (SO{sub 2}) in combustion gas during temperature-programmed coal pyrolysis-combustion was monitored. When the atmosphere of the combustion chamber was changed to a reducing condition, gaseous COS and H{sub 2}S were also detected in the combustion gas. Detection of hydrogen chloride by QGA has been improved by using a larger-diameter (75 {mu}m) capillary tubing. The HC1 evolution profile during the pyrolysis of coal IBC-109 was determined by QGA and by a chloride ion selective electrode for quantitative purposes. Second, the technique of thermogravimetry (TG) in conjunction with Fourier transform infrared (FTIR) spectroscopy was used to characterize gaseous species during coal pyrolysis. Gas evolution profiles of sulfur (SO{sub 2} and COS), chlorine (HC1), and nitrogen (NH{sub 3} and HCN) species were determined for coal IBC-109. Similar release profiles of HCI and NH{sub 3} supported an interpretation that chlorine gnd nitrogen are closely associated in coal. COS may be formed by reaction of CO with H{sub 2}S in the gas phase. A mass balance study of chlorine evolution from coal IBC-109 in a TG-FTIR experiment was completed; the chloride dissolved in solutions was determined by an ion chromatographic technique.

  4. Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995

    SciTech Connect

    Benedek, K.; Flytzani-Stephanopoulos, M.

    1996-02-01

    The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

  5. Combustion of Illinois coals and chars with natural gas. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect

    Buckinus, R.O.; Peters, J.E.; Krier, H.

    1992-08-01

    The combined combustion of coal and natural gas offers advantageous compared to burning coal or natural gas alone. For example, low volatile coals or low volatile chars derived from treatment or gasification processes can be of limited use due to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. Additionally, natural gas provides a clean cofiring fuel source which can enhance the usefulness of coals with high sulfur content. Addition of natural gas may reduce SO{sub x} emissions through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. In this research program, studies of combined Illinois coal and natural gas combustion provide particle ignition, burnout rates and ash characterization, helping clarify the effect of coal and natural gas and identify the controlling parameters and mechanisms. The Drop Tube Furnace Facility allows detailed measurements of coal particle combustion under well-controlled conditions. The combustion characteristics of single coal particles are determined through a novel set of diagnostic techniques including in situ simultaneous measurements of particle morphology, temperature and velocity. The emphasis of the effort in the second quarter of this project was on the understanding of the ignition enhancement, burning rate processes during cofiring, and sulfur retention in the ash.

  6. Development and testing of a commercial-scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 3, April 1, 1991--June 30, 1991

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-10-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  7. Development and testing of a commercial-scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 2, January 1, 1991--March 31, 1991

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-07-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  8. Control of trace metal emissions during coal combustion. Technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    Ho, T.C.

    1996-07-01

    Emissions of toxic trace metals in the form of metal fumes or submicron particulates from a coal-fired combustion source have received greater environmental and regulatory concern over the past years. Current practice of controlling these emissions is to collect them at the cold-end of the process by air-pollution control devices (APCDs) such as electrostatic precipitators and baghouses. However, trace metal fumes may not always be effectively collected by these devices because the formed fumes are extremely small. The proposed research is to explore the opportunities for improved control of toxic trace metal emissions, alternatively, at the hot-end of the coal combustion process, i.e., in the combustion chamber. The technology proposed is to prevent the metal fumes from forming during the process, which would effectively eliminate the metal emission problems. Specifically, the technology is to employ suitable sorbents to (1) reduce the amount of metal volatilization during combustion and (2) capture volatilized metal vapors. The objectives of the project are to demonstrate the technology and to characterize the metal capture process during coal combustion in a fluidized bed combustor. The observed experimental results indicated that metal capture by sorbents can be as high as 91% depending on the metal species and sorbent involved. All three sorbents tested, i.e., bauxite, zeolite and lime, were observed to be capable of capturing lead and cadmium in a various degree. Zeolite and lime were able to capture chromium. Results from thermodynamic equilibrium simulations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}(s), CdAl{sub 2}O{sub 4}(s) and CdSiO{sub 3}(s) under the combustion conditions. Additional experiments are being carried out to provide more statistically representative results for better understanding the metal capture process.

  9. Basic studies of microstructure of combusting turbulent flows. Final technical report for period ending 30 Jun 90

    SciTech Connect

    Hussain, F.

    1991-03-04

    The authors goal is to develop a state-of-the-art measurement technique--Holographic Particle Displacement Velocimetry (HPV)--which can provide instantaneous velocities everywhere in the flow field simultaneously. Another goal is to use the power of supercomputers to simulate 3D flows with heat release to study the physics of combusting turbulent flows. Computations suffer from limited flow times and Reynolds number but can provide flow properties in more detail than possible by any existing experimental techniques. Moreover, numerical simulations can provide quantities almost impossible to measure experimentally. This article discusses efforts to develop the holographic particle displacement velocimetry system and results of direct numerical simulations of combusting flows.

  10. Floating-point coprocessor for fault detection and isolation in electronically controlled internal combustion engines. Final technical report

    SciTech Connect

    Yu, T.L.; Ribbens, W.B.

    1991-09-01

    The report details the design of a floating-point coprocessor intended for real-time fault detection in electronically controlled internal combustion engines. The fault detection strategies are based on dynamic models of various engine subsystems and require the use of state estimators. The coprocessor can be operated at a clock rate of 24 MHz, and is capable of operating up to sixteen state estimators in real time. The design is suitable for application to internal combustion engines used for vehicle propulsion or power generation, whether diesel or spark ignited.

  11. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect

    Sublette, K.L.

    1992-12-31

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  12. Standard technical specifications combustion engineering plants: Bases (Sections 2.0--3.3). Volume 2, Revision 1

    SciTech Connect

    1995-04-01

    This report documents the results of the combined effort of the NRC and the industry to produce improved Standard Technical Specifications (STS), Revision 1 for General Electric BWR/6 Plants. The changes reflected in Revision 1 resulted from the experience gained from license amendment applications to convert to these improved STS or to adopt partial improvements to existing technical specifications. This NUREG is the result of extensive public technical meetings and discussions between the Nuclear Regulatory Commission (NRC) staff and various nuclear power plant licensees, Nuclear Steam Supply System (NSSS) Owners Groups, NSSS vendors, and the Nuclear Energy Institute (NEI). The improved STS were developed based on the criteria in the Final Commission Policy Statement on Technical Specifications Improvements for Nuclear Power Reactors, dated July 22, 1993. The improved STS will be used as the basis for individual nuclear power plant licensees to develop improved plant-specific technical specifications. This report contains three volumes.

  13. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  14. Synthetic chars for studies of char combustion mechanisms: Quarterly technical progress report, March 1, 1987-May 31, 1987

    SciTech Connect

    Not Available

    1987-01-01

    The physical and chemical properties of synthetic char particles formed by atomization of a solution containing a polymer of furfuryl alcohol and pore formers in acetone were examined in detail. The plain polymer char shows only pores smaller than about 20 nm, while that containing carbon blace includes a small volume of pores as large as 0.5 microns. The former was typical of all but the chars containing carbon black or that formed from tannic acid which formed cenospheres. The surface areas of the glassy carbons increased dramatically during combustion. Combustion experiments were undertaken to map the increase of the surface area with burn-off. To examine the source of this large surface area, small angle X-ray scattering (SAXS) was used as a separate measurement of the porous microstructure. 3 figs., 3 tabs.

  15. Influence of sulfur in coals on char morphology and combustion. [Quarterly] technical report, December 1, 1991--February 29, 1992

    SciTech Connect

    Marsh, H.; Crelling, J.C.

    1992-08-01

    During coal pyrolysis, in applications such as in a utility boiler, sulfur which is present in the original coal is transferred to the resultant char, to be burnt (combusted) subsequently. The influence of sulfur on char reactivity to combustion gases is not well-documented and this study addresses that problem. Because coal is such a heterogeneous material several complexities have to be separated out. Hence, initial experiments make use of model organic compounds to synthesize char structures which resemble chars from coals. Catalytic impurities can be added to the model compounds to simulate the effects of mineral matter. The equipments needed fr these experimentations have all been commissioned, even though some presented some difficulties initially. The major carbonizations have been completed and initial surface area and reactivity measurements have been made. The microscopy is working very well.

  16. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect

    Chou, C.L.; Hackley, K.C.; Cao, J.; Frost, R.R.; Ruch, R.R.; Pan, W.P.; Upchurch, M.L.; Cao, H.B.; Shao, D.; Ho, H.H.

    1993-05-01

    The goals of this project is to investigate the behavior of sulfur and chlorine during pyrolysis and combustion of Illinois coals, the chemistry of boiler deposits and the process of ash formation, and remedial measures to reduce the sulfur and chlorine compounds in combustion gases. The chemistry of boiler deposits provides information about the behavior of sulfur, chlorine, and ash particles during coal combustion. We report results obtained during this quarter on mineralogical and chemical compositions of twelve samples of boiler deposits collected from superheater and reheater tubes of an Illinois power plant. Scanning electron microscopy shows microscopic calcium sulfate droplets on cenospheres. There is a considerable variation of chemical composition among the samples. While eight out of twelve samples consist predominantly of quartz, mullite, and glass; the remaining four contain an appreciable amount additional phases (calcium sulfate and alkali iron sulfate) . The chlorine content in the samples is determined by neutron activation analysis. one sample contains 37 ppM chlorine, and the chlorine concentration is below the detection limit in other eleven samples (<15--45 ppM), indicating that most of the chlorine in feed coal is lost during combustion. In a separate set of experiments, the effects of composite gases containing Hcl, SO{sub 2}, and HCl+SO{sub 2} on six metals are determined. Chromium-nickel steel and alloy show higher resistance to corrosion than carbon-manganese steels and chromium-molybdenum steels when metal coupons are exposed to hot gases at 600{degree}C for 24 hours.

  17. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  18. Combustion characteristics of fine-ground coal. Project 61052 quarterly technical report, June 1-August 31, 1981

    SciTech Connect

    1982-03-01

    This program consists of a research study to investigate the effect of coal particle size on the flame characteristics of pulverized coal. The purpose is to determine if fine grinding will allow replacement of oil by coal in some industrial applications. The Plant Engineering Development Department of General Motors Corporation (GM) and the Research and Development Staff of York-Shipley, Inc. (Y-S), a major boiler manufacturer, are assisting IGT in this effort. These companies have offered to donate time to the program as industrial consultants. Pulverized coal will be fired at about 2 million Btu/h (approximately 160 lb/h) in a special experimental furnace designed to collect data on the combustion and heat-transfer characteristics of flames. Combustion trials with No. 6 oil are also planned to allow for direct correlation with the coal combustion data. Some of the information to be obtained from this study will be a determination of how the flame heat release density, mass burning rate, flame temperatures, and heat-transfer characteristics change with fuel particle size (fineness of coal grinding). It will also be possible to directly compare these parameters from the various coal flames with comparable oil flames to determine the feasibility of substituting fine-ground pulverized coal flames for heavy-oil flames. Data will also be collected to allow for the correlation of the flue-gas pollutant emissions with the fuel characteristics. Progress included purchasing the major equipment for the coal milling system, coal selection, and preparation of the combustion facility.

  19. Influence of sulfur in coals on char morphology and combustion. Technical report, 1 September 1991--30 November 1991

    SciTech Connect

    Marsh, H.

    1991-12-31

    During coal carbonization (pyrolysis), as during the combustion process of pulverized coal in a combustor, not all of the sulfur is released. Significant proportions become pat of the structure of the resultant coke and char. The combustion process of the char within the flames of the combustor in influenced dominantly by char morphology. This, in turn, controls the accessibility of oxidizing gases to the surfaces of the carbonaceous substance of the char. Mineral matter content, its extent and state of distribution, also exerts an influence on char morphology created during pyrolysis/carbonization. This complexity of coal renders it a very difficult material to study, systematically, to distinguish and separate out the contributing factors which influence combustion characteristics. Therefore, in such circumstances, it is necessary to simplify the systems by making use of model chars/cokes/carbons which can be made progressively more complex, but in a controlled way. In this way complicating influence in chars from coals can be eliminated, so enabling specific influences to be studied independently. It is important to note that preliminary work by Marsh and Gryglewicz (1990) indicated that levels of sulfur of about 3 to 5 wt % can reduce reactivities by 10 to 25%. The overall purpose of the study is to provide meaningful kinetic data to establish, quantitatively, the influence of organically-bound sulfur on the reactivity of carbons, and to ascertain if gasification catalysts are effective in the preferential removal of sulfur from the chars.

  20. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the designs of the remaining major components of the integrated system were completed and the equipment was ordered. DOE has elected to modify the scope of the existing R&D program being conducted under this contract to include testing of a simulated TSCA incinerator ash. The modification will be in the form of an additional Task (Task 8 -- TSCA Ash Testing) to the original Statement of Work.

  1. Combustion of Illinois coals and chars with natural gas. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect

    Buckius, R.O.

    1991-12-31

    There are applications where the combined combustion of coal and natural gas offers potential advantages over the use of either coal or natural gas alone. For example, low volatile coals or low volatile chars derived from treatment or gasification processes can be of limited use during to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. In addition, natural gas provides a clean fuel source of fuel which, in cofiring situations, can extend the usefulness of coals with high sulfur content. The addition of natural gas may reduce SO{sub x} emission through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. In this research program, studies of combined coal and natural gas combustion will provide particle ignition, burnout rates and ash characterization, that will help clarify the effect of coal and natural gas and identify the controlling parameters and mechanisms.

  2. Byproducts to New Products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Alaska fisheries industry harvests over 2 million metric tons of wild fish annually, and after processing, over 1 million metric tons of fish byproducts are produced. This presentation will discuss current utilization of products made from fish byproducts in Alaska, and opportunities for enhanci...

  3. Development and testing of a commercial-scale coal-fired combustion system: Phase 2, Quarterly technical progress report No. 7, April 1, 1992--June 20, 1992

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1992-08-01

    The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for the commercial sector. The commercial-scale coal-water slurry (CWS) fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen Inc. under contract to the Department of Energy (DOE), Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr. will be scaled to operate at 2 to 5 million Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, SO{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems. This report documents the work carried out in the seventh quarter of the program. During this period, proof-of-concept tests aimed at eliminating ash accumulation in the combustor and boiler were conducted. A compressed air soot blower system was installed on the boiler and combustor design changes implemented to reduced direct impingement of slurry on the upper chamber partition. As part of this testing, emission performance goals using Kentucky Hazard Prince Mine coal water slurry were met. Also, during this period the automatic control system for the system was installed and operation with this system was implemented.

  4. Management of dry flue gas desulfurization by-products in underground mines

    SciTech Connect

    Sevim, H.

    1997-06-01

    Disposal of coal combustion by-products (CCBs) in an environmentally sound manner is a major issue facing the coal and utility industries in the US today. Disposal into abandoned sections of underground coal mines may overcome many of the surface disposal problems along with added benefits such as mitigation of subsidence and acid mine drainage. However, many of the abandoned underground coal mines are located far from power plants, requiring long distance hauling of by-products which will significantly contribute to the cost of disposal. For underground disposal to be economically competitive, the transportation and handling cost must be minimized. This requires careful selection of the system and optimal design for efficient operation. The materials handling and system economics research addresses these issues. Transportation and handling technologies for CCBs were investigated from technical, environmental and economic points of view. Five technologies were found promising: (1) Pneumatic Trucks, (2) Pressure Differential Rail Cars, (3) Collapsible Intermodal Containers, (4) Cylindrical Intermodal Tanks, and (5) Coal Hopper Cars with Automatic Retractable Tarping. The first two technologies are currently being utilized in transporting by-products from power plants to disposal sites, whereas the next three are either in development or in conceptualization phases. In this research project, engineering design and cost models were developed for the first four technologies. The engineering design models are in the form of spreadsheets and serve the purpose of determining efficient operating schedules and sizing of system components.

  5. Finial Scientific/Technical Report: Application of a Circulating Fluidized Bed Process for the Chemical Looping Combustion of Solid Fuel

    SciTech Connect

    Dr. Wei-Ping Pan; Dr. John T. Riley

    2005-10-10

    Chemical Looping Combustion is a novel combustion technology for the inherent separation of the greenhouse gas, CO{sub 2}. In 1983, Richter and Knoche proposed reversible combustion, which utilized both the oxidation and reduction of metal. Metal associated with its oxidized form as an oxygen carrier was circulated between two reactors--oxidizer and reducer. In the reducer, the solid oxygen carrier reacts with the fuel to produce CO{sub 2}, H{sub 2}O and elemental metal only. Pure CO{sub 2} will be obtained in the exit gas stream from the reducer after H{sub 2}O is condensed. The pure CO{sub 2} is ready for subsequent sequestration. In the oxidizer, the elemental metal reacts with air to form metal oxide and separate oxygen from nitrogen. Only nitrogen and some unused oxygen are emitted from the oxidizer. The advantage of CLC compared to normal combustion is that CO{sub 2} is not diluted with nitrogen but obtained in a relatively pure form without any energy needed for separation. In addition to the energy-free purification of CO{sub 2}, the CLC process also provides two other benefits. First, NO{sub x} formation can be largely eliminated. Secondly, the thermal efficiency of a CLC system is very high. Presently, the CLC process has only been used with natural gas. An oxygen carrier based on an energy balance analysis and thermodynamics analysis was selected. Copper (Cu) seems to be the best choice for the CLC system for solid fuels. From this project, the mechanisms of CuO reduction by solid fuels may be as follows: (1) If pyrolysis products of solid fuels are available, reduction of CuO could start at about 400 C or less. (2) If pyrolysis products of solid fuels are unavailable and the reduction temperature is lower, reduction of CuO could occur at an onset temperature of about 500 C, char gasification reactivity in CO{sub 2} was lower at lower temperatures. (3) If pyrolysis products of solid fuels are unavailable and the reduction temperature is higher than 750 C

  6. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1994, April 1994--June 1994

    SciTech Connect

    1995-09-01

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NOx burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters. Results are described.

  7. Spectroscopy and kinetics of combustion gases at high temperatures. Technical progress report, March 1, 1991--October 31, 1992

    SciTech Connect

    Hanson, R.K.; Bowman, C.T.

    1992-11-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption. methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of radical-molecule and radical-radical reactions relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the development of a unique intracavity frequency-doubling system for our cw laser which operates at wavelengths in the range 210--230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions of CH{sub 3} radicals.

  8. Influence of sulfur in coals on char morphology and combustion. [Quarterly] technical report, March 1, 1992--May 31, 1992

    SciTech Connect

    Marsh, H.; Crelling, J.C.

    1992-10-01

    During coal pyrolysis, in applications such as in a utility boiler, sulfur which is present in the original coal is transferred to the resultant char, to be burnt (combusted) subsequently. The effect of sulfur on char reactivity during combustion is poorly understood and this study addresses the problem. Due to the complex nature of coal, initial experiments make use of organic model compounds which can be related to chars from coals. This approach allows for clear identification of the important parameters which influence reactivity, in this instance namely; phenolic resin concentration, sulfur and/or iron content. The addition of iron serves to mimic the effect of catalytic mineral matter in coals. The experimental approach involves the preparation of model compounds and the study of their gasification behavior, including surface characterization by adsorption techniques and microscopy. The equipment necessary to this study has been commissioned and progress has been made. Previous results indicated that increasing phenolic resin (resol) content led to greater yields and that carbons with less than 20 wt.% resol were optically anisotropic, whereas carbons with higher concentrations of resol were isotropic. Due to the high volatility of thiophene it was decided to incorporate sulfur into the model carbon structure by the addition of elemental sulfur and dibenzothiophene sulfone.

  9. Coal combustion under conditions of blast furnace injection. Technical report, 1 December 1992--28 February 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-05-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This proposed study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. The Amanda furnace of Armco is the only one in North America currently using coal injection and is, therefore, the only full scale testing facility available. During this quarter complete petrographic analyses of all of the samples so far collected were completed.

  10. Co-combustion of coal and biomass in pulverized fuel and fluidized bed systems -- Activities and research in Europe

    SciTech Connect

    Hein, K.R.G.; Spliethoff, H.

    1999-07-01

    Biomass or sewage sludge utilized as additional fuel in coal combustion systems has consequences on combustion behavior, emissions, corrosion, and residual matter. Therefore, at the beginning of 1993 the European Union within the frame of the APAS program launched a project called ``Combined Combustion of Biomass/Sewage Sludge and Coal''. Within this project, the effects of burning sewage sludge and agricultural residuals such as straw and manure as well as specially grown energy plants in combination with coals of various ranks and origin were studied for the most common large-scale systems in order to establish both the optimum and the technically achievable process modifications necessary for co-combustion. Based on the experience of the APAS program, the objective of a further EU-co-funded project titled ``Operational problems, trace emissions and by-product management for industrial biomass co-combustion'' was to concentrate the research effort on the problem areas like slagging, fouling, corrosion, ash utilization and trace emissions for different co-combustion systems and carefully investigate technical options to avoid these negative effects. The solution of these technical problems is essential for a technically and economically feasible and environmentally advantageous co-combustion and will promote a widespread utilization of existing biomass resources. The project provides a comparison of different biomass co-utilization concepts with regard to fouling, slagging, corrosion, ash utilization and trace emissions. In detail the project incorporated biofuels like wood, wood pulp, bark, straw, wood matter from pressed olive stones and sewage sludge. The major operational problems like slagging, fouling and corrosion were investigated in both PF and CFB units of various scales. Finally the effect of co-combustion on the by-product management - handling, utilization and disposal are evaluated and compared with a pure coal or pure biomass combustion system

  11. Homogeneous chemistry of NO/sub x/ production and removal from fossil fuel combustion gases. Final technical report

    SciTech Connect

    Silver, J.A.; Gozewski, C.M.; Kolb, C.E.

    1980-11-01

    The reduction of NO/sub x/ emissions from stationary combustion sources by non-catalytic homogeneous chemical addition is a promising technique. Demonstrations in laboratory experiments and on a number of field scale combustors have shown that the addition of ammonia to the exhaust flow significantly reduces the NO concentrations in a narrow temperature range. This report summarizes the work performed to understand the detailed chemical mechanism which makes this reduction occur. A model describing the NH/sub i//NO/sub x/ chemical system is developed, and rates of the key reactions identified are measured in a high temperature fast flow reactor. Product channels for certain important reactions are also identified. The experimental results are incorporated into the computer code, and the model predictions are compared with laboratory and field test results. Possible additives other than ammonia are evaluated and discussed.

  12. Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly technical progress report, October 1--December 31, 1991

    SciTech Connect

    Not Available

    1991-12-31

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The major emphasis during this reporting period was finishing the conceptual design for the test facility and discussions on the potential expansion of the test facility. Results are discussed for the following subtasks of conceptual design: design bases; quasifier/combustor and hot stream design; balance of plant designs; and particulate collection.

  13. Chemical mechanistic approaches for the suppression of soot formation in the combustion of high energy density fuels. Final technical report

    SciTech Connect

    Santoro, R.J.

    1996-09-01

    Significant advantages can be gained by the use of high energy density fuels in volume limited applications. However, excessive soot formation that accompanies the combustion of these fuels presently limits their application. Fuel additive approaches prove attractive as they require minimal modifications to already existing equipment. In the present study, a variety of flame configurations were used to study the additive effects on soot formation. Through tests conducted on laminar diffusion flames carbon disulfide (CS2) and methanol (CH3OH) were found to be the most effective soot suppressants. Chemical interaction by either additive was found to far surpass the physical influences. However, the exact nature of the chemical action could not be established with the current set of experiments. Additionally, both of these additives were found to reduce soot formation in at least one high energy density fuel - quadricyclane (C7H8). To further validate this approach, studies were conducted using droplet flames and high-pressure spray flames.

  14. Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Harb, J.N.

    1996-05-01

    Progress during the tenth quarter of a three-year study of ash formation and deposition was made in several areas. One of the key contributions this quarter was the development of an algorithm to distinguish between ash particles that are associated with char particles (included) and ash particles which are excluded. This algorithm was used to determine the extent to which pyrite transformations are influenced by whether the pyrite grains are included or excluded. The results indicate that pyrite oxidation is slower for included pyrite grains. Replicate experiments were also performed for the Pittsburgh No. 8 coal (washed) under both staged and conventional conditions. An objective of these experiments was to validate the effect of staged combustion on the size distribution of ash particles as reported for the previous quarter. Analysis of the new samples and repeat analyses of previous samples showed no significant difference in the ash particle size for samples collected at stoichiometric ratios of 0.75 (before the stage) and 1.04. The number of points in the new analyses was considerably higher than in previous analyses, resulting in greater confidence. The similarity in the ash composition for samples collected under staged and conventional conditions was also verified this quarter with replicate samples and analyses. The net result is that staged combustion does not appear to have a significant impact on either ash size or composition for the Pittsburgh No. 8 coal. Finally, numerical simulations of the temperature distribution in the laboratory combustor were performed and evaluated. Also, a paper documenting the classification algorithm developed last quarter was presented at the March ACS meeting in New Orleans and published in the ACS Division of Fuel Chemistry Preprints.

  15. Utilizing by-products in agriculture and reducing metal uptake by crops

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Several million tons of industrial, municipal, and agricultural byproducts are produced annually in the United States (U.S.). Some of the byproducts that are being used in agriculture are coal combustion materials, drinking water treatment residual (DWTR), biosolids, animal manure, steel slag, and ...

  16. Coal combustion under conditions of blast furnace injection. [Quarterly] technical report, 1 December 1993--28 February 1994

    SciTech Connect

    Crelling, J.C.

    1994-06-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. Steel Company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals for such use. During this quarter a sample of the feed coal that is being used for injection into the No. 7 Blast Furnace of Inland Steel has been analyzed petrographically and compared to both the Herrin No. 6 coal and Armco feed coal. Additional characterization is underway and an advanced program of pyrolysis and reactivity testing has been initiated.

  17. Coal combustion under conditions of blast furnace injection. Final technical report, September 1, 1992--August 31, 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-12-31

    A potentially new use for Illinois coal is as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. During the first phase of this project a number of the objectives were realized, specifically: (1) a blast furnace sampling system was developed and used successfully to collect samples inside an active furnace; (2) two sets of blast furnace samples were collected and petrographic analysis showed that char derived from injected coal is entering the reduction zone of the furnace; (3) a coal/char sampling probe was designed and fabricated; (4) the completion of a program of reactivity experiments on the injected coal char, blast furnace coke and Herrin No. 6 char. The results of the reactivity experiments indicate that Herrin No. 6 coal is similar or even superior to coals now being used in blast furnace injection and that additional testing is warranted.

  18. Coal combustion under conditions of blast furnace injection. [Quarterly] technical report, 1 March 1993--31 May 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-09-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. The basic program is designed to determine the reactivity of both coal and its derived char under blast furnace conditions and to compare the results to similar properties of blast furnace coke. The results of the first two experiments in which coal char pyrolyzed in nitrogen at 1000{degrees}C in an EPR were reacted isothermally in air at 1000{degrees}C and 1200{degrees}C. The reactivity values of the same char in these two experiments were different by an order of magnitude. The char reactivity at 1000{degrees}C was 9.7 {times} 10{sup {minus}4} grams per minute while the reactivity. of the char at 1200{degrees}C was 1.6 {times} 10{sup {minus}3} grams per minute. These results suggest that the temperature of the blast air in the tuyere may be critical in achieving complete carbon burnout.

  19. Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Harb, J.N.

    1996-02-07

    Progress during the ninth quarter of a three-year study of ash formation and deposition was made in several areas. One of the key contributions this quarter was the development of an enhanced method for classification of CCSEM data. This classification algorithm permits grouping and comparison of particles previously labeled as ``unclassifiable.`` A second analytical advancement, also made this quarter, provides more detailed information on the distribution of minerals in the coal and the potential for coalescence. This new multiple analysis technique is also applicable to ash and will permit identification of heterogeneous ash particles. Additional analyses of ash samples were also performed and it was found that the firing of Pittsburgh {number_sign}8 under staged combustion conditions yields an ash with a significantly larger particle size distribution than that obtained under conventional firing conditions, but without a significant change in composition. the size difference was noted previously, but the new classification algorithm allowed a detailed comparison of all composition groups, including unclassifiable particles, in the ashes. A mechanistic explanation for this behavior has been developed and is provided in the report. Finally, a paper documenting the new classification algorithm has been prepared and is scheduled for presentation at the March ACS meeting in New Orleans.

  20. Integrated methods for production of clean char and its combustion properties. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect

    DeBarr, J.A.; Rostam-Abadi, M.; Gullett, B.K.; Benson, S.A.

    1993-09-01

    An integrated method consisting of physical coal cleaning, mild gasification (MG) and low temperature oxidation (LTO) is proposed to produce chars with SO{sub 2} emissions at least 50% lower than those of their parent coals. MG and char desulfurization studies are conducted in both a batch fluidized-bed reactor (FBR) and in a continuous rotary tube kiln (RTK). Combustion properties and ash deposition behaviors of desulfurized chars are determined at the US EPA in a 14 kill pilotscale combustor and at UNDEERC in a drop tube furnace (DTF). This project is cost-shared with the US EPA and the US DOE through UNDEERC. During the first year of this two year project, six coals from the IBC sample program (IBC-101, 102, 104, 105, 106 and 109) were studied. Under non-optimized conditions in the FBR, desulfurized chars were made with SO{sub 2} emissions 60--71% lower than the parent coals, depending on the coal. Chars prepared from four of the six coals had SO{sub 2} emissions less than 2.5 lbs SO{sub 2}/MMBtu. Under optimum conditions, SO{sub 2} emissions of one of the coals were reduced nearly 67%, from 4.60 to 1.49 lbs SO{sub 2}/MMBtu. MG reduced the chlorine content of one coal 93%.

  1. Investigation of a rotary valving system with variable valve timing for internal combustion engines: Final technical report

    SciTech Connect

    Cross, P.C.; Hansen, C.N.

    1994-11-18

    The objective of the program was to provide a functional demonstration of the Hansen Rotary Valving System with Variable Valve timing (HRVS/VVT), capable of throttleless inlet charge control, as an alternative to conventional poppet-valves for use in spark ignited internal combustion engines. The goal of this new technology is to secure benefits in fuel economy, broadened torque band, vibration reduction, and overhaul accessibility. Additionally, use of the variable valve timing capability to vary the effective compression ratio is expected to improve multi-fuel tolerance and efficiency. Efforts directed at the design of HRVS components proved to be far more extensive than had been anticipated, ultimately requiring that proof-trial design/development work be performed. Although both time and funds were exhausted before optical or ion-probe types of in-cylinder investigation could be undertaken, a great deal of laboratory data was acquired during the course of the design/development work. This laboratory data is the basis for the information presented in this Final Report.

  2. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1993-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase 3 research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing some of the system modification installation designs, completing industry funded testing, developing a surrogate TSCA ash composition, and completing the TSCA ash Test Plan. The installation designs will be used for the equipment modifications planned for the end of CY 93. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe, recyclable glass product. Some results from this testing are provided in Section 2.2.1. The surrogate TSCA ash composition was developed with input from various DOE laboratories and subcontractors. The surrogate ash consists of a mixture of MSW fly ash and bottom ash spiked with heavy metal contaminants. The levels of metal additives are sufficient to ascertain the partitioning of the contaminants between the glass and effluent flow streams. Details of the surrogate composition and the planned testing is provided in Section 4.2.2.

  3. Lightweight combustion residues-based structural materials for use in mines. Technical report, September 1--November 30, 1994

    SciTech Connect

    Chugh, Y.P.; Zhang, Y.; Ghosh, A.K.; Palmer, S.R.

    1994-12-31

    The overall goal of the project is to develop a 70--80 pcf, 2,500--3,000 psi-compressive-strength cellular concrete-type product from PCC fly ash, PCC bottom ash, and/or FBC spent bed ash alone or in suitable combination thereof. The developed combustion residue-based lightweight structural material will be used to replace wooden posts and crib members in underground mines. This report outlines the work completed in the first quarter of the project. The density gradient centrifuge (DGC) has been used to separate a power plant fly ash sample into fractions of different density. Each of the fly ash fractions obtained by DGC, an aliquot of the unseparated fly ash and an aliquot of a magnetic component of the fly ash, were digested in strong acids following the procedures outlined in ASTM 3050. Preliminary experiments have also been carried out to study the effect of mix proportions and curing regimes on the strength and density on the developed material. The DGC separation test reveals that most of the fly ash sample (approx. 90%) has a density above 1.9 g/cm{sup 3}. Indeed, nearly half of the sample has a density greater than 2.4 g/cm{sup 3}. Since only a very small amount of this fly ash has a reasonably low specific gravity, it appears unlikely at this time that enough low density material would be isolated to significantly enhance lightweight concrete production using fractionated material. A series of mixes have been made using fly ash, sodium silicate, cement, sand and water. Preliminary tests show that both cement and sodium silicate can be used as the binders to develop residues-based lightweight concrete. To date, compressive strength as high as 1,290 psi have been achieved with a density of 133 pcf, with 50 g of cement, 50 g of fly ash and 300 g of sand. Most of the work during the first quarter was done to understand the characteristics of the component materials.

  4. Fly ash facts for highway engineers. Fly ash use in: Concrete base flowable fill structural fill grout paving. Technical report

    SciTech Connect

    1995-08-01

    Coal fly ash is a coal combustion byproduct (CCB) that has numerous applications as a engineering material; the annual production of CCBs is nearly 82 million metric tons (90 million tons). Since the first edition of Fly Ash Facts for Highway Engineers in 1986, substantial information has been accumulated regarding the use of fly ash. The purpose of this document is to provide technical information about engineering applications to potential users of CCBs and to advance the use of CCBs in ways that are technically sound, commercially competitive, and environmentally safe.

  5. Computational modeling and experimental studies on NO{sub x} reduction under pulverized coal combustion conditions. Third quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Kumpaty, S.K.; Subramanian, K.

    1995-12-31

    An experimental plan outlining the first year`s activity was sent to Dr. Lori Gould, Project Officer/Contracting Officer`s Technical Representative on April 24, 1995. An approval was received with some questions on June 15, 1995. However, with some foresight of the director of the in-house combustion group of the PETC, Dr. Ekmann, a tentative hold-off on the purchase of the equipment was requested by the project officer on June 29, 1995. Enclosed with that request were some of Dr. Ekmann`s concerns. The research team spent the month of July in study of pertinent literature as well as in the preparation of the responses to Dr. Gould`s comments and Dr. Ekmann`s concerns. These responses included the choice of the reactor, reactor design, rate of gas heating, detailed test matrix and answers to host of other comments. Upon review of the above information submitted on July 24, 1995 by the Rust research team, the project officer called for a conference call on September 6, 1995 which involved the PI (Dr. Kumpaty), the research consultant (Mr. Subramanian), Dr. Gould and Dr. Ekmann. Dr. Ekmann insisted that further calculations be made on the rate of gas heating without taking radiation into account. Accordingly, calculations pertaining to the rate of gas heating based on convection were performed and submitted to Dr. Ekmann on September 13, 1995. This report contains the information emerged through the dialogue between the Rust College research team and the PETC represented by Dr. Gould and Dr. Ekmann during this quarter.

  6. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991

    SciTech Connect

    Not Available

    1992-02-03

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an Advanced Overfire Air (AOFA) system followed by Low NO{sub x} Burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  7. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Second quarter 1992

    SciTech Connect

    Not Available

    1992-08-24

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  8. RESEARCH PLAN FOR MICROBIAL PATHOGENS AND DISINFECTION BY-PRODUCTS IN DRINKING WATER

    EPA Science Inventory

    This research plan was developed to describe research needed to support EPA's development of drinking water regulations concerning disinfectants, disinfection by-products (DBPs) and microbial pathogens, focusing on key scientific and technical information needed. The research pl...

  9. Combustion apparatus and method of generating gas

    SciTech Connect

    Van Berkum, R.A.

    1988-05-31

    A combustion apparatus for converting carbon-based fuels in combustible gas is described comprising: a housing which defines an internal reaction chamber; fuel supply means for supplying fuel to the reaction chamber such that a fuel pile of generally constant configuration is maintained in the reaction chamber; a means for supporting the fuel pile, the fuel pile supporting means being disposed adjacent a bottom of the reaction chamber and permitting the flow of gas therethrough; a gas inlet disposed below the fuel pile supporting means for supplying an oxygen-carrying gas through the supporting means to react chemically with the fuel in the fuel pile to generate the combustible gas; ash removal for removing reaction by-products from adjacent the supporting means; a gas outlet for transporting the generated combustible gas from the housing; and, means for partially combusting the generated combustible gas to inhibit condensation of the vapors from the gas.

  10. Combustion noise

    NASA Technical Reports Server (NTRS)

    Strahle, W. C.

    1977-01-01

    A review of the subject of combustion generated noise is presented. Combustion noise is an important noise source in industrial furnaces and process heaters, turbopropulsion and gas turbine systems, flaring operations, Diesel engines, and rocket engines. The state-of-the-art in combustion noise importance, understanding, prediction and scaling is presented for these systems. The fundamentals and available theories of combustion noise are given. Controversies in the field are discussed and recommendations for future research are made.

  11. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect

    Sublette, K.L.

    1993-11-01

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  12. Liming efficacy and transport in soil of a dry PFBC by-product

    SciTech Connect

    Dick, W.A.

    1995-12-01

    The by-products of pressurized fluidized-bed combustion (PFBC) systems are mixtures of coal ash, anhydrite (CaSO{sub 4}), and unspent alkaline sorbent. Because PFBC by-products are alkaline and contain large concentrations of readily soluble bases (Ca and in some cases Mg) and other essential plant nutrients such as S and K, they have potential use as soil amendments, especially in acidic soils. PFBC by-products (particularly those with large Mg contents) may cause excessively high soluble salt concentrations when applied to soil. This could be detrimental to plant growth and might also impact the release of trace elements from the coal ash component of the by-product. In field experiments on three acidic soils, the liming effectiveness of a PFBC by-product, its effects on corn and alfalfa growth, and its impacts on crop, soil, and water quality were investigated.

  13. Advanced Gasification By-Product Utilization

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

    2006-08-31

    With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this

  14. Combustion characterization of the blend of plant coal and recovered coal fines. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect

    Singh, S.; Scaroni, A.; Miller, B.; Choudhry, V.

    1992-12-31

    The overall objective of this proposed research program was to determine the combustion characteristics of the blend derived from mixing a plant coal and recovered and clean coal fines from the pond. During this study, one plant coal and three blend samples were prepared as 100% plant coal, 90% plant coal/10% fines, 85% plant coal/15% fines, and 80% plant coal /20% fines with a particle size distribution of 70% passing through {minus}200 mesh size. The plant coal and recovered coal fines were obtained from the Randolph Preparation Plant of Peabody Coal Co., Marissa, IL. These samples` combustion behavior will be examined in two different furnaces at Penn State University, i.e., a down-fired furnace and a drop-tube furnace. The down-fired furnace was used mainly to measure the emissions and ash deposition study, while the drop tube furnace was used to determine burning profile, combustion efficiency, etc. The burning profile of the plant coal and the three blends was determined in a thermogravimetric analyzer. Results indicated slower burning of the blends due to low volatile matter and oxidized coal particles. Combustion emissions of these samples were determined in the down-fired combustor, while relative ignition temperatures were determined in the drop tube furnace. Chemical composition of ashes were analyzed to establish a correlation with their respective ash fusion temperatures. Overall study of these samples suggested that the blended samples had combustion properties similar to the original plant coal. In other words, flames were stable under identical firing rates of approximately 200,000 Btu`s/hr and 25% excess air. CO, NO{sub x}, and SO{sub x}, were similar to each other and within the experimental error. Combustion efficiency of 99{sup +}% was achievable. Ash chemical analysis of each sample revealed that slagging and fouling should not be different from each other.

  15. Combustion 2000

    SciTech Connect

    2000-06-30

    This report presents work carried out under contract DE-AC22-95PC95144 ''Combustion 2000 - Phase II.'' The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: {lg_bullet} thermal efficiency (HHV) {ge} 47% {lg_bullet} NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) {lg_bullet} coal providing {ge} 65% of heat input {lg_bullet} all solid wastes benign {lg_bullet} cost of electricity {le} 90% of present plants Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. Phase II, had as its initial objective the development of a complete design base for the construction and operation of a HIPPS prototype plant to be constructed in Phase III. As part of a descoping initiative, the Phase III program has been eliminated and work related to the commercial plant design has been ended. The rescoped program retained a program of engineering research and development focusing on high temperature heat exchangers, e.g. HITAF development (Task 2); a rescoped Task 6 that is pertinent to Vision 21 objectives and focuses on advanced cycle analysis and optimization, integration of gas turbines into complex cycles, and repowering designs; and preparation of the Phase II Technical Report (Task 8). This rescoped program deleted all subsystem testing (Tasks 3, 4, and 5) and the development of a site specific engineering design and test plan for the HIPPS prototype plant (Task 7). Work reported herein is from: {lg_bullet} Task 2.2.4 Pilot Scale Testing {lg_bullet} Task 2.2.5.2 Laboratory and Bench Scale Activities

  16. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Fourth quarter 1992

    SciTech Connect

    Not Available

    1992-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x } reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. Baseline, AOFA, and LNB without AOFA test segments have been completed. Analysis of the 94 days of LNB tong-term data collected show the full load NO{sub x} emission levels to be approximately 0.65 lb/MBtu. Flyash LOI values for the LNB configuration are approximately 8 percent at full load. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. Abbreviated diagnostic tests for the LNB+AOFA configuration indicate that at 500 MWe, NO{sub x} emissions are approximately 0.55 lb/MBtu with corresponding flyash LOI values of approximately 11 percent. For comparison, the long-term, full load, baseline NO{sub x} emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing of the LNB+AOFA configuration will be performed when the stack particulate emissions issue is resolved.

  17. Reduction of fuel side costs due to biomass co-combustion.

    PubMed

    Wils, Andrea; Calmano, Wolfgang; Dettmann, Peter; Kaltschmitt, Martin; Ecke, Holger

    2012-03-15

    The feasibility and influence of co-combustion of woody biomass on the fuel side costs is discussed for three hard coal power plants located in Berlin, Germany. Fuel side costs are defined as the costs resulting from flue gas cleaning and by-products. To have reliable data, co-firing tests were conducted in two power plants (i.e., slag tap furnace and circulating fluidising bed combustion). The amount of wood which was co-fired varied at levels below 11% of the fuel heat input. Wood chips originating from landscape management were used. The analyses show that co-combustion of woody biomass can lower the fuel side costs and that the co-combustion at a level below 10% of the thermal capacity is technically feasible without major problems. Furthermore, a flexible spreadsheet tool was developed for the calculation of fuel side costs and suggestions for operational improvements were made. For example, the adaptation of the Ca/S ratio (mass ratio of calcium in limestone to sulphur in the fuel) in one plant could reduce the fuel side costs up to 135 k€ yr(-1) (0.09 €M Wh(-1)).

  18. Coal Combustion Products Extension Program

    SciTech Connect

    Tarunjit S. Butalia; William E. Wolfe

    2006-01-11

    This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to 40% by 2010, the CCP Extension Program be

  19. Device for improved combustion

    SciTech Connect

    Polomchak, R.W.; Yacko, M.

    1988-03-08

    A device for improved combustion is described comprising: a tubular housing member having a first end and a second end, the first and second ends each having a circular opening therethrough; a combustion chamber disposed about the second end of the-tubular-housing member; a first conduit member extending from the first end of the tubular housing member and in fluid communication with the circular opening in the first end of the tubular housing member so as to allow the passage of air therethrough; a second conduit member axially disposed within the first conduit member and extending through the first conduit member and through the tubular housing member to the circular opening the second end of the tubular housing member so as to allow the passage of fuel therethrough; means for effecting turbulence in the air passing through the tubular housing member; means for effecting turbulence in the fuel passing through the second conduit member; means for intermixing and emitting the turbulent air and the fuel in a mushroom shaped configuration with the turbulent air surrounding the mushroom shaped configuration so as to substantially eliminate noxious waste gases as by-product of combustion of the air and fuel mixture.

  20. Kinetic study of NO/sub x/ formation and removal processes in combustion streams. First quarterly technical progress report, June 6, 1982-August 31, 1982

    SciTech Connect

    Silver, J.A.

    1982-09-01

    The production of nitric oxide from combustion of hydrocarbon fuels with air has been recognized to be a serious potential health hazard. In dirtier fuels such as coal and oil shale, a major source of nitric oxide occurs due to the reactions of small hydrocarbon fragments with the nitrogen in the air. These reactions take place in the rich part of the combustion flame and are termed the Prompt-NO mechanism. However, the detailed reaction sequence and rates of these reactions are not well known. The purpose of this work is to directly measure key reaction rates of the CH radical and subsequent HCN reactions which form the basis for Prompt-NO production. During this initial Quarter, production and detection methods for CH were devised and tested, and preliminary rate measurements made for the reaction of CH + N/sub 2/ at 300 K.

  1. Computational Combustion

    SciTech Connect

    Westbrook, C K; Mizobuchi, Y; Poinsot, T J; Smith, P J; Warnatz, J

    2004-08-26

    Progress in the field of computational combustion over the past 50 years is reviewed. Particular attention is given to those classes of models that are common to most system modeling efforts, including fluid dynamics, chemical kinetics, liquid sprays, and turbulent flame models. The developments in combustion modeling are placed into the time-dependent context of the accompanying exponential growth in computer capabilities and Moore's Law. Superimposed on this steady growth, the occasional sudden advances in modeling capabilities are identified and their impacts are discussed. Integration of submodels into system models for spark ignition, diesel and homogeneous charge, compression ignition engines, surface and catalytic combustion, pulse combustion, and detonations are described. Finally, the current state of combustion modeling is illustrated by descriptions of a very large jet lifted 3D turbulent hydrogen flame with direct numerical simulation and 3D large eddy simulations of practical gas burner combustion devices.

  2. Combustion engineering issues for solid fuel systems

    SciTech Connect

    Bruce Miller; David Tillman

    2008-05-15

    The book combines modeling, policy/regulation and fuel properties with cutting edge breakthroughs in solid fuel combustion for electricity generation and industrial applications. This book provides real-life experiences and tips for addressing the various technical, operational and regulatory issues that are associated with the use of fuels. Contents are: Introduction; Coal Characteristics; Characteristics of Alternative Fuels; Characteristics and Behavior of Inorganic Constituents; Fuel Blending for Combustion Management; Fuel Preparation; Conventional Firing Systems; Fluidized-Bed Firing Systems; Post-Combustion Emissions Control; Some Computer Applications for Combustion Engineering with Solid Fuels; Gasification; Policy Considerations for Combustion Engineering.

  3. Basic combustion and pollutant-formation processes for pulverized fuels. Quarterly technical progress report No. 4, 1 July 1981-30 September 1981

    SciTech Connect

    Germane, G.J.; Smoot, L.D.

    1981-10-15

    This contract study of basic combustion and pollutant formation processes for pulverized solid fossil fuels includes coal-water mixtures and chars derived from coal pyrolysis, liquefaction or gasification processes. The factors that affect the physical properties of coal-water mixtures (CWM) have been identified and characterization tests initiated to determine how these variables (e.g., solids loading, particle size, particle size distribution, additives) affect the coal slurries. A bench-scale apparatus consisting of a pressure vessel and an atomizing nozzle was designed and is being fabricated. This apparatus will assist in the development of handling and atomization techniques for the combustion tests. It will also aid in comparing viscosities of slurries of different solids loadings and coal types. Chars were obtained for characterization tests. A series of potential tests to characterize the chars was identified. Grading and sizing of the chars was begun as well as elemental analysis. Samples of the chars were sent to Phillips for CO/sub 2/ reactivity tests to be performed. Coding for incorporation of swirling flows into the two-dimensional coal combustion model (PCGC-2) was completed. Debugging was initiated and sample computations are performed for a gaseous, isothermal system for low swirl numbers. Convergence problems were encountered when attempts were made to complete runs at higher swirl numbers.

  4. Combustion characterization of coal fines recovered from the handling plant. Quarterly technical progress report No. 2, January 1, 1995--March 31, 1995

    SciTech Connect

    Houshang, Masudi

    1995-04-01

    The main goal of this research project is to evaluate the combustion characteristics of the slurry fuels prepared from the recovered coal fines and plant coal fines. A specific study will include the combustion behavior, flame stability, ash behavior and emissions of SO{sub x}, NO{sub x} and particulate in a well insulated laboratory scale furnace in which the residence time and temperature history of the burning particles are similar to that of utility boiler furnace at 750,000 Btu/hr input and 20% excess air. The slurry fuel will be prepared at 60% solid to match the generic slurry properties, i.e., viscosity less than 500 cp, 100% of particles passing through 100 mesh and 80-90% of solid particles passing through 200 mesh. The coal blend is prepared using a mix of 15% effluent recovered coal and 85% plant fines. Combustion characteristics of the slurry fuels is determined at three different firing rates 750K, 625K, 500K Btu/hr. Finally a comparison of the results is made to determine the advantages of coal water slurry fuel over the plant coal blended form.

  5. Spray combustion stability project

    NASA Technical Reports Server (NTRS)

    Jeng, San-Mou; Litchford, Ron J.

    1990-01-01

    This report summarizes research activity on the Spray Combustion Stability Project, characterizes accomplishments and current status, and discusses projected future work. The purpose is to provide a concise conceptual overview of the research effort so the reader can quickly assimilate the gist of the research results and place them within the context of their potential impact on liquid rocket engine design technology. Therefore, this report does not elaborate on many of the detailed technical aspects of the research program.

  6. Simulating Combustion

    NASA Astrophysics Data System (ADS)

    Merker, G.; Schwarz, C.; Stiesch, G.; Otto, F.

    The content spans from simple thermodynamics of the combustion engine to complex models for the description of the air/fuel mixture, ignition, combustion and pollutant formation considering the engine periphery of petrol and diesel engines. Thus the emphasis of the book is on the simulation models and how they are applicable for the development of modern combustion engines. Computers can be used as the engineers testbench following the rules and recommendations described here.

  7. UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS

    SciTech Connect

    A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

    1998-10-01

    Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

  8. 10 CFR 962.3 - Byproduct material.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 4 2013-01-01 2013-01-01 false Byproduct material. 962.3 Section 962.3 Energy DEPARTMENT OF ENERGY BYPRODUCT MATERIAL § 962.3 Byproduct material. (a) For purposes of this part, the term byproduct material means any radioactive material (except special nuclear material) yielded in or...

  9. 10 CFR 962.3 - Byproduct material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Byproduct material. 962.3 Section 962.3 Energy DEPARTMENT OF ENERGY BYPRODUCT MATERIAL § 962.3 Byproduct material. (a) For purposes of this part, the term byproduct material means any radioactive material (except special nuclear material) yielded in or...

  10. Buffered flue gas scrubbing system using adipic acid by-product stream

    SciTech Connect

    Lester, J.H. Jr.; Danly, D.E.

    1983-12-27

    A by-product stream from the production of adipic acid from cyclohexane, containing glutaric acid, succinic acid and adipic acid, is employed as a buffer in lime or limestone flue gas scrubbing for the removal of sulfur dioxide from combustion gases.

  11. Combustion 2000

    SciTech Connect

    1999-12-31

    This report presents work carried out under contract DE-AC22-95PC95144 ''Combustion 2000 - Phase II.'' The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: {lg_bullet} thermal efficiency (HHV) {ge} 47% {lg_bullet} NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) {lg_bullet} coal providing {ge} 65% of heat input {lg_bullet} all solid wastes benign {lg_bullet} cost of electricity {le} 90% of present plants Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. Phase II, had as its initial objective the development of a complete design base for the construction and operation of a HIPPS prototype plant to be constructed in Phase III. As part of a descoping initiative, the Phase III program has been eliminated and work related to the commercial plant design has been ended. The rescoped program retained a program of engineering research and development focusing on high temperature heat exchangers, e.g. HITAF development (Task 2); a rescoped Task 6 that is pertinent to Vision 21 objectives and focuses on advanced cycle analysis and optimization, integration of gas turbines into complex cycles, and repowering designs; and preparation of the Phase II Technical Report (Task 8). This rescoped program deleted all subsystem testing (Tasks 3, 4, and 5) and the development of a site-specific engineering design and test plan for the HIPPS prototype plant (Task 7). Work reported herein is from: {lg_bullet} Task 2.2.4 Pilot Scale Testing {lg_bullet} Task 2.2.5.2 Laboratory and Bench Scale Activities

  12. 10 CFR 35.1000 - Other medical uses of byproduct material or radiation from byproduct material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Other medical uses of byproduct material or radiation from... MATERIAL Other Medical Uses of Byproduct Material or Radiation From Byproduct Material § 35.1000 Other medical uses of byproduct material or radiation from byproduct material. A licensee may use...

  13. 10 CFR 35.1000 - Other medical uses of byproduct material or radiation from byproduct material.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 1 2012-01-01 2012-01-01 false Other medical uses of byproduct material or radiation from... MATERIAL Other Medical Uses of Byproduct Material or Radiation From Byproduct Material § 35.1000 Other medical uses of byproduct material or radiation from byproduct material. A licensee may use...

  14. 10 CFR 35.1000 - Other medical uses of byproduct material or radiation from byproduct material.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 1 2014-01-01 2014-01-01 false Other medical uses of byproduct material or radiation from... MATERIAL Other Medical Uses of Byproduct Material or Radiation From Byproduct Material § 35.1000 Other medical uses of byproduct material or radiation from byproduct material. A licensee may use...

  15. 10 CFR 35.1000 - Other medical uses of byproduct material or radiation from byproduct material.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 1 2011-01-01 2011-01-01 false Other medical uses of byproduct material or radiation from... MATERIAL Other Medical Uses of Byproduct Material or Radiation From Byproduct Material § 35.1000 Other medical uses of byproduct material or radiation from byproduct material. A licensee may use...

  16. 10 CFR 35.1000 - Other medical uses of byproduct material or radiation from byproduct material.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 1 2013-01-01 2013-01-01 false Other medical uses of byproduct material or radiation from... MATERIAL Other Medical Uses of Byproduct Material or Radiation From Byproduct Material § 35.1000 Other medical uses of byproduct material or radiation from byproduct material. A licensee may use...

  17. Chemical production from industrial by-product gases: Final report

    SciTech Connect

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  18. Combustion-derived substances in deep basins of Puget Sound: historical inputs from fossil fuel and biomass combustion.

    PubMed

    Kuo, Li-Jung; Louchouarn, Patrick; Herbert, Bruce E; Brandenberger, Jill M; Wade, Terry L; Crecelius, Eric

    2011-04-01

    Reconstructions of 250 years historical inputs of two distinct types of black carbon (soot/graphitic black carbon (GBC) and char-BC) were conducted on sediment cores from two basins of the Puget Sound, WA. Signatures of polycyclic aromatic hydrocarbons (PAHs) were also used to support the historical reconstructions of BC to this system. Down-core maxima in GBC and combustion-derived PAHs occurred in the 1940s in the cores from the Puget Sound Main Basin, whereas in Hood Canal such peak was observed in the 1970s, showing basin-specific differences in inputs of combustion byproducts. This system showed relatively higher inputs from softwood combustion than the northeastern U.S. The historical variations in char-BC concentrations were consistent with shifts in climate indices, suggesting an influence of climate oscillations on wildfire events. Environmental loading of combustion byproducts thus appears as a complex function of urbanization, fuel usage, combustion technology, environmental policies, and climate conditions.

  19. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect

    Chou, C.L.; Hackley, K.C.; Cao, J.; Donnals, G.L.; Ruch, R.R.; Pan, W.P.; Shao, D.

    1992-12-31

    Using the pyrolysis-QGA system, samples of coal were heated from ambient temperature to 800{degrees}C at a rate of 20{degrees}C/min in the pyrolysis chamber under a nitrogen atmosphere. The volatile products were carried with the nitrogen flow to the combustion chamber which was maintained at 850{degrees}C under a constant flow of oxygen. For Illinois coals (IBC-101, 103, and -109), HCl was the only chlorine species identified by the QGA. The HCl release profiles for the coals showed a broad peak between 250{degrees}C and 600{degrees}C with a maximum at 445{degrees}C. Neutron activation analysis of pyrolysis residues showed that 98 percent of the chlorine in raw coal was volatilized. Thus, it may be inferred that the chlorine in Illinois coals is released rapidly as HCl, not as sodium chloride (NaCl), during combustion in a utility/industrial boiler. In contrast to chlorine, the sulfur release profile for IBC-109 showed three peaks: the first sulfur peak at about 350{degrees}C was probably derived from elemental sulfur, the main peak at 475{degrees}C corresponded to the release of organic sulfur, and the third peak at 600{degrees}C resulted from the decomposition of pyrite. The low-temperature peak was absent for fresh samples. Sulfur dioxide (SO{sub 2}) was the major sulfur species in combustion gases under an oxidizing condition; additional gaseous sulfur species (COS and H{sub 2}S) were observed when the atmosphere was changed to a reducing condition.

  20. The development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  1. Basic combustion and pollutant-formation processes for pulverized fuels. Quarterly technical progress report No. 1, 1 October 1980-31 December 1980

    SciTech Connect

    Germane, Geoffery J.; Smoot, L. Douglas

    1981-01-15

    A study of basic combustion and pollutant formation processes for pulverized solid fossil fuels has been initiated. The solid fossil fuels under consideration for this research include such solid fuels as non-bituminous coal types, solvent refined coal, combustion char, petroleum coke, oil shale and tar sand. The potential industrial application of pulverized fuels other than coal provides some promise for relief from present and future conventional fuel shortages. Utilization problems with these fuels such as flame stability, fuel handling, pollutant emission and ash and slag formation in large-scale furnaces may be fundamentally addressed in laboratory reactors using properly scaled operating variables. An extensive literature search was begun to assess current knowledge relative to utilization of these fuels. This review will provide a basis for selection of three solid fuels for testing. Pertinent information from industrial contacts will also be used in the fuel selection. The criteria to be used in the selection of these fuels include availability for economic industrial use, adaptability, grindability, flame stability, entrainability, uniformity, applicability to direct firing with air, solidity with heating, availability to the BYU Combustion Laboratory, cost, other physical characteristics affecting their use, industrial input and recommendations, and DOE approval. The existing laboratory coal combustor at BYU will be modified to provide flexibility for a potentially wide range of operating characteristics with the selected solid fuels. A computer system has been identified for interface both to the reactor for data acquisition and control of operating variables and to the main research computer for final data reduction and display.

  2. ADVANCED GASIFICATION BY-PRODUCT UTILIZATION

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; M. Mercedes Maroto-Valer; Zhe Lu; Harold Schobert

    2005-04-01

    The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2003 to August 31, 2004. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  3. Development and testing of industrial scale, coal-fired combustion system, Phase 3. Seventeenth quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Zauderer, B.

    1996-04-07

    In the first quarter of calendar year 1996, 9 days of combust-boiler tests were performed. Between these tests, modifications and improvements that were indicated by these tests were implemented. In January and early February, the modifications and installations indicated by the 6 days of testing in December 1995 were implemented. This was followed by 6 additional consecutive test days in mid- February. This was in turn followed by additional modifications, followed by a series of 3 one day, coal fired tests at end of March. These latter tests were the first ones in which slagging conditions were achieved in the combustor. The maximum thermal input was 13 MMBtu/hr, which equals two-thirds of the rated boiler heat input. The measured thermal, combustion, and slagging performance achieved in the combustor was superior to that achieved in the final series of tests conducted in Williamsport in 1993. The combustor-boiler facility is now ready for implementation of the task 5 site demonstration.

  4. Development and Testing of Industrial Scale, Coal Fired Combustion System, Phase 3: Twentieth quarterly technical progress report, October 1-December 31, 1996

    SciTech Connect

    Zauderer, Bert

    1997-02-27

    In the fourth quarter of calendar year 1996, 15 days of combust boiler tests were performed, including 10 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of December in the task 5 effort to 57, increased to 65 as of the date of this Report, 1/27/97. This compares with a total of 63 test days needed to complete the task 5 test effort, and it completes the number of tests days required to meet the task 5 project plan. The key project objectives of the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Work in the next quarter will focus on even greater reductions in environmental emissions. Also tests are planned with coals other than the Eastern U.S. bituminous coals tested in this project. For example, it is planned to tests Indian coals whose ash concentration is in the 40% range.

  5. Chemistry, mineralogy and artificial weathering of PFBC by-products

    SciTech Connect

    Fowler, R.K.; Soto, U.I.; Bigham, J.M.

    1995-12-31

    Chemical and mineralogical analyses were performed on spent bed residues and cyclone ashes acquired from the TIDD pressurized fluidized bed combustion (PFBC) demonstration plant operated by American Electric Power in Brilliant, OH. The cyclone ashes were composed of fly ash, dolomite, anhydrite, periclase, and calcite in decreasing order of abundance. By comparison, bed residues contained less dolomite and fly ash but more anhydrite, calcite and periclase. All samples were highly alkaline with past pH values ranging from 9.9 to 12.3. The major element chemistry of the by-products was dominated by Ca, Mg, S, Fe, Al and Si. All materials met the criteria for ceiling concentrations of Cd, Cr, Cu, Pb, Mo, Ni, Se and Zn as defined for land application of sewage sludges. As exceeded the ceiling level in one of six samples. An artificial weathering study was conducted to evaluate the impact of PFBC by-products on water quality in mined land reclamation. The study was performed using two mine spoils mixed with cyclone ash at rates of 0, 10, 20 and 40 wt % by-product. The composition of leachates from the mixtures was mostly a function of rate of by-product application and equilibration time. In general, the addition of PFBC by-product increased pH, conductivity, and the concentrations of dissolved Ca, K, Mg, Mo, Na, S, and Sr whereas the concentrations of Al, Fe, and Mn decreased. Six metals (Ag, As, Ba, Cd, Cr, and Pb) were below concentration levels defined for drinking water standards. No significant alteration of native spoil minerals was observed over the course of the study; however, hydration/precipitation reactions resulted in the rapid formation of gypsum. No evidence of ettringite crystallization was available after 132 days of periodic leaching.

  6. Develop an alternate energy source thru use of a poultry litter pelletizer and a combustion chamber to heat poultry houses. Final technical project report

    SciTech Connect

    Gonthier, M.W.; Mercier, R.A.

    1984-01-01

    Poultry litter in a pelletized form is an acceptable energy source. The machinery and mechanism to process the litter, the combustion chamber with supporting controls and equipment, is practical and marketable. The controlling factor is economic demand. With the price of fossil fuel diminishing and with the labor cost and energy cost to process the litter, it is not economically desirable to pay the equivalent of $1.50 per gallon. It would not be economically competitive with present heating power plants because of its high initial cost, the cost of labor to maintain a pellet supply and the undesirable feature of solid fuel versus liquid fuel. This system could not be fully competitive with present systems until fuel pric

  7. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, August 15, 1993--February 15, 1994

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Poe, R.L.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. The first demonstrations been completed and the combustion performance of the burner that was provided with the boiler has been determined to be unacceptable. Consequently, the first demonstration has been concluded at 500 hours. The second demonstration will be conducted after a proven CWSF-designed burner is installed on the boiler. During this reporting period, the construction of the fuel preparation facility that will contain the CWSF circuit (as well as a dry, micronized coal circuit) was completed. Proposals from potential suppliers of the flue gas treatment systems were reviewed by Penn State and DOE.

  8. SOLVENT FIRE BY-PRODUCTS

    SciTech Connect

    Walker, D; Samuel Fink, S

    2006-05-22

    Southwest Research Institute (SwRI) conducted a burn test of the Caustic-Side Solvent Extraction (CSSX) solvent to determine the combustion products. The testing showed hydrogen fluoride gas is not a combustion product from a solvent fire when up to 70% of the solvent is consumed. The absence of HF in the combustion gases may reflect concentration of the modifier containing the fluoride groups in the unburned portion. SwRI reported results for other gases (CO, HCN, NOx, formaldehyde, and hydrocarbons). The results, with other supporting information, can be used for evaluating the consequences of a facility fire involving the CSSX solvent inventory.

  9. 75 FR 10739 - Combustible Dust

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-09

    ... and technical information. Contact Mat Chibbaro, P.E., Fire Protection Engineer, Office of Safety... finely divided form. Materials that may form combustible dust include, but are not limited to, wood, coal... handling, food manufacturing, wood product manufacturing, chemical manufacturing, textile...

  10. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-06-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and missions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects test; and full-scale combustion tests.

  11. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Third quarterly technical progress report

    SciTech Connect

    Not Available

    1993-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. Baseline, AOFA, LNB, and LNB plus AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO{sub x} emission levels to be approximately 0.65 lb/MBtu with fly ash LOI values of approximately 8 percent. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. For comparison, the long-term full-load, baseline NO{sub x} emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing in the LNB+AOFA configuration indicate that at full-load, NO{sub x} emissions and fly ash LOI are near 0.40 lb/MBtu and 8 percent, respectively. However, it is believed that a substantial portion of the incremental change in NO{sub x} emissions between the LNB and LNB+AOFA configurations is the result of additional burner tuning and other operational adjustments and is not the result of the AOFA system. During this quarter, LNB+AOFA testing was concluded. Testing performed during this quarter included long-term and verification testing in the LNB+AOFA configuration.

  12. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect

    1994-10-01

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  13. JANNAF 37th Combustion Subcommittee Meeting. Volume 1

    NASA Technical Reports Server (NTRS)

    Fry, Ronald S. (Editor); Gannaway, Mary T. (Editor)

    2000-01-01

    This volume, the first of two volumes is a compilation of 59 unclassified/unlimited-distribution technical papers presented at the Joint Army-Navy-NASA-Air Force (JANNAF) 37th Combustion Subcommittee (CS) meeting held jointly with the 25th Airbreathing Propulsion Subcommittee (APS), 19th Propulsion Systems Hazards Subcommittee (PSHS), and 1st Modeling and Simulation Subcommittee (MSS) meetings. The meeting was held 13-17 November 2000 at the Naval Postgraduate School and Hyatt Regency Hotel, Monterey, California. Topics covered at the CS meeting include: a keynote address on the Future Combat Systems, and review of a new JANNAF Modeling and Simulation Subcommittee, and technical papers on gun propellant burning rate, gun tube erosion, advanced gun propulsion concepts, ETC guns, novel gun propellants; liquid, hybrid and novel propellant combustion; solid propellant combustion kinetics, GAP, ADN and RDX combustion, sandwich combustion, metal combustion, combustion instability, and motor combustion instability.

  14. Bioinspiration and Biomimicry: Possibilities for Cotton Byproducts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The byproducts from cotton gins have commonly been referred to as cotton gin trash or cotton gin waste primarily because the lint and seed were the main focus of the operation and the byproducts were a financial liability that did not have a consistent market. Even though the byproducts were called ...

  15. Development and testing of industrial scale, coal-fired combustion system, Phase 3. Nineteenth quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect

    Zauderer, B.

    1996-10-27

    In the third quarter of calendar year 1996, 13 days of combust-boiler tests were performed, including 3 days of tests on a parallel DOE sponsored project on sulfur retention in a stagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of September in the task 5 effort to 41, increased to 46 as of the date of this Report, 10/27/96. This compares with a total of 63 test days needed to complete the task 5 test effort. As reported previously, the only major modification to the Williamsport combustor has been the addition of a new downstream section, which lengthens the combustor and improves the combustor-boiler interface. The original combustor section, which includes the fuel, air, and cooling water delivery systems remained basically unchanged. Only the refractory liner was completely replaced, a task which occurs on an annual basis in all commercial stagging utility combustors. Therefore, this combustor has been operated since 1988 without replacement.

  16. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fourth quarterly technical progress report, October 1, 1992--December 31, 1992

    SciTech Connect

    Zauderer, B.

    1993-02-15

    A major part of the work in this quarter was on the combustor tests in task 2. Three of the six planned tests in this task were completed. The first two were parametric tests of nominal one shift, (8 hour) duration on coal. Due to failure of the UV detector in the first test only several hours of coal fired operation were completed. In the second test, coal fired operation continued for the planned one shift until the 4 ton coal bin was empty. After reviewing this work with DOE, it was decided to focus the remaining test on longer duration operation with each test at one optimum condition. The third test was planned for two shift coal fired operation. Due to a problem with the pilot gas ignitor, combustion was delayed by 5 hours from 7 AM to Noon. As a result coal fired operation was limited to one shift between 3 PM and 11 PM. Throughout this period the combustor remained at one fixed condition with the use of computer control. Results for these three tests are presented in this report. Most of the work on the task 4 design and cost of a 20 MW combined gas-steam turbine power plant using the air cooled combustor was completed in the previous quarter. The results obtained by the A/E subcontractor on the installation desip and cost were evaluated in the present quarter and they are summarized in this report.

  17. Development and testing of industrial scale, coal fired combustion system, Phase 3. Sixteenth quarterly technical progress report, October 1--December 31, 1995

    SciTech Connect

    Zauderer, B.

    1996-01-03

    In the fourth quarter of calendar year 1995 the installation and checkout of the 20 MMBtu/hr combustor and auxiliary equipment in Philadelphia was completed. The task 5, Site Demonstration Testing, combustor-boiler tests on gas, oil, and coal were initiated. The task 5 effort involves testing the combustor over extended periods under conditions that fully simulate commercial operation and that meet the combustion and environmental specifications for this project. To meet this project objective within the current work scope requires up to 500 hours of testing. The focus of this testing will be on the component and environmental performance of combustor, boiler, coal preparation and feeding, and the stack gas equipment. The facility can be converted to a 500 kW power plant by the addition of a steam turbine, condenser, and cooling tower. However, this added effort is beyond the current work scope and its implementation will depend on recovering the added costs by placing the steam production from the boiler to beneficial use. During the present quarterly reporting period, all the components needed to implement the initial 100 hours of testing under task 5 were installed at the test site, and checkout of this equipment was performed. Since the present installation contained substantial improvements and simplifications to all sub-systems that had been used in the Williamsport facility, each component and sub-system had to be tested individually.

  18. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fifth quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Zauderer, B.

    1993-05-17

    In the present reporting period, the first quarter of calendar year 1993, the effort was divided between Task 2. ``Pre Systems Tests`` and Task 4 ``Economics and Commercialization Plan.`` A major part of the task 2 effort was devoted converting the nozzle from adiabatic to air cooted operation. This conversion will allow immediate implementation of the longer duration task 3.2 tests after the completion of the task 2 tests. Therefore, a significant pan of the exit nozzle conversion effort is also part of task 3.1, ``Combustor Refurbishment.`` In task 1 the only activity remaining is to receive the results of the BYU combustion modeling. The results are anticipated this Spring. One of the three remaining tests in task 2 was implemented in late January under freezing weather and snow conditions. Ice plugged the coal feed lines and stack scrubber water outlet and ice jammed and damaged the coal metering auger. While these lines were thawed, the combustor was fired with oil. The coal used in this test contained fine fibrous tramp material which passed through the two tramp material retaining screens and eventually plugged several of the coal feed lines to the combustor. This cut the planned coal feed rate in half. As a result it was decided for the next test to increase the number of coal injection ports by 50% in order to provide excess capacity in the pneumatic feed feed. This will allow continued operation even in the presence of fine tramp material in the coal.

  19. Superclean coal-water slurry combustion testing in an oil-fired boiler. Quarterly technical progress report, November 15, 1989--February 15, 1990

    SciTech Connect

    Miller, B.G.; Walsh, P.M.; Elston, J.T.; Scaroni, A.W.

    1990-04-06

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the US Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of demonstrating the capability of effectively firing SCCWS in industrial boilers designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3% ash and 0.9% sulfur) can effectively be burned in oil-designed industrial boilers without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of three phases: (1) design, permitting, and test planning, (2) construction and start up, and (3) operations and disposition. The boiler testing will determine if the SCCWS combustion characteristics, heat release rate, slagging and fouling factors, erosion and corrosion limits, and fuel transport, storage, and handling can be accommodated in an oil-designed boiler. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting and operating boilers will be identified to assess the viability of future oil-to-coal retrofits. Progress for this quarter is summarized.

  20. Development and testing of a commercial scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 8, July 1, 1992--September 30, 1992

    SciTech Connect

    Litka, A.; Breault, R.

    1992-10-23

    This report summarizes the results of work performed in the development and proof-of-concept (POC) testing of a coal-fired space heating system for the commercial market sector. The objective of this program is to design, build and test a coal based heating system for this sector and determine the economic viability and market potential for the system. Coal water slurry (CWS) fuel has been chosen as the fuel form for this development effort. CWS eliminates the need to use dry pulverized coal with its attendant handling, metering and dusting problems as well as its explosive potential. Equally important in selecting a fuel form is the impact on emission levels and pollution control equipment requirements. CWS is amenable to coal washing since coal cleaning technologies are generally water-based processes requiring the fine grinding of the coal. In the first stage. an overall system heat balance was prepared, system components were designed and manufactured or purchased, the system was fully assembled and preliminary testing performed to validate component performance and identify key operating variables. In the second stage the system was operated for prolonged periods to simulate a commercial application, and combustion and thermal efficiencies; tendencies to slag, foul, erode and corrode; and gaseous and particulate emissions were evaluated. Also during the second stage, an assessment of the commercial viability of the system was made. This assessment included an evaluation of the economics and market potential, including the sensitivity to fluctuations in fuel prices.

  1. Producing ammonium sulfate from flue gas desulfurization by-products

    USGS Publications Warehouse

    Chou, I.-Ming; Bruinius, J.A.; Benig, V.; Chou, S.-F.J.; Carty, R.H.

    2005-01-01

    Emission control technologies using flue gas desulfurization (FGD) have been widely adopted by utilities burning high-sulfur fuels. However, these technologies require additional equipment, greater operating expenses, and increased costs for landfill disposal of the solid by-products produced. The financial burdens would be reduced if successful high-volume commercial applications of the FGD solid by-products were developed. In this study, the technical feasibility of producing ammonium sulfate from FGD residues by allowing it to react with ammonium carbonate in an aqueous solution was preliminarily assessed. Reaction temperatures of 60, 70, and 80??C and residence times of 4 and 6 hours were tested to determine the optimal conversion condition and final product evaluations. High yields (up to 83%) of ammonium sulfate with up to 99% purity were achieved under relatively mild conditions. The optimal conversion condition was observed at 60??C and a 4-hour residence time. The results of this study indicate the technical feasibility of producing ammonium sulfate fertilizer from an FGD by-product. Copyright ?? Taylor & Francis Inc.

  2. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, February 15, 1994--August 15, 1994

    SciTech Connect

    Miller, B.G.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new system specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. During this reporting period, the construction of the CWSF preparation circuit (as well as a dry, micronized coal circuit) continued. The CWSF preparation circuit will be completed by November 1,1994. Additional activities included receiving a coal-designed burner and installing it on the demonstration boiler, and working with DOE in selecting pollution control systems to install on the boiler.

  3. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. [Quarterly] technical report, March 1, 1992--May 31, 1992

    SciTech Connect

    Chou, C.L.; Hackley, K.C.; Donnals, G.L.; Cao, J.; Ruch, R.R.; Pan, W.P.; Shao, D.

    1992-10-01

    Four replicate experiments of pyrolysis with quadrupole gas analyzer and ion selective electrode were conducted to monitor the release of chlorine and sulfur from a high-chlorine Illinois coal IBC-109 (0.42% chlorine on dry basis). The chlorine in coal is released solely as HCl, and the HCl release profile shows a broad peak between 250{degree}C and 600{degree}C with a maximum at 445{degree}C. In contrast, the sulfur release profile shows three peaks; the sulfur released around 370{degree}C may be derived from a labile (possibly aliphatic) component of organic sulfur, the main peak at 475{degree}C corresponds to the release of the main component (thiophenic) of organic sulfur, and the third peak at 600{degree} results from the decomposition of pyrite. Sulfur dioxide (SO{sub 2}) is the major sulfur species under an oxidizing condition in the combustion gas; additional gaseous sulfur species (COS and H{sub 2}S) are observed when the atmosphere is changed to a reducing condition. Sodium and chlorine contents in char residues determined by neutron activation analysis showed that 98% of chlorine in coal was volatilized during pyrolysis to 800{degree}C, and all the sodium is retained in the chars. The thermogravimetry-Fourier transform infrared (FTIR) spectroscopy experiments were carried out to characterize gaseous species during pyrolysis of four Illinois coals (IBC-103, -105, -106, and -109). Gas evolution profiles of sulfur (H{sub 2}S, S0{sub 2}, and COS), chlorine (HCl), and nitrogen (NH{sub 3} and HCN) species were determined. Similar release profiles of HCl and NH{sub 3} supported an interpretation that chlorine and nitrogen are closely associated in coal. COS may be formed by reaction of CO with H{sub 2}S in the gas phase.

  4. Development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-04-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system, controls, and then test the complete system in order to evaluate its potential marketability. The past quarter began with a two-day test performed in January to determine the cause of pulsations in the batch feed system observed during pilot-scale testing of surrogate TSCA incinerator ash performed in December of 1993. Two different batch feedstocks were used during this test: flyash and cullet. The cause of the pulsations was traced to a worn part in the feeder located at the bottom of the batch feed tank. The problem was corrected by replacing the wom part with the corresponding part on the existing coal feed tank. A new feeder for the existing coal tank, which had previously been ordered as part of the new coal handling system, was procured and installed. The data from the pilot-scale tests performed on surrogate TSCA incinerator ash during December of 1993 was collected and analyzed. All of the glass produced during the test passed both the Toxicity characteristics Leach Procedure (TCLP) and the Product Consistency Test (PCT) by approximately two orders of magnitude.

  5. Biofuels Combustion

    NASA Astrophysics Data System (ADS)

    Westbrook, Charles K.

    2013-04-01

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

  6. Biofuels combustion.

    PubMed

    Westbrook, Charles K

    2013-01-01

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

  7. Biofuels combustion*

    SciTech Connect

    Westbrook, Charles K.

    2013-01-04

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. As a result, research efforts on so-called second- and third-generation biofuels are discussed briefly.

  8. Bubble Combustion

    NASA Technical Reports Server (NTRS)

    Corrigan, Jackie

    2004-01-01

    A method of energy production that is capable of low pollutant emissions is fundamental to one of the four pillars of NASA s Aeronautics Blueprint: Revolutionary Vehicles. Bubble combustion, a new engine technology currently being developed at Glenn Research Center promises to provide low emissions combustion in support of NASA s vision under the Emissions Element because it generates power, while minimizing the production of carbon dioxide (CO2) and nitrous oxides (NOx), both known to be Greenhouse gases. and allows the use of alternative fuels such as corn oil, low-grade fuels, and even used motor oil. Bubble combustion is analogous to the inverse of spray combustion: the difference between bubble and spray combustion is that spray combustion is spraying a liquid in to a gas to form droplets, whereas bubble combustion involves injecting a gas into a liquid to form gaseous bubbles. In bubble combustion, the process for the ignition of the bubbles takes place on a time scale of less than a nanosecond and begins with acoustic waves perturbing each bubble. This perturbation causes the local pressure to drop below the vapor pressure of the liquid thus producing cavitation in which the bubble diameter grows, and upon reversal of the oscillating pressure field, the bubble then collapses rapidly with the aid of the high surface tension forces acting on the wall of the bubble. The rapid and violent collapse causes the temperatures inside the bubbles to soar as a result of adiabatic heating. As the temperatures rise, the gaseous contents of the bubble ignite with the bubble itself serving as its own combustion chamber. After ignition, this is the time in the bubble s life cycle where power is generated, and CO2, and NOx among other species, are produced. However, the pollutants CO2 and NOx are absorbed into the surrounding liquid. The importance of bubble combustion is that it generates power using a simple and compact device. We conducted a parametric study using CAVCHEM

  9. Biofuels combustion*

    DOE PAGES

    Westbrook, Charles K.

    2013-01-04

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acidsmore » and used primarily to replace or supplement conventional diesel fuels. As a result, research efforts on so-called second- and third-generation biofuels are discussed briefly.« less

  10. Assessment of Literature Related to Combustion Appliance Venting Systems

    SciTech Connect

    Rapp, V. H.; Less, B. D.; Singer, B. C.; Stratton, J. C.; Wray, C. P.

    2015-02-01

    In many residential building retrofit programs, air tightening to increase energy efficiency is often constrained by safety concerns with naturally vented combustion appliances. Tighter residential buildings more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spill combustion exhaust into the living space. Several measures, such as installation guidelines, vent sizing codes, and combustion safety diagnostics, are in place with the intent to prevent backdrafting and combustion spillage, but the diagnostics conflict and the risk mitigation objective is inconsistent. This literature review summarizes the metrics and diagnostics used to assess combustion safety, documents their technical basis, and investigates their risk mitigations. It compiles information from the following: codes for combustion appliance venting and installation; standards and guidelines for combustion safety diagnostics; research evaluating combustion safety diagnostics; research investigating wind effects on building depressurization and venting; and software for simulating vent system performance.

  11. Development and testing of industrial scale, coal fired combustion system, Phase 3. Eighteenth quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    Zauderer, B.

    1996-08-18

    In the second quarter of calendar year 1996, 16 days of combust- boiler tests were performed, including 2 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of June in the task 5 effort to 28, increased to 36 as of the date of this Report, 8/18/96. This compares with a total of 63 test days needed to complete the task 5 test effort. It is important to note that the only major modification to the Williamsport combustor has been the addition of a new downstream section, which lengthens the combustor and improves the combustor-boiler interface. The original combustor section, which includes the fuel, air, and cooling water delivery systems remained basically unchanged. Only the refractory liner was completely replaced, a task which occurs on an annual basis in all commercial slagging utility combustors. Therefore, this combustor has been operated since 1988 without replacement. The tests in the present reporting period are of major significance in that beginning with the first test on March 31st, for the first time slagging opening conditions were achieved in the upgraded combustor. The first results showed that the present 20 MMBtu/hr combustor design is far superior to the previous one tested since 1988 in Williamsport, PA. The most important change is that over 95% of the slag was drained from the slag tap in the combustor. This compares with an range of one-third to one-half in Williamsport. In the latter, the balance of the slag flowed out of the exit nozzle into the boiler floor. In addition, the overall system performance, including the combustor, boiler, and stack equipment, ranged from good to excellent. Those areas requiring improvement were of a nature that could be corrected with some work. but in no case were the problems encountered of a barrier type.

  12. Specifics of phytomass combustion in small experimental device

    NASA Astrophysics Data System (ADS)

    Lenhard, Richard; Mičieta, Jozef; Jandačka, Jozef; Gavlas, Stanislav

    2015-05-01

    A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass), which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

  13. Performance of industrial by-products in controlled low-strength materials (CLSM).

    PubMed

    Nataraja, M C; Nalanda, Y

    2008-01-01

    As the construction industry continues to recognise the importance of sustainable development, technologies such as controlled low-strength material (CLSM) have come to the forefront as viable means of safely and efficiently using by-product and waste materials in infrastructure applications. CLSM, also known as flowable fill, can be defined as an engineered backfill material containing fine aggregates, Portland cement, water and a by-product material. CLSM can provide an economically and technically feasible alternative to conventional fill materials because of potential cost savings related to its unique and often superior technical properties. In this present experimental study, three industrial by-products, namely fly ash (FA), rice husk ash (RHA) and quarry dust (QD), were used as constituent materials in CLSM. Mixture proportions were developed for CLSM containing these industrial by-products and were tested in the laboratory for various properties, such as flowability, unconfined compressive strength (UCS), stress-strain behaviour, density, water absorption and volume changes. Comparison between the two pozzolanic materials, namely FA and RHA, for their potential to produce an effective CLSM has been made. It can be observed from the results that by-product materials such as FA, RHA and QD can be successfully used in CLSM. This successful utilization of by-product materials is important to sustainable development and is the focus of this research.

  14. Development and testing of industrial scale, coal fired combustion system, Phase 3. Second quarterly technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Zauderer, B.

    1992-07-10

    In the second quarter of calendar year 1992, work continued on Task 1.1. ``DESIGN MODIFICATIONS TO THE 20 MMBTU/HR AIR COOLED COMBUSTOR AND BOILER COMPONENTS``. This consisted of specifying and designing the changes needed to prepare the 20 MMBtu/hr air cooled combustor at the Tampella boiler house site in Williamsport, PA. In depth review of the technical status of the combustor showed that no major design changes were necessary in order to implement the effort of task 2 testing and part of the task 3 testing. Among the major planned changes eliminated were replacement of the inlet swirl air flow section of the combustor. The major changes undertaken were to improve the coal and sorbent injection into the combustor; refurbishing various components and controls systems such as the stack particle scrubber and temperature probes; automating key elements of the combustor, such as the slag tap, upgrading the computer control and automatic data acquisition; and upgrading the long duration capability of the exit nozzle. To support this effort advanced analytical modeling was used to provide guidance for the design changes. A multi-dimensional computer code was used to analyze the combustor performance for different combustor stoichiometries and geometry. A heat transfer analysis of the exit nozzle was performed to determine the best method of adding cooling capacity to the exit nozzle to allow its use for multi-day, round-the-clock coal testing.

  15. Turbulent combustion

    SciTech Connect

    Talbot, L.; Cheng, R.K.

    1993-12-01

    Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

  16. Illinois Clean Coal Institute 2005 annual report. Final technical report for the period September 1st, 2004, through August 31, 2005 on projects funded by the Illinois Department of Commerce and Economic Opportunity

    SciTech Connect

    2005-11-08

    This final technical report contains the abstracts and executive summaries of projects funded through the Illinois Clean Coal Institute solicitation entitled 'Request for proposals No. 04-1(ICCI/RFP04-1)'. Support of these projects is by the Office of Coal Development and Department of Commerce and Economic Opportunity. The projects fall into the following categories: advanced coal mining technologies; coal preparation and coal production business practice; management of coal combustion byproducts; commercialization and technology transfer. Final project extensions are also recorded.

  17. Management of dry gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1996

    SciTech Connect

    1996-12-31

    The objective is to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement using virtually dry coal combustion by-products, and (2) hydraulic placement using a paste mixture of combustion by-products with about 70% solids. Phase 2 of the overall program began April 1, 1996. The principal objective of Phase 2 is to develop and fabricate the equipment for both the pneumatic and hydraulic placement technologies, and to conduct a limited, small-scale shakedown test of the pneumatic and hydraulic placement equipment. The shakedown test originally was to take place on the surface, in trenches dug for the tests. However, after a thorough study it was decided, with the concurrence of DOE-METC, to drill additional injection wells and conduct the shakedown tests underground. This will allow a more thorough test of the placement equipment.

  18. EPA ASSESSMENT OF TECHNOLOGIES FOR CONTROLLING EMISSIONS FROM MUNICIPAL WASTE COMBUSTION

    EPA Science Inventory

    The article examines EPA technical activities relating to the development of regulations pertaining to the control of both new and existing municipal waste combustion facilities (MWCs). The activities include: (1) assessing combustion and flue gas cleaning technologies, (2) colle...

  19. Development & testing of industrial scale, coal fired combustion system, phase 3. Eighth quarterly technical progress report, 1 October, 1993--31 December, 1993

    SciTech Connect

    Zauderer, B.

    1994-01-31

    The primary objective of the present Phase 3 effort is to perform the final testing at a 20 MMBtu/hr commercial scale of an air cooled, slagging coal combustor for application to industrial steam boilers and power plants. The focus of the test effort will be on combustor durability, automatic control of the combustor`s operation, and optimum environmental control of emissions inside the combustor. In connection with the latter, the goal is to achieve 0.4 lb/MMBtu of SO{sub 2} emissions, 0.2 lb/MMBtu of NO{sub x} emissions, and 0.02 lb particulates/MMBtu. Meeting the particulate goal will require the use of a baghouse or electrostatic precipitator to augment the nominal slag retention in the combustor. The NO{sub x} emission goal will require a modest improvement over maximum reduction achieved to date in the combustor to a level of 0.26 lb/MMBtu. To reach the SO{sub 2} emissions goal may require a combination of sorbent injection inside the combustor and sorbent injection inside the boiler, especially in high (>3.5%) sulfur coals. Prior to the initiation of the project, SO{sub 2} levels as low as 0.6 lb/MMBtu, equal to 81% reduction in 2% sulfur coals, were measured with boiler injection of calcium hydrate. The final objective is to define suitable commercial power or steam generating systems to which the use of the air cooled combustor offers significant technical and economic benefits. In implementing this objective both simple steam generation and combined gas turbine-steam generation systems will be considered.

  20. Characterization and Recovery of Rare Earths from Coal and By-Products

    SciTech Connect

    Granite, Evan J.; Roth, Elliot; Alvin, Mary Anne

    2016-03-25

    Coal is a precious resource, both in the United States and around the world. The United States has a 250-year supply of coal, and generates between 30 - 40% of its electricity through coal combustion. Approximately 1 Gt of coal has been mined annually in the US, although the 2015 total will likely be closer to 900 Mt (http://www.eia.gov/coal/production/quarterly/). Most of the coal is burned for power generation, but substantial quantities are also employed in the manufacture of steel, chemicals, and activated carbons. Coal has a positive impact upon many industries, including mining, power, rail transportation, manufacturing, chemical, steel, activated carbon, and fuels. Everything that is in the earth’s crust is also present within coal to some extent, and the challenge is always to utilize abundant domestic coal in clean and environmentally friendly manners. In the case of the rare earths, these valuable and extraordinarily useful elements are present within the abundant coal and coal by-products produced domestically and world-wide. These materials include the coals, as well as the combustion by-products such as ashes, coal preparation wastes, gasification slags, and mining by-products. All of these materials can be viewed as potential sources of rare earth elements. Most of the common inorganic lanthanide compounds, such as the phosphates found in coal, have very high melting, boiling, and thermal decomposition temperatures, allowing them to concentrate in combustion and gasification by-products. Furthermore, rare earths have been found in interesting concentrations in the strata above and below certain coal seams. Much of the recent research on coal utilization in the United States has focused upon the capture of pollutants such as acid gases, particulates, and mercury, and the greenhouse gas carbon dioxide. The possible recovery of rare earth and other critical elements from abundant coal and by-products is an exciting new research area, representing a

  1. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect

    Gregory J. McCarthy; Dean G. Grier

    1998-03-01

    The goals of the project are two-fold: (1) to upgrade semi-quantitative X-ray diffraction (QXRD) methods presently used in analyzing complex coal combustion by-product (CCB) systems, with the quantitative Rietveld method, and (2) to apply this method to a set of by-product materials that have been disposed or utilized for a long period (5 years or more) in contact with the natural environment, to further study the nature of CCB diagenesis. The project is organized into three tasks to accomplish these two goals: (1) thorough characterization of a set of previously analyzed disposed by-product materials, (2) development of a set of CCB-specific protocols for Rietveld QXRD, and (3) characterization of an additional set of disposed CCB materials, including application of the protocols for Rietveld QXRD developed in Task 2.

  2. IGCC and PFBC By-Products: Generation, Characteristics, and Management Practices

    SciTech Connect

    Pflughoeft-Hassett, D.F.

    1997-09-01

    The following report is a compilation of data on by-products/wastes from clean coal technologies, specifically integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC). DOE had two objectives in providing this information to EPA: (1) to familiarize EPA with the DOE CCT program, CCT by-products, and the associated efforts by DOE contractors in the area of CCT by-product management and (2) to provide information that will facilitate EPA's effort by complementing similar reports from industry groups, including CIBO (Council of Industrial Boiler Owners) and EEI USWAG (Edison Electric Institute Utility Solid Waste Activities Group). The EERC cooperated and coordinated with DOE CCT contractors and industry groups to provide the most accurate and complete data on IGCC and PFBC by-products, although these technologies are only now being demonstrated on the commercial scale through the DOE CCT program.

  3. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect

    Gregory J. McCarthy; Dean G. Grier

    1998-09-01

    The goals of the project are two-fold: (1) to upgrade semi-quantitative X-ray diffraction (QXRD) methods presently used in analyzing complex coal combustion by-product (CCB) systems, with the quantitative Rietveld method, and (2) to apply this method to a set of by-product materials that have been disposed or utilized for a long period (5 years or more) in contact with the natural environment, to further study the nature of CCB diagenesis. The project is organized into three tasks to accomplish these two goals: (1) thorough characterization of a set of previously analyzed disposed by-product materials, (2) development of a set of CCB-specific protocols for Rietveld QXRD, and (3) characterization of an additional set of disposed CCB materials, including application of the protocols for Rietveld QXRD developed in Task 2.

  4. Regenerative combustion device

    DOEpatents

    West, Phillip B.

    2004-03-16

    A regenerative combustion device having a combustion zone, and chemicals contained within the combustion zone, such as water, having a first equilibrium state, and a second combustible state. Means for transforming the chemicals from the first equilibrium state to the second combustible state, such as electrodes, are disposed within the chemicals. An igniter, such as a spark plug or similar device, is disposed within the combustion zone for igniting combustion of the chemicals in the second combustible state. The combustion products are contained within the combustion zone, and the chemicals are selected such that the combustion products naturally chemically revert into the chemicals in the first equilibrium state following combustion. The combustion device may thus be repeatedly reused, requiring only a brief wait after each ignition to allow the regeneration of combustible gasses within the head space.

  5. Advanced Combustion

    SciTech Connect

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  6. Conceptual design for the space station Freedom modular combustion facility

    NASA Technical Reports Server (NTRS)

    1989-01-01

    A definition study and conceptual design for a combustion science facility that will be located in the Space Station Freedom's baseline U.S. Laboratory module is being performed. This modular, user-friendly facility, called the Modular Combustion Facility, will be available for use by industry, academic, and government research communities in the mid-1990's. The Facility will support research experiments dealing with the study of combustion and its byproducts. Because of the lack of gravity-induced convection, research into the mechanisms of combustion in the absence of gravity will help to provide a better understanding of the fundamentals of the combustion process. The background, current status, and future activities of the effort are covered.

  7. Building America Expert Meeting: Combustion Safety

    SciTech Connect

    Brand, L.

    2013-03-01

    This is a meeting overview of 'The Best Approach to Combustion Safety in a Direct Vent World', held June 28, 2012, in San Antonio, Texas. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

  8. Building America Expert Meeting. Combustion Safety

    SciTech Connect

    Brand, Larry

    2013-03-01

    This is an overview of "The Best Approach to Combustion Safety in a Direct Vent World," held June 28, 2012, in San Antonio, TX. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

  9. JANNAF 36th Combustion Subcommittee Meeting. Volume 2

    NASA Technical Reports Server (NTRS)

    Fry, Ronald S. (Editor); Gannaway, Mary T. (Editor)

    1999-01-01

    Volume 11, the second of three volumes is a compilation of 33 unclassified/unlimited-distribution technical papers presented at the Joint Army-Navy-NASA-Air Force (JANNAF) 36th Combustion Subcommittee held jointly with the 24 Airbreathing Propulsion Subcommittee and 18th Propulsion Systems Hazards Subcommittee. The meeting was held on 18-21 October 1999 at NASA Kennedy Space Center and The DoubleTree Oceanfront Hotel, Cocoa Beach, Florida. Topics covered include gun solid propellant ignition and combustion, Electrothermal Chemical (ETC) propulsion phenomena, liquid propellant gun combustion and barrel erosion, gas phase propellant combustion, kinetic and decomposition phenomena and liquid and hybrid propellant combustion behavior.

  10. Annual Report: Advanced Combustion (30 September 2012)

    SciTech Connect

    Hawk, Jeffrey; Richards, George

    2012-09-30

    The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

  11. Bio-based Adsorbents from Agricultural Byproducts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Agricultural byproducts are often not used to the extent possible. Here we demonstrate that these byproducts can be used as starting material for production of activated carbon. These carbons can be used for uptake of water contaminants such as trichloroethylene and perchloroethylene. We will sho...

  12. Sequestration of CO2 in Mixtures of Caustic Byproduct and Saline Waste Water

    SciTech Connect

    Dilmore, R.M.; Howard, B.H.; Soong, Y.; Griffith, C.; Hedges,S.W.; DeGalbo, A.D.; Morreale, B.; Baltrus, J.P.; Allen, D.E.; Fu, J.K.

    2009-01-01

    Ex-situ carbonation of mixtures of caustic byproduct materials and produced oil-field brine provides a niche opportunity to sequester anthropogenic CO2, while concomitantly reducing the basicity of the reactive slurry. A series of tests were conducted to investigate a novel reaction concept designed to achieve neutralization of mixtures of acidic oil field produced brine and caustic industrial byproducts while sequestering substantial quantities of anthropogenic carbon dioxide (C02) in a mixed-flow reactor. Experiments were conducted to determine the COrbearing capacity of reactive mixtures of brine from the Oriskany Sandstone Formation with three caustic industrial byproducts: flue gas desulfurization (FGO) spray dryer ash, Class C fly ash subbituminous coal combustion byproduct, and bauxite residue slurry from the alumina production process. Reactions were conducted in a closed, well-mixed (1,500 rpm) reactor with gas composed of 29.46% vol./vol. CO2 balanced by nitrogen gas (N2) fed at a rate of 300mL/min. Reactions were carried out at ambient conditions. Results show linear relationships between caustic byproduct addition and COrbearing capacity, with relatively small impact of brine addition as compared to deionized water addition. FGO spray dryer ash/brine mixtures exhibited higher CO2 reactivity than those using Class C fly ash (0.759 moles CO2, at 23.6% solids by weight and 0.036 moles CO2 at 23.3% solids by weight, respectively). Bauxite residue exhibited moderate capacities in mixtures with higher percent solids (0.335 moles CO2 in 40% solids bauxite residue slurry). Carbonation capacity of caustic byproduct/ acidic brine mixtures was shown to increase linearly with respect to percent caustic byproduct addition, but enhanced mineral carbonate precipitation resulting from synergistic reaction of brine cations with increased dissolved carbonate species was not observed in the short term.

  13. The fate of mercury in coal utilization byproducts

    SciTech Connect

    William Aljoe; Thomas Feeley; James Murphy; Lynn Brickett

    2005-05-01

    The US Department of Energy National Energy Technology Laboratory's (DOE/NETL's) research has helped to further scientific understanding of the environmental characteristics of coal-utilization by-products (CUBs) in both disposal and beneficial utilization applications. The following general observations can be drawn from results of the research that has been carried out to date: There appears to be only minimal mercury release to the environment in typical disposal or utilization applications for CUBs generated using activated carbon injection (ACI) control technologies; There appears to be only minimal mercury release to the environment in typical disposal and utilization applications for CUBs generated using wet FGD control technologies. The potential release of mercury from wet FGD gypsum during the manufacture of wallboard is still under evaluation; The amount of mercury leached from CUB samples tested by DOE/NETL is significantly lower than the federal drinking water standards and water quality criteria for the protection of aquatic life; in many cases, leachate concentrations were below the standard test method detection limits. DOE/NETL will continue to partner with industry and other key stakeholders in carrying out research to better understand the fate of mercury and other trace elements in the byproducts from coal combustion. 16 refs., 6 tabs.

  14. Homogeneous catalysts in hypersonic combustion

    SciTech Connect

    Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

    1989-01-01

    Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

  15. Advanced Gasification By-Product Utilization

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Harold Schobert

    2006-02-01

    With the recent passing of new legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2004 to August 31, 2005. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  16. Theoretical and Experimental Investigations of Ignition, Combustion and Expansion Processes of Hypergolic Liquid Fuel Combinations at Gas Temperatures up to 3000 K. Thesis - Rhein-Westfalia Technical Coll., 1967

    NASA Technical Reports Server (NTRS)

    Schulz, Harry

    1987-01-01

    The ignition, combustion, and expansion characteristics of hypergolic liquid propellant mixtures in small rocket engines are studied theoretically and experimentally. It is shown by using the Bray approximation procedure that the reaction H + OH + M = H2O + M (where M is the molecular mass of the gas mixture) has a strong effect on the combustion efficiency. Increases in recombination energies ranging from 30 to 65% were obtained when the rate of this reaction was increased by a factor of 10 in gas mixtures containing 90% oxygen. The effect of aluminum additions and various injection techniques on the combustion process is investigated.

  17. Combustion chemistry

    SciTech Connect

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  18. Codisposal of FBC by-products and coal slurry solids: Characterization of materials

    SciTech Connect

    Tungate, D.E.; Darmody, R.G.; Dreher, G.B.; Roy, W.R.; Steele, J.D.

    1997-12-31

    The preparation and combustion of high sulfur coal generates many waste products including cleaning and combustion wastes. Pyrite is associated with coal cleaning wastes and it makes them potentially acidic. Coal slurry solids (CSS), the finest textured cleaning wastes, are stored in large impoundments. After the impoundments are retired, they must be reclaimed with a 1.2 in soil cap. Reclamation of abandoned CSS impoundments by direct revegetation would avoid costs associated with the required soil cap. However, CSS have physical and chemical limitations for plant growth including undesirable pH, surface temperatures, and moisture holding capacity. Fluidized bed combustion is a coal combustion technique designed to reduce smoke stack emissions of SO{sub 2}. It results in a highly alkaline by-product (FBC). The combination of CSS and FBC may allow direct revegetation of CSS materials. This would possibly be a more cost effective method of reclaiming CSS materials than using a soil cap while creating an economic value for FBC by-products. This will also preclude the necessity of disturbing a borrow area for the soil cap. An experiment was designed to evaluate the potential for CSS/FBC mixtures to support direct revegetation. Three test blocks with 18 plots each were established on a temporarily inactive portion of an active coal slurry impoundment. The addition of FBC increased the pH of the potentially acidic CSS. Soil fertility analyses indicated Al, B, Ca, Mg, Zn, and soluble salts increased with additions of FBC, while Cu, Fe, K, P, and S remained relatively unchanged, and Mn and Na concentration decreased. Direct revegetation of CSS materials may be facilitated by the addition of FBC by-products. However, other treatments in addition to FBC amendments may be necessary to optimize conditions for plant growth.

  19. FY2013 Progress Report for Advanced Combustion Engine Research and Development

    SciTech Connect

    none,

    2013-12-01

    Annual progress report on the work of the the Advanced Combustion Engine Program. The Advanced Combustion Engine Program supports the Vehicle Technologies Office mission by addressing critical technical barriers to commercializing higher efficiency, very low emissions, advanced combustion engines for passenger and commercial vehicles that meet future federal emissions regulations.

  20. FY2012 Annual Progress Report for Advanced Combustion Engine Research and Development

    SciTech Connect

    none,

    2013-02-01

    Annual report on the work of the the Advanced Combustion Engine R&D subprogram. The Advanced Combustion Engine R&D subprogram supports the Vehicle Technologies Office mission by removing the critical technical barriers to commercialization of advanced internal combustion engines (ICEs) for passenger and commercial vehicles that meet future federal emissions regulations.

  1. Process for obtaining energy, soft water and by-products from aqueous substances

    SciTech Connect

    Grenet, E.P.

    1982-08-17

    The aqueous substance, for example sea water, is boiled, the steam produced is fed under pressure into a turbo-alternator turbine producing electricity, the residual steam is reduced into soft water and the residue of evaporation, for example sea salt, is recovered as a by-product. The steam is fed directly or on leaving the turbine onto iron heated to about 800* C., which supplies hydrogen and as a byproduct ferric oxide. The initial source of energy is, besides solar energy, any known source of energy, such as coal situated at great depths. The starting aqueous substance is, apart from sea water, waste sludges, a rock salt solution or a mixture of sludges and salt solution. In the case of sludges, the by-product is a dry and sterilized fertilizer transformable into fuel bricks. The salt residue is transformable by electrolysis into hydrogen and sodium chlorate, which is a fuel. The sludge-salt residue supplies a combustible mixture. Dried sludges-sodium chlorate, is mixable with household waste for promoting the combustibility thereof. The sodium chlorate can be transformed into potassium chlorate and the steam under pressure may be condensed in distant reservoirs and its heat recovered. The energies produced in the turbo alternator or fuel-by products are usable in the process.

  2. Sequestration of CO{sub 2} in Mixtures of Caustic Byproduct and Saline Waste Water

    SciTech Connect

    Dilmore, R.M.; Howard, B.H.; Soong, Y.; Griffith, C.; Hedges, S.W.; DeGalbo, A.D.; Morreale, B.; Baltrus, J.P.; Allen, D.E.; Fu, J.K.

    2009-08-15

    A series of tests were conducted to investigate a novel reaction concept designed to achieve neutralization of mixtures of acidic oil field produced brine and caustic industrial byproducts while sequestering substantial quantities of anthropogenic carbon dioxide (CO{sub 2}) in a mixed-flow reactor. Experiments were conducted to determine the CO{sub 2}-bearing capacity of reactive mixtures of brine from the Oriskany Sandstone Formation with three caustic industrial byproducts: flue gas desulfurization (FGD) spray dryer ash, Class C fly ash subbituminous coal combustion byproduct, and bauxite residue slurry from the alumina production process. Reactions were conducted in a closed, well-mixed (1,500 rpm) reactor with gas composed of 29.46% vol./vol. CO{sub 2} balanced by nitrogen gas fed at a rate of 300 mL/min. Reactions were carried out at ambient conditions. Results show linear relationships between caustic byproduct addition and CO{sub 2}-bearing capacity, with relatively small impact of brine addition as compared to deionized water addition. FGD spray dryer ash/brine mixtures exhibited higher CO{sub 2} reactivity than those using Class C fly ash (0.759 moles CO{sub 2}, at 23.6% solids by weight and 0.036 moles CO{sub 2} at 23.3% solids by weight, respectively). Bauxite residue exhibited moderate capacities in mixtures with higher percent solids (0.335 moles CO{sub 2} in 40% solids bauxite residue slurry). Carbonation capacity of caustic byproduct/acidic brine mixtures was shown to increase linearly with respect to percent caustic byproduct addition, but enhanced mineral carbonate precipitation resulting from synergistic reaction of brine cations with increased dissolved carbonate species was not observed in the short term.

  3. Coal combustion science

    SciTech Connect

    Hardesty, D.R.; Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  4. Combustible particluate fuel heater

    SciTech Connect

    Collins, B.H.; Jurgens, H.J.W.

    1986-01-21

    This patent describes a combustible particulate fired heater. It consists of: a combustion chamber defined by upright side walls extending between open top and bottom ends; an enclosure surrounding the combustion chamber; a retort within the combustion chamber adjacent the bottom end and having a lower particulate receiving end and an upper open end; feed conveyor means leading through the enclosure to the retort for delivering metered quantities of combustible particulates to the lower particulate receiving end of the retort; primary combustion air supply means having a primary combustion air supply manifold extending at least partially about the upper open end of the retort; primary air control means on the primary air supply means for selectively allowing entry of combustion air from outside the enclosure in to the retort; secondary combustion air supply means including a secondary air supply manifold within the combustion chamber above the primary combustion air supply manifold; secondary air control means independent of the primary air control means for selectively allowing entry of secondary air from outside the enclosure to an area within the combustion chamber above the retort; an exhaust duct opening into the enclosure; and vacuum means connected to the exhaust duct for producing a pressure differential between the area confined by the enclosure and the ambient atmosphere such that ambient air is drawn through at least one of the combustion air supply means to induce a high level of gasification and to support combustion at the retort and for drawing combustion exhaust gases out through the exhaust duct.

  5. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 4, February--April 1990

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-06-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and missions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects test; and full-scale combustion tests.

  6. Combustion technologies

    SciTech Connect

    Barsin, J.A.

    1994-12-31

    The presentation will cover the highlights of sludge, providing information as to where it comes from, projection of how much more is expected, what is sludge, what can be done with them, and finally focus in one combustion technology that can be utilized and applied to recycle sludge. The author is with Gotaverken Energy Systems Inc. where for the past 100 years they have been involved in the recovery of chemicals in chemical pulp mills. One week ago, our name was changed to Kvaerner Pulping Inc. to better reflect our present make-up which is a combination of Kamyr AB (suppliers of proprietary highly engineered totally chlorine free chemical pulp manufacturing systems, including digesters, O{sub 2} delignification systems, and bleach plant systems) and Goetaverken. Sludges that we are concerned with derive from several sources within chemical pulp mills such as: such as primary clarifier sludges, secondary clarifier sludges, and most recently those sludges derived from post consumer paper and board recycle efforts including de-inking and those from the thermal mechanical pulping processes. These sludges have been classified as non-hazardous therefore, residue can be landfilled, but the volumes involved are growing at an alarming rate.

  7. 30 CFR 206.358 - What are byproduct transportation allowances?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... MINERALS REVENUE MANAGEMENT PRODUCT VALUATION Geothermal Resources § 206.358 What are byproduct transportation allowances? (a) When you determine the value of byproducts at a point off the geothermal lease... geothermal use facility to a byproduct recovery facility when that byproduct recovery facility is off...

  8. Land application uses for dry flue gas desulfurization by-products. Executive summary

    SciTech Connect

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    Flue gas desulfurization (FGD) scrubbing technologies create several types of by-products. This project focused primarily on by-product materials obtained from what are commonly called ''dry scrubbers'' which produce a dry, solid material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Prior to this project, dry FGD by-products were generally treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing; The major objective of this project was to develop beneficial uses, via recycling, capable of providing economic benefits to both the producer and the end user of the FGD by-product. It is equally important, however, that the environmental impacts be carefully assessed so that the new uses developed are not only technically feasible but socially acceptable. Specific objectives developed for this project were derived over an 18-month period during extensive discussions with personnel from industry, regulatory agencies and research institutions. These were stated as follows: Objective 1: To characterize the material generated by dry FGD processes. Objective 2: To demonstrate the utilization of dry FGD by-product as a soil amendment on agricultural lands and on abandoned and active surface coal mines in Ohio. Objective 3: To demonstrate the use of dry FGD by-product as an engineering material for soil stabilization. Objective 4: To determine the quantities of dry FGD by-product that can be utilized in each of these applications. Objective 5. To determine the environmental and economic impacts of utilizing the material. Objective 6. To calibrate environmental, engineering, and economic models that can be used to determine the applicability and costs of utilizing these processes at other sites.

  9. Combustion 2000

    SciTech Connect

    A. Levasseur; S. Goodstine; J. Ruby; M. Nawaz; C. Senior; F. Robson; S. Lehman; W. Blecher; W. Fugard; A. Rao; A. Sarofim; P. Smith; D. Pershing; E. Eddings; M. Cremer; J. Hurley; G. Weber; M. Jones; M. Collings; D. Hajicek; A. Henderson; P. Klevan; D. Seery; B. Knight; R. Lessard; J. Sangiovanni; A. Dennis; C. Bird; W. Sutton; N. Bornstein; F. Cogswell; C. Randino; S. Gale; Mike Heap

    2001-06-30

    . To achieve these objectives requires a change from complete reliance of coal-fired systems on steam turbines (Rankine cycles) and moving forward to a combined cycle utilizing gas turbines (Brayton cycles) which offer the possibility of significantly greater efficiency. This is because gas turbine cycles operate at temperatures well beyond current steam cycles, allowing the working fluid (air) temperature to more closely approach that of the major energy source, the combustion of coal. In fact, a good figure of merit for a HIPPS design is just how much of the enthalpy from coal combustion is used by the gas turbine. The efficiency of a power cycle varies directly with the temperature of the working fluid and for contemporary gas turbines the optimal turbine inlet temperature is in the range of 2300-2500 F (1260-1371 C). These temperatures are beyond the working range of currently available alloys and are also in the range of the ash fusion temperature of most coals. These two sets of physical properties combine to produce the major engineering challenges for a HIPPS design. The UTRC team developed a design hierarchy to impose more rigor in our approach. Once the size of the plant had been determined by the choice of gas turbine and the matching steam turbine, the design process of the High Temperature Advanced Furnace (HITAF) moved ineluctably to a down-fired, slagging configuration. This design was based on two air heaters: one a high temperature slagging Radiative Air Heater (RAH) and a lower temperature, dry ash Convective Air Heater (CAH). The specific details of the air heaters are arrived at by an iterative sequence in the following order:-Starting from the overall Cycle requirements which set the limits for the combustion and heat transfer analysis-The available enthalpy determined the range of materials, ceramics or alloys, which could tolerate the temperatures-Structural Analysis of the designs proved to be the major limitation-Finally the commercialization

  10. Pulsating combustion of gas fuel in the combustion chamber with closed resonant circuit

    NASA Astrophysics Data System (ADS)

    Yallina, E. V.; Larionov, V. M.; Iovleva, O. V.

    2013-12-01

    In the combustion chambers of the pulsation of gas flow oscillation greatly accelerate heat dissipation to the walls of the combustion chamber and improve combustion efficiency as compared with a uniform combustion mode. This allows you to effectively solve a number of problems of industrial power, including an environmentally friendly combustion products. Significant drawback of such systems - the emitted noise exceeding the permissible requirements. One solution to this problem - the separation of the resonance tube into 2 parts connected at the output to the interference of sound waves. The results of theoretical studies pulsating combustion technical mixture of propane in the system, consisting of a combustion chamber and two resonance tubes forming a closed resonant circuit. Resonators have a variable length. Calculations have shown that under certain oscillation of the resonator length to the first resonant frequency of the system is achieved by reducing SPL more than 15 dB. For oscillations at a second resonant frequency is the complete elimination of noise while maintaining intense oscillations in the combustion chamber.

  11. Fundamentals of Gas Turbine combustion

    NASA Technical Reports Server (NTRS)

    Gerstein, M.

    1979-01-01

    Combustion problems and research recommendations are discussed in the areas of atomization and vaporization, combustion chemistry, combustion dynamics, and combustion modelling. The recommendations considered of highest priority in these areas are presented.

  12. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, April 1--June 30, 1996

    SciTech Connect

    1997-05-01

    On September 30, 1993, the US Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate two technologies for the placement of coal combustion residues in abandoned underground coal mines, and will assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement, using virtually dry materials, and (2) hydraulic placement, using a {open_quotes}paste{close_quotes} mixture of materials with about 70% solids. Phase II of the overall program began April 1, 1996. The principal objective of Phase II is to develop and fabricate the equipment for placing the coal combustion by-products underground, and to conduct a demonstration of the technologies on the surface. Therefore, this quarter has been largely devoted to developing specifications for equipment components, visiting fabrication plants throughout Southern Illinois to determine their capability for building the equipment components in compliance with the specifications, and delivering the components in a timely manner.

  13. JANNAF 36th Combustion Subcommittee Meeting. Volume 1

    NASA Technical Reports Server (NTRS)

    Fry, Ronald S. (Editor); Gannaway, Mary T. (Editor)

    1999-01-01

    Volume 1, the first of three volumes is a compilation of 47 unclassified/unlimited-distribution technical papers presented at the Joint Army-Navy-NASA-Air Force (JANNAF) 36th Combustion Subcommittee held jointly with the 24th Airbreathing Propulsion Subcommittee and 18th Propulsion Systems Hazards Subcommittee. The meeting was held on 18-21 October 1999 at NASA Kennedy Space Center and The DoubleTree Oceanfront Hotel, Cocoa Beach, Florida. Solid phase propellant combustion topics covered in this volume include cookoff phenomena in the pre- and post-ignition phases, solid rocket motor and gun propellant combustion, aluminized composite propellant combustion, combustion modeling and combustion instability and instability measurement techniques.

  14. JANNAF 35th Combustion Subcommittee Meeting. Volume 1

    NASA Technical Reports Server (NTRS)

    Fry, Ronald S. (Editor); Gannaway, Mary T. (Editor); Rognan, Melanie (Editor)

    1998-01-01

    Volume 1, the first of two volumes is a compilation of 63 unclassified/unlimited distribution technical papers presented at the 35th meeting of the Joint Army-Navy-NASA-Air Force (JANNAF) Combustion Subcommittee (CS) held jointly with the 17th Propulsion Systems Hazards Subcommittee (PSHS) and Airbreathing Propulsion Subcommittee (APS). The meeting was held on 7-11 December 1998 at Raytheon Systems Company and the Marriott Hotel, Tucson, AZ. Topics covered include solid gun propellant processing, ignition and combustion, charge concepts, barrel erosion and flash, gun interior ballistics, kinetics and molecular modeling, ETC gun modeling, simulation and diagnostics, and liquid gun propellant combustion; solid rocket motor propellant combustion, combustion instability fundamentals, motor instability, and measurement techniques; and liquid and hybrid rocket combustion.

  15. [Effect of combustion devices on the quality of indoor air].

    PubMed

    Ulbrich, G

    1982-01-01

    Combustion devices and the equipment conducting their effluent gases such as ducts and chimneys are factors which might have an unreasonable or even dangerous impact on the quality of air inside buildings. There is a danger of flue gases entering the indoor environment during the heating process (a) if the air-circulation associated with the operation of a combustion device is disturbed or even interrupted, (b) if the air stream - as far as flue gases are involved - flows under elevated pressure, and (c) if the combustion device and the flue gas conducting equipment are not leak-proof. These three cases and their influence on indoor air quality are extensively discussed. In the German Combustion Device Code from 1980 care is taken to minimize the pollutant concentrations in rooms with combustion devices by setting special requirements for the room in which the device is located, and by prescribing the standardization of the technical characteristics of chimneys and combustion devices.

  16. Omissions and Byproducts across Moral Domains

    PubMed Central

    DeScioli, Peter; Asao, Kelly; Kurzban, Robert

    2012-01-01

    Research indicates that moral violations are judged less wrong when the violation results from omission as opposed to commission, and when the violation is a byproduct as opposed to a means to an end. Previous work examined these effects mainly for violent offenses such as killing. Here we investigate the generality of these effects across a range of moral violations including sexuality, food, property, and group loyalty. In Experiment 1, we observed omission effects in wrongness ratings for all of the twelve offenses investigated. In Experiments 2 and 3, we observed byproduct effects in wrongness ratings for seven and eight offenses (out of twelve), respectively, and we observed byproduct effects in forced-choice responses for all twelve offenses. Our results address an ongoing debate about whether different cognitive systems compute moral wrongness for different types of behaviors (surrounding violence, sexuality, food, etc.), or, alternatively, a common cognitive architecture computes wrongness for a variety of behaviors. PMID:23071678

  17. Flameless Combustion Workshop

    DTIC Science & Technology

    2005-09-20

    future roadmap. "Flameless Combustion " is characterized by high stability levels with virtually no thermoacoustic instabilities, very low lean... future roadmap. "Flameless Combustion " is characterized by high stability levels with virtually no thermoacoustic instabilities, very low lean stability...C. Bruno, Italy 1430-1500 Technology to Ramjet Combustion Application of FLameless H. Mongia , GE Transportation, 1500-1530 Combustion (FLC) for

  18. Mechanisms of droplet combustion

    NASA Technical Reports Server (NTRS)

    Law, C. K.

    1982-01-01

    The fundamental physico-chemical mechanisms governing droplet vaporization and combustion are discussed. Specific topics include governing equations and simplifications, the classical d(2)-Law solution and its subsequent modification, finite-rate kinetics and the flame structure, droplet dynamics, near- and super-critical combustion, combustion of multicomponent fuel blends/emulsions/suspensions, and droplet interaction. Potential research topics are suggested.

  19. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997

    SciTech Connect

    Chugh, Y.P.

    1997-12-31

    The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

  20. Industrial Combustion Technology Roadmap. A Technology Roadmap by and for the Industrial Combustion Community

    SciTech Connect

    None, None

    2002-10-01

    The U.S. combustion industry is among the most productive, efficient, and technologically sophisticated in the world and remains vital to the nation’s economic competitiveness and national security. As the industry looks forward, it confronts tremendous growth opportunities but also significant technical and market challenges. Future industry success will depend on the industry's ability to respond to competitive pressures as well as public expectations for a clean and sustainable industry. Much progress has been made in understanding the fundamental science of combustion; however, much more is needed as regulatory and competitive forces push the industry to develop combustion equipment with better performance, lower environmental impact, and greater flexibility. Immense opportunities exist for companies to develop and apply new technology responding to these needs. Unfortunately, few companies can accept the high technical and financial risk required for the research if the technology is not adopted widely enough to provide a payback on their investment.

  1. Thermal treatment for chlorine removal from coal. Final technical report, September 1, 1991--December 31, 1992

    SciTech Connect

    Muchmore, C.B.; Hesketh, H.E.; Chen, Han Lin

    1992-12-31

    It was the goal of this research to provide the technical basis for development of a process to remove chlorine from coal prior to combustion, based on a thermal treatment process. Reaction rate constants and activation energy have been determined, and energy and mass balances performed. Substitution of a synthetic flue gas (7% 0{sub 2}, 12% CO{sub 2}, 81% N{sub 2}) for nitrogen in the tube furnace resulted in at least equivalent chlorine removal (85.5%) compared to nitrogen. The fluidized bed dechlorination system modifications have resulted in a steady increase in performance, the most recent run providing 64% reduction in chlorine concentration. Addition of supplemental heat to the column should permit attainment of the slightly higher temperatures required to attain over 80% removal of the chlorine. Calcium chloride by-product of 67% purity has been produced. A bench scale catenary grid concentrator with supplemental heating coils and limited insulation is capable of concentrating CaCl{sub 2} solution up to essentially 40%, with no sign of scale or plugging. Further development of the process should include a thorough evaluation of the use of combustion gases to serve as the fluidizing medium and to provide the energy for the thermal dechlorination process.

  2. 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report second quarter, 1991

    SciTech Connect

    Not Available

    1991-12-31

    ABB CE`s Low NOx Bulk Furnace Staging (LNBFS) System and Low NOx Concentric Firing System (LNCFS) are demonstrated in stepwise fashion. These systems incorporate the concept of advanced overfire air (AOFA), clustered coal nozzles, and offset air. A complete description of the installed technologies is provided in the following section. The primary objective of the Plant Lansing Smith demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology are also being performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project.

  3. Estrogenicity of agricultural by-products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Some Minnesota farms were found to have reduced conception rates in cattle receiving embryo transfers by a local veterinarian, and dietary components were called into question. Affected farms were feeding agricultural by-products, available in either a “shredded” form or a pelletized form. These by-...

  4. Biobased polymeric materials prepared from cotton byproducts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cotton burr and cottonseed hull are relatively inexpensive natural renewable materials from cotton and cottonseed processing. Recently several new polymer applications have been reported involving these cotton byproducts. These new developments are briefly reviewed in this article. In the first a...

  5. The Economics of Mineral Byproducts and Coproducts.

    ERIC Educational Resources Information Center

    Wilkenson, T.

    1983-01-01

    In the minerals industries, joint products are a normal occurrence in many production systems, and byproducts are often crucial to the viability of mining operations. A contrast was seen between the relatively free market in cabmium with volatile prices and a producer-controlled market in germanium with greater price stability. (IS)

  6. A Sustainable Future: Fish Processing Byproducts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This is the third proceedings from byproduct symposiums held in 1990, 2002 and 2009. The 2009 symposium was held in February 25th and 26th of 2009 in Portland OR immediately after the 2009 Pacific Fisheries Technologists Annual meeting. This was an international conference with 85 participants, inc...

  7. Synthesis of Cellulose Acetate from Cotton Byproducts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cotton burr and cottonseed hull are relatively inexpensive cotton byproducts. In an effort to derive greater value out of these natural renewable materials, we have succeeded in converting part of them into cellulose acetate without prior chemical breakdown or physical separation of cellulose, ligni...

  8. Opportunities in pulse combustion

    SciTech Connect

    Brenchley, D.L.; Bomelburg, H.J.

    1985-10-01

    In most pulse combustors, the combustion occurs near the closed end of a tube where inlet valves operate in phase with the pressure amplitude variations. Thus, within the combustion zone, both the temperature and the pressure oscillate around a mean value. However, the development of practical applications of pulse combustion has been hampered because effective design requires the right combination of the combustor's dimensions, valve characteristics, fuel/oxidizer combination, and flow pattern. Pulse combustion has several additional advantages for energy conversion efficiency, including high combustion and thermal efficiency, high combustion intensity, and high convective heat transfer rates. Also, pulse combustion can be self-aspirating, generating a pressure boost without using a blower. This allows the use of a compact heat exchanger that may include a condensing section and may obviate the need for a chimney. In the last decade, these features have revived interest in pulse combustion research and development, which has resulted in the development of a pulse combustion air heater by Lennox, and a pulse combustion hydronic unit by Hydrotherm, Inc. To appraise this potential for energy savings, a systematic study was conducted of the many past and present attempts to use pulse combustion for practical purposes. The authors recommended areas where pulse combustion technology could possibly be applied in the future and identified areas in which additional R and D would be necessary. Many of the results of the study project derived from a special workshop on pulse combustion. This document highlights the main points of the study report, with particular emphasis on pulse combustion application in chemical engineering.

  9. Sequestration of CO2 in Mixtures of Caustic Byproduct and Saline Waste Water

    SciTech Connect

    Dilmore, Robert M.; Howard, Bret H.; Soong, Yee; Griffith, Craig; Hedges, Sheila W.; DeGalbo, Angelo D.; Morreale, Bryan; Baltrus, John P.; Allen, Douglas E.; Fu, Jaw K.

    2009-08-01

    Ex-situ carbonation of mixtures of caustic byproduct materials and produced oil-field brine provides a niche opportunity to sequester anthropogenic CO2, while concomitantly reducing the basicity of the reactive slurry. A series of tests were conducted to investigate a novel reaction concept designed to achieve neutralization of mixtures of acidic oil field produced brine and caustic industrial byproducts while sequestering substantial quantities of anthropogenic carbon dioxide (CO2) in a mixed-flow reactor. Experiments were conducted to determine the CO2-bearing capacity of reactive mixtures of brine from the Oriskany Sandstone Formation with three caustic industrial byproducts: flue gas desulfurization (FGD) spray dryer ash, Class C fly ash subbituminous coal combustion byproduct, and bauxite residue slurry from the alumina production process. Reactions were conducted in a closed, well-mixed (1,500 rpm) reactor with gas composed of 29.46% vol./vol. CO2 balanced by nitrogen gas (N-2) fed at a rate of 300 mL/min. Reactions were carried out at ambient conditions. Results show linear relationships between caustic byproduct addition and CO2-bearing capacity, with relatively small impact of brine addition as compared to deionized water addition. FGD spray dryer ash/brine mixtures exhibited higher CO2 reactivity than those using Class C fly ash (0.759 moles CO2, at 23.6% solids by weight and 0.036 moles CO2 at 23.3% solids by weight, respectively). Bauxite residue exhibited moderate capacities in mixtures with higher percent solids (0.335 moles CO2 in 40% solids bauxite residue slurry). Carbonation capacity of caustic byproduct/acidic brine mixtures was shown to increase linearly with respect to percent caustic byproduct addition, but enhanced mineral carbonate precipitation resulting from synergistic reaction of brine cations with increased dissolved carbonate species was

  10. Sequestration of CO 2 in Mixtures of Caustic Byproduct and Saline Waste Water

    SciTech Connect

    Dilmore, Robert M.; Howard, Bret H.; Soong, Yee; Griffith, Craig; Hedges, Sheila W.; DeGalbo, Angelo D.; Morreale, Bryan; Baltrus, John P.; Allen, Douglas E.; Fu, Jaw K.

    2009-08-01

    Ex-situ carbonation of mixtures of caustic byproduct materials and produced oil-field brine provides a niche opportunity to sequester anthropogenic CO2, while concomitantly reducing the basicity of the reactive slurry. A series of tests were conducted to investigate a novel reaction concept designed to achieve neutralization of mixtures of acidic oil field produced brine and caustic industrial byproducts while sequestering substantial quantities of anthropogenic carbon dioxide (CO2) in a mixed-flow reactor. Experiments were conducted to determine the CO2-bearing capacity of reactive mixtures of brine from the Oriskany Sandstone Formation with three caustic industrial byproducts: flue gas desulfurization (FGD) spray dryer ash, Class C fly ash subbituminous coal combustion byproduct, and bauxite residue slurry from the alumina production process. Reactions were conducted in a closed, well-mixed (1,500 rpm) reactor with gas composed of 29.46% vol./vol. CO2 balanced by nitrogen gas (N-2) fed at a rate of 300 mL/min. Reactions were carried out at ambient conditions. Results show linear relationships between caustic byproduct addition and CO2-bearing capacity, with relatively small impact of brine addition as compared to deionized water addition. FGD spray dryer ash/brine mixtures exhibited higher CO2 reactivity than those using Class C fly ash (0.759 moles CO2, at 2.6% solids by weight and 0.036 moles CO2 at 23.3% solids by weight, respectively). Bauxite residue exhibited moderate capacities in mixtures with higher percent solids (0.335 moles CO2 in 40% solids bauxite residue slurry). Carbonation capacity of caustic byproduct/acidic brine mixtures was shown to increase linearly with respect to percent caustic byproduct addition, but enhanced mineral carbonate precipitation resulting from synergistic reaction of brine cations with increased dissolved carbonate species was

  11. Physical properties of a soil substitute derived from an aluminum recycling by-product.

    PubMed

    Hermsmeyer, Dirk; Diekmann, Ralf; van der Ploeg, Rienk R; Horton, Robert

    2002-11-11

    Disposal of highly saline industrial by-products in landfills is not permitted in member states of the European Union, such as Germany. Large amounts of such by-products thus have to be disposed of in alternative ways. In many countries bare potash mining residue mounds, consisting almost entirely of rock salt (NaCl), pose environmental problems. Covering such mounds with soil or soil-like material could help to reduce the yearly amount of briny runoff. A fine-granular saline aluminum recycling by-product (ALRP) has been proposed as a soil substitute to cover rock salt residue mounds. Use of this by-product as a combined soil substitute and surface barrier is not considered to be a landfill disposal, but as a beneficial by-product reuse. To judge the feasibility of ALRP for this purpose, its properties must be known. In this study physical characteristics of an industrially produced ALRP, mixed with the flue gas desulfurization by-product (FGDP) of a coal combustion power plant, were determined. It was found that the texture of both ALRP and ALRP-FGDP mix was silt loam. Bulk densities of ALRP and ALRP-FGDP were 0.93 and 0.88 Mg x m(-3) and the corresponding salt contents were 50.0 and 35.5%, respectively. The erodibility factor K of pure ALRP was estimated as 0.65 Mg h x ha (-1)N(-1). Because of the stabilizing effect of FGDP, this factor was reduced considerably in ALRP-FGDP. The water-holding capacity of unwashed ALRP was 44.5% and of washed ALRP-FGDP 61.8%. In view of its physical properties, ALRP-FGDP seems to be suitable as an evaporation enhancing, runoff reducing cover material for potash mine residue mounds, even on steep slopes. Use of ALRP, mixed with FGDP, as a soil substitute in a surface barrier, thus seems to be environmentally meaningful. However, the high salt content initially prevents plant growth. With time, after the salt has been leached, the material seems able to support plant growth, which would further reduce runoff. The physical and

  12. Light Duty Efficient, Clean Combustion

    SciTech Connect

    Donald Stanton

    2010-12-31

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy's Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of the following objectives were met with fuel efficiency improvement targets exceeded: (1) Improve light duty vehicle (5000 lb. test weight) fuel efficiency by 10.5% over today's state-of-the-art diesel engine on the FTP city drive cycle; (2) Develop and design an advanced combustion system plus aftertreatment system that synergistically meets Tier 2 Bin 5 NOx and PM emissions standards while demonstrating the efficiency improvements; (3) Maintain power density comparable to that of current conventional engines for the applicable vehicle class; and (4) Evaluate different fuel components and ensure combustion system compatibility with commercially available biofuels. Key accomplishments include: (1) A 25% improvement in fuel efficiency was achieved with the advanced LDECC engine equipped with a novel SCR aftertreatment system compared to the 10.5% target; (2) An 11% improvement in fuel efficiency was achieved with the advanced LDECC engine and no NOx aftertreamtent system; (3) Tier 2 Bin 5 and SFTP II emissions regulations were met with the advanced LDECC engine equipped with a novel SCR aftertreatment system; (4) Tier 2 Bin 5 emissions regulations were met with the advanced LDECC engine and no NOx aftertreatment, but SFTP II emissions regulations were not met for the US06 test cycle - Additional technical barriers exist for the no NOx

  13. Ice nucleation by combustion ash particles at conditions relevant to mixed-phase clouds

    NASA Astrophysics Data System (ADS)

    Umo, N. S.; Murray, B. J.; Baeza-Romero, M. T.; Jones, J. M.; Lea-Langton, A. R.; Malkin, T. L.; O'Sullivan, D.; Neve, L.; Plane, J. M. C.; Williams, A.

    2015-05-01

    Ice-nucleating particles can modify cloud properties with implications for climate and the hydrological cycle; hence, it is important to understand which aerosol particle types nucleate ice and how efficiently they do so. It has been shown that aerosol particles such as natural dusts, volcanic ash, bacteria and pollen can act as ice-nucleating particles, but the ice-nucleating ability of combustion ashes has not been studied. Combustion ashes are major by-products released during the combustion of solid fuels and a significant amount of these ashes are emitted into the atmosphere either during combustion or via aerosolization of bottom ashes. Here, we show that combustion ashes (coal fly ash, wood bottom ash, domestic bottom ash, and coal bottom ash) nucleate ice in the immersion mode at conditions relevant to mixed-phase clouds. Hence, combustion ashes could play an important role in primary ice formation in mixed-phase clouds, especially in clouds that are formed near the emission source of these aerosol particles. In order to quantitatively assess the impact of combustion ashes on mixed-phase clouds, we propose that the atmospheric abundance of combustion ashes should be quantified since up to now they have mostly been classified together with mineral dust particles. Also, in reporting ice residue compositions, a distinction should be made between natural mineral dusts and combustion ashes in order to quantify the contribution of combustion ashes to atmospheric ice nucleation.

  14. Combustion Characterization and Model Fuel Development for Micro-tubular Flame-assisted Fuel Cells.

    PubMed

    Milcarek, Ryan J; Garrett, Michael J; Baskaran, Amrish; Ahn, Jeongmin

    2016-10-02

    Combustion based power generation has been accomplished for many years through a number of heat engine systems. Recently, a move towards small scale power generation and micro combustion as well as development in fuel cell research has created new means of power generation that combine solid oxide fuel cells with open flames and combustion exhaust. Instead of relying upon the heat of combustion, these solid oxide fuel cell systems rely on reforming of the fuel via combustion to generate syngas for electrochemical power generation. Procedures were developed to assess the combustion by-products under a wide range of conditions. While theoretical and computational procedures have been developed for assessing fuel-rich combustion exhaust in these applications, experimental techniques have also emerged. The experimental procedures often rely upon a gas chromatograph or mass spectrometer analysis of the flame and exhaust to assess the combustion process as a fuel reformer and means of heat generation. The experimental techniques developed in these areas have been applied anew for the development of the micro-tubular flame-assisted fuel cell. The protocol discussed in this work builds on past techniques to specify a procedure for characterizing fuel-rich combustion exhaust and developing a model fuel-rich combustion exhaust for use in flame-assisted fuel cell testing. The development of the procedure and its applications and limitations are discussed.

  15. Combustion modeling in internal combustion engines

    NASA Technical Reports Server (NTRS)

    Zeleznik, F. J.

    1976-01-01

    The fundamental assumptions of the Blizard and Keck combustion model for internal combustion engines are examined and a generalization of that model is derived. The most significant feature of the model is that it permits the occurrence of unburned hydrocarbons in the thermodynamic-kinetic modeling of exhaust gases. The general formulas are evaluated in two specific cases that are likely to be significant in the applications of the model.

  16. Boiler using combustible fluid

    DOEpatents

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  17. Studies on Disinfection By-Products and Drinking Water

    USGS Publications Warehouse

    Rostad, Colleen E.

    2007-01-01

    Drinking water is disinfected with chemicals to remove pathogens, such as Giardia and Cryptosproridium, and prevent waterborne diseases such as cholera and typhoid. During disinfection, by-products are formed at trace concentrations. Because some of these by-products are suspected carcinogens, drinking water utilities must maintain the effectiveness of the disinfection process while minimizing the formation of by-products.

  18. Advanced Combustion and Fuels; NREL (National Renewable Energy Laboratory)

    SciTech Connect

    Zigler, Brad

    2015-06-08

    Presented at the U.S. Department of Energy Vehicle Technologies Office 2015 Annual Merit Review and Peer Evaluation Meeting, held June 8-12, 2015, in Arlington, Virginia. It addresses technical barriers of inadequate data and predictive tools for fuel and lubricant effects on advanced combustion engines, with the strategy being through collaboration, develop techniques, tools, and data to quantify critical fuel physico-chemical effects to enable development of advanced combustion engines that use alternative fuels.

  19. Lump wood combustion process

    NASA Astrophysics Data System (ADS)

    Kubesa, Petr; Horák, Jiří; Branc, Michal; Krpec, Kamil; Hopan, František; Koloničný, Jan; Ochodek, Tadeáš; Drastichová, Vendula; Martiník, Lubomír; Malcho, Milan

    2014-08-01

    The article deals with the combustion process for lump wood in low-power fireplaces (units to dozens of kW). Such a combustion process is cyclical in its nature, and what combustion facility users are most interested in is the frequency, at which fuel needs to be stoked to the fireplace. The paper defines the basic terms such as burnout curve and burning rate curve, which are closely related to the stocking frequency. The fuel burning rate is directly dependent on the immediate thermal power of the fireplace. This is also related to the temperature achieved in the fireplace, magnitude of flue gas losses and the ability to generate conditions favouring the full burnout of the fuel's combustible component, which, at once ensures the minimum production of combustible pollutants. Another part of the paper describes experiments conducted in traditional fireplaces with a grate, at which well-dried lump wood was combusted.

  20. Waste combustion in boilers and industrial furnaces

    SciTech Connect

    1996-12-31

    This publication contains technical papers published as they were presented at a recent specialty conference sponsored by the Air & Waste Management Association, titled Waste Combustion in Boilers and Industrial Furnaces, held March 26-27, 1996, in Kansas City, Missouri. Papers touch on compilance concerns for air pollution, air monitoring methodologies, risk assessment, and problems related to public anxiety. Separate abstracts have been indexed into the database from this proceedings.

  1. Fuels Combustion Research.

    DTIC Science & Technology

    1984-07-18

    uncertainties in the future sources and characteristics of fuels has emphasized the need to better understand fuel effects on combustion , e.g. energy release...experimentally to be made. Unsuccessful comparisons can lead to impro- vements in modelling concepts . Two simplified models for the combustion of slurry...AD-A149 186 FUELS COMBUSTION RESEACCH(U) PRINCETON UNIV NJ DEPT OF i/i MECHANICAL AND AEROSPACE ENGINEERING F L DRYER ET AL. 18 JUL 84 NAE-i668 AFOSR

  2. Coal combustion products

    USGS Publications Warehouse

    Kalyoncu, R.S.; Olson, D.W.

    2001-01-01

    Coal-burning powerplants, which supply more than half of U.S. electricity, also generate coal combustion products, which can be both a resource and a disposal problem. The U.S. Geological Survey collaborates with the American Coal Ash Association in preparing its annual report on coal combustion products. This Fact Sheet answers questions about present and potential uses of coal combustion products.

  3. Supersonic combustion engine and method of combustion initiation and distribution

    SciTech Connect

    Stickler, D.B.; Ballantyne, A.; Kyuman Jeong.

    1993-06-29

    A supersonic combustion ramjet engine having a combustor with a combustion zone intended to channel gas flow at relatively high speed therethrough, the engine comprising: means for substantially continuously supplying fuel into the combustion zone; and means for substantially instantaneously igniting a volume of fuel in the combustion zone for providing a spatially controlled combustion distribution, the igniting means having means for providing a diffuse discharge of energy into the volume, the volume extending across a substantially complete cross-sectional area of the combustion zone, the means for discharging energy being capable of generating free radicals within the volume of reactive fuel in the combustion zone such that fuel in the volume can initiate a controlled relatively rapid combustion of fuel in the combustion zone whereby combustion distribution in relatively high speed gas flows through the combustion zone can be initiated and controlled without dependence upon a flame holder or relatively high local static temperature in the combustion zone.

  4. Tripropellant combustion process

    NASA Technical Reports Server (NTRS)

    Kmiec, T. D.; Carroll, R. G.

    1988-01-01

    The addition of small amounts of hydrogen to the combustion of LOX/hydrocarbon propellants in large rocket booster engines has the potential to enhance the system stability. Programs being conducted to evaluate the effects of hydrogen on the combustion of LOX/hydrocarbon propellants at supercritical pressures are described. Combustion instability has been a problem during the development of large hydrocarbon fueled rocket engines. At the higher combustion chamber pressures expected for the next generation of booster engines, the effect of unstable combustion could be even more destructive. The tripropellant engine cycle takes advantage of the superior cooling characteristics of hydrogen to cool the combustion chamber and a small amount of the hydrogen coolant can be used in the combustion process to enhance the system stability. Three aspects of work that will be accomplished to evaluate tripropellant combustion are described. The first is laboratory demonstration of the benefits through the evaluation of drop size, ignition delay and burning rate. The second is analytical modeling of the combustion process using the empirical relationship determined in the laboratory. The third is a subscale demonstration in which the system stability will be evaluated. The approach for each aspect is described and the analytical models that will be used are presented.

  5. Droplet Combustion Experiment

    NASA Technical Reports Server (NTRS)

    Nayagam, Vedha

    1998-01-01

    Liquid fuel combustion provides a major portion of the world's energy supply. In most practical combustion devices, liquid burns after being separated into a droplet spray. Essential to the design of efficient combustion systems is a knowledge of droplet combustion behavior. The microgravity environment aboard spacecraft provides an opportunity to investigate the complex interactions between the physical and chemical combustion processes involved in droplet combustion without the complications of natural buoyancy. Launched on STS-83 and STS-94 (April 4 and July 1, 1997), the Droplet Combustion Experiment (DCE) investigated the fundamentals of droplet combustion under a range of pressures (0.25 to 1 atm), oxygen mole fractions (<0.5), and droplet sizes (1.5 to 5 mm). Principal DCE flight hardware features were a chamber to supply selected test environments, the use of crew-inserted bottles, and a vent system to remove unwanted gaseous combustion products. The internal apparatus contained the droplet deployment and ignition mechanisms to burn single, freely deployed droplets in microgravity. Diagnostics systems included a 35-mm high-speed motion picture camera (see the following sequence of photos) with a backlight to photograph burning droplets and a camcorder to monitor experiment operations. Additional diagnostics included an ultraviolet-light-sensitive CCD (charge couple discharge) camera to obtain flame radiation from hydroxyl radicals (see the final figure) and a 35-mm SLR (single-lens-reflex) camera to obtain color still photographs of the flames.

  6. Peanut by-products fed to cattle.

    PubMed

    Hill, Gary M

    2002-07-01

    Peanut by-products supply substantial quantities of feedstuffs to beef cattle grown in the same region where peanuts are produced. Included in the list of products fed to cattle are peanuts and peanut meal, peanut skins, peanut hulls, peanut hay, and silages. Residual peanut hay is by far the most widely used peanut by-product fed to beef cattle, and if it is properly harvested with minimal leaf shatter, it is comparable to good-quality grass hays in nutrient content. Peanut skins are often included in small quantities in cattle and pet foods, supplying both protein and energy. High tannin content of peanut skins can cause severe performance depressions in beef cattle if peanut skins are included at levels higher than 10% of the diet, unless diets contain relatively high CP (above 15% CP), or additional N sources are added such as ammonia or urea. Because dairy cattle diets are often above 16% CP in the total dietary DM, peanut skins may increase milk production when added at levels up to 16% of the dry matter. Peanut hulls are effectively used as a roughage source at levels up to 20% of beef finishing diets, for bedding in dairy cattle loafing sheds (if tested and found to contain low aflatoxin levels), and in a variety of manufactured products. Peanut hulls are economically priced because of their quantity, their inherent high fiber, and low CP content, and they should not be fed as a primary feedstuffs for beef cattle. Peanut by-products are generally priced below other by-products, and they can be incorporated into a variety of supplements and diets for cow herds, growing-finishing cattle, and dairy cattle.

  7. Disturbing effect of free hydrogen on fuel combustion in internal combustion engines

    NASA Technical Reports Server (NTRS)

    Riedler, A

    1923-01-01

    Experiments with fuel mixtures of varying composition, have recently been conducted by the Motor Vehicle and Airplane Engine Testing Laboratories of the Royal Technical High School in Berlin and at Fort Hahneberg, as well as at numerous private engine works. The behavior of hydrogen during combustion in engines and its harmful effect under certain conditions, on the combustion in the engine cylinder are of general interest. Some of the results of these experiments are given here, in order to elucidate the main facts and explain much that is already a matter of experience with chauffeurs and pilots.

  8. Indoor air quality environmental information handbook: Combustion sources

    SciTech Connect

    Not Available

    1990-06-01

    This environmental information handbook was prepared to assist both the non-technical reader (i.e., homeowner) and technical persons (such as researchers, policy analysts, and builders/designers) in understanding the current state of knowledge regarding combustion sources of indoor air pollution. Quantitative and descriptive data addressing the emissions, indoor concentrations, factors influencing indoor concentrations, and health effects of combustion-generated pollutants are provided. In addition, a review of the models, controls, and standards applicable to indoor air pollution from combustion sources is presented. The emphasis is on the residential environment. The data presented here have been compiled from government and privately-funded research results, conference proceedings, technical journals, and recent publications. It is intended to provide the technical reader with a comprehensive overview and reference source on the major indoor air quality aspects relating to indoor combustion activities, including tobacco smoking. In addition, techniques for determining potential concentrations of pollutants in residential settings are presented. This is an update of a 1985 study documenting the state of knowledge of combustion-generated pollutants in the indoor environment. 191 refs., 51 figs., 71 tabs.

  9. Production of manufactured aggregates from flue gas desulfurization by-products

    SciTech Connect

    Wu, M.M.; McCoy, D.C.; Fenger, M.L.; Scandrol, R.O.; Winschel, R.A.; Withum, J.A.; Statnick, R.M.

    1999-07-01

    CONSOL R and D has developed a disk pelletization process to produce manufactured aggregates from the by-products of various technologies designed to reduce sulfur emissions produced from coal utilization. Aggregates have been produced from the by-products of the Coolside and LIMB sorbent injection, the fluidized-bed combustion (FBC), spray dryer absorption (SDA), and lime and limestone wet flue gas desulfurization (FGD) processes. The aggregates produced meet the general specifications for use as road aggregate in road construction and for use as lightweight aggregate in concrete masonry units. Small field demonstrations with 1200 lb to 5000 lb of manufactured aggregates were conducted using aggregates produced from FBC ash and lime wet FGD sludge in road construction and using aggregates made from SDA ash and lime wet FGD sludge to manufacture concrete blocks. The aggregates for this work were produced with a bench-scale (200--400 lb batch) unit. In 1999, CONSOL R and D constructed and operated a 500 lb/hr integrated, continuous pilot plant. A variety of aggregate products were produced from lime wet FGD sludge. The pilot plant test successfully demonstrated the continuous, integrated operation of the process. The pilot plant demonstration was a major step toward commercialization of manufactured aggregate production from FGD by-products. In this paper, progress made in the production of aggregates from dry FGD (Coolside, LIMB, SDA) and FBC by-products, and lime wet FGD sludge is discussed. The discussion covers bench-scale and pilot plant aggregate production and aggregate field demonstrations.

  10. A Study on Removal of Rare Earth Elements from U.S. Coal Byproducts by Ion Exchange

    NASA Astrophysics Data System (ADS)

    Rozelle, Peter L.; Khadilkar, Aditi B.; Pulati, Nuerxida; Soundarrajan, Nari; Klima, Mark S.; Mosser, Morgan M.; Miller, Charles E.; Pisupati, Sarma V.

    2016-03-01

    Rare earth elements are known to occur in low concentrations in U.S. coals and coal byproducts. These low concentrations may make rare earth element recovery from these materials unattractive, using only physical separation techniques. However, given the significant production of rare earths through ion exchange extraction in China, two U.S. coal byproducts were examined for ion extraction, using ammonium sulfate, an ionic liquid, and a deep eutectic solvent as lixiviants. Extraction of rare earth elements in each case produced high recoveries of rare earth elements to the solution. This suggests that in at least the cases of the materials examined, U.S. coal byproducts may be technically suitable as REE ores. More work is required to establish economic suitability.

  11. Technical writing versus technical writing

    NASA Technical Reports Server (NTRS)

    Dillingham, J. W.

    1981-01-01

    Two terms, two job categories, 'technical writer' and 'technical author' are discussed in terms of industrial and business requirements and standards. A distinction between 'technical writing' and technical 'writing' is made. The term 'technical editor' is also considered. Problems inherent in the design of programs to prepare and train students for these jobs are discussed. A closer alliance between industry and academia is suggested as a means of preparing students with competent technical communication skills (especially writing and editing skills) and good technical skills.

  12. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal fired boilers. Second quarterly technical progress report, [April--June 1993

    SciTech Connect

    Not Available

    1993-12-31

    The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. Baseline, AOFA, and LNB without AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO{sub x} emission levels to be approximately 0.65 lb/MBtu with flyash LOI values of approximately 8 percent. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. For comparison, the long-term full-load, baseline NO{sub x} emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing of the LNB plus AOFA configuration began in May 1993 and is scheduled to end during August 1993. As of June 30, the diagnostic, performance, chemical emissions tests segments for this configuration have been conducted and 29 days of long-term, emissions data collected. Preliminary results from the May--June 1993 tests of the LNB plus AOFA system show that the full load NO{sub x} emissions are approximately 0.42 lb/MBtu with corresponding fly ash LOI values near 8 percent. This is a substantial improvement in both NO{sub x} emissions and LOI values when compared to the results obtained during the February--March 1992 abbreviated testing of this system.

  13. Fifteenth combustion research conference

    SciTech Connect

    1993-06-01

    The BES research efforts cover chemical reaction theory, experimental dynamics and spectroscopy, thermodynamics of combustion intermediates, chemical kinetics, reaction mechanisms, combustion diagnostics, and fluid dynamics and chemically reacting flows. 98 papers and abstracts are included. Separate abstracts were prepared for the papers.

  14. Coal Combustion Science

    SciTech Connect

    Hardesty, D.R.; Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. )

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  15. Plasma Assisted Combustion

    DTIC Science & Technology

    2007-02-28

    2005) AIAA–2005–0405. [99] E.M. Van Veldhuizen (ed) Electrical Discharges for Environmental Purposes: Fun- damentals and Applications (New York: Nova...in russian), 18, 4, 1982, 48-51. [238] Combustion Chemestry , ed. W. Gardiner-Jr, Moscow, Mir, 1988. [239] G.P.Tewari, J.R.Wilson, Combust. Flame, 24

  16. Japan's microgravity combustion science program

    NASA Technical Reports Server (NTRS)

    Sato, Junichi

    1993-01-01

    Most of energy used by us is generated by combustion of fuels. On the other hand, combustion is responsible for contamination of our living earth. Combustion, also, gives us damage to our life as fire or explosive accidents. Therefore, clean and safe combustion is now eagerly required. Knowledge of the combustion process in combustors is needed to achieve proper designs that have stable operation, high efficiency, and low emission levels. However, current understanding on combustion is far from complete. Especially, there is few useful information on practical liquid and solid particle cloud combustion. Studies on combustion process under microgravity condition will provide many informations for basic questions related to combustors.

  17. Pulsed atmospheric fluidized bed combustion

    SciTech Connect

    Not Available

    1989-11-01

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  18. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 7, October 1990--December 1990

    SciTech Connect

    Hargrove, M.J.; Chow, O.K.; Nsakala, N.Y.

    1991-02-01

    During the fourth quarter of 1990, the following technical progress was made: (1) Calculated the kinetic characteristics of chars from the combustion of microbubble flotation beneficiated products; (2) continued drop tube combustion tests of the spherical oil agglomeration beneficiated products; (3) analyzed the data from three (MIT) pilot-scale combustion tests of the Upper Freeport feed coal; and (4) continued analyses of the data from the CE pilot-scale tests of nine fuels.

  19. Combustion Dynamics Behavior in a Single-Element Lean Direct Injection (LDI) Gas Turbine Combustor

    DTIC Science & Technology

    2014-06-01

    Technical Paper 3. DATES COVERED (From - To) June 2014- July 2014 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER In-House Combustion Dynamics Behavior in a...excited combustion dynamics in a model configuration of a lean direct injection (LDI) gas turbine combustor is described. Incoming air temperature and...detailed study of the underlying combustion dynamics mechanisms. First, hydrodynamic modes are investigated by conducting the simulation with an

  20. Prediction of Combustion-Driven Dynamic Instability for High Performance Gas Turbine Combustors: Part I

    DTIC Science & Technology

    2001-06-01

    Hsiao, G., Pandalai, R., Hura, H., and Mongia , H. C., "Chropulsio a p e -Vol. o mbustor, 1998. " Combustion Dynamic Modeling for Gas Turbine...UNCLASSIFIED Defense Technical Information Center Compilation Part Notice ADPO 11162 TITLE: Predicton of Combustion -Driven Dynamic Instability for...UNCLASSIFIED , Click here to view PowerPoint presentation; Press Esc to exit ,: Prediction of Combustion -Driven Dynamic Instability For High Performance Gas

  1. FY2011 Annual Progress Report for Advanced Combustion Engine Research and Development

    SciTech Connect

    none,

    2011-12-01

    Annual Progress Report for the Advanced Combustion Engine Research and Development (R&D) subprogram supporting the mission of the Vehicle Technologies Program by removing the critical technical barriers to commercialization of advanced internal combustion engines (ICEs) for passenger and commercial vehicles that meet future federal emissions regulations.

  2. Chemical Kinetic Modeling of Biofuel Combustion

    NASA Astrophysics Data System (ADS)

    Sarathy, Subram Maniam

    Bioalcohols, such as bioethanol and biobutanol, are suitable replacements for gasoline, while biodiesel can replace petroleum diesel. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This study's contribution is experimentally validated chemical kinetic combustion mechanisms for biobutanol and biodiesel. Fundamental combustion data and chemical kinetic mechanisms are presented and discussed to improve our understanding of biofuel combustion. The net environmental impact of biobutanol (i.e., n-butanol) has not been studied extensively, so this study first assesses the sustainability of n-butanol derived from corn. The results indicate that technical advances in fuel production are required before commercializing biobutanol. The primary contribution of this research is new experimental data and a novel chemical kinetic mechanism for n-butanol combustion. The results indicate that under the given experimental conditions, n-butanol is consumed primarily via abstraction of hydrogen atoms to produce fuel radical molecules, which subsequently decompose to smaller hydrocarbon and oxygenated species. The hydroxyl moiety in n-butanol results in the direct production of the oxygenated species such as butanal, acetaldehyde, and formaldehyde. The formation of these compounds sequesters carbon from forming soot precursors, but they may introduce other adverse environmental and health effects. Biodiesel is a mixture of long chain fatty acid methyl esters derived from fats and oils. This research study presents high quality experimental data for one large fatty acid methyl ester, methyl decanoate, and models its combustion using an improved skeletal mechanism. The results indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which ultimately lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular

  3. Alternate Fuels Combustion Research

    DTIC Science & Technology

    1984-07-01

    AFWAL-TR-84-2042 ESL-TR-84-29 ALTERNATE FUELS COMBUSTION RESEARCH 0) PRATT & WHITNEY CANADA MISSISSAUGA, ONTARIO CANADA In JULY 1984 Final Report for...in small engincs. -291 REFERENCES 1. Gratton, M., Sampath, P., " Alternate Fuels Combustion Research Phase If", Pratt & Whitney Canada , AFWAL-TR-83-2057...for Period May 80 Sep e ALTERNATE FUELS COMBUSTION RESEARCHMa80-Sp3 4. PERFORMING ORIJ. REPORT NUMBER 7. AUTNOR(s) 4. 60ONTRA-CT-WI GANUMNER(s) *M

  4. Co-combustion of coal and sewage sludge: chemical and ecotoxicological properties of ashes.

    PubMed

    Barbosa, Rui; Lapa, Nuno; Boavida, Dulce; Lopes, Helena; Gulyurtlu, Ibrahim; Mendes, Benilde

    2009-10-30

    The co-combustion of sewage sludge (SS) and coal is widely used for the treatment and thermal valorization of SS produced in wastewater treatment plants. The chemical and ecotoxicological properties of the ashes produced in this thermal treatment have not been fully studied. Two combustion tests were performed in a fluidized bed combustor. Colombian coal was used as fuel in test A. A blend (1+1) of this coal and a stabilized SS (Biogran) was used in a second test B. Samples of the bottom and fly ashes trapped in two sequential cyclones were collected. The characterization of the ashes was focused on two main aspects: (1) the bulk content of a set of metals and (2) the characterization of eluates produced according to the European Standard leaching test EN 12457-2. The eluates were submitted to an ecotoxicological characterization for two bio-indicators. In what concerns the bulk content of ashes, both combustion tests have produced ashes with different compositions. The ashes formed during the co-combustion test have shown higher concentrations of metals, namely Cr, Cu, Ni, Pb, Zn and Fe for all ashes. The leaching test has shown low mobility of these elements from the by-products produced during the combustion and co-combustion tests. Cr and Cr(VI) were mainly detected in the eluates of the 1st cyclone ashes produced in both combustion tests and in the 2nd cyclone ashes produced in the co-combustion test. Considering the ecotoxicity assays, the eluates of bottom and fly ashes for both combustion and co-combustion tests have shown low ecotoxic levels. The micro-crustacean Daphnia magna was generally more sensitive than the bacterium Vibrio fischeri. CEMWE criterion has allowed to classify the bottom ashes for both combustion and co-combustion tests as non-toxic residues and the fly ashes collected in both cyclones as toxic.

  5. Energy recycling by co-combustion of coal and recovered paint solids from automobile paint operations.

    PubMed

    Suriyawong, Achariya; Magee, Rogan; Peebles, Ken; Biswas, Pratim

    2009-05-01

    During the past decade, there has been substantial interest in recovering energy from many unwanted byproducts from industries and municipalities. Co-combustion of these products with coal seems to be the most cost-effective approach. The combustion process typically results in emissions of pollutants, especially fine particles and trace elements. This paper presents the results of an experimental study of particulate emission and the fate of 13 trace elements (arsenic [As], barium [Ba], cadmium [Cd], chromium [Cr], copper [Cu], cobalt [Co], manganese [Mn], molybdenum [Mo], nickel [Ni], lead [Pb], mercury [Hg], vanadium [V], and zinc [Zn]) during combustion tests of recovered paint solids (RPS) and coal. The emissions from combustions of coal or RPS alone were compared with those of co-combustion of RPS with subbituminous coal. The distribution/partitioning of these toxic elements between a coarse-mode ash (particle diameter [dp] > 0.5 microm), a submicrometer-mode ash (dp < 0.5 microm), and flue gases was also evaluated. Submicrometer particles generated by combustion of RPS alone were lower in concentration and smaller in size than that from combustion of coal. However, co-combustion of RPS and coal increased the formation of submicrometer-sized particles because of the higher reducing environment in the vicinity of burning particles and the higher volatile chlorine species. Hg was completely volatilized in all cases; however, the fraction in the oxidized state increased with co-combustion. Most trace elements, except Zn, were retained in ash during combustion of RPS alone. Mo was mostly retained in all samples. The behavior of elements, except Mn and Mo, varied depending on the fuel samples. As, Ba, Cr, Co, Cu, and Pb were vaporized to a greater extent from cocombustion of RPS and coal than from combustion of either fuel. Evidence of the enrichment of certain toxic elements in submicrometer particles has also been observed for As, Cd, Cr, Cu, and Ni during co-combustion.

  6. Dry low combustion system with means for eliminating combustion noise

    DOEpatents

    Verdouw, Albert J.; Smith, Duane; McCormick, Keith; Razdan, Mohan K.

    2004-02-17

    A combustion system including a plurality of axially staged tubular premixers to control emissions and minimize combustion noise. The combustion system includes a radial inflow premixer that delivers the combustion mixture across a contoured dome into the combustion chamber. The axially staged premixers having a twist mixing apparatus to rotate the fluid flow and cause improved mixing without causing flow recirculation that could lead to pre-ignition or flashback.

  7. Glycerol combustion and emissions

    EPA Science Inventory

    With the growing capacity in biodiesel production and the resulting glut of the glycerol by-product, there is increasing interest in finding alternative uses for crude glycerol. One option may be to burn it locally for combined process heat and power, replacing fossil fuels and i...

  8. "Technical" Writing vs. Technical "Writing."

    ERIC Educational Resources Information Center

    Dillingham, J. W.

    Technical writers must have a working knowledge of technology in order to rearrange material others provide, but they do not have the expertise needed to originate materials; that is the job of the technical author. Another job function is that of technical editor--a person who can write, can perform the policy making tasks of an editor, and who…

  9. Combustion Technology Outreach

    NASA Technical Reports Server (NTRS)

    1995-01-01

    Lewis' High Speed Research (HSR) Propulsion Project Office initiated a targeted outreach effort to market combustion-related technologies developed at Lewis for the next generation of supersonic civil transport vehicles. These combustion-related innovations range from emissions measurement and reduction technologies, to diagnostics, spray technologies, NOx and SOx reduction of burners, noise reduction, sensors, and fuel-injection technologies. The Ohio Aerospace Institute and the Great Lakes Industrial Technology Center joined forces to assist Lewis' HSR Office in this outreach activity. From a database of thousands of nonaerospace firms considered likely to be interested in Lewis' combustion and emission-related technologies, the outreach team selected 41 companies to contact. The selected companies represent oil-gas refineries, vehicle/parts suppliers, and manufacturers of residential furnaces, power turbines, nonautomobile engines, and diesel internal combustion engines.

  10. Fluidized coal combustion

    NASA Technical Reports Server (NTRS)

    Moynihan, P. I.; Young, D. L.

    1979-01-01

    Fluidized-bed coal combustion process, in which pulverized coal and limestone are burned in presence of forced air, may lead to efficient, reliable boilers with low sulfur dioxide and nitrogen dioxide emissions.

  11. Studies in premixed combustion

    SciTech Connect

    Sivashinsky, G.I.

    1992-01-01

    This report discusses the following topics on premixed combustion: theory of turbulent flame propagation; pattern formation in premixed flames and related problems; and pattern formation in extended systems. (LSP)

  12. TENORM: Coal Combustion Residuals

    EPA Pesticide Factsheets

    Burning coal in boilers to create steam for power generation and industrial applications produces a number of combustion residuals. Naturally radioactive materials that were in the coal mostly end up in fly ash, bottom ash and boiler slag.

  13. Dynamic effects of combustion

    NASA Technical Reports Server (NTRS)

    Oppenheim, A. K.

    1982-01-01

    The dynamic effects of combustion are due to the evolution of exothermic energy and its deposition in the compressible medium where the process takes place. The paper examines the dynamics of combustion phenomena, including ignition, turbulent flame propagation (inflammation), explosion, and detonation, with emphasis on their exothermic characteristics. Ignition and explosion are treated as problems of nonlinear mechanics, and their dynamic behavior is described in terms of phase space models and cinematographic laser shear interferograms. The results of a numerical random vortex model of turbulent flame propagation are confirmed in a combustion tunnel experiment, where it was observed that a fresh mixture of burnt and unburnt gases can sustain combustion with a relatively small expenditure of overall mass flow, due to the increasing specific volume of burnt gases inside the flame front. An isentropic pressure wave is found to precede the accelerating flame in the process of detonation, and components of this presssure wave are shown to propagate at local sonic velocities.

  14. Electrical and Electronics Technical Team Roadmap

    SciTech Connect

    2013-06-01

    The Electrical and Electronics Technical Team’s (EETT's) mission is to enable cost-effective, smaller, lighter, and efficient power electronics and electric motors for electric traction drive systems (ETDSs) while maintaining performance of internal combustion engine (ICE)-based vehicles. The EETT also identifies technology gaps, establishes R&D targets, develops a roadmap to achieve technical targets and goals, and evaluates the R&D progress toward meeting the established R&D targets and goals.

  15. Generalities on combustion instabilities

    NASA Astrophysics Data System (ADS)

    Kuentzmann, Paul

    The main manifestations of combustion instabilities are reviewed, and the specific characteristics of instabilities in solid-propellant rocket engines are analyzed, with the Minuteman III third-stage engine and the SRB engine of Titan 34 D considered as examples. The main approaches for predicting combustion instabilities are discussed, including the linear approach based on the acoustic balance, the nonlinear mode-coupling approach, and the nonlinear approach using numerical calculation. Projected directions for future research are also examined.

  16. Scramjet Combustion Processes

    DTIC Science & Technology

    2010-09-01

    plan for these flights is as follows: Scramjet Combustion Processes RTO-EN-AVT-185 11 - 21 HyShot 5 – A Free-Flying Hypersonic Glider HyShot...5 will be a hypersonic glider designed to fly at Mach 8. It will separate from its rocket booster in space and perform controlled manoeuvres as it...RTO-EN-AVT-185 11 - 1 Scramjet Combustion Processes Michael Smart and Ray Stalker Centre for Hypersonics The University of Queensland

  17. ABB Combustion Engineering`s nuclear experience and technologies

    SciTech Connect

    Matzie, R.A.

    1994-12-31

    ABB Combustion Engineering`s nuclear experience and technologies are outlined. The following topics are discussed: evolutionary approach using proven technology, substantial improvement to plant safety, utility perspective up front in developing design, integrated design, competitive plant cost, operability and maintainability, standardization, and completion of US NRC technical review.

  18. Sandia Combustion Research Program

    SciTech Connect

    Johnston, S.C.; Palmer, R.E.; Montana, C.A.

    1988-01-01

    During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

  19. Coal combustion system

    DOEpatents

    Wilkes, Colin; Mongia, Hukam C.; Tramm, Peter C.

    1988-01-01

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  20. Diagnostics of automatic compensators of valve clearance in combustion engine with the use of vibration signal

    NASA Astrophysics Data System (ADS)

    Szymański, Grzegorz M.; Tomaszewski, Franciszek

    2016-02-01

    Dynamic development of internal combustion engines creates a need to adopt a strategy concerning operational use of these driving units based on the knowledge of their technical condition. The assessment of technical condition belongs to tasks of technical diagnostics. This article presents an analysis of issues concerning vibration diagnostics of automatic compensators of clearances in piston valves of combustion engine. Scientific experiments focused on delivering information necessary to create (and also to validate) diagnostic models enabling assessment of technical condition of those elements of combustion engine that are essential taking into account effectiveness and durability that were carried out and described here. On the basis of the worked out diagnostic model, the algorithm for assessment of the technical condition of automatic compensators of valve clearance was created.

  1. Characterization of products from fluidized-bed combustion of coal.

    PubMed

    Bednarik, V; Vondruska, M; Sild, M; Vondruskova, E

    2000-11-01

    The technology of fluidized-bed combustion (FBC) of coal generates byproducts that have a series of unique characteristics and potential uses in technological practice. In this study, the products of fluidized-bed combustion (FBC-P) of coal derived from Moravian heat stations, a.s. Zlin, Cinergy Global Resources, Czech Republic, were characterized. Particular attention was paid to determining the chemical composition of FBC-P, the content of polycyclic aromatic hydrocarbons (PAHs) and toxic metals in the water leachates of these FBC-P, the content of unburned carbon, the capability of FBC-P to solidify with water and form a solid matrix, and the method for discovering optimum mixing water content for FBC-P solidification. The results suggest that one of the qualitatively more important means of utilizing FBC-P could be their application during solidification/stabilization (S/S) of wastes, particularly wastewater treatment sludges.

  2. A clean coal combustion technology-slagging combustors

    SciTech Connect

    Chang, S. L.; Berry, G. F.

    1989-03-01

    Slagging combustion is an advanced clean coal technology technique characterized by low NOx and SOx emission, high combustion efficiency, high ash removal, simple design and compact size. The design of slagging combustors has operational flexibility for a wide range of applications, including retrofitting boilers, magnetohydrodynamic combustors, coal-fired gas turbines, gasifiers and hazardous waste incinerators. In recent years, developers of slagging combustors have achieved encouraging progress toward the commercialization of this technology. Although there is a diversity of technical approaches among the developers, they all aim for a compact design of pulverized coal combustion with high heat release and sub-stoichiometric combustion regimes of operation to suppress NOx formation, and most aim to capture sulfur by using sorbent injection in the combustor. If the present pace toward commercialization continues, retrofitting boilers of sizes ranging from 20 to 250 MMBtu/hr (5.9 to 73 MWt) may be available for commercial use in the 1990's. 18 refs., 2 figs.

  3. Improved low NOx firing systems for pulverized coal combustion

    SciTech Connect

    McCarthy, K.; Laux, S.; Grusha, J.; Rosin, T.; Hausman, G.L.

    1999-07-01

    More stringent emission limits or the addition of post combustion NOx control create the need for improvements of NOx emissions from pulverized coal boilers. Many boilers retrofitted with Low NOx technology during Phase 1 and Phase 2 of the CAAA fail or marginally meet their requirements. Technical solutions range from addition of overfire air and state-of-the-art low NOx burners to low cost additions of combustion enhancements. Regardless of the combustion NOx control method used, stoichiometries local to the burners must be maintained at the designed values at all times to provide high NOx performance at low efficiency loss due to unburned fuel. This paper describes Foster Wheeler's approach to NOx emission improvements for existing low NOx firing systems. The technology to measure air and coal flow individually for each burner and to control the parameters for optimum combustion are presented and discussed. Field experience shows the installation and advantages of the technology.

  4. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on Combustion Characterization of Beneficiated Coal-Based Fuels.'' The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE's laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  5. Microgravity combustion experiment using high altitude balloon.

    NASA Astrophysics Data System (ADS)

    Kan, Yuji

    In JAXA, microgravity experiment system using a high altitude balloon was developed , for good microgravity environment and short turn-around time. In this publication, I give an account of themicrogravity experiment system and a combustion experiment to utilize the system. The balloon operated vehicle (BOV) as a microgravity experiment system was developed from 2004 to 2009. Features of the BOV are (1) BOV has double capsule structure. Outside-capsule and inside-capsule are kept the non-contact state by 3-axis drag-free control. (2) The payload is spherical shape and itsdiameter is about 300 mm. (3) Keep 10-4 G level microgravity environment for about 30 seconds However, BOV’s payload was small, and could not mount large experiment module. In this study, inherits the results of past, we established a new experimental system called “iBOV” in order toaccommodate larger payload. Features of the iBOV are (1) Drag-free control use for only vertical direction. (2) The payload is a cylindrical shape and its size is about 300 mm in diameter and 700 mm in height. (3) Keep 10-3-10-4 G level microgravity environment for about 30 seconds We have "Observation experiment of flame propagation behavior of the droplets column" as experiment using iBOV. This experiment is a theme that was selected first for technical demonstration of iBOV. We are conducting the flame propagation mechanism elucidation study of fuel droplets array was placed at regular intervals. We conducted a microgravity experiments using TEXUS rocket ESA and drop tower. For this microgravity combustion experiment using high altitude balloon, we use the Engineering Model (EM) for TEXUS rocket experiment. The EM (This payload) consists of combustion vessel, droplets supporter, droplets generator, fuel syringe, igniter, digital camera, high-speed camera. And, This payload was improved from the EM as follows. (1) Add a control unit. (2) Add inside batteries for control unit and heater of combustion

  6. The use of a coal combustion by-product as substrate for oyster reef development

    SciTech Connect

    Andrews, R.S.; Alden, R.W. III; Luckenbach, M.

    1997-07-01

    In 1994, a multi-year study was initiated to determine the feasibility as well as the environmental acceptability of using pellets produced from fly ash from Virginia Power`s Chesapeake Energy Center (CEC). The intent of the study was to demonstrate a beneficial use for the fly ash that would compensate for natural reef losses by providing an alternate substrate for oyster attachment in the Chesapeake Bay. The results of the study indicate that pellets made from a mixture of approximately 88% CEC fly ash and 12% Type II Portland Cement are environmentally safe and facilitate the settlement, attachment and growth of oysters.

  7. Utilization of low NOx coal combustion by-products. Quarterly report, July 1--September 30, 1996

    SciTech Connect

    1996-12-31

    The objective of this project was to commercialize fly ash beneficiation at various facilities around the country. The paper describes laboratory characterization of fly ash samples, pilot plant testing, product testing, and market and economic analyses. Products include concrete, concrete blocks and bricks, plastic fillers, activated carbon, and metal matrix composites.

  8. Speciation and Attenuation of Arsenic and Selenium at Coal Combustion By-Product Management Facilities

    SciTech Connect

    K. Ladwig; B. Hensel; D. Wallschlager; L. Lee; I. Murarka

    2005-10-18

    Following completion of contracting activities, sites were identified for the field leachate characterization study. Sampling and Analyses Plans (SAPs) and Site Access Agreements (SAAs) were developed for each site. A total of ten sites were sampled during this reporting period. Among the trace constituents, boron, silicon, and strontium were present in highest concentrations, with median values above 1 mg/L (1,000 {micro}g/L). Work on the first of three sites for the detailed arsenic and selenium adsorption studies began in 2002, prior to completion of the final DOE award. Kd values ranged from 100 to 12,000 L/kg for arsenic (V), 15 to 160 L.kg for As(III), and 5 to 25 L/kg for Se(VI).

  9. Microgravity Combustion Research: 1999 Program and Results

    NASA Technical Reports Server (NTRS)

    Friedman, Robert (Editor); Gokoglu, Suleyman A. (Editor); Urban, David L. (Editor)

    1999-01-01

    The use of the microgravity environment of space to expand scientific knowledge and to enable the commercial development of space for enhancing the quality of life on Earth is particularly suitable to the field of combustion. This document reviews the current status of microgravity combustion research and derived information. It is the fourth in a series of timely surveys, all published as NASA Technical Memoranda, and it covers largely the period from 1995 to early 1999. The scope of the review covers three program areas: fundamental studies, applications to fire safety and other fields. and general measurements and diagnostics. The document also describes the opportunities for Principal Investigator participation through the NASA Research Announcement program and the NASA Glenn Research Center low-gravity facilities available to researchers.

  10. Characterization of a fluidized-bed combustion ash to determine potential for environmental impact. Final report

    SciTech Connect

    Hassett, D.J.; Henderson, A.K.; Pflughoeft-Hassett, D.F.; Mann, M.D.; Eylands, K.E.

    1997-10-01

    A 440-megawatt, circulating fluidized-bed combustion (CFBC), lignite-fired power plant is planned for construction in Choctaw County north of Ackerman, Mississippi. This power plant will utilize Mississippi lignite from the first lignite mine in that state. Malcolm Pirnie, Inc., is working with the power plant developer in the current planning and permitting efforts for this proposed construction project. In order to accommodate Mississippi state regulatory agencies and meet appropriate permit requirements, Malcolm Pirnie needed to provide an indication of the characteristics of the by-products anticipated to be produced at the proposed plant. Since the Mississippi lignite is from a newly tapped mine and the CFBC technology is relatively new, Malcolm Pirnie contacted with the Energy and Environmental Research Center (EERC) to develop and perform a test plan for the production and characterization of ash similar to ash that will be eventually produced at the proposed power plant. The work performed at the EERC included two primary phases: production of by-products in a bench-scale CFBC unit using lignite provided by Malcolm Pirnie with test conditions delineated by Malcolm Pirnie to represent expected operating conditions for the full-scale plant; and an extensive characterization of the by-products produced, focusing on Mississippi regulatory requirements for leachability, with the understanding that return of the by-product to the mine site was an anticipated by-product management plan. The overall focus of this project was the environmental assessment of the by-product expected to be produced at the proposed power plant. Emphasis was placed on the leachability of potentially problematic trace elements in the by-products. The leaching research documented in this report was performed to determine trends of leachability of trace elements under leaching conditions appropriate for evaluating land disposal in monofills, such as returning the by-products to the mine

  11. ALKALINITY, PH, AND COPPER CORROSION BY-PRODUCT RELEASE

    EPA Science Inventory

    Contrary to expectations, higher bicarbonate concentrations exacerbate copper corrosion rates and by-product release. In fact, as illustrated by monitoring experiences of large utilities and by laboratory data, the concentration of copper corrosion by-products in drinking water i...

  12. Pollution monitoring system. [photographic laboratory by-products

    NASA Technical Reports Server (NTRS)

    Goodding, R. A.

    1973-01-01

    An investigation was undertaken to identify those photographic laboratory by-products which can produce harmful reactions if released untreated. After identification of these by-products, specific monitoring systems for each of the offending ions were investigated and recommendations for implementation are presented. Appropriate monitoring systems are discussed.

  13. Conversion of cotton byproducts to mixed cellulose esters

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cotton byproducts, such as cotton burr and cottonseed hull, can be used as low-cost feedstock for the production of specialty chemicals. The conversion of these cellulosic byproducts into mixed cellulose esters, e.g., cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB), was stud...

  14. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 17, April--June 1993

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1993-08-01

    Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Completed modeling calculations of coal mineral matter transformations, deposition behavior, and heat transfer impacts of six test fuels; and ran pilot-scale tests of Upper Freeport feed coal, microagglomerate product, and mulled product.

  15. Hazard assessment of nitrosamine and nitramine by-products of amine-based CCS: alternative approaches.

    PubMed

    Buist, H E; Devito, S; Goldbohm, R A; Stierum, R H; Venhorst, J; Kroese, E D

    2015-04-01

    Carbon capture and storage (CCS) technologies are considered vital and economic elements for achieving global CO2 reduction targets, and is currently introduced worldwide (for more information on CCS, consult for example the websites of the International Energy Agency (http://www.iea.org/topics/ccs/) and the Global CCS Institute (http://www.globalccsinstitute.com/)). One prominent CCS technology, the amine-based post-combustion process, may generate nitrosamines and their related nitramines as by-products, the former well known for their potential mutagenic and carcinogenic properties. In order to efficiently assess the carcinogenic potency of any of these by-products this paper reviews and discusses novel prediction approaches consuming less time, money and animals than the traditionally applied 2-year rodent assay. For this, available animal carcinogenicity studies with N-nitroso compounds and nitramines have been used to derive carcinogenic potency values, that were subsequently used to assess the predictive performance of alternative prediction approaches for these chemicals. Promising cancer prediction models are the QSARs developed by the Helguera group, in vitro transformation assays, and the in vivo initiation-promotion, and transgenic animal assays. All these models, however, have not been adequately explored for this purpose, as the number of N-nitroso compounds investigated is yet too limited, and therefore further testing with relevant N-nitroso compounds is needed.

  16. Advanced Subsonic Combustion Rig

    NASA Technical Reports Server (NTRS)

    Lee, Chi-Ming

    1998-01-01

    Researchers from the NASA Lewis Research Center have obtained the first combustion/emissions data under extreme future engine operating conditions. In Lewis' new world-class 60-atm combustor research facility--the Advanced Subsonic Combustion Rig (ASCR)--a flametube was used to conduct combustion experiments in environments as extreme as 900 psia and 3400 F. The greatest challenge for combustion researchers is the uncertainty of the effects of pressure on the formation of nitrogen oxides (NOx). Consequently, U.S. engine manufacturers are using these data to guide their future combustor designs. The flametube's metal housing has an inside diameter of 12 in. and a length of 10.5 in. The flametube can be used with a variety of different flow paths. Each flow path is lined with a high-temperature, castable refractory material (alumina) to minimize heat loss. Upstream of the flametube is the injector section, which has an inside diameter of 13 in. and a length of 0.5-in. It was designed to provide for quick changeovers. This flametube is being used to provide all U.S. engine manufacturers early assessments of advanced combustion concepts at full power conditions prior to engine production. To date, seven concepts from engine manufacturers have been evaluated and improved. This collaborated development can potentially give U.S. engine manufacturers the competitive advantage of being first in the market with advanced low-emission technologies.

  17. Environmentally conscious coal combustion

    SciTech Connect

    Hickmott, D.D.; Brown, L.F.; Currier, R.P.

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  18. Microgravity Combustion Diagnostics Workshop

    NASA Technical Reports Server (NTRS)

    Santoro, Gilbert J. (Editor); Greenberg, Paul S. (Editor); Piltch, Nancy D. (Editor)

    1988-01-01

    Through the Microgravity Science and Applications Division (MSAD) of the Office of Space Science and Applications (OSSA) at NASA Headquarters, a program entitled, Advanced Technology Development (ATD) was promulgated with the objective of providing advanced technologies that will enable the development of future microgravity science and applications experimental flight hardware. Among the ATD projects one, Microgravity Combustion Diagnostics (MCD), has the objective of developing advanced diagnostic techniques and technologies to provide nonperturbing measurements of combustion characteristics and parameters that will enhance the scientific integrity and quality of microgravity combustion experiments. As part of the approach to this project, a workshop was held on July 28 and 29, 1987, at the NASA Lewis Research Center. A small group of laser combustion diagnosticians met with a group of microgravity combustion experimenters to discuss the science requirements, the state-of-the-art of laser diagnostic technology, and plan the direction for near-, intermediate-, and long-term programs. This publication describes the proceedings of that workshop.

  19. Combustion chamber noise suppressor

    SciTech Connect

    Livingston, A.M.

    1986-08-19

    A combustion chamber is described for a hot fog generating machine comprising a hollow cylindrical combustion chamber shell having a closure plate at one end and outlet means at the opposite end for directing hot combustion gasses to a fogging nozzle, air inlet means disposed adjacent the outlet means, fuel inlet means and ignition means mounted in the closure plate and liner means disposed concentrically within the cylindrical combustion chamber for controlling the flow of air and combustion gasses within the shell. The liner means includes a liner base having a frustroconical configuration with the smaller diameter end thereof disposed in communication with the outlet means and with the larger diameter end thereof disposed in spaced relation to the shell, circumferentially spaced, longitudinally extending fins extending outwardly from the liner base intermediate the liner base and the shell, a cylindrical liner midsection having circumferentially spaced fins extending outwardly therefrom between the midsection and the shell with the fins supporting the midsection on the larger diameter end of the liner base.

  20. Combustion in fluidized beds

    SciTech Connect

    Dry, F.J.; La Nauze, R.D. )

    1990-07-01

    Circulating fluidized-bed (CFB) combustion systems have become popular since the late 1970s, and, given the current level of activity in the area,it is clear that this technology has a stable future in the boiler market. For standard coal combustion applications, competition is fierce with mature pulverized-fuel-based (PF) technology set to maintain a strong profile. CFB systems, however, can be more cost effective than PF systems when emission control is considered, and, as CFB technology matures, it is expected that an ever-increasing proportion of boiler installations will utilize the CFB concept. CFB systems have advantages in the combustion of low-grade fuels such as coal waste and biomass. In competition with conventional bubbling beds, the CFB boiler often demonstrates superior carbon burn-out efficiency. The key to this combustion technique is the hydrodynamic behavior of the fluidized bed. This article begins with a description of the fundamental fluid dynamic behavior of the CFB system. This is followed by an examination of the combustion process in such an environment and a discussion of the current status of the major CFB technologies.

  1. 10 CFR 35.2647 - Records of additional technical requirements for mobile remote afterloader units.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Records of additional technical requirements for mobile remote afterloader units. 35.2647 Section 35.2647 Energy NUCLEAR REGULATORY COMMISSION MEDICAL USE OF BYPRODUCT MATERIAL Records § 35.2647 Records of additional technical requirements for mobile...

  2. TECHNICAL EDUCATION.

    ERIC Educational Resources Information Center

    FRIGIOLA, NICHOLAS F.

    THE CONSENSUS OF OUR NATION'S LEADERS AFFIRMS THAT THE COUNTRY'S GREATEST TECHNICAL EDUCATION VOID IS IN THE AREA BETWEEN THE 12TH GRADE AND THE BACCALAUREATE DEGREE. THE IMPACT OF ACCELERATED PROGRESS IN TECHNOLOGICAL ACHIEVEMENTS MAKES TECHNICAL EDUCATION MANDATORY IF THE MANPOWER SHORTAGE IS NOT TO BECOME A NATIONAL EMERGENCY. BECAUSE NEARLY 80…

  3. Combustible structural composites and methods of forming combustible structural composites

    DOEpatents

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  4. LES of Mild Combustion using Pareto-efficient Combustion Adaptation

    NASA Astrophysics Data System (ADS)

    Wu, Hao; Evans, Michael; Ihme, Matthias

    2015-11-01

    Moderate or Intense Low-Oxygen Dilution (MILD) combustion is a combustion regime that provides opportunities for improved thermal efficiency and reduced pollutant emissions. In this study, large-eddy simulation is used to investigate the ignition, mixing, and stabilization of a jet flame in this kinetics-controlled combustion regime. The combustion process is modeled by a Pareto-efficient combustion (PEC) formulation that optimally combines reaction-transport and chemistry combustion models. In this approach, a three-stream flamelet/progress variable model is used as a computationally efficient description of equilibrated flame regions, and a finite-rate chemistry representation is employed to accurately represent the ignition behavior and flame stabilization. Through comparisons with experiments and simulations with single-regime combustion models, it will be shown that this Pareto-efficient combustion submodel assignment accurately captures important dynamics in complex turbulent flame configurations.

  5. Combustible structural composites and methods of forming combustible structural composites

    DOEpatents

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D; Swank, William D.

    2011-08-30

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  6. PDF Modeling of Turbulent Lean Premixed Combustion

    SciTech Connect

    Yilmaz, S.L.; •Givi, P.; Strakey, P.A.

    2007-10-01

    The joint velocity-scalar-frequency probability density function (PDF) methodology is employed for prediction of a bluff-body stabilized lean premixed methane-air flame. A reduced mechanism with CO and NO chemistry is used to describe fuel oxidation. The predicted mean and rms values of the velocity, temperature and concentrations of major and minor species are compared with laboratory measurements. This technical effort was performed in support of the National Energy Technology Laboratory’s on-going research in “Assessment of Turbo-Chemistry Models for Gas Turbine Combustion Emissions” under the RDS contract DE-AC26-04NT41817.

  7. Sampling nitric oxide from combustion gases.

    NASA Technical Reports Server (NTRS)

    England, C.; Houseman, J.; Teixeira, D. P.

    1973-01-01

    Experimental study of several sampling tube and probe material compositions and designs aimed at preventing nitric oxide reduction when sampling nitric oxide from combustion gases. A 250,000 Btu/h furnace fired with technical grade methane was used for testing the sampling probes over a wide range of air-fuel mixtures. The results obtained include the finding that the use of stainless steel in probes creates inaccuracies in near-stoichiometric and fuel-rich sampling in hydrocarbon flames. For very fuel-rich flames, water cooling is needed even in quartz probes to prevent significant reduction of nitric oxide.-

  8. Ames Hybrid Combustion Facility

    NASA Technical Reports Server (NTRS)

    Zilliac, Greg; Karabeyoglu, Mustafa A.; Cantwell, Brian; Hunt, Rusty; DeZilwa, Shane; Shoffstall, Mike; Soderman, Paul T.; Bencze, Daniel P. (Technical Monitor)

    2003-01-01

    The report summarizes the design, fabrication, safety features, environmental impact, and operation of the Ames Hybrid-Fuel Combustion Facility (HCF). The facility is used in conducting research into the scalability and combustion processes of advanced paraffin-based hybrid fuels for the purpose of assessing their applicability to practical rocket systems. The facility was designed to deliver gaseous oxygen at rates between 0.5 and 16.0 kg/sec to a combustion chamber operating at pressures ranging from 300 to 900. The required run times were of the order of 10 to 20 sec. The facility proved to be robust and reliable and has been used to generate a database of regression-rate measurements of paraffin at oxygen mass flux levels comparable to those of moderate-sized hybrid rocket motors.

  9. Thermodynamics and combustion modeling

    NASA Technical Reports Server (NTRS)

    Zeleznik, Frank J.

    1986-01-01

    Modeling fluid phase phenomena blends the conservation equations of continuum mechanics with the property equations of thermodynamics. The thermodynamic contribution becomes especially important when the phenomena involve chemical reactions as they do in combustion systems. The successful study of combustion processes requires (1) the availability of accurate thermodynamic properties for both the reactants and the products of reaction and (2) the computational capabilities to use the properties. A discussion is given of some aspects of the problem of estimating accurate thermodynamic properties both for reactants and products of reaction. Also, some examples of the use of thermodynamic properties for modeling chemically reacting systems are presented. These examples include one-dimensional flow systems and the internal combustion engine.

  10. Droplet Combustion Experiment movie

    NASA Technical Reports Server (NTRS)

    2003-01-01

    The Droplet Combustion Experiment (DCE) was designed to investigate the fundamental combustion aspects of single, isolated droplets under different pressures and ambient oxygen concentrations for a range of droplet sizes varying between 2 and 5 mm. The DCE principal investigator was Forman Williams, University of California, San Diego. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1 mission (STS-83, April 4-8 1997; the shortened mission was reflown as MSL-1R on STS-94). Advanced combustion experiments will be a part of investigations plarned for the International Space Station. (1.1 MB, 12-second MPEG, screen 320 x 240 pixels; downlinked video, higher quality not available)A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300164.html.

  11. Internal combustion engine

    DOEpatents

    Baker, Quentin A.; Mecredy, Henry E.; O'Neal, Glenn B.

    1991-01-01

    An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

  12. Fluidized-bed combustion

    SciTech Connect

    Botros, P E

    1990-04-01

    This report describes the activities of the Morgantown Energy Technology Center's research and development program in fluidized-bed combustion from October 1, 1987, to September 30, 1989. The Department of Energy program involves atmospheric and pressurized systems. Demonstrations of industrial-scale atmospheric systems are being completed, and smaller boilers are being explored. These systems include vortex, multi-solid, spouted, dual-sided, air-cooled, pulsed, and waste-fired fluidized-beds. Combustion of low-rank coal, components, and erosion are being studied. In pressurized combustion, first-generation, combined-cycle power plants are being tested, and second-generation, advanced-cycle systems are being designed and cost evaluated. Research in coal devolatilization, metal wastage, tube corrosion, and fluidization also supports this area. 52 refs., 24 figs., 3 tabs.

  13. Antipollution combustion chamber

    SciTech Connect

    Caruel, J.E.; Gastebois, P.M.

    1981-01-27

    The invention concerns a combustion chamber for turbojet engines. The combustion chamber is of the annular type and consists of two coaxial flame tubes opening into a common dilution and mixing zone. The inner tube is designed for low operating ratings of the engine, the outer tube for high ratings. Air is injected as far upstream as possible into the dilution zone, to enhance the homogenization of the gaseous flow issuing from the two tubes prior to their passage into the turbine and to assure the optimum radial distribution of temperatures. The combustion chamber according to the invention finds application in a particularly advantageous manner in turbojet engines used in aircraft propulsion because of the reduced emission of pollutants it affords.

  14. Forced cocurrent smoldering combustion

    SciTech Connect

    Dosanjh, S.S.; Pagni, P.J.; Fernandez-Pello, A.C.

    1987-05-01

    An analytic model of the propagation of smoldering combustion through a very porous solid fuel is presented. Here smoldering is initiated at the top of a long, radially insulated, uniform fuel cylinder, so that the smolder wave propagates downward, opposing an upward forced flow of oxidizer. Because the solid fuel and the gaseous oxidizer enter the reaction zone from the same direction, this configuration is referred to as cocurrent (or premixed-flame-like). It is assumed that the propagation of the smolder wave is one-dimensional and steady in a frame of reference moving with the wave. Buoyancy is included and shown to be negligible in the proposed application of a smoldering combustion experiment for use on the Space Shuttle. Radiation heat transfer is incorporated using the diffusion approximation and smoldering combustion is modeled by a finite rate, one-step reaction mechanism.

  15. Thermal treatment for chlorine removal from coal. [Quarterly] technical report, March 1, 1992--May 31, 1992

    SciTech Connect

    Muchmore, C.B.; Hesketh, H.E.; Chen, Han Lin

    1992-10-01

    It is the goal of this research to provide the technical basis for development of a process to remove chlorine from coal prior to combustion, based on a thermal treatment process. Under the reaction conditions employed, the behavior of other trace elements of concern will also be evaluated. The recovery of the chlorine removed from the coal as a marketable byproduct, calcium chloride suitable for use as a road deicer, is also being investigated using a novel absorption/crystallization device. A value of 6.29 hr{sup {minus}1} was determined for the dechlorination rate constant of IBC-109 coal at 385{degrees}C, and an activation energy of 34.7 kcal/mol was obtained from an Arrhenius plot over the temperature range of 300--385{degrees}C. A significant removal of chlorine (84.3%) was attained while retaining 92% of the energy of the coal in the solid product by preheating the coal at lower temperatures prior to a six-minute reaction at 385{degrees}C. Volatiles lost during the thermal dechlorination may be recovered for their heating value, and/or as a source of chemical feedstocks; this aspect will require further study, but it appears that the overall energy balance on the system should prove to be favorable. The design of the bench scale fluidized bed thermal dechlorination unit has been completed, and components ordered. Operation of this system should provide the information required for further scale-up of the process.

  16. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect

    John C. Wagner

    2004-03-31

    attributes of oscillating combustion and on the results of an earlier project at GTI and Air Liquide, to determine which applications for oscillating combustion would show the greatest probability for technical success and greatest probability for market acceptability. The market study indicated that furnaces in the steel, glass, and metal melting industries would perform well in both categories. These findings guided the selection of burners for laboratory testing and, with the results of the laboratory testing, guided the selection of field test sites.

  17. NOx Emission Reduction by Oscillating combustion

    SciTech Connect

    Institute of Gas Technology

    2004-01-30

    attributes of oscillating combustion and on the results of an earlier project at GTI and Air Liquide, to determine which applications for oscillating combustion would show the greatest probability for technical success and greatest probability for market acceptability. The market study indicated that furnaces in the steel, glass, and metal melting industries would perform well in both categories. These findings guided the selection of burners for laboratory testing and, with the results of the laboratory testing, guided the selection of field test sites.

  18. Studies in combustion dynamics

    SciTech Connect

    Koszykowski, M.L.

    1993-12-01

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  19. Alternate Fuels Combustion Research

    DTIC Science & Technology

    1983-10-01

    AFWAL-TR-83-2057 AD A13 8 5 7 5 ALTERNATE FUELS COMBUSTION RESEARCH PHASE RI ’~*~~4 & IWITEY CMAAA * ’s~t:Uwz, ONTARIO October 1983 I•oerls Report...83-2057 P_______________ C TITLE (mod ,,--tt-) 5. TYPE OF REPORT A PERIOD COVERED Alternate Fuels ioahusticn Research Interim Report for Period Phase...I$. KEY WORDS (Continue on reverse sirte it necessear and identify by block number) FUELS ALTERNATE FUELS GAS TURBINE COMBUSTION EXHAUST EMISSIONS 0

  20. Thermal ignition combustion system

    DOEpatents

    Kamo, Roy; Kakwani, Ramesh M.; Valdmanis, Edgars; Woods, Melvins E.

    1988-01-01

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

  1. Thermal ignition combustion system

    DOEpatents

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  2. Transition nozzle combustion system

    DOEpatents

    Kim, Won-Wook; McMahan, Kevin Weston; Maldonado, Jaime Javier

    2016-11-29

    The present application provides a combustion system for use with a cooling flow. The combustion system may include a head end, an aft end, a transition nozzle extending from the head end to the aft end, and an impingement sleeve surrounding the transition nozzle. The impingement sleeve may define a first cavity in communication with the head end for a first portion of the cooling flow and a second cavity in communication with the aft end for a second portion of the cooling flow. The transition nozzle may include a number of cooling holes thereon in communication with the second portion of the cooling flow.

  3. Toxicology of Biodiesel Combustion products

    EPA Science Inventory

    1. Introduction The toxicology of combusted biodiesel is an emerging field. Much of the current knowledge about biological responses and health effects stems from studies of exposures to other fuel sources (typically petroleum diesel, gasoline, and wood) incompletely combusted. ...

  4. Combuster. [low nitrogen oxide formation

    NASA Technical Reports Server (NTRS)

    Mckay, R. A. (Inventor)

    1978-01-01

    A combuster is provided for utilizing a combustible mixture containing fuel and air, to heat a load fluid such as water or air, in a manner that minimizes the formation of nitrogen oxide. The combustible mixture passes through a small diameter tube where the mixture is heated to its combustion temperature, while the load fluid flows past the outside of the tube to receive heat. The tube is of a diameter small enough that the combustible mixture cannot form a flame, and yet is not subject to wall quench, so that combustion occurs, but at a temperature less than under free flame conditions. Most of the heat required for heating the combustible mixture to its combustion temperature, is obtained from heat flow through the walls of the pipe to the mixture.

  5. DISPOSAL OF FLUIDIZED BED COMBUSTION ASH IN AN UNDERGROUND MINE TO CONTROL ACID MINE DRAINAGE AND SUBSIDENCE

    SciTech Connect

    Unknown

    2000-10-01

    This project evaluated the technical, economic and environmental feasibility of filling abandoned underground mine voids with coal combustion byproducts. Success was measured in terms of technical feasibility of the approach (i.e. % void filling), cost, environmental benefits (acid mine drainage and subsidence control) and environmental impacts (noxious ion release). Phase 1 of the project was completed in September 1995 and was concerned with the development of the grout and a series of predictive models. These models were verified through the Phase II field phase and will be further verified fin the large scale field demonstration of Phase III. The verification allows the results to be packaged in such a way that the technology can be easily adapted to different site conditions. Phase II was successfully completed with 1000 cubic yards of grout being injected into Anker Energy's Fairfax mine. The grout flowed over 600 feet from a single injection borehole. The grout achieved a compressive strength of over 1000 psi (twice the level that is needed to guarantee subsidence control). Phase III was a full scale test at Anker's eleven acre Longridge mine site. The CCB grout replaced what was an open mine void with a solid so that the groundwater tends to flow around and through the pillars rather than through the previously mined areas. The project has demonstrated that CCBs can be successfully disposed in underground mines. Additionally, the project has shown that filling an abandoned underground mine with CCBs can lead to the reduction and elimination of environmental problems associated with underground mining such as acid mine drainage and subsidence. The filling of the Longridge Mine with 43,000 cubic yards of CCB grout resulted in a 97% reduction in acid mine drainage coming from the mine.

  6. Reversed flow fluidized-bed combustion apparatus

    DOEpatents

    Shang, Jer-Yu; Mei, Joseph S.; Wilson, John S.

    1984-01-01

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  7. Olive by-products in pig fattening.

    PubMed

    Rupić, V; Jerković, I; Bozac, R; Glowattzky, D; Muźic, S; Hrabak, V

    1997-01-01

    The utilisation in pig fattening of diets with various proportions of dried olive cake, i.e., olive by-product resulting from centrifugal separation, was investigated in 60 Swedish Landrace x Large White crossbreds (30 castrates and 30 gilts). The pigs were divided into three equal groups (10 + 10): two experimental groups, fed with a fodder mix containing 50 g/kg and 80 g/kg respectively of dried olive cake, and a control group, fed with the same mix but minus the cake. The experiment last 90 days. For the first 45 days the pigs were given the starter, and for the second 45 days the finisher, mix. Throughout the whole period, pigs in both experimental groups achieved greater average body mass and mass gain than the control animals. Concurrently, castrates in all three groups, became heavier and demonstrated greater mass gain than did the gilts. While supplied respectively with the finisher mix throughout the whole test period, pigs fed mixes with 50 g/kg of dried olive cake demonstrated significantly greater feed consumption than those fed without the cake and than those fed mixes with 80 g/kg of cake. While supplied with the starter mix, pigs fed mixes with 50 g/kg of dried olive cake achieved the lowest feed conversion rate, whereas those supplied with the finisher mix achieved the highest. Throughout the entire period no significant differences were observed in feed conversion rate among pig groups.

  8. Anaerobic effluent disinfection using ozone: byproducts formation.

    PubMed

    Silva, G H R; Daniel, L A; Bruning, H; Rulkens, W H

    2010-09-01

    This research was aimed at studying oxidation processes, coliform inactivation effectiveness and disinfection byproducts (DBPs) associated with the disinfection of anaerobic sanitary wastewater effluent with ozone applied at doses of 5.0, 8.0 and 10.0mg O(3)L(-1) for contact times of 5, 10 and 15 min. The wastewater used in this research was generated by the wastewater treatment plant (WWTP), University of São Paulo - Brazil. The total coliform inactivation range was 2.00-4.06 log(10), and the inactivation range for Escherichia coli was 2.41-4.65 log(10). Mean chemical oxygen demand (COD) reductions were 37.6%, 48.8% and 42.4% for doses of 5.0, 8.0 and 10.0mg O(3)L(-1), respectively. Aldehyde formation varied with dosage only when the ozone dose was increased from 5.0 to 8.0mg O(3)L(-1) for acetaldehyde and from 5.0 to 8.0 and from 8.0 to 10.0mg O(3)L(-1) for glyoxal.

  9. Combustion Gases And Heat Release Analysis During Flame And Flameless Combustion Of Wood Pellets

    NASA Astrophysics Data System (ADS)

    Horváth, Jozef; Wachter, Igor; Balog, Karol

    2015-06-01

    With the growing prices of fossil fuels, alternative fuels produced of biomass come to the fore. They are made of waste materials derived from the processing of wood and wood materials. The main objective of this study was to analyse the fire-technical characteristics of wood pellets. The study analysed three dust samples acquired from wood pellets made of various types of wood biomass. Wood pellet dust is produced when manipulating with pellets. During this process a potentially hazardous situations may occur. Biomass is chemically composed mostly of hemicellulose, cellulose and lignin. During straining of the biomass by heat flux, combustion initiation occurs. Also, there was a change in the composition of material throughout combustion gases production, and the amount of heat generated by a flame or flameless combustion. Measurement of fire characteristics was conducted according to ISO 5660-1 standard using a cone calorimeter. Two samples of wood pellet dust were tested under the heat flux of 35 kW.m-2 and 50 kW.m-2. The process of combustion, the time to ignition, the carbon monoxide concentration and the amount of released heat were observed.

  10. Chlordane (Technical)

    Integrated Risk Information System (IRIS)

    TOXICOLOGICAL REVIEW of CHLORDANE ( TECHNICAL ) ( CAS No . 12789 - 03 - 6 ) In Support of Summary Information on the Integrated Risk Information System ( IRIS ) December 1997 U.S . Environmental Protection Agency Washington , DC TABLE OF CONTENTS Authors and Reviewers . . . . . . . . . . . . . . . .

  11. Combustible dust tests

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The sugar dust explosion in Georgia on February 7, 2008 killed 14 workers and injured many others (OSHA, 2009). As a consequence of this explosion, OSHA revised its Combustible Dust National Emphasis (NEP) program. The NEP targets 64 industries with more than 1,000 inspections and has found more tha...

  12. Combustion Fundamentals Research

    NASA Technical Reports Server (NTRS)

    1984-01-01

    The various physical processes that occur in the gas turbine combustor and the development of analytical models that accurately describe these processes are discussed. Aspects covered include fuel sprays; fluid mixing; combustion dynamics; radiation and chemistry and numeric techniques which can be applied to highly turbulent, recirculating, reacting flow fields.

  13. WASTE COMBUSTION SYSTEM ANALYSIS

    EPA Science Inventory

    The report gives results of a study of biomass combustion alternatives. The objective was to evaluate the thermal performance and costs of available and developing biomass systems. The characteristics of available biomass fuels were reviewed, and the performance parameters of alt...

  14. Spray combustion stability project

    NASA Technical Reports Server (NTRS)

    Jeng, San-Mou; Litchford, Ron J.

    1992-01-01

    This report summarizes research activity on the Spray Combustion Stability Project, characterizes accomplishments and current status, and discusses projected future work. The purpose is to provide a concise conceptual overview of the research effort to date so the reader can quickly assimilate the gist of the research results and place them within the context of their potential impact on liquid rocket engine design technology.

  15. Monopropellant combustion system

    NASA Technical Reports Server (NTRS)

    Berg, Gerald R. (Inventor); Mueller, Donn C. (Inventor); Parish, Mark W. (Inventor)

    2005-01-01

    An apparatus and method are provided for decomposition of a propellant. The propellant includes an ionic salt and an additional fuel. Means are provided for decomposing a major portion of the ionic salt. Means are provided for combusting the additional fuel and decomposition products of the ionic salt.

  16. Coal combustion research

    SciTech Connect

    Daw, C.S.

    1996-06-01

    This section describes research and development related to coal combustion being performed for the Fossil Energy Program under the direction of the Morgantown Energy Technology Center. The key activity involves the application of chaos theory for the diagnosis and control of fossil energy processes.

  17. Practical approaches to field problems of stationary combustion systems

    SciTech Connect

    Lee, S.W.

    1997-09-01

    The CANMET Energy Technology Centre (CETC) business plan dictates collaboration with industrial clients and other government agencies to promote energy efficiency, health and safety, pollution reduction and productivity enhancement. The Advanced Combustion Technologies group of CETC provides consultation to numerous organizations in combustion related areas by conducting laboratory and field investigations of fossil fuel-fired combustion equipment. CETC, with its modern research facilities and technical expertise, has taken this practical approach since the seventies and has assisted many organizations in overcoming field problems and in providing cost saving measures and improved profit margins. This paper presents a few selected research projects conducted for industrial clients in north and central America. The combustion systems investigated are mostly liquid fuel fired, with the exception of the utility boiler which was coal-fired. The key areas involved include fuel quality, fuel storage/delivery system contamination, waste derived oils, crude oil combustion, unacceptable pollutant emissions, ambient soot deposition, slagging, fouling, boiler component degradation, and particulate characterization. Some of the practical approaches taken to remedy these field problems on several combustion systems including residential, commercial and industrial scale units are discussed.

  18. Bioenergy from permanent grassland--a review: 2. Combustion.

    PubMed

    Prochnow, A; Heiermann, M; Plöchl, M; Amon, T; Hobbs, P J

    2009-11-01

    The aim of this review is to summarize current knowledge on suitability and sustainability of grassland biomass for combustion. In the first section grassland management for solid biofuel as well as information on harvest, postharvest and firing technology are described. An extensive grassland management system with one late cut and low level of fertilization is favored for grass as a solid biofuel. The grass harvest usually involves drying in the field and clearing with conventional farm machinery. Pelleting or briquetting improves the biofuel quality. Grass combustion is possible as stand-alone biomass-firing or co-firing with other fuels. Firing herbaceous biomass requires various specific adaptations of the different combustion technologies. In the second section economic and environmental aspects are discussed. Costs for biomass supply mainly depend on yields and harvesting technologies, while combustion costs are influenced by the size and technical design of the plant. Market prices for grass and possible subsidies for land use are crucial for profitability. Regarding biogeochemical cycles a specific feature of combustion is the fact that none of the biomass carbon and nitrogen removed at harvest is available for return to the grassland. These exports can be compensated for by fixation from the air given legumes in the vegetation and sufficient biomass production. Greenhouse gas emissions can be considerably reduced by grass combustion. Solid biofuel production has a potential for predominantly positive impacts on biodiversity due to the extensive grassland management.

  19. Fuel properties to enable lifted-flame combustion

    SciTech Connect

    Kurtz, Eric

    2015-03-15

    The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enable LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental

  20. Pressurized fluidized-bed combustion

    SciTech Connect

    Not Available

    1980-10-01

    The US DOE pressurized fluidized bed combustion (PFBC) research and development program is designed to develop the technology and data base required for the successful commercialization of the PFBC concept. A cooperative program with the US, West Germany, and the UK has resulted in the construction of the 25 MWe IEA-Grimethorpe combined-cycle pilot plant in England which will be tested in 1981. A 13 MWe coal-fired gas turbine (air cycle) at Curtis-Wright has been designed and construction scheduled. Start-up is planned to begin in early 1983. A 75 MWe pilot plant is planned for completion in 1986. Each of these PFBC combined-cycle programs is discussed. The current status of PFB technology may be summarized as follows: turbine erosion tolerance/hot gas cleanup issues have emerged as the barrier technology issues; promising turbine corrosion-resistant materials have been identified, but long-term exposure data is lacking; first-generation PFB combustor technology development is maturing at the PDU level; however, scale-up to larger size has not been demonstrated; and in-bed heat exchanger materials have been identified, but long-term exposure data is lacking. The DOE-PFB development plan is directed at the resolution of these key technical issues. (LCL)

  1. Low emission internal combustion engine

    DOEpatents

    Karaba, Albert M.

    1979-01-01

    A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

  2. Modelling of CWS combustion process

    NASA Astrophysics Data System (ADS)

    Rybenko, I. A.; Ermakova, L. A.

    2016-10-01

    The paper considers the combustion process of coal water slurry (CWS) drops. The physico-chemical process scheme consisting of several independent parallel-sequential stages is offered. This scheme of drops combustion process is proved by the particle size distribution test and research stereomicroscopic analysis of combustion products. The results of mathematical modelling and optimization of stationary regimes of CWS combustion are provided. During modeling the problem of defining possible equilibrium composition of products, which can be obtained as a result of CWS combustion processes at different temperatures, is solved.

  3. IDENTIFICATION OF TI02/UV DISINFECTION BYPRODUCTS IN DRINKING WATER

    EPA Science Inventory

    Due to concern over the presence of trihalomethanes (THMs) and other chlorinated byproducts in chlorinated drinking water, alternative disinfection methods are being explored. One of the alternative treatment methods currently being evaluated for potential use with small systems ...

  4. IDENTIFICATION OF NEW DISINFECTION BY-PRODUCTS IN DRINKING WATER

    EPA Science Inventory

    Due to concern over the potential adverse health effects of trihalomethanes (THMs) and other chlorinated by-products in chlorinated drinking water, alternative disinfectants are being explored. Ozone, chlorine dioxide, and chloramine are popular alternatives, as they produce low...

  5. MULTISPECTRAL IDENTIFICATION OF CHLORINE DIOXIDE BYPRODUCTS IN DRINKING WATER

    EPA Science Inventory

    This paper discusses the identification of organic disinfectant byproducts (DNPS) at a pilot plant in Evansville, IN, that uses chlorine dioxide as a primary disinfectant. nconventional multispectral identification techniques (gas chromatography combined with high- and low-resolu...

  6. Formation and Occurrence of Disinfection By-Products

    EPA Science Inventory

    Disinfection by-products (DBPs) are formed when disinfectants such as chlorine, ozone, chlorine dioxide, or chloramines react with naturally occurring organic matter, anthropogenic contaminants, bromide, and iodide during the production of drinking water. There is concern about D...

  7. MULTISPECTRAL IDENTIFICATION OF CHLORINE DIOXIDE DISINFECTION BYPRODUCTS IN DRINKING WATER

    EPA Science Inventory

    This paper discusses the identification of organic disinfection byproducts (DBPs) at a pilot plant in Evansville, IN, which uses chlorine dioxide as a primary disinfectant. Unconventional multispectral identification techniques (gas chromatography combined with high- and low reso...

  8. Study of boron behaviour in two Spanish coal combustion power plants.

    PubMed

    Ochoa-González, Raquel; Cuesta, Aida Fuente; Córdoba, Patricia; Díaz-Somoano, Mercedes; Font, Oriol; López-Antón, M Antonia; Querol, Xavier; Martínez-Tarazona, M Rosa; Giménez, Antonio

    2011-10-01

    A full-scale field study was carried out at two Spanish coal-fired power plants equipped with electrostatic precipitator (ESP) and wet flue gas desulfurisation (FGD) systems to investigate the distribution of boron in coals, solid by-products, wastewater streams and flue gases. The results were obtained from the simultaneous sampling of solid, liquid and gaseous streams and their subsequent analysis in two different laboratories for purposes of comparison. Although the final aim of this study was to evaluate the partitioning of boron in a (co-)combustion power plant, special attention was paid to the analytical procedure for boron determination. A sample preparation procedure was optimised for coal and combustion by-products to overcome some specific shortcomings of the currently used acid digestion methods. In addition boron mass balances and removal efficiencies in ESP and FGD devices were calculated. Mass balance closures between 83 and 149% were obtained. During coal combustion, 95% of the incoming boron was collected in the fly ashes. The use of petroleum coke as co-combustible produced a decrease in the removal efficiency of the ESP (87%). Nevertheless, more than 90% of the remaining gaseous boron was eliminated via the FGD in the wastewater discharged from the scrubber, thereby causing environmental problems.

  9. By-products of electrochemical synthesis of suberic acid

    SciTech Connect

    Shirobokova, O.I.; Adamov, A.A.; Freidlin, G.N.; Antonenko, N.S.; Grudtsyn, Yu.D.

    1988-05-10

    By-products of the electrochemical synthesis of dimethyl suberate from glutaric anhydride were studied. This is isolated by thermal dehydration of a mixture of lower dicarboxylic acids that are wastes from the production of adipic acid. To isolate the by-products, they used the methods of vacuum rectification and preparative gas-liquid chromatography, and for their identification, PMR, IR spectroscopy, gas-liquid chromatography, and other known physicochemical methods of investigation.

  10. Treatment of disinfection by-product precursors.

    PubMed

    Bond, T; Goslan, E H; Parsons, S A; Jefferson, B

    2011-01-01

    Formation of harmful disinfection by-products (DBPs), of which trihalomethanes (THMs) and haloacetic acids (HAAs) are the major groups, can be controlled by removal of natural organic matter (NOM) before disinfection. In the literature, removal of precursors is variable, even with the same treatment. The treatment of DBP precursors and NOM was examined with the intention of outlining precursor removal strategies for various water types. Freundlich adsorption parameters and hydroxyl rate constants were collated from the literature to link treatability by activated carbon and advanced oxidation processes (AOPs), respectively, to physico-chemical properties. Whereas hydroxyl rate constants did not correlate meaningfully with any property, a moderate correlation was found between Freundlich parameters and log K(ow), indicating activated carbon will preferentially adsorb hydrophobic NOM. Humic components of NOM are effectively removed by coagulation, and, where they are the principal precursor source, coagulation may be sufficient to control DBPs. Where humic species remaining post-coagulation retain significant DBP formation potential (DBPFP), activated carbon is deemed a suitable process selection. Anion exchange is an effective treatment for transphilic species, known for high carboxylic acid functionality, and consequently is recommended for carboxylic acid precursors. Amino acids have been linked to HAA formation and are important constituents of algal organic matter. Amino acids are predicted to be effectively removed by biotreatment and nanofiltration. Carbohydrates have been found to reach 50% of NOM in river waters. If the carbohydrates were to pose a barrier to successful DBP control, additional treatment stages such as nanofiltration are likely to be required to reduce their occurrence.

  11. Digestion kinetics of carbohydrate fractions of citrus by-products.

    PubMed

    Lashkari, Saman; Taghizadeh, Akbar

    2015-01-01

    The present experiment was carried out to determine the digestion kinetics of carbohydrate fractions of citrus by-products. Grapefruit pulp (GP), lemon pulp (LE), lime pulp (LI) and orange pulp (OP) were the test feed. Digestion kinetic of whole citrus by-products and neutral detergent fiber (NDF) fraction and acid detergent fiber (ADF) fractions of citrus by-products were measured using the in vitro gas production technique. Fermentation kinetics of the neutral detergent soluble carbohydrates (NDSC) fraction and hemicelluloses were calculated using a curve subtraction. The fermentation rate of whole was the highest for the LE (p < 0.05). For all citrus by-products lag time was longer for hemicellulose than other carbohydrate fractions. There was no significant difference among potential gas production (A) volumes of whole test feeds (p < 0.16). Dry matter (DM) digestibility contents of LE and LI were the highest (p < 0.02). The NDF digestibility was the highest (p < 0.05) in LI and GP, while the lowest (p < 0.03) values of ADF digestibility were observed in LI and LE. According to the results of the present study, carbohydrate fractions of citrus by-products have high potential for degradability. It could also be concluded that carbohydrate fractions of citrus by-products have remarkable difference in digestion kinetics and digestive behavior.

  12. Power plant efficiency and combustion optimization

    SciTech Connect

    Chatterjee, A.K.; Nema, N.; Jain, A.

    1998-07-01

    Grasim, a leader producer of Rayon grade staple fiber has, with time come up with its own Captive Electric Power Generation Industry with a capacity of generating 113 MW Thermal Power for its in-house use involving state of the art technology and system. In the present paper, it is desired to share the technical development in the global environment and receive expert feedback for its own upgrade. The on site power plants have a variety of steam turbines and boilers of different capacities. At times the plants had to face power crisis due to number of reasons and has always come up with number of solutions for performance enhancement and efficiency improvement. It is desired to present the following cases: (1) Development of spiral coal caps--for atmospheric fluidized bed boilers, it is often experienced that unburned carbon is high in ash. The reason being that coal particles do not get sufficient retention time after being injected into the bed. Attempt has been made to increase the retention time and better mixing by creating a cyclone around the coal cap with help of spiral coal caps. (2) Combustion optimization--in view of the inherent design deficiency, combustion was optimized by controlling the three parameters i.e., time, temperature and turbulence. In pulverized fuel combustion boilers this was done by providing air damper regulation and in atmospheric fluidized bed combustion boilers this was done by creating a vortex and regulating fluidizing air. The details shall be given in paper. (3) Power plant efficiency improvement--by introducing online monitoring system and identifying various areas of losses for various operating reasons and the cost associated with each operating parameter and the impact of each variation.

  13. Time Resolved FTIR Analysis of Combustion of Ethanol and Gasoline Combustion in AN Internal Combustion Engine

    NASA Astrophysics Data System (ADS)

    White, Allen R.; Sakai, Stephen; Devasher, Rebecca B.

    2011-06-01

    In order to pursue In Situ measurements in an internal combustion engine, a MegaTech Mark III transparent spark ignition engine was modified with a sapphire combustion chamber. This modification will allow the transmission of infrared radiation for time-resolved spectroscopic measurements by an infrared spectrometer. By using a Step-scan equipped Fourier transform spectrometer, temporally resolved infrared spectral data were acquired and compared for combustion in the modified Mark III engine. Measurements performed with the FTIR system provide insight into the energy transfer vectors that precede combustion and also provides an in situ measurement of the progress of combustion. Measurements were performed using ethanol and gasoline.

  14. Effects of fluidized bed combustion residue on pecan seedling growth and nutrient content. [Carya illinoensis

    SciTech Connect

    Edwards, J.H.; White, A.W. Jr.; Bennett, O.L.

    1985-01-01

    Fluidized bed combustion residue from a calcitic limestone source (FBCRC), a by-product of scrubbing SO/sub 2/ from fossil fuel fired boilers using the FBC technique was evaluated as a source of calcium for pecan (Carya illinoensis (Wang.) K. Koch) seedlings. Fluidized bed combustion residue produced following injection of calcitic limestone into the combustion chamber was more effective in neutralizing soil acidity and increasing extractable soil Ca levels than agricultural calcitic limestone. The Ca concentration in the pecan leaves was increased linearly by Ca rates for both 12- and 24-week growth periods, but stem and petiole Ca concentration was increased linearly for the second 12-week growth period. Macronutrient concentrations were affected by Ca rates for both 12- and 24-week growth periods, but no effect was observed with Ca source. The primary difference was between the control and all other Ca rates.

  15. 10 CFR 31.9 - General license to own byproduct material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false General license to own byproduct material. 31.9 Section 31.9 Energy NUCLEAR REGULATORY COMMISSION GENERAL DOMESTIC LICENSES FOR BYPRODUCT MATERIAL § 31.9 General license to own byproduct material. A general license is hereby issued to own byproduct...

  16. Combustion engine system

    NASA Technical Reports Server (NTRS)

    Houseman, John (Inventor); Voecks, Gerald E. (Inventor)

    1986-01-01

    A flow through catalytic reactor which selectively catalytically decomposes methanol into a soot free hydrogen rich product gas utilizing engine exhaust at temperatures of 200 to 650 C to provide the heat for vaporizing and decomposing the methanol is described. The reactor is combined with either a spark ignited or compression ignited internal combustion engine or a gas turbine to provide a combustion engine system. The system may be fueled entirely by the hydrogen rich gas produced in the methanol decomposition reactor or the system may be operated on mixed fuels for transient power gain and for cold start of the engine system. The reactor includes a decomposition zone formed by a plurality of elongated cylinders which contain a body of vapor permeable, methanol decomposition catalyst preferably a shift catalyst such as copper-zinc.

  17. Stratified combustion engine

    SciTech Connect

    Solheim, R.G.

    1987-03-17

    The method is described of operating an internal combustion engine having a cylinder with an inner wall. The method comprises admitting, adjacent to the inner wall of the cylinder, a quantity of substantially pure air in a spirally rapidly rotating layer and directing all of the quantity uniformly coaxially relative to the cylinder and toward and against only the adjacent inner wall of the cylinder, and held thereat by Coanda effect and centrifugal force. This is done while also admitting a quantity of fuel mixture in a non-rotating and non-turbulent manner between the layer of rotating pure air and the longitudinal axis of the cylinder, compressing the rotating pure air and the non-rotating fuel mixture simultaneously and firing the non-rotating fuel mixture and exhausting the products of combustion and pure air uniformly coaxially relative to the cylinder and only from a region adjacent to the inner wall and uniformly and completely from the inner wall.

  18. Dynamic features of combustion

    NASA Technical Reports Server (NTRS)

    Oppenheim, A. K.

    1985-01-01

    The dynamic features of combustion are discussed for four important cases: ignition, inflammation, explosion, and detonation. Ignition, the initiation of a self-sustained exothermic process, is considered in the simplest case of a closed thermodynamic system and its stochastic distribution. Inflammation, the initiation and propagation of self-sustained flames, is presented for turbulent flow. Explosion, the dynamic effects caused by the deposition of exothermic energy in a compressible medium, is illustrated by self-similar blast waves with energy deposition at the front and the adiabatic non-self-similar wave. Detonation, the most comprehensive illustration of all the dynamic effects of combustion, is discussed with a phenomenological account of the development and structure of the wave.

  19. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Levasseur, A.A.

    1995-11-01

    The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

  20. Supersonic Combustion Ramjet Research

    DTIC Science & Technology

    2012-08-01

    4.2 Ignition, Flameholding, and Flame Propagation in Supersonic Flows ......................... 18 4.2.1 Plasma -Assisted Ignition and Flameholding...high- speed flows), plasma -assisted combustion, flameholding (particularly in a high-speed flow), and development and application of diagnostic...Flameholding, and Flame Propagation in Supersonic Flows 4.2.1 Plasma -Assisted Ignition and Flameholding Key questions that have guided this

  1. Combustion powered linear actuator

    DOEpatents

    Fischer, Gary J.

    2007-09-04

    The present invention provides robotic vehicles having wheeled and hopping mobilities that are capable of traversing (e.g. by hopping over) obstacles that are large in size relative to the robot and, are capable of operation in unpredictable terrain over long range. The present invention further provides combustion powered linear actuators, which can include latching mechanisms to facilitate pressurized fueling of the actuators, as can be used to provide wheeled vehicles with a hopping mobility.

  2. Industrial Combustion Coordinated Rulemaking.

    PubMed

    Melton, Lula H

    1996-08-01

    The following article is excerpted from the document Industrial Combustion Coordinated Rulemaking - Proposed Organizational Structure and Process, which is available from the Technology Transfer Network (TTN), a computer bulletin board. To access the TTN, call (919) 541-5742; to obtain help with the TTN, call (919) 541-5384. The Industrial Combustion Coordinated Rulemaking (ICCR) document is evolving, reflecting an ongoing dialogue with various stakeholders; therefore, there may be changes between this article and the ICCR as it is implemented. EPA would like to thank all stakeholders (e.g., representatives from various companies and trade associations, state and local air pollution control agencies, and environmental organizations) who have offered suggestions and comments on development of the ICCR. As mentioned in the implications statement, the overall goal of the ICCR is to develop a unified set of federal air emissions regulations. The proposed ICCR will achieve this goal by: • Obtaining active participation from stakeholders, including environmental groups, regulated industries, and state and local regulatory agencies in all phases of regulatory development. • Coordinating the schedule and approach for development of regulations under Sections 111, 112, and 129 of the Clean Air Act that affect ICI combustion. • Determining the most effective ways to address the environmental issues associated with toxic and criteria pollutants from the range of combustion sources. • More effectively considering interactions among the regulations by analyzing the combined benefits and economic impacts of the group of Section 111, 112, and 129 regulations. • Considering strategies to simplify the regulations and allow flexibility in the methods of compliance while maintaining full environmental benefits.

  3. Combustion Characteristics of Sprays

    DTIC Science & Technology

    1989-08-01

    regarded by implication or otherwise, or in any way licensing the holder or any other person or corporation, or conveying any rights or permission to...00 _’N 1. TI TLE inctuat Security CZaaafication5 Combustion Characteristics of Sprays 12. PERSONAL AUTHOR(S) Sohrab, Siavash H. 13& TYPE OF REPORT...to ?!HF of rich butane/air 3unsen flames. .lso, the rotacion speed and :he oerodic temDeracure fluc:uations of rotacfng ?HF are examined. :’!naily

  4. Combustible Cartridge Case Characterization

    DTIC Science & Technology

    1984-02-01

    University (NYU) has resulted in the selection of two cross-linked melamine / formaldehyde acrylic styrene resin systems that can be used in the beater additive... melamine resin Akaradit II stabilizer 20. ABSTRACT (con) Test coupons of combustible cartridge case material were fabricated using these recommended...and agitated for 30 min before the pH was slowly lowered to 3 with p-toluene sulfonic acid. In order to maintain this pH in the felting tank, it was

  5. Spontaneous combustion of hydrogen

    NASA Technical Reports Server (NTRS)

    Nusselt, Wilhelm; Pothmann, PH

    1923-01-01

    It is shown by the author's experiments that hydrogen which escapes to the atmosphere through openings in the system may burn spontaneously if it contains dust. Purely thermal reasoning can not account for the combustion. It seems to be rather an electrical ignition. In order to determine whether the cause of the spontaneous ignition was thermo-chemical, thermo-mechanical, or thermo-electrical, the experiments in this paper were performed.

  6. The Diesel Combustion Collaboratory: Combustion Researchers Collaborating over the Internet

    SciTech Connect

    C. M. Pancerella; L. A. Rahn; C. Yang

    2000-02-01

    The Diesel Combustion Collaborator (DCC) is a pilot project to develop and deploy collaborative technologies to combustion researchers distributed throughout the DOE national laboratories, academia, and industry. The result is a problem-solving environment for combustion research. Researchers collaborate over the Internet using DCC tools, which include: a distributed execution management system for running combustion models on widely distributed computers, including supercomputers; web-accessible data archiving capabilities for sharing graphical experimental or modeling data; electronic notebooks and shared workspaces for facilitating collaboration; visualization of combustion data; and video-conferencing and data-conferencing among researchers at remote sites. Security is a key aspect of the collaborative tools. In many cases, the authors have integrated these tools to allow data, including large combustion data sets, to flow seamlessly, for example, from modeling tools to data archives. In this paper the authors describe the work of a larger collaborative effort to design, implement and deploy the DCC.

  7. Internal combustion engine using premixed combustion of stratified charges

    DOEpatents

    Marriott, Craig D.; Reitz, Rolf D. (Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  8. A Study of Cavitation-Ignition Bubble Combustion

    NASA Technical Reports Server (NTRS)

    Nguyen, Quang-Viet; Jacqmin, David A.

    2005-01-01

    We present the results of an experimental and computational study of the physics and chemistry of cavitation-ignition bubble combustion (CIBC), a process that occurs when combustible gaseous mixtures are ignited by the high temperatures found inside a rapidly collapsing bubble. The CIBC process was modeled using a time-dependent compressible fluid-dynamics code that includes finite-rate chemistry. The model predicts that gas-phase reactions within the bubble produce CO and other gaseous by-products of combustion. In addition, heat and mechanical energy release through a bubble volume-expansion phase are also predicted by the model. We experimentally demonstrate the CIBC process using an ultrasonically excited cavitation flow reactor with various hydrocarbon-air mixtures in liquid water. Low concentrations (< 160 ppm) of carbon monoxide (CO) emissions from the ultrasonic reactor were measured, and found to be proportional to the acoustic excitation power. The results of the model were consistent with the measured experimental results. Based on the experimental findings, the computational model, and previous reports of the "micro-diesel effect" in industrial hydraulic systems, we conclude that CIBC is indeed possible and exists in ultrasonically- and hydrodynamically-induced cavitation. Finally, estimates of the utility of CIBC process as a means of powering an idealized heat engine are also presented.

  9. Compositional changes in red and violet smoke mixes after combustion

    SciTech Connect

    Buchanan, M.V.; Rubin, I.B.; Moneyhun, J.H.

    1983-01-01

    Anthraquinone-derived dyes are commonly used in colored dye mixes prepared for signal smoke grenades. Biological studies have shown, however, that a number of these dyes exhibit bacterial mutagenicity. In addition, these dyes are similar in structure to several polycyclic aromatic hydrocarbons which are well-known carcinogens. The grenades contain not only anthraquinone-derived dyes, but also a pyrotechnic fuel and cooling and starting mixes consisting primarily of potassium chlorate and nitrate, sodium bicarbonate, and sulfur. These dyes are volatilized at temperatures up to 550/sup 0/C during the detonation of the grenade, which could subject the dyes to oxidative and pyrolytic reactions that could result in a variety of reaction by-products. As part of a program to investigate possible environmental and occupational risks of the colored smoke dyes and in signal grenades, two colored smoke mixes, red and violet, have been studied both before and after detonation to evaluate any differences in composition due to the combustion process. This report focuses primarily on the separation and identification of the components of the original and combusted red and violet smoke mixes. The conditions for the detonation of the smoke grenades and sampling of the combusted smoke mixes are also discussed.

  10. Strobes: an oscillatory combustion.

    PubMed

    Corbel, Justine M L; Lingen, Joost N J; Zevenbergen, John F; Gijzeman, Onno L J; Meijerink, Andries

    2012-04-26

    Strobe compositions belong to the class of solid combustions. They are mixtures of powdered ingredients. When ignited, the combustion front evolves in an oscillatory fashion, and flashes of light are produced by intermittence. They have fascinated many scientists since their discovery at the beginning of the 20th century. However, the chemical and physical processes involved in this curious oscillatory combustion remain unknown. Several theories have been proposed: One claims that two different reactions occur: one during the slow dark phase and another during the fast flash phase. The alternation between the phases is ascribed to heat variations. Other theories suggest that the formation of intermediate species during the dark phase and the change of phase are caused by variations in their concentration. A ternary strobe composition with ammonium perchlorate, magnalium, and barium sulfate is analyzed. The role of barium sulfate is studied by replacing it by other metal sulfates that have different physical properties (melting points), and the burning of the compositions is recorded with a high-speed camera and a spectrometer coupled with a charge-coupled device (CCD) camera. Experimental results show noticeable differences in the physical and chemical processes involved in the strobe reactions.

  11. Droplet Combustion Experiment (DCE)

    NASA Technical Reports Server (NTRS)

    Haggard, John B., Jr.; Nayagan, Vedha; Dryer, Frederick L.; Williams, Forman A.

    1998-01-01

    The first space-based experiments were performed on the combustion of free, individual liquid fuel droplets in oxidizing atmospheres. The fuel was heptane, with initial droplet diameters ranging about from 1 mm to 4 mm. The atmospheres were mixtures of helium and oxygen, at pressures of 1.00, 0.50 and 0.25 bar, with oxygen mole fractions between 20% and 40%, as well as normal Spacelab cabin air. The temperatures of the atmospheres and of the initial liquid fuel were nominally 300 K. A total of 44 droplets were burned successfully on the two flights, 8 on the shortened STS-83 mission and 36 on STS-94. The results spanned the full range of heptane droplet combustion behavior, from radiative flame extinction at larger droplet diameters in the more dilute atmospheres to diffusive extinction in the less dilute atmospheres, with the droplet disappearing prior to flame extinction at the highest oxygen concentrations. Quasisteady histories of droplet diameters were observed along with unsteady histories of flame diameters. New and detailed information was obtained on burning rates, flame characteristics and soot behavior. The results have motivated new computational and theoretical investigations of droplet combustion, improving knowledge of the chemical kinetics, fluid mechanics and heat and mass transfer processes involved in burning liquid fuels.

  12. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October--December 1994

    SciTech Connect

    Chugh, Y.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1995-01-01

    On September 30, 1993, the US Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative agreement entitled ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` (DE-FC21-93MC30252). Under the agreement, Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. The major event during the quarter was the demonstration of the SEEC, Inc. technology for loading and transporting coal combustion residues in the SEEC developed Collapsible Intermodal Containers (CIC). The demonstration was held on November 17, 1994, at the Illinois Power Company Baldwin power plant, and was attended by about eighty (80) invited guest. Also during the quarter meetings were held with Peabody Coal Company officials to finalize the area in the Peabody No. 10 mine to be used for the placement of coal combustion residues. Work under the Materials Handling and Systems Economics area continued, particularly in refining the costs and systems configuration and in economic evaluation of various systems using equipment leasing rather than equipment purchases. Likewise, work progressed on residues characterization, with some preparations being made for long-term testing.

  13. Task 1.13 -- Data collection and database development for clean coal technology by-product characteristics and management practices. Semi-annual report, July 1--December 31, 1996

    SciTech Connect

    Pflughoeft-Hassett, D.F.

    1997-08-01

    Information from DOE projects and commercial endeavors in fluidized-bed combustion and coal gasification is the focus of this task by the Energy and Environmental Research Center. The primary goal of this task is to provide an easily accessible compilation of characterization information on CCT (Clean Coal Technology) by-products to government agencies and industry to facilitate sound regulatory and management decisions. Supporting objectives are (1) to fully utilize information from previous DOE projects, (2) to coordinate with industry and other research groups, (3) to focus on by-products from pressurized fluidized-bed combustion (PFBC) and gasification, and (4) to provide information relevant to the EPA evaluation criteria for the Phase 2 decision.

  14. 77 FR 27490 - Plant-Specific Adoption, Revision 4 of the Improved Standard Technical Specifications

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-10

    ... From the Federal Register Online via the Government Publishing Office NUCLEAR REGULATORY...: Nuclear Regulatory Commission. ACTION: Notice of Availability. SUMMARY: The U.S. Nuclear Regulatory... Specifications, Combustion Engineering Plants,'' NUREG-1433, ``Standard Technical Specifications,...

  15. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    SciTech Connect

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.

    1987-01-01

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air Force bases along our northern tier. This plant is producing over 137 million cubic feet per day of high-Btu Natural Gas from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation fuel jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions, thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report discusses the suitability of the tar oil stream. 5 refs., 20 figs., 15 tabs.

  16. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    SciTech Connect

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.; Smith, E. )

    1987-01-01

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air force bases along our northern tier. This plant is producing over 137 million cubic feet per day of high-Btu SNG from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report describes the stream assessment. 6 refs., 3 figs., 3 tabs.

  17. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    SciTech Connect

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.

    1987-01-01

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air Force bases along our northern tier. This plant is producing over 137 million cubic feet per day high-Btu SNG from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report describes results on feedstock characterization. 6 figs., 5 tabs.

  18. Feedback control of combustion oscillations in combustion chambers

    NASA Astrophysics Data System (ADS)

    Wei, Wei; Wang, Jing; Li, Dong-hai; Zhu, Min; Xue, Ya-li

    2010-11-01

    Model-based algorithms are generally employed in active control of combustion oscillations. Since practical combustion processes consist of complex thermal and acoustic couplings, their accurate models and parameters may not be obtained in advance economically, a model free controller is necessary for the control of thermoacoustic instabilities. Active compensation based control algorithm is applied in the suppression of combustion instabilities. Tuning the controller parameters on line, the amplitudes of the acoustic waves can be modulated to desired values. Simulations performed on a control oriented, typical longitudinal oscillations combustor model illustrate the controllers' capability to attenuate combustion oscillations.

  19. Introductory lecture. Advanced laser spectroscopy in combustion chemistry: from elementary steps to practical devices.

    PubMed

    Wolfrum, J

    2001-01-01

    In recent years a large number of linear and nonlinear laser-based diagnostic techniques for nonintrusive measurements of species concentrations, temperatures, and gas velocities in a wide pressure and temperature range with high temporal and spatial resolution have been developed and have become extremely valuable tools to study many aspects of combustion. Beside the nonintrusive diagnostics of technical combustion devices the kinetics and microscopic dynamics of elementary chemical combustion reactions can be investigated in great detail by laser spectroscopy. These investigations show, that a small number of relatively simple elementary steps like H + O2-->OH + O, H2O2-->2OH, O + N2-->NO + N, NH2 + NO-->H2O + N2, OH + N2H control a large variety of combustion phenomena and pollutant formation processes. Laminar flames are ideal objects to develop the application of laser spectroscopic methods for practical combustion systems and to test and improve the gas-phase reaction mechanism in combustion models. Nonintrusive laser point and field measurements are of basic importance in the validation and further development of turbulent combustion models. Nonlinear laser spectroscopic techniques using infrared-visible sum-frequency generation can now bridge the pressure and materials gap to provide kinetic data for catalytic combustion. Finally, the potential of laser techniques for active combustion control in municipal waste incinerators is illustrated.

  20. Technical Mathematics.

    ERIC Educational Resources Information Center

    Flannery, Carol A.

    This manuscript provides information and problems for teaching mathematics to vocational education students. Problems reflect applications of mathematical concepts to specific technical areas. The materials are organized into six chapters. Chapter 1 covers basic arithmetic, including fractions, decimals, ratio and proportions, percentages, and…

  1. Development of High Efficiency Clean Combustion Engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines

    SciTech Connect

    Marriott, Craig; Gonzalez, Manual; Russell, Durrett

    2011-06-30

    This report summarizes activities related to the revised STATEMENT OF PROJECT OBJECTIVES (SOPO) dated June 2010 for the Development of High-Efficiency Clean Combustion engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines (COOPERATIVE AGREEMENT NUMBER DE-FC26-05NT42415) project. In both the spark- (SI) and compression-ignition (CI) development activities covered in this program, the goal was to develop potential production-viable internal combustion engine system technologies that both reduce fuel consumption and simultaneously met exhaust emission targets. To be production-viable, engine technologies were also evaluated to determine if they would meet customer expectations of refinement in terms of noise, vibration, performance, driveability, etc. in addition to having an attractive business case and value. Prior to this activity, only proprietary theoretical / laboratory knowledge existed on the combustion technologies explored The research reported here expands and develops this knowledge to determine series-production viability. Significant SI and CI engine development occurred during this program within General Motors, LLC over more than five years. In the SI program, several engines were designed and developed that used both a relatively simple multi-lift valve train system and a Fully Flexible Valve Actuation (FFVA) system to enable a Homogeneous Charge Compression Ignition (HCCI) combustion process. Many technical challenges, which were unknown at the start of this program, were identified and systematically resolved through analysis, test and development. This report documents the challenges and solutions for each SOPO deliverable. As a result of the project activities, the production viability of the developed clean combustion technologies has been determined. At this time, HCCI combustion for SI engines is not considered production-viable for several reasons. HCCI combustion is excessively sensitive to control variables

  2. FY2010 Annual Progress Report for Advanced Combustion Engine Research and Development

    SciTech Connect

    Singh, Gurpreet

    2010-12-01

    The Advanced Combustion Engine R&D subprogram supports the mission of the Vehicle Technologies Program by removing the critical technical barriers to commercialization of advanced internal combustion engines (ICEs) for passenger and commercial vehicles that meet future Federal emissions regulations. Dramatically improving the efficiency of ICEs and enabling their introduction in conventional as well as hybrid electric vehicles is the most promising and cost-effective approach to increasing vehicle fuel economy over the next 30 years.

  3. Feedback Control of Combustion Instabilities: A Case Study in Active Adaptive Control of Complex Physical Systems

    DTIC Science & Technology

    1989-09-30

    Research & Development Center The technical objectives of the program are: * Study active control of combustion instability in a laboratory scale ...Center The most significant accomplishments for this year are as follows: 1. Modified an existing laboratory scale premixed gas combustor to obtain...program are: " Study active control of combustion instability in a laboratory scale combustor based on fuel flow modulation or an alternative practical

  4. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 18, July--September 1993

    SciTech Connect

    Chow, O.K.; Hargrove, M.J.

    1993-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Continued with data and sample analysis from the pilot-scale tests of Upper Freeport feed coal, air-dried and mulled microagglomerate products; air-dried Pittsburgh No. 8 as-is and mulled products for upcoming Task 3 combustion testing; and prepared two abstracts for presentation for the March 1 994 Coal Utilization and Fuel Systems Conference.

  5. Nutrient and dissolved organic carbon removal from natural waters using industrial by-products.

    PubMed

    Wendling, Laura A; Douglas, Grant B; Coleman, Shandel; Yuan, Zheng

    2013-01-01

    Attenuation of excess nutrients in wastewater and stormwater is required to safeguard aquatic ecosystems. The use of low-cost, mineral-based industrial by-products with high Ca, Mg, Fe or Al content as a solid phase in constructed wetlands potentially offers a cost-effective wastewater treatment option in areas without centralised water treatment facilities. Our objective was to investigate use of water treatment residuals (WTRs), coal fly ash (CFA), and granular activated carbon (GAC) from biomass combustion in in-situ water treatment schemes to manage dissolved organic carbon (DOC) and nutrients. Both CaO- and CaCO(3)-based WTRs effectively attenuated inorganic N species but exhibited little capacity for organic N removal. The CaO-based WTR demonstrated effective attenuation of DOC and P in column trials, and a high capacity for P sorption in batch experiments. Granular activated carbon proved effective for DOC and dissolved organic nitrogen (DON) removal in column trials, but was ineffective for P attenuation. Only CFA demonstrated effective removal of a broad suite of inorganic and organic nutrients and DOC; however, Se concentrations in column effluents exceeded Australian and New Zealand water quality guideline values. Water treated by filtering through the CaO-based WTR exhibited nutrient ratios characteristic of potential P-limitation with no potential N- or Si-limitation respective to growth of aquatic biota, indicating that treatment of nutrient-rich water using the CaO-based WTR may result in conditions less favourable for cyanobacterial growth and more favourable for growth of diatoms. Results show that selected industrial by-products may mitigate eutrophication through targeted use in nutrient intervention schemes.

  6. Energy Conversion and Combustion Sciences

    DTIC Science & Technology

    2012-03-08

    Rotational /Continuous Detonation • Only Single Initiation needed (Circumvent Initiation/DDT difficulty/loss in PDE ) • 10-100x cycle rate increase • Near...new fuels: 1. Rotational or Continuous Detonation (intense/concentrated combustion); 2. Flameless combustion (distributed combustion process...Steady Exit Flow *CFD Courtesy of NRL Rotational Detonation : (PI: Schauer, AFRL/RZ, working with NRL) Rotational Approach Allows Continuous

  7. Combustion characteristics of husk charcoal

    SciTech Connect

    Shimizu, H.; Kimura, T.; Nishiyama, Y.; Terui, T.

    1984-07-01

    This paper analyzes the factors involved in the extraordinary temperature generation in husk combustion furnaces, and investigates methods of protecting furnaces from heat damage. The combustion characteristics of fixed carbon in rice husks are examined in relation to the air flow rate using different husk charcoals. The theoretical flame temperature in a practical bed was determined from the combustion propagation velocity. It is determined that deviation from the regression line relating the combustion propagation velocity with the specific air flow rate showed a slight correlation with the bulk density of the charcoal samples used.

  8. Microgravity Smoldering Combustion Takes Flight

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The Microgravity Smoldering Combustion (MSC) experiment lifted off aboard the Space Shuttle Endeavour in September 1995 on the STS-69 mission. This experiment is part of series of studies focused on the smolder characteristics of porous, combustible materials in a microgravity environment. Smoldering is a nonflaming form of combustion that takes place in the interior of combustible materials. Common examples of smoldering are nonflaming embers, charcoal briquettes, and cigarettes. The objective of the study is to provide a better understanding of the controlling mechanisms of smoldering, both in microgravity and Earth gravity. As with other forms of combustion, gravity affects the availability of air and the transport of heat, and therefore, the rate of combustion. Results of the microgravity experiments will be compared with identical experiments carried out in Earth's gravity. They also will be used to verify present theories of smoldering combustion and will provide new insights into the process of smoldering combustion, enhancing our fundamental understanding of this frequently encountered combustion process and guiding improvement in fire safety practices.

  9. Light Duty Efficient, Clean Combustion

    SciTech Connect

    Stanton, Donald W.

    2011-06-03

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy’s Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of our objectives were met with fuel efficiency improvement targets exceeded.

  10. Flammability of Heterogeneously Combusting Metals

    NASA Technical Reports Server (NTRS)

    Jones, Peter D.

    1998-01-01

    Most engineering materials, including some metals, most notably aluminum, burn in homogeneous combustion. 'Homogeneous' refers to both the fuel and the oxidizer being in the same phase, which is usually gaseous. The fuel and oxidizer are well mixed in the combustion reaction zone, and heat is released according to some relation like q(sub c) = delta H(sub c)c[((rho/rho(sub 0))]exp a)(exp -E(sub c)/RT), Eq. (1) where the pressure exponent a is usually close to unity. As long as there is enough heat released, combustion is sustained. It is useful to conceive of a threshold pressure beyond which there is sufficient heat to keep the temperature high enough to sustain combustion, and beneath which the heat is so low that temperature drains away and the combustion is extinguished. Some materials burn in heterogeneous combustion, in which the fuel and oxidizer are in different phases. These include iron and nickel based alloys, which burn in the liquid phase with gaseous oxygen. Heterogeneous combustion takes place on the surface of the material (fuel). Products of combustion may appear as a solid slag (oxide) which progressively covers the fuel. Propagation of the combustion melts and exposes fresh fuel. Heterogeneous combustion heat release also follows the general form of Eq.(1), except that the pressure exponent a tends to be much less than 1. Therefore, the increase in heat release with increasing pressure is not as dramatic as it is in homogeneous combustion. Although the concept of a threshold pressure still holds in heterogeneous combustion, the threshold is more difficult to identify experimentally, and pressure itself becomes less important relative to the heat transfer paths extant in any specific application. However, the constants C, a, and E(sub c) may still be identified by suitable data reduction from heterogeneous combustion experiments, and may be applied in a heat transfer model to judge the flammability of a material in any particular actual

  11. Diesel Combustion Fundamentals. Phase 1. Volume 1. Technical Report.

    DTIC Science & Technology

    1987-07-01

    Dry Test (ft3) 747.79 755.87 763.02 770.81 779.27 i) Final Dry Test (ft3) 755.87 763.02 770.81 779.27 786.64 j) Dry Test Diff...ft3) 8.08 7.15 7.79 8.46 7.37 k) Dry Test Temp (°C) 34 35 35 35 35 1) Dry Test Press. (psi) 0.45 0.45 0.45 0.45 0.45 0 m) Sample Volume (cu M) 0.2175...Filter Wt. Dif. (mg) 13.89 12.03 11.90 11.51 11.94 h) Initial Dry Test (ft3) 637.91 646.42 654.83 662.68 670.40 , i) Final Dry Test (ft3) 646.42

  12. Control of Trace Metal Emissions During Coal Combustion

    SciTech Connect

    Thomas C. Ho

    1997-10-01

    Emissions of toxic trace metals in the form of metal fumes or submicron particulates from a coal-fired combustion source have received greater environmental and regulatory concern over the past years. Current practice of controlling these emissions is to collect them at the cold-end of the process by air-pollution control devices (APCDs) such as electrostatic precipitators and baghouses. However, trace metal fumes may not always be effectively collected by these devices because the formed fumes are extremely small. The proposed research is to explore the opportunities for improved control of toxic trace metal emissions, alternatively, at the hot-end of the coal combustion process, i.e., in the combustion chamber. The technology proposed is to prevent the metal fumes from forming during the process, which would effectively eliminate the metal emission problems. Specifically, the technology is to employ suitable sorbents to (1) reduce the amount of metal volatilization during combustion and (2) capture volatilized metal vapors. The objectives of the project are to demonstrate the technology and to characterize the metal capture process during coal combustion in a fluidized bed combustor. The project was started on July 1, 1994 and this is the thirteenth quarterly technical progress report. Specifically, the following progress has been made during this performance period from July 1, 1997 through September 30, 1997.

  13. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-08-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, conbustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Sciences, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the full-scale tests. Approximately nine BCFs will be in dry ultra-fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  14. FY2009 Annual Progress Report for Advanced Combustion Engine Research and Development

    SciTech Connect

    none,

    2009-12-01

    Fiscal Year 2009 Annual Progress Report for the Advanced Combustion Engine Research and Development (R&D) subprogram. The Advanced Combustion Engine R&D subprogram supports the mission of the VTP program by removing the critical technical barriers to commercialization of advanced internal combustion engines (ICEs) for passenger and commercial vehicles that meet future Federal emissions regulations. Dramatically improving the efficiency of ICEs and enabling their introduction in conventional as well as hybrid electric vehicles is the most promising and cost-effective approach to increasing vehicle fuel economy over the next 30 years.

  15. Combustion Branch Website Development

    NASA Technical Reports Server (NTRS)

    Bishop, Eric

    2004-01-01

    The NASA combustion branch is a leader in developing and applying combustion science to focused aerospace propulsion systems concepts. It is widely recognized for unique facilities, analytical tools, and personnel. In order to better communicate the outstanding research being done in this Branch to the public and other research organization, a more substantial website was desired. The objective of this project was to build an up-to-date site that reflects current research in a usable and attractive manner. In order to accomplish this, information was requested from all researchers in the Combustion branch, on their professional skills and on the current projects. This information was used to fill in the Personnel and Research sections of the website. A digital camera was used to photograph all personnel and these photographs were included in the personnel section as well. The design of the site was implemented using the latest web standards: xhtml and external css stylesheets. This implementation conforms to the guidelines recommended by the w3c. It also helps to ensure that the web site is accessible by disabled users, and complies with Section 508 Federal legislation (which mandates that all Federal websites be accessible). Graphics for the new site were generated using the gimp (www.gimp.org) an open-source graphics program similar to Adobe Photoshop. Also, all graphics on the site were of a reasonable size (less than 20k, most less than 2k) so that the page would load quickly. Technologies such as Macromedia Flash and Javascript were avoided, as these only function on some clients which have the proper software installed or enabled. The website was tested on different platforms with many different browsers to ensure there were no compatibility issues. The website was tested on windows with MS IE 6, MSIE 5 , Netscape 7, Mozilla and Opera. On a Mac, the site was tested with MS IE 5 , Netscape 7 and Safari.

  16. Combustion of White Phosphorus

    NASA Astrophysics Data System (ADS)

    Keiter, Richard L.; Gamage, Chaminda P.

    2001-07-01

    The reaction of white phosphorus with pure oxygen is conveniently and safely demonstrated by carrying out the reaction in a retort that has its open end submerged in water. After filling the retort with oxygen gas, a small amount of white phosphorus is introduced and heated with a hot-plate until it ignites. The spectacular reaction leads to consumption and expulsion of oxygen gas, creation of a partial vacuum in the retort, and back suction of water that extinguishes the combustion. Featured on the Cover

  17. Lithium Combustion: A Review

    DTIC Science & Technology

    1990-12-01

    lithium vapors generated with air formed an intense white flame that produced branched- chain condensation aerosol particles, of concentrations 򓆄 mg/im3...generated chain -aggregate lithium combustion aerosols in dry, COg-free air prior to reaction with 0, 0.10, 0.50, 1.0, 1.75, or 5.0% CO in air at a...In order to burn in gaseous chlorine or in bromine or iodine vapor, lithium needs to be heated. With iodine vapor, the reaction is accompanied by

  18. Hybrid fluidized bed combuster

    DOEpatents

    Kantesaria, Prabhudas P.; Matthews, Francis T.

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  19. Field demonstration project using clean coal technology by-products

    SciTech Connect

    Kim, Sung Hwan; Nodjomian, S.; Wolfe, W.

    1995-03-01

    The disposal of flue gas desulfurization (FGD) by-products has become a major concern as issues of emission cleansing and landfill costs continue to rise. Laboratory tests conducted in the Department of Civil Engineering at The Ohio State University have shown that the dry FGD by-products possess certain engineering properties which have been proven desirable in a considerable number of construction uses. As a follow on to the laboratory program, a field investigation into possible engineering uses of dry FGD wastes was initiated. In the work presented in this paper, FGD by-products were used to reconstruct the failed portion of a highway embankment. The paper presents the procedures used in the process and examines the stability of the repaired highway embankment.

  20. Chlorination of humic materials: Byproduct formation and chemical interpretations

    USGS Publications Warehouse

    Reckhow, D.A.; Singer, P.C.; Malcolm, R.L.

    1990-01-01

    Ten aquatic humic and fulvic acids were isolated and studied with respect to their reaction with chlorine. Yields of TOX, chloroform, trichloroacetic acid, dichloroacetic acid, dichloroacetonitrile, and 1,1,1-trichloropropanone were measured at pH 7 and 12. Humic acids produced higher concentrations than their corresponding fulvic acids of all byproducts except 1,1,1-trichloropropanone. Chlorine consumption and byproduct formation were related to fundamental chemical characteristics of the humic materials. A statistical model was proposed for activated aromatic content based on 13C NMR and base titration data. The values estimated from this model were found to be well correlated with chlorine consumption. Specific byproduct formation was related to UV absorbance, nitrogen content, or the activated aromatic content. ?? 1990 American Chemical Society.

  1. Bioluminescent toxicity assay of synfuel by-product waters

    SciTech Connect

    Delistraty, D.

    1984-05-01

    Large amounts of complex by-product waters, potentially toxic to biological systems, are generated during in situ recovery of fuels from oil shale, coal, and tar sand deposits. Since these by-product waters may contain a broad spectrum of organic and inorganic pollutants, analysis of individual compounds may not always be practical. Separation of complex by-product water into environmentally interpretable hydrophilic (HP) and organophilic (OP) fractions can, however, provide a useful approach for initial toxicity evaluation. The Microtox assay was developed by Beckman Microbics Operations. For this assay, reduction of bacterial luminescence upon exposure to potential inhibitors was used as an index of toxicity. This paper presents results of the Microtox assay on eight whole waters and their HP and OP fractions, derived from oil shale, coal, and tar sand recovery processes.

  2. AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

    EPA Science Inventory

    The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

  3. Path planning during combustion mode switch

    SciTech Connect

    Jiang, Li; Ravi, Nikhil

    2015-12-29

    Systems and methods are provided for transitioning between a first combustion mode and a second combustion mode in an internal combustion engine. A current operating point of the engine is identified and a target operating point for the internal combustion engine in the second combustion mode is also determined. A predefined optimized transition operating point is selected from memory. While operating in the first combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion engine to approach the selected optimized transition operating point. When the engine is operating at the selected optimized transition operating point, the combustion mode is switched from the first combustion mode to the second combustion mode. While operating in the second combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion to approach the target operating point.

  4. Plasma igniter for internal-combustion engines

    NASA Technical Reports Server (NTRS)

    Breshears, R. R.; Fitzgerald, D. J.

    1978-01-01

    Hot ionized gas (plasma) ignites air/fuel mixture in internal combustion engines more effectively than spark. Electromagnetic forces propel plasma into combustion zone. Combustion rate is not limited by flame-front speed.

  5. Some Factors Affecting Combustion in an Internal-Combustion Engine

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Cohn, Mildred

    1936-01-01

    An investigation of the combustion of gasoline, safety, and diesel fuels was made in the NACA combustion apparatus under conditions of temperature that permitted ignition by spark with direct fuel injection, in spite of the compression ratio of 12.7 employed. The influence of such variables as injection advance angle, jacket temperature, engine speed, and spark position was studied. The most pronounced effect was that an increase in the injection advance angle (beyond a certain minimum value) caused a decrease in the extent and rate of combustion. In almost all cases combustion improved with increased temperature. The results show that at low air temperatures the rates of combustion vary with the volatility of the fuel, but that at high temperatures this relationship does not exist and the rates depend to a greater extent on the chemical nature of the fuel.

  6. Preliminary assessment of combustion modes for internal combustion wave rotors

    NASA Technical Reports Server (NTRS)

    Nalim, M. Razi

    1995-01-01

    Combustion within the channels of a wave rotor is examined as a means of obtaining pressure gain during heat addition in a gas turbine engine. Several modes of combustion are considered and the factors that determine the applicability of three modes are evaluated in detail; premixed autoignition/detonation, premixed deflagration, and non-premixed compression ignition. The last two will require strong turbulence for completion of combustion in a reasonable time in the wave rotor. The compression/autoignition modes will require inlet temperatures in excess of 1500 R for reliable ignition with most hydrocarbon fuels; otherwise, a supplementary ignition method must be provided. Examples of combustion mode selection are presented for two core engine applications that had been previously designed with equivalent 4-port wave rotor topping cycles using external combustion.

  7. Land application uses for dry FGD by-products

    SciTech Connect

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W. ); Haefner, R. . Water Resources Div.)

    1993-04-01

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. Presently FGD by-product materials are treated as solid wastes and must be landfilled. However, landfill sites are becoming more scarce and tipping fees are constantly increasing. It is, therefore, highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. In summary Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD byproduct materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  8. Final Technical Report

    SciTech Connect

    Philip Malte

    2004-11-30

    The objective of the research is the reduction of emissions of NOx and carbon from wood waste combustion and dryer systems. Focus in on suspension (dust) burners, especially the cyclone burners that are widely used in the industry. Computational fluid dynamics (CFD) is used to help understand the details of combustion and pollutant formation in wood waste combustion systems, and to help determine the potential of combustion modification for reducing emissions. Field burners are examined with the modeling.

  9. Isotopic signature of atmospheric phosphate emitted from coal combustion

    NASA Astrophysics Data System (ADS)

    Weinberger, Roi; Weiner, Tal; Angert, Alon

    2016-07-01

    Atmospheric deposition of phosphorus (P) serves as an important nutrient input for many terrestrial, marine and freshwater ecosystems, influencing their biogeochemistry and primary production. Fossil fuel combustion, principally coal, is estimated to be a major source of atmospheric-P in industrialized regions. In this research, we aim to find a distinct isotopic signature for fly coal ash, the by-product of coal combustion that is emitted to the atmosphere. This signature could be used to identify coal's contribution to atmospheric-P. For this aim, ten fly coal ash samples from different coal sources, collected by power station filters, were analyzed for P concentrations and stable oxygen isotopic composition (δ18OP). Two inorganic phosphate fractions were analyzed: HCl-extractable and resin-extractable (bioavailable P). High HCl-P concentrations of up to 3500 μg P/g ash were found with a distinct δ18OP range of 17.1-20.5‰. The resin-P concentrations were substantially lower (<8 μg/g) with a wider and significantly lower δ18OP range of 10.6-16.5‰. The ash samples were found to have HCl-P δ18OP higher in ∼0-∼9‰ relative to the source coal. Similar isotopic values were found for ash with the same coal source country, regardless of the power station. Despite the low bioavailable P concentrations, fly ash could still be an important atmospheric P source to the biosphere since these combustion products likely acidify in the atmosphere to become bioavailable. This is also supported by our finding that smaller particles, which are more indicative of the particles actually emitted to the atmosphere, are significantly P-richer. Natural dust sources' δ18OP overlap fly ash's range, complicating the assessment of coal's contribution. Nonetheless, our results provide a new tool for identification of fossil fuel combustion sources in local and global atmospheric P deposition.

  10. Obtaining lipases from byproducts of orange juice processing.

    PubMed

    Okino-Delgado, Clarissa Hamaio; Fleuri, Luciana Francisco

    2014-11-15

    The presence of lipases was observed in three byproducts of orange juice processing: peel, core and frit. The enzymes were characterised biochemically over a wide pH range from neutral (6-7) to alkaline (8-9). The optimal temperature for the activity of these byproducts showed wide range at 20°C to 70°C, indicating fairly high thermostability. The activities were monitored on p-NP-butyrate, p-NP-laurate and p-NP-palmitate. For the first time, lipase activity was detected in these residues, reaching 68.5 lipase U/g for the crude extract from fractions called frit.

  11. Fuel Effects on Gas Turbine Combustion

    DTIC Science & Technology

    1983-01-01

    W. S., Combustion Considerations for Future Jet Fuels, Sixteenth Symposium (International) on Combustion , The Combustion Institute, pp. 1631-1638...AFWAL-TR-83-2004 -. i FUEL EFFECTS ON SGAS TURBINE COMBUSTION A. H. Lefebvre <.A t • Combustion Laboratory Thermal Science and Propulsion Center...PERIOD COVEREDFinal Report for Period FUEL EFFECTS ON GAS TURBINE COMBUSTION 21 Sep 81 - 23 Dec 82 6. PERFORMING OIG. REPORT NUMBER ś. AUT"HOR(.) S

  12. Strontium Isotope Study of Coal Untilization By-products Interacting with Environmental Waters

    SciTech Connect

    Spivak-Birndorf, Lev J; Stewart, Brian W; Capo, Rosemary C; Chapman, Elizabeth C; Schroeder, Karl T; Brubaker, Tonya M

    2011-09-01

    Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements—including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc—during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ({sup 87}Sr/{sup 86}Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-{sup 87}Sr/{sup 86}Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB–water interaction.

  13. Combustion of Methane Hydrate

    NASA Astrophysics Data System (ADS)

    Roshandell, Melika

    A significant methane storehouse is in the form of methane hydrates on the sea floor and in the arctic permafrost. Methane hydrates are ice-like structures composed of water cages housing a guest methane molecule. This caged methane represents a resource of energy and a potential source of strong greenhouse gas. Most research related to methane hydrates has been focused on their formation and dissociation because they can form solid plugs that complicate transport of oil and gas in pipelines. This dissertation explores the direct burning of these methane hydrates where heat from the combustion process dissociates the hydrate into water and methane, and the released methane fuels the methane/air diffusion flame heat source. In contrast to the pipeline applications, very little research has been done on the combustion and burning characteristics of methane hydrates. This is the first dissertation on this subject. In this study, energy release and combustion characteristics of methane hydrates were investigated both theoretically and experimentally. The experimental study involved collaboration with another research group, particularly in the creation of methane hydrate samples. The experiments were difficult because hydrates form at high pressure within a narrow temperature range. The process can be slow and the resulting hydrate can have somewhat variable properties (e.g., extent of clathration, shape, compactness). The experimental study examined broad characteristics of hydrate combustion, including flame appearance, burning time, conditions leading to flame extinguishment, the amount of hydrate water melted versus evaporated, and flame temperature. These properties were observed for samples of different physical size. Hydrate formation is a very slow process with pure water and methane. The addition of small amounts of surfactant increased substantially the hydrate formation rate. The effects of surfactant on burning characteristics were also studied. One finding

  14. Dioxinlike properties of a trichloroethylene combustion-generated aerosol

    SciTech Connect

    Villalobos, S.A.; Anderson, M.J.; Hinton, D.E.

    1996-07-01

    Conventional chemical analyses of incineration by-products identify compounds of known toxicity but often fail to indicate the presence of other chemicals that may pose health risks. In a previous report, extracts from soot aerosols formed during incomplete combustion of trichloroethylene (TCE) and pyrolysis of plastics exhibited a dioxinlike response when subjected to a keratinocyte assay. To verify this dioxinlike effect, the complete extract, its polar and nonpolar fractions, some containing primarily halogenated aromatic hydrocarbons, were evaluated for toxicity using an embryo assay, for antiestrogenicity using primary liver cell cultures, and for the ability to transform the aryl hydrocarbon receptor into its DNA binding form using liver cytosol in a gel retardation assay. Each of these assays detect dioxinlike effects. Medaka (Oryzias latipes) embryos and primary liver cell cultures of rainbow trout (Oncorhynchus mykiss) were exposed to concentrations of extract ranging from 0.05 to 45 {mu}g/l. 67 refs., 7 figs., 3 tabs.

  15. Liquid propellant rocket combustion instability

    NASA Technical Reports Server (NTRS)

    Harrje, D. T.

    1972-01-01

    The solution of problems of combustion instability for more effective communication between the various workers in this field is considered. The extent of combustion instability problems in liquid propellant rocket engines and recommendations for their solution are discussed. The most significant developments, both theoretical and experimental, are presented, with emphasis on fundamental principles and relationships between alternative approaches.

  16. Manifold methods for methane combustion

    SciTech Connect

    Yang, B.; Pope, S.B.

    1995-10-01

    Great progresses have been made in combustion research, especially, the computation of laminar flames and the probability density function (PDF) method in turbulent combustion. For one-dimensional laminar flames, by considering the transport mechanism, the detailed chemical kinetic mechanism and the interactions between these two basic processes, today it is a routine matter to calculate flame velocities, extinction, ignition, temperature, and species distributions from the governing equations. Results are in good agreement with those obtained for experiments. However, for turbulent combustion, because of the complexities of turbulent flow, chemical reactions, and the interaction between them, in the foreseeable future, it is impossible to calculate the combustion flow field by directly integrating the basic governing equations. So averaging and modeling are necessary in turbulent combustion studies. Averaging, on one hand, simplifies turbulent combustion calculations, on the other hand, it introduces the infamous closure problems, especially the closure problem with chemical reaction terms. Since in PDF calculations of turbulent combustion, the averages of the chemical reaction terms can be calculated, PDF methods overcome the closure problem with the reaction terms. It has been shown that the PDF method is a most promising method to calculate turbulent combustion. PDF methods have been successfully employed to calculate laboratory turbulent flames: they can predict phenomena such as super equilibrium radical levels, and local extinction. Because of these advantages, PDF methods are becoming used increasingly in industry combustor codes.

  17. PDF Modeling of Turbulent Combustion

    DTIC Science & Technology

    2008-11-30

    extend methodologies for the modeling and simulation of turbulent combustion. Probability density function (PDF) calculations were performed of piloted...were developed to implement the combined methodology of large-eddy simulation (LES) and filtered density function (FDF). Second-order schemes were...was to advance and extend methodologies for the modeling and simulation of turbulent combustion. Probability density function (PDF) calculations were

  18. Method for in situ combustion

    DOEpatents

    Pasini, III, Joseph; Shuck, Lowell Z.; Overbey, Jr., William K.

    1977-01-01

    This invention relates to an improved in situ combustion method for the recovery of hydrocarbons from subterranean earth formations containing carbonaceous material. The method is practiced by penetrating the subterranean earth formation with a borehole projecting into the coal bed along a horizontal plane and extending along a plane disposed perpendicular to the plane of maximum permeability. The subterranean earth formation is also penetrated with a plurality of spaced-apart vertical boreholes disposed along a plane spaced from and generally parallel to that of the horizontal borehole. Fractures are then induced at each of the vertical boreholes which project from the vertical boreholes along the plane of maximum permeability and intersect the horizontal borehole. The combustion is initiated at the horizontal borehole and the products of combustion and fluids displaced from the earth formation by the combustion are removed from the subterranean earth formation via the vertical boreholes. Each of the vertical boreholes are, in turn, provided with suitable flow controls for regulating the flow of fluid from the combustion zone and the earth formation so as to control the configuration and rate of propagation of the combustion zone. The fractures provide a positive communication with the combustion zone so as to facilitate the removal of the products resulting from the combustion of the carbonaceous material.

  19. Land application uses of pressurized fluidized-bed combustion (PFBC) ash

    SciTech Connect

    Beeghly, J.H.; Dick, W.A.; Wolfe, W.

    1993-09-01

    Dry alkaline flue gas desulfurization by-products (dry lime and limestone FGD scrubber ashes) including the American Electric Power (AEP) Tidd PFBC bed and cyclone ash, are being evaluated for beneficial uses via land application for agriculture, mine reclamation, and soil stabilization in a 5 year study that began December, 1990. A 1989 Battelle Memorial Institute report had recommended that the highest priority in stimulating reuse of FGD by-products was the sponsoring of in-field research of coal combustion products generated from high sulfur midwestern coals to (a) better understand and quantify the leach rate, fate and transport of sulfates and trace metals and (b) demonstrate the level of protection necessary to build public acceptance of land-based reuses (1). The specific objectives of the demonstration project are as follows: To characterize the material generated from dry FGD processes; to demonstrate the utilization of dry FGD by-products as an soil amendment material on agricultural lands and on abandoned and active surface coal mines in Ohio; to demonstrate the use of dry FGD by-product as an engineering material for soil stabilization; to determine the quantities of dry FGD material than can be utilized in each of these applications; to determine the environmental and economic impact of utilizing the material.

  20. Environmental release of mercury from coal utilization by-products: will new mercury controls at power plants make a difference?

    SciTech Connect

    Aljoe, W.W.; Feeley, T.J., III; Brickett, L.A.; Schroeder, K.T.; Murphy, J.T.

    2005-09-30

    The US Department of Energy's National Energy Technology Laboratory (DOE/NETL) uses the term coal utilization by-products (CUBs) to describe the solid materials produced by the combustion or gasification of coal. The following general observations can be drawn from results of field tests that have been carried out thus far to determine whether new technologies for mercury emission control at coal power plants will affect the release of mercury from CUBs. There appears to be only minimal potential mercury release to the environment in typical disposal or utilization application for CUBs generated using ACI control technologies. There appears to be only minimal mercury release to the environment for CUBs generated using wet FGD control technologies. The amount of mercury leached from CUBs samples tested is significantly lower than the federal drinking water standards and water quality criteria for the protection of aquatic life. 3 figs., 2 tabs.

  1. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  2. Pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect

    Not Available

    1989-11-01

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  3. History of the internal combustion engine

    SciTech Connect

    Somerscales, E.F.C. ); Zagotta, A.A. )

    1989-01-01

    The study of engineering history by the practioners of engineering is not well-developed. This is unfortunate, because if nothing else, it is the culture of our profession, but even more importantly, it provides us with a proper understanding of current and future engineering. Without an adequate historical background the engineer could, for example, respond incorrectly to problems that might arise in some device or make inappropriate changes in the design. History can also suggest the path that might be followed by a new product, and thereby guide the development and marketing. Because of the fuller appreciation of the art and science of engineering that is provided by an awareness of engineering history, it seems appropriate for the ASME to recognize the role in our profession. The papers in this volume, which deal and various aspects of the history of the internal combustion engine, were presented in a session at the Fall Technical Conference of the ASME Internal Combustion Engine Division held in Dearborn, Michigan on October 17, 1989. The session was jointly sponsored and arranged by the Internal Combustion Engine Division and by the History and Heritage Committee of ASME. It is the first in what the latter hopes will be a regular series of sessions at various Society meetings jointly sponsored with the different divisions of the Society. It is hoped in this way to raise the consciousness of the engineering community to its history and to encourage in particular the preparation of historical papers by engineer-historians, who are involved in the practice of engineering. An approximate chronological order has been chosen for the arrangement of the papers, with the first, by H.O. Hardenberg, being on the gunpowder engines, which were experimented with from the sixteenth century to the middle of the nineteenth century.

  4. Economics of coal combustion residue transportation

    SciTech Connect

    Sevim, H.; Gwamaka, S.

    1995-12-31

    A group of researchers at the Southern Illinois University is engaged in a research project whereby technical, environmental, and economic feasibility of coal combustion residue disposal into old underground coal mines is being investigated. Safe and economic transportation of residues from power plants to mine sites is an important segment of this project. A number of transportation alternatives have been examined, and among these, pneumatic trucks, pressure differential rail cars, and collapsible intermodal containers have been found to be promising. In this paper, all three alternatives are applied to hypothetical cases pertaining to central and southern Illinois. The operating scenarios are described and a comparative economic analysis is conducted using After-Tax Cost method. Each alternative is evaluated for varying distances and tonnages to reveal its favorable operating range.

  5. Spray combustion experiments and numerical predictions

    NASA Technical Reports Server (NTRS)

    Mularz, Edward J.; Bulzan, Daniel L.; Chen, Kuo-Huey

    1993-01-01

    The next generation of commercial aircraft will include turbofan engines with performance significantly better than those in the current fleet. Control of particulate and gaseous emissions will also be an integral part of the engine design criteria. These performance and emission requirements present a technical challenge for the combustor: control of the fuel and air mixing and control of the local stoichiometry will have to be maintained much more rigorously than with combustors in current production. A better understanding of the flow physics of liquid fuel spray combustion is necessary. This paper describes recent experiments on spray combustion where detailed measurements of the spray characteristics were made, including local drop-size distributions and velocities. Also, an advanced combustor CFD code has been under development and predictions from this code are compared with experimental results. Studies such as these will provide information to the advanced combustor designer on fuel spray quality and mixing effectiveness. Validation of new fast, robust, and efficient CFD codes will also enable the combustor designer to use them as additional design tools for optimization of combustor concepts for the next generation of aircraft engines.

  6. LIEKKI and JALO: Combustion and fuel conversion

    NASA Astrophysics Data System (ADS)

    Grace, Thomas M.; Renz, Ulrich; Sarofim, Adel F.

    LIEKKI and JALO are well conceived and structured programs designed to strengthen Finland's special needs in combustion and gasification to utilize a diversity of fuels, increase the ratio of electrical to heat output, and to support the export market. Started in 1988, these two programs provide models of how universities, Technical research center's laboratories (VTT's), and industry can collaborate successfully in order to achieve national goals. The research is focused on long term goals in certain targeted niche areas. This is an effective way to use limited resources. The niche areas were chosen in a rational manner and appear to be appropriate for Finland. The LIEKKl and JALO programs have helped pull together research efforts that were previously more fragmented. For example, the combustion modeling area still appears fragmented. Individual project objectives should be tied to program goals at a very early stage to provide sharper focusing to the research. Both the LIEKKl and JALO programs appear to be strongly endorsed by industry. Industrial members of the Executive Committees were very supportive of these programs. There are good mechanisms for technology transfer in place, and the programs provide opportunities to establish good interfaces between industrial people and the individual researchers. The interest of industry is shown by the large number of applied projects that are supported by industry. This demonstrates the relevancy of the programs. There is a strong interaction between the JALO program and industry in black liquor gasification.

  7. Co-combustion feasibility study. Final report

    SciTech Connect

    Handcock, D.J.

    1995-01-01

    This report investigates the technical and economic feasibility of co-combusting municipal sewage sludge produced by the Saratoga County Sewer District No. 1 with paper mill sludge produced by the Cottrell Paper Company, Encore Paper Company, International Paper Company, Mohawk Paper Mills, and TAGSONS Papers at the Saratoga County Sewer District No. 1`s secondary wastewater treatment plant and recovering any available energy products. The co-combustion facility would consist of sludge and wood chip storage and conveying systems, belt filter presses, screw presses, fluidized-bed incinerators, venturi scrubbers and tray cooling systems, ash dewatering facilities, heat recovery steam generators, gas-fired steam superheaters, and a back-pressure steam turbine system. Clean waste wood chips would be used as an auxiliary fuel in the fluidized-bed incinerators. It is recommended that the ash produced by the proposed facility be beneficially used, potentially as a raw material in the manufacture of cement and/or as an interim barrier layer in landfills.

  8. NASA Microgravity Combustion Science Program

    NASA Technical Reports Server (NTRS)

    King, Merrill K.

    1997-01-01

    Combustion is a key element of many critical technologies used by contemporary society. For example, electric power production, home heating, surface and air transportation, space propulsion, and materials synthesis all utilize combustion as a source of energy. Yet, although combustion technology is vital to our standard of living, it poses great challenges to maintaining a habitable environment. For example, pollutants, atmospheric change and global warming, unwanted fires and explosions, and the incineration of hazardous wastes are major problem areas which would benefit from improved understanding of combustion. Effects of gravitational forces impede combustion studies more than most other areas of science since combustion involves production of high-temperature gases whose low density results in buoyant motion, vastly complicating the execution and interpretation of experiments. Effects of buoyancy are so ubiquitous that their enormous negative impact on the rational development of combustion science is generally not recognized. Buoyant motion also triggers the onset of turbulence, yielding complicating unsteady effects. Finally, gravity forces cause particles and drops to settle, inhibiting deconvoluted studies of heterogeneous flames important to furnace, incineration and power generation technologies. Thus, effects of buoyancy have seriously limited our capabilities to carry out 'clean' experiments needed for fundamental understanding of flame phenomena. Combustion scientists can use microgravity to simplify the study of many combustion processes, allowing fresh insights into important problems via a deeper understanding of elemental phenomena also found in Earth-based combustion processes and to additionally provide valuable information concerning how fires behave in microgravity and how fire safety on spacecraft can be enhanced.

  9. Combustion instability control in the model of combustion chamber

    NASA Astrophysics Data System (ADS)

    Akhmadullin, A. N.; Ahmethanov, E. N.; Iovleva, O. V.; Mitrofanov, G. A.

    2013-12-01

    An experimental study of the influence of external periodic perturbations on the instability of the combustion chamber in a pulsating combustion. As an external periodic disturbances were used sound waves emitted by the electrodynamics. The purpose of the study was to determine the possibility of using the method of external periodic perturbation to control the combustion instability. The study was conducted on a specially created model of the combustion chamber with a swirl burner in the frequency range from 100 to 1400 Hz. The study found that the method of external periodic perturbations may be used to control combustion instability. Depending on the frequency of the external periodic perturbation is observed as an increase and decrease in the amplitude of the oscillations in the combustion chamber. These effects are due to the mechanisms of synchronous and asynchronous action. External periodic disturbance generated in the path feeding the gaseous fuel, showing the high efficiency of the method of management in terms of energy costs. Power required to initiate periodic disturbances (50 W) is significantly smaller than the thermal capacity of the combustion chamber (100 kW).

  10. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 15, October--December 1992

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1993-03-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1992, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; re-analyzed the samples from the pilot-scale ash deposition tests of the first nine feed coals and BCFs using a modified CCSEM technique; updated the topical summary report; and prepared for upcoming tests of new BCFs being produced.

  11. (Pulsed atmospheric fluidized bed combustion (PAFBC))

    SciTech Connect

    Not Available

    1988-10-01

    This first Quarterly Technical Progress Report presents the results of work accomplished during the period April 19 through July 24,1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. the program scope consisted of two tasks; the first was to establish preliminary feasibility by the use of theoretical and state-of-the-art information. This task was completed during the first quarter of the contract period and a topical report entitled, Pulsed Atmospheric Fluidized Bed combustion (PAFBC) - Preliminary Feasibility Study'' was prepared as a decision point to proceed'' deliverable in accordance with the terms of the contract. This first quarterly progress report therefore covers the contract activities subsequent to the approval of the feasibility study and the decision to proceed with the Task 2 effort. As the initial quarterly technical progress report, this document includes a subsection on background which will be omitted in subsequent reports. All effort during this period was devoted to the design and analysis of the PAFBC. Design drawings were prepared and fabrication and procurement initiated. Quotations were evaluated and a fabrication contract awarded. A site adjacent to the MTCI building was chosen for the installation of the PAFBC. Some ancillary components were purchased, renovated, and tested. Some delays in delivery of components have resulted in some schedule delay. It is anticipated that the program pace will accelerate as soon as parts are received and installation and assembly are initiated. 10 figs.,1 tab.

  12. Multiuser Droplet Combustion Apparatus Developed to Conduct Combustion Experiments

    NASA Technical Reports Server (NTRS)

    Myhre, Craig A.

    2001-01-01

    A major portion of the energy produced in the world today comes from the combustion or burning of liquid hydrocarbon fuels in the form of droplets. However, despite vigorous scientific examinations for over a century, researchers still lack a full understanding of many fundamental combustion processes of liquid fuels. Understanding how these fuel droplets ignite, spread, and extinguish themselves will help us develop more efficient ways of energy production and propulsion, as well as help us deal better with the problems of combustion-generated pollution and fire hazards associated with liquid combustibles. The ability to conduct more controlled experiments in space, without the complication of gravity, provides scientists with an opportunity to examine these complicated processes closely. The Multiuser Droplet Combustion Apparatus (MDCA) supports this continued research under microgravity conditions. The objectives are to improve understanding of fundamental droplet phenomena affected by gravity, to use research results to advance droplet combustion science and technology on Earth, and to address issues of fire hazards associated with liquid combustibles on Earth and in space. MDCA is a multiuser facility designed to accommodate different combustion science experiments. The modular approach permits the on-orbit replacement of droplet combustion principal investigator experiments such as different fuels, droplet-dispensing needles, and droplet-tethering mechanisms. Large components such as the avionics, diagnostics, and base-plate remain on the International Space Station to reduce the launch mass of new experiments. MDCA is also designed to operate in concert with ground systems on Earth to minimize the involvement of the crew during orbit.

  13. Greenhouse gas life cycle assessment of products arising from the rendering of mammalian animal byproducts in the UK.

    PubMed

    Ramirez, Angel D; Humphries, Andrea C; Woodgate, Stephen L; Wilkinson, Robert G

    2012-01-03

    Animal byproducts (ABP) are unavoidable byproduct of meat production that are categorized under EU legislation into category 1, 2, and 3 materials, which are normally treated by rendering. Rendering is a thermal process that produces rendered fat and protein. Heat is provided from the combustion of natural gas and self-produced rendered fat. The main objectives of the study were (i) to assess energy intensity in the UK rendering industry, and (ii) to quantify the greenhouse gas emissions associated with the production of mammalian rendered products using life cycle assessment. Thermal energy requirements were 2646 and 1357 kJ/kg, whereas electricity requirements were 260 and 375 kJ/kg for category 1 and 3 ABP respectively. Fossil CO(2) emissions were -0.77 and 0.15 kg CO(2)e/kg category 1 and 3 mammalian rendered fat respectively and 0.15 kg CO(2)e/kg processed animal protein. These were low relative to vegetable products such as palm oil and soya bean meal because (i) ABP were considered wastes that do not incur the environmental burden of their production, and (ii) the rendering process produces biofuels that can be used to generate energy that can be used to offset the use of fossil fuels in other systems.

  14. A novel anaerobic two-phase system for biohydrogen production and in situ extraction of organic acid byproducts.

    PubMed

    Sarma, Saurabh Jyoti; Brar, Satinder Kaur; Le Bihan, Yann; Buelna, Gerardo

    2015-06-01

    Owing to CO2-free emission, hydrogen is considered as a potential green alternative of fossil fuels. Water is the major emission of hydrogen combustion process and gravimetric energy density of hydrogen is nearly three times more than that of gasoline and diesel fuel. Biological hydrogen production, therefore, has commercial significance; especially, when it is produced from low-cost industrial waste-based feedstock. Light independent anaerobic fermentation is simple and mostly studied method of biohydrogen production. During hydrogen production by this method, a range of organic acid byproducts are produced. Accumulation of these byproducts is inhibitory for hydrogen production as it may result in process termination due to sharp decrease in medium pH or by possible metabolic shift. For the first time, therefore, a two-phase anaerobic bioreactor system has been reported for biohydrogen production which involves in situ extraction of different organic acids. Among different solvents, based on biocompatibility oleyl alcohol has been chosen as the organic phase of the two-phase system. An organic:aqueous phase ratio of 1:50 has been found to be optimum for hydrogen production. The strategy was capable of increasing the hydrogen production from 1.48 to 11.65 mmol/L-medium.

  15. 10 CFR 20.2008 - Disposal of certain byproduct material.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 1 2012-01-01 2012-01-01 false Disposal of certain byproduct material. 20.2008 Section 20.2008 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Waste Disposal... accordance with part 61 of this chapter, even though it is not defined as low-level radioactive...

  16. 10 CFR 20.2008 - Disposal of certain byproduct material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Disposal of certain byproduct material. 20.2008 Section 20.2008 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Waste Disposal... accordance with part 61 of this chapter, even though it is not defined as low-level radioactive...

  17. 10 CFR 20.2008 - Disposal of certain byproduct material.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 1 2014-01-01 2014-01-01 false Disposal of certain byproduct material. 20.2008 Section 20.2008 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Waste Disposal... accordance with part 61 of this chapter, even though it is not defined as low-level radioactive...

  18. Determining Machining Parameters of Corn Byproduct Filled Plastics

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In a collaborative project between the USDA and Northern Illinois University, the use of corn ethanol processing byproducts (i.e., DDGS) as bio-filler materials in the compression molding of phenolic plastics has been studied. This paper reports on the results of a machinability study in the milling...

  19. 30 CFR 1206.358 - What are byproduct transportation allowances?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., DEPARTMENT OF THE INTERIOR Natural Resources Revenue PRODUCT VALUATION Geothermal Resources § 1206.358 What... the geothermal lease, unit, or participating area, you are allowed a deduction in determining value... participating area, or from a geothermal use facility to a byproduct recovery facility when that...

  20. Determination of Machining Parameters of Corn Byproduct Filled Plastics

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In a collaborative project between the USDA and Northern Illinois University, the use of ethanol corn processing by-products as bio-filler materials in the compression molding of phenolic plastics has been studied. This paper reports on the results of a machinability study in the milling of various ...

  1. DISINFECTION BY-PRODUCT CONTROL THROUGH BIOLOGICAL FILTRATION

    EPA Science Inventory

    Disinfection by-product (DBP) control through biofiltration is defined as the removal of DBP precursor mateterial (PM) by bacteria attached to the filte nedia. The PM consists of dissolved organic matter (DOM) and is utilized by the filter bacteria as a substrate for cell mainten...

  2. Genotoxicity of Disinfection By-products: Comparison to Carcinogenicity

    EPA Science Inventory

    Disinfection by-products (DBPs) can be formed when water is disinfected by various agents such as chlorine, ozone, or chloramines. Among the >600 DBPs identified in drinking water, 11 are regulated by the U.S. Environmental Protection Agency, and another ~70 DBPs that occur at s...

  3. Use of agricultural byproducts as fillers in polymer composites

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A recent trend in polymer research is to use natural renewable materials as "green" raw materials for industrial applications. One of the applications pursued by the authors is to produce polymeric composites consisting of a polymer and an agricultural byproduct or waste. In this way, there is no c...

  4. Resistant starch and dietary fibers from cereal by-products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Dried distillers grains (DDG) are a cereal byproduct from ethanol distillation process. On a dry weight basis, DDG is composed of 13% fat, 30% protein, 33% fiber, with the remainder various carbohydrates. Only 6-8% of starch in DDG is in resistant form (dietary fiber). Because only about 6% of DD...

  5. 30 CFR 1206.358 - What are byproduct transportation allowances?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false What are byproduct transportation allowances? 1206.358 Section 1206.358 Mineral Resources OFFICE OF NATURAL RESOURCES REVENUE, DEPARTMENT OF THE INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Geothermal Resources § 1206.358 What are...

  6. 30 CFR 1206.358 - What are byproduct transportation allowances?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false What are byproduct transportation allowances? 1206.358 Section 1206.358 Mineral Resources OFFICE OF NATURAL RESOURCES REVENUE, DEPARTMENT OF THE INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Geothermal Resources § 1206.358 What are...

  7. 30 CFR 1206.358 - What are byproduct transportation allowances?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false What are byproduct transportation allowances? 1206.358 Section 1206.358 Mineral Resources OFFICE OF NATURAL RESOURCES REVENUE, DEPARTMENT OF THE INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Geothermal Resources § 1206.358 What are...

  8. Conversion of agricultural by-products to methyl cellulose

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Agricultural residues are attractive raw materials for the production of industrial polymers because they are renewable and biodegradable, involve less toxic materials during manufacturing, add value to agricultural byproducts, and decrease the global dependence on petroleum-based feedstock. In this...

  9. Sustainable Disposal of Edible Food Byproducts at University Research Farms

    ERIC Educational Resources Information Center

    Baldwin, Sherill; Chung, Kimberly

    2007-01-01

    Purpose: Research at agricultural universities often generates food crops that are edible by-products of the research process. The purpose of this paper is to explore the factors that affect decision-making around the disposal of these crops. Understanding decision-making suggests how universities might include food crop production into campus…

  10. Use of meatpacking by-products in fish diets

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Since fish meal is of limited supply and more expensive than most other protein sources, reducing its use in fish feeds will increase profits and improve sustainability of the aquaculture industry. Meat meal, meat and bone meal, and blood meal are by-products of the animal rendering industry and ar...

  11. DRINKING WATER DISINFECTION BYPRODUCTS AND DURATION OF GESTATION

    EPA Science Inventory

    Recent studies of drinking water disinfection by-products (DBPs) suggest high exposure decreases risk of preterm birth. We examined this association with total trihalomethane (TTHM) and five haloacetic acids (HAA5) among 2,041 women in a prospective pregnancy study conducted from...

  12. 29 CFR 784.152 - Operations performed on byproducts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... operations are performed on perishable byproducts. Any operation performed on perishable fish scraps, an unsegregated portion of which is to be canned, would come within the canning (not the processing) part of the exemption. Fish-reduction operations performed on the inedible and still perishable portions of...

  13. THE TOXICOLOGY OF COMPLEX MIXTURES OF DISINFECTION BY-PRODUCTS

    EPA Science Inventory

    Chemical disinfection of water is a major public health advance that has decreased dramatically water-borne disease. Chemical disinfectants react with naturally occurring organic and inorganic matter in water to produce a wide variety of disinfection byproducts (DBPs). DBP num...

  14. Materials with Adsorptive Properties from Agricultural By-Products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This presentation will summarize the use of agricultural by-products (e.g., animal manure and plant waste) as starting materials to adsorb environmental contaminants such as mercury from air, ammonia from air, metal ions from water, and chlorinated organics from water. The results show that the mat...

  15. 29. Coke oven byproduct building "XX" with ammonia stills; powerhouse ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    29. Coke oven by-product building "XX" with ammonia stills; powerhouse with 8 sisters (stacks) in background; conveyor #20 (with break) on right, pulevrized coal storage bunker on left. Looking north/northwest - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  16. 30. XX byproducts building (containing coke gas compressors at north ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    30. XX by-products building (containing coke gas compressors at north end, ammonia stills in south end), #20 coal conveyor jutting out of top on east side, continuing out west side to bunker. Looking south/southeast - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  17. PREDICTING THE FORMATION OF CHLORINATED AND BROMINATED BY-PRODUCTS.

    EPA Science Inventory

    Although disinfection has been and continues to be one of the major public health advances in the 20th century, the disinfectants themselves may react with naturally-occurring materials in treated water to form unintended by-products which may themselves pose risks. This is of p...

  18. OCCURRENCE OF A NEW GENERATION OF DISINFECTION BY-PRODUCTS

    EPA Science Inventory

    A survey of disinfection by-product (DBP) occurrence in the United States was conducted at 12 drinking water treatment plants. In addition to currently regulated DBPs, more than 50 DBPs that rated a high priority for potential toxicity were studied. These priority DBPs included...

  19. ANALYTICAL METHODS FOR WATER DISINFECTION BYPRODUCTS IN FOODS AND BEVERAGES

    EPA Science Inventory

    The determination of exposure to drinking water disinfection byproducts (DBPs) requires an understanding of how drinking water comes into contact with human through multiple pathways. In order to facilitate the investigation of human exposure to DBPs via foods and beverages, anal...

  20. Carcinogenicity of Disinfection By-products and Research Needs

    EPA Science Inventory

    A review by S.D. Richardson et al. (Mutat. Res. 636:178, 2007) presents the first analysis of the 30-year literature on the genotoxicity, carcinogenicity, and occurrence of 87 disinfection by-products (DBPs) identified in drinking water. Of these, 11 are regulated by the U.S. EP...