Transformation of temporal sequences in the zebra finch auditory system

PubMed Central

Lim, Yoonseob; Lagoy, Ryan; Shinn-Cunningham, Barbara G; Gardner, Timothy J

2016-01-01

This study examines how temporally patterned stimuli are transformed as they propagate from primary to secondary zones in the thalamorecipient auditory pallium in zebra finches. Using a new class of synthetic click stimuli, we find a robust mapping from temporal sequences in the primary zone to distinct population vectors in secondary auditory areas. We tested whether songbirds could discriminate synthetic click sequences in an operant setup and found that a robust behavioral discrimination is present for click sequences composed of intervals ranging from 11 ms to 40 ms, but breaks down for stimuli composed of longer inter-click intervals. This work suggests that the analog of the songbird auditory cortex transforms temporal patterns to sequence-selective population responses or ‘spatial codes', and that these distinct population responses contribute to behavioral discrimination of temporally complex sounds. DOI: http://dx.doi.org/10.7554/eLife.18205.001 PMID:27897971

Role of Silica Redistribution in the Rate-State Behavior of Megathrusts: Field Observations and Experimental Results

NASA Astrophysics Data System (ADS)

Fisher, D. M.; Den Hartog, S. A. M.

2014-12-01

Observations of ancient fault zones and results of high temperature friction experiments indicate that silica redistribution influences the rate (response to velocity increases) and state (time-dependent healing) behavior of megathrusts. The Kodiak Accretionary Complex in Alaska has four shear zones that record plate boundary deformation: the Ghost Rocks mélange, the Uganik thrust, the Uyak mélange, and the central belt of the Kodiak Formation. All these examples of underplated rocks represent top-toward-the-trench shear zones that extend along the plate margin for 100's of kms. The first three examples were accreted within the seismogenic zone and record a progressive history from stratal disruption and particulate flow to localized shearing on pervasive web-like arrays of scaly microfaults in shales. Microfaults show evidence for silica dissolution and local reprecipitation in dilational stepovers and in intensely veined sandstone blocks. The fourth example (the central belt) was accreted further downdip, and these rocks have pervasive, regularly spaced en echelon quartz vein systems. Microstructures within veins indicate periodic cracking and sealing during progressive simple shear. Silica depletion zones adjacent to veins indicate diffusive transport of silica in response to local chemical potential gradients. A simple 1-D transport-kinetics model indicates that cracks in this case could be filled with quartz in less than a year and in as little as a week. Rock friction experiments on lithologies similar to Kodiak examples depict three distinct regimes of frictional behavior as a function of increasing temperature, with velocity weakening in a T range that can be related to the seismogenic zone. These three regimes are predicted by a model for gouge deformation that includes thermally activated pressure solution during shear of quartz grains embedded in a foliated matrix. The slip instabilities that characterize the seismogenic zone may therefore be related in part to grain scale diffusive mass transfer of silica. The observations of Kodiak Fault zones indicate that silica redistribution also plays an important role in the interseismic period through crack healing and dissolution of silica, both along the plate interface and within the adjacent rocks that store elastic strain.

The Non-Regularity of Earthquake Recurrence in California: Lessons From Long Paleoseismic Records in Simple vs Complex Fault Regions (Invited)

NASA Astrophysics Data System (ADS)

Rockwell, T. K.

2010-12-01

A long paleoseismic record at Hog Lake on the central San Jacinto fault (SJF) in southern California documents evidence for 18 surface ruptures in the past 3.8-4 ka. This yields a long-term recurrence interval of about 210 years, consistent with its slip rate of ~16 mm/yr and field observations of 3-4 m of displacement per event. However, during the past 3800 years, the fault has switched from a quasi-periodic mode of earthquake production, during which the recurrence interval is similar to the long-term average, to clustered behavior with the inter-event periods as short as a few decades. There are also some periods as long as 450 years during which there were no surface ruptures, and these periods are commonly followed by one to several closely-timed ruptures. The coefficient of variation (CV) for the timing of these earthquakes is about 0.6 for the past 4000 years (17 intervals). Similar behavior has been observed on the San Andreas Fault (SAF) south of the Transverse Ranges where clusters of earthquakes have been followed by periods of lower seismic production, and the CV is as high as 0.7 for some portions of the fault. In contrast, the central North Anatolian Fault (NAF) in Turkey, which ruptured in 1944, appears to have produced ruptures with similar displacement at fairly regular intervals for the past 1600 years. With a CV of 0.16 for timing, and close to 0.1 for displacement, the 1944 rupture segment near Gerede appears to have been both periodic and characteristic. The SJF and SAF are part of a broad plate boundary system with multiple parallel strands with significant slip rates. Additional faults lay to the east (Eastern California shear zone) and west (faults of the LA basin and southern California Borderland), which makes the southern SAF system a complex and broad plate boundary zone. In comparison, the 1944 rupture section of the NAF is simple, straight and highly localized, which contrasts with the complex system of parallel faults in southern California. These observations suggest that the complexity of the southern California fault network is partly responsible for the apparent increase in “noise” and non-periodic behavior, perhaps resulting from stress transfer to adjacent faults after a large earthquake on one fault. The simplicity of the central NAF may account for its relatively simple behavior. If correct, the study of simple plate boundary faults may provide new insights into the constitutive elements of fault zones, and may aid in identifying those components that are critical for better forecasting future seismicity in complex systems.

Monitoring CO2 Intrusion in shallow aquifer using complex electrical methods and a novel CO2 sensitive Lidar-based sensor

NASA Astrophysics Data System (ADS)

Leger, E.; Dafflon, B.; Thorpe, M.; Kreitinger, A.; Laura, D.; Haivala, J.; Peterson, J.; Spangler, L.; Hubbard, S. S.

2016-12-01

While subsurface storage of CO2 in geological formations offers significant potential to mitigate atmospheric greenhouse gasses, approaches are needed to monitor the efficacy of the strategy as well as possible negative consequences, such as leakage of CO2 or brine into groundwater or release of fugitive gaseous CO2. Groundwater leakages can cause subsequent reactions that may also be deleterious. For example, a release of dissolved CO2 into shallow groundwatersystems can decrease groundwater pH which can potentiallymobilize naturally occurring trace metals and ions. In this perspective, detecting and assessing potential leak requires development of novel monitoring techniques.We present the results of using surface electrical resistivity tomography (ERT) and a novel CO2 sensitive Lidar-based sensor to monitor a controlled CO2 release at the ZeroEmission Research and Technology Center (Bozeman, Montana). Soil temperature and moisture sensors, wellbore water quality measurements as well as chamber-based CO2 flux measurements were used in addition to the ERT and a novel Lidar-based sensor to detect and assess potential leakage into groundwater, vadose zone and atmosphere. The three-week release wascarried out in the vadose and the saturated zones. Well sampling of pH and conductivity and surface CO2 fluxes and concentrations measurements were acquired during the release and are compared with complex electricalresistivity time-lapse measurements. The novel Lidar-based image of the CO2 plume were compared to chamber-based CO2 flux and concentration measurements. While a continuous increase in subsurface ERT and above ground CO2 was documented, joint analysis of the above and below ground data revealed distinct transport behavior in the vadose and saturated zones. Two type of transport were observed, one in the vadoze zone, monitored by CO2 flux chamber and ERT, and the other one in the saturated zone, were ERT and wellsampling were carried. The experiment suggests how a range of geophysical, remote sensing, hydrological and geochemical measurement approaches can be optimally configured to detect the distribution and explore behavior of possible CO2 leakages in distinct compartments, including groundwater, vadose zone, and atmosphere.

The Influence of Grain Boundary Fluids on the Recrystallization Behavior in Calcite: A Comparison of "dry" and "wet" Marble Mylonites

NASA Astrophysics Data System (ADS)

Schenk, O.; Urai, J.; Evans, B.

2003-12-01

Carbonate rocks are able to accumulate large amounts of strain and deform crystal-plastically even at low p-T conditions and thus, marble sequences are often the site of strain localization in the upper crust during late-stage deformation in mountain building processes. In this study we sought to identify the effect of fluids on grain boundary morphology and recrystallization processes in marble mylonites during shear zone evolution, as fluids play a major role in the flow behavior of many rock materials during deformation (e.g. quartz, olivine, halite, feldspar). We compared calcite marble mylonites from two geological settings: (a) Schneeberg Complex, Southern Tyrole, Italy and (b) Naxos Metamorphic Core Complex, Greece. The shear zones of the selected areas are suitable for comparison, because they consist of similar lithology and the marble mylonites resemble each other in chemical composition. In addition, calcite-dolomite solvus geothermometry and TEM observations indicate similar p-T conditions for the shear zones formation. However, the two settings are different in the availability of fluids during the shear zone evolution: In the Schneeberg mylonites, both the alteration of minerals during retrograde metamorphism of neighboring micaschists and the existence of veins suggest that fluids were present during mylonitization. The absence of these features in the Naxos samples indicates that fluids were not present during deformation of these mylonites. This difference is also supported by the signature of stable isotopes. Microstructural investigations using optical and scanning electron microscopes on broken and planar surfaces did not indicate major differences between wet and dry mylonites: Grain boundaries of both types of samples display pores with shapes controlled by crystallography, and pore morphologies that are similar to observations from crack and grain-boundary healing experiments. Grain size reduction was predominantly the result of subgrain rotation recrystallization. However, the coarse grains inside the wet protomylonites (Schneeberg) are characterized by intracrystalline shear zones. With the exception of the intracrystalline shear zones, there were no obvious microstructural signatures that were obvious indicators of the presence of fluids, at least for these two field examples.

Seasonal cross-shelf distribution of major zooplankton taxa on the northern Gulf of Alaska shelf relative to water mass properties, species depth preferences and vertical migration behavior

NASA Astrophysics Data System (ADS)

Coyle, Kenneth O.; Pinchuk, Alexei I.

2005-01-01

The cross-shelf distribution of major zooplankton species was examined on the northern Gulf of Alaska (GOA) shelf during the production season for four years, between October 1997 and October 2001. The zooplankton community on the northern GOA shelf consisted of oceanic and neritic species of the North Pacific subarctic species complex. Cross-shelf distribution of the major zooplankton species was influenced by their depth preferences, vertical migration behavior, salinity-temperature preferences, and by cross-shelf water-mass distribution and movement. The neritic community, dominated by Pseudocalanus spp., Metridia pacifica and Calanus marshallae, had highest abundances on the inner shelf, in the Alaska Coastal Current, and in the adjacent fjords in late spring and early summer. The oceanic community, which contained primarily Neocalanus cristatus and Eucalanus bungii, was observed in the Alaskan Stream and adjacent waters near the shelf break. A mid-shelf transition zone contained a mixture of oceanic and neritic species. Prince William Sound (PWS) contained a unique species complex of large mesopelagic copepods, amphipods and shrimp. Neocalanus flemingeri and Oithona similis were abundant in all four regions during spring and early summer. The transition zone commonly crossed much of the shelf between the shelf break and the ACC, but satellite images and CTD data indicate that occasionally a narrow shelf-break front can form, in which case distinct zooplankton species groups are observed on either side of the front. Satellite data also revealed numerous large and small eddies, which probably contribute to cross-shelf mixing in the transition zone.

MULTI-FREQUENCY, MULTI-EPOCH STUDY OF Mrk 501: HINTS FOR A TWO-COMPONENT NATURE OF THE EMISSION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shukla, A.; Chitnis, V. R.; Singh, B. B.

2015-01-01

Since the detection of very high energy (VHE) γ-rays from Mrk 501, its broadband emission of radiation was mostly and quite effectively modeled using the one zone emission scenario. However, broadband spectral and flux variability studies enabled by the multi-wavelength campaigns carried out during the recent years have revealed the rather complex behavior of Mrk 501. The observed emission from Mrk 501 could be due to a complex superposition of multiple emission zones. Moreover, new evidence of detection of very hard intrinsic γ-ray spectra obtained from Fermi-LAT observations has challenged the theories about the origin of VHE γ-rays. Our studiesmore » based on Fermi-LAT data indicate the existence of two separate components in the spectrum, one for low-energy γ-rays and the other for high-energy γ-rays. Using multi-waveband data from several ground- and space-based instruments, in addition to HAGAR data, the spectral energy distribution of Mrk 501 is obtained for various flux states observed during 2011. In the present work, this observed broadband spectral energy distribution is reproduced with a leptonic, multi-zone synchrotron self-Compton (SSC) model.« less

Radiation tolerance of boron doped dendritic web silicon solar cells

NASA Technical Reports Server (NTRS)

Rohatgi, A.

1980-01-01

The potential of dendritic web silicon for giving radiation hard solar cells is compared with the float zone silicon material. Solar cells with n(+)-p-P(+) structure and approximately 15% (AMl) efficiency were subjected to 1 MeV electron irradiation. Radiation tolerance of web cell efficiency was found to be at least as good as that of the float zone silicon cell. A study of the annealing behavior of radiation-induced defects via deep level transient spectroscopy revealed that E sub v + 0.31 eV defect, attributed to boron-oxygen-vacancy complex, is responsible for the reverse annealing of the irradiated cells in the temperature range of 150 to 350 C.

A Red-Light Running Prevention System Based on Artificial Neural Network and Vehicle Trajectory Data

PubMed Central

Li, Pengfei; Li, Yan; Guo, Xiucheng

2014-01-01

The high frequency of red-light running and complex driving behaviors at the yellow onset at intersections cannot be explained solely by the dilemma zone and vehicle kinematics. In this paper, the author presented a red-light running prevention system which was based on artificial neural networks (ANNs) to approximate the complex driver behaviors during yellow and all-red clearance and serve as the basis of an innovative red-light running prevention system. The artificial neural network and vehicle trajectory are applied to identify the potential red-light runners. The ANN training time was also acceptable and its predicting accurate rate was over 80%. Lastly, a prototype red-light running prevention system with the trained ANN model was described. This new system can be directly retrofitted into the existing traffic signal systems. PMID:25435870

A red-light running prevention system based on artificial neural network and vehicle trajectory data.

PubMed

Li, Pengfei; Li, Yan; Guo, Xiucheng

2014-01-01

The high frequency of red-light running and complex driving behaviors at the yellow onset at intersections cannot be explained solely by the dilemma zone and vehicle kinematics. In this paper, the author presented a red-light running prevention system which was based on artificial neural networks (ANNs) to approximate the complex driver behaviors during yellow and all-red clearance and serve as the basis of an innovative red-light running prevention system. The artificial neural network and vehicle trajectory are applied to identify the potential red-light runners. The ANN training time was also acceptable and its predicting accurate rate was over 80%. Lastly, a prototype red-light running prevention system with the trained ANN model was described. This new system can be directly retrofitted into the existing traffic signal systems.

Climate variability and vadose zone controls on damping of transient recharge

USGS Publications Warehouse

Corona, Claudia R.; Gurdak, Jason J.; Dickinson, Jesse; Ferré, T.P.A.; Maurer, Edwin P.

2018-01-01

Increasing demand on groundwater resources motivates understanding of the controls on recharge dynamics so model predictions under current and future climate may improve. Here we address questions about the nonlinear behavior of flux variability in the vadose zone that may explain previously reported teleconnections between global-scale climate variability and fluctuations in groundwater levels. We use hundreds of HYDRUS-1D simulations in a sensitivity analysis approach to evaluate the damping depth of transient recharge over a range of periodic boundary conditions and vadose zone geometries and hydraulic parameters that are representative of aquifer systems of the conterminous United States (U.S). Although the models were parameterized based on U.S. aquifers, findings from this study are applicable elsewhere that have mean recharge rates between 3.65 and 730 mm yr–1. We find that mean infiltration flux, period of time varying infiltration, and hydraulic conductivity are statistically significant predictors of damping depth. The resulting framework explains why some periodic infiltration fluxes associated with climate variability dampen with depth in the vadose zone, resulting in steady-state recharge, while other periodic surface fluxes do not dampen with depth, resulting in transient recharge. We find that transient recharge in response to the climate variability patterns could be detected at the depths of water levels in most U.S. aquifers. Our findings indicate that the damping behavior of transient infiltration fluxes is linear across soil layers for a range of texture combinations. The implications are that relatively simple, homogeneous models of the vadose zone may provide reasonable estimates of the damping depth of climate-varying transient recharge in some complex, layered vadose zone profiles.

Segmentation and supercycles: A catalog of earthquake cycle complexities from the Sumatran Sunda Megathrust and other well-studied faults worldwide

NASA Astrophysics Data System (ADS)

Philibosian, B.; Meltzner, A. J.; Sieh, K.

2017-12-01

Understanding earthquake cycle processes is key to both seismic hazard and fault mechanics. A concept that has come into focus recently is that rupture segmentation and cyclicity can be complex, and that simple models of periodically repeating similar earthquakes are inadequate. The term "supercycle" has been used to describe repeating longer periods of strain accumulation that involve multiple fault ruptures. However, this term has become broadly applied, lumping together several distinct phenomena that likely have disparate underlying causes. Earthquake recurrence patterns have often been described as "clustered," but this term is also imprecise. It is necessary to develop a terminology framework that consistently and meaningfully describes all types of behavior that are observed. We divide earthquake cycle patterns into four major classes, each having different implications for seismic hazard and fault mechanics: 1) quasi-periodic similar ruptures, 2) temporally clustered similar ruptures, 3) temporally clustered complementary ruptures, also known as rupture cascades, in which neighboring fault patches fail sequentially, and 4) superimposed cycles in which neighboring fault patches have cycles with different recurrence intervals, but may occasionally rupture together. Rupture segmentation is classified as persistent, frequent, or transient depending on how reliably ruptures terminate in a given area. We discuss the paleoseismic and historical evidence currently available for each of these types of behavior on subduction zone megathrust faults worldwide. Due to the unique level of paleoseismic and paleogeodetic detail provided by the coral microatoll technique, the Sumatran Sunda megathrust provides one of the most complete records over multiple seismic cycles. Most subduction zones with sufficient data exhibit examples of persistent and frequent segmentation, with cycle patterns 1, 3, and 4 on different segments. Pattern 2 is generally confined to overlap zones between segments. This catalog of seismic cycle observations provides a basis for exploring and modeling root causes of rupture segmentation and cycle behavior. Researchers should expect to discover similar behavior styles on other megathrust faults and perhaps major crustal faults around the world.

Neurotransmitters couple brain activity to subventricular zone neurogenesis

PubMed Central

Young, Stephanie Z.; Taylor, M. Morgan; Bordey, Angélique

2011-01-01

Adult neurogenesis occurs in two privileged microenvironments, the hippocampal subgranular zone of the dentate gyrus and the subventricular zone (SVZ) along the lateral ventricle. This review focuses on accumulating evidence suggesting that the activity of specific brain regions or bodily states influences SVZ cell proliferation and neurogenesis. Neuromodulators such as dopamine and serotonin have been shown to have long-range effects through neuronal projections into the SVZ. Local GABA and glutamate signaling have demonstrated effects on SVZ proliferation and neurogenesis, but an extra-niche source of these neurotransmitters remains to be explored and options will be discussed. There is also accumulating evidence that diseases and bodily states such as Alzheimer's disease, seizures, sleep, and pregnancy influence SVZ cell proliferation. With such complex behavior and environmentally-driven factors that control subregion-specific activity, it will become necessary to account for overlapping roles of multiple neurotransmitter systems on neurogenesis when developing cell therapies or drug treatments. PMID:21395856

Cytoarchitecture of the telencephalon in the coral reef multiband Butterflyfish ( Chaetodon multicinctus : Perciformes).

PubMed

Dewan, Adam K; Tricas, Timothy C

2014-01-01

Detailed neuroanatomical studies of model species are necessary to facilitate comparative experiments which test hypotheses relevant to brain evolution and function. Butterflyfishes (Chaetodontidae) boast numerous sympatric species that differ in social behavior, aggression and feeding ecology. However, the ability to test hypotheses relevant to brain function in this family is hindered by the lack of detailed neural descriptions. The cytoarchitecture of the telencephalon in the monogamous and territorial multiband butterflyfish, Chaetodon multicinctus, was determined with Nissl-stained serial sections and an immunohistochemical analysis of arginine vasotocin (AVT), serotonin, substance P and tyrosine hydroxylase. The ventral telencephalon was similar to that of other perciform fishes studied, with one major difference. A previously undescribed postcommissural region, the cuneate nucleus, was identified and putatively assigned to the ventral telencephalon. While the function of this nucleus is unknown, preliminary studies indicate that it may be part of a behaviorally relevant subpallial neural circuit that is modulated by AVT. The dorsal telencephalon consisted of 15 subdivisions among central, medial, lateral, dorsal and posterior zones. Several regions of the dorsal telencephalon of C. multicinctus differed from many other perciform fishes examined thus far. The nucleus taenia was in a more caudal position, and the central and lateral zones were enlarged. Within the lateral zone, an unusual third, ventral subdivision and a large-celled division were present. One hypothesis is that the enlarged ventral subdivision of the lateral zone (potential hippocampus homolog) relates to an enhancement of spatial learning or olfactory memory, which are important for this coral reef fish. This study provides the neuroanatomical basis for future comparative and evolutionary studies of brain organization and neuropeptide distributions, physiological studies of neural processing and insight into the complex social behavior of butterflyfishes. © 2014 S. Karger AG, Basel.

Influence of increasing convergence obliquity and shallow slab geometry onto tectonic deformation and seismogenic behavior along the Northern Lesser Antilles zone

NASA Astrophysics Data System (ADS)

Laurencin, M.; Graindorge, D.; Klingelhoefer, F.; Marcaillou, B.; Evain, M.

2018-06-01

In subduction zones, the 3D geometry of the plate interface is one of the key parameters that controls margin tectonic deformation, interplate coupling and seismogenic behavior. The North American plate subducts beneath the convex Northern Lesser Antilles margin. This convergent plate boundary, with a northward increasing convergence obliquity, turns into a sinistral strike-slip limit at the northwestern end of the system. This geodynamic context suggests a complex slab geometry, which has never been imaged before. Moreover, the seismic activity and particularly the number of events with thrust focal mechanism compatible with subduction earthquakes, increases northward from the Barbuda-Anguilla segment to the Anguilla-Virgin Islands segment. One of the major questions in this area is thus to analyze the influence of the increasing convergence obliquity and the slab geometry onto tectonic deformation and seismogenic behavior of the subduction zone. Based on wide-angle and multichannel reflection seismic data acquired during the Antithesis cruises (2013-2016), we decipher the deep structure of this subduction zone. Velocity models derived from wide-angle data acquired across the Anegada Passage are consistent with the presence of a crust of oceanic affinity thickened by hotspot magmatism and probably affected by the Upper Cretaceous-Eocene arc magmatism forming the 'Great Arc of the Caribbean'. The slab is shallower beneath the Anguilla-Virgin Islands margin segment than beneath the Anguilla-Barbuda segment which is likely to be directly related to the convex geometry of the upper plate. This shallower slab is located under the forearc where earthquakes and partitioning deformations increase locally. Thus, the shallowing slab might result in local greater interplate coupling and basal friction favoring seismic activity and tectonic partitioning beneath the Virgin Islands platform.

Visibility graphlet approach to chaotic time series

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mutua, Stephen; Computer Science Department, Masinde Muliro University of Science and Technology, P.O. Box 190-50100, Kakamega; Gu, Changgui, E-mail: gu-changgui@163.com, E-mail: hjyang@ustc.edu.cn

Many novel methods have been proposed for mapping time series into complex networks. Although some dynamical behaviors can be effectively captured by existing approaches, the preservation and tracking of the temporal behaviors of a chaotic system remains an open problem. In this work, we extended the visibility graphlet approach to investigate both discrete and continuous chaotic time series. We applied visibility graphlets to capture the reconstructed local states, so that each is treated as a node and tracked downstream to create a temporal chain link. Our empirical findings show that the approach accurately captures the dynamical properties of chaotic systems.more » Networks constructed from periodic dynamic phases all converge to regular networks and to unique network structures for each model in the chaotic zones. Furthermore, our results show that the characterization of chaotic and non-chaotic zones in the Lorenz system corresponds to the maximal Lyapunov exponent, thus providing a simple and straightforward way to analyze chaotic systems.« less

Coagulation of micro-polluted Pearl River water with IPF-PACls.

PubMed

Xu, Yi; Sun, Wei; Wang, Dong-sheng; Tang, Hong-xiao

2004-01-01

Water samples collected from early March 2001 to the end of April 2002 at the branch of Pearl River around the Guangzhou City were analyzed for its micro-polluted characteristics. The coagulation behavior of polyaluminum chlorides (PACls) was then examined focusing on the effect of primary water quality and speciation distribution. The results showed that PACls exhibit better coagulation efficiency than alum in accordance with the different speciation. The turbidity removal property of PACls is evidently better than alum at low dosage. While in neutral zone (about 6.5-7.5), the turbidity removal of PACls decreases owing to the restabilization of particles at higher dosage. The organic matters in raw water exhibit marked influence on coagulation. In acidic zone, organic matters complex with polymer species and promote the formation of flocs. With an increase in pH, the complexation of organics with polymer species gradually decreases, and the removal of organics mainly depends on adsorption. The effect is evidently improved with the raise of B value.

Multiple Sulfur Isotopes In The Molopo Farms Complex May Shed Light On Mechanisms Of Mineralization In The Bushveld Igneous Complex

NASA Astrophysics Data System (ADS)

Magalhaes, N.; Feineman, M. D.; Bybee, G. M.; Penniston-Dorland, S.; Farquhar, J.; Draper, C.; Escobar, E.; Gates, M.; Renusch, J.

2016-12-01

The 2.056 Ga Bushveld Igneous Complex (BIC) is host to the world's largest layered mafic-ultramafic intrusion, the Rustenburg Layered Suite (RLS), which has >80% of the world's known platinum group elements (PGEs) reserves. The BIC results from large-volume melt extraction from the mantle and may provide insight into the formation and compositional evolution of continental crust. Despite its scientific and economic importance, the total magma volume is poorly known. This is in part because the relationship between the BIC and nearby intrusive bodies of similar age remains uncertain. In this study, we present major element, trace element, and multiple sulfur isotope data for a suite of samples spanning the stratigraphy of the Molopo Farms Complex (MFC), a layered mafic intrusion located 200 km west of the Far Western Limb of the RLS. Similar to the RLS, the MFC contains an ultramafic lower zone, a mafic main zone, and an incompatible element enriched granophyric unit near the contact with the roof rocks. However, it has no Critical Zone, and an insignificant concentration of PGEs. Since the PGEs in the RLS are primarily hosted in sulfides, it has been inferred that the mineralization is closely linked to the source and behavior of sulfur. The RLS displays mass independent fractionation of sulfur (S-MIF; denoted by Δ33S), which suggests incorporation of surface-derived materials into the magma prior to or during emplacement. Multiple sulfur isotopes of MFC samples also show non-zero mean Δ33S (0.04±0.02‰, 1sd), although it is lower than the mean for the RLS (0.11±0.02‰, 1sd). Similarities in trace element ratios between the MFC mafic zone and RLS marginal zone suggest the same parental magma contributed to both intrusions. Taken together, these results suggest that both the RLS and the MFC started with similar magmatic compositions, and while both assimilated sulfur with an Archean surface-derived component, the RLS received more of this component in proportion to its volume. The lack of PGE mineralization in the MFC may reflect the lesser addition of Archean sedimentary sulfur.

The effect of water on recrystallization behavior and grain boundary morphology in calcite observations of natural marble mylonites

NASA Astrophysics Data System (ADS)

Schenk, Oliver; Urai, Janos L.; Evans, Brian

2005-10-01

Fluids are inferred to play a major role in the deformation and recrystallization of many minerals (e.g. quartz, olivine, halite, feldspar). In this study, we sought to identify the effect of fluids on grain boundary morphology and recrystallization processes in marble mylonites during shear zone evolution. We compared the chemistry, microstructure and mesostructure of calcite marble mylonites from the Schneeberg Complex, Southern Tyrole, Italy, to that from the Naxos Metamorphic Core Complex, Greece. These two areas were selected for comparison because they have similar lithology and resemble each other in chemical composition. In addition, calcite-dolomite geothermometry indicates similar temperatures for shear zone formation: 279±25 °C (Schneeberg Complex) and 271±15 °C (Naxos high-grade core). However, the two settings are different in the nature of the fluids present during the shear zone evolution. In the Schneeberg mylonites, both the alteration of minerals during retrograde metamorphism in the neighboring micaschists and the existence of veins suggest that aqueous fluids were present during mylonitization. The absence of these features in the Naxos samples indicates that aqueous fluids were not as prevalent during deformation. This conclusion is also supported by the stable isotope signature. Observations of broken and planar surfaces using optical and scanning electron microscopes did not indicate major differences between the two mylonites: grain boundaries in both settings display pores with shapes controlled by crystallography, and have pore morphologies that are similar to observations from crack and grain-boundary healing experiments. Grain size reduction was predominantly the result of subgrain rotation recrystallization. However, the coarse grains inside the wet protomylonites (Schneeberg) are characterized by intracrystalline shear zones.

Using Wavelets to Evaluate Persistence of High Frequency Hydrologic and Hydrochemistry Signals

NASA Astrophysics Data System (ADS)

Koirala, S. R.; Gentry, R. W.

2009-12-01

In the area of sustainability science, it is becoming increasingly important to understand the basal condition of a natural system, and its long-term behavior. Research is needed to better understand the temporal scaling of hydrochemistry in streams and watersheds and its relationship to the hydrologic factors that influence its behavior. Persistence of dissolved chemicals in streams has been demonstrated to be linked to certain hydrologic processes, such as interactions between hydrologic units and storage in surface or sub-surface systems. In this study, wavelet analyses provided a novel theoretical basis for insights into long-term hydrochemistry behavior in an east Tennessee watershed. Temporal analyses were conducted on weekly time series data of hydrochemistry (nitrate, chloride, sulfate and calcium concentrations) collected from November 1995 to December 2005 at the West Fork of Walker Branch in Oak Ridge, Tennessee. Hydrochemistry plays an important role in ecosystem services, particularly nitrate, and in general the signal responses can be complex. The signals in this study were modeled using a wavelet approach as a mechanism for evaluating short-and long term temporal effects. The Walker Branch conceptual hydrology model is augmented by these results that show characteristic periodicities or structures for flowpath lengths in the vadose zone (< 20 week period), saturated zone (20 to 50 week period) and bedrock zone (> 50 week period) with implications for hydrochemistry within the watershed. In general, time series signals of watershed hydrochemistry may provide clues as to broad environmental, ecological and economic impacts at the basin scale.

Structural controls on the megathrust segmentation of the Middle America Trench from multiple geophysical observations

NASA Astrophysics Data System (ADS)

Naif, S.; Bassett, D.

2016-12-01

Subduction zone megathrusts display complex seismogenic behaviors that vary at intra- and inter-margin scales. Many different physical properties have been proposed to be primarily responsible for this behavior, such as the composition of subducted sediments, the hydration state of the incoming oceanic plate, and the pore-fluid pressure at the plate interface. Here, we focus on the northern Middle America Trench and show that subducting plate structures control megathrust segmentation. We analyze multiple types of seafloor geophysical observations and compare them to the distinct behavioral and spatial characteristics of the 1992 Nicaragua (Mw7.6), 2012 El Salvador (Mw7.3), 2012 Guatemala (Mw7.4), and 2012 Costa Rica (Mw7.6) events. The residual topography, residual gravity, and magnetic anomaly structure of the incoming oceanic plate and forearc seafloor are correlated. The forearc is composed of multiple unique segments that are bounded by subducting fracture zones. These boundaries correlate with foreshock and aftershock seismicity and also coincide with the hypocenter of all four earthquakes. The relationship between observed structures, earthquake slip inversions, and radiated energy of the four large events will be discussed.

Modeling of coulpled deformation and permeability evolution during fault reactivation induced by deep underground injection of CO2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cappa, F.; Rutqvist, J.

2010-06-01

The interaction between mechanical deformation and fluid flow in fault zones gives rise to a host of coupled hydromechanical processes fundamental to fault instability, induced seismicity, and associated fluid migration. In this paper, we discuss these coupled processes in general and describe three modeling approaches that have been considered to analyze fluid flow and stress coupling in fault-instability processes. First, fault hydromechanical models were tested to investigate fault behavior using different mechanical modeling approaches, including slip interface and finite-thickness elements with isotropic or anisotropic elasto-plastic constitutive models. The results of this investigation showed that fault hydromechanical behavior can be appropriatelymore » represented with the least complex alternative, using a finite-thickness element and isotropic plasticity. We utilized this pragmatic approach coupled with a strain-permeability model to study hydromechanical effects on fault instability during deep underground injection of CO{sub 2}. We demonstrated how such a modeling approach can be applied to determine the likelihood of fault reactivation and to estimate the associated loss of CO{sub 2} from the injection zone. It is shown that shear-enhanced permeability initiated where the fault intersects the injection zone plays an important role in propagating fault instability and permeability enhancement through the overlying caprock.« less

The earthquake potential of the New Madrid seismic zone

USGS Publications Warehouse

Tuttle, Martitia P.; Schweig, Eugene S.; Sims, John D.; Lafferty, Robert H.; Wolf, Lorraine W.; Haynes, Marion L.

2002-01-01

The fault system responsible for New Madrid seismicity has generated temporally clustered very large earthquakes in A.D. 900 ± 100 years and A.D. 1450 ± 150 years as well as in 1811–1812. Given the uncertainties in dating liquefaction features, the time between the past three New Madrid events may be as short as 200 years and as long as 800 years, with an average of 500 years. This advance in understanding the Late Holocene history of the New Madrid seismic zone and thus, the contemporary tectonic behavior of the associated fault system was made through studies of hundreds of earthquake-induced liquefaction features at more than 250 sites across the New Madrid region. We have found evidence that prehistoric sand blows, like those that formed during the 1811–1812 earthquakes, are probably compound structures resulting from multiple earthquakes closely clustered in time or earthquake sequences. From the spatial distribution and size of sand blows and their sedimentary units, we infer the source zones and estimate the magnitudes of earthquakes within each sequence and thereby characterize the detailed behavior of the fault system. It appears that fault rupture was complex and that the central branch of the seismic zone produced very large earthquakes during the A.D. 900 and A.D. 1450 events as well as in 1811–1812. On the basis of a minimum recurrence rate of 200 years, we are now entering the period during which the next 1811–1812-type event could occur.

Hydromechanical heterogeneities of a mature fault zone: impacts on fluid flow.

PubMed

Jeanne, Pierre; Guglielmi, Yves; Cappa, Frédéric

2013-01-01

In this paper, fluid flow is examined for a mature strike-slip fault zone with anisotropic permeability and internal heterogeneity. The hydraulic properties of the fault zone were first characterized in situ by microgeophysical (VP and σc ) and rock-quality measurements (Q-value) performed along a 50-m long profile perpendicular to the fault zone. Then, the local hydrogeological context of the fault was modified to conduct a water-injection test. The resulting fluid pressures and flow rates through the different fault-zone compartments were then analyzed with a two-phase fluid-flow numerical simulation. Fault hydraulic properties estimated from the injection test signals were compared to the properties estimated from the multiscale geological approach. We found that (1) the microgeophysical measurements that we made yield valuable information on the porosity and the specific storage coefficient within the fault zone and (2) the Q-value method highlights significant contrasts in permeability. Fault hydrodynamic behavior can be modeled by a permeability tensor rotation across the fault zone and by a storativity increase. The permeability tensor rotation is linked to the modification of the preexisting fracture properties and to the development of new fractures during the faulting process, whereas the storativity increase results from the development of micro- and macrofractures that lower the fault-zone stiffness and allows an increased extension of the pore space within the fault damage zone. Finally, heterogeneities internal to the fault zones create complex patterns of fluid flow that reflect the connections of paths with contrasting properties. © 2013, The Author(s). Ground Water © 2013, National Ground Water Association.

Enrichment of trace elements in garnet amphibolites from a paleo-subduction zone: Catalina Schist, southern California

USGS Publications Warehouse

Sorensen, Sorena S.; Grossman, J.N.

1989-01-01

The abundance, P-T stability, solubility, and element-partitioning behavior of minerals such as rutile, garnet, sphene, apatite, zircon, zoisite, and allanite are critical variables in models for mass transfer from the slab to the mantle wedge in deep regions of subduction zones. The influence of these minerals on the composition of subduction-related magmas has been inferred (and disputed) from inverse modelling of the geochemistry of island-arc basalt, or by experiment. Although direct samples of the dehydration + partial-melting region of a mature subduction zone have not been reported from subduction complexes, garnet amphibolites from melanges of circumpacific and Caribbean blueschist terranes reflect high T (>600??C) conditions in shallower regions. Such rocks record geochemical processes that affected deep-seated, high-T portions of paleo-subduction zones. In the Catalina Schist, a subduction-zone metamorphic terrane of southern California, metasomatized and migmatitic garnet amphibolites occur as blocks in a matrix of meta-ultramafic rocks. This mafic and ultramafic complex may represent either slab-derived material accreted to the mantle wedge of a nascent subduction zone or a portion of a shear zone closely related to the slab-mantle wedge contact, or both. The trace-element geochemistry of the complex and the distribution of trace elements among the minerals of garnet amphibolites were studied by INAA, XRF, electron microprobe, and SEM. In order of increasing alteration from a probable metabasalt protolith, three common types of garnet amphibolite blocks in the Catalina Schist are: (1) non-migmatitic, clinopyroxene-bearing blocks, which are compositionally similar to MORB that has lost an albite component; (2) garnet-amphibolite blocks, which have rinds that reflect local interaction between metabasite, metaperidotite, and fluid; and (3) migmatites that are extremely enriched in Th, HFSE, LREE, and other trace elements. These trace-element enrichments are mineralogically controlled by rutile, garnet, sphene, apatite, zircon, zoisite, and allanite. Alkali and alkaline earth elements are much less enriched in the solid assemblage, and thus appear to be decoupled from the other elements in the inferred metasomatic process(es). The compositions of migmatitic garnet amphibolite blocks seem to complement that of "average" island-arc tholeiite. Trace-element metasomatism reflects fluid-solid, rather than melt-solid, interaction. The metasomatic effects indicate that H2O-rich fluid, perhaps with a significant component of Na-Al silicate and alkalis, carried Th, U, Sr, REE, and HFSE. Fractionations of LREE in migmatites resemble those of migmatitic metasedimentary rocks underlying the mafic and ultramafic complex. "Exotic" LREE deposited in allanite in migmatites could have been derived from fluids in equilibrium with subducted sediment. If the paleo-subduction zone represented by the mafic and ultramafic complex of the Catalina Schist had continued its thermal and fluid evolution, a selvage of similarly enriched rocks might have been generated along the slab-mantle wedge contact between ~30 and 85 km depth. Rocks affected by "subduction-zone metasomatism," although rarely recognized at the surface, could be volumetrically significant products of the initiation of subduction and may prove to be geochemical probes of convergent margins that approach the significance of xenoliths in the study of other magmatic environments. ?? 1989.

Strike-slip linked core complexes: A new kinematic model of basement rock exhumation in a crustal-scale fault system

NASA Astrophysics Data System (ADS)

Meyer, Sven Erik; Passchier, Cees; Abu-Alam, Tamer; Stüwe, Kurt

2014-05-01

Metamorphic core complexes usually develop as extensional features during continental crustal thinning, such as the Basin and Range and the Aegean Terrane. The Najd fault system in Saudi Arabia is a 2000 km-long and 400 km-wide complex network of crustal-scale strike-slip shear zones in a Neoproterozoic collision zone. Locally, the anastomosing shear zones lead to exhumation of lower crustal segments and represent a new kinematic model for the development of core complexes. We report on two such structures: the Qazaz complex in Saudi Arabia and the Hafafit complex in Egypt. The 15 km-wide Qazaz complex is a triangular dome of gently dipping mylonitic foliations within the 140 km-long sinistral strike-slip Qazaz mylonite zone. The gneissic dome consists of high-grade rocks, surrounded by low-grade metasediments and metavolcanics. The main SE-trending strike-slip Qazaz shear zone splits southwards into two branches around the gneiss dome: the western branch is continuous with the shallow dipping mylonites of the dome core, without overprinting, and changes by more than 90 degrees from a NS-trending strike-slip zone to an EW-trending 40 degree south-dipping detachment that bounds the gneiss dome to the south. The eastern SE-trending sinistral strike-slip shear zone branch is slightly younger and transects the central dome fabrics. The gneiss dome appears to have formed along a jog in the strike-slip shear zone during 40 km of horizontal strike-slip motion, which caused local exhumation of lower crustal rocks by 25 km along the detachment. The eastern shear zone branch formed later during exhumation, transacted the gneiss dome and offset the two parts by another 70 km. The Hafafit core complex in Egypt is of similar shape and size to the Qazaz structure, but forms the northern termination of a sinistral strike-slip zone that is at least 100 km in length. This zone may continue into Saudi Arabia as the Ajjaj shear zone for another 100 km. The NW trending strike slip mylonite zone grades into a gently N-dipping detachment to the west which accommodated strike slip by exhumation of high-grade lower crustal rocks. The Qazaz and the Hafafit Domes are similar, mirror-image structures with small differences in the accommodating shear zones. It is likely that these types of strike-slip related oblique core complexes are common in the Arabian Nubian shield, and possibly elsewhere.

Modeling lahar behavior and hazards

USGS Publications Warehouse

Manville, Vernon; Major, Jon J.; Fagents, Sarah A.

2013-01-01

Lahars are highly mobile mixtures of water and sediment of volcanic origin that are capable of traveling tens to > 100 km at speeds exceeding tens of km hr-1. Such flows are among the most serious ground-based hazards at many volcanoes because of their sudden onset, rapid advance rates, long runout distances, high energy, ability to transport large volumes of material, and tendency to flow along existing river channels where populations and infrastructure are commonly concentrated. They can grow in volume and peak discharge through erosion and incorporation of external sediment and/or water, inundate broad areas, and leave deposits many meters thick. Furthermore, lahars can recur for many years to decades after an initial volcanic eruption, as fresh pyroclastic material is eroded and redeposited during rainfall events, resulting in a spatially and temporally evolving hazard. Improving understanding of the behavior of these complex, gravitationally driven, multi-phase flows is key to mitigating the threat to communities at lahar-prone volcanoes. However, their complexity and evolving nature pose significant challenges to developing the models of flow behavior required for delineating their hazards and hazard zones.

Simulation of Mechanical Behavior and Damage of a Large Composite Wind Turbine Blade under Critical Loads

NASA Astrophysics Data System (ADS)

Tarfaoui, M.; Nachtane, M.; Khadimallah, H.; Saifaoui, D.

2018-04-01

Issues such as energy generation/transmission and greenhouse gas emissions are the two energy problems we face today. In this context, renewable energy sources are a necessary part of the solution essentially winds power, which is one of the most profitable sources of competition with new fossil energy facilities. This paper present the simulation of mechanical behavior and damage of a 48 m composite wind turbine blade under critical wind loads. The finite element analysis was performed by using ABAQUS code to predict the most critical damage behavior and to apprehend and obtain knowledge of the complex structural behavior of wind turbine blades. The approach developed based on the nonlinear FE analysis using mean values for the material properties and the failure criteria of Tsai-Hill to predict failure modes in large structures and to identify the sensitive zones.

The Effects of Positive Behavior Interventions and Support on Changing the Behavior of Red Zone Students

ERIC Educational Resources Information Center

Robinson, Fredrick

2012-01-01

In order to improve culture, safety, and climate, numerous schools nationwide are implementing Positive Behavior Interventions and Support (PBIS). The purpose of this study was to examine the effectiveness of the Positive Behavior Interventions and Support (PBIS) model for reducing high-risk behaviors of students identified as red zone. The…

An assessment of schoolyard features and behavior patterns in children's utilization and physical activity.

PubMed

Anthamatten, Peter; Brink, Lois; Kingston, Beverly; Kutchman, Eve; Lampe, Sarah; Nigg, Claudio

2014-03-01

Careful research that elucidates how behavior relates to design in the context of elementary school grounds can serve to guide cost-efficient design with the goal of encouraging physical activity (PA). This work explores patterns in children's PA behavior within playground spaces with the specific goal of guiding healthy playground design. Data on children's utilization and PA behavior in 6 playgrounds divided into 106 observation zones were collected in 2005 and 2006 at Denver elementary school playgrounds using the System for Observing Play and Leisure Activity in Youth. Analyses of variance and t tests determined whether there were differences in utilization and behavior patterns across observations zones and between genders. This study provides evidence that children prefer to use certain types of playground zones and that they are more likely to practice moderate-to-vigorous physical activity (MVPA) in some zones. The authors observed statistically significant differences between genders. Boys were more likely to engage in MVPA in zones without equipment, girls were more likely to use zones with equipment. This work suggests that the inclusion or omission of specific playground features may have an impact on the way that children use the spaces.

The Campanian-Maastrichtian foraminiferal biostratigraphy of the basement sediments from the southern Pannonian Basin (Vojvodina, northern Serbia): implications for the continuation of the Eastern Vardar and Sava zones

NASA Astrophysics Data System (ADS)

Dunčić, Milena; Dulić, Ivan; Popov, Olivera; Bogićević, Goran; Vranjković, Alan

2017-04-01

Micropalaeontological and biostratigraphical studies included Campanian-Maastrichtian complexes from five oil exploration wells drilled in northern Serbia (Vojvodina): the first is a carbonate-clastic complex and second is a complex containing ophiolites intercalated with hemipelagic and pelagic sediments. Within the studied complexes, rich associations of planktonic and benthic foraminifera, calcareous nannoplankton, palynomorphs, as well as shallow and deep-water fossil detritus were determined. The presence of relatively rich associations of planktonic foraminifera allowed recognition of two biozones: the Globotruncana ventricosa Zone, observed in the sediments of the carbonate-clastic complex and the Gansserina gansseri Zone, observed in both complexes. Except biozones, based on documented index species, for some units in both complexes, larger benthic foraminifera species had special biostratigraphical value, and in some of them, the calcareous nannoplankton zones were recognized. The studied complexes represent deep-water formations, generated in oceanic island arc and trough zones. The presence of limestones, which originate from destroyed rudist reefs, is explained by transfer by means of gravitational transport mechanisms of shallow-water sediments to deep-water depositional environments. In this paper, the results of more detailed biostratigraphical and palaeo-ecological studies of foraminifera associations in Campanian-Maastrichtian complexes in Vojvodina are presented. Combined with lithological studies, seven units were determined within the complexes. The obtained results are important as a part of multidisciplinary, regional exploration of both complexes, generated in specific geological conditions, that today constitute a part of the pre-Neogene basement complex in the southeastern part of the Pannonian Basin. The Campanian- Maastrichtian carbonate-clastic complex represents sedimentary cover of the Eastern Vardar Ophiolitic Unit, while the ophiolites intercalated with hemipelagic and pelagic limestones belongs to the Sava Zone.

Identifying Typhoon Tracks based on Event Synchronization derived Spatially Embedded Climate Networks

NASA Astrophysics Data System (ADS)

Ozturk, Ugur; Marwan, Norbert; Kurths, Jürgen

2017-04-01

Complex networks are commonly used for investigating spatiotemporal dynamics of complex systems, e.g. extreme rainfall. Especially directed networks are very effective tools in identifying climatic patterns on spatially embedded networks. They can capture the network flux, so as the principal dynamics of spreading significant phenomena. Network measures, such as network divergence, bare the source-receptor relation of the directed networks. However, it is still a challenge how to catch fast evolving atmospheric events, i.e. typhoons. In this study, we propose a new technique, namely Radial Ranks, to detect the general pattern of typhoons forward direction based on the strength parameter of the event synchronization over Japan. We suggest to subset a circular zone of high correlation around the selected grid based on the strength parameter. Radial sums of the strength parameter along vectors within this zone, radial ranks are measured for potential directions, which allows us to trace the network flux over long distances. We employed also the delay parameter of event synchronization to identify and separate the frontal storms' and typhoons' individual behaviors.

Mathematical Analysis of the Solidification Behavior of Plain Steel Based on Solute- and Heat-Transfer Equations in the Liquid-Solid Zone

NASA Astrophysics Data System (ADS)

Fujimura, Toshio; Takeshita, Kunimasa; Suzuki, Ryosuke O.

2018-04-01

An analytical approximate solution to non-linear solute- and heat-transfer equations in the unsteady-state mushy zone of Fe-C plain steel has been obtained, assuming a linear relationship between the solid fraction and the temperature of the mushy zone. The heat transfer equations for both the solid and liquid zone along with the boundary conditions have been linked with the equations to solve the whole equations. The model predictions ( e.g., the solidification constants and the effective partition ratio) agree with the generally accepted values and with a separately performed numerical analysis. The solidus temperature predicted by the model is in the intermediate range of the reported formulas. The model and Neuman's solution are consistent in the low carbon range. A conventional numerical heat analysis ( i.e., an equivalent specific heat method using the solidus temperature predicted by the model) is consistent with the model predictions for Fe-C plain steels. The model presented herein simplifies the computations to solve the solute- and heat-transfer simultaneous equations while searching for a solidus temperature as a part of the solution. Thus, this model can reduce the complexity of analyses considering the heat- and solute-transfer phenomena in the mushy zone.

Biogeochemical zonation of sulfur during the discharge of groundwater to lake in desert plateau (Dakebo Lake, NW China).

PubMed

Su, Xiaosi; Cui, Geng; Wang, Huang; Dai, Zhenxue; Woo, Nam-Chil; Yuan, Wenzhen

2018-06-01

As one of the important elements of controlling the redox system within the hyporheic and hypolentic zone, sulfur is involved in a series of complex biogeochemical processes such as carbon cycle, water acidification, formation of iron and manganese minerals, redox processes of trace metal elements and a series of important ecological processes. Previous studies on biogeochemistry of the hyporheic and hypolentic zones mostly concentrated on nutrients of nitrogen and phosphorus, heavy metals and other pollutants. Systematic study of biogeochemical behavior of sulfur and its main controlling factors within the lake hypolentic zone is very urgent and important. In this paper, a typical desert plateau lake, Dakebo Lake in northwestern China, was taken for example within which redox zonation and biogeochemical characteristics of sulfur affected by hydrodynamic conditions were studied based on not only traditional hydrochemical analysis, but also environmental isotope evidence. In the lake hypolentic zone of the study area, due to the different hydrodynamic conditions, vertical profile of sulfur species and environmental parameters differ at the two sites of the lake (western side and center). Reduction of sulfate, deposition and oxidation of sulfide, dissolution and precipitation of sulfur-bearing minerals occurred are responded well to Eh, dissolved oxygen, pH, organic carbon and microorganism according to which the lake hypolentic zone can be divided into reduced zone containing H 2 S, reduced zone containing no H 2 S, transition zone and oxidized zone. The results of this study provide valuable insights for understanding sulfur conversion processes and sulfur biogeochemical zonation within a lake hypolentic zone in an extreme plateau arid environment and for protecting the lake-wetland ecosystem in arid and semiarid regions.

Investigation of surface water behavior during glaze ice accretion

NASA Technical Reports Server (NTRS)

Hansman, R. John, Jr.; Turnock, Stephen R.

1990-01-01

A series of experimental investigations that focused on isolating the primary factors that control the behavior of unfrozen surface water during glaze ice accretion were conducted. Detailed microvideo observations were made of glaze ice accretions on 2.54 cm diam cylinders in a closed-loop refrigerated wind tunnel. Distinct zones of surface water behavior were observed; a smooth wet zone in the stagnation region with a uniform water film, a rough zone where surface tension effects caused coalescence of surface water into stationary beads, and a zone where surface water ran back as rivulets. The location of the transition from the smooth to the rough zone was found to migrate towards the stagnation point with time. Comparative tests were conducted to study the effect of the substrate thermal and roughness properties on ice accretion. The importance of surface water behavior was evaluated by the addition of a surface tension reducing agent to the icing tunnel water supply, which significantly altered the accreted glaze ice shape. Measurements were made to determine the contact angle behavior of water droplets on ice. A simple multizone modification to current glaze ice accretion models was proposed to include the observed surface roughness behavior.

Bed Erosion Process in Geophysical Viscoplastic Fluid

NASA Astrophysics Data System (ADS)

Luu, L. H.; Philippe, P.; Chambon, G.; Vigneaux, P.; Marly, A.

2017-12-01

The bulk behavior of materials involved in geophysical fluid dynamics such as snow avalanches or debris flows has often been modeled as viscoplastic fluid that starts to flow once its stress state overcomes a critical yield value. This experimental and numerical study proposes to interpret the process of erosion in terms of solid-fluid transition for these complex materials. The experimental setup consists in a closed rectangular channel with a cavity in its base. By means of high-resolution optical velocimetry (PIV), we properly examine the typical velocity profiles of a model elasto-viscoplastic flow (Carbopol) at the vicinity of the solid-fluid interface, separating a yielded flowing layer above from an unyielded dead zone below. In parallel, numerical simulations in this expansion-contraction geometry with Augmented Lagrangian and Finite-Differences methods intend to discuss the possibility to describe the specific flow related to the existence of a dead zone, with a simple Bingham rheology. First results of this comparative analysis show a good numerical ability to capture the main scalings and flow features, such as the non-monotonous evolution of the shear stress in the boundary layer between the central plug zone and the dead zone at the bottom of the cavity.

Transient Interaction Between Reduction and Slagging Reactions of Wustite in Simulated Cohesive Zone of Blast Furnace

NASA Astrophysics Data System (ADS)

Ma, Kaihui; Xu, Jian; Deng, Junyi; Wang, Dongdong; Xu, Yang; Liao, Zhehan; Sun, Chengfeng; Zhang, Shengfu; Wen, Liangying

2018-06-01

The blast furnace cohesive zone plays an important role in the gas flow distribution and heat-transfer efficiency. Previous work mainly employed temperature-based indices to evaluate and predict the shape and thickness of the cohesive zone, whereas the internal reactions and related effects on the softening and melting properties of a complex burden are ignored. In this study, an innovative index, namely, shrinkage rate (SR), is first proposed to directly estimate the shrinkage behavior of wustite (FeO)-packed bed inside a simulated cohesive zone. The index is applied as the temperature increases to elucidate the transient interaction between reduction and slagging reactions. Results show that the thermally induced slagging reaction causes the packed bed to shrink at lower temperature, and the SR doubles when compounds with low melting temperature are generated by adding a reasonable concentration of CaO or SiO2. The reduction reaction becomes the driving force during the shrinkage of the packed bed between 1173 K and 1273 K when CO is introduced in the mixture gas. Then, the dominating factors for further shrinkage include slagging, reduction, or both factors. These factors vary with respect to the added compounds or temperature.

Participatory Ethnographic Evaluation and Research: Reflections on the Research Approach Used to Understand the Complexity of Maternal Health Issues in South Sudan

PubMed Central

Elmusharaf, Khalifa; Byrne, Elaine; Manandhar, Mary; Hemmings, Joanne; O’Donovan, Diarmuid

2016-01-01

Many methodological approaches have been used to understand cultural dimensions to maternal health issues. Although a well-designed quantitative survey with a representative sample can provide essential information on trends in behavior, it does not necessarily establish a contextualized understanding of the complexity in which different behaviors occur. This article addresses how contextualized data can be collected in a short time and under conditions in which participants in conflict-affected zones might not have established, or time to establish, trust with the researchers. The solution, the Participatory Ethnographic Evaluation and Research (PEER) approach, is illustrated through a study whereby South Sudanese marginalized women were trained to design research instruments, and collect and analyze qualitative data. PEER overcomes the problem that many ethnographic or participatory approaches face—the extensive time and resources required to develop trusting relationships with the community to understand the local context and the social networks they form. PMID:27811290

Participatory Ethnographic Evaluation and Research: Reflections on the Research Approach Used to Understand the Complexity of Maternal Health Issues in South Sudan.

PubMed

Elmusharaf, Khalifa; Byrne, Elaine; Manandhar, Mary; Hemmings, Joanne; O'Donovan, Diarmuid

2017-07-01

Many methodological approaches have been used to understand cultural dimensions to maternal health issues. Although a well-designed quantitative survey with a representative sample can provide essential information on trends in behavior, it does not necessarily establish a contextualized understanding of the complexity in which different behaviors occur. This article addresses how contextualized data can be collected in a short time and under conditions in which participants in conflict-affected zones might not have established, or time to establish, trust with the researchers. The solution, the Participatory Ethnographic Evaluation and Research (PEER) approach, is illustrated through a study whereby South Sudanese marginalized women were trained to design research instruments, and collect and analyze qualitative data. PEER overcomes the problem that many ethnographic or participatory approaches face-the extensive time and resources required to develop trusting relationships with the community to understand the local context and the social networks they form.

Computational Modeling of Liquid and Gaseous Control Valves

NASA Technical Reports Server (NTRS)

Daines, Russell; Ahuja, Vineet; Hosangadi, Ashvin; Shipman, Jeremy; Moore, Arden; Sulyma, Peter

2005-01-01

In this paper computational modeling efforts undertaken at NASA Stennis Space Center in support of rocket engine component testing are discussed. Such analyses include structurally complex cryogenic liquid valves and gas valves operating at high pressures and flow rates. Basic modeling and initial successes are documented, and other issues that make valve modeling at SSC somewhat unique are also addressed. These include transient behavior, valve stall, and the determination of flow patterns in LOX valves. Hexahedral structured grids are used for valves that can be simplifies through the use of axisymmetric approximation. Hybrid unstructured methodology is used for structurally complex valves that have disparate length scales and complex flow paths that include strong swirl, local recirculation zones/secondary flow effects. Hexahedral (structured), unstructured, and hybrid meshes are compared for accuracy and computational efficiency. Accuracy is determined using verification and validation techniques.

Frictional behavior of carbonate-rich incoming sediment in the Hikurangi subduction zone

NASA Astrophysics Data System (ADS)

Rabinowitz, H. S.; Savage, H. M.; Carpenter, B.; Ikari, M.; Collettini, C.

2017-12-01

In recent years, the traditional view of the seismogenic zone has been challenged by observations of a range of seismic behaviors both above and below the depths previously considered capable of nucleating earthquakes. The Hikurangi trench is one of the few subduction zones where this transitional seismic behavior has been observed at the shallowest portions of the subduction zone, providing an opportunity to investigate the mechanical controls on seismic behavior through measurements of directly sampled sediment. To this end, an IODP cruise (March-May, 2018; Exp. 375) will recover sample from the faults that participate in this shallow seismic behavior. In order to obtain preliminary frictional characterization of the sedimentary inputs to the Hikurangi Trench, we conducted deformation experiments on samples from an ocean drill core through the incoming sediments (ODP Site 1124). The sedimentary package subducting at Hikurangi contains carbonate-rich lithologies, which have been shown to be more frictionally unstable (velocity-weakening, high healing rates) than the clays that comprise the majority of the sedimentary inputs to global subduction zones. Such frictional properties could promote seismic behavior in the shallower reaches of the subduction zone. We focus on a section of ODP Site 1124 which has a carbonate content of 40 wt% to investigate the effect of this lithology. Samples were saturated with distilled water mixed with 35 g/l sea salt. Velocity-stepping and slide-hold-slide tests were performed in multiple biaxial and triaxial deformation apparatus to investigate a range of pressures, temperatures and velocities relevant to the shallow subduction zone (σeff = 1-150 MPa, sliding velocities of 1.7 nm/s-300 μm/s, hold times of 1-1000 s, and T = 20-100 ºC). We observe transitions from velocity-strengthening to velocity-weakening behavior over these conditions which could contribute to shallow seismic behavior in the Hikurangi trench.

Scaling properties of rainfall records in some Mexican zones

NASA Astrophysics Data System (ADS)

Angulo-Fernández, Fercia; Reyes-Ramírez, Israel; Flores-Márquez, Elsa Leticia

2018-04-01

Since the 1990 decade, it has been suggested that atmospheric processes associated with rainfall could be a self-organized critical (SOC) phenomenon similar, for example, to seismicity. In this sense, the rain events taken as the output of the complex atmospheric system (sun's radiation, water evaporation, clouds, etc.) are analogous to earthquakes, as the output of a relaxation process of the earth crust. A clue on this possible SOC behavior of rain phenomenon has been the ubiquitous presence of power laws in rain statistics. In the present article, we report the scaling properties of rain precipitation data taken from meteorological stations located at six zones of Mexico. Our results are consistent with those that assert that rainfall is a SOC phenomenon. We also analyze the Hurst exponent, which is appropriate to measure long-term memory of time series.

Teleseismic P and S wave attenuation constraints on temperature and melt of the upper mantle in the Alaska Subduction Zone.

NASA Astrophysics Data System (ADS)

Soto Castaneda, R. A.; Abers, G. A.; Eilon, Z.; Christensen, D. H.

2017-12-01

Recent broadband deployments in Alaska provide an excellent opportunity to advance our understanding of the Alaska-Aleutians subduction system, with implications for subduction processes worldwide. Seismic attenuation, measured from teleseismic body waves, provides a strong constraint on thermal structure as well as an indirect indication of ground shaking expected from large intermediate-depth earthquakes. We measure P and S wave attenuation from pairwise amplitude and phase spectral ratios for teleseisms recorded at 204 Transportable Array, Alaska Regional, and Alaska Volcano Observatory, SALMON (Southern Alaska Lithosphere & Mantle Observation Network) and WVLF (Wrangell Volcanics & subducting Lithosphere Fate) stations in central Alaska. The spectral ratios are inverted in a least squares sense for differential t* (path-averaged attenuation operator) and travel time anomalies at every station. Our preliminary results indicate a zone of low attenuation across the forearc and strong attenuation beneath arc and backarc in the Cook Inlet-Kenai region where the Aleutian-Yakutat slab subducts, similar to other subduction zones. This attenuation differential is observed in both the volcanic Cook Inlet segment and amagmatic Denali segments of the Aleutian subduction zone. By comparison, preliminary results for the Wrangell-St. Elias region past the eastern edge of the Aleutian slab show strong attenuation beneath the Wrangell Volcanic Field, as well as much further south than in the Cook Inlet-Kenai region. This pattern of attenuation seems to indicate a short slab fragment in the east of the subduction zone, though the picture is complex. Results also suggest the slab may focus or transmit energy with minimal attenuation, adding to the complexity. To image the critical transition between the Alaska-Aleutian slab and the region to its east, we plan to incorporate new broadband data from the WVLF array, an ongoing deployment of 37 PASSCAL instruments installed in 2016. These stations have 10-20 km spacing, spanning the edge of the subducting slab, and so will provide a zone of increased resolution in the region where slab behavior is poorly understood. We will discuss these data in the context of enigmatic Wrangell volcanism and its relationship to the eastern end of the Alaska-Aleutian Wadati-Benioff zone.

Cannabinoid type 1 receptor ligands WIN 55,212-2 and AM 251 alter anxiety-like behaviors of marmoset monkeys in an open-field test.

PubMed

Cagni, Priscila; Barros, Marilia

2013-03-01

Cannabinoid type 1 receptors (CB1r) are an important modulatory site for emotional behavior. However, little is known on the effects of CB1r ligands on emotionality aspects of primates, even with their highly similar behavioral response and receptor density/distribution as humans. Thus, we analyzed the effects of the CB1r agonist WIN 55,212-2 (WIN; 1mg/kg) and the antagonist AM 251 (AM; 2mg/kg), systemically administered prior to a single brief (15 min) exposure to a novel open-field (OF) environment, on the behavior of individually tested adult black tufted-ear marmosets. Both WIN- and AM-treated subjects, compared to vehicle controls, had significantly lower rates of long (contact) calls and exploration, while higher levels of vigilance-related behaviors (scan/glance); these are indicators of anxiolysis in this setup. Changes in locomotion were not detected. However, in the vehicle and AM-groups, sojourn in the peripheral zone of the OF was significantly higher than in its central region. WIN-treated marmosets spent an equivalent amount of time in both zones. Therefore, activation or blockade CB1r function prior to a short and individual exposure to an unfamiliar environment exerted a significant and complex influence on different behavioral indicators of anxiety in these monkeys (i.e., a partially overlapping anxiolytic-like profile). AM 251, however, has no anxiolytic effect when the time spent in the center of the OF is considered. This is a major difference when compared to the WIN-treated group. Data were compared to the response profile reported in other pre-clinical (rodent) and clinical studies. Copyright © 2012 Elsevier B.V. All rights reserved.

Impact of different policies on unhealthy dietary behaviors in an urban adult population: an agent-based simulation model.

PubMed

Zhang, Donglan; Giabbanelli, Philippe J; Arah, Onyebuchi A; Zimmerman, Frederick J

2014-07-01

Unhealthy eating is a complex-system problem. We used agent-based modeling to examine the effects of different policies on unhealthy eating behaviors. We developed an agent-based simulation model to represent a synthetic population of adults in Pasadena, CA, and how they make dietary decisions. Data from the 2007 Food Attitudes and Behaviors Survey and other empirical studies were used to calibrate the parameters of the model. Simulations were performed to contrast the potential effects of various policies on the evolution of dietary decisions. Our model showed that a 20% increase in taxes on fast foods would lower the probability of fast-food consumption by 3 percentage points, whereas improving the visibility of positive social norms by 10%, either through community-based or mass-media campaigns, could improve the consumption of fruits and vegetables by 7 percentage points and lower fast-food consumption by 6 percentage points. Zoning policies had no significant impact. Interventions emphasizing healthy eating norms may be more effective than directly targeting food prices or regulating local food outlets. Agent-based modeling may be a useful tool for testing the population-level effects of various policies within complex systems.

Postfire logging in riparian areas.

PubMed

Reeves, Gordon H; Bisson, Peter A; Rieman, Bruce E; Benda, Lee E

2006-08-01

We reviewed the behavior of wildfire in riparian zones, primarily in the western United States, and the potential ecological consequences of postfire logging. Fire behavior in riparian zones is complex, but many aquatic and riparian organisms exhibit a suite of adaptations that allow relatively rapid recovery after fire. Unless constrained by other factors, fish tend to rebound relatively quickly, usually within a decade after a wildfire. Additionally, fire and subsequent erosion events contribute wood and coarse sediment that can create and maintain productive aquatic habitats over time. The potential effects of postfire logging in riparian areas depend on the landscape context and disturbance history of a site; however available evidence suggests two key management implications: (1) fire in riparian areas creates conditions that may not require intervention to sustain the long-term productivity of the aquatic network and (2) protection of burned riparian areas gives priority to what is left rather than what is removed. Research is needed to determine how postfire logging in riparian areas has affected the spread of invasive species and the vulnerability of upland forests to insect and disease outbreaks and how postfire logging will affect the frequency and behavior of future fires. The effectiveness of using postfire logging to restore desired riparian structure and function is therefore unproven, but such projects are gaining interest with the departure of forest conditions from those that existed prior to timber harvest, fire suppression, and climate change. In the absence of reliable information about the potential consequence of postfire timber harvest, we conclude that providing postfire riparian zones with the same environmental protections they received before they burned isjustified ecologically Without a commitment to monitor management experiments, the effects of postfire riparian logging will remain unknown and highly contentious.

Metamorphic P-T conditions across the Chugach Metamorphic Complex (Alaska)—A record of focussed exhumation during transpression

NASA Astrophysics Data System (ADS)

Bruand, Emilie; Gasser, Deta; Stüwe, Kurt

2014-03-01

The Chugach Metamorphic Complex (CMC) is a large high-grade metamorphic complex that developed in the Eocene within the Chugach accretionary complex along the margin of Alaska where subduction is still ongoing. The CMC has a conspicuous asymmetric structure with a migmatitic zone flanked in the north and west by amphibolite facies schists and in the south by a metabasite belt. To the north and south, major, crustal-scale fault zones juxtapose the Chugach terrane against much lower-grade and less-deformed sequences belonging to different terranes. Curiously these crustal-scale structures are known to have largely strike slip motion posing the question as to the nature of the exhumation of the high-grade complex between them. However, P-T conditions which would allow an estimation of the amount of exhumation were lacking for large parts of the complex. This paper presents petrographic descriptions, biotite-garnet thermometry, RSCM thermometry, average P-T calculations and pseudosection modelling from three major across-strike transects covering the complex from west to south-east. Our results reveal that, both temperature and pressure vary substantially across the complex. More specifically, peak metamorphic conditions evolve from 4-7 kbar and ~ 550-650 °C in the northern schist zone to 5-11 kbar and ~ 650-750 °C in the migmatite zone in the south of the complex. The higher pressure estimates in the south of the complex indicate that focussed exhumation must have occurred in this area and was probably initiated by the subduction of a high topographic relief (intra-oceanic arc or ridge subduction) and the accretion of the metabasite belt in the south. Exhumation of the CMC occurred in an overall transpressive strain regime, with strike-slip deformation concentrated along the northern Border Range fault zone and thrusting and exhumation focussed within the southern migmatite zone and splay faults of the Contact fault zone. The T/P ratios in the southern migmatite zone indicate that the thermal perturbation of the migmatites is less than previously inferred. These new results, associated with the structural data and the accretion of a metabasite belt in the south of the complex, seem incompatible with the existing ridge-subduction models.

Ductile creep and compaction: A mechanism for transiently increasing fluid pressure in mostly sealed fault zones

USGS Publications Warehouse

Sleep, Norman H.; Blanpied, M.L.

1994-01-01

A simple cyclic process is proposed to explain why major strike-slip fault zones, including the San Andreas, are weak. Field and laboratory studies suggest that the fluid within fault zones is often mostly sealed from that in the surrounding country rock. Ductile creep driven by the difference between fluid pressure and lithostatic pressure within a fault zone leads to compaction that increases fluid pressure. The increased fluid pressure allows frictional failure in earthquakes at shear tractions far below those required when fluid pressure is hydrostatic. The frictional slip associated with earthquakes creates porosity in the fault zone. The cycle adjusts so that no net porosity is created (if the fault zone remains constant width). The fluid pressure within the fault zone reaches long-term dynamic equilibrium with the (hydrostatic) pressure in the country rock. One-dimensional models of this process lead to repeatable and predictable earthquake cycles. However, even modest complexity, such as two parallel fault splays with different pressure histories, will lead to complicated earthquake cycles. Two-dimensional calculations allowed computation of stress and fluid pressure as a function of depth but had complicated behavior with the unacceptable feature that numerical nodes failed one at a time rather than in large earthquakes. A possible way to remove this unphysical feature from the models would be to include a failure law in which the coefficient of friction increases at first with frictional slip, stabilizing the fault, and then decreases with further slip, destabilizing it. ?? 1994 Birkha??user Verlag.

Primary weathering rates, water transit times, and concentration-discharge relations: A theoretical analysis for the critical zone

NASA Astrophysics Data System (ADS)

Ameli, Ali A.; Beven, Keith; Erlandsson, Martin; Creed, Irena F.; McDonnell, Jeffrey J.; Bishop, Kevin

2017-01-01

The permeability architecture of the critical zone exerts a major influence on the hydrogeochemistry of the critical zone. Water flow path dynamics drive the spatiotemporal pattern of geochemical evolution and resulting streamflow concentration-discharge (C-Q) relation, but these flow paths are complex and difficult to map quantitatively. Here we couple a new integrated flow and particle tracking transport model with a general reversible Transition State Theory style dissolution rate law to explore theoretically how C-Q relations and concentration in the critical zone respond to decline in saturated hydraulic conductivity (Ks) with soil depth. We do this for a range of flow rates and mineral reaction kinetics. Our results show that for minerals with a high ratio of equilibrium concentration (Ceq) to intrinsic weathering rate (Rmax), vertical heterogeneity in Ks enhances the gradient of weathering-derived solute concentration in the critical zone and strengthens the inverse stream C-Q relation. As CeqRmax decreases, the spatial distribution of concentration in the critical zone becomes more uniform for a wide range of flow rates, and stream C-Q relation approaches chemostatic behavior, regardless of the degree of vertical heterogeneity in Ks. These findings suggest that the transport-controlled mechanisms in the hillslope can lead to chemostatic C-Q relations in the stream while the hillslope surface reaction-controlled mechanisms are associated with an inverse stream C-Q relation. In addition, as CeqRmax decreases, the concentration in the critical zone and stream become less dependent on groundwater age (or transit time).

Analytics For Distracted Driver Behavior Modeling in Dilemma Zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Jan-Mou; Malikopoulos, Andreas; Thakur, Gautam

2014-01-01

In this paper, we present the results obtained and insights gained through the analysis of TRB contest data. We used exploratory analysis, regression, and clustering models for gaining insights into the driver behavior in a dilemma zone while driving under distraction. While simple exploratory analysis showed the distinguishing driver behavior patterns among different popu- lation groups in the dilemma zone, regression analysis showed statically signification relationships between groups of variables. In addition to analyzing the contest data, we have also looked into the possible impact of distracted driving on the fuel economy.

Silica-undersaturated reaction zones at a crust-mantle interface in the Highland Complex, Sri Lanka: Mass transfer and melt infiltration during high-temperature metasomatism

NASA Astrophysics Data System (ADS)

Fernando, G. W. A. R.; Dharmapriya, P. L.; Baumgartner, Lukas P.

2017-07-01

Sri Lanka is a crucial Gondwana fragment mostly composed of granulitic rocks in the Highland Complex surrounded by rocks with granulite to amphibolite grade in the Vijayan and Wanni Complex that were structurally juxtaposed during Pan-African orogeny. Fluids associated with granulite-facies metamorphism are thought to have controlled various lower crustal processes such as dehydration/hydration reactions, partial melting, and high-temperature metasomatism. Chemical disequilibrium in the hybrid contact zone between a near peak post-tectonic ultramafic enclave and siliceous granulitic gneiss at Rupaha within the Highland Complex produced metasomatic reaction zones under the presence of melt. Different reaction zones observed in the contact zone show the mineral assemblages phlogopite + spinel + sapphirine (zone A), spinel + sapphirine + corundum (zone B), corundum ( 30%) + biotite + plagioclase zone (zone C) and plagioclase + biotite + corundum ( 5%) zone (zone D). Chemical potential diagrams and mass balance reveal that the addition of Mg from ultramafic rocks and removal of Si from siliceous granulitic gneiss gave rise to residual enrichment of Al in the metasomatized mineral assemblages. We propose that contact metasomatism between the two units, promoted by melt influx, caused steady state diffusional transport across the profile. Corundum growth was promoted by the strong residual Al enrichment and Si depletion in reaction zone whereas sapphirine may have been formed under high Mg activity near the ultramafic rocks. Modelling also indicated that metasomatic alteration occurred at ca. 850 °C at 9 kbar, which is consistent with post-peak metamorphic conditions reached during the initial stage of exhumation in the lower crust and with temperature calculations based on conventional geothermometry.

Driver behavior and accident frequency in school zones: Assessing the impact of sign saturation.

PubMed

Strawderman, Lesley; Rahman, Md Mahmudur; Huang, Yunchen; Nandi, Apurba

2015-09-01

Based on the models of human information processing, if a driver observes too many of the same signs, he or she may no longer pay attention to those signs. In the case of school zones, this expected effect may lead to non-compliance to posted speeds, negatively impacting safety around nearby schools. This study aims to investigate the effect of the number of nearby school zones on driver behavior (vehicle speed and compliance) and accident frequency. As a measure of the density of school zones, this study introduced and defined a new term sign saturation and presented a methodology to calculate sign saturation for school zones. Results found a significant effect of sign saturation on vehicle speed, compliance, and accident frequency. This study also examined the speeding behavior in school zones for different time of the day and day of the week. Results found that speeding was more prevalent in the early mornings and during the weekends. Copyright © 2015 Elsevier Ltd. All rights reserved.

Corrosion Behavior of Low-C Medium-Mn Steel in Simulated Marine Immersion and Splash Zone Environment

NASA Astrophysics Data System (ADS)

Zhang, Dazheng; Gao, Xiuhua; Su, Guanqiao; Du, Linxiu; Liu, Zhenguang; Hu, Jun

2017-05-01

The corrosion behavior of low-C medium-Mn steel in simulated marine immersion and splash zone environment was studied by static immersion corrosion experiment and wet-dry cyclic corrosion experiment, respectively. Corrosion rate, corrosion products, surface morphology, cross-sectional morphology, elemental distribution, potentiodynamic polarization curves and electrochemical impedance spectra were used to elucidate the corrosion behavior of low-C medium-Mn steel. The results show that corrosion rate in immersion zone is much less than that in splash zone owing to its relatively mild environment. Manganese compounds are detected in the corrosion products and only appeared in splash zone environment, which can deteriorate the protective effect of rust layer. With the extension of exposure time, corrosion products are gradually transformed into dense and thick corrosion rust from the loose and porous one in these two environments. But in splash zone environment, alloying elements of Mn appear significant enrichment in the rust layer, which decrease the corrosion resistance of the steel.

Optimization of Highway Work Zone Decisions Considering Short-Term and Long-Term Impacts

DTIC Science & Technology

2010-01-01

strategies which can minimize the one-time work zone cost. Considering the complex and combinatorial nature of this optimization problem, a heuristic...combination of lane closure and traffic control strategies which can minimize the one-time work zone cost. Considering the complex and combinatorial nature ...zone) NV # the number of vehicle classes NPV $ Net Present Value p’(t) % Adjusted traffic diversion rate at time t p(t) % Natural diversion rate

Capture zone area distributions for nucleation and growth of islands during submonolayer deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Yong; Li, Maozhi; Evans, James W.

2016-12-07

A fundamental evolution equation is developed to describe the distribution of areas of capture zones (CZs) associated with islands formed by homogeneous nucleation and growth during submonolayer deposition on perfect flat surfaces. This equation involves various quantities which characterize subtle spatial aspects of the nucleation process. These quantities in turn depend on the complex stochastic geometry of the CZ tessellation of the surface, and their detailed form determines the CZ area distribution (CZD) including its asymptotic features. For small CZ areas, behavior of the CZD reflects the critical island size, i. For large CZ areas, it may reflect the probabilitymore » for nucleation near such large CZs. Predictions are compared with kinetic Monte Carlo simulation data for models with two-dimensional compact islands with i = 1 (irreversible island formation by diffusing adatom pairs) and i = 0 (adatoms spontaneously convert to stable nuclei, e.g., by exchange with the substrate).« less

Trade-off between morphological convergence and opportunistic diet behavior in fish hybrid zone

PubMed Central

Corse, Emmanuel; Costedoat, Caroline; Pech, Nicolas; Chappaz, Rémi; Grey, Jonathan; Gilles, André

2009-01-01

Background The invasive Chondrostoma nasus nasus has colonized part of the distribution area of the protected endemic species Chondrostoma toxostoma toxostoma. This hybrid zone is a complex system where multiple effects such as inter-species competition, bi-directional introgression, strong environmental pressure and so on are combined. Why do sympatric Chondrostoma fish present a unidirectional change in body shape? Is this the result of inter-species interactions and/or a response to environmental effects or the result of trade-offs? Studies focusing on the understanding of a trade-off between multiple parameters are still rare. Although this has previously been done for Cichlid species flock and for Darwin finches, where mouth or beak morphology were coupled to diet and genetic identification, no similar studies have been done for a fish hybrid zone in a river. We tested the correlation between morphology (body and mouth morphology), diet (stable carbon and nitrogen isotopes) and genomic combinations in different allopatric and sympatric populations for a global data set of 1330 specimens. To separate the species interaction effect from the environmental effect in sympatry, we distinguished two data sets: the first one was obtained from a highly regulated part of the river and the second was obtained from specimens coming from the less regulated part. Results The distribution of the hybrid combinations was different in the two part of the sympatric zone, whereas all the specimens presented similar overall changes in body shape and in mouth morphology. Sympatric specimens were also characterized by a larger diet behavior variance than reference populations, characteristic of an opportunistic diet. No correlation was established between the body shape (or mouth deformation) and the stable isotope signature. Conclusion The Durance River is an untamed Mediterranean river despite the presence of numerous dams that split the river from upstream to downstream. The sympatric effect on morphology and the large diet behavior range can be explained by a tendency toward an opportunistic behavior of the sympatric specimens. Indeed, the similar response of the two species and their hybrids implied an adaptation that could be defined as an alternative trade-off that underline the importance of epigenetics mechanisms for potential success in a novel environment. PMID:19860907

A reworked Lake Zone margin: Chronological and geochemical constraints from the Ordovician arc-related basement of the Hovd Zone (western Mongolia)

NASA Astrophysics Data System (ADS)

Soejono, Igor; Buriánek, David; Janoušek, Vojtěch; Svojtka, Martin; Čáp, Pavel; Erban, Vojtěch; Ganpurev, Nyamtsetseg

2017-12-01

The primary relationships and character of the boundaries between principal lithotectonic domains in the Mongolian tract of the Central Asian Orogenic Belt (CAOB) are still poorly constrained. This brings much uncertainty in understanding of the orogeny configuration and the complete accretionary history. The plutonic Khuurai Tsenkher Gol Complex and the mainly metasedimentary Bij Group represent associated medium- to high-grade basement complexes exposed in the Hovd Zone close to its boundary with the Lake Zone in western Mongolia. The Khuurai Tsenkher Gol Complex is composed of variously deformed acid to basic magmatic rocks intimately associated with the metamorphosed sedimentary and volcanic rocks of the Bij Group. Results of our field work, new U-Pb zircon ages and whole-rock geochemical data suggest an existence of two separate magmatic events within the evolution of the Khuurai Tsenkher Gol Complex. Early to Mid-Ordovician (476 ± 5 Ma and 467 ± 4 Ma protoliths) normal- to high-K calc-alkaline orthogneisses, metadiorites and metagabbros predominate over Mid-Silurian (430 ± 3 Ma) tholeiitic-mildly alkaline quartz monzodiorites. Whereas the geochemical signature of the former suite unequivocally demonstrates its magmatic-arc origin, that of the latter quartz monzodiorite suggests an intra-plate setting. As shown by Sr-Nd isotopic data, the older arc-related magmas were derived from depleted mantle and/or were generated by partial melting of juvenile metabasic crust. Detrital zircon age populations of the metasedimentary rocks together with geochemical signatures of the associated amphibolites imply that the Bij Group was a volcano-sedimentary sequence, formed probably in the associated fore-arc wedge basin. Moreover, our data argue for an identical provenance of the Altai and Hovd domains, overall westward sediment transport during the Early Palaeozoic and the east-dipping subduction polarity. The obvious similarities of the Khuurai Tsenkher Gol Complex (Hovd Zone) with the neighbouring Togtokhinshil Complex (Lake Zone) suggest that both magmatic complexes originally belonged to the same magmatic arc, related to the Palaeo-Asian subduction system. The geodynamic cause of the later, within-plate magmatic pulse is unclear, but was probably still related to the effects of retreating subduction (slab window/ocean ridge subduction or back-arc lithosphere thinning). The Khuurai Tsenkher Gol Complex was subsequently separated from the western margin of the Lake Zone and imbricated into the Hovd Zone mélange. It is proposed that the Lake/Hovd zones boundary in the study area represents a younger deformation zone rather than a true terrane boundary/suture. This could be a general feature of the suture zones within this part of the CAOB.

Permeability Variations Associated With Fault Reactivation in a Claystone Formation Investigated by Field Experiments and Numerical Simulations

NASA Astrophysics Data System (ADS)

Jeanne, Pierre; Guglielmi, Yves; Rutqvist, Jonny; Nussbaum, Christophe; Birkholzer, Jens

2018-02-01

We studied the relation between rupture and changes in permeability within a fault zone intersecting the Opalinus Clay formation at 300 m depth in the Mont Terri Underground Research Laboratory (Switzerland). A series of water injection experiments were performed in a borehole straddle interval set within the damage zone of the main fault. A three-component displacement sensor allowed an estimation of the displacement of a minor fault plane reactivated during a succession of step rate pressure tests. The experiment reveals that the fault hydromechanical (HM) behavior is different from one test to the other with varying pressure levels needed to trigger rupture and different slip behavior under similar pressure conditions. Numerical simulations were performed to better understand the reason for such different behavior and to investigate the relation between rupture nucleation, permeability change, pressure diffusion, and rupture propagation. Our main findings are as follows: (i) a rate frictional law and a rate-and-state permeability law can reproduce the first test, but it appears that the rate constitutive parameters must be pressure dependent to reproduce the complex HM behavior observed during the successive injection tests; (ii) almost similar ruptures can create or destroy the fluid diffusion pathways; (iii) a too high or too low diffusivity created by the main rupture prevents secondary rupture events from occurring whereas "intermediate" diffusivity favors the nucleation of a secondary rupture associated with the fluid diffusion. However, because rupture may in certain cases destroy permeability, this succession of ruptures may not necessarily create a continuous hydraulic pathway.

Chemotaxis in densely populated tissue determines germinal center anatomy and cell motility: a new paradigm for the development of complex tissues.

PubMed

Hawkins, Jared B; Jones, Mark T; Plassmann, Paul E; Thorley-Lawson, David A

2011-01-01

Germinal centers (GCs) are complex dynamic structures that form within lymph nodes as an essential process in the humoral immune response. They represent a paradigm for studying the regulation of cell movement in the development of complex anatomical structures. We have developed a simulation of a modified cyclic re-entry model of GC dynamics which successfully employs chemotaxis to recapitulate the anatomy of the primary follicle and the development of a mature GC, including correctly structured mantle, dark and light zones. We then show that correct single cell movement dynamics (including persistent random walk and inter-zonal crossing) arise from this simulation as purely emergent properties. The major insight of our study is that chemotaxis can only achieve this when constrained by the known biological properties that cells are incompressible, exist in a densely packed environment, and must therefore compete for space. It is this interplay of chemotaxis and competition for limited space that generates all the complex and biologically accurate behaviors described here. Thus, from a single simple mechanism that is well documented in the biological literature, we can explain both higher level structure and single cell movement behaviors. To our knowledge this is the first GC model that is able to recapitulate both correctly detailed anatomy and single cell movement. This mechanism may have wide application for modeling other biological systems where cells undergo complex patterns of movement to produce defined anatomical structures with sharp tissue boundaries.

Fast determination of soil behavior in the capillary zone using simple laboratory tests.

DOT National Transportation Integrated Search

2012-12-01

Frost heave and thaw weakening are typical problems for engineers building in northern regions. These unsaturated-soil behaviors are : caused by water flowing through the capillary zone to a freezing front, where it forms ice lenses. Although suction...

Multi-Fault Rupture Scenarios in the Brawley Seismic Zone

NASA Astrophysics Data System (ADS)

Kyriakopoulos, C.; Oglesby, D. D.; Rockwell, T. K.; Meltzner, A. J.; Barall, M.

2017-12-01

Dynamic rupture complexity is strongly affected by both the geometric configuration of a network of faults and pre-stress conditions. Between those two, the geometric configuration is more likely to be anticipated prior to an event. An important factor in the unpredictability of the final rupture pattern of a group of faults is the time-dependent interaction between them. Dynamic rupture models provide a means to investigate this otherwise inscrutable processes. The Brawley Seismic Zone in Southern California is an area in which this approach might be important for inferring potential earthquake sizes and rupture patterns. Dynamic modeling can illuminate how the main faults in this area, the Southern San Andreas (SSAF) and Imperial faults, might interact with the intersecting cross faults, and how the cross faults may modulate rupture on the main faults. We perform 3D finite element modeling of potential earthquakes in this zone assuming an extended array of faults (Figure). Our results include a wide range of ruptures and fault behaviors depending on assumptions about nucleation location, geometric setup, pre-stress conditions, and locking depth. For example, in the majority of our models the cross faults do not strongly participate in the rupture process, giving the impression that they are not typically an aid or an obstacle to the rupture propagation. However, in some cases, particularly when rupture proceeds slowly on the main faults, the cross faults indeed can participate with significant slip, and can even cause rupture termination on one of the main faults. Furthermore, in a complex network of faults we should not preclude the possibility of a large event nucleating on a smaller fault (e.g. a cross fault) and eventually promoting rupture on the main structure. Recent examples include the 2010 Mw 7.1 Darfield (New Zealand) and Mw 7.2 El Mayor-Cucapah (Mexico) earthquakes, where rupture started on a smaller adjacent segment and later cascaded into a larger event. For that reason, we are investigating scenarios of a moderate rupture on a cross fault, and determining conditions under which the rupture will propagate onto the adjacent SSAF. Our investigation will provide fundamental insights that may help us interpret faulting behaviors in other areas, such as the complex Mw 7.8 2016 Kaikoura (New Zealand) earthquake.

Chronic lymphocytic thyroiditis: could it be influenced by a petrochemical complex? Data from a cytological study in South-Eastern Sicily.

PubMed

Arena, Salvatore; Latina, Adele; Baratta, Roberto; Burgio, Giuseppe; Gullo, Damiano; Benvenga, Salvatore

2015-04-01

In genetically predisposed individuals, exogenous factors (including pollution) influence the development of Hashimoto's thyroiditis/chronic lymphocytic thyroiditis (CLT). CLT may also be a risk factor for associated thyroid cancer. Few data are available on the role of pollution from petrochemical complexes, one of which is located in the Siracusa province (South-Eastern Sicily), in the pathogenesis of CLT. i) To study the frequency of CLT in fine-needle aspiration cytology (FNAC)-interrogated thyroid nodules from patients who were stably resident in their zones, comparing it in patients living in the petrochemical complex area (zone A) with that of patients from a control area (zone B). ii) To study the frequency of CLT in the FNAC categories of malignancy risk, comparing the two zones. We retrospectively evaluated cytologically adequate slides of 1323 nodules in 1013 outpatients who underwent ultrasound-guided FNAC from 2006 to 2012. We stratified by area of residence, gender, and FNAC categories of malignancy risk. CLT was detected with significantly greater frequency in either patients or nodules from zone A compared with zone B (32.0% vs 23.1%, P=0.002 or 28.2% vs 18.8%, P=0.0001), with a female preponderance (F=35.2% vs M=21.1% or 30.4% vs 20.4%, zone A and F=26.5% vs 12.3% or 21.6% vs 9.5%, zone B). Regardless of zone, CLT was approximately twofold more frequent in the suspiciously malignant+malignant classes (TH4+THY5=47.6%, zone A and 32.4%, zone B) compared with the benign+intermediate classes (THY2+THY3=27.3%, zone A and 18.2%, zone B), but with a clear stepwise THY2 through THY5 increase only in zone A (THY2=25.3%, THY5=66.7%; THY2=18.6%, THY5=28.6% in zone B). The petrochemical complex-related pollution is an environmental factor involved in the development of CLT and, likely, in the CLT association with thyroid neoplasms. © 2015 European Society of Endocrinology.

Changes in voiding behavior in a mouse model of Alzheimer’s disease

PubMed Central

Biallosterski, B. T.; Prickaerts, J.; Rahnama’i, M. S.; de Wachter, S.; van Koeveringe, G. A.; Meriaux, C.

2015-01-01

Besides cognitive decline and behavioral alteration, urinary incontinence often occurs in patients suffering from Alzheimer’s disease (AD). To determine whether the transgenic mouse model of AD, APP/PS1 (APPSL/PS1M146L) mouse, shows alteration of the urinary bladder function and anxiety, as for patients with AD, we examined the urinary marking behavior in relation to affective behavior. At 18 months of age voiding behavior of APP/PS1 and wild type (WT) mice was assessed by using a modified filter paper assay in combination with video tracing, with the cage divided into a center and corner zones. Anxiety-related behavior and locomotion were respectively tested in an elevated zero maze (EZM) and an open field (OF). The APP/PS1 mice urinated more in the center zone than the WT mice. The total volume of markings was significantly lower in the APP/PS1 mice. In both groups, the average volume of a marking in the corner zone was larger than in the center zone. In the EZM, the APP/PS1 mice spent less time in the open arms of the arena, considered as anxiogenic zones, than the WT mice. During the OF task, the APP/PS1 mice covered a longer distance than the WT mice. These findings show that the APP/PS1 mice have a different voiding behavior compared to the WT mice, i.e., urinating with small volumes and voiding in the center of the cage, and suggest that increased locomotor activity and anxiety-related behaviors are factors in the change in voiding pattern in the APP/PS1 mouse. PMID:26379542

Magmatic structure and geochemistry of the Luanga Mafic-Ultramafic Complex: Further constraints for the PGE-mineralized magmatism in Carajás, Brazil

NASA Astrophysics Data System (ADS)

Mansur, Eduardo Teixeira; Ferreira Filho, Cesar Fonseca

2016-12-01

The Luanga Complex is part of the Serra Leste Magmatic Suite, a cluster of PGE-mineralized mafic-ultramafic intrusions located in the northeastern portion of the Carajás Mineral Province. The Luanga Complex is a medium-sized layered intrusion consisting of three main zones: i. the lower Ultramafic Zone comprising ultramafic adcumulates (peridotite), ii. the Transition Zone comprising interlayered ultramafic and mafic cumulates (harzburgite, orthopyroxenite and norite) and iii. the upper Mafic Zone comprising a monotonous sequence of mafic cumulates (norite) with minor orthopyroxenite layers. Several PGE-mineralized zones occur in the Transition Zone but the bulk of the PGE resources are hosted within a 10-50 meter thick interval of disseminated sulfides at the contact of the Ultramafic and Transition Zones. The compositional range of cumulus olivine (Fo78.9-86.4) is comparable to those reported for layered intrusions originated from moderate primitive parental magmas. Mantle normalized alteration-resistant trace element patterns of noritic rocks are fractionated, as indicated by relative enrichment in LREE and Th, with negative Nb and Ta anomalies, suggesting assimilation of older continental crust. Ni contents in olivine in the Luanga Complex (up to 7500 ppm) stand among the highest values reported in layered intrusions globally. The highest Ni contents in olivine in the Luanga Complex occur in distinctively PGE enriched (Pt + Pd > 1 ppm) intervals of the Transition Zone, in both sulfide-poor and sulfide bearing (1-3 vol.%) rocks. The origin of the PGE- and Ni-rich parental magma of the Luanga Complex is discussed considering the upgrading of magmas through dissolution of previously formed Ni-rich sulfide melts. Our results suggest that high Ni contents in olivine and/or orthopyroxene provide an additional exploration tool for Ni-PGE deposits, particularly useful for target selection in large magmatic provinces.

Extensional tectonics during the igneous emplacement of the mafic-ultramafic rocks of the Barberton greenstone belt

NASA Technical Reports Server (NTRS)

Dewit, M. J.

1986-01-01

The simatic rocks (Onverwacht Group) of the Barberton greenstone belt are part of the Jamestown ophiolite complex. This ophiolite, together with its thick sedimentary cover occupies a complex thrust belt. Field studies have identified two types of early faults which are entirely confined to the simatic rocks and are deformed by the later thrusts and associated folds. The first type of fault (F1a) is regional and always occurs in the simatic rocks along and parallel to the lower contacts of the ophiolite-related cherts (Middle Marker and equivalent layers). These fault zones have previously been referred to both as flaser-banded gneisses and as weathering horizons. In general the zones range between 1-30m in thickness. Displacements along these zones are difficult to estimate, but may be in the order of 1-100 km. The structures indicate that the faults formed close to horizontal, during extensional shear and were therefore low angle normal faults. F1a zones overlap in age with the formation of the ophiolite complex. The second type of faults (F1b) are vertical brittle-ductile shear zones, which crosscut the complex at variable angles and cannot always be traced from plutonic to overlying extrusive (pillowed) simatic rocks. F1b zones are also apparently of penecontemporaneous origin with the intrusive-extrusive igneous processs. F1b zones may either represent transform fault-type activity or represent root zones (steepened extensions) of F1a zones. Both fault types indicate extensive deformation in the rocks of the greenstone belt prior to compressional overthrust tectonics.

Indentation mapping revealed poroelastic, but not viscoelastic, properties spanning native zonal articular cartilage.

PubMed

Wahlquist, Joseph A; DelRio, Frank W; Randolph, Mark A; Aziz, Aaron H; Heveran, Chelsea M; Bryant, Stephanie J; Neu, Corey P; Ferguson, Virginia L

2017-12-01

Osteoarthrosis is a debilitating disease affecting millions, yet engineering materials for cartilage regeneration has proven difficult because of the complex microstructure of this tissue. Articular cartilage, like many biological tissues, produces a time-dependent response to mechanical load that is critical to cell's physiological function in part due to solid and fluid phase interactions and property variations across multiple length scales. Recreating the time-dependent strain and fluid flow may be critical for successfully engineering replacement tissues but thus far has largely been neglected. Here, microindentation is used to accomplish three objectives: (1) quantify a material's time-dependent mechanical response, (2) map material properties at a cellular relevant length scale throughout zonal articular cartilage and (3) elucidate the underlying viscoelastic, poroelastic, and nonlinear poroelastic causes of deformation in articular cartilage. Untreated and trypsin-treated cartilage was sectioned perpendicular to the articular surface and indentation was used to evaluate properties throughout zonal cartilage on the cut surface. The experimental results demonstrated that within all cartilage zones, the mechanical response was well represented by a model assuming nonlinear biphasic behavior and did not follow conventional viscoelastic or linear poroelastic models. Additionally, 10% (w/w) agarose was tested and, as anticipated, behaved as a linear poroelastic material. The approach outlined here provides a method, applicable to many tissues and biomaterials, which reveals and quantifies the underlying causes of time-dependent deformation, elucidates key aspects of material structure and function, and that can be used to provide important inputs for computational models and targets for tissue engineering. Elucidating the time-dependent mechanical behavior of cartilage, and other biological materials, is critical to adequately recapitulate native mechanosensory cues for cells. We used microindentation to map the time-dependent properties of untreated and trypsin treated cartilage throughout each cartilage zone. Unlike conventional approaches that combine viscoelastic and poroelastic behaviors into a single framework, we deconvoluted the mechanical response into separate contributions to time-dependent behavior. Poroelastic effects in all cartilage zones dominated the time-dependent behavior of articular cartilage, and a model that incorporates tension-compression nonlinearity best represented cartilage mechanical behavior. These results can be used to assess the success of regeneration and repair approaches, as design targets for tissue engineering, and for development of accurate computational models. Copyright © 2017 Acta Materialia Inc. All rights reserved.

Non-zero Δ33S preserved in rocks from the Basal Ultramafic Sequence indicate crustal contamination in the most primitive magma of the Rustenburg Layered Suite (Bushveld Complex, South Africa)

NASA Astrophysics Data System (ADS)

Magalhaes, N.; Wilson, A.; Penniston-Dorland, S.; Farquhar, J.

2017-12-01

The sulfur isotope composition of the Rustenburg Layered Suite (RLS) of the Bushveld Complex is different than expected from a magma sourced from the mantle (Δ33S=0), as measurements indicate the presence of an Archean surface-derived sulfur component. The Basal Ultramafic Sequence (BUS) is thought to be the most primitive magma of the RLS, as it is the lowest in the stratigraphy, has the highest Mg# (>0.92) for primary phases (olivine and orthopyroxene), and is in direct contact with the Magaliesberg quartzite of the Pretoria Group.We have measured the composition of sulfides in rocks from the Lower Zone, Marginal Zone, and the BUS, which were sampled in a 2300m drill core from the Clapham area, in the eastern Bushveld Complex. While the rocks of the Lower Zone have a relatively homogeneous non-zero Δ33S of 0.065‰, comparable to previous findings, there is an abrupt increase in the value of Δ33S (up to +0.301‰) in the Marginal Zone, which may be consistent with the observation in hand sample of assimilation of country rocks. The BUS also shows a surface-derived signal (average of 0.040‰), which is the lowest measured for any zone of the RLS.The non-zero Δ33S found in the Basal Ultramafic Sequence is evidence of the contamination of the magma with surface-derived material. In the upper parts of the intrusion, the Δ33S signature relates to whole-rock Sr and Nd isotopes, and their relationship suggests multiple sources of contamination. However, the relationship between sulfur and in-situ strontium isotope compositions (plagioclase) in this section of the RLS is not as clear as it is further up in the stratigraphy. This might reflect small-scale processes during the magmatic chamber stage, different compositions of local wall rock compared to deeper contaminants, or the presence of decoupled behavior between the isotope systems.These differences in the sulfur isotope composition between the different stratigraphic layers have been preserved regardless of any late magmatic processes that may have occurred, which further supports that the sulfur isotope composition of the RLS was not fully homogenized at a later stage by fluid migration.

Impact of Different Policies on Unhealthy Dietary Behaviors in an Urban Adult Population: An Agent-Based Simulation Model

PubMed Central

Giabbanelli, Philippe J.; Arah, Onyebuchi A.; Zimmerman, Frederick J.

2014-01-01

Objectives. Unhealthy eating is a complex-system problem. We used agent-based modeling to examine the effects of different policies on unhealthy eating behaviors. Methods. We developed an agent-based simulation model to represent a synthetic population of adults in Pasadena, CA, and how they make dietary decisions. Data from the 2007 Food Attitudes and Behaviors Survey and other empirical studies were used to calibrate the parameters of the model. Simulations were performed to contrast the potential effects of various policies on the evolution of dietary decisions. Results. Our model showed that a 20% increase in taxes on fast foods would lower the probability of fast-food consumption by 3 percentage points, whereas improving the visibility of positive social norms by 10%, either through community-based or mass-media campaigns, could improve the consumption of fruits and vegetables by 7 percentage points and lower fast-food consumption by 6 percentage points. Zoning policies had no significant impact. Conclusions. Interventions emphasizing healthy eating norms may be more effective than directly targeting food prices or regulating local food outlets. Agent-based modeling may be a useful tool for testing the population-level effects of various policies within complex systems. PMID:24832414

The history of late holocene surface-faulting earthquakes on the central segments of the Wasatch fault zone, Utah

USGS Publications Warehouse

Duross, Christopher; Personius, Stephen; Olig, Susan S; Crone, Anthony J.; Hylland, Michael D.; Lund, William R; Schwartz, David P.

2017-01-01

The Wasatch fault (WFZ)—Utah’s longest and most active normal fault—forms a prominent eastern boundary to the Basin and Range Province in northern Utah. To provide paleoseismic data for a Wasatch Front regional earthquake forecast, we synthesized paleoseismic data to define the timing and displacements of late Holocene surface-faulting earthquakes on the central five segments of the WFZ. Our analysis yields revised histories of large (M ~7) surface-faulting earthquakes on the segments, as well as estimates of earthquake recurrence and vertical slip rate. We constrain the timing of four to six earthquakes on each of the central segments, which together yields a history of at least 24 surface-faulting earthquakes since ~6 ka. Using earthquake data for each segment, inter-event recurrence intervals range from about 0.6 to 2.5 kyr, and have a mean of 1.2 kyr. Mean recurrence, based on closed seismic intervals, is ~1.1–1.3 kyr per segment, and when combined with mean vertical displacements per segment of 1.7–2.6 m, yield mean vertical slip rates of 1.3–2.0 mm/yr per segment. These data refine the late Holocene behavior of the central WFZ; however, a significant source of uncertainty is whether structural complexities that define the segments of the WFZ act as hard barriers to ruptures propagating along the fault. Thus, we evaluate fault rupture models including both single-segment and multi-segment ruptures, and define 3–17-km-wide spatial uncertainties in the segment boundaries. These alternative rupture models and segment-boundary zones honor the WFZ paleoseismic data, take into account the spatial and temporal limitations of paleoseismic data, and allow for complex ruptures such as partial-segment and spillover ruptures. Our data and analyses improve our understanding of the complexities in normal-faulting earthquake behavior and provide geological inputs for regional earthquake-probability and seismic hazard assessments.

Fault pattern at the northern end of the Death Valley - Furnace Creek fault zone, California and Nevada

NASA Technical Reports Server (NTRS)

Liggett, M. A. (Principal Investigator); Childs, J. F.

1974-01-01

The author has identified the following significant results. The pattern of faulting associated with the termination of the Death Valley-Furnace Creek Fault Zone in northern Fish Lake Valley, Nevada was studied in ERTS-1 MSS color composite imagery and color IR U-2 photography. Imagery analysis was supported by field reconnaissance and low altitude aerial photography. The northwest-trending right-lateral Death Valley-Furnace Creek Fault Zone changes northward to a complex pattern of discontinuous dip slip and strike slip faults. This fault pattern terminates to the north against an east-northeast trending zone herein called the Montgomery Fault Zone. No evidence for continuation of the Death Valley-Furnace Creek Fault Zone is recognized north of the Montgomery Fault Zone. Penecontemporaneous displacement in the Death Valley-Furnace Creek Fault Zone, the complex transitional zone, and the Montgomery Fault Zone suggests that the systems are genetically related. Mercury mineralization appears to have been localized along faults recognizable in ERTS-1 imagery within the transitional zone and the Montgomery Fault Zone.

Mapping the Habitable Zone of Exoplanets with a 2D Energy Balance Model

NASA Astrophysics Data System (ADS)

Moon, Nicole Taylor; Dr. Lisa Kaltenegger, Dr. Ramses Ramirez

2018-01-01

Traditionally, the habitable zone has been defined as the distance at which liquid water could exist on the surface of a rocky planet. However, different complexity models (simplified and fast:1D, and complex and time-intense:3D) models derive different boundaries for the habitable zone. The goal of this project was to test a new intermediate complexity 2D Energy Balance model, add a new ice albedo feedback mechanism, and derive the habitable zone boundaries. After completing this first project, we also studied how other feedback mechanisms, such as the presence of clouds and the carbonate-silicate cycle, effected the location of the habitable zone boundaries using this 2D model. This project was completed as part of a 2017 summer REU program hosted by Cornell's Center for Astrophysics and Plantary Sciecne and in partnership with the Carl Sagan Institute.

Reaction behavior of SO2 in the sintering process with flue gas recirculation.

PubMed

Yu, Zhi-Yuan; Fan, Xiao-Hui; Gan, Min; Chen, Xu-Ling; Chen, Qiang; Huang, Yun-Song

2016-07-01

The primary goal of this paper is to reveal the reaction behavior of SO2 in the sinter zone, combustion zone, drying-preheating zone, and over-wet zone during flue gas recirculation (FGR) technique. The results showed that SO2 retention in the sinter zone was associated with free-CaO in the form of CaSO3/CaSO4, and the SO2 adsorption reached a maximum under 900ºC. SO2 in the flue gas came almost from the combustion zone. One reaction behavior was the oxidation of sulfur in the sintering mix when the temperature was between 800 and 1000ºC; the other behavior was the decomposition of sulfite/sulfate when the temperature was over 1000ºC. However, the SO2 adsorption in the sintering bed mainly occurred in the drying-preheating zone, adsorbed by CaCO3, Ca(OH)2, and CaO. When the SO2 adsorption reaction in the drying-preheating zone reached equilibrium, the excess SO2 gas continued to migrate to the over-wet zone and was then absorbed by Ca(OH)2 and H2O. The emission rising point of SO2 moved forward in combustion zone, and the concentration of SO2 emissions significantly increased in the case of flue gas recirculation (FGR) technique. Aiming for the reuse of the sensible heat and a reduction in exhaust gas emission, the FGR technique is proposed in the iron ore sintering process. When using the FGR technique, SO2 emission in exhaust gas gets changed. In practice, the application of the FGR technique in a sinter plant should be cooperative with the flue gas desulfurization (FGD) technique. Thus, it is necessary to study the influence of the FGR technique on SO2 emissions because it will directly influence the demand and design of the FGD system.

Spectral Invariant Behavior of Zenith Radiance Around Cloud Edges Observed by ARM SWS

NASA Technical Reports Server (NTRS)

Marshak, A.; Knyazikhin, Y.; Chiu, J. C.; Wiscombe, W. J.

2009-01-01

The ARM Shortwave Spectrometer (SWS) measures zenith radiance at 418 wavelengths between 350 and 2170 nm. Because of its 1-sec sampling resolution, the SWS provides a unique capability to study the transition zone between cloudy and clear sky areas. A spectral invariant behavior is found between ratios of zenith radiance spectra during the transition from cloudy to cloud-free. This behavior suggests that the spectral signature of the transition zone is a linear mixture between the two extremes (definitely cloudy and definitely clear). The weighting function of the linear mixture is a wavelength-independent characteristic of the transition zone. It is shown that the transition zone spectrum is fully determined by this function and zenith radiance spectra of clear and cloudy regions. An important result of these discoveries is that high temporal resolution radiance measurements in the clear-to-cloud transition zone can be well approximated by lower temporal resolution measurements plus linear interpolation.

Strategies and Rubrics for Teaching Complex Systems Theory to Novices (Invited)

NASA Astrophysics Data System (ADS)

Fichter, L. S.

2010-12-01

Bifurcation. Self-similarity. Fractal. Sensitive dependent. Agents. Self-organized criticality. Avalanche behavior. Power laws. Strange attractors. Emergence. The language of complexity is fundamentally different from the language of equilibrium. If students do not know these phenomena, and what they tell us about the pulse of dynamic systems, complex systems will be opaque. A complex system is a group of agents. (individual interacting units, like birds in a flock, sand grains in a ripple, or individual friction units along a fault zone), existing far from equilibrium, interacting through positive and negative feedbacks, following simple rules, forming interdependent, dynamic, evolutionary networks. Complex systems produce behaviors that cannot be predicted deductively from knowledge of the behaviors of the individual components themselves; they must be experienced. What complexity theory demonstrates is that, by following simple rules, all the agents end up coordinating their behavior—self organizing—so that what emerges is not chaos, but meaningful patterns. How can we introduce Freshman, non-science, general education students to complex systems theories, in 3 to 5 classes; in a way they really get it, and can use the principles to understand real systems? Complex systems theories are not a series of unconnected or disconnected equations or models; they are developed as narratives that makes sense of how all the pieces and properties are interrelated. The principles of complex systems must be taught as deliberately and systematically as the equilibrium principles normally taught; as, say, the systematic training from pre-algebra and geometry to algebra. We have developed a sequence of logically connected narratives (strategies and rubrics) that introduce complex systems principles using models that can be simulated in a computer, in class, in real time. The learning progression has a series of 12 models (e.g. logistic system, bifurcation diagrams, genetic algorithms, etc.) leading to 19 learning outcomes that encompass most of the universality properties that characterize complex systems. They are developed in a specific order to achieve specific ends of understanding. We use these models in various depths and formats in courses ranging from gened courses, to evolutionary systems and environmental systems, to upper level geology courses. Depending on the goals of a course, the learning outcomes can be applied to understanding many other complex systems; e.g. oscillating chemical reactions (reaction-diffusion and activator-inhibitor systems), autocatalytic networks, hysteresis (bistable) systems, networks, and the rise/collapse of complex societies. We use these and other complex systems concepts in various classes to talk about the origin of life, ecosystem organization, game theory, extinction events, and environmental system behaviors. The applications are almost endless. The complete learning progression with models, computer programs, experiments, and learning outcomes is available at: www.jmu.edu/geology/ComplexEvolutionarySystems/

Barium isotope composition of altered oceanic crust from the IODP Site 1256 at the East Pacific Rise

NASA Astrophysics Data System (ADS)

Nan, X.; Yu, H.; Gao, Y.

2017-12-01

To understand the behavior of Ba isotopes in the oceanic crust during seawater alteration, we analyzed Ba isotopes for altered oceanic crust (AOC) from the IODP Site 1256 at the East Pacific Rise (EPR). The samples include 33 basalts, 5 gabbros, and 1 gabbronorite. This drill profile has four sections from top to bottom, including the volcanic section, transition zone, sheeted dyke complex, and plutonic complex. They display various degrees of alteration with obviously variable temperatures and water/rock ratios (Gao et al., 2012). The volcanic section is slightly to moderately altered by seawater at 100 to 250°; the transition zone is a mixing zone between upwelling hydrothermal fluids and downwelling seawater; and the sheeted dyke complex and plutonic complex are highly altered by hydrothermal fluids (˜250°). Ba isotopes were analyzed on a Neptune Plus MC-ICP-MS at the University of Science and Technology of China. The long-term precision of δ137/134Ba is better than 0.04‰ (2SD). The δ137/134Ba of the volcanic section and the top of the transition zone range between -0.01 and 0.30‰, higher than the δ137/134Ba of fresh MORB and upper mantle (0.020 ± 0.021‰, 2SE, Huang et al., 2015). Similarly, the δ137/134Ba of the sheeted dyke complex ranges from 0.05 to 0.28‰. The plutonic section has δ137/134Ba from -0.17 to -0.05‰, which is lower than the upper mantle, with one exception that has δ137/134Ba of 0.19‰. No correlation exists between Ba contents and δ137/134Ba. The weighted average δ137/134Ba of the AOC samples is 0.13±0.04‰ (2SE), significantly higher than that of the upper mantle. In all, our AOC data reveal obvious Ba isotopic fractionation, reflecting alteration of the AOC by hydrothermal fluids and seawater. The obvious difference of Ba isotope composition between the AOC and the upper mantle further indicates that recycling of the AOC could result in Ba isotope heterogeneity of the mantle. References: Gao Y, Vils F, Cooper K M, et al. (2012) Downhole variation of lithium and oxygen isotopic compositions of oceanic crust at East Pacific Rise, ODP Site 1256. Geochemistry, Geophysics, Geosystems,13(10). Huang F., Nan X., Hu M., Huang S. and Huang J. (2015) Barium isotope compositions of igneous rocks. Goldschm. Abstr.2015, 1331.

Mathematical model to select the optimal alternative for an integral plan to desertification and erosion control for the Chaco Area in Salta Province (Argentine)

NASA Astrophysics Data System (ADS)

Grau, J. B.; Anton, J. M.; Tarquis, A. M.; Colombo, F.; de Los Rios, L.; Cisneros, J. M.

2010-04-01

Multi-criteria Decision Analysis (MCDA) is concerned with identifying the values, uncertainties and other issues relevant in a given decision, its rationality, and the resulting optimal decision. These decisions are difficult because the complexity of the system or because of determining the optimal situation or behavior. This work will illustrate how MCDA is applied in practice to a complex problem to resolve such us soil erosion and degradation. Desertification is a global problem and recently it has been studied in several forums as ONU that literally says: "Desertification has a very high incidence in the environmental and food security, socioeconomic stability and world sustained development". Desertification is the soil quality loss and one of FAO's most important preoccupations as hunger in the world is increasing. Multiple factors are involved of diverse nature related to: natural phenomena (water and wind erosion), human activities linked to soil and water management, and others not related to the former. In the whole world this problem exists, but its effects and solutions are different. It is necessary to take into account economical, environmental, cultural and sociological criteria. A multi-criteria model to select among different alternatives to prepare an integral plan to ameliorate or/and solve this problem in each area has been elaborated taking in account eight criteria and six alternatives. Six sub zones have been established following previous studies and in each one the initial matrix and weights have been defined to apply on different criteria. Three Multicriteria Decision Methods have been used for the different sub zones: ELECTRE, PROMETHEE and AHP. The results show a high level of consistency among the three different multicriteria methods despite the complexity of the system studied. The methods are described for La Estrella sub zone, indicating election of weights, Initial Matrixes, the MATHCAD8 algorithms used for PROMETHEE, and the Graph of Expert Choice showing the results of AHP. A brief schema of the actions recommended for each of the six different sub zones is reported in Conclusions, with "We can combine Autochthonous and High Value Forest" for La Estrella.

Synthesis, characterization and antibacterial activity of a new calcium complex using sodium 2-mercaptobenzothiazole and 1, 10-phenanthroline as ligands

NASA Astrophysics Data System (ADS)

Gulab, Hussain; Shah, Zarbad; Mahmood, Mazhar; Shah, Syed Raza; Ali, Sajid; Iqbal, Muhammad; Khan, Muhammad Naeem; Flörke, Ulrich; Khan, Shahid Ali

2018-02-01

A new Ca-complex (Ca (H2 O)4 (C12 H8 N2)2)(C7 H4 N S2)2 has been synthesized by the reaction of calcium chloride, sodium 2-mercaptobenzothiazole and 1,10-phenanthroline. The complex was characterized by using X-ray crystallography and FT-IR spectroscopy. The complex was tested against different bacterial strains i.e. Staphylococcus aureus, Escherichia coli, Acinetobacter baumanni, Providencia stuartii and Pseudomonas aeruginosa. The complex was found to exhibit remarkable anti-bacterial activity against Pseudomonas aeruginosa with an inhibition zone of 25 mm and good anti-bacterial activity against Acinetobacter baumanni with a zone of inhibition of 16 mm comparable to the Levofloxacin standard (zone of inhibition of 25 mm).

Vehicle emission implications of drivers' smart advisory system for traffic operations in work zones.

PubMed

Li, Qing; Qiao, Fengxiang; Yu, Lei

2016-05-01

Wireless communication systems have been broadly applied in various complicated traffic operations to improve mobility and safety on roads, which may raise a concern about the implication of the new technology on vehicle emissions. This paper explores how the wireless communication systems improve drivers' driving behaviors and its contributions to the emission reduction, in terms of Operating Mode (OpMode) IDs distribution used in emission estimation. A simulated work zone with completed traffic operation was selected as a test bed. Sixty subjects were recruited for the tests, whose demographic distribution was based on the Census data in Houston, Texas. A scene of a pedestrian's crossing in the work zone was designed for the driving test. Meanwhile, a wireless communication system called Drivers Smart Advisory System (DSAS) was proposed and introduced in the driving simulation, which provided drivers with warning messages in the work zone. Two scenarios were designed for a leading vehicle as well as for a following vehicle driving through the work zone, which included a base test without any wireless communication systems, and a driving test with the trigger of the DSAS. Subjects' driving behaviors in the simulation were recorded to evaluate safety and estimate the vehicle emission using the Environmental Protection Agency (EPA) released emission model MOVES. The correlation between drivers' driving behavior and the distribution of the OpMode ID during each scenario was investigated. Results show that the DSAS was able to induce drivers to accelerate smoothly, keep longer headway distance and stop earlier for a hazardous situation in the work zone, which driving behaviors result in statistically significant reduction in vehicle emissions for almost all studied air pollutants (p-values range from 4.10E-51 to 2.18E-03). The emission reduction was achieved by the switching the distribution of the OpMode IDs from higher emission zones to lower emission zones. Transportation section is a significant source of greenhouse gas emissions. Many studies demonstrate that the wireless communication system dedicated for safety and mobility issues may contribute to the induction in vehicle emissions through changing driving behaviors. An insight into the correlation between the driving behaviors and the distribution of Operating Mode (OpMode) IDs is essential to enhance the emission reduction. The result of this study shows that with a Drivers Smart Advisory System (DSAS) drivers accelerated smoothly and stopped earlier for a hazardous situation, which induce the switch of the OpMode IDs from high emission zones to lower emission zones.

Paper 58714 - Exploring activated faults hydromechanical processes from semi-controled field injection experiments

NASA Astrophysics Data System (ADS)

Guglielmi, Y.; Cappa, F.; Nussbaum, C.

2015-12-01

The appreciation of the sensitivity of fractures and fault zones to fluid-induced-deformations in the subsurface is a key question in predicting the reservoir/caprock system integrity around fluid manipulations with applications to reservoir leakage and induced seismicity. It is also a question of interest in understanding earthquakes source, and recently the hydraulic behavior of clay faults under a potential reactivation around nuclear underground depository sites. Fault and fractures dynamics studies face two key problems (1) the up-scaling of laboratory determined properties and constitutive laws to the reservoir scale which is not straightforward when considering faults and fractures heterogeneities, (2) the difficulties to control both the induced seismicity and the stimulated zone geometry when a fault is reactivated. Using instruments dedicated to measuring coupled pore pressures and deformations downhole, we conducted field academic experiments to characterize fractures and fault zones hydromechanical properties as a function of their multi-scale architecture, and to monitor their dynamic behavior during the earthquake nucleation process. We show experiments on reservoir or cover rocks analogues in underground research laboratories where experimental conditions can be optimized. Key result of these experiments is to highlight how important the aseismic fault activation is compared to the induced seismicity. We show that about 80% of the fault kinematic moment is aseismic and discuss the complex associated fault friction coefficient variations. We identify that the slip stability and the slip velocity are mainly controlled by the rate of the permeability/porosity increase, and discuss the conditions for slip nucleation leading to seismic instability.

Neural Organization of the Optic Lobe Changes Steadily from Late Embryonic Stage to Adulthood in Cuttlefish Sepia pharaonis

PubMed Central

Liu, Yung-Chieh; Liu, Tsung-Han; Su, Chia-Hao; Chiao, Chuan-Chin

2017-01-01

The optic lobe is the largest structure in the cuttlefish brain. While the general morphology of the optic lobe in adult cuttlefish has been well described, the 3D structure and ontogenetic development of its neural organization have not been characterized. To correlate observed behavioral changes within the brain structure along the development of this animal, optic lobes from the late embryonic stage to adulthood were examined systematically in the present study. The MRI scan revealed that the so called “cell islands” in the medulla of the cephalopod's optic lobe (Young, 1962, 1974) are in fact a contiguous tree-like structure. Quantification of the neural organizational development of optic lobes showed that structural features of the cortex and radial column zone were established earlier than those of the tangential zone during embryonic and post-hatching stages. Within the cell islands, the density of nuclei was decreased while the size of nuclei was increased during the development. Furthermore, the visual processing area in the optic lobe showed a significant variation in lateralization during embryonic and juvenile stages. Our observation of a continuous increase in neural fibers and nucleus size in the tangential zone of the optic lobe from late embryonic stage to adulthood indicates that the neural organization of the optic lobe is modified along the development of cuttlefish. These findings thus support that the ontogenetic change of the optic lobe is responsible for their continuously increased complexity in body patterning and visuomotor behaviors. PMID:28798695

Synthesis and studies on Cu(II), Co(II), Ni(II) complexes of Knoevenagel β-diketone ligands.

PubMed

Sumathi, S; Tharmaraj, P; Sheela, C D; Anitha, C

2012-11-01

Transition metal complexes of various acetylacetone based ligands of the type ML [where M=Cu(II), Ni(II), Co(II); L=3-(aryl)-pentane-2,4-dione] have been synthesized. The structural features have been derived from their elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis, (1)H NMR, Mass and ESR spectral studies. Conductivity measurements reveal that all the complexes are non-electrolytic in nature. Spectroscopic and other analytical data of the complexes suggest octahedral geometry for other metal(II) complexes. The redox behavior of the copper(II) complexes have been studied by cyclic voltammetry. The free ligands and their metal complexes have been screened for their in vitro biological activities against the bacteria Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus as well as the fungus Candida albicans by well diffusion method. The zone of inhibition value indicates that the most of the metal(II) complexes are found to possess increased activities compared to those of the free ligands. All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic generation (SHG) efficiency of the ligands (L1-L3) was found to be considerable effect than that of urea and KDP (potassium dihydrogen phosphate). Copyright © 2012 Elsevier B.V. All rights reserved.

Synthesis and studies on Cu(II), Co(II), Ni(II) complexes of Knoevenagel β-diketone ligands

NASA Astrophysics Data System (ADS)

Sumathi, S.; Tharmaraj, P.; Sheela, C. D.; Anitha, C.

2012-11-01

Transition metal complexes of various acetylacetone based ligands of the type ML [where M = Cu(II), Ni(II), Co(II); L = 3-(aryl)-pentane-2,4-dione] have been synthesized. The structural features have been derived from their elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis, 1H NMR, Mass and ESR spectral studies. Conductivity measurements reveal that all the complexes are non-electrolytic in nature. Spectroscopic and other analytical data of the complexes suggest octahedral geometry for other metal(II) complexes. The redox behavior of the copper(II) complexes have been studied by cyclic voltammetry. The free ligands and their metal complexes have been screened for their in vitro biological activities against the bacteria Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus as well as the fungus Candida albicans by well diffusion method. The zone of inhibition value indicates that the most of the metal(II) complexes are found to possess increased activities compared to those of the free ligands. All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic generation (SHG) efficiency of the ligands (L1-L3) was found to be considerable effect than that of urea and KDP (potassium dihydrogen phosphate).

Dynamic Simulations for the Seismic Behavior on the Shallow Part of the Fault Plane in the Subduction Zone during Mega-Thrust Earthquakes

NASA Astrophysics Data System (ADS)

Tsuda, K.; Dorjapalam, S.; Dan, K.; Ogawa, S.; Watanabe, T.; Uratani, H.; Iwase, S.

2012-12-01

The 2011 Tohoku-Oki earthquake (M9.0) produced some distinct features such as huge slips on the order of several ten meters around the shallow part of the fault and different areas with radiating seismic waves for different periods (e.g., Lay et al., 2012). These features, also reported during the past mega-thrust earthquakes in the subduction zone such as the 2004 Sumatra earthquake (M9.2) and the 2010 Chile earthquake (M8.8), get attentions as the distinct features if the rupture of the mega-thrust earthquakes reaches to the shallow part of the fault plane. Although various kinds of observations for the seismic behavior (rupture process and ground motion characteristics etc.) on the shallow part of the fault plane during the mega-trust earthquakes have been reported, the number of analytical or numerical studies based on dynamic simulation is still limited. Wendt et al. (2009), for example, revealed that the different distribution of initial stress produces huge differences in terms of the seismic behavior and vertical displacements on the surface. In this study, we carried out the dynamic simulations in order to get a better understanding about the seismic behavior on the shallow part of the fault plane during mega-thrust earthquakes. We used the spectral element method (Ampuero, 2009) that is able to incorporate the complex fault geometry into simulation as well as to save computational resources. The simulation utilizes the slip-weakening law (Ida, 1972). In order to get a better understanding about the seismic behavior on the shallow part of the fault plane, some parameters controlling seismic behavior for dynamic faulting such as critical slip distance (Dc), initial stress conditions and friction coefficients were changed and we also put the asperity on the fault plane. These understandings are useful for the ground motion prediction for future mega-thrust earthquakes such as the earthquakes along the Nankai Trough.

Coffee Berry Borer Joins Bark Beetles in Coffee Klatch

PubMed Central

Jaramillo, Juliana; Torto, Baldwyn; Mwenda, Dickson; Troeger, Armin; Borgemeister, Christian; Poehling, Hans-Michael; Francke, Wittko

2013-01-01

Unanswered key questions in bark beetle-plant interactions concern host finding in species attacking angiosperms in tropical zones and whether management strategies based on chemical signaling used for their conifer-attacking temperate relatives may also be applied in the tropics. We hypothesized that there should be a common link in chemical signaling mediating host location by these Scolytids. Using laboratory behavioral assays and chemical analysis we demonstrate that the yellow-orange exocarp stage of coffee berries, which attracts the coffee berry borer, releases relatively high amounts of volatiles including conophthorin, chalcogran, frontalin and sulcatone that are typically associated with Scolytinae chemical ecology. The green stage of the berry produces a much less complex bouquet containing small amounts of conophthorin but no other compounds known as bark beetle semiochemicals. In behavioral assays, the coffee berry borer was attracted to the spiroacetals conophthorin and chalcogran, but avoided the monoterpenes verbenone and α-pinene, demonstrating that, as in their conifer-attacking relatives in temperate zones, the use of host and non-host volatiles is also critical in host finding by tropical species. We speculate that microorganisms formed a common basis for the establishment of crucial chemical signals comprising inter- and intraspecific communication systems in both temperate- and tropical-occurring bark beetles attacking gymnosperms and angiosperms. PMID:24073204

Coffee berry borer joins bark beetles in coffee klatch.

PubMed

Jaramillo, Juliana; Torto, Baldwyn; Mwenda, Dickson; Troeger, Armin; Borgemeister, Christian; Poehling, Hans-Michael; Francke, Wittko

2013-01-01

Unanswered key questions in bark beetle-plant interactions concern host finding in species attacking angiosperms in tropical zones and whether management strategies based on chemical signaling used for their conifer-attacking temperate relatives may also be applied in the tropics. We hypothesized that there should be a common link in chemical signaling mediating host location by these Scolytids. Using laboratory behavioral assays and chemical analysis we demonstrate that the yellow-orange exocarp stage of coffee berries, which attracts the coffee berry borer, releases relatively high amounts of volatiles including conophthorin, chalcogran, frontalin and sulcatone that are typically associated with Scolytinae chemical ecology. The green stage of the berry produces a much less complex bouquet containing small amounts of conophthorin but no other compounds known as bark beetle semiochemicals. In behavioral assays, the coffee berry borer was attracted to the spiroacetals conophthorin and chalcogran, but avoided the monoterpenes verbenone and α-pinene, demonstrating that, as in their conifer-attacking relatives in temperate zones, the use of host and non-host volatiles is also critical in host finding by tropical species. We speculate that microorganisms formed a common basis for the establishment of crucial chemical signals comprising inter- and intraspecific communication systems in both temperate- and tropical-occurring bark beetles attacking gymnosperms and angiosperms.

Differential timing of granule cell production during cerebellum development underlies generation of the foliation pattern.

PubMed

Legué, Emilie; Gottshall, Jackie L; Jaumouillé, Edouard; Roselló-Díez, Alberto; Shi, Wei; Barraza, Luis Humberto; Washington, Senna; Grant, Rachel L; Joyner, Alexandra L

2016-09-08

The mouse cerebellum (Cb) has a remarkably complex foliated three-dimensional (3D) structure, but a stereotypical cytoarchitecture and local circuitry. Little is known of the cellular behaviors and genes that function during development to determine the foliation pattern. In the anteroposterior axis the mammalian cerebellum is divided by lobules with distinct sizes, and the foliation pattern differs along the mediolateral axis defining a medial vermis and two lateral hemispheres. In the vermis, lobules are further grouped into four anteroposterior zones (anterior, central, posterior and nodular zones) based on genetic criteria, and each has distinct lobules. Since each cerebellar afferent group projects to particular lobules and zones, it is critical to understand how the 3D structure of the Cb is acquired. During cerebellar development, the production of granule cells (gcs), the most numerous cell type in the brain, is required for foliation. We hypothesized that the timing of gc accumulation is different in the four vermal zones during development and contributes to the distinct lobule morphologies. In order to test this idea, we used genetic inducible fate mapping to quantify accumulation of gcs in each lobule during the first two postnatal weeks in mice. The timing of gc production was found to be particular to each lobule, and delayed in the central zone lobules relative to the other zones. Quantification of gc proliferation and differentiation at three time-points in lobules representing different zones, revealed the delay involves a later onset of maximum differentiation and prolonged proliferation of gc progenitors in the central zone. Similar experiments in Engrailed mutants (En1 (-/+) ;En2 (-/-) ), which have a smaller Cb and altered foliation pattern preferentially outside the central zone, showed that gc production, proliferation and differentiation are altered such that the differences between zones are attenuated compared to wild-type mice. Our results reveal that gc production is differentially regulated in each zone of the cerebellar vermis, and our mutant analysis indicates that the dynamics of gc production plays a role in determining the 3D structure of the Cb.

Attack Coverage in High-Level Men’s Volleyball: Organization on the Edge of Chaos?

PubMed Central

Laporta, Lorenzo; Nikolaidis, Pantelis; Thomas, Luke; Afonso, José

2015-01-01

Change is pervasive, but emerging patterns are occasionally detectable through analysis of systemic behaviors. Match analysis uses these patterns in order to reduce the degree of improvisation and to optimize the training process. However, it is possible that certain game phases elude systematic patterning. In this vein, our aim was to analyze the case of attack coverage in men’s volleyball, as we suspected it would elude systematic patterning and has received negligible attention in scientific research. We analyzed the occurrence of attack coverage in 4544 plays of the 2011 Volleyball World League. A Chi-square test with residual adjusted values was applied to explore significant associations between variables. A Monte Carlo correction was applied, as some cells had n<5. Effect sizes were determined using Cramer’s V. Overall, attack coverage occurred in 3.89% of ball possessions, and 23 distinct structures emerged. These structures lacked significant associations with the game complex, setting zone, and effect of attack coverage. Conversely, attack coverage structures showed significant associations with the attack zone and tempo, with very strong effect sizes (V=0.472 and V=0.521, respectively). As certain attack zones are deeply associated with attack tempo, it is apparent that quicker attack plays affect attack coverage structuring, promoting the formation of less complex structures. Ultimately, attack coverage structures seem to depend on momentary constraints, thereby rendering rigid systematization impracticable. Still, we contended that a principle-based approach might be suitable. This invites researchers to rethink how to interpret game regularities. PMID:26557208

The Plumbing System Feeding the Lusi Eruption Revealed by Ambient Noise Tomography

NASA Astrophysics Data System (ADS)

Fallahi, Mohammad Javad; Obermann, Anne; Lupi, Matteo; Karyono, Karyono; Mazzini, Adriano

2017-10-01

Lusi is a sediment-hosted hydrothermal system featuring clastic-dominated geyser-like eruption behavior in East Java, Indonesia. We use 10 months of ambient seismic noise cross correlations from 30 temporary seismic stations to obtain a 3-D model of shear wave velocity anomalies beneath Lusi, the neighboring Arjuno-Welirang volcanic complex, and the Watukosek fault system connecting the two. Our work reveals a hydrothermal plume, rooted at a minimum 6 km depth that reaches the surface at the Lusi site. Furthermore, the inversion shows that this vertical anomaly is connected to the adjacent volcanic complex through a narrow ( 3 km wide) low velocity corridor slicing the survey area at a depth of 4-6 km. The NE-SW direction of this elongated zone matches the strike of the Watukosek fault system. Distinct magmatic chambers are also inferred below the active volcanoes. The large-scale tomography features an exceptional example of a subsurface connection between a volcanic complex and a solitary erupting hydrothermal system hosted in a hydrocarbon-rich back-arc sedimentary basin. These results are consistent with a scenario where deep-seated fluids (e.g., magmas and released hydrothermal fluids) flow along a region of enhanced transmissivity (i.e., the Watukosek fault system damage zone) from the volcanic arc toward the back arc basin where Lusi resides. The triggered metamorphic reactions occurring at depth in the organic-rich sediments generated significant overpressure and fluid upwelling that is today released at the spectacular Lusi eruption site.

Accommodative Behavior of Young Eyes Wearing Multifocal Contact Lenses.

PubMed

Altoaimi, Basal H; Almutairi, Meznah S; Kollbaum, Pete S; Bradley, Arthur

2018-05-01

The effectiveness of multifocal contact lenses (MFCLs) at slowing myopia progression may hinge on the accommodative behavior of young eyes fit with these presbyopic style lenses. Can they remove hyperopic defocus? Convergence accommodation as well as pupil size and the zonal geometry are likely to contribute to the final accommodative responses. The aim of this study was to examine the accommodation behavior of young adult eyes wearing MFCLs and the effectiveness of these MFCLs at removing foveal hyperopic defocus when viewing near targets binocularly. Using a high-resolution Shack-Hartmann aberrometer, accommodation and pupil behavior of eight young adults (27.25 ± 2.05 years) were measured while subjects fixated a 20/40 character positioned between 2 m and 20 cm (0.50 to 5.00 diopters [D]) in 0.25-D steps. Refractive states were measured while viewing binocularly and monocularly with single-vision and both center-distance and center-near +2.00 D add MFCLs. Refractive state was defined using three criteria: the dioptric power that would (1) minimize the root mean square wavefront error, (2) focus the pupil center, and (3) provide the peak image quality. Refractive state pupil maps reveal the complex optics that exist in eyes wearing MFCLs. Reduced accommodative gain beyond the far point of the near add revealed that young subjects used the added plus power to help focus near targets. During accommodation to stimuli closer than the far point generated by the add power, a midperipheral region of the pupil was approximately focused, resulting in the smallest accommodative errors for the minimum root mean square-defined measures of refractive state. Paraxial images were always hyperopically or myopically defocused in eyes viewing binocularly with center-distance or center-near MFCLs, respectively. Because of zone geometry in the concentric MFCLs tested, the highly aberrated transition zone between the distance and near optics contributed a significant proportion and sometimes the majority of light to the resulting images. Young eyes fit with MFCLs containing significant transition zones accommodated to focus pupil regions between the near and distance optics, which resulted in less than optimal retinal image quality and myopic or hyperopic defocus in either the pupil center or pupil margins.

Frictional Behavior of Altered Basement Approaching the Nankai Trough

NASA Astrophysics Data System (ADS)

Saffer, D. M.; Ikari, M.; Rooney, T. O.; Marone, C.

2017-12-01

The frictional behavior of basement rocks plays an important role in subduction zone faulting and seismicity. This includes earthquakes seaward of the trench, large megathrust earthquakes where seamounts are subducting, or where the plate interface steps down to basement. In exhumed subduction zone rocks such as the Shimanto complex in Japan, slivers of basalt are entrained in mélange which is evidence of basement involvement in the fault system. Scientific drilling during the Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) recovered basement rock from two reference sites (C0011 and C0012) located seaward of the trench offshore the Kii Peninsula during Integrated Ocean Discovery Program (IODP) Expeditions 322 and 333. The basement rocks are pillow basalts that appear to be heterogeneously altered, resulting in contrasting dense blue material and more vesicular gray material. Major element geochemistry shows differences in silica, calcium oxides and loss-on-ignition between the two types of samples. Minor element geochemistry reveals significant differences in vanadium, chromium, and barium. X-ray diffraction on a bulk sample powder representing an average composition shows a phyllosilicate content of 20%, most of which is expandable clays. We performed laboratory friction experiments in a biaxial testing apparatus as either intact sample blocks, or as gouge powders. We combine these experiments with measurements of Pennsylvania slate for comparison, including a mixed-lithology intact block experiment. Intact Nankai basement blocks exhibit a coefficient of sliding friction of 0.73; for Nankai basement powder, slate powder, slate blocks and slate-on-basement blocks the coefficient of sliding friction ranges from 0.44 to 0.57. At slip rates ranging from 3x10-8 to 3x10-4 m/s we observe predominantly velocity-strengthening frictional behavior, indicating a tendency for stable slip. At rates of < 1x10-6 m/s some velocity-weakening was observed, specifically in intact rock-on-rock experiments. Our results show that basement alteration tends to reduce the tendency for unstable slip, but that the altered Nankai basement may still exhibit seismogenic behavior in the case of localized slip in competent rock.

Seismic detection of the summit magma complex of kilauea volcano, hawaii.

PubMed

Thurber, C H

1984-01-13

Application of simultaneous inversion of seismic P-wave arrival time data to the investigation of the crust beneath Kilauea Volcano yields a detailed picture of the volcano's heterogeneous structure. Zones of anomalously high seismic velocity are found associated with the volcano's rift zones. A low-velocity zone at shallow depth directly beneath the caldera coincides with an aseismic region interpreted as being the locus of Kilauea's summit magma complex.

Investigating the relative permeability behavior of microporosity-rich carbonates and tight sandstones with multiscale pore network models

NASA Astrophysics Data System (ADS)

Bultreys, Tom; Stappen, Jeroen Van; Kock, Tim De; Boever, Wesley De; Boone, Marijn A.; Hoorebeke, Luc Van; Cnudde, Veerle

2016-11-01

The relative permeability behavior of rocks with wide ranges of pore sizes is in many cases still poorly understood and is difficult to model at the pore scale. In this work, we investigate the capillary pressure and relative permeability behavior of three outcrop carbonates and two tight reservoir sandstones with wide, multimodal pore size distributions. To examine how the drainage and imbibition properties of these complex rock types are influenced by the connectivity of macropores to each other and to zones with unresolved small-scale porosity, we apply a previously presented microcomputed-tomography-based multiscale pore network model to these samples. The sensitivity to the properties of the small-scale porosity is studied by performing simulations with different artificial sphere-packing-based networks as a proxy for these pores. Finally, the mixed-wet water-flooding behavior of the samples is investigated, assuming different wettability distributions for the microporosity and macroporosity. While this work is not an attempt to perform predictive modeling, it seeks to qualitatively explain the behavior of the investigated samples and illustrates some of the most recent developments in multiscale pore network modeling.

Numerical analysis of the creeping behavior of the S. Andrea di Perarolo secondary landslide (Italian Eastern Alps)

NASA Astrophysics Data System (ADS)

Cioli, C.; Genevois, R.; Iafelice, M.; Zorzi, L.

2012-04-01

The S. Andrea landslide is a complex secondary phenomenon characterized by continuous movements causing a very high hazard condition for the near Perarolo di Cadore village (Italian Eastern Alps). A significant amount of geological and geotechnical investigations has been carried out in the past allowing the detection of the basal sliding surface. In specific, the sliding surface coincides with the contact between the bedrock and the overlying mass of an old landslides, involving a volume of about 180.000 cubic meters. A numerical approach has been adopted to analyze the stability of slope. This method is able to simulate the formation and development of shear zones as areas of strain localization in the model. Indeed, the S. Andrea landslide has been, then, investigated using FLAC, a two-dimensional explicit finite difference program, particularly useful in case of slopes with complex geometry. In order to build up a suitable model, variation of geological, hydrogeological and geotechnical parameters have been identified from the interpretation of all available data. In a preliminary stage, a Mohr-Coulomb plasticity model has been adopted except for the bedrock, which was characterized by an isotropic elastic model. Groundwater flow condition has been performed evaluating the change in pore pressure coupled to the mechanical deformation calculation. Numerical results show that this model cannot simulate real displacement behavior of the slope mainly due to both the complex material behavior and lithological heterogeneity, and due to geotechnical spatial complexity of different soils and mechanical parameters. It has been assumed that it was necessary to improve the model in the light of a time dependent behavior of existing soils. An elastic-viscoplastic model has been then used to reproduce the observed creeping behavior, and only in viscoplastic region time effects have been considered. Discussion of results points out on: i) the evolution of the ``mechanical damage'' within the moving mass; ii) the identification of possible causes of the displacements recorded in the field; iii) the utility of the computational approach for the creeping response of the soil slopes under constant load conditions and for two dimensional applications.

Observed Spectral Invariant Behavior of Zenith Radiance in the Transition Zone Between Cloud-Free and Cloudy Regions

NASA Technical Reports Server (NTRS)

Marshak, A.; Knyazikhin, Y.; Chiu, C.; Wiscombe, W.

2010-01-01

The Atmospheric Radiation Measurement Program's (ARM) new Shortwave Spectrometer (SWS) looks straight up and measures zenith radiance at 418 wavelengths between 350 and 2200 nm. Because of its 1-sec sampling resolution, the SWS provides a unique capability to study the transition zone between cloudy and clear sky areas. A surprising spectral invariant behavior is found between ratios of zenith radiance spectra during the transition from cloudy to cloud-free atmosphere. This behavior suggests that the spectral signature of the transition zone is a linear mixture between the two extremes (definitely cloudy and definitely clear). The weighting function of the linear mixture is found to be a wavelength-independent characteristic of the transition zone. It is shown that the transition zone spectrum is fully determined by this function and zenith radiance spectra of clear and cloudy regions. This new finding may help us to better understand and quantify such physical phenomena as humidification of aerosols in the relatively moist cloud environment and evaporation and activation of cloud droplets.

Retrogressive hydration of calc-silicate xenoliths in the eastern Bushveld complex: evidence for late magmatic fluid movement

NASA Astrophysics Data System (ADS)

Wallmach, T.; Hatton, C. J.; De Waal, S. A.; Gibson, R. L.

1995-11-01

Two calc-silicate xenoliths in the Upper Zone of the Bushveld complex contain mineral assemblages which permit delineation of the metamorphic path followed after incorporation of the xenoliths into the magma. Peak metamorphism in these xenoliths occurred at T=1100-1200°C and P <1.5 kbar. Retrograde metamorphism, probably coinciding with the late magmatic stage, is characterized by the breakdown of akermanite to monticellite and wollastonite at 700°C and the growth of vesuvianite from melilite. The latter implies that water-rich fluids (X CO 2 <0.2) were present and probably circulating through the cooling magmatic pile. In contrast, calc-silicate xenoliths within the lower zones of the Bushveld complex, namely in the Marginal and Critical Zones, also contain melilite, monticellite and additional periclase with only rare development of vesuvianite. This suggests that the Upper Zone cumulate pile was much 'wetter' in the late-magmatic stage than the earlier-formed Critical and Marginal Zone cumulate piles.

Simulation of the mobility of metal - EDTA complexes in groundwater: The influence of contaminant metals

USGS Publications Warehouse

Friedly, J.C.; Kent, D.B.; Davis, J.A.

2002-01-01

Reactive transport simulations were conducted to model chemical reactions between metal - EDTA (ethylenediaminetetraacetic acid) complexes during transport in a mildly acidic quartz - sand aquifer. Simulations were compared with the results of small-scale tracer tests wherein nickel-, zinc-, and calcium - EDTA complexes and free EDTA were injected into three distinct chemical zones of a plume of sewage-contaminated groundwater. One zone had a large mass of adsorbed, sewage-derived zinc; one zone had a large mass of adsorbed manganese resulting from mildly reducing conditions created bythe sewage plume; and one zone had significantly less adsorbed manganese and negligible zinc background. The chemical model assumed that the dissolution of iron(III) from metal - hydroxypolymer coatings on the aquifer sediments by the metal - EDTA complexes was kinetically restricted. All other reactions, including metal - EDTA complexation, zinc and manganese adsorption, and aluminum hydroxide dissolution were assumed to reach equilibrium on the time scale of transport; equilibrium constants were either taken from the literature or determined independently in the laboratory. A single iron(III) dissolution rate constant was used to fit the breakthrough curves observed in the zone with negligible zinc background. Simulation results agreed well with the experimental data in all three zones, which included temporal moments derived from breakthrough curves at different distances downgradient from the injections and spatial moments calculated from synoptic samplings conducted at different times. Results show that the tracer cloud was near equilibrium with respect to Fe in the sediment after 11 m of transport in the Zn-contaminated region but remained far from equilibrium in the other two zones. Sensitivity studies showed that the relative rate of iron(III) dissolution by the different metal - EDTA complexes was less important than the fact that these reactions are rate controlled. Results suggest that the published solubility for ferrihydrite reasonably approximates the Fe solubility of the hydroxypolymer coatings on the sediments. Aluminum may be somewhat more soluble than represented by the equilibrium constant for gibbsite, and its dissolution may be rate controlled when reacting with Ca - EDTA complexes.

Fluid-injection and the mechanics of frictional stability of shale-bearing faults

NASA Astrophysics Data System (ADS)

Scuderi, Marco Maria; Collettini, Cristiano; Marone, Chris

2017-04-01

Fluid overpressure is one of the primary mechanisms for triggering tectonic fault slip and human-induced seismicity. This mechanism is appealing because fluids lubricate the fault and reduce the effective normal stress that holds the fault in place. However, current models of earthquake nucleation, based on rate- and state- friction, imply that stable sliding is favored by the increase of pore fluid pressure. Despite this apparent dilemma, there are a few studies on the role of fluid pressure in frictional stability under controlled, laboratory conditions. Here, we describe laboratory experiments on shale fault gouge, conducted in the double direct shear configuration in a true-triaxial machine. To characterize frictional stability and hydrological properties we performed three types of experiments: 1) stable sliding shear experiment to determine the material failure envelope resulting in fault strength of µ=0.28 and fault zone permeability (k 10-19m2); 2) velocity step experiments to determine the rate- and state- frictional properties, characterized by a velocity strengthening behavior with a negative rate parameter b, indicative of stable aseismic creep; 3) creep experiment to study fault slip evolution with increasing pore-fluid pressure. In these creep experiments fault slip history can be divided in three main stages: a) for low fluid pressure the fault is locked and undergoes compaction; b) with increasing fluid pressurization, we observe aseismic creep (i.e. v=0.0001 µm/s) associated with fault dilation, with maintained low permeability; c) As fluid pressure is further increased and we approach the failure criteria fault begins to accelerate, the dilation rate increases causing an increase in permeability. Following the first acceleration we document complex fault slip behavior characterized by periodic accelerations and decelerations with slip velocity that remains slow (i.e. v 200 µm/s), never approaching dynamic slip rates. Surprisingly, this complex slip behavior is associated with fault zone compaction and permeability increase as opposite to the dilation hardening mechanism that is usually invoked to quench the instability. We relate this complex fault slip behaviour to the interplay between fault weakening induced by fluid pressurization and the strong rate-strengthening behaviour of shales. Our data show that fault rheology and fault stability is controlled by the coupling between fluid pressure and rate- and state- friction parameters suggesting that their comprehensive characterization is fundamental for assessing the role of fluid pressure in natural and human induced earthquakes.

Characteristics of the Central Costa Rican Seismogenic Zone Determined from Microseismicity

NASA Astrophysics Data System (ADS)

DeShon, H. R.; Schwartz, S. Y.; Bilek, S. L.; Dorman, L. M.; Protti, M.; Gonzalez, V.

2001-12-01

Large or great subduction zone thrust earthquakes commonly nucleate within the seismogenic zone, a region of unstable slip on or near the converging plate interface. A better understanding of the mechanical, thermal and hydrothermal processes controlling seismic behavior in these regions requires accurate earthquake locations. Using arrival time data from an onland and offshore local seismic array and advanced 3D absolute and relative earthquake location techniques, we locate interplate seismic activity northwest of the Osa Peninsula, Costa Rica. We present high resolution locations of ~600 aftershocks of the 8/20/1999 Mw=6.9 underthrusting earthquake recorded by our local network between September and December 1999. We have developed a 3D velocity model based on published refraction lines and located events within a subducting slab geometry using QUAKE3D, a finite-differences based grid-searching algorithm (Nelson & Vidale, 1990). These absolute locations are input into HYPODD, a location program that uses P and S wave arrival time differences from nearby events and solves for the best relative locations (Waldhauser & Ellsworth, 2000). The pattern of relative earthquake locations is tied to an absolute reference using the absolute positions of the best-located earthquakes in the entire population. By using these programs in parallel, we minimize location errors, retain the aftershock pattern and provide the best absolute locations within a complex subduction geometry. We use the resulting seismicity pattern to determine characteristics of the seismogenic zone including geometry and up- and down-dip limits. These are compared with thermal models of the Middle America subduction zone, structures of the upper and lower plates, and characteristics of the Nankai seismogenic zone.

Modeling merging behavior at lane drops.

DOT National Transportation Integrated Search

2015-02-01

In work-zone configurations where lane drops are present, merging of traffic at the taper presents an operational concern. In : addition, as flow through the work zone is reduced, the relative traffic safety of the work zone is also reduced. Improvin...

Fault zone structure and kinematics from lidar, radar, and imagery: revealing new details along the creeping San Andreas Fault

NASA Astrophysics Data System (ADS)

DeLong, S.; Donnellan, A.; Pickering, A.

2017-12-01

Aseismic fault creep, coseismic fault displacement, distributed deformation, and the relative contribution of each have important bearing on infrastructure resilience, risk reduction, and the study of earthquake physics. Furthermore, the impact of interseismic fault creep in rupture propagation scenarios, and its impact and consequently on fault segmentation and maximum earthquake magnitudes, is poorly resolved in current rupture forecast models. The creeping section of the San Andreas Fault (SAF) in Central California is an outstanding area for establishing methodology for future scientific response to damaging earthquakes and for characterizing the fine details of crustal deformation. Here, we describe how data from airborne and terrestrial laser scanning, airborne interferometric radar (UAVSAR), and optical data from satellites and UAVs can be used to characterize rates and map patterns of deformation within fault zones of varying complexity and geomorphic expression. We are evaluating laser point cloud processing, photogrammetric structure from motion, radar interferometry, sub-pixel correlation, and other techniques to characterize the relative ability of each to measure crustal deformation in two and three dimensions through time. We are collecting new and synthesizing existing data from the zone of highest interseismic creep rates along the SAF where a transition from a single main fault trace to a 1-km wide extensional stepover occurs. In the stepover region, creep measurements from alignment arrays 100 meters long across the main fault trace reveal lower rates than those in adjacent, geomorphically simpler parts of the fault. This indicates that deformation is distributed across the en echelon subsidiary faults, by creep and/or stick-slip behavior. Our objectives are to better understand how deformation is partitioned across a fault damage zone, how it is accommodated in the shallow subsurface, and to better characterize the relative amounts of fault creep and potential stick-slip fault behavior across the plate boundary at these sites in order to evaluate the potential for rupture propagation in large earthquakes.

Evolution of a calcite marble shear zone complex on Thassos Island, Greece: microstructural and textural fabrics and their kinematic significance

NASA Astrophysics Data System (ADS)

Bestmann, Michel; Kunze, Karsten; Matthews, Alan

2000-11-01

The deformation history of a monophase calcite marble shear zone complex on Thassos Island, Northern Greece, is reconstructed by detailed geometric studies of the textural and microstructural patterns relative to a fixed reference system (shear zone boundary, SZB). Strain localization within the massive marble complex is linked to decreasing P- T conditions during the exhumation process of the metamorphic core complex. Solvus thermometry indicates that temperatures of 300-350°C prevailed during part of the shear zone deformation history. The coarse-grained marble protolith outside the shear zone is characterized by symmetrically oriented twin sets due to early coaxial deformation. A component of heterogeneous non-coaxial deformation is first recorded within the adjacent protomylonite. Enhanced strain weakening by dynamic recrystallization promoted strong localization of plastic deformation in the ultramylonite of the calcite shear zone, where high strain was accommodated by non-coaxial flow. This study demonstrates that both a pure shear and a simple shear strain path can result in similar crystallographic preferred orientations (single c-axis maximum perpendicular to the SZB) by different dominant deformation mechanisms. Separated a-axis pole figures (+ a- and - a-axis) show different density distributions with orthorhombic texture symmetry in the protolith marble and monoclinic symmetry in the ultramylonite marble consistently with the observed grain fabric symmetry.

Tracer transport in soils and shallow groundwater: model abstraction with modern tools

USDA-ARS?s Scientific Manuscript database

Vadose zone controls contaminant transport from the surface to groundwater, and modeling transport in vadose zone has become a burgeoning field. Exceedingly complex models of subsurface contaminant transport are often inefficient. Model abstraction is the methodology for reducing the complexity of a...

Overview of the magnetic signatures of the Palaeoproterozoic Rustenburg Layered Suite, Bushveld Complex, South Africa

USGS Publications Warehouse

Cole, Janine; Finn, Carol A.; Webb, Susan J.

2013-01-01

Aeromagnetic data clearly delineate the mafic rocks of the economically significant Bushveld Igneous Complex. This is mainly due to the abundance of magnetite in the Upper Zone of the Rustenburg Layered Suite of the Bushveld, but strongly remanently magnetised rocks in the Main Zone also contribute significantly in places. In addition to delineating the extent of the magnetic rocks in the complex, the magnetic anomalies also provide information about the dip and depth of these units. The presence of varying degrees of remanent magnetisation in most of the magnetic lithologies of the Rustenburg Layered Suite complicates the interpretation of the data. The combination of available regional and high resolution airborne magnetic data with published palaeomagnetic data reveals characteristic magnetic signatures associated with the different magnetic lithologies in the Rustenburg Layered Suite. As expected, the ferrogabbros of the Upper Zone cause the highest amplitude magnetic anomalies, but in places subtle features within the Main Zone can also be detected. A marker with strong remanent magnetisation located in the Main Zone close to the contact with the Upper Zone is responsible for very high amplitude negative anomalies in the southern parts of both the eastern and western lobes of the Bushveld Complex. Prominent anomalies are not necessarily related to a specific lithology, but can result from the interaction between anomalies caused by differently magnetised bodies.The magnetic data provided substantial information at different levels of detail, ranging from contacts between zones, and layering within zones, to magnetite pipes dykes and faults that can have an impact on mine planning. Finally, simple modelling of the magnetic data supports the concept of continuous mafic rocks between the western and eastern lobes.

Tectono-metamorphic evolution of high-P/T and low-P/T metamorphic rocks in the Tia Complex, southern New England Fold Belt, eastern Australia: Insights from K-Ar chronology

NASA Astrophysics Data System (ADS)

Fukui, Shiro; Tsujimori, Tatsuki; Watanabe, Teruo; Itaya, Tetsumaru

2012-10-01

The Tia Complex in the southern New England Fold Belt is a poly-metamorphosed Late Paleozoic accretionary complex. It consists mainly of high-P/low-T type pumpellyite-actinolite facies (rare blueschist facies) schists, phyllite and serpentinite (T = 300 °C and P = 5 kbar), and low-P/high-T type amphibolite facies schist and gneiss (T = 600 °C and P < 5 kbar) associated with granodioritic plutons (Tia granodiorite). White mica and biotite K-Ar ages distinguish Carboniferous subduction zone metamorphism and Permian granitic intrusions, respectively. The systematic K-Ar age mapping along a N-S traverse of the Tia Complex exhibits a gradual change. The white mica ages become younger from the lowest-grade zone (339 Ma) to the highest-grade zone (259 Ma). In contrast, Si content of muscovite changes drastically only in the highest-grade zone. The regional changes of white mica K-Ar ages and chemical compositions of micas indicate argon depletion from precursor high-P/low-T type phengitic white mica during the thermal overprinting and recrystallization by granitoids intrusions. Our new K-Ar ages and available geological data postulate a model of the eastward rollback of a subduction zone in Early Permian. The eastward shift of a subduction zone system and subsequent magmatic activities of high-Mg andesite and adakite might explain formation of S-type granitoids (Hillgrove suite) and coeval low-P/high-T type metamorphism in the Tia Complex.

"Virtual shear box" experiments of stress and slip cycling within a subduction interface mélange

NASA Astrophysics Data System (ADS)

Webber, Sam; Ellis, Susan; Fagereng, Åke

2018-04-01

What role does the progressive geometric evolution of subduction-related mélange shear zones play in the development of strain transients? We use a "virtual shear box" experiment, based on outcrop-scale observations from an ancient exhumed subduction interface - the Chrystalls Beach Complex (CBC), New Zealand - to constrain numerical models of slip processes within a meters-thick shear zone. The CBC is dominated by large, competent clasts surrounded by interconnected weak matrix. Under constant slip velocity boundary conditions, models of the CBC produce stress cycling behavior, accompanied by mixed brittle-viscous deformation. This occurs as a consequence of the reorganization of competent clasts, and the progressive development and breakdown of stress bridges as clasts mutually obstruct one another. Under constant shear stress boundary conditions, the models show periods of relative inactivity punctuated by aseismic episodic slip at rapid rates (meters per year). Such a process may contribute to the development of strain transients such as slow slip.

Multivariate temporal pattern analysis applied to the study of rat behavior in the elevated plus maze: methodological and conceptual highlights.

PubMed

Casarrubea, M; Magnusson, M S; Roy, V; Arabo, A; Sorbera, F; Santangelo, A; Faulisi, F; Crescimanno, G

2014-08-30

Aim of this article is to illustrate the application of a multivariate approach known as t-pattern analysis in the study of rat behavior in elevated plus maze. By means of this multivariate approach, significant relationships among behavioral events in the course of time can be described. Both quantitative and t-pattern analyses were utilized to analyze data obtained from fifteen male Wistar rats following a trial 1-trial 2 protocol. In trial 2, in comparison with the initial exposure, mean occurrences of behavioral elements performed in protected zones of the maze showed a significant increase counterbalanced by a significant decrease of mean occurrences of behavioral elements in unprotected zones. Multivariate t-pattern analysis, in trial 1, revealed the presence of 134 t-patterns of different composition. In trial 2, the temporal structure of behavior become more simple, being present only 32 different t-patterns. Behavioral strings and stripes (i.e. graphical representation of each t-pattern onset) of all t-patterns were presented both for trial 1 and trial 2 as well. Finally, percent distributions in the three zones of the maze show a clear-cut increase of t-patterns in closed arm and a significant reduction in the remaining zones. Results show that previous experience deeply modifies the temporal structure of rat behavior in the elevated plus maze. In addition, this article, by highlighting several conceptual, methodological and illustrative aspects on the utilization of t-pattern analysis, could represent a useful background to employ such a refined approach in the study of rat behavior in elevated plus maze. Copyright © 2014 Elsevier B.V. All rights reserved.

Computational Modeling of Interfacial Behaviors in Nanocomposite Materials

PubMed Central

Lin, Liqiang; Wang, Xiaodu; Zeng, Xiaowei

2017-01-01

Towards understanding the bulk material response in nanocomposites, an interfacial zone model was proposed to define a variety of material interface behaviors (e.g. brittle, ductile, rubber-like, elastic-perfectly plastic behavior etc.). It also has the capability to predict bulk material response though independently control of the interface properties (e.g. stiffness, strength, toughness). The mechanical response of granular nanocomposite (i.e. nacre) was investigated through modeling the “relatively soft” organic interface as an interfacial zone among “hard” mineral tablets and simulation results were compared with experimental measurements of stress-strain curves in tension and compression tests. Through modeling varies material interfaces, we found out that the bulk material response of granular nanocomposite was regulated by the interfacial behaviors. This interfacial zone model provides a possible numerical tool for qualitatively understanding of structure-property relationships through material interface design. PMID:28983123

Exploring the zone of anisotropy and broken symmetries in DNA-mediated nanoparticle crystallization.

PubMed

O'Brien, Matthew N; Girard, Martin; Lin, Hai-Xin; Millan, Jaime A; Olvera de la Cruz, Monica; Lee, Byeongdu; Mirkin, Chad A

2016-09-20

In this work, we present a joint experimental and molecular dynamics simulations effort to understand and map the crystallization behavior of polyhedral nanoparticles assembled via the interaction of DNA surface ligands. In these systems, we systematically investigated the interplay between the effects of particle core (via the particle symmetry and particle size) and ligands (via the ligand length) on crystallization behavior. This investigation revealed rich phase diagrams, previously unobserved phase transitions in polyhedral crystallization behavior, and an unexpected symmetry breaking in the ligand distribution on a particle surface. To understand these results, we introduce the concept of a zone of anisotropy, or the portion of the phase space where the anisotropy of the particle is preserved in the crystallization behavior. Through comparison of the zone of anisotropy for each particle we develop a foundational roadmap to guide future investigations.

Crystal growth and characterization of the CMR compound La 1.2(Sr,Ca) 1.8Mn 2O 7

NASA Astrophysics Data System (ADS)

Velázquez, M.; Haut, C.; Hennion, B.; Revcolevschi, A.

2000-12-01

High-quality centimeter-sized single crystals of La 1.2Sr 1.8- yCa yMn 2O 7 (0.0⩽ y⩽0.2) were successfully grown using a floating zone method associated with an image furnace. We present the growth conditions together with a characterization of the single crystals by means of optical and electron microscopy, EDX and ICP⧸AES analysis, DTA-TGA measurements and redox titration, X-ray powder diffraction, Laue X-ray back-reflection and neutron diffraction. We also stress the main aspects of the complex thermodynamical and kinetic behaviors of these compounds.

Microstructure and crystallographic preferred orientation of polycrystalline microgarnet aggregates developed during progressive creep, recovery, and grain boundary sliding

USGS Publications Warehouse

Massey, M.A.; Prior, D.J.; Moecher, D.P.

2011-01-01

Optical microscopy, electron probe microanalysis, and electron backscatter diffraction methods have been used to examine a broad range of garnet microstructures within a high strain zone that marks the western margin of a major transpression zone in the southern New England Appalachians. Garnet accommodated variable states of finite strain, expressed as low strain porphyroclasts (Type 1), high strain polycrystalline aggregates (Type 2), and transitional morphologies (Type 3) that range between these end members. Type 1 behaved as rigid porphyroclasts and is characterized by four concentric Ca growth zones. Type 2 help define foliation and lineation, are characterized by three Ca zones, and possess a consistent bulk crystallographic preferred orientation of (100) symmetrical to the tectonic fabric. Type 3 show variable degrees of porphyroclast associated with aggregate, where porphyroclasts display complex compositional zoning that corresponds to lattice distortion, low-angle boundaries, and subgrains, and aggregate CPO mimics porphyroclast orientation. All aggregates accommodated a significant proportion of greenschist facies deformation through grain boundary sliding, grain rotation and impingement, and pressure solution, which lead to a cohesive behavior and overall strain hardening of the aggregates. The characteristic CPO could not have been developed in this manner, and was the result of an older phase of partitioned amphibolite facies dislocation creep, recovery including chemical segregation, and recrystallization of porphyroclasts. This study demonstrates the significance of strain accommodation within garnet and its affect on composition under a range of PT conditions, and emphasizes the importance of utilizing EBSD methods with studies that rely upon a sound understanding of garnet. ?? 2010 Elsevier Ltd.

Complex magnetic differentiation of cobalts in Na x CoO2 with 22 K Néel temperature

NASA Astrophysics Data System (ADS)

Mukhamedshin, I. R.; Gilmutdinov, I. F.; Salosin, M. A.; Alloul, H.

2014-06-01

Single crystals of sodium cobaltates Na x CoO2 with x ≈ 0.8 were grown by the floating zone technique. Using electrochemical Na de-intercalation method we reduced the sodium content in the as-grown crystals down to pure phase with 22 K Néel temperature and x ≈ 0.77. The 59Co NMR study in the paramagnetic state of the T N = 22 K phase permitted us to evidence that at least 6 Co sites are differentiated. They could be separated by their magnetic behavior into three types: a single site with cobalt close to non-magnetic Co3+, two sites with the most magnetic cobalts in the system, and the remaining three sites displaying an intermediate behavior. This unusual magnetic differentiation calls for more detailed NMR experiments on our well characterized samples.

In vitro synchrotron-based radiography of micro-gap formation at the implant-abutment interface of two-piece dental implants.

PubMed

Rack, A; Rack, T; Stiller, M; Riesemeier, H; Zabler, S; Nelson, K

2010-03-01

Micro-gap formation at the implant-abutment interface of two-piece dental implants was investigated in vitro using high-resolution radiography in combination with hard X-ray synchrotron radiation. Images were taken with the specimen under different mechanical loads of up to 100 N. The aim of this investigation was to prove the existence of micro-gaps for implants with conical connections as well as to study the mechanical behavior of the mating zone of conical implants during loading. Synchrotron-based radiography in comparison with classical laboratory radiography yields high spatial resolution in combination with high contrast even when exploiting micro-sized features in highly attenuating objects. The first illustration of a micro-gap which was previously indistinguishable by laboratory methods underlines that the complex micro-mechanical behavior of implants requires further in vitro investigations where synchrotron-based micro-imaging is one of the prerequisites.

Deciphering igneous and metamorphic events in high-grade rocks of the Wilmington complex, Delaware: Morphology, cathodoluminescence and backscattered electron zoning, and SHRIMP U-Pb geochronology of zircon and monazite

USGS Publications Warehouse

Aleinikoff, J.N.; Schenck, W.S.; Plank, M.O.; Srogi, L.A.; Fanning, C.M.; Kamo, S.L.; Bosbyshell, H.

2006-01-01

High-grade rocks of the Wilmington Complex, northern Delaware and adjacent Maryland and Pennsylvania, contain morphologically complex zircons that formed through both igneous and metamorphic processes during the development of an island-arc complex and suturing of the arc to Laurentia. The arc complex has been divided into several members, the protoliths of which include both intrusive and extrusive rocks. Metasedimentary rocks are interlayered with the complex and are believed to be the infrastructure upon which the arc was built. In the Wilmingto n Complex rocks, both igneous and metamorphic zircons occur as elongate and equant forms. Chemical zoning, shown by cathodoluminescence (CL), includes both concentric, oscillatory patterns, indicative of igneous origin, and patchwork and sector patterns, suggestive of metamorphic growth. Metamorphic monazites are chemically homogeneous, or show oscillatory or spotted chemical zoning in backscattered electron images. U-Pb geochronology by sensitive high resolution ion microprobe (SHRIMP) was used to date complexly zoned zircon and monazite. All but one member of the Wilmington Complex crystallized in the Ordovician between ca. 475 and 485 Ma; these rocks were intruded by a suite of gabbro-to-granite plutonic rocks at 434 ?? Ma. Detrital zircons in metavolcanic and metasedimentary units were derived predominantly from 0.9 to 1.4 Ga (Grenvillian) basement, presumably of Laurentian origin. Amphibolite to granulite facies metamorphism of the Wilmington Complex, recorded by ages of metamorphic zircon (428 ?? 4 and 432 ?? 6 Ma) and monazite (429 ?? 2 and 426 ?? 3 Ma), occurred contemporaneously with emplacement of the younger plutonic rocks. On the basis of varying CL zoning patterns and external morphologies, metamorphic zircons formed by different processes (presumably controlled by rock chemistry) at slightly different times and temperatures during prograde metamorphism. In addition, at least three other thermal episodes are recorded by monazite growth at 447 ?? 4, 411 ?? 3, and 398 ?? 3 Ma. ?? 2006 Geological Society of America.

Frictional heterogeneities on carbonate-bearing normal faults: Insights from the Monte Maggio Fault, Italy

NASA Astrophysics Data System (ADS)

Carpenter, B. M.; Scuderi, M. M.; Collettini, C.; Marone, C.

2014-12-01

Observations of heterogeneous and complex fault slip are often attributed to the complexity of fault structure and/or spatial heterogeneity of fault frictional behavior. Such complex slip patterns have been observed for earthquakes on normal faults throughout central Italy, where many of the Mw 6 to 7 earthquakes in the Apennines nucleate at depths where the lithology is dominated by carbonate rocks. To explore the relationship between fault structure and heterogeneous frictional properties, we studied the exhumed Monte Maggio Fault, located in the northern Apennines. We collected intact specimens of the fault zone, including the principal slip surface and hanging wall cataclasite, and performed experiments at a normal stress of 10 MPa under saturated conditions. Experiments designed to reactivate slip between the cemented principal slip surface and cataclasite show a 3 MPa stress drop as the fault surface fails, then velocity-neutral frictional behavior and significant frictional healing. Overall, our results suggest that (1) earthquakes may readily nucleate in areas of the fault where the slip surface separates massive limestone and are likely to propagate in areas where fault gouge is in contact with the slip surface; (2) postseismic slip is more likely to occur in areas of the fault where gouge is present; and (3) high rates of frictional healing and low creep relaxation observed between solid fault surfaces could lead to significant aftershocks in areas of low stress drop.

A Benchmarking setup for Coupled Earthquake Cycle - Dynamic Rupture - Tsunami Simulations

NASA Astrophysics Data System (ADS)

Behrens, Joern; Bader, Michael; van Dinther, Ylona; Gabriel, Alice-Agnes; Madden, Elizabeth H.; Ulrich, Thomas; Uphoff, Carsten; Vater, Stefan; Wollherr, Stephanie; van Zelst, Iris

2017-04-01

We developed a simulation framework for coupled physics-based earthquake rupture generation with tsunami propagation and inundation on a simplified subduction zone system for the project "Advanced Simulation of Coupled Earthquake and Tsunami Events" (ASCETE, funded by the Volkswagen Foundation). Here, we present a benchmarking setup that can be used for complex rupture models. The workflow begins with a 2D seismo-thermo-mechanical earthquake cycle model representing long term deformation along a planar, shallowly dipping subduction zone interface. Slip instabilities that approximate earthquakes arise spontaneously along the subduction zone interface in this model. The absolute stress field and material properties for a single slip event are used as initial conditions for a dynamic earthquake rupture model.The rupture simulation is performed with SeisSol, which uses an ADER discontinuous Galerkin discretization scheme with an unstructured tetrahedral mesh. The seafloor displacements resulting from this rupture are transferred to the tsunami model with a simple coastal run-up profile. An adaptive mesh discretizing the shallow water equations with a Runge-Kutta discontinuous Galerkin (RKDG) scheme subsequently allows for an accurate and efficient representation of the tsunami evolution and inundation at the coast. This workflow allows for evaluation of how the rupture behavior affects the hydrodynamic wave propagation and coastal inundation. We present coupled results for differing earthquake scenarios. Examples include megathrust only ruptures versus ruptures with splay fault branching off the megathrust near the surface. Coupling to the tsunami simulation component is performed either dynamically (time dependent) or statically, resulting in differing tsunami wave and inundation behavior. The simplified topographical setup allows for systematic parameter studies and reproducible physical studies.

Middle to Late Devonian-Carboniferous collapse basins on the Finnmark Platform and in the southwesternmost Nordkapp basin, SW Barents Sea

NASA Astrophysics Data System (ADS)

Koehl, Jean-Baptiste P.; Bergh, Steffen G.; Henningsen, Tormod; Faleide, Jan Inge

2018-03-01

The SW Barents Sea margin experienced a pulse of extensional deformation in the Middle-Late Devonian through the Carboniferous, after the Caledonian Orogeny terminated. These events marked the initial stages of formation of major offshore basins such as the Hammerfest and Nordkapp basins. We mapped and analyzed three major fault complexes, (i) the Måsøy Fault Complex, (ii) the Rolvsøya fault, and (iii) the Troms-Finnmark Fault Complex. We discuss the formation of the Måsøy Fault Complex as a possible extensional splay of an overall NE-SW-trending, NW-dipping, basement-seated Caledonian shear zone, the Sørøya-Ingøya shear zone, which was partly inverted during the collapse of the Caledonides and accommodated top-NW normal displacement in Middle to Late Devonian-Carboniferous times. The Troms-Finnmark Fault Complex displays a zigzag-shaped pattern of NNE-SSW- and ENE-WSW-trending extensional faults before it terminates to the north as a WNW-ESE-trending, NE-dipping normal fault that separates the southwesternmost Nordkapp basin in the northeast from the western Finnmark Platform and the Gjesvær Low in the southwest. The WNW-ESE-trending, margin-oblique segment of the Troms-Finnmark Fault Complex is considered to represent the offshore prolongation of a major Neoproterozoic fault complex, the Trollfjorden-Komagelva Fault Zone, which is made of WNW-ESE-trending, subvertical faults that crop out on the island of Magerøya in NW Finnmark. Our results suggest that the Trollfjorden-Komagelva Fault Zone dies out to the northwest before reaching the western Finnmark Platform. We propose an alternative model for the origin of the WNW-ESE-trending segment of the Troms-Finnmark Fault Complex as a possible hard-linked, accommodation cross fault that developed along the Sørøy-Ingøya shear zone. This brittle fault decoupled the western Finnmark Platform from the southwesternmost Nordkapp basin and merged with the Måsøy Fault Complex in Carboniferous times. Seismic data over the Gjesvær Low and southwesternmost Nordkapp basin show that the low-gravity anomaly observed in these areas may result from the presence of Middle to Upper Devonian sedimentary units resembling those in Middle Devonian, spoon-shaped, late- to post-orogenic collapse basins in western and mid-Norway. We propose a model for the formation of the southwesternmost Nordkapp basin and its counterpart Devonian basin in the Gjesvær Low by exhumation of narrow, ENE-WSW- to NE-SW-trending basement ridges along a bowed portion of the Sørøya-Ingøya shear zone in the Middle to Late Devonian-early Carboniferous. Exhumation may have involved part of a large-scale metamorphic core complex that potentially included the Lofoten Ridge, the West Troms Basement Complex and the Norsel High. Finally, we argue that the Sørøya-Ingøya shear zone truncated and decapitated the Trollfjorden-Komagelva Fault Zone during the Caledonian Orogeny and that the western continuation of the Trollfjorden-Komagelva Fault Zone was mostly eroded and potentially partly preserved in basement highs in the SW Barents Sea.

Analysis of dynamic cantilever behavior in tapping mode atomic force microscopy.

PubMed

Deng, Wenqi; Zhang, Guang-Ming; Murphy, Mark F; Lilley, Francis; Harvey, David M; Burton, David R

2015-10-01

Tapping mode atomic force microscopy (AFM) provides phase images in addition to height and amplitude images. Although the behavior of tapping mode AFM has been investigated using mathematical modeling, comprehensive understanding of the behavior of tapping mode AFM still poses a significant challenge to the AFM community, involving issues such as the correct interpretation of the phase images. In this paper, the cantilever's dynamic behavior in tapping mode AFM is studied through a three dimensional finite element method. The cantilever's dynamic displacement responses are firstly obtained via simulation under different tip-sample separations, and for different tip-sample interaction forces, such as elastic force, adhesion force, viscosity force, and the van der Waals force, which correspond to the cantilever's action upon various different representative computer-generated test samples. Simulated results show that the dynamic cantilever displacement response can be divided into three zones: a free vibration zone, a transition zone, and a contact vibration zone. Phase trajectory, phase shift, transition time, pseudo stable amplitude, and frequency changes are then analyzed from the dynamic displacement responses that are obtained. Finally, experiments are carried out on a real AFM system to support the findings of the simulations. © 2015 Wiley Periodicals, Inc.

Work zone safety : physical and behavioral barriers in accident prevention.

DOT National Transportation Integrated Search

2014-05-01

This report discusses the usefulness of creating a work zone traffic safety culture as a methodology to improve the overall : safety of both work zone personnel and the traveling public in Missouri. As part of this research, the existing MoDOT : Work...

Work zone safety : physical and behavioral barriers in accident prevention.

DOT National Transportation Integrated Search

2014-05-01

This report discusses the usefulness of creating a work zone traffic safety culture as a methodology to improve the overall : safety of both work zone personnel and the traveling public in Missouri. As part of this research, the existing MoDOT : w : ...

THE DOE COMPLEX-WIDE VADOSE ZONE SCIENCE AND TECHNOLOGY ROADMAP: CHARACTERIZATION MODELING AND SIMULATION OF SUBSURFACE CONTAMINANT FATE AND TRANSPORT

EPA Science Inventory

The Idaho National Engineering & Environmental Lab (INEEL) was charged by DOE EM to develop a complex-wide science and technology roadmap for the characterization, modeling and simulation of the fate and transport of contamination in the vadose zone. Various types of hazardous, r...

Geophysical-geological studies of possible extensions of the New Madrid Fault Zone. Annual report, 1982. Vol. 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hinze, W.J.; Braile, L.W.; Keller, G.R.

1983-05-01

An integrated geophysical/geologic program is being conducted to evaluate the rift complex hypothesis as an explanation for the earthquake activity in the New Madrid Seismic Zone and its extensions, to refine our knowledge of the rift complex, and to investigate the possible northern extensions of the New Madrid Fault Zone, especially its possible connection to the Anna, Ohio seismogenic region. Drillhole basement lithologies are being investigated to aid in tectonic analysis and geophysical interpretation, particularly in the Anna, Ohio area. Gravity and magnetic modeling combined with limited seismic reflection studies in southwest Indiana are interpreted as confirming speculation that anmore » arm of the New Madrid Rift Complex extends northeasterly into Indiana. The geologic and geophysical evidence confirm that the basement lithology in the Anna, Ohio area is highly variable reflecting a complex geologic history. The data indicate that as many as three major Late Precambrian tectonic features intersect within the basement of the Anna area suggesting that the seismicity may be related to basement zones of weakness.« less

Geoelectrical characterisation of basement aquifers: the case of Iberekodo, southwestern Nigeria

NASA Astrophysics Data System (ADS)

Aizebeokhai, Ahzegbobor P.; Oyeyemi, Kehinde D.

2018-03-01

Basement aquifers, which occur within the weathered and fractured zones of crystalline bedrocks, are important groundwater resources in tropical and subtropical regions. The development of basement aquifers is complex owing to their high spatial variability. Geophysical techniques are used to obtain information about the hydrologic characteristics of the weathered and fractured zones of the crystalline basement rocks, which relates to the occurrence of groundwater in the zones. The spatial distributions of these hydrologic characteristics are then used to map the spatial variability of the basement aquifers. Thus, knowledge of the spatial variability of basement aquifers is useful in siting wells and boreholes for optimal and perennial yield. Geoelectrical resistivity is one of the most widely used geophysical methods for assessing the spatial variability of the weathered and fractured zones in groundwater exploration efforts in basement complex terrains. The presented study focuses on combining vertical electrical sounding with two-dimensional (2D) geoelectrical resistivity imaging to characterise the weathered and fractured zones in a crystalline basement complex terrain in southwestern Nigeria. The basement aquifer was delineated, and the nature, extent and spatial variability of the delineated basement aquifer were assessed based on the spatial variability of the weathered and fractured zones. The study shows that a multiple-gradient array for 2D resistivity imaging is sensitive to vertical and near-surface stratigraphic features, which have hydrological implications. The integration of resistivity sounding with 2D geoelectrical resistivity imaging is efficient and enhances near-surface characterisation in basement complex terrain.

Complex fragmentation and silicification structures in fault zones: quartz crystallization and repeated fragmentation in the Rusey fault zone (Cornwall/UK)

NASA Astrophysics Data System (ADS)

Yilmaz, Tim I.; Blenkinsop, Tom; Duschl, Florian; Kruhl, Jörn H.

2015-04-01

Silicified fault rocks typically show structures resulting from various stages of fragmentation and quartz crystallization. Both processes interact episodically and result in complex structures on various scales, which require a wide spectrum of analysis tools. Based on field and microstructural data, the spatial-temporal connection between deformation, quartz crystallization and fluid and material flow along the Rusey fault zone was investigated. The fault can be examined in detail in three dimensions on the north Cornwall coast, UK. It occurs within Carboniferous sandstones, siltstones, mudstones and slates of the Culm basin, and is likely to have had a long history. The fault rocks described here formed during the younger events, possibly due to Tertiary strike-slip reactivation. Frequent fragmentation, flow and crystallization events and their interaction led to various generations of complex-structured quartz units, among them quartz-mantled and partly silicified wall-rock fragments, microcrystalline quartz masses of different compositions and structures, and quartz vein patterns of various ages. Lobate boundaries of quartz masses indicate viscous flow. Fragments are separated by quartz infill, which contains cm-sized open pores, in which quartz crystals have pyramidal terminations. Based on frequent occurrence of feathery textures and the infill geometry, quartz crystallization from chalcedony appears likely, and an origin from silica gel is discussed. Fragmentation structures are generally fractal. This allows differentiation between various processes, such as corrosive wear, wear abrasion and hydraulic brecciation. Material transport along the brittle shear zone, and displacement of the wall-rocks, were at least partly governed by flow of mobile fluid-quartz-particle suspensions. The complex meso- to microstructures were generated by repeated processes of fragmentation, quartz precipitation and grain growth. In general, the brittle Rusey fault zone represents a zone of multiple fragmentation, fluid flow, crystallization and quartz dissolution and precipitation, and is regarded as key example of large-scale cyclic interaction of these processes. The geological evidence of interactions between processes implies that feedbacks and highly non-linear mechanical behaviour generated the complex meso- and microstructures. The fault zone rheology may also therefore have been complex.

The human thermoneutral and thermal comfort zones: Thermal comfort in your own skin blood flow.

PubMed

Schlader, Zachary J

2015-01-01

Human thermoregulation is achieved via autonomic and behavioral responses. Autonomic responses involve 2 synchronous 'components'. One counteracts large thermal perturbations, eliciting robust heat loss or gain (i.e., sweating or shivering). The other fends off smaller insults, relying solely on changes in sensible heat exchange (i.e., skin blood flow). This sensible component occurs within the thermoneutral zone [i.e., the ambient temperature range in which temperature regulation is achieved only by sensible heat transfer, without regulatory increases in metabolic heat production (e.g., shivering) or evaporative heat loss (e.g., sweating)].(1) The combination of behavior and sensible heat exchange permits a range of conditions that are deemed thermally comfortable, which is defined as the thermal comfort zone.(1) Notably, we spend the majority of our lives within the thermoneutral and thermal comfort zones. It is only when we are unable to stay within these zones that deleterious health and safety outcomes can occur (i.e., hypo- or hyperthermia). Oddly, although the thermoneutral zone and thermal preference (a concept similar to the thermal comfort zone) has been extensively studied in non-human animals, our understanding of human thermoregulation within the thermoneutral and thermal comfort zones remains rather crude.

Neoproterozoic Structural Evolution of the NE-trending 620-540 Ma Ad-Damm Shear Zone, Arabian Shield, Saudi Arabia

NASA Astrophysics Data System (ADS)

Hamimi, Z.; El-Sawy, E. K.; El-Fakharan, A. S.; Shujoon, A.; Matsah, M.; El-Shafei, M.

2012-04-01

Ad-Damm Shear Zone (ASZ) is a NE-trending fault zone separating Jeddah and Asir tectonostratigraphic terranes in the Neoproterozoic juvenile Arabian Shield. ASZ extends ~380 km, with an average width ~2-3 km, from the eye-catching Ruwah Fault Zone in the eastern shield to the Red Sea Coastal plain. It was believed to be one of the conjugate shears of the NW- to NNW- trending sinistral Najd Shear System based on noteworthy dextral shear criteria recorded within the 620 Ma sheared granites of Numan Complex, as well as right-lateral offsets within quartz veins and dikes transected by the shear zone. The present study is an integrated field-based structural analysis and remote sensing. We utilized the ASTER data for lithologic discrimination and automatic structural lineament extraction and analysis of the Neoproterozoic basement lithologies encountered along and within the vicinity of ASZ. Various false color composite images were generated and evaluated for lithological mapping and structural lineaments. The obtained map was analyzed using GIS techniques to interpret the behavior of the existing lineaments and their spatial distribution. Based on the results of the ASTER data, two significant areas; around Bir Ad-Damm and to the south of Wadi Numan, are selected for detailed field investigation. Shear-sense indicators and overprinting relations clearly show a complicated Neoproterozoic history of ASZ, involving at least three deformations: (1) an early attenuated NE-SW sinistral shearing; followed by (2) a SE-directed thrusting phase resulted in the formation SE-verging thrusts and associated thrust-related folds; and (3) late NE-SW intensive dextral transcurrent shearing played a significant role in the creation of mesoscopic shear-zone related folds, particularly in the area near Bir Ad-Damm. Such deformation history demonstrates the same episode of Neoproterozoic deformation exhibited in the NE-trending shear zones in the Arabian-Nubian Shield (ANS).

Constraints on the Amount of deeply subducted Water from numerical Models in comparison with natural Samples

NASA Astrophysics Data System (ADS)

Konrad-Schmolke, M.; Halama, R.

2014-12-01

The subduction of hydrated slab mantle to beyond-arc depths is the most important and yet weakly constrained factor in the quantification of the Earth's deep geologic water cycle. During subduction of hydrated oceanic lithosphere, dehydration reactions in the downgoing plate lead to a partitioning of water between upper and lower plate. Water retained in the slab is recycled into the mantle where it controls its rheology and thus plate tectonic velocities. Hence, quantification of the water partitioning in subduction zones is crucial for the understanding of mass transfer between the Earth's surface and the mantle. Combined thermomechanical and thermodynamic models yield quantitative constraints on the water cycle in subduction zones, but unless model results can be linked to natural observations, the reliability of such models remains speculative. We present combined thermomechanical, thermodynamic and geochemical models of active and paleo-subduction zones, whose results can be tested with independent geochemical features in natural rocks. In active subduction zones, evidence for the validity of our model comes from the agreement between modeled and observed across-arc trends of boron concentrations and isotopic compositions in arc volcanic rocks. In the Kamchatkan subduction zone, for example, the model successfully predicts complex geochemical patterns and the spatial distribution of arc volcanoes. In paleo-subduction zones (e.g. Western Gneiss Region and Western Alps), constraints on the water budget and dehydration behavior of the subducting slab come from trace element zoning patterns in ultra-high pressure (UHP) garnets. Distinct enrichments of Cr, Ni and REE in the UHP zones of the garnets can be reconciled by our models that predict intense rehydration and trace element re-enrichment of the eclogites at UHP conditions by fluids released from the underlying slab mantle. Models of present-day subduction zones indicate the presence of 2.5-6 wt.% of water within the uppermost 15 km of the subducted slab mantle. Depending on hydration depth, between 25 and 90% of this water is recycled into the deeper mantle. The Lower Devonian example from the Western Gneiss Region indicates that subduction of water into the Earth's deeper mantle is an active process at least since the middle Paleozoic.

Kinematic evolution of the Maacama Fault Zone, Northern California Coast Ranges

NASA Astrophysics Data System (ADS)

Schroeder, Rick D.

The Maacama Fault Zone (MFZ) is a major component of the Pacific-North American transform boundary in northern California, and its distribution of deformation and kinematic evolution defines that of a young continental transform boundary. The USGS Quaternary database (2010) currently defines the MFZ as a relatively narrow fault zone; however, a cluster analysis of microearthquakes beneath the MFZ defines a wider fault zone, composed of multiple seismogenically active faults. The surface projection of best-fit tabular zones through foci clusters correlates with previously interpreted faults that were assumed inactive. New investigations further delineate faults within the MFZ based on geomorphic features and shallow resistivity surveys, and these faults are interpreted to be part of several active pull-apart fault systems. The location of faults and changes in their geometry in relation to geomorphic features, indicate >8 km of cumulative dextral displacement across the eastern portion of the MFZ at Little Lake Valley, which includes other smaller offsets on fault strands in the valley. Some faults within the MFZ have geometries consistent with reactivated subduction-related reverse faults, and project near outcrops of pre-existing faults, filled with mechanically weak minerals. The mechanical behavior of fault zones is influenced by the spatial distribution and abundance of mechanically weak lithologies and mineralogies within the heterogeneous Franciscan melange that the MFZ displaces. This heterogeneity is characterized near Little Lake Valley (LLV) using remotely sensed data, field mapping, and wellbore data, and is composed of 2--5 km diameter disk-shaped coherent blocks that can be competent and resist deformation. Coherent blocks and the melange that surrounds them are the source for altered minerals that fill portions of fault zones. Mechanically weak minerals in pre-existing fault zones, identified by X-ray diffraction and electron microprobe analyses, are interpreted as a major reason for complex configurations of clusters of microearthquakes and zones of aseismic creep along the MFZ. Analysis of the kinematics of the MFZ and the distribution of its deformation is important because it improves the understanding of young stages of transform system evolution, which has implications that affect issues ranging from seismic hazard to petroleum and minerals exploration around the world.

The Northwest Geysers EGS Demonstration Project, California – Part 2: Modeling and interpretation

DOE PAGES

Rutqvist, Jonny; Jeanne, Pierre; Dobson, Patrick F.; ...

2015-09-02

In this paper, we summarize the results of coupled thermal, hydraulic, and mechanical (THM) modeling in support of the Northwest Geysers EGS Demonstration Project, which aims at enhancing production from a known High Temperature Reservoir (HTR) (280–400 °C) located under the conventional (240 °C) geothermal steam reservoir. The THM modeling was conducted to investigate geomechanical effects of cold-water injection during the stimulation of the EGS, first to predict the extent of the stimulation zone for a given injection schedule, and then to conduct interpretive analyses of the actual stimulation. By using a calibrated THM model based on historic injection and microseismic datamore » at a nearby well, we could reasonably predict the extent of the stimulation zone around the injection well, at least for the first few months of injection. However, observed microseismic evolution and pressure responses over the one-year stimulation-injection revealed more heterogeneous behavior as a result of more complex geology, including a network of shear zones. Therefore, for an interpretive analysis of the one-year stimulation campaign, we included two sets of vertical shear zones within the model; a set of more permeable NW-striking shear zones and a set of less permeable NE-striking shear zones. Our modeling indicates that the microseismic events in this system are related to shear reactivation of pre-existing fractures, triggered by the combined effects of injection-induced cooling around the injection well and rapid (but small) changes in steam pressure as far as a kilometer from the injection well. Overall, the integrated monitoring and modeling of microseismicity, ground surface deformations, reservoir pressure, fluid chemical composition, and seismic tomography depict an EGS system hydraulically bounded by some of the NE-striking low permeability shear zones, with the more permeable NW-striking shear zone providing liquid flow paths for stimulation deep (several kilometers) down into the HTR. The mo deling indicates that a significant mechanical degradation (damage) inferred from seismic tomography, and potential changes in fracture porosity inferred from cross-well pressure responses, are related to shear rupture in the stimulation zone driven by both pressure and cooling effects.« less

The Northwest Geysers EGS Demonstration Project, California – Part 2: Modeling and interpretation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rutqvist, Jonny; Jeanne, Pierre; Dobson, Patrick F.

In this paper, we summarize the results of coupled thermal, hydraulic, and mechanical (THM) modeling in support of the Northwest Geysers EGS Demonstration Project, which aims at enhancing production from a known High Temperature Reservoir (HTR) (280–400 °C) located under the conventional (240 °C) geothermal steam reservoir. The THM modeling was conducted to investigate geomechanical effects of cold-water injection during the stimulation of the EGS, first to predict the extent of the stimulation zone for a given injection schedule, and then to conduct interpretive analyses of the actual stimulation. By using a calibrated THM model based on historic injection and microseismic datamore » at a nearby well, we could reasonably predict the extent of the stimulation zone around the injection well, at least for the first few months of injection. However, observed microseismic evolution and pressure responses over the one-year stimulation-injection revealed more heterogeneous behavior as a result of more complex geology, including a network of shear zones. Therefore, for an interpretive analysis of the one-year stimulation campaign, we included two sets of vertical shear zones within the model; a set of more permeable NW-striking shear zones and a set of less permeable NE-striking shear zones. Our modeling indicates that the microseismic events in this system are related to shear reactivation of pre-existing fractures, triggered by the combined effects of injection-induced cooling around the injection well and rapid (but small) changes in steam pressure as far as a kilometer from the injection well. Overall, the integrated monitoring and modeling of microseismicity, ground surface deformations, reservoir pressure, fluid chemical composition, and seismic tomography depict an EGS system hydraulically bounded by some of the NE-striking low permeability shear zones, with the more permeable NW-striking shear zone providing liquid flow paths for stimulation deep (several kilometers) down into the HTR. The mo deling indicates that a significant mechanical degradation (damage) inferred from seismic tomography, and potential changes in fracture porosity inferred from cross-well pressure responses, are related to shear rupture in the stimulation zone driven by both pressure and cooling effects.« less

Hippocampal awake replay in fear memory retrieval

PubMed Central

Wu, Chun-Ting; Haggerty, Daniel; Kemere, Caleb; Ji, Daoyun

2017-01-01

Hippocampal place cells are key to episodic memories. How these cells participate in memory retrieval remains unclear. Here, after rats acquired a fear memory by receiving mild foot-shocks at a shock zone of a track, we analyzed place cells when the animals were placed back to the track and displayed an apparent memory retrieval behavior: avoidance of the shock zone. We found that place cells representing the shock zone were reactivated, despite the fact that the animals did not enter the shock zone. This reactivation occurred in ripple-associated awake replay of place cell sequences encoding the paths from the animal’s current positions to the shock zone, but not in place cell sequences within individual cycles of theta oscillation. The result reveals a specific place cell pattern underlying the inhibitory avoidance behavior and provides strong evidence for the involvement of awake replay in fear memory retrieval. PMID:28218916

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone: U TRANSPORT IN A GROUNDWATER-SURFACE WATER TRANSITION ZONE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zachara, John M.; Chen, Xingyuan; Murray, Chris

A tightly spaced well-field within a groundwater uranium (U) plume in the groundwater-surface water transition zone was monitored for a three year period for groundwater elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from mountain snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time series trendsmore » for Uaq and SpC were complex and displayed large temporal well-to well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common temporal behaviors resulting from the intrusion dynamics of river water and the location of source terms. Concentration hot spots were observed in groundwater that varied in location with increasing water table elevation. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While uranium time-series concentration trends varied significantly from year to year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of the river water intrusion event.« less

Structural Mapping Along the Central San Andreas Fault-zone Using Airborne Electromagnetics

NASA Astrophysics Data System (ADS)

Zamudio, K. D.; Bedrosian, P.; Ball, L. B.

2017-12-01

Investigations of active fault zones typically focus on either surface expressions or the associated seismogenic zones. However, the largely aseismic upper kilometer can hold significant insight into fault-zone architecture, strain partitioning, and fault-zone permeability. Geophysical imaging of the first kilometer provides a link between surface fault mapping and seismically-defined fault zones and is particularly important in geologically complex regions with limited surface exposure. Additionally, near surface imaging can provide insight into the impact of faulting on the hydrogeology of the critical zone. Airborne electromagnetic (AEM) methods offer a unique opportunity to collect a spatially-large, detailed dataset in a matter of days, and are used to constrain subsurface resistivity to depths of 500 meters or more. We present initial results from an AEM survey flown over a 60 kilometer long segment of the central San Andreas Fault (SAF). The survey is centered near Parkfield, California, the site of the SAFOD drillhole, which marks the transition between a creeping fault segment to the north and a locked zone to the south. Cross sections with a depth of investigation up to approximately 500 meters highlight the complex Tertiary and Mesozoic geology that is dismembered by the SAF system. Numerous fault-parallel structures are imaged across a more than 10 kilometer wide zone centered on the surface trace. Many of these features can be related to faults and folds within Plio-Miocene sedimentary rocks found on both sides of the fault. Northeast of the fault, rocks of the Mesozoic Franciscan and Great Valley complexes are extremely heterogeneous, with highly resistive volcanic rocks within a more conductive background. The upper 300 meters of a prominent fault-zone conductor, previously imaged to 1-3 kilometers depth by magnetotellurics, is restricted to a 20 kilometer long segment of the fault, but is up to 4 kilometers wide in places. Elevated fault-zone conductivity may be related to damage within the fault zone, Miocene marine shales, or some combination of the two.

Hypoxia interface behavior of the ctenophore Mnemiopsis leidyi

NASA Astrophysics Data System (ADS)

Gentry, L. A.; Moss, A.

2016-02-01

The ctenophore Mnemiopsis leidyi is most widely known as a destructive invasive species of the Black and Caspian seas. Ctenophores are also found endemically in oceans worldwide, where their low oxygen tolerances allow many of them to use hypoxic zones to escape predation and hunt disabled prey. Ctenophores have also been observed in the wild and laboratory conditions associating with the interface of hypoxic and normoxic waters, allowing them to feed on the organisms found there. In order to test the ability of M. leidyi to find oxygen interfaces, a 10 cm diameter X 60 cm tall cylindrical tank was designed with a sharp oxycline (<1cm) in the middle, stabilized by a 1 ppt salinity difference. The hypoxic water was produced by nitrogen bubbling prior to the experiment. We found that animals introduced to the tank under oxycline conditions increased their time spent at the interface by over nearly five-fold versus those in a fully normoxic or hypoxic water. These preliminary results would indicate that M. leidyi preferentially associates with the interfaces of hypoxic zones. As human effects such as overfishing, nutrient enrichment of coastal waters, and invasive introduction continue to rise, the complex interactions of these animals and hypoxic zones will become increasingly important to planktonic and pelagic ecosystems worldwide.

Analysis of an anisotropic coastal aquifer system using variable-density flow and solute transport simulation

USGS Publications Warehouse

Souza, W.R.; Voss, C.I.

1987-01-01

The groundwater system in southern Oahu, Hawaii consists of a thick, areally extensive freshwater lens overlying a zone of transition to a thick saltwater body. This system is analyzed in cross section with a variable-density groundwater flow and solute transport model on a regional scale. The simulation is difficult, because the coastal aquifer system has a saltwater transition zone that is broadly dispersed near the discharge area, but is very sharply defined inland. Steady-state simulation analysis of the transition zone in the layered basalt aquifer of southern Oahu indicates that a small transverse dispersivity is characteristic of horizontal regional flow. Further, in this system flow is generally parallel to isochlors and steady-state behavior is insensitive to the longitudinal dispersivity. Parameter analysis identifies that only six parameters control the complex hydraulics of the system: horizontal and vertical hydraulic conductivity of the basalt aquifer; hydraulic conductivity of the confining "caprock" layer; leakance below the caprock; specific yield; and aquifer matrix compressibility. The best-fitting models indicate the horizontal hydraulic conductivity is significantly greater than the vertical hydraulic conductivity. These models give values for specific yield and aquifer compressibility which imply a considerable degree of compressive storage in the water table aquifer. ?? 1987.

Development and application of a screening model for evaluating bioenhanced dissolution in DNAPL source zones

NASA Astrophysics Data System (ADS)

Phelan, Thomas J.; Abriola, Linda M.; Gibson, Jenny L.; Smits, Kathleen M.; Christ, John A.

2015-12-01

In-situ bioremediation, a widely applied treatment technology for source zones contaminated with dense non-aqueous phase liquids (DNAPLs), has proven economical and reasonably efficient for long-term management of contaminated sites. Successful application of this remedial technology, however, requires an understanding of the complex interaction of transport, mass transfer, and biotransformation processes. The bioenhancement factor, which represents the ratio of DNAPL mass transfer under microbially active conditions to that which would occur under abiotic conditions, is commonly used to quantify the effectiveness of a particular bioremediation remedy. To date, little research has been directed towards the development and validation of methods to predict bioenhancement factors under conditions representative of real sites. This work extends an existing, first-order, bioenhancement factor expression to systems with zero-order and Monod kinetics, representative of many source-zone scenarios. The utility of this model for predicting the bioenhancement factor for previously published laboratory and field experiments is evaluated. This evaluation demonstrates the applicability of these simple bioenhancement factors for preliminary experimental design and analysis, and for assessment of dissolution enhancement in ganglia-contaminated source zones. For ease of application, a set of nomographs is presented that graphically depicts the dependence of bioenhancement factor on physicochemical properties. Application of these nomographs is illustrated using data from a well-documented field site. Results suggest that this approach can successfully capture field-scale, as well as column-scale, behavior. Sensitivity analyses reveal that bioenhanced dissolution will critically depend on in-situ biomass concentrations.

Hydrogeologic characterization of a fractured granitic rock aquifer, Raymond, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cohen, Andrew J.B.

1993-10-01

The hydrogeologic properties of a shallow, fractured granitic rock aquifer in the foothills of the Sierra Nevada, California were investigated via the analysis of borehole geophysical logs and pumping tests. The drawdowns produced during these tests are not indicative of any simple conceptual aquifer model, and borehole logs show that the granite is intensely fractured. These observations are suggestive of a complex fracture-flow geometry which is extremely difficult to decipher. However, through the measurement of orientations of individual subsurface fractures from acoustic televiewer logs, and correlation between particular fractures and electrical resistivity and thermal-pulse flowmeter logs, it was found thatmore » the aquifer is, in general, comprised of two subhorizontal and nearly parallel zones of unloading fractures. Downhole flowmeter measurements taken in several wells provide further evidence for the inferred dual-layer structure of the aquifer, as well as yield quantitative measures of the contribution of flow from each zone. Analysis of drawdowns in pumped wells reveals that there are zones of relatively high transmissivity immediately around them. It was found that these properties, as well as a nearby zone of lower transmissivity, can account for their observed drawdowns. A numerical model was constructed to test whether these major heterogeneities could also account for the drawdowns in observation wells. This stepwise analysis of both the geophysical and hydrological data resulted in the formulation of a conceptual model of the aquifer which is consistent with observations, and which can account for its behavior when subjected to pumping.« less

Frictional behavior of carbonate-rich sediments in subduction zones

NASA Astrophysics Data System (ADS)

Rabinowitz, H. S.; Savage, H. M.; Carpenter, B. M.; Collettini, C.

2016-12-01

Deformation in rocks and sediments is controlled by multiple mechanisms, each governed by its own pressure- (P), temperature- (T), and slip velocity- (v) dependent kinetics. Frictional behavior depends on which of these mechanisms are dominant, and, thus, varies with P, T, and v. Carbonates are a useful material with which to interrogate the PTv controls on friction due to the fact that a wide range of mechanisms can be easily accessed in the lab at geologically relevant conditions. In addition, carbonate-rich layers make up a significant component of subducting sediments around the world and may impact the frictional behavior of shallow subduction zones. In order to investigate the effect of carbonate subduction and the evolution of friction at subduction zone conditions, we conducted deformation experiments on input sediments for two subduction zones, the Hikurangi trench, New Zealand (ODP Site 1124) and the Peru trench (DSDP Site 321), which have carbonate/clay contents of 40/60 wt% and 80/20 wt%, respectively. Samples were saturated with distilled water mixed with 35g/l sea salt and deformed at room temperature. Experiments were conducted at σeff = 1-100 MPa and T = 20-100 °C with sliding velocities of 1-300 μm/s and hold times of 1-1000 s. We test the changes in velocity dependence and healing over these PT conditions to elucidate the frictional behavior of carbonates in subduction zone settings. The mechanical results are complemented by microstructural analysis. In lower stress experiments, there is no obvious shear localization; however, by 25 MPa, pervasive boundary-parallel shears become dominant, particularly in the Peru samples. Optical observations of these shear zones under cross-polarized light show evidence of plastic deformation (CPO development) while SEM-EDS observations indicate phase segregation in the boundary shears. Degree of microstructural localization appears to correspond with the trends observed in velocity-dependence. Our preliminary results indicate that carbonate/clay compositions could have a significant impact on the frictional behavior of subducting sediments.

Exploring stop-go decision zones at rural high-speed intersections with flashing green signal and insufficient yellow time in China.

PubMed

Tang, Keshuang; Xu, Yanqing; Wang, Fen; Oguchi, Takashi

2016-10-01

The objective of this study is to empirically analyze and model the stop-go decision behavior of drivers at rural high-speed intersections in China, where a flashing green signal of 3s followed by a yellow signal of 3s is commonly applied to end a green phase. 1, 186 high-resolution vehicle trajectories were collected at four typical high-speed intersection approaches in Shanghai and used for the identification of actual stop-go decision zones and the modeling of stop-go decision behavior. Results indicate that the presence of flashing green significantly changed the theoretical decision zones based on the conventional Dilemma Zone theory. The actual stop-go decision zones at the study intersections were thus formulated and identified based on the empirical data. Binary Logistic model and Fuzzy Logic model were then developed to further explore the impacts of flashing green on the stop-go behavior of drivers. It was found that the Fuzzy Logic model could produce comparably good estimation results as compared to the traditional Binary Logistic models. The findings of this study could contribute the development of effective dilemma zone protection strategies, the improvement of stop-go decision model embedded in the microscopic traffic simulation software and the proper design of signal change and clearance intervals at high-speed intersections in China. Copyright © 2016 Elsevier Ltd. All rights reserved.

A new subdivision of the central Sesia Zone (Aosta Valley, Italy)

NASA Astrophysics Data System (ADS)

Giuntoli, Francesco; Engi, Martin; Manzotti, Paola; Ballèvre, Michel

2015-04-01

The Sesia Zone in the Western Alps is a continental terrane probably derived from the NW-Adriatic margin and polydeformed at HP conditions during Alpine convergence. Subdivisions of the Sesia Zone classically have been based on the dominant lithotypes: Eclogitic Micaschist Complex, Seconda Zona Diorito-Kinzigitica, and Gneiss Minuti Complex. However, recent work (Regis et al., 2014) on what was considered a single internal unit has revealed that it comprises two or more tectonic slices that experienced substantially different PTDt-evolutions. Therefore, detailed regional petrographic and structural mapping (1:3k to 1:10k) was undertaken and combined with extensive sampling for petrochronological analysis. Results allow us to propose a first tectonic scheme for the Sesia Zone between the Aosta Valley and Val d'Ayas. A set of field criteria was developed and applied, aiming to recognize and delimit the first order tectonic units in this complex structural and metamorphic context. The approach rests on three criteria used in the field: (1) Discontinuously visible metasedimentary trails (mostly carbonates) considered to be monocyclic (Permo-Mesozoic protoliths); (2) mappable high-strain zones; and (3) visible differences in the metamorphic imprint. None of these key features used are sufficient by themselves, but in combination they allow us to propose a new map that delimits main units. We propose an Internal Complex with three eclogitic sheets, each 0.5-3 km thick. Dominant lithotypes include micaschists associated with mafic rocks and minor orthogneiss. The main foliation is of HP, dipping moderately NW. Each of these sheets is bounded by (most likely monometamorphic) sediments, <10-50 m thick. HP-relics (of eclogite facies) are widespread, but a greenschist facies overprint locally is strong close to the tectonic contact to neighbouring sheets. An Intermediate Complex lies NW of the Internal Complex and comprises two thinner, wedge-shaped units termed slices. These are composed of siliceous dolomite marbles, meta-granites and -diorites with few mafic boudins. The main foliation dips SE and is of greenschist facies, but omphacite, glaucophane, and garnet occur as relics. Towards the SW, the width of the Intermediate Complex is reduced from 0.5 km to a few meters. In the External Complex several discontinuous lenses occur; these comprise 2DK-lithotypes and are aligned with greenschist facies shear zones mapped within Gneiss Minuti. By combining these features, three main sheets were delimited in the External Complex, with the main foliation being of greenschist facies and dipping moderately SE. Petrological work and in situ U-Th-Pb dating of accessory phases is underway in several of these subunits of the Sesia Zone to constrain their PTDt-history and thus their Alpine assembly. REFERENCE Regis, D., Rubatto, D., Darling, J., Cenki-Tok, B., Zucali, M., Engi, M., 2014. Multiple metamorphic stages within an eclogite-facies terrane (Sesia Zone, Western Alps) revealed by Th-U-Pb petrochronology. J.Petrol. 55, 1429-1456.

Mesozoic to Eocene ductile deformation of western Central Iran: From Cimmerian collisional orogeny to Eocene exhumation

NASA Astrophysics Data System (ADS)

Kargaranbafghi, Fariba; Neubauer, Franz; Genser, Johann; Faghih, Ali; Kusky, Timothy

2012-09-01

To advance our understanding of the Mesozoic to Eocene tectonics and kinematics of basement units exposed in the south-western Central Iran plateau, this paper presents new structural and thermochronological data from the Chapedony metamorphic core complex and hangingwall units, particularly from the Posht-e-Badam complex. The overall Paleogene structural characteristics of the area are related to an oblique convergent zone. The Saghand area represents part of a deformation zone between the Arabian and Eurasian plates, and can be interpreted to result from the Central Iran intracontinental deformation acting as a weak zone during Mesozoic to Paleogene times. Field and microstructural evidence reveal that the metamorphic and igneous rocks suffered a ductile shear deformation including mylonitization at the hangingwall boundary of the Eocene Chapedony metamorphic core complex. Comparison of deformation features in the mylonites and other structural features within the footwall unit leads to the conclusion that the mylonites were formed in a subhorizontal shear zone by NE-SW stretching during Middle to Late Eocene extensional tectonics. The Chapedony metamorphic core complex is characterized by amphibolite-facies metamorphism and development of S and S-L tectonic fabrics. The Posht-e-Badam complex was deformed by two stages during Cimmerian tectonic processes forming the Paleo-Tethyan suture.

Assessment of the capillary zone electrophoretic behavior of proteins in the presence of electroosmotic modifiers: protein-polyamine interaction studied using a polyacrylamide-coated capillary.

PubMed

Kubo, K; Hattori, A

2001-10-01

The use of polyamines as electroosmotic modifiers has been shown to be effective in enhancing resolution of protein glycoforms in capillary zone electrophoresis (CZE) using a bare capillary tube. In this study, effectiveness was evaluated by using a polyacrylamide-coated capillary tube instead of a bare capillary tube. Electropherograms obtained in the presence of polyamines were inferior to those obtained in their absence with respect to resolution. Electrophoretic mobility of the proteins decreased and their peaks were broadened by polyamines bound to them. This unfavorable effect was dependent on both the species of polyamines and the pH values of the electrolyte buffer. The reduction of resolution caused by polyamines was in the following order: spermidine (SPD) approximately spermidine-tri-hydrochloride (SPD-HCI) > putrescine (PUT) > hexamethonium chloride (HMC). The observed effect can be ascribed to the formation of complexes between the proteins and the polyamines. In addition, for the bare capillary tube the complexes showed interaction with the inner surface, resulting in local suppression of electroosmosis and poor resolution. The high resolution obtained in the coated capillary tube was reduced in the presence of the polyamines. Thus, the use of the polyamines has a negative effect on the analysis of protein microheterogeneity as a result of protein-polyamine interaction.

Intermittent tremor migrations beneath Guerrero, Mexico, and implications for fault healing within the slow slip zone

NASA Astrophysics Data System (ADS)

Peng, Yajun; Rubin, Allan M.

2017-01-01

Slow slip events exhibit significant complexity in slip evolution and variations in recurrence intervals. Behavior that varies systematically with recurrence interval is likely to reflect different extents of fault healing between these events. Here we use high-resolution tremor catalogs beneath Guerrero, Mexico, to investigate the mechanics of slow slip. We observe complex tremor propagation styles, including rapid tremor migrations propagating either along the main tremor front or backward, reminiscent of those in northern Cascadia. We also find many migrations that originate well behind the front and repeatedly occupy the same source region during a tremor episode, similar to those previously reported from Shikoku, Japan. These migrations could be driven by slow slip in the surrounding regions, with recurrence intervals possibly modulated by tides. The propagation speed of these migrations decreases systematically with time since the previous migration over the same source area. Tremor amplitudes seem consistent with changes in the propagation speeds being controlled primarily by changes in the slip speeds. One interpretation is that the high propagation speeds and inferred high slip speeds during the migrations with short recurrence intervals are caused by incomplete healing within the host rock adjacent to the shear zone, which could lead to high permeability and reduced dilatant strengthening of the fault gouge. Similar processes may operate in other slow slip source regions such as Cascadia.

The Galicia-Ossa-Morena Zone: Proposal for a new zone of the Iberian Massif. Variscan implications

NASA Astrophysics Data System (ADS)

Arenas, Ricardo; Díez Fernández, Rubén; Rubio Pascual, Francisco J.; Sánchez Martínez, Sonia; Martín Parra, Luis Miguel; Matas, Jerónimo; González del Tánago, José; Jiménez-Díaz, Alberto; Fuenlabrada, Jose M.; Andonaegui, Pilar; Garcia-Casco, Antonio

2016-06-01

Correlation of a group of allochthonous terranes (referred to as basal, ophiolitic and upper units) exposed in the NW and SW of the Iberian Massif, is used to propose a new geotectonic zone in the southern branch of the Variscan Orogen: the Galicia-Ossa-Morena Zone. Recent advances in SW Iberia identify most of the former Ossa-Morena Zone as another allochthonous complex of the Iberian Massif, the Ossa-Morena Complex, equivalent to the Cabo Ortegal, Órdenes, Malpica-Tui, Bragança and Morais complexes described in NW Iberia. The new geotectonic zone and its counterparts along the rest of the Variscan Orogen constitute an Internal Variscan Zone with ophiolites and units affected by high-P metamorphism. The Galicia-Ossa-Morena Zone includes a Variscan suture and pieces of continental crust bearing the imprint of Ediacaran-Cambrian events related to the activity of peri-Gondwanan magmatic arcs (Cadomian orogenesis). In the Iberian Massif, the general structure of this geotectonic zone represents a duplication of the Gondwanan platform, the outboard sections being juxtaposed on top of domains located closer to the mainland before amalgamation. This interpretation offers an explanation that overcomes some issues regarding the differences between the stratigraphic and paleontological record of the central and southern sections of the Iberian Massif. Also, equivalent structural relationships between other major geotectonic domains of the rest of the Variscan Orogen are consistent with our interpretation and allow suspecting similar configurations along strike of the orogen. A number of issues may be put forward in this respect that potentially open new lines of thinking about the architecture of the Variscan Orogen.

Seismotectonic zoning of Azerbaijan territory

NASA Astrophysics Data System (ADS)

Kangarli, Talat; Aliyev, Ali; Aliyev, Fuad; Rahimov, Fuad

2017-04-01

Studying of the space-time correlation and consequences effect between tectonic events and other geological processes that have created modern earth structure still remains as one of the most important problems in geology. This problem is especially important for the East Caucasus-South Caspian geodynamic zone. Being situated at the eastern part of the Caucasian strait, this zone refers to a center of Alpine-Himalayan active folded belt, and is known as a complex tectonic unit with jointing heterogeneous structural-substantial complexes arising from different branches of the belt (Doburja-Caucasus-Kopetdag from the north and Pyrenean-Alborz from the south with Kura and South Caspian zone). According to GPS and precise leveling data, activity of regional geodynamic processes shows intensive horizontal and vertical movements of the Earth's crust as conditioned by collision of the Arabian and Eurasian continental plates continuing since the end of Miocene. So far studies related to the regional of geology-geophysical data, periodically used for the geological and tectonic modeling of the environment mainly based on the fixing ideology. There still remains a number of uncertainties in solution of issues related to regional geology, tectonics and magmatism, structure and interrelation of different structural zones, space-time interrelations between onshore and offshore complexes, etc. At the same time large dataset produced by surface geological surveys, deep geological mapping of on- and offshore areas with the use of seismic and electrical reconnaissance and geophysical field zoning methods, deep well drilling and remote sensing activities. Conducted new studies produced results including differentiation of formerly unknown nappe complexes of the different ages and scales within the structure of mountain-fold zones, identification of new zones containing ophiolites in their section, outlining of currently active faulting areas, geophysical interpretation of the deep structure of Greater and Lesser Caucasus, detailed description of the deep structure of Caspian zone, Kur and Caspian megadepressions, identification of nappe-folded structure of the Absheron Peninsula and the Absheron threshold at the border of Middle and South Caspian, justification of the possible hydrocarbon concentration at the tectonically stratified substantial complexes of mountain and foothill areas, etc. Based on the outcomes of implemented researches, some general conclusions and schemes were drawn for some parts of the project region within the plate tectonics conceptual frameworks, to include the territories of Lesser Caucasus and South Caspian. Analysis and comparison of these data with macroseismic and instrumental data allowed us to conduct seismotectonic studies in a region and develop a new scheme of seismotectonic map with outlined recent and forecasted seismic activity. There also correlated foci zones of earthquakes with subhorizontal and subvertical borders in earth crust, which shows their structure-dynamic relationship. In the one hand, the earthquake foci zones belong to the faults of the basement which extend to sedimentary cover and their intersection knots. On the other hand, there appearing inner-block seismogenic levels, namely, in seismic generation acts all the earth crust: tectonic stress results on movements along fault zones, as well as lateral displacements along non-stable contacts of the structure-substance complexes of different competency.

About the Transformation Phase Zones of Shape Memory Alloys' Fracture Tests on Single Edge-Cracked Specimen

NASA Astrophysics Data System (ADS)

Taillebot, V.; Lexcellent, C.; Vacher, P.

2012-03-01

The thermomechanical behavior of shape memory alloys is now well mastered. However, a hindrance to their sustainable use is the lack of knowledge of their fracture behavior. With the aim of filling this partial gap, fracture tests on edge-cracked specimens in NiTi have been made. Particular attention was paid to determine the phase transformation zones in the vicinity of the crack tip. In one hand, experimental kinematic fields are observed using digital image correlation showing strain localization around the crack tip. In the other hand, an analytical prediction, based on a modified equivalent stress criterion and taking into account the asymmetric behavior of shape memory alloys in tension-compression, provides shape and size of transformation outset zones. Experimental results are relatively in agreement with our analytical modeling.

Three-dimensional analysis of a faulted CO 2 reservoir using an Eshelby-Mori-Tanaka approach to rock elastic properties and fault permeability

DOE PAGES

Nguyen, Ba Nghiep; Hou, Zhangshuan; Last, George V.; ...

2016-09-29

This work develops a three-dimensional multiscale model to analyze a complex CO 2 faulted reservoir that includes some key geological features of the San Andreas and nearby faults southwest of the Kimberlina site. The model uses the STOMP-CO 2 code for flow modeling that is coupled to the ABAQUS® finite element package for geomechanical analysis. A 3D ABAQUS® finite element model is developed that contains a large number of 3D solid elements with two nearly parallel faults whose damage zones and cores are discretized using the same continuum elements. Five zones with different mineral compositions are considered: shale, sandstone, faultmore » damaged sandstone, fault damaged shale, and fault core. Rocks’ elastic properties that govern their poroelastic behavior are modeled by an Eshelby-Mori-Tanka approach (EMTA). EMTA can account for up to 15 mineral phases. The permeability of fault damage zones affected by crack density and orientations is also predicted by an EMTA formulation. A STOMP-CO 2 grid that exactly maps the ABAQUS® finite element model is built for coupled hydro-mechanical analyses. Simulations of the reservoir assuming three different crack pattern situations (including crack volume fraction and orientation) for the fault damage zones are performed to predict the potential leakage of CO 2 due to cracks that enhance the permeability of the fault damage zones. Here, the results illustrate the important effect of the crack orientation on fault permeability that can lead to substantial leakage along the fault attained by the expansion of the CO 2 plume. Potential hydraulic fracture and the tendency for the faults to slip are also examined and discussed in terms of stress distributions and geomechanical properties.« less

Three-dimensional analysis of a faulted CO 2 reservoir using an Eshelby-Mori-Tanaka approach to rock elastic properties and fault permeability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nguyen, Ba Nghiep; Hou, Zhangshuan; Last, George V.

This work develops a three-dimensional multiscale model to analyze a complex CO 2 faulted reservoir that includes some key geological features of the San Andreas and nearby faults southwest of the Kimberlina site. The model uses the STOMP-CO 2 code for flow modeling that is coupled to the ABAQUS® finite element package for geomechanical analysis. A 3D ABAQUS® finite element model is developed that contains a large number of 3D solid elements with two nearly parallel faults whose damage zones and cores are discretized using the same continuum elements. Five zones with different mineral compositions are considered: shale, sandstone, faultmore » damaged sandstone, fault damaged shale, and fault core. Rocks’ elastic properties that govern their poroelastic behavior are modeled by an Eshelby-Mori-Tanka approach (EMTA). EMTA can account for up to 15 mineral phases. The permeability of fault damage zones affected by crack density and orientations is also predicted by an EMTA formulation. A STOMP-CO 2 grid that exactly maps the ABAQUS® finite element model is built for coupled hydro-mechanical analyses. Simulations of the reservoir assuming three different crack pattern situations (including crack volume fraction and orientation) for the fault damage zones are performed to predict the potential leakage of CO 2 due to cracks that enhance the permeability of the fault damage zones. Here, the results illustrate the important effect of the crack orientation on fault permeability that can lead to substantial leakage along the fault attained by the expansion of the CO 2 plume. Potential hydraulic fracture and the tendency for the faults to slip are also examined and discussed in terms of stress distributions and geomechanical properties.« less

Experimental study of boron geochemistry: implications for fluid processes in subduction zones

NASA Astrophysics Data System (ADS)

You, C. F.; Spivack, A. J.; Gieskes, J. M.; Rosenbauer, R.; Bischoff, J. L.

1995-06-01

A comprehensive experimental study, utilizing an autoclave hydrothermal apparatus with a 10B isotopic tracer, has been conducted to monitor the geochemical behavior of sediment B during early subduction zone processes. The partition coefficient of exchangeable B ( K D) was determined over a temperature range of 25-350°C, at 800 bars and a water/rock ratio of 3-1.5 w/w. These K D are shown to be a complex function of temperature, pH, and possibly mineralogy. At low temperatures, K D is significantly high at ˜4 in contrast to the value of essentially zero at temperatures higher than ˜100°C. A K D of zero represents no B adsorption, implying efficient mobilization of exchangeable B at shallow depths during sediment subduction. Our experimental results demonstrate high mobilization of bulk B in sediments (both exchangeable and lattice bound) at elevated temperatures (200-350°C), in good agreement with previous observations of B in metasediments indicating progressive depletion during metamorphism. In addition, this study emphasizes the importance of a possible water/rock ratio dependence of B mobilization. In other words, the degree of sedimentary B mobilization in subduction zones strongly depends on the local thermal structure and porosity distribution. In low geothermal gradient areas, large amounts of porewater are expelled before significant B mobilization has occurred, so that some sedimentary B will survive and get into the deeper parts of the subduction zone. Our results imply that efficient mobilization of B from the subducted slab must occur and that arc magmatism recycles most of the remaining subducted B back to surface reservoirs. A reconsideration of the B budget in subduction zones provides critical information with respect to B sources and sinks in the ocean.

Treatment of Severely Resorbed Maxilla Due to Peri-Implantitis by Guided Bone Regeneration Using a Customized Allogenic Bone Block: A Case Report

PubMed Central

Blume, Oliver; Hoffmann, Lisa; Donkiewicz, Phil; Wenisch, Sabine; Back, Michael; Franke, Jörg; Schnettler, Reinhard

2017-01-01

The objective of this case report is to introduce a customized CAD/CAM freeze-dried bone allograft (FDBA) block for its use in Guided Bone Regeneration (GBR) procedures for severely deficient maxillary bones. Additionally, a special newly developed remote incision technique is presented to avoid wound dehiscence. The results show optimal integration behavior of the FDBA block after six months and the formation of new vital bone. Thus, the results of the present case report confirm the use of the customized CAD/CAM bone block for augmentation of complex defects in the maxillary aesthetic zone as a successful treatment concept. PMID:29065477

Treatment of Severely Resorbed Maxilla Due to Peri-Implantitis by Guided Bone Regeneration Using a Customized Allogenic Bone Block: A Case Report.

PubMed

Blume, Oliver; Hoffmann, Lisa; Donkiewicz, Phil; Wenisch, Sabine; Back, Michael; Franke, Jörg; Schnettler, Reinhard; Barbeck, Mike

2017-10-21

The objective of this case report is to introduce a customized CAD/CAM freeze-dried bone allograft (FDBA) block for its use in Guided Bone Regeneration (GBR) procedures for severely deficient maxillary bones. Additionally, a special newly developed remote incision technique is presented to avoid wound dehiscence. The results show optimal integration behavior of the FDBA block after six months and the formation of new vital bone. Thus, the results of the present case report confirm the use of the customized CAD/CAM bone block for augmentation of complex defects in the maxillary aesthetic zone as a successful treatment concept.

Seismicity of the Earth 1900–2010 Australia plate and vicinity

USGS Publications Warehouse

Benz, Harley M.; Herman, Matthew; Tarr, Arthur C.; Hayes, Gavin P.; Furlong, Kevin P.; Villaseñor, Antonio; Dart, Richard L.; Rhea, Susan

2011-01-01

This map shows details of the Australia plate and vicinity not presented in Tarr and others (2010). The boundary of the Australia plate includes all fundamental plate boundary components: mid-ocean ridges, subduction zones, arc-continent collisions, and large-offset transform faults. Along the southern edge of the plate the mid-ocean ridge separates the Australia and Antarctica plates and its behavior is straightforward. In contrast, the other boundary segments that ring the Australia plate represent some of the most seismically active elements of the global plate boundary system, and some of the most rapidly evolving plate interactions. As a result, there are some very complex structures which host many large and great earthquakes

The human thermoneutral and thermal comfort zones: Thermal comfort in your own skin blood flow

PubMed Central

Schlader, Zachary J

2015-01-01

Human thermoregulation is achieved via autonomic and behavioral responses. Autonomic responses involve 2 synchronous ‘components’. One counteracts large thermal perturbations, eliciting robust heat loss or gain (i.e., sweating or shivering). The other fends off smaller insults, relying solely on changes in sensible heat exchange (i.e., skin blood flow). This sensible component occurs within the thermoneutral zone [i.e., the ambient temperature range in which temperature regulation is achieved only by sensible heat transfer, without regulatory increases in metabolic heat production (e.g., shivering) or evaporative heat loss (e.g., sweating)].1 The combination of behavior and sensible heat exchange permits a range of conditions that are deemed thermally comfortable, which is defined as the thermal comfort zone.1 Notably, we spend the majority of our lives within the thermoneutral and thermal comfort zones. It is only when we are unable to stay within these zones that deleterious health and safety outcomes can occur (i.e., hypo- or hyperthermia). Oddly, although the thermoneutral zone and thermal preference (a concept similar to the thermal comfort zone) has been extensively studied in non-human animals, our understanding of human thermoregulation within the thermoneutral and thermal comfort zones remains rather crude. PMID:27226992

Diverse behaviors of outer radial glia in developing ferret and human cortex.

PubMed

Gertz, Caitlyn C; Lui, Jan H; LaMonica, Bridget E; Wang, Xiaoqun; Kriegstein, Arnold R

2014-02-12

The dramatic increase in neocortical size and folding during mammalian brain evolution has been attributed to the elaboration of the subventricular zone (SVZ) and the associated increase in neural progenitors. However, recent studies have shown that SVZ size and the abundance of resident progenitors do not directly predict cortical topography, suggesting that complex behaviors of the progenitors themselves may contribute to the overall size and shape of the adult cortex. Using time-lapse imaging, we examined the dynamic behaviors of SVZ progenitors in the ferret, a gyrencephalic carnivore, focusing our analysis on outer radial glial cells (oRGs). We identified a substantial population of oRGs by marker expression and their unique mode of division, termed mitotic somal translocation (MST). Ferret oRGs exhibited diverse behaviors in terms of division location, cleavage angle, and MST distance, as well as fiber orientation and dynamics. We then examined the human fetal cortex and found that a subset of human oRGs displayed similar characteristics, suggesting that diversity in oRG behavior may be a general feature. Similar to the human, ferret oRGs underwent multiple rounds of self-renewing divisions but were more likely to undergo symmetric divisions that expanded the oRG population, as opposed to producing intermediate progenitor cells (IPCs). Differences in oRG behaviors, including proliferative potential and daughter cell fates, may contribute to variations in cortical structure between mammalian species.

Experimental study on spatio-temporal behavior of a single particle forming a particle accumulation structure (PAS) in half-zone liquid bridge

NASA Astrophysics Data System (ADS)

Oba, Takeru; Ueno, Ichiro; Kaneko, Toshihiro

2017-11-01

We focus on particle behavior due to thermocapillary-driven convection in a half-zone liquid bridge of high-Prandtl number fluid. It has been known that the suspended particles exhibit a unique solid-like structure known as 'particle accumulation structure (PAS)' in a rotating frame of reference with traveling-type hydrothermal wave. It is said that PAS is caused by interaction between particles and the free surface of a half-zone liquid bridge. Such structures arise even under small Stokes number conditions. When observing PAS two-dimensionally, it looks like a closed single string, but the actual movement of particles is different. Therefore we employ three-dimensional particle tracking velocimetry to the half-zone liquid bridge of 2.5 mm in radius and 1.7 mm in height, and detect the particle behaviors close to the free surface. We explain the spatio-temporal correlation between the solid-like global structure of PAS and the local particle motions, and make comparisons with proposed physical models of PAS formation.

From climate models to planetary habitability: temperature constraints for complex life

NASA Astrophysics Data System (ADS)

Silva, Laura; Vladilo, Giovanni; Schulte, Patricia M.; Murante, Giuseppe; Provenzale, Antonello

2017-07-01

In an effort to derive temperature-based criteria of habitability for multicellular life, we investigated the thermal limits of terrestrial poikilotherms, i.e. organisms whose body temperature and the functioning of all vital processes is directly affected by the ambient temperature. Multicellular poikilotherms are the most common and evolutionarily ancient form of complex life on earth. The thermal limits for the active metabolism and reproduction of multicellular poikilotherms on earth are approximately bracketed by the temperature interval 0°C <= T <= 50°C. The same interval applies to the photosynthetic production of oxygen, an essential ingredient of complex life, and for the generation of atmospheric biosignatures observable in exoplanets. Analysis of the main mechanisms responsible for the thermal thresholds of terrestrial life suggests that the same mechanisms would apply to other forms of chemical life. We therefore propose a habitability index for complex life, h 050, representing the mean orbital fraction of planetary surface that satisfies the temperature limits 0°C <= T <= 50°C. With the aid of a climate model tailored for the calculation of the surface temperature of Earth-like planets, we calculated h 050 as a function of planet insolation, S, and atmospheric columnar mass, N atm, for a few earth-like atmospheric compositions with trace levels of CO2. By displaying h 050 as a function of S and N atm, we built up an atmospheric mass habitable zone (AMHZ) for complex life. At variance with the classic habitable zone, the inner edge of the complex life habitable zone is not affected by the uncertainties inherent to the calculation of the runaway greenhouse limit. The complex life habitable zone is significantly narrower than the habitable zone of dry planets. Our calculations illustrate how changes in ambient conditions dependent on S and N atm, such as temperature excursions and surface dose of secondary particles of cosmic rays, may influence the type of life potentially present at different epochs of planetary evolution inside the AMHZ.

Early Tertiary Anaconda metamorphic core complex, southwestern Montana

USGS Publications Warehouse

O'Neill, J. M.; Lonn, J.D.; Lageson, D.R.; Kunk, Michael J.

2004-01-01

A sinuous zone of gently southeast-dipping low-angle Tertiary normal faults is exposed for 100 km along the eastern margins of the Anaconda and Flint Creek ranges in southwest Montana. Faults in the zone variously place Mesoproterozoic through Paleozoic sedimentary rocks on younger Tertiary granitic rocks or on sedimentary rocks older than the overlying detached rocks. Lower plate rocks are lineated and mylonitic at the main fault and, below the mylonitic front, are cut by mylonitic mesoscopic to microscopic shear zones. The upper plate consists of an imbricate stack of younger-on-older sedimentary rocks that are locally mylonitic at the main, lowermost detachment fault but are characteristically strongly brecciated or broken. Kinematic indicators in the lineated mylonite indicate tectonic transport to the east-southeast. Syntectonic sedimentary breccia and coarse conglomerate derived solely from upper plate rocks were deposited locally on top of hanging-wall rocks in low-lying areas between fault blocks and breccia zones. Muscovite occurs locally as mica fish in mylonitic quartzites at or near the main detachment. The 40Ar/39Ar age spectrum obtained from muscovite in one mylonitic quartzite yielded an age of 47.2 + 0.14 Ma, interpreted to be the age of mylonitization. The fault zone is interpreted as a detachment fault that bounds a metamorphic core complex, here termed the Anaconda metamorphic core complex, similar in age and character to the Bitterroot mylonite that bounds the Bitterroot metamorphic core complex along the Idaho-Montana state line 100 km to the west. The Bitterroot and Anaconda core complexes are likely components of a continuous, tectonically integrated system. Recognition of this core complex expands the region of known early Tertiary brittle-ductile crustal extension eastward into areas of profound Late Cretaceous contractile deformation characterized by complex structural interactions between the overthrust belt and Laramide basement uplifts, overprinted by late Tertiary Basin and Range faulting. ?? 2004 NRC Canada.

Relations between sedentary behavior and FITNESSGRAM healthy fitness zone achievement and physical activity.

PubMed

Tucker, Jacob S; Martin, Scott; Jackson, Allen W; Morrow, James R; Greenleaf, Christy A; Petrie, Trent A

2014-07-01

To investigate the relations between sedentary behaviors and health-related physical fitness and physical activity in middle school boys and girls. Students (n = 1515) in grades 6-8 completed the Youth Risk Behavior Survey sedentary behavior questions, the FITNESSGRAM physical fitness items, and FITNESSGRAM physical activity self-report questions. When students reported ≤ 2 hours per day of sedentary behaviors, their odds of achieving the FITNESSGRAM Healthy Fitness Zone for aerobic capacity, muscular strength and endurance, flexibility, and body composition increased. Similarly, the odds of achieving physical activity guidelines for children increased when students reported ≤ 2 hours per day of sedentary behaviors. Results illustrate the importance of keeping sedentary behaviors to ≤ 2 hours per day in middle school children, thus increasing the odds that the student will achieve sufficient health-related fitness benefits and be more likely to achieve the national physical activity guidelines.

Socially cooperative choices: An approach to achieving resource sustainability in the coastal zone

NASA Astrophysics Data System (ADS)

Crance, Colin; Draper, Dianne

1996-03-01

Achieving resource sustainability, particularly in the coastal zone, is complicated by a variety of interdependencies and trade-offs between economic, social, and ecological variables. Although trade-offs between each of these variables are important, this paper emphasizes the social components of resource management. In this regard a distinction is made between individual and cooperative choices. Individual choices frequently are made from a shortterm, self-interested perspective, whereas cooperative choices are made from a long-term, community and resource-sustainability perspective. Typically, when presented with a spectrum of resource management decisions, individuals have a tendency to act in a self-interested manner. Thus, cooperative benefits, such as reduced conflict and improved resource certainty, are not realized. An overview of selected aspects of social dilemma theory suggests that socially cooperative choice outcomes are attainable in coastal zone management by integrating structural and behavioral solutions in resource use decision making. Three barriers to successful integration of structural and behavioral solutions are identified as self-interest, mistrust, and variable perceptions of resource amenities. Examples from coastal zone management indicate that these barriers may be overcome using approaches such as scopereduction, co-management, community education, and local participation. The paper also provides comment on the potential benefits of integrating structural and behavioral solutions in international coastal zone management efforts.

Methods, Computational Platform, Verification, and Application of Earthquake-Soil-Structure-Interaction Modeling and Simulation

NASA Astrophysics Data System (ADS)

Tafazzoli, Nima

Seismic response of soil-structure systems has attracted significant attention for a long time. This is quite understandable with the size and the complexity of soil-structure systems. The focus of three important aspects of ESSI modeling could be on consistent following of input seismic energy and a number of energy dissipation mechanisms within the system, numerical techniques used to simulate dynamics of ESSI, and influence of uncertainty of ESSI simulations. This dissertation is a contribution to development of one such tool called ESSI Simulator. The work is being done on extensive verified and validated suite for ESSI Simulator. Verification and validation are important for high fidelity numerical predictions of behavior of complex systems. This simulator uses finite element method as a numerical tool to obtain solutions for large class of engineering problems such as liquefaction, earthquake-soil-structure-interaction, site effect, piles, pile group, probabilistic plasticity, stochastic elastic-plastic FEM, and detailed large scale parallel models. Response of full three-dimensional soil-structure-interaction simulation of complex structures is evaluated under the 3D wave propagation. Domain-Reduction-Method is used for applying the forces as a two-step procedure for dynamic analysis with the goal of reducing the large size computational domain. The issue of damping of the waves at the boundary of the finite element models is studied using different damping patterns. This is used at the layer of elements outside of the Domain-Reduction-Method zone in order to absorb the residual waves coming out of the boundary layer due to structural excitation. Extensive parametric study is done on dynamic soil-structure-interaction of a complex system and results of different cases in terms of soil strength and foundation embedment are compared. High efficiency set of constitutive models in terms of computational time are developed and implemented in ESSI Simulator. Efficiency is done based on simplifying the elastic-plastic stiffness tensor of the constitutive models. Almost in all the soil-structure systems, there are interface zones in contact with each other. These zones can get detached during the loading or can slip on each other. In this dissertation the frictional contact element is implemented in ESSI Simulator. Extended verification has been done on the implemented element. The interest here is the effect of slipping and gap opening at the interface of soil and concrete foundation on the soil-structure system behavior. In fact transferring the loads to structure is defined based on the contact areas which will affect the response of the system. The effect of gap openings and sliding at the interfaces are shown through application examples. In addition, dissipation of the seismic energy due to frictional sliding of the interface zones are studied. Application Programming Interface (API) and Domain Specific Language (DSL) are being developed to increase developer's and user's modeling and simulation capabilities. API describes software services developed by developers that are used by users. A domain-specific language (DSL) is a small language which usually focuses on a particular problem domain in software. In general DSL programs are translated to a common function or library which can be viewed as a tool to hide the details of the programming, and make it easier for the user to deal with the commands.

Modeling of surface roughness effects on glaze ice accretion

NASA Technical Reports Server (NTRS)

Hansman, R. John, Jr.; Yamaguchi, Keiko; Berkowitz, Brian M.; Potapczuk, Mark

1990-01-01

A series of experimental investigations focused on studying the cause and effect of roughness on accreting glaze ice surfaces were conducted. Detailed microvideo observations were made of glaze ice accretions on 1 to 4 inch diameter cylinders in three icing wind tunnels (the Data Products of New England six inch test facility, the NASA Lewis Icing Research Tunnel, and the B. F. Goodrich Ice Protection Research Facility). Infrared thermal video recordings were made of accreting ice surfaces in the Goodrich facility. Distinct zones of surface water behavior were observed; a smooth wet zone in the stagnation region with a uniform water film; a rough zone where surface tension effects caused coalescence of surface water into stationary beads; a horn zone where roughness elements grow into horn shapes; a runback zone where surface water ran back as rivulets; and a dry zone where rime feathers formed. The location of the transition from the smooth to the rough zone was found to migrate with time towards the stagnation point. The behavior of the transition appeared to be controlled by boundary layer transition and bead formation mechanisms at the interface between the smooth and rough zones. Regions of wet ice growth and enhanced heat transfer were clearly visible in the infrared video recordings of glaze ice surfaces. A simple multi-zone modification to the current glaze ice accretion model was proposed to include spatial variability in surface roughness.

Influence of the Density Structure of the Caribbean Plate Forearc on the Static Stress State and Asperity Distribution along the Costa Rican Seismogenic Zone

NASA Astrophysics Data System (ADS)

Lücke, O. H.; Gutknecht, B. D.

2014-12-01

Most of the forearc region along the Central American Subduction Zone shows a series of trench-parallel, positive gravity anomalies with corresponding gravity lows along the trench and toward the coast. These features extend from Guatemala to northern Nicaragua. However, the Costa Rican segment of the forearc does not follow this pattern. In this region, the along-trench gravity low is segmented, the coastal low is absent, and the forearc gravity high is located onshore at the Nicoya Peninsula which overlies the seismogenic zone. Geodetic and seismological studies along the Costa Rican Subduction Zone suggest the presence of coupled areas beneath the Nicoya Peninsula prior to the 2012, magnitude Mw 7.6 earthquake. These areas had previously been associated with asperities. Previous publications have proposed a mechanical model for the generation of asperities along the Chilean convergent margin based on the structure of the overriding plate above the seismogenic zone in which dense igneous bodies disturb the state of stress on the seismogenic zone and may influence seismogenic processes. In Costa Rica, surface geology and gravity data indicate the presence of dense basalt/gabbro crust overlying the seismogenic zone where the coupling is present. Bouguer anomaly values in this region reach up to 120×10-5 m/s2, which are the highest for Costa Rica. In this work, the state of stress on the Cocos-Caribbean plate interface is calculated based on the geometry and mass distribution of a 3D density model of the subduction zone as interpreted from gravity data from combined geopotential models. Results show a correlation between the coupled areas at the Nicoya Peninsula and the presence of stress anomalies on the plate interface. The stress anomalies are calculated for the normal component of the vertical stress on the seismogenic zone and are interpreted as being generated by the dense material which makes up the forearc in the area. The dense material of the Nicoya Complex mafic rocks and the topographic load of the peninsula on the seismogenic zone may play a role in the distribution of coupled areas and the seismic behavior of the region since the anomalous normal stress on the plate interface may increase the shear stress threshold for rupture.

Information fusion for the Gray Zone

NASA Astrophysics Data System (ADS)

Fenstermacher, Laurie

2016-05-01

United States Special Operations Command (SOCOM) recently published a white paper describing the "Gray Zone", security challenges characterized by "ambiguity about the nature of the conflict, opacity of the parties involved…competitive interactions among and within state and non-state actors that fall between the traditional war and peace duality."1 Ambiguity and related uncertainty about actors, situations, relationships, and intent require new approaches to information collection, processing and fusion. General Votel, the current SOCOM commander, during a recent speech on "Operating in the Gray Zone" emphasized that it would be important to get left of the next crises and stated emphatically, "to do that we must understand the Human Domain."2 This understanding of the human domain must come from making meaning based on different perspectives, including the "emic" or first person/participant and "etic" or third person/observer perspectives. Much of the information currently collected and processed is etic. Incorporation and fusion with the emic perspective enables forecasting of behaviors/events and provides context for etic information (e.g., video).3 Gray zone challenges are perspective-dependent; for example, the conflict in Ukraine is interpreted quite differently by Russia, the US and Ukraine. Russia views it as war, necessitating aggressive action, the US views it as a security issue best dealt with by economic sanctions and diplomacy and the Ukraine views it as a threat to its sovereignty.4 General Otto in the Air Force ISR 2023 vision document stated that Air Force ISR is needed to anticipate strategic surprise.5 Anticipatory analysis enabling getting left of a crisis inherently requires a greater focus on information sources that elucidate the human environment as well as new methods that elucidate not only the "who's" and "what's", but the "how's and "why's," extracting features and/or patterns and subtle cues useful for forecasting behaviors and events; for example discourse patterns related to social identity and integrative complexity.6 AFRL has been conducting research to enable analysts to understand the "emic" perspective based on discourse analysis methods and/or text analytics.7 Previous results demonstrated the value of fusion of emic and etic information in terms of improved accuracy (from 39% to 86%) in forecasting violent events.8 This paper will describe new work to extend this to anticipatory analysis in the gray zone.

What can blueschists tell about the Deep? High Pressure in the Anatolide - Taurid Belt

NASA Astrophysics Data System (ADS)

Oberhaensli, R.

2011-12-01

High-pressure metamorphic terranes in the Anatolide - Taurid belt document the complex distribution of paleo-sutures in the Tethyan realm. Field based petrologic studies of metapelites in the Anatolide-Taurid realm allow to trace HP-LT metamorphism not only in the well known ophiolitic Tavsanli Zone (2.4 GPa/500 °C) but also in the Afyon Zone (0.9 GPa/350 °C), the Menderes Massif (1.2 Gpa/500 °C;) and in the Lycian Nappes (1.0 Gpa/400 °C) - all situated north of the so called Taurid Platform. While the HP metamorphism is dated to 90-80 Ma (Rb/Sr; Ar/Ar) in the Tavsanli Zone, it ranges from 60-70 Ma (Ar/Ar) in the Afyon Zone and its tectonic equivalent, the Lycian Nappes. The Afyon Zone s.l. is closely related to the glaucophane- lawsonite-bearing rocks of the Tavsanli Zone and its eastward extension. Blueschist-facies metamorphism is documented by Fe,Mg-carpholite in regionally distributed metapelites and glaucophane in sparse mafic rocks (Afyon, Menderes, Lycia). Since observations of HP are based on Fe,Mg-carpholite bearing metasediments and not on mafic blueschists new thermodynamic data and petrologic modelling was elaborated to match P-T data and field-based observations. Moreover, newly formed phengitic mica allows precise dating. Both, Tavsanli and Afyon Zones can be followed along strike over more than 600 km and around the southern edge of the Central Anatolian Crystalline Complex. The two zones are situated north of the Taurid Platform and correlate with the Amasia Zone in Armenia. To the extreme East the Bitlis Complex underwent a LT - HP metamorphic blueschist evolution (1,1 GPa/ 350 °C; glaucophane, Fe,Mg-carpholite) in its sedimentary cover while the basement is eclogitic. Depending on the structural position and mineral association of phengitic mica metamorphic ages of the Bitlis blueschists scatter around 70-80 Ma. Eclogites from the basement are slightly older. These LT-HP units cannot be correlated with the Tavsanli - Afyon blueschist belts since they occur south of the Taurid Platform. Thus the Bitlis Complex represents a terrane detached from the Arabian Platform that subsequently collided with the Taurus Platform during closure of the Neo-Tethys. In SW Anatolia, south of the Taurus Platform, the Alanya Zone documents a Late Cretaceous HP evolution with blueschists and eclogites. Together with the Bitlis Complex the two Late Cretaceous HP-LT regions represent a suture south of the Taurid Platform but still north of the Hatay - Güleyman - Zagros ophiolites separating the Arabian Platform from the Anatolide-Taurid realm. The dissection of the Anatolide-Taurid realm into several paleo-subduction zones of Late Cretaceous age impacts on the lithospheric structure and has consequences for the Tertiary plateau formation in Central and Eastern Anatolia. Geophysical data and observations from the East Anatolian Plateau can be explained with petrologic modelling when hydration of the lithospheric lids above subduction zones is considered.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Kyoungsoo, E-mail: kpark16@illinois.ed; Paulino, Glaucio H.; Roesler, Jeffery

A simple, effective, and practical constitutive model for cohesive fracture of fiber reinforced concrete is proposed by differentiating the aggregate bridging zone and the fiber bridging zone. The aggregate bridging zone is related to the total fracture energy of plain concrete, while the fiber bridging zone is associated with the difference between the total fracture energy of fiber reinforced concrete and the total fracture energy of plain concrete. The cohesive fracture model is defined by experimental fracture parameters, which are obtained through three-point bending and split tensile tests. As expected, the model describes fracture behavior of plain concrete beams. Inmore » addition, it predicts the fracture behavior of either fiber reinforced concrete beams or a combination of plain and fiber reinforced concrete functionally layered in a single beam specimen. The validated model is also applied to investigate continuously, functionally graded fiber reinforced concrete composites.« less

Large trench-parallel gravity variations predict seismogenic behavior in subduction zones.

PubMed

Song, Teh-Ru Alex; Simons, Mark

2003-08-01

We demonstrate that great earthquakes occur predominantly in regions with a strongly negative trench-parallel gravity anomaly (TPGA), whereas regions with strongly positive TPGA are relatively aseismic. These observations suggest that, over time scales up to at least 1 million years, spatial variations of seismogenic behavior within a given subduction zone are stationary and linked to the geological structure of the fore-arc. The correlations we observe are consistent with a model in which spatial variations in frictional properties on the plate interface control trench-parellel variations in fore-arc topography, gravity, and seismogenic behavior.

Geochemical behavior of heavy metals in a Zn-Pb-Cu mining area in the State of Mexico (central Mexico).

PubMed

Lizárraga-Mendiola, L; González-Sandoval, M R; Durán-Domínguez, M C; Márquez-Herrera, C

2009-08-01

The geochemical behavior of zinc, lead and copper from sulfidic tailings in a mine site with potential to generate acidic drainage (pyrite (55%) and sphalerite (2%)) is reported in this paper. The mining area is divided in two zones, considering the topographic location of sampling points with respect to the tailings pile: (a) outer zone, out of the probable influence of acid mine drainage (AMD) pollution, and (b) inner zone, probably influenced by AMD pollution. Maximum total ions concentrations (mg/L) measured in superficial waters found were, in the outer zone: As (0.2), Cd (0.9), Fe (19), Mn (39), Pb (5.02), SO4(2-) (4650), Zn (107.67), and in the inner zone are As (0.1), Cd (0.2), Fe (88), Mn (13), Pb (6), SO4(2-) (4,880), Zn (46). The presence of these ions that exceeding the permissible maximum limits for human consume, could be associated to tailings mineralogy and acid leachates generated in tailings pile.

What if the Diatoms of the Deep Chlorophyll Maximum Can Ascend?

NASA Astrophysics Data System (ADS)

Villareal, T. A.

2016-02-01

Buoyancy regulation is an integral part of diatom ecology via its role in sinking rates and is fundamental to understanding their distribution and abundance. Numerous studies have documented the effects of size and nutrition on sinking rates. Many pelagic diatoms have low intrinsic sinking rates when healthy and nutrient-replete (< 1-2 meters per day). Physiological control of buoyancy via ion regulation and osmolyte control can easily result in cell sap densities less than seawater, resulting in near-zero sinking rates across a large size spectrum of diatoms as well as positive buoyancy in giant diatoms with their low surface:volume ratio. Ascent by smaller diatoms is much less described although predicted in cells as small as 200 cubic microns. Decreased sedimentation rates have long been linked to formation of layers in the water column, particularly at the low light and nutricline conditions of the deep chlorophyll maximum. The potential for ascending behavior adds an additional layer of complexity by allowing both active depth regulation similar to that observed in flagellated taxa and upward transport by some fraction of deep euphotic zone diatom blooms supported by nutrient injection. In this talk, I review the data documenting positive buoyancy in small diatoms, offer direct visual evidence of ascending behavior in common diatoms typical of both oceanic and coastal zones, and note the characteristics of sinking rate distributions within a single species. Buoyancy control leads to bidirectional movement at similar rates across a wide size spectrum of diatoms although the frequency of ascending behavior may be only a small portion of the individual species' abundance. While much remains to be learned, the paradigm of unidirectional downward movement by diatoms is both inaccurate and an oversimplification.

Predictive Understanding of Mountainous Watershed Hydro-Biogeochemical Function and Response to Perturbations

NASA Astrophysics Data System (ADS)

Hubbard, S. S.; Williams, K. H.; Agarwal, D.; Banfield, J. F.; Beller, H. R.; Bouskill, N.; Brodie, E.; Maxwell, R. M.; Nico, P. S.; Steefel, C. I.; Steltzer, H.; Tokunaga, T. K.; Wainwright, H. M.; Dwivedi, D.; Newcomer, M. E.

2017-12-01

Recognizing the societal importance, vulnerability and complexity of mountainous watersheds, the `Watershed Function' project is developing a predictive understanding of how mountainous watersheds retain and release downgradient water, nutrients, carbon, and metals. In particular, the project is exploring how early snowmelt, drought, floods and other disturbances will influence mountainous watershed dynamics at seasonal to decadal timescales. Located in the 300km2 East River headwater catchment of the Upper Colorado River Basin, the project is guided by several constructs. First, the project considers the integrated role of surface and subsurface flow and biogeochemical reactions - from bedrock to the top of the vegetative canopy, from terrestrial through aquatic compartments, and from summit to receiving waters. The project takes a system-of-systems perspective, focused on developing new methods to quantify the cumulative watershed hydrobiogeochemical response to perturbations based on information from select subsystems within the watershed, each having distinct vegetation-subsurface biogeochemical-hydrological characteristics. A `scale-adaptive' modeling capability, in development using adaptive mesh refinement methods, serves as the organizing framework for the SFA. The scale-adaptive approach is intended to permit simulation of system-within-systems behavior - and aggregation of that behavior - from genome through watershed scales. This presentation will describe several early project discoveries and advances made using experimental, observational and numerical approaches. Among others, examples may include:quantiying how seasonal hydrological perturbations drive biogeochemical responses across critical zone compartments, with a focus on N and C transformations; metagenomic documentation of the spatial variability in floodplain meander microbial ecology; 3D reactive transport simulations of couped hydrological-biogeochemical behavior in the hyporheic zone; and new characterization and inversion approaches to quantify co-variability between above and below ground dynamics and the susceptibility of vegetation to drought stress. More information is provided at: Watershed.lbl.gov

Fibonacci-like zone plate

NASA Astrophysics Data System (ADS)

Cheng, Shubo; Liu, Mengsi; Xia, Tian; Tao, Shaohua

2018-06-01

We present a new family of diffractive lenses, Fibonacci-like zone plates, generated with a modified Fibonacci sequence. The focusing properties and the evolution of transverse diffraction pattern for the Fibonacci-like zone plates have been analytically investigated both theoretically and experimentally and compared with the corresponding Fresnel zone plates of the same resolution. The results demonstrate that the Fibonacci-like zone plates possess the self-similar property and the multifocal behavior. Furthermore, the Fibonacci-like zone plate beams are found to possess the self-reconstruction property, and would be promising for 3D optical tweezers, laser machining, and optical imaging.

Source and sink of fluid in pelagic siliceous sediments along a cold subduction plate boundary

NASA Astrophysics Data System (ADS)

Yamaguchi, Asuka; Hina, Shoko; Hamada, Yohei; Kameda, Jun; Hamahashi, Mari; Kuwatani, Tatsu; Shimizu, Mayuko; Kimura, Gaku

2016-08-01

Subduction zones where old oceanic plate underthrusting occurs are characterized by thick pelagic sediments originating from planktonic ooze as well as cold thermal conditions. For a better understanding of dehydration from pelagic sediments and fluid behavior, which would play a key role in controlling the dynamics in the shallow portion of the subduction zone, as observed in the 2011 Tohoku earthquake and tsunami, we investigate cherts in a Jurassic accretionary complex in Japan. The microstructure and microchemistry of these cherts indicate dissolution of SiO2 from a pressure solution seam and precipitation of SiO2 to the ;white chert layer,; which would act as a fluid conduit. The amount of water necessary to precipitate SiO2 in the white chert is 102 times larger than that produced by compaction and silica/clay diagenesis. Other fluid sources, such as hydrated oceanic crust or oceanic mantle, are necessary to account for this discrepancy in the fluid budget. A large amount of external fluid likely contributed to rising pore pressure along cold plate boundaries.

Anisotropic toughness and strength in graphene and its atomistic origin

NASA Astrophysics Data System (ADS)

Hossain, M. Zubaer; Ahmed, Tousif; Silverman, Benjamin; Khawaja, M. Shehroz; Calderon, Justice; Rutten, Andrew; Tse, Stanley

2018-01-01

This paper presents the implication of crystallographic orientation on toughness and ideal strength in graphene under lattice symmetry-preserving and symmetry-breaking deformations. In symmetry-preserving deformation, both toughness and strength are isotropic, regardless of the chirality of the lattice; whereas, in symmetry-breaking deformation they are strongly anisotropic, even in the presence of vacancy defects. The maximum and minimum of toughness or strength occur for loading along the zigzag direction and the armchair direction, respectively. The anisotropic behavior is governed by a complex interplay among bond-stretching deformation, bond-bending deformation, and the chirality of the lattice. Nevertheless, the condition for crack-nucleation is dictated by the maximum bond-force required for bond rupture, and it is independent of the chiral angle of the lattice or loading direction. At the onset of crack-nucleation a localized nucleation zone is formed, wherein the bonds rupture locally satisfying the maximum bond-force criterion. The nucleation zone acts as the physical origin in triggering the fracture nucleation process, but its presence is undetectable from the macroscopic stress-strain data.

Thickness-, Composition-, and Magnetic-Field-Dependent Complex Impedance Spectroscopy of Granular-Type-Barrier Co/Co-Al2O3/Co MTJs

NASA Astrophysics Data System (ADS)

Tuan, Nguyen Anh; Anh, Nguyen Tuan; Nga, Nguyen Tuyet; Tue, Nguyen Anh; Van Cuong, Giap

2016-06-01

The alternating-current (ac) electrical properties of granular-type-barrier magnetic tunnel junctions (GBMTJs) based on Co/Co x (Al2O3)1- x ( t)/Co trilayer structures have been studied using complex impedance spectroscopy (CIS). Their CIS characteristics were investigated in external magnetic fields varying from 0 kOe to 3 kOe as a function of Co composition x at 10 at.%, 25 at.%, and 35 at.%, with barrier layer thickness t of 20 nm to 90 nm. The influence of these factors on the behaviors of the ac impedance response of the GBMTJs was deeply investigated and attributed to the dielectric or conducting nature of the Co-Al2O3 barrier layer. The most remarkable typical phenomena observed in these behaviors, even appearing paradoxical, include lower impedance for thicker t for each given x, a declining trend of Z with increasing x, a clear decrease of Z with H, and especially a partition of Z into zones according to the H value. All these effects are analyzed and discussed to demonstrate that diffusion-type and mass-transfer-type phenomena can be inferred from processes such as spin tunneling and Coulomb or spin blockade in the Co-Al2O3 barrier layer.

Bioorganic/inorganic hybrid composition of sponge spicules: matrix of the giant spicules and of the comitalia of the deep sea hexactinellid Monorhaphis.

PubMed

Müller, Werner E G; Wang, Xiaohong; Kropf, Klaus; Ushijima, Hiroshi; Geurtsen, Werner; Eckert, Carsten; Tahir, Muhammad Nawaz; Tremel, Wolfgang; Boreiko, Alexandra; Schlossmacher, Ute; Li, Jinhe; Schröder, Heinz C

2008-02-01

The giant basal spicules of the siliceous sponges Monorhaphis chuni and Monorhaphis intermedia (Hexactinellida) represent the largest biosilica structures on earth (up to 3m long). Here we describe the construction (lamellar organization) of these spicules and of the comitalia and highlight their organic matrix in order to understand their mechanical properties. The spicules display three distinct regions built of biosilica: (i) the outer lamellar zone (radius: >300 microm), (ii) the bulky axial cylinder (radius: <75 microm), and (iii) the central axial canal (diameter: <2 microm) with its organic axial filament. The spicules are loosely covered with a collagen net which is regularly perforated by 7-10 microm large holes; the net can be silicified. The silica layers forming the lamellar zone are approximately 5 microm thick; the central axial cylinder appears to be composed of almost solid silica which becomes porous after etching with hydrofluoric acid (HF). Dissolution of a complete spicule discloses its complex structure with distinct lamellae in the outer zone (lamellar coating) and a more resistant central part (axial barrel). Rapidly after the release of the organic coating from the lamellar zone the protein layers disintegrate to form irregular clumps/aggregates. In contrast, the proteinaceous axial barrel, hidden in the siliceous axial cylinder, is set up by rope-like filaments. Biochemical analysis revealed that the (dominant) molecule of the lamellar coating is a 27-kDa protein which displays catalytic, proteolytic activity. High resolution electron microscopic analysis showed that this protein is arranged within the lamellae and stabilizes these surfaces by palisade-like pillars. The mechanical behavior of the spicules was analyzed by a 3-point bending assay, coupled with scanning electron microscopy. The load-extension curve of the spicule shows a biphasic breakage/cracking pattern. The outer lamellar zone cracks in several distinct steps showing high resistance in concert with comparably low elasticity, while the axial cylinder breaks with high elasticity and lower stiffness. The complex bioorganic/inorganic hybrid composition and structure of the Monorhaphis spicules might provide the blueprint for the synthesis of bio-inspired material, with unusual mechanical properties (strength, stiffness) without losing the exceptional properties of optical transmission.

The Ethical Tipping Points of Evaluators in Conflict Zones

ERIC Educational Resources Information Center

Duggan, Colleen; Bush, Kenneth

2014-01-01

What is different about the conduct of evaluations in conflict zones compared to nonconflict zones--and how do these differences affect (if at all) the ethical calculations and behavior of evaluators? When are ethical issues too risky, or too uncertain, for evaluators to accept--or to continue--an evaluation? These are the core questions guiding…

Geologic evolution of the Kastel trough and its implications on the Adiyaman oil fields, SE Turkey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coskun, Bu.

1990-05-01

Oil field developments of the Adiyaman area one of the main oil producing zones in southeast Turkey, have been highly influenced by geologic evolution of the Kastel trough which is situated in front of the suture zone between the Arabian and Anatolian plates. The Upper Cretaceous movements created many paleostructural trends in the Kastel trough where important dolomitic and porous reservoirs exist. The most important tectonic event, which appeared during the Upper Cretaceous movements, is the accumulation of the Kocali-Karadut ophiolitic complex, advancing from the north to the south in the Kastel trough, where heavy materials caused formation of amore » structural model favoring generation and migration and entrapment of oil in the reservoir rocks. Due to the presence of the Kocali-Karadut complex in the Kastel trough the following zones have been distinguished. (1) North Uplift Area. Situated under the allochthonous units, many thrust and reverse faults characterize this zone. The presence of paleohighs, where primary dolomites develop, allows the appearance of some oil fields in the region. This is the main future exploration zone in southeast Turkey. (2) Accumulation Area. Advancing from the north to the south, the allochthonous Kocali-Karadut complex filled the Kastel trough creating a deep graben whose flanks present generally normal faults. (3) Structural Belt. Important paleohighs constitute an exploration trend in this zone where dolomitic and porous carbonates contain actual oil fields. (4) South Accumulation Area. Distant from the Arabian-Anatolian suture zone, regional tectonics and sedimentology show this zone remained deeply buried during geologic time; good source rocks were deposited during the Cretaceous. (5) South Uplift Area. This area corresponds to the northern flank of the huge regional Mardin high in southeast Turkey where new oil fields have been discovered.« less

The Implications of Strike-Slip Earthquake Source Properties on the Transform Boundary Development Process

NASA Astrophysics Data System (ADS)

Neely, J. S.; Huang, Y.; Furlong, K.

2017-12-01

Subduction-Transform Edge Propagator (STEP) faults, produced by the tearing of a subducting plate, allow us to study the development of a transform plate boundary and improve our understanding of both long-term geologic processes and short-term seismic hazards. The 280 km long San Cristobal Trough (SCT), formed by the tearing of the Australia plate as it subducts under the Pacific plate near the Solomon and Vanuatu subduction zones, shows along-strike variations in earthquake behaviors. The segment of the SCT closest to the tear rarely hosts earthquakes > Mw 6, whereas the SCT sections more than 80 - 100 km from the tear experience Mw7 earthquakes with repeated rupture along the same segments. To understand the effect of cumulative displacement on SCT seismicity, we analyze b-values, centroid-time delays and corner frequencies of the SCT earthquakes. We use the spectral ratio method based on Empirical Green's Functions (eGfs) to isolate source effects from propagation and site effects. We find high b-values along the SCT closest to the tear with values decreasing with distance before finally increasing again towards the far end of the SCT. Centroid time-delays for the Mw 7 strike-slip earthquakes increase with distance from the tear, but corner frequency estimates for a recent sequence of Mw 7 earthquakes are approximately equal, indicating a growing complexity in earthquake behavior with distance from the tear due to a displacement-driven transform boundary development process (see figure). The increasing complexity possibly stems from the earthquakes along the eastern SCT rupturing through multiple asperities resulting in multiple moment pulses. If not for the bounding Vanuatu subduction zone at the far end of the SCT, the eastern SCT section, which has experienced the most displacement, might be capable of hosting larger earthquakes. When assessing the seismic hazard of other STEP faults, cumulative fault displacement should be considered a key input in determining potential earthquake size.

Evaluation of NDOR's actuated advance warning systems.

DOT National Transportation Integrated Search

2011-12-01

"Driver behavior within the dilemma zone can be a major safety concern at high-speed signalized intersections. The : Nebraska Department of Roads (NDOR) has developed and implemented an actuated advance warning (AAW) dilemma : zone protection system....

Coupling transfer function and GIS for assessing non-point-source groundwater vulnerability at regional scale

NASA Astrophysics Data System (ADS)

Coppola, A.; Comegna, V.; de Simone, L.

2009-04-01

Non-point source (NPS) pollution in the vadose zone is a global environmental problem. The knowledge and information required to address the problem of NPS pollutants in the vadose zone cross several technological and sub disciplinary lines: spatial statistics, geographic information systems (GIS), hydrology, soil science, and remote sensing. The main issues encountered by NPS groundwater vulnerability assessment, as discussed by Stewart [2001], are the large spatial scales, the complex processes that govern fluid flow and solute transport in the unsaturated zone, the absence of unsaturated zone measurements of diffuse pesticide concentrations in 3-D regional-scale space as these are difficult, time consuming, and prohibitively costly, and the computational effort required for solving the nonlinear equations for physically-based modeling of regional scale, heterogeneous applications. As an alternative solution, here is presented an approach that is based on coupling of transfer function and GIS modeling that: a) is capable of solute concentration estimation at a depth of interest within a known error confidence class; b) uses available soil survey, climatic, and irrigation information, and requires minimal computational cost for application; c) can dynamically support decision making through thematic mapping and 3D scenarios This result was pursued through 1) the design and building of a spatial database containing environmental and physical information regarding the study area, 2) the development of the transfer function procedure for layered soils, 3) the final representation of results through digital mapping and 3D visualization. One side GIS modeled environmental data in order to characterize, at regional scale, soil profile texture and depth, land use, climatic data, water table depth, potential evapotranspiration; on the other side such information was implemented in the up-scaling procedure of the Jury's TFM resulting in a set of texture based travel time probability density functions for layered soils each describing a characteristic leaching behavior for soil profiles with similar hydraulic properties. Such behavior, in terms of solute travel time to water table, was then imported back into GIS and finally estimation groundwater vulnerability for each soil unit was represented into a map as well as visualized in 3D.

Biodiesel presence in the source zone hinders aromatic hydrocarbons attenuation in a B20-contaminated groundwater

NASA Astrophysics Data System (ADS)

Ramos, Débora Toledo; Lazzarin, Helen Simone Chiaranda; Alvarez, Pedro J. J.; Vogel, Timothy M.; Fernandes, Marilda; do Rosário, Mário; Corseuil, Henry Xavier

2016-10-01

The behavior of biodiesel blend spills have received limited attention in spite of the increasing and widespread introduction of biodiesel to the transportation fuel matrix. In this work, a controlled field release of biodiesel B20 (100 L of 20:80 v/v soybean biodiesel and diesel) was monitored over 6.2 years to assess the behavior and natural attenuation of constituents of major concern (e.g., BTEX (benzene, toluene, ethyl-benzene and xylenes) and PAHs (polycyclic aromatic hydrocarbons)) in a sandy aquifer material. Biodiesel was preferentially biodegraded compared to diesel aromatic compounds with a concomitant increase in acetate, methane (near saturation limit (≈ 22 mg L- 1)) and dissolved BTEX and PAH concentrations in the source zone during the first 1.5 to 2.0 years after the release. Benzene and benzo(a)pyrene concentrations remained above regulatory limits in the source zone until the end of the experiment (6.2 years after the release). Compared to a previous adjacent 100-L release of ethanol-amended gasoline, biodiesel/diesel blend release resulted in a shorter BTEX plume, but with higher residual dissolved hydrocarbon concentrations near the source zone. This was attributed to greater persistence of viscous (and less mobile) biodiesel than the highly-soluble and mobile ethanol in the source zone. This persistence of biodiesel/diesel NAPL at the source zone slowed BTEX and PAH biodegradation (by the establishment of an anaerobic zone) but reduced the plume length by reducing mobility. This is the first field study to assess biodiesel/diesel blend (B20) behavior in groundwater and its effects on the biodegradation and plume length of priority groundwater pollutants.

Biodiesel presence in the source zone hinders aromatic hydrocarbons attenuation in a B20-contaminated groundwater.

PubMed

Ramos, Débora Toledo; Lazzarin, Helen Simone Chiaranda; Alvarez, Pedro J J; Vogel, Timothy M; Fernandes, Marilda; do Rosário, Mário; Corseuil, Henry Xavier

2016-10-01

The behavior of biodiesel blend spills have received limited attention in spite of the increasing and widespread introduction of biodiesel to the transportation fuel matrix. In this work, a controlled field release of biodiesel B20 (100L of 20:80 v/v soybean biodiesel and diesel) was monitored over 6.2years to assess the behavior and natural attenuation of constituents of major concern (e.g., BTEX (benzene, toluene, ethyl-benzene and xylenes) and PAHs (polycyclic aromatic hydrocarbons)) in a sandy aquifer material. Biodiesel was preferentially biodegraded compared to diesel aromatic compounds with a concomitant increase in acetate, methane (near saturation limit (≈22mgL -1 )) and dissolved BTEX and PAH concentrations in the source zone during the first 1.5 to 2.0years after the release. Benzene and benzo(a)pyrene concentrations remained above regulatory limits in the source zone until the end of the experiment (6.2years after the release). Compared to a previous adjacent 100-L release of ethanol-amended gasoline, biodiesel/diesel blend release resulted in a shorter BTEX plume, but with higher residual dissolved hydrocarbon concentrations near the source zone. This was attributed to greater persistence of viscous (and less mobile) biodiesel than the highly-soluble and mobile ethanol in the source zone. This persistence of biodiesel/diesel NAPL at the source zone slowed BTEX and PAH biodegradation (by the establishment of an anaerobic zone) but reduced the plume length by reducing mobility. This is the first field study to assess biodiesel/diesel blend (B20) behavior in groundwater and its effects on the biodegradation and plume length of priority groundwater pollutants. Copyright © 2016 Elsevier B.V. All rights reserved.

The Late Jurassic Panjeh submarine volcano in the northern Sanandaj-Sirjan Zone, northwest Iran: Mantle plume or active margin?

NASA Astrophysics Data System (ADS)

Azizi, Hossein; Lucci, Federico; Stern, Robert J.; Hasannejad, Shima; Asahara, Yoshihiro

2018-05-01

The tectonic setting in which Jurassic igneous rocks of the Sanandaj-Sirjan Zone (SaSZ) of Iran formed is controversial. SaSZ igneous rocks are mainly intrusive granodiorite to gabbroic bodies, which intrude Early to Middle Jurassic metamorphic basement; Jurassic volcanic rocks are rare. Here, we report the age and petrology of volcanic rocks from the Panjeh basaltic-andesitic rocks complex in the northern SaSZ, southwest of Ghorveh city. The Panjeh magmatic complex consists of pillowed and massive basalts, andesites and microdioritic dykes and is associated with intrusive gabbros; the overall sequence and relations with surrounding sediments indicate that this is an unusually well preserved submarine volcanic complex. Igneous rocks belong to a metaluminous sub-alkaline, medium-K to high-K calc-alkaline mafic suite characterized by moderate Al2O3 (13.7-17.6 wt%) and variable Fe2O3 (6.0-12.6 wt%) and MgO (0.9-11.1 wt%) contents. Zircon U-Pb ages (145-149 Ma) define a Late Jurassic (Tithonian) age for magma crystallization and emplacement. Whole rock compositions are enriched in Th, U and light rare earth elements (LREEs) and are slightly depleted in Nb, Ta and Ti. The initial ratios of 87Sr/86Sr (0.7039-0.7076) and εNd(t) values (-1.8 to +4.3) lie along the mantle array in the field of ocean island basalts and subcontinental metasomatized mantle. Immobile trace element (Ti, V, Zr, Y, Nb, Yb, Th and Co) behavior suggests that the mantle source was enriched by fluids released from a subducting slab (i.e. deep-crustal recycling) with some contribution from continental crust for andesitic rocks. Based the chemical composition of Panjeh mafic and intermediate rocks in combination with data for other gabbroic to dioritic bodies in the Ghorveh area we offer two interpretations for these (and other Jurassic igneous rocks of the SaSZ) as reflecting melts from a) subduction-modified OIB-type source above a Neo-Tethys subduction zone or b) plume or rift tectonics involving upwelling metasomatized mantle (mostly reflecting the 550 Ma Cadomian crust-forming event).

Near-Road Exposure and Impact of Air Pollution on Allergic Diseases in Elementary School Children: A Cross-Sectional Study

PubMed Central

Kim, Ho Hyun; Lee, Chung Soo; Yu, Seung Do; Lee, Jung Sub; Chang, Jun Young; Jeon, Jun Min; Son, Hye Rim; Park, Chan Jung; Shin, Dong Chun

2016-01-01

Purpose The study aims to classify schools based on traffic pollutants and their complex sources, to assess the environment, to determine the state of allergic diseases among students using the International Study of Asthma and Allergies in children (ISAAC) questionnaire, and to assess their connection to air pollutants. Materials and Methods A total of seven schools were divided into three categories according to the characteristics of their surrounding environments: three schools in traffic-related zones, two schools in complex source zones I (urban), and two schools in complex source zones II (industrial complex). ISAAC questionnaires were administered and the 4404 completed questionnaires were analyzed. Results The frequency of asthma treatment during the past 12 months showed a significant increase (p<0.05) with exposure to NO2 [1.67, 95% confidence intervals (CIs) 1.03–2.71] in the complex source zones. The frequency of allergic rhinitis treatment during the past 12 months increased significantly with exposure to Black Carbon (1.60, 95% CIs 1.36–1.90) (p<0.001), SO2 (1.09, 95% CIs 1.01–1.17) (p<0.05), NO2 (1.18, 95% CIs 1.07–1.30) (p<0.01) for all subjects. Conclusion In terms of supporting children's health, care, and prevention related to major spaces for children, such as school zones, spaces used in coming to and leaving school, playgrounds, and classrooms are essential to ensuring not only the safety of children from traffic accidents but also their protection from local traffic pollutants and various hazardous environmental factors. PMID:26996571

Characterisation of recirculation zones in complex terrain using multi-lidar measurements

NASA Astrophysics Data System (ADS)

Menke, R.; Mann, J.; Vasiljevic, N.

2017-12-01

Wind fields in complex terrain show a higher complexity compared to sites with simpler geometries. It is imperative to understand well the characteristics of complex flows to account for them during the site validation to ensure the wind turbines can withstand the local flow conditions. This study focuses on the description of recirculation zones occurring on lee sides of hills. The flow recirculation can have a significant impact on the success of wind energy projects since it represents one of the main contributors to the turbulence generation. An extensive dataset of observation of flow over complex terrain is available from the Perdigão 2017 field campaign (https://www.nature.com/news/world-s-largest-wind-mapping-project-spins-up-in-portugal-1.21481). A setup of 8 long-range WindScanners (Vasiljević et al., 2016), scanning lidars deployed by DTU performed RHI scans at several positions along two parallel ridges probing the flow field in two vertical planes, in addition data from several meteorological masts is available. With the above-mentioned lidar setup we achieved simultaneous dual-Doppler scans of the recirculation zone at three positions and simultaneous observations of recirculation behind two parallel ridges. Methods are developed to identify and define the extent of recirculation bubbles. Different parameters are defined to characterise the dimensions of the recirculation zone. The change of these parameters along the ridges is studied. In particular, the impact of atmospheric stability and the changes of the wind field at the position of the downwind ridge are investigated. Furthermore, the geometry of the recirculation zone for different wind directions and in connection to the upstream wind conditions is investigated.

The application of ANN for zone identification in a complex reservoir

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, A.C.; Molnar, D.; Aminian, K.

1995-12-31

Reservoir characterization plays a critical role in appraising the economic success of reservoir management and development methods. Nearly all reservoirs show some degree of heterogeneity, which invariably impacts production. As a result, the production performance of a complex reservoir cannot be realistically predicted without accurate reservoir description. Characterization of a heterogeneous reservoir is a complex problem. The difficulty stems from the fact that sufficient data to accurately predict the distribution of the formation attributes are not usually available. Generally the geophysical logs are available from a considerable number of wells in the reservoir. Therefore, a methodology for reservoir description andmore » characterization utilizing only well logs data represents a significant technical as well as economic advantage. One of the key issues in the description and characterization of heterogeneous formations is the distribution of various zones and their properties. In this study, several artificial neural networks (ANN) were successfully designed and developed for zone identification in a heterogeneous formation from geophysical well logs. Granny Creek Field in West Virginia has been selected as the study area in this paper. This field has produced oil from Big Injun Formation since the early 1900`s. The water flooding operations were initiated in the 1970`s and are currently still in progress. Well log data on a substantial number of wells in this reservoir were available and were collected. Core analysis results were also available from a few wells. The log data from 3 wells along with the various zone definitions were utilized to train the networks for zone recognition. The data from 2 other wells with previously determined zones, based on the core and log data, were then utilized to verify the developed networks predictions. The results indicated that ANN can be a useful tool for accurately identifying the zones in complex reservoirs.« less

The chemical composition and source identification of soil dissolved organic matter in riparian buffer zones from Chongming Island, China.

PubMed

Wang, Yulai; Yang, Changming; Li, Jianhua; Shen, Shuo

2014-09-01

Dissolved organic matter (DOM) that is derived from the soil of riparian buffer zones has a complex chemical composition, and it plays an important role in the transport and transformation of pollutants. To identify the source of DOM and to better understand its chemical and structural properties, we collected 33 soil samples from zones with fluctuating water levels along the major rivers on Chongming Island, evaluated the DOM contents in riparian soil, analyzed the chemical composition and functional groups and traced DOM origins by using liquid chromatography quadrupole time-of-flight mass spectrometry (LC-Q-TOF-MS) combined with clustering analysis. All sampling sites were divided into four groups by principal component analysis (PCA) on the basis of the DOM molecules. The results showed that there was no significant difference in the DOM contents between every two groups; however, the DOM fractions differed significantly among the different site groups in the following order: Σ lipids and Σ proteins>Σ sugars and Σ fatty acids>Σ amino acids, Σ indoles and Σ alkaloids. DOM in the riparian buffer zones originated from riparian plants, domestic sewage and agricultural activities, and the hydrophobic and amphiphilic fractions accounting for over 60% of the identified molecules were the dominant fractions. Our study has confirmed the heterogeneous properties of DOM, and it is of vital importance to isolate and characterize the various DOM fractions at the molecular level for a better understanding of the behavior and roles of DOM in the natural environment. Copyright © 2014 Elsevier Ltd. All rights reserved.

Investigating Complex Slow Slip Evolution with High-Resolution Tremor Catalogs and Numerical Simulations

NASA Astrophysics Data System (ADS)

Peng, Y.; Rubin, A. M.

2016-12-01

Significant complexities of episodic slip and tremor (ETS) have been revealed by short tremor bursts lasting minutes to hours, many of which show clear migration patterns. In Cascadia, large-scale rapid tremor reversals (RTRs) extend tens of km along strike, repeatedly occupying the same general source area during an ETS episode [e.g. Thomas et al, 2013; Peng and Rubin, 2016]. We also observe repetitive tremor bursts occurring well behind the main front in Guerrero, Mexico. In contrast to RTRs, these bursts do not originate from the main front, and generally propagate along the slip direction, similar to those reported from Shikoku, Japan [Shelly et al., 2007]. Both types of bursts occur intermittently, with recurrence intervals gradually increasing to tidal periods. However, even the tidally-modulated bursts are unlikely to be driven solely by tidal forcing. Since the stress must decrease during each burst, while the local maxima of the tidal stress remain nearly constant, each tidal peak stress cannot supply the stress drop for the next repetition. Here we explore the possibility that these repetitive bursts are driven by surrounding tremor-less slow slip. We develop a numerical model governed by a rate-and-state friction law that transitions from velocity-weakening to velocity-strengthening with increasing slip speed. A region with a larger transitional velocity than the background is used to represent the tremor zone. For this zone to slip intermittently, its stiffness needs to be sufficiently large that the slip during each burst is less than the total slip of the background during an episode, but smaller than its own critical stiffness. This critical stiffness decreases as the ratio of the background loading rate to the transitional cutoff velocity increases; from elasticity this ratio decreases as the main front moves across the model tremor zone. With these considerations, we successfully reproduce the burst-like behavior with increasingly large recurrence intervals in the model tremor zone during a single slow slip event. Future work will include investigating the propagation velocities of these bursts, which in Guerrero decrease systematically with increasing time since the previous migration through the same region, and tidal modulation of their recurrence intervals.

Microstructural Characterization of Friction Stir Welded Aluminum-Steel Joints

NASA Astrophysics Data System (ADS)

Patterson, Erin E.; Hovanski, Yuri; Field, David P.

2016-06-01

This work focuses on the microstructural characterization of aluminum to steel friction stir welded joints. Lap weld configuration coupled with scribe technology used for the weld tool have produced joints of adequate quality, despite the significant differences in hardness and melting temperatures of the alloys. Common to friction stir processes, especially those of dissimilar alloys, are microstructural gradients including grain size, crystallographic texture, and precipitation of intermetallic compounds. Because of the significant influence that intermetallic compound formation has on mechanical and ballistic behavior, the characterization of the specific intermetallic phases and the degree to which they are formed in the weld microstructure is critical to predicting weld performance. This study used electron backscatter diffraction, energy dispersive spectroscopy, scanning electron microscopy, and Vickers micro-hardness indentation to explore and characterize the microstructures of lap friction stir welds between an applique 6061-T6 aluminum armor plate alloy and a RHA homogeneous armor plate steel alloy. Macroscopic defects such as micro-cracks were observed in the cross-sectional samples, and binary intermetallic compound layers were found to exist at the aluminum-steel interfaces of the steel particles stirred into the aluminum weld matrix and across the interfaces of the weld joints. Energy dispersive spectroscopy chemical analysis identified the intermetallic layer as monoclinic Al3Fe. Dramatic decreases in grain size in the thermo-mechanically affected zones and weld zones that evidenced grain refinement through plastic deformation and recrystallization. Crystallographic grain orientation and texture were examined using electron backscatter diffraction. Striated regions in the orientations of the aluminum alloy were determined to be the result of the severe deformation induced by the complex weld tool geometry. Many of the textures observed in the weld zone and thermo-mechanically affected zones exhibited shear texture components; however, there were many textures that deviated from ideal simple shear. Factors affecting the microstructure which are characteristic of the friction stir welding process, such as post-recrystallization deformation and complex deformation induced by tool geometry were discussed as causes for deviation from simple shear textures.

Macroscopic tensile plasticity by scalarizating stress distribution in bulk metallic glass

PubMed Central

Gao, Meng; Dong, Jie; Huan, Yong; Wang, Yong Tian; Wang, Wei-Hua

2016-01-01

The macroscopic tensile plasticity of bulk metallic glasses (BMGs) is highly desirable for various engineering applications. However, upon yielding, plastic deformation of BMGs is highly localized into narrow shear bands and then leads to the “work softening” behaviors and subsequently catastrophic fracture, which is the major obstacle for their structural applications. Here we report that macroscopic tensile plasticity in BMG can be obtained by designing surface pore distribution using laser surface texturing. The surface pore array by design creates a complex stress field compared to the uniaxial tensile stress field of conventional glassy specimens, and the stress field scalarization induces the unusual tensile plasticity. By systematically analyzing fracture behaviors and finite element simulation, we show that the stress field scalarization can resist the main shear band propagation and promote the formation of larger plastic zones near the pores, which undertake the homogeneous tensile plasticity. These results might give enlightenment for understanding the deformation mechanism and for further improvement of the mechanical performance of metallic glasses. PMID:26902264

Functional Specialization and Flexibility in Human Association Cortex

PubMed Central

Yeo, B. T. Thomas; Krienen, Fenna M.; Eickhoff, Simon B.; Yaakub, Siti N.; Fox, Peter T.; Buckner, Randy L.; Asplund, Christopher L.; Chee, Michael W.L.

2015-01-01

The association cortex supports cognitive functions enabling flexible behavior. Here, we explored the organization of human association cortex by mathematically formalizing the notion that a behavioral task engages multiple cognitive components, which are in turn supported by multiple overlapping brain regions. Application of the model to a large data set of neuroimaging experiments (N = 10 449) identified complex zones of frontal and parietal regions that ranged from being highly specialized to highly flexible. The network organization of the specialized and flexible regions was explored with an independent resting-state fMRI data set (N = 1000). Cortical regions specialized for the same components were strongly coupled, suggesting that components function as partially isolated networks. Functionally flexible regions participated in multiple components to different degrees. This heterogeneous selectivity was predicted by the connectivity between flexible and specialized regions. Functionally flexible regions might support binding or integrating specialized brain networks that, in turn, contribute to the ability to execute multiple and varied tasks. PMID:25249407

The role of cyclic plastic zone size on fatigue crack growth behavior in high strength steels

NASA Astrophysics Data System (ADS)

Korda, Akhmad A.; Miyashita, Y.; Mutoh, Y.

2015-09-01

The role of cyclic plastic zone in front of the crack tip was studied in high strength steels. Estimated plastic zone size would be compared with actual observation. Strain controlled fatigue tests of the steels were carried out to obtain cyclic stress-strain curves for plastic zone estimation. Observations of plastic zone were carried out using in situ SEM fatigue crack growth tests under a constant-ΔK. Hard microstructures in structural steels showed to inhibit the extent of plastic deformation around the crack tip. The rate of crack growth can be correlated with the size of plastic zone. The smaller the plastic zone size, the slower the fatigue crack growth.

Dilemma zone protection on high-speed arterials.

DOT National Transportation Integrated Search

2014-12-01

Driver behavior within the dilemma zone can be a major safety concern at high-speed signalized intersections, especially : for heavy trucks. The Nebraska Department of Roads (NDOR) has developed and implemented an Actuated Advance : Warning (AAW) dil...

Rapid Brownian Motion Primes Ultrafast Reconstruction of Intrinsically Disordered Phe-Gly Repeats Inside the Nuclear Pore Complex.

PubMed

Moussavi-Baygi, R; Mofrad, M R K

2016-07-29

Conformational behavior of intrinsically disordered proteins, such as Phe-Gly repeat domains, alters drastically when they are confined in, and tethered to, nan channels. This has challenged our understanding of how they serve to selectively facilitate translocation of nuclear transport receptor (NTR)-bearing macromolecules. Heterogeneous FG-repeats, tethered to the NPC interior, nonuniformly fill the channel in a diameter-dependent manner and adopt a rapid Brownian motion, thereby forming a porous and highly dynamic polymeric meshwork that percolates in radial and axial directions and features two distinguishable zones: a dense hydrophobic rod-like zone located in the center, and a peripheral low-density shell-like zone. The FG-meshwork is locally disrupted upon interacting with NTR-bearing macromolecules, but immediately reconstructs itself between 0.44 μs and 7.0 μs, depending on cargo size and shape. This confers a perpetually-sealed state to the NPC, and is solely due to rapid Brownian motion of FG-repeats, not FG-repeat hydrophobic bonds. Elongated-shaped macromolecules, both in the presence and absence of NTRs, penetrate more readily into the FG-meshwork compared to their globular counterparts of identical volume and surface chemistry, highlighting the importance of the shape effects in nucleocytoplasmic transport. These results can help our understanding of geometrical effects in, and the design of, intelligent and responsive biopolymer-based materials in nanofiltration and artificial nanopores.

Genesis of a zoned granite stock, Seward Peninsula, Alaska

USGS Publications Warehouse

Hudson, Travis

1977-01-01

A composite epizonal stock of biotite granite has intruded a diverse assemblage of metamorphic rocks in the Serpentine Hot Springs area of north-central Seward Peninsula, Alaska. The metamorphic rocks include amphibolite-facies orthogneiss and paragneiss, greenschist-facies fine-grained siliceous and graphitic metasediments, and a variety of carbonate rocks. Lithologic units within the metamorphic terrane trend generally north-northeast and dip moderately toward the southeast. Thrust faults locally juxtapose lithologic units in the metamorphic assemblage, and normal faults displace both the metamorphic rocks and some parts of the granite stock. The gneisses and graphitic metasediments are believed to be late Precambrian in age, but the carbonate rocks are in part Paleozoic. Dating by the potassium-argon method indicates that the granite stock is Late Cretaceous. The stock has sharp discordant contacts, beyond which is a well-developed thermal aureole with rocks of hornblende hornfels facies. The average mode of the granite is 29 percent plagioclase, 31 percent quartz, 36 percent K-feldspar, and 4 percent biotite. Accessory minerals include apatite, magnetite, sphene, allanite, and zircon. Late-stage or deuteric minerals include muscovite, fluorite, tourmaline, quartz, and albite. The stock is a zoned complex containing rocks with several textural facies that are present in four partly concentric zones. Zone 1 is a discontinuous border unit, containing fine- to coarse-grained biotite granite, that grades inward into zone 2. Zone 2 consists of porphyritic biotite granite with oriented phenocrysts of pinkish-gray microcline in a coarse-grained equigranular groundmass of plagioclase, quartz, and biotite. It is in sharp, concordant to discordant contact with rocks of zone 3. Zone 3 consists of seriate-textured biotite granite that has been intruded by bodies of porphyritic biotite granite containing phenocrysts of plagioclase, K-feldspar, quartz, and biotite in an aplitic groundmass. Flow structures, pegmatite and aplite segregations, and miarolitic cavities are common in the seriate-textured granite. Zone 4, which forms the central part of the complex, consists of fine- to medium-grained biotite granite and locally developed leucogranite. Small miarolitic cavities are common within it. Eight textural facies have been defined within the complex, and mineralogic, petrographic, modal, and chemical variations are broadly systematic within the facies sequence. Study of these variations shows that the gradational facies of zones l and 2 systematically shift toward more mafic compositions inward within the complex. Seriate-textured rocks of zone 3 are similar in composition to those of zone 2, but porphyritic rocks of zone 3 and rocks of zone 4 mark shifts to more felsic compositions. These late-crystallizing felsic rocks are products of an interior residual magma system. This system was enriched in water and certain trace elements including tin, lithium, niobium, lead, and zinc. The complex as a whole has higher concentrations of these elements than many other granites. The nature of this geochemical specialization is particularly well demonstrated by the trace-element composition of biotite. The crystallization history of the pluton was complex. The available data suggest that this history could have included: (1) chilling and metasomatic alteration adjacent to the contact, (2) in-situ crystallization in several marginal facies accompanied by some transfer of residual constituents toward interior parts of the pluton, (3) slight upward displacement of magma that was subjacent to the crystallized walls, accompanied by disequilibrium crystallization and local vapor saturation, (4) upward displacement of part of the residual water-rich interior magma, accompanied by rapid loss of a separated vapor phase, and (5) displacement of the margins of the pluton by normal faults, accompanied by loss of an exsolved vapor phase from th

Exploiting the locality of periodic subsystem density-functional theory: efficient sampling of the Brillouin zone.

PubMed

Genova, Alessandro; Pavanello, Michele

2015-12-16

In order to approximately satisfy the Bloch theorem, simulations of complex materials involving periodic systems are made n(k) times more complex by the need to sample the first Brillouin zone at n(k) points. By combining ideas from Kohn-Sham density-functional theory (DFT) and orbital-free DFT, for which no sampling is needed due to the absence of waves, subsystem DFT offers an interesting middle ground capable of sizable theoretical speedups against Kohn-Sham DFT. By splitting the supersystem into interacting subsystems, and mapping their quantum problem onto separate auxiliary Kohn-Sham systems, subsystem DFT allows an optimal topical sampling of the Brillouin zone. We elucidate this concept with two proof of principle simulations: a water bilayer on Pt[1 1 1]; and a complex system relevant to catalysis-a thiophene molecule physisorbed on a molybdenum sulfide monolayer deposited on top of an α-alumina support. For the latter system, a speedup of 300% is achieved against the subsystem DTF reference by using an optimized Brillouin zone sampling (600% against KS-DFT).

Tectonic study of the extension of the New Madrid fault zone near its intersection with the 38th parallel lineament

DOE Office of Scientific and Technical Information (OSTI.GOV)

Braile, L.W.; Hinze, W.J.; Sexton, J.L.

1982-06-01

Gravity, magnetic, geologic, and seismicity data have been combined in a seismotectonic analysis of the New Madrid seismic zone. Previous studies have presented evidence for several rift zones in this area (Upper Mississippi enmbayment), including the Reelfoot rift, a late precambrian-early Paleozoic failed arm which extends north-northeast from the ancient continental margin. We suggest that the northern terminus of the Reelfoot rift forms a rift complex, with arms extending northeast into southwestern Indiana, northwest along the Mississippi River, and east into western Kentucky, which appears to correlate well with the seismicity in the area. This correlation suggests that faults associatedmore » with this rift complex are being reactivated in the contemporary stress field (east-northeast compression). If this interpretation is valid, it represents a seismotectonic model which can be used to predict the extent of future seismicity in the New Madrid seismic zone. The proposed rift complex also provides a coherent model for the tectonic development of this region of the North American midcontinent.« less

High-speed superresolution imaging of the proteins in fission yeast clathrin-mediated endocytic actin patches

PubMed Central

Arasada, Rajesh; Sayyad, Wasim A.; Berro, Julien; Pollard, Thomas D.

2018-01-01

To internalize nutrients and cell surface receptors via clathrin-mediated endocytosis, cells assemble at least 50 proteins, including clathrin, clathrin-interacting proteins, actin filaments, and actin binding proteins, in a highly ordered and regulated manner. The molecular mechanism by which actin filament polymerization deforms the cell membrane is unknown, largely due to lack of knowledge about the organization of the regulatory proteins and actin filaments. We used high-speed superresolution localization microscopy of live fission yeast cells to improve the spatial resolution to ∼35 nm with 1-s temporal resolution. The nucleation promoting factors Wsp1p (WASp) and Myo1p (myosin-I) define two independent pathways that recruit Arp2/3 complex, which assembles two zones of actin filaments. Myo1p concentrates at the site of endocytosis and initiates a zone of actin filaments assembled by Arp2/3 complex. Wsp1p appears simultaneously at this site but subsequently moves away from the cell surface as it stimulates Arp2/3 complex to assemble a second zone of actin filaments. Cells lacking either nucleation-promoting factor assemble only one, stationary, zone of actin filaments. These observations support our two-zone hypothesis to explain endocytic tubule elongation and vesicle scission in fission yeast. PMID:29212877

Sensorimotor restriction affects complex movement topography and reachable space in the rat motor cortex.

PubMed

Budri, Mirco; Lodi, Enrico; Franchi, Gianfranco

2014-01-01

Long-duration intracortical microstimulation (ICMS) studies with 500 ms of current pulses suggest that the forelimb area of the motor cortex is organized into several spatially distinct functional zones that organize movements into complex sequences. Here we studied how sensorimotor restriction modifies the extent of functional zones, complex movements, and reachable space representation in the rat forelimb M1. Sensorimotor restriction was achieved by means of whole-forelimb casting of 30 days duration. Long-duration ICMS was carried out 12 h and 14 days after cast removal. Evoked movements were measured using a high-resolution 3D optical system. Long-term cast caused: (i) a reduction in the number of sites where complex forelimb movement could be evoked; (ii) a shrinkage of functional zones but no change in their center of gravity; (iii) a reduction in movement with proximal/distal coactivation; (iv) a reduction in maximal velocity, trajectory and vector length of movement, but no changes in latency or duration; (v) a large restriction of reachable space. Fourteen days of forelimb freedom after casting caused: (i) a recovery of the number of sites where complex forelimb movement could be evoked; (ii) a recovery of functional zone extent and movement with proximal/distal coactivation; (iii) an increase in movement kinematics, but only partial restoration of control rat values; (iv) a slight increase in reachability parameters, but these remained far below baseline values. We pose the hypothesis that specific aspects of complex movement may be stored within parallel motor cortex re-entrant systems.

Sensorimotor restriction affects complex movement topography and reachable space in the rat motor cortex

PubMed Central

Budri, Mirco; Lodi, Enrico; Franchi, Gianfranco

2014-01-01

Long-duration intracortical microstimulation (ICMS) studies with 500 ms of current pulses suggest that the forelimb area of the motor cortex is organized into several spatially distinct functional zones that organize movements into complex sequences. Here we studied how sensorimotor restriction modifies the extent of functional zones, complex movements, and reachable space representation in the rat forelimb M1. Sensorimotor restriction was achieved by means of whole-forelimb casting of 30 days duration. Long-duration ICMS was carried out 12 h and 14 days after cast removal. Evoked movements were measured using a high-resolution 3D optical system. Long-term cast caused: (i) a reduction in the number of sites where complex forelimb movement could be evoked; (ii) a shrinkage of functional zones but no change in their center of gravity; (iii) a reduction in movement with proximal/distal coactivation; (iv) a reduction in maximal velocity, trajectory and vector length of movement, but no changes in latency or duration; (v) a large restriction of reachable space. Fourteen days of forelimb freedom after casting caused: (i) a recovery of the number of sites where complex forelimb movement could be evoked; (ii) a recovery of functional zone extent and movement with proximal/distal coactivation; (iii) an increase in movement kinematics, but only partial restoration of control rat values; (iv) a slight increase in reachability parameters, but these remained far below baseline values. We pose the hypothesis that specific aspects of complex movement may be stored within parallel motor cortex re-entrant systems. PMID:25565987

A comparison of the fatigue behavior of cast Ti-7.5Mo with c.p. titanium, Ti-6Al-4V and Ti-13Nb-13Zr alloys.

PubMed

Lin, Chia-Wei; Ju, Chien-Ping; Chern Lin, Jiin-Huey

2005-06-01

The purpose of the present study is to compare the high-cycle fatigue behavior of newly developed Ti-7.5Mo alloy with that of c.p. Ti, Ti-13Nb-13Zr and Ti-6Al-4V alloys in their as-cast state. Experimental results indicate that Ti-6Al-4V and c.p. Ti have higher stress-controlled fatigue resistance but lower strain-controlled fatigue resistance than Ti-7.5Mo and Ti-13Nb-13Zr. Among four materials Ti-7.5Mo demonstrates the best strain-controlled fatigue performance. The fracture surfaces of the present materials are comprised of three morphologically distinct zones: crack initiation zone, crack propagation zone, and the final-stage overload zone. The fatigue cracks almost always initiate from casting-induced surface/subsurface pores. A river pattern is observed in the propagation zone. In the overload zone dimples are typically observed. Three factors most significantly affecting the fatigue performance of the present materials are the presence of the casting-induced surface/subsurface pores; the location of the pores; and the inherent mechanical properties of the materials.

Identification of fracture zones and its application in automatic bone fracture reduction.

PubMed

Paulano-Godino, Félix; Jiménez-Delgado, Juan J

2017-04-01

The preoperative planning of bone fractures using information from CT scans increases the probability of obtaining satisfactory results, since specialists are provided with additional information before surgery. The reduction of complex bone fractures requires solving a 3D puzzle in order to place each fragment into its correct position. Computer-assisted solutions may aid in this process by identifying the number of fragments and their location, by calculating the fracture zones or even by computing the correct position of each fragment. The main goal of this paper is the development of an automatic method to calculate contact zones between fragments and thus to ease the computation of bone fracture reduction. In this paper, an automatic method to calculate the contact zone between two bone fragments is presented. In a previous step, bone fragments are segmented and labelled from CT images and a point cloud is generated for each bone fragment. The calculated contact zones enable the automatic reduction of complex fractures. To that end, an automatic method to match bone fragments in complex fractures is also presented. The proposed method has been successfully applied in the calculation of the contact zone of 4 different bones from the ankle area. The calculated fracture zones enabled the reduction of all the tested cases using the presented matching algorithm. The performed tests show that the reduction of these fractures using the proposed methods leaded to a small overlapping between fragments. The presented method makes the application of puzzle-solving strategies easier, since it does not obtain the entire fracture zone but the contact area between each pair of fragments. Therefore, it is not necessary to find correspondences between fracture zones and fragments may be aligned two by two. The developed algorithms have been successfully applied in different fracture cases in the ankle area. The small overlapping error obtained in the performed tests demonstrates the absence of visual overlapping in the figures. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Digital modeling of end-mill cutting tools for FEM applications from the active cutting contour

NASA Astrophysics Data System (ADS)

Salguero, Jorge; Marcos, M.; Batista, M.; Gómez, A.; Mayuet, P.; Bienvenido, R.

2012-04-01

A very current technique in the research field of machining by material removal is the use of simulations using the Finite Element Method (FEM). Nevertheless, and although is widely used in processes that allows approximations to orthogonal cutting, such as shaping, is scarcely used in more complexes processes, such as milling. This fact is due principally to the complex geometry of the cutting tools in these processes, and the need to realize the studi es in an oblique cutting configuration. This paper shows a methodology for the geometrical characterization of commercial endmill cutting tools, by the extraction of the cutting tool contour, making use of optical metrology, and using this geometry to model the active cutting zone with a 3D CAD software. This model is easily exportable to different CAD formats, such as IGES or STEP, and importable from FEM software, where is possible to study the behavior in service of the same ones.

Effect of reservoir zones and hedging factor dynamism on reservoir adaptive capacity for climate change impacts

NASA Astrophysics Data System (ADS)

Adeloye, Adebayo J.; Soundharajan, Bankaru-Swamy

2018-06-01

When based on the zones of available water in storage, hedging has traditionally used a single hedged zone and a constant rationing ratio for constraining supply during droughts. Given the usual seasonality of reservoir inflows, it is also possible that hedging could feature multiple hedged zones and temporally varying rationing ratios but very few studies addressing this have been reported especially in relation to adaptation to projected climate change. This study developed and tested Genetic Algorithms (GA) optimised zone-based operating policies of various configurations using data for the Pong reservoir, Himachal Pradesh, India. The results show that hedging does lessen vulnerability, which dropped from ≥ 60 % without hedging to below 25 % with the single stage hedging. More complex hedging policies, e.g. two stage and/or temporally varying rationing ratios only produced marginal improvements in performance. All this shows that water hedging policies do not have to be overly complex to effectively offset reservoir vulnerability caused by water shortage resulting from e.g. projected climate change.

Characterization of the guinea pig animal model and subsequent comparison of the behavioral effects of selective dopaminergic drugs and methamphetamine

PubMed Central

Lee, Kiera-Nicole; Pellom, Samuel T.; Oliver, Ericka; Chirwa, Sanika

2014-01-01

Though not commonly used in behavior tests guinea pigs may offer subtle behavior repertoires that better mimic human activity and warrant study. To test this, 31 Hartley guinea pigs (male, 200–250 g) were evaluated in PhenoTyper cages using the video-tracking EthoVision XT 7.0 software. Results showed that guinea pigs spent more time in the hidden zone (small box in corner of cage) than the food/water zone, or arena zone. Guinea pigs exhibited thigmotaxis (a wall following strategy) and were active throughout the light and dark phases. Eating and drinking occurred throughout the light and dark phases. An injection of 0.25 mg/kg SCH23390, the dopamine D1 receptors (D1R) antagonist, produced significant decreases in time spent in the hidden zone. There were insignificant changes in time spent in the hidden zone for guinea pigs treated with 7.5 mg SKF38393 (D1R agonist), 1.0 mg/kg sulpiride (D2R antagonist), and 1.0 or 10.0 mg/kg methamphetamine. Locomotor activity profiles were unchanged after injections of saline, SKF38393, SCH23390 and sulpiride. By contrast, a single injection or repeated administration for 7 days of low-dose methamphetamine induced transient hyperactivity but this declined to baseline levels over the 22-hour observation period. Guinea pigs treated with high-dose methamphetamine displayed sustained hyperactivity and travelled significantly greater distances over the circadian cycle. Subsequent 7-day treatment with high-dose methamphetamine induced motor sensitization and significant increases in total distances moved relative to single drug injections or saline controls. These results highlight the versatility and unique features of the guinea pig for studying brain-behavior interactions. PMID:24436154

Electrolytic lesions of a discrete area within the nucleus accumbens shell attenuate the long-term expression, but not early phase, of sensitization to cocaine.

PubMed

Brenhouse, Heather C; Montalto, Stefanie; Stellar, James R

2006-06-30

Repeated exposure to cocaine leads to behavioral sensitization, which is the augmentation of the locomotor response to a subsequent exposure to the drug. The nucleus accumbens (NAc), a major termination site of dopaminergic neurons, is believed to be involved in behavioral sensitization and studies have demonstrated that the NAc shell can be split into five zones of analysis; the vertex, arch, cone, intermediate and ventrolateral zones [Todtenkopf MS, Stellar JR. Assessment of tyrosine hydroxylase immunoreactive innervation in five subregions of the nucleus accumbens shell in rats treated with repeated cocaine. Synapse 2000;38:261-70]. Several reports show cocaine-induced c-fos expression particularly in the intermediate zone after 14, but not 2, drug-free days following repeated cocaine administration, suggesting that this region may be involved in sensitization and particularly in the later phase of expression, versus the earlier phase of sensitization. Bilateral electrolytic lesions of the intermediate zone were made in two groups of rats, which were then repeatedly exposed to cocaine (15 mg/kg, twice/day for 5 days). One group was subsequently given a single cocaine challenge injection (15 mg/kg) after 14 drug-free days, while the other group was challenged after only 2 drug-free days. Two sham surgery groups in which an electrode was lowered but no current was passed served as controls. Results show that lesioned animals as well as sham controls exhibited behavioral sensitization to the drug. However, following a 14-day drug-free period, the lesioned animals showed significant reduction in sensitization, compared to sham controls. Together these findings suggest that the intermediate zone of the NAc shell is indeed involved in the expression phase of behavioral sensitization to cocaine.

Assessment of Surrogate Fractured Rock Networks for Evidence of Complex Behavior

NASA Astrophysics Data System (ADS)

Wood, T. R.; McJunkin, T. R.; Podgorney, R. K.; Glass, R. J.; Starr, R. C.; Stoner, D. L.; Noah, K. S.; LaViolette, R. A.; Fairley, J.

2001-12-01

A complex system or complex process is -"one whose properties are not fully explained by an understanding of its component parts". Results from field experiments conducted at the Hell's Half-Acre field site (Arco, Idaho) suggest that the flow of water in an unsaturated, fractured medium exhibits characteristics of a complex process. A series of laboratory studies is underway with sufficient rigor to determine if complex behavior observed in the field is in fact a fundamental characteristic of water flow in unsaturated, fractured media. As an initial step, a series of four duplicate experiments has been performed using an array of bricks to simulate fractured, unsaturated media. The array consisted of 12 limestone blocks cut to uniform size (5cm x 7 cm x 30 cm) stacked on end 4 blocks wide and 3 blocks high with the interfaces between adjacent blocks representing 3 vertical fractures intersecting 2 horizontal fractures. Water was introduced at three point sources on the upper boundary of the model at the top of the vertical fractures. Water was applied under constant flux at a rate below the infiltration capacity of the system, thus maintaining unsaturated flow conditions. Water was collected from the lower boundary via fiberglass wicks at the bottom of each fracture. An automated system acquired and processed water inflow and outflow data and time-lapse photographic data during each of the 72-hour tests. From these experiments, we see that a few general statements can be made on the overall advance of the wetting front in the surrogate fracture networks. For instance, flow generally converged with depth to the center fracture in the bottom row of bricks. Another observation is that fracture intersections integrate the steady flow in overlying vertical fractures and allow or cause short duration high discharge pulses or "avalanches" of flow to quickly traverse the fracture network below. Smaller scale tests of single fracture and fracture intersections are underway to evaluate a wide array of unit processes that are believed to contribute to complex behavior. Examples of these smaller scale experiments include the role of fracture intersections in integrating a steady inflow to generate giant fluctuations in network discharge; the influence of microbe growth on flow; and the role of geochemistry in alterations of flow paths. Experiments are planned at the meso and field scale to document and understand the controls on self-organized behavior. Modeling is being conducted in parallel with the experiments to understand how simulations can be improved to capture the complexity of fluid flow in fractured rock vadose zones and to make better predictions of contaminant transport.

Experimental design affects social behavior outcomes in adult zebrafish developmentally exposed to lead.

PubMed

Weber, Daniel N; Ghorai, Jugal K

2013-09-01

Lead (Pb(2+)) affects neuronal and endocrine systems that influence social interactions. By providing potential hiding locations, spatial heterogeneity may affect Pb(2+)-induced behavioral outcomes. Therefore, a test chamber was designed into which a refuge could be inserted. The refuge allowed test subjects to escape from the mirror image that stimulated agonistic interactions. Behaviors with a mirror were compared with baseline activity patterns without a mirror. Adult (12-month old) male and female zebrafish, exposed to Pb(2+) (0-10 μM) as embryos (2-24 hours post fertilization), were tested individually for 5 min in each chamber design within 2 h of feeding. Behaviors were evaluated for % time in mirror zone, distance traveled (=activity level), and attacks on the mirror image. When there was no refuge, significant concentration-dependent increases occurred in male % time in mirror zone, activity level, and number of attacks. Increases in these variables were less pronounced in females. When there was a refuge, there were significant differences for males only in activity level and attacks at the higher developmental exposure concentrations; % time in mirror zone followed a similar pattern and level as without refuge. Females displayed Pb(2+)-induced behavioral changes only for attacks on mirror. Since the presence of refuges that is, environmental enrichment, reduced Pb(2+)-induced agonistic behavior in both sexes, experimental spatial design can be considered an important factor when interpreting behavioral outcomes.

Effects of Task Complexity on L2 Writing Behaviors and Linguistic Complexity

ERIC Educational Resources Information Center

Révész, Andrea; Kourtali, Nektaria-Efstathia; Mazgutova, Diana

2017-01-01

This study investigated whether task complexity influences second language (L2) writers' fluency, pausing, and revision behaviors and the cognitive processes underlying these behaviors; whether task complexity affects linguistic complexity of written output; and whether relationships between writing behaviors and linguistic complexity are…

Welding Behavior of Free Machining Stainless Steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

BROOKS,JOHN A.; ROBINO,CHARLES V.; HEADLEY,THOMAS J.

2000-07-24

The weld solidification and cracking behavior of sulfur bearing free machining austenitic stainless steel was investigated for both gas-tungsten arc (GTA) and pulsed laser beam weld processes. The GTA weld solidification was consistent with those predicted with existing solidification diagrams and the cracking response was controlled primarily by solidification mode. The solidification behavior of the pulsed laser welds was complex, and often contained regions of primary ferrite and primary austenite solidification, although in all cases the welds were found to be completely austenite at room temperature. Electron backscattered diffraction (EBSD) pattern analysis indicated that the nature of the base metalmore » at the time of solidification plays a primary role in initial solidification. The solid state transformation of austenite to ferrite at the fusion zone boundary, and ferrite to austenite on cooling may both be massive in nature. A range of alloy compositions that exhibited good resistance to solidification cracking and was compatible with both welding processes was identified. The compositional range is bounded by laser weldability at lower Cr{sub eq}/Ni{sub eq} ratios and by the GTA weldability at higher ratios. It was found with both processes that the limiting ratios were somewhat dependent upon sulfur content.« less

Emotional environments retune the valence of appetitive versus fearful functions in nucleus accumbens

PubMed Central

Reynolds, Sheila M; Berridge, Kent C

2009-01-01

The nucleus accumbens mediates both appetitive motivation for rewards and fearful motivation toward threats, which are generated in part by glutamate-related circuits organized in a keyboard fashion. At rostral sites of the medial shell, localized glutamate disruptions typically generate intense appetitive behaviors in rats, but the disruption incrementally generates fearful behaviors as microinjection sites move more caudally. We found that exposure to stressful environments caused caudal fear-generating zones to expand rostrally, filling ~90% of the shell. Conversely, a preferred home environment caused fear-generating zones to shrink and appetitive-generating zones to expand caudally, filling ~90% of the shell. Thus, the emotional environments retuned the generation of motivation in corticolimbic circuits. PMID:18344996

Evolution of the transcription complex during sporulation of Bacillus subtilis.

PubMed

Brevet, J

1976-01-01

Ribonucleic acid polymerase activity in partially purified extract of cells of Bacillus subtilis harvested at different times (t-1, to, t1, and t2) was studied by zone centrifugation. During the course of sporulation, vegetative sigma-factor activity decreased and the transcription complex lost some of its affinity for active sigma factor. The complex underwent a two-stage change in sedimentation value, from 14.5S in vegetative growth phase to a 13S species very early in sporulation to a 16S species at later times. Two SpoO mutants have been studied by zone centrifugation. One strain, a rifampin-resistant (RfmR) mutant, failed to show any modification of the transcription complex, whereas the other, a Rfms strain, underwent a partial evolution of the transcription complex after to.

Agent-Based Modeling and Simulation in the Dilemma Zone

DOT National Transportation Integrated Search

2015-12-01

The goal of this study is to develop a realistic dilemma zone (DZ) model that considers the effects of factors surrounding vehicles at an intersection, particularly focusing on driver decision-making behavior, such as the presence of a pedestrian cou...

Comninou contact zones for a crack parallel to an interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joseph, P.F.; Gadi, K.S.; Erdogen, F.

One of the interesting features in studying the state of stress in elastic solids near singular points, is the so called complex singularity that gives rise to an apparent local oscillatory behavior in the stress and displacement fields. The region in which this occurs is very small, much smaller than any plastic zone would be, and therefore the oscillations can be ignored in practical applications. Nevertheless, it is a matter of interesting theoretical investigation. The Comninou model of a small contact zone near the crack tip appears to correct for this anomaly within the framework of the linear theory. Thismore » model seems to make sense out of a {open_quotes}solution{close_quotes} that violates the boundary conditions. Erdogan and Joseph, showed (to themselves anyway) that the Comninou model actually has a physical basis. They considered a crack parallel to an interface where the order of the singularity is always real. With great care in solving the singular integral equations, it was shown that as the crack approaches the interface, a pinching effect is observed at the crack tip. This pinching effect proves that in the limit as the crack approaches the interface, the correct way to handle the problem is to consider crack surface contact. In this way, the issue of {open_quotes}oscillations{close_quotes} is never encountered for the interface crack problem. In the present study, the value of h/a that corresponds to crack closure (zero value of the stress intensity factor) will be determined for a given material pair for tensile loading. An asymptotic numerical method for the solution of singular integral equations making use of is used to obtain this result. Results for the crack opening displacement near the tip of the crack and the behavior of the stress intensity factor for cracks very close to the interface are presented. Among other interesting issues to be discussed, this solution shows that the semi-infinite crack parallel to an interface is closed.« less

The Ni-Cu-PGE mineralized Brejo Seco mafic-ultramafic layered intrusion, Riacho do Pontal Orogen: Onset of Tonian (ca. 900 Ma) continental rifting in Northeast Brazil

NASA Astrophysics Data System (ADS)

Salgado, Silas Santos; Ferreira Filho, Cesar Fonseca; Caxito, Fabrício de Andrade; Uhlein, Alexandre; Dantas, Elton Luiz; Stevenson, Ross

2016-10-01

The Brejo Seco mafic-ultramafic Complex (BSC) occurs at the extreme northwest of the Riacho do Pontal Orogen Internal Zone, in the northern margin of the São Francisco Craton in Northeast Brazil. The stratigraphy of this medium size (3.5 km wide and 9 km long) layered intrusion consists of four main zones, from bottom to top: Lower Mafic Zone (LMZ; mainly troctolite), Ultramafic Zone (UZ; mainly dunite and minor troctolite); Transitional Mafic Zone (TMZ; mainly troctolite) and an Upper Mafic Zone (UMZ; gabbro and minor anorthosite, troctolite, and ilmenite magnetitite). Ni-Cu-PGE mineralization occurs at the contact of the UZ with the TMZ, consisting of an up to 50 m thick stratabound zone of disseminated magmatic sulfides. An Mg-tholeiitic affinity to the parental magma is indicated by the geochemical fractionation pattern, by the magmatic crystallization sequence and by the elevated Fo content in olivine. A Smsbnd Nd isochron yielded an age of 903 ± 20 Ma, interpreted as the age of crystallization, with initial εNd = 0.8. Evidence of interaction of the BSC parental magma with sialic crust is given by the Rare Earth and trace element patterns, and by slightly negative and overall low values of εNd(900 Ma) in between -0.2 and +3.3. Contrary to early interpretations that it might constitute an ophiolite complex, based mainly on the geochemistry of the host rocks (Morro Branco metavolcanosedimentary complex), here we interpret the BSC as a typical layered mafic-ultramafic intrusion in continental crust, related to an extensional regime. The BSC is chrono-correlated to mafic dyke swarms, anorogenic granites and thick bimodal volcanics of similar age and tectonic setting in the São Francisco Craton and surrounding areas. Intrusion of the BSC was followed by continued lithospheric thinning, which led to the development of the Paulistana Complex continental rift volcanics around 888 Ma and ultimately to plate separation and the generation of new oceanic crust (Monte Orebe Complex) around 820-650 Ma ago. Thus, the BSC provides a benchmark for the onset of Tonian continental rifting in this area, and is an important marker for the processes of Rodinia breakup and dispersion recorded in South America.

Shear Resistance Variations in Experimentally Sheared Mudstone Granules: A Possible Shear-Thinning and Thixotropic Mechanism

NASA Astrophysics Data System (ADS)

Hu, Wei; Xu, Qiang; Wang, Gonghui; Scaringi, Gianvito; Mcsaveney, Mauri; Hicher, Pierre-Yves

2017-11-01

We present results of ring shear frictional resistance for mudstone granules of different size obtained from a landslide shear zone. Little rate dependency of shear resistance was observed in sand-sized granules in any wet or dry test, while saturated gravel-sized granules exhibited significant and abrupt reversible rate-weakening (from μ = 0.6 to 0.05) at about 2 mm/s. Repeating resistance variations occurred also under constant shear displacement rate. Mudstone granules generate mud as they are crushed and softened. Shear-thinning and thixotropic behavior of the mud can explain the observed behavior: with the viscosity decreasing, the mud can flow through the coarser soil pores and migrate out from the shear zone. This brings new granules into contact which produces new mud. Thus, the process can start over. Similarities between experimental shear zones and those of some landslides in mudstone suggest that the observed behavior may play a role in some landslide kinematics.

Crustal thinning and exhumation along a fossil magma-poor distal margin preserved in Corsica: A hot rift to drift transition?

NASA Astrophysics Data System (ADS)

Beltrando, Marco; Zibra, Ivan; Montanini, Alessandra; Tribuzio, Riccardo

2013-05-01

Rift-related thinning of continental basement along distal margins is likely achieved through the combined activity of ductile shear zones and brittle faults. While extensional detachments responsible for the latest stages of exhumation are being increasingly recognized, rift-related shear zones have never been sampled in ODP sites and have only rarely been identified in fossil distal margins preserved in orogenic belts. Here we report evidence of the Jurassic multi-stage crustal thinning preserved in the Santa Lucia nappe (Alpine Corsica), where amphibolite facies shearing persisted into the rift to drift transition. In this nappe, Lower Permian meta-gabbros to meta-gabbro-norites of the Mafic Complex are separated from Lower Permian granitoids of the Diorite-Granite Complex by a 100-250 m wide shear zone. Fine-grained syn-kinematic andesine + Mg-hornblende assemblages in meta-tonalites of the Diorite-Granite Complex indicate shearing at T = 710 ± 40 °C at P < 0.5 GPa, followed by deformation at greenschist facies conditions. 40Ar/39Ar step-heating analyses on amphiboles reveal that shearing at amphibolite facies conditions possibly began at the Triassic-Jurassic boundary and persisted until t < 188 Ma, with the Mafic Complex cooling rapidly at the footwall of the Diorite-Granite Complex at ca. 165.4 ± 1.7 Ma. Final exhumation to the basin floor was accommodated by low-angle detachment faulting, responsible for the 1-10 m thick damage zone locally capping the Mafic Complex. The top basement surface is onlapped at a low angle by undeformed Mesozoic sandstone, locally containing clasts of footwall rocks. Existing constraints from the neighboring Corsica ophiolites suggest an age of ca. 165-160 Ma for these final stages of exhumation of the Santa Lucia basement. These results imply that middle to lower crustal rocks can be cooled and exhumed rapidly in the last stages of rifting, when significant crustal thinning is accommodated in less than 5 Myr through the consecutive activity of extensional shear zones and detachment faults. High thermal gradients may delay the switch from ductile shear zone- to detachment-dominated crustal thinning, thus preventing the exhumation of middle and lower crustal rocks until the final stages of rifting.

Effect of In-Vehicle Audio Warning System on Driver’s Speed Control Performance in Transition Zones from Rural Areas to Urban Areas

PubMed Central

Yan, Xuedong; Wang, Jiali; Wu, Jiawei

2016-01-01

Speeding is a major contributing factor to traffic crashes and frequently happens in areas where there is a mutation in speed limits, such as the transition zones that connect urban areas from rural areas. The purpose of this study is to investigate the effects of an in-vehicle audio warning system and lit speed limit sign on preventing drivers’ speeding behavior in transition zones. A high-fidelity driving simulator was used to establish a roadway network with the transition zone. A total of 41 participants were recruited for this experiment, and the driving speed performance data were collected from the simulator. The experimental results display that the implementation of the audio warning system could significantly reduce drivers’ operating speed before they entered the urban area, while the lit speed limit sign had a minimal effect on improving the drivers’ speed control performance. Without consideration of different types of speed limit signs, it is found that male drivers generally had a higher operating speed both upstream and in the transition zones and have a larger maximum deceleration for speed reduction than female drivers. Moreover, the drivers who had medium-level driving experience had the higher operating speed and were more likely to have speeding behaviors in the transition zones than those who had low-level and high-level driving experience in the transition zones. PMID:27347990

Synthesis, characterization and anti-microbial activity of phenylurea-formaldehyde resin (PUF) and its polymer metal complexes (PUF-Mn(II)

NASA Astrophysics Data System (ADS)

Ahamad, Tansir; Alshehri, Saad M.

2012-10-01

Phenylurea-formaldehyde polymer (PUF) was synthesized via polycondensation of phenylurea and formaldehyde in basic medium, its polymer-metal complexes [PUF-M(II)] were prepared with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) ions. PUF and PUF-M(II) were characterized with magnetic moment measurements, elemental and spectral (UV-visible, FTIR, 1H-NMR, 13C-NMR and ESR) analysis. The thermal behaviors of all the synthesized polymers were carried out using thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The thermal data revealed that all of the PUF-M(II) showed higher thermal stabilities than the PUF and also ascribed that the PUF-Cu(II) showed better thermal stability than the other PUF-M(II). The kinetic parameters such as activation energy, pre-exponential factor etc., were evaluated for these polymer metal complexes using Coats-Redfern equation. In addition, the antimicrobial activity of the synthesized polymers was tested against several microorganisms using agar well diffusion methods. Among all of the PUF-M(II), the antimicrobial activity of the PUF-Cu(II) showed the highest zone of inhibition because of its higher stability constant and may be used in biomedical applications.

The effect of diagenesis and fluid migration on rare earth element distribution in pore fluids of the northern Cascadia accretionary margin

USGS Publications Warehouse

Kim, Ji-Hoon; Torres, Marta E.; Haley, Brian A.; Kastner, Miriam; Pohlman, John W.; Riedel, Michael; Lee, Young-Joo

2012-01-01

Analytical challenges in obtaining high quality measurements of rare earth elements (REEs) from small pore fluid volumes have limited the application of REEs as deep fluid geochemical tracers. Using a recently developed analytical technique, we analyzed REEs from pore fluids collected from Sites U1325 and U1329, drilled on the northern Cascadia margin during the Integrated Ocean Drilling Program (IODP) Expedition 311, to investigate the REE behavior during diagenesis and their utility as tracers of deep fluid migration. These sites were selected because they represent contrasting settings on an accretionary margin: a ponded basin at the toe of the margin, and the landward Tofino Basin near the shelf's edge. REE concentrations of pore fluid in the methanogenic zone at Sites U1325 and U1329 correlate positively with concentrations of dissolved organic carbon (DOC) and alkalinity. Fractionations across the REE series are driven by preferential complexation of the heavy REEs. Simultaneous enrichment of diagenetic indicators (DOC and alkalinity) and of REEs (in particular the heavy elements Ho to Lu), suggests that the heavy REEs are released during particulate organic carbon (POC) degradation and are subsequently chelated by DOC. REE concentrations are greater at Site U1325, a site where shorter residence times of POC in sulfate-bearing redox zones may enhance REE burial efficiency within sulfidic and methanogenic sediment zones where REE release ensues. Cross-plots of La concentrations versus Cl, Li and Sr delineate a distinct field for the deep fluids (z > 75 mbsf) at Site U1329, and indicate the presence of a fluid not observed at the other sites drilled on the Cascadia margin. Changes in REE patterns, the presence of a positive Eu anomaly, and other available geochemical data for this site suggest a complex hydrology and possible interaction with the igneous Crescent Terrane, located east of the drilled transect.

Fluid-rock interaction recorded in fault rocks of the Nobeoka Thrust, fossilized megasplay fault in an ancient accretionary complex

NASA Astrophysics Data System (ADS)

Hasegawa, R.; Yamaguchi, A.; Fukuchi, R.; Kitamura, Y.; Kimura, G.; Hamada, Y.; Ashi, J.; Ishikawa, T.

2017-12-01

The relationship between faulting and fluid behavior has been in debate. In this study, we clarify the fluid-rock interaction in the Nobeoka Thrust by major/trace element composition analysis using the boring core of the Nobeoka Thrust, an exhumed analogue of an ancient megasplay fault in Shimanto accretionary complex, southwest Japan. The hanging wall and the footwall of the Nobeoka Thrust show difference in lithology and metamorphic grade, and their maximum burial temperature is estimated from vitrinite reflectance analysis to be 320 330°C and 250 270°C, respectively (Kondo et al., 2005). The fault zone was formed in a fluid-rich condition, as evidenced by warm fluid migration suggested by fluid inclusion analysis (Kondo et al., 2005), implosion brecciation accompanied by carbonate precipitation followed by formation of pseudotachylyte (Okamoto et al., 2006), ankerite veins coseismically formed under reducing conditions (Yamaguchi et al., 2011), and quartz veins recording stress rotation in seismic cycles (Otsubo et al., 2016). In this study, first we analyzed the major/trace element composition across the principal slip zone (PSZ) of the Nobeoka Thrust by using fragments of borehole cores penetrated through the Nobeoka Thrust. Many elements fluctuated just above the PSZ, whereas K increase and Na, Si decrease suggesting illitization of plagioclase, as well as positive anomalies in Li and Cs were found within the PSZ. For more detail understanding, we observed polished slabs and thin sections of the PSZ. Although grain size reduction of deformed clast and weak development of foliation were observed entirely in the PSZ by macroscopic observation, remarkable development of composite planar fabric nor evidence of friction melting were absent. In this presentation, we show the result of major/trace element composition corresponding to the internal structure of PSZ, and discuss fluid-rock interaction and its impact to megasplay fault activity in subduction zones.

Paleoseismicity and neotectonics of the Aleutian Subduction Zone—An overview

NASA Astrophysics Data System (ADS)

Carver, Gary; Plafker, George

The Aleutian subduction zone is one of the most seismically active plate boundaries and the source of several of the world's largest historic earthquakes. The structural architecture of the subduction zone varies considerably along its length. At the eastern end is a tectonically complex collision zone where the allochthonous Yakutat terrane is moving northwest into mainland Alaska. West of the collision zone a shallow-dipping subducted plate beneath a wide forearc, nearly orthogonal convergence, and a continental-type subduction regime characterizes the eastern part of the subduction zone. In the central part of the subduction zone, convergence becomes increasingly right oblique and the forearc is divided into a series of large clockwise-rotated fault-bounded blocks. Highly oblique convergence and island arc tectonics characterize the western part of the subduction zone. At the extreme western end of the arc, the relative plate motion is nearly pure strike-slip. A series of great subduction earthquakes ruptured most of the 4000-km length of the subduction zone during a period of several decades in the mid 1900s. The majority of these earthquakes broke multiple segments as defined by the large-scale structure of the overriding plate margin and patterns of historic seismicity. Several of these earthquakes generated Pacific-wide tsunamis and significant damage in the southwestern and south-central regions of Alaska. Characterization of previous subduction earthquakes is important in assessing future seismic and tsunami hazards. However, at present such information is available only for the eastern part of the subduction zone. The 1964 Alaska earthquake (M 9.2) ruptured about ˜950 km of the plate boundary that encompassed the Kodiak and Prince William Sound (PWS) segments. Within this region, nine paleosubduction earthquakes in the past ˜5000 years are recognized on the basis of geologic evidence of sudden land level change and, at some sites, coeval tsunami deposits. Carbon 14-based chronologies indicate recurrence intervals between median calibrated ages for these paleoearthquakes range from 333 to 875 years. The most recent occurred about 489 years ago and broke only the Kodiak segment. During the previous three cycles, both the Kodiak and PWS segments were involved in either multiple-segment ruptures or closely timed pairs of single segment ruptures. Evidence for the earlier paleosubduction earthquakes has been found only at sites in the PWS segment. Thus, future work on the paleoseismicity of other segments would by particular valuable in defining the seismic behavior of the subduction zone.

CAPILLARY ELECTROPHORETIC BEHAVIOR OF SEVEN SULFONYLUREAS

EPA Science Inventory

The electrophoretic behavior of bensulfuron Me, sulfometuron Me, nicosulfuron (Accent), chlorimuron Et, thifensulfuron Me (Harmony), metsulfuron Me, and chlorsulfuron was studied under capillary zone electrophoresis (CZE) and micellar electrokinetic chromatography (MEKC) conditio...

Late Vendian Complexes in the Structure of Metamorphic Basement of the Fore Range Zone, Greater Caucasus

NASA Astrophysics Data System (ADS)

Kamzolkin, V. A.; Latyshev, A. V.; Vidyapin, Yu. P.; Somin, M. L.; Smul'skaya, A. I.; Ivanov, S. D.

2018-05-01

The paper presents new data on the composition, age, and relationships (with host and overlying deposits) of intrusive rocks in the basement of the Fore Range zone (Greater Caucasus), in the Malaya Laba River Basin. The evolutionary features of intrusive units located within the Blyb metamorphic complex are described. It is shown for the first time that the lower levels of this complex are, in a structural sense, outcrops of the Late Vendian basement. The basement is composed of the Balkan Formation and a massif of quartz metadiorites that intrudes it; for the rocks of this massif, ages ranging from 549 ± 7.4 to 574.1 ± 6.7 Ma are obtained for three U-Pb datings by the SHRIMP-II method. The Herzyinan magmatic event is represented by a group of granodiorite intrusions penetrating the Blyb complex on a series of faults extending along its boundary with the Main Range zone. The obtained estimate for the U-Pb age of one of the intrusions (319 ± 3.8 Ma) corresponds to the end of the Serpukhovian stage of the Early Carboniferous.

VOLTAGE CLAMP BEHAVIOR OF IRON-NITRIC ACID SYSTEM AS COMPARED WITH THAT OF NERVE MEMBRANE

PubMed Central

Tasaki, I.; Bak, A. F.

1959-01-01

The current-voltage relation for the surface layer of an iron wire immersed in nitric acid was investigated by the voltage clamp technique. Comparing the phase of nitric acid to the axoplasm and the metallic phase to the external fluid medium for the nerve fiber, a striking analogy was found between the voltage clamp behavior of the iron-nitric acid system and that of the nerve membrane. The current voltage curve was found to consist of three parts: (a) a straight line representing the behavior of the resting (passive) membrane, (b) a straight line representing the fully excited (active) state, and (c) an intermediate zone connecting (a) and (b). It was shown that in the intermediate zone, the surface of iron consisted of a fully active patch (or patches) surrounded by a remaining resting area. The phenomenon corresponding to "repetitive firing of responses under voltage clamp" in the nerve membrane was demonstrated in the intermediate zone. The behavior of the cobalt electrode system was also investigated by the same technique. An attempt was made to interpret the phenomenon of initiation and abolition of an active potential on the basis of the thermodynamics of irreversible processes. PMID:13654740

Microstructure, Tensile Properties and Work Hardening Behavior of GTA-Welded Dual-Phase Steels

NASA Astrophysics Data System (ADS)

Ashrafi, H.; Shamanian, M.; Emadi, R.; Saeidi, N.

2017-03-01

In the present study, microstructure, tensile properties and work hardening behavior of a DP700 steel after gas tungsten arc welding were investigated. Formation of bainite in the fusion zone resulted in a hardness increase compared to that for the base metal (BM), whereas tempering of the pre-existing martensite in the subcritical heat-affected zone (HAZ) led to softening. The GTA-welded joint exhibited a continuous yielding behavior and a yield strength close to that for the BM, while its ultimate tensile strength and total elongation were lower than those for the BM owing to the formation of soft zone in the HAZ. A joint efficiency of about 81% was obtained for the GTA-welded joint, and it failed in the softened HAZ. Analysis of work hardening based on the Kocks-Mecking approach showed one stage of hardening behavior corresponding to the stage III for both the DP700 BM and welded sample. It was also revealed that the DP700 BM has larger values of work hardening exponent and magnitude of work hardening compared with the welded sample. Analysis of fractured surfaces showed that the dominant fracture mode for both the DP700 BM and welded joint was ductile.

Food Seeking in a Risky Environment: A Method for Evaluating Risk and Reward Value in Food Seeking and Consumption in Mice.

PubMed

Lockie, Sarah H; McAuley, Clare V; Rawlinson, Sasha; Guiney, Natalie; Andrews, Zane B

2017-01-01

Most studies that measure food intake in mice do so in the home cage environment. This necessarily means that mice do not engage in food seeking before consumption, a behavior that is ubiquitous in free-living animals. We modified and validated several commonly used anxiety tests to include a palatable food reward within the anxiogenic zone. This allowed us to assess risk-taking behavior in food seeking in mice in response to different metabolic stimuli. We modified the open field test and the light/dark box by placing palatable peanut butter chips within a designated food zone inside the anxiogenic zone of each apparatus. We then assessed parameters of the interaction with the food reward. Fasted mice or mice treated with ghrelin showed increased consumption and increased time spent in the food zone immediately around the food reward compared to ad libitum fed mice or mice treated with saline. However, fasted mice treated with IP glucose before exposure to the behavioral arena showed reduced time in the food zone compared to fasted controls, indicating that acute metabolic signals can modify the assessment of safety in food seeking in a risky environment. The tests described in this study will be useful in assessing risk processing and incentive salience of food reward, which are intrinsic components of food acquisition outside of the laboratory environment, in a range of genetic and pharmacological models.

Corrosion behavior in high heat input welded heat-affected zone of Ni-free high-nitrogen Fe–18Cr–10Mn–N austenitic stainless steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moon, Joonoh, E-mail: mjo99@kims.re.kr; Ha, Heon-Young; Lee, Tae-Ho

2013-08-15

The pitting corrosion and interphase corrosion behaviors in high heat input welded heat-affected zone (HAZ) of a metastable high-nitrogen Fe–18Cr–10Mn–N austenitic stainless steel were explored through electrochemical tests. The HAZs were simulated using Gleeble simulator with high heat input welding condition of 300 kJ/cm and the peak temperature of the HAZs was changed from 1200 °C to 1350 °C, aiming to examine the effect of δ-ferrite formation on corrosion behavior. The electrochemical test results show that both pitting corrosion resistance and interphase corrosion resistance were seriously deteriorated by δ-ferrite formation in the HAZ and their aspects were different with increasingmore » δ-ferrite fraction. The pitting corrosion resistance was decreased by the formation of Cr-depleted zone along δ-ferrite/austenite (γ) interphase resulting from δ-ferrite formation; however it didn't depend on δ-ferrite fraction. The interphase corrosion resistance depends on the total amount of Cr-depleted zone as well as ferrite area and thus continuously decreased with increasing δ-ferrite fraction. The different effects of δ-ferrite fraction on pitting corrosion and interphase corrosion were carefully discussed in terms of alloying elements partitioning in the HAZ based on thermodynamic consideration. - Highlights: • Corrosion behavior in the weld HAZ of high-nitrogen austenitic alloy was studied. • Cr{sub 2}N particle was not precipitated in high heat input welded HAZ of tested alloy. • Pitting corrosion and interphase corrosion show a different behavior. • Pitting corrosion resistance was affected by whether or not δ-ferrite forms. • Interphase corrosion resistance was affected by the total amount of δ-ferrite.« less

Parallel inversion of a massive ERT data set to characterize deep vadose zone contamination beneath former nuclear waste infiltration galleries at the Hanford Site B-Complex (Invited)

NASA Astrophysics Data System (ADS)

Johnson, T.; Rucker, D. F.; Wellman, D.

2013-12-01

The Hanford Site, located in south-central Washington, USA, originated in the early 1940's as part of the Manhattan Project and produced plutonium used to build the United States nuclear weapons stockpile. In accordance with accepted industrial practice of that time, a substantial portion of relatively low-activity liquid radioactive waste was disposed of by direct discharge to either surface soil or into near-surface infiltration galleries such as cribs and trenches. This practice was supported by early investigations beginning in the 1940s, including studies by Geological Survey (USGS) experts, whose investigations found vadose zone soils at the site suitable for retaining radionuclides to the extent necessary to protect workers and members of the general public based on the standards of that time. That general disposal practice has long since been discontinued, and the US Department of Energy (USDOE) is now investigating residual contamination at former infiltration galleries as part of its overall environmental management and remediation program. Most of the liquid wastes released into the subsurface were highly ionic and electrically conductive, and therefore present an excellent target for imaging by Electrical Resistivity Tomography (ERT) within the low-conductivity sands and gravels comprising Hanford's vadose zone. In 2006, USDOE commissioned a large scale surface ERT survey to characterize vadose zone contamination beneath the Hanford Site B-Complex, which contained 8 infiltration trenches, 12 cribs, and one tile field. The ERT data were collected in a pole-pole configuration with 18 north-south trending lines, and 18 east-west trending lines ranging from 417m to 816m in length. The final data set consisted of 208,411 measurements collected on 4859 electrodes, covering an area of 600m x 600m. Given the computational demands of inverting this massive data set as a whole, the data were initially inverted in parts with a shared memory inversion code, which revealed the general footprint of vadose zone contamination beneath infiltration galleries. In 2011, the USDOE commissioned an effort to re-invert the B-Complex ERT data as a whole using a recently developed massively parallel 3D ERT inversion code. The computational mesh included approximately 1.085 million elements and closely honored the 37m of topographic relief as determined by LiDAR imaging. The water table and tank boundaries were also incorporated into the mesh to facilitate regularization disconnects, enabling sharp conductivity contrasts where they occur naturally without penalty. The data were inverted using 1024 processors, requiring 910 Gb of memory and 11.5 hours of computation time. The imaging results revealed previously unrealized detail concerning the distribution and behavior of contaminants migrating through the vadose zone, and are currently being used by site cleanup operators and regulators to understand the origin of a groundwater nitrate plume emerging from one of the infiltration galleries. The results overall demonstrate the utility of high performance computing, unstructured meshing, and custom regularization constraints for optimal processing of massive ERT data sets enabled by modern ERT survey hardware.

Evaluation of the effects of school zone signs and markings on speed reduction: a driving simulator study.

PubMed

Zhao, Xiaohua; Li, Jiahui; Ma, Jianming; Rong, Jian

2016-01-01

Traffic control devices are one of the most significant factors affecting driving behavior. In China, there is a lack of installation guidelines or standards for traffic control devices in school zones. In addition, little research has been done to examine the effects of traffic control devices on driving behavior. Few guidelines have been established for implementing traffic control devices in school zones in China. This research conducted a driving simulator experiment to assess the effects of school zone signs and markings for two different types of schools. The efficiency of these traffic control devices was evaluated using four variables derived from the driving simulation, including average speed, relative speed difference, standard deviation of acceleration, and 85th percentile speed. Results showed that traffic control devices such as the Flashing Beacon and School Crossing Ahead Warning Assembly, the Reduce Speed and School Crossing Warning Assembly, and the School Crossing Ahead Pavement Markings were recommended for school zones adjacent to a major multilane roadway, which is characterized by a median strip, high traffic volume, high-speed traffic and the presence of pedestrian crossing signals. The School Crossing Ahead Pavement Markings were recommended for school zones on a minor two-lane roadway, which is characterized by low traffic volume, low speed, and no pedestrian crossing signals.

Rodingitization and hydration of the oceanic lithosphere as developed in the Leka ophiolite, north central Norway

NASA Astrophysics Data System (ADS)

Austrheim, H.; Prestvik, T.

2008-08-01

Ophiolite complexes in mountain chains may give supplementary information on the hydration of the oceanic lithosphere to that obtained from dredged and drilled samples from the ocean floor. The ultramafic (mantle) and the layered ultramafic to anorthositic (crustal) sequences of the Cambrian (497 Ma) Leka ophiolite are variably serpentinized and chloritized. Grossular-rodingite (rodingite s.s.) has been found over a c.500 m long and tens of meters wide zone in the layered, crustal section of the complex and is developed in both pyroxenites and gabbro/anorthosite layers. Shear zones and meter wide fracture zones, where the rock has developed a fracture cleavage, are oriented at high angel to the layering and these zones were the main conduits for transport of fluid and solute between the various lithologies. Some 5-15 cm thick layers of anorthosite (or leucogabbro) have been rodingitized around such a fractures zone, with the development of three distinct metasomatic zones along the plagioclase layer. A central grossular-dominated zone with clinopyroxene, clinozoisite, prehnite, chlorite and minor titanite (rodingite zone) extends for up to 3 m along strike and gives way to a clinozoisite-dominated zone (typically 0.5 m wide) with additional grossular, clinopyroxene and chlorite which is followed outward by a LILE-enriched zone (LILE-zone) with clinozoisite, phlogopite, K-feldspar, plagioclase and preiswerkite. The LILE-zone extends more than 3 m out from the clinozoisite-dominated zone (Clz-zone). Assuming constant volume, the rodingite formed from the plagioclase layer by addition of 20 g of CaO per 100 g of rock. All Na 2O (c. 2 g) was removed from both rodingite- and Clz-zones. Ti and V increase almost 10× in the rodingite compared to its protolith. K, Ba, Rb and Cs are strongly enriched in the LILE-zone compared to the protolith and suggest interaction with sea water. The lithologies alternating with the plagioclase layers (clinopyroxenite, wehrlite, websterite and dunite) display textures indicating a number of Ca-releasing (Cpx → Chl, Cpx → Srp, Cpx → Amph) and Ca-consuming (Opx → Cpx2, Ol → Cpx2, Cpx1 → Cpx2) reactions. The replacement textures are distributed around fracture and shear zones, with the Ca -releasing reactions in the core and the Ca -consuming reactions in distal parts, forming a metasomatic column out from the fluid pathways. Serpentinization and chloritization of clinopyroxene was the main Ca-source for the rodingitization process. This first description of rodingite in a layered sequence of an ophiolite complex indicates that the hydration of the oceanic lithosphere occurred at various structural levels and was associated with Ca-metasomatism also in places where rodingite s.s. is lacking. The different lithologies exchanged elements through transport on shear and fracture zones.

The mafic-ultramafic complex of Aniyapuram, Cauvery Suture Zone, southern India: Petrological and geochemical constraints for Neoarchean suprasubduction zone tectonics

NASA Astrophysics Data System (ADS)

Yellappa, T.; Venkatasivappa, V.; Koizumi, T.; Chetty, T. R. K.; Santosh, M.; Tsunogae, T.

2014-12-01

Several Precambrian mafic-ultramafic complexes occur along the Cauvery Suture Zone (CSZ) in Southern Granulite Terrain, India. Their origin, magmatic evolution and relationship with the associated high-grade rocks have not been resolved. The Aniyapuram Mafic-Ultramafic Complex (AMUC), the focus of the present study in southern part of the CSZ, is dominantly composed of peridotites, pyroxenites, gabbros, metagabbros/mafic granulites, hornblendites, amphibolites, plagiogranites, felsic granulites and ferruginous cherts. The rock types in the AMUC are structurally emplaced within hornblende gneiss (TTG) basement rocks and are highly deformed. The geochemical signature of the amphibolites indicates tholeiitic affinity for the protolith with magma generation in island arc-setting. N-MORB normalized pattern of the amphibolites show depletion in HFS-elements (P, Zr, Sm, Ti, and Y) and enrichment of LIL-elements (Rb, Ba, Th, Sr) with negative Nb anomalies suggesting involvement of subduction component in the depleted mantle source and formation in a supra-subduction zone tectonic setting. Our new results when correlated with the available age data suggest that the lithological association of AMUC represent the remnants of the Neoarchean oceanic lithosphere.

Barbados: Architecture and implications for accretion

NASA Astrophysics Data System (ADS)

Speed, R. C.; Larue, D. K.

1982-05-01

The island of Barbados exposes the crestal zone of the remarkably broad accretionary prism of the Lesser Antilles foreacrc. The architecture of Barbados is three-tiered: an upper arched cap of Pleistocene reefs that record rapid and differential uplift of the island, an intermediate zone of nappes of mainly abyssal or deep bathyal pelagic rocks, and a basal complex whose lithotypes extend to substantial depth and may be representative of the bulk of the western or inner accretionary prism. The exposed basal complex consists of generally steeply dipping ENE to NE-striking fault-bounded packets which contain rocks of one of three lithic suites: terrigenous (quartzose turbidite and mudstone), debris flow, and hemipelagic (chiefly radiolarite). Present but imcomplete rock dating indicates that the terrigenous and hemipelagic suites and the pelagic rocks of the intermediate zone are age overlapping in Early and Middle Eocene time. Deformation within packets of the basal complex is systematic, pre- or synfault, and indicative of shortening that is generally normal to packet boundaries. A unit of terrigenous materials that probably underwent local resedimentation in the Miocene is recognized in wells, but its relationship to exposed rocks is uncertain. The packet-bounding faults of the basal complex are interpreted to have been primary accretionary surfaces which may have been reactivated by later intraprism movements. Exposed sedimentary rocks of Barbados can be successfully assigned to contemporaneous depositional sites associated with an accretionary prism: terrigenous beds to a trench wedge that was connected to South American sediment sources, debris flow to trench floor or slope basin accumulations of material derived from the lower slope, hemipelagic to Atlantic plain strata, and pelagic rocks of the intermediate zone to deep outer forearc basin sites. The decollement at the base of the intermediate zone is probably due to uplift and arcward motion of the crestal zone of the accretionary prism with respect to the forearc basin during progressive prism growth. Principal uplift of the prism seems to have started, apparently abruptly, in the Miocene. Quaternary uplift of Barbados may be due partly to local diapirism. Paleogene subduction that created the arcward region of the prism probably occurred in a differently configured zone from the present one.

Investigation of the Microstructural, Mechanical and Corrosion Properties of Grade A Ship Steel-Duplex Stainless Steel Composites Produced via Explosive Welding

NASA Astrophysics Data System (ADS)

Kaya, Yakup; Kahraman, Nizamettin; Durgutlu, Ahmet; Gülenç, Behçet

2017-08-01

Grade A ship-building steel-AISI 2304 duplex stainless steel composite plates were manufactured via explosive welding. The AISI 2304 plates were used to clad the Grade A plates. Optical microscopy studies were conducted on the joining interface for characterization of the manufactured composite plates. Notch impact, tensile-shear, microhardness, bending and twisting tests were carried out to determine the mechanical properties of the composites. In addition, the surfaces of fractured samples were examined by scanning electron microscopy (SEM), and neutral salt spray (NSS) and potentiodynamic polarization tests were performed to examine corrosion behavior. Near the explosion zone, the interface was completely flat, but became wavy as the distance from the explosion zone increased. The notch impact tests indicated that the impact strength of the composites decreased with increasing distance from the explosion zone. The SEM studies detected brittle behavior below the impact transition temperature and ductile behavior above this temperature. Microhardness tests revealed that the hardness values increased with increasing distance from the explosion zone and mechanical tests showed that no visible cracking or separation had occurred on the joining interface. The NSS and potentiodynamic polarization tests determined that the AISI 2304 exhibited higher corrosion resistance than the Grade A steel.

Finite Strain Analysis of the Wadi Fatima Shear Zone in Western Arabia, Saudi Arabia

NASA Astrophysics Data System (ADS)

Kassem, O. M. K.; Hamimi, Z.

2018-03-01

Neoproterozoic rocks, Oligocene to Neogene sediments and Tertiary Red Sea rift-related volcanics (Harrat) are three dominant major groups exposed in the Jeddah tectonic terrane in Western Arabia. The basement complex comprises amphibolites, schists, and older and younger granites unconformably overlain by a post-amalgamation volcanosedimentary sequence (Fatima Group) exhibiting post-accretionary thrusting and thrust-related structures. The older granites and/or the amphibolites and schists display mylonitization and shearing in some outcrops, and the observed kinematic indicators indicate dextral monoclinic symmetry along the impressive Wadi Fatima Shear Zone. Finite strain analysis of the mylonitized lithologies is used to interpret the deformation history of the Wadi Fatima Shear Zone. The measured finite strain data demonstrate that the amphibolites, schists, and older granites are mildly to moderately deformed, where XZ (axial ratios in XZ direction) vary from 2.76 to 4.22 and from 2.04 to 3.90 for the Rf/φ and Fry method respectively. The shortening axes ( Z) have subvertical attitude and are associated with subhorizontal foliation. The data show oblate strain ellipsoids in the different rocks in the studied area and indication bulk flattening strain. We assume that the different rock types have similar deformation behavior. In the deformed granite, the strain data are identical in magnitude with those obtained in the Fatima Group volcanosedimentary sequence. Finite strain accumulated without any significant volume change contemporaneously with syn-accretionary transpressive structures. It is concluded that a simple-shear deformation with constant-volume plane strain exists, where displacement is strictly parallel to the shear plane. Furthermore, the contacts between various lithological units in the Wadi Fatima Shear Zone were formed under brittle to semi-ductile deformation conditions.

Precipitation Behaviors of TiN Inclusion in GCr15 Bearing Steel Billet

NASA Astrophysics Data System (ADS)

Tian, Qianren; Wang, Guocheng; Zhao, Yang; Li, Jing; Wang, Qi

2018-06-01

There are many types of non-metallic TiN-based inclusions observed in GCr15 bearing steel, including single-particle TiN, multi-particle polymerized TiN, and complex inclusions like TiN-MnS, TiN-MgO-MgAl2O4 (TiN-MgO-MA), and TiN-MgAl2O4-MnS (TiN-MA-MnS). Thermodynamic calculations suggest that single-particle TiN precipitates dominate the mushy zone of GCr15 bearing steel. Kinetic calculations regarding TiN growth suggest that the final size of the single-particle TiN ranges between 1 and 6 μm in the initial concentration range of [pct Ti] = 0.0060 to 0.0079 and [pct N] = 0.0049 to 0.0070, at 1620 to 1640 K and a local cooling rate of 0.5 to 10 K/s. The multi-particle polymerized TiN are formed by single TiN particles in three stages: single-particle TiN inclusions approach each other drawn by the cavity bridge force (CBF), local active angles consolidate, and neck region sintering occurs. Based on the thermodynamic calculations of TiN, MnS, and MgO precipitation, the formation behaviors of complex inclusions of TiN-MnS, TiN-MgO-MA, and TiN-MA-MnS were investigated.

SENSITIVE PARAMETER EVALUATION FOR A VADOSE ZONE FATE AND TRANSPORT MODEL

EPA Science Inventory

This report presents information pertaining to quantitative evaluation of the potential impact of selected parameters on output of vadose zone transport and fate models used to describe the behavior of hazardous chemicals in soil. The Vadose 2one Interactive Processes (VIP) model...

Precipitation Behavior and Quenching Sensitivity of a Spray Deposited Al-Zn-Mg-Cu-Zr Alloy

PubMed Central

Lei, Qian; Xiao, Zhu; Wang, Mingpu

2017-01-01

Precipitation behavior and the quenching sensitivity of a spray deposited Al-Zn-Mg-Cu-Zr alloy during isothermal heat treatment have been studied systematically. Results demonstrate that both the hardness and the ultimate tensile strength of the studied alloy decreased with the isothermal treatment time at certain temperatures. More notably, the hardness decreases rapidly after the isothermal heat treatment. During isothermal heat treatment processing, precipitates readily nucleated in the medium-temperature zone (250–400 °C), while the precipitation nucleation was scarce in the low-temperature zone (<250 °C) and in the high-temperature zone (>400 °C). Precipitates with sizes of less than ten nanometers would contribute a significant increase in yield strength, while the ones with a larger size than 300 nm would contribute little strengthening effect. Quenching sensitivity is high in the medium-temperature zone (250–400 °C), and corresponding time-temperature-property (TTP) curves of the studied alloy have been established. PMID:28925964

Microstructure and Corrosion Resistance of Laser-Welded Crossed Nitinol Wires.

PubMed

Dong, Peng; Yao, Runhua; Yan, Zheng; Yan, Zhifeng; Wang, Wenxian; He, Xiuli; Zhou, Jun

2018-05-18

Laser welding has been considered to be one of the most promising joining processes for Nitinol medical device manufacturing. Presently, there is still a limited understanding about how laser welding affects the microstructure and the resultant corrosion behaviors. This work aimed to reveal the microstructural factors that influence the corrosion resistance of laser-welded crossed Nitinol joints. The microstructures within various zones of the joints were characterized by using transmission electron microscopy (TEM), and the corrosion behaviors of the joints in 0.9% NaCl and Hank's solutions were studied. The base metal exhibits a single austenite (B2) phase and the highest corrosion resistance. The phase constituent of the fusion zone is the coexistence of the B2 matrix and some precipitates (T₂Ni, TiNi 3, and Ti₃Ni₄ particles), resulting in a slight decrease in corrosion resistance. The heat affected zone (HAZ) shows the austenite matrix but with the precipitation of R-phase, which considerably reduces the corrosion potential, making it the weakest zone.

Fire control method and analytical model for large liquid hydrocarbon pool fires

NASA Technical Reports Server (NTRS)

Fenton, D. L.

1986-01-01

The dominate parameter governing the behavior of a liquid hydrocarbon (JP-5) pool fire is wind speed. The most effective method of controlling wind speed in the vicinity of a large circular (10 m dia.) pool fire is a set of concentric screens located outside the perimeter. Because detailed behavior of the pool fire structure within one pool fire diameter is unknown, an analytical model supported by careful experiments is under development. As a first step toward this development, a regional pool fire model was constructed for the no-wind condition consisting of three zones -- liquid fuel, combustion, and plume -- where the predicted variables are mass burning rate and characteristic temperatures of the combustion and plume zones. This zone pool fire model can be modified to incorporate plume bending by wind, radiation absorption by soot particles, and a different ambient air flow entrainment rate. Results from the zone model are given for a pool diameter of 1.3 m and are found to reproduce values in the literature.

Wire Composition: Its Effect on Metal Disintegration and Particle Formation in Twin-Wire Arc-Spraying Process

NASA Astrophysics Data System (ADS)

Tillmann, W.; Abdulgader, M.

2013-03-01

The wire tips in twin-wire arc-spraying (TWAS) are heated in three different zones. A high-speed camera was used to observe the melting behavior, metal breakup, and particle formation under different operating conditions. In zone (I), the wire tips are melted (liquidus metal) and directly atomized in the form of smaller droplets. Their size is a function of the specific properties of the molten metal and the exerting aerodynamic forces. Zone (II) is directly beneath zone (I) and the origin of the extruded metal sheets at the wire tips. The extruded metal sheets in the case of cored wires are shorter than those observed while using solid wires. In this study, the effects of adjustable parameters and powder filling on melting behavior, particle formation, and process instability were revealed, and a comparison between solid and cored wires was made. The findings can improve the accuracy of the TWAS process modeling.

Non-universal critical exponents in earthquake complex networks

NASA Astrophysics Data System (ADS)

Pastén, Denisse; Torres, Felipe; Toledo, Benjamín A.; Muñoz, Víctor; Rogan, José; Valdivia, Juan Alejandro

2018-02-01

The problem of universality of critical exponents in complex networks is studied based on networks built from seismic data sets. Using two data sets corresponding to Chilean seismicity (northern zone, including the 2014 Mw = 8 . 2 earthquake in Iquique; and central zone without major earthquakes), directed networks for each set are constructed. Connectivity and betweenness centrality distributions are calculated and found to be scale-free, with respective exponents γ and δ. The expected relation between both characteristic exponents, δ >(γ + 1) / 2, is verified for both data sets. However, unlike the expectation for certain scale-free analytical complex networks, the value of δ is found to be non-universal.

Along-strike complex geometry of subduction zones - an experimental approach

NASA Astrophysics Data System (ADS)

Midtkandal, I.; Gabrielsen, R. H.; Brun, J.-P.; Huismans, R.

2012-04-01

Recent knowledge of the great geometric and dynamic complexity insubduction zones, combined with new capacity for analogue mechanical and numerical modeling has sparked a number of studies on subduction processes. Not unexpectedly, such models reveal a complex relation between physical conditions during subduction initiation, strength profile of the subducting plate, the thermo-dynamic conditions and the subduction zones geometries. One rare geometrical complexity of subduction that remains particularly controversial, is the potential for polarity shift in subduction systems. The present experiments were therefore performed to explore the influence of the architecture, strength and strain velocity on complexities in subduction zones, focusing on along-strike variation of the collision zone. Of particular concern were the consequences for the geometry and kinematics of the transition zones between segments of contrasting subduction direction. Although the model design to some extent was inspired by the configuration along the Iberian - Eurasian suture zone, the results are also of significance for other orogens with complex along-strike geometries. The experiments were set up to explore the initial state of subduction only, and were accordingly terminated before slab subduction occurred. The model wasbuilt from layers of silicone putty and sand, tailored to simulate the assumed lithospheric geometries and strength-viscosity profiles along the plate boundary zone prior to contraction, and comprises two 'continental' plates separated by a thinner 'oceanic' plate that represents the narrow seaway. The experiment floats on a substrate of sodiumpolytungstate, representing mantle. 24 experimental runs were performed, varying the thickness (and thus strength) of the upper mantle lithosphere, as well as the strain rate. Keeping all other parameters identical for each experiment, the models were shortened by a computer-controlled jackscrew while time-lapse images were recorded. After completion, the models were saturated with water and frozen, allowing for sectioning and profile inspection. The experiments were invariably characterized by different along-strike patterns of deformation, so that three distinct structural domains could be distinguished in all cases. Model descriptions are subdivided accordingly, including domain CC, simulating a continent-continent collision, domain OC, characterized by continent-ocean-continent collision and domain T, representing the transition zone between domain CC and domain OC. The latter zone varied in width and complexity depending on the contrast in structural style developed in the two other domains; in cases where domain OC developed very differently from domain CC, the transition zone was generally wider and more complex. A typical experiment displayed the following features and strain history: In domain CC two principal thrust sheets are displayed, which obviously developed in an in-sequence foreland-directed fashion. The lowermost detachment nucleated at the base of the High Strength Lithospheric Mantle analogue, whereas the uppermost thrust was anchored within the "lower crust". The two thrusts operated in concert, the surface trace of the deepest dominating in the west, and the shallowest in the east. The kinematic development of domain CC could be subdivided into four stages, including initiation of a symmetrical anticline with a minute amplitude and situated directly above the velocity discontinuity defined by the plate contact (stage 1), contemporaneous development of the two thrusts (stage 2) and an associated asymmetrical anticline (stage 3) with a central collapse graben in the latest phase (stage 4). It is noted that the segment CC as seen in a clear majority of the experiments followed this pattern of development. In contrast, the configuration of domain OC displayed greater variation, and included north and south-directed subduction, folding, growth of pop-up-structures and triangle zones. In the "ocean crust" domain, stage 1 was characterized by the growth of a fault-propagation anticline with an E-W-oriented fold axis, ending with the surfacing of a north-vergent thrust. In stage 2, the contraction was concentrated to the south in the oceanic domain, again ending with the surfacing of a thrust, here with top-south transport. By continued movement (stage 3), the thrust fault propagated towards the east, crossing into the "continental" domain and linking with the fault systems of the segment CC. The structure of domain T is dominated by the interference of faults propagating westwards from the domain CC and eastwards from the domain OC, respectively. The zone of overlap in the experiment was significant, and its central part had the geometry of a double "crocodile structure" (sensuMeissner 1989), separating the two areas of northerly and southerly subduction. Hence, its development is less easily subdivided into stages. Reference: Meissner,R., 1989: Rupture, creep lamellae and crocodiles: happenings in the continental crust. Terra Nova, 1, 17-28.

Hot Ductility Behaviors in the Weld Heat-Affected Zone of Nitrogen-Alloyed Fe-18Cr-10Mn Austenitic Stainless Steels

NASA Astrophysics Data System (ADS)

Moon, Joonoh; Lee, Tae-Ho; Hong, Hyun-Uk

2015-04-01

Hot ductility behaviors in the weld heat-affected zone (HAZ) of nitrogen-alloyed Fe-18Cr-10Mn austenitic stainless steels with different nitrogen contents were evaluated through hot tension tests using Gleeble simulator. The results of Gleeble simulations indicated that hot ductility in the HAZs deteriorated due to the formation of δ-ferrite and intergranular Cr2N particles. In addition, the amount of hot ductility degradation was strongly affected by the fraction of δ-ferrite.

Studies in nonlinear problems of energy. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matkowsky, B.J.

1998-12-01

The author completed a successful research program on Nonlinear Problems of Energy, with emphasis on combustion and flame propagation. A total of 183 papers associated with the grant has appeared in the literature, and the efforts have twice been recognized by DOE`s Basic Science Division for Top Accomplishment. In the research program the author concentrated on modeling, analysis and computation of combustion phenomena, with particular emphasis on the transition from laminar to turbulent combustion. Thus he investigated the nonlinear dynamics and pattern formation in the successive stages of transition. He described the stability of combustion waves, and transitions to wavesmore » exhibiting progressively higher degrees of spatio-temporal complexity. Combustion waves are characterized by large activation energies, so that chemical reactions are significant only in thin layers, termed reaction zones. In the limit of infinite activation energy, the zones shrink to moving surfaces, termed fronts, which must be found during the course of the analysis, so that the problems are moving free boundary problems. The analytical studies were carried out for the limiting case with fronts, while the numerical studies were carried out for the case of finite, though large, activation energy. Accurate resolution of the solution in the reaction zone(s) is essential, otherwise false predictions of dynamical behavior are possible. Since the reaction zones move, and their location is not known a-priori, the author has developed adaptive pseudo-spectral methods, which have proven to be very useful for the accurate, efficient computation of solutions of combustion, and other, problems. The approach is based on a combination of analytical and numerical methods. The numerical computations built on and extended the information obtained analytically. Furthermore, the solutions obtained analytically served as benchmarks for testing the accuracy of the solutions determined computationally. Finally, the computational results suggested new analysis to be considered. A cumulative list of publications citing the grant make up the contents of this report.« less

The child's behavior during inhalational induction and its impact on the anesthesiologist's sevoflurane exposure.

PubMed

Herzog-Niescery, Jennifer; Vogelsang, Heike; Bellgardt, Martin; Botteck, Nikolaj Matthias; Seipp, Hans-Martin; Bartz, Horst; Weber, Thomas Peter; Gude, Philipp

2017-12-01

Sevoflurane is commonly used for inhalational inductions in children, but the personnel's exposure to it is potentially harmful. Guidance to reduce gas pollution refers mainly to technical aspects, but the impact of the child's behavior has not yet been studied. The purpose of this study was to determine how child behavior, according to the Frankl Behavioral Scale, affects the amount of waste sevoflurane in anesthesiologists' breathing zones. Sixty-eight children aged 36-96 months undergoing elective ENT surgery were recruited for this prospective, observational investigation. After oral midazolam premedication (0.5 mg/kg body weight), patients obtained sevoflurane using a facemask with an inspiratory concentration of 8 Vol.% in 100% oxygen (flow 10 L/min). Ventilation was manually supported and a venous catheter was placed. The inspiratory sevoflurane concentration was reduced, and remifentanil and propofol were administered before the facemask was removed and a cuffed tracheal tube inserted. The child's behavior toward the operating room personnel during induction was evaluated by the anesthesiologist (Frankl Behavioral Scale: 1-2 = negative behavior, 3-4 = positive behavior). During induction mean (c¯mean) and maximum (c¯max), sevoflurane concentrations were determined in the anesthesiologist's breathing zone by continuous photoacoustic gas monitoring. Mean and maximum sevoflurane concentrations were c¯mean = 4.38 ± 4.02 p.p.m and c¯max = 70.06 ± 61.08 p.p.m in patients with positive behaviors and sufficient premedications and c¯mean = 12.63 ± 8.66 p.p.m and c¯max = 242.86 ± 139.91 p.p.m in children with negative behaviors and insufficient premedications (c¯mean: P < .001; c¯max: P < .001). Negative behavior was accompanied by significantly higher mean and maximum sevoflurane concentrations in the anesthesiologist's breathing zone compared with children with positive attitudes. Consequently, the status of premedication influences the amount of sevoflurane pollution in the air of operating rooms. © 2017 John Wiley & Sons Ltd.

Chemical and oxygen isotope zonings in garnet from subducted continental crust record mineral replacement and metasomatism

NASA Astrophysics Data System (ADS)

Vho, Alice; Rubatto, Daniela; Regis, Daniele; Baumgartner, Lukas; Bouvier, Anne-Sophie

2017-04-01

Garnet is a key mineral in metamorphic petrology for constraining pressure, temperature and time paths. Garnet can preserve multiple growth stages due to its wide P-T stability field and the relatively slow diffusivity for major and trace elements at sub-solidus temperatures. Pressure-temperature-time-fluid paths of the host rock may be reconstructed by combining metamorphic petrology with microscale trace element and oxygen isotope measurements in garnet. Subduction zones represent relevant geological settings for geochemical investigation of element exchanges during aqueous fluid-rock interactions. The Sesia Zone consists of a complex continental sequence containing a variety of mono-metamorphic and poly-metamorphic lithologies such as metagranitoids, sediments and mafic boudins. The precursor Varisican-Permian amphibolite-facies basement (6-9 kbar 650-850°C; Lardeaux and Spalla, 1991; Robyr et al., 2013) experienced high pressure metamorphism (15-22 kbar 500-550°C; Regis, et al. 2014; Robyr et al., 2013) during Alpine subduction. In different lithologies of the Internal Complex (Eclogitic Micaschist Complex), including metabasites from the Ivozio Complex, Ti-rich metasediments from Val Malone and pre-Alpine Mn-quartzites associated to metagabbros from Cima Bonze, garnet is abundant and shows a variety of complex textures that cannot be reconciled with typical growth zoning, but indicate resorption and replacement processes and possible metasomatism. In-situ, microscale oxygen isotopes analysis of garnet zones was performed by ion microprobe with the SwissSIMS Cameca IMS 1280-HR at University of Lausanne and SHRIMP-SI at the Australian National University. Each sample has a distinct δ18O composition, and the δ18O values show different degrees of variation between domains. Homogeneously low values of < 5‰ are measured in the garnets from the Ivozio Complex metagabbro. Intragrain variations of up to 3.5‰ in the porphyroblasts from Val Malone metasediments, and variations up to 6.5‰ in Cima Bonze garnets suggest significant metasomatic replacement from external fluids. The combination of oxygen isotopes, trace element geochemistry and P-T modelling allows reconstructing the major stages of metasomatism, as well as identifying the nature of the fluid interacting with the rock at each metamorphic stage. REFERENCES Lardeaux, J. M., & Spalla, M. I. (1991). From granulites to eclogites in the Sesia zone (Italian Western Alps): A record of the opening and closure of the Piedmont ocean. Journal of Metamorphic Geology, 9, 35-59. Regis, D., Rubatto, D., Darling, J., Cenki-Tok, B., Zucali, M., & Engi, M. (2014). Multiple metamorphic stages within an eclogite-facies terrane (Sesia Zone, Western Alps) revealed by Th-U-Pb petrochronology. Journal of Petrology, 55(7), 1429-1456. Robyr, M., Darbellay, B., & Baumgartner, L. P. (2014). Matrix-dependent garnet growth in polymetamorphic rocks of the Sesia zone, Italian Alps. Journal of Metamorphic Geology, 32(1), 3-24.

Receiver Function Imaging of Crustal and Lithospheric Structure Beneath the Jalisco Block and Western Michoacan, Mexico.

NASA Astrophysics Data System (ADS)

Reyes Alfaro, G.; Cruz-Atienza, V. M.; Perez-Campos, X.; Reyes Dávila, G. A.

2014-12-01

We used a receiver function technique for imaging western Mexico, a unique area with several active seismic and volcanic zones like the triple junction of Rivera, Cocos and North American plates and the Colima volcano complex (CVC), the most active in Mexico. Clear images of the distribution of the crust and the lithosphere-asthenosphere boundary are obtained using P-to-S receiver functions (RF) from around ~80 broadband stations recorded by the Mapping the Rivera Subduction Zone (MARS), the Colima Volcano Deep Seismic Experiment (CODEX) and a local network (RESCO) that allowed us to considerably increase the teleseismic database used in the project. For imaging, we constructed several 2-D profiles of depth transformed RFs to delineate the seismic discontinuities of the region. Low seismic velocities associated with the Michoacan-Guanajuato and the Mascota-Ayutla-Tapalpa volcanic fields are also observed. Most impressive, a large and well delineated magma body 100 km underneath CVC is recognized along a surely related depression of the moho discontinuity just above it. We bring more tools for a better understanding of the deep processes that ultimately control eruptive behavior in the region.

Evaluation of joint probability density function models for turbulent nonpremixed combustion with complex chemistry

NASA Technical Reports Server (NTRS)

Smith, N. S. A.; Frolov, S. M.; Bowman, C. T.

1996-01-01

Two types of mixing sub-models are evaluated in connection with a joint-scalar probability density function method for turbulent nonpremixed combustion. Model calculations are made and compared to simulation results for homogeneously distributed methane-air reaction zones mixing and reacting in decaying turbulence within a two-dimensional enclosed domain. The comparison is arranged to ensure that both the simulation and model calculations a) make use of exactly the same chemical mechanism, b) do not involve non-unity Lewis number transport of species, and c) are free from radiation loss. The modified Curl mixing sub-model was found to provide superior predictive accuracy over the simple relaxation-to-mean submodel in the case studied. Accuracy to within 10-20% was found for global means of major species and temperature; however, nitric oxide prediction accuracy was lower and highly dependent on the choice of mixing sub-model. Both mixing submodels were found to produce non-physical mixing behavior for mixture fractions removed from the immediate reaction zone. A suggestion for a further modified Curl mixing sub-model is made in connection with earlier work done in the field.

Be together, not the same: Spatiotemporal organization of different cilia types generates distinct transport functions

NASA Astrophysics Data System (ADS)

Nawroth, Janna; Guo, Hanliang; Ruby, Edward; Dabiri, John; McFall-Ngai, Margaret; Kanso, Eva

2016-11-01

Motile cilia are microscopic, hair-like structures on the cell surface that can sense and propel the extracellular fluid environment. Cilia are often thought to be limited to stereotypic morphologies, beat kinematics and non-discriminatory clearance functions, but we find that the spatiotemporal organization of different cilia types and beat behaviors can generate complex flow patterns and transport functions. Here, we present a case study in the Hawaiian bobtail squid where collective ciliary activity and resulting flow fields help recruit symbiont bacteria to the animal host. In particular, we demonstrate empirically and computationally how the squid's internal cilia act like a microfluidic device that actively filters the water for potential bacterial candidates and also provides a sheltered zone allowing for accumulation of mucus and bacteria into a biofilm. Moreover, in this sheltered zone, different cilia-driven flows enhance diffusion of biochemical signals, which could accelerate specific bacteria-host recognition. These results suggest that studying cilia activity on the population level might reveal a diverse range of biological transport and sensing functions. Moreover, understanding cilia as functional building blocks could inspire the design of ciliated robots and devices.

Platinum, palladium, and rhodium analyses of ultramafic and mafic rocks from the Stillwater Complex, Montana

USGS Publications Warehouse

Page, Norman J; Riley, Leonard Benjamin; Haffty, Joseph

1969-01-01

Analyses by a combination fire- assay-solution-optical-emission spectrographic method of 137 rocks from the Stillwater Complex, Mont., indicate that platinum, palladium, and rhodium are preferentially concentrated in chromitite zones. The A chromitite zone (21 samples) has an average of 988.9 ppb (pans per billion, 10-9) Pt, 2290.2 ppb Pd, and 245.9 ppb Rh and reaches a maximum (to date) of 8,000 ppb Pt, 11,000 ppb Pd, and 1,700 ppb Rh.

Wildlife habitats in managed rangelands—the Great Basin of southeastern Oregon: riparian zones.

Treesearch

Jack Ward Thomas; Chris Maser; Jon E. Rodiek

1979-01-01

Riparian zones can be identified by the presence of vegetation that requires free or unbound water or conditions that are more moist than normal (fig. 1) (Franklin and Dyrness 1973, Minore and Smith 1971). Riparian zones can vary considerably in size and vegetative complex because of the many combinations that can be created between water sources (fig. 2) and physical...

Geochemistry and geodynamics of the Mawat mafic complex in the Zagros Suture zone, northeast Iraq

NASA Astrophysics Data System (ADS)

Azizi, Hossein; Hadi, Ayten; Asahara, Yoshihiro; Mohammad, Youssef Osman

2013-12-01

The Iraqi Zagros Orogenic Belt includes two separate ophiolite belts, which extend along a northwest-southeast trend near the Iranian border. The outer belt shows ophiolite sequences and originated in the oceanic ridge or supra-subduction zone. The inner belt includes the Mawat complex, which is parallel to the outer belt and is separated by the Biston Avoraman block. The Mawat complex with zoning structures includes sedimentary rocks with mafic interbedded lava and tuff, and thick mafic and ultramafic rocks. This complex does not show a typical ophiolite sequences such as those in Penjween and Bulfat. The Mawat complex shows evidence of dynamic deformation during the Late Cretaceous. Geochemical data suggest that basic rocks have high MgO and are significantly depleted in LREE relative to HREE. In addition they show positive ɛ Nd values (+5 to+8) and low 87Sr/86Sr ratios. The occurrence of some OIB type rocks, high Mg basaltic rocks and some intermediate compositions between these two indicate the evolution of the Mawat complex from primary and depleted source mantle. The absence of a typical ophiolite sequence and the presence of good compatibility of the source magma with magma extracted from the mantle plume suggests that a mantle plume from the D″ layer is more consistent as the source of this complex than the oceanic ridge or supra-subduction zone settings. Based on our proposed model the Mawat basin represents an extensional basin formed during the Late Paleozoic to younger along the Arabian passive margin oriented parallel to the Neo-Tethys oceanic ridge or spreading center. The Mawat extensional basin formed without creation of new oceanic basement. During the extension, huge volumes of mafic lava were intruded into this basin. This basin was squeezed between the Arabian Plate and Biston Avoraman block during the Late Cretaceous.

Fractal analysis of the spatial distribution of earthquakes along the Hellenic Subduction Zone

NASA Astrophysics Data System (ADS)

Papadakis, Giorgos; Vallianatos, Filippos; Sammonds, Peter

2014-05-01

The Hellenic Subduction Zone (HSZ) is the most seismically active region in Europe. Many destructive earthquakes have taken place along the HSZ in the past. The evolution of such active regions is expressed through seismicity and is characterized by complex phenomenology. The understanding of the tectonic evolution process and the physical state of subducting regimes is crucial in earthquake prediction. In recent years, there is a growing interest concerning an approach to seismicity based on the science of complex systems (Papadakis et al., 2013; Vallianatos et al., 2012). In this study we calculate the fractal dimension of the spatial distribution of earthquakes along the HSZ and we aim to understand the significance of the obtained values to the tectonic and geodynamic evolution of this area. We use the external seismic sources provided by Papaioannou and Papazachos (2000) to create a dataset regarding the subduction zone. According to the aforementioned authors, we define five seismic zones. Then, we structure an earthquake dataset which is based on the updated and extended earthquake catalogue for Greece and the adjacent areas by Makropoulos et al. (2012), covering the period 1976-2009. The fractal dimension of the spatial distribution of earthquakes is calculated for each seismic zone and for the HSZ as a unified system using the box-counting method (Turcotte, 1997; Robertson et al., 1995; Caneva and Smirnov, 2004). Moreover, the variation of the fractal dimension is demonstrated in different time windows. These spatiotemporal variations could be used as an additional index to inform us about the physical state of each seismic zone. As a precursor in earthquake forecasting, the use of the fractal dimension appears to be a very interesting future work. Acknowledgements Giorgos Papadakis wish to acknowledge the Greek State Scholarships Foundation (IKY). References Caneva, A., Smirnov, V., 2004. Using the fractal dimension of earthquake distributions and the slope of the recurrence curve to forecast earthquakes in Colombia. Earth Sci. Res. J., 8, 3-9. Makropoulos, K., Kaviris, G., Kouskouna, V., 2012. An updated and extended earthquake catalogue for Greece and adjacent areas since 1900. Nat. Hazards Earth Syst. Sci., 12, 1425-1430. Papadakis, G., Vallianatos, F., Sammonds, P., 2013. Evidence of non extensive statistical physics behavior of the Hellenic Subduction Zone seismicity. Tectonophysics, 608, 1037-1048. Papaioannou, C.A., Papazachos, B.C., 2000. Time-independent and time-dependent seismic hazard in Greece based on seismogenic sources. Bull. Seismol. Soc. Am., 90, 22-33. Robertson, M.C., Sammis, C.G., Sahimi, M., Martin, A.J., 1995. Fractal analysis of three-dimensional spatial distributions of earthquakes with a percolation interpretation. J. Geophys. Res., 100, 609-620. Turcotte, D.L., 1997. Fractals and chaos in geology and geophysics. Second Edition, Cambridge University Press. Vallianatos, F., Michas, G., Papadakis, G., Sammonds, P., 2012. A non-extensive statistical physics view to the spatiotemporal properties of the June 1995, Aigion earthquake (M6.2) aftershock sequence (West Corinth rift, Greece). Acta Geophys., 60, 758-768.

Delineation systems for temporary traffic barriers in work zones.

DOT National Transportation Integrated Search

1986-01-01

Providing for the safety of traffic traversing construction and maintenance work zones is becoming increasingly complex, and over the past several years, temporary concrete barriers have come into use as a means of protecting work crews as well as mo...

Creep model of unsaturated sliding zone soils and long-term deformation analysis of landslides

NASA Astrophysics Data System (ADS)

Zou, Liangchao; Wang, Shimei; Zhang, Yeming

2015-04-01

Sliding zone soil is a special soil layer formed in the development of a landslide. Its creep behavior plays a significant role in long-term deformation of landslides. Due to rainfall infiltration and reservoir water level fluctuation, the soils in the slide zone are often in unsaturated state. Therefore, the investigation of creep behaviors of the unsaturated sliding zone soils is of great importance for understanding the mechanism of the long-term deformation of a landslide in reservoir areas. In this study, the full-process creep curves of the unsaturated soils in the sliding zone in different net confining pressure, matric suctions and stress levels were obtained from a large number of laboratory triaxial creep tests. A nonlinear creep model for unsaturated soils and its three-dimensional form was then deduced based on the component model theory and unsaturated soil mechanics. This creep model was validated with laboratory creep data. The results show that this creep model can effectively and accurately describe the nonlinear creep behaviors of the unsaturated sliding zone soils. In order to apply this creep model to predict the long-term deformation process of landslides, a numerical model for simulating the coupled seepage and creep deformation of unsaturated sliding zone soils was developed based on this creep model through the finite element method (FEM). By using this numerical model, we simulated the deformation process of the Shuping landslide located in the Three Gorges reservoir area, under the cycling reservoir water level fluctuation during one year. The simulation results of creep displacement were then compared with the field deformation monitoring data, showing a good agreement in trend. The results show that the creeping deformations of landslides have strong connections with the changes of reservoir water level. The creep model of unsaturated sliding zone soils and the findings obtained by numerical simulations in this study are conducive to reveal the mechanisms of the dynamic process of landslide deformation, and serve as an important basis for the prediction and evaluation of landslides.

Red-cockaded woodpecker foraging behavior

Treesearch

D. Craig Rudolph; Richard N. Conner; Richard R. Schaefer; Nancy E. Koerth

2007-01-01

We studied Red-cockaded Woodpeckers (Picoides borealis) to examine the effect of status and gender on foraging behavior. Foraging behavior of breeding pairs extended beyond separation by foraging height to include zones (bole, trunk in crown, primary limb, secondary limb) of the tree used and foraging methods (scaling, probing, excavating). Helper...

Palaeomagnetic study of the Kepezdaǧ and Yamadaǧ volcanic complexes, central Turkey: Neogene tectonic escape and block definition in the central-east Anatolides

NASA Astrophysics Data System (ADS)

Gürsoy, H.; Tatar, O.; Piper, J. D. A.; Koçbulut, F.; Akpınar, Zafer; Huang, Baochun; Roberts, A. P.; Mesci, B. L.

2011-05-01

The Anatolian accretionary collage between Afro-Arabia and Eurasia is currently subject to two tectonic regimes. Ongoing slip of Arabia relative to Africa along the Dead Sea Fault Zone in the east is extruding crustal blocks away from the indenter by a combination of strike-slip and rotation. This zone of compression gives way to an extensional province in western Turkey, which also includes the eastern sector of Aegean Province. Although it is now well established that rotational deformation throughout Anatolia is distributed and differential, the sizes of the blocks involved are poorly understood. As a contribution towards evaluating this issue in central-east Turkey, we report palaeomagnetic study of the mid-Miocene Kepezdağ and Yamadağ volcanic complexes in central-south Anatolia (38-39.5°N, 37.5-39°E). A distributed sample through the Yamadağ complex identifies eruption during an interval of multiple geomagnetic field reversals (40 normal, 36 reversed, 8 intermediate sites) with a selected mean defined by 63 sites of D/ I = 335.4/51.1° ( α95 = 4.4°). The smaller Kepezdağ complex (8 reversed, 4 normal and 1 intermediate site) yields a comparable mean direction from 12 sites of 338.7/49.8° ( α95 = 14.1°). In the context of a range of radiometric age evidence, two thick normal polarity zones within the Yamadağ succession probably correlate with zones C5ACn and C5ADn of the Geomagnetic Polarity Time Scale and imply that the bulk of the volcanic activity took place between ˜15 and 13.5 Ma. Comparison of the palaeomagnetic results with the adjoining major plate indenters shows that the Yamadağ complex has rotated CCW by 29.3 ± 5.2° relative to Eurasia; the much smaller dataset from the Kepezdağ complex indicates a comparable CCW rotation of 26.0 ± 11.8° with respect to Eurasia. The Arabian Indenter has also been rotating CCW since mid Miocene times, and the block incorporating these two volcanic complexes north of the East Anatolian Fault Zone (EAFZ) is determined to have rotated 18.2 ± 6.0° CCW relative to the northern perimeter of Arabia. Comparison with data to the north identifies quasi-uniform rotation across a ˜200 km wide block extending from the Central Anatolian Fault Zone in the northwest to close to the East Anatolian transform fault zone in the south east. Although absence of suitable younger rocks does not permit the timing of this rotation to be determined in the study area, analogies with results from the Sivas Basin suggest that it is young, and followed establishment of the major transform faults. Rotation has evidently taken place around bounding arcuate faults and accompanied westward expulsion as the accretionary collage north of Arabia has been subject to ongoing post-collisional indentation.

Rapid Brownian Motion Primes Ultrafast Reconstruction of Intrinsically Disordered Phe-Gly Repeats Inside the Nuclear Pore Complex

PubMed Central

Moussavi-Baygi, R.; Mofrad, M. R. K.

2016-01-01

Conformational behavior of intrinsically disordered proteins, such as Phe-Gly repeat domains, alters drastically when they are confined in, and tethered to, nan channels. This has challenged our understanding of how they serve to selectively facilitate translocation of nuclear transport receptor (NTR)-bearing macromolecules. Heterogeneous FG-repeats, tethered to the NPC interior, nonuniformly fill the channel in a diameter-dependent manner and adopt a rapid Brownian motion, thereby forming a porous and highly dynamic polymeric meshwork that percolates in radial and axial directions and features two distinguishable zones: a dense hydrophobic rod-like zone located in the center, and a peripheral low-density shell-like zone. The FG-meshwork is locally disrupted upon interacting with NTR-bearing macromolecules, but immediately reconstructs itself between 0.44 μs and 7.0 μs, depending on cargo size and shape. This confers a perpetually-sealed state to the NPC, and is solely due to rapid Brownian motion of FG-repeats, not FG-repeat hydrophobic bonds. Elongated-shaped macromolecules, both in the presence and absence of NTRs, penetrate more readily into the FG-meshwork compared to their globular counterparts of identical volume and surface chemistry, highlighting the importance of the shape effects in nucleocytoplasmic transport. These results can help our understanding of geometrical effects in, and the design of, intelligent and responsive biopolymer-based materials in nanofiltration and artificial nanopores. PMID:27470900

Numerical simulation of the vortical flow around a pitching airfoil

NASA Astrophysics Data System (ADS)

Fu, Xiang; Li, Gaohua; Wang, Fuxin

2017-04-01

In order to study the dynamic behaviors of the flapping wing, the vortical flow around a pitching NACA0012 airfoil is investigated. The unsteady flow field is obtained by a very efficient zonal procedure based on the velocity-vorticity formulation and the Reynolds number based on the chord length of the airfoil is set to 1 million. The zonal procedure divides up the whole computation domain in to three zones: potential flow zone, boundary layer zone and Navier-Stokes zone. Since the vorticity is absent in the potential flow zone, the vorticity transport equation needs only to be solved in the boundary layer zone and Navier-Stokes zone. Moreover, the boundary layer equations are solved in the boundary layer zone. This arrangement drastically reduces the computation time against the traditional numerical method. After the flow field computation, the evolution of the vortices around the airfoil is analyzed in detail.

Pore pressure control on faulting behavior in a block-gouge system

NASA Astrophysics Data System (ADS)

Yang, Z.; Juanes, R.

2016-12-01

Pore fluid pressure in a fault zone can be altered by natural processes (e.g., mineral dehydration and thermal pressurization) and industrial operations involving subsurface fluid injection/extraction for the development of energy and water resources. However, the effect of pore pressure change on the stability and slip motion of a preexisting geologic fault remain poorly understood; yet they are critical for the assessment of seismic risk. In this work, we develop a micromechanical model to investigate the effect of pore pressure on faulting behavior. The model couples pore network fluid flow and mechanics of the solid grains. We conceptualize the fault zone as a gouge layer sandwiched between two blocks; the block material is represented by a group of contact-bonded grains and the gouge is composed of unbonded grains. A pore network is extracted from the particulate pack of the block-gouge system with pore body volumes and pore throat conductivities calculated rigorously based on the geometry of the local pore space. Pore fluid exerts pressure force onto the grains, the motion of which is solved using the discrete element method (DEM). The model updates the pore network regularly in response to deformation of the solid matrix. We study the fault stability in the presence of a pressure inhomogeneity (gradient) across the gouge layer, and compare it with the case of homogeneous pore pressure. We consider both normal and thrust faulting scenarios with a focus on the onset of shear failure along the block-gouge interfaces. Numerical simulations show that the slip behavior is characterized by intermittent dynamics, which is evident in the number of slipping contacts at the block-gouge interfaces and the total kinetic energy of the gouge particles. Numerical results also show that, for the case of pressure inhomogeneity, the onset of slip occurs earlier for the side with higher pressure, and that this onset appears to be controlled by the maximum pressure of both sides of the fault. We conclude that the stability of the fault should be evaluated separately for both sides of the gouge layer, a result that sheds new light on the use of the effective stress principle and the Coulomb failure criterion in evaluating the stability of a complex fault zone.

Unraveling the history of complex zoned garnets from the North Motagua Mélange (Guatemala)

NASA Astrophysics Data System (ADS)

Barickman, M. H.; Martin, C.; Flores, K. E.; Harlow, G. E.; Bonnet, G.

2016-12-01

The Guatemala Suture Zone (GSZ) is situated in central Guatemala, between the North American and Caribbean plates. Two serpentinite mélanges straddle the Motagua Fault system: the North Motagua Mélange (NMM) and the South Motagua Mélange (SMM). In this study, chemically zoned garnet grains from four eclogite blocks from the NMM were analyzed by EMPA for major elements and LA-ICP-MS for trace elements to unravel the geological history of the eclogites. These eclogites typically consist of euhedral to subhedral garnets, partly retrogressed omphacite grains, and accessory minerals such as phengite and epidote as inclusions in garnet. EBSD was employed to examine apparent garnet inclusions in garnet. The garnet grains in NMM eclogites display complex chemical zonations: all grains roughly show a spessartine-rich core, an almandine-rich core and/or intermediate zone, and a pyrope and grossular-rich rim. Additionally, crystal resorption can be observed between the different zones, and the pyrope-grossular rim can display oscillatory zoning. Finally, grossular-rich zones (crystallographically syntactic) within garnet are present in all studied samples. REE and spider diagrams do not show any significant difference in the patterns of the different zones within the garnet, or indicating that the chemical environment from which each garnet zone grew was broadly the same. The lack of significant variation in LILE content indicates that a fluid influx during garnet growth is unlikely. Consequently, we interpret that garnet grains grew in a largely closed system; however, the presence of the grossular-rich zones, argues for occasional excursions into conditions when either two garnets crystallized or Ca-rich overgrowths that were largely resorbed prior to subsequent continued garnet growth.

Functional Constructivism: In Search of Formal Descriptors.

PubMed

Trofimova, Irina

2017-10-01

The Functional Constructivism (FC) paradigm is an alternative to behaviorism and considers behavior as being generated every time anew, based on an individual's capacities, environmental resources and demands. Walter Freeman's work provided us with evidence supporting the FC principles. In this paper we make parallels between gradual construction processes leading to the formation of individual behavior and habits, and evolutionary processes leading to the establishment of biological systems. Referencing evolutionary theory, several formal descriptors of such processes are proposed. These FC descriptors refer to the most universal aspects for constructing consistent structures: expansion of degrees of freedom, integration processes based on internal and external compatibility between systems and maintenance processes, all given in four different classes of systems: (a) Zone of Proximate Development (poorly defined) systems; (b) peer systems with emerging reproduction of multiple siblings; (c) systems with internalized integration of behavioral elements ('cruise controls'); and (d) systems capable of handling low-probability, not yet present events. The recursive dynamics within this set of descriptors acting on (traditional) downward, upward and horizontal directions of evolution, is conceptualized as diagonal evolution, or di-evolution. Two examples applying these FC descriptors to taxonomy are given: classification of the functionality of neuro-transmitters and temperament traits; classification of mental disorders. The paper is an early step towards finding a formal language describing universal tendencies in highly diverse, complex and multi-level transient systems known in ecology and biology as 'contingency cycles.'

Crash simulation of hybrid structures considering the stress and strain rate dependent material behavior of thermoplastic materials

NASA Astrophysics Data System (ADS)

Hopmann, Ch.; Schöngart, M.; Weber, M.; Klein, J.

2015-05-01

Thermoplastic materials are more and more used as a light weight replacement for metal, especially in the automotive industry. Since these materials do not provide the mechanical properties, which are required to manufacture supporting elements like an auto body or a cross bearer, plastics are combined with metals in so called hybrid structures. Normally, the plastics components are joined to the metal structures using different technologies like welding or screwing. Very often, the hybrid structures are made of flat metal parts, which are stiffened by a reinforcement structure made of thermoplastic materials. The loads on these structures are very often impulsive, for example in the crash situation of an automobile. Due to the large stiffness variation of metal and thermoplastic materials, complex states of stress and very high local strain rates occur in the contact zone under impact conditions. Since the mechanical behavior of thermoplastic materials is highly dependent on these types of load, the crash failure of metal plastic hybrid parts is very complex. The problem is that the normally used strain rate dependent elastic/plastic material models are not capable to simulate the mechanical behavior of thermoplastic materials depended on the state of stress. As part of a research project, a method to simulate the mechanical behavior of hybrid structures under impact conditions is developed at the IKV. For this purpose, a specimen for the measurement of mechanical properties dependet on the state of stress and a method for the strain rate depended characterization of thermoplastic materials were developed. In the second step impact testing is performed. A hybrid structure made from a metal sheet and a reinforcement structure of a Polybutylenterephthalat Polycarbonate blend is tested under impact conditions. The measured stress and strain rate depended material data are used to simulate the mechanical behavior of the hybrid structure under highly dynamic load with impact velocities up to 5 m/s. The mechanical behavior of the plastics structure is simulated using a quadratic yield surface, which takes the state of stress and the strain rate into account. The FE model is made from mid surface elements to reduce the computing time.

Orientation dependence of microfracture behavior in a dual-phase high-strength low-alloy steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suh, D.; Lee, S.; Kim, N.J.

1997-02-01

In selecting the processing conditions and evaluating the reliability of structural materials, microscopic observations and identification of the fracture mechanisms in local cracking behavior are required. An important instance in the failure of the local brittle zone (LBZ) in the welding zone. The LBZ, which is very brittle, is the coarse-grained heat-affected zone near the fusion line, a zone known to be critical to the fracture toughness of welded parts. Thus, maintaining stable fracture resistance by predicting the microfracture behavior is important when using high-strength low-alloy (HSLA) steels in offshore structural steel welds. Depending on the thermal cycles involved duringmore » welding, the ferrite/martensite structure can have various morphologies of martensite particles, for example, fibrous and blocky martensite. In summary, in situ SEM fracture tests reveal that in the L-oriented IQ DCB specimen, a microcrack tends to propagate relatively uniformly throughout the ferrite and well-distributed fine fibrous martensite, yielding good elongation with high strength level. Also, the IQ structure in the T orientation shows similar microfracture behavior. On the other hand, in the SQ structure, where blocky-type martensite is mixed with ferrite, strain is localized into shear bands mostly in the ferrite region, and a local microcrack propagates along the strain-localized band formed in the ferrite, resulting in the SQ structure in the T orientation, where the ferrite-martensite bands are parallel to the notch direction, the martensite cannot act as an efficient barrier to microcrack advance, and thus the tensile ductility is decreased.« less

The Relationship of Interpersonal Distances to Television Shot Selection.

ERIC Educational Resources Information Center

Meyrowitz, Joshua

Based on research suggesting spatial zones of proximity in human behavior (individuals have definable zones of intimate, personal, social, and public space), it was hypothesized that "framed shots" of people on television screens would suggest specific distances to the viewer. The hypotheses were that subjects would estimate a greater…

Compositional Zoning and Mn-Cr Systematics in Carbonates from the Y791198 CM2 Carbonaceous Chondrite

NASA Technical Reports Server (NTRS)

Brearley, Adrian J.; Hutcheon, Ian D.; Browning, Lauren

2001-01-01

Cathodoluminescence and microprobe analyses show that carbonates in Y791198 exhibit complex zoning. Cr-Mn dating suggests formation of carbonates 10 Ma after CAI formation Additional information is contained in the original extended abstract..

Investigating Segmentation in Cascadia: Anisotropic Crustal Structure and Mantle Wedge Serpentinization from Receiver Functions

NASA Astrophysics Data System (ADS)

Krueger, Hannah E.; Wirth, Erin A.

2017-10-01

The Cascadia subduction zone exhibits along-strike segmentation in structure, processes, and seismogenic behavior. While characterization of seismic anisotropy can constrain deformation processes at depth, the character of seismic anisotropy in Cascadia remains poorly understood. This is primarily due to a lack of seismicity in the subducting Juan de Fuca slab, which limits shear wave splitting and other seismological analyses that interrogate the fine-scale anisotropic structure of the crust and mantle wedge. We investigate lower crustal anisotropy and mantle wedge structure by computing P-to-S receiver functions at 12 broadband seismic stations along the Cascadia subduction zone. We observe P-to-SV converted energy consistent with previously estimated Moho depths. Several stations exhibit evidence of an "inverted Moho" (i.e., a downward velocity decrease across the crust-mantle boundary), indicative of a serpentinized mantle wedge. Stations with an underlying hydrated mantle wedge appear prevalent from northern Washington to central Oregon, but sparse in southern Oregon and northern California. Transverse component receiver functions are complex, suggesting anisotropic and/or dipping crustal structure. To constrain the orientation of crustal anisotropy we compute synthetic receiver functions using manual forward modeling. We determine that the lower crust shows variable orientations of anisotropy along-strike, with highly complex anisotropy in northern Cascadia, and generally NW-SE and NE-SW orientations of slow-axis anisotropy in central and southern Cascadia, respectively. The orientations of anisotropy from this work generally agree with those inferred from shear wave splitting of tremor studies at similar locations, lending confidence to this relatively new method of inferring seismic anisotropy from slow earthquakes.

Genome-wide ancestry and divergence patterns from low-coverage sequencing data reveal a complex history of admixture in wild baboons

PubMed Central

Wall, Jeffrey D; Schlebusch, Stephen A; Alberts, Susan C; Cox, Laura A; Snyder-Mackler, Noah; Nevonen, Kimberly; Carbone, Lucia; Tung, Jenny

2017-01-01

Naturally occurring admixture has now been documented in every major primate lineage, suggesting its key role in primate evolutionary history. Active primate hybrid zones can provide valuable insight into this process. Here, we investigate the history of admixture in one of the best-studied natural primate hybrid zones, between yellow baboons (Papio cynocephalus) and anubis baboons (Papio anubis) in the Amboseli ecosystem of Kenya. We generated a new genome assembly for yellow baboon and low coverage genome-wide resequencing data from yellow baboons, anubis baboons, and known hybrids (n=44). Using a novel composite likelihood method for estimating local ancestry from low coverage data, we found high levels of genetic diversity and genetic differentiation between the parent taxa, and excellent agreement between genome-scale ancestry estimates and a priori pedigree, life history, and morphology-based estimates (r2=0.899). However, even putatively unadmixed Amboseli yellow individuals carried a substantial proportion of anubis ancestry, presumably due to historical admixture. Further, the distribution of shared versus fixed differences between a putatively unadmixed Amboseli yellow baboon and an unadmixed anubis baboon, both sequenced at high coverage, are inconsistent with simple isolation-migration or equilibrium migration models. Our findings suggest a complex process of intermittent contact that has occurred multiple times in baboon evolutionary history, despite no obvious fitness costs to hybrids or major geographic or behavioral barriers. In combination with the extensive phenotypic data available for baboon hybrids, our results provide valuable context for understanding the history of admixture in primates, including in our own lineage. PMID:27145036

Adaptive identifier for uncertain complex nonlinear systems based on continuous neural networks.

PubMed

Alfaro-Ponce, Mariel; Cruz, Amadeo Argüelles; Chairez, Isaac

2014-03-01

This paper presents the design of a complex-valued differential neural network identifier for uncertain nonlinear systems defined in the complex domain. This design includes the construction of an adaptive algorithm to adjust the parameters included in the identifier. The algorithm is obtained based on a special class of controlled Lyapunov functions. The quality of the identification process is characterized using the practical stability framework. Indeed, the region where the identification error converges is derived by the same Lyapunov method. This zone is defined by the power of uncertainties and perturbations affecting the complex-valued uncertain dynamics. Moreover, this convergence zone is reduced to its lowest possible value using ideas related to the so-called ellipsoid methodology. Two simple but informative numerical examples are developed to show how the identifier proposed in this paper can be used to approximate uncertain nonlinear systems valued in the complex domain.

Microvascular reconstructive surgery in Operations Iraqi and Enduring Freedom: the US military experience performing free flaps in a combat zone.

PubMed

Klem, Christopher; Sniezek, Joseph C; Moore, Brian; Davis, Michael R; Coppit, George; Schmalbach, Cecelia

2013-08-01

Local nationals with complex wounds resulting from traumatic combat injuries during Operations Iraqi Freedom and Enduring Freedom usually must undergo reconstructive surgery in the combat zone. While the use of microvascular free-tissue transfer (free flaps) for traumatic reconstruction is well documented in the literature, various complicating factors exist when these intricate surgical procedures are performed in a theater of war. The microvascular experiences of six military surgeons deployed during a 30-month period between 2006 and 2011 in Iraq and Afghanistan were retrospectively reviewed. Twenty-nine patients presented with complex traumatic wounds. Thirty-one free flaps were performed for the 29 patients. Location of tissue defects included the lower extremity (15), face/neck (8), upper extremity (6). Limb salvage was successful in all but one patient. Six of eight patients with head and neck wounds were tolerating oral intake at the time of discharge. There were three flap losses in 3 patients; two patients who experienced flap loss underwent a successful second free or regional flap. Minor complications occurred in six patients. Microvascular free tissue transfer for complex tissue defects in a combat zone is a critically important task and can improve quality of life for host-nation patients. Major US combat hospitals deployed to a war zone should include personnel who are trained and capable of performing these complex reconstructive procedures and who understand the many nuances of optimizing outcomes in this challenging environment.

Effects of mesoscale structures on the distribution of cephalopod paralarvae in the Gulf of California and adjacent Pacific

NASA Astrophysics Data System (ADS)

Ruvalcaba-Aroche, Erick D.; Sánchez-Velasco, Laura; Beier, Emilio; Godínez, Victor M.; Barton, Eric D.; Pacheco, Ma. Rocío

2018-01-01

Vertical distribution of the cephalopod paralarvae was investigated in relation to a system of two cyclonic and three anticyclonic eddies in the southern Gulf of California and a front in the adjacent Pacific Ocean. Results showed that the preferential habitat for the Sthenoteuthis oualaniensis - Dosidicus gigas "SD-complex" in both regions was the oxygenated surface mixed layer and the thermocline. The highest abundances occurred in of one of the anticyclonic eddies and a frontal zone, which are convergent structures. Enoploteuthid and Pyroteuthid paralarvae both displayed their highest abundances in the thermocline. Pyroteuthids dominated in the cyclonic eddy whereas Enoploteuthidae were less evident in the eddy system. Pyroteuthids were observed on the western (California Current) side of the frontal zone, and Enoploteuthids on its eastern (Gulf of California) side. The octopods and the complex of Ommastrephes-Eucleoteuthis-Hyaloteuthis paralarvae were present below the thermocline. Both groups had a scarce presence in the eddy system and high abundance near the frontal zone. The octopods abounded on the eastern side in association with the low dissolved oxygen concentrations (< 44 μmol kg-1) of Subtropical-Subsurface Water; the complex on the western front side was immersed in California Current Water. It may be concluded that the spawning and early stages of development of these cephalopod groups are associated with particular mesoscale structures of the water masses. For example, the "SD complex" inhabits the surface water masses, preferentially in convergence zones generated by mesoscale activity.

Decoupling of the Assimilation and Fractionation Signatures in a MASH Zone: Evidence from the Sierra Valle Fértil Mafic Zone, Argentina

NASA Astrophysics Data System (ADS)

Walker, B. A., Jr.; Bergantz, G. W.; Otamendi, J.; Ducea, M. N.; Cristofolini, E.

2015-12-01

The Sierra Valle Fértil (SVF) in northern Argentina is a tilted Ordovician fossil arc complex with continuous exposure from paleodepths of ~10 km to ~30 km. The system is layered when viewed at a large scale: shallow, granodiorite plutons give way to a heterogeneous granodiorite-tonalite zone, which in turn grades into a gabbro-tonalite zone at the base of the section. A metapelitic country rock package is interlayered throughout the magmatic complex, allowing for determination of emplacement depths within the section. Our work focuses on the lowermost domain of the SVF, as it preserves what we consider to be a frozen example of a MASH zone. Here, dominant rock types are hornblende gabbronorite and tonalitie variants, which appear to be interfingered as dm- to 10s of m-scale sheets. Mappable ultramafic pods containing dunites, websterites, troctolites, and minor anorthosites are also present. Field relations are consistent with a complex series of intrusive events. Much of the SVF mafic zone compositional array can be modeled by fractional crystallization where the mafic rocks are cumulate assemblages and the intermediate rocks are the daughter magmas. Amphibole and, perhaps more importantly, Fe-Ti oxide crystallization are likely the principal agents of silica enrichment. Metapelitic rocks exposed throughout the SVF are likely the vestiges of a country rock package that was melted (or reacted) and incorporated into SVF magmas, but field and compositional evidence for assimilation is cryptic in the mafic zone. While isotopic data (Sr, Nd, O) seem to implicate crustal contributions to the SVF mafic zone, incompatible major and trace elements typically associated with an "assimilation signature" (e.g., K, Rb, Ba) are sparse. Such elements are abundant in the metapelites and in igneous rocks farther up section. We interpret this isotopic and elemental decoupling as a byproduct of prolonged MASH processes in the lower crust. A high temperature and an increasingly mafic environment likely resulted in the development of a crystal mush inhospitable to crustally contributed incompatible elements. Over time, these elements were thoroughly flushed out of the MASH zone via melt extraction. Isotopes, then, may be the only residual evidence of assimilation within the SVF mafic zone.

Compositional and mineralogical zoning by inward crystallization of mafic magma: evidence from the Guwoon hornblende gabbro-diorite Complex, Hwacheon, Korea.

NASA Astrophysics Data System (ADS)

Park, Y.-R.; Kim, G.-Y.

2009-04-01

The small body, ca. 1.3 by 1.6km, of a hot-air ballon shape hornblende gabbro - diorite Complex, in Gowoonri, Hwacheon, Korea consists of marginal diorite and central hornblende gabbro. The volumetrically dominant hornblende gabbro in the core of the Complex shows a zoned distribution with three layers distinguished by different dominant mafic mineral phases. From the margin toward the core of the hornblende gabbro body, the domintant mafic minerals change from amphibole phenocryst of nearly rounded shape in cross section with pyroxene pseudomorph through prismatic shape of amphibole to polycrystalline biotite aggregates. Systematic variations in geochemical characteristics among three distinct zones of hornblende gabbro body are also observed. From the outer zone toward the core, major oxides such as MnO, MgO, and CaO show a decreasing tendency, whereas total FeO/(total FeO + MgO) value shows an increasing tendency. Concentrations of trace elements also show systematic variations. Where incompatible elements such as Ba and Th increase, compatible elements like Cr and Sc decrease from the margin toward the core. The zonal distribution divided by change in dominant mafic mineral phase from pyroxene through amphibole to biotite, and systematic compositional changes in both major and trace elements from the outer zone toward the core of the hornblende gabbro body suggest that an inward crystallization mechanism played a major role in the formation of the hornblende gabbro in Guwoonri, Hwacheon, Korea.

Shallow subsurface structure of the Wasatch fault, Provo segment, Utah, from integrated compressional and shear-wave seismic reflection profiles with implications for fault structure and development

USGS Publications Warehouse

McBride, J.H.; Stephenson, W.J.; Williams, R.A.; Odum, J.K.; Worley, D.M.; South, J.V.; Brinkerhoff, A.R.; Keach, R.W.; Okojie-Ayoro, A. O.

2010-01-01

Integrated vibroseis compressional and experimental hammer-source, shear-wave, seismic reflection profiles across the Provo segment of the Wasatch fault zone in Utah reveal near-surface and shallow bedrock structures caused by geologically recent deformation. Combining information from the seismic surveys, geologic mapping, terrain analysis, and previous seismic first-arrival modeling provides a well-constrained cross section of the upper ~500 m of the subsurface. Faults are mapped from the surface, through shallow, poorly consolidated deltaic sediments, and cutting through a rigid bedrock surface. The new seismic data are used to test hypotheses on changing fault orientation with depth, the number of subsidiary faults within the fault zone and the width of the fault zone, and the utility of integrating separate elastic methods to provide information on a complex structural zone. Although previous surface mapping has indicated only a few faults, the seismic section shows a wider and more complex deformation zone with both synthetic and antithetic normal faults. Our study demonstrates the usefulness of a combined shallow and deeper penetrating geophysical survey, integrated with detailed geologic mapping to constrain subsurface fault structure. Due to the complexity of the fault zone, accurate seismic velocity information is essential and was obtained from a first-break tomography model. The new constraints on fault geometry can be used to refine estimates of vertical versus lateral tectonic movements and to improve seismic hazard assessment along the Wasatch fault through an urban area. We suggest that earthquake-hazard assessments made without seismic reflection imaging may be biased by the previous mapping of too few faults. ?? 2010 Geological Society of America.

Continuum damage modeling and simulation of hierarchical dental enamel

NASA Astrophysics Data System (ADS)

Ma, Songyun; Scheider, Ingo; Bargmann, Swantje

2016-05-01

Dental enamel exhibits high fracture toughness and stiffness due to a complex hierarchical and graded microstructure, optimally organized from nano- to macro-scale. In this study, a 3D representative volume element (RVE) model is adopted to study the deformation and damage behavior of the fibrous microstructure. A continuum damage mechanics model coupled to hyperelasticity is developed for modeling the initiation and evolution of damage in the mineral fibers as well as protein matrix. Moreover, debonding of the interface between mineral fiber and protein is captured by employing a cohesive zone model. The dependence of the failure mechanism on the aspect ratio of the mineral fibers is investigated. In addition, the effect of the interface strength on the damage behavior is studied with respect to geometric features of enamel. Further, the effect of an initial flaw on the overall mechanical properties is analyzed to understand the superior damage tolerance of dental enamel. The simulation results are validated by comparison to experimental data from micro-cantilever beam testing at two hierarchical levels. The transition of the failure mechanism at different hierarchical levels is also well reproduced in the simulations.

Corrosion behavior of ultrafine-grained AA2024 aluminum alloy produced by cryorolling

NASA Astrophysics Data System (ADS)

Laxman Mani Kanta, P.; Srivastava, V. C.; Venkateswarlu, K.; Paswan, Sharma; Mahato, B.; Das, Goutam; Sivaprasad, K.; Krishna, K. Gopala

2017-11-01

The objectives of this study were to produce ultrafine-grained (UFG) AA2024 aluminum alloy by cryorolling followed by aging and to evaluate its corrosion behavior. Solutionized samples were cryorolled to 85% reduction in thickness. Subsequent aging resulted in a UFG structure with finer precipitates of Al2CuMg in the cryorolled alloy. The (1) solutionized and (2) solutionized and cryorolled samples were uniformly aged at 160°C/24 h and were designated as CGPA and CRPA, respectively; these samples were subsequently subjected to corrosion studies. Potentiodynamic polarization studies in 3.5wt% NaCl solution indicated an increase in corrosion potential and a decrease in corrosion current density for CRPA compared to CGPA. In the case of CRPA, electrochemical impedance spectroscopic studies indicated the presence of two complex passive oxide layers with a higher charge transfer resistance and lower mass loss during intergranular corrosion tests. The improved corrosion resistance of CRPA was mainly attributed to its UFG structure, uniform distribution of fine precipitates, and absence of coarse grain-boundary precipitation and associated precipitate-free zones as compared with the CGPA alloy.

The behavior of the uranium decay chain nuclides and thorium during the flank eruptions of Kilauea (Hawaii) between 1983 and 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reinitz, I.M.; Turekian, K.K.

1991-12-01

The concentrations of members of the {sup 238}U decay chain and {sup 232}Th have been determined for the lavas that erupted on the East Rift Zone of Kilauea Volcano, Hawaii (Puu Oo) between January 1983 and January 1985. There was a decrease during the first 180 days in the abundances of all nuclides, following the behavior of the incompatible elements. ({sup 230}Th/{sup 238}U) varies with ({sup 232}Th/{sup 238}U) yielding a batch process age for the source magma of 127,800 {plus minus} 28,500 (2{omega}) y, similar to East Pacific Rise basalts. No ({sup 226}Ra/{sup 230}Th) disequilibrium was evident at Puu Oomore » although Haleakala and Loihi show significant excesses of ({sup 226}Ra) over ({sup 230}Th). The initial ({sup 210}Pb) excess relative to ({sup 226}Ra) implies strong incompatibility of {sup 210}Pb probably with the help of chloride complexing, and the deficiency in later episodes indicates volatilization from the melt mediated by the formation of volatile chloride compounds.« less

Critical behavior in earthquake energy dissipation

NASA Astrophysics Data System (ADS)

Wanliss, James; Muñoz, Víctor; Pastén, Denisse; Toledo, Benjamín; Valdivia, Juan Alejandro

2017-09-01

We explore bursty multiscale energy dissipation from earthquakes flanked by latitudes 29° S and 35.5° S, and longitudes 69.501° W and 73.944° W (in the Chilean central zone). Our work compares the predictions of a theory of nonequilibrium phase transitions with nonstandard statistical signatures of earthquake complex scaling behaviors. For temporal scales less than 84 hours, time development of earthquake radiated energy activity follows an algebraic arrangement consistent with estimates from the theory of nonequilibrium phase transitions. There are no characteristic scales for probability distributions of sizes and lifetimes of the activity bursts in the scaling region. The power-law exponents describing the probability distributions suggest that the main energy dissipation takes place due to largest bursts of activity, such as major earthquakes, as opposed to smaller activations which contribute less significantly though they have greater relative occurrence. The results obtained provide statistical evidence that earthquake energy dissipation mechanisms are essentially "scale-free", displaying statistical and dynamical self-similarity. Our results provide some evidence that earthquake radiated energy and directed percolation belong to a similar universality class.

Analysis of the Corrosion Behavior of an A-TIG Welded SS 409 Weld Fusion Zone

NASA Astrophysics Data System (ADS)

Vidyarthy, R. S.; Dwivedi, D. K.

2017-11-01

AISI 409 (SS 409) ferritic stainless steel is generally used as the thick gauge section in freight train wagons, in ocean containers, and in sugar refinery equipment. Activating the flux tungsten inert gas (A-TIG) welding process can reduce the welding cost during fabrication of thick sections. However, corrosion behavior of the A-TIG weld fusion zone is a prime concern for this type of steel. In the present work, the effect of the A-TIG welding process parameters on the corrosion behavior of a weld fusion zone made of 8-mm-thick AISI 409 ferritic stainless-steel plate has been analyzed. Potentiodynamic polarization tests were performed to evaluate the corrosion behavior. The maximum corrosion potential ( E corr) was shown by the weld made using a welding current of 215 A, a welding speed of 95 mm/min, and a flux coating density of 0.81 mg/cm2. The minimum E corr was observed in the weld made using a welding current of 190 A, a welding speed of 120 mm/min, and a flux coating density of 1.40 mg/cm2. The current study also presents the inclusive microstructure-corrosion property relationships using the collective techniques of scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffraction.

Titaniferous magnetite in the layered intrusive complex at Lakathah, Kingdom of Saudi Arabia

USGS Publications Warehouse

Martin, Conrad; Roberts, Ralph Jackson; Stoeser, D.B.

1979-01-01

The Lakathah layered intrusive complex about 90 km east of Qunfudhah contains significant resources of low-grade titanium-bearing rock. The complex is about 10 km in diameter and consists of three principal units: an outer syenite ring, an intermediate diorite-gabbro zone, and a central pyroxenite-hornblendite core. The principal mineralization zone is in the ultramafic core of the complex. The titanium is mainly in titaniferous magnetite, but some is in ilmenite intergrown with magnetite and in the titanium-bearing hornblende, kaersutite. The titaniferous magnetite is in concordant lenses and veinlets and is disseminated throughout the host rock. The lenses and veins range from a few centimeters to 3 m in width and are as much as 50 m long. The layered disseminated bodies contain as much as 25 percent magnetite. Exploratory drilling showed that an area 500 by 1000 m contains titaniferous rock averaging about 6.2 percent TiO2. This mineralized zone contains about 175,000,000 tons per 100 m depth. Material of this grade is not commercial at this time, but may be a future resource. Alluvial deposits along the Red Sea near Al Qunfudhah should be tested for possible deposits of titaniferous sand.

Dissolved organic matter dynamics in the oligo/meso-haline zone of wetland-influenced coastal rivers

NASA Astrophysics Data System (ADS)

Maie, Nagamitsu; Sekiguchi, Satoshi; Watanabe, Akira; Tsutsuki, Kiyoshi; Yamashita, Youhei; Melling, Lulie; Cawley, Kaelin M.; Shima, Eikichi; Jaffé, Rudolf

2014-08-01

Wetlands are key components in the global carbon cycle and export significant amounts of terrestrial carbon to the coastal oceans in the form of dissolved organic carbon (DOC). Conservative behavior along the salinity gradient of DOC and chromophoric dissolved organic matter (CDOM) has often been observed in estuaries from their freshwater end-member (salinity = 0) to the ocean (salinity = 35). While the oligo/meso-haline (salinity < 10) tidal zone of upper estuaries has been suggested to be more complex and locally influenced by geomorphological and hydrological features, the environmental dynamics of dissolved organic matter (DOM) and the environmental drivers controlling its source, transport, and fate have scarcely been evaluated. Here, we investigated the distribution patterns of DOC and CDOM optical properties determined by UV absorbance at 254 nm (A254) and excitation-emission matrix (EEM) fluorescence coupled with parallel factor analysis (PARAFAC) along the lower salinity range (salinity < 10) of the oligo/meso-haline zone for three distinct wetland-influenced rivers; namely the Bekanbeushi River, a cool-temperate river with estuarine lake in Hokkaido, Japan, the Harney River, a subtropical river with tidally-submerged mangrove fringe in Florida, USA, and the Judan River, a small, acidic, tropical rainforest river in Borneo, Malaysia. For the first two rivers, a clear decoupling between DOC and A254 was observed, while these parameters showed similar conservative behavior for the third. Three distinct EEM-PARAFAC models established for each of the rivers provided similar spectroscopic characteristics except for some unique fluorescence features observed for the Judan River. The distribution patterns of PARAFAC components suggested that the inputs from plankton and/or submerged aquatic vegetation can be important in the Bekanbeushi River. Further, DOM photo-products formed in the estuarine lake were also found to be transported upstream. In the Harney River, whereas upriver-derived terrestrial humic-like components were mostly distributed conservatively, some of these components were also derived from mangrove inputs in the oligo/meso-haline zone. Interestingly, fluorescence intensities of some terrestrial humic-like components increased with salinity for the Judan River possibly due to changes in the dissociation state of acidic functional groups and/or increase in the fluorescence quantum yield along the salinity gradient. The protein-like and microbial humic-like components were distributed differently between three wetland rivers, implying that interplay between loss to microbial degradation and inputs from diverse sources are different for the three wetland-influenced rivers. The results presented here indicate that upper estuarine oligo/meso-haline regions of coastal wetland rivers are highly dynamic with regard to the biogeochemical behavior of DOM.

Tectonic slicing and mixing processes along the subduction interface: The Sistan example (Eastern Iran)

NASA Astrophysics Data System (ADS)

Bonnet, G.; Agard, P.; Angiboust, S.; Monié, P.; Jentzer, M.; Omrani, J.; Whitechurch, H.; Fournier, M.

2018-06-01

Suture zones preserve metamorphosed relicts of subducted ocean floor later exhumed along the plate interface that can provide critical insights on subduction zone processes. Mélange-like units are exceptionally well-exposed in the Sistan suture (Eastern Iran), which results from the closure of a branch of the Neotethys between the Lut and Afghan continental blocks. High pressure rocks found in the inner part of the suture zone (i.e., Ratuk complex) around Gazik are herein compared to previously studied outcrops along the belt. Detailed field investigations and mapping allow the distinction of two kinds of subduction-related block-in-matrix units: a siliciclastic-matrix complex and a serpentinite-matrix complex. The siliciclastic-matrix complex includes barely metamorphosed blocks of serpentinized peridotite, radiolarite and basalt of maximum greenschist-facies grade (i.e., maximum temperature of 340 °C). The serpentinite-matrix complex includes blocks of various grades and lithologies: mafic eclogites, amphibolitized blueschists, blue-amphibole-bearing metacherts and aegirine-augite-albite rocks. Eclogites reached peak pressure conditions around 530 °C and 2.3 GPa and isothermal retrogression down to 530 °C and 0.9 GPa. Estimation of peak PT conditions for the other rocks are less-well constrained but suggest equilibration at P < 1 GPa. Strikingly similar Ar-Ar ages of 86 ± 3 Ma, along 70 km, are obtained for phengite and amphibole from fourteen eclogite and amphibolitized blueschist blocks. Ages in Gazik are usually younger than further south (e.g., Sulabest), but there is little age difference between the various kinds of rocks. These results (radiometric ages, observed structures and rock types) support a tectonic origin of the serpentinite-matrix mélange and shed light on subduction zone dynamics, particularly on coeval detachment and exhumation mechanisms of slab-derived rocks.

Complex adaptive behavior and dexterous action

PubMed Central

Harrison, Steven J.; Stergiou, Nicholas

2016-01-01

Dexterous action, as conceptualized by Bernstein in his influential ecological analysis of human behavior, is revealed in the ability to flexibly generate behaviors that are adaptively tailored to the demands of the context in which they are embedded. Conceived as complex adaptive behavior, dexterity depends upon the qualities of robustness and degeneracy, and is supported by the functional complexity of the agent-environment system. Using Bernstein’s and Gibson’s ecological analyses of behavior situated in natural environments as conceptual touchstones, we consider the hypothesis that complex adaptive behavior capitalizes upon general principles of self-organization. Here, we outline a perspective in which the complex interactivity of nervous-system, body, and environment is revealed as an essential resource for adaptive behavior. From this perspective, we consider the implications for interpreting the functionality and dysfunctionality of human behavior. This paper demonstrates that, optimal variability, the topic of this special issue, is a logical consequence of interpreting the functionality of human behavior as complex adaptive behavior. PMID:26375932

Bioassessment of the Effluents Discharged from Two Export Oriented Industrial Zones Located in Kelani River Basin, Sri Lanka Using Erythrocytic Responses of the Fish, Nile Tilapia (Oreochromis niloticus).

PubMed

Hemachandra, C K; Pathiratne, A

2017-10-01

Complex effluents originating from diverse industrial processes in industrial zones could pose cytotoxic/genotoxic hazards to biota in the receiving ecosystems which cannot be revealed by conventional monitoring methods. This study assessed potential cytotoxicity/genotoxicity of treated effluents of two industrial zones which are discharged into Kelani river, Sri Lanka combining erythrocytic abnormality tests and comet assay of the tropical model fish, Nile tilapia. Exposure of fish to the effluents induced erythrocytic DNA damage and deformed erythrocytes with serrated membranes, vacuolations, nuclear buds and micronuclei showing cytotoxic/genotoxic hazards in all cases. Occasional exceedance of industrial effluent discharge regulatory limits was noted for color and lead which may have contributed to the observed cytotoxicity/genotoxicity of effluents. The results demonstrate that fish erythrocytic responses could be used as effective bioanalytical tools for cytotoxic/genotoxic hazard assessments of complex effluents of industrial zones for optimization of the waste treatment process in order to reduce biological impacts.

Castro ring zone: a 4,500-km2 fossil hydrothermal system in the Challis volcanic field, central Idaho.

USGS Publications Warehouse

Criss, R.E.; Ekren, E.B.; Hardyman, R.F.

1984-01-01

The largest fossil hydrothermal system occupying a 4500 km2 area in central Idaho is revealed by delta 18O studies. The remains of this meteoric-hydrothermal system are preserved within a sharply bounded, 15 km wide, 70-km-diameter annulus of low delta 18O rock (+2.0 to -8.8per mille) termed the Castro ring zone. The zone is centred on a less depleted (+4.5) core zone consisting of granitic rocks of the Castro pluton. This 700-km2 Eocene subvolcanic batholith has intruded, domed, and hydrothermally metamorphosed a thick sequence of Challis Volcanics, the stratigraphically low rocks in the 2000-km2 Van Horn Peak and the 1000-km2 Thunder Mountain cauldron complexes being most strongly altered. Less extreme 18O depletions occur in the youngest major ash-flow sheets of these complexes, indicating a vertical 18O gradient. Water/rock ratios of geothermal systems are surprisingly insensitive to the circulation scale.-L.-di H.

Monitoring tetracycline through a solid-state nanopore sensor

NASA Astrophysics Data System (ADS)

Zhang, Yuechuan; Chen, Yanling; Fu, Yongqi; Ying, Cuifeng; Feng, Yanxiao; Huang, Qimeng; Wang, Chao; Pei, De-Sheng; Wang, Deqiang

2016-06-01

Antibiotics as emerging environmental contaminants, are widely used in both human and veterinary medicines. A solid-state nanopore sensing method is reported in this article to detect Tetracycline, which is based on Tet-off and Tet-on systems. rtTA (reverse tetracycline-controlled trans-activator) and TRE (Tetracycline Responsive Element) could bind each other under the action of Tetracycline to form one complex. When the complex passes through nanopores with 8 ~ 9 nanometers in diameter, we could detect the concentrations of Tet from 2 ng/mL to 2000 ng/mL. According to the Logistic model, we could define three growth zones of Tetracycline for rtTA and TRE. The slow growth zone is 0-39.5 ng/mL. The rapid growth zone is 39.5-529.7 ng/mL. The saturated zone is > 529.7 ng/mL. Compared to the previous methods, the nanopore sensor could detect and quantify these different kinds of molecule at the single-molecule level.

Time dependent neural network models for detecting changes of state in complex processes: applications in earth sciences and astronomy.

PubMed

Valdés, Julio J; Bonham-Carter, Graeme

2006-03-01

A computational intelligence approach is used to explore the problem of detecting internal state changes in time dependent processes; described by heterogeneous, multivariate time series with imprecise data and missing values. Such processes are approximated by collections of time dependent non-linear autoregressive models represented by a special kind of neuro-fuzzy neural network. Grid and high throughput computing model mining procedures based on neuro-fuzzy networks and genetic algorithms, generate: (i) collections of models composed of sets of time lag terms from the time series, and (ii) prediction functions represented by neuro-fuzzy networks. The composition of the models and their prediction capabilities, allows the identification of changes in the internal structure of the process. These changes are associated with the alternation of steady and transient states, zones with abnormal behavior, instability, and other situations. This approach is general, and its sensitivity for detecting subtle changes of state is revealed by simulation experiments. Its potential in the study of complex processes in earth sciences and astrophysics is illustrated with applications using paleoclimate and solar data.

Results of complex aortic stent grafting of abdominal aortic aneurysms stratified according to the proximal landing zone using the Society for Vascular Surgery classification.

PubMed

Patel, Sanjay D; Constantinou, Jason; Simring, Dominic; Ramirez, Manfred; Agu, Obiekezie; Hamilton, Hamish; Ivancev, Krassi

2015-08-01

Advances in endovascular technology have led to the successful treatment of complex abdominal aortic aneurysms. However, there is currently no consensus on what constitutes a juxtarenal, pararenal, or suprarenal aneurysm. There is emerging evidence that the extent of the aneurysm repair is associated with outcome. We compare the outcomes of 150 consecutive patients treated with a fenestrated or branched stent graft and present the data stratified according to the Society for Vascular Surgery classification based on proximal anatomic landing zones. A prospectively collected database of consecutive patients undergoing fenestrated or branched stent graft insertion in a tertiary center between 2008 and 2013 was retrospectively analyzed. Aneurysms were subdivided into zones according to where the area of proximal seal could be achieved in relation to the visceral arteries. Zone 8 covers the renal arteries, zone 7 covers the superior mesenteric artery, and zone 6 covers the celiac axis. Patient demographics, operative variables, mortality, and major morbidity were analyzed by univariate and multivariate analysis to assess for differences between zones. During the study period, 150 patients were treated. There were 49 in zone 8, 76 in zone 7, and 25 in zone 6. Prior aortic surgery had been performed in 19 patients, which included 11 patients with previous endovascular aneurysm repairs. There was significantly increased blood loss (P < .001), operative time (P < .0001), total hospital stay (P = .018), and intensive care unit stay (P < .0001) as the zones ascended the aorta. There were 14 inpatient deaths recorded across all zones with a 30-day mortality rate of 8%. Logistic regression analysis for 30 day mortality showed a significant increase as the zones ascended (P = .007). Kaplan-Meier analysis showed that 5-year survival significantly deteriorated as the zones ascended (P = .039), with no significant difference in the freedom from reintervention curves between zones (P = .37). We have shown that the extent of the aneurysm repair as determined by the proximal sealing zone is associated with outcome. Mortality, operative duration, blood loss, and hospital stay all significantly increased as the zones ascended. These data also validate the use of the proposed new classification based on aortic anatomy. Copyright © 2015 Society for Vascular Surgery. Published by Elsevier Inc. All rights reserved.

Creep Deformation and Rupture Behavior of Single- and Dual-Pass 316LN Stainless-Steel-Activated TIG Weld Joints

NASA Astrophysics Data System (ADS)

Vijayanand, V. D.; Vasudevan, M.; Ganesan, V.; Parameswaran, P.; Laha, K.; Bhaduri, A. K.

2016-06-01

Creep deformation and rupture behavior of single-pass and dual-pass 316LN stainless steel (SS) weld joints fabricated by an autogenous activated tungsten inert gas welding process have been assessed by performing metallography, hardness, and conventional and impression creep tests. The fusion zone of the single-pass joint consisted of columnar zones adjacent to base metals with a central equiaxed zone, which have been modified extensively by the thermal cycle of the second pass in the dual-pass joint. The equiaxed zone in the single-pass joint, as well as in the second pass of the dual-pass joint, displayed the lowest hardness in the joints. In the dual-pass joint, the equiaxed zone of the first pass had hardness comparable to the columnar zone. The hardness variations in the joints influenced the creep deformation. The equiaxed and columnar zone in the first pass of the dual-pass joint was more creep resistant than that of the second pass. Both joints possessed lower creep rupture life than the base metal. However, the creep rupture life of the dual-pass joint was about twofolds more than that of the single-pass joint. Creep failure in the single-pass joint occurred in the central equiaxed fusion zone, whereas creep cavitation that originated in the second pass was blocked at the weld pass interface. The additional interface and strength variation between two passes in the dual-pass joint provides more restraint to creep deformation and crack propagation in the fusion zone, resulting in an increase in the creep rupture life of the dual-pass joint over the single-pass joint. Furthermore, the differences in content, morphology, and distribution of delta ferrite in the fusion zone of the joints favors more creep cavitation resistance in the dual-pass joint over the single-pass joint with the enhancement of creep rupture life.

Fate and transport of linear alkylbenzenesulfonate in a sewage- contaminated aquifer: A comparison of natural-gradient pulsed tracer tests

USGS Publications Warehouse

Krueger, C.J.; Barber, L.B.; Metge, D.W.; Field, J.A.

1998-01-01

Two natural-gradient tracer tests were conducted to determine the transport and biodegradation behavior of linear alkylbenzenesulfonate (LAS) surfactant under in situ conditions in a sewage-contaminated aquifer. The tests were conducted in two biogeochemically distinct zones of the aquifer: (1) an aerobic uncontaminated zone (oxic zone) and (2) a moderately aerobic, sewage-contaminated zone (transition zone). Chromatographic separation of the surfactant mixture was observed in both zones and attributed to the retardation of the longer alkyl chain homologues during transport. No significant loss of IAS mass was observed for the oxic zone while 20% of the LAS mass injected into the transition zone was removed due to biodegradation. Biodegradation preferentially removed the longer alkyl chain homologues and the external isomers (i.e., 2- and 3-phenyl). The removal of LAS mass coincided with a decrease in dissolved oxygen concentrations, the appearance of LAS metabolites, and an increase in the number of free-living bacteria with a concomitant change in bacteria morphology. The formation of LAS metabolites accounted for 86% of the LAS mass removed in the transition zone. Over the duration of the test, sorption and biodegradation enriched the LAS mixture in the more water-soluble and biologically resistant components.Two natural-gradient tracer tests were conducted to determine the transport and biodegradation behavior of linear alkylbenzenesulfonate (LAS) surfactant under in situ conditions in a sewage-contaminated aquifer. The tests were conducted in two biogeochemically distinct zones of the aquifer: (1) an aerobic uncontaminated zone (oxic zone) and (2) a moderately aerobic, sewage-contaminated zone (transition zone). Chromatographic separation of the surfactant mixture was observed in both zones and attributed to the retardation of the longer alkyl chain homologues during transport. No significant loss of LAS mass was observed for the oxic zone while 20% of the LAS mass injected into the transition zone was removed due to biodegradation. Biodegradation preferentially removed the longer alkyl chain homologues and the external isomers (i.e., 2- and 3-phenyl). The removal of LAS mass coincided with a decrease in dissolved oxygen concentrations, the appearance of LAS metabolites, and an increase in the number of free-living bacteria with a concomitant change in bacteria morphology. The formation of LAS metabolites accounted for 86% of the LAS mass removed in the transition zone. Over the duration of the test, sorption and biodegradation enriched the LAS mixture in the more water-soluble and biologically resistant components.

Drilling the Bushveld Complex- the world's largest layered mafic intrusion

NASA Astrophysics Data System (ADS)

Ashwal, L. D.; Webb, S. J.; Trumbull, R. B.

2013-12-01

The fact that surprising new discoveries can be made in layered mafic intrusions (e.g., subtle 100-150 m cyclicity in apparently homogeneous cumulates over 1000s of m) means that we are still in the first-order characterization phase of understanding these objects. Accordingly, we have secured funding from ICDP for a planning workshop to be held in Johannesburg in early 2014, aimed at scientific drilling of the Bushveld Complex, the world's largest layered mafic intrusion. Science objectives include, but are not limited to: 1. Magma chamber processes & melt evolution. How many melts/magmas/mushes were involved, what were their compositions and how did they interact? What, if anything, is missing from the Complex, and where did it go? Did Bushveld magmatism have an effect upon Earth's atmosphere at 2 Ga? 2. Crust-mantle interactions & origin of Bushveld granitoids. Are Bushveld granites & rhyolites crustal melts, differentiates from the mafic magmas or products of immiscibility? How can the evolved isotopic signatures in the mafic rocks (e.g., epsilon Nd to -8) be understood? 3. Origin of ore deposits. What were the relative roles of gravity settling, magma mixing, immiscibility and hydrothermal fluid transport in producing the PGE, Cr and V deposits? We have identified 3 potential drilling targets representing a total of ~12 km of drill core. Exact locations of drill sites are to be discussed at the workshop. Target A- East-Central Bushveld Complex. We propose 3 overlapping 3 km boreholes that will provide the first roof-to-floor continuous coverage of the Rustenburg Layered Suite. These boreholes will represent a curated, internationally available reference collection of Bushveld material for present and future research. Target B- Southeastern Bushveld Complex. We propose a single borehole of ~2 km depth, collared in Rooiberg felsite, and positioned to intersect the Roof Zone, Upper Zone, Main Zone and floor of the Complex. Amongst other things, this site will evaluate the latest differentiates of the Complex: are they represented by felsic Rooiberg lavas (Van Tongeren & Mathez, 2012 J. Petrol. 51, 1891), or a newly-discovered sequence of hornblende quartz monzonites (Cawthorn, 2013, J. Petrol., in press)? Target C- Northern Lobe of Bushveld Complex. We propose 2 shorter ~500 m boreholes sited to (a) fill in missing stratigraphy of 2 existing deep cores (Bellevue & Moordkopje) including the unique 200 m thick troctolitic horizon in the Main Zone, and (b) to study the transgressive Main Zone - Upper Zone boundary several km north of the Bellevue/Moordkopje sites. All boreholes are intended to provide continuous down-hole geophysical measurements including magnetic susceptibility, density, electrical conductivity and radiometric data. There is also potential to obtain deep fluids and gases for biogeochemical and other studies. All interested geoscientists are welcome to attend the workshop. Watch the ICDP website for announcements (www.icdp-online.org).

Development of a Health Information Technology Acceptance Model Using Consumers’ Health Behavior Intention

PubMed Central

2012-01-01

Background For effective health promotion using health information technology (HIT), it is mandatory that health consumers have the behavioral intention to measure, store, and manage their own health data. Understanding health consumers’ intention and behavior is needed to develop and implement effective and efficient strategies. Objective To develop and verify the extended Technology Acceptance Model (TAM) in health care by describing health consumers’ behavioral intention of using HIT. Methods This study used a cross-sectional descriptive correlational design. We extended TAM by adding more antecedents and mediating variables to enhance the model’s explanatory power and to make it more applicable to health consumers’ behavioral intention. Additional antecedents and mediating variables were added to the hypothetical model, based on their theoretical relevance, from the Health Belief Model and theory of planned behavior, along with the TAM. We undertook structural equation analysis to examine the specific nature of the relationship involved in understanding consumers’ use of HIT. Study participants were 728 members recruited from three Internet health portals in Korea. Data were collected by a Web-based survey using a structured self-administered questionnaire. Results The overall fitness indices for the model developed in this study indicated an acceptable fit of the model. All path coefficients were statistically significant. This study showed that perceived threat, perceived usefulness, and perceived ease of use significantly affected health consumers’ attitude and behavioral intention. Health consumers’ health status, health belief and concerns, subjective norm, HIT characteristics, and HIT self-efficacy had a strong indirect impact on attitude and behavioral intention through the mediators of perceived threat, perceived usefulness, and perceived ease of use. Conclusions An extended TAM in the HIT arena was found to be valid to describe health consumers’ behavioral intention. We categorized the concepts in the extended TAM into 3 domains: health zone, information zone, and technology zone. PMID:23026508

Development of a health information technology acceptance model using consumers' health behavior intention.

PubMed

Kim, Jeongeun; Park, Hyeoun-Ae

2012-10-01

For effective health promotion using health information technology (HIT), it is mandatory that health consumers have the behavioral intention to measure, store, and manage their own health data. Understanding health consumers' intention and behavior is needed to develop and implement effective and efficient strategies. To develop and verify the extended Technology Acceptance Model (TAM) in health care by describing health consumers' behavioral intention of using HIT. This study used a cross-sectional descriptive correlational design. We extended TAM by adding more antecedents and mediating variables to enhance the model's explanatory power and to make it more applicable to health consumers' behavioral intention. Additional antecedents and mediating variables were added to the hypothetical model, based on their theoretical relevance, from the Health Belief Model and theory of planned behavior, along with the TAM. We undertook structural equation analysis to examine the specific nature of the relationship involved in understanding consumers' use of HIT. Study participants were 728 members recruited from three Internet health portals in Korea. Data were collected by a Web-based survey using a structured self-administered questionnaire. The overall fitness indices for the model developed in this study indicated an acceptable fit of the model. All path coefficients were statistically significant. This study showed that perceived threat, perceived usefulness, and perceived ease of use significantly affected health consumers' attitude and behavioral intention. Health consumers' health status, health belief and concerns, subjective norm, HIT characteristics, and HIT self-efficacy had a strong indirect impact on attitude and behavioral intention through the mediators of perceived threat, perceived usefulness, and perceived ease of use. An extended TAM in the HIT arena was found to be valid to describe health consumers' behavioral intention. We categorized the concepts in the extended TAM into 3 domains: health zone, information zone, and technology zone.

Reaction modeling of drainage quality in the Duluth Complex, northern Minnesota, USA

USGS Publications Warehouse

Seal, Robert; Lapakko, Kim; Piatak, Nadine; Woodruff, Laurel G.

2015-01-01

Reaction modeling can be a valuable tool in predicting the long-term behavior of waste material if representative rate constants can be derived from long-term leaching tests or other approaches. Reaction modeling using the REACT program of the Geochemist’s Workbench was conducted to evaluate long-term drainage quality affected by disseminated Cu-Ni-(Co-)-PGM sulfide mineralization in the basal zone of the Duluth Complex where significant resources have been identified. Disseminated sulfide minerals, mostly pyrrhotite and Cu-Fe sulfides, are hosted by clinopyroxene-bearing troctolites. Carbonate minerals are scarce to non-existent. Long-term simulations of up to 20 years of weathering of tailings used two different sets of rate constants: one based on published laboratory single-mineral dissolution experiments, and one based on leaching experiments using bulk material from the Duluth Complex conducted by the Minnesota Department of Natural Resources (MNDNR). The simulations included only plagioclase, olivine, clinopyroxene, pyrrhotite, and water as starting phases. Dissolved oxygen concentrations were assumed to be in equilibrium with atmospheric oxygen. The simulations based on the published single-mineral rate constants predicted that pyrrhotite would be effectively exhausted in less than two years and pH would rise accordingly. In contrast, only 20 percent of the pyrrhotite was depleted after two years using the MNDNR rate constants. Predicted pyrrhotite depletion by the simulation based on the MNDNR rate constant matched well with published results of laboratory tests on tailings. Modeling long-term weathering of mine wastes also can provide important insights into secondary reactions that may influence the permeability of tailings and thereby affect weathering behavior. Both models predicted the precipitation of a variety of secondary phases including goethite, gibbsite, and clay (nontronite).

A method and example of seismically imaging near‐surface fault zones in geologically complex areas using Vp, Vs, and their ratios

USGS Publications Warehouse

Catchings, Rufus D.; Rymer, Michael J.; Goldman, Mark R.; Sickler, Robert R.; Criley, Coyn J.

2014-01-01

The determination of near‐surface (vadose zone and slightly below) fault locations and geometries is important because assessment of ground rupture, strong shaking, geologic slip rates, and rupture histories occurs at shallow depths. However, seismic imaging of fault zones at shallow depths can be difficult due to near‐surface complexities, such as weathering, groundwater saturation, massive (nonlayered) rocks, and vertically layered strata. Combined P‐ and S‐wave seismic‐refraction tomography data can overcome many of the near‐surface, fault‐zone seismic‐imaging problems because of differences in the responses of elastic (bulk and shear) moduli of P and S waves to shallow‐depth, fault‐zone properties. We show that high‐resolution refraction tomography images of P‐ to S‐wave velocity ratios (VP/VS) can reliably identify near‐surface faults. We demonstrate this method using tomography images of the San Andreas fault (SAF) surface‐rupture zone associated with the 18 April 1906 ∼M 7.9 San Francisco earthquake on the San Francisco peninsula in California. There, the SAF cuts through Franciscan mélange, which consists of an incoherent assemblage of greywacke, chert, greenstone, and serpentinite. A near‐vertical zone (∼75° northeast dip) of high P‐wave velocities (up to 3000  m/s), low S‐wave velocities (∼150–600  m/s), high VP/VS ratios (4–8.8), and high Poisson’s ratios (0.44–0.49) characterizes the main surface‐rupture zone to a depth of about 20 m and is consistent with nearby trench observations. We suggest that the combined VP/VSimaging approach can reliably identify most near‐surface fault zones in locations where many other seismic methods cannot be applied.

ION-EXCHANGE METHOD FOR SEPARATING RADIUM FROM RADIUM-BARIUM MIXTURES

DOEpatents

Fuentevilla, M.E.

1959-06-30

An improved process is presented for separating radium from an aqueous feed solution containing radium and barium values and a complexing agent for these metals. In this process a feed solutlon containing radium and barium ions and a complexing agent for said ions ls cycled through an exchange zone in resins. The radiumenriched resin is then stripped of radium values to form a regeneration liquid, a portion of which is collected as an enriched product, the remaining portion being recycled to the exchange zone to further enrich the ion exchange resin in radium.

Quadrupole mass filter: design and performance for operation in stability zone 3.

PubMed

Syed, Sarfaraz U A H; Hogan, Thomas J; Antony Joseph, Mariya J; Maher, Simon; Taylor, Stephen

2013-10-01

The predicted performance of a quadrupole mass filter (QMF) operating in Mathieu stability zone 3 is described in detail using computer simulations. The investigation considers the factors that limit the ultimate maximum resolution (Rmax) and percentage transmission (%Tx), which can be obtained for a given QMF for a particular scan line of operation. The performance curve (i.e., the resolution (R) versus number (N) of radio frequency (rf) cycles experienced by the ions in the mass filter) has been modeled for the upper and lower tip of stability zone 3. The saturation behavior of the performance curve observed in practice for zone 3 is explained. Furthermore, new design equations are presented by examining the intersection of the scan line with stability zone 3. Resolution versus transmission characteristics of stability zones 1 and 3 are compared and the dependence of performance for zones 1 and 3 is related to particular instrument operating parameters.

Mass changes during hydrothermal alteration/mineralization in the gold-bearing Astaneh granitoid, western Iran

NASA Astrophysics Data System (ADS)

Zahra Afshooni, Seyedeh; Esmaeily, Dariush

2010-05-01

The Astaneh granitoid massif, located in western Iran, is a part of Sanandaj-Sirjan structural Zone. This body, mainly consist of granodioritic rocks, is widely affected under hydrothermal alteration and four alteration zones including phyllic (sericitic), chloritic, propylitic and argillic zones could be identified in this area. Four main mineralization- related alteration episodes have been studied in terms of mass transfer and element mobility during the hydrothermal evolution of Astaneh deposit. In order to illustrate these changes quantitatively, isocon plots have been applied. Isocon plots illustrate that Al, Ti, Ga and Tm was relatively immobile during alteration and that mass were essentially conserved during alteration. Phyllic alteration was accompanied by the depletion of Na and Fe and the enrichment of Si and Cu. The loss of Na and Fe reflects the sericitization of alkali feldspar and the destruction of ferromagnesian minerals. The addition of Si is consistent with widespread silicification wich is a major feature of phyllic alteration. All of the HFSE (except in Y), were enriched but all REEs were depleted in this zone. The overall obtained results show that major oxides such as SiO2, Al2O3, Fe2O3, MnO, MgO, CaO, Na2O, K2O, P2O5 and TiO2 and also LOI show dissimilar behaviors in the different zones. All of the LFSE, HFSE and FTSM (except in Cu and Mo) were depleted in argillic alteration but show dissimilar behaviors in the other alteration zones. The results shown strong depletion in REE, in particular LREE, in all of the alteration facies (except in chloritic zone), equivalent fresh rocks. In chloritic zone, compared with HREE, the LREE represent more enrichment.

Textural evolution of plagioclase feldspar across a shear zone: Implications for deformation mechanism and rock strength

NASA Astrophysics Data System (ADS)

Putnis, Andrew; Austrheim, Håkon; Mukai, Hiroki; Putnis, Christine V.

2014-05-01

Caledonian amphibolite facies shear zones developed in granulite facies anorthosites and anorthositic gabbros of the Bergen Arcs, western Norway allow a detailed study of the relationships between fluid-infiltration, mineral reactions, the evolution of microstructure and deformation mechanisms. A sequence of rocks from the relatively pristine granulites into a shear zone has been studied by optical microscopy, EMPA, SEM, EBSD and TEM, focusing on the progressive development of microstructure in the plagioclase feldspars, leading up to their deformation in the shear zone. At the outcrop scale, fluid infiltration into the granulites is marked by a distinct colour change in the plagioclase from lilac/brown to white. This is associated with the breakdown of the intermediate composition plagioclase (~An50) in the granulite to a complex intergrowth of Na-rich and Ca-rich domains. EBSD analysis shows that this intergrowth retains the crystallographic orientation of the parent feldspar, but that the Ca-rich domains contain many low-angle boundaries as well as twin-related domains. Within the shear zone, this complex intergrowth coarsens by grain boundary migration, annihilating grain boundaries but retaining the Na-rich and Ca-rich zoning pattern. Analysis of nearest-neighbour misorientations of feldspar grains in the shear zone demonstrates that local crystallographic preferred orientation (CPO) is inherited from the parent granulite grain orientations. Random pair misorientation angle distributions show that there is no CPO in the shear zone as a whole, nor is there significant shape preferred orientation (SPO) in individual grains. These observations are interpreted in terms of fluid-induced weakening and deformation by dissolution-precipitation (pressure solution) creep.

Zone-tailed Hawk (Buteo albonotatus)

Treesearch

Scott H. Stoleson; Giancarlo Sadoti

2010-01-01

The Zone-tailed Hawk (Buteo albonotatus) might well be dubbed "the Great Pretender" because it so closely resembles the ubiquitous Turkey Vulture (Cathartes aura) in appearance and behavior as to be frequently mistaken for it. In the border regions where it lives, it may be confused as well with another "Mexican" raptor, the Common Black-Hawk (...

Microstructure and Solidification Crack Susceptibility of Al 6014 Molten Alloy Subjected to a Spatially Oscillated Laser Beam.

PubMed

Kang, Minjung; Han, Heung Nam; Kim, Cheolhee

2018-04-23

Oscillating laser beam welding for Al 6014 alloy was performed using a single mode fiber laser and two-axis scanner system. Its effect on the microstructural evolution of the fusion zone was investigated. To evaluate the influence of oscillation parameters, self-restraint test specimens were fabricated with different beam patterns, widths, and frequencies. The behavior of hot cracking propagation was analyzed by high-speed camera and electron backscatter diffraction. The behavior of crack propagation was observed to be highly correlated with the microstructural evolution of the fusion zone. For most oscillation conditions, the microstructure resembled that of linear welds. A columnar structure was formed near the fusion line and an equiaxed structure was generated at its center. The wide equiaxed zone of oscillation welding increased solidification crack susceptibility. For an oscillation with an infinite-shaped scanning pattern at 100 Hz and 3.5 m/min welding speed, the bead width, solidification microstructure, and the width of the equiaxed zone at the center of fusion fluctuated. Furthermore, the equiaxed and columnar regions alternated periodically, which could reduce solidification cracking susceptibility.

Microstructure and Solidification Crack Susceptibility of Al 6014 Molten Alloy Subjected to a Spatially Oscillated Laser Beam

PubMed Central

Kang, Minjung; Han, Heung Nam

2018-01-01

Oscillating laser beam welding for Al 6014 alloy was performed using a single mode fiber laser and two-axis scanner system. Its effect on the microstructural evolution of the fusion zone was investigated. To evaluate the influence of oscillation parameters, self-restraint test specimens were fabricated with different beam patterns, widths, and frequencies. The behavior of hot cracking propagation was analyzed by high-speed camera and electron backscatter diffraction. The behavior of crack propagation was observed to be highly correlated with the microstructural evolution of the fusion zone. For most oscillation conditions, the microstructure resembled that of linear welds. A columnar structure was formed near the fusion line and an equiaxed structure was generated at its center. The wide equiaxed zone of oscillation welding increased solidification crack susceptibility. For an oscillation with an infinite-shaped scanning pattern at 100 Hz and 3.5 m/min welding speed, the bead width, solidification microstructure, and the width of the equiaxed zone at the center of fusion fluctuated. Furthermore, the equiaxed and columnar regions alternated periodically, which could reduce solidification cracking susceptibility. PMID:29690630

Phase 3 geophysical studies in the Wadi Bidah District, Kingdom of Saudi Arabia

USGS Publications Warehouse

Flanigan, V.J.; Sadek, Hamdy; Smith, C.W.

1982-01-01

Detailed geophysical measurements have been made in the Rabathan area, Wadi Bidah district, Kingdom of Saudi Arabia, at the site of diamond drill holes RAB-1, -2, and -3; these measurements suggest that the causative source for the anomalous EM (electromagnetic) and SP (self-potential) responses is probably highly conductive zones of Precambrian siliceous-carbonaceous rocks. Although many of the zones are no more than a few meters wide, they commonly contain 50 to 80 percent carbonaceous material and locally abundant pyrite. In places, several thin layers of highly concentrated carbonaceous material interlayered with chert form a multiple conductive zone that is seen in the geophysical data as complex anomaly patterns. In the geologic environment of Wadi Bidah, massive sulfide-bearing zones cannot be distinguished from siliceous-carbonaceous zones on the basis of the EM-SP responses. In North America in similar environments, complex resistivity methods used in experimental research have successfully discriminated between sulfide and carbonaceous conductors. Tests of such methods in the Wadi Bidah district are recommended. Geologic, geochemical, and geophysical data at the Jabal Mohr prospect suggest the possibility of mineralized rocks at depth over a possible strike length of 400 m.

Open chromatin structures regulate the efficiencies of pre-RC formation and replication initiation in Epstein-Barr virus

PubMed Central

Papior, Peer; Arteaga-Salas, José M.; Günther, Thomas; Grundhoff, Adam

2012-01-01

Whether or not metazoan replication initiates at random or specific but flexible sites is an unsolved question. The lack of sequence specificity in origin recognition complex (ORC) DNA binding complicates genome-scale chromatin immunoprecipitation (ChIP)-based studies. Epstein-Barr virus (EBV) persists as chromatinized minichromosomes that are replicated by the host replication machinery. We used EBV to investigate the link between zones of pre-replication complex (pre-RC) assembly, replication initiation, and micrococcal nuclease (MNase) sensitivity at different cell cycle stages in a genome-wide fashion. The dyad symmetry element (DS) of EBV’s latent origin, a well-established and very efficient pre-RC assembly region, served as an internal control. We identified 64 pre-RC zones that correlate spatially with 57 short nascent strand (SNS) zones. MNase experiments revealed that pre-RC and SNS zones were linked to regions of increased MNase sensitivity, which is a marker of origin strength. Interestingly, although spatially correlated, pre-RC and SNS zones were characterized by different features. We propose that pre-RCs are formed at flexible but distinct sites, from which only a few are activated per single genome and cell cycle. PMID:22891264

Flight response to spatial and temporal correlates informs risk from wind turbines to the California Condor

USGS Publications Warehouse

Poessel, Sharon; Brandt, Joseph; Mendenhall, Laura C.; Braham, Melissa A.; Lanzone, Michael J.; McGann, Andrew J.; Katzner, Todd

2018-01-01

Wind power is a fast-growing energy resource, but wind turbines can kill volant wildlife, and the flight behavior of obligate soaring birds can place them at risk of collision with these structures. We analyzed altitudinal data from GPS telemetry of critically endangered California Condors (Gymnogyps californianus) to assess the circumstances under which their flight behavior may place them at risk from collision with wind turbines. Condor flight behavior was strongly influenced by topography and land cover, and birds flew at lower altitudes and closer to the rotor-swept zone of wind turbines when over ridgelines and steep slopes and over forested and grassland cover types. Condor flight behavior was temporally predictable, and birds flew lower and closer to the rotor-swept zone during early morning and evening hours and during the winter months, when thermal updrafts were weakest. Although condors only occasionally flew at altitudes that placed them in the rotor-swept zone of turbines, they regularly flew near or within wind resource areas preferred by energy developers. Practitioners aiming to mitigate collision risk to this and other soaring bird species of conservation concern can consider the manner in which flight behavior varies temporally and in response to areas of high topographic relief and proximity to nocturnal roosting sites. By contrast, collision risk to large soaring birds from turbines should be relatively lower over flatter and less rugged areas and in habitat used during daytime soaring.

A two-dimensional time domain near zone to far zone transformation

NASA Technical Reports Server (NTRS)

Luebbers, Raymond J.; Ryan, Deirdre; Beggs, John H.; Kunz, Karl S.

1991-01-01

A time domain transformation useful for extrapolating three dimensional near zone finite difference time domain (FDTD) results to the far zone was presented. Here, the corresponding two dimensional transform is outlined. While the three dimensional transformation produced a physically observable far zone time domain field, this is not convenient to do directly in two dimensions, since a convolution would be required. However, a representative two dimensional far zone time domain result can be obtained directly. This result can then be transformed to the frequency domain using a Fast Fourier Transform, corrected with a simple multiplicative factor, and used, for example, to calculate the complex wideband scattering width of a target. If an actual time domain far zone result is required, it can be obtained by inverse Fourier transform of the final frequency domain result.

A two-dimensional time domain near zone to far zone transformation

NASA Technical Reports Server (NTRS)

Luebbers, Raymond J.; Ryan, Deirdre; Beggs, John H.; Kunz, Karl S.

1991-01-01

In a previous paper, a time domain transformation useful for extrapolating 3-D near zone finite difference time domain (FDTD) results to the far zone was presented. In this paper, the corresponding 2-D transform is outlined. While the 3-D transformation produced a physically observable far zone time domain field, this is not convenient to do directly in 2-D, since a convolution would be required. However, a representative 2-D far zone time domain result can be obtained directly. This result can then be transformed to the frequency domain using a Fast Fourier Transform, corrected with a simple multiplicative factor, and used, for example, to calculate the complex wideband scattering width of a target. If an actual time domain far zone result is required it can be obtained by inverse Fourier transform of the final frequency domain result.

Effects of crack tip plastic zone on corrosion fatigue cracking of alloy 690(TT) in pressurized water reactor environments

NASA Astrophysics Data System (ADS)

Xiao, J.; Qiu, S. Y.; Chen, Y.; Fu, Z. H.; Lin, Z. X.; Xu, Q.

2015-01-01

Alloy 690(TT) is widely used for steam generator tubes in pressurized water reactor (PWR), where it is susceptible to corrosion fatigue. In this study, the corrosion fatigue behavior of Alloy 690(TT) in simulated PWR environments was investigated. The microstructure of the plastic zone near the crack tip was investigated and labyrinth structures were observed. The relationship between the crack tip plastic zone and fatigue crack growth rates and the environment factor Fen was illuminated.

Using TLS to Improve Models of Volcano Conduit Processes (Invited)

NASA Astrophysics Data System (ADS)

Connor, C.; Connor, L.

2010-12-01

In volcanology, diverse numerical models of conduit flow have been developed to relate the properties of these flows to processes that occur at the surface during eruptions. Conduit models incorporate varying degrees of complexity and account for the transport properties of magmas, steady-state or transient behavior, and conduit geometry (e.g., 1- to 1.5 D, variable width and erodable conduit walls). Improvement of these models is important if we are to work toward deployment of eruption models at active volcanoes, link these models to geophysical observations (seismic, deformation, gravity) and eventually forecast eruption magnitude. One conclusion of a recent comparison of many conduit models is that next generation models need to better account for interaction of the erupting mixture with surrounding wall rocks (accounting for melting, solidification, and erosion) and better account for the effects of conduit shape on flows. We made progress toward accounting for this interaction by using TLS to map basaltic conduits in a deeply eroded volcanic field, the San Rafael volcanic field, Utah. TLS data were collected with UNAVCO support during a field campaign in summer 2010. A region of approximately 1 x 1 km was imaged from 9 TLS stations. TLS data reveal the exact geometries of several exposed conduits, their relationship to sills and dikes, and dramatic change in reflectivity of the Entrada sandstone country rock with alteration. The TLS data are particularly good for (a) quantifying rapid change in conduit shape and area as a function of height, (b) differentiating breccias zones (complex mixing zones along conduit margins) from areas of late stage intrusion, (c) imaging complexity of sill geometry near conduits, illustrating the mechanical and perhaps geochemical interaction between sills and conduits in volcanic fields. Overall, application of TLS in this volcanic field has resulted in substantial improvement in our models of volcanic conduit formation, growth, and interaction with shallow magma storage systems.

Petrography and geochemistry of clastic rocks within the Inthanon zone, northern Thailand: Implications for Paleo-Tethys subduction and convergence

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Kunii, Miyuki; Hisada, Ken-ichiro; Ueno, Katsumi; Kamata, Yoshihito; Srichan, Weerapan; Charusiri, Punya; Charoentitirat, Thasinee; Watarai, Megumi; Adachi, Yoshiko; Kurihara, Toshiyuki

2012-11-01

The provenance, source rock compositions, and sediment supply system for a convergence zone of the Paleo-Tethys were reconstructed based on the petrography and geochemistry of clastic rocks of the Inthanon Zone, northern Thailand. The clastic rocks are classified into two types based on field and microscopic observations, the modal composition of sandstone, and mineral compositions: (1) lithic sandstone and shale within mélange in a Permo-Triassic accretionary complex; and (2) Carboniferous quartzose sandstone and mudstone within the Sibumasu Block. Geochemical data indicate that the clastic rocks of the mélange were derived from continental island arc and continental margin settings, which correspond to felsic volcanic rocks within the Sukhothai Zone and quartz-rich fragments within the Indochina Block, respectively. The results of a mixing model indicate the source rocks were approximately 35% volcanic rocks of the Sukhothai Zone and 65% craton sandstone and upper continental crust of the Indochina Block. In contrast, Carboniferous quartzose sedimentary rocks within the Sibumasu Block originated from a continental margin, without a contribution from volcanic rocks. In terms of Paleo-Tethys subduction, a continental island arc in the Sukhothai Zone evolved in tandem with Late Permian-Triassic forearc basins and volcanic activity during the Middle-early Late Triassic. The accretionary complex formed contemporaneously with the evolution of continental island arc during the Permo-Triassic, supplied with sediment from the Sukhothai Zone and the Indochina Block.

Age and petrogenesis of the Diana Complex, Adirondack Mountains, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant, N.; Yang, Yingping; Cliff, R.

1992-01-01

U-Pb zircon data show that the Diana Complex was emplaced 1152[plus minus]12 Ma ago along the Carthage-Colton Mylonite Zone (CCMZ), that marks the boundary between the Adirondack Highlands and the Lowlands. The tectonic setting of the Complex is uncertain because granitoid plutons of the same age were emplaced under syntectonic conditions in the Lowlands, while in the Highlands the same plutons have been viewed as anorogenic. Deformation focused on the CCMZ is reflected in whole-rock Rb-Sr isochron age of 1038[plus minus]97 Ma for the Complex. This resetting is typical of granitoid plutons within a 10 km-wide zone across the CCMZ,more » but is absent outside this zone elsewhere in the Lowlands. Although the chemical continuity of the Complex with Adirondack mafic rocks of the same presumed age demonstrates that crystal fractionation from a basic parent was a likely origin for the Complex, it is probable the magmas were modified by crustal assimilation. For example, the initial [sup 87]Sr/[sup 86]Sr[sub 1152] values for the Complex (0.7042[plus minus]3) are higher than the same ratios for Adirondack mafic rocks (0.7033[plus minus]6), and one zircon fraction lies to the right of the discordia defined by the other four analyzed fractions. The nature and age of the assimilant may be constrained by a metasedimentary xenolith with a whole-rock Rb-Sr isochron age of 1318[plus minus]15 Ma. Changes in TiO[sub 2] and P[sub 2]O[sub 5] abundances and La/Yb values indicate that the crystallization of both accessory (e.g., Fe-Ti oxides, apatite and zircon) and silicate phases were important in the fractionation of the Diana Complex syenites.« less

An isotopic view of water and nitrate transport through the vadose zone in Oregon's southern Willamette Valley's Groundwater Management Area

NASA Astrophysics Data System (ADS)

Brooks, J. R.; Pearlstein, S.; Hutchins, S.; Faulkner, B. R.; Rugh, W.; Willard, K.; Coulombe, R.; Compton, J.

2017-12-01

Groundwater nitrate contamination affects thousands of households in Oregon's southern Willamette Valley and many more across the USA. The southern Willamette Valley Groundwater Management Area (GWMA) was established in 2004 due to nitrate levels in the groundwater exceeding the human health standard of 10 mg nitrate-N L-1. Much of the nitrogen (N) inputs to the GWMA comes from agricultural fertilizers, and thus efforts to reduce N inputs to groundwater are focused upon improving N management. However, the effectiveness of these improvements on groundwater quality is unclear because of the complexity of nutrient transport through the vadose zone and long groundwater residence times. Our objective was to focus on vadose zone transport and understand the dynamics and timing of N and water movement below the rooting zone in relation to N management and water inputs. Stable isotopes are a powerful tool for tracking water movement, and understanding N transformations. In partnership with local farmers and state agencies, we established lysimeters and groundwater wells in multiple agricultural fields in the GWMA, and have monitored nitrate, nitrate isotopes, and water isotopes weekly for multiple years. Our results indicate that vadose zone transport is highly complex, and the residence time of water collected in lysimeters was much longer than expected. While input precipitation water isotopes were highly variable over time, lysimeter water isotopes were surprisingly consistent, more closely resembling long-term precipitation isotope means rather than recent precipitation isotopic signatures. However, some particularly large precipitation events with unique isotopic signatures revealed high spatial variability in transport, with some lysimeters showing greater proportions of recent precipitation inputs than others. In one installation where we have groundwater wells and lysimeters at multiple depths, nitrate/nitrite concentrations decreased with depth. N concentrations and δ15N values indicated leaching at 1 m and denitrification at 3 m depth. However, these relationships showed spatial and temporal complexity. We are exploring how these vadose zone complexities can be incorporated into practical understanding of the impacts of N management on groundwater inputs.

On the existence of free and metal complexed sulfide in the Arabian Sea and its oxygen minimum zone

NASA Astrophysics Data System (ADS)

Theberge, Stephen M.; Luther, George W.; Farrenkopf, Anna M.

Free hydrogen sulfide was not detected in the oxygen minimum zone (OMZ) of the Arabian Sea during legs D1 (September 1992) and D3 (October-November 1992) of the Netherlands Indian Ocean Programme (NIOP). However, sulfide complexed to metals was detected by cathodic stripping square wave voltammetry at 2 nM or less throughout the water column. A slight increase in sulfide was measured in the OMZ relative to the surface waters and may be related to sulfur release from organic matter during decomposition. Sulfide complexes are of two general types at low concentrations of metal and sulfide. First, metals such as Mn, Fe, Co and Ni form complexes with bisulfide ion (HS -) that are kinetically labile to dissociation and are reactive. Second, metals such as Cu and Zn form multinuclear complexes with sulfide (S 2-) that are kinetically inert to dissociation; thus, they are less reactive than free (bi)sulfide and the labile metal bisulfide complexes. Zinc and copper sulfide complexes are important in allowing hydrogen sulfide to persist in seawater which contains measurable oxygen.

Numerical, micro-mechanical prediction of crack growth resistance in a fibre-reinforced/brittle matrix composite

NASA Technical Reports Server (NTRS)

Jenkins, Michael G.; Ghosh, Asish; Salem, Jonathan A.

1990-01-01

Micromechanics fracture models are incorporated into three distinct fracture process zones which contribute to the crack growth resistance of fibrous composites. The frontal process zone includes microcracking, fiber debonding, and some fiber failure. The elastic process zone is related only to the linear elastic creation of new matrix and fiber fracture surfaces. The wake process zone includes fiber bridging, fiber pullout, and fiber breakage. The R-curve predictions of the model compare well with empirical results for a unidirectional, continuous fiber C/C composite. Separating the contributions of each process zone reveals the wake region to contain the dominant crack growth resistance mechanisms. Fractography showed the effects of the micromechanisms on the macroscopic fracture behavior.

Various Slip Behaviors in the Frictionally Heterogeneous Fault Model

NASA Astrophysics Data System (ADS)

Yabe, S.; Ide, S.

2017-12-01

Diverse slip behaviors have been observed on the fault, including regular earthquakes followed by afterslip, and slow earthquakes. In Southwest Japan and Cascadia, hypocenters of slow earthquakes seem to be separated from the locked region of megathrust earthquakes (e.g., Liu et al., 2010). In contrary, M7 earthquakes and their afterslips and repeating occurrences of slow slip events were reported in the coseismic slip area of 2011 M9 earthquake in Tohoku region (Ohta et al., 2012; Ito et al., 2013). Understanding the physical mechanism of diverse slip behavior is important to understand the strain accumulation and release cycle in a whole subduction zone. Among various candidates to explain the slip diversity, including dynamic weakening (e.g., Noda and Lapusta, 2013), fluid-slip interactions (e.g., Segall, 2010), and along-dip variation of frictional property (e.g., Tse and Rice, 1986), we consider in this study frictional heterogeneity on the fault (e.g., Ando et al., 2010, 2012; Nakata et al., 2011; Skarbek et al., 2012; Dublanchet et al., 2013; Yabe and Ide, 2017). We have considered the finite linear fault governed by rate and state friction law on which velocity-weakening zone and velocity-strengthening zone are alternately distributed. The fault outside the model space slips stably, which loads stress to the model space. Such frictionally heterogeneous fault shows diverse slip behavior which cannot be observed in the frictionally homogeneous fault. In some parameter space, the entire faults including velocity-strengthening zones slips seismically (Skarbek et al., 2012; Dublanchet et al., 2013; Yabe and Ide, 2017). We have sometimes observed foreshocks and aftershocks within the mainshock slip area. We have also sometimes observed repeating slow slip events during the inter-seismic period around the rupture initiation point of the mainshock. We will report parameter studies to clarify the relation between diverse slip behavior and frictional heterogeneity.

Variability of High Resolution Vp/Vs and Seismic Velocity Structure Along the Nicaragua/Costa Rica Segment of the Middle America Subduction Zone

NASA Astrophysics Data System (ADS)

Moore-Driskell, M. M.; DeShon, H. R.

2012-12-01

Previous studies of subduction zone earthquakes have shown that fault conditions control earthquake rupture and behavior. There are many potential properties that may vary along the subduction margin that could cause fault zone variability, including plate age, temperature, and/or geometry, convergence rate, state of hydration, overriding geology, subducting sediment packages, or subducting seamounts/ridges. The Nicaragua/Costa Rica segment of the Middle America subduction zone is highly variable along strike and down dip. We use this margin to examine how these variable conditions affect earthquake behavior by determining local ratios of compressional to shear wave velocities (Vp/Vs) and detailed seismic velocity structure. Vp/Vs is one of the best tools available to reliably define fault conditions because it is directly related to the Poisson's ratio of the fault material, and it is sensitive to the presence of fluids and changing permeability. Thus with well-resolved near source Vp/Vs measurements we can infer composition and/or high fluid pressures. Here, we use a technique developed by Lin and Shearer (2007) to determine local Vp/Vs in small areas (~2 x 2 x 2 km) with high seismicity. Within the seismogenic zone, we find the margin to be highly variable along strike in Vp/Vs and seismic velocity. These changes correlate to documented variability in incoming plate properties. Increased Vp/Vs is associated with intraplate earthquakes along Nicaragua and northern Costa Rica. We compare our results with other geophysical studies including new high-resolution images of seismic velocity structure, an extensive catalog of high quality relocated events, apparent stress calculations, coupling, and SSE/NVT occurrence. A better understanding of the connection between fault properties and earthquake behavior gives insight into the role of fluids in seismogenesis, the spectrum of earthquake rupture, and possible hazard at subduction zones.

Viscoelastic shear zone model of a strike-slip earthquake cycle

USGS Publications Warehouse

Pollitz, F.F.

2001-01-01

I examine the behavior of a two-dimensional (2-D) strike-slip fault system embedded in a 1-D elastic layer (schizosphere) overlying a uniform viscoelastic half-space (plastosphere) and within the boundaries of a finite width shear zone. The viscoelastic coupling model of Savage and Prescott [1978] considers the viscoelastic response of this system, in the absence of the shear zone boundaries, to an earthquake occurring within the upper elastic layer, steady slip beneath a prescribed depth, and the superposition of the responses of multiple earthquakes with characteristic slip occurring at regular intervals. So formulated, the viscoelastic coupling model predicts that sufficiently long after initiation of the system, (1) average fault-parallel velocity at any point is the average slip rate of that side of the fault and (2) far-field velocities equal the same constant rate. Because of the sensitivity to the mechanical properties of the schizosphere-plastosphere system (i.e., elastic layer thickness, plastosphere viscosity), this model has been used to infer such properties from measurements of interseismic velocity. Such inferences exploit the predicted behavior at a known time within the earthquake cycle. By modifying the viscoelastic coupling model to satisfy the additional constraint that the absolute velocity at prescribed shear zone boundaries is constant, I find that even though the time-averaged behavior remains the same, the spatiotemporal pattern of surface deformation (particularly its temporal variation within an earthquake cycle) is markedly different from that predicted by the conventional viscoelastic coupling model. These differences are magnified as plastosphere viscosity is reduced or as the recurrence interval of periodic earthquakes is lengthened. Application to the interseismic velocity field along the Mojave section of the San Andreas fault suggests that the region behaves mechanically like a ???600-km-wide shear zone accommodating 50 mm/yr fault-parallel motion distributed between the San Andreas fault system and Eastern California Shear Zone. Copyright 2001 by the American Geophysical Union.

The brittle-ductile transition in porous sedimentary rocks: geological implications for accretionary wedge aseismicity

NASA Astrophysics Data System (ADS)

Zhang, Jiaxiang; Davis, Dan M.; Wong, Teng-Fong

1993-07-01

Thrusting earthquakes in subduction zones generally occur along only part of the plate boundary, with motion along the shallowest part of the plate boundary occurring ascismically. The maximum size of subduction boundary thrust earthquakes depends strongly upon the down-dip width of the seismogenic zone. The single most uncertain factor in determining that width is the location of the up-dip limit of the zone (the seismic front), which depends upon the mechanical state of the sedimentary rocks in the plate boundary zone. In order to come to a better understanding of the seismic potential of sediments in a subduction zone, we carried out a series of triaxial experiments on Berea and Kayenta sandstones. Based on our experimental data, a brittle-ductile transition map was constructed showing that both porosity and effective pressure are important factors controlling the transition from brittle to macroscopically ductile behavior in porous rocks. In the brittle field, a sample fails by shear localization on one slip plane accompanied by strain softening and dilatancy, whereas in the ductile field, a sample deforms homogeneously with a constant yield stress or slight hardening. By comparing such a map with the estimated porosity profile of an accretionary wedge, the likely nature and rough location of the boundary between brittle and ductile behavior can be inferred. If the sediments along a plate boundary are too young and undercompacted to be capable of brittle shear localization, then their deformation is likely to be aseismic. In this way, it may be possible for even a very broad fore-arcs to produce no great earthquakes. However, great earthquakes are to be expected at margins that have large zones of plate contact along which many sediments are compacted and well lithified. Such rocks are expected to be capable of shear localization and brittle failure with the potential for stick-slip behavior.

Ultra-deep oxidation and exotic copper formation at the late pliocene boyongan and bayugo porphyry copper-gold deposits, surigao, philippines: Geology, mineralogy, paleoaltimetry, and their implications for Geologic, physiographic, and tectonic controls

USGS Publications Warehouse

Braxton, D.P.; Cooke, D.R.; Ignacio, A.M.; Rye, R.O.; Waters, P.J.

2009-01-01

The Boyongan and Bayugo porphyry copper-gold deposits are part of an emerging belt of intrusion-centered gold-rich deposits in the Surigao district of northeast Mindanao, Philippines. Exhumation and weathering of these Late Pliocene-age deposits has led to the development of the world's deepest known porphyry oxidation profile at Boyongan (600 m), and yet only a modest (30-70 m) oxidation profile at adjacent Bayugo. Debris flows, volcanic rocks, and fluviolacustrine sediments accumulating in the actively extending Mainit graben subsequently covered the deposits and preserved the supergene profiles. At Boyongan and Bayugo, there is a vertical transition from shallower supergene copper oxide minerals (malachite + azurite + cuprite) to deeper sulfide-stable assemblages (chalcocite ?? hypogene sulfides). This transition provides a time-integrated proxy for the position of the water table at the base of the saturated zone during supergene oxidation. Contours of the elevation of the paleopotentiometric surface based on this min- eralogical transition show that the thickest portions of the unsaturated zone coincided with a silt-sand matrix diatreme breccia complex at Boyongan. Within the breccia complex, the thickness of the unsaturated zone approached 600 in, whereas outside the breccia complex (e.g., at Bayugo), the thickness averaged 50 m. Contours of the paleopotentiometric surface suggest that during weathering, groundwater flowed into the breccia complex from the north, south, and east, and exited along a high permeability zone to the west. The high relief (>550 m) on the elevation of the paleopotentiometric surface is consistent with an environment of high topographic relief, and the outflow zone to the west of the breccia complex probably reflects proximity to a steep scarp intersecting the western breccia complex margin. Stable isotope paleoaltimetry has enabled estimation of the elevation of the land surface, which further constrains the physiographic setting during supergene oxidation. Isotopic measurements of oxygen in supergene kaolinite from Boyongan suggest that local paleometeoric water involved in weathering had a ??180 composition of approximately -5.7 per mil. At the latitude of the southern Philippines, this value corresponds to Pleistocene rain water condensing at elevations between 750 and 1,050 m above contemporary sea level, providing a maximum estimate for the surface elevation during weathering of the porphyry systems. Physiographic reconstuctions suggest that the deep oxidation profile at Boyongan formed in an environment of high topographic relief immediately east of a prominent (>550 m) escarpment. The high permeability contrast between the breccia complex and the surrounding wall rocks, coupled with the proximity of the breccia complex to the escarpment, led to a depressed groundwater table and a vertically extensive unsaturated zone in the immediate vicinity of Boyongan. This thick vadose zone and the low hypogene pyrite/copper sulfide ratios (0.6) at Boyongan promoted in situ oxidation of copper sulfides with only modest (<200 m) supergene remobilization of copper. In contrast, higher hypogene pyrite/chalcopyrite ratios (2.3) at Bayugo led to greater acid production during weathering and more complete leaching of copper above the base of oxidation. This process promoted significant (600 m) lateral dispersion of copper down the paleohydraulic gradient into the diatreme breccia comple, ultimately leading to the formation of an exotic copper deposit. ?? 2009 Society of Economices Geologists, Inc.

Trading Time with Space - Development of subduction zone parameter database for a maximum magnitude correlation assessment

NASA Astrophysics Data System (ADS)

Schaefer, Andreas; Wenzel, Friedemann

2017-04-01

Subduction zones are generally the sources of the earthquakes with the highest magnitudes. Not only in Japan or Chile, but also in Pakistan, the Solomon Islands or for the Lesser Antilles, subduction zones pose a significant hazard for the people. To understand the behavior of subduction zones, especially to identify their capabilities to produce maximum magnitude earthquakes, various physical models have been developed leading to a large number of various datasets, e.g. from geodesy, geomagnetics, structural geology, etc. There have been various studies to utilize this data for the compilation of a subduction zone parameters database, but mostly concentrating on only the major zones. Here, we compile the largest dataset of subduction zone parameters both in parameter diversity but also in the number of considered subduction zones. In total, more than 70 individual sources have been assessed and the aforementioned parametric data have been combined with seismological data and many more sources have been compiled leading to more than 60 individual parameters. Not all parameters have been resolved for each zone, since the data completeness depends on the data availability and quality for each source. In addition, the 3D down-dip geometry of a majority of the subduction zones has been resolved using historical earthquake hypocenter data and centroid moment tensors where available and additionally compared and verified with results from previous studies. With such a database, a statistical study has been undertaken to identify not only correlations between those parameters to estimate a parametric driven way to identify potentials for maximum possible magnitudes, but also to identify similarities between the sources themselves. This identification of similarities leads to a classification system for subduction zones. Here, it could be expected if two sources share enough common characteristics, other characteristics of interest may be similar as well. This concept technically trades time with space, considering subduction zones where we have likely not observed the maximum possible event yet. However, by identifying sources of the same class, the not-yet observed temporal behavior can be replaced by spatial similarity among different subduction zones. This database aims to enhance the research and understanding of subduction zones and to quantify their potential in producing mega earthquakes considering potential strong motion impact on nearby cities and their tsunami potential.

On the behavior of site effects in Central Mexico (the Mexican Volcanic Belt - MVB), based on records of shallow earthquakes that occurred in the zone between 1998 and 2011

NASA Astrophysics Data System (ADS)

Clemente-Chavez, A.; Zúñiga, F. R.; Lermo, J.; Figueroa-Soto, A.; Valdés, C.; Montiel, M.; Chavez, O.; Arroyo, M.

2013-11-01

The Mexican Volcanic Belt (MVB) is a seismogenic zone that transects the central part of Mexico with an east-west orientation. The risk and hazard seismic of this seismogenic zone has not been studied at detail due to the scarcity of instrumental data as well as because seismicity in the continental regimen of Central Mexico is not too frequent, however, it is known that there are precedents of large earthquakes (Mw > 6.0) that have taken place in this zone. The Valley of Mexico City (VM) is the sole zone, within the MVB, which has been studied in detail; mainly focusing on the ground amplification during large events such as the 1985 subduction earthquake that occurred in Michoacan. The purpose of this article is to analyze the behavior of site effects in the MVB zone based on records of shallow earthquakes (data not reported before) that occurred in the zone between 1998 and 2011. We present a general overview of site effects on the MVB, a classification of the stations in order to reduce the uncertainty in the data to obtain attenuation parameters in future works, and some comparisons between the information presented here and that presented in previous studies. A regional evaluation of site effects and Fourier Acceleration Spectrum (FAS) shape was estimated based on 80 records of 22 shallow earthquakes within the MVB zone. Data of 25 stations were analyzed. Site effects were estimated by using the Horizontal-to-Vertical Spectral Ratio (HVSR) methodology. The results show that seismic waves are less amplified in the northeast sites of the MVB with respect to the rest of the zone and that it is possible to classify two groups of stations: (1) stations with Negligible Site Amplification (NSA) and (2) stations with Significant Site Amplification (SSA). Most of the sites in the first group showed small (< 3) amplifications while the second group showed amplifications ranging from 4 to 6.5 at frequencies of about 0.35, 0.75, 15 and 23 Hz. With these groups of stations, average levels of amplification were contrasted for the first time with those caused by the subduction zone earthaquakes. With respect to the FAS shapes, most of them showed similarities at similar epicentral distances. Finally, some variations of site effects were found when compared to those obtained in previous studies on different seismicity regions. These variations were attributed to the location of the source. These aspects help to advance the understanding about the amplification behavior and of the expected seismic risk on the Central Mexico due to large earthquakes within the MVB seismogenic zone.

On the behavior of site effects in central Mexico (the Mexican volcanic belt - MVB), based on records of shallow earthquakes that occurred in the zone between 1998 and 2011

NASA Astrophysics Data System (ADS)

Clemente-Chavez, A.; Zúñiga, F. R.; Lermo, J.; Figueroa-Soto, A.; Valdés, C.; Montiel, M.; Chavez, O.; Arroyo, M.

2014-06-01

The Mexican volcanic belt (MVB) is a seismogenic zone that transects the central part of Mexico with an east-west orientation. The seismic risk and hazard of this seismogenic zone has not been studied in detail due to the scarcity of instrumental data as well as because seismicity in the continental regime of central Mexico is not too frequent. However, it is known that there are precedents of large earthquakes (Mw > 6.0) that have taken place in this zone. The valley of Mexico City (VM) is the sole zone, within the MVB, that has been studied in detail. Studies have mainly focused on the ground amplification during large events such as the 1985 subduction earthquake that occurred off coast of Michoacán. The purpose of this article is to analyze the behavior of site effects in the MVB zone based on records of shallow earthquakes (data not reported before) that occurred in the zone between 1998 and 2011. We present a general overview of site effects in the MVB, a classification of the stations in order to reduce the uncertainty in the data when obtaining attenuation parameters in future works, as well as some comparisons between the information presented here and that presented in previous studies. A regional evaluation of site effects and Fourier acceleration spectrum (FAS) shape was estimated based on 80 records of 22 shallow earthquakes within the MVB zone. Data of 25 stations were analyzed. Site effects were estimated by using the horizontal-to-vertical spectral ratio (HVSR) methodology. The results show that seismic waves are less amplified in the northeast sites of the MVB with respect to the rest of the zone and that it is possible to classify two groups of stations: (1) stations with negligible site amplification (NSA) and (2) stations with significant site amplification (SSA). Most of the sites in the first group showed small (<3) amplifications while the second group showed amplifications ranging from 4 to 6.5 at frequencies of about 0.35, 0.75, 15 and 23 Hz. With these groups of stations, average levels of amplification were contrasted for the first time with those caused by the subduction zone earthquakes. With respect to the FAS shapes, most of them showed similarities at similar epicentral distances. Finally, some variations of site effects were found when compared to those obtained in previous studies on different seismicity regions. These variations were attributed to the location of the source. These aspects help to advance the understanding about the amplification behavior and of the expected seismic risk on central Mexico due to large earthquakes within the MVB seismogenic zone.

Impact of Hypoxia on Startle Response (C-start) of Fish in a Tropical Urban Estuary

NASA Astrophysics Data System (ADS)

Sánchez-García, M.; Zottoli, S. J.; Roberson, L.

2016-02-01

Hypoxic zones have become more prevalent in marine ecosystems as a result of physical changes to the coastal zone, pollution and eutrophication, and are expected to increase in prevalence with climate change. While some studies have examined the behavioral effects of hypoxia on coastal fishes in temperate and sub-tropical zones, none have focused on tropical coastal zones. Behavioral changes may affect fish survival, predator-prey interactions and ultimately ecosystem structure. Through behavioral endpoints we evaluated the effects of non-lethal levels of hypoxia on estuarine fish collected from the tropical Condado Lagoon, San Juan P.R, in a laboratory setting. Two groups of 10 fishes were placed individually in a sound test chamber and oxygen concentrations were modulated from a pre-treatment at 100% oxygen to increasing levels of hypoxia (80, 70, & 60%), followed by a reversal treatment (100%) to test for recovery of pretreatment behavior. An abrupt sound stimulus was used to elicit a startle response, a quantifiable biological endpoint, while recording with a high speed camera. This approach can lend valuable insight into changes in the central nervous system and effects of anthropogenic inputs on tropical ecosystems at the individual- and population-level. We found that hypoxic conditions significantly decrease fish responsiveness; fish startled only half the time at 80% O2 and dropped as much as 61% at 60% O2. Additionally, responsiveness in reversal tests were significantly lower than under pre-treatment conditions. These results indicate that hypoxia may have long-term or possibly permanent effects, even under relatively mild hypoxia conditions common to tropical estuaries. Future work will aim to understand if the startle response can be regained after a hypoxic event.

Synthesis, characterization and anti-microbial activity of phenylurea-formaldehyde resin (PUF) and its polymer metal complexes (PUF-Mn(II).

PubMed

Ahamad, Tansir; Alshehri, Saad M

2012-10-01

Phenylurea-formaldehyde polymer (PUF) was synthesized via polycondensation of phenylurea and formaldehyde in basic medium, its polymer-metal complexes [PUF-M(II)] were prepared with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) ions. PUF and PUF-M(II) were characterized with magnetic moment measurements, elemental and spectral (UV-visible, FTIR, 1H-NMR, 13C-NMR and ESR) analysis. The thermal behaviors of all the synthesized polymers were carried out using thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The thermal data revealed that all of the PUF-M(II) showed higher thermal stabilities than the PUF and also ascribed that the PUF-Cu(II) showed better thermal stability than the other PUF-M(II). The kinetic parameters such as activation energy, pre-exponential factor etc., were evaluated for these polymer metal complexes using Coats-Redfern equation. In addition, the antimicrobial activity of the synthesized polymers was tested against several microorganisms using agar well diffusion methods. Among all of the PUF-M(II), the antimicrobial activity of the PUF-Cu(II) showed the highest zone of inhibition because of its higher stability constant and may be used in biomedical applications. Copyright © 2012 Elsevier B.V. All rights reserved.

Interdiffusion behavior between NiAlHf coating and Ni-based single crystal superalloy with different crystal orientations

NASA Astrophysics Data System (ADS)

Wang, Ruili; Gong, Xueyuan; Peng, Hui; Ma, Yue; Guo, Hongbo

2015-01-01

NiAlHf coatings were deposited onto Ni-based single crystal (SC) superalloy with different crystal orientations by electron beam physical vapor deposition (EB-PVD). The effects of the crystal orientations of the superalloy substrate on inter-diffusion behavior between the substrate and the NiAlHf coating were investigated. Substrate diffusion zone (SDZ) containing needle-like μ phases and interdiffusion zone (IDZ) mainly consisting of the ellipsoidal and rod-like μ phases were formed in the SC alloy after heat-treatment 10 h at 1100 °C. The thickness of secondary reaction zone (SRZ) formed in the SC alloy with (0 1 1) crystal orientation is about 14 μm after 50 h heat-treatment at 1100 °C, which is relatively thicker than that in the SC alloy with (0 0 1) crystal orientation, whereas the IDZ revealed similar thickness.

The Consumer Behavior Challenge: Designing an Assignment to Motivate Student Reflection and Self-Growth

ERIC Educational Resources Information Center

Gravois, Renée; Lopez, Tará Burnthorne; Budden, Michael C.

2017-01-01

The tension caused by change pushes students to reflect on their new situation, examine preconceived ideas, and synthesize new with existing knowledge. In the Consumer Behavior Challenge, students are challenged to step outside of their comfort zone by changing a behavior or trying something new for a period of time. Through guided reflection…

Improving precipitation hardening behavior of Mg−Zn based alloys with Ce−Ca microalloying additions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Langelier, B., E-mail: langelb@mcmaster.ca

2016-10-15

The precipitation hardening behavior of newly developed Mg−Zn−Ca−Ce alloys, with modified texture and improved ductility, is studied to delineate the microstructural characteristics that lead to effective hardening upon ageing treatments. Advanced electron microscopy and atom probe techniques are used to analyze the structural characteristics in relevance to the hardening potential. It has been found that the formation of a new basal precipitate phase, which evolves from a single atomic layer GP zone, and is finely distributed in both under-aged and peak-aged microstructures, has a significant impact in the improvement of the hardening response compared with the base Mg−Zn alloys. Itmore » has also been found that the β′{sub 1} rod precipitates, commonly formed during ageing treatments of Mg−Zn alloys, have their size and distribution significantly refined in the Ca−Ce containing alloys. The role of alloy chemistry in the formation of the fine basal plate GP zones and the refinement in β′{sub 1} precipitation and their relationships to the hardening behavior are discussed. It is proposed that Ca microalloying governs the formation of the GP zones and the enhancement of hardening, particularly in the under-aged conditions, but that this is aided by a beneficial effect from Ce. - Highlights: • Ce−Ca microalloying additions improve hardening in Mg−Zn, over Ce or Ca alone. • Improved hardening is due to refined β′{sub 1} rods, and fine basal plate precipitates. • Atom probe tomography identifies Ca in both β′{sub 1} and the fine basal plates. • The fine basal plates originate as ordered monolayer GP zones with 1:1 Zn:Ca (at.%). • With ageing GP zones become more Zn-rich and transform to the fine basal plates.« less

Formulating a coastal zone health metric for landuse impact management in urban coastal zones.

PubMed

Anilkumar, P P; Varghese, Koshy; Ganesh, L S

2010-11-01

The need for ICZM arises often due to inadequate or inappropriate landuse planning practices and policies, especially in urban coastal zones which are more complex due to the larger number of components, their critical dimensions, attributes and interactions. A survey of literature shows that there is no holistic metric for assessing the impacts of landuse planning on the health of a coastal zone. Thus there is a need to define such a metric. The proposed metric, CHI (Coastal zone Health Indicator), developed on the basis of coastal system sustainability, attempts to gauge the health status of any coastal zone. It is formulated and modeled through an expert survey and pertains to the characteristic components of coastal zones, their critical dimensions, and relevant attributes. The proposed metric is applied to two urban coastal zones and validated. It can be used for more coast friendly and sustainable landuse planning/masterplan preparation and thereby for the better management of landuse impacts on coastal zones. Copyright 2010 Elsevier Ltd. All rights reserved.

Quasi 3D modeling of water flow in vadose zone and groundwater

USDA-ARS?s Scientific Manuscript database

The complexity of subsurface flow systems calls for a variety of concepts leading to the multiplicity of simplified flow models. One habitual simplification is based on the assumption that lateral flow and transport in unsaturated zone are not significant unless the capillary fringe is involved. In ...

ESTIMATION OF INFILTRATION RATE IN THE VADOSE ZONE: COMPILATION OF SIMPLE MATHEMATICAL MODELS - VOLUME I

EPA Science Inventory

The unsaturated or vadose zone provides a complex system for the simulation of water movement and contaminant transport and fate. Numerous models are available for performing simulations related to the movement of water. There exists extensive documentation of these models. Ho...

33 CFR 165.1710 - Port Valdez and Valdez Narrows, Valdez, Alaska-security zones.

Code of Federal Regulations, 2010 CFR

2010-07-01

... following areas are security zones: (1) Trans-Alaska Pipeline (TAPS) Valdez Terminal complex (Terminal), Valdez, Alaska and TAPS tank vessels. All waters enclosed within a line beginning on the southern... TAPS tank vessel maneuvering to approach, moor, unmoor or depart the TAPS Terminal or transiting...

Phanerozoic tectonic evolution of the Circum-North Pacific

USGS Publications Warehouse

Nokleberg, Warren J.; Parfenov, Leonid M.; Monger, James W.H.; Norton, Ian O.; Khanchuk, Alexander I.; Stone, David B.; Scotese, Christopher R.; Scholl, David W.; Fujita, Kazuya

2000-01-01

The Phanerozoic tectonic evolution of the Circum-North Pacific is recorded mainly in the orogenic collages of the Circum-North Pacific mountain belts that separate the North Pacific from the eastern part of the North Asian Craton and the western part of the North American Craton. These collages consist of tectonostratigraphic terranes that are composed of fragments of igneous arcs, accretionary-wedge and subduction-zone complexes, passive continental margins, and cratons; they are overlapped by continental-margin-arc and sedimentary-basin assemblages. The geologic history of the terranes and overlap assemblages is highly complex because of postaccretionary dismemberment and translation during strike-slip faulting that occurred subparallel to continental margins.We analyze the complex tectonics of this region by the following steps. (1) We assign tectonic environments for the orogenic collages from regional compilation and synthesis of stratigraphic and faunal data. The types of tectonic environments include cratonal, passive continental margin, metamorphosed continental margin, continental-margin arc, island arc, oceanic crust, seamount, ophiolite, accretionary wedge, subduction zone, turbidite basin, and metamorphic. (2) We make correlations between terranes. (3) We group coeval terranes into a single tectonic origin, for example, a single island arc or subduction zone. (4) We group igneous-arc and subduction- zone terranes, which are interpreted as being tectonically linked, into coeval, curvilinear arc/subduction-zone complexes. (5) We interpret the original positions of terranes, using geologic, faunal, and paleomagnetic data. (6) We construct the paths of tectonic migration. Six processes overlapping in time were responsible for most of the complexities of the collage of terranes and overlap assemblages around the Circum-North Pacific, as follows. (1) During the Late Proterozoic, Late Devonian, and Early Carboniferous, major periods of rifting occurred along the ancestral margins of present-day Northeast Asia and northwestern North America. The rifting resulted in the fragmentation of each continent and the formation of cratonal and passive continental-margin terranes that eventually migrated and accreted to other sites along the evolving margins of the original or adjacent continents. (2) From about the Late Triassic through the mid-Cretaceous, a succession of island arcs and tectonically paired subduction zones formed near the continental margins. (3) From about mainly the mid-Cretaceous through the present, a succession of igneous arcs and tectonically paired subduction zones formed along the continental margins. (4) From about the Jurassic to the present, oblique convergence and rotations caused orogenparallel sinistral and then dextral displacements within the upper-plate margins of cratons that have become Northeast Asia and North America. The oblique convergences and rotations resulted in the fragmentation, displacement, and duplication of formerly more nearly continuous arcs, subduction zones, and passive continental margins. These fragments were subsequently accreted along the expanding continental margins. (5) From the Early Jurassic through Tertiary, movement of the upper continental plates toward subduction zones resulted in strong plate coupling and accretion of the former island arcs and subduction zones to the continental margins. Accretions were accompanied and followed by crustal thickening, anatexis, metamorphism, and uplift. The accretions resulted in substantial growth of the North Asian and North American Continents. (6) During the middle and late Cenozoic, oblique to orthogonal convergence of the Pacifi c plate with present-day Alaska and Northeast Asia resulted in formation of the modern-day ring of volcanoes around the Circum-North Pacific. Oblique convergence between the Pacific plate and Alaska also resulted in major dextral-slip faulting in interior and southern Alaska and along the western p

Mineralogy, paragenesis, and mineral zoning of the Bulldog Mountain vein system, Creede District, Colorado

USGS Publications Warehouse

Plumlee, Geoffrey S.; Heald Whitehouse-Veaux, Pamela

1994-01-01

The Bulldog Mountain vein system, Creede district, Colorado, is one of four major epithermal vein systems from which the bulk of the district's historical Ag-Pb-Zn-Cu production has come. Ores deposited along the vein system were discovered in 1965 and were mined from 1969 to 1985.Six temporally gradational mineralization stages have been identified along the Bulldog Mountain vein system, each with a characteristic suite of minerals deposited or leached and a characteristic distribution within the vein system; some of these stages are also strongly zoned within the vein system. Stage A was dominated by deposition of rhodochrosite along the lower levels of the Bulldog Mountain ore zone. Stage B in the northern parts of the ore zone is characterized by abundant fine-grained sphalerite and galena, with lesser tetrahedrite and minor chlorite and hematite. With increasing elevation to the south, stage B ores become progressively more barite and silver rich, with alternating barite and fine-grained sphalerite + galena generations; native silver + or - acanthite assemblages are also locally abundant within southern stage B barite sulfide ores, whereas chalcopyrite and other Cu and Ag sulfides and sulfosalts are present erratically in minor amounts. Stage C in the upper and northern portions of the ore zone is characterized by abundant quartz and fluorite, minor adularia, hematite, Mn siderite, sphalerite, and galena, and major leaching of earlier barite; to the south, some barite and sulfides may have been deposited. Stage D sphalerite and galena were deposited in the upper and northern portions of the ore zone; a barite- and silver-rich facies of this stage may also be present in the southern portions of the vein system. Late in stage D, mineralogically complex assemblages containing chalcopyrite, tetrahedrite, polybasite, bornite, pyrargyrite, and a variety of other sulfides and sulfosalts were deposited in modest amounts throughout the vein system. This complex assemblage marked the transition to stage E. During stage E, the final sulfide stage, abundant botryoidal pyrite and marcasite with lesser stibnite, sphalerite, and sulfosalts were deposited primarily along the top of the Bulldog Mountain ore zone. Stage F, the final mineralization stage along the vein system, is marked by wire silver and concurrent leaching of earlier sulfides and sulfosalts; this stage may reflect the transition to a supergene environment.The sequence of mineralization stages identified in this study along the Bulldog Mountain system can be correlated with corresponding stages identified by other researchers along the OH and P veins, and the southern Amethyst vein system. Mineral zoning patterns identified along the Bulldog Mountain vein system also parallel larger scale zoning patterns across the central and southern Creede district.The complex variations in mineral assemblages documented in time and space along the Bulldog Mountain vein system were produced by the combined effects of many processes. Large-scale changes in vein mineralogy over time produced discrete mineralization stages. Short-term mineralogical fluctuations produced complex interbanding of mineralogically distinct generations. Fluid chemistry evolution within the vein system produced large-scale lateral zoning patterns within certain stages. Hypogene leaching substantially modified the distributions of some minerals. Finally, structural activity, mineral deposition, and mineral leaching modified fluid flow pathways repeatedly during mineralization, and so added to the complex mineral distribution patterns within the vein system.

Binarization of apodizers by adapted one-dimensional error diffusion method

NASA Astrophysics Data System (ADS)

Kowalczyk, Marek; Cichocki, Tomasz; Martinez-Corral, Manuel; Andres, Pedro

1994-10-01

Two novel algorithms for the binarization of continuous rotationally symmetric real positive pupil filters are presented. Both algorithms are based on 1-D error diffusion concept. The original gray-tone apodizer is substituted by a set of transparent and opaque concentric annular zones. Depending on the algorithm the resulting binary mask consists of either equal width or equal area zones. The diffractive behavior of binary filters is evaluated. It is shown that the pupils with equal width zones give Fraunhofer diffraction pattern more similar to that of the original continuous-tone pupil than those with equal area zones, assuming in both cases the same resolution limit of printing device.

Stratigraphic architecture and depositional history of lower Miocene, Planulina Zone, Southern Louisiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gates, B.C.; Galloway, W.E.

1988-01-01

The Planulina zone is a wedge of clastic sediment positioned between the Anahuac shale below and the Oakville sandstone interval above. Planulna sediments were deposited on an erosional surface, during a general rise in the sea level, and formed a retrogradational wedge. Within the study area, the Planulina zone consists of two large depositional complexes: the Mud Lake complex in west Cameron Parish, Louisiana, and the East Cameron complex in east Cameron Parish. The lowermost depositional sequence in the East Cameron complex is preserved in a network of submarine canyons that were eroded into the upper slope. Framework sands weremore » deposited in channel systems confined to the axis of the canyons, and the sands are encased in marine shale containing benthonic foraminifera indicative of an upper to middle slope paleoenvironment. Two younger depositional sequences overlie the submarine canyon facies and were deposited by deltaic systems that prograded basinward. A zone of expansion extends east to west through the Planulina interval and is named the ''Planulina flexure.'' The flexure is a large fault located at the relict shelf edge and soles out downdip inn the Anahuac shale. Several thousand feet of sediment downthrown on the flexure is equivalent to several hundred feet upthrown, and the flexure represented the boundary dividing updip deltaic processes from downdip slope processes during the beginning of Planulina deposition. The Planulina depositional history and stratigraphic architecture are directly related to the displacement along the flexure and the structural deformation of the underlying Anahuac shale.« less

Pseudotachylytes of the Deep Crust: Examples from a Granulite-Facies Shear Zone

NASA Astrophysics Data System (ADS)

Orlandini, O.; Mahan, K. H.; Regan, S.; Williams, M. L.; Leite, A.

2013-12-01

The Athabasca Granulite Terrane is an exhumed section of deep continental crust exposed in the western Canadian shield. The terrane hosts the 1.88 Ga Cora Lake shear zone, a 3-5 km wide sinistral and extensional oblique-slip system that was active at high-pressure granulite-grade conditions ( ~1.0 GPa, >800°C to ~0.8 GPa and 700 °C). Pseudotachylyte, a glassy vein-filling substance that results from frictional melting during seismic slip, is common in ultramylonitic strands of the shear zone, where veins run for tens of meters subparallel to foliation. Some but not all PST veins have been overprinted with the Cora Lake shear zone foliation, and undeformed PST locally bears microlitic garnet. The frictional melts that quench into PST may reach >1400 °C, but are extremely localized and cool to country rock temperatures within minutes, resulting in glass and/or microlitic mineral growths. The melt itself is thought by many to be in disequilibrium with the host rock due to its rapid nature, but during cooling equilibrium is probably reached at small scales. This allows for microprobe analysis of adjacent microlites for thermobarometric calculations. Preliminary results from undeformed (e.g., youngest of multiple generations) PST suggest that quenching occurred in upper amphibolite facies ambient conditions and is compatible with later stages of Cora Lake shear zone activity. Host-rock mylonites contain abundant garnet and pyroxene sigma clasts indicating sinistral shear, and where PST-bearing slip surfaces are found at low angles to the foliation, they display sinistral offset. The host rock contains abundant macroscopic and microscopic sinistral shear fracture systems (e.g., Riedel [R], Y, and P displacement surfaces) within the immediate proximity of PST veins, indicating a complex interplay of brittle and ductile behavior that is interpreted to be genetically related to the formation of the PST. The shear fracture systems are characterized by sharply bounded surfaces or zones populated by equant 1-15 μm grains, including orthopyroxene. These grains show no evidence of fracturing under backscatter-electron images and preserve cohesion with all surrounding grains, suggesting crystal-plastic behavior. There is evidence for multiple generations of subparallel shear fracture sets, as R shears of an earlier fracture set are cut by Y shears of a later set. The PST generation veins are overprinted in much the same way, and are consistently found in an orientation that suggests they nucleated on Y shear surfaces. Given that available data on the Cora Lake PST indicates formation under conditions where crystal-plastic deformation typically dominates, the downward propagation of faults from the traditional seismogenic zone seems the most reasonable model for emplacement. The propagation of fault slips to depths of 30-50 km has been actively observed for several Mw >7.5 strike-slip and thrust earthquakes, but the deformation mechanisms and specific conditions that allow PST formation at such depths is not well understood. The almost exclusive contemporaneous localization of brittle PST systems into highly ductile ultramylonites suggests an interesting paradox of rheological response to constant regional strain fields .

Investigation of Rock Mass Stability Around the Tunnels in an Underground Mine in USA Using Three-Dimensional Numerical Modeling

NASA Astrophysics Data System (ADS)

Xing, Yan; Kulatilake, P. H. S. W.; Sandbak, L. A.

2018-02-01

The stability of the rock mass around the tunnels in an underground mine was investigated using the distinct element method. A three-dimensional model was developed based on the available geological, geotechnical, and mine construction information. It incorporates a complex lithological system, persistent and non-persistent faults, and a complex tunnel system including backfilled tunnels. The strain-softening constitutive model was applied for the rock masses. The rock mass properties were estimated using the Hoek-Brown equations based on the intact rock properties and the RMR values. The fault material behavior was modeled using the continuously yielding joint model. Sequential construction and rock supporting procedures were simulated based on the way they progressed in the mine. Stress analyses were performed to study the effect of the horizontal in situ stresses and the variability of rock mass properties on tunnel stability, and to evaluate the effectiveness of rock supports. The rock mass behavior was assessed using the stresses, failure zones, deformations around the tunnels, and the fault shear displacement vectors. The safety of rock supports was quantified using the bond shear and bolt tensile failures. Results show that the major fault and weak interlayer have distinct influences on the displacements and stresses around the tunnels. Comparison between the numerical modeling results and the field measurements indicated the cases with the average rock mass properties, and the K 0 values between 0.5 and 1.25 provide satisfactory agreement with the field measurements.

Influence of the chemical and electronic structure on the electrical behavior of zirconium oxynitride films

NASA Astrophysics Data System (ADS)

Carvalho, P.; Chappé, J. M.; Cunha, L.; Lanceros-Méndez, S.; Alpuim, P.; Vaz, F.; Alves, E.; Rousselot, C.; Espinós, J. P.; González-Elipe, A. R.

2008-05-01

This work is devoted to the investigation of decorative zirconium oxynitride, ZrOxNy, films prepared by dc reactive magnetron sputtering, using a 17:3 nitrogen-to-oxygen-ratio gas mixture. The color of the films changed from metallic-like, very bright yellow pale, and golden yellow, for low gas mixture flows [from 0 to about 9SCCM (SCCM denotes cubic centimeter per minute at STP)] to red brownish for intermediate gas flows (values up to 12SCCM). Associated to this color change there is a significant decrease of brightness. With further increase of the reactive gas flow, the color of the samples changed from red brownish to dark blue (samples prepared with 13 and 14SCCM). The films deposited with gas flows above 14SCCM showed only apparent colorations due to interference effects. This change in optical behavior from opaque to transparent (characteristic of a transition from metallic to insulating-type materials), promoted by the change in gas flow values, revealed that significant changes were occurring in the film structure and electronic properties, thus opening new potential applications for the films, beyond those of purely decorative ones. Taking this into account, the electrical behavior of the films was investigated as a function of the reactive gas flow and correlated with the observed chemical, electronic, and structural features. The variations in composition disclosed the existence of four different zones, which were correlated to different crystalline structures. For the so-called zone I, x-ray diffraction revealed the development of films with a B1 NaCl face-centered cubic zirconium nitride-type phase, with some texture changes. Increasing the reactive gas flow, the structure of the films is that of a poorly crystallized overstoichiometric nitride phase, which may be similar to that of Zr3N4, but with some probable oxygen inclusions within nitrogen positions. This region was characterized as zone II. Zone III was indexed as an oxynitride-type phase, similar to that of γ-Zr2ON2 with some oxygen atoms occupying some of the nitrogen positions. Finally, occurring at the highest flow rates, zone IV was assigned to a ZrO2 monoclinic-type structure. The composition/structure variations were consistent with the chemical bonding analysis carried out by x-ray photoelectron spectroscopy, which showed oxygen doping in both Zr3N4- and ZrN-type grown films. The electronic properties of the films exhibited significant changes from zone to zone. Resistivity measurements revealed a very wide range of values, varying from relatively highly conductive materials (for zone I) with resistivity values around few hundreds of μΩcm to highly insulating films within zones III and IV, which presented resistivity values in the order of 1015μΩcm. Regarding zone II, corresponding to oxygen doped Zr3N4-type compounds, the observed behavior revealed resistivity values increasing steeply from about 103 up to 1015μΩcm, indicating a systematic transition from metallic to insulating regimes.

CFD Analysis in Advance of the NASA Juncture Flow Experiment

NASA Technical Reports Server (NTRS)

Lee, H. C.; Pulliam, T. H.; Neuhart, D. H.; Kegerise, M. A.

2017-01-01

NASA through its Transformational Tools and Technologies Project (TTT) under the Advanced Air Vehicle Program, is supporting a substantial effort to investigate the formation and origin of separation bubbles found on wing-body juncture zones. The flow behavior in these regions is highly complex, difficult to measure experimentally, and challenging to model numerically. Multiple wing configurations were designed and evaluated using Computational Fluid Dynamics (CFD), and a series of wind tunnel risk reduction tests were performed to further down-select the candidates for the final experiment. This paper documents the CFD analysis done in conjunction with the 6 percent scale risk reduction experiment performed in NASA Langley's 14- by 22-Foot Subsonic Tunnel. The combined CFD and wind tunnel results ultimately helped the Juncture Flow committee select the wing configurations for the final experiment.

Subcritical crack growth and other time- and environment-dependent behavior in crustal rocks

NASA Technical Reports Server (NTRS)

Swanson, P. L.

1984-01-01

Stable crack growth strongly influences both the fracture strength of brittle rocks and some of the phenomena precursory to catastrophic failure. Quantification of the time and environment dependence of fracture propagation is attempted with the use of a fracture mechanics technique. Some of the difficulties encountered when applying techniques originally developed for simple synthetic materials to complex materials like rocks are examined. A picture of subcritical fracture propagation is developed that embraces the essential ingredients of the microstructure, a microcrack process zone, and the different roles that the environment plays. To do this, the results of (1) fracture mechanics experiments on five rock types, (2) optical and scanning electron microscopy, (3) studies of microstructural aspects of fracture in ceramics, and (4) exploratory tests examining the time-dependent response of rock to the application of water are examined.

Local Laser Strengthening of Steel Sheets for Load Adapted Component Design in Car Body Structures

NASA Astrophysics Data System (ADS)

Jahn, Axel; Heitmanek, Marco; Standfuss, Jens; Brenner, Berndt; Wunderlich, Gerd; Donat, Bernd

The current trend in car body construction concerning light weight design and car safety improvement increasingly requires an adaption of the local material properties on the component load. Martensitic hardenable steels, which are typically used in car body components, show a significant hardening effect, for instance in laser welded seams. This effect can be purposefully used as a local strengthening method. For several steel grades the local strengthening, resulting from a laser remelting process was investigated. The strength in the treated zone was determined at crash relevant strain rates. A load adapted design of complex reinforcement structures was developed for compression and bending loaded tube samples, using numerical simulation of the deformation behavior. Especially for bending loaded parts, the crash energy absorption can be increased significantly by local laser strengthening.

Cyclical Fault Permeability in the Lower Seismogenic Zone: Geological Evidence

NASA Astrophysics Data System (ADS)

Sibson, R. H.

2005-12-01

Syntectonic hydrothermal veining is widespread in ancient fault zones exhibiting mixed brittle-ductile behavior that are exhumed from subgreenschist to greenschist environments. The hydrothermal material (predominantly quartz ± carbonate) commonly occurs as fault-veins developed along principal slip surfaces, with textures recording intermittent deposition, sometimes in the form of repeated episodes of brecciation and recementation. Systematic sets of extension veins with histories of incremental dilation often occur in adjacent wallrocks. Conspicuous for their size and continuity among these fault-hosted vein systems are mesozonal Au-quartz lodes, which are most widespread in Archean granite-greenstone belts but also occur throughout the geological record. Most of these lode gold deposits developed at pressures of 1-5 kbar and temperatures of 200-450°C within the lower continental seismogenic zone. A notable characteristic is their vertical continuity: many `ribbon-texture' fault veins with thicknesses of the order of a meter extend over depth ranges approaching 2 km. The largest lodes are usually hosted by reverse or reverse- oblique fault zones with low finite displacement. Associated flat-lying extension veins in the wallrock may taper away from the shear zones over tens or hundreds of meters, and demonstrate repeated attainment of the ~lithostatic fluid overpressures needed for hydraulic extension fracturing. Where hosted by extensional-transtensional fault systems, lode systems tend to be less well developed. Mesozonal vein systems are inferred to be the product of extreme fault-valve behavior, whereby episodic accumulation of pore-fluid pressure to near-lithostatic values over the interseismic period leads to fault rupture, followed by postseismic discharge of substantial fluid volumes along the freshly permeable rupture zone inducing hydrothermal precipitation that seals the fracture permeability. Aqueous mineralizing fluids were generally low-salinity and rich in CO2. Analysis of fluid inclusions suggests that cycling of fluid pressure, in at least some instances, spanned much of the lithostatic-hydrostatic range. While the mesozonal lodes appear to represent an extreme form of fault-valve behavior, minor valving action involving smaller fluid discharges seems likely to be widespread at this structural level in seismogenic crust. The vein systems themselves represent permeability barriers allowing accumulation of fluid overpressure in subseismogenic shear zones, and may occupy part or all of the transition zone between hydrostatic and lithostatic fluid pressure regimes.

Consequences of varied soil hydraulic and meteorological complexity on unsaturated zone time lag estimates.

PubMed

Vero, S E; Ibrahim, T G; Creamer, R E; Grant, J; Healy, M G; Henry, T; Kramers, G; Richards, K G; Fenton, O

2014-12-01

The true efficacy of a programme of agricultural mitigation measures within a catchment to improve water quality can be determined only after a certain hydrologic time lag period (subsequent to implementation) has elapsed. As the biophysical response to policy is not synchronous, accurate estimates of total time lag (unsaturated and saturated) become critical to manage the expectations of policy makers. The estimation of the vertical unsaturated zone component of time lag is vital as it indicates early trends (initial breakthrough), bulk (centre of mass) and total (Exit) travel times. Typically, estimation of time lag through the unsaturated zone is poor, due to the lack of site specific soil physical data, or by assuming saturated conditions. Numerical models (e.g. Hydrus 1D) enable estimates of time lag with varied levels of input data. The current study examines the consequences of varied soil hydraulic and meteorological complexity on unsaturated zone time lag estimates using simulated and actual soil profiles. Results indicated that: greater temporal resolution (from daily to hourly) of meteorological data was more critical as the saturated hydraulic conductivity of the soil decreased; high clay content soils failed to converge reflecting prevalence of lateral component as a contaminant pathway; elucidation of soil hydraulic properties was influenced by the complexity of soil physical data employed (textural menu, ROSETTA, full and partial soil water characteristic curves), which consequently affected time lag ranges; as the importance of the unsaturated zone increases with respect to total travel times the requirements for high complexity/resolution input data become greater. The methodology presented herein demonstrates that decisions made regarding input data and landscape position will have consequences for the estimated range of vertical travel times. Insufficiencies or inaccuracies regarding such input data can therefore mislead policy makers regarding the achievability of water quality targets. Copyright © 2014 Elsevier B.V. All rights reserved.

Dynamic Linkages Between the Transition Zone & Surface Plate Motions in 2D Models of Subduction

NASA Astrophysics Data System (ADS)

Arredondo, K.; Billen, M. I.

2013-12-01

While slab pull is considered the dominant force controlling plate motion and speed, its magnitude is controlled by slab behavior in the mantle, where tomographic studies show a wide range of possibilities from direct penetration to folding, or stagnation directly above the lower mantle (e.g. Fukao et al., 2009). Geodynamic studies have investigated various parameters, such as plate age and two phase transitions, to recreate observed behavior (e.g. Běhounková and Cízková, 2008). However, past geodynamic models have left out known slab characteristics that may have a large impact on slab behavior and our understanding of subduction processes. Mineral experiments and seismic observations have indicated the existence of additional phase transitions in the mantle transition zone that may produce buoyancy forces large enough to affect the descent of a subducting slab (e.g. Ricard et al., 2005). The current study systematically tests different common assumptions used in geodynamic models: kinematic versus free-slip boundary conditions, the effects of adiabatic heating, viscous dissipation and latent heat, compositional layering and a more complete suite of phase transitions. Final models have a complete energy equation, with eclogite, harzburgite and pyrolite lithosphere compositional layers, and seven composition-dependent phase transitions within the olivine, pyroxene and garnet polymorph minerals. Results show important feedback loops between different assumptions and new behavior from the most complete models. Kinematic models show slab weakening or breaking above the 660 km boundary and between compositional layers. The behavior in dynamic models with a free-moving trench and overriding plate is compared to the more commonly found kinematic models. The new behavior may have important implications for the depth distribution of deep earthquakes within the slab. Though the thermodynamic parameters of certain phase transitions may be uncertain, their presence and feedback to other added processes remain important, which could encourage mineralogical research into multiphase systems. Feedback from the compositionally complex slab to the dynamic trench may improve understanding on the mechanics of slab behavior in the upper and lower mantle and surface behavior of the subducting and overriding plates. Běhounková, M., and H. Cízková, Long-wavelength character of subducted slabs in the lower mantle, Earth and Planetary Science Letters, 275, 43-53, 2008. Fukao, Y., M. Obayashi, T. Nakakuki, and the Deep Slab Project Group, Stagnant slab: A review, Annual Reviews of Earth and Planetary Science, 37, 19-46, 2009. Ricard, Y., E. Mattern, and J. Matas, Synthetic tomographic images of slabs from mineral physics, in Earth's Deep Mantle: Structure, Composition, and Evolution, Geophysical Monograph Series, vol. 160, American Geophysical Union, 2005.

Effect of changing driving conditions on driver behavior towards design of a safe and efficient traffic system.

DOT National Transportation Integrated Search

2013-12-01

This simulation-based study explores the effects of different work zone configurations, varying distances : between traffic signs, traffic density and individual differences on drivers behavior. Conventional Lane : Merge (CLM) and Joint Lane Merge...

Rift Zone Abandonment and Reconfiguration in Hawaii: Evidence from Mauna Loa’s Ninole Rift Zone

NASA Astrophysics Data System (ADS)

Morgan, J. K.; Park, J.; Zelt, C. A.

2009-12-01

Large oceanic volcanoes commonly develop elongate rift zones that disperse viscous magmas to the distal reaches of the edifice. Intrusion and dike propagation occur under tension perpendicular to the rift zone, controlled by topography, magmatic pressures, and deformation of the edifice. However, as volcanoes grow and interact, the controlling stress fields can change, potentially altering the orientations and activities of rift zones. This phenomenon is probably common, and can produce complex internal structures that influence the evolution of a volcano and its neighbors. However, little direct evidence for such rift zone reconfiguration exists, primarily due to poor preservation or recognition of earlier volcanic configurations. A new onshore-offshore 3-D seismic velocity model for the Island of Hawaii, derived from a joint tomographic inversion of an offshore airgun shot - onshore receiver geometry and earthquake sources beneath the island, demonstrates a complicated history of rift zone reconfiguration on Mauna Loa volcano, Hawaii, including wholesale rift zone abandonment. Mauna Loa’s southeast flank contains a massive high velocity intrusive complex, now buried beneath flows derived from Mauna Loa’s active southwest rift zone (SWRZ). Introduced here as the Ninole Rift Zone, this feature extends more than 60 km south of Mauna Loa’s summit, spans a depth range of ~2-14 km below sea level, and is the probable source of the 100-200 ka Ninole volcanics in several prominent erosional hills. A lack of high velocities beneath the upper SWRZ and its separate zone of high velocities on the submarine flank, indicate that the younger rift zone was built upon a pre-existing edifice that emanated from the Ninole rift zone. The ancient Ninole rift zone may stabilize Mauna Loa’s southeast flank, focusing recent volcanic activity and deformation onto the unbuttressed west flank. The upper portion of the Ninole rift zone appears to have migrated westward over time, possibly triggered by landsliding, causing its eventual abandonment in preference to Mauna Loa’s present-day SWRZ. Subsequently, the lower SWRZ broke away, tracking rift intrusions along the trace of the Kahuku detachment fault. Similar rift zone migration is thought to be underway at Kilauea volcano, and may one-day lead to the abandonment of the east rift zone. Such rift zone reconfiguration is a reflection of changing stress conditions within growing volcanoes. It is probably much more common than previously assumed, and may enable the growth of very large volcanic edifices such as Mauna Loa.

"Sub Specie Boni": The Comfort Zone of Self-Belief--A Dimension in Counseling Offenders.

ERIC Educational Resources Information Center

Church, James Lee

1996-01-01

Claims that self-defeating behavior is a rational attempt to satisfy early, introjected messages about the type of person one is, arising from a desire for things perceived as good--sub specie boni. Examines the notion of the comfort zone, toxic shame, and therapists' responsibility to nourish acceptable joy. (RJM)

What can friction tell us about shallow megathrust slip behavior?

NASA Astrophysics Data System (ADS)

Ikari, M.; Kopf, A.; Hirose, T.

2012-12-01

In subduction zones, the updip propagation of great earthquake ruptures on plate boundary megathrusts is currently one of the most important questions in earth science, primarily because rupture that approaches the surface causes seafloor displacement, resulting in enormous tsunamis. Moreover, the extent of updip rupture propagation is a key factor in defining the magnitude of the earthquake itself. Within the depth limits of the seismogenic zone, velocity-weakening frictional behavior is essential for the nucleation of large-magnitude earthquake rupture. Results of friction experiments at low slip velocities (~10-6-10-4 m/s) have suggested that velocity-weakening tends to occur in frictionally strong materials (typically non-clay), which may act as asperities on fault surfaces. However, the role of frictional strength and velocity dependence in controlling the extent of rupture propagation beyond the updip limit of the seismogenic zone is still unclear. Low to high-velocity friction experiments have provided insights into fault strength evolution over slip velocities spanning ~10 orders of magnitude, from plate convergence rates to coseismic slip rates. Results using primarily non-clay materials typically exhibit high friction at low velocities that progressively weakens at higher velocities (velocity-weakening), becoming nearly frictionless at coseismic slip rates [Di Toro et al., 2011]. However, the shallow near-trench regions of subduction zones are typically rich in clay minerals which are weak (friction coefficient ≤ ~0.4) and velocity-strengthening at slip rates < 10-3 m/s. A compilation of friction experiments using samples from the Nankai Trough region offshore Japan obtained by scientific ocean drilling shows that this material exhibits such behavior at low to intermediate slip velocities. However, after reaching peak values at ~10-2 m/s, these materials also exhibit a precipitous drop in friction toward near-zero values at coseismic slip rates. This suggests that all geologic materials, regardless of composition, are extremely weak when coseismic slip rates are enforced. Therefore, the likelihood of near-trench rupture propagation in subduction zones depends critically on whether slip can reach velocities ≥ ~10-2 m/s, where dynamic weakening becomes dominant. This depends on whether the propagating earthquake rupture can overcome the overall strength of the fault gouge and/or velocity-strengthening behavior at low to intermediate slip rates. We discuss here the possibility of near-trench earthquake rupture at Nankai and other subduction zones on the basis of laboratory friction measurements.

Assessing the joint impact of DNAPL source-zone behavior and degradation products on the probabilistic characterization of human health risk

NASA Astrophysics Data System (ADS)

Henri, Christopher V.; Fernàndez-Garcia, Daniel; de Barros, Felipe P. J.

2016-02-01

The release of industrial contaminants into the subsurface has led to a rapid degradation of groundwater resources. Contamination caused by Dense Non-Aqueous Phase Liquids (DNAPLs) is particularly severe owing to their limited solubility, slow dissolution and in many cases high toxicity. A greater insight into how the DNAPL source zone behavior and the contaminant release towards the aquifer impact human health risk is crucial for an appropriate risk management. Risk analysis is further complicated by the uncertainty in aquifer properties and contaminant conditions. This study focuses on the impact of the DNAPL release mode on the human health risk propagation along the aquifer under uncertain conditions. Contaminant concentrations released from the source zone are described using a screening approach with a set of parameters representing several scenarios of DNAPL architecture. The uncertainty in the hydraulic properties is systematically accounted for by high-resolution Monte Carlo simulations. We simulate the release and the transport of the chlorinated solvent perchloroethylene and its carcinogenic degradation products in randomly heterogeneous porous media. The human health risk posed by the chemical mixture of these contaminants is characterized by the low-order statistics and the probability density function of common risk metrics. We show that the zone of high risk (hot spot) is independent of the DNAPL mass release mode, and that the risk amplitude is mostly controlled by heterogeneities and by the source zone architecture. The risk is lower and less uncertain when the source zone is formed mostly by ganglia than by pools. We also illustrate how the source zone efficiency (intensity of the water flux crossing the source zone) affects the risk posed by an exposure to the chemical mixture. Results display that high source zone efficiencies are counter-intuitively beneficial, decreasing the risk because of a reduction in the time available for the production of the highly toxic subspecies.

Geochemical behavior of rare earth elements of the hydrothermal alterations within the Tepeoba porphyry Cu-Mo-Au deposits at Balikesir, NW Turkey

NASA Astrophysics Data System (ADS)

Doner, Zeynep; Abdelnasser, Amr; Kiran Yildirim, Demet; Kumral, Mustafa

2016-04-01

This work reports the geochemical characteristics and behavior of the rare earth elements (REE) of the hydrothermal alteration of the Tepeoba porphyry Cu-Mo-Au deposit located in the Anatolian tectonic belt at Biga peninsula (Locally Balikesir province), NW Turkey. The Cu-Mo-Au mineralization at this deposit hosted in the hornfels rocks and related to the silicic to intermediate intrusion of Eybek pluton. It locally formed with brecciated zones and quartz vein stockworks, as well as the brittle fracture zones associated with intense hydrothermal alteration. Three main alteration zones with gradual boundaries formed in the mine area in the hornfels rock that represents the host rock, along that contact the Eybek pluton; potassic, propylitic and phyllic alteration zones. The potassic alteration zone that formed at the center having high amount of Cu-sulfide minerals contains biotite, muscovite, and sericite with less amount of K-feldspar and associated with tourmalinization alteration. The propylitic alteration surrounds the potassic alteration having high amount of Mo and Au and contains chlorite, albite, epidote, calcite and pyrite. The phyllic alteration zone also surrounds the potassic alteration containing quartz, sericite and pyrite minerals. Based on the REE characteristics and content and when we correlate the Alteration index (AI) with the light REEs and heavy REEs of each alteration zone, it concluded that the light REEs decrease and heavy REEs increase during the alteration processes. The relationships between K2O index with Eu/Eu* and Sr/Sr* reveals a positive correlation in the potassic and phyllic alteration zones and a negative correlation in the propylitic alteration zone. This refers to the hydrothermal solution which is responsible for the studied porphyry deposits and associated potassic and phyllic alterations has a positive Eu and Sr anomaly as well as these elements were added to the altered rock from the hydrothermal solution. Keywords: Rare earth elements geochemistry; Tepeoba porphyry Cu-Mo-Au deposits; Balikesir; Turkey

Multi-Dimensional Analysis of Large, Complex Slope Instability: Case study of Downie Slide, British Columbia, Canada. (Invited)

NASA Astrophysics Data System (ADS)

Kalenchuk, K. S.; Hutchinson, D.; Diederichs, M. S.

2013-12-01

Downie Slide, one of the world's largest landslides, is a massive, active, composite, extremely slow rockslide located on the west bank of the Revelstoke Reservoir in British Columbia. It is a 1.5 billion m3 rockslide measuring 2400 m along the river valley, 3300m from toe to headscarp and up to 245 m thick. Significant contributions to the field of landslide geomechanics have been made by analyses of spatially and temporally discriminated slope deformations, and how these are controlled by complex geological and geotechnical factors. Downie Slide research demonstrates the importance of delineating massive landslides into morphological regions in order to characterize global slope behaviour and identify localized events, which may or may not influence the overall slope deformation patterns. Massive slope instabilities do not behave as monolithic masses, rather, different landslide zones can display specific landslide processes occurring at variable rates of deformation. The global deformation of Downie Slide is extremely slow moving; however localized regions of the slope incur moderate to high rates of movement. Complex deformation processes and composite failure mechanism are contributed to by topography, non-uniform shear surfaces, heterogeneous rockmass and shear zone strength and stiffness characteristics. Further, from the analysis of temporal changes in landslide behaviour it has been clearly recognized that different regions of the slope respond differently to changing hydrogeological boundary conditions. State-of-the-art methodologies have been developed for numerical simulation of large landslides; these provide important tools for investigating dynamic landslide systems which account for complex three-dimensional geometries, heterogenous shear zone strength parameters, internal shear zones, the interaction of discrete landslide zones and piezometric fluctuations. Numerical models of Downie Slide have been calibrated to reproduce observed slope behaviour, and the calibration process has provided important insight to key factors controlling massive slope mechanics. Through numerical studies it has been shown that the three-dimensional interpretation of basal slip surface geometry and spatial heterogeneity in shear zone stiffness are important factors controlling large-scale slope deformation processes. The role of secondary internal shears and the interaction between landslide morphological zones has also been assessed. Further, numerical simulation of changing groundwater conditions has produced reasonable correlation with field observations. Calibrated models are valuable tools for the forward prediction of landslide dynamics. Calibrated Downie Slide models have been used to investigate how trigger scenarios may accelerate deformations at Downie Slide. The ability to reproduce observed behaviour and forward test hypothesized changes to boundary conditions has valuable application in hazard management of massive landslides. The capacity of decision makers to interpret large amounts of data, respond to rapid changes in a system and understand complex slope dynamics has been enhanced.

New access to the deep interior of the Nankai accretionary complex and comprehensive characterization of subduction inputs and recent mega splay fault activity (IODP-NanTroSEIZE Expedition 338)

NASA Astrophysics Data System (ADS)

Strasser, Michael; Moore, Gregory F.; Kanagawa, Kyuichi; Dugan, Brandon; Fabbri, Olivier; Toczko, Sean; Maeda, Lena

2013-04-01

The Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) is a coordinated, multi-expedition Integrated Ocean Drilling Program (IODP) drilling project designed to investigate fault mechanics and seismogenesis along subduction megathrusts through direct sampling, in situ measurements, and long-term monitoring in conjunction with allied laboratory and numerical modeling studies. IODP Expedition 338 (1 October 2012 - 13 January 2013), extended riser Hole C0002F from 856 meters below the sea floor (mbsf) to 2005 mbsf. Site C0002 is the centerpiece of the NanTroSEIZE project, and is planned to be deepened to eventually reach the seismogenic fault zone during upcoming drilling expeditions. The original Exp. 338 operational plan to case the hole to 3600 mbsf had to be revised as sudden changes in sea conditions resulted in damage to parts of the riser system, thus the hole was suspended at 2005 mbsf but left for future re-entry. The revised operation plan included additional riserless logging and coring of key targets not sampled during previous NanTroSEIZE expeditions, but relevant to comprehensively characterize the alteration stage of the oceanic basement input to the subduction zone, the early stage of Kumano Basin evolution and the recent activity of the shallow mega splay fault zone system and submarine landslides. Here we present preliminary results from IODP Exp. 338: Logging While Drilling (LWD), mud gas monitoring and analysis on cuttings from the deep riser hole characterize two lithological units within the internal accretionary prism, separated by a prominent fault zone at ~1640 mbsf. Internal style of deformation, downhole increase of thermogenically formed formation gas and evidence for mechanical compaction and cementation document a complex structural evolution and provide unprecedented insights into the mechanical state and behavior of the wedge at depth. Additionally, multiple samples of the unconformity between the Kumano Basin and accretionary prism at Site C0002 shed new light on this debatable unconformity boundary and suggest variable erosional processes active on small spatial scales. Results from riserless drilling at input Site C0012 include 178.7 m of detailed LWD characterization of the oceanic basement, indicating an upper ~100 m zone of altered pillow basalts and sheet flow deposits, and a lower, presumably less altered basement unit without indication for interlayered sediment horizons. Low angle faults identified in X-ray Computed Tomography images and structural investigation on cores from Site C0022, located in the slope basin immediately seaward of the megasplay fault zone, indicate splay-fault-related, out-of-sequence thrusting within slope basin sediments and shed new light on recent activity of the megasplay. Lastly, Exp. 338 added additional coring to improve our understanding of submarine landslides in the slope basins seaward of the splay fault and yields new LWD data to characterize in situ internal structures and properties of mass-transport deposits as it relates to the dynamics and kinematics of submarine landslides.

Regional variations in growth plate chondrocyte deformation as predicted by three-dimensional multi-scale simulations.

PubMed

Gao, Jie; Roan, Esra; Williams, John L

2015-01-01

The physis, or growth plate, is a complex disc-shaped cartilage structure that is responsible for longitudinal bone growth. In this study, a multi-scale computational approach was undertaken to better understand how physiological loads are experienced by chondrocytes embedded inside chondrons when subjected to moderate strain under instantaneous compressive loading of the growth plate. Models of representative samples of compressed bone/growth-plate/bone from a 0.67 mm thick 4-month old bovine proximal tibial physis were subjected to a prescribed displacement equal to 20% of the growth plate thickness. At the macroscale level, the applied compressive deformation resulted in an overall compressive strain across the proliferative-hypertrophic zone of 17%. The microscale model predicted that chondrocytes sustained compressive height strains of 12% and 6% in the proliferative and hypertrophic zones, respectively, in the interior regions of the plate. This pattern was reversed within the outer 300 μm region at the free surface where cells were compressed by 10% in the proliferative and 26% in the hypertrophic zones, in agreement with experimental observations. This work provides a new approach to study growth plate behavior under compression and illustrates the need for combining computational and experimental methods to better understand the chondrocyte mechanics in the growth plate cartilage. While the current model is relevant to fast dynamic events, such as heel strike in walking, we believe this approach provides new insight into the mechanical factors that regulate bone growth at the cell level and provides a basis for developing models to help interpret experimental results at varying time scales.

Limit cycles at the outer edge of the habitable zone

NASA Astrophysics Data System (ADS)

Haqq-Misra, J. D.; Kopparapu, R.; Batalha, N. E.; Harman, C.; Kasting, J. F.

2016-12-01

The liquid water habitable zone (HZ) describes the orbital distance at which a terrestrial planet can maintain above-freezing conditions through regulation by the carbonate-silicate cycle. Calculations with one-dimensional climate models predict that the inner edge of the HZ is limited by water loss through a runaway greenhouse, while the outer edge of the HZ is bounded by the maximum greenhouse effect of carbon dioxide. This classic picture of the HZ continues to guide interpretation of exoplanet discoveries; however, recent calculations have shown that terrestrial planets near the outer edge of the HZ may exhibit other behaviors that affect their habitability. Here I discuss results from a hierarchy of climate models to understand the stellar environments most likely to support a habitable planet. I present energy balance climate model calculations showing the conditions under which planets in the outer regions of the habitable zone should oscillate between long, globally glaciated states and shorter periods of climatic warmth, known as `limit cycles.' Such conditions would be inimical to the development of complex land life, including intelligent life. Limit cycles may also provide an explanation for fluvial features on early Mars, although this requires additional greenhouse warming by hydrogen. These calculations show that the net volcanic outgassing rate and the propensity for plant life to sequester carbon dioxide are critical factors that determine the susceptibility of a planet to limit cycling. I argue that planets orbiting mid G- to mid K-type stars offer more opportunity for supporting advanced life than do planets around F-type stars or M-type stars.

Geochemical evolution of the Critical Zone across variable time scales informs concentration-discharge relationships: Jemez River Basin Critical Zone Observatory

NASA Astrophysics Data System (ADS)

McIntosh, Jennifer C.; Schaumberg, Courtney; Perdrial, Julia; Harpold, Adrian; Vázquez-Ortega, Angélica; Rasmussen, Craig; Vinson, David; Zapata-Rios, Xavier; Brooks, Paul D.; Meixner, Thomas; Pelletier, Jon; Derry, Louis; Chorover, Jon

2017-05-01

This study investigates the influence of water, carbon, and energy fluxes on solute production and transport through the Jemez Critical Zone (CZ) and impacts on C-Q relationships over variable spatial and temporal scales. Chemical depletion-enrichment profiles of soils, combined with regolith thickness and groundwater data indicate the importance to stream hydrochemistry of incongruent dissolution of silicate minerals during deep bedrock weathering, which is primarily limited by water fluxes, in this highly fractured, young volcanic terrain. Under high flow conditions (e.g., spring snowmelt), wetting of soil and regolith surfaces and presence of organic acids promote mineral dissolution and provide a constant supply of base cations, Si, and DIC to soil water and groundwater. Mixing of waters from different hydrochemical reservoirs in the near stream environment during "wet" periods leads to the chemostatic behavior of DIC, base cations, and Si in stream flow. Metals transported by organic matter complexation (i.e., Ge, Al) and/or colloids (i.e., Al) during periods of soil saturation and lateral connectivity to the stream display a positive relationship with Q. Variable Si-Q relationships, under all but the highest flow conditions, can be explained by nonconservative transport and precipitation of clay minerals, which influences long versus short-term Si weathering fluxes. By combining measurements of the CZ obtained across different spatial and temporal scales, we were able to constrain weathering processes in different hydrological reservoirs that may be flushed to the stream during hydrologic events, thereby informing C-Q relationships.

Regional Variations in Growth Plate Chondrocyte Deformation as Predicted By Three-Dimensional Multi-Scale Simulations

PubMed Central

Gao, Jie; Roan, Esra; Williams, John L.

2015-01-01

The physis, or growth plate, is a complex disc-shaped cartilage structure that is responsible for longitudinal bone growth. In this study, a multi-scale computational approach was undertaken to better understand how physiological loads are experienced by chondrocytes embedded inside chondrons when subjected to moderate strain under instantaneous compressive loading of the growth plate. Models of representative samples of compressed bone/growth-plate/bone from a 0.67 mm thick 4-month old bovine proximal tibial physis were subjected to a prescribed displacement equal to 20% of the growth plate thickness. At the macroscale level, the applied compressive deformation resulted in an overall compressive strain across the proliferative-hypertrophic zone of 17%. The microscale model predicted that chondrocytes sustained compressive height strains of 12% and 6% in the proliferative and hypertrophic zones, respectively, in the interior regions of the plate. This pattern was reversed within the outer 300 μm region at the free surface where cells were compressed by 10% in the proliferative and 26% in the hypertrophic zones, in agreement with experimental observations. This work provides a new approach to study growth plate behavior under compression and illustrates the need for combining computational and experimental methods to better understand the chondrocyte mechanics in the growth plate cartilage. While the current model is relevant to fast dynamic events, such as heel strike in walking, we believe this approach provides new insight into the mechanical factors that regulate bone growth at the cell level and provides a basis for developing models to help interpret experimental results at varying time scales. PMID:25885547

Electronic behavior of highly correlated metals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reich, A.

1988-10-01

This thesis addresses the question of the strongly interacting many-body problem: that is, systems where the interparticle correlations are so strong as to defy perturbative approaches. These subtle correlations occur in narrow band materials, such as the lanthanides and actinides, wherein the f-electrons are so localized that a variety of new phenomena, including intermediate-valence and heavy-fermionic behavior, may occur. As well, one has the alloying problem, where local interactions are paramount in determining the overall behavior. The technique employed in dealing with these systems is the Small Cluster method, wherein the full many-body Hamiltonian for a small grouping of atoms,more » coupled with periodic boundary conditions, is solved exactly. This is tantamount to solving a bulk crystal at the high points of symmetry in the Brillouin Zone. The mathematical overhead is further reduced by employing the full space group and spin symmetries. By its very nature, the Small Cluster method is well able to handle short-range interactions, as well as the combinatorial complexity of the many-body problem, on an equal footing. The nature of long-range order and phase transition behavior cannot be incorporated, but sometimes clues as to their origin can be discerned. The calculations presented include: a two-band Anderson model for an intermediate-valence system, wherein photoemission and fluctuation behavior is examined; a single-band Hubbard model for a ternary alloy system, such as copper-silver-gold; and a Hubbard model for a heavy- fermion system, wherein Fermi surface, transport, magnetic and superconducting properties are discussed. 148 refs., 31 figs., 24 tabs.« less

Stress relaxation of swine growth plate in semi-confined compression: depth dependent tissue deformational behavior versus extracellular matrix composition and collagen fiber organization.

PubMed

Amini, Samira; Mortazavi, Farhad; Sun, Jun; Levesque, Martin; Hoemann, Caroline D; Villemure, Isabelle

2013-01-01

Mechanical environment is one of the regulating factors involved in the process of longitudinal bone growth. Non-physiological compressive loading can lead to infantile and juvenile musculoskeletal deformities particularly during growth spurt. We hypothesized that tissue mechanical behavior in sub-regions (reserve, proliferative and hypertrophic zones) of the growth plate is related to its collagen and proteoglycan content as well as its collagen fiber orientation. To characterize the strain distribution through growth plate thickness and to evaluate biochemical content and collagen fiber organization of the three histological zones of growth plate tissue. Distal ulnar growth plate samples (N = 29) from 4-week old pigs were analyzed histologically for collagen fiber organization (N = 7) or average zonal thickness (N = 8), or trimmed into the three average zones, based on the estimated thickness of each histological zone, for biochemical analysis of water, collagen and glycosaminoglycan content (N = 7). Other samples (N = 7) were tested in semi-confined compression under 10% compressive strain. Digital images of the fluorescently labeled nuclei were concomitantly acquired by confocal microscopy before loading and after tissue relaxation. Strain fields were subsequently calculated using a custom-designed 2D digital image correlation algorithm. Depth-dependent compressive strain patterns and collagen content were observed. The proliferative and hypertrophic zone developed the highest axial and transverse strains, respectively, under compression compared to the reserve zone, in which the lowest axial and transverse strains arose. The collagen content per wet mass was significantly lower in the proliferative and hypertrophic zones compared to the reserve zone, and all three zones had similar glycosaminoglycan and water content.Polarized light microscopy showed that collagen fibers were mainly organized horizontally in the reserve zone and vertically aligned with the growth direction in the proliferative and hypertrophic zones. Higher strains were developed in growth plate areas (proliferative and hypertrophic) composed of lower collagen content and of vertical collagen fiber organization. The stiffer reserve zone, with its higher collagen content and collagen fibers oriented to restrain lateral expansion under compression, could play a greater role of mechanical support compared to the proliferative and hypertrophic zones, which could be more susceptible to be involved in an abnormal growth process.

Relating runoff generation mechanisms to concentration-discharge relationships in catchments with well-characterized Critical Zone structures and hydrologic dynamics

NASA Astrophysics Data System (ADS)

Hahm, W. J.; Wang, J.; Druhan, J. L.; Rempe, D.; Dietrich, W. E.

2017-12-01

Stream solute concentration-discharge (C-Q) relationships integrate catchment-scale hydrologic and geochemical processes, potentially yielding valuable information about runoff generation and weathering mechanisms. However, recent compilations have established that chemostasis—the condition where solute concentrations are invariant across large ranges of runoff—is observed in watersheds of diverse lithology, climate, and topography, suggesting an equifinality of the C-Q relationship independent of hydrologic process. Here we explore C-Q signals in contrasting catchments of the Eel River Critical Zone (CZ) Observatory in the Northern California Coast Ranges, where, unlike most watersheds where chemostasis has been observed, hillslope hydrologic processes are well characterized via years of intensive hydrologic monitoring. Our two catchments in the Franciscan Complex have radically different runoff generation mechanisms arising from differences in CZ structure: at Elder Creek (Coastal Belt), rain passes vertically as unsaturated flow through soil, saprolite, and a thick weathered rock zone before perching as groundwater on fresh bedrock and flowing laterally through fractures to generate streamflow, resulting in nearly chemostatic major cation behavior (power law C-Q slopes (B) ≈ 0 to -0.1). At Dry Creek (Central Belt), the thin (2 to 3 m) hydrologically active CZ completely saturates in most storm events, generating saturation overland flow across the landscape. New data from Dry Creek reveal log-log C-Q relationships for major cations that exhibit negative curvature, indicating a trend towards increasing dilution at higher flow rates and a possible C-Q signature of overland flow. High geomorphic channel drainage density (16.9 km/km2) results in short flow paths and, presumably, short water hillslope residence times at high runoff when overland flow dominates (> 50 mm d-1). Surprisingly, even at these high runoff rates, pure dilution does not occur (high runoff B ≈ -0.5), suggesting a role for extremely rapid cation exchange reactions and equilibration as water flows over and through the soil surface, and underscoring limitations on the ability to interpret hydrologic processes from C-Q behavior.

Disentangling the influence of cell phone usage in the dilemma zone: An econometric approach.

PubMed

Eluru, Naveen; Yasmin, Shamsunnahar

2016-11-01

This paper focuses on developing an analysis framework to study the impact of cell phone treatment (cell phone type and call status) on driver behavior in the presence of a dilemma zone. Specifically, we examine how the treatment influences the driver maneuver decision at the intersection (stop or cross) and the eventual success of the maneuver. For a stop maneuver, success is defined as stopping before the stop line. Similarly, for a cross maneuver, success is defined as clearing the intersection safely before the light turns red. The eventual success or failure of the driver's decision process is dependent on the factors that affected the maneuver decision. Hence it is important to recognize the interconnectedness of the stop or cross decision with its eventual success (or failure). Toward this end, we formulate and estimate a joint framework to analyze the stop/cross decision with its eventual success (or failure) simultaneously. The study is conducted based on driving simulator data provided online for the 2014 Transportation Research Board Data Contest at http://depts.washington.edu/hfsm/upload.php. The model is estimated to analyze drivers' behavior at the onset of yellow by employing exogenous variables from three broad categories: driver characteristics, cell phone attributes and driving attributes. We also generate probability surfaces to identify dilemma zone distribution associated with different cell phone treatment types. The plots clearly illustrate the impact of various cellphone treatments on driver dilemma zone behavior. Copyright © 2015 Elsevier Ltd. All rights reserved.

Effect of Segregation of Secondary Phase Particles and "S" Line on Tensile Fracture Behavior of Friction Stir-Welded 2024Al-T351 Joints

NASA Astrophysics Data System (ADS)

Zhang, Z.; Xiao, B. L.; Ma, Z. Y.

2013-09-01

A 5-mm-thick 2024Al-T351 plate was friction stir welded (FSWed) at welding speeds of 100, 200, and 400 mm min-1 with a constant rotation rate of 800 rpm, and the microstructure and tensile fracture behavior of the joints were investigated in detail. FSW resulted in the redistribution of secondary phase particles along the recrystallized grain boundaries at the nugget zone (NZ), forming linear segregation bands consisting of secondary phase particles. The segregation bands, mainly present in the shoulder-driven zone, were believed to result from periodic material flow, with the average band spacing on the longitudinal and horizontal cross sections equal to the tool advancement per revolution. At a low welding speed of 100 mm min-1, in spite of the highest density of segregation bands, the FSWed 2024Al-T351 joint fractured along the low hardness zone (LHZ) of the heat-affected zone because of large hardness gap between NZ and LHZ. Increasing the welding speed to 200 and 400 mm min-1 reduced both the hardness gap between NZ and LHZ and the density of segregation bands. In this case, the segregation bands played a role, resulting in unusual fracture of the joints along the segregation bands. The "S" line originated from the oxide film on the initial butting surfaces and did not affect the fracture behavior of the FSWed 2024Al-T351 joints.

Exposing ecological and economic costs of the research-implementation gap and compromises in decision making.

PubMed

Kareksela, Santtu; Moilanen, Atte; Ristaniemi, Olli; Välivaara, Reima; Kotiaho, Janne S

2018-02-01

The frequently discussed gap between conservation science and practice is manifest in the gap between spatial conservation prioritization plans and their implementation. We analyzed the research-implementation gap of one zoning case by comparing results of a spatial prioritization analysis aimed at avoiding ecological impact of peat mining in a regional zoning process with the final zoning plan. We examined the relatively complex planning process to determine the gaps among research, zoning, and decision making. We quantified the ecological costs of the differing trade-offs between ecological and socioeconomic factors included in the different zoning suggestions by comparing the landscape-level loss of ecological features (species occurrences, habitat area, etc.) between the different solutions for spatial allocation of peat mining. We also discussed with the scientists and planners the reasons for differing zoning suggestions. The implemented plan differed from the scientists suggestion in that its focus was individual ecological features rather than all the ecological features for which there were data; planners and decision makers considered effects of peat mining on areas not included in the prioritization analysis; zoning was not truly seen as a resource-allocation process and not emphasized in general minimizing ecological losses while satisfying economic needs (peat-mining potential); and decision makers based their prioritization of sites on site-level information showing high ecological value and on single legislative factors instead of finding a cost-effective landscape-level solution. We believe that if the zoning and decision-making processes are very complex, then the usefulness of science-based prioritization tools is likely to be reduced. Nevertheless, we found that high-end tools were useful in clearly exposing trade-offs between conservation and resource utilization. © 2017 Society for Conservation Biology.

Genesis of the hydrothermal gold deposits in the Canan area, Lepaguare District, Honduras

NASA Astrophysics Data System (ADS)

Mattioli, Michele; Menichetti, Marco; Renzulli, Alberto; Toscani, Lorenzo; Salvioli-Mariani, Emma; Suarez, Pedro; Murroni, Alessandro

2014-04-01

The Canan area (Honduras) is characterized by a gold-bearing ore deposit that is associated with quartz-veined shear zones. Gold mineralization occurs in low-to medium-grade metamorphic host-rocks (graphitic and sericitic schists). Hydrothermal fluids, which are associated with the emplacement of Cretaceous-Tertiary granodioritic intrusions, are responsible for the formation of quartz veins and the hydrothermal alteration of wall-rocks. Three main altered zones have been detected in the wall-rocks as far as 150 cm from the quartz veins. The distal zone (up to 50-cm thick) contains quartz, chlorite and illite. The intermediate zone is the thickest (up to 80 cm) and is marked by quartz, muscovite, sulphides, kaolinite and native elements such as Au and Ag. The proximal zone, which is close to the quartz veins, is rather thin (up to 25 cm) and contains clay minerals, Al-oxides-hydroxides and sulphides. The transition from the distal to the proximal zone is accompanied by the enrichment of SiO2 and the depletion of all other major elements, except for Fe2O3(tot). Precious metals occur in the highest concentrations in the intermediate zone (Au up to 7.6 ppm and Ag up to 11 ppm). We suggest that gold was transported as a reduced sulphur complex and was precipitated from the hydrothermal solution by the reaction of the sulphur complexes with Fe2+ from the alteration of the mafic minerals of the host-rock. Fluid-wall-rock interactions seem to be the main cause of gold mineralization. Genetic relationships with a strike-slip fault system, hydrothermal alteration zones within the metamorphic wall-rocks, and an entire set of geochemical anomalies are consistent with orogenic-type gold deposits of the epizonal class.

Aerothermal modeling program, phase 1

NASA Technical Reports Server (NTRS)

Srinivasan, R.; Reynolds, R.; Ball, I.; Berry, R.; Johnson, K.; Mongia, H.

1983-01-01

The combustor performance submodels for complex flows are evaluated. The benchmark test cases for complex nonswirling flows are identified and analyzed. The introduction of swirl into the flow creates much faster mixing, caused by radial pressure gradients and increase in turbulence generation. These phenomena are more difficult to predict than the effects due to geometrical streamline curvatures, like the curved duct, and sudden expansion. Flow fields with swirl, both confined and unconfined are studied. The role of the dilution zone to achieve the turbine inlet radial profile plays an important part, therefore temperature field measurements were made in several idealized dilution zone configurations.

Use of photostress to characterize the mechanical behavior of weldments

NASA Technical Reports Server (NTRS)

Gambrell, S. C., Jr.

1992-01-01

Welded aluminum is an important part of many space structures. Knowledge of the properties and behavior of weld material and the material surrounding the weld is important for modeling and design of the structures. Photoelastic coatings (Photostress) and strain gages were used to determine behavior of heat treated and as welded joints made from 2219T87 parent material and 2319 weld material subjected to tensile loads. TIG welds of 1/8, 1/2, and 1.4 inches thickness were investigated. Discontinuous yielding was observed in all tests and highly non-uniform behavior through the weld thickness was observed in joints having welds 1.4 inches thick. Joints having welds 1/8 and 1/2 inches thick had only small differences in behavior through the thickness of the weld. Joints in the 1/2 inch thick material contained distinct zones of constant strain within the normal strain gradient extending outward from the weld centerline. These zones had different thickness and locations. Points at the weld centerline, and for a distance of nearly one inch from the centerline, exhibited very nonlinear behavior during the first loading but exhibited near perfect strain hardening during the second loading.

Amygdala inputs to the ventral hippocampus bidirectionally modulate social behavior.

PubMed

Felix-Ortiz, Ada C; Tye, Kay M

2014-01-08

Impairments in social interaction represent a core symptom of a number of psychiatric disease states, including autism, schizophrenia, depression, and anxiety. Although the amygdala has long been linked to social interaction, little is known about the functional role of connections between the amygdala and downstream regions in noncompetitive social behavior. In the present study, we used optogenetic and pharmacological tools in mice to study the role of projections from the basolateral complex of the amygdala (BLA) to the ventral hippocampus (vHPC) in two social interaction tests: the resident-juvenile-intruder home-cage test and the three chamber sociability test. BLA pyramidal neurons were transduced using adeno-associated viral vectors (AAV5) carrying either channelrhodopsin-2 (ChR2) or halorhodopsin (NpHR), under the control of the CaMKIIα promoter to allow for optical excitation or inhibition of amygdala axon terminals. Optical fibers were chronically implanted to selectively manipulate BLA terminals in the vHPC. NpHR-mediated inhibition of BLA-vHPC projections significantly increased social interaction in the resident-juvenile intruder home-cage test as shown by increased intruder exploration. In contrast, ChR2-mediated activation of BLA-vHPC projections significantly reduced social behaviors as shown in the resident-juvenile intruder procedure as seen by decreased time exploring the intruder and in the three chamber sociability test by decreased time spent in the social zone. These results indicate that BLA inputs to the vHPC are capable of modulating social behaviors in a bidirectional manner.

Extrapolating Solar Dynamo Models Throughout the Heliosphere

NASA Astrophysics Data System (ADS)

Cox, B. T.; Miesch, M. S.; Augustson, K.; Featherstone, N. A.

2014-12-01

There are multiple theories that aim to explain the behavior of the solar dynamo, and their associated models have been fiercely contested. The two prevailing theories investigated in this project are the Convective Dynamo model that arises from the pure solving of the magnetohydrodynamic equations, as well as the Babcock-Leighton model that relies on sunspot dissipation and reconnection. Recently, the supercomputer simulations CASH and BASH have formed models of the behavior of the Convective and Babcock-Leighton models, respectively, in the convective zone of the sun. These models show the behavior of the models within the sun, while much less is known about the effects these models may have further away from the solar surface. The goal of this work is to investigate any fundamental differences between the Convective and Babcock-Leighton models of the solar dynamo outside of the sun and extending into the solar system via the use of potential field source surface extrapolations implemented via python code that operates on data from CASH and BASH. The use of real solar data to visualize supergranular flow data in the BASH model is also used to learn more about the behavior of the Babcock-Leighton Dynamo. From the process of these extrapolations it has been determined that the Babcock-Leighton model, as represented by BASH, maintains complex magnetic fields much further into the heliosphere before reverting into a basic dipole field, providing 3D visualisations of the models distant from the sun.

Emotional Prosody Processing in Epilepsy: Some Insights on Brain Reorganization.

PubMed

Alba-Ferrara, Lucy; Kochen, Silvia; Hausmann, Markus

2018-01-01

Drug resistant epilepsy is one of the most complex, multifactorial and polygenic neurological syndrome. Besides its dynamicity and variability, it still provides us with a model to study brain-behavior relationship, giving cues on the anatomy and functional representation of brain function. Given that onset zone of focal epileptic seizures often affects different anatomical areas, cortical but limited to one hemisphere, this condition also let us study the functional differences of the left and right cerebral hemispheres. One lateralized function in the human brain is emotional prosody, and it can be a useful ictal sign offering hints on the location of the epileptogenic zone. Besides its importance for effective communication, prosody is not considered an eloquent domain, making resective surgery on its neural correlates feasible. We performed an Electronic databases search (Medline and PsychINFO) from inception to July 2017 for studies about prosody in epilepsy. The search terms included "epilepsy," "seizure," "emotional prosody," and "vocal affect." This review focus on emotional prosody processing in epilepsy as it can give hints regarding plastic functional changes following seizures (preoperatively), resection (post operatively), and also as an ictal sign enabling the assessment of dynamic brain networks. Moreover, it is argued that such reorganization can help to preserve the expression and reception of emotional prosody as a central skill to develop appropriate social interactions.

Textures of eclogites and blueschists from Syros island, Greece: Inferences for elastic anisotropy of subducted oceanic crust

NASA Astrophysics Data System (ADS)

Keppler, Ruth; Behrmann, Jan H.; Stipp, Michael

2017-07-01

Many blueschists and eclogites are inferred to have formed from oceanic basalts in subducted slabs. Knowledge of their elastic behavior is essential for reconstructing the internal structure of subduction zones. The Cycladic blueschist unit, exposed on Syros Island (Greece), contains rocks belonging to an exhumed Tertiary subduction complex. They were possibly part of a subduction channel, a shear zone above the subducting slab in which exhumation is possible during subduction. Intense plastic deformation, forming crystallographic preferred orientations (CPO), accompanied blueschist and eclogite metamorphism. CPO of the constituent minerals in the collected samples was determined by time-of-flight neutron diffraction. Two samples are foliated fine-grained blueschists with strong CPO, rich in glaucophane, zoisite, and phengite. Two coarser-grained eclogite samples rich in omphacite and clinozoisite, or glaucophane, have weaker CPO. Vp and Vs anisotropies were computed from the orientation distribution function and single-crystal elastic constants. All samples show velocity maxima parallel to the mineral lineation, and minima normal to the foliation, providing important constraints on orientations of seismic anisotropy in subduction channels. Vp anisotropies are up to 3 times higher (6.5-12%) in the blueschists than in the eclogites (3-4%), pointing to a potentially important lithological control of elastic anisotropy in subducted oceanic crust.

Petrology, geochemistry and geochonology of the Jacupiranga ultramafic, alkaline and carbonatitic complex (southern Brazil)

NASA Astrophysics Data System (ADS)

Chmyz, Luanna; Arnaud, Nicolas; Biondi, João Carlos

2015-04-01

Brazilian carbonatitic complexes are located at the edges of the Paleozoic basins and are usually associated to tectonic crustal flexuring or deep fault zones. The Jacupiranga Complex is a 65 km² ultrabasic-alkaline carbonatitic intrusive body outcroping at the northeastern border of the Paraná Basin, South of São Paulo State (Brazil). The northern portion of the unit is mostly composed of peridotitic rocks, while the southern part contains ijolites, melteigites, clinopyroxenites and carbonatites which host a phosphate deposit, mined since 1966. Even though the carbonatites only represent 1% of the Complex's area, they have concentrated most of the historical petrogenetic studies, leaving almost unknown the petrogenetic and the geochronological characteristics of other rocks. This explains why the few petrogenetic models from the literature are very partial and mostly unsatisfactory. While the peridotitic rocks are largely hindered by the absence of fresh outcrops, the regolith thickness and the high serpentinization degree, field observations and petrographic data notably show a heterogeneous zone around the peridotitic body. That zone is composed of a large variety of lithotypes over a relatively small area (~9 km²), comprising diorites, monzodiorites, alkali feldspar syenites, trachytes, lamprophyres and syenites. Moreover, these rocks present a restricted lateral continuity (decametric) and a lack of the magmatic bedding characteristic of the ijolitic and clinopyroxenitc rocks. The southern clinopyroxenitic zone (~20 km²) is composed of clinopyroxenite and melteigite with prominent magmatic layering, probably of cumulative origin, and a body of carbonatites which outcrops over less than 1 km2 essentially composed of sovite and beforsite, with abundant apatite. The Jacupiranga Complex characteristics indicate that its formation possibly comprises at least five magmatic events which cannot at present be surely ordinated in time: a) the emplacement of the peridotitic unit; b) the intrusion and probable differentiation of the clinopyroxenites and ijolitic rocks; c) intrusions of several lithotypes forming the heterogeneous zone; d) intrusion of lamprophyric dykes into the syenites; e) the carbonatite intrusion. The precise geochronological sequence is still unknown, since only the syenites (134.9 ± 0.65 Ma this study), the carbonatite (131 Ma) and the clinopyroxenite (131 Ma) were dated at present. Our goal is now to investigate the origin and evolution of the magmas which formed the Jacupiranga Complex using geochronology with Ar/Ar, U-Pb and U-Th/He dating, as well as elemental and isotopic geochemistry. Considering that the Jacupiranga Complex is one of the most differentiated alkaline complexes around the world, this contribution will be important not only for the understanding of the unit itself but also for the general comprehension of the forming process, the evolution of the alkaline and carbonatitic magmas and the concentration of apatite in carbonatites, still controversial subjects among the scientific community.

USE OF ELECTRICAL RESISTIVITY PROBE FOR DETERMINATION OF HYPORHEIC FLOW

EPA Science Inventory

The hyporheic zone can play a significant role in nutrient behavior in watersheds. Conceptual models describe the behavior of nutrients and biota for the hyporheic ecotone, but site characterization is needed to quantiiy effects at the restoration reach scale (hundreds of meters)...

Observing Complex Systems Thinking in the Zone of Proximal Development

ERIC Educational Resources Information Center

Danish, Joshua; Saleh, Asmalina; Andrade, Alejandro; Bryan, Branden

2017-01-01

Our paper builds on the construct of the zone of proximal development (ZPD) (Vygotsky in Mind in society: the development of higher psychological processes, Harvard University Press, Cambridge, 1978) to analyze the relationship between students' answers and the help they receive as they construct them. We report on a secondary analysis of…

The Sociomateriality of Education Policy

ERIC Educational Resources Information Center

Landri, Paolo

2015-01-01

By drawing on sociomaterial approaches to education, this paper presents a case study on the creation, development and consolidation of the education zone, a new policy space in South Italy. The topological reading of the case study reveals the complex reassemblage of humans and non-humans in the enactment of the education zones, and its multiple…

Coupled effects of solution chemistry and hydrodynamics on the mobility and transport of quantum dot nanomaterials in the Vadose Zone

USDA-ARS?s Scientific Manuscript database

To investigate the coupled effects of solution chemistry and vadose zone processes on the mobility of quantum dot (QD) nanoparticles, laboratory scale transport experiments were performed. The complex coupled effects of ionic strength, size of QD aggregates, surface tension, contact angle, infiltrat...

Foresters' perceptions of windthrow dynamics in northern Minnesota riparian management zones

Treesearch

Jeremy C. Steil; Charles R. Blinn; Randy Kolka

2009-01-01

A survey was mailed to foresters in northern Minnesota to identify their perceptions of what conditions result in higher incidence of windthrow in riparian management zones (RMZ) where the upland has been clearcut. Results indicate that foresters think many variables impact windthrow, often interacting in complex ways. Foresters considered topographic exposure, species...

Featured collection introduction: Riparian ecosystems and buffers II

Treesearch

Paul M. Mayer; Kathleen A. Dwire; Judith A. Okay; Philipe G. Vidon

2014-01-01

Riparian ecosystems, the interface of terrestrial and aquatic systems, are zones of high biodiversity (Naiman et al., 1993), rapid biogeochemical activity (Vidon et al., 2010), complex hydrologic activity (Mayer et al., 2010a), and offer solace that can bestow significant mental health benefits (Alcock et al., 2014). Yet, many riparian zones also represent...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hao, He; Lian, Jianming; Kalsi, Karanjit

The HVAC (Heating, Ventilation, and Air- Conditioning) system of commercial buildings is a complex system with a large number of dynamically interacting components. In particular, the thermal dynamics of each zone are coupled with those of the neighboring zones. In this paper, we study a multi-agent based approach to model and control commercial building HVAC system for providing grid services. In the multi-agent system (MAS), individual zones are modeled as agents that can communicate, interact, and negotiate with one another to achieve a common objective. We first propose a distributed characterization method on the aggregated airflow (and thus fan power)more » flexibility that the HVAC system can provide to the ancillary service market. Then, we propose a Nash-bargaining based airflow allocation strategy to track a dispatch signal (that is within the offered flexibility limit) while respecting the preference and flexibility of individual zones. Moreover, we devise a distributed algorithm to obtain the Nash bargaining solution via dual decomposition and average consensus. Numerical simulations illustrate that the proposed distributed protocols are much more scalable than the centralized approaches especially when the system becomes larger and more complex.« less

Infrared defect dynamics—Nitrogen-vacancy complexes in float zone grown silicon introduced by electron irradiation

NASA Astrophysics Data System (ADS)

Inoue, Naohisa; Kawamura, Yuichi

2018-05-01

The interaction of nitrogen and intrinsic point defects, vacancy (V) and self-interstitial (I), was examined by infrared absorption spectroscopy on the electron irradiated and post-annealed nitrogen doped float zone (FZ) silicon crystal. Various absorption lines were observed, at 551 cm-1 in as-grown samples, at 726 and 778 cm-1 in as-irradiated samples (Ir group), at 689 cm-1 after post-annealing at 400 °C and above (400 °C group), at 762 and 951 cm-1 after annealing at 600 °C (600 °C group), and at 714 cm-1 up to 800 °C (800 °C group). By irradiation, a part of N2 was changed into the Ir group. VN2 is the candidate for the origin of the Ir group. By the post annealing at 400 and 600 °C, a part of N2 and the Ir group were changed into the 400 °C group, to less extent at 600 °C. V2N2 is the candidate for the origin of the 400 °C group. By annealing at 600 °C, most of the Ir group turned into 400 °C and 600 °C groups. By annealing at 800 °C, N2 recovered almost completely, and most other complexes were not observed. Recently, lifetime degradation has been observed in the nitrogen doped FZ Si annealed at between 450 and 800 °C. The N-V interaction in the same temperature range revealed here will help to understand the lifetime degradation mechanism. The behavior of the 689 cm-1 line corresponded well to the lifetime degradation.

Artificial neural networks application for modeling of friction stir welding effects on mechanical properties of 7075-T6 aluminum alloy

NASA Astrophysics Data System (ADS)

Maleki, E.

2015-12-01

Friction stir welding (FSW) is a relatively new solid-state joining technique that is widely adopted in manufacturing and industry fields to join different metallic alloys that are hard to weld by conventional fusion welding. Friction stir welding is a very complex process comprising several highly coupled physical phenomena. The complex geometry of some kinds of joints makes it difficult to develop an overall governing equations system for theoretical behavior analyse of the friction stir welded joints. Weld quality is predominantly affected by welding effective parameters, and the experiments are often time consuming and costly. On the other hand, employing artificial intelligence (AI) systems such as artificial neural networks (ANNs) as an efficient approach to solve the science and engineering problems is considerable. In present study modeling of FSW effective parameters by ANNs is investigated. To train the networks, experimental test results on thirty AA-7075-T6 specimens are considered, and the networks are developed based on back propagation (BP) algorithm. ANNs testing are carried out using different experimental data that they are not used during networks training. In this paper, rotational speed of tool, welding speed, axial force, shoulder diameter, pin diameter and tool hardness are regarded as inputs of the ANNs. Yield strength, tensile strength, notch-tensile strength and hardness of welding zone are gathered as outputs of neural networks. According to the obtained results, predicted values for the hardness of welding zone, yield strength, tensile strength and notch-tensile strength have the least mean relative error (MRE), respectively. Comparison of the predicted and the experimental results confirms that the networks are adjusted carefully, and the ANN can be used for modeling of FSW effective parameters.

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zachara, John M.; Chen, Xingyuan; Murray, Chris

In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (U aq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time seriesmore » trends for U aq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in U aq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U aq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While U aq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

DOE PAGES

Zachara, John M.; Chen, Xingyuan; Murray, Chris; ...

2016-03-04

In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (U aq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time seriesmore » trends for U aq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in U aq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U aq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While U aq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

Mineralogical and geochemical characterization of weathering profiles developed on mylonites in the Fodjomekwet-Fotouni section of the Cameroon Shear Zone (CSZ), West Cameroon

NASA Astrophysics Data System (ADS)

Tematio, P.; Tchaptchet, W. T.; Nguetnkam, J. P.; Mbog, M. B.; Yongue Fouateu, R.

2017-07-01

The mineralogical and geochemical investigation of mylonitic weathering profiles in Fodjomekwet-Fotouni was done to better trace the occurrence of minerals and chemical elements in this area. Four representative soil profiles were identified in two geomorphological units (upland and lowland) differentiating three weathering products (organo-mineral, mineral and weathered materials). Weathering of these mylonites led to some minerals association such as vermiculite, kaolinite, goethite, smectite, halloysite, phlogopite and gibbsite. The minerals in a decreasing order of abundance are: quartz (24.2%-54.8%); kaolinite (8.4%-36.0%); phlogopite (5.5%-21.9%); goethite (7.8%-16.1%); vermiculite (6.7%-15.7%); smectite (10.2%-11.9%); gibbsite (9.0%-11.8%) and halloysite (5.6%-11.5%) respectively. Patterns of chemical elements allow highlighting three behaviors (enriched elements, depleted elements and elements with complex behavior), depending on the landscape position of the profiles. In the upland weathering products, K, Cr and REEs are enriched; Ca, Mg, Na, Mn, Rb, S and Sr are depleted while Si, Al, Fe, Ti, Ba, Co, Cu, Ga, Mo, Nb, Ni, Pb, Sc, V, Y, Zn and Zr portray a complex behavior. Contrarily, the lowland weathering profiles enriched elements are Fe, Ti, Co, Cr, Cu, V, Zr, Pr, Sm, Tb, Dy, Er and Yb; while depleted elements are Ca, Mg, K, Na, Mn, Ba, Ga, S, Sr, Y, Zn, La, Ce and Nd; and Si, Al, Mo, Nb, Ni, Pb, Rb, Sc evidenced complex behaviors. In all the studied weathering products, the REEs fractionation was also noticeable with a landscape-position dependency, showing light REEs (LREEs) enrichment in the upland areas and heavy REEs (HREEs) in lowland areas. SiO2, Al2O3 and Fe2O3 are positively correlated with most of the traces and REEs (Co, Cu, Nb, Ni, Mo, Pb, Sc, V, Zn, Zr, La, Ce, Sm, Tb, Dy, Er, Yb), pointing to the fact that they may be incorporated into newly formed clay minerals and oxides. Ba, Cr, Ga, Rb, S, Sr, Y, Pr and Nd behave like alkalis and alkaline earths, and are thus highly mobile during weathering.

Experimental study of the free surface velocity field in an asymmetrical confluence

NASA Astrophysics Data System (ADS)

Creelle, Stephan; Mignot, Emmanuel; Schindfessel, Laurent; De Mulder, Tom

2017-04-01

The hydrodynamic behavior of open channel confluences is highly complex because of the combination of different processes that interact with each other. To gain further insights in how the velocity uniformization between the upstream channels and the downstream channel is proceeding, experiments are performed in a large scale 90 degree angled concrete confluence flume with a chamfered rectangular cross-section and a width of 0.98m. The dimensions and lay-out of the flume are representative for a prototype scale confluence in e.g. drainage and irrigation systems. In this type of engineered channels with sharp corners the separation zone is very large and thus the velocity difference between the most contracted section and the separation zone is pronounced. With the help of surface particle tracking velocimetry the velocity field is recorded from upstream of the confluence to a significant distance downstream of the confluence. The resulting data allow to analyze the evolution of the incoming flows (with a developed velocity profile) that interact with the stagnation zone and each other, causing a shear layer between the two bulk flows. Close observation of the velocity field near the stagnation zone shows that there are actually two shear layers in the vicinity of the upstream corner. Furthermore, the data reveals that the shear layer observed more downstream between the two incoming flows is actually one of the two shear layers next to the stagnation zone that continues, while the other shear layer ceases to exist. The extensive measurement domain also allows to study the shear layer between the contracted section and the separation zone. The shear layers of the stagnation zone between the incoming flows and the one between the contracted flow and separation zone are localized and parameters such as the maximum gradient, velocity difference and width of the shear layer are calculated. Analysis of these data shows that the shear layer between the incoming flows disappears quite quickly, because of the severe flow contraction that aids the flow uniformization. This is also accelerated because of a flow redistribution process that starts already upstream of the confluence, resulting in a lower than expected velocity difference over the shear layer between the bulk of the incoming flows. In contrast, the shear layer between the contracted section and the separation zone proves to be of a significantly higher order of magnitude, with large turbulent structures appearing that get transported far downstream. In conclusion, the resulting understanding of this analysis of velocity fields with a larger field of view shows that when analyzing confluence hydrodynamics, one should pay ample attention to analyze data far enough up and downstream to assess all the relevant processes.

Five critical questions of scale for the coastal zone

NASA Astrophysics Data System (ADS)

Swaney, D. P.; Humborg, C.; Emeis, K.; Kannen, A.; Silvert, W.; Tett, P.; Pastres, R.; Solidoro, C.; Yamamuro, M.; Hénocque, Y.; Nicholls, R.

2012-01-01

Social and ecological systems around the world are becoming increasingly globalized. From the standpoint of understanding coastal ecosystem behavior, system boundaries are not sufficient to define causes of change. A flutter in the stock market in Tokyo or Hong Kong can affect salmon producers in Norway or farmers in Togo. The globalization of opportunistic species and the disempowerment of people trying to manage their own affairs on a local scale seem to coincide with the globalization of trade. Human-accelerated environmental change, including climate change, can exacerbate this sense of disenfranchisement. The structure and functioning of coastal ecosystems have been developed over thousands of years subject to environmental forces and constraints imposed mainly on local scales. However, phenomena that transcend these conventional scales have emerged with the explosion of human population, and especially with the rise of modern global culture. Here, we examine five broad questions of scale in the coastal zone: How big are coastal ecosystems and why should we care? Temporal scales of change in coastal waters and watersheds: Can we detect shifting baselines due to economic development and other drivers? Are footprints more important than boundaries? What makes a decision big? The tyranny of small decisions in coastal regions. Scales of complexity in coastal waters: the simple, the complicated or the complex? These questions do not have straightforward answers. There is no single "scale" for coastal ecosystems; their multiscale nature complicates our understanding and management of them. Coastal ecosystems depend on their watersheds as well as spatially-diffuse "footprints" associated with modern trade and material flows. Change occurs both rapidly and slowly on human time scales, and observing and responding to changes in coastal environments is a fundamental challenge. Apparently small human decisions collectively have potentially enormous consequences for coastal environmental quality, and our success in managing the effects of these decisions will determine the quality of life in the coastal zone in the 21st century and beyond. Vigilant monitoring, creative synthesis of information, and continued research will be necessary to properly understand and govern our coastal environments into the future.

Length Scales and Types of Heterogeneities Along the Deep Subduction Interface: Insights From an Exhumed Subduction Complex on Syros Island, Greece

NASA Astrophysics Data System (ADS)

Kotowski, A. J.; Behr, W. M.; Tong, X.; Lavier, L.

2017-12-01

The rheology of the deep subduction interface strongly influences the occurrence, recurrence, and migration of episodic tremor and slow slip (ETS) events. To better understand the environment of deep ETS, we characterize the length scales and types of rheological heterogeneities that decorate the deep interface using an exhumed subduction complex. The Cycladic Blueschist Unit on Syros, Greece, records Eocene subduction to 60 km, partial exhumation along the top of the slab, and final exhumation along Miocene detachment faults. The CBU reached 450-580˚C and 14-16 kbar, PT conditions similar to where ETS occurs in several modern subduction zones. Rheological heterogeneity is preserved in a range of rock types on Syros, with the most prominent type being brittle pods embedded within a viscous matrix. Prograde, blueschist-facies metabasalts show strong deformation fabrics characteristic of viscous flow; cm- to m-scale eclogitic lenses are embedded within them as massive, veined pods, foliated pods rotated with respect to the blueschist fabric, and attenuated, foliation-parallel lenses. Similar relationships are observed in blueschist-facies metasediments interpreted to have deformed during early exhumation. In these rocks, metabasalts form lenses ranging in size from m- to 10s of m and are distributed at the m-scale throughout the metasedimentary matrix. Several of the metamafic lenses, and the matrix rocks immediately adjacent to them, preserve multiple generations of dilational veins and shear fractures filled with quartz and high pressure minerals. These observations suggest that coupled brittle-viscous deformation under high fluid pressures may characterize the subduction interface in the deep tremor source region. To test this further, we modeled the behavior of an elasto-plastic pod in a viscous shear zone under high fluid pressures. Our models show that local stress concentrations around the pod are large enough to generate transient dilational shear at seismic strain rates. Scaling the model up to a typical source area for deep tremor suggests these heterogeneities may yield a seismic moment similar to those calculated for tremor bursts in modern subduction zones.

`Dhara': An Open Framework for Critical Zone Modeling

NASA Astrophysics Data System (ADS)

Le, P. V.; Kumar, P.

2016-12-01

Processes in the Critical Zone, which sustain terrestrial life, are tightly coupled across hydrological, physical, biological, chemical, pedological, geomorphological and ecological domains over both short and long timescales. Observations and quantification of the Earth's surface across these domains using emerging high resolution measurement technologies such as light detection and ranging (lidar) and hyperspectral remote sensing are enabling us to characterize fine scale landscape attributes over large spatial areas. This presents a unique opportunity to develop novel approaches to model the Critical Zone that can capture fine scale intricate dependencies across the different processes in 3D. The development of interdisciplinary tools that transcend individual disciplines and capture new levels of complexity and emergent properties is at the core of Critical Zone science. Here we introduce an open framework for high-performance computing model (`Dhara') for modeling complex processes in the Critical Zone. The framework is designed to be modular in structure with the aim to create uniform and efficient tools to facilitate and leverage process modeling. It also provides flexibility to maintain, collaborate, and co-develop additional components by the scientific community. We show the essential framework that simulates ecohydrologic dynamics, and surface - sub-surface coupling in 3D using hybrid parallel CPU-GPU. We demonstrate that the open framework in Dhara is feasible for detailed, multi-processes, and large-scale modeling of the Critical Zone, which opens up exciting possibilities. We will also present outcomes from a Modeling Summer Institute led by Intensively Managed Critical Zone Observatory (IMLCZO) with representation from several CZOs and international representatives.

Relating rheology to geometry in large-scale natural shear zones

NASA Astrophysics Data System (ADS)

Platt, John

2016-04-01

The geometry and width of the ductile roots of plate boundary scale faults are very poorly understood. Some field and geophysical data suggests widths of tens of km in the lower crust, possibly more in the upper mantle. Other observations suggest they are much narrower. Dip slip shear zones may flatten out and merge into zones of subhorizontal lower crustal or asthenospheric flow. The width of a ductile shear zone is simply related to relative velocity and strain rate. Strain rate is related to stress through the constitutive relationship. Can we constrain the stress, and do we understand the rheology of materials in ductile shear zones? A lot depends on how shear zones are initiated. If they are localized by pre-existing structures, width and/or rheology may be inherited, and we have too many variables. If shear zones are localized primarily by shear heating, initial shear stress has to be very high (> 1 GPa) to overcome conductive heat loss, and very large feedbacks (both positive and negative) make the system highly unstable. Microstructural weakening requires a minimum level of stress to cause deformation and damage in surrounding rock, thereby buffering the stress. Microstructural weakening leads to grain-size sensitive creep, for which we have constitutive laws, but these are complicated by phase mixing in polyphase materials, by viscous anisotropy, by hydration, and by changes in mineral assemblage. Here are some questions that need to be addressed. (1) If grain-size reduction by dynamic recrystallization results in a switch to grain-size sensitive creep (GSSC) in a stress-buffered shear zone, does dynamic recrystallization stop? Does grain growth set in? If grain-size is still controlled by dislocation processes, then the effective stress exponent for GSSC is 4-5, even though the dominant mechanism may be diffusion and/or grain-boundary sliding (GBS). (2) Is phase mixing in ultramylonites primarily a result of GBS + neighbour switching, creep cavitation and diffusion, or metamorphic reactions? (3) In two-phase / polyphase mixtures, does the strong phase generally form a load-bearing framework, favoring constant strain-rate (Voigt) bound behavior, or does the weak phase form through-going strain pathways, favoring constant stress (Reuss) bound behavior, or do the phases remain well mixed, favoring an intermediate behavior (e.g., Tullis et al model)? (4) How do we deal with the rheological effect of water? Is it simply an unconstrained variable in nature? Is the water fugacity model in flow laws adequate? (5) How can we better relate experimental results (often carried out at constant strain-rate, and not reaching microstructural steady state) to deformation in natural shear zones? Rheological observations on well-constrained natural shear zones are helping us answer some of these questions.

The Effects of Local Police Surges on Crime and Arrests in New York City.

PubMed

MacDonald, John; Fagan, Jeffrey; Geller, Amanda

2016-01-01

The New York Police Department (NYPD) under Operation Impact deployed extra police officers to high crime areas designated as impact zones. Officers were encouraged to conduct investigative stops in these areas. City officials credited the program as one of the leading causes of New York City's low crime rate. We tested the effects of Operation Impact on reported crimes and arrests from 2004 to 2012 using a difference-in-differences approach. We used Poisson regression models to compare differences in crime and arrest counts before and after census block groups were designated as impact zones compared to census block groups in the same NYPD precincts but outside impact zones. Impact zones were significantly associated with reductions in total reported crimes, assaults, burglaries, drug violations, misdemeanor crimes, felony property crimes, robberies, and felony violent crimes. Impact zones were significantly associated with increases in total reported arrests, arrests for burglary, arrests for weapons, arrests for misdemeanor crimes, and arrests for property felony crimes. Impact zones were also significantly associated with increases in investigative stops for suspected crimes, but only the increase in stops made based on probable cause indicators of criminal behaviors were associated with crime reductions. The largest increase in investigative stops in impact zones was based on indicators of suspicious behavior that had no measurable effect on crime. The findings suggest that saturating high crime blocks with police helped reduce crime in New York City, but that the bulk of the investigative stops did not play an important role in the crime reductions. The findings indicate that crime reduction can be achieved with more focused investigative stops.

The Effects of Local Police Surges on Crime and Arrests in New York City

PubMed Central

MacDonald, John; Fagan, Jeffrey; Geller, Amanda

2016-01-01

The New York Police Department (NYPD) under Operation Impact deployed extra police officers to high crime areas designated as impact zones. Officers were encouraged to conduct investigative stops in these areas. City officials credited the program as one of the leading causes of New York City’s low crime rate. We tested the effects of Operation Impact on reported crimes and arrests from 2004 to 2012 using a difference-in-differences approach. We used Poisson regression models to compare differences in crime and arrest counts before and after census block groups were designated as impact zones compared to census block groups in the same NYPD precincts but outside impact zones. Impact zones were significantly associated with reductions in total reported crimes, assaults, burglaries, drug violations, misdemeanor crimes, felony property crimes, robberies, and felony violent crimes. Impact zones were significantly associated with increases in total reported arrests, arrests for burglary, arrests for weapons, arrests for misdemeanor crimes, and arrests for property felony crimes. Impact zones were also significantly associated with increases in investigative stops for suspected crimes, but only the increase in stops made based on probable cause indicators of criminal behaviors were associated with crime reductions. The largest increase in investigative stops in impact zones was based on indicators of suspicious behavior that had no measurable effect on crime. The findings suggest that saturating high crime blocks with police helped reduce crime in New York City, but that the bulk of the investigative stops did not play an important role in the crime reductions. The findings indicate that crime reduction can be achieved with more focused investigative stops. PMID:27310252

Beyond the classic thermoneutral zone

PubMed Central

Kingma, Boris RM; Frijns, Arjan JH; Schellen, Lisje; van Marken Lichtenbelt, Wouter D

2014-01-01

The thermoneutral zone is defined as the range of ambient temperatures where the body can maintain its core temperature solely through regulating dry heat loss, i.e., skin blood flow. A living body can only maintain its core temperature when heat production and heat loss are balanced. That means that heat transport from body core to skin must equal heat transport from skin to the environment. This study focuses on what combinations of core and skin temperature satisfy the biophysical requirements of being in the thermoneutral zone for humans. Moreover, consequences are considered of changes in insulation and adding restrictions such as thermal comfort (i.e. driver for thermal behavior). A biophysical model was developed that calculates heat transport within a body, taking into account metabolic heat production, tissue insulation, and heat distribution by blood flow and equates that to heat loss to the environment, considering skin temperature, ambient temperature and other physical parameters. The biophysical analysis shows that the steady-state ambient temperature range associated with the thermoneutral zone does not guarantee that the body is in thermal balance at basal metabolic rate per se. Instead, depending on the combination of core temperature, mean skin temperature and ambient temperature, the body may require significant increases in heat production or heat loss to maintain stable core temperature. Therefore, the definition of the thermoneutral zone might need to be reformulated. Furthermore, after adding restrictions on skin temperature for thermal comfort, the ambient temperature range associated with thermal comfort is smaller than the thermoneutral zone. This, assuming animals seek thermal comfort, suggests that thermal behavior may be initiated already before the boundaries of the thermoneutral zone are reached. PMID:27583296

Beyond the classic thermoneutral zone: Including thermal comfort.

PubMed

Kingma, Boris Rm; Frijns, Arjan Jh; Schellen, Lisje; van Marken Lichtenbelt, Wouter D

2014-01-01

The thermoneutral zone is defined as the range of ambient temperatures where the body can maintain its core temperature solely through regulating dry heat loss, i.e., skin blood flow. A living body can only maintain its core temperature when heat production and heat loss are balanced. That means that heat transport from body core to skin must equal heat transport from skin to the environment. This study focuses on what combinations of core and skin temperature satisfy the biophysical requirements of being in the thermoneutral zone for humans. Moreover, consequences are considered of changes in insulation and adding restrictions such as thermal comfort (i.e. driver for thermal behavior). A biophysical model was developed that calculates heat transport within a body, taking into account metabolic heat production, tissue insulation, and heat distribution by blood flow and equates that to heat loss to the environment, considering skin temperature, ambient temperature and other physical parameters. The biophysical analysis shows that the steady-state ambient temperature range associated with the thermoneutral zone does not guarantee that the body is in thermal balance at basal metabolic rate per se. Instead, depending on the combination of core temperature, mean skin temperature and ambient temperature, the body may require significant increases in heat production or heat loss to maintain stable core temperature. Therefore, the definition of the thermoneutral zone might need to be reformulated. Furthermore, after adding restrictions on skin temperature for thermal comfort, the ambient temperature range associated with thermal comfort is smaller than the thermoneutral zone. This, assuming animals seek thermal comfort, suggests that thermal behavior may be initiated already before the boundaries of the thermoneutral zone are reached.

Complex plume dynamics in the transition zone underneath the Hawaii hotspot: seismic imaging results

NASA Astrophysics Data System (ADS)

Cao, Q.; van der Hilst, R. D.; de Hoop, M. V.; Shim, S.

2010-12-01

In recent years, progress has been made in seismology to constrain the depth variations of the transition zone discontinuities, e.g. 410 km and 660 km discontinuities, which can be used to constrain the local temperature and chemistry profiles, and hence to infer the existences and morphology of mantle plumes. Taking advantage of the abundance of natural earthquake sources in western Pacific subduction zones and the many seismograph stations in the Americas, we used a generalized Radon transform (GRT), a high resolution inverse-scattering technique, of SS precursors to form 3-D images of the transition zone structures of a 30 degree by 40 degree area underneath Hawaii and the Hawaii-Emperor seamount chain. Rather than a simple mushroom-shape plume, our seismic images suggest complex plume dynamics interacting with the transition zone phase transitions, especially at the 660’ discontinuity. A conspicuous uplift of the 660 discontinuity in a region of 800km in diameter is observed to the west of Hawaii. No correspondent localized depression of the 410 discontinuity is found. This lack of correlation between and differences in lateral length scale of the topographies of the 410 and 660 km discontinuities are consistent with many geodynamical modeling results, in which a deep-mantle plume impinging on the transition zone, creating a pond of hot material underneath endothermic phase change at 660 km depth, and with secondary plumes connecting to the present-day hotspot at Earth’s surface. This more complex plume dynamics suggests that the complicated mass transport process across the transition zone should be taken into account when we try to link the geochemical observations of Hawaiian basalt geochemistry at the Earth’s surface to deep mantle domains. In addition to clear signals at 410km, 520km and 660km depth, the data also reveals rich structures near 350km depth and between 800 - 1000km depth, which may be regional, laterally intermittent scatter interfaces. This may suggest the influence of water or minor chemical constitutes and calls for interpretations from geodynamics and mineral physics.

Internal structure of Puna Ridge: evolution of the submarine East Rift Zone of Kilauea Volcano, Hawai ̀i

NASA Astrophysics Data System (ADS)

Leslie, Stephen C.; Moore, Gregory F.; Morgan, Julia K.

2004-01-01

Multichannel seismic reflection, sonobuoy, gravity and magnetics data collected over the submarine length of the 75 km long Puna Ridge, Hawai ̀i, resolve the internal structure of the active rift zone. Laterally continuous reflections are imaged deep beneath the axis of the East Rift Zone (ERZ) of Kilauea Volcano. We interpret these reflections as a layer of abyssal sediments lying beneath the volcanic edifice of Kilauea. Early arrival times or 'pull-up' of sediment reflections on time sections imply a region of high P-wave velocity ( Vp) along the submarine ERZ. Refraction measurements along the axis of the ridge yield Vp values of 2.7-4.85 km/s within the upper 1 km of the volcanic pile and 6.5-7 km/s deeper within the edifice. Few coherent reflections are observed on seismic reflection sections within the high-velocity area, suggesting steeply dipping dikes and/or chaotic and fractured volcanic materials. Southeastward dipping reflections beneath the NW flank of Puna Ridge are interpreted as the buried flank of the older Hilo Ridge, indicating that these two ridges overlap at depth. Gravity measurements define a high-density anomaly coincident with the high-velocity region and support the existence of a complex of intrusive dikes associated with the ERZ. Gravity modeling shows that the intrusive core of the ERZ is offset to the southeast of the topographic axis of the rift zone, and that the surface of the core dips more steeply to the northwest than to the southeast, suggesting that the dike complex has been progressively displaced to the southeast by subsequent intrusions. The gravity signature of the dike complex decreases in width down-rift, and is absent in the distal portion of the rift zone. Based on these observations, and analysis of Puna Ridge bathymetry, we define three morphological and structural regimes of the submarine ERZ, that correlate to down-rift changes in rift zone dynamics and partitioning of intrusive materials. We propose that these correspond to evolutionary stages of developing rift zones, which may partially control volcano growth, mobility, and stability, and may be observable at many other oceanic volcanoes.

Decision Aids for Naval Air ASW

DTIC Science & Technology

1980-03-15

Algorithm for Zone Optimization Investigation) NADC Developing Sonobuoy Pattern for Air ASW Search DAISY (Decision Aiding Information System) Wharton...sion making behavior. 0 Artificial intelligence sequential pattern recognition algorithm for reconstructing the decision maker’s utility functions. 0...display presenting the uncertainty area of the target. 3.1.5 Algorithm for Zone Optimization Investigation (AZOI) -- Naval Air Development Center 0 A

Histological studies on the triangular fibrocartilage complex of the wrist.

PubMed Central

Benjamin, M; Evans, E J; Pemberton, D J

1990-01-01

The triangular fibrocartilage complex of the wrist was serially sectioned for routine histology. Results from eight dissecting room cadavers show that the complex is attached to hyaline cartilage on the radius via its articular disc. In contrast, the dorsal and volar radio-ulnar ligaments attach to the radius via zones of calcified and uncalcified fibrocartilage. The articular disc is thus a wide labrum that provides an articular surface for the ulna and for the carpal bones, and the radio-ulnar ligaments strengthen the attachment of the disc to the radius. Medially, the complex divides into upper and lower laminae. Arching strands of collagen fibres emerge from the upper lamina and pass through a region of highly vascular connective tissue to be attached to the ulna between the articular cartilage on the head and that at the tip of the styloid process. Much of the ulnar attachment is via zones of calcified and uncalcified fibrocartilage which blend with the adjacent articular cartilages. Such an arrangement of tissues prevents undue wear and tear at the ulnar attachment zone during pronation and supination of the forearm. The lower lamina blends with the sheath of extensor carpi ulnaris and the ulnar collateral ligament and allows the whole complex to attach to the carpal and metacarpal bones. The meniscus homologue is a region of dense irregular connective tissue with no independent histological identity. Images Fig. 2 Fig. 3 Fig. 4 Fig. 5 Fig. 6 Fig. 7 Fig. 8 Fig. 9 Fig. 10 Fig. 11 Fig. 12 PMID:2272909

Operating results of a thermocline thermal energy storage included in a parabolic trough mini power plant

NASA Astrophysics Data System (ADS)

Fasquelle, Thomas; Falcoz, Quentin; Neveu, Pierre; Lecat, Florent; Boullet, Nicolas; Flamant, Gilles

2017-06-01

A thermocline thermal energy storage tank consists in using one single tank to store sensible heat. At almost any time, three zones coexist in the tank: a hot fluid zone at the top, a cold fluid zone at the bottom, and an intermediate zone called thermocline. Filling the tank with solid materials enables to reduce cost and to maintain the thermal stratification during stand-by periods. The present paper deals with a 230 kWh experimental thermocline tank that is included into a 150 kWth parabolic trough mini power plant. The heat transfer fluid is a non-pressurized synthetic oil (dibenzyltoluene) that flows through alumina spheres in the storage tank. The solid materials are contained into baskets in order to facilitate their removing and replacement. Thermocouples measure temperature along the center of the cylinder and along its radius. It is therefore possible to study the thermocline behavior thanks to the measured temperature profiles. A typical charge, a typical discharge and a stand-by process are presented and storage performances are discussed. The behavior of the tank in a dynamic system is also considered, by analyzing a typical day of solar production and storage of the energy surplus.

Thermal behavior in the cracking reaction zone of scramjet cooling channels at different channel aspect ratios

NASA Astrophysics Data System (ADS)

Zhang, Silong; Feng, Yu; Jiang, Yuguang; Qin, Jiang; Bao, Wen; Han, Jiecai; Haidn, Oskar J.

2016-10-01

To study the thermal behavior in the cracking reaction zone of regeneratively cooled scramjet cooling channels at different aspect ratios, 3-D model of fuel flow in terms of the fuel's real properties and cracking reaction is built and validated through experiments. The whole cooling channel is divided into non-cracking and cracking reaction zones. Only the cracking reaction zone is studied in this article. The simulation results indicate that the fuel conversion presents a similar distribution with temperature because the fuel conversion in scramjet cooling channels is co-decided by the temperature and velocity but the temperature plays the dominate role. For the cases given in this paper, increasing the channel aspect ratio will increase the pressure drop and it is not beneficial for reducing the wall temperature because of the much severer thermal stratification, larger conversion non-uniformity, the corresponding M-shape velocity profile which will cause local heat transfer deterioration and the decreased chemical heat absorption. And the decreased chemical heat absorption caused by stronger temperature and conversion non-uniformities is bad for the utilization of chemical heat sink, chemical recuperation process and the ignition performance.

Groundwater response to leakage of surface water through a thick vadose zone in the middle reaches area of Heihe River Basin, in China

NASA Astrophysics Data System (ADS)

Wang, X.-S.; Ma, M.-G.; Li, X.; Zhao, J.; Dong, P.; Zhou, J.

2009-12-01

The behavior of groundwater response to leakage of surface water in the middle reaches area of Heihe River Basin is significantly influenced by a thick vadose zone. The variation of groundwater level is a result of two recharge events corresponding to leakage of Heihe River and irrigation water with different delay time. A nonlinear leakage model is developed to calculate the monthly leakage of Heihe River in considering changes of streamflow, river stage and agricultural water utilization. Numerical modeling of variable saturated flow is carried out to investigate the general behaviors of leakage-recharge conversion through a thick vadose zone. It is found that the variable recharge can be approximated by simple reservoir models for both leakage under a river and leakage under an irrigation district but with different delay-time and recession coefficient. A triple-reservoir model of relationship between surface water, vadose zone and groundwater is developed. It reproduces the in situ water table movement during 1989-2006 with variable streamflow of Heihe River and agricultural water utilization. The model is applied to interpret groundwater dynamics during 2007-2008 that observed in the Watershed Airborne Telemetry Experimental Research (WATER).

Groundwater response to leakage of surface water through a thick vadose zone in the middle reaches area of Heihe River Basin, in China

NASA Astrophysics Data System (ADS)

Wang, X.-S.; Ma, M.-G.; Li, X.; Zhao, J.; Dong, P.; Zhou, J.

2010-04-01

The behavior of groundwater response to leakage of surface water in the middle reaches area of Heihe River Basin is significantly influenced by a thick vadose zone. The groundwater regime is a result of two recharge events due to leakage of Heihe River and irrigation water with different delay time. A nonlinear leakage model is developed to calculate the monthly leakage of Heihe River in considering changes of streamflow, river stage and agricultural water utilization. Numerical modeling of variable saturated flow is carried out to investigate the general behaviors of leakage-recharge conversion through a thick vadose zone. It is found that the recharge pattern can be approximated by simple reservoir models of leakages under a river and under an irrigation district with different delay-time and recession coefficient. A triple-reservoir model of relationship between surface water, vadose zone and groundwater is developed. It reproduces the groundwater regime during 1989-2006 with variable streamflow of Heihe River and agricultural water utilization. The model is applied to interpret changes of groundwater level during 2007-2008 that observed in the Watershed Airborne Telemetry Experimental Research (WATER).

Modelling Fault Zone Evolution: Implications for fluid flow.

NASA Astrophysics Data System (ADS)

Moir, H.; Lunn, R. J.; Shipton, Z. K.

2009-04-01

Flow simulation models are of major interest to many industries including hydrocarbon, nuclear waste, sequestering of carbon dioxide and mining. One of the major uncertainties in these models is in predicting the permeability of faults, principally in the detailed structure of the fault zone. Studying the detailed structure of a fault zone is difficult because of the inaccessible nature of sub-surface faults and also because of their highly complex nature; fault zones show a high degree of spatial and temporal heterogeneity i.e. the properties of the fault change as you move along the fault, they also change with time. It is well understood that faults influence fluid flow characteristics. They may act as a conduit or a barrier or even as both by blocking flow across the fault while promoting flow along it. Controls on fault hydraulic properties include cementation, stress field orientation, fault zone components and fault zone geometry. Within brittle rocks, such as granite, fracture networks are limited but provide the dominant pathway for flow within this rock type. Research at the EU's Soultz-sous-Forệt Hot Dry Rock test site [Evans et al., 2005] showed that 95% of flow into the borehole was associated with a single fault zone at 3490m depth, and that 10 open fractures account for the majority of flow within the zone. These data underline the critical role of faults in deep flow systems and the importance of achieving a predictive understanding of fault hydraulic properties. To improve estimates of fault zone permeability, it is important to understand the underlying hydro-mechanical processes of fault zone formation. In this research, we explore the spatial and temporal evolution of fault zones in brittle rock through development and application of a 2D hydro-mechanical finite element model, MOPEDZ. The authors have previously presented numerical simulations of the development of fault linkage structures from two or three pre-existing joints, the results of which compare well to features observed in mapped exposures. For these simple simulations from a small number of pre-existing joints the fault zone evolves in a predictable way: fault linkage is governed by three key factors: Stress ratio of s1 (maximum compressive stress) to s3(minimum compressive stress), original geometry of the pre-existing structures (contractional vs. dilational geometries) and the orientation of the principle stress direction (σ1) to the pre-existing structures. In this paper we present numerical simulations of the temporal and spatial evolution of fault linkage structures from many pre-existing joints. The initial location, size and orientations of these joints are based on field observations of cooling joints in granite from the Sierra Nevada. We show that the constantly evolving geometry and local stress field perturbations contribute significantly to fault zone evolution. The location and orientations of linkage structures previously predicted by the simple simulations are consistent with the predicted geometries in the more complex fault zones, however, the exact location at which individual structures form is not easily predicted. Markedly different fault zone geometries are predicted when the pre-existing joints are rotated with respect to the maximum compressive stress. In particular, fault surfaces range from evolving smooth linear structures to producing complex ‘stepped' fault zone geometries. These geometries have a significant effect on simulations of along and across-fault flow.

Computerized Workstation for Tsunami Hazard Monitoring

NASA Astrophysics Data System (ADS)

Lavrentiev-Jr, Mikhail; Marchuk, Andrey; Romanenko, Alexey; Simonov, Konstantin; Titov, Vasiliy

2010-05-01

We present general structure and functionality of the proposed Computerized Workstation for Tsunami Hazard Monitoring (CWTHM). The tool allows interactive monitoring of hazard, tsunami risk assessment, and mitigation - at all stages, from the period of strong tsunamigenic earthquake preparation to inundation of the defended coastal areas. CWTHM is a software-hardware complex with a set of software applications, optimized to achieve best performance on hardware platforms in use. The complex is calibrated for selected tsunami source zone(s) and coastal zone(s) to be defended. The number of zones (both source and coastal) is determined, or restricted, by available hardware resources. The presented complex performs monitoring of selected tsunami source zone via the Internet. The authors developed original algorithms, which enable detection of the preparation zone of the strong underwater earthquake automatically. For the so-determined zone the event time, magnitude and spatial location of tsunami source are evaluated by means of energy of the seismic precursors (foreshocks) analysis. All the above parameters are updated after each foreshock. Once preparing event is detected, several scenarios are forecasted for wave amplitude parameters as well as the inundation zone. Estimations include the lowest and the highest wave amplitudes and the least and the most inundation zone. In addition to that, the most probable case is calculated. In case of multiple defended coastal zones, forecasts and estimates can be done in parallel. Each time the simulated model wave reaches deep ocean buoys or tidal gauge, expected values of wave parameters and inundation zones are updated with historical events information and pre-calculated scenarios. The Method of Splitting Tsunami (MOST) software package is used for mathematical simulation. The authors suggest code acceleration for deep water wave propagation. As a result, performance is 15 times faster compared to MOST, original version. Performance gain is achieved by compiler options, use of optimized libraries, and advantages of OpenMP parallel technology. Moreover, it is possible to achieve 100 times code acceleration by using modern Graphics Processing Units (GPU). Parallel evaluation of inundation zones for multiple coastal zones is also available. All computer codes can be easily assembled under MS Windows and Unix OS family. Although software is virtually platform independent, the most performance gain is achieved while using the recommended hardware components. When the seismic event occurs, all valuable parameters are updated with seismic data and wave propagation monitoring is enabled. As soon as the wave passes each deep ocean tsunameter, parameters of the initial displacement at source are updated from direct calculations based on original algorithms. For better source reconstruction, a combination of two methods is used: optimal unit source linear combination from preliminary calculated database and direct numerical inversion along the wave ray between real source and particular measurement buoys. Specific dissipation parameter along with the wave ray is also taken into account. During the entire wave propagation process the expected wave parameters and inundation zone(s) characteristics are updated with all available information. If recommended hardware components are used, monitoring results are available in real time. The suggested version of CWTHM has been tested by analyzing seismic precursors (foreshocks) and the measured tsunami waves at North Pacific for the Central Kuril's tsunamigenic earthquake of November 15, 2006.

Assessing vulnerability mapping and protection zones of karst spring waters and validating by the joint use of natural and artificial tracers. The case of Auta Spring (Southern Spain)

NASA Astrophysics Data System (ADS)

Marín, Ana Isabel; Mudarra, Matías; Andreo, Bartolomé

2016-04-01

Delineation of protection zones for water supply and implementation of proper land-use practices in surrounding areas are crucial aspects for a sustainable use of valuable drinking water resources. This is even more important in karst aquifers, which are particularly sensitive to contamination, having a very low self-cleaning capacity due to their structure and hydrological behavior. Consequently, specific methodologies adapted to the particular characteristics of karst media are necessary. In this work, an approach for protection zoning of the pilot site of Auta karst spring (southern Spain) is proposed, based on the application of COP+K method for contamination vulnerability and validation of results by natural (organic) tracers of infiltration (NO3-, TOC, intrinsic fluorescence) and by a dye tracer test conducted on June, 2011 (injecting 500 mg uranine). The aquifer drained by Auta spring (8.5 km2) presents a complex geological structure, formed by Jurassic dolostones and limestones highly folded and fractured. Recharge takes place by the infiltration of rainfall through karst landforms and also by losses in an adjacent river when it flows over the carbonate outcrops (dye injection point). Drainage is mainly through several springs located at the southwest, including Auta spring and 5 overflow springs. The source vulnerability map obtained by applying COP+K method can be adopted as the baseline to delineate the protection zones, through the conversion from vulnerability classes to degrees of protection. Dye tracer test and natural tracers of infiltration corroborate that aquifer sectors influenced by the river can be extremely vulnerable to pollution, but also well-developed exokarst features. In fact, slight evidences of pollution have been detected during the study period, with relatively-high NO3- contents and high fluorescence linked to bacteriological activity in Auta spring water. The jointly use of natural and artificial tracers constitute a reliable and effective procedure for validating vulnerability mapping of karst systems and springs used for water supply. This procedure is meant to implement and to complement protection zone mapping, particularly in countries lacking guidelines for protecting the water resources of karst aquifers.

The Role of Long-Term Tectonic Deformation on the Distribution of Present-Day Seismic Activity in the Caribbean and Central America

NASA Astrophysics Data System (ADS)

Schobelock, J.; Stamps, D. S.; Pagani, M.; Garcia, J.; Styron, R. H.

2017-12-01

The Caribbean and Central America region (CCAR) undergoes the entire spectrum of earthquake types due to its complex tectonic setting comprised of transform zones, young oceanic spreading ridges, and subductions along its eastern and western boundaries. CCAR is, therefore, an ideal setting in which to study the impacts of long-term tectonic deformation on the distribution of present-day seismic activity. In this work, we develop a continuous tectonic strain rate model based on inter-seismic geodetic data and compare it with known active faults and earthquake focal mechanism data. We first create a 0.25o x 0.25o finite element mesh that is comprised of block geometries defined in previously studies. Second, we isolate and remove transient signals from the latest open access community velocity solution from UNAVCO, which includes 339 velocities from COCONet and TLALOCNet GNSS data for the Caribbean and Central America, respectively. In a third step we define zones of deformation and rigidity by creating a buffer around the boundary of each block that varies depending on the size of the block and the expected deformation zone based on locations of GNSS data that are consistent with rigid block motion. We then assign each node within the buffer a 0 for the deforming areas and a plate index outside the buffer for the rigid. Finally, we calculate a tectonic strain rate model for CCAR using the Haines and Holt finite element approach to fit bi-cubic Bessel splines to the the GNSS/GPS data assuming block rotation for zones of rigidity. Our model of the CCAR is consistent with compression along subduction zones, extension across the mid-Pacific Rise, and a combination of compression and extension across the North America - Caribbean plate boundary. The majority of CCAR strain rate magnitudes range from -60 to 60 nanostrains/yr. Modeling results are then used to calculate expected faulting behaviors that we compare with mapped geologic faults and seismic activity.

Crustal architecture and tectonic evolution of the Cauvery Suture Zone, southern India

NASA Astrophysics Data System (ADS)

Chetty, T. R. K.; Yellappa, T.; Santosh, M.

2016-11-01

The Cauvery suture zone (CSZ) in southern India has witnessed multiple deformations associated with multiple subduction-collision history, with incorporation of the related accretionary belts sequentially into the southern continental margin of the Archaean Dharwar craton since Neoarchean to Neoproterozoic. The accreted tectonic elements include suprasubduction complexes of arc magmatic sequences, high-grade supracrustals, thrust duplexes, ophiolites, and younger intrusions that are dispersed along the suture. The intra-oceanic Neoarchean-Neoproterozoic arc assemblages are well exposed in the form of tectonic mélanges dominantly towards the eastern sector of the CSZ and are typically subjected to complex and multiple deformation events. Multi-scale analysis of structural elements with detailed geological mapping of the sub-regions and their structural cross sections, geochemical and geochronological data and integrated geophysical observations suggest that the CSZ is an important zone that preserves the imprints of multiple cycles of Precambrian plate tectonic regimes.

Precision increase in electric drive speed loop of robotic complexes and process lines

NASA Astrophysics Data System (ADS)

Tulegenov, E.; Imanova, A. A.; Platonov, V. V.

2018-05-01

The article presents the principles of synthesis of control structures for highprecision electric drives of robotic complexes and manipulators. It has been theoretically shown and experimentally confirmed that improved characteristics of speed maintenance in the zone of significant overloads are achieved in systems of series excitation. They are achieved due to the redistribution of control signals both in the zone of setting the armature current and in the excitation currents. At the same time, the characteristic of the electromagnetic torque becomes linear because the demagnetizing effect of the armature response is compensated by the setting of the excitation current. It is recommended in those cases when it is necessary to extend the range of speed control with a significant reduction in load to apply structures with two-zone speed control. The regulation of the weakening of the excitation flow is more convenient as a function of the voltage in the armature windings.

Complex permeability structure of a fault zone crosscutting a sequence of sandstones and shales and its influence on hydraulic head distribution

NASA Astrophysics Data System (ADS)

Cilona, A.; Aydin, A.; Hazelton, G.

2013-12-01

Characterization of the structural architecture of a 5 km-long, N40°E-striking fault zone provides new insights for the interpretation of hydraulic heads measured across and along the fault. Of interest is the contaminant transport across a portion of the Upper Cretaceous Chatsworth Formation, a 1400 m-thick turbidite sequence of sandstones and shales exposed in the Simi Hills, south California. Local bedding consistently dips about 20° to 30° to NW. Participating hydrogeologists monitor the local groundwater system by means of numerous boreholes used to define the 3D distribution of the groundwater table around the fault. Sixty hydraulic head measurements consistently show differences of 10s of meters, except for a small area. In this presentation, we propose a link between this distribution and the fault zone architecture. Despite an apparent linear morphological trend, the fault is made up of at least three distinct segments named here as northern, central and southern segments. Key aspects of the fault zone architecture have been delineated at two sites. The first is an outcrop of the central segment and the second is a borehole intersecting the northern segment at depth. The first site shows the fault zone juxtaposing sandstones against shales. Here the fault zone consists of a 13 meter-wide fault rock including a highly deformed sliver of sandstone on the northwestern side. In the sandstone, shear offset was resolved along N42°E striking and SE dipping fracture surfaces localized within a 40 cm thick strand. Here the central core of the fault zone is 8 m-wide and contains mostly shale characterized by highly diffuse deformation. It shows a complex texture overprinted by N30°E-striking carbonate veins. At the southeastern edge of the fault zone exposure, a shale unit dipping 50° NW towards the fault zone provides the key information that the shale unit was incorporated into the fault zone in a manner consistent with shale smearing. At the second site, a borehole more than 194 meter-long intersects the fault zone at its bottom. Based on an optical televiewer image supplemented by limited recovered rock cores, a juxtaposition plane (dipping 75° SE) between a fractured sandstone and a highly-deformed shale fault rock has been interpreted as the southeastern boundary of the fault zone. The shale fault rock estimated to be thicker than 4 meters is highly folded and brecciated with locally complex cataclastic texture. The observations and interpretations of the fault architecture presented above suggest that the drop of hydraulic head detected across the fault segments is due primarily to the low-permeability shaly fault rock incorporated into the fault zone by a shale smearing mechanism. Interestingly, at around the step between the northern and the central fault segments, where the fault offset is expected to diminish (no hard link and no significant shaly fault rock), the groundwater levels measured on either sides of the fault zone are more-or-less equal.

Inferences of Complex Anisotropic Layering and Mantle Flow Beneath the Malawi Rift Zone from Shear-Wave Splitting

NASA Astrophysics Data System (ADS)

Gao, S. S.; Reed, C. A.; Yu, Y.; Liu, K. H.; Chindandali, P. R. N.; Mdala, H. S.; Massinque, B.; Mutamina, D. M.

2016-12-01

Measuring the magnitude and orientation of seismic anisotropy beneath actively extending rift zones provides invaluable estimates of the influence of numerous geodynamic parameters upon their evolution. In order to infer the character and origin of extensional forces acting upon the Malawi Rift Zone (MRZ) and Luangwa Rift Zone (LRZ) of southern Africa, we installed 33 Seismic Arrays For African Rift Initiation (SAFARI) three-component broadband seismic stations in Malawi, Mozambique, and Zambia between 2012-2014. Shear-wave splitting parameters, including the fast-component polarization orientation and the splitting time, are extracted from 142 events recorded during that time period for a total of 642 well-defined PKS, SKKS, and SKS phase measurements. Polarizations trend NE-SW along the western flank of the LRZ, whereupon they demonstrate an abrupt shift to N-S within the rift valley and the eastern flank. SWS orientations shift increasingly counterclockwise toward the east until, at 33°E, they shift from WNW-ESE to ENE-WSW, suggesting a systematic change in dominant mantle fabric orientation. The resulting fast orientations demonstrate remarkable variability within the MRZ, with E-W measurements in the north rotating counterclockwise toward the south to N-S within the southernmost MRZ. Measurements revert to E-W and NE-SW orientations toward the east in Mozambique, suggesting the presence of complex two-layer anisotropy. Azimuthal variations of SWS parameters recorded by stations within the central MRZ exhibit excellent 90° periodicity, further suggesting complex anisotropic layering. Lateral variation of measurements between the northern and southern MRZ imply the modulation of the mantle flow system beneath the active rift zone.

Cryptic trace-element alteration of Anorthosite, Stillwater complex, Montana

USGS Publications Warehouse

Czamanske, G.K.; Loferski, P.J.

1996-01-01

Evidence of cryptic alteration and correlations among K, Ba, and LREE concentrations indicate that a post-cumulus, low-density aqueous fluid phase significantly modified the trace-element contents of samples from Anorthosite zones I and II of the Stillwater Complex, Montana. Concentrations of Ba, Ca, Co, Cr, Cu, Fe, Hf, K, Li, Mg, Mn, Na, Ni, Sc, Sr, Th, Zn, and the rare-earth elements (REE) were measured in whole rocks and plagioclase separates from five traverses across the two main plagioclase cumulate (anorthosite) zones and the contiguous cumulates of the Stillwater Complex in an attempt to better understand the origin and solidification of the anorthosites. However, nearly the entire observed compositional range for many trace elements can be duplicated at a single locality by discriminating between samples rich in oikocrystic pyroxene and those which are composed almost entirely of plagioclase and show anhedral-granular texture. Plagioclase separates with high trace-element contents were obtained from the pyroxene-poor samples, for which maps of K concentration show plagioclase grains to contain numerous fractures hosting a fine-grained, K-rich phase, presumed to be sericite. Secondary processes in layered intrusions have the potential to cause cryptic disturbance, and the utmost care must be taken to ensure that samples provide information about primary processes. Although plagioclase from Anorthosite zones I and II shows significant compositional variation, there are no systematic changes in the major- or trace-element compositions of plagioclase over as much as 630 m of anorthosite thickness or 18 km of strike length. Plagioclase in the two major anorthosite zones shows little distinction in trace-element concentrations from plagioclase in the cumulates immediately below, between, and above these zones.

Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

USGS Publications Warehouse

Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

1994-01-01

The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems. ?? 1994.

An anomalous Pt-Pd occurrence below the JM reef, Stillwater Complex, Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

McIlveen, C.L.

1993-04-01

The late Archean Stillwater Complex, in south-central Montana, consists of the Basal, Ultramafic, and Banded series. The Lower Banded series contains several anomalous platinum-group element (PGE) occurrences, with the JM reef having the highest values (an average of 6,250 ppb Pt and 24,000 ppb Pd) and greatest lateral persistence. The Coors anomaly, below the reef, is near the middle of the complex. This zone contains bronzite cumulates which range from 100--14,600 ppb Pt, with an average of 1,250 ppb. Pt:Pd ratios in the Coors zone average 1:1.7, compared to 1:3.8 in the reef. Sulfides associated with the PGE's show immisciblemore » textures indicating a magmatic origin similar to the reef. The anomaly lies approximately 200 m below the reef along the Banded-Ultramafic series contact where the Gabbronorite 1 zone is virtually absent. Layering between the reef and the Ultramafic series bronzitite is irregular and thin compared to the normal 400-m thickness exposed elsewhere in the complex. Bronzitites which contain the PGE's are podiform and often pegmatoidal. Norites adjacent to the bronzities also tend to be pegmatoidal and sulfide-bearing, but contain an average of only 75 ppb Pt. Microprobe analyses of bronzites in this zone show abruptly lower Mg/(Mg + Fe) of 0.77 compared to 0.83 in the uppermost bronzitite. The disrupted layering and thinning in the Coors area may have formed by slumping, scouring, or thermal erosion in the cumulate pile during crystallization. Coors mineralization may have developed through processes similar to those in the JM reef. However, occurrence of the coors mineralization with irregular layering and higher PGE ratios suggest an origin different than that in the reef.« less

Alternative Endpoints and Approaches Selected for the Remediation of Contaminated Groundwater at Complex Sites

NASA Astrophysics Data System (ADS)

Deeb, R. A.; Hawley, E.

2011-12-01

This presentation will focus on findings, statistics, and case studies from a recently-completed report for the Department of Defense's Environmental Security Technology Certification Program (ESTCP) (Project ER-0832) on alternative endpoints and alternative remedial strategies for groundwater remediation under a variety of Federal and state cleanup programs, including technical impracticability (TI) and other Applicable or Relevant and Appropriate Requirement (ARAR) waivers, state and local designations such as groundwater management zones, Alternate Concentration Limits (ACLs), use of monitored natural attenuation (MNA) over long timeframes, and more. The primary objective of the project was to provide environmental managers and regulators with tools, metrics, and information needed to evaluate alternative endpoints for groundwater remediation at complex sites. A statistical analysis of Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) sites receiving TI waivers will be presented as well as case studies of other types of alternative endpoints and alternative remedial strategies to illustrate the variety of approaches used at complex sites and the technical analyses used to predict and document cost, timeframe, and potential remedial effectiveness. Case studies provide examples of the flexible, site-specific, application of alternative endpoints and alternative remedial strategies that have been used in the past to manage and remediate groundwater contamination at complex sites. For example, at least 13 states consider some designation for groundwater containment in their corrective action policies, such as groundwater management zones, containment zones, and groundwater classification exemption areas. These designations typically indicate that groundwater contamination is present above permissible levels. Soil and groundwater within these zones are managed to protect human health and the environment. Lesson learned for the analyses conducted and the case studies evaluated allow for a more careful consideration of alternative, beneficial, and cost-effective cleanup objectives and metrics that can be achieved over the short-term (while eventually meeting long-term cleanup objectives or demonstrating the applicability of alternative endpoints), thus improving the site cleanup process at complex sites where appropriate.

Structural Insight Into the Role of Mutual Polymorphism and Conservatism in the Contact Zone of the NFR5-K1 Heterodimer With the Nod Factor.

PubMed

Igolkina, A A; Porozov, Yu B; Chizhevskaya, E P; Andronov, E E

2018-01-01

Sandwich-like docking configurations of the heterodimeric complex of NFR5 and K1 Vicia sativa receptor-like kinases together with the putative ligand, Nod factor (NF) of Rhizobium leguminosarum bv. viciae , were modeled and two of the most probable configurations were assessed through the analysis of the mutual polymorphisms and conservatism. We carried out this analysis based on the hypothesis that in a contact zone of two docked components (proteins or ligands) the population polymorphism or conservatism is mutual, i.e., the variation in one component has a reflected variation in the other component. The population material of 30 wild-growing V. sativa (leaf pieces) was collected from a large field (uncultivated for the past 25-years) and pooled; form this pool, 100 randomly selected cloned fragments of NFR5 gene and 100 of K1 gene were sequenced by the Sanger method. Congruence between population trees of NFR5 and K1 haplotypes allowed us to select two respective haplotypes, build their 3D structures, and perform protein-protein docking. In a separate simulation, the protein-ligand docking between NFR5 and NF was carried out. We merged the results of the two docking experiments and extracted NFR5-NF-K1 complexes, in which NF was located within the cavity between two receptors. Molecular dynamics simulations indicated two out of six complexes as stable. Regions of mutual polymorphism in the contact zone of one complex overlapped with known NF structural variations produced by R. leguminosarum bv. viciae . A total of 74% of the contact zone of another complex contained mutually polymorphic and conservative areas. Common traits of the obtained two stable structures allowed us to hypothesize the functional role of three-domain structure of plant LysM-RLKs in their heteromers.

How geometry and structure control the seismic radiation : spectral element simulation of the dynamic rupture of the Mw 9.0 Tohoku earthquake

NASA Astrophysics Data System (ADS)

Festa, G.; Vilotte, J.; Scala, A.

2012-12-01

The M 9.0, 2011 Tohoku earthquake, along the North American-Pacific plate boundary, East of the Honshu Island, yielded a complex broadband rupture extending southwards over 600 km along strike and triggering a large tsunami that ravaged the East coast of North Japan. Strong motion and high-rate continuous GPS data, recorded all along the Japanese archipelago by the national seismic networks K-Net and Kik-net and geodetic network Geonet, together with teleseismic data, indicated a complex frequency dependent rupture. Low frequency signals (f< 0.1 Hz) inverted from seismic, geodetic and tsunami data, evidenced an extremely compact region of large slip (between 30 to 50 meters), extending along-dip over about 100 km, between the hypocenter and the trench, and 150 to 200 km along strike. This slip asperity was likely the cause of the localized tsunami source and of the large amplitude tsunami waves. High-frequency signals (f>0.5 Hz) were instead generated close to the coast in the deeper part of the subduction zone, by at least four smaller size asperities, with possible repeated slip, and were mostly the cause for the ground shaking felt in the Eastern part of Japan. The deep origin of the high-frequency radiation was also confirmed by teleseismic high frequency back projection analysis. Intermediate frequency analysis showed a transition between the shallow and deeper part of the fault, with the rupture almost confined in a small stripe containing the hypocenter before propagating southward along the strike, indicating a predominant in-plane rupture mechanism in the initial stage of the rupture itself. We numerically investigate the role of the geometry of the subduction interface and of the structural properties of the subduction zone on the broadband dynamic rupture and radiation of the Tohoku earthquake. Based upon the almost in-plane behavior of the rupture in its initial stage, 2D non-smooth spectral element dynamic simulations of the earthquake rupture propagation are performed including the non planar and kink geometry of the subduction interface, together with bi-material interfaces taking into account rapid and large variations of the impedance properties along the subduction interfaces and dynamic normal stress coupling. Based on a number of tomographic studies of the NE Japan subduction zone at different space, evidencing a high-velocity "toe" mantle wedge, and wide-angle reflection and refraction studies, supporting a non planar geometry of the subduction interface with at least two strong bending or kink features, we constrain the subduction geometry and the structural properties of the subduction zone model along an off-Miyagi profile. Through several simulations, we investigate possible structural control on the broadband rupture process of the Tohoku earthquake, in terms of the rupture velocity, seismic radiation and slip/stress distribution along the subduction interface. We Explored the influence of initial stress and interface behavior to capture the main features of the rupture and its radiation pattern. Implications for the broad band strong motion observation are discussed, together with implications for the seismic cycle and future earthquake nucleation.

Vectorial structures of linear-polarized Butterfly-Gauss vortex beams in the far zone

NASA Astrophysics Data System (ADS)

Cheng, Ke; Zhou, Yan; Lu, Gang; Yao, Na; Zhong, Xianqiong

2018-05-01

By introducing the Butterfly catastrophe to optics, the far-zone vectorial structures of Butterfly-Gauss beam with vortex and non-vortex are studied using the angular spectrum representation and stationary phase method. The influence of topological charge, linear-polarized angle, off-axis distance and scaling length on the far-zone vectorial structures, especially in the Poynting vector and angular momentum density of the corresponding beam is emphasized. The results show that the embedded optical vortex at source plane lead to special dark zones in the far zone, where the number of dark zone equals the absolute value of topological charge of optical vortex. Furthermore, the symmetry and direction of the special dark zones can be controlled by off-axis distance and scaling length, respectively. The linear-polarized angle adjusts only the Poynting vectors of TE and TM terms, but it does not affect those of whole beam. Finally, the vectorial expressions also indicate that the total angular momentum density is certainly zero owing to the far-zone stable structures rather than rotation behaviors.

Effects of structural heterogeneity on frictional heating from biomarker thermal maturity analysis of the Muddy Mountain thrust, Nevada, USA

NASA Astrophysics Data System (ADS)

Coffey, G. L.; Savage, H. M.; Polissar, P. J.; Rowe, C. D.

2017-12-01

Faults are generally heterogeneous along-strike, with changes in thickness and structural complexity that should influence coseismic slip. However, observational limitations (e.g. limited outcrop or borehole samples) can obscure this complexity. Here we investigate the heterogeneity of frictional heating determined from biomarker thermal maturity and microstructural observations along a well-exposed fault to understand whether coseismic stress and frictional heating are related to structural complexity. We focus on the Muddy Mountain thrust, Nevada, a Sevier-age structure that has continuous exposure of its fault core and considerable structural variability for up to 50 m, to explore the distribution of earthquake slip and temperature rise along strike. We present new biomarker thermal maturity results that capture the heating history of fault rocks. Biomarkers are organic molecules produced by living organisms and preserved in the rock record. During heating, their structure is altered systematically with increasing time and temperature. Preliminary results show significant variability in thermal maturity along-strike at the Muddy Mountain thrust, suggesting differences in coseismic temperature rise on the meter- scale. Temperatures upwards of 500°C were generated in the principal slip zone at some locations, while in others, no significant temperature rise occurred. These results demonstrate that stress or slip heterogeneity occurred along the Muddy Mountain thrust at the meter-scale and considerable along-strike complexity existed, highlighting the importance of careful interpretation of whole-fault behavior from observations at a single point on a fault.

Preliminary geologic map of the Murrieta 7.5' quadrangle, Riverside County, California

USGS Publications Warehouse

Kennedy, Michael P.; Morton, Douglas M.

2003-01-01

The Murrieta quadrangle is located in the northern part of the Peninsular Ranges Province and includes parts of two structural blocks, or structural subdivisions of the province. The quadrangle is diagonally crossed by the active Elsinore fault zone, a major fault zone of the San Andreas fault system, and separates the Santa Ana Mountains block to the west from the Perris block to the east. Both blocks are relatively stable internally and within the quadrangle are characterized by the presence of widespread erosional surfaces of low relief. The Santa Ana Mountains block, in the Murrieta quadrangle, is underlain by undifferentiated, thick-layered, granular, impure quartzite and well-layered, fissile, phyllitic metamorphic rock of low metamorphic grade. Both quartzite and phyllitic rocks are Mesozoic. Unconformably overlying the metamorphic rocks are remnants of basalt flows having relatively unmodified flow surfaces. The age of the basalt is about 7-8Ma. Large shallow depressions on the surface of the larger basalt remnants form vernal ponds that contain an endemic flora. Beneath the basalt the upper part of the metamorphic rocks is deeply weathered. The weathering appears to be the same as the regional Paleocene saprolitic weathering in southern California. West of the quadrangle a variable thickness sedimentary rock, physically resembling Paleogene rocks, occurs between the basalt and metamorphic rock. Where not protected by the basalt, the weathered rock has been removed by erosion. The dominant feature on the Perris block in the Murrieta quadrangle is the south half of the Paloma Valley ring complex, part of the composite Peninsular Ranges batholith. The complex is elliptical in plan view and consists of an older ring-dike with two subsidiary short-arced dikes that were emplaced into gabbro by magmatic stoping. Small to large stoped blocks of gabbro are common within the ring-dikes. A younger ring-set of hundreds of thin pegmatite dikes occur largely within the central part of the complex. These pegmatite dikes were emplaced into a domal fracture system, apparently produced by cauldron subsidence, and include in the center of the complex, a number of flat-floored granophyre bodies. The granophyre is interpreted to be the result of pressure quenching of pegmatite magma. Along the eastern edge of the quadrangle is the western part of a large septum of medium metamorphic grade Mesozoic schist. A dissected basalt flow caps the Hogbacks northeast of Temecula, and represents remnants of a channel filling flow. Beneath the basalt is a thin deposit of stream gravel. Having an age of about 10Ma, this basalt is about 2-3Ma older than the basalt flows in the Santa Ana Mountains. The Elsinore fault zone forms a complex of pull-apart basins. The west edge of the fault zone, the Willard Fault, is marked by the high, steep eastern face of the Santa Ana Mountains. The east side of the zone, the Wildomar Fault, forms a less pronounced physiographic step. In the center of the quadrangle a major splay of the fault zone, the Murrieta Hot Springs Fault, strikes east. Branching of the fault zone causes the development of a broad alluvial valley between the Willard Fault and the Murrieta Hot Springs Fault. All but the axial part of the zone between the Willard and Wildomar Faults consist of dissected Pleistocene sedimentary units. The axial part of the zone is underlain by Holocene and latest Pleistocene sedimentary units.

3D characterization of the critical zone within a basaltic catchment using an airborne electromagnetic survey

NASA Astrophysics Data System (ADS)

Dumont, Marc; Join, Jean-Lambert; Wendling, Valentin; Aunay, Bertrand

2017-04-01

Shield volcano islands come from the succession of constructive phases and destructive phases. In this complex geological setting, weathering and paleo-weathering profiles have a major impact on the critical zone hydrology. Nevertheless those underground structures are difficult to characterize, which leads to a leak of understanding of the water balance, infiltration, and ground water flows. Airborne transient electromagnetic method, as SkyTEM dispositive, allows to proceed regional 3D resistivity mapping with almost no topographic and vegetation limitations with an investigation depth higher than 300 m. Electromagnetics results are highly sensitive to conductive layers depending of clay content, water content and water mineralization. Skytem investigations are useful to characterize the thickness of the weathering profile and its lateral variations among large areas. In addition, it provides precise information about buried valleys and paleo-weathering of older lavas flows which control preferential groundwater flows. The French Geological Survey (BRGM) conducted a SkyTEM survey over Reunion Island (2500 km2). This survey yields on a dense 3D resistivity mapping. This continuous information is used to characterize the critical zone of the experimental watershed of Rivière des Pluies. A wide range of weathering profiles has been identified. Their variations are highly dependent of lava flow ages. Furthermore, 3D resistivity model highlights buried valleys characterized by specific weathering due to groundwater flows. Hydrogeological implication is a partitioning of groundwater flows in three different reservoirs: (i) deep basal aquifer, (ii) perched aquifers and (iii) superficial flows. The two latter behaviors have been characterized and mapped above our experimental watershed. The 3D manner of airborne electromagnetics results allows describing the continuity of weathering and alteration structures. The identification of specific groundwater flow paths provides a better understanding of the relation between the surface hydrology, the unsaturated medium and the basal aquifer. This study underlines the key role of volcanic underground structures in the critical zone flows.

Long-term and Short-term Vertical Deformation Rates across the Forearc in the Central Mexican Subduction Zone

NASA Astrophysics Data System (ADS)

Ramirez-Herrera, M. T.; Gaidzik, K.; Forman, S. L.; Kostoglodov, V.; Burgmann, R.

2015-12-01

Spatial scales of the earthquake cycle, from rapid deformation associated with earthquake rupture to slow deformation associated with interseismic and transient slow-slip behavior, span from fractions of a meter to thousands of kilometers (plate boundaries). Similarly, temporal scales range from seconds during an earthquake rupture to thousands of years of strain accumulation between earthquakes. The complexity of the multiple physical processes operating over this vast range of scales and the limited coverage of observations leads most scientists to focus on a narrow space-time window to isolate just one or a few process. We discuss here preliminary results on the vertical crustal deformation associated with both slow and rapid crustal deformation along a profile across the forearc region of the central Mexican subduction zone on the Guerrero sector, where the Cocos plate underthrusts the North American plate. This sector of the subduction zone is characterized by a particular slab geometry (with zones of rapid bending-unbending of the slab), irregular distributed seismicity, exceptionally large slow slip events (SSE) and non-volcanic tremors (NVT). We used the river network and geomorphic features of the Papagayo River to assess Quaternary crustal deformation. The Papagayo drainage network is strongly controlled by Late Cenozoic tectonic, Holocene and recent earthquake cycle processes. This is particularly true for the southern section of the drainage basin; from the dam in La Venta to the river mouth, where W-E structures commonly offset the course of the main river. River terraces occur along the course of the river at different elevations. We measured the height of a series of terraces and obtained OSL ages on quartz extracts to determine long-term rates of deformation. Finally, we discuss associations of the topography and river characteristics with the Cocos slab geometry, slow earthquakes, crustal deformation, and interseismic deformation.

Hyporheic Interfaces Serve as Ecological Control Points for Mountainous Landscape Biological Productivity

NASA Astrophysics Data System (ADS)

Newcomer, M. E.; Dwivedi, D.; Raberg, J.; Fox, P. M.; Nico, P. S.; Wainwright, H. M.; Conrad, M. E.; Bill, M.; Bouskill, N.; Williams, K. H.; Hubbard, S.; Steefel, C. I.

2017-12-01

Riverine systems in snow-dominated mountainous regions often express complex biogeochemistry and river nutrient indicators as a function of hydrologic variability. In early spring, meltwater infiltration from a ripened snowpack creates a hydrological gradient through hillslopes, floodplains, and hyporheic zones. During this time, these systems are more-or-less a passive filter that allows the rising limb of the hydrograph to display chemo-dynamic relationships (inversely proportional) with solutes and nutrients. During the growing season, temperatures, plants, microbes, and hydrologic gradients shift dramatically and activate hyporheic-zone biogeochemistry as a major control on water nutrient degradation. Hyporheic biogeochemical reliance on the timing of meltwater infiltration and the possibility of a longer vernal window under future climate change indicates the importance of hyporheic cycling as the dominant ecological control point on carbon and nitrogen fluxes and transformations. The objective of our study is to develop a predictive understanding of the subsurface and surface controls on hyporheic biogeochemical behavior through data-model integration. Data from our 2017 field campaign in the East River, Colorado, a pristine, mountainous watershed, were taken at key times during the rising, peak, falling, and dry limb of the hydrograph. Throughout multiple locations across this spatial and temporal gradient, we measured surface and subsurface gases, geochemistry, isotopes, and hydrological flow conditions and used this data to constrain a numerical flow and reactive transport model of the hyporheic zone that included microbial and flow feedback dynamics. Our data coupled with the predictive power of our numerical model reveal that the hyporheic zone serves dual roles throughout the year—as a net source of nutrients and solutes during the early vernal phase, shifting to a net sink of nutrients during the summer dry season. The possibility of a future lengthened vernal window motivates a better understanding of the role each ecological control point plays in processing landscape biological productivity and for understanding biogeochemical cycling in riverine systems.

Microstructures and composition of brittle faults in claystones: Constraints on the barrier behavior

NASA Astrophysics Data System (ADS)

Kneuker, Tilo; Hammer, Jörg; Jahn, Steffen; Zulauf, Gernold

2017-04-01

Investigations of fault rocks are crucial to evaluate the barrier properties of clay rich formations used for the storage of hydrocarbons, carbon dioxide gas or for the storage of heat generating radioactive waste. Claystones are considered as a geological barrier. However, their barrier capability can be reduced if the claystones are cut by brittle faults. Our study is focusing on the microfabrics and element mobility of artificially and naturally fractured claystones using a multi-method approach. Particular attention was paid to small scale lithological heterogeneities occurring in the clayey sequence. The microfabrics were investigated using SEM and optical microscopy. Geochemical and phase analyses were carried out using XRD, XRF and ICP-MS. In addition, organic (TOC) and inorganic carbon (TIC), total sulphur (TS) as well as the cation exchange capacity (CEC) were determined. Macroscopic observations of fault zones on outcrops and drill cores indicate closely spaced planar and undulating discontinuities, including slickenside striations. The investigated fault zones are often accompanied by calcite veins and calcite enriched zones. The fault core is formed by a mm to cm thick clayey, fine grained, cohesionless fault gouge including reworked calcite fragments. Duplex-like domains are separated by discrete microshears, along which the rocks disintegrate. Calcareous fossils, common in undeformed claystones, appear in these zones fragmented and rotated. In contrast to calcite, quartz is more resistant to solution-precipitation processes. Rarely intracrystalline fracturing was observed. The calcite mineralization in veins, and solution-precipitation processes of calcite, documented by stylolites, reflect enhanced palaeo-permeability and activity of Ca2+- and CO2-rich fluids inside some of the fault zones, mainly along fault parallel shear planes. Elevated Sr and Ba concentrations are bound to the tectonic, secondary calcite veins within and outside the investigated fault zone. The geochemical data presented in form of isocon diagrams suggest volume gain related to the opening of veins and pores, which are now filled with calcite. Our results do not provide evidence for presently open pores or fractures, which might be related to non-artificial tectonic deformation. However, (micro)fractures as well as mineralized veins represent inherited damage in the rock, and are prone to brittle reactivation during fluid pressure increase or during the excavation of underground galleries. A complex, polyphase deformation history including a possible reactivation of older structures is supported by our observations.

Fe-Ti-oxide textures and microstructures in shear zones from oceanic gabbros at Atlantis Bank, Southwest Indian Ridge

NASA Astrophysics Data System (ADS)

Till, Jessica; Morales, Luiz F. G.; Rybacki, Erik

2016-04-01

Ocean drilling expeditions at several oceanic core complexes formed at slow- and ultra-slow-spreading ridges have recovered cores containing numerous zones of oxide-rich gabbros containing ilmenite and magnetite. In these cores, high modal concentrations of Fe-Ti-oxides are systematically associated with high-temperature plastic deformation features in silicates. We present observations of Fe-Ti-oxide mineral structures and textural characteristics from a series of oxide-rich shear zones from Atlantis Bank (ODP Site 735B) on the Southwest Indian Ridge aimed at determining how oxide mineral abundances relate to strain localization. Fe-Ti-oxide minerals in undeformed oxide gabbros and in highly deformed samples from natural shear zones generally have morphologies characteristic of crystallized melt, including highly cuspate grains and low dihedral angles. Anisotropy of magnetic susceptibility in oxide-rich shear zones is very strong, with fabrics mainly characterized by strong magnetic foliations parallel to the macroscopic foliation. Crystallographic preferred orientations (CPO) in magnetite are generally weak, with occasionally well-defined textures. Ilmenite typically displays well-developed CPOs, however, the melt-like ilmenite grain shapes indicate that at least part of the crystallographic texture results from oriented ilmenite growth during post-deformation crystallization. The oxides are hypothesized to have initially been present as isolated pockets of trapped melt (intercumulus liquid) in a load-bearing silicate framework. Progressive plastic deformation of silicate phases at high-temperature mainly produced two features: (i) elongated melt pockets, which crystallized to form strings of opaque minerals and (ii), interconnected networks of melt regions. The latter lead to intense strain localization of the rock, which appears as oxide-rich mylonites in the samples. In some samples, abundant low-angle grain boundaries in both magnetite and ilmenite suggest that deformation may have continued after crystallization of the late melt, imposing a weak strain on the oxides. Recent experimental deformation results indicate that magnetite and ilmenite should be weaker than most mafic silicates under anhydrous conditions. However, melt-like oxide morphologies observed in Atlantis Bank shear zones indicate that the redistribution of Fe-Ti-oxide melts may have more influence on the strength and strain localization behavior of oceanic gabbros than their solid-state rheology.

Orthopyroxene oikocrysts in the MG1 chromitite layer of the Bushveld Complex: implications for cumulate formation and recrystallisation

NASA Astrophysics Data System (ADS)

Kaufmann, Felix E. D.; Vukmanovic, Zoja; Holness, Marian B.; Hecht, Lutz

2018-02-01

Two typical mineral textures of the MG 1 chromitite of the Bushveld Complex, South Africa, were observed; one characterised by abundant orthopyroxene oikocrysts, and the other by coarse-grained granular chromitite with only minor amounts of interstitial material. Oikocrysts form elongate clusters of several crystals aligned parallel to the layering, and typically have subhedral, almost chromite-free, core zones containing remnants of olivine. The core zones are surrounded by poikilitic aureoles overgrowing euhedral to subhedral chromite chadacrysts. Chromite grains show no preferred crystal orientation, whereas orthopyroxene grains forming clusters commonly share the same crystallographic orientation. Oikocryst core zones have lower Mg# and higher concentrations of incompatible trace elements compared to their poikilitic aureoles. Core zones are relatively enriched in REE compared to a postulated parental magma (B1) and did not crystallise in equilibrium with the surrounding minerals, whereas the composition of the poikilitic orthopyroxene is consistent with growth from the B1 magma. These observations cannot be explained by the classic cumulus and post-cumulus models of oikocryst formation. Instead, we suggest that the oikocryst core zones in the MG1 chromitite layer formed by peritectic replacement of olivine primocrysts by reaction with an upwards-percolating melt enriched in incompatible trace elements. Poikilitic overgrowth on oikocryst core zones occurred in equilibrium with a basaltic melt of B1 composition near the magma-crystal mush interface. Finally, adcumulus crystallisation followed by grain growth resulted in the surrounding granular chromitite.

Iron Isotope Fractionation in the Bushveld Igneous Complex Provide Insight into Fractional Crystallization

NASA Astrophysics Data System (ADS)

Rios, K. L.; Feineman, M. D.; Bybee, G. M.

2016-12-01

Dated at 2.056 Ga and encompassing an estimated 65,000 km2 in surface area and 650,000 km3 in volume the Bushveld Igneous Complex in South Africa contains the largest and most unique layered mafic intrusion in the world. It contains 80-90% of the world's minable platinum group elements. Scientists are interested in understanding the origin of this intrusion due to its massive size, unique assemblage of minerals, and strongly zoned stratigraphy. Iron isotopes may help us to understand the roles of partial mantle melting and fractional crystallization in magma genesis and differentiation. For example, it may be possible to determine what role fractional crystallization of oxides and sulfides played in the formation of the Rustenburg Layered Suite (RLS) by comparing δ56Fe in samples from the Lower, Critical, Main and Upper Zones. The use of MC-ICPMS has made it more routine to study the fractionation of stable iron isotopes in natural systems; however, this technique has only been applied in a few studies of the RLS, mostly restricted to the Upper Main and Upper Zones. In this study δ56Fe was determined in Upper Zone magnetite, Critical Zone chromitite and Critical Zone sulfides using MC-ICP-MS. Previous research has shown that early crystallizing mafic phases incorporate the lighter 54Fe isotope leaving a residual magma with a higher δ56Fe value. Therefore, if the Upper Zone magma represents a high-degree differentiate of the parental Bushveld magma, then magmas from the Upper Zone would be expected to have a higher δ56Fe than magmas contributing to the Lower, Critical and Main Zones. The results of this experiment were indeed consistent with this hypothesis. The δ56Fe values recorded for the three sample types were: magnetite 0.19 ±0.03‰; sulfides -0.45 ±0.03‰ to -0.81 ±0.03‰; and chromitite 0.03 ±0.05‰. The sulfides of the Critical Zone are isotopically lighter than would be predicted based on equilibrium sulfide-melt fractionation, if the parental melt of the Critical Zone were in equilibrium with previously published whole rock data for Upper Zone. This is consistent with interpretations of the Upper Zone as a high degree differentiate of the Bushveld Parental Magma.

Style and rate of quaternary deformation of the Hosgri Fault Zone, offshore south-central coastal California

USGS Publications Warehouse

Hanson, Kathryn L.; Lettis, William R.; McLaren, Marcia; Savage, William U.; Hall, N. Timothy; Keller, Mararget A.

2004-01-01

The Hosgri Fault Zone is the southernmost component of a complex system of right-slip faults in south-central coastal California that includes the San Gregorio, Sur, and San Simeon Faults. We have characterized the contemporary style of faulting along the zone on the basis of an integrated analysis of a broad spectrum of data, including shallow high-resolution and deep penetration seismic reflection data; geologic and geomorphic data along the Hosgri and San Simeon Fault Zones and the intervening San Simeon/Hosgri pull-apart basin; the distribution and nature of near-coast seismicity; regional tectonic kinematics; and comparison of the Hosgri Fault Zone with worldwide strike-slip, oblique-slip, and reverse-slip fault zones. These data show that the modern Hosgri Fault Zone is a convergent right-slip (transpressional) fault having a late Quaternary slip rate of 1 to 3 mm/yr. Evidence supporting predominantly strike-slip deformation includes (1) a long, narrow, linear zone of faulting and associated deformation; (2) the presence of asymmetric flower structures; (3) kinematically consistent localized extensional and compressional deformation at releasing and restraining bends or steps, respectively, in the fault zone; (4) changes in the sense and magnitude of vertical separation both along trend of the fault zone and vertically within the fault zone; (5) strike-slip focal mechanisms along the fault trace; (6) a distribution of seismicity that delineates a high-angle fault extending through the seismogenic crust; (7) high ratios of lateral to vertical slip along the fault zone; and (8) the separation by the fault of two tectonic domains (offshore Santa Maria Basin, onshore Los Osos domain) that are undergoing contrasting styles of deformation and orientations of crustal shortening. The convergent component of slip is evidenced by the deformation of the early-late Pliocene unconformity. In characterizing the style of faulting along the Hosgri Fault Zone, we assessed alternative tectonic models by evaluating (1) the cumulative effects of multiple deformational episodes that can produce complex, difficult-to-interpret fault geometries, patterns, and senses of displacement; (2) the difficult imaging of high-angle fault planes and horizontal fault separations on seismic reflection data; and (3) the effects of strain partitioning that yield coeval strike-slip faults and associated fold and thrust belts.

Laser beam welding of Waspaloy: Characterization and corrosion behavior evaluation

NASA Astrophysics Data System (ADS)

Shoja Razavi, Reza

2016-08-01

In this work, a study on Nd:YAG laser welding of Waspaloy sheets has been made. Microstructures, phase changes and hardness of the laser joint were investigated using optical microscopy, scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction analysis (XRD) and vickers microhardness (HV0.3). Corrosion behavior of the weldment at low temperature in 3.5%wt NaCl solution at room temperature was also investigated using open circuit potential and cyclic potentiodynamic polarization tests. Hot corrosion studies were conducted on samples in the molten salt environment (Na2SO4-60%V2O5) at 900 °C for 50 h. Results indicated that the microstructure of weld zone was mainly dendritic grown epitaxially in the direction perpendicular to the weld boundary and heat transfer. Moreover, the Ti-Mo carbide particles were observed in the structure of the weld zone and base metal. The average size of carbides formed in the base metal (2.97±0.5 μm) was larger than that of the weld zone (0.95±0.2 μm). XRD patterns of the weld zone and base metal showed that the laser welding did not alter the phase structure of the weld zone, being in γ-Ni(Cr) single phase. Microhardness profile showed that the hardness values of the weld zone (210-261 HV) were lower than that of the base metal (323-330 HV). Electrochemical and hot corrosion tests indicated that the corrosion resistance of the weld metal was greater than the base metal in both room and high temperatures.

Understanding the Hydromechanical Behavior of a Fault Zone From Transient Surface Tilt and Fluid Pressure Observations at Hourly Time Scales

NASA Astrophysics Data System (ADS)

Schuite, Jonathan; Longuevergne, Laurent; Bour, Olivier; Burbey, Thomas J.; Boudin, Frédérick; Lavenant, Nicolas; Davy, Philippe

2017-12-01

Flow through reservoirs such as fractured media is powered by head gradients which also generate measurable poroelastic deformation of the rock body. The combined analysis of surface deformation and subsurface pressure provides valuable insights of a reservoir's structure and hydromechanical properties, which are of interest for deep-seated CO2 or nuclear waste storage for instance. Among all surveying tools, surface tiltmeters offer the possibility to grasp hydraulically induced deformations over a broad range of time scales with a remarkable precision. Here we investigate the information content of transient surface tilt generated by the pressurization a kilometer scale subvertical fault zone. Our approach involves the combination of field data and results of a fully coupled poromechanical model. The signature of pressure changes in the fault zone due to pumping cycles is clearly recognizable in field tilt data and we aim to explain the peculiar features that appear in (1) tilt time series alone from a set of four instruments and 2) the ratio of tilt over pressure. We evidence that the shape of tilt measurements on both sides of a fault zone is sensitive to its diffusivity and its elastic modulus. The ratio of tilt over pressure predominantly encompasses information about the system's dynamic behavior and extent of the fault zone and allows separating contributions of flow in the different compartments. Hence, tiltmeters are well suited to characterize hydromechanical processes associated with fault zone hydrogeology at short time scales, where spaceborne surveying methods fail to recognize any deformation signal.

Creating a safe place for pediatric care: A no hit zone.

PubMed

Frazier, Erin R; Liu, Gilbert C; Dauk, Kelly L

2014-07-01

Our goal was to create and implement a program, Kosair Children's Hospital's No Hit Zone, which trains health care workers in de-escalation techniques to address parental disruptive behaviors and physical discipline of children commonly encountered in the hospital environment. The Child Abuse Task Force, a multidisciplinary group, along with key hospital administrators developed specific content for the policy, as well as marketing and educational materials. The No Hit Zone policy designates Kosair Children's Hospital as "an environment in which no adult shall hit a child, no adult shall hit another adult, no child shall hit an adult, and no child shall hit another child. When hitting is observed, it is everyone's responsibility to interrupt the behavior as well as communicate system policy to those present." Via a multidisciplinary, collaborative approach, the No Hit Zone was successfully implemented at Kosair Children's Hospital in 2012. Cost was nominal, and the support of key hospital administrators was critical to the program's success. Education of health professionals on de-escalation techniques and intervention with families at the early signs of parental stress occurred via live sessions and online training via case-based scenarios. The No Hit Zone is an important program used to provide a safe and caring environment for all families and staff of Kosair Children's Hospital. Demand for the program continues, demonstrated by the establishment of No Hit Zones at other local hospitals and multiple outpatient clinics. This article offers information for other organizations planning to conduct similar initiatives. Copyright © 2014 by the American Academy of Pediatrics.

A BENCHMARKING ANALYSIS FOR FIVE RADIONUCLIDE VADOSE ZONE MODELS (CHAIN, MULTIMED_DP, FECTUZ, HYDRUS, AND CHAIN 2D) IN SOIL SCREENING LEVEL CALCULATIONS

EPA Science Inventory

Five radionuclide vadose zone models with different degrees of complexity (CHAIN, MULTIMED_DP, FECTUZ, HYDRUS, and CHAIN 2D) were selected for use in soil screening level (SSL) calculations. A benchmarking analysis between the models was conducted for a radionuclide (99Tc) rele...

76 FR 15290 - Foreign-Trade Zone 106-Oklahoma City, OK Application for Reorganization/Expansion Under...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-21

... been submitted to the Foreign-Trade Zones (FTZ) Board (the Board) by the Port Authority of Greater... Rogers World Airport complex; Site 2 (6 acres)--Biagi Bros. Warehouse, 5002 SW 36th, Oklahoma City; Site 8 (30 acres)--Will Rogers World Airport NE, immediately northeast of Will Rogers World Airport...

Modeling Water Waves with Smoothed Particle Hydrodynamics

DTIC Science & Technology

2013-09-30

SPH Model for Water Waves and Other Free Surface Flows ...Lagrangian nature of SPH allows the modeling of wave breaking, surf zones, ship waves, and wave-structure interaction, where the free surface becomes...proving to be a competent modeling scheme for free surface flows in three dimensions including the complex flows of the surf zone. As the GPU

Indentation Creep Behavior of Nugget Zone of Friction Stir Welded 2014 Aluminum Alloy

NASA Astrophysics Data System (ADS)

Das, Jayashree; Robi, P. S.; Sankar, M. Ravi

2018-04-01

The present study is aimed at evaluating the creep behavior of the nugget zone of friction welded 2014 Aluminum alloy by indentation creep tests. Impression creep testing was carried out at different temperatures of 300°C, 350°C and 400 °C with stress 124.77MPa, 187.16MPa, 249.55 MPa using a 1.0 mm diameter WC indenter. Experiments were conducted till the curve enters the steady state creep region. Constitutive modeling of creep behavior was carried out considering the temperature, stress and steady state creep rate. Microstructural investigation of the crept specimen at 400°C temperature and 187.16 MPa load was carried out and found that the small precipitates accumulate along the grain boundaries at the favorable conditions of the creep temperature and stress, new precipitates evolve due to the ageing. The grains are broken and deformed due to the creep phenomena.

A Comparative Study of Vygotsky's Perspectives on Child Language Development with Nativism and Behaviorism

ERIC Educational Resources Information Center

Dastpak, Mehdi; Behjat, Fatemeh; Taghinezhad, Ali

2017-01-01

This study aimed at investigating the similarities and differences between Vygotsky's perspectives on child language development with nativism and behaviorism. Proposing the idea of the Zone of Proximal Development, Vygotsky emphasized the role of collaborative interaction, scaffolding, and guided participation in language learning. Nativists, on…

Evaluating the effectiveness of regulatory and warning signs on driver behavior near highway/rail crossings : research project capsule.

DOT National Transportation Integrated Search

2016-12-01

The primary objective of this research project is to evaluate the effectiveness of regulatory and warning signs on driver behavior : by analyzing their effectiveness in reducing instances of stopped vehicles within the dynamic envelope zone (i.e., th...

Influence of water chemistry and travel distance on bacteriophage PRD-1 transport in a sandy aquifer

USGS Publications Warehouse

Blanford, W.J.; Brusseau, M.L.; Jim Yeh, T.-C.; Gerba, C.P.; Harvey, R.

2005-01-01

Experiments were conducted to evaluate the impact of groundwater chemistry and travel distance on the transport and fate behavior of PRD-1, a bacteriophage employed as a surrogate tracer for pathogenic enteric viruses. The experiments were conducted in the unconfined aquifer at the United States Geological Survey Cape Cod Toxic-Substances Hydrology Research Site in Falmouth, Massachusetts. The transport behavior of bromide (Br-) and PRD-1 were evaluated in a sewage-effluent contaminated zone and a shallower uncontaminated zone at this site. Several multilevel sampling devices located along a 13-m transect were used to collect vertically discrete samples to examine longitudinal and vertical variability of PRD-1 retardation and attenuation. The concentration of viable bacteriophage in the aqueous phase decreased greatly during the first few meters of transport. This decrease is attributed to a combination of colloid filtration (attachment) and inactivation. The removal was greater (10 -12 relative recovery) and occurred within the first meter for the uncontaminated zone, whereas it was lesser (10-9 relative recovery) and occurred over 4 m in the contaminated zone. The lesser removal observed for the contaminated zone is attributed to the influence of sorbed and dissolved organic matter, phosphate, and other anions, which are present in higher concentrations in the contaminated zone, on PRD-1 attachment. After the initial decrease, the aqueous PRD-1 concentrations remained essentially constant in both zones for the remainder of the tests (total travel distances of 13 m), irrespective of variations in geochemical properties within and between the two zones. The viable, mobile PRD-1 particles traveled at nearly the rate of bromide, which was used as a non-reactive tracer. The results of this study indicate that a small fraction of viable virus particles may persist in the aqueous phase and travel significant distances in the subsurface environment. ?? 2005 Elsevier Ltd. All rights reserved.

Structural Controls of the Friction Constitutive Properties of Carbonate-bearing Faults

NASA Astrophysics Data System (ADS)

Carpenter, B. M.; Collettini, C.; Scuderi, M.; Marone, C.

2012-12-01

The identification of hetereogenous and complex post-seismic slip for the 2009, Mw = 6.3, L'Aquila earthquake highlights the importance of fault zone structure and frictional behavior. Many of the Mw 6 to 7 earthquakes that occur on normal faults in the active Apennines, such as L'Aquila, nucleate at depths where the lithology is dominated by carbonate rocks. Due to the complex structure observed in exhumed faults (i.e. the presence of highly polished principal slip surfaces, cemented cataclasites, and phyllosilicate-bearing, foliated fault gouge) as well as the large spectrum of fault slip behaviors identified world wide, we designed a suite of experiments using intact and powdered samples to better constrain the possible slip behaviors of these carbonate bearing faults. We collected samples from the exposed Rocchetta Fault, a ~10km long, normal fault with approximately 600m of total offset. The exposed principal slip surface cuts through the Calcare Massiccio formation, which is present throughout central Italy at depths of earthquake nucleation. We collected intact specimens of the natural slip surface and cemented cataclasite, as well as fragments of both which were later pulverized. Furthermore, we collected an intact sample of the hanging wall cataclasite and footwall limestone that contained the principal slip surface. We performed friction experiments in a variety of different configurations (slip surface on slip surface, slip surface on powdered cataclasite, etc.) in order to investigate heterogeneity in frictional behavior as controlled by fault structure. We sheared saturated samples at a constant normal stress of 10 MPa at room temperature. Velocity-stepping tests were performed from 1 to 300 μm/s to identify the friction constitutive parameters of this fault material. Furthermore, a series slide-hold-slide tests were performed (holds of 3 to 1000 seconds) to measure the amount of frictional healing and determine the frictional healing rate. Results from experiments designed to reactivate slip between the principal slip surface and cemented cataclasite show a peak friction value of ~0.95 followed by a ~3 MPa stress drop as the fault surface fails. Our other results suggest that earthquakes will easily nucleate in areas of the fault where two slip surfaces are in contact and are likely to propagate in areas where pulverized fault gouge is in contact with the slip surface. Our data show that samples collected from a single fault can exhibit a large range of slip behaviors. Heterogeneous frictional behavior documented in the lab must be combined with field observations of complex fault structure and seismological observations of the different modes of fault slip to further our understanding of fault slip. Future work will consist of thin section and XRD analysis of all experimental material.

Introduction to the special issue on the 2004 Parkfield earthquake and the Parkfield earthquake prediction experiment

USGS Publications Warehouse

Harris, R.A.; Arrowsmith, J.R.

2006-01-01

The 28 September 2004 M 6.0 Parkfield earthquake, a long-anticipated event on the San Andreas fault, is the world's best recorded earthquake to date, with state-of-the-art data obtained from geologic, geodetic, seismic, magnetic, and electrical field networks. This has allowed the preearthquake and postearthquake states of the San Andreas fault in this region to be analyzed in detail. Analyses of these data provide views into the San Andreas fault that show a complex geologic history, fault geometry, rheology, and response of the nearby region to the earthquake-induced ground movement. Although aspects of San Andreas fault zone behavior in the Parkfield region can be modeled simply over geological time frames, the Parkfield Earthquake Prediction Experiment and the 2004 Parkfield earthquake indicate that predicting the fine details of future earthquakes is still a challenge. Instead of a deterministic approach, forecasting future damaging behavior, such as that caused by strong ground motions, will likely continue to require probabilistic methods. However, the Parkfield Earthquake Prediction Experiment and the 2004 Parkfield earthquake have provided ample data to understand most of what did occur in 2004, culminating in significant scientific advances.

Dramatic pressure-sensitive ion conduction in conical nanopores.

PubMed

Jubin, Laetitia; Poggioli, Anthony; Siria, Alessandro; Bocquet, Lydéric

2018-04-17

Ion transporters in Nature exhibit a wealth of complex transport properties such as voltage gating, activation, and mechanosensitive behavior. When combined, such processes result in advanced ionic machines achieving active ion transport, high selectivity, or signal processing. On the artificial side, there has been much recent progress in the design and study of transport in ionic channels, but mimicking the advanced functionalities of ion transporters remains as yet out of reach. A prerequisite is the development of ionic responses sensitive to external stimuli. In the present work, we report a counterintuitive and highly nonlinear coupling between electric and pressure-driven transport in a conical nanopore, manifesting as a strong pressure dependence of the ionic conductance. This result is at odds with standard linear response theory and is akin to a mechanical transistor functionality. We fully rationalize this behavior on the basis of the coupled electrohydrodynamics in the conical pore by extending the Poisson-Nernst-Planck-Stokes framework. The model is shown to capture the subtle mechanical balance occurring within an extended spatially charged zone in the nanopore. The pronounced sensitivity to mechanical forcing offers leads in tuning ion transport by mechanical stimuli. The results presented here provide a promising avenue for the design of tailored membrane functionalities.

Deformation behavior of laser welds in high temperature oxidation resistant Fe-Cr-Al alloys for fuel cladding applications

NASA Astrophysics Data System (ADS)

Field, Kevin G.; Gussev, Maxim N.; Yamamoto, Yukinori; Snead, Lance L.

2014-11-01

Ferritic-structured Fe-Cr-Al alloys are being developed and show promise as oxidation resistant accident tolerant light water reactor fuel cladding. This study focuses on investigating the weldability and post-weld mechanical behavior of three model alloys in a range of Fe-(13-17.5)Cr-(3-4.4)Al (wt.%) with a minor addition of yttrium using modern laser-welding techniques. A detailed study on the mechanical performance of bead-on-plate welds using sub-sized, flat dog-bone tensile specimens and digital image correlation (DIC) has been carried out to determine the performance of welds as a function of alloy composition. Results indicated a reduction in the yield strength within the fusion zone compared to the base metal. Yield strength reduction was found to be primarily constrained to the fusion zone due to grain coarsening with a less severe reduction in the heat affected zone. For all proposed alloys, laser welding resulted in a defect free weld devoid of cracking or inclusions.

Erosion behavior of composite Al-Cr cathodes in cathodic arc plasmas in inert and reactive atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franz, Robert, E-mail: robert.franz@unileoben.ac.at; Mendez Martin, Francisca; Hawranek, Gerhard

2016-03-15

Al{sub x}Cr{sub 1−x} composite cathodes with Al contents of x = 0.75, 0.5, and 0.25 were exposed to cathodic arc plasmas in Ar, N{sub 2}, and O{sub 2} atmospheres and their erosion behavior was studied. Cross-sectional analysis of the elemental distribution of the near-surface zone in the cathodes by scanning electron microscopy revealed the formation of a modified layer for all cathodes and atmospheres. Due to intermixing of Al and Cr in the heat-affected zone, intermetallic Al-Cr phases formed as evidenced by x-ray diffraction analysis. Cathode poisoning effects in the reactive N{sub 2} and O{sub 2} atmospheres were nonuniform as a resultmore » of the applied magnetic field configuration. With the exception of oxide islands on Al-rich cathodes, reactive layers were absent in the circular erosion zone, while nitrides and oxides formed in the less eroded center region of the cathodes.« less

Effect of welding on creep damage evolution in P91B steel

NASA Astrophysics Data System (ADS)

Baral, J.; Swaminathan, J.; Chakrabarti, D.; Ghosh, R. N.

2017-07-01

Study of creep behavior of base metal (without weld) and welded specimens of P91B steel over a range of temperatures (600-650 °C) and stresses (50-180 MPa) showed similar values of minimum creep-rates for both specimens at higher stress regime (>100 MPa) whilst, significantly higher creep rates in the case of welded specimens at lower stress regime. Considering that welded specimen is comprised of two distinct structural regimes, i.e. weld affected zone and base metal, a method has been proposed for estimating the material parameters describing creep behavior of those regimes. Stress-strain distribution across welded specimen predicted from finite element analysis based on material parameters revealed preferential accumulation of stress and creep strain at the interface between weld zone and base metal. This is in-line with the experimental finding that creep rupture preferentially occurs at inter-critical heat affected zone in welded specimens owing to ferrite-martensite structure with coarse Cr23C6 particles.

Strategies and Rubrics for Teaching Chaos and Complex Systems Theories as Elaborating, Self-Organizing, and Fractionating Evolutionary Systems

ERIC Educational Resources Information Center

Fichter, Lynn S.; Pyle, E. J.; Whitmeyer, S. J.

2010-01-01

To say Earth systems are complex, is not the same as saying they are a complex system. A complex system, in the technical sense, is a group of -agents (individual interacting units, like birds in a flock, sand grains in a ripple, or individual units of friction along a fault zone), existing far from equilibrium, interacting through positive and…

Dynamic Brain Network Correlates of Spontaneous Fluctuations in Attention.

PubMed

Kucyi, Aaron; Hove, Michael J; Esterman, Michael; Hutchison, R Matthew; Valera, Eve M

2017-03-01

Human attention is intrinsically dynamic, with focus continuously shifting between elements of the external world and internal, self-generated thoughts. Communication within and between large-scale brain networks also fluctuates spontaneously from moment to moment. However, the behavioral relevance of dynamic functional connectivity and possible link with attentional state shifts is unknown. We used a unique approach to examine whether brain network dynamics reflect spontaneous fluctuations in moment-to-moment behavioral variability, a sensitive marker of attentional state. Nineteen healthy adults were instructed to tap their finger every 600 ms while undergoing fMRI. This novel, but simple, approach allowed us to isolate moment-to-moment fluctuations in behavioral variability related to attention, independent of common confounds in cognitive tasks (e.g., stimulus changes, response inhibition). Spontaneously increasing tap variance ("out-of-the-zone" attention) was associated with increasing activation in dorsal-attention and salience network regions, whereas decreasing tap variance ("in-the-zone" attention) was marked by increasing activation of default mode network (DMN) regions. Independent of activation, tap variance representing out-of-the-zone attention was also time-locked to connectivity both within DMN and between DMN and salience network regions. These results provide novel mechanistic data on the understudied neural dynamics of everyday, moment-to-moment attentional fluctuations, elucidating the behavioral importance of spontaneous, transient coupling within and between attention-relevant networks. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

Texture Development and Material Flow Behavior During Refill Friction Stir Spot Welding of AlMgSc

NASA Astrophysics Data System (ADS)

Shen, Junjun; Lage, Sara B. M.; Suhuddin, Uceu F. H.; Bolfarini, Claudemiro; dos Santos, Jorge F.

2018-01-01

The microstructural evolution during refill friction stir spot welding of an AlMgSc alloy was studied. The primary texture that developed in all regions, with the exception of the weld center, was determined to be 〈110〉 fibers and interpreted as a simple shear texture with the 〈110〉 direction aligned with the shear direction. The material flow is mainly driven by two components: the simple shear acting on the horizontal plane causing an inward-directed spiral flow and the extrusion acting on the vertical plane causing an upward-directed or downward-directed flow. Under such a complex material flow, the weld center, which is subjected to minimal local strain, is the least recrystallized. In addition to the geometric effects of strain and grain subdivision, thermally activated high-angle grain boundary migration, particularly continuous dynamic recrystallization, drives the formation of refined grains in the stirred zone.

Aerodynamic study of a stall regulated horizontal-axis wind turbine

NASA Astrophysics Data System (ADS)

Constantinescu, S. G.; Crunteanu, D. E.; Niculescu, M. L.

2013-10-01

The wind energy is deemed as one of the most durable energetic variants of the future because the wind resources are immense. Furthermore, one predicts that the small wind turbines will play a vital role in the urban environment. Unfortunately, the complexity and the price of pitch regulated small horizontal-axis wind turbines represent ones of the main obstacles to widespread the use in populated zones. Moreover, the energetic efficiency of small stall regulated wind turbines has to be high even at low and medium wind velocities because, usually the cities are not windy places. During the running stall regulated wind turbines, due to the extremely broad range of the wind velocity, the angle of attack can reach high values and some regions of the blade will show stall and post-stall behavior. This paper deals with stall and post-stall regimes because they can induce significant vibrations, fatigue and even the wind turbine failure.

Hall effect analysis in irradiated silicon samples with different resistivities

NASA Astrophysics Data System (ADS)

Borchi, E.; Bruzzi, M.; Dezillie, B.; Lazanu, S.; Li, Z.; Pirollo, S.

1999-08-01

The changes induced by neutron irradiation in n- and p-type silicon samples with starting resistivities from 10 /spl Omega/-cm up to 30 k/spl Omega/-cm, grown using different techniques, as float-zone (FZ), Czochralski (CZ) and epitaxial, have been analyzed by Van der Pauw and Hall effect measurements. Increasing the fluence, each set of samples evolves toward a quasi-intrinsic p-type material. This behavior has been explained in the frame of a two-level model, that considers the introduction during irradiation of mainly two defects. A deep acceptor and a deep donor, probably related to the divacancy and to the C/sub i/O/sub i/ complex, are placed in the upper and lower half of the forbidden gap, respectively. This simple model explains quantitatively the data on resistivity and Hall coefficient of each set of samples up to the fluence of /spl ap/10/sup 14/ n/cm/sup 2/.

Simulation and in situ measurement of stress distribution in a polymer electrolyte membrane fuel cell stack

NASA Astrophysics Data System (ADS)

de la Cruz, Javier; Cano, Ulises; Romero, Tatiana

2016-10-01

A critical parameter for PEM fuel cell's electric contact is the nominal clamping pressure. Predicting the mechanical behavior of all components in a fuel cell stack is a very complex task due to the diversity of materials properties. Prior to the integration of a 3 kW PEMFC power plant, a numerical simulation was performed in order to obtain the mechanical stress distribution for two of the most pressure sensitive components of the stack: the membrane, and the graphite plates. The stress distribution of the above mentioned components was numerically simulated by finite element analysis and the stress magnitude for the membrane was confirmed using pressure films. Stress values were found within the elastic zone which guarantees mechanical integrity of fuel cell components. These low stress levels particularly for the membrane will allow prolonging the life and integrity of the fuel cell stack according to its design specifications.

The life of a dead ant: the expression of an adaptive extended phenotype.

PubMed

Andersen, Sandra B; Gerritsma, Sylvia; Yusah, Kalsum M; Mayntz, David; Hywel-Jones, Nigel L; Billen, Johan; Boomsma, Jacobus J; Hughes, David P

2009-09-01

Specialized parasites are expected to express complex adaptations to their hosts. Manipulation of host behavior is such an adaptation. We studied the fungus Ophiocordyceps unilateralis, a locally specialized parasite of arboreal Camponotus leonardi ants. Ant-infecting Ophiocordyceps are known to make hosts bite onto vegetation before killing them. We show that this represents a fine-tuned fungal adaptation: an extended phenotype. Dead ants were found under leaves, attached by their mandibles, on the northern side of saplings approximately 25 cm above the soil, where temperature and humidity conditions were optimal for fungal growth. Experimental relocation confirmed that parasite fitness was lower outside this manipulative zone. Host resources were rapidly colonized and further secured by extensive internal structuring. Nutritional composition analysis indicated that such structuring allows the parasite to produce a large fruiting body for spore production. Our findings suggest that the osmotrophic lifestyle of fungi may have facilitated novel exploitation strategies.

Testing of New Materials and Computer Aided Optimization of Process Parameters and Clamping Device During Predevelopment of Laser Welding Processes

NASA Astrophysics Data System (ADS)

Weidinger, Peter; Günther, Kay; Fitzel, Martin; Logvinov, Ruslan; Ilin, Alexander; Ploshikhin, Vasily; Hugger, Florian; Mann, Vincent; Roth, Stephan; Schmidt, Michael

The necessity for weight reduction in motor vehicles in order to save fuel consumption pushes automotive suppliers to use materials of higher strength. Due to their excellent crash behavior high strength steels are increasingly applied in various structures. In this paper some predevelopment steps for a material change from a micro alloyed to dual phase and complex phase steels of a T-joint assembly are displayed. Initially the general weldability of the materials regarding pore formation, hardening in the heat affected zone and hot cracking susceptibility is discussed. After this basic investigation, the computer aided design optimization of a clamping device is shown, in which influences of the clamping jaw, the welding position and the clamping forces upon weld quality are presented. Finally experimental results of the welding process are displayed, which validate the numerical simulation.

Transitional paleointensities from Kauai, Hawaii, and geomagnetic reversal models

USGS Publications Warehouse

Bogue, Scott W.; Coe, Robert S.

1984-01-01

Previously presented paleointensity results from an R-N transition zone in Kauai, Hawaii, show that field intensity dropped from 0. 431 Oe to 0. 101 Oe while the field remained within 30 degree of the reversed axial dipole direction. A recovery in intensity and the main directional change followed this presumably short period of low field strength. As the reversal neared completion, the field has an intensity of 0. 217 Oe while still 40 degree from the final direction. The relationship of paleointensity to field direction during the early part of the reversal thus differs from that toward the end, a feature that only some reversal models are consistent with. For example, a model in which a standing nondipole component persists through the dipole reversal predicts only symmetric intensity patterns. In contrast, zonal flooding models generate suitably complex field behavior if multiple flooding schemes operate during a single reversal or if the flooding process is itself asymmetric.

Streaks, multiplets, and holes: High-resolution spatio-temporal behavior of Parkfield seismicity

USGS Publications Warehouse

Waldhauser, F.; Ellsworth, W.L.; Schaff, D.P.; Cole, A.

2004-01-01

Double-difference locations of ???8000 earthquakes from 1969-2002 on the Parkfield section of the San Andreas Fault reveal detailed fault structures and seismicity that is, although complex, highly organized in both space and time. Distinctive features of the seismicity include: 1) multiple recurrence of earthquakes of the same size at precisely the same location on the fault (multiplets), implying frictional or geometric controls on their location and size; 2) sub-horizontal alignments of hypocenters along the fault plane (streaks), suggestive of rheological transitions within the fault zone and/or stress concentrations between locked and creeping areas; 3) regions devoid of microearthquakes with typical dimensions of 1-5 km (holes), one of which contains the M6 1966 Parkfield earthquake hypocenter. These features represent long lived structures that persist through many cycles of individual event. Copyright 2004 by the American Geophysical Union.

Geochemistry and mineralogy of the Dotson Zone HREE deposit in the Bokan Mountain peralkaline igneous complex, southeastern Alaska, USA

USGS Publications Warehouse

Taylor, Cliff D.; Lowers, Heather; Adams, David; Robinson, R. James

2017-01-01

The Bokan Mountain igneous complex (BMIC) is a typical example of a peralkaline intrusive system that has evolved to the point of developing late stage HFSE- and REE-rich silicic pegmatites and dikes. The Dotson Zone comprises a series of felsic dikes that extend from the southeast margin of the composite pluton and may represent an important resource of critical HREEs. Petrographically, the primary igneous mineral assemblage is altered by late-igneous and hydrothermal fluids resulting in redistribution and enrichment of REEs. An area of flexure in the southeastern end of the Dotson Zone was the primary locus of enrichment as shown by the pervasive alteration and consistently high REE+Y values. We favor a model in which the dikes were emplaced concurrently with the marginal intrusions, and then altered during emplacement of the inner, main intrusion in a relatively rapid series of overlapping intrusive and late magmatic fluid-high temperature hydrothermal events as the complex cooled. A much later sodic intrusive event focused on the BMIC may have resulted in additional silica-Na-Zr-rich alteration in proximity to the pluton.

In-depth analysis of drivers' merging behavior and rear-end crash risks in work zone merging areas.

PubMed

Weng, Jinxian; Xue, Shan; Yang, Ying; Yan, Xuedong; Qu, Xiaobo

2015-04-01

This study investigates the drivers' merging behavior and the rear-end crash risk in work zone merging areas during the entire merging implementation period from the time of starting a merging maneuver to that of completing the maneuver. With the merging traffic data from a work zone site in Singapore, a mixed probit model is developed to describe the merging behavior, and two surrogate safety measures including the time to collision (TTC) and deceleration rate to avoid the crash (DRAC) are adopted to compute the rear-end crash risk between the merging vehicle and its neighboring vehicles. Results show that the merging vehicle has a bigger probability of completing a merging maneuver quickly under one of the following situations: (i) the merging vehicle moves relatively fast; (ii) the merging lead vehicle is a heavy vehicle; and (iii) there is a sizable gap in the adjacent through lane. Results indicate that the rear-end crash risk does not monotonically increase as the merging vehicle speed increases. The merging vehicle's rear-end crash risk is also affected by the vehicle type. There is a biggest increment of rear-end crash risk if the merging lead vehicle belongs to a heavy vehicle. Although the reduced remaining distance to work zone could urge the merging vehicle to complete a merging maneuver quickly, it might lead to an increased rear-end crash risk. Interestingly, it is found that the rear-end crash risk could be generally increased over the elapsed time after the merging maneuver being triggered. Copyright © 2015 Elsevier Ltd. All rights reserved.

The Hydrothermal System of the Bushveld Complex, South Africa - An Analog for Subduction Zone Hydrothermal Systems

NASA Astrophysics Data System (ADS)

Boudreau, A. E.; Connolly, J. A.

2017-12-01

Crystallization of the 2.06 Ga Bushveld magma formed a 9 km (maximum) sequence of ultramafic and mafic rocks that generated a large volume of country fluid as it thermally metamorphosed a 3+ km section of previously unaltered underlying sedimentary rocks of the Transvaal sequence - a geometry similar to that seen as subducting lithospheric slabs are heated by overlying mantle rocks. The presence of a diatreme (breccia pipe) and other large, pipe-like features in the Bushveld Complex suggest that overpressured fluids generated during dehydration of the footwall sediments rapidly penetrate the lower portions of the complex. Numeric modeling of the footwall dehydration similarly suggests that most of the country fluids will be confined to pipe-like channels as it percolates into the Bushveld sill. Modeling also suggests that the maximum extent of the metamorphic aureole was reached at about the same time that the Main zone began to crystallize. It is suggested that rapid inflation of the Bushveld sill induced the sudden and catastrophic expulsion of overpressured country fluids (the "whoopee cushion" effect) to both generate the diatreme and contaminate the Main zone magma, resulting in the Main zone enrichment in a crustal Sr isotopic signature. By analogy, it is also suggested that hydration melting in the mantle wedge is episodically driven by similar sudden influxes of slab fluids that are able to retain their geochemical and isotopic character by rapid channeled influx.

Examining the Fieldwork Experience from the Site Supervisor Perspective: A Mixed-Methods Study Using Vygotsky's Zone of Proximal Development Theory

ERIC Educational Resources Information Center

Brannon, Sian

2013-01-01

The purpose of this study was to identify feelings and behaviors of fieldwork supervisors in public libraries using Lev Vygotsky's Zone of Proximal Development theory as a background for design, analysis, and discussion of results. This research sought to find out how fieldwork supervisors perform initial assessments of their fieldwork students,…

Effects of environmental complexity and temporary captivity on foraging behavior of wild-caught meadow voles.

PubMed

Kozuch, Amaranta E; McPhee, M Elsbeth

2014-01-01

Increased housing of wild nonhuman animals in captivity for conservation, research, and rehabilitation has revealed the importance of systematically analyzing effects of the captive environment on behavior. This study focused on the effects of complexity and time held in captivity on foraging behaviors of wild-caught, adult meadow voles (Microtus pennsylvanicus). Forty-six individuals captured from a meadow outside Oshkosh, WI, were assigned to 1 of 4 captive treatment groups: simple/<50 days (SS), simple/>50 days, complex/<50 days, and complex/>50 days. Number of dish visits, proportion foraging, and frequency of nonforaging behaviors recorded during a 15-min foraging trial were measured for all subjects. Kruskal-Wallis and Mann-Whitney U Tests were conducted to analyze 4 different comparisons within this behavioral data. Overall, neither time in captivity or environmental complexity affected nonforaging behaviors. In contrast, foraging behaviors did change with treatment: Voles were less active at food dishes and visited control dishes more in treatment group SS than in the other treatment groups. In addition, sex-related differences in foraging behaviors were maintained when voles were exposed to environmental complexity. This article includes options for wildlife managers to adapt captive environments to meet the welfare and behavioral needs of translocated wild nonhuman mammals.

Geodynamic models of the deep structure of the natural disaster regions of the Earth

NASA Astrophysics Data System (ADS)

Rodnikov, A. G.; Sergeyeva, N. A.; Zabarinskaya, L. P.

2012-04-01

Investigation of the deep structure and creation of geodynamic models of natural disaster regions are important for understanding of the nature of such phenomena as earthquakes, eruptions of volcanoes, tsunami and others. Carrying out of such researches is necessary for definition of areas of potential risk, forecasting and the prevention of negative consequences of acts of nature. Research region is active continental margins of the Sea of Okhotsk, and especially the area of Neftegorsk earthquake which has occurred on May, 28th 1995 in the North Sakhalin and caused many victims and destructions. The geodynamic model of the lithosphere in the region of Neftegorsk earthquake has been constructed along the profile crossing the North Sakhalin Basin, Deryugin Basin and ophiolite complex between them. The Deryugin Basin was formed at the site of an ancient deep trench after the subduction of the Okhotsk Sea Plate under Sakhalin. The basin is located above a hot plume in the mantle at a depth of 25 km. The ophiolite belt of ultramafic magmatic rocks is an ancient (K2-Pg) paleosubduction zone separating the Deryugin basin from the North Sakhalin Basin. The thickness of the ancient seismic focal zone is 80 km. It is probably that the structures of the North Sakhalin have been formed in the following way. In the Late Cretaceous the oceanic Okhotsk Sea Plate subducted under Sakhalin, the eastern part of which was an andesite island arc. Approximately in Miocene the subduction of the plate apparently ceased. In that time the Tatar Rift Strait was formed. Ophiolite rocks of the subduction zones as a result of compression have been squeezed out on a surface. The ophiolite complex combined by the ultrabasic rocks, fixes position of ancient subduction zone. It is probable that the manifestation of the Neftegorsk earthquake was a result of activization of this ancient subduction zone. On a surface the subduction zone manifests itself as deep faults running along Sakhalin. The center of the Neftegorsk earthquake was directly formed by burst of activity of this ancient subduction zone. From a position of the ancient subduction zone under Sakhalin, which is a cause of strong earthquakes here, it follows that the region is one of seismic dangerous in Russia. Constructed on the basis of complex interpretation of the geologic-geophysical data the geodynamic models of natural disaster regions give the chance: to study a deep structure under seismic dangerous zones; to investigate a role of deep processes in the upper mantle in formation of structures of earth crust; to relate the geological features, tectonomagmatic, hydrothermal activity with the processes in the upper mantle; to plot maps in detail with zones of increasing risks to prevent active building or other economic activities in such dangerous regions.

Deposition of Franciscan Complex cherts along the paleoequator and accretion to the American margin at tropical paleolatitudes

USGS Publications Warehouse

Hagstrum, J.T.; Murchey, B.L.

1993-01-01

Red radiolarian cherts from three localities within the Franciscan subduction complex of northern California contain three components of remanent magnetization which are best isolated by progressive thermal demagnetization. The available paleomagnetic, biostratigraphic, and geochemical data indicate deposition of these cherts along the paleoequator (0??-2??N or S paleolatitude) between Pliensbachian and Oxfordian time as the oceanic plate moved eastward, relative to North America, beneath the equatorial zone of high biologic productivity. The chert sequences were subsequently accreted to the American continental margin. Plate reconstruction models for the Farallon plate corrobotate low-paleolatitude trajectories from ridge crest to subduction zone, and they imply subsequent northward translation of the Franciscan Complex by strike-slip faulting related to relative motions between the Farallon, Kula, Pacific, and North American plates. -from Authors

One-dimensional error-diffusion technique adapted for binarization of rotationally symmetric pupil filters

NASA Astrophysics Data System (ADS)

Kowalczyk, Marek; Martínez-Corral, Manuel; Cichocki, Tomasz; Andrés, Pedro

1995-02-01

Two novel algorithms for the binarization of continuous rotationally symmetric real and positive pupil filters are presented. Both algorithms are based on the one-dimensional error diffusion concept. In our numerical experiment an original gray-tone apodizer is substituted by a set of transparent and opaque concentric annular zones. Depending on the algorithm the resulting binary mask consists of either equal width or equal area zones. The diffractive behavior of binary filters is evaluated. It is shown that the filter with equal width zones gives Fraunhofer diffraction pattern more similar to that of the original gray-tone apodizer than that with equal area zones, assuming in both cases the same resolution limit of device used to print both filters.

Modeling Driver Behavior near Intersections in Hidden Markov Model

PubMed Central

Li, Juan; He, Qinglian; Zhou, Hang; Guan, Yunlin; Dai, Wei

2016-01-01

Intersections are one of the major locations where safety is a big concern to drivers. Inappropriate driver behaviors in response to frequent changes when approaching intersections often lead to intersection-related crashes or collisions. Thus to better understand driver behaviors at intersections, especially in the dilemma zone, a Hidden Markov Model (HMM) is utilized in this study. With the discrete data processing, the observed dynamic data of vehicles are used for the inference of the Hidden Markov Model. The Baum-Welch (B-W) estimation algorithm is applied to calculate the vehicle state transition probability matrix and the observation probability matrix. When combined with the Forward algorithm, the most likely state of the driver can be obtained. Thus the model can be used to measure the stability and risk of driver behavior. It is found that drivers’ behaviors in the dilemma zone are of lower stability and higher risk compared with those in other regions around intersections. In addition to the B-W estimation algorithm, the Viterbi Algorithm is utilized to predict the potential dangers of vehicles. The results can be applied to driving assistance systems to warn drivers to avoid possible accidents. PMID:28009838

Distribution of Stress in Deformation Zone of Niobium Microalloyed Steel

NASA Astrophysics Data System (ADS)

Jandrlić, Ivan; Rešković, Stoja; Brlić, Tin

2018-03-01

Microalloyed steels today represent a significant part of total world production and processing of steel. Although widely used, there are scarce data on the stress distribution in the deformation zone of these steels. Research was carried out on two steel grades, both low-carbon structural steels with the same basic chemical composition, with one of them additionally microalloyed with niobium. Differences in the stress distribution in the deformation zone between two tested steels were continuously observed and measured using the methods of digital image correlation and thermography. It has been found out that niobium microalloyed steel has significantly more complex material flow and stress distribution in the deformation zone when compared to the plain low carbon steel.

Distribution of Stress in Deformation Zone of Niobium Microalloyed Steel

NASA Astrophysics Data System (ADS)

Jandrlić, Ivan; Rešković, Stoja; Brlić, Tin

2018-07-01

Microalloyed steels today represent a significant part of total world production and processing of steel. Although widely used, there are scarce data on the stress distribution in the deformation zone of these steels. Research was carried out on two steel grades, both low-carbon structural steels with the same basic chemical composition, with one of them additionally microalloyed with niobium. Differences in the stress distribution in the deformation zone between two tested steels were continuously observed and measured using the methods of digital image correlation and thermography. It has been found out that niobium microalloyed steel has significantly more complex material flow and stress distribution in the deformation zone when compared to the plain low carbon steel.

Hydropedology: Synergistic integration of soil science and hydrology in the Critical Zone

USGS Publications Warehouse

Lin, H.S.; McDonnell, J.J.; Nimmo, John R.; Pachepsky, Y. A.

2016-01-01

Soil and water are the two critical components of theEarth’s Critical Zone (Figure 1): Soil modulates the connection between bedrock and the atmospheric boundary layer and water is a major driving force and transport agent between these two zones. The interactions between soil and water are so intimate and complex that they cannot be effectively studied in a piecemeal manner; they require a systems approach. In this spirit, hydropedology has emerged in recent years as a synergistic integration of soil science and hydrology that offers a renewed perspective and an integrated approach to understanding interactive pedologic and hydrologic processes and their properties in the Critical Zone.

Damage initiated self-healing in ionomer blends

NASA Astrophysics Data System (ADS)

Rahman, Md. Arifur; Penco, Maurizio; Spagnoli, Gloria; Peroni, Isabella; Ramorino, Giorgio; Sartore, Luciana; Bignotti, Fabio; Landro, Luca Di

2012-07-01

The development and understanding of self-healing mechanisms have been investigated in blends of ionomers (Poly(ethyelene-co-methacrylic acid), sodium & zinc ions) (EMNa & EMZn) containing both elastomers (Epoxidized natural rubbers (ENR) and cis-1,4-Polyisoprene (PISP)) and crystalline component (Poly(vinly alcohol-co-ethylene) [PVAcE]) as secondary phases. All the blends were prepared by melt-blending and self-healing behavior was studied in ballistic puncture tests. Self-healing behavior of each material was evaluated by observing the impact zones under a stereo-optical microscope and the micrographic results were further supported by the fluid flow test in the punctured zones. Interestingly, ENR50 blends of sodium ion containing ionomers exhibited complete self-repairing behavior while zinc ion containing ionomer showed limited mending but EMNa/ENR25 and EMNa/PISP blends did not show any self-healing behavior following the damage. On the other hand, a composition dependent healing behavior was observed in the EMNa/PVAcE blends where healing was observed up to 30wt% PVAcE containing blends. The chemical structure studied by FTIR analysis showed that both ion content of ionomer and functionality of ENR have significant influence on the self-repairing behavior of blends. TEM analysis revealed that self-healing occurs in the blends when the dispersed phase has a dimension of 100 to 400 nm.

Alkanes as Components of Soil Hydrocarbon Status: Behavior and Indication Significance

NASA Astrophysics Data System (ADS)

Gennadiev, A. N.; Zavgorodnyaya, Yu. A.; Pikovskii, Yu. I.; Smirnova, M. A.

2018-01-01

Studies of soils on three key plots with different climatic conditions and technogenic impacts in Volgograd, Moscow, and Arkhangelsk oblasts have showed that alkanes in the soil exchange complex have some indication potential for the identification of soil processes. The following combinations of soil-forming factors and processes have been studied: (a) self-purification of soil after oil pollution; (b) accumulation of hydrocarbons coming from the atmosphere to soils of different land use patterns; and (c) changes in the soil hydrocarbon complex beyond the zone of technogenic impact due to the input of free hydrocarbon-containing gases. At the injection input of hydrocarbon pollutants, changes in the composition and proportions of alkanes allow tracing the degradation trend of pollutants in the soil from their initial content to the final stage of soil self-purification, when the background concentrations of hydrocarbons are reached. Upon atmospheric deposition of hydrocarbons onto the soil, from the composition and mass distribution of alkanes, conclusions can be drawn about the effect of toxicants on biogeochemical processes in the soil, including their manifestation under different land uses. Composition analysis of soil alkanes in natural landscapes can reveal signs of hydrocarbon emanation fluxes in soils. The indication potentials of alkanes in combination with polycyclic aromatic hydrocarbons and other components of soil hydrocarbon complex can also be used for the solution of other soil-geochemical problems.

Toward a physics-based rate and state friction law for earthquake nucleation processes in fault zones with granular gouge

NASA Astrophysics Data System (ADS)

Ferdowsi, B.; Rubin, A. M.

2017-12-01

Numerical simulations of earthquake nucleation rely on constitutive rate and state evolution laws to model earthquake initiation and propagation processes. The response of different state evolution laws to large velocity increases is an important feature of these constitutive relations that can significantly change the style of earthquake nucleation in numerical models. However, currently there is not a rigorous understanding of the physical origins of the response of bare rock or gouge-filled fault zones to large velocity increases. This in turn hinders our ability to design physics-based friction laws that can appropriately describe those responses. We here argue that most fault zones form a granular gouge after an initial shearing phase and that it is the behavior of the gouge layer that controls the fault friction. We perform numerical experiments of a confined sheared granular gouge under a range of confining stresses and driving velocities relevant to fault zones and apply 1-3 order of magnitude velocity steps to explore dynamical behavior of the system from grain- to macro-scales. We compare our numerical observations with experimental data from biaxial double-direct-shear fault gouge experiments under equivalent loading and driving conditions. Our intention is to first investigate the degree to which these numerical experiments, with Hertzian normal and Coulomb friction laws at the grain-grain contact scale and without any time-dependent plasticity, can reproduce experimental fault gouge behavior. We next compare the behavior observed in numerical experiments with predictions of the Dieterich (Aging) and Ruina (Slip) friction laws. Finally, the numerical observations at the grain and meso-scales will be used for designing a rate and state evolution law that takes into account recent advances in rheology of granular systems, including local and non-local effects, for a wide range of shear rates and slow and fast deformation regimes of the fault gouge.

Implementation of Solute Transport in the Vadose Zone into the `HYDRUS Package for MODFLOW'

NASA Astrophysics Data System (ADS)

Simunek, J.; Beegum, S.; Szymkiewicz, A.; Sudheer, K. P.

2017-12-01

The 'HYDRUS package for MODFLOW' was developed by Seo et al. (2007) and Twarakavi et al. (2008) to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package, which is based on the HYDRUS-1D model (Šimůnek et al., 2016) simulating unsaturated water flow in the vadose zone, was incorporated into MODFLOW (Harbaugh et al., 2000) simulating saturated groundwater flow. The HYDRUS package in the coupled model can be used to represent the effects of various unsaturated zone processes, including infiltration, evaporation, root water uptake, capillary rise, and recharge in homogeneous or layered soil profiles. The coupled model is effective in addressing spatially-variable saturated-unsaturated hydrological processes at the regional scale, allowing for complex layering in the unsaturated zone, spatially and temporarily variable water fluxes at the soil surface and in the root zone, and with alternating recharge and discharge fluxes (Twarakavi et al., 2008). One of the major limitations of the coupled model was that it could not be used to simulate at the same time solute transport. However, solute transport is highly dependent on water table fluctuations due to temporal and spatial variations in groundwater recharge. This is an important concern when the coupled model is used for analyzing groundwater contamination due to transport through the unsaturated zone. The objective of this study is to integrate the solute transport model (the solute transport part of HYDRUS-1D for the unsaturated zone and MT3DMS (Zheng and Wang, 1999; Zheng, 2009) for the saturated zone) into an existing coupled water flow model. The unsaturated zone component of the coupled model can consider solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption (Šimůnek and van Genuchten, 2008). Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the HYDRUS package. The developed integrated model is verified using HYDRUS-2D and analyzed for its computational time requirements.

Apparent Brecciation Gradient, Mount Desert Island, Maine

NASA Astrophysics Data System (ADS)

Hawkins, A. T.; Johnson, S. E.

2004-05-01

Mount Desert Island, Maine, comprises a shallow level, Siluro-Devonian igneous complex surrounded by a distinctive breccia zone ("shatter zone" of Gilman and Chapman, 1988). The zone is very well exposed on the southern and eastern shores of the island and provides a unique opportunity to examine subvolcanic processes. The breccia of the Shatter Zone shows wide variation in percent matrix and clast, and may represent a spatial and temporal gradient in breccia formation due to a single eruptive or other catastrophic volcanic event. The shatter zone was divided into five developmental stages based on the extent of brecciation: Bar Harbor Formation, Sols Cliffs breccia, Seeley Road breccia, Dubois breccia, and Great Head breccia. A digital camera was employed to capture scale images of representative outcrops using a 0.5 m square Plexiglas frame. Individual images were joined in Adobe Photoshop to create a composite image of each outcrop. The composite photo was then exported to Adobe Illustrator, which was used to outline the clasts and produce a digital map of the outcrop for analysis. The fractal dimension (Fd) of each clast was calculated using NIH Image and a Euclidean distance mapping method described by Bérubé and Jébrak (1999) to quantify the morphology of the fragments, or the complexity of the outline. The more complex the fragment outline, the higher the fractal dimension, indicating that the fragment is less "mature" or has had less exposure to erosional processes, such as the injection of an igneous matrix. Sols Cliffs breccia has an average Fd of 1.125, whereas Great Head breccia has an average Fd of 1.040, with the stages between having intermediate values. The more complex clasts of the Sols Cliffs breccia with a small amount (26.38%) of matrix material suggests that it is the first stage in a sequence of brecciation ending at the more mature, matrix-supported (71.37%) breccia of Great Head. The results of this study will be used to guide isotopic and geochemical analysis of the matrix igneous material in the attempt to better understand the dynamic processes that occur in subvolcanic environments and the mechanisms involved in breccia formation.

Quiescence and activation of stem and precursor cell populations in the subependymal zone of the mammalian brain are associated with distinct cellular and extracellular matrix signals

USDA-ARS?s Scientific Manuscript database

The subependymal zone (SEZ) of the lateral ventricles is one of the areas of the adult brain where new neurons are continuously generated from neural stem cells (NSCs), via rapidly dividing precursors. This neurogenic niche is a complex cellular and extracellular microenvironment, highly vascularize...

Development of an anti-EPO antibody detection kit based on lab-on-a-chip and bridging antibody technologies.

PubMed

Oh, Jin-Gyo; Seong, Jihyun; Han, Sunmi; Heo, Tae-Hwe

2018-05-17

Immunogenicity is a major concern in the use of biological drugs. In particular, antibody-mediated pure red cell aplasia (PRCA) is a rare condition that is caused by administration of recombinant erythropoietin. There are numerous assay platforms for detect EPO anti-drug antibody (ADA), and most have appropriate assay sensitivity, but in need of improvement in terms of assay turnaround time and user accessibility. Here, the new method was developed based on lab-on-a-chip technology and bridging ELISA. The FREND™ Cartridge is equipped with a microfluidic lateral flow channel, enabling easy, fast and accurate immunoassays with small sample volumes. Biotinylated EPO was immobilized on the avidin-coated solid phase of the test zone in the FREND™ cartridge. Initially, ADA in the serum sample binds to the detector conjugate (EPO-HRP-anti HRP antibody-FL bead) in the conjugation zone, and it flows into the test zone prepared with capture complex (avidin-biotinylated EPO). Unbound detector complexes are captured in the reference zone. The FREND™ system detects and quantifies the fluorescence signals in each zone and then calculates the concentration of EPO ADA in the sample. The FREND™ EPO ADA kit may be useful in local clinics as a rapid method for monitoring patients administered recombinant erythropoietin. Copyright © 2018 International Alliance for Biological Standardization. Published by Elsevier Ltd. All rights reserved.

Progressive magmatism and evolution of the Variscan suture in southern Iberia

NASA Astrophysics Data System (ADS)

Braid, James A.; Murphy, J. Brendan; Quesada, Cecilio; Gladney, Evan R.; Dupuis, Nicolle

2018-04-01

Magmatic activity is an integral component of orogenic processes, from arc magmatism during convergence to post-collisional crustal melting. Southern Iberia exposes a Late Paleozoic suture zone within Pangea and where a crustal fragment of Laurussia (South Portuguese Zone) is juxtaposed with parautochthonous Gondwana (Ossa Morena Zone). Fault-bounded oceanic metasedimentary rocks, mélanges and ophiolite complexes characterize the suture zone and are intruded by plutonic rocks and mafic dykes. The generation and emplacement of these intrusive rocks and their relationship to development of the suture zone and the orogen are undetermined. Field evidence combined with U/Pb (zircon) geochronology reveals three main phases of plutonism, a pre-collisional unfoliated gabbroic phase emplaced at ca 354 Ma, crosscut by a syn-tectonic ca 345 Ma foliated granodiorite phase followed by a ca 335 Ma granitic phase. Geochemical analyses (major, trace, rare earth elements) indicate that the gabbro exhibits a calc-alkaline arc signature whereas the granodiorite and granite are typical of post-collisional slab break-off. Taken together, these data demonstrate a protracted development of the orogen and support a complex late stage evolution broadly similar to the tectonics of the modern eastern Mediterranean. In this scenario, the highly oblique closure of a small tract of oceanic lithosphere postdates the main collision event resulting in escape of parautochthonous and allochthonous terranes toward the re-entrant.

An Isotopic view of water and nitrogen transport through the ...

EPA Pesticide Factsheets

Groundwater nitrate contamination affects thousands of households in Oregon’s southern Willamette Valley and many more across the Pacific Northwest. The southern Willamette Valley Groundwater Management Area (SWV GWMA) was established in 2004 due to nitrate levels in the groundwater exceeding the human health standard of 10 mg nitrate-N L-1. Much of the nitrogen inputs to the GWMA comes from agricultural nitrogen use, and thus efforts to reduce N inputs to groundwater are focused upon improving N management. However, the effectiveness of these improvements on groundwater quality is unclear because of the complexity of nutrient transport through the vadose zone and long groundwater residence times. Our objective was to focus on vadose zone transport and understand the dynamics and timing of N and water movement below the rooting zone in relation to N management and water inputs. Stable isotopes are a powerful tool for tracking water movement, and understanding nitrogen transformations within the vadose zone. In partnership with local farmers, and state agencies, we established lysimeters and groundwater wells in multiple agricultural fields in the GWMA, and have monitored nitrate, nitrate isotopes, and water isotopes weekly for multiple years. Our results indicate that vadose zone transport is highly complex, and the residence time of water collected in lysimeters was much longer than expected. While input precipitation water isotopes were highly variab

An Isotopic view of water and nitrogen transport through the ...

EPA Pesticide Factsheets

Background/Question/MethodsGroundwater nitrate contamination affects thousands of households in Oregon's southern Willamette Valley and many more across the Pacific Northwest. The southern Willamette Valley Groundwater Management Area (SWV GWMA) was established in 2004 due to nitrate levels in the groundwater exceeding the human health standard of 10 mg nitrate-N L-1. Much of the nitrogen inputs to the GWMA comes from agricultural nitrogen use, and thus efforts to reduce N inputs to groundwater are focused upon improving N management. However, the effectiveness of these improvements on groundwater quality is unclear because of the complexity of nutrient transport through the vadose zone and long groundwater residence times. Our objective was to focus on vadose zone transport and understand the dynamics and timing of N and water movement below the rooting zone in relation to N management and water inputs. Stable isotopes are a powerful tool for tracking water movement, and understanding nitrogen transformations within the vadose zone. In partnership with local farmers, and state agencies, we established lysimeters and groundwater wells in multiple agricultural fields in the GWMA, and have monitored nitrate, nitrate isotopes, and water isotopes weekly for multiple years Results/ConclusionsOur results indicate that vadose zone transport is highly complex, and the residence time of water collected in lysimeters was much longer than expected. While input precipitatio

Kinematics of the 2015 San Ramon, California earthquake swarm: Implications for fault zone structure and driving mechanisms

NASA Astrophysics Data System (ADS)

Xue, Lian; Bürgmann, Roland; Shelly, David R.; Johnson, Christopher W.; Taira, Taka'aki

2018-05-01

Earthquake swarms represent a sudden increase in seismicity that may indicate a heterogeneous fault-zone, the involvement of crustal fluids and/or slow fault slip. Swarms sometimes precede major earthquake ruptures. An earthquake swarm occurred in October 2015 near San Ramon, California in an extensional right step-over region between the northern Calaveras Fault and the Concord-Mt. Diablo fault zone, which has hosted ten major swarms since 1970. The 2015 San Ramon swarm is examined here from 11 October through 18 November using template matching analysis. The relocated seismicity catalog contains ∼4000 events with magnitudes between - 0.2

[Structure of newly formed capillaries of the rabbit cornea (electron microscopic study)].

PubMed

Gurina, O Iu; Karaganov, Ia L

1984-08-01

Owing to a complex application of topical analysis and tracer technique, it is possible to carry out a light optic and electron microscopic investigation of newly formed capillaries growing in the rabbit cornea after its chemical burn. The ultrastructural analysis demonstrates certain polymorphism of morphological organization of endotheliocyte in the newly formed capillaries. There is a rather elevated amount of free ribosomes, mitochondria, microtubules and microfilaments in cytoplasm. The granular endoplasmic reticulum and Golgi complex are hypertrophied. Weibel--Palade bodies appear. Taking into account certain morpho-functional peculiarities of endothelial cells along the course of the growing capillaries, on the 8th day of growth three zone are distinguished: 1--area of nondifferentiated endothelium (apex of the capillary), 2--transitional zone, 3--zone of relatively differentiated endothelium situating in the place where the capillary gets off the parental vessel. According to the zones distinguished, the ways of trans-endothelial transport of molecules are investigated. In formation of the capillary barrier-transport function an important role belongs to polymorphism of the endothelial cells along the course of the growing capillary which is determined by differentiation degree of these cells depending on their participation in permeability.

The Influence of Heating Mains on Yeast Communities in Urban Soils

NASA Astrophysics Data System (ADS)

Tepeeva, A. N.; Glushakova, A. M.; Kachalkin, A. V.

2018-04-01

The number and species diversity of yeasts in urban soils (urbanozems) affected by heating mains and in epiphytic yeast complexes of grasses growing above them were studied. The number of yeasts in the soil reached 103-104 CFU/g; on the plants, 107 CFU/g. Significant (by an order of magnitude) increase in the total number of soil yeasts in the zone of heating mains in comparison with the surrounding soil was found in winter period. Overall, 25 species of yeasts were isolated in our study. Yeast community of studied urbanozems was dominated by the Candida sake, an eurybiont of the temperate zone and other natural ecotopes with relatively low temperatures, but its share was minimal in the zone of heating mains. In general, the structure of soil and epiphytic yeast complexes in the zones of heating mains differed from that in the surrounding area by higher species diversity and a lower share of pigmented species among the epiphytic yeasts. The study demonstrated that the number and species structure of soil yeast communities in urban soils change significantly under the influence of the temperature factor and acquire a mosaic distribution pattern.

Mineral chemistry of isotropic gabbros from the Manamedu Ophiolite Complex, Cauvery Suture Zone, southern India: Evidence for neoproterozoic suprasubduction zone tectonics

NASA Astrophysics Data System (ADS)

Yellappa, T.; Tsunogae, T.; Chetty, T. R. K.; Santosh, M.

2016-11-01

The dismembered units of the Neoproterozoic Manamedu Ophiolite Complex (MOC) in the Cauvery Suture Zone, southern India comprises a well preserved ophiolitic sequence of ultramafic cumulates of altered dunites, pyroxenites, mafic cumulates of gabbros, gabbro-norites and anorthosites in association with plagiogranites, isotropic gabbros, metadolerites, metabasalts/amphibolites and thin layers of ferruginous chert bands. The isotropic gabbros occur as intrusions in association with gabbroic anorthosites, plagiogranite and metabasalts/amphibolites. The gabbros are medium to fine grained with euhedral to subhedral orthopyroxenes, clinopyroxenes and subhedral plagioclase, together with rare amphiboles. Mineral chemistry of isotropic gabbros reveal that the clinopyroxenes are diopsidic to augitic in composition within the compositional ranges of En(42-59), Fs(5-12), Wo(31-50). They are Ca-rich and Na poor (Na2O < 0.77 wt%) characterized by high-Mg (Mg# 79-86) and low-Ti (TiO2 < 0.35 wt%) contents. The tectonic discrimination plots of clinopyroxene data indicate island arc signature of the source magma. Our study further confirms the suprasubduction zone origin of the Manamedu ophiolitic suite, associated with the subduction-collision history of the Neoproterozoic Mozambique ocean during the assembly of Gondwana supercontinent.

The lateral boundary of a metamorphic core complex: The Moutsounas shear zone on Naxos, Cyclades, Greece☆

PubMed Central

Cao, Shuyun; Neubauer, Franz; Bernroider, Manfred; Liu, Junlai

2013-01-01

We describe the structure, microstructures, texture and paleopiezometry of quartz-rich phyllites and marbles along N-trending Moutsounas shear zone at the eastern margin of the Naxos metamorphic core complex (MCC). Fabrics consistently indicate a top-to-the-NNE non-coaxial shear and formed during the main stage of updoming and exhumation between ca. 14 and 11 Ma of the Naxos MCC. The main stage of exhumation postdates the deposition of overlying Miocene sedimentary successions and predates the overlying Upper Miocene/Pliocene conglomerates. Detailed microstructural and textural analysis reveals that the movement along the Moutsounas shear zone is associated with a retrograde greenschist to subgreenschist facies overprint of the early higher-temperature rocks. Paleopiezometry on recrystallized quartz and calcite yields differential stresses of 20–77 MPa and a strain rate of 10−15–10−13 s−1 at 350 °C for quartz and ca. 300 °C for calcite. Chlorite geothermometry of the shear zone yields two temperature regimes, 300–360 °C, and 200–250 °C. The lower temperature group is interpreted to result from late-stage hydrothermal overprint. PMID:26523079

Structure-property relations and crack resistance at the bovine dentin-enamel junction.

PubMed

Lin, C P; Douglas, W H

1994-05-01

The present report is a study of the fracture behavior of the dentin-enamel complex, involving enamel, dentin, and the dentin-enamel junction (DEJ), that combines experimental design, computational finite element analysis, and fractography. Seven chevron-notched short-bar bovine DEJ specimens were utilized in this study. The general plane of the DEJ was approximately perpendicular to the fracture plane. All specimens were stored at 37 degrees C and 100% relative humidity for 24 h prior to being tested. A fracture test set-up was designed for application of tensile load on the DEJ specimens to initiate a crack at the vertex of the chevron in the enamel, across the DEJ zone and into the bulk dentin. During fracture testing, a water chamber was used to avoid dehydration of the specimen. The results showed that the lower boundary value of the fracture toughness of the DEJ perpendicular to its own plane was 3.38 +/- 0.40 MN/m1.5 and 988.42 +/- 231.39 J/m2, in terms of KIC and GKC, respectively. In addition, there was an extensive plastic deformation (83 +/- 12%) collateral to the fracture process at the DEJ zone. The fractography revealed that the deviation of the crak path involved an area which was approximately 50-100 microns deep. The parallel-oriented coarse collagen bundles with diameters of 1-5 microns at the DEJ zone may play a significant role in resisting the enamel crack. This reflects the fact, that in the intact tooth, the multiple full thickness cracks commonly found in enamel do not typically cause total failure of the tooth by crack extension into the dentin.

Hydrogeochemical processes and isotopes analysis. Study case: "La Línea Tunnel", Colombia

NASA Astrophysics Data System (ADS)

Piña, Adriana; Donado, Leonardo; Cramer, Thomas

2017-04-01

Hydrogeochemical and stable isotopes analyses have been widely used to identify recharge and discharge zones, flowpaths, type, origin and age of water, chemical processes between minerals and groundwater as well as effects caused by anthropogenic or natural pollution. In this paper we analyze the interactions between groundwater and surface water using as laboratory the tunnels located at the La Línea Massif in the Cordillera Central of the Colombian Andes. The massif is formed by two igneous-metamorphic fractured complexes (Cajamarca and Quebradagrande group) plus andesithic porphyry rocks from the tertiary period. There, eight main fault zones related to surface creeks were identified and main inflows inside the tunnels were reported. 60 water samples were collected in surface and inside the tunnel in fault zones in two different years, 2010 and 2015. To classify water samples, a multivariate statistical analysis combining Factor Analysis (FA) with Hierarchical Cluster Analysis (HCA) was performed. Then, analyses of the major chemical elements and water isotopes (18O, 2H and 3H) were used to define the origin of dissolved components and to analyse the evolution in time. Most samples were classified as bicarbonate calcite water or bicarbonate magnesium water type. Isotopic analyses show a characteristic behavior for east and west watershed and each geologic group. According to the FA and HCA, obtained factors and clusters are first related to the location of the samples (surface or tunnel samples) followed by the geology. Surface samples behave according to the Colombian meteoric line as inflows related to permeable faults while less permeable faults show hydrothermal processes. Finally, water evolution in time shows a decrease of pH, conductivity and Mg2+ related to silicate weathering or precipitation/dissolution processes that affect the spacing in fractures and consequently, the hydraulic properties.

The Behavior of the Ru-bda Water Oxidation Catalysts at Low Oxidation States.

PubMed

Matheu, Roc; Ghaderian, Abolfazl; Francas, Laia; Chernev, Petko; Ertem, Mehmed; Benet-Buchholz, Jordi; Batista, Victor; Haumann, Michael; Gimbert-Suriñach, Carolina; Sala, Xavier; Llobet, Antoni

2018-06-13

The Ru complex [RuII(bda-κ-N2O2)(N-NH2)2], 1, (bda2- = (2,2'-bipyridine)-6,6'-dicarboxylate; N-NH2 = 4-(pyridin-4-yl)aniline) is used as a synthetic intermediate to prepare Ru-bda complexes that contain the NO+, acetonitrile (MeCN) or H2O ligands at oxidation states II and III. Complex 1 reacts with excess NO+ to form a Ru complex where the aryl amine ligands N-NH2 in 1 are transformed into diazonium salts (N-N2+ = 4-(pyridin-4-yl)benzenediazonium)) together with the formation of a new Ru-NO group at the equatorial zone, to generate [RuII(bda-κ-N2O)(NO)(N-N2)2]3+, 23+. Similarly, complex 1 can also react with a coordinating solvent, such as MeCN, at room temperature leading to complex [RuII(bda-κ-N2O)(MeCN)(N-NH2)2], 3. Finally in acidic aqueous solutions solvent water coordinates the Ru center forming {[RuII(bda-κ-(NO)3)(H2O)(N-NH3)2](H2O)n}2+, 42+, that is strongly hydrogen bonded with additional water molecules at the second coordination sphere. We have additionally characterized the one electron oxidized complex {[RuIII(bda-κ-(NO)3.5)(H2O)(N-NH3)2](H2O)n}3+, 53+. The coordination mode of the complexes has been studied both in the solid state and in solution through single-crystal XRD, X-ray absorption spectroscopy, variable-temperature NMR and DFT calculations. While the κ-N2O is the main coordination mode for 23+ and 3, an equilibrium that involves isomers with κ-N2O and κ-NO2 coordination modes and neighboring hydrogen bonded water molecules is observed for 42+ and 53+. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Behaviorally Mediated, Warm Adaptation: A Physiological Strategy When Mice Are Allowed to Behaviorally Thermoregulate

EPA Science Inventory

Laboratory mice housed under standard vivarium conditions with an ambient temperature (Ta) of -22°C are likely to be cold stressed because this Ta is below their thermoneutral zone (TNZ). Mice raised at Tas within the TNZ adapt to the warmer temperatures, developing smaller int...