High strain rate behavior of a SiC particulate reinforced Al{sub 2}O{sub 3} ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hall, I.W.; Guden, M.

The high strain rate deformation behavior of composite materials is important for several reasons. First, knowledge of the mechanical properties of composites at high strain rates is needed for designing with these materials in applications where sudden changes in loading rates are likely to occur. Second, knowledge of both the dynamic and quasi-static mechanical responses can be used to establish the constitutive equations which are necessary to increase the confidence limits of these materials, particularly if they are to be used in critical structural applications. Moreover, dynamic studies and the knowledge gained form them are essential for the further developmentmore » of new material systems for impact applications. In this study, the high strain rate compressive deformation behavior of a ceramic matrix composite (CMC) consisting of SiC particles and an Al{sub 2}O{sub 3} matrix was studied and compared with its quasi-static behavior. Microscopic observations were conducted to investigate the deformation and fracture mechanism of the composite.« less

Flexural behavior of the fibrous cementitious composites (FCC) containing hybrid fibres

NASA Astrophysics Data System (ADS)

Ramli, Mahyuddin; Ban, Cheah Chee; Samsudin, Muhamad Fadli

2018-02-01

In this study, the flexural behavior of the fibrous cementitious composites containing hybrid fibers was investigated. Waste materials or by product materials such as pulverized fuel ash (PFA) and ground granulated blast-furnace slag (GGBS) was used as supplementary cement replacement. In addition, barchip and kenaf fiber will be used as additional materials for enhance the flexural behavior of cementitious composites. A seven mix design of fibrous cementitious composites containing hybrid fiber mortar were fabricated with PFA-GGBS as cement replacement at 50% with hybridization of barchip and kenaf fiber between 0.5% and 2.0% by total volume weight. The FCC with hybrid fibers mortar will be fabricated by using 50 × 50 × 50 mm, 40 × 40 × 160 mm and 350 × 125 × 30 mm steel mold for assessment of mechanical performances and flexural behavior characteristics. The flexural behavior and mechanical performance of the PFA-GGBS with hybrid fiber mortar block was assessed in terms of load deflection response, stress-strain response, crack development, compressive and flexural strength after water curing for 28 days. Moreover, the specimen HBK 1 and HBK 2 was observed equivalent or better in mechanical performance and flexural behavior as compared to control mortar.

Investigations into the mechanical and physical behavior of thermoplastic elastomers

NASA Astrophysics Data System (ADS)

Wright, Kathryn Janelle

This thesis describes investigations into the physical and mechanical characteristics of two commercial thermoplastic elastomer (TPE) systems. Both systems studied exhibit elastomeric behavior similar to more traditional crosslinked elastomers; however, in these TPEs non-conventional polymer architectures and morphologies are used to produce their elastomeric behavior. The two TPEs of interest are ethylene-propylene random copolymers and dynamically vulcanized blends of ethylene-propylene-diene monomer (EPDM) and isotactic polypropylene (iPP). Very few studies have examined the mechanical behavior of these materials in terms of their composition and morphology. As such, the primary goal of this research is to both qualitatively and quantitatively understand the influence of composition and morphology on mechanical behavior. In additional very little information is available that compares their performance with that of crosslinked elastomers. As a result, the secondary goal is to qualitatively compare the mechanical responses of these TPEs with that of their more traditional counterparts. The ethylene-propylene copolymers studied have very high comonomer contents and exhibit slow crystallization kinetics. Their morphology consists of nanoscale crystallites embedded in an amorphous rubbery matrix. These crystallites act as physical crosslinks that allow for elasticity. Slow crystallization causes subsequent changes in mechanical behavior that take place over days and even weeks. Physical responses (e.g., density, crystallization kinetics, and crystal structure) of five copolymer compositions are investigated. Mechanical responses (e.g., stiffness, ductility, yielding, and reversibility) are also examined. Finally, the influence of morphology on deformation is studied using in situ analytical techniques. The EPDM/iPP blends are dynamically vulcanized which produces a complex morphology consisting of chemically crosslinked EPDM domains embedded within a semicrystalline iPP matrix. Six compositions are investigated as a function of three parameters: major volume fraction, iPP molecular weight, and EPDM cure state. The influence of these parameters on morphology and resulting mechanical behavior is examined. This work culminates in the development of a morphological model to describe the steady-state reversibility of these EPDM/iPP blends. The model is then evaluated in terms of composition and cure state.

Influence of the forming process on the mechanical behavior of a commingled carbon PPS composite part

NASA Astrophysics Data System (ADS)

Patou, J.; De Luycker, E.; Bonnaire, R.; Cutard, T.; Bernhart, G.

2018-05-01

In this research work, the influence of the forming process on commingled thermoplastic composite parts mechanical behavior was investigated. The aim of this work is to evaluate the influence of fabric shearing on the mechanical response of composite laminate. Different sheets with a given shear angle are manufactured. Tensile experimental results are compared with the properties obtained from a simple model based on the laminate plate theory for various off angles. Later, the link with a tetrahedron shape 3D part manufactured by punch deep drawing will be made.

The Effect of Various Weave Designs on Mechanical Behavior of Lamina Intraply Composite Made from Kenaf Fiber Yarn

NASA Astrophysics Data System (ADS)

Yuhazri, M. Y.; Amirhafizan, M. H.; Abdullah, A.; Sihombing, H.; Saarah, A. B.; Fadzol, O. M.

2016-11-01

The development of lamina intraply composite is a novel approach that can be adopted to address the challenges of balance mechanical properties of polymer composite. This research will focuses on the effects of weave designs on the mechanical behavior of a single ply or also known as lamina intraply composite. The six (6) specimens of lamina intraply composites were made by kenaf fiber as a reinforcement and unsaturated polyester resin as a matrix in various weave designs which were plain, twill, satin, basket, mock leno and leno weave. The vacuum infusion technique was adopted due to advantages over hand lay-up. It was found that the plain, twill and satin weave exhibited better mechanical properties on tensile strength. The fiber content of the specimen was 40% and the result of the resin content of the specimen was 60% due to the higher permeability of natural fiber.

The Effect of Keystone Individuals on Collective Outcomes Can Be Mediated through Interactions or Behavioral Persistence

PubMed Central

Pinter-Wollman, Noa; Keiser, Carl N.; Wollman, Roy; Pruitt, Jonathan N.

2017-01-01

Collective behavior emerges from interactions among group members who often vary in their behavior. The presence of just one or a few keystone individuals, such as leaders or tutors, may have a large effect on collective outcomes. These individuals can catalyze behavioral changes in other group members, thus altering group composition and collective behavior. The influence of keystone individuals on group function may lead to trade-offs between ecological situations, because the behavioral composition they facilitate may be suitable in one situation but not another. We use computer simulations to examine various mechanisms that allow keystone individuals to exert their influence on group members. We further discuss a trade-off between two potentially conflicting collective outcomes, cooperative prey attack and disease dynamics. Our simulations match empirical data from a social spider system and produce testable predictions for the causes and consequences of the influence of keystone individuals on group composition and collective outcomes. We find that a group’s behavioral composition can be impacted by the keystone individual through changes to interaction patterns or behavioral persistence over time. Group behavioral composition and the mechanisms that drive the distribution of phenotypes influence collective outcomes and lead to trade-offs between disease dynamics and cooperative prey attack. PMID:27420788

The Mechanical Properties and Modeling of Creep Behavior of UHMWPE/Nano-HA Composites

NASA Astrophysics Data System (ADS)

Li, Fan; Gao, Lilan; Gao, Hong; Cui, Yun

2017-09-01

Composites with different levels of hydroxyapatite (HA) content and ultra-high molecular weight polyethylene (UHMWPE) were prepared in this work. Mechanical properties of the composites were examined here, and to evaluate the effect of HA particles on the time-dependent behavior of the pure matrix, the creep and recovery performance of composites at various stress levels were also researched. As expected, the addition of HA influenced the time-dependent response of the UHMWPE and the effect had a strong dependence on the HA content. The creep and recovery strain of the composites significantly decreased with increasing HA content, and tensile properties were also impaired, which was due to the concentration of HA fillers. The mechanism and effect of HA dispersed into the UHMWPE matrix were examined by scanning electron microscopy. Additionally, since variations in the adjusted parameters revealed the impact of HA on the creep behavior of the UHMWPE matrix, Findley's model was employed. The results indicated that the analytical model was accurate for the prediction of creep of the pure matrix and its composites.

Metal matrix composite micromechanics: In-situ behavior influence on composite properties

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Hopkins, D. A.; Chamis, C. C.

1989-01-01

Recent efforts in computational mechanics methods for simulating the nonlinear behavior of metal matrix composites have culminated in the implementation of the Metal Matrix Composite Analyzer (METCAN) computer code. In METCAN material nonlinearity is treated at the constituent (fiber, matrix, and interphase) level where the current material model describes a time-temperature-stress dependency of the constituent properties in a material behavior space. The composite properties are synthesized from the constituent instantaneous properties by virtue of composite micromechanics and macromechanics models. The behavior of metal matrix composites depends on fabrication process variables, in situ fiber and matrix properties, bonding between the fiber and matrix, and/or the properties of an interphase between the fiber and matrix. Specifically, the influence of in situ matrix strength and the interphase degradation on the unidirectional composite stress-strain behavior is examined. These types of studies provide insight into micromechanical behavior that may be helpful in resolving discrepancies between experimentally observed composite behavior and predicted response.

The monitoring and fatigue behavior of CFCCs at ambient temperature and 1000{degrees}C

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miriyala, N.; Liaw, P.K.; McHargue, C.J.

1997-04-01

Metallographically polished flexure bars of Nicalon/SiC and Nicalon/alumina composites were subjected to monotonic and cycle-fatigue loadings, with loading either parallel or normal to the fabric plies. The fabric orientation did not significantly affect the mechanical behavior of the Nicalon/SiC composite at ambient temperature. However, the mechanical behavior of the Nicalon/alumina composite was significantly affected by the fabric orientation at ambient temperature in air and at 1000{degrees}C in argon atmosphere. In addition, there was a significant degradation in the fatigue performance of the alumina matrix composite at the elevated temperature, owing to creep in the material and degradation in the fibermore » strength.« less

ICCM/2; Proceedings of the Second International Conference on Composite Materials, Toronto, Canada, April 16-20, 1978

NASA Technical Reports Server (NTRS)

Noton, B. R. (Editor); Signorelli, R. A.; Street, K. N.; Phillips, L. N.

1978-01-01

Composite materials are discussed with reference to their mechanical and physical properties, fatigue and fracture testing and analysis, nondestructive evaluation, fabrication, and commercial applications. Particular papers are presented on such topics as analysis of mechanical strength data from hybrid laminates of glass and graphite fibers, graphite-aluminum composites, the mechanical behavior of molybdenum-reinforced metal composites, and composite laminate application in magnetic fusion energy superconducting magnet systems.

SiC Fiber-Reinforced Celsian Composites

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.

2003-01-01

Celsian is a promising matrix material for fiber-reinforced composites for high temperature structural applications. Processing and fabrication of small diameter multifilament silicon carbide tow reinforced celsian matrix composites are described. Mechanical and microstructural properties of these composites at ambient and elevated temperatures are presented. Effects of high-temperature exposures in air on the mechanical behavior of these composites are also given. The composites show mechanical integrity up to 1100 C but degrade at higher temperatures in oxidizing atmospheres. A model has been proposed for the degradation of these composites in oxidizing atmospheres at high temperatures.

Fatigue behavior of a cross-ply ceramic matrix composite at elevated temperature under tension-tension loading. Master`s thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steiner, C.D.

This study investigated the fatigue behavior and damage mechanisms of a (0/90)4s SiC/MAS ceramic matrix composite under tension-tension loading at two elevated temperatures and two frequencies. Stress and strain hystereses, maximum and minimum strain, and modulus of elasticity were evaluated to characterize the material behavior. Microscopy and fractography were used to evaluate damage progression and mechanisms. Fatigue life was independent of frequency at both temperatures.

The mechanics of delamination in fiber-reinforced composite materials. Part 2: Delamination behavior and fracture mechanics parameters

NASA Technical Reports Server (NTRS)

Wang, S. S.; Choi, I.

1983-01-01

Based on theories of laminate anisotropic elasticity and interlaminar fracture, the complete solution structure associated with a composite delamination is determined. Fracture mechanics parameters characterizing the interlaminar crack behavior are defined from asymptotic stress solutions for delaminations with different crack-tip deformation configurations. A numerical method employing singular finite elements is developed to study delaminations in fiber composites with any arbitrary combinations of lamination, material, geometric, and crack variables. The special finite elements include the exact delamination stress singularity in its formulation. The method is shown to be computationally accurate and efficient, and operationally simple. To illustrate the basic nature of composite delamination, solutions are shown for edge-delaminated (0/-0/-0/0) and (+ or - 0/+ or - 0/90/90 deg) graphite-epoxy systems under uniform axial extenstion. Three-dimensional crack-tip stress intensity factors, associated energy release rates, and delamination crack-closure are determined for each individual case. The basic mechanics and mechanisms of composite delamination are studied, and fundamental characteristics unique to recently proposed tests for interlaminar fracture toughness of fiber composite laminates are examined.

Mechanical energy dissipation in natural ceramic composites.

PubMed

Mayer, George

2017-12-01

Ceramics and glasses, in their monolithic forms, typically exhibit low fracture toughness values, but rigid natural marine ceramic and glass composites have shown remarkable resistance to mechanical failure. This has been observed in load-extension behavior by recognizing that the total area under the curve, notably the part beyond the yield point, often conveys substantial capacity to carry mechanical load. The mechanisms underlying the latter observations are proposed as defining factors for toughness that provide resistance to failure, or capability to dissipate energy, rather than fracture toughness. Such behavior is exhibited in the spicules of glass sponges and in mollusk shells. There are a number of similarities in the manner in which energy dissipation takes place in both sponges and mollusks. It was observed that crack diversion, a new form of crack bridging, creation of new surface area, and other important energy-dissipating mechanisms occur and aid in "toughening". Crack tolerance, key to energy dissipation in these natural composite materials, is assisted by promoting energy distribution over large volumes of loaded specimens by minor components of organic constituents that also serve important roles as adhesives. Viscoelastic deformation was a notable characteristic of the organic component. Some of these energy-dissipating modes and characteristics were found to be quite different from the toughening mechanisms that are utilized for more conventional structural composites. Complementary to those mechanisms found in rigid natural ceramic/organic composites, layered architectures and very thin organic layers played major roles in energy dissipation in these structures. It has been demonstrated in rigid natural marine composites that not only architecture, but also the mechanical behavior of the individual constituents, the nature of the interfaces, and interfacial bonding play important roles in energy dissipation. Additionally, the controlling effects of thin organic layers have been observed in other natural ceramic composite structures, such as teeth and bones, indicating that a variety of similar energy dissipating mechanisms in natural ceramic composites may operate as means to resist failure. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mechanical characterization and modeling of non-linear deformation and fracture of a fiber reinforced metal matrix composite

NASA Technical Reports Server (NTRS)

Jansson, S.

1991-01-01

The nonlinear anisotropic mechanical behavior of an aluminum alloy metal matrix composite reinforced with continuous alumina fibers was determined experimentally. The mechanical behavior of the composite were modeled by assuming that the composite has a periodical microstructure. The resulting unit cell problem was solved with the finite element method. Excellent agreement was found between theoretically predicted and measured stress-strain responses for various tensile and shear loadings. The stress-strain responses for transverse and inplane shear were found to be identical and this will provide a simplification of the constitutive equations for the composite. The composite has a very low ductility in transverse tension and a limited ductility in transverse shear that was correlated to high hydrostatic stresses that develop in the matrix. The shape of the initial yield surface was calculated and good agreement was found between the calculated shape and the experimentally determined shape.

The mechanisms of plastic strain accommodation and post critical behavior of heterogeneous reactive composites subject to dynamic loading

NASA Astrophysics Data System (ADS)

Olney, Karl L.

The dynamic behavior of granular/porous and laminate reactive materials is of interest due to their practical applications; reactive structural components, reactive fragments, etc. The mesostructural properties control meso- and macro-scale dynamic behavior of these heterogeneous composites including the behavior during the post-critical stage of deformation. They heavily influence mechanisms of fragment generation and the in situ development of local hot spots, which act as sites of ignition in these materials. This dissertation concentrates on understanding the mechanisms of plastic strain accommodation in two representative reactive material systems with different heterogeneous mesostructrues: Aluminum-Tungsten granular/porous and Nickel-Aluminum laminate composites. The main focus is on the interpretation of results of the following dynamic experiments conducted at different strain and strain rates: drop weight tests, explosively expanded ring experiments, and explosively collapsed thick walled cylinder experiments. Due to the natural limitations in the evaluation of the mesoscale behavior of these materials experimentally and the large variation in the size scales between the mesostructural level and the sample, it is extremely difficult, if not impossible, to examine the mesoscale behavior in situ. Therefore, numerical simulations of the corresponding experiments are used as the main tool to explore material behavior at the mesoscale. Numerical models were developed to elucidate the mechanisms of plastic strain accommodation and post critical behavior in these heterogeneous composites subjected to dynamic loading. These simulations were able to reproduce the qualitative and quantitative features that were observable in the experiments and provided insight into the evolution of the mechanisms of plastic strain accommodation and post critical behavior in these materials with complex mesotructure. Additionally, these simulations provided a framework to examine the influence of various mesoscale properties such as the bonding of interfaces, the role of material properties, and the influence of mesoscale geometry. The results of this research are helpful in the design of material mesotructures conducive to the desirable behavior under dynamic loading.

Mechanical Behavior of Dowel-Type Joints Made of Wood Scrimber Composite

PubMed Central

He, Minjuan; Tao, Duo; Li, Zheng; Li, Maolin

2016-01-01

As a renewable building material with low embodied energy characteristics, wood has gained more and more attention in the green and sustainable building industry. In terms of material resource and physical properties, scrimber composite not only makes full use of fast-growing wood species, but also has better mechanical performance and less inherent variability than natural wood material. In this study, the mechanical behavior of bolted beam-to-column joints built with a kind of scrimber composite was investigated both experimentally and numerically. Two groups of specimens were tested under monotonic and low frequency cyclic loading protocols. The experimental results showed that the bolted joints built with scrimber composite performed well in initial stiffness, ductility, and energy dissipation. A three-dimensional (3D) non-linear finite element model (FEM) for the bolted beam-to-column joints was then developed and validated by experimental results. The validated model was further used to investigate the failure mechanism of the bolted joints through stress analysis. This study can contribute to the application of the proposed scrimber composite in structural engineering, and the developed FEM can serve as a useful tool to evaluate the mechanical behavior of such bolted beam-to-column joints with different configurations in future research. PMID:28773703

Mechanical Behavior of Dowel-Type Joints Made of Wood Scrimber Composite.

PubMed

He, Minjuan; Tao, Duo; Li, Zheng; Li, Maolin

2016-07-15

As a renewable building material with low embodied energy characteristics, wood has gained more and more attention in the green and sustainable building industry. In terms of material resource and physical properties, scrimber composite not only makes full use of fast-growing wood species, but also has better mechanical performance and less inherent variability than natural wood material. In this study, the mechanical behavior of bolted beam-to-column joints built with a kind of scrimber composite was investigated both experimentally and numerically. Two groups of specimens were tested under monotonic and low frequency cyclic loading protocols. The experimental results showed that the bolted joints built with scrimber composite performed well in initial stiffness, ductility, and energy dissipation. A three-dimensional (3D) non-linear finite element model (FEM) for the bolted beam-to-column joints was then developed and validated by experimental results. The validated model was further used to investigate the failure mechanism of the bolted joints through stress analysis. This study can contribute to the application of the proposed scrimber composite in structural engineering, and the developed FEM can serve as a useful tool to evaluate the mechanical behavior of such bolted beam-to-column joints with different configurations in future research.

Mechanical properties and crystallization behavior of hydroxyapatite/poly(butylenes succinate) composites.

PubMed

Guo, Wenmin; Zhang, Yihe; Zhang, Wei

2013-09-01

Biodegradable synthetic polymers have attracted much attention nowadays, and more and more researches have been done on biodegradable polymers due to their excellent mechanical properties, biocompatibility, and biodegradability. In this work, hydroxyapatite (HA) particles were melt-mixing with poly (butylenes succinate) (PBS) to prepare the material, which could be used in the biomedical industry. To develop high-performance PBS for cryogenic engineering applications, it is necessary to investigate the cryogenic mechanical properties and crystallization behavior of HA/PBS composites. Cryogenic mechanical behaviors of the composites were studied in terms of tensile and impact strength at the glass transition temperature (-30°C) and compared to their corresponding behaviors at room temperature. With the increase of HA content, the crystallization of HA/PBS composites decreased and crystallization onset temperature shifted to a lower temperature. The diameter of spherulites increased at first and decreased with a further HA content. At the same time, the crystallization rate became slow when the HA content was no more than 15wt% and increased when HA content reached 20wt%. In all, the results we obtained demonstrate that HA/PBS composites reveal a better tensile strength at -30°C in contrast to the strength at room temperature. HA particles with different amount affect the crystallization of PBS in different ways. Copyright © 2013 Wiley Periodicals, Inc.

Assessment of mechanical behavior of PLA composites reinforced with Mg micro-particles through depth-sensing indentations analysis.

PubMed

Cifuentes, S C; Frutos, E; Benavente, R; Lorenzo, V; González-Carrasco, J L

2017-01-01

This work deals with the mechanical characterization by depth-sensing indentation (DSI) of PLLA and PLDA composites reinforced with micro-particles of Mg (up to 15wt%), which is a challenging task since the indented volume must provide information of the bulk composite, i.e. contain enough reinforcement particles. The composites were fabricated by combining hot extrusion and compression moulding. Physico-chemical characterization by TGA and DSC indicates that Mg anticipates the thermal degradation of the polymers but does not compromise their stability during processing. Especial emphasis is devoted to determine the effect of strain rate and Mg content on mechanical behavior, thus important information about the visco-elastic behavior and time-dependent response of the composites is obtained. Relevant for the intended application is that Mg addition increases the elastic modulus and hardness of the polymeric matrices and induces a higher resistance to flow. The elastic modulus obtained by DSI experiments shows good agreement with that obtained by uniaxial compression tests. The results indicate that DSI experiments are a reliable method to calculate the modulus of polymeric composites reinforced with micro-particles. Taking into consideration the mechanical properties results, PLA/Mg composite could be used as substitute for biodegradable monolithic polymeric implants already in the market for orthopedics (freeform meshes, mini plates, screws, pins, …), craniomaxillofacial, or spine. Copyright © 2016 Elsevier Ltd. All rights reserved.

High temperature deformation of Vitreloy bulk metallic glasses and their composite

NASA Astrophysics Data System (ADS)

Tao, Min

A complete understanding of the deformation mechanisms of BMGs and their composites requires investigation of the microstructural changes and their interplay with the mechanical behavior. In this dissertation, the deformation mechanisms of a series of Vitreloy glasses and their composites are experimentally investigated over a wide range of strain rates and temperatures, with focus on the supercooled liquid regime, by combining uniaxial mechanical testing with calorimetric and microscopic examinations. Various theories of deformation of metallic glasses and the composites are examined in light of the experimental data. A comparative structural relaxation study was performed on two closely related Vitreloy alloys, Zr41.2Ti13.8Cu12.5Ni 10Be22.5 (Vit 1) and Zr46.7Ti8.3Cu 7.5Ni10Be27.5 (Vit 4). Differential scanning calorimetric studies on the specimens deformed in compression at constant-strain-rate in supercooled liquid regime showed that mechanical loading accelerated the spinodal phase separation and nanocrystallization process in Vit 1, while the relaxation in Vit 4 featured local chemical composition fluctuation accompanied by annealing out of free volume. The effect of the structural relaxation on their mechanical behavior was further studied via single and multiple jump-in-strain-rate tests. The deformation and viscosity of a new Vitreloy alloy were characterized using uniaxial compression tests in its supercooled liquid regime. A new theoretical model named Cooperative Shear Model, which correlates the evolution of the macroscopic mechanical/thermal variables such as shear modulus and viscosity with the configurational energies of atom clusters in an amorphous alloy, was critically examined in this investigation. The model was successful in predicting the Newtonian and non-Newtonian viscosities of the material, as well as the shear moduli of the deformed specimens, in a self-consistent manner. The plastic flow of an in-situ metallic glass composite, beta-Vitreloy, was investigated under uniaxial compression in its supercooled liquid regime and at various strain rates (10-4 ˜ 10-1 s-1). The composite, with ˜ 25% volume fraction of crystalline beta-phase dendrites exhibited superplastic behavior similar to that of amorphous Vit 1. Significant strain hardening was observed when the material was deformed at high temperatures and low strain rates. A dual-phase composite model was employed in finite element simulations to understand the effect of the composite microstructure on its mechanical behavior.

Effect of Sericin on Mechanical Behavior of Composite Material Reinforced by Silk Woven Fabric

NASA Astrophysics Data System (ADS)

Kimura, Teruo; Ino, Haruhiro; Hanada, Koji; Katori, Sigetaka

Recent, attention has been given to shift from glass fibers and carbon fibers to natural fibers for FRP composites for the goal of protecting the environment. This paper concerned with the application of silk fabric for composite materials. Polypropylene (PP) was used for the matrix material and the silk fabric composites were molded using a compression molding method. Especially, the effect of sericin on mechanical behaviors of composite materials was discussed. Good adhesion between silk and PP was obtained by removing the sericin existing around the fibroin. The tensile modulus of composite decreased with decreasing the sericin because of the flexibility of silk fibers without sericin. In particular, the higher Izod impact value was obtained for the composites containing the silk fibers without sericin.

Characterization of fatigue behavior of 2-D woven fabric reinforced ceramic matrix composite at elevated temperature. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Groner, D.J.

This study investigated the fatigue behavior and associated damage mechanisms in notched and unnotched enhanced SiC/SiC ceramic matrix composite specimens at 1100 deg C. Stiffness degradation, strain variation, and hysteresis were evaluated to characterize material behavior. Microscopic examination was performed to characterize damage mechanisms. During high cycle/low stress fatigue tests, far less fiber/matrix interface debond was evident than in low cycle/high stress fatigue tests. Notched specimens exhibited minimal stress concentration during monotonic tensile testing and minimal notch sensitivity during fatigue testing. Damage mechanisms were also similar to unnotched.

Effect of Nb Content on Mechanical Behavior and Structural Properties of W/(Zr55Cu30Al10Ni5)100- x Nb x Composite

NASA Astrophysics Data System (ADS)

Mahmoodan, Morteza; Gholamipour, Reza; Mirdamadi, Shamseddin; Nategh, Said

2017-05-01

In the present study, (Zr55Cu30Al10Ni5)100- x Nb( x=0,1,2,3) bulk metallic glass matrix/tungsten wire composites were fabricated by infiltration process. Structural studies were investigated by scanning electron microscopy and X-ray diffraction method. Also, mechanical behaviors of the materials were analyzed using quasi-static compressive tests. Results indicated that the best mechanical properties i.e., 2105 MPa compressive ultimate strength and 28 pct plastic strain before failure, were achieved in the composite sample with X = 2. It was also found that adding Nb to the matrix modified interface structure in W fiber/(Zr55Cu30Al10Ni5)98Nb2 since the stable diffusion band formation acts as a functionally graded layer. Finally, the observation of multiple shear bands formation in the matrix could confirm the excellent plastic deformation behavior of the composite.

Delamination and debonding of materials

NASA Technical Reports Server (NTRS)

Johnson, W. S. (Editor)

1985-01-01

The general topics consist of stress analysis, mechanical behavior, and fractography/NDI of composite laminates. Papers are presented on a dynamic hybrid finite-element analysis for interfacial cracks in composites, energy release rate during delamination crack growth in composite laminates, matrix deformation and fracture in graphite-reinforced epoxies, and the role of delamination and damage development on the strength of thick notched laminates. In addition, consideration is given to a new ply model for interlaminar stress analysis, a fracture mechanics approach for designing adhesively bonded joints, the analysis of local delaminations and their influence on composite laminate behavior, and moisture and temperature effects on the mixed-mode delamination fracture of unidirectional graphite/epoxy.

Mechanical and time-dependent behavior of wood-plastic composites subjected to bending

Treesearch

S. E. Hamel; John Hermanson; S. M. Cramer

2015-01-01

The most popular use of wood–plastic composite (WPC) members in the United States has been as outdoor decking material in residential construction. If the use of these products expands into more structural applications, such as beams and joists, it is imperative that the material’s mechanical behavior be understood. Since most of the potential structural uses of this...

Mechanical and thermal behavior of ionic polymer metal composites: effects of electroded metals

NASA Astrophysics Data System (ADS)

Park, Il-Seok; Kim, Sang-Mun; Kim, Kwang J.

2007-08-01

In this study, we investigated the mechanical properties of various types of ionic polymer-metal composites (IPMCs) and Pt, Au, Pd, and Pt electroded ionic liquid (IL-Pt) IPMCs, by testing tensile modulus and dynamic mechanical behavior. The SEM was utilized to investigate the characteristics of the doped electroding layer, and the DSC was probed in order to look into the thermal behavior of various types of IPMCs. Au IPMCs, having a 5-7 µm-doped layer and nanosized Au particles (ca. 10 nm), showed the highest tensile strength (56 MPa) and modulus (602 MPa) in dried conditions. With regards to thermal behavior, Au IPMC had the highest Tg (153 °C) and Tm (263 °C) in both the DMA and DSC results. The fracture behavior of various types of IPMCs followed the behavior of the base material, Nafion™, which is represented as the semicrystalline polymer characteristic.

Electrical and mechanical behavior of polymethyl methacrylate/cadmium sulphide composites

NASA Astrophysics Data System (ADS)

Kaur, Rajdeep; Samra, Kawaljeet Singh

2018-06-01

In the present investigation, electrical and mechanical behavior of cadmium sulphide (CdS) doped polymethyl methacrylate (PMMA) have been studied using different techniques. Dip casting technique was used for preparing free standing films of pristine and CdS doped PMMA at different compositions (i.e. 1 and 5 wt%). Optical absorbance as a function of wavelength was studied, by UV-visible spectroscopy, to find the impact of CdS doping on the optical band gap of synthesized PMMA/CdS composite. DC and AC conductivities were measured as a function of dopant concentration and temperature. Considerable increase in electrical conductivity was observed with the increase of CdS contents in polymer matrix. Overall electrical conduction mechanism in PMMA/CdS composites was attributed to movement of electrons through the uniformly distributed CdS aggregates within the matrix of PMMA. Mechanical properties, such as Young's modulus, tensile strength, elongation and ductility, of PMMA/CdS composites were determined and relevant responsible phenomena were discussed.

Influence of Reinforcement Parameters and Ageing Time on Mechanical Behavior of Novel Al2024/SiC/Red Mud Composites Using Response Surface Methodology

NASA Astrophysics Data System (ADS)

Singh, Jaswinder; Chauhan, Amit

2017-12-01

This study investigates the mechanical behavior of aluminum 2024 matrix composites reinforced with silicon carbide and red mud particles. The hybrid reinforcements were successfully incorporated into the alloy matrix using the stir casting process. An orthogonal array based on Taguchi's technique was used to acquire experimental data for mechanical properties (hardness and impact energy) of the composites. The analysis of variance (ANOVA) and response surface methodology (RSM) techniques were used to evaluate the influence of test parameters (reinforcement ratio, particle size and ageing time). The morphological analysis of the surfaces (fractured during impact tests) was conducted to identify the failure mechanism. Finally, a confirmation experiment was performed to check the adequacy of the developed model. The results indicate that the ageing time is the most effective parameter as far as the hardness of the hybrid composites is concerned. It has also been revealed that red mud wt.% has maximum influence on the impact energy characteristics of the hybrid composites. The study concludes that Al2024/SiC/red mud hybrid composites possess superior mechanical performance in comparison to pure alloy under optimized conditions.

The mechanics of delamination in fiber-reinforced composite materials. II - The delamination behavior and fracture mechanics parameters

NASA Technical Reports Server (NTRS)

Wang, S. S.; Choi, I.

1983-01-01

Based on theories of laminate anisotropic elasticity and interlaminar fracture, the complete solution structure associated with a composite delamination is determined. Fracture mechanics parameters characterizing the interlaminar crack behavior are defined from asymptotic stress solutions for delaminations with different crack-tip deformation configurations. A numerical method employing singular finite elements is developed to study delaminations in fiber composites with any arbitrary combinations of lamination, material, geometric, and crack variables. The special finite elements include the exact delamination stress singularity in its formulation. The method is shown to be computationally accurate and efficient, and operationally simple. To illustrate the basic nature of composite delamination, solutions are shown for edge-delaminated (0/-0/-0/0) and (+ or - 0/+ or - 0/90/90 deg) graphite-epoxy systems under uniform axial extension. Three-dimensional crack-tip stress intensity factors, associated energy release rates, and delamination crack-closure are determined for each individual case. The basic mechanics and mechanisms of composite delamination are studied, and fundamental characteristics unique to recently proposed tests for interlaminar fracture toughness of fiber composite laminates are examined. Previously announced in STAR as N84-13222

Rapid shape memory TEMPO-oxidized cellulose nanofibers/polyacrylamide/gelatin hydrogels with enhanced mechanical strength.

PubMed

Li, Nan; Chen, Wei; Chen, Guangxue; Tian, Junfei

2017-09-01

TEMPO-oxidized cellulose nanofibers/polyacrylamide/gelatin shape memory hydrogels were successfully fabricated through a facile in-situ free-radical polymerization method, and double network was formed by chemically cross-linked polyacrylamide (PAM) network and physically cross-linked gelatin network. TEMPO-oxidized cellulose nanofibers (TOCNs) were introduced to improve the mechanical properties of the hydrogel. The structure, shape memory behaviors and mechanical properties of the resulting composite gels with varied gel compositions were investigated. The results obtained from those different studies revealed that TOCNs, gelatin, and PAM could mix with each other homogeneously. Due to the thermoreversible nature of the gelatin network, the composite hydrogels exhibited attractive thermo-induced shape memory properties. In addition, good mechanical properties (strength >200kPa, strain >650%) were achieved. Such composite hydrogels with good shape memory behavior and enhanced mechanical strength would be an attractive candidate for a wide variety of applications. Copyright © 2017 Elsevier Ltd. All rights reserved.

Hybrid composites prepared from Industrial waste: Mechanical and swelling behavior

PubMed Central

Ahmed, Khalil

2013-01-01

In this assessment, hybrid composites were prepared from the combination of industrial waste, as marble waste powder (MWP) with conventional fillers, carbon black (CB) as well as silica as reinforcing material, incorporated with natural rubber (NR). The properties studied were curing, mechanical and swelling behavior. Assimilation of CB as well as silica into MWP containing NR compound responded in decreasing the scorch time and cure time besides increasing in the torque. Additionally, increasing the CB and silica in their respective NR hybrid composite increases the tensile, tear, modulus, hardness, and cross-link density, but decreases the elongation and swelling coefficient. The degradation property e.g., thermal aging of the hybrid composite was also estimated. The overall behavior at 70 °C aging temperature signified that the replacement of MS by CB and silica improved the aging performance. PMID:25750756

Experimentally determined wear behavior of an Al2O3-SiC composite from 25 to 1200 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Farmer, Serene C.; Book, Patricia O.

1990-01-01

The sliding wear behavior of a self-mated alumina-silicon carbide whisker toughened composite was studied using optical, scanning electron (SEM) and transmission electron (TEM) microscopy. Because of its excellent strength and toughness properties this composite material is under consideration for use in heat engine applications for sliding contacts which operate at elevated temperatures. The composite's wear behavior and especially its wear mechanisms are not well understood. Pin-on-disk specimens were slid in air at 2.7 m/s sliding velocity, under a 26.5-N load, at temperatures 25 to 1200 C. Pin wear increased with increasing temperature. Based upon the microscopic analyses, the wear mechanism seems to be loosening of the reinforcing whiskers due to frictional and bulk heating. This leads to whisker pullout and increased wear.

An experimental study of mechanical behavior of natural fiber reinforced polymer matrix composites

NASA Astrophysics Data System (ADS)

Ratna, Sanatan; Misra, Sheelam

2018-05-01

Fibre-reinforced polymer composites have played a dominant role for a long time in a variety of applications for their high specific strength and modulus. The fibre which serves as a reinforcement in reinforced plastics may be synthetic or natural. Past studies show that only synthetic fibres such as glass, carbon etc., have been used in fibre reinforced plastics. Although glass and other synthetic fibre-reinforced plastics possess high specific strength, their fields of application are very limited because of their inherent higher cost of production. In this connection, an investigation has been carried out to make use of horse hair, an animal fibre abundantly available in India. Animal fibres are not only strong and lightweight but also relatively very cheaper than mineral fibre. The present work describes the development and characterization of a new set of animal fiber based polymer composites consisting of horse hair as reinforcement and epoxy resin. The newly developed composites are characterized with respect to their mechanical characteristics. Experiments are carried out to study the effect of fibre length on mechanical behavior of these epoxy based polymer composites. Composite made form horse hair can be used as a potential reinforcing material for many structural and non-structural applications. This work can be further extended to study other aspects of such composites like effect of fiber content, loading pattern, fibre treatment on mechanical behavior of horse hair based polymer horse hair.

Effect of processing method on the mechanical and thermal of Silvergrass/HDPE composites

NASA Astrophysics Data System (ADS)

Liu, Bing; Jin, Yueqiang; Wang, Shuying

2017-05-01

This paper investigates the effect of compression and injection molding methods on properties of Silvergrass-HDPE (High Density Polyethylene) composites, with respect to mechanical behaviors. Maleated polyethylene (MAPE) was added in the composite and improved the mechanical property of the composite. The research founds MAPE can improve the mechanical property because it improved the interfacial compatibility as a coupling agent. When added a content of 8% of MAPE, Silvergrass-HDPE composites made from compression molding shows a better mechanical performance in tensile strength and flexural strength than that made from injection molding, with increasing Silvergrass fiber content from 30% to 50%. However, the WPCs (wood plastics composites) made from injection molding had a lower degree of crystallinity with or without MAPE treatment.

Modeling the Mechanical Behavior of Ceramic Matrix Composite Materials

NASA Technical Reports Server (NTRS)

Jordan, William

1998-01-01

Ceramic matrix composites are ceramic materials, such as SiC, that have been reinforced by high strength fibers, such as carbon. Designers are interested in using ceramic matrix composites because they have the capability of withstanding significant loads while at relatively high temperatures (in excess of 1,000 C). Ceramic matrix composites retain the ceramic materials ability to withstand high temperatures, but also possess a much greater ductility and toughness. Their high strength and medium toughness is what makes them of so much interest to the aerospace community. This work concentrated on two different tasks. The first task was to do an extensive literature search into the mechanical behavior of ceramic matrix composite materials. This report contains the results of this task. The second task was to use this understanding to help interpret the ceramic matrix composite mechanical test results that had already been obtained by NASA. Since the specific details of these test results are subject to the International Traffic in Arms Regulations (ITAR), they are reported in a separate document (Jordan, 1997).

Load Diffusion in Composite Structures

NASA Technical Reports Server (NTRS)

Horgan, Cornelius O.; Simmonds, J. G.

2000-01-01

This research has been concerned with load diffusion in composite structures. Fundamental solid mechanics studies were carried out to provide a basis for assessing the complicated modeling necessary for large scale structures used by NASA. An understanding of the fundamental mechanisms of load diffusion in composite subcomponents is essential in developing primary composite structures. Analytical models of load diffusion behavior are extremely valuable in building an intuitive base for developing refined modeling strategies and assessing results from finite element analyses. The decay behavior of stresses and other field quantities provides a significant aid towards this process. The results are also amendable to parameter study with a large parameter space and should be useful in structural tailoring studies.

Designing with figer-reinforced plastics (planar random composites)

NASA Technical Reports Server (NTRS)

Chamis, C. C.

1982-01-01

The use of composite mechanics to predict the hygrothermomechanical behavior of planar random composites (PRC) is reviewed and described. These composites are usually made from chopped fiber reinforced resins (thermoplastics or thermosets). The hygrothermomechanical behavior includes mechanical properties, physical properties, thermal properties, fracture toughness, creep and creep rupture. Properties are presented in graphical form with sample calculations to illustrate their use. Concepts such as directional reinforcement and strip hybrids are described. Typical data that can be used for preliminary design for various PRCs are included. Several resins and molding compounds used to make PRCs are described briefly. Pertinent references are cited that cover analysis and design methods, materials, data, fabrication procedures and applications.

Durability of Structural Adhesively Bonded System.

DTIC Science & Technology

1981-06-01

Composites , Finite Element Method. II DURABILITY OF STRUCTURAL ADHESIVELY BONDED SYSTEMS TABLE OF CONTENTS 1. Introduction...That investigation was mainly devoted to the temperature effects in time on the mechanical behavior of fiber-reinforced plastic (FRP) composites and...ervironmental-loading history on the mechanical performance of similar FRP composites (which may serve as adherends in structural bcnded systems). That

Short beam shear tests of polymeric laminates and unidirectional composites

NASA Technical Reports Server (NTRS)

Stinchcomb, W. W.; Henneke, E. G.

1980-01-01

The application of advanced composite materials in aerospace, ground transportation, and sporting industries are discussed. Failure theories for the design and mechanical behavior of composite materials are emphasized. Methods for detecting specific types of flaws are outlined. The effect of detected flaws on mechanical properties such as stiffness, strength, fatigue lifetime, or residual strength is described.

The mechanical properties of ionic polymer-metal composites

NASA Astrophysics Data System (ADS)

Park, Il-Seok; Kim, Sang-Mun; Kim, Doyeon; Kim, Kwang J.

2007-04-01

In this study, we investigated the mechanical properties of various type ionic polymer-metal composites (IPMCs) and Pt, Au, Pd, and Pt electroded ionic liquid (IL-Pt) IPMCs, by testing tensile modulus and dynamic mechanical behavior. The SEM was utilized to investigate the characteristics of the doped electroding layer, and the DSC was probed in order to look into the thermal behavior of various types of IPMCs. Au IPMCs, having a 5~7 μm doped layer and nano-sized Au particles (ca. 10 nm), showed the highest tensile strength (56 MPa) and modulus (602 MPa) in a dried condition. In a thermal behavior, Au IPMC has the highest T g (153°C) and T m (263°C) in both the DMA and DSC results. The fracture behavior of various types IPMCs followed base material's behavior, Nafion TM, which is represented as the semicrystalline polymer characteristic.

Numerical and Experimental Investigations on Mechanical Behavior of Composite Corrugated Core

NASA Astrophysics Data System (ADS)

Dayyani, Iman; Ziaei-Rad, Saeed; Salehi, Hamid

2012-06-01

Tensile and flexural characteristics of corrugated laminate panels were studied using numerical and analytical methods and compared with experimental data. Prepreg laminates of glass fiber plain woven cloth were hand-laid by use of a heat gun to ease the creation of the panel. The corrugated panels were then manufactured by using a trapezoidal machined aluminium mould. First, a series of simple tension tests were performed on standard samples to evaluate the material characteristics. Next, the corrugated panels were subjected to tensile and three-point bending tests. The force-displacement graphs were recorded. Numerical and analytical solutions were proposed to simulate the mechanical behavior of the panels. In order to model the energy dissipation due to delamination phenomenon observed in tensile tests in all members of corrugated core, plastic behavior was assigned to the whole geometry, not only to the corner regions. Contrary to the literature, it is shown that the three-stage mechanical behavior of composite corrugated core is not confined to aramid reinforced corrugated laminates and can be observed in other types such as fiber glass. The results reveal that the mechanical behavior of the core in tension is sensitive to the variation of core height. In addition, for the first time, the behavior of composite corrugated core was studied and verified in bending. Finally, the analytical and numerical results were validated by comparing them with experimental data. A good degree of correlation was observed which showed the suitability of the finite element model for predicting the mechanical behavior of corrugated laminate panels.

Prediction of composites behavior undergoing an ATP process through data-mining

NASA Astrophysics Data System (ADS)

Martin, Clara Argerich; Collado, Angel Leon; Pinillo, Rubén Ibañez; Barasinski, Anaïs; Abisset-Chavanne, Emmanuelle; Chinesta, Francisco

2018-05-01

The need to characterize composite surfaces for distinct mechanical or physical processes leads to different manners of evaluate the state of the surface. During many manufacturing processes deformation occurs, thus hindering composite classification for fabrication processes. In this work we focus on the challenge of a priori identifying the surfaces' behavior in order to optimize manufacturing. We will propose and validate the curvature of the surface as a reliable parameter and we will develop a tool that allows the prediction of the surface behavior.

Tunneling Conductivity and Piezoresistivity of Composites Containing Randomly Dispersed Conductive Nano-Platelets

PubMed Central

Oskouyi, Amirhossein Biabangard; Sundararaj, Uttandaraman; Mertiny, Pierre

2014-01-01

In this study, a three-dimensional continuum percolation model was developed based on a Monte Carlo simulation approach to investigate the percolation behavior of an electrically insulating matrix reinforced with conductive nano-platelet fillers. The conductivity behavior of composites rendered conductive by randomly dispersed conductive platelets was modeled by developing a three-dimensional finite element resistor network. Parameters related to the percolation threshold and a power-low describing the conductivity behavior were determined. The piezoresistivity behavior of conductive composites was studied employing a reoriented resistor network emulating a conductive composite subjected to mechanical strain. The effects of the governing parameters, i.e., electron tunneling distance, conductive particle aspect ratio and size effects on conductivity behavior were examined. PMID:28788580

Mechanics of composite materials: Recent advances; Proceedings of the Symposium, Virginia Polytechnic Institute and State University, Blacksburg, VA, August 16-19, 1982

NASA Technical Reports Server (NTRS)

Hashin, Z. (Editor); Herakovich, C. T. (Editor)

1983-01-01

The present conference on the mechanics of composites discusses microstructure's influence on particulate and short fiber composites' thermoelastic and transport properties, the elastoplastic deformation of composites, constitutive equations for viscoplastic composites, the plasticity and fatigue of metal matrix composites, laminate damping mechanisms, the micromechanical modeling of Kevlar/epoxy composites' time-dependent failure, the variational characterization of waves in composites, and computational methods for eigenvalue problems in composite design. Also discussed are the elastic response of laminates, elastic coupling nonlinear effects in unsymmetrical laminates, elasticity solutions for laminate problems having stress singularities, the mechanics of bimodular composite structures, the optimization of laminated plates and shells, NDE for laminates, the role of matrix cracking in the continuum constitutive behavior of a damaged composite ply, and the energy release rates of various microcracks in short fiber composites.

Multiscale mechanics of graphene oxide and graphene based composite films

NASA Astrophysics Data System (ADS)

Cao, Changhong

The mechanical behavior of graphene oxide is length scale dependent: orders of magnitude different between the bulk forms and monolayer counterparts. Understanding the underlying mechanisms plays a significant role in their versatile application. A systematic multiscale mechanical study from monolayer to multilayer, including the interactions between layers of GO, can provide fundamental support for material engineering. In this thesis, an experimental coupled with simulation approach was used to study the multiscale mechanics of graphene oxide (GO) and the methods developed for GO study are proved to be applicable also to mechanical study of graphene based composites. GO is a layered nanomaterial comprised of hierarchical units whose characteristic dimension lies between monolayer GO (0.7 nm - 1.2 nm) and bulk GO papers (≥ 1 mum). Mechanical behaviors of monolayer GO and GO nanosheets (10 nm- 100 nm) were comprehensively studied this work. Monolayer GO was measured to have an average strength of 24.7 GPa,, orders of magnitude higher than previously reported values for GO paper and approximately 50% of the 2D intrinsic strength of pristine graphene. The huge discrepancy between the strength of monolayer GO and that of bulk GO paper motivated the study of GO at the intermediate length scale (GO nanosheets). Experimental results showed that GO nanosheets possess high strength in the gigapascal range. Molecular Dynamic simulations showed that the transition in the failure behavior from interplanar fracture to intraplanar fracture was responsible for the huge strength discrepancy between nanometer scale GO and bulk GO papers. Additionally, the interfacial shear strength between GO layers was found to be a key contributing factor to the distinct mechanical behavior among hierarchical units of GO. The understanding of the multiscale mechanics of GO is transferrable in heterogeneous layered nanomaterials, such as graphene-metal oxide based anode materials in Li-ion batteries. The novel methods developed in this work to study GO multilayered structures were also applied to study the mechanics of graphene-TiO 2 composites. It was found that a critical thickness range of TiO2 deposition on graphene is required for the observed stiffness enhancement effect of graphene to influence the mechanical behavior of the composite.

Tissue Anisotropy Modeling Using Soft Composite Materials.

PubMed

Chanda, Arnab; Callaway, Christian

2018-01-01

Soft tissues in general exhibit anisotropic mechanical behavior, which varies in three dimensions based on the location of the tissue in the body. In the past, there have been few attempts to numerically model tissue anisotropy using composite-based formulations (involving fibers embedded within a matrix material). However, so far, tissue anisotropy has not been modeled experimentally. In the current work, novel elastomer-based soft composite materials were developed in the form of experimental test coupons, to model the macroscopic anisotropy in tissue mechanical properties. A soft elastomer matrix was fabricated, and fibers made of a stiffer elastomer material were embedded within the matrix material to generate the test coupons. The coupons were tested on a mechanical testing machine, and the resulting stress-versus-stretch responses were studied. The fiber volume fraction (FVF), fiber spacing, and orientations were varied to estimate the changes in the mechanical responses. The mechanical behavior of the soft composites was characterized using hyperelastic material models such as Mooney-Rivlin's, Humphrey's, and Veronda-Westmann's model and also compared with the anisotropic mechanical behavior of the human skin, pelvic tissues, and brain tissues. This work lays the foundation for the experimental modelling of tissue anisotropy, which combined with microscopic studies on tissues can lead to refinements in the simulation of localized fiber distribution and orientations, and enable the development of biofidelic anisotropic tissue phantom materials for various tissue engineering and testing applications.

Tissue Anisotropy Modeling Using Soft Composite Materials

PubMed Central

Callaway, Christian

2018-01-01

Soft tissues in general exhibit anisotropic mechanical behavior, which varies in three dimensions based on the location of the tissue in the body. In the past, there have been few attempts to numerically model tissue anisotropy using composite-based formulations (involving fibers embedded within a matrix material). However, so far, tissue anisotropy has not been modeled experimentally. In the current work, novel elastomer-based soft composite materials were developed in the form of experimental test coupons, to model the macroscopic anisotropy in tissue mechanical properties. A soft elastomer matrix was fabricated, and fibers made of a stiffer elastomer material were embedded within the matrix material to generate the test coupons. The coupons were tested on a mechanical testing machine, and the resulting stress-versus-stretch responses were studied. The fiber volume fraction (FVF), fiber spacing, and orientations were varied to estimate the changes in the mechanical responses. The mechanical behavior of the soft composites was characterized using hyperelastic material models such as Mooney-Rivlin's, Humphrey's, and Veronda-Westmann's model and also compared with the anisotropic mechanical behavior of the human skin, pelvic tissues, and brain tissues. This work lays the foundation for the experimental modelling of tissue anisotropy, which combined with microscopic studies on tissues can lead to refinements in the simulation of localized fiber distribution and orientations, and enable the development of biofidelic anisotropic tissue phantom materials for various tissue engineering and testing applications. PMID:29853996

Thermal behavior of silicone rubber-based ceramizable composites characterized by Fourier transform infrared (FT-IR) spectroscopy and microcalorimetry.

PubMed

Anyszka, Rafał; Bieliński, Dariusz M; Jędrzejczyk, Marcin

2013-12-01

Ceramizable (ceramifiable) silicone rubber-based composites are commonly used for cable insulation. These materials are able to create a protective ceramic layer during fire due to the ceramization process, which occurs at high temperature. When the temperature is increased, the polymer matrix is degraded and filler particles stick together by the fluxing agent, producing a solid, continuous ceramic phase that protects the copper wire from heat and mechanical stress. Despite increasing interest in these materials that has resulted in growing applications in the cable industry, their thermal behavior and ceramization process are still insufficiently described in the literature. In this paper, the thermal behavior of ceramizable silicone rubber-based composites is studied using microcalorimetry and Fourier transform infrared spectroscopy. The analysis of the experimental data made it possible to develop complete information on the mechanism of composite ceramization.

Relaxation processes and conduction mechanism in bismuth ferrite lead titanate composites

NASA Astrophysics Data System (ADS)

Sahu, Truptimayee; Behera, Banarji

2018-02-01

In this study, samarium (Sm)-doped multiferroic composites of 0.8BiSmxFe1-xO3-0.2PbTiO3 where x = 0.05, 0.10, 0.15, and 0.20 were prepared via the conventional solid state reaction route. The electrical properties of these composites were analyzed using an impedance analyzer over a wide range of temperatures and frequencies (102-106 Hz). The impedance and modulus analyses confirmed the presence of both bulk and grain boundary effects in the materials. The temperature dependence of impedance and modulus spectrum indicated the negative temperature coefficient of resistance behavior. The dielectric relaxation exhibited non-Debye type behavior and it was temperature dependent. The relaxation time (τ) and DC conductivity followed an Arrhenius type behavior. The frequency-dependent AC conductivity obeyed Jonscher's power law. The correlated barrier hopping model was appropriate to understand the conduction mechanism in the composites considered.

Synthesis and mechanical behavior of β-tricalcium phosphate/titania composites addressed to regeneration of long bone segments.

PubMed

Sprio, Simone; Guicciardi, Stefano; Dapporto, Massimiliano; Melandri, Cesare; Tampieri, Anna

2013-01-01

Bioactive tricalcium phosphate/titania ceramic composites were synthesized by pressureless air sintering of mixed hydroxyapatite and titania (TiO2) powders. The sintering process was optimized to achieve dense ceramic bodies consisting in a bioactive/bioresorbable matrix (β-tricalcium phosphate) reinforced with defined amounts of sub-micron sized titania particles. Extensive chemico-physical and mechanical characterization was carried out on the resulting composites, which displayed values of flexural strength, fracture toughness and elastic modulus in the range or above the typical ranges of values manifested by human cortical bone. It was shown that titania particles provided a toughening effect to the calcium-phosphate matrix and a reinforcement in fracture strength, in comparison with sintered hydroxyapatite bodies characterized by similar relative density. The characteristics of the resulting composites, i.e. bioactivity/bioresorbability and ability of manifesting biomimetic mechanical behavior, are features that can promote processes of bone regeneration in load-bearing sites. Hence, in the perspective of developing porous bone scaffolds with high bioactivity and improved biomechanical behavior, TCP/TiO2 composites with controlled composition can be considered as very promising biomaterials for application in a field of orthopedics where no acceptable clinical solutions still exist. Copyright © 2012 Elsevier Ltd. All rights reserved.

Thermo-mechanical response predictions for metal matrix composite laminates

NASA Technical Reports Server (NTRS)

Aboudi, J.; Hidde, J. S.; Herakovich, C. T.

1991-01-01

An analytical micromechanical model is employed for prediction of the stress-strain response of metal matrix composite laminates subjected to thermomechanical loading. The predicted behavior of laminates is based upon knowledge of the thermomechanical response of the transversely isotropic, elastic fibers and the elastic-viscoplastic, work-hardening matrix. The method is applied to study the behavior of silicon carbide/titanium metal matrix composite laminates. The response of laminates is compared with that of unidirectional lamina. The results demonstrate the effect of cooling from a stress-free temperature and the mismatch of thermal and mechanical properties of the constituent phases on the laminate's subsequent mechanical response. Typical results are presented for a variety of laminates subjected to monotonic tension, monotonic shear and cyclic tensile/compressive loadings.

Mechanical properties of green composites based on thermoplastic starch

NASA Astrophysics Data System (ADS)

Fornes, F.; Sánchez-Nácher, L.; Fenollar, O.; Boronat, T.; Garcia-Sanoguera, D.

2010-06-01

The present work is focused on study of "green composites" elaborated from thermoplastic starch (TPS) as polymer matrix and a fiber from natural origin (rush) as reinforced fiber. The effect of the fiber content has been studied by means of the mechanical properties. The composite resulting presents a lack of interaction between matrix and fiber that represents a performance decrease. However the biodegradability behavior of the resulting composite raise this composite as useful an industrial level.

Effect of Al content on impact resistance behavior of Al-Ti-B4C composite fabricated under air atmosphere.

PubMed

Zhao, Qian; Liang, Yunhong; Zhang, Zhihui; Li, Xiujuan; Ren, Luquan

2016-12-01

Reaction behavior, mechanical property and impact resistance of TiC-TiB 2 /Al composite reacted from Al-Ti-B 4 C system with various Al content via combination method of combustion synthesis and hot pressed sintering under air was investigated. Al content was the key point to the variation of mechanical property and impact resistance. Increasing Al content could increase the density, strength and toughness of the composite. Due to exorbitant ceramic content, 10wt.% and 20wt.% Al-Ti-B 4 C composites exhibited poor molding ability and machinability. Flexural strength, fracture toughness, compressive strength and impact toughness of 30-50wt.% Al-Ti-B 4 C composite were higher than those of Al matrix. The intergranular fracture dispersed and defused impact load and restricted crack extension, enhancing the impact resistance of the composite. The composite with 50wt.% Al content owned highest mechanical properties and impact resistance. The results were useful for the application of TiC-TiB 2 /Al composite in impact resistance field of ceramic reinforced Al matrix composite. Copyright © 2016 Elsevier Ltd. All rights reserved.

Impact of head and neck radiotherapy on the mechanical behavior of composite resins and adhesive systems: A systematic review.

PubMed

Madrid Troconis, Cristhian Camilo; Santos-Silva, Alan Roger; Brandão, Thaís Bianca; Lopes, Marcio Ajudarte; de Goes, Mario Fernando

2017-11-01

To analyze the evidence regarding the impact of head and neck radiotherapy (HNRT) on the mechanical behavior of composite resins and adhesive systems. Searches were conducted on PubMed, Embase, Scopus and ISI Web of Science databases using "Radiotherapy", "Composite resins" and "Adhesive systems" as keywords. Selected studies were written in English and assessed the mechanical behavior of composite resins and/or adhesive systems when bonding procedure was conducted before and/or after a maximum radiation dose ≥50Gy, applied under in vitro or in vivo conditions. In total, 115 studies were found but only 16 were included, from which five evaluated the effect of in vitro HNRT on microhardness, wear resistance, diametral tensile and flexural strength of composite resins, showing no significant negative effect in most of reports. Regarding bond strength of adhesive systems, 11 studies were included from which five reported no meaningful negative effect when bonding procedure was conducted before simulated HNRT. Conversely, five studies showed that bond strength diminished when adhesive procedure was done after in vitro radiation therapy. Only two studies about dental adhesion were conducted after in vivo radiotherapy but the results were not conclusive. The mechanical behavior of composite resins and adhesive systems seems not to be affected when in vitro HNRT is applied after bonding procedure. However, bond strength of adhesive systems tends to decrease when simulated radiotherapy is used immediately before bonding procedure. Studies assessing dentin bond strength after in-vivo HNRT were limited and controversial. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Viscoelastic Properties of Collagen-Adhesive Composites under Water Saturated and Dry Conditions

PubMed Central

Singh, Viraj; Misra, Anil; Parthasarathy, Ranganathan; Ye, Qiang; Spencer, Paulette

2014-01-01

To investigate the time and rate dependent mechanical properties of collagen-adhesive composites, creep and monotonic experiments are performed under dry and wet conditions. The composites are prepared by infiltration of dentin adhesive into a demineralized bovine dentin. Experimental results show that for small stress level under dry conditions, both the composite and neat adhesive have similar behavior. On the other hand, in wet conditions, the composites are significantly soft and weak compared to the neat adhesives. The behavior in the wet condition is found to be affected by the hydrophilicity of both the adhesive and collagen. Since the adhesive-collagen composites area part of the complex construct that forms the adhesive-dentin interface, their presence will affect the overall performance of the restoration. We find that Kelvin-Voigt model with at least 4-elements is required to fit the creep compliance data, indicating that the adhesive-collagen composites are complex polymers with several characteristics time-scales whose mechanical behavior will be significantly affected by loading rates and frequencies. Such mechanical properties have not been investigated widely for these types of materials. The derived model provides an additional advantage that it can be exploited to extract other viscoelastic properties which are, generally, time consuming to obtain experimentally. The calibrated model is utilized to obtain stress relaxation function, frequency-dependent storage and loss modulus, and rate dependent elastic modulus. PMID:24753362

[Nano-hydroxyapatite/collagen composite for bone repair].

PubMed

Feng, Qing-ling; Cui, Fu-zhai; Zhang, Wei

2002-04-01

To develop nano-hydroxyapatite/collagen (NHAC) composite and test its ability in bone repairing. NHAC composite was developed by biomimetic method. The composite showed some features of natural bone in both composition and microstructure. The minerals could contribute to 50% by weight of the composites in sheet form. The inorganic phase in the composite was carbonate-substituted hydroxyapatite (HA) with low crystallinity and nanometer size. HA precipitates were uniformly distributed on the type I collagen matrix without preferential orientation. The composite exhibited an isotropic mechanical behavior. However, the resistance of the composite to localized pressure could reach the lower limit of that of femur compacta. The tissue response to the NHAC composite implanted in marrow cavity was investigated. Knoop micro-hardness test was performed to compare the mechanical behavior of the composite and bone. At the interface of the implant and marrow tissue, solution-mediated dissolution and macrophage-mediated resorption led to the degradation of the composite, followed by interfacial bone formation by osteoblasts. The process of implant degradation and bone substitution was reminiscent of bone remodeling. The composite can be incorporated into bone metabolism instead of being a permanent implant.

Oxidation effects on the mechanical properties of SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.

1989-01-01

The room temperature mechanical properties of SiC fiber reinforced reaction bonded silicon nitride composites were measured after 100 hrs exposure at temperatures to 1400 C in nitrogen and oxygen environments. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers in a reaction bonded Si3N4 matrix. The results indicate that composites heat treated in a nitrogen environment at temperatures to 1400 C showed deformation and fracture behavior equivalent to that of the as-fabricated composites. Also, the composites heat treated in an oxidizing environment beyond 400 C yielded significantly lower tensile strength values. Specifically in the temperature range from 600 to 1000 C, composites retained approx. 40 percent of their as-fabricated strength, and those heat treated in the temperatures from 1200 to 1400 C retained 70 percent. Nonetheless, for all oxygen heat treatment conditions, composite specimens displayed strain capability beyond the matrix fracture stress; a typical behavior of a tough composite.

Multi-physics modeling of multifunctional composite materials for damage detection

NASA Astrophysics Data System (ADS)

Sujidkul, Thanyawalai

This study presents a modeling of multifunction composite materials for damage detection with its verification and validation to mechanical behavior predictions of Carbon Fibre Reinforced Polymer composites (CFRPs), CFRPs laminated composites, and woven SiC/SiC matrix composites that are subjected to fracture damage. Advantages of those materials are low cost, low density, high strength-to-weight ratio, and comparable specific tensile properties, the special of SiC/SiC is good environmental stability at high temperature. Resulting in, the composite has been used for many important structures such as helicopter rotors, aerojet engines, gas turbines, hot control surfaces, sporting goods, and windmill blades. Damage or material defect detection in a mechanical component can provide vital information for the prediction of remaining useful life, which will result in the prevention of catastrophic failures. Thus the understanding of the mechanical behavior have been challenge to the prevent damage and failure of composites in different scales. The damage detection methods in composites have been investigated widely in recent years. Non-destructive techniques are the traditional methods to detect the damage such as X-ray, acoustic emission and thermography. However, due to the invisible damage in composite can be occurred, to prevent the failure in composites. The developments of damage detection methods have been considered. Due to carbon fibers are conductive materials, in resulting CFRPs can be self-sensing to detect damage. As is well known, the electrical resistance has been shown to be a sensitive measure of internal damage, and also this work study in thermal resistance can detect damage in composites. However, there is a few number of different micromechanical modeling schemes has been proposed in the published literature for various types of composites. This works will provide with a numerical, analytical, and theoretical failure models in different damages to predict the mechanical damage behavior with electrical properties and thermal properties.

Mechanical Properties and Tribological Behavior of In Situ NbC/Fe Surface Composites

NASA Astrophysics Data System (ADS)

Cai, Xiaolong; Zhong, Lisheng; Xu, Yunhua

2017-01-01

The mechanical properties and tribological behavior of the niobium carbide (NbC)-reinforced gray cast iron surface composites prepared by in situ synthesis have been investigated. Composites are comprised of a thin compound layer and followed by a deep diffusion zone on the surface of gray cast iron. The graded distributions of the hardness and elastic modulus along the depth direction of the cross section of composites form in the ranges of 6.5-20.1 and 159.3-411.2 GPa, respectively. Meanwhile, dry wear tests for composites were implemented on pin-on-disk equipment at sliding speed of 14.7 × 10-2 m/s and under 5 or 20 N, respectively. The result indicates that tribological performances of composites are considerably dependent on the volume fraction and the grain size of the NbC as well as the mechanical properties of the matrices in different areas. The surface compound layer presents the lowest coefficient of friction and wear rate, and exhibits the highest wear resistance, in comparison with diffusion zone and substrate. Furthermore, the worn morphologies observed reveal the dominant wear mechanism is abrasive wear feature in compound layer and diffusion zone.

Improvement of Progressive Damage Model to Predicting Crashworthy Composite Corrugated Plate

NASA Astrophysics Data System (ADS)

Ren, Yiru; Jiang, Hongyong; Ji, Wenyuan; Zhang, Hanyu; Xiang, Jinwu; Yuan, Fuh-Gwo

2018-02-01

To predict the crashworthy composite corrugated plate, different single and stacked shell models are evaluated and compared, and a stacked shell progressive damage model combined with continuum damage mechanics is proposed and investigated. To simulate and predict the failure behavior, both of the intra- and inter- laminar failure behavior are considered. The tiebreak contact method, 1D spot weld element and cohesive element are adopted in stacked shell model, and a surface-based cohesive behavior is used to capture delamination in the proposed model. The impact load and failure behavior of purposed and conventional progressive damage models are demonstrated. Results show that the single shell could simulate the impact load curve without the delamination simulation ability. The general stacked shell model could simulate the interlaminar failure behavior. The improved stacked shell model with continuum damage mechanics and cohesive element not only agree well with the impact load, but also capture the fiber, matrix debonding, and interlaminar failure of composite structure.

Mechanical and physical behavior of newly developed functionally graded materials and composites of stainless steel 316L with calcium silicate and hydroxyapatite.

PubMed

Ataollahi Oshkour, Azim; Pramanik, Sumit; Mehrali, Mehdi; Yau, Yat Huang; Tarlochan, Faris; Abu Osman, Noor Azuan

2015-09-01

This study aimed to investigate the structural, physical and mechanical behavior of composites and functionally graded materials (FGMs) made of stainless steel (SS-316L)/hydroxyapatite (HA) and SS-316L/calcium silicate (CS) employing powder metallurgical solid state sintering. The structural analysis using X-ray diffraction showed that the sintering at high temperature led to the reaction between compounds of the SS-316L and HA, while SS-316L and CS remained intact during the sintering process in composites of SS-316L/CS. A dimensional expansion was found in the composites made of 40 and 50 wt% HA. The minimum shrinkage was emerged in 50 wt% CS composite, while the maximum shrinkage was revealed in samples with pure SS-316L, HA and CS. Compressive mechanical properties of SS-316L/HA decreased sharply with increasing of HA content up to 20 wt% and gradually with CS content up to 50 wt% for SS-316L/CS composites. The mechanical properties of the FGM of SS-316L/HA dropped with increase in temperature, while it was improved for the FGM of SS-316L/CS with temperature enhancement. It has been found that the FGMs emerged a better compressive mechanical properties compared to both the composite systems. Therefore, the SS-316L/CS composites and their FGMs have superior compressive mechanical properties to the SS-316L/HA composites and their FGMs and also the newly developed FGMs of SS-316L/CS with improved mechanical and enhanced gradation in physical and structural properties can potentially be utilized in the components with load-bearing application. Copyright © 2015 Elsevier Ltd. All rights reserved.

Dry sliding wear behavior of Al 2219/SiCp-Gr hybrid metal matrix composites

NASA Astrophysics Data System (ADS)

Basavarajappa, S.; Chandramohan, G.; Mukund, K.; Ashwin, M.; Prabu, M.

2006-12-01

The dry sliding wear behavior of Al 2219 alloy and Al 2219/SiCp/Gr hybrid composites are investigated under similar conditions. The composites are fabricated using the liquid metallurgy technique. The dry sliding wear test is carried out for sliding speeds up to 6 m/s and for normal loads up to 60 N using a pin on disc apparatus. It is found that the addition of SiCp and graphite reinforcements increases the wear resistance of the composites. The wear rate decreases with the increase in SiCp reinforcement content. As speed increases, the wear rate decreases initially and then increases. The wear rate increases with the increase in load. Scanning electron microscopy micrographs of the worn surface are used to predict the nature of the wear mechanism. Abrasion is the principle wear mechanism for the composites at low sliding speeds and loads. At higher loads, the wear mechanism changes to delamination.

The role of oxygen vacancies in resistive switching behavior of organic-TiO2 hybrid composite

NASA Astrophysics Data System (ADS)

Zhang, Jiahua; Chen, Da; Huang, Shihua

2017-10-01

Effects of polyethylene glycol (PEG) on resistive switching behaviors and mechanisms in organic-TiO2 hybrid composites were investigated. The reversed current-voltage curves in the negative bias during the initial voltage sweeps were first observed in the composites annealed at 150, 200 and 250 °C, which is ascribed to the accumulation of oxygen vacancies and the inhibition effect of polarities of PEG chains. In addition, the volatility of composites with relatively high content of PEG is caused by the inhibition effect of PEG on creating oxygen vacancies. The formation and rupture of oxygen-vacancy filaments was considered as the resistive switching mechanism. Finally, the charging and discharging process in PEG-TiO2 composite annealed at 150 °C results in the instability of the electron-occupied oxygen vacancies and the inhibition of PEG chains. This study demonstrates a new way to investigate the interaction between polymers and TiO2 for understanding the resistive switching mechanism of TiO2-based memories.

Mechanical property characterization of intraply hybrid composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Lark, R. F.; Sinclair, J. H.

1979-01-01

An investigation of the mechanical properties of intraply hybrids made from graphite fiber/epoxy matrix hybridized with secondary S-glass or Kevlar 49 fiber composites is presented. The specimen stress-strain behavior was determined, showing that mechanical properties of intraply hybrid composites can be measured with available methods such as the ten-degree off-axis test for intralaminar shear, and conventional tests for tensile, flexure, and Izod impact properties. The results also showed that combinations of high modulus graphite/S-glass/epoxy matrix composites exist which yield intraply hybrid laminates with the best 'balanced' properties, and that the translation efficiency of mechanical properties from the constituent composites to intraply hybrids may be assessed with a simple equation.

Compressive Deformation Behavior of Closed-Cell Micro-Pore Magnesium Composite Foam.

PubMed

Wang, Jing; Wang, Nannan; Liu, Xin; Ding, Jian; Xia, Xingchuan; Chen, Xueguang; Zhao, Weimin

2018-05-04

The closed-cell micro-pore magnesium composite foam with hollow ceramic microspheres (CMs) was fabricated by a modified melt foaming method. The effect of CMs on the compressive deformation behavior of CM-containing magnesium composite foam was investigated. Optical microscopy and scanning electron microscopy were used for observation of the microstructure. Finite element modeling of the magnesium composite foam was established to predict localized stress, fracture of CMs, and the compressive deformation behavior of the foam. The results showed that CMs and pores directly affected the compressive deformation behavior of the magnesium composite foam by sharing a part of load applied on the foam. Meanwhile, the presence of Mg₂Si phase influenced the mechanical properties of the foam by acting as the crack source during the compression process.

Compressive Deformation Behavior of Closed-Cell Micro-Pore Magnesium Composite Foam

PubMed Central

Wang, Jing; Wang, Nannan; Liu, Xin; Ding, Jian; Xia, Xingchuan; Chen, Xueguang; Zhao, Weimin

2018-01-01

The closed-cell micro-pore magnesium composite foam with hollow ceramic microspheres (CMs) was fabricated by a modified melt foaming method. The effect of CMs on the compressive deformation behavior of CM-containing magnesium composite foam was investigated. Optical microscopy and scanning electron microscopy were used for observation of the microstructure. Finite element modeling of the magnesium composite foam was established to predict localized stress, fracture of CMs, and the compressive deformation behavior of the foam. The results showed that CMs and pores directly affected the compressive deformation behavior of the magnesium composite foam by sharing a part of load applied on the foam. Meanwhile, the presence of Mg2Si phase influenced the mechanical properties of the foam by acting as the crack source during the compression process. PMID:29734700

Ablation behaviors of carbon reinforced polymer composites by laser of different operation modes

NASA Astrophysics Data System (ADS)

Wu, Chen-Wu; Wu, Xian-Qian; Huang, Chen-Guang

2015-10-01

Laser ablation mechanism of Carbon Fiber Reinforced Polymer (CFRP) composite is of critical meaning for the laser machining process. The ablation behaviors are investigated on the CFRP laminates subject to continuous wave, long duration pulsed wave and short duration pulsed wave lasers. Distinctive ablation phenomena have been observed and the effects of laser operation modes are discussed. The typical temperature patterns resulted from laser irradiation are computed by finite element analysis and thereby the different ablation mechanisms are interpreted.

Effect of space exposure of some epoxy matrix composites on their thermal expansion and mechanical properties (A0138-8)

NASA Technical Reports Server (NTRS)

Jabs, Heinrich

1992-01-01

Assessments of the behavior of the carbon/epoxy composites in space conditions are described. After an exposure of five years, the mechanical characteristics and the coefficient of thermal expansion are measured and compared to reference values.

Fiber Composite Sandwich Thermostructural Behavior: Computational Simulation

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Aiello, R. A.; Murthy, P. L. N.

1986-01-01

Several computational levels of progressive sophistication/simplification are described to computationally simulate composite sandwich hygral, thermal, and structural behavior. The computational levels of sophistication include: (1) three-dimensional detailed finite element modeling of the honeycomb, the adhesive and the composite faces; (2) three-dimensional finite element modeling of the honeycomb assumed to be an equivalent continuous, homogeneous medium, the adhesive and the composite faces; (3) laminate theory simulation where the honeycomb (metal or composite) is assumed to consist of plies with equivalent properties; and (4) derivations of approximate, simplified equations for thermal and mechanical properties by simulating the honeycomb as an equivalent homogeneous medium. The approximate equations are combined with composite hygrothermomechanical and laminate theories to provide a simple and effective computational procedure for simulating the thermomechanical/thermostructural behavior of fiber composite sandwich structures.

Program For Analysis Of Metal-Matrix Composites

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Mital, S. K.

1994-01-01

METCAN (METal matrix Composite ANalyzer) is computer program used to simulate computationally nonlinear behavior of high-temperature metal-matrix composite structural components in specific applications, providing comprehensive analyses of thermal and mechanical performances. Written in FORTRAN 77.

Effect of MoSi2 Content on Dry Sliding Tribological Properties of Zr-Based Bulk Metallic Glass Composites

NASA Astrophysics Data System (ADS)

Liu, Longfei; Yang, Jun

2017-12-01

Zr55Cu30Al10Ni5 bulk metallic glass and its composites were prepared by suction casting into a copper mold. The effect of MoSi2 content on the tribological behavior of Zr55Cu30Al10Ni5 BMG was studied by using a high-speed reciprocating friction and wear tester. The results indicate that the friction coefficient and wear resistance of the BMGs can be improved by a certain amount of crystalline phase induced by MoSi2 content from 1 to 3% and deteriorated with MoSi2 content of 4%. The wear mechanism of both the metallic glass and its composite is abrasive wear. The mechanism of crystalline phase-dependent tribological properties of the composite was discussed based on the wear track and mechanical properties in the present work. The wear behavior of Zr55Cu30Al10Ni5 BMG and its composite indicates that a good combination of the toughness and the hardness can make the composite be well wear resistant.

Development and characterization of powder metallurgically produced discontinuous tungsten fiber reinforced tungsten composites

NASA Astrophysics Data System (ADS)

Mao, Y.; Coenen, J. W.; Riesch, J.; Sistla, S.; Almanstötter, J.; Jasper, B.; Terra, A.; Höschen, T.; Gietl, H.; Bram, M.; Gonzalez-Julian, J.; Linsmeier, Ch; Broeckmann, C.

2017-12-01

In future fusion reactors, tungsten is the prime candidate material for the plasma facing components. Nevertheless, tungsten is prone to develop cracks due to its intrinsic brittleness—a major concern under the extreme conditions of fusion environment. To overcome this drawback, tungsten fiber reinforced tungsten (Wf/W) composites are being developed. These composite materials rely on an extrinsic toughing principle, similar to those in ceramic matrix composite, using internal energy dissipation mechanisms, such as crack bridging and fiber pull-out, during crack propagation. This can help Wf/W to facilitate a pseudo-ductile behavior and allows an elevated damage resilience compared to pure W. For pseudo-ductility mechanisms to occur, the interface between the fiber and matrix is crucial. Recent developments in the area of powder-metallurgical Wf/W are presented. Two consolidation methods are compared. Field assisted sintering technology and hot isostatic pressing are chosen to manufacture the Wf/W composites. Initial mechanical tests and microstructural analyses are performed on the Wf/W composites with a 30% fiber volume fraction. The samples produced by both processes can give pseudo-ductile behavior at room temperature.

High Temperature Mechanical Behavior of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Hemann, John

1996-01-01

The research accomplishments under this grant were very extensive in the areas of the high temperature behavior of ceramics, ceramic composites and testing standards for these materials. Rather than try to summarize all this research I have enclosed research papers and reports which were completed with the funding provided by the grant.

Mechanical property characterization of intraply hybrid composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Lark, R. F.; Sinclair, J. H.

1979-01-01

An investigation was conducted to characterize the mechanical properties of intraply hybrids made from graphite fiber/epoxy matrix (primary composites) hybridized with varying amounts of secondary composites made from S-glass or Kevlar 49 fibers. The tests were conducted using thin laminates having the same thickness. The specimens for these tests were instrumented with strain gages to determine stress-strain behavior. Significant results are included.

Synthesis, mechanical properties and corrosion behavior of powder metallurgy processed Fe/Mg2Si composites for biodegradable implant applications.

PubMed

Sikora-Jasinska, M; Paternoster, C; Mostaed, E; Tolouei, R; Casati, R; Vedani, M; Mantovani, D

2017-12-01

Recently, Fe and Fe-based alloys have shown their potential as degradable materials for biomedical applications. Nevertheless, the slow corrosion rate limits their performance in certain situations. The shift to iron matrix composites represents a possible approach, not only to improve the mechanical properties, but also to accelerate and tune the corrosion rate in a physiological environment. In this work, Fe-based composites reinforced by Mg 2 Si particles were proposed. The initial powders were prepared by different combinations of mixing and milling processes, and finally consolidated by hot rolling. The influence of the microstructure on mechanical properties and corrosion behavior of Fe/Mg 2 Si was investigated. Scanning electron microscopy and X-ray diffraction were used for the assessment of the composite structure. Tensile and hardness tests were performed to characterize the mechanical properties. Potentiodynamic and static corrosion tests were carried out to investigate the corrosion behavior in a pseudo-physiological environment. Samples with smaller Mg 2 Si particles showed a more homogenous distribution of the reinforcement. Yield and ultimate tensile strength increased when compared to those of pure Fe (from 400MPa and 416MPa to 523MPa and 630MPa, respectively). Electrochemical measurements and immersion tests indicated that the addition of Mg 2 Si could increase the corrosion rate of Fe even twice (from 0.14 to 0.28mm·year -1 ). It was found that the preparation method of the initial composite powders played a major role in the corrosion process as well as in the corrosion mechanism of the final composite. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of mechanical properties of hybrid fiber (hemp, jute, kevlar) reinforced composites

NASA Astrophysics Data System (ADS)

Suresha, K. V.; Shivanand, H. K.; Amith, A.; Vidyasagar, H. N.

2018-04-01

In today's world composites play wide role in all the engineering fields. The reinforcement of composites decides the properties of the material. Natural fiber composites compared to synthetic fiber possesses poor mechanical properties. The solution for this problem is to use combination of natural fiber and synthetic fiber. Hybridization helps to improve the overall mechanical properties of the material. In this study, hybrid reinforced composites of Hemp fabric/Kevlar fabric/Epoxy and Jute fabric/ Kevlar fabric/Epoxy composites are fabricated using Simple hand layup technique followed by Vacuum bagging process. Appropriate test methods as per standards and guidelines are followed to analyze mechanical behavior of the composites. The mechanical characteristics like tensile, compression and flexural properties of the hybrid reinforced composites are tested as per the ASTM standards by series of tensile test; compression test and three point bending tests were conducted on the hybrid composites. A quantitative relationship between the Hemp fabric/Kevlar fabric/Epoxy and Jute/ Kevlar fabric/Epoxy has been established with constant thickness.

Tension-Compression Fatigue Behavior of 2D and 3D Polymer Matrix Composites at Elevated Temperature

DTIC Science & Technology

2015-09-21

temperature calibrations, tests procedures and optical microscopy used in this research. 4.1 Mechanical Testing Equipment A Model 810 MTS servo -hydraulic...Composite Materials”. Oxford University Press , New York, NY, 2nd edition, 1994. 4. F.C. Campbell. “Structural Composite Materials” ASM International...M. “Mechanics of Composite Materials”. CRC Press , second Edition, ISBN-10: 156032712x, July 1998. 13. Ruggles-Wrenn, M. B., D. T. Christensen, A. L

The hygroscopic behavior of plant fibers: a review.

PubMed

Célino, Amandine; Fréour, Sylvain; Jacquemin, Frédéric; Casari, Pascal

2013-01-01

Environmental concern has resulted in a renewed interest in bio-based materials. Among them, plant fibers are perceived as an environmentally friendly substitute to glass fibers for the reinforcement of composites, particularly in automotive engineering. Due to their wide availability, low cost, low density, high-specific mechanical properties, and eco-friendly image, they are increasingly being employed as reinforcements in polymer matrix composites. Indeed, their complex microstructure as a composite material makes plant fiber a really interesting and challenging subject to study. Research subjects about such fibers are abundant because there are always some issues to prevent their use at large scale (poor adhesion, variability, low thermal resistance, hydrophilic behavior). The choice of natural fibers rather than glass fibers as filler yields a change of the final properties of the composite. One of the most relevant differences between the two kinds of fiber is their response to humidity. Actually, glass fibers are considered as hydrophobic whereas plant fibers have a pronounced hydrophilic behavior. Composite materials are often submitted to variable climatic conditions during their lifetime, including unsteady hygroscopic conditions. However, in humid conditions, strong hydrophilic behavior of such reinforcing fibers leads to high level of moisture absorption in wet environments. This results in the structural modification of the fibers and an evolution of their mechanical properties together with the composites in which they are fitted in. Thereby, the understanding of these moisture absorption mechanisms as well as the influence of water on the final properties of these fibers and their composites is of great interest to get a better control of such new biomaterials. This is the topic of this review paper.

The hygroscopic behavior of plant fibers: a review

PubMed Central

Célino, Amandine; Fréour, Sylvain; Jacquemin, Frédéric; Casari, Pascal

2013-01-01

Environmental concern has resulted in a renewed interest in bio-based materials. Among them, plant fibers are perceived as an environmentally friendly substitute to glass fibers for the reinforcement of composites, particularly in automotive engineering. Due to their wide availability, low cost, low density, high-specific mechanical properties, and eco-friendly image, they are increasingly being employed as reinforcements in polymer matrix composites. Indeed, their complex microstructure as a composite material makes plant fiber a really interesting and challenging subject to study. Research subjects about such fibers are abundant because there are always some issues to prevent their use at large scale (poor adhesion, variability, low thermal resistance, hydrophilic behavior). The choice of natural fibers rather than glass fibers as filler yields a change of the final properties of the composite. One of the most relevant differences between the two kinds of fiber is their response to humidity. Actually, glass fibers are considered as hydrophobic whereas plant fibers have a pronounced hydrophilic behavior. Composite materials are often submitted to variable climatic conditions during their lifetime, including unsteady hygroscopic conditions. However, in humid conditions, strong hydrophilic behavior of such reinforcing fibers leads to high level of moisture absorption in wet environments. This results in the structural modification of the fibers and an evolution of their mechanical properties together with the composites in which they are fitted in. Thereby, the understanding of these moisture absorption mechanisms as well as the influence of water on the final properties of these fibers and their composites is of great interest to get a better control of such new biomaterials. This is the topic of this review paper. PMID:24790971

Investigation of the Microstructural, Mechanical and Corrosion Properties of Grade A Ship Steel-Duplex Stainless Steel Composites Produced via Explosive Welding

NASA Astrophysics Data System (ADS)

Kaya, Yakup; Kahraman, Nizamettin; Durgutlu, Ahmet; Gülenç, Behçet

2017-08-01

Grade A ship-building steel-AISI 2304 duplex stainless steel composite plates were manufactured via explosive welding. The AISI 2304 plates were used to clad the Grade A plates. Optical microscopy studies were conducted on the joining interface for characterization of the manufactured composite plates. Notch impact, tensile-shear, microhardness, bending and twisting tests were carried out to determine the mechanical properties of the composites. In addition, the surfaces of fractured samples were examined by scanning electron microscopy (SEM), and neutral salt spray (NSS) and potentiodynamic polarization tests were performed to examine corrosion behavior. Near the explosion zone, the interface was completely flat, but became wavy as the distance from the explosion zone increased. The notch impact tests indicated that the impact strength of the composites decreased with increasing distance from the explosion zone. The SEM studies detected brittle behavior below the impact transition temperature and ductile behavior above this temperature. Microhardness tests revealed that the hardness values increased with increasing distance from the explosion zone and mechanical tests showed that no visible cracking or separation had occurred on the joining interface. The NSS and potentiodynamic polarization tests determined that the AISI 2304 exhibited higher corrosion resistance than the Grade A steel.

Monitoring the fracture behavior of metal matrix composites by combined NDE methodologies

NASA Astrophysics Data System (ADS)

Kordatos, E. Z.; Exarchos, D. A.; Mpalaskas, A. C.; Matikas, T. E.

2015-03-01

Current work deals with the non-destructive evaluation (NDE) of the fatigue behavior of metal matrix composites (MMCs) materials using Infrared Thermography (IRT) and Acoustic Emission (AE). AE monitoring was employed to record a wide spectrum of cracking events enabling the characterization of the severity of fracture in relation to the applied load. IR thermography as a non-destructive, real-time and non-contact technique, allows the detection of heat waves generated by the thermo-mechanical coupling during mechanical loading of the sample. In this study an IR methodology, based on the monitoring of the intrinsically dissipated energy, was applied for the determination of the fatigue limit of A359/SiCp composites. The thermographic monitoring is in agreement with the AE results enabling the reliable monitoring of the MMCs' fatigue behavior.

The Experiment and Numerical Simulation of Composite Countersunk-head Fasteners Pull-through Mechanical Behavior

NASA Astrophysics Data System (ADS)

Mu, Junwu; Guan, Zhidong; Bian, Tianya; Li, Zengshan; Wang, Kailun; Liu, Sui

2014-10-01

Fasteners made of the anisotropic carbon/carbon (C/C) composite material have been developed for joining C/C composite material components in the high-temperature environment. The fastener specimens are fabricated from the C/C composites which are made from laminated carbon cloths with Z-direction carbon fibers being punctured as perform. Densification process cycles such as the thermal gradient chemical vapor infiltration (CVI) technology were repeated to obtain high density C/C composites fastener. The fasteners were machined parallel to the carbon cloths (X-Y direction). A method was proposed to test pull-through mechanical behavior of the countersunk-head C/C composite material fasteners. The damage morphologies of the fasteners were observed through the charge coupled device (CCD) and the scanning electron microscope (SEM). The internal micro-structure were observed through the high-resolution Mirco-CT systems. Finally, an excellent simulation of the C/C composite countersunk-head fasteners were performed with the finite element method (FEM), in which the damage evolution model of the fastener was established based on continuum damage mechanics. The simulation is correspond well with the test result . The damage evolution process and the relation between the countersunk depth and the ultimate load was investigated.

On the Mechanical Behavior of Advanced Composite Material Structures

NASA Astrophysics Data System (ADS)

Vinson, Jack

During the period between 1993 and 2004, the author, as well as some colleagues and graduate students, had the honor to be supported by the Office of Naval Research to conduct research in several aspects of the behavior of structures composed of composite materials. The topics involved in this research program were numerous, but all contributed to increasing the understanding of how various structures that are useful for marine applications behaved. More specifically, the research topics focused on the reaction of structures that were made of fiber reinforced polymer matrix composites when subjected to various loads and environmental conditions. This included the behavior of beam, plate/panel and shell structures. It involved studies that are applicable to fiberglass, graphite/carbon and Kevlar fibers imbedded in epoxy, polyester and other polymeric matrices. Unidirectional, cross-ply, angle ply, and woven composites were involved, both in laminated, monocoque as well as in sandwich constructions. Mid-plane symmetric as well as asymmetric laminates were studied, the latter involving bending-stretching coupling and other couplings that only can be achieved with advanced composite materials. The composite structures studied involved static loads, dynamic loading, shock loading as well as thermal and hygrothermal environments. One major consideration was determining the mechanical properties of composite materials subjected to high strain rates because the mechanical properties vary so significantly as the strain rate increases. A considerable number of references are cited for further reading and study for those interested.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siranosian, Antranik Antonio; Schembri, Philip Edward; Luscher, Darby Jon

The Los Alamos National Laboratory's Weapon Systems Engineering division's Advanced Engineering Analysis group employs material constitutive models of composites for use in simulations of components and assemblies of interest. Experimental characterization, modeling and prediction of the macro-scale (i.e. continuum) behaviors of these composite materials is generally difficult because they exhibit nonlinear behaviors on the meso- (e.g. micro-) and macro-scales. Furthermore, it can be difficult to measure and model the mechanical responses of the individual constituents and constituent interactions in the composites of interest. Current efforts to model such composite materials rely on semi-empirical models in which meso-scale properties are inferredmore » from continuum level testing and modeling. The proposed approach involves removing the difficulties of interrogating and characterizing micro-scale behaviors by scaling-up the problem to work with macro-scale composites, with the intention of developing testing and modeling capabilities that will be applicable to the mesoscale. This approach assumes that the physical mechanisms governing the responses of the composites on the meso-scale are reproducible on the macro-scale. Working on the macro-scale simplifies the quantification of composite constituents and constituent interactions so that efforts can be focused on developing material models and the testing techniques needed for calibration and validation. Other benefits to working with macro-scale composites include the ability to engineer and manufacture—potentially using additive manufacturing techniques—composites that will support the application of advanced measurement techniques such as digital volume correlation and three-dimensional computed tomography imaging, which would aid in observing and quantifying complex behaviors that are exhibited in the macro-scale composites of interest. Ultimately, the goal of this new approach is to develop a meso-scale composite modeling framework, applicable to many composite materials, and the corresponding macroscale testing and test data interrogation techniques to support model calibration.« less

Effect of reinforcement phase on the mechanical property of tungsten nanocomposite synthesized by spark plasma sintering

DOE PAGES

Lee, Jin -Kyu; Kim, Song -Yi; Ott, Ryan T.; ...

2015-07-15

Nanostructured tungsten composites were fabricated by spark plasma sintering of nanostructured composite powders. The composite powders, which were synthesized by mechanical milling of tungsten and Ni-based alloy powders, are comprised of alternating layers of tungsten and metallic glass several hundred nanometers in size. The mechanical behavior of the nanostructured W composite is similar to pure tungsten, however, in contrast to monolithic pure tungsten, some macroscopic compressive plasticity accompanies the enhanced maximum strength up to 2.4 GPa by introducing reinforcement. As a result, we have found that the mechanical properties of the composites strongly depend on the uniformity of the nano-grainedmore » tungsten matrix and reinforcement phase distribution.« less

Nonlinear laminate analysis for metal matrix fiber composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Sinclair, J. H.

1981-01-01

A nonlinear laminate analysis is described for predicting the mechanical behavior (stress-strain relationships) of angleplied laminates in which the matrix is strained nonlinearly by both the residual stress and the mechanical load and in which additional nonlinearities are induced due to progressive fiber fractures and ply relative rotations. The nonlinear laminate analysis (NLA) is based on linear composite mechanics and a piece wise linear laminate analysis to handle the nonlinear responses. Results obtained by using this nonlinear analysis on boron fiber/aluminum matrix angleplied laminates agree well with experimental data. The results shown illustrate the in situ ply stress-strain behavior and synergistic strength enhancement.

Mechanical Properties of Graphene Nanoplatelet/Carbon Fiber/Epoxy Hybrid Composites: Multiscale Modeling and Experiments

NASA Technical Reports Server (NTRS)

Hadden, C. M.; Klimek-McDonald, D. R.; Pineda, E. J.; King, J. A.; Reichanadter, A. M.; Miskioglu, I.; Gowtham, S.; Odegard, G. M.

2015-01-01

Because of the relatively high specific mechanical properties of carbon fiber/epoxy composite materials, they are often used as structural components in aerospace applications. Graphene nanoplatelets (GNPs) can be added to the epoxy matrix to improve the overall mechanical properties of the composite. The resulting GNP/carbon fiber/epoxy hybrid composites have been studied using multiscale modeling to determine the influence of GNP volume fraction, epoxy crosslink density, and GNP dispersion on the mechanical performance. The hierarchical multiscale modeling approach developed herein includes Molecular Dynamics (MD) and micromechanical modeling, and it is validated with experimental testing of the same hybrid composite material system. The results indicate that the multiscale modeling approach is accurate and provides physical insight into the composite mechanical behavior. Also, the results quantify the substantial impact of GNP volume fraction and dispersion on the transverse mechanical properties of the hybrid composite while the effect on the axial properties is shown to be insignificant.

Mechanical Properties of Graphene Nanoplatelet/Carbon Fiber/Epoxy Hybrid Composites: Multiscale Modeling and Experiments

NASA Technical Reports Server (NTRS)

Hadden, C. M.; Klimek-McDonald, D. R.; Pineda, E. J.; King, J. A.; Reichanadter, A. M.; Miskioglu, I.; Gowtham, S.; Odegard, G. M.

2015-01-01

Because of the relatively high specific mechanical properties of carbon fiber/epoxy composite materials, they are often used as structural components in aerospace applications. Graphene nanoplatelets (GNPs) can be added to the epoxy matrix to improve the overall mechanical properties of the composite. The resulting GNP/carbon fiber/epoxy hybrid composites have been studied using multiscale modeling to determine the influence of GNP volume fraction, epoxy crosslink density, and GNP dispersion on the mechanical performance. The hierarchical multiscale modeling approach developed herein includes Molecular Dynamics (MD) and micromechanical modeling, and it is validated with experimental testing of the same hybrid composite material system. The results indicate that the multiscale modeling approach is accurate and provides physical insight into the composite mechanical behavior. Also, the results quantify the substantial impact of GNP volume fraction and dispersion on the transverse mechanical properties of the hybrid composite, while the effect on the axial properties is shown to be insignificant.

Mechanical Properties of Graphene Nanoplatelet Carbon Fiber Epoxy Hybrid Composites: Multiscale Modeling and Experiments

NASA Technical Reports Server (NTRS)

Hadden, Cameron M.; Klimek-McDonald, Danielle R.; Pineda, Evan J.; King, Julie A.; Reichanadter, Alex M.; Miskioglu, Ibrahim; Gowtham, S.; Odegard, Gregory M.

2015-01-01

Because of the relatively high specific mechanical properties of carbon fiber/epoxy composite materials, they are often used as structural components in aerospace applications. Graphene nanoplatelets (GNPs) can be added to the epoxy matrix to improve the overall mechanical properties of the composite. The resulting GNP/carbon fiber/epoxy hybrid composites have been studied using multiscale modeling to determine the influence of GNP volume fraction, epoxy crosslink density, and GNP dispersion on the mechanical performance. The hierarchical multiscale modeling approach developed herein includes Molecular Dynamics (MD) and micromechanical modeling, and it is validated with experimental testing of the same hybrid composite material system. The results indicate that the multiscale modeling approach is accurate and provides physical insight into the composite mechanical behavior. Also, the results quantify the substantial impact of GNP volume fraction and dispersion on the transverse mechanical properties of the hybrid composite, while the effect on the axial properties is shown to be insignificant.

Progressive Fracture of Composite Structures

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Minnetyan, Levon

2008-01-01

A new approach is described for evaluating fracture in composite structures. This approach is independent of classical fracture mechanics parameters like fracture toughness. It relies on computational simulation and is programmed in a stand-alone integrated computer code. It is multiscale, multifunctional because it includes composite mechanics for the composite behavior and finite element analysis for predicting the structural response. It contains seven modules; layered composite mechanics (micro, macro, laminate), finite element, updating scheme, local fracture, global fracture, stress based failure modes, and fracture progression. The computer code is called CODSTRAN (Composite Durability Structural ANalysis). It is used in the present paper to evaluate the global fracture of four composite shell problems and one composite built-up structure. Results show that the composite shells and the built-up composite structure global fracture are enhanced when internal pressure is combined with shear loads.

Effect of Composite Substrates on the Mechanical Behavior of Brazed Joints in Metal-Composite System

NASA Technical Reports Server (NTRS)

Singh, M.; Morscher, Gregory N.; Shpargel, Tarah; Asthana, Rajiv

2006-01-01

Advanced composite components are being considered for a wide variety of demanding applications in aerospace, space exploration, and ground based systems. A number of these applications require robust integration technologies to join dissimilar materials (metalcomposites) into complex structural components. In this study, three types of composites (C-C, C-SiC, and SiC-SiC) were vacuum brazed to commercially pure Ti using the active metal braze alloy Cusil-ABA (63Ag-35.3Cu-1.75Ti). Composite substrates with as fabricated and polished surfaces were used for brazing. The microstructure and composition of the joint, examined using scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS), showed sound metallurgical bonding in all systems. The butt strap tensile (BST) test was performed on bonded specimens at room and elevated temperatures. Effect of substrate composition, interlaminar properties, and surface roughness on the mechanical properties and failure behavior of joints will be discussed.

Correlation between Mechanical Properties with Specific Wear Rate and the Coefficient of Friction of Graphite/Epoxy Composites

PubMed Central

Alajmi, Mahdi; Shalwan, Abdullah

2015-01-01

The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE), Graphite/Epoxy composites (GE), and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE). The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR) and coefficient of friction (COF) of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs), as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites. PMID:28793431

Correlation between Mechanical Properties with Specific Wear Rate and the Coefficient of Friction of Graphite/Epoxy Composites.

PubMed

Alajmi, Mahdi; Shalwan, Abdullah

2015-07-08

The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE), Graphite/Epoxy composites (GE), and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE). The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR) and coefficient of friction (COF) of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs), as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites.

High-Strength Hybrid Textile Composites with Carbon, Kevlar, and E-Glass Fibers for Impact-Resistant Structures. A Review.

NASA Astrophysics Data System (ADS)

Priyanka, P.; Dixit, A.; Mali, H. S.

2017-11-01

The paper reviews the characterization of high-performance hybrid textile composites and their hybridization effects of composite's behavior. Considered are research works based on the finite-element modeling, simulation, and experimental characterization of various mechanical properties of such composites.

METCAN: The metal matrix composite analyzer

NASA Technical Reports Server (NTRS)

Hopkins, Dale A.; Murthy, Pappu L. N.

1988-01-01

Metal matrix composites (MMC) are the subject of intensive study and are receiving serious consideration for critical structural applications in advanced aerospace systems. MMC structural analysis and design methodologies are studied. Predicting the mechanical and thermal behavior and the structural response of components fabricated from MMC requires the use of a variety of mathematical models. These models relate stresses to applied forces, stress intensities at the tips of cracks to nominal stresses, buckling resistance to applied force, or vibration response to excitation forces. The extensive research in computational mechanics methods for predicting the nonlinear behavior of MMC are described. This research has culminated in the development of the METCAN (METal Matrix Composite ANalyzer) computer code.

Mechanics of Elevated Temperature Fatigue Damage in Fiber-Reinforced Ceramics

DTIC Science & Technology

1993-01-01

Wang and Parvizi- Majidi 117] have measured the frictional shear stress in Nicalon"h(CAS-lI composites; shear stress ranged from 12.4±2.6 for fiber...Parvizi- Majidi . "Mechanical Behavior of NicaloniM Fiber-Reinforced Calcium-Aluminosilicate Matrix Composites," Ceram. Eng. Sci. Proc., 11 [9-101 1607

Analysis of stress-strain, fracture and ductility behavior of aluminum matrix composites containing discontinuous silicon carbide reinforcement

NASA Technical Reports Server (NTRS)

Mcdanels, D. L.

1984-01-01

Mechanical properties and stress-strain behavior for several types of commercially fabricated aluminum matrix composites, containing up to 40 vol % discontinuous SiC whisker, nodule, or particulate reinforcement were evaluated. It was found that the elastic modulus of the composites was isotropic, to be independent of type of reinforcement, and to be controlled solely by the volume percentage of SiC reinforcement present. The yield/tensile strengths and ductility were controlled primarily by the matrix alloy and temper condition. Ductility decreased with increasing reinforcement content, however, the fracture strains observed were higher than those reported in the literature for this type of composite. This increase in fracture strain is attributed to cleaner matrix powder and increased mechanical working during fabrication. Conventional aluminum and titanium structural alloys were compared and have shown that the properties of these low cost, lightweight composites have good potential for application to aerospace structures.

Effect of Interface Structure on Mechanical Properties of Advanced Composite Materials

PubMed Central

Gan, Yong X.

2009-01-01

This paper deals with the effect of interface structures on the mechanical properties of fiber reinforced composite materials. First, the background of research, development and applications on hybrid composite materials is introduced. Second, metal/polymer composite bonded structures are discussed. Then, the rationale is given for nanostructuring the interface in composite materials and structures by introducing nanoscale features such as nanopores and nanofibers. The effects of modifying matrices and nano-architecturing interfaces on the mechanical properties of nanocomposite materials are examined. A nonlinear damage model for characterizing the deformation behavior of polymeric nanocomposites is presented and the application of this model to carbon nanotube-reinforced and reactive graphite nanotube-reinforced epoxy composite materials is shown. PMID:20054466

Properties predictive modeling through the concept of a hybrid interphase existing between phases in contact

NASA Astrophysics Data System (ADS)

Portan, D. V.; Papanicolaou, G. C.

2018-02-01

From practical point of view, predictive modeling based on the physics of composite material behavior is wealth generating; by guiding material system selection and process choices, by cutting down on experimentation and associated costs; and by speeding up the time frame from the research stage to the market place. The presence of areas with different properties and the existence of an interphase between them have a pronounced influence on the behavior of a composite system. The Viscoelastic Hybrid Interphase Model (VHIM), considers the existence of a non-homogeneous viscoelastic and anisotropic interphase having properties depended on the degree of adhesion between the two phases in contact. The model applies for any physical/mechanical property (e.g. mechanical, thermal, electrical and/or biomechanical). Knowing the interphasial variation of a specific property one can predict the corresponding macroscopic behavior of the composite. Moreover, the model acts as an algorithm and a two-way approach can be used: (i) phases in contact may be chosen to get the desired properties of the final composite system or (ii) the initial phases in contact determine the final behavior of the composite system, that can be approximately predicted. The VHIM has been proven, amongst others, to be extremely useful in biomaterial designing for improved contact with human tissues.

Analysis of thermomechanical fatigue of unidirectional titanium metal matrix composites

NASA Technical Reports Server (NTRS)

Mirdamadi, M.; Johnson, W. S.; Bahei-El-din, Y. A.; Castelli, M. G.

1991-01-01

Thermomechanical fatigue (TMF) data was generated for a Ti-15V-3Cr-3Al-3Sn (Ti-15-3) material reinforced with SCS-6 silicon carbide fibers for both in-phase and out-of-phase thermomechanical cycling. Significant differences in failure mechanisms and fatigue life were noted for in-phase and out-of-phase testing. The purpose of the research is to apply a micromechanical model to the analysis of the data. The analysis predicts the stresses in the fiber and the matrix during the thermal and mechanical cycling by calculating both the thermal and mechanical stresses and their rate-dependent behavior. The rate-dependent behavior of the matrix was characterized and was used to calculate the constituent stresses in the composite. The predicted 0 degree fiber stress range was used to explain the composite failure. It was found that for a given condition, temperature, loading frequency, and time at temperature, the 0 degree fiber stress range may control the fatigue life of the unidirectional composite.

Resin Composites Reinforced by Nanoscaled Fibers or Tubes for Dental Regeneration

PubMed Central

Li, Xiaoming; Liu, Wei; Sun, Lianwen; Aifantis, Katerina E.; Yu, Bo; Fan, Yubo; Cui, Fuzhai; Watari, Fumio

2014-01-01

It has been stated clearly that nanofillers could make an enhancement on the mechanical performances of dental composites. In order to address current shortage of traditional dental composites, fillers in forms of nanofibers or nanotubes are broadly regarded as ideal candidates to greatly increase mechanical performances of dental composites with low content of fillers. In this review, the efforts using nanofibers and nanotubes to reinforce mechanical performances of dental composites, including polymeric nanofibers, metallic nanofibers or nanotubes, and inorganic nanofibers or nanotubes, as well as their researches related, are demonstrated in sequence. The first purpose of current paper was to confirm the enhancement of nanofibers or nanotubes' reinforcement on the mechanical performances of dental restorative composite. The second purpose was to make a general description about the reinforcement mechanism of nanofibers and nanotubes, especially, the impact of formation of interphase boundary interaction and nanofibers themselves on the advanced mechanical behaviors of the dental composites. By means of the formation of interface interaction and poststretching nanofibers, reinforced effect of dental composites by sorts of nanofibers/nanotubes has been successfully obtained. PMID:24982894

Hierarchical Simulation of Hot Composite Structures

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Murthy, P. L. N.; Singhal, S. N.

1993-01-01

Computational procedures are described to simulate the thermal and mechanical behavior of high temperature metal matrix composites (HT-MMC) in the following three broad areas: (1) Behavior of HT-MMC's from micromechanics to laminate via Metal Matrix Composite Analyzer (METCAN), (2) tailoring of HT-MMC behavior for optimum specific performance via Metal Matrix Laminate Tailoring (MMLT), and (3) HT-MMC structural response for hot structural components via High Temperature Composite Analyzer (HITCAN). Representative results from each area are presented to illustrate the effectiveness of computational simulation procedures. The sample case results show that METCAN can be used to simulate material behavior such as strength, stress-strain response, and cyclic life in HTMMC's; MMLT can be used to tailor the fabrication process for optimum performance such as that for in-service load carrying capacity of HT-MMC's; and HITCAN can be used to evaluate static fracture and fatigue life of hot pressurized metal matrix composite rings.

Fracture behavior of reinforced aluminum alloy matrix composites using thermal imaging tools

NASA Astrophysics Data System (ADS)

Avdelidis, N. P.; Exarchos, D.; Vazquez, P.; Ibarra-Castanedo, C.; Sfarra, S.; Maldague, X. P. V.; Matikas, T. E.

2016-05-01

In this work the influence of the microstructure at the vicinity of the interface on the fracture behavior of particulate-reinforced aluminum alloy matrix composites (Al/SiCp composites) is studied by using thermographic tools. In particular, infrared thermography was used to monitor the plane crack propagation behavior of the materials. The deformation of solid materials is almost always accompanied by heat release. When the material becomes deformed or is damaged and fractured, a part of the energy necessary to initiate and propagate the damage is transformed in an irreversible way into heat. The thermal camera detects the heat wave, generated by the thermo-mechanical coupling and the intrinsic dissipated energy during mechanical loading of the sample. By using an adapted detector, thermography records the two dimensional "temperature" field as it results from the infrared radiation emitted by the object. The principal advantage of infrared thermography is its noncontact, non-destructive character. This methodology is being applied to characterise the fracture behavior of the particulate composites. Infrared thermography is being used to monitor the plane crack propagation behavior of such materials. Furthermore, an innovative approach to use microscopic measurements using IR microscopic lenses was attempted, in order to enable smaller features (in the micro scale) to be imaged with accuracy and assurance.

Simulating Microfracture In Metal-Matrix Composites

NASA Technical Reports Server (NTRS)

Mital, Subodh K.; Chamis, Christos C.; Gotsis, Pascal K.

1994-01-01

Computational procedures developed for simulating microfracture in metal-matrix/fiber composite materials under mechanical and/or thermal loads at ambient and high temperatures. Procedures evaluate microfracture behavior of composites, establish hierarchies and sequences of fracture modes, and examine influences of compliant layers and partial debonding on properties of composites and on initiation of microfractures in them.

Influence of nanoclay on properties of HDPE/wood composites

Treesearch

Yong Lei; Qinglin Wu; Craig M. Clemons; Fei Yao; Yanjun Xu

2007-01-01

Composites based on high density polyethylene (HDPE), pine flour, and organic clay were made by melt compounding and then injection molding. The influence of clay on crystallization behavior, mechanical properties, water absorption, and thermal stability of HDPE/pine composites was investigated. The HDPE/pine composites containing exfoliated clay were made by a two-...

Variation of mechanical behavior of β-TCP/collagen two phase composite scaffold with mesenchymal stem cell in vitro.

PubMed

Arahira, Takaaki; Todo, Mitsugu

2016-08-01

The primary aim of this study is to characterize the variational behavior of the compressive mechanical property of bioceramic-based scaffolds using stem cells during the cell culture period. β-Tricalcium phosphate (TCP)/collagen two phase composites and β-TCP scaffolds were fabricated using the polyurethane template technique and a subsequent freeze-drying method. Rat bone-marrow mesenchymal stem cells (rMSCs) were then cultured in these scaffolds for up to 28 days. Compression tests of the scaffolds with rMSCs were periodically conducted. Biological properties, such as the cell number, alkaline phosphatase (ALP) activity, and gene expressions of osteogenesis, were evaluated. The microstructural change due to cell growth and the formation of extracellular matrices was examined using a field-emission scanning electron microscope. The compressive property was then correlated with the biological properties and microstructures to understand the mechanism of the variational behavior of the macroscopic mechanical property. The porous collagen structure in the β-TCP scaffold effectively improved the structural stability of the composite scaffold, whereas the β-TCP scaffold exhibited structural instability with the collapse of the porous structure when immersed in a culture medium. The β-TCP/collagen composite scaffold exhibited higher ALP activity and more active generation of osteoblastic markers than the β-TCP scaffold. Copyright © 2016 Elsevier Ltd. All rights reserved.

Parametric Study Of A Ceramic-Fiber/Metal-Matrix Composite

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Hopkins, D. A.; Chamis, C. C.

1992-01-01

Report describes computer-model parametric study of effects of degradation of constituent materials upon mechanical properties of ceramic-fiber/metal-matrix composite material. Contributes to understanding of weakening effects of large changes in temperature and mechanical stresses in fabrication and use. Concerned mainly with influences of in situ fiber and matrix properties upon behavior of composite. Particular attention given to influence of in situ matrix strength and influence of interphase degradation.

Structure, mechanical property and corrosion behaviors of (HA+β-TCP)/Mg-5Sn composite with interpenetrating networks.

PubMed

Wang, X; Li, J T; Xie, M Y; Qu, L J; Zhang, P; Li, X L

2015-11-01

In this paper, a novel (Hydroxyapatite+β-tricalcium phosphate)/Mg-5Sn ((HA+β-TCP)/Mg-5Sn) composite with interpenetrating networks was fabricated by infiltrating Mg-5Sn alloy into porous HA+β-TCP using suction casting technique. The structure, mechanical property and corrosion behaviors of the composite have been evaluated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), mechanical testing, electrochemical and immersion test. It is shown that the molten Mg-5Sn alloy has infiltrated not only into the pores but also into the struts of the HA+β-TCP scaffold to forming a compact composite. The microstructure observation also shows that the Mg alloy contacts to the HA+β-TCP closely, and no reaction layer can be found between Mg-5Sn alloy and scaffold. The ultimate compressive strength of the composite is as high as 176MPa, which is about four fifths of the strength of the Mg-5Sn bulk alloy. The electrochemical and immersion tests indicate that the corrosion resistance of the composite is better than that of the Mg-5Sn bulk alloy. The corrosion products on the composite surface are mainly Mg(OH)2, Ca3(PO4)2 and HA. Appropriate mechanical and corrosion properties of the (HA+β-TCP)/Mg-5Sn composite indicate its possibility for new bone tissue implant materials. Copyright © 2015 Elsevier B.V. All rights reserved.

Coupled multi-disciplinary simulation of composite engine structures in propulsion environment

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Singhal, Surendra N.

1992-01-01

A computational simulation procedure is described for the coupled response of multi-layered multi-material composite engine structural components which are subjected to simultaneous multi-disciplinary thermal, structural, vibration, and acoustic loadings including the effect of hostile environments. The simulation is based on a three dimensional finite element analysis technique in conjunction with structural mechanics codes and with acoustic analysis methods. The composite material behavior is assessed at the various composite scales, i.e., the laminate/ply/constituents (fiber/matrix), via a nonlinear material characterization model. Sample cases exhibiting nonlinear geometrical, material, loading, and environmental behavior of aircraft engine fan blades, are presented. Results for deformed shape, vibration frequency, mode shapes, and acoustic noise emitted from the fan blade, are discussed for their coupled effect in hot and humid environments. Results such as acoustic noise for coupled composite-mechanics/heat transfer/structural/vibration/acoustic analyses demonstrate the effectiveness of coupled multi-disciplinary computational simulation and the various advantages of composite materials compared to metals.

Experimentation and analysis of mechanical behavior modification of titanium matrix composites through controlled fiber placement

NASA Astrophysics Data System (ADS)

Bowman, Cheryl Lynne

Titanium composites reinforced with SiC fibers in a uniaxial direction are being considered for various high temperature applications which require high specific strength or stiffness in the primary loading direction. However the very low tensile and creep strength of these composites in the transverse direction (loading perpendicular to the fiber axis) limits their use in many practical applications. Recent advances in composite fabrication techniques have provided not only better control of fiber volume fraction and distribution, but also the ability to control the relative fiber placement. The goal of this research was produce continuously reinforced SiC/Ti composites with precise fiber arrangement in order to ascertain the significance of fiber arrangements on transverse mechanical properties. In this study, TIMETAL 21S and Ti-6-4 composites reinforced with SCS-6 SiC fibers were produced with six distinct fiber placement arrangements. The effect of fiber placement on uniaxial tensile and creep behaviors was assessed and the results compared to analytical predictions. Consistent with analytical predictions, the fiber arrangements used in this study did not significantly change the longitudinal tensile behavior, but differences were obtained in the transverse loading response. For example, a diamond (non-equilateral triangle) fiber packing was found to have a higher transverse ultimate tensile strength and better transverse creep resistance than a rectangular fiber packing arrangement for a given volume fraction and fiber spacing (within-ply vs. between-ply). Initially this result appeared to be in contrast to previous computational and analytical simulations which predicted more favorable mechanical behavior for rectangular-type arrangements. However, this experimental/predictive conflict was resolved, in part, by simply defining a fiber spacing ratio which could describe both rectangular type and diamond-type arrangements. The computationally efficient Micromechanical Analysis Code based on the Generalized Method of Cells captured the correct behavior trends for these fiber arrangements and thus can be used to estimate the optimum fiber arrangement for a given materials system. Although this research utilized SiC/titanium alloy composites, the results should be relevant to any composite with a continuous reinforcement, a ductile matrix, and a finite fiber/matrix interfacial bond strength.

Mechanical behavior and fatigue performance of SMA short fiber reinforced MMC

NASA Astrophysics Data System (ADS)

Al-Matar, Basem Jawad

The mechanical behavior and performance of Shape Memory Alloy (SMA) short fiber NiTi reinforced Al was experimentally investigated for monotonic and fatigue test Al 6061 NiTi-SiC T6 was superior to unreinforced materials as well as to the reinforced Al T4. Taya three-dimensional model was performed on the monotonic tensile test at room temperature. It showed good agreement with experimental results. In order to utilize the compressive criterion for SMA, the NiTi reinforced Al composite was cooled at -10°C and prestrained at 1.2%. Beyond this limit composite suffered from damage. The net enhancement of SMA effect was around 10 MPa on composite yield stress. Results showed that the elastic constant for the composite did not change with loading and unloading suggesting that the inelastic behavior is plasticity. Further investigation on the inelastic behavior model as damage and/or plasticity by evaluating Poisson's ratio during loading was carried out by Adaptive Image Correlation Technique for Full-Field Strain Measurement. Poisson's ratio increased from around 0.33 to 0.5 demonstrating that it is plasticity that is responsible for the inelastic behavior. Scanning electron microscopy was also used and confirmed model results. The overall damage-behavior was quantified in terms of the post fatigue failure strength for low-cycle fatigue tests. Power law model was best to fit experimental findings.

Effect of Silane Coupling Agent on the Creep Behavior and Mechanical Properties of Carbon Fibers/Acrylonitrile Butadiene Rubber Composites.

PubMed

Choi, Woong-Ki; Park, Gil-Young; Kim, Byoung-Shuk; Seo, Min-Kang

2018-09-01

In this study, we investigated the effect of the silane coupling agent on the relationship between the surface free energy of carbon fibers (CFs) and the mechanical strength of CFs/acrylonitrile butadiene rubber (NBR) composites. Moreover, the creep behavior of the CF/NBR composites at surface energetic point of view were studied. The specific component of the surface free energy of the carbon fibers was found to increase upon grafting of the silane coupling agent, resulting in an increase in the tensile strength of the CF/NBR composites. On the other hand, the compressive creep strength was found to follow a slightly different trend. These results indicate the possible formation of a complex interpenetrating polymer network depending on the molecular size of the organic functional groups of the silane coupling agent.

Mechanical properties and ultrastructural characteristics of a glass fiber-reinforced composite.

PubMed

García Barbero, Alvaro Enrique; Vera González, Vicente; García Barbero, Ernesto; Aliaga Vera, Ignacio

2015-06-01

To examine the ultrastructural characteristics of a fiber-reinforced composite (FRC) and its behavior in vitro as a framework for fixed partial dentures (FPDs). A total of 40 specimens were prepared using extracted teeth fixed in methacrylate blocks as supports for the FPD, then the specimens were divided into four groups depending on whether a retaining box was used to fix the FPD to the support teeth, and on whether a composite pontic was assembled on top of the fibers. Fracture testing was performed in a universal testing machine (1 mm/minute). Fracture strength values and failure types were statistically compared for each group. Using retaining boxes did not improve the mechanical behavior of the restorative system. The weakest element of the system was the composite tooth constructed on top of the FRC.

Tensile and Flexural Properties of Cement Composites Reinforced with Flax Nonwoven Fabrics

PubMed Central

Claramunt, Josep; Ventura, Heura; Fernández-Carrasco, Lucía J; Ardanuy, Mònica

2017-01-01

The aim of this study is to develop a process to produce high-performance cement-based composites reinforced with flax nonwoven fabrics, analyzing the influence of the fabric structure—thickness and entanglement—on mechanical behavior under flexural and tensile loadings. For this purpose, composite with flax nonwoven fabrics with different thicknesses were first prepared and their cement infiltration was evaluated with backscattered electron (BSE) images. The nonwoven fabrics with the optimized thickness were then subjected to a water treatment to improve their stability to humid environments and the fiber-matrix adhesion. For a fixed thickness, the effect of the nonwoven entanglement on the mechanical behavior was evaluated under flexural and direct tension tests. The obtained results indicate that the flax nonwoven fabric reinforcement leads to cement composites with substantial enhancement of ductility. PMID:28772573

Interfacial Micromechanics in Fibrous Composites: Design, Evaluation, and Models

PubMed Central

Lei, Zhenkun; Li, Xuan; Qin, Fuyong; Qiu, Wei

2014-01-01

Recent advances of interfacial micromechanics in fiber reinforced composites using micro-Raman spectroscopy are given. The faced mechanical problems for interface design in fibrous composites are elaborated from three optimization ways: material, interface, and computation. Some reasons are depicted that the interfacial evaluation methods are difficult to guarantee the integrity, repeatability, and consistency. Micro-Raman study on the fiber interface failure behavior and the main interface mechanical problems in fibrous composites are summarized, including interfacial stress transfer, strength criterion of interface debonding and failure, fiber bridging, frictional slip, slip transition, and friction reloading. The theoretical models of above interface mechanical problems are given. PMID:24977189

Mechanical Properties and Fatigue Behavior of Unitized Composite Airframe Structures at Elevated Temperature

DTIC Science & Technology

2016-09-01

investigated. The unitized composite consisted of a polymer matrix composite (PMC) co-cured with a ceramic matrix composite (CMC). The PMC portion...ply non- crimp 3D orthogonal weave composite consisting of a ceramic matrix reinforced with glass fibers. In order to assess the performance and...2.3 Ceramic Matrix Composites ...................................................................................5  2.4 2D vs 3D Reinforcement

Predicting the flexure response of wood-plastic composites from uni-axial and shear data using a finite-element model

Treesearch

Scott E. Hamel; John C. Hermanson; Steven M. Cramer

2014-01-01

Wood-plastic composites (WPCs), commonly used in residential decks and railings, exhibit mechanical behavior that is bimodal, anisotropic, and nonlinear viscoelastic. They exhibit different stress-strain responses to tension and compression, both of which are nonlinear. Their mechanical properties vary with respect to extrusion direction, their deformation under...

Dynamic mechanical analysis and high strain-rate energy absorption characteristics of vertically aligned carbon nanotube reinforced woven fiber-glass composites

USDA-ARS?s Scientific Manuscript database

The dynamic mechanical behavior and energy absorption characteristics of nano-enhanced functionally graded composites, consisting of 3 layers of vertically aligned carbon nanotube (VACNT) forests grown on woven fiber-glass (FG) layer and embedded within 10 layers of woven FG, with polyester (PE) and...

The Shock and Vibration Digest. Volume 18, Number 11

DTIC Science & Technology

1986-11-01

instantaneous clearances for various conductor loadings and weather conditions. Composite insulators are now more widely used. They consists...ter under gunfire. However, their electrical and mechanical behaviors are mote complicated than those of analogous porcelain insulators because...mechanical considerations by discussing recent research papets. Tensile tests on composite insulators have shown that short-term tensile

Mechanical analysis of carbon fiber reinforced shape memory polymer composite for self-deployable structure in space environment

NASA Astrophysics Data System (ADS)

Hong, Seok Bin; Ahn, Yong San; Jang, Joon Hyeok; Kim, Jin-Gyun; Goo, Nam Seo; Yu, Woong-Ryeol

2016-04-01

Shape memory polymer (SMP) is one of smart polymers which exhibit shape memory effect upon external stimuli. Reinforcements as carbon fiber had been used for making shape memory polymer composite (CF-SMPC). This study investigated a possibility of designing self-deployable structures in harsh space condition using CF-SMPCs and analyzed their shape memory behaviors with constitutive equation model.CF-SMPCs were prepared using woven carbon fabrics and a thermoset epoxy based SMP to obtain their basic mechanical properties including actuation in harsh environment. The mechanical and shape memory properties of SMP and CF-SMPCs were characterized using dynamic mechanical analysis (DMA) and universal tensile machine (UTM) with an environmental chamber. The mechanical properties such as flexural strength and tensile strength of SMP and CF-SMPC were measured with simple tensile/bending test and time dependent shape memory behavior was characterized with designed shape memory bending test. For mechanical analysis of CF-SMPCs, a 3D constitutive equation of SMP, which had been developed using multiplicative decomposition of the deformation gradient and shape memory strains, was used with material parameters determined from CF-SMPCs. Carbon fibers in composites reinforced tensile and flexural strength of SMP and acted as strong elastic springs in rheology based equation models. The actuation behavior of SMP matrix and CF-SMPCs was then simulated as 3D shape memory bending cases. Fiber bundle property was imbued with shell model for more precise analysis and it would be used for prediction of deploying behavior in self-deployable hinge structure.

Mechanical behavior of glass and Blackglas{reg_sign} ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stawovy, R.H.; Kampe, S.L.; Curtin, W.A.

Room temperature tensile tests are reported on two low-cost ceramic matrix composite materials, comprised of matrices of Blackglas{reg_sign} and a proprietary glass composition each reinforced with Nicalon{reg_sign} SiC-based fibers. The measured mechanical behaviors, supplemented by post-fracture analysis of fiber pullout and fiber fracture mirrors, are compared in detail to the performance predicted theoretically. This allows for an assessment of the roles of the matrix, fiber strength, residual stresses, fiber geometry, and the fiber/matrix interfacial properties in determining mechanical response. The Blackglas{reg_sign} matrix cracks extensively during processing, and so the mechanical response is controlled by the deformation and fracture of themore » fiber bundle. The interfacial sliding resistance, {tau}, is determined to be {approx} 17 MPa and the in-situ (post-processed) fiber characteristic strength, {sigma}{sub c} is found to be {approx} 2.0 GPa, both similar to values reported in the literature for Nicalon{reg_sign}/CAS-glass systems. For the glass matrix, the unidirectional and cross-ply materials show marked differences in mechanical behavior. In the cross-ply composites, {tau} {approx} 14 MPa and {sigma}{sub c} {approx} 2.9 GPa; in the unidirectional variants, these values were 1.7 MPa and 1.6 GPa, respectively. With these data and other derived micromechanical parameters, the stress-strain and failure point of these materials was predicted using existing models, and excellent agreement with the experiments was obtained. These materials thus perform as expected given the in-situ fiber and interface properties. Notably, the cross-ply glass matrix composites exhibit high fiber strength retention and hence show tensile strengths that are better than other Nicalon{reg_sign}-based materials tested to date.« less

Analysis of linear elasticity and non-linearity due to plasticity and material damage in woven and biaxial braided composites

NASA Astrophysics Data System (ADS)

Goyal, Deepak

Textile composites have a wide variety of applications in the aerospace, sports, automobile, marine and medical industries. Due to the availability of a variety of textile architectures and numerous parameters associated with each, optimal design through extensive experimental testing is not practical. Predictive tools are needed to perform virtual experiments of various options. The focus of this research is to develop a better understanding of linear elastic response, plasticity and material damage induced nonlinear behavior and mechanics of load flow in textile composites. Textile composites exhibit multiple scales of complexity. The various textile behaviors are analyzed using a two-scale finite element modeling. A framework to allow use of a wide variety of damage initiation and growth models is proposed. Plasticity induced non-linear behavior of 2x2 braided composites is investigated using a modeling approach based on Hill's yield function for orthotropic materials. The mechanics of load flow in textile composites is demonstrated using special non-standard postprocessing techniques that not only highlight the important details, but also transform the extensive amount of output data into comprehensible modes of behavior. The investigations show that the damage models differ from each other in terms of amount of degradation as well as the properties to be degraded under a particular failure mode. When compared with experimental data, predictions of some models match well for glass/epoxy composite whereas other's match well for carbon/epoxy composites. However, all the models predicted very similar response when damage factors were made similar, which shows that the magnitude of damage factors are very important. Full 3D as well as equivalent tape laminate predictions lie within the range of the experimental data for a wide variety of braided composites with different material systems, which validated the plasticity analysis. Conclusions about the effect of fiber type on the degree of plasticity induced non-linearity in a +/-25° braid depend on the measure of non-linearity. Investigations about the mechanics of load flow in textile composites bring new insights about the textile behavior. For example, the reasons for existence of transverse shear stress under uni-axial loading and occurrence of stress concentrations at certain locations were explained.

The effect of storage temperature on blue cheese mechanical properties.

PubMed

Joyner Melito, Helen S; Francis, Dorothy; Luzzi, Brooke; Johnson, John R

2018-06-01

Blue cheese is commonly aged for 60 days at 10°C after curing. However, some manufacturers store blue cheese at 4°C and the effect of lower storage temperature on blue cheese final properties is unknown. Thus, the objective of this study was to determine the effect of storage temperature and time on blue cheese mechanical behaviors. Blue cheeses were stored at 4 or 10°C for 77 days after production. Composition and small- and large-strain rheological behaviors were evaluated every 2 weeks of storage. Storage time had significant impact on blue cheese rheological behaviors; storage temperature did not. Large-strain compressive force and viscoelastic moduli decreased with storage time, and the extent of nonlinear viscoelastic behavior increased. These results indicated that sample microstructure likely weakened and was more easily deformed as storage time increased. Overall, blue cheese can be stored at 4-10°C without significant changes to its composition or mechanical behavior. The results of this work can be used by blue cheese manufacturers to better understand the impact of storage time and temperature on blue cheese end quality. Manufacturers can take advantage of the effects of storage time on blue cheese mechanical behaviors to determine how long to age blue cheese to achieve the desired texture. © 2017 Wiley Periodicals, Inc.

On the structure of nonlinear constitutive equations for fiber reinforced composites

NASA Technical Reports Server (NTRS)

Jansson, Stefan

1992-01-01

The structure of constitutive equations for nonlinear multiaxial behavior of transversely isotropic fiber reinforced metal matrix composites subject to proportional loading was investigated. Results from an experimental program were combined with numerical simulations of the composite behavior for complex stress to reveal the full structure of the equations. It was found that the nonlinear response can be described by a quadratic flow-potential, based on the polynomial stress invariants, together with a hardening rule that is dominated by two different hardening mechanisms.

Multiscale Multifunctional Progressive Fracture of Composite Structures

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Minnetyan, L.

2012-01-01

A new approach is described for evaluating fracture in composite structures. This approach is independent of classical fracture mechanics parameters like fracture toughness. It relies on computational simulation and is programmed in a stand-alone integrated computer code. It is multiscale, multifunctional because it includes composite mechanics for the composite behavior and finite element analysis for predicting the structural response. It contains seven modules; layered composite mechanics (micro, macro, laminate), finite element, updating scheme, local fracture, global fracture, stress based failure modes, and fracture progression. The computer code is called CODSTRAN (Composite Durability Structural ANalysis). It is used in the present paper to evaluate the global fracture of four composite shell problems and one composite built-up structure. Results show that the composite shells. Global fracture is enhanced when internal pressure is combined with shear loads. The old reference denotes that nothing has been added to this comprehensive report since then.

Al-TiC composites in situ-processed by ingot metallurgy and rapid solidification technology. Part 2: Mechanical behavior

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tong, X.C.; Fang, H.S.

1998-03-01

In Part 2 of this article, the high-strength Al-Si/TiC composite and the elevated-temperature-resistant Al-Fe(-V-Si)/TiC composite, developed on the basis of the in situ Al-TiC composites (Part 1 of the article), have been evaluated for their room- and elevated-temperature mechanical behavior. The microstructural characteristics of ingot metallurgy (IM) or rapid solidification (RS) Al-Si/TiC and Al-Fe(-V-Si)/TiC composites could be thought of as a combination of the related alloy matrix microstructures and the IM or RS Al/TiC composites. The IM Al/TiC and the Al-Si/TiC composites show superior strength and ductility to the relevant aluminum-based composites. The RS Al/TiC and the Al-Fe-V-Si/TiC exhibit highmore » Young`s moduli and substantial improvements in room- and elevated-temperature tensile properties compared to those of rapidly solidified alloys and conventional composites. The Young`s modulus values of RS Al/TiC and Al-Fe-V-Si/TiC composites are well within Hashin-Shtrikman (H-S) limits, in keeping with the strong interfacial bonding. In the micromechanics approach, the principal strengthening mechanisms for the present dispersed, particle-hardened RS in situ Al-TiC composites would include Orowan strengthening, grain-size and substructure strengthening, and solid-solution strengthening.« less

Progressive delamination in polymer matrix composite laminates: A new approach

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

1992-01-01

A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive delamination in polymer matrix composite laminates. The damage stages are quantified based on physics via composite mechanics while the degradation of the laminate behavior is quantified via the finite element method. The approach accounts for all types of composite behavior, laminate configuration, load conditions, and delamination processes starting from damage initiation, to unstable propagation, and to laminate fracture. Results of laminate fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach.

Fracture modes in off-axis fiber composites

NASA Technical Reports Server (NTRS)

Sinclair, J. H.; Chamis, C. C.

1978-01-01

Criteria were developed for identifying, characterizing, and quantifying fracture modes in high-modulus graphite-fiber/resin unidirectional composites subjected to off-axis tensile loading. Procedures are described which use sensitivity analyses and off-axis data to determine the uniaxial strength of fiber composites. It was found that off-axis composites fail by three fracture modes which produce unique fracture surface characteristics. The stress that dominates each fracture mode and the load angle range of its dominance can be identified. Linear composite mechanics is adequate to describe quantitatively the mechanical behavior of off-axis composites. The uniaxial strengths predicted from off-axis data are comparable to these measured in uniaxial tests.

A Coupled Layerwise Analysis of the Thermopiezoelectric Response of Smart Composite Beams Beams

NASA Technical Reports Server (NTRS)

Lee, H.-J.; Saravanos, D. A.

1995-01-01

Thermal effects are incorporated into previously developed discrete layer mechanics for piezoelectric composite beam structures. The updated mechanics explicitly account for the complete coupled thermoelectromechanical response of smart composite beams. This unified representation leads to an inherent capability to model both the sensory and actuator responses of piezoelectric composite beams in a thermal environment. Finite element equations are developed and numerical results are presented to demonstrate the capability of the current formulation to represent the behavior of both sensory and active smart structures under thermal loadings.

Effect of a solid solution on the steady-state creep behavior of an aluminum matrix composite

NASA Astrophysics Data System (ADS)

Pandey, A. B.; Mishra, R. S.; Mahajan, Y. R.

1996-02-01

The effect of an alloying element, 4 wt pct Mg, on the steady-state creep behavior of an Al-10 vol pct SiCp composite has been studied. The Al-4 wt pct Mg-10 vol pct SiCp composite has been tested under compression creep in the temperature range 573 to 673 K. The steady-state creep data of the composite show a transition in the creep behavior (regions I and II) depending on the applied stress at 623 and 673 K. The low stress range data (region I) exhibit a stress exponent of about 7 and an activation energy of 76.5 kJ mol-1. These values conform to the dislocation-climb-controlled creep model with pipe diffusion as a rate-controlling mechanism. The intermediate stress range data (region II) exhibit high and variable apparent stress exponents, 18 to 48, and activation energy, 266 kJ mol-1, at a constant stress, σ = 50 MPa, for creep of this composite. This behavior can be rationalized using a substructure-invariant model with a stress exponent of 8 and an activation energy close to the lattice self-diffusion of aluminum together with a threshold stress. The creep data of the Al-Mg-A12O3f composite reported by Dragone and Nix also conform to the substructure-invariant model. The threshold stress and the creep strength of the Al-Mg-SiCp, composite are compared with those of the Al-Mg-Al2O3f and 6061 Al-SiCp.w, composites and discussed in terms of the load-transfer mechanism. Magnesium has been found to be very effective in improving the creep resistance of the Al-SiCp composite.

Modulation of mesenchymal stem cell behavior by nano- and micro-sized β-tricalcium phosphate particles in suspension and composite structures

NASA Astrophysics Data System (ADS)

Smoak, Mollie; Hogan, Katie; Kriegh, Lisa; Chen, Cong; Terrell, LeKeith B.; Qureshi, Ammar T.; Todd Monroe, W.; Gimble, Jeffrey M.; Hayes, Daniel J.

2015-04-01

Interest has grown in the use of microparticles and nanoparticles for modifying the mechanical and biological properties of synthetic bone composite structures. Micro- and nano-sized calcium phosphates are of interest for their osteoinductive behavior. Engineered composites incorporating polymers and ceramics, such as poly-l-lactic acid (PLLA) and beta-tricalcium phosphate (β-TCP), for bone tissue regeneration have been well investigated for their proliferative and osteoinductive abilities. Only limited research has been done to investigate the effects of different sizes of β-TCP particles on human mesenchymal stromal cell behavior. As such, the aim of this study was to investigate the modulations of human adipose-derived stem cell (hASCs) behavior within cell/particle and cell/composite systems as functions of particle size, concentration, and exposure time. The incorporation of nanoscale calcium phosphate resulted in improved mechanical properties and osteogenic behavior within the scaffold compared to the microscale calcium phosphate additives. Particle exposure results indicate that cytotoxicity on hASCs correlates inversely with particle size and increases with the increasing exposure time and particle concentration. Composites with increasing β-TCP content, whether microparticles or nanoparticles, were less toxic than colloidal micro- and nano-sized β-TCP particles directly supplied to hASCs. The difference in viability observed as a result of varying exposure route is likely related to the increased cell-particle interactions in the direct exposure compared to the particles becoming trapped within the scaffold/polymer matrix.

Fatigue behavior of a cross-ply metal matrix composite at elevated temperature under strain controlled mode. Master`s thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, L.B.

1994-12-01

This research extends the existing knowledge of cross-ply metal matrix composites (MMC) to include fatigue behavior under strain-controlled fully reversed loading. This study investigated fatigue life, failure modes and damage mechanisms of the SCS-6/Ti-15-3, (O/9O)2s, MMC. The laminate was subjected to fully reversed fatigue at elevated temperature (427 deg C) at various strain levels. Stress, strain and modulus data were analyzed to characterize the macro-mechanical behavior of the composite. Microscopy and fractography were accomplished to identify and characterize the damage mechanisms at the microscopic level. Failure modes varied according to the maximum applied strain level showing either mixed mode (i.e.more » combination of both fiber and matrix dominated modes) or matrix dominated fatigue failures. As expected, higher strain loadings resulted in more ductility of the matrix at failure, evidenced by fracture surface features. For testing of the same composite laminate, the fatigue life under strain controlled mode slightly increased, compared to its load-controlled mode counterpart, using the effective strain range comparison basis. However, the respective fatigue life curves converged in the high cycle region, suggesting that the matrix dominated failure mode produces equivalent predicted fatigue lives for both control modes.« less

Effect of particle morphology of Ni on the mechanical behavior of AZ91E-Ni coated nano Al2O3 composites

NASA Astrophysics Data System (ADS)

Sameer Kumar, D.; Suman, K. N. S.; Poddar, Palash

2017-06-01

The properties of any composite always depend on the bonding between the matrix and reinforcement phases. One way of improving the wettability of reinforcement in a matrix is to apply a layer of coating on reinforcing particles. The present study aims at developing Ni coating on nano Al2O3 ceramic particles and dispersing them in AZ91E magnesium matrix material. The electroless plating method has been employed to coat the particles and semi solid stir casting technique was adopted to prepare the composites. Several weight fractions of dispersed phase are considered to analyze the behavior of the fabricated composites. Field emission scanning electron microscopy (FESEM) and x-ray diffraction analysis has been carried out to investigate the distribution of particles and phase characteristics of the proposed material. The physical and mechanical behavior of the material was examined through density measurements, hardness, elastic modulus, ductility and tensile strength calculations. The metal coating on reinforcement aids to promote metal-metal bonding interface reactions which result in improved properties of the composite. Tensile fractography was carried out under FESEM and presented.

Nonlinear Deformation Behavior of New Braided Composites with Six-axis Yarn Orientations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahn, H.-C.; Yu, W.-R.; Guo, Z.

The braiding technology is one of fabrication methods that can produce three-dimensional fiber preforms. Braided composites have many advantages over other two-dimensional composites such as no delamination, high impact and fatigue properties, near-net shape preform, etc. Due to the undulated yarns in the braided preforms, however, their axial stiffness is lower than that of uni-directional or woven composites. To improve the axial stiffness, the longitudinal axial yarns were already introduced along with the braiding axis (five-axis braiding technology). In this study, we developed a new braided structure using six-axis braiding technology. In addition to braiding and longitudinal axial yarns, transversemore » axial yarn was introduced. New braided composites, so called six-axis braiding composites, were manufactured using ultra high molecular weight polyethylene and epoxy resin and their mechanical properties were characterized. To investigate the mechanical performance of these braided composites according to their manufacturing conditions, a numerical analysis was performed using their unit-cell modeling and finite element analysis. In the analysis the nonlinear deformation behavior will be included.« less

Review: mechanical behavior of metal/ceramic interfaces in nanolayered composites—experiments and modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Nan; Liu, Xiang-Yang

In this study, recent experimental and modeling studies in nanolayered metal/ceramic composites are reviewed, with focus on the mechanical behaviors of metal/nitrides interfaces. The experimental and modeling studies of the slip systems in bulk TiN are reviewed first. Then, the experimental studies of interfaces, including co-deformation mechanism by micropillar compression tests, in situ TEM straining tests for the dynamic process of the co-deformation, thickness-dependent fracture behavior, and interrelationship among the interfacial bonding, microstructure, and mechanical response, are reviewed for the specific material systems of Al/TiN and Cu/TiN multilayers at nanoscale. The modeling studies reviewed cover first-principles density functional theory-based modeling,more » atomistic molecular dynamics simulations, and mesoscale modeling of nanolayered composites using discrete dislocation dynamics. The phase transformation between zinc-blende and wurtzite AlN phases in Al/AlN multilayers at nanoscale is also reviewed. Finally, a summary and perspective of possible research directions and challenges are given.« less

Review: mechanical behavior of metal/ceramic interfaces in nanolayered composites—experiments and modeling

DOE PAGES

Li, Nan; Liu, Xiang-Yang

2017-11-03

In this study, recent experimental and modeling studies in nanolayered metal/ceramic composites are reviewed, with focus on the mechanical behaviors of metal/nitrides interfaces. The experimental and modeling studies of the slip systems in bulk TiN are reviewed first. Then, the experimental studies of interfaces, including co-deformation mechanism by micropillar compression tests, in situ TEM straining tests for the dynamic process of the co-deformation, thickness-dependent fracture behavior, and interrelationship among the interfacial bonding, microstructure, and mechanical response, are reviewed for the specific material systems of Al/TiN and Cu/TiN multilayers at nanoscale. The modeling studies reviewed cover first-principles density functional theory-based modeling,more » atomistic molecular dynamics simulations, and mesoscale modeling of nanolayered composites using discrete dislocation dynamics. The phase transformation between zinc-blende and wurtzite AlN phases in Al/AlN multilayers at nanoscale is also reviewed. Finally, a summary and perspective of possible research directions and challenges are given.« less

Microstructure and Strain Rate Effects on the Mechanical Behavior of Particle Reinforced Epoxy-Based Reactive Materials

DTIC Science & Technology

2011-12-01

LIST OF TABLES 2.1 Experimentally measured mechanical properties of pure epoxy and Ni+ Al powder -reinforced composites...for the same quantity of Cu , Ni, and Al deposited . Figure taken from [31]. stronger reactivity of Cu with metals also caused clusters to form. In the...Experimentally measured mechanical properties of pure epoxy and Ni+ Al powder -reinforced composites. Table data is from [14] Material Density Measured E

Mechanical properties, morphology, and hydrolytic degradation behavior of polylactic acid / natural rubber blends

NASA Astrophysics Data System (ADS)

Buys, Y. F.; Aznan, A. N. A.; Anuar, H.

2018-01-01

Due to its biodegradability and renewability, polylactic acid (PLA) has been receiving enormous attention as a potential candidate to replace petroleum based polymers. However, PLA has limitation due to its inherent brittleness. In order to overcome this limitation, blending PLA with elastomeric materials such as natural rubber (NR) are commonly reported. In previous, several researches on PLA/NR blend had been reported, with most of them evaluated the mechanical properties. On the other hand, study of degradation behavior is significance of importance, as controlling materials degradation is required in some applications. This research studied the effect of blend composition on mechanical properties, morphology development, and hydrolytic degradation behavior of PLA/NR blends. Various compositions of PLA/NR blends were prepared by melt blending technique. Tensile test and impact test of the blends were performed to evaluate the mechanical properties. Addition of NR improved the elongation at break and impact strength of the blends, but reduced the tensile strength and stiffness of the specimens. Dynamic Mechanical Analysis (DMA) measurements of the blends displayed two peaks at temperature -70˚C which corresponded to T g of NR and 65˚C which corresponded to T g of PLA. Field Emission Scanning Electron Microscopy (FE-SEM) micrograph of 70/30 PLA/NR specimen also showed two distinct phases, which lead to indication that PLA/NR blends are immiscible. Hydrolytic degradation behavior was evaluated by measuring the remaining weight of the samples immersed in sodium hydroxide solution for a predetermined times. It was shown that the degradation behavior of PLA/NR blends is affected by composition of the blends, with 100 PLA and 70/30 PLA/NR blend showed the fastest degradation rate and 100 NR displayed the slowest one.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang, L. L.; Wang, Y. D.; Ren, Y.

Microstructure evolution, mechanical behaviors of cold rolled Ti-Nb alloys with different Nb contents subjected to different heat treatments were investigated. Here, optical microstructure and phase compositions of Ti-Nb alloys were characterized using optical microscopy and X-ray diffractometre, while mechanical behaviors of Ti-Nb alloys were examined by using tension tests. Stress-induced martensitic transformation in a Ti-30. at%Nb binary alloy was in-situ explored by synchrotron-based high-energy X-ray diffraction (HE-XRD). The results obtained suggested that mechanical behavior of Ti-Nb alloys, especially Young's modulus was directly dependent on chemical compositions and heat treatment process. According to the results of HE-XRD, α"-V1 martensite generated priormore » to the formation of α"-V2 during loading and a partial reversible transformation from α"-V1 to β phase was detected while α"-V2 tranformed to β completely during unloading.« less

Influence of Stacking Sequence and Notch Angle on the Charpy Impact Behavior of Hybrid Composites

NASA Astrophysics Data System (ADS)

Behnia, S.; Daghigh, V.; Nikbin, K.; Fereidoon, A.; Ghorbani, J.

2016-09-01

The low-velocity impact behavior of hybrid composite laminates was investigated. The epoxy matrix was reinforced with aramid, glass, basalt, and carbon fabrics using the hand lay-up technique. Different stacking sequences and notch angles were and notch angles considered and tested using a Charpy impact testing machine to study the hybridization and notch angle effects on the impact response of the hybrid composites. The energy absorption capability of specimens with different stacking sequences and notch angles is compared and discussed. It is shown that the hybridization can enhance the mechanical performance of composite materials.

Effects of Fiber Coating Composition on Mechanical Behavior of Silicon Carbide Fiber-Reinforced Celsian Composites

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.; Elderidge, Jeffrey I.

1998-01-01

Celsian matrix composites reinforced with Hi-Nicalon fibers, precoated with a dual layer of BN/SiC by chemical vapor deposition in two separate batches, were fabricated. Mechanical properties of the composites were measured in three-point flexure. Despite supposedly identical processing, the composite panels fabricated with fibers coated in two batches exhibited substantially different mechanical behavior. The first matrix cracking stresses (sigma(sub mc)) of the composites reinforced with fibers coated in batch 1 and batch 2 were 436 and 122 MPa, respectively. This large difference in sigma(sub mc) was attributed to differences in fiber sliding stresses(tau(sub friction)), 121.2+/-48.7 and 10.4+/-3.1 MPa, respectively, for the two composites as determined by the fiber push-in method. Such a large difference in values of tau(sub friction) for the two composites was found to be due to the difference in the compositions of the interface coatings. Scanning Auger microprobe analysis revealed the presence of carbon layers between the fiber and BN, and also between the BN and SiC coatings in the composite showing lower tau(sub friction). This resulted in lower sigma(sub mc) in agreement with the ACK theory. The ultimate strengths of the two composites, 904 and 759 MPa, depended mainly on the fiber volume fraction and were not significantly effected by tau(sub friction) values, as expected. The poor reproducibility of the fiber coating composition between the two batches was judged to be the primary source of the large differences in performance of the two composites.

Mechanical and time-dependent behavior of wood-plastic composites subjected to tension and compression

Treesearch

Scott E. Hamel; John C. Hermanson; Steven M. Cramer

2012-01-01

The thermoplastics within wood—plastic composites (WPCs) are known to experience significant time-dependent deformation or creep. In some formulations, creep deformation can be twice as much as the initial quasi-static strain in as little as 4 days. While extensive work has been done on the creep behavior of pure polymers, little information is available on the...

Stress Rupture Behavior of Silicon Carbide Coated, Low Modulus Carbon/Carbon Composites. M.S. Thesis

NASA Technical Reports Server (NTRS)

Rozak, Gary A.; Wallace, John F.

1988-01-01

The disadvantages of carbon-carbon composites, in addition to the oxidation problem, are low thermal expansion, expensive fabrication procedures, and poor off axis properties. The background of carbon-carbon composites, their fabrication, oxidation, oxidation protection and mechanical testing in flexure are discussed.

Novel phase diagram behavior and materials design in heterostructural semiconductor alloys

PubMed Central

Holder, Aaron M.; Siol, Sebastian; Ndione, Paul F.; Peng, Haowei; Deml, Ann M.; Matthews, Bethany E.; Schelhas, Laura T.; Toney, Michael F.; Gordon, Roy G.; Tumas, William; Perkins, John D.; Ginley, David S.; Gorman, Brian P.; Tate, Janet; Zakutayev, Andriy; Lany, Stephan

2017-01-01

Structure and composition control the behavior of materials. Isostructural alloying is historically an extremely successful approach for tuning materials properties, but it is often limited by binodal and spinodal decomposition, which correspond to the thermodynamic solubility limit and the stability against composition fluctuations, respectively. We show that heterostructural alloys can exhibit a markedly increased range of metastable alloy compositions between the binodal and spinodal lines, thereby opening up a vast phase space for novel homogeneous single-phase alloys. We distinguish two types of heterostructural alloys, that is, those between commensurate and incommensurate phases. Because of the structural transition around the critical composition, the properties change in a highly nonlinear or even discontinuous fashion, providing a mechanism for materials design that does not exist in conventional isostructural alloys. The novel phase diagram behavior follows from standard alloy models using mixing enthalpies from first-principles calculations. Thin-film deposition demonstrates the viability of the synthesis of these metastable single-phase domains and validates the computationally predicted phase separation mechanism above the upper temperature bound of the nonequilibrium single-phase region. PMID:28630928

Novel phase diagram behavior and materials design in heterostructural semiconductor alloys.

PubMed

Holder, Aaron M; Siol, Sebastian; Ndione, Paul F; Peng, Haowei; Deml, Ann M; Matthews, Bethany E; Schelhas, Laura T; Toney, Michael F; Gordon, Roy G; Tumas, William; Perkins, John D; Ginley, David S; Gorman, Brian P; Tate, Janet; Zakutayev, Andriy; Lany, Stephan

2017-06-01

Structure and composition control the behavior of materials. Isostructural alloying is historically an extremely successful approach for tuning materials properties, but it is often limited by binodal and spinodal decomposition, which correspond to the thermodynamic solubility limit and the stability against composition fluctuations, respectively. We show that heterostructural alloys can exhibit a markedly increased range of metastable alloy compositions between the binodal and spinodal lines, thereby opening up a vast phase space for novel homogeneous single-phase alloys. We distinguish two types of heterostructural alloys, that is, those between commensurate and incommensurate phases. Because of the structural transition around the critical composition, the properties change in a highly nonlinear or even discontinuous fashion, providing a mechanism for materials design that does not exist in conventional isostructural alloys. The novel phase diagram behavior follows from standard alloy models using mixing enthalpies from first-principles calculations. Thin-film deposition demonstrates the viability of the synthesis of these metastable single-phase domains and validates the computationally predicted phase separation mechanism above the upper temperature bound of the nonequilibrium single-phase region.

Novel phase diagram behavior and materials design in heterostructural semiconductor alloys

DOE PAGES

Holder, Aaron M.; Siol, Sebastian; Ndione, Paul F.; ...

2017-06-07

Structure and composition control the behavior of materials. Isostructural alloying is historically an extremely successful approach for tuning materials properties, but it is often limited by binodal and spinodal decomposition, which correspond to the thermodynamic solubility limit and the stability against composition fluctuations, respectively. We show that heterostructural alloys can exhibit a markedly increased range of metastable alloy compositions between the binodal and spinodal lines, thereby opening up a vast phase space for novel homogeneous single-phase alloys. We distinguish two types of heterostructural alloys, that is, those between commensurate and incommensurate phases. Because of the structural transition around the criticalmore » composition, the properties change in a highly nonlinear or even discontinuous fashion, providing a mechanism for materials design that does not exist in conventional isostructural alloys. The novel phase diagram behavior follows from standard alloy models using mixing enthalpies from first-principles calculations. Furthermore, thin-film deposition demonstrates the viability of the synthesis of these metastable single-phase domains and validates the computationally predicted phase separation mechanism above the upper temperature bound of the nonequilibrium single-phase region.« less

Mechanical Reinforcement, Shapestabilization and Thermal Improvement of Phase-Change Energy Storage Materials Using Graphene Oxide Aerogel

NASA Astrophysics Data System (ADS)

Schuman, Yue Xu

Paraffin is known as a good energy storage phase change material (PCM) because of its high energy storage capacity and low cost. However, the leakage of liquid paraffin beyond its melting point and its low thermal conductivity hinder applications of paraffin in energy storage systems. Recently, nanomaterials have been used to create PCM composites in order to enhance their thermal properties while shape stabilizing the PCMs. However, fundamental studies on the material structures and mechanical behavior of the thermally enhanced PCM composites are limited especially at the nanoscale. In this study, we developed a PCM composite using graphene oxide aerogel (GOxA) as the reinforcing 3D network. The GOxA functions thermally as a heat transfer path and mechanically as a nanofiller to reinforce the PCM matrix. We characterized the morphology, the crystal and molecular structures as well as the multiscale mechanical and thermal behavior of the GOxA-PCM composite to evaluate the role of GOxA in the PCM composite. The molecular and diffraction characterizations imply that the GOxA network may affect the paraffin's crystallization, potentially forming an interfacial phase at the surfaces of GOxA. Furthermore, the mechanical properties were studied using nanoindentation at the nano/microscale and a digital durometer at the macroscale from 25degree C to 80 degree C. The mechanical characterizations show that the GOxA-PCM composite is 3 7x harder than pure paraffin and maintains significant strength even above paraffin's melting point due to the support from the GoxA. Moreover, the composite is much less strain-rate sensitive than paraffin. The reinforcement via GOxA is much beyond the prediction by the rule of mixture, implying a strong GOxA-paraffin interfacial bonding. Finally, a thermal scanning microscopy (SThM) along with AFM was used to study the thermal properties at microscale. AFM and thermal images indicate that GOxA-PCM has a better thermal conductivity. The latent heats and thermal conductivities were analyzed using DSC and TPS at the macroscale. Results imply that there might be an interphase between the paraffin and the GOxA resulting in a greater latent heat storage ability and better thermal conductivity of the GOxA-PCM. We believe this is the first fundamental study on the mechanical and thermal behaviors of paraffin and GOxA-PCM composite at the multiscale. The enhancement in hardness, latent heat, and thermal conductivity are expected to aid the analysis and design of thermal energy storage composites with higher performance in the future.

Gallium containing composites as a tunable material to understand neuronal behavior under variable stiffness and radiation conditions.

PubMed

Berg, Nora G; Pearce, Brady L; Rohrbaugh, Nathaniel; Jiang, Lin; Nolan, Michael W; Ivanisevic, Albena

2017-02-01

We report a composite biomaterial containing nanostructured GaOOH and Matrigel™ that can be modulated with respect to its stiffness and radiosensitization properties. A variety of concentrations of GaOOH were added to the composite to alter the mechanical properties of the material as well as to tune the radiosensitizing properties to the composite. PC-12 cells were used to study the combined effects of different stimuli on cell behavior. NGF was given to the cells to record their morphology as well as viability. An increase in the substrate stiffness caused an increase in neurite outgrowth but a decrease in cell viability. In addition, increasing the radiation dose decreased neurite outgrowth but increased cell viability when radiosensitizing particles were present. A subtractive effect between radiosensitizing and mechanical stimuli was observed when PC-12 cells were grown on the GaOOH containing composite. Copyright © 2016 Elsevier B.V. All rights reserved.

Electrical and mechanical behavior of PMN-PT/CNT based polymer composite film for energy harvesting

NASA Astrophysics Data System (ADS)

Das, Satyabati; Biswal, Asutya Kumar; Parida, Kalpana; Choudhary, R. N. P.; Roy, Amritendu

2018-01-01

The pyrochlore-free 30-PMN-PT/CNT/PVDF based piezoelectric flexible composite film has been synthesized for potential application in piezoelectric energy harvesting. Electrical characterization reveals that the maximum output voltage and current generated by the 30 vol.% PMN-PT/CNT/PVDF composite is ∼4 V and 30 nA respectively, comparable with the available literature. Further, impedance analysis has revealed a significant improvement in permittivity at low frequency and high temperature with a minimal dielectric loss. AC conductivity behavior fits well with Johnscher's universal power law that predicts the motion of the charge carriers is translational with sudden hopping. The Nyquist plots indicate the contributions of both grain and grain boundaries at lower temperature (25-100 °C) and additional electrode effect of higher temperature (100-150 °C) on the capacitive and resistive properties of the composite. Mechanical characterization of the composite shows an increase in Young's modulus of 705 MPa compared to 597 MPa in pure PVDF.

Computer modeling of the mechanical behavior of composites -- Interfacial cracks in fiber-reinforced materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schmauder, S.; Haake, S.; Mueller, W.H.

Computer modeling of materials and especially modeling the mechanical behavior of composites became increasingly popular in the past few years. Among them are examples of micromechanical modeling of real structures as well as idealized model structures of linear elastic and elasto-plastic material response. In this paper, Erdogan`s Integral Equation Method (IEM) is chosen as an example for a powerful method providing principle insight into elastic fracture mechanical situations. IEM or, alternatively, complex function techniques sometimes even allow for deriving analytical solutions such as in the case of a circumferential crack along a fiber/matrix interface. The analytical formulae of this interfacemore » crack will be analyzed numerically and typical results will be presented graphically.« less

A constitutive model for developing blood clots with various compositions and their nonlinear viscoelastic behavior.

PubMed

van Kempen, Thomas H S; Donders, Wouter P; van de Vosse, Frans N; Peters, Gerrit W M

2016-04-01

The mechanical properties determine to a large extent the functioning of a blood clot. These properties depend on the composition of the clot and have been related to many diseases. However, the various involved components and their complex interactions make it difficult at this stage to fully understand and predict properties as a function of the components. Therefore, in this study, a constitutive model is developed that describes the viscoelastic behavior of blood clots with various compositions. Hereto, clots are formed from whole blood, platelet-rich plasma and platelet-poor plasma to study the influence of red blood cells, platelets and fibrin, respectively. Rheological experiments are performed to probe the mechanical behavior of the clots during their formation. The nonlinear viscoelastic behavior of the mature clots is characterized using a large amplitude oscillatory shear deformation. The model is based on a generalized Maxwell model that accurately describes the results for the different rheological experiments by making the moduli and viscosities a function of time and the past and current deformation. Using the same model with different parameter values enables a description of clots with different compositions. A sensitivity analysis is applied to study the influence of parameter variations on the model output. The relative simplicity and flexibility make the model suitable for numerical simulations of blood clots and other materials showing similar behavior.

Microstructure-failure mode correlations in braided composites

NASA Technical Reports Server (NTRS)

Filatovs, G. J.; Sadler, Robert L.; El-Shiekh, Aly

1992-01-01

Explication of the fracture processes of braided composites is needed for modeling their behavior. Described is a systematic exploration of the relationship between microstructure, loading mode, and micro-failure mechanisms in carbon/epoxy braided composites. The study involved compression and fracture toughness tests and optical and scanning electron fractography, including dynamic in-situ testing. Principal failure mechanisms of low sliding, buckling, and unstable crack growth are correlated to microstructural parameters and loading modes; these are used for defining those microstructural conditions which are strength limiting.

Ultrasonic NDE and mechanical testing of fiber placement composites

NASA Astrophysics Data System (ADS)

Liu, Zhanjie; Fei, Dong; Hsu, David K.; Dayal, Vinay; Hale, Richard D.

2002-05-01

A fiber placed composite, especially with fiber steering, has considerably more complex internal structure than a laminate laid up from unidirectional prepreg tapes. In this work, we performed ultrasonic imaging of ply interfaces of fiber placed composite laminates, with an eye toward developing a tool for evaluating their quality. Mechanical short-beam shear tests were also conducted on both nonsteered and steered specimens to examine their failure behavior and its relationship to the structural defects indicated by ultrasonic imaging.

Synchrotron Microtomography Reveals the Fine Three-Dimensional Porosity of Composite Polysaccharide Aerogels

PubMed Central

Ghafar, Abdul; Parikka, Kirsti; Tenkanen, Maija; Suuronen, Jussi-Petteri

2017-01-01

This study investigates the impact of ice-templating conditions on the morphological features of composite polysaccharide aerogels in relation to their mechanical behavior and aims to get a better insight into the parameters governing these properties. We have prepared polysaccharide aerogels of guar galactomannan (GM) and tamarind seed xyloglucan (XG) by enzymatic oxidation with galactose oxidase (GaO) to form hydrogels, followed by conventional and unidirectional ice-templating (freezing) methods and lyophilization to form aerogels. Composite polysaccharide aerogels were prepared by incorporating nanofibrillated cellulose (NFC) into polysaccharide solutions prior to enzymatic oxidation and gel formation; such a cross linking technique enabled the homogeneous distribution of the NFC reinforcement into the gel matrix. We conducted phase-enhanced synchrotron X-ray microtomography (XMT) scans and visualized the internal microstructure of the aerogels in three-dimensional (3D) space. Volume-weighted pore-size and pore-wall thickness distributions were quantitatively measured and correlated to the aerogels’ mechanical properties regarding ice-templating conditions. Pore-size distribution and orientation depended on the ice-templating methods and the NFC reinforcement that significantly determined the mechanical and shape-recovery behavior of the aerogels. The results obtained will guide the design of the microporous structure of polysaccharide aerogels with optimal morphology and mechanical behavior for life-sciences applications. PMID:28773235

A multi-scale and multi-field coupling nonlinear constitutive theory for the layered magnetoelectric composites

NASA Astrophysics Data System (ADS)

Xu, Hao; Pei, Yongmao; Li, Faxin; Fang, Daining

2018-05-01

The magnetic, electric and mechanical behaviors are strongly coupled in magnetoelectric (ME) materials, making them great promising in the application of functional devices. In this paper, the magneto-electro-mechanical fully coupled constitutive behaviors of ME laminates are systematically studied both theoretically and experimentally. A new probabilistic domain switching function considering the surface ferromagnetic anisotropy and the interface charge-mediated effect is proposed. Then a multi-scale multi-field coupling nonlinear constitutive model for layered ME composites is developed with physical measureable parameters. The experiments were performed to compare the theoretical predictions with the experimental data. The theoretical predictions have a good agreement with experimental results. The proposed constitutive relation can be used to describe the nonlinear multi-field coupling properties of both ME laminates and thin films. Several novel coupling experimental phenomena such as the electric-field control of magnetization, and the magnetic-field tuning of polarization are observed and analyzed. Furthermore, the size-effect of the electric tuning behavior of magnetization is predicted, which demonstrates a competition mechanism between the interface strain-mediated effect and the charge-driven effect. Our study offers deep insight into the coupling microscopic mechanism and macroscopic properties of ME layered composites, which is benefit for the design of electromagnetic functional devices.

Effect of chemical composition and microstructure on the mechanical behavior of fish scales from Megalops Atlanticus.

PubMed

Gil-Duran, S; Arola, D; Ossa, E A

2016-03-01

This paper presents an experimental study of the composition, microstructure and mechanical behavior of scales from the Megalops Atlanticus (Atlantic tarpon). The microstructure and composition were evaluated by Scanning Electron Microscopy (SEM) and RAMAN spectroscopy, respectively. The mechanical properties were evaluated in uniaxial tension as a function of position along the length of the fish (head, mid-length and tail). Results showed that the scales are composed of collagen and hydroxyapatite, and these constituents are distributed within three well-defined layers from the bottom to the top of the scale. The proportion of these layers with respect to the total scale thickness varies radially. The collagen fibers are arranged in plies with different orientations and with preferred orientation in the longitudinal direction of the fish. Results from the tensile tests showed that scales from Megalops Atlanticus exhibit variations in the elastic modulus as a function of body position. Additional testing performed with and without the highly mineralized top layers of the scale revealed that the mechanical behavior is anisotropic and that the highest strength was exhibited along the fish length. Furthermore, removing the top mineralized layers resulted in an increase in the tensile strength of the scale. Copyright © 2015 Elsevier Ltd. All rights reserved.

Investigation on mechanical properties of basalt composite fabrics (experiment study)

NASA Astrophysics Data System (ADS)

Talebi Mazraehshahi, H.; Zamani, H.

2010-06-01

To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1). Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2). Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3). Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4). Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one material with another, the effect of weight must be considered. Weight measurement showed that the replacement of glass fabric reinforcement with basalt fabric has little effect on weight. Investigation also shows that mechanical behavior of basalt fabric is higher than glass fabric. This is due to the excellent mechanical properties of the ballast fabric such as Young modulus and strength in compare with the glass fabric. Figure1 shows the samples which used for tensile testing in warp direction.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panwar, Ranvir Singh, E-mail: ranvir.panwar@thapar.edu; Pandey, O.P., E-mail: oppandey@thapar.edu

Particulate reinforced aluminum metal matrix composite is in high demand in automobile industry where the operational conditions vary from low to high temperature. In order to understand the wear mode at elevated temperature, this study was planned. For this purpose we developed a metal matrix composite containing aluminum alloy (LM13) as matrix and zircon sand as particulate reinforcement by stir casting process. Different amounts of zircon sand (5, 10, 15 and 20 wt.%) were incorporated in the matrix to study the effect of reinforcement on the wear resistance. Dispersion of zircon sand particles in the matrix was confirmed by usingmore » optical microscopy. Sliding wear tests were done to study the durability of the composite with respect to the base alloy. The effects of load and temperature on wear behavior from room temperature to 300 Degree-Sign C were studied to understand the wear mechanism deeply. Surface morphology of the worn surfaces after the wear tests as well as wear debris was observed under scanning electron microscope. Mild to severe wear transition was noticed in tests at high temperature and high load. However, there is interesting change in wear behavior of the composite near the critical temperature of the composite. All the observed behavior has been explained with reference to the observed microstructure of the wear track and debris. - Highlights: Black-Right-Pointing-Pointer Good interfacial bonding between zircon sand particles and Al matrix was observed. Black-Right-Pointing-Pointer The effect of temperature on the wear behavior of LM13/Zr composites was studied. Black-Right-Pointing-Pointer Wear resistance of the composite was improved with addition of zircon sand. Black-Right-Pointing-Pointer Transition temperature from mild to severe wear also improved in composite. Black-Right-Pointing-Pointer SEM analysis of the tracks and debris was done to establish wear mechanism.« less

Effect of space exposure of some epoxy matrix composites on their thermal expansion and mechanical properties (AO 138-8)

NASA Technical Reports Server (NTRS)

Jabs, Heinrich

1991-01-01

The experiment objectives are: to detect a variation of the coefficient of thermal expansion (CTE) of composite samples; to detect an evolution of mechanical properties; to compare the behavior of two epoxy resins. The CTE is measured by interferometric method in a vacuum chamber. The following mechanical tests are achieved on the samples: interlaminar shear strength; flexural strength; flatwise tensile strength. The results are reported.

Thermomechanical Fatigue Behavior of a Silicon Carbide Fiber-Reinforced Calcium Aluminosilicate Glass-Ceramic Matrix Composite.

DTIC Science & Technology

1992-08-01

space applications. Prior to being used to replace current metal superalloys and monolithic ceramics, the mechanical and thermal properties of CMCs...many investigations of the general mechanical properties of ceramic composites have been performed (see sources 2-10 for a briej sampling), the room...Review of Materials Science, Vol. 17, 1987, pp. 341-383. 7 Thouless, M.D., and Evans, A.G., "Effects of Pull-Out on the Mechanical Properties of

Inter-wall bridging induced peeling of multi-walled carbon nanotubes during tensile failure in aluminum matrix composites.

PubMed

Chen, Biao; Li, Shufeng; Imai, Hisashi; Umeda, Junko; Takahashi, Makoto; Kondoh, Katsuyoshi

2015-02-01

In situ scanning electron microscopy (SEM) observation of a tensile test was performed to investigate the fracturing behavior of multi-walled carbon nanotubes (MWCNTs) in powder metallurgy Al matrix composites. A multiple peeling phenomenon during MWCNT fracturing was clearly observed. Its formation mechanism and resultant effect on the composite strength were examined. Through transition electron microscopy characterizations, it was observed that defective structures like inter-wall bridges cross-linked adjacent walls of MWCNTs. This structure was helpful to improve the inter-wall bonding conditions, leading to the effective load transfer between walls and resultant peeling behaviors of MWCNTs. These results might provide new understandings of the fracturing mechanisms of carbon nanotube reinforcements for designing high-performance nanocomposites. Copyright © 2014 Elsevier Ltd. All rights reserved.

The hygroscopic behavior of plant fibres: a review

NASA Astrophysics Data System (ADS)

Célino, Amandine; Freour, Sylvain; Jacquemin, Frederic; Casari, Pascal

2013-12-01

Environmental concern has resulted in a renewed interest in bio-based materials. Among them, plant fibres are perceived as an environmentally friendly substitute to glass fibres for the reinforcement of composites, particularly in automotive engineering. Due to their wide availability, low cost, low density, high-specific mechanical properties and eco-friendly image, they are increasingly being employed as reinforcements in polymer matrix composites. Indeed, their complex microstructure as a composite material makes plant fibre a really interesting and challenging subject to study. Research subjects about such fibres are abundant because there are always some issues to prevent their use at large scale (poor adhesion, variability, low thermal resistance, hydrophilic behavior). The choice of natural fibres rather than glass fibres as filler yields a change of the final properties of the composite. One of the most relevant differences between the two kinds of fibre is their response to humidity. Actually, glass fibres are considered as hydrophobic whereas plant fibres have a pronounced hydrophilic behavior. Composite materials are often submitted to variable climatic conditions during their lifetime, including unsteady hygroscopic conditions. However, in humid conditions, strong hydrophilic behaviour of such reinforcing fibres leads to high level of moisture absorption in wet environments. This results in the structural modification of the fibres and an evolution of their mechanical properties together with the composites in which they are fitted in. Thereby, the understanding of these moisture absorption mechanisms as well as the influence of water on the final properties of these fibres and their composites is of great interest to get a better control of such new biomaterials. This is the topic of this review paper.

Mechanical behavior of carbon-carbon composites

NASA Technical Reports Server (NTRS)

Rozak, G. A.

1984-01-01

A general background, test plan, and some results of preliminary examinations of a carbon-carbon composite material are presented with emphasis on mechanical testing and inspection techniques. Experience with testing and evaluation was gained through tests of a low modulus carbon-carbon material, K-Karb C. The properties examined are the density - 1.55 g/cc; four point flexure strength in the warp - 137 MPa (19,800 psi) and the fill - 95.1 MPa (13,800 psi,) directions; and the warp interlaminar shear strength - 14.5 MPa (2100 psi). Radiographic evaluation revealed thickness variations and the thinner areas of the composite were scrapped. The ultrasonic C-scan showed attenuation variations, but these did not correspond to any of the physical and mechanical properties measured. Based on these initial tests and a survey of the literature, a plan has been devised to examine the effect of stress on the oxidation behavior, and the strength degradation of coated carbon-carbon composites. This plan will focus on static fatigue tests in the four point flexure mode in an elevated temperature, oxidizing environment.

Numerical Simulation of Thermal Response and Ablation Behavior of a Hybrid Carbon/Carbon Composite

NASA Astrophysics Data System (ADS)

Zhang, Bai; Li, Xudong

2017-09-01

The thermal response and ablation behavior of a hybrid carbon/carbon (C/C) composite are studied herein by using a numerical model. This model is based on the energy- and mass-conservation principles as well as on the calculation of the thermophysical properties of materials. The thermal response and ablation behavior are simulated from the perspective of the matrix and fiber components of a hybrid C/C composite. The thermophysical properties during ablation are calculated, and a moving boundary is implemented to consider the recession of the ablation surface. The temperature distribution, thermophysical properties, char layer thickness, linear ablation rate, mass flow rate of the pyrolysis gases, and mass loss of the hybrid C/C composite are quantitatively predicted. This numerical study describing the thermal response and ablation behavior provides a fundamental understanding of the ablative mechanism of a hybrid C/C composite, serving as a reference and basis for further designs and optimizations of thermoprotective materials.

Numerical Simulation of Thermal Response and Ablation Behavior of a Hybrid Carbon/Carbon Composite

NASA Astrophysics Data System (ADS)

Zhang, Bai; Li, Xudong

2018-06-01

The thermal response and ablation behavior of a hybrid carbon/carbon (C/C) composite are studied herein by using a numerical model. This model is based on the energy- and mass-conservation principles as well as on the calculation of the thermophysical properties of materials. The thermal response and ablation behavior are simulated from the perspective of the matrix and fiber components of a hybrid C/C composite. The thermophysical properties during ablation are calculated, and a moving boundary is implemented to consider the recession of the ablation surface. The temperature distribution, thermophysical properties, char layer thickness, linear ablation rate, mass flow rate of the pyrolysis gases, and mass loss of the hybrid C/C composite are quantitatively predicted. This numerical study describing the thermal response and ablation behavior provides a fundamental understanding of the ablative mechanism of a hybrid C/C composite, serving as a reference and basis for further designs and optimizations of thermoprotective materials.

A finite element framework for multiscale/multiphysics analysis of structures with complex microstructures

NASA Astrophysics Data System (ADS)

Varghese, Julian

This research work has contributed in various ways to help develop a better understanding of textile composites and materials with complex microstructures in general. An instrumental part of this work was the development of an object-oriented framework that made it convenient to perform multiscale/multiphysics analyses of advanced materials with complex microstructures such as textile composites. In addition to the studies conducted in this work, this framework lays the groundwork for continued research of these materials. This framework enabled a detailed multiscale stress analysis of a woven DCB specimen that revealed the effect of the complex microstructure on the stress and strain energy release rate distribution along the crack front. In addition to implementing an oxidation model, the framework was also used to implement strategies that expedited the simulation of oxidation in textile composites so that it would take only a few hours. The simulation showed that the tow architecture played a significant role in the oxidation behavior in textile composites. Finally, a coupled diffusion/oxidation and damage progression analysis was implemented that was used to study the mechanical behavior of textile composites under mechanical loading as well as oxidation. A parametric study was performed to determine the effect of material properties and the number of plies in the laminate on its mechanical behavior. The analyses indicated a significant effect of the tow architecture and other parameters on the damage progression in the laminates.

A methodology for developing anisotropic AAA phantoms via additive manufacturing.

PubMed

Ruiz de Galarreta, Sergio; Antón, Raúl; Cazón, Aitor; Finol, Ender A

2017-05-24

An Abdominal Aortic Aneurysm (AAA) is a permanent focal dilatation of the abdominal aorta at least 1.5 times its normal diameter. The criterion of maximum diameter is still used in clinical practice, although numerical studies have demonstrated the importance of biomechanical factors for rupture risk assessment. AAA phantoms could be used for experimental validation of the numerical studies and for pre-intervention testing of endovascular grafts. We have applied multi-material 3D printing technology to manufacture idealized AAA phantoms with anisotropic mechanical behavior. Different composites were fabricated and the phantom specimens were characterized by biaxial tensile tests while using a constitutive model to fit the experimental data. One composite was chosen to manufacture the phantom based on having the same mechanical properties as those reported in the literature for human AAA tissue; the strain energy and anisotropic index were compared to make this choice. The materials for the matrix and fibers of the selected composite are, respectively, the digital materials FLX9940 and FLX9960 developed by Stratasys. The fiber proportion for the composite is equal to 0.15. The differences between the composite behavior and the AAA tissue are small, with a small difference in the strain energy (0.4%) and a maximum difference of 12.4% in the peak Green strain ratio. This work represents a step forward in the application of 3D printing technology for the manufacturing of AAA phantoms with anisotropic mechanical behavior. Copyright © 2017 Elsevier Ltd. All rights reserved.

Multifunctional Flexible Composites Based on Continuous Carbon Nanotube Fiber

DTIC Science & Technology

2014-07-28

fibers [1] The mechanical and electrical behavior of carbon nanotube fibers spun continuously from an aerogel is discussed. These fibers exhibit moderate...loading, demonstrates their potential for sensing applications in advanced composite materials. Insight into the failure behavior of the aerogel -spun...nanotube fibers is reported-the aerogel -spun fibers are observed to undergo mild to severe kinking due to tensile failure. This kinking is attributed to

Model-Based Experimental Development of Passive Compliant Robot Legs from Fiberglass Composites

PubMed Central

Lin, Shang-Chang; Hu, Chia-Jui; Lin, Pei-Chun

2015-01-01

We report on the methodology of developing compliant, half-circular, and composite robot legs with designable stiffness. First, force-displacement experiments on flat cantilever composites made by one or multifiberglass cloths are executed. By mapping the cantilever mechanics to the virtual spring model, the equivalent elastic moduli of the composites can be derived. Next, by using the model that links the curved beam mechanics back to the virtual spring, the resultant stiffness of the composite in a half-circular shape can be estimated without going through intensive experimental tryouts. The overall methodology has been experimentally validated, and the fabricated composites were used on a hexapod robot to perform walking and leaping behaviors. PMID:27065748

Tribological behavior of Al-WC nano-composites fabricated by ultrasonic cavitation assisted stir-cast method

NASA Astrophysics Data System (ADS)

Pal, Arpan; Poria, Suswagata; Sutradhar, Goutam; Sahoo, Prasanta

2018-03-01

In the present study, the effects of WC nano-particles content on the microstructure, hardness, wear, and friction behavior of aluminum matrix composites are investigated. Al-WC nano composites with varying wt% of WC (0, 1, 1.5, and 2) are fabricated using ultrasonic cavitation assisted stir-cast method. The microstructure of the nano-composite samples is analyzed using optical microscopy and scanning electron microscopy. Elemental composition is determined by energy dispersive x-ray analysis. Vicker’s microhardness test is performed in different locations on the composite sample surface with a load of 50 gf and 10s dwell time. Wear and friction of the composites under dry sliding is studied using a pin-on-disk tribotester for varying normal load (10–40 N) and sliding speed (0.1–0.4 m/s). Uniform distribution of nano-WC is observed over composite surface without noticeable clustering. Reinforcement of nano-WC particles improves wear resistance and frictional behavior of the composite. Hardness is seen to increase with increase in wt% of nano-particles. Wear behavior of composites depends on formation of layers over the surface mixed with oxidized debris and counter-face particles. Wear mechanism changes from adhesion to abrasion with increase in wt% of hard nano particles.

Characterization, Long-Term Behavior Evaluation and Thermomechanical Properties of Untreated and Treated Flax Fiber-Reinforced Composites

NASA Astrophysics Data System (ADS)

Amiri, Ali

In recent years there has been a resurgence of interest in the usage of natural fiber reinforced composites in more advanced structural applications. Consequently, the need for improving their mechanical properties as well as service life and long-term behavior modeling and predictions has arisen. In a step towards further development of these materials, in this study, two newly developed biobased resins, derived from soybean oil, methacrylated epoxidized sucrose soyate and double methacrylated epoxidized sucrose soyate are combined with untreated and alkaline treated flax fiber to produce novel biocomposites. Vinyl ester reinforced with flax fiber is used as control in addition to comparing properties of biobased composites against commercial pultruded composites. Effects of alkaline treatment of flax fiber as well as addition of 1% acrylic resin to vinyl ester and the two mentioned biobased resins on mechanical properties are studied. Properties are evaluated in short-term and also, after being exposed to accelerated weathering (i.e. UV and moisture). Moreover, long-term creep of these novel biobased composites and effect of fiber and matrix treatment on viscoelastic behavior is investigated using Time-temperature superposition (TTS) principle. Based on the results of this study, the TTS provides an accelerated method for evaluation of mechanical properties of biobased composites, and satisfactory master curves are achieved by use of this principle. Also, fiber and matrix treatments were effective in increasing mechanical properties of biobased composites in short-term, and treatments delayed the creep response and slowed the process of creep in composites under study in the steady state region. Overall, results of this study reveal the successful production of biocomposites having properties that meet or exceed those of conventional pultruded members while maintaining high biocontent. Composites using treated flax fiber and newly developed resins showed less degradation in properties after accelerated weather exposure. Procedures and methods developed throughout this study, as well as results presented are essential to further development of these novel materials and utilizing them in more advanced structural applications. Results presented in this dissertation have been published as 5 peer reviewed journal articles, 2 book chapters and have been presented in 6 national and international conferences.

Polymeric Additives For Graphite/Epoxy Composites

NASA Technical Reports Server (NTRS)

Kourtides, D. A.; Nir, Z.

1990-01-01

Report describes experimental studies of properties of several graphite/epoxy composites containing polymeric additives as flexibilizing or toughening agents. Emphasizes effects of brominated polymeric additives (BPA's) with or without carboxy-terminated butadiene acrylonitrile rubber. Reviews effects of individual and combined additives on fracture toughnesses, environmental stabilities, hot/wet strengths, thermomechanical behaviors, and other mechanical properties of composites.

An investigation of the compressive strength of PRD-49-3/Epoxy composites

NASA Technical Reports Server (NTRS)

Kulkarni, S. V.; Rice, J. S.; Rosen, B. W.

1973-01-01

The development of unidirectional fiber composite materials is discussed. The mechanical and physical properties of the materials are described. Emphasis is placed in analyzing the compressive behavior of composite materials and developing methods for increasing compressive strength. The test program for evaluating the various procedures for improving compressive strength are reported.

A New Approach to Improve the Water Absorption Behavior of Flax Fibers Reinforced Soy-based Composites

USDA-ARS?s Scientific Manuscript database

Flax fibers are often used in reinforced composites which have exhibited numerous advantages such as high mechanical properties, low density and biodegradability. On the other hand, the hydrophilic nature of flax fiber is a major problem. In this study, we prepared the soybean oil based composites...

Analysis of stress-strain, fracture, and ductility behavior of aluminum maxtrix composites containing discontinuous silicon carbide reinforcement

NASA Technical Reports Server (NTRS)

Mcdanels, D. L.

1985-01-01

Mechanical properties and stress-strain behavior were evaluated for several types of commercially fabricated aluminum matrix composites, containing up to 40 vol pct discontinuous SiC whisker, nodule, or particulate reinforcement. The elastic modulus of the composites was found to be isotropic, to be independent of type of reinforcement, and to be controlled solely by the volume percentage of SiC reinforcement present. The yield/tensile strengths and ductility were controlled primarily by the matrix alloy and temper condition. Type and orientation of reinforcement had some effect on the strengths of composites, but only for those in which the whisker reinforcement was highly oriented. Ductility decreased with increasing reinforcement content; however, the fracture strains observed were higher than those reported in the literature for this type of composite. This increase in fracture strain was probably attributable to cleaner matrix powder, better mixing, and increased mechanical working during fabrication. Comparison of properties with conventional aluminum and titanium structural alloys showed that the properties of the low-cost, lightweight composites demonstrated very good potential for application to aerospace structures.

Simulation of Mechanical Behavior and Damage of a Large Composite Wind Turbine Blade under Critical Loads

NASA Astrophysics Data System (ADS)

Tarfaoui, M.; Nachtane, M.; Khadimallah, H.; Saifaoui, D.

2018-04-01

Issues such as energy generation/transmission and greenhouse gas emissions are the two energy problems we face today. In this context, renewable energy sources are a necessary part of the solution essentially winds power, which is one of the most profitable sources of competition with new fossil energy facilities. This paper present the simulation of mechanical behavior and damage of a 48 m composite wind turbine blade under critical wind loads. The finite element analysis was performed by using ABAQUS code to predict the most critical damage behavior and to apprehend and obtain knowledge of the complex structural behavior of wind turbine blades. The approach developed based on the nonlinear FE analysis using mean values for the material properties and the failure criteria of Tsai-Hill to predict failure modes in large structures and to identify the sensitive zones.

Fatigue behavior of a cross-ply ceramic matrix composite subjected to tension-tension cycling with hold time. Master`s thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant, S.A.

This study was carried out to investigate the elevated temperature behavior of the SiC-MAS5 cross- ply (O/9O)4S ceramic matrix composite manufactured by Corning Inc. to fatigue with loading waveforms that combine the characteristics of stress rupture and high cycle fatigue. The test results were compiled in the form of S-N (cycles to failure), S-T (exposure time versus cycles to failure), S-S (energy exposure versus cycles to failure), normalized modulus degradation, strain progression, and hysteresis loop progression. From the mechanical behavior demonstrated by these curves, relationships between the effect of the environment and loading waveform were developed. In addition, a post-mortemmore » SEM analysis of the fracture surface was conducted and the results compared to the mechanical behavior.« less

Mechanical and thermal properties of short-coirfiber-reinforced natural rubber/polyethylene composites

NASA Astrophysics Data System (ADS)

Xu, Zh. H.; Kong, Zh. N.

2014-07-01

Natural rubber (NR) and polyethylene (PE) composites were compounded with chemically treated coir fibers by using a heated two-roll mill. Two chemical treatments of the fibers — by silane and sodium hydroxide — were carried out to improve the interfacial adhesion between them and the polyethylene matrix. The mechanical properties of the composites obtained were evaluated and compared with those made from a neat polymer and untreated fibers. The mechanical properties of the composites, such as the tensile strength, Young's modulus, and the elongation at break, were examined, and their shrinkage and flame retardant characteristics were measured. From these experiments, the effect of plasma treatment on the mechanical-physical behavior of coconut-fiberreinforced NR/PE composites was identified. In addition, their thermal characteristics were evaluated, and the results showed a slight decrease in them with increasing content of coir fibers.

Mechanical Behavior and Processing of Aluminum Metal Matrix Composites

DTIC Science & Technology

1992-02-21

SUgeCT TERMS Spray Atomization and Co-Deposition; metal Matrix IS. NUMBER OF PAGeiS Composites; Solidification Mechanisms; Non -Equilibrium...continuously reinforced MMCs, such as: (a) fiber damage, (b) microstructural non -uniformity, (c) fiber to fiber contact, and (d) extensive...of the high reactiJity of lithium. The excessive high temperature reactivity of aluminum-lithium alloys results in the formation of non -protective

Crazing of nanocomposites with polymer-tethered nanoparticles

DOE PAGES

Meng, Dong; Kumar, Sanat K.; Ge, Ting; ...

2016-09-07

The crazing behavior of polymer nanocomposites formed by blending polymer grafted nanoparticles with an entangled polymer melt is studied by molecular dynamics simulations. We focus on the three key differences in the crazing behavior of a composite relative to the pure homopolymer matrix, namely, a lower yield stress, a smaller extension ratio, and a grafted chain length dependent failure stress. The yield behavior is found to be mostly controlled by the local nanoparticle-grafted polymer interfacial energy, with the grafted polymer-polymer matrix interfacial structure being of little to no relevance. Increasing the attraction between nanoparticle core and the grafted polymer inhibitsmore » void nucleation and leads to a higher yield stress. In the craze growth regime, the presence of “grafted chain” sections of ≈100 monomers alters the mechanical response of composite samples, giving rise to smaller extension ratios and higher drawing stresses than for the homopolymer matrix. As a result, the dominant failure mechanism of composite samples depends strongly on the length of the grafted chains, with disentanglement being the dominant mechanism for short chains, while bond breaking is the failure mode for chain lengths >10N e, where N e is the entanglement length.« less

Enhanced nonlinear current-voltage behavior in Au nanoparticle dispersed CaCu 3 Ti 4 O 12 composite films

NASA Astrophysics Data System (ADS)

Chen, Cong; Wang, Can; Ning, Tingyin; Lu, Heng; Zhou, Yueliang; Ming, Hai; Wang, Pei; Zhang, Dongxiang; Yang, Guozhen

2011-10-01

An enhanced nonlinear current-voltage behavior has been observed in Au nanoparticle dispersed CaCu 3Ti 4O 12 composite films. The double Schottky barrier model is used to explain the enhanced nonlinearity in I-V curves. According to the energy-band model and fitting result, the nonlinearity in Au: CCTO film is mainly governed by thermionic emission in the reverse-biased Schottky barrier. This result not only supports the mechanism of double Schottky barrier in CCTO, but also indicates that the nonlinearity of current-voltage behavior could be improved in nanometal composite films, which has great significance for the resistance switching devices.

Analyses of quasi-isotropic composite plates under quasi-static point loads simulating low-velocity impact phenomena

NASA Technical Reports Server (NTRS)

Kelkar, A. D.

1984-01-01

In thin composite laminates, the first level of visible damage occurs in the back face and is called back face spalling. A plate-membrane coupling model, and a finite element model to analyze the large deformation behavior of eight-ply quasi-isotropic circular composite plates under impact type point loads are developed. The back face spalling phenomenon in thin composite plates is explained by using the plate-membrane coupling model and the finite element model in conjunction with the fracture mechanics principles. The experimental results verifying these models are presented. Several conclusions concerning the deformation behavior are reached and discussed in detail.

Tough composite materials: Recent developments

NASA Technical Reports Server (NTRS)

Vosteen, L. F. (Editor); Johnston, N. J. (Editor); Teichman, L. A. (Editor); Blankenship, C. P. (Editor)

1985-01-01

The present volume broadly considers topics in composite fracture toughness and impact behavior characterization, composite system constituent properties and their interrelationships, and matrix systems' synthesis and characterization. Attention is given to the characterization of interlaminar crack growth in composites by means of the double cantilever beam specimen, the characterization of delamination resistance in toughened resin composites, the effect of impact damage and open holes on the compressive strength of tough resin/high strain fiber laminates, the effect of matrix and fiber properties on compression failure mechanisms and impact resistance, the relation of toughened neat resin properties to advanced composite mechanical properties, and constituent and composite properties' relationships in thermosetting matrices. Also treated are the effect of cross-link density on the toughening mechanism of elastomer-modified epoxies, the chemistry of fiber/resin interfaces, novel carbon fibers and their properties, the development of a heterogeneous laminating resin, solvent-resistant thermoplastics, NASA Lewis research in advanced composites, and opportunities for the application of composites in commercial aircraft transport structures.

Multi-layer composite mechanical modeling for the inhomogeneous biofilm mechanical behavior.

PubMed

Wang, Xiaoling; Han, Jingshi; Li, Kui; Wang, Guoqing; Hao, Mudong

2016-08-01

Experiments showed that bacterial biofilms are heterogeneous, for example, the density, the diffusion coefficient, and mechanical properties of the biofilm are different along the biofilm thickness. In this paper, we establish a multi-layer composite model to describe the biofilm mechanical inhomogeneity based on unified multiple-component cellular automaton (UMCCA) model. By using our model, we develop finite element simulation procedure for biofilm tension experiment. The failure limit and biofilm extension displacement obtained from our model agree well with experimental measurements. This method provides an alternative theory to study the mechanical inhomogeneity in biological materials.

Hierarchical nonlinear behavior of hot composite structures

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Chamis, C. C.; Singhal, S. N.

1993-01-01

Hierarchical computational procedures are described to simulate the multiple scale thermal/mechanical behavior of high temperature metal matrix composites (HT-MMC) in the following three broad areas: (1) behavior of HT-MMC's from micromechanics to laminate via METCAN (Metal Matrix Composite Analyzer), (2) tailoring of HT-MMC behavior for optimum specific performance via MMLT (Metal Matrix Laminate Tailoring), and (3) HT-MMC structural response for hot structural components via HITCAN (High Temperature Composite Analyzer). Representative results from each area are presented to illustrate the effectiveness of computational simulation procedures and accompanying computer codes. The sample case results show that METCAN can be used to simulate material behavior such as the entire creep span; MMLT can be used to concurrently tailor the fabrication process and the interphase layer for optimum performance such as minimum residual stresses; and HITCAN can be used to predict the structural behavior such as the deformed shape due to component fabrication. These codes constitute virtual portable desk-top test laboratories for characterizing HT-MMC laminates, tailoring the fabrication process, and qualifying structural components made from them.

Study of the influence of volume fraction of ceramic inclusions in NiCr-TiC composite with columnar structure on its mechanical behavior

NASA Astrophysics Data System (ADS)

Eremina, Galina M.; Smolin, Alexey Yu.; Shilko, Evgeny V.

2017-12-01

Metal-ceramic materials are characterized by high mechanical and tribological properties. The surface treatment of the composite by an electron beam in inert gas plasma leads to a qualitative and quantitative change in its microstructure as well as to a change in mechanical properties of the components: a columnar structure forms in the modified layer. Different treatment regimes result in different concentrations of inclusions in the surface layer. In this paper, the effect of the volume concentration of inclusions on the integral mechanical properties of a dispersion-strengthened NiCr-TiC composite is studied on the basis of 3D numerical simulation. The results of computer simulation show that the change in concentration significantly affects the integral mechanical characteristics of the composite material as well as the nature of the nucleation and development of damages in it.

A Continuum Damage Mechanics Model for the Static and Cyclic Fatigue of Cellular Composites

PubMed Central

Huber, Otto

2017-01-01

The fatigue behavior of a cellular composite with an epoxy matrix and glass foam granules is analyzed and modeled by means of continuum damage mechanics. The investigated cellular composite is a particular type of composite foam, and is very similar to syntactic foams. In contrast to conventional syntactic foams constituted by hollow spherical particles (balloons), cellular glass, mineral, or metal place holders are combined with the matrix material (metal or polymer) in the case of cellular composites. A microstructural investigation of the damage behavior is performed using scanning electron microscopy. For the modeling of the fatigue behavior, the damage is separated into pure static and pure cyclic damage and described in terms of the stiffness loss of the material using damage models for cyclic and creep damage. Both models incorporate nonlinear accumulation and interaction of damage. A cycle jumping procedure is developed, which allows for a fast and accurate calculation of the damage evolution for constant load frequencies. The damage model is applied to examine the mean stress effect for cyclic fatigue and to investigate the frequency effect and the influence of the signal form in the case of static and cyclic damage interaction. The calculated lifetimes are in very good agreement with experimental results. PMID:28809806

Mechanical analysis of CFRP-steel hybrid composites considering the interfacial adhesion

NASA Astrophysics Data System (ADS)

Jang, Jinhyeok; Sung, Minchang; Han, Sungjin; Shim, Wonbo; Yu, Woong-Ryeol

2017-10-01

Recently, hybrid composites of carbon fiber reinforced plastics (CFRP) and steel have attracted great attention from automotive engineers due to their high potential for lightweight and multi-materials structures. Interestingly, such hybrid composites have demonstrated increased breaking strain, i.e., the breaking strain of CFRP in the hybrid was larger than that of single CFRP. As such the mechanical properties of hybrid composites could not be calculated using the rule of mixture. In addition, such increase is strongly dependent on the adhesion between CFRP and steel. In this study, a numerical analysis model was built to investigate the mechanism behind increased breaking strain of CFRP in the hybrid structure. Using cohesive zone model, the adhesion between CFRP and steel was effectively considered. The numerical results showed that the simulated mechanical behavior of the hybrid composites did not change as much as observed in experimental as the interfacial adhesion varied. We will investigate this discrepancy in detail and will report new analysis method suitable for CFRP and steel hybrid composites.

Role of polymeric binders on mechanical behavior and cracking resistance of silicon composite electrodes during electrochemical cycling

NASA Astrophysics Data System (ADS)

Li, Dawei; Wang, Yikai; Hu, Jiazhi; Lu, Bo; Dang, Dingying; Zhang, Junqian; Cheng, Yang-Tse

2018-05-01

This work focuses on understanding the role of various binders, including sodium alginate (SA), Nafion, and polyvinylidene fluoride (PVDF), on the mechanical behavior and cracking resistance of silicon composite electrodes during electrochemical cycling. In situ curvature measurement of bilayer electrodes, consisting of a silicon-binder-carbon black composite layer on a copper foil, is used to determine the effects of binders on bending deformation, elastic modulus, and stress on the composite electrodes. It is found that the lithiation induced curvature and the modulus of the silicon/SA electrodes are larger than those of electrodes with Nafion and PVDF as binders. Although the modulus of Nafion is smaller than that of PVDF, the curvature and the modulus of silicon/Nafion composite are larger than those of silicon/PVDF electrodes. The moduli of all three composites decrease not only during lithiation but also during delithiation. Based on the measured stress and scanning electron microscopy observations of cracking in the composite electrodes, we conclude that the stress required to crack the composite electrodes with SA and Nafion binders is considerably higher than that of the silicon/PVDF electrode during electrochemical cycling. Thus, the cracking resistance of silicon/SA and silicon/Nafion composite electrodes is higher than that of silicon/PVDF electrodes.

Resin composite characterizations following a simplified protocol of accelerated aging as a function of the expiration date.

PubMed

D'Alpino, Paulo Henrique Perlatti; Vismara, Marcus Vinícius Gonçalves; Mello, Luciano Marcelo de Medeiros; Di Hipólito, Vinicius; González, Alejandra Hortencia Miranda; Graeff, Carlos Frederico de Oliveira

2014-07-01

This study evaluated the mechanical, thermal, and morphological characteristics of different classifications of dental composites as a function of the material condition (new, aged and expired). Specimens were obtained according to these factors: Composites: Filtek P60, Filtek Z250, Filtek Z350XT, and Filtek Silorane; and Material conditions: new, aged, and expired. The syringe composites underwent an accelerated aging protocol (Arrhenius model). The flexural strength (FS) and flexural modulus (E) were obtained. The thermogravimetric analysis (TGA) and differential thermal analysis (DTA) were also performed and the glass transition temperature (Tg) and the weight loss calculated. Topographic analysis of the composites was performed under SEM. The material conditions influenced the mechanical properties of the composites. The silorane composite exhibited a characteristic thermal behavior different from that of the methacrylates. In general, the Tg increased after the accelerated aging protocol and decreased for expired ones, compared to the new composites. A significant increase in FS of Filtek Z350XT after aging was accompanied by an increase in the Tg. The filler packings were in accordance with the manufacture׳s information. The topographic aspects of the composites were modified as a function of the material condition. The mechanical properties of the composites following a simplified protocol of accelerated aging varied as a function of the expiration date. The silorane composite presented a characteristic thermal behavior. Although the dental manufacturers may not be able to control variables as storage temperature and transportation conditions, these effects on the composite clinical performance can be minimized if properly considered. Copyright © 2014 Elsevier Ltd. All rights reserved.

NASA-UVA light aerospace alloy and structures technology program (LA(sup 2)ST)

NASA Technical Reports Server (NTRS)

Gangloff, Richard P.; Haviland, John K.; Herakovich, Carl T.; Pilkey, Walter D.; Pindera, Marek-Jerzy; Scully, John R.; Starke, Edgar A., Jr.; Stoner, Glenn E.; Thornton, Earl A.; Wawner, Franklin E., Jr.

1992-01-01

The general objective of the Light Aerospace Alloy and Structures Technology (LA(sup 2)ST) Program is to conduct interdisciplinary graduate student research on the performance of next generation, light weight aerospace alloys, composites, and thermal gradient structures in collaboration with Langley researchers. Specific technical objectives are established for each research project. We aim to produce relevant data and basic understanding of material behavior and microstructure, new monolithic and composite alloys, advanced processing methods, new solid and fluid mechanics analyses, measurement advances, and critically, a pool of educated graduate students for aerospace technologies. Four research areas are being actively investigated, including: (1) Mechanical and Environmental Degradation Mechanisms in Advanced Light Metals and Composites; (2) Aerospace Materials Science; (3) Mechanics of Materials and Composites for Aerospace Structures; and (4) Thermal Gradient Structures.

Discontinuously reinforced intermetallic matrix composites via XD synthesis. [exothermal dispersion

NASA Technical Reports Server (NTRS)

Kumar, K. S.; Whittenberger, J. D.

1992-01-01

A review is given of recent results obtained for discontinuously reinforced intermetallic matrix composites produced using the XD process. Intermetallic matrices investigated include NiAl, multiphase NiAl + Ni2AlTi, CoAl, near-gamma titanium aluminides, and Ll2 trialuminides containing minor amounts of second phase. Such mechanical properties as low and high temperature strength, compressive and tensile creep, elastic modulus, ambient ductility, and fracture toughness are discussed as functions of reinforcement size, shape, and volume fraction. Microstructures before and after deformation are examined and correlated with measured properties. An observation of interest in many of the systems examined is 'dispersion weakening' at high temperatures and high strain rates. This behavior is not specific to the XD process; rather similar observations have been reported in other discontinuous composites. Proposed mechanisms for this behavior are presented.

Influence of internal composition on physicochemical properties of alginate aqueous-core capsules.

PubMed

Ben Messaoud, Ghazi; Sánchez-González, Laura; Probst, Laurent; Desobry, Stéphane

2016-05-01

To enhance physicochemical properties of alginate aqueous-core capsules, conventional strategies were focused in literature on designing composite and coated capsules. In the present study, own effect of liquid-core composition on mechanical and release properties was investigated. Capsules were prepared by dripping a CaCl2 solution into an alginate gelling solution. Viscosity of CaCl2 solution was adjusted by adding cationic, anionic and non-ionic naturally derived polymers, respectively chitosan, xanthan gum and guar gum. In parallel, uniform alginate hydrogels were prepared by different methods (pouring, in situ forming and mixing). Mechanical stability of capsules and plane hydrogels were respectively evaluated by compression experiments and small amplitude oscillatory shear rheology and then correlated. Capsules permeability was evaluated by monitoring diffusion of encapsulated cochineal dye, riboflavin and BSA. The core-shell interactions were investigated by ATR-FTIR. Results showed that inner polymer had an impact on membrane stability and could act as an internal coating or provide mechanical reinforcement. Mechanical properties of alginate capsules were in a good agreement with rheological behavior of plane hydrogels. Release behavior of the entrapped molecules changed considerably. This study demonstrated the importance of aqueous-core composition, and gave new insights for possible adjusting of microcapsules physicochemical properties by modulating core-shell interactions. Copyright © 2016 Elsevier Inc. All rights reserved.

Influence of nanosize clay platelets on the mechanical properties of glass fiber reinforced polyester composites.

PubMed

Jawahar, P; Balasubramanian, M

2006-12-01

Glass fiber reinforced polyester composite and hybrid nanoclay-fiber reinforced composites were prepared by hand lay-up process. The mechanical behavior of these materials and the changes as a result of the incorporation of both nanosize clay and glass fibers were investigated. Composites were prepared with a glass fibre content of 25 vol%. The proportion of the nanosize clay platelets was varied from 0.5 to 2.5 vol%. Hybrid clay-fiber reinforced polyester composite posses better tensile, flexural, impact, and barrier properties. Hybrid clay-fiber reinforced polyester composites also posses better shear strength, storage modulus, and glass transition temperature. The optimum properties were found to be with the hybrid laminates containing 1.5 vol% nanosize clay.

Simulation of Impact Phenomena on the Composite Structures Containing Ceramic Plates and High Entropy Alloys

NASA Astrophysics Data System (ADS)

Geantă, V.; Cherecheș, T.; Lixandru, P.; Voiculescu, I.; Ștefănoiu, R.; Dragnea, D.; Zecheru, T.; Matache, L.

2017-06-01

Due to excellent mechanical properties, high entropy alloys from the system AlxCrFeCoNi can be used successfully to create composite structures containing both metallic and ceramic plates, which resists at dynamic load during high speeds impact (like projectiles, explosion). The paper presents four different composite structures made from a combination of metallic materials and ceramics plates: duralumin-ceramics, duralumin-ceramics-HEA, HEA-ceramics-HEA, HEA-ceramics-duralumin. Numerical simulation of impact behavior of the composite structures was performed by virtual methods, taking into account the mechanical properties of both materials. The best results were obtained using composite structures HEA-ceramics-HEA, HEA-ceramics-duralumin.

Thermoviscoplastic nonlinear constitutive relationships for structural analysis of high temperature metal matrix composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Hopkins, D. A.

1985-01-01

A set of thermoviscoplastic nonlinear constitutive relationships (1VP-NCR) is presented. The set was developed for application to high temperature metal matrix composites (HT-MMC) and is applicable to thermal and mechanical properties. Formulation of the TVP-NCR is based at the micromechanics level. The TVP-NCR are of simple form and readily integrated into nonlinear composite structural analysis. It is shown that the set of TVP-NCR is computationally effective. The set directly predicts complex materials behavior at all levels of the composite simulation, from the constituent materials, through the several levels of composite mechanics, and up to the global response of complex HT-MMC structural components.

The mechanical behavior of nanoscale metallic multilayers: A survey

NASA Astrophysics Data System (ADS)

Zhou, Q.; Xie, J. Y.; Wang, F.; Huang, P.; Xu, K. W.; Lu, T. J.

2015-06-01

The mechanical behavior of nanoscale metallic multilayers (NMMs) has attracted much attention from both scientific and practical views. Compared with their monolithic counterparts, the large number of interfaces existing in the NMMs dictates the unique behavior of this special class of structural composite materials. While there have been a number of reviews on the mechanical mechanism of microlaminates, the rapid development of nanotechnology brought a pressing need for an overview focusing exclusively on a property-based definition of the NMMs, especially their size-dependent microstructure and mechanical performance. This article attempts to provide a comprehensive and up-to-date review on the microstructure, mechanical property and plastic deformation physics of NMMs. We hope this review could accomplish two purposes: (1) introducing the basic concepts of scaling and dimensional analysis to scientists and engineers working on NMM systems, and (2) providing a better understanding of interface behavior and the exceptional qualities the interfaces in NMMs display at atomic scale.

Composite strengthening. [of nonferrous, fiber reinforced alloys

NASA Technical Reports Server (NTRS)

Stoloff, N. S.

1976-01-01

The mechanical behavior of unidirectionally reinforced metals is examined, with particular attention to fabrication techniques for artificial composites and eutectic alloys and to principles of fiber reinforcement. The properties of artificial composites are discussed in terms of strength of fiber composites, strength of ribbon-reinforced composites, crack initiation, crack propagation, and creep behavior. The properties of eutectic composites are examined relative to tensile strength, compressive strength, fracture, high-temperature strength, and fatigue. In the case of artificial composites, parallelism of fibers, good bonding between fibers and matrix, and freedom of fibers from damage are all necessary to ensure superior performance. For many eutectic systems there are stringent boundary conditions relative to melt purity and superheat, atmosphere control, temperature gradient, and growth rate in order to provide near-perfect alignment of the reinforcements with a minimum of growth defects.

Micro-mechanical evaluation of SiC-SiC composite interphase properties and debond mechanisms

DOE PAGES

Kabel, Joey; Yang, Y.; Balooch, Mehdi; ...

2017-07-31

SiC-SiC composites exhibit exceptional high temperature strength and oxidation properties making them an advantageous choice for accident tolerant nuclear fuel cladding. In the present work, small scale mechanical testing along with AFM and TEM analysis were employed to evaluate PyC interphase properties that play a key role in the overall mechanical behavior of the composite. The Mohr-Coulomb formulation allowed for the extraction of the internal friction coefficient and debonding shear strength as a function of the PyC layer thickness, an additional parameter. Here, these results have led to re-evaluation of the Mohr-Coulomb failure criterion and adjustment via a new phenomenologicalmore » equation.« less

The Stress-strain Behavior of Polymer-Nanotube Composites from Molecular Dynamics Simulations

NASA Technical Reports Server (NTRS)

Frankland, S. J. V.; Harik, V. M.; Odegard, G. M.; Brenner, D. W.; Gates, T. S.; Bushnell, Dennis M. (Technical Monitor)

2002-01-01

Stress-strain curves of polymer-carbon nanotube composites are derived from molecular dynamics simulations of a single-walled carbon nanotube embedded in polyethylene. A comparison is made between the response to mechanical loading of a composite with a long, continuous nanotube (replicated via periodic boundary conditions) and the response of a composite with a short, discontinuous nanotube. Both composites are mechanically loaded in the direction of and transverse to the NT axis. The long-nanotube composite shows an increase in the stiffness relative to the polymer and behaves anisotropically under the different loading conditions. The short-nanotube composite shows no enhancement relative to the polymer, most probably because of its low aspect ratio. The stress-strain curves are compared with rule-of-mixtures predictions.

Mineralization behavior and interface properties of BG-PVA/bone composite implants in simulated body fluid.

PubMed

Ma, Yanxuan; Zheng, Yudong; Huang, Xiaoshan; Xi, Tingfei; Lin, Xiaodan; Han, Dongfei; Song, Wenhui

2010-04-01

Due to the non-bioactivity and poor conjunction performance of present cartilage prostheses, the main work here is to develop the bioactive glass-polyvinyl alcohol hydrogel articular cartilage/bone (BG-PVA/bone) composite implants. The essential criterion for a biomaterial to bond with living bone is well-matched mechanical properties as well as biocompatibility and bioactivity. In vitro studies on the formation of a surface layer of carbonate hydroxyl apatite (HCA) and the corresponding variation of the properties of biomaterials are imperative for their clinical application. In this paper, the mineralization behavior and variation of the interface properties of BG-PVA/bone composites were studied in vitro by using simulated body fluid (SBF). The mineralization and HCA layer formed on the interface between the BG-PVA hydrogel and bone in SBF could provide the composites with bioactivity and firmer combination. The compression property, shear strength and interface morphology of BG-PVA/bone composite implants varying with the immersion time in SBF were characterized. Also, the influence laws of the immersion time, content of BG in the composites and aperture of bones to the mineralization behavior and interface properties were investigated. The good mineralization behavior and enhanced conjunction performance of BG-PVA/bone composites demonstrated that this kind of composite implant might be more appropriate cartilage replacements.

Processing, Microstructure, and Mechanical Properties of Interpenetrating Biomorphic Graphite/Copper Composites

NASA Astrophysics Data System (ADS)

Childers, Amanda Esther Sall

Composite properties can surpass those of the individual phases, allowing for the development of advanced, high-performance materials. Bio-inspired and naturally-derived materials have garnered attention as composite constituents due to their inherently efficient and complex structures. Wood-derived ceramics, produced by converting a wood precursor into a ceramic scaffold, can exhibit a wide range of microstructures depending on the wood species, including porosity, pore size and distribution, and connectivity. The focus of this work was to investigate the processing, microstructure, and properties of graphite/copper composites produced using wood-derived graphite scaffolds. Graphite/copper composites combine low specific gravity, high thermal conductivity, and tailorable thermal expansion properties, and due to the non-wetting behavior of copper to graphite, offer a unique system in which mechanically bonded interfaces in composites can be studied. Graphite scaffolds were produced from red oak, beech, and pine precursors using a catalytic pyrolyzation method, resulting in varying types of pore networks. Two infiltration methods were investigated to overcome challenges associated with non-wetting systems: copper electrodeposition and pressure-assisted melt infiltration. The phase distributions, constituent properties, interfacial characteristics, mechanical behavior, and load partitioning of these biomorphic graphite/copper composites were investigated, and were correlated to the wood species. The multi-domain feature sizes in the graphite scaffolds resulted in composites with copper relegated not only to the large, connected channels produced from the transport features in the wood, but also within the smaller, lower aspect ratio fibrous regions of the scaffold. Both features contributed to the mechanical behavior of the composites to varying degrees depending on the wood species. A multi-component predictive model also was developed and used to guide the additive-assisted electroplating of the graphitized scaffold, and helped illuminate the roles of plating additives in macro-sized channels. The model can be adapted for many material systems, sample geometries, and plating conditions to investigate the use of metal electrodeposition as a means of scaffold infiltration. Additionally, X-ray diffraction tomography was used to resolve position-dependent strain in a composite. The results of this nascent capability were discussed with respect to a two-component system under increasing uniaxial load, and compared to the results of conventional volume-averaged measurements.

Technical features and criteria in designing fiber-reinforced composite materials: from the aerospace and aeronautical field to biomedical applications.

PubMed

Gloria, Antonio; Ronca, Dante; Russo, Teresa; D'Amora, Ugo; Chierchia, Marianna; De Santis, Roberto; Nicolais, Luigi; Ambrosio, Luigi

2011-01-01

Polymer-based composite materials are ideal for applications where high stiffness-to-weight and strength-to-weight ratios are required. From aerospace and aeronautical field to biomedical applications, fiber-reinforced polymers have replaced metals, thus emerging as an interesting alternative. As widely reported, the mechanical behavior of the composite materials involves investigation on micro- and macro-scale, taking into consideration micromechanics, macromechanics and lamination theory. Clinical situations often require repairing connective tissues and the use of composite materials may be suitable for these applications because of the possibility to design tissue substitutes or implants with the required mechanical properties. Accordingly, this review aims at stressing the importance of fiber-reinforced composite materials to make advanced and biomimetic prostheses with tailored mechanical properties, starting from the basic principle design, technologies, and a brief overview of composites applications in several fields. Fiber-reinforced composite materials for artificial tendons, ligaments, and intervertebral discs, as well as for hip stems and mandible models will be reviewed, highlighting the possibility to mimic the mechanical properties of the soft and hard tissues that they replace.

METCAN-PC - METAL MATRIX COMPOSITE ANALYZER

NASA Technical Reports Server (NTRS)

Murthy, P. L.

1994-01-01

High temperature metal matrix composites offer great potential for use in advanced aerospace structural applications. The realization of this potential however, requires concurrent developments in (1) a technology base for fabricating high temperature metal matrix composite structural components, (2) experimental techniques for measuring their thermal and mechanical characteristics, and (3) computational methods to predict their behavior. METCAN (METal matrix Composite ANalyzer) is a computer program developed to predict this behavior. METCAN can be used to computationally simulate the non-linear behavior of high temperature metal matrix composites (HT-MMC), thus allowing the potential payoff for the specific application to be assessed. It provides a comprehensive analysis of composite thermal and mechanical performance. METCAN treats material nonlinearity at the constituent (fiber, matrix, and interphase) level, where the behavior of each constituent is modeled accounting for time-temperature-stress dependence. The composite properties are synthesized from the constituent instantaneous properties by making use of composite micromechanics and macromechanics. Factors which affect the behavior of the composite properties include the fabrication process variables, the fiber and matrix properties, the bonding between the fiber and matrix and/or the properties of the interphase between the fiber and matrix. The METCAN simulation is performed as point-wise analysis and produces composite properties which are readily incorporated into a finite element code to perform a global structural analysis. After the global structural analysis is performed, METCAN decomposes the composite properties back into the localized response at the various levels of the simulation. At this point the constituent properties are updated and the next iteration in the analysis is initiated. This cyclic procedure is referred to as the integrated approach to metal matrix composite analysis. METCAN-PC is written in FORTRAN 77 for IBM PC series and compatible computers running MS-DOS. An 80286 machine with an 80287 math co-processor is required for execution. The executable requires at least 640K of RAM and DOS 3.1 or higher. The package includes sample executables which were compiled under Microsoft FORTRAN v. 5.1. The standard distribution medium for this program is one 5.25 inch 360K MS-DOS format diskette. The contents of the diskette are compressed using the PKWARE archiving tools. The utility to unarchive the files, PKUNZIP.EXE, is included. METCAN-PC was developed in 1992.

Property and Microstructural Characterization of Diboride Composites for High Temperature Aerospace Applications

NASA Technical Reports Server (NTRS)

Gusman, Michael I.; Stackpoole, Mairead; Ellerby, Donald T.; Johnson, Sylvia M.; Arnold, Jim (Technical Monitor)

2001-01-01

Previous work on refractory diboride composites has shown these systems to have potential for use in high temperature leading edge applications for reusable reentry vehicles. These composites, based on compositions of HfB2 or ZrB2 with SiC particulate reinforcements, have shown good oxidation resistance in reentry environments. In this work we are investigating the effects of composition and microstructure on properties. Preliminary studies of composite mechanical properties and oxidation behavior will be discussed.

Evaluation of CVI SiC/SiC Composites for High Temperature Applications

NASA Technical Reports Server (NTRS)

Kiser, D.; Almansour, A.; Smith, C.; Gorican, D.; Phillips, R.; Bhatt, R.; McCue, T.

2017-01-01

Silicon carbide fiber reinforced silicon carbide (SiC/SiC) composites are candidate materials for various high temperature turbine engine applications because of their high specific strength and good creep resistance at temperatures of 1400 C (2552 F) and higher. Chemical vapor infiltration (CVI) SiC/SiC ceramic matrix composites (CMC) incorporating Sylramic-iBN SiC fiber were evaluated via fast fracture tensile tests (acoustic emission damage characterization to assess cracking behavior), tensile creep testing, and microscopy. The results of this testing and observed material behavior degradation mechanisms are reviewed.

The effect of surface modification of glass fiber on the performance of poly(lactic acid) composites: Graphene oxide vs. silane coupling agents

NASA Astrophysics Data System (ADS)

Jing, Mengfan; Che, Junjin; Xu, Shuman; Liu, Zhenwei; Fu, Qiang

2018-03-01

In this work, a comparison study was carried out to investigate the efficacy of glass fiber (GF) in reinforcing poly(lactic acid) (PLA) by using traditional silane coupling agents (GF-S) and novel graphene oxide (GF-GO) as surface modifiers. The crystallization behavior of the PLA matrix was investigated by differential scanning calorimetry. The mechanical performances and the thermomechanical properties of the composites were evaluated by uniaxial tensile testing and dynamic mechanical analysis, respectively. For neat GF without any treatment, the poor interfacial adhesion and the sharp shortening of the GF length result in the relatively poor mechanical performances of PLA/GF composites. However, the incorporation of GF-S significantly improves the mechanical strength and keeps relatively good toughness of the composites, while GF-GO exhibits excellent nucleation ability for PLA and could moderately increase the modulus of the composites. The thermomechanical properties of the composites are improved markedly resulting from the crystallinity increase. The different surface modification of glass fiber influences the crystallinity of matrix, the interfacial interaction and the length of fiber, which altogether affect the mechanical performances of the prepared PLA/GF composites.

Achieving "organic compositionality" through self-organization: reviews on brain-inspired robotics experiments.

PubMed

Tani, Jun; Nishimoto, Ryunosuke; Paine, Rainer W

2008-05-01

The current paper examines how compositional structures can self-organize in given neuro-dynamical systems when robot agents are forced to learn multiple goal-directed behaviors simultaneously. Firstly, we propose a basic model accounting for the roles of parietal-premotor interactions for representing skills for goal-directed behaviors. The basic model had been implemented in a set of robotics experiments employing different neural network architectures. The comparative reviews among those experimental results address the issues of local vs distributed representations in representing behavior and the effectiveness of level structures associated with different sensory-motor articulation mechanisms. It is concluded that the compositional structures can be acquired "organically" by achieving generalization in learning and by capturing the contextual nature of skilled behaviors under specific conditions. Furthermore, the paper discusses possible feedback for empirical neuroscience studies in the future.

The effect of altered lignin composition on mechanical properties of CINNAMYL ALCOHOL DEHYDROGENASE (CAD) deficient poplars.

PubMed

Özparpucu, Merve; Gierlinger, Notburga; Burgert, Ingo; Van Acker, Rebecca; Vanholme, Ruben; Boerjan, Wout; Pilate, Gilles; Déjardin, Annabelle; Rüggeberg, Markus

2018-04-01

CAD-deficient poplars enabled studying the influence of altered lignin composition on mechanical properties. Severe alterations in lignin composition did not influence the mechanical properties. Wood represents a hierarchical fiber-composite material with excellent mechanical properties. Despite its wide use and versatility, its mechanical behavior has not been entirely understood. It has especially been challenging to unravel the mechanical function of the cell wall matrix. Lignin engineering has been a useful tool to increase the knowledge on the mechanical function of lignin as it allows for modifications of lignin content and composition and the subsequent studying of the mechanical properties of these transgenics. Hereby, in most cases, both lignin composition and content are altered and the specific influence of lignin composition has hardly been revealed. Here, we have performed a comprehensive micromechanical, structural, and spectroscopic analysis on xylem strips of transgenic poplar plants, which are downregulated for cinnamyl alcohol dehydrogenase (CAD) by a hairpin-RNA-mediated silencing approach. All parameters were evaluated on the same samples. Raman microscopy revealed that the lignin of the hpCAD poplars was significantly enriched in aldehydes and reduced in the (relative) amount of G-units. FTIR spectra indicated pronounced changes in lignin composition, whereas lignin content was not significantly changed between WT and the hpCAD poplars. Microfibril angles were in the range of 18°-24° and were not significantly different between WT and transgenics. No significant changes were observed in mechanical properties, such as tensile stiffness, ultimate stress, and yield stress. The specific findings on hpCAD poplar allowed studying the specific influence of lignin composition on mechanics. It can be concluded that the changes in lignin composition in hpCAD poplars did not affect the micromechanical tensile properties.

Multidisciplinary tailoring of hot composite structures

NASA Technical Reports Server (NTRS)

Singhal, Surendra N.; Chamis, Christos C.

1993-01-01

A computational simulation procedure is described for multidisciplinary analysis and tailoring of layered multi-material hot composite engine structural components subjected to simultaneous multiple discipline-specific thermal, structural, vibration, and acoustic loads. The effect of aggressive environments is also simulated. The simulation is based on a three-dimensional finite element analysis technique in conjunction with structural mechanics codes, thermal/acoustic analysis methods, and tailoring procedures. The integrated multidisciplinary simulation procedure is general-purpose including the coupled effects of nonlinearities in structure geometry, material, loading, and environmental complexities. The composite material behavior is assessed at all composite scales, i.e., laminate/ply/constituents (fiber/matrix), via a nonlinear material characterization hygro-thermo-mechanical model. Sample tailoring cases exhibiting nonlinear material/loading/environmental behavior of aircraft engine fan blades, are presented. The various multidisciplinary loads lead to different tailored designs, even those competing with each other, as in the case of minimum material cost versus minimum structure weight and in the case of minimum vibration frequency versus minimum acoustic noise.

Sintered Intermetallic Reinforced 434L Ferritic Stainless Steel Composites

NASA Astrophysics Data System (ADS)

Upadhyaya, A.; Balaji, S.

2009-03-01

The present study examines the effect of aluminide (Ni3Al, Fe3Al) additions on the sintering behavior of ferritic 434L stainless steels during solid-state sintering (SSS) and supersolidus liquid-phase sintering (SLPS). 434L stainless steel matrix composites containing 5 and 10 wt pct of each aluminide were consolidated at 1200 °C (SSS) and 1400 °C (SLPS). The effects of sintering and aluminide additions on the densification, microstructural evolution, mechanical, tribological, and corrosion behavior of sintered ferritic (434L) stainless steels were investigated. The performances of the 434L-aluminide composites were compared with the straight 434L stainless steels processed at similar conditions. Supersolidus sintering resulted in significant improvement in densification, mechanical, wear, and corrosion resistance in both straight 434L and 434L-aluminide composites. Fe3Al additions to 434L stainless steels result in improved wear resistance without significant degradation of corrosion resistance in 3.56 wt pct NaCl solution.

Thermo-Mechanical Fatigue of Polymer Matrix Composites

DTIC Science & Technology

1994-10-01

MATRIX COMPOSITES by L. H. Strait . - , 4- . [ : ’ . .. N ..::ii Technical Report No. TR 94-12 October 1994 94 11 3 002 Supported by: L.R. Hettche...mnechanical loading is an increasingly common service condition for polymer mnmx composite materials. Unfortunately, little or no information is available...regarding the behavior of polymer composites subject to this loading condition. The present thesis research program was undertaken to evaluate the effects

Advanced Single-Polymer Nanofiber-Reinforced Composite - Towards Next Generation Ultralight Superstrong/Tough Structural Material

DTIC Science & Technology

2015-04-29

AFRL-OSR-VA-TR-2015-0144 ADVANCED SINGLE-POLYMER NANOFIBER-REINFORCED COMPOSITE YURIS DZENIS UNIVERSITY OF NEBRSKA Final Report 04/29/2015... COMPOSITE - TOWARDS NEXT GENERATION ULTRALIGHT SUPERSTRONG/TOUGH STRUCTURAL MATERIAL 5a. CONTRACT NUMBER 5b. GRANT NUMBER FA9550-11-1-0204 5c. PROGRAM...characterize their mechanical behavior and properties; and (3) fabricate and characterize polyimide nanofiber-reinforced composites . Continuous

Thermo-viscoelastic response of graphite/epoxy composites

NASA Technical Reports Server (NTRS)

Lin, Kuen; Hwang, I. H.

1988-01-01

The thermo-viscoelastic behavior of composite material is studied analytically using a special finite-element formulation. Numerical results on stress and deformation histories are obtained for both unnotched and notched graphite/epoxy composites subjected to mechanical and thermal spectrum loads. The results indicate that time-dependent effects are important in composites with matrix-dominated layup orientations. Such effects also strongly depend on the specific environment condition and load spectrum applied.

Thermal degradation behaviors and reaction mechanism of carbon fibre-epoxy composite from hydrogen tank by TG-FTIR.

PubMed

Zhang, Zhi; Wang, Changjian; Huang, Gai; Liu, Haoran; Yang, Shenlin; Zhang, Aifeng

2018-05-28

Thermal degradation behaviors and reaction mechanism of Carbon fibre-epoxy composite, obtained from Chinese widely applied hydrogen storage tank, were studied by thermogravimetry combined with Fourier transform infrared spectrometry at varying heating rates. The pyrolysis of carbon fibre-epoxy composite mainly occurs at 550-750 K. The average value of final residue is 72.42%. The calculated activation energies increase exponentially from 206.27 KJ/mol to 412.98 KJ/mol with the average value of 276.6 KJ/mol. The fourth reaction order model is responsible for the pyrolysis of carbon fibre-epoxy composite. The absorption spectra of the evolved gases provided the information that the main evolved products are H 2 O, CO 2 , CO (acid anhydride, ketone or aldehyde), ε- caprolactam, alcohols and phenol. Moreover, CO group > alcohols > phenol > ε- caprolactam > CO 2  > H 2 O. Epoxy is the main pyrolysis crude material in carbon fibre-epoxy composite. Copyright © 2018 Elsevier B.V. All rights reserved.

Optical and electrical properties of P3HT:graphene composite based devices

NASA Astrophysics Data System (ADS)

Yadav, Anjali; Verma, Ajay Singh; Gupta, Saral Kumar; Negi, Chandra Mohan Singh

2018-04-01

The polymer-carbon derivate composites are well known for their uses and performances in the photovoltaic and optoelectronic industries. In this paper, we synthesis P3HT:graphene composites and discuss their optical and electrical properties. The composites have been prepared by using spin-coating technique onto the glass substrates. It has been found that the incorporation of graphene reduces absorption intensity. However, absorption peak remain unchanged with addition of graphene. The surface morphology studies display homogeneous distribution of graphene with P3HT. Raman studies suggest that chemical structure was not affected by graphene doping. Devices having the structure of glass/ITO/P3HT/ Al and glass ITO/P3HT:graphene/Al were then fabricated. I-V behavior of the fabricated devices was found to be similar to the Schottky diode. ITO/P3HT:graphene/Al structure shows tremendous increase in current values as compared to the ITO/P3HT/Al. Furthermore, charge transport mechanism were studied by analyzing the double logarithmic J-V characteristics curve, which indicates that the current at low voltage follows Ohmic behavior, trap-charge limited conduction (TCLC) mechanism at an intermediate voltage and space charge limited conduction (SCLC) mechanism at sufficiently high voltages.

Tribological and Mechanical Behaviors of Polyamide 6/Glass Fiber Composite Filled with Various Solid Lubricants

PubMed Central

Li, Duxin; Xie, Ying; Li, Wenjuan; You, Yilan; Deng, Xin

2013-01-01

The effects of polytetrafluoroethylene (PTFE), graphite, ultrahigh molecular weight polyethylene (UHMWPE), and their compounds on mechanical and tribological properties of glass-fiber-reinforced polyamide 6 (PA6/GF) were studied. The polymeric materials were blended using twin-screw extruder and subsequently injection molded for test samples. Mechanical properties were investigated in terms of hardness, tensile strength, and impact strength. Friction and wear experiments were run under ambient conditions at a rotating speed of 200 rpm and load of 100 N. The morphologies of the worn surfaces were also observed with scanning electron microscope. The results showed that graphite could increase the tensile strength of PA6/GF-15 composite, but the material became soft. Graphite/UHMWPE complex solid lubricants were effective in increasing the already high impact strength of PA6/GF-15 composite. 5% PTFE gave the maximum reduction in the coefficient of friction. However, PTFE/UHMWPE complex solid lubricants were the best choice for improving both friction and wear behaviors due to the lower friction coefficient and mass wear rate. Moreover, the worn surface of PA6 composites revealed that adhesive wear, abrasive wear, and fatigue wear occurred in this study. PMID:23766687

The Microstructural Design of Trimodal Aluminum Composites

NASA Astrophysics Data System (ADS)

Jiang, Lin; Ma, Kaka; Yang, Hanry; Li, Meijuan; Lavernia, Enrique J.; Schoenung, Julie M.

2014-06-01

Trimodal composites, consisting of nanocrystalline or ultrafine grains (UFGs), coarse grains (CGs), and ceramic particles, were originally formulated to achieve combinations of physical and mechanical properties that are unattainable with the individual phases, such as strength, ductility, and high-strain-rate deformation. The concept of a trimodal structure is both scientifically novel as well as technologically promising because it provides multiple controllable degrees of freedom that allow for extensive microstructure design. The UFGs provide efficient obstacles for dislocation movement, such as grain boundaries and other crystalline defects. The size, distribution, and spatial arrangement of the CGs can be controlled to provide plasticity during deformation. The size, morphology, and distribution of the reinforcement particles can be tailored to attain various engineering and physical properties. Moreover, the interfaces that form among the various phases also help determine the overall behavior of the trimodal composites. In this article, a review is provided to discuss the selection and design of each component in trimodal Al composites. The toughening and strengthening mechanisms in the trimodal composite structure are discussed, paying particular attention to strategies that can be implemented to tailor microstructures for optimal mechanical behavior. Recent results obtained with high-performance trimodal Al composites that contain nanometric reinforcements are also discussed to highlight the ability to control particle-matrix interface characteristics. Finally, a perspective is provided on potential approaches that can be explored to develop the next generation of trimodal composites, and interesting scientific paradigms that evolve from the proposed design strategies are discussed.

Effect of Copper Coated SiC Reinforcements on Microstructure, Mechanical Properties and Wear of Aluminium Composites

NASA Astrophysics Data System (ADS)

Kori, P. S.; Vanarotti, Mohan; Angadi, B. M.; Nagathan, V. V.; Auradi, V.; Sakri, M. I.

2017-08-01

Experimental investigations are carried out to study the influence of copper coated Silicon carbide (SiC) reinforcements in Aluminum (Al) based Al-SiC composites. Wear behavior and mechanical Properties like, ultimate tensile strength (UTS) and hardness are studied in the present work. Experimental results clearly revealed that, an addition of SiC particles (5, 10 and 15 Wt %) has lead in the improvement of hardness and ultimate tensile strength. Al-SiC composites containing the Copper coated SiC reinforcements showed better improvement in mechanical properties compared to uncoated ones. Characterization of Al-SiC composites are carried out using optical photomicrography and SEM analysis. Wear tests are carried out to study the effects of composition and normal pressure using Pin-On Disc wear testing machine. Results suggested that, wear rate decreases with increasing SiC composition, further an improvement in wear resistance is observed with copper coated SiC reinforcements in the Al-SiC metal matrix composites (MMC’s).

Simulation of Fatigue Behavior of High Temperature Metal Matrix Composites

NASA Technical Reports Server (NTRS)

Tong, Mike T.; Singhal, Suren N.; Chamis, Christos C.; Murthy, Pappu L. N.

1996-01-01

A generalized relatively new approach is described for the computational simulation of fatigue behavior of high temperature metal matrix composites (HT-MMCs). This theory is embedded in a specialty-purpose computer code. The effectiveness of the computer code to predict the fatigue behavior of HT-MMCs is demonstrated by applying it to a silicon-fiber/titanium-matrix HT-MMC. Comparative results are shown for mechanical fatigue, thermal fatigue, thermomechanical (in-phase and out-of-phase) fatigue, as well as the effects of oxidizing environments on fatigue life. These results show that the new approach reproduces available experimental data remarkably well.

Molecular-Level Computational Investigation of Mechanical Transverse Behavior of p-Phenylene Terephthalamide (PPTA) Fibers

DTIC Science & Technology

2013-01-01

fabricated today are based on polymer matrix composites containing Kevlarw KM2 reinforcements , the present work will deal with generic PPTA fibers . In...Multi-length scale enriched continuum-level material model for Kevlarw- fiber reinforced polymer-matrix composites”, Journal of Materials...mechanical transverse behavior of p-phenylene terephthalamide (PPTA) fibers Purpose – A series of all-atom molecular-level computational analyses is

Processing, microstructure and mechanics of functionally graded Al A359/SiC(p) composite

NASA Astrophysics Data System (ADS)

Rodriguez-Castro, Ramon

2000-11-01

Metal matrix composites (MMCs) have great promise for high temperature, high strength, wear resistant applications. However, their brittleness has limited their use in load bearing applications. Functionally graded MMCs with a reinforcement concentration higher on the surface than in the interior offer new opportunities, as these materials will have high surface hardness as well as high resistance to crack growth towards the interior. In this dissertation the processing and mechanical properties of a functionally graded MMC are investigated. Rectangular blocks (100 mmx60 mmx50 mm) of functionally graded SiC particulate reinforced aluminum A359 matrix composite were prepared by centrifugal casting techniques. The reinforcement volume fraction profiles varied as the centrifugal force was applied, owing to the different densities of Al and SiC. The casting at 1300 rpm (angular velocity) had a well-mixed, refined microstructure with the maximum SiC volume fraction of 44% near the outer surface of the blocks. This surface exhibited an elevated hardness. The effect of SiC particulate reinforcement on strengthening of A359 Al alloy was experimentally studied by tensile testing specimens prepared from the cast blocks. There was a continuous increase in tensile and yield strength with increasing SiC volume fractions in the range of 0.20 to 0.30. On the contrary, there was a reduction in tensile and yield strength for SiC concentrations in the range of 0.30 to 0.40. The elasticity modulus increased with increasing SiC volume fractions in the whole reinforcement range (0.20--0.40). Fractographic analysis by SEM revealed a ductile failure process of void growth in the matrix, but the amount of the void growth was less when the SiC concentration was higher. SEM also revealed SiC reinforcement fracture and decohesion, with the particle fracture increasing with the particle concentration. Appropriate flat specimens with a continuously graded microstructure for fracture mechanics testing were machined from the cast blocks. No published work has reported specimens of similar characteristics (size of the specimens and continuous reinforcement gradation). Fracture mechanics of the composite specimens with the crack parallel to the gradation in elastic properties was studied to investigate the effect of the nonhomogeneous microstructure on fracture toughness. Fatigue pre-cracking was used and a limited amount of fatigue crack propagation data was gathered. Low values of DeltaKth and increased crack growth resistance in the Paris region were observed for the functionally graded composite compared to a homogeneous 20 vol% composite. R-curve (KR) behavior of fracture was investigated in the functionally graded composite. At elevated SiC concentrations (low values of crack length), limited dissipation of energy by restrained plastic deformation of the matrix at the crack tip produced low fracture toughness values. On the contrary, at longer crack lengths SiC content decreased and there was more absorption of energy, resulting in higher fracture toughness values. In addition, the crack growth resistance behavior of the FGM composite was compared to the corresponding behavior of an Al A359/SiCp 20 vol% homogeneous composite. The latter exhibited a declining KR-curve behavior whereas the FGM composite displayed an increasing KR-curve behavior. Consequently, this increasing crack growth resistance behavior displayed by the functionally graded Al A359/SiCp composite shows that tailored changes in the microstructure could circumvent the low toughness inherent in MMCs.

Finite Element Simulation of Compression Molding of Woven Fabric Carbon Fiber/Epoxy Composites: Part I Material Model Development

DOE PAGES

Li, Yang; Zhao, Qiangsheng; Mirdamadi, Mansour; ...

2016-01-06

Woven fabric carbon fiber/epoxy composites made through compression molding are one of the promising choices of material for the vehicle light-weighting strategy. Previous studies have shown that the processing conditions can have substantial influence on the performance of this type of the material. Therefore the optimization of the compression molding process is of great importance to the manufacturing practice. An efficient way to achieve the optimized design of this process would be through conducting finite element (FE) simulations of compression molding for woven fabric carbon fiber/epoxy composites. However, performing such simulation remains a challenging task for FE as multiple typesmore » of physics are involved during the compression molding process, including the epoxy resin curing and the complex mechanical behavior of woven fabric structure. In the present study, the FE simulation of the compression molding process of resin based woven fabric composites at continuum level is conducted, which is enabled by the implementation of an integrated material modeling methodology in LS-Dyna. Specifically, the chemo-thermo-mechanical problem of compression molding is solved through the coupling of three material models, i.e., one thermal model for temperature history in the resin, one mechanical model to update the curing-dependent properties of the resin and another mechanical model to simulate the behavior of the woven fabric composites. Preliminary simulations of the carbon fiber/epoxy woven fabric composites in LS-Dyna are presented as a demonstration, while validations and models with real part geometry are planned in the future work.« less

Damage Characterization of Bio and Green Polyethylene-Birch Composites under Creep and Cyclic Testing with Multivariable Acoustic Emissions.

PubMed

Bravo, Alencar; Toubal, Lotfi; Koffi, Demagna; Erchiqui, Fouad

2015-11-02

Despite the knowledge gained in recent years regarding the use of acoustic emissions (AEs) in ecologically friendly, natural fiber-reinforced composites (including certain composites with bio-sourced matrices), there is still a knowledge gap in the understanding of the difference in damage behavior between green and biocomposites. Thus, this article investigates the behavior of two comparable green and biocomposites with tests that better reflect real-life applications, i.e. , load-unloading and creep testing, to determine the evolution of the damage process. Comparing the mechanical results with the AE, it can be concluded that the addition of a coupling agent (CA) markedly reduced the ratio of AE damage to mechanical damage. CA had an extremely beneficial effect on green composites because the Kaiser effect was dominant during cyclic testing. During the creep tests, the use of a CA also avoided the transition to new damaging phases in both composites. The long-term applications of PE green material must be chosen carefully because bio and green composites with similar properties exhibited different damage processes in tests such as cycling and creep that could not be previously understood using only monotonic testing.

Damage Characterization of Bio and Green Polyethylene–Birch Composites under Creep and Cyclic Testing with Multivariable Acoustic Emissions

PubMed Central

Bravo, Alencar; Toubal, Lotfi; Koffi, Demagna; Erchiqui, Fouad

2015-01-01

Despite the knowledge gained in recent years regarding the use of acoustic emissions (AEs) in ecologically friendly, natural fiber-reinforced composites (including certain composites with bio-sourced matrices), there is still a knowledge gap in the understanding of the difference in damage behavior between green and biocomposites. Thus, this article investigates the behavior of two comparable green and biocomposites with tests that better reflect real-life applications, i.e., load-unloading and creep testing, to determine the evolution of the damage process. Comparing the mechanical results with the AE, it can be concluded that the addition of a coupling agent (CA) markedly reduced the ratio of AE damage to mechanical damage. CA had an extremely beneficial effect on green composites because the Kaiser effect was dominant during cyclic testing. During the creep tests, the use of a CA also avoided the transition to new damaging phases in both composites. The long-term applications of PE green material must be chosen carefully because bio and green composites with similar properties exhibited different damage processes in tests such as cycling and creep that could not be previously understood using only monotonic testing. PMID:28793640

Numerical Investigation of the Macroscopic Mechanical Behavior of NiTi-Hybrid Composites Subjected to Static Load-Unload-Reload Path

NASA Astrophysics Data System (ADS)

Taheri-Behrooz, Fathollah; Kiani, Ali

2017-04-01

Shape memory alloys (SMAs) are a type of shape memory materials that recover large deformation and return to their primary shape by rising temperature. In the current research, the effect of embedding SMA wires on the macroscopic mechanical behavior of glass-epoxy composites is investigated through finite element simulations. A perfect interface between SMA wires and the host composite is assumed. Effects of various parameters such as SMA wires volume fraction, SMA wires pre-strain and temperature are investigated during loading-unloading and reloading steps by employing ANSYS software. In order to quantify the extent of induced compressive stress in the host composite and residual tensile stress in the SMA wires, a theoretical approach is presented. Finally, it was shown that smart structures fabricated using composite layers and pre-strained SMA wires exhibited overall stiffness reduction at both ambient and elevated temperatures which were increased by adding SMA volume fraction. Also, the induced compressive stress on the host composite was increased remarkably using 4% pre-strained SMA wires at elevated temperature. Results obtained by FE simulations were in good correlation with the rule of mixture predictions and available experimental data in the literature.

Investigation of a ceramic matrix composite under strain controlled fatigue condition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gudaitis, J.J.; Mall, S.

The fatigue behavior along with damage mechanisms and failure modes of a fiber reinforced ceramic matrix composite with a cross-ply lay-up was investigated under strain controlled mode. Two fatigue conditions involving tension-tension and tension-compression cycling were employed. The strain range versus fatigue life curves for both fatigue conditions were in agreement with each other. However, damage mechanisms and failure modes were different for both cases.

Corrosion behavior of aluminum-alumina composites in aerated 3.5 percent chloride solution

NASA Astrophysics Data System (ADS)

Acevedo Hurtado, Paul Omar

Aluminum based metal matrix composites are finding many applications in engineering. Of these Al-Al2O3 composites appear to have promise in a number of defense applications because of their mechanical properties. However, their corrosion behavior remains suspect, especially in marine environments. While efforts are being made to improve the corrosion resistance of Al-Al2O3 composites, the mechanism of corrosion is not well known. In this study, the corrosion behavior of powder metallurgy processed Al-Cu alloy reinforced with 10, 15, 20 and 25 vol. % Al2O3 particles (XT 1129, XT 2009, XT 2048, XT 2031) was evaluated in aerated 3.5% NaCl solution using microstructural and electrochemical measurements. AA1100-O and AA2024T4 monolithic alloys were also studied for comparison purposes. The composites and unreinforced alloys were subjected to potentiodynamic polarization and Electrochemical Impedance Spectroscopy (EIS) testing. Addition of 25 vol. % Al2O 3 to the base alloys was found to increase its corrosion resistance considerably. Microstructural studies revealed the presence of intermetallic Al2Cu particles in these composites that appeared to play an important role in the observations. Pitting potential for these composites was near corrosion potential values, and repassivation potential was below the corresponding corrosion potential, indicating that these materials begin to corrode spontaneously as soon as they come in contact with the 3.5 % NaCl solution. EIS measurements indicate the occurrence of adsorption/diffusion phenomena at the interface of the composites which ultimately initiate localized or pitting corrosion. Polarization resistance values were extracted from the EIS data for all the materials tested. Electrically equivalent circuits are proposed to describe and substantiate the corrosive processes occurring in these Al-Al2O 3 composite materials.

Interphase and particle dispersion correlations in polymer nanocomposites

NASA Astrophysics Data System (ADS)

Senses, Erkan

Particle dispersion in polymer matrices is a major parameter governing the mechanical performance of polymer nanocomposites. Controlling particle dispersion and understanding aging of composites under large shear and temperature variations determine the processing conditions and lifetime of composites which are very important for diverse applications in biomedicine, highly reinforced materials and more importantly for the polymer composites with adaptive mechanical responses. This thesis investigates the role of interphase layers between particles and polymer matrices in two bulk systems where particle dispersion is altered upon deformation in repulsive composites, and good-dispersion of particles is retained after multiple oscillatory shearing and aging cycles in attractive composites. We demonstrate that chain desorption and re-adsorption processes in attractive composites under shear can effectively enhance the bulk microscopic mechanical properties, and long chains of adsorbed layers lead to a denser entangled interphase layer. We further designed experiments where particles are physically adsorbed with bimodal lengths of homopolymer chains to underpin the entanglement effect in interphases. Bimodal adsorbed chains are shown to improve the interfacial strength and used to modulate the elastic properties of composites without changing the particle loading, dispersion state or polymer conformation. Finally, the role of dynamic asymmetry (different mobilities in polymer blends) and chemical heterogeneity in the interphase layer are explored in systems of poly(methyl methacrylate) adsorbed silica nanoparticles dispersed in poly(ethylene oxide) matrix. Such nanocomposites are shown to exhibit unique thermal-stiffening behavior at temperatures above glass transitions of both polymers. These interesting findings suggest that the mobility of the surface-bound polymer is essential for reinforcement in polymer nanocomposites, contrary to existing glassy layer theories for polymers on attractive particle surfaces. The shown thermally-induced stiffening behavior is reversible and makes this interfacial mechanism highly attractive in developing new active, remotely controllable engineered materials from non-responsive components.

Dynamic mechanical analysis of fiber reinforced composites

NASA Technical Reports Server (NTRS)

Reed, K. E.

1979-01-01

Dynamic mechanical and thermal properties were determined for unidirectional epoxy/glass composites at various fiber orientation angles. Resonant frequency and relative logarithmic decrement were measured as functions of temperature. In low angle and longitudinal specimens a transition was observed above the resin glass transition temperature which was manifested mechanically as an additional damping peak and thermally as a change in the coefficient of thermal expansion. The new transition was attributed to a heterogeneous resin matrix induced by the fiber. The temperature span of the glass-rubber relaxation was found to broaden with decreasing orientation angle, reflecting the growth of fiber contribution and exhibiting behavior similar to that of Young's modulus. The change in resonant frequency through the glass transition was greatest for samples of intermediate fiber angle, demonstrating behavior similar to that of the longitudinal shear modulus.

Effect of surface modified kaolin on properties of polypropylene grafted maleic anhydride

NASA Astrophysics Data System (ADS)

Yang, Ni; Zhang, Zuo-Cai; Ma, Ning; Liu, Huan-Li; Zhan, Xue-Qing; Li, Bing; Gao, Wei; Tsai, Fang-Chang; Jiang, Tao; Chang, Chang-Jung; Chiang, Tai-Chin; Shi, Dean

To achieve reinforcement of mechanical and thermal performances of polypropylene (PP) product, this work aimed at fabrication of surface modified kaolin (M-kaolin) filled polypropylene grafted maleic anhydride (PP-g-MAH) composites with varying contents of fillers and investigation of their mechanical and thermal properties. And the prepared PP-g-MAH/M-kaolin composites were characterized by means of Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Fracture analysis by SEM showed M-kaolin particles were well dispersed in the PP-g-MAH matrix. Mechanical behaviors were determined by tensile strength, tensile strain at break and impact strength analysis. Impact strength of PP-g-MAH/2 wt% M-kaolin composites was improved up to 30% comparing with unfilled composites. Thermostability had been found enhanced when M-kaolin added. The results revealed PP-g-MAH/M-kaolin composites showed the optimal thermal and mechanical properties when 2 wt% of M-kaolin was added.

Mechanisms of CFR composites destruction studying with pulse acoustic microscopy

NASA Astrophysics Data System (ADS)

Petronyuk, Y. S.; Morokov, E. S.; Levin, V. M.; Ryzhova, T. B.; Chernov, A. V.

2016-05-01

Non-destructive inspection of carbon-fiber-reinforced (CFR) composites applied in aerospace industry attracts a wide attention. In the paper, high frequency focused ultrasound (50-100 MHz) has been applied to study the bulk microstructure of the CFR material and mechanisms of its destruction under the mechanical loading. It has been shown impulse acoustic microscopy provides detecting the areas of adhesion loss at millimeter and micron level. Behavior of the CFR laminate structure fabricated by prepreg or infusion technology has been investigated under the tensile and impact loading.

Mechanical Characterization of Thermomechanical Matrix Residual Stresses Incurred During MMC Processing

NASA Technical Reports Server (NTRS)

Castelli, Michael G.

1998-01-01

In recent years, much effort has been spent examining the residual stress-strain states of advanced composites. Such examinations are motivated by a number of significant concerns that affect composite development, processing, and analysis. The room-temperature residual stress states incurred in many advanced composite systems are often quite large and can introduce damage even prior to the first external mechanical loading of the material. These stresses, which are induced during the cooldown following high-temperature consolidation, result from the coefficient of thermal expansion mismatch between the fiber and matrix. Experimental techniques commonly used to evaluate composite internal residual stress states are non-mechanical in nature and generally include forms of x-ray and neutron diffraction. Such approaches are usually complex, involving a number of assumptions and limitations associated with a wide range of issues, including the depth of penetration, the volume of material being assessed, and erroneous effects associated with oriented grains. Furthermore, and more important to the present research, these techniques can assess only "single time" stress in the composite. That is, little, if any, information is obtained that addresses the time-dependent point at which internal stresses begin to accumulate, the manner in which the accumulation occurs, and the presiding relationships between thermoelastic, thermoplastic, and thermoviscous behaviors. To address these critical issues, researchers at the NASA Lewis Research Center developed and implemented an innovative mechanical test technique to examine in real time, the time-dependent thermomechanical stress behavior of a matrix alloy as it went through a consolidation cycle.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Yang; Zhao, Qiangsheng; Mirdamadi, Mansour

Woven fabric carbon fiber/epoxy composites made through compression molding are one of the promising choices of material for the vehicle light-weighting strategy. Previous studies have shown that the processing conditions can have substantial influence on the performance of this type of the material. Therefore the optimization of the compression molding process is of great importance to the manufacturing practice. An efficient way to achieve the optimized design of this process would be through conducting finite element (FE) simulations of compression molding for woven fabric carbon fiber/epoxy composites. However, performing such simulation remains a challenging task for FE as multiple typesmore » of physics are involved during the compression molding process, including the epoxy resin curing and the complex mechanical behavior of woven fabric structure. In the present study, the FE simulation of the compression molding process of resin based woven fabric composites at continuum level is conducted, which is enabled by the implementation of an integrated material modeling methodology in LS-Dyna. Specifically, the chemo-thermo-mechanical problem of compression molding is solved through the coupling of three material models, i.e., one thermal model for temperature history in the resin, one mechanical model to update the curing-dependent properties of the resin and another mechanical model to simulate the behavior of the woven fabric composites. Preliminary simulations of the carbon fiber/epoxy woven fabric composites in LS-Dyna are presented as a demonstration, while validations and models with real part geometry are planned in the future work.« less

A synergetic analysis method for antifouling behavior investigation on PES ultrafiltration membrane with self-assembled TiO2 nanoparticles.

PubMed

Li, Xin; Li, Jiansheng; Fang, Xiaofeng; Bakzhan, Kariboz; Wang, Lianjun; Van der Bruggen, Bart

2016-05-01

Fouling of ultrafiltration (UF) membranes is a major impediment for their use in drinking water production. Mixed matrix membranes (MMMs) may have great opportunities in dealing with this challenge due to their hierarchical structures and multiple functionalities. In this study, a synergetic analysis method based on intermolecular adhesion force measurement and fouling process simulation was applied to investigate the fouling mechanism of polyethersulfone (PES) UF membranes containing in situ self-assembled TiO2 nanoparticles (NPs). The fouling resistance behavior and antifouling mechanism of the newly developed composite membranes were investigated with sodium alginate (SA), bovine serum albumin (BSA) and humic acid (HA) as model organic foulants. An improved antifouling effect was conspicuously observed for the composite membranes, expressed by a lower flux decline and significantly better cleaning efficiency. A strong correlation between the self-assembled structure of TiO2 NPs and the antifouling behavior of the composite membrane was observed. A lower magnitude and a narrower distribution of adhesion forces for the composite membrane suggest the effective suppression of foulants adsorption on the clean or fouled membrane. The simulation analysis indicates that the main fouling mechanism was standard blocking and cake filtration, further confirming the superiority of the NPs self-assembled structure in mitigating membrane fouling. This dual analysis method may provide a promising technological support for the application of modified UF membranes with self-assembled NPs in drinking water production. Copyright © 2016 Elsevier Inc. All rights reserved.

Damping behavior of polymer composites with high volume fraction of NiMnGa powders

NASA Astrophysics Data System (ADS)

Sun, Xiaogang; Song, Jie; Jiang, Hong; Zhang, Xiaoning; Xie, Chaoying

2011-03-01

Polymer composites inserted with high volume fraction (up to 70 Vol%) of NiMnGa powders were fabricated and their damping behavior was investigated by dynamic mechanical analysis. It is found that the polymer matrix has little influence on the transformation temperatures of NiMnGa powders. A damping peak appears for NiMnGa/epoxy resin (EP) composites accompanying with the martensitic transformation or reverse martensitic transformation of NiMnGa powders during cooling or heating. The damping capacity for NiMnGa/EP composites increases linearly with the increase of volume fraction of NiMnGa powders and, decreases dramatically as the test frequency increases. The fracture strain of NiMnGa/EP composites decrease with the increase of NiMnGa powders.

Composite materials research and education program: The NASA-Virginia Tech composites program

NASA Technical Reports Server (NTRS)

Herakovich, C. T.

1980-01-01

Major areas of study include: (1) edge effects in finite width laminated composites subjected to mechanical, thermal and hygroscopic loading with temperature dependent material properties and the influence of edge effects on the initiation of failure; (2) shear and compression testing of composite materials at room and elevated temperatures; (3) optical techniques for precise measurement of coefficients of thermal expansion of composites; (4) models for the nonlinear behavior of composites including material nonlinearity and damage accumulation and verification of the models under biaxial loading; (5) compressive failure of graphite/epoxy plates with circular holes and the buckling of composite cylinders under combined compression and torsion; (6) nonlinear mechanical properties of borsic/aluminum, graphite/polyimide and boron/aluminum; (7) the strength characteristics of spliced sandwich panels; and (8) curved graphite/epoxy panels subjected to internal pressure.

Processing, microstructure evolution and properties of nanoscale aluminum alloys

NASA Astrophysics Data System (ADS)

Han, Jixiong

In this project, phase transformations and precipitation behavior in age-hardenable nanoscale materials systems, using Al-Cu alloys as model materials, were first studied. The Al-Cu nanoparticles were synthesized by a Plasma Ablation process and found to contain a 2˜5 nm thick adherent aluminum oxide scale, which prevented further oxidation. On aging of the particles, a precipitation sequence consisting of, nearly pure Cu precipitates to the metastable theta' to equilibrium theta was observed, with all three forming along the oxide-particle interface. The structure of theta' and its interface with the Al matrix has been characterized in detail. Ultrafine Al-Cu nanoparticles (5˜25 nm) were also synthesized by inert gas condensation (IGC) and their aging behavior was studied. These particles were found to be quite stable against precipitation. Secondly, pure Al nanoparticles were prepared by the Exploding Wire process and their sintering and consolidation behavior were studied. It was found that nanopowders of Al could be processed to bulk structures with high hardness and density. Sintering temperature was found to have a dominant effect on density, hardness and microstructure. Sintering at temperatures >600°C led to breakup of the oxide scale, leading to an interesting nanocomposite composed of 100˜200 nm Al oxide dispersed in a bimodal nanometer-micrometer size Al matrix grains. Although there was some grain growth, the randomly dispersed oxide fragments were quite effective in pinning the Al grain boundaries, preventing excessive grain growth and retaining high hardness. Cold rolling and hot rolling were effective methods for attaining full densification and high hardness. Thirdly, the microstructure evolution and mechanical behavior of Al-Al 2O3 nanocomposites were studied. The composites can retain high strength at elevated temperature and thermal soaking has practically no detrimental effect on strength. Although the ductility of the composite remains quite low, there was substantial evidence for high localized plasticity. The strengthening mechanisms of the composite include: Orowan strengthening, grain size strengthening and Forest strengthening. Finally, the microstructure evolution and mechanical behavior of 2024Al-Al 2O3 nanocomposites were studied. This 2024Al-Al2O 3 composite exhibits similar thermal stability and high strength at elevated temperature as Al-Al2O3. On aging, the matrix of 2024Al-Al2O3 composites revealed a precipitation sequence of: alphaAl → GP/GPB → theta'/S' → theta/S. The strengthening mechanisms of the 2024Al-Al2O3 composites include precipitation strengthening, Orowan strengthening, grain size strengthening and Forest strengthening.

Creep Behavior of Hafnia and Ytterbium Silicate Environmental Barrier Coating Systems on SiC/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Fox, Dennis S.; Ghosn, Louis J.; Harder, Bryan

2011-01-01

Environmental barrier coatings will play a crucial role in future advanced gas turbine engines because of their ability to significantly extend the temperature capability and stability of SiC/SiC ceramic matrix composite (CMC) engine components, thus improving the engine performance. In order to develop high performance, robust coating systems for engine components, appropriate test approaches simulating operating temperature gradient and stress environments for evaluating the critical coating properties must be established. In this paper, thermal gradient mechanical testing approaches for evaluating creep and fatigue behavior of environmental barrier coated SiC/SiC CMC systems will be described. The creep and fatigue behavior of Hafnia and ytterbium silicate environmental barrier coatings on SiC/SiC CMC systems will be reported in simulated environmental exposure conditions. The coating failure mechanisms will also be discussed under the heat flux and stress conditions.

Carbon nanotubes reinforced chitosan films: mechanical properties and cell response of a novel biomaterial for cardiovascular tissue engineering.

PubMed

Kroustalli, A; Zisimopoulou, A E; Koch, S; Rongen, L; Deligianni, D; Diamantouros, S; Athanassiou, G; Kokozidou, M; Mavrilas, D; Jockenhoevel, S

2013-12-01

Carbon nanotubes have been proposed as fillers to reinforce polymeric biomaterials for the strengthening of their structural integrity to achieve better biomechanical properties. In this study, a new polymeric composite material was introduced by incorporating various low concentrations of multiwalled carbon nanotubes (MWCNTs) into chitosan (CS), aiming at achieving a novel composite biomaterial with superior mechanical and biological properties compared to neat CS, in order to be used in cardiovascular tissue engineering applications. Both mechanical and biological characteristics in contact with the two relevant cell types (endothelial cells and vascular myofibroblasts) were studied. Regarding the mechanical behavior of MWCNT reinforced CS (MWCNT/CS), 5 and 10 % concentrations of MWCNTs enhanced the mechanical behavior of CS, with that of 5 % exhibiting a superior mechanical strength compared to 10 % concentration and neat CS. Regarding biological properties, MWCNT/CS best supported proliferation of endothelial and myofibroblast cells, MWCNTs and MWCNT/CS caused no apoptosis and were not toxic of the examined cell types. Conclusively, the new material could be suitable for tissue engineering (TE) and particularly for cardiovascular TE applications.

Preparation, Electromechanical, and Structural Study of Carbon Nanotube/Gelatin Nanocomposites

DTIC Science & Technology

2008-01-15

surfactant sodium dodecyl sulfate (SDS). The swelling behavior and the bending mechanism of the composite and pure gelatin films were studied in order...vacuum-dried gels samples into a 0.1 M NaCl aqueous solution at room temperature. The incorporation of MWNT gradually decreased the swelling of the...ultrasonication in an aqueous medium with anionic surfactant sodium dodecyl sulfate (SDS). The swelling behavior and the bending mechanism of the

Bio-inspired Self-healing Composite Hydrogel with Iron Oxide Nanoparticle as Coordination Crosslinker

NASA Astrophysics Data System (ADS)

Li, Qiaochu; Barret, Devin G.; Messersmith, Phillip B.; Holten-Andersen, Niels

2014-03-01

Polymer-nanoparticle (NP) composites have attracted renewed attention due to enhanced mechanical strength combined with various functionalities, but controlling the interfacial chemistry between NPs and polymer matrix, which is crucial for the composite's mechanical behavior, remains a major challenge. Inspired by the adhesion chemistry of mussel fibers, we investigated a novel approach to incorporate Fe3O4 NPs into hydrogel matrix. A polyethylene glycol polymer is designed with both ends conjugated by catechol groups, which have strong coordination affinity to Fe. The polymer network is crosslinked via coordination bonding at the surface of Fe3O4 NPs, yielding a stiff nanocomposite hydrogel. Due to the reversible nature of coordination bonding, the hydrogel presents self-healing behavior. Oscillatory rheology allows comparative kinetic studies of self-healing driven by catechol bonding at Fe3O4 NP interfaces and by catechol-Fe3+ coordination complexes. Furthermore, the superparamagnetic property of Fe3O4 NP is preserved after gelation, allowing for response to external stimuli. This gelation motif can serve as a versatile platform for tuning functional and mechanical properties for future polymer nanocomposite materials.

Semicrystalline Ionomer-Metal Carboxylate Composite: Phase Behavior and Mechanical Properties

NASA Astrophysics Data System (ADS)

Wakabayashi, Katsuyuki

2005-03-01

We have shown previously that the thermal and mechanical behavior of ethylene-methacrylic acid (E-MAA) ionomers can be tuned by the addition of certain magnesium carboxylates, such as magnesium stearate (MgSt). The property modifications result from coassembly of the two components, both co-aggregation of the ionic groups and co-crystallization of the methylene sequences, as revealed by X-ray scattering. When MgSt is replaced by sodium stearate (NaSt), a different suite of mechanical properties is obtained. NaSt, with its high melting and clearing (288 ^oC) points, readily crystallizes out of solution in the molten polymer and forms an effective composite upon cooling from a single-phase melt. The NaSt crystals in the composite resemble the rectangular polymorph in pure NaSt, though with some differences in lattice parameters and transition temperatures due to interaction with the acid groups of the copolymer. The different physical properties of the NaSt vs. MgSt modified ionomers are traced to these microstructural differences, elucidated through a combination of X-ray scattering and microscopy.

Investigation of Thermal and Electrical Properties for Conductive Polymer Composites

NASA Astrophysics Data System (ADS)

Juwhari, Hassan K.; Abuobaid, Ahmad; Zihlif, Awwad M.; Elimat, Ziad M.

2017-10-01

This study addresses the effects of temperature ranging from 300 K to 400 K on thermal ( κ) and electrical ( σ) conductivities, and Lorenz number ( L) for different conductive polymeric composites (CPCs), as tailoring the ratios between both conductivities of the composites can be influential in the design optimization of certain thermo-electronic devices. Both κ and σ were found to have either a linear or a nonlinear (2nd and 3rd degree polynomial function) increasing behavior with increased temperatures, depending on the conduction mechanism occurring in the composite systems studied. Temperature-dependent behavior of L tends to show decreasing trends above 300 K, where at 300 K the highest and the lowest values were found to be 3 × 103 W Ω/K2 for CPCs containing iron particles and 3 × 10-2 W Ω/K2 for CPCs-containing carbon fibers respectively. Overall, temperature-dependent behavior of κ/ σ and L can be controlled by heterogeneous structures produced via mechanical-molding-compression. These structures are mainly responsible for energy-transfer processes or transport properties that take place by electrons and phonons in the CPCs' bulks. Hence, the outcome is considered significant in the development process of high performing materials for the thermo-electronic industry.

Analysis of dynamic properties for a composite robotic arm at intermediate strain rate

NASA Astrophysics Data System (ADS)

Lin, Jin-Chein

The dynamic mechanical properties of any structure are governed by the storage moduli representing the stiffness and loss moduli representing the internal damping capacity. The dynamic mechanical behavior of a graphite epoxy composite laminate in flexural vibration has been investigated. This study presents the results of a theoretical and experimental effort to determine the dynamic properties of multilaminate composites. The effects of fiber orientation and vibration frequency for both unidirectional tape and Kevlar fabric were studied both analytically and experimentally. Measurement of storage and loss moduli were presented for laminated double cantilever beams of fiber reinforced composite with frequency range from 8 to 1230 Hz (up to 5th mode).

Analysis of CFRP Joints by Means of T-Pull Mechanical Test and Ultrasonic Defects Detection.

PubMed

Casavola, Caterina; Palano, Fania; De Cillis, Francesco; Tati, Angelo; Terzi, Roberto; Luprano, Vincenza

2018-04-18

Defects detection within a composite component, with the aim of understanding and predicting its mechanical behavior, is of great importance in the aeronautical field because the irregularities of the composite material could compromise functionality. The aim of this paper is to detect defects by means of non-destructive testing (NDT) on T-pull samples made by carbon fiber reinforced polymers (CFRP) and to evaluate their effect on the mechanical response of the material. Samples, obtained from an industrial stringer having an inclined web and realized with a polymeric filler between cap and web, were subjected to ultrasonic monitoring and then to T-pull mechanical tests. All samples were tested with the same load mode and the same test configuration. An experimental set-up consisting of a semiautomatic C-scan ultrasonic mapping system with a phased array probe was designed and developed, optimizing control parameters and implementing image processing software. The present work is carried out on real composites parts that are characterized by having their intrinsic defectiveness, as opposed to the previous similar results in the literature mainly obtained on composite parts with artificially produced defects. In fact, although samples under study were realized free from defects, ultrasonic mapping found defectiveness inside the material. Moreover, the ultrasonic inspection could be useful in detecting both the location and size of defects. Experimental data were critically analyzed and qualitatively correlated with results of T-pull mechanical tests in order to better understand and explain mechanical behavior in terms of fracture mode.

Analysis of CFRP Joints by Means of T-Pull Mechanical Test and Ultrasonic Defects Detection

PubMed Central

Casavola, Caterina; Palano, Fania; De Cillis, Francesco; Tati, Angelo; Terzi, Roberto; Luprano, Vincenza

2018-01-01

Defects detection within a composite component, with the aim of understanding and predicting its mechanical behavior, is of great importance in the aeronautical field because the irregularities of the composite material could compromise functionality. The aim of this paper is to detect defects by means of non-destructive testing (NDT) on T-pull samples made by carbon fiber reinforced polymers (CFRP) and to evaluate their effect on the mechanical response of the material. Samples, obtained from an industrial stringer having an inclined web and realized with a polymeric filler between cap and web, were subjected to ultrasonic monitoring and then to T-pull mechanical tests. All samples were tested with the same load mode and the same test configuration. An experimental set-up consisting of a semiautomatic C-scan ultrasonic mapping system with a phased array probe was designed and developed, optimizing control parameters and implementing image processing software. The present work is carried out on real composites parts that are characterized by having their intrinsic defectiveness, as opposed to the previous similar results in the literature mainly obtained on composite parts with artificially produced defects. In fact, although samples under study were realized free from defects, ultrasonic mapping found defectiveness inside the material. Moreover, the ultrasonic inspection could be useful in detecting both the location and size of defects. Experimental data were critically analyzed and qualitatively correlated with results of T-pull mechanical tests in order to better understand and explain mechanical behavior in terms of fracture mode. PMID:29669992

Modeling the Tensile Behavior of Cross-Ply C/SiC Ceramic-Matrix Composites

NASA Astrophysics Data System (ADS)

Li, L. B.; Song, Y. D.; Sun, Y. C.

2015-07-01

The tensile behavior of cross-ply C/SiC ceramic-matrix composites (CMCs) at room temperature has been investigated. Under tensile loading, the damage evolution process was observed with an optical microscope. A micromechanical approach was developed to predict the tensile stress-strain curve, which considers the damage mechanisms of transverse multicracking, matrix multicracking, fiber/matrix interface debonding, and fiber fracture. The shear-lag model was used to describe the microstress field of the damaged composite. By combining the shear-lag model with different damage models, the tensile stress-strain curve of cross-ply CMCs corresponding to each damage stage was modeled. The predicted tensile stress-strain curves of cross-ply C/SiC composites agreed with experimental data.

Biodegradation behavior of styrene butadiene rubber (SBR) reinforced with modified coconut shell powder

NASA Astrophysics Data System (ADS)

Sreejith, M. P.; Balan, Aparna K.; Shaniba, V.; Jinitha, T. V.; Subair, N.; Purushothaman, E.

2017-06-01

Biodegradation behavior of styrene butadiene rubber composites reinforced with natural filler, coconut shell powder (CSP), with different filler loadings were carried out under soil burial conditions for three to six months. The extent of biodegradation of the composites was evaluated through weight loss, tensile strength and hardness measurements. It was observed that the permanence of the composites was remarkably dependent on filler modification, size of the filler particle and filler content. Composites containing silane modified filler were found to be more resistant to attack by the microbes present in the soil. Mechanical properties such as tensile strength, Young's modulus and hardness were decreased after soil burial testing due to the microbial attack onto the samples.

Composite fibres based on cellulose and vinyltriethoxysilane: preparation, properties and carbonization

NASA Astrophysics Data System (ADS)

Makarov, I. S.; Golova, L. K.; Mironova, M. V.; Vinogradov, M. I.; Kulichikhin, V. G.

2018-04-01

For the first time the composite fibers based on cellulose with additives of vinyltriethoxysilane (VTEOS) have been obtained. The choice of the additive was justified by the chemical structure of the VTEOS, namely the Si-C links content and the low C/O ratio. Composite fibers were prepared from solid phase pre-solutions of cellulose with VTEOS in N-methylmorpholine-N-oxide (NMMO). An investigation of the rheological behavior of the filled cellulose solutions with VTEOS showed a slight effect of the additive on the viscosity properties of the system. Introduction of 5% of VTEOS to cellulose does not lead to significant structural changes and, as a result, mechanical properties of the fibers. The thermal behavior of composite fibers differs from cellulose fibers.

Influence of different functionalization on mechanical and interface behavior of MWCNTs/NBR sealing composites

NASA Astrophysics Data System (ADS)

Li, Kun; Gu, Boqin

2017-04-01

Rubber sealants are key components in processing industries. Carbon nanotubes (CNTs), which are randomly dispersed in polymer, are able to generate exciting effects. Focusing on mechanical properties of composites and interface characteristic between the fillers and matrix, carrying out SEM, DMA and uniaxial tensile tests, the tensile strength of the composites with 4 phr (parts by weight per hundred parts of rubber) multiwalled carbon nanotubes (MWNTs) is obviously improved. MWNTs with different functionalization have different influence on the viscoelastic and mechanical properties of the composites. Results indicate that MWNTs-COOH are broken when composites fractured. While MWNTs, MWNTs-OH and MWNTs-NH2 are pulled out from the matrix because interface debonds under the tensile failure. The interfacial shear stress (IFSS) is about 4.7 MPa in composites. The glass transition temperature (T g) shifts higher temperatures compared to pure NBR (Acrylonitrile-butadiene Rubber). The presence of the nanotubes limite the movement of NBR macromolecules.

Sintering, thermal stability and mechanical properties of ZrO2-WC composites obtained by pulsed electric current sintering

NASA Astrophysics Data System (ADS)

Huang, Shuigen; Vanmeensel, Kim; van der Biest, Omer; Vleugels, Jozef

2011-03-01

ZrO2-WC composites exhibit comparable mechanical properties as traditional WC-Co materials, which provides an opportunity to partially replace WC-Co for some applications. In this study, 2 mol.% Y2O3 stabilized ZrO2 composites with 40 vol.% WC were consolidated in the 1150°C-1850°C range under a pressure of 60 MPa by pulsed electric current sintering (PECS). The densification behavior, microstructure and phase constitution of the composites were investigated to clarify the role of the sintering temperature on the grain growth, mechanical properties and thermal stability of ZrO2 and WC components. Analysis results indicated that the composites sintered at 1350°C and 1450°C exhibited the highest tetragonal ZrO2 phase transformability, maximum toughness, and hardness and an optimal flexural strength. Chemical reaction of ZrO2 and C, originating from the graphite die, was detected in the composite PECS for 20 min at 1850°C in vacuum.

A micromechanical study of the damage mechanics of acrylic particulate composites under thermomechanical loading

NASA Astrophysics Data System (ADS)

Nie, Shihua

The main aim of this dissertation was to characterize the damage mechanism and fatigue behavior of the acrylic particulate composite. This dissertation also investigated how the failure mechanism is influenced by changes in certain parameters including the volume fraction of particle, the interfacial bonding strength, the stiffness and thickness of the interphase, and the CTE mismatch between the particle and the matrix. Monotonic uniaxial tensile and compressive testing under various temperatures and strain rates, isothermal low-cycle mechanical testing and thermal cycling of a plate with a cutout were performed. The influence of the interfacial bonding strength between the particle and the matrix on the failure mechanism of the ATH filled PMMA was investigated using in situ observations under uniaxial loading conditions. For composites with weak interfacial bonding, the debonding is the major damage mode. For composites with strong interfacial bonding, the breakage of the agglomerate of particles is the major damage mode. Experimental studies also demonstrated the significant influence of interfacial bonding strength on the fatigue life of the ATH filled PMMA. The damage was characterized in terms of the elastic modulus degradation, the load-drop parameter, the plastic strain range and the hysteresis dissipation. Identifying the internal state variables that quantify material degradation under thermomechanical loading is an active research field. In this dissertation, the entropy production, which is a measure of the irreversibility of the thermodynamic system, is used as the metric for damage. The close correlation between the damage measured in terms of elastic modulus degradation and that obtained from the finite element simulation results validates the entropy based damage evolution function. A micromechanical model for acrylic particulate composites with imperfect interfacial bonds was proposed. Acrylic particulate composites are treated as three-phase composites consisting of agglomerated particles, bulk matrix and an interfacial transition zone around the agglomerate. The influence of the interfacial bonding and the CTE mismatch between the matrix and the filler on the overall thermomechanical behavior of composites is studied analytically and experimentally. The comparison of analytical simulation with experimental data demonstrated the validity of the proposed micromechanical model for acrylic particulate composites with an imperfect interface. (Abstract shortened by UMI.)

Outsourcing neural active control to passive composite mechanics: a tissue engineered cyborg ray

NASA Astrophysics Data System (ADS)

Gazzola, Mattia; Park, Sung Jin; Park, Kyung Soo; Park, Shirley; di Santo, Valentina; Deisseroth, Karl; Lauder, George V.; Mahadevan, L.; Parker, Kevin Kit

2016-11-01

Translating the blueprint that stingrays and skates provide, we create a cyborg swimming ray capable of orchestrating adaptive maneuvering and phototactic navigation. The impossibility of replicating the neural system of batoids fish is bypassed by outsourcing algorithmic functionalities to the body composite mechanics, hence casting the active control problem into a design, passive one. We present a first step in engineering multilevel "brain-body-flow" systems that couple sensory information to motor coordination and movement, leading to behavior. This work paves the way for the development of autonomous and adaptive artificial creatures able to process multiple sensory inputs and produce complex behaviors in distributed systems and may represent a path toward soft-robotic "embodied cognition".

Modeling of Nonlinear Mechanical Response in CFRP Angle-Ply Laminates

NASA Astrophysics Data System (ADS)

Ogihara, Shinji

2014-03-01

It is known that the failure process in angle-ply laminate involves matrix cracking and delamination and that they exhibit nonlinear stress-strain relation. There may be a significant effect of the constituent blocked ply thickness on the mechanical behavior of angle-ply laminates. These days, thin prepregs whose thickness is, for example 50 micron, are developed and commercially available. Therefore, we can design wide variety of laminates with various constituent ply thicknesses. In this study, effects of constituent ply thickness on the nonlinear mechanical behavior and the damage behavior of CFRP angle-ply laminates are investigated experimentally. Based on the experimental results, the mechanical response in CFRP angle-ply laminates is modeled by using the finite strain viscoplasticity model. We evaluated the mechanical behavior and damage behavior in CFRP angle-ply laminates with different constituent ply thickness under tensile loading experimentally. It was found that as the constituent ply thickness decreases, the strength and failure strain increases. We also observed difference in damage behavior. The preliminary results of finite strain viscoplasticity model considering the damage effect for laminated composites are shown. A qualitative agreement is obtained.

Bamboo reinforced polymer composite - A comprehensive review

NASA Astrophysics Data System (ADS)

Roslan, S. A. H.; Rasid, Z. A.; Hassan, M. Z.

2018-04-01

Bamboo has greatly attention of researchers due to their advantages over synthetic polymers. It is entirely renewable, environmentally-friendly, non-toxic, cheap, non-abrasive and fully biodegradable. This review paper summarized an oveview of the bamboo, fiber extraction and mechanical behavior of bamboo reinforced composites. A number of studies proved that mechanical properties of bamboo fibers reinforced reinforced polymer composites are excellent and competent to be utilized in high-tech applications. The properties of the laminate are influenced by the fiber loading, fibre orientation, physical and interlaminar adhesion between fibre and matrix. In contrast, the presence of chemical constituents such as cellulose, lignin, hemicellulose and wax substances in natural fibres preventing them from firmly binding with polymer resin. Thus, led to poor mechanical properties for composites. Many attempt has been made in order to overcome this issue by using the chemical treatment.

A review of mechanical and tribological behaviour of polymer composite materials

NASA Astrophysics Data System (ADS)

Prabhakar, K.; Debnath, S.; Ganesan, R.; Palanikumar, K.

2018-04-01

Composite materials are finding increased applications in many industrial applications. A nano-composite is a matrix to which nanosized particles have been incorporated to drastically improve the mechanical performance of the original material. The structural components produced using nano-composites will exhibit a high strength-to-weight ratio. The properties of nano-composites have caused researchers and industries to consider using this material in several fields. Polymer nanocomposites consists of a polymer material having nano-particles or nano-fillers dispersed in the polymer matrix which may be of different shapes with at least one of the dimensions less than 100nm. In this paper, comprehensive review of polymer nanocomposites was done majorly in three different areas. First, mechanical behaviour of polymer nanocomposites which focuses on the mechanical property evaluation such as tensile strength, impact strength and modulus of elasticity based on the different combination of filler materials and nanoparticle inclusion. Second, wear behavior of Polymer composite materials with respect to different impingement angles and variation of filler composition using different processing techniques. Third, tribological (Friction and Wear) behaviour of nanocomposites using various combination of nanoparticle inclusion and time. Finally, it summarized the challenges and prospects of polymer nanocomposites.

Residual Stresses and Thermo-Mechanical Behavior of Metal-Matrix Composites

DTIC Science & Technology

1984-01-01

necessary and identify by block number) ELO I GROUP I Sue. GR. I Metal-matrix composites Silicon -carbide/Aluminum Graphite/Alumimun Cross-plied laminate I...aluminum, tungsten/aluminum and silicon -carbide aluminum composites . For the graphite/aluminum material a parametric study was carried out on the...PROPERTIES AS GIVEN IN TABLE 2.1. 5 3.1 CALCULATED THERUMOELASTIC PROPERTIES OF A TUNG- STEN /AL 2024 COMPOSITE 54 5.1 INPUT ELASTIC CONSTANTS FOR FIBER AND

Formation of functionalized nanoclusters by solvent evaporation and their effect on the physicochemical properties of dental composite resins.

PubMed

Rodríguez, Henry A; Giraldo, Luis F; Casanova, Herley

2015-07-01

The aim of this work was to study the effect of silica nanoclusters (SiNC), obtained by a solvent evaporation method and functionalized by 3-methacryloxypropyltrimethoxysilane (MPS) and MPS+octyltrimethoxysilane (OTMS) (50/50wt/wt), on the rheological, mechanical and sorption properties of urethane dimethylacrylate (UDMA)/triethylenglycol dimethacrylate (TEGDMA) (80/20wt/wt) resins blend. Silica nanoparticles (SiNP) were silanized with MPS or MPS+OTMS (50/50wt/wt) and incorporated in an UDMA-isopropanol mix to produce functionalized silica nanoclusters after evaporating the isopropanol. The effect of functionalized SiNC on resins rheological properties was determined by large and small deformation tests. Mechanical, thermal, sorption and solubility properties were evaluated for composite materials. The UDMA/TEGDMA (80/20wt/wt) resins blend with added SiNC (ca. 350nm) and functionalized with MPS showed a Newtonian flow behavior associated to their spheroidal shape, whereas the resins blend with nanoclusters silanized with MPS+OTMS (50/50wt/wt) (ca. 400nm) showed a shear-thinning behavior due to nanoclusters irregular shape. Composite materials prepared with bare silica nanoclusters showed lower compressive strength than functionalized silica nanoclusters. MPS functionalized nanoclusters showed better mechanical properties but higher water sorption than functionalized nanoclusters with both silane coupling agents, MPS and OTMS. The solvent evaporation method applied to functionalized nanoparticles showed to be an alternative way to the sinterization method for producing nanoclusters, which improved some dental composite mechanical properties and reduced water sorption. The shape of functionalized silica nanoclusters showed to have influence on the rheological properties of SiNC resin suspensions and the mechanical and sorption properties of light cured composites. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Mechanical properties and shape memory effect of thermal-responsive polymer based on PVA

NASA Astrophysics Data System (ADS)

Lin, Liulan; Zhang, Lingfeng; Guo, Yanwei

2018-01-01

In this study, the effect of content of glutaraldehyde (GA) on the shape memory behavior of a shape memory polymer based on polyvinyl alcohol chemically cross-linked with GA was investigated. Thermal-responsive shape memory composites with three different GA levels, GA-PVA (3 wt%, 5 wt%, 7 wt%), were prepared by particle melting, mold forming and freeze-drying technique. The mechanical properties, thermal properties and shape memory behavior were measured by differential scanning calorimeter, physical bending test and cyclic thermo-mechanical test. The addition of GA to PVA led to a steady shape memory transition temperature and an improved mechanical compressive strength. The composite with 5 wt% of GA exhibited the best shape recoverability. Further increase in the crosslinking agent content of GA would reduce the recovery force and prolong the recovery time due to restriction in the movement of the soft PVA chain segments. These results provide important information for the study on materials in 4D printing.

In-situ investigation of stress-induced martensitic transformation in Ti–Nb binary alloys with low Young's modulus [In-situ high-energy X-ray diffraction investigation on stress-induced martensitic transformation in Ti-Nb binary alloys

DOE PAGES

Chang, L. L.; Wang, Y. D.; Ren, Y.

2015-11-04

Microstructure evolution, mechanical behaviors of cold rolled Ti-Nb alloys with different Nb contents subjected to different heat treatments were investigated. Here, optical microstructure and phase compositions of Ti-Nb alloys were characterized using optical microscopy and X-ray diffractometre, while mechanical behaviors of Ti-Nb alloys were examined by using tension tests. Stress-induced martensitic transformation in a Ti-30. at%Nb binary alloy was in-situ explored by synchrotron-based high-energy X-ray diffraction (HE-XRD). The results obtained suggested that mechanical behavior of Ti-Nb alloys, especially Young's modulus was directly dependent on chemical compositions and heat treatment process. According to the results of HE-XRD, α"-V1 martensite generated priormore » to the formation of α"-V2 during loading and a partial reversible transformation from α"-V1 to β phase was detected while α"-V2 tranformed to β completely during unloading.« less

Investigation of mechanical properties of modern dental composites after artificial aging for one year.

PubMed

Hahnel, Sebastian; Henrich, Anne; Bürgers, Ralf; Handel, Gerhard; Rosentritt, Martin

2010-01-01

This in vitro study investigated the aging behavior of dental composites with regard to surface roughness (SR), Vickers hardness (VH) and flexural strength (FS), and the study elucidated the impact of artificial aging parameters. One hundred and sixty-five rectangular specimens were prepared from five composites (Filtek Supreme XT, Filtek Silorane, CeramX, Quixfil, experimental ormocer) and subjected to various artificial aging protocols (storage in distilled water/ethanol/artificial saliva for 7, 90 and 365 days; thermal cycling, 2 x 3000 cycles 5/55 degrees C). SR, VH and FS were determined at baseline and after each aging treatment. Means and standard deviations were calculated; statistical analysis was performed using three-way ANOVA and the Tukey-Kramer multiple comparison test (alpha=.05). The results showed a significant influence in the composite and aging duration on mechanical parameters; the aging medium did not have a significant influence on VH and FS, but there was a significant influence on SR. The highest overall VH was found for theexperimental ormocer; Filtek Silorane yielded the lowest values. For FS, the significantly highest values were found for Filtek Silorane, and the lowest values were found for the experimental ormocer. Prolonged aging periods (90 or 365 days) or thermal cycling led to significant decreases in both VH and FS and significant increases in SR. The findings of the current study indicate that composites differ significantly for SR and its mechanical properties with regard to FS and VH, as well as in aging behavior. Generally, artificial aging leads to a significant decrease in mechanical properties, which underlines the relevance of continuous improvement of dental composites.

Molecular dynamics study of strengthening mechanism of nanolaminated graphene/Cu composites under compression.

PubMed

Weng, Shayuan; Ning, Huiming; Fu, Tao; Hu, Ning; Zhao, Yinbo; Huang, Cheng; Peng, Xianghe

2018-02-15

Molecular dynamics simulations of nanolaminated graphene/Cu (NGCu) and pure Cu under compression are conducted to investigate the underlying strengthening mechanism of graphene and the effect of lamella thickness. It is found that the stress-strain curves of NGCu undergo 3 regimes i.e. the elastic regime I, plastic strengthening regime II and plastic flow regime III. Incorporating graphene monolayer is proved to simultaneously contribute to the strength and ductility of the composites and the lamella thickness has a great effect on the mechanical properties of NGCu composites. Different strengthening mechanisms play main role in different regimes, the transition of mechanisms is found to be related to the deformation behavior. Graphene affected zone is developed and integrated with rule of mixtures and confined layer slip model to describe the elastic properties of NGCu and the strengthening effect of the incorporated graphene.

Effects of thermal cycling on graphie-fiber-reinforced 6061 aluminum

NASA Technical Reports Server (NTRS)

Dries, G. A.; Tompkins, S. S.

1986-01-01

Graphite-reinforced aluminum alloy metal-matrix composites are among materials being considered for structural components in dimensionally stable space structures. This application requires materials with low values of thermal expansions and high specific stiffnesses. They must remain stable during exposures to the space environment for periods extending to 20 years. The effects of thermal cycling on the thermal expansion behavior and mechanical properties of Thornel P100 graphite 6061 aluminum composites, as fabricated and after thermal processing to eliminate thermal strain hysteresis, have been investigated. Two groups of composites were studied: one was fabricated by hot roll bonding and the other by diffusion bonding. Processing significantly reduced strain hysteresis during thermal cycling in both groups and improved the ultimate tensile strength and modulus in the diffusion-bonded composites. Thermal cycling stabilized the as-fabricated composites by reducing the residual fabrication stress and increased the matrix strength by metallurgical aging. Thermal expansion behavior of both groups after processing was insensitive to thermal cycling. Data scatter was too large to determine effects of thermal cycling on the mechanical properties. The primary effects of processing and thermal cycling can be attributed to changes in the metallurgical condition and stress state of the matrix.

Strengthening behavior of chopped multi-walled carbon nanotube reinforced aluminum matrix composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shin, S.E.; Bae, D.H., E-mail: donghyun@yonsei.ac.kr

2013-09-15

Strengthening behavior of the aluminum composites reinforced with chopped multi-walled carbon nanotubes (MWCNTs) or aluminum carbide formed during annealing at 500 °C has been investigated. The composites were fabricated by hot-rolling the powders which were ball-milled under various conditions. During the early annealing process, aluminum atoms can cluster inside the tube due to the diffusional flow of aluminum atoms into the tube, providing an increase of the strength of the composite. Further annealing induces the formation of the aluminum carbide phase, leading to an overall drop in the strength of the composites. While the strength of the composites can bemore » evaluated according to the rule of mixture, a particle spacing effect can be additionally imparted on the strength of the composites reinforced with the chopped MWCNTs or the corresponding carbides since the reinforcing agents are smaller than the submicron matrix grains. - Highlights: • Strengthening behavior of chopped CNT reinforced Al-based composites is investigated. • Chopped CNTs have influenced the strength and microstructures of the composites. • Chopped CNTs are created under Ar- 3% H2 atmosphere during mechanical milling. • Strength can be evaluated by the rule of the mixture and a particle spacing effect.« less

Study on influence of vibration behavior of composite material damage by holography

NASA Astrophysics Data System (ADS)

Guo, Linfeng; Zhao, Zhimin; Gao, Mingjuan; Zhuang, Xianzhong

2006-01-01

Composite material has been applied widely in aeronautics, astronautics and some other fields due to their high strength, light weight and antifatigue and etc. But in the application, composite material may be destroyed or damaged, which may have impact on its further applications. Therefore, study on the influence of behavior of composite material damage becomes a hot research. In this paper, the common composite material for aircraft is used as the test object, and a study is conducted to investigate the influence of vibration behavior of composite material damage. The authors adopt the method of light-carrier wave and time-average holography. Compared the interference fringes of composite materials before and after damage, the width of the interference fringes of hologram of the damaged composite material is narrower than that of the fringes before. It means that the off-plane displacement of each point on the test object is larger than before. Based on the elastic mechanics theory, the off-plane displacement is inverse to the bending stiffness, and the bending stiffness of the test object will decrease after it is damaged. In other words, the vibration property of the composite material changes after damages occur. The research results of the paper show that the results accord with the analysis of theory.

Characterization of Metal Matrix Composites

NASA Technical Reports Server (NTRS)

Daniel, I. M.; Chun, H. J.; Karalekas, D.

1994-01-01

Experimental methods were developed, adapted, and applied to the characterization of a metal matrix composite system, namely, silicon carbide/aluminim (SCS-2/6061 Al), and its constituents. The silicon carbide fiber was characterized by determining its modulus, strength, and coefficient of thermal expansion. The aluminum matrix was characterized thermomechanically up to 399 C (750 F) at two strain rates. The unidirectional SiC/Al composite was characterized mechanically under longitudinal, transverse, and in-plane shear loading up to 399 C (750 F). Isothermal and non-isothermal creep behavior was also measured. The applicability of a proposed set of multifactor thermoviscoplastic nonlinear constitutive relations and a computer code was investigated. Agreement between predictions and experimental results was shown in a few cases. The elastoplastic thermomechanical behavior of the composite was also described by a number of new analytical models developed or adapted for the material system studied. These models include the rule of mixtures, composite cylinder model with various thermoelastoplastic analyses and a model based on average field theory. In most cases satisfactory agreement was demonstrated between analytical predictions and experimental results for the cases of stress-strain behavior and thermal deformation behavior at different temperatures. In addition, some models yielded detailed three-dimensional stress distributions in the constituents within the composite.

Effects of Polypropylene Orientation on Mechanical and Heat Seal Properties of Polymer-Aluminum-Polymer Composite Films for Pouch Lithium-Ion Batteries.

PubMed

Zeng, Fangxinyu; Chen, Jinyao; Yang, Feng; Kang, Jian; Cao, Ya; Xiang, Ming

2018-01-16

In this study, polyamide-aluminum foil-polypropylene (PA-Al-PP) composite films with different orientation status of the PP layer were prepared, and their morphology, tensile, peeling and heat seal behavior were studied. The comparative study of tensile and fracture behaviors of single-layer film of PA, Al and PP, as well as the composite films of PA-Al, PP-Al and PA-Al-PP revealed that in PA-Al-PP composite film, the PA layer with the highest tensile strength can share the tensile stress from the Al layer during stretching, while the PP layer with the lowest tensile strength can prevent further development of the small cracks on boundary of the Al layer during stretching. Moreover, the study of heat seal behavior suggested that both the orientation status and the heat seal conditions were important factors in determining the heat seal strength ( HSS ) and failure behavior of the sample. Four failure types were observed, and a clear correspondence between HSS and failure types was found. The results also elucidated that for the composite film, only in the cases where the tensile stress was efficiently released by each layer during HSS measurement could the composite film exhibit desired high HSS that was even higher than its tensile strength.

Mechanical behavior and electrical conductivity of La1-xCaxCoO3 (x = 0, 0.2, 0.4, 0.55) perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pathak, Siddhartha; Steinmetz, David; Kuebler, Jakob

2010-01-01

This paper compares the important mechanical properties and the electrical conductivities from room temperature to 800oC of four LaCoO3 based cobaltite compositions with 0, 20, 40 and 55% Ca2+ ions substituted on the A site of the perovskite structure respectively. Ca2+ doped lanthanum cobaltite materials are strong candidates for use as cathodes in lower temperature solid oxide fuel cells operating at or below 800oC. Among these four cobaltite compositions, two (LaCoO3 and La0.8Ca0.2CoO3) were found to be phase pure materials, whereas the remaining two compositions (La0.6Ca0.4CoO3 and La0.45Ca0.55CoO3) contained precipitation of secondary phases such as CaO and Co3O4. The mechanicalmore » properties of the four compositions, in terms of Young s modulus, four-point bending strength and fracture toughness measurements, were measured at both room temperature and 800oC. At room temperature, doping with Ca2+ was found to substantially increase the mechanical properties of the cobaltites, whereas at 800oC the pure LaCoO3 composition exhibited higher modulus and strength values than La0.8Ca0.2CoO3. All of the four compositions exhibited ferroelastic behavior, as shown by the hysteresis loops generated during uniaxial load-unload compression tests. Electrical conductivity measurements showed the La0.8Ca0.2CoO3 composition to have the highest conductivity among the four compositions.« less

Laminate behavior for SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

NASA Technical Reports Server (NTRS)

Rhatt, R. T.; Phillips, R. E.

1988-01-01

The room temperature mechanical properties of SiC fiber reinforced reaction-bonded silicon nitride matrix composite laminates (SiC/RBSN) have been measured. The laminates contained approx 30 volume fraction of aligned 142-micron diameter SiC fiber in a porous RBSN matrix. Three types of laminate studied were unidirectional: (1) (0) sub 8, (2) (10) sub 8, and (3) (45) sub 8, and (90) sub 8; cross plied laminates (0 sub 2/90 sub 2); and angle plied laminates: (+45 sub 2/-45 sub 2). Each laminate contained eight fiber plies. Results of the unidirectionally reinforced composites tested at various angles to the reinforcement direction indicate large anisotropy in in-plane properties. In addition, strength properties of these composites along the fiber direction were independent of specimen gage length and were unaffected by notches normal to the fiber direction. Splitting parallel to the fiber at the notch tip appears to be the dominant crack blunting mechanism responsible for notch insensitive behavior of these composites. In-plane properties of the composites can be improved by 2-D laminate construction. Mechanical property results for (0 sub 2/90 sub 2)sub s and (+45/-45 sub 2) sub s laminates showed that their matrix failure strains were similar to that for (0) sub 8 laminates, but their primary elastic moduli, matrix cracking strengths, and ultimate composite strengths were lower. The elastic properties of unidirectional, cross-ply, and angle-ply composites can be predicted from modified constitutive equations and laminate theory. Further improvements in laminate properties may be achieved by reducing the matrix porosity and by optimizing the bond strength between the SiC fiber and RBSN matrix.

Laminate behavior for SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; Phillips, Ronald E.

1990-01-01

The room temperature mechanical properties of SiC fiber reinforced reaction-bonded silicon nitride matrix composite laminates (SiC/RBSN) have been measured. The laminates contained approx 30 volume fraction of aligned 142-micron diameter SiC fiber in a porous RBSN matrix. Three types of laminate studied were unidirectional: (1) (0) sub 8, (2) (10) sub 8, and (3) (45) sub 8, and (90) sub 8; cross plied laminates (0 sub 2/90 sub 2); and angle plied laminates: (+45 sub 2/-45 sub 2). Each laminate contained eight fiber plies. Results of the unidirectionally reinforced composites tested at various angles to the reinforcement direction indicate large anisotropy in in-plane properties. In addition, strength properties of these composites along the fiber direction were independent of specimen gage length and were unaffected by notches normal to the fiber direction. Splitting parallel to the fiber at the notch tip appears to be the dominant crack blunting mechanism responsible for notch insensitive behavior of these composites. In-plane properties of the composites can be improved by 2-D laminate construction. Mechanical property results for (0 sub 2/90 sub 2) sub s and (+45/-45 sub 2) sub s laminates showed that their matrix failure strains were similar to that for (0) sub 8 laminates, but their primary elastic moduli, matrix cracking strengths, and ultimate composite strengths were lower. The elastic properties of unidirectional, cross-ply, and angle-ply composites can be predicted from modified constitutive equations and laminate theory. Further improvements in laminate properties may be achieved by reducing the matrix porosity and by optimizing the bond strength between the SiC fiber and RBSN matrix.

Ultrafine-grained Aluminm and Boron Carbide Metal Matrix Composites

NASA Astrophysics Data System (ADS)

Vogt, Rustin

Cryomilling is a processing technique used to generate homogenously distributed boron carbide (B4C) particulate reinforcement within an ultrafine-grained aluminum matrix. The motivation behind characterizing a composite consisting of cryomilled aluminum B4C metal matrix composite is to design and develop a high-strength, lightweight aluminum composite for structural and high strain rate applications. Cryomilled Al 5083 and B4C powders were synthesized into bulk composite by various thermomechanical processing methods to form plate and extruded geometries. The effects of processing method on microstructure and mechanical behavior for the final consolidated composite were investigated. Cryomilling for extended periods of time in liquid nitrogen has shown to increase strength and thermal stability. The effects associated with cryomilling with stearic acid additions (as a process-control agent) on the degassing behavior of Al powders is investigated and results show that the liberation of compounds associated with stearic acid were suppressed in cryomilled Al powders. The effect of thermal expansion mismatch strain on strengthening due to geometrically necessary dislocations resulting from quenching is investigated and found not to occur in bulk cryomilled Al 5083 and B 4C composites. Previous cryomilled Al 5083 and B4C composites have exhibited ultrahigh strength associated with considerable strain-to-failure (>14 pct.) at high strain rates (>103/s) during mechanical testing, but only limited strain-to-failure (˜0.75 pct.) at quasi-static strain rates (10-3/s). The increased strain to failure at high strain rates is attributed to micro-flaw developments, including kinking, extensive axial splitting, and grain growth were observed after high strain rate deformation, and the significance of these mechanisms is considered.

End Effects and Load Diffusion in Composite Structures

NASA Technical Reports Server (NTRS)

Horgan, Cornelius O.; Ambur, D. (Technical Monitor); Nemeth, M. P. (Technical Monitor)

2002-01-01

The research carried out here builds on our previous NASA supported research on the general topic of edge effects and load diffusion in composite structures. Further fundamental solid mechanics studies were carried out to provide a basis for assessing the complicated modeling necessary for large scale structures used by NASA. An understanding of the fundamental mechanisms of load diffusion in composite subcomponents is essential in developing primary composite structures. Specific problems recently considered were focussed on end effects in sandwich structures and for functionally graded materials. Both linear and nonlinear (geometric and material) problems have been addressed. Our goal is the development of readily applicable design formulas for the decay lengths in terms of non-dimensional material and geometric parameters. Analytical models of load diffusion behavior are extremely valuable in building an intuitive base for developing refined modeling strategies and assessing results from finite element analyses. The decay behavior of stresses and other field quantities provides a significant aid towards this process. The analysis is also amenable to parameter study with a large parameter space and should be useful in structural tailoring studies.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holder, Aaron M.; Siol, Sebastian; Ndione, Paul F.

Structure and composition control the behavior of materials. Isostructural alloying is historically an extremely successful approach for tuning materials properties, but it is often limited by binodal and spinodal decomposition, which correspond to the thermodynamic solubility limit and the stability against composition fluctuations, respectively. We show that heterostructural alloys can exhibit a markedly increased range of metastable alloy compositions between the binodal and spinodal lines, thereby opening up a vast phase space for novel homogeneous single-phase alloys. We distinguish two types of heterostructural alloys, that is, those between commensurate and incommensurate phases. Because of the structural transition around the criticalmore » composition, the properties change in a highly nonlinear or even discontinuous fashion, providing a mechanism for materials design that does not exist in conventional isostructural alloys. The novel phase diagram behavior follows from standard alloy models using mixing enthalpies from first-principles calculations. Furthermore, thin-film deposition demonstrates the viability of the synthesis of these metastable single-phase domains and validates the computationally predicted phase separation mechanism above the upper temperature bound of the nonequilibrium single-phase region.« less

Mechanical properties and corrosion behavior of Mg-HAP composites.

PubMed

Campo, R Del; Savoini, B; Muñoz, A; Monge, M A; Garcés, G

2014-11-01

Mg and Mg-HAP composites containing 5, 10 and 15 wt% of hydroxyapatite have been produced following a powder metallurgy route that consists of mixing raw powders and consolidation by extrusion. The microstructure, texture, mechanical behavior and resistance to corrosion under a PBS solution have been studied. Addition of HAP increases the microhardness of the composites, however the yield strength under compression slightly decreases. Texture analyses reveal a fiber texture for pure Mg that is weakened increasing the HAP fraction. This texture promotes twinning and softening of Mg and Mg-5HAP during the initial deformation stages. Mg-10HAP and Mg-15HAP present a strain-hardening dependence showing no softening. The volume fraction of HAP particles weakens the texture and favors the activation of secondary slip systems. Corrosion experiments in PBS solution have shown that Mg-5HAP exhibits the best resistance to corrosion. Texture and porosity appear to be the main material features controlling the corrosion rates of Mg-HAP composites under the present conditions. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effects of electron beam radiation dose on the compatibilization behaviour in recycled polypropylene/microcrystalline cellulose composites

NASA Astrophysics Data System (ADS)

Samat, N.; Motsidi, S. N. R.; Lazim, N. H. M.

2018-01-01

The purpose of this research was to evaluate the influence of dose level of electron beam on the compatibilization behavior of recycled polypropylene (rPP) in rPP/microcrystalline cellulose (MCC) composites. Initially, the rPP was irradiated with various dose of electron beam (5 kGy up to 250 kGy) which then mixed with unirradiated rPP (u-rPP) at a ratio of 30:70 respectively. The composites were prepared by incorporating a series wt% of MCC fibers into rPP (u-rPP : i-rPP) using extruder and finally moulded with an injection moulding machine. The compatibility behavior of irradiated rPP (i-rPP) were analysed with mechanical tensile and thermal methods. The results of mechanical analysis showed great improvement in tensile modulus but an increase in radiation dosage gradually decreased this property. Nevertheless, the tensile strength exhibited a minor effect. The thermal stability of composites is lowered with increase in the absorbed dose, more significantly at higher content of MCC. Fracture surface observations reveal adhesion between the cellulose and rPP matrix.

Rigid Biological Systems as Models for Synthetic Composites

NASA Astrophysics Data System (ADS)

Mayer, George

2005-11-01

Advances that have been made in understanding the mechanisms underlying the mechanical behavior of a number of biological materials (namely mollusk shells and sponge spicules) are discussed here. Attempts at biomimicry of the structure of a nacreous layer of a mollusk shell have shown reasonable success. However, they have revealed additional issues that must be addressed if new synthetic composite materials that are based on natural systems are to be constructed. Some of the important advantages and limitations of copying from nature are also described here.

Mechanical and fracture behavior of veneer-framework composites for all-ceramic dental bridges.

PubMed

Studart, André R; Filser, Frank; Kocher, Peter; Lüthy, Heinz; Gauckler, Ludwig J

2007-01-01

High-strength ceramics are required in dental posterior restorations in order to withstand the excessive tensile stresses that occur during mastication. The aim of this study was to investigate the fracture behavior and the fast-fracture mechanical strength of three veneer-framework composites (Empress 2/IPS Eris, TZP/Cercon S and Inceram-Zirconia/Vita VM7) for all-ceramic dental bridges. The load bearing capacity of the veneer-framework composites were evaluated using a bending mechanical apparatus. The stress distribution through the rectangular-shaped layered samples was assessed using simple beam calculations and used to estimate the fracture strength of the veneer layer. Optical microscopy of fractured specimens was employed to determine the origin of cracks and the fracture mode. Under fast fracture conditions, cracks were observed to initiate on, or close to, the veneer outer surface and propagate towards the inner framework material. Crack deflection occurred at the veneer-framework interface of composites containing a tough framework material (TZP/Cercon S and Inceram-Zirconia/Vita VM7), as opposed to the straight propagation observed in the case of weaker frameworks (Empress 2/IPS Eris). The mechanical strength of dental composites containing a weak framework (K(IC)<3 MPam(1/2)) is ultimately determined by the low fracture strength of the veneer layer, since no crack arresting occurs at the veneer-framework interface. Therefore, high-toughness ceramics (K(IC)>5 MPam(1/2)) should be used as framework materials of posterior all-ceramic bridges, so that cracks propagating from the veneer layer do not lead to a premature failure of the prosthesis.

Effect of Specimen Thickness on Mechanical Behavior of SiC/SiC Composites

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.; Singh, Mrityunjay; Freedman, Marc

2004-01-01

Potential composite applications in aerospace and transportation application systems have different thickness requirements. For example, space applications such as nozzle ramps or heat exchangers use very thin (less than 1 mm) structures whereas turbine blades need very thick parts greater than or equal to cm). There has been little investigation into the effect of thickness on stress-strain behavior or elevated temperature tensile properties controlled by oxidation. In this study, composites consisting of woven Hi-NicalonTM fibers, a carbon interphase, and CVI Sic matrix were fabricated with different numbers of plies to provide variable thickness. The composites ranged from a single ply (approximately 0.4 mm) to thirty-six plies (approximately 1 cm). Tensile tests were performed at room temperature with acoustic emission used to monitor matrix crack behavior. Elevated temperature tensile stress-rupture tests were performed in air. Considerably different room and elevated temperature tensile behavior was observed that will be discussed with respect to the effect of thickness on matrix crack formation, matrix crack growth and oxidation diffusion kinetics.

Microstructure, mechanical and fretting wear properties of TiC-stainless steel composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akhtar, F.; Department of Metallurgical and Materials Engineering, University of Engineering and Technology, Lahore; Guo, S.J.

2008-01-15

This study deals with the processing, microstructure, and wear behavior of TiC-reinforced stainless steel matrix composites, containing 50 to 70 wt.% TiC. Powder technology was used to successfully fabricate the composites. The microstructure of the composite was characterized by scanning electron microscopy. The microstructural study revealed that the TiC particles were distributed uniformly in the steel matrix phase. Interface debonding and microcracks were not observed in the composite. The composite hardness increased with TiC content. The fretting wear resistance of the composites was studied against high speed steel. The wear mechanisms are discussed by means of microscopical observations on themore » worn surfaces. The wear was severe at higher wear loads and lower TiC content. Microplowing of the stainless steel matrix was found to be the dominant wear mechanism. Heavy microplowing and rapid removal of material from the wear surface was observed at high wear load. The variation of wear loss with volume fraction and mean free path of the binder phase is also reported.« less

Experimental Study on Impact-Induced Reaction Characteristics of PTFE/Ti Composites Enhanced by W Particles.

PubMed

Li, Yan; Wang, Zaicheng; Jiang, Chunlan; Niu, Haohao

2017-02-13

Metal/fluoropolymer composites are a category of energetic structural materials that release energy through exothermic chemical reactions initiated under highly dynamic loadings. In this paper, the chemical reaction mechanism of PTFE (polytetrafluoroethylene)/Ti/W composites is investigated through thermal analysis and composition analysis. These composites undergo exothermic reactions at 510 °C to 600 °C, mainly producing TiF x . The tungsten significantly reduces the reaction heat due to its inertness. In addition, the dynamic compression properties and impact-induced reaction behaviors of PTFE/Ti/W composites with different W content prepared by pressing and sintering are studied using Split Hopkinson Pressure Bar and high speed photography. The results show that both the mechanical strength and the reaction degree are significantly improved with the increasing strain rate. Moreover, as W content increases, the mechanical strength is enhanced, but the elasticity/plasticity is decreased. The PTFE/Ti/W composites tend to become more inert with the increasing W content, which is reflected by the reduced reaction degree and the increased reaction threshold for the impact ignition.

Experimental Study on Impact-Induced Reaction Characteristics of PTFE/Ti Composites Enhanced by W Particles

PubMed Central

Li, Yan; Wang, Zaicheng; Jiang, Chunlan; Niu, Haohao

2017-01-01

Metal/fluoropolymer composites are a category of energetic structural materials that release energy through exothermic chemical reactions initiated under highly dynamic loadings. In this paper, the chemical reaction mechanism of PTFE (polytetrafluoroethylene)/Ti/W composites is investigated through thermal analysis and composition analysis. These composites undergo exothermic reactions at 510 °C to 600 °C, mainly producing TiFx. The tungsten significantly reduces the reaction heat due to its inertness. In addition, the dynamic compression properties and impact-induced reaction behaviors of PTFE/Ti/W composites with different W content prepared by pressing and sintering are studied using Split Hopkinson Pressure Bar and high speed photography. The results show that both the mechanical strength and the reaction degree are significantly improved with the increasing strain rate. Moreover, as W content increases, the mechanical strength is enhanced, but the elasticity/plasticity is decreased. The PTFE/Ti/W composites tend to become more inert with the increasing W content, which is reflected by the reduced reaction degree and the increased reaction threshold for the impact ignition. PMID:28772534

Probabilistic Simulation of Multi-Scale Composite Behavior

NASA Technical Reports Server (NTRS)

Chamis, Christos C.

2012-01-01

A methodology is developed to computationally assess the non-deterministic composite response at all composite scales (from micro to structural) due to the uncertainties in the constituent (fiber and matrix) properties, in the fabrication process and in structural variables (primitive variables). The methodology is computationally efficient for simulating the probability distributions of composite behavior, such as material properties, laminate and structural responses. Bi-products of the methodology are probabilistic sensitivities of the composite primitive variables. The methodology has been implemented into the computer codes PICAN (Probabilistic Integrated Composite ANalyzer) and IPACS (Integrated Probabilistic Assessment of Composite Structures). The accuracy and efficiency of this methodology are demonstrated by simulating the uncertainties in composite typical laminates and comparing the results with the Monte Carlo simulation method. Available experimental data of composite laminate behavior at all scales fall within the scatters predicted by PICAN. Multi-scaling is extended to simulate probabilistic thermo-mechanical fatigue and to simulate the probabilistic design of a composite redome in order to illustrate its versatility. Results show that probabilistic fatigue can be simulated for different temperature amplitudes and for different cyclic stress magnitudes. Results also show that laminate configurations can be selected to increase the redome reliability by several orders of magnitude without increasing the laminate thickness--a unique feature of structural composites. The old reference denotes that nothing fundamental has been done since that time.

Modeling Composite Laminate Crushing for Crash Analysis

NASA Technical Reports Server (NTRS)

Fleming, David C.; Jones, Lisa (Technical Monitor)

2002-01-01

Crash modeling of composite structures remains limited in application and has not been effectively demonstrated as a predictive tool. While the global response of composite structures may be well modeled, when composite structures act as energy-absorbing members through direct laminate crushing the modeling accuracy is greatly reduced. The most efficient composite energy absorbing structures, in terms of energy absorbed per unit mass, are those that absorb energy through a complex progressive crushing response in which fiber and matrix fractures on a small scale dominate the behavior. Such failure modes simultaneously include delamination of plies, failure of the matrix to produce fiber bundles, and subsequent failure of fiber bundles either in bending or in shear. In addition, the response may include the significant action of friction, both internally (between delaminated plies or fiber bundles) or externally (between the laminate and the crushing surface). A figure shows the crushing damage observed in a fiberglass composite tube specimen, illustrating the complexity of the response. To achieve a finite element model of such complex behavior is an extremely challenging problem. A practical crushing model based on detailed modeling of the physical mechanisms of crushing behavior is not expected in the foreseeable future. The present research describes attempts to model composite crushing behavior using a novel hybrid modeling procedure. Experimental testing is done is support of the modeling efforts, and a test specimen is developed to provide data for validating laminate crushing models.

In vitro investigation of the performance of different restorative materials under cast circumferential clasps for removable dental prostheses.

PubMed

Pospiech, Peter; Nagel, Florian; Gebhart, Florian; Nothdurft, Frank P; Mitov, Gergo

2012-12-01

The objective of this in vitro study was to investigate the behavior of different composite restorative materials under the load of cast circumferential clasps for removable dental prostheses (RDPs). In 60 human molars, standardized mesial-occlusal-distal cavities were prepared. The cavities were restored with the following materials: Definite, Tetric Ceram, SureFil, Heliomolar RO, Ariston pHc, and Oralloy, and provided with a rest seat. The rest seats were subjected to 5,000 cycles of thermal cycling and 1,200,000 masticatory cycles in a mastication simulator via cobalt-chromium circumferential clasps cast to standardized frameworks in a laboratory model designed to simulate the biomechanics of a free-end denture base. Fracture analysis of the restorations was performed by light microscopy. Before and after loading, material wear was measured with a 3D-laser scanner, and an analysis of the marginal quality was performed in an SEM at ×200 applying the replica technique. No significant differences in the fracture behavior among the composite materials were found; the amalgam control group showed a significantly higher fracture resistance. Regarding the wear of the materials, the composites Definite and SureFil exhibited a behavior similar to that of amalgam. The other composites demonstrated higher wear rates. The initial marginal quality was significantly worse for Ariston pHc. The marginal adaptation decreased significantly after thermal and mechanical loading for Definite and Ariston pHc. In terms of the investigated aspects of mechanical performance, the tested composites seemed to be inferior to amalgam. Further clinical studies are needed to evaluate the ability of composite restorations to provide support for RDP clasps. The use of composites as direct restoration materials should be avoided in teeth, which serve as abutments for clasp-retained RDPs.

Continuous fiber-reinforced titanium aluminide composites

NASA Technical Reports Server (NTRS)

Mackay, R. A.; Brindley, P. K.; Froes, F. H.

1991-01-01

An account is given of the fabrication techniques, microstructural characteristics, and mechanical behavior of a lightweight, high service temperature SiC-reinforced alpha-2 Ti-14Al-21Nb intermetallic-matrix composite. Fabrication techniques under investigation to improve the low-temperature ductility and environmental resistance of this material system, while reducing manufacturing costs to competitive levels, encompass powder-cloth processing, foil-fiber-foil processing, and thermal-spray processing. Attention is given to composite microstructure problems associated with fiber distribution and fiber-matrix interfaces, as well as with mismatches of thermal-expansion coefficient; major improvements are noted to be required in tensile properties, thermal cycling effects, mechanical damage, creep, and environmental effects.

Modeling the mechanical behavior of ceramic and heterophase structures manufactured using selective laser sintering and spark plasma sintering

NASA Astrophysics Data System (ADS)

Skripnyak, Vladimir A.; Skripnyak, Evgeniya G.; Skripnyak, Vladimir V.; Vaganova, Irina K.

A model for predicting mechanical properties of ultra-high temperature ceramics and composites manufactured by selective laser sintering (SLS) and spark plasma sintering (SPS) under shock loading is presented. The model takes into account the porous structure, the specific volume and average sizes of phases, and the temperature of sintering. Residual stresses in ceramic composites reinforced with particles of refractory borides, carbides and nitrides after SLS or SPS were calculated. It is shown that the spall strength of diboride-zirconium matrix composites can be increased by the decreasing of porosity and the introduction of inclusions of specially selected refractory strengthening phases.

Acoustic Emission Behavior of Early Age Concrete Monitored by Embedded Sensors.

PubMed

Qin, Lei; Ren, Hong-Wei; Dong, Bi-Qin; Xing, Feng

2014-10-02

Acoustic emission (AE) is capable of monitoring the cracking activities inside materials. In this study, embedded sensors were employed to monitor the AE behavior of early age concrete. Type 1-3 cement-based piezoelectric composites, which had lower mechanical quality factor and acoustic impedance, were fabricated and used to make sensors. Sensors made of the composites illustrated broadband frequency response. In a laboratory, the cracking of early age concrete was monitored to recognize different hydration stages. The sensors were also embedded in a mass concrete foundation to localize the temperature gradient cracks.

Effect of Graphene Addition on Shape Memory Behavior of Epoxy Resins

NASA Technical Reports Server (NTRS)

Williams, Tiffany; Meador, Michael; Miller, Sandi; Scheiman, Daniel

2011-01-01

Shape memory polymers (SMPs) and composites are a special class of smart materials known for their ability to change size and shape upon exposure to an external stimulus (e.g. light, heat, pH, or magnetic field). These materials are commonly used for biomedical applications; however, recent attempts have been made towards developing SMPs and composites for use in aircraft and space applications. Implementing SMPs and composites to create a shape change effect in some aircraft structures could potentially reduce drag, decrease fuel consumption, and improve engine performance. This paper discusses the development of suitable materials to use in morphing aircraft structures. Thermally responsive epoxy SMPs and nanocomposites were developed and the shape memory behavior and thermo-mechanical properties were studied. Overall, preliminary results from dynamic mechanical analysis (DMA) showed that thermally actuated shape memory epoxies and nanocomposites possessed Tgs near approximately 168 C. When graphene nanofiller was added, the storage modulus and crosslinking density decreased. On the other hand, the addition of graphene enhanced the recovery behavior of the shape memory nanocomposites. It was assumed that the addition of graphene improved shape memory recovery by reducing the crosslinking density and increasing the elasticity of the nanocomposites.

Dispersion and Mechanical Properties of Carbon Nanotube/Polymer Composites via Melt Compounding

NASA Astrophysics Data System (ADS)

Gorga, Russell; Cohen, Robert

2003-03-01

This work is focused on the fabrication of carbon nanotube/ polymer composites via melt compounding. The main objective of this work is to realize the outstanding properties of carbon nanotubes (high modulus, high thermal and electrical conductivity, elastic buckling) at the macroscopic level by blending carbon nanotubes into a polymer matrix. The challenge lies in dispersing these one dimensional nanoparticles in the polymer matrix. Dispersion of the nanotubes in the composites is analyzed via transmission and scanning electron microscopy. Mechanical properties as well as electrical and thermal conductivity are measured as a function of nanotube loading, orientation, and extrusion conditions. Multi-wall nanotube loadings in the range of 1 and 10 wtconcave-downward departures from the linear stress-strain behavior of the unmodified polymer below 5observations are discussed in the context of possible deformation mechanisms for the nanotube composites.

Finite Element Modeling of Thermal Cycling Induced Microcracking in Carbon/Epoxy Triaxial Braided Composites

NASA Technical Reports Server (NTRS)

Zhang, Chao; Binienda, Wieslaw K.; Morscher, Gregory; Martin, Richard E.

2012-01-01

The microcrack distribution and mass change in PR520/T700s and 3502/T700s carbon/epoxy braided composites exposed to thermal cycling was evaluated experimentally. Acoustic emission was utilized to record the crack initiation and propagation under cyclic thermal loading between -55 C and 120 C. Transverse microcrack morphology was investigated using X-ray Computed Tomography. Different performance of two kinds of composites was discovered and analyzed. Based on the observations of microcrack formation, a meso-mechanical finite element model was developed to obtain the resultant mechanical properties. The simulation results exhibited a decrease in strength and stiffness with increasing crack density. Strength and stiffness reduction versus crack densities in different orientations were compared. The changes of global mechanical behavior in both axial and transverse loading conditions were studied. Keywords: Thermal cycles; Microcrack; Finite Element Model; Braided Composite

Damage evolution and mechanical response of cross-ply ceramic composite laminates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weitsman, Y.; Yu, N.; Zhu, H.

1995-12-31

A mechanistic model for the damage evolution and mechanical response of cross-ply ceramic composite laminates under monotonically increasing uniaxial tension is presented. The model accounts for a variety of damage mechanisms evolving in cross-ply ceramic composite laminates, such as fiber-bridged matrix cracks in 0{degrees}-plies, transversely oriented matrix cracks in 90{degrees}-plies, and slips at 0{degrees}/90{degrees} ply interfaces as well as at the fiber/matrix interfaces. Energy criteria are developed to determine the creation and progression of matrix cracks and slip zones. The model predicts that the crack density in 0{degrees}-plies becomes higher than that within the 90{degrees}-plies as the applied load ismore » incrementally increased, which agrees with the experimental observation. It is also shown that the model provides a reasonable prediction for the nonlinear stress-strain behavior of crossply SiC/CAS ceramic composites.« less

ASTM and VAMAS activities in titanium matrix composites test methods development

NASA Technical Reports Server (NTRS)

Johnson, W. S.; Harmon, D. M.; Bartolotta, P. A.; Russ, S. M.

1994-01-01

Titanium matrix composites (TMC's) are being considered for a number of aerospace applications ranging from high performance engine components to airframe structures in areas that require high stiffness to weight ratios at temperatures up to 400 C. TMC's exhibit unique mechanical behavior due to fiber-matrix interface failures, matrix cracks bridged by fibers, thermo-viscoplastic behavior of the matrix at elevated temperatures, and the development of significant thermal residual stresses in the composite due to fabrication. Standard testing methodology must be developed to reflect the uniqueness of this type of material systems. The purpose of this paper is to review the current activities in ASTM and Versailles Project on Advanced Materials and Standards (VAMAS) that are directed toward the development of standard test methodology for titanium matrix composites.

Fibre-matrix bond strength studies of glass, ceramic, and metal matrix composites

NASA Technical Reports Server (NTRS)

Grande, D. H.; Mandell, J. F.; Hong, K. C. C.

1988-01-01

An indentation test technique for compressively loading the ends of individual fibers to produce debonding has been applied to metal, glass, and glass-ceramic matrix composites; bond strength values at debond initiation are calculated using a finite-element model. Results are correlated with composite longitudinal and interlaminar shear behavior for carbon and Nicalon fiber-reinforced glasses and glass-ceramics including the effects of matrix modifications, processing conditions, and high-temperature oxidation embrittlement. The data indicate that significant bonding to improve off-axis and shear properties can be tolerated before the longitudinal behavior becomes brittle. Residual stress and other mechanical bonding effects are important, but improved analyses and multiaxial interfacial failure criteria are needed to adequately interpret bond strength data in terms of composite performance.

Activity of plasma sprayed yttria stabilized zirconia reinforced hydroxyapatite/Ti-6Al-4V composite coatings in simulated body fluid.

PubMed

Gu, Y W; Khor, K A; Pan, D; Cheang, P

2004-07-01

Hydroxyapatite (HA)/yttria stabilized zirconia/Ti-6Al-4V bio-composite coatings deposited onto Ti-6Al-4V substrate through a plasma spray technique were immersed in simulated body fluid (SBF) to investigate their behavior in vitro. Surface morphologies and structural changes in the coatings were analyzed by scanning electron microscopy, thin-film X-ray diffractometer, and X-ray photoelectron spectroscopy. The tensile bond strength of the coatings after immersion was also conducted through the ASTM C-633 standard for thermal sprayed coatings. Results showed that carbonate-containing hydroxyapatite (CHA) layer formed on the surface of composite coatings after 4 weeks immersion in SBF solution, indicating the composite coating possessed excellent bioactivity. The mechanical properties were found to decrease with immersion duration of maximum 56 days. However, minimal variation in mechanical properties was found subsequent to achieving supersaturation of the calcium ions, which was attained with the precipitation of the calcium phosphate layers. The mechanical properties of the composite coating were found to be significantly higher than those of pure HA coatings even after immersion in the SBF solution, indicating the enhanced mechanical properties of the composite coatings.

Electrochemical Behavior of Al-B4C Metal Matrix Composites in NaCl Solution

PubMed Central

Han, Yu-Mei; Chen, X.-Grant

2015-01-01

Aluminum based metal matrix composites (MMCs) have received considerable attention in the automotive, aerospace and nuclear industries. One of the main challenges using Al-based MMCs is the influence of the reinforcement particles on the corrosion resistance. In the present study, the corrosion behavior of Al-B4C MMCs in a 3.5 wt.% NaCl solution were investigated using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques. Results indicated that the corrosion resistance of the composites decreased when increasing the B4C volume fraction. Al-B4C composite was susceptible to pitting corrosion and two types of pits were observed on the composite surface. The corrosion mechanism of the composite in the NaCl solution was primarily controlled by oxygen diffusion in the solution. In addition, the galvanic couples that formed between Al matrix and B4C particles could also be responsible for the lower corrosion resistance of the composites. PMID:28793574

Role of Polymer Segregation on the Mechanical Behavior of All-Polymer Solar Cell Active Layers.

PubMed

Balar, Nrup; Xiong, Yuan; Ye, Long; Li, Sunsun; Nevola, Daniel; Dougherty, Daniel B; Hou, Jianhui; Ade, Harald; O'Connor, Brendan T

2017-12-20

An all-polymer bulk heterojunction (BHJ) active layer that removes the use of commonly used small molecule electron acceptors is a promising approach to improve the thermomechanical behavior of organic solar cells. However, there has been limited research on their mechanical properties. Here, we report on the mechanical behavior of high-performance blade-coated all-polymer BHJ films cast using eco-friendly solvents. The mechanical properties considered include the elastic modulus, crack onset strain, and cohesive fracture energy. We show that the mechanical behavior of the blend is largely unaffected by significant changes in the segregation characteristics of the polymers, which was varied systematically through solvent formulation. In comparison to a polymer:fullerene BHJ counterpart, the all-polymer films were found to have lower stiffness and increased ductility. Yet, the fracture energy of the all-polymer films is not significantly improved compared to that of the polymer:fullerene films. This study highlights that improved mechanical behavior of all-polymer systems cannot be assumed, and that details of the molecular structure, molecular weight, and film morphology play an important role in both the optoelectronic and mechanical properties. Furthermore, we show that simple composite modeling provides a predictive tool for the mechanical properties of the polymer blend films, providing a framework to guide future optimization of the mechanical behavior.

Dynamic behavior of the mechanical systems from the structure of a hybrid automobile

NASA Astrophysics Data System (ADS)

Dinel, Popa; Irina, Tudor; Nicolae-Doru, Stănescu

2017-10-01

In introduction are presented solutions of planetary mechanisms that can be used in the construction of the hybrid automobiles where the thermal and electrical sources must be coupled. The systems have in their composition a planetary mechanism with two degrees of mobility at which are coupled a thermal engine, two revertible electrical machines, a gear transmission with four gears and a differential mechanism which transmits the motion at the driving wheels. For the study of the dynamical behavior, with numerical results, one designs such mechanisms, models the elements with solids in AutoCAD, and obtains the mechanical properties of the elements. Further on, we present and solve the equations of motion of a hybrid automotive for which one knows the dynamical parameters.

On Some Mechanical Properties and Wear Behavior of Sintered Bronze Based Composites Reinforced with Some Aluminides Microadditives

NASA Astrophysics Data System (ADS)

Feldshtein, E.; Kiełek, P.; Kiełek, T.; Dyachkova, L.; Letsko, A.

2017-05-01

In the paper, the changes in some mechanical properties and wear behavior of CuSn10 sintered bronze and MMCs based on this bronze reinforced with composite ultrafine aluminide powders FeAl/15 % Al2O3, NiAl/15 % Al2O3 and Ti-46Al-8Cr are described. It was observed that the presence of aluminides in the MMCs leads to an increase in the hardness, but the flexural strength may increase or decrease depending on the type of aluminide. The presence of aluminides in the MMC reduces the wear rate considerably. It is decreased in the direction of FeAl/15 % Al2O3 → NiAl/15 % Al2O3 → Ti-46Al-8Cr aluminides and for the best MMC composition the advantage is about 20 times. In the MMCs wear process, micro-craters are formed on the contact surface and it is the principal reason of a decrease in the wear rate.

Comparison of biofouling mechanisms between cellulose triacetate (CTA) and thin-film composite (TFC) polyamide forward osmosis membranes in osmotic membrane bioreactors.

PubMed

Wang, Xinhua; Zhao, Yanxiao; Yuan, Bo; Wang, Zhiwei; Li, Xiufen; Ren, Yueping

2016-02-01

There are two types of popular forward osmosis (FO) membrane materials applied for researches on FO process, cellulose triacetate (CTA) and thin film composite (TFC) polyamide. However, performance and fouling mechanisms of commercial TFC FO membrane in osmotic membrane bioreactors (OMBRs) are still unknown. In current study, its biofouling behaviors in OMBRs were investigated and further compared to the CTA FO membrane. The results indicated that β-D-glucopyranose polysaccharides and microorganisms accounted for approximately 77% of total biovolume on the CTA FO membrane while β-D-glucopyranose polysaccharides (biovolume ratio of 81.1%) were the only dominant biofoulants on the TFC FO membrane. The analyses on the biofouling structure implied that a tighter biofouling layer with a larger biovolume was formed on the CTA FO membrane. The differences in biofouling behaviors including biofoulants composition and biofouling structure between CTA and TFC FO membranes were attributed to different membrane surface properties. Copyright © 2015 Elsevier Ltd. All rights reserved.

A general computation model based on inverse analysis principle used for rheological analysis of W/O rapeseed and soybean oil emulsions

NASA Astrophysics Data System (ADS)

Vintila, Iuliana; Gavrus, Adinel

2017-10-01

The present research paper proposes the validation of a rigorous computation model used as a numerical tool to identify rheological behavior of complex emulsions W/O. Considering a three-dimensional description of a general viscoplastic flow it is detailed the thermo-mechanical equations used to identify fluid or soft material's rheological laws starting from global experimental measurements. Analyses are conducted for complex emulsions W/O having generally a Bingham behavior using the shear stress - strain rate dependency based on a power law and using an improved analytical model. Experimental results are investigated in case of rheological behavior for crude and refined rapeseed/soybean oils and four types of corresponding W/O emulsions using different physical-chemical composition. The rheological behavior model was correlated with the thermo-mechanical analysis of a plane-plane rheometer, oil content, chemical composition, particle size and emulsifier's concentration. The parameters of rheological laws describing the industrial oils and the W/O concentrated emulsions behavior were computed from estimated shear stresses using a non-linear regression technique and from experimental torques using the inverse analysis tool designed by A. Gavrus (1992-2000).

The Effects of Fiber Orientation and Volume Fraction of Fiber on Mechanical Properties of Additively Manufactured Composite Material

NASA Astrophysics Data System (ADS)

Kuchipudi, Suresh Chandra

Additive manufacturing (AM) also known as 3D printing has tremendous advancements in recent days with a vast number of applications in industrial, automotive, architecture, consumer projects, fashion, toys, food, art, etc. Composite materials are widely used in structures with weight as a critical factor especially in aerospace industry. Recently, additive manufacturing technology, a rapidly growing innovative technology, has gained lot of importance in making composite materials. The properties of composite materials depend upon the properties of constituent's matrix and fiber. There is lot of research on effect of fiber orientation on mechanical properties of composite materials made using conventional manufacturing methods. It will be interesting and relevant to study the relationship between the fiber orientation and fiber volume with mechanical properties of additively manufactured composite materials. This thesis work presents experimental investigation of mechanical behavior like tensile strength and fatigue life with variation in fiber orientation and fiber volume fraction of 3D printed composite materials. The aim is to study the best combination of volume fraction of fiber and fiber orientation that has better fatigue strength for additive manufactured composite materials. Using this study, we can decide the type of orientation and volume percent for desired properties. This study also finds the range of fatigue limits of 3d printed composite materials.

Atomic-level study on mechanical properties and strengthening mechanisms of Al/SiC nano-composites

NASA Astrophysics Data System (ADS)

Huo, Shiyan; Xie, Lijing; Xiang, Junfeng; Pang, Siqin; Hu, Fang; Umer, Usama

2018-02-01

Molecular dynamics (MD) models for the study on the mechanical properties of β-SiC particles-reinforced aluminum matrix nano-composites (Al/SiC nano-composites) are established. The nano-composites in the model are fabricated by a powder metallurgy (P/M) process, followed by a hot isostatic pressing and then annealing to room temperature. The fabricated nano-composites have dense and even distributions of reinforced particles. Then representative volume elements (RVEs) of the fabricated nano-composites are built by adding periodic boundary conditions (PBCs). In this way, RVEs with different volume fractions and particle sizes of SiC are produced and put into the simulation of tension tests. The elasticity and strength in single axial tension obtained from MD analysis are in good agreement with those calculated according to the rule of mixture. It is found that the dispersion of SiC particles into the Al matrix leads to a significant enhancement in the strength of nano-composites compared to pure Al, which is also dramatically affected by both the volume fraction and particle size. Additionally, the Al/SiC nano-composites with finer SiC particles get greater enhancement in the mechanical behavior than those with coarser ones. MD analysis clearly shows the contributions of load-transfer effect, thermal mismatch strengthening and Orowan strengthening to the strengthening of Al/SiC nano-composites.

Stress Corrosion Cracking of Basalt/Epoxy Composites under Bending Loading

NASA Astrophysics Data System (ADS)

Shokrieh, Mahmood M.; Memar, Mahdi

2010-04-01

The purpose of this research is to study the stress corrosion behavior of basalt/epoxy composites under bending loading and submerged in 5% sulfuric acid corrosive medium. There are limited numbers of research in durability of fiber reinforced polymer composites. Moreover, studies on basalt fibers and its composites are very limited. In this research, mechanical property degradation of basalt/epoxy composites under bending loading and submerged in acidic corrosive medium is investigated. Three states of stress, equal to 30%, 50% and 70% of the ultimate strength of composites, are applied on samples. High stress states are applied to the samples to accelerate the testing procedure. Mechanical properties degradation consists of bending strength, bending modulus of elasticity and fracture energy of samples are examined. Also, a normalized strength degradation model for stress corrosion condition is presented. Finally, microscopic images of broken cross sections of samples are examined.

Effect of severely thermal shocked MWCNT enhanced glass fiber reinforced polymer composite: An emphasis on tensile and thermal responses

NASA Astrophysics Data System (ADS)

Mahato, K. K.; Fulmali, A. O.; Kattaguri, R.; Dutta, K.; Prusty, R. K.; Ray, B. C.

2018-03-01

Fiber reinforced polymeric (FRP) composite materials are exposed to diverse changing environmental temperatures during their in-service period. Current investigation is aimed to investigate the influence of thermal-shock exposure on the mechanical behavior of multiwalled carbon nanotube (MWCNT) enhanced glass fiber reinforced polymeric (GFRP) composites. The samples were exposed to +70°C for 36 hrs followed by further exposure to ‑ 60°C for the similar interval of time. Tensile tests were conducted in order to evaluate the results of thermal-shock on the mechanical behavior of the neat and conditioned samples at 1 mm/min loading rate. The polymer phase i.e. epoxy was modified with various MWCNT content. The ultimate tensile strength (UTS) was raised by 15.11 % with increase in the 0.1 % MWCNT content GFRP as related to the thermal-shocked neat GFRP conditioned samples. The possible reason may be attributed to the variation in the coefficients of thermal expansion at the time of conditioning. Also, upto some extent the pre-existing residual stresses allows uniform distribution of stress and hence the reason in enhanced mechanical properties of GFRP and MWCNT filled composites. In order to access the modifications in the glass transition temperature (Tg) due to the addition of MWCNT in GFRP composite and also due to the thermal shock temperature modulated differential scanning calorimeter (TMDSC) measurements are carried out. Scanning electron microscopy(SEM) was carried out to identify different modes of failures and strengthening morphology in the composites.

Analysis of dynamic properties for a composite laminated beam at intermediate strain rate

NASA Astrophysics Data System (ADS)

Lin, J. C.; Pendleton, R. L.; Dolan, D. F.

The dynamic mechanical behavior of a graphite epoxy composite laminate in flexural vibration has been investigated. The effects of fiber orientation and vibration frequency for both unidirectional tape and Kevlar fabric were studied both analytically and experimentally. Measurement of storage and loss moduli were presented for laminated double cantilever beams of fiber reinforced composite with frequency range from 8 to 1230 Hz (up to 5th mode).

Tendon exhibits complex poroelastic behavior at the nanoscale as revealed by high-frequency AFM-based rheology.

PubMed

Connizzo, Brianne K; Grodzinsky, Alan J

2017-03-21

Tendons transmit load from muscle to bone by utilizing their unique static and viscoelastic tensile properties. These properties are highly dependent on the composition and structure of the tissue matrix, including the collagen I hierarchy, proteoglycans, and water. While the role of matrix constituents in the tensile response has been studied, their role in compression, particularly in matrix pressurization via regulation of fluid flow, is not well understood. Injured or diseased tendons and tendon regions that naturally experience compression are known to have alterations in glycosaminoglycan content, which could modulate fluid flow and ultimately mechanical function. While recent theoretical studies have predicted tendon mechanics using poroelastic theory, no experimental data have directly demonstrated such behavior. In this study, we use high-bandwidth AFM-based rheology to determine the dynamic response of tendons to compressive loading at the nanoscale and to determine the presence of poroelastic behavior. Tendons are found to have significant characteristic dynamic relaxation behavior occurring at both low and high frequencies. Classic poroelastic behavior is observed, although we hypothesize that the full dynamic response is caused by a combination of flow-dependent poroelasticity as well as flow-independent viscoelasticity. Tendons also demonstrate regional dependence in their dynamic response, particularly near the junction of tendon and bone, suggesting that the structural and compositional heterogeneity in tendon may be responsible for regional poroelastic behavior. Overall, these experiments provide the foundation for understanding fluid-flow-dependent poroelastic mechanics of tendon, and the methodology is valuable for assessing changes in tendon matrix compressive behavior at the nanoscale. Copyright © 2017 Elsevier Ltd. All rights reserved.

Progressive fracture of polymer matrix composite structures: A new approach

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

1992-01-01

A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive fracture of polymer matrix composite structures. The damage stages are quantified based on physics via composite mechanics while the degradation of the structural behavior is quantified via the finite element method. The approach account for all types of composite behavior, structures, load conditions, and fracture processes starting from damage initiation, to unstable propagation and to global structural collapse. Results of structural fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach. Parameters and guidelines are identified which can be used as criteria for structural fracture, inspection intervals, and retirement for cause. Generalization to structures made of monolithic metallic materials are outlined and lessons learned in undertaking the development of new approaches, in general, are summarized.

Development of FRP composite structural biomaterials: ultimate strength of the fiber/matrix interfacial bond in in vivo simulated environments.

PubMed

Latour, R A; Black, J

1992-05-01

Fiber reinforced polymer (FRP) composites are being developed as alternatives to metals for structural orthopedic implant applications. FRP composite fracture behavior and environmental interactions are distinctly different from those which occur in metals. These differences must be accounted for in the design and evaluation of implant performance. Fiber/matrix interfacial bond strength in a FRP composite is known to strongly influence fracture behavior. The interfacial bond strength of four candidate fiber/matrix combinations (carbon fiber/polycarbonate, carbon fiber/polysulfone, polyaramid fiber/polycarbonate, polyaramid fiber/polysulfone) were investigated at 37 degrees C in dry and in vivo simulated (saline, exudate) environments. Ultimate bond strength was measured by a single fiber-microdroplet pull-out test. Dry bond strengths were significantly decreased following exposure to either saline or exudate with bond strength loss being approximately equal in both the saline and exudate. Bond strength loss is attributed to the diffusion of water and/or salt ions into the sample and their interaction with interfacial bonding. Because bond degradation is dependent upon diffusion, diffusional equilibrium must be obtained in composite test samples before the full effect of the test environment upon composite mechanical behavior can be determined.

Long-Term Viscoelastic Response of E-glass/Bismaleimide Composite in Seawater Environment

NASA Astrophysics Data System (ADS)

Yian, Zhao; Zhiying, Wang; Keey, Seah Leong; Boay, Chai Gin

2015-12-01

The effect of seawater absorption on the long-term viscoelastic response of E-glass/BMI composite is presented in this paper. The diffusion of seawater into the composite shows a two-stage behavior, dominated by Fickian diffusion initially and followed by polymeric relaxation. The Glass transition temperature (Tg) of the composite with seawater absorption is considerably lowered due to the plasticization effect. However the effect of water absorption at 50 °C is found to be reversible after drying process. The time-temperature superposition (TTS) was performed based on the results of Dynamic Mechanical Analysis to construct the master curve of storage modulus. The shift factors exhibit Arrhenius behavior when temperature is well below Tg and Vogel-Fulcher-Tammann (VFT) like behavior when temperature gets close to glass transition region. As a result, a semi-empirical formulation is proposed to account for the seawater absorption effect in predicting long-term viscoelastic response of BMI composites based on temperature dependent storage modulus and TTS. The predicted master curves show that the degradation of storage modulus accelerates with both seawater exposure and increasing temperature. The proposed formulation can be applied to predict the long-term durability of any thermorheologically simple composite materials in seawater environment.

Investigation on Polylactide (PLA)/Poly(butylene adipate-co-terephthalate) (PBAT)/Bark Flour of Plane Tree (PF) Eco-Composites

PubMed Central

Dou, Qiang; Cai, Jun

2016-01-01

Polylactide (PLA)/poly(butylene adipate-co-terephthalate) (PBAT)/bark flour of plane tree (PF) eco-composites were prepared via melt blending. The morphologies, mechanical properties, crystal structures and melting and crystallization behaviors of the eco-composites were investigated by means of scanning electron microscopy (SEM), mechanical tests, polarized light microscopy (PLM), wide angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC), respectively. It is shown that the interfacial adhesion between PLA matrix and PF is weak and the mechanical properties of PLA/PF eco-composites are poor. The titanate treatment improves the adhesion between the matrix and the filler and enhances the stiffness of the eco-composites. The toughness is improved by PBAT and ductile fractured surfaces can be found. The spherulitic size of PLA is decreased by the addition of PF. The α crystalline form of PLA remains in the composites. Compared with PF, T-PF (PF treated by a titanate coupling agent) and PBAT have negative effects on the crystallization of PLA. PMID:28773515

Computational Simulation of the Formation and Material Behavior of Ice

NASA Technical Reports Server (NTRS)

Tong, Michael T.; Singhal, Surendra N.; Chamis, Christos C.

1994-01-01

Computational methods are described for simulating the formation and the material behavior of ice in prevailing transient environments. The methodology developed at the NASA Lewis Research Center was adopted. A three dimensional finite-element heat transfer analyzer was used to predict the thickness of ice formed under prevailing environmental conditions. A multi-factor interaction model for simulating the material behavior of time-variant ice layers is presented. The model, used in conjunction with laminated composite mechanics, updates the material properties of an ice block as its thickness increases with time. A sample case of ice formation in a body of water was used to demonstrate the methodology. The results showed that the formation and the material behavior of ice can be computationally simulated using the available composites technology.

An Efficient Analysis Methodology for Fluted-Core Composite Structures

NASA Technical Reports Server (NTRS)

Oremont, Leonard; Schultz, Marc R.

2012-01-01

The primary loading condition in launch-vehicle barrel sections is axial compression, and it is therefore important to understand the compression behavior of any structures, structural concepts, and materials considered in launch-vehicle designs. This understanding will necessarily come from a combination of test and analysis. However, certain potentially beneficial structures and structural concepts do not lend themselves to commonly used simplified analysis methods, and therefore innovative analysis methodologies must be developed if these structures and structural concepts are to be considered. This paper discusses such an analysis technique for the fluted-core sandwich composite structural concept. The presented technique is based on commercially available finite-element codes, and uses shell elements to capture behavior that would normally require solid elements to capture the detailed mechanical response of the structure. The shell thicknesses and offsets using this analysis technique are parameterized, and the parameters are adjusted through a heuristic procedure until this model matches the mechanical behavior of a more detailed shell-and-solid model. Additionally, the detailed shell-and-solid model can be strategically placed in a larger, global shell-only model to capture important local behavior. Comparisons between shell-only models, experiments, and more detailed shell-and-solid models show excellent agreement. The discussed analysis methodology, though only discussed in the context of fluted-core composites, is widely applicable to other concepts.

Metal Matrix Laminate Tailoring (MMLT) code: User's manual

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Morel, M. R.; Saravanos, D. A.

1993-01-01

The User's Manual for the Metal Matrix Laminate Tailoring (MMLT) program is presented. The code is capable of tailoring the fabrication process, constituent characteristics, and laminate parameters (individually or concurrently) for a wide variety of metal matrix composite (MMC) materials, to improve the performance and identify trends or behavior of MMC's under different thermo-mechanical loading conditions. This document is meant to serve as a guide in the use of the MMLT code. Detailed explanations of the composite mechanics and tailoring analysis are beyond the scope of this document, and may be found in the references. MMLT was developed by the Structural Mechanics Branch at NASA Lewis Research Center (LeRC).

Mechanical Behavior of Al-SiC Nanolaminate Composites Using Micro-Scale Testing Methods

NASA Astrophysics Data System (ADS)

Mayer, Carl Randolph

Nanolaminate composite materials consist of alternating layers of materials at the nanoscale (≤100 nm). Due to the nanometer scale thickness of their layers, these materials display unique and tailorable properties. This enables us to alter both mechanical attributes such as strength and wear properties, as well as functional characteristics such as biocompatibility, optical, and electronic properties. This dissertation focuses on understanding the mechanical behavior of the Al-SiC system. From a practical perspective, these materials exhibit a combination of high toughness and strength which is attractive for many applications. Scientifically, these materials are interesting due to the large elastic modulus mismatch between the layers. This, paired with the small layer thickness, allows a unique opportunity for scientists to study the plastic deformation of metals under extreme amounts of constraint. Previous studies are limited in scope and a more diverse range of mechanical characterization is required to understand both the advantages and limitations of these materials. One of the major challenges with testing these materials is that they are only able to be made in thicknesses on the order of micrometers so the testing methods are limited to small volume techniques. This work makes use of both microscale testing techniques from the literature as well as novel methodologies. Using these techniques we are able to gain insight into aspects of the material's mechanical behavior such as the effects of layer orientation, flaw dependent fracture, tension-compression asymmetry, fracture toughness as a function of layer thickness, and shear behavior as a function of layer thickness.

Effects of Polypropylene Orientation on Mechanical and Heat Seal Properties of Polymer-Aluminum-Polymer Composite Films for Pouch Lithium-Ion Batteries

PubMed Central

Chen, Jinyao; Yang, Feng; Kang, Jian; Cao, Ya; Xiang, Ming

2018-01-01

In this study, polyamide-aluminum foil-polypropylene (PA-Al-PP) composite films with different orientation status of the PP layer were prepared, and their morphology, tensile, peeling and heat seal behavior were studied. The comparative study of tensile and fracture behaviors of single-layer film of PA, Al and PP, as well as the composite films of PA-Al, PP-Al and PA-Al-PP revealed that in PA-Al-PP composite film, the PA layer with the highest tensile strength can share the tensile stress from the Al layer during stretching, while the PP layer with the lowest tensile strength can prevent further development of the small cracks on boundary of the Al layer during stretching. Moreover, the study of heat seal behavior suggested that both the orientation status and the heat seal conditions were important factors in determining the heat seal strength (HSS) and failure behavior of the sample. Four failure types were observed, and a clear correspondence between HSS and failure types was found. The results also elucidated that for the composite film, only in the cases where the tensile stress was efficiently released by each layer during HSS measurement could the composite film exhibit desired high HSS that was even higher than its tensile strength. PMID:29337881

Innovative Structural Materials and Sections with Strain Hardening Cementitious Composites

NASA Astrophysics Data System (ADS)

Dey, Vikram

The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites phases using servo-hydraulic and digital image correlation techniques. Structural behavior of these systems were predicted using ductility based design procedures using classical laminate theory and structural mechanics. SHCC sections are made up of thin sections of matrix with Portland cement based binder and fine aggregates impregnating continuous one-dimensional fibers in individual or bundle form or two/three dimensional woven, bonded or knitted textiles. Traditional fiber reinforced concrete (FRC) use random dispersed chopped fibers in the matrix at a low volume fractions, typically 1-2% to avoid to avoid fiber agglomeration and balling. In conventional FRC, fracture localization occurs immediately after the first crack, resulting in only minor improvement in toughness and tensile strength. However in SHCC systems, distribution of cracking throughout the specimen is facilitated by the fiber bridging mechanism. Influence of material properties of yarn, composition, geometry and weave patterns of textile in the behavior of laminated SHCC skin composites were investigated. Contribution of the cementitious matrix in the early age and long-term performance of laminated composites was studied with supplementary cementitious materials such as fly ash, silica fume, and wollastonite. A closed form model with classical laminate theory and ply discount method, coupled with a damage evolution model was utilized to simulate the non-linear tensile response of these composite materials. A constitutive material model developed earlier in the group was utilized to characterize and correlate the behavior of these structural composites under uniaxial tension and flexural loading responses. Development and use of analytical models enables optimal design for application of these materials in structural applications. Another area of immediate focus is the development of new construction products from SHCC laminates such as angles, channels, hat sections, closed sections with optimized cross sections. Sandwich composites with stress skin-cellular core concept were also developed to utilize strength and ductility of fabric reinforced skin in addition to thickness, ductility, and thermal benefits of cellular core materials. The proposed structurally efficient and durable sections promise to compete with wood and light gage steel based sections for lightweight construction and panel application.

Effects of Grain Orientation on Cu6Sn5 Growth Behavior in Cu6Sn5-Reinforced Composite Solder Joints During Electromigration

NASA Astrophysics Data System (ADS)

Han, Jing; Wang, Yan; Tan, Shihai; Guo, Fu

2018-02-01

Electromigration is a major reliability problem in composite solder joints. Due to the anisotropy of the β-Sn crystal structure, the Sn grain orientations present in the solder matrix dominate the principal failure mechanism in solder joints under electric current stressing. In this work, the Cu6Sn5 growth behavior in Cu6Sn5-reinforced composite solder joints with three different Sn grain orientations was investigated at current density of 104 A/cm2 at room temperature. Micron-sized Cu particles were added to Sn-3.5Ag solder at 2% volume fraction using an in situ method. After current stressing for 528 h, the polarity effect in the composite solder joint was greatest for an angle ( θ) between the c-axis and electron flow direction of 30°, resulting in higher growth rate of Cu6Sn5 in the solder matrix compared with composite solder joints with θ of 60° or 90°. There were no noticeable changes in the composite solder joint with θ of 90°. The growth behavior of Cu6Sn5, Cu atomic motion, and Cu diffusivity in the composite solder joints with different Sn grain orientations were analyzed in detail.

Advanced bredigite-containing magnesium-matrix composites for biodegradable bone implant applications.

PubMed

Dezfuli, Sina Naddaf; Huan, Zhiguang; Mol, Arjan; Leeflang, Sander; Chang, Jiang; Zhou, Jie

2017-10-01

The present research was aimed at developing magnesium-matrix composites that could allow effective control over their physiochemical and mechanical responses when in contact with physiological solutions. A biodegradable, bioactive ceramic - bredigite was chosen as the reinforcing phase in the composites, based on the hypothesis that the silicon- and magnesium-containing ceramic could protect magnesium from fast corrosion and at the same time stimulate cell proliferation. Methods to prepare composites with integrated microstructures - a prerequisite to achieve controlled biodegradation were developed. A systematic experimental approach was taken in order to elucidate the in vitro biodegradation mechanisms and kinetics of the composites. It was found that the composites with 20-40% homogenously dispersed bredigite particles, prepared from powders, could indeed significantly decrease the degradation rate of magnesium by up to 24 times. Slow degradation of the composites resulted in the retention of the mechanical integrity of the composites within the strength range of cortical bone after 12days of immersion in a cell culture medium. Cell attachment, cytotoxicity and bioactivity tests confirmed the stimulatory effects of bredigite embedded in the composites on the attachment, viability and differentiation of bone marrow stromal cells. Thus, the multiple benefits of adding bredigite to magnesium in enhancing degradation behavior, mechanical properties, biocompatibility and bioactivity were obtained. The results from this research showed the excellent potential of the bredigite-containing composites for bone implant applications, thus warranting further in vitro and in vivo research. Copyright © 2017 Elsevier B.V. All rights reserved.

High Temperature Mechanical Characterization and Analysis of Al2O3 /Al2O3 Composition

NASA Technical Reports Server (NTRS)

Gyekenyesi, John Z.; Jaskowiak, Martha H.

1999-01-01

Sixteen ply unidirectional zirconia coated single crystal Al2O3 fiber reinforced polycrystalline Al2O3 was tested in uniaxial tension at temperatures to 1400 C in air. Fiber volume fractions ranged from 26 to 31%. The matrix has primarily open porosity of approximately 40%. Theories for predicting the Young's modulus, first matrix cracking stress, and ultimate strength were applied and evaluated for suitability in predicting the mechanical behavior of Al2O3/Al2O3 composites. The composite exhibited pseudo tough behavior (increased area under the stress/strain curve relative to monolithic alumina) from 22 to 1400 C. The rule-of-mixtures provides a good estimate of the Young's modulus of the composite using the constituent properties from room temperature to approximately 1200 C for short term static tensile tests in air. The ACK theory provides the best approximation of the first matrix cracking stress while accounting for residual stresses at room temperature. Difficulties in determining the fiber/matrix interfacial shear stress at high temperatures prevented the accurate prediction of the first matrix cracking stress above room temperature. The theory of Cao and Thouless, based on Weibull statistics, gave the best prediction for the composite ultimate tensile strength.

Fatigue Behavior of a Cross-Ply Ceramic Matrix Composite Under Tension-Tension and Tension-Compression Loading.

DTIC Science & Technology

1992-12-01

Majidi [5] had experimented with cross-ply Nicalon/CAS and varied the number of plies. They theorized that the number of plies affected when the transverse...74, No 11, November 1991, p 2851 - 2858 5. Wang, S.-W., and Parvizi- Majidi , A., "Mechanical Behavior of Nicalon Fiber-Reinforced Calcium

Probabilistic assessment of uncertain adaptive hybrid composites

NASA Technical Reports Server (NTRS)

Shiao, Michael C.; Singhal, Surendra N.; Chamis, Christos C.

1994-01-01

Adaptive composite structures using actuation materials, such as piezoelectric fibers, were assessed probabilistically utilizing intraply hybrid composite mechanics in conjunction with probabilistic composite structural analysis. Uncertainties associated with the actuation material as well as the uncertainties in the regular (traditional) composite material properties were quantified and considered in the assessment. Static and buckling analyses were performed for rectangular panels with various boundary conditions and different control arrangements. The probability density functions of the structural behavior, such as maximum displacement and critical buckling load, were computationally simulated. The results of the assessment indicate that improved design and reliability can be achieved with actuation material.

Progressive damage, fracture predictions and post mortem correlations for fiber composites

NASA Technical Reports Server (NTRS)

1985-01-01

Lewis Research Center is involved in the development of computational mechanics methods for predicting the structural behavior and response of composite structures. In conjunction with the analytical methods development, experimental programs including post failure examination are conducted to study various factors affecting composite fracture such as laminate thickness effects, ply configuration, and notch sensitivity. Results indicate that the analytical capabilities incorporated in the CODSTRAN computer code are effective in predicting the progressive damage and fracture of composite structures. In addition, the results being generated are establishing a data base which will aid in the characterization of composite fracture.

High Performance Composites and Adhesives for V/STOL Aircraft.

DTIC Science & Technology

1984-02-22

out to examine the effect of humidity and out-time on the processing behavior and the mechanical properties of C-10/T-300 composites. 39 M&ffcici...stored at room temperature in two separate environmental chambers, controlled at l6% and 95/« relative humidity , respective- ly. At the end of every...NBS Special Publication 563, 17 (Oct 1979). " Effects of Prepreg Out-time and Humidity on the Composition and Processing of Polyimide/Graphite

Thermo-Mechanical and Thermal behavior of High-Temperature Structural Materials.

DTIC Science & Technology

1982-12-31

34-’- Mr. 3. D. SilboldMr-J-..ibl Columbus, OH 43201 Coor Porcelain Company 17750 W. 32nd Avenue Dr. R. E. Engdahl Golden, CO 80401 Deposits and Composites ...number) Thermal shock, thermal stress, thermal diffusivity, thermal conductivity; refractories, composites , radiation heat transfer, cyclic heating...Hasselman and R. Ruh, "Effect of Hot-Pressing 4 -; Temperature on the Thermal Diffusivity/Conductivity of SiC-AIN Composites ." III M. A. Bucknam, L. D

Acoustic emission monitoring of polymer composite materials

NASA Technical Reports Server (NTRS)

Bardenheier, R.

1981-01-01

The techniques of acoustic emission monitoring of polymer composite materials is described. It is highly sensitive, quasi-nondestructive testing method that indicates the origin and behavior of flaws in such materials when submitted to different load exposures. With the use of sophisticated signal analysis methods it is possible the distinguish between different types of failure mechanisms, such as fiber fracture delamination or fiber pull-out. Imperfections can be detected while monitoring complex composite structures by acoustic emission measurements.

Coupled multi-disciplinary composites behavior simulation

NASA Technical Reports Server (NTRS)

Singhal, Surendra N.; Murthy, Pappu L. N.; Chamis, Christos C.

1993-01-01

The capabilities of the computer code CSTEM (Coupled Structural/Thermal/Electro-Magnetic Analysis) are discussed and demonstrated. CSTEM computationally simulates the coupled response of layered multi-material composite structures subjected to simultaneous thermal, structural, vibration, acoustic, and electromagnetic loads and includes the effect of aggressive environments. The composite material behavior and structural response is determined at its various inherent scales: constituents (fiber/matrix), ply, laminate, and structural component. The thermal and mechanical properties of the constituents are considered to be nonlinearly dependent on various parameters such as temperature and moisture. The acoustic and electromagnetic properties also include dependence on vibration and electromagnetic wave frequencies, respectively. The simulation is based on a three dimensional finite element analysis in conjunction with composite mechanics and with structural tailoring codes, and with acoustic and electromagnetic analysis methods. An aircraft engine composite fan blade is selected as a typical structural component to demonstrate the CSTEM capabilities. Results of various coupled multi-disciplinary heat transfer, structural, vibration, acoustic, and electromagnetic analyses for temperature distribution, stress and displacement response, deformed shape, vibration frequencies, mode shapes, acoustic noise, and electromagnetic reflection from the fan blade are discussed for their coupled effects in hot and humid environments. Collectively, these results demonstrate the effectiveness of the CSTEM code in capturing the coupled effects on the various responses of composite structures subjected to simultaneous multiple real-life loads.

Long-life physical property preservation and postendodontic rehabilitation with the Composipost.

PubMed

Duret, B; Duret, F; Reynaud, M

1996-01-01

Most coronal radicular reconstructions are made of cast inlay core metals or prefabricated posts covered in composite. The differences in the mechanical properties of these elements create a heterogeneous mass with inconsistent mechanical behavior. Studies using the Finite Element Method have shown the biomechanical disturbances caused by the inclusion of materials with a modulus of elasticity that is superior to that of dentine (i.e., nickel, chrome, zircon, etc). The use of materials with a modulus of elasticity close to that of dentine does not disturb the flow of stress inside the root. To our knowledge, only a composite material structured with programmable mechanical properties would be capable of producing both high mechanical performance and a modulus of elasticity adapted to dentine values. The C-POST, made of carbon epoxy, accommodates the demands of the dentine, as well as the in vitro stress linked to the prosthesis. The internal structure, consisting of long high-performance carbon fibers, unidirectionally and equally stretched, confers a totally original behavior that is adapted to clinical objectives. In addition, the C-POST has a fracture resistance superior to most metals.

High elongation elastomers

NASA Technical Reports Server (NTRS)

Brady, V. L.; Reed, R.; Merwin, L.; Nissan, R.

1994-01-01

A new class of liquid curable elastomers with unusual strength and elasticity has been developed at the Naval Air Warfare Center Weapons Division, China Lake. Over the years, studies have been conducted on polymer structure and its influence on the mechanical properties of the ensuing composites. Different tools, including nuclear magnetic resonance, have been used. This paper presents a summary of the factors controlling the mechanical behavior of composites produced with the new liquid curable elastomers, including the effects of plasticizers. It also provides an overview of the nuclear magnetic resonance study on polymer structure, the composition and properties of some live and inert formulations produced at China Lake, and some possible peace-time applications for these new elastomeric materials.

High Temperature Mechanical Characterization of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Gyekenyesi, John Z.

1998-01-01

A high temperature mechanical characterization laboratory has been assembled at NASA Lewis Research Center. One contribution of this work is to test ceramic matrix composite specimens in tension in environmental extremes. Two high temperature tensile testing systems were assembled. The systems were assembled based on the performance and experience of other laboratories and meeting projected service conditions for the materials in question. The systems use frames with an electric actuator and a center screw. A PC based data acquisition and analysis system is used to collect and analyze the data. Mechanical extensometers are used to measure specimen strain. Thermocouples, placed near the specimen, are used to measure the specimen gage section temperature. The system for testing in air has a resistance element furnace with molybdenum disilicide elements and pneumatic grips with water cooling attached to hydraulic alignment devices. The system for testing in an inert gas has a graphite resistance element furnace in a chamber with rigidly mounted, water cooled, hydraulically actuated grips. Unidirectional SiC fiber reinforced reaction bonded Si3N4 and triaxially woven, two dimensional, SiC fiber reinforced enhanced SiC composites were tested in unidirectional tension. Theories for predicting the Young's modulus, modulus near the ultimate strength, first matrix cracking stress, and ultimate strength were applied and evaluated for suitability in predicting the mechanical behavior of SiC/RBSN and enhanced SiC/SiC composites. The SiC/RBSN composite exhibited pseudo tough behavior (increased area under the stress/strain curve) from 22 C to 1500 C. The rule of mixtures provides a good estimate of the Young's modulus of the SiC/RBSN composite using the constituent properties from room temperature to 1440 C for short term static tensile tests in air or nitrogen. The rule of mixtures significantly overestimates the secondary modulus near the ultimate strength. The ACK theory provides the best approximation of the first matrix cracking stress when residual stresses are ignored. The theory of Cao and Thouless, based on Weibull statistics, gave the best prediction for the composite ultimate strength. The enhanced SiC/SiC composite exhibited nonlinear stress/strain behavior from 24 C to 1370 C in air with increased ultimate strain when compared to monolithic SiC. The theory of Yang and Chou with the assumption of a frictional fiber/matrix interface provided the best estimate of the Young's modulus. The theory of Cao and Thouless gave the best estimate for the ultimate strength.

Polyimide Composites from 'Salt-Like' Solution Precursors

NASA Technical Reports Server (NTRS)

Cano, Roberto J.; Hou, Tan H.; Weiser, Erik S.; SaintClair, Terry L.

2001-01-01

Four NASA Langley-developed polyimide matrix resins, LaRC(TM)-IA, LaRC(TM)-IAX, LaRC(TM)-8515 and LaRC(TM)-PETI-5, were produced via a 'saltlike' process developed by Unitika Ltd. The salt-like solutions (65% solids in NMP) were prepregged onto Hexcel IM7 carbon fiber using the NASA LaRC multipurpose tape machine. Process parameters were determined and composite panels fabricated. The temperature dependent volatile depletion rates, the thermal crystallization behavior and the resin rheology were characterized. Composite molding cycles were developed which consistently yielded well consolidated, void-free laminated parts. Composite mechanical properties such as the short beam shear strength; the longitudinal and transverse flexural strength and flexural modulus; the longitudinal compression strength and modulus; and the open hole compression strength and compression after impact strength were measured at room temperature and elevated temperatures. The processing characteristics and the composite mechanical properties of the four intermediate modulus carbon fiber/polyimide matrix composites were compared to existing data on the same polyimide resin systems and IM7 carbon fiber manufactured via poly(amide acid) solutions (30-35% solids in NMP). This work studies the effects of varying the synthetic route on the processing and mechanical properties of the polyimide composites.

Effects of Interface Modification on Mechanical Behavior of Hi-Nicalon Fiber-Reinforced Celsian Matrix Composites

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.; Eldridge, Jeffrey I.

1997-01-01

Unidirectional celsian matrix composites having approx. 42 volume percent of uncoated or BN/SiC-coated Hi-Nicalon fibers were tested in three-point bend at room temperature. The uncoated fiber-reinforced composites showed catastrophic failure with strength of 210 +/- 35 MPa and a flat fracture surface. In contrast, composites reinforced with BN/SiC-coated fibers exhibited graceful failure with extensive fiber pullout. Values of first matrix cracking stress and strain were 435 +/- 35 MPa and 0.27 +/- 0.01 %, respectively, with ultimate strength as high as 960 MPa. The elastic Young's modulus of the uncoated and BN/SiC-coated fiber-reinforced composites were measured as 184 q 4 GPa and 165 +/- 5 GPa, respectively. Fiber push-through tests and microscopic examination indicated no chemical reaction at the uncoated or coated fiber-matrix interface. The low strength of the uncoated fiber-reinforced composite is probably due to degradation of the fibers from mechanical surface damage during processing. Because both the coated and uncoated fiber reinforced composites exhibited weak interfaces, the beneficial effect of the BN-SiC dual layer is primarily the protection of fibers from mechanical damage during processing.

Matrix density effects on the mechanical properties of SiC/RBSN composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; Kiser, James D.

1990-01-01

The room temperature mechanical properties were measured for SiC fiber reinforced reaction-bonded silicon nitride composites (SiC/RBSN) of different densities. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers (Textron SCS-6) in a reaction-bonded Si3N4 matrix. The composite density was varied by changing the consolidation pressure during RBSN processing and by hot isostatically pressing the SiC/RBSN composites. Results indicate that as the consolidation pressure was increased from 27 to 138 MPa, the average pore size of the nitrided composites decreased from 0.04 to 0.02 microns and the composite density increased from 2.07 to 2.45 gm/cc. Nonetheless, these improvements resulted in only small increases in the first matrix cracking stress, primary elastic modulus, and ultimate tensile strength values of the composites. In contrast, HIP consolidation of SiC/RBSN resulted in a fully dense material whose first matrix cracking stress and elastic modulus were approx. 15 and 50 percent higher, respectively, and ultimate tensile strength values were approx. 40 percent lower than those for unHIPed SiC/RBSN composites. The modulus behavior for all specimens can be explained by simple rule-of-mixture theory. Also, the loss in ultimate strength for the HIPed composites appears to be related to a degradation in fiber strength at the HIP temperature. However, the density effect on matrix fracture strength was much less than would be expected based on typical monolithic Si3N4 behavior, suggesting that composite theory is indeed operating. Possible practical implications of these observations are discussed.

Mechanical Behavior of Sapphire Reinforced Alumina Matrix Composites at Elevated Temperatures

NASA Technical Reports Server (NTRS)

Jaskowiak, Martha H.; Eldridge, Jeffrey I.; Setlock, John A.; Gyekenyesi, John Z.

1997-01-01

Zirconia coated sapphire reinforced alumina matrix composites have been tested both after heat treatment to 1400 C and at temperatures ranging from 800 C to 1200 C in. air. Interfacial shear stress has also been measured with fiber pushout tests performed in air at room temperature, 800 C and 1OOO C. Matrix crack spacing was measured for the tensile tested composites and used to estimate interfacial shear stress up to 1200 C. Electron microscopy was used to determine the source of fiber fracture and to study interfacial failure within the composite.

Thermal-Mechanical and Thermal Behavior of High-Temperature Structural Materials.

DTIC Science & Technology

1979-12-31

on feveroe side If neceseary at d identify by block number) Absorption coefficient; composites (A1203-BN, BeG-SiC, glass-Ni, ZrC-graphite); crack...Diffusivity of Glass-Ni Composites ’ V1 ’ P H -" ng ._T F,_J’" --Becher and K.S. Mazdiyasn4, -"Aalysis of the Resistance of High-E, Low-E Brittle Composites ...J .S r.PH..-iaeselman, W.M. Su, J.A. Rubin and R. Palicka, r’ ?Dbservations on the Nature of Micro-Cracking in Brittle Composites ,- ..X.L..--K

Multiscale Modeling of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Mital, Subodh K.; Pineda, Evan J.; Arnold, Steven M.

2015-01-01

Results of multiscale modeling simulations of the nonlinear response of SiC/SiC ceramic matrix composites are reported, wherein the microstructure of the ceramic matrix is captured. This micro scale architecture, which contains free Si material as well as the SiC ceramic, is responsible for residual stresses that play an important role in the subsequent thermo-mechanical behavior of the SiC/SiC composite. Using the novel Multiscale Generalized Method of Cells recursive micromechanics theory, the microstructure of the matrix, as well as the microstructure of the composite (fiber and matrix) can be captured.

Altered brain-gut axis in autism: comorbidity or causative mechanisms?

PubMed

Mayer, Emeran A; Padua, David; Tillisch, Kirsten

2014-10-01

The concept that alterated communications between the gut microbiome and the brain may play an important role in human brain disorders has recently received considerable attention. This is the result of provocative preclinical and some clinical evidence supporting early hypotheses about such communication in health and disease. Gastrointestinal symptoms are a common comorbidity in patients with autism spectrum disorders (ASD), even though the underlying mechanisms are largely unknown. In addition, alteration in the composition and metabolic products of the gut microbiome has long been implicated as a possible causative mechanism contributing to ASD pathophysiology, and this hypothesis has been supported by several recently published evidence from rodent models of autism induced by prenatal insults to the mother. Recent evidence in one such model involving maternal infection, that is characterized by alterations in behavior, gut physiology, microbial composition, and related metabolite profile, suggests a possible benefit of probiotic treatment on several of the observed abnormal behaviors. © 2014 WILEY Periodicals, Inc.

Mechanical Behavior of a Hi-Nicalon(tm)/SiC Composite Having a Polycarbosilane Derived Matrix

NASA Technical Reports Server (NTRS)

Hurwitz, Frances I.; Calomino, Anthony M.; McCue, Terry R.

1999-01-01

Polymer infiltration of a rigidized preform, followed by pyrolysis to convert the polymer to a ceramic, potentially offers a lower cost alternative to CVD. It also offers more moderate temperature requirements than melt infiltration approaches, which should minimize potential fiber damage during processing. However, polymer infiltration and pyrolysis results in a more microcracked matrix. Preliminary mechanical property characterization, including elevated temperature (1204 C) tensile, 500 h stress rupture behavior and low cycle fatigue, was conducted on Hi-Nicalon (TM)/Si-C-(O) composites having a dual layer BN/SiC interface and a matrix derived by impregnation and pyrolysis of allylhydridopolycarbosilane (AHPCS). Microstructural evaluation of failure surfaces and of polished transverse and longitudinal cross sections of the failed specimens was used to identify predominant failure mechanisms. In stress rupture testing at 1093 C, the failure was interface dominated, while at 1204 C in both stress rupture and two hour hold/fatigue tests failure was matrix dominated, resulting in specimen delamination.

Application-Oriented Chemical Optimization of a Metakaolin Based Geopolymer.

PubMed

Ferone, Claudio; Colangelo, Francesco; Roviello, Giuseppina; Asprone, Domenico; Menna, Costantino; Balsamo, Alberto; Prota, Andrea; Cioffi, Raffaele; Manfredi, Gaetano

2013-05-10

In this study the development of a metakaolin based geopolymeric mortar to be used as bonding matrix for external strengthening of reinforced concrete beams is reported. Four geopolymer formulations have been obtained by varying the composition of the activating solution in terms of SiO₂/Na₂O ratio. The obtained samples have been characterized from a structural, microstructural and mechanical point of view. The differences in structure and microstructure have been correlated to the mechanical properties. A major issue of drying shrinkage has been encountered in the high Si/Al ratio samples. In the light of the characterization results, the optimal geopolymer composition was then applied to fasten steel fibers to reinforced concrete beams. The mechanical behavior of the strengthened reinforced beams was evaluated by four-points bending tests, which were performed also on reinforced concrete beams as they are for comparison. The preliminary results of the bending tests point out an excellent behavior of the geopolymeric mixture tested, with the failure load of the reinforced beams roughly twice that of the control beam.

Elevated-temperature fracture resistances of monolithic and composite ceramics using chevron-notched bend tests

NASA Technical Reports Server (NTRS)

Ghosh, Asish; Jenkins, Michael G.; Ferber, Mattison K.; Peussa, Jouko; Salem, Jonathan A.

1992-01-01

The quasi-static fracture behaviors of monolithic ceramics (SiC, Si3N4, MgAl2O4), self-reinforced monoliths (acicular grained Si3N4, acicular grained mullite), and ceramic matrix composites (SiC whisker/Al2O3 matrix, TiB2 particulate/SiC matrix, SiC fiber/CVI SiC matrix, Al2O3 fiber/CVI SiC matrix) were measured over the temperature range of 20 to 1400 C. The chevron notched, bend bar test geometry was essential for characterizing the elevated temperature fracture resistances of this wide range of quasi-brittle materials during stable crack growth. Fractography revealed the differences in the fracture behavior of the different materials at the various temperatures. The fracture resistances of the self-reinforced monoliths were comparable to those of the composites and the fracture mechanisms were found to be similar at room temperature. However at elevated temperatures the differences of the fracture behavior became apparent where the superior fracture resistance of the self-reinforced monoliths were attributed to the minor amounts of glassy, intergranular phases which were often more abundant in the composites and affected the fracture behavior when softened by elevated temperatures.

Modelling and simulation of the consolidation behavior during thermoplastic prepreg composites forming process

NASA Astrophysics Data System (ADS)

Xiong, H.; Hamila, N.; Boisse, P.

2017-10-01

Pre-impregnated thermoplastic composites have recently attached increasing interest in the automotive industry for their excellent mechanical properties and their rapid cycle manufacturing process, modelling and numerical simulations of forming processes for composites parts with complex geometry is necessary to predict and optimize manufacturing practices, especially for the consolidation effects. A viscoelastic relaxation model is proposed to characterize the consolidation behavior of thermoplastic prepregs based on compaction tests with a range of temperatures. The intimate contact model is employed to predict the evolution of the consolidation which permits the microstructure prediction of void presented through the prepreg. Within a hyperelastic framework, several simulation tests are launched by combining a new developed solid shell finite element and the consolidation models.

Mechanical properties of as-cast and heat-treated ZA-27 alloy/short glass fiber composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, S.C.; Girish, B.M.; Satish, B.M.

1998-02-01

This paper reports on the mechanical properties of as-cast and heat-treated ZA-27 alloy composites reinforced with glass fibers from 1 to 5 wt%. The composites were fabricated using the Compocasting method, in which short glass fibers were introduced into the vortex created in the molten alloy through an impeller rotated at 500 rpm. The molten mass was thoroughly stirred and poured into permanent molds and squeezed under pressure. The specimens were heat treated at 320 C for 1, 2, 3, and 4 h. The tests on the as-cast composites revealed that as the glass content in the composites was increased,more » the ultimate tensile strength (UTS), compressive strength, and hardness of the composite increased, while the ductility and impact strength were decreased. Heat treatment was found to improve significantly the ductility, compressive strength, and impact strength, while the hardness and UTS were reduced. This paper discusses the behavior of these composites.« less

Real time in-situ sensing of damage evolution in nanocomposite bonded surrogate energetic materials

NASA Astrophysics Data System (ADS)

Sengezer, Engin C.; Seidel, Gary D.

2016-04-01

The current work aims to explore the potential for in-situ structural health monitoring in polymer bonded energetic materials through the introduction of carbon nanotubes (CNTs) into the binder phase as a means to establish a significant piezoresistive response through the resulting nanocomposite binder. The experimental effort herein is focused towards electro-mechanical characterization of surrogate materials in place of actual energetic (explosive) materials in order to provide proof of concept for the strain and damage sensing. The electrical conductivity and the piezoresistive behavior of samples containing randomly oriented MWCNTs introduced into the epoxy (EPON 862) binder of 70 wt% ammonium perchlorate-epoxy hybrid composites are quantitatively and qualitatively evaluated. Brittle failure going through linear elastic behavior, formation of microcracks leading to reduction in composite load carrying capacity and finally macrocracks resulting in eventual failure are observed in the mechanical response of MWNT-ammonium perchlorateepoxy hybrid composites. Incorporating MWNTs into local polymer binder improves the effective stiffness about 40% compared to neat ammonium perchlorate-polymer samples. The real time in-situ relative change in resistance for MWNT hybrid composites was detected with the applied strains through piezoresistive response.

Mechanical behavior and fracture characteristics of off-axis fiber composites. 1: Experimental investigation. [at the Lewis Research Center

NASA Technical Reports Server (NTRS)

Sinclair, J. H.; Chamis, C. C.

1977-01-01

The mechanical behavior, fracture surfaces, and fracture modes of unidirectional high-modulus graphite-fiber/epoxy composites subjected to off-axis tensile loads were investigated experimentally. The investigation included the generation of stress-strain-to-fracture data and scanning electron microscope studies of the fractured surfaces. The results led to the identification of fracture modes and distinct fracture surface characteristics for off-axis tensile loading. The results also led to the formulation of critical for identifying and characterizing these fracture modes and their associated fracture surfaces. The results presented and discussed herein were used in the theoretical investigation and comparisons described in Part 2. These results should also provide a good foundation for identifying, characterizing, and quantifying fracture modes in both off-axis and angle-plied laminates.

Enhanced interfacial interaction and antioxidative behavior of novel halloysite nanotubes/silica hybrid supported antioxidant in styrene-butadiene rubber

NASA Astrophysics Data System (ADS)

Lin, Jing; Luo, Yuanfang; Zhong, Bangchao; Hu, Dechao; Jia, Zhixin; Jia, Demin

2018-05-01

A novel antioxidant (HS-s-RT) to improve the mechanical properties and anti-aging performance of styrene-butadiene (SBR) composites was prepared by antioxidant intermediate p-aminodiphenylamine (RT) grafting on the surface of halloysite nanotubes/silica hybrid (HS) via the linkage of silane coupling agent. The analysis of SEM and rubber processing analyzer (RPA) demonstrated HS-s-RT was uniformly dispersed in SBR, and stronger interfacial interaction between HS-s-RT and SBR was formed. Consequently, SBR/HS-s-RT composites have improving mechanical properties. Furthermore, the test of the retention of mechanical properties, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR), and oxidation induction time (OIT) showed HS-s-RT can effectively improve the anti-aging effect of SBR composites than corresponding low molecular-weight antioxidant N-isopropyl-N‧-phenyl-4-phenylenediamin (4010NA). Then, the mechanism of thermo-oxidative aging of SBR/HS composites was also investigated, and the superior antioxidative efficiency is attributed to the uniform dispersion and excellent migration resistance of HS-s-RT. Hence, this novel antioxidant might open up new opportunities for the fabrication of high-performance rubber composites due to its superior anti-aging effect and reinforcement.

NASA-UVA light aerospace alloy and structures technology program (LA2ST)

NASA Technical Reports Server (NTRS)

Gangloff, Richard P.

1992-01-01

The NASA-UVa Light Aerospace Alloy and Structure Technology (LAST) Program continues to maintain a high level of activity, with projects being conducted by graduate students and faculty advisors in the Departments of Materials Science and Engineering, Civil Engineering and Applied Mechanics, and Mechanical and Aerospace Engineering at the University of Virginia. This work is funded by the NASA-Langley Research Center under Grant NAG-1-745. Here, we report on progress achieved between January 1 and June 30, 1992. The objectives of the LA2ST Program is to conduct interdisciplinary graduate student research on the performance of the next generation, light weight aerospace alloys, composites and thermal gradient structures in collaboration with Langley researchers. Technical objectives are established for each research project. We aim to produce relevant data and basic understanding of material mechanical response, corrosion behavior, and microstructure; new monolithic and composite alloys; advanced processing methods; new solid and fluid mechanics analyses; measurement advances; and critically, a pool of educated graduate students for aerospace technologies. The accomplishments presented in this report cover topics including: (1) Mechanical and Environmental Degradation Mechanisms in Advance Light Metals and Composites; (2) Aerospace Materials Science; (3) Mechanics of Materials and Composites for Aerospace Structures; and (4) Thermal Gradient Structures.

Preparation and Dynamic Mechanical Properties at Elevated Temperatures of a Tungsten/Glass Composite

NASA Astrophysics Data System (ADS)

Gao, Chong; Wang, Yingchun; Ma, Xueya; Liu, Keyi; Wang, Yubing; Li, Shukui; Cheng, Xingwang

2018-03-01

Experiments were conducted to prepare a borosilicate glass matrix composite containing 50 vol.% tungsten and examine its dynamic compressive behavior at elevated temperatures in the range of 450-775 °C. The results show that the homogenous microstructure of the tungsten/glass composite with relative density of 97% can be obtained by hot-pressing sintering at 800 °C for 1 h under pressure of 30 MPa. Dynamic compressive testing was carried out by a separate Hopkinson pressure bar system with a synchronous device. The results show that the peak stress decreases and the composite transforms from brittle to ductile in nature with testing temperature increasing from 450 to 750 °C. The brittle-ductile transition temperature is about 500 °C. Over 775 °C, the composite loses load-bearing capacity totally because of the excessive softening of the glass phase. In addition, the deformation and failure mechanism were analyzed.

Microstructure and Interfacial Shear Strength in W/(Zr55Cu30Al10Ni5)100- x Nb x Composites

NASA Astrophysics Data System (ADS)

Mahmoodan, M.; Gholamipour, R.; Mirdamadi, Sh.; Nategh, S.

2017-11-01

In the present study, (Zr55Cu30Al10Ni5)100- x Nb( x=0,1,2,3) bulk metallic glass matrix/tungsten wire composites were fabricated by a gas pressure infiltration process at temperature 950 °C for 5 min. Microstructural studies and mechanical behaviors of the materials have been investigated by scanning electron microscopy, transmission electron microscopy and pullout tests. The mechanical results showed that the interface shear strength in the composite sample with X = 2 increased more than twice compared to the composite sample with X = 0. Based on the microstructural results, the addition of two atomic percent Nb in the matrix composite causes an increase in the diffusion band thickness during the melt infiltration and change in the interface fracture mode as a result of pullout test.

Studying Some of Electrical and Mechanical Properties for Kevlar Fiber Reinforced Epoxy

NASA Astrophysics Data System (ADS)

Rafeeq, Sewench N.; Hussein, Samah M.

2011-12-01

As ordinary known the ability of synthesizing electrical conducting polymer composites is possible but with poor mechanical properties, for the solution of this problem, we carried out this study in order to obtain that both properties. Three methods were applied for preparing the conductive polyaniline (PANI) composites using Kevlar fiber fabric as substrate for the deposition of the PANI at one time and the prepared composite (EP/Kevlar fiber) at others. The chemical oxidative method was adopted for polymerization of the aniline and simultaneously protonated of PANI with a hydrochloric acid at concentration (1M). Two kinds of oxidation agents (FeCl3.6H2O) and ((NH4)2S2O8) were used. The electrical measurements indicate the effect of each preparation method, kind of oxidant agent and the kind of mat erial which PANI deposited on the electrical results. The conductivity results showed that the prepared composites lie within semiconductors region. Temperature—dependence of electric conductivity results showed semiconductors and conductors behavior of this material within the applied temperature ranges. The mechan ical property (tensile strength) was studied. X-ray diffraction study showed the crystalline structure for EP/Kevlar fiber/PANI composites prepared by the three methods. These results gave optimism to the synthesis of conductive polymer composites with excellent mechanical properties..

Effect of fiber reinforcement on thermo-oxidative stability and mechanical properties of polymer matrix composites

NASA Technical Reports Server (NTRS)

Bowles, K. J.

1992-01-01

A number of studies have investigated the thermooxidative behavior of polymer matrix composites. Two significant observations have been made from these research efforts: (1) fiber reinforcement has a significant effect on composite thermal stability; and (2) geometric effects must be considered when evaluating thermal aging data. The polyimide PMR-15 was the matrix material used in these studies. The control composite material was reinforced with Celion 6000 graphite fiber. T-4OR graphite fibers, along with some very stable ceramic fibers were selected as reinforcing fibers because of their high thermal stability. The ceramic fibers were Nicalon (silicon carbide) and Nextel 312 (alumina-silica-boron oxide). The mechanical properties of the two graphite fiber composites were significantly different, probably owing to variations in interfacial bonding between the fibers and the polyimide matrix. Three oxidation mechanisms were observed: (1) the preferential oxidation of the Celion 6000 fiber ends at cut surfaces, leaving a surface of matrix material with holes where the fiber ends were originally situated; (2) preferential oxidation of the composite matrix; and (3) interfacial degradation by oxidation. The latter two mechanisms were also observed on fiber end cut surfaces. The fiber and interface attacks appeared to initiate interfiber cracking along these surfaces.

Effect of chemical environment and rock composition on fracture mechanics properties of reservoir lithologies in context of CO2 sequestration

NASA Astrophysics Data System (ADS)

Major, J. R.; Eichhubl, P.; Callahan, O. A.

2015-12-01

The coupled chemical and mechanical response of reservoir and seal rocks to injection of CO2 have major implications on the short and long term security of sequestered carbon. Many current numerical models evaluating behavior of reservoirs and seals during and after CO2 injection in the subsurface consider chemistry and mechanics separately and use only simple mechanical stability criteria while ignoring time-dependent failure parameters. CO2 injection irreversibly alters the subsurface chemical environment which can then affect geomechanical properties on a range of time scales by altering rock mineralogy and cements through dissolution, remobilization, and precipitation. It has also been documented that geomechanical parameters such as fracture toughness (KIC) and subcritical index (SCI) are sensitive to chemical environment. Double torsion fracture mechanics testing of reservoir lithologies under controlled environmental conditions relevant to CO2 sequestration show that chemical environment can measurably affect KIC and SCI. This coupled chemical-mechanical behavior is also influenced by rock composition, grains, amount and types of cement, and fabric. Fracture mechanics testing of the Aztec Sandstone, a largely silica-cemented, subarkose sandstone demonstrate it is less sensitive to chemical environment than Entrada Sandstone, a silty, clay-rich sandstone. The presence of de-ionized water lowers KIC by approximately 20% and SCI 30% in the Aztec Sandstone relative to tests performed in air, whereas the Entrada Sandstone shows reductions on the order of 70% and 90%, respectively. These results indicate that rock composition influences the chemical-mechanical response to deformation, and that the relative chemical reactivity of target reservoirs should be recognized in context of CO2 sequestration. In general, inert grains and cements such as quartz will be less sensitive to the changing subsurface environment than carbonates and clays.

Thermal-Mechanical Response of Cracked Satin Weave CFRP Composites at Cryogenic Temperatures

NASA Astrophysics Data System (ADS)

Watanabe, S.; Shindo, Y.; Narita, F.; Takeda, T.

2008-03-01

This paper examines the thermal-mechanical response of satin weave carbon fiber reinforced polymer (CFRP) laminates with internal and/or edge cracks subjected to uniaxial tension load at cryogenic temperatures. Cracks are considered to occur in the transverse fiber bundles and extend through the entire thickness of the fiber bundles. Two-dimentional generalized plane strain finite element models are developed to study the effects of residual thermal stresses and cracks on the mechanical behavior of CFRP woven laminates. A detailed examination of the Young's modulus and stress distributions near the crack tip is carried out which provides insight into material behavior at cryogenic temperatures.

Characteristics of starch-based biodegradable composites reinforced with date palm and flax fibers.

PubMed

Ibrahim, Hamdy; Farag, Mahmoud; Megahed, Hassan; Mehanny, Sherif

2014-01-30

The aim of this work is to study the behavior of completely biodegradable starch-based composites containing date palm fibers in the range from 20 to 80 wt%. Hybrid composites containing date palm and flax fibers, 25 wt% each, were also examined. The composites were preheated and then hot pressed at 5 MPa and 160°C for 30 min. SEM investigation showed strong adhesion between fibers and matrix. Density measurements showed very small void fraction (less than 0.142%) for composites containing up to 50 wt% fiber content. Increasing fiber weight fraction up to 50 wt% increased the composite static tensile and flexural mechanical properties (stiffness and strength). Composite thermal stability, water uptake and biodegradation improved with increasing fiber content. The present work shows that starch-based composites with 50 wt% fibers content have the optimum mechanical properties. The hybrid composite of flax and date palm fibers, 25 wt% each, has good properties and provides a competitive eco-friendly candidate for various applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

Improved Friction and Wear of M50 Steel Composites Incorporated with ZnO as a Solid Lubricant with Different Concentrations Under Different Loads

NASA Astrophysics Data System (ADS)

Essa, F. A.; Zhang, Qiaoxin; Huang, Xingjiu; Ibrahim, Ahmed Mohamed Mahmoud; Ali, Mohamed Kamal Ahmed; Abdelkareem, Mohamed A. A.; Elagouz, Ahmed

2017-10-01

This experimental study explores improving the tribological behavior of M50 steel using ZnO as a solid lubricant with different concentrations of 5, 10, 15, 20, and 25 wt.%. Tribological tests were conducted using pin-on-disk tribometer under different loads of 3, 6, 9, and 12 N and constant sliding speed of 0.2 m s-1 in air. XRD, EPMA, FESEM, EDS mapping, and XPS tests were performed to understand the major mechanisms leading to improve the tribological and mechanical properties of M50 composites. Results showed that the best tribological and mechanical properties were obtained at 20.0 wt.% of ZnO. Friction coefficient and wear rate were reduced by 52.909 and 70%, respectively, due to the formation of tribo-films on the worn surfaces. Furthermore, the hardness of M50 composites increased by 27.86%. Our study provides results with suggestions to overcome the challenges facing the technology when using M50 matrix composites in mechanical applications.

Integrating end-to-end threads of control into object-oriented analysis and design

NASA Technical Reports Server (NTRS)

Mccandlish, Janet E.; Macdonald, James R.; Graves, Sara J.

1993-01-01

Current object-oriented analysis and design methodologies fall short in their use of mechanisms for identifying threads of control for the system being developed. The scenarios which typically describe a system are more global than looking at the individual objects and representing their behavior. Unlike conventional methodologies that use data flow and process-dependency diagrams, object-oriented methodologies do not provide a model for representing these global threads end-to-end. Tracing through threads of control is key to ensuring that a system is complete and timing constraints are addressed. The existence of multiple threads of control in a system necessitates a partitioning of the system into processes. This paper describes the application and representation of end-to-end threads of control to the object-oriented analysis and design process using object-oriented constructs. The issue of representation is viewed as a grouping problem, that is, how to group classes/objects at a higher level of abstraction so that the system may be viewed as a whole with both classes/objects and their associated dynamic behavior. Existing object-oriented development methodology techniques are extended by adding design-level constructs termed logical composite classes and process composite classes. Logical composite classes are design-level classes which group classes/objects both logically and by thread of control information. Process composite classes further refine the logical composite class groupings by using process partitioning criteria to produce optimum concurrent execution results. The goal of these design-level constructs is to ultimately provide the basis for a mechanism that can support the creation of process composite classes in an automated way. Using an automated mechanism makes it easier to partition a system into concurrently executing elements that can be run in parallel on multiple processors.

Mechanism-Based FE Simulation of Tool Wear in Diamond Drilling of SiCp/Al Composites.

PubMed

Xiang, Junfeng; Pang, Siqin; Xie, Lijing; Gao, Feinong; Hu, Xin; Yi, Jie; Hu, Fang

2018-02-07

The aim of this work is to analyze the micro mechanisms underlying the wear of macroscale tools during diamond machining of SiC p /Al6063 composites and to develop the mechanism-based diamond wear model in relation to the dominant wear behaviors. During drilling, high volume fraction SiC p /Al6063 composites containing Cu, the dominant wear mechanisms of diamond tool involve thermodynamically activated physicochemical wear due to diamond-graphite transformation catalyzed by Cu in air atmosphere and mechanically driven abrasive wear due to high-frequency scrape of hard SiC reinforcement on tool surface. An analytical diamond wear model, coupling Usui abrasive wear model and Arrhenius extended graphitization wear model was proposed and implemented through a user-defined subroutine for tool wear estimates. Tool wear estimate in diamond drilling of SiC p /Al6063 composites was achieved by incorporating the combined abrasive-chemical tool wear subroutine into the coupled thermomechanical FE model of 3D drilling. The developed drilling FE model for reproducing diamond tool wear was validated for feasibility and reliability by comparing numerically simulated tool wear morphology and experimentally observed results after drilling a hole using brazed polycrystalline diamond (PCD) and chemical vapor deposition (CVD) diamond coated tools. A fairly good agreement of experimental and simulated results in cutting forces, chip and tool wear morphologies demonstrates that the developed 3D drilling FE model, combined with a subroutine for diamond tool wear estimate can provide a more accurate analysis not only in cutting forces and chip shape but also in tool wear behavior during drilling SiC p /Al6063 composites. Once validated and calibrated, the developed diamond tool wear model in conjunction with other machining FE models can be easily extended to the investigation of tool wear evolution with various diamond tool geometries and other machining processes in cutting different workpiece materials.

Mechanism-Based FE Simulation of Tool Wear in Diamond Drilling of SiCp/Al Composites

PubMed Central

Xiang, Junfeng; Pang, Siqin; Xie, Lijing; Gao, Feinong; Hu, Xin; Yi, Jie; Hu, Fang

2018-01-01

The aim of this work is to analyze the micro mechanisms underlying the wear of macroscale tools during diamond machining of SiCp/Al6063 composites and to develop the mechanism-based diamond wear model in relation to the dominant wear behaviors. During drilling, high volume fraction SiCp/Al6063 composites containing Cu, the dominant wear mechanisms of diamond tool involve thermodynamically activated physicochemical wear due to diamond-graphite transformation catalyzed by Cu in air atmosphere and mechanically driven abrasive wear due to high-frequency scrape of hard SiC reinforcement on tool surface. An analytical diamond wear model, coupling Usui abrasive wear model and Arrhenius extended graphitization wear model was proposed and implemented through a user-defined subroutine for tool wear estimates. Tool wear estimate in diamond drilling of SiCp/Al6063 composites was achieved by incorporating the combined abrasive-chemical tool wear subroutine into the coupled thermomechanical FE model of 3D drilling. The developed drilling FE model for reproducing diamond tool wear was validated for feasibility and reliability by comparing numerically simulated tool wear morphology and experimentally observed results after drilling a hole using brazed polycrystalline diamond (PCD) and chemical vapor deposition (CVD) diamond coated tools. A fairly good agreement of experimental and simulated results in cutting forces, chip and tool wear morphologies demonstrates that the developed 3D drilling FE model, combined with a subroutine for diamond tool wear estimate can provide a more accurate analysis not only in cutting forces and chip shape but also in tool wear behavior during drilling SiCp/Al6063 composites. Once validated and calibrated, the developed diamond tool wear model in conjunction with other machining FE models can be easily extended to the investigation of tool wear evolution with various diamond tool geometries and other machining processes in cutting different workpiece materials. PMID:29414839

Aluminium. II - A review of deformation properties of high purity aluminium and dilute aluminium alloys.

NASA Technical Reports Server (NTRS)

Reed, R. P.

1972-01-01

The elastic and plastic deformation behavior of high-purity aluminum and of dilute aluminum alloys is reviewed. Reliable property data, including elastic moduli, elastic coefficients, tensile, creep, fatigue, hardness, and impact are presented. Single crystal tensile results are discussed. Rather comprehensive reference lists, containing publications of the past 20 years, are included for each of the above categories. Defect structures and mechanisms responsible for mechanical behavior are presented. Strengthening techniques (alloys, cold work, irradiation, quenching, composites) and recovery are briefly reviewed.

Matrix density effects on the mechanical properties of SiC fiber-reinforced silicon nitride matrix properties

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; Kiser, Lames D.

1990-01-01

The room temperature mechanical properties were measured for SiC fiber reinforced reaction-bonded silicon nitride composites (SiC/RBSN) of different densities. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers (Textron SCS-6) in a reaction-bonded Si3N4 matrix. The composite density was varied by changing the consolidation pressure during RBSN processing and by hot isostatically pressing the SiC/RBSN composites. Results indicate that as the consolidation pressure was increased from 27 to 138 MPa, the average pore size of the nitrided composites decreased from 0.04 to 0.02 microns and the composite density increased from 2.07 to 2.45 gm/cc. Nonetheless, these improvements resulted in only small increases in the first matrix cracking stress, primary elastic modulus, and ultimate tensile strength values of the composites. In contrast, HIP consolidation of SiC/RBSN resulted in a fully dense material whose first matrix cracking stress and elastic modulus were approx. 15 and 50 percent higher, respectively, and ultimate tensile strength values were approx. 40 percent lower than those for unHIPed SiC/RBSN composites. The modulus behavior for all specimens can be explained by simple rule-of-mixture theory. Also, the loss in ultimate strength for the HIPed composites appears to be related to a degradation in fiber strength at the HIP temperature. However, the density effect on matrix fracture strength was much less than would be expected based on typical monolithic Si3N4 behavior, suggesting that composite theory is indeed operating. Possible practical implications of these observations are discussed.

Mechanical and functional behavior of high-temperature Ni-Ti-Pt shape memory alloys

DOE PAGES

Buchheit, Thomas E.; Susan, Donald F.; Massad, Jordan E.; ...

2016-01-22

A series of Ti-rich Ni-Ti-Pt ternary alloys with 13 to 18 at. pct Pt were processed by vacuum arc melting and characterized for their transformation behavior to identify shape memory alloys (SMA) that undergo transformation between 448 K and 498 K (175 °C and 225 °C) and achieve recoverable strain exceeding 2 pct. From this broader set of compositions, three alloys containing 15.5 to 16.5 at. pct Pt exhibited transformation temperatures in the vicinity of 473 K (200 °C), thus were targeted for more detailed characterization. Preliminary microstructural evaluation of these three compositions revealed a martensitic microstructure with small amountsmore » of Ti 2(Ni,Pt) particles. Room temperature mechanical testing gave a response characteristic of martensitic de-twinning followed by a typical work-hardening behavior to failure. Elevated mechanical testing, performed while the materials were in the austenitic state, revealed yield stresses of approximately 500 MPa and 3.5 pct elongation to failure. Thermal strain recovery characteristics were more carefully investigated with unbiased incremental strain-temperature tests across the 1 to 5 pct strain range, as well as cyclic strain-temperature tests at 3 pct strain. As a result, the unbiased shape recovery results indicated a complicated strain recovery path, dependent on prestrain level, but overall acceptable SMA behavior within the targeted temperature and recoverable strain range.« less

Thermal Degradation, Mechanical Properties and Morphology of Wheat Straw Flour Filled Recycled Thermoplastic Composites

PubMed Central

Mengeloglu, Fatih; Karakus, Kadir

2008-01-01

Thermal behaviors of wheat straw flour (WF) filled thermoplastic composites were measured applying the thermogravimetric analysis and differential scanning calorimetry. Morphology and mechanical properties were also studied using scanning electron microscope and universal testing machine, respectively. Presence of WF in thermoplastic matrix reduced the degradation temperature of the composites. One for WF and one for thermoplastics, two main decomposition peaks were observed. Morphological study showed that addition of coupling agent improved the compatibility between WFs and thermoplastic. WFs were embedded into the thermoplastic matrix indicating improved adhesion. However, the bonding was not perfect because some debonding can also be seen on the interface of WFs and thermoplastic matrix. In the case of mechanical properties of WF filled recycled thermoplastic, HDPE and PP based composites provided similar tensile and flexural properties. The addition of coupling agents improved the properties of thermoplastic composites. MAPE coupling agents performed better in HDPE while MAPP coupling agents were superior in PP based composites. The composites produced with the combination of 50-percent mixture of recycled HDPE and PP performed similar with the use of both coupling agents. All produced composites provided flexural properties required by the ASTM standard for polyolefin-based plastic lumber decking boards. PMID:27879719

Fundamental aspects of and failure modes in high-temperature composites

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Ginty, Carol A.

1990-01-01

Fundamental aspects of and attendant failure mechanisms for high temperature composites are summarized. These include: (1) in-situ matrix behavior; (2) load transfer; (3) limits on matrix ductility to survive a given number of cyclic loadings; (4) fundamental parameters which govern thermal stresses; (5) vibration stresses; and (6) impact resistance. The resulting guidelines are presented in terms of simple equations which are suitable for the preliminary assessment of the merits of a particular high temperature composite in a specific application.

Proceedings of the Annual Mechanics of Composites Review (8th) Held at Wright-Patterson AFB, Ohio on 5-7 October 1982.

DTIC Science & Technology

1983-04-01

Spectrum Fatigue Behavior of Postbuckled Shear Panels; PO01 246 Development of Analysis for Predicting Compression Fatigt Life and Residual Strength in...Lazyup and Frequency Effects on Fatigue Life of Composites, POOl 256 Effect of Stress Ratio on Fatigue Life of Composites,’ POOl 257 High-Load Transfer...L. Agerwall, Northrop Corporation 0950-1020 BREAK 1020-1100 DEVELOPMENT OF ANALYSIS FOR PREDICTING COMPRESSION 34 FATIGUE LIFE AND RESIDUAL STRENGTH

Creep Behavior in Interlaminar Shear of a SiC/SiC Ceramic Composite with a Self-healing Matrix

NASA Astrophysics Data System (ADS)

Ruggles-Wrenn, M. B.; Pope, M. T.

2014-02-01

Creep behavior in interlaminar shear of a non-oxide ceramic composite with a multilayered matrix was investigated at 1,200 °C in laboratory air and in steam environment. The composite was produced via chemical vapor infiltration (CVI). The composite had an oxidation inhibited matrix, which consisted of alternating layers of silicon carbide and boron carbide and was reinforced with laminated Hi-Nicalon™ fibers woven in a five-harness-satin weave. Fiber preforms had pyrolytic carbon fiber coating with boron carbide overlay applied. The interlaminar shear properties were measured. The creep behavior was examined for interlaminar shear stresses in the 16-22 MPa range. Primary and secondary creep regimes were observed in all tests conducted in air and in steam. In air and in steam, creep run-out defined as 100 h at creep stress was achieved at 16 MPa. Larger creep strains were accumulated in steam. However, creep strain rates and creep lifetimes were only moderately affected by the presence of steam. The retained properties of all specimens that achieved run-out were characterized. Composite microstructure, as well as damage and failure mechanisms were investigated.

Study on the Tensile Creep Behavior of Carbon Nanotubes-Reinforced Sn-58Bi Solder Joints

NASA Astrophysics Data System (ADS)

Yang, Li; Liu, Haixiang; Zhang, Yaocheng

2018-01-01

The microstructure and tensile creep behavior of plain Sn-58Bi solder and carbon nanotubes (CNTs)-reinforced composite solder joints were investigated. The stress exponent n under different stresses and the creep activation energy Q c under different temperatures of solder joints were obtained by an empirical equation. The results reveal that the microstructure of the composite solder joint is refined and the tensile creep resistance is improved by CNTs. The improvement of creep behavior is due to the microstructural change of the composite solder joints, since the CNTs could provide more obstacles for dislocation pile-up, which enhances the values of the stress exponent and the creep activation energy. The steady-state tensile creep rates of plain solder and composite solder joints are increased with increasing temperature and applied stress. The tensile creep constitutive equations of plain solder and composite solder joints are written as \\dot{ɛ }_{s1} = 14.94( {σ /G} )^{3.7} \\exp ( { - 81444/RT} ) and \\dot{ɛ }_{s2} = 2.5( {σ /G} )^{4.38} \\exp ( { - 101582/RT} ) , respectively. The tensile creep mechanism of the solder joints is the effects of lattice diffusion determined by dislocation climbing.

Mechanical properties and material characterization of polysialate structural composites

NASA Astrophysics Data System (ADS)

Foden, Andrew James

One of the major concerns in using Fiber Reinforced Composites in applications that are subjected to fire is their resistance to high temperature. Some of the fabrics used in FRC, such as carbon, are fire resistant. However, almost all the resins used cannot withstand temperatures higher than 200°C. This dissertation deals with the development and use of a potassium aluminosilicate (GEOPOLYMER) resin that is inorganic and can sustain more than 1000°C. The results presented include the mechanical properties of the unreinforced polysialate matrix in tension, flexure, and compression as well as the strain capacities and surface energy. The mechanical properties of the matrix reinforced with several different fabrics were obtained in flexure, tension, compression and shear. The strength and stiffness of the composite was evaluated for each loading condition. Tests were conducted on unexposed samples as well as samples exposed to temperatures from 200 to 1000°C. Fatigue properties were determined using flexural loading. A study of the effect of several processing variables on the properties of the composite was undertaken to determine the optimum procedure for manufacturing composite plates. The processing variables studied were the curing temperature and pressure, and the post cure drying time required to remove any residual water. The optimum manufacturing conditions were determined using the void content, density, fiber volume fraction, and flexural strength. Analytical models are presented based on both micro and macro mechanical analysis of the composite. Classic laminate theory is used to evaluate the state of the composite as it is being loaded to determine the failure mechanisms. Several failure criteria theories are considered. The analysis is then used to explain the mechanical behavior of the composite that was observed during the experimental study.

Structure, corrosion behavior and mechanical property of a novel poly(vinyl alcohol) composite in simulated body fluid.

PubMed

Li, Juan; Suo, Jinping; Zou, Peng; Jia, Lintao; Wang, Shifang

2010-01-01

The data for long-term drug-delivery systems are scarce compared to the short-term systems because the required research efforts are more time-consuming. In this study, we report a novel cross-linked composite based on poly(vinyl alcohol) (PVA) containing cupric ions for long-term delivery, which is helpful for contraception and trace element balance in the human body. The composition, corrosion products, crystal structure, chemical structure and mechanical stability of the composite, after being immersed in simulated body fluid (SBF) for one year, were studied by X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FT-IR) and mechanical testing. The results show that no other new elements, such as P, Cl and Ca, appear on the surface of the composite and no Cu(2)O was formed after immersion in SBF for one year. The effectiveness of copper can be greatly improved and the side-effects caused by these compounds might also be eliminated. Furthermore, this novel composite exhibits long-term mechanical stability in SBF. The present in vitro long-term data suggest that this novel copper-containing composite may serve as a substitute for conventional materials of copper-containing intrauterine devices (Cu-IUDs) and as a carrier for controlled-release material in a variety of other applications.

Influence of reinforcement type on the mechanical behavior and fire response of hybrid composites and sandwich structures

NASA Astrophysics Data System (ADS)

Giancaspro, James William

Lightweight composites and structural sandwich panels are commonly used in marine and aerospace applications. Using carbon, glass, and a host of other high strength fiber types, a broad range of laminate composites and sandwich panels can be developed. Hybrid composites can be constructed by laminating multiple layers of varying fiber types while sandwich panels are manufactured by laminating rigid fiber facings onto a lightweight core. However, the lack of fire resistance of the polymers used for the fabrication remains a very important problem. The research presented in this dissertation deals with an inorganic matrix (Geopolymer) that can be used to manufacture laminate composites and sandwich panels that are resistant up to 1000°C. This dissertation deals with the influence of fiber type on the mechanical behavior and the fire response of hybrid composites and sandwich structures manufactured using this resin. The results are categorized into the following distinct studies. (i) High strength carbon fibers were combined with low cost E-glass fibers to obtain hybrid laminate composites that are both economical and strong. The E-glass fabrics were used as a core while the carbon fibers were placed on the tension face and on both tension and compression faces. (ii) Structural sandwich beams were developed by laminating various types of reinforcement onto the tension and compression faces of balsa wood cores. The flexural behavior of the beams was then analyzed and compared to beams reinforced with organic composite. The effect of core density was evaluated using oak beams reinforced with inorganic composite. (iii) To measure the fire response, balsa wood sandwich panels were manufactured using a thin layer of a fire-resistant paste to serve for fire protection. Seventeen sandwich panels were fabricated and tested to measure the heat release rates and smoke-generating characteristics. The results indicate that Geopolymer can be effectively used to fabricate both high strength composite plates and sandwich panels. A 2 mm thick coating of fireproofing on balsa wood is sufficient to satisfy FAA fire requirements.

Combined effects of different heat treatments and Cu element on transformation behavior of NiTi orthodontic wires.

PubMed

Seyyed Aghamiri, S M; Ahmadabadi, M Nili; Raygan, Sh

2011-04-01

The shape memory nickel-titanium alloy has been applied in many fields due to its unique thermal and mechanical performance. One of the successful applications of NiTi wires is in orthodontics because of its good characteristics such as low stiffness, high spring back, high stored energy, biocompatibility, superelasticity and shape memory effect. The mechanical properties of wires are paid special attention which results in achieving continuous optimal forces and eventually causing rapid tooth movement without any damage. The behavior of the alloy can be controlled by chemical composition and thermo-mechanical treatment during the manufacturing process. In this study two kinds of commercial superelastic NiTi archwires of 0.41 mm diameter were investigated: Copper NiTi and Highland Metal. The chemical analysis of both wires was estimated by energy dispersive spectroscopy (EDS). It was showed that Copper NiTi wire contained copper and chromium. The two types of wires were exposed to different heat treatment conditions at 400 and 500 °C for 10 and 60 min to compare the behavior of the wires at aged and as-received conditions. Phase transformation temperatures clarified by differential scanning calorimetry (DSC) showed B2 <--> R <--> B19 transformation in Highland Metal wire and B2 <--> B19(') transformation in Copper NiTi wire. Three point bending (TPB) tests in the certain designed fixture were performed at 37 °C to evaluate the mechanical behavior of the wires. The experimental results revealed the superelastic behavior of the Highland Metal wire after 60 min ageing at 400 and 500 °C and the plastic deformation of the Copper NiTi wire after annealing due to the effect of copper in the alloy composition. Copyright © 2010 Elsevier Ltd. All rights reserved.

Processing and mechanical properties of metal-ceramic composites with controlled microstructure formed by reactive metal penetration

NASA Astrophysics Data System (ADS)

Ellerby, Donald Thomas

1999-12-01

Compared to monolithic ceramics, metal-reinforced ceramic composites offer the potential for improved toughness and reliability in ceramic materials. As such, there is significant scientific and commercial interest in the microstructure and properties of metal-ceramic composites. Considerable work has been conducted on modeling the toughening behavior of metal reinforcements in ceramics; however, there has been limited application and testing of these concepts on real systems. Composites formed by newly developed reactive processes now offer the flexibility to systematically control metal-ceramic composite microstructure, and to test some of the property models that have been proposed for these materials. In this work, the effects of metal-ceramic composite microstructure on resistance curve (R-curve) behavior, strength, and reliability were systematically investigated. Al/Al2O3 composites were formed by reactive metal penetration (RMP) of aluminum metal into aluminosilicate ceramic preforms. Processing techniques were developed to control the metal content, metal composition, and metal ligament size in the resultant composite microstructure. Quantitative stereology and microscopy were used to characterize the composite microstructures, and then the influence of microstructure on strength, toughness, R-curve behavior, and reliability, was investigated. To identify the strength limiting flaws in the composite microstructure, fractography was used to determine the failure origins. Additionally, the crack bridging tractions produced by the metal ligaments in metal-ceramic composites formed by the RMP process were modeled. Due to relatively large flaws and low bridging stresses in RMP composites, no dependence of reliability on R-curve behavior was observed. The inherent flaws formed during reactive processing appear to limit the strength and reliability of composites formed by the RMP process. This investigation has established a clear relationship between processing, microstructure, and properties in metal-ceramic composites formed by the RMP process. RMP composite properties are determined by the metal-ceramic composite microstructure (e.g., metal content and ligament size), which can be systematically varied by processing. Furthermore, relative to the ceramic preforms used to make the composites, metal-ceramic composites formed by RMP generally have improved properties and combinations of properties that make them more desirable for advanced engineering applications.

Preparation and properties of carboxylated styrene-butadiene rubber/cellulose nanocrystals composites.

PubMed

Cao, Xiaodong; Xu, Chuanhui; Liu, Yuhong; Chen, Yukun

2013-01-30

A series of carboxylated styrene-butadiene rubber (XSBR)/cellulose nanocrystals (CNs) latex composites were successfully prepared. The vulcanization process, morphology, dynamic viscoelastic behavior, dynamic mechanical property, thermal and mechanical performance of the XSBR/CNs composites were investigated in detail. The results revealed that CNs were dispersed uniformly in the XSBR matrix and formed a strong filler-filler network. The dynamic mechanical analysis (DMA) showed that the glass transition temperature (T(g)) of XSBR matrix was shifted from 48.45 to 50.64 °C with 3 phr CNs, but decreased from 50.64 to 46.28 °C when further increasing CNs content up to 15 phr. The composites exhibited a significant enhancement in tensile strength (from 16.9 to 24.1 MPa) and tear strength (from 43.5 to 65.2 MPa) with loading CNs from 0 to 15 phr. In addition, the thermo-gravimetric analysis (TGA) showed that the temperature at 5% weight loss of the XSBR/CNs composites decreased slightly with an increase of the CNs content. Crown Copyright © 2012. Published by Elsevier Ltd. All rights reserved.

Study of the time varying properties of flax fiber reinforced composites

NASA Astrophysics Data System (ADS)

Stochioiu, Constantin; Chettah, Ameur; Piezel, Benoit; Fontaine, Stéphane; Gheorghiu, Horia-Miron

2018-02-01

Bio materials have seen an increase of interest from the scientific community and the industry as a possible future generation of mass produced materials, some of the main arguments being their renewability, low production costs and recyclability. The current work is focused on the experimental data required for the viscoelastic characterization of a composite material. Similar work has been conducted on different types of composite materials by Tuttle and Brinson [1] who verified for a carbon epoxy laminate the possibility of long term predicament of creep. Nordin et al [2] studied paper impregnated with phenol-formaldehyde under compression. Muliana [3] conducted experiments on E-glass/vinyl ester materials. Behavior characterization was based on a model presented by Schapery [4]. The main objective of this work is to understand the mechanical behaviors of bio-laminates structures subjected to long and severe operating conditions. The studied material is a bio composite laminate consisting in long flax fibers embedded in an epoxy resin system. The laminates were obtained from pre-impregnated unidirectional fibers, which were cured though a thermo-compression cycle followed by a post curing cycle. Test specimens were cut down to sizes, with the help of an electric saw. The concerned fiber direction was 0° with sample dimensions of 250x25x2 mm. First, testing consisted in quasi static mechanical tests. Second, to characterize linear viscoelastic behavior of the bio-laminates, creep - recovery tests with multiple load levels have been performed for the chosen fiber direction.

Drawing dependent structures, mechanical properties and cyclization behaviors of polyacrylonitrile and polyacrylonitrile/carbon nanotube composite fibers prepared by plasticized spinning.

PubMed

Li, Xiang; Qin, Aiwen; Zhao, Xinzhen; Liu, Dapeng; Wang, Haiye; He, Chunju

2015-09-14

Drawing to change the structural properties and cyclization behaviors of the polyacrylonitrile (PAN) chains in crystalline and amorphous regions is carried out on PAN and PAN/carbon nanotube (CNT) composite fibers. Various characterization methods including Fourier transform infrared spectroscopy, differential scanning calorimetry, X-ray diffraction and thermal gravimetric analysis are used to monitor the structural evolution and cyclization behaviors of the fibers. With an increase of the draw ratio during the plasticized spinning process, the structural parameters of the fibers, i.e. crystallinity and planar zigzag conformation, are decreased at first, and then increased, which are associated with the heat exchange rate and the oriented-crystallization rate. A possible mechanism for plasticized spinning is proposed to explain the changing trends of crystallinity and planar zigzag conformation. PAN and PAN/CNT fibers exhibit various cyclization behaviors induced by drawing, e.g., the initiation temperature for the cyclization (Ti) of PAN fibers is increased with increasing draw ratio, while Ti of PAN/CNT fibers is decreased. Drawing also facilitates cyclization and lowers the percentage of β-amino nitrile for PAN/CNT fibers during the stabilization.

Mechanical characterization and structural assessment of biocomposites for construction

NASA Astrophysics Data System (ADS)

Christian, Sarah Jane

The objective of this dissertation is to assess whether or not two particular biocomposite materials, made from hemp fabric and cellulose acetate or polyhydroxybutyrate matrices, are capable of being used for structural and/or construction purposes within in the construction and building industry. The objective of this dissertation was addressed by conducting research to meet the following three goals: (1) to measure the basic mechanical properties of hemp/cellulose acetate and hemp/PHB biocomposites and evaluate if they suitable for use in construction applications, (2) to determine how quickly moisture diffuses into the biocomposite materials and how the moisture affects the mechanical behavior, and (3) to determine how well simple models can predict behavior of structural scale laminates in tension and flexure using biocomposite ply behavior. Compression molding was used to manufacturing the biocomposites from hemp fabric and the themoplastic matrices: cellulose acetate and polyhydroxybutyrate. Four methods for determining the fiber volume fraction were evaluated, and the dissolution method, using different solvents for each matrix type, was used to determine the fiber volume fraction for each composite plate manufactured. Both types of biocomposite were tested in tension, compression, shear, and flexure and the measured properties were compared to wood and engineered wood products to assess whether the biocomposite properties are suitable for use in the construction industry. The biocomposites were conditioned in a humid environment to determine the rate of moisture diffusion into the materials. Then saturated specimens and specimens that were saturated and then dried were tested in tension to evaluate how moisture absorption affects the mechanical behavior of the biocomposites. Finally, simple models of laminate behavior based on laminate plate theory were evaluated to determine if ply level behavior could be used to predict structural scale laminate behavior. While the biocomposite strengths in flexure, compression, and shear were comparable to the strengths of wood and wood-based products parallel to grain, the biocomposite strengths exceeded the strengths perpendicular to the wood grain, as would be expected with fabric reinforcement. The biocomposite moduli of elasticity were between 35% and 75% of the wood moduli parallel to grain. While structural shape of the biocomposites could be manipulated to achieve a comparable structural stiffness to replace wood and short fiber FRPs, the biocomposites have comparable stiffness to the engineered wood-products. Thus, in terms of mechanical properties, the biocomposites can be used in place of engineered-wood products. Yet, the higher densities of the biocomposites as compared to wood and engineered-wood products may limit their implementation in construction. The diffusion coefficients for both biocomposites were comparable to wood and higher than the coefficients for synthetic composites as expected due to the hydrophilicity of the natural fibers. Significantly greater moisture absorption of the hemp/cellulose acetate composite as compared to the hemp/PHB composite was attributed to the cellulose acetate itself being hydrophilic whereas PHB is hydrophobic. The rate of diffusion for both materials was found to increase with increasing temperature. Moisture absorption negatively affected the biocomposites as shown through lower initial stiffnesses and higher strains at failure of saturated specimens. The hemp/cellulose acetate composites were much more affected by moisture absorption than the hemp/PHB composites likely because the moisture plasticized the cellulose acetate and also weakened the interfacial fiber-matrix bond. Moisture was assumed to cause permanent damage because the stress-strain behavior did not return to the unconditioned behavior upon drying of the saturated specimens. The degradation of mechanical properties upon introduction to humid environments limits the potential applications of these biocomposites. For these biocomposites to be used widely within the construction industry, they must therefore be protected from moisture for example through sealants and/or fiber treatments. Classical laminate plate theory was shown to be effective in predicting the initial linear behavior of all of the laminates in tension and flexure, but did not capture stiffness degradation or the full nonlinear stress-strain response of the biocomposites because the model was for linear elastic materials. Use of this model would be appropriate for design of deflection-limited applications within certain stress ranges. The modified nonlinear laminate plate theory predicted the initial stress-strain response well, but at higher strains overestimated the strength and stiffness. The overestimation was attributed to the constitutive model assuming uncoupled stress-strain behavior for each strain component and, additionally in flexure, to the use of tensile behavior as the constitutive behavior in compression. While the simple models provided an adequate prediction of laminate behavior at low strains, to predict behavior at higher strains, it is recommended instead to evaluate the use of finite element analysis to predict response using experimental stress-strain as models for orthotropic materials and non-linear behavior are well-established. (Abstract shortened by UMI.)

Evaluation of the filler packing structures in dental resin composites: From theory to practice.

PubMed

Wang, Ruili; Habib, Eric; Zhu, X X

2018-07-01

The aim of this study is to evaluate the packing properties of uniform silica particles and their mixture with secondary particles yielding maximally loaded dental composites. We intend to verify the difference between the idealized models (the close-packed structures and the random-packed structures) and the actual experimental results, in order to provide guidance for the preparation of dental composites. The influence of secondary particle size and the resin composition on the physical-mechanical properties and the rheological properties of the experimental dental composites was also investigated. Silica particles (S-920, S-360, and S-195) with average diameters of 920, 360, and 195nm were synthesized via the Stöber process. Their morphology and size distribution were determined by field-emission scanning electron microscopy and laser particle sizer. A series of silica fillers, S-920, S-920+195, S-920+360, and S-920+360+195, were then formulated with two Bis-GMA/TEGDMA resins (weight ratios of 70:30 and 50:50). For these experimental dental composites, their maximum filler loadings were assessed and compared to the theory. The mechanical properties, degree of conversion, depth of cure, and polymerization shrinkage of these composites were then evaluated. Their rheological behaviors were measured with a rheometer. Unimodal S-920 had the maximally filler loading of 70.80wt% with the 5B5T resin, close to the theoretical estimation of the random loose packing (71.92wt%). The maximum loading of the S-920+360+195 filled composite was 72.92wt% for the same resin, compared to the theoretical estimation of 89.29wt% obtained for the close-packed structures. These findings indicate that random loose packing matches more closely to the real packing state for the filler formulations used. When maximally loaded, the composite with S-920+360+195 produced the best mechanical properties and the lowest polymerization shrinkage. The degree of conversion and depth of cure were higher with secondary particles added, and the viscosity of all unpolymerized pastes exhibited shear thinning behavior. Theoretical estimations of filler packing structures provide a useful guidance in the design of multimodal filler formulations and the preparation of dental composites with higher filler loading, improved physical-mechanical properties. Copyright © 2018 The Academy of Dental Materials. Published by Elsevier Inc. All rights reserved.

Chemical Stress Cracking of Acrylic Fibers.

DTIC Science & Technology

1982-05-01

stress, high fiber permeability, moderate fibe orientation, and water- plasticization . The proposed mechanism for bond cleava e involves cyclization of...tensile stress, high fiber permeability, moderate fiber orientation, and water- plasticization . The proposed mechanism for bond cleavage involves...chemical composition, plasticization , and other factors. It will be shown that the etching behavior does not reflect underlying hetero- geneities in the

Friction and Wear Behavior of Carbon Fabric-Reinforced Epoxy Composites

NASA Astrophysics Data System (ADS)

Şahin, Y.; De Baets, Patrick

2017-12-01

Besides intrinsic material properties, weight/energy savings and wear performance play an important role in the selection of materials for any engineering application. The tribological behavior of carbon fabric-reinforced epoxy composites produced by molding technique was investigated using a reciprocating pin-on-plate configuration. It was shown that the wear rate considerably decreased (by a factor of approx. 8) with the introduction of the reinforcing carbon fabric into the epoxy matrix. It was observed that the wear rate of the tested composites increased with an increase in normal load. Moreover, the coefficient of friction for epoxy/steel and composites/steel tribo-pairs was also determined and decreased with increasing load. By means of scanning electron microscopy of the wear tracks, different wear mechanisms such as matrix wear, matrix fatigue and cracking, matrix debris formation for neat epoxy together with fabric/fiber thinning, fabric breakage and fabric/matrix debonding for the reinforced epoxy could be distinguished.

European Scientific Notes. Volume 34, Number 7,

DTIC Science & Technology

1980-07-31

fatigue , the effect of patient during the fitting, but which moisture on mechanical properties, could still be bent 900 without delamin- and creep...behavior. In the fatigue ating the composite or debonding the work; different reinforcing fibers composite from the aluminum . Once (including glass-carbon... fatigue work sulting structure has better properties Sturgeon has under way includes the than steel and weighs a good deal less, effect of

Effect of stress concentrations in composite structures

NASA Technical Reports Server (NTRS)

Babcock, G. D.; Knauss, W. G.

1984-01-01

The goal of achieving a better understanding of the failure of complex composite structure is sought. This type of structure requires a thorough understanding of the behavior under load both on a macro and micro scale if failure mechanisms are to be understood. The two problems being studied are the failure at a panel/stiffener interface and a generic problem of failure at a stress concentration.

Nonlinear mechanics of composite materials with periodic microstructure

NASA Technical Reports Server (NTRS)

Jordan, E. H.; Walker, K. P.

1991-01-01

This report summarizes the result of research done under NASA NAG3-882 Nonlinear Mechanics of Composites with Periodic Microstructure. The effort involved the development of non-finite element methods to calculate local stresses around fibers in composite materials. The theory was developed and some promising numerical results were obtained. It is expected that when this approach is fully developed, it will provide an important tool for calculating local stresses and averaged constitutive behavior in composites. NASA currently has a major contractual effort (NAS3-24691) to bring the approach developed under this grant to application readiness. The report has three sections. One, the general theory that appeared as a NASA TM, a second section that gives greater details about the theory connecting Greens functions and Fourier series approaches, and a final section shows numerical results.

Effect of Hydroxyapatite on the Mechanical Properties and Corrosion Behavior of Mg-Zn-Y Alloy

PubMed Central

Chiu, Chun; Lu, Chih-Te; Chen, Shih-Hsun; Ou, Keng-Liang

2017-01-01

Mg-Zn-Y alloys with a long period stacking ordered (LPSO) phase are potential candidates for biodegradable implants; however, an unfavorable degradation rate has limited their applications. Hydroxyapatite (HA) has been shown to enhance the corrosion resistance of Mg alloys. In this study, Mg97Zn1Y2-0.5 wt% HA composite was synthesized and solution treated at 500 °C for 10 h. The corrosion behavior of the composite was studied by electrochemical and immersion tests, while the mechanical properties were investigated by a tensile test. Addition of HA particles improves the corrosion resistance of Mg97Zn1Y2 alloy without sacrificing tensile strength. The improved corrosion resistance is due to the formation of a compact Ca-P surface layer and a decrease of the volume fraction of the LPSO phase, both resulting from the addition of HA. After solution-treatment, the corrosion resistance of the composite decreases. This is due to the formation of a more extended LPSO phase, which weakens its role as a corrosion barrier in protecting the Mg matrix. PMID:28773216

Mechanical Behavior of Fabric-Film Laminates

NASA Technical Reports Server (NTRS)

Said, Magdi S.

1999-01-01

Inflatable structures are gaining wide support in planetary scientific missions as well as commercial applications. For such applications a new class of materials made of laminating thin homogenous films to lightweight fabrics are being considered us structura1 gas envelops. The emerging composite materials are a result of recent advances in the manufacturing cf 1ightweight, high strength fibers, fabrics and scrims. The lamination of these load-carrying members with the proper gas barrier film results in wide range of materials suitable for various loading and environmental conditions. Polyester - based woven fabrics laminated to thin homogeneus film of polyester (Maylar) is an example of this class. This fabric/ film laminate is being considered for the development a material suitable for building large gas envelopes for use in the NASA Ultra Long Duration Balloon Program (ULDB). Compared to commercial homogeneus films, the material provides relatively high strength to weight ratio as well as better resistance to crack and tear propagation. The purpose of this papers is to introduce the mechanical behavior of this class of multi-layers composite and to highlight some of the concerns observed during the characterization of these laminate composites.

Study of erosion characterization of carbon fiber reinforced composite material

NASA Astrophysics Data System (ADS)

Debnath, Uttam Kumar; Chowdhury, Mohammad Asaduzzaman; Kowser, Md. Arefin; Mia, Md. Shahin

2017-06-01

Carbon fiber composite materials are widely used at different engineering and industrial applications there are good physical, mechanical, chemical properties and light weight. Erosion behavior of materials depends on various factors such as impact angle, particle velocity, particle size, particle shape, particle type, particle flux, temperature of the tested materials. Among these factors impact angle and particle velocity have been recognized as two parameters that noticeably influence the erosion rates of all tested materials. Irregular shaped sand (SiO2) particles of various sizes (200-300 µm, 400-500 µm, and 500-600 µm) were selected erosive element. Tested conditions such as impingement angles between 15 degree to 90 degree, impact velocities between 30-50 m/sec, and stand-off distances 15-25 mm at surrounding room temperature were maintained. The highest level of erosion of the tested composite is obtained at 60° impact angle, which signifies the semi-ductile behavior of this material. Erosion showed increasing trend with impact velocity and decreasing nature in relation to stand-off distance. Surface damage was analyzed using SEM to examine the nature of the erosive wear mechanism.

Polypropylene/glass fiber hierarchical composites incorporating inorganic fullerene-like nanoparticles for advanced technological applications.

PubMed

Díez-Pascual, Ana M; Naffakh, Mohammed

2013-10-09

Novel isotactic polypropylene (iPP)/glass fiber (GF) laminates reinforced with inorganic fullerene-like tungsten disulfide (IF-WS2) nanoparticles as environmentally friendly fillers have been successfully fabricated by simple melt-blending and fiber impregnation in a hot-press without the addition of any compatibilizer. The influence of IF-WS2 concentration on the morphology, viscosity. and thermal and mechanical behavior of the hierarchical composites has been investigated. Results revealed an unprecedented 62 °C increase in the degradation temperature of iPP/GF upon addition of only 4.0 wt % IF-WS2. The coexistence of both micro- and nanoscale fillers resulted in synergistic effects on enhancing the stiffness, strength, crystallinity, thermal stability, glass transition (Tg) and heat distortion temperature (HDT) of the matrix. The approach used in this work is an efficient, versatile, scalable and economic strategy to improve the mechanical and thermal behavior of GF-reinforced thermoplastics with a view to extend their use in advanced technological applications. This new type of composite materials shows great potential to improve the efficiency and sustainability of many forms of transport.

NASA-UVA Light Aerospace Alloy and Structures Technology Program (LA2ST)

NASA Technical Reports Server (NTRS)

Gangloff, Richard P.; Scully, John R.; Stoner, Glenn E.; Thornton, Earl A.; Wawner, Franklin E., Jr.; Wert, John A.

1993-01-01

The NASA-UVA Light Aerospace Alloy and Structures Technology (LA2ST) Program continues a high level of activity. Progress achieved between 1 Jan. and 30 Jun. 1993 is reported. The objective of the LA2ST Program is to conduct interdisciplinary graduate student research on the performance of next generation, light weight aerospace alloys, composites, and thermal gradient structures in collaboration with NASA-Langley researchers. The following projects are addressed: environmental fatigue of Al-Li-Cu alloys; mechanisms of localized corrosion and environmental fracture in Al-Cu-Li-Mg-Ag alloy X2095 and compositional variations; the effect of zinc additions on the precipitation and stress corrosion cracking behavior of alloy 8090; hydrogen interactions with Al-Li-Cu alloy 2090 and model alloys; metastable pitting of aluminum alloys; cryogenic fracture toughness of Al-Cu-Li + In alloys; the fracture toughness of Weldalite (TM); elevated temperature cracking of advanced I/M aluminum alloys; response of Ti-1100/SCS-6 composites to thermal exposure; superplastic forming of Weldalite (TM); research to incorporate environmental effects into fracture mechanics fatigue life prediction codes such as NASA FLAGRO; and thermoviscoplastic behavior.

Polyfunctional epoxies. I - Rubber-toughened brominated and nonbrominated formulations for graphite composites. II - Nonrubber versus rubber-toughened brominated formulations for graphite composites

NASA Technical Reports Server (NTRS)

Nir, Z.; Gilwee, W. J.; Kourtides, D. A.; Parker, J. A.

1985-01-01

A new trifunctional epoxy resin, Tris-(hydroxyphenyl) methane triglycidyl ether, is compared to a state-of-the-art tetraglycidyl 4,4'-diaminodiphenyl methane (TGDDM), in graphite composites. Rubber-toughened brominated formulations of the epoxy resin are compared to nonbrominated ones in terms of their mechanical performance, environmental stability, thermochemical behavior, and flame retardancy. It is shown that the new resin performs almost the same way as the TGDDM does, but has improved glass transition temperature and environmental properties. Brominated polymeric additives (BPA) of different molecular weights are tested as a Br source to flame retardant graphite epoxy composites. The optimal molecular weight of the BPA and its polymeric backbone length are derived and compared with a 10 percent rubber-toughened formulation of the epoxy resin. Results indicate that when the Br content in the graphite composite is increased without the use of rubber, the mechanical properties improved. The use of BPAs as tougheners for graphite composites is also considered.

EFFECTS OF TEMPERATURE AND ENVIRONMENT ON MECHANICAL PROPERTIES OF TWO CHOPPED-FIBER AUTOMOTIVE STRUCTURAL COMPOSITES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ruggles-Wrenn, M.B.

2003-10-06

The Durability of Lightweight Composite Structures Project was established at Oak Ridge National Laboratory (ORNL) by the U.S. Department of Energy to provide the experimentally-based, durability-driven design guidelines necessary to assure long-term structural integrity of automotive composite components. The initial focus of the ORNL Durability Project was on composite materials consisting of polyurethane reinforced with E-glass. Current focus of the project is on composite materials reinforced with carbon fibers. The primary purpose of this report is to provide the individual specimen test date. Basic mechanical property testing and results for two chopped-fiber composite materials, one reinforced with glass- and themore » other with carbon fiber are provided. Both materials use the same polyurethane matrix. Preforms for both materials were produced using the P4 process. Behavioral trends, effects of temperature and environment, and corresponding design knockdown factors are established for both materials. Effects of prior short-time loads and of prior thermal cycling are discussed.« less

Modification of the Interfacial Interaction between Carbon Fiber and Epoxy with Carbon Hybrid Materials

PubMed Central

Yu, Kejing; Wang, Menglei; Wu, Junqing; Qian, Kun; Sun, Jie; Lu, Xuefeng

2016-01-01

The mechanical properties of the hybrid materials and epoxy and carbon fiber (CF) composites were improved significantly as compared to the CF composites made from unmodified epoxy. The reasons could be attributed to the strong interfacial interaction between the CF and the epoxy composites for the existence of carbon nanomaterials. The microstructure and dispersion of carbon nanomaterials were characterized by transmission electron microscopy (TEM) and optical microscopy (OM). The results showed that the dispersion of the hybrid materials in the polymer was superior to other carbon nanomaterials. The high viscosity and shear stress characterized by a rheometer and the high interfacial friction and damping behavior characterized by dynamic mechanical analysis (DMA) indicated that the strong interfacial interaction was greatly improved between fibers and epoxy composites. Remarkably, the tensile tests presented that the CF composites with hybrid materials and epoxy composites have a better reinforcing and toughening effect on CF, which further verified the strong interfacial interaction between epoxy and CF for special structural hybrid materials. PMID:28335217

Nonlinear effective permittivity of field grading composite dielectrics

NASA Astrophysics Data System (ADS)

Yang, Xiao; Zhao, Xiaolei; Li, Qi; Hu, Jun; He, Jinliang

2018-02-01

Field grading composite dielectrics with good nonlinear electrical properties can function as smart materials for electrical field control in a high-voltage apparatus. Besides the well-documented nonlinear conducting behavior, the field-dependent effective permittivity of field grading composites were also reported; however, in-depth research on the mechanism and influencing factors of this nonlinear permittivity are absent. This paper theoretically discusses the origin of the nonlinear effective permittivity, and the mechanism is illustrated through the waveform analysis of the nonlinear response of ZnO microvaristor/silicone rubber composites under a pure AC field. The field-dependent effective permittivity and loss property of the ZnO composites are measured by a dielectric spectrometer in both DC and AC fields under different frequencies. Through comparison of measurement results and theoretical models, the influence of the filler concentration, frequency, and time domain characteristics of the applied field on the nonlinear permittivity of the field grading composites are well explained. This paper provides insight into the nonlinear permittivity of field grading composites, and will be helpful for further tuning the performance of field grading composites.

Enhanced dielectric standoff and mechanical failure in field-structured composites

NASA Astrophysics Data System (ADS)

Martin, James E.; Tigges, Chris P.; Anderson, Robert A.; Odinek, Judy

1999-09-01

We report dielectric breakdown experiments on electric-field-structured composites of high-dielectric-constant BaTiO3 particles in an epoxy resin. These experiments show a significant increase in the dielectric standoff strength perpendicular to the field structuring direction, relative to control samples consisting of randomly dispersed particles. To understand the relation of this observation to microstructure, we apply a simple resistor-short breakdown model to three-dimensional composite structures generated from a dynamical simulation. In this breakdown model the composite material is assumed to conduct primarily through particle contacts, so the simulated structures are mapped onto a resistor network where the center of mass of each particle is a node that is connected to neighboring nodes by resistors of fixed resistance that irreversibly short to perfect conductors when the current reaches a threshold value. This model gives relative breakdown voltages that are in good agreement with experimental results. Finally, we consider a primitive model of the mechanical strength of a field-structured composite material, which is a current-driven, conductor-insulator fuse model. This model leads to a macroscopic fusing behavior and can be related to mechanical failure of the composite.

Nonlinear Inelastic Mechanical Behavior Of Epoxy Resin Polymeric Materials

NASA Astrophysics Data System (ADS)

Yekani Fard, Masoud

Polymer and polymer matrix composites (PMCs) materials are being used extensively in different civil and mechanical engineering applications. The behavior of the epoxy resin polymers under different types of loading conditions has to be understood before the mechanical behavior of Polymer Matrix Composites (PMCs) can be accurately predicted. In many structural applications, PMC structures are subjected to large flexural loadings, examples include repair of structures against earthquake and engine fan cases. Therefore it is important to characterize and model the flexural mechanical behavior of epoxy resin materials. In this thesis, a comprehensive research effort was undertaken combining experiments and theoretical modeling to investigate the mechanical behavior of epoxy resins subject to different loading conditions. Epoxy resin E 863 was tested at different strain rates. Samples with dog-bone geometry were used in the tension tests. Small sized cubic, prismatic, and cylindrical samples were used in compression tests. Flexural tests were conducted on samples with different sizes and loading conditions. Strains were measured using the digital image correlation (DIC) technique, extensometers, strain gauges, and actuators. Effects of triaxiality state of stress were studied. Cubic, prismatic, and cylindrical compression samples undergo stress drop at yield, but it was found that only cubic samples experience strain hardening before failure. Characteristic points of tensile and compressive stress strain relation and load deflection curve in flexure were measured and their variations with strain rate studied. Two different stress strain models were used to investigate the effect of out-of-plane loading on the uniaxial stress strain response of the epoxy resin material. The first model is a strain softening with plastic flow for tension and compression. The influence of softening localization on material behavior was investigated using the DIC system. It was found that compression plastic flow has negligible influence on flexural behavior in epoxy resins, which are stronger in pre-peak and post-peak softening in compression than in tension. The second model was a piecewise-linear stress strain curve simplified in the post-peak response. Beams and plates with different boundary conditions were tested and analytically studied. The flexural over-strength factor for epoxy resin polymeric materials were also evaluated.

Thermal/Mechanical Response and Damage Growth in Polymeric Composites at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Whitley, Karen S.; Gates, Thomas S.

2002-01-01

In order to increase the reliability of the next generation of space transportation systems, the mechanical behavior of polymeric matrix composite (PMC) materials at cryogenic temperatures must be investigated. This paper presents experimental data on the residual mechanical properties of a carbon fiber polymeric composite, IM7/PETI-5 both before and after aging at cryogenic temperatures. Tension modulus and strength were measured at room temperature, -196 C, and -269 C on five different specimen ply lay-ups, [0](sub 12), [90](sub 12), [+/-45](sub 3S), [+/-25](sub 3s) and [45,90(sub 3),-45,0(sub 3),-45,90(sub 3),45]. Specimens were preconditioned with one set of coupons being isothermally aged for 555 hours at -184 C in an unloaded state. Another set of corresponding coupons were mounted in constant displacement fixtures such that a constant uniaxial strain was applied to the specimens for 555 hours at -184 C. The measured lamina level properties indicated that cryogenic temperatures have an appreciable influence on behavior, and residual stress calculations based on lamination theory showed that the transverse tensile ply stresses could be quite high for cryogenic test temperatures. Microscopic examination of the surface morphology showed evidence of degradation along the exposed edges of the material due to aging at cryogenic temperatures.

Probabilistic analysis of the behavior of polymer matrix composite materials reinforced by different types of fibers

NASA Astrophysics Data System (ADS)

Harb, N.; Bezzazi, B.; Mehraz, S.; Hamitouche, K.; Dilmi, H.

2017-11-01

The requests of lightening of the structures and gains in performance lead to search for new materials and the associated processes for aeronautical and space applications. Long-fiber composites have been used for many years for these applications; they make it possible to reduce the mass of the structures because of their excellent compromise of mass/rigidity / resistance. The materials in general contain defects which are essentially due to their nature and their mode of elaboration. To this purpuse, we carried out a probabilistic analysis of the mechanical behavior in three-point bending of composite materials with a thermosetting matrix in order to highlight the influence of the number of folds of the fibers and the nature of the fibers on the dispersion of the defects in the stratified structures fiberglass, carbon fiber laminates and hybrid (carbon / glass) laminates. From the results obtained, the dispersion of the defects is lower in the laminates of greater number of plies of the fibers and the hybrid laminates; the more the number of folds increases the more the mechanical characteristics increase; the hybrid laminates exhibit better mechanical properties compared to laminates of the same type of fiber. Finally, a morphological analysis of fracture structures and facies was investigated by scanning electron microscope (SEM) observations.

Fabrication and Evaluation of Bis-GMA/TEGDMA Dental Resins/Composites Containing Nano Fibrillar Silicate

PubMed Central

Tian, Ming; Gao, Yi; Liu, Yi; Liao, Yiliang; Hedin, Nyle E.; Fong, Hao

2008-01-01

Objective To investigate the reinforcement of Bis-GMA/TEGDMA dental resins (without conventional glass filler) and composites (with conventional glass filler) with various mass fractions of nano fibrillar silicate (FS). Methods Three dispersion methods were studied to separate the silanized FS as nano-scaled single crystals and uniformly distribute them into dental matrices. The photo-curing behaviors of the Bis-GMA/TEGDMA/FS resins were monitored in situ by RT-NIR to study the photopolymerization rate and the vinyl double bond conversion. Mechanical properties (flexural strength, elastic modulus and work of fracture) of the nano FS reinforced resins/composites were tested, and Analysis of Variance (ANOVA) was used for the statistical analysis of the acquired data. The morphology of nano FS and the representative fracture surfaces of its reinforced resins/composites were examined by SEM/TEM. Results Impregnation of small mass fractions (1 % and 2.5 %) of nano FS into Bis-GMA/TEGDMA (50/50 mass ratio) dental resins/composites improved the mechanical properties substantially. Larger mass fraction of impregnation (7.5 %), however, did not further improve the mechanical properties (one way ANOVA, P > 0.05) and may even reduce the mechanical properties. The high degree of separation and uniform distribution of nano FS into dental resins/composites was a challenge. Impregnation of nano FS into dental resins/composites could result in two opposite effects: a reinforcing effect due to the highly separated and uniformly distributed nano FS single crystals, or a weakening effect due to the formation of FS agglomerates/particles. Significance Uniform distribution of highly separated nano FS single crystals into dental resins/composites could significantly improve the mechanical properties of the resins/composites. PMID:17572485

Fabrication and evaluation of Bis-GMA/TEGDMA dental resins/composites containing nano fibrillar silicate.

PubMed

Tian, Ming; Gao, Yi; Liu, Yi; Liao, Yiliang; Hedin, Nyle E; Fong, Hao

2008-02-01

To investigate the reinforcement of Bis-GMA/TEGDMA dental resins (without conventional glass filler) and composites (with conventional glass filler) with various mass fractions of nano fibrillar silicate (FS). Three dispersion methods were studied to separate the silanized FS as nano-scaled single crystals and uniformly distribute them into dental matrices. The photo-curing behaviors of the Bis-GMA/TEGDMA/FS resins were monitored in situ by RT-NIR to study the photopolymerization rate and the vinyl double bond conversion. Mechanical properties (flexural strength, elastic modulus and work-of-fracture) of the nano FS reinforced resins/composites were tested, and analysis of variance (ANOVA) was used for the statistical analysis of the acquired data. The morphology of nano FS and the representative fracture surfaces of its reinforced resins/composites were examined by SEM/TEM. Impregnation of small mass fractions (1% and 2.5%) of nano FS into Bis-GMA/TEGDMA (50/50 mass ratio) dental resins/composites improved the mechanical properties substantially. Larger mass fraction of impregnation (7.5%), however, did not further improve the mechanical properties (one way ANOVA, P>0.05) and may even reduce the mechanical properties. The high degree of separation and uniform distribution of nano FS into dental resins/composites was a challenge. Impregnation of nano FS into dental resins/composites could result in two opposite effects: a reinforcing effect due to the highly separated and uniformly distributed nano FS single crystals, or a weakening effect due to the formation of FS agglomerates/particles. Uniform distribution of highly separated nano FS single crystals into dental resins/composites could significantly improve the mechanical properties of the resins/composites.

Effect of amorphous Mg{sub 50}Ni{sub 50} on hydriding and dehydriding behavior of Mg{sub 2}Ni alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guzman, D., E-mail: danny.guzman@uda.cl; Ordonez, S.; Fernandez, J.F.

Composite Mg{sub 2}Ni (25 wt.%) amorphous Mg{sub 50}Ni{sub 50} was prepared by mechanical milling starting with nanocrystalline Mg{sub 2}Ni and amorphous Mg{sub 50}Ni{sub 50} powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg{submore » 50}Ni{sub 50} improved the hydriding and dehydriding kinetics of Mg{sub 2}Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: {yields} First study of the hydriding behavior of composite Mg{sub 2}Ni (25 wt.%) amorphous Mg{sub 50}Ni{sub 50}. {yields} Microstructural characterization of composite material using XRD and SEM was obtained. {yields} An improved effect of Mg{sub 50}Ni{sub 50} on the Mg{sub 2}Ni hydriding behavior was verified. {yields} The apparent activation energy for the hydrogen desorption of composite was obtained.« less

Finite Element Modeling of Multilayer Orthogonal Auxetic Composites under Low-Velocity Impact

PubMed Central

Jiang, Lili; Hu, Hong

2017-01-01

The multilayer orthogonal auxetic composites have been previously developed and tested to prove that they own excellent energy absorption and impact protection characteristics in a specific strain range under low-velocity impact. In this study, a three dimensional finite element (FE) model in ANSYS LS-DYNA was established to simulate the mechanical behavior of auxetic composites under low-velocity drop-weight impact. The simulation results including the Poisson’s ratio versus compressive strain curves and the contact stress versus compressive strain curves were compared with those in the experiments. The clear deformation pictures of the FE models have provided a simple and effective way for investigating the damage mechanism and optimizing the material, as well as structure design. PMID:28783054

Chameleon Coatings: Adaptive Surfaces to Reduce Friction and Wear in Extreme Environments

NASA Astrophysics Data System (ADS)

Muratore, C.; Voevodin, A. A.

2009-08-01

Adaptive nanocomposite coating materials that automatically and reversibly adjust their surface composition and morphology via multiple mechanisms are a promising development for the reduction of friction and wear over broad ranges of ambient conditions encountered in aerospace applications, such as cycling of temperature and atmospheric composition. Materials selection for these composites is based on extensive study of interactions occurring between solid lubricants and their surroundings, especially with novel in situ surface characterization techniques used to identify adaptive behavior on size scales ranging from 10-10 to 10-4 m. Recent insights on operative solid-lubricant mechanisms and their dependency upon the ambient environment are reviewed as a basis for a discussion of the state of the art in solid-lubricant materials.

Numerical, micro-mechanical prediction of crack growth resistance in a fibre-reinforced/brittle matrix composite

NASA Technical Reports Server (NTRS)

Jenkins, Michael G.; Ghosh, Asish; Salem, Jonathan A.

1990-01-01

Micromechanics fracture models are incorporated into three distinct fracture process zones which contribute to the crack growth resistance of fibrous composites. The frontal process zone includes microcracking, fiber debonding, and some fiber failure. The elastic process zone is related only to the linear elastic creation of new matrix and fiber fracture surfaces. The wake process zone includes fiber bridging, fiber pullout, and fiber breakage. The R-curve predictions of the model compare well with empirical results for a unidirectional, continuous fiber C/C composite. Separating the contributions of each process zone reveals the wake region to contain the dominant crack growth resistance mechanisms. Fractography showed the effects of the micromechanisms on the macroscopic fracture behavior.

Flexural creep behaviour of jute polypropylene composites

NASA Astrophysics Data System (ADS)

Chandekar, Harichandra; Chaudhari, Vikas

2016-09-01

Present study is about the flexural creep behaviour of jute fabric reinforced polypropylene (Jute-PP) composites. The PP sheet and alkali treated jute fabric is stacked alternately and hot pressed in compression molding machine to get Jute-PP composite laminate. The flexural creep study is carried out on dynamic mechanical analyzer. The creep behaviour of the composite is modeled using four-parameter Burgers model. Short-term accelerated creep testing is conducted which is later used to predict long term creep behaviour. The feasibility of the construction of a master curve using the time-temperature superposition (TTS) principle to predict long term creep behavior of unreinforced PP and Jute-PP composite is investigated.

Progressive Fracture of Fiber Composite Build-Up Structures

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Chamis, C. C.; Minnetyan, Levon

1997-01-01

Damage progression and fracture of built-up composite structures is evaluated by using computational simulation. The objective is to examine the behavior and response of a stiffened composite (0/ +/- 45/90)(sub s6) laminate panel by simulating the damage initiation, growth, accumulation, progression and propagation to structural collapse. An integrated computer code, CODSTRAN, was augmented for the simulation of the progressive damage and fracture of built-up composite structures under mechanical loading. Results show that damage initiation and progression have significant effect on the structural response. Influence of the type of loading is investigated on the damage initiation, propagation and final fracture of the build-up composite panel.

Progressive Fracture of Fiber Composite Build-Up Structures

NASA Technical Reports Server (NTRS)

Minnetyan, Levon; Gotsis, Pascal K.; Chamis, C. C.

1997-01-01

Damage progression and fracture of built-up composite structures is evaluated by using computational simulation. The objective is to examine the behavior and response of a stiffened composite (0 +/-45/90)(sub s6) laminate panel by simulating the damage initiation, growth, accumulation, progression and propagation to structural collapse. An integrated computer code CODSTRAN was augmented for the simulation of the progressive damage and fracture of built-up composite structures under mechanical loading. Results show that damage initiation and progression to have significant effect on the structural response. Influence of the type of loading is investigated on the damage initiation, propagation and final fracture of the build-up composite panel.

Tailoring the Microstructure of Sol–Gel Derived Hydroxyapatite/Zirconia Nanocrystalline Composites

PubMed Central

2011-01-01

In this study, we tailor the microstructure of hydroxyapatite/zirconia nanocrystalline composites by optimizing processing parameters, namely, introducing an atmosphere of water vapor during sintering in order to control the thermal stability of hydroxyapatite, and a modified sol–gel process that yields to an excellent intergranular distribution of zirconia phase dispersed intergranularly within the hydroxyapatite matrix. In terms of mechanical behavior, SEM images of fissure deflection and the presence of monoclinic ZrO2 content on cracked surface indicate that both toughening mechanisms, stress-induced tetragonal to monoclinic phase transformation and deflection, are active for toughness enhancement. PMID:24764458

Wear and friction behavior of Al-TiB2-nano-Gr hybrid composites fabricated through ultrasonic cavitation assisted stir casting

NASA Astrophysics Data System (ADS)

Poria, Suswagata; Sutradhar, Goutam; Sahoo, Prasanta

2018-05-01

The present study reports the role of nano-graphite particles in determining wear and friction behavior of Al-TiB2-nano-Gr hybrid composites. Ultrasonic cavitation assisted stir casting method has been used for fabrication of composites. Al-Si5Cu3 alloy is used as base alloy along with micro sized TiB2 hard ceramic particles (2.5 and 5.5 wt%) as reinforcement and nano-Gr particles (2 and 4 wt%) as solid lubricant additives. SEM micrographs, EDAX spectrum and optical images are considered to observe uniform dispersion of reinforcing phases. Micro-hardness is evaluated using Vicker’s microhardness tester. Hardness is seen to increase with incorporation of TiB2 while the same decreases with incorporation of graphite. Wear and friction of composites are tested for varying load (10 to 40 N) and sliding speed (0.2 to 0.4 m s‑1) using a pin-on-disk tribometer. Worn surfaces are characterized using SEM and EDAX analysis. Wear resistance of composites increases with incorporation of reinforcing phases together. Nano-Gr particles are easily sheared out from the sub-surface and provide a layer over the tribo-surface of composite that enhances friction and wear behavior. Wear mechanism in composites is predominantly adhesion while abrasion and ploughing is prominent in base alloy.

Interfacial complexation in microfluidic droplets for single-step fabrication of microcapsule

NASA Astrophysics Data System (ADS)

Kaufman, Gilad; Nejati, Siamak; Sarfati, Raphael; Boltyanskiy, Rostislav; Williams, Danielle; Liu, Wei; Schloss, Ashley; Regan, Lynn; Yan, Elsa; Dufrense, Eric; Loewenberg, Michael; Osuji, Chinedum

We present microfluidic interfacial complexation in emulsion droplets as a simple single-step approach for fabricating a large variety of stable monodisperse microcapsules with tailored mechanical properties, protein binding and controlled release behavior. We rely on electrostatic interactions and hydrogen bonding to direct the assembly of complementary species at oil-water droplet interfaces to form microcapsules with polyelectrolyte shells, composite polyelectrolyte-nanoparticle shells, and copolymer-nanofiber shells. Additionally, we demonstrate the formation of microcapsules by adsorption of an amphiphilic bacterial hydrophobin, BslA, at oil-in-water and water-in-oil droplets, and protein capture on these capsules using engineered variants of the hydrophobin. We discuss the composition dependence of mechanical properties, shell thickness and release behavior, and regimes of stability for microcapsule fabrication. Nanoparticle based microcapsules display an intriguing plastic deformation response which enables the formation of large aspect ratio asperities by pipette aspiration of the shell.

Rheology and mechanics of polyether(ether)ketone - Polyetherimide blends for composites in aeronautics

NASA Astrophysics Data System (ADS)

Rosa, Mattia; Grassia, Luigi; D'Amore, Alberto; Carotenuto, Claudia; Minale, Mario

2016-05-01

In the present work rheological and mechanical properties of PEEK-PEI blends were investigated. Besides the pure components, blends with PEI concentration ranging from 10% to 90% in mass were considered. Oscillatory experiments in controlled atmosphere were conducted at different frequencies and temperatures. The frequency responses at different temperatures allowed using the TTS principle to reconstruct the master curves. All systems showed a shear thinning behavior and a flux index increasing with the percentage of PEI. The zero-shear viscosity was computed with the implementation of the Cross model and showed a decreasing behavior with the percentage of PEI. The relaxation time estimated from the crossover value of storage and loss moduli didn't change significantly with blend composition, suggesting the non-sensibility of the elasticity of the system. Lastly, tensile tests were executed to investigate the dependence of Young modulus in the different blends.

AC and DC electrical properties of graphene nanoplatelets reinforced epoxy syntactic foam

NASA Astrophysics Data System (ADS)

Zegeye, Ephraim; Wicker, Scott; Woldesenbet, Eyassu

2018-04-01

Benefits of employing graphene nanopletlates (GNPLs) in composite structures include mechanical as well as multifunctional properties. Understanding the impedance behavior of GNPLs reinforced syntactic foams may open new applications for syntactic foam composites. In this work, GNPLs reinforced syntactic foams were fabricated and tested for DC and AC electrical properties. Four sets of syntactic foam samples containing 0, 0.1, 0.3, and 0.5 vol% of GNPLs were fabricated and tested. Significant increase in conductivity of syntactic foams due to the addition of GNPLs was noted. AC impedance measurements indicated that the GNPLs syntactic foams become frequency dependent as the volume fraction of GNPLs increases. With addition of GNPLs, the characteristic of the syntactic foams are also observed to transition from dominant capacitive to dominant resistive behavior. This work was carried out at Southern University, Mechanical Engineering Department, Baton Rouge, LA 70802, United States of America.

Morphological and mechanical properties of styrene butadiene rubber/nano copper nanocomposites

NASA Astrophysics Data System (ADS)

Harandi, Maryam Hadizadeh; Alimoradi, Fakhrodin; Rowshan, Gholamhussein; Faghihi, Morteza; Keivani, Maryam; Abadyan, Mohamadreza

In this research, rubber based nanocomposites with presence of nanoparticle has been studied. Styrene butadiene rubber (SBR)/nanocopper (NC) composites were prepared using two-roll mill method. Transmission electron microscope (TEM) and scanning electron microscope (SEM) images showed proper dispersion of NC in the SBR matrix without substantial agglomeration of nanoparticles. To evaluate the curing properties of nanocomposite samples, swelling and cure rheometric tests were conducted. Moreover, the rheological studies were carried out over a range of shear rates. The effect of NC particles was examined on the thermal behavior of the SBR using thermal gravimetric analysis (TGA). Furthermore, tensile tests were employed to investigate the capability of nanoparticles to enhance mechanical behavior of the compounds. The results showed enhancement in tensile properties with incorporation of NC to SBR matrix. Moreover, addition of NC increased shear viscosity and curing time of SBR composites.

An experimental investigation of damage evolution in a ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walter, M.E.; Ravichandran, G.

The mechanical behavior of a glass-ceramic matrix composite, SiC/CAS (calcium aluminosilicate reinforced with unidirectional SiC fibers), is studied. Results based on uniaxial tension experiments are presented for specimens with fibers aligned in the loading direction. Axial and transverse strain gages on all four gage section surfaces and in situ acoustic emission and ultrasonic wave speed measurements were used to monitor the evolution of damage. All measurements were made with high-resolution, continuous data acquisition. Post-test optical and scanning electron microscopy was also used to identify the various micromechanisms of damage. The experimental results demonstrate the existence of zones of deformation'' whichmore » are associated with the onset of different damage mechanisms. It is shown that the observed stress-strain behavior can be explained in terms of the material properties of the matrix and the fiber, the material processing, and the postulated zones of deformation.« less

The Hardness and Strength Properties of WC-Co Composites

PubMed Central

Armstrong, Ronald W.

2011-01-01

The industrially-important WC-Co composite materials provide a useful, albeit complicated materials system for understanding the combined influences on hardness and strength properties of the constituent WC particle strengths, the particle sizes, their contiguities, and of Co binder hardness and mean free paths, and in total, the volume fraction of constituents. A connection is made here between the composite material properties, especially including the material fracture toughness, and the several materials-type considerations of: (1) related hardness stress-strain behaviors; (2) dislocation (viscoplastic) thermal activation characterizations; (3) Hall-Petch type reciprocal square root of particle or grain size dependencies; and (4) indentation and conventional fracture mechanics results. Related behaviors of MgO and Al2O3 crystal and polycrystal materials are also described for the purpose of making comparisons. PMID:28824143

Tensile behavior of cenosphere/epoxy syntactic foams

NASA Astrophysics Data System (ADS)

Shahapurkar, Kiran; Doddamani, Mrityunjay; Kumar, G. C. Mohan

2018-04-01

Tensile behavior of syntactic foam composites are very critical to the engineering applications. The fracture modes and failure mechanisms under tension must be fully understood in order to realize the potential of such composites. In the present work, syntactic foam composites are fabricated using as received and surface modified hollow cenospheres embedded into epoxy matrix. Combinations of cenosphere volume fraction (0, 20, 40 and 60%) and surface modification are studied. Experimental results reveal that modulus of both untreated and treated syntactic foams increases with increase in cenosphere volume fraction compared to neat resin. Strength values of syntactic foams show decreasing trend compared to neat resin. However, treated syntactic foams demonstrated better results compared to untreated ones attributing to good bonding between matrix and filler. Scanning electron microscopy reveal brittle fracture for all the syntactic foams.

Nitrite sensing composite systems based on a core-shell emissive-superamagnetic structure: Construction, characterization and sensing behavior

NASA Astrophysics Data System (ADS)

Yang, Yan; Liu, Liang; Zha, Jianhua; Yuan, Ningyi

2017-04-01

Two recyclable nitrite sensing composite samples were designed and constructed through a core-shell structure, with Fe3O4 nanoparticles as core, silica molecular sieve MCM-41 as shell and two rhodamine derivatives as chemosensors, respectively. These samples and their structure were identified with their electron microscopy images, N2 adsorption/desorption isotherms, magnetic response, IR spectra and thermogravimetric analysis. Their nitrite sensing behavior was discussed based on emission intensity quenching, their limit of detection was found as low as 1.2 μM. Further analysis suggested a static sensing mechanism between nitrite and chemosensors through an additive reaction between NO+ and chemosensors. After finishing their nitrite sensing, these composite samples and their emission could be recycled and recovered by sulphamic acid.

Tribocorrosion behavior of beta titanium biomedical alloys in phosphate buffer saline solution.

PubMed

Pina, V Guiñón; Dalmau, A; Devesa, F; Amigó, V; Muñoz, A Igual

2015-06-01

The tribo-electrochemical behavior of different β titanium alloys for biomedical applications sintered by powder metallurgy has been investigated. Different mechanical, electrochemical and optical techniques were used to study the influence of the chemical composition, Sn content, and the electrochemical conditions on the tribocorrosion behavior of those alloys Ti30NbxSn alloys (where "x" is the weight percentage of Sn content, 2% and 4%). Sn content increases the active and passive dissolution rate of the titanium alloys, thus increasing the mechanically activated corrosion under tribocorrosion conditions. It also increases the mechanical wear of the alloy. Prevailing electrochemical conditions between -1 and 2V influences the wear accelerated corrosion by increasing it with the applied potential and slightly increases the mechanical wear of Ti30Nb4Sn. Wear accelerated corrosion can be predicted by existing models as a function of electrochemical and mechanical parameters of the titanium alloys. Copyright © 2015 Elsevier Ltd. All rights reserved.

Nanoindentation and thermal characterization of poly (vinylidenefluoride)/MWCNT nanocomposites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eggedi, Obulapathi; Valiyaneerilakkal, Uvais; Varghese, Soney, E-mail: soneyva@nitc.ac.in

2014-04-15

We report the preparation, thermal and micro/nanomechanical behavior of poly (vinylidine diflouride) (PVDF)/multiwalled carbon nanotube (MWCNT) nanocomposites. It has been found that the addition of MWCNT considerably enhances the β-phase formation, thermal and mechanical properties of PVDF. Atomic force microscope (AFM) studies have been performed on the composites under stress conditions to measure the mechanical properties. The nanoscale mechanical properties of the composites like Young's modulus and hardness of the nanocomposites were investigated by nanoindentation technique. Morphological studies of the nanocomposites were also studied, observations show a uniform distribution of MWCNT in the matrix and interfacial adhesion between PVDF andmore » MWCNT was achieved, which was responsible for enhancement in the hardness and Young's modulus. Differential scanning calorimetry (DSC) studies indicate that the melting temperature of the composites have been slightly increased while the heat of fusion markedly decreased with increasing MWCNT content.« less

Effect of Mechanical and Thermal Loading Histories on Residual Properties of SiCf/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Almansour, Amjad; Kiser, Doug; Smith, Craig; Bhatt, Ram; Gorican, Dan; Phillips, Ron; McCue, Terry R.

2017-01-01

Silicon Carbide based Ceramic Matrix Composites (CMCs) are attractive materials for use in high-temperature structural applications in the aerospace and nuclear industries. Under high stresses and temperatures, creep degradation is the dominant damage mechanism in CMCs. Consequently, chemical vapor infiltration (CVI) SiCf/SiC ceramic matrix composites (CMC) incorporating SylramicTM-iBN SiC fibers coated with boron nitride (BN) interphase and CVI-SiC matrix were tested to examine creep behavior in air at a range of elevated temperatures of (2200 - 2700 F). Samples that survived creep tests were evaluated via RT fast fracture tensile tests to determine residual properties, with the use of acoustic emission (AE) to assess stress dependent damage initiation and progression. Microscopy of regions within the gage section of the tested specimens was performed. Observed material degradation mechanisms are discussed.

Mechanical behavior of glass/epoxy composite laminate with varying amount of MWCNTs under different loadings

NASA Astrophysics Data System (ADS)

Singh, K. K.; Rawat, Prashant

2018-05-01

This paper investigates the mechanical response of three phased (glass/MWCNTs/epoxy) composite laminate under three different loadings. Flexural strength, short beam strength and low-velocity impact (LVI) testing are performed to find an optimum doping percentage value for maximum enhancement in mechanical properties. In this work, MWCNTs were used as secondary reinforcement for three-phased composite plate. MWCNT doping was done in a range of 0–4 wt% of the thermosetting matrix system. Symmetrical design eight layered glass/epoxy laminate with zero bending extension coupling laminate was fabricated using a hybrid method i.e. hand lay-up technique followed by vacuum bagging method. Ranging analysis of MWCNT mixing highlighted the enhancement in flexural, short beam strength and improvement in damage tolerance under LVI loading. While at higher doping wt%, agglomeration of MWCNTs are observed. Results of mechanical testing proposed an optimized doping value for maximum strength and damage resistance of the laminate.

Variable ecological conditions promote male helping by changing banded mongoose group composition.

PubMed

Marshall, Harry H; Sanderson, Jennifer L; Mwanghuya, Francis; Businge, Robert; Kyabulima, Solomon; Hares, Michelle C; Inzani, Emma; Kalema-Zikusoka, Gladys; Mwesige, Kenneth; Thompson, Faye J; Vitikainen, Emma I K; Cant, Michael A

2016-01-01

Ecological conditions are expected to have an important influence on individuals' investment in cooperative care. However, the nature of their effects is unclear: both favorable and unfavorable conditions have been found to promote helping behavior. Recent studies provide a possible explanation for these conflicting results by suggesting that increased ecological variability, rather than changes in mean conditions, promote cooperative care. However, no study has tested whether increased ecological variability promotes individual-level helping behavior or the mechanisms involved. We test this hypothesis in a long-term study population of the cooperatively breeding banded mongoose, Mungos mungo , using 14 years of behavioral and meteorological data to explore how the mean and variability of ecological conditions influence individual behavior, body condition, and survival. Female body condition was more sensitive to changes in rainfall leading to poorer female survival and pronounced male-biased group compositions after periods of high rainfall variability. After such periods, older males invested more in helping behavior, potentially because they had fewer mating opportunities. These results provide the first empirical evidence for increased individual helping effort in more variable ecological conditions and suggest this arises because of individual differences in the effect of ecological conditions on body condition and survival, and the knock-on effect on social group composition. Individual differences in sensitivity to environmental variability, and the impacts this has on the internal structure and composition of animal groups, can exert a strong influence on the evolution and maintenance of social behaviors, such as cooperative care.

Variable ecological conditions promote male helping by changing banded mongoose group composition

PubMed Central

Sanderson, Jennifer L.; Mwanghuya, Francis; Businge, Robert; Kyabulima, Solomon; Hares, Michelle C.; Inzani, Emma; Kalema-Zikusoka, Gladys; Mwesige, Kenneth; Thompson, Faye J.; Vitikainen, Emma I. K.; Cant, Michael A.

2016-01-01

Ecological conditions are expected to have an important influence on individuals’ investment in cooperative care. However, the nature of their effects is unclear: both favorable and unfavorable conditions have been found to promote helping behavior. Recent studies provide a possible explanation for these conflicting results by suggesting that increased ecological variability, rather than changes in mean conditions, promote cooperative care. However, no study has tested whether increased ecological variability promotes individual-level helping behavior or the mechanisms involved. We test this hypothesis in a long-term study population of the cooperatively breeding banded mongoose, Mungos mungo, using 14 years of behavioral and meteorological data to explore how the mean and variability of ecological conditions influence individual behavior, body condition, and survival. Female body condition was more sensitive to changes in rainfall leading to poorer female survival and pronounced male-biased group compositions after periods of high rainfall variability. After such periods, older males invested more in helping behavior, potentially because they had fewer mating opportunities. These results provide the first empirical evidence for increased individual helping effort in more variable ecological conditions and suggest this arises because of individual differences in the effect of ecological conditions on body condition and survival, and the knock-on effect on social group composition. Individual differences in sensitivity to environmental variability, and the impacts this has on the internal structure and composition of animal groups, can exert a strong influence on the evolution and maintenance of social behaviors, such as cooperative care. PMID:27418750

Fabrication of Continuous Microfibers Containing Magnetic Nanoparticles by a Facile Magneto-Mechanical Drawing

NASA Astrophysics Data System (ADS)

Li, Jin-Tao; Jia, Xian-Sheng; Yu, Gui-Feng; Yan, Xu; He, Xiao-Xiao; Yu, Miao; Gong, Mao-Gang; Ning, Xin; Long, Yun-Ze

2016-09-01

A facile method termed magneto-mechanical drawing is used to produce polymer composite microfibers. Compared with electrospinning and other fiber spinning methods, magneto-mechanical drawing uses magnetic force generated by a permanent magnet to draw droplets of polymer/magnetic nanoparticle suspensions, leading to fabrication of composite microfibers. In addition, because of the rotating collector, it is easy to control the fiber assembly such as fibrous array in parallel or crossed fibrous structure. The general applicability of this method has also been proved by spinning different polymers and magnetic nanoparticles. The resultant fibers exhibit good superparamagnetic behavior at room temperature and ultrahigh stretchability (~443.8 %). The results indicate that magneto-mechanical drawing is a promising technique to fabricate magnetic and stretchable microfibers and devices.

Fabrication of Continuous Microfibers Containing Magnetic Nanoparticles by a Facile Magneto-Mechanical Drawing.

PubMed

Li, Jin-Tao; Jia, Xian-Sheng; Yu, Gui-Feng; Yan, Xu; He, Xiao-Xiao; Yu, Miao; Gong, Mao-Gang; Ning, Xin; Long, Yun-Ze

2016-12-01

A facile method termed magneto-mechanical drawing is used to produce polymer composite microfibers. Compared with electrospinning and other fiber spinning methods, magneto-mechanical drawing uses magnetic force generated by a permanent magnet to draw droplets of polymer/magnetic nanoparticle suspensions, leading to fabrication of composite microfibers. In addition, because of the rotating collector, it is easy to control the fiber assembly such as fibrous array in parallel or crossed fibrous structure. The general applicability of this method has also been proved by spinning different polymers and magnetic nanoparticles. The resultant fibers exhibit good superparamagnetic behavior at room temperature and ultrahigh stretchability (~443.8 %). The results indicate that magneto-mechanical drawing is a promising technique to fabricate magnetic and stretchable microfibers and devices.

Properties of M40J Carbon/PMR-II-50 Composites Fabricated with Desized and Surface Treated Fibers. Characterization of M40J Desized and Finished Fibers

NASA Technical Reports Server (NTRS)

Allred, Ronald E.; Gosau, Jan M.; Shin, E. Eugene; McCorkle, Linda S.; Sutter, James K.; OMalley, Michelle; Gray, Hugh R. (Technical Monitor)

2002-01-01

To increase performance and durability of high temperature composites for potential rocket engine components, it is necessary to optimize wetting and interfacial bonding between high modulus carbon fibers and high temperature polyimide resins. It has been previously demonstrated that the electro-oxidative shear treatments used by fiber manufacturers are not effective on higher modulus fibers that have fewer edge and defect sites in the surface crystallites. In addition, sizings commercially supplied on most carbon fibers are not compatible with polyimides. This study was an extension of prior work characterizing the surface chemistry and energy of high modulus carbon fibers (M40J and M60J, Torray) with typical fluorinated polyimide resins, such as PMR-II-50. A continuous desizing system which utilizes environmentally friendly chemical- mechanical processes was developed for tow level fiber and the processes were optimized based on weight loss behavior, surface elemental composition (XPS) and morphology (FE-SEM) analyses, and residual tow strength of the fiber, and the similar approaches have been applied on carbon fabrics. Both desized and further treated with a reactive finish were investigated for the composite reinforcement. The effects of desizing and/or subsequent surface retreatment on carbon fiber on composite properties and performance including fiber-matrix interfacial mechanical properties, thermal properties and blistering onset behavior will be discussed in this presentation.

Novel Formulations of Phase Change Materials—Epoxy Composites for Thermal Energy Storage

PubMed Central

Alvarez Feijoo, Miguel Angel

2018-01-01

This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs)-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a) inorganic PCMs (hydrated salts), epoxy resins and aluminum particulates or (b) organic PCM (paraffin), epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC) was used to analyze the thermal behavior of the samples, while hardness measurements were used to determine changes in mechanical properties at diverse PCM and conductive phase loading values. The results indicate that the epoxy matrix can act as a container for the PCM phase without hindering the heat-absorbing behavior of the PCMs employed. Organic PCMs presented reversible phase transformations over multiple cycles, an advantage that was lacking in their inorganic counterparts. The enthalpy of the organic PCM-epoxy specimens increased linearly with the PCM content in the matrix. The use of thickening agents prevented phase segregation issues and allowed the fabrication of specimens containing up to 40% PCM, a loading significantly higher than others reported. The conductive phase seemed to improve the heat transfer and the mechanical properties of the composites when present in low percentages (<10 wt %); however, given its mass, the enthalpy detected in the composites was reduced as their loading further increased. The conductive phase combination (PCM + epoxy resin + hardener + thickening agent) presents great potential as a heat-absorbing material at the temperatures employed. PMID:29373538

Cycle oxidation behavior and anti-oxidation mechanism of hot-dipped aluminum coating on TiBw/Ti6Al4V composites with network microstructure.

PubMed

Li, X T; Huang, L J; Wei, S L; An, Q; Cui, X P; Geng, L

2018-04-10

Controlled and compacted TiAl 3 coating was successfully fabricated on the network structured TiBw/Ti6Al4V composites by hot-dipping aluminum and subsequent interdiffusion treatment. The network structure of the composites was inherited to the TiAl 3 coating, which effectively reduces the thermal stress and avoids the cracks appeared in the coating. Moreover, TiB reinforcements could pin the TiAl 3 coating which can effectively improve the bonding strength between the coating and composite substrate. The cycle oxidation behavior of the network structured coating on 873 K, 973 K and 1073 K for 100 h were investigated. The results showed the coating can remarkably improve the high temperature oxidation resistance of the TiBw/Ti6Al4V composites. The network structure was also inherited to the Al 2 O 3 oxide scale, which effectively decreases the tendency of cracking even spalling about the oxide scale. Certainly, no crack was observed in the coating after long-term oxidation due to the division effect of network structured coating and pinning effect of TiB reinforcements. Interfacial reaction between the coating and the composite substrate occurred and a bilayer structure of TiAl/TiAl 2 formed next to the substrate after oxidation at 973 K and 1073 K. The anti-oxidation mechanism of the network structured coating was also discussed.

Novel Formulations of Phase Change Materials-Epoxy Composites for Thermal Energy Storage.

PubMed

Arce, Maria Elena; Alvarez Feijoo, Miguel Angel; Suarez Garcia, Andres; Luhrs, Claudia C

2018-01-26

This research aimed to evaluate the thermal properties of new formulations of phase change materials (PCMs)-epoxy composites, containing a thickening agent and a thermally conductive phase. The composite specimens produced consisted of composites fabricated using (a) inorganic PCMs (hydrated salts), epoxy resins and aluminum particulates or (b) organic PCM (paraffin), epoxy resins, and copper particles. Differential Scanning Calorimetry (DSC) was used to analyze the thermal behavior of the samples, while hardness measurements were used to determine changes in mechanical properties at diverse PCM and conductive phase loading values. The results indicate that the epoxy matrix can act as a container for the PCM phase without hindering the heat-absorbing behavior of the PCMs employed. Organic PCMs presented reversible phase transformations over multiple cycles, an advantage that was lacking in their inorganic counterparts. The enthalpy of the organic PCM-epoxy specimens increased linearly with the PCM content in the matrix. The use of thickening agents prevented phase segregation issues and allowed the fabrication of specimens containing up to 40% PCM, a loading significantly higher than others reported. The conductive phase seemed to improve the heat transfer and the mechanical properties of the composites when present in low percentages (<10 wt %); however, given its mass, the enthalpy detected in the composites was reduced as their loading further increased. The conductive phase combination (PCM + epoxy resin + hardener + thickening agent) presents great potential as a heat-absorbing material at the temperatures employed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marin, E.; Lekka, M., E-mail: maria.lekka@uniud.it; Andreatta, F.

In this paper, two different ASTM C 618 Class C fly ashes (FA) were used for the production of aluminum metal matrix composites (MMCs) using powder metallurgy (PM) technology. Calcareous FAs were sampled from the electrostatic precipitators of two different lignite-fired power stations: from Megalopolis, Southern Greece (MFA) and from Kardia, Northen Greece (KFA), under maximum electricity load. FAs were milled in order to reduce the mean particle diameter and Aluminum-FA composites containing 10% and 20% of FA were then prepared and compacted. The green products were sintered for 2 h at 600 Degree-Sign C. Sintered Al-FA MMCs showed increasedmore » hardness and wear resistance suggesting their possible use in industrial applications for example in covers, casings, brake rotors or engine blocks. As most possible industrial applications of MMCs not only require wear resistance, but also corrosion resistance in different mild aggressive medias, this paper aims to study the electrochemical behavior of FA MMCs in order to evaluate their corrosion resistance. The morphology and chemical composition of the phases in the Aluminum-FA composite samples were investigated using Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDXS). Moreover, topographic and Volta potential maps were acquired by Scanning Kelvin Probe Force Microscopy (SKP-FM). Volta potential maps provide information about the electrochemical behavior of the different phases in absence of electrolyte. The electrochemical behavior was investigated by Open Circuit Potential measurements and potentiodynamic polarization, while the corrosion mechanisms were studied by SEM observations after different times of immersion in a mild corrosive medium. In all cases it could be stated that the addition of the FA particles into the Al matrix might cause an increase of the hardness and mechanical properties of the pure aluminum but deteriorates the corrosion resistance. The degradation phenomena occurring on the FA containing samples might be related to the following mechanisms: 1) Partial detachment or dissolution of the FA soluble phases, in particular based on Si, Fe and Ca; 2) dissolution of the Al matrix surrounding the FA particles due to crevice corrosion; 3) Al localized dissolution due to galvanic coupling between the Fe-rich intermetallics and the matrix. - Highlights: Black-Right-Pointing-Pointer Aluminum metal matrix composites containing two types of fly ashes have been characterized. Black-Right-Pointing-Pointer The microstructure and the electrochemical behavior have been studied using different techniques. Black-Right-Pointing-Pointer The addition of FA deteriorates the corrosion resistance of the aluminum. Black-Right-Pointing-Pointer Degradation mechanisms: galvanic coupling, crevice corrosion, detachment of FA particles.« less

Correlations Between Bone Mechanical Properties and Bone Composition Parameters in Mouse Models of Dominant and Recessive Osteogenesis Imperfecta and the Response to Anti-TGF-β Treatment.

PubMed

Bi, Xiaohong; Grafe, Ingo; Ding, Hao; Flores, Rene; Munivez, Elda; Jiang, Ming Ming; Dawson, Brian; Lee, Brendan; Ambrose, Catherine G

2017-02-01

Osteogenesis imperfecta (OI) is a group of genetic disorders characterized by brittle bones that are prone to fracture. Although previous studies in animal models investigated the mechanical properties and material composition of OI bone, little work has been conducted to statistically correlate these parameters to identify key compositional contributors to the impaired bone mechanical behaviors in OI. Further, although increased TGF-β signaling has been demonstrated as a contributing mechanism to the bone pathology in OI models, the relationship between mechanical properties and bone composition after anti-TGF-β treatment in OI has not been studied. Here, we performed follow-up analyses of femurs collected in an earlier study from OI mice with and without anti-TGF-β treatment from both recessive (Crtap -/- ) and dominant (Col1a2 +/P.G610C ) OI mouse models and WT mice. Mechanical properties were determined using three-point bending tests and evaluated for statistical correlation with molecular composition in bone tissue assessed by Raman spectroscopy. Statistical regression analysis was conducted to determine significant compositional determinants of mechanical integrity. Interestingly, we found differences in the relationships between bone composition and mechanical properties and in the response to anti-TGF-β treatment. Femurs of both OI models exhibited increased brittleness, which was associated with reduced collagen content and carbonate substitution. In the Col1a2 +/P.G610C femurs, reduced hydroxyapatite crystallinity was also found to be associated with increased brittleness, and increased mineral-to-collagen ratio was correlated with increased ultimate strength, elastic modulus, and bone brittleness. In both models of OI, regression analysis demonstrated that collagen content was an important predictor of the increased brittleness. In summary, this work provides new insights into the relationships between bone composition and material properties in models of OI, identifies key bone compositional parameters that correlate with the impaired mechanical integrity of OI bone, and explores the effects of anti-TGF-β treatment on bone-quality parameters in these models. © 2016 American Society for Bone and Mineral Research. © 2016 American Society for Bone and Mineral Research.

Temperature dependent nonlinear metal matrix laminae behavior

NASA Technical Reports Server (NTRS)

Barrett, D. J.; Buesking, K. W.

1986-01-01

An analytical method is described for computing the nonlinear thermal and mechanical response of laminated plates. The material model focuses upon the behavior of metal matrix materials by relating the nonlinear composite response to plasticity effects in the matrix. The foundation of the analysis is the unidirectional material model which is used to compute the instantaneous properties of the lamina based upon the properties of the fibers and matrix. The unidirectional model assumes that the fibers properties are constant with temperature and assumes that the matrix can be modelled as a temperature dependent, bilinear, kinematically hardening material. An incremental approach is used to compute average stresses in the fibers and matrix caused by arbitrary mechanical and thermal loads. The layer model is incorporated in an incremental laminated plate theory to compute the nonlinear response of laminated metal matrix composites of general orientation and stacking sequence. The report includes comparisons of the method with other analytical approaches and compares theoretical calculations with measured experimental material behavior. A section is included which describes the limitations of the material model.

Erosion of iron-chromium alloys by glass particles

NASA Technical Reports Server (NTRS)

Salik, J.; Buckley, D. H.

1984-01-01

The material loss upon erosion was measured for several iron-chromium alloys. Two types of erodent material were used: spherical glass beads and sharp particles of crushed glass. For erosion with glass beads the erosion resistance (defined as the reciprocal of material loss rate) was linearly dependent on hardness. This is in accordance with the erosion behavior of pure metals, but contrary to the erosion behavior of alloys of constant composition that were subjected to different heat treatments. For erosion with crushed glass, however, no correlation existed between hardness and erosion resistance. Instead, the erosion resistance depended on alloy composition rather than on hardness and increased with the chromium content of the alloy. The difference in erosion behavior for the two types of erodent particles suggested that two different material removal mechanisms were involved. This was confirmed by SEM micrographs of the eroded surfaces, which showed that for erosion with glass beads the mechanism of material removal was deformation-induced flaking of surface layers, or peening, whereas for erosion with crushed glass it was cutting or chopping.

Non-linear mechanical behavior of a sintered material for braking application using digital image correlation

NASA Astrophysics Data System (ADS)

Mann, Ruddy; Magnier, Vincent; Serrano-Munoz, Itziar; Brunel, Jean-Francois; Brunel, Florent; Dufrenoy, Philippe; Henrion, Michele

2017-12-01

Friction materials for braking applications are complex composites made of many components to ensure the various performances required (friction coefficient level, low wear, mechanical strength, thermal resistance, etc.). The material is developed empirically by a trial and error approach. With the solicitation, the material evolves and probably also its properties. In the literature, the mechanical behavior of such materials is generally considered as linear elastic and independent of the loading history. This paper describes a methodology to characterize the mechanical behavior of such a heterogeneous material in order to investigate its non-linear mechanical behavior. Results from mechanical tests are implemented into material laws for numerical simulations. Thanks to the instrumentation, some links with the microstructure can also be proposed. The material is made of a metallic matrix embedding graphite and ceramic particles and is manufactured by sintering. It is used for dry friction applications such as high-energy brake for trains, cars and motorcycles. Compression tests are done with digital image correlation to measure full-filled displacement. It allows to calculate strain fields with enough resolution to identify the material heterogeneity and the role of some of the components of the formulation. A behavior model of the material with plasticity and damage is proposed to simulate the non-linear mechanical behavior and is implemented in an FEM code. Results of mechanical test simulations are compared with two types of experiments showing good agreement. This method thus makes it possible to determine mechanical properties at a virgin state but is extensible for characterizing a material having been submitted to braking solicitations.

Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hemalatha, K. S.; Damle, R.; Rukmani, K., E-mail: rukmani9909@yahoo.co.in

2015-10-21

Dielectric and conductivity behaviors of nano ZnO doped polyvinyl alcohol (PVA) composites for various concentrations of dopant were investigated using impedance spectroscopy for a wide range of temperatures (303 K–423 K) and frequencies (5 Hz–30 MHZ). The dielectric properties of host polymer matrix have been improved by the addition of nano ZnO and are found to be highly temperature dependent. Anomalous dielectric behavior was observed in the frequency range of 2.5 MHz–5 MHz. Increase in dielectric permittivity and dielectric loss was observed with respect to temperature. The Cole-Cole plot could be modeled by low resistance regions in a high resistance matrix and the lowest resistance wasmore » observed for the 10 mol. % films. The imaginary part of the electric modulus showed asymmetric peaks with the relaxation following Debye nature below and non-Debye nature above the peaks. The ac conductivity is found to obey Jonscher's power law, whereas the variation of dc conductivity with temperature was found to follow Arrhenius behavior. Two different activation energy values were obtained from Arrhenius plot indicating that two conduction mechanisms are involved in the composite films. Fitting the ac conductivity data to Jonscher's law indicates that large polaron assisted tunneling is the most likely conduction mechanism in the composites. Maximum conductivity is observed at 423 K for all the samples and it is optimum for 10 mol. % ZnO doped PVA composite film. Significant increase in dc and ac conductivities in these composite films makes them a potential candidate for application in electronic devices.« less

Effects of physical aging on long-term behavior of composites

NASA Technical Reports Server (NTRS)

Brinson, L. Catherine

1993-01-01

The HSCT plane, envisioned to have a lifetime of over 60,000 flight hours and to travel at speeds in excess of Mach 2, is the source of intensive study at NASA. In particular, polymer matrix composites are being strongly considered for use in primary and secondary structures due to their high strength to weight ratio and the options of property tailoring. However, an added difficulty in the use of polymer based materials is that their properties change significantly over time, especially at the elevated temperatures that will be experienced during flight, and prediction of properties based on irregular thermal and mechanical loading is extremely difficult. This study focused on one aspect of long-term polymer composite behavior: physical aging. When a polymer is cooled to below its glass transition temperature, the material is not in thermodynamic equilibrium and the free volume and enthalpy evolve over time to approach their equilibrium values. During this time, the mechanical properties change significantly and this change is termed physical aging. This work begins with a review of the concepts of physical aging on a pure polymer system. The effective time theory, which can be used to predict long term behavior based on short term data, is mathematically formalized. The effects of aging to equilibrium are proven and discussed. The theory developed for polymers is then applied first to a unidirectional composite, then to a general laminate. Comparison to experimental data is excellent. It is shown that the effects of aging on the long-term properties of composites can be counter-intuitive, stressing the importance of the development and use of a predictive theory to analyze structures.

Size dependent anomalous dielectric behavior in nanoparticle Gd2 O 3 : SiO2 glass composite system

NASA Astrophysics Data System (ADS)

Mukherjee, Sudip; Lin, Yu-Hsing; Kao, Ting-Hui; Chou, C. C.; Yang, H. D.

2011-03-01

Gd 2 O3 (0.5 mol%) nanoparticles have been synthesized in a silica glass matrix by the sol-gel method at calcination temperatures of 700& circ; C and above. Compared with the parent material Si O2 , this nano-glass composite system shows enhancement of dielectric constant and diffuse phase transition along with magnetodielectric effect around room temperature. Observed conduction mechanism is found to be closely related to the thermally activated oxygen vacancies. Magnetodielectric behavior is strongly associated with magnetoresistance changes, depending on the nanoparticle size and separation. Such a material might be treated as a potential candidate for device miniaturization.

The Effect of Temperature on Faceplate/Core Delamination in Composite/Titanium Sandwich Plates

NASA Technical Reports Server (NTRS)

Liechti, Kenneth M.; Marton, Balazs

2000-01-01

A study was made of the delamination behavior of sandwich beams made of titanium core bonded to face-plates that consisted of carbon fiber reinforced polymer composite. Nominally mode I behavior was considered at 23C and 180C, by making use of a specially reinforced double cantilever (DCB) specimens. The toughness of the bond between the faceplate and the core was determined on the basis of a beam on elastic foundation analysis. The specimen compliance, and toughness were all independent of temperature in these relatively short-term experiments. The fracture mechanism showed temperature dependence, due to the hygrothermal sensitivity of the adhesive.

Fabrication and Mechanical Behavior of Ex Situ Mg-Based Bulk Metallic Glass Matrix Composite Reinforced with Electroless Cu-Coated SiC Particles.

PubMed

Wang, Xin; Zhao, Lichen; Hu, Ximei; Cheng, Yongjian; Liu, Shuiqing; Chen, Peng; Cui, Chunxiang

2017-11-30

Magnesium-based bulk metallic glass matrix composites (BMGMCs) have better plasticity than the corresponding bulk metallic glasses (BMGs); however, their strength and density are often compromised due to the fact that the effective reinforcement phase is mostly plastic heavy metal. For lightweight SiC-particle reinforced BMGMCs, interface wettability and the sharpness of the particles often reduce the strengthening effect. In this work, SiC particles were coated with a thin Cu coating by electroless plating, and added to Mg 54 Cu 26.5 Ag 8.5 Gd 11 melt in an amount of 5 wt % to prepare a BMGMC. The microstructure of the interface, mechanical behavior and fracture morphology of the BMGMC were studied by scanning electron microscopy and quasi-static compression testing. The results showed that the Cu coating improved the wettability between SiC and the matrix alloy without obvious interfacial reactions, leading to the dispersion of SiC particles in the matrix. The addition of Cu-coated SiC particles improved the plastic deformation ability of Mg 54 Cu 26.5 Ag 8.5 Gd 11 BMG, proving that electroless plating was an effective method for controlling the interface microstructure and mechanical behavior of BMGMCs.

Effect of SiO2 addition on photocatalytic activity, water contact angle and mechanical stability of visible light activated TiO2 thin films applied on stainless steel by a sol gel method

NASA Astrophysics Data System (ADS)

Momeni, Mansour; Saghafian, Hasan; Golestani-Fard, Farhad; Barati, Nastaran; Khanahmadi, Amirhossein

2017-01-01

Nanostructured N doped TiO2/20%SiO2 thin films were developed on steel surface via sol gel method using a painting airbrush. Thin films then were calcined at various temperatures in a range of 400-600 °C. The effect of SiO2 addition on phase composition and microstructural evolution of N doped TiO2 films were studied using XRD and FESEM. Optical properties, visible light photocatalytic activity, hydrophilic behavior, and mechanical behavior of the films were also investigated by DRS, methylene blue degradation, water contact angle measurements, and nanoscratch testing. Results indicated that the band gap energy of N doped TiO2/SiO2 was increased from 2.93 to 3.09 eV. Crack formation during calcination was also significantly promoted in the composite films. All composite films demonstrated weaker visible light photocatalytic activities and lower mechanical stability in comparison with N doped TiO2 films. Moreover, the N doped TiO2/SiO2 film calcined at 600 °C showed undesirable hydrophilic behavior with a water contact angle of 57° after 31 h of visible light irradiation. Outcomes of the present study reveal some different results to previous reports on TiO2/SiO2 films. In general, we believe the differences in substrate material as well as application in visible light are the main reasons for the above mentioned contradiction.

Predictions of High Strain Rate Failure Modes in Layered Aluminum Composites

NASA Astrophysics Data System (ADS)

Khanikar, Prasenjit; Zikry, M. A.

2014-01-01

A dislocation density-based crystalline plasticity formulation, specialized finite-element techniques, and rational crystallographic orientation relations were used to predict and characterize the failure modes associated with the high strain rate behavior of aluminum layered composites. Two alloy layers, a high strength alloy, aluminum 2195, and an aluminum alloy 2139, with high toughness, were modeled with representative microstructures that included precipitates, dispersed particles, and different grain boundary distributions. Different layer arrangements were investigated for high strain rate applications and the optimal arrangement was with the high toughness 2139 layer on the bottom, which provided extensive shear strain localization, and the high strength 2195 layer on the top for high strength resistance The layer thickness of the bottom high toughness layer also affected the bending behavior of the roll-bonded interface and the potential delamination of the layers. Shear strain localization, dynamic cracking, and delamination are the mutually competing failure mechanisms for the layered metallic composite, and control of these failure modes can be used to optimize behavior for high strain rate applications.

A Progressive Damage Methodology for Residual Strength Predictions of Notched Composite Panels

NASA Technical Reports Server (NTRS)

Coats, Timothy W.; Harris, Charles E.

1998-01-01

The translaminate fracture behavior of carbon/epoxy structural laminates with through-penetration notches was investigated to develop a residual strength prediction methodology for composite structures. An experimental characterization of several composite materials systems revealed a fracture resistance behavior that was very similar to the R-curve behavior exhibited by ductile metals. Fractographic examinations led to the postulate that the damage growth resistance was primarily due to fractured fibers in the principal load-carrying plies being bridged by intact fibers of the adjacent plies. The load transfer associated with this bridging mechanism suggests that a progressive damage analysis methodology will be appropriate for predicting the residual strength of laminates with through-penetration notches. A progressive damage methodology developed by the authors was used to predict the initiation and growth of matrix cracks and fiber fracture. Most of the residual strength predictions for different panel widths, notch lengths, and material systems were within about 10% of the experimental failure loads.

Additive Manufacturing and Characterization of Polylactic Acid (PLA) Composites Containing Metal Reinforcements

NASA Technical Reports Server (NTRS)

Kuentz, Lily; Salem, Anton; Singh, M.; Halbig, M. C.; Salem, J. A.

2016-01-01

Additive manufacturing of polymeric systems using 3D printing has become quite popular recently due to rapid growth and availability of low cost and open source 3D printers. Two widely used 3D printing filaments are based on polylactic acid (PLA) and acrylonitrile butadiene styrene (ABS) systems. PLA is much more environmentally friendly in comparison to ABS since it is made from renewable resources such as corn, sugarcane, and other starches as precursors. Recently, polylactic acid-based metal powder containing composite filaments have emerged which could be utilized for multifunctional applications. The composite filaments have higher density than pure PLA, and the majority of the materials volume is made up of polylactic acid. In order to utilize functionalities of composite filaments, printing behavior and properties of 3-D printed composites need to be characterized and compared with the pure PLA materials. In this study, pure PLA and composite specimens with different metallic reinforcements (Copper, Bronze, Tungsten, Iron, etc) were 3D printed at various layer heights and resulting microstructures and properties were characterized. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) behavior of filaments with different reinforcements were studied. The microscopy results show an increase in porosity between 3-D printed regular PLA and the metal composite PLA samples, which could produce weaker mechanical properties in the metal composite materials. Tensile strength and fracture toughness behavior of specimens as a function of print layer height will be presented.

Tensile and fatigue behavior of polymer composites reinforced with superelastic SMA strands

NASA Astrophysics Data System (ADS)

Daghash, Sherif M.; Ozbulut, Osman E.

2018-06-01

This study explores the use of superelastic shape memory alloy (SMA) strands, which consist of seven individual small-diameter wires, in an epoxy matrix and characterizes the tensile and fatigue responses of the developed SMA/epoxy composites. Using a vacuum assisted hand lay-up technique, twelve SMA fiber reinforced polymer (FRP) specimens were fabricated. The developed SMA-FRP composites had a fiber volume ratio of 50%. Tensile response of SMA-FRP specimens were characterized under both monotonic loading and increasing amplitude loading and unloading cycles. The degradation in superelastic properties of the developed SMA-FRP composites during fatigue loading at different strain amplitudes was investigated. The effect of loading rate on the fatigue response of SMA-FRP composites was also explored. In addition, fractured specimens were examined using the scanning electron microscopy (SEM) technique to study the failure mechanisms of the tested specimens. A good interfacial bonding between the SMA strands and epoxy matrix was observed. The developed SMA-FRP composites exhibited good superelastic behavior at different strain amplitudes up to at least 800 cycle after which significant degradation occurred.

A Numerical Solution Routine for Investigating Oxidation-Induced Strength Degradation Mechanisms in SiC/SiC Composites

NASA Technical Reports Server (NTRS)

Sullivan, Roy M.

2015-01-01

The stress rupture strength of silicon carbide fiber-reinforced silicon carbide (SiCSiC) composites with a boron nitride (BN) fiber coating decreases with time within the intermediate temperature range of 700-950 C. Various theories have been proposed to explain the cause of the time dependent stress rupture strength. Some previous authors have suggested that the observed composite strength behavior is due to the inherent time dependent strength of the fibers, which is caused by the slow growth of flaws within the fibers. Flaw growth is supposedly enabled by oxidation of free carbon at the grain boundaries. The objective of this paper is to investigate the relative significance of the various theories for the time-dependent strength of SiCSiC composites. This is achieved through the development of a numerically-based progressive failure analysis routine and through the application of the routine to simulate the composite stress rupture tests. The progressive failure routine is a time marching routine with an iterative loop between a probability of fiber survival equation and a force equilibrium equation within each time step. Failure of the composite is assumed to initiate near a matrix crack and the progression of fiber failures occurs by global load sharing. The probability of survival equation is derived from consideration of the strength of ceramic fibers with randomly occurring and slow growing flaws as well as the mechanical interaction between the fibers and matrix near a matrix crack. The force equilibrium equation follows from the global load sharing presumption. The results of progressive failure analyses of the composite tests suggest that the relationship between time and stress-rupture strength is attributed almost entirely to the slow flaw growth within the fibers. Although other mechanisms may be present, they appear to have only a minor influence on the observed time dependent behavior.

Mechanical properties of moso bamboo treated with chemical agents

Treesearch

Benhua Fei; Zhijia Liu; Zehui Jiang; Zhiyong Cai

2013-01-01

Bamboo is a type of biomass material and has great potential as a bioenergy resource for the future in China. Surface chemical and thermal–mechanical behavior play an important role in the manufacturing process of bamboo composites and pellets. In this study, moso bamboo was treated by sodium hydrate solution and acetic acid solution. Surface chemical and dynamic...

Predicting the viscosity of solids using steady-state creep behavior of the fibrous composites semi-theoretically

NASA Astrophysics Data System (ADS)

Monfared, Vahid

A semi-analytical formulation is presented for obtaining the viscosity of solids (such as metals) using the steady state creep model of the short-fiber composites. For achieving this aim, fluid mechanics theory is used for determining the viscosity. Sometimes, obtaining the viscosity is experimentally difficult and intricate. So, the present model may be beneficial to obtain the viscosity of metals.

Thermomechanical Fatigue Behavior of a Silicone Carbide Fiber-Reinforced Calcium Aluminosilicate Glass-Ceramic Matrix Composite

DTIC Science & Technology

1991-01-01

Fibers," Journal of Materials Science Letters, Chapman & Hall, Ltd., London, England, 2, [9], 1983, pp. 80-82. Wang, S-W, and Parvizi- Majidi , A...cross-plied [0/9012s material and found behavior similar to that seen by Rousseau, and Wang & Parvizi- Majidi . 17 References - CHAPTER I1: BACKGROUND...eds., American Society for Testing and Materials, Philadelphia, PA, 1990, pp. 136-151. 63 Wang, S-W, and Parvizi- Majidi , A., "Mechanical Behavior of

Fabrication and mechanical evaluation of hydroxyapatite/oxide nano-composite materials.

PubMed

Mohamed, Khaled R; Beherei, Hanan H; El Bassyouni, Gehan T; El Mahallawy, Nahed

2013-10-01

In the current study, the semiconducting metal oxides such as nano-ZnO and SiO2 powders were prepared via sol-gel technique and conducted on nano-hydroxyapatite (nHA) which was synthesized by chemical precipitation. The properties of fabricated nano-structured composites containing different ratios of HA, ZnO and SiO2 were examined using X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscope (SEM) and transmission electron microscope (TEM) techniques. The effect of the variation of ratios between the three components on mechanical, microstructure and in-vitro properties was assessed to explore the possibility of enhancing these properties. The results proved that the mechanical properties exhibited an increment with increasing the ZnO content at the extent of HA. In-vitro study proved the formation and nucleation of apatite onto the surface of the fabricated composites after one week of immersion. It is concluded that HA composites containing SiO2 or SiO2/ZnO content had a suitable mechanical properties and ability to form apatite particles onto the composite surface. Based on bioactivity behavior, Si-HA is more bioactive than pure hydroxyapatite and nano-arrangements will provide an interface for better bone formation. Therefore, these nano-composites will be promising as bone substitutes especially in load bearing sites. Copyright © 2013 Elsevier B.V. All rights reserved.

A Study of Flexible Composites for Expandable Space Structures

NASA Technical Reports Server (NTRS)

Scotti, Stephen J.

2016-01-01

Payload volume for launch vehicles is a critical constraint that impacts spacecraft design. Deployment mechanisms, such as those used for solar arrays and antennas, are approaches that have successfully accommodated this constraint, however, providing pressurized volumes that can be packaged compactly at launch and expanded in space is still a challenge. One approach that has been under development for many years is to utilize softgoods - woven fabric for straps, cloth, and with appropriate coatings, bladders - to provide this expandable pressure vessel capability. The mechanics of woven structure is complicated by a response that is nonlinear and often nonrepeatable due to the discrete nature of the woven fiber architecture. This complexity reduces engineering confidence to reliably design and certify these structures, which increases costs due to increased requirements for system testing. The present study explores flexible composite materials systems as an alternative to the heritage softgoods approach. Materials were obtained from vendors who utilize flexible composites for non-aerospace products to determine some initial physical and mechanical properties of the materials. Uniaxial mechanical testing was performed to obtain the stress-strain response of the flexible composites and the failure behavior. A failure criterion was developed from the data, and a space habitat application was used to provide an estimate of the relative performance of flexible composites compared to the heritage softgoods approach. Initial results are promising with a 25% mass savings estimated for the flexible composite solution.

Manipulation of mechanical compliance of elastomeric PGS by incorporation of halloysite nanotubes for soft tissue engineering applications.

PubMed

Chen, Qi-Zhi; Liang, Shu-Ling; Wang, Jiang; Simon, George P

2011-11-01

Poly (glycerol sebacate) (PGS) is a promising elastomer for use in soft tissue engineering. However, it is difficult to achieve with PGS a satisfactory balance of mechanical compliance and degradation rate that meet the requirements of soft tissue engineering. In this work, we have synthesised a new PGS nanocomposite system filled with halloysite nanotubes, and mechanical properties, as well as related chemical characters, of the nanocomposites were investigated. It was found that the addition of nanotubular halloysite did not compromise the extensibility of material, compared with the pure PGS counterpart; instead the elongation at rupture was increased from 110 (in the pure PGS) to 225% (in the 20 wt% composite). Second, Young's modulus and resilience of 3-5 wt% composites were ∼0.8 MPa and >94% respectively, remaining close to the level of pure PGS which is desired for applications in soft tissue engineering. Third, an important feature of the 1-5 wt% composites was their stable mechanical properties over an extended period, which could allow the provision of reliable mechanical support to damaged tissues during the lag phase of the healing process. Finally, the in vitro study indicated that the addition of halloysite slowed down the degradation rate of the composites. In conclusion, the good compliance, enhanced stretchability, stable mechanical behavior over an extended period, and reduced degradation rates make the 3-5 wt% composites promising candidates for application in soft tissue engineering. Copyright © 2011 Elsevier Ltd. All rights reserved.

Structural and electronic properties of carbon nanotube-reinforced epoxy resins.

PubMed

Suggs, Kelvin; Wang, Xiao-Qian

2010-03-01

Nanocomposites of cured epoxy resin reinforced by single-walled carbon nanotubes exhibit a plethora of interesting behaviors at the molecular level. We have employed a combination of force-field-based molecular mechanics and first-principles calculations to study the corresponding binding and charge-transfer behavior. The simulation study of various nanotube species and curing agent configurations provides insight into the optimal structures in lieu of interfacial stability. An analysis of charge distributions of the epoxy functionalized semiconducting and metallic tubes reveals distinct level hybridizations. The implications of these results for understanding dispersion mechanism and future nano reinforced composite developments are discussed.

Improvement of mechanical behaviors of a superlight Mg-Li base alloy by duplex phases and fine precipitates

DOE PAGES

Zou, Yun; Zhang, Lehao; Li, Yang; ...

2017-12-06

Limitations of strength and formability are the major obstacles to the industrial application of magnesium alloys. Here, we demonstrate, by producing the duplex phases and fine intermetallic particles in composition-optimized superlight Mg-Li-Al alloys, a unique approach to simultaneously improve the comprehensive mechanical properties (a strength-ductility balance). In conclusion, the phase components and microstructures, including the size, morphology, and distribution of precipitated-intermetallic particles can be optimized by tuning the Li content, which strongly influences the work-hardening behavior and tension-compression yield asymmetry.

Entanglement revive and information flow within the decoherent environment.

PubMed

Shi, Jia-Dong; Wang, Dong; Ye, Liu

2016-08-10

In this paper, the dynamics of entanglement is investigated in the presence of a noisy environment. We reveal its revival behavior and probe the mechanisms of this behavior via an information-theoretic approach. By analyzing the correlation distribution and the information flow within the composite system including the qubit subsystem and a noisy environment, it has been found that the subsystem-environment coupling can induce the quasi-periodic entanglement revival. Furthermore, the dynamical relationship among tripartite correlations, bipartite entanglement and local state information is explored, which provides a new insight into the non-Markovian mechanisms during the evolution.

Application-Oriented Chemical Optimization of a Metakaolin Based Geopolymer

PubMed Central

Ferone, Claudio; Colangelo, Francesco; Roviello, Giuseppina; Asprone, Domenico; Menna, Costantino; Balsamo, Alberto; Prota, Andrea; Cioffi, Raffaele; Manfredi, Gaetano

2013-01-01

In this study the development of a metakaolin based geopolymeric mortar to be used as bonding matrix for external strengthening of reinforced concrete beams is reported. Four geopolymer formulations have been obtained by varying the composition of the activating solution in terms of SiO2/Na2O ratio. The obtained samples have been characterized from a structural, microstructural and mechanical point of view. The differences in structure and microstructure have been correlated to the mechanical properties. A major issue of drying shrinkage has been encountered in the high Si/Al ratio samples. In the light of the characterization results, the optimal geopolymer composition was then applied to fasten steel fibers to reinforced concrete beams. The mechanical behavior of the strengthened reinforced beams was evaluated by four-points bending tests, which were performed also on reinforced concrete beams as they are for comparison. The preliminary results of the bending tests point out an excellent behavior of the geopolymeric mixture tested, with the failure load of the reinforced beams roughly twice that of the control beam. PMID:28809251

Effects of fiber/matrix interactions on the properties of graphite/epoxy composites

NASA Technical Reports Server (NTRS)

Mcmahon, P. E.; Ying, L.

1982-01-01

A state-of-the-art literature review of the interactions between fibers and resin within graphite epoxy composite materials was performed. Emphasis centered on: adhesion theory; wetting characteristics of carbon fiber; load transfer mechanisms; methods to evaluate and measure interfacial bond strengths; environmental influence at the interface; and the effect of the interface/interphase on composite performance, with particular attention to impact toughness. In conjunction with the literature review, efforts were made to design experiments to study the wetting behavior of carbon fibers with various finish variants and their effect on adhesion joint strength. The properties of composites with various fiber finishes were measured and compared to the base-line properties of a control. It was shown that by tailoring the interphase properties, a 30% increase in impact toughness was achieved without loss of mechanical properties at both room and elevated temperatures.

Assessment of nanoscopic dynamic mechanical properties and B-C-N triad effect on MWCNT/h-BNNP nanofillers reinforced HDPE hybrid composite using oscillatory nanoindentation: An insight into medical applications.

PubMed

Badgayan, Nitesh Dhar; Sahu, Santosh Kumar; Samanta, Sutanu; Rama Sreekanth, P S

2018-04-01

A thrust on improvement of different properties of polymer has taken a contemporary route with advent of nanofillers. Although several nanofillers are existent; MultiWalled Carbon Nanotubes- (MWCNTs) and h-Boron Nitride nanoplatelets-(h-BNNPs) unique combination of 1D and 2D dimensional geometry aids an advantage of B-C-N triad elemental effects on properties of tested samples. The current study aims to investigate the effects of MWCNT and h-BNNP reinforcement in High Density Polyethylene (HDPE) for high load bearing areas of medical applications requiring both elastic and viscous behavior. The results were analyzed keeping a view of its application in areas like HDPE based fracture fixation plates, acetabular cups and others. The composite and hybrid samples with different loadings were prepared after surface modification of nanofillers by mechanical mixing and molding technique. The dynamic nano-mechanical properties like storage modulus, loss modulus and tan delta were assessed for each sample during frequency swept from 10 to 220 Hz. The viscoelastic properties like h c /h m , H/E, elastic-plastic deformation were investigated and evaluated. At a frequency of 10 Hz, the storage and loss modulus of 0.1 CNT increased by 37.56% and decreased by 23.52% respectively on comparison with pure HDPE. This infers a good elastic as well as viscous behavior. Overall elastic behavior of 0.1 CNT was confirmed from tan delta evaluation. The interaction between B-C-N elemental triad had significant effect on creep strength, visco-damping property (h c /h m and H/E), elastic plastic displacement and pile-up and sink-in behavior. Highest creep strength and visco-damping property was exhibited by 0.25 CNT/0.15 BNNP hybrid. The elastic-plastic displacement of hybrid composite was noted as least, which decreased by 30% on comparison with pure HDPE. It can be inferred that presence of 1D-MWCNT and 2D-h-BNNP had significant effect on important dynamic viscoelastic and creep properties of HDPE based hybrid composites. Copyright © 2018 Elsevier Ltd. All rights reserved.

Multiscale Modeling of Novel Carbon Nanotube/Copper-Composite Material Used in Microelectronics

NASA Astrophysics Data System (ADS)

Awad, Ibrahim; Ladani, Leila

2016-06-01

Current carrying capacity is one of the elements that hinders further miniaturization of Copper (Cu) interconnects. Therefore, there is a need to propose new materials with higher ampacity (current carrying capacity) that have the potential to replace Cu. Experimental observations have shown that Carbon Nanotube (CNT)/Cu-composite material has a hundredfold ampacity of Cu, which makes it a good candidate to replace Cu. However, sufficient information about the mechanical behavior of the novel CNT/Cu-composite is not available. In the current paper, the CNT/Cu-composite is utilized to construct Through Silicon Via (TSV). The mechanical behavior, specifically the fatigue life, of the CNT/Cu-TSV is evaluated by applying a multiscale modeling approach. Molecular Dynamics (MD) simulations are conducted to evaluate the tensile strength and the coefficient of thermal expansion of CNTs. MD simulation is also used to determine the interface behavior between CNTs and Cu. MD simulation results are integrated into Finite Element analysis at the micro-level to estimate the fatigue life of the CNT/Cu-TSV. A comparison is made with base material; Cu. CNTs addition has redistributed the plastic deformation in Cu to occur at two different locations (Si/Cu interface and Cu/CNT interface) instead of only one location (Si/Cu interface) in the case of Cu-only-TSV. Thus, the maximum equivalent plastic strain has been alleviated in the CNT/Cu-TSV. Accordingly, CNT/Cu-TSV has shown a threefold increase in the fatigue life. This is a solid indication of the improvement in the fatigue life that is attributed to the addition of CNTs.

Mechanical behavior of bulk direct composite versus block composite and lithium disilicate indirect Class II restorations by CAD-FEM modeling.

PubMed

Ausiello, Pietro; Ciaramella, Stefano; Fabianelli, Andrea; Gloria, Antonio; Martorelli, Massimo; Lanzotti, Antonio; Watts, David C

2017-06-01

To study the influence of resin based and lithium disilicate materials on the stress and strain distributions in adhesive class II mesio-occlusal-distal (MOD) restorations using numerical finite element analysis (FEA). To investigate the materials combinations in the restored teeth during mastication and their ability to relieve stresses. One 3D model of a sound lower molar and three 3D class II MOD cavity models with 95° cavity-margin-angle shapes were modelled. Different material combinations were simulated: model A, with a 10μm thick resin bonding layer and a resin composite bulk filling material; model B, with a 70μm resin cement with an indirect CAD-CAM resin composite inlay; model C, with a 70μm thick resin cement with an indirect lithium disilicate machinable inlay. To simulate polymerization shrinkage effects in the adhesive layers and bulk fill composite, the thermal expansion approach was used. Shell elements were employed for representing the adhesive layers. 3D solid CTETRA elements with four grid points were employed for modelling the food bolus and tooth. Slide-type contact elements were used between the tooth surface and food. A vertical occlusal load of 600 N was applied, and nodal displacements on the bottom cutting surfaces were constrained in all directions. All the materials were assumed to be isotropic and elastic and a static linear analysis was performed. Displacements were different in models A, B and C. Polymerization shrinkage hardly affected model A and mastication only partially affected mechanical behavior. Shrinkage stress peaks were mainly located marginally along the enamel-restoration interface at occlusal and mesio-distal sites. However, at the internal dentinal walls, stress distributions were critical with the highest maximum stresses concentrated in the proximal boxes. In models B and C, shrinkage stress was only produced by the 70μm thick resin layer, but the magnitudes depended on the Young's modulus (E) of the inlay materials. Model B mastication behavior (with E=20GPa) was similar to the sound tooth stress relief pattern. Model B internally showed differences from the sound tooth model but reduced maximum stresses than model A and partially than model C. Model C (with E=70GPa) behaved similarly to model B with well redistributed stresses at the occlusal margins and the lateral sides with higher stress concentrations in the proximal boxes. Models B and C showed a more favorable performance than model A with elastic biomechanics similar to the sound tooth model. Bulk filling resin composite with 1% linear polymerization shrinkage negatively affected the mechanical behavior of class II MOD restored teeth. Class II MOD direct resin composite showed greater potential for damage because of higher internal and marginal stress evolution during resin polymerization shrinkage. With a large class II MOD cavity an indirect composite or a lithium disilicate inlay restoration may provide a mechanical response close to that of a sound tooth. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Growth Kinetics of Magnesio-Aluminate Spinel in Al/Mg Lamellar Composite Interface

NASA Astrophysics Data System (ADS)

Fouad, Yasser; Rabeeh, Bakr Mohamed

The synthesis of Mg-Al2O3 double layered interface is introduced via the application of hot isostatic pressing, HIPing, in Al-Mg foils. Polycrystalline spinel layers are grown experimentally at the interfacial contacts between Al-Mg foils. The growth behavior of the spinel layers along with the kinetic parameters characterizing interface motion and long-range diffusion is established. Low melting depressant (LMD), Zn, and alloying element segregation tends to form micro laminated and/or Nano structure interphase in a lamellar composite solid state processing. Nano composite ceramic interphase materials offer interesting mechanical properties not achievable in other materials, such as superplastic flow and metal-like machinability. Microstructural characterization, mechanical characterization is also established via optical microscopy scanning electron microscopy, energy dispersive X-ray spectroscopy and tensile testing. Chemical and mechanical bonding via inter diffusion processing with alloy segregation are dominant for interphase kinetics. Mechanical characterization with interfacial shear strength is also introduced. HIPing processing is successfully applied on 6082 Al-alloy and AZ31 magnesium alloy for either particulate or micro-laminated interfacial composite processing. The interphase kinetic established through localized micro plasticity, metal flow, alloy segregation and delocalized Al oxide and Mg oxide. The kinetic of interface/interphase induce new nontraditional crack mitigation a long with new bridging and toughening mechanisms.

Mechanical behavior of bioactive composite cements consisting of resin and glass-ceramic powder in a simulated body fluid: effect of silane coupling agent.

PubMed

Miyata, N; Matsuura, W; Kokubo, T; Nakamura, T

2004-09-01

Time-dependent strength behavior was investigated for bisphenol-a-glycidyl methacrylate/triethylene glycol dimethacrylate (Bis-GMA/TEGDMA) resin cements combined with glass-ceramic A-W filler treated with various kinds of silane coupling agents. The fracture strength of the composite resin cements was measured by three-point bending as a function of stressing rate in a simulated body fluid (SBF), and thereby the stress-corrosion susceptibility constant was evaluated. The fracture strength was found to depend on the kind of coupling agent used. For the present Bis-GMA/TEGDMA resin, the silane coupling agents without hydrophilic amine groups can be used to obtain good adhesion between resin and A-W filler owing to their nature of co-polymerizing with the resin. On the other hand, all the composite resin cements showed nearly the same degree of stress-corrosion susceptibility whether the A-W fillers were treated or untreated with silane coupling agents. This means that the stress-corrosion susceptibility of the present composite cements is predominantly affected by that of the matrix resin. Thus, the microcrack formation and growth at the resin matrix near particle - resin interface were thought to determine overall time-dependent strength behavior of the composite cements.

A mesoporous silica composite scaffold: Cell behaviors, biomineralization and mechanical properties

NASA Astrophysics Data System (ADS)

Xu, Yong; Gao, Dan; Feng, Pei; Gao, Chengde; Peng, Shuping; Ma, HaoTian; Yang, Sheng; Shuai, Cijun

2017-11-01

Mesoporous structure is beneficial to cellular response due to the large specific surface area and high pore volume. In this study, mesoporous silica (SBA15) was incorporated into poly-L-lactic acid (PLLA) to construct composite scaffold by selective laser sintering. The results showed that SBA15 facilitated cells proliferation, which was mainly attributed to its unique intrinsic mesoporous structure and the released bioactive silicon. Moreover, the hydrolyzate of soluble mesoporous silica can adsorb ions to form nucleation sites that promote biomineralization, leading to improve biological activity of the composite scaffold. In addition, the compressive strength, compressive modulus and Vickers hardness of the scaffold were increased by 47.6%, 35.5% and 29.53% respectively with 1.5 wt.% SBA15. It was found that the particle enhancement of uniform distributed SBA15 accounted for the mechanic reinforcement of the composite scaffold. It indicated that the PLLA-SBA15 composite scaffold had potential applications in bone tissue engineering.

Poly(vinylidene fluoride)/ CaCu{sub 3}Ti{sub 4}O{sub 12} and La doped CaCu{sub 3}Ti{sub 4}O{sub 12} composites with improved dielectric and mechanical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Srivastava, Anshuman; Jana, Karun Kumar; Maiti, Pralay

2015-10-15

Highlights: • High ϵ′ PVDF/CCTO and La doped CCTO composites prepared by Extrusion. • With addition of ceramic, there is substantial increase in the ϵ′ of matrix PVDF. • Composites exhibit double relaxation behavior. - Abstract: Melt extrusion process has been used to prepare high relative permittivity, ϵ' PVDF–CCTO and PVDF–LaCCTO composites. Phase composition has been studied using powder X-ray diffraction (XRD). Microstructural, dielectric and mechanical properties have also been studied. Young's modulus of PVDF increases with the ceramic reinforcement. Dielectric measurements are made in the frequency range 10{sup −2}–10{sup 6} Hz using two probe Novocontrol impedance analyser (ZG4) frommore » room temp to 120 °C to study the dielectric relaxation. There is a substantial increase in ϵ' of the matrix PVDF on addition of LaCCTO.« less

Performance of mechanical behavior of kenaf fibre reinforced foamed composite

NASA Astrophysics Data System (ADS)

Mahzabin, Mst. Sadia; Hock, Lim Jee; Kang, Lim Siong; Jarghouyeh, Ehsan Nikbakht

2017-10-01

This paper investigates the mechanical properties of lightweight foamed composite (LFC) with the inclusion of kenaf fibres and superplasticizer. NaOH treated kenaf fibre contents of 0.4%, 0.45% and 0.5% (by weight of cement) with 5cm length were used in composite. The density of 1000kg/m3 to 2000kg/m3 foamed concrete was used for all the tested specimens. The ratio of cement, sand and water used was 1:1.5:0.45. All the experiments were set up in accordance with International standard methods of testing. In reference to the results and discussion, the different percentages of fibre used were proven to have a lesser contribution towards compressive strength or might even have reduced the result. The results also showed that water absorption and density of the composite mortar increased as the volume of fiber increased from 0.4% to 0.5% However, a higher percentage of fiber inclusions had been recorded to have a positive contribution towards flexural and tensile splitting properties of composites.

A combined analytical formulation and genetic algorithm to analyze the nonlinear damage responses of continuous fiber toughened composites

NASA Astrophysics Data System (ADS)

Jeon, Haemin; Yu, Jaesang; Lee, Hunsu; Kim, G. M.; Kim, Jae Woo; Jung, Yong Chae; Yang, Cheol-Min; Yang, B. J.

2017-09-01

Continuous fiber-reinforced composites are important materials that have the highest commercialized potential in the upcoming future among existing advanced materials. Despite their wide use and value, their theoretical mechanisms have not been fully established due to the complexity of the compositions and their unrevealed failure mechanisms. This study proposes an effective three-dimensional damage modeling of a fibrous composite by combining analytical micromechanics and evolutionary computation. The interface characteristics, debonding damage, and micro-cracks are considered to be the most influential factors on the toughness and failure behaviors of composites, and a constitutive equation considering these factors was explicitly derived in accordance with the micromechanics-based ensemble volume averaged method. The optimal set of various model parameters in the analytical model were found using modified evolutionary computation that considers human-induced error. The effectiveness of the proposed formulation was validated by comparing a series of numerical simulations with experimental data from available studies.

Laser Cladding of Composite Bioceramic Coatings on Titanium Alloy

NASA Astrophysics Data System (ADS)

Xu, Xiang; Han, Jiege; Wang, Chunming; Huang, Anguo

2016-02-01

In this study, silicon nitride (Si3N4) and calcium phosphate tribasic (TCP) composite bioceramic coatings were fabricated on a Ti6Al4V (TC4) alloy using Nd:YAG pulsed laser, CO2 CW laser, and Semiconductor CW laser. The surface morphology, cross-sectional microstructure, mechanical properties, and biological behavior were carefully investigated. These investigations were conducted employing scanning electron microscope, energy-dispersive x-ray spectroscopy, and other methodologies. The results showed that both Si3N4 and Si3N4/TCP composite coatings were able to form a compact bonding interface between the coating and the substrate by using appropriate laser parameters. The coating layers were dense, demonstrating a good surface appearance. The bioceramic coatings produced by laser cladding have good mechanical properties. Compared with that of the bulk material, microhardness of composite ceramic coatings on the surface significantly increased. In addition, good biological activity could be obtained by adding TCP into the composite coating.

Microstructure and Mechanical Behavior of Microwave Sintered Cu50Ti50 Amorphous Alloy Reinforced Al Metal Matrix Composites

NASA Astrophysics Data System (ADS)

Reddy, M. Penchal; Ubaid, F.; Shakoor, R. A.; Mohamed, A. M. A.

2018-06-01

In the present work, Al metal matrix composites reinforced with Cu-based (Cu50Ti50) amorphous alloy particles synthesized by ball milling followed by a microwave sintering process were studied. The amorphous powders of Cu50Ti50 produced by ball milling were used to reinforce the aluminum matrix. They were examined by x-ray diffraction (XRD), scanning electron microscopy (SEM), microhardness and compression testing. The analysis of XRD patterns of the samples containing 5 vol.%, 10 vol.% and 15 vol.% Cu50Ti50 indicates the presence of Al and Cu50Ti50 peaks. SEM images of the sintered composites show the uniform distribution of reinforced particles within the matrix. Mechanical properties of the composites were found to increase with an increasing volume fraction of Cu50Ti50 reinforcement particles. The hardness and compressive strength were enhanced to 89 Hv and 449 MPa, respectively, for the Al-15 vol.% Cu50Ti50 composites.

Resistive switching characteristics and mechanisms in silicon oxide memory devices

NASA Astrophysics Data System (ADS)

Chang, Yao-Feng; Fowler, Burt; Chen, Ying-Chen; Zhou, Fei; Wu, Xiaohan; Chen, Yen-Ting; Wang, Yanzhen; Xue, Fei; Lee, Jack C.

2016-05-01

Intrinsic unipolar SiOx-based resistance random access memories (ReRAM) characterization, switching mechanisms, and applications have been investigated. Device structures, material compositions, and electrical characteristics are identified that enable ReRAM cells with high ON/OFF ratio, low static power consumption, low switching power, and high readout-margin using complementary metal-oxide semiconductor transistor (CMOS)-compatible SiOx-based materials. These ideas are combined with the use of horizontal and vertical device structure designs, composition optimization, electrical control, and external factors to help understand resistive switching (RS) mechanisms. Measured temperature effects, pulse response, and carrier transport behaviors lead to compact models of RS mechanisms and energy band diagrams in order to aid the development of computer-aided design for ultralarge-v scale integration. This chapter presents a comprehensive investigation of SiOx-based RS characteristics and mechanisms for the post-CMOS device era.

NASA-UVA Light Aerospace Alloy and Structures Technology Program (LA2ST)

NASA Technical Reports Server (NTRS)

Scully, John R.; Shiflet, Gary J.; Stoner, Glenn E.; Wert, John A.

1996-01-01

The NASA-UVA Light Aerospace Alloy and Structures Technology (LA2ST) Program was initiated in 1986 and continues with a high level of activity. The objective of the LA2ST Program is to conduct interdisciplinary graduate student research on the performance of next generation, light-weight aerospace alloys, composites and thermal gradient structures in collaboration with NASA-Langley researchers. Specific technical objectives are presented for each research project. We generally aim to produce relevant data and basic understanding of material mechanical response, environmental/corrosion behavior, and microstructure; new monolithic and composite alloys; advanced processing methods; new solid and fluid mechanics analyses; measurement and modeling advances; and a pool of educated graduate students for aerospace technologies. Three research areas are being actively investigated, including: (1) Mechanical and environmental degradation mechanisms in advanced light metals, (2) Aerospace materials science, and (3) Mechanics of materials for light aerospace structures.

The Assessing of the Failure Behavior of Glass/Polyester Composites Subject to Quasi Static Stresses

NASA Astrophysics Data System (ADS)

Stanciu, M. D.; Savin, A.; Teodorescu-Drăghicescu, H.

2017-06-01

Using glass fabric reinforced composites for structure of wind turbine blades requires high mechanical strengths especially to cyclic stresses. Studies have shown that approximately 50% of composite material failure occurs because of fatigue. Composites behavior to cyclic stresses involves three stages regarding to stiffness variation: the first stage is characterized by the accelerated decline of stiffness with micro-cracks, the second stage - a slight decrease of stiffness characterized by the occurrence of delamination and third stage characterized by higher decreases of resistance and occurrence of fracture thereof. The aim of the paper is to analyzed the behavior of composites reinforced with glass fibers fabric type RT500 and polyester resin subjected to tensile cyclic loading with pulsating quasi-static regime with asymmetry coefficient R = 0. The samples were tested with the universal tensile machine LS100 Lloyd Instruments Plus, with a load capacity of 100 kN. The load was applied with different speeds of 1 mm/min, 10 mm/min and 20 mm/min. After tests, it was observed that the greatest permanent strains were recorded in the first load cycles when the total energy storage by material was lost due to internal friction. With increasing number of cycles, the glass/polyester composites ability to store energy of deformation decreases, the flow phenomenon characterized by large displacements to smaller loading forces appearing.

In situ synchrotron high-energy X-ray diffraction study of microscopic deformation behavior of a hard-soft dual phase composite containing phase transforming matrix

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Junsong; Hao, Shijie; Jiang, Daqiang

This study explored a novel intermetallic composite design concept based on the principle of lattice strain matching enabled by the collective atomic load transfer. It investigated the hard-soft microscopic deformation behavior of a Ti3Sn/TiNi eutectic hard-soft dual phase composite by means of in situ synchrotron high-energy X-ray diffraction (HE-XRD) during compression. The composite provides a unique micromechanical system with distinctive deformation behaviors and mechanisms from the two components, with the soft TiNi matrix deforming in full compliance via martensite variant reorientation and the hard Ti3Sn lamellae deforming predominantly by rigid body rotation, producing a crystallographic texture for the TiNi matrixmore » and a preferred alignment for the Ti3Sn lamellae. HE-XRD reveals continued martensite variant reorientation during plastic deformation well beyond the stress plateau of TiNi. The hard and brittle Ti3Sn is also found to produce an exceptionally large elastic strain of 1.95% in the composite. This is attributed to the effect of lattice strain matching between the transformation lattice distortion of the TiNi matrix and the elastic strain of Ti3Sn lamellae. With such unique micromechanic characteristics, the composite exhibits high strength and large ductility.« less

Facile synthesis of Fe3O4/C composites for broadband microwave absorption properties

NASA Astrophysics Data System (ADS)

Liu, Xiang; Ma, Yating; Zhang, Qinfu; Zheng, Zhiming; Wang, Lai-Sen; Peng, Dong-Liang

2018-07-01

Rod-like and flower-like Fe3O4/C composites were successfully synthesized via a facile approach in aqueous phase. The morphologies, structures and static magnetic properties of as-prepared rod-like and flower-like Fe3O4/C composites were characterized thoroughly. The relative complex permittivity and permeability of Fe3O4/C/paraffin composites were recorded by a vector network analyzer (VNA) in the range of 1-18 GHz. The resonant-antiresonant electromagnetic behavior was observed simultaneously in both rod-like and flower-like Fe3O4/C composites. Moreover, the resonant-antiresonant behavior was explained using displacement current lag at the "core/shell" interface. The flower-like Fe3O4/C/paraffin composites show superior microwave absorption performance with minimum reflection loss (RL) of up to -18.73 dB at 15.37 GHz. Comparatively, the rod-like Fe3O4/C/paraffin composites have uncommon continuous trinal absorption peaks at a thickness of 2.5 mm that effectively broadens the absorption bandwidth which is from 8.0 to 13.4 GHz. Furthermore, the microwave absorption mechanism has been discussed to provide a novel design for microwave absorption materials.

Studies of Water Absorption Behavior of Plant Fibers at Different Temperatures

NASA Astrophysics Data System (ADS)

Saikia, Dip

2010-05-01

Moisture absorption of natural fiber plastic composites is one major concern in their outdoor applications. The absorbed moisture has many detrimental effects on the mechanical performance of these composites. A knowledge of the moisture diffusivity, permeability, and solubility is very much essential for the application of natural fibers as an excellent reinforcement in polymers. An effort has been made to study the water absorption behavior of some natural fibers such as bowstring hemp, okra, and betel nut at different temperatures to improve the long-term performance of composites reinforced with these fibers. The gain in moisture content in the fibers due to water absorption was measured as a function of exposure time at temperatures ranging from 300 K to 340 K. The thermodynamic parameters of the sorption process, such as diffusion coefficients and corresponding activation energies, were estimated.

Thermal-mechanical behavior of high precision composite mirrors

NASA Technical Reports Server (NTRS)

Kuo, C. P.; Lou, M. C.; Rapp, D.

1993-01-01

Composite mirror panels were designed, constructed, analyzed, and tested in the framework of a NASA precision segmented reflector task. The deformations of the reflector surface during the exposure to space enviroments were predicted using a finite element model. The composite mirror panels have graphite-epoxy or graphite-cyanate facesheets, separated by an aluminum or a composite honeycomb core. It is pointed out that in order to carry out detailed modeling of composite mirrors with high accuracy, it is necessary to have temperature dependent properties of the materials involved and the type and magnitude of manufacturing errors and material nonuniformities. The structural modeling and analysis efforts addressed the impact of key design and materials parameters on the performance of mirrors.

Progressive Fracture of Fiber Composite Builtup Structures

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Chamis, Christos C.; Minnetyan, Levon

1996-01-01

The damage progression and fracture of builtup composite structures was evaluated by using computational simulation to examine the behavior and response of a stiffened composite (0 +/- 45/90)(sub s6) laminate panel subjected to a bending load. The damage initiation, growth, accumulation, progression, and propagation to structural collapse were simulated. An integrated computer code (CODSTRAN) was augmented for the simulation of the progressive damage and fracture of builtup composite structures under mechanical loading. Results showed that damage initiation and progression have a significant effect on the structural response. Also investigated was the influence of different types of bending load on the damage initiation, propagation, and final fracture of the builtup composite panel.

C-Coupon Studies of CMCS: Fracture Behavior and Microstructural Characterization

NASA Technical Reports Server (NTRS)

Hurwitz, Frances I.; Calomino, Anthony M.; McCue, Terry R.; Abdul-Aziz, Ali

2001-01-01

A curved beam 'C-coupon' was used to assess fracture behavior in a Sylramic(tm)/melt infiltration (MI) SiC matrix composite. Failure stresses and fracture mechanisms, as determined by optical and scanning electron microstructural analysis, are compared with finite element stress calculations to analyze failure modes. Material microstructure was found to have a strong influence on mechanical behavior. Fracture occurs in interlaminar tension (ILT), provided that the ratio of ILT to tensile strength for the material is less than the ratio of radial to hoop stresses for the C-coupon geometry. Utilization of 3D architectures to improve interlaminar strength requires significant development efforts to incorporate through thickness fibers in regions with high curvatures while maintaining uniform thickness, radius, and microstructure.

Modeling of process-induced residual stresses and resin flow behavior in resin transfer molded composites with woven fiber mats

NASA Astrophysics Data System (ADS)

Golestanian, Hossein

This research focuses on modeling Resin Transfer Molding process for manufacture of composite parts with woven fiber mats. Models are developed to determine cure dependent stiffness matrices for composites manufactured with two types of woven fiber mats. Five-harness carbon and eight-harness fiberglass mats with EPON 826 resin composites are considered. The models presented here take into account important material/process parameters with emphasis on; (1) The effects of cure-dependent resin mechanical properties, (2) Fiber undulation due to the weave of the fiber fill and warp bundles, and (3) Resin interaction with the fiber bundles at a microscopic scale. Cure-dependent mechanical properties were then used in numerical models to determine residual stresses and deformation in the composite parts. The complete cure cycle was modeled in these analyses. Also the cool down stage after the composite cure was analyzed. The effect of 5% resin shrinkage on residual stresses and deformations was also investigated. In the second part of the study, Finite Element models were developed to simulate mold filling in RTM processes. Resin flow in the fiber mats was modeled as flow through porous media. Physical models were also developed to investigate resin flow behavior into molds of rectangular and irregular shapes. Silicone fluids of 50 and 100 centistoke viscosities as well as EPON 826 epoxy resin were used in the mold filling experiments. The reinforcements consisted of several layers of woven fiberglass and carbon fiber mats. The effects of injection pressure, fluid viscosity, type of reinforcement, and mold geometry on mold filling times were investigated. Fiber mat permeabilities were determined experimentally for both types of reinforcements. Comparison of experimental and numerical resin front positions indicated the importance of edge effects in resin flow behavior in small cavities. The resin front positions agreed well for the rectangular mold geometry.

Stress-intensity factors of r-cracks in fiber-reinforced composites under thermal and mechanical loading

NASA Astrophysics Data System (ADS)

Mueller, W. H.; Schmauder, S.

1993-02-01

This paper is concerned with the problem of the calculation of stress-intensity factors at the tips of radial matrix cracks (r-cracks) in fiber-reinforced composites under thermal and/or transverse uniaxial or biaxial mechanical loading. The crack is either located in the immediate vicinity of a single fiber or it terminates at the interface between the fiber and the matrix. The problem is stated and solved numerically within the framework of linear elasticity using Erdogan's integral equation technique. It is shown that the solutions for purely thermal and purely mechanical loading can simply be superimposed in order to obtain the results of the combined loading case. Stress-intensity factors (SIFs) are calculated for various lengths and distances of the crack from the interface for each of these loading conditions. The behavior of the SIFs for cracks growing towards or away from the interface is examined. The role of the elastic mismatch between the fibers and the matrix is emphasized and studied extensively using the so-called Dundurs' parameters. It is shown that an r-crack, which is remotely located from the fiber, can either be stabilized or destabilized depending on both the elastic as well as the thermal mismatch of the fibrous composite. Furthermore, Dundurs' parameters are used to predict the exponent of the singularity of the crack tip elastic field and the behavior of the corresponding SIFs for cracks which terminate at the interface. An analytical solution for the SIFs is derived for all three loading conditions under the assumption that the elastic constants of the matrix and the fiber are equal. It is shown that the analytical solution is in good agreement with the corresponding numerical results. Moreover, another analytical solution from the literature, which is based upon Paris' equation for the calculation of stress-intensity factors, is compared with the numerical results and it is shown to be valid only for extremely short r-cracks touching the interface. The numerical results presented are valid for practical fiber composites with r-cracks close to or terminating at the interface provided the matrix material is brittle and the crack does not interact with other neighboring fibers. They may be applied to predict the transverse mechanical behavior of high strength fiber composites.

Online monitoring of corrosion behavior in molten metal using laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Zeng, Qiang; Pan, Congyuan; Li, Chaoyang; Fei, Teng; Ding, Xiaokang; Du, Xuewei; Wang, Qiuping

2018-04-01

The corrosion behavior of structure materials in direct contact with molten metals is widespread in metallurgical industry. The corrosion of casting equipment by molten metals is detrimental to the production process, and the corroded materials can also contaminate the metals being produced. Conventional methods for studying the corrosion behavior by molten metal are offline. This work explored the application of laser-induced breakdown spectroscopy (LIBS) for online monitoring of the corrosion behavior of molten metal. The compositional changes of molten aluminum in crucibles made of 304 stainless steel were obtained online at 1000 °C. Several offline techniques were combined to determine the corrosion mechanism, which was highly consistent with previous studies. Results proved that LIBS was an efficient method to study the corrosion mechanism of solid materials in molten metal.

Mechanical performance of hybrid polyester composites reinforced Cloisite 30B and kenaf fibre

NASA Astrophysics Data System (ADS)

Bonnia, N. N.; Surip, S. N.; Ratim, S.; Mahat, M. M.

2012-06-01

Hybridization of rubber toughened polyester-kenaf nanocomposite was prepared by adding various percentage of kenaf fiber with 4% Cloisite 30B in unsaturated polyester resin. Composite were prepared by adding filler to modified polyester resin subsequently cross-linked using methyl ethyl ketone peroxide and the accelerator cobalt octanoate 1%. Three per hundred rubbers (phr) of liquid natural rubber (LNR) were added in producing this composite. This composite expected to be applied in the interior of passenger cars and truck cabins. This is a quality local product from a combination of good properties polyester and high performance natural fiber, kenaf that is suitable for many applications such as in automotive sector and construction sector. The mechanical and thermal properties of composite were characterized using Durometer Shore-D hardness test, Izod impact test, Scanning electron microscopy, thermogravimetry (TGA) and differential scanning calorimetry (DSC). Result shows that addition of LNR give good properties on impact, flexural and hardness compare to without LNR composite. DSC curve shows that all composition of composites is fully cured and good in thermal properties. Addition of higher percentage of kenaf will lead the composite to elastic behavior and decrease the toughened properties of the composite. Hybrid system composite showed the flexural properties within the flexural properties of kenaf - polyester and Cloisite 30B.

The Sliding Wear and Friction Behavior of M50-Graphene Self-Lubricating Composites Prepared by Laser Additive Manufacturing at Elevated Temperature

NASA Astrophysics Data System (ADS)

Liu, Xiyao; Shi, Xiaoliang; Huang, Yuchun; Deng, Xiaobin; Lu, Guanchen; Yan, Zhao; Zhou, Hongyan; Xue, Bing

2018-03-01

M50 steel is widely applied to manufacture aircraft bearings where service lives are mainly determined by the friction and wear behaviors. The main purpose of this study is to investigate the tribological behaviors and wear mechanisms of M50-1.5 wt.% graphene composites (MGC) prepared by laser additive manufacturing (LAM) (MGC-LAM) sliding against Si3N4 ball from 25 to 550 °C at 18 N-0.2 m/s. XRD, EPMA, FESEM, and EDS mapping were conducted to understand the major mechanisms leading to the improvement in the sliding behavior of MGC-LAM. The results indicated that MGC-LAM showed the excellent friction and wear performance at 25-550 °C for the lower friction coefficient of 0.16-0.52 and less wear rate of 6.1-9.5 × 10-7 mm3 N-1 m-1. Especially at 350 °C, MGC-LAM obtained the best tribological performance (0.16, 6.1 × 10-7mm3 N-1 m-1). It was attributed to the dense coral-like microstructure, as well as the formed surface lubricating structure which is composed of the upper uniform lubricating film with massive graphene and the underneath compacted layer.

Fatigue behavior of a cross-ply metal matrix composite at elevated temperature under the strain controlled mode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sanders, B.P.; Mall, S.; Dennis, L.B.

1997-10-01

A study was conducted to investigate the fatigue behavior of a cross-ply metal matrix composite subjected to fully-reversed, strain-controlled fatigue cycling at elevated temperature. The stress-strain response, maximum and minimum stresses, and modulus during cycling were analyzed to characterize the macro-mechanical behavior. Additionally, microscopy and fractography were conducted to identify damage mechanisms. Damage always initiated in the 90 deg plies, but the governing factor in the fatigue life was damage in the 0 deg plies. The dominant failure mode was fracturing of fibers in the 0 deg plies when the maximum strain was greater than 0.55%, but the dominant failuremore » mode was matrix cracking when the maximum strain was less than 0.55%. Combining the fatigue life data with the macro-mechanical and microscopic observations, a fatigue life diagram was developed and partitioned into three regions. These regions showed relationships between the maximum applied strain and the dominant damage mechanisms. Also, on a strain range basis, the fatigue lives of the specimens tested under the strain-controlled mode in this study were compared with its counterpart under the load-controlled mode of the previous study. It was found that the fatigue lives for these two conditions were the same within the experimental scatter. The MMC tested in this investigation was the Ti-15V-3Cr-3Al-3Sn titanium alloy reinforced with 36 volume percent of silicon carbide fibers (SCS-6).« less

Utilization of modernized global navigation satellite systems for aircraft-based navigation integrity

NASA Astrophysics Data System (ADS)

Ene, Alexandru

The objective of this dissertation is to assess whether or not two particular biocomposite materials, made from hemp fabric and cellulose acetate or polyhydroxybutyrate matrices, are capable of being used for structural and/or construction purposes within in the construction and building industry. The objective of this dissertation was addressed by conducting research to meet the following three goals: (1) to measure the basic mechanical properties of hemp/cellulose acetate and hemp/PHB biocomposites and evaluate if they suitable for use in construction applications, (2) to determine how quickly moisture diffuses into the biocomposite materials and how the moisture affects the mechanical behavior, and (3) to determine how well simple models can predict behavior of structural scale laminates in tension and flexure using biocomposite ply behavior. Compression molding was used to manufacturing the biocomposites from hemp fabric and the themoplastic matrices: cellulose acetate and polyhydroxybutyrate. Four methods for determining the fiber volume fraction were evaluated, and the dissolution method, using different solvents for each matrix type, was used to determine the fiber volume fraction for each composite plate manufactured. Both types of biocomposite were tested in tension, compression, shear, and flexure and the measured properties were compared to wood and engineered wood products to assess whether the biocomposite properties are suitable for use in the construction industry. The biocomposites were conditioned in a humid environment to determine the rate of moisture diffusion into the materials. Then saturated specimens and specimens that were saturated and then dried were tested in tension to evaluate how moisture absorption affects the mechanical behavior of the biocomposites. Finally, simple models of laminate behavior based on laminate plate theory were evaluated to determine if ply level behavior could be used to predict structural scale laminate behavior. While the biocomposite strengths in flexure, compression, and shear were comparable to the strengths of wood and wood-based products parallel to grain, the biocomposite strengths exceeded the strengths perpendicular to the wood grain, as would be expected with fabric reinforcement. The biocomposite moduli of elasticity were between 35% and 75% of the wood moduli parallel to grain. While structural shape of the biocomposites could be manipulated to achieve a comparable structural stiffness to replace wood and short fiber FRPs, the biocomposites have comparable stiffness to the engineered wood-products. Thus, in terms of mechanical properties, the biocomposites can be used in place of engineered-wood products. Yet, the higher densities of the biocomposites as compared to wood and engineered-wood products may limit their implementation in construction. The diffusion coefficients for both biocomposites were comparable to wood and higher than the coefficients for synthetic composites as expected due to the hydrophilicity of the natural fibers. Significantly greater moisture absorption of the hemp/cellulose acetate composite as compared to the hemp/PHB composite was attributed to the cellulose acetate itself being hydrophilic whereas PHB is hydrophobic. The rate of diffusion for both materials was found to increase with increasing temperature. Moisture absorption negatively affected the biocomposites as shown through lower initial stiffnesses and higher strains at failure of saturated specimens. The hemp/cellulose acetate composites were much more affected by moisture absorption than the hemp/PHB composites likely because the moisture plasticized the cellulose acetate and also weakened the interfacial fiber-matrix bond. Moisture was assumed to cause permanent damage because the stress-strain behavior did not return to the unconditioned behavior upon drying of the saturated specimens. The degradation of mechanical properties upon introduction to humid environments limits the potential applications of these biocomposites. For these biocomposites to be used widely within the construction industry, they must therefore be protected from moisture for example through sealants and/or fiber treatments. Classical laminate plate theory was shown to be effective in predicting the initial linear behavior of all of the laminates in tension and flexure, but did not capture stiffness degradation or the full nonlinear stress-strain response of the biocomposites because the model was for linear elastic materials. Use of this model would be appropriate for design of deflection-limited applications within certain stress ranges. The modified nonlinear laminate plate theory predicted the initial stress-strain response well, but at higher strains overestimated the strength and stiffness. The overestimation was attributed to the constitutive model assuming uncoupled stress-strain behavior for each strain component and, additionally in flexure, to the use of tensile behavior as the constitutive behavior in compression. While the simple models provided an adequate prediction of laminate behavior at low strains, to predict behavior at higher strains, it is recommended instead to evaluate the use of finite element analysis to predict response using experimental stress-strain as models for orthotropic materials and non-linear behavior are well-established. (Abstract shortened by UMI.)

Effect of space exposure of some epoxy matrix composites on their thermal expansion and mechanical properties (A0138-8)

NASA Technical Reports Server (NTRS)

Elberg, R.

1984-01-01

This experiment has three objectives. The first and main objective is to detect a possible variation in the coefficient of thermal expansion of composite samples during a 1-year exposure to the near-Earth orbital environment. A second objective is to detect a possible change in the mechanical integrity of composite products, both simple elements and honeycomb sandwich assemblies. A third objective is to compare the behavior of two epoxy resins commonly used in space structural production. The experimental approach is to passively expose samples of epoxy matrix composite materials to the space environment and to compare preflight and postflight measurements of mechanical properties. The experiment will be located in one of the three FRECOPA (French cooperative payload) boxes in a 12-in.-deep peripheral tray that contains nine other experiments from France. The FRECOPA box will protect the samples from contamination during the launch and reentry phases of the mission. The coefficients of thermal expansion are measured on Earth before and after space exposure.