A-type and I-type granitoids and mylonitic granites of Hassan Salaran area of SE Saqqez, Kurdistan, Iran

NASA Astrophysics Data System (ADS)

Abdullah, Fakhraddin Mohammad; Saeed Ahmad, Sheler

2014-05-01

The Hassan Salarn area is located 20km to southeast of Saqqez city in Kurdistan Province, western Iran. In this area there are two distinct granitic rock suites consisting A-type and I-type granites and also mylonitic granites. These A-type and I-type granites have various petrological and geochemical characteristics. They also have different origins and petrogenesis. A-type granitoids comprise alkali feldspar granite, syenogranite and quartz alkali feldspar syenite, whereas I-type granitoids are composed of monzogranite, granodiorite and tonalite. Geochemically, A-type granitoids are peralkaline and acmite-normative but I-type granitoids are subalkaline (calc-alkaline), metaluminous and diopside-normative. A-type granitoids are also ferroan alkali and ferroan alkali-calcic whereas I-type granitoids are magnesian and calcic. A-type granitoids resemble to within plate granites and post-orogenic granites whereas I-type granitoids resemble to volcanic arc granites. A-type granitoids contain higher concentrations of alkalies, Zr, Rb, Nb, Y, Th, Ce, high FeO/MgO ratios and lower concentrations of Mg, Ca and Sr, resembling post-orogenic A-type granites. It is possible that heat from a mantle-derived magma which intruded into the lower crust, and/or rapid crustal extension have been essential generation of approriate melts producing A-type granitoids. Thus we can conclude that A-type granitoids were generated from a mixed mantle-crust source. Negative Nb anomalies and low contents of Ti and P probably indicate a subduction-related origin for protolith of I-type granitoids. Negative Nb anomalies and enrichment in Ce relative to its adjacent elements can be related to involvement of continental crust in magmatic processes. I-type granitoids are also enriched in Rb, Ba, K, Th, Ce and depleted in Nb, Zr and Y, indicating that they have had interacted with crust. I-type granitoids may result from contamination of mantle-derived magmas by continental crust during a subduction event. The mylonitic granites are elongated masses with a NE-SW trend and their contacts with the A-type and I-type granitoids are fault contact. Hand specimens have a layered appearance with green bands made from chlorite and epidote and grey to white bands with quartz and feldspar. These rocks contain plagioclase, quartz and orthoclase under the microscope. Also fine-grained minerals such as quartz, sericite, epidote, chlorite and opaque minerals make the groundmass wrapping the porphyroclasts. Pressure shadows around porphyroclasts of plagioclase and quartz and crystallization of fine-grained quartz and sericite in these places along with intense alteration of plagioclase to epidote and sericite, existence of quartz with different sizes, andaluse extinction in quartz crystals, and elongation of chlorites, resulted from dynamic recrystallisation of biotites all indicate effect of stresses on the rocks. Considering the similar mineralogical composition of the mylonitic rocks with I-type granitoid, it could be concluded that the granodioritic magma, after intrusion and solidification, is changed to mylonite in a shear zone due to tectonical forces.

Effects of shielding gas composition on arc profile and molten pool dynamics in gas metal arc welding of steels

NASA Astrophysics Data System (ADS)

Wang, L. L.; Lu, F. G.; Wang, H. P.; Murphy, A. B.; Tang, X. H.

2014-11-01

In gas metal arc welding, gases of different compositions are used to produce an arc plasma, which heats and melts the workpiece. They also protect the workpiece from the influence of the air during the welding process. This paper models gas metal arc welding (GMAW) processes using an in-house simulation code. It investigates the effects of the gas composition on the temperature distribution in the arc and on the molten pool dynamics in gas metal arc welding of steels. Pure argon, pure CO2 and different mixtures of argon and CO2 are considered in the study. The model is validated by comparing the calculated weld profiles with physical weld measurements. The numerical calculations reveal that gas composition greatly affects the arc temperature profile, heat transfer to the workpiece, and consequently the weld dimension. As the CO2 content in the shielding gas increases, a more constricted arc plasma with higher energy density is generated as a result of the increased current density in the arc centre and increased Lorentz force. The calculation also shows that the heat transferred from the arc to the workpiece increases with increasing CO2 content, resulting in a wider and deeper weld pool and decreased reinforcement height.

Mid-to-Lower-level Plutonic Rocks From Crust of the Southern Mariana Forearc: Implications for Growth of Continental Crust

NASA Astrophysics Data System (ADS)

Fryer, P.; Reagan, M.

2006-12-01

Tonalitic plutonic rocks dredged from the southern Mariana forearc are similar in terms of major element composition to tonalitic plutonic rocks of the Tanzawa Mountains on the Izu Peninsula of Japan. The tonalites of the Tanzawa Mountains have been interpreted to represent mid-lower crustal plutonic rocks that make up the 6.0 to 6.3 km/s layer identified in seismic velocity profiles of the Izu arc at 32°N. The tonalities of the southern Mariana forearc may be analogous to the Tanzawa tonalities in terms of lithology and presumably seismic velocities, but have distinctive trace element and isotopic compositions. The exposure of these rocks on the southern Mariana forearc in a location where it is narrower by up to 80 km than elsewhere along its strike indicates a truncation of the arc lithosphere by tectonic erosion in the southern Mariana forearc. If tectonic processes in the forearc have exposed silicic plutonic rock of the arc lithosphere within 150 km of the volcanic front, then the structure of the Mariana arc and forearc is likely similar to that of the Izu arc, where seismic velocity structure suggests 25% of the arc/forearc lithosphere is comprised of a mid-crustal level tonalitic plutonic complex. The trace element and Sr isotopic compositions of the tonalities dredged from the Mariana forearc links them to a suprasubduction-zone environment. The Pb isotopic compositions, however, are consistent with crystallization ages that may be as old as Cretaceous. The compositions of these tonalites differ markedly from those of silicic volcanic rocks that have erupted throughout the history of the IBM arc and suggest that they represent a minor component of the arc. Nevertheless, the presence of Cretaceous tonalites in the Mariana forearc suggests that a portion of its crust may predate subduction initiation. The presence of silicic mid-to-lower crustal level plutonics beneath the Mariana arc as well as Eocene rhyolites on Saipan indicate that average major element composition of the arc crust may be comparable with average continental crust. This is consistent with estimates of the average composition of the Izu arc crust from seismic velocity studies and petrologic studies of exposures of the Izu arc crust in southern Japan's Izu peninsula. These data imply that the island arc that developed along the entire margin of the Philippine Sea plate may have had a generally similar structure and composition. Most components of the IBM arc crust, however, have relatively flat rare-earth patterns and low rare-earth concentrations compared with average continental crust. The averaged composition of the IBM crust, as a whole, differs markedly from that suggested by studies of the velocity structure of the central Aleutian arc. If the continental crust was generated in oceanic island arc settings throughout the history of the Earth, then its sources were significantly more enriched in LREE than the sources for the Cenozoic IBM arcs.

Two-phase southward subduction of the Mongol-Okhotsk oceanic plate constrained by Permian-Jurassic granitoids in the Erguna and Xing'an massifs (NE China)

NASA Astrophysics Data System (ADS)

Liu, Huichuan; Li, Yinglei; He, Hongyun; Huangfu, Pengpeng; Liu, Yongzheng

2018-04-01

Geodynamics of the Mongol-Okhotsk oceanic plate southward subduction are still pending problems. This paper presents new zircon LA-ICP-MS U-Pb age and whole-rock geochemical data for the middle Permian to Middle Jurassic granitoids in the western Erguna and central Xing'an massifs. 267-264 Ma, 241 Ma and 173 Ma I-type granites, and 216 Ma A-type granites were identified in the Erguna and Xing'an massifs (NE China). The I-type granites were produced by partial melting of the lower mafic crust. The 216 Ma A-type granites were derived from partial melting of crustal materials with tonalitic to granodioritic compositions. The 267-264 Ma and 241 Ma I-type granites were generated in an Andean-type arc setting, wheras the 216 Ma A-type and 173 Ma granites were formed in supra subduction extensional setting. We summarized previous age data of the middle Permian to Middle Jurassic magmtaic rocks in the Erguna and Xing'an Massifs and identified two isolated phases of magmatic activity including the ca. 267-225 Ma and ca. 215-165 Ma periods, with a significant magmatic gap at ca. 225-215 Ma. These middle Permian to Middle Jurassic magmatic rocks are closely related to the southward subduction of the Mongol-Okhotsk ocean. A two-stage tectonic evolutionary model was proposed to account for these geological observations in the Erguna and Xing'an massifs, involving Permian to Middle Triassic continuous southward subduction of the Mongol-Okhotsk oceanic plate and Late Triassic to Jurassic slab-rollback and supra subduction extension.

Cretaceous and Paleogene granitoid suites of the Sikhote-Alin area (Far East Russia): Geochemistry and tectonic implications

NASA Astrophysics Data System (ADS)

Grebennikov, Andrei V.; Khanchuk, Alexander I.; Gonevchuk, Valeriy G.; Kovalenko, Sergey V.

2016-09-01

The Mesozoic and Cenozoic geological history of NE Asia comprises alternating episodes of subduction or transform strike-slip movement of the oceanic plate along the continental margin of Eurasia. This sequence resulted in the regular generation of granitoid suites that are characterized by different ages, compositions, and tectonic settings. The Hauterivian-Aptian orogenic stage of the Sikhote-Alin, associated with the strike-slip displacement of the early Paleozoic continental blocks, the successive deformation of the Jurassic and Early Cretaceous terranes, and the injection of the earliest S-type granitoids. During late Albian, the area underwent syn-strike-slip compression caused by collision with the Aptian island arc and resulted in the injection of voluminous magmas of calc-alkaline magnesian (S- and I-type) and alkali-calcic ferroan (A-type) granitoids into syn-faulting compressional and extensional basins, respectively. Northwestward to westward movement of the Izanagi Plate resulted in the initiation of frontal subduction of the Paleo-Pacific Plate during the Cenomanian-Maastrichtian. In turn, this resulted in the generation of plateau-forming ignimbrites and their intrusive analogs formed from metaluminous I-type felsic magmas. Paleocene-Eocene magmatism in the Sikhote-Alin area commenced after the termination of subduction in a rifting regime related to strike-slip movement of the oceanic plate relative to the continent. The break-off of the subducted plate and the injection of oceanic asthenospheric material into the subcontinental lithosphere resulted in the eruption of lamproites and fayalite rhyolites, and coeval intrusions of gabbro and alkali feldspar granites (A-type). The A-type granitic-rocks and coeval gabbro-monzonites are considered to be reliable indicators of the transform continental margin geodynamic settings.

Compositional Variations of Paleogene and Neogene Tephra From the Northern Izu-Bonin-Mariana Arc

NASA Astrophysics Data System (ADS)

Tepley, F. J., III; Barth, A. P.; Brandl, P. A.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Li, H.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Yogodzinski, G. M.

2014-12-01

A primary objective of IODP Expedition 351 was to evaluate arc initiation processes of the Izu-Bonin-Mariana (IBM) volcanic arc and its compositional evolution through time. To this end, a single thick section of sediment overlying oceanic crust was cored in the Amami Sankaku Basin where a complete sediment record of arc inception and evolution is preserved. This sediment record includes ash and pyroclasts, deposited in fore-arc, arc, and back-arc settings, likely associated with both the ~49-25 Ma emergent IBM volcanic arc and the evolving Ryukyu-Kyushu volcanic arc. Our goal was to assess the major element evolution of the nascent and evolving IBM system using the temporally constrained record of the early and developing system. In all, more than 100 ash and tuff layers, and pyroclastic fragments were selected from temporally resolved portions of the core, and from representative fractions of the overall core ("core catcher"). The samples were prepared to determine major and minor element compositions via electron microprobe analyses. This ash and pyroclast record will allow us to 1) resolve the Paleogene evolutionary history of the northern IBM arc in greater detail; 2) determine compositional variations of this portion of the IBM arc through time; 3) compare the acquired data to an extensive whole rock and tephra dataset from other segments of the IBM arc; 4) test hypotheses of northern IBM arc evolution and the involvement of different source reservoirs; and 5) mark important stratigraphic markers associated with the Neogene volcanic history of the adjacent evolving Ryukyu-Kyushu arc.

Along and Across Arc Variation of the Central Andes by Single Crystal Trace Element Analaysis

NASA Astrophysics Data System (ADS)

Michelfelder, G.; Sundell, T.; Wilder, A.; Salings, E. E.

2017-12-01

Along arc and across arc geochemical variations at continental volcanic arcs are influenced by a number of factors including the composition and thickness of the continental crust, mantle heterogeneity, and fluids from the subducted slab. Whole rock geochemical trends along and across the arc front of the Central Volcanic Zone (CVZ) have been suggested to be primarily influenced by the composition and thickness of the crust. In the CVZ, Pb isotopic domains relate volcanic rock compositions to the crustal basement and systematically varies with crustal age. It has been shown repeatedly that incompatible trace element trends and trace element ratios can be used to infer systematic geochemical changes. However, there is no rule linking magmatic process or chemical heterogeneity/ homogeneity as a result of large crustal magma storage reservoirs such as MASH zones to the observed variation. Here we present a combination of whole rock major- and trace element data, isotopic data and in situ single crystal data from plagioclase, pyroxene and olivine for six stratovolcanoes along the arc front and in the back arc of the CVZ. We compare geochemical trends at the whole and single crystal scale. These volcanoes include lava flows and domes from Cerro Uturuncu in the back-arc, Aucanquilcha, Ollagüe, San Pedro-San Pablo, Lascar, and Lazufre from the arc front. On an arc-wide scale, whole rock samples of silicic lavas from these six composite volcanoes display systematically higher K2O, LILE, REE and HFSE contents and 87Sr/86Sr ratios with increasing distance from the arc-front. In contrast, the lavas have systematically lower Na2O, Sr, and Ba contents; LILE/HFSE ratios; 143Nd/144Nd ratios; and more negative Eu anomalies. Silicic magmas along the arc-front reflecting melting of young, mafic composition source rocks with the continental crust becoming increasingly older and more felsic toward the east. These trends are paralleled in the trace element compositions of plagioclase cores which systematically become less diverse in composition in younger lava flows from each center. We suggest these trends result from progressively smaller degrees of mantle partial melting, primary melt generation, and crustal hybridization with distance from the arc-front and varying influence of MASH zone processes.

Characterization of Mullite-Zirconia Composite Processed by Non-Transferred and Transferred Arc Plasma

NASA Astrophysics Data System (ADS)

Yugeswaran, S.; Selvarajan, V.; Lusvarghi, L.; I. Y. Tok, A.; D. Siva Rama, Krishna

2009-04-01

The arc plasma melting technique is a simple method to synthesize high temperature reaction composites. In this study, mullite-zirconia composite was synthesized by transferred and non-transferred arc plasma melting, and the results were compared. A mixture of alumina and zircon powders with a mole ratio of 3: 2 were ball milled for four hours and melted for two minutes in the transferred and non-transferred mode of plasma arcs. Argon and air were used as plasma forming gases. The phase and microstructural formation of melted samples were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM). The microstructure of the composites was found to be affected by the mode of melting. In transferred arc melting, zirconia flowers with uniform lines along with mullite whiskers were obtained. In the case of non-transferred arc plasma melting, mullite whiskers along with star shape zirconia were formed. Differential thermal analysis (DTA) of the synthesized mullite-zirconia composites provided a deeper understanding of the mechanisms of mullite formation during the two different processes.

Generation of Silicic Melts in the Early Izu-Bonin Arc Recorded by Detrital Zircons in Proximal Arc Volcaniclastic Rocks From the Philippine Sea

NASA Astrophysics Data System (ADS)

Barth, A. P.; Tani, K.; Meffre, S.; Wooden, J. L.; Coble, M. A.; Arculus, R. J.; Ishizuka, O.; Shukle, J. T.

2017-10-01

A 1.2 km thick Paleogene volcaniclastic section at International Ocean Discovery Program Site 351-U1438 preserves the deep-marine, proximal record of Izu-Bonin oceanic arc initiation, and volcano evolution along the Kyushu-Palau Ridge (KPR). Pb/U ages and trace element compositions of zircons recovered from volcaniclastic sandstones preserve a remarkable temporal record of juvenile island arc evolution. Pb/U ages ranging from 43 to 27 Ma are compatible with provenance in one or more active arc edifices of the northern KPR. The abundances of selected trace elements with high concentrations provide insight into the genesis of U1438 detrital zircon host melts, and represent useful indicators of both short and long-term variations in melt compositions in arc settings. The Site U1438 zircons span the compositional range between zircons from mid-ocean ridge gabbros and zircons from relatively enriched continental arcs, as predicted for melts in a primitive oceanic arc setting derived from a highly depleted mantle source. Melt zircon saturation temperatures and Ti-in-zircon thermometry suggest a provenance in relatively cool and silicic melts that evolved toward more Th and U-rich compositions with time. Th, U, and light rare earth element enrichments beginning about 35 Ma are consistent with detrital zircons recording development of regional arc asymmetry and selective trace element-enriched rear arc silicic melts as the juvenile Izu-Bonin arc evolved.

Petrologic, tectonic, and metallogenic evolution of the Ancestral Cascades magmatic arc, Washington, Oregon, and northern California

USGS Publications Warehouse

du Bray, Edward A.; John, David A.

2011-01-01

Present-day High Cascades arc magmatism was preceded by ~40 m.y. of nearly cospatial magmatism represented by the ancestral Cascades arc in Washington, Oregon, and northernmost California (United States). Time-space-composition relations for the ancestral Cascades arc have been synthesized from a recent compilation of more than 4000 geochemical analyses and associated age data. Neither the composition nor distribution of ancestral Cascades magmatism was uniform along the length of the ancestral arc through time. Initial (>40 to 36 Ma) ancestral Cascades magmatism (mostly basalt and basaltic andesite) was focused at the north end of the arc between the present-day locations of Mount Rainier and the Columbia River. From 35 to 18 Ma, initial basaltic andesite and andesite magmatism evolved to include dacite and rhyolite; magmatic activity became more voluminous and extended along most of the arc. Between 17 and 8 Ma, magmatism was focused along the part of the arc coincident with the northern two-thirds of Oregon and returned to more mafic compositions. Subsequent ancestral Cascades magmatism was dominated by basaltic andesite to basalt prior to the post–4 Ma onset of High Cascades magmatism. Transitional tholeiitic to calc-alkaline compositions dominated early (before 40 to ca. 25 Ma) ancestral Cascades eruptive products, whereas the majority of the younger arc rocks have a calc-alkaline affinity. Tholeiitic compositions characteristic of the oldest ancestral arc magmas suggest development associated with thin, immature crust and slab window processes, whereas the younger, calc-alkaline magmas suggest interaction with thicker, more evolved crust and more conventional subduction-related magmatic processes. Presumed changes in subducted slab dip through time also correlate with fundamental magma composition variation. The predominance of mafic compositions during latest ancestral arc magmatism and throughout the history of modern High Cascades magmatism probably reflects extensional tectonics that dominated during these periods of arc magmatism. Mineral deposits associated with ancestral Cascades arc rocks are uncommon; most are small and low grade relative to those found in other continental magmatic arcs. The small size, low grade, and dearth of deposits, especially in the southern two-thirds of the ancestral arc, probably reflect many factors, the most important of which may be the prevalence of extensional tectonics within this arc domain during this magmatic episode. Progressive clockwise rotation of the forearc block west of the evolving Oregon part of the ancestral Cascades magmatism produced an extensional regime that did not foster significant mineral deposit formation. In contrast, the Washington arc domain developed in a transpressional to mildly compressive regime that was more conducive to magmatic processes and hydrothermal fluid channeling critical to deposit formation. Small, low-grade porphyry copper deposits in the northern third of the ancestral Cascades arc segment also may be a consequence of more mature continental crust, including a Mesozoic component, beneath Washington north of Mount St. Helens.

Complex structure of the carbon arc discharge for synthesis of nanotubes

DOE PAGES

Vekselman, V.; Feurer, M.; Huang, T.; ...

2017-06-06

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C 2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc coremore » populated with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. Furthermore, this result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Complex structure of the carbon arc discharge for synthesis of nanotubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vekselman, V.; Feurer, M.; Huang, T.

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C 2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc coremore » populated with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. Furthermore, this result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Method for gas-metal arc deposition

DOEpatents

Buhrmaster, C.L.; Clark, D.E.; Smartt, H.B.

1990-11-13

Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites are disclosed. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite. 1 fig.

Method for gas-metal arc deposition

DOEpatents

Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

1990-01-01

Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment wiht the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

Apparatus for gas-metal arc deposition

DOEpatents

Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

1991-01-01

Apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspenion of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

Seismic anisotropy and slab dynamics from SKS splitting recorded in Colombia

NASA Astrophysics Data System (ADS)

Porritt, Robert W.; Becker, Thorsten W.; Monsalve, Gaspar

2014-12-01

The Nazca, Caribbean, and South America plates meet in northwestern South America where the northern end of the Andean volcanic arc and Wadati-Benioff zone seismicity indicate ongoing subduction. However, the termination of Quaternary volcanism at ~5.5°N and eastward offset in seismicity underneath Colombia suggest the presence of complex slab geometry. To help link geometry to dynamics, we analyze SKS splitting for 38 broadband stations of the Colombian national network. Measurements of fast polarization axes in western Colombia close to the trench show dominantly trench-perpendicular orientations. Orientations measured at stations in the back arc, farther to the east, however, abruptly change to roughly trench parallel anisotropy. This may indicate along-arc mantle flow, possibly related to the suggested "Caldas" slab tear, or a lithospheric signature, but smaller-scale variations in anisotropy remain to be explained. Our observations are atypical globally and challenge our understanding of the complexities of subduction zone seismic anisotropy.

Conductivity tensor for anisotropic plasma in gyrokinetic theory

DOE PAGES

Porazik, Peter; Johnson, Jay R.

2017-05-18

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C-2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc core populatedmore » with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. This result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Conductivity tensor for anisotropic plasma in gyrokinetic theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porazik, Peter; Johnson, Jay R.

Comprehensive non-invasive spectroscopic techniques and electrical measurements of the carbon arc revealed two distinguishable plasma synthesis regions in the radial direction normal to the arc axis. These regions, which are defined as the arc core and the arc periphery, are shown to have very different compositions of carbon species with different densities and temperatures. The colder arc periphery is dominated by carbon diatomic molecules (C-2), which are in the minority in the composition of the hot arc core. These differences are due to a highly non-uniform distribution of the arc current, which is mainly conducted through the arc core populatedmore » with carbon atoms and ions. Therefore, the ablation of the graphite anode is governed by the arc core, while the formation of carbon molecules occurs in the colder arc periphery. This result is consistent with previous predictions that the plasma environment in the arc periphery is suitable for synthesis of carbon nanotubes.« less

Coordinated Petrography and Oxygen Isotopic Compositions of Al-Rich Chondrules from CV3 Chondrites

NASA Astrophysics Data System (ADS)

Zhang, M. M.; Lin, Y. T.; Tang, G. Q.; Li, X. H.

2017-07-01

In this study, we coordinated the petrology, bulk compositions and oxygen isotope compositions of 12 ARCs from Allende and Leoville and Ningqiang chondrites in order to elucidate any potential genetic relationships between ARCs, CAIs and FMCs.

Scintillation screen applications in a vacuum arc ion source with composite hydride cathode

NASA Astrophysics Data System (ADS)

Wang, X. H.; Tuo, X. G.; Yang, Z.; Peng, Y. F.; Li, J.; Lv, H. Y.; Li, J. H.; Long, J. D.

2018-05-01

Vacuum arc ion source with composite hydride cathode was developed to produce intense ion beams which can be applied in particle accelerator injections. Beam profile and beam composition are two fundamental parameters of the beam for the vacuum arc ion source in such specific applications. An aluminum-coated scintillation screen with an ICCD camera readout was used to show the space-time distribution of the beam directly. A simple magnetic analysis assembly with the scintillation screen shows the beam composition information of this kind ion source. Some physical and technical issues are discussed and analyzed in the text.

Intrusive rocks of the Wadi Hamad Area, North Eastern Desert, Egypt: Change of magma composition with maturity of Neoproterozoic continental island arc and the role of collisional plutonism in the differentiation of arc crust

NASA Astrophysics Data System (ADS)

Basta, Fawzy F.; Maurice, Ayman E.; Bakhit, Bottros R.; Azer, Mokhles K.; El-Sobky, Atef F.

2017-09-01

The igneous rocks of the Wadi Hamad area are exposed in the northernmost segment of the Arabian-Nubian Shield (ANS). These rocks represent part of crustal section of Neoproterozoic continental island arc which is intruded by late to post-collisional alkali feldspar granites. The subduction-related intrusives comprise earlier gabbro-diorites and later granodiorites-granites. Subduction setting of these intrusives is indicated by medium- to high-K calc-alkaline affinity, Ta-Nb troughs on the spider diagrams and pyroxene and biotite compositions similar to those crystallized from arc magmas. The collisional alkali feldspar granites have high-K highly fractionated calc-alkaline nature and their spider diagrams almost devoid of Ta-Nb troughs. The earlier subduction gabbro-diorites have lower alkalis, LREE, Nb, Zr and Hf values compared with the later subduction granodiorites-granites, which display more LILE-enriched spider diagrams with shallower Ta-Nb troughs, reflecting variation of magma composition with arc evolution. The later subduction granitoids were generated by lower degree of partial melting of mantle wedge and contain higher arc crustal component compared with the earlier subduction gabbro-diorites. The highly silicic alkali feldspar granites represent extensively evolved melts derived from partial melting of intermediate arc crustal sources during the collisional stage. Re-melting of arc crustal sources during the collisional stage results in geochemical differentiation of the continental arc crust and the silicic collisional plutonism drives the composition of its upper part towards that of mature continental crust.

A-type granites and related rocks: Evolution of a concept, problems and prospects

NASA Astrophysics Data System (ADS)

Bonin, Bernard

2007-08-01

Although A-type granites have long been recognized as a distinct group of granites, the term A-type was coined first less than thirty years ago. A-type suites occur in geodynamic contexts ranging from within-plate settings to plate boundaries, locations and times of emplacement are not random. Rare in the lower crust, as some charnockite suites, they are fairly common at shallower depths, especially at the subvolcanic level where they form ring complexes rooting caldera volcanoes. Characteristic features include hypersolvus to transsolvus to subsolvus alkali feldspar textures, iron-rich mafic mineralogy, bulk-rock compositions yielding ferroan, alkali-calcic to alkaline affinities, high LILE+HFSE abundances, and pronounced anomalies due to high degrees of mineral fractionation. Isotopic features evidence sources containing a large mantle input. Experimental data show that A-type magmas contain dissolved OH F-bearing fluids, crystallised under reduced and oxidized conditions, and yield high-temperature liquidus, favouring early crystallisation of anhydrous iron minerals, such as fayalite. Though many petrogenetic models imply solely crustal derivation, no convincing A-type liquids were produced experimentally from crustal materials, nor have any leucosomes of A-type composition been detected within migmatitic terranes. As it occurs in association with mafic igneous rocks in continents as well as on the ocean floor, A-type granite is likely to come from mantle-derived transitional to alkaline mafic to intermediate magmas. Rare felsic materials found in the meteoritic and lunar record yield dominantly A-type features. Contrary to the more common types of granite, A-type granite is, therefore, not typical of Earth and was produced in planetary environments differing from those prevailing on Earth.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sherrod, D.R.; Smith, J.G.

Quaternary (2-0 Ma) extrusion rates change significantly along the Cascade Range volcanic arc. The extrusion rate north of Mount Rainier is about 0.21 km{sup 3} km{sup {minus}1} m.y.{sup {minus}1}; the rate in southern Washington and northern Oregon south to Mount Hood is about 1.6 km{sup 3} km{sup {minus}1} m.y.{sup {minus}1}; in central Oregon the rate is 3-6 km{sup 3} km{sup {minus}1}; and in northern California, the rate is 3.2 km{sup 3} km{sup {minus}1} m.y.{sup {minus}1}. Eruption style also changes along the arc but at latitudes different from rate changes. At the ends of the arc, volcanism is focused at isolatedmore » intermediate to silicic composite volcanoes. The composite volcanoes represent {approximately}30% of the total volume of the arc. Mafic volcanic fields partly ring some composite volcanoes, especially in the south. In contrast, volcanism is diffused in the middle of the arc, where numerous overlapping mafic shields and a few composite volcanoes have built a broad ridge. Contrasting eruption style may signify diffuse versus focused heat sources or may reflect changes in permeability to ascending magma along the arc.« less

Quaternary extrusion rates of the Cascade Range, northwestern United States and southern British Columbia

NASA Astrophysics Data System (ADS)

Sherrod, David R.; Smith, James G.

1990-11-01

Quaternary (2-0 Ma) extrusion rates change significantly along the Cascade Range volcanic arc. The extrusion rate north of Mount Rainier is about 0.21 km3 km-1 m.y.-1; the rate in southern Washington and northern Oregon south to Mount Hood is about 1.6 km3 km-1 m.y.-1; in central Oregon the rate is 3-6 km3 km-1 m.y.-1; and in northern California, the rate is 3.2 km3 km-1 m.y.-1. Eruption style also changes along the arc but at latitudes different from rate changes. At the ends of the arc, volcanism is focused at isolated intermediate to silicic composite volcanoes. The composite volcanoes represent ˜30% of the total volume of the arc. Mafic volcanic fields partly ring some composite volcanoes, especially in the south. In contrast, volcanism is diffused in the middle of the arc, where numerous overlapping mafic shields and a few composite volcanoes have built a broad ridge. Contrasting eruption style may signify diffuse versus focused heat sources or may reflect changes in permeability to ascending magma along the arc.

A 1400 km geochemical transect along the Central American Arc: Summary of mafic Holocene volcanism from Guatemala to Panama

NASA Astrophysics Data System (ADS)

Geldmacher, J.; Hoernle, K.; Gill, J. B.; Hauff, F.; Heydolph, K.

2016-12-01

It is generally accepted that subducted oceanic crust and sediments contribute to the composition of arc magmas. Systematic variations of input parameters (including age, subduction angle, and chemical composition of the subducting material) make the Central American Volcanic Arc (CAVA), which extends from Guatemala in the northwest through El Salvador, Honduras, Nicaragua, Costa Rica and Panama to the southeast, a prime study object. We present a comprehensive (major and trace element and Sr-Nd-Pb-Hf isotope data) and consistent (all data generated in the same labs using the same methods and data reduction procedures) compilation of published and unpublished Holocene mafic volcanic rocks sampled along the entire arc. New data include Sr and, for the first time, Hf isotope data from the entire CAVA as well as major and trace element data for 43 samples from southern Nicaragua and central Costa Rica from which only isotopic compositions were previously published. The combined elemental and isotopic data confirm the influence of distinct subduction components on the composition of CAVA magmas. Along-arc geochemical variations (especially delta 208Pb/204Pb) of volcanic front magmas in Costa Rica and Panama have been explained by the different compositions of seamounts/ridges of the isotopically zoned Galápagos hotspot track that covers the subducting Cocos Plate in this sector of the arc (Hoernle et al. 2008, Nature 451). Our new data confirm this relationship with arc lavas from Costa Rica having higher 87Sr/86Sr ratios than those from western Panama reflecting a similar spatial-compositional distinction in the subducting hotspot track beneath them. In contrast, 176Hf/177Hf shows no comparable variations in this sector of the arc, indicating that the Hf is primarily derived from the mantle wedge rather than the subducting slab. Although small degree hydrous melts are believed to fertilize the mantle wedge beneath Costa Rica, residual zircon may hold back the Hf.

Seafloor Spreading in the Lau-Havre Backarc Basins: From Fast to Ultra Slow

NASA Astrophysics Data System (ADS)

Martinez, F.; Dunn, R. A.; Sleeper, J. D.

2013-12-01

Seafloor spreading in the Lau Basin occurs along the well-organized Eastern Lau Spreading Center (ELSC) and Valu Fa Ridges (VFR) opening at 97-39 mm/yr. The ELSC/VFR produce two distinct crustal types sub-parallel to the ridge as a function of their separation from the arc volcanic front. Arc-proximal spreading forms a shallow, thick crust with arc-like lavas that abruptly changes to a deeper, thinner crust with backarc basin basalt (BABB)-like lavas as the ridges separate from the arc volcanic front. Southward in the Havre Trough opening rates decrease to 15 mm/yr and a well-organized spreading axis is largely absent. Instead, active volcanism appears to be distributed across a broad zone located asymmetrically near the arc side of the basin. Further, crustal accretion appears to have two distinct styles forming a shallower terrain floored by arc-like lavas and deeper rifted basins floored by more BABB-like lavas [Wysoczanski et al., 2010, G-cubed]. Although these crustal terrains broadly resemble those flanking the ELSC/VFR, in the Havre Trough they are organized into bands that trend across the basin with the shallower arc-like terrains typically trailing from Kermadec arc front volcanoes. We hypothesize that the variation in style of crustal accretion along the Lau-Havre backarc system is controlled by the southward decreasing rate of plate extension superimposed on a compositionally variable mantle wedge. Distinct hydrous and less-hydrous mantle domains have been proposed for the mantle wedge [Martinez & Taylor, 2002; Dunn & Martinez, 2011; Nature]. Within the hydrous domain (< about 50 km from the arc volcanic front) further compositional 'fingers' trailing basinward from arc front volcanoes have been interpreted in the Lau Basin based on ridge axis morphology and chemistry [Sleeper & Martinez, submitted]. In the Lau Basin, intermediate to fast spreading rates impose a 2D plate-driven advective regime in the mantle wedge constraining volcanic accretion to the 2D narrow ridge axis. Effects of the cross trending compositional 'fingers' are minimized and only expressed as second-order geological and geochemical features at the ridge. As opening rates decrease to ultra-slow in the Havre Trough, 2D plate-driven components of mantle advection and melting are minimized. The inherent buoyancy of melts dominate advection and volcanic emplacement allowing a clearer expression of intrinsic 3D compositional and melt generation patterns in the mantle wedge. These observations suggest that mantle wedge structure fundamentally consists of arc-like mantle source compositional fingers trailing basinward from arc front volcanoes within a hydrous but more MORB source-like mantle. Spreading rate controls the degree of expression of these compositional fingers in back-arc volcanic crustal accretion. Fast to intermediate rate spreading imposes a 2D ridge-parallel distribution to crustal domains whereas slow to ultra slow spreading rates allow 3D mantle wedge compositional and melt generation patterns to be expressed.

The Origin of Silicic Arc Crust - Insights from the Northern Pacific Volcanic Arcs through Space and Time

NASA Astrophysics Data System (ADS)

Straub, S. M.; Kelemen, P. B.

2016-12-01

The remarkable compositional similarities of andesitic crust at modern convergent margins and the continental crust has long evoked the hypothesis of similar origins. Key to understanding either genesis is understanding the mode of silica enrichment. Silicic crust cannot be directly extracted from the upper mantle. Hence, in modern arcs, numerous studies - observant of the pervasive and irrefutable evidence of melt mixing - proposed that arc andesites formed by mixing of mantle-derived basaltic melts and fusible silicic material from the overlying crust. Mass balance requires the amount of silicic crust in such hybrid andesites to be on the order to tens of percent, implying that their composition to be perceptibly influenced by the various crustal basements. In order to test this hypothesis, major and trace element compositions of mafic and silicic arc magmas with arc-typical low Ce/Pb< 10 of Northern Pacific arcs (Marianas through Mexico) were combined with Pb isotope ratios. Pb isotope ratios are considered highly sensitive to crustal contamination, and hence should reflect the variable composition of the oceanic and continental basement on which these arcs are constructed. In particular, in thick-crust continental arcs where the basement is isotopically different from the mantle and crustal assimilation thought to be most prevalent, silicic magmas must be expected to be distinct from those of the associated mafic melts. However, in a given arc, the Pb isotope ratios are constant with increasing melt silica regardless of the nature of the basement. This observation argues against a melt origin of silicic melts from the crustal basement and suggest them to be controlled by the same slab flux as their co-eval mafic counterparts. This inference is validated by the spatial and temporal pattern of arc Pb isotope ratios along the Northern Pacific margins and throughout the 50 million years of Cenozoic evolution of the Izu Bonin Mariana arc/trench system that are can be related to with systematic, `real-time' changes in the composition of the slab flux with no role of the crustal basement. In summary, these data suggest that that silicic melts are ultimately genetically linked to the mafic co-eval series from the mantle, by such mechanisms as fractional crystallization, or melt-rock reactions, or a combination of both.

Effect of water on the composition of partial melts of greenstone and amphibolite

NASA Technical Reports Server (NTRS)

Beard, James S.; Lofgren, Gary E.

1989-01-01

Closed-system partial melts of hydrated, metamorphosed arc basalts and andesites (greenstones and amphibolites), where only water structurally bound in metamorphic minerals is available for melting (dehydration melting), are generally water-undersaturated, coexist with plagioclase-rich, anhydrous restites, and have compositions like island arc tonalites. In contrast, water-saturated melting at water pressures of 3 kilobars yields strongly peraluminous, low iron melts that coexist with an amphibole-bearing, plagioclase-poor restite. These melt compositions are unlike those of most natural silicic rocks. Thus, dehydration melting over a range of pressures in the crust of island arcs is a plausible mechanism for the petrogenesis of islands arc tonalite, whereas water-saturated melting at pressure of 3 kilobars and above is not.

Adolescent build plotting on body composition chart and the type of diabetes mellitus.

PubMed

Park, Hye Won; Kim, Yong Hyuk; Cho, Myunghyun; Kwak, Byung Ok; Kim, Kyo Sun; Chung, Sochung

2012-11-01

Although the prevalence of type 2 diabetes is increasing, there are cases difficult to categorize into certain type in pediatric diabetic patients. The aims of this study were to detect and choose a proper treatment modality for atypical cases of diabetes mellitus, using the body composition chart. We conducted a retrospective study from August 2005 to 2012 with patients who visited Konkuk University Medical Center, and were diagnosed with diabetes mellitus. The medical records were reviewed for the anthropometric data and indices of body composition. The subjects were grouped by the type of diabetes and gender. We constructed a body composition chart plotting fat free mass index and fat mass index (FMI). Body mass index and all body composition indices were higher in type 2 diabetes, in each gender in analysis with Mann-Whitney test. Significant determinant of diabetes type was revealed as FMI and contributing factors on FMI were analyzed with regression analysis. Six atypical cases were identified by a body composition chart including non-obese type 2 diabetes showing suboptimal growth with lower BMI related to relatively lower insulin secretion and type 1 diabetes with insulin resistance resulted from obesity. Body composition chart analysis might be useful in characterization of diabetes type and detection of atypical cases and early adjustment of diabetes management strategy.

Field guide to the Mesozoic arc and accretionary complex of South-Central Alaska, Indian to Hatcher Pass

USGS Publications Warehouse

Karl, Susan M.; Oswald, P.J.; Hults, Chad P.

2015-01-01

This field trip traverses exposures of a multi-generation Mesozoic magmatic arc and subduction-accretion complex that had a complicated history of magmatic activity and experienced variations in composition and deformational style in response to changes in the tectonic environment. This Mesozoic arc formed at an unknown latitude to the south, was accreted to North America, and was subsequently transported along faults to its present location (Plafker and others, 1989; Hillhouse and Coe, 1994). Some of these faults are still active. Similar tectonic, igneous, and sedimentary processes to those that formed the Mesozoic arc complex persist today in southern Alaska, building on, and deforming the Mesozoic arc. The rocks we will see on this field trip provide insights on the three-dimensional composition of the modern arc, and the processes involved in the evolution of an arc and its companion accretionary complex.

Composition of island arcs and continental growth.

NASA Technical Reports Server (NTRS)

Jakes, P.; White, A. J. R.

1971-01-01

Island arc volcanism has contributed and is still contributing to continental growth, but the composition of island arcs differs from that of the upper continental crust in its lower abundance of Si, K, Rb, Ba, Sr and light rare earth elements. In their advanced stage of evolution, island arcs contain more than 80% of tholeiitic and 15% of ?island arc' calc-alkaline rocks with varied SiO2 contents. The larger proportion of tholeiitic rocks is in the lower crustal levels. The high stratigraphical levels of the island arcs are composed of tholeiitic plus calc-alkaline and/or high potash (shoshonitic) associations with higher abundances of K, Rb, Sr, and Ba. Stratification of the island arc crust is accentuated by another type of calc-alkaline volcanism (Andean type) originating at a late stage of arc evolution, probably by partial melting at the base of the crust. This causes enrichment of the upper crust in K, Rb, Ba and REE and accounts for upper crustal abundances of these elements as well as of SiO2.

Silica-enriched mantle sources of subalkaline picrite-boninite-andesite island arc magmas

NASA Astrophysics Data System (ADS)

Bénard, A.; Arculus, R. J.; Nebel, O.; Ionov, D. A.; McAlpine, S. R. B.

2017-02-01

Primary arc melts may form through fluxed or adiabatic decompression melting in the mantle wedge, or via a combination of both processes. Major limitations to our understanding of the formation of primary arc melts stem from the fact that most arc lavas are aggregated blends of individual magma batches, further modified by differentiation processes in the sub-arc mantle lithosphere and overlying crust. Primary melt generation is thus masked by these types of second-stage processes. Magma-hosted peridotites sampled as xenoliths in subduction zone magmas are possible remnants of sub-arc mantle and magma generation processes, but are rarely sampled in active arcs. Published studies have emphasised the predominantly harzburgitic lithologies with particularly high modal orthopyroxene in these xenoliths; the former characteristic reflects the refractory nature of these materials consequent to extensive melt depletion of a lherzolitic protolith whereas the latter feature requires additional explanation. Here we present major and minor element data for pristine, mantle-derived, lava-hosted spinel-bearing harzburgite and dunite xenoliths and associated primitive melts from the active Kamchatka and Bismarck arcs. We show that these peridotite suites, and other mantle xenoliths sampled in circum-Pacific arcs, are a distinctive peridotite type not found in other tectonic settings, and are melting residues from hydrous melting of silica-enriched mantle sources. We explore the ability of experimental studies allied with mantle melting parameterisations (pMELTS, Petrolog3) to reproduce the compositions of these arc peridotites, and present a protolith ('hybrid mantle wedge') composition that satisfies the available constraints. The composition of peridotite xenoliths recovered from erupted arc magmas plausibly requires their formation initially via interaction of slab-derived components with refractory mantle prior to or during the formation of primary arc melts. The liquid compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe ('calc-alkaline') andesite-dacite-rhyolite suites, key lithologies forming the continental crust.

Magma Differentiation Processes That Develop an "Enriched" Signature in the Izu Bonin Rear Arc: Evidence from Drilling at IODP Site U1437

NASA Astrophysics Data System (ADS)

Heywood, L. J.; DeBari, S. M.; Schindlbeck, J. C.; Escobar-Burciaga, R. D.

2015-12-01

The Izu Bonin rear arc represents a unique laboratory to study the development of continental crust precursors at an intraoceanic subduction zone., Volcanic output in the Izu Bonin rear arc is compositionally distinct from the Izu Bonin main volcanic front, with med- to high-K and LREE-enrichment similar to the average composition of the continental crust. Drilling at IODP Expedition 350 Site U1437 in the Izu Bonin rear arc obtained volcaniclastic material that was deposited from at least 13.5 Ma to present. IODP Expedition 350 represents the first drilling mission in the Izu Bonin rear arc region. This study presents fresh glass and mineral compositions (obtained via EMP and LA-ICP-MS) from unaltered tephra layers in mud/mudstone (Lithostratigraphic Unit I) and lapillistone (Lithostratigraphic Unit II) <4.5 Ma to examine the geochemical signature of Izu Bonin rear arc magmas. Unit II samples are coarse-grained tephras that are mainly rhyolitic in composition (72.1-77.5 wt. % SiO2, 3.2-3.9 wt. % K2O and average Mg# 24) and LREE-enriched. These rear-arc rhyolites have an average La/Sm of 2.6 with flat HREEs, average Th/La of 0.15, and Zr/Y of 4.86. Rear-arc rhyolite trace element signature is distinct from felsic eruptive products from the Izu Bonin main volcanic front, which have lower La/Sm and Th/La as well as significantly lower incompatible element concentrations. Rear arc rhyolites have similar trace element ratios to rhyolites from the adjacent but younger backarc knolls and actively-extending rift regions, but the latter is typified by lower K2O, as well as a smaller degree of enrichment in incompatible elements. Given these unique characteristics, we explore models for felsic magma formation and intracrustal differentiation in the Izu Bonin rear arc.

The arc arises: The links between volcanic output, arc evolution and melt composition

NASA Astrophysics Data System (ADS)

Brandl, Philipp A.; Hamada, Morihisa; Arculus, Richard J.; Johnson, Kyle; Marsaglia, Kathleen M.; Savov, Ivan P.; Ishizuka, Osamu; Li, He

2017-03-01

Subduction initiation is a key process for global plate tectonics. Individual lithologies developed during subduction initiation and arc inception have been identified in the trench wall of the Izu-Bonin-Mariana (IBM) island arc but a continuous record of this process has not previously been described. Here, we present results from International Ocean Discovery Program Expedition 351 that drilled a single site west of the Kyushu-Palau Ridge (KPR), a chain of extinct stratovolcanoes that represents the proto-IBM island arc, active for ∼25 Ma following subduction initiation. Site U1438 recovered 150 m of oceanic igneous basement and ∼1450 m of overlying sediments. The lower 1300 m of these sediments comprise volcaniclastic gravity-flow deposits shed from the evolving KPR arc front. We separated fresh magmatic minerals from Site U1438 sediments, and analyzed 304 glass (formerly melt) inclusions, hosted by clinopyroxene and plagioclase. Compositions of glass inclusions preserve a temporal magmatic record of the juvenile island arc, complementary to the predominant mid-Miocene to recent activity determined from tephra layers recovered by drilling in the IBM forearc. The glass inclusions record the progressive transition of melt compositions dominated by an early 'calc-alkalic', high-Mg andesitic stage to a younger tholeiitic stage over a time period of 11 Ma. High-precision trace element analytical data record a simultaneously increasing influence of a deep subduction component (e.g., increase in Th vs. Nb, light rare earth element enrichment) and a more fertile mantle source (reflected in increased high field strength element abundances). This compositional change is accompanied by increased deposition rates of volcaniclastic sediments reflecting magmatic output and maturity of the arc. We conclude the 'calc-alkalic' stage of arc evolution may endure as long as mantle wedge sources are not mostly advected away from the zones of arc magma generation, or the rate of wedge replenishment by corner flow does not overwhelm the rate of magma extraction.

The Continental Margin of East Asia: a collage of multiple plates formed by convergence and extension from multiple directions

NASA Astrophysics Data System (ADS)

Mao, J.; Wang, T.; Ludington, S.; Qiu, Z.; Li, Z.

2017-12-01

East Asia is one of the most complex regions in the world. Its margin was divided into 4 parts: Northeast Asia, North China, South China and Southeast Asia. During the Phanerozoic, continental plates of East Asia have interacted successively with a) the Paleo Tethyan Ocean, b) the Tethyan and Paleo Pacific Oceans and c) the Pacific and Indian. In the Early Mesozoic, the Indosinian orogeny is characterized by the convergence and extension within multiple continental plates, whereas the Late Mesozoic Yanshanian orogeny is characterized by both convergence and compression due to oceanic subduction and by widespread extension. We propose this combination as "East Asia Continental Margin type." Except in Northeast Asia, where Jurassic and Cretaeous accretionary complexes are common, most magmatic rocks are the result of reworking of ancient margins of small continental plates; and oceanic island arc basalts and continental margin arc andesites are largely absent. Because South China is adjacent to the western margin of the Pacific Plate, some effects of its westward subduction must be unavoidable, but juvenile arc-related crust has not been identified. The East Asian Continental Margin is characterized by magmatic rocks that are the result of post-convergent tectonics, which differs markedly from the active continental margins of both South and North America. In summary, the chief characteristics of the East Asian Continental Margin are: 1) In Mesozoic, the periphery of multiple blocks experienced magmatism caused by lithospheric delamination and thinning in response to extension punctuated by shorter periods of convergence. 2) The main mechanism of magma generation was the partial melting of crustal rocks, due to underplating by upwelling mafic magma associated with the collapse of orogenic belts and both extension and compression between small continental blocks. 3) During orogeny, mostly high Sr/Y arc-related granitoids formed, whereas during post-orogenic times, A-type granitoids formed. 4) These dynamics are the result of subduction and extension of the oceanic plates that bordered East Asia. 5) The complex mosaic of geology and geochemistry is the result of compositional variation in the deep lithosphere, as well as variation in the dynamics of oceanic plate movements.

Geochronological, geochemical and Sr-Nd-Hf isotopic constraints on the petrogenesis of Late Cretaceous A-type granites from the Sibumasu Block, Southern Myanmar, SE Asia

NASA Astrophysics Data System (ADS)

Jiang, Hai; Li, Wen-Qian; Jiang, Shao-Yong; Wang, He; Wei, Xiao-Peng

2017-01-01

The Late Cretaceous to Paleogene granitoids occur widespread in the Sibumasu block within Myanmar (SE Asia), which show a close association with tin-tungsten mineralization. However, the precise timing, petrogenesis and tectonic significance of these granitoids are poorly constrained so far. In this study, we present a detailed study on geochronology, elemental and Sr-Nd-Hf isotopic geochemistry for the Hermyingyi and Taungphila granites in southern Myanmar, with the aim of determining their petrogenesis and tectonic implications. LA-ICP-MS U-Pb dating of zircon grains from the two granites yield ages of 69-70 Ma, indicating a Late Cretaceous magmatic event. These granitic rocks are weakly peraluminous and belong to the high-K calc-alkaline series. They are both characterized by high SiO2, K2O + Na2O, FeOT/(FeOT + MgO) and Ga/Al ratios and low Al2O3, CaO, MgO, P2O5 and TiO2 contents, enriched in Rb, Th, U and Y, but depleted in Ba, Sr, P, and Eu, suggesting an A-type granite affinity. Moreover, they display prominent tetrad REE patterns and non-CHARAC trace element behavior, which are common in late magmatic differentiates with strong hydrothermal interaction or deuteric alteration. The granites belong to A2-type and probably formed at a high temperature and anhydrous condition. They have zircon εHf(t) values from - 12.4 to - 10.0 and whole-rock εNd(t) values from - 11.3 to - 10.6, with Paleoproterozoic TDM2 ages (1741-1922 Ma) for both Hf and Nd isotopes. Geochemical and isotopic data suggest that these A-type granites were derived from partial melting of the Paleoproterozoic continental crust dominated by metaigneous rocks with tonalitic to granodioritic compositions, without significant input of mantle-derived magma and followed by subsequent fractional crystallization. By integrating all available data for the regional tectonic evolution in SE Asia and adjacent regions, we attribute the formation of the Late Cretaceous A-type granites to a back-arc extension in the hinterland behind the subduction zone, which is induced by the rollback of the flat Neo-Tethyan subducting slab around ca. 70 Ma. Table 2 Major (wt.%) and trace element (ppm) compositions from the Hermyingyi and Taungphila granites. LOI is loss on ignition; A/CNK = Al2O3/(CaO + Na2O + K2O) (molar ratio); FeOT = FeO + Fe2O3 × 0.8998. Eu/Eu* is a measure of the Eu anomaly when compare to Sm and Gd. Eu/Eu* = EuN/[(SmN) × (GdN)]0.5. Table 3 Sr-Nd isotopic compositions of the Hermyingyi and Taungphila granites. Table 4 Hf isotopic compositions of zircons from the Hermyingyi and Taungphila granites. (176Lu/177Hf)CHUR = 0.0032, (176Hf/177Hf)CHUR,0 = 0.282772 (Blichert-Toft and Albarède, 1997); (176Lu/177Hf)DM = 0.0384, (176Hf/177Hf)DM,0 = 0.28325 (Griffin et al., 2000); λ = 1.867 × 10- 11/year (Soderlund et al., 2004).

IODP Expedition 351 Lithostratigraphy: Volcaniclastic Record of Izu-Bonin-Mariana (IBM) Arc Initiation

NASA Astrophysics Data System (ADS)

Barth, A. P.; Brandl, P. A.; Li, H.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Tepley, F. J., III; Yogodzinski, G. M.

2014-12-01

The destruction of lithospheric plates by subduction is a fundamentally important process leading to arc magmatism and the creation of continental crust, yet subduction initiation and early magmatic arc evolution remain poorly understood. For many arc systems, onset of arc volcanism and early evolution are obscured by metamorphism or the record is deeply buried; however, initial products of arc systems may be preserved in forearc and backarc sedimentary records. IODP Expedition 351 recovered this history from the dispersed ash and pyroclast record in the proximal rear-arc of the northern IBM system west of the Kyushu-Palau Ridge. Drilling at Site U1438 in the Amami Sankaku Basin recovered a thick volcaniclastic record of subduction initiation and the early evolution of the Izu-Bonin Arc. A 160-m thick section of Neogene sediment overlies 1.3 kilometers of Paleogene volcaniclastic rocks with andesitic average composition; this volcaniclastic section was deposited on mafic volcanic basement rocks. The thin upper sediment layer is primarily terrigenous, biogenic and volcaniclastic mud and ooze with interspersed ash layers. The underlying Eocene to Oligocene volcaniclastic rocks are 33% tuffaceous mudstone, 61% tuffaceous sandstone, and 6% conglomerate with volcanic and rare sedimentary clasts commonly up to pebble and rarely to cobble size. The clastic section is characterized by repetitive conglomerate and sandstone-dominated intervals with intervening mudstone-dominated intervals, reflecting waxing and waning of coarse arc-derived sediment inputs through time. Volcanic lithic clasts in sandstones and conglomerates range from basalt to rhyolite in composition and include well-preserved pumice, reflecting a lithologically diverse and compositionally variable arc volcanic source.

Composite-Metal-Matrix Arc-Spray Process

NASA Technical Reports Server (NTRS)

Westfall, Leonard J.

1987-01-01

Arc-spray "monotape" process automated, low in cost, and produces at high rate. Ideal for development of new metal-matrix composites. "Monotape" reproducible and of high quality. Process carried out in controlled gas environment with programmable matrix-deposition rates, resulting in significant cost saving

Surface Catalysis and Oxidation on Stagnation Point Heat Flux Measurements in High Enthalpy Arc Jets

NASA Technical Reports Server (NTRS)

Nawaz, Anuscheh; Driver, David M.; Terrazas-Salinas

2013-01-01

Heat flux sensors are routinely used in arc jet facilities to determine heat transfer rates from plasma plume. The goal of this study is to assess the impact of surface composition changes on these heat flux sensors. Surface compositions can change due to oxidation and material deposition from the arc jet. Systematic surface analyses of the sensors were conducted before and after exposure to plasma. Currently copper is commonly used as surface material. Other surface materials were studied including nickel, constantan gold, platinum and silicon dioxide. The surfaces were exposed to plasma between 0.3 seconds and 3 seconds. Surface changes due to oxidation as well as copper deposition from the arc jets were observed. Results from changes in measured heat flux as a function of surface catalycity is given, along with a first assessment of enthalpy for these measurements. The use of cupric oxide is recommended for future heat flux measurements, due to its consistent surface composition arc jets.

Magmatic record of Late Devonian arc-continent collision in the northern Qiangtang, Tibet: Implications for the early evolution of East Paleo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Dan, Wei; Wang, Qiang; Zhang, Xiu-Zheng; Zhang, Chunfu; Tang, Gong-Jian; Wang, Jun; Ou, Quan; Hao, Lu-Lu; Qi, Yue

2018-05-01

Recognizing the early-developed intra-oceanic arc is important in revealing the early evolution of East Paleo-Tethys Ocean. In this study, new SIMS zircon U-Pb dating, O-Hf isotopes, and whole-rock geochemical data are reported for the newly-discovered Late Devonian-Early Carboniferous arc in Qiangtang, central Tibet. New dating results reveal that the eastern Riwanchaka volcanic rocks were formed at 370-365 Ma and were intruded by the 360 Ma Gangma Co alkali feldspar granites. The volcanic rocks consist of basalts, andesites, dacites, and rhyodacites, whose geochemistry is similar to that typical of subduction-related volcanism. The basalts and andesites were generated by partial melting of the fluid and sediment-melt metasomatized mantle, respectively. The rhyodacites and dacites were probably derived from the fractional crystallization of andesites and from partial melting of the juvenile underplated mafic rocks, respectively. The Gangma Co alkali feldspar granites are A-type granites, and were possibly derived by partial melting of juvenile underplated mafic rocks in a post-collisional setting. The 370-365 Ma volcanic arc was characterized by basalts with oceanic arc-like Ce/Yb ratios and by rhyodacites with mantle-like or slightly higher zircon δ18O values, and it was associated with the contemporary ophiolites. Thus, we propose that it is the earliest intra-oceanic arc in the East Paleo-Tethys Ocean, and was accreted to the Northern Qiangtang Terrane during 365-360 Ma.

Early Carboniferous magmatism in Lhasa generated in passive continental margin: constrained by new SIMS dating from Carboniferous arc in Qiantang terrane, Tibet

NASA Astrophysics Data System (ADS)

Zhang, X. Z.; Dan, W.; Wang, Q.; Hao, L. L.; Qi, Y.

2016-12-01

In today's oceans, they are rarely undergone subduction on one side and extension on the opposite side. In contrast, there are a few magmatisms in the passive continental margins in the Tethys Ocean. However, because of their long and complex evolution of the northern continental margin of the Gondwana, the geodynamics of the magmatism occurred in this area is speculative or highly depute. One of these examples is the geodynamics of the 360-350 Ma magmatism in southern Lhasa, Tibet. Many authors speculated that it was generated in back-arc setting. Our recent new high-resolution SIMS zircon U-Pb dating reveals that there is a subduction arc with ages of 370-350 Ma in the Qiangtang terrane. The arc rocks compose of andesites, plagiogranites, A-type granites and cumulated gabbros, indicating an initial subduction. This initial subduction arc is located on the north margin of the eastern Paleo-Tethys Ocean, and it was formed slightly earlier than the 360-350 Ma magmatism in southern Lhasa, located on the south margin of the eastern Paleo-Tethys Ocean. Combined with similar aged magmatism generating the back-arc basin in the Sanjiang area, the 360-350 Ma magmatism in southern Lhasa was proposed to be generated in a passive continental margin, and induced by the regional extensional setting related to the subduction in the north margin of the eastern Paleo-Tethys Ocean.

Simulations of Atmospheric Plasma Arcs

NASA Astrophysics Data System (ADS)

Pearcy, Jacob; Chopra, Nirbhav; Jaworski, Michael

2017-10-01

We present the results of computer simulation of cylindrical plasma arcs with characteristics similar to those predicted to be relevant in magnetohydrodynamic (MHD) power conversion systems. These arcs, with core temperatures on the order of 1 eV, place stringent limitations on the lifetime of conventional electrodes used in such systems, suggesting that a detailed analysis of arc characteristics will be crucial in designing more robust electrode systems. Simulations utilize results from NASA's Chemical Equilibrium with Applications (CEA) program to solve the Elenbaas-Heller equation in a variety of plasma compositions, including approximations of coal-burning plasmas as well as pure gas discharges. The effect of carbon dioxide injection on arc characteristics, emulating discharges from molten carbonate salt electrodes, is also analyzed. Results include radial temperature profiles, composition maps, and current-voltage (IV) characteristics of these arcs. Work supported by DOE contract DE-AC02-09CH11466.

Effect of Si on DC arc plasma generation from Al-Cr and Al-Cr-Si cathodes used in oxygen

NASA Astrophysics Data System (ADS)

Zhirkov, I.; Landälv, L.; Göthelid, E.; Ahlgren, M.; Eklund, P.; Rosen, J.

2017-02-01

Al2O3 alloyed with Cr is an important material for the tooling industry. It can be synthesized from an arc discharge using Al-Cr cathodes in an oxygen atmosphere. Due to formation of Al-rich oxide islands on the cathode surface, the arc process stability is highly sensitive to oxygen pressure. For improved stability, the use of Al0.70Cr0.25Si0.05 cathodes has previously been suggested, where Si may reduce island formation. Here, we have investigated the effect of Si by comparing plasma generation and thin film deposition from Al0.7Cr0.3 and Al0.7Cr0.25Si0.05 cathodes. Plasma ion composition, ion energies, ion charge states, neutral species, droplet formation, and film composition have been characterized at different O2 flow rates for arc currents of 60 and 90 A. Si and related compounds are detected in plasma ions and in plasma neutrals. Scanning electron microscopy and energy dispersive X-ray analysis show that the cathode composition and the film composition are the same, with Si present in droplets as well. The effect of Si on the process stability, ion energies, and ion charge states is found to be negligible compared to that of the arc current. The latter is identified as the most relevant parameter for tuning the properties of the reactive discharge. The present work increases the fundamental understanding of plasma generation in a reactive atmosphere, and provides input for the choice of cathode composition and process parameters in reactive DC arc synthesis.

Oxidation of boron nitride in an arc heated jet.

NASA Technical Reports Server (NTRS)

Buckley, J. D.

1971-01-01

Two grades of hot pressed boron nitride and a boron nitride composite were subjected to oxidation tests in a 2.5 megawatt atmospheric arc jet. The results showed that fabrication and/or composition influenced thermal shock and oxidation resistance. Changes in surface structure and recession due to oxidation suggest correlation with specimen composition. The boron nitride composite reacted with the oxygen in the hot subsonic airstream to produce a glassy coating on the hot face surface.

Research Progress in Plasma arc welding of Magnesium Alloys and Magnesium Matrix Composites

NASA Astrophysics Data System (ADS)

Hui, Li; Yang, Zou; Yongbo, Li; Lei, Jiao; Ruijun, Hou

2017-11-01

Magnesium alloys and magnesium matrix composites by means of its excellent performance have wide application prospect in electronics, automotive, biotechnology, aerospace field, and welding technology has become a key of restricting its application. This paper describes the welding characteristics of magnesium, the obvious advantages in the application and the domestic and foreign research advance technology of plasma arc welding of magnesium, and summarizes the existing problems and development trends of plasma arc welding technology of magnesium.

Construction of Continental Crust at the Central American and Philippines Arc Systems

NASA Astrophysics Data System (ADS)

Whattam, S. A.; Stern, R. J.

2016-12-01

Whether or not magmatic arcs evolve compositionally with time and the processes responsible remain controversial. Resolution of this question requires reconstructing arc geochemical evolution at the level of discrete arc systems, as has been done for IBM, Central America, and the Greater Antilles. Emphasis should be on arcs built on oceanic crust because interaction with continental crust complicates interpretations. The Philippines are a particularly attractive target because this may be the best example where proto-continental crust has been generated and processed in Cretaceous and younger time. Here, we show how this question could be addressed for the Philippines using the well-studied Central American Volcanic Arc System (CAVAS) as an example. For the CAVAS, we avoided the northern arc segment because these are (Guatemala) or maybe (El Salvador) sections built on continental crust. Geochemical and isotopic data were compiled for 1031 samples of lavas and intrusive rocks from the 1100 km-long segment built on thickened, initially plume-derived oceanic crust over its 75 million year lifespan (Panama, Costa Rica, Nicaragua) . The most striking observation is the overall evolution of the CAVAS to more incompatible element enriched and ultimately continental-like compositions with time. Models entailing progressive arc magmatic enrichment are generally supported by the CAVAS record. Progressive enrichment of the oceanic CAVAS with time reflects changes in mantle wedge composition and decreased melting due to arc crust thickening, which was kick-started by the involvement of enriched plume mantle. Progressive crustal thickening and associated changes in the sub-arc thermal regime resulted in decreasing degrees of partial melting over time, which allowed for progressive enrichment of the CAVAS and ultimately the production of continental-like crust in Panama and Costa Rica by 16-10 Ma. Our similar study of the Philippine Arc system is in its infancy but earlier studies have shown that older magmatic rocks are tholeiitic and MORB-like whereas younger ones are invariably calc-alkaline and arc-like. Results of the Philippines Arc study will be compared with the CAVAS and other magmatic arc systems comprised of continental crust.

Geochemical Relationships between Middle- to Upper-Crustal Exposures of the Alisitos Oceanic Arc (Baja California, Mexico): An Outstanding Field Analog to Active Extensional Oceanic Arcs

NASA Astrophysics Data System (ADS)

Morris, R.; DeBari, S. M.; Busby, C.; Medynski, S.

2016-12-01

The southern volcano-bounded basin of the Rosario segment of the Cretaceous Alisitos oceanic arc provides outstanding 3-D exposures of an extensional arc, where crustal generation processes are recorded in the upper-crustal volcanic units and underlying middle-crustal plutonic rocks. Geochemical linkages between exposed crustal levels provide an analog for extensional arc systems such as the Izu-Bonin-Mariana (IBM) Arc. Upper-crustal units comprise a 3-5 km thick volcanic-volcaniclastic stratigraphy with hypabyssal intrusions. Deep-seated plutonic rocks intrude these units over a transition of <500m, where rafted volcanic blocks and evidence of magma mingling are exposed. Thermobarometry suggests <6 km emplacement depths. Compositional ranges (basalt to rhyolite) and mineral assemblages are similar in both middle-crustal and upper-crustal units, with striking compositional overlap. The most mafic compositions occur in upper-crustal hypabyssal units, and as amphibole cumulates in the plutonic rocks ( 51% SiO2). The most felsic compositions occur in welded ignimbrites and a tonalite pluton ( 71% SiO2). All units are low K with flat REE patterns, and show LILE enrichment and HFSE depletion. Trace element ratios show limited variation throughout the crustal section. Zr/Y and Nb/Y ratios are similar to the Izu active ( 3 Ma to present) zone of extension immediately behind the arc front, suggesting comparable mantle melt % during extension. Th/Zr ratios are more enriched in Alisitos compared to Izu, suggesting greater subducted sediment input. The Alisitos crustal section shows a limited range in ɛNd (5.7-7.1), but a wider range in 87Sr/86Sr (0.7035-0.7055) and 206Pb/204Pb (18.12-19.12); the latter is likely alteration effects. Arc magmas were derived from a subduction-modified MORB mantle source, less depleted than Izu arc front and less enriched than the rear arc, but is a good match with the zone of extension that lies between. Differentiation occurred in a closed system (i.e., fractional crystallization/self-melting with back mixing), producing the entire crustal section in <3 Ma.

Hydrogen storage and hydrolysis properties of core-shell structured Mg-MFx (M=V, Ni, La and Ce) nano-composites prepared by arc plasma method

NASA Astrophysics Data System (ADS)

Mao, Jianfeng; Zou, Jianxin; Lu, Chong; Zeng, Xiaoqin; Ding, Wenjiang

2017-10-01

In this work, core-shell structured Mg-MFx (M = V, Ni, La and Ce) nano-composites are prepared by using arc plasma method. The particle size distribution, phase components, microstructures, hydrogen sorption properties of these composites and hydrolysis properties of their corresponding hydrogenated powders are carefully investigated. It is shown that the addition of MFx through arc plasma method can improve both the hydrogen absorption kinetics of Mg and the hydrolysis properties of corresponding hydrogenated powders. Among them, the Mg-NiF2 composite shows the best hydrogen absorption properties at relatively low temperatures, which can absorb 3.26 wt% of H2 at 373 K in 2 h. Such rapid hydrogen absorption rate is mainly due to the formation of Mg2Ni and MgF2 on Mg particles during arc evaporation and condensation. In contrast, measurements also show that the hydrogenated Mg-VF3 composite has the lowest peak desorption temperature and the fastest hydrolysis rate among all the hydrogenated Mg-MFx composites. The less agglomeration tendency of Mg particles and VO2 covered on MgH2 particles account for the reduced hydrogen desorption temperature and enhanced hydrolysis rate.

Ankaramite: A New Type of High-Magnesium and High-Calcium Primitive Melt in the Magnitogorsk Island-Arc Zone (Southern Urals)

NASA Astrophysics Data System (ADS)

Pushkarev, E. V.; Ryazancev, A. V.; Gottman, I. A.; Degtyarev, K. E.; Kamenetsky, V. S.

2018-04-01

This work describes the geological position, mineral and chemical composition of high-Mg effusive ankaramites occurring as dykes and lava flows. They were found in the mélange zone of the western margin of the Magnitogorsk island arc zone in the Southern Urals. Data on the liquidus association of phenocrysts and on the composition of the matrix of effusives are given. According to the data obtained, the conclusion was drawn that the ankaramites studied can be attributed to the primary island arc melts, which were not subject to essential differentiation. This type of effusives has not been distinguished previously among island arc volcanogenic formations of the Urals. It is shown that ankaramites can be considered to be primary melts parental for dunite-clinopyroxenites-gabbro complexes of Ural-Alaskan type. The occurrence of ankaramites in the Paleozoic island arc formations of the Urals indicates the wehrlite composition of the mantle as the reason for the extremely wide development of wehrlites and clinopyroxenites in different mafic-ultramafic complexes of the Urals.

Geochemical differentiation processes for arc magma of the Sengan volcanic cluster, Northeastern Japan, constrained from principal component analysis

NASA Astrophysics Data System (ADS)

Ueki, Kenta; Iwamori, Hikaru

2017-10-01

In this study, with a view of understanding the structure of high-dimensional geochemical data and discussing the chemical processes at work in the evolution of arc magmas, we employed principal component analysis (PCA) to evaluate the compositional variations of volcanic rocks from the Sengan volcanic cluster of the Northeastern Japan Arc. We analyzed the trace element compositions of various arc volcanic rocks, sampled from 17 different volcanoes in a volcanic cluster. The PCA results demonstrated that the first three principal components accounted for 86% of the geochemical variation in the magma of the Sengan region. Based on the relationships between the principal components and the major elements, the mass-balance relationships with respect to the contributions of minerals, the composition of plagioclase phenocrysts, geothermal gradient, and seismic velocity structure in the crust, the first, the second, and the third principal components appear to represent magma mixing, crystallizations of olivine/pyroxene, and crystallizations of plagioclase, respectively. These represented 59%, 20%, and 6%, respectively, of the variance in the entire compositional range, indicating that magma mixing accounted for the largest variance in the geochemical variation of the arc magma. Our result indicated that crustal processes dominate the geochemical variation of magma in the Sengan volcanic cluster.

Vacuum arc behavior and its voltage characteristics in drawing process controlled by composite magnetic fields along axial and transverse directions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Lijun, E-mail: lijunwang@mail.xjtu.edu.cn; Deng, Jie; Wang, Haijing

In this research, drawing vacuum arc (VA) experiments were conducted using composite contacts under currents ranging from 5 kA to 20 kA root mean square (rms). The new type of contact comprised an axial magnetic field (AMF) configuration and a transverse magnetic field (TMF) configuration. The TMF plate was in the center, surrounded by the AMF plate. The contact generated both AMFs and TMFs simultaneously. VA appearances and arc voltages were recorded, and the VA was modeled as a conductor for electromagnetic force analysis in ANSYS software. The results showed that the coaxiality of operating mechanisms significantly influenced arc behavior just asmore » the arc was ignited. When arc brightness did not increase after ignition, there was a voltage drop accompanied with diffusion of the VA. As to VA development, when an arc was ignited on an AMF plate, it spread on the plate and rotated. Over time the arc current increased, the constricting arc forms, and the arc column rotated on the TMF plate under the action of Ampere's force. With regard to the influence of a magnetic field on a VA at different stages, in the initial drawing arc stage the TMF was dominant, and the arc started to rotate under the action of Ampere's force. Afterwards, the AMF was dominant, with a steadily burning arc. As for contact melting, in the initial arcing period, a contracted short arc caused severe melting and erosion of the contact plate. When the ignition spot or root was close to the slot of plate, the electromagnetic force pushed the arc toward slot and contact edge, resulting in local erosion of the slot region.« less

Rear-arc vs. arc-front volcanoes in the Katmai reach of the Alaska Peninsula: A critical appraisal of across-arc compositional variation

USGS Publications Warehouse

Hildreth, W.; Fierstein, J.; Siems, D.F.; Budahn, J.R.; Ruiz, J.

2004-01-01

Physical and compositional data and K-Ar ages are reported for 14 rear-arc volcanoes that lic 11-22 km behind the narrowly linear volcanic front defined by the Mount Katmai-to-Devils Desk chain on the Alaska Peninsula. One is a 30-km3 stratocone (Mount Griggs; 51-63% SiO2) active intermittently from 292 ka to Holocene. The others are monogenetic cones, domes, lava flows, plugs, and maars, of which 12 were previously unnamed and unstudied; they include seven basalts (48-52% SiO2), four mafic andesites (53-55% SiO2), and three andesite-dacite units. Six erupted in the interval 500-88 ka, one historically in 1977, and five in the interval 3-2 Ma. No migration of the volcanic front is discernible since the late Miocene, so even the older units erupted well behind the front. Discussion explores the significance of the volcanic front and the processes that influence compositional overlaps and differences among mafic products of the rear-arc volcanoes and of the several arc-front edifices nearby. The latter have together erupted a magma volume of about 200 km3, at least four times that of all rear-arc products combined. Correlation of Sr-isotope ratios with indices of fractionation indicates crustal contributions in volcanic-front magmas (0.7033-0.7038), but lack of such trends among the rear-arc units (0.70298-0.70356) suggests weaker and less systematic crustal influence. Slab contributions and mantle partial-melt fractions both appear to decline behind the front, but neither trend is crisp and unambiguous. No intraplate mantle contribution is recognized nor is any systematic across-arc difference in intrinsic mantle-wedge source fertility discerned. Both rear-arc and arc-front basalts apparently issued from fluxing of typically fertile NMORB-source mantle beneath the Peninsular terrane, which docked here in the Mesozoic. ?? Springer-Verlag 2004.

Nd, Pb, Sr, and O isotopic characterization of Saudi Arabian Shield terranes

USGS Publications Warehouse

Stoeser, D.B.; Frost, C.D.

2006-01-01

New Nd, Sr and O isotopic data for granitoid rocks of the Saudi Arabian Shield are presented together with published Nd, Pb, Sr and O isotopic data and all available geologic and geochronologic information to re-evaluate the terranes defined for the Saudi Arabian part of the Arabian-Nubian Shield. Three groups of terranes are identified: 1) the western arc terranes, 2) the eastern arc terranes, and 3) the Khida terrane. The Khida terrane is the only terrane composed of pre-Neoproterozoic continental crust. The western arc terranes are of oceanic arc affinity, and have the least radiogenic Pb and Sr and most radiogenic Nd isotopic compositions and some of the lowest ??18O values of any rocks of the Saudi Arabian Shield. Although some previous studies have characterized the eastern arc terranes as of continental affinity, this study shows that they too are composed of Neoproterozoic oceanic arcs, although their sources have slightly elevated 208Pb/204Pb, Nd, Sri, and ??18O values compared to the western arc terranes. These data suggest that either the isotopic composition of the mantle source for the western arc terranes is more depleted than that of the eastern arc terranes or the eastern arc terranes have been mixed with a small amount of cratonic source material, or both. We further elaborate on the Hulayfah-Ad Dafinah fault zone as a major boundary within the Saudi Arabian portion of the East African Orogen. With further study, its northern extension may be shown to pass through what has been defined as the Hail terrane, and its southern extension appears to lie under cover east of the Tathlith-Malahah terrane and extend into Yemen. It may represent the collision zone between East and West Gondwana, and at the very least it is an important suture between groups of arc terranes of contrasting isotopic composition caught between two converging continents.

Reduced granitic magmas in an arc setting: The Catface porphyry Cu-Mo deposit of the Paleogene Cascade Arc

NASA Astrophysics Data System (ADS)

Smith, C. M.; Canil, D.; Rowins, S. M.; Friedman, R.

2012-12-01

The Catface porphyry Cu (Mo-Au) deposit, Vancouver Island, British Columbia was studied to characterize the age, geometry and geochemical affinity of its different intrusive phases, and their tectonic setting. Four different intrusive phases of quartz diorite are broadly calc-alkaline, moderately metaluminous, and have typical arc geochemical affinity. U-Pb age dating of zircons showing two intrusive phases was emplaced at 41.26 ± 0.11 and 41.15 ± 0.10 Ma, and a second two 40.93 ± 0.11 and 40.88 ± 0.10 (95% confidence). The latter ages are identical to the Re-Os age of molybdenite mineralization of 40.9 ± 0.2 Ma. The depth of emplacement is less than 4 km, as determined by amphibole-plagioclase thermobarometry (630-815 °C and 50-300 MPa). A reduced magmatic-hydrothermal system is evidenced by: (1) presence of pyrrhotite and absence of anhydrite and hematite, (2) low SO3 (< 450 ppm) in apatite, and (3) oxygen fugacities (fO2) of 0.5-3.0 log units below the quartz-fayalite-magnetite (QFM) buffer recorded by the assemblage K-feldspar-biotite-ilmenite-quartz. Reduced porphyry-related magmas on Vancouver Island of similar age to those at North Fork, Washington (37 Ma) suggests consanguinity of reduced arc magmatism and related ore deposits within the Paleogene Cascade arc of the Pacific Northwest. Reduced evolved magmas at Catface are atypical in an arc setting, but can be attributed to thorough degassing of S from the magmas as evidenced by low S in apatite.

Nonlinear system identification of the reduction nickel oxide smelting process in electric arc furnace

NASA Astrophysics Data System (ADS)

Gubin, V.; Firsov, A.

2018-03-01

As the title implies the article describes the nonlinear system identification of the reduction smelting process of nickel oxide in electric arc furnaces. It is suggested that for operational control ratio of components of the charge must be solved the problem of determining the qualitative composition of the melt in real time. The use of 0th harmonic of phase voltage AC furnace as an indirect measure of the melt composition is proposed. Brief description of the mechanism of occurrence and nature of the non-zero 0th harmonic of the AC voltage of the arc is given. It is shown that value of 0th harmonic of the arc voltage is not function of electrical parameters but depends of the material composition of the melt. Processed industrial data are given. Hammerstein-Wiener model is used for description of the dependence of 0th harmonic of the furnace voltage from the technical parameters of melting furnace: the melt composition and current. Recommendations are given about the practical use of the model.

A review of processable high temperature resistant addition-type laminating resins

NASA Technical Reports Server (NTRS)

Serafini, T. T.; Delvigs, P.

1973-01-01

An important finding that resulted from research that was conducted to develop improved ablative resins was the discovery of a novel approach to synthesize processable high temperature resistant polymers. Low molecular weight polyimide prepolymers end-capped with norbornene groups were polymerized into thermo-oxidatively stable modified polyimides without the evolution of void producing volatile materials. This paper reviews basic studies that were performed using model compounds to elucidate the polymerization mechanism of the so-called addition-type polyimides. The fabrication and properties of polyimide/graphite fiber composites using A-type polyimide prepolymer as the matrix are described. An alternate method for preparing processable A-type polyimides by means of in situ polymerization of monomeric reactants on the fiber reinforcement is also described. Polyimide/graphite fiber composite performance at elevated temperatures is presented for A-type polyimides.

Eocene to Oligocene volcanism in the Mariana fore-arc and crustal melting

NASA Astrophysics Data System (ADS)

Hartman, B.; Reagan, M.; Hickey-Vargas, R.; Hanan, B.; Blichert-Toft, J.

2003-04-01

Recently collected volcanic rocks from the Mariana fore-arc islands of Saipan and Rota provide evidence that the genesis of silicic magmas in the IBM system involves extensive crustal melting. Rhyolites from the island of Saipan are unusually high in silica for an oceanic island arc setting. They also are unique in the Izu-Bonin-Mariana (IBM) system in that they erupted during the earliest stages of subduction (45--46 Ma), but have "mature arc" major element, trace element, and isotopic compositions. For example, the rhyolites have flat REE patterns and pronounced negative Nb anomalies. These trace element patterns are nearly identical to those Oligocene (36--32 Ma) "early arc" andesites and dacites on Saipan, Guam, and Rota. All of the aforementioned lavas also have similar 207Pb/204Pb and 208Pb/204Pb values that plot along a trend that stretches from West Philippine basin basalt compositions toward those Pacific siliceous sediments. In contrast, Eocene volcanic rocks from other locations in the IBM arc are basaltic to boninitic and have U-shaped REE patterns and small to nonexistent Nb anomalies. The Pb isotopic compositions of these samples are similar to Pacific basin volcanics and volcanogenic sediments. Mathematical modeling suggests that the Saipan rhyolites were most likely derived by partial melting of an arc-like amphibolite crust and not through crystal fractionation of a "protoarc" boninite series magma. The data and these modelings suggest that a piece of preexisting arc-like amphibolite crust was trapped in the Mariana fore-arc early in its evolution. The Saipan rhyolites were produced by melting this crust at relatively shallow depths.

The importance of mantle wedge heterogeneity to subduction zone magmatism and the origin of EM1

NASA Astrophysics Data System (ADS)

Turner, Stephen J.; Langmuir, Charles H.; Dungan, Michael A.; Escrig, Stephane

2017-08-01

The composition of the convecting asthenospheric mantle that feeds the mantle wedge can be investigated via rear-arc lavas that have minimal slab influence. This "ambient mantle wedge" composition (the composition of the wedge prior to the addition of a slab component) varies substantially both worldwide and within individual arcs. 143Nd/144Nd measurements of rear-arc samples that have minimal slab influence are similar to 143Nd/144Nd in the stratovolcanoes of the adjacent volcanic fronts, suggesting that 143Nd/144Nd of arc-front volcanics are largely inherited from the ambient mantle composition. 143Nd/144Nd correlates with ratios such as Th/U, Zr/Nb, and La/Sm, indicating that these ratios also are strongly influenced by ambient wedge heterogeneity. The same phenomenon is observed among individual volcanoes from the Chilean Southern Volcanic Zone (SVZ), where along-strike variability of the volcanic front tracks that of rear-arc monogenetic volcanics. Depleted mantle wedges are more strongly influenced by slab-derived components than are enriched wedges. This leads to surprising trace element correlations in the global dataset, such as between Pb/Nb and Zr/Nb, which are not explicable by variable compositions or fluxes of slab components. Depleted ambient mantle is present beneath arcs with back-arc spreading; relatively enriched mantle is present adjacent to continents. Ambient mantle wedge heterogeneity both globally and regionally forms isotope mixing trajectories for Sr, Nd and Hf between depleted mantle and EM1-type enriched compositions as represented by Gough Island basalts. Making use of this relationship permits a quantitative match with the SVZ data. It has been suggested that EM1-type mantle reservoirs are the result of recycled lower continental crust, though such models do not account for certain trace element ratios such as Ce/Pb and Nb/U or the surprisingly homogeneous trace element compositions of EM1 volcanics. A model in which the EM1 end-member found in continental arcs is produced by low-degree melt-metasomatism of the sub-continental lithospheric mantle may be more plausible. The 143Nd/144Nd maximum along the SVZ may be a consequence of either rifting and collision of two ancient lithospheric domains or a slab tear. The correspondence of mantle wedge variations with EM1 suggests a potential role for metasomatized sub-continental lithosphere in creating EM1 sources globally.

Assimilation of sediments embedded in the oceanic arc crust: myth or reality?

NASA Astrophysics Data System (ADS)

Bezard, Rachel; Davidson, Jon P.; Turner, Simon; Macpherson, Colin G.; Lindsay, Jan M.; Boyce, Adrian J.

2014-06-01

Arc magmas are commonly assumed to form by melting of sub-arc mantle that has been variably enriched by a component from the subducted slab. Although most magmas that reach the surface are not primitive, the impact of assimilation of the arc crust is often ignored with the consequence that trace element and isotopic compositions are commonly attributed only to varying contributions from different components present in the mantle. This jeopardises the integrity of mass balance recycling calculations. Here we use Sr and O isotope data in minerals from a suite of volcanic rocks from St Lucia, Lesser Antilles arc, to show that assimilation of oceanic arc basement can be significant. Analysis of 87Sr/86Sr in single plagioclase phenocrysts from four Soufrière Volcanic Complex (SVC; St Lucia) hand samples with similar composition (87Sr/86Sr = 0.7089-0.7091) reveals crystal isotopic heterogeneity among hand samples ranging from 0.7083 to 0.7094 with up to 0.0008 difference within a single hand sample. δO18 measurements in the SVC crystals show extreme variation beyond the mantle range with +7.5 to +11.1‰ for plagioclase (n=19), +10.6 to +11.8‰ for quartz (n=10), +9.4 to +9.8‰ for amphibole (n=2) and +9 to +9.5‰ for pyroxene (n=3) while older lavas (Pre-Soufriere Volcanic Complex), with less radiogenic whole rock Sr composition (87Sr/86Sr = 0.7041-0.7062) display values closer to mantle range: +6.4 to +7.9‰ for plagioclase (n=4) and +6 to +6.8‰ for pyroxene (n=5). We argue that the 87Sr/86Sr isotope disequilibrium and extreme δO18 values provide compelling evidence for assimilation of material located within the arc crust. Positive correlations between mineral δO18 and whole rock 87Sr/86Sr, 143Nd/144Nd and 206,207,208Pb/204Pb shows that assimilation seems to be responsible not only for the isotopic heterogeneity observed in St Lucia but also in the whole Lesser Antilles since St Lucia encompasses almost the whole-arc range of isotopic compositions. This highlights the need for detailed mineral-scale investigation of oceanic arc suites to quantify assimilation that could otherwise lead to misinterpretation of source composition and subduction processes.

Silicic melt evolution in the early Izu-Bonin arc recorded in detrital zircons: Zircon U-Pb geochronology and trace element geochemistry for Site U1438, Amami Sankaku Basin

NASA Astrophysics Data System (ADS)

Barth, A. P.; Tani, K.; Meffre, S.; Wooden, J. L.; Coble, M. A.

2016-12-01

Understanding the petrologic evolution of oceanic arc magmas through time is important because these arcs reveal the processes of formation and the early evolution of juvenile continental crust. The Izu-Bonin (IB) arc system has been targeted because it is one of several western Pacific intraoceanic arcs initiated at 50 Ma and because of its prominent spatial asymmetry, with widespread development of relatively enriched rear arc lavas. We examined Pb/U and trace element compositions in zircons recovered at IODP Site 351-U1438 and compared them to regional and global zircon suites. These new arc zircon data indicate that detrital zircons will yield new insights into the generation of IB silicic melts and form a set of useful geochemical proxies for interpreting ancient arc detrital zircon provenance. Project IBM drilling target IBM1 was explored by Expedition 351 at Site U1438, located in the proximal back-arc of the northern Kyushu-Palau Ridge (KPR) at 27.3°N. A 1.2 km thick section of Paleogene volcaniclastic rocks, increasingly lithified and hydrothermally altered with depth, constitutes a proximal rear arc sedimentary record of IB arc initiation and early arc evolution. The ages and compositions of U1438 zircons are compatible with provenance in one or more edifices of the northern KPR and are incompatible with drilling contamination. Melt zircon saturation temperatures and Ti-in-zircon thermometry suggest a provenance in relatively cool and silicic KPR melts. The abundances of selected trace elements with high native concentrations provide insight into the petrogenesis of U1438 detrital zircon host melts, and may be useful indicators of both short and long-term variations in melt compositions in arc settings. The U1438 zircons are slightly enriched in U and LREE and are depleted in Nb compared to zircons from mid-ocean ridges and the Parece-Vela Basin, as predicted for melts in a primitive oceanic arc setting with magmas derived from a highly depleted mantle source. Close age and geochemical affinity of U1438 detrital zircons to igneous zircons in Eocene leucotonalite from the partially exhumed intrusive suite at Komahashi-Daini Seamount in the northernmost KPR suggests that these zircons also can yield insight into the link between silicic volcanism and evolving tonalitic intrusions in the Paleogene IB arc.

Tracing subducted sediment inputs to the Ryukyu arc-Okinawa Trough system: Evidence from thallium isotopes

NASA Astrophysics Data System (ADS)

Shu, Yunchao; Nielsen, Sune G.; Zeng, Zhigang; Shinjo, Ryuichi; Blusztajn, Jerzy; Wang, Xiaoyuan; Chen, Shuai

2017-11-01

Sediments are actively subducted in virtually every arc worldwide. However, quantifying their contributions to arc lavas and thereby establishing budgets of how sediments participate in slab-mantle interaction is challenging. In this contribution we use thallium (Tl) abundances and isotopic compositions of lavas from the Ryukyu arc (including south Kyushu) and its back-arc basin, Okinawa Trough, to investigate the influence of sediments from arc to back-arc. We also present extensive geochemical data for sediments and altered oceanic crust (AOC) outboard of the northern (DSDP Sites 296, 442B, 443 and 444) and central (DSDP Sites 294 and 295) part of the Ryukyu arc. The Tl isotopic compositions of sediments change systematically from lighter outboard of northern Ryukyu arc to heavier outboard of central Ryukyu arc. The feature reflects the dominance of terrigenous material and pelagic sedimentation outboard of the northern and central Ryukyu arc, respectively. Central and northern sections of Ryukyu arc and Okinawa Trough display larger range of Tl isotopic variation than southern section, which is consistent with more pelagic provenance for sediments outboard of central and northern Ryukyu arcs than that of expected sediments outboard of southern Ryukyu arc. Identical Tl, Sr, Nd and Pb isotope variations are found when comparing arc and back arc lavas, which indicates that sediments fluxes also account for the Tl isotopic variations in the Okinawa Trough lavas. Two-end-member mixing models of Tl with Pb, Sr and Nd isotopes require sediment inputs of< 1%, 0.1-1% and 0.3-2% by weight to the depleted mantle source to account for all these isotopic compositions of lavas from northern, central and southern portion of the Ryukyu arc and Okinawa Trough. Bulk mixing between mantle and sediment end members predict very similar sediment fluxes when using Tl, Sr, Nd and Pb isotopes, which indicates that fractionation of these elements must have happened after mixing between mantle and sediments. This conclusion is corroborated by model calculations of mixing between sediment melts with fractionated Sr/Nd ratios and mantle wedge, which show that no arc lava plot on such mixing lines. Thus bulk sediment mixing, rather than sediment melt, is required for the generation of the lavas from the Ryukyu arc and Okinawa Trough. The requirement of bulk sediment mixing occurring before trace element fractionation in the sub-arc mantle is consistent with models where mélange layers form at the top of the slab and are the principle source material for arc lavas. In addition, the fact that sediment components observed in the Ryukyu arc and Okinawa Trough lavas are similar, suggests that transport of mélange material to the source regions of the arc and back arc is equally efficient. This feature is most readily explained if mélange material is transported from the slab as diapirs.

Transformation of juvenile Izu-Bonin-Mariana oceanic arc into mature continental crust: An example from the Neogene Izu collision zone granitoid plutons, Central Japan

NASA Astrophysics Data System (ADS)

Saito, Satoshi; Tani, Kenichiro

2017-04-01

Granitic rocks (sensulato) are major constituents of upper continental crust. Recent reviews reveal that the average composition of Phanerozoic upper continental crust is granodioritic. Although oceanic arcs are regarded as a site producing continental crust material in an oceanic setting, intermediate to felsic igneous rocks occurring in modern oceanic arcs are dominantly tonalitic to trondhjemitic in composition and have lower incompatible element contents than the average upper continental crust. Therefore, juvenile oceanic arcs require additional processes in order to get transformed into mature continental crust enriched in incompatible elements. Neogene granitoid plutons are widely exposed in the Izu Collision Zone in central Japan, where the northern end of the Izu-Bonin-Mariana (IBM) arc (juvenile oceanic arc) has been colliding with the Honshu arc (mature island arc) since Middle Miocene. The plutons in this area are composed of various types of granitoids ranging from tonalite to trondhjemite, granodiorite, monzogranite and granite. Three main granitoid plutons are distributed in this area: Tanzawa plutonic complex, Kofu granitic complex, and Kaikomagatake granitoid pluton. Tanzawa plutonic complex is dominantly composed of tonalite and trondhjemite and characterized by low concentration of incompatible elements and shows geochemical similarity with modern juvenile oceanic arcs. In contrast, Kofu granitic complex and Kaikomagatake granitoid pluton consists mainly of granodiorite, monzogranite and granite and their incompatible element abundances are comparable to the average upper continental crust. Previous petrogenetic studies on these plutons suggested that (1) the Tanzawa plutonic complex formed by lower crustal anatexis of juvenile basaltic rocks occurring in the IBM arc, (2) the Kofu granitic complex formed by anatexis of 'hybrid lower crust' comprising of both basaltic rocks of the IBM arc and metasedimentary rocks of the Honshu arc, and (3) the Kaikomagatake granitoid pluton formed by anatexis of 'hybrid lower crust' consisting of K-rich rear-arc crust of the IBM arc and metasedimentary rocks of the Honshu arc. These studies collectively suggest that the chemical diversity within the Izu Collision Zone granitoid plutons reflects the chemical variation of basaltic sources (i.e., across-arc chemical variation in the IBM arc) as well as variable contribution of the metasedimentary component in the source region. The petrogenetic models of the Izu Collision Zone granitoid plutons suggest that collision with another mature arc/continent, hybrid lower crust formation and subsequent hybrid source anatexis are required for juvenile oceanic arcs to produce granitoid magmas with enriched compositions. The Izu Collision Zone granitoid plutons provide an exceptional example of the collision-induced transformation from a juvenile oceanic arc to the mature continental crust.

Toward Assessing the Causes of Volcanic Diversity in the Cascades Arc

NASA Astrophysics Data System (ADS)

Till, C. B.; Kent, A. J.; Abers, G. A.; Pitcher, B.; Janiszewski, H. A.; Schmandt, B.

2017-12-01

A fundamental unanswered question in subduction system science is the cause of the observed diversity in volcanic arc style at an arc-segment to whole-arc scale. Specifically, we have yet to distinguish the predominant mantle and crustal processes responsible for the diversity of arc volcanic phenomenon, including the presence of central volcanoes vs. dispersed volcanism; episodicity in volcanic fluxes in time and space; variations in magma chemistry; and differences in the extent of magmatic focusing. Here we present a thought experiment using currently available data to estimate the relative role of crustal magmatic processes in producing the observed variations in Cascades arc volcanism. A compilation of available major element compositions of Quaternary arc volcanism and estimates of eruptive volumes are used to examine variations in the composition of arc magmas along strike. We then calculate the Quaternary volcanic heat flux into the crust, assuming steady state, required to produce the observed distribution of compositions via crystallization of mantle-derived primitive magmas vs. crustal melting using experiment constraints on possible liquid lines of descent and crustal melting scenarios. For pure crystallization, heat input into the crust scales with silica content, with dacitic to rhyolite compositions producing significantly greater latent heat relative to basalts to andesites. In contrast, the heat required to melt lower crustal amphibolite decreases with increasing silica and is likely provided by the latent heat of crystallization. Thus we develop maximum and minimum estimates for heat added to the crust at a given SiO2 range. When volumes are considered, we find that the average Quaternary volcanic heat flux at latitudes south of South Sister to be more than twice that to the north. Distributed mafic volcanism produces only a quarter to half the heat flux calculated for the main edifices at a given latitude because of their lesser eruptive volumes and quantities of evolved magma. When we compare our Quaternary heat flux calculations to a variety of geophysical observations, we find that regions of calculated higher volcanic heat flux coincide with regions of significantly lower crustal seismic wave speeds beneath and behind the arc, as well as with regions of significantly higher heat flow.

Characteristics of Atmospheric Pressure Rotating Gliding Arc Plasmas

NASA Astrophysics Data System (ADS)

Zhang, Hao; Zhu, Fengsen; Tu, Xin; Bo, Zheng; Cen, Kefa; Li, Xiaodong

2016-05-01

In this work, a novel direct current (DC) atmospheric pressure rotating gliding arc (RGA) plasma reactor has been developed for plasma-assisted chemical reactions. The influence of the gas composition and the gas flow rate on the arc dynamic behaviour and the formation of reactive species in the N2 and air gliding arc plasmas has been investigated by means of electrical signals, high speed photography, and optical emission spectroscopic diagnostics. Compared to conventional gliding arc reactors with knife-shaped electrodes which generally require a high flow rate (e.g., 10-20 L/min) to maintain a long arc length and reasonable plasma discharge zone, in this RGA system, a lower gas flow rate (e.g., 2 L/min) can also generate a larger effective plasma reaction zone with a longer arc length for chemical reactions. Two different motion patterns can be clearly observed in the N2 and air RGA plasmas. The time-resolved arc voltage signals show that three different arc dynamic modes, the arc restrike mode, takeover mode, and combined modes, can be clearly identified in the RGA plasmas. The occurrence of different motion and arc dynamic modes is strongly dependent on the composition of the working gas and gas flow rate. supported by National Natural Science Foundation of China (No. 51576174), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20120101110099) and the Fundamental Research Funds for the Central Universities (No. 2015FZA4011)

The Kalatongke magmatic Ni-Cu deposits in the Central Asian Orogenic Belt, NW China: product of slab window magmatism?

NASA Astrophysics Data System (ADS)

Li, Chusi; Zhang, Mingjie; Fu, Piaoer; Qian, Zhuangzhi; Hu, Peiqing; Ripley, Edward M.

2012-01-01

The Permian Kalatongke Ni-Cu deposits in the Central Asian Orogenic Belt are among the most important Ni-Cu deposits in northern Xinjiang, western China. The deposits are hosted by three small mafic intrusions comprising mainly norite and diorite. Its tectonic context, petrogenesis, and ore genesis have been highly contested. In this paper, we present a new model involving slab window magmatism for the Kalatongke intrusions. The origin of the associated sulfide ores is explained in the context of this new model. Minor amounts of olivine in the intrusions have Fo contents varying between 71 and 81.5 mol%, which are similar to the predicted values for olivine crystallizing from coeval basalts in the region. Analytic modeling based on major element concentrations suggests that the parental magma of the Kalatongke intrusions and the coeval basalts represent fractionated liquids produced by ˜15% of olivine crystallization from a primary magma, itself produced by 7-8% partial melting of depleted mantle peridotite. Positive ɛ Nd values (+4 to +10) and significant negative Nb anomalies for both intrusive and extrusive rocks can be explained by the mixing of magma derived from depleted mantle with 6-18% of a partial melt derived from the lower part of a juvenile arc crust with a composition similar to coeval A-type granites in the region, plus up to 10% contamination with the upper continental crust. Our model suggests that a slab window was created due to slab break-off during a transition from oceanic subduction to arc-arc or arc-continent collision in the region in the Early Permian. Decompression melting in the upwelling oceanic asthenosphere produced the primary magma. When this magma ascended to pond in the lower parts of a juvenile arc crust, it underwent olivine crystallization and at the same time triggered partial melting of the arc crust. Mixing between these two magmas followed by contamination with the upper crust after the magma ascended to higher crustal levels formed the parental magma of the Kalatongke intrusions. The parental magma of the Kalatongke intrusions was saturated with sulfide upon arrival primarily due to olivine fractional crystallization and selective assimilation of crustal sulfur. Sulfide mineralization in the Kalatongke intrusions can be explained by accumulation of immiscible sulfide droplets by flow differentiation, gravitational settling, and downward percolation which operated in different parts of the intrusions. Platinum-group element (PGE) depletion in the bulk sulfide ores of the Kalatongke deposits was due to depletion in the parental magma which in turn was likely due to depletion in the primary magma. PGE depletion in the primary magma can be explained by a relatively low degree of partial melting of the mantle and retention of coexisting sulfide liquid in the mantle.

Inception and Early Evolution of the Aleutian Arc

NASA Astrophysics Data System (ADS)

Bezard, R.; Hoernle, K.; Hauff, F.; Portnyagin, M.; Werner, R.; Yogodzinski, G.; Jicha, B.; Garbe-Schönberg, D.; Turner, S.; Schaefer, B. F.

2017-12-01

Constraining the timing and style of subduction initiation in the Aleutian system is critical to model the Cenozoic geodynamic evolution of the Pacific. Until now, the oldest ages for the Aleutian arc suggest a subduction inception at c.a. 46-47 Ma. However, the compositions of these samples (arc tholeiites and calc-alkaline rocks) are different from those of typical early-arc sequences found at extensively studied subduction systems (Izu-Bonin-Mariana), dominated by FABs and boninites. Thus, if the FAB/boninite model applies to the Aleutian, the oldest units might not have been recovered yet and the arc inception could have occurred earlier than 47 Ma. To test this hypothesis, we have sampled the lowermost submarine Aleutian sequences at ten forearc and rear-arc localities during the R/V SONNE Cruise 249. We present preliminary whole-rock major and trace element concentrations, Sr-Nd-Hf-Pb isotopes as well as U-Pb zircon dating on the recovered igneous rocks. The sample compositions range from tholeiitic to calc-alkaline. No boninites were found. Most of the samples show strong subduction signatures. However, the remaining rocks present no or minor arc-type trace element features. These samples are either depleted tholeiites with similar trace element characteristics to FABs or enriched calc-alkaline rocks. Preliminary zircon dating suggests an age of 47.2 ± 1.2 Ma for one of the samples with strong arc signatures, consistent with the oldest published ages for the Aleutian so far. However, based on their compositional similarities to FABs, the depleted tholeiites should be older than the arc-type rocks, suggesting that subduction initiation could have occurred earlier than the above-mentioned age. The absence of boninite could either reflect an incomplete sampling of the early-arc sequences or a different initiation style compared to other Pacific subduction zones. Further ages and radiogenic isotope data should refine these interpretations.

The Upper- to Middle-Crustal Section of the Alisitos Oceanic Arc, (Baja, Mexico): an Analog of the Izu-Bonin-Marianas (IBM) Arc

NASA Astrophysics Data System (ADS)

Medynski, S.; Busby, C.; DeBari, S. M.; Morris, R.; Andrews, G. D.; Brown, S. R.; Schmitt, A. K.

2016-12-01

The Rosario segment of the Cretaceous Alisitos arc in Baja California is an outstanding field analog for the Izu-Bonin-Mariana (IBM) arc, because it is structurally intact, unmetamorphosed, and has superior three-dimensional exposures of an upper- to middle-crustal section through an extensional oceanic arc. Previous work1, done in the pre-digital era, used geologic mapping to define two phases of arc evolution, with normal faulting in both phases: (1) extensional oceanic arc, with silicic calderas, and (2) oceanic arc rifting, with widespread diking and dominantly mafic effusions. Our new geochemical data match the extensional zone immediately behind the Izu arc front, and is different from the arc front and rear arc, consistent with geologic relations. Our study is developing a 3D oceanic arc crustal model, with geologic maps draped on Google Earth images, and GPS-located outcrop information linked to new geochemical, geochronological and petrographic data, with the goal of detailing the relationships between plutonic, hypabyssal, and volcanic rocks. This model will be used by scientists as a reference model for past (IBM-1, 2, 3) and proposed IBM (IBM-4) drilling activities. New single-crystal zircon analysis by TIMS supports the interpretation, based on batch SIMS analysis of chemically-abraded zircon1, that the entire upper-middle crustal section accumulated in about 1.5 Myr. Like the IBM, volcanic zircons are very sparse, but zircon chemistry on the plutonic rocks shows trace element compositions that overlap to those measured in IBM volcanic zircons by A. Schmitt (unpublished data). Zircons have U-Pb ages up to 20 Myr older than the eruptive age, suggesting remelting of older parts of the arc, similar to that proposed for IBM (using different evidence). Like IBM, some very old zircons are also present, indicating the presence of old crustal fragments, or sediments derived from them, in the basement. However, our geochemical data show that the magmas are differentiated from a single mantle source, so any older crust that was remelted had the same compositional characteristics. This is similar to previous conclusion that the different parts of the Izu arc have retained their distinct compositions over the last 15 Myr2. 1Busby et al., 2006 JVGR 149, 1-46 2 Hochstaedter et al., 2000 JGR 105, 495-512

The Rondonian-San Ignacio Province in the SW Amazonian Craton: An overview

NASA Astrophysics Data System (ADS)

Bettencourt, Jorge Silva; Leite, Washington Barbosa; Ruiz, Amarildo Salina; Matos, Ramiro; Payolla, Bruno Leonelo; Tosdal, Richard M.

2010-01-01

The Rondonian-San Ignacio Province (1.56-1.30 Ga) is a composite orogen created through successive accretion of arcs, ocean basin closure and final oblique microcontinent-continent collision. The effects of the collision are well preserved mostly in the Paraguá Terrane (Bolivia and Mato Grosso regions) and in the Alto Guaporé Belt and the Rio Negro-Juruena Province (Rondônia region), considering that the province was affected by later collision-related deformation and metamorphism during the Sunsás Orogeny (1.25-1.00 Ga). The Rondonian-San Ignacio Province comprises: (1) the Jauru Terrane (1.78-1.42 Ga) that hosts Paleoproterozoic basement (1.78-1.72 Ga), and the Cachoeirinha (1.56-1.52 Ga) and the Santa Helena (1.48-1.42 Ga) accretionary orogens, both developed in an Andean-type magmatic arc; (2) the Paraguá Terrane (1.74-1.32 Ga) that hosts pre-San Ignacio units (>1640 Ma: Chiquitania Gneiss Complex, San Ignacio Schist Group and Lomas Manechis Granulitic Complex) and the Pensamiento Granitoid Complex (1.37-1.34 Ga) developed in an Andean-type magmatic arc; (3) the Rio Alegre Terrane (1.51-1.38 Ga) that includes units generated in a mid-ocean ridge and an intra-oceanic magmatic arc environments; and (4) the Alto Guaporé Belt (<1.42-1.34 Ga) that hosts units developed in passive marginal basin and intra-oceanic arc settings. The collisional stage (1.34-1.32 Ga) is characterized by deformation, high-grade metamorphism, and partial melting during the metamorphic peak, which affected primarily the Chiquitania Gneiss Complex and Lomas Manechis Granulitic Complex in the Paraguá Terrane, and the Colorado Complex and the Nova Mamoré Metamorphic Suite in the Alto Guaporé Belt. The Paraguá Block is here considered as a crustal fragment probably displaced from its Rio Negro-Juruena crustal counterpart between 1.50 and 1.40 Ga. This period is characterized by extensive A-type and intra-plate granite magmatism represented by the Rio Crespo Intrusive Suite (ca. 1.50 Ga), Santo Antonio Intrusive Suite (1.40-1.36 Ga), and the Teotônio Intrusive Suite (1.38 Ga). Magmatism of these types also occur at the end of the Rondonian-San Ignacio Orogeny, and are represented by the Alto Candeias Intrusive Suite (1.34-1.36 Ga), and the São Lourenço-Caripunas Intrusive Suite (1.31-1.30 Ga). The cratonization of the province occurred between 1.30 and 1.25 Ga.

Evolution of A-Type Macrosegregation in Large Size Steel Ingot After Multistep Forging and Heat Treatment

NASA Astrophysics Data System (ADS)

Loucif, Abdelhalim; Ben Fredj, Emna; Harris, Nathan; Shahriari, Davood; Jahazi, Mohammad; Lapierre-Boire, Louis-Philippe

2018-03-01

A-type macrosegregation refers to the channel chemical heterogeneities that can be formed during solidification in large size steel ingots. In this research, a combination of experiment and simulation was used to study the influence of open die forging parameters on the evolution of A-type macrosegregation patterns during a multistep forging of a 40 metric ton (MT) cast, high-strength steel ingot. Macrosegregation patterns were determined experimentally by macroetch along the longitudinal axis of the forged and heat-treated ingot. Mass spectroscopy, on more than 900 samples, was used to determine the chemical composition map of the entire longitudinal sectioned surface. FORGE NxT 1.1 finite element modeling code was used to predict the effect of forging sequences on the morphology evolution of A-type macrosegregation patterns. For this purpose, grain flow variables were defined and implemented in a large scale finite element modeling code to describe oriented grains and A-type segregation patterns. Examination of the A-type macrosegregation showed four to five parallel continuous channels located nearly symmetrical to the axis of the forged ingot. In some regions, the A-type patterns became curved or obtained a wavy form in contrast to their straight shape in the as-cast state. Mass spectrometry analysis of the main alloying elements (C, Mn, Ni, Cr, Mo, Cu, P, and S) revealed that carbon, manganese, and chromium were the most segregated alloying elements in A-type macrosegregation patterns. The observed differences were analyzed using thermodynamic calculations, which indicated that changes in the chemical composition of the liquid metal can affect the primary solidification mode and the segregation intensity of the alloying elements. Finite element modeling simulation results showed very good agreement with the experimental observations, thereby allowing for the quantification of the influence of temperature and deformation on the evolution of the shape of the macrosegregation channels during the open die forging process.

Evolution of A-Type Macrosegregation in Large Size Steel Ingot After Multistep Forging and Heat Treatment

NASA Astrophysics Data System (ADS)

Loucif, Abdelhalim; Ben Fredj, Emna; Harris, Nathan; Shahriari, Davood; Jahazi, Mohammad; Lapierre-Boire, Louis-Philippe

2018-06-01

A-type macrosegregation refers to the channel chemical heterogeneities that can be formed during solidification in large size steel ingots. In this research, a combination of experiment and simulation was used to study the influence of open die forging parameters on the evolution of A-type macrosegregation patterns during a multistep forging of a 40 metric ton (MT) cast, high-strength steel ingot. Macrosegregation patterns were determined experimentally by macroetch along the longitudinal axis of the forged and heat-treated ingot. Mass spectroscopy, on more than 900 samples, was used to determine the chemical composition map of the entire longitudinal sectioned surface. FORGE NxT 1.1 finite element modeling code was used to predict the effect of forging sequences on the morphology evolution of A-type macrosegregation patterns. For this purpose, grain flow variables were defined and implemented in a large scale finite element modeling code to describe oriented grains and A-type segregation patterns. Examination of the A-type macrosegregation showed four to five parallel continuous channels located nearly symmetrical to the axis of the forged ingot. In some regions, the A-type patterns became curved or obtained a wavy form in contrast to their straight shape in the as-cast state. Mass spectrometry analysis of the main alloying elements (C, Mn, Ni, Cr, Mo, Cu, P, and S) revealed that carbon, manganese, and chromium were the most segregated alloying elements in A-type macrosegregation patterns. The observed differences were analyzed using thermodynamic calculations, which indicated that changes in the chemical composition of the liquid metal can affect the primary solidification mode and the segregation intensity of the alloying elements. Finite element modeling simulation results showed very good agreement with the experimental observations, thereby allowing for the quantification of the influence of temperature and deformation on the evolution of the shape of the macrosegregation channels during the open die forging process.

A Detailed Geochemical Study of Island Arc Crust: The Talkeetna Arc Section, South-central Alaska

NASA Astrophysics Data System (ADS)

Greene, A. R.; Debari, S. M.; Kelemen, P. B.; Clift, P. D.; Blusztajn, J.

2002-12-01

The Talkeetna arc section in south-central Alaska is recognized as the exposed upper mantle and crust of an accreted, Late Triassic to Middle Jurassic island arc. Detailed geochemical studies of layered gabbronorite from the middle and lower crust of this arc and a diverse suite of volcanic and plutonic rocks from the middle and upper crust provide crucial data for understanding arc magma evolution. We also present new data on parental magma compositions for the arc. The deepest level of the arc section consists of residual mantle and ultramafic cumulates adjacent to garnet gabbro and basal gabbronorite interlayered with pyroxenite. The middle crust is primarily layered gabbronorite, ranging from anorthosite to pyroxenite in composition, and is the most widespread plutonic lithology. The upper mid crust is a heterogenous assemblage of dioritic to tonalitic rocks mixed with gabbro and intruded by abundant mafic dikes and chilled pillows. The upper crust of the arc is comprised of volcanic rocks of the Talkeetna Formation ranging from basalt to rhyolite. Most of these volcanic rocks have evolved compositions (<5% MgO, Mg# <60) and overlap the composition of intermediate to felsic plutonic rocks (<3.5% MgO, Mg# <45). However, several chilled mafic rocks and one basalt have primitive characteristics (>8% MgO, Mg# >60). Ion microprobe analyses of clinopyroxene in mid-crustal layered gabbronorites have parallel REE patterns with positive-sloping LREE segments (La/Sm(N)=0.05-0.17; mean 0.11) and flat HREE segments (5-25xchondrite; mean 10xchondrite). Liquids in REE equilibrium with the clinopyroxene in these gabbronorite cumulates were calculated in order to constrain parental magmas. These calculated liquids(La/Sm(N)=0.77-1.83; mean 1.26) all fall within the range of dike and volcanic rock(La/Sm(N)=0.78-2.12; mean 1.23) compositions. However, three lavas out of the 44 we have analyzed show strong HREE depletion, which is not observed in any of the liquid compositions calculated from clinopyroxene in the gabbronorite samples. Three lavas have Mg# 50-63 (49-57 % SiO2) and two of these are in REE equilibrium with calculated liquids of cumulate gabbronorites. Five chilled samples (three dikes and two mafic inclusions) have Mg# 54-64 (48-52 % SiO2) and lie just below the calculated liquid REE patterns. The most primitive mafic dike (SiO2 =48.1; MgO =8.1 ; Mg# =62.0; Ni =73) represents a well-constrained potential parental magma to the gabbroic cumulates in the mid-crust of the arc, although, like the three primitive basalts, it is not in Fe/Mg equilibrium with the gabbros.The Mg# is too high. Presumably, this parent has lost Ni and MgO to fractionation of ultramafic cumulates at deeper levels of the arc. The average dike REE pattern is nearly identical to the calculated primary magma composition of DeBari and Sleep(1991) for the Talkeetna arc, as are the REE patterns for the chilled pillows. Least-squares mass-balance calculations of mid-crustal gabbronorites indicate pl + cpx + opx + mgt + amph represent the bulk of removed solids. Fractionation of these phases using the most primitive mafic dike described above as the parental composition can produce many of the more evolved volcanic rocks. Fe-Ti oxide accounts for 0.05-12.3 wt% (mean 5.92 wt%) of the sampled cumulates and amphibole represents 0.97-40.1 wt% (mean 16.4 wt%). Fractionation of the observed phases in the cumulate gabbronorite is reflected by TiO2 depletion in the volcanic and intermediate to felsic plutonic rocks of the middle and upper crust.

Unraveling the diversity in arc volcanic eruption styles: Examples from the Aleutian volcanic arc, Alaska

NASA Astrophysics Data System (ADS)

Larsen, Jessica F.

2016-11-01

The magmatic systems feeding arc volcanoes are complex, leading to a rich diversity in eruptive products and eruption styles. This review focuses on examples from the Aleutian subduction zone, encompassed within the state of Alaska, USA because it exhibits a rich diversity in arc structure and tectonics, sediment and volatile influx feeding primary magma generation, crustal magma differentiation processes, with the resulting outcome the production of a complete range in eruption styles from its diverse volcanic centers. Recent and ongoing investigations along the arc reveal controls on magma production that result in diversity of eruptive products, from crystal-rich intermediate andesites to phenocryst-poor, melt-rich silicic and mafic magmas and a spectrum in between. Thus, deep to shallow crustal "processing" of arc magmas likely greatly influences the physical and chemical character of the magmas as they accumulate in the shallow crust, the flow physics of the magmas as they rise in the conduit, and eruption style through differences in degassing kinetics of the bubbly magmas. The broad spectrum of resulting eruption styles thus depends on the bulk magma composition, melt phase composition, and the bubble and crystal content (phenocrysts and/or microlites) of the magma. Those fundamental magma characteristics are in turn largely determined by the crustal differentiation pathway traversed by the magma as a function of tectonic location in the arc, and/or the water content and composition of the primary magmas. The physical and chemical character of the magma, set by the arc differentiation pathway, as it ascends towards eruption determines the kinetic efficiency of degassing versus the increasing internal gas bubble overpressure. The balance between degassing rate and the rate at which gas bubble overpressure builds then determines the conditions of fragmentation, and ultimately eruption intensity.

Arc spray fabrication of metal matrix composite monotape

NASA Technical Reports Server (NTRS)

Westfall, L. J. (Inventor)

1985-01-01

Arc metal spraying is used to spray liquid metal onto an array of high strength fibers that were previously wound onto a large drum contained inside a controlled atmosphere chamber. This chamber is first evacuated to remove gaseous contaminants and then backfilled with a neutral gas up to atmospheric pressure. This process is used to produce a large size metal matrix composite monotape.

Crustal forensics in arc magmas

NASA Astrophysics Data System (ADS)

Davidson, Jon P.; Hora, John M.; Garrison, Jennifer M.; Dungan, Michael A.

2005-01-01

The geochemical characteristics of continental crust are present in nearly all arc magmas. These characteristics may reflect a specific source process, such as fluid fluxing, common to both arc magmas and the continental crust, and/or may reflect the incorporation of continental crust into arc magmas either at source via subducted sediment, or via contamination during differentiation. Resolving the relative mass contributions of juvenile, mantle-derived material, versus that derived from pre-existing crust of the upper plate, and providing these estimates on an element-by-element basis, is important because: (1) we want to constrain crustal growth rates; (2) we want to quantitatively track element cycling at convergent margins; and (3) we want to determine the origin of economically important elements and compounds. Traditional geochemical approaches for determining the contributions of various components to arc magmas are particularly successful when applied on a comparative basis. Studies of suites from multiple magmatic systems along arcs, for which differentiation effects can be individually constrained, can be used to extrapolate to potential source compositions. In the Lesser Antilles Arc, for example, differentiation trends from individual volcanoes are consistent with open-system evolution. However, such trends do not project back to a common primitive magma composition, suggesting that differentiation modifies magmas that were derived from distinct mantle sources. We propose that such approaches should now be complemented by petrographically constrained mineral-scale isotope and trace element analysis to unravel the contributing components to arc magmas. This innovative approach can: (1) better constrain true end-member compositions by returning wider ranges in geochemical compositions among constituent minerals than is found in whole rocks; (2) better determine magmatic evolution processes from core-rim isotopic or trace element profiles from the phases contained in magmas; and (3) constrain rates of differentiation by applying diffusion-controlled timescales to element profiles. An example from Nguaruhoe Volcano, New Zealand, underscores the importance of such a microsampling approach, showing that mineral isotopic compositions encompass wide ranges, that whole-rock isotopic compositions are consequently simply element-weighted averages of the heterogeneous crystal cargo, and that open-system evolution is proved by core-rim variations in Sr isotope ratios. Nguaruhoe is just one of many systems examined through microanalytical approaches. The overwhelming conclusion of these studies is that crystal cargoes are not truly phenocrystic, but are inherited from various sources. The implication of this realization is that the interpretation of whole-rock isotopic data, including the currently popular U-series, needs careful evaluation in the context of petrographic observations.

Analytical methods to characterize heterogeneous raw material for thermal spray process: cored wire Inconel 625

NASA Astrophysics Data System (ADS)

Lindner, T.; Bonebeau, S.; Drehmann, R.; Grund, T.; Pawlowski, L.; Lampke, T.

2016-03-01

In wire arc spraying, the raw material needs to exhibit sufficient formability and ductility in order to be processed. By using an electrically conductive, metallic sheath, it is also possible to handle non-conductive and/or brittle materials such as ceramics. In comparison to massive wire, a cored wire has a heterogeneous material distribution. Due to this fact and the complex thermodynamic processes during wire arc spraying, it is very difficult to predict the resulting chemical composition in the coating with sufficient accuracy. An Inconel 625 cored wire was used to investigate this issue. In a comparative study, the analytical results of the raw material were compared to arc sprayed coatings and droplets, which were remelted in an arc furnace under argon atmosphere. Energy-dispersive X-ray spectroscopy (EDX) and X-ray fluorescence (XRF) analysis were used to determine the chemical composition. The phase determination was performed by X-ray diffraction (XRD). The results were related to the manufacturer specifications and evaluated in respect to differences in the chemical composition. The comparison between the feedstock powder, the remelted droplets and the thermally sprayed coatings allows to evaluate the influence of the processing methods on the resulting chemical and phase composition.

Distinctly different parental magmas for plutons and lavas in the central Aleutian arc

NASA Astrophysics Data System (ADS)

Cai, Y.; Rioux, M. E.; Kelemen, P. B.; Goldstein, S. L.; Bolge, L.; Kylander-Clark, A. R.

2014-12-01

While it is generally agreed that continental crust is generated by arc magmatism, average arc lavas are basaltic while the bulk continental crust is andesitic, and this has led to many models for secondary reprocessing of the arc crust in order to form continental crust. We report new data on calc-alkaline plutons in the central Aleutians showing that they have distinctly different sources compared to Holocene tholeiitic lavas. Therefore the lavas are not representative of the net magmatic transfer from the mantle into the arc crust. Eocene to Miocene (9-39 Ma) intermediate to felsic plutonic rocks from the central Aleutian arc show higher SiO2 at a given Mg#, higher ɛNd- and ɛHf-values, and lower Pb isotope ratios than Holocene volcanic rocks from the same region. Instead, the plutonic rocks resemble volcanics from the western Aleutians isotopically, and have chemical compositions similar to bulk continental crust. These data could reflect temporal variation of Aleutian magma source compositions, from Eocene-Miocene "isotopically depleted" and predominantly calc-alkaline to Holocene "isotopically enriched" and predominantly tholeiitic. Alternatively, they may reflect different transport and emplacement processes for the magmas that form plutons and lavas: calc-alkaline magmas with higher Si content and high viscosity may preferentially form plutons, perhaps after extensive mid-crustal degassing of initially high water contents. The latter case implies that the upper and middle arc crust is more like the calc-alkaline bulk composition of the continental crust than the lavas alone. Crustal reprocessing mechanisms that preserve upper and middle arc crust, while removing lower arc crust, can account for the genesis and evolution of continental crust. Since gabbroic lower arc crust extends from ca 20-40 km depth, and is density stable over most of this depth range, "delamination" of dense lithologies [1] may not be sufficient to accomplish this. Alternatively, subduction erosion of arc crust followed by "relamination" [2] of buoyant calc-alkaline rocks may be more effective. [1] e.g. Ringwood & Green, Tectonophysics 1966; Herzberg et al. Contributions to mineralogy and petrology 1983; [2] e.g. Hacker et al. Earth and Planetary Science Letters 2011.

Openness to Gender Atypical Occupations in Youth: Do Peer Groups and School Classes Matter?

ERIC Educational Resources Information Center

Alm, Susanne; Bäckman, Olof

2015-01-01

The article analyses aspects of gender composition and social dominance in peer groups and school classes and their effects on the degree of openness to gender-atypical occupations in young adolescents. The data set used contains information for some 13,000 girls and boys living in Stockholm in the early 1960s. Results from multi-level regressions…

Structure of propagating arc in a magneto-hydrodynamic rail plasma actuator

NASA Astrophysics Data System (ADS)

Gray, Miles D.; Choi, Young-Joon; Sirohi, Jayant; Raja, Laxminarayan L.

2016-01-01

The spatio-temporal evolution of a magnetically driven arc in a rail plasma flow actuator has been characterized with high-speed imaging, electrical measurements, and spectroscopy. The arc draws a peak current of ~1 kA. High-speed framing cameras were used to observe the complex arc propagation phenomenon. In particular, the anode and cathode roots were observed to have different modes of transit, which resulted in distinct types of electrode degradation on the anode and cathode surfaces. Observations of the arc electrical properties and induced magnetic fields are used to explain the transit mechanism of the arc. Emission spectroscopy revealed the arc temperature and species composition as a function of transit distance of the arc. The results obtained offer significant insights into the electromagnetic properties of the arc-rail system as well as arc-surface interaction phenomena in a propagating arc.

A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites.

PubMed

Reubi, Olivier; Blundy, Jon

2009-10-29

Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records.

Geochemical Relationships between Volcanic and Plutonic Upper to Mid Crustal Exposures of the Rosario Segment, Alisitos Arc (Baja California, Mexico): An Outstanding Field Analog to the Izu-Bonin-Mariana Arc

NASA Astrophysics Data System (ADS)

Morris, R.; DeBari, S. M.; Busby, C. J.; Medynski, S.

2015-12-01

Exposed paleo-arcs, such as the Rosario segment of the Cretaceous Alisitos Arc in Baja California, Mexico, provide an opportunity to explore the evolution of arc crust through time. Remarkable 3-D exposures of the Rosario segment record crustal generation processes in the volcanic rocks and underlying plutonic rocks. In this study, we explore the physical and geochemical connection between the plutonic and volcanic sections of the extensional Alisitos Arc, and elucidate differentiation processes responsible for generating them. These results provide an outstanding analog for extensional active arc systems, such as the Izu-Bonin-Mariana (IBM) Arc. Upper crustal volcanic rocks have a coherent stratigraphy that is 3-5 km thick and ranges in composition from basalt to dacite. The most felsic compositions (70.9% SiO2) are from a welded ignimbrite unit. The most mafic compositions (51.5% SiO2, 3.2% MgO) are found in basaltic sill-like units. Phenocrysts in the volcanic units include plagioclase +/- amphibole and clinopyroxene. The transition to deeper plutonic rocks is clearly an intrusive boundary, where plutonic units intrude the volcanic units. Plutonic rocks are dominantly a quartz diorite main phase with a more mafic, gabbroic margin. A transitional zone is observed along the contact between the plutonic and volcanic rocks, where volcanics have coarsely recrystallized textures. Mineral assemblages in the plutonic units include plagioclase +/- quartz, biotite, amphibole, clinopyroxene and orthopyroxene. Most, but not all, samples are low K. REE patterns are relatively flat with limited enrichment. Normalization diagrams show LILE enrichment and HFSE depletion, where trends are similar to average IBM values. We interpret plutonic and volcanic units to have similar geochemical relationships, where liquid lines of descent show the evolution of least to most evolved magma types. We provide a model for the formation and magmatic evolution of the Alisitos Arc.

Glenohumeral joint rotation range of motion in competitive swimmers.

PubMed

Riemann, Bryan L; Witt, Joe; Davies, George J

2011-08-01

Much research has examined shoulder range of motion adaptations in overhead-unilateral athletes. Based on the void examining overhead-bilateral athletes, especially competitive swimmers, we examined shoulder external rotation, isolated internal rotation, composite internal rotation, and total arc of motion range of motion of competitive swimmers. The range of motion of registered competitive swimmers (n = 144, age = 12-61 years) was compared by limb (dominant, non-dominant), sex, and age group (youth, high school, college, masters). Significantly (P < 0.05) greater dominant external rotation was observed for both men and women high school and college swimmers, youth women swimmers, and men masters swimmers compared with the non-dominant limb. The isolated internal rotation (glenohumeral rotation), composite internal rotation (glenohumeral rotation plus scapulothoracic protraction), and total arc of motion (external rotation plus composite internal rotation) of the non-dominant limb was significantly greater than that of the dominant limb by sex and age group. Youth and high school swimmers demonstrated significantly greater composite internal rotation than college and masters swimmers. Youth swimmers displayed significantly greater total arc of motion than all other age groups. These data will aid in the interpretation of shoulder range of motion values in competitive swimmers during preseason screenings, injury evaluations and post-rehabilitation programmes, with the results suggesting that differences exist in bilateral external rotation, isolated internal rotation, composite internal rotation, and total arc of motion range of motion.

Geochemical Database for Igneous Rocks of the Ancestral Cascades Arc - Southern Segment, California and Nevada

USGS Publications Warehouse

du Bray, Edward A.; John, David A.; Putirka, Keith; Cousens, Brian L.

2009-01-01

Volcanic rocks that form the southern segment of the Cascades magmatic arc are an important manifestation of Cenozoic subduction and associated magmatism in western North America. Until recently, these rocks had been little studied and no systematic compilation of existing composition data had been assembled. This report is a compilation of all available chemical data for igneous rocks that constitute the southern segment of the ancestral Cascades magmatic arc and complement a previously completed companion compilation that pertains to rocks that constitute the northern segment of the arc. Data for more than 2,000 samples from a diversity of sources were identified and incorporated in the database. The association between these igneous rocks and spatially and temporally associated mineral deposits is well established and suggests a probable genetic relationship. The ultimate goal of the related research is an evaluation of the time-space-compositional evolution of magmatism associated with the southern Cascades arc segment and identification of genetic associations between magmatism and mineral deposits in this region.

Experimental research on electric propulsion. Note 7: Analysis of the performance of an arc-jet driven by means of hydrogen and nitrogen

NASA Technical Reports Server (NTRS)

Robotti, A. C.; Oggero, M.

1984-01-01

Experiments which use a new type of arc-jet, characterized by composite electromagnetic and vortex stabilization and propelled by hydrogen and nitrogen in turn are described. The electrical characteristics of the arc and the loss of heat through the electrodes is emphasized.

Turbidite geochemistry and evolution of the Izu-Bonin arc and continents

NASA Astrophysics Data System (ADS)

Gill, J. B.; Hiscott, R. N.; Vidal, Ph.

1994-10-01

The major and trace element and NdPb isotopic composition of Oligocene to Pleistocene volcaniclastic sands and sandstones derived from the Izu Bonin island arc has been determined. Many characteristics of the igneous sources are preserved and record the geochemical evolution of juvenile proto-continental crust in an island arc. After an initial boninitic phase, arc geochemistry has varied primarily as the result of backarc basin formation. The Izu arc source became depleted in incompatible trace elements during backarc basin formation, and re-enriched after spreading stopped in the basin. Renewed rifting during the Pliocene to Recent caused felsic magmatism as a result of easier eruption of differentiates rather than as a result of crustal melting. Four isotopically-distinct source components are recognized. Their combination in the sources of the Izu-Bonin and Mariana arcs initially was similar but diverged after backarc basin formation. The Izu arc turbidites are more similar to Archean than post-Archean sedimentary rocks, indicating that the production of new upper crust at subduction zones has changed little over time. The turbidites are similar in major element composition to average continental crust but are depleted in incompatible trace elements, especially Th and Nb. Consequently, the net effect of adding juvenile arc crust to continents is to reverse the trend of planetary trace element differentiation instead of continuing the process.

Magnesium Isotopes as a Tracer of Crustal Materials in Volcanic Arc Magmas in the Northern Cascade Arc

NASA Astrophysics Data System (ADS)

Brewer, Aaron W.; Teng, Fang-Zhen; Mullen, Emily

2018-03-01

Fifteen North Cascade Arc basalts and andesites were analyzed for Mg isotopes to investigate the extent and manner of crustal contributions to this magmatic system. The δ26Mg of these samples vary from within the range of ocean island basalts (the lightest being -0.33 ± 0.07‰) to heavier compositions (as heavy as -0.15 ± 0.06‰). The observed range in chemical and isotopic composition is similar to that of other volcanic arcs that have been assessed to date in the circum-pacific subduction zones and in the Caribbean. The heavy Mg isotope compositions are best explained by assimilation and fractional crystallization within the deep continental crust with a possible minor contribution from the addition of subducting slab-derived fluids to the primitive magma. The bulk mixing of sediment into the primitive magma or mantle source and the partial melting of garnet-rich peridotite are unlikely to have produced the observed range of Mg isotope compositions. The results show that Mg isotopes may be a useful tracer of crustal input into a magma, supplementing traditional methods such as radiogenic isotopic and trace element data, particularly in cases in which a high fraction of crustal material has been added.

Evolution of residual stresses in micro-arc oxidation ceramic coatings on 6061 Al alloy

NASA Astrophysics Data System (ADS)

Shen, Dejiu; Cai, Jingrui; Guo, Changhong; Liu, Peiyu

2013-11-01

Most researches on micro-arc oxidation mainly focus on the application rather than discovering the evolution of residual stresses. However, residual stresses in the surface coatings of structural components have adverse effects on their properties, such as fatigue life, dimensional stability and corrosion resistance, etc. The micro-arc oxidation ceramic coatings are produced on the surfaces of 6061 aluminum alloy by a homemade asymmetric AC type of micro-arc oxidation equipment of 20 kW. A constant current density of 4.4±0.1 A/dm2 and a self-regulated composite electrolyte are used. The micro-arc oxidation treatment period ranges from 10 min to 40 min, and the thickness of the ceramic coatings is more than 20 μm. Residual stresses attributed to γ-Al2O3 constituent in the coatings at different micro-arc oxidation periods are analyzed by an X-ray diffractometer using the sin2 ψ method. The analysis results show that the residual stress in the ceramic coatings is compressive in nature, and it increases first and then decreases with micro-arc oxidation time increase. The maximum stress value is 1 667±20 MPa for period of 20 min. Through analyzing the coating thickness, surface morphology and phase composition, it is found that the residual stress in the ceramic coatings is linked closely with the coating growth, the phase composition and the micro cracks formed. It is also found that both the heat treatment and the ultrasonic action release remarkably the residual compressive stress. The heat treatment makes the residual compressive stress value decrease 1 378 MPa. The ultrasonic action even alters the nature of the residual stress, making the residual compressive stress change into a residual tensile stress.

Back-arc basin development: Constraints on geochronology and geochemistry of arc-like and OIB-like basalts in the Central Qilian block (Northwest China)

NASA Astrophysics Data System (ADS)

Gao, Zhong; Zhang, Hong-Fei; Yang, He; Pan, Fa-Bin; Luo, Bi-Ji; Guo, Liang; Xu, Wang-Chun; Tao, Lu; Zhang, Li-Qi; Wu, Jing

2018-06-01

The Lajishan belt of the Central Qilian block was a back-arc basin during Early Paleozoic. The basaltic magmatism and temporal evolution in this basin provide an opportunity to study the development of back-arc basin in an active continental margin. In this study, we carry out an integrated study of geochronological, geochemical and Sr-Nd isotopic compositions for the Early Paleozoic arc-like and OIB-like basalts. The Lajishan arc-like basalts are enriched in large ion lithophile element (LILE) and show negative Nb and Ta anomalies whereas the OIB-like basalts have high LILE abundances and show positive Nb and Ta anomalies. The arc-like basalts have initial 87Sr/86Sr values of 0.7050-0.7054 and εNd(t) values of +0.51-+2.63, and the OIB-like basalts have initial 87Sr/86Sr values of 0.7049-0.7050 and εNd(t) values of +0.66-+1.57. The geochemical and Sr-Nd isotopic compositions suggest that the arc-like basalts are derived from partial melting of a depleted mantle source metasomatized by slab-derived components at shallow depth levels, and the OIB-like basalts also originated from a metasomatized mantle wedge source. U-Pb zircon dating yielded the ages of 494 ± 4 Ma for the arc-like basalts and 468 ± 6 Ma for the OIB-like basalts. We argue that the arc-like basalts are products of back-arc extension before the back-arc rifting initiated in earlier stage, resulting from the northward subduction of the Qaidam-West Qinling oceanic slab, while the OIB-like basalts represent products of further back-arc spreading in response to rollback of the Qaidam-West Qinling oceanic lithospheric slab. The association of arc-like and OIB-like basalts in the Lajishan belt records the development of back-arc basin from initial rifting to subsequent spreading, offering insight into how basaltic magmatism generates in the formation of back-arc basin in subduction zone setting.

Transition From Archean Plume-Arc Orogens to Phanerozoic Style Convergent Margin Orogens, and Changing Mantle Lithosphere

NASA Astrophysics Data System (ADS)

Kerrich, R.; Jia, Y.; Wyman, D.

2001-12-01

Mantle plume activity was more intense in the Archean and komatiite-basalt volcanic sequences are a major component of many Archean greenstone belts. Tholeiitic basalts compositionally resemble Phanerozoic and Recent ocean plateau basalts, such as those of Ontong Java and Iceland. However, komatiite-basalt sequences are tectonically imbricated with bimodal arc lavas and associated trench turbidites. Interfingering of komatiite flows with boninite series flows, and primitive to evolved arc basalts has recently been identified in the 2.7 Ga Abitibi greenstone belt, demonstrating spatially and temporally associated plume and arc magmatism. These observations are consistent with an intra-oceanic arc migrating and capturing an ocean plateau, where the plateau jams the arc and imbricated plateau-arc crust forms a greenstone belt orogen. Melting of shallowly subducted plateau basalt crust (high Ba, Th, LREE) accounts for the areally extensive and voluminous syntectonic tonalite batholiths. In contrast, the adakite-Mg-andesite-Niobium enriched basalt association found in Archean greenstone belts and Cenozoic arcs are melts of LREE depleted MORB slab. Buoyant residue from anomalously hot mantle plume melting at > 100km rises to couple with the composite plume-arc crust to form the distinctively thick and refractory Archean continental lithospheric mantle. New geochemical data for structurally hosted ultramafic units along the N. American Cordillera, from S. California to the Yukon, show that these are obducted slices of sub-arc lithospheric mantle. Negatively fractionated HREE with high Al2O3/TiO2 ratios signify prior melt extraction, and variably enriched Th and LREE with negative Nb anomalies a subduction component in a convergent margin. A secular decrease of mantle plume activity and temperature results in plume-arc dominated geodynamics in the Archean with shallow subduction and thick CLM, whereas Phanerozoic convergent margins are dominated by arc-continent, arc-terrane, and terrane-terrane collision with steep subduction resulting in narrow belts of granitoids and obduction of lithospheric mantle.

Tracing crustal contamination along the Java segment of the Sunda Arc, Indonesia

NASA Astrophysics Data System (ADS)

Jolis, E. M.; Troll, V.; Deegan, F.; Blythe, L.; Harris, C.; Freda, C.; Hilton, D.; Chadwick, J.; Van Helden, M.

2012-04-01

Arc magmas typically display chemical and petrographic characteristics indicative of crustal input. Crustal contamination can take place either in the mantle source region or as magma traverses the upper crust (e.g. [1]). While source contamination is generally considered the dominant process (e.g. [2]), late-stage crustal contamination has been recognised at volcanic arcs too (e.g. [3]). In light of this, we aim to test the extent of upper crustal versus source contamination along the Java segment of the Sunda arc, which, due its variable upper crustal structure, is an exemplary natural laboratory. We present a detailed geochemical study of 7 volcanoes along a traverse from Anak-Krakatau in the Sunda strait through Java and Bali, to characterise the impact of the overlying crust on arc magma composition. Using rock and mineral elemental geochemistry, radiogenic (Sr, Nd and Pb) and, stable (O) isotopes, we show a correlation between upper crustal composition and the degree of upper crustal contamination. We find an increase in 87Sr/86Sr and δ18O values, and a decrease in 143Nd/144Nd values from Krakatau towards Merapi, indicating substantial crustal input from the thick continental basement present. Volcanoes to the east of Merapi and the Progo-Muria fault transition zone, where the upper crust is thinner, in turn, show considerably less crustal input in their isotopic signatures, indicating a stronger influence of the mantle source. Our new data represent a systematic and high-resolution arc-wide sampling effort that allows us to distinguish the effects of the upper crust on the compositional spectrum of individual volcanic systems along the Sunda arc. [1] Davidson, J.P, Hora, J.M, Garrison, J.M & Dungan, M.A 2005. Crustal Forensics in Arc Magmas. J. Geotherm. Res. 140, 157-170; [2] Debaille, V., Doucelance, R., Weis, D., & Schiano, P. 2005. Geochim. Cosmochim. Acta, 70,723-741; [3] Gasparon, M., Hilton, D.R., & Varne, R. 1994. Earth Planet. Sci. Lett., 126, 15-22.

Melt Inclusion Evidence for Subduction-modified Mantle Beneath the Woodlark Spreading Center, Solomon Islands

NASA Astrophysics Data System (ADS)

Chadwick, J.; Turner, A.; Collins, E.

2015-12-01

The Woodlark Spreading Center (WSC) to the east of Papua New Guinea separates the Indo-Australian plate and Solomon Sea microplate. At its eastern terminus, the WSC is being subducted at the New Britain trench, forming a triple junction near the New Georgia Group arc in the Solomon Islands. Previous studies have shown that lavas recovered from greater than 100 km from the trench on the WSC are N-MORB, but closer to the trench they have arc-like Sr-Nd-Pb isotopic ratios, enrichments in LILE, and depletions in HFSE. In the complex triple junction area of the WSC on the Simbo and Ghizo Ridges, island arc tholeiites to medium-K calc-alkaline andesites and dacites have been recovered, many with trace element and isotopic characteristics that are similar to the true arc lavas in the New Georgia Group on the other side of the trench. We suggest that subduction-modified arc mantle migrates through slab windows created by the subduction of the WSC as the plates continue to diverge after subduction. This transfer of mantle across the plate boundary leads to variable mixing between arc and N-MORB end-members, forming the hybrid to arc-like lavas recovered on the WSC. To test this hypothesis and to characterize the end-member compositions, we have analyzed melt inclusions in olivine, pyroxene, and plagioclase phenocrysts in Simbo and Ghizo Ridge lava samples. Major elements were analyzed using the electron microprobe facility at Fayetteville State University and volatiles were analyzed on the ion probe facility at Woods Hole Oceanographic Institution. The melt inclusions show a wide diversity of magmas from basalts to dacites, and mixing modeling shows that most Woodlark Spreading Center lava compositions are explained by mixing between the most extreme mafic (MORB) and felsic (arc) inclusion compositions.

Differential preservation in the geologic record of intraoceanic arc sedimentary and tectonic processes

USGS Publications Warehouse

Draut, Amy; Clift, Peter D.

2013-01-01

Records of ancient intraoceanic arc activity, now preserved in continental suture zones, are commonly used to reconstruct paleogeography and plate motion, and to understand how continental crust is formed, recycled, and maintained through time. However, interpreting tectonic and sedimentary records from ancient terranes after arc–continent collision is complicated by preferential preservation of evidence for some arc processes and loss of evidence for others. In this synthesis we examine what is lost, and what is preserved, in the translation from modern processes to the ancient record of intraoceanic arcs. Composition of accreted arc terranes differs as a function of arc–continent collision geometry. ‘Forward-facing’ collision can accrete an oceanic arc on to either a passive or an active continental margin, with the arc facing the continent and colliding trench- and forearc-side first. In a ‘backward-facing’ collision, involving two subduction zones with similar polarity, the arc collides backarc-first with an active continental margin. The preservation of evidence for contemporary sedimentary and tectonic arc processes in the geologic record depends greatly on how well the various parts of the arc survive collision and orogeny in each case. Preservation of arc terranes likely is biased towards those that were in a state of tectonic accretion for tens of millions of years before collision, rather than tectonic erosion. The prevalence of tectonic erosion in modern intraoceanic arcs implies that valuable records of arc processes are commonly destroyed even before the arc collides with a continent. Arc systems are most likely to undergo tectonic accretion shortly before forward-facing collision with a continent, and thus most forearc and accretionary-prism material in ancient arc terranes likely is temporally biased toward the final stages of arc activity, when sediment flux to the trench was greatest and tectonic accretion prevailed. Collision geometry and tectonic erosion vs. accretion are important controls on the ultimate survival of material from the trench, forearc, arc massif, intra-arc basins, and backarc basins, and thus on how well an ancient arc terrane preserves evidence for tectonic processes such as subduction of aseismic ridges and seamounts, oblique plate convergence, and arc rifting. Forward-facing collision involves substantial recycling, melting, and fractionation of continent-derived material during and after collision, and so produces melts rich in silica and incompatible trace elements. As a result, forward-facing collision can drive the composition of accreted arc crust toward that of average continental crust.

Physical and chemical consequences of crustal melting in fossil mature intra-oceanic arcs

NASA Astrophysics Data System (ADS)

Berger, J.; Burg, J.-P.

2012-04-01

Seismic velocity models of active intra-oceanic arcs show roots with densities and P-wave velocities intermediate to classical lower oceanic crust (density; ~3.0, Vp: ~7.0 km/s) and uppermost harzburgitic mantle (density: 3.2-3.3, Vp: 7.9-8.0 km/s). Most studies on active and fossil exhumed island arcs interpret the petrological nature of this root as ultramafic cumulates crystallized from primitive melts and/or as pyroxenites formed via basalt-peridotite reactions. Igneous cumulates and pyroxenites have densities close to or above that of uppermost mantle rocks; they can consequently undergo gravity-driven delamination, a process thought to drive the bulk composition of the arc toward an andesitic, continental crust-like composition. Dehydration and melting reactions are reported from exposed arc roots (Jijal complex in Kohistan; Amalaoulaou arc in Mali; Fiordland arc in New-Zealand). Intense influx of mantle-derived basaltic magmas at high pressure in a thickening island arc can enable lower crustal rocks to locally cross the dehydration-melting solidus of hydrous subalkaline basalts. Thermodynamic modeling using Perple_X, geochemical analysis and compilation of experimental and field data have been combined to constrain processes, conditions and consequences of intra-arc melting. The position of the solidus in a P-T grid is strongly dependent of the bulk water content: at 1 GPa, it is as low as 750 °C for water saturated hornblende-gabbros (>1 wt% H2O) and 830°C for gabbros with 0.1 wt% H2O. Incipient melting (F <10 %) near the solidus produces trondhjemitic melt and garnet granulites residue. The latter has composition very close to that of igneous precursors but is characterized by contrasted physical properties (density: 3.2-3.3, Vp: 6.9-7.4 km/s). Higher partial melting degrees (F: 10-20 %) lead to the formation of anorthositic melts in equilibrium with garnet-clinopyroxene-rutile residues (density: up to 3.45, Vp: up to 7.7 km/s). These melts are rich in LILE (Rb, Ba, Sr) and LREE but strongly depleted in HREE and Y, while the residues are moderately enriched in Ti, Zr, Nb, HREE and Y but depleted in LREE relative to their igneous precursors. Compared to depleted mantle values, the residues also have low Rb/Sr but high Sm/Nd and Lu/Hf ratios. Partial melting in the lowermost oceanic arc crust thus produces the conditions to trigger gravity-driven delamination of the root and could lead to introduction of fertile arc garnet pyroxenites within the upper mantle. However, in Kohistan and at Amalaoulaou, the dense garnet-clinopyroxene residues are dispersed in the arc roots; they are intermingled with hornblendite and pyroxenite bodies. The small density contrast between garnet granulites and the harzburgitic mantle, and the low volumes of garnet-clinopyroxene residues preclude massive delamination of the partial melting residues. Further numerical modeling of physical modifications induced by dehydration-melting together with igneous mineral segregation in arc roots will help constraining fundamental parameters (mantle and arc crust rheology and density, composition, P-T conditions, volume and rate of incoming basaltic fluxes…) that control the stability of the lowermost arc crust.

ADHD-Related School Compositional Effects: An Exploration

ERIC Educational Resources Information Center

Stone, Susan; Brown, Timothy T.; Hinshaw, Stephen P.

2010-01-01

Background/Context: Children with attention-deficit/hyperactivity disorder (ADHD) provide a test case through which to investigate psychosocial school compositional effects. Characterized by developmentally atypical levels of inattention, activity, and impulsivity, the condition often manifests itself, and is identified, in school settings and is…

Controls on the iron isotopic composition of global arc magmas

NASA Astrophysics Data System (ADS)

Foden, John; Sossi, Paolo A.; Nebel, Oliver

2018-07-01

We determined the iron isotope composition of 130 mafic lavas from 15 arcs worldwide with the hypothesis that the results would reflect the relatively high oxidation state of arc magmas. Although this expectation was not realized, this Fe isotope data set reveals important insights into the geodynamic controls and style of the melting regimes in the sub-arc mantle. Samples are from oceanic arcs from the circum-Pacific, the Indonesian Sunda-Banda islands, Scotia and the Lesser Antilles as well as from the eastern Pacific Cascades. Their mean δ57Fe value is +0.075 ± 0.05‰, significantly lighter than MORB (+0.15 ± 0.03‰). Western Pacific arcs extend to very light δ57Fe (Kamchatka = -0.11 ± 0.04‰). This is contrary to expectation, because Fe isotope fractionation factors (Sossi et al., 2016, 2012) and the incompatibility of ferric versus ferrous iron during mantle melting, predict that melts of more oxidized sources will be enriched in heavy Fe isotopes. Subducted oxidation capacity flux may correlate with hydrous fluid release from the slab. If so, a positive correlation between each arc's thermal parameter (ϕ) and δ57Fe is predicted. On the contrary, the sampled arcs mostly contribute to a negative array with the ϕ value. High ϕ arcs, largely in the western Pacific, have primary magmas with lower δ57Fe values than the low ϕ, eastern Pacific arcs. Arcs with MORB-like Sr-, Nd- and Pb-isotopes, show a large range of δ57Fe from heavy MORB-like values (Scotia or the Cascades) to very light values (Kamchatka, Tonga). Although all basalts with light δ57Fe values have MORB-like Pb-, Nd- and Sr-isotope ratios some, particularly those from eastern Indonesia, have heavier δ57Fe and higher Pb- and Sr- and lower Nd-isotope ratios reflecting sediment contamination of the mantle wedge. Because basalts with MORB-like radiogenic isotopes range all the way from heavy to light δ57Fe values this trend is process-, not source composition-driven. Neither the slab-derived influx of fluids with light iron or sediment-derived melts with heavier iron can drive the iron isotopic shifts. The trend to light iron isotopes is partly the result of repeated, hydrous flux-driven, fO2-buffered, melting of initially normal-DMM-like mantle. However the most negative δ57Fe must also reflect re-melting of sources that have experienced prior diffusive (disequilibrium) stripping of heavy Fe isotopes due to rapid melt extraction and metasomatism. Data from intra-arc to back-arc rifts in the western Pacific show that these arc signatures are rapidly dispersed by influx of DMM or OIB mantle once intra- and back-arc rifting and slab rollback gains momentum. We suggest that the characteristic light arc signatures only form when the source is lodged under arcs where sub-arc mantle undergoes corner flow forming an isolated roll. This process of heavy iron depletion is most efficient in the high ϕ arcs of the western Pacific and least prevalent in the low ϕ arcs of the eastern Pacific where δ57Fe values are MORB-like. This implies that there is a fundamental change in character of sub-arc mantle melting between east and west Pacific, percolative and fluid fluxed in the west and diapiric and decompressional in the east.

Beam-contamination-induced compositional alteration and its neutron-atypical consequences in ion simulation of neutron-induced void swelling

DOE PAGES

Gigax, Jonathan G.; Kim, Hyosim; Aydogan, Eda; ...

2017-05-16

Although accelerator-based ion irradiation has been widely accepted to simulate neutron damage, neutron-atypical features need to be carefully investigated. In this study, we have shown that Coulomb force drag by ion beams can introduce significant amounts of carbon, nitrogen, and oxygen into target materials even under ultra-high vacuum conditions. The resulting compositional and microstructural changes dramatically suppress void swelling. By applying a beam-filtering technique, introduction of vacuum contaminants is greatly minimized and the true swelling resistance of the alloys is revealed and matches neutron behavior closely. These findings are a significant step toward developing standardized procedures for emulating neutron damage.

[Spectra and thermal analysis of the arc in activating flux plasma arc welding].

PubMed

Chai, Guo-Ming; Zhu, Yi-Feng

2010-04-01

In activating flux plasma arc welding the welding arc was analyzed by spectra analysis technique, and the welding arc temperature field was measured by the infrared sensing and computer image technique. The distribution models of welding arc heat flow density of activating flux PAW welding were developed. The composition of welding arc affected by activated flux was studied, and the welding arc temperature field was studied. The results show that the spectral lines of argon atom and ionized argon atom of primary ionization are the main spectra lines of the conventional plasma welding arc. The spectra lines of weld metal are inappreciable in the spectra lines of the conventional plasma welding arc. The gas particle is the main in the conventional plasma welding arc. The conventional plasma welding arc is gas welding arc. The spectra lines of argon atom and ionized argon atom of primary ionization are intensified in the activating flux plasma welding arc, and the spectra lines of Ti, Cr and Fe elements are found in the activating flux plasma welding arc. The welding arc temperature distribution in activating flux plasma arc welding is compact, the outline of the welding arc temperature field is narrow, the range of the welding arc temperature distribution is concentrated, the welding arc radial temperature gradient is large, and the welding arc radial temperature gradient shows normal Gauss distribution.

The Lake Forest Tuff Ring, Lake Tahoe, CA: Age and Geochemistry of a Post-arc Phreatomagmatic Eruption

NASA Astrophysics Data System (ADS)

Cousens, B. L.; Henry, C. D.; Pauly, B. D.

2007-12-01

The Lake Tahoe region of the northern Sierra Nevada consists of Mesozoic plutonic rocks blanketed by Mio- Pliocene arc volcanic rocks and locally overlain by < 2.5 Ma post-arc lavas. Several volcanic features along the Lake Tahoe shoreline indicate that magmas commonly erupted into shallow regions of the lake during the last 2.5 Ma, including the Eagle Rock vent (Kortemeier and Schweickert 2007), Tahoe City pillow lavas and palagonite layers, and the Lake Forest tuff ring (Sylvester et al., 2007). Here we report on the age and composition of the rocks at Lake Forest, aiming to identify the source of the volcanic rocks compared to arc and post-arc lavas in the area. The low-relief Lake Forest tuff ring, located on the lakeshore west of Dollar Point, consists of radially outward-dipping layers composed primarily of loosely-cemented angular, microvesicular lava fragments with minor basaltic bombs and a scoria pile at the east end of the exposed ring. Most fragments are poorly phyric, and two samples are andesites similar to post-arc lavas sampled at higher elevations. The bombs are vesicular, poorly olivine/plagioclase-phyric basaltic andesites with chilled margins and glassy matrices. Scoria in the scoria pile, which we tentatively interpret as a slump, are similar texturally to the bombs but are more silica-rich. Chemically, the fragments, bombs and scoria are more primitive (higher Mg number) than local post-arc and arc lavas, and have trace element ratios and normalized incompatible element patterns similar to, but not identical to, local post-arc lava flows. Thus the Lake Forest tuff ring was the product of a shoreline eruptive event and did not form from lavas flowing downslope into the water. The fragments, bombs and scoria each have different radiogenic isotopic compositions and incompatible element ratios, indicating that primary magma compositions varied during the eruption(s) that produced the tuff ring. Our ongoing geochronological analyses will help constrain the timing of magmatism and the formation of Lake Tahoe.

Petrology of the Basalt of Summit Creek: A [Slab] Window into Pacific Northwest Tectonics during the Eocene

NASA Astrophysics Data System (ADS)

Kant, L. B.; Tepper, J. H.; Nelson, B. K.

2012-12-01

Variation in composition of basalts within the Cascade arc reflects the regional effects of subducting slab windows. The earliest preserved Tertiary manifestation of this process is the 55-44 Ma Basalt of Summit Creek (BSC), located southeast of Mount Rainier. At the base of this steeply dipping 2000 m section of subaerial lavas are basalts / diabases with arc traits (e.g., HFSE depletions, 1.0-1.2 wt. % K2O) and isotopic compositions (207Pb/204Pb > 15.58; ɛNd = +5.8 to +6.7) that overlap those of modern Cascade arc rocks. Conformably overlying these arc rocks (and separated by ~35m of shale, sandstone and conglomerate) are tholeiitic basalts with OIB affinities (<0.4 wt. % K2O, Y/Nb = 1.1-2.3, concave spidergram profiles) and isotopic signatures of a more depleted mantle source (207Pb/204Pb < 15.56; ɛNd = +7.1 to +7.8). In major element, trace element, and isotopic composition the upper BSC lavas are broadly similar to the voluminous Crescent Formation basalts on the Olympic Peninsula, which are coeval with the BSC but located ~100 km farther west. Compositional diversity within the upper BSC section (Mg# 66-30) appears to reflect both fractional crystallization and source heterogeneity. Modeling with MELTS (Ghiroso and Sack, 1995) indicates that differentiation dominated by removal of clinopyroxene and plagioclase took place at mid crustal depths (P = 5 kbar) and that the parent magma had <0.2 wt. % water. However, this process cannot account for all incompatible element data, which indicate the existence of two distinct magma series that differ most notably in Sr, Zr, and K2O contents. Arc basalts of the lower BSC may represent the southernmost extension of the Cretaceous-Tertiary North Cascades arc (Miller et al., 2009); however, basalts higher in the section have OIB traits and reflect a different tectonic setting. We propose that the transition from arc to OIB magmatism in the BSC records the arrival beneath the arc of a slab window produced by subduction of the Kula-Farallon Ridge (KFR). Previous research on subduction of the KFR has been limited to the coast. Improved dating and petrology of the BSC will help to better constrain the location and behavior of the KFR slab window as it moved further inboard beneath the North American plate.

Magnesium Isotopic Composition of Kamchatka Sub-Arc Mantle Peridotites

NASA Astrophysics Data System (ADS)

Hu, Y.; Teng, F. Z.; Ionov, D. A.

2016-12-01

Subduction of the oceanic slab may add a crustal isotopic signal to the mantle wedge. The highly variable Mg isotopic compositions (δ26Mg) of the subducted oceanic crust input[1] and arc lava output[2] imply a distinctive Mg isotopic signature of the mantle wedge. Magnesium isotopic data on samples from the sub-arc mantle are still limited, however. To characterize the Mg isotopic composition of typical sub-arc mantle, 17 large and fresh spinel harzburgite xenoliths from Avacha volcano were analyzed. The harzburgites were formed by 30% melt extraction at ≤ 1 2 GPa and fluid fluxing condition, and underwent possible fluid metasomatism as suggested by distinctively high orthopyroxene mode in some samples, the presence of accessory amphibole and highly variable Ba/La ratios[3]. However, their δ26Mg values display limited variation from -0.32 to -0.21, which are comparable to the mantle average at -0.25 ± 0.07[4]. The overall mantle-like and homogenous δ26Mg of Avacha sub-arc peridotites are consistent with their similar chemical compositions and high MgO contents (> 44 wt%) relative to likely crustal fluids. Furthermore, clinopyroxene (-0.24 ± 0.10, 2SD, n = 5), a late-stage mineral exsolved from high-temperature, Ca-rich residual orthopyroxene, is in broad Mg isotopic equilibrium with olivine (-0.27 ± 0.04, 2SD, n = 17) and orthopyroxene (-0.22 ± 0.06, 2SD, n = 17). Collectively, this study finds that the Kamchatka mantle wedge, as represented by the Avacha peridotites, has a mantle-like δ26Mg, and low-degree fluid-mantle interaction does not cause significant Mg isotope fractionation in sub-arc mantle peridotites. [1] Wang et al., EPSL, 2012 [2] Teng et al., PNAS, 2016 [3] Ionov, J. Petrol., 2010, [4] Teng et al., GCA, 2010.

Monogenetic Arc Volcanism in the Central Andes: The "Hidden" Mafic Component in the Land of Andesite and Ignimbrite

NASA Astrophysics Data System (ADS)

van Alderwerelt, B. M.; Ukstins Peate, I.; Ramos, F. C.

2016-12-01

Faulting in the upper crust of the Central Andes has provided passage for small volumes of mafic magma to reach the surface, providing a window into petrogenetic processes in the region's deep crust and upper mantle. Mafic lavas are rare in the Central Andean region dominated by intermediate-composition arc volcanism and massive sheets of silicic ignimbrite, and provide key data on magmatic origin, evolution, and transport. This work characterizes fault-controlled, within-arc monogenetic eruptive centers representative of the most mafic volcanism in the Altiplano-Puna region of the Andes since (at least) the Mesozoic. Olivine-phyric basaltic andesite (54 wt% SiO2, 7.3 wt% MgO) at Cerro Overo maar and associated dome, La Albóndiga Grande, and an olivine-clinopyroxene flow (53 wt% SiO2, 6.7 wt% MgO) from Cordón de Puntas Negras have been erupted at the intersection of regional structural features and the modern volcanic arc. Bulk magma chemistry, radiogenic isotopes, and microanalyses of mineral and melt inclusion composition provide insight on the composition(s) of mafic magmas being delivered to the lowermost crust and the deep crustal processes which shape central Andean magma. Bulk major and trace elements follow regional arc differentiation trends and are clearly modified by crustal magmatic processes. In contrast, microanalyses reveal a much richer history with olivine-hosted melt inclusions recording multiple distinct magmas, including potential primary melts. Single crystal olivine 87Sr/86Sr from Cerro Overo (0.7041-0.7071) define a broader range than whole rock (0.7062-0.7065), indicating preservation of juvenile melt in olivine-hosted inclusions lost at the whole rock scale. Mineral chemistry (via EMPA) P-T calculations define a petrogenetic history for these endmember lavas. Field mapping, bulk chemistry, and microanalyses outline the generation, storage, transportation, and eventual eruption of the "hidden" mafic component of the Andean arc.

An Overview of the Southern Mariana Subduction Factory: Arc, Cross-Chains, and Back-Arc Basin

NASA Astrophysics Data System (ADS)

Stern, R. J.; Hargrove, U. S.; Leybourne, M. I.; Pearce, J. A.; Bloomer, S. H.

2002-12-01

The Mariana arc system south of 18°N provides 3 opportunities to study the magmatic outputs of the IBM Subduction Factory: 1) Along the Magmatic arc; 2) Across arc cross-chains; and 3) Along the back-arc basin spreading axis. In spite of being located near population centers of Guam and Saipan, this is a relatively poorly known part of the arc system. There is a clear break in the trend and morphology of the magmatic arc west of the144°E fault and slab tear, and we surveyed and sampled the region north and east of this during the Cook 7 expedition in March-April 2001. Systematic morphologic covariations are observed along the arc and backarc basin magmatic systems, with the shallower ridge depths adjacent to more magmatically-robust arc segments. Our preliminary results reveal a compositional discontinuity in back-arc basin basalts (BABB) south of a bathymetric break near 15°30'N, with BABB in shallower segments to the north having a strong subduction component (higher Ba/Nb, Rb, Zr, etc.) and deeper regions to the south being more MORB-like. This is close to the morphological break along the magmatic front, with larger (>10E11 m3) edifices of the Central Island Province north of 16°N and smaller, entirely submarine volcanoes to the south, implying a more robust magmatic budget in the north; a similar variations are observed for cross-chain volcanoes, with smaller ones associated with the smaller, southern arc volcanoes and larger ones associated with the larger arc volcanoes of the Central Island Province. In contrast to the back-arc basin spreading axis, no systematic compositional variations are observed along or across the arc. Arc and cross-chains comprise a coherent, low- to medium-K, dominantly tholeiitic suite. REE patterns show moderate LREE-enrichment, with chondrite-normalized La/Yb = 1.5-2. Rear-arc volcanoes sometimes are slightly less fractionated, slightly more potassic, and slightly more LREE-enriched, but these are second order differences. The strong increase in K and LREE enrichment and decrease in fluid-mobile elements observed for the Kasuga cross-chain to the north is not observed in the southern cross-chains.

Manganese in occupational arc welding fumes--aspects on physiochemical properties, with focus on solubility.

PubMed

Taube, Fabian

2013-01-01

Physicochemical properties, such as particle sizes, composition, and solubility of welding fumes are decisive for the bioaccessibility of manganese and thereby for the manganese cytotoxic and neurotoxic effects arising from various welding fumes. Because of the diverse results within the research on welding fume solubility, this article aims to review and discuss recent literature on physicochemical properties of gas metal arc welding, shielded metal arc welding, and flux-cored arc welding fumes, with focus on solubility properties. This article also presents a short introduction to the literature on arc welding techniques, health effects from manganese, and occupational exposure to manganese among welders.

Sr-isotopic composition of marbles from the Puerto Galera area (Mindoro, Philippines): additional evidence for a Paleozoic age of a metamorphic complex in the Philippine island arc

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knittel, U.; Daniels, U.

1987-02-01

The Sr-isotopic composition of marbles from the Puerto Galera area (Mindoro, Philippines) is compatible with either a Tertiary or a Paleozoic age. The former is considered as unlikely because nonmetamorphic sediments of that age overlie the metamorphic complex. This implies that the metamorphic complex does not represent the basement of the Philippine arc but is an accreted terrane.

Metal transfer and V-I transients in GMAW of aluminium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pandey, S.; Rao, U.R.K.; Aghakhani, M.

1996-12-31

The mode of metal transfer in arc welding significantly affects the positional weldability; particularly the overhead welding, the chemical composition and properties of weld metal, metallurgy of weld metal, weld pool stability, arc stability, spatter losses, and weld bead geometry. The mode of metal transfer is affected mainly by the type of the arc, welding current, electrode polarity, arc voltage, contact tube to plate distance (CTPD)/Stand-off, type and flow rate of the shielding gas, torch angle and alloying elements in GMAW of aluminium and its alloys.

Magmatism and Epithermal Gold-Silver Deposits of the Southern Ancestral Cascade Arc, Western Nevada and Eastern California

USGS Publications Warehouse

John, David A.; du Bray, Edward A.; Henry, Christopher D.; Vikre, Peter

2015-01-01

Many epithermal gold-silver deposits are temporally and spatially associated with late Oligocene to Pliocene magmatism of the southern ancestral Cascade arc in western Nevada and eastern California. These deposits, which include both quartz-adularia (low- and intermediate-sulfidation; Comstock Lode, Tonopah, Bodie) and quartz-alunite (high-sulfidation; Goldfield, Paradise Peak) types, were major producers of gold and silver. Ancestral Cascade arc magmatism preceded that of the modern High Cascades arc and reflects subduction of the Farallon plate beneath North America. Ancestral arc magmatism began about 45 Ma, continued until about 3 Ma, and extended from near the Canada-United States border in Washington southward to about 250 km southeast of Reno, Nevada. The ancestral arc was split into northern and southern segments across an inferred tear in the subducting slab between Mount Shasta and Lassen Peak in northern California. The southern segment extends between 42°N in northern California and 37°N in western Nevada and was active from about 30 to 3 Ma. It is bounded on the east by the northeast edge of the Walker Lane. Ancestral arc volcanism represents an abrupt change in composition and style of magmatism relative to that in central Nevada. Large volume, caldera-forming, silicic ignimbrites associated with the 37 to 19 Ma ignimbrite flareup are dominant in central Nevada, whereas volcanic centers of the ancestral arc in western Nevada consist of andesitic stratovolcanoes and dacitic to rhyolitic lava domes that mostly formed between 25 and 4 Ma. Both ancestral arc and ignimbrite flareup magmatism resulted from rollback of the shallowly dipping slab that began about 45 Ma in northeast Nevada and migrated south-southwest with time. Most southern segment ancestral arc rocks have oxidized, high potassium, calc-alkaline compositions with silica contents ranging continuously from about 55 to 77 wt%. Most lavas are porphyritic and contain coarse plagioclase ± hornblende, biotite, and pyroxene phenocrysts. Seven epithermal gold-silver deposits with >1 Moz gold production, several large elemental sulfur deposits, and many large areas (10s to >100 km2) of hydrothermally altered rocks are present in the southern ancestral arc, especially south of latitude 40°N. These deposits are principally hosted by intermediate to silicic lava dome complexes; only a few deposits are associated with mafic- to intermediate-composition stratovolcanoes. Large deposits are most abundant and well developed in volcanic fields whose evolution spanned millions of years. Most deposits are hundreds of thousands to several million years younger than their host rocks, although some quartz-alunite deposits are essentially coeval with their host rocks. Variable composition and thickness of crustal basement is the primary control on mineralization along the length of the southern ancestral arc; most deposits and large alteration zones are localized in basement rock terranes with a strong continental affinity, either along the edge of the North American craton (Goldfield, Tonopah) or in an accreted terrane with continental affinities (Walker Lake terrane; Aurora, Bodie, Comstock Lode, Paradise Peak). Epithermal deposits and quartz-alunite alteration zones are scarce to absent in the northern part of the ancestral arc above an accreted island arc (Black Rock terrane) or unknown basement rocks (Modoc Plateau). Walker Lane structures and areas that underwent large magnitude extension during the Late Cenozoic (areas with Oligocene-early Miocene volcanic rocks dipping >40°) do not provide regional control on mineralization. Instead, these features may have served as local-scale conduits for mineralizing fluids.

Influencing the arc and the mechanical properties of the weld metal in GMA-welding processes by additive elements on the wire electrode surface

NASA Astrophysics Data System (ADS)

Wesling, V.; Schram, A.; Müller, T.; Treutler, K.

2016-03-01

Under the premise of an increasing scarcity of raw materials and increasing demands on construction materials, the mechanical properties of steels and its joints are gaining highly important. In particular high- and highest-strength steels are getting in the focus of the research and the manufacturing industry. To the same extent, the requirements for filler metals are increasing as well. At present, these low-alloy materials are protected by a copper coating (<1μm) against corrosion. In addition, the coating realizes a good ohmic contact and good sliding properties between the welding machine and the wire during the welding process. By exchanging the copper with other elements it should be possible to change the mechanical properties of the weld metal and the arc stability during gas metal arc welding processes and keep the basic functions of the coating nearly untouched. On a laboratory scale solid wire electrodes with coatings of various elements and compounds such as titanium oxide were made and processed with a Gas Metal Arc Welding process. During the processing a different process behavior between the wire electrodes, coated and original, could be observed. The influences ranges from greater/shorter arc-length over increasing/decreasing droplets to larger/smaller arc foot point. Furthermore, the weld metal of the coated electrodes has significantly different mechanical and technological characteristics as the weld metal from the copper coated ground wire. The yield strength and tensile strength can be increased by up to 50%. In addition, the chemical composition of the weld metal was influenced by the application of coatings with layer thicknesses to 15 microns in the lower percentage range (up to about 3%). Another effect of the coating is a modified penetration. The normally occurring “argon finger” can be suppressed or enhanced by the choice of the coating. With the help of the presented studies it will be shown that Gas Metal Arc Welding processes are significantly affected by thin film coatings on solid wire electrodes for Gas Metal Arc welding. The influences are regarding the stability of the arc, the properties of the weld metal in terms of geometric expression, chemical composition and mechanical properties, the composition of the arc-plasma and the dynamics of the molten metal.

Long-Term Geochemical and Geodynamic Segmentation of the Paleo-Pacific Margin of Gondwana: Insight From the Antarctic and Adjacent Sectors

NASA Astrophysics Data System (ADS)

Nelson, D. A.; Cottle, J. M.

2017-12-01

Combined zircon geochemistry and geochronology of Mesozoic volcaniclastic sediments of the central Transantarctic Mountains, Antarctica, yield a comprehensive record of both the timing and geochemical evolution of the magmatic arc along the Antarctic sector of the paleo-Pacific margin of Gondwana. Zircon age populations at 266-183 Ma, 367-328 Ma, and 550-490 Ma correspond to episodic arc activity from the Ediacaran to the Jurassic. Zircon trace element geochemistry indicates a temporal shift from granitoid-dominated source(s) during Ediacaran to Early Ordovician times to mafic sources in the Devonian through Early Jurassic. Zircon initial ɛHf shifts to more radiogenic Hf isotope compositions following the Ross Orogeny and is inferred to reflect juvenile crustal growth within an extensional arc system during progressive slab rollback. These new ages and Hf isotopic record are similar to those from the Australian sector, indicating that these regions constituted an 3,000 km laterally continuous extensional arc from at least the Carboniferous to the Permian. Conversely, the South American sector records enriched zircon Hf isotopic compositions and compressional/advancing arc tectonics during the same time period. Our new data constrain the location of this profound along-arc geochemical and geodynamic "switch" to the vicinity of the Thurston Island block of West Antarctica.

The determination of micro-arc plasma composition and properties of nanoparticles formed during cathodic plasma electrolysis of 304 stainless steel

NASA Astrophysics Data System (ADS)

Jovović, Jovica; Stojadinović, Stevan; Vasilić, Rastko; Tadić, Nenad; Šišović, Nikola M.

2017-05-01

This paper presents the research focused on the determination of micro-arc plasma composition during cathodic plasma electrolysis of AISI304 stainless steel in water solution of sodium hydroxide. The complex line shape of several Fe I spectral lines was observed and, by means of a dedicated fitting procedure based on the spectral line broadening theory and H2O thermal decomposition data, the mole fraction of micro-arc plasma constituents (H2, Fe, O, H, H2O, and OH) was determined. Subsequent characterization of the cathodic plasma electrolysis product formed during the process revealed that it consists of Fe-nanoparticles with median diameter of approximately 60 nm.

Resolving the crustal composition paradox by 3.8 billion years of slab failure magmatism and collisional recycling of continental crust

NASA Astrophysics Data System (ADS)

Hildebrand, Robert S.; Whalen, Joseph B.; Bowring, Samuel A.

2018-06-01

In the standard paradigm, continental crust is formed mainly by arc magmatism, but because the compositions of magma rising from the mantle are basaltic and continental crust is estimated to contain about 60% SiO2 and much less MgO than basalt, the two do not match. To resolve this paradox, most researchers argue that large amounts of magmatic fractionation produce residual cumulates at the base of the crust, which because arcs are inferred to have magmatically thickened crust, form eclogites that ultimately founder and sink into the mantle. Not only are there problems with the contrasting bulk compositions, but the standard model also fails because prior to collision most modern arcs do not have thick crust, as documented by their eruption close to sea level, and in cases of ancient arc sequences, their intercalation with marine sedimentary rocks. Our study of Cretaceous batholiths in the North American Cordillera resolves the crustal composition paradox because we find that most are not arc-derived as commonly believed; but instead formed during the waning stages of collision and consequent slab failure. Because the batholiths typically have silica contents >60% and are derived directly from the mantle, we argue that they are the missing link in the formation of continental crust. Slab failure magmas worldwide are compositionally similar to tonalite-trondhjemite-granodiorite suites as old as 3.8 Ga, which points to their collective formation by slab failure and long-lived plate tectonics. Our model also provides (1) an alternative solution to interpret compiled detrital zircon arrays, because episodic peaks that coincide with periods of supercontinent amalgamation are easily interpreted to represent collisions with formation of new crust by slab failure; and (2) that models of early whole-earth differentiation are more reasonable than those invoking progressive growth of continental crust.

Geochemical Variation of Subducting Pacific Crust Along the Izu-Bonin Arc System and its Implications on the Generation of Arc Magmas

NASA Astrophysics Data System (ADS)

Durkin, K.; Castillo, P.; Abe, N.; Kaneko, R.; Straub, S. M.; Garcia, E. S. M.; Yan, Q.; Tamura, Y.

2015-12-01

Subduction zone magmatism primarily occurs due to flux melting of the mantle wedge that has been metasomatized by the slab component. The latter is enriched in volatiles and fluid-mobile elements and derived mainly from subducted sediments and altered oceanic crust (AOC). Subduction input has been linked to arc output in many studies, but this relationship is especially well documented in sedimented arc-trench systems. However, the Izu-Bonin system is sediment-poor, therefore the compositional and latitudinal variations (especially in Pb isotopes) of its arc magmas must be sourced from the subduction component originating primarily from the AOC. Pb is a very good tracer of recycled AOC that may contribute 50% or more of arc magma Pb. Izu-Bonin arc chemistry suggests a subduction influx of Indian-type crust, but the subducting crust sampled at ODP Site 1149 is Pacific-type. The discrepancy between subduction input and arc output calls into question the importance of the AOC as a source of the subduction component, and raises major concerns with our understanding of slab input. During the R/V Revelle 1412 cruise in late 2014, we successfully dredged vertical fault scarps at several sites from 27.5 N to 34.5 N, spanning a range of crustal ages that include a suggested compositional change at ~125 Ma. Major element data show an alkali enrichment towards the north of the study transect. Preliminary incompatible trace element data (e.g. Ba, Zr and Sr) data support this enrichment trend. Detailed mass balance calculations supported by Sr, Nd, Hf and especially Pb isotope analyses will be performed to evaluate whether the AOC controls the Pb isotope chemistry of the Izu-Bonin volcanic arc.

Cumberland batholith, Trans-Hudson Orogen, Canada: Petrogenesis and implications for Paleoproterozoic crustal and orogenic processes

NASA Astrophysics Data System (ADS)

Whalen, Joseph B.; Wodicka, Natasha; Taylor, Bruce E.; Jackson, Garth D.

2010-06-01

Large volume, plutonic belts, such as the ˜ 221,000 km 2, ca. 1.865-1.845 Ga Cumberland batholith (CB) of the Trans-Hudson Orogen in Canada, are major components of Paleoproterozoic orogenic belts. In many cases, they have been interpreted as continental arc batholiths. The petrogenesis and tectonic context of the CB and implications for crustal growth and recycling are interpreted herein based on a 900 km geochemical-isotopic (Nd-O) transect across it and into granitoid plutons within bounding Archean cratons in central and southern Baffin Island. The mainly granulite grade CB, emplaced over an age span of between 14 and 24 Ma, consists mainly of high-K to shoshonitic monzogranite and granodiorite, but also includes low- and medium-K granitoid rocks. Metaluminous to slightly peraluminous compositions and δ 18O (VSMOW) values (+ 6 to + 10‰) indicate derivation from infracrustal (I-type) sources. ɛ Nd 1.85 Ga signatures (- 12 to - 2) of both mafic and felsic units suggest a dominance of evolved sources. Isotopic signatures in the interior of the CB (- 2 to - 7) are more radiogenic than those within Archean domains in central (- 8 to - 15) and southern (- 5 to - 19) Baffin Island. The isotopic transect is interpreted as 'imaging' an accreted microcontinental block (Meta Incognita) and bounding Archean cratons. The CB includes granites of arc, within-plate (A-type) and post-collisional affinity and volumetrically minor mafic rocks with both arc and non-arc features. (La/Yb) CN and Sr/Y values range from < 1 to 225 and < 1 to 611, respectively. In these respects, some CB granitoid rocks resemble Paleozoic adakitic granites, interpreted as partial melts of greatly thickened crust within post-collisional settings, such as Tibet. Thus, the CB likely encompasses various non-consanguineous magmatic suites generated at deep- to mid-crustal depths. Although CB granitoid rocks undoubtedly had important crustal sources, it is hard to assess the relative contribution of mantle-derived magmas. The CB is best interpreted as a post-accretion batholith resulting from large-scale lithospheric mantle delamination followed by the upwelling of hot asthenospheric mantle leading to voluminous crustal partial melting. Contributors to crustal instability which may have facilitated such delamination included: (a) a collage of recently assembled small cratons underlain by hot, weak lithosphere with mantle-depth structural breaks within this segment of the Trans-Hudson Orogen; (b) the gabbro-eclogite phase transformation, and (c) a greatly thickened crustal section (> 60 km), as evidenced by adakitic granites.

Magma genesis of the acidic volcanism in the intra-arc rift zone of the Izu volcanic arc, Japan

NASA Astrophysics Data System (ADS)

Haraguchi, S.; Tokuyama, H.; Ishii, T.

2010-12-01

The Izu volcanic arc extends over 550 km from the Izu Peninsula, Japan, to the Nishinoshima Trough or Sofugan tectonic line. It is the northernmost segment of the Izu-Bonin-Mariana arc system, which is located at the eastern side of the Philippine Sea Plate. The recent magmatism of the Izu arc is bimodal and characterized by basalt and rhyolite (e.g. Tamura and Tatsumi 2002). In the southern Izu arc, volcanic front from the Aogashima to the Torishima islands is characterized by submarine calderas and acidic volcanisms. The intra-arc rifting, characterized by back-arc depressions, small volcanic knolls and ridges, is active in this region. Volcanic rocks were obtained in 1995 during a research cruise of the R/V MOANA WAVE (Hawaii University, cruise MW9507). Geochemical variation of volcanic rocks and magma genesis was studied by Hochstaedter et al. (2000, 2001), Machida et al (2008), etc. These studies focused magma and mantle dynamics of basaltic volcanism in the wedge mantle. Acidic volcanic rocks were also dredged during the curies MW9507. However, studies of these acidic volcanics were rare. Herein, we present petrographical and chemical analyses of these acidic rocks, and compare these results with those of other acidic rocks in the Izu arc and lab experiments, and propose a model of magma genesis in a context of acidic volcanism. Dredge sites by the cruise MW9507 are 120, and about 50 sites are in the rift zone. Recovered rocks are dominated by the bimodal assemblage of basalt-basaltic andesite and dacite-rhyolite. The most abundant phase is olivine basalt, less than 50 wt% SiO2. Andesites are minor in volume and compositional gap from 56 to 65 wt% SiO2 exists. The across-arc variation of the HFSE contents and ratios, such as Zr/Y and Nb/Zr of rhyolites exhibit depleted in the volcanic front side and enriched in reararc side. This characteristic is similar to basaltic volcanism pointed out by Hochstaedter et al (2000). The petrographical features of rhyolites exhibit massive or flow textures, and aphyric or rare phyric. Phenocrysts are mainly plagioclase and quartz. Colored minerals are rare and observed mainly orthopyroxene. Amphibole and biotite are not observed. The phenocryst and groundmass mineral compositions of rhyolites exhibit felsic characteristics and narrow ranges. These mineral compositions are not overlapped on those of andesites and basalts. Acidic volcanism in the Izu arc is considered to partial melting of arc middle to lower crust (e.g. Tamura and Tatsumi, 2003) because rhyolite exhibits similar composition to melting experimental results of basaltic or andesitic parental material under anhydrous, low pressure and low temperature (e.g. Shukuno et al., 2006). Compare to these experiments, we consider that parent material of acidic volcanics in the rift zone is andesitic middle crust, and this crust exhibits depleted in the front side and enriched in the reararc side caused by across-arc variation of basaltic volcanism. During the rifting activity, rhyolitic magma was produced by melting of this andesitic middle crust by heating from magma and decompression, and produced rhyolites exhibit enriched in reararc side and depleted in front side.

Early Carboniferous adakite-like and I-type granites in central Qiangtang, northern Tibet: Implications for intra-oceanic subduction and back-arc basin formation within the Paleo-Tethys Ocean

NASA Astrophysics Data System (ADS)

Liu, Jin-Heng; Xie, Chao-Ming; Li, Cai; Wang, Ming; Wu, Hao; Li, Xing-Kui; Liu, Yi-Ming; Zhang, Tian-Yu

2018-01-01

Recent studies have proposed that the Late Devonian ophiolites in the central Qiangtang region of northern Tibet were formed in an oceanic back-arc basin setting, which has led to controversy over the subduction setting of the Longmucuo-Shuanghu-Lancangjiang Suture Zone (LSLSZ) during the Late Devonian to Early Carboniferous. In this paper we present new data about a suite of granite plutons that intrude into ophiolite in central Qiangtang. Our aim was to identify the type of subduction and to clarify the existence of an intra-oceanic back-arc basin in the LSLSZ during the Late Devonian to Early Carboniferous. The suite of granites consists of monzogranites, syenogranites, and granodiorites. Our laser ablation-inductively coupled plasma-mass spectrometry zircon U-Pb data yielded Early Carboniferous crystallization ages of 357.2 Ma, 357.4 Ma and 351.1 Ma. We subsequently investigated the petrogenesis and tectonic setting of these granites based on their geochemical and Hf isotopic characteristics. First, we divided the granites into high Sr/Y (HSG) and low Sr/Y granites (LSG). The HSG group contains monzogranites and granodiorites that have similar geochemical characteristics to adakites (i.e., high Sr/Y and La/Yb ratios, low MgO, Y, and Yb contents, and no pronounced negative Eu anomaly), although they have slightly lower Sr and Al2O3 contents, caused by crystal fractionation during late magmatic evolution. Therefore, we define the HSG group as adakite-like granites. The study of the HSG shows that they are adakite-like granites formed by partial melting of oceanic crust and experience fractional crystallization process during late evolution. However, some differences between the monzogranites and granodiorites indicate that there are varying degree contributions of subducted sediments during diagenesis. The LSG group contains syenogranites that have distinct negative correlations between their P2O5 and SiO2 contents, and Y and Th contents have significant positive correlations with Rb. The above characteristics indicate that the syenogranites are typical I-type granites. The results of this study also show that the LSG were produced by magma mixing between the mantle and juvenile oceanic crust. The field study found that the Early Carboniferous suite of granites intruded into contemporaneous ophiolites that formed in an intra-oceanic back-arc basin, and were associated with coeval A-type granites in this region. Based on the geochemical and isotopic data presented in this paper and regional geological data, we consider that the HSG were formed during intra-oceanic subduction of the Paleo-Tethys Ocean in the Early Carboniferous. The LSG and A-type granites were formed in an intra-oceanic back-arc basin setting caused by roll-back of the Paleo-Tethys Ocean slab. This confirms that the subduction of the Paleo-Tethys Ocean in the Early Carboniferous was intra-oceanic subduction, and provides important evidence for the existence of an intra-oceanic back-arc basin during the Late Devonian to Early Carboniferous.

Petrographic and Geochemical Investigation of Andesitic Arc Volcanism: Mount Kerinci, Sunda Arc, Indonesia

NASA Astrophysics Data System (ADS)

Tully, M.; Saunders, K.; Troll, V. R.; Jolis, E.; Muir, D. D.; Deegan, F. M.; Budd, D. A.; Astbury, R.; Bromiley, G. D.

2014-12-01

Present knowledge of the chain of dominantly andesitic volcanoes, which span the Sumatran portion of the Sunda Arc is extremely limited. Previous studies have focused on Toba and Krakatau, although over 13 further volcanic edifices are known. Several recent explosive eruptions in Sumatra such as that of Mt. Sinabung, 2014, have highlighted the potential hazard that these volcanoes pose to the local and regional communities. Mount Kerinci, is one of the most active of the volcanoes in this region, yet little is known about the petrogenesis of the magma by which it is fed. Kerinci is located approximately mid-way between Toba in the North and Krakatau in the south. Along arc variations are observed in the major, minor and trace elements of whole rock analyses. However, bulk rock approaches produce an average chemical composition for a sample, potentially masking important chemical signatures. In-situ micro-analytical analysis of individual components of samples such as melt inclusions, crystals and groundmass provides chemical signatures of individual components allowing the evolution of volcanic centres to be deciphered in considerably more detail. Examination of whole rock chemistry indicates its location may be key to unravelling the petrogenesis of the arc as significant chemical changes occur between Kerinci and Kaba, 250 km to the south. Kerinci samples are dominantly porphyritic with large crystals of plagioclase, pyroxene and Fe-Ti oxides, rare olivine crystals are observed. Plagioclase and pyroxene crystals are chemically zoned and host melt inclusions. Multiple plagioclase populations are observed. A combination of in-situ micro-analysis techniques will be used to characterise the chemical composition of melt inclusions and crystals. These data can be used along with extant geothermobarometric models to help determine the magma source, storage conditions and composition of the evolving melt. Integration of the findings from this study with existing data for the volcanic chain will enable along-arc variations in magmatic processes in Sumatra to be assessed more thoroughly, providing fundamental insights into the evolution of not only Kerinci, but magma genesis in Sumatra in general. Keywords: Sunda Arc, andesite, arc volcanism, petrogenesis.

Generation of multicomponent ion beams by a vacuum arc ion source with compound cathode.

PubMed

Savkin, K P; Yushkov, Yu G; Nikolaev, A G; Oks, E M; Yushkov, G Yu

2010-02-01

This paper presents the results of time-of-flight mass spectrometry studies of the elemental and mass-to-charge state compositions of metal ion beams produced by a vacuum arc ion source with compound cathode (WC-Co(0.5), Cu-Cr(0.25), Ti-Cu(0.1)). We found that the ion beam composition agrees well with the stoichiometric composition of the cathode material from which the beam is derived, and the maximum ion charge state of the different plasma components is determined by the ionization capability of electrons within the cathode spot plasma, which is common to all components. The beam mass-to-charge state spectrum from a compound cathode features a greater fraction of multiply charged ions for those materials with lower electron temperature in the vacuum arc cathode spot, and a smaller fraction for those with higher electron temperature within the spot. We propose a potential diagram method for determination of attainable ion charge states for all components of the compound cathodes.

New constraints on subduction inputs and volatile outputs along the Aleutian Arc

NASA Astrophysics Data System (ADS)

Lopez, T. M.; Fischer, T. P.; Plank, T. A.; Rizzo, A. L.; Rasmussen, D. J.; Cottrell, E.; Werner, C. A.; Kern, C.; Ilanko, T.; Buff, L.; Andrys, J.; Kelley, K. A.

2017-12-01

Volatile cycling drives volcanism in subduction zone settings. At arcs, volatiles can originate from the subducted slab, mantle wedge and/or crust. Each region has characteristic isotopic signatures, which can be used to fingerprint volatile provenance. We speculate that differences in subduction parameters, such as convergence angle, plate coupling and subducted sediment fluxes, may lead to differences in volatile provenance, which may in turn influence volcanic eruption style and frequency. Here we combine updated constraints on subduction inputs and volatile outputs to provide new insights into volatile cycling within the Aleutian Arc. The high proportion of organic carbon (80-100% to total carbon) in sediments subducting at the Aleutian trench stands out globally and predicts a light carbon isotopic composition of recycled volcanic fluids. We assess volatile outputs on volcanic timescales and along the arc by combining carbon (C), nitrogen (N) and helium (He) isotopic compositions of volcanic gases and new analyses of He and, where possible, C isotopes in olivine-hosted fluid inclusions. From our preliminary isotopic analyses of volcanic gases, we find a greater proportion of mantle-derived volatiles released from the Western segment of the Aleutian Arc (>40% mantle) compared with other volcanic arcs around the world (<30% mantle), where volatiles are sourced primarily from subducted or upper crustal carbonates. This trend may be due to the oblique convergence and low subducted sediment input in this region. The Aleutian Arc also exhibits among the lightest carbon isotope ratios of arcs worldwide (δ13C = -10 to -15‰), especially in the central part of the arc, where organic-bearing terrigneous sediment fills the trench and the convergence rate is high. New constraints on subduction inputs and outputs presented here will help discriminate between upper crustal and subducted carbon sources, and provide further insights into volatile cycling and subduction processes within the Aleutian Arc.

Magmatically Greedy Reararc Volcanoes of the N. Tofua Segment of the Tonga Arc

NASA Astrophysics Data System (ADS)

Rubin, K. H.; Embley, R. W.; Arculus, R. J.; Lupton, J. E.

2013-12-01

Volcanism along the northernmost Tofua Arc is enigmatic because edifices of the arc's volcanic front are mostly, magmatically relatively anemic, despite the very high convergence rate of the Pacific Plate with this section of Tonga Arc. However, just westward of the arc front, in terrain generally thought of as part of the adjacent NE Lau Backarc Basin, lie a series of very active volcanoes and volcanic features, including the large submarine caldera Niuatahi (aka volcano 'O'), a large composite dacite lava flow terrain not obviously associated with any particular volcanic edifice, and the Mata volcano group, a series of 9 small elongate volcanoes in an extensional basin at the extreme NE corner of the Lau Basin. These three volcanic terrains do not sit on arc-perpendicular cross chains. Collectively, these volcanic features appear to be receiving a large proportion of the magma flux from the sub-Tonga/Lau mantle wedge, in effect 'stealing' this magma flux from the arc front. A second occurrence of such magma 'capture' from the arc front occurs in an area just to the south, on southernmost portion of the Fonualei Spreading Center. Erupted compositions at these 'magmatically greedy' volcanoes are consistent with high slab-derived fluid input into the wedge (particularly trace element abundances and volatile contents, e.g., see Lupton abstract this session). It is unclear how long-lived a feature this is, but the very presence of such hyperactive and areally-dispersed volcanism behind the arc front implies these volcanoes are not in fact part of any focused spreading/rifting in the Lau Backarc Basin, and should be thought of as 'reararc volcanoes'. Possible tectonic factors contributing to this unusually productive reararc environment are the high rate of convergence, the cold slab, the highly disorganized extension in the adjacent backarc, and the tear in the subducting plate just north of the Tofua Arc.

Back-arc basalts from the Loncopue graben (Province of Neuquen, Argentina)

NASA Astrophysics Data System (ADS)

Varekamp, J. C.; Hesse, A.; Mandeville, C. W.

2010-11-01

Young basaltic back-arc volcanoes occur east of the main Andes chain at about 37.5°-39°S in the Loncopue graben, Province of Neuquen, Argentina. These olivine-rich basalts and trachybasalts have up to 8% MgO, with high Ni and Cr contents, but highly variable incompatible element concentrations. Mafic lava flows and cinder cones at the southern end of the graben lack phenocrystic plagioclase. The northern samples have relative Ta-Nb depletions and K, Pb and LREE enrichment. These samples strongly resemble rocks of the nearby arc volcanoes Copahue and Caviahue, including their Fe-Ti enrichment relative to the main Andes arc rocks. The Sr, Nd and Pb isotope ratios show that the source regions of these back-arc basalts are enriched in subducted components that were depleted in the aqueous mobile elements such as Cs, Sr and Ba as a result of prior extractions from the subducted complex below the main arc. Some mafic flows show slightly low 206Pb/ 204Pb and 143Nd/ 144Nd values as well as incompatible trace element ratios similar to southern Patagonia plateau back-arc basalts, suggesting contributions from an EM1 mantle source. Geothermometry and barometry suggest that the basalts crystallized and fractionated small amounts of olivine and spinel at ˜ 35 km depth at temperatures of 1170-1220 °C, at about QFM + 0.5 to QFM + 1 with 1-2% H 2O, and then rose rapidly to the surface. The Loncopue graben back-arc basalts are transitional in composition between the South Patagonia back-arc plateau basalts and the Caviahue and Copahue arc volcanoes to the northwest. The EM1 source endmember is possibly the subcontinental lithospheric mantle. Strong variations in incompatible element enrichment and isotopic compositions between closely spaced cinder cones and lava flows suggest a heterogeneous mantle source for the Loncopue graben volcanics.

Spectroscopy peculiarities of thermal plasma of electric arc discharge between electrodes with Zn admixtures

NASA Astrophysics Data System (ADS)

Semenyshyn, R. V.; Veklich, A. N.; Babich, I. L.; Boretskij, V. F.

2014-10-01

Plasma of the free burning electric arc between Ag-SnO2-ZnO composite electrodes as well as brass electrodes were investigated. The plasma temperature distributions were obtained by Boltzmann plot method involving Cu I, Ag I or Zn I spectral line emissions. The electron density distributions were obtained from the width and from absolute intensity of spectral lines. The laser absorption spectroscopy was used for measurement of copper atom concentration in plasma. Plasma equilibrium composition was calculated using two independent groups of experimental values (temperature and copper atom concentration, temperature and electron density). It was found that plasma of the free burning electric arc between brass electrodes is in local thermodynamical equilibrium. The experimental verification of the spectroscopic data of Zn I spectral lines was carried out.

A petrologic comparison of Triassic plutonism in the San Gabriel and Mule Mountains, southern California

NASA Astrophysics Data System (ADS)

Barth, Andrew P.; Tosdal, R. M.; Wooden, J. L.

1990-11-01

Triassic magmatism in the southwest U.S. Cordillera forms a semicontinuous magmatic arc extending from northwestern Nevada to southeastern California. Quartz monzodioritic and quartz monzonitic rocks and associated diorites and granites are widespread in southeastern California, and we suggest that these rocks represent exposure of a structurally deeper part of the Triassic arc, where it was emplaced into comparatively thick Proterozoic crust. Elemental and isotopic data suggest that Triassic quartz monzodiorites and quartz monzonites in the Mule and San Gabriel Mountains were derived from a relatively undepleted, nonradiogenic mafic lithospheric source, with virtually no upper crustal interaction. Very limited data for associated Triassic(?) diorites indicate a wide range in composition and a surprisingly radiogenic isotopic signature. Younger Triassic(?) granites record a strong geochemical signature of interaction with continental crust, including inherited zircon and high initial Sr ratios but comparatively less radiogenic Pb isotopic compositions. The major and trace element geochemistry of Late Triassic plutonic rocks in southeastern California is similar in many respects to alkalic components of the Triassic arc in the Mojave Desert. However, contemporaneous rocks farther north have a calc-alkalic signature, perhaps reflecting the variation in age and composition of lithosphere across which the Triassic arc was constructed.

A petrologic comparison of Triassic plutonism in the San Gabriel and Mule Mountains, southern California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barth, A.P.; Tosdal, R.M.; Wooden, J.L.

1990-11-10

Triassic magmatism in the southwest US Cordillera forms a semicontinuous magmatic arc extending from northwestern Nevada to southeastern California. Quartz monzodioritic and quartz monzonitic rocks and associated diorites and granites are widespread in southeastern California, and the authors suggest that these rocks represent exposure of a structurally deeper part of the Triassic arc, where it was emplaced into comparatively thick Proterozoic crust. Elemental and isotopic data suggest that Triassic quartz monzodiorites and quartz monzonites in the Mule and San Gabriel Mountains were derived from a relatively undepleted, nonradiogenic mafic lithospheric source, with virtually no upper crustal interaction. Very limited datamore » for associated Triassic ( ) diorites indicate a wide range in composition and a surprisingly radiogenic isotopic signature. Younger Triassic( ) granites record a strong geochemical signature of interaction with continental crust, including inherited zircon and high initial Sr ratios but comparatively less radiogenic Pb isotopic compositions. The major and trace element geochemistry of Late Triassic plutonic rocks in southeastern California is similar in many respects to akalic components of the Triassic arc in the Mojave Desert. However, contemporaneous rocks farther north have a calc-alkalic signature, perhaps reflecting the variation in age and composition of lithosphere across which the Triassic arc was constructed.« less

Origin and tectonic evolution of early Paleozoic arc terranes abutting the northern margin of North China Craton

NASA Astrophysics Data System (ADS)

Zhou, Hao; Pei, Fu-Ping; Zhang, Ying; Zhou, Zhong-Biao; Xu, Wen-Liang; Wang, Zhi-Wei; Cao, Hua-Hua; Yang, Chuan

2017-12-01

The origin and tectonic evolution of the early Paleozoic arc terranes abutting the northern margin of the North China Craton (NCC) are widely debated. This paper presents detrital zircon U-Pb and Hf isotopic data of early Paleozoic strata in the Zhangjiatun arc terrane of central Jilin Province, northeast (NE) China, and compares them with the Bainaimiao and Jiangyu arc terranes abutting the northern margin of the NCC. Detrital zircons from early Paleozoic strata in three arc terranes exhibit comparable age groupings of 539-430, 1250-577, and 2800-1600 Ma. The Paleoproterozoic to Neoarchean ages and Hf isotopic composition of the detrital zircons imply the existence of the Precambrian fragments beneath the arc terranes. Given the evidences from geology, igneous rocks, and detrital zircons, we proposed that the early Paleozoic arc terranes abutting the northern margin of the NCC are a united arc terrane including the exotic Precambrian fragments, and these fragments shared a common evolutionary history from Neoproterozoic to early-middle Paleozoic.

Thermal emittance enhancement of graphite-copper composites for high temperature space based radiators

NASA Technical Reports Server (NTRS)

Rutledge, Sharon K.; Forkapa, Mark J.; Cooper, Jill M.

1991-01-01

Graphite-copper composites are candidate materials for space based radiators. The thermal emittance of this material, however, is a factor of two lower than the desired emittance for these systems of greater than or equal to 0.85. Arc texturing was investigated as a surface modification technique for enhancing the emittance of the composite. Since the outer surface of the composite is copper, and samples of the composite could not be readily obtained for testing, copper was used for optimization testing. Samples were exposed to various frequencies and currents of arcs during texturing. Emittances near the desired goal were achieved at frequencies less than 500 Hz. Arc current did not appear to play a major role under 15 amps. Particulate carbon was observed on the surface, and was easily removed by vibration and handling. In order to determine morphology adherence, ultrasonic cleaning was used to remove the loosely adherent material. This reduced the emittance significantly. Emittance was found to increase with increasing frequency for the cleaned samples up to 500 Hz. The highest emittance achieved on these samples over the temperature range of interest was 0.5 to 0.6, which is approximately a factor of 25 increase over the untextured copper emittance.

Geochemical and Isotopic Data from Micron to Across-Arc Scales in the Andean Central Volcanic Zone: Applications for Resolving Crustal Magmatic Differentiation and Modification Processes

NASA Astrophysics Data System (ADS)

Michelfelder, G.; Wilder, A.; Feeley, T.

2014-12-01

Plagioclase crystals from silicic (andesitic to dacitic) lavas and domes at Volcán Uturuncu, a potentially active volcano in the back-arc of the Andean CVZ (22.3°S, 67.2°W), exhibit large variations in An contents, textures, and core to rim 87Sr/86Sr ratios. Many of the isotopic variations can not have existed at magmatic temperatures for more than a few thousand years. The crystals likely derived from different locations in the crustal magmatic system and mixed just prior to eruption. Uturuncu magmas initially assimilated crustal rocks with high 87Sr/86Sr ratios. The magmas were subsequently modified by frequent recharge of more mafic magmas with lower 87Sr/86Sr ratios. A typical Uturuncu silicic magma therefore only attains its final composition just prior to or during eruption. In the Lazufre region of active surface uplift (~25˚14'S; Volcán Lastarria and Cordon del Azufre) closed system differentiation processes are not the only factors influencing silicic magma compositions. 87Sr/86Sr (0.70651-0.70715) and 206Pb/204Pb ratios (18.83-18.88) are highly elevated and143Nd/144Nd ratios (0.512364 -0.512493) are low relative to similar composition rocks from the "southern Cordillera domain." These data, along with major and trace element trends, reflect a multitude of differentiation processes and magma sources including crystallization-differentiation of more mafic magmas, melting and assimilation of older crustal rocks, and magma mixing and mingling. On an arc-wide scale silicic lavas erupted from three well-characterized composite volcanoes between 21oS and 22oS (Aucanquilcha, Ollagüe, and Uturuncu) display systematically higher K2O, LILE, REE and HFSE contents and 87Sr/86Sr ratios with increasing distance from the arc-front. In contrast, the lavas have systematically lower Na2O, Sr, and Ba contents; LILE/HFSE ratios; 143Nd/144Nd ratios; and more negative Eu anomalies. Silicic magmas along the arc-front apparently reflect melting of relatively young, mafic composition amphibolitic source rocks with the continental crust becoming increasingly older with a more felsic bulk composition toward the east. We suggest this results from progressively smaller degrees of mantle partial melting, primary melt generation, and crustal hybridization with distance from the arc-front.

Community Structure Comparisons of Hydrothermal Vent Microbial Mats Along the Mariana Arc and Back-arc

NASA Astrophysics Data System (ADS)

Hager, K. W.; Fullerton, H.; Moyer, C. L.

2015-12-01

Hydrothermal vents along the Mariana Arc and back-arc represent a hotspot of microbial diversity that has not yet been fully recognized. The Mariana Arc and back-arc contain hydrothermal vents with varied vent effluent chemistry and temperature, which translates to diverse community composition. We have focused on iron-rich sites where the dominant primary producers are iron oxidizing bacteria. Because microbes from these environments have proven elusive in culturing efforts, we performed culture independent analysis among different microbial communities found at these hydrothermal vents. Terminal-restriction fragment length polymorphism (T-RFLP) and Illumina sequencing of small subunit ribosomal gene amplicons were used to characterize community members and identify samples for shotgun metagenomics. Used in combination, these methods will better elucidate the composition and characteristics of the bacterial communities at these hydrothermal vent systems. The overarching goal of this study is to evaluate and compare taxonomic and metabolic diversity among different communities of microbial mats. We compared communities collected on a fine scale to analyze the bacterial community based on gross mat morphology, geography, and nearby vent effluent chemistry. Taxa richness and evenness are compared with rarefaction curves to visualize diversity. As well as providing a survey of diversity this study also presents a juxtaposition of three methods in which ribosomal small subunit diversity is compared with T-RFLP, next generation amplicon sequencing, and metagenomic shotgun sequencing.

Petrology and age of volcanic-arc rocks from the continental margin of the Bering Sea: implications for Early Eocene relocation of plate boundaries

USGS Publications Warehouse

Davis, A.S.; Pickthorn, L.-B.G.; Vallier, T.L.; Marlow, M. S.

1989-01-01

Eocene volcanic flow and dike rocks from the Beringian margin have arc characteristics, implying a convergent history for this region during the early Tertiary. Chemical and mineralogical compositions are similar to those of modern Aleutian-arc lavas. They also resemble volcanic-arc compositions from western mainland Alaska, although greater chemical diversity and a stronger continental influence are observed in the Alaskan mainland rocks. Early Eocene ages of 54.4-50.2 Ma for the Beringian samples are well constrained by conventional K-Ar ages of nine plagioclase separates and by concordant 40Ar/39Ar incremental heating and total-fusion experiments. A concordant U-Pb zircon age of 53 Ma for the quartz-diorite dike is in good agreement with the K-Ar data. Plate motion studies of the North Pacific Ocean indicate more northerly directed subduction prior to the Tertiary and a continuous belt of arc-type volcanism extending from Siberia, along the Beringian margin, into mainland Alaska. Around 56 Ma (chron 25-24), subduction changed to a more westerly direction and subduction-related volcanism ceased for most of mainland Alaska. The increasingly oblique angle of convergence should have ended subduction along the Beringian margin as well. However, consistent ages of 54-50 Ma indicate a final pulse in arc-type magmatism during this period of plate adjustment. -from Authors

Cycling of sulfur in subduction zones: The geochemistry of sulfur in the Mariana Island Arc and back-arc trough

USGS Publications Warehouse

Alt, J.C.; Shanks, Wayne C.; Jackson, M.C.

1993-01-01

The sulfur contents and sulfur isotopic compositions of 24 glassy submarine volcanics from the Mariana Island Arc and back-arc Mariana Trough were determined in order to investigate the hypothesis that subducted seawater sulfur (??34S = 21???) is recycled through arc volcanism. Our results for sulfur are similar to those for subaerial arc volcanics: Mariana Arc glasses are enriched in 34S (??34S = up to 10.3???, mean = 3.8???) and depleted in S (20-290 ppm, mean = 100 ppm) relative to MORB (850 ppm S, ??34S = 0.1 ?? 0.5???). The back-arc trough basalts contain 200-930 ppm S and have ??34S values of 1.1 ?? 0.5???, which overlap those for the arc and MORB. The low sulfur contents of the arc and some of the trough glasses are attributed to (1) early loss of small amounts of sulfur through separation of immiscible sulfide and (2) later vapor-melt equilibrium control of sulfur contents and loss of sulfur in a vapor phase from sulfide-undersaturated melts near the minimum in sulfur solubility at f{hook}O2 ??? NNO (nickel-nickel oxide). Although these processes removed sulfur from the melts their effects on the sulfur isotopic compositions of the melts were minimal. Positive trends of ??34S with 87Sr 86Sr, LILE and LREE contents of the arc volcanics are consistent with a metasomatic seawater sulfur component in the depleted sub-arc mantle source. The lack of a 34S-rich slab signature in the trough lavas may be attributed to equilibration of metasomatic fluid with mantle material along the longer pathway from the slab to the source of the trough volcanics. Sulfur is likely to have been transported into the mantle wedge by metasomatic fluid derived from subducted sediments and pore fluids. Gases extracted from vesicles in arc and back-arc samples are predominantly H2O, with minor CO2 and traces of H2S and SO2. CO2 in the arc and back-arc rocks has ??13C values of -2.1 to -13.1???, similar to MORB. These data suggest that degassing of CO2 could explain the slightly lower ??13C values for some Mariana Trough volcanic glasses, and that incorporation of subduction-derived organic carbon into the Mariana Trough mantle source may not be necessary. More analyses are required to resolve this question, however. ?? 1993.

Intergranular metal phase increases thermal shock resistance of ceramic coating

NASA Technical Reports Server (NTRS)

Carpenter, H. W.

1966-01-01

Dispersed copper phase increases the thermal shock resistance of a plasma-arc-sprayed coating of zirconia used as a heat barrier on a metal substrate. A small amount of copper is deposited on the granules of the zirconia powder before arc-spraying the resultant powder composite onto the substrate.

The mantle source of island arc magmatism during early subduction: Evidence from Hf isotopes in rutile from the Jijal Complex (Kohistan arc, Pakistan)

NASA Astrophysics Data System (ADS)

Ewing, Tanya A.; Müntener, Othmar

2018-05-01

The Cretaceous-Paleogene Kohistan arc complex, northern Pakistan, is renowned as one of the most complete sections through a preserved paleo-island arc. The Jijal Complex represents a fragment of the plutonic roots of the Kohistan arc, formed during its early intraoceanic history. We present the first Hf isotope determinations for the Jijal Complex, made on rutile from garnet gabbros. These lithologies are zircon-free, but contain rutile that formed as an early phase. Recent developments in analytical capabilities coupled with a careful analytical and data reduction protocol allow the accurate determination of Hf isotope composition for rutile with <30 ppm Hf for the first time. Rutile from the analysed samples contains 5-35 ppm Hf, with sample averages of 13-17 ppm. Rutile from five samples from the Jijal Complex mafic section, sampling 2 km of former crustal thickness, gave indistinguishable Hf isotope compositions with εHf(i) ranging from 11.4 ± 3.2 to 20.1 ± 5.7. These values are within error of or only slightly more enriched than modern depleted mantle. The analysed samples record variable degrees of interaction with late-stage melt segregations, which produced symplectitic overprints on the main mineral assemblage as well as pegmatitic segregations of hydrous minerals. The indistinguishable εHf(i) across this range of lithologies demonstrates the robust preservation of the Hf isotope composition of rutile. The Hf isotope data, combined with previously published Nd isotope data for the Jijal Complex garnet gabbros, favour derivation from an inherently enriched, Indian Ocean type mantle. This implies a smaller contribution from subducted sediments than if the source was a normal (Pacific-type) depleted mantle. The Jijal Complex thus had only a limited recycled continental crustal component in its source, and represents a largely juvenile addition of new continental crust during the early phases of intraoceanic magmatism. The ability to determine the Hf isotope composition of rutile with low Hf contents is an important development for zircon-free mafic lithologies. This study highlights the potential of Hf isotope analysis of rutile to characterise the most juvenile deep arc crust cumulates worldwide.

Exotic Members of Southern Alaska's Jurassic Arc

NASA Astrophysics Data System (ADS)

Todd, E.; Jones, J. V., III; Karl, S. M.; Box, S.; Haeussler, P. J.

2017-12-01

The Jurassic Talkeetna arc and contemporaneous plutonic rocks of the Alaska-Aleutian Range batholith (ARB) are key components of the Peninsular terrane of southern Alaska. The Talkeetna arc, considered to be a type example of an intra-oceanic arc, was progressively accreted to northwestern North America in the Jurassic to Late Cretaceous, together with associated components of the Wrangellia Composite terrane. Older Paleozoic and Mesozoic rock successions closely associated with the ARB suggest that at least part of the Peninsular terrane might be an overlap succession built on pre-existing crust, possibly correlative with the Wrangellia terrane to the east. However, the relationship between the Talkeetna arc, ARB, and any pre-existing crust remains incompletely understood. Field investigations focused on the petrogenesis of the ARB near Lake Clark National Park show that Jurassic to Late Cretaceous plutonic rocks commonly host a diverse range of mineralogically distinct xenolith inclusions, ranging in size from several cm to hundreds of meters. The modal fraction of these inclusions ranges from <1% to >50% in some outcrops. They are generally mafic in composition and, with few exceptions, are more mafic than host plutonic rocks, although they are observed as both igneous (e.g., gabbro cumulate, diorite porphyry) and metamorphic types (e.g., amphibolite, gneiss and quartzite). Inclusion shapes range from angular to rounded with sharp to diffuse boundaries and, in some instances, are found as planar, compositionally distinct bands or screens containing high-temperature ductile shear fabrics. Other planar bands are more segmented, consistent with lower-temperature brittle behavior. Comparison of age, geochemical fractionation trends, and isotope systematics between the inclusions and host plutons provides a critical test of whether they are co-genetic with host plutons. Where they are related, mafic inclusions provide clues about magmatic evolution and fractionation history of the Jurassic arc. In cases where they are not related, inclusion composition and texture provides important clues about of pre-existing basement and insights into its possible tectonic affinities, and some host-inclusion textures provide evidence for both partial melting of, and physical mingling with, preexisting crust.

Variation of oil composition in vicinity of Arbuckle Mountains, Oklahoma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zemmels, I.; Walters, C.C.

1987-08-01

Fifteen oils in an 8-county area in the vicinity of the Arbuckle Mountains were classified into 6 oil types: stable platform type, Mill Creek syncline type, Joiner City field type, Gloeocapsamorpha type, Hoover field A-type; and Fitts field type. The stable platform, Mill Creek syncline, and Joiner City field types have a common element (diminished C/sub 32/ hopane) and are thought to be derived from distinctly different facies of the Woodford Formation. The Viola Limestone oil is typical of oil generated from Ordovician rocks. The Hoover field A-type has an element of Ordovician composition and is thought to have beenmore » derived from an Arbuckle Group shale. The Fitts field oil has a unique composition and has not been assigned to a source. The variation of oil composition in the vicinity of the Arbuckle Mountains is attributed to (1) the large number of potential source rocks, (2) the variety of facies going from the stable platform into the southern Oklahoma aulacogen, and (3) biodegradation of oils in shallow reservoirs.« less

Sr-Nd-Pb isotope variability across and along the Ecuadorian volcanic arc

NASA Astrophysics Data System (ADS)

Ancellin, Marie-Anne; Samaniego, Pablo; Vlastélic, Ivan; Nauret, François; Gannoun, Mouhcine; Hidalgo, Silvana

2016-04-01

Determining the contribution of different potential sources in arc magma genesis is of paramount importance for discriminating the role of deep-seated processes at work in the slab and mantle wedge, as well as the process occurring during the magma ascent through the arc crust. The Ecuadorian volcanic arc (2°S - 1°N) results from the subduction of the oceanic Nazca plate below the continental south-American plate. This volcanic province, developed in front of the subducting Carnegie ridge, is characterized by at least 50-60 volcanic centres of Pleistocene-Holocene age, which are distributed along the Western and Eastern Cordilleras and in the back-arc region. Previous studies on this province focused on two main issues: (1) the role of the deep-seated process occurring at the level of the subducting slab and the mantle wedge ([1], [2]), and (2) the role of crustal process ([3]). In this work, we use existing and new (57 samples from 36 volcanoes of the whole Ecuadorian arc) major-trace element and Sr-Nd-Pb isotope data to resolve precisely magma compositional changes occurring across and along the volcanic arc and to precise the role of the heterogeneous crust underlying this arc segment. In the 207Pb/204Pb vs. 206Pb/204Pb diagram, most of Western Cordillera volcanic centres and Back arc volcanoes display a flat trend characterized by a large variation in 206Pb/204Pb (18.5 - 19.15), with little variation in 207Pb/204Pb (15.54-15.62). Along this trend, back arc volcanoes tend towards unradiogenic compositions with Reventador as end-member whereas western cordilleras volcanoes generally show more radiogenic compositions (Pilavo, Imbabura). In contrast, the Eastern cordillera volcanoes display more radiogenic 207Pb/204Pb (15.60 - 15.70) or 208Pb/204Pb (38.7 - 39) at a given 206Pb/204Pb compared to the Western cordillera with similar variation in 206Pb/204Pb (18.85 - 19.05). Extreme compositions are observed at Tungurahua and Antisana volcanoes. Several volcanoes of the 2 cordilleras and of the inter-andean valley plot at the junction of the two trends. These new data confirm previous observations made with the trace element and Sr-Nd systematics that suggested marked differences between the two cordilleras ([1], [3], [4]), and allow us to go forward distinguishing the back-arc. In addition, we are able to test the influence of Carnegie ridge on magma geochemistry, which is still debated. Altogether, Sr-Nd-Pb isotope variations require three different magmatic sources: (1) an unradiogenic component, represented by back-arc magmas, which may correspond to the mantle source; (2) an upper crustal radiogenic component, expressed in Eastern cordillera magmas and (3) a third component (low 87Sr/86Sr, radiogenic Nd-Pb isotopes), represented by some Western Cordillera magmas, which could either be an unradiogenic, immature oceanic basement or a slab influence. [1] Hidalgo et al., Lithos 132-133 (2012), 180-192 [2] Samaniego et al., Contrib. Mineral. Petrol. 160 (2010), 239-260 [3] Chiaradia et al., Contrib. Mineral. Petrol. 158 (2009), 563-588 [4] Schiano et al., Contrib. Mineral. Petrol. 160 (2010), 297-312

Petrogenesis of Mesoproterozoic granitic plutons, eastern Llano Uplift, central Texas, USA

NASA Astrophysics Data System (ADS)

Smith, R. K.; Gray, Walt; Gibbs, Tyson; Gallegos, M. A.

2010-08-01

The Llano Uplift of central Texas is a gentle structural dome exposing ˜ 1370 to 1230 Ma metaigneous and metasedimentary rocks of Grenville affinity along the southern margin of Laurentia. The metamorphic rocks were subsequently intruded by ˜ 1119 to 1070 Ma late syn- to post-tectonic granites collectively known as the Town Mountain Granite (TMG). The eastern most of the TMG, the Marble Falls (MF), Kingsland (KL), and Lone Grove (LG) plutons, are metaluminous to marginally peraluminous, high-K, calc-alkaline, ferroan, biotite-calcic amphibole granites [Fe/(Fe + Mg) = 0.71-0.92 and 0.78-0.91 for biotite and calcic amphibole, respectively] displaying distinct variation trends with increasing silica content. They are chemically and texturally zoned and have mineralogical and chemical characteristics similar to A-type granites; i.e., 1) Fe-rich biotites, calcic amphiboles, accessory fluorite, and sporadic rapakivi texture, 2) high K 2O (> 4 wt.%), 3) low Al 2O 3 (< 16 wt.%) and CaO (< 3 wt.%), 4) high Fe/(Fe + Mg), 5) enrichments in Zr, Nb, REE, Ga/Al, and 6) depleted Eu. However, in contrast to typical A-type granites (having low Sr and Ba) the MF, KL,and LG plutons are enriched in Sr and Ba; i.e., up to 229 ppm and 1090 ppm, respectively. On granite discrimination diagrams [(K 2O + Na 2O)/CaO vs. Zr + Nb + Ce + Y (ppm) and Zr (ppm) vs. Ga/Al*10,000] the KL and MF plutons plot within the A-type field, whereas the LG pluton compositions are divided between A-type and fractionated granite fields (I-, S- and M-types). On tectonic discrimination diagrams (Y vs. Nb ) the MF and KL granites plot in the "within-plate" granite field, but the LG pluton plots across several fields including "within-plate" and "volcanic arc plus syn-collisional" fields. Consequently the tectonic classification on a geochemical basis for the LG pluton is unclear. Based on thermal metamorphic mineral assemblages, normative Q-Ab-Or plots, and Q-Ab-Or-H 2O experimental data (Johannes and Holtz, 1996), crystallization temperatures and pressures are estimated to range from 750 to 850 °C and 200 to 500 MPa, respectively. The assemblage of titanite + magnetite + quartz suggests crystallization at low fO2 [confirmed by Fe/(Fe + Mg) vs. [4] Al microprobe analyses of calcic amphibole] and a water content of less than 1.5 wt.% (Wones, 1989). Like other Town Mountain-type plutons, the MF, KL, and LG granites display comparable iron contents at similar alkali and silica enrichments. Melting models (Ba vs. Sr) suggest the MF, KL, and LG plutons may have evolved from the partial melting (anatexis) of juvenile, tonalitic, lower crustal rocks, followed by plagioclase and pyroxene dominated fractionation. Nd isotopic data for the MF pluton ( ɛNd = + 3.4 at 1.06 Ga; Patchett and Ruiz, 1989) and whole-rock δ18O values for the MF, KL, and LG plutons (+ 7.0 < δ 18O >+10.1‰; Rangel et al., 2008) suggest that the magmas in the eastern Llano Uplift may contain a significant mantle component, whereas relatively high δ18O values (+ 9.3 to + 9.7‰; Bebout and Carlson, 1986) for other coeval TMG rocks suggest that a significant crustal component is involved. Whole-rock and trace-element chemistry indicate that the MF and KL plutons, along with the coarser grained textures of the LG pluton, are 'A-type' granites. However, with no coeval mafic dikes, syenitic compositions, or volcanic rocks it is clear that the TMG plutons do not represent anorogenic granites. The available evidence is most compatible with emplacement of the TMG plutons in a post-orogenic (Grenville), relaxation and extensional (i.e., slab breakoff) setting.

Glass strengthening and patterning methods

DOEpatents

Harper, David C; Wereszczak, Andrew A; Duty, Chad E

2015-01-27

High intensity plasma-arc heat sources, such as a plasma-arc lamp, are used to irradiate glass, glass ceramics and/or ceramic materials to strengthen the glass. The same high intensity plasma-arc heat source may also be used to form a permanent pattern on the glass surface--the pattern being raised above the glass surface and integral with the glass (formed of the same material) by use of, for example, a screen-printed ink composition having been irradiated by the heat source.

Morphology of zirconia particles exposed to D.C. arc plasma jet

NASA Technical Reports Server (NTRS)

Zaplatynsky, Isidor

1987-01-01

Zirconia particles were sprayed into water with an arc plasma gun in order to determine the effect of various gun operating parameters on their morphology. The collected particles were examined by XRD and SEM techniques. A correlation was established between the content of spherical (molten) particles and the operating parameters by visual inspection and regression analysis. It was determined that the composition of the arc gas and the power input were the predominant parameters that affected the melting of zirconia particles.

Clinical survival of indirect, anterior 3-unit surface-retained fibre-reinforced composite fixed dental prosthesis: Up to 7.5-years follow-up.

PubMed

Kumbuloglu, Ovul; Özcan, Mutlu

2015-06-01

This prospective clinical study evaluated the performance of indirect, anterior, surface-retained, fibre-reinforced-composite restorations (ISFRCR). Between June-2003 and January-2011, a total of 134 patients (83 females, 51 males, 16-68 years old) received 175 ISFRCRs (local ethical registration number: 14/9/4). All restorations were made indirectly on a plaster model using unidirectional E-glass fibres (everStick C&B, StickTech) in combination with a laboratory resin composite (Dialogue, Schütz Dental) and cemented according to the instructions of 4 resin cements [(RelyX ARC, 3M-ESPE, n=61), Bifix DC, VOCO, n=45), Variolink II (Ivoclar Vivadent, n=32) and Multilink (Ivoclar Vivadent, n=37)]. After baseline recordings, patients were followed at 6 months and thereafter annually up to 7.5 years. The evaluation protocol involved technical (chipping, debonding or fracture of tooth/restoration) and biological failures (caries). Mean observation period was 58 months. Altogether, 13 failures were observed [survival rate: 97.7%] (Kaplan-Meier). One catastrophic fracture [(cement: RelyX ARC), eight partial debonding (cement: Bifix DC (5), Multilink (1), RelyX ARC (1), Variolink II (1)] and four delaminations of veneering composite [(cement: Bifix DC (2), RelyX ARC (1), Multilink (1)] were observed. Except one replacement, all defective restorations were repaired or recemented. Annual failure rate of ISFRCRs was 1.73%. The survival rates with the four resin cements did not show significant differences (RelyX ARC: 98.3%; Bifix DC: 93.5%; Variolink 2: 100%; Multilink: 100%) (p=0.114). Secondary caries did not occur in any of the teeth. The 3-unit anterior indirect surface-retained resin-bonded FRC FDPs showed similar clinical survival rate when cemented with the resin cements tested. Experienced failures in general were due to debonding of the restoration or delamination of the veneering composite. 3-unit surface retained resin-bonded FRC FDPs could be considered minimal invasive and cost-effective alternatives to conventional tooth- or implant-borne FDPs. Failures were mainly repairable in the form of chipping or debonding depending on the resin cement type. Copyright © 2015 Elsevier Ltd. All rights reserved.

Role of crystallizational differention in the origin of island-arc andesitic melts: evidence from data on melt inclusions and oxygen isotopes

NASA Astrophysics Data System (ADS)

Krasheninnikov, S. P.; Portnyagin, M.; Bindeman, I. N.; Bazanova, L. I.

2012-12-01

Several recent studies of melt inclusions in island-arc rocks revealed a strong bimodality of the melt compositions at the predominance of basic and silicic melts and the scarcity of intermediate melts with SiO2=59-66 wt% (e.g. [1]). These observations were used to interpret the origin of island-arc andesites by magma mingling, crustal assimilation and crystal accumulation rather than by fractional crystallization of basaltic magmas. In this work we addressed the question about the scarcity of andesitic melts in island-arc setting by systematic study of bulk compositions, melt inclusions and oxygen isotopes in minerals from Avachinskiy volcano in Kamchatka. We studied ~500 melt inclusions in 6 different mineral phases (Ol, Cpx, Opx, Pl, Amph, Mt), and concentrated on rapidly-quenched tephra samples from 40 Holocene eruptions of andesites and basaltic andesites. The melt inclusions span a large range of compositions from basalts to rhyolites. In comparison with host bulk tephra samples, melt inclusions tend to have more silicic compositions (up to 10 wt% of SiO2), and this disparity tend to increase with increasing SiO2 content in the host rocks. Both melt inclusion and host rock compositions form trends along the line dividing low- and middle-K island-arc series, and variations of major elements are continuous, without apparent bimodality, which is observed in data set from [1]. The MI statistical distribution is rather three-modal with maxima at ~56-58, ~66 and 74 wt% of SiO2. Much of the major element variability in MI can be explained by fractional crystallization from parental basaltic melts using numerical modeling of crystallization path. Magnetite crystallization starts at ~58 wt% of SiO2 and affects significantly on the evolutional path of melts. Abundant crystallization of magnetite lead to formation of more silica rich coexistent melts and change of crystallizing assemblage occurred at ~60 wt% of SiO2, when Opx replaced Ol, and Amph and Ap become stable. Paragenesis of OPx, CPx, Amph, Pl, Mt, Ilm and Ap dominated the following evolution of melts toward strongly acid compositions with 78-80 wt% SiO2. Individual Pl and Amph crystals are in magmatic isotopic equilibrium, have heavy δ18O values increasing from 6.3 ‰ in basaltic andesites to 7.1 ‰ in andesites, suggesting that magmatic evolution started from primary high-d18O basalt likely related to the abundant high-d18O sources described for Kamchatkan primitive magmas. The oxygen isotopic data support the conclusion that island-arc andesitic melts of Avachinsky Volcano generate predominantly due to the processes of fractional crystallization of high-d18O. The new data on composition of melt inclusions allowed us to reconstruct the entire spectrum of parental melts for Avacha volcano. Melt inclusions in different minerals form coherent trends of major elements, which can be well explained by fractional crystallization. Unlike some other island-arc volcanoes, Avachinskiy melts do not display clear bimodality of SiO2 content. Melts of intermediate compositions are relatively abundant and found in minerals from basaltic andesites. [1] Reuby & Blundy (2009) Nature, 461(7268), 1269-1273.

Free Fall Plasma-Arc Reactor for Synthesis of Carbon Nanotubes in Microgravity

NASA Technical Reports Server (NTRS)

Alford, J. M.; Mason, G. R.; Feinkema, D. A.

2006-01-01

High temperatures inside the plasma of a carbon arc generate strong buoyancy driven convection which has an effect on the growth and morphology of the single-walled carbon nanotubes (SWNTs). To study the effect of buoyancy on the arc process, a miniature carbon arc apparatus was designed and developed to synthesize SWNTs in a microgravity environment substantially free from buoyant convective flows. An arc reactor was operated in the 2.2- and 5.18-second drop towers at the NASA Glenn Research Center. The apparatus employed a 4 mm diameter anode and was powered by a portable battery pack capable of providing in excess of 300 amps at 30 volts to the arc for the duration of a 5-second drop. However, the principal result is that no dramatic difference in sample yield or composition was noted between normal gravity, 2.2-and 5-second long microgravity runs.

Growth of early continental crust by partial melting of eclogite.

PubMed

Rapp, Robert P; Shimizu, Nobumichi; Norman, Marc D

2003-10-09

The tectonic setting in which the first continental crust formed, and the extent to which modern processes of arc magmatism at convergent plate margins were operative on the early Earth, are matters of debate. Geochemical studies have shown that felsic rocks in both Archaean high-grade metamorphic ('grey gneiss') and low-grade granite-greenstone terranes are comprised dominantly of sodium-rich granitoids of the tonalite-trondhjemite-granodiorite (TTG) suite of rocks. Here we present direct experimental evidence showing that partial melting of hydrous basalt in the eclogite facies produces granitoid liquids with major- and trace-element compositions equivalent to Archaean TTG, including the low Nb/Ta and high Zr/Sm ratios of 'average' Archaean TTG, but from a source with initially subchondritic Nb/Ta. In modern environments, basalts with low Nb/Ta form by partial melting of subduction-modified depleted mantle, notably in intraoceanic arc settings in the forearc and back-arc regimes. These observations suggest that TTG magmatism may have taken place beneath granite-greenstone complexes developing along Archaean intraoceanic island arcs by imbricate thrust-stacking and tectonic accretion of a diversity of subduction-related terranes. Partial melting accompanying dehydration of these generally basaltic source materials at the base of thickened, 'arc-like' crust would produce compositionally appropriate TTG granitoids in equilibrium with eclogite residues.

Particulate and gaseous emissions when welding aluminum alloys.

PubMed

Cole, Homer; Epstein, Seymour; Peace, Jon

2007-09-01

Fabrication and repair of aluminum components and structures commonly involves the use of electric arc welding. The interaction of the arc and the metal being welded generates ultraviolet radiation, metallic oxides, fumes, and gases. Aluminum is seldom used as the pure metal but is often alloyed with other metals to improve strength and other physical properties. Therefore, the exact composition of any emissions will depend on the welding process and the particular aluminum alloy being welded. To quantify such emissions, The Aluminum Association sponsored several studies to characterize arc welding emissions by the gas metal arc welding (GMAW) and gas tungsten arc welding (GTAW) processes for various combinations of base and filler alloys. In all cases, the tests were conducted under conditions that could be found in a production weld shop without forced ventilation. The concentrations of each analyte that a welder could be exposed to were greatly affected by the welding process, the composition of the base and filler alloys, the position of the welder, and the welding helmet. The results obtained can be used by employers to identify and control potential hazards associated with the welding of aluminum alloys and can provide the basis for hazard communication to employees involved in the welding of these alloys.

Along and across arc geochemical variations in NW Central America: Evidence for involvement of lithospheric pyroxenite

NASA Astrophysics Data System (ADS)

Heydolph, Ken; Hoernle, Kaj; Hauff, Folkmar; Bogaard, Paul van den; Portnyagin, Maxim; Bindeman, Ilya; Garbe-Schönberg, Dieter

2012-05-01

The Central American Volcanic Arc (CAVA) has been the subject of intensive research over the past few years, leading to a variety of distinct models for the origin of CAVA lavas with various source components. We present a new model for the NW Central American Volcanic Arc based on a comprehensive new geochemical data set (major and trace element and Sr-Nd-Pb-Hf-O isotope ratios) of mafic volcanic front (VF), behind the volcanic front (BVF) and back-arc (BA) lava and tephra samples from NW Nicaragua, Honduras, El Salvador and Guatemala. Additionally we present data on subducting Cocos Plate sediments (from DSDP Leg 67 Sites 495 and 499) and igneous oceanic crust (from DSDP Leg 67 Site 495), and Guatemalan (Chortis Block) granitic and metamorphic continental basement. We observe systematic variations in trace element and isotopic compositions both along and across the arc. The data require at least three different endmembers for the volcanism in NW Central America. (1) The NW Nicaragua VF lavas require an endmember with very high Ba/(La, Th) and U/Th, relatively radiogenic Sr, Nd and Hf but unradiogenic Pb and low δ18O, reflecting a largely serpentinite-derived fluid/hydrous melt flux from the subducting slab into a depleted N-MORB type of mantle wedge. (2) The Guatemala VF and BVF mafic lavas require an enriched endmember with low Ba/(La, Th), U/Th, high δ18O and radiogenic Sr and Pb but unradiogenic Nd and Hf isotope ratios. Correlations of Hf with both Nd and Pb isotopic compositions are not consistent with this endmember being subducted sediments. Granitic samples from the Chiquimula Plutonic Complex in Guatemala have the appropriate isotopic composition to serve as this endmember, but the large amounts of assimilation required to explain the isotope data are not consistent with the basaltic compositions of the volcanic rocks. In addition, mixing regressions on Nd vs. Hf and the Sr and O isotope plots do not go through the data. Therefore, we propose that this endmember could represent pyroxenites in the lithosphere (mantle and possibly lower crust), derived from parental magmas for the plutonic rocks. (3) The Honduras and Caribbean BA lavas define an isotopically depleted endmember (with unradiogenic Sr but radiogenic Nd, Hf and Pb isotope ratios), having OIB-like major and trace element compositions (e.g. low Ba/(La, Th) and U/Th, high La/Yb). This endmember is possibly derived from melting of young, recycled oceanic crust in the asthenosphere upwelling in the back-arc. Mixing between these three endmember types of magmas can explain the observed systematic geochemical variations along and across the NW Central American Arc.

Thermodynamic properties and transport coefficients of air thermal plasmas mixed with ablated vapors of Cu and polytetrafluoroethylene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, JunMin, E-mail: jmzhang@buaa.edu.cn, E-mail: guanyg@tsinghua.edu.cn; Lu, ChunRong; Guan, YongGang, E-mail: jmzhang@buaa.edu.cn, E-mail: guanyg@tsinghua.edu.cn

2015-10-15

Because the fault arc in aircraft electrical system often causes a fire, it is particularly important to analyze its energy and transfer for aircraft safety. The calculation of arc energy requires the basic parameters of the arc. This paper is mainly devoted to the calculations of equilibrium composition, thermodynamic properties (density, molar weight, enthalpy, and specific heat at constant pressure) and transport coefficients (thermal conductivity, electrical conductivity, and viscosity) of plasmas produced by a mixture of air, Cu, and polytetrafluoroethylene under the condition of local thermodynamic equilibrium. The equilibrium composition is determined by solving a system of equations around themore » number densities of each species. The thermodynamic properties are obtained according to the standard thermodynamic relationships. The transport coefficients are calculated using the Chapman-Enskog approximations. Results are presented in the temperature range from 3000 to 30 000 K for pressures of 0.08 and 0.1 MPa, respectively. The results are more accurate and are reliable reference data for theoretical analysis and computational simulation of the behavior of fault arc.« less

Control of exposure to hexavalent chromium and ozone in gas metal arc welding of stainless steels by use of a secondary shield gas.

PubMed

Dennis, John H; French, Michael J; Hewitt, Peter J; Mortazavi, Seyed B; Redding, Christopher A J

2002-01-01

Previous work has demonstrated that the shield gas composition in gas metal arc welding can have a considerable effect on hexavalent chromium [Cr(VI)] concentration in the fume and on ozone concentrations near the arc. Normally a single shield gas is used. This paper describes a double shroud torch that allows used of concentric shield gases of different compositions. A solid stainless steel wire was used for welding. The double shroud torch used secondary shield gases containing small amounts of the reducing agents NO and C2H4. The Cr(VI) concentration in the fume and ozone concentration at a fixed point relative to the arc were measured and compared with results when using a single shield gas. Use of the reducing agents in secondary shielding using the double shroud torch was found to offer advantages for ozone concentration reduction compared with use in a conventional torch, but this was not found to be an advantage for reducing Cr(VI) concentrations.

IFN-gamma signaling in the central nervous system controls the course of experimental autoimmune encephalomyelitis independently of the localization and composition of inflammatory foci

PubMed Central

2012-01-01

Background Murine experimental autoimmune encephalomyelitis (EAE), a model for multiple sclerosis, presents typically as ascending paralysis. However, in mice in which interferon-gamma (IFNγ) signaling is disrupted by genetic deletion, limb paralysis is accompanied by atypical deficits, including head tilt, postural imbalance, and circling, consistent with cerebellar/vestibular dysfunction. This was previously attributed to intense cerebellar and brainstem infiltration by peripheral immune cells and formation of neutrophil-rich foci within the CNS. However, the exact mechanism by which IFNγ signaling prohibits the development of vestibular deficits, and whether the distribution and composition of inflammatory foci within the CNS affects the course of atypical EAE remains elusive. Methods We induced EAE in IFNγ-/- mice and bone marrow chimeric mice in which IFNγR is not expressed in the CNS but is intact in the periphery (IFNγRCNSKO) and vice versa (IFNγRperiKO). Blood-brain barrier permeability was determined by Evans blue intravenous administration at disease onset. Populations of immune cell subsets in the periphery and the CNS were quantified by flow cytometry. CNS tissues isolated at various time points after EAE induction, were analyzed by immunohistochemistry for composition of inflammatory foci and patterns of axonal degeneration. Results Incidence and severity of atypical EAE were more pronounced in IFNγRCNSKO as compared to IFNγRperiKO mice. Contrary to what we anticipated, cerebella/brainstems of IFNγRCNSKO mice were only minimally infiltrated, while the same areas of IFNγRperiKO mice were extensively populated by peripheral immune cells. Furthermore, the CNS of IFNγRperiKO mice was characterized by persistent neutrophil-rich foci as compared to IFNγRCNSKO. Immunohistochemical analysis of the CNS of IFNγ-/- and IFNγR chimeric mice revealed that IFNγ protective actions are exerted through microglial STAT1. Conclusions Alterations in distribution and composition of CNS inflammatory foci are not sufficient for the onset of atypical EAE. IFNγ dictates the course of neuroinflammatory disorders mainly through actions exerted within the CNS. This study provides strong evidence that link microglial STAT1 inactivation to vestibular dysfunction. PMID:22248039

Geochemical evidence for mélange melting in global arcs

PubMed Central

Nielsen, Sune G.; Marschall, Horst R.

2017-01-01

In subduction zones, sediments and hydrothermally altered oceanic crust, which together form part of the subducting slab, contribute to the chemical composition of lavas erupted at the surface to form volcanic arcs. Transport of this material from the slab to the overlying mantle wedge is thought to involve discreet melts and fluids that are released from various portions of the slab. We use a meta-analysis of geochemical data from eight globally representative arcs to show that melts and fluids from individual slab components cannot be responsible for the formation of arc lavas. Instead, the data are compatible with models that first invoke physical mixing of slab components and the mantle wedge, widely referred to as high-pressure mélange, before arc magmas are generated. PMID:28435882

Thomson scattering diagnostics of steady state and pulsed welding processes without and with metal vapor

NASA Astrophysics Data System (ADS)

Kühn-Kauffeldt, M.; Marqués, J.-L.; Schein, J.

2015-01-01

Thomson scattering is applied to measure temperature and density of electrons in the arc plasma of the direct current gas tungsten arc welding (GTAW) process and pulsed gas metal arc welding (GMAW) process. This diagnostic technique allows to determine these plasma parameters independent from the gas composition and heavy particles temperature. The experimental setup is adapted to perform measurements on stationary as well as transient processes. Spatial and temporal electron temperature and density profiles of a pure argon arc in the case of the GTAW process and argon arc with the presence of aluminum metal vapor in the case of the GMAW process were obtained. Additionally the data is used to estimate the concentration of the metal vapor in the GMAW plasma.

Geochemical evidence for mélange melting in global arcs.

PubMed

Nielsen, Sune G; Marschall, Horst R

2017-04-01

In subduction zones, sediments and hydrothermally altered oceanic crust, which together form part of the subducting slab, contribute to the chemical composition of lavas erupted at the surface to form volcanic arcs. Transport of this material from the slab to the overlying mantle wedge is thought to involve discreet melts and fluids that are released from various portions of the slab. We use a meta-analysis of geochemical data from eight globally representative arcs to show that melts and fluids from individual slab components cannot be responsible for the formation of arc lavas. Instead, the data are compatible with models that first invoke physical mixing of slab components and the mantle wedge, widely referred to as high-pressure mélange, before arc magmas are generated.

Influence of DC arc current on the formation of cobalt-based nanostructures

NASA Astrophysics Data System (ADS)

Orpe, P. B.; Balasubramanian, C.; Mukherjee, S.

2017-08-01

The synthesis of cobalt-based magnetic nanostructures using DC arc discharge technique with varying arc current is reported here. The structural, morphological, compositional and magnetic properties of these nanostructures were studied as a function of applied arc current. Various techniques like X-ray diffraction, transmission electron microscopy, EDAX and vibrating sample magnetometry were used to carry out this study and the results are reported here. The results clearly indicate that for a given oxygen partial pressure, an arc current of 100 A favours the formation of unreacted cobalt atomic species. Also change in arc current leads to variation in phase, diversity in morphology etc. Other property changes such as thermal changes, mechanical changes etc. are not addressed here. The magnetic characterization further indicates that the anisotropy in shape plays a crucial role in deciding the magnetic properties of the nanostructured materials. We have quantified an interesting result in our experiment, that is, for a given partial pressure, 100 A arc current results in unique variation in structural and magnetic properties as compared to other arc currents.

Solidification observations and sliding wear behavior of vacuum arc melting processed Ni-Al-TiC composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karantzalis, A.E., E-mail: akarantz@cc.uoi.gr; Lekatou, A.; Tsirka, K.

2012-07-15

Monolithic Ni{sub 3}Al and Ni-25 at.%Al intermetallic matrix TiC-reinforced composites were successfully produced by vacuum arc melting. TiC crystals were formed through a dissolution-reprecipitation mechanism and their final morphology is explained by means of a) Jackson's classical nucleation and growth phenomena and b) solidification rate considerations. The TiC presence altered the matrix microconstituents most likely due to specific melt-particle interactions and crystal plane epitaxial matching. TiC particles caused a significant decrease on the specific wear rate of the monolithic Ni{sub 3}Al alloy and the possible wear mechanisms are approached by means of a) surface oxidation, b) crack/flaws formation, c) materialmore » detachment and d) debris-counter surfaces interactions. - Highlights: Black-Right-Pointing-Pointer Vacuum arc melting (VAM) of Ni-Al based intermetallic matrix composite materials. Black-Right-Pointing-Pointer Solidification phenomena examination. Black-Right-Pointing-Pointer TiC crystal formation and growth mechanisms. Black-Right-Pointing-Pointer Sliding wear examination.« less

High-Purity Composite Briquette for Direct UMG-Si Production in Arc Furnaces

NASA Astrophysics Data System (ADS)

Perruchoud, Raymond; Fischer, Jean-Claude

2013-12-01

In metallurgical grade Si (MG-Si), the coal (B) and charcoal (P) contents are on average above 30 ppm as the carbon reduction materials used in the arc furnace are either rich in B or in P. A decrease of both impurities by a factor of 3 using purer raw materials would allow for the direct production of the upgraded metallurgical grade (UMG).This would significantly improve the efficiency of the resulting photovoltaic (PV) cells made with the refined solar grade silicon (SoG-Si) or massively decrease the costs of Si purification by shortening the number of steps needed for reaching B and P contents below 1 ppm requested for the SoG-Si used for the PV cells. A composite C/SiO2 briquette fulfilling the purity targets for the direct production of UMG-Si in the arc furnace was developed. The composite contains several carbon materials with different levels of reactivities and quartz sand. The raw materials aspects, the paste and briquette preparation, as well as the final carbonization step are discussed. The finished briquettes are free of volatiles and are mechanically and thermally very stable, thus, ensuring stable arc furnace charges with minimum losses of dust and SiO gas. Semi-industrial trials including the downstream purification steps for the production of SoG-Si by a metallurgical low-cost route are contemplated.

Regional and temporal variability of melts during a Cordilleran magma pulse: Age and chemical evolution of the jurassic arc, eastern mojave desert, California

USGS Publications Warehouse

Barth, A.P.; Wooden, J.L.; Miller, David; Howard, Keith A.; Fox, Lydia; Schermer, Elizabeth R.; Jacobson, C.E.

2017-01-01

Intrusive rock sequences in the central and eastern Mojave Desert segment of the Jurassic Cordilleran arc of the western United States record regional and temporal variations in magmas generated during the second prominent pulse of Mesozoic continental arc magmatism. U/Pb zircon ages provide temporal control for describing variations in rock and zircon geochemistry that reflect differences in magma source components. These source signatures are discernible through mixing and fractionation processes associated with magma ascent and emplacement. The oldest well-dated Jurassic rocks defining initiation of the Jurassic pulse are a 183 Ma monzodiorite and a 181 Ma ignimbrite. Early to Middle Jurassic intrusive rocks comprising the main stage of magmatism include two high-K calc-alkalic groups: to the north, the deformed 183–172 Ma Fort Irwin sequence and contemporaneous rocks in the Granite and Clipper Mountains, and to the south, the 167–164 Ma Bullion sequence. A Late Jurassic suite of shoshonitic, alkali-calcic intrusive rocks, the Bristol Mountains sequence, ranges in age from 164 to 161 Ma and was emplaced as the pulse began to wane. Whole-rock and zircon trace-element geochemistry defines a compositionally coherent Jurassic arc with regional and secular variations in melt compositions. The arc evolved through the magma pulse by progressively greater input of old cratonic crust and lithospheric mantle into the arc magma system, synchronous with progressive regional crustal thickening.

Composite Sunrise Butte pluton: Insights into Jurassic–Cretaceous collisional tectonics and magmatism in the Blue Mountains Province, northeastern Oregon

USGS Publications Warehouse

Johnson, Kenneth H.; Schwartz, J.J.; Žák, Jiří; Verner, Krystof; Barnes, Calvin G.; Walton, Clay; Wooden, Joseph L.; Wright, James E.; Kistler, Ronald W.

2015-01-01

The composite Sunrise Butte pluton, in the central part of the Blue Mountains Province, northeastern Oregon, preserves a record of subduction-related magmatism, arc-arc collision, crustal thickening, and deep-crustal anatexis. The earliest phase of the pluton (Desolation Creek unit) was generated in a subduction zone environment, as the oceanic lithosphere between the Wallowa and Olds Ferry island arcs was consumed. Zircons from this unit yielded a 206Pb/238U age of 160.2 ± 2.1 Ma. A magmatic lull ensued during arc-arc collision, after which partial melting at the base of the thickened Wallowa arc crust produced siliceous magma that was emplaced into metasedimentary rocks and serpentinite of the overthrust forearc complex. This magma crystallized to form the bulk of the Sunrise Butte composite pluton (the Sunrise Butte unit; 145.8 ± 2.2 Ma). The heat necessary for crustal anatexis was supplied by coeval mantle-derived magma (the Onion Gulch unit; 147.9 ± 1.8 Ma).The lull in magmatic activity between 160 and 148 Ma encompasses the timing of arc-arc collision (159–154 Ma), and it is similar to those lulls observed in adjacent areas of the Blue Mountains Province related to the same shortening event. Previous researchers have proposed a tectonic link between the Blue Mountains Province and the Klamath Mountains and northern Sierra Nevada Provinces farther to the south; however, timing of Late Jurassic deformation in the Blue Mountains Province predates the timing of the so-called Nevadan orogeny in the Klamath Mountains. In both the Blue Mountains Province and Klamath Mountains, the onset of deep-crustal partial melting initiated at ca. 148 Ma, suggesting a possible geodynamic link. One possibility is that the Late Jurassic shortening event recorded in the Blue Mountains Province may be a northerly extension of the Nevadan orogeny. Differences in the timing of these events in the Blue Mountains Province and the Klamath–Sierra Nevada Provinces suggest that shortening and deformation were diachronous, progressing from north to south. We envision that Late Jurassic deformation may have collapsed a Gulf of California–style oceanic extensional basin that extended from the Klamath Mountains (e.g., Josephine ophiolite) to the central Blue Mountains Province, and possibly as far north as the North Cascades (i.e., the coeval Ingalls ophiolite).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yogodzinski, Gene; Vervoort, Jeffery; Brown, Shaun Tyler

The Hf and Nd isotopic compositions of 71 Quaternary lavas collected from locations along the full length of the Aleutian island arc are used to constrain the sources of Aleutian magmas and to provide insight into the geochemical behavior of Nd and Hf and related elements in the Aleutian subduction-magmatic system. Isotopic compositions of Aleutian lavas fall approximately at the center of, and form a trend parallel to, the terrestrial Hf-Nd isotopic array with {var_epsilon}{sub Hf} of +12.0 to +15.5 and {var_epsilon}{sub Nd} of +6.5 to +10.5. Basalts, andesites, and dacites within volcanic centers or in nearby volcanoes generally allmore » have similar isotopic compositions, indicating that there is little measurable effect of crustal or other lithospheric assimilation within the volcanic plumbing systems of Aleutian volcanoes. Hafnium isotopic compositions have a clear pattern of along-arc increase that is continuous from the eastern-most locations near Cold Bay to Piip Seamount in the western-most part of the arc. This pattern is interpreted to reflect a westward decrease in the subducted sediment component present in Aleutian lavas, reflecting progressively lower rates of subduction westward as well as decreasing availability of trench sediment. Binary bulk mixing models (sediment + peridotite) demonstrate that 1-2% of the Hf in Aleutian lavas is derived from subducted sediment, indicating that Hf is mobilized out of the subducted sediment with an efficiency that is similar to that of Sr, Pb and Nd. Low published solubility for Hf and Nd in aqueous subduction fluids lead us to conclude that these elements are mobilized out of the subducted component and transferred to the mantle wedge as bulk sediment or as a silicate melt. Neodymium isotopes also generally increase from east to west, but the pattern is absent in the eastern third of the arc, where the sediment flux is high and increases from east to west, due to the presence of abundant terrigenous sediment in the trench east of the Amlia Fracture Zone, which is being subducting beneath the arc at Seguam Island. Mixing trends between mantle wedge and sediment end members become flatter in Hf-Nd isotope space at locations further west along the arc, indicating that the sediment end member in the west has either higher Nd/Hf or is more radiogenic in Hf compared to Nd. This pattern is interpreted to reflect an increase in pelagic clay relative to the terrigenous subducted sedimentary component westward along the arc. Results of this study imply that Hf does not behave as a conservative element in the Aleutian subduction system, as has been proposed for some other arcs.« less

Cycling of sulfur in subduction zones: The geochemistry of sulfur in the Mariana Island Arc and back-arc trough

NASA Astrophysics Data System (ADS)

Alt, Jeffrey C.; Shanks, Wayne C., III; Jackson, Michael C.

1993-10-01

The sulfur contents and sulfur isotopic compositions of 24 glassy submarine volcanics from the Mariana Island Arc and back-arc Mariana Trough were determined in order to investigate the hypothesis that subducted seawater sulfur (delta S-34 = 21 parts per thousand) is recycled through arc volcanism. Our results for sulfur are similar to those for subaerial arc volcanics: Mariana Arc glasses are enriched in S-34(delta S-34 = up to 10.3 parts per thousand, mean = 3.8 parts per thousand) and depleted in S(20-290 ppm, mean = 100 ppm) relative to mid ocean ridge basalt (MORB)(850 ppm S, delta S-34 = 0.1 +/- 0.5 parts per thousand). The bac-arc trough basalts contain 200-930 ppm S and have delta S-34 values of 1.1 +/- 0.5 parts per thousand, which overlap those for the arc and MORB. The low sulfur contents of the arc and some of the trough glasses are attributed to (1) early loss of small amounts of sulfur through separation of immiscible sulfide and (2) later vapor-melt equilibrium control of sulfur contents and loss of sulfur in a vapor phase from sulfide-undersaturated melts near the minimum in sulfur solubility at fO2 is approximately equal to NNO (nickel-nickel oxide). Although these processes removed sulfur from the melts their effects on the sulfur isotopic compositions of the melts were minimal. Positive trends of delta S-34 with Sr-87/Sr-86 large ion lithophile element (LILE) and Light rare earth elements (LREE) contents of the arc volcanics are consistent with a metasomatic seawater sulfur component in the depleted sub-arc mantle source. The lack of a S-34-rich slab signature in the trough lavas may be attributed to equilibration of metasomatic fluid with mantle material along the longer pathway from the slab to the source of the trough volcanics. Sulfur is likely to have been transported into the mantle wedge by metasomatic fluid derived from subducted sediments and pore fluids. Gases extracted from vesicles in arc and back-arc samples are predominantly H2O, with minor CO2 and traces of H2S and SO2.CO2 in the arc and back-arc rocks has delta C-13 values of -2.1 to 13.1 parts per thousand, similar to MORB. These data suggest that degassing of CO2 could explain the slightly lower delta C-13 values for some Mariana Trough volcanic glasses, and that incorporation of subduction-derived organic carbon into the Mariana trough mantle source may not be necessary. More analyses are required to resolve this question, however.

Voluminous arc dacites as amphibole reaction-boundary liquids

NASA Astrophysics Data System (ADS)

Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben

2017-05-01

Dacites dominate the large-volume, explosive eruptions in magmatic arcs, and compositionally similar granodiorites and tonalites constitute the bulk of convergent margin batholiths. Shallow, pre-eruptive storage conditions are well known for many dacitic arc magmas through melt inclusions, Fe-Ti oxides, and experiments, but their potential origins deeper in the crust are not well determined. Accordingly, we report experimental results identifying the P-T-H2O conditions under which hydrous dacitic liquid may segregate from hornblende (hbl)-gabbroic sources either during crystallization-differentiation or partial melting. Two compositions were investigated: (1) MSH-Yn-1 dacite (SiO2: 65 wt%) from Mount St. Helens' voluminous Yn tephra and (2) MSH-Yn-1 + 10% cpx to force saturation with cpx and map a portion of the cpx + melt = hbl peritectic reaction boundary. H2O-undersaturated (3, 6, and 9 wt% H2O) piston cylinder experiments were conducted at pressures, temperatures, and fO2 appropriate for the middle to lower arc crust (400, 700, and 900 MPa, 825-1100 °C, and the Re-ReO2 buffer ≈ Ni-NiO + 2). Results for MSH-Yn-1 indicate near-liquidus equilibrium with a cpx-free hbl-gabbro residue (hbl, plg, magnetite, ± opx, and ilmeno-hematite) with 6-7 wt% dissolved H2O, 925 °C, and 700-900 MPa. Opx disappears down-temperature consistent with the reaction opx + melt = hbl. Cpx-added phase relations are similar in that once 10% cpx crystallizes, multiple saturation is attained with cpx, hbl, and plg, +/- opx, at 6-7 wt% dissolved H2O, 940 °C, and 700-900 MPa. Plg-hbl-cpx saturated liquids diverge from plg-hbl-opx saturated liquids, consistent with the MSH-Yn-1 dacite marking a liquid composition along a peritectic distributary reaction boundary where hbl appears down-temperature as opx + cpx are consumed. The abundance of saturating phases along this distributary peritectic (liquid + hbl + opx + cpx + plg + oxides) reduces the variance, so liquids are restricted to dacite-granodiorite-tonalite compositions. Higher-K dacites than the Yn would also saturate with biotite, further limiting their compositional diversity. Theoretical evaluation of the energetics of peritectic melting of pargasitic amphiboles indicates that melting and crystallization of amphibole occur abruptly, proximal to amphibole's high-temperature stability limit, which causes the system to dwell thermally under the conditions that produce dacitic compositions. This process may account for the compositional homogeneity of dacites, granodiorites, and tonalites in arc settings, but their relative mobility compared to rhyolitic/granitic liquids likely accounts for their greater abundance.

Sulphide-sulphate stability and melting in subducted sediment and its role in arc mantle redox and chalcophile cycling in space and time

NASA Astrophysics Data System (ADS)

Canil, Dante; Fellows, Steven A.

2017-07-01

The redox budget during subduction is tied to the evolution of oxygen and biogeochemical cycles on Earth's surface over time. The sulphide-sulphate couple in subducted crust has significant potential for redox and control on extraction of chalcophile metals from the arc mantle. We derive oxygen buffers for sulphide-sulphate stability ('SSO buffers') using mineral assemblages in subducted crust within the eclogite facies, and examine their disposition relative to the fO2 in the arc mantle along various P-T trajectories for subduction. The fO2 required for sulphide stability in subducted crust passing beneath an arc is shifted by variations in the bulk Ca/(Ca + Mg + Fe) of the subducting crust alone. Hotter slabs and more Fe-rich sediments stabilize sulphide and favour chalcophile sequestration deep into the mantle, whereas colder slabs and calcic sediment will stabilize anhydrite, in some cases at depths of melt generation in the arc mantle (<130 km). The released sulphate on melting potentially increases the fO2 of the arc mantle. We performed melting experiments on three subducted sediment compositions varying in bulk Ca/(Ca + Mg + Fe) from 0.3 to 0.6 at 2.5 GPa and 900-1100 °C to confirm how anhydrite stability can change by orders of magnitude the S, Cu, As, Zn, Mo, Pb, and Sb contents of sediment melts, and their subsequent liberation to the arc mantle. Using Cu/Sc as a proxy for the behaviour of S, the effect of variable subducted sediment composition on sulphide-sulphate stability and release of chalcophiles to the arc mantle is recognizable in volcanic suites from several subduction zones in space and time. The fO2 of the SSO buffers in subducted sediment relative to the arc mantle may have changed with time by shifts in the nature of pelagic sedimentation in the oceans over earth history. Oxidation of arc mantle and the proliferation of porphyry Cu deposits may be latter-day advents in earth history partly due to the rise of planktic calcifiers in the oceans in only the past 250 million years.

Magmatic Complexes of the Vetlovaya Marginal Sea Paleobasin (Kamchatka): Composition and Geodynamic Setting

NASA Astrophysics Data System (ADS)

Tsukanov, N. V.; Saveliev, D. P.; Kovalenko, D. V.

2018-01-01

This study presents new geochemical and isotope data on igneous rocks of the Vetlovaya marginal sea paleobasin (part of the Late Mesozoic-Cenozoic margin of the northwestern Pacific). The results show that the rock complexes of this marginal sea basin comprise igneous rocks with geochemical compositions similar to those of normal oceanic tholeiites, enriched transitional tholeiites, and ocean island and back-arc basin basalts. Island-arc tholeiitic basalts are present only rarely. The specific geochemical signatures of these rocks are interpreted as being related to mantle heterogeneity and the geodynamic conditions in the basin.

DC Electric Arc Furnace Application for Production of Nickel-Boron Master Alloys

NASA Astrophysics Data System (ADS)

Alkan, Murat; Tasyürek, Kerem Can; Bugdayci, Mehmet; Turan, Ahmet; Yücel, Onuralp

2017-09-01

In this study, nickel-boron (Ni-B) alloys were produced via a carbothermic reduction starting from boric acid (H3BO3) with high-purity nickel oxide (NiO), charcoal, and wood chips in a direct current arc furnace. In electric arc furnace experiments, different starting mixtures were used, and their effects on the chemical compositions of the final Ni-B alloys were investigated. After the reduction and melting stages, Ni-B alloys were obtained by tapping from the bottom of the furnace. The samples from the designated areas were also taken and analyzed. The chemical composition of the final alloys and selected samples were measured with wet chemical analysis. The Ni-B alloys had a composition of up to 14.82 mass% B. The phase contents of the final alloys and selected samples were measured using x-ray diffraction (XRD). The XRD data helped predict possible reactions and reaction mechanisms. The material and energy balance calculations were made via the XRD Rietveld and chemical compositions. Nickel boride phases started to form 600 mm below the surface. The targeted NiB phase was detected at the tapping zone of the crucible (850-900 mm depth). The energy consumption was 1.84-4.29 kWh/kg, and the electrode consumption was 10-12 g/kg of raw material charged.

Lithium isotopic systematics of submarine vent fluids from arc and back-arc hydrothermal systems in the western Pacific

NASA Astrophysics Data System (ADS)

Araoka, Daisuke; Nishio, Yoshiro; Gamo, Toshitaka; Yamaoka, Kyoko; Kawahata, Hodaka

2016-10-01

The Li concentration and isotopic composition (δ7Li) in submarine vent fluids are important for oceanic Li budget and potentially useful for investigating hydrothermal systems deep under the seafloor because hydrothermal vent fluids are highly enriched in Li relative to seawater. Although Li isotopic geochemistry has been studied at mid-ocean-ridge (MOR) hydrothermal sites, in arc and back-arc settings Li isotopic composition has not been systematically investigated. Here we determined the δ7Li and 87Sr/86Sr values of 11 end-member fluids from 5 arc and back-arc hydrothermal systems in the western Pacific and examined Li behavior during high-temperature water-rock interactions in different geological settings. In sediment-starved hydrothermal systems (Manus Basin, Izu-Bonin Arc, Mariana Trough, and North Fiji Basin), the Li concentrations (0.23-1.30 mmol/kg) and δ7Li values (+4.3‰ to +7.2‰) of the end-member fluids are explained mainly by dissolution-precipitation model during high-temperature seawater-rock interactions at steady state. Low Li concentrations are attributable to temperature-related apportioning of Li in rock into the fluid phase and phase separation process. Small variation in Li among MOR sites is probably caused by low-temperature alteration process by diffusive hydrothermal fluids under the seafloor. In contrast, the highest Li concentrations (3.40-5.98 mmol/kg) and lowest δ7Li values (+1.6‰ to +2.4‰) of end-member fluids from the Okinawa Trough demonstrate that the Li is predominantly derived from marine sediments. The variation of Li in sediment-hosted sites can be explained by the differences in degree of hydrothermal fluid-sediment interactions associated with the thickness of the marine sediment overlying these hydrothermal sites.

Mass-spectroscopic study of the influence of nozzle material on high-pressure SF6 arcs

NASA Astrophysics Data System (ADS)

Meier, R.; Kneubühl, F. K.; Schötzau, H. J.

1989-03-01

The interrupting capability of a gas-blast high-voltage circuit breaker (CB) is mainly determined by the self-induced pressure rise caused by the thermal arc energy, the composition of the arc plasma and the chemical reactions occuring during and after current interruption. We have studied the nozzle materials boron nitride (BN), quartz (SiO2), polytetrafluoroethylene (PTFE), ethylene-tetrafluoroethylene (ETFE), polyethylene (PE) and epoxy resin (ER) with respect to their influence on these processes with the aid of a model circuit breaker (MCB). Direct measurements of the arc-induced pressure rise reveal that the portion of the arc energy available for the pressure rise varies greatly (˜20% 65%) with the properties of the nozzle material. Nozzle erosion is significantly higher for materials with high values (e.g. polymers). Therefore, the lifetime of polymer nozzles is considerably shorter than that of ceramic nozzles. We have investigated the influence of the nozzle material on the decomposition products formed in the arc discharge of our MCB by studying the composition and time dependence of these products. The MCB was directly attached to the time-of-flight mass spectrometer (TOFMS) with the aid of a molecular-beam sampling system, which allowed real-time measurements of the arced gas during and after current interruption, thus providing information on the ablation mechanism and on the reaction kinetics of vaporised nozzle material with dissociated SF6. The most abundant long-lived reaction products are SF4, SOF2, C2H2, CO, and CS2. Their formation rates have been determined as functions of the nozzle material. With respect to quantities and properties of decomposition products, ceramics are superior to polymers since they form only small concentrations of corrosive and toxic products.

Microstructure of arc brazed and diffusion bonded joints of stainless steel and SiC reinforced aluminum matrix composite

NASA Astrophysics Data System (ADS)

Elßner, M.; Weis, S.; Grund, T.; Wagner, G.; Habisch, S.; Mayr, P.

2016-03-01

Joint interfaces of aluminum and stainless steel often exhibit intermetallics of Al-Fe, which limit the joint strength. In order to reduce these brittle phases in joints of aluminum matrix composites (AMC) and stainless steel, diffusion bonding and arc brazing are used. Due to the absence of a liquid phase, diffusion welding can reduce the formation of these critical in- termetallics. For this joining technique, the influence of surface treatments and adjusted time- temperature-surface-pressure-regimes is investigated. On the other hand, arc brazing offers the advantage to combine a localized heat input with the application of a low melting filler and was conducted using the system Al-Ag-Cu. Results of the joining tests using both approaches are described and discussed with regard to the microstructure of the joints and the interfaces.

Investigations into the damage for various types of unprotected carbon fibre composites with a variety of lightning arc attachments

NASA Technical Reports Server (NTRS)

Reid, G. W.

1991-01-01

Very little quantitative information exists on the extent and nature of damage caused to unprotected carbon fiber composites (CFC's) due to lightning arc attachment. An initial investigation into the arc damage to three different types and various thickness of CFC's from A and C component type lightning discharges is described. The difference in damage which the two types of waveform produced and the way the area of damage varies with different levels of action integral and charge transfer is compared. In some cases, the temperature rise at the rear of the panels was recorded for various levels of action integral and charge transfer. A comparison was made of the area of damage from visual inspection and soft x ray photography, using a suitable penetrant in the damage area. It is concluded there is a need for a more detailed analysis of the damage.

Friction surfaced Stellite6 coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid, E-mail: khalidrafi@gmail.com

2012-08-15

Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material formore » friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.« less

ARC-1989-A89-7042

NASA Image and Video Library

1989-08-11

P-34578 BW One of two new ring arcs, or partial rings, discovered by Voyager 2, is faintly visible just outside the orbit of the Neptunian moon 1989N4.The 155-second exposure taken by the spacecraft's narrow-angle camera shows the glare of an overexposed Neptune to the right of the moon and ring arc. The two bright streaks below the moon and ring arc are stars. The ring arc is approximately 50,000 kilometers (30,000 miles) long. The second ring arc, not apparent here, is about 10,000 kilometers (6,000 miles) long and is assoiciated with moon 1989N3. The ring arc, along with 1989N4, orbits about 62,000 kilometers (38,000 miles) from the planet's cloud tops. Astronomers long suspected the existence of such an irregular ring system around Neptune. Data from repeated ground-based observations hinted at the existence of irregular strands of partial rings orbiting Neptune. Voyager's photographs of the ring arcs are the first photographic evidence that such a ring system exists. Voyager scientists said the ring arcs may be comprised of debris associated with the nearby moons, or may be the remnants of moons that have been torn apart or ground down through collisions. Close-up studies of the ring arcs by Voyager 2 will help determine their composition.

Serpentinites and Boron Isotope Evidence for Shallow Fluid Transfer Across Subduction Zones

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Tonarini, S.

2012-04-01

In subduction zones, fluid-mediated chemical exchanges between subducting plates and overlying mantle dictate volatile and incompatible element cycles in earth and influence arc magmatism. One of the outstanding issues is concerned with the sources of water for arc magmas and mechanisms for its slab-to-mantle wedge transport. Does it occur by slab dehydration at depths directly beneath arc front, or by hydration of fore-arc mantle and subsequent subduction of the hydrated mantle? Historically, the deep slab dehydration hypothesis had strong support, but it appears that the hydrated mantle wedge hypothesis is gaining ground. At the center of this hypothesis are studies of fluid-mobile element tracers in volatile-rich mantle wedge peridotites (serpentinites) and their subducted high-pressure equivalents. Serpentinites are key players in volatile and fluid-mobile element cycles in subduction zones. Their dehydration represents the main event for fluid and element flux from slabs to mantle, though direct evidence for this process and identification of dehydration environments have been elusive. Boron isotopes are known markers of fluid-assisted element transfer during subduction and can be the tracers of these processes. Until recently, the altered oceanic crust has been considered the main 11B reservoir for arc magmas, which largely display positive delta11B. However, slab dehydration below fore-arcs transfers 11B to the overlying hydrated mantle and leaves the residual mafic crust very depleted in 11B below sub-arcs. The 11B-rich composition of serpentinites candidate them as the heavy B carriers for subduction. Here we present high positive delta11B of Alpine high-pressure (HP) serpentinites recording subduction metamorphism from hydration at low gades to eclogite-facies dehydration: we show a connection among serpentinite dehydration, release of 11B-rich fluids and arc magmatism. In general, the delta11B of these rocks is heavy (16‰ to + 24‰ delta11B). No B loss and no 11B fractionation occurs in these rocks with progressive burial: their high B and 11B compositions demonstrate that initially high budgets acquired during shallow hydration are transferred and released to fluids at arc magma depths, providing the high-boron component requested for arcs. Interaction of depleted mantle-wedge with de-serpentinization fluids and/or serpentinite diapirs uprising from the slab-mantle interface thus provide an efficient self-consistent mechanism for water and B transfer to many arcs. The boron compositions documented here for Erro-Tobbio serpentinites are unexpected for slabs, deputed to loose much B and 11B during subduction dehydration. Their isotopic compositions can be achieved diluting through the mantle the subduction-fluids released during shallow dehydration (30 km) of a model slab. Moreover their delta11B is close to values measured in Syros eclogite blocks, hosted in mélanges atop of the slab and metasomatized by uprising subduction-fluids. The nature of serpentinizing fluids and the fluid-transfer mechanism in Erro-Tobbio is further clarified integrating B isotopes with O-H and Sr isotopic systems. Low deltaD (-102‰), high delta18O (8‰) of early serpentinites suggest low-temperature hydration by metamorphic fluids. 87Sr/86Sr ranges from 0.7044 to 0.7065 and is lower than oceanic serpentinites formed from seawater. Our data indicate that alteration occurred distant from mid-ocean ridges: we propose metamorphic environments like the slab-mantle interface or the fore-arc mantle fed by B- and 11B-rich slab fluids. We therefore provide field-based evidence for delivery of water and 11B at sub-arcs by serpentinites formed by subduction-fluid infiltration in mantle rocks atop of the slab since the early stages of burial, witnessing shallow fluid transfer across the subduction zone.

Effect of weathering variables on the lightness of high-density polyethylene woodflour composites

Treesearch

Nicole M. Stark

2005-01-01

Wood-plastic lumber is promoted as a low-maintenance, high-durability product. After weathering, however, wood-plastic composites (WPCs) often fade. In the first part of this study, 50 percent woodflour-filled high- density polyethylene (HDPE) composite samples were manufactured. Composites were exposed to two accelerated weathering cycles in a xenon- arc type...

Process for HIP canning of composites

NASA Technical Reports Server (NTRS)

Juhas, John J. (Inventor)

1990-01-01

A single step is relied on in the canning process for hot isostatic pressing (HIP) metallurgy composites. The composites are made from arc sprayed and plasma sprayed monotape. The HIP can is of compatible refractory metal and is sealed at high vacuum and temperature. This eliminates outgassing during hot isostatic pressing.

Detecting stellar-wind bubbles through infrared arcs in H II regions

NASA Astrophysics Data System (ADS)

Mackey, Jonathan; Haworth, Thomas J.; Gvaramadze, Vasilii V.; Mohamed, Shazrene; Langer, Norbert; Harries, Tim J.

2016-02-01

Mid-infrared arcs of dust emission are often seen near ionizing stars within H II regions. A possible explanations for these arcs is that they could show the outer edges of asymmetric stellar wind bubbles. We use two-dimensional, radiation-hydrodynamics simulations of wind bubbles within H II regions around individual stars to predict the infrared emission properties of the dust within the H II region. We assume that dust and gas are dynamically well-coupled and that dust properties (composition, size distribution) are the same in the H II region as outside it, and that the wind bubble contains no dust. We post-process the simulations to make synthetic intensity maps at infrared wavebands using the torus code. We find that the outer edge of a wind bubble emits brightly at 24 μm through starlight absorbed by dust grains and re-radiated thermally in the infrared. This produces a bright arc of emission for slowly moving stars that have asymmetric wind bubbles, even for cases where there is no bow shock or any corresponding feature in tracers of gas emission. The 24 μm intensity decreases exponentially from the arc with increasing distance from the star because the dust temperature decreases with distance. The size distribution and composition of the dust grains has quantitative but not qualitative effects on our results. Despite the simplifications of our model, we find good qualitative agreement with observations of the H II region RCW 120, and can provide physical explanations for any quantitative differences. Our model produces an infrared arc with the same shape and size as the arc around CD -38°11636 in RCW 120, and with comparable brightness. This suggests that infrared arcs around O stars in H II regions may be revealing the extent of stellar wind bubbles, although we have not excluded other explanations.

Early Cretaceous ( 140 Ma) aluminous A-type granites in the Tethyan Himalaya, Tibet: Products of crust-mantle interaction during lithospheric extension

NASA Astrophysics Data System (ADS)

Ma, Lin; Kerr, Andrew C.; Wang, Qiang; Jiang, Zi-Qi; Hu, Wan-Long

2018-02-01

A-type granites have been the focus of considerable research due to their distinctive major- and trace-element signatures and tectonic significance. However, their petrogenesis, magmatic source and tectonic setting remain controversial, particularly for aluminous A-type granites. The earliest Cretaceous (ca. 140 Ma) Comei granite in the eastern Tethyan Himalaya is associated with coeval oceanic island basalt (OIB)-type mafic lava, and has A-type granite geochemical characteristics including high 10,000 × Ga/Al (up to 6), FeOtotal/MgO (4.6-6.1) and (Na2O + K2O)/Al2O3 (0.50-0.61) ratios but low CaO (0.6-1.6 wt%) and Na2O (1.8-2.6 wt%) contents. The Comei granite also has variable peraluminous compositions (A/CNK = 1.00-1.36) along with zircon δ18O, εNd(t) and initial 87Sr/86Sr values of 8.2‰ to 9.3‰, - 13.0 to - 12.4 and 0.7238 to 0.7295, respectively. This range of compositions can be interpreted as the interaction between high-temperature upwelling OIB type basaltic magmas and a shallow crustal (< 5 kbar) metapelitic source. The Comei granite and coeval OIB type basaltic rock could represent the earliest stage (145-140 Ma) of a large igneous event in eastern Tethyan Himalaya, which may well have been triggered by pre-breakup lithospheric extension prior to the arrival of the Kerguelen plume head.

Improved microstructure and mechanical properties in gas tungsten arc welded aluminum joints by using graphene nanosheets/aluminum composite filler wires.

PubMed

Fattahi, M; Gholami, A R; Eynalvandpour, A; Ahmadi, E; Fattahi, Y; Akhavan, S

2014-09-01

In the present study, different amounts of graphene nanosheets (GNSs) were added to the 4043 aluminum alloy powders by using the mechanical alloying method to produce the composite filler wires. With each of the produced composite filler wires, one all-weld metal coupon was welded using the gas tungsten arc (GTA) welding process. The microstructure, mechanical properties and fracture surface morphology of the weld metals have been evaluated and the results are compared. As the amount of GNSs in the composition of filler wire is increased, the microstructure of weld metal was changed from the dendritic structure to fine equiaxed grains. Furthermore, the tensile strength and microhardness of weld metal was improved, and is attributed to the augmented nucleation and retarded growth. From the results, it was seen that the GNSs/Al composite filler wire can be used to improve the microstructure and mechanical properties of GTA weld metals of aluminum and its alloys. Copyright © 2014 Elsevier Ltd. All rights reserved.

Nanodiamond embedded ta-C composite film by pulsed filtered vacuum arc deposition from a single target

NASA Astrophysics Data System (ADS)

Iyer, Ajai; Etula, Jarkko; Ge, Yanling; Liu, Xuwen; Koskinen, Jari

2016-11-01

Detonation Nanodiamonds (DNDs) are known to have sp3 core, sp2 shell, small size (few nm) and are gaining importance as multi-functional nanoparticles. Diverse methods have been used to form composites, containing detonation nanodiamonds (DNDs) embedded in conductive and dielectric matrices for various applications. Here we show a method, wherein DND-ta-C composite film, consisting of DNDs embedded in ta-C matrix have been co-deposited from the same cathode by pulsed filtered cathodic vacuum arc method. Transmission Electron Microscope analysis of these films revel the presence of DNDs embedded in the matrix of amorphous carbon. Raman spectroscopy indicates that the presence of DNDs does not adversely affect the sp3 content of DND-ta-C composite film compared to ta-C film of same thickness. Nanoindentation and nanowear tests indicate that DND-ta-C composite films possess improved mechanical properties in comparison to ta-C films of similar thickness.

Effect of Compositional Variation in TiO2-Based Flux-Cored Arc Welding Fluxes on the Thermo-physical Properties and Mechanical Behavior of a Weld Zone

NASA Astrophysics Data System (ADS)

Kim, J. B.; Lee, T. H.; Sohn, I.

2018-04-01

The effect of compositional variation in TiO2-based flux-cored arc welding fluxes on viscosity, wettability, and electronegativity was studied. The thermo-physical properties of the retrieved fluxes and their relationship with the mechanical properties of the weld zone, including tensile strength and micro-Vickers hardness, after welding were identified. Microstructural observation under similar welding conditions revealed significant grain coarsening at a corrected optical basicity (Λcorr) of 0.62, resulting in reduced strength and hardness due to greater heat transfer. Welding fluxes containing TiO2-based simple structural units should result in greater heat transfer due to the deficiency in complex [AlO4]5-- and [SiO4]4--based structural units, as identified through spectroscopic analyses using fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. The electronegativity of the retrieved fluxes was also evaluated since higher electronegativity results in greater absorption of electrons in the arc, resulting in arc condensation towards the center direction. Consequently, deeper penetration could be obtained, where the highest electronegativity was identified to be approximately 0.62 of the corrected optical basicity. Thus, both the thermal conductivity and electronegativity of the welding fluxes were identified to determine the heat transfer phenomenon during flux-cored arc welding.

Two mantle domains and the time scales of fluid transfer beneath the Vanuatu arc

NASA Astrophysics Data System (ADS)

Turner, Simon P.; Peate, David W.; Hawkesworth, Chris J.; Eggins, Stephen M.; Crawford, Anthony J.

1999-11-01

U-Th isotope disequilibria can provide constraints on the time elapsed since fluid addition to the mantle wedge beneath island arcs. The Vanuatu arc offers new insights into these processes because Pb isotopes there are not dominated by components from the subducting plate and so preserve the signatures of the mantle wedge. The Pb isotope data document the presence of separate Pacific and Indian mantle domains beneath the arc volcanoes. The Indian mantle was brought beneath the central part of the arc from the backarc by collision with the D'Entrecasteaux Ridge, resulting in a slowing of subduction there. The distinction in the mantle wedge composition is also uniquely apparent in U-Th isotope data, which define two subparallel arrays on the U-Th equiline diagram, one anchored to high U/Th Pacific mantle and the other to lower U/Th Indian mantle. These data provide clear evidence of the effects of variable mantle composition on U-Th isotope disequilibria. We argue that such arrays faithfully record the time elapsed since fluid release from the subducting plate. The data indicate that this occurred ca. 16 ka in the area of collision and slow subduction, but ca. 60 ka where the rate of subduction is substantially faster. This suggests a link between the rate of subduction and the time elapsed since fluid release.

Effect of Compositional Variation in TiO2-Based Flux-Cored Arc Welding Fluxes on the Thermo-physical Properties and Mechanical Behavior of a Weld Zone

NASA Astrophysics Data System (ADS)

Kim, J. B.; Lee, T. H.; Sohn, I.

2018-07-01

The effect of compositional variation in TiO2-based flux-cored arc welding fluxes on viscosity, wettability, and electronegativity was studied. The thermo-physical properties of the retrieved fluxes and their relationship with the mechanical properties of the weld zone, including tensile strength and micro-Vickers hardness, after welding were identified. Microstructural observation under similar welding conditions revealed significant grain coarsening at a corrected optical basicity (Λcorr) of 0.62, resulting in reduced strength and hardness due to greater heat transfer. Welding fluxes containing TiO2-based simple structural units should result in greater heat transfer due to the deficiency in complex [AlO4]5-- and [SiO4]4--based structural units, as identified through spectroscopic analyses using fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. The electronegativity of the retrieved fluxes was also evaluated since higher electronegativity results in greater absorption of electrons in the arc, resulting in arc condensation towards the center direction. Consequently, deeper penetration could be obtained, where the highest electronegativity was identified to be approximately 0.62 of the corrected optical basicity. Thus, both the thermal conductivity and electronegativity of the welding fluxes were identified to determine the heat transfer phenomenon during flux-cored arc welding.

Physicochemical modifications and applications of carbon nano-onions for electrochemical energy storage

NASA Astrophysics Data System (ADS)

Borgohain, Rituraj

Carbon nano-onions (CNOs), concentrically multilayered fullerenes, are prepared by several different methods. We are studying the properties of two specific CNOs: A-CNOs and N-CNOs. A-CNOs are synthesized by underwater arc discharge, and N-CNOs are synthesized by high-temperature graphitization of commercial nanodiamond. In this study the synthesis of A-CNOs are optimized by designing an arc discharge aparatus to control the arc plasma. Moreover other synthesis parameters such as arc power, duty cycles, temperature, graphitic and metal impurities are controlled for optimum production of A-CNOs. Also, a very efficient purification method is developed to screen out A-CNOs from carboneseous and metal impurities. In general, A-CNOs are larger than N-CNOs (ca. 30 nm vs. 7 nm diameter). The high surface area, appropriate mesoporosity, high thermal stability and high electrical conductivity of CNOs make them a promising material for various applications. These hydrophobic materials are functionalized with organic groups on their outer layers to study their surface chemistry and to decorate with metal oxide nanoparticles. Both CNOs and CNO nanocomposites are investigated for application in electrochemical capacitors (ECs). The influences of pH, concentration and additives on the performance of the composites are studied. Electrochemical measurements demonstrate high specific capacitance and high cycling stability with high energy and power density of the composite materials in aqueous electrolyte. Key words: Carbon Nano-onions, Arc discharge, Purification, Functionalization, Supercapacitor.

Polymerisation characteristics of resin composites polymerised with different curing units.

PubMed

Danesh, Gholamreza; Davids, Hendrick; Reinhardt, Klaus-Jürgen; Ott, Klaus; Schäfer, Edgar

2004-08-01

The aim of this study was to compare the plasma arc light source Apollo 95E and the conventional halogen lamp Elipar Visio regarding a number of polymerisation characteristics of different resin composites. Four different resin composites (Arabesk Top, Herculite XRV, Pertac II, Tetric) were irradiated using the Apollo 95E unit for one, two or three cycles of 3 s and using the Elipar Visio unit for 40 s. The investigated polymerisation characteristics were: flexural strength and modulus of elasticity, bond strength to dentine, depth of polymerisation, and quantity of remaining double bonds. The data were treated statistically by analysis of variance and by Scheffé test. The modulus of elasticity and the flexural strength resulting from curing with Apollo 95E for 1 x 3 s were equal to or less than those resulting from curing with Elipar Visio. The bond strength to dentine and the depth of polymerisation with Apollo 95E used for 1 x 3 s were equal to or less than that obtained with the conventional lamp, depending on the resin composite. Irradiation of Herculite XRV resulted in a higher quantity of remaining double bonds than did Elipar Visio. In general, two or three curing cycles of 3 s with Apollo 95E were necessary to produce mechanical properties not significantly worse than with 40 s of conventional curing. The efficiency of plasma arc curing with Apollo 95E strongly depends on the resin composite. For most resin composites tested, plasma arc curing for 3 s resulted in inferior mechanical properties as compared to conventional curing.

Recording the transition from flare-up to steady-state arc magmatism at the Purico-Chascon volcanic complex, northern Chile

NASA Astrophysics Data System (ADS)

Burns, Dale H.; de Silva, Shanaka L.; Tepley, Frank; Schmitt, Axel K.; Loewen, Matthew W.

2015-07-01

The long-term evolution of continental magmatic arcs is episodic, where a few transient events of high magmatic flux or flare-ups punctuate the low-flux magmatism or "steady state" that makes up most of the arc history. How this duality manifests in terms of differences in crustal architecture, magma dynamics and chemistry, and the time scale over which transitions occur is poorly known. Herein we use multiscale geochemical and isotopic characteristics coupled with geothermobarometry at the Purico-Chascon Volcanic Complex (PCVC) in the Central Andes to identify a transition from flare-up to steady state arc magmatism over ∼800 kyr during which significant changes in upper crustal magmatic dynamics are recorded. The PCVC is one of the youngest volcanic centers related to a 10-1 Ma ignimbrite flare-up in the Altiplano-Puna Volcanic Complex of the Central Andes. Activity at the PCVC initiated 0.98 ± 0.03 Ma with the eruption of a large 80-100 km3 crystal-rich dacite ignimbrite. High, restricted 87Sr/86Sr isotope ratios between 0.7085 and 0.7090 in the bulk rock and plagioclase crystals from the Purico ignimbrite, combined with mineral chemistry and phase relationships indicate the dacite magma accumulated and evolved at relatively low temperatures around 800-850 °C in the upper crust at 4-8 km depth. Minor andesite pumice erupted late in the ignimbrite sequence records a second higher temperature (965 °C), higher pressure environment (17-20 km), but with similar restricted radiogenic bulk rock 87Sr/86Sr = 0.7089-0.7091 to the dacites. The compositional and isotopic characteristics of the Purico ignimbrite implicate an extensive zone of upper crustal mixing, assimilation, storage and homogenization (MASH) between ∼30 and 4 km beneath the PCVC ∼1 Ma. The final eruptions at the PCVC < 0.18 ± 0.02 Ma suggest a change in the magmatic architecture beneath the PCVC. These eruptions produced three small <6 km3 crystal-rich dacite lava domes with radiogenic bulk rock 87Sr/86Sr ratios ranging from 0.7075 to 0.7081, that contain abundant basaltic-andesite inclusions with relatively low bulk rock 87Sr/86Sr ratios of 0.7057-0.7061. Plagioclase and amphibole in the host lava of Cerro Chascon, the largest of the domes, record two distinct magmatic environments; an upper crustal environment identical to that recorded in the Purico ignimbrite, and a second deeper, ∼15-20 km depth, higher temperature (∼922-1001 °C) environment. This deeper environment is recorded in textures and compositions of distinct mineral phases, and in intracrystalline isotope ratios. Plagioclase cores in the host dacite lava and mafic inclusions have in situ87Sr/86Sr isotopic compositions of 0.7083 to 0.7095, broadly similar to plagioclase from the Purico ignimbrite. In contrast, plagioclase rims and microphenocrysts in the mafic inclusions are isotopically distinct with lower 87Sr/86Sr isotope ratios (0.7057 to 0.7065 and 0.7062 to 0.7064, respectively) that overlap with the regional isotopic "baseline" compositions that are parental to the modern arc lavas. The textural and compositional characteristics of the PCVC attest to two distinct stages in its history. At ∼1 Ma the system was broadly homogeneous and dominantly dacitic recording extensive upper crustal magmatism. By ∼0.2 Ma the PCVC had transitioned to a more compositionally heterogeneous, smaller volume, mixed dacite to basaltic-andesite system, coinciding with the appearance of less-enriched "baseline" compositions. The evolution of PCVC is a microcosm of the Central Andean arc in this region where, from 10 to 1 Ma, upper crustal MASH processes resulted in the production and eruption of large volumes of homogeneous crystal-rich dacite during a regional ignimbrite flare-up. Since ∼1 Ma, decreasing explosivity, smaller eruptive volumes, increasing heterogeneity, and the emergence of less isotopically enriched basaltic-andesite to dacite composite volcanoes signal a return to steady-state arc volcanism. We posit that the transition from flare-up to steady state captured at the PCVC tracks the waning of the arc scale "thermal engine". High magmatic fluxes during the flare-up would lead to elevated geothermal gradients and efficient crustal processing leading to a dominantly "crustal" magmatism feeding the large volume Purico ignimbrite. This upper crustal MASH zone would act as an efficient filter to any parental compositions precluding them from the eruption record. As magmatic flux and thermal energy wanes, crustal isotherms would relax leading to greater thermal contrast between parental magmas, upper crust, and remnant felsic magmas stored in the upper crust. These changes are manifested in the preservation of textural and compositional heterogeneity and the survival of less isotopically enriched magmas in the upper crust. The chemical imprint of these arc-scale changes in magma dynamics is recorded at all scales from bulk rock to intra-crystalline. The distinct magma dynamics and chemical signatures of the two modes of arc magmatism detailed here should provide a model for investigations of mature continental arc evolution through time and space.

Miocene magmatism in the Bodie Hills volcanic field, California and Nevada: A long-lived eruptive center in the southern segment of the ancestral Cascades arc

USGS Publications Warehouse

John, David A.; du Bray, Edward A.; Blakely, Richard J.; Fleck, Robert J.; Vikre, Peter; Box, Stephen E.; Moring, Barry C.

2012-01-01

The Middle to Late Miocene Bodie Hills volcanic field is a >700 km2, long-lived (∼9 Ma) but episodic eruptive center in the southern segment of the ancestral Cascades arc north of Mono Lake (California, U.S.). It consists of ∼20 major eruptive units, including 4 trachyandesite stratovolcanoes emplaced along the margins of the field, and numerous, more centrally located silicic trachyandesite to rhyolite flow dome complexes. Bodie Hills volcanism was episodic with two peak periods of eruptive activity: an early period ca. 14.7–12.9 Ma that mostly formed trachyandesite stratovolcanoes and a later period between ca. 9.2 and 8.0 Ma dominated by large trachyandesite-dacite dome fields. A final period of small silicic dome emplacement occurred ca. 6 Ma. Aeromagnetic and gravity data suggest that many of the Miocene volcanoes have shallow plutonic roots that extend to depths ≥1–2 km below the surface, and much of the Bodie Hills may be underlain by low-density plutons presumably related to Miocene volcanism.Compositions of Bodie Hills volcanic rocks vary from ∼50 to 78 wt% SiO2, although rocks with <55 wt% SiO2 are rare. They form a high-K calc-alkaline series with pronounced negative Ti-P-Nb-Ta anomalies and high Ba/Nb, Ba/Ta, and La/Nb typical of subduction-related continental margin arcs. Most Bodie Hills rocks are porphyritic, commonly containing 15–35 vol% phenocrysts of plagioclase, pyroxene, and hornblende ± biotite. The oldest eruptive units have the most mafic compositions, but volcanic rocks oscillated between mafic and intermediate to felsic compositions through time. Following a 2 Ma hiatus in volcanism, postsubduction rocks of the ca. 3.6–0.1 Ma, bimodal, high-K Aurora volcanic field erupted unconformably onto rocks of the Miocene Bodie Hills volcanic field.At the latitude of the Bodie Hills, subduction of the Farallon plate is inferred to have ended ca. 10 Ma, evolving to a transform plate margin. However, volcanism in the region continued until 8 Ma without an apparent change in rock composition or style of eruption. Equidimensional, polygenetic volcanoes and the absence of dike swarms suggest a low differential horizontal stress regime throughout the lifespan of the Bodie Hills volcanic field. However, kinematic data for veins and faults in mining districts suggest a change in the stress field from transtensional to extensional approximately coincident with the inferred cessation of subduction.Numerous hydrothermal systems were operative in the Bodie Hills during the Miocene. Several large systems caused alteration of volcaniclastic rocks in areas as large as 30 km2, but these altered rocks are mostly devoid of economic mineral concentrations. More structurally focused hydrothermal systems formed large epithermal Au-Ag vein deposits in the Bodie and Aurora mining districts. Economically important hydrothermal systems are temporally related to intermediate to silicic composition domes.Rock types, major and trace element compositions, petrographic characteristics, and volcanic features of the Bodie Hills volcanic field are similar to those of other large Miocene volcanic fields in the southern segment of the ancestral Cascade arc. Relative to other parts of the ancestral arc, especially north of Lake Tahoe in northeastern California, the scarcity of mafic rocks, relatively K-rich calc-alkaline compositions, and abundance of composite dome fields in the Bodie Hills may reflect thicker crust beneath the southern ancestral arc segment. Thicker crust may have inhibited direct ascent and eruption of mafic, mantle-derived magma, instead stalling its ascent in the lower or middle crust, thereby promoting differentiation to silicic compositions and development of porphyritic textures characteristic of the southern ancestral arc segment.

Effects of hydrogenation on thermal conductivity of ultrananocrystalline diamond/amorphous carbon composite films prepared via coaxial arc plasma deposition

NASA Astrophysics Data System (ADS)

Takeichi, Satoshi; Nishiyama, Takashi; Tabara, Mitsuru; Kawawaki, Shuichi; Kohno, Masamichi; Takahashi, Koji; Yoshitake, Tsuyoshi

2018-06-01

Ultrananocrystalline diamond (UNCD)/hydrogenated amorphous carbon (a-C:H) composite (UNCD/a-C:H) and UNCD/non-hydrogenated amorphous carbon (a-C) composite (UNCD/a-C) films were prepared via coaxial arc plasma deposition, and their thermal conductivity and interfacial conductance in grain boundaries were measured using a time-domain thermoreflectance method. The interfacial conductance was estimated to be 1,010 and 4,892 MW/(m2·K) for UNCD/a-C:H and UNCD/a-C films, respectively. The reasons for the hydrogenated film having lower interfacial conductance than the non-hydrogenated film are 1) the reduced number of carriers that contribute to heat transport and 2) the hydrogen atoms, which are preferentially located at the grain boundaries and enhance phonon scattering.

Method for processing aluminum spent potliner in a graphite electrode ARC furnace

DOEpatents

O'Connor, William K.; Turner, Paul C.; Addison, Gerald W.

2002-12-24

A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

Geological Development of the Izu-Bonin Forearc Since the Eocene Based on Biostratigraphic, Rock Magnetic, and Sediment Provenance Observations from IODP Expedition 352 Drill Cores

NASA Astrophysics Data System (ADS)

Petronotis, K. E.; Robertson, A.; Kutterolf, S.; Avery, A.; Baxter, A.; Schindlbeck, J. C.; Wang, K. L.; Acton, G.

2016-12-01

International Ocean Discovery Program (IODP) Expedition 352 recovered early Oligocene to recent sediments above Eocene igneous basement at 4 sites in the Izu-Bonin Forearc. The sites were selected to investigate the forearc region since subduction initiation in the Eocene, with Sites U1439 and U1442 being cored into the upper trench slope and Sites U1440 and U1441 into the lower trench slope. Postcruise studies of biostratigraphy, sediment chemistry, tephra composition and chronology and magnetic properties, along with observations from prior coring help constrain the regional geological development. Volcanic activity in the area, as inferred from its influence on sediment composition, has varied between long periods of activity and quiescence. Combined whole-rock sediment chemistry and tephra compositions suggest that during the Oligocene to earliest Miocene ( 30-22 Ma) tuffaceous input of predominantly dacitic composition was mainly derived from the intra-oceanic Izu-Bonin Arc. The early Miocene interval ( 22-15 Ma) lacks tuffaceous input, as supported by rock magnetic data. During this period, the forearc subsided beneath the carbonate compensation depth (CCD), as evidenced by radiolarian-bearing mud and metal-rich silty clay. This was followed by input of tephra with bimodal felsic and mafic compositions from the Izu-Bonin Arc from 15 to 5 Ma. Middle Miocene to Quaternary time was characterized by increased carbonate preservation, coupled with abundant, predominantly felsic tephra input, which is chemically indicative of a Japan continental arc source (Honshu), with additional chemically distinctive input from the Izu-Bonin Arc. Extending back to 32 Ma, tephra layers can be correlated between the upper-slope sites, extrapolated to the less well-dated lower-slope sites, and further correlated with onland Japanese tephra (Kutterolf et al., 2016; Goldschmidt Conference). Overall, the new results provide an improved understanding of the regional tectonic evolution.

THE MOTION OF RX J185635-3754 -- THE NEAREST NEUTRON STAR TO EARTH

NASA Technical Reports Server (NTRS)

2002-01-01

This photograph is the sum of three Hubble Space Telescope images. North is down, east is to the right. The image, taken by the Wide Field and Planetary Camera 2, is 8.8 seconds of arc across (west to east), and 6.6 seconds of arc top-to-bottom (south to north). An arc second is a unit of angular measure. There are 3,600 arc seconds in 1 degree and 360 degrees in a full circle. All stars line up in this composite picture, except the neutron star, which moves across the image in a direction 10 degrees south of east. The three images of the neutron star are labeled by date. The proper motion is 1/3 of a second of arc per year. The small wobble caused by parallax (not visible in the image) has a size of 0.016 seconds of arc, giving a distance of 200 light-years. Credit: NASA and F.M. Walter (State University of New York at Stony Brook)

Resin/graphite fiber composites

NASA Technical Reports Server (NTRS)

Cavano, P. J.; Jones, R. J.; Vaughan, R. W.

1972-01-01

High temperature resin matrices suitable for use in advanced graphite fiber composites for jet engine applications were evaluated. A series of planned, sequential screening experiments with resin systems in composite form were performed to reduce the number of candidates to a single A-type polyimide resin that repetitively produced void-free, high strength and modulus composites acceptable for use in the 550 F range for 1000 hours. An optimized processing procedure was established for this system. Extensive mechanical property studies characterized this single system, at room temperature, 500 F, 550 F and 600 F, for various exposure times.

Geochemical characteristics of Proterozoic granite magmatism from Southern Granulite Terrain, India: Implications for Gondwana

NASA Astrophysics Data System (ADS)

Yellappa, T.; Rao, J. Mallikharjuna

2018-03-01

Granitoid intrusions occur widely in the Southern Granulite Terrain (SGT) of India, particularly within the Cauvery Suture Zone (CSZ), which is considered as the trace of the Neoproterozoic Mozambique ocean closure. Here we present the petrological and geochemical features of 19 granite plutons across the three major tectonic blocks of the terrain. Our data show a wide variation in the compositions of these intrusions from alkali feldspathic syenite to granite. The whole rock geochemistry of these intrusions displays higher concentrations of SiO2, FeO*, K2O, Ba, Zr, Th, LREE and low MgO, Na2O, Ti, P, Nb, Y and HREE's. The granitoids are metaluminous to slightly peraluminous in nature revealing both I-type and A-type origin. In tectonic discrimination plots, the plutons dominantly show volcanic arc and syn-collisional as well as post-collisional affinity. Based on the available age data together with geochemical constrains, we demonstrate that the granitic magmatism in the centre and south of the terrain is mostly associated with the Neoproterozoic subduction-collision-accretion-orogeny, followed by extensional mechanism of Gondwana tectonics events. Similar widespread granitic activity has also been documented in the Arabian Nubian shield, Madagascar, Sri Lanka and Antarctica, providing similarities for the reconstruction of the crustal fragments of Gondwana supercontinent followed by Pan-African orogeny.

A model for prediction of fume formation rate in gas metal arc welding (GMAW), globular and spray modes, DC electrode positive.

PubMed

Dennis, J H; Hewitt, P J; Redding, C A; Workman, A D

2001-03-01

Prediction of fume formation rate during metal arc welding and the composition of the fume are of interest to occupational hygienists concerned with risk assessment and to manufacturers of welding consumables. A model for GMAW (DC electrode positive) is described based on the welder determined process parameters (current, wire feed rate and wire composition), on the surface area of molten metal in the arc and on the partial vapour pressures of the component metals of the alloy wire. The model is applicable to globular and spray welding transfer modes but not to dip mode. Metal evaporation from a droplet is evaluated for short time increments and total evaporation obtained by summation over the life of the droplet. The contribution of fume derived from the weld pool and spatter (particles of metal ejected from the arc) is discussed, as are limitations of the model. Calculated droplet temperatures are similar to values determined by other workers. A degree of relationship between predicted and measured fume formation rates is demonstrated but the model does not at this stage provide a reliable predictive tool.

The Ordovician magmatic arc in the northern Chile-Argentina Andes between 21° and 26° south latitude

NASA Astrophysics Data System (ADS)

Niemeyer, Hans; Götze, Jens; Sanhueza, Marcos; Portilla, Carolina

2018-01-01

A continental magmatic arc (the Famatinian magmatic arc) was developed on the western margin of Gondwana during the Early to Middle Ordovician. This has a northwestern orientation in the northern Chile-Argentina Andes between 21° and 26° south latitude with a northeastern directed subduction zone and developed on a continental crust represented by a metamorphic basement. A paleogeographical scheme for the Ordovician magmatic arc is proposed and two tectonic environments can be recognized from our own data and data from the literature: forearc and arc. The Cordón de Lila Complex can be assigned to a forearc position. Here the turbiditic flows become paralell to the northwestern elongation of the magmatic arc. The sedimentation in the frontal-arc high platform of the forearc is represented by stromatolitic limestones and a zone of phosphate production. The internal structure of the arc can be inferred from the petrographic composition of the turbidites: basaltic and andesitic lavas, dacitic and/or rhyolitic lavas and ash fall tuffs. Also the Quebrada Grande Formation was developed on the forearc. Plutonic Ordovician rocks testify the continuity of the magmatic arc. The data about the basement exposed in the present paper do not support the existence of the Arequipa-Antofalla Terrane.

Cross-linked gelatin/nanoparticles composite coating on micro-arc oxidation film for corrosion and drug release

NASA Astrophysics Data System (ADS)

Xu, Xinhua; Lu, Ping; Guo, Meiqing; Fang, Mingzhong

2010-02-01

A composite coating which could control drug release and biocorrosion of magnesium alloy stent materials WE42 was prepared. This composite coating was fabricated on the surface of the micro-arc oxidation (MAO) film of the magnesium alloy, WE42, by mixing different degrees of cross-linked gelatin with well-dispersed poly( DL-lactide-co-glycolide) (PLGA) nanoparticles. The PLGA nanoparticles were prepared by emulsion solvent evaporation/extraction technique. Nano ZS laser diffraction particle size analyzer detected that the size of the nanoparticles to be 150-300 nm. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) was used to analyze the morphology of the nanoparticles and the composite coating. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were used to evaluate the corrosion behavior of the composite coating. Drug release was determined by ultraviolet-visible (UV-vis) spectrophotometer. The corrosion resistance of the composite coating was improved by preventing the corrosive ions from diffusing to the MAO films. The drug release rate of paclitaxel (PTX) exhibited a nearly linear sustained-release profile with no significant burst releases.

Metallogenetic systems associated with granitoid magmatism in the Amazonian Craton: An overview of the present level of understanding and exploration significance

NASA Astrophysics Data System (ADS)

Bettencourt, Jorge Silva; Juliani, Caetano; Xavier, Roberto P.; Monteiro, Lena V. S.; Bastos Neto, Artur C.; Klein, Evandro L.; Assis, Rafael R.; Leite, Washington Barbosa, Jr.; Moreto, Carolina P. N.; Fernandes, Carlos Marcello Dias; Pereira, Vitor Paulo

2016-07-01

The Amazonian Craton hosts world-class metallogenic provinces with a wide range of styles of primary precious, rare, base metal, and placer deposits. This paper provides a synthesis of the geological database with regard to granitoid magmatic suites, spatio temporal distribution, tectonic settings, and the nature of selected mineral deposits. The Archean Carajás Mineral Province comprises greenstone belts (3.04-2.97 Ga), metavolcanic-sedimentary units (2.76-2.74 Ga), granitoids (3.07-2.84 Ga) formed in a magmatic arc and syn-collisional setting, post-orogenic A2-type granites as well as gabbros (ca. 2.74 Ga), and anorogenic granites (1.88 Ga). Archean iron oxide-Cu-Au (IOCG) deposits were synchronous or later than bimodal magmatism (2.74-2.70 Ga). Paleoproterozoic IOCG deposits, emplaced at shallow-crustal levels, are enriched with Nb-Y-Sn-Be-U. The latter, as well as Sn-W and Au-EGP deposits are coeval with ca. 1.88 Ga A2-type granites. The Tapajós Mineral Province includes a low-grade meta-volcano-sedimentary sequence (2.01 Ga), tonalites to granites (2.0-1.87 Ga), two calc-alkaline volcanic sequences (2.0-1.95 Ga to 1.89-1.87 Ga) and A-type rhyolites and granites (1.88 Ga). The calc-alkaline volcanic rocks host epithermal Au and base metal mineralization, whereas Cu-Au and Cu-Mo ± Au porphyry-type mineralization is associated with sub-volcanic felsic rocks, formed in two continental magmatic arcs related to an accretionary event, resulting from an Andean-type northwards subduction. The Alta Floresta Gold Province consists of Paleoproterozoic plutono-volcanic sequences (1.98-1.75 Ga), generated in ocean-ocean orogenies. Disseminated and vein-type Au ± Cu and Au + base metal deposits are hosted by calc-alkaline I-type granitic intrusions (1.98 Ga, 1.90 Ga, and 1.87 Ga) and quartz-feldspar porphyries (ca. 1.77 Ga). Timing of the gold deposits has been constrained between 1.78 Ga and 1.77 Ga and linked to post-collisional Juruena arc felsic magmatism (e.g., Colíder and Teles Pires suites). The Transamazonas Province corresponds to a N-S-trending orogenic belt, consolidated during the Transamazonian cycle (2.26-1.95 Ga), comprising the Lourenço, Amapá, Carecuru, Bacajá, and Santana do Araguaia tectonic domains. They show a protracted tectonic evolution, and are host to the pre-, syn-, and post-orogenic to anorogenic granitic magmatism. Gold mineralization associated with magmatic events is still unclear. Greisen and pegmatite Sn-Nb-Ta deposits are related to 1.84 to 1.75 Ga late-orogenic to anorogenic A-type granites. The Pitinga Tin Province includes the Madeira Sn-Nb-Ta-F deposit, Sn-greisens and Sn-episyenites. These are associated with A-type granites of the Madeira Suite (1.84-1.82 Ga), which occur within a cauldron complex (Iricoumé Group). The A-type magmatism evolved from a post-collisional extension, towards a within-plate setting. The hydrothermal processes (400 °C-100 °C) resulted in albitization and formation of disseminated cryolite, pyrochlore columbitization, and formation of a massive cryolite deposit in the core of the Madeira deposit. The Rondônia Tin Province hosts rare-metal (Ta, Nb, Be) and Sn-W mineralization, which is associated with the São Lourenço-Caripunas (1.31-1.30 Ga), related to the post-collisional stage of the Rondônia San Ignácio Province (1.56-1.30 Ga), and to the Santa Clara (1.08-1.07 Ga) and Younger Granites of Rondônia (0.99-0.97 Ga) A-type granites. The latter are linked to the evolution of the Sunsás-Aguapeí Province (1.20-0.95 Ga). Rare-metal polymetallic deposits are associated with late stage peraluminous granites, mainly as greisen, quartz vein, and pegmatite types.

Formation of continental crust in a temporally linked arc magma system from 5 to 30 km depth: ~ 90 Ma plutonism in the Cascades Crystalline Core composite arc section

NASA Astrophysics Data System (ADS)

Ratschbacher, B. C.; Miller, J. S.; Kent, A. J.; Miller, R. B.; Anderson, J. L.; Paterson, S. R.

2015-12-01

Continental crust has an andesitic bulk composition with a mafic lower crust and a granodioritic upper crust. The formation of stratified continental crust in general and the vertical extent of processes active in arc crustal columns leading to the differentiation of primitive, mantle-derived melts entering the lower crust are highly debated. To investigate where in the crustal column magma mixing, fractionation, assimilation and crystal growth occur and to what extent, we study the ~ 90 Ma magmatic flare-up event of the Cascades arc, a magma plumbing system from ~ 5 to 30 km depth. We focus on three intrusive complexes, emplaced at different depths during major regional shortening in an exceptionally thick crust (≥ 55 km1) but which are temporally related: the upper crustal Black Peak intrusion (1-3 kbar at 3.7 to 11 km; ~ 86.8 to 91.7 Ma2), the mid-crustal Mt. Stuart intrusion (3.5-4.0 kbar at 13 to 15 km; 90.8 and 96.3 Ma3) and the deep crustal Tenpeak intrusion (7 to 10 kbar at 25 to 37 km; 89.7 to 92.3 Ma4). These intrusive complexes are well characterized by geochronology showing that they have been constructed incrementally by multiple magma batches over their lifespans and thus allow the monitoring and comparison of geochemical parameters over time at different depths. We use a combination of whole rock major and trace element data and isotopes combined with detailed investigation of amphibole, which has been recognized to be important in the generation of calc-alkaline rocks in arcs to test the following hypotheses: (a) compositional bimodality is produced in the lower crust, whereas upper crustal levels are dominated by mixing to form intermediate compositions, or (b) differentiation occurs throughout the crustal column with different crystallizing phases and their compositions controlling the bulk chemistry. 1. Miller et al. 2009: GSA Special Paper 456, p. 125-149 2. Shea 2014: PhD thesis, Massachusetts Institute of Technology 3. Anderson et al. 2012: International Geology Review, v. 54, no. 5, p. 491-508 4. Matzel et al. 2006: GSA Bulletin, v. 118, no. 11-12, p. 1412-1430

Bone density, body composition, and psychopathology of anorexia nervosa spectrum disorders in DSM-IV vs DSM-5

PubMed Central

Schorr, Melanie; Thomas, Jennifer J.; Eddy, Kamryn T.; Dichtel, Laura E.; Lawson, Elizabeth A.; Meenaghan, Erinne; Paskal, Margaret Lederfine; Fazeli, Pouneh K.; Faje, Alexander T.; Misra, Madhusmita; Klibanski, Anne; Miller, Karen K.

2016-01-01

Objective DSM-5 revised diagnostic criteria for anorexia nervosa (AN) by eliminating the amenorrhea requirement, liberalizing weight and psychological criteria, and adding the formal diagnosis of “atypical AN” for individuals with AN psychological symptoms without low weight. We sought to determine whether bone density (BMD) is impaired in women diagnosed with AN using the new, more liberal DSM-5 criteria. Method Cross-sectional study of 168 women, 18–45y: 1) AN by DSM-IV (DSM-IV)(n=37), 2) AN by DSM-5 but not DSM-IV criteria (DSM-5)(n=33), 3) atypical AN (ATYPICAL)(n=77), 4) healthy comparison group (HC)(n=21). Measurements included dual energy x-ray absorptiometry, Eating Disorder Examination-Questionnaire, Eating Disorder Inventory-2, Hamilton Depression and Anxiety Rating Scales. Results BMD Z-score <−1.0 was present in 78% of DSM-IV, 82% of DSM-5, and 69% of ATYPICAL. Mean Z-scores were comparably low in DSM-IV and DSM-5, intermediate in ATYPICAL, and highest in HC. Lack of prior low weight or amenorrhea was, but history of overweight/obesity was not, protective against bone loss. Mean lean mass and percent fat mass were significantly lower in all AN groups than HC. DSM-IV, DSM-5 and ATYPICAL had comparable psychopathology. Discussion Despite liberalizing diagnostic criteria, many women diagnosed with AN and atypical AN using DSM-5 criteria have low BMD. Presence or history of low weight and/or amenorrhea remain important indications for DXA. Loss of lean mass, in addition to fat mass, is present in all AN groups, and may contribute to low BMD. The deleterious effect of eating disorders on BMD extends beyond those with current low weight and amenorrhea. PMID:27527115

Unzipping of the volcano arc, Japan

USGS Publications Warehouse

Stern, R.J.; Smoot, N.C.; Rubin, M.

1984-01-01

A working hypothesis for the recent evolution of the southern Volcano Arc, Japan, is presented which calls upon a northward-progressing sundering of the arc in response to a northward-propagating back-arc basin extensional regime. This model appears to explain several localized and recent changes in the tectonic and magrnatic evolution of the Volcano Arc. Most important among these changes is the unusual composition of Iwo Jima volcanic rocks. This contrasts with normal arc tholeiites typical of the rest of the Izu-Volcano-Mariana and other primitive arcs in having alkaline tendencies, high concentrations of light REE and other incompatible elements, and relatively high silica contents. In spite of such fractionated characteristics, these lavas appear to be very early manifestations of a new volcanic and tectonic cycle in the southern Volcano Arc. These alkaline characteristics and indications of strong regional uplift are consistent with the recent development of an early stage of inter-arc basin rifting in the southern Volcano Arc. New bathymetric data are presented in support of this model which indicate: 1. (1) structural elements of the Mariana Trough extend north to the southern Volcano Arc. 2. (2) both the Mariana Trough and frontal arc shoal rapidly northwards as the Volcano Arc is approached. 3. (3) rugged bathymetry associated with the rifted Mariana Trough is replaced just south of Iwo Jima by the development of a huge dome (50-75 km diameter) centered around Iwo Jima. Such uplifted domes are the immediate precursors of rifts in other environments, and it appears that a similar situation may now exist in the southern Volcano Arc. The present distribution of unrifted Volcano Arc to the north and rifted Mariana Arc to the south is interpreted not as a stable tectonic configuration but as representing a tectonic "snapshot" of an arc in the process of being rifted to form a back-arc basin. ?? 1984.

Geochemical and NdSr isotopic composition of deep-sea turbidites: Crustal evolution and plate tectonic associations

NASA Astrophysics Data System (ADS)

McLennan, S. M.; Taylor, S. R.; McCulloch, M. T.; Maynard, J. B.

1990-07-01

Petrographic, geochemical, and isotopic data for turbidites from a variety of tectonic settings exhibit considerable variability that is related to tectonic association. Passive margin turbidites (Trailing Edge, Continental Collision) display high framework quartz (Q) content in sands, evolved major element compositions (high Si/Al, K/Na), incompatible element enrichments (high Th/Sc, La/Sc, La/Yb), negative Eu-anomalies and variable Th/U ratios. They have low 143Nd /144Nd and high 87Sr /86Sr ( ɛNd = -26 to -10; 87Sr /86Sr = 0.709 to 0.734 ), indicating a dominance of old upper crustal sources. Active margin settings (Fore Arc, Continental Arc, Back Arc, Strike Slip) commonly exhibit quite different compositions. Th/Sc varies from <0.01 to 1.8, and ɛNd varies from -13.8 to +8.3. Eu-anomalies range from no anomaly ( Eu/Eu ∗ = 1.0 ) to Eu-depletions typical of post-Archean shales ( Eu/Eu ∗ = 0.65 ). Active margin data are explained by mixtures of young arc-derived material, with variable composition and old upper crustal sources. Major element data indicate that passive margin turbidites have experienced more severe weathering histories than those from active settings. Most trace elements are enriched in muds relative to associated sands because of dilution effects from quartz and calcite and concentration of trace elements in clays. Exceptions include Zr, Hf (heavy mineral influence) and Tl (enriched in feldspar) which display enrichments in sands. Active margin sands commonly exhibit higher Eu/Eu ∗ than associated muds, resulting from concentration of plagioclase during sorting. Some associated sands and muds, especially from active settings, have systematic differences in Th/Sc ratios and Nd-isotopic composition, indicating that various provenance components may separate into different grain-size fractions during sedimentary sorting processes. Trace element abundances of modern turbidites, from both active and passive settings, differ from Archean turbidites in several important ways. Modern turbidites have less uniformity, for example, in Th/Sc ratios. On average, modern turbidites have greater depletions in Eu (lower Eu/Eu ∗) than do Archean turbidites, suggesting that the processes of intracrustal differentiation (involving plagioclase fractionation) are of greater importance for crustal evolution at modern continental margins than they were during the Archean. Modern turbidites do not display HREE depletion, a feature commonly seen in Archean data. HREE depletion ( Gd N/Yb N > 2.0 ) in Archean sediments results from incorporation of felsic igneous rocks that were in equilibrium (or their sources were in equilibrium) with garnet sometime in their history. Absence of HREE depletion at modern continental margins suggests that processes of crust formation (or mantle source compositions) may have differed. Differences in trace element abundances for Archean and modern turbidites add support to suggestions that upper continental crust compositions and major processes responsible for continental crust differentiation differed during the Archean. Neodymium model ages, thought to approximate average provenance age, are highly variable ( TDMND = 0-2.6 Ga) in modern turbidites, in contrast with studies that indicate Nd-model ages of lithified Phanerozoic sediment are fairly constant at about 1.5-2.0 Ga. This variability indicates that continental margin sediments incorporate new mantle-derived components, as well as continental crust of widely varying age, during recycling. The apparent dearth of ancient sediments with Nd-model age similar to stratigraphic age supports the suggestion that preservation potential of sediments is related to tectonic setting. Many samples from active settings have isotopic compositions similar to or only slightly evolved from mantle-derived igneous rocks. Subduction of active margin turbidites should be considered in models of crust-mantle recycling. For short-term recycling, such as that postulated for island arc petrogenesis, arc-derived turbidites cannot be easily recognized as a source component because of the lack of time available for isotopic evolution. If turbidites were incorporated into the sources of ocean island volcanics, the isotopic signatures would be considerably more evolved since most models call for long mantle storage times (1.0-2.0 Ga), prior to incorporation. Four provenance components are recognized on the basis of geochemistry and Nd-isotopic composition: (1) Old Upper Continental Crust (old igneous/metamorphic terranes, recycled sediment); (2) Young Undifferentiated Arc (young volcanic/plutonic source that has not experienced plagioclase fractionation); (3) Young Differentiated Arc (young volcanic/plutonic source that has experienced plagioclase fractionation); (4) MORB (minor). Relative proportions of these components are influenced by the plate tectonic association of the provenance and are typically (but not necessarily) reflected in the depositional basin. Provenance of quartzose (mainly passive settings) and non-quartzose (mainly active settings) turbidites can be characterized by bulk composition (e.g., Th/Sc) and Nd-isotopic composition (reflecting age).

Late Cambrian - Early Ordovician turbidites of Gorny Altai (Russia): Compositions, sources, deposition settings, and tectonic implications

NASA Astrophysics Data System (ADS)

Kruk, Nikolai N.; Kuibida, Yana V.; Shokalsky, Sergey P.; Kiselev, Vladimir I.; Gusev, Nikolay I.

2018-06-01

The Cambrian-Ordovician transition was the time of several key events in the history of Central Asia. They were the accretion of Mariana-type island arc systems to the Siberian continent, the related large-scale orogeny and intrusions of basaltic and granitic magma and the formation of a huge turbidite basin commensurate with the Bengal Gulf basin in the western part of the Central Asian orogenic belt (CAOB). The structure of the basin, as well as the sources and environments of deposition remain open to discussion. This paper presents new major- and trace-element data on Late-Cambrian-Early Ordovician turbidites from different parts of the Russian Altai and a synthesis of Nd isotope composition and ages of detrital zircons. The turbidites share chemical similarity with material shed from weathered continental arcs. Broad variations of CIA (39-73) and ICV (0.63-1.66) signatures in sandstones suggest origin from diverse sources and absence of significant sorting. Trace elements vary considerably and have generally similar patterns in rocks from different terranes. On the other hand, there are at least two provinces according to Nd isotope composition and age of detrital zircons. Samples from eastern Russian Altai contain only Phanerozoic zircons and have Nd isotope ratios similar to those in Early Cambrian island arcs (εNdt + 4.4… + 5.4; TNd(DM)-2-st = 0.8-0.9 Ga). Samples from central, western, and southern parts of Russian Altai contain Precambrian zircons (some as old as Late Archean) and have a less radiogenic Nd composition (εNdt up to -3.6; TNd(DM)-2-st up to 1.5 Ga). The chemical signatures of Late Cambrian to Early Ordovician turbidites indicate a provenance chemically more mature than the island arc rocks, and the presence of zircons with 510-490 Ma ages disproves their genetic relation with island arcs. The turbidite basin formed simultaneously with peaks of granitic and alkali-basaltic magmatism in the western Central Asian orogen and resulted from interplay of plate tectonic and plume tectonic processes.

Petrology and tectonics of Phanerozoic continent formation: From island arcs to accretion and continental arc magmatism

USGS Publications Warehouse

Lee, C.-T.A.; Morton, D.M.; Kistler, R.W.; Baird, A.K.

2007-01-01

Mesozoic continental arcs in the North American Cordillera were examined here to establish a baseline model for Phanerozoic continent formation. We combine new trace-element data on lower crustal xenoliths from the Mesozoic Sierra Nevada Batholith with an extensive grid-based geochemical map of the Peninsular Ranges Batholith, the southern equivalent of the Sierras. Collectively, these observations give a three-dimensional view of the crust, which permits the petrogenesis and tectonics of Phanerozoic crust formation to be linked in space and time. Subduction of the Farallon plate beneath North America during the Triassic to early Cretaceous was characterized by trench retreat and slab rollback because old and cold oceanic lithosphere was being subducted. This generated an extensional subduction zone, which created fringing island arcs just off the Paleozoic continental margin. However, as the age of the Farallon plate at the time of subduction decreased, the extensional environment waned, allowing the fringing island arc to accrete onto the continental margin. With continued subduction, a continental arc was born and a progressively more compressional environment developed as the age of subducting slab continued to young. Refinement into a felsic crust occurred after accretion, that is, during the continental arc stage, wherein a thickened crustal and lithospheric column permitted a longer differentiation column. New basaltic arc magmas underplate and intrude the accreted terrane, suture, and former continental margin. Interaction of these basaltic magmas with pre-existing crust and lithospheric mantle created garnet pyroxenitic mafic cumulates by fractional crystallization at depth as well as gabbroic and garnet pyroxenitic restites at shallower levels by melting of pre-existing lower crust. The complementary felsic plutons formed by these deep-seated differentiation processes rose into the upper crust, stitching together the accreted terrane, suture and former continental margin. The mafic cumulates and restites, owing to their high densities, eventually foundered into the mantle, leaving behind a more felsic crust. Our grid-based sampling allows us to estimate an unbiased average upper crustal composition for the Peninsular Ranges Batholith. Major and trace-element compositions are very similar to global continental crust averaged over space and time, but in detail, the Peninsular Ranges are slightly lower in compatible to mildly incompatible elements, MgO, Mg#, V, Sc, Co, and Cr. The compositional similarities suggest a strong arc component in global continental crust, but the slight discrepancies suggest that additional crust formation processes are also important in continent formation as a whole. Finally, the delaminated Sierran garnet pyroxenites have some of the lowest U/Pb ratios ever measured for silicate rocks. Such material, if recycled and stored in the deep mantle, would generate a reservoir with very unradiogenic Pb, providing one solution to the global Pb isotope paradox. ?? 2007 Elsevier B.V. All rights reserved.

Oxygen Isotopes in Intra-Back Arc Basalts from the Andean Southern Volcanic Zone

NASA Astrophysics Data System (ADS)

Parks, B. H.; Wang, Z.; Saal, A. E.; Frey, F. A.; Blusztajn, J.

2013-12-01

The chemical compositions of volcanic rocks from the Andean Southern Volcanic Zone (SVZ) reflect complex and dynamic interactions among the subducting oceanic lithosphere, the mantle wedge, and the overlying continental crust. Oxygen isotope ratios of olivine phenocrysts can be a useful means to identifying their relative contributions to the arc magmatism. In this study, we report high-precision oxygen-isotope ratios of olivine phenocrysts in a set of intra-back arc basalts from the SVZ. The samples were collected from monogenetic cinder cones east of the volcanic front (35-39 degrees S), and have been geochemically well-characterized with major and trace element contents, and Sr-Nd-Pb isotope compositions. Compared to lavas from the volcanic front, these intra-back arc lavas have similar radiogenic isotope, and a more alkalic and primitive (higher MgO content) chemical composition. We determined the oxygen-isotope ratios using the CO2-laser-fluorination method set up at the Department of Geology and Geophysics, Yale University following the techniques reported in Wang et al (2011). The samples were analyzed with standards of Gore Mountain Garnet (5.77×0.12‰ 1σ; Valley et al., 1995) and Kilbourne Hole Olivine (5.23×0.07‰ 1σ; Sharp, 1990) in order to account for minor changes in the vacuum line during analyses. The obtained δ18OSMOW values of olivine phenocrysts from the intra-back arc basalts vary from 4.98×0.01 to 5.34×0.01‰. This range, surprisingly, is similar to the δ18O values of olivines from mantle peridotites (5.2×0.2‰). Preliminary results indicate significant correlations of 87Sr/86Sr, 143Nd/144Nd and trace element ratios of the basaltic matrix with the δ18O values of olivine phenocrysts, indicating at least three components involved in the formation of the arc volcanism. By comparing the δ18O with the variations of major and trace element contents (e.g., MgO, TiO2 and Ni), and trace element ratios (e.g. Ba/Nb), we evaluate the effects of fractionation crystallization, crustal contamination, the extent of slab flux, metasomatism, and melting of the mantle wedge on the intra-back arc lavas from the SVZ.

Provenance of Late Ordovician Sandstones along the southeastern Appalachian Mountains: Implications for the Tectonic Model of the Taconic Orogeny

NASA Astrophysics Data System (ADS)

Guerrero, J. C.; Herrmann, A. D.; Haynes, J.

2017-12-01

A provenance study of sandstones along the southeastern Appalachian Mountains has been conducted in order to test the current volcanic arc-continent collision and foreland basin formation model of the Taconic Orogeny. Samples along the southeastern Appalachians were taken from sandstone sequences deposited between 460-450 Ma. Results from these sandstones show three dominate age ranges: 465-685 Ma, 980-1300 Ma, and 1300-1500 Ma. The 980-1300 Ma and 1300-1500 Ma ages are seen throughout the study area and are compatible with previously reported ages of the Grenville Orogeny and the Rhyolite-Granite Province. The northernmost samples have a small quantity of 465-685 Ma zircons which is attributed to an accretionary wedge that formed as a result of the continent-island arc collision and acted as a physical barrier keeping sediment from depositing within the basin. The younger age signal becomes stronger to the south, as samples in Georgia and Alabama show strong concentrations of 465-685 zircons. These ages are attributed to exotic terranes (Dalhonega Terrane and Carolina Terrane) that were accreted onto Laurentia during the Taconic Orogeny and/or a possible change in subduction direction leading to a back-arc basin model for the southern Appalachian Taconic Orogeny. The results from this provenance analysis support previous studies indicating that the model for the Taconic Orogeny is a combined A-type subduction for the north and a B-type subduction model for the southern part of the orogeny.

Tracing subducted crustal materials in the mantle by using magnesium isotopes

NASA Astrophysics Data System (ADS)

Teng, F. Z.

2016-12-01

Recent studies show that some continental basalt, mantle-metasomatised peridotite and cratonic eclogite have heterogeneous Mg isotopic compositions. These isotopically distinct Mg isotopic compositions have been explained by the incorporation of subducted materials in their mantle sources though the detailed mechanisms are still not well understood. In particular, how Mg-poor crustal materials can modify Mg isotopic systematics of Mg-rich mantle is unknown. Subduction zones are the most efficient sites for crust and mantle interactions, hence should be where the most prominent Mg isotopic variation occurs. However, to date, little is known on Mg isotope systematics in the subduction factory. Here I first review and report new Mg isotopic data for arc lava, subarc peridotite and the subducted slab (marine sediment, altered basalt and abyssal peridotite), then use them to constrain the origins of mantle Mg isotopic heterogeneity and lay the foundation for using Mg isotopes as new tools for tracing crust-mantle interactions. The main conclusions are 1) fluid-rock interactions can modify Mg isotopic systematics of abyssal peridotites; 2) island arc lavas have non-MORB Mg isotopic compositions, reflecting distinct surbarc mantle Mg isotopic signature; 3) continental arcs have non-MORB Mg isotopic compositions, likely resulting from crustal contamination and 4) the isotopically heterogeneous continental basalts are mainly produced by mixing of isotopically distinct magmas instead of being partial melting products of metasomatised mantle peridotites.

Voluminous arc dacites as amphibole reaction-boundary liquids

USGS Publications Warehouse

Blatter, Dawnika; Sisson, Thomas W.; Hankins, William B.

2017-01-01

Dacites dominate the large-volume, explosive eruptions in magmatic arcs, and compositionally similar granodiorites and tonalites constitute the bulk of convergent margin batholiths. Shallow, pre-eruptive storage conditions are well known for many dacitic arc magmas through melt inclusions, Fe–Ti oxides, and experiments, but their potential origins deeper in the crust are not well determined. Accordingly, we report experimental results identifying the P–T–H2O conditions under which hydrous dacitic liquid may segregate from hornblende (hbl)-gabbroic sources either during crystallization–differentiation or partial melting. Two compositions were investigated: (1) MSH–Yn−1 dacite (SiO2: 65 wt%) from Mount St. Helens’ voluminous Yn tephra and (2) MSH–Yn−1 + 10% cpx to force saturation with cpx and map a portion of the cpx + melt = hbl peritectic reaction boundary. H2O-undersaturated (3, 6, and 9 wt% H2O) piston cylinder experiments were conducted at pressures, temperatures, and fO2 appropriate for the middle to lower arc crust (400, 700, and 900 MPa, 825–1100 °C, and the Re–ReO2 buffer ≈ Ni–NiO + 2). Results for MSH–Yn−1 indicate near-liquidus equilibrium with a cpx-free hbl-gabbro residue (hbl, plg, magnetite, ± opx, and ilmeno-hematite) with 6–7 wt% dissolved H2O, 925 °C, and 700–900 MPa. Opx disappears down-temperature consistent with the reaction opx + melt = hbl. Cpx-added phase relations are similar in that once ~10% cpx crystallizes, multiple saturation is attained with cpx, hbl, and plg, +/− opx, at 6–7 wt% dissolved H2O, 940 °C, and 700–900 MPa. Plg–hbl–cpx saturated liquids diverge from plg–hbl–opx saturated liquids, consistent with the MSH–Yn−1 dacite marking a liquid composition along a peritectic distributary reaction boundary where hbl appears down-temperature as opx + cpx are consumed. The abundance of saturating phases along this distributary peritectic (liquid + hbl + opx + cpx + plg + oxides) reduces the variance, so liquids are restricted to dacite–granodiorite–tonalite compositions. Higher-K dacites than the Yn would also saturate with biotite, further limiting their compositional diversity. Theoretical evaluation of the energetics of peritectic melting of pargasitic amphiboles indicates that melting and crystallization of amphibole occur abruptly, proximal to amphibole’s high-temperature stability limit, which causes the system to dwell thermally under the conditions that produce dacitic compositions. This process may account for the compositional homogeneity of dacites, granodiorites, and tonalites in arc settings, but their relative mobility compared to rhyolitic/granitic liquids likely accounts for their greater abundance.

Seismic velocity variation along the Izu-Bonin arc estaimated from traveltime tomography using OBS data

NASA Astrophysics Data System (ADS)

Obana, K.; Tamura, Y.; Takahashi, T.; Kodaira, S.

2014-12-01

The Izu-Bonin (Ogasawara) arc is an intra-oceanic island arc along the convergent plate boundary between the subducting Pacific and overriding Philippine Sea plates. Recent active seismic studies in the Izu-Bonin arc reveal significant along-arc variations in crustal structure [Kodaira et al., 2007]. The thickness of the arc crust shows a remarkable change between thicker Izu (~30 km) and thinner Bonin (~10 km) arcs. In addition to this, several geological and geophysical contrasts, such as seafloor topography and chemical composition of volcanic rocks, between Izu and Bonin arc have been reported [e.g., Yuasa 1992]. We have conducted earthquake observations using ocean bottom seismographs (OBSs) to reveal seismic velocity structure of the crust and mantle wedge in the Izu-Bonin arc and to investigate origin of the along-arc structure variations. We deployed 40 short-period OBSs in Izu and Bonin area in 2006 and 2009, respectively. The OBS data were processed with seismic data recorded at routine seismic stations on Hachijo-jima, Aoga-shima, and Chichi-jima operated by National Research Institute for Earth Science and Disaster Prevention (NIED). More than 5000 earthquakes were observed during about three-months observation period in each experiment. We conducted three-dimensional seismic tomography using manually picked P- and S-wave arrival time data. The obtained image shows a different seismic velocity structures in the mantle beneath the volcanic front between Izu and Bonin arcs. Low P-wave velocity anomalies in the mantle beneath the volcanic front in the Izu arc are limited at depths deeper than those in the Bonin arc. On the other hand, P-wave velocity in the low velocity anomalies beneath volcanic front in the Bonin arc is slower than that in the Izu arc. These large-scale along-arc structure variations in the mantle could relate to the geological and geophysical contrasts between Izu and Bonin arcs.

Bivergent thrust wedges surrounding oceanic island arcs: Insight from observations and sandbox models of the northeastern caribbean plate

USGS Publications Warehouse

ten Brink, Uri S.; Marshak, S.; Granja, Bruna J.L.

2009-01-01

At several localities around the world, thrust belts have developed on both sides of oceanic island arcs (e.g., Java-Timor, Panama, Vanuatu, and the northeastern Caribbean). In these localities, the overall vergence of the backarc thrust belt is opposite to that of the forearc thrust belt. For example, in the northeastern Caribbean, a north-verging accretionary prism lies to the north of the Eastern Greater Antilles arc (Hispaniola and Puerto Rico), whereas a south-verging thrust belt called the Muertos thrust belt lies to the south. Researchers have attributed such bivergent geometry to several processes, including: reversal of subduction polarity; subduction-driven mantle flow; stress transmission across the arc; gravitational spreading of the arc; and magmatic inflation within the arc. New observations of deformational features in the Muertos thrust belt and of fault geometries produced in sandbox kinematic models, along with examination of published studies of island arcs, lead to the conclusion that the bivergence of thrusting in island arcs can develop without reversal of subduction polarity, without subarc mantle flow, and without magmatic inflation. We suggest that the Eastern Greater Antilles arc and comparable arcs are simply crustalscale bivergent (or "doubly vergent") thrust wedges formed during unidirectional subduction. Sandbox kinematic modeling suggests, in addition, that a broad retrowedge containing an imbricate fan of thrusts develops only where the arc behaves relatively rigidly. In such cases, the arc acts as a backstop that transmits compressive stress into the backarc region. Further, modeling shows that when arcs behave as rigid blocks, the strike-slip component of oblique convergence is accommodated entirely within the prowedge and the arc-the retrowedge hosts only dip-slip faulting ("frontal thrusting"). The existence of large retrowedges and the distribution of faulting in an island arc may, therefore, be evidence that the arc is relatively rigid. The rigidity of an island arc may arise from its mafi c composition and has implications for seismic-hazard analysis. ?? 2009 Geological Society of America.

IODP Expedition 351 Izu-Bonin-Mariana Arc Origins: Preliminary Results

NASA Astrophysics Data System (ADS)

Ishizuka, O.; Arculus, R. J.; Bogus, K.

2014-12-01

Understanding how subduction zones initiate and continental crust forms in intraoceanic arcs requires knowledge of the inception and evolution of a representative intraoceanic arc, such as the Izu-Bonin-Mariana (IBM) Arc system. This can be obtained by exploring regions adjacent to an arc, where unequivocal pre-arc crust overlain by undisturbed arc-derived materials exists. IODP Exp. 351 (June-July 2014) specifically targeted evidence for the earliest evolution of the IBM system following inception. Site U1438 (4711 m water depth) is located in the Amami Sankaku Basin (ASB), west of the Kyushu-Palau Ridge (KPR), a paleo-IBM arc. Primary objectives of Exp. 351 were: 1) determine the nature of the crust and mantle pre-existing the IBM arc; 2) identify and model the process of subduction initiation and initial arc crust formation; 3) determine the compositional evolution of the IBM arc during the Paleogene; 4) establish geophysical properties of the ASB. Seismic reflection profiles indicate a ~1.3 km thick sediment layer overlying ~5.5 km thick igneous crust, presumed to be oceanic. This igneous crust seemed likely to be the basement of the IBM arc. Four holes were cored at Site U1438 spanning the entire sediment section and into basement. The cored interval comprises 5 units: uppermost Unit I is hemipelagic sediment with intercalated ash layers, presumably recording explosive volcanism mainly from the Ryukyu and Kyushu arcs; Units II and III host a series of volcaniclastic gravity-flow deposits, likely recording the magmatic history of the IBM Arc from arc initiation until 25 Ma; Siliceous pelagic sediment (Unit IV) underlies these deposits with minimal coarse-grained sediment input and may pre-date arc initiation. Sediment-basement contact occurs at 1461 mbsf. A basaltic lava flow section dominantly composed of plagioclase and clinopyroxene with rare chilled margins continues to the bottom of the Site (1611 mbsf). The expedition successfully recovered pre-IBM Arc basement, a volcanic and geologic record spanning pre-Arc, Arc initiation to remnant Arc stages, which permits testing for subduction initiation and subsequent Arc evolution.

Silica-alumina trihydrate filled epoxy castings resistant to arced SF.sub.6

DOEpatents

Chenoweth, Terrence E.; Yeoman, Frederick A.

1978-01-01

A cured, insulating, casting composition, having a coefficient of linear thermal expansion of below about 38 .times. 10.sup.-6 in./in./.degree. C and being resistant to arced sulfur hexafluoride gas, in contact with a metal surface in a sulfur hexafluoride gas environment, is made from hydantoin epoxy resin, anhydride curing agent and a filler combination of fused silica and alumina trihydrate.

Wilson cycle studies

NASA Technical Reports Server (NTRS)

1987-01-01

Continents originate by the sweeping together of island arcs. Continental and island arc crusts are dominated by rocks of comparable compositional and density ranges, evidence of the operation of this process is abundant in the geological record, and can be seen in action today in Indonesia. Lineaments within continents are attributable to a small number of processes of continent formation and modification, but interactions among these processes may produce complex patterns.

Development of a new generation of high-temperature composite materials

NASA Technical Reports Server (NTRS)

Brindley, P. K.

1990-01-01

Intermetallic matrix composites proposed to meet advanced aeropropulsion requirements are discussed. The powder metallurgy fabrication process currently being used to produce these intermetallic matrix composites will be presented, as will properties of one such composite, SiC/Ti3Al+Nb. In addition, the direction of future research will be outlined, including plans for enhanced fabrication of intermetallic composites by the arc-spray technique and fiber development by the floating-zone process.

Evaluation of mechanical properties of Aluminum-Copper cold sprayed and alloy 625 wire arc sprayed coatings

NASA Astrophysics Data System (ADS)

Bashirzadeh, Milad

This study examines microstructural-based mechanical properties of Al-Cu composite deposited by cold spraying and wire arc sprayed nickel-based alloy 625 coating using numerical modeling and experimental techniques. The microhardness and elastic modulus of samples were determined using the Knoop hardness technique. Hardness in both transverse and longitudinal directions on the sample cross-sections has been measured. An image-based finite element simulation algorithm was employed to determine the mechanical properties through an inverse analysis. In addition mechanical tests including, tensile, bending, and nano-indentation tests were performed on alloy 625 wire arc sprayed samples. Overall, results from the experimental tests are in relatively good agreement for deposited Al-Cu composites and alloy 625 coating. However, results obtained from numerical simulation are significantly higher in value than experimentally obtained results. Examination and comparison of the results are strong indications of the influence of microstructure characteristics on the mechanical properties of thermally spray deposited coatings.

Tracing halogen and B cycling in subduction zones based on obducted, subducted and forearc serpentinites of the Dominican Republic.

PubMed

Pagé, Lilianne; Hattori, Keiko

2017-12-19

Serpentinites are important reservoirs of fluid-mobile elements in subduction zones, contributing to volatiles in arc magmas and their transport into the Earth's mantle. This paper reports halogen (F, Cl, Br, I) and B abundances of serpentinites from the Dominican Republic, including obducted and subducted abyssal serpentinites and forearc mantle serpentinites. Abyssal serpentinite compositions indicate the incorporation of these elements from seawater and sediments during serpentinization on the seafloor and at slab bending. During their subduction and subsequent lizardite-antigorite transition, F and B are retained in serpentinites, whilst Cl, Br and I are expelled. Forearc mantle serpentinite compositions suggest their hydration by fluids released from subducting altered oceanic crust and abyssal serpentinites, with only minor sediment contribution. This finding is consistent with the minimal subduction of sediments in the Dominican Republic. Forearc mantle serpentinites have F/Cl and B/Cl ratios similar to arc magmas, suggesting the importance of serpentinite dehydration in the generation of arc magmatism in the mantle wedge.

Atypical fracture with long-term bisphosphonate therapy is associated with altered cortical composition and reduced fracture resistance

PubMed Central

Lloyd, Ashley A.; Gludovatz, Bernd; Riedel, Christoph; Luengo, Emma A.; Saiyed, Rehan; Marty, Eric; Lorich, Dean G.; Lane, Joseph M.; Ritchie, Robert O.

2017-01-01

Bisphosphonates are the most widely prescribed pharmacologic treatment for osteoporosis and reduce fracture risk in postmenopausal women by up to 50%. However, in the past decade these drugs have been associated with atypical femoral fractures (AFFs), rare fractures with a transverse, brittle morphology. The unusual fracture morphology suggests that bisphosphonate treatment may impair toughening mechanisms in cortical bone. The objective of this study was to compare the compositional and mechanical properties of bone biopsies from bisphosphonate-treated patients with AFFs to those from patients with typical osteoporotic fractures with and without bisphosphonate treatment. Biopsies of proximal femoral cortical bone adjacent to the fracture site were obtained from postmenopausal women during fracture repair surgery (fracture groups, n = 33) or total hip arthroplasty (nonfracture groups, n = 17). Patients were allocated to five groups based on fracture morphology and history of bisphosphonate treatment [+BIS Atypical: n = 12, BIS duration: 8.2 (3.0) y; +BIS Typical: n = 10, 7.7 (5.0) y; +BIS Nonfx: n = 5, 6.4 (3.5) y; −BIS Typical: n = 11; −BIS Nonfx: n = 12]. Vibrational spectroscopy and nanoindentation showed that tissue from bisphosphonate-treated women with atypical fractures was harder and more mineralized than that from bisphosphonate-treated women with typical osteoporotic fractures. In addition, fracture mechanics measurements showed that tissue from patients treated with bisphosphonates had deficits in fracture toughness, with lower crack-initiation toughness and less crack deflection at osteonal boundaries than that of bisphosphonate-naïve patients. Together, these results suggest a deficit in intrinsic and extrinsic toughening mechanisms, which contribute to AFFs in patients treated with long-term bisphosphonates. PMID:28760963

Constraints on the source of Cu in a submarine magmatic-hydrothermal system, Brothers volcano, Kermadec island arc

NASA Astrophysics Data System (ADS)

Keith, Manuel; Haase, Karsten M.; Klemd, Reiner; Smith, Daniel J.; Schwarz-Schampera, Ulrich; Bach, Wolfgang

2018-05-01

Most magmatic-hydrothermal Cu deposits are genetically linked to arc magmas. However, most continental or oceanic arc magmas are barren, and hence new methods have to be developed to distinguish between barren and mineralised arc systems. Source composition, melting conditions, the timing of S saturation and an initial chalcophile element-enrichment represent important parameters that control the potential of a subduction setting to host an economically valuable deposit. Brothers volcano in the Kermadec island arc is one of the best-studied examples of arc-related submarine magmatic-hydrothermal activity. This study, for the first time, compares the chemical and mineralogical composition of the Brothers seafloor massive sulphides and the associated dacitic to rhyolitic lavas that host the hydrothermal system. Incompatible trace element ratios, such as La/Sm and Ce/Pb, indicate that the basaltic melts from L'Esperance volcano may represent a parental analogue to the more evolved Brothers lavas. Copper-rich magmatic sulphides (Cu > 2 wt%) identified in fresh volcanic glass and phenocryst phases, such as clinopyroxene, plagioclase and Fe-Ti oxide suggest that the surrounding lavas that host the Brothers hydrothermal system represent a potential Cu source for the sulphide ores at the seafloor. Thermodynamic calculations reveal that the Brothers melts reached volatile saturation during their evolution. Melt inclusion data and the occurrence of sulphides along vesicle margins indicate that an exsolving volatile phase extracted Cu from the silicate melt and probably contributed it to the overlying hydrothermal system. Hence, the formation of the Cu-rich seafloor massive sulphides (up to 35.6 wt%) is probably due to the contribution of Cu from a bimodal source including wall rock leaching and magmatic degassing, in a mineralisation style that is hybrid between Cyprus-type volcanic-hosted massive sulphide and subaerial epithermal-porphyry deposits.

QUES, a new Phaseolus vulgaris genotype resistant to common bean weevils, contains the Arcelin-8 allele coding for new lectin-related variants.

PubMed

Zaugg, Isabelle; Magni, Chiara; Panzeri, Dario; Daminati, Maria Gloria; Bollini, Roberto; Benrey, Betty; Bacher, Sven; Sparvoli, Francesca

2013-03-01

In common bean (Phaseolus vulgaris L.), the most abundant seed proteins are the storage protein phaseolin and the family of closely related APA proteins (arcelin, phytohemagglutinin and α-amylase inhibitor). High variation in APA protein composition has been described and the presence of arcelin (Arc) has been associated with bean resistance against two bruchid beetles, the bean weevil (Acanthoscelides obtectus Say) and the Mexican bean weevil (Zabrotes subfasciatus Bohemian). So far, seven Arc variants have been identified, all in wild accessions, however, only those containing Arc-4 were reported to be resistant to both species. Although many efforts have been made, a successful breeding of this genetic trait into cultivated genotypes has not yet been achieved. Here, we describe a newly collected wild accession (named QUES) and demonstrate its resistance to both A. obtectus and Z. subfasciatus. Immunological and proteomic analyses of QUES seed protein composition indicated the presence of new Arc and arcelin-like (ARL) polypeptides of about 30 and 27 kDa, respectively. Sequencing of cDNAs coding for QUES APA proteins confirmed that this accession contains new APA variants, here referred to as Arc-8 and ARL-8. Moreover, bioinformatic analysis showed the two proteins are closely related to APA components present in the G12949 wild bean accession, which contains the Arc-4 variant. The presence of these new APA components, combined with the observations that they are poorly digested and remain very abundant in A. obtectus feces, so-called frass, suggest that the QUES APA locus is involved in the bruchid resistance. Moreover, molecular analysis indicated a lower complexity of the locus compared to that of G12949, suggesting that QUES should be considered a valuable source of resistance for further breeding purposes.

Regional-scale input of dispersed and discrete volcanic ash to the Izu-Bonin and Mariana subduction zones

NASA Astrophysics Data System (ADS)

Scudder, Rachel P.; Murray, Richard W.; Schindlbeck, Julie C.; Kutterolf, Steffen; Hauff, Folkmar; McKinley, Claire C.

2014-11-01

We have geochemically and statistically characterized bulk marine sediment and ash layers at Ocean Drilling Program Site 1149 (Izu-Bonin Arc) and Deep Sea Drilling Project Site 52 (Mariana Arc), and have quantified that multiple dispersed ash sources collectively comprise ˜30-35% of the hemipelagic sediment mass entering the Izu-Bonin-Mariana subduction system. Multivariate statistical analyses indicate that the bulk sediment at Site 1149 is a mixture of Chinese Loess, a second compositionally distinct eolian source, a dispersed mafic ash, and a dispersed felsic ash. We interpret the source of these ashes as, respectively, being basalt from the Izu-Bonin Front Arc (IBFA) and rhyolite from the Honshu Arc. Sr-, Nd-, and Pb isotopic analyses of the bulk sediment are consistent with the chemical/statistical-based interpretations. Comparison of the mass accumulation rate of the dispersed ash component to discrete ash layer parameters (thickness, sedimentation rate, and number of layers) suggests that eruption frequency, rather than eruption size, drives the dispersed ash record. At Site 52, the geochemistry and statistical modeling indicates that Chinese Loess, IBFA, dispersed BNN (boninite from Izu-Bonin), and a dispersed felsic ash of unknown origin are the sources. At Site 1149, the ash layers and the dispersed ash are compositionally coupled, whereas at Site 52 they are decoupled in that there are no boninite layers, yet boninite is dispersed within the sediment. Changes in the volcanic and eolian inputs through time indicate strong arc-related and climate-related controls.

A multifaceted comparison of ArcGIS and MapMarker for automated geocoding.

PubMed

Kumar, Sanjaya; Liu, Ming; Hwang, Syni-An

2012-11-01

Geocoding is increasingly being used for public health surveillance and spatial epidemiology studies. Public health departments in the United States of America (USA) often use this approach to investigate disease outbreaks and clusters or assign health records to appropriate geographic units. We evaluated two commonly used geocoding software packages, ArcGIS and MapMarker, for automated geocoding of a large number of residential addresses from health administrative data in New York State, USA to better understand their features, performance and limitations. The comparison was based on three metrics of evaluation: completeness (or match rate), geocode similarity and positional accuracy. Of the 551,798 input addresses, 318,302 (57.7%) were geocoded by MapMarker and 420,813 (76.3%) by the ArcGIS composite address locator. High similarity between the geocodes assigned by the two methods was found, especially in suburban and urban areas. Among addresses with a distance of greater than 100 m between the geocodes assigned by the two packages, the point assigned by ArcGIS was closer to the associated parcel centroid ("true" location) compared with that assigned by MapMarker. In addition, the composite address locator in ArcGIS allows users to fully utilise available reference data, which consequently results in better geocoding results. However, the positional differences found were minimal, and a large majority of addresses were placed on the same locations by both geocoding packages. Using both methods and combining the results can maximise match rates and save the time needed for manual geocoding.

Magmatic evolution of Panama Canal volcanic rocks: A record of arc processes and tectonic change.

PubMed

Farris, David W; Cardona, Agustin; Montes, Camilo; Foster, David; Jaramillo, Carlos

2017-01-01

Volcanic rocks along the Panama Canal present a world-class opportunity to examine the relationship between arc magmatism, tectonic forcing, wet and dry magmas, and volcanic structures. Major and trace element geochemistry of Canal volcanic rocks indicate a significant petrologic transition at 21-25 Ma. Oligocene Bas Obispo Fm. rocks have large negative Nb-Ta anomalies, low HREE, fluid mobile element enrichments, a THI of 0.88, and a H2Ocalc of >3 wt. %. In contrast, the Miocene Pedro Miguel and Late Basalt Fm. exhibit reduced Nb-Ta anomalies, flattened REE curves, depleted fluid mobile elements, a THI of 1.45, a H2Ocalc of <1 wt. %, and plot in mid-ocean ridge/back-arc basin fields. Geochemical modeling of Miocene rocks indicates 0.5-0.1 kbar crystallization depths of hot (1100-1190°C) magmas in which most compositional diversity can be explained by fractional crystallization (F = 0.5). However, the most silicic lavas (Las Cascadas Fm.) require an additional mechanism, and assimilation-fractional-crystallization can reproduce observed compositions at reasonable melt fractions. The Canal volcanic rocks, therefore, change from hydrous basaltic pyroclastic deposits typical of mantle-wedge-derived magmas, to hot, dry bi-modal magmatism at the Oligocene-Miocene boundary. We suggest the primary reason for the change is onset of arc perpendicular extension localized to central Panama. High-resolution mapping along the Panama Canal has revealed a sequence of inward dipping maar-diatreme pyroclastic pipes, large basaltic sills, and bedded silicic ignimbrites and tuff deposits. These volcanic bodies intrude into the sedimentary Canal Basin and are cut by normal and subsequently strike-slip faults. Such pyroclastic pipes and basaltic sills are most common in extensional arc and large igneous province environments. Overall, the change in volcanic edifice form and geochemistry are related to onset of arc perpendicular extension, and are consistent with the idea that Panama arc crust fractured during collision with South America forming the observed Canal extensional zone.

Pliocene granodioritic knoll with continental crust affinities discovered in the intra-oceanic Izu-Bonin-Mariana Arc: Syntectonic granitic crust formation during back-arc rifting

NASA Astrophysics Data System (ADS)

Tani, Kenichiro; Dunkley, Daniel J.; Chang, Qing; Nichols, Alexander R. L.; Shukuno, Hiroshi; Hirahara, Yuka; Ishizuka, Osamu; Arima, Makoto; Tatsumi, Yoshiyuki

2015-08-01

A widely held hypothesis is that modern continental crust of an intermediate (i.e. andesitic) bulk composition forms at intra-oceanic arcs through subduction zone magmatism. However, there is a critical paradox in this hypothesis: to date, the dominant granitic rocks discovered in these arcs are tonalite, rocks that are significantly depleted in incompatible (i.e. magma-preferred) elements and do not geochemically and petrographically represent those of the continents. Here we describe the discovery of a submarine knoll, the Daisan-West Sumisu Knoll, situated in the rear-arc region of the intra-oceanic Izu-Bonin-Mariana Arc. Remotely-operated vehicle surveys reveal that this knoll is made up entirely of a 2.6 million year old porphyritic to equigranular granodiorite intrusion with a geochemical signature typical of continental crust. We present a model of granodiorite magma formation that involves partial remelting of enriched mafic rear-arc crust during the initial phase of back-arc rifting, which is supported by the preservation of relic cores inherited from initial rear-arc source rocks within magmatic zircon crystals. The strong extensional tectonic regime at the time of intrusion may have allowed the granodioritic magma to be emplaced at an extremely shallow level, with later erosion of sediment and volcanic covers exposing the internal plutonic body. These findings suggest that rear-arc regions could be the potential sites of continental crust formation in intra-oceanic convergent margins.

Effect of sandblasting intensity on microstructures and properties of pure titanium micro-arc oxidation coatings in an optimized composite technique

NASA Astrophysics Data System (ADS)

Wang, Hong-Yuan; Zhu, Rui-Fu; Lu, Yu-Peng; Xiao, Gui-Yong; He, Kun; Yuan, Y. F.; Ma, Xiao-Ni; Li, Ying

2014-02-01

Sandblasting is one of the most effective methods to modify a metal surface and improve its properties for application. Micro-arc oxidation (MAO) could produce a ceramic coating on a dental implant, facilitating cellular differentiation and osseocomposite on it. This study aims to deposit bioceramic Ca- and P-containing coatings on sandblasted commercially pure titanium by an optimum composite technique to improve the bioactive performance. The effect of sandblasting intensity on microstructures and properties of the implant coatings is examined, and the modified surfaces are characterized in terms of their topography, phase, chemical composition, mechanical properties and hydroxyapatite (HA)-inducing ability. The results show that a moderate sandblasting micromachines the substrate in favorable combination of rough and residual stresses; its MAO coating deposits nano-hydroxyapatite after immersion in simulated body fluid (SBF) for 5 days exhibiting better bioactivity. The further improvement of the implant surface performance is attributed to an optimized composite technique.

Ages and geochemical comparison of coeval plutons and volcanics from the central and eastern Aleutian arc

NASA Astrophysics Data System (ADS)

Cai, Y.; Kelemen, P. B.; Goldstein, S. L.; Yogodzinski, G. M.; Hemming, S. R.; Rioux, M. E.; Cooperdock, E. H. G.

2016-12-01

On average, arc volcanics are compositionally different from the bulk continental crust. The relatively little known plutonic part of intra-oceanic arcs is more similar to continental crust, and may play a significant role for understanding continental crust formation. Our pilot study [1] demonstrated that in the central and eastern Aleutian islands, predominantly tholeiitic Quaternary volcanic rocks have statistically different Pb-Nd-Sr-Hf isotopic signatures than predominantly calc-alkaline Miocene and older plutonic rocks, showing that these plutonics and volcanics were derived from compositionally different sources. However, studies of older volcanics are needed to determine whether (1) there was a change in magma chemistry in the central and eastern Aleutian arc between the Miocene and the present-day, or (2) coeval plutonics and volcanics are compositionally different, and formed by different processes. For example, silica- and water-rich calc-alkaline magmas may preferentially stall and form plutons after extensive degassing and rapid viscosity increase in the mid-crust, while silica- and water-poor tholeiitic magmas tend to erupt at the surface. Here we report new geochronological and geochemical results on samples collected during the 2015 GeoPRISMS shared logistics field campaign. We collected more than 500 volcanic and plutonic samples from Unalaska, Umnak and Atka islands, including pillow lavas, sills, and larger plutons. A subset of 50 samples has been analyzed for major and trace element chemistry, Pb-Nd-Sr-Hf isotopes, and Ar-Ar geochronology. So far,40Ar/39Ar cooling dates measured for the volcanics span a wide range, from zero to 35 Ma, which is comparable to the age distribution of the plutons ( 9 Ma to 39 Ma) from these islands. The forthcoming, combined geochronology and geochemistry of coeval plutonics and volcanics will contribute to our understanding of the connections between arc magmatism and continental crust formation. [1] Cai et al., EPSL, 2015, vol 431, pp. 119-126.

Whole-Brain Radiotherapy With Simultaneous Integrated Boost to Multiple Brain Metastases Using Volumetric Modulated Arc Therapy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lagerwaard, Frank J.; Hoorn, Elles A.P. van der; Verbakel, Wilko

2009-09-01

Purpose: Volumetric modulated arc therapy (RapidArc [RA]; Varian Medical Systems, Palo Alto, CA) allows for the generation of intensity-modulated dose distributions by use of a single gantry rotation. We used RA to plan and deliver whole-brain radiotherapy (WBRT) with a simultaneous integrated boost in patients with multiple brain metastases. Methods and Materials: Composite RA plans were generated for 8 patients, consisting of WBRT (20 Gy in 5 fractions) with an integrated boost, also 20 Gy in 5 fractions, to Brain metastases, and clinically delivered in 3 patients. Summated gross tumor volumes were 1.0 to 37.5 cm{sup 3}. RA plans weremore » measured in a solid water phantom by use of Gafchromic films (International Specialty Products, Wayne, NJ). Results: Composite RA plans could be generated within 1 hour. Two arcs were needed to deliver the mean of 1,600 monitor units with a mean 'beam-on' time of 180 seconds. RA plans showed excellent coverage of planning target volume for WBRT and planning target volume for the boost, with mean volumes receiving at least 95% of the prescribed dose of 100% and 99.8%, respectively. The mean conformity index was 1.36. Composite plans showed much steeper dose gradients outside Brain metastases than plans with a conventional summation of WBRT and radiosurgery. Comparison of calculated and measured doses showed a mean gamma for double-arc plans of 0.30, and the area with a gamma larger than 1 was 2%. In-room times for clinical RA sessions were approximately 20 minutes for each patient. Conclusions: RA treatment planning and delivery of integrated plans of WBRT and boosts to multiple brain metastases is a rapid and accurate technique that has a higher conformity index than conventional summation of WBRT and radiosurgery boost.« less

Spinel-Bearing, Al-Rich Chrondrules in the Unequilibrated Ordinary Chondrite NWA7402

NASA Technical Reports Server (NTRS)

Ross, D. K.; Simon, J. I.; Cato, M. J.

2017-01-01

Several Al-rich chondrules (ARCs) have been discovered in the unequilibrated ordinary chondrite NWA7402. Two of these three ARCs are spinel-bearing. Here we have characterized these unusual chondrules with respect to their mineralogy and bulk compositions. These objects will be targets for future O and Mg isotope analysis. NWA7402 is clearly unequilibrated, with wide ranges of olivine compositions in chondrules (Fo99-Fo70, excluding rims). Chromium-oxide contents in olivine, and Raman organic spectral parameters support the classification of this meteorite as petrologic type 3.1 [1]. NWA7402 is similar to, and could be paired with NWA5717, in that they both possess light and dark lithologies.

Analytical Modeling of Weld Bead Shape in Dry Hyperbaric GMAW Using Ar-He Chamber Gas Mixtures

NASA Astrophysics Data System (ADS)

Azar, Amin S.; Ås, Sigmund K.; Akselsen, Odd M.

2013-03-01

Hyperbaric arc welding is a special application of joining the pipeline steels under seawater. In order to analyze the behavior of the arc under ambient pressure, a model is required to estimate the arc efficiency. A distributed point heat source model was employed. The simulated isotherms were calibrated iteratively to fit the actual bead cross section. Basic gas mixture rules and models were used to calculate the thermal properties of the low-temperature shielding gas under the ambient pressure of 10 bar. Nine bead-on-plate welds were deposited each of which under different Ar-He chamber gas compositions. The well-known correlation between arc efficiency (delivered heat) and the thermal conductivity was established for different gas mixtures. The arc efficiency was considered separately for the transverse and perpendicular heat sources. It was found that assigning single heat efficiency factor for the entire arc, which is usually below unity, causes a noticeable underestimation for the heat transfer in the perpendicular direction and a little overestimation in the transverse direction.

40Ar/39Ar dating and zircon chronochemistry for the Izu-Bonin rear arc, IODP site U1437

NASA Astrophysics Data System (ADS)

Schmitt, A. K.; Konrad, K.; Andrews, G. D.; Horie, K.; Brown, S. R.; Koppers, A. A. P.; Busby, C.; Tamura, Y.

2016-12-01

The scientific objective of IODP Expedition 350 drilling at Site U1437 (31°47.390'N, 139°01.580'E) was to reveal the "missing half of the subduction factory": the rear arc of a long-lived intraoceanic subduction zone. Site U1437 lies in a 50 km long and 20 km wide volcano-bounded basin, 90 km west of the Izu arc front, and is the only IODP site drilled in the rear arc. The Izu rear arc is dominated by Miocene basaltic to dacitic seamount chains, which strike at a high angle to the arc front. Radiometric dating targeted a single igneous unit (1390 mbsf), and fine to coarse volcaniclastic units for which we present zircon and 40Ar/39Ar (hornblende, plagioclase, and groundmass) age determinations. All zircons analyzed as grain separates were screened for contamination from drill-mud (Andrews et al., 2016) by analyzing trace elements and, where material was available, O and Hf isotope compositions. Igneous Unit 1 is a rhyolite sheet and yielded concordant in-situ and crystal separate U-Pb zircon ages (13.7±0.3 Ma; MSWD = 1.3; n = 40 spots), whereas the 40Ar/39Ar hornblende plateau age (12.9±0.3; MSWD = 1.1; n = 9 steps) is slightly younger, possibly reflecting pre-eruptive zircon crystallization, or alteration of hornblende. U-Pb zircon and 40Ar/39Ar plateau ages from samples above igneous Unit 1 are concordant with biostratigraphic and paleomagnetic ages (available to 1300 mbsf), but plagioclase and groundmass samples below 1300 m become younger with depth, hinting at post-depositional alteration. A single zircon from 1600 mbsf yielded a U-Pb age of 15.4±1.8 Ma; its trace element composition resembles other igneous zircons from U1437, and is tentatively interpreted as a Middle Miocene age for the lowermost lithostratigraphic unit VII. Oxygen and Hf isotopic values of igneous zircon indicate mantle origins, with some influence of assimilation of hydrothermally altered oceanic crust evident in sub-mantle oxygen isotopic compositions. Lessons from site U1437 are that integrated chronochemistry is essential for achieving accurate age models in oceanic drilling. Reference: Andrews, G. D., Schmitt, A. K., Busby, C. J., Brown, S. R., Blum, P., & Harvey, J. (2016). Age and compositional data of zircon from sepiolite drilling mud to identify contamination of ocean drilling samples. G3. doi: 10.1002/2016GC006397.

Recycling and transport of continental material through the mantle wedge above subduction zones: A Caribbean example

NASA Astrophysics Data System (ADS)

Rojas-Agramonte, Yamirka; Garcia-Casco, Antonio; Kemp, Anthony; Kröner, Alfred; Proenza, Joaquín A.; Lázaro, Concepción; Liu, Dunyi

2016-02-01

Estimates of global growth rates of continental crust critically depend upon knowledge of the rate at which crustal material is delivered back into the mantle at subduction zones and is then returned to the crust as a component of mantle-derived magma. Quantification of crustal recycling by subduction-related magmatism relies on indirect chemical and isotopic tracers and is hindered by the large range of potential melt sources (e.g., subducted oceanic crust and overlying chemical and clastic sediment, sub-arc lithospheric mantle, arc crust), whose composition may not be accurately known. There is also uncertainty about how crustal material is transferred from subducted lithosphere and mixed into the mantle source of arc magmas. We use the resilient mineral zircon to track crustal recycling in mantle-derived rocks of the Caribbean (Greater Antilles) intra-oceanic arc of Cuba, whose inception was triggered after the break-up of Pangea. Despite juvenile Sr and Nd isotope compositions, the supra-subduction zone ophiolitic and volcanic arc rocks of this Cretaceous (∼135-70 Ma) arc contain old zircons (∼200-2525 Ma) attesting to diverse crustal inputs. The Hf-O isotope systematics of these zircons suggest derivation from exposed crustal terranes in northern Central America (e.g. Mexico) and South America. Modeling of the sedimentary component in the most mafic lavas suggests a contribution of no more than 2% for the case of source contamination or less than 4% for sediment assimilation by the magma. We discuss several possibilities for the presence of inherited zircons and conclude that they were transported as detrital grains into the mantle beneath the Caribbean Plate via subduction of oceanic crust. The detrital zircons were subsequently entrained by mafic melts that were rapidly emplaced into the Caribbean volcanic arc crust and supra-subduction mantle. These findings suggest transport of continental detritus, through the mantle wedge above subduction zones, in magmas that otherwise do not show strong evidence for crustal input and imply that crustal recycling rates in some arcs may be higher than hitherto realized.

Emission spectrometric arcing procedure with minimal effect of chemical form of sample. [performed on refractory metal matrix composites

NASA Technical Reports Server (NTRS)

Gordon, W. A.

1975-01-01

Matrix effects related to the chemical form of analyzed materials were studied. An arc in argon was used which was buffered with silver chloride. The effect of chemical form was minimal for a variety of metals, oxides, and carbides representing the most refractory compounds and thermally stable metal-containing molecules. Only four of the most refractory materials known showed significant emission depressions due to incomplete volatilization in the arc system. These results are discussed in terms of vapor pressures of the solid materials placed on the anodes and dissociation reactions of the molecules in the gaseous environment.

The geochemistry and petrogenesis of the Paleoproterozoic Green Mountain arc: A composite(?), bimodal, oceanic, fringing arc

USGS Publications Warehouse

Jones, D.S.; Barnes, C.G.; Premo, W.R.; Snoke, A.W.

2011-01-01

The inferred subduction affinity of the ~1780-Ma Green Mountain arc, a dominantly bimodal igneous terrane (together with immature marine and volcaniclastic sedimentary rocks) accreted to the southern margin of the Wyoming province, is integral to arc-accretion models of the Paleoproterozoic growth of southern Laurentia. Conversely, the dominantly bimodal nature of many putative arc-related igneous suites throughout southern Laurentia, including the Green Mountain arc, has also been used to support models of growth by extension of pre-existing crust. We report new geochemical and isotopic data from ~1780-Ma gabbroic and granodioritic to tonalitic rocks of the Big Creek Gneiss, interpreted as consanguineous with previously studied metavolcanic rocks of the Green Mountain Formation.The ~1780-Ma Big Creek Gneiss mafic rocks show clear geochemical signatures of a subduction origin and provide no supporting evidence for extensional tectonism. The ~1780-Ma Big Creek Gneiss felsic rocks are attributed to partial melting of mafic and/or mixed lower-crustal material. The bimodal nature of the suite results from the combination of arc basalts and felsic crustal melts. The lack of andesite is consistent with the observed tholeiitic differentiation trend of the mafic magmas. The lower e{open}Nd(1780Ma) values for the felsic rocks vs. the mafic rocks suggest that the unexposed lower crust of the arc may be older than the arc and that Trans-Hudson- or Penokean-aged rocks possibly form the substratum of the arc. Our results reinforce previous interpretations that arc-related magmatism played a key role in the Paleoproterozoic crustal growth of southern Laurentia, but also support the possibility of unexposed older crust as basement to the arcs. ?? 2011 Elsevier B.V.

Seismic anisotropy from compositional banding in granulites from the deep magmatic arc of Fiordland, New Zealand

NASA Astrophysics Data System (ADS)

Cyprych, Daria; Piazolo, Sandra; Almqvist, Bjarne S. G.

2017-11-01

We present calculated seismic velocities and anisotropies of mafic granulites and eclogites from the Cretaceous deep lower crust (∼40-65 km) of Fiordland, New Zealand. Both rock types show a distinct foliation defined by cm-scale compositional banding. Seismic properties are estimated using the Asymptotic Expansion Homogenisation - Finite Element (AEH-FE) method that, unlike the commonly used Voigt-Reuss-Hill homogenisation, incorporates the phase boundary network into calculations. The predicted mean P- and S-wave velocities are consistent with previously published data for similar lithologies from other locations (e.g., Kohistan Arc), although we find higher than expected anisotropies (AVP ∼ 5.0-8.0%, AVS ∼ 3.0-6.5%) and substantial S-wave splitting along foliation planes in granulites. This seismic signature of granulites results from a density and elasticity contrast between cm-scale pyroxene ± garnet stringers and plagioclase matrix rather than from crystallographic orientations alone. Banded eclogites do not show elevated anisotropies as the contrast in density and elastic constants of garnet and pyroxene is too small. The origin of compositional banding in Fiordland granulites is primarily magmatic and structures described here are expected to be typical for the base of present day magmatic arcs. Hence, we identify a new potential source of anisotropy within this geotectonic setting.

Optical enhancing durable anti-reflective coating

DOEpatents

Maghsoodi, Sina; Varadarajan, Aravamuthan; Movassat, Meisam

2016-07-05

Disclosed herein are polysilsesquioxane based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In embodiments, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in the polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, Si--OH condensation catalyst and/or nanofillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes including flow coating and roll coating, and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.

High gain durable anti-reflective coating

DOEpatents

Maghsoodi, Sina; Brophy, Brenor L.; Colson, Thomas E.; Gonsalves, Peter R.; Abrams, Ze'ev R.

2016-07-26

Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si--OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.

Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franz, Robert; Polcik, Peter; Anders, André

The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr 2+ ions were dominating in Ar and N 2 and Cr + in O 2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ionsmore » that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O 2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

DOE PAGES

Franz, Robert; Polcik, Peter; Anders, André

2015-06-01

The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr 2+ ions were dominating in Ar and N 2 and Cr + in O 2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ionsmore » that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O 2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

Episodic construction of the Tatra granitoid intrusion (Central Western Carpathians, Poland/Slovakia): consequences for the geodynamics of Variscan collision and Rheic Ocean closure

NASA Astrophysics Data System (ADS)

Gawęda, Aleksandra; Burda, Jolanta; Klötzli, Urs; Golonka, Jan; Szopa, Krzysztof

2016-06-01

The Tatra granitoid pluton (Central Western Carpathians, Poland/Slovakia) is an example of composite polygenetic intrusion, comprising many magmatic pulses varying compositionally from diorite to granite. The U-Pb LA-MC-ICP-MS zircon dating of successive magma batches indicates the presence of magmatic episodes at 370-368, 365, 360, 355 and 350-340 Ma, all together covering a time span of 30 Ma of magmatic activity. The partial resorption and recycling of former granitoid material ("petrological cannibalism") was a result of the incremental growth of the pluton and temperature in the range of 750-850 °C. The long-lasting granitoid magmatism was connected to the prolonged subduction of oceanic crust and collision of the Proto-Carpathian Terrane with a volcanic arc and finally with Laurussia, closing the Rheic Ocean. The differences in granitoid composition are the results of different depths of crustal melting. More felsic magmas were generated in the outer zone of the volcanic arc, whilst more mafic magmas were formed in the inner part of the supra-subduction zone. The source rocks of the granitoid magmas covered the compositional range of metapelite-amphibolite and were from both lower and upper crust. The presence of the inherited zircon cores suggests that the collision and granitoid magmatism involved crust of Cadomian consolidation age (c. 530 and 518 Ma) forming the Proto-Carpathian Terrane, crust of Avalonian affinity (462, 426 Ma) and melted metasedimentary rocks of volcanic arc provenance.

Influence of Plasma Jet Temperature Profiles in Arc Discharge Methods of Carbon Nanotubes Synthesis

PubMed Central

Raniszewski, Grzegorz; Wiak, Slawomir; Pietrzak, Lukasz; Szymanski, Lukasz; Kolacinski, Zbigniew

2017-01-01

One of the most common methods of carbon nanotubes (CNTs) synthesis is application of an electric-arc plasma. However, the final product in the form of cathode deposit is composed of carbon nanotubes and a variety of carbon impurities. An assay of carbon nanotubes produced in arc discharge systems available on the market shows that commercial cathode deposits contain about 10% CNTs. Given that the quality of the final product depends on carbon–plasma jet parameters, it is possible to increase the yield of the synthesis by plasma jet control. Most of the carbon nanotubes are multiwall carbon nanotubes (MWCNTs). It was observed that the addition of catalysts significantly changes the plasma composition, effective ionization potential, the arc channel conductance, and in effect temperature of the arc and carbon elements flux. This paper focuses on the influence of metal components on plasma-jet forming containing carbon nanotubes cathode deposit. The plasma jet temperature control system is presented. PMID:28336884

Influence of Plasma Jet Temperature Profiles in Arc Discharge Methods of Carbon Nanotubes Synthesis.

PubMed

Raniszewski, Grzegorz; Wiak, Slawomir; Pietrzak, Lukasz; Szymanski, Lukasz; Kolacinski, Zbigniew

2017-02-23

One of the most common methods of carbon nanotubes (CNTs) synthesis is application of an electric-arc plasma. However, the final product in the form of cathode deposit is composed of carbon nanotubes and a variety of carbon impurities. An assay of carbon nanotubes produced in arc discharge systems available on the market shows that commercial cathode deposits contain about 10% CNTs. Given that the quality of the final product depends on carbon-plasma jet parameters, it is possible to increase the yield of the synthesis by plasma jet control. Most of the carbon nanotubes are multiwall carbon nanotubes (MWCNTs). It was observed that the addition of catalysts significantly changes the plasma composition, effective ionization potential, the arc channel conductance, and in effect temperature of the arc and carbon elements flux. This paper focuses on the influence of metal components on plasma-jet forming containing carbon nanotubes cathode deposit. The plasma jet temperature control system is presented.

Spatial and mineralogic variation of Na-Ca alteration in Laramide porphyry systems of Arizona

NASA Astrophysics Data System (ADS)

Runyon, S.; Seedorff, E.; Barton, M. D.; Mazdab, F. K.; Lecumberri-Sanchez, P.; Steele-MacInnis, M.

2017-12-01

Na-Ca alteration is characterized by the metasomatic addition of Ca ± Na and the loss of K. Minor volumes of Na-Ca alteration in Laramide porphyry systems develops from 3 to 8 km paleodepth. Mineral assemblages, mineral compositions, hydrogen isotopes, whole-rock analyses, and reconnaissance fluid inclusion characteristics have been documented for Na-Ca alteration in Laramide porphyry systems such as Tea Cup and Sierrita. Volumetrically minor Na-Ca alteration in Laramide porphyry systems documented in this study commonly takes the form of one of three mineral assemblages: albite-epidote-chlorite, Na-plagioclase-actinolite ± epidote, and garnet- or diopside-stable Na-plagioclase-actinolite ± epidote. These different Na-Ca mineral assemblages have broad spatial relationships, from shallow albite-chlorite-epidote to deeper Na-plagioclase-actinolite within a given district. Hydrogen isotope data on Na-Ca alteration minerals shows consistently distinct δD compositions of Na-Ca alteration minerals compared to igneous minerals in a given district. Further, calculated hydrogen isotope composition of fluids in equilibrium with Na-Ca alteration minerals are consistently enriched in δD compared to magmatic-hydrothermal fluids. Whole-rock analyses show consistent losses of K and variable addition of Na and Ca across different Na-Ca alteration assemblages. Na-Ca alteration has been well documented associated with the Jurassic arc. Previous studies demonstrated through mass balance, timing and spatial relationships, isotopic, and fluid inclusion studies that Na-Ca alteration associated with the Jurassic arc likely formed from the circulation of external, highly saline, non-magmatic fluids (e.g., Battles and Barton, 1995; Dilles et al., 1995). Na-Ca alteration documented in Laramide systems is generally similar to Na-Ca alteration documented along the Jurassic arc in mineral assemblages, compositions, and timing, but the volume of Na-Ca alteration in the Laramide systems is small as compared to the voluminous Na-Ca alteration documented in systems associated with the Jurassic arc.

Isotopic and trace element constraints on the petrogenesis of lavas from the Mount Adams volcanic field, Washington

USGS Publications Warehouse

Jicha, B.R.; Hart, G.L.; Johnson, C.M.; Hildreth, Wes; Beard, B.L.; Shirey, S.B.; Valley, J.W.

2009-01-01

Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources, a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators of slab-fluids such as (Sr/P)n and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. ??18O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal interaction in this juvenile arc, in stark contrast to Os isotopes, which are highly sensitive to interaction with young, mafic material in the lower crust. ?? Springer-Verlag 2008.

Oligocene and Miocene arc volcanism in northeastern California: evidence for post-Eocene segmentation of the subducting Farallon plate

USGS Publications Warehouse

Colgan, J.P.; Egger, A.E.; John, D.A.; Cousens, B.; Fleck, R.J.; Henry, C.D.

2011-01-01

The Warner Range in northeastern California exposes a section of Tertiary rocks over 3 km thick, offering a unique opportunity to study the long-term history of Cascade arc volcanism in an area otherwise covered by younger volcanic rocks. The oldest locally sourced volcanic rocks in the Warner Range are Oligocene (28–24 Ma) and include a sequence of basalt and basaltic andesite lava flows overlain by hornblende and pyroxene andesite pyroclastic flows and minor lava flows. Both sequences vary in thickness (0–2 km) along strike and are inferred to be the erosional remnants of one or more large, partly overlapping composite volcanoes. No volcanic rocks were erupted in the Warner Range between ca. 24 and 16 Ma, although minor distally sourced silicic tuffs were deposited during this time. Arc volcanism resumed ca. 16 Ma with eruption of basalt and basaltic andesite lavas sourced from eruptive centers 5–10 km south of the relict Oligocene centers. Post–16 Ma arc volcanism continued until ca. 8 Ma, forming numerous eroded but well-preserved shield volcanoes to the south of the Warner Range. Oligocene to Late Miocene volcanic rocks in and around the Warner Range are calc-alkaline basalts to andesites (48%–61% SiO2) that display negative Ti, Nb, and Ta anomalies in trace element spider diagrams, consistent with an arc setting. Middle Miocene lavas in the Warner Range are distinctly different in age, composition, and eruptive style from the nearby Steens Basalt, with which they were previously correlated. Middle to Late Miocene shield volcanoes south of the Warner Range consist of homogeneous basaltic andesites (53%–57% SiO2) that are compositionally similar to Oligocene rocks in the Warner Range. They are distinctly different from younger (Late Miocene to Pliocene) high-Al, low-K olivine tholeiites, which are more mafic (46%–49% SiO2), did not build large edifices, and are thought to be related to backarc extension. The Warner Range is ∼100 km east of the axis of the modern arc in northeastern California, suggesting that the Cascade arc south of modern Mount Shasta migrated west during the Late Miocene and Pliocene, while the arc north of Mount Shasta remained in essentially the same position. We interpret these patterns as evidence for an Eocene to Miocene tear in the subducting slab, with a more steeply dipping plate segment to the north, and an initially more gently dipping segment to the south that gradually steepened from the Middle Miocene to the present.

Halogen content in Lesser Antilles arc volcanic rocks : exploring subduction recycling

NASA Astrophysics Data System (ADS)

Thierry, Pauline; Villemant, Benoit; Caron, Benoit

2016-04-01

Halogens (F, Cl, Br and I) are strongly reactive volatile elements which can be used as tracers of igneous processes, through mantle melting, magma differentiation and degassing or crustal material recycling into mantle at subduction zones. Cl, Br and I are higly incompatible during partial melting or fractional cristallization and strongly depleted in melts by H2O degassing, which means that no Cl-Br-I fractionation is expected through magmatic differenciation [current thesis]. Thus, Cl/Br/I ratios in lavas reflect the halogen content of their mantle sources. Whereas these ratios seemed quite constant (e.g. Cl/Br =300 as seawater), recent works suggest significant variations in arc volcanism [1,2]. In this work we provide high-precision halogen measurements in volcanic rocks from the recent activity of the Lesser Antilles arc (Montserrat, Martinique, Guadeloupe, Dominique). Halogen contents of powdered samples were determined through extraction in solution by pyrohydrolysis and analysed by Ion Chromatography for F and Cl and high performance ICP-MS (Agilent 8800 Tripe Quad) for Cl, Br and I [3,4]. We show that lavas - and mantle sources - display significant vraiations in Cl/Br/I ratios along the Lesser Antilles arc. These variations are compared with Pb, Nd and Sr isotopes and fluid-mobile elements (Ba, U, Sr, Pb etc.) compositions which vary along the arc from a nothern ordinary arc compositions to a southern 'crustal-like' composition [5,6]. These characteristics are attributed to subducted sediments recycling into the mantle wedge, whose contribution vary along the arc from north to south [7,8]. The proportion of added sediments is also related to the distance to the trench as sediment melting and slab dehydration may occur depending on the slab depth [9]. Further Cl-Br-I in situ measurements by LA-ICP-MS in Lesser Antilles arc lavas melt inclusions will be performed, in order to provide better constraints on the deep halogen recycling cycle from crust to mantle. 1. Villemant, B., Mouatt, J. & Michel, A., 2008. Earth Planet. Sci. Lett. 269(1), 212-229. 2. Kutterolf, S. et al., 2015. Earth Planet. Sci. Lett. 429, 234-246. 3. Michel, A. & Villemant, B., 2003. Geostand. Geoanalytical Res. 27(2), 163-171. 4. Balcone-Boissard, H., Michel, A. & Villemant, B., 2009. Geostand. Geoanalytical Res. 33(4), 477-485. 5. White, W. M. & Dupré, B., 1986. J. Geophys. Res. 91(B6), 5927. 6. Labanieh, S. et al., 2010. Earth Planet. Sci. Lett. 298(1-2), 35-46. 7. Turner, S. et al., 1996. Earth Planet. Sci. Lett. 142(1-2), 191-207. 8. Carpentier, M., Chauvel, C. & Mattielli, N., 2008. Earth Planet. Sci. Lett. 272(1-2), 199-211. 9. Labanieh, S. et al., 2012. J. Petrol. 53(12), 2441-2464.

The electrical discharge machining of ceramics

NASA Astrophysics Data System (ADS)

Trueman, Christopher Stuart

This study introduces the concept of developing a novel and rapid rough-machining methodology for spark eroding suitable ceramic compositions based on material removal by thermal shock induced spalling, as opposed to conventional melting mechanisms. The principal materials studied were TiB2 dispersion toughened SiC, and Syalon501 - a commercially available TiN toughened sialon ceramic specifically designed for spark erosion. A preliminary study was also carried out on a range of SiC:B4C composites. Machinability and material performance were assessed where appropriate using machining parameters, material removal rate tests, surface analysis, four-point flexure testing, and tool wear. The machining technologies which supported the different mechanisms of material removal were identified, and each mechanism investigated by analysis of captured debris and sectioning of the workpiece. The SiC:B4C composites were found to be spark erodible only with B4C levels above 50% (by mass), and material removal was found to be solely by melting mechanisms. A SiC:TiB2 composition with the addition of 26.5% TiB2 (by mass) was found to be more machinable than a composition with 10% TiB2 (by mass), achieving greater material removal rates owing to its higher electrical conductivity. An in-depth study of the latter (10%TiB2) SiC composition and Syalon501 revealed surprisingly robust materials. Under conventional sparking (no arcing), material was removed by combined dissociation, melting and evaporation. Syalon501 in particular behaved with a high degree of predictability, and neither material could be made to spall under conventional sparking. However, by imposing conditions which deliberately induced arcing, both compositions spalled large flakes of material (up to several hundred microns across) in the localised region of the arc-strike. Examination of captured debris and fracture facets of the spall interface revealed the existence of small "penny cracks", each characterised by the presence of a dispersed particle (of greater thermal expansion) at its centre acting as a stress- raising nucleation point under the intense thermal loading of arcing. Sub-surface cracks in the near horizontal and near-vertical planes were discovered in line with published models based on the application of a hot-spot to brittle material, and evidence of discrete crack propagation under the thermally punctuated pulses of successive sparking was identified. Similar sub-surface cracking was also confirmed in Syalon501 which had been subjected to arcing. Sectioning of the workpiece revealed shallow sub-surface cracks which followed the profile of the machined surface in the near-horizontal plane, and which often limited the extent of near-vertical cracking to the layer of material above the crack, thereby offering the potential for a reliable and fast "planning" technique in which material would be removed in shallow layers. This research has shown that the possibility exists for increased material removal rates and improved process efficiency under a spalling-based machining regime, in which layers of material are released by thermal-shock induced fracture caused by arcing. The viability of developing a new rough-machining technology for ceramics, in which material is "planed" away prior to fine surface finishing by conventional spark erosion has, therefore, been successfully demonstrated.

Regional framework and geology of iron oxide-apatite-rare earth element and iron oxide-copper-gold deposits of the Mesoproterozoic St. Francois Mountains Terrane, southeast Missouri

USGS Publications Warehouse

Day, Warren C.; Slack, John F.; Ayuso, Robert A.; Seeger, Cheryl M.

2016-01-01

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.The Missouri iron orebodies are magmatic-related hydrothermal deposits that, when considered in aggregate, display a vertical zonation from high-temperature, magmatic ± hydrothermal IOA deposits emplaced at moderate depths (~1–2 km), to magnetite-dominant IOA veins and IOCG deposits emplaced at shallow subvolcanic depths. The shallowest parts of these systems include near-surface, iron oxide-only replacement deposits, surficial epithermal sediment-hosted replacement deposits, synsedimentary ironstone deposits, and Mn-rich exhalite deposits. Alteration associated with the IOA and IOCG mineralizing systems of the host volcanic rocks dominantly produced potassic with lesser amounts of calcic- and sodic-rich mineral assemblages. No deposits are known to be hosted in granite, implying that the mineralizing systems were operative during a relatively short, postvolcanic period yet prior to intrusion of the granitoids.Companion studies in this special issue on mineral chemistry, stable isotopes, and iron isotopes suggest that the magnetite within the IOA deposits formed from high-temperature fluids of magmatic or magmatic-hydrothermal origin. However, the data do not discriminate between a magmatic-hydrothermal source fluid exsolved from an Fe-rich immiscible liquid or an Fe-rich silicate magma. Mineral chemical, fluid inclusion, and stable isotope data from these new studies record the effects of metasomatic fluids that interacted with crustal reservoirs such as volcanic rocks or seawater.

Boron Isotope Evidence for Shallow Fluid Transfer Across Subduction Zones by Serpentinized Mantle

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Tonarini, S.; Agostini, S.; Cannaò, E.

2012-12-01

Boron Isotope Evidence for Shallow Fluid Transfer Across Subduction Zones by Serpentinized Mantle M. Scambelluri (1), S. Tonarini (2), S. Agostini (2), E. Cannaò (1) (1) Dipartimento di Scienze della Terra, Ambiente e vita, University of Genova, Italy (2) Istituto di Geoscienze e Georisorse-CNR, Pisa, Italy In subduction zones, fluid-mediated chemical exchange between slabs and mantle dictates volatile and incompatible element cycles and influences arc magmatism. Outstanding issues concern the sources of water for arc magmas and its slab-to-mantle wedge transport. Does it occur by slab dehydration beneath arc fronts, or by hydration of fore-arc mantle and subsequent subduction of the hydrated mantle? So far, the deep slab dehydration hypothesis had strong support, but the hydrated mantle wedge idea is advancing supported by studies of fluid-mobile elements in serpentinized wedge peridotites and their subducted high-pressure (HP) equivalents. Serpentinites are volatile and fluid-mobile element reservoirs for subduction: their dehydration causes large fluid and element flux to the mantle.However, direct evidence for their key role in arc magmatism and identification of dehydration environments has been elusive and boron isotopes can trace the process. Until recently, the altered oceanic crust (AOC) was considered the 11B reservoir for arcs, which largely display positive δ11B. However, shallow slab dehydration transfers 11B to the fore-arc mantle and leaves the residual AOC very depleted in 11B below arcs. Here we present high positive δ11B of HP serpentinized peridotites from Erro Tobbio (Ligurian Alps), recording subduction metamorphism from hydration at low-grade to eclogite-facies dehydration. We show a connection among serpentinite dehydration, release of 11B-rich fluids and arc magmatism. The dataset is completed by B isotope data on other HP Alpine serpentinites from Liguria and Lanzo Massif. In general, the δ11B of these rocks is heavy (16 to + 30 permil). No significant B loss and 11B fractionation occurs with burial. Their B and 11B abundance shows that high budgets acquired during shallow hydration are transferred to HP fluids, providing the heavy-boron component requested for arcs. The B compositions of Erro-Tobbio are unexpected for slabs, deputed to loose B and 11B during dehydration: its isotopic composition can be achieved diluting in the mantle shallow subduction-fluids (30 km). The serpentinizing fluids and the fluid-transfer mechanism in Erro-Tobbio are clarified integrating B with O-H and Sr isotopes. Low δD (-102permil), high δ18O (8permil) of early serpentinites suggest low-temperature hydration by metamorphic fluids. 87Sr/86Sr (0.7044 to 0.7065) is lower than oceanic serpentinites formed from seawater. We conclude that alteration was distant from mid-ocean ridges and occurred at the slab-mantle interface or in forearc environments. We thus provide evidence for delivery of water and 11B at sub-arcs by serpentinized mantle altered by subduction-fluid infiltration atop of the slab since the early stages of burial, witnessing shallow fluid transfer across the subduction zone. Similarity of the B composition of Erro Tobbio with other Alpine serpentinized peridotites suggests that these materials might have spent much of their subduction lifetime at the plate interface, fed by B and 11Bich fluids uprising from the slab.

High-Ca Boninites From the Modern Tonga Arc

NASA Astrophysics Data System (ADS)

Cooper, L. B.; Plank, T.; Arculus, R. J.; Hauri, E. H.; Worthington, T. J.

2007-12-01

High-Ca boninites are volcanic rocks with unusual compositions (SiO2>53 wt%, Mg#>0.6, CaO/Al2O3>0.75) found in forearcs and trenches, continental cratons, and ophiolites. Generation of high-Ca boninites requires a combination of refractory mantle sources, elevated mantle temperatures and the addition of hydrous fluids. To satisfy these conditions, petrogenetic models invoke unusual tectonic settings such as subduction initiation, ridge subduction, or mantle plume interaction. We have discovered high-Ca boninites from an active arc volcano, Volcano A, a submarine volcano in the Tonga arc dredged during the NoToVE cruise in Nov 2004. Multi-beam sonar images of two pristine volcanic cones and glassy samples lacking Mn coatings suggest that these edifices were formed by modern volcanism. The boninites are represented in both the whole rock and melt inclusion populations of a sample dredged from a ridge on the northern flank of the northern cone. Similarities in the major element compositions of the largely aphyric whole rock and the glassy melt inclusions support both as samples of true boninitic liquids (MgO>9 wt%). These liquids are related by coupled crystal fractionation (from Fo92 to Fo85 in olivine hosts) and degassing (from 4 to 1 wt% H2O in the melt inclusions). Three other dredges from Volc A include whole rocks, glass, and melt inclusions that are related to the boninites by crystal fractionation. Taken together, the samples from Volc A represent a suite of boninites and their differentiates, forming a coherent liquid line of descent with parallel whole rock REE patterns which become more enriched with decreasing Mg#. The REE patterns for Volc A whole rocks are depleted in LREE, however, in contrast to the characteristic U-shaped REE patterns of classic boninites. Volc A is only the second example of boninites being erupted in an active volcanic arc, the first being Bamus volcano in New Britain (Johnson et al., Geol. Rund., 1983). Volc A is not remarkable in its geographical setting, located in the central portion of the Tonga arc, at around 21°S, along-strike with the arc island of Hunga- Ha'apai, and east of the Eastern Lau Spreading Center. Although it contains volcanic rocks with the highest Ba/La (100-130), Si6.00 (56 wt%) and lowest Ti6.00 (0.44 wt%) in the Tonga arc, Volc A forms an end- member within a continuous spectrum of compositions, and much of the Tonga arc appears to have boninite- affinities. Of the three conditions that promote boninite production (mantle depletion, high mantle temperatures, and high mantle water contents), we can exclude mantle temperature as the primary cause of Volc A boninites. Olivine-liquid temperatures are 1348±13°C for Volc A liquids, calculated in equilibrium with Fo92 mantle olivine at 2 GPa (using thermometers in Sisson & Grove, CMP, 1993; Sugawara, JGR, 2000). Such temperatures are very similar to those calculated for Central American arc volcanoes (1315-1320°C; Plank et al., this meeting) where magmas with similar water contents erupt, but boninites do not. Volc A olivine-liquid temperatures also contrast with those recorded in the high-Ca boninites found in the Tonga forearc (~1480°C; Falloon and Danyushevsky, JPet, 2000). Thus, we attribute the presence of boninites in the Tonga arc to the remelting of refractory mantle that melted previously during rapid back-arc spreading in the nearby Lau Basin.

Diversity and Petrogenesis of <4.4 Ma Rhyolites from the Izu Bonin Rear-Arc

NASA Astrophysics Data System (ADS)

Heywood, L. J.; DeBari, S. M.; Schindlbeck, J. C.; Escobar-Burciaga, R. D.; Gill, J.

2016-12-01

The Izu Bonin subduction zone has a history of abundant rhyolite production that is relevant to the development of intermediate to silicic middle crust. This study presents major and trace elemental compositions (via electron microprobe and LA-ICP-MS) of unaltered volcanic glass and phenocrysts from select medium- to high-K tephra intervals from IODP Site 1437 (Expedition 350, Izu Bonin Rear Arc). These data provide a time-resolved record of regional explosive magmatism ( 4.4Ma to present). Tephra from Site 1437 is basaltic to rhyolitic glass with accompanying phenocrysts, including hornblende. Glass compositions form a medium-K magmatic series with LREE enrichment (LaN/YbN = 2.5-6) whose trace element ratios and isotopic compositions are distinct from magmas with similar SiO2 contents in the main Izu Bonin volcanic front. Other workers have shown progressive enrichment in K and other trace element ratios moving from volcanic front westwards through the extensional region to the western seamounts in the rear arc. The <4.4 Ma rear-arc rhyolites from Site 1437 show pronounced negative Eu anomalies, high LaN/SmN (2-3.5), Ba/La <25 and Th of 1.5-4 ppm. These rhyolites show the highest variability for a given SiO2 content among all rear-arc magmas (rhyolites have 1.5-3.5 wt% K2O, Zr/Y of 1-8, LaN of 5-9 ppm) consistent with variability in literature reports of other rhyolite samples dredged from surrounding seamounts. Rhyolites have been dredged from several nearby seamounts with other high-K rhyolites dredged as close as nearby Meireki Seamount ( 3.8 Ma) and further afield in the Genroku seamount chain ( 1.88 Ma), which we compare to Site 1437 rhyolites. An extremely low-K rhyolite sill (13.6 Ma) was drilled lower in the section at Site U1437, suggesting that the mechanism for producing rhyolites in the Western Seamounts region changed over time. Rhyolites are either produced by differentiation of mafic magmas, by melting of pre-existing arc crust (as hypothesized in the Izu Bonin volcanic front), or through a combination of various processes. Because the oldest rear-arc rhyolites are low-K with limited LREE enrichment, any scenario that requires melting of pre-existing crust to produce the 4.4 Ma high-K rhyolites would require a crustal source that is younger than 13.6 Ma.

Large volume submarine ignimbrites in the Shikoku Basin: An example for explosive volcanism in the Western Pacific during the Late Miocene

NASA Astrophysics Data System (ADS)

Kutterolf, Steffen; Schindlbeck, Julie C.; Scudder, Rachel P.; Murray, Richard W.; Pickering, Kevin T.; Freundt, Armin; Labanieh, Shasa; Heydolph, Ken; Saito, Sanny; Naruse, Hajime; Underwood, Michael B.; Wu, Huaichun

2014-05-01

IODP Expedition 322, an interval of Late Miocene (7.6 to ˜9.1 Ma) tuffaceous and volcaniclastic sandstones was discovered in the Shikoku Basin (Site C0011B), Nankai region. This interval consists of bioturbated silty claystone including four 1-7 m thick interbeds of tuffaceous sandstones (TST) containing 57-82% (by volume) pyroclasts. We use major and trace element glass compositions, as well as radiogenic isotope compositions, to show that the tuffaceous sandstones beds derived from single eruptive events, and that the majority (TST 1, 2, 3a) came from different eruptions from a similar source region, which we have identified to be the Japanese mainland, 350 km away. In particular, diagnostic trace element ratios (e.g., Th/La, Sm/La, Rb/Hf, Th/Nb, and U/Th) and isotopic data indicate a marked contribution from a mantle source beneath continental crust, which is most consistent with a Japanese mainland source and likely excludes the Izu-Bonin island arc and back arc as a source region for the younger TST beds. Nevertheless, some of the chemical data measured on the oldest sandstone bed (TST 3b, Unit IIb) show affinity to or can clearly be attributed to an Izu-Bonin composition. While we cannot completely exclude the possibility that all TST beds derived from unknown and exotic Izu-Bonin source(s), the collected lines of evidence are most consistent with an origin from the paleo-Honshu arc for TST 1 through 3a. We therefore suggest the former collision zone between the Izu-Bonin arc and Honshu paleo-arc as the most likely region where the eruptive products entered the ocean, also concurrent with nearby (˜200 km) possible Miocene source areas for the tuffaceous sandstones at the paleo-NE-Honshu arc. Estimating the distribution area of the tuffaceous sandstones in the Miocene between this source region and the ˜350 km distant Expedition 322, using bathymetric constraints, we calculate that the sandstone beds represent minimum erupted magma volumes between ˜1 and 17 km3 (Dense Rock Equivalent (DRE)). We conclude that several large volume eruptions occurred during the Late Miocene time next to the collision zone of paleo-Honshu and Izu-Bonin arc and covered the entire Philippine Sea plate with meter thick, sheet-like pyroclastic deposits that are now subducted in the Nankai subduction zone.

Across-arc geochemical variations in the Southern Volcanic Zone, Chile (34.5-38.0°S): Constraints on mantle wedge and slab input compositions

NASA Astrophysics Data System (ADS)

Jacques, G.; Hoernle, K.; Gill, J.; Hauff, F.; Wehrmann, H.; Garbe-Schönberg, D.; van den Bogaard, P.; Bindeman, I.; Lara, L. E.

2013-12-01

Crustal assimilation (e.g. Hildreth and Moorbath, 1988) and/or subduction erosion (e.g. Stern, 1991; Kay et al., 2005) are believed to control the geochemical variations along the northern portion of the Chilean Southern Volcanic Zone. In order to evaluate these hypotheses, we present a comprehensive geochemical data set (major and trace elements and O-Sr-Nd-Hf-Pb isotopes) from Holocene primarily olivine-bearing volcanic rocks across the arc between 34.5°S and 38.0°S, including volcanic front centers from Tinguiririca to Callaqui, the rear arc centers of Infernillo Volcanic Field, Laguna del Maule and Copahue, and extending 300 km into the backarc. We also present an equivalent data set for Chile trench sediments outboard of this profile. The volcanic arc (including volcanic front and rear arc) samples primarily range from basalt to andesite/trachyandesite, whereas the backarc rocks are low-silica alkali basalts and trachybasalts. All samples show some characteristic subduction zone trace element enrichments and depletions, but the backarc samples show the least. Backarc basalts have higher Ce/Pb, Nb/U, Nb/Zr, and Ta/Hf, and lower Ba/Nb and Ba/La, consistent with less of a slab-derived component in the backarc and, consequently, lower degrees of mantle melting. The mantle-like δ18O in olivine and plagioclase phenocrysts (volcanic arc = 4.9-5.6‰ and backarc = 5.0-5.4‰) and lack of correlation between δ18O and indices of differentiation and other isotope ratios, argue against significant crustal assimilation. Volcanic arc and backarc samples almost completely overlap in Sr and Nd isotopic composition. High precision (double-spike) Pb isotope ratios are tightly correlated, precluding significant assimilation of older sialic crust but indicating mixing between a South Atlantic Mid Ocean-Ridge Basalt (MORB) source and a slab component derived from subducted sediments and altered oceanic crust. Hf-Nd isotope ratios define separate linear arrays for the volcanic arc and backarc, neither of which trend toward subducting sediment, possibly reflecting a primarily asthenospheric mantle array for the volcanic arc and involvement of enriched Proterozoic lithospheric mantle in the backarc. We propose a quantitative mixing model between a mixed-source, slab-derived melt and a heterogeneous mantle beneath the volcanic arc. The model is consistent with local geodynamic parameters, assuming water-saturated conditions within the slab.

Bone density, body composition, and psychopathology of anorexia nervosa spectrum disorders in DSM-IV vs DSM-5.

PubMed

Schorr, Melanie; Thomas, Jennifer J; Eddy, Kamryn T; Dichtel, Laura E; Lawson, Elizabeth A; Meenaghan, Erinne; Lederfine Paskal, Margaret; Fazeli, Pouneh K; Faje, Alexander T; Misra, Madhusmita; Klibanski, Anne; Miller, Karen K

2017-04-01

DSM-5 revised the diagnostic criteria for anorexia nervosa (AN) by eliminating the amenorrhea requirement, liberalizing weight and psychological criteria, and adding the formal diagnosis of "atypical AN" for individuals with AN psychological symptoms without low weight. We sought to determine whether bone density (BMD) is impaired in women diagnosed with AN using the new, more liberal, DSM-5 criteria. Cross-sectional study of 168 women, 18 - 45y: (1) AN by DSM-IV (DSM-IV AN) (n = 37), (2) AN by DSM-5 but not DSM-IV criteria (DSM-5 AN) (n = 33), (3) atypical AN (ATYPICAL AN) (n = 77), (4) healthy comparison group (HC) (n = 21). Measurements included dual energy X-ray absorptiometry, Eating Disorder Examination-Questionnaire, Eating Disorder Inventory-2, Hamilton Depression and Anxiety Rating Scales. BMD Z-score <-1.0 was present in 78% of DSM-IV, 82% of DSM-5, and 69% of ATYPICAL. Mean Z-scores were comparably low in DSM-IV and DSM-5, intermediate in ATYPICAL, and highest in HC. Lack of prior low weight or amenorrhea was, but history of overweight/obesity was not, protective against bone loss. Mean lean mass and percent fat mass were significantly lower in all AN groups than HC. DSM-IV, DSM-5, and ATYPICAL had comparable psychopathology. Despite liberalizing diagnostic criteria, many women diagnosed with AN and atypical AN using DSM-5 criteria have low BMD. Presence or history of low weight and/or amenorrhea remain important indications for DXA. Loss of lean mass, in addition to fat mass, is present in all AN groups, and may contribute to low BMD. The deleterious effect of eating disorders on BMD extends beyond those with current low weight and amenorrhea. © 2016 Wiley Periodicals, Inc.(Int J Eat Disord 2017; 50:343-351). © 2016 Wiley Periodicals, Inc.

Geologic field-trip guide to Medicine Lake Volcano, northern California, including Lava Beds National Monument

USGS Publications Warehouse

Donnelly-Nolan, Julie M.; Grove, Timothy L.

2017-08-17

Medicine Lake volcano is among the very best places in the United States to see and walk on a variety of well-exposed young lava flows that range in composition from basalt to rhyolite. This field-trip guide to the volcano and to Lava Beds National Monument, which occupies part of the north flank, directs visitors to a wide range of lava flow compositions and volcanic phenomena, many of them well exposed and Holocene in age. The writing of the guide was prompted by a field trip to the California Cascades Arc organized in conjunction with the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) quadrennial meeting in Portland, Oregon, in August of 2017. This report is one of a group of three guides describing the three major volcanic centers of the southern Cascades Volcanic Arc. The guides describing the Mount Shasta and Lassen Volcanic Center parts of the trip share an introduction, written as an overview to the IAVCEI field trip. However, this guide to Medicine Lake volcano has descriptions of many more stops than are included in the 2017 field trip. The 23 stops described here feature a range of compositions and volcanic phenomena. Many other stops are possible and some have been previously described, but these 23 have been selected to highlight the variety of volcanic phenomena at this rear-arc center, the range of compositions, and for the practical reason that they are readily accessible. Open ground cracks, various vent features, tuffs, lava-tube caves, evidence for glaciation, and lava flows that contain inclusions and show visible evidence of compositional zonation are described and visited along the route.

The Boring Volcanic Field of the Portland-Vancouver area, Oregon and Washington: tectonically anomalous forearc volcanism in an urban setting

USGS Publications Warehouse

Evarts, Russell C.; Conrey, Richard M.; Fleck, Robert J.; Hagstrum, Jonathan T.; O'Connor, Jim; Dorsey, Rebecca; Madin, Ian P.

2009-01-01

More than 80 small volcanoes are scattered throughout the Portland-Vancouver metropolitan area of northwestern Oregon and southwestern Washington. These volcanoes constitute the Boring Volcanic Field, which is centered in the Neogene Portland Basin and merges to the east with coeval volcanic centers of the High Cascade volcanic arc. Although the character of volcanic activity is typical of many monogenetic volcanic fields, its tectonic setting is not, being located in the forearc of the Cascadia subduction system well trenchward of the volcanic-arc axis. The history and petrology of this anomalous volcanic field have been elucidated by a comprehensive program of geologic mapping, geochemistry, 40Ar/39Ar geochronology, and paleomag-netic studies. Volcanism began at 2.6 Ma with eruption of low-K tholeiite and related lavas in the southern part of the Portland Basin. At 1.6 Ma, following a hiatus of ~0.8 m.y., similar lavas erupted a few kilometers to the north, after which volcanism became widely dispersed, compositionally variable, and more or less continuous, with an average recurrence interval of 15,000 yr. The youngest centers, 50–130 ka, are found in the northern part of the field. Boring centers are generally monogenetic and mafic but a few larger edifices, ranging from basalt to low-SiO2 andesite, were also constructed. Low-K to high-K calc-alkaline compositions similar to those of the nearby volcanic arc dominate the field, but many centers erupted magmas that exhibit little influence of fluids derived from the subducting slab. The timing and compositional characteristics of Boring volcanism suggest a genetic relationship with late Neogene intra-arc rifting.

Across and along arc geochemical variations in altered volcanic rocks: Evidence from mineral chemistry of Jurassic lavas in northern Chile, and tectonic implications

NASA Astrophysics Data System (ADS)

Rossel, Pablo; Oliveros, Verónica; Ducea, Mihai N.; Hernandez, Laura

2015-12-01

Postmagmatic processes mask the original whole-rock chemistry of most Mesozoic igneous rocks from the Andean arc and back-arc units preserved in Chile. Mineral assemblages corresponding to subgreenschist metamorphic facies and/or propylitic hydrothermal alteration are ubiquitous in volcanic and plutonic rocks, suggesting element mobility at macroscopic and microscopic scale. However, fresh primary phenocrysts of clinopyroxene and plagioclase do occur in some of the altered rocks. We use major and trace element chemistry of such mineral phases to infer the geochemical variations of four Jurassic arc and four back-arc units from northern Chile. Clinopyroxene belonging to rocks of the main arc and two units of the bark-arc are augites with low contents of HFSE and REE; they originated from melting of an asthenospheric mantle source. Clinopyroxenes from a third back-arc unit show typical OIB affinities, with high Ti and trace element contents and low Si. Trace elemental variations in clinopyroxenes from these arc and back-arc units suggest that olivine and clinopyroxene were the main fractionating phases during early stages of magma evolution. The last back-arc unit shows a broad spectrum of clinopyroxene compositions that includes depleted arc-like augite, high Al and high Sr-Ca diopside (adakite-like signature). The origin of these lavas is the result of melting of a mixture of depleted mantle plus Sr-rich sediments and subsequent high pressure fractionation of garnet. Thermobarometric calculations suggest that the Jurassic arc and back-arc magmatism had at least one crustal stagnation level where crystallization and fractionation took place, located at ca. ~ 8-15 km. The depth of this stagnation level is consistent with lower-middle crust boundary in extensional settings. Crystallization conditions calculated for high Al diopsides suggest a deeper stagnation level that is not consistent with a thinned back-arc continental crust. Thus minor garnet fractionation occurred before these magmas reached the base of the crust. The presented data support the existence of a heterogeneous sub arc mantle and complex magmatic processes in the early stages of the Andean subduction.

Geochemical constraints on genesis of Paleoproterozoic A-type granite in the south margin of North China Craton

NASA Astrophysics Data System (ADS)

Xue, Shuo; Xu, Yang; Ling, Ming-Xing; Kang, Qing-Qing; Jiang, Xiao-Yan; Sun, Sai-Jun; Wu, Kai; Zhang, Zhe-Kun; Luo, Ze-Bin; Liu, Yu-Long; Sun, Weidong

2018-04-01

Paleoproterozoic A-type granites are widely outcropped in the North China Craton (NCC), particularly in the Trans-North China Orogen. However, their genesis and tectonic significance remain obscure. Here we report systematic studies on geochronology and geochemical characteristics of A-type granite in Huayangchuan, south margin of the NCC. The samples are enriched in total alkali (K2O + Na2O > 8.97 wt%), and depleted in MgO (0.84-0.93 wt%), CaO (1.28-1.90 wt%) and P2O5 (0.18-0.20 wt%), with high FeOT/MgO (5.69-6.67). They are characterized by high Zr + Y + Nb + Ce values (1293-1392 ppm) and 10,000 × Ga/Al ratios (3.14-3.35), which are typical characteristics of A-type granite. The Huayangchuan A-type granite can be further classified as A1-type subgroup based on particular geochemical features, e.g., low Y/Nb (0.87-1.00) and Yb/Ta (0.88-1.10). High precision zircon U-Pb dating of the A-type granite by secondary ion mass spectrometry (SIMS) yields Paleoproterozoic 207Pb/206Pb ages of 1829.5 ± 2.5 Ma. The low zircon ɛHf(t) values (-6.97 to -10.45), along with zircon Hf model age of 2.7-2.9 Ga, indicate that the Huayangchuan A-type granite was derived from partial melting of the ancient continental crust with contribution of enriched mantle components. The low zircon δ18O composition (4.00 to 6.78‰) indicates that the zircons were crystallized from low δ18O magmas, which derived from the crust metasomatized by low δ18O mantle fluids or melts. The E-W trend A1-type granitic plutons in the NCC are generally outcropped in a rift tectonic regime, which is consistent with the development of the mantle plume in the Xiong'er district. The large volume of basaltic magmas, generated by mantle plume head, underplated the lower continental crust and formed the Huayangchuan A-type granite.

The geochemistry of oils and gases from the Cumberland overthrust sheet in Virginia and Tennessee: Chapter G.12 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Dennen, Kristen O.; Deering, Mark; Burruss, Robert A.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

This study presents high-resolution gas chromatograms of oils and molecular and isotopic analyses of oil-associated gases from 17 wells producing in the Upper Cambrian to Lower Ordovician Knox Group, the Middle and Upper Ordovician Stones River Group, and the Upper Ordovician Trenton Limestone in the Cumberland overthrust sheet. The wells are located in the Ben Hur and Rose Hill fields in Lee County, Va., and in the Swan Creek field in Hancock and Claiborne Counties, Tenn. They produce oils typical of those from source rocks that are rich in Gloeocapsomorpha prisca (G. prisca) (Assemblage A-type kerogen). The Rose Hill oils appear to come from a source that contains a higher proportion of Assemblage A-type kerogen than the Ben Hur and Swan Creek oils. Extrapolation of the δ13C compositions of oil-associated gases to possible kerogen compositions gives estimates of -23 to -24 per mil within the range of isotopic compositions of known G. prisca source material. Gases produced from the Knox Group wells in the Swan Creek field are different from those in the Middle and Upper Ordovician reservoirs and come from a source with a broader range of isotopic values. Trends in isotopic and gasoline-range compositional parameters of the oils and associated gas isotopic and molecular compositions are most likely influenced by changes in local source depositional facies.

Vegetation community composition in wetlands created following oil sand mining in Alberta, Canada.

PubMed

Roy, Marie-Claude; Foote, Lee; Ciborowski, Jan J H

2016-05-01

Reclaiming wetlands following open pit mining for industrial oil sand extraction is challenging due to the physical and chemical conditions of the post-mined landscape. The aim of our study was to examine and compare the influence of oil sands process water (OSPW) and material (fine fluid tails or FFT) on the plant community composition of created wetlands. Compared to created-unamended and natural wetlands, the created wetlands amended with OSPW and/or FFT (created-tailings wetlands) had significantly higher water salinity, conductivity, dissolved oxygen concentration and lower oxidative-reductive potential. Water chemistry parameters of created-unamended did not differ significantly from those of natural wetlands. The sediment of created wetlands had significantly less moisture, total nitrogen, and organic content than the natural wetlands. The application of OSPW/FFT in created wetlands will likely lead to initial vegetation composition atypical of natural regional wetlands. For the objective of reclaiming vegetation composition to the status of natural regional wetlands, unamended wetlands were the best reclamation option, based on the physical and chemical parameters measured. Despite being the favored reclamation option, created-unamended wetlands' physical and chemical characteristics remain atypical of natural wetlands. Most significantly, the basin morphometry of created wetlands was significantly different from that of naturally-formed wetlands in the region, and this appears to partly explain difference in vegetation composition. We also demonstrate that species richness alone is not a useful measure in wetland monitoring. Instead, plant community composition is a better indicator of wetland conditions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Profiles of observed infant anger predict preschool behavior problems: Moderation by life stress

PubMed Central

Brooker, Rebecca J.; Buss, Kristin A.; Lemery-Chalfant, Kathryn; Aksan, Nazan; Davidson, Richard J.; Goldsmith, H. Hill

2014-01-01

Using both traditional composites and novel profiles of anger, we examined associations between infant anger and preschool behavior problems in a large, longitudinal data set (N = 966). We also tested the role of life stress as a moderator of the link between early anger and the development of behavior problems. Although traditional measures of anger were largely unrelated to later behavior problems, profiles of anger that dissociated typical from atypical development predicted behavior problems during preschool. Moreover, the relation between infant anger profiles and preschool behavior problems was moderated such that, when early life stress was low, infants with atypical profiles of early anger showed more preschool behavior problems than did infants with normative anger profiles. However, when early life stress was high, infants with atypical and normative profiles of infant anger did not differ in preschool behavior problems. We conclude that a discrete emotions approach including latent profile analysis is useful for elucidating biological and environmental developmental pathways to early problem behaviors. PMID:25151247

Middle Neoproterozoic (ca. 705-716 Ma) arc to rift transitional magmatism in the northern margin of the Yangtze Block: Constraints from geochemistry, zircon U-Pb geochronology and Hf isotopes

NASA Astrophysics Data System (ADS)

Wang, Ruirui; Xu, Zhiqin; Santosh, M.; Xu, Xianbing; Deng, Qi; Fu, Xuehai

2017-09-01

The South Qinling Belt in Central China is an important window to investigate the Neoproterozoic tectono-magmatic processes along the northern margin of the Yangtze Block. Here we present whole-rock geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes of a suite of Middle Neoproterozoic intrusion from the Wudang Uplift in South Qinling. Zircon LA-ICP-MS U-Pb ages reveal that these rocks were formed at ca. 705-716 Ma. Geochemical features indicate that the felsic magmatic rocks are I-type granitoids, belong to calcic- to calc-alkaline series, and display marked negative Nb, Ta and Ti anomalies. Moreover, the enrichment of light rare earth elements (LREEs) and large ion lithophile elements (LILEs), combined with depletion of heavy rare earth elements (HREEs) support that these rocks have affinity to typical arc magmatic rocks formed in Andean-type active continental margins. The REE patterns are highly to moderately fractionated, with (La/Yb)N = 5.13-8.10 in meta-granites, and 2.32-2.35 in granodiorite. The granitoids have a wide range of zircon εHf(t) values (-29.91 to 14.76) and zircon Hf two-stage model ages (696-3482 Ma). We suggest that the ca. 705-716 Ma granitoids were sourced from different degrees of magma mixing between partial melting of the overlying mantle wedge triggered by hydrous fluids released from subducted materials and crustal melting. The hybrid magmas were emplaced in the shallow crust accompanied by assimilation and fractional crystallization (AFC). Both isotopic and geochemical data suggest that the ca. 705-716 Ma felsic magmatic rocks were formed along a continental arc. These rocks as well as the contemporary A-type granite may mark a transitional tectonic regime from continental arc to rifting, probably related to slab rollback during the oceanic subduction beneath the northern margin of Yangtze Block.

Two flysch belts having distinctly different provenance suggest no stratigraphic link between the Wrangellia composite terrane and the paleo-Alaskan margin

USGS Publications Warehouse

Hults, Chad P.; Wilson, Frederic H.; Donelick, Raymond A.; O'Sullivan, Paul B.

2013-01-01

The provenance of Jurassic to Cretaceous flysch along the northern boundary of the allochthonous Wrangellia composite terrane, exposed from the Lake Clark region of southwest Alaska to the Nutzotin Mountains in eastern Alaska, suggests that the flysch can be divided into two belts having different sources. On the north, the Kahiltna flysch and Kuskokwim Group overlie and were derived from the Farwell and Yukon-Tanana terranes, as well as smaller related terranes that were part of the paleo-Alaskan margin. Paleocurrent indicators for these two units suggest that they derived sediment from the north and west. Sandstones are predominantly lithic wacke that contain abundant quartz grains, lithic rock fragments, and detrital mica, which suggest that these rocks were derived from recycled orogen and arc sources. Conglomerates contain limestone clasts that have fossils matching terranes that made up the paleo-Alaskan margin. In contrast, flysch units on the south overlie and were derived from the Wrangellia composite terrane. Paleocurrent indicators for these units suggest that they derived sediment from the south. Sandstones are predominantly feldspathic wackes that contain abundant plagioclase grains and volcanic rock fragments, which suggest these rocks were derived from an arc. Clast compositions in conglomerate south of the boundary match rock types of the Wrangellia composite terrane. The distributions of detrital zircon ages also differentiate the flysch units. Flysch units on the north average 54% Mesozoic, 14% Paleozoic, and 32% Precambrian detrital zircons, reflecting derivation from the older Yukon-Tanana, Farewell, and other terranes that made up the paleo-Alaskan margin. In comparison, flysch units on the south average 94% Mesozoic, 1% Paleozoic, and 5% Precambrian zircons, which are consistent with derivation from the Mesozoic oceanic magmatic arc rocks in the Wrangellia composite terrane. In particular, the flysch units on the south contain a large proportion of zircons ranging from 135 to 175 Ma, corresponding to the age of the Chitina magmatic arc in the Wrangellia terrane and the plutons of the Peninsular terrane, which are part of the Wrangellia composite terrane. Flysch units on the north do not contain significant numbers of zircons in this age range. The flysch overlying the Wrangellia composite terrane apparently does not contain detritus derived from rocks of the paleo-Alaska margin, and the flysch overlying the paleo-Alaskan margin apparently does not contain detritus derived from the Wrangellia composite terrane. The provenance difference between the two belts helps to constrain the location of the northern boundary of the Wrangellia composite terrane. Geophysical models place a deep, through-going, crustal-scale suture zone in the area between the two flysch belts. The difference in the provenance of the two belts supports this interpretation. The youngest flysch is Late Cretaceous in age, and structural disruption of the flysch units is constrained to the Late Cretaceous, so it appears that the Wrangellia composite terrane was not near the paleo-Alaskan margin until the Late Cretaceous.

Along Arc Structural Variation in the Izu-Bonin Arc and its Implications for Crustal Evolution Processes

NASA Astrophysics Data System (ADS)

Kodaira, S.; Sato, T.; Takahashi, N.; Ito, A.; Kaneda, Y.

2005-12-01

A continental-type middle crust having Vp = 6.1 - 6.3 km/s has been imaged at several oceanic island arcs (e.g. northern Izu, Mariana, Tonga, Kyushu-Palau ridge) since Suyehiro et al. (1996) has found a felsic middle crust in the northern Izu arc. A high velocity lower crust (Vp > 7.3 km/s) underlying the felsic middle crust has been also underlined as a characteristic structure in the northern Izu arc. A bulk composition of the crust in the Izu arc may indicate more mafic than that of a typical continental crust due to a large volume of the high velocity lower crust. Since a crust becomes more mature toward the north along the Izu-Bonin arc, investigating structural variation along the volcanic front has been believed to provide a fundamental knowledge for a crustal evolution process. In 2004 and 2005, Japan Agency for Marine-Earth Science and Technology has conducted two along arc wide-angle seismic surveys from the Sagami-bay to the Kita-Iwo jima, a total profile length of about 1000 km. Although data from the Bonin-part of the profile which were acquired this year has not been processed yet, a result from the Izu-part, from the Sagami-bay to Tori shima, shows significant structural variations along the volcanic front. The crustal thickness are varied with a wavelength of several tens of km, i.e., thickened up to 25-30 km around the volcanoes (the Miyake jama, Hachijo jima, Aoga sima, Sumisu jima), while thinned down to 20 km between them. The fine seismic velocity image obtained by refraction tomography as well as a wide-angle reflection migration shows that the variation of the crustal block having 6.0 - 6.7 km/s, which is a typical continental crustal velocity, is mainly responsible for the observed variation of the crustal thickness. The thickness of the high velocity lower crust is not significantly varied along the arc. Therefore, an average crustal seismic velocity (varied 6.6 to 7.0 km/s) represents a higher velocity that that of a typical continental crust (6. 4 km/s), and a negative correlation between the thickness of the 6.0 - 6.7 km/s block and the average crustal seismic velocity is recognized. In conclusion, the continental-type of the crust efficiently grow at the Quaternary volcanoes along Izu arc, but even at those areas the bulk composition of the entire crustal section shows more mafic than a continental crust due to the uniformly existing high velocity lower crust. A delamination process may be necessary to form a continental crust form the Izu island arc crust

Organic antireflective coatings for 193-nm lithography

NASA Astrophysics Data System (ADS)

Trefonas, Peter, III; Blacksmith, Robert F.; Szmanda, Charles R.; Kavanagh, Robert J.; Adams, Timothy G.; Taylor, Gary N.; Coley, Suzanne; Pohlers, Gerd

1999-06-01

Organic anti-reflective coatings (ARCs) continue to play an important role in semiconductor manufacturing. These materials provide a convenient means of greatly reducing the resist photospeed swing and reflective notching. In this paper, we describe a novel class of ARC materials optimized for lithographic applications using 193 nm exposure tools. These ARCs are based upon polymers containing hydroxyl-alkyl methacrylate monomers for crosslinkable sites, styrene for a chromophore at 193 nm, and additional alkyl-methacrylate monomers as property modifiers. A glycouril crosslinker and a thermally-activated acidic catalyst provide a route to forming an impervious crosslinked film activate data high bake temperatures. ARC compositions can be adjusted to optimize the film's real and imaginary refractive indices. Selection of optimal target indices for 193 nm lithographic processing through simulations is described. Potential chromophores for 193 nm were explored using ZNDO modeling. We show how these theoretical studies were combined with material selection criteria to yield a versatile organic anti-reflectant film, Shipley 193 G0 ARC. Lithographic process data indicates the materials is capable of supporting high resolution patterning, with the line features displaying a sharp resist/ARC interface with low line edge roughness. The resist Eo swing is successfully reduced from 43 percent to 6 percent.

Investigation on the properties of nano copper matrix composite via vacuum arc melting method

NASA Astrophysics Data System (ADS)

Liu, Yi; Leng, Jinfeng; Wu, Qirui; Zhang, Shaochen; Teng, Xinying

2017-10-01

Copper and copper matrix composites (CMCs) are widely used as electrical contact materials in electrical switch systems due to their excellent electrical properties. Graphene has great mechanical, physical and electrical properties, which is competent as an attractive reinforcing material for fabricating CMCs. Therefore, graphene was added to CMCs to improve the mechanical properties. In this study, graphene-reinforced copper matrix composites (Gr/Cu composites) were obtained. The xGr/Cu (x  =  0, 0.1, 0.3 and 0.5 wt.%) composites were fabricated via the vacuum arc melting method and compared the performance of them. The mechanical properties and electrical properties were obtained by measuring the hardness and conductivity. The microstructure of Gr/Cu composites was observed by optical microscopy (OM) and scanning electron microscopy (SEM). With the addition of graphene from 0 wt.% to 0.5 wt.%, the densities of materials decreased from 97.0% to 95.7%. With the increasing of graphene content, the hardness of composites increased at beginning and then decreased. In this range of adding amount, the hardness of 0.3Gr/Cu composite was up to 66.8 HB and increased by 15.4% compared to Al2O3/Cu composites without graphene. With the addition of graphene powder, the international annealing copper standard IACS% of Gr/Cu composites decreased from 86.16 to 69.86. The range of decline and the percentage of decline range are middle and 18.9%, respectively.

An evaluation of the electric arc spray and (HPPS) processes for the manufacturing of high power plasma spraying MCrAIY coatings

NASA Astrophysics Data System (ADS)

Sacriste, D.; Goubot, N.; Dhers, J.; Ducos, M.; Vardelle, A.

2001-06-01

The high power plasma torch (PlazJet) can be used to spray refractory ceramics with high spray rates and deposition efficiency. It can provide dense and hard coating with high bond strengths. When manufacturing thermal barrier coatings, the PlazJet gun is well adapted to spraying the ceramic top coat but not the MCrAIY materials that are used as bond coat. Arc spraying can compete with plasma spraying for metallic coatings since cored wires can be used to spray alloys and composites. In addition, the high production rate of arc spraying enables a significant decrease in coating cost. This paper discusses the performances of the PlazJet gun, and a twin-wire are spray system, and compares the properties and cost of MCrAIY coatings made with these two processes. For arc spraying, the use of air or nitrogen as atomizing gas is also investigated.

Gas metal arc welding fume generation using pulsed current

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castner, H.R.

1994-12-31

This paper describes a study of the effects of pulsed welding current on the amount of welding fume and ozone produced during gas metal arc welding (GMAW) using a range of welding procedures and pulse parameters. The results reported in this paper show that pulsed current can reduce GMAW fumes compared to steady current. This research also shows that welding parameters need to be properly controlled if pulsed current is to be used to reduce welding fumes. Fume and ozone generation rates were measured during this study for GMAW of mild steel using copper-coated ER70S-3 electrode wire and 95%Ar-5%CO{sub 2}more » and 85%Ar-15%CO{sub 2} shielding gases. Welds were made with both steady current and pulsed current over a wide range of welding parameters. Fume generation rates for steady current were found to be typically between 0.2 g/min and 0.8 g/min which agrees with other researchers. No significant difference was found in the chemical composition of welding fumes from pulsed current compared to the composition of fumes generated by steady current. New technology that can reduce arc welding fumes is of significant interest to a wide range of companies that use arc welding processes and this research should assist these users in evaluating the potential for the application of this technology to their own operations.« less

Graphene-Carbon-Metal Composite Film for a Flexible Heat Sink.

PubMed

Cho, Hyunjin; Rho, Hokyun; Kim, Jun Hee; Chae, Su-Hyeong; Pham, Thang Viet; Seo, Tae Hoon; Kim, Hak Yong; Ha, Jun-Seok; Kim, Hwan Chul; Lee, Sang Hyun; Kim, Myung Jong

2017-11-22

The heat generated from electronic devices such as light emitting diodes (LEDs), batteries, and highly integrated transistors is one of the major causes obstructing the improvement of their performance and reliability. Herein, we report a comprehensive method to dissipate the generated heat to a vast area by using the new type of graphene-carbon-metal composite film as a heat sink. The unique porous graphene-carbon-metal composite film that consists of an electrospun carbon nanofiber with arc-graphene (Arc-G) fillers and an electrochemically deposited copper (Cu) layer showed not only high electrical and thermal conductivity but also high mechanical stability. Accordingly, superior thermal management of LED devices to that of conventional Cu plates and excellent resistance stability during the repeated 10 000 bending cycles has been achieved. The heat dissipation of LEDs has been enhanced by the high heat conduction in the composite film, heat convection in the air flow, and thermal radiation at low temperature in the porous carbon structure. This result reveals that the graphene-carbon-metal composite film is one of the most promising materials for a heat sink of electronic devices in modern electronics.

Structure and Tribological Properties of B83 Babbit-Based Composite Rods and the Coatings Produced from Them by Arc Surfacing

NASA Astrophysics Data System (ADS)

Bolotova, L. K.; Kalashnikov, I. E.; Kobeleva, L. I.; Katin, I. E.; Kolmakov, A. G.; Mikheev, R. S.; Kobernik, N. V.; Podymova, N. B.

2018-01-01

Surfacing composite rods based on a B83 babbit alloy reinforced by silicon carbide and boron carbide particles are fabricated by extrusion. The structure and the tribological properties of the rods are studied. Extrusion allowed us to introduce and to uniformly distribute reinforcing fillers and to change the size and the morphology of the intermetallic phases in the matrix alloy. The wear resistance of the rods made of the B83 babbit + 5 wt % SiC composite material is shown to be higher than that of commercial B83 alloy samples by a factor of 1.2. Arc surfacing is used to deposit antifriction coatings, which are made of the surfacing composite rods based on B83 babbit reinforced by boron carbide or silicon carbide particles, onto steel substrates. The deposited layers exhibit good adhesion to the substrates: the melting line is continuous and does not contain discontinuities. The structure and the tribological properties of the deposited coatings are studied. The wear resistance of the composite coatings is higher than that of the B83 alloy-based coating by 30%.

COMPOSITIONAL LANDSCAPE METRICS AND LANDCOVER CONNECTIVITY MEASURES FOR THE SUB-WATERSHEDS OF THE UPPER SAN PEDRO RIVER 1997

EPA Science Inventory

Various compositional landscape metrics and landcover connectivity measures for the sub-watersheds of the Upper San Pedro River. Metrics were computed using the ATtILA v.3.03 ArcView extension. Inputs included the sub-watershed coverage obtained from the USDA-ARS-SWRC in Tucson,...

Surface characterization of weathered wood-plastic composites produced from modified wood flour

Treesearch

James S. Fabiyi; Armando G. McDonald; Nicole M. Stark

2007-01-01

The effects of weathering on the surface properties of wood-plastic composites (WPC) were examined. High-density polyethylene (HDPE) based WPCs made from modified wood flour (untreated, extractives free, and holocellulose (delignified) fibers) were subjected to accelerated (xenon-arc) weathering. Colorimetry and Fourier-transform infrared spectroscopy were employed to...

Petrochemical evolution of the White Mfolozi Granite pluton: Evidence for a late Palaeoarchaean A-type granite from the SE Kaapvaal Craton, South Africa

NASA Astrophysics Data System (ADS)

Misra, Saumitra; Reinhardt, Jürgen; Wilson, Allan H.

2017-08-01

One of the major limitations in understanding the geochemical evolution of the Kaapvaal Craton, South Africa, is the scarcity of whole rock trace element data of the granitoid and other rocks compared to the vastness of this cratonic block. Here we present new XRF major oxide and ICP-MS trace element analyses of the White Mfolozi Granitoid (WMG) pluton, SE Kaapvaal Craton, which suggest that the 3.25 Ga (U-Pb zircon age) old WMG pluton is a peraluminous A-type granite and could be equivalent to the intrusive potassic granite phase of the Anhalt Granitoid suite, occurring to the North of the WMG pluton. The pluton was generated by batch partial melting of a pre-existing TTG source in two major phases under relatively anhydrous conditions, and the heat of partial melting could have been provided by a voluminous mantle-derived mafic magma, which intruded into mid-crustal levels (c. 17 km), perhaps during a period of crustal extension. The estimated pressure and temperature of generation of the WMG parent magma with average molar [or/(or + ab)] 0.48 could be 500 MPa and close to 1000 °C, respectively, when compared with the results of experimental petrology. Interstitial occurrence of relatively iron-rich biotite [Mg/(Mg + Fe) 0.41-0.45] suggests that the final temperature of crystallization of the pluton was close to 800 °C. An important magmatic event following the main phase of partial melting was limited mixing between the intrusive mafic magma and co-existing newly generated granitic melt. This magma mixing resulted in distinct variations in SiO2 and a low initial Sr isotopic ratio (0.7013) of the WMG pluton. Although both the models of partial melting of quartzo-feldspathic sources and fractional crystallization of basaltic magmas with or without crustal assimilation have been proposed for the origin of A-type granites, the model of magmatic evolution of the WMG pluton presented here can also be an alternative model for the generation of A-type granites. In this model, post-partial melting magma mixing is perhaps critical in explaining the Daly gap in composition and extreme variations in chemical (e.g., SiO2) and isotopic compositions observed in many bimodal A-type granite suites. The emplacement of the oldest known A-type granitoid suite in the Kaapvaal Craton, the WMG pluton, marks a period of stabilization of the craton before erosion and deposition of the overlying volcano-sedimentary succession of the Pongola Supergroup.

Atypical centrioles during sexual reproduction

PubMed Central

Avidor-Reiss, Tomer; Khire, Atul; Fishman, Emily L.; Jo, Kyoung H.

2015-01-01

Centrioles are conserved, self-replicating, microtubule-based, 9-fold symmetric subcellular organelles that are essential for proper cell division and function. Most cells have two centrioles and maintaining this number of centrioles is important for animal development and physiology. However, how animals gain their first two centrioles during reproduction is only partially understood. It is well established that in most animals, the centrioles are contributed to the zygote by the sperm. However, in humans and many animals, the sperm centrioles are modified in their structure and protein composition, or they appear to be missing altogether. In these animals, the origin of the first centrioles is not clear. Here, we review various hypotheses on how centrioles are gained during reproduction and describe specialized functions of the zygotic centrioles. In particular, we discuss a new and atypical centriole found in sperm and zygote, called the proximal centriole-like structure (PCL). We also discuss another type of atypical centriole, the “zombie” centriole, which is degenerated but functional. Together, the presence of centrioles, PCL, and zombie centrioles suggests a universal mechanism of centriole inheritance among animals and new causes of infertility. Since the atypical centrioles of sperm and zygote share similar functions with typical centrioles in somatic cells, they can provide unmatched insight into centriole biology. PMID:25883936

Atypical centrioles during sexual reproduction.

PubMed

Avidor-Reiss, Tomer; Khire, Atul; Fishman, Emily L; Jo, Kyoung H

2015-01-01

Centrioles are conserved, self-replicating, microtubule-based, 9-fold symmetric subcellular organelles that are essential for proper cell division and function. Most cells have two centrioles and maintaining this number of centrioles is important for animal development and physiology. However, how animals gain their first two centrioles during reproduction is only partially understood. It is well established that in most animals, the centrioles are contributed to the zygote by the sperm. However, in humans and many animals, the sperm centrioles are modified in their structure and protein composition, or they appear to be missing altogether. In these animals, the origin of the first centrioles is not clear. Here, we review various hypotheses on how centrioles are gained during reproduction and describe specialized functions of the zygotic centrioles. In particular, we discuss a new and atypical centriole found in sperm and zygote, called the proximal centriole-like structure (PCL). We also discuss another type of atypical centriole, the "zombie" centriole, which is degenerated but functional. Together, the presence of centrioles, PCL, and zombie centrioles suggests a universal mechanism of centriole inheritance among animals and new causes of infertility. Since the atypical centrioles of sperm and zygote share similar functions with typical centrioles in somatic cells, they can provide unmatched insight into centriole biology.

Atypical centromeres in plants-what they can tell us.

PubMed

Cuacos, Maria; H Franklin, F Chris; Heckmann, Stefan

2015-01-01

The centromere, visible as the primary constriction of condensed metaphase chromosomes, is a defined chromosomal locus essential for genome stability. It mediates transient assembly of a multi-protein complex, the kinetochore, which enables interaction with spindle fibers and thus faithful segregation of the genetic information during nuclear divisions. Centromeric DNA varies in extent and sequence composition among organisms, but a common feature of almost all active eukaryotic centromeres is the presence of the centromeric histone H3 variant cenH3 (a.k.a. CENP-A). These typical centromere features apply to most studied species. However, a number of species display "atypical" centromeres, such as holocentromeres (centromere extension along almost the entire chromatid length) or neocentromeres (ectopic centromere activity). In this review, we provide an overview of different atypical centromere types found in plants including holocentromeres, de novo formed centromeres and terminal neocentromeres as well as di-, tri- and metapolycentromeres (more than one centromere per chromosomes). We discuss their specific and common features and compare them to centromere types found in other eukaryotic species. We also highlight new insights into centromere biology gained in plants with atypical centromeres such as distinct mechanisms to define a holocentromere, specific adaptations in species with holocentromeres during meiosis or various scenarios leading to neocentromere formation.

The Effect of Irradiation Distance on Microhardness of Resin Composites Cured with Different Light Curing Units

PubMed Central

Cekic-Nagas, Isil; Egilmez, Ferhan; Ergun, Gulfem

2010-01-01

Objectives: The aim of this study was to compare the microhardness of five different resin composites at different irradiation distances (2 mm and 9 mm) by using three light curing units (quartz tungsten halogen, light emitting diodes and plasma arc). Methods: A total of 210 disc-shaped samples (2 mm height and 6 mm diameter) were prepared from different resin composites (Simile, Aelite Aesthetic Enamel, Clearfil AP-X, Grandio caps and Filtek Z250). Photoactivation was performed by using quartz tungsten halogen, light emitting diode and plasma arc curing units at two irradiation distances (2 mm and 9 mm). Then the samples (n=7/per group) were stored dry in dark at 37°C for 24 h. The Vickers hardness test was performed on the resin composite layer with a microhardness tester (Shimadzu HMV). Data were statistically analyzed using nonparametric Kruskal Wallis and Mann-Whitney U tests. Results: Statistical analysis revealed that the resin composite groups, the type of the light curing units and the irradiation distances have significant effects on the microhardness values (P<.05). Conclusions: Light curing unit and irradiation distance are important factors to be considered for obtaining adequate microhardness of different resin composite groups. PMID:20922164

Geochemical signature variation of pre-, syn-, and post-shearing intrusives within the Najd Fault System of western Saudi Arabia

NASA Astrophysics Data System (ADS)

Hassan, M.; Abu-Alam, T. S.; Hauzenberger, C.; Stüwe, K.

2016-10-01

Late Precambrian intrusive rocks in the Arabian-Nubian Shield emplaced within and around the Najd Fault System of Saudi Arabia feature a great compositional diversity and a variety of degrees of deformation (i.e. pre-shearing deformed, sheared mylonitized, and post-shearing undeformed) that allows placing them into a relative time order. It is shown here that the degree of deformation is related to compositional variations where early, usually pre-shearing deformed rocks are of dioritic, tonalitic to granodioritic, and later, mainly post-shearing undeformed rocks are mostly of granitic composition. Correlation of the geochemical signature and time of emplacement is interpreted in terms of changes in the source region of the produced melts due to the change of the stress regime during the tectonic evolution of the Arabian-Nubian Shield. The magma of the pre-shearing rocks has tholeiitic and calc-alkaline affinity indicating island arc or continental arc affinity. In contrast, the syn- and post-shearing rocks are mainly potassium rich peraluminous granites which are typically associated with post-orogenic uplift and collapse. This variation in geochemical signature is interpreted to reflect the change of the tectonic regime from a compressional volcanic arc nature to extensional within-plate setting of the Arabian-Nubian Shield. Within the context of published geochronological data, this change is likely to have occurred around 605-580 Ma.

Magmatic evolution of Panama Canal volcanic rocks: A record of arc processes and tectonic change

PubMed Central

Cardona, Agustin; Montes, Camilo; Foster, David; Jaramillo, Carlos

2017-01-01

Volcanic rocks along the Panama Canal present a world-class opportunity to examine the relationship between arc magmatism, tectonic forcing, wet and dry magmas, and volcanic structures. Major and trace element geochemistry of Canal volcanic rocks indicate a significant petrologic transition at 21–25 Ma. Oligocene Bas Obispo Fm. rocks have large negative Nb-Ta anomalies, low HREE, fluid mobile element enrichments, a THI of 0.88, and a H2Ocalc of >3 wt. %. In contrast, the Miocene Pedro Miguel and Late Basalt Fm. exhibit reduced Nb-Ta anomalies, flattened REE curves, depleted fluid mobile elements, a THI of 1.45, a H2Ocalc of <1 wt. %, and plot in mid-ocean ridge/back-arc basin fields. Geochemical modeling of Miocene rocks indicates 0.5–0.1 kbar crystallization depths of hot (1100–1190°C) magmas in which most compositional diversity can be explained by fractional crystallization (F = 0.5). However, the most silicic lavas (Las Cascadas Fm.) require an additional mechanism, and assimilation-fractional-crystallization can reproduce observed compositions at reasonable melt fractions. The Canal volcanic rocks, therefore, change from hydrous basaltic pyroclastic deposits typical of mantle-wedge-derived magmas, to hot, dry bi-modal magmatism at the Oligocene-Miocene boundary. We suggest the primary reason for the change is onset of arc perpendicular extension localized to central Panama. High-resolution mapping along the Panama Canal has revealed a sequence of inward dipping maar-diatreme pyroclastic pipes, large basaltic sills, and bedded silicic ignimbrites and tuff deposits. These volcanic bodies intrude into the sedimentary Canal Basin and are cut by normal and subsequently strike-slip faults. Such pyroclastic pipes and basaltic sills are most common in extensional arc and large igneous province environments. Overall, the change in volcanic edifice form and geochemistry are related to onset of arc perpendicular extension, and are consistent with the idea that Panama arc crust fractured during collision with South America forming the observed Canal extensional zone. PMID:28489866

Thermophysical and radiation properties of high-temperature C4F8-CO2 mixtures to replace SF6 in high-voltage circuit breakers

NASA Astrophysics Data System (ADS)

Zhong, Linlin; Cressault, Yann; Teulet, Philippe

2018-03-01

C4F8-CO2 mixtures are one of the potential substitutes to SF6 in high-voltage circuit breakers. However, the arc quenching ability of C4F8-CO2 mixtures is still unknown. In order to provide the necessary basic data for the further investigation of arc quenching performance, the compositions, thermodynamic properties, transport coefficients, and net emission coefficients (NEC) of various C4F8-CO2 mixtures are calculated at temperatures of 300-30 000 K in this work. The thermodynamic properties are presented as the product of mass density and specific heat, i.e., ρCp. The transport coefficients include electrical conductivity, viscosity, and thermal conductivity. The atomic and molecular radiation are both taken into account in the calculation of NEC. The comparison of the properties between SF6 and C4F8-CO2 mixtures is also discussed to find their differences. The results of compositions show that C4F8-CO2 mixtures have a distinctive advantage over other alternative gases e.g., CF3I and C3F8, because the dissociative product (i.e., C4F6) of C4F8 at low temperatures has a very high dielectric strength. This is good for an arc quenching medium to endure the arc recovery phase. Compared with SF6, C4F8-CO2 mixtures present lower ρCp at temperatures below 2800 K and larger thermal conductivity above 2800 K. Based on the position of peaks in thermal conductivity, we predict that the cooling of C4F8-CO2 arc will be slowed down at higher temperatures than that of SF6 arc. It is also found that the mixing of CO2 shows slight effects on the electrical conductivity and NEC of C4F8-CO2 mixtures.

Characterization of Material Response During Arc-Jet Testing with Optical Methods Status and Perspectives

NASA Technical Reports Server (NTRS)

Winter, Michael

2012-01-01

The characterization of ablation and recession of heat shield materials during arc jet testing is an important step towards understanding the governing processes during these tests and therefore for a successful extrapolation of ground test data to flight. The behavior of ablative heat shield materials in a ground-based arc jet facility is usually monitored through measurement of temperature distributions (across the surface and in-depth), and through measurement of the final surface recession. These measurements are then used to calibrate/validate materials thermal response codes, which have mathematical models with reasonably good fidelity to the physics and chemistry of ablation, and codes thus calibrated are used for predicting material behavior in flight environments. However, these thermal measurements only indirectly characterize the pyrolysis processes within an ablative material pyrolysis is the main effect during ablation. Quantification of pyrolysis chemistry would therefore provide more definitive and useful data for validation of the material response codes. Information of the chemical products of ablation, to various levels of detail, can be obtained using optical methods. Suitable optical methods to measure the shape and composition of these layers (with emphasis on the blowing layer) during arc jet testing are: 1) optical emission spectroscopy (OES) 2) filtered imaging 3) laser induced fluorescence (LIF) and 4) absorption spectroscopy. Several attempts have been made to optically measure the material response of ablative materials during arc-jet testing. Most recently, NH and OH have been identified in the boundary layer of a PICA ablator. These species are suitable candidates for a detection through PLIF which would enable a spatially-resolved characterization of the blowing layer in terms of both its shape and composition. The recent emission spectroscopy data will be presented and future experiments for a qualitative and quantitative characterization of the material response of ablative materials during arc-jet testing will be discussed.

Low-void polyimide resins for autoclave processing

NASA Technical Reports Server (NTRS)

Jones, R. J.; Vaughan, R. W.

1972-01-01

Development of an advanced A-type polyimide, which can be used to produce autoclave molded, low-void content composites suitable for use at temperatures up to 316 C is reported. It consists of a mixture of methyl nadic anhydride, an 80:20 molar ratio of methylene dianaline and thiodianilene, and pyromellitic dianhydride.

Late Cretaceous infant intra-oceanic arc volcanism, the Central Pontides, Turkey: Petrogenetic and tectonic implications

NASA Astrophysics Data System (ADS)

Aygül, Mesut; Okay, Aral I.; Oberhänsli, Roland; Schmidt, Alexander; Sudo, Masafumi

2015-11-01

A tectonic slice of an arc sequence consisting of low-grade metavolcanic rocks and overlying metasedimentary succession is exposed in the Central Pontides north of the İzmir-Ankara-Erzincan suture separating Laurasia from Gondwana-derived terranes. The metavolcanic rocks mainly consist of basaltic andesite/andesite and mafic cognate xenolith-bearing rhyolite with their pyroclastic equivalents, which are interbedded with recrystallized pelagic limestone and chert. The metasedimentary succession comprises recrystallized micritic limestone with rare volcanogenic metaclastic rocks and stratigraphically overlies the metavolcanic rocks. The geochemistry of the metavolcanic rocks indicates an arc setting evidenced by depletion of HFSE (Ti, P and Nb) and enrichment of fluid mobile LILE. Identical trace and rare earth elements compositions of basaltic andesites/andesites and rhyolites suggest that they are cogenetic and derived from a common parental magma. The arc sequence crops out between an Albian-Turonian subduction-accretionary complex representing the Laurasian active margin and an ophiolitic mélange. Absence of continent derived detritus in the arc sequence and its tectonic setting in a wide Cretaceous accretionary complex suggest that the Kösdağ Arc was intra-oceanic. Zircons from two metarhyolite samples give Late Cretaceous (93.8 ± 1.9 and 94.4 ± 1.9 Ma) U/Pb ages. These ages are the same as the age of the supra-subduction ophiolites in western Turkey, which implies that that the Kösdağ Arc may represent part of the incipient arc formed during the generation of the supra-subduction ophiolites. The low-grade regional metamorphism in the Kösdağ Arc is constrained to 69.9 ± 0.4 Ma by 40Ar/39Ar muscovite dating indicating that the arc sequence became part of a wide Tethyan Cretaceous accretionary complex by the latest Cretaceous. Non-collisional cessation of the arc volcanism is possibly associated with southward migration of the magmatism as in the Izu-Bonin-Mariana arc system.

Generation of alkaline magmas in subduction zones by melting of mélange diapirs

NASA Astrophysics Data System (ADS)

Cruz-Uribe, A. M.; Marschall, H.; Gaetani, G. A.; Le Roux, V.

2016-12-01

Alkaline lavas occur globally in subduction-related volcanic arcs. Existing explanations for the occurrence of alkaline lavas in volcanic arcs invoke at least one - and in some cases multiple - `metasomatic' events in addition to the traditional three-component mixing of altered oceanic crust (AOC), sediment melt, and depleted mantle, in order to explain the range of rock types found in a given region. These multi-stage models posit the existence of metasomatized mantle wedge peridotite containing phlogopite or amphibole-enriched veins, which partially melt when fluxed by the addition of materials from the subducted slab. The mélange diapir model is informed by observations and modeling of the subduction side of the arc system, and predicts the generation of alkaline arc magmas by advection of buoyant material from the slab-wedge interface into the mantle wedge below arcs. Here we report results from experiments in which natural mélange materials partially melted at upper mantle conditions were found to produce alkaline magmas compositionally similar to those found in arcs worldwide. The starting material for our experiments is a chlorite-omphacite fels (SY400) from the island of Syros, Greece, that is representative of a hybrid rock containing AOC, sediment, and mantle components. Melting experiments were performed using a piston cylinder apparatus at conditions relevant to the heating-decompression path of mélange diapirs (1000-1300 °C, 1.5-2.5 GPa). The compositions of experimentally produced melts range from 51-61 wt% SiO2, and fall within the trachyte and tephrite-phonolite series (7.5-12.9 wt% Na2O+K2O). Restitic phases in equilibrium with melt include clinopyroxene, garnet (at high P), phlogopite (at high P), amphibole, olivine, rutile, and ilmenite. Partial melts produced in our experiments have trace-element abundance patterns that are typical of alkaline arc lavas, such as enrichment in large ion lithophile elements (Cs, Rb, Ba, Pb, Sr) and alkalis (K and Na), and depletion in Nb and Ta. The presence of a light rare earth element (LREE)-bearing accessory phase results in trace element fractionation by a factor of 4.2 for Nd/Hf and 2.6 for Sr/Nd. Melting of mélange diapirs provides a simple, single-stage model for the origin of alkaline magmatism in the arc and backarc regions of subduction zones.

Effects of crustal thickness on magmatic differentiation in subduction zone volcanism: A global study

NASA Astrophysics Data System (ADS)

Farner, Michael J.; Lee, Cin-Ty A.

2017-07-01

The majority of arc magmas are highly evolved due to differentiation within the lithosphere or crust. Some studies have suggested a relationship between crustal thickness and magmatic differentiation, but the exact nature of this relationship is unclear. Here, we examine the interplay of crustal thickness and magmatic differentiation using a global geochemical dataset compiled from active volcanic arcs and elevation as a proxy for crustal thickness. With increasing crustal thickness, average arc magma compositions become more silicic (andesitic) and enriched in incompatible elements, indicating that on average, arc magmas in thick crust are more evolved, which can be easily explained by the longer transit and cooling times of magmas traversing thick arc lithosphere and crust. As crustal thickness increases, arc magmas show higher degrees of iron depletion at a given MgO content, indicating that arc magmas saturate earlier in magnetite when traversing thick crust. This suggests that differentiation within thick crust occurs under more oxidizing conditions and that the origin of oxidation is due to intracrustal processes (contamination or recharge) or the role of thick crust in modulating melting degree in the mantle wedge. We also show that although arc magmas are on average more silicic in thick crust, the most silicic magmas (>70 wt.% SiO2) are paradoxically found in thin crust settings, where average compositions are low in silica (basaltic). We suggest that extreme residual magmas, such as those exceeding 70 wt.% SiO2, are preferentially extracted from shallow crustal magma bodies than from deep-seated magma bodies, the latter more commonly found in regions of thick crust. We suggest that this may be because the convective lifespan of crustal magma bodies is limited by conductive cooling through the overlying crustal lid and that magma bodies in thick crust cool more slowly than in thin crust. When the crust is thin, cooling is rapid, preventing residual magmas from being extracted; in the rare case that residual magmas can be extracted, they represent the very last melt fractions, which are highly silicic. When the crust is thick, cooling is slow, so intermediate melt fractions can readily segregate and erupt to the surface, where they cool and crystallize before highly silicic residual melts can be generated.

Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes

NASA Astrophysics Data System (ADS)

Gill, R. C. O.; Aparicio, A.; El Azzouzi, M.; Hernandez, J.; Thirlwall, M. F.; Bourgois, J.; Marriner, G. F.

2004-12-01

Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr-Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (˜0.5×N-MORB), especially Nb (˜0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. 143Nd/ 144Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas 87Sr/ 86Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with ( 87Sr/ 86Sr) 0 up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr-Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies. The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere arising from convective thinning of over-thickened lithosphere. Our data support recent models in which subsidence is caused by westward rollback of an eastward-dipping subduction zone beneath the westernmost Mediterranean. Moreover, severance of the lithosphere at the edges of the rolling-back slab provides opportunities for locally melting lithospheric mantle, providing a possible explanation for the shoshonitic volcanism seen in northern Morocco and more sporadically in SE Spain.

Post-emplacement history of the Zambales Ophiolite Complex: Insights from petrography, geochronology and geochemistry of Neogene clastic rocks

NASA Astrophysics Data System (ADS)

Dimalanta, C. B.; Salapare, R. C.; Faustino-Eslava, D. V.; Ramos, N. T.; Queaño, K. L.; Yumul, G. P.; Yang, T. F.

2015-05-01

The Zambales Ophiolite Complex in Luzon, Philippines is made up of two blocks with differing geochemical signatures and ages - the Middle Jurassic to Early Cretaceous Acoje Block-San Antonio Massif that is of island arc tholeiite composition and the Eocene Coto Block-Cabangan Massif which is of transitional mid-ocean ridge basalt-island arc tholeiite affinity. These ophiolitic bodies are overlain by Miocene to Pliocene sedimentary units whose petrochemistry are reported here for the first time. Varying degrees of influences from ophiolitic detritus and from arc volcanic materials, as shown by petrography and indicator elements including Cr, Co and Ni, are observed in these sedimentary formations from north to south and from the oldest to the youngest. The Early to Middle Miocene Cabaluan Formation, whose outcrops are found to overlie only the Acoje Block, registers a more dominant ophiolitic signature as compared to the Late Miocene to Pliocene Santa Cruz Formation. The Santa Cruz Formation is generally characterized by fewer ophiolitic clasts and higher amounts of felsic components. Additionally, within this formation itself, a pronounced compositional change is observed relative to its spatial distribution. From the south to the north, an increase in ophiolitic components and a relative decrease in felsic signature is noted in units of the Santa Cruz Formation. It is therefore inferred that changes in the petrochemistry of rocks from the older Cabaluan to the younger Santa Cruz sedimentary formations record a decline in the influx of ophiolitic detritus or, conversely, the introduction of more diverse sediment sources as the deposition progressed. Detrital zircon U-Pb ages from the Santa Cruz Formation, with peaks at 46.73 ± 0.94 and 5.78 ± 0.13 Ma, reflects this change in provenance from the unroofing of an Early Eocene oceanic crust to fresh contributions from an active volcanic arc during the Late Miocene. The contrast in compositions of the southern and northern Santa Cruz Formation also indicates a closer proximity of the southern units to the source of these non-ophiolitic sources, which most likely corresponds to the Pliocene volcanoes of the West Luzon Arc.

Changes in Lava Compositions and With Time From the Eocene Through the Miocene for the Mariana Forearc

NASA Astrophysics Data System (ADS)

Reagan, M. K.; Mohler, D.; Brian, H.; Hickey-Vargas, R.; Hanan, B.

2003-12-01

We are investigating the evolution of volcanism in the Mariana arc from the initiation of subduction of the Pacific plate beneath the Philippine plate in the Eocene through the Miocene. The oldest lavas in the Mariana fore-arc region are a ca 49 Ma tholeiite to boninite sequence from DSDP sites 458 and 459. These tholeiites have NMORB-like REE, HFSE, and Th concentrations, but are enriched in LIL elements, Pb, and U. The capping boninite-series glasses have similar slab-derived trace element abundance patterns, but lower and flatter REE contents (1-2 x PUM). 40Ar/39Ar ages obtained on boninite series lavas from Guam stretch back to 44Ma. These lavas have U-shaped REE patterns and HREE concentrations about 3-8 x PUM. La/Nb decrease and Hf/Sm increase with increasing Ba/La for both the DSDP and Guam lavas. Pb isotope values plot within fields defined by Pacific plate lavas and volcanogenic sediments (Meijer, 1976, GSA Bull., v. 87; Pearce et al., 1999, J. Petrol., v. 40). Hf and Pb isotopic compositions change consistently with Hf/Sm and Ba/La ratios for lavas from the DSDP sites, but not for those from Guam. The data suggest either that little of the Pb in these lavas was derived from subducting sediments, or that the contrast in Pb isotopes between lavas from Guam and slab fluids was inconsequential. The source of the DSDP site lavas was similar to a Pacific or transitional Pacific-Indian Ocean MORB-source. Fluxed melting at high-P generated the tholeiites. Boninites were generated at low-P by continued fluxed melting. The mantle source for the boninite-series lavas from Guam was less depleted. Progressive fluxed melting here apparently occurred with less mantle upwelling. In both locations, the variations in La/Nb and perhaps the Hf/Sm ratios appear to be related to changes in the residual mantle source mineralogy with progressive melting. Rhyolites erupted on Saipan at 45- 46 Ma are unusually high in silica for an oceanic island arc setting. These lavas are enigmatic in that they have trace element and isotopic compositions similar to those of Oligocene (36-32 Ma) mature arc andesites and dacites from forearc sites. Pb isotope values for all of these lavas plot along a trend that stretches from the NHRL toward Pacific siliceous sediments, with the rhyolites plotting at the least radiogenic end of the array. Basalt dikes with ages of ca. 41 Ma cut the boninite series lavas in Guam. These basalts have trace element patterns of typical arc tholeiites, and mark the first appearance of relatively normal mafic arc lavas in this system. Pb isotope compositions for these samples indicate that siliceous sediment also makes its first appearance at this time. A second stage of normal arc volcanism began on Guam and Saipan at about 14 Ma, after spreading in the Parece Vela Basin ceased. These lavas have incompatible trace element and isotopic ratios that are remarkably similar to those of the modern Mariana arc. In conclusion: lavas from DSDP sites 458 and 459 were apparently generated from upwelling mantle that rushed in behind the newly subducting Pacific lithosphere (see Stern and Bloomer, 1992, GSA Bull. v. 104; Hall et al., 2003, EPSL, v. 212). The transition from an upwelling mantle wedge to relatively normal mantle counterflow and P-T distributions in the mantle wedge apparently required several million years of subduction and cooling of the corner of the mantle wedge. The compositions of the mantle (Pacific to Indian) and the subducted components (basaltic to silicic sediment) both changed with the mantle convection regime.

ARC-1981-AC81-0174

NASA Image and Video Library

1981-03-20

Artist: Ken Hodges Composite image explaining Objective and Motivation for Galileo Probe Heat Loads: Galileo Probe descending into Jupiters Atmosphere shows heat shield separation with parachute deployed. (Ref. JPL P-19180)

Crustal structure of Yunnan province, People's Republic of China, from seismic refraction profiles

USGS Publications Warehouse

Kan, R.-J.; Hu, H.-X.; Zeng, R.-S.; Mooney, W.D.; McEvilly, T.V.

1986-01-01

Seismic refraction, profiles in Yunnan Province, southwestern China, define the crustal structure in an area of active tectonics, on the southern end of the Himalaya-Burma arc. The crustal thickness ranges from 38 to 46 kilometers, and the relatively low mean crustal velocity indicates a crustal composition compatible with normal continental crust and consisting mainly of meta-sedimentary and silicic intrusive rocks, with little mafic or ultramafic component. This composition suggests a crustal evolution involving sedimentary processes on the flank of the Yangtze platform rather than the accretion of oceanic island arcs, as has been proposed. An anomalously low upper-mantle velocity observed on one profile, but not on another at right angles to it may indicate active tectonic processes in the mantle or seismic anisotropy.

Crustal Structure of Yunnan Province, People's Republic of China, from Seismic Refraction Profiles.

PubMed

Kan, R J; Hu, H X; Zeng, R S; Mooney, W D; McEvilly, T V

1986-10-24

Seismic refraction, profiles in Yunnan Province, southwestern China, define the crustal structure in an area of active tectonics on the southern end of the Himalaya-Burma arc. The crustal thickness ranges from 38 to 46 kilometers, and the relatively low mean crustal velocity indicates a crustal composition compatible with normal continental crust and consisting mainly of meta-sedimentary and silicic intrusive rocks, with little mafic or ultramafic component. This composition suggests a crustal evolution involving sedimentary processes on the flank of the Yangtze platform rather than the accretion of oceanic island arcs, as has been proposed. An anomalously low upper-mantle velocity observed on one profile but not on another at right angles to it may indicate active tectonic processes in the mantle or seismic anisotropy.

Geochemistry of hydrothermal fluids from the PACMANUS, Northeast Pual and Vienna Woods hydrothermal fields, Manus Basin, Papua New Guinea

USGS Publications Warehouse

Reeves, Eoghan P.; Seewald, Jeffrey S.; Saccocia, Peter; Bach, Wolfgang; Craddock, Paul R.; Shanks, Wayne C.; Sylva, Sean P.; Walsh, Emily; Pichler, Thomas; Rosner, Martin

2011-01-01

Processes controlling the composition of seafloor hydrothermal fluids in silicic back-arc or near-arc crustal settings remain poorly constrained despite growing evidence for extensive magmatic-hydrothermal activity in such environments. We conducted a survey of vent fluid compositions from two contrasting sites in the Manus back-arc basin, Papua New Guinea, to examine the influence of variations in host rock composition and magmatic inputs (both a function of arc proximity) on hydrothermal fluid chemistry. Fluid samples were collected from felsic-hosted hydrothermal vent fields located on Pual Ridge (PACMANUS and Northeast (NE) Pual) near the active New Britain Arc and a basalt-hosted vent field (Vienna Woods) located farther from the arc on the Manus Spreading Center. Vienna Woods fluids were characterized by relatively uniform endmember temperatures (273-285 degrees C) and major element compositions, low dissolved CO2 concentrations (4.4 mmol/kg) and high measured pH (4.2-4.9 at 25 degrees C). Temperatures and compositions were highly variable at PACMANUS/NE Pual and a large, newly discovered vent area (Fenway) was observed to be vigorously venting boiling (358 degrees C) fluid. All PACMANUS fluids are characterized by negative delta DH2O values, in contrast to positive values at Vienna Woods, suggesting substantial magmatic water input to circulating fluids at Pual Ridge. Low measured pH (25 degrees C) values (~2.6-2.7), high endmember CO2 (up to 274 mmol/kg) and negative delta 34SH2S values (down to -2.7 permille) in some vent fluids are also consistent with degassing of acid-volatile species from evolved magma. Dissolved CO2 at PACMANUS is more enriched in 13C (-4.1 permille to -2.3 permille) than Vienna Woods (-5.2 permille to -5.7 permille), suggesting a contribution of slab-derived carbon. The mobile elements (e.g. Li, K, Rb, Cs and B) are also greatly enriched in PACMANUS fluids reflecting increased abundances in the crust there relative to the Manus Spreading Center. Variations in alkali and dissolved gas abundances with Cl at PACMANUS and NE Pual suggest that phase separation has affected fluid chemistry despite the low temperatures of many vents. In further contrast to Vienna Woods, substantial modification of PACMANUS/NE Pual fluids has taken place as a result of seawater ingress into the upflow zone. Consistently high measured Mg concentrations as well as trends of increasingly non-conservative SO4 behavior, decreasing endmember Ca/Cl and Sr/Cl ratios with increased Mg indicate extensive subsurface anhydrite deposition is occurring as a result of subsurface seawater entrainment. Decreased pH and endmember Fe/Mn ratios in higher Mg fluids indicate that the associated mixing/cooling gives rise to sulfide deposition and secondary acidity production. Several low temperature (< or = 80 degrees C) fluids at PACMANUS/NE Pual also show evidence for anhydrite dissolution and water-rock interaction (fixation of B) subsequent to seawater entrainment. Hence, the evolution of fluid compositions at Pual Ridge reflects the cumulative effects of water/rock interaction, admixing and reaction of fluids exsolved from silicic magma, phase separation/segregation and seawater ingress into upflow zones.

Scientific and Technological Principles of Development of New Cold-Resistant Arc-Steels (Steels for Arctic Applications)

NASA Astrophysics Data System (ADS)

Sych, O. V.; Khlusova, E. I.; Yashin, E. A.

2017-12-01

The paper presents the results of quantitative analysis of C, Mn, Ni and Cu content on strength and cold-resistance of rolled plates. Relations between the ferritic-bainitic structure morphology and anisotropy and steel performance characteristics have been established. Influence of thermal and deformation rolling patterns on steel structure has been studied. The steel chemical composition has been improved and precision thermomechanical processing conditions for production of cold-resistant Arc-steel plates have been developed.

Plutonic rocks in the Mineoka-Setogawa ophiolitic mélange, central Japan: Fragments of middle to lower crust of the Izu-Bonin-Mariana Arc?

NASA Astrophysics Data System (ADS)

Ichiyama, Yuji; Ito, Hisatoshi; Hokanishi, Natsumi; Tamura, Akihiro; Arai, Shoji

2017-06-01

A Paleogene accretionary complex, the Mineoka-Setogawa Belt, is distributed around the Izu Collision Zone, central Japan. Plutonic rocks of gabbro, diorite and tonalite compositions are included as fragments and dykes in an ophiolitic mélange in this belt. Zircon U-Pb dating of the plutonic rocks indicates that they were formed at ca. 35 Ma simultaneously. These ages are consistent with Eocene-Oligocene tholeiite and calc-alkaline arc magmatism in the Izu-Bonin-Mariana (IBM) Arc and exclude several previous models for the origin of the Mineoka-Setogawa ophiolitic rocks. The geochemical characteristics of these plutonic rocks are similar to those of the Eocene-Oligocene IBM tholeiite and calc-alkaline volcanic rocks as well as to the accreted middle crust of the IBM Arc, the Tanzawa Plutonic Complex. Moreover, their lithology is consistent with those of the middle and lower crust of the IBM Arc estimated from the seismic velocity structure. These lines of evidence strongly indicate that the plutonic rocks in the Mineoka-Setogawa ophiolitic mélange are fragments of the middle to lower crust of the IBM Arc. Additionally, the presence of the Mineoka-Setogawa intermediate to felsic plutonic rocks supports the hypothesis that intermediate magma can form continental crust in intra-oceanic arcs.

Effects of laser remelting on microstructures and immersion corrosion performance of arc sprayed Al coating in 3.5% NaCl solution

NASA Astrophysics Data System (ADS)

Sun, Ze; Zhang, Donghui; Yan, Baoxu; Kong, Dejun

2018-02-01

An arc sprayed aluminum (Al) coating on S355 steel was processed using a laser remelting (LR). The microstructures, chemical element composition, and phases of the obtained Al coating were analyzed using a field mission scanning electronic microscope (FESEM), energy dispersive spectrometer (EDS), and X-ray diffractometer (XRD), respectively, and the residual stresses were measured using an X-ray diffraction stress tester. The immersion corrosion tests and potentiodynamic polarization of Al coating in 3.5% NaCl solution were performed to investigate the effects of LR on its immersion corrosion behaviors, and the corrosion mechanism of Al coating was also discussed. The results show that the arc sprayed Al coating is composed of Al phase, while that by LR is composed of Al-Fe and AlO4FeO6 phases, and the porosities and cracks in the arc sprayed Al coating are eliminated by LR, The residual stress of arc sprayed Al coating is -5.6 ± 18 MPa, while that after LR is 137.9 ± 12 MPa, which deduces the immersion corrosion resistance of Al coating. The corrosion mechanism of arc sprayed Al coating is pitting corrosion and crevice corrosion, while that by LR is uniform corrosion and pitting corrosion. The corrosion potential of arc sprayed Al coating by LR shifts positively, which improves its immersion corrosion resistance.

Constraining the Compositional Heterogeneity in CO-Dominated Comet C/2016 R2 (PanSTARRS)

NASA Astrophysics Data System (ADS)

McKay, Adam; Kelley, Michael; DiSanti, Michael; Womack, Maria; Wierzchos, Kacper; Biver, Nicolas; de Val-Borro, Miguel; Cordiner, Martin; Dello Russo, Neil; Feaga, Lori; Bauer, James; Cochran, Anita; Harrington Pinto, Olga

2018-05-01

Comets exhibit a primitive volatile composition, making them invaluable tools for understanding the formation of the Solar System. Constraining the compositional heterogeneity of cometary nuclei is vital for interpreting cometary composition in terms of the physical conditions operating in the protosolar disk at the time of planet formation. Some comets exhibit variability in observed coma composition over the course of their orbit. This could be indicative of a heterogeneous nucleus consisting of cometesimals formed in different parts of the protosolar nebula under differing conditions. Alternatively, the observed heterogeneity could be post-formation evolution. We propose to use Spitzer IRAC observations of CO2 in the atypically CO-rich comet C/2016 R2 (PanSTARRS) to better understand the compositional heterogeneity of cometary nuclei.

High gain durable anti-reflective coating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maghsoodi, Sina; Brophy, Brenor L.; Colson, Thomas E.

Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers,more » Si--OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.« less

Polyimide resin composites via in situ polymerization of monomeric reactants

NASA Technical Reports Server (NTRS)

Cavano, P. J.

1974-01-01

Thermo-oxidatively stable polyimide/graphite-fiber composites were prepared using a unique in situ polymerization of monomeric reactants directly on reinforcing fibers. This was accomplished by using an aromatic diamine and two ester-acids in a methyl alcohol solvent, rather than a previously synthesized prepolymer varnish, as with other A-type polyimides. A die molding procedure was developed and a composite property characterization conducted with high modulus graphite fiber tow. Flexure, tensile, compressive, and shear tests were conducted at temperatures from 72 to 650 F on laminates before and after exposures at the given temperatures in an air environment for times up to 1000 hours. The composite material was determined to be oxidatively, thermally, and hydrolytically stable.

Major and trace element abundances in volcanic rocks of orogenic areas.

NASA Technical Reports Server (NTRS)

Jakes, P.; White, A. J. R.

1972-01-01

The composition of recent island-arc volcanic rocks in relation to their geographic and stratigraphic relations is discussed. The differences in composition between volcanic rocks and those in continental margins are pointed out. Trace elements and major elements are shown to suggest a continuous gradational sequence from tholeiites through calc-alkaline rocks to shoshonites.

COMPOSITIONAL LANDSCAPE METRICS AND LANDCOVER CONNECTIVITY MEASURES FOR THE SUB-WATERSHEDS OF THE UPPER SAN PEDRO RIVER 1973

EPA Science Inventory

Various compositional landscape metrics and landcover connectivity measures for the sub-watersheds of the Upper San Pedro River. Metrics were computed using the ATtILA v3.03 ArcView extension. Inputs included the sub-watershed coverage obtained from the USDA-ARS-SWRC in Tucson, A...

Correlation of Flux Composition and Inclusion Characteristics With Submerged Arc Weld Metal Properties in HY-100 Steel

DTIC Science & Technology

1993-09-01

chemistries are complex, the welding engineer needs to obtain the correct CCT diagram for the alloy system in question. Once the CCT diagram is estimated...the CCT diagram must be pertinent to the particular chemistry of the weld metal, especially when the weld metal composition varies with flux

Late Carboniferous to Early Permian magmatic pulses in the Uliastai continental margin linked to slab rollback: Implications for evolution of the Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Chai, Hui; Wang, Qingfei; Tao, Jixiong; Santosh, M.; Ma, Tengfei; Zhao, Rui

2018-05-01

The Paleo Asian Ocean underwent a protracted closure history during Late Paleozoic. Here we investigate the magmatic evolution during this process based on a detailed study in the Baiyinwula region along the Uliastai continental margin. The major rock types in this area are Late Carboniferous-Early Permian volcanic sequences and coeval intrusions. We identified four stages of magmatic evolution based on the diverse assemblages and their precise isotopic ages. The first stage is represented by andesites with a zircon 206Pb/238U age of ca. 326 ± 12 Ma. These rocks are metaluminous to weakly peraluminous, high-K calc-alkaline, and possess high Na2O/K2O ratios in the range of 1.23 to 2.45. They also display enrichment of large ion lithophile elements (LILE) and depletion of high field strength elements (HFSE), with markedly positive zircon εHf (t) varying from 8.1 to 15.6.The geochemical features of these andesites are similar to those of typical arc volcanic rocks. The second stage includes granodiorites emplaced at 318.6 + 1.8 Ma. The rocks are high-K calc-alkaline with A/CNK values ranging from 0.95 to 1.06, and show enrichment in LILE and depletion in HFSE. They show geochemical affinities to adakites, with high Sr and low Y and Yb contents, indicating magma derivation from thickened lower crust. Zircon grains from these rocks display positive initial εHf (t) values ranging from 11.1 to 14.6 with corresponding two-stage Hf model ages (TDM2) of 394-622 Ma. The third stage consists of syenogranite together with a volcanic suite ranging in composition from rhyolite todacite, which formed during 303.4 ± 1.2 to 285.1 ± 2.2 Ma. They possess elevated silica and alkali contents, high FeOt/MgO and Ga/Al ratios, low Al2O3, MgO and CaO contents, and high Rb, Y, Nb, Ce, Zr, Y, and Ga contents, strong negative Ba, Sr and Eu anomalies, showing I- to A-type granitic affinities. Zircons in these rocks show elevated Hf isotopic compositions (εHf (t) = 9.9 to 14.6) with TDM2 varying from 324 to 673 Ma. The fourth magmatic pulse is represented by K-feldspar granite with zircon U-Pb ages from 283.2 ± 1.9 Ma to 280.0 ± 1.4 Ma, and typical alkalic A-type granite geochemistry. These rocks possess positive εHf (t) values in the range of 9.7 to15.2, and a restricted range of Hf model age from 327 to 684 Ma. The magmatic rocks from the four stages show comparable εHf (t) and T2DM, suggesting that the magmas were derived from the same evolving mantle-derived source. We propose a tectonic model linking the evolution of the magmatism with the closure of the Paleo Asian Ocean that involved the following stages. The andesites were formed during the initial oceanic subduction stage with magma sourced from the metasomatized lithospheric mantle. Stage 2 adakite-like rocks were derived from subduction-induced thickened crust. Subsequent slab rollback resulted in asthenospheric upwelling and melting of residual juvenile crust to generate the I- and A- type syenogranite, rhyolite and dacite suite, finally followed by the A-type K-feldspar granite.

Picrite "Intelligence" from the Middle-Late Triassic Stikine arc: Composition of mantle wedge asthenosphere

NASA Astrophysics Data System (ADS)

Milidragovic, D.; Zagorevski, A.; Weis, D.; Joyce, N.; Chapman, J. B.

2018-05-01

Primitive, near-primary arc magmas occur as a volumetrically minor ≤100 m thick unit in the Canadian Cordillera of northwestern British Columbia, Canada. These primitive magmas formed an olivine-phyric, picritic tuff near the base of the Middle-Late Triassic Stuhini Group of the Stikine Terrane (Stikinia). A new 40Ar/39Ar age on hornblende from a cross-cutting basaltic dyke constrains the tuff to be older than 221 ± 2 Ma. An 87Sr/86Sr isochron of texturally-unmodified tuff samples yields 212 ± 25 Ma age, which is interpreted to represent syn-depositional equilibration with sea-water. Parental trace element magma composition of the picritic tuff is strongly depleted in most incompatible trace elements relative to MORB and implies a highly depleted ambient arc mantle. High-precision trace element and Hf-Nd-Pb isotopic analyses indicate an origin by mixing of a melt of depleted ambient asthenosphere with ≤2% of subducted sediment melt. Metasomatic addition of non-conservative incompatible elements through melting of subducted Panthalassa Ocean floor sediments accounts for the arc signature of the Stuhini Group picritic tuff, enrichment of light rare earth elements (LREE) relative to heavy rare earth elements (HREE) and high field strength elements (HFSE), and anomalous enrichment in Pb. The inferred Panthalassan sediments are similar in composition to the Neogene-Quaternary sediments of the modern northern Cascadia Basin. The initial Hf isotopic composition of the picritic tuff closely approximates that of the ambient Middle-Late Triassic asthenosphere beneath Stikinia and is notably less radiogenic than the age-corrected Hf isotopic composition of the Depleted (MORB) Mantle reservoir (DM or DMM). This suggests that the ambient asthenospheric mantle end-member experienced melt depletion (F ≤ 0.05) a short time before picrite petrogenesis. The mantle end-member in the source of the Stuhini Group picritic tuff is isotopically similar to the mantle source of enriched mid-ocean ridge basalts (E-MORB) erupted today at the southern end of the Explorer Ridge in northeastern Pacific Ocean. The isotopic similarity between the Middle-Late Triassic ambient mantle under Stikinia, and mantle presently tapped at the southern Explorer Ridge suggests that enriched domains in the northeastern Pacific mantle are long-lived (≥222 million years).

Characterization of carbon fiber polymer matrix composites subjected to simultaneous application of electric current pulse and low velocity impact

NASA Astrophysics Data System (ADS)

Hart, Robert James

2011-12-01

The use of composite materials in aerospace, electronics, and wind industries has become increasingly common, and these composite components are required to carry mechanical, electrical, and thermal loads simultaneously. A unique property of carbon fiber composites is that when an electric current is applied to the specimen, the mechanical strength of the specimen increases. Previous studies have shown that the higher the electric current, the greater the increase in impact strength. However, as current passes through the composite, heat is generated through Joule heating. This Joule heating can cause degradation of the composite and thus a loss in strength. In order to minimize the negative effects of heating, it is desired to apply a very high current for a very short duration of time. This thesis investigated the material responses of carbon fiber composite plates subjected to electrical current pulse loads of up to 1700 Amps. For 32 ply unidirectional IM7/977-3 specimens, the peak impact load and absorbed energy increased slightly with the addition of a current pulse at the time of an impact event. In 16 ply cross-ply IM7/977-2 specimens, the addition of the current pulse caused detrimental effects due to electrical arcing at the interface between the composite and electrodes. Further refinement of the experimental setup should minimize the risk of electrical arcing and should better elucidate the effects of a current pulse on the impact strength of the specimens.

Advent of Continents: A New Hypothesis

PubMed Central

Tamura, Yoshihiko; Sato, Takeshi; Fujiwara, Toshiya; Kodaira, Shuichi; Nichols, Alexander

2016-01-01

The straightforward but unexpected relationship presented here relates crustal thickness to magma type in the Izu-Ogasawara (Bonin) and Aleutian oceanic arcs. Volcanoes along the southern segment of the Izu-Ogasawara arc and the western Aleutian arc (west of Adak) are underlain by thin crust (10–20 km). In contrast those along the northern segment of the Izu-Ogasawara arc and eastern Aleutian arc are underlain by crust ~35 km thick. Interestingly, andesite magmas dominate eruptive products from the former volcanoes and mostly basaltic lavas erupt from the latter. According to the hypothesis presented here, rising mantle diapirs stall near the base of the oceanic crust at depths controlled by the thickness of the overlying crust. Where the crust is thin, melting occurs at relatively low pressures in the mantle wedge producing andesitic magmas. Where the crust is thick, melting pressures are higher and only basaltic magmas tend to be produced. The implications of this hypothesis are: (1) the rate of continental crust accumulation, which is andesitic in composition, would have been greatest soon after subduction initiated on Earth, when most crust was thin; and (2) most andesite magmas erupted on continental crust could be recycled from “primary” andesite originally produced in oceanic arcs. PMID:27669662

Applications of biotite inclusion composition to zircon provenance determination

NASA Astrophysics Data System (ADS)

Bell, Elizabeth A.; Boehnke, Patrick; Mark Harrison, T.

2017-09-01

Detrital zircons are the only confirmed surviving remnants of >4.03 Ga crust while younger detrital zircons provide a parallel record of more recent crustal evolution to that preserved in crystalline rocks. Zircons often preserve inclusions that may provide clues as to the origins of out-of-context grains in the sedimentary record. Previous studies have established that inclusions of biotite in magmatic zircon are compositionally well-matched to biotite in the source rock matrix, although a direct application to ancient detrital zircons has not been made. A number of studies have documented variations in the Fe, Mg, and Al contents of magmatic biotite from different source rocks and tectonic settings, suggesting that biotite inclusions may indeed serve as provenance indicators for detrital zircons. Consistent with earlier studies, we find that the FeO*/MgO ratio of magmatic biotite from continental arcs, collisional, and within-plate settings varies with relative oxidation state as well as whole-rock FeO*/MgO, while its Al2O3/(FeO* + MgO) varies with whole-rock A/CNK (molar Al/(2 ṡ Ca + Na + K)). Biotite from oxidized metaluminous and reduced S-type granitoids can be readily distinguished from each other using FeO*/MgO and Al2O3/(FeO* + MgO), while biotite from reduced I-type and oxidized peraluminous granites may in some cases be more ambiguous. Biotite from peralkaline and reduced A-type granites are also distinguishable from all other categories by Al2O3/(FeO* + MgO) and FeO*/MgO, respectively. Biotite inclusions in Hadean zircons from Jack Hills, Western Australia indicate a mixture of metaluminous and reduced S-type host rocks, while inclusions in 3.6-3.8 Ga detrital zircons from the Nuvvuagittuq Supracrustal Belt indicate more oxidized peraluminous magmas. These results highlight the diversity of felsic materials on the early Earth and suggest that biotite inclusions are applicable to zircon provenance throughout the sedimentary record.

Regional offshore geology of central and western Solomon Islands and Bougainville, Papua New Guinea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vedder, J.G.; Colwell, J.B.; Bruns, T.R.

The central and western Solomon Islands and the Bougainville regions are parts of a complex island-arc system that includes an intra-arc basin and remnants of both forearc and back-arc depositional wedges. These features formed in response to episodic Cenozoic tectonism along the convergent boundary between the Pacific and Australia-India plates. Presumed early Tertiary southwest-directed subduction of the Pacific plate and associated arc magmatism were curtailed by impingement of the leading edge of the Ontong Java Plateau. Aprons of back-arc and forearc sediment were derived from highstanding parts of the arc during the late Oligocene and early Miocene. Late Tertiary arc-polaritymore » reversal and northeastward-directed subduction of the Woodlark spreading system caused a renewal of island-arc magmatism that completed the construction of the Central Solomons Trough as an enclosed intra-arc basin. Interpretations of multichannel profiles from 1982 and 1984 CCOP/SOPAC Tripartite Cruises of the research vessel R/V S.P. Lee indicate that the Central Solomons Trough is a composite intra-arc basin containing as much as 5.5 km of late Oligocene(.) and younger sedimentary rocks. As many as five lenticular seismic-stratigraphic units can be identified on the basis of unconformities and abrupt velocity changes. Late Miocene and younger folds and faults deform the northeast and southwest flanks of the basin. Profiles across the Kilinailau Trench show Ontong Java Plateau rocks covered by 2-4 km of trench sediment. The inner trench wall consists of folded, upfaulted, and rotated blocks of trench and forearc strata. The deep-water basin northwest of Bougainville is a southeastward extension of the New Ireland forearc basin, the southern margin of which is formed by a subsided part of the early Cenozoic arc. There, Oligocene(.) and younger basin strata, as much as 7 km thick, are deformed by pre-Pliocene faults and folds.« less

Development and Processing of Nickel Aluminide-Carbide Alloys

NASA Technical Reports Server (NTRS)

Newport, Timothy Scott

1996-01-01

With the upper temperature limit of the Ni-based superalloys attained, a new class of materials is required. Intermetallics appear as likely candidates because of their attractive physical properties. With a relatively low density, high thermal conductivity, excellent oxidation resistance, high melting point, and simple crystal structure, nickel aluminide (NiAl) appears to be a potential candidate. However, NiAl is limited in structural applications due to its low room temperature fracture toughness and poor elevated temperature strength. One approach to improving these properties has been through the application of eutectic composites. Researchers have shown that containerless directional solidification of NiAl-based eutectic alloys can provide improvement in both the creep strength and fracture toughness. Although these systems have shown improvements in the mechanical properties, the presence of refractory metals increases the density significantly in some alloys. Lower density systems, such as the carbides, nitrides, and borides, may provide NiAl-based eutectic structure. With little or no information available on these systems, experimental investigation is required. The objective of this research was to locate and develop NiAl-carbide eutectic alloys. Exploratory arc-melts were performed in NiAl-refractory metal-C systems. Refractory metal systems investigated included Co, Cr, Fe, Hf, Mo, Nb, Ta, Ti, W, and Zr. Systems containing carbides with excellent stability (i.e.,HfC, NbC, TaC, TiC, and ZrC) produced large blocky cubic carbides in an NiAl matrix. The carbides appeared to have formed in the liquid state and were randomly distributed throughout the polycrystalline NiAl. The Co, Cr, Fe, Mo, and W systems contained NiAl dendrites with a two-phase interdendritic microconstituent present. Of these systems, the NiAl-Mo-C system had the most promising microstructure for in-situ composites. Three processing techniques were used to evaluate the NiAl-Mo-C system: arc-melting, slow cooling, and containerless directional solidification. Arc-melting provided a wide range of compositions in an economical and simple fashion. The slow cooled ingots provided larger ingots and slower cooling rates than arc-melting. Directional solidification was used to produce in-situ composites consisting of NiAl reinforced with molybdenum carbides.

Tracing chlorine sources of thermal and mineral springs along and across the Cascade Range using halogen and chlorine isotope compositions

USGS Publications Warehouse

Cullen, Jeffrey T.; Barnes, Jaime D.; Hurwitz, Shaul; Leeman, William P.

2015-01-01

In order to provide constraints on the sources of chlorine in spring waters associated with arc volcanism, the major/minor element concentrations and stable isotope compositions of chlorine, oxygen, and hydrogen were measured in 28 thermal and mineral springs along the Cascade Range in northwestern USA. Chloride concentrations in the springs range from 64 to 19,000 mg/L and View the MathML source values range from +0.2‰ to +1.9‰ (average=+1.0±0.4‰), with no systematic variation along or across the arc, nor correlations with their presumed underlying basement lithologies. Additionally, nine geochemically well-characterized lavas from across the Mt. St. Helens/Mt. Adams region of the Cascade Range (Leeman et al., 2004 and Leeman et al., 2005) were analyzed for their halogen concentrations and Cl isotope compositions. In the arc lavas, Cl and Br concentrations from the volcanic front are higher than in lavas from the forearc and backarc. F and I concentrations progressively decrease from forearc to backarc, similar to the trend documented for B in most arcs. View the MathML source values of the lavas range from −0.1 to +0.8‰ (average = +0.4±0.3‰). Our results suggest that the predominantly positive View the MathML source values observed in the springs are consistent with water interaction with underlying 37Cl-enriched basalt and/or altered oceanic crust, thereby making thermal spring waters a reasonable proxy for the Cl isotope compositions of associated volcanic rocks in the Cascades. However, waters with View the MathML source values >+1.0‰ also suggest additional contributions of chlorine degassed from cooling magmas due to subsurface vapor–liquid HCl fractionation in which Cl is lost to the aqueous fluid phase and 37Cl is concentrated in the ascending magmatic HCl vapor. Future work is necessary to better constrain Cl isotope behavior during volcanic degassing and fluid–rock interaction in order to improve volatile flux estimates through subduction zones.

The Diversity and Evolution of Different type Granitoids in Eastern Dharwar Craton: Evidence from "Arc-Plume" Collision in Neoarchaean

NASA Astrophysics Data System (ADS)

Nandy, J.; Dey, S.

2017-12-01

Neoarchaean crustal growth, role of plate tectonics and potential secular changes is still disoriented in Dharwar craton. To provide constraints on these questions, geochronological and geochemical data are presented on the unstudied granitoids associated with Kadiri greenstone belt, eastern Dharwar craton. Five diverse type of granitoids suites are identified in that area. Field setting, petrography, whole rock geochemistry study with Sm-Nd isotopes and zircon dates help to identify their source and petrogenesis. Along the eastern margin of the Kadiri belt a sanukitoid-like granitoid body is exposed which was probably derived from a metasomatised mantle wedge above a subduction zone followed by some older crustal contamination. Along the western margin transitional TTG is exposed displaying an intrusive relation with Kadiri dacite-rhyolite. This suite is interpreted to be derived from a mafic source with some enriched crustal component. Further east and west vast area is occupied highly silicic biotite monzogranite which is enriched in LILE, high K2O/Na2O. These granitoids are product of intracrustal shallow melting. At the south-eastern tip of the Kadiri belt occurs a well-foliated and banded transitional TTG which was probably derived from melting of mafic source with some contribution of felsic crustal material. At the north-eastern tip of the belt a highly silicic ferroan granitoid is exposed. Geochemical characteristics indicate that it is A-type granite, produced from shallow melting of a felsic crustal source. The basalt in greenstone belt is generated in oceanic plateau setting and granitoids in arc setting in different time. A tectonic scenario envisaging collision between an arc and oceanic plateau followed by repeated slab break-off and crustal recycling is proposed to explain the evolution of the terrain.

Anatexis, hybridization and the modification of ancient crust: Mesozoic plutonism in the Old Woman Mountains area, California

USGS Publications Warehouse

Miller, C.F.; Wooden, J.L.

1994-01-01

A compositionally expanded array of granitic (s.l.) magmas intruded the > 2 Ga crust of the Old Woman Mountains area between 160 and 70 Ma. These magmas were emplaced near the eastern (inland) edge of the Jurassic/Cretaceous arcs of western North America, in an area where magma flux, especially during the Jurassic, was considerably lower than to the west. The Jurassic intrusives and over half of the Cretaceous intrusives are predominantly metaluminous and variable in composition; a major Cretaceous suite comprises only peraluminous monzogranite. Only the Jurassic intrusions show clear evidence for the presence of mafic liquids. All units, including the most mafic rocks, reveal isotopic evidence for a significant crustal component. However, none of the Mesozoic intrusives matches in isotopic composition either average pre-intrusion crust or any major unit of the exposed crust. Elemental inconsistencies also preclude closed system derivation from exposed crust. Emplacement of these magmas, which doubled the volume of the mid- to upper crust, did not dramatically change its elemental composition. It did, however, affect its Nd and especially Sr isotopic composition and modify some of the distinctive aspects of the elemental chemistry. We propose that Jurassic magmatism was open-system, with a major influx of mantle-derived mafic magma interacting strongly with the ancient crust. Mesozoic crustal thickening may have led to closed-system crustal melting by the Late Cretaceous, but the deep crust had been profoundly modified by earlier Mesozoic hybridization so that crustal melts did not simply reflect the original crustal composition. The clear evidence for a crustal component in magmas of the Old Woman Mountains area may not indicate any fundamental differences from the processes at work elsewhere in this or other magmatic arcs where the role of pre-existing crust is less certain. Rather, a compositionally distinctive, very old crust may simply have yielded a more readily identifiable crustal fingerprint. The same processes that were involved here-mafic magma influx, hybridization, and remelting of hybridized crust-are likely to be typical of arc settings. ?? 1994.

Time-resolved ion energy and charge state distributions in pulsed cathodic arc plasmas of Nb‑Al cathodes in high vacuum

NASA Astrophysics Data System (ADS)

Zöhrer, Siegfried; Anders, André; Franz, Robert

2018-05-01

Cathodic arcs have been utilized in various applications including the deposition of thin films and coatings, ion implantation, and high current switching. Despite substantial progress in recent decades, the physical mechanisms responsible for the observed plasma properties are still a matter of dispute, particularly for multi-element cathodes, which can play an essential role in applications. The analysis of plasma properties is complicated by the generally occurring neutral background of metal atoms, which perturbs initial ion properties. By using a time-resolved method in combination with pulsed arcs and a comprehensive Nb‑Al cathode model system, we investigate the influence of cathode composition on the plasma, while making the influence of neutrals visible for the observed time frame. The results visualize ion detections of 600 μs plasma pulses, extracted 0.27 m from the cathode, resolved in mass-per-charge, energy-per-charge and time. Ion properties are found to be strongly dependent on the cathode material in a way that cannot be deduced by simple linear extrapolation. Subsequently, current hypotheses in cathodic arc physics applying to multi-element cathodes, like the so-called ‘velocity rule’ or the ‘cohesive energy rule’, are tested for early and late stages of the pulse. Apart from their fundamental character, the findings could be useful in optimizing or designing plasma properties for applications, by actively utilizing effects on ion distributions caused by composite cathode materials and charge exchange with neutrals.

Buckling Design and Analysis of a Payload Fairing One-Sixth Cylindrical Arc-Segment Panel

NASA Technical Reports Server (NTRS)

Kosareo, Daniel N.; Oliver, Stanley T.; Bednarcyk, Brett A.

2013-01-01

Design and analysis results are reported for a panel that is a 16th arc-segment of a full 33-ft diameter cylindrical barrel section of a payload fairing structure. Six such panels could be used to construct the fairing barrel, and, as such, compression buckling testing of a 16th arc-segment panel would serve as a validation test of the buckling analyses used to design the fairing panels. In this report, linear and nonlinear buckling analyses have been performed using finite element software for 16th arc-segment panels composed of aluminum honeycomb core with graphiteepoxy composite facesheets and an alternative fiber reinforced foam (FRF) composite sandwich design. The cross sections of both concepts were sized to represent realistic Space Launch Systems (SLS) Payload Fairing panels. Based on shell-based linear buckling analyses, smaller, more manageable buckling test panel dimensions were determined such that the panel would still be expected to buckle with a circumferential (as opposed to column-like) mode with significant separation between the first and second buckling modes. More detailed nonlinear buckling analyses were then conducted for honeycomb panels of various sizes using both Abaqus and ANSYS finite element codes, and for the smaller size panel, a solid-based finite element analysis was conducted. Finally, for the smaller size FRF panel, nonlinear buckling analysis was performed wherein geometric imperfections measured from an actual manufactured FRF were included. It was found that the measured imperfection did not significantly affect the panel's predicted buckling response

Tectonic control on the genesis of magmas in the New Hebrides arc (Vanuatu)

NASA Astrophysics Data System (ADS)

Beier, Christoph; Brandl, Philipp A.; Lima, Selma M.; Haase, Karsten M.

2018-07-01

We present here new bathymetric, petrological and geochemical whole rock, glass and mineral data from the submarine Epi volcano in the New Hebrides (Vanuatu) island arc. The structure has previously been interpreted to be part of a larger caldera structure but new bathymetric data reveal that the volcanic cones are aligned along shear zones controlled by the local tectonic stress field parallel to the recent direction of subduction. We aim to test if there is an interaction between local tectonics and magmatism and to what extent the compositions of island arc volcanoes may be influenced by their tectonic setting. Primitive submarine Epi lavas and those from the neighbouring Lopevi and Ambrym islands originate from a depleted mantle wedge modified by addition of subduction zone components. Incompatible element ratios sensitive to fluid input (e.g., Th/Nb, Ce/Yb) in the lavas are positively correlated with those more sensitive to mantle wedge depletion (e.g., Nb/Yb, Zr/Nb) amongst the arc volcanoes suggesting that fluids or melts from the subducting sediments have a stronger impact on the more depleted compositions of the mantle wedge. The whole rock, glass and mineral major and trace element compositions and the occurrence of exclusively normally zoned clinopyroxene and plagioclase crystals combined with the absence of inversely zoned crystals and water-bearing phases in both mafic and evolved lavas suggest that the erupted melt was relatively dry compared to other subduction zone melts and has experienced little disequilibrium modification by melt mixing or assimilation. Our data also imply that differentiation of amphibole is not required to explain the incompatible element patterns but may rather result from extensive clinopyroxene fractionation in agreement with petrographic observations. Thermobarometric calculations indicate that the melts fractionated continuously during ascent, contrasting with fractionation during stagnation in an established crustal magma reservoir. We interpret the occurrence of this fractional crystallisation end-member in a relatively thick island arc crust ( 30 km thickness) to result from isolated and relatively rapid ascent of melts, most likely through a complex system of dykes and sills that developed due to the tectonic positioning of Epi in a complex tectonic zone between a compressional environment in the north and an extensional setting in the south. We can show that the alignment of the cones largely depends on the local tectonic stress field at Epi that is especially influenced by a large dextral strike-slip zone, indicating that structural features have a significant impact on the location and composition of volcanic edifices.

Petrogenesis of Permian A-type granitoids in the Cihai iron ore district, Eastern Tianshan, NW China: Constraints on the timing of iron mineralization and implications for a non-plume tectonic setting

NASA Astrophysics Data System (ADS)

Zheng, Jiahao; Mao, Jingwen; Chai, Fengmei; Yang, Fuquan

2016-09-01

The geochronology and geochemistry of granitoids in the Eastern Tianshan, NW China provide important constraints on the timing of iron mineralization, as well as in understanding evolution history of the southern Central Asian Orogenic Belt (CAOB). Here we present results from a detailed study on granitoid rocks from the Cihai iron ore district in the Beishan region, southern part of the Eastern Tianshan. The granitoid rocks are composed of granodiorite, quartz monzonite, granite, and monzonite. Zircon U-Pb analyses yielded the ages of 294.1 ± 2.2 Ma, 286.5 ± 0.7 Ma, 284.3 ± 3.3 Ma, and 265.6 ± 3.0 Ma, respectively, suggesting they were formed in Early-Middle Permian. Among these granitoid rocks, the ages of quartz monzonite and granite are close to the timing of iron mineralization ( 282 Ma), indicating they may provide a source of iron in the Cihai ore district. Geochemically, the granodiorite, granite, and quartz monzonite samples are characterized by high FeOt/(FeOt + MgO) and Ga/Al ratios (0.84-0.94 and 2.28-3.27, respectively), as well as high zircon saturation temperatures (781-908 °C), similar to those of typical A-type granitoids. Isotopically, they display consistently depleted Hf isotopic compositions (εHf(t) = + 1.18 to + 15.37). Geological, geochemical, and isotopic data suggest that the Cihai A-type granitoids were derived from melting of juvenile lower crust. Some Early Permian A-type granitoids were recently identified in the Tarim and Eastern Tianshan with the ages between 294 and 269 Ma. The A-type granitoids in the Eastern Tianshan formed earlier between 294-284 Ma and exhibit characteristics of A2 type granitoids, whereas the A-type granitoids in the Tarim formed later between 277-269 Ma and show A1 granitoids affinity. We suggest that the Permian Tarim mantle plume does not account for the formation of the A-type granitoids in the Eastern Tianshan area, and the Eastern Tianshan was in a non-plume tectonic setting during Early Permian time. A slab break-off event has been suggested as the possible tectonic mechanism that triggered the formation of Early Permian A-type granitoids in the Eastern Tianshan.

Properties of thermal air plasma with admixing of copper and carbon

NASA Astrophysics Data System (ADS)

Fesenko, S.; Veklich, A.; Boretskij, V.; Cressault, Y.; Gleizes, A.; Teulet, Ph

2014-11-01

This paper deals with investigations of air plasma with admixing of copper and carbon. Model plasma source unit with real breaking arc was used for the simulation of real discharges, which can be occurred during sliding of Cu-C composite electrodes on copper wire at electromotive vehicles. The complex technique of plasma property studies is developed. From one hand, the radial profiles of temperature and electron density in plasma of electric arc discharge in air between Cu-C composite and copper electrodes in air flow were measured by optical spectroscopy techniques. From another hand, the radial profiles of electric conductivity of plasma mixture were calculated by solution of energy balance equation. It was assumed that the thermal conductivity of air plasma is not depending on copper or carbon vapor admixtures. The electron density is obtained from electric conductivity profiles by calculation in assumption of local thermodynamic equilibrium in plasma. Computed in such way radial profiles of electron density in plasma of electric arc discharge in air between copper electrodes were compared with experimentally measured profiles. It is concluded that developed techniques of plasma diagnostics can be reasonably used in investigations of thermal plasma with copper and carbon vapors.

Tephrostratigraphy and Provenance From IODP Expedition 352, Izu-Bonin Arc: Tracing Tephra Sources and Volumes From the Oligocene to Recent

NASA Astrophysics Data System (ADS)

Kutterolf, S.; Schindlbeck, J. C.; Robertson, A. H. F.; Avery, A.; Baxter, A. T.; Petronotis, K.; Wang, K.-L.

2018-01-01

Provenance studies of widely distributed tephras, integrated within a well-defined temporal framework, are important to deduce systematic changes in the source, scale, distribution, and changes in regional explosive volcanism. Here, we establish a robust tephrochronostratigraphy for a total of 157 marine tephra layers collected during IODP Expedition 352. We infer at least three major phases of highly explosive volcanism during Oligocene to Pleistocene time. Provenance analysis based on glass composition assigns 56 of the tephras to a Japan source, including correlations with 12 major and widespread tephra layers resulting from individual eruptions in Kyushu, Central Japan, and North Japan between 115 ka and 3.5 Ma. The remaining 101 tephras are assigned to four source regions along the Izu-Bonin arc. One, exclusively assigned to the Oligocene age, is proximal to the Bonin Ridge islands; two reflect eruptions within the volcanic front and back-arc of the central Izu-Bonin arc, and a fourth region corresponds to the Northern Izu-Bonin arc source. First-order volume estimates imply eruptive magnitudes ranging from 6.3 to 7.6 for Japan-related eruptions and between 5.5 and 6.5 for IBM eruptions. Our results suggest tephras between 30 and 22 Ma reflect a subtly different Izu-Bonin chemical signature compared to the recent arc. After a ˜9 Ma gap in eruption, tephra supply from the Izu-Bonin arc predominated from 15 to 5 Ma, and finally a subequal mixture of tephra sources from the (palaeo)Honshu and Izu-Bonin arcs occured within the last ˜5 Ma.

Clinopyroxene composition of volcanics from the Manipur Ophiolite, Northeastern India: implications to geodynamic setting

NASA Astrophysics Data System (ADS)

Ovung, Thungyani N.; Ray, Jyotisankar; Ghosh, Biswajit; Koeberl, Christian; Topa, Dan; Paul, Madhuparna

2017-08-01

The volcanic section of the Manipur Ophiolite (MO), representing the crustal portion of the Neo-Tethyan oceanic lithosphere occurs as basalt, basaltic trachyandesite, and dacite in the Gamnom-Phangrei sector, Manipur, at 25°01'N-25°09'N and 94°24'E-94°27'E. They associate with cherts and ultramafics. The clinopyroxene compositions of basalt and basaltic trachyandesite, obtained through electron microprobe analyzer, were used as a petrogenetic indicator to identify the parent magma-types and their tectonic settings. Based on the variable content of major oxides, they are classified as high- and low-Ti clinopyroxenes. High Ti and Al contents with relatively lower silica saturation are observed in the former group and vice versa in the latter. The TiDCpx/rock values in low- and high-Ti clinopyroxene are comparable with island-arc basaltic andesite and MORB, respectively, which confirms that the clinopyroxene composition is primarily related to the host magma-type and its tectonic setting. Clinopyroxene thermometry (ranging 1150-605 °C) suggests progressive differentiation of the parent magmas. Several bivariate and tectonic discrimination diagrams depict MORB (non-orogenic setting) and island-arc boninitic magma affinities (orogenic setting) for the high- and low-Ti clinopyroxenes, respectively. The coexistence of both MORB and island-arc boninitic magma-types in the volcanic section of Manipur Ophiolite as characterized by their varying Ti, Al, and Si contents may indicate either juxtaposition of rocks formed in diverse tectonic settings (i.e., due to transformation of tectonic setting from mid-ocean ridge to supra-subduction zone) or, a change in magma composition in a subduction zone setting. However, field relationships coupled with the mineral-chemical signatures implies a supra-subduction zone setting for the evolution of the crustal section of MO.

Scanning and transmission electron microscopy study of the microstructural changes occurring in aluminium matrix composites reinforced with SiC particles during casting and welding: interface reactions

PubMed

Urena; Gomez De Salazar JM; Gil; Escalera; Baldonedo

1999-11-01

Processing of aluminium matrix composites (AMCs), especially those constituted by a reactive system such as Al-SiC, presents great difficulties which limit their potential applications. The interface reactivity between SiC and molten Al generates an aluminium carbide which degrades the composite properties. Scanning and transmission electron microscopes equipped with energy-dispersive X-ray spectroscopes are essential tools for determining the structure and chemistry of the Al-SiC interfaces in AMCs and changes occurring during casting and arc welding. In the present work, an aluminium-copper alloy (AA2014) reinforced with three different percentages of SiC particles was subjected to controlled remelting tests, at temperatures in the range 750-900 degrees C for 10 and 30 min. Arc welding tests using a tungsten intert gas with power inputs in the range 850-2000 W were also carried out. The results of these studies showed that during remelting there is preferential SiC particle consumption with formation of Al4C3 by interface reaction between the solid SiC particle and the molten aluminium matrix. The formation of Al4C3 by the same mechanism has also been detected in molten pools of arc welded composites. However, in this case there was formation of an almost continuous layer of Al4C3, which protects the particle against further consumption, and formation of aciculate aluminium carbide on the top weld. Both are formed by fusion and dissolution of the SiC in molten aluminium followed by reaction and precipitation of the Al4C3 during cooling.

Clinopyroxene composition of volcanics from the Manipur Ophiolite, Northeastern India: implications to geodynamic setting

NASA Astrophysics Data System (ADS)

Ovung, Thungyani N.; Ray, Jyotisankar; Ghosh, Biswajit; Koeberl, Christian; Topa, Dan; Paul, Madhuparna

2018-06-01

The volcanic section of the Manipur Ophiolite (MO), representing the crustal portion of the Neo-Tethyan oceanic lithosphere occurs as basalt, basaltic trachyandesite, and dacite in the Gamnom-Phangrei sector, Manipur, at 25°01'N-25°09'N and 94°24'E-94°27'E. They associate with cherts and ultramafics. The clinopyroxene compositions of basalt and basaltic trachyandesite, obtained through electron microprobe analyzer, were used as a petrogenetic indicator to identify the parent magma-types and their tectonic settings. Based on the variable content of major oxides, they are classified as high- and low-Ti clinopyroxenes. High Ti and Al contents with relatively lower silica saturation are observed in the former group and vice versa in the latter. The TiDCpx/rock values in low- and high-Ti clinopyroxene are comparable with island-arc basaltic andesite and MORB, respectively, which confirms that the clinopyroxene composition is primarily related to the host magma-type and its tectonic setting. Clinopyroxene thermometry (ranging 1150-605 °C) suggests progressive differentiation of the parent magmas. Several bivariate and tectonic discrimination diagrams depict MORB (non-orogenic setting) and island-arc boninitic magma affinities (orogenic setting) for the high- and low-Ti clinopyroxenes, respectively. The coexistence of both MORB and island-arc boninitic magma-types in the volcanic section of Manipur Ophiolite as characterized by their varying Ti, Al, and Si contents may indicate either juxtaposition of rocks formed in diverse tectonic settings (i.e., due to transformation of tectonic setting from mid-ocean ridge to supra-subduction zone) or, a change in magma composition in a subduction zone setting. However, field relationships coupled with the mineral-chemical signatures implies a supra-subduction zone setting for the evolution of the crustal section of MO.

The Molybdenum Isotope System as a Tracer of Slab Input in Subduction Zones: An Example From Martinique, Lesser Antilles Arc

NASA Astrophysics Data System (ADS)

Gaschnig, Richard M.; Reinhard, Christopher T.; Planavsky, Noah J.; Wang, Xiangli; Asael, Dan; Chauvel, Catherine

2017-12-01

Molybdenum isotopes are fractionated by Earth-surface processes and may provide a tracer for the recycling of crustal material into the mantle. Here, we examined the Mo isotope composition of arc lavas from Martinique in the Lesser Antilles arc, along with Cretaceous and Cenozoic Deep Sea Drilling Project sediments representing potential sedimentary inputs into the subduction zone. Mo stable isotope composition (defined as δ98Mo in ‰ deviation from the NIST 3134 standard) in lavas older than ˜7 million years (Ma) exhibits a narrow range similar to and slightly higher than MORB, whereas those younger than ˜7 Ma show a much greater range and extend to unusually low δ98Mo values. Sediments from DSDP Leg 78A, Site 543 have uniformly low δ98Mo values whereas Leg 14, Site 144 contains both sediments with isotopically light Mo and Mo-enriched black shales with isotopically heavy Mo. When coupled with published radiogenic isotope data, Mo isotope systematics of the lavas can be explained through binary mixing between a MORB-like end-member and different sedimentary compositions identified in the DSDP cores. The lavas older than ˜7 Ma were influenced by incorporation of isotopically heavy black shales into the mantle wedge. The younger lavas are the product of mixing isotopically light sedimentary material into the mantle wedge. The change in Mo isotope composition of the lavas at ˜7 Ma is interpreted to reflect the removal of the Cretaceous black shale component due to the arrival of younger ocean crust where the age-equivalent Cretaceous sediments were deposited in shallower oxic waters. Isotopic fractionation of Mo during its removal from the slab is not required to explain the observed systematics in this system.

Investigation of anatomical anomalies in Hanford Site mule deer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiller, B.L.; Cadwell, L.L.; Poston, T.M.

Rocky Mountain mule deer (Odocoileus hemionus hemionus), common residents of the Hanford Site, are an important part of the shrub-steppe ecosystem as well as being valued for aesthetics and hunting. Because mule deer have been protected from hunting on the Site for 50 years, the herd has developed unique population characteristics, including a large number of old animals and males with either large or atypically developed antlers, in contrast to other herds in the semi-arid regions of the Northwest. Hanford Site mule deer have been studied since 1991 because of the herd`s unique nature and high degree of public interest.more » A special study of the mule deer herd was initiated in 1993 after observations were made of a relatively large number of male deer with atypical, velvet-covered antlers. This report specifically describes our analyses of adult male deer found on the Site with atypical antlers. The report includes estimates of population densities and composition; home ranges, habitat uses, and dietary habits; natural and human-induced causes of mortality; and the herd`s overall health and reproductive status.« less

High-transition-temperature superconductors in the Nb-Al-Ge system

DOEpatents

Giorgi, A.L.; Szklarz, E.G.

1972-09-26

The patent describes superconducting materials of the nominal composition Nb(x)Al(y)Ge(l-y), where x is in the range of 1.9 to 2.8 and y is in the range of 0.5 to 0.9, having transition temperatures in the 19 -20K. range which are readily produced by annealing arc-melted compositions, or cold-pressed, heat-treated compositions at moderate temperatures for reasonably long times (about 50 hours).

[Calculating the stark broadening of welding arc spectra by Fourier transform method].

PubMed

Pan, Cheng-Gang; Hua, Xue-Ming; Zhang, Wang; Li, Fang; Xiao, Xiao

2012-07-01

It's the most effective and accurate method to calculate the electronic density of plasma by using the Stark width of the plasma spectrum. However, it's difficult to separate Stark width from the composite spectrum linear produced by several mechanisms. In the present paper, Fourier transform was used to separate the Lorentz linear from the spectrum observed, thus to get the accurate Stark width. And we calculated the distribution of the TIG welding arc plasma. This method does not need to measure arc temperature accurately, to measure the width of the plasma spectrum broadened by instrument, and has the function to reject the noise data. The results show that, on the axis, the electron density of TIG welding arc decreases with the distance from tungsten increasing, and changes from 1.21 X 10(17) cm(-3) to 1.58 x 10(17) cm(-3); in the radial, the electron density decreases with the distance from axis increasing, and near the tungsten zone the biggest electronic density is off axis.

New osmium isotope evidence for intracrustal recycling of crustal domains with discrete ages

USGS Publications Warehouse

Hart, G.L.; Johnson, C.M.; Hildreth, W.; Shirey, S.B.

2003-01-01

New 187Os/188Os ratios of Quaternary Mount Adams volcanic rocks from the Cascade arc in southern Washington vary by >300% (187Os/188Os = 0.165-0.564) and fall into high (>0.319) and low (0.166 to 0.281) groups of 187Os/188Os ratios that are substantially more radiogenic than mantle values. These Os isotope compositions and groupings are interpreted to reflect recycling of discrete intracrustal domains with high 187Os/188Os ratios but differing ages, thus recording the process of crustal hybridization and homogenization. Os isotope compositions provide new constraints on amounts of intracrustal recycling in young subduction-zone environments that reflect the magmatic history of the arc. Sr, Nd, Hf, and Pb isotope variations in this young, mafic are complex are too small to allow such constraints.

Improving the corrosion properties of magnesium AZ31 alloy GTA weld metal using microarc oxidation process

NASA Astrophysics Data System (ADS)

Siva Prasad, M.; Ashfaq, M.; Kishore Babu, N.; Sreekanth, A.; Sivaprasad, K.; Muthupandi, V.

2017-05-01

In this work, the morphology, phase composition, and corrosion properties of microarc oxidized (MAO) gas tungsten arc (GTA) weldments of AZ31 alloy were investigated. Autogenous gas tungsten arc welds were made as full penetration bead-on-plate welding under the alternating-current mode. A uniform oxide layer was developed on the surface of the specimens with MAO treatment in silicate-based alkaline electrolytes for different oxidation times. The corrosion behavior of the samples was evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy. The oxide film improved the corrosion resistance substantially compared to the uncoated specimens. The sample coated for 10 min exhibited better corrosion properties. The corrosion resistance of the coatings was concluded to strongly depend on the morphology, whereas the phase composition and thickness were concluded to only slightly affect the corrosion resistance.

A Study on the Deposition of Al2O3 Coatings on Polymer Substrates by a Plasma Spray/Micro-Arc Oxidation Two-Step Method

NASA Astrophysics Data System (ADS)

Sun, Guanhong; He, Xiaodong; Jiang, Jiuxing; Sun, Yue; Zhong, Yesheng

2013-02-01

To increase the wear resistance of polymer matrix composites, alumina coatings were deposited on polymer substrates by a two-step method combining plasma spraying and micro-arc oxidation. The microstructures and phase compositions of the processed coatings were investigated for different treatment times. Uniformly distributed pores were found in addition to the presence of various coral-like structures and floccules on the surface of the coatings. The presence of α-Al2O3 and γ-Al2O3 phases was identified by XRD. The distribution of alumina was analyzed by EDS and is discussed. The maximum bond strength of the coatings was found to be 5.89 MPa. There was little thermal damage in the polymer substrates after the coatings were produced.

Petrography and geochemistry of clastic rocks within the Inthanon zone, northern Thailand: Implications for Paleo-Tethys subduction and convergence

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Kunii, Miyuki; Hisada, Ken-ichiro; Ueno, Katsumi; Kamata, Yoshihito; Srichan, Weerapan; Charusiri, Punya; Charoentitirat, Thasinee; Watarai, Megumi; Adachi, Yoshiko; Kurihara, Toshiyuki

2012-11-01

The provenance, source rock compositions, and sediment supply system for a convergence zone of the Paleo-Tethys were reconstructed based on the petrography and geochemistry of clastic rocks of the Inthanon Zone, northern Thailand. The clastic rocks are classified into two types based on field and microscopic observations, the modal composition of sandstone, and mineral compositions: (1) lithic sandstone and shale within mélange in a Permo-Triassic accretionary complex; and (2) Carboniferous quartzose sandstone and mudstone within the Sibumasu Block. Geochemical data indicate that the clastic rocks of the mélange were derived from continental island arc and continental margin settings, which correspond to felsic volcanic rocks within the Sukhothai Zone and quartz-rich fragments within the Indochina Block, respectively. The results of a mixing model indicate the source rocks were approximately 35% volcanic rocks of the Sukhothai Zone and 65% craton sandstone and upper continental crust of the Indochina Block. In contrast, Carboniferous quartzose sedimentary rocks within the Sibumasu Block originated from a continental margin, without a contribution from volcanic rocks. In terms of Paleo-Tethys subduction, a continental island arc in the Sukhothai Zone evolved in tandem with Late Permian-Triassic forearc basins and volcanic activity during the Middle-early Late Triassic. The accretionary complex formed contemporaneously with the evolution of continental island arc during the Permo-Triassic, supplied with sediment from the Sukhothai Zone and the Indochina Block.

Characterization and Properties of Micro-arc Composite Ceramic Coatings on Magnesium Alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Long; Jiang, Bailing; Ge, Yanfeng

2013-05-21

Magnesium alloys are of growing interest for many industrial applications due to their favorable strength-to-weight ratio and excellent cast ability. However, one of the limiting factors in the use of magnesium on production vehicles is its poor corrosion resistance. Micro-arc Composite Ceramic (MCC) coatings on AZ91D magnesium alloys were prepared in combination with Micro-arc Oxidation (MAO) and electrophoresis technologies. The microstructure, corrosion resistance, abrasion resistance, stone impact resistance, thermal shock resistance and adhesion of MCC coating were studied, respectively. The surface and cross-section morphologies of MAO and MCC coating showed that the outer organic coating filled the holes on themore » surface of the MAO coating. It acted as a shelter on the MAO coating surface when the MCC coatings were exposed to corrosive environments. The corrosion resistance of the MCC coating was characterized by a copper-accelerated acetic acid salt spray test. The testing results showed that the creep back from scribe lines was less than 1mm and completely fit the evaluation standard. The composite structure of the MCC coating vastly improved the corrosion resistance of Mg alloys. According to testing standards, the resistance to abrasion, stone impact resistance, thermal shock resistance and adhesion of MCC coatings completely met the evaluation standard requirements. The MCC coated AZ91D magnesium alloys possessed excellent properties; this is a promising corrosion and wear resistance surface treatment technology on magnesium alloys for production vehicles.« less

Influence of matrix metalloproteinase synthetic inhibitors on dentin microtensile bond strength of resin cements.

PubMed

Stape, T H S; Menezes, M S; Barreto, B C F; Aguiar, F H B; Martins, L R; Quagliatto, P S

2012-01-01

This study evaluated the effect of dentin pretreatment with 2% chlorhexidine (CHX) or 24% ethylenediamine tetra-acetic acid gel (EDTA) on the dentin microtensile bond strength (μTBS) of resin cements. Composite blocks were luted to superficial noncarious human dentin (n=10) using two resin cements (RelyX ARC [ARC] and RelyX U100 [U100]) and three dentin pretreatments (without pretreatment-control, CHX, and EDTA). CHX was applied for 60 seconds on the acid-etched dentin in the ARC/CHX group, and for the same time on smear layer-covered dentin in the U100/CHX group. EDTA was applied for 45 seconds on smear-covered dentin in the U100/EDTA group, and it replaced phosphoric acid conditioning in the ARC/EDTA group for 60 seconds. After storage in water for 24 hours, specimens were prepared for microtensile bond strength testing. The results were submitted to two-way analysis of variance (ANOVA) followed by Tukey test. ARC produced significantly higher μTBS (p<0.05) compared to the U100, except when EDTA was used. For ARC, no pretreatment and CHX produced higher μTBS than EDTA. For U100, EDTA produced higher μTBS; no statistical difference occurred between CHX pretreatment and when no pretreatment was performed. While CHX did not affect immediate dentin bond strength of both cements, EDTA improved bond strength of U100, but it reduced dentin bond strength of ARC.

Magnesium isotope geochemistry in arc volcanism.

PubMed

Teng, Fang-Zhen; Hu, Yan; Chauvel, Catherine

2016-06-28

Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ(26)Mg of the Martinique Island lavas varies from -0.25 to -0.10, in contrast to the narrow range that characterizes the mantle (-0.25 ± 0.04, 2 SD). These high δ(26)Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid-mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration.

Evaluation of degree of conversion and the effect of thermal aging on the color stability of resin cements and flowable composite.

PubMed

Prieto, Lúcia Trazzi; Pimenta de Araújo, Cíntia Tereza; Araujo Pierote, Josué Junior; Salles de Oliveira, Dayane Carvalho Ramos; Coppini, Erick Kamiya; Sartini Paulillo, Luís Alexandre Maffei

2018-01-01

The aim of this in vitro study was to evaluate the color stability and degree of conversion (DC) of dual-cure and light-cure cements and flowable composites after thermal aging. A total of 50 human incisors were prepared and divided into six groups ( n = 10). Veneers were fabricated using IPS Empress Direct composite resin were bonded with three types of luting agents: Light-cured, conventional dual, and flowable composite according to the manufacturer's instructions. The groups were as follows: Filtek Z350XT Flow/Single Bond 2, RelyX ARC/Single Bond 2, RelyX Veneer/Single Bond 2, Tetric N-Flow/Tetric N-Bond, and Variolink II/Tetric N-Bond. Commission Internationale de l'Éclairage L*, a* and b* color coordinates were measured 24 h after cementation procedure with a color spectrophotometer and reevaluated after 10,000 thermal cycles. To evaluate the DC 50 specimens ( n = 10) of each resin material were obtained and Fourier transform infrared spectroscopy was used to evaluate the absorption spectra. Statistical analysis was performed with one-way ANOVA and Tukey's test (α = 0.05). No statistically significant differences in ΔE* occurred after aging. The greatest change in lightness occurred in the Variolink II resin cement. Changes in red-green hue were very small for the same cement and largest in the Tetric N-Flow flowable resin composite, while the greatest change in blue-yellow hue was a yellowing of the RelyX ARC luting cement. RelyX ARC exhibited the highest DC, and there were no statistically significant differences in DC among the other cements. Resin-based luting agent might affect the final of ceramic veneer restorations. The thermal aging affected the final color of the evaluated materials, and these were regarded as clinically unacceptable (ΔE >3.3).

Geochemical Character of the Aono Volcanic Group in SW Japan Arc: Implications for Genetic Relationship between Slab Melting and EM Isotopic Signature

NASA Astrophysics Data System (ADS)

Shimoda, G.; Shinjoe, H.; Kogiso, T.; Ishizuka, O.; Yamashita, K.; Yoshitake, M.; Itoh, J.; Ogasawara, M.

2016-12-01

The SW Japan arc is characterized by active subduction of a relatively young (15-26 Ma) segment of the Philippine Sea plate, Shikoku basin, beneath the Eurasian plate and is known for the occurrence of adakites on the quaternary volcanic front. As adakite is typically generated in subduction zones, where high geothermal gradients can be attained in the slab, the adakite magmas are considered to be produced by slab melting. From this perspective, adakites are considered to be modern geochemical analogues of the tonalite-trondhjemite-granodiorite (TTG) suite that can be a major constituent of early continental crust. It has been inferred that recycling of continental crustal material back into the mantle could be a possible origin of enriched mantle reservoirs, such as EM1 and EM2. In order to reveal the role of slab melting on the production of EM isotopic signature, we have conducted a detailed major/trace element and Pb-Nd-Sr isotopic study of 17 adakites from Aono volcanic group in the western end of Honshu Island. The isotopic compositions of the Aono volcanic rocks clearly form a mixing line between the Shikoku back arc basin basalts and local sediments from the Nankai Trough. In addition, the isotopic compositions of Aono adakites have depleted isotopic composition showing some overlap with subducted Shikoku basin basalts. This may imply that the chemical composition of Aono adakites could be mainly derived from Shikoku basin basalts as pointed out by recent work (Kimura et al., 2014). Accordingly, the effect of crustal contamination or sediment melting could be relatively small. On the basis of this assumption, the chemical composition of Aono adakites are used to estimate the chemical fractionation during slab melting. In this presentation, we will present new results of isotopic and trace element analyses of adakites from Aono volcanic group in the SW Japan and discuss role of slab melting in the production of EM reservoirs.

Temporal Geochemical Variations in Glass and Minerals from Early Oligocene to Miocene Volcanic Sediments, DSDP Site 296, Kyushu Palau Ridge: Is There a Geochemical Signal for Arc Rifting?

NASA Astrophysics Data System (ADS)

Hickey-Vargas, R.; Samajpati, E.

2015-12-01

Volcaniclastic sediments and sedimentary rocks from DSDP Site 296, located within a basin at the crest of the northern Kyushu Palau ridge (KPR), record the latter part of the first stage of Izu Bonin Mariana (IBM) arc evolution, up to the cessation of volcanism caused by arc rifting and opening of the Shikoku basin. The lower section consists of early to late Oligocene coarse volcaniclastic sedimentary rocks, and is overlain by late Oligocene to Pleistocene nannofossil chalks and oozes with volcanic sand and ash-rich layers. We have studied the chemical composition of pyroxene, feldspar and glass grains separated from the coarse volcaniclastic rocks at depths from 435 to 1082 meters below sea floor, and of glass shards in layers in the overlying sediments of late Oligocene to early Miocene age. Overall, pyroxene and feldspar compositions show little systematic variation with depth in the core, although for pyroxene, highest En and highest Al2O3 contents are found in the interval from 600-900 meters bsf. An contents in feldspars show a bimodal distribution throughout the core, with most values > 90 or in the range 60-70, with more abundant intermediate compositions in the 600-900 meter interval. Compositions of glass shards vary widely, from basalt to rhyolite, and from low K, light rare earth (LREE)-depleted to high K, strongly LREE-enriched character, without systematic variation with depth in the core. However, all cores sampled from early Oligocene to early Miocene contain relatively low K basalt and basaltic andesite glass. Like the pyroxenes, a wider range of compositions is found in glass from the 600 to 900 mbsf interval. The Site 296 sequence overlaps in age with the uppermost sedimentary section of recently drilled IODP Site 1438, located 230 km to the southwest in the Amami Sankaku basin, thus the two sites may contain volcanic debris shed from contemporaneous sections of the KPR.

Mineral complexities as evidence for open-system processes in intermediate magmas of the Mount Baker volcanic field, northern Cascade arc

NASA Astrophysics Data System (ADS)

Escobar-Burciaga, R. D.; DeBari, S. M.

2015-12-01

The petrogenesis of intermediate magmas in arcs is a critical contribution to crustal growth. Andesites are commonly thought of as a hybrid product, the result of two endmember magmas mixing. At the Mount Baker volcanic field (MBVF), northern Cascade arc, andesites are the predominantly erupted lavas since 1 Ma and yet their origin is poorly constrained. Previous studies have suggested that open-system processes play a dominant role. However, the studies rely heavily on bulk rock compositions and overlook complex mineral textures and compositions. To better understand the complex processes at work at MBVF, we focus on establishing mineral and crystal clot populations in three andesitic flow units (55-59% SiO2). Petrographic and geochemical analyses suggest that variable-composition crystal clot and phenocryst populations in a single flow are related. We interpret the crystal clots to represent cumulates entrained in the erupting host magma and that related phenocrysts are disaggregates of crystal clots. The existence of common, multiple phenocryst and crystal clot populations in each flow of different age and SiO2 content provides strong evidence that intermediate magmas of MBVF are more than just the end product of mixing between two magmas. Furthermore, we suggest that most phenocrysts do not represent equilibrium products of their host liquid, evident from wide compositional ranges of ferromagnesian minerals (e.g. augite core Mg# 70-87). In fact, the most primitive phenocryst populations show the least amount of disequilibrium texture but represent assemblages expected to fractionate from basaltic to basaltic-andesitic liquids rather than equilibrium assemblages from their host bulk rock "liquid" composition. As a result, we interpret the variable SiO2 signature of the three andesitic flow units to have been obtained through the incorporation of cumulates/liquids as basaltic to basaltic-andesitic magma ascends.

Regional Variations in Aleutian Magma Composition

NASA Astrophysics Data System (ADS)

Nye, C. J.

2008-12-01

This study is based on sample data spanning 20 years from USGS, UAF, and DGGS geologists too numerous to list here. The 2900-km long Aleutian arc contains more than 50 active and over 90 Holocene volcanoes. The arc is built on oceanic Bering-sea floor west of 166W and quasi-continental crust east of 166W. Over the past twenty years the Alaska Volcano Observatory has conducted baseline geologic mapping (or remapping) and volcanic-hazards studies of selected volcanoes - generally those targeted for geophysical monitoring. This marks the largest sustained effort to study Aleutian volcanoes in half a century; AVO scientists have logged as many as 700 person-days per field season. Geologic studies have resulted in comprehensive suites of stratigraphically constrained samples and more than 3500 new whole-rock analyses by XRF and ICP/MS from more than 30 centers, more than doubling the number of previously published analyses. Examination of the data for regional and inter-volcano variations yields a number of first-order observations. (1) The arc can be broadly divided into an eastern segment (east of 158W) of calcalkaline andesite stratocones; a central segment dominated by large, mafic, tholeiitic shield volcanoes and stratocones; and a western segment (west of 175W) of smaller volcanoes with variable morphologies and generally more andesitic compositions. (2) There are NO significant first-order compositional signals that coincide with the transition from oceanic to continental basement. (3) Individual volcanoes are often subtly distinct from neighbors, and those distinctions persist for the lifetime of the centers. (4) All centers, notably including the large basaltic centers of the central arc, are strongly affected by open-system processes significantly more complicated than mixing among sibling-fractionates of parental mafic magmas. (5) Petrogenetic pathways are long-lived; individual batches of magma are (generally) not. (6) Calcalkaline andesites have dramatically lower REE and HFSE, yet higher Cr and Ni than tholeiitic andesites, suggesting that it is overly simplistic to consider calcalkaline andesites to be simple fractionates of basalts.

The deep layers of a Paleozoic arc: geochemistry of the Copley-Balaklala series, northern California

NASA Astrophysics Data System (ADS)

Brouxel, Marc; Lapierre, Henriette; Michard, Annie; Albarède, Francis

1987-10-01

REE, Zr, Nb concentrations and Sr, Nd isotope compositions have been measured in Copley basalts and andesites, Balaklala rhyolites, and Mule Mountain trondhjemites (northern California) which represent the deep layers of a well preserved intra-oceanic island arc of Siluro-Devonian age. 87Sr/ 86Sr is shifted towards high values (up to 0.707) whereas Ce is preferentially removed from rhyolites. A large proportion of the analyzed samples including some acidic rocks shows a pronounced depletion in light REE. The ɛ Nd(T) values of most Copley, Balaklala, and Mule Mountain rocks fall in the range +6 to +8 which suggests that they originated from a normal MORB-type source ( ɛ Nd(T) ≈ +9 ) contaminated with either sediments or an OIB-type component. In modern island arcs, only the shallow levels are accessible: comparison with the Copley-Balaklala-Mule Mountain Series suggests that, at depth, an immature island arc is likely to comprise thick layers of LILE-depleted tholeiites and rhyolites intensely altered by pervasive circulation of seawater. Least-square solutions of trace element models suggest that rhyolites and trondhjemites represent remelting of mafic volcanics from the arc basement rather than residual melts of basalt-andesite differentiation.

Relation Between the Arc-Root Fluctuations, the Cold Boundary Layer Thickness and the Particle Thermal Treatment

NASA Astrophysics Data System (ADS)

Noguès, E.; Fauchais, P.; Vardelle, M.; Granger, P.

2007-12-01

In plasma spraying, the arc-root fluctuations, modifying the length and characteristics of the plasma jet, have an important influence on particle thermal treatment. These voltage fluctuations are strongly linked to the thickness of the cold boundary layer (CBL), surrounding the arc column. This thickness depends on the plasma spray parameters (composition and plasma forming gas mass flow rate, arc current, etc.) and the plasma torch design (anode-nozzle internal diameter and shape, etc.). In order to determine the influence of these different spray parameters on the CBL properties and voltage fluctuations, experiments were performed with two different plasma torches from Sulzer Metco. The first one is a PTF4 torch with a cylindrical anode-nozzle, working with Ar-H2 plasma gas mixtures and the second one is a 3MB torch with either a conical or a cylindrical anode-nozzle, working with N2-H2 plasma gas mixtures. Moreover, arc voltage fluctuations influence on particle thermal treatment was studied through the measurements of transient temperature and velocity of particles, issued from an yttria partially stabilized zirconia powder with a size distribution between 5 and 25 μm.

Titanium nitride plasma-chemical synthesis with titanium tetrachloride raw material in the DC plasma-arc reactor

NASA Astrophysics Data System (ADS)

Kirpichev, D. E.; Sinaiskiy, M. A.; Samokhin, A. V.; Alexeev, N. V.

2017-04-01

The possibility of plasmochemical synthesis of titanium nitride is demonstrated in the paper. Results of the thermodynamic analysis of TiCl4 - H2 - N2 system are presented; key parameters of TiN synthesis process are calculated. The influence of parameters of plasma-chemical titanium nitride synthesis process in the reactor with an arc plasmatron on characteristics on the produced powders is experimentally investigated. Structure, chemical composition and morphology dependencies on plasma jet enthalpy, stoichiometric excess of hydrogen and nitrogen in a plasma jet are determined.

Diameter control of single-walled carbon nanotube forests from 1.3–3.0 nm by arc plasma deposition

PubMed Central

Chen, Guohai; Seki, Yasuaki; Kimura, Hiroe; Sakurai, Shunsuke; Yumura, Motoo; Hata, Kenji; Futaba, Don N.

2014-01-01

We present a method to both precisely and continuously control the average diameter of single-walled carbon nanotubes in a forest ranging from 1.3 to 3.0 nm with ~1 Å resolution. The diameter control of the forest was achieved through tuning of the catalyst state (size, density, and composition) using arc plasma deposition of nanoparticles. This 1.7 nm control range and 1 Å precision exceed the highest reports to date. PMID:24448201

Average current per vacuum-arc cathode spot and spot velocity in a magnetic field on a CuCr50/50 nanocomposite

NASA Astrophysics Data System (ADS)

Zabello, K. K.; Poluyanova, I. N.; Yakovlev, V. V.; Shkol'nik, S. M.

2017-11-01

It has been shown that such cathode spot characteristics as the average current per spot and its dependence on tangential magnetic-field induction B t and the spot velocity and its dependence on B t for two CuCr50/50 specimens with very different structures (nanocomposite and "solid-state sintered" composite) almost coincide if the surface of contacts has been totally remelted before measurements with the use of moderate arc currents in the process of conditioning.

Archaean tectonic systems: A view from igneous rocks

NASA Astrophysics Data System (ADS)

Moyen, Jean-François; Laurent, Oscar

2018-03-01

This work examines the global distribution of Archaean and modern igneous rock's compositions, without relying on preconceptions about the link between rock compositions and tectonic sites (in contrast with "geotectonic" diagrams). Rather, Archaean and modern geochemical patterns are interpreted and compared in terms of source and melting conditions. Mafic rocks on the modern Earth show a clear chemical separation between arc and non-arc rocks. This points to the first order difference between wet (arc) and dry (mid-ocean ridges and hotspots) mantle melting. Dry melts are further separated in depleted (MORB) and enriched (OIB) sources. This three-fold pattern is a clear image of the ridge/subduction/plume system that dominates modern tectonics. In contrast, Archaean mafic and ultramafic rocks are clustered in an intermediate position, between the three main modern types. This suggests that the Archaean mantle had lesser amounts of clearly depleted or enriched portions; that true subductions were rare; and that the distinction between oceanic plateaus and ridges may have been less significant. Modern granitic rocks dominantly belong to two groups: arc-related granitoids, petrologically connected to arc basalts; and collision granitoids, related to felsic sources. In contrast, the Archaean record is dominated by the TTG suite that derives from an alkali-rich mafic source (i.e. altered basalt). The geochemical diversity of the TTG suite points to a great range of melting depths, from ca. 5 to > 20 kbar. This reveals the absence of large sedimentary accumulations, again the paucity of modern-like arc situations, and the importance played by reworking of an earlier basaltic shell, in a range of settings (including some proto-subduction mechanisms). Nonetheless, granitoids in each individual region show a progressive transition towards more modern-looking associations of arc-like and peraluminous granites. Collectively, the geochemical evidence suggests an Archaean Earth with somewhat different tectonic systems. In particular, the familiar distinction between collision, arcs, ridges and hotspots seems to blur in the Archaean. Rather, the large-scale geochemical pattern reveals a long-lived, altered and periodically resurfaced basaltic crust. This protocrust is reworked, through a range of processes occurring at various depths that correspond to a progressive stabilization of burial systems and the establishment of true subductions. A punctuated onset of global plate tectonics is unlikely to have occurred, but rather short-term episodes of proto-subduction in the late Archaean evolved over time into longer-term, more stable style of plate tectonics as mantle temperature decayed.

Geochemistry of southern Pagan Island lavas, Mariana arc: The role of subduction zone processes

USGS Publications Warehouse

Marske, J.P.; Pietruszka, A.J.; Trusdell, F.A.; Garcia, M.O.

2011-01-01

New major and trace element abundances, and Pb, Sr, and Nd isotopic ratios of Quaternary lavas from two adjacent volcanoes (South Pagan and the Central Volcanic Region, or CVR) located on Pagan Island allow us to investigate the mantle source (i.e., slab components) and melting dynamics within the Mariana intra-oceanic arc. Geologic mapping reveals a pre-caldera (780-9.4ka) and post-caldera (<9.4ka) eruptive stage for South Pagan, whereas the eruptive history of the older CVR is poorly constrained. Crystal fractionation and magma mixing were important crustal processes for lavas from both volcanoes. Geochemical and isotopic variations indicate that South Pagan and CVR lavas, and lavas from the northern volcano on the island, Mt. Pagan, originated from compositionally distinct parental magmas due to variations in slab contributions (sediment and aqueous fluid) to the mantle wedge and the extent of mantle partial melting. A mixing model based on Pb and Nd isotopic ratios suggests that the average amount of sediment in the source of CVR (~2.1%) and South Pagan (~1.8%) lavas is slightly higher than Mt. Pagan (~1.4%) lavas. These estimates span the range of sediment-poor Guguan (~1.3%) and sediment-rich Agrigan (~2.0%) lavas for the Mariana arc. Melt modeling demonstrates that the saucer-shaped normalized rare earth element (REE) patterns observed in Pagan lavas can arise from partial melting of a mixed source of depleted mantle and enriched sediment, and do not require amphibole interaction or fractionation to depress the middle REE abundances of the lavas. The modeled degree of mantle partial melting for Agrigan (2-5%), Pagan (3-7%), and Guguan (9-15%) lavas correlates with indicators of fluid addition (e.g., Ba/Th). This relationship suggests that the fluid flux to the mantle wedge is the dominant control on the extent of partial melting beneath Mariana arc volcanoes. A decrease in the amount of fluid addition (lower Ba/Th) and extent of melting (higher Sm/Yb), and an increase in the sediment contribution (higher Th/Nb, La/Sm, and Pb isotopic ratios) from Mt. Pagan to South Pagan could reflect systematic cross-arc or irregular along-arc melting variations. These observations indicate that the length scale of compositional heterogeneity in the mantle wedge beneath Mariana arc volcanoes is small (~10km).

The role of water in the petrogenesis of Marina trough magmas

NASA Astrophysics Data System (ADS)

Stolper, Edward; Newman, Sally

1994-02-01

Most variations in composition among primitive basalts from the Mariana back-arc trough can be explained by melting mixtures of an N-type mid-ocean ridge basalt (NMORB) mantle source and an H2O rich component, provided the degree of melting is positively and approximately linearly correlated with the proportion of the H2O-rich component in the mixture. We conclude that the degrees of melting by which Mariana trough magmas are generated increase from magmas similar to NMORB, through more H2O-enriched basalts, to 'arc-like' basalts, and that this increase is due to the lowering of the solidus of mantle peridotite that accompanies addition of the H2O-rich component. The H2O-rich component is likely to be ultimately derived from fluid from a subducting slab, but we propose that by the time fluids reach the source regions of Mariana trough basalts, they have interacted with sufficient mantle material that for all but the most incompatible of elements (with respect to fluid-mantle interaction), they are in equilibrium with the mantle. In contrast, fluids added to the source regions of Mariana island-arc magmas have typically interacted with less mantle and thus retain the signature of slab-derived fluids to varying degrees for all but the most compatible elements. Primitive Mariana arc basalts can be generated by melting mixtures of such incompletely exchanged slab-derived fluids and sources similar to NMORB-type mantle sources, but the degrees of melting are typically higher than those of Mariana trough NMORB and the sources have been variably depleted relative to the back-arc sources by previous melt extraction. This depletion may be related to earlier extraction of back-arc basin magmas or may evolve by repeated fluxing of the sources as fluid is continually added to them in the regions of arc magma generation. If fluid with partitioning behavior relative to the solid mantle similar to that deduced for the H2O-rich component involved in the generation of Mariana trough basalts were extracted from primitive mantle, the residual mantle would have many of the minor and trace element characteristics of typical oceanic upper mantle; primitive mantle enriched in such fluid would be a satisfactory source for the continental crust in terms of its trace and minor element chemical composition.

Estimation of axial curvature of anterior sclera: correlation between axial length and anterior scleral curvature as affected by angle kappa.

PubMed

Lee, Sang-Mok; Choi, Hyuk Jin; Choi, Heejin; Kim, Mee Kum; Wee, Won Ryang

2016-10-07

BACKGROUND: Though the development and fitting of scleral contact lenses are expanding steadily, there is no simple method to provide scleral metrics for scleral contact lens fitting yet. The aim of this study was to establish formulae for estimation of the axial radius of curvature (ARC) of the anterior sclera using ocular biometric parameters that can be easily obtained with conventional devices. A semi-automated stitching method and a computational analysis tool for calculating ARC were developed by using the ImageJ and MATLAB software. The ARC of all the ocular surface points were analyzed from the composite horizontal cross-sectional images of the right eyes of 24 volunteers; these measurements were obtained using anterior segment optical coherence tomography for a previous study (AS-OCT; Visante). Ocular biometric parameters were obtained from the same volunteers with slit-scanning topography and partial coherence interferometry. Correlation analysis was performed between the ARC at 8 mm to the axis line (ARC[8]) and other ocular parameters (including age). With ARC obtained on several nasal and temporal points (7.0, 7.5, 8.0, 8.5, and 9.0 mm from the axis line), univariate and multivariate linear regression analyses were performed to develop a model for estimating ARC with the help of ocular biometric parameters. Axial length, spherical equivalent, and angle kappa showed correlations with temporal ARC[8] (tARC[8]; Pearson's r = 0.653, -0.579, and -0.341; P = 0.001, 0.015, and 0.015, respectively). White-to-white corneal diameter (WTW) and anterior chamber depth (ACD) showed correlation with nasal ARC[8] (nARC[8]; Pearson's r = -0.492 and -0.461; P = 0.015 and 0.023, respectively). The formulae for estimating scleral curvatures (tARC, nARC, and average ARC) were developed as a function of axial length, ACD, WTW, and distance from the axis line, with good determinant power (72 - 80 %; SPSS ver. 22.0). Angle kappa showed strong correlation with axial length (Pearson's r = -0.813, P <0.001), and the different correlation patterns of nasal and temporal ARC with axial length can be explained by the ocular surface deviation represented by angle kappa. Axial length, ACD, and WTW are useful parameters for estimating the ARC of the anterior sclera, which is important for the haptic design of scleral contact lenses. Angle kappa affects the discrepancies between the nasal and temporal scleral curvature.

Assembly of the Pamirs: Age and origin of magmatic belts from the southern Tien Shan to the southern Pamirs and their relation to Tibet

USGS Publications Warehouse

Schwab, M.; Ratschbacher, L.; Siebel, W.; McWilliams, M.; Minaev, V.; Lutkov, V.; Chen, F.; Stanek, K.; Nelson, B.; Frisch, W.; Wooden, J.L.

2004-01-01

Magmatic rocks and depositional setting of associated volcaniclastic strata along a north-south traverse spanning the southern Tien Shan and eastern Pamirs of Kyrgyzstan and Tajikistan constrain the tectonics of the Pamirs and Tibet. The northern Pamirs and northwestern Tibet contain the north facing Kunlun suture, the south facing Jinsha suture, and the intervening Carboniferous to Triassic Karakul-Mazar subduction accretion system; the latter is correlated with the Songpan-Garze-Hoh Xi system of Tibet. The Kunlun arc is a composite early Paleozoic to late Paleozoic-Triassic arc. Arc formation in the Pamirs is characterized by ???370-320 Ma volcanism that probably continued until the Triassic. The cryptic Tanymas suture of the southern northern Pamirs is part of the Jinsha suture. A massive ??????227 Ma batholith stitches the Karakul-Mazar complex in the Pamirs. There are striking similarities between the Qiangtang block in the Pamirs and Tibet. Like Tibet, the regional structure of the Pamirs is an anticlinorium that includes the Muskol and Sares domes. Like Tibet, the metamorphic rocks in these domes are equivalents to the Karakul-Mazar-Songpan-Garze system. Granitoids intruding the Qiangtang block yield ???200-230 Ma ages in the Pamirs and in central Tibet. The stratigraphy of the eastern Pshart area in the Pamirs is similar to the Bangong-Nujiang suture zone in the Amdo region of eastern central Tibet, but a Triassic ocean basin sequence is preserved in the Pamirs. Arc-type granitoids that intruded into the eastern Pshart oceanic-basin-arc sequence (???190-160 Ma) and granitoids that cut the southern Qiangtang block (???170-160 Ma) constitute the Rushan-Pshart arc. Cretaceous plutons that intruded the central and southern Pamirs record a long-lasting magmatic history. Their zircons and those from late Miocene xenoliths show that the most distinct magmatic events were Cambro-Ordovician (???410-575 Ma), Triassic (???210-250 Ma; likely due to subduction along the Jinsha suture), Middle Jurassic (???147-195 Ma; subduction along Rushan-Pshart suture), and mainly Cretaceous. Middle and Late Cretaceous magmatism may reflect arc activity in Asia prior to the accretion of the Karakoram block and flat-slab subduction along the Shyok suture north of the Kohistan-Ladakh arc, respectively. Before India and Asia collided, the Pamir region from the Indus-Yarlung to the Jinsha suture was an Andean-style plate margin. Our analysis suggests a relatively simple crustal structure for the Pamirs and Tibet. From the Kunlun arc in the north to the southern Qiangtang block in the south the Pamirs and Tibet likely have a dominantly sedimentary crust, characterized by Karakul-Mazar-Songpan-Garze accretionary wedge rocks. The crust south of the southern Qiangtang block is likely of granodioritic composition, reflecting long-lived subduction, arc formation, and Cretaceous-Cenozoic underthrusting. Copyright 2004 by the American Geophysical Union.

Thallium isotopes as tracers of recycled materials in subduction zones: Review and new data for lavas from Tonga-Kermadec and Central America

NASA Astrophysics Data System (ADS)

Nielsen, Sune G.; Prytulak, Julie; Blusztajn, Jerzy; Shu, Yunchao; Auro, Maureen; Regelous, Marcel; Walker, Jim

2017-06-01

Sediment is actively being subducted in every convergent margin worldwide. Yet, geochemical data for arc lavas from several subduction zones, such as Northern Tonga and Costa Rica have revealed either attenuated or limited evidence for sediment in their mantle source regions. Here we use thallium (Tl) isotopes to trace slab components in lavas from the Tonga-Kermadec and Central American arcs. In general, both arcs display Tl isotope data that are most compatible with addition of sediment to the sub-arc mantle from the subducting slab. This evidence is particular strong in the Tonga-Kermadec arc where pelagic clays dominate the Tl budget along the entire arc. Contributions from altered oceanic crust as well as the Louisville Seamount chain that subducts underneath Northern Tonga are not visible in Tl isotopes, which is likely due to the very high Tl concentrations found in pelagic sediments outboard of the Tonga-Kermadec arc. Lavas from Central America reveal variable and systematic Tl isotope compositions along-strike. In particular, lavas from Nicaragua are dominated by contributions from sediments, whereas Costa Rican samples reveal a significant altered oceanic crust component with little influence from sediments on thallium isotope composition. The absence of a sediment signature in Costa Rica corresponds with the Cocos Ridge and the seamount province subduction, which results in a thinner sediment cover. Furthermore, the subducted sediment is dominated by carbonates with very low Tl concentrations and, therefore, small amounts of carbonate sediment added to the mantle wedge do not contribute significantly to the overall Tl budget. A review of Tl isotope and concentration data from the Aleutians, Marianas, Tonga-Kermadec and Central American arcs demonstrate that pelagic sediments are detectable in most arcs, whereas altered oceanic crust components only become appreciable when sediment Tl concentrations are very low (e.g. carbonate) or if sediments are no longer a significant component of the subducting slab (e.g. slab melting in Western Aleutians). As such, Tl isotopes are a promising tool to trace sediment subduction although this requires at least some pelagic sediment is present in the subducted sediment package. We suggest that thallium partitioning between the slab and mantle wedge is most likely controlled by retention in phengite or by partitioning into fluids. Residual phengite likely produces high Cs/Tl ratios because Tl should be more compatible in phengite than is Cs, however, this conclusion needs experimental verification. The stability of phengite is lower at higher fluid contents, which results in hyperbolic relationships between Cs/Tl and possible indicators of fluids such as Sr/Nd and Ba/Th. Thus, combined Tl isotopic and elemental systematics not only provide detailed information about the specific slab components that contribute to arc lavas, but also potentially shed light on the mineralogy and physical conditions of subducting slabs.

The final pulse of the Early Cenozoic adakitic activity in the Eastern Pontides Orogenic Belt (NE Turkey): An integrated study on the nature of transition from adakitic to non-adakitic magmatism in a slab window setting

NASA Astrophysics Data System (ADS)

Eyuboglu, Yener; Dudas, Francis O.; Santosh, M.; Eroğlu-Gümrük, Tuğba; Akbulut, Kübra; Yi, Keewook; Chatterjee, Nilanjan

2018-05-01

The Eastern Pontides Orogenic Belt, one of the best examples of a fossil continental arc in the Alpine-Himalayan system, is characterized by adakitic magmatism during the Early Cenozoic. Popular models correlate the adakitic magmatism to syn- or post-collisional processes occurring after the collision between the Eastern Pontides Orogenic Belt and the Tauride Platform at the end of Late Mesozoic and/or beginning of the Cenozoic. We present new geological, petrological and chronological data from andesites and felsic tuffs exposed in the Bayburt area, in the southern part of the Eastern Pontides Orogenic Belt, and discuss the nature of the transition from adakitic to non-adakitic activities in a continental arc. Major, trace and rare earth element concentrations of both andesites and felsic tuffs clearly suggest that they are related to arc magmatism in a continental arc with adakitic composition. The isotopic compositions are permissive of mixing between a component similar to depleted mantle and a second component that is either mafic lower crust or subducted oceanic crust. 39Ar/40Ar hornblende and U/Pb zircon dating indicate that this adakitic magmatism in the Bayburt area ended by about 47 Ma, and transformed into non-adakitic, granitoid arc magmatism in the area immediately north of Bayburt in the Lutetian (∼46 Ma). Based on our new results in conjunction with available data, we propose that the beginning of northward rollback of a south-directed subducting slab, and simultaneous opening of a slab window related to ridge subduction, triggered both adakitic magmatism for approximately a 10 Myr period between 57.6 and 47 Ma and arc-parallel extension that caused the opening of the Early Cenozoic sedimentary basins. We also suggest that the shallow marine environment, in which Nummulite-bearing sandy limestones accumulated in the Early Cenozoic, was transformed into a saline-lake environment during the pyroclastic activity that produced the studied felsic tuffs at ∼47 Ma.

Discovery of a Triassic magmatic arc source for the Permo-Triassic Karakaya subduction complex, NW Turkey

NASA Astrophysics Data System (ADS)

Ayda Ustaömer, Petek; Ustaömer, Timur; Gerdes, Axel; Robertson, Alastair H. F.; Zulauf, Gernold

2014-05-01

The Permo-Triassic Karakaya Complex is well explained by northward subduction of Palaeotethys but until now no corresponding magmatic arc has been identified in the region. With the aim of determining the compositions and ages of the source units, ten sandstone samples were collected from the mappably distinct Ortaoba, Hodul, Kendirli and Orhanlar Units. Zircon grains were extracted from these sandstones and >1300 were dated by the U-Pb method and subsequently analysed for the Lu-Hf isotopic compositions by LA-MC-ICPMS at Goethe University, Frankfurt. The U-Pb-Hf isotope systematics are indicative of two different sediment provenances. The first, represented by the Ortaoba, Hodul and Kendirli Units, is dominated by igneous rocks of Triassic (250-220 Ma), Early Carboniferous-Early Permian (290-340 Ma) and Early to Mid-Devonian (385-400 Ma) ages. The second provenance, represented by the Orhanlar Unit, is indicative of derivation from a peri-Gondwanan terrane. In case of the first provenance, the Devonian and Carboniferous source rocks exibit intermediate eHf(t) values (-11 to -3), consistent with the formation at a continental margin where juvenile mantle-derived magmas mixed with (recycled) old crust having Palaeoproterozoic Hf model ages. In contrast, the Triassic arc magma exhibits higher eHf(t) values (-6 to +6), consistent with the mixing of juvenile mantle-derived melts with (recycled) old crust perhaps somewhat rejuvanated during the Cadomian period. We have therefore identified a Triassic magmatic arc as predicted by the interpretation of the Karakaya Complex as an accretionary complex related to northward subduction (Carboniferous and Devonian granites are already well documented in NW Turkey). Possible explanations for the lack of any outcrop of the source magmatic arc are that it was later subducted or the Karakaya Complex was displaced laterally from its source arc (both post 220 Ma). Strike-slip displacement (driven by oblique subduction?) can also explain the presence of two different sandstone source areas as indicated by the combined U-Pb-Hf isotope and supporting petrographic data. This study was supported by TUBITAK, Project no: 111R015

Soil biochar amendment shapes the composition of N2O-reducing microbial communities.

PubMed

Harter, Johannes; Weigold, Pascal; El-Hadidi, Mohamed; Huson, Daniel H; Kappler, Andreas; Behrens, Sebastian

2016-08-15

Soil biochar amendment has been described as a promising tool to improve soil quality, sequester carbon, and mitigate nitrous oxide (N2O) emissions. N2O is a potent greenhouse gas. The main sources of N2O in soils are microbially-mediated nitrogen transformation processes such as nitrification and denitrification. While previous studies have focused on the link between N2O emission mitigation and the abundance and activity of N2O-reducing microorganisms in biochar-amended soils, the impact of biochar on the taxonomic composition of the nosZ gene carrying soil microbial community has not been subject of systematic study to date. We used 454 pyrosequencing in order to study the microbial diversity in biochar-amended and biochar-free soil microcosms. We sequenced bacterial 16S rRNA gene amplicons as well as fragments of common (typical) nosZ genes and the recently described 'atypical' nosZ genes. The aim was to describe biochar-induced shifts in general bacterial community diversity and taxonomic variations among the nosZ gene containing N2O-reducing microbial communities. While soil biochar amendment significantly altered the 16S rRNA gene-based community composition and structure, it also led to the development of distinct functional traits capable of N2O reduction containing typical and atypical nosZ genes related to nosZ genes found in Pseudomonas stutzeri and Pedobacter saltans, respectively. Our results showed that biochar amendment can affect the relative abundance and taxonomic composition of N2O-reducing functional microbial traits in soil. Thus these findings broaden our knowledge on the impact of biochar on soil microbial community composition and nitrogen cycling. Copyright © 2016 Elsevier B.V. All rights reserved.

Nugget-Navaho-Aztec sandstone: interaction of eolian sand sea with Andean-type volcanic arc

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marzolf, J.E.

1986-05-01

The Nugget-Navaho-Aztec sand sea was deposited east of an Andean-type volcanic arc. During the early stage of eolian deposition, fluvially transported sand was concentrated in the marine littoral zone and returned inland by onshore winds from the northwest. With progressive development of the arc, the sea withdrew. Wind direction changed from northwest to northeast. Previously deposited eolian sand was transported southwestward into the volcanic arc. Proximity of the arc can be detected with great difficulty by examining eolian and underlying red-bed facies. In southern Nevada, the volcanic arc is undetectable in eolian facies, but thin sandstone beds containing volcanic clastsmore » or weathered feldspar in the finer grained red-bed facies indicate arc volcanism; volcanic clasts are distinct in a basal conglomerate. Westward into California, the sub-Aztec Sandstone contains volcanic pebbles. The upper part of the Aztec Sandstone contains a 1 to 2-m thick volcaniclastic siltstone. Farther west, the Aztec Sandstone is interbedded with volcanic flows, ash flows, and flow breccias. These rocks might easily be mistaken for red beds in well cores or cuttings. Sand in sets of large-scale cross-beds remain virtually identical in composition and texture to sand in eolian facies of the Colorado Plateau. Where sets of eolian cross-beds lie on volcanics, the quartzose sandstone contains pebble to cobble-size volcanic clasts. Locally, cross-bed sets of yellowish-white, quartzose sandstone alternate with purplish-gray cross-bed sets containing numerous pebble to cobble-size volcanic clasts. The ability to recognize volcanic indicators within Nugget-Navaho-Aztec eolian facies is important in delineating the western margin of the back-arc eolian basin.« less

Towards Understanding the Sunda and Banda Arcs

NASA Astrophysics Data System (ADS)

Hall, R.

2014-12-01

The present change from oceanic subduction beneath the Sunda Arc to arc-continent collision east of Sumba is merely the latest stage in a complex collision history that began more than 20 million years ago. Understanding present-day tectonics requires restoring the pre-collisional margins and unravelling the history of the entire Sunda-Banda Arc, not just a segment centred on Sumba. Seismic tomography displays a single folded slab beneath the Banda Arc around which mantle has flowed. Above this is a wide actively deforming zone of complex geology. Australian crust was first added to the Sunda margin in the Cretaceous. Early Miocene closure of the oceanic gap north of Australia led to further additions of continental crust during collision of the Sula Spur. Few microcontinental fragments were sliced from New Guinea as commonly interpreted. Most are parts of the Sula Spur fragmented by extension and strike-slip faulting during development of subduction zones and rollback into the Banda embayment. Many metamorphic 'basement' rocks are significantly younger than expected. They were metamorphosed during multiple episodes of extension which also exhumed the sub-lithospheric mantle, melted the deep continental crust, created new ocean basins, and dispersed continental crust throughout the inner and outer arc, and forearc, so that in places Australian crust is colliding with Australian crust. Thus, many of the arc volcanoes are built on continental not oceanic crust, and sediment eroded from recently emergent islands is compositionally different to subducted sediment that contributed to arc magmas. The published literature is inadequate. New fieldwork and data are required, particularly in remote areas, with integration of information from a variety of sources (e.g. industry seismic and multibeam bathymetry, remotely acquired imagery) and sub-disciplines (e.g. geochronology, geochemistry, seismology, modelling). No single methodology can provide a complete solution.

Late Jurassic - Early Cretaceous convergent margins of Northeastern Asia with Northwestern Pacific and Proto-Arctic oceans

NASA Astrophysics Data System (ADS)

Sokolov, Sergey; Luchitskaya, Marina; Tuchkova, Marianna; Moiseev, Artem; Ledneva, Galina

2013-04-01

Continental margin of Northeastern Asia includes many island arc terranes that differ in age and tectonic position. Two convergent margins are reconstructed for Late Jurassic - Early Cretaceous time: Uda-Murgal and Alazeya - Oloy island arc systems. A long tectonic zone composed of Upper Jurassic to Lower Cretaceous volcanic and sedimentary rocks is recognized along the Asian continent margin from the Mongol-Okhotsk thrust-fold belt on the south to the Chukotka Peninsula on the north. This belt represents the Uda-Murgal arc, which was developed along the convergent margin between Northeastern Asia and Northwestern Meso-Pacific. Several segments are identified in this arc based upon the volcanic and sedimentary rock assemblages, their respective compositions and basement structures. The southern and central parts of the Uda-Murgal island arc system were a continental margin belt with heterogeneous basement represented by metamorphic rocks of the Siberian craton, the Verkhoyansk terrigenous complex of Siberian passive margin and the Koni-Taigonos late Paleozoic to early Mesozoic island arc with accreted oceanic terranes. At the present day latitude of the Pekulney and Chukotka segments there was an ensimatic island arc with relicts of the South Anyui oceanic basin in backarc basin. Alazeya-Oloy island arc systems consists of Paleozoic and Mesozoic complexes that belong to the convergent margin between Northeastern Asia and Proto-Artic Ocean. It separated structures of the North American and Siberian continents. The Siberian margin was active whereas the North American margin was passive. The Late Jurassic was characterized by termination of a spreading in the Proto-Arctic Ocean and transformation of the latter into the closing South Anyui turbidite basin. In the beginning the oceanic lithosphere and then the Chukotka microcontinent had been subducted beneath the Alazeya-Oloy volcanic belt

Diamondlike flake composites

NASA Technical Reports Server (NTRS)

Banks, B. A. (Inventor)

1984-01-01

A carbon coating is vacuum arc deposited on a smooth surface of a target which is simultaneously ion beam sputtered. The bombarding ions have sufficient energy to create diamond bonds. Spalling occurs as the carbon deposit thickens. The resulting diamond-like carbon flakes are mixed with a binder or matrix material to form a composite material having improved thermal, electrical, mechanical, and tribological properties when used in aerospace structures and components.

Influence of photostabilizers on wood flour-HDPE composites exposed to xenon-arc radiation with and without water spray

Treesearch

Nicole M. Stark; Laurent M. Matuana

2006-01-01

The weathering of wood-plastic composites changes their appearance and/or mechanical properties. These changes can be slowed through the addition of ultraviolet absorbers and pigments. The first phase of this study examined the effect of incorporating different concentrations of an ultraviolet absorber and/or pigment into wood-flour-filled high-density polyethylene (WF...

Effect of N{sub 2} and Ar gas on DC arc plasma generation and film composition from Ti-Al compound cathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhirkov, Igor, E-mail: igozh@ifm.liu.se; Rosen, Johanna; Oks, Efim

2015-06-07

DC arc plasma from Ti, Al, and Ti{sub 1−x}Al{sub x} (x = 0.16, 0.25, 0.50, and 0.70) compound cathodes has been characterized with respect to plasma chemistry (charged particles) and charge-state-resolved ion energy for Ar and N{sub 2} pressures in the range 10{sup −6} to 3 × 10{sup −2} Torr. Scanning electron microscopy was used for exploring the correlation between the cathode and film composition, which in turn was correlated with the plasma properties. In an Ar atmosphere, the plasma ion composition showed a reduction of Al of approximately 5 at. % compared to the cathode composition, while deposited films were in accordance with the cathodemore » stoichiometry. Introducing N{sub 2} above ∼5 × 10{sup −3} Torr, lead to a reduced Al content in the plasma as well as in the film, and hence a 1:1 correlation between the cathode and film composition cannot be expected in a reactive environment. This may be explained by an influence of the reactive gas on the arc mode and type of erosion of Ti and Al rich contaminations, as well as on the plasma transport. Throughout the investigated pressure range, a higher deposition rate was obtained from cathodes with higher Al content. The origin of generated gas ions was investigated through the velocity rule, stating that the most likely ion velocities of all cathode elements from a compound cathode are equal. The results suggest that the major part of the gas ions in Ar is generated from electron impact ionization, while gas ions in a N{sub 2} atmosphere primarily originate from a nitrogen contaminated layer on the cathode surface. The presented results provide a contribution to the understanding processes of plasma generation from compound cathodes. It also allows for a more reasonable approach to the selection of composite cathode and experimental conditions for thin film depositions.« less

Synthesis of single-walled carbon nanotubes and graphene composite in arc for ultracapacitors

NASA Astrophysics Data System (ADS)

Li, Jian; Cheng, Xiaoqian; Shashurin, Alexey; Keidar, Michael

2012-10-01

Arc discharge supported by the erosion of graphite anode is considered as one of the most practical and efficient methods to synthesize various carbon nanostructures such as single-walled carbon nanotubes (SWCNT) and graphene with minimal defects and large yield due to the relatively high synthesis temperature and eco-friendly growth mechanism. By introducing a non-uniform magnetic field during synthesis process, large-scale graphene and high-purity SWCNT can be obtained in one step. In addition, the yield of graphene can be controlled by external parameters, such as the type and pressure of buffer gas, the temperature of substrate, and so on. Possessing the properties of highly accessible surface area and good electrical conductivity, the composite of graphene and SWCNT are promising nanomaterials for the electrodes of ultracapacitor, which can store electric energy with high level of capacitance. In this work, we fabricated electrodes of ultracapacitor based on nanostructures composite by wire-wound rod coating method, characterized them by SEM, EDX and Raman spectroscopy, and tested the performance by a potentiostat/galvanostat.

Juxtaposition of Neoproterozoic units along the Baruda - Tulu Dimtu shear-belt in the East African Orogen of western Ethiopia

USGS Publications Warehouse

Braathen, A.; Grenne, Tor; Selassie, M.G.; Worku, T.

2001-01-01

Amalgamation of East and West Gondwanaland during the Neoproterozoic East African Orogen is recorded by several shear-belts or 'suture zones', some of which are associated with ultramafic and mafic complexes that have been interpreted as ophiolite fragments. The Baruda shear-belt is a major structure of this type that belongs to the N-S trending Barka - Tulu Dimtu zone. The significance of this zone has been studied within a transect in western Ethiopia which covers a variety of metasedimentary and metavolcanic sequences, ultramafic rocks and synkinematic intrusive complexes. All rocks participated in the regional D1 event as reflected in a penetrative steep foliation in supracrustal rocks and marginal parts of the intrusions. Highly strained rocks contain a stretching lineation that plunge to the east. The several-km thick Baruda shear-belt, comprising mylonitic supracrustal and plutonic rocks including mafic-ultramafic mega-lenses, is the most prominent expression of this event. Shear-sense indicators demonstrate top-to-the-west shear. Subsequent D2 deformation is recorded in 2-300 m wide, N-S striking, subvertical shear-zones with subhorizontal stretching lineation relatable to sinistral transcurrent movements. Our data indicate that rock units on either side of the Baruda shear-belt are related, rather than being exotic to each other as implied in suture zone models, since there is no major lithologic or metamorphic difference, geochemical data on metavolcanic rocks and pre-tectonic intrusions suggest a paleotectonic link, and style and extent of deformation is similar across the shear-belt. A tentative model for the transect suggests an arc and back-arc setting which experienced later continental collision and tectonic shortening. The initial setting was that of a shallow marine platform characterised by carbonates and sandstones, which covered extensive areas prior to break-up of a pre-existing supercontinent. Continental convergence is first recorded in high-K calc-alkaline volcanism characterised by pyroclastic deposits of andesitic composition, at an active continental margin at about 800 Ma. Subaerial arc volcanism was temporally and spatially overlapping with limited arc rifting, represented by submarine basalts compositionally transitional between enriched MORB and calc-alkaline magmas, and associated dyke swarms in the older carbonate-sandstone platform sequence. It is suggested that the large, mafic-ultramafic, bodies relate to this event and were originally formed as intrusions along one or more propagating rift axis within the arc complex. The regional Baruda shear-belt formed in response to contractional D1 deformation, and its location may have been largely controlled by competence contrasts between the array of rift-related intrusions and the marble-dominated lithologies. Associated shortening of the arc and back-arc region led to crustal thickening and emplacement of synkinematic, composite, batholiths at about 570-550 Ma. These are composed of moderately peraluminous granite and coeval, intermediate to mafic intrusions of shoshonitic affinity. D2 sinistral movements succeeded the contractional deformation. ?? 2001 Elsevier Science B.V.

Manipulation of Guaiacyl and Syringyl Monomer Biosynthesis in an Arabidopsis Cinnamyl Alcohol Dehydrogenase Mutant Results in Atypical Lignin Biosynthesis and Modified Cell Wall Structure

PubMed Central

Anderson, Nickolas A.; Tobimatsu, Yuki; Ciesielski, Peter N.; Ximenes, Eduardo; Ralph, John; Donohoe, Bryon S.; Ladisch, Michael; Chapple, Clint

2015-01-01

Modifying lignin composition and structure is a key strategy to increase plant cell wall digestibility for biofuel production. Disruption of the genes encoding both cinnamyl alcohol dehydrogenases (CADs), including CADC and CADD, in Arabidopsis thaliana results in the atypical incorporation of hydroxycinnamaldehydes into lignin. Another strategy to change lignin composition is downregulation or overexpression of ferulate 5-hydroxylase (F5H), which results in lignins enriched in guaiacyl or syringyl units, respectively. Here, we combined these approaches to generate plants enriched in coniferaldehyde-derived lignin units or lignins derived primarily from sinapaldehyde. The cadc cadd and ferulic acid hydroxylase1 (fah1) cadc cadd plants are similar in growth to wild-type plants even though their lignin compositions are drastically altered. In contrast, disruption of CAD in the F5H-overexpressing background results in dwarfism. The dwarfed phenotype observed in these plants does not appear to be related to collapsed xylem, a hallmark of many other lignin-deficient dwarf mutants. cadc cadd, fah1 cadc cadd, and cadd F5H-overexpressing plants have increased enzyme-catalyzed cell wall digestibility. Given that these CAD-deficient plants have similar total lignin contents and only differ in the amounts of hydroxycinnamaldehyde monomer incorporation, these results suggest that hydroxycinnamaldehyde content is a more important determinant of digestibility than lignin content. PMID:26265762

Structure and properties of Hardox 450 steel with arc welded coatings

NASA Astrophysics Data System (ADS)

Ivanov, Yu. F.; Konovalov, S. V.; Kormyshev, V. E.; Gromov, V. E.; Teresov, A. D.; Semina, O. A.

2017-12-01

The paper reports on a study of the surface structure, phase composition, and microhardness of Hardox 450 steel with coatings deposited by arc welding of powder wires differing in chemical composition. The study shows that to a depth of 6-8 mm, the microhardness of the thus formed coatings is more than two times the microhardness of the base metal and that their higher mechanical properties are provided by martensite structure containing Nb2C and NbC carbides and Fe2B borides as eutectic lamellae with a transverse size of 30-70 nm; their volume reveals a net-like dislocation substructure with a scalar dislocation density of 1011 cm-2. The highest surface hardness is found for the steel coated with boron-containing wire material. Some ideas are suggested on possible mechanisms and temperature for the formation of Nb and B carbides during the process.

Chlorine and fluorine partition coefficients and abundances in sub-arc mantle xenoliths (Kamchatka, Russia): Implications for melt generation and volatile recycling processes in subduction zones

NASA Astrophysics Data System (ADS)

Bénard, A.; Koga, K. T.; Shimizu, N.; Kendrick, M. A.; Ionov, D. A.; Nebel, O.; Arculus, R. J.

2017-02-01

We report chlorine (Cl) and fluorine (F) abundances in minerals, interstitial glasses, and melt inclusions in 12 andesite-hosted, spinel harzburgite xenoliths and crosscutting pyroxenite veins exhumed from the sub-arc lithospheric mantle beneath Avacha volcano in the Kamchatka Arc (NE Russia). The data are used to calculate equilibrium mineral-melt partition coefficients (D mineral / melt) for Cl and F relevant to subduction-zone processes and unravel the history of volatile depletion and enrichment mechanisms in an arc setting. Chlorine is ∼100 times more incompatible in pyroxenes (DClmineral/melt = 0.005-0.008 [±0.002-0.003]) than F (DFmineral/melt = 0.50-0.57 [±0.21-0.24]), which indicates that partial melting of mantle sources leads to strong depletions in Cl relative to F in the residues. The data set in this study suggests a strong control of melt composition on DCl,Fpyroxene/melt, in particular H2O contents and Al/(Al + Si), which is in line with recent experiments. Fluorine is compatible in Ca-amphibole in the 'wet' sub-arc mantle (DFamphibole/melt = 3.5-3.7 [±1.5]) but not Cl (DClamphibole/melt = 0.03-0.05 [±0.01-0.03]), indicating that amphibole may fractionate F from Cl in the mantle wedge. The inter-mineral partition coefficients for Cl and F in this study are consistent amongst different harzburgite samples, whether they contain glass or not. In particular, disseminated amphibole hosts much of the Cl and F bulk rock budgets of spinel harzburgites (DClamphibole/pyroxene up to 14 and DFamphibole/pyroxene up to 40). Chlorine and fluorine are variably enriched (up to 1500 ppm Cl and 750 ppm F) in the parental arc picrite and boninite melts of primitive pyroxenite veins (and related melt inclusions) crosscutting spinel harzburgites. Based on the data in this study, the main inferences on the behaviour of Cl and F during melting and metasomatic processes in the sub-arc mantle are as follow: (i) Melting models show that most depleted mantle protoliths of intra-oceanic arc sources can have extremely low Cl/F (0.002-0.007) before being overprinted by subduction-derived components. (ii) Chlorine has a higher percolation distance in the mantle than F. Even for small fluid or melt volumes, Cl and F signatures of partial melting are overprinted by those of pervasive percolation, which increases Cl/F in percolating agents and bulk peridotites during chromatographic interaction and/or amphibole-forming metasomatic reactions. These processes ultimately control the bulk Cl and F compositions of the residual mantle lithosphere beneath arcs, and likely in other tectonic settings. (iii) Fluxed melting models suggest that Cl enrichment in arc picrite and boninite melts in this study, and in many arc melt inclusions reported in the literature, could be related to the infiltration of high Cl/F fluids derived from subducted serpentinite or altered crust in mantle wedge sources. However, these high Cl/F signatures should be re-evaluated with new models in light of the possible overprint of pervasive percolation effects in the mantle. The breakdown of amphibole (and/or mica) in the deep metasomatised mantle at higher pressure and temperature conditions than in the slab may explain, at least in part, the positive correlations between F abundances and Cl/F in primitive arc melt inclusions and slab depth.

Reestablishment of the Ancestral Cascades Arc in Western Nevada and Eastern California by Rollback of the Shallow Farallon Slab

NASA Astrophysics Data System (ADS)

Henry, C. D.; Cousens, B.; John, D. A.; Colgan, J. P.

2009-12-01

The character and even existence of an ancestral Tertiary Cascades arc in western Nevada and eastern California south of the modern arc are controversial. Based on extensive published and new data on the regional distribution, timing, style, and composition of magmatism, we conclude that an ancestral arc was established by WSW migration of magmatism into western NV and the northeastern Sierra Nevada in the Oligocene and Miocene as a result of progressive rollback of the shallow subducted slab. Magma migration started with the well-known southward sweep through NE NV and NW UT between ~46 and 36 Ma. By ~30 Ma, migration of the leading edge and central belt of activity was much more WSW, especially after removing younger ~E-W extension. Locally sourced, initially dispersed and small volume, intermediate to mafic lavas erupted in western NV and northeastern CA by ~30 Ma and the eastern Sierra Nevada by ~28 Ma, contemporaneous with the much more voluminous ignimbrite flare-up in central NV. As migration continued, the ignimbrite flare-up tapered off. A voluminous, NNW-trending, dominantly effusive volcanic belt developed by ~22-18 Ma in western NV and was continuous from the Bodie Hills (CA/NV) to the Warner Range (northeast CA) by ~16-15 Ma. The volcanic belt was dominated by intermediate to mafic magmas compositionally similar to those of the modern south Cascades arc but reflecting melting of an old, subduction-modified lithosphere (Cousens et al. 2008; Geosphere). Extensive middle Miocene bimodal rocks related to the Yellowstone hotspot cover these rocks in NW NV, NE CA, and SE OR, but 30-23 Ma, intermediate to mafic and lesser silicic rocks are voluminous wherever older rocks are exposed below the middle Miocene rocks. Between ~25 Ma and the present, magmatism migrated WSW at an average rate of ~8 km/Ma but was at least partly stepwise, as exemplified by an ~50 km westward step at 2 Ma in the Lassen area (Guffanti et al. 1990, JGR). The magmatic belt was as much as 250 km wide (present-day NE-SW, perpendicular to WSW migration) during much of its activity and only narrowed as it focused in western NV. In contrast, the ancestral Western Cascades arc in OR developed by ~35-40 Ma and persisted to the present as a narrow (≤50 km) belt nearly coincident with the modern Cascade arc. The Western Cascades and ancestral arc activity in NV and CA were misaligned by 100s of km and only became aligned during the ~2 Ma westward step. Misalignment suggests a major tear in the subducted slab near the OR-NV/CA border. Steep subduction was reestablished in OR by 35 Ma but only developed in NV/CA by progressive foundering of the shallow slab. Examining the magmatic record from past to present (WSW migration) complicates the question of what constituted an ancestral Cascades arc, e.g., what is the setting of the ignimbrite flare-up? In contrast, by examining the record from present to past and W to E, it is difficult to determine when and where the modern arc stopped being a continental volcanic arc. More important to address the existence of a southern ancestral Cascades arc is to comprehensively determine the distribution, timing, and origin of magmatism.

Miniature Arcs for Synthesis of Carbon Nanotubes in Microgravity

NASA Technical Reports Server (NTRS)

Alford, J. M.; Mason, G. R.; Feikema, D. A.

2006-01-01

Although many methods are available for producing single-walled carbon nanotubes (SWNTs), the conventional carbon arc process remains the most popular due to its simplicity and large production rate. In the carbon arc, SWNTs are catalytically synthesized by rapidly evaporating a graphite anode impregnated with NiN metal catalyst from which the nanotubes grow in an inert atmosphere. However, high temperatures inside the carbon arc generate strong buoyancy driven convection, and it is hypothesized that the non-uniform environment created by this flow has a large effect on the growth and morphology of the SWNTs. To study the effect of buoyancy on the arc process, a miniature carbon arc apparatus was developed to synthesize SWNTs in a microgravity environment substantially free from these strong convective flows. The reactor was operated for either 2.2 or 5 seconds during free-fall in the drop towers at the NASA Glenn Research Center. Two apparatus designs differing mainly in their production rate and power capacity were investigated. The first consisted of a miniaturized carbon arc employing a 1 mm diameter graphite anode and powered by a 0.54 F capacitor bank charged to 65 V. The second, larger apparatus employed a 4 mm diameter anode and was powered by a portable battery pack capable of providing in excess of 300 amps at 30 volts to the arc for the duration of a 5 second drop. Initial results indicated that transient heating is a very large effect in the short-duration drop tower carbon arcs, and thermal equilibrium of the arc plasma, buffer gas, and apparatus was not attained during the short microgravity periods. In addition, removal of the buoyant convection by the microgravity now allowed clear observation of large jets of evaporated carbon vapor streaming from the anode and mixing with the inert buffer gas. The initial mixing of these jets with the cold buffer gas combined with the thermal transient made it difficult to establish a uniform high temperature environment around the arc in the 2.1 to 5 second microgravity time interval, and even with a very high-powered arc, the arc region was cooler than in continuously operated arcs. Despite these difficulties, the miniature arc produced SWNTs in microgravity. However, given the large thermal transient to overcome, no dramatic difference in sample yield or composition was noted between normal gravity and q2-,andL%econd long microgravity runs.

Quantifying crustal thickness over time in magmatic arcs

NASA Astrophysics Data System (ADS)

Profeta, Lucia; Ducea, Mihai N.; Chapman, James B.; Paterson, Scott R.; Gonzales, Susana Marisol Henriquez; Kirsch, Moritz; Petrescu, Lucian; Decelles, Peter G.

2015-12-01

We present global and regional correlations between whole-rock values of Sr/Y and La/Yb and crustal thickness for intermediate rocks from modern subduction-related magmatic arcs formed around the Pacific. These correlations bolster earlier ideas that various geochemical parameters can be used to track changes of crustal thickness through time in ancient subduction systems. Inferred crustal thicknesses using our proposed empirical fits are consistent with independent geologic constraints for the Cenozoic evolution of the central Andes, as well as various Mesozoic magmatic arc segments currently exposed in the Coast Mountains, British Columbia, and the Sierra Nevada and Mojave-Transverse Range regions of California. We propose that these geochemical parameters can be used, when averaged over the typical lifetimes and spatial footprints of composite volcanoes and their intrusive equivalents to infer crustal thickness changes over time in ancient orogens.

Quantifying crustal thickness over time in magmatic arcs

PubMed Central

Profeta, Lucia; Ducea, Mihai N.; Chapman, James B.; Paterson, Scott R.; Gonzales, Susana Marisol Henriquez; Kirsch, Moritz; Petrescu, Lucian; DeCelles, Peter G.

2015-01-01

We present global and regional correlations between whole-rock values of Sr/Y and La/Yb and crustal thickness for intermediate rocks from modern subduction-related magmatic arcs formed around the Pacific. These correlations bolster earlier ideas that various geochemical parameters can be used to track changes of crustal thickness through time in ancient subduction systems. Inferred crustal thicknesses using our proposed empirical fits are consistent with independent geologic constraints for the Cenozoic evolution of the central Andes, as well as various Mesozoic magmatic arc segments currently exposed in the Coast Mountains, British Columbia, and the Sierra Nevada and Mojave-Transverse Range regions of California. We propose that these geochemical parameters can be used, when averaged over the typical lifetimes and spatial footprints of composite volcanoes and their intrusive equivalents to infer crustal thickness changes over time in ancient orogens. PMID:26633804

Baseline tests for arc melter vitrification of INEL buried wastes. Volume II: Baseline test data appendices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oden, L.L.; O`Conner, W.K.; Turner, P.C.

1993-11-19

This report presents field results and raw data from the Buried Waste Integrated Demonstration (BWID) Arc Melter Vitrification Project Phase 1 baseline test series conducted by the Idaho National Engineering Laboratory (INEL) in cooperation with the U.S. Bureau of Mines (USBM). The baseline test series was conducted using the electric arc melter facility at the USBM Albany Research Center in Albany, Oregon. Five different surrogate waste feed mixtures were tested that simulated thermally-oxidized, buried, TRU-contaminated, mixed wastes and soils present at the INEL. The USBM Arc Furnace Integrated Waste Processing Test Facility includes a continuous feed system, the arc meltingmore » furnace, an offgas control system, and utilities. The melter is a sealed, 3-phase alternating current (ac) furnace approximately 2 m high and 1.3 m wide. The furnace has a capacity of 1 metric ton of steel and can process as much as 1,500 lb/h of soil-type waste materials. The surrogate feed materials included five mixtures designed to simulate incinerated TRU-contaminated buried waste materials mixed with INEL soil. Process samples, melter system operations data and offgas composition data were obtained during the baseline tests to evaluate the melter performance and meet test objectives. Samples and data gathered during this program included (a) automatically and manually logged melter systems operations data, (b) process samples of slag, metal and fume solids, and (c) offgas composition, temperature, velocity, flowrate, moisture content, particulate loading and metals content. This report consists of 2 volumes: Volume I summarizes the baseline test operations. It includes an executive summary, system and facility description, review of the surrogate waste mixtures, and a description of the baseline test activities, measurements, and sample collection. Volume II contains the raw test data and sample analyses from samples collected during the baseline tests.« less

Baseline tests for arc melter vitrification of INEL buried wastes. Volume 1: Facility description and summary data report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oden, L.L.; O`Connor, W.K.; Turner, P.C.

1993-11-19

This report presents field results and raw data from the Buried Waste Integrated Demonstration (BWID) Arc Melter Vitrification Project Phase 1 baseline test series conducted by the Idaho National Engineering Laboratory (INEL) in cooperation with the U.S. Bureau of Mines (USBM). The baseline test series was conducted using the electric arc melter facility at the USBM Albany Research Center in Albany, Oregon. Five different surrogate waste feed mixtures were tested that simulated thermally-oxidized, buried, TRU-contaminated, mixed wastes and soils present at the INEL. The USBM Arc Furnace Integrated Waste Processing Test Facility includes a continuous feed system, the arc meltingmore » furnace, an offgas control system, and utilities. The melter is a sealed, 3-phase alternating current (ac) furnace approximately 2 m high and 1.3 m wide. The furnace has a capacity of 1 metric ton of steel and can process as much as 1,500 lb/h of soil-type waste materials. The surrogate feed materials included five mixtures designed to simulate incinerated TRU-contaminated buried waste materials mixed with INEL soil. Process samples, melter system operations data and offgas composition data were obtained during the baseline tests to evaluate the melter performance and meet test objectives. Samples and data gathered during this program included (a) automatically and manually logged melter systems operations data, (b) process samples of slag, metal and fume solids, and (c) offgas composition, temperature, velocity, flowrate, moisture content, particulate loading and metals content. This report consists of 2 volumes: Volume I summarizes the baseline test operations. It includes an executive summary, system and facility description, review of the surrogate waste mixtures, and a description of the baseline test activities, measurements, and sample collection. Volume II contains the raw test data and sample analyses from samples collected during the baseline tests.« less

Trace-element geochemistry of metabasaltic rocks from the Yukon-Tanana Upland and implications for the origin of tectonic assemblages in east-central Alaska

USGS Publications Warehouse

Dusel-Bacon, C.; Cooper, K.M.

1999-01-01

We present major- and trace- element geochemical data for 27 amphibolites and six greenstones from three structural packages in the Yukon-Tanana Upland of east-central Alaska: the Lake George assemblage (LG) of Devono-Mississippian augen gneiss, quartz-mica schist, quartzite, and amphibolite; the Taylor Mountain assemblage (TM) of mafic schist and gneiss, marble, quartzite, and metachert; and the Seventymile terrane of greenstone, serpentinized peridotite, and Mississippian to Late Triassic metasedimentary rocks. Most LG amphibolites have relatively high Nb, TiO2, Zr, and light rare earth element contents, indicative of an alkalic to tholeiitic, within-plate basalt origin. The within-plate affinities of the LG amphibolites suggest that their basaltic parent magmas developed in an extensional setting and support a correlation of these metamorphosed continental-margin rocks with less metamorphosed counterparts across the Tintina fault in the Selwyn Basin of the Canadian Cordillera. TM amphibolites have a tholeiitic or calc-alkalic composition, low normalized abundances of Nb and Ta relative to Th and La, and Ti/V values of <20, all indicative of a volcanic-arc origin. Limited results from Seventymile greenstones indicate a tholeiitic or calc-alkalic composition and intermediate to high Ti/V values (27-48), consistent with either a within-plate or an ocean-floor basalt origin. Y-La-Nb proportions in both TM and Seventymile metabasalts indicate the proximity of the arc and marginal basin to continental crust. The arc geochemistry of TM amphibolites is consistent with a model in which the TM assemblage includes arc rocks generated above a west-dipping subduction zone outboard of the North American continental margin in mid-Paleozoic through Triassic time. The ocean-floor or within-plate basalt geochemistry of the Seventymile greenstones supports the correlation of the Seventymile terrane with the Slide Mountain terrane in Canada and the hypothesis that these oceanic rocks originated in a basin between the continental margin and an arc to the west.

Influence of magmatic volatiles on boron isotope compositions in vent fluids from the Eastern Manus Basin, Papua New Guinea

NASA Astrophysics Data System (ADS)

Wilckens, F. K.; Kasemann, S.; Bach, W.; Reeves, E. P.; Meixner, A.; Seewald, J.

2016-12-01

In this study we present boron (B), lithium (Li) and strontium (Sr) concentrations and isotopic composition of submarine hydrothermal fluids collected in 2006 and 2011 from PACMANUS, DESMOS and SuSu Knolls vent fields located in the Eastern Manus Basin [1,2]. Hydrothermal vent fluids within the Eastern Manus Basin range from high-temperature black smoker fluids to low-temperature diffuse fluids and acid-sulfate fluids. In general, the different fluid types show variable water-rock ratios during water-rock interaction and different inputs of magmatic volatiles. End-member black smoker fluids, which have in general high temperatures (mostly higher than 280°C) and pH values higher than 2 (measured at 25°C) are characterized by low δ7Li values (3.9 to 5.9‰) and 87Sr/86Sr ratios (0.704 to 0.705) similar to the values for island arc basalts. These results suggest low water-rock ratios during hydrothermal circulation. B concentrations and isotopic compositions in these fluids range from 1.0 to 2.6μM and 13 to 20‰, respectively. These data match with other vent fluids from island arc settings in the Western Pacific and plot in a B versus δ11B diagram on a two-component mixing line between seawater and island arc basalts [3]. Sr and Li isotopic composition of white smoker and acid-sulfate fluids overlap generally with the isotopic ratios for the black smoker fluids. However, in some fluids Sr isotope ratios are up to 0.709 near seawater composition suggesting higher water-rock ratios during water-rock interaction. B concentrations and isotope ratios in the white smoker and acid-sulfate fluids range from 0.6 to 2.2μM and 9 to 16‰, respectively which are lower compared with the values of black smoker fluids. In addition, these fluids do not fit on the mixing line between seawater and island arc basalt, and define another mixing trend in a B versus δ11B diagram. To explain this contradictory trend, a third mixing endmember is required that shifts B concentrations and δ11B to lower values. A possible mixing endmember is B volatized from magmatic gases. This endmember seems to be reasonable because it only influences B, whereas Li and Sr stay unaffected. [1] Reeves et al. (2011) GCA 75, 1088-1123 [2] Seewald et al. (2015) GCA 163, 178-199 [3] Yamaoka et al. (2015) CG 392, 9-18

Comparison of halogen, plasma and LED curing units.

PubMed

Nomoto, Rie; McCabe, John F; Hirano, Susumu

2004-01-01

This study evaluated the characteristics of two kinds of recently developed light-curing unit; plasma arc and blue light emitting diodes (LED), in comparison with a conventional tungsten-halogen light-curing unit. The light intensity and spectral distribution of light from these light-curing units, the temperature rise of the bovine enamel surface and the depth of cure of composites exposed to each unit were investigated. The light intensity and depth of cure were determined according to ISO standards. The spectral distributions of emitted light were measured using a spectro-radiometer. The temperature increase induced by irradiation was measured by using a thermocouple. Generally, light intensities in the range 400-515 nm emitted from the plasma arc were greater than those from other types. Light in the UV-A region was emitted from some plasma arc units. The required irradiation times were six to nine seconds for the plasma arc units and 40 to 60 seconds for the LED units to create a depth of cure equal to that produced by the tungsten-halogen light with 20 seconds of irradiation. The temperature increased by increasing the irradiation time for every light-curing unit. The temperature increases were 15 degrees C to 60 degrees C for plasma arc units, around 15 degrees C for a conventional halogen unit and under 10 degrees C for LED units. Both the plasma arc and LED units required longer irradiation times than those recommended by their respective manufacturers. Clinicians should be aware of potential thermal rise and UV-A hazard when using plasma arc units.

Large Scale Composite Manufacturing for Heavy Lift Launch Vehicles

NASA Technical Reports Server (NTRS)

Stavana, Jacob; Cohen, Leslie J.; Houseal, Keth; Pelham, Larry; Lort, Richard; Zimmerman, Thomas; Sutter, James; Western, Mike; Harper, Robert; Stuart, Michael

2012-01-01

Risk reduction for the large scale composite manufacturing is an important goal to produce light weight components for heavy lift launch vehicles. NASA and an industry team successfully employed a building block approach using low-cost Automated Tape Layup (ATL) of autoclave and Out-of-Autoclave (OoA) prepregs. Several large, curved sandwich panels were fabricated at HITCO Carbon Composites. The aluminum honeycomb core sandwich panels are segments of a 1/16th arc from a 10 meter cylindrical barrel. Lessons learned highlight the manufacturing challenges required to produce light weight composite structures such as fairings for heavy lift launch vehicles.

Atypical Lymphocytes and Cellular Cannibalism: A Phenomenon, First of its Kind to be Discovered in Chronic Periapical Lesions.

PubMed

Kalele, Ketki P; Patil, Kaustubh P; Nayyar, Abhishek Singh; Sasane, Rutuparna S

2016-04-01

Lymphocytes are often termed to be isomorphic, having a monotonous light microscopic appearance. Morphological aspects of lymphocytes in tissue sections thereby are not routinely taken notice of as their morphology seems to vary only in case of lymphoid malignancies, hematological malignancies apart from certain viral infections. Atypical lymphocytes are the lymphocytes with unusual shape, size or overall structure. These are more commonly known as reactive lymphocytes. The unusual histomorphological feature of these cells include larger size than normal lymphocytes; in some cells the size exceeds even 30 microns. The large size is the result of antigenic stimulation of the cell. Alongwith these, the other rare feature which is recently coming under light is "Cellular Cannibalism" which is defined as a large cell enclosing a slightly smaller one within its cytoplasm. Previously, this feature was noted only in cases of malignant tumors. The objectives of this study were to determine the proportion of atypical lymphocytes in chronic periapical granulomas and cysts; to determine the proportionate cellular cannibalism in these periapical lesions. This was a descriptive, observational study conducted in the Department of Oral Medicine and Radiology and Oral Pathology and Microbiology. Haematoxylin and eosin stained 30 slides of chronic periapical granulomas and 20 slides of cysts reported in the year 2014-15 and the clinical proformas of the patients were retrieved from the files of the Department of Oral Medicine and Radiology and Oral Pathology and Microbiology. These slides were evaluated by 3 experts from the specialization of Oral Pathology and Microbiology to determine the presence of atypical lymphocytes and cellular cannibalism under high power magnification (400X). Out of the 30 slides of chronic periapical granulomas, about 12 slides (40%) revealed presence of atypical lymphocytes. In case of slides of chronic periapical cysts, however, only 4 out of the 20 slides (20%) examined histopathologically showed presence of atypical lymphocytes. An interesting feature of cellular cannibalism was noted in tissues with atypical cells. Cannibalistic cells were present in 12 out of the 30 slides of chronic periapical granulomas (40%). None of the cysts, however, revealed cannibalistic cells (0%). In the present study, we have quoted our observations on the unique cellular composition that was seen in histopathological sections of chronic periapical lesions. As also it was noted that those cases in which atypical cells & cellular cannibalism was evident the lesion clinically showed size more than 5cm. The question arises that whether presence of atypical cells from the tissue sections in these lesions denotes an aggressive clinical behavior and should be given a due consideration in deciding the treatment protocols for such cases to provide an optimum patient care.

Effect of sulfuric acid etching of polyetheretherketone on the shear bond strength to resin cements.

PubMed

Sproesser, Oliver; Schmidlin, Patrick R; Uhrenbacher, Julia; Roos, Malgorzata; Gernet, Wolfgang; Stawarczyk, Bogna

2014-10-01

To examine the influence of etching duration on the bond strength of PEEK substrate in combination with different resin composite cements. In total, 448 PEEK specimens were fabricated, etched with sulfuric acid for 5, 15, 30, 60, 90, 120, and 300 s and then luted with two conventional resin cements (RelyX ARC and Variolink II) and one self-adhesive resin cement (Clearfil SA Cement) (n = 18/subgroup). Non-etched specimens served as the control group. Specimens were stored in distilled water for 28 days at 37°C and shear bond strengths were measured. Data were analyzed nonparametrically using Kruskal-Wallis-H (p < 0.05). Non-etched PEEK demonstrated no bond strength to resin composite cements. The optimal etching duration varied with the type of resin composite: 60 s for RelyX ARC (15.3 ± 7.2 MPa), 90 s for Variolink II (15.2 ± 7.2 MPa), and 120 s for Clearfil SA Cement (6.4 ± 5.9 MPa). Regardless of etching duration, however, the self-etching resin composite cement showed significantly lower shear bond strength values when compared to groups luted with the conventional resin composites. Although sulfuric acid seems to be suitable and effective for PEEK surface pre-treatment, further investigations are required to examine the effect of other adhesive systems and cements.

Enrichments of the mantle sources beneath the Southern Volcanic Zone (Andes) by fluids and melts derived from abraded upper continental crust

NASA Astrophysics Data System (ADS)

Holm, Paul Martin; Søager, Nina; Dyhr, Charlotte Thorup; Nielsen, Mia Rohde

2014-05-01

Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr-Nd-high-precision Pb isotope data from the Quaternary arc volcanic centres of Maipo (NSVZ) and Infernillo and Laguna del Maule (TSVZ) are argued to reflect mainly their mantle source and its melting. For the C-T-NSVZ, we identify two types of source enrichment: one, represented by Antuco in CSVZ, but also present northward along the arc, was dominated by fluids which enriched a pre-metasomatic South Atlantic depleted MORB mantle type asthenosphere. The second enrichment was by melts having the characteristics of upper continental crust (UCC), distinctly different from Chile trench sediments. We suggest that granitic rocks entered the source mantle by means of subduction erosion in response to the northward increasingly strong coupling of the converging plates. Both types of enrichment had the same Pb isotope composition in the TSVZ with no significant component derived from the subducting oceanic crust. Pb-Sr-Nd isotopes indicate a major crustal compositional change at the southern end of the NSVZ. Modelling suggests addition of around 2 % UCC for Infernillo and 5 % for Maipo.

Underestimated risks of recurrent long-range ash dispersal from northern Pacific Arc volcanoes

PubMed Central

Bourne, A. J.; Abbott, P. M.; Albert, P. G.; Cook, E.; Pearce, N. J. G.; Ponomareva, V.; Svensson, A.; Davies, S. M.

2016-01-01

Widespread ash dispersal poses a significant natural hazard to society, particularly in relation to disruption to aviation. Assessing the extent of the threat of far-travelled ash clouds on flight paths is substantially hindered by an incomplete volcanic history and an underestimation of the potential reach of distant eruptive centres. The risk of extensive ash clouds to aviation is thus poorly quantified. New evidence is presented of explosive Late Pleistocene eruptions in the Pacific Arc, currently undocumented in the proximal geological record, which dispersed ash up to 8000 km from source. Twelve microscopic ash deposits or cryptotephra, invisible to the naked eye, discovered within Greenland ice-cores, and ranging in age between 11.1 and 83.7 ka b2k, are compositionally matched to northern Pacific Arc sources including Japan, Kamchatka, Cascades and Alaska. Only two cryptotephra deposits are correlated to known high-magnitude eruptions (Towada-H, Japan, ca 15 ka BP and Mount St Helens Set M, ca 28 ka BP). For the remaining 10 deposits, there is no evidence of age- and compositionally-equivalent eruptive events in regional volcanic stratigraphies. This highlights the inherent problem of under-reporting eruptions and the dangers of underestimating the long-term risk of widespread ash dispersal for trans-Pacific and trans-Atlantic flight routes. PMID:27445233

Pleistocene volcaniclastic units from North-Eastern Sicily (Italy): new evidence for calc-alkaline explosive volcanism in the Southern Tyrrhenian Sea

NASA Astrophysics Data System (ADS)

Di Bella, Marcella; Italiano, Francesco; Sabatino, Giuseppe; Tripodo, Alessandro; Baldanza, Angela; Casella, Sergio; Pino, Paolo; Rasa', Riccardo; Russo, Selma

2016-08-01

A well-preserved volcaniclastic sequence crops out in Pleistocene marine sediments along the Tyrrhenian coastline of the Calabrian-Peloritani arc (Sicily, Italy), testifying the occurrence of Lower-Middle Pleistocene volcanic activity in Southern Tyrrhenian Sea. The presence of dominant highly vesicular and minor blocky glassy particles indicates that the volcanic clasts were originated by explosive events related to the ascent and violent emission of volatile-rich magmas accompanied by and/or alternated with hydromagmatic fragmentation due to magma-sea water interaction. Field investigations and sedimentological features of the studied volcaniclastic units suggest a deposition from sediment-water density flows. The chemical classification of the pumice clasts indicates prevalent rhyolitic and dacitic compositions with calc-alkaline to high-K calc-alkaline affinity. The geochemical features of immobile trace elements together with the presence of orthopyroxene are indicative of a provenance from an arc-type environment. The age (from 980-910 to 589 ka), the chemical composition and the evidence of subaerial explosive volcanic activity constrain the origin nature and temporal evolution of the arc-type volcanism in the Southern Tyrrhenian domain. Finally, the new information here provided contribute to a better understanding of the temporal geodynamic evolution of this sector of the Mediterranean domain.

Underestimated risks of recurrent long-range ash dispersal from northern Pacific Arc volcanoes.

PubMed

Bourne, A J; Abbott, P M; Albert, P G; Cook, E; Pearce, N J G; Ponomareva, V; Svensson, A; Davies, S M

2016-07-21

Widespread ash dispersal poses a significant natural hazard to society, particularly in relation to disruption to aviation. Assessing the extent of the threat of far-travelled ash clouds on flight paths is substantially hindered by an incomplete volcanic history and an underestimation of the potential reach of distant eruptive centres. The risk of extensive ash clouds to aviation is thus poorly quantified. New evidence is presented of explosive Late Pleistocene eruptions in the Pacific Arc, currently undocumented in the proximal geological record, which dispersed ash up to 8000 km from source. Twelve microscopic ash deposits or cryptotephra, invisible to the naked eye, discovered within Greenland ice-cores, and ranging in age between 11.1 and 83.7 ka b2k, are compositionally matched to northern Pacific Arc sources including Japan, Kamchatka, Cascades and Alaska. Only two cryptotephra deposits are correlated to known high-magnitude eruptions (Towada-H, Japan, ca 15 ka BP and Mount St Helens Set M, ca 28 ka BP). For the remaining 10 deposits, there is no evidence of age- and compositionally-equivalent eruptive events in regional volcanic stratigraphies. This highlights the inherent problem of under-reporting eruptions and the dangers of underestimating the long-term risk of widespread ash dispersal for trans-Pacific and trans-Atlantic flight routes.

Mesozoic arc magmatism along the southern Peruvian margin during Gondwana breakup and dispersal

NASA Astrophysics Data System (ADS)

Boekhout, Flora; Spikings, Richard; Sempere, Thierry; Chiaradia, Massimo; Ulianov, Alexey; Schaltegger, Urs

2012-08-01

A high-resolution U-Pb zircon geochronological study of plutonic units along the south Peruvian margin between 17° and 18°S allows the integration of the geochemical, geodynamic and tectonic evolution of this part of the Andean margin. This study focuses on the composite Jurassic-early Cretaceous Ilo Batholith that was emplaced along the southern Peruvian coast during two episodes of intrusive magmatism; a first period between 173 and 152 Ma (with a peak in magmatic activity between roughly 168 and 162 Ma) and a second period between 110 and 106 Ma. Emplacement of the Jurassic part of the composite Ilo Batholith shortly post-dated the accumulation of the volcanosedimentary succession it intruded (Chocolate formation), which allows to estimate a subsidence rate for this unit of ~ 3.5 km/Ma. The emplacement of the main peak of Jurassic plutonism of the Ilo Batholith was also closely coeval with widespread and repeated slumping (during deposition of the Cachíos Formation) in the back-arc region, suggesting a common causal link between these phenomena, which is discussed in the context of an observed 100 km trenchward arc migration at ~ 175 Ma, and the relation with extensional tectonics that prevailed along the Central Andean margin during Pangaea break-up.

Chemical versus temporal controls on the evolution of tholeiitic and calc-alkaline magmas at two volcanoes in the Alaska-Aleutian arc

USGS Publications Warehouse

George, R.; Turner, S.; Hawkesworth, C.; Bacon, C.R.; Nye, C.; Stelling, P.; Dreher, S.

2004-01-01

The Alaska-Aleutian island arc is well known for erupting both tholeiitic and calc-alkaline magmas. To investigate the relative roles of chemical and temporal controls in generating these contrasting liquid lines of descent we have undertaken a detailed study of tholeiitic lavas from Akutan volcano in the oceanic A1eutian arc and calc-alkaline products from Aniakchak volcano on the continental A1askan Peninsula. The differences do not appear to be linked to parental magma composition. The Akutan lavas can be explained by closed-system magmatic evolution, whereas curvilinear trace element trends and a large range in 87 Sr/86 Sr isotope ratios in the Aniakchak data appear to require the combined effects of fractional crystallization, assimilation and magma mixing. Both magmatic suites preserve a similar range in 226 Ra-230 Th disequilibria, which suggests that the time scale of crustal residence of magmas beneath both these volcanoes was similar, and of the order of several thousand years. This is consistent with numerical estimates of the time scales for crystallization caused by cooling in convecting crustal magma chambers. During that time interval the tholeiitic Akutan magmas underwent restricted, closed-system, compositional evolution. In contrast, the calc-alkaline magmas beneath Aniakchak volcano underwent significant open-system compositional evolution. Combining these results with data from other studies we suggest that differentiation is faster in calc-alkaline and potassic magma series than in tholeiitic series, owing to a combination of greater extents of assimilation, magma mixing and cooling.

Composition and annealing effects on superconductivity in sintered and arc-melted Fe1+εTe0.5Se0.5

NASA Astrophysics Data System (ADS)

Foreman, M. M.; Ponti, G.; Mozaffari, S.; Markert, J. T.

2018-03-01

We present the results of x-ray diffraction, electrical resistivity, and ac magnetic susceptibility measurements on specimens of the “11”-structure superconductor Fe1+εTe0.50Se0.50 (0 ≤ ε ≤ 0.15). Samples were initially either sintered in sealed quartz tubes or melted in a zirconium-gettered arc furnace. Sintered samples were fired two to three times at temperatures of 425°C, 600°C, or 675°C, while arc-melted samples were studied both asmelted and after annealing at 650°C. X-ray diffraction data show a predominant PbO-type tetragonal phase, with a secondary hexagonal NiAs-type phase; for sintered specimens annealed at 600°C, the secondary phase decreases as ε increases over the range 0 ≤ ε ≤ 0.10, with the composition Fe1.10Te0.5Se0.5 exhibiting x-ray phase purity. A higher annealing temperature of 675°C provided such tetragonal phase purity at the composition Fe1.05Te0.5Se0.5. The resistive superconducting transition temperature Tc was nearly independent of the iron concentration 1+ε, suggesting a single superconducting phase, while the magnetic screening fraction varied greatly with concentration and conditions, peaking at ɛ = 0.07, indicating that the amount of superconducting phase is strongly dependent on conditions. We propose that the behaviour can also be viewed in terms of an electron-doped, chalcogen-deficient stoichiometry.

A-type granitoid in Hasansalaran complex, northwestern Iran: Evidence for extensional tectonic regime in northern Gondwana in the Late Paleozoic

NASA Astrophysics Data System (ADS)

Azizi, Hossein; Kazemi, Tahmineh; Asahara, Yoshihiro

2017-07-01

The Hasansalaran plutonic complex is one of the main intrusive bodies with a wide range of granite, monzonite, diorite and syenite that crop out in northwest Iran. This body includes Paleozoic granitoids that are surrounded and cut by Cretaceous granitoids. Zircon U-Pb age dating shows that the crystallization of this body occurred at 360 Ma ago in the Early Carboniferous. Whole rock compositions of the investigated intrusive body, show high contents of Ga (11.1-76.3 ppm), Zr (73.5-1280 ppm), Zn (43.7-358 ppm), Y(17.9-177 ppm), enrichment of rare earth elements (REEs) together with high Ga/Al ratios and a strong Eu negative anomaly, fairly consistent with typical A-type signature. The low εNd(t = 360 Ma) value (< + 3) and high variation of 87Sr/86Sr(initial) ratios are evidence of the role of the continental component for the evolution of A-type granitoids in the Hasansalaran area. Because of the high contents of Ta, Yb, Nb and Y, all samples are plotted in the within-plate tectonic regime without interfering oceanic released fluids in the subduction zone. These high Nb content rocks (37.2-342 ppm without one sample) are classified as A1-type granitoids. Based on the distribution of A1- and A2-type granitoids in the Late Paleozoic in northwest Iran, the existence of some gabbroic rocks with tholeiitic to alkali composition and a long gap for magmatic activities in the area from 550 to 360 Ma (approximately 180 my.a.) between the Zagros and Tabriz faults, we suggest a new thematic model for evolution of northwest Iran in the Late Paleozoic. Based on our model, the upwelling of a mantle plume, probably due to the proto-Tethys oceanic rollback activity beneath northern Gondwana, had a crucial role in the uplifting of the continental crust and resulted in the crystallization of A-type granitoids with some gabbroic rocks in northwest Iran.

Early Cretaceous MORB-type basalt and A-type rhyolite in northern Tibet: Evidence for ridge subduction in the Bangong-Nujiang Tethyan Ocean

NASA Astrophysics Data System (ADS)

Fan, Jian-Jun; Li, Cai; Sun, Zhen-Ming; Xu, Wei; Wang, Ming; Xie, Chao-Ming

2018-04-01

New zircon U-Pb ages, major- and trace-element data, and Hf isotopic compositions are presented for bimodal volcanic rocks of the Zhaga Formation (ZF) in the western-middle segment of the Bangong-Nujiang suture zone (BNSZ), northern Tibet. The genesis of these rocks is described, and implications for late-stage evolution of the Bangong-Nujiang Tethyan Ocean (BNTO) are considered. Detailed studies show that the ZF bimodal rocks, which occur as layers within a typical bathyal to abyssal flysch deposit, comprise MORB-type basalt that formed at a mid-ocean ridge, and low-K calc-alkaline A-type rhyolite derived from juvenile crust. The combination of MORB-type basalt, calc-alkaline A-type rhyolite, and bathyal to abyssal flysch deposits in the ZF leads us to propose that they formed as a result of ridge subduction. The A-type ZF rhyolites yield LA-ICP-MS zircon U-Pb ages of 118-112 Ma, indicating formation during the Early Cretaceous. Data from the present study, combined with regional geological data, indicate that the BNTO underwent conversion from ocean opening to ocean closure during the Late Jurassic-Early Cretaceous. The eastern segment of the BNTO closed during this period, while the western and western-middle segments were still at least partially open and active during the Early Cretaceous, accompanied by ridge subduction within the Bangong-Nujiang Tethyan Ocean.

Structure and Evolution of the Forearc-Arc Crust Along the Tonga-Kermadec Subduction System from Integrated Geophysical Data

NASA Astrophysics Data System (ADS)

Funnell, M.; Peirce, C.; Robinson, A. H.; Watts, A. B.; Grevemeyer, I.

2016-12-01

Variations in tectonic forces and inputs to subduction systems generate, alter, and deform overriding crustal material. Although these processes are recorded in the crustal structure of volcanic arcs and their backarcs, the continuous nature of plate convergence superimposes subsequent episodes of crustal evolution on older features. Seismic imaging at modern subduction zones enhances our understanding of forearc development and variations in present-day deformation caused by inherited structures. In 2011 a set of multichannel and wide-angle seismic profiles imaged the forearc-arc crust and upper mantle structure along the 2700 km-long NNE-SSW trending Tonga-Kermadec subduction zone. The Tonga forearc region exhibits an 100 km-wide, 2 km high bathymetric elevation, with a 3 km-thick upper and mid-crust (Vp <6 km s-1), and a lower-crustal ridge 30 km wide comprising velocities up to 7.4 km s-1 that characterize an extinct Eocene ( 50 Ma) arc. By contrast, the active arc is <10 km wide and exhibits lower-crustal velocities below 7.0 km s-1, most likely representing intermediate compositions. This structural change suggests significant evolution, alteration, and modification of the overriding crust since the onset of subduction at this margin. Gravity anomaly modelling suggests that the extinct arc within the Tonga forearc region comprises relatively dense mafic-ultrabasic material that extends south beneath the Kermadec forearc and terminates at 32°S. The apparent southern termination of the extinct arc coincides with the partitioning of morphological features at 32°S, including a 10-km westward-step of the active arc and a 1.5 km deeper backarc to the south. We propose that tectonic partitioning about the 32°S boundary is the result of variations in the inherited crustal structure, which is divided by the presence and absence, to the north and south respectively, of the extinct volcanic arc.

Fore-arc mantle peridotites and back-arc basin basalts from the Izu-Bonin-Mariana subduction factory (ODP LEGs 125 and 195): a modern analogue for Mediterranean ophiolites

NASA Astrophysics Data System (ADS)

Zanetti, A.; D'Antonio, M.; Vannucci, R.; Raffone, N.; Spadea, P.

2009-04-01

Serpentinites, basaltic lavas and calc-alkaline volcanoclastic sequences sampled during recent Ocean Drilling Program cruises in the western Pacific Ocean allow comparisons with ophiolites from eastern Mediterranean area, which are believed to be related to marginal seas characterised by rapidly propagating back-arc extension and slab rollback (e.g. Albania and Cyprus). Serpentinites recovered at the Torishima, Conical and South Chamorro Seamounts (ODP Legs 125 and 195), located on the Izu-Bonin-Mariana (IBM) forearc, still record complex petrochemical features acquired during their high-T mantle evolution. This latter has been referred to a three-stages-model, involving in chronological sequence: 1) adiabatic mantle upwelling accompanied by 20-25% polybaric partial melting; 2) local depletion in modal orthopyroxene determined by reactive melt migration; 3) late interstitial crystallisation of ultra-depleted to depleted melts. The record of the first stage is preserved in the less-refractory IBM forearc peridotites, which compositions lie on trends describing the decompression melting of uprising asthenospheric mantle. During this stage, the peridotites were actual melt sources. The large average degree of depletion suggests that partial melting events were assisted by particularly hot geotherms. The second stage occurred at relatively lower pressures, according to the large orthopyroxene dissolution, and is guessed to be firmly related to arc volcanism. Nevertheless, the progressive change of oxidation state of the mantle minerals, which decreases from the Torishima (N Izu-Bonin forearc) through the Conical (N Mariana forearc) to the South Chamorro Seamount (S Mariana forearc), highlights a marked gradient in terms of contribution to the uprising melts from slab-derived component. It is argued that the melt compositions changed from boninitic (at Torishima) to depleted-MORB at (South Chamorro). The third stage determined the petrographic and mineralogical features occurring in all IBM forearc peridotites (e.g. crystallisation of late cpx, embayment of opx porphyroclasts), and likely marks the accretion of the mantle sequence to the thermal boundary layer. It was accompanied by the devolopment of transient geochemical gradients in the migrating liquids mainly governed by chromatographic-type chemical exchange with the peridotite. The West Philippine Basin (WPB) is a back-arc basin that opened in the Philippine Sea Plate (PSP) between the current position of the Palau-Kyushu Ridge (PKR) and the margin of East Asia. Spreading occurred at the Central Basin Fault (CBF) from 54 to 30 Ma. The PKR was active since ~48 to 35 Ma constituting a single volcanic arc with the Izu-Bonin-Mariana Arc. ODP Leg 195 Site 1201 is located in the WPB, ~100 km west of the PKR, on 49 Ma basaltic crust formed by NE-SW spreading at the CBF. From ~35 to 30 Ma, pelagic sedimentation at Site 1201 was followed by turbidite sedimentation, fed mostly by early Mariana Arc (PKR)-derived volcanic clasts. These volcanics are calc-alkaline, whereas PKR rocks from literature have mostly boninitic and arc tholeiitic affinity; the WPB basement basalts have MORB to arc-like affinity, as expected for a back-arc basin. Sr, Nd, Pb and Hf isotope data highlight the Indian Ocean MORB-like character of WPB basement basalts, suggesting an upper mantle domain distinct from that underlying the Pacific Plate. The geochemical and isotopic features of PKR volcanics reflect higher amounts of subduction-derived components, added mostly as siliceous melts, in the source of arc magmas relative to that of basement basalts. In that respect, Site 1201 PKR volcanics resemble calc-alkaline volcanics of the currently active Mariana Arc. In addition, their calc-alkaline affinity, unradiogenic neodymium, and inferred Middle Oligocene age, suggest they might represent an evolved stage of arc volcanism at Palau-Kyushu Ridge, perhaps shortly before the end of its activity.

Process for manufacturing an auto-collimating scintillator and product produced thereby

DOEpatents

Goodman, C.A.; Lyon, A.F.; Perez-Mendez, V.

1995-06-27

There is described a process for the vapor deposition of a scintillator phosphor composition with concomitant shadowing wherein the substrate to be processed is rotated through an arc relative to a vapor source of the scintillator phosphor composition whereby shadowing introduces voided gaps or interstices between columns as a result of the preferential components receiving more coating flux, particularly in the presence of oblique flux. 8 figs.

Process for manufacturing an auto-collimating scintillator and product produced thereby

DOEpatents

Goodman, Claude A.; Lyon, Alan F.; Perez-Mendez, Victor

1995-01-01

There is described a process for the vapor deposition of a scintillator phosphor composition with concomitant shadowing wherein the substrate to be processed is rotated through an arc relative to a vapor source of the scintillator phosphor composition whereby shadowing introduces voided gaps or interstices between columns as a result of the preferential components receiving more coating flux, particularly in the presence of oblique flux.

Weldability of extruded aluminum-alumina composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gedeon, S.A.; Lane, C.; Altshuller, B.

1994-12-31

Acceptable procedure were developed for welding the following types of aluminum particle-reinforced aluminum: 6061/Al{sub 2}O{sub 3}/10p-T6, 6061/Al{sub x}/O{sub 3}20p-T6, and 7005Al{sub 2}O{sub 3}/10p-T6,. Automated and manual procedures were developed and using both gas tungsten arc welding (GTAW), with a cold wire feed, and gas metal arc welding (GMAW). The effect of welding procedures on porosity, reinforcing particulate distribution, and mechanical properties was determined. Postweld heat treatment and microhardness testing were used to understand the effect of the welded microstructure on the strength and ductility of the joint. Fracture surfaces and transverse microsections of mechanical test specimens were examined to determinemore » the origins and mechanisms of failure. Cleanliness of the joint and weld wire were found to be essential to eliminate porosity. Based on these experimentally determined data, general guidelines for welding aluminum oxide particle-reinforced aluminum composites are proposed. Discussion includes proper selection of weld joint geometry, filler metals, travel speed, voltage, and current ranges. These parameters are compared to those used in an actual production environment for composite products. Distinctions between welding these composites and others produced via powder metallurgy or with silicon carbide reinforcements are also discussed.« less

Incremental assembly and prolonged consolidation of Cordilleran magma chambers--Evidence from the Southern Rocky Mountain volcanic field

USGS Publications Warehouse

Lipman, Peter W.

2007-01-01

Plutons thus provide an integrated record of prolonged magmatic evolution, while volcanism offers snapshots of conditions at early stages. Growth of subvolcanic batholiths involved sustained multistage open-system processes. These commonly involved ignimbrite eruptions at times of peak power input, but assembly and consolidation processes continued at diminishing rates long after peak volcanism. Some evidence cited for early incremental pluton assembly more likely records late events during or after volcanism. Contrasts between relatively primitive arc systems dominated by andesitic compositions and small upper-crustal plutons versus more silicic volcanic fields and associated batholiths probably reflect intertwined contrasts in crustal thickness and magmatic power input. Lower power input would lead to a Cascade- or Aleutian-type arc system, where intermediate-composition magma erupts directly from middle- and lower-crustal storage without development of large shallow plutons. Andean and southern Rocky Mountain–type systems begin similarly with intermediate-composition volcanism, but increasing magma production, perhaps triggered by abrupt changes in plate boundaries, leads to development of larger upper-crustal reservoirs, more silicic compositions, large ignimbrites, and batholiths. Lack of geophysical evidence for voluminous eruptible magma beneath young calderas suggests that near-solidus plutons can be rejuvenated rapidly by high-temperature mafic recharge, potentially causing large explosive eruptions with only brief precursors.

The Effect of Filler Wire and Flux Compositions on the Microstructure and Properties of Microalloyed Steel Weld Metal.

DTIC Science & Technology

1984-08-01

obtained from subsize (5.0 x 10.0 x 55.0 mm) Charpy V-Notch specimens, subsize (7.6 x 7.6 x 55.0 mm)-Izod specimens, and subsize (5.0 x 9.5 x 101.6 mm...47 15. Schematic of a submerged arc weld showing the dimensions and orientation of subsize Charpy V-Notch specimens... Subsize (5.0 x 10.0 x 55.0 mm) Charpy impact values P of two submerged arc welds performed on quenched and tempered C-Mn-Mo-Nb plate as a function of

Shapes of Spectral Lines of Nonuniform Plasma of Electric Arc Discharge Between Copper Electrodes

NASA Astrophysics Data System (ADS)

Babich, Ida L.; Boretskij, Viacheslav F.; Veklich, Anatoly N.

2007-09-01

The radial profiles of the temperature and electron density in the plasma of the free burning electric arc between copper electrodes are studied by optical spectroscopy techniques. The electron density and the temperature in plasma as initial parameters were used in the calculation of the plasma composition in local thermodynamic equilibrium (LTE) assumption. We used the Saha's equation for copper, nitrogen and oxygen, dissociation equation for nitrogen and oxygen, the equation of plasma electrical neutrality and Dalton's law as well. So, it would be possible to determine the amounts of metal vapours in plasma.

Basalt-Limestone and Andesite-Limestone Interaction in the Arc Crust - Implications for Volcanic Degassing of CO2

NASA Astrophysics Data System (ADS)

Carter, L. B.; Dasgupta, R.

2014-12-01

Volcanically emitted CO2 is generally mantle-derived, but high degassing rates at some arcs (e.g. Merapi [1] and Colli Albani Volcanic District [2]) are thought to be affected by magma-carbonate interaction in the upper plate. However, the effects of depth, temperature, and composition on this process are poorly known. We experimentally simulated magma (50%)-limestone (50%) wallrock interactions at 0.5-1.0 GPa, 1100-1200 °C using pure calcite and a hydrous (~3-5 wt.% H2O) melt (basalt, andesite, or dacite). At 1.0 GPa, 1200 °C starting melts are superliquidus, whereas in the presence of calcite, Ca-rich cpx ± Ca-scapolite are produced. With increasing T, basalt-calcite interaction causes the melt, on a volatile-free basis, to become silica-poor and Ca-rich with alumina decreasing as cpx becomes more CaTs-rich. The same trend is seen with all starting melt compositions as P decreases at a constant T (1200 °C), producing melts similar to ultracalcic (CaO/Al2O3>>1) melt inclusions found in arc settings. Shifting from basalt to andesite has little effect on SiO2 and CaO of the reacted melt (e.g. 37 wt.% SiO2, 42 wt.% CaO at 0.5 GPa, 1200 °C), whereas Al2O3 of andesite-derived reacted melt is lower, likely a result of lower alumina in the starting andesite. Wall-rock calcite consumption is observed to increase with increasing T, decreasing P, and increasing melt XSiO2. At 0.5 GPa between 1100 and 1200 °C, our basalt experiments yield carbonate assimilation from 22 to 48 wt.%. This decreases to 20 wt.% at 1.0 GPa, 1200 °C, whereas an andesitic composition assimilates 59 to 52 wt.% from 0.5 to 1.0 GPa at 1200 °C. The higher assimilation in andesite-added runs at high-T is because of lower silicate liquidus as evidenced by lower modal proportion or absence of cpx ± scapolite. Using a magma flux rate estimated for Mt. Vesuvius [3], we obtain a CO2 outflux for a single such volcano experiencing arc magma-calcite reaction [4] of at least 2-4% of the present-day global arc flux of CO2 [5]. Therefore, greater lengths of continental arcs with carbonate strata in some geologic time periods might have caused excess degassing of CO2. [1] Troll et al. (2012) GRL 11, 1-6; [2] Freda et al. (2008) Lithos 101, 397-415; [3] Scandone et al. (2008) JVGR 170, 167-180; [4] Iacono Marziano et al. (2009) Geol 37, 319-322; [5] Sano & Williams (1996) GRL 23, 2749-2752.

Structural analysis of a Petri net model of oxidative stress in atherosclerosis.

PubMed

Kozak, Adam; Formanowicz, Dorota; Formanowicz, Piotr

2018-06-01

Atherosclerosis is a complex process of gathering sub-endothelial plaques decreasing lumen of the blood vessels. This disorder affects people of all ages, but its progression is asymptomatic for many years. It is regulated by many typical and atypical factors including the immune system response, a chronic kidney disease, a diet rich in lipids, a local inflammatory process and a local oxidative stress that is here one of the key factors. In this study, a Petri net model of atherosclerosis regulation is presented. This model includes also some information about stoichiometric relationships between its components and covers all mentioned factors. For the model, a structural analysis based on invariants was made and biological conclusions are presented. Since the model contains inhibitor arcs, a heuristic method for analysis of such cases is presented. This method can be used to extend the concept of feasible t -invariants.

Seismicity and eruptive activity at Fuego Volcano, Guatemala: February 1975 -January 1977

USGS Publications Warehouse

Yuan, A.T.E.; McNutt, S.R.; Harlow, D.H.

1984-01-01

We examine seismic and eruptive activity at Fuego Volcano (14??29???N, 90?? 53???W), a 3800-m-high stratovolcano located in the active volcanic arc of Guatemala. Eruptions at Fuego are typically short-lived vulcanian eruptions producing ash falls and ash flows of high-alumina basalt. From February 1975 to December 1976, five weak ash eruptions occurred, accompanied by small earthquake swarms. Between 0 and 140 (average ??? 10) A-type or high-frequency seismic events per day with M > 0.5 were recorded during this period. Estimated thermal energies for each eruption are greater by a factor of 106 than cumulative seismic energies, a larger ratio than that reported for other volcanoes. Over 4000 A-type events were recorded January 3-7, 1977 (cumulative seismic energy ??? 109 joules), yet no eruption occurred. Five 2-hour-long pulses of intense seismicity separated by 6-hour intervals of quiescence accounted for the majority of events. Maximum likelihood estimates of b-values range from 0.7 ?? 0.2 to 2.1 ?? 0.4 with systematically lower values corresponding to the five intense pulses. The low values suggest higher stress conditions. During the 1977 swarm, a tiltmeter located 6 km southeast of Fuego recorded a 14 ?? 3 microradian tilt event (down to SW). This value is too large to represent a simple change in the elastic strain field due to the earthquake swarm. We speculate that the earthquake swarm and tilt are indicative of subsurface magma movement. ?? 1984.

Progressive enrichment of arc magmas caused by the subduction of seamounts under Nishinoshima volcano, Izu-Bonin Arc, Japan

NASA Astrophysics Data System (ADS)

Sano, Takashi; Shirao, Motomaro; Tani, Kenichiro; Tsutsumi, Yukiyasu; Kiyokawa, Shoichi; Fujii, Toshitsugu

2016-06-01

The chemical composition of intraplate seamounts is distinct from normal seafloor material, meaning that the subduction of seamounts at a convergent margin can cause a change in the chemistry of the mantle wedge and associated arc magmas. Nishinoshima, a volcanic island in the Izu-Bonin Arc of Japan, has been erupting continuously over the past 2 years, providing an ideal opportunity to examine the effect of seamount subduction on the chemistry of arc magmas. Our research is based on the whole-rock geochemistry and the chemistry of minerals within lavas and air-fall scoria from Nishinoshima that were erupted before 1702, in 1973-1974, and in 2014. The mineral phases within the analyzed samples crystallized under hydrous conditions (H2O = 3-4 wt.%) at temperatures of 970 °C-990 °C in a shallow (3-6 km depth) magma chamber. Trace element data indicate that the recently erupted Nishinoshima volcanics are much less depleted in the high field strength elements (Nb, Ta, Zr, Hf) than other volcanics within the Izu-Bonin Arc. In addition, the level of enrichment in the Nishinoshima magmas has increased in recent years, probably due to the addition of material from HIMU-enriched (i.e., high Nb/Zr and Ta/Hf) seamounts on the Pacific Plate, which is being subducted westwards beneath the Philippine Sea Plate. This suggests that the chemistry of scoria from Nishinoshima volcano records the progressive addition of components derived from subducted seamounts.

Geochemistry and geochronology of Tobago Island: a preliminary re-appraisal

NASA Astrophysics Data System (ADS)

Neill, I.; Kerr, A. C.; Snoke, A. W.; Hastie, A.; Pindell, J. L.; Chamberlain, K.; Millar, I. L.

2009-12-01

A unifying model to constrain the sources, polarity and geometry of the Great Arc of the Caribbean during the Jurassic-Cretaceous remains elusive. The arc was the leading edge of the Caribbean plate prior to, and during, its late Cretaceous tectonic emplacement between the Americas1,2. Tobago Island in the SE Caribbean has long been considered a partial cross-section through at least two generations of mid-Cretaceous Great Arc magmatism3. ICP-OES/MS and Nd-Hf-Pb radiogenic isotope whole rock determinations are combined with three new U-Pb zircon LA-ICP-MS and several existing mineral ages to present a geochemical and geochronological re-appraisal of the origin of the igneous suites on Tobago. The North Coast Schist (>115 Ma3) is a suite of tholeiitic mafic-felsic tuffs and volcanic breccias with variable Nb-Ta, Ti and slight Th depletions indicative of an arc or back-arc origin. This suite was deformed and metamorphosed to greenschist facies prior to the formation of the Tobago pluton and volcanic suite. The pluton (104±1 Ma3) comprises peridotite cumulates, gabbro-diorites and hornblende pegmatites. It is cogenetic with the volcanic suite, which consists of mafic volcanic breccias, tuffs and lavas (~104 Ma3), and a suite of mafic dykes (~105-91 Ma3). The volcano-plutonic suite has a tholeiitic island arc composition and appears geochemically similar to the North Coast Schist. A 6 km-long tonalite body cross-cuts the pluton and has a trondhjemitic composition, with high Si, Al, La/Yb and Sr/Y, low MgO, Y and Nb. It may be derived from partial melting of an enriched, garnet-bearing basaltic or amphibolitic source region. Furthermore, several mafic-to-granitic dykes have non-arc highly enriched signatures consistent with a plume source and may be related to the ~90 Ma Caribbean Oceanic Plateau2. The data indicate a more complex magmatic history for the igneous rocks of Tobago than suggested by previous studies3 and thus they require a more detailed tectonomagmatic interpretation. Radiogenic isotopes provide a unique opportunity to study in detail the changing nature of the mantle sources involved in both arc and plume magmatism on Tobago and to test potential links with arc outcrops of a similar age throughout the Caribbean. A vital test will be to place constraints upon whether or not subduction polarity reversal occurred between eruption of the North Coast Schist and the Tobago Volcanic Group, a key tenet of the work by Pindell et al.1. 1: Pindell, J.L. et al., 2009. In: James, K., Lorente, M. A. & Pindell, J. (eds), The geology and evolution of the region between North and South America, Geological Society, London, Special Publication, in press. 2: Kerr, A.C. et al., 2003. AAPG Memoir 79: 126-168. 3: Snoke, A.W. et al., 2001. GSA Special Paper 354: pp.54.

Petrogenesis of meta-volcanic rocks from the Maimón Formation (Dominican Republic): Geochemical record of the nascent Greater Antilles paleo-arc

NASA Astrophysics Data System (ADS)

Torró, Lisard; Proenza, Joaquín A.; Marchesi, Claudio; Garcia-Casco, Antonio; Lewis, John F.

2017-05-01

Metamorphosed basalts, basaltic andesites, andesites and plagiorhyolites of the Early Cretaceous, probably pre-Albian, Maimón Formation, located in the Cordillera Central of the Dominican Republic, are some of the earliest products of the Greater Antilles arc magmatism. In this article, new whole-rock element and Nd-Pb radiogenic isotope data are used to give new insights into the petrogenesis of the Maimón meta-volcanic rocks and constrain the early evolution of the Greater Antilles paleo-arc system. Three different groups of mafic volcanic rocks are recognized on the basis of their immobile element contents. Group 1 comprises basalts with compositions similar to low-Ti island arc tholeiites (IAT), which are depleted in light rare earth elements (LREE) and resemble the forearc basalts (FAB) and transitional FAB-boninitic basalts of the Izu-Bonin-Mariana forearc. Group 2 rocks have boninite-like compositions relatively rich in Cr and poor in TiO2. Group 3 comprises low-Ti island arc tholeiitic basalts with near-flat chondrite-normalized REE patterns. Plagiorhyolites and rare andesites present near-flat to subtly LREE-depleted chondrite normalized patterns typical of tholeiitic affinity. Nd and Pb isotopic ratios of plagiorhyolites, which are similar to those of Groups 1 and 3 basalts, support that these felsic lavas formed by anatexis of the arc lower crust. Geochemical modelling points that the parental basic magmas of the Maimón meta-volcanic rocks formed by hydrous melting of a heterogeneous spinel-facies mantle source, similar to depleted MORB mantle (DMM) or depleted DMM (D-DMM), fluxed by fluids from subducted oceanic crust and Atlantic Cretaceous pelagic sediments. Variations of subduction-sensitive element concentrations and ratios from Group 1 to the younger rocks of Groups 2 and 3 generally match the geochemical progression from FAB-like to boninite and IAT lavas described in subduction-initiation ophiolites. Group 1 basalts likely formed at magmatic stages transitional between FAB and first-island arc magmatism, whereas Group 2 boninitic lavas resulted from focused flux melting and higher degrees of melt extraction in a more mature stage of subduction. Group 3 basalts probably represent magmatism taking place immediately before the establishment of a steady-state subduction regime. The relatively high extents of flux melting and slab input recorded in the Maimón lavas support a scenario of hot subduction beneath the nascent Greater Antilles paleo-arc. Paleotectonic reconstructions and the markedly depleted, though heterogeneous character of the mantle source, indicate the rise of shallow asthenosphere which had sourced mid-ocean ridge basalts (MORB) and/or back-arc basin basalts (BABB) in the proto-Caribbean domain prior to the inception of SW-dipping subduction. Relative to the neighbouring Aptian-Albian Los Ranchos Formation, we suggest that Maimón volcanic rocks extruded more proximal to the vertical projection of the subducting proto-Caribbean spreading ridge.

Origin of back-arc basins and effects of western Pacific subduction systems on eastern China geology

NASA Astrophysics Data System (ADS)

Niu, Y.

2013-12-01

Assuming that subduction initiation is a consequence of lateral compositional buoyancy contrast within the lithosphere [1], and recognizing that subduction initiation within normal oceanic lithosphere is unlikely [1], we can assert that passive continental margins that are locations of the largest compositional buoyancy contrast within the lithosphere are the loci of future subduction zones [1]. We hypothesize that western Pacific back-arc basins were developed as and evolved from rifting at passive continental margins in response to initiation and continuation of subduction zones. This hypothesis can be tested by demonstrating that intra-oceanic island arcs must have basement of continental origin. The geology of the Islands of Japan supports this. The highly depleted forearc peridotites (sub-continental lithosphere material) from Tonga and Mariana offer independent lines of evidence for the hypothesis [1]. The origin and evolution of the Okinawa Trough (back-arc basin) and Ryukyu Arc/Trench systems represents the modern example of subduction initiation and back-arc basin formation along a (Chinese) continental margin. The observation why back-arc basins exit behind some subduction zones (e.g., western Pacific) but not others (e.g., in South America) depends on how the overlying plate responds to subduction, slab-rollback and trench retreat. In the western Pacific, trench retreat towards east results in the development of extension in the upper Eurasian plate and formation of back-arc basins. In the case of South America, where no back-arc basins form because trench retreat related extension is focused at the 'weakest' South Mid-Atlantic Ridge. It is thus conceptually correct that the South Atlantic is equivalent to a huge 'back-arc basin' although its origin may be different. Given the negative Clayperon slope of the Perovskite-ringwoodite phase transition at the 660 km mantle seismic discontinuity (660-D), slab penetration across the 660-D is difficult and trench retreat in the western Pacific readily result in the horizontal stagnation of the Pacific plate in the transition zone beneath eastern Asian continent [2]. Dehydration of this slab supplies water, which rises and results in 'basal hydration weakening' of the eastern China lithosphere and its thinning by converting it into weak material of asthenospheric property [3]. We note the proposal that multiple subduction zones with more water (i.e., subduction of the South China Block beneath the North China Craton, NCC; subduction of the Siberian/Mongolian block beneath the NCC) all contribute to the lithosphere thinning beneath the NCC [4]. However, 'South China-NCC' and 'Siberian/Mongolian-NCC' represent two collisional tectonics involving no trench retreat, causing no transition-zone slab stagnation, supplying no water, and thus contributing little to lithosphere thinning beneath the NCC. Furthermore, lithosphere thinning happened to the entire eastern China, not just limited to the NCC, emphasizing the effects of the western Pacific subduction system on eastern China geology. References: [1] Niu et al., 2003, Journal of Petrology, 44, 851-866. [2] Kárason & van der Hilst, R., 2000, Geophysical Monograph, 121, 277-288. [3] Niu, 2005, Geological Journal of China Universities, 11, 9-46. [4] Windley et al., 2010, American Journal of Science, 310, 1250-1293.

Incorporation of crust at the Lesser Antilles arc

NASA Astrophysics Data System (ADS)

Davidson, J. P.; Bezard, R. C.

2012-12-01

Most convergent margin magmas exhibit geochemical characteristics of continental crust, incorporated via subduction of continental sediment into the arc source (mantle wedge) or via assimilation of continental crust by arc magmas en route to surface. Resolving which of these processes dominate at a given arc is important in avoiding the circularity of the question of the origin of the continental crust. The Lesser Antilles is built on oceanic lithosphere so in principle any crustal signature has been introduced via sediment subduction. Geochemical variations in magmas along the arc have been matched with the variations displayed in sediments outboard of the trench 1 . At about the same time, similarly comprehensive data sets were produced from along the Lesser Antilles, arguing that much of the geochemical diversity reflected crustal contamination rather than source contamination 2. These claims were based on; 1) correlations between isotopic ratios and indices of differentiation, 2) high delta18O, which argues for extensive interaction with material that has interacted with water at low T and finally the observation that the highest Pb isotope ratios in the lavas actually exceed the highest seen in the sediments. The latter problem has now been solved since a wider range of sediments have now been examined, with a section of black shales exhibiting remarkably radiogenic Pb isotopes 3 . We have re-examined the origin of geochemical variations by comparing two specific volcanoes, Mt Pelee in the centre of the arc and The Quill in the north 4. The idea is to explore differentiation trends at a given volcano, and back project them to reasonable primitive magma compositions. In that way we can account for geochemical effects resulting from differentiation, and focus on source variations (contributions from slab to wedge along the Antilles). From this we conclude that 1) both suites differentiate largely by amphibole-plag fractionation, along with contamination by the arc crust, and 2) the source at each volcano is modified by addition of sediment or melt thereof, +/- fluid, consistent with observed sediment compositions. We have also focussed on some of the most isotopically extreme rocks along the arc (at St Lucia), given that they are the most crust-like and therefore have either assimilated prodigious amounts of sediment, or incorporated massive amounts of sediment into their sources. Here we have found variations in 87Sr/86Sr in single feldspar crystals and high delta 18O in crystals. Both observations are consistent with crustal contamination rather than source contamination. The implication that a continental component is available in the arc lithosphere as an assimilant needs to be reconciled with geodynamic models for the arc. 1. White, W. M. & Dupre, B. (1986).. Journal of Geophysical Research 91, 5927^5941. 2. Davidson, J. P. 1987.. Geochimica et Cosmochimica Acta 51, 2185-2198. 3. Carpentier, M., Chauvel, C. & Mattielli, N., 2008.. Earth and Planetary Science Letters 272, 199-211. 4. Davidson, J. P. and Wilson, B.M., 2011.. J. Petrol., 52, 1493-1531. doi:10.1093/petrology/egq095

Structural Composite Construction Materials Manufactured from Municipal Solid Waste

DTIC Science & Technology

1994-04-20

in Table 1. Candidate matrix materials included polystyrene (PS) or expanded polystyrene (EPS), high density polyethylene (HDPE), and polyethylene...companies make a variety of expanded polystyrene insulation panels that arc used in insulation and roofing systems.46 Thermoplastics are seeing

Effect of sulfate on the liquidus and sulfur concentration at anhydrite saturation (SCAS) of hydrous basalt at subduction zones

NASA Astrophysics Data System (ADS)

Chowdhury, P.; Dasgupta, R.

2017-12-01

Sulfur (S) as sulfide minerals, melts, and as S2- species in silicate melts is prevalent in many different tectono-magmatic settings in Earth. Yet, S as anhydrite or as SO42- species in fluids and melts is thought to be relevant for subduction zones, where the presence of sulfate over sulfide is argued to play a key role in processes such as mobility of chalcophile element [e.g., 1], oxidation of mantle and mantle-derived magmas [2], and release of excess S-rich gases [3]. However, it remains unclear what role the slab-released SO42-, dissolved in fluids or melts plays in magma genesis in sub-arc mantle. Furthermore, although oxidized arc magma is thought to transport SO42- from mantle to volcanic arc crust and atmosphere, the SO42- carrying capacity of arc basalts at mantle conditions are unknown as the existing S concentration at anhydrite saturation (SCAS) experiments are restricted to 1 GPa and mostly on felsic compositions [e.g. 4,5]. We performed piston-cylinder experiments in Au-Pd capsules at 1-3 GPa and 1000-1325 °C to investigate (a) the effect of variable dissolved SO42- (0-2 wt.% S) on the liquidus of a primary hydrous arc basalt with 4 wt.% H2O and (b) the SCAS of hydrous mafic magmas. Dissolved SO42- in the silicate melt was confirmed by S Kα X-ray peak position using electron microprobe. S-free hydrous liquidus of cpx at 2 GPa is 25 °C hotter than the liquidus with 0.1 wt.% S as SO42- and the liquidus depression with further S enrichment to anhydrite saturation ( 2 wt.% S) can be fitted by an empirical power function. Experiments on more mafic compositions show that SCAS increases with increasing temperature and CaO and decreases with SiO2. Calculations using a new SCAS model, fitted with our new data and previous experiments, and assuming 150-550 ppm S in the arc mantle [6] show that <10% melting would exhaust anhydrite, if present. The S content as SO42- of hydrous arc basalts produced by 10-20% melting [7] will be 500-4000 ppm, which is comparable to the melt inclusion S contents from various arcs [8]. The SO42- undersaturated basalts may assimilate crustal sulfate and lead to high observed SO2 flux. [1] Canil & Fellows, 2017, EPSL [2] Kelley and Cottrell, 2009, Science [3] Wallace, 2005, JVGR [4] Luhr, 1990, J.Pet [5] Costa et al., 2004, J.Pet [6] de Hoog et al., 2001a, GCA [7] Kelley et al., 2006, JGR [8] Ruscitto et al., 2012, G3

Influence of sediment recycling on the trace element composition of primitive arc lavas

NASA Astrophysics Data System (ADS)

Collinet, M.; Jagoutz, O. E.

2017-12-01

Primitive calc-alkaline lavas from continental arcs are, on average, enriched in incompatible elements compared to those from intra-oceanic arcs. This relative enrichment is observed in different groups of trace elements: LILE (e.g. K, Rb), LREE to MREE (La-Dy) and HFSE (e.g.Zr, Nb) and is thought to result from (1) a transfer of material from the subducting slab to the mantle wedge at higher temperature than in intra-oceanic margins and/or (2) lower average degrees of melting in the mantle wedge, as a consequence of thicker overlying crusts and higher average pressures of melting. In addition to thicker overlying crusts and generally higher slab temperatures, continental margins are characterized by larger volumes of rock exposed above sea level and enhanced erosion rates compared to intra-oceanic arcs. As several geochemical signatures of arc lavas attest to the importance of sediment recycling in subduction zones, we explore the possibility that the high concentrations of incompatible elements in primitive lavas from continental arcs directly reflect a larger input of sediment to the subduction system. Previous efforts to quantify the sediment flux to oceanic trenches focused on the thickness of pelagic and hemipelagic sediments on top of the plate entering the subduction zone (Plank and Langmuir, 1993, Nature). These estimates primarily relied on the sediment layer drilled outboard from the subduction system and likely underestimate the volume of sediment derived from the arc itself. Accordingly, we find that such estimates of sediment flux do not correlate with the concentration of incompatible elements in primitive arc lavas. To account for regional contributions of coarser detrital sediments, usually delivered to oceanic trenches by turbidity currents, we apply to arc segments a model that quantifies the sediment load of rivers based on the average relief, area, temperature and runoff of their respective drainage areas (Syvitski et al., 2003, Sediment. Geol.). Our new estimates of sediment fluxes correlate positively with incompatible element concentrations in primitive arc lavas. We conclude that a large fraction of the local terrigenous sediments is subducted and contributes to the observed dichotomy in the trace element budget between primitive lavas from continental and oceanic margins.

Examination of the physical processes associated with the keyhole region of variable polarity plasma arc welds in aluminum alloy 2219

NASA Technical Reports Server (NTRS)

Walsh, Daniel W.

1987-01-01

The morphology and properties of the Variable Polarity Plasma Arc (VPPA) weld composite zone are intimately related to the physical processes associated with the keyhole. This study examined the effects of oxide, halide, and sulfate additions to the weld plate on the keyhole and the weld pool. Changes in both the arc plasma character and the bead morphology were correlated to the chemical environment of the weld. Pool behavior was observed by adding flow markers to actual VPPA welds. A low temperature analog to the welding process was developed. The results of the study indicate that oxygen, even at low partial pressures, can disrupt the stable keyhole and weld pool. The results also indicate that the Marangoni surface tension driven flows dominate the weld pool over the range of welding currents studied.

High intensity discharge device containing oxytrihalides

DOEpatents

Lapatovich, Walter P.; Keeffe, William M.; Liebermann, Richard W.; Maya, Jakob

1987-01-01

A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO.sub.2, with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube.

High intensity discharge device containing oxytrihalides

DOEpatents

Lapatovich, W.P.; Keeffe, W.M.; Liebermann, R.W.; Maya, J.

1987-06-09

A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO[sub 2], with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube. 7 figs.

Insights into the Early to Late Oligocene Izu-Bonin Mariana Arc Magmatic History from Volcanic Minerals and Glass within Volcaniclastic Sediments of IODP Site U1438 and DSDP Site 296

NASA Astrophysics Data System (ADS)

Samajpati, E.; Hickey-Vargas, R.

2017-12-01

The Kyushu-Palau Ridge (KPR) is a remnant of the early Izu-Bonin-Mariana (IBM) island arc, separated by arc rifting and seafloor spreading. We examine and compare volcanic materials from two sites where the transition from IBM arc building to rifting is well sampled: DSDP Site 296 on the northern KPR crest, and recent IODP Site U1438 in the adjacent Amami-Sankaku basin to the west. The purpose of the study is to understand the origin and depositional regime of volcaniclastic sediments during the arc rifting stage. Site 1438 sedimentary Unit II and the upper part of Unit III (300 and 453 mbsf) correlate in time with sedimentary Units 1G and 2 of DSDP Site 296 (160 and 300 mbsf). The upper part of Site U1438 Unit III and Site 296 Unit 2 consist of early to late Oligocene coarse volcaniclastic sedimentary rocks. These are overlain by late Oligocene nannofossil chalks with volcanic sand and ash-rich layers at Site 296 Unit 1G, and tuffaceous silt, sand, siltstone and sandstone at Site 1438 Unit II. The chemical composition of volcanic glass shards, pyroxenes with melt inclusions and amphiboles separated from volcaniclastic sediments were analyzed by EPMA and LA-ICPMS. Glasses are found at Site 296 only, range from medium-K basalt to rhyolite and have trace element patterns typical of arc volcanics. Clinopyroxene and orthopyroxene are found as detrital grains in sediments from both sites. Mg-numbers range from 58 to 94. Interestingly, the alumina content of pyroxene grain populations from both sites increase and then decrease with decreasing Mg-number. This probably reflects control of Al contents in magma and pyroxene by suppressed plagioclase saturation, which apparently was a consistent feature of KPR volcanoes. Melt-inclusions within the pyroxenes are typically small (30-50 microns) and have similar chemical compositions within one grain. The melt inclusions range from basalt to rhyolite with moderate alkali content. Amphibole is more prevalent in late Oligocene sequences and is mainly magnesiohornblende, with some more alkali-rich grains. Mantle normalized trace element patterns of the amphiboles show depletion in LREE and HFSE (Nb, Zr and Hf) and flat MREE and HREE. Downcore mineralogical and geochemical changes at these sites will be interpreted in the context of arc evolution.

A study of the role of fillers in silicone rubber compounds for outdoor insulation

NASA Astrophysics Data System (ADS)

Meyer, Luiz Henrique

Polymeric materials are being used as a housing material on high voltage outdoor insulation as an alternative to porcelain or glass in line insulators, surge arresters, station posts, and bushings. Among the polymeric materials in use, silicone rubber has proven to have good aging performance under polluted conditions by keeping low levels of leakage current by virtue of its hydrophobicity. However, the exposure of polymeric materials to contaminated and humid environments can lead to certain surface conditions that reduces hydrophobicity increasing leakage current levels, giving rise to dry band arcing. Dry band arcing produces heat, which can result in tracking or erosion of the housing material. Although this dry band arcing does not harm porcelain or glass housings, it will erode pure silicone rubber to such an extent that its application in outdoor environments is not, practical. Fillers are added to silicone rubber to improve tracking and erosion resistance. Among the filler choices, alumina trihydrate (ATH) and silica have been extensively adopted in the compounding of polymeric housings. ATH is a flame retardant that has a molecular water in its formulation. Whenever the surface temperature of an ATH filled polymer reaches approximately 220°C, the water of hydration is released from the ATH molecule, what is recognized as an efficient way to cool down the surface, for example, in the case of dry band arcing. Alternatively, silica has very good bonding with the polymer backbone, imparting mechanical strength to the composite matrix. In addition, fillers such as ATH or silica increase the thermal conductivity of silicone rubber composites, which facilitates moving the heat away from its source, that is, from the origin of dry band arcing. Although heat is considered to be the main degradation factor when dry band arcing occurs, very little information is available on the thermal performance of filled silicone rubber. The standard methods available to test tracking and erosion resistance of filled silicone rubber do not allow to delineate the fundamentals of the thermal degradation, where the heat from the dry band arcing is the main degradation factor. In this work, a thermal imaging camera is used to investigate the thermal performance of filled silicone rubber in an inclined plane test. Infrared laser based techniques are developed to study the material performance. Furthermore, this thesis addresses the measurement of the thermal conductivity, based on infrared laser and thermal imaging, but using simple concepts. Theoretical and empirical models are developed in support of the experimental investigation.

Relationships between Microbial Activities and Subduction-related Outgassing and Volatile Flux at Aleutian Arc Volcanoes

NASA Astrophysics Data System (ADS)

Miller, H.; Lopez, T. M.; Fischer, T. P.; Schrenk, M. O.

2016-12-01

Subduction-related processes, including the movement and alteration of carbon compounds, are an important component of global geochemical cycles. Actively degassing volcanoes of the Aleutian Island arc offer interesting opportunities to not only characterize the composition and abundance of volatiles, but also to identify the origin of the discharging gases (e.g. mantle, organic matter, or carbonates). Taking this approach a step further, microbial activities in and around volcanic fumarole areas may impact the composition and flux of reduced volcanic gases, either through their modification or their assimilation into fixed biomass. Microbiological studies of these systems can be used to develop predictive models to complement those based upon geochemical data while providing greater understanding of the causal relationships between microbial populations and their environment, and ultimately refine estimates of volcanic outgassing. Coupled fumarole soil and gas samples were collected from several Aleutian Island volcanoes in 2015 (Gareloi, Kanaga, Kiska, Little Sitkin) and 2016 (Okmok, Resheschnoi). DNA was extracted from the soil and used to describe microbial community composition, while gas samples were analyzed through chromatography and mass spectrometry. Preliminary data suggests a relationship between the abundance of specific groups of prokaryotes known to metabolize reduced gases, such as sulfur-oxidizers and methanotrophs, and the abundances of the degassing volatiles, including sulfur dioxide and methane. Ongoing studies aimed at investigating the relationship between the genomic composition of the fumarolic microbial community and the physical and chemical properties of the soil (i.e. mineralogy, bulk geochemistry, nutrient concentration, gas flux, and environmental measurements) are underway. These data will be used to evaluate the potential for microbial communities to remove volcanic carbon and store it as biomass, or to modify the volatile carbon flux through metabolic activities. When holistically considered, these data will help to refine estimates of volatile flux and outgassing from the Aleutian Arc, particularly those involving carbon compounds, and potentially provide a novel predictive tool that can be applied in high throughput to volcanoes worldwide.

Petrogenesis of ultramafic rocks and olivine-rich troctolites from the East Taiwan Ophiolite in the Lichi mélange

NASA Astrophysics Data System (ADS)

Morishita, Tomoaki; Ghosh, Biswajit; Soda, Yusuke; Mizukami, Tomoyuki; Tani, Ken-ichiro; Ishizuka, Osamu; Tamura, Akihiro; Komaru, Chihiro; Aari, Shoji; Yang, Hsiao-Chin; Chen, Wen-Shan

2017-12-01

We examine ultramafic and olivine-rich troctolite blocks of the East Taiwan Ophiolite (ETO) in the Lichi Mélange. Although ultramafic rocks are extensively serpentinized, the primary minerals, such as olivine, orthopyroxene, clinopyroxene, spinel and plagioclase can be identified. The ultramafic rocks are classified into harzburgite (± clinopyroxene), dunite, and olivine websterite. Major and trace element compositions of the primary minerals in harzburgites, such as the Cr# [= Cr/(Cr + Al) atomic ratio] of chromian spinel (0.3-0.58) and incompatible elements-depleted trace element patterns of clinopyroxenes, indicate their residue origin after partial melting with less flux components. These compositions are similar to those from mid-ocean ridge peridotites as well as back-arc peridotites from the Philippine Sea Plate. The olivine websterite contains discrete as well as occasional locally concentrated plagioclase grains. Petrological characteristics coupled with similarity in trace element patterns of clinopyroxenes in the harzburgite and olivine websterite samples indicate that the olivine websterite is likely formed by clinopyroxene addition to a lherzolitic/harzburgitic peridotite from a pyroxene-saturated mafic melt. Dunite with medium Cr# spinels indicates cumulus or replacement by melt-peridotite reaction origins. Mineral composition of olivine-rich troctolite cannot be explained by simple crystallization from basaltic magmas, but shows a chemical trend expected for products after melt-peridotite interactions. Mineral compositions of the dunite and olivine-rich troctolite are also within chemical ranges of mid-ocean ridge samples, and are slightly different from back-arc samples from the Philippine Sea Plate. We conclude that peridotites in the ETO are not derived from the northern extension of the Luzon volcanic arc mantle. Further geochronological study is, however, required to constrain the origin of the ETO ophiolite, because peridotites are probably indistinguishable in petrology and mineralogy between the Philippine Sea and the South China Sea/Eurasian Plates.

Subaerial records of large-scale explosive volcanism and tsunami along an oceanic arc, Tonga, SW Pacific

NASA Astrophysics Data System (ADS)

Cronin, S. J.; Smith, I. E.

2015-12-01

We present a new chronology of major terrestrial eruptions and tsunami events for the central Tongan Arc. The active Tonga-Kermadec oceanic arc extends 2500 km northward of New Zealand and hosts many tens of submarine volcanoes with around a dozen forming islands. Despite its obious volcanic setting, the impacts of explosive volcanism and volcano-tectonic related tsunami are an often overlooked in archaeological and paleo-botanical histories, mainly due the lack of good Holocene subaerial exposures. The inhabited small uplifted coral platform islands east of the volcanic arc in Tonga collectively cover only <550 km2. Inspired by local mythology of gods flying overhead with baskets of ash, and an analysis of the high-level wind distribution patterns, lake and wetland sites were investigated along the Tongan chain. In most cases former lagoon basins lifted above sea-level by a combination of tectonic rise and the lowering of mean sea levels by around 2 m since the Mid-Holocene form closed lake or swampy depressions. Coring reveaed between 6 and 20 mineral layers at each site, withn humic sediment or peat. Over thirty new radiocarbon dates were collected to develop a chronology for the sequences and the mineral layers were examined mineralogically and geochemically. These sites reveal mainly tephra fall layers of <6500 cal. years B.P., including several very large and regionally significant tephras. Erupted compositions range from basaltic to dacitic, with some showing compositional change during eruption. In addition, some large eruptions appear to have generated regionally significant tsunami, represented by characteristically mixed sandy layers with lithologies including shell fragment, foraminifera and volcanic particles.

Linking Serpentinite Geochemistry with Possible Alteration and Evolution of Supra-Subduction Wedge Mantle

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Cannaò, E.; Agostini, S.; Gilio, M.

2016-12-01

Serpentinites are able to transport and release volatiles and fluid-mobile elements (FME) found in arc magmas. Constraining the trace element compositions of these rocks and of fluids released by de-serpentinization improves our knowledge of mass transfer from subduction zones to volcanic arcs, and of the role of slab and wedge mantle in this global process. Studies of high-pressure ultramafic rocks exhumed from plate interface settings reveal the fluid/rock interactions atop the slab and the processes that can affect the mantle wedge. Alpine eclogite-facies antigorite serpentinite (Voltri Massif) and fully de-serpentinized meta-peridotite (Cima di Gagnone) are enriched in sediment-derived As, Sb, U, Pb before peak dehydration. Their Sr, Pb and B isotopic compositions are reset during prograde (forearc) interaction with slab fluids. The eclogitic garnet and olivine from the Cima di Gagnone metaperidotite trap primary inclusions of the fluid released during breakdown of antigorite and chlorite. The inclusions display FME enrichments (high Cl, S; variable Cs, Rb, Ba, B, Pb, As, Sb) indicating element release from rocks to fluids during dehydration under subarc conditions. Our studies show that serpentinized mantle rocks from subduction zones sequester FME from slab fluids and convey these components and radiogenic isotopes into the mantle wedge upon dehydration. The geochemical processes revealed by such plate-interface rocks can apply to the supra-subduction mantle. Shallow element release from slabs to mantle wedge, downdrag of this altered mantle and its subsequent (subarc) dehydration transfers crust-derived FMEs to the arc magma sources without the need of concomitant subarc dehydration/melting of metasedimentary slab components. The slab signature detected in arc lavas can thus result from geochemical mixing of sediment, oceanic crust and ultramafic reservoirs into altered wedge-mantle rocks, rather than being attributed to multiple fluids.

Lower Brioverian formations (Upper Proterozoic) of the Armorican Massif (France): geodynamic evolution of source areas revealed by sandstone petrography and geochemistry

NASA Astrophysics Data System (ADS)

Dabard, Marie Pierre

1990-11-01

Formations with interbedded cherts constitute an important part of the Lower Brioverian succession (Upper Proterozoic age) in the Armorican Massif (northwest France). These formations are composed of shale-sandstone alternations with interbedded siliceous carbonaceous members. Petrographic and geochemical study of the detrital facies shows that these rocks are compositionally immature. The wackes are rich in lithic fragments (volcanic fragments: 3-20% modal; sedimentary and metamorphic fragments: 0-7% modal) and in feldspar (5-16%). From the geochemical point of view, they are relatively enriched in Fe 2+MgO (about 5.5%) and in alkalis with {Na 2O }/{K 2O } ratios greater than 1. The CaO contents are low (about 0.3%). Slightly negative Eu anomalies are observed ( {Eu}/{Eu ∗} = 0.8 ). Their chemical compositions are in agreement with a dominantly acidic source area with deposition in a continental active margin setting. Compared with other Upper Proterozoic deposits of the Armorican Massif, the interbedded-chert formations appear rather similar to other deposits in North Brittany which accumulated in an intra-arc or back-arc basin environment. The formations with interbedded cherts are interpreted as having been deposited during an early stage of magmatic arc activity (around 640-630 Ma ago) in an immature marginal basin. The clastic supply to these formations is derived in part from early volcanic products (acidic to intermediate) which are linked to subduction beneath the North Armorican Domain. Another component is inherited from the reworking of 2000 Ma old basement relics. The opening of the back-arc domain, with associated basaltic volcanism, would bring about a progressive displacement of the interbedded-chert depositional basin towards the continental margin.

USSR and Eastern Europe Scientific Abstracts, Materials Science and Metallurgy, Number 47

DTIC Science & Technology

1977-09-27

temperature intervals may vary and depends on the composition and previous heat treatment history of the alloy. Figures 2; references 13: 1 Russian, 12... HISTORY OF AMg6 ALLOY INTERMEDIATE WORKPIECES ON THE TIGHTNESS AND MECHANICAL PROPERTIES OF WELDS Kiev AVTOMATICHESKAYA SVARKA In Russian No 5(290), May...of Sciences Ukrainian SSR [Abstract] The effect of flux composition during argon-arc welding of titani - um with a nonconsumable electrode on melting

Defense Small Business Innovation Research Program (SBIR). Program Solicitation Number 89.1. FY-1989

DTIC Science & Technology

1989-01-06

scale testing, such as plasma-arc and oxyacetylene torch test are performed. However, correlations to relate ablation rate from these test data to...helicopter rotor. In phase II, the contractor should construct and demonstrate a working model. 36 A89-010 TITLE: Smooth, Erosion Resistant Coatings ...for Organic Matrix Composites OBJECTIVE: Erosion Resistant Coatings for Organic Matrix Composites for use in Compressor Section of Future Gas Turbine

Origin of narrow terranes and adjacent major terranes occurring along the denali fault in the eastern and central alaska range, alaska

USGS Publications Warehouse

Nokleberg, W.J.; Richter, D.H.

2007-01-01

Several narrow terranes occur along the Denali fault in the Eastern and Central Alaska Range in Southern Alaska. These terranes are the Aurora Peak, Cottonwood Creek, Maclaren, Pingston, and Windy terranes, and a terrane of ultramafic and associated rocks. Exterior to the narrow terranes to the south is the majorWrangellia island arc composite terrane, and to the north is the major Yukon Tanana metamorphosed continental margin terrane. Overlying mainly the northern margin of the Wrangellia composite terrane are the Kahiltna overlap assemblage to the west, and the Gravina- Nutzotin-Gambier volcanic-plutonic- sedimentary belt to the east and southeast. The various narrow terranes are interpreted as the result of translation of fragments of larger terranes during two major tectonic events: (1) Late Jurassic to mid-Cretaceous accretion of the Wrangellia island arc composite terrane (or superterrane composed of the Wrangellia, Peninsular, and Alexander terranes) and associated subduction zone complexes; and (2) starting in about the Late Cretaceous, dextral transport of the Wrangellia composite terrane along the Denali fault. These two major tectonic events caused: (1) entrapment of a lens of oceanic lithosphere along the suture belt between the Wrangellia composite terrane and the North American Craton Margin and outboard accreted terranes to form the ultramafic and mafic part of the terrane of ultramafic and associated rocks, (2) subsequent dextral translation along the Denali fault of the terrane of ultramafic and associated rocks, (3) dextral translation along the Denali fault of the Aurora Peak, Cottonwood Creek, and Maclaren and continental margin arc terranes from part of the Coast plutonic-metamorphic complex (Coast-North Cascade plutonic belt) in the southwest Yukon Territory or Southeastern Alaska, (4) dextral translation along the Denali fault of the Pingston passive continental margin from a locus along the North American Continental Margin, and (5) formation and dextral transport along the Denali fault of the m??lange of the Windy terrane from fragments of the Gravina-Nutzotin-Gambier volcanic-plutonic-sedimentary belt and from the North American Continental Margin. Copyright ?? 2007 The Geological Society of America.

Crustal composition in the Hidaka Metamorphic Belt estimated from seismic velocity by laboratory measurements

NASA Astrophysics Data System (ADS)

Yamauchi, K.; Ishikawa, M.; Sato, H.; Iwasaki, T.; Toyoshima, T.

2015-12-01

To understand the dynamics of the lithosphere in subduction systems, the knowledge of rock composition is significant. However, rock composition of the overriding plate is still poorly understood. To estimate rock composition of the lithosphere, it is an effective method to compare the elastic wave velocities measured under the high pressure and temperature condition with the seismic velocities obtained by active source experiment and earthquake observation. Due to an arc-arc collision in central Hokkaido, middle to lower crust is exposed along the Hidaka Metamorphic Belt (HMB), providing exceptional opportunities to study crust composition of an island arc. Across the HMB, P-wave velocity model has been constructed by refraction/wide-angle reflection seismic profiling (Iwasaki et al., 2004). Furthermore, because of the interpretation of the crustal structure (Ito, 2000), we can follow a continuous pass from the surface to the middle-lower crust. We corrected representative rock samples from HMB and measured ultrasonic P-wave (Vp) and S-wave velocities (Vs) under the pressure up to 1.0 GPa in a temperature range from 25 to 400 °C. For example, the Vp values measured at 25 °C and 0.5 GPa are 5.88 km/s for the granite (74.29 wt.% SiO2), 6.02-6.34 km/s for the tonalites (66.31-68.92 wt.% SiO2), 6.34 km/s for the gneiss (64.69 wt.% SiO2), 6.41-7.05 km/s for the amphibolites (50.06-51.13 wt.% SiO2), and 7.42 km/s for the mafic granulite (50.94 wt.% SiO2). And, Vp of tonalites showed a correlation with SiO2 (wt.%). Comparing with the velocity profiles across the HMB (Iwasaki et al., 2004), we estimate that the lower to middle crust consists of amphibolite and tonalite, and the estimated acoustic impedance contrast between them suggests an existence of a clear reflective boundary, which accords well to the obtained seismic reflection profile (Iwasaki et al., 2014). And, we can obtain the same tendency from comparing measured Vp/Vs ratio and Vp/Vs ratio structure model (Matsubara and Obara, 2011).

Lithospheric and Asthenospheric Contributions to Post-Collisional Volcanism in the Lesser Caucasus Mts (Armenia)

NASA Astrophysics Data System (ADS)

Sugden, P.; Savov, I. P.; Wilson, M.; Meliksetian, K.; Navasardyan, G.

2017-12-01

Continental collision zones remain the most enigmatic tectonic setting for volcanic activity on earth. The Lesser Caucasus Mts are host to widespread and unique intraplate volcanism, associated with the active Arabia-Eurasia continental collision. Volcanic products range from alkali basalts to rhyolites (including extensive ignimbrites), and occur as basaltic lava flow fields, large composite and shield volcanoes, and regions of distributed (mostly monogenetic) volcanism. Geomorphology, archaeology, and historical accounts suggest volcanic activity has extended in to the Holocene-historical period. The high quality of the exposures and the diversity of unaltered rock types makes Armenia an ideal natural laboratory for studying the sources of magmatism in an active continental collision zone. For the first time, we will present the mineral chemistry (ol, px, amph), whole rock major and trace element, and Sr-Nd isotope compositions of volcanic rocks from southernmost Armenia- namely the Gegham, Vardenis and Syunik volcanic highlands. We compare our dataset with the composition of post-collisional volcanic rocks elsewhere in the Arabia-Eurasia collision zone. Samples from S. Armenia are more mafic, more alkaline and more K2O rich. All volcanic rocks show negative HFSE anomalies and LILE and LREE enrichments reminiscent of continental volcanic arc settings. However, volcanic rocks in Southern Armenia are further enriched in some of the most incompatible trace elements, most notably LREE, Sr and P, and have higher La/Yb, Th/Yb, Ta/Yb, and more variable Th/Nb. Volcanic rocks from Eastern Anatolia and N. Armenia have Sr-Nd isotope compositions similar to those of the Mesozoic volcanic arc (87Sr/86Sr 0.7034-0.7045; 143Nd/144Nd 0.5128-0.5129), whereas samples from S. Armenia deviate towards more enriched compositions resembling a typical EM-I type reservoir (87Sr/86Sr 0.7041- 0.7047; 143Nd/144Nd 0.5127-0.5128). We argue that these distinctive geochemical characteristics result from the addition of an enriched lithospheric component to a ubiquitous subduction-modified baseline asthenospheric mantle. This EM-I like component may be characteristic for not only intraplate hotspot volcanoes but also to collisional and arc settings.

Early Silurian to Early Carboniferous ridge subduction in NW Junggar: Evidence from geochronological, geochemical, and Sr-Nd-Hf isotopic data on alkali granites and adakites

NASA Astrophysics Data System (ADS)

Zhang, Chen; Santosh, M.; Liu, Luofu; Luo, Qun; Zhang, Xin; Liu, Dongdong

2018-02-01

The Central Asian Orogenic Belt (CAOB) evolved through a long-lived orogeny involving multiple episodes of subduction and accretion marking a major phase of continental growth during the Paleozoic. The northern part of the Western Junggar region (NW Junggar) offers a window into these processes, particularly to constrain the timing of closure of the Paleo-Asian Ocean. Here we report geochemical, geochronological, and isotopic data from K-feldspar granites and adakitic rocks from the NW Junggar region. Zircon U-Pb ages suggest that the granites were emplaced during Early Silurian to the Early Carboniferous (434-328 Ma). The granites show geochemical characteristics similar to those of A-type granites, with high SiO2 (71.13-76.72 wt%), Na2O + K2O (8.00-9.59 wt%), and Al2O3 (12.28-14.08 wt%), but depleted Sr, Nb, Ta and Eu. They display moderate to high positive εNd(t) and εHf(t) values (4.26-8.21 and 7.69-14.60, respectively) and young Nd and Hf model ages (T2DM-Nd = 489-740 Ma and T2DM-Hf = 471-845 Ma), suggesting magma derivation through partial melting of lower crust in the Boshchekul-Chingiz and Zharma-Saur arcs. The adakites are characterized by high Sr content (406.5-751.6 ppm), and low Y (13.8-16.4 ppm) and Yb (1.5-1.8 ppm) content, yielding relatively high Sr/Y ratios (25.38-49.41) similar to those of modern adakites. They have high positive εNd(t) and εHf(t) values (7.85-8.25 and 13.23-15.97, respectively) and young Nd and Hf model ages (T2DM-Nd = 429-535 Ma and T2DM-Hf = 355-550 Ma), indicating that their source magmas were likely derived from partial melting of the oceanic crust beneath the Boshchekul-Chingiz arc. The petrogenesis and distribution of the A-type granites and adakites, as well as the tectonic architecture of the region, suggest that a ridge subduction event might have occurred during the Early Silurian to Early Carboniferous. In combination with previous studies in the Chinese Altai, we suggest a two-sided ridge subduction model for the Junggar-Altai region.

Job Stability among Young Women: A Comparison of Traditional and Nontraditional Occupations. A Rand Note.

ERIC Educational Resources Information Center

Waite, Linda J.; Berryman, Sue E.

This study explores young women's retention in sex-atypical jobs in the military and in civilian firms. It tests the hypothesis that women tend to leave stereotypically male jobs at higher rates than they leave stereotypically female jobs. The study models job turnover over a one-year period as a function of (1) the sex composition of an…

Seeing the Forest "and" the Trees: Default Local Processing in Individuals with High Autistic Traits Does Not Come at the Expense of Global Attention

ERIC Educational Resources Information Center

Stevenson, Ryan A.; Sun, Sol Z.; Hazlett, Naomi; Cant, Jonathan S.; Barense, Morgan D.; Ferber, Susanne

2018-01-01

Atypical sensory perception is one of the most ubiquitous symptoms of autism, including a tendency towards a local-processing bias. We investigated whether local-processing biases were associated with global-processing impairments on a global/local attentional-scope paradigm in conjunction with a composite-face task. Behavioural results were…

Manipulation of Guaiacyl and Syringyl Monomer Biosynthesis in an Arabidopsis Cinnamyl Alcohol Dehydrogenase Mutant Results in Atypical Lignin Biosynthesis and Modified Cell Wall Structure.

PubMed

Anderson, Nickolas A; Tobimatsu, Yuki; Ciesielski, Peter N; Ximenes, Eduardo; Ralph, John; Donohoe, Bryon S; Ladisch, Michael; Chapple, Clint

2015-08-01

Modifying lignin composition and structure is a key strategy to increase plant cell wall digestibility for biofuel production. Disruption of the genes encoding both cinnamyl alcohol dehydrogenases (CADs), including CADC and CADD, in Arabidopsis thaliana results in the atypical incorporation of hydroxycinnamaldehydes into lignin. Another strategy to change lignin composition is downregulation or overexpression of ferulate 5-hydroxylase (F5H), which results in lignins enriched in guaiacyl or syringyl units, respectively. Here, we combined these approaches to generate plants enriched in coniferaldehyde-derived lignin units or lignins derived primarily from sinapaldehyde. The cadc cadd and ferulic acid hydroxylase1 (fah1) cadc cadd plants are similar in growth to wild-type plants even though their lignin compositions are drastically altered. In contrast, disruption of CAD in the F5H-overexpressing background results in dwarfism. The dwarfed phenotype observed in these plants does not appear to be related to collapsed xylem, a hallmark of many other lignin-deficient dwarf mutants. cadc cadd, fah1 cadc cadd, and cadd F5H-overexpressing plants have increased enzyme-catalyzed cell wall digestibility. Given that these CAD-deficient plants have similar total lignin contents and only differ in the amounts of hydroxycinnamaldehyde monomer incorporation, these results suggest that hydroxycinnamaldehyde content is a more important determinant of digestibility than lignin content. © 2015 American Society of Plant Biologists. All rights reserved.

Formation mechanism and adhesive strength of a hydroxyapatite/TiO2 composite coating on a titanium surface prepared by micro-arc oxidation

NASA Astrophysics Data System (ADS)

Liu, Shimin; Li, Baoe; Liang, Chunyong; Wang, Hongshui; Qiao, Zhixia

2016-01-01

A hydroxyapatite (HA)/TiO2 composite coating was prepared on a titanium surface by one-step micro-arc oxidation (MAO). The formation mechanism of the composite coating was investigated and the adhesion of the coating to the substrate was also measured. The results showed that flocculent structures could be obtained during the early stages of treatment. As the treatment period extended, increasing amounts of Ca-P precipitate appeared on the surface, and the flocculent morphology transformed into a plate-like morphology. Then the plate-like calcium and phosphate salt self-assembled to form flower-like apatite. The Ca/P atomic ratio gradually decreased, indicating that the amounts of Ca2+ ions which diffused into the coating decreased more rapidly than that of PO43- or HPO42-. The adhesive strength between the apatite and TiO2 coating was improved. This improvement is attributed to the interlocking effect between the apatite and TiO2 layer which formed simultaneously during the early stages of the one-step MAO. This study shows that it is a promising method to prepare bioactive coating on a titanium surface.

Transition Metal Systematics of Opx-Enriched Harzburgites From the Cascades Arc With Implications for the Origin of Cratonic Peridotites

NASA Astrophysics Data System (ADS)

Turner, S. J.

2007-12-01

A number of peridotite xenoliths collected from the Simcoe volcanic field region of the Cascades arc exhibit notable enrichment of modal orthopyroxene. The process driving this enrichment is most likely metasomatism of the mantle wedge by Si-rich fluids derived ultimately from the underlying slab. By investigating the resultant elemental systematics associated with subduction zone metasomatism of this type, we hope to shed light on the origin of other opx-rich peridotites, such as those seen in many cratonic xenolith suites. The xenoliths found in the Simcoe volcanic field provide a rare opportunity to examine the composition of sub arc mantle, as it is unusual to find mantle xenoliths in volcanic arc lavas. The samples were analyzed using laser ablation ICPMS and their bulk compositions were reconstructed from point-counted mineral modes. Two-pyroxene mineral thermometry of the samples yield temperatures of approximately 1000 degrees C, corresponding to a depth of origin at uppermost mantle pressures if typical arc geotherms are assumed. Most of the peridotites are harzburgites or olivine-orthopyroxenites (Mg#s 0.88-0.9; opx mode 0.15-0.9), with small amounts of clinopyroxene (<0.02). Clinopyroxenes are significantly enriched in the light rare earths, consistent with a metasomatic origin for these opx-rich harzburgites. Of note is the counterintuitive systematics of Zn. Whole-rock Zn decreases with opx, but Zn in olivine also decreases with opx mode while Zn in opx increases with opx mode, hence the decrease in whole- rock Zn is not simply due to mechanical segregation of harzburgite into opx- and ol-rich zones. In summary, the REE signatures suggest the subducting slab as the most likely candidate for the source of the fluids that caused the opx enrichment. The opx-enrichment itself and the unusual trends in Zn suggest a reaction between a silicic fluid and normal harzburgite. Moreover, the concomitant decrease in olivine and whole-rock Zn with opx mode suggests significant leaching of Zn from the peridotite during this process. Because the bulk partitioning of Zn in anhydrous peridotite melting is unity, low Zn contents are anomalous. The best explanation for these low values is that Zn partition coefficients decrease in hydrous environments. Many opx-enriched Archean cratonic peridotite xenoliths have anomalously low Zn contents, supporting the suggestion that such peridotites formed in arc environments.

Philippine Sea Plate inception, evolution, and consumption with special emphasis on the early stages of Izu-Bonin-Mariana subduction

NASA Astrophysics Data System (ADS)

Lallemand, Serge

2016-12-01

We compiled the most relevant data acquired throughout the Philippine Sea Plate (PSP) from the early expeditions to the most recent. We also analyzed the various explanatory models in light of this updated dataset. The following main conclusions are discussed in this study. (1) The Izanagi slab detachment beneath the East Asia margin around 60-55 Ma likely triggered the Oki-Daito plume occurrence, Mesozoic proto-PSP splitting, shortening and then failure across the paleo-transform boundary between the proto-PSP and the Pacific Plate, Izu-Bonin-Mariana subduction initiation and ultimately PSP inception. (2) The initial splitting phase of the composite proto-PSP under the plume influence at ˜54-48 Ma led to the formation of the long-lived West Philippine Basin and short-lived oceanic basins, part of whose crust has been ambiguously called "fore-arc basalts" (FABs). (3) Shortening across the paleo-transform boundary evolved into thrusting within the Pacific Plate at ˜52-50 Ma, allowing it to subduct beneath the newly formed PSP, which was composed of an alternance of thick Mesozoic terranes and thin oceanic lithosphere. (4) The first magmas rising from the shallow mantle corner, after being hydrated by the subducting Pacific crust beneath the young oceanic crust near the upper plate spreading centers at ˜49-48 Ma were boninites. Both the so-called FABs and the boninites formed at a significant distance from the incipient trench, not in a fore-arc position as previously claimed. The magmas erupted for 15 m.y. in some places, probably near the intersections between back-arc spreading centers and the arc. (5) As the Pacific crust reached greater depths and the oceanic basins cooled and thickened at ˜44-45 Ma, the composition of the lavas evolved into high-Mg andesites and then arc tholeiites and calc-alkaline andesites. (6) Tectonic erosion processes removed about 150-200 km of frontal margin during the Neogene, consuming most or all of the Pacific ophiolite initially accreted to the PSP. The result was exposure of the FABs, boninites, and early volcanics that are near the trench today. (7) Serpentinite mud volcanoes observed in the Mariana fore-arc may have formed above the remnants of the paleo-transform boundary between the proto-PSP and the Pacific Plate.

The vanadium isotope compositions of subduction zone lavas

NASA Astrophysics Data System (ADS)

Tian, S.; Huang, F.

2017-12-01

Vanadium is a redox sensitive element with multiple oxidation states, and thus it has the potential to trace redox-related processes. With the advancement of analytical method for V isotopes, we are now able to recognize V isotope fractionation for igneous rocks. Subduction zones are critical zones on the Earth for the interaction between crust and mantle where undergo complex geological processes. However, V isotope data of subduction zone lavas are still rare except those reported in [1]. To investigate the V isotope variations of subduction zones and discuss the potential to apply V to trace mantle redox state. In this contribution, we report δ51V for three subduction zone lavas from Kamchatka, Lesser Antilles, and Aleutians which are characterized by well-documented magmatic evolutionary series. 47 arc lava samples have been analyzed and the δ51V data of them range from -0.91‰ to -0.53‰ (2sd = 0.10 ‰). Among these samples, primitive arc basalts with MgO > 6 wt. % have an average δ51V of -0.80 ± 0.15‰ (2sd, n = 20), broadly consistent with δ51V data of MORB [2, 3]. Within the single arc of Kamchatka, δ51V data of primitive basalts from the arc front to the back-arc is almost constant, suggesting limited influences of mantle melting and source heterogeneity on V isotopes. δ51V data of these samples show no correlation with Ba/Nb, suggesting that fluids have little impact on V isotopes. On the other hand, δ51V data of the more involved samples with MgO < 6 wt. % are negatively correlated with MgO contents, indicating that the 50V preferentially enters crystalline minerals, which produces heavier V isotope compositions of residual melts. Distinct to the observation showing 2‰ fractionation reported in [1], the magnitude of V isotope fractionation in arc lavas is much smaller (0.38‰) in this study. Future works are needed for better understanding the V isotope fractionation mechanisms of subduction zone lavas. [1]Prytulak et al., 2017, Geochem. Persp. Let. 3, 75-84. [2]Huang et al., 2016, Goldschmidt Abstracts. 1190. [3] Prytulak et al., 2013, EPSL. 365, 177-189.

Sub-micrometer particles produced by a low-powered AC electric arc in liquids.

PubMed

Jaworski, Jacek A; Fleury, Eric

2012-01-01

The article presents the report of the production of composites of sub-micrometer metal particles in matrix consisted of the metal compounds by means of an AC electric arc in water and paraffin solutions using electrodes carbon-metal and metal-metal (metal: Ni, Fe, Co, Cu). The advantage of this method is the low electric power (from 5 to 10 W) needed in comparison to standard DC arc-discharge methods (0.8 to 3 kW). This method enables the production of particles from conductive material also in wide range of temperature and in solvent which could be either transparent to light or opaque. Moreover the solvent can be electrolyte or insulating liquid. The microstructure of the composite layer was investigated by scanning electron microscopy (SEM), Electron Probe Microanalysis (EPMA) and X-ray. During particles production in water metal oxides were created. Additionally using cobalt-copper, nickel-copper as couple electrodes, insoluble in water copper (II) hydroxide crystal grains were created additionally which crystals shape was depended on transition metal. For iron-copper couple electrodes system the copper (II) hydroxide was not formed. Experiments with sequence production of Ni and Fe particles with C electrode assisting in molten paraffin let to obtain both Ni and Fe particles surrounded by paraffin. After solidification the material was insulator but if locally magnetic field influenced on the liquid solution in that place after solidification a new composite was created which was electric current conductor with resistivity around 0.1 omega x m, was attracted by magnetic field and presented magneto resistance around 0.4% in changing magnetic field in a range 150 mT. After mixing the concentrated paraffin with normal paraffin resistivity of the mixture increased and it became photosensitive and created small voltage under light influence.

Tracing Altiplano-Puna plateau surface uplift via radiogenic isotope composition of Andean arc lavas

NASA Astrophysics Data System (ADS)

Scott, E. M.; Allen, M. B.; Macpherson, C.; McCaffrey, K. J. W.; Davidson, J.; Saville, C.

2016-12-01

We have compiled published geochemical data for Jurassic to Holocene Andean arc lavas from 5oN to 47oS, covering the current extent of the northern, central and southern volcanic zones. Using this dataset we evaluate the spatial and temporal evolution of age corrected Sr- and Nd-radiogenic isotopes in arc lavas at a continental-scale, in order to understand the tectonic and surface uplift histories of the Andean margin. It has long been noted that baseline 87Sr/86Sr and 143Nd/144Nd ratios of Quaternary lavas from the central volcanic zone, located within the Altiplano-Puna plateau, are distinct from volcanic rocks to the north and south. This is commonly attributed to greater crustal thickness, which increases to roughly twice that of the average continental crust within the Altiplano-Puna plateau. By comparing 87Sr/86Sr and 143Nd/144Nd ratios in Quaternary lavas to published crustal thickness models, present day topography and the compositions of basement terranes, we note that Sr- and Nd-isotope values of Quaternary lavas are an effective proxy for present day regional elevation. In contrast, variation in basement terranes has only a small, second order effect on isotopic composition at the scale of our study. Using this isotopic proxy, we infer the spatial extent of the plateau and its surface uplift history from the Jurassic to the present. Our results concur with a crustal thickening model of continued surface uplift, which initiated in the Altiplano, with deformation propagating southwards into the Puna throughout the Neogene and then continuing in central Chile and Argentina up to the present day.

Olivine and chromian spinel in primitive calc-alkaline and tholeiitic lavas from the southernmost cascade range, California: A reflection of relative fertility of the source

USGS Publications Warehouse

Clynne, M.A.; Borg, L.E.

1997-01-01

Chromian spinel and coexisting olivine phenocrysts from a geochemically diverse suite of primitive tholeiitic and calc-alkaline basalts and magnesian andesites from the Lassen region, in the southernmost Cascade Range, in California, show that the sub-arc mantle is zoned. Depleted calc-alkaline basalts and magnesian andesites erupt in the forearc region, and calc-alkaline basalts contain increasing abundances of incompatible elements toward the backarc. High-alumina olivine tholeiites erupt from the arc and backarc areas. Olivine from all these lavas displays a limited compositional range, from Fo86 to Fo91, and crystallized at high temperature, generally 1225-1275??C. Chromian spinel trapped in the olivine phenocrysts displays a large range of composition: Cr# values span the range 9-76. Excess Al in the spinel relative to that in 1-atm spinel suggests that it crystallized at elevated pressure. The phenocrysts in these lavas are in equilibrium with their host liquids. The full range of Cr# of the spinel compositions cannot be explained by differentiation or variable pressure, variations in f(O2), subsolidus equilibration or variations in degree of partial melting of a single peridotitic source. Rather, the systematic compositional differences among phenocrysts in these primitive lavas result from bulk chemical variability in their mantle sources. Correlations between spinel and host-rock compositions support the assertion that the geochemical diversity of Lassen basalts reflects the relative fertility of their mantle sources.

The dynamic history of the Trans-Mexican Volcanic Belt and the Mexico subduction zone

NASA Astrophysics Data System (ADS)

Ferrari, Luca; Orozco-Esquivel, Teresa; Manea, Vlad; Manea, Marina

2012-02-01

The Trans-Mexican Volcanic Belt (TMVB) is a 1000 km long Neogene continental arc showing a large variation in composition and volcanic style, and an intra-arc extensional tectonics. It overlies the Rivera and Cocos slabs, which display marked changes in geometry. Geophysical studies indicate that lithospheric mantle is very thin or absent beneath the forearc and arc, the fluids from the slab are released in a 40 to 100 km wide belt beneath the frontal part of the arc, and the lower crust beneath the arc is partially molten. East of 101°W the TMVB is built on a Precambrian to Paleozoic crust with thickness of 50-55 km. West of 101°W the TMVB is underlain by Jurassic to Cenozoic marine and continental arcs with a 35-40 km thick crust. The evolution of the TMVB occurred in four stages: 1) from ~ 20 to 10 Ma the initial andesitic arc moved inland showing progressively drier melting and, eventually, slab melting, suggesting flattening of the subducted slab; 2) since ~ 11 Ma a pulse of mafic volcanism migrated from west to east reaching the Gulf of Mexico by 7 Ma. This mafic lavas marks the lateral propagation of a slab tear, triggered by cessation of subduction beneath Baja California; 3) thereafter, the volcanic front started moving trenchward, with a marked phase of silicic volcanism between 7.5 and 3 Ma, local emplacement of small volume intraplate-like basalts since 5 Ma, and development of extensional faulting. These features are related to slab rollback, enhancing asthenophere flux into the mantle wedge and promoting partial melting of the crust; 4) the modern arc consists of a frontal belt dominated by flux and slab melting, and a rear belt characterized by more differentiated rocks or by mafic lavas with little or no evidence of subduction fluids but higher asthenosphere fingerprint.

Amphibole Fractional Crystallization and Delamination in Arc Roots: Implications for the `Missing' Nb Reservoir in the Earth

NASA Astrophysics Data System (ADS)

Galster, F.; Chatterjee, R. N.; Stockli, D. F.

2017-12-01

Most geologic processes should not fractionate Nb from Ta but Earth's major silicate reservoirs have subchondritic Nb/Ta values. Nb/Ta of >10000 basalts and basaltic andesites from different tectonic settings (GEOROC) cluster around 16, indistinguishable from upper mantle values. In contrast, Nb/Ta in more evolved arc volcanics have progressively lower values, reaching continental crust estimates, and correlate negatively with SiO2 (see figure) and positively with TiO2 and MgO. This global trend suggests that differentiation processes in magmatic arcs could explain bulk crustal Nb/Ta estimates. Understanding processes that govern fractionation of Nb from Ta in arcs can provide key insights on continental crust formation and help identify Earth's `missing' Nb reservoir. Ti-rich phases (rutile, titanite and ilmenite) have DNb/DTa <1, and therefore, their fractionation from mafic to intermediate liquids cannot explain the observed trend. Instead, fractionation of biotite and amphibole could lower Nb/Ta values in the evolved liquid. Lack of correlation between Nb/Ta and K2O in global volcanic rocks implies that biotite plays a minor role in fractionating Nb from Ta during differentiation. Experimental petrology and evidence from exposed arc sections indicate that amphibole fractionation and delamination of island arc roots can explain the andesitic composition of bulk continental crust. Experimental studies have shown that amphibole Mg# correlate with DNb/DTa and amphibole could effectively fractionate Nb from Ta. Preliminary data from lower to middle crustal amphiboles from preserved arcs show sub- to super-chondritic Nb/Ta up to >60. This suggests that delamination of amphibole-rich cumulates can be a viable mechanism for the preferential removal of Nb from the continental crust. Future examination of Nb/Ta ratios in lower crustal amphiboles from various preserved arcs will provide improved constraints on the Nb-Ta paradox of the silicate Earth.

Effect of indirect composite treatment microtensile bond strength of self-adhesive resin cements

PubMed Central

Escribano, Nuria; Baracco, Bruno; Romero, Martin; Ceballos, Laura

2016-01-01

Background No specific indications about the pre-treatment of indirect composite restorations is provided by the manufacturers of most self-adhesive resin cements. The potential effect of silane treatment to the bond strength of the complete tooth/indirect restoration complex is not available.The aim of this study was to determine the contribution of different surface treatments on microtensile bond strength of composite overlays to dentin using several self-adhesive resin cements and a total-etch one. Material and Methods Composite overlays were fabricated and bonding surfaces were airborne-particle abraded and randomly assigned to two different surface treatments: no treatment or silane application (RelyX Ceramic Primer) followed by an adhesive (Adper Scotchbond 1 XT). Composite overlays were luted to flat dentin surfaces using the following self-adhesive resin cements: RelyX Unicem, G-Cem, Speedcem, Maxcem Elite or Smartcem2, and the total-etch resin cement RelyX ARC. After 24 h, bonded specimens were cut into sticks 1 mm thick and stressed in tension until failure. Two-way ANOVA and SNK tests were applied at α=0.05. Results Bond strength values were significantly influenced by the resin cement used (p<0.001). However, composite surface treatment and the interaction between the resin cement applied and surface treatment did not significantly affect dentin bond strength (p>0.05). All self-adhesive resin cements showed lower bond strength values than the total-etch RelyX ARC. Among self-adhesive resin cements, RelyX Unicem and G-Cem attained statistically higher bond strength values. Smartcem2 and Maxcem Elite exhibited 80-90% of pre-test failures. Conclusions The silane and adhesive application after indirect resin composite sandblasting did not improve the bond strength of dentin-composite overlay complex. Selection of the resin cement seems to be a more relevant factor when bonding indirect composites to dentin than its surface treatment. Key words:Bond strength, self-adhesive cement, silane, dentin, indirect composite. PMID:26855700

Numerical investigation of the effects of iron oxidation reactions on the fume formation mechanism in arc welding

NASA Astrophysics Data System (ADS)

Sanibondi, Paolo

2015-09-01

Fume formation during arc welding has been modelled using a stochastic approach taking into account iron oxidation reactions. The model includes the nucleation and condensation of Fe and FeO vapours, the reaction of gaseous O2 and O on the nanoparticle surface, the coagulation of the nanoparticles including a sintering time as a function of temperature and composition, assuming chemical equilibrium for species in the gaseous phase. Results suggest that fumes generated in gas metal arc welding with oxidizing shielding mixtures are composed of aggregates of primary particles that are nucleated from gas-phase FeO and further oxidized to Fe3O4 and Fe2O3 in the liquid and solid phase, respectively. The composition of the fumes at the end of the formation process depends on the relative initial concentration of Fe and O2 species in the gas mixture and on the diameter of the primary particles that compose the aggregates: as the oxidation reactions are driven by deposition of oxygen on nanoparticle surface, the oxidation of larger particles is slower than that of smaller particles because of their lower surface to volume ratio. Solid-state diffusion is limiting the oxidation process at temperatures lower than 1500 K, inducing the formation of not fully oxidized particles composed of Fe3O4.

Cl-rich hydrous mafic mineral assemblages in the Highiș massif, Apuseni Mountains, Romania

NASA Astrophysics Data System (ADS)

Bonin, Bernard; Tatu, Mihai

2016-08-01

The Guadalupian (Mid-Permian) Highiș massif (Apuseni Mountains, Romania) displays a bimodal igneous suite of mafic (gabbro, diorite) and A-type felsic (alkali feldspar granite, albite granite, and hybrid granodiorite) rocks. Amphibole is widespread throughout the suite, and yields markedly high chlorine contents. Three groups are identified: Cl-rich potassic hastingsite (2.60-3.40 wt% Cl) within A-type felsic rocks and diorite, mildly Cl-rich pargasite to hornblende (0.80-1.90 wt% Cl) within gabbro, and low F-Cl hornblende within gabbro and hybrid granodiorite. Coexisting biotite is either Cl-rich within diorite, or F-Cl-poor to F-rich within A-type felsic rocks. Chlorine and fluorine are distributed in both mafic phases, according to the F-Fe and Cl-Mg avoidance rules. The low-Ti contents suggest subsolidus compositions. Cl-rich amphibole within diorite and A-type felsic rocks yields a restricted temperature range - from 575 °C down to 400 °C, whereas mildly Cl-rich amphibole within gabbro displays the highest range - from 675 to 360 °C. Temperatures recorded by Cl-rich biotite within diorite range from 590 to 410 °C. Biotite within A-type felsic rocks yields higher temperatures than amphibole: the highest values- from 640 to 540 °C - are recorded in low-F-Cl varieties, whereas the lowest values- from 535 to 500 °C - are displayed by F-rich varieties. All data point to halogen-rich hydrothermal fluids at upper greenschist facies conditions percolating through fractures and shear zones and pervasively permeating the whole Highiș massif, with F precipitating as interstitial fluorite and Cl incorporating into amphibole, during one, or possibly several, hydrothermal episodes that would have occurred during a ~ 150 My-long period of time extending from the Guadalupian (Mid-Permian) to the Albian (Mid-Cretaceous).

Modeling-independent elucidation of inactivation pathways in recombinant and native A-type Kv channels.

PubMed

Fineberg, Jeffrey D; Ritter, David M; Covarrubias, Manuel

2012-11-01

A-type voltage-gated K(+) (Kv) channels self-regulate their activity by inactivating directly from the open state (open-state inactivation [OSI]) or by inactivating before they open (closed-state inactivation [CSI]). To determine the inactivation pathways, it is often necessary to apply several pulse protocols, pore blockers, single-channel recording, and kinetic modeling. However, intrinsic hurdles may preclude the standardized application of these methods. Here, we implemented a simple method inspired by earlier studies of Na(+) channels to analyze macroscopic inactivation and conclusively deduce the pathways of inactivation of recombinant and native A-type Kv channels. We investigated two distinct A-type Kv channels expressed heterologously (Kv3.4 and Kv4.2 with accessory subunits) and their native counterparts in dorsal root ganglion and cerebellar granule neurons. This approach applies two conventional pulse protocols to examine inactivation induced by (a) a simple step (single-pulse inactivation) and (b) a conditioning step (double-pulse inactivation). Consistent with OSI, the rate of Kv3.4 inactivation (i.e., the negative first derivative of double-pulse inactivation) precisely superimposes on the profile of the Kv3.4 current evoked by a single pulse because the channels must open to inactivate. In contrast, the rate of Kv4.2 inactivation is asynchronous, already changing at earlier times relative to the profile of the Kv4.2 current evoked by a single pulse. Thus, Kv4.2 inactivation occurs uncoupled from channel opening, indicating CSI. Furthermore, the inactivation time constant versus voltage relation of Kv3.4 decreases monotonically with depolarization and levels off, whereas that of Kv4.2 exhibits a J-shape profile. We also manipulated the inactivation phenotype by changing the subunit composition and show how CSI and CSI combined with OSI might affect spiking properties in a full computational model of the hippocampal CA1 neuron. This work unambiguously elucidates contrasting inactivation pathways in neuronal A-type Kv channels and demonstrates how distinct pathways might impact neurophysiological activity.

Geochemistry and tectonic implications of the Early Carboniferous Keketuobie intrusion in the West Junggar foldbelt, NW China

NASA Astrophysics Data System (ADS)

Deng, Yu-Feng; Yuan, Feng; Zhou, Taofa; Hollings, Pete; Zhang, Dayu

2018-06-01

The Keketuobie intrusion is situated in the northern part of the West Junggar foldbelt at the southern margin of the Central Asian Orogeic Belt. The intrusion consists of medium- to coarse-grained gabbro, fine-grained gabbro and diorite. Igneous zircons from the medium- to coarse-grained gabbro yielded a LA-ICP-MS U-Pb age of 320.8 ± 5.7 Ma, indicating that the intrusion was emplaced in the Early Carboniferous. The intrusive contact between the medium- to coarse-grained gabbro and the fine-grained gabbro indicates they formed from distinct magma pulses. Magnetite crystals from the fine-grained gabbro have lower V2O3 but higher TiO2 and Al2O3 contents than those of the medium- to coarse-grained gabbro, suggesting that the fine-grained gabbro crystallized in a relatively higher fO2 and temperature magma than the medium- to coarse-grained gabbro. The Keketuobie intrusive rocks are characterized by enriched large ion lithophile elements and depleted high field strength elements relative to N-MORB with restricted (87Sr/86Sr)t ratios (0.70370-0.70400) and εNd(t) values (+5.85 to +6.97). The petrography and geochemistry are comparable to those of subduction-related volcanic rocks. The trace elements and isotopic compositions of the mafic intrusive rocks suggest that the primary magmas were derived from mixing of metasomatized lithospheric mantle and depleted asthenospheric melts, perhaps triggered by slab break-off. The Keketuobie intrusion is younger than adjacent ophiolite sequences, island arc volcanic rocks and porphyry deposits, but predates the post-collisional A-type granites and bimodal volcanic rocks in the district, suggesting that the Keketuobie intrusion likely formed in a syn-collisional setting.

Drilling constraints on bimodal volcanism and subsequent formation of contrasted uppermost crustal compositions at the middle Okinawa Trough

NASA Astrophysics Data System (ADS)

Yamasaki, T.; Takaya, Y.; Mukae, N.; Nagase, T.; Tindell, T.; Totsuka, S.; Uno, Y.; Yonezu, K.; Nozaki, T.; Ishibashi, J. I.; Kumagai, H.; Maeda, L.; Shipboard Scientist, C.

2016-12-01

The Okinawa Trough (OT) is a young and actively spreading back-arc basin, extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. The OT is believed to be in an initial rifting stage (starting from 6-9 Ma), prior to the normal/stable seafloor spreading which constitutes the main stage of back-arc basin formation. Two drilling cruises ‒ the IODP Exp. 331 and SIP CK14-04 D/V Chikyu Cruise (Exp. 907) in 2010 and 2014 ‒ were conducted at the Iheya North Knoll, middle OT. The Iheya North Knoll is a domal volcanic complex consisting of small volcanic bodies. On these cruises, pumiceous gravel and altered rhyolitic rocks, as well as hemi-pelagic sediments, hydrothermal clay and Kuroko-type ores, were recovered from the upper 200 m of the crust. From Feb. 11, 2016 to Mar. 17, 2016, the SIP CK16-01 (Exp. 908) D/V Chikyu cruise was conducted at Iheya North Knoll and the sediment-covered rifting center of the Iheya-Minor Ridge area, middle OT. The Iheya-Minor ridge area is also an active hydrothermal field, located 25 km southeast of the Iheya North Knoll. In this area, basaltic rocks are widely distributed, and drilling has confirmed that the basaltic materials continue to 120 m below the seafloor. From an igneous petrological point of view, the volcanic rocks in the Okinawa Trough are characterized by bimodal basaltic and rhyolitic compositions, with a compositional gap between SiO2 = 56-66 wt%. The origin of the rhyolitic rock has been interpreted as magmatic differentiation of basaltic magma. However, the existence of an active basalt-hosted hydrothermal field in the Iheya-Minor ridge area suggests the presence of hot basaltic rocks at a shallow position in the crust, and reaching recharged seawater at this depth. Furthermore, the composition of felsic rocks just after the compositional gap (SiO2 = 67 wt%) is very similar to that of the minimum melt of a granitic system, and experimental partial melt of hydrous basalt. Therefore, the contrast in the uppermost crustal composition between very close ( 25 km) areas can reasonably be explained by re-melting of hydrothermally-altered basaltic rocks and production of felsic magma at the upper crustal level, and direct eruption of basaltic magma at the seafloor.

Intelligent Support System of Steel Technical Preparation in an Arc Furnace: Functional Scheme of Interactive Builder of the Multi Objective Optimization Problem

NASA Astrophysics Data System (ADS)

Logunova, O. S.; Sibileva, N. S.

2017-12-01

The purpose of the study is to increase the efficiency of the steelmaking process in large capacity arc furnace on the basis of implementation a new decision-making system about the composition of charge materials. The authors proposed an interactive builder for the formation of the optimization problem, taking into account the requirements of the customer, normative documents and stocks of charge materials in the warehouse. To implement the interactive builder, the sets of deterministic and stochastic model components are developed, as well as a list of preferences of criteria and constraints.

Excess europium content in Precambrian sedimentary rocks and continental evolution

NASA Technical Reports Server (NTRS)

Jakes, P.; Taylor, S. R.

1974-01-01

It is proposed that the europium excess in Precambrian sedimentary rocks, relative to those of younger age, is derived from volcanic rocks of ancient island arcs, which were the source materials for the sediments. Precambrian sedimentary rocks and present-day volcanic rocks of island arcs have similar REE patterns, total REE abundances, and excess Eu, relative to the North American shale composite. The present upper crustal REE pattern, as exemplified by that of sediments, is depleted in Eu, relative to chondrites. This depletion is considered to be a consequence of development of a granodioritic upper crust by partial melting in the lower crust, which selectively retains europium.

Transmutation Fuel Fabrication-Fiscal Year 2016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fielding, Randall Sidney; Grover, Blair Kenneth

ABSTRACT Nearly all of the metallic fuel that has been irradiated and characterized by the Advanced Fuel Campaign, and its earlier predecessors, has been arc cast. Arc casting is a very flexible method of casting lab scale quantities of materials. Although the method offers flexibility, it is an operator dependent process. Small changes in parameter space or alloy composition may affect how the material is cast. This report provides a historical insight in how the casting process has been modified over the history of the advanced fuels campaign as well as the physical parameters of the fuels cast in fiscalmore » year 2016.« less

Erosion behavior of composite Al-Cr cathodes in cathodic arc plasmas in inert and reactive atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franz, Robert, E-mail: robert.franz@unileoben.ac.at; Mendez Martin, Francisca; Hawranek, Gerhard

2016-03-15

Al{sub x}Cr{sub 1−x} composite cathodes with Al contents of x = 0.75, 0.5, and 0.25 were exposed to cathodic arc plasmas in Ar, N{sub 2}, and O{sub 2} atmospheres and their erosion behavior was studied. Cross-sectional analysis of the elemental distribution of the near-surface zone in the cathodes by scanning electron microscopy revealed the formation of a modified layer for all cathodes and atmospheres. Due to intermixing of Al and Cr in the heat-affected zone, intermetallic Al-Cr phases formed as evidenced by x-ray diffraction analysis. Cathode poisoning effects in the reactive N{sub 2} and O{sub 2} atmospheres were nonuniform as a resultmore » of the applied magnetic field configuration. With the exception of oxide islands on Al-rich cathodes, reactive layers were absent in the circular erosion zone, while nitrides and oxides formed in the less eroded center region of the cathodes.« less

Diverse Electron-Induced Optical Emissions from Space Observatory Materials at Low Temperatures

NASA Technical Reports Server (NTRS)

Dennison, J.R.; Jensen, Amberly Evans; Wilson, Gregory; Dekany, Justin; Bowers, Charles W.; Meloy, Robert

2013-01-01

Electron irradiation experiments have investigated the diverse electron-induced optical and electrical signatures observed in ground-based tests of various space observatory materials at low temperature. Three types of light emission were observed: (i); long-duration cathodoluminescence which persisted as long as the electron beam was on (ii) short-duration (<1 s) arcing, resulting from electrostatic discharge; and (iii) intermediate-duration (100 s) glow-termed "flares". We discuss how the electron currents and arcing-as well as light emission absolute intensity and frequency-depend on electron beam energy, power, and flux and the temperature and thickness of different bulk (polyimides, epoxy resins, and silica glasses) and composite dielectric materials (disordered SiO2 thin films, carbon- and fiberglass-epoxy composites, and macroscopically-conductive carbon-loaded polyimides). We conclude that electron-induced optical emissions resulting from interactions between observatory materials and the space environment electron flux can, in specific circumstances, make significant contributions to the stray light background that could possibly adversely affect the performance of space-based observatories.

Effects of copper vapour on thermophysical properties of CO2-N2 plasma

NASA Astrophysics Data System (ADS)

Zhong, Linlin; Wang, Xiaohua; Rong, Mingzhe; Cressault, Yann

2016-10-01

CO2-N2 mixtures are often used as arc quenching medium (to replace SF6) in circuit breakers and shielding gas in arc welding. In such applications, copper vapour resulting from electrode surfaces can modify characteristics of plasmas. This paper therefore presents an investigation of the effects of copper on thermophysical properties of CO2-N2 plasma. The equilibrium compositions, thermodynamic properties (including mass density, specific enthalpy, and specific heat), transport coefficients (including electrical conductivity, viscosity, and thermal conductivity), and four kinds of combined diffusion coefficients due to composition gradients, applied electric fields, temperature gradients, and pressure gradients respectively, were calculated and discussed for CO2-N2 (mixing ratio 7:3) plasma contaminated by different proportions of copper vapour. The significant influences of copper were observed on all the properties of CO2-N2-Cu mixtures. The better ionization ability and larger molar mass of copper and larger collision integrals related to copper, should be responsible for such influences.

Ablative performance of uncoated silicone-modified and shuttle baseline reinforced carbon composites

NASA Technical Reports Server (NTRS)

Dicus, D. L.; Hopko, R. N.; Brown, R. D.

1976-01-01

The relative ablative performance of uncoated silicone-modified reinforced carbon composite (RCC) and uncoated shuttle baseline RCC substrates was investigated. The test specimens were 13 plies (5.3 to 5.8 millimeters) thick and had a 25-millimeter-diameter test face. Prior to arc tunnel testing, all specimens were subjected to a heat treatment simulating the RCC coating process. During arc tunnel testing, the specimens were exposed to cold wall heating rates of 178 to 529 kilowatts/sq m and stagnation pressures ranging from 0.015 to 0.046 atmosphere at Mach 4.6 in air, with and without preheating in nitrogen. The results show that the ablative performance of uncoated silicone-modified RCC substrates is significantly superior to that of uncoated shuttle baseline RCC substrates over the range of heating conditions used. These results indicate that the silicone-modified RCC substrate would yield a substantially greater safety margin in the event of complete coating loss on the shuttle orbiter.

Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc

USGS Publications Warehouse

Hedge, C.E.; Lewis, J.F.

1971-01-01

Si87/Sr86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc-Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si87/Sr86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr87/Sr86 values from each center are the same within analytical uncertainty (??0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source - in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization. ?? 1971 Springer-Verlag.

Iron isotopic systematics of oceanic basalts

NASA Astrophysics Data System (ADS)

Teng, Fang-Zhen; Dauphas, Nicolas; Huang, Shichun; Marty, Bernard

2013-04-01

The iron isotopic compositions of 93 well-characterized basalts from geochemically and geologically diverse mid-ocean ridge segments, oceanic islands and back arc basins were measured. Forty-three MORBs have homogeneous Fe isotopic composition, with δ56Fe ranging from +0.07‰ to +0.14‰ and an average of +0.105 ± 0.006‰ (2SD/√n, n = 43, MSWD = 1.9). Three back arc basin basalts have similar δ56Fe to MORBs. By contrast, OIBs are slightly heterogeneous with δ56Fe ranging from +0.05‰ to +0.14‰ in samples from Koolau and Loihi, Hawaii, and from +0.09‰ to +0.18‰ in samples from the Society Islands and Cook-Austral chain, French Polynesia. Overall, oceanic basalts are isotopically heavier than mantle peridotite and pyroxenite xenoliths, reflecting Fe isotope fractionation during partial melting of the mantle. Iron isotopic variations in OIBs mainly reflect Fe isotope fractionation during fractional crystallization of olivine and pyroxene, enhanced by source heterogeneity in Koolau samples.

Permian arc evolution associated with Panthalassa subduction along the eastern margin of the South China block, based on sandstone provenance and U-Pb detrital zircon ages of the Kurosegawa belt, Southwest Japan

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Hirano, Miho; Kurihara, Toshiyuki; Takahashi, Toshiro; Ueda, Hayato

2018-01-01

We have studied the petrography, geochemistry, and detrital zircon U-Pb ages of sandstones from shallow-marine forearc sediments, accretionary complexes (ACs), and metamorphosed accretionary complexes (Meta-ACs) within the Kurosegawa belt of Southwest Japan. Those rocks formed in a forearc region of a Permian island arc associated with subduction of the Panthalassa oceanic crust along the eastern margin of the South China block (Yangtze block). The provenance of the shallow-marine sediments was dominated by basaltic to andesitic volcanic rocks and minor granitic rocks during the late Middle to Late Permian. The ACs were derived from felsic to andesitic volcanic rocks during the Late Permian. The provenance of Meta-ACs was dominated by andesitic volcanic rocks in the Middle Permian. The provenance, source rock compositions, and zircon age distribution for the forearc sediments, ACs and Meta-ACs have allowed us to reconstruct the geological history of the Permian arc system of the Kurosegawa belt. During the Middle Permian, the ACs were accreted along the eastern margin of the South China block. The Middle Permian arc was an immature oceanic island arc consisting of andesitic volcanic rocks. During the Late Permian, the ACs formed in a mature arc, producing voluminous felsic to andesitic volcanic rocks. A forearc basin developed during the late Middle to Late Permian. Subsequently, the Middle Permian ACs and part of the Late Permian AC underwent low-grade metamorphism in the Late to Early Jurassic, presenting the Meta-ACs.

Arc-continent collision and the formation of continental crust: A new geochemical and isotopic record from the Ordovician Tyrone Igneous Complex, Ireland

USGS Publications Warehouse

Draut, Amy E.; Clift, Peter D.; Amato, Jeffrey M.; Blusztajn, Jerzy; Schouten, Hans

2009-01-01

Collisions between oceanic island-arc terranes and passive continental margins are thought to have been important in the formation of continental crust throughout much of Earth's history. Magmatic evolution during this stage of the plate-tectonic cycle is evident in several areas of the Ordovician Grampian-Taconic orogen, as we demonstrate in the first detailed geochemical study of the Tyrone Igneous Complex, Ireland. New U-Pb zircon dating yields ages of 493 2 Ma from a primitive mafic intrusion, indicating intra-oceanic subduction in Tremadoc time, and 475 10 Ma from a light rare earth element (LREE)-enriched tonalite intrusion that incorporated Laurentian continental material by early Arenig time (Early Ordovician, Stage 2) during arc-continent collision. Notably, LREE enrichment in volcanism and silicic intrusions of the Tyrone Igneous Complex exceeds that of average Dalradian (Laurentian) continental material that would have been thrust under the colliding forearc and potentially recycled into arc magmatism. This implies that crystal fractionation, in addition to magmatic mixing and assimilation, was important to the formation of new crust in the Grampian-Taconic orogeny. Because similar super-enrichment of orogenic melts occurred elsewhere in the Caledonides in the British Isles and Newfoundland, the addition of new, highly enriched melt to this accreted arc terrane was apparently widespread spatially and temporally. Such super-enrichment of magmatism, especially if accompanied by loss of corresponding lower crustal residues, supports the theory that arc-continent collision plays an important role in altering bulk crustal composition toward typical values for ancient continental crust. ?? 2009 Geological Society of London.

Arcjet Flow Properties Determined from Laser-Induced Fluorescence of Atomic Species

NASA Technical Reports Server (NTRS)

Fletcher, Douglas G.

1997-01-01

Flow property measurements that were recently acquired in the Ames Research Center Aerodynamic Heating Facility (AHF) arc jet using two-photon Laser-Induced Fluorescence (LIF) of atomic nitrogen and oxygen are reported. The measured properties, which include velocity, translational temperature, and species concentration, cover a wide range of facility operation for the 30 cm nozzle. During the tests, the arc jet pressure and input stream composition were maintained at fixed values and the arc current was varied to vary the flow enthalpy. As part of this ongoing effort, a measurement of the two-photon absorption coefficient for the 3p4D<-2p4S transition of atomic nitrogen was performed, and the measured value is used to convert the relative concentration measurements to absolute values. A flow reactor is used to provide a known temperature line shape profile to deconvolve the laser line width contribution to the translational temperature measurements. Results from the current experiments are compared with previous results obtained using NO-Beta line profiles at room temperature and the problem of multimode laser oscillation and its impact on the two-photon excitation line shape are discussed. One figure is attached, and this figure shows relative N atom concentration measurements as a function of the arc power. Other measurements have already been acquired and analyzed. This poster represents an application of laser-spectroscopic measurements in an important test facility. The arc jet flow facilities are heavily used in thermal protection material development and evaluation. All hypersonic flight and planetary atmospheric entry vehicles will use materials tested in these arc jet facilities.

Fluorine partitioning between hydrous minerals and aqueous fluid at 1 GPa and 770-947 °C: A new constraint on slab flux

NASA Astrophysics Data System (ADS)

Wu, Jia; Koga, Kenneth T.

2013-10-01

Mechanisms of volatile element transfer from subducting slab to the melting region beneath arc volcanoes are probably the least understood process in arc magma genesis. Fluorine, which suffers minimal degassing in arc primitive melt inclusions, is highly enriched in arc lavas and retains information about the role of volatiles during magma genesis at depth. Experimentally determined solubility of F in aqueous fluids, and partition coefficients of F between fluid and minerals provide first order geochemical constraints about the character of the volatile-transporting agent. We present experimentally determined F solubility in fluid in equilibrium with hornblende and a humite group mineral at 1 GPa, from 770 to 947 °C, and partition coefficients between these phases. The composition of the fluid is determined by mass-balance calculations and consistency is verified by high pressure liquid chromatography measurements of the quenched fluids. The partition coefficient DFFlu /Hb can be represented by a single value of 0.13 ± 0.03. The average F concentration in the fluid is 2700 ppm for F-rich experiments, constraining the maximum amount of F carried by fluid in the presence of amphibole. Where the initial natural F concentrations in the slab are much lower than in our experiments, the increase of F concentration in the sub-arc mantle by a fluid in equilibrium with hornblende is expected to be no more than a few ppm. Thus significant arc lava F enrichments cannot result from aqueous fluids deriving from an amphibole-bearing subducting slab.

Assessing contamination in Great Lakes sediments using benthic invertebrate communities and the sediment quality triad approach

USGS Publications Warehouse

Canfield, Timothy J.; Dwyer, F. James; Fairchild, James F.; Haverland, Pamela S.; Ingersoll, Christopher G.; Kemble, Nile E.; Mount, David R.; La Point, Thomas W.; Burton, G. Allen; Swift, M. C.

1996-01-01

Sediments in many Great Lakes harbors and tributary rivers are contaminated. As part of the USEPA's Assessment and Remediation of Contaminated Sediment (ARCS) program, a number of studies were conducted to determine the nature and extent of sediment contamination in Great Lakes Areas of Concern (AOC). This paper describes the composition of benthic invertebrate communities in contaminated sediments and is one in a series of papers describing studies conducted to evaluate sediment toxicity from three AOC's (Buffalo River, NY; Indiana Harbor, IN; Saginaw River, MI), as part of the ARCS Program. Oligochaeta (worms) and Chironomidae (midge) comprised over 90% of the benthic invertebrate numbers in samples collected from depositional areas. Worms and midge consisted of taxa identified as primarily contaminant tolerant organisms. Structural deformities of mouthparts in midge larvae were pronounced in many of the samples. Good concurrence was evident between measures of laboratory toxicity, sediment contaminant concentration, and benthic invertebrate community composition in extremely contaminated samples. However, in moderately contaminated samples, less concordance was observed between the benthos community composition and either laboratory toxicity test results or sediment contaminant concentration. Laboratory sediment toxicity tests may better identify chemical contamination in sediments than many commonly used measures of benthic invertebrate community composition. Benthic measures may also reflect other factors such as habitat alteration. Evaluation of non-contaminant factors are needed to better interpret the response of benthic invertebrates to sediment contamination.

The Chinese North Tianshan Orogen was a rear-arc (or back-arc) environment in the Late Carboniferous: constraint from the volcanic rocks in the Bogda Mountains

NASA Astrophysics Data System (ADS)

Xie, W.

2017-12-01

The Tianshan Orogen is a key area for understanding the Paleozoic tectonics and long-lasting evolution of the Central Asian Orogenic Belt (CAOB). However, considerable debate persists as to its tectonic setting during the late Paleozoic, with active subduction system and intraplate large igneous provinces as two dominant schools (Ma et al., 1997; Gu et al., 2000; Xiao et al., 2004; Han et al., 2010; Shu et al., 2011; Chen et al., 2011; Xia et al., 2012). With aims of providing constraints on this issue, petrology, mineralogy, geochronological and geochemistry for the Late Carboniferous volcanics from the Bogda Mountains have been carried out. We find two suits of high-Al basalt (HAB, 315-319 Ma) and a suit of submarine pillow basalt ( 311 Ma) in this region. Both of the two basalts belong to the tholeiitic magma (the tholeiitic index THI > 1) and contain low pre-eruptive magmatic H2O (< 2%). High Al content of the Bogda HABs is due to high crystallization pressure rather than water content. It is different from the pillow lavas that are formed in a shallower and more stable magma chamber (Xie et al., 2016a, b). The felsic volcanism coexisted with the Bogda HABs is I-type intermediate ignimbrites and rhyolite lavas. The rhyolites are formed by partial melting of a hydrated and juvenile arc crust and the ignimbrites are affected by magma mingling and feldspar fractionation (Xie et al., 2016c). The two basalts both have the MORB-like Sr-Nd-Hf-Pb isotopes and arc-like trace element compositions. We discuss that they may have been generated from a dry and depleted mantle source metasomatized by <1% sediment-derived melts. Compared with basalts from the Permian large igneous provinces (e.g., the Siberia, Emeishan and Tarim), they are different from the mantle plume-related basalts in many aspects. Meanwhile, we also compare the Bogda basalts with the Izu-Bonin fore-arc and rear-arc/back-arc basalts. Our samples show great resemblance to the Izu-Bonin rear-arc basalt (including the arc-like back-arc basalt). These lines of evidence indicate that these basalts and coexisted felsic volcanics were likely formed in a rear-arc or back-arc environment, probably related to southward subduction of the Paleo-Tianshan Ocean (Xie et al., 2016a, b, c).

Crustal Accretion at Subduction Initiation Along Izu-Bonin-Mariana Arc and the Link to SSZ Ophiolites

NASA Astrophysics Data System (ADS)

Ishizuka, O.; Tani, K.; Reagan, M. K.; Kanayama, K.; Umino, S.; Harigane, Y.; Sakamoto, I.

2014-12-01

The Izu-Bonin-Mariana (IBM) forearc preserves the earliest arc magmatic history from subduction initiation to the establishment of the arc. Recent investigations have established a bottom to top igneous stratigraphy of: 1) mantle peridotite, 2) gabbroic rocks, 3) a sheeted dyke complex, 4) basaltic pillow lavas (forearc basalts: FAB), 5) boninites and magnesian andesites, 6) tholeiites and calcalkaline arc lavas. This stratigraphy has many similarities to supra-subduction zone (SSZ) ophiolites. One of the most important common characteristics between the SSZ ophiolites and the forearc crust is the occurrence of MORB-like basaltic lavas underlying or accompanying boninites and early arc volcanic suites. A key observation from the IBM forearc is that FAB differs from nearby back-arc lavas in chemical characteristics, including a depletion in moderately incompatible elements. This indicates that FAB is not a pre-existing oceanic basement of the arc, but the first magmatic product after subduction initiation. Sheeted dikes of FAB composition imply that this magmatism was associated with seafloor spreading, possibly triggered by onset of slab sinking. Recognition of lavas with transitional geochemical characteristics between the FAB and the boninites strongly implies genetic linkage between these two magma types. The close similarity of the igneous stratigraphy of SSZ ophiolites to the IBM forearc section strongly implies a common magmatic evolutionary path, i.e., decompressional melting of a depleted MORB-type mantle is followed by melting of an even more depleted mantle with the addition of slab-derived fluid/melt to produce boninite magma. Similarity of magmatic process between IBM forearc and Tethyan ophiolites appears to be reflected on common characteristics of upper mantle section. Peridotite from both sections show more depleted characteristics compared to upper mantle rocks from mid-ocean ridges. Age determinations reveal that first magmatism at the IBM arc occurred at c. 52 Ma, and transition from forearc basalt to normal arc magmatism took 7-8 million years. Combined with the age information from SSZ-ophiolites, significant constraints on time scale of subduction initiation and associated crustal accretion might be obtained.

Crustal inheritance and arc magmatism: Magnetotelluric constraints from the Washington Cascades on top-down control

NASA Astrophysics Data System (ADS)

Bedrosian, P.; Peacock, J.; Bowles-martinez, E.; Schultz, A.; Hill, G.

2017-12-01

Worldwide, arc volcanism occurs along relatively narrow magmatic arcs, the locations of which are considered to mark the onset of dehydration reactions within the subducting slab. This `bottom-up' approach, in which the location of arc volcanism reflects where fluids and melt are generated, explains first-order differences in trench-to-arc distance and is consistent with known variations in the thermal structure and geometry of subducting slabs. At a finer scale, arc segmentation, magmatic gaps, and anomalous forearc and backarc magmatism are also frequently interpreted in terms of variations in slab geometry, composition, or thermal structure.The role of inherited crustal structure in controlling faulting and deformation is well documented; less well examined is the role of crustal structure in controlling magmatism. While the source distribution of melt and subduction fluids is critical to determining the location of arc magmatism, we argue that crustal structure provides `top-down' control on patterns or seismicity and deformation as well as the channeling and ascent of arc magmas. We present evidence within the Washington Cascades based upon correlation between a new three-dimensional resistivity model, potential-field data, seismicity, and Quaternary volcanism. We image a mid-Tertiary batholith, intruded within an Eocene crustal suture zone, and extending throughout much of the crustal column. This and neighboring plutons are interpreted to channel crustal fluids and melt along their margins within steeply dipping zones of marine to transitional metasedimentary rock. Mount St. Helens is interpreted to be fed by fluids and melt generated further east at greater slab depths, migrating laterally (underplating?) beneath the Spirit Lake batholith, and ascending through metasedimentary rocks within the brittle crust. At a regional scale, we argue that this concealed suture zone controls present-day deformation and seismicity as well as the distribution of forearc magmatism. More generally, our results highlight the control that inherited crustal structure has on both the location and style of arc magmatism. We also address divergent interpretations of the Southern Washington Cascades Conductor, which we show results from limited data density and modeling assumptions in previous studies.

New zircon U-Pb LA-ICP-MS ages and Hf isotope data from the Central Pontides (Turkey): Geological and geodynamic constraints

NASA Astrophysics Data System (ADS)

Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan

2018-05-01

The Central Pontides in northern Anatolia is located on the accretionary complex formed by the closure of Neotethyan Intra-Pontide Ocean between the southern Eurasian margin (Istanbul-Zonguldak Terrane) and the Cimmerian Sakarya Composite Terrane. Among other components of the oceanic lithosphere, it comprises not yet well-dated felsic igneous rocks formed in arc-basin as well as continent margin settings. In-situ U-Pb age results for zircons from the arc-basin system (öangaldağ Metamorphic Complex) and the continental arc (Devrekani Metadiorite and Granitoid) yield ages of 176 ± 6 Ma, 163 ± 9 Ma and 165 ± 3 Ma, respectively. Corresponding in-situ average (initial) 176Hf/177Hf initial ratios are 0.28261 ± 0.00003, 0.28267 ± 0.00002 and 0.28290 ± 0.00004 for these units and indicative of a subduction-modified mantle source. The new U-Pb ages and Hf isotope data from these oceanic and continental arc units together with regional geological constraints support the presence of a multiple subduction system within the Intra-Pontide Ocean during the Middle Jurassic.

Integration of decoy domains derived from protein targets of pathogen effectors into plant immune receptors is widespread.

PubMed

Kroj, Thomas; Chanclud, Emilie; Michel-Romiti, Corinne; Grand, Xavier; Morel, Jean-Benoit

2016-04-01

Plant immune receptors of the class of nucleotide-binding and leucine-rich repeat domain (NLR) proteins can contain additional domains besides canonical NB-ARC (nucleotide-binding adaptor shared by APAF-1, R proteins, and CED-4 (NB-ARC)) and leucine-rich repeat (LRR) domains. Recent research suggests that these additional domains act as integrated decoys recognizing effectors from pathogens. Proteins homologous to integrated decoys are suspected to be effector targets and involved in disease or resistance. Here, we scrutinized 31 entire plant genomes to identify putative integrated decoy domains in NLR proteins using the Interpro search. The involvement of the Zinc Finger-BED type (ZBED) protein containing a putative decoy domain, called BED, in rice (Oryza sativa) resistance was investigated by evaluating susceptibility to the blast fungus Magnaporthe oryzae in rice over-expression and knock-out mutants. This analysis showed that all plants tested had integrated various atypical protein domains into their NLR proteins (on average 3.5% of all NLR proteins). We also demonstrated that modifying the expression of the ZBED gene modified disease susceptibility. This study suggests that integration of decoy domains in NLR immune receptors is widespread and frequent in plants. The integrated decoy model is therefore a powerful concept to identify new proteins involved in disease resistance. Further in-depth examination of additional domains in NLR proteins promises to unravel many new proteins of the plant immune system. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

Arc Crustal Structure around Mount Rainier Constrained by Receiver Functions and Seismic Noise

NASA Astrophysics Data System (ADS)

Obrebski, M. J.; Abers, G. A.; Foster, A. E.

2013-12-01

Volcanic arcs along subduction zones are thought to be loci for continental growth. Nevertheless, the amount of material transferred from the mantle to crust and the associated magmatic plumbing are poorly understood. While partial melting of mantle peridotite produces basaltic melt, the average composition of continental crust is andesitic. Several models of magma production, migration and differentiation have been proposed to explain the average crust composition in volcanic arcs. The formation of mafic cumulate and restite during fractional crystallization and partial melting has potential to alter the structure of the crust-mantle interface (Moho). The computed composition and distribution of crust and mantle rocks based on these different models convert into distinctive vertical velocity profiles, which seismic imaging methods can unravel . With a view to put more constraints on magmatic processes in volcanic arc, we analyze the shear wave velocity (Vs) distribution in the crust and uppermost mantle below Mount Rainier, WA, in the Cascadia arc. We resolve the depth of the main velocity contrasts based on converted phases, for which detection in the P coda is facilitated by source normalization or receiver function (RF) analysis. To alleviate the trade-off between depth and velocity intrinsic to RF analysis, we jointly invert RF with frequency-dependent surface wave velocities. We analyze earthquake surface waves to constrain long period dispersion curves (20-100 s). For shorter period (5-20s), we use seismic noise cross-correlograms and Aki's spectral formulation, which allows longer periods for given path. We use a transdimensional Bayesian scheme to explore the model space (shear velocity in each layer, number of interfaces and their respective depths). This approach tends to minimize the number of layers required to fit the observations given their noise level. We apply this tool to a set of broad-band stations from permanent and EarthScope temporary stations, all within 35 km of Mt Rainier. The receiver functions significantly differ from one station to another, indicating short wavelength lateral contrast in the lithospheric structure. Below arc stations offset from Mount Rainier, preliminary models show a rather clear Moho transition around 40km, separating lower crust with 3.6-3.9 km/s shear velocity, from a ~ 20 km thick mantle lid with Vs ~ 4.2 km/s. In contrast, at station PANH located 9 km east of Mount Rainier, the exact location of the Moho is not clear. Shear velocity ranges from 3.3 to 3.9 km/s from the surface down to 55 km depth, with the exception of a fast layer imaged between 25 and 32 km depth with Vs ~ 4.2 km/s. It seems likely that partial melt in the mantle, combined with high-velocity underplated or differentiated lower crust, are acting in various ways to create a complicated structure around the Moho.

Atypical centromeres in plants—what they can tell us

PubMed Central

Cuacos, Maria; H. Franklin, F. Chris; Heckmann, Stefan

2015-01-01

The centromere, visible as the primary constriction of condensed metaphase chromosomes, is a defined chromosomal locus essential for genome stability. It mediates transient assembly of a multi-protein complex, the kinetochore, which enables interaction with spindle fibers and thus faithful segregation of the genetic information during nuclear divisions. Centromeric DNA varies in extent and sequence composition among organisms, but a common feature of almost all active eukaryotic centromeres is the presence of the centromeric histone H3 variant cenH3 (a.k.a. CENP-A). These typical centromere features apply to most studied species. However, a number of species display “atypical” centromeres, such as holocentromeres (centromere extension along almost the entire chromatid length) or neocentromeres (ectopic centromere activity). In this review, we provide an overview of different atypical centromere types found in plants including holocentromeres, de novo formed centromeres and terminal neocentromeres as well as di-, tri- and metapolycentromeres (more than one centromere per chromosomes). We discuss their specific and common features and compare them to centromere types found in other eukaryotic species. We also highlight new insights into centromere biology gained in plants with atypical centromeres such as distinct mechanisms to define a holocentromere, specific adaptations in species with holocentromeres during meiosis or various scenarios leading to neocentromere formation. PMID:26579160

Archean greenstone belt magmatism and the continental growth-mantle evolution connection: constraints from Th-U-Nb-LREE systematics of the 2.7 Ga Wawa subprovince, Superior Province, Canada

NASA Astrophysics Data System (ADS)

Polat, Ali; Kerrich, Robert

2000-01-01

An extensive database, including Th-;U-Nb-REE systematics, for diverse magmatic and sedimentary lithologies of 2.7 Ga Wawa greenstone belts provide new constraints on the mechanism of crustal growth in the southern Superior Province, and controls on its composition. The greenstone belts are characterized by collages of oceanic plateaus, oceanic island arcs, and trench turbidites; these lithotectonic fragments were tectonically assembled in a large subduction-accretion complex. Following juxtaposition, these diverse lithologies were collectively intruded by syn-kinematic TTG (tonalite-trondhjemite-granodiorite) plutons and ultramafic to felsic dykes and sills, with subduction zone geochemical signatures. Intra-oceanic basalts are characterized by near-flat REE patterns, and Nb/U and Nb/Th ratios generally greater than primitive mantle values, consistent with positive ɛNd values. They are associated with komatiites, the association being interpreted as an ocean plateau sequence erupted from a mantle plume. Bimodal arc volcanic sequences, trench turbidites, and contemporaneous TTG suites are characterized by fractionated REE, with Nb/U and Nb/Th ratios less than primitive mantle values. Mixing hyperbolae between oceanic plateau and magmatic arc sequences pass through the estimated composition of bulk continental crust, suggesting that crustal growth in the late Archean was by tectonic, sedimentary, and chemical mixing of oceanic plateau and arc sequences at convergent plate boundaries. Mixing calculations suggest that oceanic plateau and subduction zone components in the Wawa continental crust are represented by 6-12% and 88-94%, respectively. High Nb/U and Nb/Th ratios of plateau tholeiitic basalts are interpreted as a complementary reservoir to arc magmatism (low Nb/U and Nb/Th), hundreds of millions of years prior to recycling of oceanic lithosphere through a subduction zone (high Nb/U, Nb/Th), and its incorporation into a mantle plume from which 2.7 Ga plateau tholeiites erupted. The variably high Nb/U ratios of the plateau basalts are consistent with early extraction of large quantities of the protoliths (magmatic precursor) of continental crust from the southern Superior Province asthenospheric mantle.

Compositional diversity of Late Cenozoic basalts in a transect across the southern Washington Cascades: Implications for subduction zone magmatism

NASA Astrophysics Data System (ADS)

Leeman, William P.; Smith, Diane R.; Hildreth, Wes; Palacz, Zen; Rogers, Nick

1990-11-01

Major volcanoes of the Southern Washington Cascades (SWC) include the large Quaternary stratovolcanoes of Mount St. Helens (MSH) and Mount Adams (MA) and the Indian Heaven (IH) and Simcoe Mountain (SIM) volcanic fields. There are significant differences among these volcanic centers in terms of their composition and evolutionary history. The stratovolcanoes consist largely of andesitic to dacitic lavas and pyroclastics with minor basalt flows. IH consists dominantly of basaltic with minor andesite lavas, all erupted from monogenetic rift and cinder cone vents. SIM has a poorly exposed andesite to rhyolite core but mainly consists of basaltic lavas erupted from numerous widely dispersed vents; it has the morphology of a shield volcano. Distribution of mafic lavas across the SWC is related to north-northwest trending faults and fissure zones that indicate a significant component of east-west extension within the area. There is overlap in eruptive history for the areas studied, but it appears that peak activity was progressively older (MSH (<40 Ka), IH (mostly <0.5 Ma), MA (<0.5 Ma), SIM (1-4 Ma)) and more alkalic toward the east. A variety of compositionally distinct mafic magma types has been identified in the SWC, including low large ion lithophile element (LILE) tholeiitic basalts, moderate LILE calcalkalic basalts, basalts transitional between these two, LILE-enriched mildly alkalic basalts, and basaltic andesites. Compositional diversity among basaltic lavas, both within individual centers as well as across the arc, is an important characteristic of the SWC traverse. The fact that the basaltic magmas either show no correlation between isotopic and trace element components or show trends quite distinct from those of the associated evolved lavas, suggests that their compositional variability is attributable to subcrustal processes. Both the primitive nature of the erupted basalts and the fact that they are relatively common in the SWC sector also imply that such magmas had little residence time in the crust. A majority of the SWC basaltic samples studies are indistinguishable from oceanic island basalts (OIB) in terms of trace element and isotopic compositions, and more importantly, most do not display the typical high field strength element (HFSE) depletion seen in subduction-related magmas in volcanic arcs elsewhere. LILE enrichment and HRSE depletion characteristics of most arc magmas are generally attributed to the role of fluids released by dehydration of subducted oceanic lithosphere and to the effects of sediment subduction. Because most SWC basalts lack these compositional features, we conclude that subducted fluids and sediments do not play an essential role in producing these magmas. Rather, we infer that they formed by variable degree melting of a mixed mantle source consisting mainly of heterogeneously distributed OIB and mid-ocean ridge basalt source domains. Relatively minor occurrences of HFSE-depleted arclike basalts may reflect the presence of a small proportion of slab-metasomatized subarc mantle. The juxtaposition of such different mantle domains within the lithospheric mantle is viewed as a consequence of (1) tectonic mixing associated with accretion of oceanic and island arc terranes along the Pacific margin of North America prior to Neogene time, and possibly (2) a seaward jump in the locus of subduction at about 40 Ma. The Cascades arc is unusual in that the subducting oceanic plate is very young and hot. We suggest that slab dehydration outboard of the volcanic front resulted in a diminished role of aqueous fluids in generating or subsequently modifying SWC magmas compared to the situation at most convergent margins. Furthermore, with low fluid flux conditions, basalt generation is presumably triggered by other processes that increase the temperature of the mantle wedge (e.g., convective mantle flow, shear heating, etc.).

GM2-ganglioside metabolism in hexosaminidase A deficiency states: determination in situ using labeled GM2 added to fibroblast cultures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raghavan, S.S.; Krusell, A.; Krusell, J.

1985-11-01

To clarify the relationship between hexosaminidase A (HEX A) activity and GM2-ganglioside hydrolysis in atypical clinical situations of HEX A deficiency, we have developed a simple method to assess GM2-ganglioside metabolism in cultured fibroblasts utilizing GM2 labeled with tritium in the sphingosine portion of the molecule. The radioactive lipid is added to the media of cultured skin fibroblasts, and after 10 days the cells are thoroughly washed, then harvested, and their lipid composition analyzed by HPLC. The degree of hydrolysis of the ingested GM2 is determined by comparing the amount of radioactive counts recovered in undegraded substrate with total cellularmore » radioactivity. A deficiency in GM2-ganglioside hydrolysis was demonstrated in seven HEX A-deficient adults with neurological signs and in two healthy-appearing adolescents with older affected siblings. In each case, an analysis of endogenous monosialoganglioside composition revealed an increase in GM2-ganglioside, confirming the presence of a block in the metabolism of GM2. No defect in GM2-catabolism was found in four other healthy individuals with HEX A deficiency. This method of assay is especially helpful in the evaluation of atypical cases of HEX A deficiency for the definitive diagnosis of GM2-gangliosidosis.« less

Long-term changes in explosive and effusive behaviour at andesitic arc volcanoes: Chronostratigraphy of the Centre Hills Volcano, Montserrat

NASA Astrophysics Data System (ADS)

Coussens, Maya; Cassidy, Michael; Watt, Sebastian F. L.; Jutzeler, Martin; Talling, Peter J.; Barfod, Dan; Gernon, Thomas M.; Taylor, Rex; Hatter, Stuart J.; Palmer, Martin R.; Montserrat Volcano Observatory

2017-03-01

Volcanism on Montserrat (Lesser Antilles arc) has migrated southwards since the formation of the Silver Hills 2.5 Ma, and has formed three successively active volcanic centres. The Centre Hills volcano was the focus of volcanism from 1-0.4 Ma, before activity commenced at the currently active Soufrière Hills volcano. The history of activity at these two volcanoes provides an opportunity to investigate the pattern of volcano behaviour on an andesitic arc island over the lifetime of individual volcanoes. Here, we describe the pyroclastic stratigraphy of subaerial exposures around central Montserrat; identifying 11 thick (> 1 m) pumiceous units derived from sustained explosive eruptions of Centre Hills from 0.8-0.4 Ma. Over 10 other, less well- exposed pumiceous units have also been identified. The pumice-rich units are interbedded with andesite lava breccias derived from effusive, dome-forming eruptions of Centre Hills. The stratigraphy indicates that large (up to magnitude 5) explosive eruptions occurred throughout the history of Centre Hills, alongside effusive activity. This behaviour at Centre Hills contrasts with Soufrière Hills, where deposits from sustained explosive eruptions are much less common and restricted to early stages of activity at the volcano, from 175-130 ka. Subsequent eruptions at Soufriere Hills have been dominated by andesitic effusive eruptions. The bulk composition, petrography and mineral chemistry of volcanic rocks from Centre Hills and Soufrière Hills are similar throughout the history of both volcanoes, except for occasional, transient departures to different magma compositions, which mark shifts in vent location or dominant eruption style. For example, the final recorded eruption of Centre Hills, before the initiation of activity at Soufrière Hills, was more silicic than any other identified eruption on Montserrat; and the basaltic South Soufrière Hills episode marked the transition to the current stage of predominantly effusive Soufrière Hills activity. The compositional stability observed throughout the history of Centre Hills and Soufrière Hills suggests that a predominance towards effusive or explosive eruption styles is not driven by major compositional shifts of magma, but may reflect local changes in long-term magma storage conditions that characterise individual episodes (on 105 year timescales) of volcanism on Montserrat. Supplementary Table 2: Complete XRF analyses for all analysed samples Supplementary Table 3: Complete ICP-MS analyses for all analysed samples. Supplementary Table 4: Plagioclase composition and precision data from SEM analysis Supplementary Table 5: Clinopyroxene composition and precision data from SEM analysis Supplementary Table 6: Orthopyroxene composition and precision data from SEM analysis Supplementary Table 7: Amphibole composition and precision data from SEM analysis Supplementary Table 8: Glass compositions from EMP analysis Supplementary Table 9: Standard Deviation of glass compositions from EMP analysis. Supplementary Table 10: Isotopic composition of argon from plagioclase crystals from select units. Data obtained using an ARGUS V multi-collector mass spectrometer.

Fluid-related inclusions in Alpine high-pressure peridotite reveal trace element recycling during subduction-zone dehydration of serpentinized mantle (Cima di Gagnone, Swiss Alps)

NASA Astrophysics Data System (ADS)

Scambelluri, Marco; Pettke, Thomas; Cannaò, Enrico

2015-11-01

Serpentinites release at sub-arc depths volatiles and several fluid-mobile trace elements found in arc magmas. Constraining element uptake in these rocks and defining the trace element composition of fluids released upon serpentinite dehydration can improve our understanding of mass transfer across subduction zones and to volcanic arcs. The eclogite-facies garnet metaperidotite and chlorite harzburgite bodies embedded in paragneiss of the subduction melange from Cima di Gagnone derive from serpentinized peridotite protoliths and are unique examples of ultramafic rocks that experienced subduction metasomatism and devolatilization. In these rocks, metamorphic olivine and garnet trap polyphase inclusions representing the fluid released during high-pressure breakdown of antigorite and chlorite. Combining major element mapping and laser-ablation ICP-MS bulk inclusion analysis, we characterize the mineral content of polyphase inclusions and quantify the fluid composition. Silicates, Cl-bearing phases, sulphides, carbonates, and oxides document post-entrapment mineral growth in the inclusions starting immediately after fluid entrapment. Compositional data reveal the presence of two different fluid types. The first (type A) records a fluid prominently enriched in fluid-mobile elements, with Cl, Cs, Pb, As, Sb concentrations up to 103 PM (primitive mantle), ∼102 PM Tl, Ba, while Rb, B, Sr, Li, U concentrations are of the order of 101 PM, and alkalis are ∼2 PM. The second fluid (type B) has considerably lower fluid-mobile element enrichments, but its enrichment patterns are comparable to type A fluid. Our data reveal multistage fluid uptake in these peridotite bodies, including selective element enrichment during seafloor alteration, followed by fluid-rock interaction along with subduction metamorphism in the plate interface melange. Here, infiltration of sediment-equilibrated fluid produced significant enrichment of the serpentinites in As, Sb, B, Pb, an enriched trace element pattern that was then transferred to the fluid released at greater depth upon serpentine dehydration (type A fluid). The type B fluid hosted by garnet may record the composition of the chlorite breakdown fluid released at even greater depth. The Gagnone study-case demonstrates that serpentinized peridotites acquire water and fluid-mobile elements during ocean floor hydration and through exchange with sediment-equilibrated fluids in the early subduction stages. Subsequent antigorite devolatilization at subarc depths delivers aqueous fluids to the mantle wedge that can be prominently enriched in sediment-derived components, potentially triggering arc magmatism without the need of concomitant dehydration/melting of metasediments or altered oceanic crust.

Gabbroic and Peridotitic Enclaves from the 2008 Kasatochi Eruption, Aleutian Islands, Alaska

NASA Astrophysics Data System (ADS)

Kentner, A.; Nadin, E. S.; Izbekov, P. E.; Nye, C. J.; Neill, O. K.

2012-12-01

Kasatochi volcano of the Andreanof Islands in the western Aleutian Arc violently erupted over a two day period from August 7-8, 2008. The eruption involved multiple explosive events generating pyroclastic flows, which included abundant mafic and ultramafic enclaves that have since weathered out and accumulated in talus along the coast. These and other mafic enclaves sampled by modern island arc lavas provide insight into subduction magmatism because they emerge from a section of the subduction system that is less likely than shallower zones to be modified by magmatic processes such as mixing, assimilation, or fractionation. We present new whole rock, clinopyroxene, amphibole, plagioclase, and melt compositions from Kasatochi enclaves of the 2008 eruption. The highly crystalline (~40 vol. % phenocryst content), medium-K basaltic andesite host rock contains ~52-55 wt. % SiO2 and 0.6-0.9 wt. % K2O, and is composed of plagioclase, ortho- and clinopyroxene, amphibole, and Ti-magnetite in a microlite-rich groundmass. Upon eruption, this magma sampled two distinct enclave populations: gabbro and peridotite. The gabbro has abundant amphibole (mostly magnesio-hastingsite) and plagioclase with minor clinopyroxene, olivine, and magnetite, while the peridotite is composed of olivine with minor amounts of clinopyroxene and orthopyroxene. There is little textural variation amongst the peridotitic samples collected, but the gabbroic samples vary from layered to massive and cover a range in grain size from fine-grained to pegmatitic. The layered gabbros display centimeter-scale bands of alternating plagioclase- and amphibole-rich layers, with a strong preferential alignment of the amphibole grains. The coarser-grained samples are very friable, with ~10% pore space; disaggregation of these upon host-magma ascent likely formed the amphibole and plagioclase xenocrysts in the andesitic host. Based on the textural and compositional differences, we divide the enclaves into four groups, (1) fine-grained gabbro, (2) medium- to coarse-grained gabbro, (3) pegmatitic gabbro with crystals up to 11 cm long, and (4) medium-grained peridotite. Bulk analyses of the gabbros using LA-ICP-MS show strong light rare-earth element depletion typical of primitive melts and arc volcanics such as the South Sandwich Arc. Our data suggest that the enclaves are primitive, with plagioclase compositions of An92-96 and crystallization temperatures of 900-1100 deg. C. Initial thermobarometric analyses from compositions of amphibole in the gabbroic samples suggest different temperature-pressure conditions for crystallization of fine-grained and very coarse-grained gabbros. We interpret these rocks as hydrous cumulate-melt mixtures with primitive geochemistry that is similar to Aleutian xenoliths of Kanaga Island.

The Sulfur Cycle at Subduction Zones

NASA Astrophysics Data System (ADS)

de Moor, M. J.; Fischer, T. P.; Sharp, Z. D.

2013-12-01

We present sulfur (S) isotope data for magmatic gases emitted along the Central American (CA) Arc (oxidizing conditions ΔQFM ~+ 1.5) and at the East African Rift (reduced conditions ΔQFM ~0). The results are interpreted through mass balance calculations to characterize the S cycle through subduction zones with implications for the redox conditions of arc magmas. Voluminous gas emissions from Masaya, an open vent basaltic volcano in Nicaragua, represent >20% of the SO2 flux from the CA arc [1]. Samples from the Masaya plume have S isotope compositions of + 4.8 × 0.4 ‰ [2]. Degassing fractionation modeling and assessment of differentiation processes in this oxidized volcano suggest that this value is close to that of the source composition. High T gas samples from other CA volcanoes (Momotombo, Cerro Negro, Poas, Turrialba) range from + 3 ‰ (Cerro Negro) to + 7 ‰ (Poas; [3]). The high δ34S values are attributed to recycling of subducted oxidized sulfur (sulfate ~ + 20 ‰) through the CA arc. The δ34S values of the more reduced samples from East African Rift volcanoes, Erta Ale - 0.5 × 0.6 ‰ [3] and Oldoinyo Lengai -0.7 ‰ to + 1.2 ‰) are far lower and are probably sourced directly from ambient mantle. The subduction of oxidized material at arcs presents a likely explanation for the oxidized nature of arc magmas relative to magmas from spreading centers. We observe no distinguishable change in melt fO2 with S degassing and attribute these differences to tectonic setting. Monte Carlo modeling suggests that subducted crust (sediments, altered oceanic crust, and serpentinized lithospheric mantle) delivers ~7.7 × 2.2 x 1010 mols of S with δ34S of -1.5 × 2.3‰ per year into the subduction zone. The total S output from the arc is estimated to be 3.4 × 1.1 x 1010 mols/yr with a δ34S value similar to that of Masaya gas (+5 × 0.5 ‰). Considering δ34S values for ambient upper mantle (0 ‰ [4]) and slab-derived fluids (+14 ‰ [5]) allows calculation of the flux of S released from slab into the mantle wedge. Based on these constraints, we calculate that 1.2 × 0.4 x 1010 mols of S/yr is released from the slab. If slab-derived S is in the S6+ oxidation state, this flux is enough to oxidize the entire mantle wedge to the Fe3+/Fe2+ observed in typical arc rocks in ~ 20 million years. [1] Hilton et al. (2002) Noble Gases in Geochemistry and Cosmochemistry. pp. 319-370 [2] de Moor et al., (in review) G-cubed [3] Rowe (1994) Chem. Geol., 236:303-322 [4] Sakai et al. (1984) J. Petrol., 52: 1307-1331 [5] Alt et al. (2012) Earth Plan. Sci. Lett., 327: 50-60

Welding of a corrosion-resistant composite material based on VT14 titanium alloy obtained using an electron beam emitted into the atmosphere

NASA Astrophysics Data System (ADS)

Golkovski, M. G.; Samoylenko, V. V.; Polyakov, I. A.; Lenivtseva, O. G.; Chakin, I. K.; Komarov, P. N.; Ruktuev, A. A.

2017-01-01

The study investigates the possibility of inert gas arc welding of a double layer composite material on a titanium base with an anti-corrosive layer obtained by fused deposition of a powder mix containing tantalum and niobium over a titanium base using an electron beam emitted into the atmosphere. Butt welding and fillet welding options were tested with two types of edge preparation. Welds were subjected to a metallographic examination including a structural study and an analysis of the chemical and phase composition of the welds. A conclusion was made regarding the possibility of using welding for manufacturing of items from the investigated composite material.

A possible recycling method for high grade steels EAFD in polymer composites.

PubMed

Niubó, M; Fernández, A I; Chimenos, J M; Haurie, L

2009-11-15

This work evaluates the feasibility of incorporating electric arc furnace dust (EAFD), as filler in a polymer matrix, to obtain a moldable heavyweight sheet, useful for acoustic insulation in automotive industry. For this purpose EAFD from a steel factory that manufactures high quality steels, was characterized and different formulations of composites were prepared. Physical and mechanical properties, as well as fire behaviour were tested and compared with a polymer composite compounded with common mineral fillers. Optimum formulation with 25% EAFD fulfils the RoHs Directive used by automotive industry to regulate heavy metals content. Leaching test was also performed on prepared composites to classify the material after use.

Partitioning of Large-ion Lithophile Elements Between Aqueous Fluids and Melts: Role of Saline Fluids in Sub-arc Mantle

NASA Astrophysics Data System (ADS)

Kawamoto, T.; Mibe, K.

2014-12-01

Chemical fractionation of slab-derived supercritical fluids can play an important role in elemental transfer from subducting slab to the mantle wedge and arc magmatism [1]. Recent findings of saline fluids from sub-arc mantle peridotite indicate that aqueous fluids in mantle wedge can contain 3.7 wt% NaCl in Ichinomageta, Northeast Japan arc [2] to 5.1 wt% NaCl in Pinatubo, Luzon arc [3]. It is, therefore, important to determine the effect of Cl on the trace element partitioning between aqueous fluids and melts. Synchrotron radiation X-ray fluorescence (XRF) analysis is conducted to know Rb, Sr, and Pb partitioning between aqueous fluids and melts [4]. There is a positive correlation between partition coefficients and pressure, as well as salinity. Two slab-derived components, melt and fluid components, are suggested to explain trace element characteristics of arc-basalts in the Mariana arc [5]. The fluid component is characterized by enrichment of alkali and alkali earth elements. Such features can be explained if the fluid component is a saline fluid, because alkali earth elements and Pb are much less mobile with Cl-free fluids than Cl-rich fluids [4]. We suggest that slab-derived components have compositional features consistent with a saline fluid and a melt, which can be formed through a separation of a slab-derived supercritical fluid [1]. Slab derived supercritical fluids contain Cl, and aqueous fluids inherit much of the Cl and some of the large-ion lithophile elements. [1] Kawamoto et al. 2012, Separation of supercritical slab-fluids to form aqueous fluid and melt components in subduction zone magmatism. PNAS, pnas.org/content/109/46/18695 [2] Kumagai et al. Evolution of carbon dioxide bearing saline fluids in the mantle wedge beneath the Northeast Japan arc, CMP [3] Kawamoto et al. 2013, Mantle wedge infiltrated with saline fluids from dehydration and decarbonation of subducting slab. PNAS, pnas.org/content/110/24/9663 [4] Kawamoto et al. 2014, Large ion lithophile elements delivered by saline fluids to the sub-arc mantle, EPS, earth-planets-space.com/content/66/1/61 [5] Pearce et al. 2005, Geochemical mapping of the Mariana arc-basin system: Implications for the nature and distribution of subduction components. G-cubed, onlinelibrary.wiley.com/doi/10.1029/2004GC000895/full

Europium anomalies in plagioclase-free deep arc cumulates constrain the redox evolution of arc magmas

NASA Astrophysics Data System (ADS)

Tang, M.; Erdman, M.; Eldridge, G.; Lee, C. T.

2017-12-01

Arc lavas are generally more oxidized than mid-ocean-ridge basalts, but how arc lavas acquire their oxidized signatures remains poorly understood. Iron oxidation state in melts have been used to suggest that fluids released from subducted slab may oxidize the sub-arc mantle and produce oxidized arc magmas from the source (e.g., Carmichael, 1991; Kelley and Cottrell), but redox-sensitive trace element and Fe isotope signatures of basalts also suggest that oxidation may happen during magma differentiation (e.g., Dauphas et al., 2009; Lee et al., 2005, 2010). One potential problem, however, is that all of these studies, represent indirect constraints on the primary, pre-erupted magma oxidation state. Here, we examine the Eu systematics of primitive, deep-seated (>45-80 km) arc cumulates, which provide the most direct constraint on arc magmas before they rise into the crust. The ratio of Eu2+/Eu3+ is a function of fo2, temperature and composition. Eu2+ is more incompatible than Eu3+ except in plagioclase. Combining Eu partitioning in minerals and experimentally calibrated Eu oxybarometer (Burnham et al., 2015) allows the application of mineral Eu anomalies in constraining magma redox conditions. The cumulates are represented by garnet-bearing pyroxenites from Arizona, USA and are arc cumulates. Because they derive from depths > 60 km, plagioclase was never present during their petrogenesis, hence any Eu anomalies reflect the effects of oxygen fugacity. We find that the most primitive cumulates have negative Eu anomalies in garnet and clinopyroxene (Eu/Eu*<1), despite the fact that depths of differentiation were too high to stabilize plagioclase. We further show that garnet and clinopyroxene Eu/Eu* increases with differentiation (decreasing Mg#), consistent with Eu2+ being more incompatible than Eu3+. Based on the Eu oxybarometer calibrated by Burnham et al. (2015), the Eu deficits in the most primitive cumulate (Mg# = 77) suggest crystallization at Dlogfo2 of FMQ-1, similar to that of mid-ocean-ridge basalts. Crystal fractionation modelling shows that the increasing Eu/Eu* in the evolved cumulates require fo2 to increase by at least 2 log units as the fractionated cumulate Mg# decreases from 77 to 53. These observations suggest that the oxidized nature of arc magmas occurs during intracrustal differentiation.

Crustal evolution of Eocene paleo arc around Ogasawara region obtained by seismic reflection survey

NASA Astrophysics Data System (ADS)

Yamashita, M.; Takahashi, N.; Kodaira, S.; Miura, S.; Ishizuka, O.; Tatsumi, Y.

2011-12-01

The Izu-Bonin (Ogasawara)-Mariana (IBM) arc is known to the typical oceanic island arc, and it is the most suitable area to understand the growth process of island arc. The existence of two paleo arc which consists of Oligocene and Eocene paleo age is known in IBM forearc region by geological and geophysical studies. The Ogasawara ridge is also known to locate the initial structure of arc evolution from geologic sampling of research submersible. In this region, IODP drilling site: IBM-2 is proposed in order to understand the temporal and spatial change in arc crust composition from 50 to 40Ma magmatism. Site IBM-2 consists of two offset drilling holes (BON-1, BON-2). BON-1 designed to first encounter forearc basalt and will reach the sheeted dykes. BON-2 will start in boninites and finish in fore arc basalts. The purpose of these drilling is sampling the full volcanic stratigraphy from gabbro to boninite. There is no seismic data around BON-1 and BON-2, therefore it is need to conduct the multi-channel seismic reflection survey. Japan Agency for Marine-Earth Science and Technology carried out multi-channel seismic reflection survey and wide-angle reflection survey using 7,800 cu.in. air gun, 5 km streamer with 444 ch hydrophones and 40 OBSs in March 2011. We obtained two seismic reflection profiles of lines KT06 and KT07 along the paleo arc around Ogasawara ridge. Line KT06 located the north side of Ogasawara ridge. Line KT07 located the trench side of Ogasawara ridge. Lines KT06 is also deployed the OBSs every 5 km interval. Thin sediments are covered with basement in both survey lines. There are some sediment filled in depression topography. The low-frequency reflection from the top of subducting Pacific plate is recognized in line KT06. The continuity of this reflection is not clear due to the complicated bathymetry. The displacement of basement in northern side of Ogasawara ridge is identified along the lineament of bathymetry in Line 06. This structure is estimated to relate the deformation in the Ogasawara Trough and lineament of paleo arc. We will discuss the relationship this lineament and deformation with regard to activity such as post volcanism.

The southwestern extension of the Jiao-Liao-Ji belt in the North China Craton: Geochronological and geochemical evidence from the Wuhe Group in the Bengbu area

NASA Astrophysics Data System (ADS)

Liu, Chaohui; Zhao, Guochun; Liu, Fulai; Cai, Jia

2018-04-01

The Wuhe complex is located at the southeastern margin of the North China Craton. The complex consists of metamorphosed Paleoproterozoic potassic granitoids and supracrustal rocks, of which the latter include the Fengyang and Wuhe groups. Meta-mafic rocks from the lower Wuhe Group have igneous zircon U-Pb ages of 2126 ± 37 Ma with εHf(t) values of -6.22 to +8.38, and xenocrystic zircons of 2.39-2.36 Ga, 2.55-2.54 Ga and 2.77-2.69 Ga. Geochemically, the meta-mafic rocks can be classified into two groups. Group 1 island arc tholeiites display flat to slightly right declined REE patterns and moderately negative Nb, Ta, Zr, and Ti anomalies. Group 2 mature arc calcalkaline basalts display strongly fractionated chondrite-normalized REE patterns and evidently negative Nb, Ta and Ti anomalies. These meta-mafic rocks formed by partial melting of sub-arc depleted mantle wedge which had been modified by slab-derived melts at an active continental margin. Depositional age of the group can be constrained in the period of 2.16-2.10 Ga based on ages of the youngest detrital zircons and latter intrusions. U-Pb ages of detrital zircons yield major age peaks of 2.69 Ga and 2.52 Ga, with minor peaks at 2.88 Ga, 2.78 Ga, 2.35 Ga and 2.17 Ga, most of which are derived from the late Mesoarchean to early Paleoproterozoic granitoids in the Wuhe complex and the Jiaodong Terrane. Metamorphic zircons in the marbles coexisting with garnet amphibolites or granulites occur as either single grains or overgrowth (or recrystallization) rims surrounding magmatic zircon cores and yield ages of 1882 ± 19 Ma to 1844 ± 15 Ma. The comparable ca. 2.1 Ga potassic granites with A-type granite affinity, the ca. 2.1 Ga meta-mafic rocks with arc-like geochemical features, the 2.1-1.9 Ga meta-sedimentary units and the 1.9-1.8 Ga subduction- and collision-related granulite-facies metamorphism suggest that the Wuhe complex and the Jiao-Liao-Ji Belt share the same late Paleoproterozoic tectonic evolution process and the former is the southwestern extension of the latter.

Neoarchean Subduction Recorded in the Northern Margin of the Yangtze Craton, South China

NASA Astrophysics Data System (ADS)

Zhang, S. B.; Zheng, Y. F.

2016-12-01

The Neoarchean is an important era during which plate tectonics began to operate widely on the earth and the continental crust compositions changed dramatically. However, reliable record of plate subduction has never been reported yet in the Yangtze Craton. Here we report geochemical studies on gneissic tonalite, trondhjemite and amphibolite in the Yudongzi Complex in the northern margin of the Yangtze Craton, which suggests that there is a plate subduction recorded in this area at about 2.7 Ga.The rocks in the Yudongzi Complex are gneissic granite, gneissic tonalite, amphibolite gneiss and magnetite quartzite. Most rocks are enriched in sodic. The gneissic granites show positive Eu anomalies, high (La/Yb)cn and Sr/Y ratios, low Ybcn and Y, resembling typical TTG. The amphibolite and tonalite gneiss show less fractionated REE patterns. SHRIMP zircon U-Pb dating on one gneissic trondhjemite, one amphibolite and one tonalite gave crystallization ages of 2667±21 Ma, 2701±10 Ma and 2697±9 Ma, respectively. They all recorded a metamorphic event at about 2.48 Ga. The SHRIMP zircon oxygen isotope analysis for a trondhjemite and an amphibolite gave δ18O values of 6.2±0.3‰ and 6.3±0.4‰, respectively. The oxygen isotope ratios higher than normal mantle values suggest a source experienced low temperature alteration. The laser fluoration analysis of bulk minerals gave δ18O values of 6.4-8.8‰ for zircon and 12.5-15.2‰ for quartz. The zircon Lu-Hf isotope analysis on the trondhjemite and amphibolite gave similar ɛHf(t) values of 0.08±0.48 and 0.07±0.63, respectively. Whole-rock ɛNd(t) values range from -1.5 to +1.0. These trondhjemite and tonalite can be interpreted as derivation from partial melting of subducted oceanic slab with a garnet-amphibolite residue.Considering the 2.67 Ga A-type granitic rocks at Huji in the interior of the craton, plate subduction took place in the northern edge of the Yangtze Craton. The Yudongzi trondhjemite and tonalite were formed in an active continental margin and the A-type granites formed as a response to the back-arc extension. The identification of 2.65-2.7 Ga subduction provides a possible link of the Yangtze Craton with the other cratons worldwide. This is also a new clue to reconstruct the Neoarchean supercontinent Kenorland.

Th-REE- and Nb-Ta-accessory minerals in post-collisional Ediacaran felsic rocks from the Katerina Ring Complex (S. Sinai, Egypt): An assessment for the fractionation of Y/Nb, Th/Nb, La/Nb and Ce/Pb in highly evolved A-type granites

NASA Astrophysics Data System (ADS)

Moreno, J. A.; Molina, J. F.; Bea, F.; Abu Anbar, M.; Montero, P.

2016-08-01

The relationships of Y/Nb, Th/Nb, La/Nb and Ce/Pb ratios in A-type felsic rocks from the Ediacaran Katerina Ring Complex, northernmost Arabian-Nubian Shield (ANS; S. Sinai, Egypt), are investigated in this work to understand their behavior during generation of highly evolved granitic magmas and to explore the nature of magma sources. Textural and compositional relationships of cognate Th-REE- and Nb-Ta-accessory minerals in Katerina felsic rocks show that chevkinite-group minerals (CGM), monazite, thorite, allanite and xenotime formed from residual liquids in quartz syenite porphyries, quartz monzonites and peralkaline granites, whereas in aluminous granites, allanite and monazite crystallized early, and thorite and columbite formed from residual liquids. Relationships of Y/Nb, Th/Nb, La/Nb and Ce/Pb ratios with Zr/Hf ratios in the aluminous granites and with Be abundances in the peralkaline granites suggest a decrease in La/Nb and Ce/Pb ratios in the former, and in Y/Nb and La/Nb ratios in the latter with crystallization progress. This contrasts with absence of systematic variations of Th/Nb and Ce/Pb ratios in the peralkaline compositions and of Y/Nb ratio in the aluminous ones. In this latter, Th/Nb ratio can present a significant decrease only in highly evolved compositions. An analysis of Y/Nb, Th/Nb, La/Nb and Ce/Pb relationships in worldwide OIB and subduction-related magmatic suites reveals that A-type felsic rocks with (Th/Nb)N < 1.3, (La/Nb)N < 1.3, and (Ce/Pb)N > 1 may have A1-type affinity, and those with (Th/Nb)N > 2, (La/Nb)N > 2, and (Ce/Pb)N < 1 tend to present A2-type affinity. The crystal fractionation of Th-LREE- and Nb-Ta-accessory minerals and mixing of components derived from the two granite groups may cause deviations from these compositional limits that can be evaluated using constraints imposed by Th/Nb-La/Nb, Ce/Pb-Th/Nb and Ce/Pb-La/Nb relationships in OIB and subduction-related magmatic suites. Three mantle sources might have been involved in the Ediacaran alkaline magmatism from northernmost ANS that are chemically similar to those of (1) OIB suites, (2) subduction-related magmatic suites, and (3) carbonatite-metasomatized peridotites. In addition, compositions characterized by (Y/Nb)N > 0.18, (Th/Nb)N > 2, (La/Nb)N > 2, (Ce/Pb)N < 1, and crustal-like Nb/Ta ratios may point to a significant contribution of crustal sources.

Performance and Long Duration Test of a 30 kw Thermal Arcjet Engine.

DTIC Science & Technology

1987-11-01

Surface ____________________________ 69 50. SEM Close-up of Cathode Crater Surface Completely Covered with Arc Microspots and Splashed Tung- sten ...gaskets, and possibly stretching the bolts and/or nuts. 17 CL 4- C4 ---- 40 as 00 CiC E 18~ le J .Ir e 5 Figure 11 is a composite picture of the... composition . This transducer was zeroed both electronically and with reference to an ion gauge in a second vacuum system pumped by 26 F6 W. 320 a 280- (n, gis

Debonding/Delamination of Composites (Le Decollement et le Delaminage des Materiaux Composites)

DTIC Science & Technology

1992-12-01

augmented by the first cigenmode Z, magnified b% arc related, however, to a finite total potential energy % al- a scale factor ). In the algebraiL ,,stem...strength of cr ack canniit be measured because of the brushike mect- the r3tltl914C-material lapping of fibers. in reality , after a certain crack...the delamination growth This is not true in reality fracture theory the ERR is defined by and, therefor,, some ideas will be discucsed here to over

Petrogenesis of metamorphosed Paleoproterozoic, arc-related tonalites, granodiorites and coeval basic to intermediate rocks from southernmost Brazil, based on elemental and isotope geochemistry

NASA Astrophysics Data System (ADS)

Gregory, Tiago Rafael; Bitencourt, Maria de Fátima; Nardi, Lauro Valentim Stoll; Florisbal, Luana Moreira

2017-04-01

In southern Brazil, three associations of metamorphosed tonalites and granodiorites that are compositionally similar to tonalite-trondhjemite-granodiorite (TTG) or adakitic associations have been identified in the Arroio dos Ratos Complex (ARC) Paleoproterozoic magmatism. The metatonalites of Association 1 (A1; 2148 ± 33 Ma) have a well-developed fabric, compatible with strong solid-state deformation. The metatonalites and metagranodiorites of Association 2 (A2; 2150 ± 28 Ma) are intrusive in A1 and have a similar composition, but are less deformed, and their primary structures are partly preserved. Both associations display contemporaneity relations with basic to intermediate magmas. Association 3 (A3; 2077 ± 13 Ma) is represented by tonalitic to granodioritic gneisses, without any associated basic to intermediate magmatism, and its main characteristic is the banding that resulted from strong solid-state deformation. Partial melting features are locally present in A3. The geochemical compositions of the three associations are similar and indicate sources related to a continental magmatic arc environment. The 87Sr/86Sr(i) ratios (between 0.701 and 0.703), positive ƐNd(t) values (+ 1.45 to + 5.19), and TDM ages close to the crystallization ages indicate juvenile sources for the A1 and A2 associations. The A3 rocks have a 87Sr/86Sr(i) ratio of 0.715, an ƐNd(t) value of + 0.47 and a TDM age that is close to the crystallization age, indicating a source composition different from those of the other associations. The Pb isotope ratios of A1 and A2 are similar and compatible with the evolution of mantle and orogen (208Pb/204Pb = 37.3-37.6; 207Pb/204Pb = 15.62-15.65; 206Pb/204Pb = 18.0-18.2). The Pb isotope ratios of A3 differ from A1 and A2, indicating a more Th-poor source (208Pb/204Pb = 37.1; 207Pb/204Pb = 15.64; 206Pb/204Pb = 18.5). The geochemistry of associations A1 and A2 suggests a juvenile source with contamination by crustal material. However, the Sr-Nd-Pb isotope signature of this contaminant is similar to that of the source material that originated these associations. This may be the crust generated in the magmatic arc, which is compatible with the geochronological results. The dataset points to the occurrence of self-cannibalism processes in the generation of the ARC rocks. The similar chemical composition and ƐNd(t) values of A3 relative to A1 and A2 indicate that the A3 source is similar to the one that generated the tonalitic and granodioritic rocks of A1 and A2. However, the slightly lower 208Pb/204Pb, and higher 206Pb/204Pb and 87Sr/86Sr(i) ratios indicate that the A3 association has also the addition of a distinct crustal source. The A3 association high values of the parameter 87Sr/86Sr(i) and its Pb isotope signature indicate a source with high Rb and U, and low Th contents. Such features, and moreover the depletion of HREE combined with TDM values near the igneous age, suggest that the source for A3 may be juvenile arc sediments. The greater degree of crustal contribution, the lack of associated basic to intermediate rocks, and the younger age possibly mark the more mature or late stages of the arc. The major and trace elements, as well as the isotope data obtained in this study suggest that melting of a metasomatized mantle wedge can be the process that generated the ARC basic to intermediate rocks (A1 and A2). The generation of tonalitic and granodioritic rocks with adakitic characteristics (i.e., the depletion of heavy rare earth elements in tonalitic and granodioritic rocks of A1, A2 and A3) may have arisen from the melting of a garnet-rich source or from fractional crystallization of ARC basic to intermediate magmas, which in time increased crustal assimilation under high-pressure conditions. The crustal garnet-rich source could be the basic rocks newly placed at the base of the crust, derived from partial melting of metasomatized mantle. The remobilization of this material by partial melting may have generated tonalitic and granodioritic liquids depleted in heavy REE due to the presence of garnet in the residue. The three associations display microstructures that indicate two episodes of recrystallization, one of a higher temperature and one of a lower temperature. The age of the high-temperature structure remains under discussion and may be attributed to a Paleoproterozoic metamorphic event. The low-temperature event is compatible with the temperature conditions observed in adjacent areas, in the host rocks of the Neoproterozoic post-collisional granitoids that have been emplaced along the Southern Brazilian Shear Belt (SBSB). Zircon crystals with Paleoproterozoic igneous cores exhibit a metamorphic overgrowth at 635 ± 6 Ma, compatible with the crystallization ages of the SBSB granitoids.

Straddling the tholeiitic/calc-alkaline transition: the effects of modest amounts of water on magmatic differentiation at Newberry Volcano, Oregon

USGS Publications Warehouse

Mandler, Ben E.; Donnelly-Nolan, Julie M.; Grove, Timothy L.

2014-01-01

Melting experiments have been performed at 1 bar (anhydrous) and 1- and 2-kbar H2O-saturated conditions to study the effect of water on the differentiation of a basaltic andesite. The starting material was a mafic pumice from the compositionally zoned tuff deposited during the ~75 ka caldera-forming eruption of Newberry Volcano, a rear-arc volcanic center in the central Oregon Cascades. Pumices in the tuff of Newberry caldera (TNC) span a continuous silica range from 53 to 74 wt% and feature an unusually high-Na2O content of 6.5 wt% at 67 wt% SiO2. This wide range of magmatic compositions erupted in a single event makes the TNC an excellent natural laboratory in which to study the conditions of magmatic differentiation. Our experimental results and mineral–melt hygrometers/thermometers yield similar estimates of pre-eruptive H2O contents and temperatures of the TNC liquids. The most primitive (mafic) basaltic andesites record a pre-eruptive H2O content of 1.5 wt% and a liquidus temperature of 1,060–1,070 °C at upper crustal pressure. This modest H2O content produces a distinctive fractionation trend that is much more enriched in Na, Fe, and Ti than the calc-alkaline trend typical of wetter arc magmas, but slightly less enriched in Fe and Ti than the tholeiitic trend of dry magmas. Modest H2O contents might be expected at Newberry Volcano given its location in the Cascade rear arc, and the same fractionation trend is also observed in the rim andesites of the rear-arc Medicine Lake volcano in the southern Cascades. However, the Na–Fe–Ti enrichment characteristic of modest H2O (1–2 wt%) is also observed to the west of Newberry in magmas erupted from the arc axis, such as the Shevlin Park Tuff and several lava flows from the Three Sisters. This shows that modest-H2O magmas are being generated directly beneath the arc axis as well as in the rear arc. Because liquid lines of descent are particularly sensitive to water content in the range of 0–3 wt% H2O, they provide a quantitative and reliable tool for precisely determining pre-eruptive H2O content using major-element data from pumices or lava flows. Coupled enrichment in Na, Fe, and Ti relative to the calc-alkaline trend is a general feature of fractional crystallization in the presence of modest amounts of H2O, which may be used to look for “damp” fractionation sequences elsewhere.

"I Can't Relate": Refusing Identification Demands in Teaching and Learning

ERIC Educational Resources Information Center

Barnard, Ian

2016-01-01

In literature, composition, and other areas of English Studies, relateability can be an important tool to inscribe marginalized subjects as academic citizens. However, its larger arc reproduces ethnocentric and individualistic ideologies at the national and personal levels that foreclose the true understanding of and engagement with Otherness that…

Study the Effect of SiO2 Based Flux on Dilution in Submerged Arc Welding

NASA Astrophysics Data System (ADS)

kumar, Aditya; Maheshwari, Sachin

2017-08-01

This paper highlights the method for prediction of dilution in submerged arc welding (SAW). The most important factors of weld bead geometry are governed by the weld dilution which controls the chemical and mechanical properties. Submerged arc welding process is used generally due to its very easy control of process variables, good penetration, high weld quality, and smooth finish. Machining parameters, with suitable weld quality can be achieved with the different composition of the flux in the weld. In the present study Si02-Al2O3-CaO flux system was used. In SiO2 based flux NiO, MnO, MgO were mixed in various proportions. The paper investigates the relationship between the process parameters like voltage, % of flux constituents and dilution with the help of Taguchi’s method. The experiments were designed according to Taguchi L9 orthogonal array, while varying the voltage at two different levels in addition to alloying elements. Then the optimal results conditions were verified by confirmatory experiments.

Arc-Induced Long Period Gratings from Standard to Polarization-Maintaining and Photonic Crystal Fibers

PubMed Central

Campopiano, Stefania; Iadicicco, Agostino

2018-01-01

In this work, we report about our recent results concerning the fabrication of Long Period Grating (LPG) sensors in several optical fibers, through the Electric Arc Discharge (EAD) technique. In particular, the following silica fibers with both different dopants and geometrical structures are considered: standard Ge-doped, photosensitive B/Ge codoped, P-doped, pure-silica core with F-doped cladding, Panda type Polarization-maintaining, and Hollow core Photonic crystal fiber. An adaptive platform was developed and the appropriate “recipe” was identified for each fiber, in terms of both arc discharge parameters and setup arrangement, for manufacturing LPGs with strong and narrow attenuation bands, low insertion losses, and short length. As the fabricated devices have appealing features from the application point of view, the sensitivity characteristics towards changes in different external perturbations (i.e., surrounding refractive index, temperature, and strain) are investigated and compared, highlighting the effects of different fiber composition and structure. PMID:29558407

Process characteristics of the combination of laser beam- and gas metal arc welding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalla, G.; Neuenhahn, J.; Koerber, C.

1994-12-31

In this presentation, experiences regarding the combination of laser beam-and gas metal arc welding are discussed. The combination of both techniques offers the possibility of using the specific advantages include the deep penetration effect and the concentrated heat input. Additionally, the gas metal arc welding (GMAW) process is characterized by several advantages, such as high thermal efficiency and good gap-bridging ability. Beyond these characteristics, the combination leads to additional advantages concerning process, technique, and quality. Improvement of seam quality and properties are of special note. Adaptation of the GMAW parameters reduces the hardness of the seam weld at increasing weldingmore » speed. This is possible by adapting the efficiency of metal deposition and by the suitable choice of wire material composition. Another advantage is an improvement of surface topology. The surface of the weld seam and the connection to the base material are very smooth. This leads to advantages with regard to the fatigue strength of the seam.« less

Timing of magmatism following initial convergence at a passive margin, southwestern U.S. Cordillera, and ages of lower crustal magma sources

USGS Publications Warehouse

Barth, A.P.; Wooden, J.L.

2006-01-01

Initiation of the Cordilleran magmatic arc in the southwestern United States is marked by intrusion of granitic plutons, predominantly composed of alkali-calcic Fe- and Sr-enriched quartz monzodiorite and monzonite, that intruded Paleoproterozoic basement and its Paleozoic cratonal-miogeoclinal cover. Three intrusive suites, recognized on the basis of differences in high field strength element and large ion lithophile element abundances, contain texturally complex but chronologically distinctive zircons. These zircons record heterogeneous but geochemically discrete mafic crustal magma sources, discrete Permo-Triassic intrusion ages, and a prolonged postemplacement thermal history within the long-lived Cordilleran arc, leading to episodic loss of radiogenic Pb. Distinctive lower crustal magma sources reflect lateral heterogeneity within the composite lithosphere of the Proterozoic craton. Limited interaction between derived magmas and middle and upper crustal rocks probably reflects the relatively cool thermal structure of the nascent Cordilleran continental margin magmatic arc. ?? 2006 by The University of Chicago. All rights reserved.

Sentinel-2 ArcGIS Tool for Environmental Monitoring

NASA Astrophysics Data System (ADS)

Plesoianu, Alin; Cosmin Sandric, Ionut; Anca, Paula; Vasile, Alexandru; Calugaru, Andreea; Vasile, Cristian; Zavate, Lucian

2017-04-01

This paper addresses one of the biggest challenges regarding Sentinel-2 data, related to the need of an efficient tool to access and process the large collection of images that are available. Consequently, developing a tool for the automation of Sentinel-2 data analysis is the most immediate need. We developed a series of tools for the automation of Sentinel-2 data download and processing for vegetation health monitoring. The tools automatically perform the following operations: downloading image tiles from ESA's Scientific Hub or other venders (Amazon), pre-processing of the images to extract the 10-m bands, creating image composites, applying a series of vegetation indexes (NDVI, OSAVI, etc.) and performing change detection analyses on different temporal data sets. All of these tools run in a dynamic way in the ArcGIS Platform, without the need of creating intermediate datasets (rasters, layers), as the images are processed on-the-fly in order to avoid data duplication. Finally, they allow complete integration with the ArcGIS environment and workflows

Microstructural changes of a thermally aged stainless steel submerged arc weld overlay cladding of nuclear reactor pressure vessels

NASA Astrophysics Data System (ADS)

Takeuchi, T.; Kameda, J.; Nagai, Y.; Toyama, T.; Matsukawa, Y.; Nishiyama, Y.; Onizawa, K.

2012-06-01

The effect of thermal aging on microstructural changes in stainless steel submerged arc weld-overlay cladding of reactor pressure vessels was investigated using atom probe tomography (APT). In as-received materials subjected to post-welding heat treatments (PWHTs), with a subsequent furnace cooling, a slight fluctuation of the Cr concentration was observed due to spinodal decomposition in the δ-ferrite phase but not in the austenitic phase. Thermal aging at 400 °C for 10,000 h caused not only an increase in the amplitude of spinodal decomposition but also the precipitation of G phases with composition ratios of Ni:Si:Mn = 16:7:6 in the δ-ferrite phase. The degree of the spinodal decomposition in the submerged arc weld sample was similar to that in the electroslag weld one reported previously. We also observed a carbide on the γ-austenite and δ-ferrite interface. There were no Cr depleted zones around the carbide.

Flight and ground tests of a very low density elastomeric ablative material

NASA Technical Reports Server (NTRS)

Olsen, G. C.; Chapman, A. J., III

1972-01-01

A very low density ablative material, a silicone-phenolic composite, was flight tested on a recoverable spacecraft launched by a Pacemaker vehicle system; and, in addition, it was tested in an arc heated wind tunnel at three conditions which encompassed most of the reentry heating conditions of the flight tests. The material was composed, by weight, of 71 percent phenolic spheres, 22.8 percent silicone resin, 2.2 percent catalyst, and 4 percent silica fibers. The tests were conducted to evaluate the ablator performance in both arc tunnel and flight tests and to determine the predictability of the albator performance by using computed results from an existing one-dimensional numerical analysis. The flight tested ablator experienced only moderate surface recession and retained a smooth surface except for isolated areas where the char was completely removed, probably following reentry and prior to or during recovery. Analytical results show good agreement between arc tunnel and flight test results. The thermophysical properties used in the analysis are tabulated.

Resin/graphite fiber composites

NASA Technical Reports Server (NTRS)

Cavano, P. J.

1974-01-01

Techniques were developed that provided thermo-oxidatively stable A-type polyimide/graphite fiber composites using the approach of in situ polymerization of monomeric reactants directly on reinforcing fibers, rather than employing separately prepared prepolymer varnish. This was accomplished by simply mixing methylene dianiline and two ester-acids and applying this solution to the fibers for subsequent molding. Five different formulated molecular weight resins were examined, and an optimized die molding procedure established for the 1500 formulated molecular weight system. Extensive ultrasonic inspection of composites was successfully utilized as a technique for monitoring laminate quality. Composite mechanical property studies were conducted with this polyimide resin at room temperature and after various time exposures in a thermo-oxidative environment at 561 K (550 F), 589 K (600 F) and 617 K (650 F). It was determined that such composites have a long term life in the temperature range of 561 K to 589 K. The final phase involved the fabrication and evaluation of a series of demonstration airfoil specimens.

40Ar/39Ar geochronology of subaerial lava flows of Barren Island volcano and the deep crust beneath the Andaman Island Arc, Burma Microplate

NASA Astrophysics Data System (ADS)

Ray, Jyotiranjan S.; Pande, Kanchan; Bhutani, Rajneesh

2015-06-01

Little was known about the nature and origin of the deep crust beneath the Andaman Island Arc in spite of the fact that it formed part of the highly active Indonesian volcanic arc system, one of the important continental crust forming regions in Southeast Asia. This arc, formed as a result of subduction of the Indian Plate beneath the Burma Microplate (a sliver of the Eurasian Plate), contains only one active subaerial magmatic center, Barren Island volcano, whose evolutional timeline had remained uncertain. In this work, we present results of the first successful attempt to date crustal xenoliths and their host lava flows from the island, by incremental heating 40Ar/39Ar method, in an attempt to understand the evolutionary histories of the volcano and its basement. Based on concordant plateau and isochron ages, we establish that the oldest subaerial lava flows of the volcano are 1.58 ± 0.04 (2σ) Ma, and some of the plagioclase xenocrysts have been derived from crustal rocks of 106 ± 3 (2σ) Ma. Mineralogy (anorthite + Cr-rich diopside + minor olivine) and isotopic compositions (87Sr/86Sr < 0.7040; ɛNd > 7.0) of xenoliths not only indicate their derivation from a lower (oceanic) crustal olivine gabbro but also suggest a genetic relationship between the arc crust and the ophiolitic basement of the Andaman accretionary prism. We speculate that the basements of the forearc and volcanic arc of the Andaman subduction zone belong to a single continuous unit that was once attached to the western margin of the Eurasian Plate.

Copahue volcano and its regional magmatic setting

USGS Publications Warehouse

Varekamp, J C; Zareski, J E; Camfield, L M; Todd, Erin

2016-01-01

Copahue volcano (Province of Neuquen, Argentina) has produced lavas and strombolian deposits over several 100,000s of years, building a rounded volcano with a 3 km elevation. The products are mainly basaltic andesites, with the 2000–2012 eruptive products the most mafic. The geochemistry of Copahue products is compared with those of the main Andes arc (Llaima, Callaqui, Tolhuaca), the older Caviahue volcano directly east of Copahue, and the back arc volcanics of the Loncopue graben. The Caviahue rocks resemble the main Andes arc suite, whereas the Copahue rocks are characterized by lower Fe and Ti contents and higher incompatible element concentrations. The rocks have negative Nb-Ta anomalies, modest enrichments in radiogenic Sr and Pb isotope ratios and slightly depleted Nd isotope ratios. The combined trace element and isotopic data indicate that Copahue magmas formed in a relatively dry mantle environment, with melting of a subducted sediment residue. The back arc basalts show a wide variation in isotopic composition, have similar water contents as the Copahue magmas and show evidence for a subducted sedimentary component in their source regions. The low 206Pb/204Pb of some backarc lava flows suggests the presence of a second endmember with an EM1 flavor in its source. The overall magma genesis is explained within the context of a subducted slab with sediment that gradually looses water, water-mobile elements, and then switches to sediment melt extracts deeper down in the subduction zone. With the change in element extraction mechanism with depth comes a depletion and fractionation of the subducted complex that is reflected in the isotope and trace element signatures of the products from the main arc to Copahue to the back arc basalts.

Magmatic arc structure around Mount Rainier, WA, from the joint inversion of receiver functions and surface wave dispersion

NASA Astrophysics Data System (ADS)

Obrebski, Mathias; Abers, Geoffrey A.; Foster, Anna

2015-01-01

The deep magmatic processes in volcanic arcs are often poorly understood. We analyze the shear wave velocity (VS) distribution in the crust and uppermost mantle below Mount Rainier, in the Cascades arc, resolving the main velocity contrasts based on converted phases within P coda via source normalization or receiver function (RF) analysis. To alleviate the trade-off between depth and velocity, we use long period phase velocities (25-100 s) obtained from earthquake surface waves, and at shorter period (7-21 s) we use seismic noise cross correlograms. We use a transdimensional Bayesian scheme to explore the model space (VS in each layer, number of interfaces and their respective depths, level of noise on data). We apply this tool to 15 broadband stations from permanent and Earthscope temporary stations. Most results fall into two groups with distinctive properties. Stations east of the arc (Group I) have comparatively slower middle-to-lower crust (VS = 3.4-3.8 km/s at 25 km depth), a sharp Moho and faster uppermost mantle (VS = 4.2-4.4 km/s). Stations in the arc (Group II) have a faster lower crust (VS = 3.7-4 km/s) overlying a slower uppermost mantle (VS = 4.0-4.3 km/s), yielding a weak Moho. Lower crustal velocities east of the arc (Group I) most likely represent ancient subduction mélanges mapped nearby. The lower crust for Group II ranges from intermediate to felsic. We propose that intermediate-felsic to felsic rocks represent the prearc basement, while intermediate composition indicates the mushy andesitic crustal magmatic system plus solidified intrusion along the volcanic conduits. We interpret the slow upper mantle as partial melt.

Volcanic signature of Basin and Range extension on the shrinking Cascade arc, Klamath Falls-Keno area, Oregon

NASA Astrophysics Data System (ADS)

Priest, George R.; Hladky, Frank R.; Mertzman, Stanley A.; Murray, Robert B.; Wiley, Thomas J.

2013-08-01

geologic mapping of the Klamath Falls-Keno area revealed the complex relationship between subduction, crustal extension, and magmatic composition of the southern Oregon Cascade volcanic arc. Volcanism in the study area at 7-4 Ma consisted of calc-alkaline basaltic andesite and andesite lava flowing over a relatively flat landscape. Local angular unconformities are evidence that Basin and Range extension began at by at least 4 Ma and continues today with fault blocks tilting at a long-term rate of 2°/Ma to 3°/Ma. Minimum NW-SE extension is 1.5 km over 28 km ( 5%). High-alumina olivine tholeiite (HAOT) or low-K, low-Ti transitional high-alumina olivine tholeiite (LKLT) erupted within and adjacent to the back edge of the calc-alkaline arc as the edge receded westward at a rate of 10 km/Ma at 2.7-0.45 Ma. The volcanic front migrated east much slower than the back arc migrated west: 0 km/Ma for 6-0.4 Ma calc-alkaline rocks; 0.7 km/Ma, if 6 Ma HAOT-LKLT is included; and 1 km/Ma, if highly differentiated 17-30 Ma volcanic rocks of the early Western Cascades are included. Declining convergence probably decreased asthenospheric corner flow, decreasing width of calc-alkaline and HAOT-LKLT volcanism and the associated heat flow anomaly, the margins of which focused on Basin and Range extension and leakage of HAOT-LKLT magma to the surface. This declining corner flow combined with steepening slab dip shifted the back arc west. Compensation of extension by volcanic intrusion and extrusion allowed growth of imposing range-front fault scarps only behind the trailing edge of the shrinking arc.

Sexual health literacy of the student population of the University of Tasmania: results of the RUSSL Study.

PubMed

Simpson, Steve; Clifford, Christine; Ross, Kaz; Sefton, Neil; Owen, Louise; Blizzard, Leigh; Turner, Richard

2015-06-01

Background Evidence suggests a varied level of sexual health literacy (SHL) among university student populations, so we evaluated the SHL among students at the University of Tasmania. Students were invited to complete an anonymous online questionnaire during August/September 2013. SHL was assessed using the ARCSHS National Survey of Australian Secondary Students & Sexual Health (ARC) and the Sexual Health Questionnaire (SHS). Predictors of literacy scores were evaluated by linear regression. The study recruited 1786 participants (8.2% of 2013 student population), of similar composition to the general university population. Female sex, older age, sexual education, and sexual experience were significant predictors of SHL. As hypothesised, students in medical/nursing disciplines had the highest SHL. Less expected were the significant differences by birthplace and religious affiliation, many of which persisted on adjustment for confounders. Compared with Australian/New Zealander students, overseas-born students had significantly lower ARC (-3.6%, P<0.001) & SHS (-4.2%, P<0.001); this was driven by Malaysian, Indian, and Chinese students. Compared with agnostic/atheist-identifying students, those of Buddhist (ARC: -5.4%, P=0.014; SHS: -6.7%, P=0.002), Hindu (ARC: -8.8%, P=0.098; SHS: -12.2%, P=0.027), Muslim (ARC: -16.5%, P<0.001; SHS: -13.4%, P=0.001) and Protestant (ARC: -2.3%, P=0.023; SHS: -4.4%, P<0.001) identifications had markedly lower SHL. This study, one of the first among university students in Australia, found a varied SHL by sex, age, sexual education and sexual experience, as well as by birthplace and religious affiliation. These findings have applications in orientation and education programs at Australian universities.

Slab edge interaction with a back-arc spreading center: 3D instantaneous mantle flow models of Vanuatu, SW Pacific

NASA Astrophysics Data System (ADS)

McLean, K. A.; Jadamec, M.; Durance-Sie, P. M.; Moresi, L. N.

2011-12-01

The Vanuatu area of the south-west Pacific is a dynamic region of high heat-flow and strain-rate, dominated by ongoing plate boundary processes. At the southern termination of the Vanuatu arc the curved geometry of the New Hebrides trench juxtaposes the slab edge perpendicular to its back-arc spreading center. While existing 3D subduction models have demonstrated the importance of mantle flow around a slab edge, the nature of interaction between back-arc upwelling and circum-slab edge mantle flow is not well understood. We use 3D instantaneous numerical models of a Newtonian mantle rheology to test the effect of the slab edge and back-arc upwelling on the mantle flow vector field beneath southern Vanuatu. These high-resolution models simulate temperature-dependent buoyancy-driven deformation of the lithosphere and mantle for a realistic slab geometry. Model results show a small but significant component of vertical mantle flow velocity associated with the slab edge and back-arc spreading center. We also see strain-rate and dynamic topography commensurate with surface observations. Mantle flow by toroidal-type motion brings hotter mantle material from behind the slab into the mantle wedge, elevating geothermal gradients in the slab edge vicinity. The implications of moderate vertical displacement of this hot mantle material at the slab edge are wide-ranging, and such a tectonic framework might aid interpretation of a number of surface observations. For example, induced decompression partial-melting in the mantle wedge and/or slab, and thermal erosion of the slab may contribute to the diverse magma compositions from this region.

A high-performance nonenzymatic glucose sensor made of CuO-SWCNT nanocomposites.

PubMed

Quoc Dung, Nguyen; Patil, Dewyani; Jung, Hyuck; Kim, Dojin

2013-04-15

Nanocomposites of CuO and single-wall carbon nanotubes (SWCNTs) were synthesized using an arc-discharging graphite rod that contained copper wires. Simultaneous arc discharges produced a CuO-SWCNT composite network. The crystalline structure and morphology of the CuO-SWCNT composite films were investigated using XRD, Raman spectroscopy, FE-SEM and TEM. The electrochemical properties were investigated by cyclic voltammogram and amperometric measurements in a 0.1 M NaOH solution. The CuO content in the CuO-SWCNT nanocomposites was optimized for nonenzymatic glucose detection. The glucose sensing properties of the optimized CuO-SWCNT electrode showed good stability, selectivity, and linear glucose detection that ranged from 0.05 to 1800 μM with a higher sensitivity of 1610 μA cm⁻² mM⁻¹, a quick response time of 1-2 s, and the lowest limit of detection at 50 nM. The sensing performance was better than the pure CuO and SWCNT sensors, and the synergetic effect of the composite sensor was attributed to the high conductivity network of highly porous nanowires. The sensor also showed a good response in a human serum sample, which proves its high potential towards a commercial nonenzymatic glucose sensor. Copyright © 2012 Elsevier B.V. All rights reserved.

Fabrication of a Mo based high temperature TZM alloy by non-consumable arc melting technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chakraborty, S.P.; Krishnamurthy, N., E-mail: spc@barc.gov.in

High temperature structural materials are in great demand for power, chemical and nuclear industries which can perform beyond 1000 °C as super alloys usually fail. In this regard, Mo based TZM alloy is capable of retaining strength up to 1500 °C with excellent corrosion compatibility against molten alkali metals. Hence, currently this alloy is considered an important candidate material for high temperature compact nuclear and fusion reactors. Due to reactive nature of Mo and having high melting point, manufacturing this alloy by conventional process is unsuitable. Powder metallurgy technique has limited success due to restriction in quantity and purity. Thismore » paper deals with fabrication of TZM alloy by nonconsumable tungsten arc melting technique. Initially a ternary master alloy of Mo-Ti-Zr was prepared which subsequently by dilution method, was converted into TZM alloy gradually by external addition of Mo and C in various proportions. A number of melting trials were conducted to optimize the process parameters like current, voltage and time to achieve desired alloy composition. The alloy was characterized with respect to composition, elemental distribution profile, microstructure, hardness profile and phase analysis. Well consolidated alloy button was obtained having desired composition, negligible material loss and having microstructure as comparable to standard TZM alloy. (author)« less