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Sample records for confinement potential geometry

  1. Freezing in confined geometries

    NASA Technical Reports Server (NTRS)

    Sokol, P. E.; Ma, W. J.; Herwig, K. W.; Snow, W. M.; Wang, Y.; Koplik, Joel; Banavar, Jayanth R.

    1992-01-01

    Results of detailed structural studies, using elastic neutron scattering, of the freezing of liquid O2 and D2 in porous vycor glass, are presented. The experimental studies have been complemented by computer simulations of the dynamics of freezing of a Lennard-Jones liquid in narrow channels bounded by molecular walls. Results point to a new simple physical interpretation of freezing in confined geometries.

  2. PREFACE: Water in confined geometries

    NASA Astrophysics Data System (ADS)

    Rovere, Mauro

    2004-11-01

    particularly important to understand whether the glass transition temperature could be experimentally accessible for confined water. In this respect the modifications induced by the confinement on the dynamics of water on supercooling are of extreme interest and a number of experimental and computer simulation studies have been devoted in recent years to this topic. This special section contains papers from different groups which have contributed with various experimental and computer simulation techniques to the progress made in the study of water in confined geometry. I thank all of the authors for their stimulating contributions. I am very pleased in particular that Sow-Hsin Chen agreed to contribute since he has done pioneering experimental work on the dynamical properties of confined water upon supercooling, and he is still very active in the field. The work presented by the group of J Swenson concerns also the glass transition of confined water. The Messina group (Crupi et al) is very active in the study of dynamical properties of confined water and they present their results on water in zeolites. From the experimental side there is also a contribution from J Dore's group, one of the first to perform neutron scattering studies on confined water. The work of J Klein looks at the mobility of water molecules confined in subnanometre films. Important contributions on the computer simulation side come from the Geiger group (Brovchenko et al). They performed very accurate simulations of water in nanopores, exploring a large portion of the phase space. Puibasset et al were able to build a very realistic model to simulate water inside Vycor. Zangi et al review the extensive work performed on confined water. Jedlovszky is an expert on the model potential for water and studied how the hydrogen bond network of water can be modified by the presence of an interface. The special issue is intended to stimulate interest and future work on this important subject.

  3. Amoeboid motion in confined geometry

    NASA Astrophysics Data System (ADS)

    Wu, Hao; Thiébaud, M.; Hu, W.-F.; Farutin, A.; Rafaï, S.; Lai, M.-C.; Peyla, P.; Misbah, C.

    2015-11-01

    Many eukaryotic cells undergo frequent shape changes (described as amoeboid motion) that enable them to move forward. We investigate the effect of confinement on a minimal model of amoeboid swimmer. A complex picture emerges: (i) The swimmer's nature (i.e., either pusher or puller) can be modified by confinement, thus suggesting that this is not an intrinsic property of the swimmer. This swimming nature transition stems from intricate internal degrees of freedom of membrane deformation. (ii) The swimming speed might increase with increasing confinement before decreasing again for stronger confinements. (iii) A straight amoeoboid swimmer's trajectory in the channel can become unstable, and ample lateral excursions of the swimmer prevail. This happens for both pusher- and puller-type swimmers. For weak confinement, these excursions are symmetric, while they become asymmetric at stronger confinement, whereby the swimmer is located closer to one of the two walls. In this study, we combine numerical and theoretical analyses.

  4. Amoeboid motion in confined geometry.

    PubMed

    Wu, Hao; Thiébaud, M; Hu, W-F; Farutin, A; Rafaï, S; Lai, M-C; Peyla, P; Misbah, C

    2015-01-01

    Many eukaryotic cells undergo frequent shape changes (described as amoeboid motion) that enable them to move forward. We investigate the effect of confinement on a minimal model of amoeboid swimmer. A complex picture emerges: (i) The swimmer's nature (i.e., either pusher or puller) can be modified by confinement, thus suggesting that this is not an intrinsic property of the swimmer. This swimming nature transition stems from intricate internal degrees of freedom of membrane deformation. (ii) The swimming speed might increase with increasing confinement before decreasing again for stronger confinements. (iii) A straight amoeoboid swimmer's trajectory in the channel can become unstable, and ample lateral excursions of the swimmer prevail. This happens for both pusher- and puller-type swimmers. For weak confinement, these excursions are symmetric, while they become asymmetric at stronger confinement, whereby the swimmer is located closer to one of the two walls. In this study, we combine numerical and theoretical analyses.

  5. Multiphase flows in confinement with complex geometries

    NASA Astrophysics Data System (ADS)

    Aymard, Benjamin; Pradas, Marc; Vaes, Urbain; Kalliadasis, Serafim

    2016-11-01

    Understanding the dynamics of immiscible fluids in confinement is crucial in numerous applications such as oil recovery, fuel cells and the rapidly growing field of microfluidics. Complexities such as microstructures, chemical-topographical heterogeneities or porous membranes, can often induce non-trivial effects such as critical phenomena and phase transitions . The dynamics of confined multiphase flows may be efficiently described using diffuse-interface theory, leading to the Cahn-Hilliard-Navier-Stokes(CHNS) equations with Cahn wetting boundary conditions. Here we outline an efficient numerical method to solve the CHNS equations using advanced geometry-capturing mesh techniques both in two and three dimensional scenarios. The methodology is applied to two different systems: a droplet on a spatially chemical-topographical heterogeneous substrateand a microfluidic separator.

  6. Swimming Vorticella convallaria in various confined geometries

    NASA Astrophysics Data System (ADS)

    Sotelo, Luz; Lee, Donghee; Jung, Sunghwan; Ryu, Sangjin

    2014-11-01

    Vorticella convallaria is a stalked ciliate observed in the sessile form (trophont) or swimming form (telotroch). Trophonts are mainly composed of an inverted bell-shaped cell body generating vortical feeding currents, and a slender stalk attaching the cell body to a substrate. If the surrounding environment is no longer suitable, the trophont transforms into a telotroch by elongating its cell body into a cylindrical shape, resorbing its oral cilia and producing an aboral cilia wreath. After a series of contractions, the telotroch will completely detach from the stalk and swim away to find a better location. While sessile Vorticella has been widely studied because of its stalk contraction and usefulness in waste treatment, Vorticella's swimming has not yet been characterized. The purpose of this study is to describe V. convallaria's swimming modes, both in its trophont and telotroch forms, in different confined geometries. Using video microscopy, we observed Vorticellae swimming in semi-infinite field, in Hele-Shaw configurations, and in capillary tubes. Based on measured swimming displacement and velocity, we investigated how V. convallaria's mobility was affected by the geometry constrictions. We acknolwedge support from the First Award grant of Nebraska EPSCoR.

  7. Plasma confinement. [Physics for magnetic geometries

    SciTech Connect

    Boozer, A.H.

    1985-03-01

    The physics of plasma confinement by a magnetic field is developed from the basic properties of plasmas through the theory of equilibrium, stability, and transport in toroidal and open-ended configurations. The close relationship between the theory of plasma confinement and Hamiltonian mechanics is emphasized, and the modern view of macroscopic instabilities as three-dimensional equilibria is given.

  8. Crystallization of carbon tetrachloride in confined geometries.

    PubMed

    Meziane, Adil; Grolier, Jean-Pierre E; Baba, Mohamed; Nedelec, Jean-Marie

    2007-01-01

    The thermal behaviour of carbon tetrachloride confined in silica gels of different porosities was studied by differential scanning calorimetry. Both the melting point and the low temperature phase transition were measured and found to be inextricably dependant on the degree of confinement. The amount of solvent was varied through two sets of experiments, sequential addition and original progressive evaporation allowing the measurement of DSC signals for the various transitions as a function of the amount of CCl4. These experiments allowed the determination of the transition enthalpies in the confined state, which in turn allowed the determination of the exact quantities of solvent undergoing these transitions. A clear correlation was found between the amounts of solvent (both free and confined) undergoing the two transitions, demonstrating that the formation of the adsorbed layer t does not interfere with the second transition. The thickness of this layer and the porous volumes of the two silica samples were measured and found to be in very close agreement with the values determined by gas sorption.

  9. Dimensional reduction in Bose-Einstein condensed clouds of atoms confined in tight potentials of any geometry and any interaction strength

    NASA Astrophysics Data System (ADS)

    Sandin, P.; Ögren, M.; Gulliksson, M.; Smyrnakis, J.; Magiropoulos, M.; Kavoulakis, G. M.

    2017-01-01

    Motivated by numerous experiments on Bose-Einstein condensed atoms which have been performed in tight trapping potentials of various geometries [elongated and/or toroidal (annular)], we develop a general method which allows us to reduce the corresponding three-dimensional Gross-Pitaevskii equation for the order parameter into an effectively one-dimensional equation, taking into account the interactions (i.e., treating the width of the transverse profile variationally) and the curvature of the trapping potential. As an application of our model we consider atoms which rotate in a toroidal trapping potential. We evaluate the state of lowest energy for a fixed value of the angular momentum within various approximations of the effectively one-dimensional model and compare our results with the full solution of the three-dimensional problem, thus getting evidence for the accuracy of our model.

  10. Dynamical density functional theory with hydrodynamic interactions in confined geometries

    NASA Astrophysics Data System (ADS)

    Goddard, B. D.; Nold, A.; Kalliadasis, S.

    2016-12-01

    We study the dynamics of colloidal fluids in both unconfined geometries and when confined by a hard wall. Under minimal assumptions, we derive a dynamical density functional theory (DDFT) which includes hydrodynamic interactions (HI; bath-mediated forces). By using an efficient numerical scheme based on pseudospectral methods for integro-differential equations, we demonstrate its excellent agreement with the full underlying Langevin equations for systems of hard disks in partial confinement. We further use the derived DDFT formalism to elucidate the crucial effects of HI in confined systems.

  11. Schwinger effect and entanglement entropy in confining geometries

    NASA Astrophysics Data System (ADS)

    Ghodrati, Mahdis

    2015-09-01

    By using AdS /CFT , we study the critical electric field, the Schwinger pair creation rate and the potential phase diagram for the quark and antiquark in four confining supergravity backgrounds which are the Witten QCD (WQCD), the Maldacena-Nunez (MN), the Klebanov-Tseytlin (KT) and the Klebanov-Strassler (KS) models. We compare the rate of phase transition in these models and compare it also with the conformal case. We then present the phase diagrams of the entanglement entropy of a strip in these geometries and find the predicted butterfly shape in the diagrams. We found that the phase transitions have a higher rate in WQCD and KT relative to MN and KS. Finally we show the effect of turning on an additional magnetic field on the rate of pair creation by using the imaginary part of the Euler-Heisenberg effective Lagrangian. The result is increasing the parallel magnetic field would increase the pair creation rate and increasing the perpendicular magnetic field would decrease the rate.

  12. Diffusion of finite-size particles in confined geometries.

    PubMed

    Bruna, Maria; Chapman, S Jonathan

    2014-04-01

    The diffusion of finite-size hard-core interacting particles in two- or three-dimensional confined domains is considered in the limit that the confinement dimensions become comparable to the particle's dimensions. The result is a nonlinear diffusion equation for the one-particle probability density function, with an overall collective diffusion that depends on both the excluded-volume and the narrow confinement. By including both these effects, the equation is able to interpolate between severe confinement (for example, single-file diffusion) and unconfined diffusion. Numerical solutions of both the effective nonlinear diffusion equation and the stochastic particle system are presented and compared. As an application, the case of diffusion under a ratchet potential is considered, and the change in transport properties due to excluded-volume and confinement effects is examined.

  13. Multiple patterns of diblock copolymer confined in irregular geometries with soft surface

    NASA Astrophysics Data System (ADS)

    Li, Ying; Sun, Min-Na; Zhang, Jin-Jun; Pan, Jun-Xing; Guo, Yu-Qi; Wang, Bao-Feng; Wu, Hai-Shun

    2015-12-01

    The different confinement shapes can induce the formation of various interesting and novel morphologies, which might inspire potential applications of materials. In this paper, we study the directed self-assembly of diblock copolymer confined in irregular geometries with a soft surface by using self-consistent field theory. Two types of confinement geometries are considered, namely, one is the concave pore with one groove and the other is the concave pore with two grooves. We obtain more novel and different structures which could not be produced in other two-dimensional (2D) confinements. Comparing these new structures with those obtained in regular square confinement, we find that the range of ordered lamellae is enlarged and the range of disordered structure is narrowed down under the concave pore confinement. We also compare the different structures obtained under the two types of confinement geometries, the results show that the effect of confinement would increase, which might induce the diblock copolymer to form novel structures. We construct the phase diagram as a function of the fraction of B block and the ratio of h/L of the groove. The simulation reveals that the wetting effect of brushes and the shape of confinement geometries play important roles in determining the morphologies of the system. Our results improve the applications in the directed self-assembly of diblock copolymer for fabricating the irregular structures. Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20121404110004), the Research Foundation for Excellent Talents of Shanxi Provincial Department of Human Resources and Social Security, China, and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province, China.

  14. Confinement-dependent localization of diffusing aggregates in cellular geometries.

    PubMed

    Keramati, Mahdi Rezaei; Wasnik, Vaihbav; Ping, Liyan; Das, Dibyendu; Emberly, Eldon

    2015-01-01

    Confinement has a strong influence on diffusing nano-sized clusters. In particular, biomolecular aggregates within the shell-like confining space of a bacterial cell have been shown to display a variety of localization patterns, from being midcell to the poles. How does the confining space determine where the aggregate will localize? Here, using Monte Carlo simulations we have calculated the equilibrium spatial distribution of fixed-sized clusters diffusing in spherocylindrical shells. We find that localization to the poles depends strongly on shell thickness and the size of the cluster. Compared to being at midcell, polar clusters can be more bent and hence have higher energy, but they also can have a greater number of defects and hence have more entropy. Under certain conditions this can lead to polar clusters having a lower free energy than at midcell, favoring localization to the poles. Our findings suggest possible localization selection mechanisms within shell-like geometries that can arise purely from cluster confinement.

  15. Adsorbed molecules in external fields: Effect of confining potential

    NASA Astrophysics Data System (ADS)

    Tyagi, Ashish; Silotia, Poonam; Maan, Anjali; Prasad, Vinod

    2016-12-01

    We study the rotational excitation of a molecule adsorbed on a surface. As is well known the interaction potential between the surface and the molecule can be modeled in number of ways, depending on the molecular structure and the geometry under which the molecule is being adsorbed by the surface. We explore the effect of change of confining potential on the excitation, which is largely controlled by the static electric fields and continuous wave laser fields. We focus on dipolar molecules and hence we restrict ourselves to the first order interaction in field-molecule interaction potential either through permanent dipole moment or/and the molecular polarizability parameter. It is shown that confining potential shapes, strength of the confinement, strongly affect the excitation. We compare our results for different confining potentials.

  16. Adsorbed molecules in external fields: Effect of confining potential.

    PubMed

    Tyagi, Ashish; Silotia, Poonam; Maan, Anjali; Prasad, Vinod

    2016-12-05

    We study the rotational excitation of a molecule adsorbed on a surface. As is well known the interaction potential between the surface and the molecule can be modeled in number of ways, depending on the molecular structure and the geometry under which the molecule is being adsorbed by the surface. We explore the effect of change of confining potential on the excitation, which is largely controlled by the static electric fields and continuous wave laser fields. We focus on dipolar molecules and hence we restrict ourselves to the first order interaction in field-molecule interaction potential either through permanent dipole moment or/and the molecular polarizability parameter. It is shown that confining potential shapes, strength of the confinement, strongly affect the excitation. We compare our results for different confining potentials.

  17. A molecular dynamics study of freezing in a confined geometry

    NASA Technical Reports Server (NTRS)

    Ma, Wen-Jong; Banavar, Jayanth R.; Koplik, Joel

    1992-01-01

    The dynamics of freezing of a Lennard-Jones liquid in narrow channels bounded by molecular walls is studied by computer simulation. The time development of ordering is quantified and a novel freezing mechanism is observed. The liquid forms layers and subsequent in-plane ordering within a layer is accompanied by a sharpening of the layer in the transverse direction. The effects of channel size, the methods of quench, the liquid-wall interaction and the roughness of walls on the freezing mechanism are elucidated. Comparison with recent experiments on freezing in confined geometries is presented.

  18. Binding of two helium atoms in confined geometries

    SciTech Connect

    Kilic, S. |; Krotscheck, E.; Zillich, R.

    1999-08-01

    The authors carry out a comprehensive study of the binding of two helium atoms in unrestricted and, in particular, in restricted geometries in both two and three dimensions. Besides the well known binding of the {sup 4}He dimer in unrestricted geometry in two and three dimensions, the authors also find weakly bound states of the {sup 3}He-{sup 4}He molecule and the {sup 3}He dimer in 2 dimensions. Furthermore, any combination of two {sup 4}He or {sup 3}He atoms can form a molecule if their motion is sufficiently confined. The calculations are carried out by numerically solving the Schroedinger equation as well as by constructing a suitable variational wave function.

  19. Crystallization features of normal alkanes in confined geometry.

    PubMed

    Su, Yunlan; Liu, Guoming; Xie, Baoquan; Fu, Dongsheng; Wang, Dujin

    2014-01-21

    How polymers crystallize can greatly affect their thermal and mechanical properties, which influence the practical applications of these materials. Polymeric materials, such as block copolymers, graft polymers, and polymer blends, have complex molecular structures. Due to the multiple hierarchical structures and different size domains in polymer systems, confined hard environments for polymer crystallization exist widely in these materials. The confined geometry is closely related to both the phase metastability and lifetime of polymer. This affects the phase miscibility, microphase separation, and crystallization behaviors and determines both the performance of polymer materials and how easily these materials can be processed. Furthermore, the size effect of metastable states needs to be clarified in polymers. However, scientists find it difficult to propose a quantitative formula to describe the transition dynamics of metastable states in these complex systems. Normal alkanes [CnH2n+2, n-alkanes], especially linear saturated hydrocarbons, can provide a well-defined model system for studying the complex crystallization behaviors of polymer materials, surfactants, and lipids. Therefore, a deeper investigation of normal alkane phase behavior in confinement will help scientists to understand the crystalline phase transition and ultimate properties of many polymeric materials, especially polyolefins. In this Account, we provide an in-depth look at the research concerning the confined crystallization behavior of n-alkanes and binary mixtures in microcapsules by our laboratory and others. Since 2006, our group has developed a technique for synthesizing nearly monodispersed n-alkane containing microcapsules with controllable size and surface porous morphology. We applied an in situ polymerization method, using melamine-formaldehyde resin as shell material and nonionic surfactants as emulsifiers. The solid shell of microcapsules can provide a stable three-dimensional (3-D

  20. Universal properties of branching random walks in confined geometries

    NASA Astrophysics Data System (ADS)

    de Mulatier, C.; Mazzolo, A.; Zoia, A.

    2014-08-01

    Characterizing the occupation statistics of random walks through confined geometries amounts to assessing the distribution of the travelled length ℓ and the number of collisions n performed by the stochastic process in a given region, for which remarkably simple Cauchy-like formulas were established in the case of branching Pearson random walks with exponentially distributed jumps. In this letter, we derive two key results: first, we show that such formulas strikingly carry over to the much broader class of branching processes with arbitrary jumps, and have thus a universal character; second, we obtain a stronger version of these formulas relating the travelled length density and the collision density at any point of the phase space. Our results are key to such technological issues as the analysis of radiation flow for nuclear reactor design and medical diagnosis and apply more broadly to physical and biological systems with diffusion, reproduction and death.

  1. Confining potential in momentum space

    NASA Technical Reports Server (NTRS)

    Norbury, John W.; Kahana, David E.; Maung, Khin Maung

    1992-01-01

    A method is presented for the solution in momentum space of the bound state problem with a linear potential in r space. The potential is unbounded at large r leading to a singularity at small q. The singularity is integrable, when regulated by exponentially screening the r-space potential, and is removed by a subtraction technique. The limit of zero screening is taken analytically, and the numerical solution of the subtracted integral equation gives eigenvalues and wave functions in good agreement with position space calculations.

  2. Yukawa particles in a confining potential

    SciTech Connect

    Girotto, Matheus Levin, Yan; Santos, Alexandre P. dos; Colla, Thiago

    2014-07-07

    We study the density distribution of repulsive Yukawa particles confined by an external potential. In the weak coupling limit, we show that the mean-field theory is able to accurately account for the particle distribution. In the strong coupling limit, the correlations between the particles become important and the mean-field theory fails. For strongly correlated systems, we construct a density functional theory which provides an excellent description of the particle distribution, without any adjustable parameters.

  3. Electron Confinement in Cylindrical Potential Well

    NASA Astrophysics Data System (ADS)

    Baltenkov, A. S.; Msezane, A. Z.

    2016-05-01

    We show that studying the solutions of the wave equation for an electron confined in a cylindrical potential well offers the possibility to analyze the confinement behavior of an electron executing one- or two-dimensional motion in the remaining three-dimensional space within the framework of the same mathematical model of the potential well. Some low-lying electronic states with different symmetries are considered and the corresponding wave functions are calculated. The behavior of their nodes and their peak positions with respect to the parameters of the cylindrical well is analyzed. Additionally, the momentum distributions of electrons in these states are calculated. The limiting cases of the ratio of the cylinder length H to its radius R0 are considered; when H significantly exceeds R0 and when R0 is much greater than H. The possible application of the results obtained here for the description of the general features in the behavior of electrons in nanowires with metallic type of conductivity (or nanotubes) and ultrathin epitaxial films (or graphene sheets) are discussed. Possible experiments are suggested as well where the quantum confinement can be manifested. Work supported by the Uzbek Foundation (ASB) and by the U.S. DOE, Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences, Office of Energy Research (AZM).

  4. Polymer escape from a confining potential

    SciTech Connect

    Mökkönen, Harri; Ikonen, Timo; Jónsson, Hannes; Ala-Nissila, Tapio

    2014-02-07

    The rate of escape of polymers from a two-dimensionally confining potential well has been evaluated using self-avoiding as well as ideal chain representations of varying length, up to 80 beads. Long timescale Langevin trajectories were calculated using the path integral hyperdynamics method to evaluate the escape rate. A minimum is found in the rate for self-avoiding polymers of intermediate length while the escape rate decreases monotonically with polymer length for ideal polymers. The increase in the rate for long, self-avoiding polymers is ascribed to crowding in the potential well which reduces the free energy escape barrier. An effective potential curve obtained using the centroid as an independent variable was evaluated by thermodynamic averaging and Kramers rate theory then applied to estimate the escape rate. While the qualitative features are well reproduced by this approach, it significantly overestimates the rate, especially for the longer polymers. The reason for this is illustrated by constructing a two-dimensional effective energy surface using the radius of gyration as well as the centroid as controlled variables. This shows that the description of a transition state dividing surface using only the centroid fails to confine the system to the region corresponding to the free energy barrier and this problem becomes more pronounced the longer the polymer is. A proper definition of a transition state for polymer escape needs to take into account the shape as well as the location of the polymer.

  5. Spin probe dynamics of n-hexadecane in confined geometry

    NASA Astrophysics Data System (ADS)

    Lukešová, Miroslava; Švajdlenková, Helena; Sippel, Pit; Macová, Eva; Berek, Dušan; Loidl, Alois; Bartoš, Josef

    2015-02-01

    A combined study of the rotational dynamics of the stable free radical 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) and the phase behavior of n-hexadecane (n-HXD) in the bulk and the confined states in a series of silica gels (SG) by means of ESR and DSC is presented. A slow to fast motion transition of the spin probe TEMPO in the bulk n-HXD occurs at T50 G,bulk ≪ Tm,bulk, i.e., well below the melting temperature due to its trapping and localized mobility in the interlamellar gap of the crystallites [J. Bartoš, H. Švajdlenková, M. Zaleski, M. Edelmann, M. Lukešová, Physica B 430, 99 (2013)]. On the other hand, the dynamics of the TEMPO in the confined systems is strongly slowing down with T50 G (Dpore) >Tm(Dpore) and slightly increases with the pore size Dpore = 60, 100 and 300 Å of the SG's. At the same time, both the corresponding melting temperature, Tm (Dpore), and melting enthalpy, ΔHm (Dpore), decrease with Dpore together with the mutual anti-correlation between T50 G and Tm as a function of the inverse of pore diameter, 1/Dpore. Moreover, the dynamic heterogeneity of the TEMPO in the confined state below T50 G (Dpore) is closely related to the phase transformation. The strong slowing down of the spin probe motion likely results from its preferential localization at the interface layer of the matrix pore due to specific interaction of TEMPO molecules with the polar silanol groups of the SG matrix. This is supported by special study on a series of the variously filled n-HXD/SG systems, other similar experimental findings as well as by theoretical spectral argument.

  6. Deformable cells in confined geometries: From hemolysis to hydrodynamic interactions

    NASA Astrophysics Data System (ADS)

    Abkarian, Manouk; Faivre, Magalie; Stone, Howard A.

    2004-11-01

    Recent developments in microfluidics allow a wide range of possibilities for studying cellular-scale hydrodynamics. Here we use microfluidic technology to address several open questions in the blood flow literature where cell deformation and hydrodynamic interactions are significant. In particular, we investigate the pressure-driven flow of a dilute suspension in a channel and characterize the transition from steady axisymmetric cell shapes (for which numerical calculations exist) to asymmetric, highly extended shapes, which are precursors to hemolysis (i.e. destruction of the cell). In addition, we examine the influence of geometry on hydrodynamic interactions of deformable cells by contrasting one-dimensional motion of a train of particles in a channel with two-dimensional motions in a Hele-Shaw cell. This study can help to understand flow of cells in microcirculation from the unidirectional flow in capillaries to the two-dimensional flow in the lung alveoli and provides the basic steps to understand certain aspects of microcirculatory deseases like sickle cell anemia for example.

  7. Modeling cavities exhibiting strong lateral confinement using open geometry Fourier modal method

    NASA Astrophysics Data System (ADS)

    Häyrynen, Teppo; Gregersen, Niels

    2016-04-01

    We have developed a computationally efficient Fourier-Bessel expansion based open geometry formalism for modeling the optical properties of rotationally symmetric photonic nanostructures. The lateral computation domain is assumed infinite so that no artificial boundary conditions are needed. Instead, the leakage of the modes due to an imperfect field confinement is taken into account by using a basis functions that expand the whole infinite space. The computational efficiency is obtained by using a non-uniform discretization in the frequency space in which the lateral expansion modes are more densely sampled around a geometry specific dominant transverse wavenumber region. We will use the developed approach to investigate the Q factor and mode confinement in cavities where top DBR mirror has small rectangular defect confining the modes laterally on the defect region.

  8. Analytical trajectories of skyrmions in confined geometries: Skyrmionic racetracks and nano-oscillators

    NASA Astrophysics Data System (ADS)

    Navau, Carles; Del-Valle, Nuria; Sanchez, Alvaro

    2016-11-01

    Magnetic skyrmions are candidates for a new generation of information carriers due to their nanometric size and topologically protected stability. The study of the dynamics of such skyrmions in racetrack geometries and, in general, in confined geometries becomes essential to achieve these goals. Here we present analytical expressions for the trajectories of skyrmions in confined geometries (including long tracks and squared samples) when driven by polarized electric currents. The force exerted by the borders is derived as a function of the material parameters (anisotropy, Dzyaloshinskii-Moriya, and exchange constants) and incorporated in the equation of motion of the skyrmions. We find the general expressions for the trajectories in several possible scenarios, and we also find simple expressions for the stationary position, the velocity, as well as for the threshold velocity of the driving electrons that could overcome the edge repulsion. In fully confined geometries, the geometric edges can produce a naturally oscillating movement, allowing for dynamical resonances if the driving current is an ac current with adequate frequency. Numerical micromagnetic simulations considering typical experimental parameters are used to corroborate the theory.

  9. Observation of the self-organized vortex structures in confined flow with various geometries

    NASA Astrophysics Data System (ADS)

    Naumov, Igor V.; Podolskaya, Irina Yu.; Tsoy, Michael A.

    2016-10-01

    The vortex breakdown bubble in confined flow generated by a rotating lid in a closed container with different cross-section geometry has been analyzed experimentally for the case with the height/radius aspect ratio h = 2 and numerically for different aspect ratios. The stagnation point locations of the breakdown bubble emergence and corresponding Reynolds number were determined experimentally and numerically by STAR-CCM+ CFD software for square, pentagonal, hexagonal and octagonal cross-section configurations. The flow pattern and velocity were observed and measured combining the seeding particle visualization and Laser Doppler Anemometry (LDA). The vortex breakdown size and position on the container axis were identified for Reynolds numbers ranging from 1450 to 2400. The obtained results were compared with flow structure in closed cylindrical container. Numerical results shown good agreement with experiment and have allowed to reveal regularities of formation of a vortex breakdown bubble depending on Re and cross-section geometry of confined container.

  10. Ring polymer chains confined in a slit geometry of two parallel walls: the massive field theory approach

    NASA Astrophysics Data System (ADS)

    Usatenko, Z.; Halun, J.

    2017-01-01

    The investigation of a dilute solution of phantom ideal ring polymer chains confined in a slit geometry of two parallel repulsive walls, two inert walls, and for the mixed case of one inert and the other one repulsive wall, was performed. Taking into account the well known correspondence between the field theoretical {φ4} O(n)-vector model in the limit n\\to 0 and the behaviour of long-flexible polymer chains in a good solvent, the investigation of a dilute solution of long-flexible ring polymer chains with the excluded volume interaction (EVI) confined in a slit geometry of two parallel repulsive walls was performed in the framework of the massive field theory approach at fixed space dimensions d  =  3 up to one-loop order. For all the above mentioned cases, the correspondent depletion interaction potentials, the depletion forces and the forces which exert the phantom ideal ring polymers and the ring polymers with the EVI on the walls were calculated, respectively. The obtained results indicate that the phantom ideal ring polymer chains and the ring polymer chains with the EVI due to the complexity of chain topology and because of the entropical reason demonstrate completely different behaviour in confined geometries than linear polymer chains. For example, the phantom ideal ring polymers prefer to escape from the space not only between two repulsive walls but also in the case of two inert walls, which leads to the attractive depletion forces. The ring polymer chains with less complex knot types (with the bigger radius of gyration) in a ring topology in the wide slit region exert higher forces on the confining repulsive walls. The depletion force in the case of mixed boundary conditions becomes repulsive in contrast to the case of linear polymer chains.

  11. Preparation of nanocrystals and nanocomposites of nanocrystal-conjugated polymer, and their photophysical properties in confined geometries

    SciTech Connect

    Xu, Jun

    2007-01-01

    Semiconductors nanocrystals (NCs), also called quantum dots (QDs), have attracted tremendous interest over the past decade in the fields of physics, chemistry, and engineering. Due to the quantum-confined nature of QDs, the variation of particle size provides continuous and predictable changes in fluorescence emission. On the other hand, conjugated polymers (CPs) have been extensively studied for two decades due to their semiconductor-like optical and electronic properties. The electron and energy transfer between NCs and CPs occur in solar cells and light emitting diodes (LEDs), respectively. Placing CPs in direct contact with a NC (i.e., preparing NC-CP nanocomposites) carries advantage over cases where NC aggregation dominates. Such NC-CP nanocomposites possess a well-defined interface that significantly promotes the charge or energy transfer between these two components. However, very few studies have centered on such direct integration. We prepared NCs and NC-CP nanocomposites based on heck coupling and investigated the energy and charge transfer between semiconductor NCs (i.e., CdSe QDs), CPs (i.e., poly(3-hexyl thiophene) (P3HT)) in the nanocomposites in confined geometries. Two novel strategies were used to confine NC and/or NC-CP nanocomposites: (a) directly immobilizing nanohybrids, QDs and nanorods in nanoscopic porous alumina membrane (PAM) , and (b) confining the QDs and CPs in sphere-on-flat geometry to induce self-assembly. While investigating the confinement effect, gradient concentric ring patterns of high regularity form spontaneously simply by allowing a droplet of solution containing either conjugated polymer or semiconductor nanocrystal in a consecutive stick-slip mothion in a confined geometry. Such constrained evaporation can be utilized as a simple, cheap, and robust strategy for self-assembling various materials with easily tailored optical and electronic properties into spatially ordered, two-dimensional patterns. These self

  12. Preparation of nanocrystals and nanocomposites of nanocrystal-conjugated polymer, and their photophysical properties in confined geometries

    NASA Astrophysics Data System (ADS)

    Xu, Jun

    Semiconductors nanocrystals (NCs), also called quantum dots (QDs), have attracted tremendous interest over the past decade in the fields of physics, chemistry, and engineering. Due to the quantum-confined nature of QDs, the variation of particle size provides continuous and predictable changes in fluorescence emission. On the other hand, conjugated polymers (CPs) have been extensively studied for two decades due to their semiconductor-like optical and electronic properties. The electron and energy transfer between NCs and CPs occur in solar cells and light emitting diodes (LEDs), respectively. Placing CPs in direct contact with a NC (i.e., preparing NC-CP nanocomposites) carries advantage over cases where NC aggregation dominates. Such NC-CP nanocomposites possess a well-defined interface that significantly promotes the charge or energy transfer between these two components. However, very few studies have centered on such direct integration. We prepared NCs and NC-CP nanocomposites based on heck coupling and investigated the energy and charge transfer between semiconductor NCs (i.e., CdSe QDs), CPs (i.e., poly(3-hexyl thiophene) (P3HT)) in the nanocomposites in confined geometries. Two novel strategies were used to confine NC and/or NC-CP nanocomposites: (a) directly immobilizing nanohybrids, QDs and nanorods in nanoscopic porous alumina membrane (PAM), and (b) confining the QDs and CPs in sphere-on-flat geometry to induce self-assembly. While investigating the confinement effect, gradient concentric ring patterns of high regularity form spontaneously simply by allowing a droplet of solution containing either conjugated polymer or semiconductor nanocrystal in a consecutive stick-slip motion in a confined geometry. Such constrained evaporation can be utilized as a simple, cheap, and robust strategy for self-assembling various materials with easily tailored optical and electronic properties into spatially ordered, two-dimensional patterns. These self

  13. Infrared Thermography Investigation of an Evaporating Water/Oil Meniscus in Confined Geometry.

    PubMed

    Liu, Xiang; Huang, Lu; Guo, Dan; Xie, Guoxin

    2017-01-10

    To simulate the heat and mass transfer in real heterogeneous systems, such as metal-production processes and lubrication, the point-contact condition with the formation of narrowly confined liquid film and its surrounding meniscus was constructed to study the classical microchannel boiling problem in this work. Specifically, the evaporation and diffusion of the superheated water meniscus and water/oil droplet in the point-contact geometry were investigated. The emphasis is put on the influence of the contact-line transport behaviors on nucleation and bubble dynamics in the confined meniscus. The observations suggested that superheat is the necessary condition for bubble formation, and enough vapor supply is the necessary condition for bubble growth in the confined liquid. The oil film could significantly inhibit the evaporation and diffusion of water molecules in the superheat geometry. The water/oil droplet can exist for a long time even in the hot contact region, which could have sustained damages to the mechanical system suffering from water pollution. This work is of great significance to better understand the damage mechanism of water pollution to the mechanical system.

  14. Lattice-Boltzmann simulations of the dynamics of polymer solutions in periodic and confined geometries

    NASA Astrophysics Data System (ADS)

    Berk Usta, O.; Ladd, Anthony J. C.; Butler, Jason E.

    2005-03-01

    A numerical method to simulate the dynamics of polymer solutions in confined geometries has been implemented and tested. The method combines a fluctuating lattice-Boltzmann model of the solvent [Ladd, Phys. Rev. Lett. 70, 1339 (1993)] with a point-particle model of the polymer chains. A friction term couples the monomers to the fluid [Ahlrichs and Dünweg, J. Chem. Phys. 111, 8225 (1999)], providing both the hydrodynamic interactions between the monomers and the correlated random forces. The coupled equations for particles and fluid are solved on an inertial time scale, which proves to be surprisingly simple and efficient, avoiding the costly linear algebra associated with Brownian dynamics. Complex confined geometries can be represented by a straightforward mapping of the boundary surfaces onto a regular three-dimensional grid. The hydrodynamic interactions between monomers are shown to compare well with solutions of the Stokes equations down to distances of the order of the grid spacing. Numerical results are presented for the radius of gyration, end-to-end distance, and diffusion coefficient of an isolated polymer chain, ranging from 16 to 1024 monomers in length. The simulations are in excellent agreement with renormalization group calculations for an excluded volume chain. We show that hydrodynamic interactions in large polymers can be systematically coarse-grained to substantially reduce the computational cost of the simulation. Finally, we examine the effects of confinement and flow on the polymer distribution and diffusion constant in a narrow channel. Our results support the qualitative conclusions of recent Brownian dynamics simulations of confined polymers [Jendrejack et al., J. Chem. Phys. 119, 1165 (2003) and Jendrejack et al., J. Chem. Phys. 120, 2513 (2004)].

  15. Hierarchical Self-Assembly of Cellulose Nanocrystals in a Confined Geometry

    PubMed Central

    2016-01-01

    Complex hierarchical architectures are ubiquitous in nature. By designing and controlling the interaction between elementary building blocks, nature is able to optimize a large variety of materials with multiple functionalities. Such control is, however, extremely challenging in man-made materials, due to the difficulties in controlling their interaction at different length scales simultaneously. Here, hierarchical cholesteric architectures are obtained by the self-assembly of cellulose nanocrystals within shrinking, micron-sized aqueous droplets. This confined, spherical geometry drastically affects the colloidal self-assembly process, resulting in concentric ordering within the droplet, as confirmed by simulation. This provides a quantitative tool to study the interactions of cellulose nanocrystals beyond what has been achieved in a planar geometry. Our developed methodology allows us to fabricate truly hierarchical solid-state architectures from the nanometer to the macroscopic scale using a renewable and sustainable biopolymer. PMID:27564644

  16. Degeneracies and fluctuations of Néel skyrmions in confined geometries

    NASA Astrophysics Data System (ADS)

    Keesman, Rick; Leonov, A. O.; van Dieten, P.; Buhrandt, Stefan; Barkema, G. T.; Fritz, Lars; Duine, R. A.

    2015-10-01

    The recent discovery of tunable Dzyaloshinskii-Moriya interactions in layered magnetic materials with perpendicular magnetic anisotropy makes them promising candidates for stabilization and manipulation of skyrmions at elevated temperatures. In this article, we use Monte Carlo simulations to investigate the robustness of skyrmions in these materials against thermal fluctuations and finite-size effects. We find that in confined geometries and at finite temperatures skyrmions are present in a large part of the phase diagram. Moreover, we find that the confined geometry favors the skyrmion over the spiral phase when compared to infinitely large systems. Upon tuning the magnetic field through the skyrmion phase, the system undergoes a cascade of transitions in the magnetic structure through states of different number of skyrmions, elongated and half-skyrmions, and spiral states. We consider how quantum and thermal fluctuations lift the degeneracies that occur at these transitions, and find that states with more skyrmions are typically favored by fluctuations over states with less skyrmions. Finally, we comment on electrical detection of the various phases through the topological and anomalous Hall effects.

  17. Advancing Edge Speeds of Epithelial Monolayers Depend on Their Initial Confining Geometry

    PubMed Central

    Kollimada, Somanna A.; Kulkarni, Ankur H.; Ravan, Aniket; Gundiah, Namrata

    2016-01-01

    Collective cell migrations are essential in several physiological processes and are driven by both chemical and mechanical cues. The roles of substrate stiffness and confinement on collective migrations have been investigated in recent years, however few studies have addressed how geometric shapes influence collective cell migrations. Here, we address the hypothesis that the relative position of a cell within the confinement influences its motility. Monolayers of two types of epithelial cells—MCF7, a breast epithelial cancer cell line, and MDCK, a control epithelial cell line—were confined within circular, square, and cross-shaped stencils and their migration velocities were quantified upon release of the constraint using particle image velocimetry. The choice of stencil geometry allowed us to investigate individual cell motility within convex, straight and concave boundaries. Cells located in sharp, convex boundaries migrated at slower rates than those in concave or straight edges in both cell types. The overall cluster migration occurred in three phases: an initial linear increase with time, followed by a plateau region and a subsequent decrease in cluster speeds. An acto-myosin contractile ring, present in the MDCK but absent in MCF7 monolayer, was a prominent feature in the emergence of leader cells from the MDCK clusters which occurred every ~125 μm from the vertex of the cross. Further, coordinated cell movements displayed vorticity patterns in MDCK which were absent in MCF7 clusters. We also used cytoskeletal inhibitors to show the importance of acto-myosin bounding cables in collective migrations through translation of local movements to create long range coordinated movements and the creation of leader cells within ensembles. To our knowledge, this is the first demonstration of how bounding shapes influence long-term migratory behaviours of epithelial cell monolayers. These results are important for tissue engineering and may also enhance our

  18. Advancing Edge Speeds of Epithelial Monolayers Depend on Their Initial Confining Geometry.

    PubMed

    Kollimada, Somanna A; Kulkarni, Ankur H; Ravan, Aniket; Gundiah, Namrata

    2016-01-01

    Collective cell migrations are essential in several physiological processes and are driven by both chemical and mechanical cues. The roles of substrate stiffness and confinement on collective migrations have been investigated in recent years, however few studies have addressed how geometric shapes influence collective cell migrations. Here, we address the hypothesis that the relative position of a cell within the confinement influences its motility. Monolayers of two types of epithelial cells--MCF7, a breast epithelial cancer cell line, and MDCK, a control epithelial cell line--were confined within circular, square, and cross-shaped stencils and their migration velocities were quantified upon release of the constraint using particle image velocimetry. The choice of stencil geometry allowed us to investigate individual cell motility within convex, straight and concave boundaries. Cells located in sharp, convex boundaries migrated at slower rates than those in concave or straight edges in both cell types. The overall cluster migration occurred in three phases: an initial linear increase with time, followed by a plateau region and a subsequent decrease in cluster speeds. An acto-myosin contractile ring, present in the MDCK but absent in MCF7 monolayer, was a prominent feature in the emergence of leader cells from the MDCK clusters which occurred every ~125 μm from the vertex of the cross. Further, coordinated cell movements displayed vorticity patterns in MDCK which were absent in MCF7 clusters. We also used cytoskeletal inhibitors to show the importance of acto-myosin bounding cables in collective migrations through translation of local movements to create long range coordinated movements and the creation of leader cells within ensembles. To our knowledge, this is the first demonstration of how bounding shapes influence long-term migratory behaviours of epithelial cell monolayers. These results are important for tissue engineering and may also enhance our

  19. Controlled evaporative self-assembly of poly(acrylic acid) in a confined geometry for fabricating patterned polymer brushes.

    PubMed

    Men, Yonghong; Xiao, Peng; Chen, Jing; Fu, Jun; Huang, Youju; Zhang, Jiawei; Xie, Zhengchao; Wang, Wenqin; Chen, Tao

    2014-04-29

    A simple yet robust approach was exploited to fabricate large-scaled patterned polymer brushes by combining controlled evaporative self-assembly (CESA) in a confined geometry and self-initiated photografting and photopolymerization (SIPGP). Our method was carried out without any sophisticated instruments, free of lithography, overcoming current difficulties in fabricating polymer patterns by using complex instruments.

  20. Effects of self-heating and phase change on the thermal profile of hydrogen isotopes in confined geometries

    SciTech Connect

    Baxamusa, S. Field, J.; Dylla-Spears, R.; Kozioziemski, B.; Suratwala, T.; Sater, J.

    2014-03-28

    Growth of high-quality single-crystal hydrogen in confined geometries relies on the in situ formation of seed crystals. Generation of deuterium-tritium seed crystals in a confined geometry is governed by three effects: self-heating due to tritium decay, external thermal environment, and latent heat of phase change at the boundary between hydrogen liquid and vapor. A detailed computation of the temperature profile for liquid hydrogen inside a hollow shell, as is found in inertial confinement fusion research, shows that seeds are likely to form at the equatorial plane of the shell. Radioactive decay of tritium to helium slowly alters the composition of the hydrogen vapor, resulting in a modified temperature profile that encourages seed formation at the top of the shell. We show that the computed temperature profile is consistent with a variety of experimental observations.

  1. Phase transitions of amorphous solid acetone in confined geometry investigated by reflection absorption infrared spectroscopy.

    PubMed

    Shin, Sunghwan; Kang, Hani; Kim, Jun Soo; Kang, Heon

    2014-11-26

    We investigated the phase transformations of amorphous solid acetone under confined geometry by preparing acetone films trapped in amorphous solid water (ASW) or CCl4. Reflection absorption infrared spectroscopy (RAIRS) and temperature-programmed desorption (TPD) were used to monitor the phase changes of the acetone sample with increasing temperature. An acetone film trapped in ASW shows an abrupt change in the RAIRS features of the acetone vibrational bands during heating from 80 to 100 K, which indicates the transformation of amorphous solid acetone to a molecularly aligned crystalline phase. Further heating of the sample to 140 K produces an isotropic solid phase, and eventually a fluid phase near 157 K, at which the acetone sample is probably trapped in a pressurized, superheated condition inside the ASW matrix. Inside a CCl4 matrix, amorphous solid acetone crystallizes into a different, isotropic structure at ca. 90 K. We propose that the molecularly aligned crystalline phase formed in ASW is created by heterogeneous nucleation at the acetone-water interface, with resultant crystal growth, whereas the isotropic crystalline phase in CCl4 is formed by homogeneous crystal growth starting from the bulk region of the acetone sample.

  2. Multipole electrodynamic ion trap geometries for microparticle confinement under standard ambient temperature and pressure conditions

    NASA Astrophysics Data System (ADS)

    Mihalcea, Bogdan M.; Giurgiu, Liviu C.; Stan, Cristina; Vişan, Gina T.; Ganciu, Mihai; Filinov, Vladimir; Lapitsky, Dmitry; Deputatova, Lidiya; Syrovatka, Roman

    2016-03-01

    Trapping of microparticles and aerosols is of great interest for physics and chemistry. We report microparticle trapping in case of multipole linear Paul trap geometries, operating under standard ambient temperature and pressure conditions. An 8- and 12-electrode linear trap geometries have been designed and tested with an aim to achieve trapping for larger number of particles and to study microparticle dynamical stability in electrodynamic fields. We report emergence of planar and volume ordered structures of microparticles, depending on the a.c. trapping frequency and particle specific charge ratio. The electric potential within the trap is mapped using the electrolytic tank method. Particle dynamics is simulated using a stochastic Langevin equation. We emphasize extended regions of stable trapping with respect to quadrupole traps, as well as good agreement between experiment and numerical simulations.

  3. Dynamic Fracture of Borosilicate Glass with Plasma Confinement geometry in Pure Water by Laser-induced Shock Wave

    NASA Astrophysics Data System (ADS)

    Saito, Fumikazu; Kishimura, Hiroaki; Suzuki, Takanori

    2013-06-01

    In order to characterize dynamic fracture of borosilicate glass, we performed laser-shock-experiments of both an aluminum-ablator mounted glass and a glass with plasma confinement geometry in pure water by Q-switched Nd3+:YAG laser. The incident beam with 440 mJ were focused onto the target approximately 300 μm in diameter. The dynamic fracture of the glass targets is observed with high-speed digital framing-camera photography. For the aluminum-ablator mounted glass, propagation of the shock wave in water was observed, and the shock-wave velocity is obtained to be 1.65 +/- 0.02 km/s using image processing. Shock-pressure applied the target is estimated to be 180 MPa by Hugoniot relation. For the glass with plasma confinement geometry, generation of the micro-fragments from the rear side of the target was observed. This result indicates that shock-induced fragmentation by laser irradiation is enhanced by the plasma confinement effect. The soft-recovered fragments are separated according the size with PET mesh having deferent mesh size. As a result, the glass with plasma confinement geometry generated smaller fragment than the aluminum-ablator mounted glass.

  4. Heavy quarks, gluons and the confinement potential in Coulomb gauge

    SciTech Connect

    Popovici, Carina; Watson, Peter; Reinhardt, Hugo

    2011-05-23

    We consider the heavy quark limit of Coulomb gauge QCD, with the truncation of the Yang-Mills sector to include only (dressed) two-point functions. We find that the rainbow-ladder approximation to the gap and Bethe-Salpeter equations is nonperturbatively exact and moreover, we provide a direct connection between the temporal gluon propagator and the quark confinement potential. Further, we show that only bound states of color singlet quark-antiquark (meson) and quark-quark (SU(2) baryon) pairs are physically allowed.

  5. Dynamics of a ±1/2 defect pair in a confined geometry: A thin hybrid aligned nematic cell

    NASA Astrophysics Data System (ADS)

    Lu, Li-Xia; Zhang, Zhi-Dong

    2015-02-01

    Confined geometry can change the defect structure and its properties. In this paper, we investigate numerically the dynamics of a dipole of ±1/2 parallel wedge disclination lines in a confined geometry: a thin hybrid aligned nematic (HAN) cell, based on the Landau-de Gennes theory. When the cell gap d is larger than a critical value of 12ξ (where ξ is the characteristic length for order-parameter change), the pair annihilates. A pure HAN configuration without defect is formed in an equilibrium state. In the confined geometry of d ≤ 12ξ, the diffusion process is discovered for the first time and an eigenvalue exchange configuration is formed in an equilibrium state. The eigenvalue exchange configuration is induced by different essential reasons. When 10ξ < d ≤ 12ξ, the two defects coalesce and annihilate. The biaxial wall is created by the inhomogeneous distortion of the director, which results in the eigenvalue exchange configuration. When d ≤ 10ξ, the defects do not collide and the eigenvalue exchange configuration originates from the biaxial seeds concentrated at the defects. Project supported by the National Natural Science Foundation of China (Grant No. 11374087) and the Key Subject Construction Project of Hebei Province University.

  6. States of the Dirac equation in confining potentials.

    PubMed

    Giachetti, Riccardo; Sorace, Emanuele

    2008-11-07

    We study the Dirac equation in confining potentials with pure vector coupling, proving the existence of metastable states with longer and longer lifetimes as the nonrelativistic limit is approached and eventually merging with continuity into the Schrödinger bound states. The existence of these states could concern high energy models and possible resonant scattering effects in systems like graphene. We present numerical results for the linear and the harmonic cases and we show that the density of the states of the continuous spectrum is well described by a sum of Breit-Wigner lines. The width of the line with lowest positive energy well reproduces the Schwinger pair production rate for a linear potential: this gives an explanation of the Klein paradox for bound states and a new concrete way to get information on pair production in unbounded, nonuniform electric fields, where very little is known.

  7. Potentials for Spatial Geometry Curriculum Development with Three-Dimensional Dynamic Geometry Software in Lower Secondary Mathematics

    ERIC Educational Resources Information Center

    Miyazaki, Mikio; Kimiho, Chino; Katoh, Ryuhei; Arai, Hitoshi; Ogihara, Fumihiro; Oguchi, Yuichi; Morozumi, Tatsuo; Kon, Mayuko; Komatsu, Kotaro

    2012-01-01

    Three-dimensional dynamic geometry software has the power to enhance students' learning of spatial geometry. The purpose of this research is to clarify what potential using three-dimensional dynamic geometry software can offer us in terms of how to develop the spatial geometry curriculum in lower secondary schools. By focusing on the impacts the…

  8. Spectral singularity in confined PT symmetric optical potential

    SciTech Connect

    Sinha, Anjana; Roychoudhury, R.

    2013-11-15

    We present an analytical study for the scattering amplitudes (Reflection ‖R‖ and Transmission ‖T‖), of the periodic PT symmetric optical potential V(x)=W{sub 0}cos{sup 2}x+iV{sub 0}sin2x confined within the region 0 ⩽x⩽L, embedded in a homogeneous medium having uniform potential W{sub 0}. The confining length L is considered to be some integral multiple of the period π. We give some new and interesting results. Scattering is observed to be normal (‖T‖{sup 2}⩽ 1, ‖R‖{sup 2}⩽ 1) for V{sub 0}⩽ 0.5, when the above potential can be mapped to a Hermitian potential by a similarity transformation. Beyond this point (V{sub 0} > 0.5) scattering is found to be anomalous (‖T‖{sup 2}, ‖R‖{sup 2} not necessarily ⩽1). Additionally, in this parameter regime of V{sub 0}, one observes infinite number of spectral singularities E{sub SS} at different values of V{sub 0}. Furthermore, for L= 2nπ, the transition point V{sub 0}= 0.5 shows unidirectional invisibility with zero reflection when the beam is incident from the absorptive side (Im[V(x)] < 0) but with finite reflection when the beam is incident from the emissive side (Im[V(x)] > 0), transmission being identically unity in both cases. Finally, the scattering coefficients ‖R‖{sup 2} and ‖T‖{sup 2} always obey the generalized unitarity relation : ‖T|{sup 2}−1|=√(|R{sub R}|{sup 2}|R{sub L}|{sup 2}), where subscripts R and L stand for right and left incidence, respectively.

  9. Specific heat of 4He confined to 9869 Å planar geometry

    NASA Astrophysics Data System (ADS)

    Kimball, Mark O.; Gasparini, Francis M.

    2000-07-01

    We report new data for 4He confined between two silicon wafers spaced 9869 Å apart. This spacing complements a series of previous measurements which now span a factor of 20 between the smallest and largest confinements. These new data allow us to further check scaling predictions. We find, as reported with previous data, that the present data scale well except near the heat capacity maximum, and below into the superfluid region.

  10. Protection from Potential Exposure for the Chernobyl New Safe Confinement

    SciTech Connect

    Shipler, Dillard B.; Rudko, Vladimir; Batiy, Valeriy; Timmins, Douglas C.; Brothers, Alan J.; Schmidt, John P.; Swearingen, Gary L.; Schmieman, Eric A.

    2004-03-24

    The Bechtel/EDF/Battelle Consortium has recently completed developing the conceptual design for the Chernobyl New Safe Confinement (NSC). Battelle has the scope of work related to environment and safety of the design. As part of the safety analysis, an analysis was performed to determine the degree of protection to be provided during the construction and 100-year operation period for expected upsets and lower-probability events that would occur from errors, procedures, other human factors, and equipment failures, i.e., ''potential exposures'' other than normal operations. The analysis was based on results of the Preliminary Hazards Analysis. The potential exposure analysis was performed in accordance with existing Ukranian regulations and working processes and procedures in place at the Shelter Object. KSK (a Ukranian Consortium), a subcontractor to the Bechtel/EDF/Battelle Consortium, performed much of the dose analysis. The analysis concluded that potential exposures, outside of those expected during normal operations, would be acceptable and that design criteria and features, and preventative and mitigative measures currently in place at the Shelter would be sufficient to meet operating exposure limits.

  11. An x-ray setup to investigate the atomic order of confined liquids in slit geometry

    SciTech Connect

    Lippmann, M.; Ehnes, A.; Seeck, O. H.

    2014-01-15

    A setup has been designed to investigate thin films of confined liquids with the use of X-ray scattering methods. The confinement is realized between the flat culets of a pair of diamonds by positioning and orienting the lower diamond with nanometer and micro radian accuracy. We routinely achieve gaps between 5 and 50 nm at culet diameters of 200 μm. With this setup and a micro focused X-ray beam we have investigated the in-plane and the out-off-plane atomic order of benzene with atomic resolution.

  12. An x-ray setup to investigate the atomic order of confined liquids in slit geometry.

    PubMed

    Lippmann, M; Ehnes, A; Seeck, O H

    2014-01-01

    A setup has been designed to investigate thin films of confined liquids with the use of X-ray scattering methods. The confinement is realized between the flat culets of a pair of diamonds by positioning and orienting the lower diamond with nanometer and micro radian accuracy. We routinely achieve gaps between 5 and 50 nm at culet diameters of 200 μm. With this setup and a micro focused X-ray beam we have investigated the in-plane and the out-off-plane atomic order of benzene with atomic resolution.

  13. Scattering and confinement dynamics of Dirac particles in external electrostatic and Lorentz scalar potentials

    NASA Astrophysics Data System (ADS)

    M, Haritha; P, Durganandini

    2015-06-01

    We study the scattering and confinement of Dirac particles in external electrostatic and Lorentz scalar potentials. We use a numerical finite difference time -domain method to solve the equation and obtain the particle dynamics. We find qualitatively different dynamical behavior for electrostatic and Lorentz scalar potentials. Electrostatic potentials lead to Klein tunneling and do not exhibit confinement, while Lorentz scalar potentials inhibit Klein tunneling and exhibit confinement.

  14. Fractional Brownian motion and motion governed by the fractional Langevin equation in confined geometries.

    PubMed

    Jeon, Jae-Hyung; Metzler, Ralf

    2010-02-01

    Motivated by subdiffusive motion of biomolecules observed in living cells, we study the stochastic properties of a non-Brownian particle whose motion is governed by either fractional Brownian motion or the fractional Langevin equation and restricted to a finite domain. We investigate by analytic calculations and simulations how time-averaged observables (e.g., the time-averaged mean-squared displacement and displacement correlation) are affected by spatial confinement and dimensionality. In particular, we study the degree of weak ergodicity breaking and scatter between different single trajectories for this confined motion in the subdiffusive domain. The general trend is that deviations from ergodicity are decreased with decreasing size of the movement volume and with increasing dimensionality. We define the displacement correlation function and find that this quantity shows distinct features for fractional Brownian motion, fractional Langevin equation, and continuous time subdiffusion, such that it appears an efficient measure to distinguish these different processes based on single-particle trajectory data.

  15. Competing ν = 5/2 fractional quantum Hall states in confined geometry.

    PubMed

    Fu, Hailong; Wang, Pengjie; Shan, Pujia; Xiong, Lin; Pfeiffer, Loren N; West, Ken; Kastner, Marc A; Lin, Xi

    2016-11-01

    Some theories predict that the filling factor 5/2 fractional quantum Hall state can exhibit non-Abelian statistics, which makes it a candidate for fault-tolerant topological quantum computation. Although the non-Abelian Pfaffian state and its particle-hole conjugate, the anti-Pfaffian state, are the most plausible wave functions for the 5/2 state, there are a number of alternatives with either Abelian or non-Abelian statistics. Recent experiments suggest that the tunneling exponents are more consistent with an Abelian state rather than a non-Abelian state. Here, we present edge-current-tunneling experiments in geometrically confined quantum point contacts, which indicate that Abelian and non-Abelian states compete at filling factor 5/2. Our results are consistent with a transition from an Abelian state to a non-Abelian state in a single quantum point contact when the confinement is tuned. Our observation suggests that there is an intrinsic non-Abelian 5/2 ground state but that the appropriate confinement is necessary to maintain it. This observation is important not only for understanding the physics of the 5/2 state but also for the design of future topological quantum computation devices.

  16. DNA electrophoresis in confined, periodic geometries: a new lakes-straits model.

    PubMed

    Laachi, Nabil; Dorfman, Kevin D

    2010-12-21

    We present a method to study the dynamics of long DNA molecules inside a cubic array of confining spheres, connected through narrow openings. Our method is based on the coarse-grained, lakes-straits model of Zimm and is therefore much faster than Brownian dynamics simulations. In contrast to Zimm's approach, our method uses a standard stochastic kinetic simulation to account for the mass transfer through the narrow straits and the formation of new lakes. The different rates, or propensities, of the reactions are obtained using first-passage time statistics and a Monte Carlo sampling to compute the total free energy of the chain. The total free energy takes into account the self-avoiding nature of the chain as well as confinement effects from the impenetrable spheres. The mobilities of various chains agree with biased reptation theory at low and high fields. At moderate fields, confinement effects lead to a new regime of reptation where the mobility is a linear function of molecular weight and the dispersion is minimal.

  17. Competing ν = 5/2 fractional quantum Hall states in confined geometry

    PubMed Central

    Fu, Hailong; Shan, Pujia; Xiong, Lin; Pfeiffer, Loren N.; West, Ken; Kastner, Marc A.; Lin, Xi

    2016-01-01

    Some theories predict that the filling factor 5/2 fractional quantum Hall state can exhibit non-Abelian statistics, which makes it a candidate for fault-tolerant topological quantum computation. Although the non-Abelian Pfaffian state and its particle-hole conjugate, the anti-Pfaffian state, are the most plausible wave functions for the 5/2 state, there are a number of alternatives with either Abelian or non-Abelian statistics. Recent experiments suggest that the tunneling exponents are more consistent with an Abelian state rather than a non-Abelian state. Here, we present edge-current–tunneling experiments in geometrically confined quantum point contacts, which indicate that Abelian and non-Abelian states compete at filling factor 5/2. Our results are consistent with a transition from an Abelian state to a non-Abelian state in a single quantum point contact when the confinement is tuned. Our observation suggests that there is an intrinsic non-Abelian 5/2 ground state but that the appropriate confinement is necessary to maintain it. This observation is important not only for understanding the physics of the 5/2 state but also for the design of future topological quantum computation devices. PMID:27791162

  18. Glass transition of polymers in bulk, confined geometries, and near interfaces

    NASA Astrophysics Data System (ADS)

    Napolitano, Simone; Glynos, Emmanouil; Tito, Nicholas B.

    2017-03-01

    When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular mobility. If the process is performed at a constant rate, the structural relaxation time of the liquid eventually exceeds the time allowed for equilibration. This brings the system out of equilibrium, and the liquid is operationally defined as a glass—a solid lacking long-range order. Despite almost 100 years of research on the (liquid/)glass transition, it is not yet clear which molecular mechanisms are responsible for the unique slow-down in molecular dynamics. In this review, we first introduce the reader to experimental methodologies, theories, and simulations of glassy polymer dynamics and vitrification. We then analyse the impact of connectivity, structure, and chain environment on molecular motion at the length scale of a few monomers, as well as how macromolecular architecture affects the glass transition of non-linear polymers. We then discuss a revised picture of nanoconfinement, going beyond a simple picture based on interfacial interactions and surface/volume ratio. Analysis of a large body of experimental evidence, results from molecular simulations, and predictions from theory supports, instead, a more complex framework where other parameters are relevant. We focus discussion specifically on local order, free volume, irreversible chain adsorption, the Debye–Waller factor of confined and confining media, chain rigidity, and the absolute value of the vitrification temperature. We end by highlighting the molecular origin of distributions in relaxation times and glass transition temperatures which exceed, by far, the size of a chain. Fast relaxation modes, almost universally present at the free surface between polymer and air, are also remarked upon. These modes relax at rates far larger than those characteristic of glassy dynamics in bulk. We speculate on how these may be a signature of unique relaxation processes occurring in confined or heterogeneous polymeric

  19. Non-Newtonian flow of an ultralow-melting chalcogenide liquid in strongly confined geometry

    SciTech Connect

    Wang, Siyuan; Jain, Chhavi; Wondraczek, Katrin; Kobelke, Jens; Wondraczek, Lothar; Troles, Johann; Caillaud, Celine; Schmidt, Markus A.

    2015-05-18

    The flow of high-viscosity liquids inside micrometer-size holes can be substantially different from the flow in the bulk, non-confined state of the same liquid. Such non-Newtonian behavior can be employed to generate structural anisotropy in the frozen-in liquid, i.e., in the glassy state. Here, we report on the observation of non-Newtonian flow of an ultralow melting chalcogenide glass inside a silica microcapillary, leading to a strong deviation of the shear viscosity from its value in the bulk material. In particular, we experimentally show that the viscosity is radius-dependent, which is a clear indication that the microscopic rearrangement of the glass network needs to be considered if the lateral confinement falls below a certain limit. The experiments have been conducted using pressure-assisted melt filling, which provides access to the rheological properties of high-viscosity melt flow under previously inaccessible experimental conditions. The resulting flow-induced structural anisotropy can pave the way towards integration of anisotropic glasses inside hybrid photonic waveguides.

  20. Quantum mechanics of a constrained particle and the problem of prescribed geometry-induced potential

    NASA Astrophysics Data System (ADS)

    da Silva, Luiz C. B.; Bastos, Cristiano C.; Ribeiro, Fábio G.

    2017-04-01

    The experimental techniques have evolved to a stage where various examples of nanostructures with non-trivial shapes have been synthesized, turning the dynamics of a constrained particle and the link with geometry into a realistic and important topic of research. Some decades ago, a formalism to deduce a meaningful Hamiltonian for the confinement was devised, showing that a geometry-induced potential (GIP) acts upon the dynamics. In this work we study the problem of prescribed GIP for curves and surfaces in Euclidean space R3, i.e., how to find a curved region with a potential given a priori. The problem for curves is easily solved by integrating Frenet equations, while the problem for surfaces involves a non-linear 2nd order partial differential equation (PDE). Here, we explore the GIP for surfaces invariant by a 1-parameter group of isometries of R3, which turns the PDE into an ordinary differential equation (ODE) and leads to cylindrical, revolution, and helicoidal surfaces. Helicoidal surfaces are particularly important, since they are natural candidates to establish a link between chirality and the GIP. Finally, for the family of helicoidal minimal surfaces, we prove the existence of geometry-induced bound and localized states and the possibility of controlling the change in the distribution of the probability density when the surface is subjected to an extra charge.

  1. Adapting SAFT-γ perturbation theory to site-based molecular dynamics simulation. III. Molecules with partial charges at bulk phases, confined geometries and interfaces

    NASA Astrophysics Data System (ADS)

    Ghobadi, Ahmadreza F.; Elliott, J. Richard

    2014-09-01

    In Paper I [A. F. Ghobadi and J. R. Elliott, J. Chem. Phys. 139(23), 234104 (2013)], we showed that how a third-order Weeks-Chandler-Anderson (WCA) Thermodynamic Perturbation Theory and molecular simulation can be integrated to characterize the repulsive and dispersive contributions to the Helmholtz free energy for realistic molecular conformations. To this end, we focused on n-alkanes to develop a theory for fused and soft chains. In Paper II [A. F. Ghobadi and J. R. Elliott, J. Chem. Phys. 141(2), 024708 (2014)], we adapted the classical Density Functional Theory and studied the microstructure of the realistic molecular fluids in confined geometries and vapor-liquid interfaces. We demonstrated that a detailed consistency between molecular simulation and theory can be achieved for both bulk and inhomogeneous phases. In this paper, we extend the methodology to molecules with partial charges such as carbon dioxide, water, 1-alkanols, nitriles, and ethers. We show that the electrostatic interactions can be captured via an effective association potential in the framework of Statistical Associating Fluid Theory (SAFT). Implementation of the resulting association contribution in assessing the properties of these molecules at confined geometries and interfaces presents satisfactory agreement with molecular simulation and experimental data. For example, the predicted surface tension deviates less than 4% comparing to full potential simulations. Also, the theory, referred to as SAFT-γ WCA, is able to reproduce the specific orientation of hydrophilic head and hydrophobic tail of 1-alkanols at the vapor-liquid interface of water.

  2. Adapting SAFT-γ perturbation theory to site-based molecular dynamics simulation. III. Molecules with partial charges at bulk phases, confined geometries and interfaces.

    PubMed

    Ghobadi, Ahmadreza F; Elliott, J Richard

    2014-09-07

    In Paper I [A. F. Ghobadi and J. R. Elliott, J. Chem. Phys. 139(23), 234104 (2013)], we showed that how a third-order Weeks-Chandler-Anderson (WCA) Thermodynamic Perturbation Theory and molecular simulation can be integrated to characterize the repulsive and dispersive contributions to the Helmholtz free energy for realistic molecular conformations. To this end, we focused on n-alkanes to develop a theory for fused and soft chains. In Paper II [A. F. Ghobadi and J. R. Elliott, J. Chem. Phys. 141(2), 024708 (2014)], we adapted the classical Density Functional Theory and studied the microstructure of the realistic molecular fluids in confined geometries and vapor-liquid interfaces. We demonstrated that a detailed consistency between molecular simulation and theory can be achieved for both bulk and inhomogeneous phases. In this paper, we extend the methodology to molecules with partial charges such as carbon dioxide, water, 1-alkanols, nitriles, and ethers. We show that the electrostatic interactions can be captured via an effective association potential in the framework of Statistical Associating Fluid Theory (SAFT). Implementation of the resulting association contribution in assessing the properties of these molecules at confined geometries and interfaces presents satisfactory agreement with molecular simulation and experimental data. For example, the predicted surface tension deviates less than 4% comparing to full potential simulations. Also, the theory, referred to as SAFT-γ WCA, is able to reproduce the specific orientation of hydrophilic head and hydrophobic tail of 1-alkanols at the vapor-liquid interface of water.

  3. Hydrodynamic interactions in colloidal systems confined to linear geometries with a singular corner

    NASA Astrophysics Data System (ADS)

    Lin, Binhua; Zarcone, Ryan; Rice, Stuart A.

    Here we investigate the question of whether or not the requirement that particles diffuse around a corner affects their hydrodynamic coupling. We report the results of studies of the collective diffusion coefficients of particles in quasi-one-dimensional linear channels of widths 3 and 5um, each with a singular central corner of angle: 60-, 90-, 120-, and 180-degrees. We find that for large angles, the channels are so close in their geometry to 180-degrees that the corner has very little to no effect on the hydrodynamic coupling of particles on opposite sides of the apex. For small angles, the corner's effect is to increase the particle separation at which the maximum hydrodynamic coupling occurs. U Chicago MRSEC (NSF-DMR-1420709), Dreyfus Foundation (Agency Award #: SI-14-014).

  4. Characterisation of blast loading in complex, confined geometries using quarter symmetry experimental methods

    NASA Astrophysics Data System (ADS)

    Anthistle, T.; Fletcher, D. I.; Tyas, A.

    2016-11-01

    Explosions in confined spaces lead to complicated patterns of shock wave reflection and interactions which are best investigated by use of experimental tests or numerical simulations. This paper describes the design and outcome of a series of experiments using a test cell to measure the pressures experienced when structures were placed inside to alter the propagation of shock waves, utilising quarter symmetry to reduce the size of the required test cell and charge. An 80 g charge of PE4 (a conventional RDX-based plastic explosive) was placed at half height in one corner of the test cell, which represents the centre of a rectangular enclosure when symmetry is taken into consideration. Steel cylinders and rectangular baffles were placed within the test cell at various locations. Good reproducibility was found between repeated tests in three different arrangements, in terms of both the recorded pressure data and the calculated cumulative impulse. The presence of baffles within the test cell made a small difference to the pressures and cumulative impulse experienced compared to tests with no baffles present; however, the number and spacing of baffles was seen to make minimal difference to the experienced pressures and no noticeable difference to the cumulative impulse history. The paper presents useful experimental data that may be used for three-dimensional code validation.

  5. [Structure and dynamics of microemulsions in bulk, at interfaces, and in confined geometries]. Progress report

    SciTech Connect

    Not Available

    1993-12-31

    The authors have been constructing a special purpose small angle neutron scattering spectrometer (SAND) in collaboration with IPNS of Argonne National Laboratory and Texaco Research Laboratories in Beacon, New York. The spectrometer, having a moderate neutron flux, will be uniquely suited for detailed studies of complex fluids in their various phases. This spectrometer will be fully available to general users of the small angle scattering community after a year of testing and upon installation of the auxiliary equipment. The general research objective of the MIT group is to continue studies of the microstructural relationship to phase-behavior in three-component microemulsion systems. Specifically, they shall study the (1) variation of bulk structures when a microemulsion undergoes a non-wetting to wetting transition, (2) correlating interfacial reflectivity measurements of these wetting transitions to the SANS results, (3) use the contrast variation technique they recently developed for measuring the mean and Gaussian curvatures of the surfactant sheet to study the structural inversion of water-in-oil to oil-in-water microemulsions and the transition of disordered bicontinuous microemulsion to ordered lamellar phases, (4) investigation of the effects of spatial confinement on the phase behavior and structure of bicontinuous microemulsions, and finally (5) they shall continue the study of the recently discovered non-exponential relaxation of droplet density fluctuations near the critical and percolation points in water-in-oil droplet microemulsions.

  6. Solution of Two-Body Bound State Problems with Confining Potentials

    SciTech Connect

    Hadizadeh, M. R.; Tomio, Lauro

    2010-11-12

    The homogeneous Lippmann-Schwinger integral equation is solved in momentum space by using confining potentials. Since the confining potentials are unbounded at large distances, they lead to a singularity at small momentum. In order to remove the singularity of the kernel of the integral equation, a regularized form of the potentials is used. As an application of the method, the mass spectra of heavy quarkonia, mesons consisting from heavy quark and antiquark ({Upsilon}(bb-bar), {psi}(cc-bar)), are calculated for linear and quadratic confining potentials. The results are in good agreement with configuration space and experimental results.

  7. Exploring the interactions of gliadins with model membranes: effect of confined geometry and interfaces.

    PubMed

    Banc, Amélie; Desbat, Bernard; Renard, Denis; Popineau, Yves; Mangavel, Cécile; Navailles, Laurence

    2009-08-01

    Mechanisms leading to the assembly of wheat storage proteins into proteins bodies within the endoplasmic reticulum (ER) of endosperm cells are unresolved today. In this work, physical chemistry parameters which could be involved in these processes were explored. To model the confined environment of proteins within the ER, the dynamic behavior of gamma-gliadins inserted inside lyotropic lamellar phases was studied using FRAP experiments. The evolution of the diffusion coefficient as a function of the lamellar periodicity enabled to propose the hypothesis of an interaction between gamma-gliadins and membranes. This interaction was further studied with the help of phospholipid Langmuir monolayers. gamma- and omega-gliadins were injected under DMPC and DMPG monolayers and the two-dimensional (2D) systems were studied by Brewster angle microscopy (BAM), polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS), and surface tension measurements. Results showed that both gliadins adsorbed under phospholipid monolayers, considered as biological membrane models, and formed micrometer-sized domains at equilibrium. However, their thicknesses, probed by reflectance measurements, were different: omega-gliadins aggregates displayed a constant thickness, consistent with a monolayer, while the thickness of gamma-gliadins aggregates increased with the quantity of protein injected. These different behaviors could find some explanations in the difference of aminoacid sequence distribution: an alternate repeated - unrepeated domain within gamma-gliadin sequence, while one unique repeated domain was present within omega-gliadin sequence. All these findings enabled to propose a model of gliadins self-assembly via a membrane interface and to highlight the predominant role of wheat prolamin repeated domain in the membrane interaction. In the biological context, these results would mean that the repeated domain could be considered as an anchor for the interaction with

  8. Confined quantum time of arrival for the vanishing potential

    SciTech Connect

    Galapon, Eric A.; Caballar, Roland F.; Bahague, Ricardo

    2005-12-15

    We give full account of our recent report in E. A. Galapon, R. Caballar, and R. Bahague, Phys. Rev. Lett. 93, 180406 (2004), where it is shown that formulating the free quantum time of arrival problem in a segment of the real line suggests rephrasing the quantum time of arrival problem to finding a complete set of states that evolve to unitarily arrive at a given point at a definite time. For a spatially confined particle, here it is shown explicitly that the problem admits a solution in the form of an eigenvalue problem of a class of compact and self-adjoint time of arrival operators derived by a quantization of the classical time of arrival. The eigenfunctions of these operators are numerically demonstrated to unitarily arrive at the origin at their respective eigenvalues.

  9. Edge-mediated skyrmion chain and its collective dynamics in a confined geometry

    PubMed Central

    Du, Haifeng; Che, Renchao; Kong, Lingyao; Zhao, Xuebing; Jin, Chiming; Wang, Chao; Yang, Jiyong; Ning, Wei; Li, Runwei; Jin, Changqing; Chen, Xianhui; Zang, Jiadong; Zhang, Yuheng; Tian, Mingliang

    2015-01-01

    The emergence of a topologically nontrivial vortex-like magnetic structure, the magnetic skyrmion, has launched new concepts for memory devices. Extensive studies have theoretically demonstrated the ability to encode information bits by using a chain of skyrmions in one-dimensional nanostripes. Here, we report experimental observation of the skyrmion chain in FeGe nanostripes by using high-resolution Lorentz transmission electron microscopy. Under an applied magnetic field, we observe that the helical ground states with distorted edge spins evolve into individual skyrmions, which assemble in the form of a chain at low field and move collectively into the interior of the nanostripes at elevated fields. Such a skyrmion chain survives even when the width of the nanostripe is much larger than the size of single skyrmion. This discovery demonstrates a way of skyrmion formation through the edge effect, and might, in the long term, shed light on potential applications. PMID:26446692

  10. Effect of confining wall potential on charged collimated dust beam in low-pressure plasma

    NASA Astrophysics Data System (ADS)

    Kausik, S. S.; Kakati, B.; Saikia, B. K.

    2013-05-01

    The effect of confining wall potential on charged collimated dust beam in low-pressure plasma has been studied in a dusty plasma experimental setup by applying electrostatic field to each channel of a multicusp magnetic cage. Argon plasma is produced by hot cathode discharge method at a pressure of 5×10-4 millibars and is confined by a full line cusped magnetic field confinement system. Silver dust grains are produced by gas-evaporation technique and move upward in the form of a collimated dust beam due to differential pressure maintained between the dust and plasma chambers. The charged grains in the beam after coming out from the plasma column enter into the diagnostic chamber and are deflected by a dc field applied across a pair of deflector plates at different confining potentials. Both from the amount of deflection and the floating potential, the number of charges collected by the dust grains is calculated. Furthermore, the collimated dust beam strikes the Faraday cup, which is placed above the deflector plates, and the current (˜pA) so produced is measured by an electrometer at different confining potentials. The experimental results demonstrate the significant effect of confining wall potential on charging of dust grains.

  11. Effect of confining wall potential on charged collimated dust beam in low-pressure plasma

    SciTech Connect

    Kausik, S. S.; Kakati, B.; Saikia, B. K.

    2013-05-15

    The effect of confining wall potential on charged collimated dust beam in low-pressure plasma has been studied in a dusty plasma experimental setup by applying electrostatic field to each channel of a multicusp magnetic cage. Argon plasma is produced by hot cathode discharge method at a pressure of 5×10{sup −4} millibars and is confined by a full line cusped magnetic field confinement system. Silver dust grains are produced by gas-evaporation technique and move upward in the form of a collimated dust beam due to differential pressure maintained between the dust and plasma chambers. The charged grains in the beam after coming out from the plasma column enter into the diagnostic chamber and are deflected by a dc field applied across a pair of deflector plates at different confining potentials. Both from the amount of deflection and the floating potential, the number of charges collected by the dust grains is calculated. Furthermore, the collimated dust beam strikes the Faraday cup, which is placed above the deflector plates, and the current (∼pA) so produced is measured by an electrometer at different confining potentials. The experimental results demonstrate the significant effect of confining wall potential on charging of dust grains.

  12. The asymmetric Hubbard model with a confining potential: The partial filling case

    NASA Astrophysics Data System (ADS)

    Silva-Valencia, J.; Franco, R.; Figueira, M. S.

    We investigate the one-dimensional asymmetric Hubbard model with a confining potential, which may describe the ground state of two species of fermionic atoms trapped in a one-dimensional optical lattice. We use White's density matrix renormalization group and the global electronic density considered is n=0.8. The fermion density profiles and their variance were computed. We observe coexistence of insulating and metallic regions in the system. The effective confinement region is different for each kind of fermionic atom.

  13. Interacting Bose gas confined in a Kronig-Penney potential

    NASA Astrophysics Data System (ADS)

    Rodríguez, O. A.; Solís, M. A.

    We analyze the effect of the 1D periodic Kronig-Penney potential, composed of barriers of width b and separated a distance a, over an interacting Bose gas. At T = 0 , the Gross-Pitaevskii equation is solved analytically in terms of the Jacobi elliptic functions for repulsive or attractive interaction between bosons. By applying the boundary conditions for periodic solutions as well as the normalization of the wave function, we arrive to a set of nonlinear equations from which we obtain the density profile and the chemical potential of the condensate as a function of the particle momentum. The profiles for attractive and repulsive interactions are compared with that of the non-interacting case. For attractive interaction we are able to observe a pronounced spatial localization in the middle of every two barriers. We reproduce the well known results when the Kronig-Penney potential becomes a Dirac Comb. We acknowledge partial support from Grants PAPIIT IN111613 and CONACyT 221030.

  14. The confinement of an annealed branched polymer by a potential well

    NASA Astrophysics Data System (ADS)

    Grosberg, Alexander Y.; Kelly, Joshua; Bruinsma, Robijn

    2017-01-01

    The Lifshitz equation for the confinement of a linear polymer in a spherical cavity of radius R has the form of the Schrödinger equation for a quantum particle trapped in a potential well with flat bottom and infinite walls at radius R. We show that the Lifshitz equation of a confined annealed branched polymer has the form of the Schrödinger equation for a quantum harmonic oscillator. The harmonic oscillator potential results from the repulsion of the many branches from the potential walls. Mathematically, it must be obtained from the solution of the equation of motion of a second, now classical, particle in a non-linear potential that depends self-consistently on the eigenvalue of the quantum oscillator. The resulting confinement energy has a 1/R4 dependence on the confinement radius R, in agreement with scaling arguments. We discuss the application of this result to the problem of the confinement of single-stranded RNA molecules inside spherical capsids.

  15. Quantum-Carnot engine for particle confined to cubic potential

    SciTech Connect

    Sutantyo, Trengginas Eka P. Belfaqih, Idrus H. Prayitno, T. B.

    2015-09-30

    Carnot cycle consists of isothermal and adiabatic processes which are reversible. Using analogy in quantum mechanics, these processes can be well explained by replacing variables in classical process with a quantum system. Quantum system which is shown in this paper is a particle that moves under the influence of a cubic potential which is restricted only to the state of the two energy levels. At the end, the efficiency of the system is shown as a function of the width ratio between the initial conditions and the farthest wall while expanding. Furthermore, the system efficiency will be considered 1D and 2D cases. The providing efficiencies are different due to the influence of the degeneration of energy and the degrees of freedom of the system.

  16. Quantum-Carnot engine for particle confined to cubic potential

    NASA Astrophysics Data System (ADS)

    Sutantyo, Trengginas Eka P.; Belfaqih, Idrus H.; Prayitno, T. B.

    2015-09-01

    Carnot cycle consists of isothermal and adiabatic processes which are reversible. Using analogy in quantum mechanics, these processes can be well explained by replacing variables in classical process with a quantum system. Quantum system which is shown in this paper is a particle that moves under the influence of a cubic potential which is restricted only to the state of the two energy levels. At the end, the efficiency of the system is shown as a function of the width ratio between the initial conditions and the farthest wall while expanding. Furthermore, the system efficiency will be considered 1D and 2D cases. The providing efficiencies are different due to the influence of the degeneration of energy and the degrees of freedom of the system.

  17. A particle-in-mesh method for Brownian Dynamics simulation of many-particle systems with hydrodynamics interactions in a confined geometry

    NASA Astrophysics Data System (ADS)

    Zhao, Xujun; Hernandez-Ortiz, Juan; Karpeyev, Dmitry; de Pablo, Juan; Smith, Barry

    In this work, we present an efficient parallel particle-in-mesh method for Brownian Dynamics simulations of many-particle systems confined in micro- and nano-fluidic devices. A general geometry Ewald-like method (GGEM) combined with finite element method is used to account for the hydrodynamic interaction. A fast parallel Krylov-type iterative solver with hybrid preconditioning techniques is developed for solving the large sparse systems of equations arising from finite element discretization of the Stokes equations. In addition, the current computer code is developed based on PETSc, a scalable library of numerical algorithms developed at Argonne, SLEPc - Scalable Library for Eigenvalue Problem Computations, and libMesh, a finite element library for numerical solution of PDEs built on top of PETSc, which allows for direct simulation of large scale systems with arbitrary confined geometries. This scheme is applied to Brownian dynamics simulations of flowing confined polymer solutions and colloidal dispersions in micro-fluid channels. The effects of hydrodynamics interactions and geometric confinement on the migration phenomena are illustrated.

  18. On the calculation of the absolute grand potential of confined smectic-A phases

    NASA Astrophysics Data System (ADS)

    Huang, Chien-Cheng; Baus, Marc; Ryckaert, Jean-Paul

    2015-09-01

    We determine the absolute grand potential Λ along a confined smectic-A branch of a calamitic liquid crystal system enclosed in a slit pore of transverse area A and width L, using the rod-rod Gay-Berne potential and a rod-wall potential favouring perpendicular orientation at the walls. For a confined phase with an integer number of smectic layers sandwiched between the opposite walls, we obtain the excess properties (excess grand potential Λexc, solvation force fs and adsorption Γ) with respect to the bulk phase at the same μ (chemical potential) and T (temperature) state point. While usual thermodynamic integration methods are used along the confined smectic branch to estimate the grand potential difference as μ is varied at fixed L, T, the absolute grand potential at one reference state point is obtained via the evaluation of the absolute Helmholtz free energy in the (N, L, A, T) canonical ensemble. It proceeds via a sequence of free energy difference estimations involving successively the cost of localising rods on layers and the switching on of a one-dimensional harmonic field to keep layers integrity coupled to the elimination of inter-layers and wall interactions. The absolute free energy of the resulting set of fully independent layers of interacting rods is finally estimated via the existing procedures. This work opens the way to the computer simulation study of phase transitions implying confined layered phases.

  19. The Electrophoretic Mobility of a Polyelectrolyte within a Radially Confining Potential Well

    NASA Astrophysics Data System (ADS)

    Shendruk, Tyler; Bertrand, Martin; Slater, Gary W.

    2013-03-01

    We demonstrate that a polyelectrolyte electrophoresing while radially confined by a mechanical force has a conformationally dependent electrophoretic mobility that differs from its free-draining value. The mobility increases as a function of the confining harmonic potential and in the absence of solid walls. Mesoscale MPCD-MD hybrid simulations that include electro-hydrodynamics through a mean-field Debye Hückel approximation will be presented for a variety of well widths and contour lengths, demonstrating that mobility increases with confinement after a critical point but remains independent of polymerization. For this reason, models based on a change of monomer friction coefficient at the confinement boundary (such as those recently put forward to explain experimentally measured mobility polyelectrolytes confined within nano- and microfluidic channels) are not sufficient to explain our observations. Since the potential acts perpendicular to the electric field and only on the monomers, the Electro-Hydrodynamic Equivalence Principle does not predict the mobility to differ. We present a course-grained theory explaining these findings in terms of hydrodynamic coupling within overlapping diffuse layers.

  20. Potential of mean force in confined colloids: integral equations with fundamental measure bridge functions.

    PubMed

    Ayadim, A; Malherbe, J G; Amokrane, S

    2005-06-15

    The potential of mean force for uncharged macroparticles suspended in a fluid confined by a wall or a narrow pore is computed for solvent-wall and solvent-macroparticle interactions with attractive forces. Bridge functions taken from Rosenfeld's density-functional theory are used in the reference hypernetted chain closure of the Ornstein-Zernike integral equations. The quality of this closure is assessed by comparison with simulation. As an illustration, the role of solvation forces is investigated. When the "residual" attractive tails are given a range appropriate to "hard sphere-like" colloids, the unexpected role of solvation forces previously observed in bulk colloids is confirmed in the confinement situation.

  1. Optical probing of MgZnO/ZnO heterointerface confinement potential energy levels

    SciTech Connect

    Solovyev, V. V.; Van'kov, A. B.; Kukushkin, I. V.; Falson, J.; Kozuka, Y.; Zhang, D.; Smet, J. H.; Maryenko, D.; Tsukazaki, A.; Kawasaki, M.

    2015-02-23

    Low-temperature photoluminescence and reflectance measurements were employed to study the optical transitions present in two-dimensional electron systems confined at Mg{sub x}Zn{sub 1–x}O/ZnO heterojunctions. Transitions involving A- and B-holes and electrons from the two lowest subbands formed within the confinement potential are detected. In the studied density range of 2.0–6.5 × 10{sup 11 }cm{sup −2}, the inter-subband splitting is measured and the first excited electron subband is shown to be empty of electrons.

  2. Perfect Abelian dominance of confinement in quark-antiquark potential in SU(3) lattice QCD

    NASA Astrophysics Data System (ADS)

    Suganuma, Hideo; Sakumichi, Naoyuki

    2016-01-01

    In the context of the dual superconductor picture for the confinement mechanism, we study maximally Abelian (MA) projection of quark confinement in SU(3) quenched lattice QCD with 324 at β=6.4 (i.e., a ≃ 0.058 fm). We investigate the static quark-antiquark potential V(r), its Abelian part VAbel(r) and its off-diagonal part Voff(r), respectively, from the on-axis lattice data. As a remarkable fact, we find almost perfect Abelian dominance for quark confinement, i.e., σAbel ≃ σ for the string tension, on the fine and large-volume lattice. We find also a nontrivial summation relation of V (r) ≃ VAbel(r)+Voff(r).

  3. Perfect Abelian dominance of confinement in quark-antiquark potential in SU(3) lattice QCD

    SciTech Connect

    Suganuma, Hideo; Sakumichi, Naoyuki

    2016-01-22

    In the context of the dual superconductor picture for the confinement mechanism, we study maximally Abelian (MA) projection of quark confinement in SU(3) quenched lattice QCD with 32{sup 4} at β=6.4 (i.e., a ≃ 0.058 fm). We investigate the static quark-antiquark potential V(r), its Abelian part V{sub Abel}(r) and its off-diagonal part V{sub off}(r), respectively, from the on-axis lattice data. As a remarkable fact, we find almost perfect Abelian dominance for quark confinement, i.e., σ{sub Abel} ≃ σ for the string tension, on the fine and large-volume lattice. We find also a nontrivial summation relation of V (r) ≃ V{sub Abel}(r)+V{sub off}(r)

  4. Geometry and earthquake potential of the shoreline fault, central California

    USGS Publications Warehouse

    Hardebeck, Jeanne L.

    2013-01-01

    The Shoreline fault is a vertical strike‐slip fault running along the coastline near San Luis Obispo, California. Much is unknown about the Shoreline fault, including its slip rate and the details of its geometry. Here, I study the geometry of the Shoreline fault at seismogenic depth, as well as the adjacent section of the offshore Hosgri fault, using seismicity relocations and earthquake focal mechanisms. The Optimal Anisotropic Dynamic Clustering (OADC) algorithm (Ouillon et al., 2008) is used to objectively identify the simplest planar fault geometry that fits all of the earthquakes to within their location uncertainty. The OADC results show that the Shoreline fault is a single continuous structure that connects to the Hosgri fault. Discontinuities smaller than about 1 km may be undetected, but would be too small to be barriers to earthquake rupture. The Hosgri fault dips steeply to the east, while the Shoreline fault is essentially vertical, so the Hosgri fault dips towards and under the Shoreline fault as the two faults approach their intersection. The focal mechanisms generally agree with pure right‐lateral strike‐slip on the OADC planes, but suggest a non‐planar Hosgri fault or another structure underlying the northern Shoreline fault. The Shoreline fault most likely transfers strike‐slip motion between the Hosgri fault and other faults of the Pacific–North America plate boundary system to the east. A hypothetical earthquake rupturing the entire known length of the Shoreline fault would have a moment magnitude of 6.4–6.8. A hypothetical earthquake rupturing the Shoreline fault and the section of the Hosgri fault north of the Hosgri–Shoreline junction would have a moment magnitude of 7.2–7.5.

  5. Dielectric confinement influenced screened Coulomb potential for a semiconductor quantum wire

    NASA Astrophysics Data System (ADS)

    Aharonyan, K. H.; Margaryan, N. B.

    2016-01-01

    A formalism of the Thomas-Fermi method has been applied for studying the screening effect due to quasi-one-dimensional electron gas in a semiconductor cylindrical quantum wire embedded in the barrier environment. With taking into account of strongly low dielectric properties of the barrier material, an applicability of the quantum wire effective interaction potential of the confined charge carriers has been revealed. Both screened quasi- one-dimensional interaction potential and effective screening length analytical expressions are derived in the first time. It is shown that in the long wavelength moderate limit dielectric confinement effect enhances strength of the screening potential depending on the both radius of the wire and effective screening length, whereas in the long wavelength strong limit the screening potential solely is determined by barrier environment dielectric properties.

  6. A Scaling Law of Plasma Confining Potential Formation with Electron Cyclotron Heating Powers in GAMMA 10

    SciTech Connect

    Numakura, T.; Cho, T.; Kohagura, J.; Hirata, M.; Fukai, T.; Yoshida, M.; Minami, R.; Kiminami, S.; Sakamoto, K.; Imai, T.; Miyoshi, S.

    2005-01-15

    Scaling laws of potential formation and associated effects are theoretically and experimentally investigated in the GAMMA 10 tandem mirror. In GAMMA 10, the main tandem-mirror operations from 1979 to 2003 are characterized in terms of (i) a high-potential mode having kV-order plasma-confining potentials, and (ii) a hot-ion mode yielding fusion neutrons with 10-20 keV bulk-ion temperatures. In this paper, the externally controllable parameter scaling including electron cyclotron heating (ECH) powers for potential formation covering over these two representative operational modes is investigated; that is, the construction of 'the central-cell plasma-confining potentials' {phi}{sub c} formation scaling with plug ECH is studied on the basis of the electron energy-balance equation and Cohen's strong electron cyclotron heating (ECH) theory for investigating the formation physics of plasma confining potentials.It is found that our proposed scaling formulae are in good agreement with the experimental data in the two representative operational modes of the high-potential and hot-ion modes in the GAMMA 10 tandem mirror.This scaling shows a favorable increase in confining potentials with installing more powerful ECH sources by the use of ECH powers over the present 250 kW. On the basis of the scaling prediction, we also report the design of a newly developed 500 kW gyrotron for an application to investigate the validity of the above described {phi}{sub c} formation scaling with plug ECH aiming at achieving higher plasma parameters.

  7. A new perspective on plasmonics: Confinement and propagation length of surface plasmons for different materials and geometries [A new perspective on materials for plasmonics

    SciTech Connect

    Dastmalchi, Babak; Tassin, Philippe; Koschny, Thomas; Soukoulis, Costas M.

    2015-09-21

    Surface-plasmon polaritons are electromagnetic waves propagating on the surface of a metal. Thanks to subwavelength confinement, they can concentrate optical energy on the micrometer or even nanometer scale, enabling new applications in bio-sensing, optical interconnects, and nonlinear optics, where small footprint and strong field concentration are essential. The major obstacle in developing plasmonic applications is dissipative loss, which limits the propagation length of surface plasmons and broadens the bandwidth of surface-plasmon resonances. Here, a new analysis of plasmonic materials and geometries is presented which fully considers the tradeoff between propagation length and degree of confinement. It is based on a two-dimensional analysis of two independent figures of merit and the analysis is applied to relevant plasmonic materials, e.g., noble metals, aluminum, silicon carbide, doped semiconductors, graphene, etc. Furthermore, the analysis provides guidance on how to improve the performance of any particular plasmonic application and substantially eases the selection of the plasmonic material.

  8. Quantum-Carnot engine for particle confined to 2D symmetric potential well

    SciTech Connect

    Belfaqih, Idrus Husin Sutantyo, Trengginas Eka Putra Prayitno, T. B.; Sulaksono, Anto

    2015-09-30

    Carnot model of heat engine is the most efficient cycle consisting of isothermal and adiabatic processes which are reversible. Although ideal gas usually used as a working fluid in the Carnot engine, Bender used quantum particle confined in 1D potential well as a working fluid. In this paper, by following Bender we generalize the situation to 2D symmetric potential well. The efficiency is express as the ratio of the initial length of the system to the final length of the compressed system. The result then is shown that for the same ratio, 2D potential well is more efficient than 1D potential well.

  9. Quantum-Carnot engine for particle confined to 2D symmetric potential well

    NASA Astrophysics Data System (ADS)

    Belfaqih, Idrus Husin; Sutantyo, Trengginas Eka Putra; Prayitno, T. B.; Sulaksono, Anto

    2015-09-01

    Carnot model of heat engine is the most efficient cycle consisting of isothermal and adiabatic processes which are reversible. Although ideal gas usually used as a working fluid in the Carnot engine, Bender used quantum particle confined in 1D potential well as a working fluid. In this paper, by following Bender we generalize the situation to 2D symmetric potential well. The efficiency is express as the ratio of the initial length of the system to the final length of the compressed system. The result then is shown that for the same ratio, 2D potential well is more efficient than 1D potential well.

  10. Spectral characteristics of steady-state Lévy flights in confinement potential profiles

    NASA Astrophysics Data System (ADS)

    Kharcheva, A. A.; Dubkov, A. A.; Dybiec, B.; Spagnolo, B.; Valenti, D.

    2016-05-01

    The steady-state correlation characteristics of superdiffusion in the form of Lévy flights in one-dimensional confinement potential profiles are investigated both theoretically and numerically. Specifically, for Cauchy stable noise we calculate the steady-state probability density function for an infinitely deep rectangular potential well and for a symmetric steep potential well of the type U(x)\\propto {{x}2m} . For these potential profiles and arbitrary Lévy index α, we obtain the asymptotic expression of the spectral power density.

  11. Dielectric constant of liquids confined in the extended nanospace measured by a streaming potential method.

    PubMed

    Morikawa, Kyojiro; Kazoe, Yutaka; Mawatari, Kazuma; Tsukahara, Takehiko; Kitamori, Takehiko

    2015-02-03

    Understanding liquid structure and the electrical properties of liquids confined in extended nanospaces (10-1000 nm) is important for nanofluidics and nanochemistry. To understand these liquid properties requires determination of the dielectric constant of liquids confined in extended nanospaces. A novel dielectric constant measurement method has thus been developed for extended nanospaces using a streaming potential method. We focused on the nonsteady-state streaming potential in extended nanospaces and successfully measured the dielectric constant of liquids within them without the use of probe molecules. The dielectric constant of water was determined to be significantly reduced by about 3 times compared to that of the bulk. This result contributes key information toward further understanding of the chemistry and fluidics in extended nanospaces.

  12. Structural orderings of anisotropically confined colloids interacting via a quasi-square-well potential

    NASA Astrophysics Data System (ADS)

    Campos, L. Q. Costa; Apolinario, S. W. S.

    2015-01-01

    We implement Brownian dynamics to investigate the static properties of colloidal particles confined anisotropically and interacting via a potential which can be tailored in a repulsive-attractive-respulsive fashion as the interparticle distance increases. A diverse number of structural phases are self-assembled, which were classified according to two aspects, that is, their macroscopic and microscopic patterns. Concerning the microscopic phases we found the quasicrystalline, triangular, square, and mixed orderings, where this latter is a combination of square and triangular cells in a 3 ×2 proportion, i.e., the so-called (33,42) Archimedian lattice. On the macroscopic level the system could self-organize in a compact or perforated single cluster surrounded or not by fringes. All the structural phases are summarized in detailed phases diagrams, which clearly show that the different phases are extended as the confinement potential becomes more anisotropic.

  13. The influence of divertor geometry on access to high confinement regimes on the Alcator C-Mod tokamak

    NASA Astrophysics Data System (ADS)

    Hughes, J. W.; Labombard, B.; Hubbard, A.; Marmar, E.; Terry, J.; Rice, J.; Walk, J.; Whyte, D.; Ma, Y.; Cziegler, I.; Edlund, E.; Theiler, C.

    2014-10-01

    The placement of X-point and strike points in a diverted tokamak can have a remarkable impact on properties of the discharge, including thermal and particle confinement. The distinctive divertor of Alcator C-Mod allows us to demonstrate these effects experimentally, as we vary equilibrium shaping to obtain substantial variation of divertor leg length, field line attack angle and divertor baffling. In response to these changes, we observe differences in both L-mode confinement and access to high-confinement regimes (i.e. ELMy H-mode and I-mode). With the ion grad-B drift directed toward the divertor, scanning the strike point can induce ~2× reductions in H-mode power threshold, and can produce a window for I-mode operation with H98 > 1. Recent experiments seek to explore these effects using improved diagnostics, and to extend them to the case with ion grad-B drift directed away from the divertor. Supported by USDoE award DE-FC02-99ER54512.

  14. A simple method for estimating potential source term bypass fractions from confinement structures

    SciTech Connect

    Kalinich, D.A.; Paddleford, D.F.

    1997-07-01

    Confinement structures house many of the operating processes at the Savannah River Site (SRS). Under normal operating conditions, a confinement structure in conjunction with its associated ventilation systems prevents the release of radiological material to the environment. However, under potential accident conditions, the performance of the ventilation systems and integrity of the structure may be challenged. In order to calculate the radiological consequences associated with a potential accident (e.g. fires, explosion, spills, etc.), it is necessary to determine the fraction of the source term initially generated by the accident that escapes from the confinement structure to the environment. While it would be desirable to estimate the potential bypass fraction using sophisticated control-volume/flow path computer codes (e.g. CONTAIN, MELCOR, etc.) in order to take as much credit as possible for the mitigative effects of the confinement structure, there are many instances where using such codes is not tractable due to limits on the level-of-effort allotted to perform the analysis. Moreover, the current review environment, with its emphasis on deterministic/bounding-versus probabilistic/best-estimate-analysis discourages using analytical techniques that require the consideration of a large number of parameters. Discussed herein is a simplified control-volume/flow path approach for calculating source term bypass fraction that is amenable to solution in a spreadsheet or with a commercial mathematical solver (e.g. MathCad or Mathematica). It considers the effects of wind and fire pressure gradients on the structure, ventilation system operation, and Halon discharges. Simple models are used to characterize the engineered and non-engineered flow paths. By making judicious choices for the limited set of problem parameters, the results from this approach can be defended as bounding and conservative.

  15. The photino sector and a confining potential in a supersymmetric Lorentz-symmetry-violating model

    NASA Astrophysics Data System (ADS)

    Belich, H.; Bernald, L. D.; Gaete, Patricio; Helayël-Neto, J. A.

    2013-11-01

    We study the spectrum of the minimal supersymmetric extension of the Carroll-Field-Jackiw model for Electrodynamics with a topological Chern-Simons-like Lorentz-symmetry violating term. We identify a number of independent background fermion condensates, work out the gaugino dispersion relation and propose a photonic effective action to consider aspects of confinement induced by the SUSY background fermion condensates, which also appear to signal Lorentz-symmetry violation in the photino sector of the action. Our calculations of the static potential are carried out within the framework of the gauge-invariant but path-dependent variables formalism which are alternative to the Wilson loop approach. Our results show that the interaction energy contains a linear term leading to the confinement of static probe charges.

  16. Access to high-confinement regimes on Alcator C-Mod and the complex influence of divertor geometry

    NASA Astrophysics Data System (ADS)

    Hughes, J. W.; Labombard, B.; Brunner, D.; Hubbard, A.; Terry, J.; Rice, J.; Walk, J.; Cziegler, I.; Edlund, E.; Theiler, C.

    2015-11-01

    Placement of X-points and strike points in a diverted tokamak can have a remarkable impact on plasma properties, including thermal and particle confinement. The distinctive divertor of Alcator C-Mod allows substantial variation of divertor leg length, field line attack angle and divertor baffling, allowing us to induce changes in both L-mode confinement and access to both H-mode and I-mode. With the ion ∇B drift directed toward the divertor, scanning the strike point can induce ~ 2 × reductions in H-mode power threshold, and can produce a window for I-mode operation with H98 > 1 . Detailed high-resolution measurements, spanning the last closed flux surface, provide profiles of key quantities (n, T, ϕ) and their gradients, which are of likely importance in determining whether a discharge evolves an edge transport barrier, or remains in an L-mode state. Advances in Langmuir probes have enabled characterization of both radial profiles and fast (< 1 MHz) fluctuations in L-mode as the L-H threshold power is approached. These data allow new tests of models for H-mode access, especially those attempting to explain the non-monotonic density dependence of the H-mode power threshold through changes in transport and/or turbulence. Supported by U.S. Department of Energy award DE-FC02-99ER54512, using Alcator C-Mod, a DOE Office of Science User Facility.

  17. Model of waterlike fluid under confinement for hydrophobic and hydrophilic particle-plate interaction potentials.

    PubMed

    Krott, Leandro B; Barbosa, Marcia C

    2014-01-01

    Molecular dynamic simulations were employed to study a waterlike model confined between hydrophobic and hydrophilic plates. The phase behavior of this system is obtained for different distances between the plates and particle-plate potentials. For both hydrophobic and hydrophilic walls, there are the formation of layers. Crystallization occurs at lower temperature at the contact layer than at the middle layer. In addition, the melting temperature decreases as the plates become more hydrophobic. Similarly, the temperatures of maximum density and extremum diffusivity decrease with hydrophobicity.

  18. A new perspective on plasmonics: Confinement and propagation length of surface plasmons for different materials and geometries [A new perspective on materials for plasmonics

    DOE PAGES

    Dastmalchi, Babak; Tassin, Philippe; Koschny, Thomas; ...

    2015-09-21

    Surface-plasmon polaritons are electromagnetic waves propagating on the surface of a metal. Thanks to subwavelength confinement, they can concentrate optical energy on the micrometer or even nanometer scale, enabling new applications in bio-sensing, optical interconnects, and nonlinear optics, where small footprint and strong field concentration are essential. The major obstacle in developing plasmonic applications is dissipative loss, which limits the propagation length of surface plasmons and broadens the bandwidth of surface-plasmon resonances. Here, a new analysis of plasmonic materials and geometries is presented which fully considers the tradeoff between propagation length and degree of confinement. It is based on amore » two-dimensional analysis of two independent figures of merit and the analysis is applied to relevant plasmonic materials, e.g., noble metals, aluminum, silicon carbide, doped semiconductors, graphene, etc. Furthermore, the analysis provides guidance on how to improve the performance of any particular plasmonic application and substantially eases the selection of the plasmonic material.« less

  19. Monte Carlo study of one-dimensional confined fluids with Gay-Berne intermolecular potential

    NASA Astrophysics Data System (ADS)

    Moradi, M.; Hashemi, S.

    2011-11-01

    The thermodynamic quantities of a one dimensional system of particles with Gay-Berne model potential confined between walls have been obtained by means of Monte Carlo computer simulations. For a number of temperatures, the systems were considered and their density profiles, order parameter, pressure, configurational temperature and average potential energy per particle are reported. The results show that by decreasing the temperature, the soft particles become more ordered and they align to the walls and also they don't show any tendency to be near the walls at very low temperatures. We have also changed the structure of the walls by embedding soft ellipses in them, this change increases the total density near the wall whereas, increasing or decreasing the order parameter depend on the angle of embedded ellipses.

  20. Escape rate of Lévy particles from truncated confined and unconfined potentials

    NASA Astrophysics Data System (ADS)

    Bai, Zhan-Wu; Hu, Meng

    2015-06-01

    For a double-well potential consisting of a truncated quartic potential and a truncated harmonic potential, the inter-well escape rates of Lévy particles are investigated numerically, and analytically for the Cauchy case, with focus on the former. The escape rate of Lévy particles from the truncated confined quartic potential well possesses qualitatively different characteristics compared with that from the truncated harmonic potential well, as reflected in the noise intensity dependence and Lévy index dependence of the escape rate. Two kinds of different escape mechanisms exist for low noise and high noise intensities. As the noise intensity increases, the escaping particles in quasi-stationary state present a noise-induced phase transition phenomenon, wherein the distribution of Lévy particles transits from a bimodal narrow distribution to a unimodal wide distribution. The characteristics of the escape rate in low and high noise intensities can be understood by the distributions of Lévy particles and the features of Lévy noise.

  1. Confining interparticle potential makes both heat transport and energy diffusion anomalous in one-dimensional phononic systems

    NASA Astrophysics Data System (ADS)

    Kosevich, Yuriy A.; Savin, Alexander V.

    2016-10-01

    We provide molecular dynamics simulation of heat transport and energy diffusion in one-dimensional molecular chains with different interparticle pair potentials at zero and non-zero temperature. We model the thermal conductivity (TC) and energy diffusion (ED) in the chain of coupled rotators and in the Lennard-Jones chain either without or with the confining parabolic interparticle potential. The considered chains without the confining potential have normal TC and ED at non-zero temperature, while the corresponding chains with the confining potential are characterized by anomalous (diverging with the system length) TC and superdiffusion of energy. Similar effect is produced by the anharmonic quartic confining pair potential. We confirm in such a way that, surprisingly, the confining pair potential makes both heat transport and energy diffusion anomalous in one-dimensional phononic systems. We show that the normal TC is always accompanied by the normal ED in the thermalized anharmonic chains, while the superdiffusion of energy occurs in the thermalized chains with only anomalous heat transport.

  2. Exploring the potential high energy locations and intensities in confined work spaces of waveguide dimensions

    NASA Astrophysics Data System (ADS)

    Rodriguez, Ricardo; Lewis, Winston G.

    2014-07-01

    review visits the likelihood for potential energy build-up due to RF propagation in confined spaces that are of waveguide design but with larger dimensions. Such confined spaces include silos, tanks, pipes, manholes, air-condition ducts, tunnels, wells, engine rooms and operator rooms on board vessels. In these confined spaces waves reflect off of the walls and combine constructively or destructively with incident waves producing reinforcement or cancellation respectively. Where there is reinforcement, the intensity of the wave for a particular distance in accordance with the standard, may exceed the exposure limit for this distance from the source thereby exposing the worker to larger intensities than the accepted limit and presenting a potential health and safety threat.

  3. Elastic anisotropy and pore space geometry of schlieren granite: direct 3-D measurements at high confining pressure combined with microfabric analysis

    NASA Astrophysics Data System (ADS)

    Staněk, Martin; Géraud, Yves; Lexa, Ondrej; Špaček, Petr; Ulrich, Stanislav; Diraison, Marc

    2013-07-01

    Pore space geometry of granitic rocks and its evolution with depth are key factors in large-scale seismics or in projects of enhanced geothermal systems or of deep hazardous waste repositories. In this study, we studied macroscopically anisotropic schlieren-bearing granite by experimental P-wave velocity (VP) measurements on spherical sample in 132 directions at seven different confining pressures in the range 0.1-400 MPa. In order to discriminate the phenomena affecting the rock elastic properties we analysed the orientation of microcracks and of grain boundaries and we measured the anisotropy of magnetic susceptibility of the rock. Three sets of microcracks were defined, with two of them linked to the massif exfoliation process and one to cooling contraction of the massif. During pressurization the measured mean VP and VP anisotropy degree at ambient pressure and at highest confinement (400 MPa) yielded 3.3 km s-1 and 24 per cent, and 6.2 km s-1 and 3 per cent, respectively. The associated VP anisotropy pattern was transversely isotropic and governed by the schlieren, with a minimum VP direction perpendicular to them and a girdle of high VP directions parallel to them. The highest change in VP was observed between 0.1 and 10 MPa, suggesting a significant closure of porosity below depths of 500 m. Change of the VP anisotropy pattern to orthorhombic together with increase of mean VP and VP anisotropy degree during depressurization was attributed to inelastic response of one of the sets of microcracks to the loading-unloading cycle.

  4. Foraging on the potential energy surface: A swarm intelligence-based optimizer for molecular geometry

    NASA Astrophysics Data System (ADS)

    Wehmeyer, Christoph; Falk von Rudorff, Guido; Wolf, Sebastian; Kabbe, Gabriel; Schärf, Daniel; Kühne, Thomas D.; Sebastiani, Daniel

    2012-11-01

    We present a stochastic, swarm intelligence-based optimization algorithm for the prediction of global minima on potential energy surfaces of molecular cluster structures. Our optimization approach is a modification of the artificial bee colony (ABC) algorithm which is inspired by the foraging behavior of honey bees. We apply our modified ABC algorithm to the problem of global geometry optimization of molecular cluster structures and show its performance for clusters with 2-57 particles and different interatomic interaction potentials.

  5. The potential impact of flooding on confined animal feeding operations in eastern North Carolina.

    PubMed Central

    Wing, Steve; Freedman, Stephanie; Band, Lawrence

    2002-01-01

    Thousands of confined animal feeding operations (CAFOs) have been constructed in eastern North Carolina. The fecal waste pit and spray field waste management systems used by these operations are susceptible to flooding in this low-lying region. To investigate the potential that flood events can lead to environmental dispersion of animal wastes containing numerous biologic and chemical hazards, we compared the geographic coordinates of 2,287 CAFOs permitted by the North Carolina Division of Water Quality (DWQ) with estimates of flooding derived from digital satellite images of eastern North Carolina taken approximately 1 week after Hurricane Floyd dropped as much as 15-20 inches of rain in September 1999. Three cattle, one poultry, and 237 swine operations had geographic coordinates within the satellite-based flooded area. DWQ confirmed 46 operations with breached or flooded fecal waste pits in the same area. Only 20 of these 46 CAFOs were within the satellite-based estimate of the inundated area. CAFOs within the satellite-based flood area were located in 132 census block groups with a population of 171,498 persons in the 2000 census. African Americans were more likely than whites to live in areas with flooded CAFOs according to satellite estimates, but not according to DWQ reports. These areas have high poverty rates and dependence on wells for drinking water. Our analysis suggests that flood events have a significant potential to degrade environmental health because of dispersion of wastes from industrial animal operations in areas with vulnerable populations. PMID:11940456

  6. Bent waveguides for matter-waves: supersymmetric potentials and reflectionless geometries

    PubMed Central

    Campo, Adolfo del; Boshier, Malcolm G.; Saxena, Avadh

    2014-01-01

    Non-zero curvature in a waveguide leads to the appearance of an attractive quantum potential which crucially affects the dynamics in matter-wave circuits. Using methods of supersymmetric quantum mechanics, pairs of bent waveguides are found whose geometry-induced potentials share the same scattering properties. As a result, reflectionless waveguides, dual to the straight waveguide, are identified. Strictly isospectral waveguides are also found by modulating the depth of the trapping potential. Numerical simulations are used to demonstrate the efficiency of these approaches in tailoring and controlling curvature-induced quantum-mechanical effects. PMID:24919423

  7. Noninvasive recovery of epicardial potentials in a realistic heart-torso geometry. Normal sinus rhythm.

    PubMed

    Messinger-Rapport, B J; Rudy, Y

    1990-04-01

    The inverse problem in electrocardiography implies the reconstruction of electrical events within the heart from information measured noninvasively on the body surface. Deduction of these electrical events is possible from measured epicardial potentials, and, thus, a noninvasive method of recovering epicardial potentials from body surface data is useful in experimental and clinical studies. In the present study, an inverse method that uses Tikhonov regularization was shown to reconstruct, with good accuracy, important events in cardiac excitation. The inverse procedure was employed on data obtained from a human-torso tank in which a beating canine heart was placed in the correct anatomical position. Comparison with the actual, measured epicardial potentials indicates that positions and shapes of potential features (maxima, minima, zero potential line, saddles, etc.) are recovered with good accuracy throughout the QRS. An error in position of up to 1 cm is typical, while amplitudes are slightly diminished. In addition, application was extended from the above setting, in which the geometry was precisely known and potentials at a large number of leads were measured accurately, to a situation that is more representative of clinical and experimental settings. Effects of inaccuracy in location of the position of the heart were examined. A stylized torso that approximates the actual geometry was designed, and its performance in the inverse computations was evaluated. A systematic method of reduction of the number of leads on the body surface was proposed, and the resulting lead configurations were evaluated in terms of the accuracy of inverse solutions. The results indicate that the inverse problem can be stabilized with respect to different types of uncertainties in measured data and offer promise in the use of the inverse procedure in clinical and experimental situations.

  8. POTENTIAL OF CONFINED ANIMAL FEED OPERATIONS (CAFOS) TO CONTRIBUTE ESTROGENS TO THE ENVIRONMENT

    EPA Science Inventory

    Confined Animal Feed Operations (CAFOs) are a growing industry, with a trend towards fewer operations with higher concentrations of animals. Animals are either fed and/or treated with many different types of pharmaceuticals, including antibiotics and hormones, which can end up in...

  9. Analysis of the radial potential structure and neutron production rate in the spherical inertial electrostatic confinement fusion devices

    NASA Astrophysics Data System (ADS)

    Ramzanpour, M. A.; Pahlavani, M. R.

    2017-01-01

    The radial dependent potential and neutron production rate in spherical inertial electrostatic confinement fusion (IECF) devices is investigated. The electrostatic potential is determined by solving the Poisson equation for various deuteron and electron distribution functions. The fusion reaction rates are determined using energy distribution function. Also, dependence of potential structure and neutron production rate on some important parameters as the ion and electron convergence, working pressure, kinetic energy of the secondary electrons emitted from the cathode and the fraction of secondary electrons drawn inside the cathode are studied. Total produced neutrons as a function of input power at different working conditions are also obtained.

  10. Comparison of non-neutral electron plasma confinement in harmonic and rectangular potentials in a very dense regime

    SciTech Connect

    Mohamed, T.; Mohri, A.; Yamazaki, Y.

    2013-01-15

    Confinement of high density electron plasmas in a strong uniform magnetic field was experimentally studied in a multi-ring trap (MRT). The trap was housed inside a bore tube and surrounded by a superconducting solenoid. A 5 T magnetic field was used to provide radial confinement while an electrostatic harmonic or rectangular potential well was used for axial confinement. For trapped electrons of N = 1.2 Multiplication-Sign 10{sup 10} in a harmonic potential well (HPW) with the trap length of L{sub T} = 320 mm, the plasma lifetime was about 10{sup 4} s and it became much longer at lower N = 4.5 Multiplication-Sign 10{sup 9}. Such long holding times were achieved without application of rotating electric fields. Contrastingly, in a rectangular potential well (RPW), the plasma of N = 1.2 Multiplication-Sign 10{sup 10} under the same trap length expanded to cover the whole Faraday Cup within 200 s, where its radial expansion rate was {eta} = 3.2 Multiplication-Sign 10{sup -2} mm/s, which was 20 times faster than HPW. The lifetime for RPW became shorter with increasing L{sub T} and scaled as 1/[L{sub T}]{sup 2}. This scaling found for high density plasmas is similar to the obtained one with different Penning-Malmberg traps at UC San Diego (USCD).

  11. Navigability Potential of Washington Rivers and Streams Determined with Hydraulic Geometry and a Geographic Information System

    USGS Publications Warehouse

    Magirl, Christopher S.; Olsen, Theresa D.

    2009-01-01

    Using discharge and channel geometry measurements from U.S. Geological Survey streamflow-gaging stations and data from a geographic information system, regression relations were derived to predict river depth, top width, and bottom width as a function of mean annual discharge for rivers in the State of Washington. A new technique also was proposed to determine bottom width in channels, a parameter that has received relatively little attention in the geomorphology literature. These regression equations, when combined with estimates of mean annual discharge available in the National Hydrography Dataset, enabled the prediction of hydraulic geometry for any stream or river in the State of Washington. Predictions of hydraulic geometry can then be compared to thresholds established by the Washington State Department of Natural Resources to determine navigability potential of rivers. Rivers with a mean annual discharge of 1,660 cubic feet per second or greater are 'probably navigable' and rivers with a mean annual discharge of 360 cubic feet per second or less are 'probably not navigable'. Variance in the dataset, however, leads to a relatively wide range of prediction intervals. For example, although the predicted hydraulic depth at a mean annual discharge of 1,660 cubic feet per second is 3.5 feet, 90-percent prediction intervals indicate that the actual hydraulic depth may range from 1.8 to 7.0 feet. This methodology does not determine navigability - a legal concept determined by federal common law - instead, this methodology is a tool for predicting channel depth, top width, and bottom width for rivers and streams in Washington.

  12. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    SciTech Connect

    Kushwaha, Manvir S.

    2014-12-15

    Semiconducting quantum dots – more fancifully dubbed artificial atoms – are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement – or the lack of any degree of freedom for the electrons (and/or holes) – in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines’ random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing) the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding) the size of the quantum dots: resulting into a blue (red) shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower) magneto-optical transitions survive even in the extreme instances. However, the intra-Landau level

  13. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    NASA Astrophysics Data System (ADS)

    Kushwaha, Manvir S.

    2014-12-01

    Semiconducting quantum dots - more fancifully dubbed artificial atoms - are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement - or the lack of any degree of freedom for the electrons (and/or holes) - in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines' random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing) the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding) the size of the quantum dots: resulting into a blue (red) shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower) magneto-optical transitions survive even in the extreme instances. However, the intra-Landau level transitions are seen

  14. Observing the confinement potential of bacterial pore-forming toxin receptors inside rafts with nonblinking Eu(3+)-doped oxide nanoparticles.

    PubMed

    Türkcan, Silvan; Masson, Jean-Baptiste; Casanova, Didier; Mialon, Geneviève; Gacoin, Thierry; Boilot, Jean-Pierre; Popoff, Michel R; Alexandrou, Antigoni

    2012-05-16

    We track single toxin receptors on the apical cell membrane of MDCK cells with Eu-doped oxide nanoparticles coupled to two toxins of the pore-forming toxin family: α-toxin of Clostridium septicum and ε-toxin of Clostridium perfringens. These nonblinking and photostable labels do not perturb the motion of the toxin receptors and yield long uninterrupted trajectories with mean localization precision of 30 nm for acquisition times of 51.3 ms. We were thus able to study the toxin-cell interaction at the single-molecule level. Toxins bind to receptors that are confined within zones of mean area 0.40 ± 0.05 μm(2). Assuming that the receptors move according to the Langevin equation of motion and using Bayesian inference, we determined mean diffusion coefficients of 0.16 ± 0.01 μm(2)/s for both toxin receptors. Moreover, application of this approach revealed a force field within the domain generated by a springlike confining potential. Both toxin receptors were found to experience forces characterized by a mean spring constant of 0.30 ± 0.03 pN/μm at 37°C. Furthermore, both toxin receptors showed similar distributions of diffusion coefficient, domain area, and spring constant. Control experiments before and after incubation with cholesterol oxidase and sphingomyelinase show that these two enzymes disrupt the confinement domains and lead to quasi-free motion of the toxin receptors. Our control data showing cholesterol and sphingomyelin dependence as well as independence of actin depolymerization and microtubule disruption lead us to attribute the confinement of both receptors to lipid rafts. These toxins require oligomerization to develop their toxic activity. The confined nature of the toxin receptors leads to a local enhancement of the toxin monomer concentration and may thus explain the virulence of this toxin family.

  15. Effect of conductivity variations within the electric double layer on the streaming potential estimation in narrow fluidic confinements.

    PubMed

    Das, Siddhartha; Chakraborty, Suman

    2010-07-06

    In this article, we investigate the implications of ionic conductivity variations within the electrical double layer (EDL) on the streaming potential estimation in pressure-driven fluidic transport through narrow confinements. Unlike the traditional considerations, we do not affix the ionic conductivities apriori by employing preset values of dimensionless parameters (such as the Dukhin number) to estimate the streaming potential. Rather, utilizing the Gouy-Chapman-Grahame model for estimating the electric potential and charge density distribution within the Stern layer, we first quantify the Stern layer electrical conductivity as a function of the zeta potential and other pertinent parameters quantifying the interaction of the ionic species with the charged surface. Next, by invoking the Boltzmann model for cationic and anionic distribution within the diffuse layer, we obtain the diffuse layer electrical conductivity. On the basis of these two different conductivities pertaining to the two different portions of the EDL as well as the bulk conductivity, we define two separate Dukhin numbers that turn out to be functions of the dimensionless zeta potential and the channel height to Debye length ratio. We derive analytical expressions for the streaming potential as a function of the fundamental governing parameters, considering the above. The results reveal interesting and significant deviations between the streaming potential predictions from the present considerations against the corresponding predictions from the classical considerations in which electrochemically consistent estimates of variable EDL conductivity are not traditionally accounted for. In particular, it is revealed that the variations of streaming potential with zeta potential are primarily determined by the competing effects of EDL electromigration and ionic advection. Over low and high zeta potential regimes, the Stern layer and diffuse layer conductivities predominantly dictate the streaming

  16. Generalized Sturmians in the time-dependent frame: effect of a fullerene confining potential

    NASA Astrophysics Data System (ADS)

    Frapiccini, Ana Laura; Gasaneo, Gustavo; Mitnik, Dario M.

    2017-02-01

    In this work we present a novel implementation of the Generalized Sturmian Functions in the time-dependent frame to numerically solve the time-dependent Schrödinger equation. We study the effect of the confinement of H atom in a fullerene cage for the 1s → 2p resonant transition of the atom interacting with a finite laser pulse, calculating the population of bound states and spectral density.

  17. Nanoscopic Cellular Imaging: Confinement Broadens Understanding.

    PubMed

    Lee, Stephen A; Ponjavic, Aleks; Siv, Chanrith; Lee, Steven F; Biteen, Julie S

    2016-09-27

    In recent years, single-molecule fluorescence imaging has been reconciling a fundamental mismatch between optical microscopy and subcellular biophysics. However, the next step in nanoscale imaging in living cells can be accessed only by optical excitation confinement geometries. Here, we review three methods of confinement that can enable nanoscale imaging in living cells: excitation confinement by laser illumination with beam shaping; physical confinement by micron-scale geometries in bacterial cells; and nanoscale confinement by nanophotonics.

  18. Consistent prediction of streaming potential in non-Newtonian fluids: the effect of solvent rheology and confinement on ionic conductivity.

    PubMed

    Bandopadhyay, Aditya; Chakraborty, Suman

    2015-03-21

    By considering an ion moving inside an imaginary sphere filled with a power-law fluid, we bring out the implications of the fluid rheology and the influence of the proximity of the other ions towards evaluating the conduction current in an ionic solution. We show that the variation of the conductivity as a function of the ionic concentration is both qualitatively and quantitatively similar to that predicted by the Kohlrausch law. We then utilize this consideration for estimating streaming potentials developed across narrow fluidic confinements as a consequence of the transport of ions in a convective medium constituting a power-law fluid. These estimates turn out to be in sharp contrast to the classical estimates of streaming potential for non-Newtonian fluids, in which the effect of rheology of the solvent is merely considered to affect the advection current, disregarding its contributions to the conduction current. Our results have potential implications of devising a new paradigm of consistent estimation of streaming potentials for non-Newtonian fluids, with combined considerations of the confinement effect and fluid rheology in the theoretical calculations.

  19. Pore Diameter Dependence and Segmental Dynamics of Poly-Z-L-lysine and Poly-L-alanine Confined in 1D Nanocylindrical Geometry

    NASA Astrophysics Data System (ADS)

    Tuncel, Eylul; Suzuki, Yasuhito; Iossifidis, Agathaggelos; Steinhart, Martin; Butt, Hans-Jurgen; Floudas, George; Duran, Hatice

    Structure formation, thermodynamic stability, phase and dynamic behaviors of polypeptides are strongly affected by confinement. Since understanding the changes in these behaviors will allow their rational design as functional devices with tunable properties, herein we investigated Poly-Z-L-lysine (PZLL) and Poly-L-alanine (PAla) homopolypeptides confined in nanoporous alumina containing aligned cylindrical nanopores as a function of pore size by differential scanning calorimetry (DSC), Fourier Transform Infrared Spectroscopy, Solid-state NMR, X-ray diffraction, Dielectric spectroscopy(DS). Bulk PZLL exhibits a glass transition temperature (Tg) at about 301K while PZLL nanorods showed slightly lower Tg (294K). The dynamic investigation by DS also revealed a decrease (4K) in Tg between bulk and PZLL nanorods. DS is a very sensitive probe of the local and global secondary structure relaxation through the large dipole to study effect of confinement. The results revealed that the local segmental dynamics, associated with broken hydrogen bonds, and segmental dynamics speed-up on confinement.

  20. Making Conjectures in Dynamic Geometry: The Potential of a Particular Way of Dragging

    ERIC Educational Resources Information Center

    Mariotti, Maria Alessandra; Baccaglini-Frank, Anna

    2011-01-01

    When analyzing what has changed in the geometry scenario with the advent of dynamic geometry systems (DGS), one can notice a transition from the traditional graphic environment made of paper-and-pencil, and the classical construction tools like the ruler and compass, to a virtual graphic space, made of a computer screen, graphical tools that are…

  1. An ab Initio Study on Solar Geometry and Potential for N-E India

    NASA Astrophysics Data System (ADS)

    Bhattacharjee, S.

    2012-09-01

    In north-east (N-E) India, there is severe power shortage and associated power quality problems; the quality of grid supply in most of the places is characterized by large voltage and frequency fluctuations, scheduled and unscheduled power cuts and load restrictions. Load shedding due to power shortage and faults in many cities in N-E India is a major problem for which there is no immediate remedy in near future since the gap between power demand and supply is increasing every year. But this region being rich in sun shine, solar energy is available all over the year at free of cost. In order to harness solar energy, it is important to know the amount of solar radiation available at a given location at a given time. Knowledge of solar radiation requires information about many parameters. This paper tries to analyze the solar geometry and potential of the region and presents various parameters for evaluation of solar resource as a promising option for power generation in N-E India.

  2. Transition state geometry of driven chemical reactions on time-dependent double-well potentials.

    PubMed

    Junginger, Andrej; Craven, Galen T; Bartsch, Thomas; Revuelta, F; Borondo, F; Benito, R M; Hernandez, Rigoberto

    2016-11-09

    Reaction rates across time-dependent barriers are difficult to define and difficult to obtain using standard transition state theory approaches because of the complexity of the geometry of the dividing surface separating reactants and products. Using perturbation theory (PT) or Lagrangian descriptors (LDs), we can obtain the transition state trajectory and the associated recrossing-free dividing surface. With the latter, we are able to determine the exact reactant population decay and the corresponding rates to benchmark the PT and LD approaches. Specifically, accurate rates are obtained from a local description regarding only direct barrier crossings and to those obtained from a stability analysis of the transition state trajectory. We find that these benchmarks agree with the PT and LD approaches for obtaining recrossing-free dividing surfaces. This result holds not only for the local dynamics in the vicinity of the barrier top, but also for the global dynamics of particles that are quenched at the reactant or product wells after their sojourn over the barrier region. The double-well structure of the potential allows for long-time dynamics related to collisions with the outside walls that lead to long-time returns in the low-friction regime. This additional global dynamics introduces slow-decay pathways that do not result from the local transition across the recrossing-free dividing surface associated with the transition state trajectory, but can be addressed if that structure is augmented by the population transfer of the long-time returns.

  3. Are scaling laws of sub-optical wavelength electric field confinement in arrays of metal nanoparticles related to plasmonics or to geometry?

    PubMed

    Mezeme, M Essone; Brosseau, C

    2012-07-30

    In this work, we describe finite element simulations of the plasmonic resonance (PLR) properties of a self-similar chain of plasmonic nanostructures. Using a broad range of conditions, we find strong numerical evidence that the electric field confinement behaves as (Ξ/λ)(PLR)[proporationality] EFE(-γ), where EFE is the electric field enhancement, Ξis the linear size of the focusing length, and λ is the wavelength of the resonant excitation. We find that the exponent γ is close to 1, i.e. significantly lower than the 1.5 found for two-dimensional nanodisks. This scaling law provides support for the hypothesis of a universal regime in which the sub-optical wavelength electric field confinement is controlled by the Euclidean dimensionality and is independent of nanoparticle size, metal nature, or embedding medium permittivity.

  4. Confining and repulsive potentials from effective non-Abelian gauge fields in graphene bilayers

    NASA Astrophysics Data System (ADS)

    González, J.

    2016-10-01

    We investigate the effect of shear and strain in graphene bilayers, under conditions where the distortion of the lattice gives rise to a smooth one-dimensional modulation in the stacking sequence of the bilayer. We show that strain and shear produce characteristic Moiré patterns which can have the same visual appearance on a large scale, but representing graphene bilayers with quite different electronic properties. The different features in the low-energy electronic bands can be ascribed to the effect of a fictitious non-Abelian gauge field mimicking the smooth modulation of the stacking order. Strained and sheared bilayers show a complementary behavior, which can be understood from the fact that the non-Abelian gauge field acts as a repulsive interaction in the former, expelling the electron density away from the stacking domain walls, while behaving as a confining interaction leading to localization of the electronic states in the sheared bilayers. In this latter case, the presence of the effective gauge field explains the development of almost flat low-energy bands, resembling the form of the zeroth Landau level characteristic of a Dirac fermion field. The estimate of the gauge field strength in those systems gives a magnitude of the order of several tens of tesla, implying a robust phenomenology that should be susceptible of being observed in suitably distorted bilayer samples.

  5. Near-surface, marine seismic-reflection data defines potential hydrogeologic confinement bypass in a tertiary carbonate aquifer, southeastern Florida

    USGS Publications Warehouse

    Cunningham, Kevin J.; Walker, Cameron; Westcott, Richard L.

    2012-01-01

    Approximately 210 km of near-surface, high-frequency, marine seismic-reflection data were acquired on the southeastern part of the Florida Platform between 2007 and 2011. Many high-resolution, seismic-reflection profiles, interpretable to a depth of about 730 m, were collected on the shallow-marine shelf of southeastern Florida in water as shallow as 1 m. Landward of the present-day shelf-margin slope, these data image middle Eocene to Pleistocene strata and Paleocene to Pleistocene strata on the Miami Terrace. This high-resolution data set provides an opportunity to evaluate geologic structures that cut across confining units of the Paleocene to Oligocene-age carbonate rocks that form the Floridan aquifer system.Seismic profiles image two structural systems, tectonic faults and karst collapse structures, which breach confining beds in the Floridan aquifer system. Both structural systems may serve as pathways for vertical groundwater flow across relatively low-permeability carbonate strata that separate zones of regionally extensive high-permeability rocks in the Floridan aquifer system. The tectonic faults occur as normal and reverse faults, and collapse-related faults have normal throw. The most common fault occurrence delineated on the reflection profiles is associated with karst collapse structures. These high-frequency seismic data are providing high quality structural analogs to unprecedented depths on the southeastern Florida Platform. The analogs can be used for assessment of confinement of other carbonate aquifers and the sealing potential of deeper carbonate rocks associated with reservoirs around the world.

  6. The potential role of electric fields and plasma barodiffusion on the inertial confinement fusion databasea)

    NASA Astrophysics Data System (ADS)

    Amendt, Peter; Wilks, S. C.; Bellei, C.; Li, C. K.; Petrasso, R. D.

    2011-05-01

    The generation of strong, self-generated electric fields (GV/m) in direct-drive, inertial-confinement-fusion (ICF) capsules has been reported [Rygg et al., Science 319, 1223 (2008); Li et al., Phys. Rev. Lett. 100, 225001 (2008)]. A candidate explanation for the origin of these fields based on charge separation across a plasma shock front was recently proposed [Amendt et al., Plasma Phys. Controlled Fusion 51 124048 (2009)]. The question arises whether such electric fields in imploding capsules can have observable consequences on target performance. Two well-known anomalies come to mind: (1) an observed ≈2× greater-than-expected deficit of neutrons in an equimolar D3He fuel mixture compared with hydrodynamically equivalent D [Rygg et al., Phys. Plasmas 13, 052702 (2006)] and DT [Herrmann et al., Phys. Plasmas 16, 056312 (2009)] fuels, and (2) a similar shortfall of neutrons when trace amounts of argon are mixed with D in indirect-drive implosions [Lindl et al., Phys. Plasmas 11, 339 (2004)]. A new mechanism based on barodiffusion (or pressure gradient-driven diffusion) in a plasma is proposed that incorporates the presence of shock-generated electric fields to explain the reported anomalies. For implosions performed at the Omega laser facility [Boehly et al., Opt. Commun. 133, 495 (1997)], the (low Mach number) return shock has an appreciable scale length over which the lighter D ions can diffuse away from fuel center. The depletion of D fuel is estimated and found to lead to a corresponding reduction in neutrons, consistent with the anomalies observed in experiments for both argon-doped D fuels and D3He equimolar mixtures. The reverse diffusional flux of the heavier ions toward fuel center also increases the pressure from a concomitant increase in electron number density, resulting in lower stagnation pressures and larger imploded cores in agreement with gated, self-emission, x-ray imaging data.

  7. Atmospheric Transport Modelling confining potential source location of East-Asian radionuclide detections in May 2010

    NASA Astrophysics Data System (ADS)

    Ross, J. Ole; Ceranna, Lars

    2016-04-01

    The radionuclide component of the International Monitoring System (IMS) to verify compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT) is in place to detect tiny traces of fission products from nuclear explosions in the atmosphere. The challenge for the interpretation of IMS radionuclide data is to discriminate radionuclide sources of CTBT relevance against emissions from nuclear facilities. Remarkable activity concentrations of Ba/La-140 occurred at the IMS radionuclide stations RN 37 (Okinawa) and RN 58 (Ussurysk) mid of May 2010. In those days also an elevated Xe-133 level was measured at RN 38 (Takasaki). Additional regional measurements of radioxenon were reported in the press and further analyzed in various publications. The radionuclide analysis gives evidence for the presence of a nuclear fission source between 10 and 12 May 2010. Backward Atmospheric Transport Modelling (ATM) with HYSPLIT driven by 0.2° ECMWF meteorological data for the IMS samples indicates that, assuming a single source, a wide range of source regions is possible including the Korean Peninsula, the Sea of Japan (East Sea), and parts of China and Russia. Further confinement of the possible source location can be provided by atmospheric backtracking for the assumed sampling periods of the reported regional xenon measurements. New studies indicate a very weak seismic event at the DPRK test site on early 12 May 2010. Forward ATM for a pulse release caused by this event shows fairly good agreement with the observed radionuclide signature. Nevertheless, the underlying nuclear fission scenario remains quite unclear and speculative even if assuming a connection between the waveform and the radionuclide event.

  8. Monitoring and modelling of pumping-induced self-potentials for transmissivity estimation within a heterogeneous confined aquifer

    NASA Astrophysics Data System (ADS)

    DesRoches, Aaron J.; Butler, Karl E.

    2016-12-01

    Variations in self-potentials (SP) measured at surface during pumping of a heterogeneous confined fractured rock aquifer have been monitored and modelled in order to investigate capabilities and limitations of SP methods in estimating aquifer hydraulic properties. SP variations were recorded around a pumping well using an irregular grid of 31 non-polarizing Pb-PbCl2 that were referenced to a remote electrode and connected to a commercial multiplexer and digitizer/data logger through a passive lowpass filter on each channel. The lowpass filter reduced noise by a factor of 10 compared to levels obtained using the data logger's integration-based sampling method for powerline noise suppression alone. SP signals showed a linear relationship with water levels observed in the pumping and monitoring wells over the pumping period, with an apparent electrokinetic coupling coefficient of -3.4 mV · m-1. Following recent developments in SP methodology, variability of the SP response between different electrodes is taken as a proxy for lateral variations in hydraulic head within the aquifer and used to infer lateral variations in the aquifer's apparent transmissivity. In order to demonstrate the viability of this approach, SP is modelled numerically to determine its sensitivity to (i) lateral variations in the hydraulic conductivity of the confined aquifer and (ii) the electrical conductivity of the confining layer and conductive well casing. In all cases, SP simulated on the surface still varies linearly with hydraulic head modelled at the base on the confining layer although the apparent coupling coefficient changes to varying degrees. Using the linear relationship observed in the field, drawdown curves were inferred for each electrode location using SP variations observed over the duration of the pumping period. Transmissivity estimates, obtained by fitting the Theis model to inferred drawdown curves at all 31 electrodes, fell within a narrow range of (2.0-4.2) × 10-3 m2

  9. Internal geometry, seismic facies, and petroleum potential of canyons and inner fan channels of the Indus submarine fan

    SciTech Connect

    McHargue, T.R.; Webb, J.E.

    1986-02-01

    The Indus Fan, the second largest submarine fan in the world, covers 1,250,000 km/sup 2/ (500,000 mi/sup 2/) and contains sediment more than 7 km (23,000 ft) thick. Multichannel (24-fold) CDP seismic data provide the bases for evaluating the Indus Fan and consist of four seismic facies. Of these, only the high-amplitude, discontinuous (H-D) facies is thought to contain reservoir-quality sandstones. The H-D facies is confined to the axes of leveed channels. Canyon-channel systems that fed the fan in the past can be divided into three zones. The degradational zone is composed of an erosional canyon complex filled by prodelta mud. The transitional zone, located near the canyon mouth, consists of superimposed channels that initially were erosional but eventually aggraded and developed levees. The headward termination of the H-D facies occurs in this zone. The aggradational zone consists of superimposed leveed channels confined solely by their own levees. The proximal termination of the H-D facies near canyon mouths implies the presence of reservoir-quality sandstone surrounded by source/seal mudstone in the transitional zone. This stratigraphic trapping geometry and structural leads may represent a vast, untapped petroleum province.

  10. The potentiation of geometry by features in human children: Evidence against modularity in the domain of navigation.

    PubMed

    Lourenco, Stella F; Cabrera, Janine

    2015-12-01

    Accumulating evidence demonstrates that humans and other animals use geometric information, such as the shape of a surrounding space, to recover from disorientation. Less clear is to what extent human children integrate geometry with featural cues, such as the color of walls within an enclosed space, for this purpose. One view holds that reorientation relies on a cognitive module that processes geometric information independently of features. Here we provide evidence against this position by demonstrating that prior exposure to features within a kite-shaped space facilitated the use of geometry in 3- and 4-year-old children, as has been shown with nonhuman animals. Children were tasked with localizing a hidden object within a kite space following disorientation. Their performance was compared across two blocks of trials. We found that children first exposed to features (two black walls and two white walls) within the kite space (first block) were subsequently better at relying on the space's geometry to localize the target object (second block) than children not previously exposed to features. Follow-up experiments ruled out nonspecific effects of practice and attention. Not only did featural cues interact with the processing of geometry, but also features specifically enhanced children's representations of the space's geometry, which they used for reorientation. We suggest that this potentiation of geometry was possible because the placement of wall colors highlighted the major axis of the kite space, which may be critical for aiding the encoding of global shape or for maintaining the representation of a complex geometry in memory.

  11. Oscillatory and fluctuating terms in energies of assemblies of equicharged particles subject to spherically symmetric power-law confining potentials.

    PubMed

    Cioslowski, Jerzy; Albin, Joanna

    2013-09-14

    Energies E(N) of assemblies of equicharged particles subject to spherically symmetric power-law confining potentials vary in a convoluted fashion with the particle totalities N. Accurate rigorous upper bounds to these energies, which are amenable to detailed mathematical analysis, are found to comprise terms with smooth, oscillatory, and fluctuating dependences on N. The smooth energy component is obtained as a power series in N(-2/3) with the first two terms corresponding to the bulk and Madelung energies. The oscillatory component possesses the large-N asymptotics given by a product of N(1/(λ + 1)), where λ is the power-law exponent, and a function periodic in N(1/3). The amplitude of the fluctuating component, which originates mostly from the irregular dependence of the Thomson energy E(Th)(n) on n, also scales like N(1/(λ + 1)).

  12. Relativistic bounds states for a neutral particle confined to a parabolic potential induced by noninertial effects

    NASA Astrophysics Data System (ADS)

    Bakke, K.

    2010-10-01

    We obtain the solutions of the Dirac equation when the noninertial effects of the Fermi-Walker reference frame break the relativistic Landau-Aharonov-Casher quantization, but they provide bound states in an analogous way to a Dirac neutral particle subject to Tan-Inkson quantum dot potential [W.-C. Tan, J.C. Inkson, Semicond. Sci. Technol. 11 (1996) 1635].

  13. Overdamped motion of interacting particles in general confining potentials: time-dependent and stationary-state analyses

    NASA Astrophysics Data System (ADS)

    Ribeiro, M. S.; Nobre, F. D.; Curado, E. M. F.

    2012-12-01

    By comparing numerical and analytical results, it is shown that a system of interacting particles under overdamped motion is very well described by a nonlinear Fokker-Planck equation, which can be associated with nonextensive statistical mechanics. The particle-particle interactions considered are repulsive, motivated by three different physical situations: (i) modified Bessel function, commonly used in vortex-vortex interactions, relevant for the flux-front penetration in disordered type-II superconductors; (ii) Yukawa-like forces, useful for charged particles in plasma, or colloidal suspensions; (iii) derived from a Gaussian potential, common in complex fluids, like polymer chains dispersed in a solvent. Moreover, the system is subjected to a general confining potential, φ( x) = ( α| x| z )/ z ( α > 0 , z > 1), so that a stationary state is reached after a sufficiently long time. Recent numerical and analytical investigations, considering interactions of type (i) and a harmonic confining potential ( z = 2), have shown strong evidence that a q-Gaussian distribution, P( x,t), with q = 0, describes appropriately the particle positions during their time evolution, as well as in their stationary state. Herein we reinforce further the connection with nonextensive statistical mechanics, by presenting numerical evidence showing that: (a) in the case z = 2, different particle-particle interactions only modify the diffusion parameter D of the nonlinear Fokker-Planck equation; (b) for z ≠ 2, all cases investigated fit well the analytical stationary solution P st( x), given in terms of a q-exponential (with the same index q = 0) of the general external potential φ( x). In this later case, we propose an approximate time-dependent P( x,t) (not known analytically for z ≠ 2), which is in very good agreement with the simulations for a large range of times, including the approach to the stationary state. The present work suggests that a wide variety of physical phenomena

  14. Viscous properties of isotropic fluids composed of linear molecules: departure from the classical Navier-Stokes theory in nano-confined geometries.

    PubMed

    Hansen, J S; Daivis, Peter J; Todd, B D

    2009-10-01

    In this paper we present equilibrium molecular-dynamics results for the shear, rotational, and spin viscosities for fluids composed of linear molecules. The density dependence of the shear viscosity follows a stretched exponential function, whereas the rotational viscosity and the spin viscosities show approximately power-law dependencies. The frequency-dependent shear and spin viscosities are also studied. It is found that viscoelastic behavior is first manifested in the shear viscosity and that the real part of the spin viscosities features a maximum for nonzero frequency. The calculated transport coefficients are used together with the extended Navier-Stokes equations to investigate the effect of the coupling between the intrinsic angular momentum and linear momentum for highly confined fluids. Both steady and oscillatory flows are studied. It is shown, for example, that the fluid flow rate for Poiseuille flow is reduced by up to 10% in a 2 nm channel for a buta-triene fluid at density 236 kg m(-3) and temperature 306 K. The coupling effect may, therefore, become very important for nanofluidic applications.

  15. Preliminary potential-field constraints on the geometry of the San Fernando basin, Southern California

    USGS Publications Warehouse

    Langenheim, V.E.; Griscom, Andrew; Jachens, R.C.; Hildenbrand, T.G.

    2000-01-01

    Gravity and magnetic data provide new insights on the structural underpinnings of the San Fernando Basin region, which may be important to ground motion models. Gravity data indicate that a deep basin (>5 km) underlies the northern part of the San Fernando Valley; this deep basin is required to explain the lowest gravity values over the Mission Hills thrust fault. Gravity modeling, constrained by well data and density information, shows that the basin may reach a thickness of 8 km, coinciding with the upper termination of the 1994 Northridge earthquake mainshock rupture. The basin is deeper than previous estimates by 2 to 4 km; this estimate is the result of high densities for the gravels of the Pliocene-Pleisocene Saugus Formation. The geometry of the southern margin of the deep basin is not well-constrained by the gravity data, but may dip to the south. Recently acquired seismic data along the LARSE (Los Angeles Regional Seismic Experiment) II profile may provide constraints to determine the location and attitude of the basin edge. Gravity and aeromagnetic models across the eastern margin of the San Fernando Valley indicate that the Verdugo fault may dip to the southwest along its southern extent and therefore have a normal fault geometry whereas it clearly has a thrust fault geometry along its northern strand.

  16. Architectural variability of confined turbidite sheet-sands: facies, geometry and infill of associated elementary channels. Examples from the Trois Evêchés Basin, Annot Sandstone Formation, SE France

    NASA Astrophysics Data System (ADS)

    Etienne, S.; Mulder, T.; Pace, A.; Bez, M.; Desaubliaux, G.

    2012-04-01

    The worldwide known Annot Sandstone Formation has been considered as a reference of confined siliciclastic turbidite system. This formation crops out in SE France and represents the Upper Eocene to Lower Oligocene gravitary infill of complex foreland basins, developed in front of the Alpine thrusts. This system can be assimilated as a sand-rich turbidite ramp, sourced by multiple fan deltas leading to topographically complex sub-basins. Highly bypassing channelized systems dominate in the most proximal and most confined areas. They distally evolve to relatively less confined areas, in which sedimentary bodies appear to be more continuous and homogenous on a regional scale. These last architectural elements, defined as sheet-sands or depositional lobes, have been the focus of this study in poorly documented areas. From an important dataset made of very high resolution outcrop correlations (gathered mainly in the Trois Evêchés and Lauzanier sub-basins), we have quantified the complex distribution of sedimentary facies and structures, grain-size and key surfaces in sand-rich sheets. This was done to understand their variability from depositional event to architectural element scales and to better characterize dimensions and characteristics of their components. Six main types of architectural elements were defined, composed of both channelized and unchannelized elements. Channelized units show a high variability in terms of facies, geometry and patterns of infill that are related to multiple erosional and depositional processes, which will be discussed. We notably relate some evidences of sinuous channels, represented by lateral accretion deposits in the channel complex axis and by low angle cross-bedded facies. We interpret this particular facies as the result of flow deconfinement and overbanks above channel margins. The stratigraphic analysis of elementary objects allows us to propose a genetic model and a spatial distribution model of sheet-sand architectural

  17. Influence of the radial profile of the electric potential on the confinement of a high-{beta} two-component plasma in a gas-dynamic trap

    SciTech Connect

    Soldatkina, E. I.; Bagryansky, P. A.; Solomakhin, A. L.

    2008-04-15

    One of the most important problems to be studied in the gas-dynamic trap (GDT) facility is the investigation of MHD stability and cross-field transport in a plasma with a relatively high value of {beta} = {pi}p/B{sup 2}. Recent experiments demonstrated that the radial electric field produced in the plasma by using radial limiters and coaxial end plasma collectors improves plasma stability in axisymmetric magnetic mirror systems without applying special MHD stabilizers. The experimental data presented in this work show that stable plasma confinement can be achieved by producing a radial potential drop across a narrow region near the plasma boundary. Creating radial electric fields of strength 15-40 V/cm causes a shear plasma flow, thereby substantially increasing the plasma confinement time. When all the radial electrodes were grounded, the confinement was unstable and the plasma confinement time was much shorter than the characteristic time of plasma outflow through the magnetic mirrors. Measurements of cross-field plasma fluxes with the use of a specially designed combined probe show that, in confinement modes with differential plasma rotation, transverse particle losses are negligibly small as compared to longitudinal ones and thus can be ignored. It is also shown that, when the GDT plasma is in electric contact with the radial limiters and end collectors, the growth rate of interchange instability decreases considerably; such a contact, however, does not ensure complete MHD stability when the electrodes are at the same potential.

  18. Phase transitions in normal mode spectra of two-dimensional clusters in an anisotropic power-law confining potential

    NASA Astrophysics Data System (ADS)

    Bessaa, Assia; Djebli, Mourad

    2017-02-01

    We present a numerical analysis of several phase transitions which take place in the eigenmode spectrum of a two-dimensional (2D) logarithmic cluster subjected to an anisotropic power law confinement. Varying the anisotropy in a non-parabolic soft confinement drives the system to undergo structural phase transitions of first order, while for a hard wall confinement this variation affects strongly the eigenmode spectrum and breaks the symmetry of the system due to the removal of degeneracy and the coupling between some normal modes.

  19. Computational issues of importance to the inverse recovery of epicardial potentials in a realistic heart-torso geometry.

    PubMed

    Messinger-Rapport, B J; Rudy, Y

    1989-11-01

    In vitro data from a realistic-geometry electrolytic tank were used to demonstrate the consequences of computational issues critical to the ill-posed inverse problem in electrocardiography. The boundary element method was used to discretize the relationship between the body surface potentials and epicardial cage potentials. Variants of Tikhonov regularization were used to stabilize the inversion of the body surface potentials in order to reconstruct the epicardial surface potentials. The computational issues investigated were (1) computation of the regularization parameter; (2) effects of inaccuracy in locating the position of the heart; and (3) incorporation of a priori information on the properties of epicardial potentials into the regularization methodology. Two methods were suggested by which a priori information could be incorporated into the regularization formulation: (1) use of an estimate of the epicardial potential distribution everywhere on the surface and (2) use of regional bounds on the excursion of the potential. Results indicate that the a posteriori technique called CRESO, developed by Colli Franzone and coworkers, most consistently derives the regularization parameter closest to the optimal parameter for this experimental situation. The sensitivity of the inverse computation in a realistic-geometry torso to inaccuracies in estimating heart position are consistent with results from the eccentric spheres model; errors of 1 cm are well tolerated, but errors of 2 cm or greater result in a loss of position and amplitude information. Finally, estimates and bounds based on accurate, known information successfully lower the relative error associated with the inverse and have the potential to significantly enhance the amplitude and feature position information obtainable from the inverse-reconstructed epicardial potential map.

  20. On the Rotating Effects and the Landau-Aharonov-Casher System Subject to a Hard-Wall Confining Potential in the Cosmic String Spacetime

    NASA Astrophysics Data System (ADS)

    Bakke, K.

    2015-07-01

    The behaviour of the Landau-Aharonov-Casher system is discussed by showing a case where the external electric field cannot yield the Landau-Aharonov-Casher quantization under the influence of rotating effects in the cosmic string spacetime, but it can yield bound states solutions to the Schrödinger-Pauli equation analogous to having the Landau-Aharonov-Casher system confined to a hard-wall confining potential under the influence of rotating effects and the topology of the cosmic string spacetime (by assuming ω ρ≪1 and neglecting the effects of a gravitational self-force on the particle).

  1. Quasi-exactly-solvable confining solutions for spin-1 and spin-0 bosons in (1+1)-dimensions with a scalar linear potential

    SciTech Connect

    Castro, Luis B.; Castro, Antonio S. de

    2014-12-15

    We point out a misleading treatment in the recent literature regarding confining solutions for a scalar potential in the context of the Duffin–Kemmer–Petiau theory. We further present the proper bound-state solutions in terms of the generalized Laguerre polynomials and show that the eigenvalues and eigenfunctions depend on the solutions of algebraic equations involving the potential parameter and the quantum number.

  2. NASA Ames potential flow analysis (POTFAN) geometry program (POTGEM), version 1

    NASA Technical Reports Server (NTRS)

    Medan, R. T.; Bullock, R. B.

    1976-01-01

    A computer program known as POTGEM is reported which has been developed as an independent segment of a three-dimensional linearized, potential flow analysis system and which is used to generate a panel point description of arbitrary, three-dimensional bodies from convenient engineering descriptions consisting of equations and/or tables. Due to the independent, modular nature of the program, it may be used to generate corner points for other computer programs.

  3. Generating end plug potentials in tandem mirror plasma confinement by heating thermal particles so as to escape low density end stoppering plasmas

    DOEpatents

    Baldwin, D.E.; Logan, B.G.

    The invention provides a method and apparatus for raising the potential of a magnetic mirror cell by pumping charged particles of the opposite sign of the potential desired out of the mirror cell through excitation, with the pumping being done by an externally imposed field at the bounce frequence of the above charged particles. These pumped simple mirror cells then provide end stoppering for a center mirror cell for the tandem mirror plasma confinement apparatus. For the substantially complete pumping case, the end plugs of a tandem mirror can be up to two orders of magnitude lower in density for confining a given center mirror cell plasma than in the case of end plugs without pumping. As a result the decrease in recirculating power required to keep the system going, the technical state of the art required, and the capital cost are all greatly lowered.

  4. Generating end plug potentials in tandem mirror plasma confinement by heating thermal particles so as to escape low density end stoppering plasmas

    DOEpatents

    Baldwin, David E.; Logan, B. Grant

    1981-01-01

    The invention provides a method and apparatus for raising the potential of a magnetic mirror cell by pumping charged particles of the opposite sign of the potential desired out of the mirror cell through excitation, with the pumping being done by an externally imposed field at the bounce frequency of the above charged particles. These pumped simple mirror cells then provide end stoppering for a center mirror cell for the tandem mirror plasma confinement apparatus. For the substantially complete pumping case, the end plugs of a tandem mirror can be up to two orders of magnitude lower in density for confining a given center mirror cell plasma than in the case of end plugs without pumping. As a result the decrease in recirculating power required to keep the system going, the technological state of the art required, and the capital cost are all greatly lowered.

  5. Scalar perturbation potentials in a homogeneous and isotropic Weitzenböck geometry

    NASA Astrophysics Data System (ADS)

    Behboodi, A.; Akhshabi, S.; Nozari, K.

    2016-05-01

    We describe the fully gauge invariant cosmological perturbation equations in teleparallel gravity by using the gauge covariant version of the Stewart lemma for obtaining the variations in tetrad perturbations. In teleparallel theory, perturbations are the result of small fluctuations in the tetrad field. The tetrad transforms as a vector in both its holonomic and anholonomic indices. As a result, in the gauge invariant formalism, physical degrees of freedom are those combinations of perturbation parameters which remain invariant under a diffeomorphism in the coordinate frame, followed by an arbitrary rotation of the local inertial (Lorentz) frame. We derive these gauge invariant perturbation potentials for scalar perturbations and present the gauge invariant field equations governing their evolution.

  6. Simulations of Enhanced Confinement

    NASA Astrophysics Data System (ADS)

    Dorland, W.; Kotschenreuther, M.; Liu, Q. P.; Jones, C. S.; Beer, M. A.; Hammett, G. W.

    1996-11-01

    Most existing tokamaks routinely achieve enhanced confinement regimes. Designs for new, larger tokamaks therefore are typically predicated upon reliable enhanced confinement performance. However, most enhanced confinement regimes rely (to some degree) upon sheared E×B flows to stabilize the turbulence that otherwise limits the confinement. For example, the pedestal H-mode transport barrier is typically attributed to shear stabilization [Biglari, Diamond and Terry, Phys. Fl. B, 2 1 (1990)]. Unfortunately, it is easily shown that sheared E×B stabilization of microinstabilities such as the ITG mode does not scale favorably with machine size. Here, using nonlinear gyrofluid simulations in general geometry, we attempt to quantify the confinement enhancement that can be expected from velocity shear stabilization for conventional reactor plasmas. We also consider other microinstability stabilization mechanisms(See related presentations by Beer, Kotschenreuther, Manickam, and Ramos, this conference.) (strong density peaking, Shafranov shift stabilization, dots) and unconventional reactor configurations.^2 Experimental datasets from JET, DIII-D, C-Mod and TFTR are analyzed, and ITER operation is considered.

  7. Relativistically corrected geometries obtained with analytical gradients: normalized elimination of the small component using an effective potential

    NASA Astrophysics Data System (ADS)

    Filatov, Michael; Cremer, Dieter

    2003-03-01

    For the quasi-relativistic normalized elimination of small component using an effective potential (NESC-EP) method, analytical energy gradients were developed, programmed, and implemented in a standard quantum chemical program package. NESC-EP with analytical gradients was applied to determine geometry, vibrational frequencies, and dissociation enthalpies of ferrocene, tungsten hexafluoride, and tungsten hexacarbonyle. Contrary to non-relativistic calculations and calculations carried out with RECPs for the same compounds, NESC-EP provided reliable molecular properties in good agreement with experiment. The computational power of NESC-EP results from the fact that reliable relativistic corrections are obtained at a cost level only slightly larger than that of a non-relativistic calculation.

  8. System of fermions confined in a harmonic potential and subject to a magnetic field or a rotational motion

    SciTech Connect

    Naiedja, H.; Quentin, P.; Bartel, J.

    2011-05-15

    Making use of the Bloch density matrix technique, we derive exact analytical expressions for the density profile in Fourier space, for the current density and the so-called integrated current for fermionic systems confined by a two-dimensional harmonic oscillator, in the presence of a magnetic field or in a rotating trap of arbitrary strength. We present numerical, illustrative examples with or without magnetic field (with or without rotation).

  9. Edge states in confined active fluids

    NASA Astrophysics Data System (ADS)

    Souslov, Anton; Vitelli, Vincenzo

    Recently, topologically protected edge modes have been proposed and realized in both mechanical and acoustic metamaterials. In one class of such metamaterials, Time-Reversal Symmetry is broken, and, to achieve this TRS breaking in mechanical and acoustic systems, an external energy input must be used. For example, motors provide a driving force that uses energy and, thus, explicitly break TRS. As a result, motors have been used as an essential component in the design of topological metamaterials. By contrast, we explore the design of topological metamaterials that use a class of far-from-equilibrium liquids, called polar active liquids, that spontaneously break TRS. We thus envision the confinement of a polar active liquid to a prescribed geometry in order to realize topological order with broken time-reversal symmetry. We address the design of the requisite geometries, for example a regular honeycomb lattice composed of annular channels, in which the active liquid may be confined. We also consider the physical character of the active liquid that, when introduced into the prescribed geometry, will spontaneously form the flow pattern of a metamaterial with topologically protected edge states. Finally, we comment on potential experimental realizations of such metamaterials.

  10. Design of specially adapted reactive coordinates to economically compute potential and kinetic energy operators including geometry relaxation

    NASA Astrophysics Data System (ADS)

    Thallmair, Sebastian; Roos, Matthias K.; de Vivie-Riedle, Regina

    2016-06-01

    Quantum dynamics simulations require prior knowledge of the potential energy surface as well as the kinetic energy operator. Typically, they are evaluated in a low-dimensional subspace of the full configuration space of the molecule as its dimensionality increases proportional to the number of atoms. This entails the challenge to find the most suitable subspace. We present an approach to design specially adapted reactive coordinates spanning this subspace. In addition to the essential geometric changes, these coordinates take into account the relaxation of the non-reactive coordinates without the necessity of performing geometry optimizations at each grid point. The method is demonstrated for an ultrafast photoinduced bond cleavage in a commonly used organic precursor for the generation of electrophiles. The potential energy surfaces for the reaction as well as the Wilson G-matrix as part of the kinetic energy operator are shown for a complex chemical reaction, both including the relaxation of the non-reactive coordinates on equal footing. A microscopic interpretation of the shape of the G-matrix elements allows to analyze the impact of the non-reactive coordinates on the kinetic energy operator. Additionally, we compare quantum dynamics simulations with and without the relaxation of the non-reactive coordinates included in the kinetic energy operator to demonstrate its influence.

  11. Design of specially adapted reactive coordinates to economically compute potential and kinetic energy operators including geometry relaxation.

    PubMed

    Thallmair, Sebastian; Roos, Matthias K; de Vivie-Riedle, Regina

    2016-06-21

    Quantum dynamics simulations require prior knowledge of the potential energy surface as well as the kinetic energy operator. Typically, they are evaluated in a low-dimensional subspace of the full configuration space of the molecule as its dimensionality increases proportional to the number of atoms. This entails the challenge to find the most suitable subspace. We present an approach to design specially adapted reactive coordinates spanning this subspace. In addition to the essential geometric changes, these coordinates take into account the relaxation of the non-reactive coordinates without the necessity of performing geometry optimizations at each grid point. The method is demonstrated for an ultrafast photoinduced bond cleavage in a commonly used organic precursor for the generation of electrophiles. The potential energy surfaces for the reaction as well as the Wilson G-matrix as part of the kinetic energy operator are shown for a complex chemical reaction, both including the relaxation of the non-reactive coordinates on equal footing. A microscopic interpretation of the shape of the G-matrix elements allows to analyze the impact of the non-reactive coordinates on the kinetic energy operator. Additionally, we compare quantum dynamics simulations with and without the relaxation of the non-reactive coordinates included in the kinetic energy operator to demonstrate its influence.

  12. Seismic-Reflection Technology Defines Potential Vertical Bypass in Hydrogeologic Confinement within Tertiary Carbonates of the Southeastern Florida Platform

    NASA Astrophysics Data System (ADS)

    Cunningham, K. J.; Walker, C.; Westcott, R. L.

    2011-12-01

    Continuous improvements in shallow-focused, high-resolution, marine seismic-reflection technology has provided the opportunity to evaluate geologic structures that breach confining units of the Floridan aquifer system within the southeastern Florida Platform. The Floridan aquifer system is comprised mostly of Tertiary platform carbonates. In southeastern Florida, hydrogeologic confinement is important to sustainable use of the Floridan aquifer system, where the saline lower part is used for injection of wastewater and the brackish upper part is an alternative source of drinking water. Between 2007 and 2011, approximately 275 km of 24- and 48-channel seismic-reflection profiles were acquired in canals of peninsular southeastern Florida, Biscayne Bay, present-day Florida shelf margin, and the deeply submerged Miami Terrace. Vertical to steeply dipping offsets in seismic reflections indicate faults, which range from Eocene to possible early Pliocene age. Most faults are associated with karst collapse structures; however, a few tectonic faults of early Miocene to early Pliocene age are present. The faults may serve as a pathway for vertical groundwater flow across relatively low-permeability carbonate strata that separate zones of regionally extensive high-permeability in the Floridan aquifer system. The faults may collectively produce a regional confinement bypass system. In early 2011, twenty seismic-reflection profiles were acquired near the Key Biscayne submarine sinkhole located on the seafloor of the Miami Terrace. Here the water depth is about 365 m. A steeply dipping (eastward) zone of mostly deteriorated quality of seismic-reflection data underlies the sinkhole. Correlation of coherent seismic reflections within and adjacent to the disturbed zone indicates a series of faults occur within the zone. It is hypothesized that upward movement of groundwater within the zone contributed to development of a hypogenic karst system and the resultant overlying sinkhole

  13. Methods for two-dimensional cell confinement.

    PubMed

    Le Berre, Maël; Zlotek-Zlotkiewicz, Ewa; Bonazzi, Daria; Lautenschlaeger, Franziska; Piel, Matthieu

    2014-01-01

    Protocols described in this chapter relate to a method to dynamically confine cells in two dimensions with various microenvironments. It can be used to impose on cells a given height, with an accuracy of less than 100 nm on large surfaces (cm(2)). The method is based on the gentle application of a modified glass coverslip onto a standard cell culture. Depending on the preparation, this confinement slide can impose on the cells a given geometry but also an environment of controlled stiffness, controlled adhesion, or a more complex environment. An advantage is that the method is compatible with most optical microscopy technologies and molecular biology protocols allowing advanced analysis of confined cells. In this chapter, we first explain the principle and issues of using these slides to confine cells in a controlled geometry and describe their fabrication. Finally, we discuss how the nature of the confinement slide can vary and provide an alternative method to confine cells with gels of controlled rigidity.

  14. Preliminary identification of potentially disruptive scenarios at the Greater Confinement Disposal Facility, Area 5 of the Nevada Test Site

    SciTech Connect

    Guzowski, R.V.; Newman, G.

    1993-12-01

    The Greater Confinement Disposal location is being evaluated to determine whether defense-generated transuranic waste buried at this location complies with the Containment Requirements established by the US Environmental Protection Agency. One step in determining compliance is to identify those combinations of events and processes (scenarios) that define possible future states of the disposal system for which performance assessments must be performed. An established scenario-development procedure was used to identify a comprehensive set of mutually exclusive scenarios. To assure completeness, 761 features, events, processes, and other listings (FEPS) were compiled from 11 references. This number was reduced to 205 primarily through the elimination of duplications. The 205 FEPs were screened based on site-specific, goal-specific, and regulatory criteria. Four events survived screening and were used in preliminary scenario development: (1) exploratory drilling penetrates a GCD borehole, (2) drilling of a withdrawal/injection well penetrates a GCD borehole, (3) subsidence occurs at the RWMS, and (4) irrigation occurs at the RWMS. A logic diagram was used to develop 16 scenarios from the four events. No screening of these scenarios was attempted at this time. Additional screening of the currently retained events and processes will be based on additional data and information from site-characterization activities. When screening of the events and processes is completed, a final set of scenarios will be developed and screened based on consequence and probability of occurrence.

  15. Alterations in streaming potential in presence of time periodic pressure-driven flow of a power law fluid in narrow confinements with nonelectrostatic ion-ion interactions.

    PubMed

    Dhar, Jayabrata; Ghosh, Uddipta; Chakraborty, Suman

    2014-03-01

    We study the coupled effect of electrokinetic phenomena and fluid rheology in altering the induced streaming potential in narrow fluidic confinements, which is manifested by establishing a time periodic pressure-driven flow in presence of electrical double layer phenomenon. However, in sharp contrast with reported literature, we take into account nonelectrostatic ion-ion interactions toward estimating the same in addition to electrostatic interactions and steric effects. We employ power law based rheological model for estimating the induced streaming potential. We bring out an intricate interaction between nonelectrostatic interactions and fluid rheology on the concerned electrokinetic phenomena, bearing immense consequences toward designing of integrated lab-on-a-chip-based microdevices and nanodevices.

  16. Confined Brownian ratchets

    NASA Astrophysics Data System (ADS)

    Malgaretti, Paolo; Pagonabarraga, Ignacio; Rubi, J. Miguel

    2013-05-01

    We analyze the dynamics of Brownian ratchets in a confined environment. The motion of the particles is described by a Fick-Jakobs kinetic equation in which the presence of boundaries is modeled by means of an entropic potential. The cases of a flashing ratchet, a two-state model, and a ratchet under the influence of a temperature gradient are analyzed in detail. We show the emergence of a strong cooperativity between the inherent rectification of the ratchet mechanism and the entropic bias of the fluctuations caused by spatial confinement. Net particle transport may take place in situations where none of those mechanisms leads to rectification when acting individually. The combined rectification mechanisms may lead to bidirectional transport and to new routes to segregation phenomena. Confined Brownian ratchets could be used to control transport in mesostructures and to engineer new and more efficient devices for transport at the nanoscale.

  17. Energies and densities of electrons confined in elliptical and ellipsoidal quantum dots

    NASA Astrophysics Data System (ADS)

    Halder, Avik; Kresin, Vitaly V.

    2016-10-01

    We consider a droplet of electrons confined within an external harmonic potential well of elliptical or ellipsoidal shape, a geometry commonly encountered in work with semiconductor quantum dots and other nanoscale or mesoscale structures. For droplet sizes exceeding the effective Bohr radius, the dominant contribution to average system parameters in the Thomas-Fermi approximation comes from the potential energy terms, which allows us to derive expressions describing the electron droplet’s shape and dimensions, its density, total and capacitive energy, and chemical potential. The analytical results are in very good agreement with experimental data and numerical calculations, and make it possible to follow the dependence of the properties of the system on its parameters (the total number of electrons, the axial ratios and curvatures of the confinement potential, and the dielectric constant of the material). An interesting feature is that the eccentricity of the electron droplet is not the same as that of its confining potential well.

  18. Composite mesostructures by nano-confinement.

    PubMed

    Wu, Yiying; Cheng, Guosheng; Katsov, Kirill; Sides, Scott W; Wang, Jianfang; Tang, Jing; Fredrickson, Glenn H; Moskovits, Martin; Stucky, Galen D

    2004-11-01

    In a physically confined environment, interfacial interactions, symmetry breaking, structural frustration and confinement-induced entropy loss can play dominant roles in determining molecular organization. Here we present a systematic study of the confined assembly of silica-surfactant composite mesostructures within cylindrical nanochannels of varying diameters. Using exactly the same precursors and reaction conditions that form the two-dimensional hexagonal SBA-15 mesostructured thin film, unprecedented silica mesostructures with chiral mesopores such as single- and double-helical geometries spontaneously form inside individual alumina nanochannels. On tightening the degree of confinement, a transition is observed in the mesopore morphology from a coiled cylindrical to a spherical cage-like geometry. Self-consistent field calculations carried out to account for the observed mesostructures accord well with experiment. The mesostructures produced by confined syntheses are useful as templates for fabricating highly ordered mesostructured nanowires and nanowire arrays.

  19. Lorentz-covariant quantum 4-potential and orbital angular momentum for the transverse confinement of matter waves

    NASA Astrophysics Data System (ADS)

    Ducharme, R.; da Paz, I. G.

    2016-08-01

    In two recent papers exact Hermite-Gaussian solutions to relativistic wave equations were obtained for both electromagnetic and particle beams. The solutions for particle beams correspond to those of the Schrödinger equation in the nonrelativistic limit. Here, it will be shown that each beam particle has additional 4-momentum resulting from transverse localization compared to a free particle traveling in the same direction as the beam with the same speed. This will be referred to as the quantum 4-potential term since it will be shown to play an analogous role in relativistic Hamiltonian quantum mechanics as the Bohm potential in the nonrelativistic quantum Hamilton-Jacobi equation. Low-order localization effects include orbital angular momentum, Gouy phase, and beam spreading. Toward a more systematic approach for calculating localization effects at all orders, it will be shown that both the electromagnetic and quantum 4-potentials couple into the canonical 4-momentum of a particle in a similar way. This offers the prospect that traditional methods used to calculate the affect of an electromagnetic field on a particle can now be adapted to take localization effects into account. The prospects for measuring higher order quantum 4-potential related effects experimentally are also discussed alongside some questions to challenge the quantum information and quantum field theorists.

  20. Quark confinement potential examined by excitation energy of the Λc and Λb baryons in a quark-diquark model

    NASA Astrophysics Data System (ADS)

    Jido, Daisuke; Sakashita, Minori

    2016-08-01

    The possibility of having a diquark configuration in heavy baryons, such as Λ and Λ, is examined by a nonrelativistic potential model with a heavy quark and a light scalar diquark. Assuming that the Λ and Λ baryons are composed of the heavy quark and the point-like scalar-isoscalar ud diquark, we solve the two-body Schrödinger equation with the Coulomb plus linear potential and obtain the energy spectra for the heavy baryons. Contrary to our expectation, it is found that the potential determined by the quarkonium spectra fails to reproduce the excitation spectra of the Λ and Λ in the quark-diquark picture, while the Λ and Λ spectra are reproduced with half the strength of the confinement string tension than for the quarkonium. The finite size effect of the diquark is also examined and it is found that the introduction of a finite size diquark would resolve the failure of the spectrum reproduction. The Ξ excitation energy is also calculated and is found to be smaller than Λ in the quark-diquark model. This is not consistent with experimental observations.

  1. Developments in special geometry

    NASA Astrophysics Data System (ADS)

    Mohaupt, Thomas; Vaughan, Owen

    2012-02-01

    We review the special geometry of Script N = 2 supersymmetric vector and hypermultiplets with emphasis on recent developments and applications. A new formulation of the local c-map based on the Hesse potential and special real coordinates is presented. Other recent developments include the Euclidean version of special geometry, and generalizations of special geometry to non-supersymmetric theories. As applications we disucss the proof that the local r-map and c-map preserve geodesic completeness, and the construction of four- and five-dimensional static solutions through dimensional reduction over time. The shared features of the real, complex and quaternionic version of special geometry are stressed throughout.

  2. Diffusing Polymers in Confined Microdomains and Estimation of Chromosomal Territory Sizes from Chromosome Capture Data

    NASA Astrophysics Data System (ADS)

    Amitai, A.; Holcman, D.

    2013-06-01

    Is it possible to extract the size and structure of chromosomal territories (confined domain) from the encounter frequencies of chromosomal loci? To answer this question, we estimate the mean time for two monomers located on the same polymer to encounter, which we call the mean first encounter time in a confined microdomain (MFETC). We approximate the confined domain geometry by a harmonic potential well and obtain an asymptotic expression that agrees with Brownian simulations for the MFETC as a function of the polymer length, the radius of the confined domain, and the activation distance radius ɛ at which the two searching monomers meet. We illustrate the present approach using chromosome capture data for the encounter rate distribution of two loci depending on their distances along the DNA. We estimate the domain size that restricts the motion of one of these loci for chromosome II in yeast.

  3. Confined helium on Lagrange meshes.

    PubMed

    Baye, D; Dohet-Eraly, J

    2015-12-21

    The Lagrange-mesh method has the simplicity of a calculation on a mesh and can have the accuracy of a variational method. It is applied to the study of a confined helium atom. Two types of confinement are considered. Soft confinements by potentials are studied in perimetric coordinates. Hard confinement in impenetrable spherical cavities is studied in a system of rescaled perimetric coordinates varying in [0,1] intervals. Energies and mean values of the distances between electrons and between an electron and the helium nucleus are calculated. A high accuracy of 11 to 15 significant figures is obtained with small computing times. Pressures acting on the confined atom are also computed. For sphere radii smaller than 1, their relative accuracies are better than 10(-10). For larger radii up to 10, they progressively decrease to 10(-3), still improving the best literature results.

  4. A reactive transport model for the geochemical response, detection and potential mitigation of CO2 leakage into a confined aquifer

    NASA Astrophysics Data System (ADS)

    Maher, K.; Druhan, J. L.; Vialle, S.; Benson, S. M.; Agarwal, A.

    2013-12-01

    Long-term storage of anthropogenic CO2 in the subsurface generally assumes that caprock formations will serve as physical barriers to upward migration of CO2. Stability and coherence of the caprocks are thus important criteria for site selection, but caprock integritycannot be guaranteed with total certainty over the lifetime of the project. As a result, carbon capture and storage projects require reliable techniques to monitor geologic storage sites for newly formed leaks, and the ability to rapidly deploy mitigation measures should leakage occur. Here, we present two-dimensional reactive transport simulations to evaluate the hydrogeochemical characteristics of a newly formed CO2 leak into an overlying reservoir. Simulations use the ToughReact multi-component reactive transport code and hypothetical reservoir characteristics. We focus on the comparatively short time period of days to months following formation of the leak to consider (1) geochemical shifts in formation water indicative of the leak, (2) hydrodynamics of pumping wells in the vicinity of the leak, and (3) delivery of a sealant to the leak through an adjacent well bore. Our results suggest that characteristic shifts in pH and dissolved inorganic carbon might be detected in down-gradient mentoring wells prior to the breakthrough of CO2, and could offer a potential means of identifying small and newly formed leaks. Injecting water into the aquifer through pumping wells in the vicinity of the leak provides a hydrodynamic control that can prevent CO2 from reaching the top of the reservoir, but this action will likely have only minor influence on the rate of leakage through the caprock defect. Injection of a hypothetical sealant through an adjacent pumping well is considered using an aqueous solute with pH-dependent equilibrium constraints such that the species is soluble in the basic pH range but forms a precipitate at neutral to acidic pH conditions associated with CO2-rich water. Injection of this

  5. Effects of confinement on the thermodynamics of supercooled water

    NASA Astrophysics Data System (ADS)

    Strekalova, Elena G.

    The main focus of this thesis is to understand how confinement alters the phase diagram of supercooled liquid water by employing methods of statistical mechanics and numerical simulations. Water is very complex and anomalous when compared to simple liquids. For example, experimental data for liquid water reveals the presence of a temperature of maximum density (TMD) below which the density decreases under isobaric cooling. Another anomaly is the hypothesized liquid--liquid phase transition (LLPT) between two types of liquid water with different densities. In this thesis we study how confinement affects such anomalies as TMD and LLPT in supercooled liquid water. This thesis is separated into three parts: (i) Monte Carlo simulations of a 2D coarse-grained model of a water layer confined in a fixed disordered matrix of hydrophobic nanoparticles, (ii) molecular dynamics simulations of a Jagla ramp model of liquid confined in fixed ordered and disordered matrices of hydrophobic nanoparticles, and (iii) all-atom simulations of trehalose and maltose in aqueous solution of lysozyme. In Part (i), we perform Monte Carlo simulations and find that a nanoparticle concentration as small as 2.4% is enough to destroy the LLPT for pressure P > 0.14 GPa. Moreover, we find a substantial (more than 90%) decrease of compressibility, thermal expansion coefficient and specific heat at high P and low temperature T upon increase of nanoparticle concentration from 0% to 25%. In Part (ii), we ask how, for single component systems interacting via a soft-core isotropic potential with two characteristic length scales, the geometry of hydrophobic confinement affects the phase diagram. We use molecular dynamics simulations to study particles interacting through a ramp potential and a shoulder potential, each confined in a fixed matrix of nanoscopic particles with a fixed volume fraction. We find a substantial weakening of the LLPT and the disappearance of TMD upon the increase of disorder in the

  6. Semiflexible chains in confined spaces

    NASA Astrophysics Data System (ADS)

    Morrison, Greg; Thirumalai, D.

    2009-01-01

    We develop an analytical method for studying the properties of a noninteracting wormlike chain (WLC) in confined geometries. The mean-field-like theory replaces the rigid constraints of confinement with average constraints, thus allowing us to develop a tractable method for treating a WLC wrapped on the surface of a sphere, and fully encapsulated within it. The efficacy of the theory is established by reproducing the exact correlation functions for a WLC confined to the surface of a sphere. In addition, the coefficients in the free energy are exactly calculated. We also describe the behavior of a surface-confined chain under external tension that is relevant for single molecule experiments on histone-DNA complexes. The force-extension curves display spatial oscillations, and the extension of the chain, whose maximum value is bounded by the sphere diameter, scales as f-1 at large forces, in contrast to the unconfined chain that approaches the contour length as f-1/2 . A WLC encapsulated in a sphere, that is relevant for the study of the viral encapsulation of DNA, can also be treated using the mean-field approach. The predictions of the theory for various correlation functions are in excellent agreement with Langevin simulations. We find that strongly confined chains are highly structured by examining the correlations using a local winding axis. The predicted pressure of the system is in excellent agreement with simulations but, as is known, is significantly lower than the pressures seen for DNA packaged in viral capsids.

  7. Confinement and Transport in a Laboratory Magnetosphere

    NASA Astrophysics Data System (ADS)

    Peterson, Ethan; Clark, Michael; Cooper, Christopher; Endrizzi, Douglass; Wallace, John; Weisberg, David; Forest, Cary

    2016-10-01

    Measurements of density, temperature, diamagnetic currents, and ion flows throughout a dipole magnetosphere immersed in a homogeneous plasma are presented. A 1-D ambipolar diffusion transport model developed for multi-cusp confinement systems is adapted for a dipole magnetosphere geometry and compared to measurements. In addition, differential azimuthal flow is imposed on the magnetosphere through electrically driven flow at the boundary of the machine. Modifications to the transport and confinement due to differential rotation are presented as well.

  8. Analysis of strain-modified confinement potentials in vertically stacked InAs/GaAs quantum dot nanostructures with varying stacking period

    NASA Astrophysics Data System (ADS)

    Shin, Hyunho; Yoo, Yo-Han; Lee, Woong

    2003-11-01

    The change in confinement potentials in InAs/GaAs quantum dot (QD) nanostructures due to the interaction of strain fields from InAs QDs has been systematically investigated as a function of vertical stacking period in the light of the 'model solid' theory of Van de Walle and Martin using the strain information obtained from finite element analysis. As the stacking period (inter-dot separation) of InAs QDs decreases, in general, the interaction of strain fields in the nanostructure increases the direct band gap in most of the QD volume while a minor volume near the apex region shows a decreased band gap. A substantially close stacking of QDs results in a type-II behaviour along the stacking direction. In the inter-dot separation regime where the influences of the minor volume in the apex region, the type-II behaviour, and quantum mechanical coupling among QDs are not significant, it is anticipated that the closer stacking of QDs would yield an increased band gap and thus increased recombination energy for blue shift in photoluminescence spectra, as experimentally observed elsewhere recently.

  9. Exact solution for chameleon field, self-coupled through the Ratra-Peebles potential with n =1 and confined between two parallel plates

    NASA Astrophysics Data System (ADS)

    Ivanov, A. N.; Cronenberg, G.; Höllwieser, R.; Jenke, T.; Pitschmann, M.; Wellenzohn, M.; Abele, H.

    2016-10-01

    We calculate the chameleon field profile, confined between two parallel plates, filled with air at pressure P =10-4 mbar and room temperature and separated by the distance L , in the chameleon field theory with Ratra-Peebles self-interaction potential with index n =1 . We give the exact analytical solution in terms of Jacobian elliptic functions, depending on the mass density of the ambient matter. The obtained analytical solution can be used in qBounce experiments, measuring transition frequencies between quantum gravitational states of ultracold neutrons and also for the calculation of the chameleon field induced Casimir force for the CANNEX experiment. We show that the chameleon-matter interactions with coupling constants β ≤1 04 can be probed by qBounce experiments with sensitivities Δ E ≤10-18 eV . At L =30.1 μ m we reproduce the result β <5.8 ×1 08 , obtained by Jenke et al. [Phys. Rev. Lett. 112, 151105 (2014)] at sensitivity Δ E ˜10-14 eV . In the vicinity of one of the plates our solution coincides with the solution, obtained by Brax and Pignol [Phys. Rev. Lett. 107, 111301 (2011)] [see also Ivanov et al. Phys. Rev. D 87, 105013 (2013)] above a plate at zero density of the ambient matter.

  10. Alternative approaches to plasma confinement

    NASA Technical Reports Server (NTRS)

    Roth, J. R.

    1977-01-01

    The potential applications of fusion reactors, the desirable properties of reactors intended for various applications, and the limitations of the Tokamak concept are discussed. The principles and characteristics of 20 distinct alternative confinement concepts are described, each of which may be an alternative to the Tokamak. The devices are classed as Tokamak-like, stellarator-like, mirror machines, bumpy tori, electrostatically assisted, migma concept, and wall-confined plasma.

  11. A Review of Quantum Confinement

    NASA Astrophysics Data System (ADS)

    Connerade, Jean-Patrick

    2009-12-01

    A succinct history of the Confined Atom problem is presented. The hydrogen atom confined to the centre of an impenetrable sphere counts amongst the exactly soluble problems of physics, alongside much more noted exact solutions such as Black Body Radiation and the free Hydrogen atom in absence of any radiation field. It shares with them the disadvantage of being an idealisation, while at the same time encapsulating in a simple way particular aspects of physical reality. The problem was first formulated by Sommerfeld and Welker [1]—henceforth cited as SW—in connection with the behaviour of atoms at very high pressures, and the solution was published on the occasion of Pauli's 60th birthday celebration. At the time, it seemed that there was not much other connection with physical reality beyond a few simple aspects connected to the properties of atoms in solids, for which more appropriate models were soon developed. Thus, confined atoms attracted little attention until the advent of the metallofullerene, which provided the first example of a confined atom with properties quite closely related to those originally considered by SW. Since then, the problem has received much more attention, and many more new features of quantum confinement, quantum compression, the quantum Faraday cage, electronic reorganisation, cavity resonances, etc have been described, which are relevant to real systems. Also, a number of other situations have been uncovered experimentally to which quantum confinement is relevant. Thus, studies of the confined atom are now more numerous, and have been extended both in terms of the models used and the systems to which they can be applied. Connections to thermodynamics are explored through the properties of a confined two-level atom adapted from Einstein's celebrated model, and issues of dynamical screening of electromagnetic radiation by the confining shell are discussed in connection with the Faraday cage produced by a confining conducting shell

  12. A Review of Quantum Confinement

    SciTech Connect

    Connerade, Jean-Patrick

    2009-12-03

    A succinct history of the Confined Atom problem is presented. The hydrogen atom confined to the centre of an impenetrable sphere counts amongst the exactly soluble problems of physics, alongside much more noted exact solutions such as Black Body Radiation and the free Hydrogen atom in absence of any radiation field. It shares with them the disadvantage of being an idealisation, while at the same time encapsulating in a simple way particular aspects of physical reality. The problem was first formulated by Sommerfeld and Welker - henceforth cited as SW - in connection with the behaviour of atoms at very high pressures, and the solution was published on the occasion of Pauli's 60th birthday celebration. At the time, it seemed that there was not much other connection with physical reality beyond a few simple aspects connected to the properties of atoms in solids, for which more appropriate models were soon developed. Thus, confined atoms attracted little attention until the advent of the metallofullerene, which provided the first example of a confined atom with properties quite closely related to those originally considered by SW. Since then, the problem has received much more attention, and many more new features of quantum confinement, quantum compression, the quantum Faraday cage, electronic reorganisation, cavity resonances, etc have been described, which are relevant to real systems. Also, a number of other situations have been uncovered experimentally to which quantum confinement is relevant. Thus, studies of the confined atom are now more numerous, and have been extended both in terms of the models used and the systems to which they can be applied. Connections to thermodynamics are explored through the properties of a confined two-level atom adapted from Einstein's celebrated model, and issues of dynamical screening of electromagnetic radiation by the confining shell are discussed in connection with the Faraday cage produced by a confining conducting shell. The

  13. Two particle system in spherically confined plasma environment

    NASA Astrophysics Data System (ADS)

    Munjal, Dipti; Sen, K. D.; Prasad, Vinod

    2017-03-01

    Energy eigenvalues of Harmonium atom are reported for the first time under spherically confined Debye and spherically confined exponentially cosine screened coulomb potential. Energy of different states of Harmonium is analyzed as a function of confinement radius and Debye screening length. Comparison of radial matrix elements of Harmonium atom under spherically confined Debye and spherically confined exponentially cosine screened coulomb potential is done. Interesting results are obtained.

  14. Rapid Design of Knowledge-Based Scoring Potentials for Enrichment of Near-Native Geometries in Protein-Protein Docking

    PubMed Central

    Sasse, Alexander; de Vries, Sjoerd J.; Schindler, Christina E. M.; de Beauchêne, Isaure Chauvot

    2017-01-01

    Protein-protein docking protocols aim to predict the structures of protein-protein complexes based on the structure of individual partners. Docking protocols usually include several steps of sampling, clustering, refinement and re-scoring. The scoring step is one of the bottlenecks in the performance of many state-of-the-art protocols. The performance of scoring functions depends on the quality of the generated structures and its coupling to the sampling algorithm. A tool kit, GRADSCOPT (GRid Accelerated Directly SCoring OPTimizing), was designed to allow rapid development and optimization of different knowledge-based scoring potentials for specific objectives in protein-protein docking. Different atomistic and coarse-grained potentials can be created by a grid-accelerated directly scoring dependent Monte-Carlo annealing or by a linear regression optimization. We demonstrate that the scoring functions generated by our approach are similar to or even outperform state-of-the-art scoring functions for predicting near-native solutions. Of additional importance, we find that potentials specifically trained to identify the native bound complex perform rather poorly on identifying acceptable or medium quality (near-native) solutions. In contrast, atomistic long-range contact potentials can increase the average fraction of near-native poses by up to a factor 2.5 in the best scored 1% decoys (compared to existing scoring), emphasizing the need of specific docking potentials for different steps in the docking protocol. PMID:28118389

  15. Casimir effects for classical and quantum liquids in slab geometry: A brief review

    NASA Astrophysics Data System (ADS)

    Biswas, Shyamal

    2015-05-01

    We analytically explore Casimir effects for confinement of classical and quantum fluctuations in slab (film) geometry (i) for classical (critical) fluctuations over 4He liquid around the λ point, and (ii) for quantum (phonon) fluctuations of Bogoliubov excitations over an interacting Bose-Einstein condensate. We also briefly review Casimir effects for confinement of quantum vacuum fluctuations confined to two plates of different geometries.

  16. CCSD(T) calculations of stabilities and properties of confined systems

    SciTech Connect

    Holka, F.; Urban, M.; Melicherčík, M.; Neogrády, P.; Paldus, J.

    2015-01-22

    We analyze energies, electron affinities and polarizabilities of small anions exposed to an external confinement. The second electron in free O{sup 2−} and S{sup 2−} anions is unbound. We investigate the stabilizing effect of the spherical harmonic-oscillator confining potential ω. on these anions employing the Hartree-Fock stability analysis as introduced by Čížek and Paldus. With increasing strength of the external harmonic-oscillator confinement potential ω the broken symmetry (BS) solutions are systematically eliminated. For ω larger than 0.1 all BS solutions for O{sup 2−} disappear. For ω larger than 0.13 the CCSD(T) energy of O{sup 2−} becomes more negative than the energy of the singly charged O{sup −} anion. We relate the harmonic-oscillator confining potential to a crystalline environment in which the O{sup 2−} and S{sup 2−} anions are stable. We also present a model allowing calculations of the in-crystal polarizabilities of anions. The model is based on CCSD(T) calculations of static polarizabilities of selected anions exposed to the spherical harmonic-oscillator confining potential ω This artificial confinement potential ω is then related to the ionic radii of the cation in representative crystal lattices. We investigate the polarizability of O{sup 2−} and S{sup 2−} anions in MgO, MgS, CaO, CaS, SrO, SrS, BaO and BaS crystals. We compare our results with alternative models for in-crystal polarizabilities. External confinement also stabilizes the uracil anion U{sup −}, as is shown by calculations with a stepwise micro-hydration of U{sup −}. Upon hydration is the CCSD(T) adiabatic electron affinity (AEA) of uracil enhanced by about 250 up to 570 meV in comparison with AEA of the isolated molecule, depending on the geometry of the hydrated uracil anion complex. We tried to find an analogy of the stabilization effect of the external confinement on the otherwise unstable anions. In uracil and its anion is the external

  17. Molecular Geometry.

    ERIC Educational Resources Information Center

    Desseyn, H. O.; And Others

    1985-01-01

    Compares linear-nonlinear and planar-nonplanar geometry through the valence-shell electron pairs repulsion (V.S.E.P.R.), Mulliken-Walsh, and electrostatic force theories. Indicates that although the V.S.E.P.R. theory has more advantages for elementary courses, an explanation of the best features of the different theories offers students a better…

  18. Walking droplets in confined domains

    NASA Astrophysics Data System (ADS)

    Sáenz, Pedro; Bush, John

    2016-11-01

    A millimetric liquid drop can walk spontaneously along the surface of a vibrating fluid bath, propelled by a resonant interaction with its own wave field. These walking droplets exhibit features previously thought to be exclusive to the microscopic quantum realm. We here explore experimentally the dynamics and statistics of this macroscopic wave-particle system in confined domains, or 'corrals'. Particular attention is given to characterizing the influence of the corral geometry on the emergent probability distributions. The relation to analogous quantum systems (specifically, quantum corrals, the quantum mirage and scarring in Bose-Einstein condensates) is discussed. NSF support via CMMI-1333242.

  19. Isomers and Conformers of H(NH₂BH₂)(n)H Oligomers: Understanding the Geometries and Electronic Structure of Boron-Nitrogen-Hydrogen Compounds as Potential Hydrogen Storage Materials

    SciTech Connect

    Li, Jun; Kathmann, Shawn M.; Schenter, Gregory K.; Gutowski, Maciej S.

    2007-02-07

    Boron-nitrogen-hydrogen (BNHx) materials are polar analogs of hydrocarbons with potential applications as media for hydrogen storage. As H(NH₂BH₂)nH oligomers result from dehydrogenation of NH₃BH₃ and NH₄BH₄ materials, understanding the geometries, stabilities, and electronic structure of these oligomers is essential for developing chemical methods of hydrogen release and regeneration of the BNHx-based hydrogen storage materials. In this work we have performed computational modeling on the H(NH₂BH₂)nH (n = 1 – 6) oligomers using density functional theory (DFT). We have investigated linear chain structures and the stabilizing effects of coiling, biradicalization, and branching through Car-Parrinello molecular dynamics simulations and geometry optimizations. We find that the zig-zag linear oligomers are unstable with respect to the coiled, square-wave chain, and branched structures, with the coiled structures being the most stable. Dihydrogen bonding in oligomers, where protic Hδ⁺(N) hydrogens interact with hydridic Hδ⁻(B) hydrogens, plays a crucial role in stabilizing different isomers and conformers. The results are consistent with structures of products that are seen in experimental NMR studies of dehydrogenated ammonia borane.

  20. Development of empirical potential functions for the study of molecular geometry, and applications to chlorophyll a dimers

    SciTech Connect

    Oie, Tetsuro

    1980-07-28

    A purpose of the present studies is twofold: (1) development of an empirical potential function (EDF) and (2) application of it to the studies of photoreaction center chlorophyll a dimer. The reliable estimate of geometric structures and energies of large molecules by quantum mechanical methods is not possible at the present time. An alternative method is, therefore, needed for the studies of large molecular systems, and Chapter I is dedicated to the development of this tool, i.e., an empirical potential function, which could suffice this purpose. Because of a large number of variable chemical compositions and functional groups characteristically present in a large molecule, it is important to include a large number of structurally diverse molecules in the development of the EPF. In Chapter II, the EPF is applied to study the geometrical structure of a chlorophyll a (Ch1 a) dimer, which is believed to exist at the photoreaction center of green plants and is known to play an essential role in photosynthetic energy conversion. Although various models have been proposed for this dimer structure, there is still a great need for information concerning the detailed geometric structure of this dimer. Therefore, in this chapter the structural stabilities of various dimer models are examined by the EPF, and detailed and quantitative information on the structure and stability of these models is provided.

  1. Development of empirical potential functions for the study of molecular geometry, and applications to chlorophyll a dimers. [Dissertation

    SciTech Connect

    Oie, Tetsuro

    1980-01-01

    A purpose of the present studies is twofold: (1) development of an empirical potential function (EPF) and (2) application of it to the studies of photoreaction center chlorophyll a dimer. The reliable estimate of geometric structures and energies of large molecules by quantum mechanical methods is not possible at the present time. An alternative method is, therefore, needed for the studies of large molecular systems, and Chapter I is dedicated to the development of this tool, i.e., an empirical potential function, which could suffice this purpose. Because of a large number of variable chemical compositions and functional groups characteristically present in a large molecule, it is important to include a large number of structurally diverse molecules in the development of the EPF. In Chapter II, the EPF is applied to study the geometrical structure of a chlorophyll a (Chl a) dimer, which is believed to exist at the photoreaction center of green plants and is known to play an essential role in photosynthetic energy conversion. Although various models have been proposed for this dimer structure, there is still a great need for information concerning the detailed geometric structure of this dimer. Therefore, in this chapter the structural stabilities of various dimer models are examined by the EPF, and detailed and quantitative information on the structure and stability of these models is provided.

  2. Quark Confinement and Strings

    NASA Astrophysics Data System (ADS)

    't Hooft, Gerardus

    QCD was proposed as a theory for the strong interactions long before we had any idea as to how it could be that its fundamental constituents, the quarks, are never seen as physical particles. Massless gluons also do not exist as free particles. How can this be explained? The first indication that this question had to be considered in connection with the topological structure of a gauge theory came when Nielsen and Olesen observed the occurrence of stable magnetic vortex structures [1] in the Abelian Higgs model. Expanding on such ideas, the magnetic monopole solution was found [2]. Other roundabout attempts to understand confinement involve instantons. Today, we have better interpretations of these topological structures, including a general picture of the way they do lead to unbound potentials confining quarks. It is clear that these unbound potentials can be ascribed to a string-like structure of the vortices formed by the QCD field lines. Can string theory be used to analyze QCD? Many researchers think so. The leading expert on this is Sacha Polyakov. In his instructive account he adds how he experienced the course of events in Gauge Theory, emphasizing the fact that quite a few discoveries often ascribed to researchers from the West, actually were made independently by scientists from the Soviet Union…

  3. Colloidal cholesteric liquid crystal in spherical confinement

    PubMed Central

    Li, Yunfeng; Jun-Yan Suen, Jeffrey; Prince, Elisabeth; Larin, Egor M.; Klinkova, Anna; Thérien-Aubin, Héloïse; Zhu, Shoujun; Yang, Bai; Helmy, Amr S.; Lavrentovich, Oleg D.; Kumacheva, Eugenia

    2016-01-01

    The organization of nanoparticles in constrained geometries is an area of fundamental and practical importance. Spherical confinement of nanocolloids leads to new modes of packing, self-assembly, phase separation and relaxation of colloidal liquids; however, it remains an unexplored area of research for colloidal liquid crystals. Here we report the organization of cholesteric liquid crystal formed by nanorods in spherical droplets. For cholesteric suspensions of cellulose nanocrystals, with progressive confinement, we observe phase separation into a micrometer-size isotropic droplet core and a cholesteric shell formed by concentric nanocrystal layers. Further confinement results in a transition to a bipolar planar cholesteric morphology. The distribution of polymer, metal, carbon or metal oxide nanoparticles in the droplets is governed by the nanoparticle size and yields cholesteric droplets exhibiting fluorescence, plasmonic properties and magnetic actuation. This work advances our understanding of how the interplay of order, confinement and topological defects affects the morphology of soft matter. PMID:27561545

  4. Colloidal cholesteric liquid crystal in spherical confinement

    NASA Astrophysics Data System (ADS)

    Li, Yunfeng; Jun-Yan Suen, Jeffrey; Prince, Elisabeth; Larin, Egor M.; Klinkova, Anna; Thérien-Aubin, Héloïse; Zhu, Shoujun; Yang, Bai; Helmy, Amr S.; Lavrentovich, Oleg D.; Kumacheva, Eugenia

    2016-08-01

    The organization of nanoparticles in constrained geometries is an area of fundamental and practical importance. Spherical confinement of nanocolloids leads to new modes of packing, self-assembly, phase separation and relaxation of colloidal liquids; however, it remains an unexplored area of research for colloidal liquid crystals. Here we report the organization of cholesteric liquid crystal formed by nanorods in spherical droplets. For cholesteric suspensions of cellulose nanocrystals, with progressive confinement, we observe phase separation into a micrometer-size isotropic droplet core and a cholesteric shell formed by concentric nanocrystal layers. Further confinement results in a transition to a bipolar planar cholesteric morphology. The distribution of polymer, metal, carbon or metal oxide nanoparticles in the droplets is governed by the nanoparticle size and yields cholesteric droplets exhibiting fluorescence, plasmonic properties and magnetic actuation. This work advances our understanding of how the interplay of order, confinement and topological defects affects the morphology of soft matter.

  5. Geometries of hyperextended continental crust in northeastern continental brazilian margin: insights from potential field and seismic interpretation

    NASA Astrophysics Data System (ADS)

    Magalhães, José; Barbosa, José; Ribeiro, Vanessa; Oliveira, Jefferson; Filho, Osvaldo; Buarque, Bruno

    2016-04-01

    The study region encompasses a set of three basins located at Northeast Brazilian continental margin: Pernambuco (south sector), Paraíba and Natal platform (north sector). These basins were formed during the last stage of separation between South America and African plates during Cretaceous. The continental breakup in these regions occurred probably during the Middle-Upper Albian (~102 m.y). The adjacent basement rocks belong to Borborema Province (BP), which was formed due a complex superposition between Pre-Cambrian orogenic cycles. The structural framework of BP is dominated by large shear zones that divided this province in three main tectonic domains: South, Central and North. The Pernambuco Basin is located in the South Domain and the Paraíba and Natal platform basins are related to the Central Domain. The tectonic and magmatic evolution of the Pernambuco Basin was influenced by oblique rifting (~ 35° to rift axis) and a thermal anomaly probably caused by the Santa Helena hotspot. The north sector represents a continental shelf characterized by basement high with a narrow platform and an abrupt shelf break on transition to the abyssal plain. The continental platform break of this sector was parallel to the rift axis. In this way, we present a regional structural interpretation of these sectors of Brazilian rifted margin based on interpretation and 2D forward modeling of potential field and 2D seismic data. The magnetic maps (Reduction to magnetic pole and Analytic signal) revealed the influence of an alternating pattern of large narrow magnetic and non-magnetic lineaments, oriented NE-SW, E-W and NW-SE. In the Pernambuco Basin these lineaments (NE-SW and E-W) are related to shear zones in the hyperextended basement which is interpreted as a continuation of the granitic-gneissic and metasedimentary rocks of the South Domain of BP. The Paraíba and Natal platform basins show a slight change in the orientation of structures trending E-W (shear zones in

  6. Critical role of axonal A-type K+ channels and axonal geometry in the gating of action potential propagation along CA3 pyramidal cell axons: a simulation study.

    PubMed

    Kopysova, I L; Debanne, D

    1998-09-15

    A model of CA3 pyramidal cell axons was used to study a new mode of gating of action potential (AP) propagation along the axon that depends on the activation of A-type K+ current (Debanne et al., 1997). The axonal membrane contained voltage-dependent Na+ channels, K+ channels, and A-type K+ channels. The density of axonal A-channels was first determined so that (1) at the resting membrane potential an AP elicited by a somatic depolarization was propagated into all axon collaterals and (2) propagation failures occurred when a brief somatic hyperpolarization preceded the AP induction. Both conditions were fulfilled only when A-channels were distributed in clusters but not when they were homogeneously distributed along the axon. Failure occurs in the proximal part of the axon. Conduction failure could be determined by a single cluster of A-channels, local decrease of axon diameter, or axonal elongation. We estimated the amplitude and temporal parameters of the hyperpolarization required for induction of a conduction block. Transient and small somatic hyperpolarizations, such as simulated GABAA inhibitory postsynaptic potentials, were able to block the AP propagation. It was shown that AP induction had to occur with a short delay (<30 msec) after the hyperpolarization. We discuss the possible conditions in which such local variations of the axon geometry and A-channel density may occur and the incidence of AP propagation failures on hippocampal network properties.

  7. Sequence specificity, statistical potentials, and three-dimensional structure prediction with self-correcting distance geometry calculations of beta-sheet formation in proteins.

    PubMed Central

    Zhu, H.; Braun, W.

    1999-01-01

    A statistical analysis of a representative data set of 169 known protein structures was used to analyze the specificity of residue interactions between spatial neighboring strands in beta-sheets. Pairwise potentials were derived from the frequency of residue pairs in nearest contact, second nearest and third nearest contacts across neighboring beta-strands compared to the expected frequency of residue pairs in a random model. A pseudo-energy function based on these statistical pairwise potentials recognized native beta-sheets among possible alternative pairings. The native pairing was found within the three lowest energies in 73% of the cases in the training data set and in 63% of beta-sheets in a test data set of 67 proteins, which were not part of the training set. The energy function was also used to detect tripeptides, which occur frequently in beta-sheets of native proteins. The majority of native partners of tripeptides were distributed in a low energy range. Self-correcting distance geometry (SECODG) calculations using distance constraints sets derived from possible low energy pairing of beta-strands uniquely identified the native pairing of the beta-sheet in pancreatic trypsin inhibitor (BPTI). These results will be useful for predicting the structure of proteins from their amino acid sequence as well as for the design of proteins containing beta-sheets. PMID:10048326

  8. Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites

    NASA Astrophysics Data System (ADS)

    Fenwick, Oliver; Coutiño-Gonzalez, Eduardo; Grandjean, Didier; Baekelant, Wouter; Richard, Fanny; Bonacchi, Sara; de Vos, Dirk; Lievens, Peter; Roeffaers, Maarten; Hofkens, Johan; Samorì, Paolo

    2016-09-01

    The integration of metal atoms and clusters in well-defined dielectric cavities is a powerful strategy to impart new properties to them that depend on the size and geometry of the confined space as well as on metal-host electrostatic interactions. Here, we unravel the dependence of the electronic properties of metal clusters on space confinement by studying the ionization potential of silver clusters embedded in four different zeolite environments over a range of silver concentrations. Extensive characterization reveals a strong influence of silver loading and host environment on the cluster ionization potential, which is also correlated to the cluster’s optical and structural properties. Through fine-tuning of the zeolite host environment, we demonstrate photoluminescence quantum yields approaching unity. This work extends our understanding of structure-property relationships of small metal clusters and applies this understanding to develop highly photoluminescent materials with potential applications in optoelectronics and bioimaging.

  9. QUIESCENT H-MODE, AN ELM-FREE HIGH-CONFINEMENT MODE ON DIII-D WITH POTENTIAL FOR STATIONARY STATE OPERATION

    SciTech Connect

    WEST,WP; BURRELL,KH; deGRASSIE,JS; DOYLE,EJ; GREENFIELD,CM; LASNIER,CJ; SNYDER,PB; ZENG,L

    2003-08-01

    OAK-B135 The quiescent H-mode (QH-mode) is an ELM-free and stationary state mode of operation discovered on DIII-D. This mode achieves H-mode levels of confinement and pedestal pressure while maintaining constant density and radiated power. The elimination of edge localized modes (ELMs) and their large divertor loads while maintaining good confinement and good density control is of interest to next generation tokamaks. This paper reports on the correlations found between selected parameters in a QH-mode database developed from several hundred DIII-D counter injected discharges. Time traces of key plasma parameters from a QH-mode discharge are shown. On DIII-D the negative going plasma current (a) indicates that the beam injection direction is counter to the plasma current direction, a common feature of all QH-modes. The D{sub {alpha}} time behavior (c) shows that soon after high powered beam heating (b) is applied, the discharge makes a transition to ELMing H-mode, then the ELMs disappear, indicating the start of the QH period that lasts for the remainder of the high power beam heating (3.5 s). Previously published work showing density and temperature profiles indicates that long-pulse, high-triangularity QH discharges develop an internal transport barrier in combination with the QH edge barrier. These discharges are known as quiescent, double-barrier discharges (QDB). The H-factor (d) and stored energy (c) rise then saturate at a constant level and the measured axial and minimum safety factors remain above 1.0 for the entire QH duration. During QDB operation the performance of the plasma can be very good, with {beta}{sub N}*H{sub 89L} product reaching 7 for > 10 energy confinement times. These discharges show promise that a stationary state can be achieved.

  10. Note: Light output enhanced fast response and low afterglow {sup 6}Li glass scintillator as potential down-scattered neutron diagnostics for inertial confinement fusion

    SciTech Connect

    Arikawa, Yasunobu; Yamanoi, Kohei; Nagai, Takahiro; Watanabe, Kozue; Kouno, Masahiro; Sakai, Kohei; Nakazato, Tomoharu; Shimizu, Toshihiko; Cadatal, Marilou Raduban; Estacio, Elmer Surat; Sarukura, Nobuhiko; Nakai, Mitsuo; Norimatsu, Takayoshi; Azechi, Hiroshi; Murata, Takahiro; Fujino, Shigeru; Yoshida, Hideki; Izumi, Nobuhiko; Satoh, Nakahiro; Kan, Hirofumi

    2010-10-15

    The characteristics of an APLF80+3Ce scintillator are presented. Its sufficiently fast decay profile, low afterglow, and an improved light output compared to the recently developed APLF80+3Pr, were experimentally demonstrated. This scintillator material holds promise for applications in neutron imaging diagnostics at the energy regions of 0.27 MeV of DD fusion down-scattered neutron peak at the world's largest inertial confinement fusion facilities such as the National Ignition Facility and the Laser Megajoule.

  11. Confined aquifers as viral reservoirs.

    PubMed

    Smith, Renee J; Jeffries, Thomas C; Roudnew, Ben; Seymour, Justin R; Fitch, Alison J; Simons, Keryn L; Speck, Peter G; Newton, Kelly; Brown, Melissa H; Mitchell, James G

    2013-10-01

    Knowledge about viral diversity and abundance in deep groundwater reserves is limited. We found that the viral community inhabiting a deep confined aquifer in South Australia was more similar to reclaimed water communities than to the viral communities in the overlying unconfined aquifer community. This similarity was driven by high relative occurrence of the single-stranded DNA viral groups Circoviridae, Geminiviridae and Microviridae, which include many known plant and animal pathogens. These groups were present in a 1500-year-old water situated 80 m below the surface, which suggests the potential for long-term survival and spread of potentially pathogenic viruses in deep, confined groundwater. Obtaining a broader understanding of potentially pathogenic viral communities within aquifers is particularly important given the ability of viruses to spread within groundwater ecosystems.

  12. Electronic structure of donor-spacer-acceptor molecules of potential interest for molecular electronics. IV. Geometry and device properties of P3CNQ and Q3CNQ

    NASA Astrophysics Data System (ADS)

    Broo, Anders; Zerner, Michael C.

    1995-07-01

    Z-β-(1-hexadecyl-4-quinolinium)-α-cyano-4-styryldicyanomethanide (C 16H 33-Q3CNQ) and the pyridinium analogue Z-β-(1-hexadecyl-4-pyridinium)-α-cyano-4-styryldicyanomethanide (C 16H 33-P3NCQ) are two very promising candidates for molecular device design. We obtain the geometry of the ground and excited state of these systems using the PM3 quantum mechanical model. The absorption spectra in vacuum and in solution are calculated using the INDO/Cl model, and compared to experimental spectra. The solvatochromic shift of the absorption spectra was calculated using a self-consistent reaction field approach. The observed bleaching of Langmuir-Blodgett films and solutions of C 16H 33-Q3CNQ and C 16H 33-P3CNQ is explained as resulting from a twisted configuration formed without barrier upon absorption into a twisted intramolecular charge transfer state. The observed rectification is explained from a ground state potential energy surface with two minima, one of which is characterized by a very large dipole moment. The relative energy of these minima is easily shifted by an electric field. The overall electron transport rate is found to be very small due to the small electronic coupling between the mono-layers of the L-B film. Thus, the electron transport through the sample is likely through defects of the L-B film. A way to increase the electronic coupling between the mono-layers is also discussed.

  13. Enrichment Activities for Geometry.

    ERIC Educational Resources Information Center

    Usiskin, Zalman

    1983-01-01

    Enrichment activities that teach about geometry as they instruct in geometry are given for some significant topics. The facets of geometry included are tessellations, round robin tournaments, geometric theorems on triangles, and connections between geometry and complex numbers. (MNS)

  14. Diffusion of micrometer-sized soft particles in confinement

    NASA Astrophysics Data System (ADS)

    Jordan, Benjamin; Aptowicz, Kevin

    We investigate the diffusion of micrometer sized poly(N-isopropylacrylamide) (PNIPAM) gel particles in confinement. The influence of confinement on the transport of small particles is becoming increasingly important for microfluidics and bio-fluidics. Analytical solutions to this problem are limited to very unique geometries or gross approximations. Computational methods have provided more insight into the problem as well as experimental investigations. However, most research has focused on the hard-sphere problem. In this work, we will explore the diffusion of soft particles in confinement. The dynamics of the particles confined between two parallel walls is captured with video-microscopy. In addition, we use a recently developed technique to measurement confinement of particles in-situ with a precision of 1%. This poster will present some preliminary results of how confinement affects the diffusion of these soft particles. We acknowledge support from Grant DMR-1206231.

  15. Progress in toroidal confinement and fusion research

    SciTech Connect

    Furth, H.P.

    1987-10-01

    During the past 30 years, the characteristic T/sub i/n tau/sub E/-value of toroidal-confinement experiments has advanced by more than seven orders of magnitude. Part of this advance has been due to an increase of gross machine parameters. Most of this advance has been due to an increase of gross machine parameters. Most of the advance is associated with improvements in the ''quality of plasma confinement.'' The combined evidence of spherator and tokamak research clarifies the role of magnetic-field geometry in determining confinement and points to the importance of shielding out plasma edge effects. A true physical understanding of anomalous transport remains to be achieved. 39 refs., 11 figs., 1 tab.

  16. Dynamical conductivity of confined water

    NASA Astrophysics Data System (ADS)

    Artemov, V. G.

    2017-01-01

    The electrodynamic response of water confined in nanoporous MCM-41 is measured in the frequency range 1 MHz-3 THz at room temperature. The results are analyzed in the context of a recently proposed ionic model of water. We found an increase in dc-conductivity of confined water by 3 orders of magnitude (3.3 · 10-3 Ω-1 · m-1) compared to bulk water (5.5 · 10-6 Ω-1 · m-1). This is attributed to the increase of H3O+ and OH- ion mobility, due to a decrease of the effective potential amplitude by walls of the confining environment. We found that the absorption in the microwave frequency range is much smaller in the medium with confined water than in the bulk water, and the quadratic dependence of the conductivity (σ) on frequency (ω) becomes less steep and tends to σ ~ ω. The results are of fundamental importance and can be used for understanding of the proton transport in systems with water in the nanoconfined state.

  17. Confinement Aquaculture. Final Report.

    ERIC Educational Resources Information Center

    Delaplaine School District, AR.

    The Delaplaine Agriculture Department Confinement Project, begun in June 1988, conducted a confinement aquaculture program by comparing the growth of channel catfish raised in cages in a pond to channel catfish raised in cages in the Black River, Arkansas. The study developed technology that would decrease costs in the domestication of fish, using…

  18. Indoor Confined Feedlots.

    PubMed

    Grooms, Daniel L; Kroll, Lee Anne K

    2015-07-01

    Indoor confined feedlots offer advantages that make them desirable in northern climates where high rainfall and snowfall occur. These facilities increase the risk of certain health risks, including lameness and tail injuries. Closed confinement can also facilitate the rapid spread of infectious disease. Veterinarians can help to manage these health risks by implementing management practices to reduce their occurrence.

  19. Nucleation of Vortices in Superconductors in Confined Geometries

    NASA Astrophysics Data System (ADS)

    Wu, W. M.; Sobnack, M. B.; Kusmartsev, F. V.

    2008-06-01

    We investigate the nucleation of vortices in a small superconducting disk. We formulate the Gibbs free energy of the disk with an arbitrary number of vortices (arranged in rings concentric with the disk) as a function of temperature and applied magnetic field and minimize the energy to obtain the optimal position of vortices for different applied fields and temperatures. We also analyze the stability of the different vortex states inside the disk and compare our results with those of other theoretical studies and with available experimental observations. Our results are in very good agreement with experiments.

  20. Convection, evaporation, and condensation of binary fluids in confined geometries

    NASA Astrophysics Data System (ADS)

    Grigoriev, Roman; Qin, Tongran; Li, Yaofa; Chan, Benjamin; Yoda, Minami

    2011-11-01

    Phase change has a major effect on convection in liquid layers with a free surface. Significant latent heat generated at the free surface as a result of phase change can dramatically alter the interfacial temperature, inducing thermocapillary stresses. For binary fluids, differential evaporation leads to a variation in the concentration, and hence, induces solutocapillary stresses. This talk describes numerical and experimental studies of convection in alcohol-water mixtures due to a horizontal temperature gradient in the presence of phase change. Evaporation and condensation is known to be a notoriously difficult problem to model due to a poorly defined vapor transport problem which is strongly influenced by the presence/absence and flows of non-condensable gases (e.g., air). This issue is addressed by using a sealed cuvette heated at one end and cooled at the other. Both numerics and experiments show that, by adding or removing air from the cuvette, the direction of flow in a liquid layer covering the bottom of the cell can be reversed by emphasizing either thermocapillary or solutocapillary stresses. Supported by ONR.

  1. Non-resonant Nanoscale Extreme Light Confinement

    SciTech Connect

    Subramania, Ganapathi Subramanian; Huber, Dale L.

    2014-09-01

    A wide spectrum of photonics activities Sandia is engaged in such as solid state lighting, photovoltaics, infrared imaging and sensing, quantum sources, rely on nanoscale or ultrasubwavelength light-matter interactions (LMI). The fundamental understanding in confining electromagnetic power and enhancing electric fields into ever smaller volumes is key to creating next generation devices for these programs. The prevailing view is that a resonant interaction (e.g. in microcavities or surface-plasmon polaritions) is necessary to achieve the necessary light confinement for absorption or emission enhancement. Here we propose new paradigm that is non-resonant and therefore broadband and can achieve light confinement and field enhancement in extremely small areas [~(λ/500)^2 ]. The proposal is based on a theoretical work[1] performed at Sandia. The paradigm structure consists of a periodic arrangement of connected small and large rectangular slits etched into a metal film named double-groove (DG) structure. The degree of electric field enhancement and power confinement can be controlled by the geometry of the structure. The key operational principle is attributed to quasistatic response of the metal electrons to the incoming electromagnetic field that enables non-resonant broadband behavior. For this exploratory LDRD we have fabricated some test double groove structures to enable verification of quasistatic electronic response in the mid IR through IR optical spectroscopy. We have addressed some processing challenges in DG structure fabrication to enable future design of complex sensor and detector geometries that can utilize its non-resonant field enhancement capabilities.].

  2. Computer simulations of charged colloids in confinement.

    PubMed

    Puertas, Antonio M; de las Nieves, F Javier; Cuetos, Alejandro

    2015-02-15

    We study by computer simulations the interaction between two similarly charged colloidal particles confined between parallel planes, in salt free conditions. Both the colloids and ions are simulated explicitly, in a fine-mesh lattice, and the electrostatic interaction is calculated using Ewald summation in two dimensions. The internal energy is measured by setting the colloidal particles at a given position and equilibrating the ions, whereas the free energy is obtained introducing a bias (attractive) potential between the colloids. Our results show that upon confining the system, the internal energy decreases, resulting in an attractive contribution to the interaction potential for large charges and strong confinement. However, the loss of entropy of the ions is the dominant mechanism in the interaction, irrespective of the confinement of the system. The interaction potential is therefore repulsive in all cases, and is well described by the DLVO functional form, but effective values have to be used for the interaction strength and Debye length.

  3. Describing the Diverse Geometries of Gold from Nanoclusters to Bulk—A First-Principles-Based Hybrid Bond-Order Potential

    SciTech Connect

    Narayanan, Badri; Kinaci, Alper; Sen, Fatih G.; Davis, Michael J.; Gray, Stephen K.; Chan, Maria K. Y.; Sankaranarayanan, Subramanian K. R. S.

    2016-05-19

    Molecular dynamics simulations using empirical force fields (EFFs) are crucial for gaining fundamental insights into atomic structure and long time scale dynamics of Au nanoclusters with far-reaching applications in energy and devices. This approach is thwarted by the failure of currently available EFFs in describing the size-dependent dimensionality and diverse geometries exhibited by Au clusters (e.g., planar structures, hollow cages, tubes, pyramids, space-filled structures). Here, we mitigate this issue by introducing a new hybrid bond-order potential (HyBOP), which accounts for (a) short-range interactions via Tersoff-type BOP terms that accurately treat bond directionality and (b) long-range dispersion effects by a scaled Lennard–Jones term whose contribution depends on the local atomic density. We optimized the independent parameters for our HyBOP using a global optimization scheme driven by genetic algorithms. Moreover, to ensure good transferability of these parameters across different length scales, we used an extensive training data set that encompasses structural and energetic properties of 1000 13-atom Au clusters, surface energies, as well as bulk polymorphs, obtained from density functional theory (DFT) calculations. Our newly developed HyBOP has been found to accurately describe (a) global minimum energy configurations at different cluster sizes as well as order of stability of various cluster configurations at any size, (b) critical size of transition from planar to globular clusters, (c) evolution of structural motifs with cluster size, and (c) thermodynamics, structure, elastic properties, and energetic ordering of bulk condensed phases as well as surfaces, in excellent agreement with DFT calculations and spectroscopic experiments. This makes our newly developed HyBOP a valuable, computationally robust but inexpensive tool for investigating a wide range of materials phenomena occurring in Au at the atomistic level.

  4. Simulations of Coulomb systems with slab geometry using an efficient 3D Ewald summation method.

    PubMed

    dos Santos, Alexandre P; Girotto, Matheus; Levin, Yan

    2016-04-14

    We present a new approach to efficiently simulate electrolytes confined between infinite charged walls using a 3d Ewald summation method. The optimal performance is achieved by separating the electrostatic potential produced by the charged walls from the electrostatic potential of electrolyte. The electric field produced by the 3d periodic images of the walls is constant inside the simulation cell, with the field produced by the transverse images of the charged plates canceling out. The non-neutral confined electrolyte in an external potential can be simulated using 3d Ewald summation with a suitable renormalization of the electrostatic energy, to remove a divergence, and a correction that accounts for the conditional convergence of the resulting lattice sum. The new algorithm is at least an order of magnitude more rapid than the usual simulation methods for the slab geometry and can be further sped up by adopting a particle-particle particle-mesh approach.

  5. Electromagnetic Confinement via Spin-Orbit Interaction in Anisotropic Dielectrics.

    PubMed

    Alberucci, Alessandro; Jisha, Chandroth P; Marrucci, Lorenzo; Assanto, Gaetano

    2016-12-21

    We investigate electromagnetic propagation in uniaxial dielectrics with a transversely varying orientation of the optic axis, the latter staying orthogonal everywhere in the propagation direction. In such a geometry, the field experiences no refractive index gradients, yet it acquires a transversely modulated Pancharatnam-Berry phase, that is, a geometric phase originating from a spin-orbit interaction. We show that the periodic evolution of the geometric phase versus propagation gives rise to a longitudinally invariant effective potential. In certain configurations, this geometric phase can provide transverse confinement and waveguiding. The theoretical findings are tested and validated against numerical simulations of the complete Maxwell's equations. Our results introduce and illustrate the role of geometric phases on electromagnetic propagation over distances well exceeding the diffraction length, paving the way to a whole new family of guided waves and waveguides that do not rely on refractive index tailoring.

  6. Electromagnetic Confinement via Spin–Orbit Interaction in Anisotropic Dielectrics

    PubMed Central

    2016-01-01

    We investigate electromagnetic propagation in uniaxial dielectrics with a transversely varying orientation of the optic axis, the latter staying orthogonal everywhere in the propagation direction. In such a geometry, the field experiences no refractive index gradients, yet it acquires a transversely modulated Pancharatnam–Berry phase, that is, a geometric phase originating from a spin–orbit interaction. We show that the periodic evolution of the geometric phase versus propagation gives rise to a longitudinally invariant effective potential. In certain configurations, this geometric phase can provide transverse confinement and waveguiding. The theoretical findings are tested and validated against numerical simulations of the complete Maxwell’s equations. Our results introduce and illustrate the role of geometric phases on electromagnetic propagation over distances well exceeding the diffraction length, paving the way to a whole new family of guided waves and waveguides that do not rely on refractive index tailoring. PMID:28217716

  7. Elastic membranes in confinement

    NASA Astrophysics Data System (ADS)

    Bostwick, Joshua; Miksis, Michael; Davis, Stephen

    2014-11-01

    An elastic membrane stretched between two walls takes a shape defined by its length and the volume of fluid it encloses. Many biological structures, such as cells, mitochondria and DNA, have finer internal structure in which a membrane (or elastic member) is geometrically ``confined'' by another object. We study the shape stability of elastic membranes in a ``confining'' box and introduce repulsive van der Waals forces to prevent the membrane from intersecting the wall. We aim to define the parameter space associated with mitochondria-like deformations. We compare the confined to `unconfined' solutions and show how the structure and stability of the membrane shapes changes with the system parameters.

  8. Effects of confinement on nanoparticle flows

    NASA Astrophysics Data System (ADS)

    Conrad, Jacinta

    The transport properties of nanoparticles that are dispersed in complex fluids and flowed through narrow confining geometries affect a wide range of materials shaping and forming processes, including three-dimensional printing and nanocomposite processing. Here, I will describe two sets of experiments in which we use optical microscopy to probe the structure and transport properties of suspensions of particles that are confined geometrically. First, we investigate the structure and flow properties of dense suspensions of submicron particles, in which the particles interact via an entropic depletion attraction, that are confined in thin films and microchannels. Second, we characterize the transport properties of nanoparticles, dispersed at low concentration in water or in aqueous solutions of high-molecular weight polymers, that are confined in regular arrays of nanoposts or in disordered porous media. I will discuss our results and their practical implications for materials processing as well as for other applications that require confined transport of nanomaterials through complex media. Welch Foundation (E-1869) and NSF (CBET-1438204).

  9. Inertial electrostatic confinement: Theoretical and experimental studies of spherical devices

    NASA Astrophysics Data System (ADS)

    Meyer, Ryan

    Inertial Electrostatic Confinement (IEC) is a means to confine ions for fusion purposes with electrostatic fields in a converging geometry. Its engineering simplicity makes it appealing when compared to magnetic confinement devices. It is hoped that such a device may one day be a net energy producer, but it has near term applications as a neutron generator. We study spherical IECs (SIECs), both theoretically and experimentally. Theoretically, we compute solutions in the free molecular limit and map out regions in control parameter space conducive to the formation of double potential wells. In addition, several other observables are mapped in the control parameter space. Such studies predict the threshold for the phenomena of "core splitting" to occur when the fractional well depth (FWD) is ˜70%-80%. With respect to double potential wells, it is shown that an optimal population of electrons exists for double well formation. In addition, double well depth is relatively insensitive to space charge spreading of ion beams. Glow discharge devices are studied experimentally with double and single Langmuir probes. The postulated micro-channeling phenomenon is verified with density measurements along a micro-channel and along the radius where micro-channels are absent. In addition, the measurements allow an evaluation of the neutrality of micro-channels and the heterogeneous structure of "Star Mode". It is shown that, despite visual evidence, micro-channeling persists well into "Jet" mode. In addition, the threshold for the "Star" mode to "Jet" mode transition is obtained experimentally. The studies have revealed new techniques for estimating tangential electric field components and studying the focusing of ion flow.

  10. Polymer Crystallization under Confinement

    NASA Astrophysics Data System (ADS)

    Floudas, George

    Recent efforts indicated that polymer crystallization under confinement can be substantially different from the bulk. This can have important technological applications for the design of polymeric nanofibers with tunable mechanical strength, processability and optical clarity. However, the question of how, why and when polymers crystallize under confinement is not fully answered. Important studies of polymer crystallization confined to droplets and within the spherical nanodomains of block copolymers emphasized the interplay between heterogeneous and homogeneous nucleation. Herein we report on recent studies1-5 of polymer crystallization under hard confinement provided by model self-ordered AAO nanopores. Important open questions here are on the type of nucleation (homogeneous vs. heterogeneous), the size of critical nucleus, the crystal orientation and the possibility to control the overall crystallinity. Providing answers to these questions is of technological relevance for the understanding of nanocomposites containing semicrystalline polymers. In collaboration with Y. Suzuki, H. Duran, M. Steinhart, H.-J. Butt.

  11. Confinement and the Pomeron

    SciTech Connect

    White, A.R.

    1989-09-25

    The importance of confinement for obtaining a unitary high-energy limit for QCD is discussed. Minijets'' are argued to build up non-unitary behavior{endash}when k{sub T} {gt} {Lambda} is imposed. For minijets to mix with low k{sub T} Pomeron Field Theory describing confinement, and give consistent asymptotic behavior, new quarks'' must enter the theory above the minijet transverse momentum scale. The Critical Pomeron is the resulting high-energy limit. 22 refs.

  12. Geometry of thermodynamic control.

    PubMed

    Zulkowski, Patrick R; Sivak, David A; Crooks, Gavin E; DeWeese, Michael R

    2012-10-01

    A deeper understanding of nonequilibrium phenomena is needed to reveal the principles governing natural and synthetic molecular machines. Recent work has shown that when a thermodynamic system is driven from equilibrium then, in the linear response regime, the space of controllable parameters has a Riemannian geometry induced by a generalized friction tensor. We exploit this geometric insight to construct closed-form expressions for minimal-dissipation protocols for a particle diffusing in a one-dimensional harmonic potential, where the spring constant, inverse temperature, and trap location are adjusted simultaneously. These optimal protocols are geodesics on the Riemannian manifold and reveal that this simple model has a surprisingly rich geometry. We test these optimal protocols via a numerical implementation of the Fokker-Planck equation and demonstrate that the friction tensor arises naturally from a first-order expansion in temporal derivatives of the control parameters, without appealing directly to linear response theory.

  13. Casimir effects for classical and quantum liquids in slab geometry: A brief review

    SciTech Connect

    Biswas, Shyamal

    2015-05-15

    We analytically explore Casimir effects for confinement of classical and quantum fluctuations in slab (film) geometry (i) for classical (critical) fluctuations over {sup 4}He liquid around the λ point, and (ii) for quantum (phonon) fluctuations of Bogoliubov excitations over an interacting Bose-Einstein condensate. We also briefly review Casimir effects for confinement of quantum vacuum fluctuations confined to two plates of different geometries.

  14. Fusion, magnetic confinement

    SciTech Connect

    Berk, H.L.

    1992-08-06

    An overview is presented of the principles of magnetic confinement of plasmas for the purpose of achieving controlled fusion conditions. Sec. 1 discusses the different nuclear fusion reactions which can be exploited in prospective fusion reactors and explains why special technologies need to be developed for the supply of tritium or {sup 3}He, the probable fuels. In Sec. 2 the Lawson condition, a criterion that is a measure of the quality of confinement relative to achieving fusion conditions, is explained. In Sec. 3 fluid equations are used to describe plasma confinement. Specific confinement configurations are considered. In Sec. 4 the orbits of particle sin magneti and electric fields are discussed. In Sec. 5 stability considerations are discussed. It is noted that confinement systems usually need to satisfy stability constraints imposed by ideal magnetohydrodynamic (MHD) theory. The paper culminates with a summary of experimental progress in magnetic confinement. Present experiments in tokamaks have reached the point that the conditions necessary to achieve fusion are being satisfied.

  15. Engaging All Students with "Impossible Geometry"

    ERIC Educational Resources Information Center

    Wiest, Lynda R.; Ayebo, Abraham; Dornoo, Michael D.

    2010-01-01

    Geometry is an area in which Australian students performed particularly poorly on the 2007 Trends in International Mathematics and Science Study (TIMSS). One innovative area of recreational geometry that has rich potential to engage and challenge a wide variety of students is "impossible geometry." An impossible geometric object is a…

  16. Capillary condensation in a square geometry with surface fields

    NASA Astrophysics Data System (ADS)

    Zubaszewska, M.; Gendiar, A.; Drzewiński, A.

    2012-12-01

    We study the influence of wetting on capillary condensation for a simple fluid in a square geometry with surface fields, where the reference system is an infinitely long slit. The corner transfer matrix renormalization group method has been extended to study a two-dimensional Ising model confined in an L×L geometry with equal surface fields. Our results have confirmed that in both geometries the coexistence line shift is governed by the same scaling powers, but their prefactors are different.

  17. Is sarcomere lattice geometry optimal? Analysis of several potential virtual polygon cross-sectional patterns for actin and myosin myofilaments in muscle.

    PubMed

    Kepner, Gordon R

    2014-09-01

    The hexagonal arrangement of actin filaments in skeletal muscle is not the fundamental geometrical or functioning myofilament unit. This analysis of several possible sarcomere lattice geometries for the arrangement of the actin and myosin filaments identifies several geometrical constraints that can be compared for their effect on muscle sarcomere functioning and efficiency. Three distinct virtual polygons, with myosins at their vertices and that tessellate the plane, are compared for both centered actin and perimeter actin arrangements. The analysis evaluates the optimal ratio of myosin to actin filaments, the packing density, and the effect on new myofilament formation in muscle hypertrophy for the various lattice geometries. The results support the view that no single measure of geometrical effectiveness can evaluate definitively the efficiency of any particular arrangement of the myofilaments. The analysis provides quantitative measures of several parameters that, taken overall, support the effectiveness of the myofilament arrangement in Nature. It provides a new definition of the fundamental myofilament unit (FMU). It is possible to calculate the number of actin and myosin myofilaments that need to be added to each polygon arrangement of the myofilaments to create a new FMU for that specific geometry. This leads to useful conclusions about the biochemical efficiency involved in where such units arise in the course of muscle hypertrophy. It supports the idea that the evolutionary endpoint for optimizing muscle's force-generating function can be better understood via the concepts of a FMU and the polygon arrangement of the sarcomere lattice geometry.

  18. Interfacial electrofluidics in confined systems

    NASA Astrophysics Data System (ADS)

    Tang, Biao; Groenewold, Jan; Zhou, Min; Hayes, Robert A.; Zhou, Guofu (G. F.)

    2016-05-01

    Electrofluidics is a versatile principle that can be used for high speed actuation of liquid interfaces. In most of the applications, the fundamental mechanism of electro-capillary instability plays a crucial role, yet it’s potential richness in confined fluidic layers has not been well addressed. Electrofluidic displays which are comprised of thin pixelated colored films in a range of architectures are excellent systems for studying such phenomena. In this study we show theoretically and experimentally that confinement leads to the generation of a cascade of voltage dependent modes as a result of the electro-capillary instability. In the course of reconciling theory with our experimental data we have observed a number of previously unreported phenomena such as a significant induction time (several milliseconds) prior to film rupture as well as a rupture location not corresponding to the minimum electric field strength in the case of the standard convex water/oil interface used in working devices. These findings are broadly applicable to a wide range of switchable electrofluidic applications and devices having confined liquid films.

  19. Interfacial electrofluidics in confined systems

    PubMed Central

    Tang, Biao; Groenewold, Jan; Zhou, Min; Hayes, Robert A.; Zhou, Guofu (G.F.)

    2016-01-01

    Electrofluidics is a versatile principle that can be used for high speed actuation of liquid interfaces. In most of the applications, the fundamental mechanism of electro-capillary instability plays a crucial role, yet it’s potential richness in confined fluidic layers has not been well addressed. Electrofluidic displays which are comprised of thin pixelated colored films in a range of architectures are excellent systems for studying such phenomena. In this study we show theoretically and experimentally that confinement leads to the generation of a cascade of voltage dependent modes as a result of the electro-capillary instability. In the course of reconciling theory with our experimental data we have observed a number of previously unreported phenomena such as a significant induction time (several milliseconds) prior to film rupture as well as a rupture location not corresponding to the minimum electric field strength in the case of the standard convex water/oil interface used in working devices. These findings are broadly applicable to a wide range of switchable electrofluidic applications and devices having confined liquid films. PMID:27221211

  20. Hot electron confinement in a microwave heated spindle cusp

    SciTech Connect

    Prelas, M.A.

    1991-08-01

    The Plasma Research Laboratory at the University of Missouri-Columbia was established with awards from the McDonnel Douglas Foundation, ARMCO, Union Electric, Black and Vetch, Kansas City Power and Light, the National Science Foundation, and DOE. The Plasma Research Lab's major effort is the Missouri Magnetic Mirror (MMM or M{sup 3}) Project. The technical goals of MMM have been (1) Diagnostic Development, (2) Plasma Physics in the Cusp geometry, (3) plasma-wall interactions, (4) impurity effects in a steady-state plasma, and (5) Development of Diagnostics for use in harsh plasma processing environments. The other major goal of MMM has remained providing a facility for hands-on training in experimental plasma physics. The major experimental facility of MMM is the MMM Modified Experiment (M4X). Other research efforts in the Plasma Research Laboratory include small efforts in cold fusion, toroidal magnetic confinement, and inertial confinement and a potentially major effort in direct conversion of nuclear energy.

  1. Hot electron confinement in a microwave heated spindle cusp

    NASA Astrophysics Data System (ADS)

    Prelas, M. A.

    1991-08-01

    The Plasma Research Laboratory at the University of Missouri-Columbia was established with awards from the McDonnell Douglas Foundation, ARMCO, Union Electric, Black and Vetch, Kansas City Power and Light, the National Science Foundation, and DOE. The Plasma Research Lab's major effort is the Missouri Magnetic Mirror (MMM or M(exp 3)) Project. The technical goals of MMM have been (1) Diagnostic Development, (2) Plasma Physics in the Cusp geometry, (3) plasma-wall interactions, (4) impurity effects in a steady-state plasma, and (5) Development of Diagnostics for use in harsh plasma processing environments. The other major goal of MMM has remained providing a facility for hands-on training in experimental plasma physics. The major experimental facility of MMM is the MMM Modified Experiment (M4X). Other research efforts in the Plasma Research Laboratory include small efforts in cold fusion, toroidal magnetic confinement, and inertial confinement and a potentially major effort in direct conversion of nuclear energy.

  2. The development of a laterally confined laboratory fan delta under sediment supply reduction

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaofeng; Wang, Siqiang; Wu, Xi; Xu, Shun; Li, Zhangyong

    2016-03-01

    In previous fan delta experiments, the effect of lateral confinement was generally ignored as these fans were usually unconfined with semiconical geometries. However, in gorge areas, fan development is usually laterally confined by valley walls. This study investigates autogenic processes of fan deltas in a laterally confined experimental tank. The experiment is divided into three phases. The sediment supply is held constant within each phase, so the autogenic processes of the fan are separated from the allogenic forcings. Results indicate that laterally confined fan deltas have higher progradation and aggradation potential, more regular channel braiding, and more even transverse sedimentation than unconfined fans. Besides, responses of fan deltas to sediment supply reduction are investigated in this research. At the initiation of the second and third phases, sediment feed rates are instantaneously reduced so that the allogenic forcings are predominant. Observations show that under sediment supply reduction, channelization on fan deltas are more pronounced and durations of the fluvial cycles are longer. The adjustment of fan morphology becomes slower as the self-regulation capacity of the fan decreases with reduced sediment supply.

  3. Elementary framework for cold field emission: Incorporation of quantum-confinement effects

    SciTech Connect

    Patterson, A. A. Akinwande, A. I.

    2013-12-21

    Although the Fowler-Nordheim (FN) equation serves as the foundation of cold field emission theory, it may not be suitable for predicting the emitted current density (ECD) from emitters with a quantum-confined electron supply. This work presents an analytical framework for treating cold field emission from metals that includes the effects of a quantum-confined electron supply. Within the framework, quantum confinement in emitters is classified into transverse and normal quantum confinement based on the orientation of the confinement relative to the emission direction. The framework is used to generate equations predicting the ECD from rectangular and cylindrical emitter geometries comprised of electron supplies of reduced dimensionality. Transverse quantum confinement of the electron supply leads to a reduction in the total ECD as transverse emitter dimensions decrease and normal quantum confinement results in an oscillatory ECD as a function of the normal quantum well width. Incorporating a geometry-dependent field enhancement factor into the model reveals an optimal transverse well width for which quantum confinement of the electron supply and field enhancement equally affect the ECD and a maximum total ECD for the emitter geometry at a given applied field is obtained. As a result, the FN equation over-predicts the ECD from emitters with transverse dimensions under approximately 5 nm, and in those cases, geometry-specific ECD equations incorporating quantum-confinement effects should be employed instead.

  4. Heat-capacity scaling function for confined superfluids

    NASA Astrophysics Data System (ADS)

    Nho, Kwangsik; Manousakis, Efstratios

    2003-11-01

    We study the specific-heat scaling function of confined superfluids using Monte Carlo simulation. While the scaling function is insensitive to the microscopic details, it depends on the confining geometry and boundary conditions (BC’s). In the present work we have studied (a) cubic geometry with open BC’s in all three directions and (b) parallel-plate (film) geometry using open BC’s along the finite dimension and periodic BC’s along the other two dimensions. We find that the specific-heat scaling function is significantly different for the two different geometries studied. The scaling function for each geometry (a) or (b) is very different when compared to that obtained for the same geometry but with periodic BC’s. On the contrary, we find that in case (b) the calculated scaling function is very close to the earlier calculated using Dirichlet instead of open BC’s. This demonstrates that Dirichlet and open boundary conditions act in a similar way. Our results for both scaling functions obtained for the parallel-plate geometry and for cubic geometry with open BC’s along the finite dimensions are in very good agreement with recent very-high-quality experimental measurements with no free parameters.

  5. Critical and near-critical phase behavior and interplay between the thermodynamic Casimir and van der Waals forces in a confined nonpolar fluid medium with competing surface and substrate potentials

    NASA Astrophysics Data System (ADS)

    Valchev, Galin; Dantchev, Daniel

    2015-07-01

    We study, using general scaling arguments and mean-field type calculations, the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance L from each other, confining some fluctuating fluid medium, say a nonpolar one-component fluid or a binary liquid mixture. The surfaces of the slabs are coated by thin layers exerting strong preference to the liquid phase of the fluid, or one of the components of the mixture, modeled by strong adsorbing local surface potentials ensuring the so-called (+,+) boundary conditions. The slabs, on the other hand, influence the fluid by long-range competing dispersion potentials, which represent irrelevant interactions in renormalization-group sense. Under such conditions, one usually expects attractive Casimir force governed by universal scaling function, pertinent to the extraordinary surface universality class of Ising type systems, to which the dispersion potentials provide only corrections to scaling. We demonstrate, however, that below a given threshold thickness of the system Lcrit for a suitable set of slabs-fluid and fluid-fluid coupling parameters the competition between the effects due to the coatings and the slabs can result in sign change of the Casimir force acting between the surfaces confining the fluid when one changes the temperature T , the chemical potential of the fluid μ , or L . The last implies that by choosing specific materials for the slabs, coatings, and the fluid for L ≲Lcrit one can realize repulsive Casimir force with nonuniversal behavior which, upon increasing L , gradually turns into an attractive one described by a universal scaling function, depending only on the relevant scaling fields related to the temperature and the excess chemical potential, for L ≫Lcrit . We present arguments and relevant data for specific substances in support of the experimental feasibility of the predicted behavior of the force. It can

  6. Glycerol in micellar confinement with tunable rigidity

    NASA Astrophysics Data System (ADS)

    Lannert, Michael; Müller, Allyn; Gouirand, Emmanuel; Talluto, Vincenzo; Rosenstihl, Markus; Walther, Thomas; Stühn, Bernd; Blochowicz, Thomas; Vogel, Michael

    2016-12-01

    We investigate the glassy dynamics of glycerol in the confinement of a microemulsion system, which is stable on cooling down to the glass transition of its components. By changing the composition, we vary the viscosity of the matrix, while keeping the confining geometry intact, as is demonstrated by small angle X-ray scattering. By means of 2H NMR, differential scanning calorimetry, and triplet solvation dynamics we, thus, probe the dynamics of glycerol in confinements of varying rigidity. 2H NMR results show that, at higher temperatures, the dynamics of confined glycerol is unchanged compared to bulk behavior, while the reorientation of glycerol molecules becomes significantly faster than in the bulk in the deeply supercooled regime. However, comparison of different 2H NMR findings with data from calorimetry and solvation dynamics reveals that this acceleration is not due to the changed structural relaxation of glycerol, but rather due to the rotational motion of essentially rigid glycerol droplets or of aggregates of such droplets in a more fluid matrix. Thus, independent of the matrix mobility, the glycerol dynamics remains unchanged except for the smallest droplets, where an increase of Tg and, thus, a slowdown of the structural relaxation is observed even in a fluid matrix.

  7. Geometry in Medias Res

    ERIC Educational Resources Information Center

    Cukier, Mimi; Asdourian, Tony; Thakker, Anand

    2012-01-01

    Geometry provides a natural window into what it is like to do mathematics. In the world of geometry, playful experimentation is often more fruitful than following a procedure, and logic plus a few axioms can open new worlds. Nonetheless, teaching a geometry course in a way that combines both rigor and play can be difficult. Many geometry courses…

  8. Metal-organic frameworks as host materials of confined supercooled liquids

    NASA Astrophysics Data System (ADS)

    Fischer, J. K. H.; Sippel, P.; Denysenko, D.; Lunkenheimer, P.; Volkmer, D.; Loidl, A.

    2015-10-01

    In this work, we examine the use of metal-organic framework (MOF) systems as host materials for the investigation of glassy dynamics in confined geometry. We investigate the confinement of the molecular glass former glycerol in three MFU-type MOFs with different pore sizes (MFU stands for "Metal-Organic Framework Ulm-University") and study the dynamics of the confined liquid via dielectric spectroscopy. In accord with previous reports on confined glass formers, we find different degrees of deviations from bulk behavior depending on pore size, demonstrating that MOFs are well-suited host systems for confinement investigations.

  9. Precision platform for convex lens-induced confinement microscopy

    NASA Astrophysics Data System (ADS)

    Berard, Daniel; McFaul, Christopher M. J.; Leith, Jason S.; Arsenault, Adriel K. J.; Michaud, François; Leslie, Sabrina R.

    2013-10-01

    We present the conception, fabrication, and demonstration of a versatile, computer-controlled microscopy device which transforms a standard inverted fluorescence microscope into a precision single-molecule imaging station. The device uses the principle of convex lens-induced confinement [S. R. Leslie, A. P. Fields, and A. E. Cohen, Anal. Chem. 82, 6224 (2010)], which employs a tunable imaging chamber to enhance background rejection and extend diffusion-limited observation periods. Using nanopositioning stages, this device achieves repeatable and dynamic control over the geometry of the sample chamber on scales as small as the size of individual molecules, enabling regulation of their configurations and dynamics. Using microfluidics, this device enables serial insertion as well as sample recovery, facilitating temporally controlled, high-throughput measurements of multiple reagents. We report on the simulation and experimental characterization of this tunable chamber geometry, and its influence upon the diffusion and conformations of DNA molecules over extended observation periods. This new microscopy platform has the potential to capture, probe, and influence the configurations of single molecules, with dramatically improved imaging conditions in comparison to existing technologies. These capabilities are of immediate interest to a wide range of research and industry sectors in biotechnology, biophysics, materials, and chemistry.

  10. Mobility in geometrically confined membranes.

    PubMed

    Domanov, Yegor A; Aimon, Sophie; Toombes, Gilman E S; Renner, Marianne; Quemeneur, François; Triller, Antoine; Turner, Matthew S; Bassereau, Patricia

    2011-08-02

    Lipid and protein lateral mobility is essential for biological function. Our theoretical understanding of this mobility can be traced to the seminal work of Saffman and Delbrück, who predicted a logarithmic dependence of the protein diffusion coefficient (i) on the inverse of the size of the protein and (ii) on the "membrane size" for membranes of finite size [Saffman P, Delbrück M (1975) Proc Natl Acad Sci USA 72:3111-3113]. Although the experimental proof of the first prediction is a matter of debate, the second has not previously been thought to be experimentally accessible. Here, we construct just such a geometrically confined membrane by forming lipid bilayer nanotubes of controlled radii connected to giant liposomes. We followed the diffusion of individual molecules in the tubular membrane using single particle tracking of quantum dots coupled to lipids or voltage-gated potassium channels KvAP, while changing the membrane tube radius from approximately 250 to 10 nm. We found that both lipid and protein diffusion was slower in tubular membranes with smaller radii. The protein diffusion coefficient decreased as much as 5-fold compared to diffusion on the effectively flat membrane of the giant liposomes. Both lipid and protein diffusion data are consistent with the predictions of a hydrodynamic theory that extends the work of Saffman and Delbrück to cylindrical geometries. This study therefore provides strong experimental support for the ubiquitous Saffman-Delbrück theory and elucidates the role of membrane geometry and size in regulating lateral diffusion.

  11. Mobility in geometrically confined membranes

    PubMed Central

    Domanov, Yegor A.; Aimon, Sophie; Toombes, Gilman E. S.; Renner, Marianne; Quemeneur, François; Triller, Antoine; Turner, Matthew S.; Bassereau, Patricia

    2011-01-01

    Lipid and protein lateral mobility is essential for biological function. Our theoretical understanding of this mobility can be traced to the seminal work of Saffman and Delbrück, who predicted a logarithmic dependence of the protein diffusion coefficient (i) on the inverse of the size of the protein and (ii) on the “membrane size” for membranes of finite size [Saffman P, Delbrück M (1975) Proc Natl Acad Sci USA 72:3111—3113]. Although the experimental proof of the first prediction is a matter of debate, the second has not previously been thought to be experimentally accessible. Here, we construct just such a geometrically confined membrane by forming lipid bilayer nanotubes of controlled radii connected to giant liposomes. We followed the diffusion of individual molecules in the tubular membrane using single particle tracking of quantum dots coupled to lipids or voltage-gated potassium channels KvAP, while changing the membrane tube radius from approximately 250 to 10 nm. We found that both lipid and protein diffusion was slower in tubular membranes with smaller radii. The protein diffusion coefficient decreased as much as 5-fold compared to diffusion on the effectively flat membrane of the giant liposomes. Both lipid and protein diffusion data are consistent with the predictions of a hydrodynamic theory that extends the work of Saffman and Delbrück to cylindrical geometries. This study therefore provides strong experimental support for the ubiquitous Saffman–Delbrück theory and elucidates the role of membrane geometry and size in regulating lateral diffusion. PMID:21768336

  12. Effects of molecular potential and geometry on atomic core-level photoemission over an extended energy range - the case study of CO molecule

    NASA Astrophysics Data System (ADS)

    Kukk, E.; Ayuso, D.; Thomas, T. D.; Decleva, P.; Patanen, M.; Argenti, L.; Plésiat, E.; Palacios, A.; Kooser, K.; Travnikova, O.; Mondal, S.; Kimura, M.; Sakai, K.; Miron, C.; Martín, F.; Ueda, K.

    2014-04-01

    We report an experimental and theoretical study of single-molecule inner-shell photoemission over an extended range of photon energies. The vibrational ratios v=1/v=0 from the C 1s photoelectron spectra, although mostly determined by the bond length change, are shown to be affected also by photoelectron recoil and scattering on the neighboring oxygen atom. Density functional theory is used to encompass all these effect in unified treatment. It is also demonstrated that the DFT calculations can be used as a means to extract dynamic and static molecular geometry values.

  13. Quantum confinement in self-assembled two-dimensional nanoporous honeycomb networks at close-packed metal surfaces.

    PubMed

    Kepčija, N; Huang, T-J; Klappenberger, F; Barth, J V

    2015-03-14

    Quantum confinement of a two-dimensional electron gas by supramolecular nanoporous networks is investigated using the boundary elements method based on Green's functions for finite geometries and electron plane wave expansion for periodic systems. The "particle in a box" picture was analyzed for cases with selected symmetries that model previously reported architectures constructed from organic and metal-organic scattering centers confining surface state electrons of Ag(111) and Cu(111). First, by analyzing a series of cases with systematically defined parameters (scattering geometry, potentials, and effective broadening), we demonstrate how the scattering processes affect the properties of the confined electrons. For the features of the local density of states reported by scanning tunneling spectroscopy (STS), we disentangle the contributions of lifetime broadening and splitting of quantum well states due to coupling of neighboring quantum dots. For each system, we analyze the local electron density distribution and relate it to the corresponding band structure as calculated within the plane-wave expansion framework. Then, we address two experimental investigations, where in one case only STS data and in the other case mainly angle-resolved photoemission spectroscopy (ARPES) data were reported. In both cases, the experimental findings can be successfully simulated. Furthermore, the missing information can be complemented because our approach allows to correlate the information obtained by STS with that of ARPES. The combined analysis of several observations suggests that the scattering potentials created by the network originate primarily from the adsorbate-induced changes of the local surface dipole barrier.

  14. Quantum confinement in self-assembled two-dimensional nanoporous honeycomb networks at close-packed metal surfaces

    NASA Astrophysics Data System (ADS)

    Kepčija, N.; Huang, T.-J.; Klappenberger, F.; Barth, J. V.

    2015-03-01

    Quantum confinement of a two-dimensional electron gas by supramolecular nanoporous networks is investigated using the boundary elements method based on Green's functions for finite geometries and electron plane wave expansion for periodic systems. The "particle in a box" picture was analyzed for cases with selected symmetries that model previously reported architectures constructed from organic and metal-organic scattering centers confining surface state electrons of Ag(111) and Cu(111). First, by analyzing a series of cases with systematically defined parameters (scattering geometry, potentials, and effective broadening), we demonstrate how the scattering processes affect the properties of the confined electrons. For the features of the local density of states reported by scanning tunneling spectroscopy (STS), we disentangle the contributions of lifetime broadening and splitting of quantum well states due to coupling of neighboring quantum dots. For each system, we analyze the local electron density distribution and relate it to the corresponding band structure as calculated within the plane-wave expansion framework. Then, we address two experimental investigations, where in one case only STS data and in the other case mainly angle-resolved photoemission spectroscopy (ARPES) data were reported. In both cases, the experimental findings can be successfully simulated. Furthermore, the missing information can be complemented because our approach allows to correlate the information obtained by STS with that of ARPES. The combined analysis of several observations suggests that the scattering potentials created by the network originate primarily from the adsorbate-induced changes of the local surface dipole barrier.

  15. Confined Space Evaluation Student Manual, #19613

    SciTech Connect

    Chochoms, Michael

    2016-08-29

    Many workplaces contain spaces that are considered to be “confined” because their configuration hinders the activities of employees who must enter into, work in, and exit from them. In general, the permit-required confined spaces (PRCSs) Occupational Safety and Health Administration (OSHA) standard requires that Los Alamos National Laboratory (LANL) evaluate the workplace to determine if any spaces are PRCSs. The standard specifies strict procedures for the evaluation and atmospheric testing of a space before and during an entry by workers. The OSHA PRCS standard provides for alternative (less stringent than full-permit) entry procedures in cases where the only hazard in a space is atmospheric and the hazard can be controlled by forced air. At LANL, all confined spaces or potential confined spaces on LANL-owned or -operated property must be identified and evaluated by a confined space evaluator accompanied by a knowledgeable person. This course provides the information needed by confined space evaluators to make judgements about whether a space is a confined space, and if so, whether the space will require a permit for entry.

  16. Single string based global optimizer for geometry optimization in strongly coupled finite clusters: An adaptive mutation-driven strategy.

    PubMed

    Sarkar, Kanchan; Bhattacharyya, S P

    2013-08-21

    We propose and implement a simple adaptive heuristic to optimize the geometries of clusters of point charges or ions with the ability to find the global minimum energy configurations. The approach uses random mutations of a single string encoding the geometry and accepts moves that decrease the energy. Mutation probability and mutation intensity are allowed to evolve adaptively on the basis of continuous evaluation of past explorations. The resulting algorithm has been called Completely Adaptive Random Mutation Hill Climbing method. We have implemented this method to search through the complex potential energy landscapes of parabolically confined 3D classical Coulomb clusters of hundreds or thousands of charges--usually found in high frequency discharge plasmas. The energy per particle (EN∕N) and its first and second differences, structural features, distribution of the oscillation frequencies of normal modes, etc., are analyzed as functions of confinement strength and the number of charges in the system. Certain magic numbers are identified. In order to test the feasibility of the algorithm in cluster geometry optimization on more complex energy landscapes, we have applied the algorithm for optimizing the geometries of MgO clusters, described by Coulomb-Born-Mayer potential and finding global minimum of some Lennard-Jones clusters. The convergence behavior of the algorithm compares favorably with those of other existing global optimizers.

  17. Single string based global optimizer for geometry optimization in strongly coupled finite clusters: An adaptive mutation-driven strategy

    NASA Astrophysics Data System (ADS)

    Sarkar, Kanchan; Bhattacharyya, S. P.

    2013-08-01

    We propose and implement a simple adaptive heuristic to optimize the geometries of clusters of point charges or ions with the ability to find the global minimum energy configurations. The approach uses random mutations of a single string encoding the geometry and accepts moves that decrease the energy. Mutation probability and mutation intensity are allowed to evolve adaptively on the basis of continuous evaluation of past explorations. The resulting algorithm has been called Completely Adaptive Random Mutation Hill Climbing method. We have implemented this method to search through the complex potential energy landscapes of parabolically confined 3D classical Coulomb clusters of hundreds or thousands of charges—usually found in high frequency discharge plasmas. The energy per particle (EN/N) and its first and second differences, structural features, distribution of the oscillation frequencies of normal modes, etc., are analyzed as functions of confinement strength and the number of charges in the system. Certain magic numbers are identified. In order to test the feasibility of the algorithm in cluster geometry optimization on more complex energy landscapes, we have applied the algorithm for optimizing the geometries of MgO clusters, described by Coulomb-Born-Mayer potential and finding global minimum of some Lennard-Jones clusters. The convergence behavior of the algorithm compares favorably with those of other existing global optimizers.

  18. Learning Geometry through Dynamic Geometry Software

    ERIC Educational Resources Information Center

    Forsythe, Sue

    2007-01-01

    In this article, the author investigates effective teaching and learning of geometrical concepts using dynamic geometry software (DGS). Based from her students' reactions to her project, the author found that her students' understanding of the concepts was better than if they had learned geometry through paper-based tasks. However, mixing computer…

  19. Anomalous diffusion in confined turbulent convection.

    PubMed

    Boffetta, G; De Lillo, F; Musacchio, S

    2012-06-01

    Turbulent convection in quasi-one-dimensional geometry is studied by means of high-resolution direct numerical simulations within the framework of Rayleigh-Taylor turbulence. Geometrical confinement has dramatic effects on the dynamics of the turbulent flow, inducing a transition from superdiffusive to subdiffusive evolution of the mixing layer and arresting the growth of kinetic energy. A nonlinear diffusion model is shown to reproduce accurately the above phenomenology. The model is used to predict, without free parameters, the spatiotemporal evolution of the heat flux profile and the dependence of the Nusselt number on the Rayleigh number.

  20. Water self-diffusivity confined in graphene nanogap using molecular dynamics simulations

    NASA Astrophysics Data System (ADS)

    Moulod, M.; Hwang, G.

    2016-11-01

    Fundamental understanding of water confined in graphene is crucial to optimally design and operate sustainable energy, water desalination, and bio-medical systems. However, the current understanding predominantly remains in the static properties near the graphene surfaces. In this paper, a key water transport property, i.e., self-diffusivity, is examined under confinement by various graphene nanogap sizes (Lz = 0.7-4.17 nm), using molecular dynamics simulations with various graphene-water interatomic potentials (Simple Point Charge (SPC/E) and TIP3P water models). It is found that the water self-diffusivity nearly linearly decreases as the graphene-water interatomic potential energy increases at a given nanogap size. It also decreases as the graphene nanogap size decreases down to Lz = 1.34 nm; however, it shows the peak water self-diffusivity at Lz = 0.8 nm and then continues to decrease. The peak water self-diffusivity is related to the significant change of the overlapping surface force, and associated, nonlinear local water density distribution. The in-plane water self-diffusivity is higher up to nearly an order of magnitude than that of the out-of-plane due to the geometrical confinement effect by the graphene nanogap. The obtained results provide a roadmap to fundamentally understand the water transport properties in the graphene geometries and surface interactions.

  1. Effects of molecular potential and geometry on atomic core-level photoemission over an extended energy range: The case study of the CO molecule

    NASA Astrophysics Data System (ADS)

    Kukk, E.; Ayuso, D.; Thomas, T. D.; Decleva, P.; Patanen, M.; Argenti, L.; Plésiat, E.; Palacios, A.; Kooser, K.; Travnikova, O.; Mondal, S.; Kimura, M.; Sakai, K.; Miron, C.; Martín, F.; Ueda, K.

    2013-09-01

    We report an experimental and theoretical study of single-molecule inner-shell photoemission measured over an extended range of photon energies. The vibrational intensity ratios I(ν=1)/I(ν=0) from the C 1s photoelectron spectra of carbon monoxide, although mostly determined by the bond length change upon ionization, are shown to be affected also by photoelectron recoil and by scattering from the neighboring oxygen atom. Static-exchange density functional theory (DFT) is used to encompass all these effects in a unified theoretical treatment. The ab initio calculations show that the vibrational ratio as a function of the photoelectron momentum is sensitive to both the ground-state internuclear distance and its contraction upon photoionization. We present a proof-of-principle application of DFT calculations as a quantitative structural analysis tool for extracting the dynamic and static molecular geometry parameters simultaneously.

  2. Tomographic imaging of sub-basalt Mesozoic sediments and shallow basement geometry for hydrocarbon potential below the Deccan Volcanic Province (DVP) of India

    NASA Astrophysics Data System (ADS)

    Behera, Laxmidhar; Sen, Mrinal K.

    2014-10-01

    We have derived a shallow subsurface 2-D tomographic P-wave velocity image of the Deccan Volcanic Province (DVP) of India using first-arrival traveltime data along a 90-km-long N-S trending seismic profile in the Deccan Syneclise region. The tomographic image depicts smooth velocity variations of Quaternary and Tertiary (2.0-3.0 km s-1) sediments, basalts/traps (5.0-5.5 km s-1), sub-trappean Mesozoic sediments (4.3-4.5 km s-1) as well as the basement (5.9-6.1 km s-1) geometry down to a maximum depth of 5.0 km. Due to Late Cretaceous volcanism and outpouring of basaltic lava flows, this region is affected by numerous dyke intrusions and thick basaltic trap (2-3 km) exposed on the surface and surrounded by graben structures due to deep basinal faults forming a large igneous province. Although sub-basalt imaging is a major challenge for the oil industry, with the help of tomographic imaging technique of first-arrival seismic refraction data, we were able to image sub-trappean Mesozoic sediments (<0.75 km) deposited below the two sequences of thick basaltic flows above the basement. The imaged Mesozoic sediments are expected to contain hydrocarbon because of their wide extension in this sedimentary basin with suitable trapping mechanism due to basalts. The robustness of the velocity image is assessed through numerous tests like velocity perturbations, χ2 estimates, rms residuals of traveltime fit, uncertainty estimates through computation of ray-density or hits and series of checkerboard resolution tests with velocity anomalies having different cell size. The thickness of the basalt and the sub-trappean Mesozoic sediments along with the basement geometry obtained from tomography are constrained through ray-trace modelling and pre-stack depth migration (PSDM) of the wide-angle reflection phases for different shot gathers along the profile.

  3. Totally confined explosive welding

    NASA Technical Reports Server (NTRS)

    Bement, L. J. (Inventor)

    1978-01-01

    The undesirable by-products of explosive welding are confined and the association noise is reduced by the use of a simple enclosure into which the explosive is placed and in which the explosion occurs. An infrangible enclosure is removably attached to one of the members to be bonded at the point directly opposite the bond area. An explosive is completely confined within the enclosure at a point in close proximity to the member to be bonded and a detonating means is attached to the explosive. The balance of the enclosure, not occupied by explosive, is filled with a shaped material which directs the explosive pressure toward the bond area. A detonator adaptor controls the expansion of the enclosure by the explosive force so that the enclosure at no point experiences a discontinuity in expansion which causes rupture. The use of the technique is practical in the restricted area of a space station.

  4. Energy confinement in tokamaks

    SciTech Connect

    Sugihara, M.; Singer, C.

    1986-08-01

    A straightforward generalization is made of the ohmic heating energy confinement scalings of Pfeiffer and Waltz and Blackwell et. al. The resulting model is systematically calibrated to published data from limiter tokamaks with ohmic, electron cyclotron, and neutral beam heating. With considerably fewer explicitly adjustable free parameters, this model appears to give a better fit to the available data for limiter discharges than the combined ohmic/auxiliary heating model of Goldston.

  5. Classical confined particles

    NASA Technical Reports Server (NTRS)

    Horzela, Andrzej; Kapuscik, Edward

    1993-01-01

    An alternative picture of classical many body mechanics is proposed. In this picture particles possess individual kinematics but are deprived from individual dynamics. Dynamics exists only for the many particle system as a whole. The theory is complete and allows to determine the trajectories of each particle. It is proposed to use our picture as a classical prototype for a realistic theory of confined particles.

  6. Geometry and Erdkinder.

    ERIC Educational Resources Information Center

    McDonald, Nathaniel J.

    2001-01-01

    Chronicles a teacher's first year teaching geometry at the Hershey Montessori Farm School in Huntsburg, Ohio. Instructional methods relied on Euclid primary readings and combined pure abstract logic with practical applications of geometry on the land. The course included geometry background imparted by Montessori elementary materials as well as…

  7. Theory of inelastic confinement-induced resonances due to the coupling of center-of-mass and relative motion

    NASA Astrophysics Data System (ADS)

    Sala, Simon; Saenz, Alejandro

    2016-08-01

    A detailed study of the anharmonicity-induced resonances caused by the coupling of center-of-mass and relative motion is presented for a system of two ultracold atoms in single-well potentials. As has been confirmed experimentally, these inelastic confinement-induced resonances are of interest since they can lead to coherent molecule formation, losses, and heating in ultracold atomic gases. A perturbative model is introduced to describe the resonance positions and the coupling strengths. The validity of the model and the behavior of the resonances for different confinement geometries are analyzed in comparison with exact numerical ab initio calculations. While such resonances have so far only been detected for large positive values of the s -wave scattering length, it is found that they are present also for negative s -wave scattering lengths, i.e., for attractive interactions. The possibility to coherently tune the resonances by a variation of the external confinement geometry might pave the way for coherent molecule association where magnetic Feshbach resonances are inaccessible.

  8. Confinement of water droplets on rectangular micro/nano-arrayed surfaces.

    PubMed

    Kašpar, Ondřej; Zhang, Hailong; Tokárová, Viola; Boysen, Reinhard I; Suñé, Gemma Rius; Borrise, Xavier; Perez-Murano, Francesco; Hearn, Milton T W; Nicolau, Dan V

    2016-07-07

    Micro-patterned surfaces with alternate hydrophilic and hydrophobic rectangular areas effectively confine water droplets down to attolitre volumes. The contact angle, volume, and geometry of the confined droplets as a function of the geometry and physico-chemical properties of the confining surfaces have been determined by phenomenological simulations, validated by atomic force microscopy measurements. The combination between experiments and simulations can be used for the purposeful design of arrays with surface-addressable hydrophobicity employed in digital microfluidics and high-throughput screening nanoarrays.

  9. Electrons Confined with an Axially Symmetric Magnetic Mirror Field

    SciTech Connect

    Higaki, H.; Ito, K.; Kira, K.; Okamoto, H.

    2008-08-08

    Low energy non-neutral electron plasmas were confined with an axially symmetric magnetic mirror field and an electrostatic potential to investigate the basic confinement properties of a simple magnetic mirror trap. As expected the confinement time became longer as a function of the mirror ratio. The axial electrostatic oscillations of a confined electron plasma were also observed. Obtained results suggested an improved scheme to accumulate low energy charged particles with the use of a magnetic mirror field, which would enable the investigation of electron-positron plasmas.

  10. Magnetism in curved geometries

    NASA Astrophysics Data System (ADS)

    Streubel, Robert; Fischer, Peter; Kronast, Florian; Kravchuk, Volodymyr P.; Sheka, Denis D.; Gaididei, Yuri; Schmidt, Oliver G.; Makarov, Denys

    2016-09-01

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii-Moriya-like interaction. As a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. These recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.

  11. Magnetism in curved geometries

    SciTech Connect

    Streubel, Robert; Fischer, Peter; Kronast, Florian; Kravchuk, Volodymyr P.; Sheka, Denis D.; Gaididei, Yuri; Schmidt, Oliver G.; Makarov, Denys

    2016-08-17

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii–Moriya-like interaction. As a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. Finally, these recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.

  12. Magnetism in curved geometries

    DOE PAGES

    Streubel, Robert; Fischer, Peter; Kronast, Florian; ...

    2016-08-17

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii–Moriya-like interaction. Asmore » a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. Finally, these recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.« less

  13. Potential change in flaw geometry of an initially shallow finite-length surface flaw during a pressurized-thermal-shock transient

    SciTech Connect

    Shum, D.K.; Bryson, J.W.; Merkle, J.G.

    1993-09-01

    This study presents preliminary estimates on whether an shallow, axially oriented, inner-surface finite-length flaw in a PWR-RPV would tend to elongate in the axial direction and/or deepen into the wall of the vessel during a postulated PTS transient. Analysis results obtained based on the assumptions of (1) linear-elastic material response, and (2) cladding with same toughness as the base metal, indicate that a nearly semicircular flaw would likely propagate in the axial direction followed by propagation into the wall of the vessel. Note that these results correspond to initiation within the lower-shelf fracture toughness temperature range, and that their general validity within the lower-transition temperature range remains to be determined. The sensitivity of the numerical results aid conclusions to the following analysis assumptions are evaluated: (1) reference flaw geometry along the entire crack front and especially within the cladding region; (2) linear-elastic vs elastic-plastic description of material response; and (3) base-material-only vs bimaterial cladding-base vessel-model assumption. The sensitivity evaluation indicates that the analysis results are very sensitive to the above assumptions.

  14. MHD Stability of Centrifugally Confined Plasmas

    NASA Astrophysics Data System (ADS)

    Huang, Yi-Min

    2003-10-01

    Centrifugally confined plasmas utilize centrifugal forces from plasma rotation to augment magnetic confinement, as an alternative approach to fusion. One magnetic geometry is mirror-type, with rotation about the axis induced from a central, biased core conductor. The outward centrifugal forces from the rotation have a component along the field lines, thus confining ions to the center. The immediate concern, of course, is that the system could be flute unstable to the interchange. The antidote here is that the radial shear in the rotation could stabilize the flute. Our 2D simulations show, first, that plasma pressure is highly peaked at the center away from the mirror end coils. Next, 3D simulations show unequivocally that velocity shear is providing the stability. Further study indicates that the flute stability is sensitive to the density profile. A favorable density profile could be achieved by judiciously placing the particle source, also necessary for a steady state centrifuge. As flows approach the Alfven speed, electromagnetic modes could be involved. The latter is motivated by the question of whether magnetorotational instability, thought to be an angular momentum transporter in accretion disks, could be found in centrifugal plasmas, since all the ingredients are there. We show that the MRI as understood should be stable; however, a related astrophysical instability, the Parker instability, could arise. The Parker instability results in plasma accumulating in regions of bent field lines, further accentuating the bending.

  15. Solid phase extraction of lactic acid from fermentation broth by anion-exchangeable silica confined ionic liquids.

    PubMed

    Bi, Wentao; Zhou, Jun; Row, Kyung Ho

    2011-01-15

    Three anion-exchangeable, silica-confined ionic liquids were synthesized for solid phase extraction of lactic acid from fermentation broth, followed by high-performance liquid chromatography coupled to ultraviolet detection. By comparing the adsorption isotherms of lactic acid on different silica-confined ionic liquids, interactions between the lactic acid and sorbents were investigated. The adsorbed amounts were then fitted into different adsorption isotherm equations; finally, the Langmuir equation was selected. Then the imidazolium silica with the highest adsorption capacity of lactic acid was packed into a cartridge for solid phase extraction. The loading volume of the cartridge was optimized by the Langmuir equation and geometry. After washing with distilled water and eluting with 0.25 mol L(-1) of an HCl solution, the lactic acid was separated from interference with a recovery yield of 91.9%. Furthermore, this kind of anion-exchangeable material exhibited potential for industrial applications and separation of other anionic bioactive compounds.

  16. Colloid-polymer mixtures under slit confinement.

    PubMed

    Pérez-Ramírez, Allan; Figueroa-Gerstenmaier, Susana; Odriozola, Gerardo

    2017-03-14

    We report a NVT molecular dynamic study of colloid-polymer mixtures under slit confinement. For this purpose, we are employing the Asakura-Oosawa model for studying colloidal particles, polymer coils, and hard walls as the external confining field. The colloid-polymer size ratio, q, is varied in the range 1⩾q⩾0.4 and the confinement distance, H, in 10σc⩾H⩾3σc, σc being the colloidal diameter. Vapor-liquid coexistence properties are assessed, from which phase diagrams are built. The obtained data fulfill the corresponding states law for a constant H when q is varied. The shift of the polymer and colloidal chemical potentials of coexistence follows a linear relationship with (H-σc)(-1) for H≳4σc. The confined vapor-liquid interfaces can be fitted with a semicircular line of curvature (H-σc)(-1), from which the contact angle can be obtained. We observe complete wetting of the confining walls for reservoir polymer concentrations above and close to the critical value, and partial wetting for reservoir polymer concentrations above and far from it.

  17. Colloid-polymer mixtures under slit confinement

    NASA Astrophysics Data System (ADS)

    Pérez-Ramírez, Allan; Figueroa-Gerstenmaier, Susana; Odriozola, Gerardo

    2017-03-01

    We report a NVT molecular dynamic study of colloid-polymer mixtures under slit confinement. For this purpose, we are employing the Asakura-Oosawa model for studying colloidal particles, polymer coils, and hard walls as the external confining field. The colloid-polymer size ratio, q, is varied in the range 1 ⩾q ⩾0.4 and the confinement distance, H, in 10 σc ⩾H ⩾3 σc , σc being the colloidal diameter. Vapor-liquid coexistence properties are assessed, from which phase diagrams are built. The obtained data fulfill the corresponding states law for a constant H when q is varied. The shift of the polymer and colloidal chemical potentials of coexistence follows a linear relationship with (H-σc ) -1 for H ≳4 σc . The confined vapor-liquid interfaces can be fitted with a semicircular line of curvature (H-σc ) -1, from which the contact angle can be obtained. We observe complete wetting of the confining walls for reservoir polymer concentrations above and close to the critical value, and partial wetting for reservoir polymer concentrations above and far from it.

  18. Confinement studies in TFTR

    SciTech Connect

    Murakami, M.; Arunasalam, V.; Bell, J.D.; Bell, M.G.; Bitter, M.; Blanchard, W.R.; Boody, F.; Boyd, D.; Bretz, N.; Bush, C.E.

    1985-06-01

    The paper describes the present (end of February 1985) status of the plasma confinement studies in the TFTR tokamak with emphasis on those with neutral beam injection (NBI). Recent improvements in the device capabilities have substantially extended operating parameters: B/sub T/ increased to 4.0 T, I/sub p/ to 2.0 MA, injection power (P/sub b/) to 5 MW with H/sup 0/ or D/sup 0/ beams anti n/sub e/ to 5 x 10/sup 19/ m/sup -3/, and Z/sub eff/ reduced to 1.4. With ohmic heating (OH) alone, the previously established scaling for gross energy confinement time (tau/sub E/ = anti n/sub e/q) has been confirmed at higher I/sub p/ and B/sub T/, and the maximum tau/sub E/ of 0.4 sec has been achieved. With NBI at P/sub b/ substantially (by factor >2) higher than P/sub OH/, excellent power and particle accountability have been established. This suggests that the less-than-expected increase in stored energy with NBI is not due to problems of power delivery, but due to problems of confinement deterioration. tau/sub E/ is observed to scale approximately as I/sub p/ P/sub b//sup -0.5/ (independent of anti n/sub e/), consistent with previous L-mode scalings. With NBI we have achieved the maximum tau/sub E/ of 0.2 sec and the maximum T/sub i/(o) of 4.4 keV in the normal operating regime, and even higher T/sub i/(o) in the energetic-ion regime with low-n/sub e/ and low-I/sub p/ operation.

  19. Quark confinement dynamics

    SciTech Connect

    Allen, T.J.; Olsson, M.G.; Veseli, S.; Williams, K. |

    1997-05-01

    Starting from Buchm{umlt u}ller{close_quote}s observation that a chromoelectric flux tube meson will exhibit only the Thomas-type spin-orbit interaction, we show that a model built upon the related assumption that a quark feels only a constant radial chromoelectric field in its rest frame implies a complete relativistic effective Hamiltonian that can be written explicitly in terms of quark canonical variables. The model yields linear Regge trajectories and exhibits some similarities to scalar confinement, but with the advantage of being more closely linked to QCD. {copyright} {ital 1997} {ital The American Physical Society}

  20. Confinement Vessel Dynamic Analysis

    SciTech Connect

    R. Robert Stevens; Stephen P. Rojas

    1999-08-01

    A series of hydrodynamic and structural analyses of a spherical confinement vessel has been performed. The analyses used a hydrodynamic code to estimate the dynamic blast pressures at the vessel's internal surfaces caused by the detonation of a mass of high explosive, then used those blast pressures as applied loads in an explicit finite element model to simulate the vessel's structural response. Numerous load cases were considered. Particular attention was paid to the bolted port connections and the O-ring pressure seals. The analysis methods and results are discussed, and comparisons to experimental results are made.

  1. Confinement Contains Condensates

    SciTech Connect

    Brodsky, Stanley J.; Roberts, Craig D.; Shrock, Robert; Tandy, Peter C.

    2012-03-12

    Dynamical chiral symmetry breaking and its connection to the generation of hadron masses has historically been viewed as a vacuum phenomenon. We argue that confinement makes such a position untenable. If quark-hadron duality is a reality in QCD, then condensates, those quantities that have commonly been viewed as constant empirical mass-scales that fill all spacetime, are instead wholly contained within hadrons; i.e., they are a property of hadrons themselves and expressed, e.g., in their Bethe-Salpeter or light-front wave functions. We explain that this paradigm is consistent with empirical evidence, and incidentally expose misconceptions in a recent Comment.

  2. Z-Pinch Generated X-Rays in Static-Wall Hohlraum Geometry Demonstrate Potential for Indirect-Drive ICF Studies

    SciTech Connect

    Sandord, T.W.L.; Olson, R.E.; Chandler, G.A.; Hebron, D.E.; Mock, R.C.; Leeper, R.J.; Nash, T.J.; Ruggles, L.E.; Simpson, W.W.; Struve, K.W.; Vesey, R.A.; Bowers, R.L.; Matuska, W.; Peterson, D.L.; Peterson, R.R.

    1999-08-25

    Hohlraums of full ignition scale (6-mm diameter by 7-mm length) have been heated by x-rays from a z-pinch target on Z to a variety of temperatures and pulse shapes which can be used to simulate the early phases of the National Ignition Facility (NIF) temperature drive. The pulse shape is varied by changing the on-axis target of the z pinch in a static-wall-hohlraum geometry. A 2-{micro}m-thick walled Cu cylindrical target of 8-mm diameter filled with 10 mg/cm{sup 3} CH, for example, produces foot-pulse conditions of {minus}85 eV for a duration of {approximately} 10 ns, while a solid cylindrical target of 5-mm diameter and 14-mg/cm{sup 3} CH generates first-step-pulse conditions of {approximately} 122 eV for a duration of a few ns. Alternatively, reducing the hohlraum size (to 4-mm diameter by 4-mm length) with the latter target has increased the peak temperature to {approximately} 150 eV, which is characteristic of a second-step-pulse temperature. In general, the temperature T of these x-ray driven hohlraums is in agreement with the Planckian relation (T-(P/A){sup 1/4}). P is the measured x-ray input power and A is the surface area of the hohlraum. Fully-integrated 2-D radiation-hydrodynamic simulations of the z pinch and subsequent hohlraum heating show plasma densities within the useful volume of the hohlraums to be on the order of air or less.

  3. Phonon lateral confinement enables thermal rectification in asymmetric single-material nanostructures.

    PubMed

    Wang, Yan; Vallabhaneni, Ajit; Hu, Jiuning; Qiu, Bo; Chen, Yong P; Ruan, Xiulin

    2014-02-12

    We show that thermal rectification (TR) in asymmetric graphene nanoribbons (GNRs) is originated from phonon confinement in the lateral dimension, which is a fundamentally new mechanism different from that in macroscopic heterojunctions. Our molecular dynamics simulations reveal that, though TR is significant in nanosized asymmetric GNRs, it diminishes at larger width. By solving the heat diffusion equation, we prove that TR is indeed absent in both the total heat transfer rate and local heat flux for bulk-size asymmetric single materials, regardless of the device geometry or the anisotropy of the thermal conductivity. For a deeper understanding of why lateral confinement is needed, we have performed phonon spectra analysis and shown that phonon lateral confinement can enable three possible mechanisms for TR: phonon spectra overlap, inseparable dependence of thermal conductivity on temperature and space, and phonon edge localization, which are essentially related to each other in a complicated manner. Under such guidance, we demonstrate that other asymmetric nanostructures, such as asymmetric nanowires, thin films, and quantum dots, of a single material are potentially high-performance thermal rectifiers.

  4. Spatially confined assembly of nanoparticles.

    PubMed

    Jiang, Lin; Chen, Xiaodong; Lu, Nan; Chi, Lifeng

    2014-10-21

    The ability to assemble NPs into ordered structures that are expected to yield collective physical or chemical properties has afforded new and exciting opportunities in the field of nanotechnology. Among the various configurations of nanoparticle assemblies, two-dimensional (2D) NP patterns and one-dimensional (1D) NP arrays on surfaces are regarded as the ideal assembly configurations for many technological devices, for example, solar cells, magnetic memory, switching devices, and sensing devices, due to their unique transport phenomena and the cooperative properties of NPs in assemblies. To realize the potential applications of NP assemblies, especially in nanodevice-related applications, certain key issues must still be resolved, for example, ordering and alignment, manipulating and positioning in nanodevices, and multicomponent or hierarchical structures of NP assemblies for device integration. Additionally, the assembly of NPs with high precision and high levels of integration and uniformity for devices with scaled-down dimensions has become a key and challenging issue. Two-dimensional NP patterns and 1D NP arrays are obtained using traditional lithography techniques (top-down strategies) or interfacial assembly techniques (bottom-up strategies). However, a formidable challenge that persists is the controllable assembly of NPs in desired locations over large areas with high precision and high levels of integration. The difficulty of this assembly is due to the low efficiency of small features over large areas in lithography techniques or the inevitable structural defects that occur during the assembly process. The combination of self-assembly strategies with existing nanofabrication techniques could potentially provide effective and distinctive solutions for fabricating NPs with precise position control and high resolution. Furthermore, the synergistic combination of spatially mediated interactions between nanoparticles and prestructures on surfaces may play

  5. Aerofractures in Confined Granular Media

    NASA Astrophysics Data System (ADS)

    Eriksen, Fredrik K.; Turkaya, Semih; Toussaint, Renaud; Måløy, Knut J.; Flekkøy, Eirik G.

    2015-04-01

    We will present the optical analysis of experimental aerofractures in confined granular media. The study of this generic process may have applications in industries involving hydraulic fracturing of tight rocks, safe construction of dams, tunnels and mines, and in earth science where phenomena such as mud volcanoes and sand injectites are results of subsurface sediment displacements driven by fluid overpressure. It is also interesting to increase the understanding the flow instability itself, and how the fluid flow impacts the solid surrounding fractures and in the rest of the sample. Such processes where previously studied numerically [Niebling 2012a, Niebling 2012b] or in circular geometries. We will here explore experimentally linear geometries. We study the fracturing patterns that form when air flows into a dense, non-cohesive porous medium confined in a Hele-Shaw cell - i.e. into a packing of dry 80 micron beads placed between two glass plates separated by ~1mm. The cell is rectangular and fitted with a semi-permeable boundary to the atmosphere - blocking beads but not air - on one short edge, while the other three edges are impermeable. The porous medium is packed inside the cell between the semi-permeable boundary and an empty volume at the sealed side where the air pressure can be set and kept at a constant overpressure (1-2bar). Thus, for the air trapped inside the cell to release the overpressure it has to move through the solid. At high enough overpressures the air flow deforms the solid and increase permeability in some regions along the air-solid interface, which results in unstable flow and aerofracturing. Aerofractures are thought to be an analogue to hydrofractures, and an advantage of performing aerofracturing experiments in a Hele-Shaw cell is that the fracturing process can easily be observed in the lab. Our experiments are recorded with a high speed camera with a framerate of 1000 frames per second. In the analysis, by using various image

  6. Confinement Correction to Mercury Intrusion Capillary Pressure of Shale Nanopores

    PubMed Central

    Wang, Sen; Javadpour, Farzam; Feng, Qihong

    2016-01-01

    We optimized potential parameters in a molecular dynamics model to reproduce the experimental contact angle of a macroscopic mercury droplet on graphite. With the tuned potential, we studied the effects of pore size, geometry, and temperature on the wetting of mercury droplets confined in organic-rich shale nanopores. The contact angle of mercury in a circular pore increases exponentially as pore size decreases. In conjunction with the curvature-dependent surface tension of liquid droplets predicted from a theoretical model, we proposed a technique to correct the common interpretation procedure of mercury intrusion capillary pressure (MICP) measurement for nanoporous material such as shale. Considering the variation of contact angle and surface tension with pore size improves the agreement between MICP and adsorption-derived pore size distribution, especially for pores having a radius smaller than 5 nm. The relative error produced in ignoring these effects could be as high as 44%—samples that contain smaller pores deviate more. We also explored the impacts of pore size and temperature on the surface tension and contact angle of water/vapor and oil/gas systems, by which the capillary pressure of water/oil/gas in shale can be obtained from MICP. This information is fundamental to understanding multiphase flow behavior in shale systems. PMID:26832445

  7. Confinement Correction to Mercury Intrusion Capillary Pressure of Shale Nanopores

    NASA Astrophysics Data System (ADS)

    Wang, Sen; Javadpour, Farzam; Feng, Qihong

    2016-02-01

    We optimized potential parameters in a molecular dynamics model to reproduce the experimental contact angle of a macroscopic mercury droplet on graphite. With the tuned potential, we studied the effects of pore size, geometry, and temperature on the wetting of mercury droplets confined in organic-rich shale nanopores. The contact angle of mercury in a circular pore increases exponentially as pore size decreases. In conjunction with the curvature-dependent surface tension of liquid droplets predicted from a theoretical model, we proposed a technique to correct the common interpretation procedure of mercury intrusion capillary pressure (MICP) measurement for nanoporous material such as shale. Considering the variation of contact angle and surface tension with pore size improves the agreement between MICP and adsorption-derived pore size distribution, especially for pores having a radius smaller than 5 nm. The relative error produced in ignoring these effects could be as high as 44%—samples that contain smaller pores deviate more. We also explored the impacts of pore size and temperature on the surface tension and contact angle of water/vapor and oil/gas systems, by which the capillary pressure of water/oil/gas in shale can be obtained from MICP. This information is fundamental to understanding multiphase flow behavior in shale systems.

  8. Confinement Correction to Mercury Intrusion Capillary Pressure of Shale Nanopores.

    PubMed

    Wang, Sen; Javadpour, Farzam; Feng, Qihong

    2016-02-01

    We optimized potential parameters in a molecular dynamics model to reproduce the experimental contact angle of a macroscopic mercury droplet on graphite. With the tuned potential, we studied the effects of pore size, geometry, and temperature on the wetting of mercury droplets confined in organic-rich shale nanopores. The contact angle of mercury in a circular pore increases exponentially as pore size decreases. In conjunction with the curvature-dependent surface tension of liquid droplets predicted from a theoretical model, we proposed a technique to correct the common interpretation procedure of mercury intrusion capillary pressure (MICP) measurement for nanoporous material such as shale. Considering the variation of contact angle and surface tension with pore size improves the agreement between MICP and adsorption-derived pore size distribution, especially for pores having a radius smaller than 5 nm. The relative error produced in ignoring these effects could be as high as 44%--samples that contain smaller pores deviate more. We also explored the impacts of pore size and temperature on the surface tension and contact angle of water/vapor and oil/gas systems, by which the capillary pressure of water/oil/gas in shale can be obtained from MICP. This information is fundamental to understanding multiphase flow behavior in shale systems.

  9. Beam ion confinement on NSTX-U

    NASA Astrophysics Data System (ADS)

    Liu, D.; Heidbrink, W. W.; Hao, G. Z.; Podesta, M.; Darrow, D. S.; Fredrickson, E. D.

    2016-10-01

    A second and more tangential neutral beam line is a major upgrade component of the National Spherical Torus Experiment - Upgrade (NSTX-U) with the purpose of improving neutral beam current drive efficiency and providing more flexibility in current/pressure profile control. Good beam ion confinement is essential to achieve the anticipated improvements in performance. In the planned beam ion confinement experiment, various short and long (relative to fast ion slowing-down time) neutral beam (NB) pulses from six neutral beam sources will be injected into center-stack limited L-mode plasmas to characterize the beam ion confinement and distribution function produced by the new and the existing NBI lines. The neutron rate decay after the turn-off of short NB pulses will be used to estimate the beam ion confinement time and to investigate its dependence on NB source/geometry, injection energy, and plasma current. The tangential and vertical Fast-Ion D-Alpha (FIDA) diagnostics and multi-view Solid State Neutral Particle Analyzer (SSNPA) arrays will be used to measure beam ion slowing-down distribution function and spatial profile during the injection of relatively long NB pulses. Beam ion prompt losses will be monitored with a scintillator Fast Lost Ion Probe (sFLIP) diagnostic. The experimental data and comparisons with classical predictions from NUBEAM modeling will be presented. Work supported by U.S. DOE DE-AC0209CH11466, DE-FG02-06ER54867, and DE-FG03-02ER54681.

  10. The Properties of Confined Water and Fluid Flow at the Nanoscale

    SciTech Connect

    Schwegler, E; Reed, J; Lau, E; Prendergast, D; Galli, G; Grossman, J C; Cicero, G

    2009-03-09

    This project has been focused on the development of accurate computational tools to study fluids in confined, nanoscale geometries, and the application of these techniques to probe the structural and electronic properties of water confined between hydrophilic and hydrophobic substrates, including the presence of simple ions at the interfaces. In particular, we have used a series of ab-initio molecular dynamics simulations and quantum Monte Carlo calculations to build an understanding of how hydrogen bonding and solvation are modified at the nanoscale. The properties of confined water affect a wide range of scientific and technological problems - including protein folding, cell-membrane flow, materials properties in confined media and nanofluidic devices.

  11. Study of the Potential Earthquake Risk in the Western United States by the LURR Method Based on the Seismic Catalogue, Fault Geometry and Focal Mechanisms

    NASA Astrophysics Data System (ADS)

    Zhang, Yongxian; Yikilmaz, M. Burak; Rundle, John B.; Yin, Xiangchu; Liu, Yue; Zhang, Langping; Wang, Zijin

    2015-08-01

    Based on the load/unload response ratio (LURR) theory, spatial and temporal variation of Y/ Y c (value of LURR/critical value of LURR under 90 % confidence) in the western United States and its adjacent area (31°-44°N, -128° to -112°E) during the period from 1980 to 2011 was studied. The selected study area was zoned into 20 sub-regions, in each of which the fault geometry and the focal mechanisms were very similar such that the stress fields were almost uniform. The loading and unloading periods were determined by calculating perturbations in the Coulomb failure stress in each sub-regions induced by earth tides. Earthquakes occurring in these sub-regions were identified as a loading or unloading type, and the response rate was chosen as the Benioff strain that can be calculated from earthquake magnitude M. With a time window of 1 year, a time moving step of 1 month, a space window of a circle region with a radius of 100 km, and a space moving step of 0.5° latitudinally and longitudinally, snapshots of the evolution of Y/ Y c were generated. Scanning results show that obvious Y/ Y c anomalies can be detected near the epicenter of all big earthquakes larger than M6.5 in regions with reasonable seismic monitoring abilities. They also show Y/ Y c anomalies occurred several years prior to the big earthquakes and the lasting time of the anomaly is from one year to several years. For some LURR anomalous regions, however, no earthquakes occurred. According to the characteristics of LURR anomalies, two regions with a high risk of big earthquakes were detected. One is between the northern region of the Bay Area and the Mendocino triple junction (38°-40°N, -124° to -122°E) and the other is between Lake Tahoe and Mono Lake (37.5°-39.5°N, -120° to -118°E) along the border of California and Nevada.

  12. Riemannian geometry of fluctuation theory: An introduction

    NASA Astrophysics Data System (ADS)

    Velazquez, Luisberis

    2016-05-01

    Fluctuation geometry was recently proposed as a counterpart approach of Riemannian geometry of inference theory (information geometry), which describes the geometric features of the statistical manifold M of random events that are described by a family of continuous distributions dpξ(x|θ). This theory states a connection among geometry notions and statistical properties: separation distance as a measure of relative probabilities, curvature as a measure about the existence of irreducible statistical correlations, among others. In statistical mechanics, fluctuation geometry arises as the mathematical apparatus of a Riemannian extension of Einstein fluctuation theory, which is also closely related to Ruppeiner geometry of thermodynamics. Moreover, the curvature tensor allows to express some asymptotic formulae that account for the system fluctuating behavior beyond the gaussian approximation, while curvature scalar appears as a second-order correction of Legendre transformation between thermodynamic potentials.

  13. Home versus hospital confinement

    PubMed Central

    Barry, C. N.

    1980-01-01

    The case for hospital rather than home delivery has been powerfully argued, especially in and since the Report of the Peel Committee. Nevertheless, evidence of comparison with other countries, notably the Netherlands, suggests the choice is not necessarily simple. Some general practitioner units are now reporting perinatal mortality rates which are consistently lower than those of specialist units, and recent statistical analyses suggest that the presence of more high risk cases in consultant units does not explain this. The only big controlled home-versus-hospital trial did not lead to a significantly lower perinatal mortality rate in the hospital group. The onus of proof now seems to lie with those who advocate 100 per cent hospital confinement. PMID:7373581

  14. Dynamics of Confined Water Molecules in Aqueous Salt Hydrates

    SciTech Connect

    Werhahn, Jasper C.; Pandelov, S.; Yoo, Soohaeng; Xantheas, Sotiris S.; Iglev, H.

    2011-04-01

    The unusual properties of water are largely dictated by the dynamics of the H bond network. A single water molecule has more H bonding sites than atoms, hence new experimental and theoretical investigations about this peculiar liquid have not ceased to appear. Confinement of water to nanodroplets or small molecular clusters drastically changes many of the liquid’s properties. Such confined water plays a major role in the solvation of macro molecules such as proteins and can even be essential to their properties. Despite the vast results available on bulk and confined water, discussions about the correlation between spectral and structural properties continue to this day. The fast relaxation of the OH stretching vibration in bulk water, and the variance of sample geometries in the experiments on confined water obfuscate definite interpretation of the spectroscopic results in terms of structural parameters. We present first time-resolved investigations on a new model system that is ideally suited to overcome many of the problems faced in spectroscopical investigation of the H bond network of water. Aqueous hydrates of inorganic salts provide water molecules in a crystal grid, that enables unambiguous correlations of spectroscopic and structural features. Furthermore, the confined water clusters are well isolated from each other in the crystal matrix, so different degrees of confinement can be achieved by selection of the appropriate salt.

  15. CUSP Energetic Particles: Confinement, Acceleration and Implications

    NASA Technical Reports Server (NTRS)

    Chen, Jiasheng

    1999-01-01

    The cusp energetic particle (CEP) event is a new magnetospheric phenomenon. The events were detected in the dayside cusp for hours, in which the measured helium ions had energies up to 8 MeV. All of these events were associated with a dramatic decrease and large fluctuations in the local magnetic field strength. During January 1999 - December 1999 covered by this report, I have studied the CEP events by analyzing the POLAR, GEOTAIL, and WIND particle and magnetic field data measured during the geomagnetic quiet periods in 1996 and one geomagnetic storm period in 1998. The simultaneous observations indicated that the ion fluxes in the CEP events were higher than that in both the upstream and the downstream from the bow shock. The pitch angle distribution of the helium ions in the CEP events was found to peak around 90 deg. It was found that the mirror parameter, defined as the ratio of the square root of the integration of the parallel turbulent power spectral component over the ultra-low frequency (ULF) ranges to the mean field in the cusp, is correlated with the intensity of the cusp MeV helium flux, which is a measure of the influence of mirroring interactions and an indication of local effect. It was also found that the turbulent power of the local magnetic field in the ultra-low frequency (ULF) ranges is correlated with the intensity of the cusp energetic helium ions. Such ULF ranges correspond to periods of about 0.33-500 seconds that cover the gyroperiods, the bounce periods, and the drift periods of the tens keV to MeV charged particles when they are temporarily confined in the high-altitude dayside cusp. These observations represent a discovery that the high-altitude dayside cusp is a new acceleration and dynamic trapping region of the magnetosphere. The cusp geometry is connected via gradient and curvature drift of these energized ions to the equatorial plasma sheet as close as the geostationary orbit at local midnight. It implies that the dayside cusp is

  16. Onset of anomalous diffusion in colloids confined to quasimonolayers

    NASA Astrophysics Data System (ADS)

    Bleibel, J.; Domínguez, Alvaro; Oettel, M.

    2017-03-01

    It has been recently shown that a colloidal monolayer, e.g., formed at a fluid interface or by means of a suitable confining potential, exhibits anomalous collective diffusion. This is a consequence of the hydrodynamic interactions mediated by the three-dimensional (3D) ambient fluid when the particles are confined to reside on a two-dimensional (2D) manifold. We study theoretically and with numerical simulations the crossover from normal to anomalous diffusion as the particles are, in real systems, confined by a 3D external potential and thus have the possibility to fluctuate out of the 2D manifold, thus forming a quasimonolayer.

  17. Geometry of multihadron production

    SciTech Connect

    Bjorken, J.D.

    1994-10-01

    This summary talk only reviews a small sample of topics featured at this symposium: Introduction; The Geometry and Geography of Phase space; Space-Time Geometry and HBT; Multiplicities, Intermittency, Correlations; Disoriented Chiral Condensate; Deep Inelastic Scattering at HERA; and Other Contributions.

  18. Geometry + Technology = Proof

    ERIC Educational Resources Information Center

    Lyublinskaya, Irina; Funsch, Dan

    2012-01-01

    Several interactive geometry software packages are available today to secondary school teachers. An example is The Geometer's Sketchpad[R] (GSP), also known as Dynamic Geometry[R] software, developed by Key Curriculum Press. This numeric based technology has been widely adopted in the last twenty years, and a vast amount of creativity has been…

  19. Euclidean Geometry via Programming.

    ERIC Educational Resources Information Center

    Filimonov, Rossen; Kreith, Kurt

    1992-01-01

    Describes the Plane Geometry System computer software developed at the Educational Computer Systems laboratory in Sofia, Bulgaria. The system enables students to use the concept of "algorithm" to correspond to the process of "deductive proof" in the development of plane geometry. Provides an example of the software's capability…

  20. The Beauty of Geometry

    ERIC Educational Resources Information Center

    Morris, Barbara H.

    2004-01-01

    This article describes a geometry project that used the beauty of stained-glass-window designs to teach middle school students about geometric figures and concepts. Three honors prealgebra teachers and a middle school mathematics gifted intervention specialist created a geometry project that covered the curriculum and also assessed students'…

  1. Oscillations of a fiber flowing in a confined microchannel

    NASA Astrophysics Data System (ADS)

    Berthet, Helene; Fermigier, Marc; Daccord, Gerard; Lindner, Anke

    2011-11-01

    Transport of slender bodies in confined geometries is of interest in various industrial applications. In the oil industry, fibers are widely used for stimulation or to prevent losses into the rock formations. Applications can also be found in biology systems such as targeted drug delivery. We present an experimental and numerical investigation of the flow of an advected fiber in a confined microchannel. The fiber is fabricated in situ using a photo-polymerization method to ensure an excellent control of its geometry and its mechanical properties. When imposing a constant flowrate, we observe that the fiber oscillates continuously between the lateral walls until it exits the channel. We characterize the oscillation period as a function of the flow velocity, the fiber length and channel width. This phenomenon can be used to generate efficient mixing at the microscale.

  2. Geometry of membrane fission.

    PubMed

    Frolov, Vadim A; Escalada, Artur; Akimov, Sergey A; Shnyrova, Anna V

    2015-01-01

    Cellular membranes define the functional geometry of intracellular space. Formation of new membrane compartments and maintenance of complex organelles require division and disconnection of cellular membranes, a process termed membrane fission. Peripheral membrane proteins generally control membrane remodeling during fission. Local membrane stresses, reflecting molecular geometry of membrane-interacting parts of these proteins, sum up to produce the key membrane geometries of fission: the saddle-shaped neck and hour-glass hemifission intermediate. Here, we review the fundamental principles behind the translation of molecular geometry into membrane shape and topology during fission. We emphasize the central role the membrane insertion of specialized protein domains plays in orchestrating fission in vitro and in cells. We further compare individual to synergistic action of the membrane insertion during fission mediated by individual protein species, proteins complexes or membrane domains. Finally, we describe how local geometry of fission intermediates defines the functional design of the protein complexes catalyzing fission of cellular membranes.

  3. Confined Mobility of TonB and FepA in Escherichia coli Membranes

    PubMed Central

    Lill, Yoriko; Jordan, Lorne D.; Smallwood, Chuck R.; Newton, Salete M.; Lill, Markus A.; Klebba, Phillip E.; Ritchie, Ken

    2016-01-01

    The important process of nutrient uptake in Escherichia coli, in many cases, involves transit of the nutrient through a class of beta-barrel proteins in the outer membrane known as TonB-dependent transporters (TBDTs) and requires interaction with the inner membrane protein TonB. Here we have imaged the mobility of the ferric enterobactin transporter FepA and TonB by tracking them in the membranes of live E. coli with single-molecule resolution at time-scales ranging from milliseconds to seconds. We employed simple simulations to model/analyze the lateral diffusion in the membranes of E.coli, to take into account both the highly curved geometry of the cell and artifactual effects expected due to finite exposure time imaging. We find that both molecules perform confined lateral diffusion in their respective membranes in the absence of ligand with FepA confined to a region 0.180−0.007+0.006 μm in radius in the outer membrane and TonB confined to a region 0.266−0.009+0.007 μm in radius in the inner membrane. The diffusion coefficient of these molecules on millisecond time-scales was estimated to be 21−5+9 μm2/s and 5.4−0.8+1.5 μm2/s for FepA and TonB, respectively, implying that each molecule is free to diffuse within its domain. Disruption of the inner membrane potential, deletion of ExbB/D from the inner membrane, presence of ligand or antibody to FepA and disruption of the MreB cytoskeleton was all found to further restrict the mobility of both molecules. Results are analyzed in terms of changes in confinement size and interactions between the two proteins. PMID:27935943

  4. Role of Dynamical Heterogeneities on the Mechanical Response of Confined Polymer

    NASA Astrophysics Data System (ADS)

    Masurel, R. J.; Gelineau, P.; Cantournet, S.; Dequidt, A.; Long, D. R.; Lequeux, F.; Montes, H.

    2017-01-01

    Confinement induces various modifications in the dynamics of polymers as compared to bulk. We focus here on the role of dynamical heterogeneities on the mechanics of confined polymers. Using a simple model that allows computation of the mechanical response over 10 decades in frequency, we show that the local mechanical coupling controlling the macroscopic response in the bulk disappears in a confined geometry. The slowest domains significantly contribute to the mechanical response for increasing confinement. As a consequence, the apparent glass transition is broadened and shifted towards lower frequencies as confinement increases. We compare our numerical predictions with experiments performed on poly(ethylacrylate) chains in model filled elastomers. We suggest that the change of elastic coupling between domains induced by confinement should contribute significantly to the polymer mobility shift observed on filled systems.

  5. Self-organizing human cardiac microchambers mediated by geometric confinement

    NASA Astrophysics Data System (ADS)

    Ma, Zhen; Wang, Jason; Loskill, Peter; Huebsch, Nathaniel; Koo, Sangmo; Svedlund, Felicia L.; Marks, Natalie C.; Hua, Ethan W.; Grigoropoulos, Costas P.; Conklin, Bruce R.; Healy, Kevin E.

    2015-07-01

    Tissue morphogenesis and organ formation are the consequences of biochemical and biophysical cues that lead to cellular spatial patterning in development. To model such events in vitro, we use PEG-patterned substrates to geometrically confine human pluripotent stem cell colonies and spatially present mechanical stress. Modulation of the WNT/β-catenin pathway promotes spatial patterning via geometric confinement of the cell condensation process during epithelial-mesenchymal transition, forcing cells at the perimeter to express an OCT4+ annulus, which is coincident with a region of higher cell density and E-cadherin expression. The biochemical and biophysical cues synergistically induce self-organizing lineage specification and creation of a beating human cardiac microchamber confined by the pattern geometry. These highly defined human cardiac microchambers can be used to study aspects of embryonic spatial patterning, early cardiac development and drug-induced developmental toxicity.

  6. Magnon waveguide with nanoscale confinement constructed from topological magnon insulators

    NASA Astrophysics Data System (ADS)

    Mook, Alexander; Henk, Jürgen; Mertig, Ingrid

    2015-05-01

    Topological magnon insulators host spatially confined edge magnons brought about by the Dzyaloshinskii-Moriya interaction. Bringing two topological magnon insulators into contact results in topologically protected unidirectional interface magnons. These interface modes decay rapidly toward the bulk regions of the sample. As a result, heat and spin currents associated with these magnons are as well unidirectional and strongly confined to a few-nanometer-wide strip along the interface. On top of this, these interface currents follow any geometry owing to the topological nature of the magnons. In this theoretical study, we propose and analyze two recipes for composing magnon waveguides with nanoscale confinement, one from topologically different phases, another from identical phases. We further identify material classes to construct these magnon waveguides and propose an experiment to verify their topological nature.

  7. Spatial confinement governs orientational order in patchy particles

    PubMed Central

    Iwashita, Yasutaka; Kimura, Yasuyuki

    2016-01-01

    Orientational order in condensed matter plays a key role in determining material properties such as ferromagnetism, viscoelasticity or birefringence. We studied purely orientational ordering in closely-packed one-patch colloidal particles confined between flat substrates, where the particles can only rotate and are ordered via the sticky interaction between the patches. For the first time, we experimentally realized a rich variety of mesoscopic patterns through orientational ordering of colloids by controlling patch size and confinement thickness. The combination of experiment and numerical simulation reveals the decisive role of confinement: An ordered state(s) is selected from the (meta)stable options in bulk when it is commensurate with the system geometry and boundary conditions; otherwise, frustration induces a unique order. Our study offers a new means of systematic control over mesoscopic structures via orientational ordering in patchy particles. The system would also possess unique functionalities through the rotational response of the particles to external stimuli. PMID:27264521

  8. Density Fluctuations of Hard-Sphere Fluids in Narrow Confinement

    NASA Astrophysics Data System (ADS)

    Nygârd, Kim; Sarman, Sten; Hyltegren, Kristin; Chodankar, Shirish; Perret, Edith; Buitenhuis, Johan; van der Veen, J. Friso; Kjellander, Roland

    2016-01-01

    Spatial confinement induces microscopic ordering of fluids, which in turn alters many of their dynamic and thermodynamic properties. However, the isothermal compressibility has hitherto been largely overlooked in the literature, despite its obvious connection to the underlying microscopic structure and density fluctuations in confined geometries. Here, we address this issue by probing density profiles and structure factors of hard-sphere fluids in various narrow slits, using x-ray scattering from colloid-filled nanofluidic containers and integral-equation-based statistical mechanics at the level of pair distributions for inhomogeneous fluids. Most importantly, we demonstrate that density fluctuations and isothermal compressibilities in confined fluids can be obtained experimentally from the long-wavelength limit of the structure factor, providing a formally exact and experimentally accessible connection between microscopic structure and macroscopic, thermodynamic properties. Our approach will thus, for example, allow direct experimental verification of theoretically predicted enhanced density fluctuations in liquids near solvophobic interfaces.

  9. Force correcting atom centred potentials for generalised gradient approximated density functional theory: Approaching hybrid functional accuracy for geometries and harmonic frequencies in small chlorofluorocarbons

    NASA Astrophysics Data System (ADS)

    Anatole von Lilienfeld, O.

    2013-08-01

    Generalised gradient approximated (GGA) density functional theory (DFT) typically overestimates polarisability and bond-lengths, and underestimates force constants of covalent bonds. To overcome this problem we show that one can use empirical force correcting atom centred potentials (FCACPs), parametrised for every nuclear species. Parameters are obtained through minimisation of a penalty functional that explicitly encodes hybrid DFT forces and static polarisabilities of reference molecules. For hydrogen, fluorine, chlorine and carbon the respective reference molecules consist of H2, F2, Cl2 and CH4. The transferability of this approach is assessed for harmonic frequencies in a small set of chlorofluorocarbon molecules. Numerical evidence, gathered for CF4, CCl4, CCl3F, CCl2F2, CClF3, ClF, HF, HCl, CFH3, CF2H2, CF3H, CHCl3, CH2Cl2 and CH3Cl indicates that the GGA+FCACP level of theory yields harmonic frequencies that are significantly more consistent with hybrid DFT values, as well as slightly reduced molecular polarisability.

  10. Inertial confinement fusion method producing line source radiation fluence

    DOEpatents

    Rose, Ronald P.

    1984-01-01

    An inertial confinement fusion method in which target pellets are imploded in sequence by laser light beams or other energy beams at an implosion site which is variable between pellet implosions along a line. The effect of the variability in position of the implosion site along a line is to distribute the radiation fluence in surrounding reactor components as a line source of radiation would do, thereby permitting the utilization of cylindrical geometry in the design of the reactor and internal components.

  11. Surface depletion induced quantum confinement in CdS nanobelts.

    PubMed

    Li, Dehui; Zhang, Jun; Xiong, Qihua

    2012-06-26

    We investigate the surface depletion induced quantum confinement in CdS nanobelts beyond the quantum confinement regime, where the thickness is much larger than the bulk exciton Bohr radius. From room temperature to 77 K, the emission energy of free exciton A scales linearly versus 1/L(2) when the thickness L is less than 100 nm, while a deviation occurs for those belts thicker than 100 nm due to the reabsorption effect. The 1/L(2) dependence can be explained by the surface depletion induced quantum confinement, which modifies the confinement potential leading to a quasi-square potential well smaller than the geometric thickness of nanobelts, giving rise to the confinement effect to exciton emission beyond the quantum confinement regime. The surface depletion is sensitive to carrier concentration and surface states. As the temperature decreases, the decrease of the electrostatic potential drop in the surface depletion region leads to a weaker confinement due to the decrease of carrier concentration. With a layer of polymethyl methacrylate (PMMA) passivation, PL spectra exhibit pronounced red shifts due to the decrease of the surface states at room temperature. No shift is found at 10 K both with or without PMMA passivation, suggesting a much weaker depletion field due to the freezing-out of donors.

  12. Statistical Mechanics of Confined Quantum Particles

    NASA Astrophysics Data System (ADS)

    Bannur, Vishnu M.; Udayanandan, K. M.

    We develop statistical mechanics and thermodynamics of Bose and Fermi systems in relativistic harmonic oscillator (RHO) confining potential, which is applicable in quark gluon plasma (QGP), astrophysics, Bose-Einstein condensation (BEC) etc. Detailed study of QGP system is carried out and compared with lattice results. Furthermore, as an application, our equation of state (EoS) of QGP is used to study compact stars like quark star.

  13. Dancing droplets: Contact angle, drag, and confinement

    NASA Astrophysics Data System (ADS)

    Benusiglio, Adrien; Cira, Nate; Prakash, Manu

    2015-11-01

    When deposited on a clean glass slide, a mixture of water and propylene glycol forms a droplet of given contact angle, when both pure liquids spread. (Cira, Benusiglio, Prakash: Nature, 2015). The droplet is stabilized by a gradient of surface tension due to evaporation that induces a Marangoni flow from the border to the apex of the droplets. The apparent contact angle of the droplets depends on both their composition and the external humidity as captured by simple models. These droplets present remarkable properties such as lack of a large pinning force. We discuss the drag on these droplets as a function of various parameters. We show theoretical and experimental results of how various confinement geometries change the vapor gradient and the dynamics of droplet attraction.

  14. Confined Selective Withdrawal

    NASA Astrophysics Data System (ADS)

    Evangelio, Alvaro; Campo-Cortes, Francisco; Gordillo, Jose Manuel

    2014-11-01

    It is well known that the controlled production of monodisperse simple and composite emulsions possesses uncountable applications in medicine, pharmacy, materials science and industry. Here we present both experiments and slender-body theory regarding the generation of simple emulsions using a configuration that we have called Confined Selective Withdrawal, since it is an improved configuration of the classical Selective Withdrawal. We consider two different situations, namely, the cases when the outer flow Reynolds number is high and low, respectively. Several geometrical configurations and a wide range of viscosity ratios are analyzed so that the physics behind the phenomenon can be fully understood. In addition, we present both experiments and theory regarding the generation of composite emulsions. This phenomenon is only feasible when the outer flow Reynolds number is low enough. In this case, we propose a more complex theory which requires the simultaneous resolution of two interfaces in order to predict the shape of the jet and the sizes of the drops formed. The excellent agreement between our slender-body approximation and the experimental evidence fully validates our theories.

  15. Inertial confinement fusion

    SciTech Connect

    Powers, L.; Condouris, R.; Kotowski, M.; Murphy, P.W.

    1992-01-01

    This issue of the ICF Quarterly contains seven articles that describe recent progress in Lawrence Livermore National Laboratory's ICF program. The Department of Energy recently initiated an effort to design a 1--2 MJ glass laser, the proposed National Ignition Facility (NIF). These articles span various aspects of a program which is aimed at moving forward toward such a facility by continuing to use the Nova laser to gain understanding of NIF-relevant target physics, by developing concepts for an NIF laser driver, and by envisioning a variety of applications for larger ICF facilities. This report discusses research on the following topics: Stimulated Rotational Raman Scattering in Nitrogen; A Maxwell Equation Solver in LASNEX for the Simulation of Moderately Intense Ultrashort Pulse Experiments; Measurements of Radial Heat-Wave Propagation in Laser-Produced Plasmas; Laser-Seeded Modulation Growth on Directly Driven Foils; Stimulated Raman Scattering in Large-Aperture, High-Fluence Frequency-Conversion Crystals; Fission Product Hazard Reduction Using Inertial Fusion Energy; Use of Inertial Confinement Fusion for Nuclear Weapons Effects Simulations.

  16. Positron confinement in embedded lithium nanoclusters

    NASA Astrophysics Data System (ADS)

    van Huis, M. A.; van Veen, A.; Schut, H.; Falub, C. V.; Eijt, S. W.; Mijnarends, P. E.; Kuriplach, J.

    2002-02-01

    Quantum confinement of positrons in nanoclusters offers the opportunity to obtain detailed information on the electronic structure of nanoclusters by application of positron annihilation spectroscopy techniques. In this work, positron confinement is investigated in lithium nanoclusters embedded in monocrystalline MgO. These nanoclusters were created by means of ion implantation and subsequent annealing. It was found from the results of Doppler broadening positron beam analysis that approximately 92% of the implanted positrons annihilate in lithium nanoclusters rather than in the embedding MgO, while the local fraction of lithium at the implantation depth is only 1.3 at. %. The results of two-dimensional angular correlation of annihilation radiation confirm the presence of crystalline bulk lithium. The confinement of positrons is ascribed to the difference in positron affinity between lithium and MgO. The nanocluster acts as a potential well for positrons, where the depth of the potential well is equal to the difference in the positron affinities of lithium and MgO. These affinities were calculated using the linear muffin-tin orbital atomic sphere approximation method. This yields a positronic potential step at the MgO||Li interface of 1.8 eV using the generalized gradient approximation and 2.8 eV using the insulator model.

  17. Flyby Geometry Optimization Tool

    NASA Technical Reports Server (NTRS)

    Karlgaard, Christopher D.

    2007-01-01

    The Flyby Geometry Optimization Tool is a computer program for computing trajectories and trajectory-altering impulsive maneuvers for spacecraft used in radio relay of scientific data to Earth from an exploratory airplane flying in the atmosphere of Mars.

  18. What Is Geometry?

    ERIC Educational Resources Information Center

    Chern, Shiing-Shen

    1990-01-01

    Discussed are the major historical developments of geometry. Euclid, Descartes, Klein's Erlanger Program, Gaus and Riemann, globalization, topology, Elie Cartan, and an application to molecular biology are included as topics. (KR)

  19. Gingerbread-House Geometry.

    ERIC Educational Resources Information Center

    Emenaker, Charles E.

    1999-01-01

    Describes a sixth-grade interdisciplinary geometry unit based on Charles Dickens's "A Christmas Carol". Focuses on finding area, volume, and perimeter, and working with estimation, decimals, and fractions in the context of making gingerbread houses. (ASK)

  20. Facilitating Understandings of Geometry.

    ERIC Educational Resources Information Center

    Pappas, Christine C.; Bush, Sara

    1989-01-01

    Illustrates some learning encounters for facilitating first graders' understanding of geometry. Describes some of children's approaches using Cuisenaire rods and teacher's intervening. Presents six problems involving various combinations of Cuisenaire rods and cubes. (YP)

  1. Proof in Transformation Geometry

    ERIC Educational Resources Information Center

    Bell, A. W.

    1971-01-01

    The first of three articles showing how inductively-obtained results in transformation geometry may be organized into a deductive system. This article discusses two approaches to enlargement (dilatation), one using coordinates and the other using synthetic methods. (MM)

  2. Geometry-induced modification of fluctuation spectrum in quasi-two-dimensional condensates

    NASA Astrophysics Data System (ADS)

    Roy, Arko; Angom, D.

    2016-08-01

    We report the structural transformation of the low-lying spectral modes, especially the Kohn mode, from radial to circular topology as harmonic confining potential is modified to a toroidal one, and this corresponds to a transition from simply to multiply connected geometry. For this we employ the Hartree-Fock-Bogoliubov theory to examine the evolution of low energy quasiparticles. We, then, use the Hartree-Fock-Bogoliubov theory with the Popov approximation to demonstrate the two striking features of quantum and thermal fluctuations. At T = 0, the non-condensate density due to interaction induced quantum fluctuations increases with the transformation from pancake to toroidal geometry. The other feature is, there is a marked change in the density profile of the non-condensate density at finite temperatures with the modification of trapping potential. In particular, the condensate and non-condensate density distributions have overlapping maxima in the toroidal condensate, which is in stark contrast to the case of pancake geometry. The genesis of this difference lies in the nature of the thermal fluctuations.

  3. Evaluation of Several Two-Step Scoring Functions Based on Linear Interaction Energy, Effective Ligand Size, and Empirical Pair Potentials for Prediction of Protein-Ligand Binding Geometry and Free Energy

    PubMed Central

    Rahaman, Obaidur; Estrada, Trilce P.; Doren, Douglas J.; Taufer, Michela; Brooks, Charles L.; Armen, Roger S.

    2011-01-01

    The performance of several two-step scoring approaches for molecular docking were assessed for their ability to predict binding geometries and free energies. Two new scoring functions designed for “step 2 discrimination” were proposed and compared to our CHARMM implementation of the linear interaction energy (LIE) approach using the Generalized-Born with Molecular Volume (GBMV) implicit solvation model. A scoring function S1 was proposed by considering only “interacting” ligand atoms as the “effective size” of the ligand, and extended to an empirical regression-based pair potential S2. The S1 and S2 scoring schemes were trained and five-fold cross validated on a diverse set of 259 protein-ligand complexes from the Ligand Protein Database (LPDB). The regression-based parameters for S1 and S2 also demonstrated reasonable transferability in the CSARdock 2010 benchmark using a new dataset (NRC HiQ) of diverse protein-ligand complexes. The ability of the scoring functions to accurately predict ligand geometry was evaluated by calculating the discriminative power (DP) of the scoring functions to identify native poses. The parameters for the LIE scoring function with the optimal discriminative power (DP) for geometry (step 1 discrimination) were found to be very similar to the best-fit parameters for binding free energy over a large number of protein-ligand complexes (step 2 discrimination). Reasonable performance of the scoring functions in enrichment of active compounds in four different protein target classes established that the parameters for S1 and S2 provided reasonable accuracy and transferability. Additional analysis was performed to definitively separate scoring function performance from molecular weight effects. This analysis included the prediction of ligand binding efficiencies for a subset of the CSARdock NRC HiQ dataset where the number of ligand heavy atoms ranged from 17 to 35. This range of ligand heavy atoms is where improved accuracy of

  4. Evaluation of several two-step scoring functions based on linear interaction energy, effective ligand size, and empirical pair potentials for prediction of protein-ligand binding geometry and free energy.

    PubMed

    Rahaman, Obaidur; Estrada, Trilce P; Doren, Douglas J; Taufer, Michela; Brooks, Charles L; Armen, Roger S

    2011-09-26

    The performances of several two-step scoring approaches for molecular docking were assessed for their ability to predict binding geometries and free energies. Two new scoring functions designed for "step 2 discrimination" were proposed and compared to our CHARMM implementation of the linear interaction energy (LIE) approach using the Generalized-Born with Molecular Volume (GBMV) implicit solvation model. A scoring function S1 was proposed by considering only "interacting" ligand atoms as the "effective size" of the ligand and extended to an empirical regression-based pair potential S2. The S1 and S2 scoring schemes were trained and 5-fold cross-validated on a diverse set of 259 protein-ligand complexes from the Ligand Protein Database (LPDB). The regression-based parameters for S1 and S2 also demonstrated reasonable transferability in the CSARdock 2010 benchmark using a new data set (NRC HiQ) of diverse protein-ligand complexes. The ability of the scoring functions to accurately predict ligand geometry was evaluated by calculating the discriminative power (DP) of the scoring functions to identify native poses. The parameters for the LIE scoring function with the optimal discriminative power (DP) for geometry (step 1 discrimination) were found to be very similar to the best-fit parameters for binding free energy over a large number of protein-ligand complexes (step 2 discrimination). Reasonable performance of the scoring functions in enrichment of active compounds in four different protein target classes established that the parameters for S1 and S2 provided reasonable accuracy and transferability. Additional analysis was performed to definitively separate scoring function performance from molecular weight effects. This analysis included the prediction of ligand binding efficiencies for a subset of the CSARdock NRC HiQ data set where the number of ligand heavy atoms ranged from 17 to 35. This range of ligand heavy atoms is where improved accuracy of predicted ligand

  5. Hyperbolic geometry of cosmological attractors

    NASA Astrophysics Data System (ADS)

    Carrasco, John Joseph M.; Kallosh, Renata; Linde, Andrei; Roest, Diederik

    2015-08-01

    Cosmological α attractors give a natural explanation for the spectral index ns of inflation as measured by Planck while predicting a range for the tensor-to-scalar ratio r , consistent with all observations, to be measured more precisely in future B-mode experiments. We highlight the crucial role of the hyperbolic geometry of the Poincaré disk or half plane in the supergravity construction. These geometries are isometric under Möbius transformations, which include the shift symmetry of the inflaton field. We introduce a new Kähler potential frame that explicitly preserves this symmetry, enabling the inflaton to be light. Moreover, we include higher-order curvature deformations, which can stabilize a direction orthogonal to the inflationary trajectory. We illustrate this new framework by stabilizing the single superfield α attractors.

  6. Correlation Effects in the Photoionization of Confined Calcium and Zinc

    NASA Astrophysics Data System (ADS)

    Varma, R. Hari; Manson, S. T.

    2005-05-01

    Studies of atoms confined in an endohedral environment have aroused significant recent interest [1]. In this work, the photoionization @Ca and @Zn have been studied using the Relativistic-Random-Phase Approximation, modified to include the confinement potential. Photoionization of the 4s and 3p subshells of free and confined atomic calcium, along with the 4s, 3d, 3p and 3s subshells of free and confined atomic zinc, have been studied. The photoionization parameters of confined atoms differ significantly from those of their ``free'' counterparts. The dipole cross sections and angular distribution asymmetry parameters exhibit oscillations with energy arising from the back scattering of the escaping electron by the confining potential, i.e., ``confinement resonances'' [2]. These oscillations persist when nondipole matrix elements are also included as is reflected in the nondipole cross section and angular distribution asymmetry parameters [3]; the relative strengths of the oscillations due to back-scattering in the E1 and E2 photoionization parameters have qualitatively different profiles as a function of photon energy. [1] V. K. Dolmatov, A. S. Baltenkov, J.-P. Connerade and S. T. Manson, Radiation Phys. Chem. 70, 417 (2004). [2] M. Ya. Amusia, A. S. Baltenkov, V. K. Dolmatov, S. T. Manson and A. Z. Msezane, Phys. Rev. A 70, 023201 (2004). [3] P.C. Deshmukh, Tanima Banerjee, K. P. Sunanda and R. Hari Varma, Radiation Phys. and Chem (submitted).

  7. Common Geometry Module

    SciTech Connect

    Tautges, Timothy J.

    2005-01-01

    The Common Geometry Module (CGM) is a code library which provides geometry functionality used for mesh generation and other applications. This functionality includes that commonly found in solid modeling engines, like geometry creation, query and modification; CGM also includes capabilities not commonly found in solid modeling engines, like geometry decomposition tools and support for shared material interfaces. CGM is built upon the ACIS solid modeling engine, but also includes geometry capability developed beside and on top of ACIS. CGM can be used as-is to provide geometry functionality for codes needing this capability. However, CGM can also be extended using derived classes in C++, allowing the geometric model to serve as the basis for other applications, for example mesh generation. CGM is supported on Sun Solaris, SGI, HP, IBM, DEC, Linux and Windows NT platforms. CGM also indudes support for loading ACIS models on parallel computers, using MPI-based communication. Future plans for CGM are to port it to different solid modeling engines, including Pro/Engineer or SolidWorks. CGM is being released into the public domain under an LGPL license; the ACIS-based engine is available to ACIS licensees on request.

  8. Software Geometry in Simulations

    NASA Astrophysics Data System (ADS)

    Alion, Tyler; Viren, Brett; Junk, Tom

    2015-04-01

    The Long Baseline Neutrino Experiment (LBNE) involves many detectors. The experiment's near detector (ND) facility, may ultimately involve several detectors. The far detector (FD) will be significantly larger than any other Liquid Argon (LAr) detector yet constructed; many prototype detectors are being constructed and studied to motivate a plethora of proposed FD designs. Whether it be a constructed prototype or a proposed ND/FD design, every design must be simulated and analyzed. This presents a considerable challenge to LBNE software experts; each detector geometry must be described to the simulation software in an efficient way which allows for multiple authors to easily collaborate. Furthermore, different geometry versions must be tracked throughout their use. We present a framework called General Geometry Description (GGD), written and developed by LBNE software collaborators for managing software to generate geometries. Though GGD is flexible enough to be used by any experiment working with detectors, we present it's first use in generating Geometry Description Markup Language (GDML) files to interface with LArSoft, a framework of detector simulations, event reconstruction, and data analyses written for all LAr technology users at Fermilab. Brett is the other of the framework discussed here, the General Geometry Description (GGD).

  9. Psychopathological effects of solitary confinement.

    PubMed

    Grassian, S

    1983-11-01

    Psychopathological reactions to solitary confinement were extensively described by nineteenth-century German clinicians. In the United States there have been several legal challenges to the use of solitary confinement, based on allegations that it may have serious psychiatric consequences. The recent medical literature on this subject has been scarce. The author describes psychiatric symptoms that appeared in 14 inmates exposed to periods of increased social isolation and sensory restriction in solitary confinement and asserts that these symptoms form a major, clinically distinguishable psychiatric syndrome.

  10. Spatial confinement of muonium atoms

    NASA Astrophysics Data System (ADS)

    Khaw, K. S.; Antognini, A.; Prokscha, T.; Kirch, K.; Liszkay, L.; Salman, Z.; Crivelli, P.

    2016-08-01

    We report the achievement of spatial confinement of muonium atoms (the bound state of a positive muon and an electron). Muonium emitted into a vacuum from mesoporous silica reflects between two SiO2 confining surfaces separated by 1 mm. From the data, one can extract that the reflection probability on the confining surfaces kept at 100 K is about 90% and the reflection process is well described by a cosine law. This technique enables new experiments with this exotic atomic system and is a very important step towards a measurement of the 1 S -2 S transition frequency using continuous-wave laser spectroscopy.

  11. The swimming speed of a confined rotating helix in creeping flow

    NASA Astrophysics Data System (ADS)

    Angeles, Veronica; Zenit, Roberto

    2016-11-01

    Recent theoretical and numerical studies have shown that the swimming speed of a rotating helix confined in a tube or between walls is higher that the unconfined case, for the same helix properties (helix geometry and rotation speed). We conduct experiments using a magnetic self-propelled force-free robot placed in between two walls or inside a cylinder. We vary the degree of confinement and measure the translation speed for different helix geometries and rotation speeds. We do find an increase of the swimming speeds, which is in good agreement with the predictions of a wall-corrected resistive-force theory. However, since the torque also increases as a result of confinement, the experiments are restricted by the available magnetic torque. Therefore, the increase in swimming speed is only observed for low confinement levels.

  12. Initial results on positron confinement in a magnetospheric configuration

    NASA Astrophysics Data System (ADS)

    Saitoh, Haruhiko; Yoshida, Zensho; Yano, Yoshihisa; Morikawa, Junji

    2011-10-01

    Creation of positron-electron plasma in a laboratory is an interesting and challenging subject, which may open many scientific applications. Although single-component plasma is stably confined in linear traps, for example Penning-Malmberg trap, it is not straightforward to simultaneously confine electrons and positrons as plasma. Toroidal geometries have advantages for solving this problem. For this purpose, studies on toroidal non-neutral plasma have been conducted in the levitated magnetospheric configuration, RT-1. Stable confinement and self-organization of toroidal non-neutral plasma was realized in RT-1; rigid-rotating pure electron plasma is confined for more than 300s [Z. Yoshida et al., PRL 104, 235004 (2010)]. As the initial step toward the formation of magnetospheric antimatter plasmas, we installed a 1MBq Na-22 radiation source in RT-1. Annihilation gamma-rays were observed by a NaI(TI) scintillator detector, for the estimation of basic injection and confinement properties of positrons in the magnetospheric configuration. Numerical analysis of positron orbits in RT-1 and the initial experimental results will be presented. Work funded by MEXT of Japan (23224014, 23654201).

  13. Cooperative Length Scale and Fragility of Polystyrene under Confinement

    NASA Astrophysics Data System (ADS)

    Zhang, Chuan; Guo, Yunlong; Priestley, Rodney

    2012-02-01

    While thin films are an attractive model system to investigate the impact of confinement on glassy behavior, extending studies beyond thin films to geometries of higher dimensionalities is vital from both scientific and technological viewpoints. In this talk, we present the impact of confinement on the characteristic length at the glass transition as well as the fragility for confined polystyrene (PS) nanoparticles under isochoric conditions. We measure the glass transition temperature (Tg), fictive temperature (Tf) and isochoric heat capacity of silica-capped PS nanoparticles as a function of diameter via differential scanning calorimetry. From the measurement of Tf, we obtain the isochoric fragility, and via the fluctuation formula, the characteristic length at the glass transition. We illustrate that confinement under isochoric conditions for PS nanoparticles leads to a significant increase in the isochoric fragility while the characteristic length is reduced with size. At the minimum the results demonstrate a relationship between fragility and the characteristics length of isochorically-confined polymer that is not intuitive from the Adam-Gibbs theory.

  14. Experimental study on confined two-phase jets

    SciTech Connect

    Levy, Y.; Albagli, D. )

    1991-09-01

    The basic mixing phenomena in confined, coaxial, particle-laden turbulent flows are studied within the scope of ram combustor research activities. Cold-flow experiments in a relatively simple configuration of confined, coaxial two-phase jets provided both qualitative and quantitative insight on the multiphase mixing process. Pressure, tracer gas concentration, and two-phase velocity measurements revealed that unacceptably long ram combustors are needed for complete confined jet mixing. Comparison of the experimental results with a previous numerical simulation displayed a very good agreement, indicating the potential of the experimental facility for validation of computational parametric studies. 38 refs.

  15. Numerical Studies of Properties of Confined Helium

    NASA Technical Reports Server (NTRS)

    Manousakis, Efstratios

    2003-01-01

    We carry out state of the art simulations of properties of confined liquid helium near the superfluid transition to a degree of accuracy which allows to make predictions for the outcome of fundamental physics experiments in microgravity. First we report our results for the finite-size scaling behavior of heat capacity of superfluids for cubic and parallel-plate geometry. This allows us to study the crossover from zero and two dimensions to three dimensions. Our calculated scaling functions are in good agreement with recently measured specific heat scaling functions for the above mentioned geometries. We also present our results of a quantum simulation of submonolayer of molecular hydrogen deposited on an ideal graphite substrate using path-integral quantum Monte Carlo simulation. We find that the monolayer phase diagram is rich and very similar to that of helium monolayer. We are able to uncover the main features of the complex monolayer phase diagram, such as the commensurate solid phases and the commensurate to incommensurate transition, in agreement with the experiments and to find some features which are missing from the experimental analysis.

  16. Coronal electron confinement by double layers

    SciTech Connect

    Li, T. C.; Drake, J. F.; Swisdak, M.

    2013-12-01

    In observations of flare-heated electrons in the solar corona, a longstanding problem is the unexplained prolonged lifetime of the electrons compared to their transit time across the source. This suggests confinement. Recent particle-in-cell (PIC) simulations, which explored the transport of pre-accelerated hot electrons through ambient cold plasma, showed that the formation of a highly localized electrostatic potential drop, in the form of a double layer (DL), significantly inhibited the transport of hot electrons. The effectiveness of confinement by a DL is linked to the strength of the DL as defined by its potential drop. In this work, we investigate the scaling of the DL strength with the hot electron temperature by PIC simulations and find a linear scaling. We demonstrate that the strength is limited by the formation of parallel shocks. Based on this, we analytically determine the maximum DL strength, and also find a linear scaling with the hot electron temperature. The DL strength obtained from the analytic calculation is comparable to that from the simulations. At the maximum strength, the DL is capable of confining a significant fraction of hot electrons in the source.

  17. Confinement from gluodynamics in curved space-time

    SciTech Connect

    Gaete, Patricio; Spallucci, Euro

    2008-01-15

    We determine the static potential for a heavy quark-antiquark pair from gluodynamics in curved space-time. Our calculation is done within the framework of the gauge-invariant, path-dependent, variables formalism. The potential energy is the sum of a Yukawa and a linear potential, leading to the confinement of static charges.

  18. Quantum confinement in self-assembled two-dimensional nanoporous honeycomb networks at close-packed metal surfaces

    SciTech Connect

    Kepčija, N.; Huang, T.-J.; Klappenberger, F. Barth, J. V.

    2015-03-14

    Quantum confinement of a two-dimensional electron gas by supramolecular nanoporous networks is investigated using the boundary elements method based on Green’s functions for finite geometries and electron plane wave expansion for periodic systems. The “particle in a box” picture was analyzed for cases with selected symmetries that model previously reported architectures constructed from organic and metal-organic scattering centers confining surface state electrons of Ag(111) and Cu(111). First, by analyzing a series of cases with systematically defined parameters (scattering geometry, potentials, and effective broadening), we demonstrate how the scattering processes affect the properties of the confined electrons. For the features of the local density of states reported by scanning tunneling spectroscopy (STS), we disentangle the contributions of lifetime broadening and splitting of quantum well states due to coupling of neighboring quantum dots. For each system, we analyze the local electron density distribution and relate it to the corresponding band structure as calculated within the plane-wave expansion framework. Then, we address two experimental investigations, where in one case only STS data and in the other case mainly angle-resolved photoemission spectroscopy (ARPES) data were reported. In both cases, the experimental findings can be successfully simulated. Furthermore, the missing information can be complemented because our approach allows to correlate the information obtained by STS with that of ARPES. The combined analysis of several observations suggests that the scattering potentials created by the network originate primarily from the adsorbate-induced changes of the local surface dipole barrier.

  19. Assessing confinement in coastal lagoons.

    PubMed

    Canu, Donata Melaku; Solidoro, Cosimo; Umgiesser, Georg; Cucco, Andrea; Ferrarin, Christian

    2012-11-01

    Measures of transport scale in aquatic systems can contribute to the formulation of definitions of indicators of the system's ecological properties. This paper addresses confinement, a specific transport scale proposed by biological scientists as a parameter that can capture and synthesize the principal properties that determine the spatial structure of biological communities in transitional environments. Currently, there is no direct experimental measure of confinement. In this study, a methodology based on the accumulation rate within a lagoon of a passive tracer of marine origin is proposed, the influences of different factors in the calculation of confinement are analyzed, and general recommendations are derived. In particular, we analyze the spatial and the temporal variability of confinement and its sensitivity to the seasonal variability of climatic forcing, the inputs from rivers and the parameterization of the tidal exchanges. The Lagoon of Venice is used as a case study.

  20. Alternative approaches to plasma confinement

    NASA Technical Reports Server (NTRS)

    Roth, J. R.

    1978-01-01

    The paper discusses 20 plasma confinement schemes each representing an alternative to the tokamak fusion reactor. Attention is given to: (1) tokamak-like devices (TORMAC, Topolotron, and the Extrap concept), (2) stellarator-like devices (Torsatron and twisted-coil stellarators), (3) mirror machines (Astron and reversed-field devices, the 2XII B experiment, laser-heated solenoids, the LITE experiment, the Kaktus-Surmac concept), (4) bumpy tori (hot electron bumpy torus, toroidal minimum-B configurations), (5) electrostatically assisted confinement (electrostatically stuffed cusps and mirrors, electrostatically assisted toroidal confinement), (6) the Migma concept, and (7) wall-confined plasmas. The plasma parameters of the devices are presented and the advantages and disadvantages of each are listed.

  1. Tandem mirror plasma confinement apparatus

    DOEpatents

    Fowler, T. Kenneth

    1978-11-14

    Apparatus and method for confining a plasma in a center mirror cell by use of two end mirror cells as positively charged end stoppers to minimize leakage of positive particles from the ends of the center mirror cell.

  2. Central cell confinement in MFTF-B

    SciTech Connect

    Jong, R.A.

    1981-05-05

    The point code TANDEM has been used to survey the range of plasma parameters which can be attained in MFTF-B. The code solves for the electron and ion densities and temperatures in the central cell, yin-yang, barrier, and A-cell regions as well as the plasma potential in each region. In these studies, the A-cell sloshing ion beams were fixed while the neutral beams in the yin-yang and central cell, the gas feed in the central cell, and the applied ECRH power ..beta.., central cell ion density and temperature, and the confining potential are discussed.

  3. Don't Fence Me In: Free Meanders in a Confined River Valley

    NASA Astrophysics Data System (ADS)

    Eke, E. C.; Wilcock, P. R.

    2015-12-01

    The interaction between meandering river channels and inerodible valley walls provides a useful test of our ability to understand meander dynamics. In some cases, river meanders confined between valley walls display distinctive angular bends in a dynamic equilibrium such that their size and shape persist as the meander migrates. In other cases, meander geometry is more varied and changes as the meander migrates. The ratio of channel to valley width has been identified as a useful parameter for defining confined meanders, but is not sufficient to distinguish cases in which sharp angular bends are able to migrate with little change in geometry. Here, we examine the effect of water and sediment supply on the geometry of confined rivers in order to identify conditions under which meander geometry reaches a persistent dynamic equilibrium. Because channel width and meander geometry are closely related, we use a numerical meander model that allows for independent migration of both banks, thereby allowing channel width to vary in space and time. We hypothesize that confined meanders with persistent angular bends have smaller transport rates of bed material and that their migration is driven by erosion of the cutbank (bank-pull migration). When bed material supply is sufficiently large that point bar deposition drives meander migration (bar-push migration), confined meander bends have a larger radius of curvature and a geometry that varies as the meander migrates. We test this hypothesis using historical patterns of confined meander migration for rivers with different rates of sediment supply and bed material transport. Interpretation of the meander migration pattern is provided by the free-width meander migration model.

  4. Solvent cavitation under solvophobic confinement

    NASA Astrophysics Data System (ADS)

    Ashbaugh, Henry S.

    2013-08-01

    The stability of liquids under solvophobic confinement can tip in favor of the vapor phase, nucleating a liquid-to-vapor phase transition that induces attractive forces between confining surfaces. In the case of water adjacent to hydrophobic surfaces, experimental and theoretical evidence support confinement-mediated evaporation stabilization of biomolecular and colloidal assemblies. The macroscopic thermodynamic theory of cavitation under confinement establishes the connection between the size of the confining surfaces, interfacial free energies, and bulk solvent pressure with the critical evaporation separation and interfacial forces. While molecular simulations have confirmed the broad theoretical trends, a quantitative comparison based on independent measurements of the interfacial free energies and liquid-vapor coexistence properties has, to the best of our knowledge, not yet been performed. To overcome the challenges of simulating a large number of systems to validate scaling predictions for a three-dimensional fluid, we simulate both the forces and liquid-vapor coexistence properties of a two-dimensional Lennard-Jones fluid confined between solvophobic plates over a range of plate sizes and reservoir pressures. Our simulations quantitatively agree with theoretical predictions for solvent-mediated forces and critical evaporation separations once the length dependence of the solvation free energy of an individual confining plate is taken into account. The effective solid-liquid line tension length dependence results from molecular scale correlations for solvating microscopic plates and asymptotically decays to the macroscopic value for plates longer than 150 solvent diameters. The success of the macroscopic thermodynamic theory at describing two-dimensional liquids suggests application to surfactant monolayers to experimentally confirm confinement-mediated cavitation.

  5. Integrable Background Geometries

    NASA Astrophysics Data System (ADS)

    Calderbank, David M. J.

    2014-03-01

    This work has its origins in an attempt to describe systematically the integrable geometries and gauge theories in dimensions one to four related to twistor theory. In each such dimension, there is a nondegenerate integrable geometric structure, governed by a nonlinear integrable differential equation, and each solution of this equation determines a background geometry on which, for any Lie group G, an integrable gauge theory is defined. In four dimensions, the geometry is selfdual conformal geometry and the gauge theory is selfdual Yang-Mills theory, while the lower-dimensional structures are nondegenerate (i.e., non-null) reductions of this. Any solution of the gauge theory on a k-dimensional geometry, such that the gauge group H acts transitively on an ℓ-manifold, determines a (k+ℓ)-dimensional geometry (k+ℓ≤4) fibering over the k-dimensional geometry with H as a structure group. In the case of an ℓ-dimensional group H acting on itself by the regular representation, all (k+ℓ)-dimensional geometries with symmetry group H are locally obtained in this way. This framework unifies and extends known results about dimensional reductions of selfdual conformal geometry and the selfdual Yang-Mills equation, and provides a rich supply of constructive methods. In one dimension, generalized Nahm equations provide a uniform description of four pole isomonodromic deformation problems, and may be related to the {SU}(∞) Toda and dKP equations via a hodograph transformation. In two dimensions, the {Diff}(S^1) Hitchin equation is shown to be equivalent to the hyperCR Einstein-Weyl equation, while the {SDiff}(Σ^2) Hitchin equation leads to a Euclidean analogue of Plebanski's heavenly equations. In three and four dimensions, the constructions of this paper help to organize the huge range of examples of Einstein-Weyl and selfdual spaces in the literature, as well as providing some new ! ones. The nondegenerate reductions have a long ancestry. More ! recently

  6. Glow discharges with electrostatic confinement of fast electrons

    NASA Astrophysics Data System (ADS)

    Kolobov, V. I.; Metel, A. S.

    2015-06-01

    This review presents a unified treatment of glow discharges with electrostatic confinement of fast electrons. These discharges include hollow cathode discharges, wire and cage discharges, reflect discharges with brush and multirod cathodes, and discharges in crossed electric and magnetic fields. Fast electrons bouncing inside electrostatic traps provide efficient ionization of gas at very low gas pressures. The electrostatic trap effect (ETE) was first observed by Paschen in hollow cathode discharges almost a century ago. The key parameters that define fundamental characteristics of ETE discharges are the ionization length λN, the penetration range, Λ, and the diffusion length λ of the fast electrons, and two universal geometric parameters of the traps: effective width a and length L. Peculiarities of electron kinetics and ion collection mechanism explain experimental observations for different trap geometries. The ETE is observed only at Λ > a, when the penetration range of the γ-electrons emitted by the cathode exceeds the trap width. In the optimal pressure range, when λN > a, and Λ < L, the cathode potential fall Uc is independent of gas pressure p. With increasing current, Uc tends to its upper limit W/eβγ, where β is the percentage of ions arriving at the cathode and W is the gas ionization cost. In the low-pressure range, Λ > L, Uc rises from hundreds to thousands of volts. The sign of the anode potential fall, Ua, depends on the anode surface Sa and its position. When Sa is large compared to a critical value S*, Ua is negative and small. At Sa < S*, the value of Ua becomes positive and rises up to 0.5-1 kV with decreasing p ultimately causing discharge extinction. Scaling laws indicate common physics between vacuum discharges and atmospheric pressure micro-discharges. We discuss peculiarities of electron kinetics under different conditions using semi-analytical models. Recent experimental results and applications of glow

  7. Origins of cellular geometry

    PubMed Central

    2011-01-01

    Cells are highly complex and orderly machines, with defined shapes and a startling variety of internal organizations. Complex geometry is a feature of both free-living unicellular organisms and cells inside multicellular animals. Where does the geometry of a cell come from? Many of the same questions that arise in developmental biology can also be asked of cells, but in most cases we do not know the answers. How much of cellular organization is dictated by global cell polarity cues as opposed to local interactions between cellular components? Does cellular structure persist across cell generations? What is the relationship between cell geometry and tissue organization? What ensures that intracellular structures are scaled to the overall size of the cell? Cell biology is only now beginning to come to grips with these questions. PMID:21880160

  8. Geometry and Cloaking Devices

    NASA Astrophysics Data System (ADS)

    Ochiai, T.; Nacher, J. C.

    2011-09-01

    Recently, the application of geometry and conformal mappings to artificial materials (metamaterials) has attracted the attention in various research communities. These materials, characterized by a unique man-made structure, have unusual optical properties, which materials found in nature do not exhibit. By applying the geometry and conformal mappings theory to metamaterial science, it may be possible to realize so-called "Harry Potter cloaking device". Although such a device is still in the science fiction realm, several works have shown that by using such metamaterials it may be possible to control the direction of the electromagnetic field at will. We could then make an object hidden inside of a cloaking device. Here, we will explain how to design invisibility device using differential geometry and conformal mappings.

  9. A simple formula to predict the influence of the near-field in the optical control of confined electron systems

    NASA Astrophysics Data System (ADS)

    Takeuchi, Takashi; Ohnuki, Shinichiro; Sako, Tokuei

    2017-02-01

    A simple formula for predicting the ratio between the field strengths of the incident laser pulse and of the near-field created in the vicinity of the target electron system has been proposed, in the context of optically controlling confined electron systems. The formula is easy to use and does not involve elaborate computation, thus enabling one to judge whether to use the time-consuming Maxwell–Schrödinger hybrid simulation or to stay with the conventional time-dependent Schrödinger equation approach that takes no near-field effect into account. As a demonstration we have examined in detail the system of an electron confined in a quasi-one-dimensional nanoscale potential well. The highly accurate Maxwell–Schrödinger hybrid simulation has been employed to demonstrate the usefulness of the proposed formula in predicting the significance of the near-field effect. The near-field effect has shown to depend sensitively on the characteristics of the laser pulse and of the geometry of the confined electron system, which can be predicted well by the proposed formula.

  10. Students Discovering Spherical Geometry Using Dynamic Geometry Software

    ERIC Educational Resources Information Center

    Guven, Bulent; Karatas, Ilhan

    2009-01-01

    Dynamic geometry software (DGS) such as Cabri and Geometers' Sketchpad has been regularly used worldwide for teaching and learning Euclidean geometry for a long time. The DGS with its inductive nature allows students to learn Euclidean geometry via explorations. However, with respect to non-Euclidean geometries, do we need to introduce them to…

  11. The Dynamics of a Polymer Confined in Anodic Aluminum Oxide Nanopore

    NASA Astrophysics Data System (ADS)

    Xue, Gi; Sa, Ye

    2015-03-01

    The dynamics of poly (n-butyl methacrylate) confined in porous templates are investigated using DSC and Fluorescence nonradiative energy transfer. Two glass transition temperatures are obtained at a slow cooling rate of which one bulk-like phase reflects core layer while the other at much higher temperature indicates interfacial layer in the confined polymer glass. Because of cylindrical geometry, the glass transition energy barrier of interfacial layer is elevated, and the thereof temperature threshold to form one or two glass transitions is determined through adjusting infiltrating temperatures. In addition, the glass transition behavior is speculated to be meditated by the counterbalance of the size and interfacial effects in the confined space.

  12. Ambipolar potential formation in TMX

    SciTech Connect

    Correll, D.L.; Allen, S.L.; Casper, T.A.

    1981-05-05

    TMX experimental data on ambipolar potential control and on the accompanying electrostatic confinement are reported. New results on the radial dependence of the central-cell confining potential are given. Radial and axial particle losses as well as scaling of the central-cell axial confinement are discussed.

  13. Density Shock Waves in Confined Microswimmers

    NASA Astrophysics Data System (ADS)

    Tsang, Alan Cheng Hou; Kanso, Eva

    2016-01-01

    Motile and driven particles confined in microfluidic channels exhibit interesting emergent behavior, from propagating density bands to density shock waves. A deeper understanding of the physical mechanisms responsible for these emergent structures is relevant to a number of physical and biomedical applications. Here, we study the formation of density shock waves in the context of an idealized model of microswimmers confined in a narrow channel and subject to a uniform external flow. Interestingly, these density shock waves exhibit a transition from "subsonic" with compression at the back to "supersonic" with compression at the front of the population as the intensity of the external flow increases. This behavior is the result of a nontrivial interplay between hydrodynamic interactions and geometric confinement, and it is confirmed by a novel quasilinear wave model that properly captures the dependence of the shock formation on the external flow. These findings can be used to guide the development of novel mechanisms for controlling the emergent density distribution and the average population speed, with potentially profound implications on various processes in industry and biotechnology, such as the transport and sorting of cells in flow channels.

  14. Gaspé Belt subsurface geometry in the northern Québec Appalachians as revealed by an integrated geophysical and geological study: 2 — Seismic interpretation and potential field modelling results

    NASA Astrophysics Data System (ADS)

    Pinet, Nicolas

    2013-03-01

    Geological information, seismic reflection profiles and potential field data are used to study the geometry of the Middle Paleozoic Gaspé Belt (eastern Canada) that has been interpreted in various ways in the past. On the western edge of the Gaspé Belt, in the Matapédia area, growth strata are imaged on seismic profiles and testify of normal (or transtensional) motion during the period spanning the Silurian (and possibly Late Ordovician) to earliest Devonian along several faults, including the Shickshock-Sud Fault. In this area, Acadian deformation during the Middle to Late Devonian is associated with relatively modest shortening (less than 20%) accommodated by broad open folds, steeply-dipping neo-formed faults and inversion of previously formed faults. Neo-formed faults cut the entire Middle Paleozoic succession and offset the Ordovician Taconian unconformity suggesting that no sedimentary interval acted as an efficient décollement level. Toward the SE, the Sainte-Florence Fault divides rock assemblages with different paleogeographic settings and structural styles. Increase in tectonic complexity and amount of shortening to the south of the fault is interpreted as resulting of a vise effect between two basement blocks.

  15. Interplay of explosive thermal reaction dynamics and structural confinement

    NASA Astrophysics Data System (ADS)

    Perry, W. Lee; Zucker, Jonathan; Dickson, Peter M.; Parker, Gary R.; Asay, Blaine W.

    2007-04-01

    Explosives play a significant role in human affairs; however, their behavior in circumstances other than intentional detonation is poorly understood. Accidents may have catastrophic consequences, especially if additional hazardous materials are involved. Abnormal ignition stimuli, such as impact, spark, friction, and heat may lead to a very violent outcome, potentially including detonation. An important factor influencing the behavior subsequent to abnormal ignition is the strength and inertia of the vessel confining the explosive, i.e., the near-field structural/mechanical environment, also known as confinement (inertial or mechanical). However, a comprehensive and quantified understanding of how confinement affects reaction violence does not yet exist. In the research discussed here, we have investigated a wide range of confinement conditions and related the explosive response to the fundamentals of the combustion process in the explosive. In our experiments, a charge of an octahydrotetranitrotetrazine-based plastic bonded explosive (PBX 9501) was loaded into a gun assembly having variable confinement conditions and subjected to a heating profile. The exploding charge breached the confinement and accelerated a projectile down the gun barrel. High bandwidth pressure and volume measurements were made and a first-law analysis was used to obtain enthalpy and power from the raw data. These results were then used to quantify reaction violence. Enthalpy change and power ranged from 0-1.8 kJ and 0-12 MW for 300 mg charges, respectively. Below a confinement strength of 20 MPa, violence was found to decline precipitously with decreasing confinement, while the violence for the heaviest confinement experiments was found to be relatively constant. Both pressure and pressurization rate were found to have critical values to induce and sustain violent reaction.

  16. Origami, Geometry and Art

    ERIC Educational Resources Information Center

    Wares, Arsalan; Elstak, Iwan

    2017-01-01

    The purpose of this paper is to describe the mathematics that emanates from the construction of an origami box. We first construct a simple origami box from a rectangular sheet and then discuss some of the mathematical questions that arise in the context of geometry and algebra. The activity can be used as a context for illustrating how algebra…

  17. Emergent Hyperbolic Network Geometry.

    PubMed

    Bianconi, Ginestra; Rahmede, Christoph

    2017-02-07

    A large variety of interacting complex systems are characterized by interactions occurring between more than two nodes. These systems are described by simplicial complexes. Simplicial complexes are formed by simplices (nodes, links, triangles, tetrahedra etc.) that have a natural geometric interpretation. As such simplicial complexes are widely used in quantum gravity approaches that involve a discretization of spacetime. Here, by extending our knowledge of growing complex networks to growing simplicial complexes we investigate the nature of the emergent geometry of complex networks and explore whether this geometry is hyperbolic. Specifically we show that an hyperbolic network geometry emerges spontaneously from models of growing simplicial complexes that are purely combinatorial. The statistical and geometrical properties of the growing simplicial complexes strongly depend on their dimensionality and display the major universal properties of real complex networks (scale-free degree distribution, small-world and communities) at the same time. Interestingly, when the network dynamics includes an heterogeneous fitness of the faces, the growing simplicial complex can undergo phase transitions that are reflected by relevant changes in the network geometry.

  18. Sliding vane geometry turbines

    DOEpatents

    Sun, Harold Huimin; Zhang, Jizhong; Hu, Liangjun; Hanna, Dave R

    2014-12-30

    Various systems and methods are described for a variable geometry turbine. In one example, a turbine nozzle comprises a central axis and a nozzle vane. The nozzle vane includes a stationary vane and a sliding vane. The sliding vane is positioned to slide in a direction substantially tangent to an inner circumference of the turbine nozzle and in contact with the stationary vane.

  19. Fractal geometry of music.

    PubMed Central

    Hsü, K J; Hsü, A J

    1990-01-01

    Music critics have compared Bach's music to the precision of mathematics. What "mathematics" and what "precision" are the questions for a curious scientist. The purpose of this short note is to suggest that the mathematics is, at least in part, Mandelbrot's fractal geometry and the precision is the deviation from a log-log linear plot. PMID:11607061

  20. The Helen of Geometry

    ERIC Educational Resources Information Center

    Martin, John

    2010-01-01

    The cycloid has been called the Helen of Geometry, not only because of its beautiful properties but also because of the quarrels it provoked between famous mathematicians of the 17th century. This article surveys the history of the cycloid and its importance in the development of the calculus.

  1. Emergent Hyperbolic Network Geometry

    NASA Astrophysics Data System (ADS)

    Bianconi, Ginestra; Rahmede, Christoph

    2017-02-01

    A large variety of interacting complex systems are characterized by interactions occurring between more than two nodes. These systems are described by simplicial complexes. Simplicial complexes are formed by simplices (nodes, links, triangles, tetrahedra etc.) that have a natural geometric interpretation. As such simplicial complexes are widely used in quantum gravity approaches that involve a discretization of spacetime. Here, by extending our knowledge of growing complex networks to growing simplicial complexes we investigate the nature of the emergent geometry of complex networks and explore whether this geometry is hyperbolic. Specifically we show that an hyperbolic network geometry emerges spontaneously from models of growing simplicial complexes that are purely combinatorial. The statistical and geometrical properties of the growing simplicial complexes strongly depend on their dimensionality and display the major universal properties of real complex networks (scale-free degree distribution, small-world and communities) at the same time. Interestingly, when the network dynamics includes an heterogeneous fitness of the faces, the growing simplicial complex can undergo phase transitions that are reflected by relevant changes in the network geometry.

  2. Emergent Hyperbolic Network Geometry

    PubMed Central

    Bianconi, Ginestra; Rahmede, Christoph

    2017-01-01

    A large variety of interacting complex systems are characterized by interactions occurring between more than two nodes. These systems are described by simplicial complexes. Simplicial complexes are formed by simplices (nodes, links, triangles, tetrahedra etc.) that have a natural geometric interpretation. As such simplicial complexes are widely used in quantum gravity approaches that involve a discretization of spacetime. Here, by extending our knowledge of growing complex networks to growing simplicial complexes we investigate the nature of the emergent geometry of complex networks and explore whether this geometry is hyperbolic. Specifically we show that an hyperbolic network geometry emerges spontaneously from models of growing simplicial complexes that are purely combinatorial. The statistical and geometrical properties of the growing simplicial complexes strongly depend on their dimensionality and display the major universal properties of real complex networks (scale-free degree distribution, small-world and communities) at the same time. Interestingly, when the network dynamics includes an heterogeneous fitness of the faces, the growing simplicial complex can undergo phase transitions that are reflected by relevant changes in the network geometry. PMID:28167818

  3. Gravity is Geometry.

    ERIC Educational Resources Information Center

    MacKeown, P. K.

    1984-01-01

    Clarifies two concepts of gravity--those of a fictitious force and those of how space and time may have geometry. Reviews the position of Newton's theory of gravity in the context of special relativity and considers why gravity (as distinct from electromagnetics) lends itself to Einstein's revolutionary interpretation. (JN)

  4. Geoff Giles and Geometry

    ERIC Educational Resources Information Center

    Fielker, David

    2007-01-01

    Geoff Giles died suddenly in 2005. He was a highly original thinker in the field of geometry teaching. As early as 1964, when teaching at Strathallen School in Perth, he was writing in "MT27" about constructing tessellations by modifying the sides of triangles and (irregular) quadrilaterals to produce what he called "trisides" and "quadrisides".…

  5. Geometry of spinor regularization

    NASA Technical Reports Server (NTRS)

    Hestenes, D.; Lounesto, P.

    1983-01-01

    The Kustaanheimo theory of spinor regularization is given a new formulation in terms of geometric algebra. The Kustaanheimo-Stiefel matrix and its subsidiary condition are put in a spinor form directly related to the geometry of the orbit in physical space. A physically significant alternative to the KS subsidiary condition is discussed. Derivations are carried out without using coordinates.

  6. Making Solid Geometry Solid.

    ERIC Educational Resources Information Center

    Hartz, Viggo

    1981-01-01

    Allowing students to use a polystyrene cutter to fashion their own three-dimensional models is suggested as a means of allowing individuals to experience problems and develop ideas related to solid geometry. A list of ideas that can lead to mathematical discovery is provided. (MP)

  7. Listening to Geometry

    ERIC Educational Resources Information Center

    Cooper, Brett D.; Barger, Rita

    2009-01-01

    The many connections between music and mathematics are well known. The length of a plucked string determines its tone, the time signature of a piece of music is a ratio, and note durations are measured in fractions. One connection commonly overlooked is that between music and geometry--specifically, geometric transformations, including…

  8. GEOMETRY, TENTATIVE GUIDES.

    ERIC Educational Resources Information Center

    KLIER, KATHERINE M.

    PRESENTED IS A FUSED COURSE IN PLANE, SOLID, AND COORDINATE GEOMETRY. ELEMENTARY SET THEORY, LOGIC, AND THE PRINCIPLE OF SEPARATION PROVIDE UNIFYING THREADS THROUGHOUT THE TEXT. THE TWO CURRICULUM GUIDES HAVE BEEN PREPARED FOR USE WITH TWO DIFFERENT TEXTS. EITHER CURRICULUM GUIDE MAY BE USED DEPENDING UPON THE CHOICE OF THE TEACHER AND THE NEEDS…

  9. Core Geometry Manual.

    ERIC Educational Resources Information Center

    Hirata, Li Ann

    Core Geometry is a course offered in the Option Y sequence of the high school mathematics program described by the Hawaii State Department of Education's guidelines. The emphasis of this course is on the general awareness and use of the relationships among points, lines, and figures in planes and space. This sample course is based on the…

  10. The Geometry of Viruses.

    ERIC Educational Resources Information Center

    Case, Christine L.

    1991-01-01

    Presented is an activity in which students make models of viruses, which allows them to visualize the shape of these microorganisms. Included are some background on viruses, the biology and geometry of viruses, directions for building viruses, a comparison of cells and viruses, and questions for students. (KR)

  11. Geometry and physics

    PubMed Central

    Atiyah, Michael; Dijkgraaf, Robbert; Hitchin, Nigel

    2010-01-01

    We review the remarkably fruitful interactions between mathematics and quantum physics in the past decades, pointing out some general trends and highlighting several examples, such as the counting of curves in algebraic geometry, invariants of knots and four-dimensional topology. PMID:20123740

  12. Advanced geometries and regimes

    SciTech Connect

    Bulanov, S. S.; Bulanov, S. V.; Turchetti, G.; Limpouch, J.; Klimo, O.; Psikal, J.; Margarone, D.; Korn, G.

    2013-07-26

    We review and discuss different schemes of laser ion acceleration as well as advanced target geometries in connection with the development of the laser-driven proton source for hadron therapy of oncological diseases, which is a part of the ELIMED project.

  13. Geometry of PDE's. IV

    NASA Astrophysics Data System (ADS)

    Prástaro, Agostino

    2008-02-01

    Following our previous results on this subject [R.P. Agarwal, A. Prástaro, Geometry of PDE's. III(I): Webs on PDE's and integral bordism groups. The general theory, Adv. Math. Sci. Appl. 17 (2007) 239-266; R.P. Agarwal, A. Prástaro, Geometry of PDE's. III(II): Webs on PDE's and integral bordism groups. Applications to Riemannian geometry PDE's, Adv. Math. Sci. Appl. 17 (2007) 267-285; A. Prástaro, Geometry of PDE's and Mechanics, World Scientific, Singapore, 1996; A. Prástaro, Quantum and integral (co)bordism in partial differential equations, Acta Appl. Math. (5) (3) (1998) 243-302; A. Prástaro, (Co)bordism groups in PDE's, Acta Appl. Math. 59 (2) (1999) 111-201; A. Prástaro, Quantized Partial Differential Equations, World Scientific Publishing Co, Singapore, 2004, 500 pp.; A. Prástaro, Geometry of PDE's. I: Integral bordism groups in PDE's, J. Math. Anal. Appl. 319 (2006) 547-566; A. Prástaro, Geometry of PDE's. II: Variational PDE's and integral bordism groups, J. Math. Anal. Appl. 321 (2006) 930-948; A. Prástaro, Th.M. Rassias, Ulam stability in geometry of PDE's, Nonlinear Funct. Anal. Appl. 8 (2) (2003) 259-278; I. Stakgold, Boundary Value Problems of Mathematical Physics, I, The MacMillan Company, New York, 1967; I. Stakgold, Boundary Value Problems of Mathematical Physics, II, Collier-MacMillan, Canada, Ltd, Toronto, Ontario, 1968], integral bordism groups of the Navier-Stokes equation are calculated for smooth, singular and weak solutions, respectively. Then a characterization of global solutions is made on this ground. Enough conditions to assure existence of global smooth solutions are given and related to nullity of integral characteristic numbers of the boundaries. Stability of global solutions are related to some characteristic numbers of the space-like Cauchy dataE Global solutions of variational problems constrained by (NS) are classified by means of suitable integral bordism groups too.

  14. Order-disorder structural transition in a confined fluid

    NASA Astrophysics Data System (ADS)

    de la Calleja-Mora, E. M.; Krott, Leandro B.; Barbosa, M. C.

    2016-05-01

    In this paper we analyze the amorphous/solid to disordered liquid structural phase transitions of an anomalous confined fluid in terms of their fractal dimensions. The model studied is composed by particles interaction through a two-length scales potential confined by two infinite plates. This fluid that in the bulk exhibits water-like anomalies under confinement forms layers of particles. We show that the fluid at the contact layer forms at high densities structures and transitions that can be mapped into fractal dimensions. The multi-fractal singularity spectrum is obtained in all these cases and it is used as the order parameter to quantify the structural transitions for each stage on the confined liquid. This mapping shows that the fractal dimension increases with the density and with the temperature.

  15. Designing Phoxonic Metamaterials with Fractal Geometry

    NASA Astrophysics Data System (ADS)

    Ni, Sisi; Koh, Cheong Yang; Kooi, Steve; Thomas, Edwin

    2012-02-01

    Recently, the concepts of fractal geometry have been introduced into electromagnetic and plasmonic metamaterials. With their self-similarity, structures based on fractal geometry should exhibit multi-band character with high Q factors due to the scaling law. However, there exist few studies of phononic metamaterials based on fractal geometry. We use COMSOL to investigate the wave propagation in two dimensional systems possessing fractal geometries. The simulations of these systems, guided by our recently developed general design framework, help to understand the role of design in determining the phononic properties of the structures. Proposed structures are being fabricated via standard lithographic or 3D printing techniques. The wave behavior of the structures can be characterized using Brillouin Light Scattering, Scanning Acoustic Microscope and Near-field Scanning Optical Microscopy. Due to their sparse spatial distribution, fractal phononic structures show potential fir ``smart skin'', where multifunctional components can be fabricated on the same platform.

  16. Scaling behaviour for the water transport in nanoconfined geometries

    PubMed Central

    Chiavazzo, Eliodoro; Fasano, Matteo; Asinari, Pietro; Decuzzi, Paolo

    2014-01-01

    The transport of water in nanoconfined geometries is different from bulk phase and has tremendous implications in nanotechnology and biotechnology. Here molecular dynamics is used to compute the self-diffusion coefficient D of water within nanopores, around nanoparticles, carbon nanotubes and proteins. For almost 60 different cases, D is found to scale linearly with the sole parameter θ as D(θ)=DB[1+(DC/DB−1)θ], with DB and DC the bulk and totally confined diffusion of water, respectively. The parameter θ is primarily influenced by geometry and represents the ratio between the confined and total water volumes. The D(θ) relationship is interpreted within the thermodynamics of supercooled water. As an example, such relationship is shown to accurately predict the relaxometric response of contrast agents for magnetic resonance imaging. The D(θ) relationship can help in interpreting the transport of water molecules under nanoconfined conditions and tailoring nanostructures with precise modulation of water mobility. PMID:24699509

  17. CORRELATIONS IN CONFINED QUANTUM PLASMAS

    SciTech Connect

    DUFTY J W

    2012-01-11

    This is the final report for the project 'Correlations in Confined Quantum Plasmas', NSF-DOE Partnership Grant DE FG02 07ER54946, 8/1/2007 - 7/30/2010. The research was performed in collaboration with a group at Christian Albrechts University (CAU), Kiel, Germany. That collaboration, almost 15 years old, was formalized during the past four years under this NSF-DOE Partnership Grant to support graduate students at the two institutions and to facilitate frequent exchange visits. The research was focused on exploring the frontiers of charged particle physics evolving from new experimental access to unusual states associated with confinement. Particular attention was paid to combined effects of quantum mechanics and confinement. A suite of analytical and numerical tools tailored to the specific inquiry has been developed and employed

  18. Nuclear Quantum Effects in H(+) and OH(-) Diffusion along Confined Water Wires.

    PubMed

    Rossi, Mariana; Ceriotti, Michele; Manolopoulos, David E

    2016-08-04

    The diffusion of protons and hydroxide ions along water wires provides an efficient mechanism for charge transport that is exploited by biological membrane channels and shows promise for technological applications such as fuel cells. However, what is lacking for a better control and design of these systems is a thorough theoretical understanding of the diffusion process at the atomic scale. Here we focus on two aspects of this process that are often disregarded because of their high computational cost: the use of first-principles potential energy surfaces and the treatment of the nuclei as quantum particles. We consider proton and hydroxide ions in finite water wires using density functional theory augmented with an apolar cylindrical confining potential. We employ machine learning techniques to identify the charged species, thus obtaining an agnostic definition that takes explicitly into account the delocalization of the charge in the Grotthus-like mechanism. We include nuclear quantum effects (NQEs) through the thermostated ring polymer molecular dynamics method and model finite system size effects by considering Langevin dynamics on the potential of mean force of the charged species, allowing us to extract the same "universal" diffusion coefficient from simulations with different wire sizes. In the classical case, diffusion coefficients depend significantly on the potential energy surface, in particular on how dispersion forces modulate water-water distances. NQEs, however, make the diffusion less sensitive to the underlying potential and geometry of the wire.

  19. Isolation and confinement - Considerations for colonization

    NASA Technical Reports Server (NTRS)

    Akins, F. R.

    1978-01-01

    This paper discusses three types of isolation (sensory/perceptual, temporal, and social) that could adversely affect mankind in space. The literature dealing with laboratory and field experiments relevant to these areas is summarized and suggestions are given for dealing with these problems within the space colony community. Also, consideration is given to the potential effects of physical confinement and the need for usable space. Finally, a modification of Maslow's hierarchy of needs is proposed as a theoretical framework to understand and investigate mankind's psychological needs in space.

  20. Acoustic confinement in superlattice cavities

    NASA Astrophysics Data System (ADS)

    Garcia-Sanchez, Daniel; Déleglise, Samuel; Thomas, Jean-Louis; Atkinson, Paola; Lagoin, Camille; Perrin, Bernard

    2016-09-01

    The large coupling rate between the acoustic and optical fields confined in GaAs/AlAs superlattice cavities makes them appealing systems for cavity optomechanics. We have developed a mathematical model based on the scattering matrix that allows the acoustic guided modes to be predicted in nano and micropillar superlattice cavities. We demonstrate here that the reflection at the surface boundary considerably modifies the acoustic quality factor and leads to significant confinement at the micropillar center. Our mathematical model also predicts unprecedented acoustic Fano resonances on nanopillars featuring small mode volumes and very high mechanical quality factors, making them attractive systems for optomechanical applications.

  1. Special topics in plasma confinement

    NASA Astrophysics Data System (ADS)

    Taylor, J. B.; Newton, S. L.

    2015-10-01

    > These notes are based on lectures given by one of us (J.B.T.) at the University of Texas in Austin in 1991. Part I concerns some basic features of plasma confinement by magnetic fields as an introduction to an account of plasma relaxation in Part II. Part III discusses confinement by magnetic mirrors, especially minimum- systems. It also includes a general discussion of adiabatic invariants and of the principle of maximal ordering in perturbation theory. Part IV is devoted to the analysis of perturbations in toroidal plasmas and the stability of ballooning modes.

  2. CONFINEMENT OF HIGH TEMPERATURE PLASMA

    DOEpatents

    Koenig, H.R.

    1963-05-01

    The confinement of a high temperature plasma in a stellarator in which the magnetic confinement has tended to shift the plasma from the center of the curved, U-shaped end loops is described. Magnetic means are provided for counteracting this tendency of the plasma to be shifted away from the center of the end loops, and in one embodiment this magnetic means is a longitudinally extending magnetic field such as is provided by two sets of parallel conductors bent to follow the U-shaped curvature of the end loops and energized oppositely on the inside and outside of this curvature. (AEC)

  3. Building solids inside nano-space: from confined amorphous through confined solvate to confined 'metastable' polymorph.

    PubMed

    Nartowski, K P; Tedder, J; Braun, D E; Fábián, L; Khimyak, Y Z

    2015-10-14

    The nanocrystallisation of complex molecules inside mesoporous hosts and control over the resulting structure is a significant challenge. To date the largest organic molecule crystallised inside the nano-pores is a known pharmaceutical intermediate - ROY (259.3 g mol(-1)). In this work we demonstrate smart manipulation of the phase of a larger confined pharmaceutical - indomethacin (IMC, 357.8 g mol(-1)), a substance with known conformational flexibility and complex polymorphic behaviour. We show the detailed structural analysis and the control of solid state transformations of encapsulated molecules inside the pores of mesoscopic cellular foam (MCF, pore size ca. 29 nm) and controlled pore glass (CPG, pore size ca. 55 nm). Starting from confined amorphous IMC we drive crystallisation into a confined methanol solvate, which upon vacuum drying leads to the stabilised rare form V of IMC inside the MCF host. In contrast to the pure form, encapsulated form V does not transform into a more stable polymorph upon heating. The size of the constraining pores and the drug concentration within the pores determine whether the amorphous state of the drug is stabilised or it recrystallises into confined nanocrystals. The work presents, in a critical manner, an application of complementary techniques (DSC, PXRD, solid-state NMR, N2 adsorption) to confirm unambiguously the phase transitions under confinement and offers a comprehensive strategy towards the formation and control of nano-crystalline encapsulated organic solids.

  4. From stripe to slab confinement for DNA linearization in nanochannels

    NASA Astrophysics Data System (ADS)

    Cifra, Peter; Benkova, Zuzana; Namer, Pavol

    We investigate suggested advantageous analysis in the linearization experiments with macromolecules confined in a stripe-like channel using Monte Carlo simulations. The enhanced chain extension in a stripe that is due to significant excluded volume interactions between monomers in two dimensions weakens on transition to experimentally feasible slit-like channel. Based on the chain extension-confinement strength dependence and the structure factor behavior for the chain in stripe we infer the excluded volume regime typical for two-dimensional systems. On transition to the slab geometry, the advantageous chain extension decreases and the Gaussian regime is observed for not very long semiflexible chains. The evidence for pseudo-ideality in confined chains is based on indicators such as the extension curves, variation of the extension with the persistence length or the structure factor. The slab behavior is observed when the stripe (originally of monomer thickness) reaches the thickness larger than cca 10nm in the third dimension. This maximum height of the slab to retain the advantage of the stripe is very low and this have implication for DNA linearization experiments. The presented analysis, however, has a broader relevance for confined polymers. Support from Slovak R&D Agency (SRDA-0451-11) is acknowledged.

  5. Long-range interactions between soft colloidal particles in slit-pore geometries.

    PubMed

    Klapp, Sabine H L; Qu, D; Klitzing, Regine V

    2007-02-15

    Combining theoretical and experimental techniques, we investigate the structure formation of charged colloidal suspensions of silica particles in bulk and in spatial confinement (slit-pore geometry). Our focus is to identify characteristic length scales determining typical quantities, such as the position of the main peak of the bulk structure factor and the period of the oscillatory force profile in the slitpore. We obtain these quantities from integral equations/SANS experiments (bulk) and Monte Carlo simulations/colloidal probe-AFM measurements (confinement), in which the theoretical calculations are based on the Derjaguin-Landau-Verwey-Overbeck (DLVO) potential. Both in bulk and in the slitpore, we find excellent qualitative and quantitative agreement between theory and experiment as long as the ionic strength chosen in the DLVO potential is sufficiently low (implying a relatively long-ranged interaction). In particular, the bulk properties of these systems obey the widely accepted density scaling of xi proportional to phi(-1/3). On the other hand, systems with larger ionic strengths and, consequently, more short-ranged interactions do not obey such power law behavior and rather resemble an uncharged hard-sphere fluid, in which the relevant length scale is the particle diameter.

  6. An electrostatically and a magnetically confined electron gun lens system

    NASA Technical Reports Server (NTRS)

    Bernius, Mark T.; Man, Kin F.; Chutjian, Ara

    1988-01-01

    Focal properties, electron trajectory calculations, and geometries are given for two electron 'gun' lens systems that have a variety of applications in, for example, electron-neutral and electron-ion scattering experiments. One nine-lens system utilizes only electrostatic confinement and is capable of focusing electrons onto a fixed target with extremely small divergence angles, over a range of final energies 1-790 eV. The second gun lens system is a simpler three-lens system suitable for use in a uniform, solenoidal magnetic field. While the focusing properties of such a magnetically confined lens systenm are simpler to deal with, the system does illustrate features of electron extraction and Brillouin flow that have not been suitably emphasized in the literature.

  7. 3D cancer cell migration in a confined matrix

    NASA Astrophysics Data System (ADS)

    Alobaidi, Amani; Sun, Bo

    Cancer cell migration is widely studied in 2D motion, which does not mimic the invasion processes in vivo. More recently, 3D cell migration studies have been performed. The ability of cancer cells to migrate within the extracellular matrix depends on the physical and biochemical features of the extracellular matrix. We present a model of cell motility in confined matrix geometry. The aim of the study is to study cancer migration in collagen matrix, as a soft tissue, to investigate their motility within the confined and surrounding collagen environment. Different collagen concentrations have been used to show the ability of these cancer cells to move through such a complex structure by measuring Cancer cell migration velocity as well as the displacement. Graduate student physics department.

  8. Confinement induces actin flow in a meiotic cytoplasm

    PubMed Central

    Pinot, Mathieu; Steiner, Villier; Dehapiot, Benoit; Yoo, Byung-Kuk; Chesnel, Franck; Blanchoin, Laurent; Kervrann, Charles; Gueroui, Zoher

    2012-01-01

    In vivo, F-actin flows are observed at different cell life stages and participate in various developmental processes during asymmetric divisions in vertebrate oocytes, cell migration, or wound healing. Here, we show that confinement has a dramatic effect on F-actin spatiotemporal organization. We reconstitute in vitro the spontaneous generation of F-actin flow using Xenopus meiotic extracts artificially confined within a geometry mimicking the cell boundary. Perturbations of actin polymerization kinetics or F-actin nucleation sites strongly modify the network flow dynamics. A combination of quantitative image analysis and biochemical perturbations shows that both spatial localization of F-actin nucleators and actin turnover play a decisive role in generating flow. Interestingly, our in vitro assay recapitulates several symmetry-breaking processes observed in oocytes and early embryonic cells. PMID:22753521

  9. Defect topologies in chiral liquid crystals confined to mesoscopic channels

    SciTech Connect

    Schlotthauer, Sergej Skutnik, Robert A.; Stieger, Tillmann; Schoen, Martin

    2015-05-21

    We present Monte Carlo simulations in the grand canonical and canonical ensembles of a chiral liquid crystal confined to mesochannels of variable sizes and geometries. The mesochannels are taken to be quasi-infinite in one dimension but finite in the two other directions. Under thermodynamic conditions chosen and for a selected value of the chirality coupling constant, the bulk liquid crystal exhibits structural characteristics of a blue phase II. This is established through the tetrahedral symmetry of disclination lines and the characteristic simple-cubic arrangement of double-twist helices formed by the liquid-crystal molecules along all three axes of a Cartesian coordinate system. If the blue phase II is then exposed to confinement, the interplay between its helical structure, various anchoring conditions at the walls of the mesochannels, and the shape of the mesochannels gives rise to a broad variety of novel, qualitative disclination-line structures that are reported here for the first time.

  10. Cylindrical geometry hall thruster

    DOEpatents

    Raitses, Yevgeny; Fisch, Nathaniel J.

    2002-01-01

    An apparatus and method for thrusting plasma, utilizing a Hall thruster with a cylindrical geometry, wherein ions are accelerated in substantially the axial direction. The apparatus is suitable for operation at low power. It employs small size thruster components, including a ceramic channel, with the center pole piece of the conventional annular design thruster eliminated or greatly reduced. Efficient operation is accomplished through magnetic fields with a substantial radial component. The propellant gas is ionized at an optimal location in the thruster. A further improvement is accomplished by segmented electrodes, which produce localized voltage drops within the thruster at optimally prescribed locations. The apparatus differs from a conventional Hall thruster, which has an annular geometry, not well suited to scaling to small size, because the small size for an annular design has a great deal of surface area relative to the volume.

  11. E 8 geometry

    NASA Astrophysics Data System (ADS)

    Cederwall, Martin; Rosabal, J. A.

    2015-07-01

    We investigate exceptional generalised diffeomorphisms based on E 8(8) in a geometric setting. The transformations include gauge transformations for the dual gravity field. The surprising key result, which allows for a development of a tensor formalism, is that it is possible to define field-dependent transformations containing connection, which are covariant. We solve for the spin connection and construct a curvature tensor. A geometry for the Ehlers symmetry SL( n + 1) is sketched. Some related issues are discussed.

  12. Poisson-Riemannian geometry

    NASA Astrophysics Data System (ADS)

    Beggs, Edwin J.; Majid, Shahn

    2017-04-01

    We study noncommutative bundles and Riemannian geometry at the semiclassical level of first order in a deformation parameter λ, using a functorial approach. This leads us to field equations of 'Poisson-Riemannian geometry' between the classical metric, the Poisson bracket and a certain Poisson-compatible connection needed as initial data for the quantisation of the differential structure. We use such data to define a functor Q to O(λ2) from the monoidal category of all classical vector bundles equipped with connections to the monoidal category of bimodules equipped with bimodule connections over the quantised algebra. This is used to 'semiquantise' the wedge product of the exterior algebra and in the Riemannian case, the metric and the Levi-Civita connection in the sense of constructing a noncommutative geometry to O(λ2) . We solve our field equations for the Schwarzschild black-hole metric under the assumption of spherical symmetry and classical dimension, finding a unique solution and the necessity of nonassociativity at order λ2, which is similar to previous results for quantum groups. The paper also includes a nonassociative hyperboloid, nonassociative fuzzy sphere and our previously algebraic bicrossproduct model.

  13. Integral geometry and holography

    DOE PAGES

    Czech, Bartlomiej; Lamprou, Lampros; McCandlish, Samuel; ...

    2015-10-27

    We present a mathematical framework which underlies the connection between information theory and the bulk spacetime in the AdS3/CFT2 correspondence. A key concept is kinematic space: an auxiliary Lorentzian geometry whose metric is defined in terms of conditional mutual informations and which organizes the entanglement pattern of a CFT state. When the field theory has a holographic dual obeying the Ryu-Takayanagi proposal, kinematic space has a direct geometric meaning: it is the space of bulk geodesics studied in integral geometry. Lengths of bulk curves are computed by kinematic volumes, giving a precise entropic interpretation of the length of any bulkmore » curve. We explain how basic geometric concepts -- points, distances and angles -- are reflected in kinematic space, allowing one to reconstruct a large class of spatial bulk geometries from boundary entanglement entropies. In this way, kinematic space translates between information theoretic and geometric descriptions of a CFT state. As an example, we discuss in detail the static slice of AdS3 whose kinematic space is two-dimensional de Sitter space.« less

  14. Emergent Complex Network Geometry

    PubMed Central

    Wu, Zhihao; Menichetti, Giulia; Rahmede, Christoph; Bianconi, Ginestra

    2015-01-01

    Networks are mathematical structures that are universally used to describe a large variety of complex systems such as the brain or the Internet. Characterizing the geometrical properties of these networks has become increasingly relevant for routing problems, inference and data mining. In real growing networks, topological, structural and geometrical properties emerge spontaneously from their dynamical rules. Nevertheless we still miss a model in which networks develop an emergent complex geometry. Here we show that a single two parameter network model, the growing geometrical network, can generate complex network geometries with non-trivial distribution of curvatures, combining exponential growth and small-world properties with finite spectral dimensionality. In one limit, the non-equilibrium dynamical rules of these networks can generate scale-free networks with clustering and communities, in another limit planar random geometries with non-trivial modularity. Finally we find that these properties of the geometrical growing networks are present in a large set of real networks describing biological, social and technological systems. PMID:25985280

  15. Integral geometry and holography

    SciTech Connect

    Czech, Bartlomiej; Lamprou, Lampros; McCandlish, Samuel; Sully, James

    2015-10-27

    We present a mathematical framework which underlies the connection between information theory and the bulk spacetime in the AdS3/CFT2 correspondence. A key concept is kinematic space: an auxiliary Lorentzian geometry whose metric is defined in terms of conditional mutual informations and which organizes the entanglement pattern of a CFT state. When the field theory has a holographic dual obeying the Ryu-Takayanagi proposal, kinematic space has a direct geometric meaning: it is the space of bulk geodesics studied in integral geometry. Lengths of bulk curves are computed by kinematic volumes, giving a precise entropic interpretation of the length of any bulk curve. We explain how basic geometric concepts -- points, distances and angles -- are reflected in kinematic space, allowing one to reconstruct a large class of spatial bulk geometries from boundary entanglement entropies. In this way, kinematic space translates between information theoretic and geometric descriptions of a CFT state. As an example, we discuss in detail the static slice of AdS3 whose kinematic space is two-dimensional de Sitter space.

  16. Noncommutative geometry and arithmetics

    NASA Astrophysics Data System (ADS)

    Almeida, P.

    2009-09-01

    We intend to illustrate how the methods of noncommutative geometry are currently used to tackle problems in class field theory. Noncommutative geometry enables one to think geometrically in situations in which the classical notion of space formed of points is no longer adequate, and thus a “noncommutative space” is needed; a full account of this approach is given in [3] by its main contributor, Alain Connes. The class field theory, i.e., number theory within the realm of Galois theory, is undoubtedly one of the main achievements in arithmetics, leading to an important algebraic machinery; for a modern overview, see [23]. The relationship between noncommutative geometry and number theory is one of the many themes treated in [22, 7-9, 11], a small part of which we will try to put in a more down-to-earth perspective, illustrating through an example what should be called an “application of physics to mathematics,” and our only purpose is to introduce nonspecialists to this beautiful area.

  17. X-ray absorption spectroscopy to analyze nuclear geometry and electronic structure of biological metal centers--potential and questions examined with special focus on the tetra-nuclear manganese complex of oxygenic photosynthesis.

    PubMed

    Dau, Holger; Liebisch, Peter; Haumann, Michael

    2003-07-01

    X-ray absorption spectroscopy (XAS) has become a prominent tool for the element-specific analysis of transition metals at the catalytic center of metalloenzymes. In the present study the information content of X-ray spectra with respect to the nuclear geometry and, in particular, to the electronic structure of the protein-bound metal ions is explored using the manganese complex of photosystem II (PSIII) as a model system. The EXAFS range carries direct information on the number and distances of ligands as well as on the chemical type of the ligand donor function. For first-sphere ligands and second-sphere metals (in multinuclear complexes), the determination of precise distances is mostly straightforward, whereas the determination of coordination numbers clearly requires more effort. The EXAFS section starts with an exemplifying discussion of a PSII spectrum data set with focus on the coordination number problem. Subsequently, the method of linear dichroism EXAFS spectroscopy is introduced and it is shown how the EXAFS data leads to an atomic resolution model for the tetra-manganese complex of PSII. In the XANES section the following aspects are considered: (1) Alternative approaches are evaluated for determination of the metal-oxidation state by comparison with a series of model compounds. (2) The interpretation of XANES spectra in terms of molecular orbitals (MOs) is approached by comparative multiple-scattering calculations and MO calculations. (3) The underlying reasons for the oxidation-state dependence of the XANES spectra are explored. Furthermore, the potential of modern XANES theory is demonstrated by presenting first simulations of the dichroism in the XANES spectra of the PSII manganese complex.

  18. Confinement and lattice gauge theory

    SciTech Connect

    Creutz, M

    1980-06-01

    The motivation for formulating gauge theories on a lattice to study non-perturbative phenomena is reviewed, and recent progress supporting the compatibility of asymptotic freedom and quark confinement in the standard SU(3) Yang-Mills theory of the strong interaction is discussed.

  19. Permit-Required Confined Spaces

    DTIC Science & Technology

    1998-01-01

    Permit-Required Confined Spaces U.S. Department of Labor Occupational Safety and Health Administration OSHA 3138 1998 (Revised) Report Documentation...Department of Labor Occupational Safety & Health Administration 200 Constitution Avenue Washington, DC 20210 Performing Organization Report Number OSHA 3138...determine compliance responsibili- ties, which are set forth in OSHA standards themselves and the Occupational Safety and Health Act. Moreover, because

  20. Inertial confinement fusion (ICF) review

    SciTech Connect

    Hammer, D.; Dyson, F.; Fortson, N.; Novick, B.; Panofsky, W.; Rosenbluth, M.; Treiman, S.; York, H.

    1996-03-01

    During its 1996 winter study JASON reviewed the DOE Inertial Confinement Fusion (ICF) program. This included the National Ignition Facility (NIF) and proposed studies. The result of the review was to comment on the role of the ICF program in support of the DOE Science Based Stockpile Stewardship program.

  1. Cable equation for general geometry.

    PubMed

    López-Sánchez, Erick J; Romero, Juan M

    2017-02-01

    The cable equation describes the voltage in a straight cylindrical cable, and this model has been employed to model electrical potential in dendrites and axons. However, sometimes this equation might give incorrect predictions for some realistic geometries, in particular when the radius of the cable changes significantly. Cables with a nonconstant radius are important for some phenomena, for example, discrete swellings along the axons appear in neurodegenerative diseases such as Alzheimers, Parkinsons, human immunodeficiency virus associated dementia, and multiple sclerosis. In this paper, using the Frenet-Serret frame, we propose a generalized cable equation for a general cable geometry. This generalized equation depends on geometric quantities such as the curvature and torsion of the cable. We show that when the cable has a constant circular cross section, the first fundamental form of the cable can be simplified and the generalized cable equation depends on neither the curvature nor the torsion of the cable. Additionally, we find an exact solution for an ideal cable which has a particular variable circular cross section and zero curvature. For this case we show that when the cross section of the cable increases the voltage decreases. Inspired by this ideal case, we rewrite the generalized cable equation as a diffusion equation with a source term generated by the cable geometry. This source term depends on the cable cross-sectional area and its derivates. In addition, we study different cables with swelling and provide their numerical solutions. The numerical solutions show that when the cross section of the cable has abrupt changes, its voltage is smaller than the voltage in the cylindrical cable. Furthermore, these numerical solutions show that the voltage can be affected by geometrical inhomogeneities on the cable.

  2. Cable equation for general geometry

    NASA Astrophysics Data System (ADS)

    López-Sánchez, Erick J.; Romero, Juan M.

    2017-02-01

    The cable equation describes the voltage in a straight cylindrical cable, and this model has been employed to model electrical potential in dendrites and axons. However, sometimes this equation might give incorrect predictions for some realistic geometries, in particular when the radius of the cable changes significantly. Cables with a nonconstant radius are important for some phenomena, for example, discrete swellings along the axons appear in neurodegenerative diseases such as Alzheimers, Parkinsons, human immunodeficiency virus associated dementia, and multiple sclerosis. In this paper, using the Frenet-Serret frame, we propose a generalized cable equation for a general cable geometry. This generalized equation depends on geometric quantities such as the curvature and torsion of the cable. We show that when the cable has a constant circular cross section, the first fundamental form of the cable can be simplified and the generalized cable equation depends on neither the curvature nor the torsion of the cable. Additionally, we find an exact solution for an ideal cable which has a particular variable circular cross section and zero curvature. For this case we show that when the cross section of the cable increases the voltage decreases. Inspired by this ideal case, we rewrite the generalized cable equation as a diffusion equation with a source term generated by the cable geometry. This source term depends on the cable cross-sectional area and its derivates. In addition, we study different cables with swelling and provide their numerical solutions. The numerical solutions show that when the cross section of the cable has abrupt changes, its voltage is smaller than the voltage in the cylindrical cable. Furthermore, these numerical solutions show that the voltage can be affected by geometrical inhomogeneities on the cable.

  3. The Geometry of Quasar Outflows

    NASA Astrophysics Data System (ADS)

    Ganguly, Rajib

    2012-10-01

    Quasar outflows are important for understanding the accretion and growth processes of the central black hole, but also potentially play a role in feedback to the galaxy, halting star formation and infall of gas. A big uncertainty lies in the geometry and density of these outflows, especially as a function of ionization and velocity. We aim to tackle this using the archival COS M grating spectra of 266 quasars. We separate the geometry of outflows into two parts: the solid angle subtended around the black hole, and the distance of the outflow from the central engine. Large numbers of quasars with high resolution spectra are required for each aspect of this statistical investigation. First, we will determine which/how many absorption-line systems are intrinsic through both partial covering methods and statistical assessments. Second, we will consider the incidence of intrinsic absorbers as a function of quasar property {e.g., radio-loudness, SED shape, black hole mass, bolometric luminosity}. This will reveal what determines the solid angle. This can only be done at moderate redshifts where quasars with a larger range of properties are observable, and hence requires HST/COS. Third, we will use the wide range of diagnostic lines to constrain the physical conditions of the absorbers. We will target the CIII*1175 complex and apply photoionization models to constrain the densities and ionization parameters. This will provide the largest set yet of intrinsic absorbers with systematic distance constraints. In tandem with the solid angles, this work will inform models regarding the geometry of quasar outflows.

  4. Simulation of confined magnetohydrodynamic flows with Dirichlet boundary conditions using a pseudo-spectral method with volume penalization

    SciTech Connect

    Morales, Jorge A.; Leroy, Matthieu; Bos, Wouter J.T.; Schneider, Kai

    2014-10-01

    A volume penalization approach to simulate magnetohydrodynamic (MHD) flows in confined domains is presented. Here the incompressible visco-resistive MHD equations are solved using parallel pseudo-spectral solvers in Cartesian geometries. The volume penalization technique is an immersed boundary method which is characterized by a high flexibility for the geometry of the considered flow. In the present case, it allows to use other than periodic boundary conditions in a Fourier pseudo-spectral approach. The numerical method is validated and its convergence is assessed for two- and three-dimensional hydrodynamic (HD) and MHD flows, by comparing the numerical results with results from literature and analytical solutions. The test cases considered are two-dimensional Taylor–Couette flow, the z-pinch configuration, three dimensional Orszag–Tang flow, Ohmic-decay in a periodic cylinder, three-dimensional Taylor–Couette flow with and without axial magnetic field and three-dimensional Hartmann-instabilities in a cylinder with an imposed helical magnetic field. Finally, we present a magnetohydrodynamic flow simulation in toroidal geometry with non-symmetric cross section and imposing a helical magnetic field to illustrate the potential of the method.

  5. Impact of surface charges on the solvation forces in confined colloidal solutions.

    PubMed

    Grandner, Stefan; Zeng, Yan; v Klitzing, Regine; Klapp, Sabine H L

    2009-10-21

    Combining computer simulations and experiments we address the impact of charged surfaces on the solvation forces of a confined, charged colloidal suspension (slit-pore geometry). Investigations based on the colloidal-probe atomic-force-microscope technique indicate that an increase in surface charges markedly enhances the oscillations of the force in terms of their amplitude. To understand this effect on a theoretical level we perform grand-canonical Monte-Carlo simulations (GCMC) of a coarse-grained model system. It turns out that various established approaches of the interaction between a charged colloid and a charged wall, such as linearized Poisson-Boltzmann (PB) theory involving the bulk screening length, do not reproduce the experimental observations. We thus introduce a modified PB potential with a space-dependent screening parameter. The latter takes into account, in an approximate way, the fact that the charged walls release additional (wall) counterions which accumulate in a thin layer at the surface(s). The resulting, still purely repulsive fluid-wall potential displays a nonmonotonic behavior as function of the surface potential with respect to the strength and range of repulsion. GCMC simulations based on this potential reproduce the experimentally observed charge-induced enhancement in the force oscillations. We also show, both by experiment and by simulations, that the asymptotic wave- and decay length of the oscillating force do not change with the wall charge, in agreement with predictions from density functional theory.

  6. Impact of surface charges on the solvation forces in confined colloidal solutions

    NASA Astrophysics Data System (ADS)

    Grandner, Stefan; Zeng, Yan; Klitzing, Regine v.; Klapp, Sabine H. L.

    2009-10-01

    Combining computer simulations and experiments we address the impact of charged surfaces on the solvation forces of a confined, charged colloidal suspension (slit-pore geometry). Investigations based on the colloidal-probe atomic-force-microscope technique indicate that an increase in surface charges markedly enhances the oscillations of the force in terms of their amplitude. To understand this effect on a theoretical level we perform grand-canonical Monte-Carlo simulations (GCMC) of a coarse-grained model system. It turns out that various established approaches of the interaction between a charged colloid and a charged wall, such as linearized Poisson-Boltzmann (PB) theory involving the bulk screening length, do not reproduce the experimental observations. We thus introduce a modified PB potential with a space-dependent screening parameter. The latter takes into account, in an approximate way, the fact that the charged walls release additional (wall) counterions which accumulate in a thin layer at the surface(s). The resulting, still purely repulsive fluid-wall potential displays a nonmonotonic behavior as function of the surface potential with respect to the strength and range of repulsion. GCMC simulations based on this potential reproduce the experimentally observed charge-induced enhancement in the force oscillations. We also show, both by experiment and by simulations, that the asymptotic wave- and decay length of the oscillating force do not change with the wall charge, in agreement with predictions from density functional theory.

  7. Spatial Variations in Carbon Storage along Headwater Fluvial Networks with Differing Valley Geometry

    NASA Astrophysics Data System (ADS)

    Wohl, E. E.; Dwire, K. A.; Polvi, L. E.; Sutfin, N. A.; Bazan, R. A.

    2011-12-01

    We distinguish multiple valley types along headwater fluvial networks in the Colorado Front Range based on valley geometry (downstream gradient and valley-bottom width relative to active channel width) and the presence of biotic drivers (beaver dams or channel-spanning logjams associated with old-growth forest) capable of creating a multi-thread channel pattern. Valley type influences storage of fine sediment, organic matter, and carbon. Deep, narrow valleys have limited storage potential, whereas wide, shallow valleys with multi-thread channels have substantial storage potential. Multi-thread channels only occur in the presence of a biotic driver. Given the importance of headwater streams in the global carbon cycle, it becomes important to understand the spatial distribution and magnitude of carbon storage along these streams, as well as the processes governing patterns of storage. We compare carbon stored in three reservoirs: riparian vegetation (live, dead, and litter), instream and floodplain large wood, and floodplain soils for 100-m-long valley segments in seven different valley types. The valley types are (i) laterally confined valleys in old-growth forest, (ii) partly confined valleys in old-growth forest, (iii) laterally unconfined valleys with multi-thread channels in old-growth forest, (iv) laterally unconfined valleys with single-thread channels in old-growth forest, (v) laterally confined valleys in younger forest, (vi) recently abandoned beaver-meadow complexes with multi-thread channels and willow thickets, and (vii) longer abandoned beaver-meadow complexes with single-thread channels and very limited woody vegetation. Preliminary results suggest that, although multi-thread channel segments driven by beavers or logjams cover less than 25 percent of the total length of headwater river networks in the study area, they account for more than three-quarters of the carbon stored along the river network. Historical loss of beavers and old-growth forest has

  8. Open-ended magnetic confinement systems for fusion

    SciTech Connect

    Post, R.F.; Ryutov, D.D.

    1995-05-01

    Magnetic confinement systems that use externally generated magnetic fields can be divided topologically into two classes: ``closed`` and `open``. The tokamak, the stellarator, and the reversed-field-pinch approaches are representatives of the first category, while mirror-based systems and their variants are of the second category. While the recent thrust of magnetic fusion research, with its emphasis on the tokamak, has been concentrated on closed geometry, there are significant reasons for the continued pursuit of research into open-ended systems. The paper discusses these reasons, reviews the history and the present status of open-ended systems, and suggests some future directions for the research.

  9. Local Chain Segregation and Entanglements in a Confined Polymer Melt

    NASA Astrophysics Data System (ADS)

    Lee, Nam-Kyung; Diddens, Diddo; Meyer, Hendrik; Johner, Albert

    2017-02-01

    The reptation mechanism, introduced by de Gennes and Edwards, where a polymer diffuses along a fluffy tube, defined by the constraints imposed by its surroundings, convincingly describes the relaxation of long polymers in concentrated solutions and melts. We propose that the scale for the tube diameter is set by local chain segregation, which we study analytically. We show that the concept of local segregation is especially operational for confined geometries, where segregation extends over mesoscopic domains, drastically reducing binary contacts, and provide an estimate of the entanglement length. Our predictions are quantitatively supported by extensive molecular dynamics simulations on systems consisting of long, entangled chains.

  10. Weyl gravity and Cartan geometry

    NASA Astrophysics Data System (ADS)

    Attard, J.; François, J.; Lazzarini, S.

    2016-04-01

    We point out that the Cartan geometry known as the second-order conformal structure provides a natural differential geometric framework underlying gauge theories of conformal gravity. We are concerned with two theories: the first one is the associated Yang-Mills-like Lagrangian, while the second, inspired by [1], is a slightly more general one that relaxes the conformal Cartan geometry. The corresponding gauge symmetry is treated within the Becchi-Rouet-Stora-Tyutin language. We show that the Weyl gauge potential is a spurious degree of freedom, analogous to a Stueckelberg field, that can be eliminated through the dressing field method. We derive sets of field equations for both the studied Lagrangians. For the second one, they constrain the gauge field to be the "normal conformal Cartan connection.''Finally, we provide in a Lagrangian framework a justification of the identification, in dimension 4, of the Bach tensor with the Yang-Mills current of the normal conformal Cartan connection, as proved in [2].

  11. Azimuthal field instability in a confined ferrofluid.

    PubMed

    Dias, Eduardo O; Miranda, José A

    2015-02-01

    We report the development of interfacial ferrohydrodynamic instabilities when an initially circular bubble of a nonmagnetic inviscid fluid is surrounded by a viscous ferrofluid in the confined geometry of a Hele-Shaw cell. The fluid-fluid interface becomes unstable due to the action of magnetic forces induced by an azimuthal field produced by a straight current-carrying wire that is normal to the cell plates. In this framework, a pattern formation process takes place through the interplay between magnetic and surface tension forces. By employing a perturbative mode-coupling approach we investigate analytically both linear and intermediate nonlinear regimes of the interface evolution. As a result, useful analytical information can be extracted regarding the destabilizing role of the azimuthal field at the linear level, as well as its influence on the interfacial pattern morphology at the onset of nonlinear effects. Finally, a vortex sheet formalism is used to access fully nonlinear stationary solutions for the two-fluid interface shapes.

  12. Action-at-a-distance in confined superfluid 4-HE

    NASA Astrophysics Data System (ADS)

    Thomson, Stephen R. D.

    Previous measurements of the superfluid density for 4He revealed effects at distances much larger than the correlation length. The first study in this thesis was to systematically examine the length scale over which these effects can manifest via confining the 4He in a Corbino geometry. The Corbino geometry consists of two concentric 268 nm planar regions connected via a 34 nm film above a ring of width W. This width W is varied from 4 micrometers up to 100 micrometers in different experimental cells. Two new effects in the superfluid fraction were found: one is hydrodynamic and the other is a shift in the transition temperature as a function of ring width. A second study examined planar films. This revealed that overall scaling fails while the critical temperature can be scaled.

  13. Swimming of Vorticella in two-dimensional confinements

    NASA Astrophysics Data System (ADS)

    Sotelo, Luz; Park, Young-Gil; Jung, Sunghwan; Ryu, Sangjin

    2015-03-01

    Vorticellais a ciliate observed in the stalked sessile form (trophont), which consists of an inverted bell-shaped cell body (zooid) and a slender stalk attaching the zooid to a substrate. Having circular cilia bands around the oral part, the stalkless zooid of Vorticella can serve as a model system for microorganism swimming. Here we present how the stalkess trophont zooid of Vorticella swims in two-dimensional confined geometries which are similar to the Hele-Shaw cell. Having harvested stalkless Vorticella zooids, we observed their swimming in water between two glass surfaces using video microscopy. Based on measured swimming trajectories and distributions of zooid orientation and swimming velocity, we analyzed how Vorticella's swimming mobility was influenced by the geometry constraints. Supported by First Award grant from Nebraska EPSCoR.

  14. Diffusion in quantum geometry

    NASA Astrophysics Data System (ADS)

    Calcagni, Gianluca

    2012-08-01

    The change of the effective dimension of spacetime with the probed scale is a universal phenomenon shared by independent models of quantum gravity. Using tools of probability theory and multifractal geometry, we show how dimensional flow is controlled by a multiscale fractional diffusion equation, and physically interpreted as a composite stochastic process. The simplest example is a fractional telegraph process, describing quantum spacetimes with a spectral dimension equal to 2 in the ultraviolet and monotonically rising to 4 towards the infrared. The general profile of the spectral dimension of the recently introduced multifractional spaces is constructed for the first time.

  15. Geometrie verstehen: statisch - kinematisch

    NASA Astrophysics Data System (ADS)

    Kroll, Ekkehard

    Dem Allgemeinen steht begrifflich das Besondere gegenüber. In diesem Sinne sind allgemeine Überlegungen zum Verstehen von Mathematik zu ergänzen durch Untersuchungen hinsichtlich des Verstehens der einzelnen mathematischen Disziplinen, insbesondere der Geometrie. Hier haben viele Schülerinnen und Schüler Probleme. Diese rühren hauptsächlich daher, dass eine fertige geometrische Konstruktion in ihrer statischen Präsentation auf Papier nicht mehr die einzelnen Konstruktionsschritte erkennen lässt; zum Nachvollzug müssen sie daher ergänzend in einer Konstruktionsbeschreibung festgehalten werden.

  16. Graded geometry and Poisson reduction

    SciTech Connect

    Cattaneo, A. S.; Zambon, M.

    2009-02-02

    The main result extends the Marsden-Ratiu reduction theorem in Poisson geometry, and is proven by means of graded geometry. In this note we provide the background material about graded geometry necessary for the proof. Further, we provide an alternative algebraic proof for the main result.

  17. Computer-Aided Geometry Modeling

    NASA Technical Reports Server (NTRS)

    Shoosmith, J. N. (Compiler); Fulton, R. E. (Compiler)

    1984-01-01

    Techniques in computer-aided geometry modeling and their application are addressed. Mathematical modeling, solid geometry models, management of geometric data, development of geometry standards, and interactive and graphic procedures are discussed. The applications include aeronautical and aerospace structures design, fluid flow modeling, and gas turbine design.

  18. Teaching of Geometry in Bulgaria

    ERIC Educational Resources Information Center

    Bankov, Kiril

    2013-01-01

    Geometry plays an important role in the school mathematics curriculum all around the world. Teaching of geometry varies a lot (Hoyls, Foxman, & Kuchemann, 2001). Many countries revise the objectives, the content, and the approaches to the geometry in school. Studies of the processes show that there are not common trends of these changes…

  19. Geometry dependence of stellarator turbulence

    NASA Astrophysics Data System (ADS)

    Mynick, H. E.; Xanthopoulos, P.; Boozer, A. H.

    2009-11-01

    Using the nonlinear gyrokinetic code package GENE/GIST [F. Jenko, W. Dorland, M. Kotschenreuther, and B. N. Rogers, Phys. Plasmas 7, 1904 (2000); P. Xanthopoulos, W. A. Cooper, F. Jenko, Yu. Turkin, A. Runov, and J. Geiger, Phys. Plasmas 16, 082303 (2009)], we study the turbulent transport in a broad family of stellarator designs, to understand the geometry dependence of the microturbulence. By using a set of flux tubes on a given flux surface, we construct a picture of the two-dimensional structure of the microturbulence over that surface and relate this to relevant geometric quantities, such as the curvature, local shear, and effective potential in the Schrödinger-like equation governing linear drift modes.

  20. Geometry of minisuperspace in examples

    NASA Astrophysics Data System (ADS)

    Kerbrat, Yvan; Kerbrat-Lunc, Hélène; Śniatycki, Jȩdrzej

    1992-04-01

    Minisuperspace, interpreted as the configuration space for homogeneous cosmologies, has a naturally defined pseudo-Riemannian metric (supermetric) such that solutions of the ADM equations correspond to geodesics of the supermetric parametrized by arc-length (supertime). The supermetric is used to analyse the geometry of minisuperspace. In particular, if the supermetric is incomplete, its prolongations relate different components of minisuperspace. For Robertson-Walker universes with a homogeneous scalar field there exists a C1 prolongation of supermetric relating the positive and the negative curvature models. If the potential vanishes, then this prolongation is C∞. There is no prolongation of supermetric through generic boundary points between the Bianchi VIII and Bianchi IX models.

  1. Enzymatic reactions in confined environments

    NASA Astrophysics Data System (ADS)

    Küchler, Andreas; Yoshimoto, Makoto; Luginbühl, Sandra; Mavelli, Fabio; Walde, Peter

    2016-05-01

    Within each biological cell, surface- and volume-confined enzymes control a highly complex network of chemical reactions. These reactions are efficient, timely, and spatially defined. Efforts to transfer such appealing features to in vitro systems have led to several successful examples of chemical reactions catalysed by isolated and immobilized enzymes. In most cases, these enzymes are either bound or adsorbed to an insoluble support, physically trapped in a macromolecular network, or encapsulated within compartments. Advanced applications of enzymatic cascade reactions with immobilized enzymes include enzymatic fuel cells and enzymatic nanoreactors, both for in vitro and possible in vivo applications. In this Review, we discuss some of the general principles of enzymatic reactions confined on surfaces, at interfaces, and inside small volumes. We also highlight the similarities and differences between the in vivo and in vitro cases and attempt to critically evaluate some of the necessary future steps to improve our fundamental understanding of these systems.

  2. Theory of rheology in confinement

    NASA Astrophysics Data System (ADS)

    Aerov, Artem A.; Krüger, Matthias

    2015-10-01

    The viscosity of fluids is generally understood in terms of kinetic mechanisms, i.e., particle collisions, or thermodynamic ones as imposed through structural distortions upon, e.g., applying shear. Often the latter are more relevant, which allows a simpler theoretical description, and, e.g., (damped) Brownian particles can be considered good fluid model systems. We formulate a general theoretical approach for rheology in confinement, based on microscopic equations of motion and classical density functional theory. Specifically, we discuss the viscosity for the case of two parallel walls in relative motion as a function of the wall-to-wall distance, analyzing its relation to the slip length found for a single wall. The previously observed [A. A. Aerov and M. Krüger, J. Chem. Phys. 140, 094701 (2014)., 10.1063/1.4866450] deficiency of inhomogeneous (unphysical) stresses under naive application of shear in confinement is healed when hydrodynamic interactions are included.

  3. Theory of rheology in confinement.

    PubMed

    Aerov, Artem A; Krüger, Matthias

    2015-10-01

    The viscosity of fluids is generally understood in terms of kinetic mechanisms, i.e., particle collisions, or thermodynamic ones as imposed through structural distortions upon, e.g., applying shear. Often the latter are more relevant, which allows a simpler theoretical description, and, e.g., (damped) Brownian particles can be considered good fluid model systems. We formulate a general theoretical approach for rheology in confinement, based on microscopic equations of motion and classical density functional theory. Specifically, we discuss the viscosity for the case of two parallel walls in relative motion as a function of the wall-to-wall distance, analyzing its relation to the slip length found for a single wall. The previously observed [A. A. Aerov and M. Krüger, J. Chem. Phys. 140, 094701 (2014).] deficiency of inhomogeneous (unphysical) stresses under naive application of shear in confinement is healed when hydrodynamic interactions are included.

  4. Enzymatic reactions in confined environments.

    PubMed

    Küchler, Andreas; Yoshimoto, Makoto; Luginbühl, Sandra; Mavelli, Fabio; Walde, Peter

    2016-05-05

    Within each biological cell, surface- and volume-confined enzymes control a highly complex network of chemical reactions. These reactions are efficient, timely, and spatially defined. Efforts to transfer such appealing features to in vitro systems have led to several successful examples of chemical reactions catalysed by isolated and immobilized enzymes. In most cases, these enzymes are either bound or adsorbed to an insoluble support, physically trapped in a macromolecular network, or encapsulated within compartments. Advanced applications of enzymatic cascade reactions with immobilized enzymes include enzymatic fuel cells and enzymatic nanoreactors, both for in vitro and possible in vivo applications. In this Review, we discuss some of the general principles of enzymatic reactions confined on surfaces, at interfaces, and inside small volumes. We also highlight the similarities and differences between the in vivo and in vitro cases and attempt to critically evaluate some of the necessary future steps to improve our fundamental understanding of these systems.

  5. Core geometry in perspective

    PubMed Central

    Dillon, Moira R.; Spelke, Elizabeth S.

    2015-01-01

    Research on animals, infants, children, and adults provides evidence that distinct cognitive systems underlie navigation and object recognition. Here we examine whether and how these systems interact when children interpret 2D edge-based perspectival line drawings of scenes and objects. Such drawings serve as symbols early in development, and they preserve scene and object geometry from canonical points of view. Young children show limits when using geometry both in non-symbolic tasks and in symbolic map tasks that present 3D contexts from unusual, unfamiliar points of view. When presented with the familiar viewpoints in perspectival line drawings, however, do children engage more integrated geometric representations? In three experiments, children successfully interpreted line drawings with respect to their depicted scene or object. Nevertheless, children recruited distinct processes when navigating based on the information in these drawings, and these processes depended on the context in which the drawings were presented. These results suggest that children are flexible but limited in using geometric information to form integrated representations of scenes and objects, even when interpreting spatial symbols that are highly familiar and faithful renditions of the visual world. PMID:25441089

  6. Ion beam inertial confinement target

    DOEpatents

    Bangerter, Roger O.; Meeker, Donald J.

    1985-01-01

    A target for implosion by ion beams composed of a spherical shell of frozen DT surrounded by a low-density, low-Z pusher shell seeded with high-Z material, and a high-density tamper shell. The target has various applications in the inertial confinement technology. For certain applications, if desired, a low-density absorber shell may be positioned intermediate the pusher and tamper shells.

  7. Inertial-confinement-fusion targets

    SciTech Connect

    Hendricks, C.D.

    1981-11-16

    Inertial confinement fusion (ICF) targets are made as simple flat discs, as hollow shells or as complicated multilayer structures. Many techniques have been devised for producing the targets. Glass and metal shells are made by using drop and bubble techniques. Solid hydrogen shells are also produced by adapting old methods to the solution of modern problems. Some of these techniques, problems and solutions are discussed. In addition, the applications of many of the techniques to fabrication of ICF targets is presented.

  8. Towards assessing the violence of reaction during cookoff of confined energetic materials

    SciTech Connect

    Baer, M.R.; Kipp, M.E.; Schmitt, R.G.; Hobbs, M.L.

    1996-11-01

    An analysis of post-ignition events in a variable confinement cookoff test (VCCT) geometry is presented aimed toward predicting the level of violence during cookoff of confined thermally-degraded energetic materials. This study focuses on the dynamic events following thermal initiation whereby accelerated combustion interacts with confinement. Numerical simulations, based on a model of reactive multiphase mixtures, indicate that the response of energetic material is highly dependent upon thermal/mechanical damage states prior to ignition. These damaged states affect the rate of pressurization, dynamic compaction behavior and subsequent growth to detonation. Variations of the specific surface area and porosity produced by decomposition of the energetic material causes different responses ranging from pressure burst to detonation. Calculated stress histories are used in estimating breakup of the VCCT confinement based on Grady-Kipp fragmentation theory.

  9. Differential Geometry Based Multiscale Models

    PubMed Central

    Wei, Guo-Wei

    2010-01-01

    Large chemical and biological systems such as fuel cells, ion channels, molecular motors, and viruses are of great importance to the scientific community and public health. Typically, these complex systems in conjunction with their aquatic environment pose a fabulous challenge to theoretical description, simulation, and prediction. In this work, we propose a differential geometry based multiscale paradigm to model complex macromolecular systems, and to put macroscopic and microscopic descriptions on an equal footing. In our approach, the differential geometry theory of surfaces and geometric measure theory are employed as a natural means to couple the macroscopic continuum mechanical description of the aquatic environment with the microscopic discrete atom-istic description of the macromolecule. Multiscale free energy functionals, or multiscale action functionals are constructed as a unified framework to derive the governing equations for the dynamics of different scales and different descriptions. Two types of aqueous macromolecular complexes, ones that are near equilibrium and others that are far from equilibrium, are considered in our formulations. We show that generalized Navier–Stokes equations for the fluid dynamics, generalized Poisson equations or generalized Poisson–Boltzmann equations for electrostatic interactions, and Newton's equation for the molecular dynamics can be derived by the least action principle. These equations are coupled through the continuum-discrete interface whose dynamics is governed by potential driven geometric flows. Comparison is given to classical descriptions of the fluid and electrostatic interactions without geometric flow based micro-macro interfaces. The detailed balance of forces is emphasized in the present work. We further extend the proposed multiscale paradigm to micro-macro analysis of electrohydrodynamics, electrophoresis, fuel cells, and ion channels. We derive generalized Poisson–Nernst–Planck equations that

  10. Differential geometry based multiscale models.

    PubMed

    Wei, Guo-Wei

    2010-08-01

    Large chemical and biological systems such as fuel cells, ion channels, molecular motors, and viruses are of great importance to the scientific community and public health. Typically, these complex systems in conjunction with their aquatic environment pose a fabulous challenge to theoretical description, simulation, and prediction. In this work, we propose a differential geometry based multiscale paradigm to model complex macromolecular systems, and to put macroscopic and microscopic descriptions on an equal footing. In our approach, the differential geometry theory of surfaces and geometric measure theory are employed as a natural means to couple the macroscopic continuum mechanical description of the aquatic environment with the microscopic discrete atomistic description of the macromolecule. Multiscale free energy functionals, or multiscale action functionals are constructed as a unified framework to derive the governing equations for the dynamics of different scales and different descriptions. Two types of aqueous macromolecular complexes, ones that are near equilibrium and others that are far from equilibrium, are considered in our formulations. We show that generalized Navier-Stokes equations for the fluid dynamics, generalized Poisson equations or generalized Poisson-Boltzmann equations for electrostatic interactions, and Newton's equation for the molecular dynamics can be derived by the least action principle. These equations are coupled through the continuum-discrete interface whose dynamics is governed by potential driven geometric flows. Comparison is given to classical descriptions of the fluid and electrostatic interactions without geometric flow based micro-macro interfaces. The detailed balance of forces is emphasized in the present work. We further extend the proposed multiscale paradigm to micro-macro analysis of electrohydrodynamics, electrophoresis, fuel cells, and ion channels. We derive generalized Poisson-Nernst-Planck equations that are

  11. Holographic confinement in inhomogeneous backgrounds

    NASA Astrophysics Data System (ADS)

    Marolf, Donald; Wien, Jason

    2016-08-01

    As noted by Witten, compactifying a d-dimensional holographic CFT on an S 1 gives a class of ( d - 1)-dimensional confining theories with gravity duals. The proto-typical bulk solution dual to the ground state is a double Wick rotation of the AdS d+1 Schwarzschild black hole known as the AdS soliton. We generalize such examples by allowing slow variations in the size of the S 1, and thus in the confinement scale. Coefficients governing the second order response of the system are computed for 3 ≤ d ≤ 8 using a derivative expansion closely related to the fluid-gravity correspondence. The primary physical results are that i) gauge-theory flux tubes tend to align orthogonal to gradients and along the eigenvector of the Hessian with the lowest eigenvalue, ii) flux tubes aligned orthogonal to gradients are attracted to gradients for d ≤ 6 but repelled by gradients for d ≥ 7, iii) flux tubes are repelled by regions where the second derivative along the tube is large and positive but are attracted to regions where the eigenvalues of the Hessian are large and positive in directions orthogonal to the tube, and iv) for d > 3, inhomogeneities act to raise the total energy of the confining vacuum above its zeroth order value.

  12. Sheared magnetofluids and Bernoulli confinement

    NASA Astrophysics Data System (ADS)

    Quevado, H. J.; Bengtson, Roger; Mahajan, S. M.; Valanju, P. M.

    2001-10-01

    New magnetofluid states that differ qualitatively from those accessible to either neutral fluids or to conventional MHD plasmas have been predited theoretically. They are predicted to appear if plasmas with strong velocity shear flows (with large initial values of both magnetic and magnetofluid helicity) are created and allowed to relax. The dynamic invariance of these two helicities will force the plasma to self-organize and relax to a long-lived quasi equilibrium state away from thermal equilibrium. The investigation of these states bears critically upon basic plasma confinement and heating issues in both natural and laboratory plasmas. We have built a magnetic mirror device designed to create and investigate these theoretically predicted pressure-confining magnetofluid states. The primary experimental challenge is to create an initial plasma (with significant flows and currents) which is relatively isolated from walls and embedded in a modest magnetic external field. Our machine has a central bias rod to create a radial electric field for generating fast plasma flow, a large mirror ratio for good centrifugal confinement, and magnetic, Langmuir, and Mach probes to measure the evolution of plasma rotation profiles and fluctuations. Initial results will be presented demonstrating plasma rotation.

  13. Nanoparticle Order through Entropic Confinement

    NASA Astrophysics Data System (ADS)

    Zhang, Ren; Lee, Bongjoon; Stafford, Christopher; Douglas, Jack; Bockstaller, Michael; Karim, Alamgir

    As has been addressed in colloidal science, visual order transitions can be achieved with entropy contributions alone. Herein, entropy-driven ordering of nanoparticle (NP) structures is generated where entropy increase and visual order are achieved simultaneously. We study an ``athermal'' NP-polymer blends where NPs are densely grafted with polymer brush of the same chemical composition as the polymer matrix. Visual order of the NPs is induced by geometrically confining the thin film blends with meso-scale topographic patterns. When the residual layer thickness of the patterned blend films approaches the nanoparticle dimension, exclusive segregation of NPs to less confining imprinted mesa region occurs. This preferential segregation of NPs, defined by partition coefficient K = 0, is attributed to purely entropic penalty, where K denotes the particle density ratio at highly confined residual layer to that at mesa region. We further demonstrate K is fully tunable and even invertible with increasing matrix chain dimension. The associated entropic free energy change (ΔF = - ln K) is calculated to explain NP segregation preference. Accordingly, variation of residual layer thickness and polymer matrix molecule size can both affect NP distribution among patterned thick and thin regions.

  14. Motion, relaxation dynamics, and diffusion processes in two-dimensional colloidal crystals confined between walls.

    PubMed

    Wilms, Dorothea; Virnau, Peter; Snook, Ian K; Binder, Kurt

    2012-11-01

    The dynamical behavior of single-component two-dimensional colloidal crystals confined in a slit geometry is studied by Langevin dynamics simulation of a simple model. The colloids are modeled as pointlike particles, interacting with the repulsive part of the Lennard-Jones potential, and the fluid molecules in the colloidal suspension are not explicitly considered. Considering a crystalline strip of triangular lattice structure with n=30 rows, the (one-dimensional) walls confining the strip are chosen as two rigidly fixed crystalline rows at each side, commensurate with the lattice structure and, thus, stabilizing long-range order. The case when the spacing between the walls is incommensurate with the ideal triangular lattice is also studied, where (due to a transition in the number of rows, n → n-1) the confined crystal is incommensurate with the confining boundaries, and a soliton staircase forms along the walls. It is shown that mean-square displacements (MSDs) of particles as a function of time show an overshoot and then saturate at a horizontal plateau in the commensurate case, the value of the plateau being largest in the center of the strip. Conversely, when solitons are present, MSDs are largest in the rows containing the solitons, and all MSDs do not settle down at well-defined plateaus in the direction parallel to the boundaries, due to the lack of positional long-range order in ideal two-dimensional crystals. The MSDs of the solitons (which can be treated like quasiparticles at very low temperature) have also been studied and their dynamics are found to be about an order of magnitude slower than that of the colloidal particles themselves. Finally, transport of individual colloidal particles by diffusion processes is studied: both standard vacancy-interstitial pair formation and cooperative ring rotation processes are identified. These processes require thermal activation, with activation energies of the order of 10T(m) (T(m) being the melting

  15. Influence of Geometry and Flow Variation on Jet Mixing and NO Formation in a Model Staged Combustor Mixer with Eight Orifices

    NASA Technical Reports Server (NTRS)

    Samuelsen, G. S.; Sowa, W. A.; Hatch, M. S.

    1996-01-01

    A series of non-reacting parametric experiments was conducted to investigate the effect of geometric and flow variations on mixing of cold jets in an axis-symmetric, heated cross flow. The confined, cylindrical geometries tested represent the quick mix region of a Rich-Burn/Quick-Mix/Lean-Burn (RQL) combustor. The experiments show that orifice geometry and jet to mainstream momentum-flux ratio significantly impact the mixing characteristic of jets in a cylindrical cross stream. A computational code was used to extrapolate the results of the non-reacting experiments to reacting conditions in order to examine the nitric oxide (NO) formation potential of the configurations examined. The results show that the rate of NO formation is highest immediately downstream of the injection plane. For a given momentum-flux ratio, the orifice geometry that mixes effectively in both the immediate vicinity of the injection plane, and in the wall regions at downstream locations, has the potential to produce the lowest NO emissions. The results suggest that further study may not necessarily lead to a universal guideline for designing a low NO mixer. Instead, an assessment of each application may be required to determine the optimum combination of momentum-flux ratio and orifice geometry to minimize NO formation. Experiments at reacting conditions are needed to verify the present results.

  16. Wall depletion length of a channel-confined polymer

    NASA Astrophysics Data System (ADS)

    Cheong, Guo Kang; Li, Xiaolan; Dorfman, Kevin D.

    2017-02-01

    Numerous experiments have taken advantage of DNA as a model system to test theories for a channel-confined polymer. A tacit assumption in analyzing these data is the existence of a well-defined depletion length characterizing DNA-wall interactions such that the experimental system (a polyelectrolyte in a channel with charged walls) can be mapped to the theoretical model (a neutral polymer with hard walls). We test this assumption using pruned-enriched Rosenbluth method (PERM) simulations of a DNA-like semiflexible polymer confined in a tube. The polymer-wall interactions are modeled by augmenting a hard wall interaction with an exponentially decaying, repulsive soft potential. The free energy, mean span, and variance in the mean span obtained in the presence of a soft wall potential are compared to equivalent simulations in the absence of the soft wall potential to determine the depletion length. We find that the mean span and variance about the mean span have the same depletion length for all soft potentials we tested. In contrast, the depletion length for the confinement free energy approaches that for the mean span only when depletion length no longer depends on channel size. The results have implications for the interpretation of DNA confinement experiments under low ionic strengths.

  17. Thickness of the Mississippi River Valley confining unit, eastern Arkansas

    USGS Publications Warehouse

    Gonthier, Gerard J.; Mahon, Gary L.

    1993-01-01

    Concern arose in the late 1980s over the vulnerability of the Mississippi Valley alluvial aquifer to contamination from potential surface sources related to pesticide or fertilizer use, industrial activity, landfills, or livestock operations. In 1990 a study was begun to locate areas in Arkansas where the groundwater flow system is susceptible to contamination by surface contaminants. As a part of that effort, the thickness of the clay confining unit overlying the alluvial aquifer in eastern Arkansas was mapped. The study area included all or parts of 27 counties in eastern Arkansas that are underlain by the alluvial aquifer and its overlying confining unit. A database of well attributes was compiled based on data from driller's logs and from published data and stored in computer files. A confining-unit thickness map was created from the driller's-log database using geographic information systems technology. A computer program was then used to contour the data. Where the confining unit is present, it ranges in thickness from 0 feet in many locations in the study area to 140 feet in northeastern Greene County and can vary substantially over short distances. Although general trends in the thickness of the confining unit are apparent, the thickness has great spatial variability. An apparent relation exists between thickness of the confining unit and spatial variability in thickness. In areas where the thickness of the confining unit is 40 feet or less, such as in Clay, eastern Craighead, northwestern Mississippi, and Woodruff Counties, thickness of the unit tends robe more uniform than in areas where the thickness of the unit generally exceeds 40 feet, such as in Arkansas, Lonoke, and Prairie Counties. At some sites the confining unit is very thick compared to its thickness in the immediate surrounding area. Locations of abandoned Mississippi River meander channels generally coincide with location of locally thick confining unit. Deposition of the confining unit onto

  18. Quantum chromodynamics near the confinement limit

    SciTech Connect

    Quigg, C.

    1985-09-01

    These nine lectures deal at an elementary level with the strong interaction between quarks and its implications for the structure of hadrons. Quarkonium systems are studied as a means for measuring the interquark interaction. This is presumably (part of) the answer a solution to QCD must yield, if it is indeed the correct theory of the strong interactions. Some elements of QCD are reviewed, and metaphors for QCD as a confining theory are introduced. The 1/N expansion is summarized as a way of guessing the consequences of QCD for hadron physics. Lattice gauge theory is developed as a means for going beyond perturbation theory in the solution of QCD. The correspondence between statistical mechanics, quantum mechanics, and field theory is made, and simple spin systems are formulated on the lattice. The lattice analog of local gauge invariance is developed, and analytic methods for solving lattice gauge theory are considered. The strong-coupling expansion indicates the existence of a confining phase, and the renormalization group provides a means for recovering the consequences of continuum field theory. Finally, Monte Carlo simulations of lattice theories give evidence for the phase structure of gauge theories, yield an estimate for the string tension characterizing the interquark force, and provide an approximate description of the quarkonium potential in encouraging good agreement with what is known from experiment.

  19. First-order Dyson coordinates and geometry.

    PubMed

    Hermes, Matthew R; Hirata, So

    2013-08-15

    The mathematical constructs of the Dyson coordinates and geometry are introduced. The former are a unitary transformation of the normal coordinates and the anharmonic vibrational counterpart of the Dyson orbitals in electronic structure theory. The first-order Dyson coordinates bring the sums of the harmonic force constants and their first-order diagrammatic perturbation corrections (the first-order Dyson self-energy) to a diagonal form. The first-order Dyson geometry has no counterpart in electronic structure theory. It is the point on the potential energy surface at which the sums of the energy gradients and their first-order diagrammatic perturbation corrections vanish. It agrees with the vibrationally averaged geometry of vibrational self-consistent field (VSCF) theory in the bulk limit. These constructs provide a unified view of the relationship of VSCF and its diagrammatically size-consistent modifications as well as the self-consistent phonon method widely used in solid-state physics.

  20. Confinement-Induced Supercriticality and Phase Equilibria of Hydrocarbons in Nanopores.

    PubMed

    Luo, Sheng; Lutkenhaus, Jodie L; Nasrabadi, Hadi

    2016-11-08

    For over a century, the phase behavior of bulk fluids has been described as PVT (pressure-volume-temperature) three-dimensional properties, but it has become increasingly clear that the liquid-vapor phase behavior in confined geometries is significantly altered from the bulk. Efforts have been devoted to accessing confined phase transitions using sorption, molecular simulations, and theoretical methods. However, a comprehensive picture of PVT relationships for confined hydrocarbons remains uncertain. Herein, we introduce d (confining pore diameter) as a fourth dimension, and we present PVT-d behavior of confined fluids in nanopores. For the first time, a T-d phase diagram is presented for n-hexane, n-octane, and n-decane under multiple confinement scales (37.9, 14.8, 9.8, 6.0, 4.1, 3.3, and 2.2 nm cylindrical pore diameter) using experimental differential scanning calorimetry and PVT-d equation of state theory at atmospheric pressure. As pore diameter decreases from 37.9 to 4.1 nm, the bubble point increases by as much as 15 K above bulk, until we observe behavior consistent with a supercritical state, pointing to confinement-induced supercriticality. Remarkably, experimental and theoretical findings overlap very well, showing that this approach effectively captures the phase boundaries between the liquid, vapor, and supercritical fluid regions. The model and completed EOS are additionally extended to calculation of isothermal capillary adsorption, and its validity is discussed.

  1. Noncommutative geometry of Zitterbewegung

    NASA Astrophysics Data System (ADS)

    Eckstein, Michał; Franco, Nicolas; Miller, Tomasz

    2017-03-01

    Drawing from the advanced mathematics of noncommutative geometry, we model a "classical" Dirac fermion propagating in a curved spacetime. We demonstrate that the inherent causal structure of the model encodes the possibility of Zitterbewegung—the "trembling motion" of the fermion. We recover the well-known frequency of Zitterbewegung as the highest possible speed of change in the fermion's "internal space." Furthermore, we show that the bound does not change in the presence of an external electromagnetic field and derive its explicit analogue when the mass parameter is promoted to a Yukawa field. We explain the universal character of the model and discuss a table-top experiment in the domain of quantum simulation to test its predictions.

  2. Critique of information geometry

    SciTech Connect

    Skilling, John

    2014-12-05

    As applied to probability, information geometry fails because probability distributions do not form a metric space. Probability theory rests on a compelling foundation of elementary symmetries, which also support information (aka minus entropy, Kullback-Leibler) H(p;q) as the unique measure of divergence from source probability distribution q to destination p. Because the only compatible connective H is from≠to asymmetric, H(p;q)≠H(q;p), there can be no compatible geometrical distance (which would necessarily be from=to symmetric). Hence there is no distance relationship compatible with the structure of probability theory. Metrics g and densities sqrt(det(g)) interpreted as prior probabilities follow from the definition of distance, and must fail likewise. Various metrics and corresponding priors have been proposed, Fisher's being the most popular, but all must behave unacceptably. This is illustrated with simple counter-examples.

  3. Classical and revival time periods of confined harmonic oscillator

    NASA Astrophysics Data System (ADS)

    Ghosh, P.; Ghosh, S.; Bera, N.

    2015-02-01

    We have used perturbation theory to compute energy eigenvalues, classical and the revival time periods for a one-dimensional harmonic oscillator confined in a box. First we have considered a simple harmonic oscillator as the unperturbed problem and boundary as perturbation. In next case, free particle in a box is considered as unperturbed problem that has been perturbed by a parabolic potential. We have used Fourier Grid Hamiltonian method to estimate classical and revival time period for the confined harmonic oscillator, which crosses smoothly from free particle in a box to a simple harmonic oscillator.

  4. Perfect Abelian dominance of confinement in mesons and baryons in SU(3) lattice QCD

    NASA Astrophysics Data System (ADS)

    Sakumichi, Naoyuki; Suganuma, Hideo

    2016-11-01

    For a long time, the quark confinement mechanism has been one of the most difficult problems in theoretical physics. In particular, there is no clear correspondence between the confinement and non-Abelian nature of QCD. We study the static interquark potential and its Abelian projection in both mesons and baryons in the maximally Abelian (MA) gauge in SU(3) quenched lattice QCD. Remarkably, we find that the quark confining force in QCD can be perfectly described only with Abelian variables in theMAgauge, which we call "perfect Abelian dominance" of the quark confinement.

  5. Confinement Driven by Scalar Field in 4d Non Abelian Gauge Theories

    SciTech Connect

    Chabab, Mohamed

    2007-01-12

    We review some of the most recent work on confinement in 4d gauge theories with a massive scalar field (dilaton). Emphasis is put on the derivation of confining analytical solutions to the Coulomb problem versus dilaton effective couplings to gauge terms. It is shown that these effective theories can be relevant to model quark confinement and may shed some light on confinement mechanism. Moreover, the study of interquark potential, derived from Dick Model, in the heavy meson sector proves that phenomenological investigation of tmechanism is more than justified and deserves more efforts.

  6. The effect of boundary adaptivity on hexagonal ordering and bistability in circularly confined quasi hard discs.

    PubMed

    Williams, Ian; Oğuz, Erdal C; Jack, Robert L; Bartlett, Paul; Löwen, Hartmut; Royall, C Patrick

    2014-03-14

    The behaviour of materials under spatial confinement is sensitively dependent on the nature of the confining boundaries. In two dimensions, confinement within a hard circular boundary inhibits the hexagonal ordering observed in bulk systems at high density. Using colloidal experiments and Monte Carlo simulations, we investigate two model systems of quasi hard discs under circularly symmetric confinement. The first system employs an adaptive circular boundary, defined experimentally using holographic optical tweezers. We show that deformation of this boundary allows, and indeed is required for, hexagonal ordering in the confined system. The second system employs a circularly symmetric optical potential to confine particles without a physical boundary. We show that, in the absence of a curved wall, near perfect hexagonal ordering is possible. We propose that the degree to which hexagonal ordering is suppressed by a curved boundary is determined by the "strictness" of that wall.

  7. Detection of confinement and jumps in single-molecule membrane trajectories

    NASA Astrophysics Data System (ADS)

    Meilhac, N.; Le Guyader, L.; Salomé, L.; Destainville, N.

    2006-01-01

    We propose a variant of the algorithm by [R. Simson, E. D. Sheets, and K. Jacobson, Biophys. 69, 989 (1995)]. Their algorithm was developed to detect transient confinement zones in experimental single-particle tracking trajectories of diffusing membrane proteins or lipids. We show that our algorithm is able to detect confinement in a wider class of confining potential shapes than that of Simson Furthermore, it enables to detect not only temporary confinement but also jumps between confinement zones. Jumps are predicted by membrane skeleton fence and picket models. In the case of experimental trajectories of μ -opioid receptors, which belong to the family of G-protein-coupled receptors involved in a signal transduction pathway, this algorithm confirms that confinement cannot be explained solely by rigid fences.

  8. Theory of Activated Relaxation in Nanoscale Confined Liquids

    NASA Astrophysics Data System (ADS)

    Mirigian, Stephen; Schweizer, Kenneth

    2014-03-01

    We extend the recently developed Elastically Cooperative Nonlinear Langevin Equation(ECNLE) theory of activated relaxation in supercooled liquids to treat the case of geometrically confined liquids. Generically, confinement of supercooled liquids leads to a speeding up of the dynamics(with a consequent depression of the glass transition temperature) extending on the order of tens of molecular diameters away from a free surface. At present, this behavior is not theoretically well understood. Our theory interprets the speed up in dynamics in terms of two coupled effects. First, a direct surface effect, extending two to three molecular diameters from a free surface, and related to a local rearrangement of molecules with a single cage. The second is a longer ranged ``confinement'' effect, extending tens of molecular diameters from a free surface and related to the long range elastic penalty necessary for a local rearrangement. The theory allows for the calculation of relaxation time and Tg profiles within a given geometry and first principles calculations of relevant length scales. Comparison to both dynamic and pseudo-thermodynamic measurements shows reasonable agreement to experiment with no adjustable parameters.

  9. Optimizing Stellarators for Energetic Particle Confinement using BEAMS3D

    NASA Astrophysics Data System (ADS)

    Bolgert, Peter; Drevlak, Michael; Lazerson, Sam; Gates, David; White, Roscoe

    2015-11-01

    Energetic particle (EP) loss has been called the ``Achilles heel of stellarators,'' (Helander, Rep. Prog. Phys. 77 087001 (2014)) and there is a great need for magnetic configurations with improved EP confinement. In this study we utilize a newly developed capability of the stellarator optimization code STELLOPT: the ability to optimize EP confinement via an interface with guiding center code BEAMS3D (McMillan et al., Plasma Phys. Control. Fusion 56, 095019 (2014)). Using this new tool, optimizations of the W7-X experiment and ARIES-CS reactor are performed where the EP loss fraction is one of many target functions to be minimized. In W7-X, we simulate the experimental NBI system using realistic beam geometry and beam deposition physics. The goal is to find configurations with improved neutral beam deposition and energetic particle confinement. These calculations are compared to previous studies of W7-X NBI deposition. In ARIES-CS, we launch 3.5 MeV alpha particles from a near-axis flux surface using a uniform grid in toroidal and poloidal angle. As these particles are born from D-T reactions, we consider an isotropic distribution in velocity space. This research is supported by DoE Contract Number DE-AC02-09CH11466.

  10. Nonlocal effects in a hybrid plasmonic waveguide for nanoscale confinement.

    PubMed

    Huang, Qiangsheng; Bao, Fanglin; He, Sailing

    2013-01-28

    The effect of nonlocal optical response is studied for a novel silicon hybrid plasmonic waveguide (HPW). Finite element method is used to implement the hydrodynamic model and the propagation mode is analyzed for a hybrid plasmonic waveguide of arbitrary cross section. The waveguide has an inverted metal nano-rib over a silicon-on-insulator (SOI) structure. An extremely small mode area of~10⁻⁶λ² is achieved together with several microns long propagation distance at the telecom wavelength of 1.55 μm. The figure of merit (FoM) is also improved in the same time, compared to the pervious hybrid plasmonic waveguide. We demonstrate the validity of our method by comparing our simulating results with some analytical results for a metal cylindrical waveguide and a metal slab waveguide in a wide wavelength range. For the HPW, we find that the nonlocal effects can give less loss and better confinement. In particular, we explore the influence of the radius of the rib's tip on the loss and the confinement. We show that the nonlocal effects give some new fundamental limitation on the confinement, leaving the mode area finite even for geometries with infinitely sharp tips.

  11. Universal behavior of hydrogels confined to narrow capillaries

    PubMed Central

    Li, Yang; Sarıyer, Ozan S.; Ramachandran, Arun; Panyukov, Sergey; Rubinstein, Michael; Kumacheva, Eugenia

    2015-01-01

    Flow of soft matter objects through one-dimensional environments is important in industrial, biological and biomedical systems. Establishing the underlying principles of the behavior of soft matter in confinement can shed light on its performance in many man-made and biological systems. Here, we report an experimental and theoretical study of translocation of micrometer-size hydrogels (microgels) through microfluidic channels with a diameter smaller than an unperturbed microgel size. For microgels with different dimensions and mechanical properties, under a range of applied pressures, we established the universal principles of microgel entrance and passage through microchannels with different geometries, as well as the reduction in microgel volume in confinement. We also show a non-monotonic change in the flow rate of liquid through the constrained microgel, governed by its progressive confinement. The experimental results were in agreement with the theory developed for non-linear biaxial deformation of unentangled polymer gels. Our work has implications for a broad range of phenomena, including occlusion of blood vessels by thrombi and needle-assisted hydrogel injection in tissue engineering. PMID:26596468

  12. Understanding nanorheology and surface forces of confined thin films

    NASA Astrophysics Data System (ADS)

    Huang, Jun; Yan, Bin; Faghihnejad, Ali; Xu, Haolan; Zeng, Hongbo

    2014-02-01

    Understanding the nanorheology and associated intermolecular/surface forces of fluids in confined geometries or porous media is of both fundamental and practical importance, providing significant insights into various applications such as lubrication and micro/nanoelectromechanical systems. In this work, we briefly reviewed the fundamentals of nanoreheolgy, advances in experimental techniques and theoretical simulation methods, as well as important progress in the nanorheology of confined thin films. The advent of advanced experimental techniques such as surface forces apparatus (SFA), X-ray surface forces apparatus (XSFA) and atomic force microscope (AFM) and computational methods such as molecular dynamics simulations provides powerful tools to study a wide range of rheological phenomena at molecular level and nano scale. One of the most challenging issues unresolved is to elucidate the relationship between the rheological properties and structural evolution of the confined fluid films and particles suspensions. Some of the emerging research areas in the nanorheology field include, but are not limited to, the development of more advanced characterization techniques, design of multifunctional rheological fluids, bio-related nanorheology, and polymer brushes.

  13. Universal behavior of hydrogels confined to narrow capillaries

    NASA Astrophysics Data System (ADS)

    Li, Yang; Sarıyer, Ozan S.; Ramachandran, Arun; Panyukov, Sergey; Rubinstein, Michael; Kumacheva, Eugenia

    2015-11-01

    Flow of soft matter objects through one-dimensional environments is important in industrial, biological and biomedical systems. Establishing the underlying principles of the behavior of soft matter in confinement can shed light on its performance in many man-made and biological systems. Here, we report an experimental and theoretical study of translocation of micrometer-size hydrogels (microgels) through microfluidic channels with a diameter smaller than an unperturbed microgel size. For microgels with different dimensions and mechanical properties, under a range of applied pressures, we established the universal principles of microgel entrance and passage through microchannels with different geometries, as well as the reduction in microgel volume in confinement. We also show a non-monotonic change in the flow rate of liquid through the constrained microgel, governed by its progressive confinement. The experimental results were in agreement with the theory developed for non-linear biaxial deformation of unentangled polymer gels. Our work has implications for a broad range of phenomena, including occlusion of blood vessels by thrombi and needle-assisted hydrogel injection in tissue engineering.

  14. Quantum confined Stark effect in Gaussian quantum wells: A tight-binding study

    SciTech Connect

    Ramírez-Morales, A.; Martínez-Orozco, J. C.; Rodríguez-Vargas, I.

    2014-05-15

    The main characteristics of the quantum confined Stark effect (QCSE) are studied theoretically in quantum wells of Gaussian profile. The semi-empirical tight-binding model and the Green function formalism are applied in the numerical calculations. A comparison of the QCSE in quantum wells with different kinds of confining potential is presented.

  15. DEVELOPMENT OF A METHODOLOGY FOR REGIONAL EVALUATION OF CONFINING BED INTEGRITY

    EPA Science Inventory

    For safe underground injection of liquid waste, confining formations must be thick, extensive, and have low permeability. Recognition of faults that extend from the potential injection zone to underground sources of drinking water is critical for evaluation of confining-bed integ...

  16. Using off-diagonal confinement as a cooling method

    SciTech Connect

    Rousseau, V. G.; Hettiarachchilage, K.; Jarrell, M.; Moreno, J.; Sheehy, D. E.

    2010-12-15

    In a recent letter [Phys. Rev. Lett. 104, 167201 (2010)] we proposed a new confining method for ultracold atoms on optical lattices, which is based on off-diagonal confinement (ODC). This method was shown to have distinct advantages over the conventional diagonal confinement (DC), which makes use of a trapping potential, such as the existence of pure Mott phases and highly populated condensates. In this manuscript we show that the ODC method can also lead to lower temperatures than the DC method for a wide range of control parameters. Using exact diagonalization we determine this range of parameters for the hard-core case and then we extend our results to the soft-core case by performing quantum Monte Carlo (QMC) simulations for both DC and ODC systems at fixed temperature and analyzing the corresponding entropies. We also propose a method for measuring the entropy in QMC simulations.

  17. Subwavelength confined terahertz waves on planar waveguides using metallic gratings.

    PubMed

    You, Borwen; Lu, Ja-Yu; Chang, Wei-Lun; Yu, Chin-Ping; Liu, Tze-An; Peng, Jin-Long

    2013-03-11

    A terahertz plasmonic waveguide is experimentally demonstrated using a plastic ribbon waveguide integrated with a diffraction metal grating to approach subwavelength-scaled confinement and long-distance delivery. Appropriately adjusting the metal-thickness and the periodical slit width of a grating greatly improves both guiding ability and field confinement in the hybrid waveguide structure. The measured lateral decay length of the bound terahertz surface waves on the hybrid waveguide can be reduced to less than λ/4 after propagating a waveguide of around 50mm-long in length. The subwavelength-confined field is potentially advantageous to biomolecular sensing or membrane detection because of the long interaction length between the THz field and analytes.

  18. Multiple reentrant glass transitions in confined hard-sphere glasses

    NASA Astrophysics Data System (ADS)

    Mandal, Suvendu; Lang, Simon; Gross, Markus; Oettel, Martin; Raabe, Dierk; Franosch, Thomas; Varnik, Fathollah

    2014-07-01

    Glass-forming liquids exhibit a rich phenomenology upon confinement. This is often related to the effects arising from wall-fluid interactions. Here we focus on the interesting limit where the separation of the confining walls becomes of the order of a few particle diameters. For a moderately polydisperse, densely packed hard-sphere fluid confined between two smooth hard walls, we show via event-driven molecular dynamics simulations the emergence of a multiple reentrant glass transition scenario upon a variation of the wall separation. Using thermodynamic relations, this reentrant phenomenon is shown to persist also under constant chemical potential. This allows straightforward experimental investigation and opens the way to a variety of applications in micro- and nanotechnology, where channel dimensions are comparable to the size of the contained particles. The results are in line with theoretical predictions obtained by a combination of density functional theory and the mode-coupling theory of the glass transition.

  19. Stepwise melting of a model glass former under confinement

    NASA Astrophysics Data System (ADS)

    Calvo, F.; Wales, D. J.

    2009-10-01

    The equilibrium thermodynamics of a binary Lennard-Jones model glass former are investigated using exchange Monte Carlo simulations, covering the crystalline and amorphous regions of configuration space in appropriate temperature ranges. We investigate both bulk and film mixtures, the latter being confined between noninteracting flat walls. Both the bulk and film systems exhibit a principal heat capacity peak at the melting point, but confinement leads to a significant depression in the melting temperature by about 25%. Microcanonical caloric curves, as well as analysis of the probability distributions of a bond-orientational order parameter, show that this transition has first-order character. However, the film system shows additional features at lower temperatures, which are interpreted in terms of localized partial melting, perpendicular to the confining walls and near the walls, with some increase in layering. This premelting is associated with local minima on the underlying potential energy surface that are not supported by the bulk system.

  20. Inertial-Electrostatic Confinement (IEC) Fusion for Space Propulsion

    NASA Technical Reports Server (NTRS)

    Nadler, Jon

    1999-01-01

    An Inertial-Electrostatic Confinement (IEC) device was assembled at the Marshall Space Flight Center (MSFC) Propulsion Research Center (PRC) to study the possibility of using EEC technology for deep space propulsion and power. Inertial-Electrostatic Confinement is capable of containing a nuclear fusion plasma in a series of virtual potential wells. These wells would substantially increase plasma confinement, possibly leading towards a high-gain, breakthrough fusion device. A one-foot in diameter IEC vessel was borrowed from the Fusion Studies Laboratory at the University of Illinois@Urbana-Champaign for the summer. This device was used in initial parameterization studies in order to design a larger, actively cooled device for permanent use at the PRC.

  1. Inertial-Electrostatic Confinement (IEC) Fusion For Space Propulsion

    NASA Technical Reports Server (NTRS)

    Nadler, Jon

    1999-01-01

    An Inertial-Electrostatic Confinement (IEC) device was assembled at the Marshall Space Flight Center (MSFC) Propulsion Research Center (PRC) to study the possibility of using IEC technology for deep space propulsion and power. Inertial-Electrostatic Confinement is capable of containing a nuclear fusion plasma in a series of virtual potential wells. These wells would substantially increase plasma confinement, possibly leading towards a high-gain, breakthrough fusion device. A one-foot in diameter IEC vessel was borrowed from the Fusion Studies Laboratory at the University of Illinois @ Urbana-Champaign for the summer. This device was used in initial parameterization studies in order to design a larger, actively cooled device for permanent use at the PRC.

  2. On the sigma-model of deformed special geometry

    NASA Astrophysics Data System (ADS)

    Lopes Cardoso, Gabriel; Véliz-Osorio, Alvaro

    2013-07-01

    We discuss the deformed sigma-model that arises when considering four-dimensional N=2 abelian vector multiplets in the presence of an arbitrary chiral background field. In addition, we allow for a class of deformations of special geometry by non-holomorphic terms. We analyze the geometry of the sigma-model in terms of intrinsic torsion classes. We show that, generically, the deformed geometry is non-Kähler. We illustrate our findings with an example. We also express the deformed sigma-model in terms of the Hesse potential that underlies the real formulation of special geometry.

  3. Color Confinement from Fluctuating Topology

    NASA Astrophysics Data System (ADS)

    Kharzeev, Dmitri E.

    QCD possesses a compact gauge group, and this implies a non-trivial topological structure of the vacuum. In this contribution to the Gribov-85 Memorial volume, we first discuss the origin of Gribov copies and their interpretation in terms of fluctuating topology in the QCD vacuum. We then describe the recent work with E. Levin that links the confinement of gluons and color screening to the fluctuating topology, and discuss implications for spin physics, high energy scattering, and the physics of quark-gluon plasma.

  4. Color confinement from fluctuating topology

    NASA Astrophysics Data System (ADS)

    Kharzeev, Dmitri E.

    2016-10-01

    QCD possesses a compact gauge group, and this implies a non-trivial topological structure of the vacuum. In this contribution to the Gribov-85 Memorial volume, we first discuss the origin of Gribov copies and their interpretation in terms of fluctuating topology in the QCD vacuum. We then describe the recent work with E. Levin that links the confinement of gluons and color screening to the fluctuating topology, and discuss implications for spin physics, high energy scattering, and the physics of quark-gluon plasma.

  5. Thermoelectricity in Confined Liquid Electrolytes.

    PubMed

    Dietzel, Mathias; Hardt, Steffen

    2016-06-03

    The electric field in an extended phase of a liquid electrolyte exposed to a temperature gradient is attributed to different thermophoretic mobilities of the ion species. As shown herein, such Soret-type ion thermodiffusion is not required to induce thermoelectricity even in the simplest electrolyte if it is confined between charged walls. The space charge of the electric double layer leads to selective ion diffusion driven by a temperature-dependent electrophoretic ion mobility, which-for narrow channels-may cause thermovoltages larger in magnitude than for the classical Soret equilibrium.

  6. Confined Space Imager (CSI) Software

    SciTech Connect

    Karelilz, David

    2013-07-03

    The software provides real-time image capture, enhancement, and display, and sensor control for the Confined Space Imager (CSI) sensor system The software captures images over a Cameralink connection and provides the following image enhancements: camera pixel to pixel non-uniformity correction, optical distortion correction, image registration and averaging, and illumination non-uniformity correction. The software communicates with the custom CSI hardware over USB to control sensor parameters and is capable of saving enhanced sensor images to an external USB drive. The software provides sensor control, image capture, enhancement, and display for the CSI sensor system. It is designed to work with the custom hardware.

  7. Electromelting of confined monolayer ice.

    PubMed

    Qiu, Hu; Guo, Wanlin

    2013-05-10

    In sharp contrast to the prevailing view that electric fields promote water freezing, here we show by molecular dynamics simulations that monolayer ice confined between two parallel plates can melt into liquid water under a perpendicularly applied electric field. The melting temperature of the monolayer ice decreases with the increasing strength of the external field due to the field-induced disruption of the water-wall interaction induced well-ordered network of the hydrogen bond. This electromelting process should add an important new ingredient to the physics of water.

  8. Generalized Kähler Geometry

    NASA Astrophysics Data System (ADS)

    Gualtieri, Marco

    2014-10-01

    Generalized Kähler geometry is the natural analogue of Kähler geometry, in the context of generalized complex geometry. Just as we may require a complex structure to be compatible with a Riemannian metric in a way which gives rise to a symplectic form, we may require a generalized complex structure to be compatible with a metric so that it defines a second generalized complex structure. We prove that generalized Kähler geometry is equivalent to the bi-Hermitian geometry on the target of a 2-dimensional sigma model with (2, 2) supersymmetry. We also prove the existence of natural holomorphic Courant algebroids for each of the underlying complex structures, and that these split into a sum of transverse holomorphic Dirac structures. Finally, we explore the analogy between pre-quantum line bundles and gerbes in the context of generalized Kähler geometry.

  9. Statistical Mechanics of Confined Biological Materials

    NASA Astrophysics Data System (ADS)

    El Kinani, R.; Benhamou, M.; Kaïdi, H.

    2017-03-01

    In this work, we propose a model to study the Statistical Mechanics of a confined bilayer-membrane that fluctuates between two interactive flat substrates. From the scaling laws point of view, the bilayer-membranes and strings are very similar. Therefore, it is sufficient to consider only the problem of a string. We assume that the bilayer-membrane (or string) interact with the substrate via a Double Morse potential that reproduces well the characteristics of the real interaction. We show that the Statistical Mechanic of the string can be adequately described by the Schrödinger equation approach that we solve exactly using the Bethe method. Finally, from the exact value of the energy of the ground state, we extract the expression of the free energy density as well as the specific heat.

  10. Simulations of artificial swimmers in confined flows

    NASA Astrophysics Data System (ADS)

    Brandt, Luca; Zhu, Lailai; Gjølberg, Eerik

    2012-11-01

    Miniature swimmming robots are potentially powerful for microobject manipulation, such as flow control in lab-on-a-chip, localized drug delivery and screening for diseases. Magnetically driven artificial bacterial flagella (ABF) performing helical motion is advantegous due to high swimming speed and accurate control. Using boundary element method, we numerically investigate the propulsion of ABF in free space and near solid boundaries. Step-out at high actuation frequencies, wobbling and near-wall drifting are documented, in qualitative agreement with recent experiments. We aim to explore the effect of swimmer shape on the performance, thus benefiting design of efficient microswimmers. Propulsion of ABF confined by a solid wall with and without background shear flow is also studied, with a focus on wall-induced hydrodynamic interaction and its influence on the stability of the motion. Funding by VR (the Swedish Research Council) and Linne flow centre at KTH is acknowledged.

  11. Planetary Image Geometry Library

    NASA Technical Reports Server (NTRS)

    Deen, Robert C.; Pariser, Oleg

    2010-01-01

    The Planetary Image Geometry (PIG) library is a multi-mission library used for projecting images (EDRs, or Experiment Data Records) and managing their geometry for in-situ missions. A collection of models describes cameras and their articulation, allowing application programs such as mosaickers, terrain generators, and pointing correction tools to be written in a multi-mission manner, without any knowledge of parameters specific to the supported missions. Camera model objects allow transformation of image coordinates to and from view vectors in XYZ space. Pointing models, specific to each mission, describe how to orient the camera models based on telemetry or other information. Surface models describe the surface in general terms. Coordinate system objects manage the various coordinate systems involved in most missions. File objects manage access to metadata (labels, including telemetry information) in the input EDRs and RDRs (Reduced Data Records). Label models manage metadata information in output files. Site objects keep track of different locations where the spacecraft might be at a given time. Radiometry models allow correction of radiometry for an image. Mission objects contain basic mission parameters. Pointing adjustment ("nav") files allow pointing to be corrected. The object-oriented structure (C++) makes it easy to subclass just the pieces of the library that are truly mission-specific. Typically, this involves just the pointing model and coordinate systems, and parts of the file model. Once the library was developed (initially for Mars Polar Lander, MPL), adding new missions ranged from two days to a few months, resulting in significant cost savings as compared to rewriting all the application programs for each mission. Currently supported missions include Mars Pathfinder (MPF), MPL, Mars Exploration Rover (MER), Phoenix, and Mars Science Lab (MSL). Applications based on this library create the majority of operational image RDRs for those missions. A

  12. T-branes and geometry

    NASA Astrophysics Data System (ADS)

    Anderson, Lara B.; Heckman, Jonathan J.; Katz, Sheldon

    2014-05-01

    T-branes are a non-abelian generalization of intersecting branes in which the matrix of normal deformations is nilpotent along some subspace. In this paper we study the geometric remnant of this open string data for six-dimensional F-theory vacua. We show that in the dual M-theory / IIA compactification on a smooth Calabi-Yau threefold X smth, the geometric remnant of T-brane data translates to periods of the three-form potential valued in the intermediate Jacobian of X smth. Starting from a smoothing of a singular Calabi-Yau, we show how to track this data in singular limits using the theory of limiting mixed Hodge structures, which in turn directly points to an emergent Hitchin-like system coupled to defects. We argue that the physical data of an F-theory compactification on a singular threefold involves specifying both a geometry as well as the remnant of three-form potential moduli and flux which is localized on the discriminant. We give examples of T-branes in compact F-theory models with heterotic duals, and comment on the extension of our results to four-dimensional vacua.

  13. Thermodynamics of Asymptotically Conical Geometries.

    PubMed

    Cvetič, Mirjam; Gibbons, Gary W; Saleem, Zain H

    2015-06-12

    We study the thermodynamical properties of a class of asymptotically conical geometries known as "subtracted geometries." We derive the mass and angular momentum from the regulated Komar integral and the Hawking-Horowitz prescription and show that they are equivalent. By deriving the asymptotic charges, we show that the Smarr formula and the first law of thermodynamics hold. We also propose an analog of Christodulou-Ruffini inequality. The analysis can be generalized to other asymptotically conical geometries.

  14. Autoionization resonance states of two-electron atomic systems with finite spherical confinement

    SciTech Connect

    Chakraborty, Sumana; Ho, Y. K.

    2011-09-15

    We investigate the lowest-lying S-wave resonant states of two-electron atoms confined by a spherical quantum cavity under the framework of the stabilization method. Hylleraas-type wave functions (basis length N = 444) taking the correlation effects between all the charged particles into account are used in the present paper. The finite oscillator potential is used to represent the confinement potential. We present the resonant parameters (energies and widths) of the quantum-confined two-electron atoms with different depths and various ranges of the potentials.

  15. Investigating Fractal Geometry Using LOGO.

    ERIC Educational Resources Information Center

    Thomas, David A.

    1989-01-01

    Discusses dimensionality in Euclidean geometry. Presents methods to produce fractals using LOGO. Uses the idea of self-similarity. Included are program listings and suggested extension activities. (MVL)

  16. Influence of confinement by smooth and rough walls on particle dynamics in dense hard-sphere suspensions.

    PubMed

    Eral, H B; van den Ende, D; Mugele, F; Duits, M H G

    2009-12-01

    We used video microscopy and particle tracking to study the dynamics of confined hard-sphere suspensions. Our fluids consisted of 1.1-microm-diameter silica spheres suspended at volume fractions of 0.33-0.42 in water-dimethyl sulfoxide. Suspensions were confined in a quasiparallel geometry between two glass surfaces: a millimeter-sized rough sphere and a smooth flat wall. First, as the separation distance (H) is decreased from 18 to 1 particle diameter, a transition takes place from a subdiffusive behavior (as in bulk) at large H, to completely caged particle dynamics at small H. These changes are accompanied by a strong decrease in the amplitude of the mean-square displacement (MSD) in the horizontal plane parallel to the confining surfaces. In contrast, the global volume fraction essentially remains constant when H is decreased. Second, measuring the MSD as a function of distance from the confining walls, we found that the MSD is not spatially uniform but smaller close to the walls. This effect is the strongest near the smooth wall where layering takes place. Although confinement also induces local variations in volume fraction, the spatial variations in MSD can be attributed only partially to this effect. The changes in MSD are predominantly a direct effect of the confining surfaces. Hence, both the wall roughness and the separation distance (H) influence the dynamics in confined geometries.

  17. Ion separation effects in mixed-species ablators for inertial-confinement-fusion implosions

    NASA Astrophysics Data System (ADS)

    Amendt, Peter; Bellei, Claudio; Ross, J. Steven; Salmonson, Jay

    2015-02-01

    Recent efforts to demonstrate significant self-heating of the fuel and eventual ignition at the National Ignition Facility make use of plastic (CH) ablators [O. A. Hurricane et al., Phys. Plasmas 21, 056314 (2014), 10.1063/1.4874330]. Mainline simulation techniques for modeling CH capsule implosions treat the ablator as an average-atom fluid and neglect potential species separation phenomena. The mass-ablation process for a mixture is shown to lead to the potential for species separation, parasitic energy loss according to thermodynamic arguments, and reduced rocket efficiency. A generalized plasma barometric formula for a multispecies concentration gradient that includes collisionality and steady flows in spherical geometry is presented. A model based on plasma expansion into a vacuum is used to interpret reported experimental evidence for ablator species separation in an inertial-confinement-fusion target [J. S. Ross et al., Rev. Sci. Instrum. 83, 10E323 (2012)]. The possibility of "runaway" hydrogen ions in the thermoelectric field of the ablation front is conjectured.

  18. Ion separation effects in mixed-species ablators for inertial-confinement-fusion implosions.

    PubMed

    Amendt, Peter; Bellei, Claudio; Ross, J Steven; Salmonson, Jay

    2015-02-01

    Recent efforts to demonstrate significant self-heating of the fuel and eventual ignition at the National Ignition Facility make use of plastic (CH) ablators [O. A. Hurricane et al., Phys. Plasmas 21, 056314 (2014)]. Mainline simulation techniques for modeling CH capsule implosions treat the ablator as an average-atom fluid and neglect potential species separation phenomena. The mass-ablation process for a mixture is shown to lead to the potential for species separation, parasitic energy loss according to thermodynamic arguments, and reduced rocket efficiency. A generalized plasma barometric formula for a multispecies concentration gradient that includes collisionality and steady flows in spherical geometry is presented. A model based on plasma expansion into a vacuum is used to interpret reported experimental evidence for ablator species separation in an inertial-confinement-fusion target [J. S. Ross et al., Rev. Sci. Instrum. 83, 10E323 (2012)]. The possibility of "runaway" hydrogen ions in the thermoelectric field of the ablation front is conjectured.

  19. Geometry of blind thrusts

    SciTech Connect

    Kligfield, R.; Geiser, P.; Geiser, J.

    1985-01-01

    Blind thrusts are structures which at no time in their history broke the erosion surface and along which displacement progressively changes upwards. Faults of the stiff layer along which displacement progressively decreases to zero (tip) are one prominent type of blind thrust structure. Shortening above such tips is accommodated entirely by folding whereas shortening below the tip is partitioned between folding and faulting. For these types of faults it is possible to determine the original length of the stiff layer for balancing purposes. A systematic methodology for line length and area restoration is outlined for determining blind thrust geometry. Application of the methodology is particularly suitable for use with microcomputers. If the folded form of the cover is known along with the position of the fault and its tip, then it is possible to locate hanging and footwall cutoffs. If the fault trajectory, tip, and a single hanging wall footwall cutoff pair are known, then the folded form of the cover layer can be determined. In these constructions it is necessary to specify pin lines for balancing purposes. These pin lines may or may not have a zero displacement gradient, depending upon the amount of simple shear deformation. Examples are given from both Laramide structures of the western USA and the Appalachians.

  20. Are polymers glassier upon confinement?

    NASA Astrophysics Data System (ADS)

    Napolitano, Simone; Spiece, Jean; Martinez-Tong, Daniel E.; Sferrazza, Michele; Nogales, Aurora

    Glass forming systems are characterized by a stability against crystallization upon heating and by the easiness with which their liquid phase can be transformed into a solid lacking of long-range order upon cooling (glass forming ability). Here, we discuss on the the thickness dependence of the thermal phase transition temperatures of poly(L-lactide acid) thin films supported onto solid substrates. The determination of the glass transition (Tg), cold crystallization (TCC) and melting (Tm) temperatures down to a thickness of 6 nm via ellipsometry, permitted us to build up parameters describing glass stability and glass forming ability. We observed a strong influence of the film thickness on the latter, while the former is not affected by 1D confinement. Remarkably, the increase in Tg/Tm ratio, a parameter related to glass forming ability, is not accompanied by an increase in TCC-Tg, as observed on the contrary, in bulk metallic glasses. We explained this peculiar behavior of soft matter in confinement considering the impact of irreversible adsorption on local free volume content.

  1. Soft confinement for polymer solutions

    NASA Astrophysics Data System (ADS)

    Oya, Yutaka; Kawakatsu, Toshihiro

    2014-07-01

    As a model of soft confinement for polymers, we investigated equilibrium shapes of a flexible vesicle that contains a phase-separating polymer solution. To simulate such a system, we combined the phase field theory (PFT) for the vesicle and the self-consistent field theory (SCFT) for the polymer solution. We observed a transition from a symmetric prolate shape of the vesicle to an asymmetric pear shape induced by the domain structure of the enclosed polymer solution. Moreover, when a non-zero spontaneous curvature of the vesicle is introduced, a re-entrant transition between the prolate and the dumbbell shapes of the vesicle is observed. This re-entrant transition is explained by considering the competition between the loss of conformational entropy and that of translational entropy of polymer chains due to the confinement by the deformable vesicle. This finding is in accordance with the recent experimental result reported by Terasawa et al. (Proc. Natl. Acad. Sci. U.S.A., 108 (2011) 5249).

  2. Pattern formation in confined chemical gardens

    NASA Astrophysics Data System (ADS)

    De Wit, Anne; Haudin, Florence; Brau, Fabian; Cartwright, Julyan

    2014-05-01

    Chemical gardens are plant-like mineral structures first described in the seventeenth century and popularly known from chemistry sets for children. They are classically grown in three-dimensional containers by placing a solid metal-salt seed into a silicate solution. When the metal salt starts dissolving in the silicate solution, a semi-permeable membrane forms by precipitation across which water is pumped by osmosis from the silicate solution into the metal salt solution, further dissolving the salt. Above a given pressure, the membrane breaks. The dissolved metal salt solution being generally less dense than the reservoir silicate solution, it rises as a buoyant jet through the broken membrane and further precipitates in contact with the silicate solution, producing a collection of mineral forms that resemble a garden. Such gardens are the subject of increased interest as a model system to understand pattern formation in sea-ice brinicles and hydrothermal vents on the seafloor, among others. All these self-organized precipitation structures at the interface between chemistry, fluid dynamics and mechanics share indeed common chemical, mechanical and electrical properties. In this framework, we study experimentally spatial patterns resulting from the growth of chemical gardens in confined quasi-two-dimensional (2D) geometries upon radial injection of a metallic salt solution into a silicate solution in a horizontal Hele-Shaw cell. We find a large variety of patterns including spirals, fingers, worms, filiform tubes, and flower-like patterns. By exploring the phase space of reactant concentrations and injection flow rates, we observe transitions between these spatio-temporal structures resulting from a coupling between the precipitation reaction, mechanical effects and hydrodynamic instabilities.

  3. Proton radiography of PBX 9502 detonation shock dynamics confinement sandwich test

    SciTech Connect

    Aslam, Tariq D; Jackson, Scott I; Morris, John S

    2009-01-01

    Recent results utilizing proton radiography (P-Rad) during the detonation of the high explosive PBX 9502 are presented. Specifically, the effects of confinement of the detonation are examined in the LANL detonation confinement sandwich geometry. The resulting detonation velocity and detonation shock shape are measured. In addition, proton radiography allows one to image the reflected shocks through the detonation products. Comparisons are made with detonation shock dynamics (DSD) and reactive flow models for the lead detonation shock and detonation velocity. In addition, predictions of reflected shocks are made with the reactive flow models.

  4. Specific heat critical amplitudes and the approach to bulk criticality in parallel plate geometries

    NASA Astrophysics Data System (ADS)

    Leite, M. M.; Nemirovsky, A. M.; Coutinho-Filho, M. D.

    1992-02-01

    We calculate the universal ration A+/ A- of the specific heat critical amplitudes of an Ising system confined in a layered geometry of thickness L in the regime L/ξ≥1, where ξ is the bulk critical correlation length. Using field-theoretic renormalization-group techniques we determine A+/ A- under various surface boundary conditions for the local field.

  5. Effects of edge dc biasing on plasma rotation and transport in a toroidal geometry

    NASA Astrophysics Data System (ADS)

    Fredriksen, Åshild; Riccardi, Claudia; Magni, Simone

    2006-02-01

    We report results from experiments performed to study how a change in boundary conditions affects the plasma state in the toroidal geometry of the Blaamann device in Tromso. The boundary condition was changed by applying a dc bias on a limiter extended around the entire poloidal circumference of the plasma column. Two distinctly different plasma potential states were found. One state was associated with a bias at or negative with respect to the floating potential of the limiter, and a small ion-saturation current. The other state was associated with a positive bias with respect to the floating potential, near or in the electron saturation regime of the limiter. In the latter case the potential minimum in the middle of the cross-section was significantly less negative than in the case of ion-saturation current to the limiter. On the other hand, the grounded limiter provided the best confinement properties, for which the density maximum was significantly higher than for both more positive and more negative biases. This state also had the lowest fluctuation levels, and near zero poloidal velocities close to the boundaries, as well as the smallest radial, anomalous particle transport.

  6. Effects of Edge DC Biasing on Plasma Rotation and Transport in a Toroidal Geometry.

    NASA Astrophysics Data System (ADS)

    Fredriksen, Ashild; Riccardi, Claudia

    2005-10-01

    We report results from experiments performed to study how a change in boundary conditions is affecting the plasma states in the toroidal geometry of the Blaamann device in Tromso. The boundary condition was changed by applying a DC bias on a limiter extended around the entire poloidal circumference of the plasma column. Two distinctly different plasma potential states were found. One state was associated with a bias at or negative with respect to the floating potential of the limiter, and a small ion saturation current. The other state was associated with a positive bias with respect to the floating potential, near or in the electron saturation regime of the limiter. In the latter case the potential minimum in the middle of the cross-section was significantly less negative than in the case of ion-saturation current to the limiter. On the other hand, the grounded limiter provided the best confinement properties, for which the density maximum was significantly higher than for both more positive and more negative biases. This state also had the lowest fluctuation levels, and near zero poloidal velocities close to the boundaries, as well as the smallest radial, anomalous particle transport.

  7. A double-layer based model of ion confinement in electron cyclotron resonance ion source

    SciTech Connect

    Mascali, D. Neri, L.; Celona, L.; Castro, G.; Gammino, S.; Ciavola, G.; Torrisi, G.; Sorbello, G.

    2014-02-15

    The paper proposes a new model of ion confinement in ECRIS, which can be easily generalized to any magnetic configuration characterized by closed magnetic surfaces. Traditionally, ion confinement in B-min configurations is ascribed to a negative potential dip due to superhot electrons, adiabatically confined by the magneto-static field. However, kinetic simulations including RF heating affected by cavity modes structures indicate that high energy electrons populate just a thin slab overlapping the ECR layer, while their density drops down of more than one order of magnitude outside. Ions, instead, diffuse across the electron layer due to their high collisionality. This is the proper physical condition to establish a double-layer (DL) configuration which self-consistently originates a potential barrier; this “barrier” confines the ions inside the plasma core surrounded by the ECR surface. The paper will describe a simplified ion confinement model based on plasma density non-homogeneity and DL formation.

  8. Electronic confinement in graphene quantum rings due to substrate-induced mass radial kink.

    PubMed

    Xavier, L J P; da Costa, D R; Chaves, A; Pereira, J M; Farias, G A

    2016-12-21

    We investigate localized states of a quantum ring confinement in monolayer graphene defined by a circular mass-related potential, which can be induced e.g. by interaction with a substrate that breaks the sublattice symmetry, where a circular line defect provides a change in the sign of the induced mass term along the radial direction. Electronic properties are calculated analytically within the Dirac-Weyl approximation in the presence of an external magnetic field. Analytical results are also compared with those obtained by the tight-binding approach. Regardless of its sign, a mass term [Formula: see text] is expected to open a gap for low-energy electrons in Dirac cones in graphene. Both approaches confirm the existence of confined states with energies inside the gap, even when the width of the kink modelling the mass sign transition is infinitely thin. We observe that such energy levels are inversely proportional to the defect line ring radius and independent on the mass kink height. An external magnetic field is demonstrated to lift the valley degeneracy in this system and easily tune the valley index of the ground state in this system, which can be polarized on either K or [Formula: see text] valleys of the Brillouin zone, depending on the magnetic field intensity. Geometrical changes in the defect line shape are considered by assuming an elliptic line with different eccentricities. Our results suggest that any defect line that is closed in a loop, with any geometry, would produce the same qualitative results as the circular ones, as a manifestation of the topologically protected nature of the ring-like states investigated here.

  9. Electronic confinement in graphene quantum rings due to substrate-induced mass radial kink

    NASA Astrophysics Data System (ADS)

    Xavier, L. J. P.; da Costa, D. R.; Chaves, A.; Pereira, J. M., Jr.; Farias, G. A.

    2016-12-01

    We investigate localized states of a quantum ring confinement in monolayer graphene defined by a circular mass-related potential, which can be induced e.g. by interaction with a substrate that breaks the sublattice symmetry, where a circular line defect provides a change in the sign of the induced mass term along the radial direction. Electronic properties are calculated analytically within the Dirac-Weyl approximation in the presence of an external magnetic field. Analytical results are also compared with those obtained by the tight-binding approach. Regardless of its sign, a mass term Δ is expected to open a gap for low-energy electrons in Dirac cones in graphene. Both approaches confirm the existence of confined states with energies inside the gap, even when the width of the kink modelling the mass sign transition is infinitely thin. We observe that such energy levels are inversely proportional to the defect line ring radius and independent on the mass kink height. An external magnetic field is demonstrated to lift the valley degeneracy in this system and easily tune the valley index of the ground state in this system, which can be polarized on either K or {{K}\\prime} valleys of the Brillouin zone, depending on the magnetic field intensity. Geometrical changes in the defect line shape are considered by assuming an elliptic line with different eccentricities. Our results suggest that any defect line that is closed in a loop, with any geometry, would produce the same qualitative results as the circular ones, as a manifestation of the topologically protected nature of the ring-like states investigated here.

  10. Whole-volume integrated gyrokinetic simulation of plasma turbulence in realistic diverted-tokamak geometry

    SciTech Connect

    Chang, C S; Ku, Seung-Hoe; Diamond, P. H.; Adams, Mark; Tchoua, Roselyne B; Chen, Yang; Cummings, J.; D'Azevedo, Ed F; Dif-Pradalier, Guilhem; Ethier, Stephane; Greengard, Leslie; Hahm, Taik Soo; Hinton, Fred; Keyes, David E; Klasky, Scott A; Lin, Z.; Lofstead, J.; Park, G.; Podhorszki, Norbert; Schwan, Karsten; Shoshani, A.; Silver, D.; Wolf, M.; Worley, Patrick H; Zorin, Denis

    2009-01-01

    Performance prediction for ITER is based upon the ubiquitous experimental observation that the plasma energy confinement in the device core is strongly coupled to the edge confinement for an unknown reason. The coupling time-scale is much shorter than the plasma transport time-scale. In order to understand this critical observation, a multi-scale turbulence-neoclassical simulation of integrated edge-core plasma in a realistic diverted geometry is a necessity, but has been a formidable task. Thanks to the recent development in high performance computing, we have succeeded in the integrated multiscale gyrokinetic simulation of the ion-temperature-gradient driven turbulence in realistic diverted tokamak geometry for the first time. It is found that modification of the self-organized criticality in the core plasma by nonlocal core-edge coupling of ITG turbulence can be responsible for the core-edge confinement coupling.

  11. Whole-volume integrated gyrokinetc simulation of plasma turbulence in realistic diverted-tokamak geometry

    SciTech Connect

    Chang, C S; Ku, Seung-Hoe; Diamond, Patrick; Adams, Mark; Tchoua, Roselyne B; Chen, Yang; Cummings, Julian; D'Azevedo, Eduardo; Dif-Pradalier, Guilhem; Ethier, Stephane; Greengard, Leslie; Hahm, Taik Soo; Hinton, Fred; Keyes, David E; Klasky, Scott A; Lin, Zhihong; Lofstead, J.; Park, G.; Parker, Scott; Podhorszki, Norbert; Schwan, Karsten; Shoshani, A.; Silver, D.; Weitzner, Harold; Wolf, M.; Worley, Patrick H; Yoon, E.; Zorin, Denis

    2009-01-01

    Performance prediction for ITER is based upon the ubiquitous experimental observation that the plasma energy confinement in the device core is strongly coupled to the edge confinement for an unknown reason. The coupling time-scale is much shorter than the plasma transport time-scale. In order to understand this critical observation, a multi-scale turbulence-neoclassical simulation of integrated edge-core plasma in a realistic diverted geometry is a necessity, but has been a formidable task. Thanks to the recent development in high performance computing, we have succeeded in the integrated multiscale gyrokinetic simulation of the ion-temperature-gradient driven turbulence in realistic diverted tokamak geometry for the first time. It is found that modification of the self-organized criticality in the core plasma by nonlocal core-edge coupling of ITG turbulence can be responsible for the core-edge confinement coupling.

  12. Engineered Models of Confined Cell Migration

    PubMed Central

    Paul, Colin D.; Hung, Wei-Chien; Wirtz, Denis; Konstantopoulos, Konstantinos

    2017-01-01

    Cells in the body are physically confined by neighboring cells, tissues, and the extracellular matrix. Although physical confinement modulates intracellular signaling and the underlying mechanisms of cell migration, it is difficult to study in vivo. Furthermore, traditional two-dimensional cell migration assays do not recapitulate the complex topographies found in the body. Therefore, a number of experimental in vitro models that confine and impose forces on cells in well-defined microenvironments have been engineered. We describe the design and use of microfluidic microchannel devices, grooved substrates, micropatterned lines, vertical confinement devices, patterned hydrogels, and micropipette aspiration assays for studying cell responses to confinement. Use of these devices has enabled the delineation of changes in cytoskeletal reorganization, cell–substrate adhesions, intracellular signaling, nuclear shape, and gene expression that result from physical confinement. These assays and the physiologically relevant signaling pathways that have been elucidated are beginning to have a translational and clinical impact. PMID:27420571

  13. Electrokinetic ion transport in confined micro-nanochannel.

    PubMed

    Wang, Junyao; Liu, Chong; Xu, Zheng

    2016-03-01

    In this paper, a confined micronanochannel is presented to concentrate ions in a restricted zone. A general model exploiting the Poisson-Nernst-Plank equations coupled with the Navier-Stokes equation is employed to simulate the electrokinetic ion transport. The influences of the micronanochannel dimension and the surface charge density on the potential distribution, the ion concentration, and the fluid flow are investigated. The numerical results show that the potential drop depends mainly on the nanochannel, instead of the confined channel. Both decreasing the width and increasing the length enhance the ion enrichment performance. For a given nanochannel, ultimate value of ion concentration may be determined by the potential at the center point of the nanochannel. The study also shows that the enrichment stability can be improved by increasing the micronanochannel width, decreasing the micronanochannel length and reducing the surface charge density.

  14. Linguistic geometry for autonomous navigation

    SciTech Connect

    Stilman, B.

    1995-09-01

    To discover the inner properties of human expert heuristics, which were successful in a certain class of complex control systems, we develop a formal theory, the Linguistic Geometry. This paper reports two examples of application of Linguistic Geometry to autonomous navigation of aerospace vehicles that demonstrate dramatic search reduction.

  15. GPS: Geometry, Probability, and Statistics

    ERIC Educational Resources Information Center

    Field, Mike

    2012-01-01

    It might be said that for most occupations there is now less of a need for mathematics than there was say fifty years ago. But, the author argues, geometry, probability, and statistics constitute essential knowledge for everyone. Maybe not the geometry of Euclid, but certainly geometrical ways of thinking that might enable us to describe the world…

  16. Inertial Confinement Fusion R&D and Nuclear Proliferation

    SciTech Connect

    Robert J. Goldston

    2011-04-28

    In a few months, or a few years, the National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory may achieve fusion gain using 192 powerful lasers to generate x-rays that will compress and heat a small target containing isotopes of hydrogen. This event would mark a major milestone after decades of research on inertial confinement fusion (ICF). It might also mark the beginning of an accelerated global effort to harness fusion energy based on this science and technology. Unlike magnetic confinement fusion (ITER, 2011), in which hot fusion fuel is confined continuously by strong magnetic fields, inertial confinement fusion involves repetitive fusion explosions, taking advantage of some aspects of the science learned from the design and testing of hydrogen bombs. The NIF was built primarily because of the information it would provide on weapons physics, helping the United States to steward its stockpile of nuclear weapons without further underground testing. The U.S. National Academies' National Research Council is now hosting a study to assess the prospects for energy from inertial confinement fusion. While this study has a classified sub-panel on target physics, it has not been charged with examining the potential nuclear proliferation risks associated with ICF R&D. We argue here that this question urgently requires direct and transparent examination, so that means to mitigate risks can be assessed, and the potential residual risks can be balanced against the potential benefits, now being assessed by the NRC. This concern is not new (Holdren, 1978), but its urgency is now higher than ever before.

  17. Study for Air Vehicles at High Speeds, Identifying the Potential Benefits to Transport Aircraft of a Continuously Variable Geometry Trailing-Edge Structure that can be Utilized for Aircraft Control, Trim, Load-Alleviation, and High Lift

    DTIC Science & Technology

    2011-08-01

    1.58 for deltas , Ref.16. The GR is a function of CLmax, wing loading (W/S), rolling friction (µ), Thrust (T) and Lift Induced Drag factor (k). VSTALL...5.2.10 L/D – CL, M 0.75, AR 6 WING + TAILPLANE, Effect of Flap Angle (Plain Flap ) CDi Wing CDi Tail CDo PITCH TRIMMED CASES δTE CL...Geometry and Modelling 6.2. High Speed (M 0.75) Performance, Clean Wing , Plain Flaps and Variable TE 6.3. Low Speed (M 0.20) Performance 6.4. Stability

  18. Quark confinement in a constituent quark model

    SciTech Connect

    Langfeld, K.; Rho, M.

    1995-07-01

    On the level of an effective quark theory, we define confinement by the absence of quark anti-quark thresholds in correlation function. We then propose a confining Nambu-Jona-Lasinio-type model. The confinement is implemented in analogy to Anderson localization in condensed matter systems. We study the model`s phase structure as well as its behavior under extreme conditions, i.e. high temperature and/or high density.

  19. Analytic Coleman-de Luccia Geometries

    SciTech Connect

    Dong, Xi; Harlow, Daniel; /Stanford U., ITP /Stanford U., Phys. Dept.

    2012-02-16

    We present the necessary and sufficient conditions for a Euclidean scale factor to be a solution of the Coleman-de Luccia equations for some analytic potential V ({psi}), with a Lorentzian continuation describing the growth of a bubble of lower-energy vacuum surrounded by higher-energy vacuum. We then give a set of explicit examples that satisfy the conditions and thus are closed-form analytic examples of Coleman-de Luccia geometries.

  20. Hessian geometry and the holomorphic anomaly

    NASA Astrophysics Data System (ADS)

    Cardoso, G. L.; Mohaupt, T.

    2016-02-01

    We present a geometrical framework which incorporates higher derivative corrections to the action of N = 2 vector multiplets in terms of an enlarged scalar manifold which includes a complex deformation parameter. This enlarged space carries a deformed version of special Kähler geometry which we characterise. The holomorphic anomaly equation arises in this framework from the integrability condition for the existence of a Hesse potential.

  1. Molecular Motion and Confined Polymers

    NASA Astrophysics Data System (ADS)

    Dobrynin, Andrey V.; Jeon, Junhwan

    2004-03-01

    Microorganisms such as myxobacteria, cyanobacteria, and flexibacteria move by gliding. The gliding has been described by two quite different mechanisms: social (S) motility and adventurous (A) motility. Though retraction of type 4-pili provides the force for the S motility, extrusion of slime, which may be associated with the A motility, is not well known. Nozzle-like structures recently found in cyanobacteria can support the A motility. However, complete understaning A motility is still lacking. To describe the A motility, we use molecular dynamics simulations of a polymer growing inside a cylindrically shaped tube with one end capped. Confined polymers provide a driving force for a tube motion as if a rocket flew with emitting gas. It is seen from the mean-squared displacement of a tube that its motion is ballistic under constant applied force.

  2. Multishell inertial confinement fusion target

    DOEpatents

    Holland, James R.; Del Vecchio, Robert M.

    1984-01-01

    A method of fabricating multishell fuel targets for inertial confinement fusion usage. Sacrificial hemispherical molds encapsulate a concentric fuel pellet which is positioned by fiber nets stretched tautly across each hemispherical mold section. The fiber ends of the net protrude outwardly beyond the mold surfaces. The joint between the sacrificial hemispheres is smoothed. A ceramic or glass cover is then deposited about the finished mold surfaces to produce an inner spherical surface having continuously smooth surface configuration. The sacrificial mold is removed by gaseous reaction accomplished through the porous ceramic cover prior to enclosing of the outer sphere by addition of an outer coating. The multishell target comprises the inner fuel pellet concentrically arranged within a surrounding coated cover or shell by fiber nets imbedded within the cover material.

  3. Multishell inertial confinement fusion target

    DOEpatents

    Holland, James R.; Del Vecchio, Robert M.

    1987-01-01

    A method of fabricating multishell fuel targets for inertial confinement fusion usage. Sacrificial hemispherical molds encapsulate a concentric fuel pellet which is positioned by fiber nets stretched tautly across each hemispherical mold section. The fiber ends of the net protrude outwardly beyond the mold surfaces. The joint between the sacrificial hemispheres is smoothed. A ceramic or glass cover is then deposited about the finished mold surfaces to produce an inner spherical surface having continuously smooth surface configuration. The sacrificial mold is removed by gaseous reactions accomplished through the porous ceramic cover prior to enclosing of the outer sphere by addition of an outer coating. The multishell target comprises the inner fuel pellet concentrically arranged within a surrounding coated cover or shell by fiber nets imbedded within the cover material.

  4. Trapping, entrainment and synchronization of semiflexible polymers in narrow, asymmetric confinements.

    PubMed

    Swank, Zoe; Deshpande, Siddharth; Pfohl, Thomas

    2016-01-07

    The physical properties of polymeric actin facilitate many mechanical processes within the cell, including cellular deformation and locomotion, whereby the polymers can be confined to a range of different geometries. As actin polymers often form entangled solutions in the cell, we have investigated the effect of confinement on the evolution of entangled semiflexible polymer solutions. Using a microfluidic platform, we examined the physical dynamics of actin polymers confined within narrow (2-4 μm) rectangular channels. Focusing on the entanglement process of two actin polymers, we found that their prolonged entrainment leads to synchronized horizontal undulations and decreased translational diffusion. In the absence of cross-linking molecules or proteins, the long-range entrainment interactions are predominantly controlled by the geometric boundaries. We directly measure the deflection length Λ for an individual polymer, either solitarily confined within a channel or confined in the presence of a second filament, enabling the determination of the change in free energy associated with polymer entanglement. Our results indicate that geometrical confinement can serve as a solitary variable influencing the physical dynamics of entangled semiflexible polymers.

  5. Graph-based representation for multiview image geometry.

    PubMed

    Maugey, Thomas; Ortega, Antonio; Frossard, Pascal

    2015-05-01

    In this paper, we propose a new geometry representation method for multiview image sets. Our approach relies on graphs to describe the multiview geometry information in a compact and controllable way. The links of the graph connect pixels in different images and describe the proximity between pixels in 3D space. These connections are dependent on the geometry of the scene and provide the right amount of information that is necessary for coding and reconstructing multiple views. Our multiview image representation is very compact and adapts the transmitted geometry information as a function of the complexity of the prediction performed at the decoder side. To achieve this, our graph-based representation (GBR) carefully selects the amount of geometry information needed before coding. This is in contrast with depth coding, which directly compresses with losses the original geometry signal, thus making it difficult to quantify the impact of coding errors on geometry-based interpolation. We present the principles of this GBR and we build an efficient coding algorithm to represent it. We compare our GBR approach to classical depth compression methods and compare their respective view synthesis qualities as a function of the compactness of the geometry description. We show that GBR can achieve significant gains in geometry coding rate over depth-based schemes operating at similar quality. Experimental results demonstrate the potential of this new representation.

  6. Large Amplitude Nonlinear Richtmyer-Meshkov Instability in Convergent Geometries

    NASA Astrophysics Data System (ADS)

    Nelson, A.; Ramaprabhu, P.

    The Richtmyer Meshkov Instability (RMI) is a common hydrodynamic instability that occurs when an interface seperating two fluids of different densities is impulsively accelerated. Any perturbation along the seperating interface will likely evolve to induce mixing. This occurs in many natural events and engineering applications, such as supernovae and Inertial Confinement Fusion (ICF), both of which are inherently spherical. Therefore, to further understand these complicated events in their entirety, it is of interest to identify the specific effects of convergence in RMI induced mixing. To this end, we report results from detailed simulations of singlemode RMI in spherically convergent geometry, and focus on the nonlinear growth of imposed perturbations.

  7. Elementary framework for cold field emission from quantum-confined, non-planar emitters

    SciTech Connect

    Patterson, A. A. Akinwande, A. I.

    2015-05-07

    For suitably small field emitters, the effects of quantum confinement at the emitter tip may have a significant impact on the emitter performance and total emitted current density (ECD). Since the geometry of a quantum system uniquely determines the magnitude and distribution of its energy levels, a framework for deriving ECD equations from cold field electron emitters of arbitrary geometry and dimensionality is developed. In the interest of obtaining semi-analytical ECD equations, the framework is recast in terms of plane wave solutions to the Schrödinger equation via the use of the Jeffreys-Wentzel-Kramers-Brillouin approximation. To demonstrate the framework's consistency with our previous work and its capabilities in treating emitters with non-planar geometries, ECD equations were derived for the normally unconfined cylindrical nanowire (CNW) and normally confined (NC) CNW emitter geometries. As a function of the emitter radius, the NC CNW emitter ECD profile displayed a strong dependence on the Fermi energy and had an average ECD that exceeded the Fowler-Nordheim equation for typical values of the Fermi energy due to closely spaced, singly degenerate energy levels (excluding electron spin), comparatively large electron supply values, and the lack of a transverse, zero-point energy. Such characteristics suggest that emitters with non-planar geometries may be ideal for emission from both an electron supply and electrostatics perspective.

  8. Impact of lateral carrier confinement on electro-optical tuning properties of polariton condensates

    SciTech Connect

    Brodbeck, S.; Suchomel, H.; Amthor, M.; Wolf, A.; Kamp, M.; Schneider, C.; Höfling, S.

    2015-07-27

    Electro-optical measurements on exciton-polaritons below and above the condensation threshold are performed on high quality, pin-doped microcavities with embedded GaAs quantum wells. Applying an external electric field shifts the polariton emission by hundreds of μeV both in the linear and the nonlinear regime. We study three device geometries to investigate the influence of carrier confinement in the plane of the quantum well on the electro-optical tuning properties. In the conventional micropillar geometry, the electric field tuning behavior is dominated by the effects of carrier tunneling and electric field screening that manifest in a blueshift of the polariton emission. In stark contrast, for a planar sample geometry, we can significantly extend the range of electric fields and a redshift is observed. To separate the contributions of quantum confined Stark effect and reduced exciton oscillator strength to the energy shift, we study a third sample where the etching of micropillars is stopped just above the active region. In this semi-planar geometry, exciton and polariton emissions can be measured simultaneously. As for the planar geometry, redshifts of the polariton emission are observed below and above threshold that are well reproduced by theoretical shifts.

  9. X-Ray Studies of Diffusion Dynamics in Nano-Confined Geometries

    NASA Astrophysics Data System (ADS)

    Boucheron, Leandra

    Since their discovery in the late 1800s, x-rays have taken the stage as one of the most powerful research techniques for materials science. Their element-specific absorption has allowed for everyday applications in security and medical imaging, while their short wavelength has a tremendous ability to resolve materials on a molecular or even atomic level. In this dissertation, I will discuss basic properties of x-rays as well as how they are produced and detected. I will also present x-ray scattering and analysis techniques before moving onto a discussion of my research on diffusion in soft-matter systems. I provide a full alignment guide for a lab-based dynamic light scattering (DLS) goniometer system, which I used for some preliminary studies of systems. I proceed to discuss diffusion on the nanoscale in quasi-1D (nanopores) and quasi-2D (liquid surface) systems. The latter of these systems was the main focus of my dissertation research. I utilized x-ray photon correlation spectroscopy (XPCS) to study the diffusion and interparticle dynamics of iron oxide nanoparticles at the air-water interface. Autocorrelation analysis revealed that these particles show signatures of a jammed system under lateral compression. I present these results as well as a description of their interpretation and importance in the main text.

  10. Quantum Computation with Neutral Atoms at Addressable Optical Lattice Sites and Atoms in Confined Geometries

    DTIC Science & Technology

    2014-10-13

    SECURITY CLASSIFICATION OF: We have performed a set of experiments using arrays of 1D Bose gases in various configurations. Uncoupled 1D gases have been...used to study the limits of statistical mechanics near integrable points. We have shown that nearly integrable gases thermalize at an even slower...NAME(S) AND ADDRESS (ES) U.S. Army Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 ultracold atoms, optical lattices, 1D gases

  11. Plastic ice in confined geometry: the evidence from neutron diffraction and NMR relaxation.

    PubMed

    Webber, J Beau W; Dore, John C; Strange, John H; Anderson, Ross; Tohidi, Bahman

    2007-10-17

    Neutron diffraction and nuclear magnetic resonance (NMR) relaxation studies have been made of water/ice in mesoporous SBA-15 silica with ordered structures of cylindrical mesopores with a pore diameter ∼8.6 nm, over the temperature range 180-300 K. Both measurements show similar depressed freezing and melting points due to the Gibb-Thomson effect. The neutron diffraction measurements for fully filled pores show, in addition to cubic and hexagonal crystalline ice, the presence of a disordered water/ice component extending a further 50-80 K, down to around or below 200 K. NMR relaxation measurements over the same temperature range show a free induction decay that is partly Gaussian and characteristic of brittle ice but that also exhibits a longer exponential relaxation component. An argument has been made (Liu et al 2006 J. Phys:. Condens. Matter 18 10009-28; Webber et al 2007 Magn. Reson. Imag. 25 533-6) to suggest that this is an observation of ice in a plastic or rotationally mobile state, and that there is a fully reversible inter-conversion between brittle and plastic states of ice as the temperature is lowered or raised. More recent detailed NMR measurements are also discussed that allow the extraction of activation enthalpies and an estimate to be made of the equilibrium thickness, as a function of temperature, if the the assumption is made that the plastic component is in the form of a layer at the silica interface. The two different techniques suggest a maximum layer thickness of about 1.0-1.5 nm.

  12. Plastic ice in confined geometry: the evidence from neutron diffraction and NMR relaxation

    NASA Astrophysics Data System (ADS)

    Webber, J. Beau W.; Dore, John C.; Strange, John H.; Anderson, Ross; Tohidi, Bahman

    2007-10-01

    Neutron diffraction and nuclear magnetic resonance (NMR) relaxation studies have been made of water/ice in mesoporous SBA-15 silica with ordered structures of cylindrical mesopores with a pore diameter ~8.6 nm, over the temperature range 180-300 K. Both measurements show similar depressed freezing and melting points due to the Gibb-Thomson effect. The neutron diffraction measurements for fully filled pores show, in addition to cubic and hexagonal crystalline ice, the presence of a disordered water/ice component extending a further 50-80 K, down to around or below 200 K. NMR relaxation measurements over the same temperature range show a free induction decay that is partly Gaussian and characteristic of brittle ice but that also exhibits a longer exponential relaxation component. An argument has been made (Liu et al 2006 J. Phys:. Condens. Matter 18 10009-28 Webber et al 2007 Magn. Reson. Imag. 25 533-6) to suggest that this is an observation of ice in a plastic or rotationally mobile state, and that there is a fully reversible inter-conversion between brittle and plastic states of ice as the temperature is lowered or raised. More recent detailed NMR measurements are also discussed that allow the extraction of activation enthalpies and an estimate to be made of the equilibrium thickness, as a function of temperature, if the the assumption is made that the plastic component is in the form of a layer at the silica interface. The two different techniques suggest a maximum layer thickness of about 1.0-1.5 nm.

  13. Electron and boson clusters in confined geometries: Symmetry breaking in quantum dots and harmonic traps

    PubMed Central

    Yannouleas, Constantine; Landman, Uzi

    2006-01-01

    We discuss the formation of crystalline electron clusters in semiconductor quantum dots and of crystalline patterns of neutral bosons in harmonic traps. In a first example, we use calculations for two electrons in an elliptic quantum dot to show that the electrons can localize and form a molecular dimer. The calculated singlet–triplet splitting (J) as a function of the magnetic field (B) agrees with cotunneling measurements with its behavior reflecting the effective dissociation of the dimer for large B. Knowledge of the dot shape and of J(B) allows determination of the degree of entanglement. In a second example, we study strongly repelling neutral bosons in two-dimensional harmonic traps. Going beyond the Gross–Pitaevskii (GP) mean-field approximation, we show that bosons can localize and form polygonal-ring-like crystalline patterns. The total energy of the crystalline phase saturates in contrast to the GP solution, and its spatial extent becomes smaller than that of the GP condensate. PMID:16740665

  14. Molecule-induced quantum confinement in single-walled carbon nanotube

    NASA Astrophysics Data System (ADS)

    Hida, Akira; Ishibashi, Koji

    2015-04-01

    A method of fabricating quantum-confined structures with single-walled carbon nanotubes (SWNTs) has been developed. Scanning tunneling spectroscopy revealed that a parabolic confinement potential appeared when collagen model peptides were attached to both ends of an individual SWNT via the formation of carboxylic anhydrides. On the other hand, the confinement potential was markedly changed by yielding the peptide bonds between the SWNT and the collagen model peptides. Photoluminescence spectroscopy measurements showed that a type-II quantum dot was produced in the obtained heterostructure.

  15. Structure and Dynamics of Octamethylcyclotetrasiloxane Confined between Mica Surfaces.

    PubMed

    Vadhana, V; Ayappa, K G

    2016-03-24

    Using a molecular model for octamethylcyclotetrasiloxane (OMCTS), molecular dynamics simulations are carried out to probe the phase state of OMCTS confined between two mica surfaces in equilibrium with a reservoir. Molecular dynamics simulations are carried out for elevations ranging from 5 to 35 K above the melting point for the OMCTS model used in this study. The Helmholtz free energy is computed for a specific confinement using the two-phase thermodynamic (2PT) method. Analysis of the in-plane pair correlation functions did not reveal signatures of freezing even under an extreme confinement of two layers. OMCTS is found to orient with a wide distribution of orientations with respect to the mica surface, with a distinct preference for the surface parallel configuration in the contact layers. The self-intermediate scattering function is found to decay with increasing relaxation times as the surface separation is decreased, and the two-step relaxation in the scattering function, a signature of glassy dynamics, distinctly evolves as the temperature is lowered. However, even at 5 K above the melting point, we did not observe a freezing transition and the self-intermediate scattering functions relax within 200 ps for the seven-layered confined system. The self-diffusivity and relaxation times obtained from the Kohlrausch-Williams-Watts stretched exponential fits to the late α-relaxation exhibit power law scalings with the packing fraction as predicted by mode coupling theory. A distinct discontinuity in the Helmholtz free energy, potential energy, and a sharp change in the local bond order parameter, Q4, was observed at 230 K for a five-layered system upon cooling, indicative of a first-order transition. A freezing point depression of about 30 K was observed for this five-layered confined system, and at the lower temperatures, contact layers were found to be disordered with long-range order present only in the inner layers. These dynamical signatures indicate that

  16. Effect of curvature on cholesteric liquid crystals in toroidal geometries

    NASA Astrophysics Data System (ADS)

    Fialho, Ana R.; Bernardino, Nelson R.; Silvestre, Nuno M.; Telo da Gama, Margarida M.

    2017-01-01

    The confinement of liquid crystals inside curved geometries leads to exotic structures, with applications ranging from biosensors to optical switches and privacy windows. Here we study how curvature affects the alignment of a cholesteric liquid crystal. We model the system on the mesoscale using the Landau-de Gennes model. Our study was performed in three stages, analyzing different curved geometries from cylindrical walls and pores, to toroidal domains, in order to isolate the curvature effects. Our results show that the stresses introduced by the curvature influence the orientation of the liquid crystal molecules, and cause distortions in the natural periodicity of the cholesteric that depend on the radius of curvature, on the pitch, and on the dimensions of the system. In particular, the cholesteric layers of toroidal droplets exhibit a symmetry breaking not seen in cylindrical pores and that is driven by the additional curvature.

  17. Spontaneous emergence of chirality in achiral lyotropic chromonic liquid crystals confined to cylinders

    PubMed Central

    Nayani, Karthik; Chang, Rui; Fu, Jinxin; Ellis, Perry W.; Fernandez-Nieves, Alberto; Park, Jung Ok; Srinivasarao, Mohan

    2015-01-01

    The presumed ground state of a nematic fluid confined in a cylindrical geometry with planar anchoring corresponds to that of an axial configuration, wherein the director, free of deformations, is along the long axis of the cylinder. However, upon confinement of lyotropic chromonic liquid crystals in cylindrical geometries, here we uncover a surprising ground state corresponding to a doubly twisted director configuration. The stability of this ground state, which involves significant director deformations, can be rationalized by the saddle-splay contribution to the free energy. We show that sufficient anisotropy in the elastic constants drives the transition from a deformation-free ground state to a doubly twisted structure, and results in spontaneous symmetry breaking with equal probability for either handedness. Enabled by the twist angle measurements of the spontaneous twist, we determine the saddle-splay elastic constant for chromonic liquid crystals for the first time. PMID:26287517

  18. Electrophoretic mobility of spherical nanoparticles confined in nanochannels

    NASA Astrophysics Data System (ADS)

    Liu, Yu-Wei; Wynne, Tom; Pennathur, Sumita; Meinhart, Carl

    2013-11-01

    We investigate the mobility of a charged spherical nanoparticle driven by weak electric fields that are confined in nanochannels. Factors affecting mobility include particle zeta potential, electrolyte concentration, and channel size. Classic models for electrophoretic mobility (e.g. Smoluchowski and Huckel) are valid only in the linear regime of small particle zeta potential, and for an unbounded fluid domain. The classical models fail to predict electrophoretic mobility estimated from experiments using ~ 42 nm diameter particles confined in a ~ 100 nm nanochannel. We adopt the asymptotically-expanded formulations of Khair and Squires (Phys. Fluids, 2009), and solve the fully-coupled equations on a well-resolved 3D finite element domain. For a charged 42 nm diameter nanoparticle, confined in a 100 nm high nanochannel, the electrophoretic mobility increases nonlinearly when particle zeta potential is greater than thermal potential kB T / e . When the channel size is decreased from 2.5 um to 100 nm, the mobility is reduced by up to 20%. The result suggests that particle/wall interactions, including overlapping double layers may affect electrophoretic mobility in a non-linear manner.

  19. CATIA-GDML geometry builder

    NASA Astrophysics Data System (ADS)

    Belogurov, S.; Berchun, Yu; Chernogorov, A.; Malzacher, P.; Ovcharenko, E.; Semennikov, A.

    2011-12-01

    Due to conceptual difference between geometry descriptions in Computer-Aided Design (CAD) systems and particle transport Monte Carlo (MC) codes direct conversion of detector geometry in either direction is not feasible. An original set of tools has been developed for building a GEANT4/ROOT compatible geometry in the CATIA CAD system and exchanging it with mentioned MC packages using GDML file format. A Special structure of a CATIA product tree, a wide range of primitives, different types of multiple volume instantiation, and supporting macros have been implemented.

  20. An improved combinatorial geometry model for arbitrary geometry in DSMC

    NASA Astrophysics Data System (ADS)

    Kargaran, H.; Minuchehr, A.; Zolfaghari, A.

    2017-03-01

    This paper focuses on a new direct simulation Monte Carlo (DSMC) code based on combinatorial geometry (CG) for simulation of any rarefied gas flow. The developed code, called DgSMC-A, has been supplied with an improved CG modeling able to significantly optimize the particle-tracking process, resulting in a highly reduced runtime compared to the conventional codes. The improved algorithm inserts a grid over the geometry and saves those grid elements containing some part of the geometry border. Since only a small part of a grid is engaged with the geometry border, significant time can be saved using the proposed algorithm. Embedding the modified algorithm in the DgSMC-A resulted in a fast, robust and self-governing code needless to any mesh generator. The code completely handles complex geometries created with first-and second-order surfaces. In addition, we developed a new surface area calculator in the CG methodology for complex geometries based on the Monte Carlo method with acceptable accuracy. Several well-known test cases are examined to indicate the code ability to deal with a wide range of realistic problems. Results are also found to be in good agreement with references and experimental data.