Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides.

PubMed

Shintani, Ryo; Duan, Wei-Liang; Hayashi, Tamio

2006-05-03

A rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to substituted maleimides has been described. The regioselectivity in this reaction is controlled by the choice of ligand (dienes or bisphosphines), and 1,4-adducts with a quaternary stereocenter can be obtained with high regio- and enantioselectivity by the use of (R)-H8-binap.

Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters

PubMed Central

Hong, Allen Y.; Bennett, Nathan B.; Krout, Michael R.; Jensen, Thomas; Harned, Andrew. M.

2011-01-01

General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoesters to form α-quaternary vinylogous esters. Recognition of the unusual reactivity of β-hydroxyketones resulting from the addition of hydride or organometallic reagents enabled divergent access to γ-quaternary acylcyclopentenes through a ring contraction pathway or γ-quaternary cycloheptenones through a carbonyl transposition pathway. Synthetic applications of these compounds were explored through the preparation of mono-, bi-, and tricyclic derivatives that can serve as valuable intermediates for the total synthesis of complex natural products. This work complements our previous work with cyclohexanoid systems. PMID:22347731

Antimicrobial activity of betaine esters, quaternary ammonium amphiphiles which spontaneously hydrolyze into nontoxic components.

PubMed Central

Lindstedt, M; Allenmark, S; Thompson, R A; Edebo, L

1990-01-01

A series of quaternary ammonium compounds that are esters of betaine and fatty alcohols with hydrocarbon chain lengths of 10 to 18 carbon atoms were tested with respect to antimicrobial activities and rates of hydrolysis. When the tetradecyl derivative was tested against some selected microorganisms, the killing effect was comparable to that of the stable quaternary ammonium compound cetyltrimethylammonium bromide. At higher pH values, both the antimicrobial effect and the rate of hydrolysis of the esters increased. However, whereas at pH 6 greater than 99.99% killing of Salmonella typhimurium was achieved with 5 micrograms/ml in 3 min, the rate of hydrolysis was less than 20% in 18 h. At pH 7, a similar killing effect was achieved in 2 min and 50% hydrolysis occurred in ca. 5 h. Thus, it is possible to exploit the rapid microbicidal effect of the compounds before they hydrolyze. The rate of hydrolysis was reduced by the presence of salt. The bactericidal effect of the betaine esters increased with the length of the hydrocarbon chain of the fatty alcohol moiety up to 18 carbon atoms. Since the hydrolysis products are normal human metabolites, the hydrolysis property may extend the use of these quaternary ammonium compounds as disinfectants and antiseptics for food and body surfaces. PMID:2291660

Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles

PubMed Central

Balaraman, Kaluvu; Wolf, Christian

2017-01-01

Synthetically versatile 3,3-disubstituted fluorooxindoles exhibiting vicinal chirality centers were obtained in high yields and with excellent enantio-, diastereo- and regioselectivity by catalytic asymmetric fluoroenolate alkylation with allylic acetates. The reaction proceeds under mild conditions and can be upscaled without compromising the asymmetric induction. The unique synthetic usefulness of the products is highlighted with the incorporation of additional functionalities and the formation of 3-fluorinated oxindoles exhibiting an array of four adjacent chirality centers. A new C-F bond functionalization path that provides unprecedented means for stereoselective generation of a chiral quaternary carbon center in the alkaloid scaffold is introduced. PMID:28026079

Relationship Between Carbon Dioxide Levels and Reported Congestion and Headaches on the International Space Station

NASA Technical Reports Server (NTRS)

Cole, Robert; Wear, Mary; Young, Millennia; Cobel, Christopher; Mason, Sara

2017-01-01

Congestion is commonly reported during spaceflight, and most crewmembers have reported using medications for congestion during International Space Station (ISS) missions. Although congestion has been attributed to fluid shifts during spaceflight, fluid status reaches equilibrium during the first week after launch while congestion continues to be reported throughout long duration missions. Congestion complaints have anecdotally been reported in relation to ISS CO2 levels; this evaluation was undertaken to determine whether or not an association exists. METHODS: Reported headaches, congestion symptoms, and CO2 levels were obtained for ISS expeditions 2-31, and time-weighted means and single-point maxima were determined for 24-hour (24hr) and 7-day (7d) periods prior to each weekly private medical conference. Multiple imputation addressed missing data, and logistic regression modeled the relationship between probability of reported event of congestion or headache and CO2 levels, adjusted for possible confounding covariates. The first seven days of spaceflight were not included to control for fluid shifts. Data were evaluated to determine the concentration of CO2 required to maintain the risk of congestion below 1% to allow for direct comparison with a previously published evaluation of CO2 concentrations and headache. RESULTS: This study confirmed a previously identified significant association between CO2 and headache and also found a significant association between CO2 and congestion. For each 1-mm Hg increase in CO2, the odds of a crew member reporting congestion doubled. The average 7-day CO2 would need to be maintained below 1.5 mmHg to keep the risk of congestion below 1%. The predicted probability curves of ISS headache and congestion curves appear parallel when plotted against ppCO2 levels with congestion occurring at approximately 1mmHg lower than a headache would be reported. DISCUSSION: While the cause of congestion is multifactorial, this study showed congestion is associated with CO2 levels on ISS. Data from additional expeditions could be incorporated to further assess this finding. CO2 levels are also associated with reports of headaches on ISS. While it may be expected for astronauts with congestion to also complain of headaches, these two symptoms are commonly mutually exclusive. Furthermore, it is unknown if a temporal CO2 relationship exists between congestion and headache on ISS. CO2 levels were time-weighted for 24hr and 7d, and thus the time course of congestion leading to headache was not assessed; however, congestion could be an early CO2-related symptom when compared to headache. Future studies evaluating the association of CO2-related congestion leading to headache would be difficult due to the relatively stable daily CO2 levels on ISS currently, but a systematic study could be implemented on-orbit if desired.

Changes in Quaternary Structure in the Signaling Mechanisms of PAS Domains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ayers, Rebecca A.; Moffat, Keith

2008-12-15

FixL from Bradyrhizobium japonicum is a PAS sensor protein in which two PAS domains covalently linked to a histidine kinase domain are responsible for regulating nitrogen fixation in an oxygen-dependent manner. The more C-terminal PAS domain, denoted bjFixLH, contains a heme cofactor that binds diatomic molecules such as carbon monoxide and oxygen and regulates the activity of the FixL histidine kinase as part of a two-component signaling system. We present the structures of ferric, deoxy, and carbon monoxide-bound bjFixLH in a new space group (P1) and at resolutions (1.5--1.8 {angstrom}) higher than the resolutions of those previously obtained. Interestingly, bjFixLHmore » can form two different dimers (in P1 and R32 crystal forms) in the same crystallization solution, where the monomers in one dimer are rotated {approx}175 deg. relative to the second. This suggests that PAS monomers are plastic and that two quite distinct quaternary structures are closely similar in free energy. We use screw rotation analysis to carry out a quantitative pairwise comparison of PAS quaternary structures, which identifies five different relative orientations adopted by isolated PAS monomers. We conclude that PAS monomer arrangement is context-dependent and could differ depending on whether the PAS domains are isolated or are part of a full-length protein. Structurally homologous residues comprise a conserved dimer interface. Using network analysis, we find that the architecture of the PAS dimer interface is continuous rather than modular; the network of residues comprising the interface is strongly connected. A continuous dimer interface is consistent with the low dimer-monomer dissociation equilibrium constant. Finally, we quantitate quaternary structural changes induced by carbon monoxide binding to a bjFixLH dimer, in which monomers rotate by up to 2 deg. relative to each other. We relate these changes to those in other dimeric PAS domains and discuss the role of quaternary structural changes in the signaling mechanisms of PAS sensor proteins.« less

High Performance Heteroatoms Quaternary-doped Carbon Catalysts Derived from Shewanella Bacteria for Oxygen Reduction.

PubMed

Guo, Zhaoyan; Ren, Guangyuan; Jiang, Congcong; Lu, Xianyong; Zhu, Ying; Jiang, Lei; Dai, Liming

2015-11-25

A novel heteroatoms (N, P, S and Fe) quaternary-doped carbon (HQDC-X, X refers to the pyrolysis temperature) can be fabricated by directly pyrolyzing a gram-negative bacteria, S. oneidensis MR-1 as precursors at 800 °C, 900 °C and 1000 °C under argon atmosphere. These HQDC-X catalysts maintain the cylindrical shape of bacteria after pyrolysis under high temperatures, while heteroatoms including N, P, S and Fe distribute homogeneously on the carbon frameworks. As a result, HQDC-X catalysts exhibit excellent electrocatalytic activity for ORR via a dominant four-electron oxygen reduction pathway in alkaline medium, which is comparable with that of commercial Pt/C. More importantly, HQDC-X catalysts show better tolerance for methanol crossover and CO poisoning effects, long-term durability than commercial Pt/C, which could be promising alternatives to costly Pt-based electrocatalysts for ORR. The method may provide a promising avenue to develop cheap ORR catalysts from inexpensive, scalable and biological recursors.

Nickel-Catalyzed Reductive Allylation of Tertiary Alkyl Halides with Allylic Carbonates.

PubMed

Chen, Haifeng; Jia, Xiao; Yu, Yingying; Qian, Qun; Gong, Hegui

2017-10-09

The construction of all C(sp 3 ) quaternary centers has been successfully achieved under Ni-catalyzed cross-electrophile coupling of allylic carbonates with unactivated tertiary alkyl halides. For allylic carbonates bearing C1 or C3 substituents, the reaction affords excellent regioselectivity through the addition of alkyl groups to the unsubstituted allylic carbon terminus. The allylic alkylation method also exhibits excellent functional-group compatibility, and delivers the products with high E selectivity. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fossil organic matter characteristics in permafrost deposits of the northeast Siberian Arctic

Treesearch

Lutz Schirrmeister; Guido Grosse; Sebastian Wetterich; Pier Paul Overduin; Jens Straub; Edward A.G. Schuur; Hans-Wolfgang Hubberton

2011-01-01

Permafrost deposits constitute a large organic carbon pool highly vulnerable to degradation and potential carbon release due to global warming. Permafrost sections along coastal and river bank exposures in NE Siberia were studied for organic matter (OM) characteristics and ice content. OM stored in Quaternary permafrost grew, accumulated, froze, partly decomposed, and...

Evaluating the reliability of Late Quaternary landform ages: Integrating 10Be cosmogenic surface exposure dating with U-series dating of pedogenic carbonate on alluvial and fluvial deposits, Sonoran desert, California

NASA Astrophysics Data System (ADS)

Blisniuk, K.; Sharp, W. D.

2015-12-01

To assess the reliability of Quaternary age determinations of alluvial and fluvial deposits across the Sonoran Desert (Coachella Valley and Anza Borrego) in southern California, we applied both 10Be exposure age dating of surface clasts and U-series dating of pedogenic carbonate from subsurface clast-coatings to the same deposits. We consider agreement between dates from the two techniques to indicate reliable age estimates because each technique is subject to distinct assumptions and therefore their systematic uncertainties are largely independent. 10Be exposure dates should yield maximum ages when no correction is made for inheritance and post-depositional erosion is negligible. U-series dating, in contrast, provides minimum dates because pedogenic carbonate forms after deposition. Our results show that: (1) For deposits ca. 70 ka or younger, 10Be and U-series dates were generally concordant. We note, however, that in most cases U-series soil dates exceed 10Be exposure dates that are corrected for inheritance when using 10Be in modern alluvium. This suggests that 10Be concentrations of modern alluvium may exceed the 10Be acquired by late Pleistocene deposits during fluvial transport and hillslope residence (i.e., Pleistocene inherited 10Be). (2) For deposits older than ~70 ka, U-series dates are significantly younger than the 10Be dates. This implies that U-series dates in this region may significantly underestimate the depositional age of older alluvium, probably because of delayed onset of deposition, slow accumulation, or poor preservation of secondary carbonate in response to climatic controls. Thus, whenever possible, multiple dating methods should be applied to obtain reliable ages for late Quaternary deposits.

An assessment of biodegradability of quaternary carbon-containing fragrance compounds: comparison of experimental OECD screening test results and in silico prediction data.

PubMed

Seyfried, Markus; Boschung, Alain

2014-05-01

An assessment of biodegradability was carried out for fragrance substances containing quaternary carbons by using data obtained from Organisation for Economic Co-operation and Development (OECD) 301F screening tests for ready biodegradation and from Biowin and Catalogic prediction models. Despite an expected challenging profile, a relatively high percentage of common-use fragrance substances showed significant biodegradation under the stringent conditions applied in the OECD 301F test. Among 27 test compounds, 37% met the pass level criteria after 28 d, while another 26% indicated partial breakdown (≥20% biodegradation). For several compounds for which structural analogs were available, the authors found that structures that were rendered less water soluble by either the presence of an acetate ester or the absence of oxygen tended to degrade to a lesser extent compared to the primary alcohols or oxygenated counterparts under the test conditions applied. Difficulties were encountered when attempting to correlate experimental with in silico data. Whereas the Biowin model combinations currently recommended by regulatory agencies did not allow for a reliable discrimination between readily and nonbiodegradable compounds, only a comparably small proportion of the chemicals studied (30% and 63% depending on the model) fell within the applicability domain of Catalogic, a factor that critically reduced its predictive power. According to these results, currently neither Biowin nor Catalogic accurately reflects the potential for biodegradation of fragrance compounds containing quaternary carbons. © 2014 SETAC.

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

PubMed Central

Gao, Fang; McGrath, Kevin P.; Lee, Yunmi; Hoveyda, Amir H.

2010-01-01

Catalytic enantioselective allylic substitution (EAS) reactions, which involve the use of alkyl- or aryl-substituted vinylaluminum reagents and afford 1,4-dienes containing a quaternary carbon stereogenic center at their C-3 site, are disclosed. The C–C bond forming transformations are promoted by 0.5–2.5 mol % of sulfonate bearing chiral bidentate N-heterocyclic carbene (NHC) complexes, furnishing the desired products efficiently (66–97% yield of isolated products) and in high site- (>98% SN2′) and enantioselectivity [up to 99:1 enantiomer ratio (er)]. To the best of our knowledge, the present report puts forward the first cases of allylic substitution reactions that result in the generation of all-carbon quaternary stereogenic centers through the addition of a vinyl unit. The aryl- and vinyl-substituted vinylaluminum reagents, which cannot be prepared in high efficiency through direct reaction with diisobutylaluminum hydride, are accessed through a recently introduced Ni-catalyzed reaction of the corresponding terminal alkynes with the same inexpensive metal-hydride agent. Sequential Ni-catalyzed hydrometallations and Cu-catalyzed C–C bond forming reactions allow for efficient and selective synthesis of a range of enantiomerically enriched EAS products, which cannot cannot be accessed by previously disclosed strategies (due to inefficient vinylmetal synthesis or low reactivity and/or selectivity with Si-substituted derivatives). The utility of the protocols developed is demonstrated through a concise enantioselective synthesis of natural product bakuchiol. PMID:20860365

Quaternary stratigraphy of Bermuda: A high-resolution pre-Sangamonian rock record

NASA Astrophysics Data System (ADS)

Hearty, Paul J.; Vacher, H. Leonard

Carbonate islands such as Bermuda are created by climatic change. Warm climates and high sea levels stimulate carbonate sediment production that may ultimately result in island growth, while cold glacials expose the platforms to weathering, dissolution and soil formation. Of great importance in Quaternary studies is the ability to decipher this climatic history. Mapping and geochronologic studies have established that Bermuda may have one of the most continuous and detailed Quaternary interglacial depositional records on a carbonate platform. Advances in racemization dating (AAR) have offered a means of deciphering this climatic history and generating a high-resolution stratigraphic and age framework for the Quaternary. Bermudian interglacial units consist predominantly of eolianites, with less voluminous occurrences of beach deposits and calcarenite protosols (Entisols). Glacial or stadial-age terra rossa (aluminous laterite) paleosols, whose degree of development is a function of time of exposure, form boundaries between interglacial units. D-alloiso-leucine/ L-isoleucine ( {A}/{I}) ratios have been determined on marine pelecypods, land snails and whole-rock samples from mapped sections; aminozones have been defined for two Sangamonian and at least five pre-Sangamonian depositional intervals. From kinetic models based on calibration with previously published U-series coral dates, estimated ages of middle Pleistocene and older aminozones are: F = 190,000-265,000 years; G = 300,000-400,000 years; H = 400,000-500,000 years; J = >700,000 years; and K = > 900,000 years. Aminozone G, which is correlated with the upper Town Hill Formation and Isotope Stage 9, is volumetrically the most important depositional event of the middle Pleistocene. The great mass of sediment deposited during this period suggests an interglacial of significant duration and prolonged shelf submergence, during which the island grew to over half its present size. Only the Sangamonian ( sensu lato) rivals Stage 9 in volume of eolianite deposited on the island. Sea-level amplitude, as determined from dated outcrops, appears to correlate well with amplitudinal variations in the oxygen isotope record.

Interplay of late Cenozoic siliciclastic supply and carbonate response on the southeast Florida platform

USGS Publications Warehouse

Cunningham, K.J.; Locker, S.D.; Hine, A.C.; Bukry, D.; Barron, J.A.; Guertin, L.A.

2003-01-01

High-resolution seismic-reflection data collected along the length of the Caloosahatchee River in southwestern Florida have been correlated to nannofossil biostratigraphy and strontium-isotope chemostratigraphy at six continuously cored boreholes. These data are interpreted to show a major Late Miocene(?) to Early Pliocene fluvial-deltaic depositional system that prograded southward across the carbonate Florida Platform, interrupting nearly continuous carbonate deposition since early in the Cretaceous. Connection of the platform top to a continental source of siliciclastics and significant paleotopography combined to focus accumulation of an immense supply of siliciclastics on the southeastern part of the Florida Platform. The remarkably thick (> 100 m), sand-rich depositional system, which is characterized by clinoformal progradation, filled in deep accommodation, while antecedent paleotopography directed deltaic progradation southward within the middle of the present-day Florida Peninsula. The deltaic depositional system may have prograded about 200 km southward to the middle and upper Florida Keys, where Late Miocene to Pliocene siliciclastic form the foundation of the Quaternary carbonate shelf and shelf margin of the Florida Keys. These far-traveled siliciclastic deposits filled accommodation on the southeastern part of the Florida Platform so that paleobathymetry was sufficiently shallow to allow Quaternary recovery of carbonate sedimentation in the area of southern peninsular Florida and the Florida Keys.

(Model) Peatlands in late Quaternary interglacials

NASA Astrophysics Data System (ADS)

Kleinen, Thomas; Brovkin, Victor

2016-04-01

Peatlands have accumulated a substantial amount of carbon, roughly 600 PgC, during the Holocene. Prior to the Holocene, there is relatively little direct evidence of peatlands, though coal deposits bear witness to a long history of peat-forming ecosystems going back to the Carboniferous. We therefore need to rely on models to investigate peatlands in times prior to the Holocene. We have developed a dynamical model of wetland extent and peat accumulation, integrated in the coupled climate carbon cycle model of intermediate complexity CLIMBER2-LPJ, in order to mechanistically model interglacial carbon cycle dynamics. This model consists of the climate model of intermediate complexity CLIMBER2 and the dynamic global vegetation model LPJ, which we have extended with modules to determine peatland extent and carbon accumulation. The model compares reasonably well to Holocene peat data. We have used this model to investigate the dynamics of atmospheric CO2 in the Holocene and two other late Quaternary interglacials, namely the Eemian, which is interesting due to its warmth, and Marine Isotope Stage 11 (MIS11), which is the longest interglacial during the last 500ka. We will also present model results of peatland extent and carbon accumulation for these interglacials. We will discuss model shortcomings and knowledge gaps currently preventing an application of the model to full glacial-interglacial cycles.

Quaternary FeCoNiMn-Based Nanocarbon Electrocatalysts for Bifunctional Oxygen Reduction and Evolution: Promotional Role of Mn Doping in Stabilizing Carbon

DOE PAGES

Gupta, Shiva; Zhao, Shuai; Wang, Xiao Xia; ...

2017-10-31

The intrinsic instability of carbon largely limits its use for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as a bifunctional catalyst in reversible fuel cells or water electrolyzers. In this paper, we discovered that Mn doping has a promotional role in stabilizing nanocarbon catalysts for the ORR/OER in alkaline media. Stable nanocarbon composites are derived from an inexpensive carbon/nitrogen precursor (i.e., dicyandiamide) and quaternary FeCoNiMn alloy via a template-free carbonization process. In addition to FeCoNiMn metal alloys/oxides, the carbon composites comprise substantial carbon tube forests growing on a thick and dense graphitic substrate. The dense carbon substratemore » with high degree of graphitization results from Mn doping, while active nitrogen-doped carbon tubes stem from FeCoNi. Catalyst structures and performance are greatly dependent on the doping content of Mn. Various accelerated stress tests (AST) and life tests verify the encouraging ORR/OER stability of the nanocarbon composite catalyst with optimal Mn doping. Extensive characterization before and after ASTs elucidates the mechanism of stability enhancement resulting from Mn doping, which is attributed to (i) hybrid carbon nanostructures with enhanced resistance to oxidation and (ii) the in situ formation of the β-MnO 2 and FeCoNi-based oxides capable of preventing carbon corrosion and promoting activity. Note that the improvement in stability due to Mn doping is accompanied by a slight activity loss due to a decrease in surface area. Finally, this work provides a strategy to stabilize carbon catalysts by appropriately integrating transition metals and engineering carbon structures.« less

Quaternary FeCoNiMn-Based Nanocarbon Electrocatalysts for Bifunctional Oxygen Reduction and Evolution: Promotional Role of Mn Doping in Stabilizing Carbon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gupta, Shiva; Zhao, Shuai; Wang, Xiao Xia

The intrinsic instability of carbon largely limits its use for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as a bifunctional catalyst in reversible fuel cells or water electrolyzers. In this paper, we discovered that Mn doping has a promotional role in stabilizing nanocarbon catalysts for the ORR/OER in alkaline media. Stable nanocarbon composites are derived from an inexpensive carbon/nitrogen precursor (i.e., dicyandiamide) and quaternary FeCoNiMn alloy via a template-free carbonization process. In addition to FeCoNiMn metal alloys/oxides, the carbon composites comprise substantial carbon tube forests growing on a thick and dense graphitic substrate. The dense carbon substratemore » with high degree of graphitization results from Mn doping, while active nitrogen-doped carbon tubes stem from FeCoNi. Catalyst structures and performance are greatly dependent on the doping content of Mn. Various accelerated stress tests (AST) and life tests verify the encouraging ORR/OER stability of the nanocarbon composite catalyst with optimal Mn doping. Extensive characterization before and after ASTs elucidates the mechanism of stability enhancement resulting from Mn doping, which is attributed to (i) hybrid carbon nanostructures with enhanced resistance to oxidation and (ii) the in situ formation of the β-MnO 2 and FeCoNi-based oxides capable of preventing carbon corrosion and promoting activity. Note that the improvement in stability due to Mn doping is accompanied by a slight activity loss due to a decrease in surface area. Finally, this work provides a strategy to stabilize carbon catalysts by appropriately integrating transition metals and engineering carbon structures.« less

Agricultural contaminants in Quaternary aquitards: A review of occurrence and fate in North America

NASA Astrophysics Data System (ADS)

Rodvang, S. J.; Simpkins, W. W.

2001-01-01

The intensity of agriculture has increased significantly during the past 30 years, resulting in increased detection of agricultural contaminants (nutrients, pesticides, salts, trace elements, and pathogens) in groundwater. Till, glaciolacustrine, and loess deposits of Quaternary age compose the most common surficial deposits underlying agricultural areas in North America. Quaternary aquitards generally contain higher concentrations of solid organic carbon (SOC, as much as 1.4%), dissolved organic carbon (DOC, as much as 205 mg/L), and reduced sulfur (as much as 0.9%) than do aquifers. Their potential to sorb pesticides increases with the percent of older SOC, because diagenesis increases Koc. Denitrification consistently reduces nitrate to non-detectable levels in unweathered Quaternary aquitards. Organic carbon of Quaternary age is a more labile electron donor than carbon from shale clasts. Pyrite is a more labile electron donor than carbon in many instances. Unweathered Quaternary aquitards provide a high degree of protection for underlying aquifers, due to their large reserves of SOC and reduced sulfur for sorption and denitrification, combined with their typically low hydraulic conductivity. In contrast, agricultural contaminants are common in weathered Quaternary aquitards. Lower reserves of reduced sulfur and sorptive/labile organic carbon, and a higher bulk K due to fractures, limit their ability to attenuate nitrate and pesticides. Subsurface drainage, which is common in Quaternary aquitards because of high water tables, bypasses the attenuation capacity of Quaternary aquitards and facilitates the transport of agricultural contaminants to surface water. Résumé. L'agriculture s'est significativement accrue au cours des dernières 30 années, provoquant une détection plus fréquente dans les eaux souterraines de contaminants agricoles (engrais, pesticides, sels, éléments en traces et germes pathogènes). Les moraines, les formations glacio-lacustres et les lœss d'âge quaternaire sont les dépôts superficiels les plus courants sur lesquels sont implantées les régions agricoles d'Amérique du Nord. Les imperméables quaternaires contiennent généralement des concentrations en carbone organique particulaire (COP), jusqu'à 1,4%, en carbone organique dissous, jusqu'à 205 mg/L et en soufre réduit, jusqu'à 0,9%, plus élevées que dans les aquifères. Leur potentiel à adsorber les pesticides augmente en même temps que le pourcentage en COP plus ancien, parce que la diagenèse fait croître KOC. La dénitrification réduit logiquement les nitrates à des niveaux non détectables dans les imperméables quaternaires non altérés. Le carbone organique d'âge quaternaire est un donneur d'électrons plus labile que le carbone des débris schisteux. La pyrite est un donneur d'électrons plus labile que le carbone dans de nombreux cas. Les imperméables quaternaires non altérés constituent une protection très efficace pour les aquifères sous-jacents, du fait de leur importante réserve en COP et en soufre réduit, qui interviennent dans la sorption et la dénitrification, et du fait de leur conductivité hydraulique typiquement faible. Au contraire, les contaminants agricoles sont communs dans les imperméables quaternaires altérés. Leur plus faible réserve en soufre réduit et en carbone organique labile impliqué dans la sorption, ainsi qu'une conductivité globale plus forte due aux fractures, limite leur aptitude à atténuer les nitrates et les pesticides. Le drainage souterrain, qui est courant dans les imperméables quaternaires à cause des niveaux élevés des nappes, court-circuite la capacité d'atténuation des imperméables quaternaires et facilite le transport des contaminants agricoles vers les eaux de surface. Resúmen. La intensidad de la agricultura ha aumentado de forma significativa durante los últimos 30 años, provocando una afección creciente de contaminantes de origen agrícola (tales como nutrientes, pesticidas, sales, elementos traza y patógenos) en las aguas subterráneas. Los depósitos cuaternarios de till, de origen glaciolacustre y de loess constituyen la mayor parte de los terrenos aprovechados desde el punto de vista agrícola en Norteamérica. Los acuitardos cuaternarios contienen normalmente concentraciones más elevadas que los acuíferos en carbono orgánico sólido (COS, con hasta un 1,4%), carbono orgánico disuelto (COD, hasta 205 mg/L) y sulfuro reducido (hasta un 0,9%). Su potencial para absorber pesticidas aumenta con el porcentaje de COS más antiguo, ya que la diagénesis incrementa el coeficiente de partición, Koc. El nitrato se reduce por denitrificación hasta alcanzar valores no detectables en acuitardos cuanternarios no meteorizados. El carbono orgánico de la Edad Cuaternaria es un dador de electrones más lábil que el carbono presente en los clastos de esquisto. La pirita es un dador de electrones más lábil que el carbono en muchas circunstancias. Los acuitardos no meteorizados del Cuaternario proporcionan un alto grado de protección para los acuíferos subyacentes, puesto que tienen grandes reservas de COS y sulfuro reducido para sorción y denitrificación, además de conductividades hidráulicas normalmente bajas. Por el contrario, los contaminantes agrícolas son más habituales en acuitardos meteorizados del Cuaternario, donde la capacidad para atenuar nitratos y pesticidas se ve limitada por unas reservas menores de sulfuro reducido y de carbono orgánico sorbible/lábil, así como por la elevada conductividad hidráulica promedio debido a las fracturas. El drenaje subsuperficial, que es común en los acuitardos cuaternarios que tienen niveles freáticos altos, evita la capacidad de atenuación propia de dichos acuitardos y facilita el transporte de los contaminantes de origen agrícola hacia las aguas superficiales.

Cerebral blood flow in patients with congestive heart failure treated with captopril.

PubMed

Paulson, O B; Jarden, J O; Godtfredsen, J; Vorstrup, S

1984-05-31

The effect of captopril on cerebral blood flow was studied in five patients with severe congestive heart failure and in five control subjects. Cerebral blood flow was measured by inhalation of 133xenon and registration of its uptake and washout from the brain by single photon emission computer tomography. In addition, cerebral (internal jugular) venous oxygen tension was determined in the controls. The measurements were made before and 15, 60, and 180 minutes after a single oral dose of captopril (6.25 mg in patients with congestive heart failure and 25 mg in controls). Despite a marked decrease in blood pressure, cerebral blood flow increased slightly in the patients with severe congestive heart failure. When a correction was applied to take account of a change in arterial carbon dioxide tension, however, cerebral blood flow was unchanged after captopril administration even in patients with the greatest decrease in blood pressure, in whom a decrease in cerebral blood flow might have been expected. In the controls, blood pressure was little affected by captopril, whereas a slight, but not statistically significant, decrease in cerebral blood flow was observed. The cerebral venous oxygen tension decreased concomitantly.

The Density and Compressibility of BaCO3-SrCO3-CaCO3-K2CO3-Na2CO3-Li2CO3 Liquids: New Measurements and a Systematic Trend with Cation Field Strength

NASA Astrophysics Data System (ADS)

Hurt, S. M.; Lange, R. A.; Ai, Y.

2015-12-01

The volumetric properties of multi-component carbonate liquids are required to extend thermodynamic models that describe partial melting of the deep mantle (e.g. pMELTS; Ghiorso et al., 2003) to carbonate-bearing lithologies. Carbonate in the mantle is an important reservoir of carbon, which is released to the atmosphere as CO2 through volcanism, and thus contributes to the carbon cycle. Although MgCO3 is the most important carbonate component in the mantle, it is not possible to directly measure the 1-bar density and compressibility of MgCO3 liquid because, like other alkaline-earth carbonates, it decomposes at a temperature lower than its melting temperature. Despite this challenge, Liu and Lange (2003) and O'Leary et al. (2015) showed that the one bar molar volume, thermal expansion and compressibility of the CaCO3 liquid component could be obtained by measuring the density and sound speeds of stable liquids in the CaCO3-Li2CO3-Na2CO3-K2CO3 quaternary system at one bar. In this study, this same strategy is employed on SrCO3- and BaCO3-bearing alkali carbonate liquids. The density and sound speed of seven liquids in the SrCO3-Li2CO3-Na2CO3-K2CO3 quaternary and three liquids in the BaCO3-Li2CO3-Na2CO3-K2CO3 quaternary were measured from 739-1367K, with SrCO3 and BaCO3 concentrations ranging from 10-50 mol%. The density measurements were made using the double-bob Archimedean method and sound speeds were obtained with a frequency-sweep acoustic interferometer. The molar volume and sound speed measurements were used to calculate the isothermal compressibility of each liquid, and the results show the volumetric properties mix ideally with composition. The partial molar volume and compressibility of the SrCO3 and BaCO3 components are compared to those obtained for the CaCO3 component as a function of cation field strength. The results reveal a systematic trend that allows the partial molar volume and compressibility of the MgCO3 liquid component to be estimated.

Soft antimicrobial agents: synthesis and activity of labile environmentally friendly long chain quaternary ammonium compounds.

PubMed

Thorsteinsson, Thorsteinn; Másson, Már; Kristinsson, Karl G; Hjálmarsdóttir, Martha A; Hilmarsson, Hilmar; Loftsson, Thorsteinn

2003-09-11

A series of soft quaternary ammonium antimicrobial agents, which are analogues to currently used quaternary ammonium preservatives such as cetyl pyridinium chloride and benzalkonium chloride, were synthesized. These soft analogues consist of long alkyl chain connected to a polar headgroup via chemically labile spacer group. They are characterized by facile nonenzymatic and enzymatic degradation to form their original nontoxic building blocks. However, their chemical stability has to be adequate in order for them to have antimicrobial effects. Stability studies and antibacterial and antiviral activity measurements revealed relationship between activity, lipophilicity, and stability. Their minimum inhibitory concentration (MIC) was as low as 1 microg/mL, and their viral reduction was in some cases greater than 6.7 log. The structure-activity studies demonstrate that the bioactive compounds (i.e., MIC for Gram-positive bacteria of <10 microg/mL) have an alkyl chain length between 12 and 18 carbon atoms, with a polar headgroup preferably of a small quaternary ammonium group, and their acquired inactivation half-life must be greater than 3 h at 60 degrees C.

Prussian blue caged in spongiform adsorbents using diatomite and carbon nanotubes for elimination of cesium.

PubMed

Hu, Baiyang; Fugetsu, Bunshi; Yu, Hongwen; Abe, Yoshiteru

2012-05-30

We developed a spongiform adsorbent that contains Prussian blue, which showed a high capacity for eliminating cesium. An in situ synthesizing approach was used to synthesize Prussian blue inside diatomite cavities. Highly dispersed carbon nanotubes (CNTs) were used to form CNT networks that coated the diatomite to seal in the Prussian blue particles. These ternary (CNT/diatomite/Prussian-blue) composites were mixed with polyurethane (PU) prepolymers to produce a quaternary (PU/CNT/diatomite/Prussian-blue), spongiform adsorbent with an in situ foaming procedure. Prussian blue was permanently immobilized in the cell walls of the spongiform matrix and preferentially adsorbed cesium with a theoretical capacity of 167 mg/g cesium. Cesium was absorbed primarily by an ion-exchange mechanism, and the absorption was accomplished by self-uptake of radioactive water by the quaternary spongiform adsorbent. Copyright © 2012 Elsevier B.V. All rights reserved.

Determination of trace quaternary ammonium surfactants in water by combining solid-phase extraction with surface-assisted laser desorption/ionization mass spectrometry.

PubMed

Chen, Y C; Sun, M C

2001-01-01

This study demonstrates the feasibility of combining solid-phase extraction (SPE) with surface-assisted laser desorption/ionization (SALDI) mass spectrometry to determine trace quaternary ammonium surfactants in water. The trace surfactants in water were directly concentrated on the surface of activated carbon sorbent in SPE. The activated carbon sorbent was then mixed with the SALDI liquid for SALDI analysis. No SPE elution procedure was necessary. Experimental results indicate that the surfactants with longer chain alkyl groups exhibit higher sensitivities than those with shorter chain alkyl groups in SPE-SALDI analysis. The detection limit for hexadecyltrimethylammonium bromide is around 10 ppt in SPE-SALDI analysis by sampling 100 mL of aqueous solution, while that of tetradecyltrimethylammonium bromide is about 100 ppt. The detection limit for decyltrimethylammonium bromide and dodecyltrimethylammonium bromide is in the low-ppb range. Copyright 2001 John Wiley & Sons, Ltd.

Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

NASA Astrophysics Data System (ADS)

Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

2016-06-01

Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration.

Anaerobic mineralization of quaternary carbon atoms: isolation of denitrifying bacteria on pivalic acid (2,2-dimethylpropionic acid).

PubMed

Probian, Christina; Wülfing, Annika; Harder, Jens

2003-03-01

The degradability of pivalic acid was established by the isolation of several facultative denitrifying strains belonging to Zoogloea resiniphila, to Thauera and Herbaspirillum, and to Comamonadaceae, related to [Aquaspirillum] and Acidovorax, and of a nitrate-reducing bacterium affiliated with Moraxella osloensis. Pivalic acid was completely mineralized to carbon dioxide. The catabolic pathways may involve an oxidation to dimethylmalonate or a carbon skeleton rearrangement, a putative 2,2-dimethylpropionyl coenzyme A mutase.

Perspectives on Proterozoic surface ocean redox from iodine contents in ancient and recent carbonate

NASA Astrophysics Data System (ADS)

Hardisty, Dalton S.; Lu, Zunli; Bekker, Andrey; Diamond, Charles W.; Gill, Benjamin C.; Jiang, Ganqing; Kah, Linda C.; Knoll, Andrew H.; Loyd, Sean J.; Osburn, Magdalena R.; Planavsky, Noah J.; Wang, Chunjiang; Zhou, Xiaoli; Lyons, Timothy W.

2017-04-01

The Proterozoic Eon hosted the emergence and initial recorded diversification of eukaryotes. Oxygen levels in the shallow marine settings critical to these events were lower than today's, although how much lower is debated. Here, we use concentrations of iodate (the oxidized iodine species) in shallow-marine limestones and dolostones to generate the first comprehensive record of Proterozoic near-surface marine redox conditions. The iodine proxy is sensitive to both local oxygen availability and the relative proximity to anoxic waters. To assess the validity of our approach, Neogene-Quaternary carbonates are used to demonstrate that diagenesis most often decreases and is unlikely to increase carbonate-iodine contents. Despite the potential for diagenetic loss, maximum Proterozoic carbonate iodine levels are elevated relative to those of the Archean, particularly during the Lomagundi and Shuram carbon isotope excursions of the Paleo- and Neoproterozoic, respectively. For the Shuram anomaly, comparisons to Neogene-Quaternary carbonates suggest that diagenesis is not responsible for the observed iodine trends. The baseline low iodine levels in Proterozoic carbonates, relative to the Phanerozoic, are linked to a shallow oxic-anoxic interface. Oxygen concentrations in surface waters would have at least intermittently been above the threshold required to support eukaryotes. However, the diagnostically low iodine data from mid-Proterozoic shallow-water carbonates, relative to those of the bracketing time intervals, are consistent with a dynamic chemocline and anoxic waters that would have episodically mixed upward and laterally into the shallow oceans. This redox instability may have challenged early eukaryotic diversification and expansion, creating an evolutionary landscape unfavorable for the emergence of animals.

Loess and its geomorphic, stratigraphic and paleoclimatic significance in the Quaternary

USGS Publications Warehouse

Muhs, Daniel R.

2013-01-01

Loess is aeolian silt visible in the field as a sedimentary body. It covers a significant portion of the land surface of the Earth. Loess thickness, particle size, and carbonate content decrease downwind from sources, useful trends for paleowinds. Many loess sections consist of relatively thick deposits of mostly unaltered sediment with intercalated paleosols. Paleosols represent periods of landscape stability when loess deposition slowed significantly. Loess in most regions was deposited during glacial periods and paleosols formed during interglacial periods. Loess has the potential to record the timing and environment of glacial–interglacial cycles of the Quaternary on many continents.

Surface modification and antimicrobial properties of cellulose nanocrystals

NASA Astrophysics Data System (ADS)

Bespalova, Yulia A.

Surface modification of cellulose nanocrystals (CNC) was performed by acetylation and subsequent reaction with various tertiary amines with different lengths of alkyl groups. Chloroacetic anhydride (95%) was used for acetylation. The acetylation of CNC was confirmed using IR spectroscopy. The bands associated with C=0 stretching (1740 cm-1) and C-Cl stretching (793 cm -1) was present in the acetylated CNC but they were absent in the neat CNC. It has been suggested that the primary hydroxyl groups of CNC are substituted by chloro acetyl groups during acetylation reaction. Subsequent reaction of chloro acetylated CNC with N, N - Dimethyl ethylamine, N, N - Dimethyl hexylamine, N, N - Dimethyl dodecylamine, N, N - Dimethyl hexadecylamine and N, N - Dimethyl decylamine formed quaternary ammonium salts. These quaternary ammonium salts were characterized by FTIR and solid state13C NMR spectroscopy. FTIR spectra of five types of quaternary ammonium salts of CNC are similar and they showed infrared bands at 2905 -1 and 2850 cm-1, attributed to symmetrical and unsymmetrical C-H stretching vibration. The absence of C-Cl band at 793 cm-1 proves that quaternary salt formation was successful. The 13C NMR spectrum of quaternary ammonium modified CNC with N, N - Dimethyl dodecylamine shows several additional resonances ranging from 14.5 ppm to 58.0 ppm when compared to 13C NMR spectrum of pure CNC. This evidence proves that long alkyl chains have been added to the pure CNC. The disc diffusion method confirmed that quaternary ammonium modified CNCs with a chain longer than ten carbons are effective antimicrobial agents against Staphylococcus aureus and E. coli bacteria. Pure CNC and quaternary ammonium modified CNCs with an alkyl chain length of ten or less were not able to inhibit bacteria growth.

The role of African dust in the formation of Quaternary soils on Mallorca, Spain and implications for the genesis of Red Mediterranean soils

USGS Publications Warehouse

Muhs, D.R.; Budahn, J.; Avila, A.; Skipp, G.; Freeman, J.; Patterson, D.

2010-01-01

African dust additions explain the origin of terra rossa soils that are common on the carbonate-platform island of Mallorca, Spain. Mineralogical and geochemical analyses indicate that Quaternary carbonate eolianites on Mallorca have a very high purity, usually composed of more than 90% carbonate minerals (calcite, dolomite, and aragonite). In contrast, terra rossa soils developed on these eolianites have lower carbonate contents and contain higher concentrations of quartz and other silicates. Analyses of immobile trace elements indicate that the non-carbonate fractions of the eolianites have distinctive Zr/Hf, La/Yb, Cr/Sc and Th/Ta values that differ from the superjacent terra rossa soils. These observations indicate that even if sufficient dissolution of the eolianite had taken place to create the soils by residual accumulation, immobile element ratios in the soils require an external source. However, Zr/Hf, La/Yb, Cr/Sc and Th/Ta values in the soils fall within the range of values for these element ratios in African dust collected on Barbados and mainland Spain. We conclude that the silicate fractions of terra rossa soils on Mallorca are derived mainly, though not wholly, from far-traveled African dust, and this process may explain the origin of other terra rossa soils found in southern Europe. ?? 2010.

A structural study of epoxidized natural rubber (ENR-50) and its cyclic dithiocarbonate derivative using NMR spectroscopy techniques.

PubMed

Hamzah, Rosniza; Bakar, Mohamad Abu; Khairuddean, Melati; Mohammed, Issam Ahmed; Adnan, Rohana

2012-09-12

A structural study of epoxidized natural rubber (ENR-50) and its cyclic dithiocarbonate derivative was carried out using NMR spectroscopy techniques. The overlapping (1)H-NMR signals of ENR-50 at δ 1.56, 1.68-1.70, 2.06, 2.15-2.17 ppm were successfully assigned. In this work, the <(13)C-NMR chemical shift assignments of ENR-50 were consistent to the previously reported work. A cyclic dithiocarbonate derivative of ENR-50 was synthesized from the reaction of purified ENR-50 with carbon disulfide (CS(2)), in the presence of 4-dimethylaminopyridine (DMAP) as catalyst at reflux temperature. The cyclic dithiocarbonate formation involved the epoxide ring opening of the ENR-50. This was followed by insertion of the C-S moiety of CS(2) at the oxygen attached to the quaternary carbon and methine carbon of epoxidized isoprene unit, respectively. The bands due to the C=S and C-O were clearly observed in the FTIR spectrum while the (1)H-NMR spectrum of the derivative revealed the peak attributed to the methylene protons had split. The (13)C-NMR spectrum of the derivative further indicates two new carbon peaks arising from the >C=S and quaternary carbon of cyclic dithiocarbonate. All other (1)H- and (13)C-NMR chemical shifts of the derivative remain unchanged with respect to the ENR-50.

Radiocarbon dating of individual lignin phenols: a new approach for establishing chronology of late quaternary lake sediments.

PubMed

Hou, Juzhi; Huang, Yongsong; Brodsky, Corynn; Alexandre, Marcelo R; McNichol, Ann P; King, John W; Hu, Feng Sheng; Shen, Ji

2010-09-01

The reliability of chronology is a prerequisite for meaningful paleoclimate reconstructions from sedimentary archives. The conventional approach of radiocarbon dating bulk organic carbon in lake sediments is often hampered by the old carbon effect, i.e., the assimilation of ancient dissolved inorganic carbon (DIC) derived from carbonate bedrocks or other sources. Therefore, radiocarbon dating is ideally performed on organic compounds derived from land plants that use atmospheric CO(2) and rapidly delivered to sediments. We demonstrate that lignin phenols isolated from lake sediments using reversed phase high performance liquid chromatography (HPLC) can serve as effective (14)C dating materials for establishing chronology during the late Quaternary. We developed a procedure to purify lignin phenols, building upon a published method. By isolating lignin from standard wood reference substances, we show that our method yields pure lignin phenols and consistent ages as the consensus ages and that our procedure does not introduce radiocarbon contamination. We further demonstrate that lignin phenol ages are compatible with varve counted and macrofossil dated sediment horizons in Steel Lake and Fayetteville Green Lake. Applying the new method to lake sediment cores from Lake Qinghai demonstrates that lignin phenol ages in Lake Qinghai are consistently younger than bulk total organic carbon (TOC) ages which are contaminated by old carbon effect. We also show that the age offset between lignin and bulk organic carbon differs at different Lake Qinghai sedimentary horizons, suggesting a variable hard water effect at different times and that a uniform age correction throughout the core is inappropriate.

Humans and intelligent vehicles : the hope, the help, and the harm.

DOT National Transportation Integrated Search

2016-03-01

Intelligent vehicles offer hope for a world in which crashes are rare, congestion is reduced, carbon emissions are decreased, and mobility is extended to a wider population. As long as humans are in the loop, over a half century of research in human ...

Alkynylation of heterocyclic compounds using hypervalent iodine reagent.

PubMed

Kamlar, M; Císařová, I; Veselý, J

2015-03-14

The alkynylation of various nitrogen- and/or sulphur-containing heterocyclic compounds using hypervalent iodine TMS-EBX by utilization of tertiary amines under mild conditions is described. The developed metal-free methodology furnishes the corresponding alkynylated heterocycles bearing quaternary carbon in high yields.

Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes.

PubMed

Denmark, Scott E; Wilson, Tyler W; Burk, Matthew T; Heemstra, John R

2007-12-05

Silyl ketene imines derived from a variety of alpha-branched nitriles have been developed as highly useful reagents for the construction of quaternary stereogenic centers via the aldol addition reaction. In the presence of SiCl4 and the catalytic action of chiral phosphoramide (R,R)-5, silyl ketene imines undergo extremely rapid and high yielding addition to a wide variety of aromatic aldehydes with excellent diastereo- and enantioselectivity. Of particular note is the high yields and selectivities obtained from electron-rich, electron-poor, and hindered aldehydes. The nitrile function serves as a useful precursor for further synthetic manipulation.

Scenario-based carbon footprint inventory tool for urban sustainable development decision support: The Cincinnati Case Study

EPA Science Inventory

Rapid growing of travel demand and transportation activities and co-occurring land use changes have resulted in traffic congestion and negative impacts on the environment, energy consumption and green house gas (GHG) emissions in an urban environment. The challenge lies in quanti...

Integrating Land Use and Socioeconomic Factors into Scenario-Based Travel Demand and Carbon Emission Impact Study

EPA Science Inventory

Urban sprawl continues since the last century, leading to a rapid increase in automobile ownership and vehicle travel demand, while resulting in more traffic congestion and automobile emissions. Land use, serving as a source of travel demand, can significantly impact travel behav...

Ultrasonic enhancement of the simultaneous removal of quaternary toxic organic dyes by CuO nanoparticles loaded on activated carbon: Central composite design, kinetic and isotherm study.

PubMed

Dashamiri, Somayeh; Ghaedi, Mehrorang; Dashtian, Kheibar; Rahimi, Mahmood Reza; Goudarzi, Alireza; Jannesar, Ramin

2016-07-01

Copper oxide nanoparticles loaded on activated carbon (CuO-NPs-AC) were prepared and fully analyzed and characterized with FE-SEM, XRD and FT-IR. Subsequently, this novel material was used for simultaneous ultrasound-assisted adsorption of brilliant green (BG), auramine O (AO), methylene blue (MB) and eosin yellow (EY) dyes. Problems regard to dyes spectra overlap in quaternary solution of this dyes were omitted by derivative spectrophotometric method. The best pH in quaternary system was studied by using one at a time method to achieved maximum dyes removal percentage. Subsequently, sonication time, adsorbent dosage and initial dyes concentrations influence on dyes removal was optimized by central composite design (CCD) combined with desirability function approach (DFA). Desirability score of 0.978 show optimum conditions set at sonication time (4.2 min), adsorbent mass (0.029 g), initial dyes concentration (4.5 mg L(-1)). Under this optimum condition the removal percentage for MB, AO, EY and BG dyes 97.58, 94.66, 96.22 and 94.93, respectively. The adsorption rate well fitted by pseudo second-order while adsorption capacity according to the Langmuir model as best equilibrium isotherm model for BG, MB, AO and EY was 20.48, 21.26, 22.34 and 21.29 mg g(-1), respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

Dynamic kinetic asymmetric transformation (DYKAT) by combined amine- and transition-metal-catalyzed enantioselective cycloisomerization.

PubMed

Zhao, Gui-Ling; Ullah, Farman; Deiana, Luca; Lin, Shuangzheng; Zhang, Qiong; Sun, Junliang; Ibrahem, Ismail; Dziedzic, Pawel; Córdova, Armando

2010-02-01

The first examples of one-pot highly chemo- and enantioselective dynamic kinetic asymmetric transformations (DYKATs) involving alpha,beta-unsaturated aldehydes and propargylated carbon acids are presented. These DYKATs, which proceed by a combination of catalytic iminium activation, enamine activation, and Pd(0)-catalyzed enyne cycloisomerization, give access to functionalized cyclopentenes with up to 99 % ee and can be used for the generation of all-carbon quaternary stereocenters.

Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

PubMed Central

Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

2016-01-01

Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration. PMID:27270486

Method and solvent composition for regenerating an ion exchange resin

DOEpatents

Even, William R.; Irvin, David J.; Irvin, Jennifer A.; Tarver, Edward E.; Brown, Gilbert M.; Wang, James C. F.

2002-01-01

A method and composition for removing perchlorate from a highly selective ion exchange resin is disclosed. The disclosed approach comprises treating the resin in a solution of super critical or liquid carbon dioxide and one or more quaternary ammonium chloride surfactant compounds.

Influence of temperature on nitrogen fate during hydrothermal carbonization of food waste.

PubMed

Wang, Tengfei; Zhai, Yunbo; Zhu, Yun; Peng, Chuan; Xu, Bibo; Wang, Tao; Li, Caiting; Zeng, Guangming

2018-01-01

The influence of temperature (180-260°C) on the fate of nitrogen during hydrothermal carbonization (HTC) of food waste (FW) was assessed. The distribution and evolution of nitrogen in aqueous products and bio-oil, as well as hydrochar, were conducted. Results suggested that elevated temperature enhanced the deamination and the highest ammonium concentration (929.75mg/L) was acquired at 260°C. At temperatures above 220°C, the total N in the hydrochar became stable, whereas the mass percentage of N increased. Amines and heterocyclic-N compounds from protein cracking and Maillard reactions were identified as the main nitrogen-containing compounds in the bio-oil. As to the hydrochar, increasing temperature resulted in condensed nitrogen-containing aromatic heterocycles (e.g. pyridine-N and quaternary-N). In particular, remarkable Maillard reactions at 180°C and the highest temperature at 260°C enhanced nitrogen incorporation (i.e. quaternary-N) into hydrochar. Copyright © 2017 Elsevier Ltd. All rights reserved.

Radiocarbon dating of terrestrial carbonates

USGS Publications Warehouse

Pigati, Jeffrey S.; Rink, W. Jack; Thompson, Jeroen

2014-01-01

Terrestrial carbonates encompass a wide range of materials that potentially could be used for radiocarbon (14C) dating. Biogenic carbonates, including shells and tests of terrestrial and aquatic gastropods, bivalves, ostracodes, and foraminifera, are preserved in a variety of late Quaternary deposits and may be suitable for 14C dating. Primary calcareous deposits (marls, tufa, speleothems) and secondary carbonates (rhizoliths, fracture fill, soil carbonate) may also be targeted for dating when conditions are favorable. This chapter discusses issues that are commonly encountered in 14C dating of terrestrial carbonates, including isotopic disequilibrium and open-system behavior, as well as methods used to determine the reliability of ages derived from these materials. Recent methodological advancements that may improve the accuracy and precision of 14C ages of terrestrial carbonates are also highlighted.

In situ analysis of corrosion inhibitors using a portable mass spectrometer with paper spray ionization.

PubMed

Jjunju, Fred P M; Li, Anyin; Badu-Tawiah, Abraham; Wei, Pu; Li, Linfan; Ouyang, Zheng; Roqan, Iman S; Cooks, R Graham

2013-07-07

Paper spray (PS) ambient ionization is implemented using a portable mass spectrometer and applied to the detection of alkyl quaternary ammonium salts in a complex oil matrix. These salts are commonly used as active components in the formulation of corrosion inhibitors. They were identified in oil and confirmed by their fragmentation patterns recorded using tandem mass spectrometry (MS/MS). The cations of alkyl and benzyl-substituted quaternary ammonium salts showed characteristic neutral losses of CnH2n (n carbon number of the longest chain) and C7H8, respectively. Individual quaternary ammonium compounds were detected at low concentrations (<1 ng μL(-1)) and over a dynamic range of ∼5 pg μL(-1) to 500 pg μL(-1) (ppb). Direct detection of these compounds in complex oil samples without prior sample preparation or pre-concentration was also demonstrated using a home-built miniature mass spectrometer at levels below 1 ng μL(-1).

Strengthened PAN-based carbon fibers obtained by slow heating rate carbonization.

PubMed

Kim, Min-A; Jang, Dawon; Tejima, Syogo; Cruz-Silva, Rodolfo; Joh, Han-Ik; Kim, Hwan Chul; Lee, Sungho; Endo, Morinobu

2016-03-23

Large efforts have been made over the last 40 years to increase the mechanical strength of polyacrylonitrile (PAN)-based carbon fibers (CFs) using a variety of chemical or physical protocols. In this paper, we report a new method to increase CFs mechanical strength using a slow heating rate during the carbonization process. This new approach increases both the carbon sp(3) bonding and the number of nitrogen atoms with quaternary bonding in the hexagonal carbon network. Theoretical calculations support a crosslinking model promoted by the interstitial carbon atoms located in the graphitic interlayer spaces. The improvement in mechanical performance by a controlled crosslinking between the carbon hexagonal layers of the PAN based CFs is a new concept that can contribute further in the tailoring of CFs performance based on the understanding of their microstructure down to the atomic scale.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paulson, O.B.; Jarden, J.O.; Godtfredsen, J.

The effect of captopril on cerebral blood flow was studied in five patients with severe congestive heart failure and in five control subjects. Cerebral blood flow was measured by inhalation of /sup 133/xenon and registration of its uptake and washout from the brain by single photon emission computer tomography. In addition, cerebral (internal jugular) venous oxygen tension was determined in the controls. The measurements were made before and 15, 60, and 180 minutes after a single oral dose of captopril (6.25 mg in patients with congestive heart failure and 25 mg in controls). Despite a marked decrease in blood pressure,more » cerebral blood flow increased slightly in the patients with severe congestive heart failure. When a correction was applied to take account of a change in arterial carbon dioxide tension, however, cerebral blood flow was unchanged after captopril administration even in patients with the greatest decrease in blood pressure, in whom a decrease in cerebral blood flow might have been expected. In the controls, blood pressure was little affected by captopril, whereas a slight, but not statistically significant, decrease in cerebral blood flow was observed. The cerebral venous oxygen tension decreased concomitantly.« less

Mild rhodium(iii)-catalyzed intramolecular annulation of benzamides with allylic alcohols to access azepinone derivatives.

PubMed

Peneau, Augustin; Tricart, Quentin; Guillou, Catherine; Chabaud, Laurent

2018-05-23

Azepinone derivatives are important frameworks of several natural products and bioactive compounds. They are synthetized using a Rh(iii)-catalyzed intramolecular annulation of benzamide-tethered allylic alcohols. The reaction requires mild conditions at room temperature and affords diversely substituted azepinones bearing a quaternary carbon.

Concise Synthesis of (-)-Hodgkinsine, (-)-Calycosidine, (-)-Hodgkinsine B, (-)-Quadrigemine C, and (-)-Psycholeine via Convergent and Directed Modular Assembly of Cyclotryptamines.

PubMed

Lindovska, Petra; Movassaghi, Mohammad

2017-12-06

The enantioselective total synthesis of (-)-hodgkinsine, (-)-calycosidine, (-)-hodgkinsine B, (-)-quadrigemine C, and (-)-psycholeine through a diazene-directed assembly of cyclotryptamine fragments is described. Our synthetic strategy enables multiple and directed assembly of intact cyclotryptamine subunits for convergent synthesis of highly complex bis- and tris-diazene intermediates. Photoextrusion of dinitrogen from these intermediates enables completely stereoselective formation of all C3a-C3a' and C3a-C7' carbon-carbon bonds and all the associated quaternary stereogenic centers. In a representative example, photoextrusion of three dinitrogen molecules from an advanced intermediate in a single-step led to completely controlled introduction of four quaternary stereogenic centers and guided the assembly of four cyclotryptamine monomers en route to (-)-quadrigemine C. The synthesis of these complex diazenes was made possible through a new methodology for synthesis of aryl-alkyl diazenes using electronically attenuated hydrazine-nucleophiles for a silver-promoted addition to C3a-bromocyclotryptamines. The application of Rh- and Ir-catalyzed C-H amination reactions in complex settings were used to gain rapid access to C3a- and C7-functionalized cyclotryptamine monomers, respectively, used for diazene synthesis. This convergent and modular assembly of intact cyclotryptamines offers the first solution to access these alkaloids through completely stereoselective union of monomers at challenging linkages and the associated quaternary stereocenters as illustrated in our synthesis of five members of the oligocyclotryptamine family of alkaloids.

A phosphine mediated sequential annulation process of 2-tosylaminochalcones with MBH carbonates to construct functionalized aza-benzobicyclo[4.3.0] derivatives.

PubMed

Zhang, Qinglong; Zhu, Yannan; Jin, Hongxing; Huang, You

2017-04-04

A novel phosphine mediated sequential annulation process to construct functionalized aza-benzobicyclo[4.3.0] derivatives has been developed involving a one-pot sequential catalytic and stoichiometric process, which generates a series of benzobicyclo[4.3.0] compounds containing one quaternary center with up to 94% yield and 20 : 1 dr value. In this reaction, MBH carbonates act as 1,2,3-C 3 synthons.

Radiolarian Indices of Paleoproductivity Variation in the late Pleistocene Benguela Upwelling System, ODP Site 1084

NASA Astrophysics Data System (ADS)

Bittniok, B. B.; Lazarus, D. B.; Diester-Haass, L.; Billups, K.; Meyers, P.

2006-12-01

Changes in export productivity play a significant role in ocean carbon budgets and global climate change. Proxies for export productivity can be difficult to interpret: benthic foraminifera accumulation rates (BFAR) can be affected by carbonate dissolution in organic-carbon rich sediments; bulk opal can be affected by silica limitation of source waters. Recent work (Lazarus et al. 2006; Mar. Micropal.) has shown that a new index based on radiolarian faunal changes (WADE ratio) correlates well to total organic carbon (TOC) values from the same samples over the long term (latest Miocene-Recent) history of productivity in the Benguela Upwelling System (BUS). We present new data on variation in export productivity proxies (WADE, TOC, carbonate, radiolarian opal, BFAR) for the last glacial-interglacial cycle from ODP Site 1084, located just offshore from the main coastal upwelling cells of the BUS. Our age model, from mean Quaternary sedimentation rates (Leg 175 Scientific Results), is in accordance with cyclic variation in other climate sensitive parameters (carbonate and color reflectance). Although opal content and radiolarian preservation is only moderate in our samples, WADE values vary significantly and suggest higher productivity during the last glacial, in accordance with current interpretations of BUS history. Radiolarian opal accumulation is also higher during the last glacial, suggesting that silica limitation (opal paradox) conditions did not dominate over this time period. Similar results for bulk opal have been reported from late Quaternary piston cores from the more northerly Congo upwelling region (Schneider et al, 1997; Paleoc.). We conclude that WADE ratios are a useful proxy for late Pleistocene productivity in the BUS at glacial- interglacial time scales.

Multi-proxy approach for palaeoclimate reconstruction using a loess-palaeosol sequence from Süttő , Hungary

NASA Astrophysics Data System (ADS)

Thiel, Christine; Königer, Paul; Ostertag-Henning, Christian; Scheeder, Georg; Novothny, Ágnes; Horváth, Erzsébet; Wacha, Lara; Techmer, Astrid; Frechen, Manfred

2010-05-01

The loess-palaeosol sequence at Süttő , Hungary contains a high-resolution terrestrial archive of palaeoenvironmental changes. The sequence is about 20 m thick and overlies travertine which was dated using Uranium-series to 235-314 ka (Sierralta et al., in press). Imbedded with the loess are two greyish stratified horizons, three brownish steppe-like soils and a pedocomplex composed of a reddish-brown palaeosol covered by a chernozem. Detailed dating studies were carried out (Novothny et al, 2009, Novothny et al., in press) revealing more or less continuous sedimentation from marine isotope stage (MIS) 6 to MIS 2. High-resolution grain size and magnetic susceptibility data exist (Novothny et al., in prep.) which allow for palaeoenvironmental reconstructions. In addition to those data sets we analysed the carbon and oxygen isotopic composition of bulk carbonate, carbonate nodules, and organic material in order to get further insight into palaeoprecipitation and palaeoclimatic conditions. To strengthen the interpretation based on isotopic data, we examined biomarkers derived from land plants (long-chain n-alkanes) for both loess and palaeosols to add information on the vegetation changes. We will discuss the new results in comparison with the published data sets and highlight inherent problems of the individual approaches. Novothny, A., Frechen, M., Horváth, E., Wacha, L., Rolf, C., in prep. High resolution grain size and magnetic susceptibility record of the last glacial cycles in the Süttő loess section, Hungary. Quaternary International. Novothny, A., Frechen, M., Horváth, E., Krbetschek, M., Tsukamoto, S., in press. Infrared stimulated luminescence and radiofluorescence dating of aeolian sediments from Hungary. Quaternary Geochronology, doi:10.1016/j.quageo.2009.05.002. Novothny, A., Frechen, M., Horváth, E., Bradák, B., Oches, E. A., McCoy, W. D., Stevens, T., 2009a. Luminescence and amino acid racemisation chronology of the loess-paleosol sequence at Süttő , Hungary. Quaternary International 198, 62-76. Sierralta, M., Kele, S., Melcher, F., Hambach, U., Reinders, J., van Geldern, R., Frechen, M., in press. Uranium-series dating of travertine from Süttő : Implications for reconstruction of environmental change in Hungary. Quaternary International, doi:10.1016/j.quaint.2009.04.004.

Strengthened PAN-based carbon fibers obtained by slow heating rate carbonization

PubMed Central

Kim, Min-A; Jang, Dawon; Tejima, Syogo; Cruz-Silva, Rodolfo; Joh, Han-Ik; Kim, Hwan Chul; Lee, Sungho; Endo, Morinobu

2016-01-01

Large efforts have been made over the last 40 years to increase the mechanical strength of polyacrylonitrile (PAN)-based carbon fibers (CFs) using a variety of chemical or physical protocols. In this paper, we report a new method to increase CFs mechanical strength using a slow heating rate during the carbonization process. This new approach increases both the carbon sp3 bonding and the number of nitrogen atoms with quaternary bonding in the hexagonal carbon network. Theoretical calculations support a crosslinking model promoted by the interstitial carbon atoms located in the graphitic interlayer spaces. The improvement in mechanical performance by a controlled crosslinking between the carbon hexagonal layers of the PAN based CFs is a new concept that can contribute further in the tailoring of CFs performance based on the understanding of their microstructure down to the atomic scale. PMID:27004752

Coupling δ18O values of rodent tooth and mollusc shell carbonates: a new approach to reconstructing Pleistocene palaeotemperatures?

NASA Astrophysics Data System (ADS)

Peneycad, Elizabeth; Candy, Ian; Schreve, Danielle

2017-04-01

The ratio of stable oxygen isotopes in fossil rodent teeth (δ18Ort) can potentially provide valuable quantitative information about terrestrial palaeoclimate conditions. Grimes et al. (2004) suggested that δ18Ort could be usefully combined with the δ18O values of coeval biominerals, e.g. mollusc shells (δ18Oms), to estimate past summer temperatures during the Quaternary period. Nevertheless, until now, the application of this approach to Quaternary palaeoclimate reconstruction has remained unexplored. In addition, the success of this approach is dependent upon the establishment of a statistically robust relationship between δ18Ort and the δ18O of meteoric water (δ18Omw) in the modern environment. However, such a relationship is yet to be quantified in relation to rodent tooth carbonate. Here, we present the preliminary results of 2 studies investigating the validity of δ18Ort as a climate proxy. Firstly, isotope analyses were undertaken on modern vole (Microtus agrestis) teeth from 3 locations across the UK. The results of these analyses reveal a significant linear correlation between the mean δ18Ort and the mean δ18Omw. These findings therefore demonstrate that a quantifiable relationship exists between δ18Ort and δ18Omw, highlighting the potential of δ18Ort as an accurate recorder of local climatic conditions. This modern relationship was subsequently applied to the reconstruction of past δ18Omw values for two Pleistocene interglacial sites in the UK. The δ18Omw values were calculated using δ18Ort, and then combined with δ18Oms values derived from coeval fossil gastropod assemblages in order to estimate mean summer palaeotemperatures. The results of these calculations are in close agreement with multi-proxy temperature reconstructions derived from the same deposits. This suggests that coupling the δ18O values of rodent tooth and mollusc shell carbonates offers great potential as an approach to quantifying summer palaeotemperatures in Europe, particularly for carbonate-rich sites at which alternative temperature proxies may be unavailable. References: Grimes, S.T., Mattey, D.P., Collinson, M.E. & Hooker, J.J. (2004) Using mammal tooth phosphate with freshwater carbonate and phosphate palaeoproxies to obtain mean paleotemperatures. Quaternary Science Reviews, 23, pp.967-976.

Liquid-liquid distribution of ion associates of tetrabromoindate(III) with quaternary ammonium counter ions.

PubMed

Yamamoto, K; Matsumoto, A

1997-11-01

The solvent extraction of an ion associate of tetrabromoindate(III) ion, InBr(-)(4), with quaternary ammonium cations (Q(+)) has been studied. The extraction constant (K(ex)) were determined for the ion associates of InBr(-)(4) with Q(+) between an aqueous phase and several organic phases (chloroform, chlorobenzene, benzene and toluene). A linear relationship was found between log K(ex) and the total number of carbon atoms in Q(+); from the slope of the lines, the contribution of a methylene group to log K(ex) was calculated to be 0.91 for the chloroform extraction system and 0.52 for the other extraction systems. The extractability with alkyltrimethylammonium cations was larger than that with symmetrical tetraalkylammonium cations and the mean difference in log K(ex) for two cations (one of each type) with the same number of carbon atoms was about 1.3. From the extraction constant obtained, the extractability of InBr(-)(4) among metal-halogeno complex anions was in the order TlBr(-)(4) > BiI(-)(4) > AuBr(-)(4) > AuCl(-)(4) > TlCl(-)(4) > InBr(-)(4) > CuCl(-)(2).

Low Temperature Double-Layer Capacitors Using Asymmetric and Spiro-Type Quaternary Ammonium Salts

NASA Technical Reports Server (NTRS)

Smart, Marshall C. (Inventor); Brandon, Erik J. (Inventor); West, William C. (Inventor)

2014-01-01

Double-layer capacitors capable of operating at extremely low temperatures (e.g., as low as -80.degree. C.) are disclosed. Electrolyte solutions combining a base solvent (e.g., acetonitrile) and a cosolvent are employed to lower the melting point of the base electrolyte. Example cosolvents include methyl formate, ethyl acetate, methyl acetate, propionitrile, butyronitrile, and 1,3-dioxolane. A quaternary ammonium salt including at least one of triethylmethylammonium tetrafluoroborate (TEMATFB) and spiro-(1,1')-bipyrrolidium tetrafluoroborate (SBPBF.sub.4), is used in an optimized concentration (e.g., 0.10 M to 0.75 M), dissolved into the electrolyte solution. Conventional device form factors and structural elements (e.g., porous carbon electrodes and a polyethylene separator) may be employed.

Random quaternary ammonium Diels-Alder poly(phenylene) copolymers for improved vanadium redox flow batteries

NASA Astrophysics Data System (ADS)

Largier, Timothy D.; Cornelius, Chris J.

2017-06-01

This study analyzes the effect of quaternary ammonium homopolymer (AmPP) and ionic and non-ionic random unit copolymerization (AmPP-PP) of Diels-Alder poly(phenylene)s on electrochemical and transport properties, vanadium redox flow battery performance, and material stability. AmPP-PP materials were synthesized with IEC's up to 2.2 meq/g, displaying a carbonate form ion conductivity of 17.3 mS/cm and water uptake of 57.3%. Vanadium ion permeability studies revealed that the random copolymers possess superior charge carrier selectivity. For materials of comparable ion content, at 10 mA/cm2 the random copolymer displayed a 14% increase in coulombic efficiency (CE) corresponding to a 7% increase in energy efficiency. All quaternary ammonium materials displayed ex situ degradation in a 0.5 M V5+ + 5 M H2SO4 solution, with the rate of degradation appearing to increase with IEC. Preliminary studies reveal that the neutralizing counter-ion has a significant effect on VRB performance, proportional to changes in vanadium ion molecular diffusion.

Origin of Bermuda's clay-rich Quaternary paleosols and their paleoclimatic significance

USGS Publications Warehouse

Herwitz, S.R.; Muhs, D.R.; Prospero, J.M.; Mahan, S.; Vaughn, B.

1996-01-01

Red clayey paleosols that are chiefly the product of aerosolic dust deposition are interbedded in the Quaternary carbonate formations of the Bermuda oceanic island system. These paleosols provide a basis for reconstructing Quaternary atmospheric circulation patterns in the northwestern Atlantic. Geochemical analyses were performed on representative paleosol samples to identify their parent dust source. Fine-grained fractions were analyzed by energy-dispersive X ray fluorescence to determine trace element (Zr, Y, La, Ti, and Nb) concentrations and to derive geochemical signatures based on immobile element ratios. These ratios were compared with geochemical signatures determined for three possible sources of airborne dust: (1) Great Plains loess, (2) Mississippi River Valley loess, and (3) Saharan dust. The Zr/Y and Zr/La ratios provided the clearest distinction between the hypothesized dust sources. The low ratios in the paleosol B horizons most closely resemble Saharan dust in the <2-??m size class fraction. Contributions from the two North American loessial source areas could not be clearly detected. Thus Bermuda paleosols have a predominantly Saharan aerosolic dust signature. Saharan dust deposition on Bermuda during successive Quaternary glacial periods is consistent with patterns of general circulation models, which indicate that during glacial maxima the northeast summer trade winds were stronger than at present and reached latitudes higher than 30 ?? N despite lower-than-present sea surface temperatures in the North Atlantic.

Geochemical evidence of Saharan dust parent material for soils developed on Quaternary limestones of Caribbean and western Atlantic islands

USGS Publications Warehouse

Muhs, D.R.; Bush, C.A.; Stewart, K.C.; Rowland, T.R.; Crittenden, R.C.

1990-01-01

Most previous workers have regarded the insoluble residues of high-purity Quaternary limestones (coral reefs and oolites) as the most important parent material for well-developed, clay-rich soils on Caribbean and western Atlantic islands, but this genetic mechanism requires unreasonable amounts of limestone solution in Quaternary time. Other possible parent materials from external sources are volcanic ash from the Lesser Antilles island arc and Saharan dust carried across the Atlantic Ocean on the northeast trade winds. Soils on Quaternary coral terraces and carbonate eolianites on Barbados, Jamaica, the Florida Keys (United States), and New Providence Island (Bahamas) were studied to determine which, if either, external source was important. Caribbean volcanic ashes and Saharan dust can be clearly distinguished using ratios of relatively immobile elements ( Al2O3 TiO2, Ti Y, Ti Zr, and Ti Th). Comparison of these ratios in 25 soils, where estimated ages range from 125,000 to about 870,000 yr, shows that Saharan dust is the most important parent material for soils on all islands. These results indicate that the northeast trade winds have been an important component of the regional climatology for much of the Quaterary. Saharan dust may also be an important parent material for Caribbean island bauxites of much greater age. ?? 1990.

Aqueous biphasic systems containing PEG-based deep eutectic solvents for high-performance partitioning of RNA.

PubMed

Zhang, Hongmei; Wang, Yuzhi; Zhou, Yigang; Xu, Kaijia; Li, Na; Wen, Qian; Yang, Qin

2017-08-01

In this work, 16 kinds of novel deep eutectic solvents (DESs) composed of polyethylene glycol (PEG) and quaternary ammonium salts, were coupled with Aqueous Biphasic Systems (ABSs) to extract RNA. The phase forming ability of ABSs were comprehensively evaluated, involving the effects of various proportions of DESs' components, carbon chain length and anions species of quaternary ammonium salts, average molecular weights of PEG and inorganic salts nature. Then the systems were applied in RNA extraction, and the results revealed that the extraction efficiency values were distinctly enhanced by relatively lower PEG content in DESs, smaller PEG molecular weights, longer carbon chain of quaternary ammonium salts and more hydrophobic inorganic salts. Then the systems composed of [TBAB][PEG600] and Na 2 SO 4 were utilized in the influence factor experiments, proving that the electrostatic interaction was the dominant force for RNA extraction. Therefore, back-extraction efficiency values ranging between 85.19% and 90.78% were obtained by adjusting the ionic strength. Besides, the selective separation of RNA and tryptophane (Trp) was successfully accomplished. It was found that 86.19% RNA was distributed in the bottom phase, while 72.02% Trp was enriched in the top phase in the novel ABSs. Finally, dynamic light scattering (DLS) and transmission electron microscope (TEM) were used to further investigate the extraction mechanism. The proposed method reveals the outstanding feasibility of the newly developed ABSs formed by PEG-based DESs and inorganic salts for the green extraction of RNA. Copyright © 2017 Elsevier B.V. All rights reserved.

Asymmetric organocatalyzed Michael addition of nitromethane to a 2-oxoindoline-3-ylidene acetaldehyde and the three one-pot sequential synthesis of (-)-horsfiline and (-)-coerulescine.

PubMed

Mukaiyama, Takasuke; Ogata, Kento; Sato, Itaru; Hayashi, Yujiro

2014-10-13

(-)-Horsfiline and (-)-coerulescine were synthesized through three one-pot operations in 33 and 46% overall yield, respectively. Key to the success was the efficient use of a diarylprolinol silyl ether to catalyze the asymmetric Michael addition of nitromethane to a 2-oxoindoline-3-ylidene acetaldehyde. This allowed the all-carbon quaternary, spirocyclic carbon stereocenter to be constructed in good yield with excellent enantioselectivity. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The 87Sr/86Sr ratios of lacustrine carbonates and lake-level history of the Bonneville paleolake system

USGS Publications Warehouse

Hart, W.S.; Quade, Jay; Madsen, D.B.; Kaufman, D.S.; Oviatt, Charles G.

2004-01-01

Lakes in the Bonneville basin have fluctuated dramatically in response to changes in rainfall, temperature, and drainage diversion during the Quaternary. We analyzed tufas and shells from shorelines of known ages in order to develop a relation between 87Sr/86Sr ratio of carbonates and lake level, which then can be used as a basis for constraining lake level from similar analyses on carbonates in cores. Carbonates from the late Quaternary shorelines yield the following average 87Sr/86Sr ratios: 0.71173 for the Stansbury shoreline (22-20 14C ka; 1350 m), 0.71153 for the Bonneville shoreline (15.5-14.5 14C ka; 1550 m), 0.71175 for the Provo shoreline (14.4-14.0 14C ka; 1450 m), 0.71244 for the Gilbert shoreline (???10.3-10.9 14C ka; 1300 m), and 0.71469 for the modern Great Salt Lake (1280 m). These analyses show that the 87Sr/86Sr ratio of lacustrine carbonates changes substantially at low- to mid-lake levels but is invariant at mid- to high-lake levels. Sr-isotope mixing models of Great Salt Lake and the Bonneville paleolake system were constructed to explain these variations in 87Sr/86Sr ratios with change in lake level. Our model of the Bonneville system produced a 87Sr/86Sr ratio of 0.71193, very close to the observed ratios from high-shoreline tufa and shell. The model verifies that the integration of the southern Sevier and Beaver rivers with the Bear and others rivers in the north is responsible for the lower 87Sr/86Sr ratios in Lake Bonneville compared to the modern Great Salt Lake. We also modeled the 87Sr/86Sr ratio of Lake Bonneville with the upper Bear River diverted into the Snake River basin and obtained an 87Sr/86Sr ratio of 0.71414. Coincidentally, this ratio is close to the observed ratio for Great Salt Lake of 0.71469. This means that 87Sr/86Sr ratios of >0.714 for carbonate can be produced by climatically induced low-lake conditions or by diversion of the upper Bear River out of the Bonneville basin. This model result also demonstrates that the upper Bear River had to be flowing into the Bonneville basin during highstands of other late Quaternary lake cycles: carbonates from the Little Valley (130-160 ka) and Cutler Dam (59 ?? 5 ka) lake cycles returned 87Sr/86Sr ratios of 0.71166 and 0.71207, respectively, and are too low to be produced by a lake without the upper Bear River input. ?? 2004 Geological Society of America.

Caves, Carbonates and Climate: Karst Landscape Development through Environmental Forcing, Little Cayman Island

NASA Astrophysics Data System (ADS)

Hsia, S.; Ouellette, G., Jr.; Manfrino, C.

2016-12-01

The Cayman Islands are situated in the west-central Caribbean Sea, between Cuba and the Yucatan Peninsula. Little Cayman Island (LCI) is relatively underdeveloped and understudied in comparison to its sister islands, Grand Cayman and Cayman Brac, and hosts less than 200 permanent residents over a 30 square kilometer area. However, like its sister islands, LCI is a small carbonate platform derived from reef building during the Oligocene, Miocene, and Quaternary. The shared geologic history of the Cayman Islands along with minimal human disturbance makes LCI an ideal site to study an island karst landscape. Conduction of field surveys, stratigraphic and petrologic comparisons between primary lithologic formations, and compilation of a geospatial inventory of karst features and lithology of LCI using GIS revealed novel insights into landscape evolution on LCI. In addition to surface karst surveys, several caves on the island were mapped. Cave morphologies suggest that evolution of LCI karst features have been driven by both hydroclimate, as well as salt and freshwater mixing, modulated by sea level fluctuations. These findings are mirrored in the lithology of partially dolomitized Miocene carbonates, which contain paleo-karst fill features and reveal hydroclimate influence, as well as enhanced resistance to dissolution in the present day, ostensibly from submersion in Mg-rich sea waters prior to the Quaternary. These findings shed light on the complex relationship of climate, geology, and karst landscape development on this particular carbonate island. This information is critical in anticipating structural and hydrogeological integrity on LCI under future climate change scenarios and serves as an example of the interplay linking climate and geologic processes to karst landscape development on small carbonate islands.

Shifting migration patterns without genetic erosion: evidence from the Zamia pumila complex (Cycadales: Zamiaceae) at the northern of the Caribbean island biodiversity hotspot

USDA-ARS?s Scientific Manuscript database

The Bahamas archipelago is the northernmost land area of the Caribbean island biodiversity hotspot (CIBH). It is defined by several banks composed of quaternary carbonates that are tectonically stable. Such stability has provided direct geological evidence of global ice-volume changes that is valuab...

Enhanced Stability of PtRu Supported on N-Doped Carbon for the Anode of a DMFC

DTIC Science & Technology

2012-09-18

nitrogen functionalities are most likely limited to pyrrolic , N-C=O and amine groups. In the case of PtRu/C (N- doped), the ion implantation introduces...suggesting the presence of graphitic, quaternary, pyridinic, C-N=O, pyrrolic , amine and nitrile groups.32,46 Initial DMFC performance and electrochemical

N-Heterocyclic carbene-catalyzed chemoselective cross-aza-benzoin reaction of enals with isatin-derived ketimines: access to chiral quaternary aminooxindoles.

PubMed

Xu, Jianfeng; Mou, Chengli; Zhu, Tingshun; Song, Bao-An; Chi, Yonggui Robin

2014-06-20

A chemo- and enantioselective cross-aza-benzoin reaction between enals and isatin-derived ketimines is disclosed. The high chemoselectivity (of the acyl anion reaction over enal α- and β-carbon reactions) is enabled by the electronic and steric properties of the N-heterocyclic carbene organocatalyst.

Strategic redox relay enables a scalable synthesis of ouabagenin, a bioactive cardenolide.

PubMed

Renata, Hans; Zhou, Qianghui; Baran, Phil S

2013-01-04

Here, we report on a scalable route to the polyhydroxylated steroid ouabagenin with an unusual take on the age-old practice of steroid semisynthesis. The incorporation of both redox and stereochemical relays during the design of this synthesis resulted in efficient access to more than 500 milligrams of a key precursor toward ouabagenin-and ultimately ouabagenin itself-and the discovery of innovative methods for carbon-hydrogen (C-H) and carbon-carbon activation and carbon-oxygen bond homolysis. Given the medicinal relevance of the cardenolides in the treatment of congestive heart failure, a variety of ouabagenin analogs could potentially be generated from the key intermediate as a means of addressing the narrow therapeutic index of these molecules. This synthesis also showcases an approach to bypass the historically challenging problem of selective C-H oxidation of saturated carbon centers in a controlled fashion.

Hydrothermal Origin for Carbonate Globules in Martian Meteorite ALH84001: A Terrestrial Analogue from Spitsbergen (Norway)

NASA Technical Reports Server (NTRS)

Treiman, Allan H.; Amundsen, Hans E. F.; Blake, David F.; Bunch, Ted

2002-01-01

Carbonate minerals in the ancient Martian meteorite ALH84001 are the only known solid phases that bear witness to the processing of volatile and biologically critical compounds (CO2, H2O) on early Mars. Similar carbonates have been found in xenoliths and their host basalts from Quaternary volcanic centers in northern Spitsbergen (Norway). These carbonates were deposited by hot (i.e., hydrothermal) waters associated with the volcanic activity. By analogy with the Spitsbergen carbonates, the ALH84001 carbonates were probably also deposited by hot water. Hydrothermal activity was probably common and widespread on Early Mars, which featured abundant basaltic rocks, water as ice or liquid, and heat from volcanos and asteroid impacts. On Earth, descendants of the earliest life forms still prefer hydrothermal environments, which are now shown to have been present on early Mars.

Paleoclimatic interpretations for clay-rich paleosols--Potential and limitations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blodgett, R.H.

1992-01-01

A worldwide survey of Quaternary Vertisols and pre-Quaternary vertic paleosols indicates that these soils have morphologic features which may allow for a refined assessment of seasonal wet-dry paleoclimates. Optimal development of vertisols occurs under wet/dry tropical and subtropical climates with annual rainfall of 500-1,000 mm/yr. These typic Vertisols'' have well-developed gilgai, subsurface bowl and dome macrostructure, cross-cutting slickensided surfaces, and disseminated pedogenic carbonate nodules. Typic Vertisols occur in central Texas, East Africa, India and Australia. Corresponding typic vertic paleosols have been found in 14 Paleozoic formations of Pangea. Humid Vertisols can be difficult to distinguish from typic forms. In themore » humid group, carbonate nodules are absent or few in number and smaller in size. Nodules commonly show surficial pitting from dissolution. Humid Vertisols occur in East Texas, the central Gulf Coast, Central America, Caribbean, and Papau-New Guinea. Paleosol equivalents have been described in Mesozoic and Carboniferous rocks of North America. Dry Vertisols have subdued gilgai, well-developed surficial mulch, large sediment-filled desiccation cracks, common carbonate nodules, and in some areas, disseminated crystals or veins of gypsum. These soils occur in the southwestern U.S., Sahel, and in Australia. Dry vertic paleosols have been identified in Cenozoic deposits of Texas and North Africa. The above assessments may not be possible in composite paleosols or in soils influenced by a shallow water table.« less

Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs.

PubMed

Zhu, Yi; Han, Jianlin; Wang, Jiandong; Shibata, Norio; Sodeoka, Mikiko; Soloshonok, Vadim A; Coelho, Jaime A S; Toste, F Dean

2018-04-11

New methods for preparation of tailor-made fluorine-containing compounds are in extremely high demand in nearly every sector of chemical industry. The asymmetric construction of quaternary C-F stereogenic centers is the most synthetically challenging and, consequently, the least developed area of research. As a reflection of this apparent methodological deficit, pharmaceutical drugs featuring C-F stereogenic centers constitute less than 1% of all fluorine-containing medicines currently on the market or in clinical development. Here we provide a comprehensive review of current research activity in this area, including such general directions as asymmetric electrophilic fluorination via organocatalytic and transition-metal catalyzed reactions, asymmetric elaboration of fluorine-containing substrates via alkylations, Mannich, Michael, and aldol additions, cross-coupling reactions, and biocatalytic approaches.

U-series dating of impure carbonates: An isochron technique using total-sample dissolution

USGS Publications Warehouse

Bischoff, J.L.; Fitzpatrick, J.A.

1991-01-01

U-series dating is a well-established technique for age determination of Late Quaternary carbonates. Materials of sufficient purity for nominal dating, however, are not as common as materials with mechanically inseparable aluminosilicate detritus. Detritus contaminates the sample with extraneous Th. We propose that correction for contamination is best accomplished with the isochron technique using total sample dissolution (TSD). Experiments were conducted on artificial mixtures of natural detritus and carbonate and on an impure carbonate of known age. Results show that significant and unpredictable transfer of radionuclides occur from the detritus to the leachate in commonly used selective leaching procedures. The effects of correcting via leachate-residue pairs and isochron plots were assessed. Isochrons using TSD gave best results, followed by isochron plots of leachates only. ?? 1991.

Organic solvents, electrolytes, and lithium ion cells with good low temperature performance

NASA Technical Reports Server (NTRS)

Huang, Chen-Kuo (Inventor); Smart, Marshall C. (Inventor); Surampudi, Subbarao (Inventor); Bugga, Ratnakumar V. (Inventor)

2002-01-01

Multi-component organic solvent systems, electrolytes and electrochemical cells characterized by good low temperature performance are provided. In one embodiment, an improved organic solvent system contains a ternary mixture of ethylene carbonate, dimethyl carbonate and diethyl carbonate. In other embodiments, quaternary systems include a fourth component, i.e, an aliphatic ester, an asymmetric alkyl carbonate or a compound of the formula LiOX, where X is R, COOR, or COR, where R is alkyl or fluoroalkyl. Electrolytes based on such organic solvent systems are also provided and contain therein a lithium salt of high ionic mobility, such as LiPF.sub.6. Reversible electrochemical cells, particularly lithium ion cells, are constructed with the improved electrolytes, and preferably include a carbonaceous anode, an insertion type cathode, and an electrolyte interspersed therebetween.

Understanding the major transitions in Quaternary climate dynamics

NASA Astrophysics Data System (ADS)

Willeit, Matteo; Ganopolski, Andrey

2017-04-01

Climate dynamics over the past 3 million years was characterized by strong variability associated with glacial cycles and several distinct regime changes. The Pliocene-Pleistocene Transition (PPT), which happened around 2.7 million years ago, was characterized by the appearance of the large continental ice sheets over Northern Eurasia and North America. For two million years after the PPT climate variability was dominated by relatively symmetric 40 kyr cycles. At around 1 million years ago the dominant mode of climate variability experienced a relatively rapid transition from 40 kyr to strongly asymmetric 100 kyr cycles of larger amplitude (Mid-Pleistocene Transition). Additionally, during the past 800 kyr there are clear differences between the earlier and the later glacial cycles with the last five cycles characterized by larger magnitude of variability (Mid-Brunhes Event). Here, we use the Earth system model of intermediate complexity CLIMBER-2 to explore possible mechanisms that could explain these regime shifts. CLIMBER-2 incorporates all major components of the Earth system - atmosphere, ocean, land surface, northern hemisphere ice sheets, terrestrial biota and soil carbon, marine biogeochemistry and aeolian dust. The model was optimally tuned to reproduce climate, ice volume and CO2 variability over the last 400,000 years. Using the same model version, we performed a large set of simulations covering the entire Quaternary (3 million years) starting from identical initial conditions and using a parallelization in time technique which consists of starting the model at different times (every 100,000 years) and running each simulation for 500,000 years. The Earth's orbital variations are the only prescribed radiative forcing. Several sets of the Northern Hemisphere orography and sediment thickness representing different stages of landscape evolution during the Quaternary are prescribed as boundary conditions for the ice sheet model and volcanic CO2 outgassing is used as the external forcing for the carbon cycle to allow for different background atmospheric CO2 concentrations. We show that by varying only these two model boundary conditions and volcanic forcing the model is able to reproduce the major regime changes of Quaternary long-term climate dynamics.

Soil genesis on the island of Bermuda in the Quaternary: the importance of African dust transport and deposition

USGS Publications Warehouse

Muhs, Daniel R.; Budahn, James R.; Prospero, Joseph M.; Skipp, Gary; Herwitz, Stanley R.

2012-01-01

The origin of terra rossa, red or reddish-brown, clay-rich soils overlying high-purity carbonate substrates, has intrigued geologists and pedologists for decades. Terra rossa soils can form from accumulation of insoluble residues during dissolution of the host limestones, addition of volcanic ash, or addition of externally derived, long-range-transported (LRT) aeolian particles. We studied soils and paleosols on high-purity, carbonate aeolianites of Quaternary age on Bermuda, where terra rossa origins have been debated for more than a century. Potential soil parent materials on this island include sand-sized fragments of local volcanic bedrock, the LRT, fine-grained (N/YbN, GdN/YbN that can be distinguished from African dust and lower Mississippi River valley loess. Bermuda soils have Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, LaN/YbN, GdN/YbN that indicate derivation from a combination of LRT dust from Africa and local volcanic bedrock. Our results indicate that soils on islands in a very broad latitudinal belt of the western Atlantic margin have been influenced by African LRT dust inputs over much of the past –500 ka.

Merging allylic carbon-hydrogen and selective carbon-carbon bond activation.

PubMed

Masarwa, Ahmad; Didier, Dorian; Zabrodski, Tamar; Schinkel, Marvin; Ackermann, Lutz; Marek, Ilan

2014-01-09

Since the nineteenth century, many synthetic organic chemists have focused on developing new strategies to regio-, diastereo- and enantioselectively build carbon-carbon and carbon-heteroatom bonds in a predictable and efficient manner. Ideal syntheses should use the least number of synthetic steps, with few or no functional group transformations and by-products, and maximum atom efficiency. One potentially attractive method for the synthesis of molecular skeletons that are difficult to prepare would be through the selective activation of C-H and C-C bonds, instead of the conventional construction of new C-C bonds. Here we present an approach that exploits the multifold reactivity of easily accessible substrates with a single organometallic species to furnish complex molecular scaffolds through the merging of otherwise difficult transformations: allylic C-H and selective C-C bond activations. The resulting bifunctional nucleophilic species, all of which have an all-carbon quaternary stereogenic centre, can then be selectively derivatized by the addition of two different electrophiles to obtain more complex molecular architecture from these easily available starting materials.

Merging allylic carbon-hydrogen and selective carbon-carbon bond activation

NASA Astrophysics Data System (ADS)

Masarwa, Ahmad; Didier, Dorian; Zabrodski, Tamar; Schinkel, Marvin; Ackermann, Lutz; Marek, Ilan

2014-01-01

Since the nineteenth century, many synthetic organic chemists have focused on developing new strategies to regio-, diastereo- and enantioselectively build carbon-carbon and carbon-heteroatom bonds in a predictable and efficient manner. Ideal syntheses should use the least number of synthetic steps, with few or no functional group transformations and by-products, and maximum atom efficiency. One potentially attractive method for the synthesis of molecular skeletons that are difficult to prepare would be through the selective activation of C-H and C-C bonds, instead of the conventional construction of new C-C bonds. Here we present an approach that exploits the multifold reactivity of easily accessible substrates with a single organometallic species to furnish complex molecular scaffolds through the merging of otherwise difficult transformations: allylic C-H and selective C-C bond activations. The resulting bifunctional nucleophilic species, all of which have an all-carbon quaternary stereogenic centre, can then be selectively derivatized by the addition of two different electrophiles to obtain more complex molecular architecture from these easily available starting materials.

Biocidal quaternary ammonium resin

NASA Technical Reports Server (NTRS)

Janauer, G. E.

1983-01-01

Activated carbon (charcoal) and polymeric resin sorbents are widely used in the filtration and treatment of drinking water, mainly to remove dissolved organic and inorganic impurities and to improve the taste. Earlier hopes that activated carbon might "disinfect' water proved to be unfounded. The feasibility of protecting against microbial infestation in charcoal and resin beds such as those to be incorporated into total water reuse systems in spacecraft was investigated. The biocidal effect of IPCD (insoluable polymeric contact disinfectants) in combination with a representative charcoal was assessed. The ion exchange resins (IPCD) were shown to adequately protect charcoal and ion exchange beds.

Forging Fluorine-Containing Quaternary Stereocenters by a Light-Driven Organocatalytic Aldol Desymmetrization Process.

PubMed

Cuadros, Sara; Dell'Amico, Luca; Melchiorre, Paolo

2017-09-18

Reported herein is a light-triggered organocatalytic strategy for the desymmetrization of achiral 2-fluoro-substituted cyclopentane-1,3-diketones. The chemistry is based on an intermolecular aldol reaction of photochemically generated hydroxy-o-quinodimethanes and simultaneously forges two adjacent fully substituted carbon stereocenters, with one bearing a stereogenic carbon-fluorine unit. The method uses readily available substrates, a simple chiral organocatalyst, and mild reaction conditions to afford an array of highly functionalized chiral 2-fluoro-3-hydroxycyclopentanones. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

On Quaternary glaciations, observations and theories

NASA Astrophysics Data System (ADS)

Paillard, D.

2015-07-01

In a recent paper, Paillard (2015) presents a rapid overview of both major theoretical and empirical studies of Pleistocene glaciations. In particular, it is explained how, over the last 150 years, astronomical theories were confronted to observational constraints and why the "100-kyr problem" is still the major unsolved issue of Quaternary ice ages. This paper also discusses the main alternative theory, which involves changes in atmospheric carbon dioxide concentration. It is then argued that a synthesis of both theories would better account for empirical evidences, as well as for our current knowledge of climate physics. Indeed, if there is no doubt that ice ages are "paced" by the astronomy as evidenced in Hays et al. (1976), the cause of terminations, and therefore the dynamics of the 100-kyr cycles, appears to be closely linked to Southern Ocean climate and atmospheric pCO2.

Curbing gridlock: Peak-period fees to relieve traffic congestion. Volume 2. Commissioned papers. Special report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-01-01

;Contents: Volume 2: Commissioned Papers: Congestion Trends in Metropolitan Areas; Alternative Methods for Measuring Congestion Levels; Potential of Congestion Pricing in the Metropolitan Washington Region; Transportation Pricing and Travel Behavior; Peak Pricing Strategies in Transportation, Utilities, and Telecommunications: Lessons for Road Pricing; Cashing Out Employer-Paid Parking: A Precedent for Congestion Pricing; The New York Region: First in Tolls, Last in Road Pricing; Pricing Urban Roadways: Administrative and Institutional Issues; Equity and Fairness Considerations of Congestion Pricing; The Politics of Congestion Pricing; Institutional and Political Challenges in Implementing Congestion Pricing: Case Study of the San Francisco Bay Area; How Congestion Pricingmore » Came to Be Proposed in the San Diego Region: A Case History; Urban Transportation Congestion Pricing: Effects on Urban Form; Congestion Pricing and Motor Vehicle Emissions: An Initial Review; Private Toll Roads: Acceptability of Congestion Pricing in Southern California; Potential of Next-Generation Technology; Electronic Toll Collection Systems; and Impacts of Congestion Pricing on Transit and Carpool Demand and Supply.« less

Isolation and characterization of heterotrophic bacteria able to grow aerobically with quaternary ammonium alcohols as sole source of carbon and nitrogen.

PubMed

Kaech, Andres; Vallotton, Nathalie; Egli, Thomas

2005-04-01

The quaternary ammonium alcohols (QAAs) 2,3-dihydroxypropyl-trimethyl-ammonium (TM), dimethyl-diethanol-ammonium (DM) and methyl-triethanol-ammonium (MM) are hydrolysis products of their parent esterquat surfactants, which are widely used as softeners in fabric care. We isolated several bacteria growing with QAAs as the sole source of carbon and nitrogen. The strains were compared with a previously isolated TM-degrading bacterium, which was identified as a representative of the species Pseudomonas putida (Syst. Appl. Microbiol. 24 (2001) 252). Two bacteria were isolated with DM, referred to as strains DM 1 and DM 2, respectively. Based on 16S-rDNA analysis, they provided 97% (DM 1) and 98% (DM 2) identities to the closest related strain Zoogloea ramigera Itzigsohn 1868AL. Both strains were long, slim, motile rods but only DM 1 showed the floc forming activity, which is typical for representatives of the genus Zoogloea. Using MM we isolated a Gram-negative, non-motile rod referred to as strain MM 1. The 16S-rDNA sequence of the isolated bacterium revealed 94% identities (best match) to Rhodobacter sphaeroides only. The strains MM 1 and DM 1 exclusively grew with the QAA which was used for their isolation. DM 2 was also utilizing TM as sole source of carbon and nitrogen. However, all of the isolated bacteria were growing with the natural and structurally related compound choline.

Seismic study of the Mesozoic carbonate basement around Mt. Somma Vesuvius, Italy

NASA Astrophysics Data System (ADS)

Bruno, Pier Paolo G.; Cippitelli, Giuseppe; Rapolla, Antonio

1998-09-01

Fifteen seismic reflection lines from AGIP surveys, in and around the Campanian Plain and Mt. Somma-Vesuvius (south Italy) have been interpreted. The attention has been focused to the horizon pertinent to the top of the Mesozoic carbonate sequence and the Quaternary faults dissecting it. As a matter of fact, both are very important elements for understanding the origin of the volcanic activity in the area, that often in the past, has been the topic of debates not supported by reliable data. In the study area, referring to the depth of the carbonate basement, comparison between the result achieved by the seismic prospecting and previous gravity studies has been made. It shows coherence in some areas but large discrepancy within others. Near the town of S. Anastasia, the gravity and seismic depth estimates differ as much as 1000 m or more. Furthermore, the seismic data show that the source of the greatest volcanic eruption in the area (the so-called `Campanian Ignimbrite') is probably not located in the Acerra depression, as suggested by other authors. A main NE-SW fault directed toward Vesuvius, considered as playing a primary role on volcanogenetic processes and previously recognised only offshore by marine seismic survey, has been now identified also inland using this new seismic information. The results presented here strengthen the hypothesis that Mt. Vesuvius is located at the crossing point of two regional Quaternary sets of fault heading NW-SE and NE-SW.

Traffic congestion and reliability : trends and advanced strategies for congestion mitigation.

DOT National Transportation Integrated Search

2005-09-01

The report Traffic Congestion and Reliability: Trends and Advanced Strategies for : Congestion Mitigation provides a snapshot of congestion in the United States by : summarizing recent trends in congestion, highlighting the role of travel time : reli...

Identification of anthropogenic and natural inputs of sulfate into a karstic coastal groundwater system in northeast China: evidence from major ions, δ13CDIC and δ34SSO4

NASA Astrophysics Data System (ADS)

Han, Dongmei; Song, Xianfang; Currell, Matthew J.

2016-05-01

The hydrogeochemical processes controlling groundwater evolution in the Daweijia area of Dalian, northeast China, were characterised using hydrochemistry and isotopes of carbon and sulfur (δ13CDIC and δ34SSO4). The aim was to distinguish anthropogenic impacts as distinct from natural processes, with a particular focus on sulfate, which is found at elevated levels (range: 54.4 to 368.8 mg L-1; mean: 174.4 mg L-1) in fresh and brackish groundwater. The current investigation reveals minor seawater intrusion impact (not exceeding 5 % of the overall solute load), in contrast with extensive impacts observed in 1982 during the height of intensive abstraction. This indicates that measures to restrict groundwater abstraction have been effective. However, hydrochemical facies analysis shows that the groundwater remains in a state of ongoing hydrochemical evolution (towards Ca-Cl type water) and quality degradation (increasing nitrate and sulfate concentrations). The wide range of NO3 concentrations (74.7-579 mg L-1) in the Quaternary aquifer indicates considerable input of fertilisers and/or leakage from septic systems. Both δ13C (-14.5 to -5.9 permil) and δ34SSO4 (+5.4 to +13.1 permil) values in groundwater show increasing trends along groundwater flow paths. While carbonate minerals may contribute to increasing δ13CDIC and δ34SSO4 values in deep karstic groundwater, high loads of agricultural fertilisers reaching the aquifer via irrigation return flow are likely the main source of the dissolved sulfate in Quaternary groundwater, as shown by distinctive isotopic ratios and a lack of evidence for other sources in the major ion chemistry. According to isotope mass balance calculations, the fertiliser contribution to overall sulfate has reached an average of 62.1 % in the Quaternary aquifer, which has a strong hydraulic connection to the underlying carbonate aquifer. The results point to an alarming level of impact from the local intensive agriculture on the groundwater system, a widespread problem throughout China.

Identification of anthropogenic and natural inputs of sulfate into a karstic coastal groundwater system in northeast China: evidence from major ions, δ13CDIC and δ34SSO4

NASA Astrophysics Data System (ADS)

Han, D.; Song, X.; Currell, M. J.

2015-11-01

The hydrogeochemical processes controlling groundwater evolution in the Daweijia area of Dalian, northeast China, were characterized using hydrochemistry and isotopes of carbon and sulfur (δ13CDIC and δ34SSO4). The aim was to distinguish anthropogenic impacts as distinct from natural processes, with a particular focus on sulfate, which is found at elevated levels (range: 54.4 to 368.8 mg L-1; mean: 174.4 mg L-1) in fresh and brackish groundwater. The current investigation reveals minor seawater intrusion impact (not exceeding 5 % of overall solute load), in contrast with extensive impacts observed in 1982 during the height of intensive abstraction. This indicates that measures to restrict groundwater abstraction have been effective. However, hydrochemical facies analysis shows that the groundwater remains in a state of ongoing hydrochemical evolution (towards Ca-Cl type water) and quality degradation (increasing nitrate and sulphate concentrations). The wide range of NO3 concentrations (74.7-579 mg L-1) in the Quaternary aquifer indicates considerable input of fertilizers and/or leakage from septic systems. Both δ13C (-14.5 to -5.9 ‰) and δ34SSO4 (+5.4-+13.1 ‰) values in groundwater show increasing trends along groundwater flow paths. While carbonate minerals may contribute to increasing δ13CDIC and δ34SSO4 values in deep karstic groundwater, high loads of agricultural fertilizers reaching the aquifer via irrigation return flow are likely the main source of the dissolved sulfate in Quaternary groundwater, as shown by distinctive isotopic ratios and a lack of evidence for other sources in the major ion chemistry. According to isotope mass balance calculations, the fertilizer contribution to overall sulfate has reached an average of 62.1 % in the Quaternary aquifer, which has a strong hydraulic connection to the underlying carbonate aquifer. The results point to an alarming level of impact from the local intensive agriculture on the groundwater system, a widespread problem throughout China.

Origin of Cretaceous phosphorites from the onshore of Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Purnachandra Rao, V.; Kessarkar, Pratima M.; Nagendra, R.; Babu, E. V. S. S. K.

2007-12-01

Cretaceous phosphorites from the onshore of Tamil Nadu have been investigated for their origin and compared with those in the offshore. Cretaceous phosphorites occur as light brown to yellowish brown or white nodules in Karai Shale of the Uttatur Group in the onshore Cauvery basin. Nodules exhibit phosphatic nucleus encrusted by a chalky shell of carbonate. The nucleus of the nodules consists of light and dark coloured laminae, phosphate peloids/coated grains and detrital particles interspersed between the laminae. Scanning electron microscope (SEM) studies reveal trapping and binding activity of microbial filaments. A mat structure with linearly arranged microbial filaments and hollow, cell-based coccoid cyanobacterial mat are present. Nodules contain abundant carbonate fluorapatite, followed by minor calcite, quartz and feldspar. The P2O5 content of the phosphorites ranges from 18 to 26%. The CaO/P2O5, Sr and F contents are higher than that of pure carbonate fluorapatite. Concentrations of Si, Al, K, Fe, and Ti are low. We suggest that the nuclei of the nodules represent phosphate clasts related to phosphate stromatolites formed at intertidal conditions. At high energy levels the microbial mats were disintegrated into phosphate clasts, coated with carbonate and then reworked into Karai Shale. On the other hand, Quaternary phosphorites occur as irregular to rounded, grey coloured phosphate clasts at water depths between 180 and 320m on the continental shelf of Tamil Nadu. They exhibit grain-supported texture. Despite Quaternary in age, they also resemble phosphate stromatolites of intertidal origin and reworked as phosphate clasts onto the shelf margin depressions. Benthic microbial mats probably supplied high phosphorus to the sediments. Availability of excess phosphorus seems to be a pre-requisite for the formation of phosphate stromatolites.

Sedimentology of polar carbonate systems

NASA Astrophysics Data System (ADS)

Frank, T. D.; James, N. P.

2013-12-01

The key attributes, processes, and products associated with carbonate accumulation and diagenesis at tropical and temperate latitudes are well known. Comparatively little work has concentrated on carbonate deposition at the coldest end of the depositional spectrum, the polar shelves. Such deposits are not abundant, but they have the potential to provide unique insights into paleoceanographic and paleoclimatic conditions in regions of the planet that are arguably the most sensitive to global change. We examined skeletal assemblages, facies, stratigraphy, petrography, geochemistry, and diagenesis of Quaternary deposits from the Ross Sea, Antarctica and Permian counterparts from Gondwana (now eastern Australia). These modern and ancient polar carbonate factories possess several unique characteristics that set them apart from better-known systems of the temperate and tropical latitudes. All production is biogenic and there are no significant calcareous phototrophs. Carbonate communities are not capable of building rigid frameworks, and thus their deposits are prone to winnowing and reworking by waves and bottom currents. The seawater, although frigid, is isothermal, and thus deep-water benthic communities can exist near the surface. Carbonate saturation, which is at or below solubility for both aragonite and high-Mg calcite, plays a key role in determining the dominant mineralogy of benthos as well as the preservation potential of skeletal debris. As many taxa precipitate low-Mg calcite in isotopic equilibrium, deposits have potential to provide geochemical proxy information for use in paleoceanographic and paleoclimatic reconstructions. More than any other type of carbonate system, the slow biogenic carbonate production and accumulation in cold waters is achieved firstly by arresting siliciclastic sedimentation and secondly by increasing nutrient availability. Thus, carbonate deposition may occur during the coldest of times, such as during glacial advance when terrigenous clastics are sequestered inboard and invigorated ocean circulation enhances upwelling. Radiocarbon data from Quaternary deposits in the Ross Sea indicate that short windows of accumulation during favorable conditions are followed by longer intervals of non-productivity, during which skeletal debris undergoes dissolution and infestation by endolithic borers, carbonate sediments are reworked by bottom currents, and glacigene siliciclastic facies are deposited. Similar patterns are evident in Permian deposits. We interpret the post-carbonate depositional periods as not only due to increased terrigenous input but also dramatically reduced trophic resources. The foregoing hypothesis is at odds with most current thinking about carbonate deposition and points to an evolving paradigm within which polar carbonate deposition is dramatically different than that in temperate and tropical settings.

Emission rates of particulate matter and elemental and organic carbon from in-use diesel engines.

PubMed

Shah, Sandip D; Cocker, David R; Miller, J Wayne; Norbeck, Joseph M

2004-05-01

Elemental carbon (EC), organic carbon (OC), and particulate matter (PM) emission rates are reported for a number of heavy heavy-duty diesel trucks (HHDDTs) and back-up generators (BUGs) operating under real-world conditions. Emission rates were determined using a unique mobile emissions laboratory (MEL) equipped with a total capture full-scale dilution tunnel connected directly to the diesel engine via a snorkel. This paper shows that PM, EC, and OC emission rates are strongly dependent on the mode of vehicle operation; highway, arterial, congested, and idling conditions were simulated by following the speed trace from the California Air Resources Board HHDDT cycle. Emission rates for BUGs are reported as a function of engine load at constant speed using the ISO 8178B Cycle D2. The EC, OC, and PM emission rates were determined to be highly variable for the HHDDTs. It was determined that the per mile emission rate of OC from a HHDDT in congested traffic is 8.1 times higher than that of an HHDDT in cruise or highway speed conditions and 1.9 times higher for EC. EC/OC ratios for BUGs (which generally operate at steady states) and HHDDTs show marked differences, indicating that the transient nature of engine operation dictates the EC/OC ratio. Overall, this research shows that the EC/OC ratio varies widely for diesel engines in trucks and BUGs and depends strongly on the operating cycle. The findings reported here have significant implications in the application of chemical mass balance modeling, diesel risk assessment, and control strategies such as the Diesel Risk Reduction Program.

Analysis of Random Drop for Gateway Congestion Control

DTIC Science & Technology

1989-11-01

effective congest)on control policies. Currently No Gateway Policy is used to relieve and signal congestion, which leads to unfair service to the...early application of the policy removes the pressure of congestion relief and allows more accurate signaling of congestion. ’ To be used effectively ...prompted the need for more effective congestion control policies. Currently No Gateway Policy is used to relieve and signal congestion, which leads to

Estimation of the tectonic slip-rate from Quaternary lacustrine facies within the intraplate Albacete province (SE of Spain)

USGS Publications Warehouse

Rodriguez-Pascua, M. A.; Bischoff, J.; Garduno-Monroy, Victor H.; Pérez-López, R.; Giner-Robles, J.L.; Israde-Alcántara, I.; Calvo, J.P.; Williams, Ross W.

2009-01-01

The Quaternary lacustrine basin of Cordovilla (CB) represents one of the most active tectonic areas of the Prebetic Zone (Albacete, SE of Spain). The Quaternary sedimentary deposits of this basin are mainly endoreic lacustrine carbonate and alluvial deposits, developed in a semi-arid climate (Pleistocene-present). The basin is a NW-SE-elongated graben bounded by a major right-lateral oblique-fault, the Pozohondo Fault. This fault trends NW-SE, with an approximate trace of 55 km, and is composed of various segments which are identified by fault scarps. In order to establish the slip-rate of the most active segment of the Pozohondo Fault, called the Cordovilla segment, we carried out a detailed study of the affected Quaternary lacustrine deposits. We found that the lacustrine facies could be related to episodic moderate paleoearthquakes. The slip-rate is calculated to be 0.05 and 0.09 mm/yr, using radiometric dating for the vertical offsets of the lacustrine facies. A trenching study at the northern part of the Cordovilla segment revealed two events caused by paleoearthquakes, with the most recent expressed as an oblique-fault off-setting a poorly-developed soil. The magnitude of the last event was greater than 6, using various empirical relationships for the fault displacement and the surface-length rupture. We estimate episodic activity across the Cordovilla segment, to be characterized by moderate-sized paleoearthquakes (M6), which is in agreement with the tectonic context of an intraplate zone of the Iberian plate. ?? 2009 Elsevier B.V.

Carbonate Deposition on Antarctic Shelves

NASA Astrophysics Data System (ADS)

Frank, T. D.; James, N. P.; Malcolm, I.

2011-12-01

Limestones associated with glaciomarine deposits occur throughout the geologic record but remain poorly understood. The best-described examples formed during major ice ages of the Neoproterozoic and Late Paleozoic. Quaternary analogs on Antarctic shelves have received comparatively little study. Here, we report on the composition, spatial distribution, and stratigraphic context of carbonate sediments contained in piston cores from the Ross Sea. The goals of this work are to (1) document the nature and distribution of carbonate sediments on the Ross Sea continental shelf and (2) examine temporal relationships to Quaternary glaciation. Results will be used to develop criteria that will improve understanding of analogous deposits in the ancient record. All carbonate-rich intervals in piston cores from the Ross Rea, now housed at the Antarctic Marine Geology Research Facility at Florida State University, were examined and described in detail. Sediment samples were disaggregated and sieved into size fractions before description with paleontological analysis carried out on the coarsest size fraction (>250 microns). Carbonate-rich sediments are concentrated in the northwestern Ross Sea, along the distal margins of Mawson and Pennell Banks. Calcareous facies include a spectrum of lithologies that range from fossiliferous mud, sand, and gravel to skeletal floatstone-rudstone and bafflestone. Floatstone-rudstone and bafflestone is most abundant along western-facing slopes in areas protected from the Antarctic Coastal Current. Sand-prone facies dominate the tops of banks and mud-prone, often spicultic, facies occur in deeper areas. The carbonate factory is characterized by a low-diversity, heterozoan assemblage that is dominated by stylasterine hydrocorals, barnacles, and bryozoans. Molluscs and echinoids are present but not abundant. Planktic and benthic foraminifera are ubiquitous components of the sediment matrix, which is locally very rich in sponge spicules. Biota rarely occur in growth position. Rather, there is much evidence of postdepositional reworking so that these carbonates accumulate as clastic sediments. Available radiocarbon ages place deposition during the transition from MIS 3 to MIS 2, during a time of glacial expansion. Accumulation ceased during the Last Glacial Maximum and so calcareous sediments in the Ross Sea are restricted in both time and space. Deposition occured during windows of time when subdued siliciclastic input and high trophic resource availablity combined to create conditions that favor cold-water carbonate production. Results provide a context for interpreting older carbonates recovered in drillcores from more proximal regions of the Ross Sea.

Late Quaternary landscape evolution, climate, and neotectonism along the eastern margin of the Puna Plateau: Pucará Valley, NW Argentina

NASA Astrophysics Data System (ADS)

McCarthy, J. A.; Schoenbohm, L. M.; Bierman, P. R.; Rood, D. H.

2013-12-01

The eastern margin of the Puna Plateau has been the focus of many studies seeking to link climatically-moderated surface processes and tectonism through dynamic feedbacks. However, evaluating any theories regarding climatic-tectonic feedbacks requires the determination of tectonic, climatic, and geomorphic chronologies across a wide region, from plateau to wedge-top to foreland. In this study, we contribute to that effort by examining Quaternary landscape evolution of a single intermontane basin of spatially uniform climate, adjacent to the plateau margin. The semi-arid Pucará Valley contains eight abandoned and incised geomorphic surfaces, most of which are deformed by active structures. These geomorphic surfaces - thin alluvial fans and strath terraces - dominate the landscape and record multiple pulses of incision in the late Quaternary. We find no evidence for significant depositional intervals and valley incision continues currently. Substantial accumulations of pedogenic carbonate and pedogenic gypsum within abandoned surfaces indicate that arid or semi-arid conditions are long lived in this valley. Conversely, relict periglacial morphology in adjacent ranges supports cooler temperatures in the past. River incision is enhanced across active structures, but preliminary observations suggest that the magnitude of deformation cannot fully explain the magnitude of incision. As a result, we argue that extrabasinal base-level lowering is the primary driver of incision in the Pucará Valley, but Quaternary deformation is significant enough to spatially influence erosion. Cooler climatic intervals may influence the sedimentology of alluvial and fluvial deposits, but we find no evidence for significant climatic changes that could change rates or styles of landscape evolution over this time frame. Pending cosmogenic nuclide analysis of fan deposits and river sediments will permit the derivation of fault slip rates, surface ages, modern and paleo-erosion rates, and sediment transport histories. These results will further refine our understanding of tectonic and climatic forcing of surface processes in the Quaternary.

Enantioselective construction of quaternary stereogenic carbon atoms by the Lewis base catalyzed additions of silyl ketene imines to aldehydes.

PubMed

Denmark, Scott E; Wilson, Tyler W; Burk, Matthew T

2014-07-21

Silyl ketene imines derived from a variety of α-branched nitriles have been developed as highly useful reagents for the construction of quaternary stereogenic centers via the aldol addition reaction. In the presence of SiCl4 and the catalytic action of a chiral phosphoramide, silyl ketene imines undergo extremely rapid and high yielding addition to a wide variety of aromatic aldehydes with excellent diastereo- and enantioselectivity. Of particular note are the high yields and selectivities obtained from electron-rich, electron-poor, and hindered aldehydes. Linear aliphatic aldehydes did react with good diastereo- and enantioselectivity in the presence of nBu4N(+)I(-), but branched aldehydes were much less reactive. Semiempirical calculations provided a rationalization of the observed diastereo- and enantioselectivity via open transitions states. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Aragonite preservation in late Quaternary sediment cores on the Brazilian Continental Slope: implications for intermediate water circulation

NASA Astrophysics Data System (ADS)

Gerhardt, S.; Groth, H.; Rühlemann, C.; Henrich, R.

We present late Quaternary records of aragonite preservation determined for sediment cores recovered on the Brazilian Continental Slope (1790-2585m water depth) where North Atlantic Deep Water (NADW) dominates at present. We have used various indirect dissolution proxies (carbonate content, aragonite/calcite contents, and sand percentages) as well as gastropodal abundances and fragmentation of Limacina inflata to determine the state of aragonite preservation. In addition, microscopic investigations of the dissolution susceptibility of three Limacina species yielded the Limacina Dissolution Index which correlates well with most of the other proxies. Excellent preservation of aragonite was found in the Holocene section, whereas aragonite dissolution gradually increases downcore. This general pattern is attributed to an overall increase in aragonite corrosiveness of pore waters. Overprinted on this early diagenetic trend are high-frequency fluctuations of aragonite preservation, which may be related to climatically induced variations of intermediate water masses.

Controls on Cyclic Formation of Quaternary Early Diagenetic Dolomite

NASA Astrophysics Data System (ADS)

McCormack, J.; Bontognali, T. R. R.; Immenhauser, A.; Kwiecien, O.

2018-04-01

The origin of sedimentary dolomite and the factors that control its formation within the geological record remain speculative. In most models, dolomite formation is linked to evaporative conditions, high water temperature, increasing Mg/Ca ratio, increasing alkalinity, and high amounts of biomass. Here we challenge these archetypal views, by documenting a case example of Quaternary dolomite which formed in Lake Van at constantly low temperature (<4°C) and without direct control of the latter conditions. Dolomite occurs within highstand sediments related to suborbital climate variability (Dansgaard-Oeschger cycles). We propose that dolomite precipitation is a product of a microbially influenced process, triggered by ecological stress, resulting from reventilation of the water-sediment interface. Independently from the validity of this hypothesis, our results call for a reevaluation of the paleoenvironmental conditions often invoked for early diagenetic dolomite-rich intervals within sedimentary sequences and for caution when interpreting time series of subrecent lacustrine carbonates.

Occurrence and genesis of Quaternary microbialitic tufa at Hammam Al Ali, Oman

NASA Astrophysics Data System (ADS)

Khalaf, Fikry I.

2017-05-01

Remnants of late Quaternary microbialitic tufa occurs within a shallow depression in the Hammam Al Ali hot spring area, which is located approximately 14.5 km to the southwest of Muscat, Oman. The tufa precipitated from hot spring water supersaturated with respect to calcium carbonate and is mostly of a porous phytogenic type, with occasional detrital and stromatolitic types. Microscopic and nanoscopic examination revealed that the tufa deposits developed through two successive processes of calcite precipitation, biotic and abiotic, preceded by limited precipitation of unstable aragonite. It is suggested that biologically mediated precipitation results in the construction of incomplete skeletal calcite crystals. The latter provide a base for classical physiochemical precipitation and, eventually, the development of complete sparry calcite crystals. The initiation of dendritic calcite crystals in the stromatolitic tufa as incomplete biogenic skeletal crystals and their characteristic growth pattern indicates that the tufa represents a clear example of hot spring calcitic microbialite.

The preparation of new perfluoro ether fluids exhibiting excellent thermal-oxidative stabilities

NASA Technical Reports Server (NTRS)

Jones, William R., Jr.; Bierschenk, Thomas R.; Juhlke, Timothy J.; Kawa, Hajima; Lagow, Richard J.

1988-01-01

A series of low molecular weight perfluoroalkyl ethers (PFAEs) were synthesized by direct fluorination. Viscosity-temperature properties and oxidation stabilities were determined. Viscosity-temperature correlations indicated that increases in branching and increases in the size of the branching substituent caused a deterioration in viscometric properties (i.e., an increase in ASTM slope). In addition, increasing the ratio of carbon to oxygen in these compounds also increased the ASTM slope. Preliminary oxidation stability measurements indicated that highly branched PFAE fluids (i.e., those containing quaternary carbons) may be less stable than either those containing a single trifluoromethyl pendant group or those containing no branching at all.

The preparation of new perfluoroether fluids exhibiting excellent thermal-oxidative stabilities

NASA Technical Reports Server (NTRS)

Jones, W. R., Jr.; Bierschenk, T. R.; Juhlke, T. J.; Kawa, H.; Lagow, R. J.

1986-01-01

A series of low molecular weight perfluoroalkylethers (PFAE) were synthesized by direct fluorination. Viscosity-temperature properties and oxidation stabilities were determined. Viscosity-temperature correlations indicated that increases in branching and increases in the size of the branching substituent caused a deterioration in viscometric properties (i.e., an increase in ASTM slope). In addition, increasing the ratio of carbon to oxygen in these compounds also increased the ASTM slope. Preliminary oxidation stability tests indicated that highly branched PFAE fluids. (i.e., those containing quaternary carbons) may be less stable than either those containing a single trifluoromethyl pendant group or those containing no branching at all.

Molecular structure of the dioctadecyldimethylammonium bromide (DODAB) bilayer.

PubMed

Jamróz, Dorota; Kepczynski, Mariusz; Nowakowska, Maria

2010-10-05

Dioctadecyldimethylammonium bromide (DODAB) is a double-chained quaternary ammonium surfactant that assembles in water into bilayer structures. This letter reports the molecular dynamics (MD) computer simulations of the DODAB bilayer at 25 °C. The simulations show that the surfactant membrane arranges spontaneously into the rippled phase (P(β)(')) at that temperature. The ordering within the chain fragment closest to the hydrophilic head (carbon atoms 1-5) is relatively low. It grows significantly for the carbon atoms located in the center of the membrane (atoms 6-17). The C6-C17 chain fragments are well aligned and tilted by ca. 15° with respect to the bilayer normal.

Comparing Perceptions and Measures of Congestion

DOT National Transportation Integrated Search

2012-10-01

Peoples perception of congestion and the actual measured congestion do not always agree. Measured : congestion relates to the delay resulting from field measurements of traffic volume, speed, and travel : time. Peoples perception of congestion ...

Enantiomeric scaffolding of α-tetralone and related scaffolds by EKR (enzymatic kinetic resolution) and stereoselective ketoreduction with ketoreductases.

PubMed

Bhuniya, Rajib; Nanda, Samik

2012-01-21

Stereochemically pure compounds containing an all carbon quaternary stereocenter based on 1-tetralone, 1-indanone and 4-chromanone scaffolds have been synthesized by employing Lipase PS (Burkholderia cepacia) catalyzed kinetic resolution. These scaffolds are further functionalized by microbial ketoreductase enzymes (Geotrichum candidum, Candida parapsilosis and Aspergillus niger) to access stereochemically pure diols which, on further synthetic manipulation, yield novel cyclic compounds.

Palladium-Catalyzed Asymmetric Allylic Alkylation of 4-Substituted Isoxazolidin-5-ones: Straightforward Access to β2,2 -Amino Acids.

PubMed

Nascimento de Oliveira, Marllon; Arseniyadis, Stellios; Cossy, Janine

2018-04-03

We report here an unprecedented and highly enantioselective palladium-catalyzed allylic alkylation applied to 4-substituted isoxazolidin-5-ones. Ultimately, the process provides a straightforward access to β 2,2 -amino acids bearing an all-carbon quaternary stereogenic center in great yields and a high degree of enantioselectivity. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Late Pleistocene Magnitude Glacial Incursions of Southern Component Water to the Deep North Atlantic Resolved Using Nd Isotopes during the Intensification of Northern Hemisphere Glaciation (3.3 to 2.4 Ma)

NASA Astrophysics Data System (ADS)

Lang, D.; Bailey, I.; Wilson, P. A.; Foster, G. L.; Gutjahr, M.

2014-12-01

The ocean, through its ability to globally redistribute heat and partition carbon dioxide, is believed to play a key role in driving and amplifying climate change during Quaternary glaciations on orbital to millennial timescales. Relatively little is known, however, about changes in Atlantic Meridional Overturning Circulation (AMOC) associated with the Pliocene intensification of Northern Hemisphere glaciation (iNHG). To help fill this gap in our knowledge we present a new high resolution (~6 ka) record of the Nd isotope composition of the deep North Atlantic between ~3.3 and 2.4 Ma, measured on fish debris at IODP Site U1313 (3426 m, 41°N, 32.5°W). This record represents the first orbital-resolution record of variations in watermass mixing in this region for iNHG independent of changes in the carbon cycle and, in contrast to existing benthic foraminiferal δ13C records for this time interval, our Nd dataset contains evidence for late Pleistocene magnitude incursions of Southern Component Waters to the deep North Atlantic Ocean during key glacial periods through this time. We therefore infer an important role for AMOC variability in amplifying Quaternary glacial-interglacial cycles

d-PET-controlled “off-on” Polarity-sensitive Probes for Reporting Local Hydrophilicity within Lysosomes

NASA Astrophysics Data System (ADS)

Zhu, Hao; Fan, Jiangli; Mu, Huiying; Zhu, Tao; Zhang, Zhen; Du, Jianjun; Peng, Xiaojun

2016-10-01

Polarity-sensitive fluorescent probes are powerful chemical tools for studying biomolecular structures and activities both in vitro and in vivo. However, the lack of “off-on” polarity-sensing probes has limited the accurate monitoring of biological processes that involve an increase in local hydrophilicity. Here, we design and synthesize a series of “off-on” polarity-sensitive fluorescent probes BP series consisting of the difluoroboron dippyomethene (BODIPY) fluorophore connected to a quaternary ammonium moiety via different carbon linkers. All these probes showed low fluorescence quantum yields in nonpolar solution but became highly fluorescent in polar media. BP-2, which contains a two-carbon linker and a trimethyl quaternary ammonium, displayed a fluorescence intensity and quantum yield that were both linearly correlated with solvent polarity. In addition, BP-2 exhibited high sensitivity and selectivity for polarity over other environmental factors and a variety of biologically relevant species. BP-2 can be synthesized readily via an unusual Mannich reaction followed by methylation. Using electrochemistry combined with theoretical calculations, we demonstrated that the “off-on” sensing behavior of BP-2 is primarily due to the polarity-dependent donor-excited photoinduced electron transfer (d-PET) effect. Live-cell imaging established that BP-2 enables the detection of local hydrophilicity within lysosomes under conditions of lysosomal dysfunction.

Lignin geochemistry of a Late Quaternary sediment core from Lake Washington

NASA Astrophysics Data System (ADS)

Hedges, John I.; Ertel, John R.; Leopold, Estella B.

1982-10-01

Long-term lignin stability and paleovegetation patterns were investigated using CuO oxidation products of sediments from an 11 m core of Late Quaternary sediment collected from the mid-basin of Lake Washington, Washington State. Relatively constant yields of lignin-derived phenols (normalized to organic carbon) from the entire core indicate minimal in situ lignin degradation over the last 13,000 years. Compositional patterns within the phenolic suite and increased corresponding yields from baseextracted sediments indicate that sedimentary lignins are present predominantly as well preserved plant tissue fragments. Abundance patterns of vanillyl, syringyl, and cinnamyl phenols record four distinct sequences within the core characterized by: (a) high concentrations of gymnosperm wood in a basal horizon of glacial flour, 11-10 m; (b) an essentially pure mixture of nonwoody angiosperm tissues in late Pleistocene sediments, 10-8 m; (c) relatively high concentrations of angiosperm woods in the bottom half of a limnic peat sequence deposited approximately 10,000-7,000 years B.P., 8-4 m; and (d) a progressive enrichment in gymnosperm woods at the expense of angiosperm woods over the last 7,000 years in the upper limnic peat, 4-0 m. Vascular plant tissues account for less than half the total sedimentary organic carbon throughout the core.

Determination of perchlorate from tea leaves using quaternary ammonium modified magnetic carboxyl-carbon nanotubes followed by liquid chromatography-tandem quadrupole mass spectrometry.

PubMed

Zhao, Yong-Gang; Zhang, Yun; Wang, Feng-Lian; Zhou, Jian; Zhao, Qi-Ming; Zeng, Xiu-Qiong; Hu, Mei-Qin; Jin, Mi-Cong; Zhu, Yan

2018-08-01

The novel quaternary ammonium modified magnetic carboxyl-carbon nanotubes (QA-Mag-CCNTs) have been synthesised and characterized. QA-Mag-CCNTs were applied in magnetic dispersive solid phase extraction (Mag-dSPE) for preconcentration of perchlorate from tea leaves prior to liquid chromatography-tandem quadrupole mass spectrometry (LC-MS/MS) analysis. The Mag-dSPE procedure for preconcentration of perchlorate succeed in overcoming the flaw (containing target analyte randomly) of commercially available SPE cartridge. Under optimal conditions, the results showed higher extraction efficiency of QA-Mag-CCNTs, with recoveries between 85.2% and 107%. And the satisfactory precision with inter-day and intra-day RSD values were lower than 8.0%. Furthermore, QA-Mag-CCNTs were evaluated for reuse up to 20 times. The limit of quantification (LOQ) for perchlorate was 8.21 ng kg -1 . The developed method was successfully applied in tea leaves for food-safety risk monitoring in Zhejiang province, China. The results showed the concentrations of perchlorate in 229 out of 240 collected samples were in the range of 0.082-988 μg kg -1 . It was confirmed that QA-Mag-CCNTs were highly effective materials used for preconcentration of perchlorate. Copyright © 2018 Elsevier B.V. All rights reserved.

Coupled micromorphological and stable isotope analysis of Quaternary calcrete development

NASA Astrophysics Data System (ADS)

Adamson, Kathryn; Candy, Ian; Whitfield, Liz

2015-09-01

Pedogenic calcretes are widespread in arid and semi-arid regions. Using calcrete profiles from four river terraces of the Rio Alias in southeast Spain, this study explores the potential of using detailed micromorphological and stable isotopic analysis to more fully understand the impacts of Quaternary environmental change on calcrete development. The four profiles increase in carbonate complexity with progressive age, reflecting calcretisation over multiple glacial-interglacial cycles since MIS 9 (c. 300 ka). Calcrete profiles contain a mixture of Alpha (non-biogenic) and Beta (biogenic) microfabrics. Alpha fabrics have higher δ13C and δ18O values. The profiles contain a range of crystal textures, but there is little difference between the δ13C and δ18O values of spar, microspar, and micrite cements. Strong positive covariance between δ13C and δ18O suggests that both isotopes are responding to the same environmental parameter, which is inferred to be relative aridity. The study reveals that the detailed co-analysis of calcrete micromorphology and stable isotope signatures can allow patterns of calcrete formation to be placed into a wider palaeoclimatic context. This demonstrates the potential of this technique to more reliably constrain the palaeoenvironmental significance of secondary carbonates in dryland settings where other proxy records may be poorly preserved.

Bifunctional Nitrogen-Doped Microporous Carbon Microspheres Derived from Poly(o-methylaniline) for Oxygen Reduction and Supercapacitors.

PubMed

He, Yanzhen; Han, Xijiang; Du, Yunchen; Song, Bo; Xu, Ping; Zhang, Bin

2016-02-17

Heteroatom-doped carbon materials have attracted significant attention because of their applications in oxygen reduction reaction (ORR) and supercapacitors. Here we demonstrate a facile poly(o-methylaniline)-derived fabrication of bifunctional microporous nitrogen-doped carbon microspheres (NCMSs) with high electrocatalytic activity and stability for ORR and energy storage in supercapacitors. At a pyrolysis temperature of 900 °C, the highly dispersed NCMSs present a high surface area (727.1 m(2) g(-1)), proper total content of doping N, and high concentration of quaternary N, which exhibit superior electrocatalytic activities for ORR to the commercial Pt/C catalysts, high specific capacitance (414 F g(-1)), and excellent durability, making them very promising for advanced energy conversion and storage. The presented conducting polymer-derived strategy may provide a new way for the fabrication of heteroatom-doped carbon materials for energy device applications.

Delivering Faster Congestion Feedback with the Mark-Front Strategy

NASA Technical Reports Server (NTRS)

Liu, Chunlei; Jain, Raj

2001-01-01

Computer networks use congestion feedback from the routers and destinations to control the transmission load. Delivering timely congestion feedback is essential to the performance of networks. Reaction to the congestion can be more effective if faster feedback is provided. Current TCP/IP networks use timeout, duplicate Acknowledgement Packets (ACKs) and explicit congestion notification (ECN) to deliver the congestion feedback, each provides a faster feedback than the previous method. In this paper, we propose a markfront strategy that delivers an even faster congestion feedback. With analytical and simulation results, we show that mark-front strategy reduces buffer size requirement, improves link efficiency and provides better fairness among users. Keywords: Explicit Congestion Notification, mark-front, congestion control, buffer size requirement, fairness.

Investigating the effect of freeway congestion thresholds on decision-making inputs.

DOT National Transportation Integrated Search

2010-05-01

Congestion threshold is embedded in the congestion definition. Two basic approaches exist in : current practice for setting the congestion threshold. One common approach uses the free-flow or : unimpeded conditions as the congestion threshold. ...

Hydrogeochemical processes in the Plio-Quaternary Remila aquifer (Khenchela, Algeria)

NASA Astrophysics Data System (ADS)

Aouidane, Laiche; Belhamra, Mohamed

2017-06-01

The Remila Plain is a synclinal structure in northeast Algeria, situated within a semi-arid climate zone and composed of Mio-Pliocene-Quaternary deposits. Within the syncline, the Plio-Quaternary aquifer is the main source of drinking water for cattle and for agricultural irrigation water. This work aims to investigate the origin of groundwater mineralization and to identify the primary hydrogeochemical processes controlling groundwater evolution in the Remila aquifer. A total of 86 water samples from boreholes were analyzed for major, minor and stable isotopes (18O, 2H) over three seasons: first during low water levels in 2013, second during high water levels in 2014 and third for stable isotopes during low water levels in 2015. The analysis showed that the aquifer is controlled by five principal geochemical processes: (I) the dissolution of evaporite rocks, (II) cation exchange and reverse exchange reactions, (III) congruent dissolution of carbonates (calcite, dolomite) coupled with the dissolution of gypsum and calcite precipitation, (IV) sulfate reduction under anaerobic conditions, and (V) saltwater intrusion in the northeastern Sabkha plains. The 18O and deuterium concentrations in groundwater are very low, indicating that the aquifer is recharged by evaporated rainfall originating from the north slope of the Aurès Mountains which confirms that the aquifer is recharged in the southern part of the plain.

Reducing congestion : congestion pricing has promise for improving use of transportation infrastructure

DOT National Transportation Integrated Search

2003-05-06

Congestion pricing can potentially reduce congestion by providing incentives for drivers to shift trips to off-peak periods, use less congested routes, or use alternative modes, thereby spreading out demand for available transportation infrastructure...

Understanding the topological characteristics and flow complexity of urban traffic congestion

NASA Astrophysics Data System (ADS)

Wen, Tzai-Hung; Chin, Wei-Chien-Benny; Lai, Pei-Chun

2017-05-01

For a growing number of developing cities, the capacities of streets cannot meet the rapidly growing demand of cars, causing traffic congestion. Understanding the spatial-temporal process of traffic flow and detecting traffic congestion are important issues associated with developing sustainable urban policies to resolve congestion. Therefore, the objective of this study is to propose a flow-based ranking algorithm for investigating traffic demands in terms of the attractiveness of street segments and flow complexity of the street network based on turning probability. Our results show that, by analyzing the topological characteristics of streets and volume data for a small fraction of street segments in Taipei City, the most congested segments of the city were identified successfully. The identified congested segments are significantly close to the potential congestion zones, including the officially announced most congested streets, the segments with slow moving speeds at rush hours, and the areas near significant landmarks. The identified congested segments also captured congestion-prone areas concentrated in the business districts and industrial areas of the city. Identifying the topological characteristics and flow complexity of traffic congestion provides network topological insights for sustainable urban planning, and these characteristics can be used to further understand congestion propagation.

Network congestion control algorithm based on Actor-Critic reinforcement learning model

NASA Astrophysics Data System (ADS)

Xu, Tao; Gong, Lina; Zhang, Wei; Li, Xuhong; Wang, Xia; Pan, Wenwen

2018-04-01

Aiming at the network congestion control problem, a congestion control algorithm based on Actor-Critic reinforcement learning model is designed. Through the genetic algorithm in the congestion control strategy, the network congestion problems can be better found and prevented. According to Actor-Critic reinforcement learning, the simulation experiment of network congestion control algorithm is designed. The simulation experiments verify that the AQM controller can predict the dynamic characteristics of the network system. Moreover, the learning strategy is adopted to optimize the network performance, and the dropping probability of packets is adaptively adjusted so as to improve the network performance and avoid congestion. Based on the above finding, it is concluded that the network congestion control algorithm based on Actor-Critic reinforcement learning model can effectively avoid the occurrence of TCP network congestion.

Forearm vasodilatation following release of venous congestion

PubMed Central

Caro, C. G.; Foley, T. H.; Sudlow, M. F.

1970-01-01

1. The volume rate of forearm blood flow was measured with a mercury-in-rubber strain gauge, or with a water-filled plethysmograph, from 1 sec after termination of a 2-3 min period of venous congestion. 2. When congesting pressure had been less than 18 mm Hg, average post-congestion flow (five subjects) was constant during approx. 10 sec and not significantly different from resting flow. 3. When congesting pressure had been 30 mm Hg, average post-congestion flow (eight subjects) was 26% higher than resting, during 3-4 sec after release of congestion, but rose to 273% of resting during 4-6 sec after release of congestion. 4. In other studies forearm vascular resistance had been found normal or increased during such venous congestion, and theoretical studies here indicated that passive mechanical factors could not account for the delayed occurrence of high post-congestion flow. 5. It appears, therefore, that the forearm vascular bed dilates actively shortly after release of substantial venous congestion. It would seem more likely that a myogenic mechanism, rather than a metabolic one, is responsible. PMID:5532541

Research on Urban Road Traffic Congestion Charging Based on Sustainable Development

NASA Astrophysics Data System (ADS)

Ye, Sun

Traffic congestion is a major problem which bothers our urban traffic sustainable development at present. Congestion charging is an effective measure to alleviate urban traffic congestion. The paper first probes into several key issues such as the goal, the pricing, the scope, the method and the redistribution of congestion charging from theoretical angle. Then it introduces congestion charging practice in Singapore and London and draws conclusion and suggestion that traffic congestion charging should take scientific plan, support of public, public transportation development as the premise.

Late Quaternary paleohydrology deduced from new marine sediment cores taken on the proximal Amazon continental margin

NASA Astrophysics Data System (ADS)

Nace, T.; Baker, P. A.; Dwyer, G. S.; Hollander, D. J.; Silva, C. G.

2010-12-01

Throughout the late Quaternary the Amazon Basin has been influenced by abrupt North-South climate forcing and has undergone several large climate variations as recorded in previously reported speleothem records. Despite its importance in the global carbon cycle there are few continuous, high-resolution records of the Amazon Basin that date back to and beyond the last glacial period. In this study, we report the first results of a marine geological expedition to the Amazon continental shelf and fan region. During this expedition we collected eight ~30 meter piston cores along with gravity, box and multicores. At both sites we undertook complementary multibeam and high resolution seismic reflection profiling. Analyses will be presented from two sets of box/gravity/piston cores. One core (32m) is from a high sedimentation site on the northern flank of the main submarine canyon within the Amazon Fan complex at 1700m water depth. The other core (30m) is located on a seamount to the south of the Amazon Fan complex at 3100m water depth. A mixed assemblage of foraminifera is used for 14C dating to obtain an age model and bulk organic geochemistry is analyzed to determine percent organic carbon, C/N ratios, δ13C and δ15N. The cores were continuously measured shipboard for magnetic susceptibility and gamma density using a GEOTEK logger. These findings uncover the contribution of pelagic and terrestrial organic matter, whether the terrigenous carbon is derived from C3 versus C4 vegetation, and whether the marine organic matter is composed of phytoplankton or marine algae.

Environmentally Reformed Travel Habits During the 2006 Congestion Charge Trial in Stockholm—A Qualitative Study

PubMed Central

Henriksson, Greger; Hagman, Olle; Andréasson, Håkan

2011-01-01

Policy measures that reduce or replace road traffic can improve environmental conditions in most large cities. In Stockholm a congestion charge was introduced during a test period in 2006. This was a full-scale trial that proved to meet its targets by reducing traffic crossing the inner city segment during rush hours by 20%. Emissions of carbon dioxide and particles were also substantially reduced. This study, based on in-depth interviews with 40 inhabitants, analyses how and why new travel habits emerged. The results show that particular, sometimes unexpected, features of everyday life (habits, resources, opportunities, values, etc.) were crucial for adjustment of travel behaviour in relation to the policy instrument. One example was that those accustomed to mixing different modes of transport on a daily basis more easily adapted their travel in the targeted way. On a more general level, the results revealed that the policy measure could actually tip the scales for the individual towards trying out a new behaviour. PMID:21909301

Interaction between worsening renal function and persistent congestion in acute decompensated heart failure.

PubMed

Wattad, Malak; Darawsha, Wisam; Solomonica, Amir; Hijazi, Maher; Kaplan, Marielle; Makhoul, Badira F; Abassi, Zaid A; Azzam, Zaher S; Aronson, Doron

2015-04-01

Worsening renal function (WRF) and congestion are inextricably related pathophysiologically, suggesting that WRF occurring in conjunction with persistent congestion would be associated with worse clinical outcome. We studied the interdependence between WRF and persistent congestion in 762 patients with acute decompensated heart failure (HF). WRF was defined as ≥0.3 mg/dl increase in serum creatinine above baseline at any time during hospitalization and persistent congestion as ≥1 sign of congestion at discharge. The primary end point was all-cause mortality with mean follow-up of 15 ± 9 months. Readmission for HF was a secondary end point. Persistent congestion was more common in patients with WRF than in patients with stable renal function (51.0% vs 26.6%, p <0.0001). Both persistent congestion and persistent WRF were significantly associated with mortality (both p <0.0001). There was a strong interaction (p = 0.003) between persistent WRF and congestion, such that the increased risk for mortality occurred predominantly with both WRF and persistent congestion. The adjusted hazard ratio for mortality in patients with persistent congestion as compared with those without was 4.16 (95% confidence interval [CI] 2.20 to 7.86) in patients with WRF and 1.50 (95% CI 1.16 to 1.93) in patients without WRF. In conclusion, persisted congestion is frequently associated with WRF. We have identified a substantial interaction between persistent congestion and WRF such that congestion portends increased mortality particularly when associated with WRF. Copyright © 2015 Elsevier Inc. All rights reserved.

Optimal Wind Energy Integration in Large-Scale Electric Grids

NASA Astrophysics Data System (ADS)

Albaijat, Mohammad H.

The major concern in electric grid operation is operating under the most economical and reliable fashion to ensure affordability and continuity of electricity supply. This dissertation investigates the effects of such challenges, which affect electric grid reliability and economic operations. These challenges are: 1. Congestion of transmission lines, 2. Transmission lines expansion, 3. Large-scale wind energy integration, and 4. Phaser Measurement Units (PMUs) optimal placement for highest electric grid observability. Performing congestion analysis aids in evaluating the required increase of transmission line capacity in electric grids. However, it is necessary to evaluate expansion of transmission line capacity on methods to ensure optimal electric grid operation. Therefore, the expansion of transmission line capacity must enable grid operators to provide low-cost electricity while maintaining reliable operation of the electric grid. Because congestion affects the reliability of delivering power and increases its cost, the congestion analysis in electric grid networks is an important subject. Consequently, next-generation electric grids require novel methodologies for studying and managing congestion in electric grids. We suggest a novel method of long-term congestion management in large-scale electric grids. Owing to the complication and size of transmission line systems and the competitive nature of current grid operation, it is important for electric grid operators to determine how many transmission lines capacity to add. Traditional questions requiring answers are "Where" to add, "How much of transmission line capacity" to add, and "Which voltage level". Because of electric grid deregulation, transmission lines expansion is more complicated as it is now open to investors, whose main interest is to generate revenue, to build new transmission lines. Adding a new transmission capacity will help the system to relieve the transmission system congestion, create profit for investors for renting their transmission capacity, and cheaper electricity for end users. We propose a hybrid method based on a heuristic and deterministic method to attain new transmission lines additions and increase transmission capacity. Renewable energy resources (RES) have zero operating cost, which makes them very attractive for generation companies and market participants. In addition, RES have zero carbon emission, which helps relieve the concerns of environmental impacts of electric generation resources' carbon emission. RES are wind, solar, hydro, biomass, and geothermal. By 2030, the expectation is that more than 30% of electricity in the U.S. will come from RES. One major contributor of RES generation will be from wind energy resources (WES). Furthermore, WES will be an important component of the future generation portfolio. However, the nature of WES is that it experiences a high intermittency and volatility. Because of the great expectation of high WES penetration and the nature of such resources, researchers focus on studying the effects of such resources on the electric grid operation and its adequacy from different aspects. Additionally, current market operations of electric grids add another complication to consider while integrating RES (e.g., specifically WES). Mandates by market rules and long-term analysis of renewable penetration in large-scale electric grid are also the focus of researchers in recent years. We advocate a method for high-wind resources penetration study on large-scale electric grid operations. PMU is a geographical positioning system (GPS) based device, which provides immediate and precise measurements of voltage angle in a high-voltage transmission system. PMUs can update the status of a transmission line and related measurements (e.g., voltage magnitude and voltage phase angle) more frequently. Every second, a PMU can provide 30 samples of measurements compared to traditional systems (e.g., supervisory control and data acquisition [SCADA] system), which provides one sample of measurement every 2 to 5 seconds. Because PMUs provide more measurement data samples, PMU can improve electric grid reliability and observability. (Abstract shortened by UMI.)

First enantiocontrolled formal synthesis of (+)-neovibsanin B, a neurotrophic diterpenoid.

PubMed

Esumi, Tomoyuki; Mori, Takehiro; Zhao, Ming; Toyota, Masao; Fukuyama, Yoshiyasu

2010-02-19

An enantiocontrolled formal synthesis of (+)-neovibsanin B has been achieved by a sequence that applies an asymmetric 1,4-addition of (H(2)C=CH)(2)Cu(CN)Li(2) to trisubstituted alpha,beta-carboxylic acid derivative 1 to induce the chirality at the C-11 all-carbon quaternary center. Together with a modified Negishi cyclic carbopalladation-carbonylative esterification tandem reaction for constructing the A-ring, the synthesis was completed.

Delay-based virtual congestion control in multi-tenant datacenters

NASA Astrophysics Data System (ADS)

Liu, Yuxin; Zhu, Danhong; Zhang, Dong

2018-03-01

With the evolution of cloud computing and virtualization, the congestion control of virtual datacenters has become the basic issue for multi-tenant datacenters transmission. Regarding to the friendly conflict of heterogeneous congestion control among multi-tenant, this paper proposes a delay-based virtual congestion control, which translates the multi-tenant heterogeneous congestion control into delay-based feedback uniformly by setting the hypervisor translation layer, modifying three-way handshake of explicit feedback and packet loss feedback and throttling receive window. The simulation results show that the delay-based virtual congestion control can effectively solve the unfairness of heterogeneous feedback congestion control algorithms.

Novel Quaternary Quantum Decoder, Multiplexer and Demultiplexer Circuits

NASA Astrophysics Data System (ADS)

Haghparast, Majid; Monfared, Asma Taheri

2017-05-01

Multiple valued logic is a promising approach to reduce the width of the reversible or quantum circuits, moreover, quaternary logic is considered as being a good choice for future quantum computing technology hence it is very suitable for the encoded realization of binary logic functions through its grouping of 2-bits together into quaternary values. The Quaternary decoder, multiplexer, and demultiplexer are essential units of quaternary digital systems. In this paper, we have initially designed a quantum realization of the quaternary decoder circuit using quaternary 1-qudit gates and quaternary Muthukrishnan-Stroud gates. Then we have presented quantum realization of quaternary multiplexer and demultiplexer circuits using the constructed quaternary decoder circuit and quaternary controlled Feynman gates. The suggested circuits in this paper have a lower quantum cost and hardware complexity than the existing designs that are currently used in quaternary digital systems. All the scales applied in this paper are based on Nanometric area.

Quantitative estimates of Asian dust input to the western Philippine Sea in the mid-late Quaternary and its potential significance for paleoenvironment

NASA Astrophysics Data System (ADS)

Xu, Zhaokai; Li, Tiegang; Clift, Peter D.; Lim, Dhongil; Wan, Shiming; Chen, Hongjin; Tang, Zheng; Jiang, Fuqing; Xiong, Zhifang

2015-09-01

We present a new high-resolution multiproxy data set of Sr-Nd isotopes, rare earth element, soluble iron, and total organic carbon data from International Marine Global Change Study Core MD06-3047 located in the western Philippine Sea. We integrate our new data with published clay mineralogy, rare earth element chemistry, thermocline depth, and δ13C differences between benthic and planktonic foraminifera, in order to quantitatively constrain Asian dust input to the basin. We explore the relationship between Philippine Sea and high-latitude Pacific eolian fluxes, as well as its significance for marine productivity and atmospheric CO2 during the mid-late Quaternary. Three different indices indicate that Asian dust contributes between ˜15% and ˜50% to the detrital fraction of the sediments. Eolian dust flux in Core MD06-3047 is similar to that in the polar southern Pacific sediment. Coherent changes for most dust flux maximum/minimum indicate that dust generation in interhemispheric source areas might have a common response to climatic variation over the mid-late Quaternary. Furthermore, we note relatively good coherence between Asian dust input, soluble iron concentration, local marine productivity, and even global atmospheric CO2 concentration over the entire study interval. This suggests that dust-borne iron fertilization of marine phytoplankton might have been a periodic process operating at glacial/interglacial time scales over the past 700 ka. We suggest that strengthening of the biological pump in the Philippine Sea, and elsewhere in the tropical western Pacific during the mid-late Quaternary glacial periods may contribute to the lowering of atmospheric CO2 concentrations during ice ages.

The oldest Quaternary ooids and young reefs in the eastern Indian Ocean, evidence from the Northwest Shelf of Australia, IODP Expedition 356.

NASA Astrophysics Data System (ADS)

Gallagher, S. J.; Reuning, L.; Himmler, T.; Henderiks, J.; De Vleeschouwer, D.; Groeneveld, J.; Fulthorpe, C.; Bogus, K.; Expedition 356 Scientists, I.

2016-12-01

Modern reefs are common in the Indian Ocean off the west coast of Australia (south of 15°S) where the warm Leeuwin Current extends their modern distribution to 29°S. Two key features that distinguish these tropical from non-tropical carbonates are the presence of coral reefs and ooids. Coral reefs are generally confined to seawater >18°C. Ooids form at temperatures >20°C with salinities >37‰. Modern ooids are forming in the hypersaline Shark Bay and are well known from late Quaternary strata in the region. Globally, marine ooids have been interpreted to be direct evidence of physiochemical precipitation from seawater during periods of elevated alkalinity and supersaturation. Their occurrence in the subsurface of the Northwest Shelf of Australia (NWS) may be used as sea surface temperature, palaeobathymetry and aridity indices. However, the longer-term history of reefs and ooids is not well constrained in the NWS. IODP expedition 356 cored a series of sections down dip from the Houtman-Abrolhos (29°S) and Barrow Island reefs (22°S) and up dip from the Rowley Shoals (18°S) to determine their age and origin. The stratigraphy of the cored sections was mapped using regional seismic data to constrain the age of reef onset. Coring also yielded several horizons of pre-late Quaternary ooids. Our analyses reveals that reefs from 22°S to 30°S are younger than 600,000 years old and that ooids are present in strata up to 750,000 years old. We suggest stronger Leeuwin Current activity related to an enhanced Indonesian Throughflow and increased aridity triggered tropical carbonate expansion on the Northwest Shelf during the Middle Pleistocene Transition. Knowledge of the timing and circumstances that triggered tropical reef development in the Indo-Pacific in the past is critical if we are to understand the resilience of modern reefs with future climate change.

Unexpected Magnetic Ordering on the Cr Substructure in UCr2Si2C and Structural Relationships in Quaternary U-Cr-Si-C Compounds.

PubMed

Lemoine, Pierric; Vernière, Anne; Pasturel, Mathieu; Venturini, Gérard; Malaman, Bernard

2018-03-05

Previous experimental and theoretical studies revealed that carbon insertion into the RCr 2 Si 2 compounds drastically affects the magnetic behavior, since chromium does not carry any magnetic moment in RCr 2 Si 2 C (R = Y, La-Sm, Gd-Er) compounds in contrast to RCr 2 Si 2 (R = Y, Sm, Gd-Lu, Th) compounds. In this study, we report on the unexpected magnetic ordering of chromium atoms in the isotype quaternary UCr 2 Si 2 C compound. While specific heat and magnetic measurements suggest a Pauli paramagnetic behavior, neutron powder diffraction reveals an antiferromagnetic ordering of the chromium substructure at high temperature ( T N > 300 K), while that of uranium remains nonmagnetically ordered down to 2 K. Its magnetic behavior, inverse in comparison to the RCr 2 Si 2 C carbides involving a magnetic lanthanide, is discussed in relation with the singularity of its crystal structure among the series. Moreover, the crystallographic structures and the structural stability of UCr 2 Si 2 C and of two other quaternary U-Cr-Si-C compounds (i.e., UCr 3 Si 2 C and U 2 Cr 3 Si 2 C 3 ), based on the full occupancy of interstitial sites by carbon atoms, are discussed and compared to those of the related ternary intermetallics. Finally, the low-temperature form of UCr 2 Si 2 , corresponding to a displacive transformation around 210 K of the ThCr 2 Si 2 -type structure, is reinvestigated by considering a higher symmetry monoclinic unit cell ( C2/ m) instead of the previously reported triclinic cell ( P1̅). The antiferromagnetic ordering at low temperature ( T N = 30(2) K) of the uranium substructure is confirmed, and its magnetic structure is reanalyzed and discussed considering the monoclinic crystal structure.

Treatment bed microbiological control

NASA Technical Reports Server (NTRS)

Janauer, Gilbert E.; Fitzpatrick, Timothy W.; Kril, Michael B.; Wilber, Georgia A.; Sauer, Richard L.

1987-01-01

The effects of microbial fouling on treatment bed (TB) performance are being studied. Fouling of activated carbon (AC) and ion exchange resins (IEX) by live and devitalized bacteria can cause decreased capacity for selected sorbates with AC and IEX TB. More data are needed on organic species removal in the trace region of solute sorption isotherms. TB colonization was prevented by nonclassical chemical disinfectant compositions (quaternary ammonium resins) applied in suitable configurations. Recently, the protection of carbon beds via direct disinfectant impregnation has shown promise. Effects (of impregnation) upon bed sorption/removal characteristics are to be studied with representative contaminants. The potential need to remove solutes added or produced during water disinfection and/or TB microbiological control must be investigated.

A Study of the Effects of Congestion Information and a Priority Boarding Pass in a Theme Park with Multi-Agents

NASA Astrophysics Data System (ADS)

Tone, Tetsuya; Kohara, Kazuhiro

We have investigated ways to reduce congestion in a theme park with multi-agents. We constructed a theme park model called Digital Park 1.0 with twenty-three attractions similar in form to Tokyo Disney Sea. We consider not only congestion information (number of vistors standing in line at each attraction) but also the advantage of a priority boarding pass, like Fast Pass which is used at Tokyo Disney Sea. The congestion-information-usage ratio, which reflects the ratio of visitors who behave according to congestion information, was changed from 0% to 100% in both models, with and without priority boarding pass. The “mean stay time of visitors" is a measure of satisfaction. The smaller mean stay time, the larger degree of satisfaction. Here, a short stay time means a short wait time. The resluts of each simulation are averaged over ten trials. The main results are as follows. (1) When congestion-information-usage ratio increased, the mean stay time decreases. When 20% of visitors behaved according to congestion information, the mean stay time was reduced by 30%. (2) A priority boarding pass reduced congestion, and mean stay time was reduced by 15%. (3) When visitors used congestion information and a priority boarding pass, mean stay time was further reduced. When the congestion-information-usage ratio was 20%, mean stay time was reduced by 35%. (4) When congestion-information-usage ratio was over 50%, the congestion reduction effects reached saturation.

Photochemical studies on aromatic γ,δ-epoxy ketones: efficient synthesis of benzocyclobutanones and indanones.

PubMed

Shao, Yutian; Yang, Chao; Gui, Weijun; Liu, Yang; Xia, Wujiong

2012-04-11

Irradiation of terminal aromatic γ,δ-epoxy ketones with a 450 W UV lamp led to Norrish type II cyclization/semi-pinacol rearrangement cascade reaction which formed the benzocyclobutanones containing a full-carbon quaternary center, whereas irradiation of substituted aromatic γ,δ-epoxy ketones led to the indanones through a photochemical epoxy rearrangement and 1,5-biradicals cyclization tandem reaction. This journal is © The Royal Society of Chemistry 2012

Chemical investigations of aquifers affected by pyrite oxidation in the Bitterfeld lignite district.

PubMed

Grützmacher, G; Hindel, R; Kantor, W; Wimmer, R

2001-01-01

In a large area around the former open-pit lignite mines near Bitterfeld, Germany, groundwater taken from wells was analyzed for the major cations, anions, and trace elements. Quaternary and Tertiary sediments were collected from aquifers exposed on the sides of the pits and from boreholes outside the mines and analyzed for major and trace elements, as well as for carbonate, pyritic sulfur and total organic carbon. The pH and electrical conductivity of the sediments in suspension were measured. Significant differences were determined between the Tertiary sediments of the aquifers that were exposed to atmospheric oxygen during the lowering of the groundwater table and those outside the cone of depression. The greatest differences were found in the pyrite content, the pH values, and the electrical conductivity. In order to map the degree to which the mining of the lignite has affected the quality of the groundwater in the study area, the water samples were divided into six classes on the basis of their sulfate content. The neutralization potential was calculated to estimate the potential for acidification. Prediction of future groundwater quality is based on both (i) the present composition of the groundwater, surface water, and Quaternary and Tertiary aquifer sediments and (ii) the present and future groundwater flow directions. These studies have shown which parameters are important for future groundwater monitoring.

Enhancement of perchlorate removal from groundwater by cationic granular activated carbon: Effect of preparation protocol and surface properties.

PubMed

Hou, Pin; Yan, Zhe; Cannon, Fred S; Yue, Ye; Byrne, Timothy; Nieto-Delgado, Cesar

2018-06-01

In order to obtain a high adsorption capacity for perchlorate, the epoxide-forming quaternary ammonium (EQA) compounds were chemically bonded onto granular activated carbon (GAC) surface by cationic reaction. The optimum preparation condition of the cationic GAC was achieved while applying softwood-based Gran C as the parent GAC, dosing EQA first at a pH of 12, preparation time of 48 h, preparation temperature of 50 °C, and mole ratio of EQA/oxygen groups of 2.5. The most favorable cationic GAC that had the QUAB360 pre-anchored exhibited the highest perchlorate adsorption capacity of 24.7 mg/g, and presented the longest bed volumes (3000 BV) to 2 ppb breakthrough during rapid small scale column tests (RSSCTs), which was 150 times higher than that for the pristine Gran C. This was attributed to its higher nitrogen amount (1.53 At%) and higher positive surface charge (0.036 mmol/g) at pH 7.5. Also, there was no leaching of the quaternary ammonium detected in the effluent of the RSSCTs, indicating there was no secondary pollution occurring during the perchlorate removal process. Overall, this study provides an effective and environmental-friendly technology for improving GAC perchlorate adsorption capacity for groundwater treatment. Copyright © 2018 Elsevier Ltd. All rights reserved.

Dynamic, stochastic models for congestion pricing and congestion securities.

DOT National Transportation Integrated Search

2010-12-01

This research considers congestion pricing under demand uncertainty. In particular, a robust optimization (RO) approach is applied to optimal congestion pricing problems under user equilibrium. A mathematical model is developed and an analysis perfor...

Geochemical evidence for the origin of late Quaternary loess in central Alaska

USGS Publications Warehouse

Muhs, D.R.; Budahn, J.R.

2006-01-01

Loess is extensive in central Alaska, but there are uncertainties about its source and the direction of paleo-winds that deposited it. Both northerly and southerly winds have been inferred. The most likely sources of loess are the Tanana River (south), the Nenana River (southeast), and the Yukon River (north). Late Quaternary loess in central Alaska has immobile trace-element compositions (Cr/Sc, Th/Ta, Th/ Sc, Th/U, Eu/Eu*, GdN/YbN) that indicate derivation mostly from the Tanana River. However, other ratios (As/Sb, Zr/Hf, LaN/YbN) and quantitative modeling indicate that the Yukon River was also a source. During the last glacial period, there may have been a longer residence time of the Siberian and Canadian high-pressure cells, along with a strengthened Aleutian low-pressure cell. This would have generated regional-scale northeasterly winds and explains derivation of loess from the Yukon River. However, superim-posed upon this synoptic-scale circulation, there may have been strong, southerly katabatic winds from expanded glaciers on the northern flank of the Alaska Range. These winds could have provided eolian silt from the Tanana River. Yukon River and Tanana River sediments are highly calcareous, whereas Fairbanks-area loess is not. This suggests that carbonate leaching in loess kept ahead of sedimentation and that late Quaternary loess in central Alaska was deposited relatively slowly. ?? 2006 NRC Canada.

Influence of porous texture and surface chemistry on the CO₂ adsorption capacity of porous carbons: acidic and basic site interactions.

PubMed

Sánchez-Sánchez, Angela; Suárez-García, Fabián; Martínez-Alonso, Amelia; Tascón, Juan M D

2014-12-10

Doped porous carbons exhibiting highly developed porosity and rich surface chemistry have been prepared and subsequently applied to clarify the influence of both factors on carbon dioxide capture. Nanocasting was selected as synthetic route, in which a polyaramide precursor (3-aminobenzoic acid) was thermally polymerized inside the porosity of an SBA-15 template in the presence of different H3PO4 concentrations. The surface chemistry and the porous texture of the carbons could be easily modulated by varying the H3PO4 concentration and carbonization temperature. Porous texture was found to be the determinant factor on carbon dioxide adsorption at 0 °C, while surface chemistry played an important role at higher adsorption temperatures. We proved that nitrogen functionalities acted as basic sites and oxygen and phosphorus groups as acidic ones toward adsorption of CO2 molecules. Among the nitrogen functional groups, pyrrolic groups exhibited the highest influence, while the positive effect of pyridinic and quaternary functionalities was smaller. Finally, some of these N-doped carbons exhibit CO2 heats of adsorption higher than 42 kJ/mol, which make them excellent candidates for CO2 capture.

Understanding the carbon cycle in a Late Quaternary-age limestone aquifer system using radiocarbon of dissolved inorganic and organic carbon

NASA Astrophysics Data System (ADS)

Bryan, Eliza; Meredith, Karina T.; Baker, Andy; Andersen, Martin S.; Post, Vincent E. A.

2017-04-01

Estimating groundwater residence time is critical for our understanding of hydrogeological systems, for groundwater resource assessments and for the sustainable management of groundwater resources. Due to its capacity to date groundwater up to 30 thousand years old, as well as the ubiquitous nature of dissolved carbon (as organic and inorganic forms) in groundwater, 14C is the most widely used radiogenic dating technique in regional aquifers. However, the geochemistry of carbon in groundwater systems includes interaction with the atmosphere, biosphere and geosphere, which results in multiple sources and sinks of carbon that vary in time and space. Identifying these sources of carbon and processes relating to its release or removal is important for understanding the evolution of the groundwater and essential for residence time calculations. This study investigates both the inorganic and organic facets of the carbon cycle in groundwaters throughout a freshwater lens and mixing zone of a carbonate island aquifer and identifies the sources of carbon that contribute to the groundwater system. Groundwater samples were collected from shallow (5-20 m) groundwater wells on a small carbonate Island in Western Australia in September 2014 and analysed for major and minor ions, stable water isotopes (SWIs: δ18O, δ2H), 3H, 14C and 13C carbon isotope values of both DIC and DOC, and 3H. The composition of groundwater DOC was investigated by Liquid Chromatography-Organic Carbon Detection (LC-OCD) analysis. The presence of 3H (0.12 to 1.35 TU) in most samples indicates that groundwaters on the Island are modern, however the measured 14CDIC values (8.4 to 97.2 pmc) suggest that most samples are significantly older due to carbonate dissolution and recrystallisation reactions that are identified and quantified in this work. 14CDOC values (46.6 to 105.6 pMC) were higher than 14CDIC values and were well correlated with 3H values, however deeper groundwaters had lower 14CDOC values than expected. LC-OCD chromatography of these groundwaters were found to contain higher concentrations of humic substances, that are most likely attributed to the presence of paleosol horizons at depth in the limestone, which are a common feature in aeolianite deposits along the Western coast of Australia and are related to Quaternary sea level change. The paleosols likely contribute old organic matter to the deeper groundwaters, which may explain the lower 14CDOC values. This study has shown that a combined approach that utilises both DIC and DOC tracers, as well as 3H, is required to identify the sources and evolution of carbon in a groundwater system, as well as the processes that effect the application of 14C dating to groundwaters within a carbonate aquifer.

Traffic congestion and reliability : linking solutions to problems.

DOT National Transportation Integrated Search

2004-07-19

The Traffic Congestion and Reliability: Linking Solutions to Problems Report provides : a snapshot of congestion in the United States by summarizing recent trends in : congestion, highlighting the role of unreliable travel times in the effects of con...

RELATIVE ACTIONS OF QUATERNARY METHYL DERIVATIVES OF TYRAMINE, DOPAMINE AND NORADRENALINE.

PubMed

CUTHBERT, M F

1964-08-01

Tyramine methiodide and dopamine methobromide have greater pressor effect (three- to five-times) in the spinal cat than the parent amines. Noradrenaline methochloride has little pressor effect. Dopamine methobromide is about four times as potent as nicotine; tyramine methiodide is about equiactive to nicotine; and noradrenaline methochloride has only one-tenth the potency of nicotine. Their pressor effects are usually abolished by hexamethonium but in some experiments the effect of noradrenaline methochloride persisted and was then abolished by tolazoline. Injected intravenously into the cat anaesthetized with chloralose, each of the three quaternary derivatives contracts the nictitating membrane; dopamine methobromide is again the most active, having more than six times the potency of nicotine. When the contractions of the nictitating membrane are induced by continuous stimulation of the preganglionic fibres of the cervical sympathetic nerve, intravenous injection of the quaternary derivatives of tyramine and dopamine has a biphasic effect; there is a block on which a contraction of the membrane appears to be superimposed. Noradrenaline methochloride produces only a further contraction of the membrane. On the isolated rectus abdominis muscle preparation of the frog, dopamine methobromide is the most active in contracting the muscle, being about twelve times as active as nicotine; noradrenaline methochloride is weakest, having only one-hundredth the activity of nicotine. These effects are antagonized by hexamethonium. On the isolated phrenic nerve-diaphragm preparation of the rat, the quaternary derivatives of tyramine and dopamine each have neuromuscular blocking properties, 0.7- and 3-times respectively that of nicotine. Noradrenaline methochloride has no effect. In the sciatic nerve-tibialis preparation of the cat, the quaternary derivatives of tyramine and dopamine are approximately equipotent in producing neuromuscular paralysis, having about three times the activity of nicotine and one-fifth that of suxamethonium. These effects are not antagonized either by neostigmine or by edrophonium. Noradrenaline methochloride has no neuromuscular blocking effect. The nicotine-like properties of these quaternized sympathomimetic amines are discussed. It is of interest that the presence of an hydroxyl group attached to the beta-carbon atom of the side-chain greatly reduces nicotine-like activity. By comparison, choline had about one forty-fifth the pressor activity of ethyltrimethylammonium.

Relative actions of quaternary methyl derivatives of tyramine, dopamine and noradrenaline

PubMed Central

Cuthbert, M. F.

1964-01-01

Tyramine methiodide and dopamine methobromide have greater pressor effect (three- to five-times) in the spinal cat than the parent amines. Noradrenaline methochloride has little pressor effect. Dopamine methobromide is about four times as potent as nicotine; tyramine methiodide is about equiactive to nicotine; and noradrenaline methochloride has only one-tenth the potency of nicotine. Their pressor effects are usually abolished by hexamethonium but in some experiments the effect of noradrenaline methochloride persisted and was then abolished by tolazoline. Injected intravenously into the cat anaesthetized with chloralose, each of the three quaternary derivatives contracts the nictitating membrane; dopamine methobromide is again the most active, having more than six times the potency of nicotine. When the contractions of the nictitating membrane are induced by continuous stimulation of the preganglionic fibres of the cervical sympathetic nerve, intravenous injection of the quaternary derivatives of tyramine and dopamine has a biphasic effect; there is a block on which a contraction of the membrane appears to be superimposed. Noradrenaline methochloride produces only a further contraction of the membrane. On the isolated rectus abdominis muscle preparation of the frog, dopamine methobromide is the most active in contracting the muscle, being about twelve times as active as nicotine; noradrenaline methochloride is weakest, having only one-hundredth the activity of nicotine. These effects are antagonized by hexamethonium. On the isolated phrenic nerve-diaphragm preparation of the rat, the quaternary derivatives of tyramine and dopamine each have neuromuscular blocking properties, 0.7- and 3-times respectively that of nicotine. Noradrenaline methochloride has no effect. In the sciatic nerve-tibialis preparation of the cat, the quaternary derivatives of tyramine and dopamine are approximately equipotent in producing neuromuscular paralysis, having about three times the activity of nicotine and one-fifth that of suxamethonium. These effects are not antagonized either by neostigmine or by edrophonium. Noradrenaline methochloride has no neuromuscular blocking effect. The nicotine-like properties of these quaternized sympathomimetic amines are discussed. It is of interest that the presence of an hydroxyl group attached to the β-carbon atom of the side-chain greatly reduces nicotine-like activity. By comparison, choline had about one forty-fifth the pressor activity of ethyltrimethylammonium. PMID:14206269

Multicomponent homogeneous alloys and method for making same

DOEpatents

Dutta, Partha S.; Miller, Thomas R.

2003-09-02

The present application discloses a method for preparing a homogeneous ternary or quaternary alloy from a quaternary melt. The method includes providing a family of phase diagrams for the quaternary melt which shows (i) composition/temperature data, (ii) tie lines connecting equilibrium liquid and solid compositions, and (iii) isotherms representing boundaries of a miscibility gap. Based on the family of phase diagrams, a quaternary melt composition and an alloy growth temperature is selected. A quaternary melt having the selected quaternary melt composition is provided and a ternary or quaternary alloy is grown from the quaternary melt at the selected alloy growth temperature. A method for making homogeneous ternary or quaternary alloy from a ternary or quaternary melt is also disclosed, as are homogeneous quaternary single-crystal alloys which are substantially free from crystal defects and which have the formula A.sub.x B.sub.1-x C.sub.y D.sub.1-y, x and y being the same or different and in the range of 0.001 to 0.999.

A Test of the Biogenicity Criteria Established for Microfossils and Stromatolites on Quaternary Tufa and Speleothem Materials Formed in the "Twilight Zone" at Caerwys, UK.

PubMed

Brasier, A T; Rogerson, M R; Mercedes-Martin, R; Vonhof, H B; Reijmer, J J G

2015-10-01

The ability to distinguish the features of a chemical sedimentary rock that can only be attributed to biology is a challenge relevant to both geobiology and astrobiology. This study aimed to test criteria for recognizing petrographically the biogenicity of microbially influenced fabrics and fossil microbes in complex Quaternary stalactitic carbonate rocks from Caerwys, UK. We found that the presence of carbonaceous microfossils, fabrics produced by the calcification of microbial filaments, and the asymmetrical development of tufa fabrics due to the more rapid growth of microbially influenced laminations could be recognized as biogenic features. Petrographic evidence also indicates that the development of "speleothem-like" laminae was related to episodes of growth interrupted by intervals of nondeposition and erosion. The lack of any biogenic characteristics in these laminae is consistent with their development as a result of variation in the physicochemical parameters that drive calcite precipitation from meteoric waters in such environmental settings.

Statistical analyses of soil properties on a quaternary terrace sequence in the upper sava river valley, Slovenia, Yugoslavia

USGS Publications Warehouse

Vidic, N.; Pavich, M.; Lobnik, F.

1991-01-01

Alpine glaciations, climatic changes and tectonic movements have created a Quaternary sequence of gravely carbonate sediments in the upper Sava River Valley, Slovenia, Yugoslavia. The names for terraces, assigned in this model, Gu??nz, Mindel, Riss and Wu??rm in order of decreasing age, are used as morphostratigraphic terms. Soil chronosequence on the terraces was examined to evaluate which soil properties are time dependent and can be used to help constrain the ages of glaciofluvial sedimentation. Soil thickness, thickness of Bt horizons, amount and continuity of clay coatings and amount of Fe and Me concretions increase with soil age. The main source of variability consists of solutions of carbonate, leaching of basic cations and acidification of soils, which are time dependent and increase with the age of soils. The second source of variability is the content of organic matter, which is less time dependent, but varies more within soil profiles. Textural changes are significant, presented by solution of carbonate pebbles and sand, and formation is silt loam matrix, which with age becomes finer, with clay loam or clayey texture. The oldest, Gu??nz, terrace shows slight deviation from general progressive trends of changes of soil properties with time. The hypothesis of single versus multiple depositional periods of deposition was tested with one-way analysis of variance (ANOVA) on a staggered, nested hierarchical sampling design on a terrace of largest extent and greatest gravel volume, the Wu??rm terrace. The variability of soil properties is generally higher within subareas than between areas of the terrace, except for the soil thickness. Observed differences in soil thickness between the areas of the terrace could be due to multiple periods of gravel deposition, or to the initial differences of texture of the deposits. ?? 1991.

Differential Degradation of Nonylphenol Isomers by Sphingomonas xenophaga Bayram

PubMed Central

Gabriel, Frédéric L. P.; Giger, Walter; Guenther, Klaus; Kohler, Hans-Peter E.

2005-01-01

Sphingomonas xenophaga Bayram, isolated from the activated sludge of a municipal wastewater treatment plant, was able to utilize 4-(1-ethyl-1,4-dimethylpentyl)phenol, one of the main isomers of technical nonylphenol mixtures, as a sole carbon and energy source. The isolate degraded 1 mg of 4-(1-ethyl-1,4-dimethylpentyl)phenol/ml in minimal medium within 1 week. Growth experiments with five nonylphenol isomers showed that the three isomers with quaternary benzylic carbon atoms [(1,1,2,4-tetramethylpentyl)phenol, 4-(1-ethyl-1,4-dimethylpentyl)phenol, and 4-(1,1-dimethylheptyl)phenol] served as growth substrates, whereas the isomers containing one or two hydrogen atoms in the benzylic position [4-(1-methyloctyl)phenol and 4-n-nonylphenol] did not. However, when the isomers were incubated as a mixture, all were degraded to a certain degree. Differential degradation was clearly evident, as isomers with more highly branched alkyl side chains were degraded much faster than the others. Furthermore, the C9 alcohols 2,3,5-trimethylhexan-2-ol, 3,6-dimethylheptan-3-ol, and 2-methyloctan-2-ol, derived from the three nonylphenol isomers with quaternary benzylic carbon atoms, were detected in the culture fluid by gas chromatography-mass spectrometry, but no analogous metabolites could be found originating from 4-(1-methyloctyl)phenol and 4-n-nonylphenol. We propose that 4-(1-methyloctyl)phenol and 4-n-nonylphenol were cometabolically transformed in the growth experiments with the mixture but that, unlike the other isomers, they did not participate in the reactions leading to the detachment of the alkyl moiety. This hypothesis was corroborated by the observed accumulation in the culture fluid of an as yet unidentified metabolite derived from 4-(1-methyloctyl)phenol. PMID:15746308

Pseudoimpactites in anthropocenically overprinted quaternary sediments

NASA Astrophysics Data System (ADS)

Huber, Robert; Darga, Robert; Lauterbach, Hans

2017-04-01

Whereas typical anthropogenic materials such as plastics can easily be identified in the anthropocene record, other materials such as building materials or industrial waste often closely resemble natural rocks or minerals. Especially transported and weathered anthropocenic matter is hard to distinguish from natural rocks. Whereas most rock samples may easily be distinguished by visual inspection, definite identification of exotic and small sized matter is not always an easy exercise which has been shown during the controversial discussion on the cosmic origin of carbon spherules found in Younger Dryas sediments. Similarly, a variety of exotic materials and lithological phenomena reported from quaternary sediments in Upper Bavaria have been associated to a cosmic impact in the area. Findings of carbonatic regmaglypts, glass coated and fragmented rocks, glassy carbon or pumice like carbon have been proposed to represent impact related rocks, an hypothesis which has further been supported by findings of iron silicides and the postulated detection of nanodiamonds and Carbine. Many of these findings have been strongly doubted within the geoscientific community, however a systematic, independent investigation of these phenomena has not yet been conducted. We present the results of our examinations which have been carried out to critically test the impact related origin of the mentioned strange materials and rocks. We could identify some key sites and independently collected samples of several of the materials and analysed these thoroughly. We found that the majority of these impact related materials is of anthropogenic or biogenic origin, thus they are pseudoimpactites partly originating from old fireplaces and waste pits. The claimed cosmic origin of this matter is an illusion caused by the anthropocene overprint of the original sedimentary record.

Deep Ocean Circulation and Nutrient Contents from Atlantic-Pacific Gradients of Neodymium and Carbon Isotopes During the Last 1 Ma

NASA Astrophysics Data System (ADS)

Piotrowski, A. M.; Elderfield, H.; Howe, J. N. W.

2014-12-01

The last few million years saw changing boundary conditions to the Earth system which set the stage for bi-polar glaciation and Milankovich-forced glacial-interglacial cycles which dominate Quaternary climate variability. Recent studies have highlighted the relative importance of temperature, ice volume and ocean circulation changes during the Mid-Pleistocene Transition at ~900 ka (Elderfield et al., 2012, Pena and Goldstein, 2014). Reconstructing the history of global deep water mass propagation and its carbon content is important for fully understanding the ocean's role in amplifying Milankovich changes to cause glacial-interglacial transitions. A new foraminiferal-coating Nd isotope record from ODP Site 1123 on the deep Chatham Rise is interpreted as showing glacial-interglacial changes in the bottom water propagation of Atlantic-sourced waters into the Pacific via the Southern Ocean during the last 1 million years. This is compared to globally-distributed bottom water Nd isotope records; including a new deep western equatorial Atlantic Ocean record from ODP Site 929, as well as published records from ODP 1088 and Site 1090 in the South Atlantic (Pena and Goldstein, 2014), and ODP 758 in the deep Indian Ocean (Gourlan et al., 2010). Atlantic-to-Pacific gradients in deep ocean neodymium isotopes are constructed for key time intervals to elucidate changes in deep water sourcing and circulation pathways through the global ocean. Benthic carbon isotopes are used to estimate deep water nutrient contents of deep water masses and constrain locations and modes of deep water formation. References: Elderfield et al. Science 337, 704 (2012) Pena and Goldstein, Science 345, 318 (2014) Gourlan et al., Quaternary Science Reviews 29, 2484-2498 (2010)

Revealing the Origin of Activity in Nitrogen-Doped Nanocarbons towards Electrocatalytic Reduction of Carbon Dioxide.

PubMed

Xu, Junyuan; Kan, Yuhe; Huang, Rui; Zhang, Bingsen; Wang, Bolun; Wu, Kuang-Hsu; Lin, Yangming; Sun, Xiaoyan; Li, Qingfeng; Centi, Gabriele; Su, Dangsheng

2016-05-23

Carbon nanotubes (CNTs) are functionalized with nitrogen atoms for reduction of carbon dioxide (CO2 ). The investigation explores the origin of the catalyst's activity and the role of nitrogen chemical states therein. The catalysts show excellent performances, with about 90 % current efficiency for CO formation and stability over 60 hours. The Tafel analyses and density functional theory calculations suggest that the reduction of CO2 proceeds through an initial rate-determining transfer of one electron to CO2 , which leads to the formation of carbon dioxide radical anion (CO2 (.-) ). The initial reduction barrier is too high on pristine CNTs, resulting in a very high overpotentials at which the hydrogen evolution reaction dominates over CO2 reduction. The doped nitrogen atoms stabilize the radical anion, thereby lowering the initial reduction barrier and improving the intrinsic activity. The most efficient nitrogen chemical state for this reaction is quaternary nitrogen, followed by pyridinic and pyrrolic nitrogen. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A Bayesian ridge regression analysis of congestion's impact on urban expressway safety.

PubMed

Shi, Qi; Abdel-Aty, Mohamed; Lee, Jaeyoung

2016-03-01

With the rapid growth of traffic in urban areas, concerns about congestion and traffic safety have been heightened. This study leveraged both Automatic Vehicle Identification (AVI) system and Microwave Vehicle Detection System (MVDS) installed on an expressway in Central Florida to explore how congestion impacts the crash occurrence in urban areas. Multiple congestion measures from the two systems were developed. To ensure more precise estimates of the congestion's effects, the traffic data were aggregated into peak and non-peak hours. Multicollinearity among traffic parameters was examined. The results showed the presence of multicollinearity especially during peak hours. As a response, ridge regression was introduced to cope with this issue. Poisson models with uncorrelated random effects, correlated random effects, and both correlated random effects and random parameters were constructed within the Bayesian framework. It was proven that correlated random effects could significantly enhance model performance. The random parameters model has similar goodness-of-fit compared with the model with only correlated random effects. However, by accounting for the unobserved heterogeneity, more variables were found to be significantly related to crash frequency. The models indicated that congestion increased crash frequency during peak hours while during non-peak hours it was not a major crash contributing factor. Using the random parameter model, the three congestion measures were compared. It was found that all congestion indicators had similar effects while Congestion Index (CI) derived from MVDS data was a better congestion indicator for safety analysis. Also, analyses showed that the segments with higher congestion intensity could not only increase property damage only (PDO) crashes, but also more severe crashes. In addition, the issues regarding the necessity to incorporate specific congestion indicator for congestion's effects on safety and to take care of the multicollinearity between explanatory variables were also discussed. By including a specific congestion indicator, the model performance significantly improved. When comparing models with and without ridge regression, the magnitude of the coefficients was altered in the existence of multicollinearity. These conclusions suggest that the use of appropriate congestion measure and consideration of multicolilnearity among the variables would improve the models and our understanding about the effects of congestion on traffic safety. Copyright © 2015 Elsevier Ltd. All rights reserved.

Geochemical and Sedimentological Records of Late Quaternary Climate Change, Lake Tanganyika, Tropical East Africa

NASA Astrophysics Data System (ADS)

Felton, A. A.; Russell, J. M.; Cohen, A. S.; Baker, M. E.; McGlue, M. M.; Lezzar, K. E.

2005-12-01

We have analyzed piston core records from Lake Tanganyika (western Tanzania, East African Rift Valley) to investigate possible signals of tropical paleoclimate change during the Late Quaternary. Long paleoclimate records from East Africa are of importance for understanding climatic processes such as the role of solar variability in regulating tropical climates at Milankovitch time scales, and the relationship between abrupt climate changes, migration of Intertropical Convergence Zone, and regional climate variability (Nicholson, 2000). However, records of pre-Holocene climate variability from tropical African lakes (>25ka) are still quite rare. Long records from Lake Tanganyika are of particular interest given the lake's antiquity and its demonstrated potential for producing high resolution (frequently annually laminated) sedimentary records (Cohen et al., 1993). We analyzed physical properties, grain size, total organic carbon, major, minor and trace element variability, and biogenic silica data for a 7.75 m core from the Kalya slope and horst region of central Lake Tanganyika at 640m water depth. Nine 14C dates provide an age model for the core, which spans ~62 cal kyr. Elemental concentrations preserved in Lake Tanganyika sediments record variability in deposition and runoff into the lake basin. Under conditions of rapid erosion, exposure and rapid weathering of bedrock has been shown to generate high concentrations of original silicate minerals enriched in soluble cations such as sodium and potassium, elements that are also biologically conservative. Prior to 40ka cal yr. core sediments are characterized by high magnetic susceptibility, intermediate levels of organic carbon, low to intermediate levels of biogenic silica, and fine grain size, indicative of relatively high precipitation. There is a profound decrease in magnetic susceptibility, a decrease in organic carbon and an increase in grain size at 40ka cal yr, which persists until ~16ka cal yr. Seismic reflection profiles demonstrate the existence of paleodeltas at ~360m below modern lake level that may have formed during this period, although it is unclear whether this deposit represents a Late Quaternary (OIS 2) or earlier (OIS 6) event. Maximum aridity occurred at about 20-20.5ka cal yr, consist with earlier interpretations of lake lowstands (Gasse et al., 1989, Scholz et al., 1997). The late Pleistocene and earliest Holocene sediments in our record are characterized by generally rising magnetic susceptibility, declining organic carbon and biogenic silica, and finer grain size. However during this period there are marked fluctuations in magnetic susceptibility and biogenic silica at millennial time-scales. These indicate intervals of fluctuating precipitation, productivity, and possibly windiness and are particularly prominent during the Pleistocene-Holocene transition. Massive clays, rising magnetic susceptibility, low biogenic silica and low organic carbon mark the early Holocene, indicative of increased rainfall during a regionally wet interval. These sediments are capped by a laminated ooze, indicative of drier conditions and a more stratified water body.

A study of low-dimensional quaternary mixed-transition metal chalcogenides

NASA Astrophysics Data System (ADS)

Oledzka, Magdalena Agata

New quaternary alkali metal mixed-transition metal sulfides: ACuMSsb2 (A = K, Rb, Cs; M = Mn, Fe, Co) and KCosb{2-x}Cusb{x}Ssb2 (0.5 ≤ x ≤ 1.5) were prepared by CSsb2/Nsb2 sulfurization of a mixture of oxide or sulfide and carbonate precursors of the corresponding metals. All of the phases form in the tetragonal ThCrsb2Sisb2-type structure in space group I4/mmm. The ACoCuSsb2 phases are semiconducting, with room temperature resistivities rhosbRT˜ 10sp{-2}Omega {*}cm;\\ KCosb{0.5}CUsb{1.5}Ssb2 is metallic with a metal-to-nonmetal transition at ˜120 K. Seebeck measurements indicate that the majority of charge carriers are holes. The temperature dependence of magnetic susceptibility shows an anomalous transition to the ferromagnetic state in the ACoCuSsb2 phases. The electrical and magnetic properties of the new quaternary phases are compared to those of ternary ACosb2Ssb2 (A = K, Rb, Cs). The quaternary sulfides ACuFeSsb2 show semiconducting behavior. Magnetic susceptibility data indicate the presence of localized magnetic moment arising from the di- and trivalent iron ions. The semiconducting properties observed in this system are in contrast to the metallic behavior predicted by theoretical calculations. Investigations of the electrical properties of the sulfides ACuMnSsb2 revealed semiconducting behavior with a broad anomaly at ≈70 K. In the temperature range 100-300 K, the molar magnetic susceptibility of all the samples shows a weak maximum consistent with localized antiferromagnetic exchange of isolated two-dimensional manganese cluster nets. The divergence of the FC and ZFC molar susceptibilities at low temperatures, for all the samples, suggests spin-glass-type behavior with a well defined freezing temperature of ≈35 K. Single phase polycrystalline quaternary selenides ACuMnSesb2 (A = K, Rb, Cs) were prepared for the first time by the reduction of the mixture containing corresponding alkali metal carbonates, copper oxide, manganese and selenium powders. p-Type semiconducting behavior was observed for the samples with rhosbRT of {˜}10sp{-1}Omega{*}cm, and Esba˜ 0.1 eV. The relatively high values of magnetic susceptibility and the weak maximum in the temperature dependence of the magnetic susceptibility above 100 K was attributed to short-range antiferromagnetic interactions. New quaternary layered sulfides: NaCuMSsb2 (M = Mn, Fe, Co, Zn) crystallize in the trigonal CaAlsb2Sisb2-type structure in space group P{bar 3}m1. All the new phases are semiconducting, with rhosb{RT} varying from 6.2× 10sp{-1} to 5× 10sp{-2}Omega{*}cm, depending upon the transition metal M. Magnetic susceptibility measurements indicate the presence of localized Mnsp{2+} ions in NaCuMnSsb2. The NaCuMSsb2 (M = Fe, Co) phases display temperature independent paramagnetism whereas the NaCuZnSsb2 phase is diamagnetic, as expected. In addition, detailed low-temperature magnetic studies of the NaCuFeSsb2 phase revealed spin-glass-type behavior with the freezing temperature Tsbf˜ 50 K.

2012 urban congestion trends, operations : the key to reliable travel.

DOT National Transportation Integrated Search

2013-04-01

Congestion levels remained relatively unchanged : from 2011 to 2012 in the 19 urban areas in the United States monitored : in this report. : Congestion levels across all of the congestion measures are still generally : below the levels experienced in...

Desloratadine and pseudoephedrine combination therapy as a comprehensive treatment for allergic rhinitis and nasal congestion.

PubMed

Anolik, Robert

2009-06-01

Allergic rhinitis (AR) is rapidly increasing in global prevalence. Symptoms of AR, particularly nasal congestion, can cause quality of life (QoL) impairment. Second-generation antihistamines are a recommended first-line therapy for AR but are not viewed as very effective for the treatment of congestion. Therefore, an antihistamine plus a decongestant, such as the combination of desloratadine and pseudoephedrine, is a convenient and efficacious treatment. To review the clinical evidence on the efficacy and safety of combination desloratadine/pseudoephedrine for the treatment of AR symptoms, particularly nasal congestion. Four large studies found that improvement in nasal congestion is enhanced when patients are treated with combination desloratadine/pseudoephedrine. The combination drug significantly improved mean reflective nasal congestion scores in these studies compared with either component as monotherapy (p

Quaternary sea-level history and the origin of the northernmost coastal aeolianites in the Americas: Channel Islands National Park, California, USA

USGS Publications Warehouse

Muhs, Daniel; Pigati, Jeffrey S.; Schumann, R. Randall; Skipp, Gary L.; Porat, Naomi; DeVogel, Stephen B.

2018-01-01

Along most of the Pacific Coast of North America, sand dunes are dominantly silicate-rich. On the California Channel Islands, however, dunes are carbonate-rich, due to high productivity offshore and a lack of dilution by silicate minerals. Older sands on the Channel Islands contain enough carbonate to be cemented into aeolianite. Several generations of carbonate aeolianites are present on the California Channel Islands and represent the northernmost Quaternary coastal aeolianites on the Pacific Coast of North America. The oldest aeolianites on the islands may date to the early Pleistocene and thus far have only been found on Santa Cruz Island. Aeolianites with well-developed soils are found on both San Miguel Island and Santa Rosa Island and likely date to the middle Pleistocene. The youngest and best-dated aeolianites are located on San Miguel Island and Santa Rosa Island. These sediments were deposited during the late Pleistocene following the emergence of marine terraces that date to the last interglacial complex (~ 120,000 yr to ~ 80,000 yr). Based on radiocarbon and luminescence dating, the ages of these units correspond in time with marine isotope stages [MIS] 4, 3, and 2. Sea level was significantly lower than present during all three time periods. Reconstruction of insular paleogeography indicates that large areas to the north and northwest of the islands would have been exposed at these times, providing a ready source of carbonate-rich skeletal sands. These findings differ from a previously held concept that carbonate aeolianites are dominantly an interglacial phenomenon forming during high stands of sea. In contrast, our results are consistent with the findings of other investigators of the past decade who have reported evidence of glacial-age and interstadial-age aeolianites on coastlines of Australia and South Africa. They are also consistent with observations made by Darwin regarding the origin of aeolianites on the island of St. Helena, in the South Atlantic Ocean, more than a century and a half ago.

Paleo-fluid flow in folded, poorly lithified Quaternary sediments revealed by diagenetic concretions developed during the growth of Quattro Castella Anticline (Northern Apennines, Italy)

NASA Astrophysics Data System (ADS)

Pizzati, Mattia; Balsamo, Fabrizio; Iacumin, Paola; Swennen, Rudy; Storti, Fabrizio

2017-04-01

Diagenetic concretions and mineral masses may provide a useful tool to better understand paleo-fluid flows in transforming porous media. Moreover, the selective cementation responsible of diagenetic alterations formation, plays a key role in diminishing sediments porosity and permeability and hence reservoir quality. In compressive settings of a fold-and-thrust-belt, the presence of deep or blind thrusts could lead to the generation of folds which may influence syn-kinematic sedimentation, deep fluids migration and shallow fluid flow pattern. In this contribution we present a multidisciplinary field and laboratory study on carbonate concretions developed in Quaternary poorly lithified, shallow marine syn-kinematic sediments of the Quattro Castella Anticline in Northern Apennines (Italy). The study site is located along the Enza River, where shallow marine to continental sediments are exposed along the forelimb of the fold nucleated during Late Miocene and still active today. Field mapping was aimed to link bedding attitude of syn-kinematic sediments with the geometry, arrangement, shape and size of concretionary bodies. The studied concretions are both tabular (i.e. parallel to sediment bedding) and elongate single or coalescent concretionary bodies (i.e. plunging at different angle to bedding dip throughout the stratigraphic section). Concretions dimensions range from a few centimeters in single elongate concretions, up to a few meters in tabular and coalescent ones. In situ permeability measurements and laboratory grain size analyses were performed along the studied section to constrain the petrophysical properties of sediments hosting carbonate concretions. Carbon and oxygen stable isotopes analyses on carbonate concretions (performed both on hand specimens and also on thin sections), together with petrographic and cathodoluminescence observations, were used to better constrain the diagenetic environment in which calcite precipitation occurred. Our results indicate that the growing anticline promoted the development of a local topographic and hydraulic gradient which induced cement precipitation in the form of carbonate concretions in syn-kinematic sediments. Such diagenetic alterations can be a good marker to reconstruct the paleo-fluid flow history in structurally complex siliciclastic reservoirs.

CO2 outburst events in relation to seismicity: Constraints from microscale geochronology, geochemistry of late Quaternary vein carbonates, SW Turkey

NASA Astrophysics Data System (ADS)

Ünal-İmer, Ezgi; Uysal, I. Tonguç; Zhao, Jian-Xin; Işık, Veysel; Shulmeister, James; İmer, Ali; Feng, Yue-Xing

2016-08-01

Vein and breccia carbonates precipitated in a highly fractured/faulted carbonate bedrock in SW Turkey were investigated through high-resolution U-series geochronology, microstructural and geochemical studies including C-O-Sr isotope and rare-earth element and yttrium (REY) analyses. Petrographical observations and geochronological data are interpreted as evidence that the calcite veins formed through a crack-seal mechanism, mostly accompanied/initiated by intensive hydraulic fracturing of the host limestone in response to high-pressure fluids, which is manifested by multi-stage breccia deposits. Microscale U-series dates (272.6-20.5 kyr) and geochemical compositions of the vein/breccia samples provide information on the timing and mechanism of the vein formation and identify the source of CO2-bearing fluids responsible for the carbonate precipitation. δ18OVPDB and δ13CVPDB values of the calcite veins range between -5.9 and -1.7‰, and -10.6 and -4.6‰, respectively. The isotopic compositions of the veins show highly fluctuating values as calcite grew successively perpendicular to vein walls, which, in combination with microstructural and geochronological constraints, are interpreted to reflect episodic CO2 degassing events associated with seismic and aseismic deformation. Oxygen and Sr isotope compositions (δ18OVPDB: -5.9 to -1.7‰; 87Sr/86Sr: 0.7082 to 0.7085) together with REY concentrations indicate deep infiltration of meteoric waters with various degrees of interactions mostly with the host limestone and siliciclastic parts of the basement rocks. Oxygen and carbon isotope compositions suggest CO2 degassing through intensive limestone dissolution. While majority of the veins display similar Post-Archaean Australian Shale (PAAS)-normalised REY variations, some of the veins show positive EuPAAS anomalies, which could be indicative of contributions from a deeply derived, heated, and reduced fluid component, giving rise to multiple fluid sources for the calcite veins. Vein calcite formed in fault-induced fractures offers insights into structural features, genetic characterisation of the parental fluids, and late Quaternary degassing of subsurface CO2 accumulations.

Global ice-sheet system interlocked by sea level

NASA Astrophysics Data System (ADS)

Denton, George H.; Hughes, Terence J.; Karlén, Wibjörn

1986-07-01

Denton and Hughes (1983, Quaternary Research20, 125-144) postulated that sea level linked a global ice-sheet system with both terrestrial and grounded marine components during late Quaternary ice ages. Summer temperature changes near Northern Hemisphere melting margins initiated sea-level fluctuations that controlled marine components in both polar hemispheres. It was further proposed that variations of this ice-sheet system amplified and transmitted Milankovitch summer half-year insolation changes between 45 and 75°N into global climatic changes. New tests of this hypothesis implicate sea level as a major control of the areal extent of grounded portions of the Antarctic Ice Sheet, thus fitting the concept of a globally interlocked ice-sheet system. But recent atmospheric modeling results ( Manabe and Broccoli, 1985, Journal of Geophysical Research90, 2167-2190) suggest that factors other than areal changes of the grounded Antarctic Ice Sheet strongly influenced Southern Hemisphere climate and terminated the last ice age simultaneously in both polar hemispheres. Atmospheric carbon dioxide linked to high-latitude oceans is the most likely candidate ( Shackleton and Pisias, 1985, Atmospheric carbon dioxide, orbital forcing, and climate. In "The Carbon Cycle and Atmospheric CO 2: Natural Variations Archean to Present" (E. T. Sundquest and W. S. Broecker, Eds.), pp. 303-318. Geophysical Monograph 32, American Geophysical Union, Washington, D.C.), but another potential influence was high-frequency climatic oscillations (2500 yr). It is postulated that variations in atmospheric carbon dioxide acted through an Antarctic ice shelf linked to the grounded ice sheet to produce and terminate Southern Hemisphere ice-age climate. It is further postulated that Milankovitch summer insolation combined with a warm high-frequency oscillation caused marked recession of Northern Hemisphere ice-sheet melting margins and the North Atlantic polar front about 14,000 14C yr B.P. This permitted renewed formation of North Atlantic Deep Water, which could well have controlled atmospheric carbon dioxide ( W. S. Broecker, D. M. Peteet, and D. Rind, 1985, Nature ( London) 315, 21-26). Combined melting and consequent sea-level rise from the three warming factors initiated irreversible collapse of the interlocked global ice-sheet system, which was at its largest but most vulnerable configuration.

Comparative analyses of quaternary arrangements in homo-oligomeric proteins in superfamilies: Functional implications.

PubMed

Sudha, Govindarajan; Srinivasan, Narayanaswamy

2016-09-01

A comprehensive analysis of the quaternary features of distantly related homo-oligomeric proteins is the focus of the current study. This study has been performed at the levels of quaternary state, symmetry, and quaternary structure. Quaternary state and quaternary structure refers to the number of subunits and spatial arrangements of subunits, respectively. Using a large dataset of available 3D structures of biologically relevant assemblies, we show that only 53% of the distantly related homo-oligomeric proteins have the same quaternary state. Considering these homologous homo-oligomers with the same quaternary state, conservation of quaternary structures is observed only in 38% of the pairs. In 36% of the pairs of distantly related homo-oligomers with different quaternary states the larger assembly in a pair shows high structural similarity with the entire quaternary structure of the related protein with lower quaternary state and it is referred as "Russian doll effect." The differences in quaternary state and structure have been suggested to contribute to the functional diversity. Detailed investigations show that even though the gross functions of many distantly related homo-oligomers are the same, finer level differences in molecular functions are manifested by differences in quaternary states and structures. Comparison of structures of biological assemblies in distantly and closely related homo-oligomeric proteins throughout the study differentiates the effects of sequence divergence on the quaternary structures and function. Knowledge inferred from this study can provide insights for improved protein structure classification and function prediction of homo-oligomers. Proteins 2016; 84:1190-1202. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

Hybrid carbon nanoparticles modified core-shell silica: a high efficiency carbon-based phase for hydrophilic interaction liquid chromatography.

PubMed

Ibrahim, Mohammed E A; Wahab, M Farooq; Lucy, Charles A

2014-04-11

Hydrophilic interaction liquid chromatography (HILIC) is a fast growing separation technique for hydrophilic and polar analytes. In this work, we combine the unique selectivity of carbon surfaces with the high efficiency of core-shell silica. First, 5 μm core-shell silica is electrostatically coated with 105 nm cationic latex bearing quaternary ammonium groups. Then 50 nm anionic carbon nanoparticles are anchored onto the surface of the latex coated core-shell silica particles to produce a hybrid carbon-silica phase. The hybrid phase shows different selectivity than ten previously classified HILIC column chemistries and 36 stationary phases. The hybrid HILIC phase has shape selectivity for positional isomeric pairs (phthalic/isophthalic and 1-naphthoic/2-naphthoic acids). Fast and high efficiency HILIC separations of biologically important carboxylates, phenols and pharmaceuticals are reported with efficiencies up to 85,000 plates m(-1). Reduced plate height of 1.9 (95,000 plates m(-1)) can be achieved. The hybrid phase is stable for at least 3 months of usage and storage under typical HILIC eluents. Copyright © 2014 Elsevier B.V. All rights reserved.

Deconvoluting Mixtures ofEmissions Sources to Investigate PM2.5's Ability to Generate Reactive Oxygen Species and its Associations with Cardiorespiratory Effects

NASA Astrophysics Data System (ADS)

Weber, R. J.; Bates, J.; Abrams, J.; Verma, V.; Fang, T.; Klein, M.; Strickland, M. J.; Sarnat, S. E.; Chang, H. H.; Mulholland, J. A.; Tolbert, P. E.; Russell, A. G.

2015-12-01

It is hypothesized that fine particulate matter (PM2.5) inhalation can catalytically generate reactive oxygen species (ROS) in excess of the body's antioxidant capacity, leading to oxidative stress and ultimately adverse health. PM2.5 emissions from different sources vary widely in chemical composition, with varied effects on the body. Here, the ability of mixtures of different sources of PM2.5 to generate ROS and associations of this capability with acute health effects were investigated. A dithiothreitol (DTT) assay that integrates over different sources was used to quantify ROS generation potential of ambient water-soluble PM2.5 in Atlanta from June 2012 - June 2013. PM2.5 source impacts, estimated using the Chemical Mass Balance method with ensemble-averaged source impact profiles, were related to DTT activity using a linear regression model, which provided information on intrinsic DTT activity (i.e., toxicity) of each source. The model was then used to develop a time series of daily DTT activity over a ten-year period (1998-2010) for use in an epidemiologic study. Light-duty gasoline vehicles exhibited the highest intrinsic DTT activity, followed by biomass burning and heavy-duty diesel vehicles. Biomass burning contributed the largest fraction to total DTT activity, followed by gasoline and diesel vehicles (45%, 20% and 14%, respectively). These results suggest the importance of aged oxygenated organic aerosols and metals in ROS generation. Epidemiologic analyses found significant associations between estimated DTT activity and emergency department visits for congestive heart failure and asthma/wheezing attacks in the 5-county Atlanta area. Estimated DTT activity was the only pollutant measure out of PM2.5, O3, and PM2.5 constituents elemental carbon and organic carbon) that exhibited a significant link to congestive heart failure. In two-pollutant models, DTT activity was significantly associated with asthma/wheeze and congestive heart failure while PM2.5 was not, which supports the hypothesis that PM2.5 health effects are, in part, due to oxidative stress and that DTT activity may be a better indicator of some aerosol-related health effects than PM2.5 mass.

Contemporary approaches to congestion pricing : lessons learned from the national evaluation of congestion pricing strategies at six sites.

DOT National Transportation Integrated Search

2015-08-01

This document represents the final report of the national evaluation of congestion reduction strategies at six sites that received federal funding under the Urban Partnership Agreement (UPA) and Congestion Reduction Demonstration (CRD) programs. The ...

Mobility and the costs of congestion in New Jersey : 2001 update

DOT National Transportation Integrated Search

2001-07-01

The objective of the Mobility and the Costs of Congestion study is to measure quantifiable and qualitative impacts of roadway congestion in New Jersey. The study addresses the impacts of congestion on an average traveler or affected person, as well a...

Diagnosis and management of nasal congestion: the role of intranasal corticosteroids.

PubMed

Benninger, Michael

2009-01-01

Nasal congestion is considered the most bothersome of allergic rhinitis (AR) symptoms and can significantly impair ability to function at work, home, and school. Effective management of AR-related nasal congestion depends on accurate diagnosis and appropriate treatment. Many individuals with AR and AR-related congestion remain undiagnosed and do not receive prescription medication. However, new tools intended to improve the diagnosis of nasal congestion have been developed and validated. Intranasal corticosteroids (INSs) are recommended as first-line therapy for patients with moderate-to-severe AR and also when nasal congestion is a prominent symptom. Double blind, randomized clinical trials have demonstrated greater efficacy of INSs versus placebo, antihistamines, or montelukast for relief of all nasal symptoms, especially congestion. Patient adherence to treatment also affects outcomes, and this may be influenced by patient preferences for the sensory attributes of an individual drug. Increased awareness of the effects of AR-related nasal congestion, the efficacy and safety of available pharmacotherapies, and barriers to adherence may improve clinical outcomes.

Studies toward the synthesis of palhinine lycopodium alkaloids: a Morita-Baylis-Hillman/intramolecular Diels-Alder approach.

PubMed

Sizemore, Nicholas; Rychnovsky, Scott D

2014-02-07

A synthetic route to the isotwistane core of palhinine lycopodium alkaloids is described. A Morita-Baylis-Hillman/intramolecular Diels-Alder (IMDA) strategy sets the vicinal all-carbon quaternary centers present in this family of natural products. The regioselectivity of the IMDA reaction is dictated by the conditions employed for silyl enol ether formation, with one set of conditions providing the core of cardionine and alternate conditions generating the desired isotwistane core of isopalhinine.

Silyl Ketene Imines: Highly Versatile Nucleophiles for Catalytic, Asymmetric Synthesis

PubMed Central

Denmark, Scott E.; Wilson, Tyler W.

2012-01-01

This Minireview provides an overview on the development of silyl ketene imines and their recent applications in catalytic, enantioselective reactions. The unique structure of the ketene imine allows a diverse range of reactivity patterns and provides solutions to existing challenges in the enantioselective construction of quaternary stereogenic carbon centers and cross-benzoin adducts. A variety of reactions for which silyl ketene imines have been applied are presented with an overall goal of inspiring new uses for these underutilized nucleophiles. PMID:22968901

Stereoselectivity in N-Iminium Ion Cyclization: Development of an Efficient Synthesis of (±)-Cephalotaxine.

PubMed

Liu, Hao; Yu, Jing; Li, Xinyu; Yan, Rui; Xiao, Ji-Chang; Hong, Ran

2015-09-18

A stereoselective N-iminium ion cyclization with allylsilane to construct vicinal quaternary-tertiary carbon centers was developed for the concise synthesis of (±)-cephalotaxine. The current strategy features a TiCl4-promoted cyclization and ring-closure metathesis to furnish the spiro-ring system. The stereochemical outcome in the N-acyliminium ion cyclization was rationalized by the stereoelectronic effect of the Z- or E-allylsilane. Two diastereomers arising from the cyclization were merged into the formal synthesis of (±)-cephalotaxine.

Signalling and obfuscation for congestion control

NASA Astrophysics Data System (ADS)

Mareček, Jakub; Shorten, Robert; Yu, Jia Yuan

2015-10-01

We aim to reduce the social cost of congestion in many smart city applications. In our model of congestion, agents interact over limited resources after receiving signals from a central agent that observes the state of congestion in real time. Under natural models of agent populations, we develop new signalling schemes and show that by introducing a non-trivial amount of uncertainty in the signals, we reduce the social cost of congestion, i.e., improve social welfare. The signalling schemes are efficient in terms of both communication and computation, and are consistent with past observations of the congestion. Moreover, the resulting population dynamics converge under reasonable assumptions.

Improving Explicit Congestion Notification with the Mark-Front Strategy

NASA Technical Reports Server (NTRS)

Liu, Chunlei; Jain, Raj

2001-01-01

Delivering congestion signals is essential to the performance of networks. Current TCP/IP networks use packet losses to signal congestion. Packet losses not only reduces TCP performance, but also adds large delay. Explicit Congestion Notification (ECN) delivers a faster indication of congestion and has better performance. However, current ECN implementations mark the packet from the tail of the queue. In this paper, we propose the mark-front strategy to send an even faster congestion signal. We show that mark-front strategy reduces buffer size requirement, improves link efficiency and provides better fairness among users. Simulation results that verify our analysis are also presented.

23 CFR 971.214 - Federal lands congestion management system (CMS).

Code of Federal Regulations, 2011 CFR

2011-04-01

... congestion management strategies; (v) Determine methods to monitor and evaluate the performance of the multi... Federal lands congestion management system (CMS). (a) For purposes of this section, congestion means the... for the transportation systems providing access to and within National Forests, as appropriate, that...

23 CFR 970.214 - Federal lands congestion management system (CMS).

Code of Federal Regulations, 2014 CFR

2014-04-01

... 23 Highways 1 2014-04-01 2014-04-01 false Federal lands congestion management system (CMS). 970... LANDS HIGHWAYS NATIONAL PARK SERVICE MANAGEMENT SYSTEMS National Park Service Management Systems § 970.214 Federal lands congestion management system (CMS). (a) For purposes of this section, congestion...

Carbon emissions tax policy of urban road traffic and its application in Panjin, China

PubMed Central

Yang, Longhai; Fang, Lin

2018-01-01

How to effectively solve traffic congestion and transportation pollution in urban development is a main research emphasis for transportation management agencies. A carbon emissions tax can affect travelers’ generalized costs and will lead to changes in passenger demand, mode choice and traffic flow equilibrium in road networks, which are of significance in green travel and low-carbon transportation management. This paper first established a mesoscopic model to calculate the carbon emissions tax and determined the value of this charge in China, which was based on road traffic flow, vehicle speed, and carbon emissions. Referring to existing research results to calibrate the value of time, this paper modified the traveler’s generalized cost function, including the carbon emissions tax, fuel surcharge and travel time cost, which can be used in the travel impedance model with the consideration of the carbon emissions tax. Then, a method for analyzing urban road network traffic flow distribution was put forward, and a joint traffic distribution model was established, which considered the relationship between private cars and taxis. Finally, this paper took the city of Panjin as an example to analyze the road traffic carbon emissions tax’s impact. The results illustrated that the carbon emissions tax has a positive effect on road network flow equilibrium and carbon emission reduction. This paper will have good reference value and practical significance for the calculation and implementation of urban traffic carbon emissions taxes in China. PMID:29738580

Carbon emissions tax policy of urban road traffic and its application in Panjin, China.

PubMed

Yang, Longhai; Hu, Xiaowei; Fang, Lin

2018-01-01

How to effectively solve traffic congestion and transportation pollution in urban development is a main research emphasis for transportation management agencies. A carbon emissions tax can affect travelers' generalized costs and will lead to changes in passenger demand, mode choice and traffic flow equilibrium in road networks, which are of significance in green travel and low-carbon transportation management. This paper first established a mesoscopic model to calculate the carbon emissions tax and determined the value of this charge in China, which was based on road traffic flow, vehicle speed, and carbon emissions. Referring to existing research results to calibrate the value of time, this paper modified the traveler's generalized cost function, including the carbon emissions tax, fuel surcharge and travel time cost, which can be used in the travel impedance model with the consideration of the carbon emissions tax. Then, a method for analyzing urban road network traffic flow distribution was put forward, and a joint traffic distribution model was established, which considered the relationship between private cars and taxis. Finally, this paper took the city of Panjin as an example to analyze the road traffic carbon emissions tax's impact. The results illustrated that the carbon emissions tax has a positive effect on road network flow equilibrium and carbon emission reduction. This paper will have good reference value and practical significance for the calculation and implementation of urban traffic carbon emissions taxes in China.

23 CFR 450.320 - Congestion management process in transportation management areas.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 23 Highways 1 2014-04-01 2014-04-01 false Congestion management process in transportation... Programming § 450.320 Congestion management process in transportation management areas. (a) The transportation planning process in a TMA shall address congestion management through a process that provides for safe and...

23 CFR 450.320 - Congestion management process in transportation management areas.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 23 Highways 1 2011-04-01 2011-04-01 false Congestion management process in transportation... Programming § 450.320 Congestion management process in transportation management areas. (a) The transportation planning process in a TMA shall address congestion management through a process that provides for safe and...

23 CFR 450.320 - Congestion management process in transportation management areas.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 23 Highways 1 2013-04-01 2013-04-01 false Congestion management process in transportation... Programming § 450.320 Congestion management process in transportation management areas. (a) The transportation planning process in a TMA shall address congestion management through a process that provides for safe and...

76 FR 75875 - Plan for Conduct of 2012 Electric Transmission Congestion Study

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-05

... DEPARTMENT OF ENERGY Plan for Conduct of 2012 Electric Transmission Congestion Study AGENCY... preparation of a study of electric transmission congestion pursuant to section 216(a)(1) of the Federal Power...-register at this Web site: http://energy.gov/oe/congestion-study-2012 . [[Page 75876

Active noise control for infant incubators.

PubMed

Yu, Xun; Gujjula, Shruthi; Kuo, Sen M

2009-01-01

This paper presents an active noise control system for infant incubators. Experimental results show that global noise reduction can be achieved for infant incubator ANC systems. An audio-integration algorithm is presented to introduce a healthy audio (intrauterine) sound with the ANC system to mask the residual noise and soothe the infant. Carbon nanotube based transparent thin film speaker is also introduced in this paper as the actuator for the ANC system to generate the destructive secondary sound, which can significantly save the congested incubator space and without blocking the view of doctors and nurses.

Isotope Geochemistry of Possible Terrestrial Analogue for Martian Meteorite ALH84001

NASA Technical Reports Server (NTRS)

Mojzsis, Stephen J.

2000-01-01

We have studied the microdomain oxygen and carbon isotopic compositions by SIMS of complex carbonate rosettes from spinel therzolite xenoliths, hosted by nepheline basanite, from the island of Spitsbergen (Norway). The Quaternary volcanic rocks containing the xenoliths erupted into a high Arctic environment and through relatively thick continental crust containing carbonate rocks. We have attempted to constrain the sources of the carbonates in these rocks by combined O-18/O-16 and C-13/C-12 ratio measurements in 25 micron diameter spots of the carbonate and compare them to previous work based primarily on trace-element distributions. The origin of these carbonates can be interpreted in terms of either contamination by carbonate country rock during ascent of the xenoliths in the host basalt, or more probably by hydrothermal processes after emplacement. The isotopic composition of these carbonates from a combined delta.18O(sub SMOW) and delta.13C(sub PDB) standpoint precludes a primary origin of these minerals from the mantle. Here a description is given of the analysis procedure, standardization of the carbonates, major element compositions of the carbonates measured by electron microprobe, and their correlated C and O isotope compositions as measured by ion microprobe. Since these carbonate rosettes may represent a terrestrial analogue to the carbonate "globules" found in the martian meteorite ALH84001 interpretations for the origin of the features found in the Spitsbergen may be of interest in constraining the origin of these carbonate minerals on Mars.

Geology and hydrogeology of the Caribbean islands aquifer system of the Commonwealth of Puerto Rico and the U.S. Virgin Islands

USGS Publications Warehouse

Renken, Robert A.; Ward, W. C.; Gill, I.P.; Gómez-Gómez, Fernando; Rodríguez-Martínez, Jesús; ,

2002-01-01

Poorly lithified to unconsolidated carbonate and clastic sedimentary rocks of Tertiary (Oligocene to Pliocene) and Quaternary (Pleistocene to Holocene) age compose the South Coast aquifer and the North Coast limestone aquifer system of Puerto Rico; poorly lithified to unlithified carbonate rocks of late Tertiary (early Miocene to Pliocene) age make up the Kingshill aquifer of St. Croix, U.S. Virgin Islands. The South Coast aquifer, North Coast limestone aquifer system, and Kingshill aquifer are the most areally extensive and function as the major sources of ground water in the U.S. Caribbean Islands Regional Aquifer-System Analysis (CI-RASA) study area. In Puerto Rico's South Coast ground-water province, more than 1,000 meters of clastic and carbonate rocks of Oligocene to Pliocene age infill the South Coast Tertiary Basin. The pattern of lithofacies within this basin appears to have been controlled by changes in base level that were, at times, dominated by tectonic movement (uplift and subsidence), but were also influenced by eustasy. Deposition of the 70-kilometer long and 3- to 8-kilometer wide fan-delta plain that covers much of the South Coast ground-water province occurred largely in response to glacially-induced changes in sea level and climate during the Quaternary period. Tectonic movement played a much less important role during the Quaternary. The North Coast ground-water province of Puerto Rico is underlain by homoclinal coastal plain wedge of carbonate and siliciclastic rocks that infill the North Coast Tertiary Basin and thicken to more than 1,700 meters. A thin basal siliciclastic sequence of late Oligocene age is overlain by a thick section of mostly carbonate rocks of Oligocene to middle Miocene age. Globigerinid limestone of late Miocene to Pliocene age crops out and lies in the shallow subsurface areas of northwestern Puerto Rico. Oligocene to middle Miocene age rocks tentatively can be divided into five depositional sequences and associated systems tracts; these rocks record carbonate and minor siliciclastic deposition that occurred in response to changes in relative sea level. The Cibao Formation represents the most complex of these sequences and contains a varied facies of carbonate, mixed carbonate-siliciclastic, and siliciclastic rocks that reflect differential uplift, subsidence, and transgression of the sea. Uplift, graben formation, and gradual shallowing of the sea are reflected within the bathyal-dominated sedimentary facies of the Kingshill Limestone in St. Croix, U.S. Virgin Islands. Reef-tract limestone beds of Pliocene age were subject to exposure, resubmergence, and meteoric leaching of aragonitic skeletal debris; these beds contain patchy lenses of dolomite that are restricted to a small, structurally-controlled embayment. The South Coast aquifer, the principal water-bearing unit of Puerto Rico's South Coast ground-water province, consists of boulder- to silt-size detritus formed by large and small coalescing fan deltas of Pleistocene to Holocene age. Deep well data indicates that it is possible to vertically separate and group a highly complex and irregular-bedded detrital sequence that underlies distal parts of the fan-delta plain into discrete water-bearing units if correlated with 30- to 40-meter thick, eustatically-controlled depositional cycles. Lithofacies maps show that greatest hydraulic conductivity within the fan-delta plain is generally associated with proximal fan and midfan areas. Distal and interfan areas are least permeable. Alluvial valley aquifers located in the western part of the South Coast ground-water province are important local sources of water supply and appear to contain some of the same physical and hydraulic characteristics as the South Coast aquifer. Older sedimentary rocks within the basin are poor aquifers; conglomeratic beds are well-cemented, and carbonate beds do not contain well-developed solution features, except locally where the beds are over

Autonomous Congestion Control in Delay-Tolerant Networks

NASA Technical Reports Server (NTRS)

Burleigh, Scott; Jennings, Esther; Schoolcraft, Joshua

2006-01-01

Congestion control is an important feature that directly affects network performance. Network congestion may cause loss of data or long delays. Although this problem has been studied extensively in the Internet, the solutions for Internet congestion control do not apply readily to challenged network environments such as Delay Tolerant Networks (DTN) where end-to-end connectivity may not exist continuously and latency can be high. In DTN, end-to-end rate control is not feasible. This calls for congestion control mechanisms where the decisions can be made autonomously with local information only. We use an economic pricing model and propose a rule-based congestion control mechanism where each router can autonomously decide on whether to accept a bundle (data) based on local information such as available storage and the value and risk of accepting the bundle (derived from historical statistics). Preliminary experimental results show that this congestion control mechanism can protect routers from resource depletion without loss of data.

A research of the community’s opening to the outside world

NASA Astrophysics Data System (ADS)

Xu, Lan; Liu, Xiangzhuo

2017-03-01

Closed residential areas, called community, the traffic network and result in various degrees of traffic congestion such as amputating, dead ends and T-shaped roads. In order to reveal the mechanism of the congestion, establish an effective evaluation index system and finally provide theoretical basis for the study of traffic congestion, we have done researches on factors for traffic congestion and have established a scientific evaluation index system combining experiences home and abroad, based on domestic congestion status. Firstly, we analyse the traffic network as the entry point, and then establish the evaluation model of road capacity with the method of AHP index system. Secondly, we divide the condition of urban congestion into 5 levels from congestion to smoothness. Besides, with VISSIM software, simulations about traffic capacity before and after community opening are carried out. Finally, we provide forward reasonable suggestions upon the combination of models and reality.

Water-quality characteristics of quaternary unconsolidated-deposit aquifers and lower tertiary aquifers of the Bighorn Basin, Wyoming and Montana, 1999-2001

USGS Publications Warehouse

Bartos, Timothy T.; Eddy-Miller, Cheryl A.; Norris, Jody R.; Gamper, Merry E.; Hallberg, Laura L.

2004-01-01

As part of the Yellowstone River Basin National Water Quality Assessment study, ground-water samples were collected from Quaternary unconsolidated-deposit and lower Tertiary aquifers in the Bighorn Basin of Wyoming and Montana from 1999 to 2001. Samples from 54 wells were analyzed for physical characteristics, major ions, trace elements, nutrients, dissolved organic carbon, radionuclides, pesticide compounds, and volatile organic compounds (VOCs) to evaluate current water-quality conditions in both aquifers. Water-quality samples indicated that waters generally were suitable for most uses, and that natural conditions, rather than the effects of human activities, were more likely to limit uses of the waters. Waters in both types of aquifers generally were highly mineralized, and total dissolved-solids concentrations frequently exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 milligrams per liter (mg/L). Because of generally high mineralization, waters from nearly one-half of the samples from Quaternary aquifers and more than one-half of the samples from lower Tertiary aquifers were not classified as fresh (dissolved-solids concentration were not less than 1,000 mg/L). The anions sulfate, fluoride, and chloride were measured in some ground-water samples at concentrations greater than SMCLs. Most waters from the Quaternary aquifers were classified as very hard (hardness greater than 180 mg/L), but hardness varied much more in waters from the lower Tertiary aquifers and ranged from soft (less than 60 mg/L) to very hard (greater than 180 mg/L). Major-ion chemistry varied with dissolved-solids concentrations. In both types of aquifers, the predominant anion changes from bicarbonate to sulfate with increasing dissolved-solids concentrations. Samples from Quaternary aquifers with fresh waters generally were calcium-bicarbonate, calcium-sodium-bicarbonate, and calcium-sodium-sulfate-bicarbonate type waters, whereas samples with larger concentrations generally were calcium-sodium-sulfate, calcium-sulfate, or sodium-sulfate-type waters. In the lower Tertiary aquifers, samples with fresh waters generally were sodium-bicarbonate or sodium-bicarbonate-sulfate type waters, whereas samples with larger concentrations were sodium-sulfate or calcium-sodium-sulfate types. Concentrations of most trace elements in both types of aquifers generally were small and most were less than applicable USEPA standards. The trace elements that most often did not meet USEPA secondary drinking-water standards were iron and manganese. In fact, the SMCL for manganese was the most frequently exceeded standard; 68 percent of the samples from the Quaternary aquifers and 31 percent of the samples from the lower Tertiary aquifers exceeded the manganese standard. Geochemical conditions may control manganese in both aquifers as concentrations in Quaternary aquifers were negatively correlated with dissolved oxygen concentrations and concentrations in lower Tertiary aquifers decreased with increasing pH. Elevated nitrate concentrations, in addition to detection of pesticides and VOCs in both aquifers, indicated some effects of human activities on ground-water quality. Nitrate concentrations in 36 percent of the wells in Quaternary aquifers and 28 percent of the wells in lower Tertiary aquifers were greater than 1 mg/L, which may indicate ground-water contamination from human sources. The USEPA drinking-water Maximum Contaminant Level (MCL) for nitrate, 10 mg/L, was exceeded in 8 percent of samples collected from Quaternary aquifers and 3 percent from lower Tertiary aquifers. Nitrate concentrations in Quaternary aquifers were positively correlated with the percentage of cropland and other agricultural land (non-cropland), and negatively correlated with rangeland and riparian land. In the lower Tertiary aquifers, nitrate concentrations only were correlated with the percentage of cropland. Concentratio

Pulmonary edema

MedlinePlus

... congestion; Lung water; Pulmonary congestion; Heart failure - pulmonary edema ... Pulmonary edema is often caused by congestive heart failure . When the heart is not able to pump efficiently, blood ...

A resilience-oriented approach for quantitatively assessing recurrent spatial-temporal congestion on urban roads.

PubMed

Tang, Junqing; Heinimann, Hans Rudolf

2018-01-01

Traffic congestion brings not only delay and inconvenience, but other associated national concerns, such as greenhouse gases, air pollutants, road safety issues and risks. Identification, measurement, tracking, and control of urban recurrent congestion are vital for building a livable and smart community. A considerable amount of works has made contributions to tackle the problem. Several methods, such as time-based approaches and level of service, can be effective for characterizing congestion on urban streets. However, studies with systemic perspectives have been minor in congestion quantification. Resilience, on the other hand, is an emerging concept that focuses on comprehensive systemic performance and characterizes the ability of a system to cope with disturbance and to recover its functionality. In this paper, we symbolized recurrent congestion as internal disturbance and proposed a modified metric inspired by the well-applied "R4" resilience-triangle framework. We constructed the metric with generic dimensions from both resilience engineering and transport science to quantify recurrent congestion based on spatial-temporal traffic patterns and made the comparison with other two approaches in freeway and signal-controlled arterial cases. Results showed that the metric can effectively capture congestion patterns in the study area and provides a quantitative benchmark for comparison. Also, it suggested not only a good comparative performance in measuring strength of proposed metric, but also its capability of considering the discharging process in congestion. The sensitivity tests showed that proposed metric possesses robustness against parameter perturbation in Robustness Range (RR), but the number of identified congestion patterns can be influenced by the existence of ϵ. In addition, the Elasticity Threshold (ET) and the spatial dimension of cell-based platform differ the congestion results significantly on both the detected number and intensity. By tackling this conventional problem with emerging concept, our metric provides a systemic alternative approach and enriches the toolbox for congestion assessment. Future work will be conducted on a larger scale with multiplex scenarios in various traffic conditions.

Analysis of random drop for gateway congestion control. M.S. Thesis

NASA Technical Reports Server (NTRS)

Hashem, Emam Salaheddin

1989-01-01

Lately, the growing demand on the Internet has prompted the need for more effective congestion control policies. Currently No Gateway Policy is used to relieve and signal congestion, which leads to unfair service to the individual users and a degradation of overall network performance. Network simulation was used to illustrate the character of Internet congestion and its causes. A newly proposed gateway congestion control policy, called Random Drop, was considered as a promising solution to the pressing problem. Random Drop relieves resource congestion upon buffer overflow by choosing a random packet from the service queue to be dropped. The random choice should result in a drop distribution proportional to the bandwidth distribution among all contending TCP connections, thus applying the necessary fairness. Nonetheless, the simulation experiments demonstrate several shortcomings with this policy. Because Random Drop is a congestion control policy, which is not applied until congestion has already occurred, it usually results in a high drop rate that hurts too many connections including well-behaved ones. Even though the number of packets dropped is different from one connection to another depending on the buffer utilization upon overflow, the TCP recovery overhead is high enough to neutralize these differences, causing unfair congestion penalties. Besides, the drop distribution itself is an inaccurate representation of the average bandwidth distribution, missing much important information about the bandwidth utilization between buffer overflow events. A modification of Random Drop to do congestion avoidance by applying the policy early was also proposed. Early Random Drop has the advantage of avoiding the high drop rate of buffer overflow. The early application of the policy removes the pressure of congestion relief and allows more accurate signaling of congestion. To be used effectively, algorithms for the dynamic adjustment of the parameters of Early Random Drop to suite the current network load must still be developed.

Late Quaternary palaeoenvironmental reconstruction of sediment drift accumulation in the Malta Graben (central Mediterranean Sea)

NASA Astrophysics Data System (ADS)

Ferraro, Serena; Sulli, Attilio; Di Stefano, Enrico; Giaramita, Luigi; Incarbona, Alessandro; Graham Mortyn, P.; Sprovieri, Mario; Sprovieri, Rodolfo; Tonielli, Renato; Vallefuoco, Mattia; Zizzo, Elisabetta; Tranchida, Giorgio

2018-06-01

The Malta Graben is a deep tectonic depression in the Sicily Channel, bounded by NW-SE normal faults and filled by thick Pliocene-Quaternary deposits. A previous analysis of a giant piston core (LC09) from the Malta Graben had revealed a wide range of sedimentary features (carbonate turbidites, bioturbated mud and scours), although the chronostratigraphic constraint of the stacking pattern has remained elusive. After establishing a reliable chronological framework based on seven radiocarbon dates for a shorter core from the Malta Graben (ANSIC03-735), a down-core analysis of planktonic foraminifer and coccolith abundance, stable isotopes and sediment grain size was carried out. Since the last glacial maximum, palaeoenvironmental conditions (surface fertility and deep chlorophyll maximum during the last glacial and the Younger Dryas; warm and oligotrophic water masses, with a deep nutricline and intense winter mixing during the Holocene) as well as selected calcareous plankton taxa trends and peaks seem to be similar to those reported for other central and western Mediterranean sites, possibly in spite of a unique response of these areas to late Quaternary climatic fluctuations. Four distinct layers, each tens of centimetres thick, are barren of foraminifers but not of coccoliths. Morphobathymetric data as well as new high-resolution and high-penetration seismic profiles show that prolonged contouritic activity has persisted on the western side of the Malta Graben. It is thus likely that layers barren of foraminifers are due to the overflow of fine-grained (clayey) material beyond drift channel dikes.

Late Quaternary palaeoenvironmental reconstruction of sediment drift accumulation in the Malta Graben (central Mediterranean Sea)

NASA Astrophysics Data System (ADS)

Ferraro, Serena; Sulli, Attilio; Di Stefano, Enrico; Giaramita, Luigi; Incarbona, Alessandro; Graham Mortyn, P.; Sprovieri, Mario; Sprovieri, Rodolfo; Tonielli, Renato; Vallefuoco, Mattia; Zizzo, Elisabetta; Tranchida, Giorgio

2018-03-01

The Malta Graben is a deep tectonic depression in the Sicily Channel, bounded by NW-SE normal faults and filled by thick Pliocene-Quaternary deposits. A previous analysis of a giant piston core (LC09) from the Malta Graben had revealed a wide range of sedimentary features (carbonate turbidites, bioturbated mud and scours), although the chronostratigraphic constraint of the stacking pattern has remained elusive. After establishing a reliable chronological framework based on seven radiocarbon dates for a shorter core from the Malta Graben (ANSIC03-735), a down-core analysis of planktonic foraminifer and coccolith abundance, stable isotopes and sediment grain size was carried out. Since the last glacial maximum, palaeoenvironmental conditions (surface fertility and deep chlorophyll maximum during the last glacial and the Younger Dryas; warm and oligotrophic water masses, with a deep nutricline and intense winter mixing during the Holocene) as well as selected calcareous plankton taxa trends and peaks seem to be similar to those reported for other central and western Mediterranean sites, possibly in spite of a unique response of these areas to late Quaternary climatic fluctuations. Four distinct layers, each tens of centimetres thick, are barren of foraminifers but not of coccoliths. Morphobathymetric data as well as new high-resolution and high-penetration seismic profiles show that prolonged contouritic activity has persisted on the western side of the Malta Graben. It is thus likely that layers barren of foraminifers are due to the overflow of fine-grained (clayey) material beyond drift channel dikes.

Making the Traffic Operations Case for Congestion Pricing: Operational Impacts of Congestion Pricing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chin, Shih-Miao; Hu, Patricia S; Davidson, Diane

2011-02-01

Congestion begins when an excess of vehicles on a segment of roadway at a given time, resulting in speeds that are significantly slower than normal or 'free flow' speeds. Congestion often means stop-and-go traffic. The transition occurs when vehicle density (the number of vehicles per mile in a lane) exceeds a critical level. Once traffic enters a state of congestion, recovery or time to return to a free-flow state is lengthy; and during the recovery process, delay continues to accumulate. The breakdown in speed and flow greatly impedes the efficient operation of the freeway system, resulting in economic, mobility, environmentalmore » and safety problems. Freeways are designed to function as access-controlled highways characterized by uninterrupted traffic flow so references to freeway performance relate primarily to the quality of traffic flow or traffic conditions as experienced by users of the freeway. The maximum flow or capacity of a freeway segment is reached while traffic is moving freely. As a result, freeways are most productive when they carry capacity flows at 60 mph, whereas lower speeds impose freeway delay, resulting in bottlenecks. Bottlenecks may be caused by physical disruptions, such as a reduced number of lanes, a change in grade, or an on-ramp with a short merge lane. This type of bottleneck occurs on a predictable or 'recurrent' basis at the same time of day and same day of week. Recurrent congestion totals 45% of congestion and is primarily from bottlenecks (40%) as well as inadequate signal timing (5%). Nonrecurring bottlenecks result from crashes, work zone disruptions, adverse weather conditions, and special events that create surges in demand and that account for over 55% of experienced congestion. Figure 1.1 shows that nonrecurring congestion is composed of traffic incidents (25%), severe weather (15%), work zones, (10%), and special events (5%). Between 1995 and 2005, the average percentage change in increased peak traveler delay, based on hours spent in traffic in a year, grew by 22% as the national average of hours spent in delay grew from 36 hours to 44 hours. Peak delay per traveler grew one-third in medium-size urban areas over the 10 year period. The traffic engineering community has developed an arsenal of integrated tools to mitigate the impacts of congestion on freeway throughput and performance, including pricing of capacity to manage demand for travel. Congestion pricing is a strategy which dynamically matches demand with available capacity. A congestion price is a user fee equal to the added cost imposed on other travelers as a result of the last traveler's entry into the highway network. The concept is based on the idea that motorists should pay for the additional congestion they create when entering a congested road. The concept calls for fees to vary according to the level of congestion with the price mechanism applied to make travelers more fully aware of the congestion externality they impose on other travelers and the system itself. The operational rationales for the institution of pricing strategies are to improve the efficiency of operations in a corridor and/or to better manage congestion. To this end, the objectives of this project were to: (1) Better understand and quantify the impacts of congestion pricing strategies on traffic operations through the study of actual projects, and (2) Better understand and quantify the impacts of congestion pricing strategies on traffic operations through the use of modeling and other analytical methods. Specifically, the project was to identify credible analytical procedures that FHWA can use to quantify the impacts of various congestion pricing strategies on traffic flow (throughput) and congestion.« less

Biocompatibility of Ricinus communis polymer with addition of calcium carbonate compared to titanium. Experimental study in guinea pigs

PubMed Central

Graça, Yorgos Luiz Santos De Salles; Opolski, Ana Cristina; Barboza, Barbara Evelin Gonçalves; Erbano, Bruna Olandoski; Mazzaro, Caroline Cantalejo; Klostermann, Flávia Caroline; Sucharski, Enéas Eduardo; Kubrusly, Luiz Fernando

2014-01-01

Objective The aim of the present investigation was to determine whether the difference in inflammatory tissue reaction between the Riccinus communis (castor) polymer with calcium carbonate and the titanium implant is statistically significant. Methods Thirty-two Cavia porcellus were allocated into four groups of eight animals each. We implanted the two types of materials in the retroperitoneal space of all the animals. They were euthanized at 7, 20, 30 and 40 days after surgery, and an histological study of the samples was conducted. Results All implants showed characteristics of chronic inflammation regardless of the material and timepoint of evaluation. There was no statistically significant difference between Pm+CaCO3 and Ti with regard to the presence of granulation tissue, tissue congestion, histiocytes, lymphocytes, neutrophils, giant cells, and fibrosis (P> 0.05). Conclusion The castor oil polymer plus calcium carbonate implant was not statistically different from the titanium implant regarding inflammatory tissue reaction. PMID:25140479

Late quaternary history and uranium isotopic compositions of ground water discharge deposits, Crater Flat, Nevada

USGS Publications Warehouse

Paces, James B.; Taylor, Emily M.; Bush, Charles

1993-01-01

Three carbonate-rich spring deposits are present near the southern end of Crater Flat, NV, approximately 18 km southwest of the potential high-level waste repository at Yucca Mountain. We have analyzed five samples of carbonate-rich material from two of the deposits for U and Th isotopic compositions. Resulting U-series disequilibrium ages indicate that springs were active at 18 ?? 1, 30 ?? 3, 45 ?? 4 and >70 ka. These ages are consistent with a crude internal stratigraphy at one site. Identical ages for two samples at two separate sites suggest that springs were contemporaneous, at least in part, and were most likely part of the same hydrodynamic system. In addition, initial U isotopic compositions range from 2.8 to 3.8 and strongly suggest that ground water from the regional Tertiary-volcanic aquifer provided the source for these hydrogenic deposits. This interpretation, along with water level data from near-by wells suggest that the water table rose approximately 80 to 115 m above present levels during the late Quaternary and may have fluctuated repeatedly. Current data are insufficient to allow reconstruction of a detailed depositional history, however geochronological data are in good agreement with other paleoclimatic proxy records preserved throughout the region. Since these deposits are down gradient from the potential repository site, the possibility of higher ground water levels in the future dramatically shortens both vertical and lateral ground water pathways and reduces travel times of transported radionuclides to potential discharge sites.

Permafrost soils and carbon cycling

DOE PAGES

Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; ...

2015-02-05

Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore » this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

Middle to Late Pleistocene coastal deposits of Eivissa (Western Mediterranean): Chronology and evolution.

NASA Astrophysics Data System (ADS)

Del Valle, Laura; Pomar, Francisco; Fornós, Joan J.; Gómez-Pujol, Lluís; Anechitei-Deacu, Valentina; Timar-Gabor, Alida

2016-04-01

This study deals with the sedimentary and stratigraphical description of Pleistocene deposits from seven coastal areas of Eivissa (Balearic Islands). Twenty two sedimentary facies have been described involving the succession of eolian, colluvial and edaphic environments. Carbonate sandstones, breccias and silty deposits are the main component of these sequences. Despite the extensive eolian systems outcropping along the coast of Eivissa, there are very few studies performed to chronological framework of these deposits. Luminescence measurements were carried out using an automated RisØ TL/OSL-DA-20 reader in the Luminescence Dating Laboratory of Babes-Bolyai University (Cluj-Napoca, Romania) under low intensity red light. OSL dating of nineteen eolian levels indicate that their deposition took place between the Middle and Late Pleistocene, establishing a paleoclimatic evolution of Eivissa Island since 755 ka to 70 Ka. Eolian activity in the Eivissa Island can be correlated with regression episodes which took place during cold periods associated with different isotopic stages, concretely the MIS 18, 16, 12, 10, 8, 6 and 4. Similar results have been obtained from many sites along the western Mediterranean Sea such as Mallorca (Pomar i Cuerda, 1979; Nielsen et al, 2004; Fornós et al, 2009), Sardinia (Andreucci et al, 2009; Pascucci et al, 2014), Liguria (Pappalardo et al., 2013). Keywords: Eolian dunes, Pleistocene, Climatic evolution, Eivissa. References - Andreucci, S.; Pascucci, V.; Murray, A. S.; Clemmensen, L. B. 2009. Late Pleistocene coastal evolution of San Giovanni di Sinis, west Sardinia (Western Mediterranean). Sedimentary Geology, 216: 104- 116 - Fornós, J.J.; Clemmensen, L.B.; Gómez-Pujol, L.; Murray, A. 2009. Late Pleistocene carbonate aeolianites on Mallorca, Western Mediterranean: a luminescence chronology. Quaternary Science reviews 28: 2697-2709. -Nielsen, K.A.; Clemmensen, L.B.; Fornós, J.J. 2004. Middle Pleistocene magnetostratigraphy and susceptibility stratigraphy: data from a carbonate aeolian system, Mallorca, Western Mediterranean. Quaternary Science Reviews, 23: 1733-1756 -Pappalardo, M.; Chelli, A.; Ciampalini, A.; Rellini, I.; Biagioni, F.; Brückner, H.; Fülling, A.; Firpo, M. 2013. Evolution of an Upper Pleistocene aeolianite in the northern Mediterranean (Liguria, NW Italy). Ital. j. Geosci. Vol. 132, 2: 290-303 -Pascucci, V.; Sechi, D.; Andreucci, S. 2014. Middle Pleistocene to Holocene coastal evolution of NW Sardinia (Mediterranean Sea, Italy). Quaternary International, 328-329: 3-20 -Pomar, L.; Cuerda, J. 1979. Los depósitos marinos pleistocénicos en Mallorca Acta Geológica Hispánica. Homenatge a Lluís Soler i Sarabaris. Vol. 14: 505-513

A model of late quaternary landscape development in the Delaware Valley, New Jersey and Pennsylvania

USGS Publications Warehouse

Ridge, J.C.; Evenson, E.B.; Sevon, W.D.

1992-01-01

In the Delaware Valley of New Jersey and eastern Pennsylvania the late Quaternary history of colluviation, fluvial adjustment, and soil formation is based on the ages of pre-Wisconsinan soils and glacial deposits which are indicated by feld relationships and inferred from mid-latitude climate changes indicated by marine oxygen-isotope records. The area is divided into four terranes characterized by sandstone, gneiss, slate and carbonate rocks. Since the last pre-Wisconsinan glaciation (> 130 ka, inferred to be late Illinoian), each terrane responded differently to chemical and mechanical weathering. During the Sangamon interglacial stage (??? 130-75 ka) in situ weathering is inferred to have occurred at rates greater than transportation of material which resulted in the formation of deep, highly weathered soil and saprolite, and dissolution of carbonate rocks. Cold climatic conditions during the Wisconsinan, on the other hand, induced erosion of the landscape at rates faster than soil development. Upland erosion during the Wisconsinan removed pre-Wisconsinan soil and glacial sediment and bedrock to produce muddy to blocky colluvium, gre??zes lite??es, and alluvial fans on footslopes. Fluvial gravel and overlying colluvium in the Delaware Valley, both buried by late Wisconsinan outwash, are inferred to represent episodes of early and middle Wisconsinan (??? 75-25 ka) upland erosion and river aggradiation followed by river degradation and colluvium deposition. Early-middle Wisconsinan colluvium is more voluminous than later colluvium despite colder, possibly permafrost conditions during the late Wisconsinan ??? 25-10 ka). Extensive colluviation during the early and middle Wisconsinan resulted from a longer (50 kyr), generally cold interval of erosion with a greater availability of easily eroded pre-Wisconsinan surficial materials on uplands than during the late Wisconsinan. After recession of late Wisconsinan ice from its terminal position, soil formation and landscape stability were delayed until the Holocene by a lingering cold climate, slope erosion, colluvium and alluvial fan deposition, and eolian sedimentation. Late Quaternary erosion in the Delaware Valley was dominated by glacial and periglacial processes during glacial stages. During the warm interglacial stages, soils developed on a more stable landscape. These souls were easily colluviated by periglacial erosion during periods of intermittent cold climate. ?? 1992.

Radiocarbon dating late Quaternary loess deposits using small terrestrial gastropod shells

USGS Publications Warehouse

Pigati, Jeff S.; McGeehin, John P.; Muhs, Daniel R.; Bettis, E. Arthur

2013-01-01

Constraining the ages and mass accumulation rates of late Quaternary loess deposits is often difficult because of the paucity of organic material typically available for 14C dating and the inherent limitations of luminescence techniques. Radiocarbon dating of small terrestrial gastropod shells may provide an alternative to these methods as fossil shells are common in loess and contain ∼12% carbon by weight. Terrestrial gastropod assemblages in loess have been used extensively to reconstruct past environmental conditions but have been largely ignored for dating purposes. Here, we present the results of a multi-faceted approach to understanding the potential for using small terrestrial gastropod shells to date loess deposits in North America. First, we compare highly resolved 14C ages of well-preserved wood and gastropod shells (Succineidae) recovered from a Holocene loess section in Alaska. Radiocarbon ages derived from the shells are nearly identical to wood and plant macrofossil ages throughout the section, which suggests that the shells behaved as closed systems with respect to carbon for at least the last 10 ka (thousands of calibrated 14C years before present). Second, we apply 14C dating of gastropod shells to late Pleistocene loess deposits in the Great Plains using stratigraphy and independent chronologies for comparison. The new shell ages require less interpretation than humic acid radiocarbon ages that are commonly used in loess studies, provide additional stratigraphic coverage to previous dating efforts, and are in correct stratigraphic order more often than their luminescence counterparts. Third, we show that Succineidae shells recovered from historic loess in the Matanuska River Valley, Alaska captured the 20th century 14C bomb spike, which suggests that the shells can be used to date late Holocene and historic-aged loess. Finally, results from Nebraska and western Iowa suggest that, similar to other materials, shell ages approaching ∼40 ka should be viewed with caution as they may reflect trace amounts of contamination. In sum, our results show that small terrestrial gastropod shells, especially from the Succineidae family, provide reliable ages for late Quaternary loess deposits in North America.

Rate of change of heart size before congestive heart failure in dogs with mitral regurgitation.

PubMed

Lord, P; Hansson, K; Kvart, C; Häggström, J

2010-04-01

The objective of the study was to examine the changes in vertebral heart scale, and left atrial and ventricular dimensions before and at onset of congestive heart failure in cavalier King Charles spaniels with mitral regurgitation. Records and radiographs from 24 cavalier King Charles spaniels with mitral regurgitation were used. Vertebral heart scale (24 dogs), and left atrial dimension and left ventricular end diastolic and end systolic diameters (18 dogs) and their rate of increase were measured at intervals over years to the onset of congestive heart failure. They were plotted against time to onset of congestive heart failure. Dimensions and rates of change of all parameters were highest at onset of congestive heart failure, the difference between observed and chance outcome being highly significant using a two-tailed chi-square test (P<0.001). The left heart chambers increase in size rapidly only in the last year before the onset of congestive heart failure. Increasing left ventricular end systolic dimension is suggestive of myocardial failure before the onset of congestive heart failure. Rate of increase of heart dimensions may be a useful indicator of impending congestive heart failure.

Studies of quaternary saline lakes-I. Hydrogen isotope fractionation in saline minerals

USGS Publications Warehouse

Matsuo, S.; Friedman, I.; Smith, G.I.

1972-01-01

Borax, gaylussite, nahcolite and trona were synthesized in aqueous solution at temperatures ranging from 8?? to 35??C. Except for borax, deuterium was always depleted in these hydrated minerals relative to the solutions from which they were crystallized. In borax, no significant fractionation was found. The fractionation factor of D H for the trona-water system exhibited a marked temperature dependence. By combining the deuterium contents of trona and the solution from which trona was crystallized, the following thermometer scale was obtained: In ( D H) trona ( D H)water = 1.420 ?? 104 T2 + 23.56 T (1). An attempt to establish a geothermometer based on C13 C12 fractionation between carbonate minerals and carbonate ions in aqueous solution was not successful. ?? 1972.

Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qu, Jun; Luo, Huimin

An ionic liquid composition having the following generic structural formula: ##STR00001## wherein R 1, R 2, R 3, and R 4 are equivalent and selected from hydrocarbon groups containing at least three carbon atoms, and X - is a phosphorus-containing anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base oil, wherein the ionic liquid is dissolved in the base oil. Further described are methods for applying the ionic liquid or lubricant composition onto amore » mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.« less

Characterisation of the Permafrost Carbon Pool

USGS Publications Warehouse

Kuhry, P.; Grosse, G.; Harden, J.W.; Hugelius, G.; Koven, C.D.; Ping, C.-L.; Schirrmeister, L.; Tarnocai, C.

2013-01-01

The current estimate of the soil organic carbon (SOC) pool in the northern permafrost region of 1672 Petagrams (Pg) C is much larger than previously reported and needs to be incorporated in global soil carbon (C) inventories. The Northern Circumpolar Soil Carbon Database (NCSCD), extended to include the range 0–300 cm, is now available online for wider use by the scientific community. An important future aim is to provide quantitative uncertainty ranges for C pool estimates. Recent studies have greatly improved understanding of the regional patterns, landscape distribution and vertical (soil horizon) partitioning of the permafrost C pool in the upper 3 m of soils. However, the deeper C pools in unconsolidated Quaternary deposits need to be better constrained. A general lability classification of the permafrost C pool should be developed to address potential C release upon thaw. The permafrost C pool and its dynamics are beginning to be incorporated into Earth System models, although key periglacial processes such as thermokarst still need to be properly represented to obtain a better quantification of the full permafrost C feedback on global climate change.

A novel route to recognizing quaternary ammonium cations using electrospray mass spectrometry.

PubMed

Shackman, Holly M; Ding, Wei; Bolgar, Mark S

2015-01-01

Characterizing and elucidating structures is a commonplace and necessary activity in the pharmaceutical industry with mass spectrometry and NMR being the primary tools for analysis. Although many functional groups are readily identifiable, quaternary ammonium cations have proven to be difficult to unequivocally identify using these techniques. Due to the lack of an N-H bond, quaternary ammonium groups can only be detected in the (1)H NMR spectra by weak signals generated from long-range (14)N-H coupling, which by themselves are inconclusive evidence of a quaternary ammonium functional group. Due to their low intensity, these signals are frequently not detected. Additionally, ions cannot be differentiated in a mass spectrum as an M(+) or [M + H](+) ion without prior knowledge of the compound's structure. In order to utilize mass spectrometry as a tool for determining this functionality, ion cluster formation of quaternary ammonium cations and non-quaternary amines was studied using electrospray ionization. Several mobile phase modifiers were compared; however, the addition of small amounts of trifluoroacetic acid proved superior in producing characteristic and intense [M +2TFA](-) clusters for compounds containing quaternary ammonium cations when using negative electrospray. By fragmenting this characteristic ion using CID, nearly all compounds studied could be unambiguously identified as containing a quaternary ammonium cation or a non-quaternary amine attributable to the presence (non-quaternary amine) or absence (quaternary ammonium cation) of the resulting [2TFA + H](-) ion in the product spectra. This method of analysis provides a rapid, novel, and reliable technique for indicating the presence of quaternary ammonium cations in order to aid in structural elucidation.

Phosphorous and nitrogen dual heteroatom doped mesoporous carbon synthesized via microwave method for supercapacitor application

NASA Astrophysics Data System (ADS)

Nasini, Udaya B.; Bairi, Venu Gopal; Ramasahayam, Sunil Kumar; Bourdo, Shawn E.; Viswanathan, Tito; Shaikh, Ali U.

2014-03-01

Phosphorus (P) and nitrogen (N) dual heteroatom doped mesoporous carbon (PNDC) synthesized by microwave assisted carbonization of tannin cross-linked to melamine in the presence of polyphosphoric acid was evaluated electrochemically for supercapacitor application. Controlling the N content by varying the amount of tannin to melamine in the carbonization process produced varying nitrogen, phosphorus and oxygen functionalities along with different physical properties. Electrochemical characterization studies revealed that N content is responsible for pseudocapacitance and high surface area plays a vital role in improving the capacitative behavior by enhanced electric double layer formation. In 1.0 M H2SO4 and 6.0 M KOH, PNDC-2 showed a high specific capacitance of 271 F g-1 and 236 F g-1, respectively. XPS results demonstrate the presence of pyridinic-N, quaternary-N as well as quinone type oxygen functionalities, which accounts for redox reactions and likely play an important role in the transportation of electrons during the charge/discharge process. Thus, the microwave assisted synthesis of doped carbon can provide a novel method of synthesizing materials useful for the fabrication of cheap and high performance supercapacitors.

Intelligent traffic lights based on MATLAB

NASA Astrophysics Data System (ADS)

Nie, Ying

2018-04-01

In this paper, I describes the traffic lights system and it has some. Through analysis, I used MATLAB technology, transformed the camera photographs into digital signals. Than divided the road vehicle is into three methods: very congestion, congestion, a little congestion. Through the MCU programming, solved the different roads have different delay time, and Used this method, saving time and resources, so as to reduce road congestion.

Effect of ten quaternary ammonium cations on tetrachloromethane sorption to clay from water

USGS Publications Warehouse

Smith, J.A.

1990-01-01

The mineral surface of Wyoming bentonite (clay) was modified by replacing inorganic ions by each of 10 quaternary ammonium compounds, and tetrachloromethane sorption to the modified sorbents from water was studied. Tetrachloromethane sorption from solution to clay modified with tetramethyl-, tetraethyl-, benzyltrimethyl-, or benzyltriethylammonium cations generally is characterized by relatively high solute uptake, isotherm nonlinearity, and competitive sorption (with trichloroethene as the competing sorbate). For these sorbents, the ethyl functional groups yield reduced sorptive capacity relative to methyl groups, whereas the benzyl group appears to have a similar effect on sorbent capacity as the methyl group. Sorption of tetrachloromethane to clay modified with dodecyldimethyl(2-phenoxyethyl)-, dodecyltrimethyl-, tetradecyltrimethyl-, hexadecyltrimethyl-, or benzyldimethylhexadecylammonium bromide is characterized by relatively low solute uptake, isotherm linearity, and noncompetitive sorption. For these sorbents, an increase in the size of the nonpolar functional group(s) causes an increase in the organic carbon normalized sorption coefficient (Koc). No measurable uptake of tetrachloromethane sorption by the unmodified clay or clay modified by ammonium bromide was observed. ?? 1990 American Chemical Society.

Simulation of Glacial Cycles Before and After the Mid-Pleistocene Transition

NASA Astrophysics Data System (ADS)

Ganopolski, A.; Willeit, M.; Calov, R.

2017-12-01

In spite of significant progress achieved in understanding of glacial cycles, the cause of Mid-Pleistocene transition (MPT) is still not fully understood. To study possible mechanisms of the MPT we used the Earth system model of intermediate complexity CLIMBER-2 which incorporates all major components of the Earth system - atmosphere, ocean, land surface, northern hemisphere ice sheets, terrestrial biota and soil carbon, aeolian dust and marine biogeochemistry. We run the model through the entire Quaternary. The only prescribed forcing in these simulations is variations in Earth orbital parameters. In addition we prescribed gradually evolving in time terrestrial sediment cover and global volcanic outgassing. We found that gradual removal of terrestrial sediment from the Northern Hemisphere continent by glacial processes is sufficient to explain transition from 40-ka to 100-ka worlds around 1 million years ago. By starting the model at different times and using the same initial conditions we found that modeling results converge to the same solution which depends only on the orbital forcing and lower boundary conditions. Our results thus strongly suggest that Quaternary glacial cycles are externally forced and nearly deterministic.

A Cation-containing Polymer Anion Exchange Membrane based on Poly(norbornene)

NASA Astrophysics Data System (ADS)

Beyer, Frederick; Price, Samuel; Ren, Xiaoming; Savage, Alice

Cation-containing polymers are being studied widely for use as anion exchange membranes (AEMs) in alkaline fuel cells (AFCs) because AEMs offer a number of potential benefits including allowing a solid state device and elimination of the carbonate poisoning problem. The successful AEM will combine high performance from several orthogonal properties, having robust mechanical strength even when wet, high hydroxide conductivity, and the high chemical stability required for long device lifetimes. In this study, we have synthesized a model cationic polymer that combines three of the key advantages of Nafion. The polymer backbone based on semicrystalline atactic poly(norbornene) offers good mechanical properties. A flexible, ether-based tether between the backbone and fixed cation charged species (quaternary ammonium) should provide the low-Tg, hydrophilic environment required to facilitate OH- transport. Finally, methyl groups have been added at the beta position relative to the quaternary ammonium cation to prevent Hoffman elimination, one mechanism by which AEMs are neutralized in a high pH environment. In this poster, we will present our findings on mechanical properties, morphology, charge transport, and chemical stability of this material.

Paleoenvironmental dynamics of Western Beringia - New studies from the Yedoma key site Duvanny Yar (Lower Kolyma River, Siberia)

NASA Astrophysics Data System (ADS)

Strauss, Jens; Schirrmeister, Lutz; Wetterich, Sebastian

2010-05-01

Duvanny Yar is a stratigraphic key site for the late Quaternary in Western Beringia. It is characteristic for ice-rich permafrost sequences of the so-called Yedoma Suite in north-east Siberia (e.g. KAPLINA et al. 1978; SHER et al. 1979) and is an important reference site for the late Pleistocene history of Beringia (HOPKINS 1982). The aim of our study was to reconstruct the paleoenvironmental dynamics at the Duvanny Yar site during the late Quaternary using its terrestrial archive. A multidisciplinary approach using geocryological, geochronological, sedimentological, hydrochemical, isotope geochemical, and paleoecological methods was applied to obtain multiproxy records. Sediment samples were analysed for ice contents, grain size parameters, biogeochemistry (total carbon, total organic carbon, total nitrogen, stable carbon isotopes), mineral density, mass specific magnetic susceptibility, and for radiocarbon age. Stable isotopes of water were measured for ground ice (ice wedges, segregated ice, and pore ice), modern surface waters and modern precipitation. Six profiles along the riverbank were sampled in August 2008. They contained Eemian lacustrine deposits, long sequences of Ice Complex deposits of the Late Pleistocene Yedoma, Holocene lacustrine and boggy deposits in thermokarst depressions. All profiles showed very bad sorted sediment of fine to coarse silt. A homogenous and polymodal grain size distribution for the ice rich (~30 to 60 wt %) Yedoma Suite revealed a polygenetic origin and disproves the pure "arctic loess" hypothesis for these deposits. Measurements of bulk density, ice content and total organic carbon content (TOC) enable for a relative TOC content in Ice Complex deposits at Duvanny Yar. The mean value of organic carbon at Duvanny Yar is 16 ± 11 kg/m^3. Geochronological results based on 11 new AMS ages revealed that the Yedoma Suite was continuously formed from the end of the Middle Weichselian (~ 40000 years BP) and at least until the Late Glacial Maximum (~ 20000 years BP). Stable water isotopes measured in ice wedges, segregated ice and ice lenses were used to estimate paleotemperature changes. Isotopic signals revealed cold temperatures for the whole period with relative warm peaks in the Eemian and Holocene times. During Yedoma Suite formation the climate was stable and cold. A better understanding of the paleoenvironmental dynamics at Duvanny Yar may provide a basis for more reliable predictions of future reaction on global warming of organic-bearing ice-rich permafrost in Siberia which is considered as a potential greenhouse gas source permafrost (DUTTA et al. 2006; ZIMOV et al. 2006). References Dutta, K., Schuur, E.A.G., Neff, J.C. and Zimov, S.A. (2006). "Potential carbon release from permafrost soils of Northeastern Siberia", Global Change Biology 12(12): 2336-2351. Hopkins, D.M. (1982). Aspects of the paleogeography of Beringia during the Late Pleistocene. In: Paleoecology of Beringia. Hopkins, D. M., Matthews, J. V., Schweger, C. E. and Young, S. B., Academic Press: 3-28. Kaplina, T.N., Giterman, R.E., Lakhtina, O.V., Abrashov, B.A., Kiselyov, S.V. and Sher, A.V. (1978). "Duvannyy Yar - a key section of Upper Pleistocene deposits of the Kolyma lowland", Bulletin of Quaternary Research Commission 48: 49-65. (in Russian) Sher, A.V., Kaplina, T.N., Giterman, R.E., Lozhkin, A.V., Arkhangelov, A.A., Kiselyov, S.V., Kouznetsov, Y.V., Virina, E.I. and Zazhigin, V.S. (1979). Late Cenozoic of the Kolyma Lowland. 14th Pacific Science Congress, Khabarovsk, Academy of Science, USSR. Zimov, S.A., Davydov, S.P., Zimova, G.M., Davydova, A.I., Schuur, E.A.G., Dutta, K. and Chapin III, F.S. (2006). "Permafrost carbon: Stock and decomposability of a globally significant carbon pool", Geophysical Research Letters 33(20): L20502.

Nucleophilic addition of Grignard reagents to 3-acylindoles: stereoselective synthesis of highly substituted indoline scaffolds.

PubMed

Wang, Lu; Shao, Yushang; Liu, Yuanhong

2012-08-03

3-Acylindoles undergo nucleophilic-type reactions with Grignard reagents to efficiently afford either cis- or trans-substituted indolines, depending on the different quenching procedures. The enolate intermediate could be trapped by aryl acyl chlorides to provide indolines bearing a quaternary carbon center with high stereoselectivity. In contrast, the use of benzyl bromide as an electrophile results in the fragmentation of the indole ring. The indoline products could be easily transformed into indoles through oxidation with DDQ in a one-pot manner.

Synthetic study toward the misassigned (±)-tronoharine.

PubMed

Zhong, Xue; Li, You; Zhang, Jing; Han, Fu-She

2015-02-06

The synthesis of a pentacyclic indole compound corresponding to the core structure of the misassigned indole alkaloid, tronoharine (1), is presented. The key reactions were a formal [3 + 3] cycloaddition of an indol-2-yl carbinol with an azadiene for the construction of the 6/5/6/6 tetracyclic system containing an all-carbon quaternary center and an intramolecular substitution reaction of an amine and a triflate for the creation of the bridged azepine ring. In addition, some other interesting transformations discovered during the synthetic studies are also discussed.

One-pot Diels–Alder cycloaddition/gold(I)-catalyzed 6-endo-dig cyclization for the synthesis of the complex bicyclo[3.3.1]alkenone framework

PubMed Central

Sow, Boubacar; Bellavance, Gabriel; Barabé, Francis

2011-01-01

Summary The rapid synthesis of bicyclo[m.n.1]alkanone cores possessing quaternary carbon centers adjacent to a bridged ketone represents a significant synthetic challenge. This type of architectural feature is embedded in various complex biologically active compounds such as hyperforin and garsubellin A. Herein, we report a highly diastereoselective one-pot Diels–Alder reaction/Au(I)-catalyzed carbocyclization to generate bicyclo[3.3.1]alkanones in yields ranging from 48–93%. PMID:21915201

Forging Fluorine‐Containing Quaternary Stereocenters by a Light‐Driven Organocatalytic Aldol Desymmetrization Process

PubMed Central

Cuadros, Sara; Dell'Amico, Luca

2017-01-01

Abstract Reported herein is a light‐triggered organocatalytic strategy for the desymmetrization of achiral 2‐fluoro‐substituted cyclopentane‐1,3‐diketones. The chemistry is based on an intermolecular aldol reaction of photochemically generated hydroxy‐o‐quinodimethanes and simultaneously forges two adjacent fully substituted carbon stereocenters, with one bearing a stereogenic carbon–fluorine unit. The method uses readily available substrates, a simple chiral organocatalyst, and mild reaction conditions to afford an array of highly functionalized chiral 2‐fluoro‐3‐hydroxycyclopentanones. PMID:28746742

A Tunable and Enantioselective Hetero-Diels-Alder Reaction Provides Access to Distinct Piperidinoyl Spirooxindoles.

PubMed

Jayakumar, Samydurai; Louven, Kathrin; Strohmann, Carsten; Kumar, Kamal

2017-12-11

The active complexes of chiral N,N'-dioxide ligands with dysprosium and magnesium salts catalyze the hetero-Diels-Alder reaction between 2-aza-3-silyloxy-butadienes and alkylidene oxindoles to selectively form 3,3'- and 3,4'-piperidinoyl spirooxindoles, respectively, in very high yields and with excellent enantioselectivities. The exo-selective asymmetric cycloaddition successfully regaled the construction of sp 3 -rich and highly substituted natural-product-based spirooxindoles supporting many chiral centers, including contiguous all-carbon quaternary centers. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

A new casemix adjustment index for hospital mortality among patients with congestive heart failure.

PubMed

Polanczyk, C A; Rohde, L E; Philbin, E A; Di Salvo, T G

1998-10-01

Comparative analysis of hospital outcomes requires reliable adjustment for casemix. Although congestive heart failure is one of the most common indications for hospitalization, congestive heart failure casemix adjustment has not been widely studied. The purposes of this study were (1) to describe and validate a new congestive heart failure-specific casemix adjustment index to predict in-hospital mortality and (2) to compare its performance to the Charlson comorbidity index. Data from all 4,608 admissions to the Massachusetts General Hospital from January 1990 to July 1996 with a principal ICD-9-CM discharge diagnosis of congestive heart failure were evaluated. Massachusetts General Hospital patients were randomly divided in a derivation and a validation set. By logistic regression, odds ratios for in-hospital death were computed and weights were assigned to construct a new predictive index in the derivation set. The performance of the index was tested in an internal Massachusetts General Hospital validation set and in a non-Massachusetts General Hospital external validation set incorporating data from all 1995 New York state hospital discharges with a primary discharge diagnosis of congestive heart failure. Overall in-hospital mortality was 6.4%. Based on the new index, patients were assigned to six categories with incrementally increasing hospital mortality rates ranging from 0.5% to 31%. By logistic regression, "c" statistics of the congestive heart failure-specific index (0.83 and 0.78, derivation and validation set) were significantly superior to the Charlson index (0.66). Similar incrementally increasing hospital mortality rates were observed in the New York database with the congestive heart failure-specific index ("c" statistics 0.75). In an administrative database, this congestive heart failure-specific index may be a more adequate casemix adjustment tool to predict hospital mortality in patients hospitalized for congestive heart failure.

Quaternary and Geomorphology.

ERIC Educational Resources Information Center

Andrews, J. T.; Graf, W. L.

1983-01-01

Highlights conferences and meetings of organizations involved with quaternary geology and geomorphology, including International Union of Quaternary Research Conference held in Moscow. The impetus of a revision of "The Quaternary of the United States" resulted from this conference. Includes activities/aims of "Friends of the…

Rhode Island congestion management plan : executive summary

DOT National Transportation Integrated Search

1997-09-01

This document provides an overview of the Rhode Island Congestion Management System (CMS) program consisting of the following: Congestion Management System Plan; Incident Management Plan; and Intelligent Transportation System (ITS) Early Deployment P...

Technologies that enable congestion pricing : a primer

DOT National Transportation Integrated Search

2008-10-01

This volume explores transportation technologies that enable congestion pricing. This document considers the following: the functional processes for tolling and congestion pricing; what technologies there are to consider; how the technologies are app...

Better road congestion measures are needed

DOT National Transportation Integrated Search

2003-05-01

Road congestion is growing worse as demand : outstrips new roadway construction and other : efforts to increase traffic flows. : Better ways to measure congestion are needed to : effectively address the problem. : Actual measures of speeds an...

Income-based equity impacts of congestion pricing

DOT National Transportation Integrated Search

2008-12-01

This equity primer was produced to examine the impacts of congestion pricing on low-income groups, public opinion as expressed by various income groups, and ways to mitigate the equity impacts of congestion pricing

Income-based equity impacts of congestion pricing.

DOT National Transportation Integrated Search

2008-12-01

This equity primer was produced to examine the impacts of congestion pricing on low-income groups, public opinion as expressed by various income groups, and ways to mitigate the equity impacts of congestion pricing.

Autonomous Congestion Control in Delay-Tolerant Networks

NASA Technical Reports Server (NTRS)

Burleigh, Scott C.; Jennings, Esther H.

2005-01-01

Congestion control is an important feature that directly affects network performance. Network congestion may cause loss of data or long delays. Although this problem has been studied extensively in the Internet, the solutions for Internet congestion control do not apply readily to challenged network environments such as Delay Tolerant Networks (DTN) where end-to-end connectivity may not exist continuously and latency can be high. In DTN, end-to-end rate control is not feasible. This calls for congestion control mechanisms where the decisions can be made autonomously with local information only. We use an economic pricing model and propose a rule-based congestion control mechanism where each router can autonomously decide on whether to accept a bundle (data) based on local information such as available storage and the value and risk of accepting the bundle (derived from historical statistics).

Liver congestion in heart failure contributes to inappropriately increased serum hepcidin despite anemia.

PubMed

Ohno, Yukako; Hanawa, Haruo; Jiao, Shuang; Hayashi, Yuka; Yoshida, Kaori; Suzuki, Tomoyasu; Kashimura, Takeshi; Obata, Hiroaki; Tanaka, Komei; Watanabe, Tohru; Minamino, Tohru

2015-01-01

Hepcidin is a key regulator of mammalian iron metabolism and mainly produced by the liver. Hepcidin excess causes iron deficiency and anemia by inhibiting iron absorption from the intestine and iron release from macrophage stores. Anemia is frequently complicated with heart failure. In heart failure patients, the most frequent histologic appearance of liver is congestion. However, it remains unclear whether liver congestion associated with heart failure influences hepcidin production, thereby contributing to anemia and functional iron deficiency. In this study, we investigated this relationship in clinical and basic studies. In clinical studies of consecutive heart failure patients (n = 320), anemia was a common comorbidity (41%). In heart failure patients without active infection and ongoing cancer (n = 30), log-serum hepcidin concentration of patients with liver congestion was higher than those without liver congestion (p = 0.0316). Moreover, in heart failure patients with liver congestion (n = 19), the anemia was associated with the higher serum hepcidin concentrations, which is a type of anemia characterized by induction of hepcidin. Subsequently, we produced a rat model of heart failure with liver congestion by injecting monocrotaline that causes pulmonary hypertension. The monocrotaline-treated rats displayed liver congestion with increase of hepcidin expression at 4 weeks after monocrotaline injection, followed by anemia and functional iron deficiency observed at 5 weeks. We conclude that liver congestion induces hepcidin production, which may result in anemia and functional iron deficiency in some patients with heart failure.

Pedo-sedimentary constituents as paleoenvironmental proxies in the Sudano-Sahelian belt during the Late Quaternary (southwestern Chad Basin)

NASA Astrophysics Data System (ADS)

Diaz, Nathalie; Dietrich, Fabienne; Sebag, David; King, Georgina E.; Valla, Pierre G.; Durand, Alain; Garcin, Yannick; de Saulieu, Geoffroy; Deschamps, Pierre; Herman, Frédéric; Verrecchia, Eric P.

2018-07-01

Climate and environmental changes since the Last Glacial Maximum in the tropical zone of West Africa are usually inferred from marine and continental records. In this study, the potential of carbonate pedo-sedimentary geosystems, i.e. Vertisol relics, to record paleoenvironmental changes in the southwestern part of Chad Basin are investigated. A multi-dating approach was applied on different pedogenic organo-mineral constituents. Optically stimulated luminescence (OSL) dating was performed on the soil K-rich feldspars and was combined with radiocarbon dating on both the inorganic (14Cinorg) and organic carbon (14Corg) soil fractions. Three main pedo-sedimentary processes were assessed over the last 20 ka BP: 1) the soil parent material deposition, from 18 ka to 12 ka BP (OSL), 2) the soil organic matter integration, from 11 cal ka to 8 cal ka BP (14Corg), and 3) the pedogenic carbonate nodule precipitation, from 7 cal ka to 5 cal ka BP (14Cinorg). These processes correlate well with the Chad Basin stratigraphy and West African records and are shown to be related to significant changes in the soil water balance responding to the evolution of continental hydrology during the Late Quaternary. The last phase affecting the Vertisol relics is the increase of erosion, which is hypothesized to be due to a decrease of the vegetation cover triggered by (i) the onset of drier conditions, possibly strengthened by (ii) anthropogenic pressure. Archaeological data from Far North Cameroon and northern Nigeria, as well as sedimentation times in Lake Tilla (northeastern Nigeria), were used to test these relationships. The increase of erosion is suggested to possibly occur between c. 3 cal ka and 1 cal ka BP. Finally, satellite images revealed similar geosystems all along the Sudano-Sahelian belt, and initial 14Cinorg ages of the samples collected in four sites gave similar ages to those reported in this study. Consequently, the carbonate pedo-sedimentary geosystems are valuable continental paleoenvironmental archives and soil water balance proxies of the semiarid tropics of West Africa.

High-resolution analysis of Quaternary calcretes: a coupled stable isotope and micromorphological approach

NASA Astrophysics Data System (ADS)

Adamson, Kathryn; Candy, Ian; Whitfield, Liz

2015-04-01

Pedogenic calcretes are abundant in arid and semi-arid regions, and they are widely used as proxy records of palaeoclimatic change. Calcrete oxygen (δ18O) and carbon (δ13C) isotopic signatures are indicative of temperature, aridity, or vegetation at the time of calcrete formation. Their microfabrics also reflect carbonate formation mechanisms in response to the prevailing environmental conditions. Many studies have explored calcrete micromorphology or stable isotope composition, but these techniques have not yet been applied simultaneously. This co-analysis is important as it allows us to establish whether calcrete morphology directly reflects environmental change. This study tests the potential of combining these analyses to examine the relationships between calcrete microfabrics, their isotopic signals, and Quaternary climate change. Calcretes from four river terraces of the Rio Alias in southeast Spain have been analysed in detail. On the basis of morphostratigraphic correlation (Maher et al., 2007) and Uranium-series ages (Candy et al., 2005), these span the period from 304 ± 26 ka (MIS 9) to the Holocene. The oldest profiles have therefore been exposed to multiple glacial-interglacial cycles. A total of 37 micromorphological profiles have been used to extract stable oxygen and carbon isotopic indicators from 77 microfacies. The morphological and isotopic complexity of the calcrete profiles increases with progressive age. The oldest samples display multiple calcretisation phases, and their microfabrics have a larger isotopic range than the younger samples. Alpha (non-biogenic) fabrics have higher δ13C and δ18O values than beta (biogenic) fabrics. Strong positive covariance between δ13C and δ18O within all profiles suggests that both isotopes are responding to the same environmental parameter. We suggest that this is relative aridity. The study demonstrates that the detailed co-analysis of calcrete micromorphology and stable isotope signatures allows calcrete formation patterns to be placed into a wider palaeoclimatic context. Importantly, this technique provides a level of detail that is not possible through bulk isotope sampling alone. It demonstrates the potential of this technique to more reliably constrain the palaeoenvironmental significance of secondary carbonates in dryland settings where other proxy records may be poorly preserved.

New characterization aspects of carbonate accumulation horizons in Chalky Champagne (NE of the Paris Basin, France)

NASA Astrophysics Data System (ADS)

Linoir, Damien; Thomachot-Schneider, Céline; Gommeaux, Maxime; Fronteau, Gilles; Barbin, Vincent

2016-05-01

The soil profiles of the Champagne area (NE of Paris Basin, France) occasionally show carbonate accumulation horizons (CAHs). From the top to the bottom, these soil profiles include a rendic leptosol horizon, a Quaternary cryoturbated paleosol (QCP), and a chalky substratum. The CAHs are located in the top part of the QCP. This study is aimed at highlighting the specific characteristics of CAHs compared to other soil profile horizons using geophysics, geochemistry, micromorphology, and mercury injection porosimetry. It is the first essential step for understanding the impact of CAHs on water transfers into the Champagne soil profiles. Our analyses show that Champagne CAHs are not systematically characterized by a typical induration unlike generally put forward in the regional literature. They are more porous and heterogeneous than their parent material (QCP). Carbonate accumulation horizons are also characterized by singular colorimetric parameters that are linked to their geochemical specific content, even if they bear a signature of the initial QCP before the pedogenic modification.

Photochemical activity of a key donor-acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes.

PubMed

Arceo, Elena; Jurberg, Igor D; Alvarez-Fernández, Ana; Melchiorre, Paolo

2013-09-01

Asymmetric catalytic variants of sunlight-driven photochemical processes hold extraordinary potential for the sustainable preparation of chiral molecules. However, the involvement of short-lived electronically excited states inherent to any photochemical reaction makes it challenging for a chiral catalyst to dictate the stereochemistry of the products. Here, we report that readily available chiral organic catalysts, with well-known utility in thermal asymmetric processes, can also confer a high level of stereocontrol in synthetically relevant intermolecular carbon-carbon bond-forming reactions driven by visible light. A unique mechanism of catalysis is proposed, wherein the catalyst is involved actively in both the photochemical activation of the substrates (by inducing the transient formation of chiral electron donor-acceptor complexes) and the stereoselectivity-defining event. We use this approach to enable transformations that are extremely difficult under thermal conditions, such as the asymmetric α-alkylation of aldehydes with alkyl halides, the formation of all-carbon quaternary stereocentres and the control of remote stereochemistry.

Alternative performance measures for evaluating congestion.

DOT National Transportation Integrated Search

2004-04-01

This report summarizes the results of the work performed under the project Alternative Performance Measures for Evaluating : Congestion. The study first outlines existing approaches to looking at congestion. It then builds on the previous work in the...

Technologies that complement congestion pricing : a primer.

DOT National Transportation Integrated Search

2008-10-01

The purpose of this volume is to consider the technology options that are available to complement congestion-pricing approaches. This primer explores how technology broadens the success for congestion pricing by supporting the traveler's decision to ...

Multimodal and corridor applications of travel time reliability.

DOT National Transportation Integrated Search

2012-03-30

Congestion is all too familiar in Floridas cities. Traditionally, agencies have tried to mitigate recurring congestion by comparing demand and capacity during peak periods and alleviating bottlenecks. However, congestion is often due to nonrecurri...

Multimodal and corridor applications of travel time reliability : [summary].

DOT National Transportation Integrated Search

2012-01-01

Congestion is all too familiar in Floridas cities. Traditionally, agencies have tried to mitigate recurring congestion by comparing demand and capacity during peak periods and alleviating bottlenecks. However, congestion is often due to nonrecurri...

Statewide GIS mapping of recurring congestion corridors : final report.

DOT National Transportation Integrated Search

2009-07-01

Recurring congestion occurs when travel demand reaches or exceeds the available roadway : capacity. This project developed an interactive geographic information system (GIS) map of the : recurring congestion corridors (labeled herein as hotspots) in ...

Congestion pricing : a primer : overview

DOT National Transportation Integrated Search

2008-10-01

This Overview primer was produced to explain the concept of congestion pricing and its benefits, to present examples of congestion-pricing approaches implemented in the United States and abroad, and to briefly discuss federal-aid policy and programs ...

Local empathy provides global minimization of congestion in communication networks

NASA Astrophysics Data System (ADS)

Meloni, Sandro; Gómez-Gardeñes, Jesús

2010-11-01

We present a mechanism to avoid congestion in complex networks based on a local knowledge of traffic conditions and the ability of routers to self-coordinate their dynamical behavior. In particular, routers make use of local information about traffic conditions to either reject or accept information packets from their neighbors. We show that when nodes are only aware of their own congestion state they self-organize into a hierarchical configuration that delays remarkably the onset of congestion although leading to a sharp first-order-like congestion transition. We also consider the case when nodes are aware of the congestion state of their neighbors. In this case, we show that empathy between nodes is strongly beneficial to the overall performance of the system and it is possible to achieve larger values for the critical load together with a smooth, second-order-like, transition. Finally, we show how local empathy minimize the impact of congestion as much as global minimization. Therefore, here we present an outstanding example of how local dynamical rules can optimize the system’s functioning up to the levels reached using global knowledge.

Fixture congestion modulates post-match recovery kinetics in professional soccer players.

PubMed

Lundberg, Tommy R; Weckström, Kristoffer

2017-01-01

This study examined the influence of fixture congestion on physical performance and biochemical variables in professional male footballers. After 3 competitive matches within a week (3M cycle), 16 players underwent blood sampling and field testing 72 h after the last match. The same tests were performed after a regular 1 match-week cycle (1M cycle). The 1M vs. 3M change scores were compared between Congested (high match exposure) and non-selected Control players. The change score in muscle soreness was greater (effect size 1.0; CI 0.0-1.9) in the Congested players than Controls, indicating a possible negative effect of fixture congestion. There were no effects on sprint and jump performance. The change in plasma (P)-Urea was greater in Congested players than controls (effect size 1.3; CI 0.3-2.2). The effects on other blood variables were either non-existing/trivial, or unclear. Altogether, physical fitness and immune function were not compromised by match congestion, yet some indices of physiological stress and muscle damage were still evident.

Quaternary fault-controlled volcanic vents and crustal thinning: new insights from the magma-rich Tyrrhenian passive margin (Italy)

NASA Astrophysics Data System (ADS)

Cardello, Giovanni Luca; Conti, Alessia; Consorti, Lorenzo; Do Couto, Damien

2017-04-01

The discover of monogenic Quaternary volcanic vents, that were recently mapped along major fault zones both inland and offshore the Tyrrhenian magma-rich passive margin, poses questions about: timing and role they had into Plio-Pleistocene crustal thinning with relevant consequences for the hazard assessment of an area inhabited by some 0.5 million people. The present-day margin is stretched over 100 km between the Volsci Range (VR) and the Pontian escarpment, being defined by moderate shallow seismicity (Mw≤4.6), relative high geothermal gradient and ongoing hydrothermal activity. Although major central volcanoes (e.g., Colli Albani), occurring at major fault intersections are well studied, smaller volcanic fields were so far unconstrained. Both field survey in the VR and offshore high-resolution geophysical data, allow us to: 1) better define the anatomy of the poorly known VR volcanic field; 2) furnish new insights on the regional Quaternary dynamics; 3) propose modes and reason of magma emplacement. The VR is composed of about 40 punctual and linear monogenic and mostly phreatomagmatic vents occurring at the edges of the Apennine carbonate fold-and-thrust belt and within the VR backbone. Volcanites are characterized by zeolitized to incoherent tuffs and surge deposits locally covered by lavas and slope deposits. Most explosive units host carbonate-rich lithics with different degrees of rounding and decarbonation, which frequently belong to Albian-Cenomanian aquifers. By comparing cross-section with lithic analyses we demonstrate that fragmentation, transport, progressive disintegration and decarbonation occur at multiple depths, depending on the fold-and-thrust belt setting. Thus, along the same vent zone, juvenile lithic composition proves repeated fragmentation within pressured-aquifers, testifying for fissural activity with implications for local seismic and volcanic assessment. Pyroclastic deposits occur as well in the Pontina and Fondi coastal plains at shallow depth suggesting recent (<10 kyr) and possibly local eruptions. Offshore, 25 km north of Ventotene, a middle Pleistocene 200 m-high truncated volcano was found partially covered by middle to recent deposits. It is delimited by well defined WNW-striking fault-controlled escarpment dissected by NE-striking faults. As on the Ponza-Zannone high, volcanic complex occur on a horst intersecting the two main regional trends, possibly associated with younger SE-stretching. Quaternary stretching rotation occurs as a response to Tyrrhenian back-arc opening and contemporaneous inarching of the Apennine front. In this frame, frontal to lateral slab tearing and retreat is tracked by E-rejuvenated volcanic activity along the Palmarola-Vesuvius lineament. In conclusion, we argue about the role NE-dipping crustal detachment(s) may have played into crustal thinning, driving and occasionally hampering magma-emplacement.

Health effects of people living close to a petrochemical industrial estate in Thailand.

PubMed

Kongtip, Pornpimol; Singkaew, Panawadee; Yoosook, Witaya; Chantanakul, Suttinun; Sujiratat, Dusit

2013-12-01

An acute health effect of people living near the petrochemical industrial estate in Thailand was assessed using a panel study design. The populations in communities near the petrochemical industrial estates were recruited. The daily air pollutant concentrations, daily percentage of respiratory and other health symptoms reported were collected for 63 days. The effect of air pollutants to reported symptoms of people were estimated by adjusted odds ratios and 95% confidence interval using binary logistic regression. The significant associations were found with the adjusted odds ratios of 38.01 for wheezing, 18.63 for shortness of breath, 4.30 for eye irritation and 3.58 for dizziness for total volatile organic compounds (Total VOCs). The adjusted odds ratio for carbon monoxide (CO2) was 7.71 for cough, 4.55 for eye irritation and 3.53 for weakness and the adjusted odds ratio for ozone (O3) was 1.02 for nose congestion, sore throat and 1.05 for phlegm. The results showed that the people living near petrochemical industrial estate had acute adverse health effects, shortness of breath, eye irritation, dizziness, cough, nose congestion, sore throat, phlegm and weakness from exposure to industrial air pollutants.

Atlanta congestion reduction demonstration : national evaluation report.

DOT National Transportation Integrated Search

2014-03-01

This document presents the final report on the national evaluation of the Atlanta Congestion Reduction Demonstration (CRD) under the United States Department of Transportation (U.S. DOT) CRD Program. The Atlanta CRD projects focus on reducing congest...

Modeling the effect of accessibility and congestion in location choice.

DOT National Transportation Integrated Search

2012-12-01

This study explores the relationship between accessibility and congestion, and their impacts on property values. Three research questions are addressed: (1) What is the relation between accessibility and congestion both regional and neighborhood leve...

Speed harmonization and peak-period shoulder use to manage urban freeway congestion.

DOT National Transportation Integrated Search

2009-10-01

Traffic congestion is an increasing problem in the nations urban areas, leading to personal inconvenience, : increased pollution, hampered economic productivity, and reduced quality of life. While traffic congestion tends : to continuously increas...

A toolbox for alleviating traffic congestion and enhancing mobility

DOT National Transportation Integrated Search

2012-06-01

This report presents the Tolling Data Test Plan for the national evaluation of the Los Angeles (LA) Congestion Reduction Demonstration (Metro ExpressLanes) under the United States Department of Transportation (U.S. DOT) Congestion Reduction Demonstra...

Determining queue and congestion in highway work zone bottlenecks.

DOT National Transportation Integrated Search

2011-03-11

Construction zones, though required for infrastructure maintenance, have become congestion choke points on most highway systems in the US. The congestion may create potentially unsafe driving conditions for approaching motorists that do not expect qu...

Determining Queue and Congestion in Highway Work Zone Bottlenecks

DOT National Transportation Integrated Search

2011-03-11

Construction zones, though required for infrastructure maintenance, have become congestion choke points on most highway systems in the US. The congestion may create potentially unsafe driving conditions for approaching motorists that do not expect qu...

21 CFR 172.165 - Quaternary ammonium chloride combination.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Quaternary ammonium chloride combination. 172.165... HUMAN CONSUMPTION Food Preservatives § 172.165 Quaternary ammonium chloride combination. The food additive, quaternary ammonium chloride combination, may be safely used in food in accordance with the...

Quaternary prevention: reviewing the concept.

PubMed

Martins, Carlos; Godycki-Cwirko, Maciek; Heleno, Bruno; Brodersen, John

2018-12-01

According to the Wonca International Dictionary for General/Family Practice Quaternary Prevention is defined as: 'Action taken to identify patient at risk of overmedicalization, to protect him from new medical invasion, and to suggest to him interventions, which are ethically acceptable.' The concept of quaternary prevention was initially proposed by Marc Jamoulle and the targets were mainly patients with illness but without a disease. The purpose of this opinion article is to open the debate around a new possible definition and a new conceptual model of quaternary prevention based on the belief that quaternary prevention should be present in physicians' minds for every intervention they suggest to a patient. The debate around quaternary prevention is vital in the context of contemporary medicine and has expanded worldwide. The human being may suffer harm from medical interventions from conception, during their childhood, during their entire healthy lifetime as well as during a self-limited disease, a chronic disease, or a terminal disease. The current definition of quaternary prevention has limitations because it excludes patients and medical interventions where a quaternary prevention perspective would be needed and useful to protect patients from harm. In this context, a new definition and conceptual model of quaternary prevention is proposed. In this new proposal, quaternary prevention is defined as an 'action taken to protect individuals (persons/patients) from medical interventions that are likely to cause more harm than good.'

Improved performance and safety of lithium ion cells with the use of fluorinated carbonate-based electrolytes

NASA Technical Reports Server (NTRS)

Smart, M. C.; Ratnakumar, B. V.; Ryan, V. S.; Surampudi, S.; Prakashi, G. K. S.; Hu, J.; Cheung, I.

2002-01-01

There has been increasing interest in developing lithium-ion electrolytes that possess enhanced safety characteristics, while still able to provide the desired stability and performance. Toward this end, our efforts have been focused on the development of lithium-ion electrolytes which contain partially and fully fluorinated carbonate solvents. The advantage of using such solvents is that they possess the requisite stability demonstrated by the hydrocarbon-based carbonates, while also possessing more desirable physical properties imparted by the presence of the fluorine substituents, such as lower melting points, increased stability toward oxidation, and favorable SEI film forming Characteristics on carbon. Specifically, we have demonstrated the beneficial effect of electrolytes which contain the following fluorinated carbonate-based solvents: methyl 2,2,2-trifluoroethyl carbonate (MTFEC), ethyl-2,2,2 trifluoroethyl carbonate (ETFEC), propyl 2,2,2-trifluoroethyl carbonate (PTFEC), methyl-2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (MHFPC), ethyl- 2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (EHFPC), and di-2,2,2-trifluoroethyl carbonate (DTFEC). These solvents have been incorporated into multi-component ternary and quaternary carbonate-based electrolytes and evaluated in lithium-carbon and carbon-LiNio.8Coo.202 cells (equipped with lithium reference electrodes). In addition to determining the charge/discharge behavior of these cells, a number of electrochemical techniques were employed (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further characterize the performance of these electrolytes, including the SEI formation characteristics and lithium intercalatiodde-intercalation kinetics. In addition to their evaluation in experimental cells, cyclic voltammetry (CV) and conductivity measurements were performed on select electrolyte formulations to further our understanding of the trends in stability and ionic mobility imparted by different alkyl substituents in linear carbonates.

Diagnosis and Treatment of Depression in Patients With Congestive Heart Failure: A Review of the Literature

PubMed Central

Stern, Theodore A.; Hebert, Kathy A.; Musselman, Dominique L.

2013-01-01

Context: Major depressive disorder (MDD) can be challenging to diagnose in patients with congestive heart failure, who often suffer from fatigue, insomnia, weight changes, and other neurovegetative symptoms that overlap with those of depression. Pathophysiologic mechanisms (eg, inflammation, autonomic nervous system dysfunction, cardiac arrhythmias, and altered platelet function) connect depression and congestive heart failure. Objective: We sought to review the prevalence, diagnosis, neurobiology, and treatment of depression associated with congestive heart failure. Data Sources: A search of all English-language articles between January 2003 and January 2013 was conducted using the search terms congestive heart failure and depression. Study Selection: We found 1,498 article abstracts and 19 articles (meta-analyses, systematic reviews, and original research articles) that were selected for inclusion, as they contained information about our focus on diagnosis, treatment, and pathophysiology of depression associated with congestive heart failure. The search was augmented with manual review of reference lists of articles from the initial search. Articles selected for review were determined by author consensus. Data Extraction: The prevalence, diagnosis, neurobiology, and treatment of depression associated with congestive heart failure were reviewed. Particular attention was paid to the safety, efficacy, and tolerability of antidepressant medications commonly used to treat depression and how their side-effect profiles impact the pathophysiology of congestive heart failure. Drug-drug interactions between antidepressant medications and medications used to treat congestive heart failure were examined. Results: MDD is highly prevalent in patients with congestive heart failure. Moreover, the prevalence and severity of depression correlate with the degree of cardiac dysfunction and development of congestive heart failure. Depression increases the risk of congestive heart failure, particularly in those patients with coronary artery disease , and is associated with a poorer quality of life, increased use of health care resources, more frequent adverse clinical events and hospitalizations, and twice the risk of mortality. Conclusions: At present, limited empirical data exist with regard to treatment of depression in the increasingly large population of patients with congestive heart failure. Evidence reveals that both psychotherapeutic treatment (eg, cognitive-behavioral therapy) and pharmacologic treatment (eg, use of the selective serotonin reuptake inhibitor sertraline) are safe and effective in reducing depression severity in patients with cardiovascular disease. Collaborative care programs featuring interventions that work to improve adherence to medical and psychiatric treatments improve both cardiovascular disease and depression outcomes. Depression rating scales such as the 9-item Patient Health Questionnaire should be used to monitor therapeutic efficacy. PMID:24392265

Policy Choice for Urban Low-carbon transportation in Beijing: Scenario Analysis Based on LEAP model

NASA Astrophysics Data System (ADS)

Zhang, Yu

2016-04-01

Beijing is a fast developing megacity with serious traffic problems, such as high energy consumption, high CO2 emission and traffic congestion. The coming 13th Five-Year Plan for Beijing economic and social development will focus on the low-carbon transportation policy to achieve the urban traffic sustainable development. In order to improve the feasibility of urban low-carbon transportation policies, this paper analyzes the future trends of CO2 emissions from transportation of Beijing. Firstly, five policies scenarios are developed according to the coming Beijing 13th Five-Year Plan, including the "Business As Usual (BAU)", the "Public Transportation Priority(PTP)", the "New Energy Vehicle(NEV)", the "Active Transportation(AT)", the "Private Car Regulation(PCR)" and the "Hybrid Policy(HP)". Then the Long-range Energy Alternatives Planning System(LEAP model) framework is adopted to estimate CO2 emission under given policies scenarios up to year 2020 and analyze the implications. The results demonstrate that the low-carbon transportation policies can reduce CO2 emission effectively. Specifically, the "Hybrid Policy(HP)" has the best performance. In terms of single policy effect, the "Private Car Regulation(PCR)" comes first followed by the "Public Transportation Priority(PTP)".

The ethanopharmacological aspect of carbon nanodots in turmeric smoke.

PubMed

Chun, Sechul; Muthu, Manikandan; Gansukh, Enkhtaivan; Thalappil, Pradeep; Gopal, Judy

2016-11-02

Smoke manifested ever since our ancient's lit fire; today it has evolved to become an environmental concern. However, medicinal smoke is still part of man's natural remedies, religious and cultural practices too. The Asiatic household practice of burning turmeric rhizomes to relieve nose and chest congestion is a well known yet never scientifically authenticated or studied practice. For the first time we investigate the components of these turmeric smudges, validate their antimicrobial and anticancer properties and their cell compatibility. With smoke there is always nanoparticulate carbon and turmeric smoke is no exception. If so, what is the role of the nano carbon (NC) in the turmeric smudge effect? This study isolated, characterized and exposed these secret natural NC undercover agents in turmeric smoke. Their unequivocal role in the ethanopharmocological activity of turmeric smudging has been demonstrated. This work opens a new avenue for use of such nano components of smoke for harnessing the ethanopharmacological property of various medicinal smokes, by excluding the smoke factor, through extracting the nano carbon material in them. This is a possibility to realizing the use of such naturally available nanomaterial, as an eco friendly substitute for the notorious anthropogenic nanomaterials.

The ethanopharmacological aspect of carbon nanodots in turmeric smoke

NASA Astrophysics Data System (ADS)

Chun, Sechul; Muthu, Manikandan; Gansukh, Enkhtaivan; Thalappil, Pradeep; Gopal, Judy

2016-11-01

Smoke manifested ever since our ancient’s lit fire; today it has evolved to become an environmental concern. However, medicinal smoke is still part of man’s natural remedies, religious and cultural practices too. The Asiatic household practice of burning turmeric rhizomes to relieve nose and chest congestion is a well known yet never scientifically authenticated or studied practice. For the first time we investigate the components of these turmeric smudges, validate their antimicrobial and anticancer properties and their cell compatibility. With smoke there is always nanoparticulate carbon and turmeric smoke is no exception. If so, what is the role of the nano carbon (NC) in the turmeric smudge effect? This study isolated, characterized and exposed these secret natural NC undercover agents in turmeric smoke. Their unequivocal role in the ethanopharmocological activity of turmeric smudging has been demonstrated. This work opens a new avenue for use of such nano components of smoke for harnessing the ethanopharmacological property of various medicinal smokes, by excluding the smoke factor, through extracting the nano carbon material in them. This is a possibility to realizing the use of such naturally available nanomaterial, as an eco friendly substitute for the notorious anthropogenic nanomaterials.

The ethanopharmacological aspect of carbon nanodots in turmeric smoke

PubMed Central

Chun, Sechul; Muthu, Manikandan; Gansukh, Enkhtaivan; Thalappil, Pradeep; Gopal, Judy

2016-01-01

Smoke manifested ever since our ancient’s lit fire; today it has evolved to become an environmental concern. However, medicinal smoke is still part of man’s natural remedies, religious and cultural practices too. The Asiatic household practice of burning turmeric rhizomes to relieve nose and chest congestion is a well known yet never scientifically authenticated or studied practice. For the first time we investigate the components of these turmeric smudges, validate their antimicrobial and anticancer properties and their cell compatibility. With smoke there is always nanoparticulate carbon and turmeric smoke is no exception. If so, what is the role of the nano carbon (NC) in the turmeric smudge effect? This study isolated, characterized and exposed these secret natural NC undercover agents in turmeric smoke. Their unequivocal role in the ethanopharmocological activity of turmeric smudging has been demonstrated. This work opens a new avenue for use of such nano components of smoke for harnessing the ethanopharmacological property of various medicinal smokes, by excluding the smoke factor, through extracting the nano carbon material in them. This is a possibility to realizing the use of such naturally available nanomaterial, as an eco friendly substitute for the notorious anthropogenic nanomaterials. PMID:27805007

Glacial Age Correlations and Pedogenesis Rates at Long Valley, Costilla Masif, Northern New Mexico

NASA Astrophysics Data System (ADS)

Feldman, A. D.

2017-12-01

New Mexico represents the southernmost extent of glacial activity in the United States. As such an enhanced understanding of glacial climate cycles in the region as expressed through the relict landscapes they leave behind can enhance our understanding of the evolution of high altitude landscapes and soils throughout the Quaternary period. The Sangre De Cristo mountain range in northern New Mexico exhibits some of the southernmost expansion of glacial activity in the Southwest during the Quaternary; yet the range has had only limited correlation of its glacial chronology performed to date. In this study a detailed investigation into soil pedogenesis on relict moraine features is used to fit the Long Valley glacial sequence extending eastward from the Costilla Masif into the established Rocky Mountain glacial chronology. Analyzed soil development characteristics are particle size, organic carbon, and iron oxide distributions including total iron, ferric iron, ferrous iron, citrate dithionite, hydroxylamine for amorphous ferrihydrite, and pyrophosphate for organically bound iron. In addition, soils developement will be analyzed in situ for computation of a modified Harden soil profile development index. A secondary purpose of the study is to establish better constraints on the rates of soil pedogenesis in these high altitude glacial features. Soil profile developement and pedogenesis rates will be compared with previously published data from areas both further south in the Sangre De Cristo's as well as throughout the more northern sections of the Rocky Mountains to correlate moraine ages as well as to constrain how the particular climate of the Long Valley has affected soil development during the Quaternary.

Forecasting the clearance time of freeway accidents

DOT National Transportation Integrated Search

2002-01-01

Freeway congestion is a major and costly problem in many U.S. metropolitan areas. From a traveler's perspective, congestion has costs in terms of longer travel times and lost productivity. From the traffic manager's perspective, congestion causes a f...

The economic cost of traffic congestion in Florida.

DOT National Transportation Integrated Search

2010-08-01

Traffic congestion in the U.S. is bad and getting worse, and it is expensive. Appropriate solutions to this problem require appropriate information. A comprehensive and accurate analysis of congestion costs is a critical tool for planning and impleme...

Air quality assessment at a congested urban intersection

DOT National Transportation Integrated Search

2000-09-01

The deficient transportation system of Beirut results in significant economic losses for the city and causes severe traffic congestion in the urban areas. Proposals have been made for grade separations at some of the worst congested intersections. Th...

Impact of congestion on bus operations and costs.

DOT National Transportation Integrated Search

2003-10-01

Traffic congestion in Northern New Jersey imposes substantial operational and monetary penalty on bus service. The purpose of this project was to quantify the additional time and costs due to traffic congestion. A regression model was developed that ...

Mobility and the Costs of Congestion in New Jersey

DOT National Transportation Integrated Search

2000-02-01

This study measured quantifiable and qualitative impacts of congestion in New Jersey on mobility, the cost of transportation, and economic productivity. It addressed the impacts of congestion on both an individual level (impacts on an average travele...

Measuring non-recurrent congestion in small to medium sized urban areas.

DOT National Transportation Integrated Search

2013-05-01

Understanding the relative magnitudes of recurrent vs. non-recurrent congestion in an urban area is critical to the selection of proper countermeasures and the appropriate allocation of resources to address congestion problems. Small to medium sized ...

Estimating teat canal cross-sectional area to determine the effects of teat-end and mouthpiece chamber vacuum on teat congestion.

PubMed

Penry, J F; Upton, J; Mein, G A; Rasmussen, M D; Ohnstad, I; Thompson, P D; Reinemann, D J

2017-01-01

The primary objective of this experiment was to assess the effect of mouthpiece chamber vacuum on teat-end congestion. The secondary objective was to assess the interactive effects of mouthpiece chamber vacuum with teat-end vacuum and pulsation setting on teat-end congestion. The influence of system vacuum, pulsation settings, mouthpiece chamber vacuum, and teat-end vacuum on teat-end congestion were tested in a 2×2 factorial design. The low-risk conditions for teat-end congestion (TEL) were 40 kPa system vacuum (Vs) and 400-ms pulsation b-phase. The high-risk conditions for teat-end congestion (TEH) were 49 kPa Vs and 700-ms b-phase. The low-risk condition for teat-barrel congestion (TBL) was created by venting the liner mouthpiece chamber to atmosphere. In the high-risk condition for teat-barrel congestion (TBH) the mouthpiece chamber was connected to short milk tube vacuum. Eight cows (32 quarters) were used in the experiment conducted during 0400 h milkings. All cows received all treatments over the entire experimental period. Teatcups were removed after 150 s for all treatments to standardize the exposure period. Calculated teat canal cross-sectional area (CA) was used to assess congestion of teat tissue. The main effect of the teat-end treatment was a reduction in CA of 9.9% between TEL and TEH conditions, for both levels of teat-barrel congestion risk. The main effect of the teat-barrel treatment was remarkably similar, with a decrease of 9.7% in CA between TBL and TBH conditions for both levels of teat-end congestion risk. No interaction between treatments was detected, hence the main effects are additive. The most aggressive of the 4 treatment combinations (TEH plus TBH) had a CA estimate 20% smaller than for the most gentle treatment combination (TEL plus TBL). The conditions designed to impair circulation in the teat barrel also had a deleterious effect on circulation at the teat end. This experiment highlights the importance of elevated mouthpiece chamber vacuum on teat-end congestion and resultant decreases in CA. Copyright © 2017 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Medicinal Leech Therapy for Glans Penis Congestion After Primary Bladder Exstrophy-Epispadias Repair in an Infant: A Case Report.

PubMed

Wagenheim, Gavin N; Au, Jason; Gargollo, Patricio C

2016-01-01

Many postoperative complications have been reported after repair of classic bladder exstrophy. We present a case of medicinal leech therapy for glans penis congestion following exstrophy repair in an infant. A 2-week-old male with classic bladder exstrophy underwent complete primary repair. On postoperative day 1, he developed rapidly worsening glans penis venous congestion. Medicinal leech therapy was instituted with antibiotics and blood transfusions to maintain a hematocrit >30%. After 24 hours, venous congestion improved and therapy was discontinued. The patient's remaining hospital course was uncomplicated. Medicinal leeches are an effective therapy to relieve glans penis venous congestion. Copyright © 2015 Elsevier Inc. All rights reserved.

Phase diagram of congested traffic flow: An empirical study

PubMed

Lee; Lee; Kim

2000-10-01

We analyze traffic data from a highway section containing one effective on-ramp. Based on two criteria, local velocity variation patterns and expansion (or nonexpansion) of congested regions, three distinct congested traffic states are identified. These states appear at different levels of the upstream flux and the on-ramp flux, thereby generating a phase digram of the congested traffic flow. Observed traffic states are compared with recent theoretical analyses and both agreeing and disagreeing features are found.

Commuter exposure to black carbon, carbon monoxide, and noise in the mass transport khlong boats of Bangkok, Thailand

NASA Astrophysics Data System (ADS)

Ziegler, A. D.; Velasco, E.; Ho, K. J.

2013-12-01

Khlong (canal) boats are a unique mass transport alternative in the congested city of Bangkok. Canals and rivers provide exclusive transit-ways for reducing the commuting time of thousands of city residents daily. However, as a consequence of the service characteristics and boats design and state of repair, they can represent a potential public health risk and an important source of black carbon and greenhouse gases. This work quantifies commuter exposure to black carbon, CO and noise when waiting for and travelling in these diesel fueled boats. Exposure to toxic pollutants and acute noise is similar or worse than for other transportation modes. Mean black carbon concentrations observed at one busy pier and along the main canal were much higher than ambient concentrations at sites impacted by vehicular traffic. Concentrations of CO were similar to those reported for roadside areas of Bangkok. The equivalent continuous sound levels registered at the landing pier were similar to those reported for roadsides, but values recorded inside the boats were significantly higher. We believe that the boat service is a viable alternative mode of mass transport, but public safety could be improved to provide a high quality service, comparable to modern rail systems or emerging bus rapid transit systems. These investments would also contribute to reduce the emission of black carbon and other greenhouse and toxic pollutants.

[Use of antihypertensive drug therapy and risk of development of congestive heart failure].

PubMed

Sobrino, Javier; Plana, Jaume; Felip, Angela; Doménech, Mónica; Reth, Peter; Adrián, María Jesús; de la Sierra, Alejandro

2004-09-18

It has been suggested that the use of some antihypertensive agents may favour the development of congestive heart failure. The aim of the present study was to evaluate such a possible association in patients who had a new diagnosis of congestive heart failure. This was a retrospective case-control study of 81 patients who had a first hospital admission with a new diagnosis of congestive heart failure (cases) and 162 patients admitted for other hypertensive complications (controls). Previous antihypertensive drug use was registered and the possible association with congestive heart failure was evaluated. The presence of congestive heart failure was not associated with the use of any antihypertensive drug class. When treatments were grouped in classic (diuretics and betablockers) or modern (calcium channel blockers, angiotensin-converting-enzyme inhibitors, alphablockers or angiotensin receptor blockers), a negative association was observed with the latter group, which was observed in 48.1% of cases and 63.6% of controls (odds ratio: 0.532; 95% confidence interval, 0.310-0.913). This association was lost after adjustment for other cardiovascular risk factors or previous hypertensive complications. The development of congestive heart failure was not associated with the use of any specific antihypertensive drug class. From the present evidence, it is not possible to recommend a specific antihypertensive agent in patients at risk of developing congestive heart failure but without evidence of such disease.

Reconstruction of Late Quaternary Climate in Central Europe - A Comparison of Stable Isotope and Trace Element Variations in Speleothems From Different Cave Systems in Germany.

NASA Astrophysics Data System (ADS)

Nordhoff, P.; Wiegand, B.; Simon, K.; Rosendahl, W.; Hansen, B. T.; Kempe, S.

2003-12-01

Speleothems (stalagmites, stalactites, flowstones) are important archives for Late Quaternary continental climatic and paleo-environmental reconstruction. Speleothems form when calcium carbonate precipitates from solutions seeping into caves hosted e.g. in limestone or dolomite complexes. Information of past climate variability and changes in local environmental conditions can be obtained from signatures of the stable isotopes of oxygen and carbon as well as trace element pattern recorded in speleothems. Reconstruction of paleo-temperature and past environmental conditions from stable isotopes, however, require isotopic equilibrium between the drip water and the precipitating calcium carbonate. Results from Dietzel et al. (1992) and Johnson and Ingram (2001) indicate that the formation of modern travertine and speleothem calcite occurs under isotopic equilibrium. Factors that influence the stable oxygen and carbon isotope composition during speleothem precipitation include e.g. the moisture source and precipitation, photosynthetic pathways, the bedrock proportion, and the drip rate. This often leads to a situation with several variables. However, a specific interpretation is possible when dealing with environments where only one of the factors is dominant, or specific settings are assumed to be invariant, or further proxies like trace element variations help to define the frame conditions during speleothem formation. Concentrations of trace elements (e.g. Sr, Mg) which are co-precipitated with calcite are related to changes in the composition of the solution and strongly depend on the dissolution/precipitation dynamics along drip water flow paths. In a multiproxy approach they are a valuable tool for the interpretation of the recorded stable isotope variations. We present first results from different cave systems located in the Swabian Alps and the Harz Mountains (Germany). Our study includes a high-resolution multiproxy approach, using U/Th-TIMS data, stable oxygen/carbon isotope data, and geochemical compositions of speleothems, covering ages from the Late Pleistocene to the Early Holocene. The results are compared to geochemical data from host rocks, soil zones, cave sediments, drip water compositions, and recent calcium carbonate precipitates. Understanding the response of a cave system to the actual climatic, hydrologic and environmental regimen is a main requirement for the interpretation of "paleo-information" conserved in speleothems in order to lead to a coherent picture of past continental climate dynamics. References: Dietzel M., Usdowski E., and Hoefs J., (1992): Applied Geochemistry 7: 177-184. Johnson, K.R. and Ingram, B.L. (2001): Abstract volume, 4th Internat. Symp. On Applied Isotope Geochemistry, Pacific Groove, USA: 70-72.

Evaluation of the public health impacts of traffic congestion: a health risk assessment.

PubMed

Levy, Jonathan I; Buonocore, Jonathan J; von Stackelberg, Katherine

2010-10-27

Traffic congestion is a significant issue in urban areas in the United States and around the world. Previous analyses have estimated the economic costs of congestion, related to fuel and time wasted, but few have quantified the public health impacts or determined how these impacts compare in magnitude to the economic costs. Moreover, the relative magnitudes of economic and public health impacts of congestion would be expected to vary significantly across urban areas, as a function of road infrastructure, population density, and atmospheric conditions influencing pollutant formation, but this variability has not been explored. In this study, we evaluate the public health impacts of ambient exposures to fine particulate matter (PM2.5) concentrations associated with a business-as-usual scenario of predicted traffic congestion. We evaluate 83 individual urban areas using traffic demand models to estimate the degree of congestion in each area from 2000 to 2030. We link traffic volume and speed data with the MOBILE6 model to characterize emissions of PM2.5 and particle precursors attributable to congestion, and we use a source-receptor matrix to evaluate the impact of these emissions on ambient PM2.5 concentrations. Marginal concentration changes are related to a concentration-response function for mortality, with a value of statistical life approach used to monetize the impacts. We estimate that the monetized value of PM2.5-related mortality attributable to congestion in these 83 cities in 2000 was approximately $31 billion (2007 dollars), as compared with a value of time and fuel wasted of $60 billion. In future years, the economic impacts grow (to over $100 billion in 2030) while the public health impacts decrease to $13 billion in 2020 before increasing to $17 billion in 2030, given increasing population and congestion but lower emissions per vehicle. Across cities and years, the public health impacts range from more than an order of magnitude less to in excess of the economic impacts. Our analyses indicate that the public health impacts of congestion may be significant enough in magnitude, at least in some urban areas, to be considered in future evaluations of the benefits of policies to mitigate congestion.

Catalyst-Dependent Chemoselective Formal Insertion of Diazo Compounds into C-C or C-H Bonds of 1,3-Dicarbonyl Compounds.

PubMed

Liu, Zhaohong; Sivaguru, Paramasivam; Zanoni, Giuseppe; Anderson, Edward A; Bi, Xihe

2018-05-08

A catalyst-dependent chemoselective one-carbon insertion of diazo compounds into the C-C or C-H bonds of 1,3-dicarbonyl species is reported. In the presence of silver(I) triflate, diazo insertion into the C(=O)-C bond of the 1,3-dicarbonyl substrate leads to a 1,4-dicarbonyl product containing an all-carbon α-quaternary center. This reaction constitutes the first example of an insertion of diazo-derived carbenoids into acyclic C-C bonds. When instead scandium(III) triflate was applied as the catalyst, the reaction pathway switched to formal C-H insertion, affording 2-alkylated 1,3-dicarbonyl products. Different reaction pathways are proposed to account for this powerful catalyst-dependent chemoselectivity. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Development of congestion performance measures using ITS information.

DOT National Transportation Integrated Search

2003-01-01

The objectives of this study were to define a performance measure(s) that could be used to show congestion levels on critical corridors throughout Virginia and to develop a method to select and calculate performance measures to quantify congestion in...

Urban roadway congestion : annual report

DOT National Transportation Integrated Search

1998-01-01

The annual traffic congestion study is an effort to monitor roadway congestion in major urban areas in the United States. The comparisons to other areas and to previous experiences in each area are facilitated by a database that begins in 1982 and in...

A simulation-optimization-based decision support tool for mitigating traffic congestion.

DOT National Transportation Integrated Search

2009-12-01

"Traffic congestion has grown considerably in the United States over the past twenty years. In this paper, we develop : a robust decision support tool based on simulation optimization to evaluate and recommend congestion-mitigation : strategies to tr...

Designing Novel Quaternary Quantum Reversible Subtractor Circuits

NASA Astrophysics Data System (ADS)

Haghparast, Majid; Monfared, Asma Taheri

2018-01-01

Reversible logic synthesis is an important area of current research because of its ability to reduce energy dissipation. In recent years, multiple valued logic has received great attention due to its ability to reduce the width of the reversible circuit which is a main requirement in quantum technology. Subtractor circuits are between major components used in quantum computers. In this paper, we will discuss the design of a quaternary quantum reversible half subtractor circuit using quaternary 1-qudit, 2-qudit Muthukrishnan-Stroud and 3-qudit controlled gates and a 2-qudit Generalized quaternary gate. Then a design of a quaternary quantum reversible full subtractor circuit based on the quaternary half subtractor will be presenting. The designs shall then be evaluated in terms of quantum cost, constant input, garbage output, and hardware complexity. The proposed quaternary quantum reversible circuits are the first attempt in the designing of the aforementioned subtractor.

The diagnostic accuracy of physical examination compared to lung ultrasound for determining lung congestion in hemodialysis patients who have reached their dry weight

NASA Astrophysics Data System (ADS)

Rahardjo, K. D.; Dharmaeizar; Nainggolan, G.; Harimurti, K.

2017-08-01

Research has shown that hemodialysis patients with lung congestion have high morbidity and mortality. Patients were assumed to be free of lung congestion if they had reached their post-dialysis dry weight. Most often, to determine if the patient was free of lung congestion, physical examination was used. However, the accuracy of physical examination in detecting lung congestion has not been established. To compare the capabilities of physical examination and lung ultrasound in detection of lung congestion, cross-sectional data collection was conducted on hemodialysis patients. Analysis was done to obtain proportion, sensitivity, specificity, positive predictive value, negative predictive value, and positive likelihood ratio. Sixty patients participated in this study. The inter observer variation of 20 patients revealed a kappa value of 0.828. When all 60 patients were taken into account, we found that 36 patients (57.1%) had lung congestion. Mild lung congestion was found in 24 (38.1%), and 12 (19%) had a moderate degree of congestion. In the analysis comparing jugular venous pressure to lung ultrasound, we found that sensitivity was 0.47 (0.31-0.63), specificity was 0.73 (0.54-0.86), positive predictive value (PPV) was 0.51 (0.36-0.67), negative predictive value (NPV) was 0.70 (0.49-0.84), positive likelihood ratio (PLR) was 1.75 (0.88-3.47), and the negative likelihood ratio (NLR) was 0.72 (0.47-1.12). In terms of lung auscultation, we found that sensitivity was 0.56 (0.39-0.71), specificity was 0.54 (0.35-0.71), PPV was 0.61 (0.44-0.76), NPV was 0.48 (0.31-0.66), PLR was 1.21 (0.73-2.0), and NLR was 0.82 (0.49-1.38). The results of our study showed that jugular venous distention and lung auscultation examination are not reliable means of detecting lung congestion.

The congestion control algorithm based on queue management of each node in mobile ad hoc networks

NASA Astrophysics Data System (ADS)

Wei, Yifei; Chang, Lin; Wang, Yali; Wang, Gaoping

2016-12-01

This paper proposes an active queue management mechanism, considering the node's own ability and its importance in the network to set the queue threshold. As the network load increases, local congestion of mobile ad hoc network may lead to network performance degradation, hot node's energy consumption increase even failure. If small energy nodes congested because of forwarding data packets, then when it is used as the source node will cause a lot of packet loss. This paper proposes an active queue management mechanism, considering the node's own ability and its importance in the network to set the queue threshold. Controlling nodes buffer queue in different levels of congestion area probability by adjusting the upper limits and lower limits, thus nodes can adjust responsibility of forwarding data packets according to their own situation. The proposed algorithm will slow down the send rate hop by hop along the data package transmission direction from congestion node to source node so that to prevent further congestion from the source node. The simulation results show that, the algorithm can better play the data forwarding ability of strong nodes, protect the weak nodes, can effectively alleviate the network congestion situation.

A New Procedure for Wrapped-Negative Pressure Wound Therapy for Congestion After Arterialized Venous Flap Surgery

PubMed Central

Niimi, Yosuke; Mori, Satoko; Takeuchi, Masaki

2017-01-01

Negative pressure wound therapy (NPWT) is a method for treating wound. However, there are no case reports using NPWT for treating congestion after arterialized venous flap. Therefore, this study reported favorable outcomes after using a single-use NPWT system for managing congestion. A 39-year-old man had his index finger caught by a press machine. The finger had a soft tissue defect at the ventral part. An arterialized venous flap taken from the right forearm was transplanted. Perfusion of the flap was favorable, but on postoperative day 5, congestion and the edema of the flap were found. Then, NPWT was initiated. The congestion and edema in the flap were improved without complications such as flap necrosis and wound infection. At 4 months postoperatively, the morphology of the finger was favorable. In this study, NPWT was speculated to force the deeper blood vessels within the flap to dilate with inducing drainage and the simultaneous reduction in excess blood flow to the cortical layer, resulting in the improvement of congestion. Negative pressure wound therapy was used for treating congestion after the transplantation of arterialized venous flap, and the wound was favorably managed. PMID:29270041

How Travel Demand Affects Detection of Non-Recurrent Traffic Congestion on Urban Road Networks

NASA Astrophysics Data System (ADS)

Anbaroglu, B.; Heydecker, B.; Cheng, T.

2016-06-01

Occurrence of non-recurrent traffic congestion hinders the economic activity of a city, as travellers could miss appointments or be late for work or important meetings. Similarly, for shippers, unexpected delays may disrupt just-in-time delivery and manufacturing processes, which could lose them payment. Consequently, research on non-recurrent congestion detection on urban road networks has recently gained attention. By analysing large amounts of traffic data collected on a daily basis, traffic operation centres can improve their methods to detect non-recurrent congestion rapidly and then revise their existing plans to mitigate its effects. Space-time clusters of high link journey time estimates correspond to non-recurrent congestion events. Existing research, however, has not considered the effect of travel demand on the effectiveness of non-recurrent congestion detection methods. Therefore, this paper investigates how travel demand affects detection of non-recurrent traffic congestion detection on urban road networks. Travel demand has been classified into three categories as low, normal and high. The experiments are carried out on London's urban road network, and the results demonstrate the necessity to adjust the relative importance of the component evaluation criteria depending on the travel demand level.

Quaternary prevention: reviewing the concept

PubMed Central

Martins, Carlos; Godycki-Cwirko, Maciek; Heleno, Bruno; Brodersen, John

2018-01-01

Abstract Background: According to the Wonca International Dictionary for General/Family Practice Quaternary Prevention is defined as: ‘Action taken to identify patient at risk of overmedicalization, to protect him from new medical invasion, and to suggest to him interventions, which are ethically acceptable.’ The concept of quaternary prevention was initially proposed by Marc Jamoulle and the targets were mainly patients with illness but without a disease. Objectives: The purpose of this opinion article is to open the debate around a new possible definition and a new conceptual model of quaternary prevention based on the belief that quaternary prevention should be present in physicians’ minds for every intervention they suggest to a patient. Discussion: The debate around quaternary prevention is vital in the context of contemporary medicine and has expanded worldwide. The human being may suffer harm from medical interventions from conception, during their childhood, during their entire healthy lifetime as well as during a self-limited disease, a chronic disease, or a terminal disease. The current definition of quaternary prevention has limitations because it excludes patients and medical interventions where a quaternary prevention perspective would be needed and useful to protect patients from harm. In this context, a new definition and conceptual model of quaternary prevention is proposed. Conclusion: In this new proposal, quaternary prevention is defined as an ‘action taken to protect individuals (persons/patients) from medical interventions that are likely to cause more harm than good.’ PMID:29384397

An evaluation of congestion-reducing measures used in Virginia.

DOT National Transportation Integrated Search

1992-01-01

Congestion on our nation's highways, especially in urban areas, is a serious problem that is growing steadily worse. In Virginia, it is estimated that 28 percent of the daily vehicle miles of travel (VMT) occurring during peak hour traffic is congest...

Seasonal variation in traffic congestion : a study of three U.S. cities

DOT National Transportation Integrated Search

2008-08-01

Drivers may notice seasonal : changes in patterns of highway : congestion in many urban : areas of the country. These : patterns, however, can be very different for individual cities. : This report looks at congestion patterns over a 3-year period : ...

Projecting future landside congestion delays at the BWI Airport : final report.

DOT National Transportation Integrated Search

2003-10-01

This study examines the access to the BWI Airport in detail. Complex density functions are utilized to determine the : congestion curves faced by passengers arriving at the airport. It is found that all lots have congestion during peak : periods and ...

Long Island Transportation Plan to Manage Congestion: Framework for Developing and Evaluating Improvement Strategies

DOT National Transportation Integrated Search

2002-04-20

The Long Island Transportation Plan to Manage Congestion (LITP 2000) will establish an integrated, multi-modal transportation program of cost-effective strategies to manage congestion and improve the movement of people and goods in Nassau and Suffolk...

Quick Vegas: Improving Performance of TCP Vegas for High Bandwidth-Delay Product Networks

NASA Astrophysics Data System (ADS)

Chan, Yi-Cheng; Lin, Chia-Liang; Ho, Cheng-Yuan

An important issue in designing a TCP congestion control algorithm is that it should allow the protocol to quickly adjust the end-to-end communication rate to the bandwidth on the bottleneck link. However, the TCP congestion control may function poorly in high bandwidth-delay product networks because of its slow response with large congestion windows. In this paper, we propose an enhanced version of TCP Vegas called Quick Vegas, in which we present an efficient congestion window control algorithm for a TCP source. Our algorithm improves the slow-start and congestion avoidance techniques of original Vegas. Simulation results show that Quick Vegas significantly improves the performance of connections as well as remaining fair when the bandwidth-delay product increases.

Fair and efficient network congestion control based on minority game

NASA Astrophysics Data System (ADS)

Wang, Zuxi; Wang, Wen; Hu, Hanping; Deng, Zhaozhang

2011-12-01

Low link utility, RTT unfairness and unfairness of Multi-Bottleneck network are the existing problems in the present network congestion control algorithms at large. Through the analogy of network congestion control with the "El Farol Bar" problem, we establish a congestion control model based on minority game(MG), and then present a novel network congestion control algorithm based on the model. The result of simulations indicates that the proposed algorithm can make the achievements of link utility closing to 100%, zero packet lose rate, and small of queue size. Besides, the RTT unfairness and the unfairness of Multi-Bottleneck network can be solved, to achieve the max-min fairness in Multi-Bottleneck network, while efficiently weaken the "ping-pong" oscillation caused by the overall synchronization.

Traffic jams induced by fluctuation of a leading car.

PubMed

Nagatani, T

2000-04-01

We present a phase diagram of the different kinds of congested traffic triggered by fluctuation of a leading car in an open system without sources and sinks. Traffic states and density waves are investigated numerically by varying the amplitude of fluctuation using a car following model. The phase transitions among the free traffic, oscillatory congested traffic, and homogeneous congested traffic occur by fluctuation of a leading car. With increasing the amplitude of fluctuation, the transition between the free traffic and oscillatory traffic occurs at lower density and the transition between the homogeneous congested traffic and the oscillatory traffic occurs at higher density. The oscillatory congested traffic corresponds to the coexisting phase. Also, the moving localized clusters appear just above the transition lines.

Publications - MP 141 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

DGGS MP 141 Publication Details Title: Quaternary faults and folds in Alaska: A digital database Combellick, R.A., 2012, Quaternary faults and folds in Alaska: A digital database, in Koehler, R.D Quaternary faults, scale 1:3,700,000 (63.0 M) Digital Geospatial Data Digital Geospatial Data Quaternary

Enhancing CORSIM for simulating high occupancy/toll lane operations.

DOT National Transportation Integrated Search

2012-03-15

Congestion pricing has been advocated as an efficient way to mitigate traffic congestion : since 1920s. A prevalent form of congestion pricing in the U.S. is high occupancy/toll (HOT) : lanes. The operating objective of HOT lanes is to improve the th...

23 CFR 500.109 - CMS.

Code of Federal Regulations, 2011 CFR

2011-04-01

.... Congestion management means the application of strategies to improve system performance and reliability by... SYSTEMS Management Systems § 500.109 CMS. (a) For purposes of this part, congestion means the level at... management system or process is a systematic and regionally accepted approach for managing congestion that...

23 CFR 500.109 - CMS.

Code of Federal Regulations, 2010 CFR

2010-04-01

.... Congestion management means the application of strategies to improve system performance and reliability by... SYSTEMS Management Systems § 500.109 CMS. (a) For purposes of this part, congestion means the level at... management system or process is a systematic and regionally accepted approach for managing congestion that...

23 CFR 500.109 - CMS.

Code of Federal Regulations, 2013 CFR

2013-04-01

... SYSTEMS Management Systems § 500.109 CMS. (a) For purposes of this part, congestion means the level at.... Congestion management means the application of strategies to improve system performance and reliability by... management system or process is a systematic and regionally accepted approach for managing congestion that...

23 CFR 500.109 - CMS.

Code of Federal Regulations, 2014 CFR

2014-04-01

... SYSTEMS Management Systems § 500.109 CMS. (a) For purposes of this part, congestion means the level at.... Congestion management means the application of strategies to improve system performance and reliability by... management system or process is a systematic and regionally accepted approach for managing congestion that...

23 CFR 500.109 - CMS.

Code of Federal Regulations, 2012 CFR

2012-04-01

... SYSTEMS Management Systems § 500.109 CMS. (a) For purposes of this part, congestion means the level at.... Congestion management means the application of strategies to improve system performance and reliability by... management system or process is a systematic and regionally accepted approach for managing congestion that...

Value of travel-time reliability, part II : a study of tradeoffs between travel reliability, congestion-mitigation strategies and emissions.

DOT National Transportation Integrated Search

2012-09-01

Capacity, demand, and vehicle based emissions reduction strategies are compared for several pollutants employing aggregate US : congestion and vehicle fleet condition data. We find that congestion mitigation does not inevitably lead to reduced emissi...

Statewide planning scenario synthesis : transportation congestion measurement and management.

DOT National Transportation Integrated Search

2005-09-01

This study is a review of current practices in 13 states to: (1) measure traffic congestion and its costs; and (2) manage congestion with programs and techniques that do not involve the building of new highway capacity. In regard to the measures of c...

Impact of traffic congestion on road accidents: a spatial analysis of the M25 motorway in England.

PubMed

Wang, Chao; Quddus, Mohammed A; Ison, Stephen G

2009-07-01

Traffic congestion and road accidents are two external costs of transport and the reduction of their impacts is often one of the primary objectives for transport policy makers. The relationship between traffic congestion and road accidents however is not apparent and less studied. It is speculated that there may be an inverse relationship between traffic congestion and road accidents, and as such this poses a potential dilemma for transport policy makers. This study aims to explore the impact of traffic congestion on the frequency of road accidents using a spatial analysis approach, while controlling for other relevant factors that may affect road accidents. The M25 London orbital motorway, divided into 70 segments, was chosen to conduct this study and relevant data on road accidents, traffic and road characteristics were collected. A robust technique has been developed to map M25 accidents onto its segments. Since existing studies have often used a proxy to measure the level of congestion, this study has employed a precise congestion measurement. A series of Poisson based non-spatial (such as Poisson-lognormal and Poisson-gamma) and spatial (Poisson-lognormal with conditional autoregressive priors) models have been used to account for the effects of both heterogeneity and spatial correlation. The results suggest that traffic congestion has little or no impact on the frequency of road accidents on the M25 motorway. All other relevant factors have provided results consistent with existing studies.

Substance P contributes to rapidly adapting receptor responses to pulmonary venous congestion in rabbits.

PubMed

Bonham, A C; Kott, K S; Ravi, K; Kappagoda, C T; Joad, J P

1996-05-15

1. This study tested the hypothesis that substance P stimulates rapidly adapting receptors (RARs), contributes to the increase in RAR activity produced by mild pulmonary congestion, and evokes an augmented response from RARs when combined with near-threshold levels of pulmonary congestion. 2. RAR activity, peak tracheal pressure, arterial blood pressure and left atrial pressure were measured in paralysed, anaesthetized and ventilated rabbits. Substance P was given i.v. in one-half log incremental doses to a maximum of 3 micrograms kg-1. Mild pulmonary congestion was produced by inflating a balloon in the left atrium to increase left atrial pressure by 5 mmHg. Near-threshold levels of pulmonary congestion were produced by increasing left atrial pressure by 2 mmHg. 3. Substance P produced dose-dependent increases in RAR activity. The highest dose given increased the activity from 1.3 +/- 0.5 to 11.0 +/- 3.1 impulses bin-1. Increases in left atrial pressure of 5 mmHg increased RAR activity from 3.8 +/- 1.4 to 14.7 +/- 3.9 impulses bin-1. Blockade of NK1 receptors with CP 96345 significantly attenuated RAR responses to substance P and to mild pulmonary congestion. 4. Doses of substance P, which alone had no effect, stimulated the RARs when delivered during near-threshold levels of pulmonary congestion. 5. The findings suggest that substance P augments the stimulatory effect of mild pulmonary congestion on RAR activity, most probably by enhancing hydraulically induced microvascular leak.

76 FR 34848 - Drawbridge Operation Regulation; Atlantic Intracoastal Waterway (AIWW), Elizabeth River, Southern...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-15

... until December 20, 2013, relieving vehicular traffic congestion during the weekday and weekend daytime... final temporary could result in additional vehicular traffic congestion without providing any additional... anticipates continued vehicular traffic congestion over the Gilmerton Highway Bridge due to the reduction of...

Alternative Fuels Data Center: Deploying Alternative Fuel Vehicles and

Science.gov Websites

Infrastructure in Chicago, Illinois, Through the Congestion Mitigation and Air Quality Improvement Program and Infrastructure in Chicago, Illinois, Through the Congestion Mitigation and Air Quality Vehicles and Infrastructure in Chicago, Illinois, Through the Congestion Mitigation and Air Quality

Increased thermohaline stratification as a possible cause for an ocean anoxic event in the Cretaceous period.

PubMed

Erbacher, J; Huber, B T; Norris, R D; Markey, M

2001-01-18

Ocean anoxic events were periods of high carbon burial that led to drawdown of atmospheric carbon dioxide, lowering of bottom-water oxygen concentrations and, in many cases, significant biological extinction. Most ocean anoxic events are thought to be caused by high productivity and export of carbon from surface waters which is then preserved in organic-rich sediments, known as black shales. But the factors that triggered some of these events remain uncertain. Here we present stable isotope data from a mid-Cretaceous ocean anoxic event that occurred 112 Myr ago, and that point to increased thermohaline stratification as the probable cause. Ocean anoxic event 1b is associated with an increase in surface-water temperatures and runoff that led to decreased bottom-water formation and elevated carbon burial in the restricted basins of the western Tethys and North Atlantic. This event is in many ways similar to that which led to the more recent Plio-Pleistocene Mediterranean sapropels, but the greater geographical extent and longer duration (approximately 46 kyr) of ocean anoxic event 1b suggest that processes leading to such ocean anoxic events in the North Atlantic and western Tethys were able to act over a much larger region, and sequester far more carbon, than any of the Quaternary sapropels.

Effect of air humidity on the removal of carbon tetrachloride from air using Cu-BTC metal-organic framework.

PubMed

Martín-Calvo, Ana; García-Pérez, Elena; García-Sánchez, Almudena; Bueno-Pérez, Rocío; Hamad, Said; Calero, Sofia

2011-06-21

We have used interatomic potential-based simulations to study the removal of carbon tetrachloride from air at 298 K, using Cu-BTC metal organic framework. We have developed new sets of Lennard-Jones parameters that accurately describe the vapour-liquid equilibrium curves of carbon tetrachloride and the main components from air (oxygen, nitrogen, and argon). Using these parameters we performed Monte Carlo simulations for the following systems: (a) single component adsorption of carbon tetrachloride, oxygen, nitrogen, and argon molecules, (b) binary Ar/CCl(4), O(2)/CCl(4), and N(2)/CCl(4) mixtures with bulk gas compositions 99 : 1 and 99.9 : 0.1, (c) ternary O(2)/N(2)/Ar mixtures with both, equimolar and 21 : 78 : 1 bulk gas composition, (d) quaternary mixture formed by 0.1% of CCl(4) pollutant, 20.979% O(2), 77.922% N(2), and 0.999% Ar, and (e) five-component mixtures corresponding to 0.1% of CCl(4) pollutant in air with relative humidity ranging from 0 to 100%. The carbon tetrachloride adsorption selectivity and the self-diffusivity and preferential sitting of the different molecules in the structure are studied for all the systems.

Environmental dynamics and carbon accumulation rate of a tropical peatland in Central Sumatra, Indonesia

NASA Astrophysics Data System (ADS)

Hapsari, Kartika Anggi; Biagioni, Siria; Jennerjahn, Tim C.; Reimer, Peter Meyer; Saad, Asmadi; Achnopha, Yudhi; Sabiham, Supiandi; Behling, Hermann

2017-08-01

Tropical peatlands are important for the global carbon cycle as they store 18% of the total global peat carbon. As they are vulnerable to changes in temperature and precipitation, a rapidly changing environment endangers peatlands and their carbon storage potential. Understanding the mechanisms of peatland carbon accumulation from studying past developments may, therefore, help to assess the future role of tropical peatlands. Using a multi-proxy palaeoecological approach, a peat core taken from the Sungai Buluh peatland in Central Sumatra has been analyzed for its pollen and spore, macro charcoal and biogeochemical composition. The result suggests that peat and C accumulation rates were driven mainly by sea level change, river water level, climatic variability and anthropogenic activities. It is also suggested that peat C accumulation in Sungai Buluh is correlated to the abundance of Freycinetia, Myrtaceae, Calophyllum, Stemonuraceae, Ficus and Euphorbiaceae. Sungai Buluh has reasonable potential for being a future global tropical peat C sinks. However, considering the impact of rapid global climate change in addition to land-use change following rapid economic growth in Indonesia, such potential may be lost. Taking advantage of available palaeoecological records and advances made in Quaternary studies, some considerations for management practice such as identification of priority taxa and conservation sites are suggested.

Electrochemical membrane incinerator

DOEpatents

Johnson, Dennis C.; Houk, Linda L.; Feng, Jianren

2001-03-20

Electrochemical incineration of p-benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 .mu.g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called "supporting electrolyte" was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.

The adjuvant activity of aliphatic nitrogenous bases

PubMed Central

Gall, D.

1966-01-01

By the use of diphtheria toxoid in guinea-pigs, high adjuvant activity has been found in a number of aliphatic nitrogenous bases including amines, quaternary ammonium compounds, guanidines, benzamidines and thiouroniums. Activity appears to depend on a combination of basicity and a long aliphatic chain of twelve or more carbon atoms. Such adjuvants tend to be haemolytic, and cause damage to tissue culture monolayers. It is suggested that their activity is connected with their surface activity and hence their ability to alter cell membranes, but that the basicity plays a further as yet undetermined role. ImagesFIG. 1-2FIG. 3-4 PMID:5924622

Hydrology of carbonate aquifers in southwestern Linn County and adjacent parts of Benton, Iowa, and Johnson Counties, Iowa

USGS Publications Warehouse

Wahl, Kenneth; Bunker, Bill J.

1986-01-01

Water analyses from the Devonian and Silurian aquifers indicate that they are of similar chemical quality at most locations in the study area. However, they may commonly contain concentrations of sulfate that exceed 1,000 mil grams per liter. Dissolved-solids concentrations as much as 2,350 milligrams per liter occur in the Silurian aquifer in the western and southwestern part of the study area. Water from the Quaternary aquifer generally is suitable for most uses and dissolved-solids concentrations generally are less than 750 milligrams per liter.

Thermally stable surfactants and compositions and methods of use thereof

DOEpatents

Chaiko, David J [Woodridge, IL

2008-09-02

There are provided novel thermally stable surfactants for use with fillers in the preparation of polymer composites and nanocomposites. Typically, surfactants of the invention are urethanes, ureas or esters of thiocarbamic acid having a hydrocarbyl group of from 10 to 50 carbons and optionally including an ionizable or charged group (e.g., carboxyl group or quaternary amine). Thus, there are provided surfactants having Formula I: ##STR00001## wherein the variables are as defined herein. Further provided are methods of making thermally stable surfactants and compositions, including composites and nanocomposites, using fillers coated with the surfactants.

MOF-253-Pd(OAc) 2 : a recyclable MOF for transition-metal catalysis in water

DOE PAGES

Van Zeeland, Ryan; Li, Xinle; Huang, Wenyu; ...

2016-06-06

We report palladium(II)-functionalized MOF-253 (MOF-253-Pd(OAc) 2) as a recyclable catalyst to form all-carbon quaternary centers via conjugate additions of arylboronic acids to β,β-disubstituted enones in aqueous media. We demonstrate MOF-253-Pd(OAc) 2 can be reused 8 times to form ketone products in yields above 75% while maintaining its crystallinity. Additions of a range of stereoelectronically diverse arylboronic acids to a variety of β,β-disubstituted enones catalyzed by MOF-253-Pd(OAc) 2 occur in modest-to-high yields (34–95%).

Chronology of Quaternary coastal aeolianite deposition and the drowned shorelines of southwestern Western Australia - a reappraisal

NASA Astrophysics Data System (ADS)

Brooke, B. P.; Olley, J. M.; Pietsch, T.; Playford, P. E.; Haines, P. W.; Murray-Wallace, C. V.; Woodroffe, C. D.

2014-06-01

Aeolianite successions of low-gradient continental margins commonly show complex records of coastal dune deposition linked to a wide range of sea-level positions and climatic periods of the middle and late Pleistocene, recording both regional and broader-scale drivers of sediment production, coastal dune development and landform preservation. To better characterise the general pattern of sedimentation that occurs over Quaternary glacial-interglacial cycles on low-gradient, temperate carbonate continental shelves we examine the morphology, stratigraphy and age of aeolianite deposits in the Perth region, Western Australia. This includes an analysis of well-defined drowned coastal landforms preserved on the adjacent shelf. New and previously published optical ages provide a preliminary timeframe for the deposition of aeolianite in the Perth region and on Rottnest Island, 17 km offshore. An extensive aeolianite ridge near Perth, representing a former barrier, has Optically Stimulated Luminesence (OSL) ages that range from 120 ± 12 to 103 ± 10 ka (MIS 5e-5a in the context of associated age uncertainties). OSL ages for an exposure in the same ridge 2.5 km inland, record the onlap of much older aeolianite, OSL age 415 ± 70 ka, by shell-rich estuarine beds, OSL age 290 ± 30 ka. A further 5.5 km inland from the coast, two thick aeolianite units, separated by a well-developed palaeosol, have stratigraphically consistent OSL ages of 310 ± 30 and 155 ± 20 ka. In contrast, aeolianite units that form the northern coast of Rottnest Island have OSL ages of 77 ± 12 ka and 27 ± 5 ka. The new OSL ages and previously reported TL and U/Th ages indicate that the bulk of the island comprises dunes deposited around the end of the Last Interglacial sensu lato (MIS 5a-4) and during the Last Glacial (MIS 4-2), accumulating over a Last Interglacial coral reef and basal calcarenite. Drowned barrier and dune landforms preserved on the adjacent continental shelf reveal that barriers were formed during periods of intermediate sea level (e.g. MIS 3) and significant dune mobility occurred when the shelf was subaerially exposed. The pattern of shelf sedimentation discernible in the Perth region - large-scale coastal carbonate dune deposition during periods of high and intermediate sea level and reactivation during glacial lowstands - is largely consistent with published stratigraphic and age data for large-scale aeolianite deposits on other low-gradient carbonate shelves. Based on these data, a general model is proposed for the cycle of Quaternary sedimentation and landform evolution that occurs on these shelves, which are dynamic sedimentary environments with coastal landforms and sedimentary successions that are very sensitive to erosion and sediment reworking.

Urban partnership agreement and congestion reduction demonstration programs : lessons learned on congestion pricing from the Seattle and Atlanta household travel behavior surveys.

DOT National Transportation Integrated Search

2014-04-01

This paper presents lessons learned from household traveler surveys administered in Seattle and Atlanta as part of the evaluation of the Urban Partnership Agreement and Congestion Reduction Demonstration Programs. The surveys use a two-stage panel su...

23 CFR 970.214 - Federal lands congestion management system (CMS).

Code of Federal Regulations, 2011 CFR

2011-04-01

... experiencing congestion, the NPS shall develop a separate CMS to cover those facilities. Approaches may include... congestion management strategies; (v) Determine methods to monitor and evaluate the performance of the multi... means the level at which transportation system performance is no longer acceptable due to traffic...

23 CFR 970.214 - Federal lands congestion management system (CMS).

Code of Federal Regulations, 2010 CFR

2010-04-01

... experiencing congestion, the NPS shall develop a separate CMS to cover those facilities. Approaches may include... congestion management strategies; (v) Determine methods to monitor and evaluate the performance of the multi... means the level at which transportation system performance is no longer acceptable due to traffic...

23 CFR 973.214 - Indian lands congestion management system (CMS).

Code of Federal Regulations, 2014 CFR

2014-04-01

... 23 Highways 1 2014-04-01 2014-04-01 false Indian lands congestion management system (CMS). 973.214... HIGHWAYS MANAGEMENT SYSTEMS PERTAINING TO THE BUREAU OF INDIAN AFFAIRS AND THE INDIAN RESERVATION ROADS PROGRAM Bureau of Indian Affairs Management Systems § 973.214 Indian lands congestion management system...

Feasibility of incorporating crash risk in developing congestion mitigation measures for interstate highways : a case study of the Hampton Roads area.

DOT National Transportation Integrated Search

2002-01-01

A relationship between traffic flow variables and crash characteristics can greatly help the traffic engineer in the field to arrive at appropriate congestion mitigation measures that not only alleviate congestion and save time but also reduce the pr...

14 CFR 137.49 - Operations over other than congested areas.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Operations over other than congested areas. 137.49 Section 137.49 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF... congested areas below 500 feet above the surface and closer than 500 feet to persons, vessels, vehicles, and...

76 FR 70122 - Plan for Conduct of 2012 Electric Transmission Congestion Study

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-10

... preparations for the 2012 Congestion Study, and seeks comments on what publicly-available data and information...), and Microsoft PowerPoint (.ppt). The Department intends to use only data that is publicly available... Study, the Department gathered historical congestion data obtained from existing studies prepared by...

Quantum random walks on congested lattices and the effect of dephasing.

PubMed

Motes, Keith R; Gilchrist, Alexei; Rohde, Peter P

2016-01-27

We consider quantum random walks on congested lattices and contrast them to classical random walks. Congestion is modelled on lattices that contain static defects which reverse the walker's direction. We implement a dephasing process after each step which allows us to smoothly interpolate between classical and quantum random walks as well as study the effect of dephasing on the quantum walk. Our key results show that a quantum walker escapes a finite boundary dramatically faster than a classical walker and that this advantage remains in the presence of heavily congested lattices.

Integrative Assessment of Congestion in Heart Failure Throughout the Patient Journey.

PubMed

Girerd, Nicolas; Seronde, Marie-France; Coiro, Stefano; Chouihed, Tahar; Bilbault, Pascal; Braun, François; Kenizou, David; Maillier, Bruno; Nazeyrollas, Pierre; Roul, Gérard; Fillieux, Ludivine; Abraham, William T; Januzzi, James; Sebbag, Laurent; Zannad, Faiez; Mebazaa, Alexandre; Rossignol, Patrick

2018-04-01

Congestion is one of the main predictors of poor patient outcome in patients with heart failure. However, congestion is difficult to assess, especially when symptoms are mild. Although numerous clinical scores, imaging tools, and biological tests are available to assist physicians in ascertaining and quantifying congestion, not all are appropriate for use in all stages of patient management. In recent years, multidisciplinary management in the community has become increasingly important to prevent heart failure hospitalizations. Electronic alert systems and communication platforms are emerging that could be used to facilitate patient home monitoring that identifies congestion from heart failure decompensation at an earlier stage. This paper describes the role of congestion detection methods at key stages of patient care: pre-admission, admission to the emergency department, in-hospital management, and lastly, discharge and continued monitoring in the community. The multidisciplinary working group, which consisted of cardiologists, emergency physicians, and a nephrologist with both clinical and research backgrounds, reviewed the current literature regarding the various scores, tools, and tests to detect and quantify congestion. This paper describes the role of each tool at key stages of patient care and discusses the advantages of telemedicine as a means of providing true integrated patient care. Copyright © 2018. Published by Elsevier Inc.

Does rush hour see a rush of emotions? Driver mood in conditions likely to exhibit congestion

PubMed Central

Morris, Eric A; Hirsch, Jana A.

2016-01-01

Polls show that a large portion of the public considers traffic congestion to be a problem and believes a number of policy interventions would ameliorate it. However, most of the public rejects new taxes and fees to fund these improvements. This may be because of a disconnect between the public's stated antipathy towards congestion and the recalled emotional costs congestion imposes. To explore this, we use a large and representative sample drawn from the American Time Use Survey to examine how drivers experience four emotions (happiness, sadness, stress, and fatigue), plus a constructed composite mood variable, when they travel in peak periods, in large cities, in city centers, and in combinations of these. We also explore the interactions between these indicators and trip duration. We find evidence that drivers in the largest cities at the very peak of rush hour (5:00pm-6:00pm) are in a less positive mood, presumably because of congestion. However, this effect, though significant, is small, and we find no significant results using broader definitions of the peak period. In all, our findings suggest that congestion's impact on drivers as a group is quite limited. This may help explain why the public's attitude toward painful financial trade-offs to address congestion is lukewarm. PMID:27231669

Frame Transmission Efficiency-Based Cross-Layer Congestion Notification Scheme in Wireless Ad Hoc Networks.

PubMed

He, Huaguang; Li, Taoshen; Feng, Luting; Ye, Jin

2017-07-15

Different from the traditional wired network, the fundamental cause of transmission congestion in wireless ad hoc networks is medium contention. How to utilize the congestion state from the MAC (Media Access Control) layer to adjust the transmission rate is core work for transport protocol design. However, recent works have shown that the existing cross-layer congestion detection solutions are too complex to be deployed or not able to characterize the congestion accurately. We first propose a new congestion metric called frame transmission efficiency (i.e., the ratio of successful transmission delay to the frame service delay), which describes the medium contention in a fast and accurate manner. We further present the design and implementation of RECN (ECN and the ratio of successful transmission delay to the frame service delay in the MAC layer, namely, the frame transmission efficiency), a general supporting scheme that adjusts the transport sending rate through a standard ECN (Explicit Congestion Notification) signaling method. Our method can be deployed on commodity switches with small firmware updates, while making no modification on end hosts. We integrate RECN transparently (i.e., without modification) with TCP on NS2 simulation. The experimental results show that RECN remarkably improves network goodput across multiple concurrent TCP flows.

Evaluation of the public health impacts of traffic congestion: a health risk assessment

PubMed Central

2010-01-01

Background Traffic congestion is a significant issue in urban areas in the United States and around the world. Previous analyses have estimated the economic costs of congestion, related to fuel and time wasted, but few have quantified the public health impacts or determined how these impacts compare in magnitude to the economic costs. Moreover, the relative magnitudes of economic and public health impacts of congestion would be expected to vary significantly across urban areas, as a function of road infrastructure, population density, and atmospheric conditions influencing pollutant formation, but this variability has not been explored. Methods In this study, we evaluate the public health impacts of ambient exposures to fine particulate matter (PM2.5) concentrations associated with a business-as-usual scenario of predicted traffic congestion. We evaluate 83 individual urban areas using traffic demand models to estimate the degree of congestion in each area from 2000 to 2030. We link traffic volume and speed data with the MOBILE6 model to characterize emissions of PM2.5 and particle precursors attributable to congestion, and we use a source-receptor matrix to evaluate the impact of these emissions on ambient PM2.5 concentrations. Marginal concentration changes are related to a concentration-response function for mortality, with a value of statistical life approach used to monetize the impacts. Results We estimate that the monetized value of PM2.5-related mortality attributable to congestion in these 83 cities in 2000 was approximately $31 billion (2007 dollars), as compared with a value of time and fuel wasted of $60 billion. In future years, the economic impacts grow (to over $100 billion in 2030) while the public health impacts decrease to $13 billion in 2020 before increasing to $17 billion in 2030, given increasing population and congestion but lower emissions per vehicle. Across cities and years, the public health impacts range from more than an order of magnitude less to in excess of the economic impacts. Conclusions Our analyses indicate that the public health impacts of congestion may be significant enough in magnitude, at least in some urban areas, to be considered in future evaluations of the benefits of policies to mitigate congestion. PMID:20979626

Late Quaternary faulting in the Cabo San Lucas-La Paz Region, Baja California

NASA Astrophysics Data System (ADS)

Busch, M.; Arrowsmith, J. R.; Umhoefer, P. J.; Gutiérrez, G. M.; Toke, N.; Brothers, D.; Dimaggio, E.; Maloney, S.; Zielke, O.; Buchanan, B.

2006-12-01

While Baja California drifts, active deformation on and just offshore indicates that spreading is not completely localized to the rift axis in the Gulf of California. Using on and offshore data, we characterize normal faulting- related deformation in the Cabo San Lucas-La Paz area. We mapped sections of the north trending faults in a 150 km long left-stepping fault array. Starting in the south, the San Jose del Cabo fault (east dipping) bounds the ~2 km high Sierra La Laguna. It is >70 km long with well defined 1-10 meter fault scarps cutting the youngest late Quaternary geomorphic surfaces. Our preliminary mapping along the north central section exhibits extensive late Quaternary terraces with riser heights of tens of meters above Holocene terraces. The San Jose del Cabo fault trace becomes diffuse and terminates in the area of Los Barriles. Moving northward, the fault system steps to the west, apparently transferring slip to the faults of San Juan de Los Planes and Saltito, which then step left again across the La Paz basin to the NNW trending Carrizal Fault. It has an on shore length of > 60 km. We produced a 25 km detailed strip map along the northern segment. It is embayed by convex east arcs several km long and 100 m deep. In the south, few-m-high scarps cut a pediment of thin Quaternary cover over tertiary volcanic rocks. The escarpment along the fault is hundreds of meters high and scarps 1-10 m high where it goes offshore in the north. Near Bonfil, a quarry cut exposes the fault zone. It comprises a 5-10 m wide bedrock shear zone with sheared tertiary volcanic units. On the footwall, the lower silty and sandy units have moderately well developed pedogenic carbonate, whereas the upper coarse gravel does not. These late Quaternary units appear to be faulted by one to three earthquakes. Finally, we mapped the Saltito fault zone NNE of La Paz. It is a NW trending structure with well developed 5- 10 meter high bedrock scarps defining its NW 5 km and slightly concave east with a 500 m left. Along all the fault zones studied, offset geomorphic surfaces indicate late Pleistocene to Holocene offset. These surfaces can be exploited to determine slip rates and produce a regional chronosequence to test for synchroneity of climatically modulated variations in sediment supply and transport capacity. In addition, a shallow marine geophysics and coring extends our mapping and provides important age control and improved stratigraphic assessment of fault activity.

Comparison of GPS and Quaternary slip rates: Insights from a new Quaternary fault database for Central Asia

NASA Astrophysics Data System (ADS)

Mohadjer, Solmaz; Ehlers, Todd; Bendick, Rebecca; Mutz, Sebastian

2016-04-01

Previous studies related to the kinematics of deformation within the India-Asia collision zone have relied on slip rate data for major active faults to test kinematic models that explain the deformation of the region. The slip rate data, however, are generally disputed for many of the first-order faults in the region (e.g., Altyn Tagh and Karakorum faults). Several studies have also challenged the common assumption that geodetic slip rates are representative of Quaternary slip rates. What has received little attention is the degree to which geodetic slip rates relate to Quaternary slip rates for active faults in the India-Asia collision zone. In this study, we utilize slip rate data from a new Quaternary fault database for Central Asia to determine the overall relationship between Quaternary and GPS-derived slip rates for 18 faults. The preliminary analysis investigating this relationship uses weighted least squares and a re-sampling analysis to test the sensitivity of this relationship to different data point attributes (e.g., faults associated with data points and dating methods used for estimating Quaternary slip rates). The resulting sample subsets of data points yield a maximum possible Pearson correlation coefficient of ~0.6, suggesting moderate correlation between Quaternary and GPS-derived slip rates for some faults (e.g., Kunlun and Longmen Shan faults). Faults with poorly correlated Quaternary and GPS-derived slip rates were identified and dating methods used for the Quaternary slip rates were examined. Results indicate that a poor correlation between Quaternary and GPS-derived slip rates exist for the Karakorum and Chaman faults. Large differences between Quaternary and GPS slip rates for these faults appear to be connected to qualitative dating of landforms used in the estimation of the Quaternary slip rates and errors in the geomorphic and structural reconstruction of offset landforms (e.g., offset terrace riser reconstructions for Altyn Tagh fault). Other factors such as a low density in the GPS network (e.g., GPS rate based on data from a single station for the Karakorum fault) appear to also contribute to the mismatch observed between the slip rates. Taken together, these results suggest that GPS-derived slip rates are often (but not always) representative of Quaternary slip rates and that the dating methods and sampling approaches used to identify transients in a fault slip rate history should be heavily scrutinized before interpreting the seismic hazards for a region.

Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C-H Functionalizations.

PubMed

Bedell, T Aaron; Hone, Graham A B; Valette, Damien; Yu, Jin-Quan; Davies, Huw M L; Sorensen, Erik J

2016-07-11

Methods for functionalizing carbon-hydrogen bonds are featured in a new synthesis of the tricyclic core architecture that characterizes the indoxamycin family of secondary metabolites. A unique collaboration between three laboratories has engendered a design for synthesis featuring two sequential C-H functionalization reactions, namely a diastereoselective dirhodium carbene insertion followed by an ester-directed oxidative Heck cyclization, to rapidly assemble the congested tricyclic core of the indoxamycins. This project exemplifies how multi-laboratory collaborations can foster conceptually novel approaches to challenging problems in chemical synthesis. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Reconnaissance geology, mineral occurrences, and geochemical anomalies of the Yentna district, Alaska

USGS Publications Warehouse

Clark, Allen L.; Hawley, C.C.

1968-01-01

The Yentna district, in south-central Alaska, is underlain by slightly metamorphosed Mesozoic sedimentary rocks, and by sandstones, conglomerates and coaly minerals of the Tertiary Kenai Formation. The bedrock is locally covered by extensive surficial deposits of Quaternary and Recent (Holocene) age. The Mesozoic strata are cut by a quartz monzonite batholith in the Tokositna Mountains and by alaskitic dikes and plugs in the Peters and Dutch Hills. A silica-carbonate dike, which formed by alteration of a mafic or ultramafic dike, was noted in the Peters Hills. The major ore deposits are gold placer deposits of several types, including stream and bench deposits of Recent (Holocene) age, glacial-fluviatile deposits of Quaternary age, and conglomerates of Tertiary age. Quartz-rich conglomerates and breccias have also been productive and are interesting and controversial genetically. The present study indicates that they are closely related to shear zones containing quartz veins and highly altered rocks; previously the origin of the associated altered rocks had been ascribed to deep weathering. The report also contains descriptions of a few gold lode prospects and of geochemically anomalous areas such as those at Bunco Creek and near Mount Goldie.

Synthesis of Quaternary Ammonium Salts Based on Diketopyrrolopyrroles Skeletons and Their Applications in Copper Electroplating.

PubMed

Chen, Biao; Xu, Jie; Wang, Limin; Song, Longfeng; Wu, Shengying

2017-03-01

A series of DPP derivatives bearing quaternary ammonium salt centers with different lengths of carbon chains have been designed and synthesized. Their inhibition actions on copper electroplating were first investigated. A total of four diketopyrrolopyrrole (DPP) derivatives showed different inhibition capabilities on copper electroplating. To investigate interactions between metal surface and additives, we used quantum chemical calculations. Static and dynamic surface tension of four DPP derivatives had been measured, and the results showed DPP-10C (1c) with a faster-decreasing rate of dynamic surface tension among the four derivatives, which indicated higher adsorption rate of additive on the cathode surface and gives rise to stronger inhibiting effect of copper electrodeposition. Then, DPP-10C (1c) as the representative additive, was selected for the systematic study of the leveling influence during microvia filling through comprehensive electroplating tests. In addition, field-emission scanning electron microscope images and X-ray diffraction results showed the surface morphology, which indicated that addition of DPP derivative (1c) could lead a fine copper deposit and cause the preferential orientations of copper deposits to change from [220] to [111], which happened in particular at higher concentrations.

Development of Ternary and Quaternary Catalysts for the Electrooxidation of Glycerol

PubMed Central

Artem, L. M.; Santos, D. M.; De Andrade, A. R.; Kokoh, K. B.; Ribeiro, J.

2012-01-01

This work consisted in the preparation of platinum-based catalysts supported on carbon (Vulcan XC-72) and investigation of their physicochemical and electrochemical properties. Catalysts of the C/Pt-Ni-Sn-Me (Me = Ru or Ir) type were prepared by the Pechini method at temperature of 350°C. Four different compositions were homemade: C/Pt60Sn10Ni30, C/Pt60Sn10Ni20Ru10, C/Pt60Sn10Ni10Ru20, and C/Pt60Sn10Ni10Ir20. These catalysts were electrochemically and physically characterized by cyclic voltammetry (CV), chronoamperometry (CA) in the presence of glycerol 1.0 mol dm−3, X-ray diffraction (XRD), and high-resolution transmission electron microscopy (HRTEM). XRD results showed the main peaks of face-centered cubic Pt. The particle sizes obtained from XRD and HRTEM experiments were close to values ranging from 3 to 8.5 nm. The CV results indicate behavior typical of Pt-based catalysts in acid medium. The CV and CA data reveal that quaternary catalysts present the highest current density for the electrooxidation of glycerol. PMID:22623905

Tufa and travertine of the Lesser Caucasus: a light on the Quaternary palaeoenvironment of the Circumcaspian regions

NASA Astrophysics Data System (ADS)

Ollivier, V.; Roiron, P.; Nahapetyan, S.; Joannin, S.; Chataigner, C.

2012-04-01

In the course of the International Associated Laboratory HEMHA (Humans and Environment in Mountainous Habitats : the case of Armenia), the French Foreign Affair Ministry Caucasus Mission (CNRS-UMR 5133 Archéorient, Lyon University) and the French-German research program Ancient Kura (CNRS-UMR 7192 PrOCauLAC, Paris, France, Deutsches Archäologisches Institut, Eurasien-Abteilung, Berlin, Germany with ANR-CNRS and DFG funding) numerous sites of the Lesser Caucasus territory are under geomorphological, palaeoenvironmental and archaeological investigations. Through comparisons between the tufa/travertine system and the detrital formation morphosedimentary evolution, one of our research interests is to define the Late Quaternary landscape mutations as well as the origin and rhythmicity of the major morphogenic trends reversals. The impacts of the environmental changes highlighted on the human occupation modes are also debated. A total of 14 travertine and tufa formations were studied (8 Pleistocene and 6 Postglacial formations) on a Northwest-Southeast transect of more than 300 km across the Lesser Caucasus. Each of these carbonated system development are correlated with high global relative sea levels and interstadial climates on a range between the Marine Isotopic Stage 11 and 1 (ca. 335 to 1.5 Ky BP). The absolute chronology is constrained by a series of U/Th and 14C dating. A total of 24 dating was performed (6 radiocarbon and 18 U/Th datings), allowing a high quality overview of the travertinization process over the time at a regional scale. Jointly with the measurement of the late Quaternary interglacial series impact on the tufas development in the Caucasus, the geomorphological position of some travertinous formations and their absolute dating gives some clues about the neotectonic evolution of the studied valleys. In some area, the uplift rate has been determined (ca. 8 mm/year) and discretized from the alluvial incision signal. The analysis of the carbonated deposits (faciological determinations, palaeobotanical and palynological identifications of leave imprints and pollens), which are the expression of specific climatic conditions, and the comparative approach with the general morphosedimentary evolution, give a complete reading grid of the regional landscape mutation expressions and origins (Caspian Sea eustatism or exclusive climatic impact), necessary to understand the magnitude of the changes and their influence on the Circumcaspian societies.

Quaternary Deformation of Sumba, Indonesia: Evidence from Carbonate Terraces

NASA Astrophysics Data System (ADS)

Dahlquist, M. P.; West, A. J.; Dolan, J. F.

2014-12-01

The Banda Arc of Indonesia remains one of the least understood tectonic domains on the modern Earth. The island of Sumba, located approximately 50 km south of Flores and 120 km north of the Java Trench, northwest of where it transitions into the Timor Trough, lies in a region of tectonic transition and potentially offers insights into regional dynamics. The Banda Arc is volcanically active, but Sumba itself is not volcanic. The northern coast of Sumba is covered in Quaternary coral terraces, with the rest of the island's surface geology composed of Mio-pliocene carbonates and uplifted Late Cretaceous-Oligocene forearc basin and volcanic rocks. The purpose of this study is to remotely map the topographic expression of the coral terraces and use the information gained to better understand deformation on Sumba since their deposition. The ages of the coral terraces, of which many platforms are exposed over significant areas of the island, have been constrained at Cape Luandi in north central Sumba, but uplift rates calculated from those ages may not be representative of the island as a whole. The lateral continuity of these dated terraces can help constrain the extent to which uplift of Sumba is spatially variable. Analysis of the terraces using SRTM digital elevation data with ArcGIS software makes it possible to trace the same terrace platforms over large distances, and shows that the north central part of the island has experienced the most uplift since the deposition of the terraces, forming an anticline with the east limb dipping more steeply than the west. The terraces are not well preserved on the southern half of the island. Exposure of older rocks and lack of terrace preservation, as well as a south-skewed drainage divide suggests the southern half of the island experiences greater exhumation, but this could be driven by climate or other factors and does not necessarily indicate more rapid uplift. Study of Quaternary deformation of Sumba can offer greater understanding of the ongoing collision of the Banda Arc with the Australian continent. A more complete picture of the region may provide insights into seismic hazards as well as the behavior of arc-continent collision systems and active margins in general.

Assessment of the role of micropore size and N-doping in CO2 capture by porous carbons.

PubMed

Sevilla, Marta; Parra, Jose B; Fuertes, Antonio B

2013-07-10

The role of micropore size and N-doping in CO2 capture by microporous carbons has been investigated by analyzing the CO2 adsorption properties of two types of activated carbons with analogous textural properties: (a) N-free carbon microspheres and (b) N-doped carbon microspheres. Both materials exhibit a porosity made up exclusively of micropores ranging in size between <0.6 nm in the case of the pristine materials and up to 1.6 nm for the highly activated carbons (47% burnoff). The N-doped carbons possess ~3 wt % of N heteroatoms that are incorporated into several types of functional groups (i.e., pyrrole/pyridone, pyridine, quaternary, and pyridine-N-oxide). Under conventional operation conditions (i.e., T ~ 0-25 °C and P(CO2) ~ 0-1 bar), CO2 adsorption proceeds via a volume-filling mechanism, the size limit for volume-filling being ~0.7-0.8 nm. Under these circumstances, the adsorption of CO2 by nonfunctionalized porous carbons is mainly determined by the volume of the micropores with a size below 0.8 nm. It was also observed that the CO2 capture capacities of undoped and N-doped carbons are analogous which shows that the nitrogen functionalities present in these N-doped samples do not influence CO2 adsorption. Taking into account the temperature invariance of the characteristic curve postulated by the Dubinin theory, we show that CO2 uptakes can be accurately predicted by using the adsorption data measured at just one temperature.

Substance P contributes to rapidly adapting receptor responses to pulmonary venous congestion in rabbits.

PubMed Central

Bonham, A C; Kott, K S; Ravi, K; Kappagoda, C T; Joad, J P

1996-01-01

1. This study tested the hypothesis that substance P stimulates rapidly adapting receptors (RARs), contributes to the increase in RAR activity produced by mild pulmonary congestion, and evokes an augmented response from RARs when combined with near-threshold levels of pulmonary congestion. 2. RAR activity, peak tracheal pressure, arterial blood pressure and left atrial pressure were measured in paralysed, anaesthetized and ventilated rabbits. Substance P was given i.v. in one-half log incremental doses to a maximum of 3 micrograms kg-1. Mild pulmonary congestion was produced by inflating a balloon in the left atrium to increase left atrial pressure by 5 mmHg. Near-threshold levels of pulmonary congestion were produced by increasing left atrial pressure by 2 mmHg. 3. Substance P produced dose-dependent increases in RAR activity. The highest dose given increased the activity from 1.3 +/- 0.5 to 11.0 +/- 3.1 impulses bin-1. Increases in left atrial pressure of 5 mmHg increased RAR activity from 3.8 +/- 1.4 to 14.7 +/- 3.9 impulses bin-1. Blockade of NK1 receptors with CP 96345 significantly attenuated RAR responses to substance P and to mild pulmonary congestion. 4. Doses of substance P, which alone had no effect, stimulated the RARs when delivered during near-threshold levels of pulmonary congestion. 5. The findings suggest that substance P augments the stimulatory effect of mild pulmonary congestion on RAR activity, most probably by enhancing hydraulically induced microvascular leak. Images Figure 6 PMID:8735708

75 FR 69906 - Drawbridge Operation Regulation; Atlantic Intracoastal Waterway (AIWW), Elizabeth River, Southern...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-16

... opening periods for the bridge during the day, relieving vehicular traffic congestion during the weekday... the rush hour periods and on the weekends, we anticipate a decrease in vehicular traffic congestion... vehicular traffic congestion over the Gilmerton Highway Bridge due to the reduction of highway lanes and...

Financial and technical feasibility of dynamic congestion pricing as a revenue generation source in Indiana : exploiting the availability of real-time information and dynamic pricing technologies.

DOT National Transportation Integrated Search

2011-10-19

"Highway stakeholders continue to support research studies that address critical issues of the current era, including congestion mitigation and revenue generation. A mechanism that addresses both concerns is congestion pricing which establishes a dir...

Distributive routing and congestion control in wireless multihop ad hoc communication networks

NASA Astrophysics Data System (ADS)

Glauche, Ingmar; Krause, Wolfram; Sollacher, Rudolf; Greiner, Martin

2004-10-01

Due to their inherent complexity, engineered wireless multihop ad hoc communication networks represent a technological challenge. Having no mastering infrastructure the nodes have to selforganize themselves in such a way that for example network connectivity, good data traffic performance and robustness are guaranteed. In this contribution the focus is on routing and congestion control. First, random data traffic along shortest path routes is studied by simulations as well as theoretical modeling. Measures of congestion like end-to-end time delay and relaxation times are given. A scaling law of the average time delay with respect to network size is revealed and found to depend on the underlying network topology. In the second step, a distributive routing and congestion control is proposed. Each node locally propagates its routing cost estimates and information about its congestion state to its neighbors, which then update their respective cost estimates. This allows for a flexible adaptation of end-to-end routes to the overall congestion state of the network. Compared to shortest-path routing, the critical network load is significantly increased.

Congestion and flow control in signaling system no. 7: Impacts of intelligent networks and new services

NASA Astrophysics Data System (ADS)

Zepf, Joachim; Rufa, Gerhard

1994-04-01

This paper focuses on the transient performance analysis of the congestion and flow control mechanisms in CCITT Signaling System No. 7 (SS7). Special attention is directed to the impacts of the introduction of intelligent services and new applications, e.g., Freephone, credit card services, user-to-user signaling, etc. In particular, we show that signaling traffic characteristics like signaling scenarios or signaling message length as well as end-to-end signaling capabilities have a significant influence on the congestion and flow control and, therefore, on the real-time signaling performance. One important result of our performance studies is that if, e.g., intelligent services are introduced, the SS7 congestion and flow control does not work correctly. To solve this problem, some reinvestigations into these mechanisms would be necessary. Therefore, some approaches, e.g., modification of the Signaling Connection Control Part (SCCP) congestion control, usage of the SCCP relay function, or a redesign of the MTP flow control procedures are discussed in order to guarantee the efficacy of the congestion and flow control mechanisms also in the future.

Receiver-Assisted Congestion Control to Achieve High Throughput in Lossy Wireless Networks

NASA Astrophysics Data System (ADS)

Shi, Kai; Shu, Yantai; Yang, Oliver; Luo, Jiarong

2010-04-01

Many applications would require fast data transfer in high-speed wireless networks nowadays. However, due to its conservative congestion control algorithm, Transmission Control Protocol (TCP) cannot effectively utilize the network capacity in lossy wireless networks. In this paper, we propose a receiver-assisted congestion control mechanism (RACC) in which the sender performs loss-based control, while the receiver is performing delay-based control. The receiver measures the network bandwidth based on the packet interarrival interval and uses it to compute a congestion window size deemed appropriate for the sender. After receiving the advertised value feedback from the receiver, the sender then uses the additive increase and multiplicative decrease (AIMD) mechanism to compute the correct congestion window size to be used. By integrating the loss-based and the delay-based congestion controls, our mechanism can mitigate the effect of wireless losses, alleviate the timeout effect, and therefore make better use of network bandwidth. Simulation and experiment results in various scenarios show that our mechanism can outperform conventional TCP in high-speed and lossy wireless environments.

Lignin phenols in sediments of Lake Baikal, Siberia: Application to paleoenvironmental studies

USGS Publications Warehouse

Orem, W.H.; Colman, Steven M.; Lerch, H.E.

1997-01-01

Sediments from three cores obtained from distinct depositional environments in Lake Baikal, Siberia were analyzed for organic carbon, total nitrogen and lignin phenol concentration and composition. Results were used to examine changes in paleoenvironmental conditions during climatic cycles of the late Quaternary (< 125 ka). Average organic carbon, and total nitrogen concentrations, atomic C/N ratios and organic carbon accumulation rates were significantly higher in the Holocene compared with the late Pleistocene, reflecting overall warmer temperatures and increased runoff during the Holocene. A Holocene maximum in organic carbon was observed at about 6 ka, and may represent the warmest wettest period of the Holocene. At one site (Academician Ridge) pronounced late Pleistocene maxima in organic carbon and biogenic silica were observed at about 80-85 ka, probably indicative of an interstadial period with enhanced aquatic productivity. Total sedimentary lignin phenol contents were generally lower in the late Pleistocene compared to the Holocene, but with several peaks in concentration during the late Pleistocene. These late Pleistocene peaks in total sedimentary lignin content (dated at about 80, 50 and 30 ka) directly precede or occur during peaks in sedimentary biogenic silica contents. These periods likely represent relatively warm interstadial times, with increased precipitation producing the observed increase in terrestrial runoff and aquatic productivity. Lignin phenol ratios (S/V, C/V and P/V) were used to examine changes in terrestrial vegetation type resulting from changes in paleoenvironmental conditions during the late Pleistocene. A degree of caution must be used in the interpretation of these ratios with regard to vegetation sources and paleoenvironmental conditions, because of potential compositional changes in lignin resulting from biodegradation. Nevertheless, results show that long glacial periods were characterized by terrestrial vegetation composed of a mix of non-woody angiosperm vegetation and minor gymnosperm forest. Shorter interstadial periods are defined by a change to dominant gymnosperm forest and were observed at about 80, 75, 63, 50 and 30 ka, ranging from about 2-6 kyr in duration. These interstadial periods of the late Pleistocene defined by lignin phenol ratios generally occur during longer periods of enhanced sedimentary biogenic silica content (about 10-15 ka in duration), providing corroborative evidence of these warm interstadial periods.Sediments obtained in Lake Baikal were analyzed for organic carbon, total nitrogen and lignin phenol composition and used to study changes in paleoenvironmental conditions during climatic cycles of the late Quaternary. The organic carbon, total nitrogen concentrations, atomic C/N ratios and organic carbon accumulation rates were higher in the Holocene showing overall warmer temperatures and increased runoff. Total lignin phenol contents were lower in the Pleistocene representing relatively warm interstadial times with increased precipitation, runoff and aquatic productivity. Lignin phenol was used to examine vegetation changes due to paleoenvironmental conditions and showed that long glacial periods were characterized by terrestrial vegetation.

Geological evolution of the Iraqi Mesopotamia Foredeep, inner platform and near surroundings of the Arabian Plate

NASA Astrophysics Data System (ADS)

Sissakian, Varoujan K.

2013-08-01

The Iraqi territory could be divided into four main tectonic zones; each one has its own characteristics concerning type of the rocks, their age, thickness and structural evolution. These four zones are: (1) Inner Platform (stable shelf), (2) Outer Platform (unstable shelf), (3) Shalair Zone (Terrain), and (4) Zagros Suture Zone. The first two zones of the Arabian Plate lack any kind of metamorphism and volcanism. The Iraqi territory is located in the extreme northeastern part of the Arabian Plate, which is colliding with the Eurasian (Iranian) Plate. This collision has developed a foreland basin that includes: (1) Imbricate Zone, (2) High Folded Zone, (3) Low Folded Zone and (4) Mesopotamia Foredeep. The Mesopotamia Foredeep, in Iraq includes the Mesopotamia Plain and the Jazira Plain; it is less tectonically disturbed as compared to the Imbricate, High Folded and Low Folded Zones. Quaternary alluvial sediments of the Tigris and Euphrates Rivers and their tributaries as well as distributaries cover the central and southeastern parts of the Foredeep totally; it is called the Mesopotamian Flood Plain. The extension of the Mesopotamia Plain towards northwest however, is called the Jazira Plain, which is covered by Miocene rocks. The Mesopotamia Foredeep is represented by thick sedimentary sequence, which thickens northwestwards including synrift sediments; especially of Late Cretaceous age, whereas on surface the Quaternary sediments thicken southeastwards. The depth of the basement also changes from 8 km, in the west to 14 km, in the Iraqi-Iranian boarders towards southeast. The anticlinal structures have N-S trend, in the extreme southern part of the Mesopotamia Foredeep and extends northwards until the Latitude 32°N, within the Jazira Plain, there they change their trends to NW-SE, and then to E-W trend. The Mesozoic sequence is almost without any significant break, with increase in thickness from the west to the east, attaining 5 km. The sequence forms the main source and reservoir rocks in the central and southern parts of Iraq. The Cenozoic sequence consists of Paleogene open marine carbonates, which grades upwards into Neogene lagoonal marine; of Early Miocene and evaporitic rocks; of Middle Miocene age, followed by thick molasses of continental clastics that attain 3500 m in thickness; starting from Late Miocene. The Quaternary sediments are very well developed in the Mesopotamia Plain and they thicken southwards to reach about 180 m near Basra city; in the extreme southeastern part of Iraq. The Iraqi Inner Platform (stable shelf) is a part of the Arabian Plate, being less affected by tectonic disturbances; it covers the area due to south and west of the Euphrates River. The main tectonic feature in this zone that had affected on the geology of the area is the Rutbah Uplift; with less extent is the Ga'ara High. The oldest exposed rocks within the Inner Platform belong to Ga'ara Formation of Permian age; it is exposed only in the Ga'ara Depression. The Permian rocks are overlain by Late Triassic rocks; represented by Mulussa and Zor Hauran formations, both of marine carbonates with marl intercalations. The whole Triassic rocks are absent west, north and east of Ga'ara Depression. Jurassic rocks, represented by five sedimentary cycles, overlie the Triassic rocks. Each cycle consists of clastic rocks overlain by carbonates, being all of marine sediments; whereas the last one (Late Jurassic) consists of marine carbonates only. All the five formations are separated from each other by unconformable contacts. Cretaceous rocks, represented by seven sedimentary cycles, overlie the Jurassic rocks. Marine clastics overlain by marine carbonates. Followed upwards (Late Cretaceous) by continental clastics overlain by marine carbonates; then followed by marine carbonates with marl intercalations, and finally by marine clastics overlain by carbonates; representing the last three cycles, respectively. The Paleocene rocks form narrow belt west of the Ga'ara Depression, represented by Early-Late Paleocene phosphatic facies, which is well developed east of Rutbah Uplift and extends eastwards in the Foredeep. Eocene rocks; west of Rutbah Uplift are represented by marine carbonates that has wide aerial coverage in south Iraq. Locally, east of Rutbah Uplift unconformable contacts are recorded between Early, Middle and Late Eocene rocks. During Oligocene, in the eastern margin of the Inner Platform, the Outer Platform was uplifted causing very narrow depositional Oligocene basin. Therefore, very restricted exposures are present in the northern part of the Inner Platform (north of Ga'ara Depression), represented by reef, forereef sediments of some Oligocene formations. The Miocene rocks have no exposures west of Rutbah Uplift, but north and northwestwards are widely exposed represented by Early Miocene of marine carbonates with marl intercalations. Very locally, Early Miocene deltaic clastics and carbonates, are interfingering with the marine carbonates. The last marine open sea sediments, locally with reef, represent the Middle Miocene rocks and fore reef facies that interfingers with evaporates along the northern part of Abu Jir Fault Zone, which is believed to be the reason for the restriction of the closed lagoons; in the area. During Late Miocene, the continental phase started in Iraq due to the closure of the Neo-Tethys and collision of the Sanandaj Zone with the Arabian Plate. The continental sediments consist of fine clastics. The Late Miocene - Middle Pliocene sediments were not deposited in the Inner Platform. The Pliocene-Pleistocene sediments are represented by cyclic sediments of conglomeratic sandstone overlain by fresh water limestone, and by pebbly sandstone. The Quaternary sediments are poorly developed in the Inner Platform. Terraces of Euphrates River and those of main valleys represent pleistocene sediments. Flood plain of the Euphrates River and those of large valleys represent Holocene sediments. Residual soil is developed, widely in the western part of Iraq, within the western marginal part of the Inner Platform.

Tidal notches, coastal landforms and relative sea-level changes during the Late Quaternary at Ustica Island (Tyrrhenian Sea, Italy)

NASA Astrophysics Data System (ADS)

Furlani, Stefano; Antonioli, Fabrizio; Cavallaro, Danilo; Chirco, Pietro; Caldareri, Francesco; Martin, Franco Foresta; Morticelli, Maurizio Gasparo; Monaco, Carmelo; Sulli, Attilio; Quarta, Gianluca; Biolchi, Sara; Sannino, Gianmaria; de Vita, Sandro; Calcagnile, Lucio; Agate, Mauro

2017-12-01

In this paper we present and discuss data concerning the morphostructural evolution at Ustica Island (Tyrrhenian Sea, Italy) during Late Quaternary. New insights on the relative sea-level changes of Ustica are coming from data collected during a geomorphological field survey around the island, together with the bathymetric analysis of the surrounding seabed and 14C datings on samples of speleothems, flowstones and marine shells found inside three selected sea caves. The survey was mainly accomplished on June 2015 through the first complete snorkel investigation off the about 18 km-long volcanic coast of the island, which allowed to precisely define location, relationship and morphometric features of coastal landforms associated with modern sea level. This study highlights the occurrence, for the first time in the Mediterranean, of tidal notches in correspondence of carbonate inclusions in volcanic rocks. The elevation of the modern tidal notch suggests that no significant vertical deformations occurred in the southeastern and eastern sectors of Ustica in the last 100 years. However, the presence of pillow lavas along the coast demonstrates that Ustica was affected by a regional uplift since the Late Quaternary, as also confirmed by MIS5.5 deposits located at about 30 m a.s.l., which suggests an average uplift rate of 0.23 mm/y. Radiocarbon dating of fossil barnacles collected inside the Grotta Segreta cave indicate an age of 1823 ± 104 cal. BP. The difference in height with respect to living barnacles in the same site suggests that their present elevation could be related to stick-slip coseismic deformations caused by the four earthquake sequences (two of which with Mw = 4.63 ± 0.46) that strongly struck the island between 1906 and 1924.

Synthesis of novel quaternary silica hybrid bioactive microspheres.

PubMed

Angelopoulou, A; Efthimiadou, E Κ; Kordas, G

2018-01-01

To survey the preparation of novel hybrid microspheres of quaternary silicate glassy composition (SiO 2 P 2 O 5 CaONa 2 O) and the prospect of using them as an osteogenic system with enhanced bioactive properties for the development of hydroxyapatite. In line with our previous synthetic procedure a two-step process was followed, wherein polystyrene (PS) microspheres were prepared by the emulsifier free-emulsion polymerization method and constituted the core for the sol-gel coating of the silicate inorganic shell. The development of the hybrid microspheres was based on silane and phosphate precursors and was assesses at different ratio of ethanol/water (of 9/1, 4/1, and 2/1, in mL) and at varied ammonia concentration of 4.8-1.0 mL. The hybrid microspheres had an average size ranged between 350 and 550 nm according to SEM, depending on the ethanol/water solution rate and ammonia content. The final microspheres probably exhibited a porous-like structure through the formation of diffused voids along with the low carbon content of the EDX analysis, which could be regulated by the catalyst content. The hybrid microspheres exhibited effective in vitro bioactivity assessed in simulated body fluids (SBF). Quaternary hybrid silica microspheres were effectively synthesized. The bioassay evaluation of the final microspheres revealed the rapid in vitro formation of a bone-like apatite layer. The results verify the bioactivity of the microspheres and promote further research of their suitability on regenerative treatment of bone abnormalities. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 112-120, 2018. © 2016 Wiley Periodicals, Inc.

Palaeohydrological evolution of the late Cenozoic saline lake in the Qaidam Basin, NE Tibetan Plateau: Tectonic vs. climatic control

NASA Astrophysics Data System (ADS)

Guo, Pei; Liu, Chiyang; Huang, Lei; Yu, Mengli; Wang, Peng; Zhang, Guoqing

2018-06-01

As the largest Cenozoic terrestrial intermountain basin on the Tibetan Plateau, the Qaidam Basin is an ideal setting to understand the coupled controls of tectonics and climate on hydrological evolution. In this study, we used 47,846 data of carbonate and chloride contents from 146 boreholes to reconstruct the Neogene-Quaternary basin-wide hydrological evolution of the Qaidam Basin. Our results show that during the early Miocene (22-15 Ma), the palaeolake in the Qaidam Basin was mainly situated in the southwestern part of the basin, and its water was mostly brackish. From then on, this palaeolake progressively migrated southeastward, and its salinity increased from late Miocene saline water to Quaternary brines. This generally increasing trend of the water palaeosalinity during the late Cenozoic corresponded with regional and global climate changes at that time, suggesting the dominance of climatic control. However, the paces of the salinity increase from sediments in front of the three basin-bounding ranges were not the same, indicating that extra tectonic controls occurred. Sediments in front of the Eastern Kunlun Shan to the southwest and the Altyn Shan to the northwest showed an abrupt, dramatic increase in salinity at 15 Ma and 8 Ma, respectively; sediments in front of the Qilian Shan to the northeast showed steady increase without prominent, abrupt changes, indicating the occurrence of asynchronous tectonic controls from the basin-bounding ranges. The late Miocene depocentre migration was synchronous with the hydrological changes in front of the Altyn Shan, while the more significant migration during the Quaternary was consistent with the pulsing, intense extrabasinal and intrabasinal tectonic movements along the Tibetan Plateau.

Conflicting drainage patterns in the Matera Horst Area, southern Italy

NASA Astrophysics Data System (ADS)

Beneduce, P.; Festa, V.; Francioso, R.; Schiattarella, M.; Tropeano, M.

The Matera Horst (“ Murgia materana”) is included in the Apulian plateau, basically formed by Mesozoic shallow-water carbonates. The zone is located in a present-day temperate belt and form a flat-topped morphostructural large element inside the foreland area of the southern Apennines. This horst is bordered by high-angle faults and surrounded by downthrown blocks covered by Plio-Quaternary marine and alluvial sediments. The structural high experienced several morphological cycles from Miocene to Quaternary. In particular, three evolutionary stages can be recognized at least. The first stage is currently represented by relics of a flat erosional landscape at the top of the relieves. The second one is testified by gentle slopes with wide glacis at the foothills, locally covered by coarse waste deposits. During the third stage a series of marine terraces formed and a drainage system developed creating both bland valleys and well-defined channels and gorges. The latter streams deeply carve the Cretaceous limestone of the Matera Horst for they represent the morphological response to the tectonic uplift of the area and clearly post-date the former features. Since the fluvial net took place on Pleistocene covers, later widely eroded, it is possible to conclude that the major part of the Matera Horst drainage system represents a good example of superimposition. However, low order streams and segments of major rivers appear to be structurally controlled, as suggested by comparison with the fracture system. Further, also open synclines and gently steeped flexures may locally exert a driving control on minor streams. These apparently conflicting genetic hypotheses can be explained by the role of exhumation of inherited structures of the bedrock in add to a constant interplay between tectonics, erosion and drainage evolution during Quaternary times.

Evolution of soils on quaternary reef terraces of Barbados, West Indies

USGS Publications Warehouse

Muhs, D.R.

2001-01-01

Soils on uplifted Quaternary reef terraces of Barbados, ???125,000 to ???700,000 yr old, form a climo-chronosequence and show changes in physical, chemical, and mineralogical properties with terrace age. Parent materials are dust derived from the Sahara, volcanic ash from the Lesser Antilles island arc, and detrital carbonate from the underlying reef limestone. Although some terrace soils are probably eroded, soils or their remnants are redder and more clay-rich with increasing terrace age. Profile-average Al2O3 and Fe2O3 content increases with terrace age, which partially reflects the increasing clay content, but dithionite-extractable Fe also increases with terrace age. Profile-average K2O/TiO2, Na2O/TiO2, and P2O5/TiO2 values decrease with terrace age, reflecting the depletion of primary minerals. Average SiO2/Al2O3 values also decrease with terrace age and reflect not only loss of primary minerals but also evolution of secondary clay minerals. Although they are not present in any of the parent materials, the youngest terrace soils are dominated by smectite and interstratified kaolinite-smectite, which gradually alter to relatively pure kaolinite over ???700,000 yr. Comparisons with other tropical islands, where precipitation is higher and rates of dust fall may be lower, show that Barbados soils are less weathered than soils of comparable age. It is concluded that many soil properties in tropical regions can be potentially useful relative-age indicators in Quaternary stratigraphic studies, even when soils are eroded or changes in soil morphology are not dramatic. ?? 2001 University of Washington.

Understanding congested travel in urban areas

PubMed Central

Çolak, Serdar; Lima, Antonio; González, Marta C.

2016-01-01

Rapid urbanization and increasing demand for transportation burdens urban road infrastructures. The interplay of number of vehicles and available road capacity on their routes determines the level of congestion. Although approaches to modify demand and capacity exist, the possible limits of congestion alleviation by only modifying route choices have not been systematically studied. Here we couple the road networks of five diverse cities with the travel demand profiles in the morning peak hour obtained from billions of mobile phone traces to comprehensively analyse urban traffic. We present that a dimensionless ratio of the road supply to the travel demand explains the percentage of time lost in congestion. Finally, we examine congestion relief under a centralized routing scheme with varying levels of awareness of social good and quantify the benefits to show that moderate levels are enough to achieve significant collective travel time savings. PMID:26978719

Understanding congested travel in urban areas

NASA Astrophysics Data System (ADS)

Çolak, Serdar; Lima, Antonio; González, Marta C.

2016-03-01

Rapid urbanization and increasing demand for transportation burdens urban road infrastructures. The interplay of number of vehicles and available road capacity on their routes determines the level of congestion. Although approaches to modify demand and capacity exist, the possible limits of congestion alleviation by only modifying route choices have not been systematically studied. Here we couple the road networks of five diverse cities with the travel demand profiles in the morning peak hour obtained from billions of mobile phone traces to comprehensively analyse urban traffic. We present that a dimensionless ratio of the road supply to the travel demand explains the percentage of time lost in congestion. Finally, we examine congestion relief under a centralized routing scheme with varying levels of awareness of social good and quantify the benefits to show that moderate levels are enough to achieve significant collective travel time savings.

A review on the synthesis, crystal growth, structure and physical properties of rare earth based quaternary intermetallic compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumbaraddi, Dundappa; Sarkar, Sumanta; Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in

2016-04-15

This review highlights the synthesis and crystal growth of quaternary intermetallic compounds based on rare earth metals. In the first part of this review, we highlight briefly about intermetallics and their versatile properties in comparison to the constituent elements. In the next part, we have discussed about various synthesis techniques with more focus on the metal flux technique towards the well shaped crystal growth of novel compounds. In the subsequent parts, several disordered quaternary compounds have been reviewed and then outlined most known ordered quaternary compounds with their complex structure. A special attention has been given to the ordered compoundsmore » with structural description and relation to the parent binary and ternary compounds. The importance of electronic and structural feature is highlighted as the key roles in designing these materials for emerging applications. - Graphical abstract: Rare earth based quaternary intermetallic compounds crystallize in complex novel crystal structures. The diversity in the crystal structure may induce unique properties and can be considered them as future materials. - Highlights: • Crystal growth and crystal structure of quaternary rare earth based intermetallics. • Structural complexity of quaternary compounds in comparison to the parent compounds. • Novel quaternary compounds display unique crystal structure.« less

Effect of venous and lymphatic congestion on lymph capillary pressure of the skin in healthy volunteers and patients with lymph edema.

PubMed

Gretener, S B; Läuchli, S; Leu, A J; Koppensteiner, R; Franzeck, U K

2000-01-01

The aim of the present study was to assess the influence of venous and lymphatic congestion on lymph capillary pressure (LCP) in the skin of the foot dorsum of healthy volunteers and of patients with lymph edema. LCP was measured at the foot dorsum of 12 patients with lymph edema and 18 healthy volunteers using the servo-nulling technique. Glass micropipettes (7-9 microm) were inserted under microscopic control into lymphatic microvessels visualized by fluorescence microlymphography before and during venous congestion. Venous and lymphatic congestion was attained by cuff compression (50 mm Hg) at the thigh level. Simultaneously, the capillary filtration rate was measured using strain gauge plethysmography. The mean LCP in patients with lymph edema increased significantly (p < 0.05) during congestion (15.7 +/- 8.8 mm Hg) compared to the control value (12.2 +/- 8.9 mm Hg). The corresponding values of LCP in healthy volunteers were 4.3 +/- 2.6 mm Hg during congestion and 2.6 +/- 2.8 mm Hg during control conditions (p < 0.01). The mean increase in LCP in patients with lymph edema was 3.4 +/- 4.1 mm Hg, and 1.7 +/- 2.0 mm Hg in healthy volunteers (NS). The maximum spread of the lymph capillary network in patients increased from 13.9 +/- 6.8 mm before congestion to 18.8 +/- 8.2 mm during thigh compression (p < 0.05). No increase could be observed in healthy subjects. In summary, venous and lymphatic congestion by cuff compression at the thigh level results in a significant increase in LCP in healthy volunteers as well as in patients with lymph edema. The increased spread of the contrast medium in the superficial microlymphatics in lymph edema patients indicates a compensatory mechanism for lymphatic drainage during congestion of the veins and lymph collectors of the leg. Copyright 2000 S. Karger AG, Basel

Quantum random walks on congested lattices and the effect of dephasing

PubMed Central

Motes, Keith R.; Gilchrist, Alexei; Rohde, Peter P.

2016-01-01

We consider quantum random walks on congested lattices and contrast them to classical random walks. Congestion is modelled on lattices that contain static defects which reverse the walker’s direction. We implement a dephasing process after each step which allows us to smoothly interpolate between classical and quantum random walks as well as study the effect of dephasing on the quantum walk. Our key results show that a quantum walker escapes a finite boundary dramatically faster than a classical walker and that this advantage remains in the presence of heavily congested lattices. PMID:26812924

Stratigraphy and depositional sequences of the US Atlantic shelf and slope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poag, C.W.; Valentine, P.C.

1985-01-01

Litho-, bio-, and seismostratigraphic analyses of Georges Bank basin, Baltimore Canyon trough, and Blake Plateau basin reveal common aspects of stratigraphic framework and depositional history. Synrift graben-fill is inferred to be chiefly coarse terrigenous siliciclastics of Triassic-Early Jurassic age, as thick as 5 km. Following widespread erosion, restricted marine carbonates and evaporites formed initial post-rift deposits during an Early-Middle Jurassic transition to sea floor spreading. As sea floor spreading proceeded, shallow-water limestones and shelf-edge reefs built up, culminating in a discontinuous, margin-rimming reefal bank during the Late Jurassic-Early Cretaceous. During the Early Cretaceous, thick siliciclastics buried the shelf-edge barrier northmore » of Cape Hatteras, whereas shallow-water carbonates persisted in the Blake Plateau basin. Late Cretaceous deposits became increasingly finer-grained as they accumulated beneath a deepening shelf-sea; maximum thickness is more than 2 km. Cretaceous deposition was terminated by marginwide erosion and followed by widespread carbonate deposition in the Paleogene. Neogene and Quaternary deposition was chiefly siliciclastic, characterized by deltaic progradation. Cenozoic sediment thickness reaches 2 km in the Baltimore Canyon trough.« less

A Mycobacterium Strain with Extended Capacities for Degradation of Gasoline Hydrocarbons

PubMed Central

Solano-Serena, Floriane; Marchal, Rémy; Casarégola, Serge; Vasnier, Christelle; Lebeault, Jean-Michel; Vandecasteele, Jean-Paul

2000-01-01

A bacterial strain (strain IFP 2173) was selected from a gasoline-polluted aquifer on the basis of its capacity to use 2,2,4-trimethylpentane (isooctane) as a sole carbon and energy source. This isolate, the first isolate with this capacity to be characterized, was identified by 16S ribosomal DNA analysis, and 100% sequence identity with a reference strain of Mycobacterium austroafricanum was found. Mycobacterium sp. strain IFP 2173 used an unusually wide spectrum of hydrocarbons as growth substrates, including n-alkanes and multimethyl-substituted isoalkanes with chains ranging from 5 to 16 carbon atoms long, as well as substituted monoaromatic hydrocarbons. It also attacked ethers, such as methyl t-butyl ether. During growth on gasoline, it degraded 86% of the substrate. Our results indicated that strain IFP 2173 was capable of degrading 3-methyl groups, possibly by a carboxylation and deacetylation mechanism. Evidence that it attacked the quaternary carbon atom structure by an as-yet-undefined mechanism during growth on 2,2,4-trimethylpentane and 2,2-dimethylpentane was also obtained. PMID:10831416

Rapid, Microwave-Assisted Synthesis of Cubic, Three-Dimensional, Highly Porous MOF-205 for Room Temperature CO2 Fixation via Cyclic Carbonate Synthesis.

PubMed

Babu, Robin; Roshan, Roshith; Kathalikkattil, Amal Cherian; Kim, Dong Woo; Park, Dae-Won

2016-12-14

A dual-porous, three-dimensional, metal-organic framework [Zn 4 O(2,6-NDC)(BTB) 4/3 ] (MOF-205, BET = 4200 m 2 /g) has been synthesized using microwave power as an alternative energy source for the first time, and its catalytic activity has been exploited for CO 2 -epoxide coupling reactions to produce five-membered cyclic carbonates under solvent-free conditions. Microwave synthesis was performed at different time intervals to reveal the formation of the crystals. Significant conversion of various epoxides was obtained at room temperature, with excellent selectivity toward the desired five-membered cyclic carbonates. The importance of the dual porosity and the synergistic effect of quaternary ammonium salts on efficiently catalyzed CO 2 conversion were investigated using various experimental and physicochemical characterization techniques, and the results were compared with those of the solvothermally synthesized MOF-205 sample. On the basis of literature and experimental inferences, a rationalized mechanism mediated by the zinc center of MOF-205 for the CO 2 -epoxide cycloaddition reaction has been proposed.

An improved global dynamic routing strategy for scale-free network with tunable clustering

NASA Astrophysics Data System (ADS)

Sun, Lina; Huang, Ning; Zhang, Yue; Bai, Yannan

2016-08-01

An efficient routing strategy can deliver packets quickly to improve the network capacity. Node congestion and transmission path length are inevitable real-time factors for a good routing strategy. Existing dynamic global routing strategies only consider the congestion of neighbor nodes and the shortest path, which ignores other key nodes’ congestion on the path. With the development of detection methods and techniques, global traffic information is readily available and important for the routing choice. Reasonable use of this information can effectively improve the network routing. So, an improved global dynamic routing strategy is proposed, which considers the congestion of all nodes on the shortest path and incorporates the waiting time of the most congested node into the path. We investigate the effectiveness of the proposed routing for scale-free network with different clustering coefficients. The shortest path routing strategy and the traffic awareness routing strategy only considering the waiting time of neighbor node are analyzed comparatively. Simulation results show that network capacity is greatly enhanced compared with the shortest path; congestion state increase is relatively slow compared with the traffic awareness routing strategy. Clustering coefficient increase will not only reduce the network throughput, but also result in transmission average path length increase for scale-free network with tunable clustering. The proposed routing is favorable to ease network congestion and network routing strategy design.

Tolvaptan in Patients Hospitalized With Acute Heart Failure: Rationale and Design of the TACTICS and the SECRET of CHF Trials.

PubMed

Felker, G Michael; Mentz, Robert J; Adams, Kirkwood F; Cole, Robert T; Egnaczyk, Gregory F; Patel, Chetan B; Fiuzat, Mona; Gregory, Douglas; Wedge, Patricia; O'Connor, Christopher M; Udelson, James E; Konstam, Marvin A

2015-09-01

Congestion is a primary reason for hospitalization in patients with acute heart failure (AHF). Despite inpatient diuretics and vasodilators targeting decongestion, persistent congestion is present in many AHF patients at discharge and more severe congestion is associated with increased morbidity and mortality. Moreover, hospitalized AHF patients may have renal insufficiency, hyponatremia, or an inadequate response to traditional diuretic therapy despite dose escalation. Current alternative treatment strategies to relieve congestion, such as ultrafiltration, may also result in renal dysfunction to a greater extent than medical therapy in certain AHF populations. Truly novel approaches to volume management would be advantageous to improve dyspnea and clinical outcomes while minimizing the risks of worsening renal function and electrolyte abnormalities. One effective new strategy may be utilization of aquaretic vasopressin antagonists. A member of this class, the oral vasopressin-2 receptor antagonist tolvaptan, provides benefits related to decongestion and symptom relief in AHF patients. Tolvaptan may allow for less intensification of loop diuretic therapy and a lower incidence of worsening renal function during decongestion. In this article, we summarize evidence for decongestion benefits with tolvaptan in AHF and describe the design of the Targeting Acute Congestion With Tolvaptan in Congestive Heart Failure Study (TACTICS) and Study to Evaluate Challenging Responses to Therapy in Congestive Heart Failure (SECRET of CHF) trials. © 2015 American Heart Association, Inc.

Congestion based mechanism for route discovery in a V2I-V2V system applying smart devices and IoT.

PubMed

Parrado, Natalia; Donoso, Yezid

2015-03-31

The Internet of Things is a new paradigm in which objects in a specific context can be integrated into traditional communication networks to actively participate in solving a determined problem. The Vehicle-to-Vehicle (V2V) and Vehicle-to-Infrastructure (V2I) technologies are specific cases of IoT and key enablers for Intelligent Transportation Systems (ITS). V2V and V2I have been widely used to solve different problems associated with transportation in cities, in which the most important is traffic congestion. A high percentage of congestion is usually presented by the inappropriate use of resources in vehicular infrastructure. In addition, the integration of traffic congestion in decision making for vehicular traffic is a challenge due to its high dynamic behavior. In this paper, an optimization model over the load balancing in the congestion percentage of the streets is formulated. Later, we explore a fully congestion-oriented route discovery mechanism and we make a proposal on the communication infrastructure that should support it based on V2I and V2V communication. The mechanism is also compared with a modified Dijkstra's approach that reacts at congestion states. Finally, we compare the results of the efficiency of the vehicle's trip with the efficiency in the use of the capacity of the vehicular network.

Limb congestion enhances the synchronization of sympathetic outflow with muscle contraction

NASA Technical Reports Server (NTRS)

Mostoufi-Moab, S.; Herr, M. D.; Silber, D. H.; Gray, K. S.; Leuenberger, U. A.; Sinoway, L. I.

2000-01-01

In this report, we examined if the synchronization of muscle sympathetic nerve activity (MSNA) with muscle contraction is enhanced by limb congestion. To explore this relationship, we applied signal-averaging techniques to the MSNA signal obtained during short bouts of forearm contraction (2-s contraction/3-s rest cycle) at 40% maximal voluntary contraction for 5 min. We performed this analysis before and after forearm venous congestion; an intervention that augments the autonomic response to sustained static muscle contractions via a local effect on muscle afferents. There was an increased percentage of the MSNA noted during second 2 of the 5-s contraction/rest cycles. The percentage of total MSNA seen during this particular second increased from minute 1 to 5 of contraction and was increased further by limb congestion (control minute 1 = 25.6 +/- 2.0%, minute 5 = 32.8 +/- 2.2%; limb congestion minute 1 = 29.3 +/- 2.1%, minute 5 = 37.8 +/- 3.9%; exercise main effect <0.005; limb congestion main effect P = 0.054). These changes in the distribution of signal-averaged MSNA were seen despite the fact that the mean number of sympathetic discharges did not increase over baseline. We conclude that synchronization of contraction and MSNA is seen during short repetitive bouts of handgrip. The sensitizing effect of contraction time and limb congestion are apparently due to feedback from muscle afferents within the exercising muscle.

Congestion Based Mechanism for Route Discovery in a V2I-V2V System Applying Smart Devices and IoT

PubMed Central

Parrado, Natalia; Donoso, Yezid

2015-01-01

The Internet of Things is a new paradigm in which objects in a specific context can be integrated into traditional communication networks to actively participate in solving a determined problem. The Vehicle-to-Vehicle (V2V) and Vehicle-to-Infrastructure (V2I) technologies are specific cases of IoT and key enablers for Intelligent Transportation Systems (ITS). V2V and V2I have been widely used to solve different problems associated with transportation in cities, in which the most important is traffic congestion. A high percentage of congestion is usually presented by the inappropriate use of resources in vehicular infrastructure. In addition, the integration of traffic congestion in decision making for vehicular traffic is a challenge due to its high dynamic behavior. In this paper, an optimization model over the load balancing in the congestion percentage of the streets is formulated. Later, we explore a fully congestion-oriented route discovery mechanism and we make a proposal on the communication infrastructure that should support it based on V2I and V2V communication. The mechanism is also compared with a modified Dijkstra’s approach that reacts at congestion states. Finally, we compare the results of the efficiency of the vehicle’s trip with the efficiency in the use of the capacity of the vehicular network. PMID:25835185

Large-scale transportation network congestion evolution prediction using deep learning theory.

PubMed

Ma, Xiaolei; Yu, Haiyang; Wang, Yunpeng; Wang, Yinhai

2015-01-01

Understanding how congestion at one location can cause ripples throughout large-scale transportation network is vital for transportation researchers and practitioners to pinpoint traffic bottlenecks for congestion mitigation. Traditional studies rely on either mathematical equations or simulation techniques to model traffic congestion dynamics. However, most of the approaches have limitations, largely due to unrealistic assumptions and cumbersome parameter calibration process. With the development of Intelligent Transportation Systems (ITS) and Internet of Things (IoT), transportation data become more and more ubiquitous. This triggers a series of data-driven research to investigate transportation phenomena. Among them, deep learning theory is considered one of the most promising techniques to tackle tremendous high-dimensional data. This study attempts to extend deep learning theory into large-scale transportation network analysis. A deep Restricted Boltzmann Machine and Recurrent Neural Network architecture is utilized to model and predict traffic congestion evolution based on Global Positioning System (GPS) data from taxi. A numerical study in Ningbo, China is conducted to validate the effectiveness and efficiency of the proposed method. Results show that the prediction accuracy can achieve as high as 88% within less than 6 minutes when the model is implemented in a Graphic Processing Unit (GPU)-based parallel computing environment. The predicted congestion evolution patterns can be visualized temporally and spatially through a map-based platform to identify the vulnerable links for proactive congestion mitigation.

Large-Scale Transportation Network Congestion Evolution Prediction Using Deep Learning Theory

PubMed Central

Ma, Xiaolei; Yu, Haiyang; Wang, Yunpeng; Wang, Yinhai

2015-01-01

Understanding how congestion at one location can cause ripples throughout large-scale transportation network is vital for transportation researchers and practitioners to pinpoint traffic bottlenecks for congestion mitigation. Traditional studies rely on either mathematical equations or simulation techniques to model traffic congestion dynamics. However, most of the approaches have limitations, largely due to unrealistic assumptions and cumbersome parameter calibration process. With the development of Intelligent Transportation Systems (ITS) and Internet of Things (IoT), transportation data become more and more ubiquitous. This triggers a series of data-driven research to investigate transportation phenomena. Among them, deep learning theory is considered one of the most promising techniques to tackle tremendous high-dimensional data. This study attempts to extend deep learning theory into large-scale transportation network analysis. A deep Restricted Boltzmann Machine and Recurrent Neural Network architecture is utilized to model and predict traffic congestion evolution based on Global Positioning System (GPS) data from taxi. A numerical study in Ningbo, China is conducted to validate the effectiveness and efficiency of the proposed method. Results show that the prediction accuracy can achieve as high as 88% within less than 6 minutes when the model is implemented in a Graphic Processing Unit (GPU)-based parallel computing environment. The predicted congestion evolution patterns can be visualized temporally and spatially through a map-based platform to identify the vulnerable links for proactive congestion mitigation. PMID:25780910

Multi-Scale Visualization Analysis of Bus Flow Average Travel Speed in Qingdao

NASA Astrophysics Data System (ADS)

Yong, HAN; Man, GAO; Xiao-Lei, ZHANG; Jie, LI; Ge, CHEN

2016-11-01

Public transportation is a kind of complex spatiotemporal behaviour. The traffic congestion and environmental pollution caused by the increase in private cars is becoming more and more serious in our city. Spatiotemporal data visualization is an effective tool for studying traffic, transforming non-visual data into recognizable images, which can reveal where/when congestion is formed, developed and disappeared in space and time simultaneously. This paper develops a multi-scale visualization of average travel speed derived from floating bus data, to enable congestion on urban bus networks to be shown and analyzed. The techniques of R language, Echarts, WebGL are used to draw statistical pictures and 3D wall map, which show the congestion in Qingdao from the view of space and time. The results are as follows:(1) There is a more severely delay in Shibei and Shinan areas than Licun and Laoshan areas; (2) The high congestion usually occurs on Hong Kong Middle Road, Shandong Road, Nanjing Road, Liaoyang West Road and Taiping Road;(3) There is a similar law from Monday to Sunday that the congestion is severer in the morning and evening rush hours than other hours; (4) On Monday morning the severity of congestion is higher than on Friday morning, and on Friday evening the severity is higher than on Monday evening. The research results will help to improve the public transportation of Qingdao.

Late Quaternary Faulting along the San Juan de los Planes Fault Zone, Baja California Sur, Mexico

NASA Astrophysics Data System (ADS)

Busch, M. M.; Coyan, J. A.; Arrowsmith, J.; Maloney, S. J.; Gutierrez, G.; Umhoefer, P. J.

2007-12-01

As a result of continued distributed deformation in the Gulf Extensional Province along an oblique-divergent plate margin, active normal faulting is well manifest in southeastern Baja California. By characterizing normal-fault related deformation along the San Juan de los Planes fault zone (SJPFZ) southwest of La Paz, Baja California Sur we contribute to understanding the patterns and rates of faulting along the southwest gulf-margin fault system. The geometry, history, and rate of faulting provide constraints on the relative significance of gulf-margin deformation as compared to axial system deformation. The SJPFZ is a major north-trending structure in the southern Baja margin along which we focused our field efforts. These investigations included: a detailed strip map of the active fault zone, including delineation of active scarp traces and geomorphic surfaces on the hanging wall and footwall; fault scarp profiles; analysis of bedrock structures to better understand how the pattern and rate of strain varied during the development of this fault zone; and a gravity survey across the San Juan de los Planes basin to determine basin geometry and fault behavior. The map covers a N-S swath from the Gulf of California in the north to San Antonio in the south, an area ~45km long and ~1-4km wide. Bedrock along the SJPFZ varies from Cretaceous Las Cruces Granite in the north to Cretaceous Buena Mujer Tonalite in the south and is scarred by shear zones and brittle faults. The active scarp-forming fault juxtaposes bedrock in the footwall against Late Quaternary sandstone-conglomerate. This ~20m wide zone is highly fractured bedrock infused with carbonate. The northern ~12km of the SJPFZ, trending 200°, preserves discontinuous scarps 1-2km long and 1-3m high in Quaternary units. The scarps are separated by stretches of bedrock embayed by hundreds of meters-wide tongues of Quaternary sandstone-conglomerate, implying low Quaternary slip rate. Further south, ~2 km north of the Los Planes highway, the fault steps to the right 2km with no overlap. The fault is inactive until ~3km south of the Los Planes highway where scarp heights in the Quaternary sediments rise to ~3-11m for ~11km with an average trend of 160°, implying increasing slip rate. The fault then steps left 2km with no overlap, trending 145°. Scarp heights range from 3-6m in the step. The southernmost 9km of the fault zone, trending 200°, is marked by discontinuous scarps and embayed bedrock, reflecting diminished fault activity. The footwall landscape in this area is characterized by a broad, gently-sloping, low-relief pediment surface with thin Quaternary cover, disrupted by inselberg-like hills. The young scarp-forming fault appears to have reactivated older faults to rupture this pediment, reflecting the episodic nature of slip along this fault zone. Preliminary OSL ages of the youngest faulted deposit imply a Late Pleistocene-Holocene slip rate of 0.1-1mm/yr. The SJPFZ is thus characterized by reactivation of pre-existing faults to rupture a pre-existing low relief erosional landscape. Whereas the entire region might have experienced the quiescent period that allowed for development of the low- relief, stable surface along the SJPFZ, we speculate that while the SJPFZ was dormant, other faults within the gulf-margin system were actively accommodating strain.

Gravity and magnetic data in the vicinity of Virgin Valley, southern Nevada

USGS Publications Warehouse

Morin, Robert L.

2006-01-01

This report contains 10 interpretive cross sections and an integrated text describing the geology of parts of the Colorado, White River, and Death Valley regional ground-water flow systems, Nevada, Utah, and Arizona. The primary purpose of the report is to provide geologic framework data for input into a numerical ground-water model. Therefore, the stratigraphic and structural summaries are written in a hydrogeologic context. The oldest rocks (basement) are Early Proterozoic metamorphic and intrusive crystalline rocks that are considered confining units because of their low permeability. Late Proterozoic to Lower Cambrian clastic units overlie the crystalline rocks and are also considered confining units within the regional flow systems. Above the clastic units are Middle Cambrian to Lower Permian carbonate rocks that are the primary aquifers in the flow systems. The Middle Cambrian to Lower Permian carbonate rocks are overlain by a sequence of mainly clastic rocks of late Paleozoic to Mesozoic age that are mostly considered confining units, but they may be permeable where faulted. Tertiary volcanic and plutonic rocks are exposed in the northern and southern parts of the study area. In the Clover and Delamar Mountains, these rocks are highly deformed by north- and northwest-striking normal and strike-slip faults that are probably important conduits in transmitting ground water from the basins in the northern Colorado and White River flow systems to basins in the southern part of the flow systems. The youngest rocks in the region are Tertiary to Quaternary basin-fill deposits. These rocks consist of middle to late Tertiary sediments consisting of limestone, conglomerate, sandstone, tuff, and gypsum, and younger Quaternary surficial units consisting of alluvium, colluvium, playa deposits, and eolian deposits. Basin-fill deposits are both aquifers and aquitards.

Dynamics, chemical properties and bioavailability of DOC in an early successional catchment

NASA Astrophysics Data System (ADS)

Risse-Buhl, U.; Hagedorn, F.; Dümig, A.; Gessner, M. O.; Schaaf, W.; Nii-Annang, S.; Gerull, L.; Mutz, M.

2013-07-01

The dynamics of dissolved organic carbon (DOC) have been intensively studied in mature ecosystems, but little is known about DOC dynamics and the significance of DOC as a substrate for microbial activity in early-successional catchments. We determined the concentration, chemical composition, source, radiocarbon age, and bioavailability of DOC along the hydrological flow path from soil solution to a downstream pond in a recently constructed catchment (Chicken Creek Catchment, Germany). Soil solution, upwelling ground water, stream water, subsurface water in an alluvial fan, and pond water all had high DOC concentrations (averages: 6.0-11.6 mg DOC L-1), despite small carbon stocks in both vegetation and soil of the catchment. Solid-state CPMAS 13C NMR of DOC in upwelling ground water revealed a higher proportion of aromatic compounds (32%) and a lower proportion of carbohydrates (33%) than in pond water (18% and 45%, respectively). The average 14C age of DOC in upwelling ground water was 2600 to 2900 yr, while organic matter of the Quaternary substrate of the catchment had a 14C age of 3000 to 16 000 yr. Both the 14C age data and 13C NMR spectra suggest that DOC partly derived from organic matter of the Quaternary substrate (about 40 to 90% of the C in the DOC), indicating that both recent and old C of the DOC can support microbial activity during early ecosystem succession. However, in a 70 day incubation experiment, only about 11% of the total DOC was found to be bioavailable. This proportion was irrespective of the water type. Origin of the microbial communities within the catchment (enriched from soil, stream sediment or pond water) also had only a marginal effect on overall DOC utilization.

Effect of applied bias voltage on corrosion-resistance for TiC 1- xN x and Ti 1- xNb xC 1- yN y coatings

NASA Astrophysics Data System (ADS)

Caicedo, J. C.; Amaya, C.; Yate, L.; Aperador, W.; Zambrano, G.; Gómez, M. E.; Alvarado-Rivera, J.; Muñoz-Saldaña, J.; Prieto, P.

2010-02-01

Corrosion-resistance behavior of titanium carbon nitride (Ti-C-N) and titanium niobium carbon nitride (Ti-Nb-C-N) coatings deposited onto Si(1 0 0) and AISI 4140 steel substrates via r.f. magnetron sputtering process was analyzed. The coatings in contact with a solution of sodium chloride at 3.5% were studied by Tafel polarization curves and impedance spectroscopy methods (EIS). Variations of the bias voltage were carried out for each series of deposition to observe the influence of this parameter upon the electrochemical properties of the coatings. The introduction of Nb in the ternary Ti-C-N film was evaluated via X-ray diffraction (XRD) analysis. The structure was characterized by using Raman spectroscopy to identify ternary and quaternary compounds. Surface corrosion processes were characterized using optical microscopy and scanning electron microscopy (SEM). XRD results show conformation of the quaternary phase, change in the strain of the film, and lattice parameter as the effect of the Nb inclusion. The main Raman bands were assigned to interstitial phases and "impurities" of the coatings. Changes in Raman intensities were attributed to the incorporation of niobium in the Ti-C-N structure and possibly to resonance enhancement. Finally, the corrosion data obtained for Ti-C-N were compared with the results of corrosion tests of Ti-Nb-C-N coating. The results obtained showed that the incorporation of niobium to Ti-C-N coatings led to an increase in the corrosion-resistance. On another hand, an increase in the bias voltage led to a decrease in the corrosion-resistance for both Ti-C-N and Ti-Nb-C-N coatings.

The impact of anti-congestion policies on fuel consumption, carbon dioxide emissions and urban sprawl: Application of RELU-TRAN2, a CGE model

NASA Astrophysics Data System (ADS)

Hiramatsu, Tomoru

RELU-TRAN (Regional Economy and Land Use and Transportation) is a numerically solvable general equilibrium model (Anas and Liu, 2007), which treats in a unified manner the regional economy, urban land use and urban personal transportation sectors. In this dissertation, the model is extended by adding the consumer-workers' choice of private vehicle type according to the vehicle's fuel economy, by treating congestion on local roads as well as on major roads and by introducing car fuel consumption as a function of congested vehicle speed. By making the extensions, the model becomes more suitable to analyze the fuel consumption and CO2 emission consequences of urban development. The model is calibrated and simulated for the Chicago metropolitan area. By adjusting the model to the longer time span gradually, the shortand long-run price elasticities of fuel consumption are examined. As the time span becomes longer, fuel consumption becomes more elastic with respect to gasoline price, but when technological improvements in car fuel economy over comparable time spans are introduced exogenously, then the elasticity of fuel with respect to gasoline price becomes similar to that estimated in the econometric literature. Comparative statics exercises show that, if travel by auto becomes relatively more attractive in terms of travel time or travel cost than travel by public transit, then the Chicago MSA becomes more sprawled in total developed land area, whereas if public transit travel becomes relatively more attractive, then the Chicago MSA becomes more centralized. To mitigate fuel consumption and CO2 emissions, relative effectiveness of quasi-Pigouvian congestion tolls, a fuel tax on gasoline, a cordon toll around the downtown and a downtown parking fee are tested. All of these policies successfully reduce the aggregate fuel consumption and CO2. The urban growth boundary (UGB) is an alternative policy tested by the model. The UGB directly makes the Chicago MSA more centralized by prohibiting the development into urban use of a part of the vacant land in the suburban areas. The UGB also reduces aggregate fuel and CO2 emissions, but the impact is much smaller than the quasi-Pigouvian toll. Although Chicago MSA is centralized by both the UGB and the quasi-Pigouvian toll, the auto travel is directly discouraged by quasi-Pigouvian toll and but not by the UGB.

Traffic Congestion on a University Campus: A Consideration of Unconventional Remedies to Nontraditional Transportation Patterns

ERIC Educational Resources Information Center

Kaplan, Dave; Clapper, Thomas

2007-01-01

U.S. transportation data suggest that the number of vehicle miles traveled has far surpassed new capacity, resulting in increased traffic congestion in many communities throughout the country. This article reports on traffic congestion around a university campus located within a small town. The mix of trip purposes varies considerably in this…

Examining the speed-flow-delay paradox in the Washington, DC region : potential impacts of reduced traffic on congestion delay and potential for reductions in discretionary travel during peak periods.

DOT National Transportation Integrated Search

2008-12-01

Traffic congestion in the Washington, DC area, especially congestion on our freeways, costs our residents every day : in terms of wasted time, fuel, and increased air pollution. Highway studies have determined that once traffic volumes : exceed the c...

PRN 88-2: Clustering of Quaternary Ammonium Compounds

EPA Pesticide Factsheets

This Notice announces that EPA has clustered the Quaternary Ammonium Compounds into four groups for the purpose of testing chemicals to build a database that will support continued registration of the entire family of quaternary ammonium compounds

Losartan corrects abnormal frequency response of renal vasculature in congestive heart failure.

PubMed

DiBona, Gerald F; Sawin, Linda L

2003-11-01

In congestive heart failure, renal blood flow is decreased and renal vascular resistance is increased in a setting of increased activity of both the sympathetic nervous and renin-angiotensin systems. The renal vasoconstrictor response to renal nerve stimulation is enhanced. This is associated with an abnormality in the low-pass filter function of the renal vasculature wherein higher frequencies (> or =0.01 Hz) within renal sympathetic nerve activity are not normally attenuated and are passed into the renal blood flow signal. This study tested the hypothesis that excess angiotensin II action mediates the abnormal frequency response characteristics of the renal vasculature in congestive heart failure. In anesthetized rats, the renal vasoconstrictor response to graded frequency renal nerve stimulation was significantly greater in congestive heart failure than in control rats. Losartan attenuated the renal vasoconstrictor response to a significantly greater degree in congestive heart failure than in control rats. In control rats, the frequency response of the renal vasculature was that of a first order (-20 dB/frequency decade) low-pass filter with a corner frequency (-3 dB, 30% attenuation) of 0.002 Hz and 97% attenuation (-30 dB) at > or =0.1 Hz. In congestive heart failure rats, attenuation did not exceed 45% (-5 dB) over the frequency range of 0.001-0.6 Hz. The frequency response of the renal vasculature was not affected by losartan treatment in control rats but was completely restored to normal by losartan treatment in congestive heart failure rats. The enhanced renal vasoconstrictor response to renal nerve stimulation and the associated abnormality in the frequency response characteristics of the renal vasculature seen in congestive heart failure are mediated by the action of angiotensin II on renal angiotensin II AT1 receptors.

The Terrestrial Paleoclimatic Record of the Late Quaternary as Revealed by Drilling Lake Titicaca, Peru/Bolivia

NASA Astrophysics Data System (ADS)

Baker, P. A.; Fritz, S. C.; Seltzer, G. O.; Ballantyne, A. P.; Rigsby, C. A.

2004-12-01

Seven drill cores were recovered from Lake Titicaca during the NSF/ICDP/DOSECC drilling expedition of 2001; our most detailed multi-proxy analyses have been done on Core 2B raised from 232 m water depth in the central basin of the lake. This site was drilled to 139 mblf with 141 m of total sediment recovered (101%). The recovered sediments consist of two main lithologies, organic- and inorganic-carbon-rich (often-laminated) muds that alternate with detrital-rich muds. These lithologies represent respectively low and high lakestand deposits. Proxies for water level include planktic-to-benthic diatom ratio, sedimentary carbonate content, and stable isotopic ratio of organic carbon. There are six highstand intervals separated by five lowstand intervals indicating that the level and volume of Lake Titicaca underwent several large changes during the late Quaternary. We infer from high values of magnetic susceptibility in most highstand muds that glacial advances in the surrounding Andes coincided with periods of relative wetness. During the most recent lowstand, in the early and middle Holocene, Lake Titicaca fell to 85 m below its modern level, salinity increased several-fold, and the downstream Salar de Uyuni desiccated. By contrast, throughout the LGM from ca. 25,000 cal BP to 15,000 cal BP, Lake Titicaca was deep and fresh, and overflowed southward to the Salar de Uyuni. Prior to the LGM, back to ca. 53,000 BP, the lake was predominantly fresh and overflowing. Pulses of increased benthic diatom abundance and inorganic carbon concentration during that time were likely due to episodes of downslope transport. We believe (based on U-Th dates of authigenic carbonate layers) that the penultimate lowstand of Lake Titicaca (seismic evidence indicates a lake level 200 m lower than today) was coincident with MIS 5. We recovered sediments recording three older lowstands, each separated by periods in which the lake freshened dramatically and when glaciers apparently advanced in the Andes. We tentatively correlate these lowstands with MIS 7, 9, and 11. The high abundance of benthic diatoms in the lowermost 40 m of drill core may imply that the Altiplano was persistently drier than today, prior to and including MIS 9. Alternatively, basin morphometry may have been significantly different than today because of geomorphic or tectonic effects. This period apparently coincides with a period when the Salar de Uyuni was mostly dry and dominated by salt deposition.

On-board congestion control for satellite packet switching networks

NASA Technical Reports Server (NTRS)

Chu, Pong P.

1991-01-01

It is desirable to incorporate packet switching capability on-board for future communication satellites. Because of the statistical nature of packet communication, incoming traffic fluctuates and may cause congestion. Thus, it is necessary to incorporate a congestion control mechanism as part of the on-board processing to smooth and regulate the bursty traffic. Although there are extensive studies on congestion control for both baseband and broadband terrestrial networks, these schemes are not feasible for space based switching networks because of the unique characteristics of satellite link. Here, we propose a new congestion control method for on-board satellite packet switching. This scheme takes into consideration the long propagation delay in satellite link and takes advantage of the the satellite's broadcasting capability. It divides the control between the ground terminals and satellite, but distributes the primary responsibility to ground terminals and only requires minimal hardware resource on-board satellite.

Traffic congestion and blood pressure elevation: A comparative cross-sectional study in Lebanon.

PubMed

Bou Samra, Patrick; El Tomb, Paul; Hosni, Mohammad; Kassem, Ahmad; Rizk, Robin; Shayya, Sami; Assaad, Sarah

2017-12-01

This comparative cross-sectional study examines the association between traffic congestion and elevation of systolic and/or diastolic blood pressure levels among a convenience sample of 310 drivers. Data collection took place during a gas station pause at a fixed time of day. Higher average systolic (142 vs 123 mm Hg) and diastolic (87 vs 78 mm Hg) blood pressures were detected among drivers exposed to traffic congestion compared with those who were not exposed (P<.001), while controlling for body mass index, age, sex, pack-year smoking, driving hours per week, and occupational driving. Moreover, among persons exposed to traffic congestion, longer exposure time was associated with higher systolic and diastolic blood pressures. Further studies are needed to better understand the mechanisms of the significant association between elevated blood pressure and traffic congestion. ©2017 Wiley Periodicals, Inc.

Deepwater carbonate ion concentrations in the western tropical Pacific since 250 ka: Evidence for oceanic carbon storage and global climate influence

NASA Astrophysics Data System (ADS)

Qin, Bingbin; Li, Tiegang; Xiong, Zhifang; Algeo, Thomas J.; Chang, Fengming

2017-04-01

We present new "size-normalized weight" (SNW)-Δ[CO32-] core-top calibrations for three planktonic foraminiferal species and assess their reliability as a paleo-alkalinity proxy. SNWs of Globigerina sacculifer and Neogloboquadrina dutertrei can be used to reconstruct past deep Pacific [CO32-], whereas SNWs of Pulleniatina obliquiloculata are controlled by additional environmental factors. Based on this methodological advance, we reconstruct SNW-based deepwater [CO32-] for core WP7 from the western tropical Pacific since 250 ka. Secular variation in the SNW proxy documents little change in deep Pacific [CO32-] between the Last Glacial Maximum and the Holocene. Further back in time, deepwater [CO32-] shows long-term increases from marine isotope stage (MIS) 5e to MIS 3 and from early MIS 7 to late MIS 6, consistent with the "coral reef hypothesis" that the deep Pacific Ocean carbonate system responded to declining shelf carbonate production during these two intervals. During deglaciations, we have evidence of [CO32-] peaks coincident with Terminations 2 and 3, which suggests that a breakdown of oceanic vertical stratification drove a net transfer of CO2 from the ocean to the atmosphere, causing spikes in carbonate preservation (i.e., the "deglacial ventilation hypothesis"). During MIS 4, a transient decline in SNW-based [CO32-], along with other reported [CO32-] and/or dissolution records, implies that increased deep-ocean carbon storage resulted in a global carbonate dissolution event. These findings provide new insights into the role of the deep Pacific in the global carbon cycle during the late Quaternary.

Influences on the stable oxygen and carbon isotopes in gerbillid rodent teeth in semi-arid and arid environments: Implications for past climate and environmental reconstruction

NASA Astrophysics Data System (ADS)

Jeffrey, Amy; Denys, Christiane; Stoetzel, Emmanuelle; Lee-Thorp, Julia A.

2015-10-01

The stable isotope composition of small mammal tissues has the potential to provide detailed information about terrestrial palaeoclimate and environments, because their remains are abundant in palaeontological and archaeological sites, and they have restricted home ranges. Applications to the Quaternary record, however, have been sparse and limited by an acute lack of understanding of small mammal isotope ecology, particularly in arid and semi-arid environments. Here we document the oxygen and carbon isotope composition of Gerbillinae (gerbil) tooth apatite across a rainfall gradient in northwestern Africa, in order to test the relative influences of the 18O/16O in precipitation or moisture availability on gerbil teeth values, the sensitivity of tooth apatite 13C/12C to plant responses to moisture availability, and the influence of developmental period on the isotopic composition of gerbil molars and incisors. The results show that the isotopic composition of molars and incisors from the same individuals differs consistent with the different temporal periods reflected by the teeth; molar teeth are permanently rooted and form around the time of birth, whereas incisors grow continuously. The results indicate that tooth choice is an important consideration for applications as proxy Quaternary records, but also highlights a new potential means to distinguish seasonal contexts. The oxygen isotope composition of gerbil tooth apatite is strongly correlated with mean annual precipitation (MAP) below 600 mm, but above 600 mm the teeth reflect the oxygen isotope composition of local meteoric water instead. Predictably, the carbon isotope composition of the gerbil teeth reflected C3 and C4 dietary inputs, however arid and mesic sites could not be distinguished because of the high variability displayed in the carbon isotope composition of the teeth due to the microhabitat and short temporal period reflected by the gerbil. We show that the oxygen isotope composition of small mammal teeth strongly reflects moisture availability in semi-arid and arid environments and would provide an excellent record of palaeo-aridity in a terrestrial setting. The results illustrate that an understanding of an animal's physiology is essential for interpreting the animal's isotopic responses to external contexts, especially in arid zones.

OMVPE Growth of Quaternary (Al,Ga,In)N for UV Optoelectronics (title change from A)

DOE Office of Scientific and Technical Information (OSTI.GOV)

HAN,JUNG; FIGIEL,JEFFREY J.; PETERSEN,GARY A.

We report the growth and characterization of quaternary AlGaInN. A combination of photoluminescence (PL), high-resolution x-ray diffraction (XRD), and Rutherford backscattering spectrometry (RBS) characterizations enables us to explore the contours of constant PL peak energy and lattice parameter as functions of the quaternary compositions. The observation of room temperature PL emission at 351nm (with 20% Al and 5% In) renders initial evidence that the quaternary could be used to provide confinement for GaInN (and possibly GaN). AlGaInN/GrdnN MQW heterostructures have been grown; both XRD and PL measurements suggest the possibility of incorporating this quaternary into optoelectronic devices.

Database and Map of Quaternary Faults and Folds in Peru and its Offshore Region

USGS Publications Warehouse

Machare, Jose; Fenton, Clark H.; Machette, Michael N.; Lavenu, Alain; Costa, Carlos; Dart, Richard L.

2003-01-01

This publication consists of a main map of Quaternary faults and fiolds of Peru, a table of Quaternary fault data, a region inset map showing relative plate motion, and a second inset map of an enlarged area of interest in southern Peru. These maps and data compilation show evidence for activity of Quaternary faults and folds in Peru and its offshore regions of the Pacific Ocean. The maps show the locations, ages, and activity rates of major earthquake-related features such as faults and fault-related folds. These data are accompanied by text databases that describe these features and document current information on their activity in the Quaternary.

Quaternary Geologic Map of Connecticut and Long Island Sound Basin

USGS Publications Warehouse

Stone, Janet Radway; Schafer, John P.; London, Elizabeth Haley; DiGiacomo-Cohen, Mary L.; Lewis, Ralph S.; Thompson, Woodrow B.

2005-01-01

The Quaternary geologic map (sheet 1) and explanatory figures and cross sections (sheet 2) portray the geologic features formed in Connecticut during the Quaternary Period, which includes the Pleistocene (glacial) and Holocene (postglacial) Epochs. The Quaternary Period has been a time of development of many details of the landscape and of all the surficial deposits. At least twice in the late Pleistocene, continental ice sheets swept across Connecticut. Their effects are of pervasive importance to the present occupants of the land. The Quaternary geologic map illustrates the geologic history and the distribution of depositional environments during the emplacement of glacial and postglacial surficial deposits and the landforms resulting from those events.

Factors controlling carbon isotopic composition of land snail shells estimated from lab culturing experiment

NASA Astrophysics Data System (ADS)

Zhang, Naizhong; Yamada, Keita; Yoshida, Naohiro

2014-05-01

Carbon isotopic composition (δ13C) of land snail shell carbonate is widely applied in reconstructing the C3/C4 vegetation distribution of paleo-environment, which is considered to reflect variations of some environmental parameters [1][2][3]. Land snail shell carbon has three potential sources: diet, atmospheric CO2 and ingested carbonate (limestone) [4]. However, their relative contributions to shell carbonate have not been understood well yet [4][5][6][7][8]. More researches are necessary before we could apply this tool in paleo-environment reconstruction, especially inter-lab culturing experiment. A kind of land snail species, Acusta despecta sieboldiana, was collected at Yokohama, Japan and cultured under suitable environment to lay eggs. The second generations were growing up from eggs to adults around 6-12 months at the temperature of 20°, 25° and 30°, respectively. All of the snails at 25° and 30° and most of those at 20° were fed by cabbage (C3 plant) during their life span while others were fed by corn (C4 plant). To investigate the effect of ingested carbonate, some of them were fed by Ca3(PO4)2 powder while others were fed by CaCO3 powder. δ13C of shells were analyzed by an Isotope Ratio Mass Spectrometry (Thermo Finnigan MAT 253); δ13C of food and snail tissue were measured by a Cavity Ring-Down Spectroscopy (Picarro G1121-i). At the same time, δ13C of eggshell and new born snails were analyzed by a Continuous Flow Isotope Ratio Mass Spectrometry (GasBench II). We confirmed that diet, atmospheric CO2 and ingested limestone could be important sources controlling shell δ13C values. And the temperature could affect shell carbonate δ13C values, too. A simple but credible frame was raised to discuss the mechanism of how each possible source and environmental parameter could affect shell carbonate δ13C values based on previous works [4][6][8] and this study. According to this frame and some reasonable assumptions, we have estimated the contribution of different carbon sources for each snail individual: to cabbage (C3 plant) fed groups, the contributions of diet, atmospheric CO2 and ingested limestone vary in a range of 66~80%, 16~24% and 0~13%, respectively. And to corn (C4 plant) fed groups, because of the possible food stress (lower consumption ability of C4 plant), they vary in 56~64%, 18~20% and 16~26%, respectively. We will discuss how these results could be consistent to the observations, which suggests our calculations are suitable and believable. In addition, we will discuss the carbon isotope fractionation during egg laying and hatching of land snails, too. [1] Goodfriend, 1992, Quaternary Sciences Reviews. 11, 665-685 [2] Yanes et al. 2009. Geochimica et Cosmochimica Acta, 73, 4077-4099 [3] Yanes et al., 2013. Palaeogeography, Plaeoclimatology, Palaeoecology, 378, 91-102 [4] Goodfriend and Hood, 1983. Radiocarbon, 25, 810-830 [5] Goodfriend and Stipp, 1983. Geology, 11, 575-577 [6] Stott, 2002. Earth and Planetary Science Letters, 195, 249-259 [7] Metref et al., 2003. Earth and Planetary Science Letters, 211, 381-393 [8] Romaniello et al., 2008. Quaternary Geochronology, 3, 68-75

Cold-water coral carbonate mounds as unique palaeo-archives: the Plio-Pleistocene Challenger Mound record (NE Atlantic)

NASA Astrophysics Data System (ADS)

Thierens, M.; Browning, E.; Pirlet, H.; Loutre, M.-F.; Dorschel, B.; Huvenne, V. A. I.; Titschack, J.; Colin, C.; Foubert, A.; Wheeler, A. J.

2013-08-01

Through the interplay of a stabilising cold-water coral framework and a dynamic sedimentary environment, cold-water coral carbonate mounds create distinctive centres of bio-geological accumulation in often complex (continental margin) settings. The IODP Expedition 307 drilling of the Challenger Mound (eastern Porcupine Seabight; NE Atlantic) not only retrieved the first complete developmental history of a coral carbonate mound, it also exposed a unique, Early-Pleistocene sedimentary sequence of exceptional resolution along the mid-latitudinal NE Atlantic margin. In this study, a comprehensive assessment of the Challenger Mound as an archive of Quaternary palaeo-environmental change and long-term coral carbonate mound development is presented. New and existing environmental proxy records, including clay mineralogy, planktonic foraminifer and calcareous nannofossil biostratigraphy and assemblage counts, planktonic foraminifer oxygen isotopes and siliciclastic particle-size, are thereby discussed within a refined chronostratigraphic and climatic context. Overall, the development of the Challenger Mound shows a strong affinity to the Plio-Pleistocene evolution of the Northern Hemisphere climate system, albeit not being completely in phase with it. The two major oceanographic and climatic transitions of the Plio-Pleistocene - the Late Pliocene/Early Pleistocene intensification of continental ice-sheet development and the mid-Pleistocene transition to the more extremely variable and more extensively glaciated late Quaternary - mark two major thresholds in Challenger Mound development: its Late Pliocene (>2.74 Ma) origin and its Middle-Late Pleistocene to recent decline. Distinct surface-water perturbations (i.e. water-mass/polar front migrations, productivity changes, melt-water pulses) are identified throughout the sequence, which can be linked to the intensity and extent of ice development on the nearby British-Irish Isles since the earliest Pleistocene. Glaciation-induced shifts in surface-water primary productivity are thereby proposed to fundamentally control cold-water coral growth, which in turn influences on-mound sediment accumulation and, hence, coral carbonate mound development throughout the Pleistocene. As local factors, such as proximal ice-sheet dynamics and on-mound changes in cold-water coral density, significantly affected the development of the Challenger Mound, they can potentially explain the nature of its palaeo-record and its offsets with the periodicities of global climate variability. On the other hand, owing to this unique setting, a regionally exceptional, high-resolution palaeo-record of Early Pleistocene (ca 2.6 to 2.1 Ma) environmental change (including early British-Irish ice-sheet development), broadly in phase with the 41 ka-paced global climate system, is preserved in the lower Challenger Mound. All in all, the Challenger Mound record highlights the wider relevance of coral carbonate mound archives and their potential to capture unique records from dynamic (continental margin) environments.

Congestion and flow control in signaling system No. 7: Impacts of intelligent networks and new services

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zepf, J.; Rufa, G.

1994-04-01

This paper focuses on the transient performance analysis of the congestion and flow control mechanisms in CCITT Signaling System No. 7 (SS7). Special attention is directed to the impacts of the introduction of intelligent services and new applications, e.g., Freephone, credit card services, user-to-user signaling, etc. In particular, we show that signaling traffic characteristics like signaling scenarios or signaling message length as well as end-to-end signaling capabilities have a significant influence on the congestion and flow control and, therefore, on the real-time signaling performance. One important result of our performance studies is that if, e.g., intelligent services are introduced, themore » SS7 congestion and flow control does not work correctly. To solve this problem, some reinvestigations into these mechanisms would be necessary. Therefore, some approaches, e.g., modification of the Signaling Connection Control Part (SCCP) congestion control, usage of the SCCP relay function, or a redesign of the MTP flow control procedures are discussed in order to guarantee the efficacy of the congestion and flow control mechanisms also in the future. 16 refs.« less

Diuretics as pathogenetic treatment for heart failure

PubMed Central

Guglin, Maya

2011-01-01

Increased intracardiac filling pressure or congestion causes symptoms and leads to hospital admissions in patients with heart failure, regardless of their systolic function. A history of hospital admission, in turn, predicts further hospitalizations and morbidity, and a higher number of hospitalizations determine higher mortality. Congestion is therefore the driving force of the natural history of heart failure. Congestion is the syndrome shared by heart failure with preserved and reduced systolic function. These two conditions have almost identical morbidity, mortality, and survival because the outcomes are driven by congestion. A small difference in favor of heart failure with preserved systolic function comes from decreased ejection fraction and left ventricular remodeling which is only present in heart failure with decreased systolic function. The magnitude of this difference reflects the contribution of decreased systolic function and ventricular remodeling to the progression of heart failure. The only treatment available for congestion is fluid removal via diuretics, ultrafiltration, or dialysis. It is the only treatment that works equally well for heart failure with reduced and preserved systolic function because it affects congestion, the main pathogenetic feature of the disease. Diuretics are pathogenetic therapy for heart failure. PMID:21403798

Congestive heart failure in subjects with thyrotoxicosis in a black community

PubMed Central

Anakwue, R C; Onwubere, B J C; Anisiuba, B C; Ikeh, V O; Mbah, A; Ike, S O

2010-01-01

Introduction: Thyroid hormone has profound effects on a number of metabolic processes in virtually all tissues but the cardiovascular manifestations are prominent usually creating a hyperdynamic circulatory state. Thyrotoxicosis is not a common cause of congestive heart failure among black communities. Objectives: To determine the hospital prevalence, clinical characteristics and echocardiographic findings in patients with thyrotoxicosis who present with congestive heart failure (CCF) in the eastern part of Nigeria. Subjects and methods: A total of 50 subjects aged 15 years and above who were diagnosed as thyrotoxic following clinical and thyroid function tests were consecutively recruited. Fifty age- and sex-matched controls with no clinical or biochemical evidence of thyrotoxicosis and no comorbidities were used as controls. Two-dimensional echocardiography was carried out on all the subjects. CCF was determined clinically and echocardiographically. Results: Eight patients (5 females and 3 males) out of a total of 50 thyrotoxic patients presented with congestive heart failure. Conclusion: The study revealed that congestive heart failure can occur in thyrotoxicosis in spite of the associated hyperdynamic condition. The underlying mechanism may include direct damage by autoimmune myocarditis, congestive circulation secondary to excess sodium, and fluid retention. PMID:20730063

Synthesis and anticoagulant activity of the quaternary ammonium chitosan sulfates.

PubMed

Fan, Lihong; Wu, Penghui; Zhang, Jinrong; Gao, Song; Wang, Libo; Li, Mingjia; Sha, Mingming; Xie, Weiguo; Nie, Min

2012-01-01

Quaternary ammonium chitosan sulfates with diverse degrees of substitution (DS) ascribed to sulfate groups between 0.52 and 1.55 were synthesized by reacting quaternary ammonium chitosan with an uncommon sulfating agent (N(SO(3)Na)(3)) that was prepared from sodium bisulfite (NaHSO(3)) through reaction with sodium nitrite (NaNO(2)) in the aqueous system homogeneous. The structures of the derivatives were characterized by FTIR, (1)H NMR and (13)C NMR. The factors affecting DS of quaternary ammonium chitosan sulfates which included the molar ratio of NaNO(2) to quaternary ammonium chitosan, sulfated temperature, sulfated time and pH of sulfated reaction solution were investigated in detail. Its anticoagulation activity in vitro was determined by an activated partial thromboplastin time (APTT) assay, a thrombin time (TT) assay and a prothrombin time (PT) assay. Results of anticoagulation assays showed quaternary ammonium chitosan sulfates significantly prolonged APTT and TT, but not PT, and demonstrated that the introduction of sulfate groups into the quaternary ammonium chitosan structure improved its anticoagulant activity obviously. The study showed its anticoagulant properties strongly depended on its DS, concentration and molecular weight. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

Leech Therapy For The Treatment Of Venous Congestion In Flaps, Digital Re-Plants And Revascularizations - A Two-Year Review From A Regional Centre.

PubMed

Butt, Ahsan Masood; Ismail, Amir; Lawson-Smith, Matthew; Shahid, Muhammad; Webb, Jill; Chester, Darren L

2016-01-01

Leeches are a well-recognized treatment for congested tissue. This study reviewed the efficacy of leech therapy for salvage of venous congested flaps and congested replanted or revascularized hand digits over a 2-year period. All patients treated with leeches between 1 Oct 2010 and 30 Sep 2012 (two years) at Queen Elizabeth Hospital, Birmingham, UK were included in the study. Details regarding mode of injury requiring reconstruction, surgical procedure, leech therapy duration, subsequent surgery requirement and tissue salvage rates were recorded. Twenty tissues in 18 patients required leeches for tissue congestion over 2 years: 13 men and 5 women. The mean patient age was 41 years (range 17-79). The defect requiring reconstruction was trauma in 16 cases, following tumour resection in two, and two miscellaneous causes. Thirteen cases had flap reconstruction and seven digits in six patients had hand digit replantations or revascularisation. Thirteen of 20 cases (65%) had successful tissue salvage following leech therapy for congestion (77% in 10 out of 13 flaps, and 43% in 3 of 7 digits). The rate of tissue salvage in pedicled flaps was good 6/6 (100%) and so was in digital revascularizations 2/3 (67%), but poor in digital re-plants 1/4 (25%) and free flaps 0/2 (0%). Leeches are a helpful tool for congested tissue salvage and in this study, showed a greater survival benefit for pedicled flaps than for free flaps or digital replantations.

Plasmapheresis affects responses of slowly and rapidly adapting airway receptors to pulmonary venous congestion in dogs.

PubMed Central

Kappagoda, C T; Ravi, K

1989-01-01

1. The effects of plasmapheresis on the responses of rapidly adapting receptors (RARs) and slowly adapting receptors (SARs) of the airways to pulmonary venous congestion were examined in dogs anaesthetized with alpha-chloralose. Pulmonary venous congestion was produced in a graded manner by partial obstruction of the mitral valve sufficient to raise the mean left atrial pressure by 5, 10 and 15 mmHg. Plasmapheresis was performed by withdrawing 10% of blood volume twice. 2. Both RARs (n = 11) and SARs (n = 5) responded to pulmonary venous congestion by increasing their activities. The responses of the former were proportionately greater. 3. After plasmapheresis which reduced the concentration of plasma proteins by 12.3 +/- 1.0%, the responses of the RARs to pulmonary venous congestion were enhanced significantly. There was no significant change in the responses of SARs. 4. In another set of six RARs, the effects of graded pulmonary venous congestion were investigated twice with an interval of 45 min between the two observations. No significant differences were noted between the two responses. 5. Collection of lymph from the tracheobronchial lymph duct (n = 6) showed that after plasmapheresis, there was an increase in the control lymph flow. In addition, the lymph flow was enhanced during pulmonary venous congestion (mean left atrial pressure increased by 10 mmHg). 6. It is suggested that a natural stimulus for the excitation of the RAR is a function of the fluid fluxes in the pulmonary extravascular space. PMID:2607464

Antimicrobial Polymeric Materials with Quaternary Ammonium and Phosphonium Salts

PubMed Central

Xue, Yan; Xiao, Huining; Zhang, Yi

2015-01-01

Polymeric materials containing quaternary ammonium and/or phosphonium salts have been extensively studied and applied to a variety of antimicrobial-relevant areas. With various architectures, polymeric quaternary ammonium/phosphonium salts were prepared using different approaches, exhibiting different antimicrobial activities and potential applications. This review focuses on the state of the art of antimicrobial polymers with quaternary ammonium/phosphonium salts. In particular, it discusses the structure and synthesis method, mechanisms of antimicrobial action, and the comparison of antimicrobial performance between these two kinds of polymers. PMID:25667977

C2-Selective Branched Alkylation of Benzimidazoles by Rhodium(I)-Catalyzed C-H Activation.

PubMed

Tran, Gaël; Confair, Danielle; Hesp, Kevin D; Mascitti, Vincent; Ellman, Jonathan A

2017-09-01

Herein, we report a Rh(I)/bisphosphine/K 3 PO 4 catalytic system allowing for the first time the selective branched C-H alkylation of benzimidazoles with Michael acceptors. Branched alkylation with N,N-dimethyl acrylamide was successfully applied to the alkylation of a broad range of benzimidazoles incorporating a variety of N-substituents and with both electron-rich and -poor functionality displayed at different sites of the arene. Moreover, the introduction of a quaternary carbon was achieved by alkylation with ethyl methacrylate. The method was also shown to be applicable to the C2-selective branched alkylation of azabenzimidazoles.

The geology of Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.

2015-01-01

Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.

Scaffold Diversity Synthesis Delivers Complex, Structurally, and Functionally Distinct Tetracyclic Benzopyrones

PubMed Central

Sankar, Muthukumar G.; Roy, Sayantani; Tran, Tuyen Thi Ngoc; Wittstein, Kathrin; Bauer, Jonathan O.; Strohmann, Carsten; Ziegler, Slava

2018-01-01

Abstract Complexity‐generating chemical transformations that afford novel molecular scaffolds enriched in sp 3 character are highly desired. Here, we present a highly stereoselective scaffold diversity synthesis approach that utilizes cascade double‐annulation reactions of diverse pairs of zwitterionic and non‐zwitterionic partners with 3‐formylchromones to generate highly complex tetracyclic benzopyrones. Each pair of annulation partners adds to the common chroman‐4‐one scaffold to build two new rings, supporting up to four contiguous chiral centers that include an all‐carbon quaternary center. Differently ring‐fused benzopyrones display different biological activities, thus demonstrating their immense potential in medicinal chemistry and chemical biology research. PMID:29721402

14 CFR 105.21 - Parachute operations over or into a congested area or an open-air assembly of persons.

Code of Federal Regulations, 2010 CFR

2010-01-01

... congested area or an open-air assembly of persons. 105.21 Section 105.21 Aeronautics and Space FEDERAL...-air assembly of persons. (a) No person may conduct a parachute operation, and no pilot in command of... congested area of a city, town, or settlement, or an open-air assembly of persons unless a certificate of...

Airport Characterization for the Adaptation of Surface Congestion Management Approaches

DTIC Science & Technology

2013-02-01

Surface Congestion Management Program at New York JFK airport [6,7], the human-in-the-loop simulations of the Spot and Runway Departure Advisor...a surface congestion management technique at New York JFK airport ,” AIAA Aviation Technology, Integration and Operations (ATIO) Conference...Virginia Beach, VA, September 2011. [7] S. Stroiney, H. Khadilkar and H. Balakrishnan, “Ground Management Program at JFK Airport : Implementation and

Reduction of fuel consumption and exhaust pollutant using intelligent transport systems.

PubMed

Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M A; Masum, B M

2014-01-01

Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NO x ). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment.

Reduction of Fuel Consumption and Exhaust Pollutant Using Intelligent Transport Systems

PubMed Central

Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M. A.; Masum, B. M.

2014-01-01

Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NOx). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment. PMID:25032239

Improved low temperature performance of lithium ion cells with quaternary carbonate-based electrolytes

NASA Technical Reports Server (NTRS)

Smart, M. C.; Ratnakumar, B. V.; Whitcanack, L. D.; Chin, K. B.; Surampudi, S.; Croft, H.; Tice, D.; Staniewicz, R.

2002-01-01

In order to enable future missions involving the exploration of the surface of Mars with Landers and Rovers, NASA desires long life, high energy density rechargeable batteries which can operate well at very low temperature (down to 40(deg)C). Lithium-ion technology has been identified as being the most promising chemistry, due to high gravimetric and volumetric energy densities, as well as, long life characteristics. However, the state-of-art (SOA) technology is not sufficient to meet the needs of many applications that require excellent low temperature capabilities. To further improve this technology, work at JF'L has been focused upon developing electrolytes that result in lithium-ion cells with wider temperature ranges of operation. These efforts have led to the identification of a number of ternary and quaternary, all carbonate-based electrolytes that have been demonstrated to result in improved low temperature performance in experimental three-electrode MCMB carbon/LiNio.sCoo.zOz cells. A number of electrochemical characterization techniques were performed on these cells (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further enhance our understanding of the performance limitations at low temperature. The most promising electrolyte formulations, namely 1 .O M LiPF6EC+DEC+DMC+EMC (1 : 1: 1 :2 v/v) and 1 .O M LiPF6 EC+DEC+DMC+EMC (1 : 1 : 1 :3 v/v), were incorporated into SAFT prototype DD-size (9 Ahr) lithium- cells for evaluation. A number of electrical tests were performed on these cells, including rate characterization as a function of temperature, cycle life characterization at different temperatures, as well as, many mission specific characterization test to determine their viability to enable future missions to Mars. Excellent performance was observed with the prototype DD-size cells over a wide temperature range (-50 to 4OoC), with high specific energy being delivered at very low temperatures (i.e, over 95 WHrKg being delivered at 40(deg)C using a C/10 discharge rate).

The story of landscape evolution in Lower Austria told by sedimentological analysis and luminescence dating

NASA Astrophysics Data System (ADS)

Hofer, Ingo; Thiel, Christine; Terhorst, Birgit; Jaburova, Iva; Buylaert, Jan-Pieter; Murray, Andrew; Frechen, Manfred

2010-05-01

Loess/palaeosol sequences contain detailed information about palaeoenvironmental changes during the Quaternary. Furthermore, because of its long distance aeolian transport, which resets the luminescence signal to zero prior to deposition, loess is highly suitable for luminescence dating. This allows the determination of geodynamic processes with time. The loess deposits in the Kremser Feld (Lower Austria) are up to 30 m thick. The loess/paleosol sequence of Stratzing is situated at the eastern margin of the west-east elongated hill of the ‘Galgenberg'; this location is famous for its archaeological finds, e.g. the sculpture "Fanny", one of the oldest identifiable representations of the human figure (Neugebauer-Maresch, 1993). The loess profile examined here has a total depth of 7.5 m and is subdivided into 19 prominent horizons. For each horizon the grain size distribution, pH-value, total carbonate content, total organic content and sulphur content was derived in order to reconstruct the environmental conditions leading to sedimentation and soil formation. To set up a geochronological framework for the loess deposition and the subsequent soil formation, nine samples were dated by means of elevated temperature post-IR IRSL (Thiel et al., submitted). Besides a general discussion about the sedimentological data we will discuss horizon 18 in more detail; this is a paleosol rich in clay and poor in mineralic carbonate. The sulphur content is relatively high and indicates higher humidity and warmer climate, all making the unexpectedly low organic carbon content of particular interest. The luminescence ages reveal an important hiatus above this well-developed palaeosol (from ~ 100 to ~ at least 200 ka) clearly showing that this loess/palaeosol sequence is not a continuous record. This implies either significant erosion or lack of loess deposition in this area. Neugebauer-Maresch, C., 1993. Kunst und geistige Welt. - In: Neugebauer-Maresch, C., (ed): Altsteinzeit im Osten Österreichs. Wissenschaftliche Schriftenreihe Niederösterreich 95/96/97 (St. Pölten). Thiel, C., Buylaert, J. P., Terhorst, B., Murray, A. S., Hofer, I., Tsukamoto, S., Frechen, M., submitted. Luminescence dating of the Stratzing loess profile (Austria) - Testing the potential of an elevated temperature post-IR IRSL protocol. Quaternary International.

Glacial versus interglacial sedimentation rates and turbidite frequency in the Bahamas

NASA Astrophysics Data System (ADS)

Droxler, Andre W.; Schlager, Wolfgang

1985-11-01

The southern Tongue of the Ocean is a 1300-m-deep, flat-floored basin in the Bahamas that receives large amounts of sediment from the carbonate platforms surrounding it on three sides. We have examined five 8 13-m-long piston cores and determined bulk sedimentation rates, turbidite frequency, and turbidite accumulation rates for the past two glacial and interglacial periods. The mean of bulk sedimentation rates is four to six times higher in interglacial periods; average accumulation rates of recognizable turbidites are higher by a factor of 21 to 45, and interglacial turbidite frequency is higher by a factor of 6 to 14. Sediment composition indicates that increased interglacial rates are due to higher accumulation of platform-derived material. Additional data from other Bahamian basins as well as published material from the Caribbean strongly suggest that highstand shedding is a general trend in pure carbonate depositional systems. Carbonate platforms without a siliciclastic component export more material during highstands of sea level when the platform tops are flooded and produce sediment. The response of carbonate platforms to Quaternary sea-level cycles is opposed to that of siliciclastic ocean margins, where sediment is stored on the inner shelf during highstands and passed on to continental rises and abyssal plains during lowstands of sea level.

Geologic map of the White Hall quadrangle, Frederick County, Virginia, and Berkeley County, West Virginia

USGS Publications Warehouse

Doctor, Daniel H.; Orndorff, Randall C.; Parker, Ronald A.; Weary, David J.; Repetski, John E.

2010-01-01

The White Hall 7.5-minute quadrangle is located within the Valley and Ridge province of northern Virginia and the eastern panhandle of West Virginia. The quadrangle is one of several being mapped to investigate the geologic framework and groundwater resources of Frederick County, Va., as well as other areas in the northern Shenandoah Valley of Virginia and West Virginia. All exposed bedrock outcrops are clastic and carbonate strata of Paleozoic age ranging from Middle Cambrian to Late Devonian. Surficial materials include unconsolidated alluvium, colluvium, and terrace deposits of Quaternary age, and local paleo-terrace deposits possibly of Tertiary age. The quadrangle lies across the northeast plunge of the Great North Mountain anticlinorium and includes several other regional folds. The North Mountain fault zone cuts through the eastern part of the quadrangle; it is a series of thrust faults generally oriented northeast-southwest that separate the Silurian and Devonian clastic rocks from the Cambrian and Ordovician carbonate rocks and shales. Karst development in the quadrangle occurs in all of the carbonate rocks. Springs occur mainly near or on faults. Sinkholes occur within all of the carbonate rock units, especially where the rocks have undergone locally intensified deformation through folding, faulting, or some combination.

Performance analysis of SS7 congestion controls under sustained overload

NASA Astrophysics Data System (ADS)

Manfield, David R.; Millsteed, Gregory K.; Zukerman, Moshe

1994-04-01

Congestion controls are a key factor in achieving the robust performance required of common channel signaling (CCS) networks in the face of partial network failures and extreme traffic loads, especially as networks become large and carry high traffic volume. The CCITT recommendations define a number of types of congestion control, and the parameters of the controls must be well set in order to ensure their efficacy under transient and sustained signalling network overload. The objective of this paper is to present a modeling approach to the determination of the network parameters that govern the performance of the SS7 congestion controls under sustained overload. Results of the investigation by simulation are presented and discussed.

The role of Quaternary environmental change in plant macroevolution: the exception or the rule?

PubMed Central

Willis, Katherine J; Niklas, Karl J

2004-01-01

The Quaternary has been described as an important time for genetic diversification and speciation. This is based on the premise that Quaternary climatic conditions fostered the isolation of populations and, in some instances, allopatric speciation. However, the 'Quaternary Ice-Age speciation model' rests on two key assumptions: (i) that biotic responses to climate change during the Quaternary were significantly different from those of other periods in Earth's history; and (ii) that the mechanisms of isolation during the Quaternary were sufficient in time and space for genetic diversification to foster speciation. These assumptions are addressed by examining the plant fossil record for the Quaternary (in detail) and for the past 410 Myr, which encompasses previous intervals of icehouse Earth. Our examination of the Quaternary record indicates that floristic responses to climate changes during the past 1.8 Myr were complex and that a distinction has to be made between those plants that were able to withstand the extremes of glacial conditions and those that could not. Generation times are also important as are different growth forms (e.g. herbaceous annuals and arborescent perennials), resulting in different responses in terms of genetic divergence rates during isolation. Because of these variations in the duration of isolation of populations and genomic diversification rates, no canonical statement about the predominant floristic response to climatic changes during the Quaternary (i.e. elevated rates of speciation or extinction, or stasis) is currently possible. This is especially true because of a sampling bias in terms of the fossil record of tree species over that of species with non-arborescent growth forms. Nevertheless, based on the available information, it appears that the dominant response of arborescent species during the Quaternary was extinction rather than speciation or stasis. By contrast, our examination of the fossil record of vascular plants for the past 410 Myr indicates that speciation rates often increased during long intervals of icehouse Earth (spanning up to 50 Myr). Therefore, longer periods of icehouse Earth than those occurring during the Quaternary may have isolated plant populations for sufficiently long periods of time to foster genomic diversification and allopatric speciation. Our results highlight the need for more detailed study of the fossil record in terms of finer temporal and spatial resolution than is currently available to examine the significance of intervals of icehouse Earth. It is equally clear that additional and detailed molecular studies of extant populations of Quaternary species are required in order to determine the extent to which these 'relic' species have genomically diversified across their current populations. PMID:15101573

Performance Analysis on the Coexistence of Multiple Cognitive Radio Networks

DTIC Science & Technology

2015-05-28

the scarce spectrum resources. Cognitive radio is a key in minimizing the spectral congestion through its adaptability, where the radio parameters...static allocation of spectrum results in congestion in some parts of the spectrum and non use in some others, therefore, spectra utilization is...well as the secondary user (SU) activities in multiple CR networks. It is shown that the scheduler provided much needed gain during congestions . However

CONGESTIVE HEART FAILURE ASSOCIATED WITH PREGNANCY IN OKAPI (OKAPIA JOHNSTONI).

PubMed

Warren, Joshua D; Aitken-Palmer, Copper; Weldon, Alan D; Flanagan, Joseph P; Howard, Lauren L; Garner, Michael M; Citino, Scott B

2017-03-01

Acute signs associated with cardiovascular disease occurred in three pregnant okapi ( Okapia johnstoni ) during early to midgestation and progressed to congestive heart failure. Congestive heart failure was diagnosed antemortem using echocardiography and plasma cardiac troponin levels. Clinical signs included decreased activity, hyporexia, tachypnea, dyspnea, flared nostrils, and productive coughing with copious amounts of foamy nasal discharge. Parenteral and oral treatment with furosemide, enalapril, and spironolactone controlled clinical signs in the three okapi allowing each to carry out one pregnancy to term. Two okapi carried the first pregnancy to term after showing signs, while one okapi aborted the first calf and gave birth to a healthy calf in a subsequent pregnancy. Subsequent pregnancy in one okapi ended with abortion and associated dystocia and endometritis. Following parturition, clinical signs associated with heart failure resolved in all three individuals; serial echocardiography in two individuals showed improvement in fractional shortening and left atrial size and all three okapi showed markedly decreased pleural effusion and resolution of pulmonary edema. However, subsequent pregnancies in all three okapi induced respiratory distress and recurrence of congestive heart failure; one okapi died from congestive heart failure associated with subsequent pregnancy. This case series describes the clinical presentation and pathologic findings of congestive heart failure during pregnancy in adult okapi.

Liver Function in Areas of Hepatic Venous Congestion After Hepatectomy for Liver Cancer: 99mTc-GSA SPECT/CT Fused Imaging Study.

PubMed

Yoshida, Morikatsu; Beppu, Toru; Shiraishi, Shinya; Tsuda, Noriko; Sakamoto, Fumi; Kuramoto, Kunitaka; Okabe, Hirohisa; Nitta, Hidetoshi; Imai, Katsunori; Tomiguchi, Seiji; Baba, Hideo; Yamashita, Yasuyuki

2018-05-01

Background/Aim: The sacrifice of a major hepatic vein can cause hepatic venous congestion (HVC). We evaluated the effects of HVC on regional liver function using the liver uptake value (LUV), that was calculated from 99m Tc-labeled-galactosyl-human-serum-albumin ( 99m Tc-GSA) single-photon emission computed tomography (SPECT) /contrast-enhanced computed tomography (CE-CT) fused images. Patients and Methods: Sixty-two patients underwent 99m Tc-GSA SPECT/CE-CT prior to hepatectomy for liver cancer and at 7 days after surgery were divided into groups with (n=8) and without HVC (n=54). In the HVC group, CT volume (CTv) and LUV were separately calculated in both congested and non-congested areas. Results: The remnant LUV/CTv of the HVC group was significantly smaller than that of the non-HVC group (p<0.01). The mean functional ratio was 0.47±0.05, and all ratios were ≥0.39. Conclusion: After hepatectomy with sacrifice of major hepatic vein, liver function per unit volume in the congested areas was approximately 40% of that in the non-congested areas. Copyright© 2018, International Institute of Anticancer Research (Dr. George J. Delinasios), All rights reserved.

SE Great Basin Play Fairway Analysis

DOE Data Explorer

Adam Brandt

2015-11-15

Within this submission are multiple .tif images with accompanying metadata of magnetotelluric conductor occurrence, fault critical stress composite risk segment (CRS), permeability CRS, Quaternary mafic extrusions, Quaternary fault density, and Quaternary rhyolite maps. Each of these contributed to a final play fairway analysis (PFA) for the SE Great Basin study area.

Attitudes, perceptions and awareness concerning quaternary prevention among family doctors working in the Social Security System, Peru: a cross-sectional descriptive study.

PubMed

Cuba Fuentes, María Sofía; Zegarra Zamalloa, Carlos Orlando; Reichert, Sonja; Gill, Dawn

2016-04-27

Quaternary Prevention is defined as the action taken to identify patients at risk of overtreatment, to protect them from additional medical treatments, and to suggest interventions that are ethically acceptable. Many countries and organizations have joined in the efforts to practice quaternary prevention. These countries started a campaign called Choosing Wisely that implements recommendations in order to avoid harming patients. To determine the attitudes, perceptions and awareness towards Quaternary Prevention and the practice of “Choosing Wisely Canada Recommendations” among family doctors working in the Social Security System in Peru. A questionnaire was developed after reviewing the literature and contacting experts in the field and was sent by email to all 64 family physicians in the Social Security System (Essalud) in Lima Peru. Responses were received from 40 participants. The response rate was 64%. Approximately 95% reported that they understand the concept of quaternary prevention. Agreement with all the recommendations was 90% or higher. In most of the recommendations the applicability was more than 80%. The most important barriers perceived for the practice of Quaternary Prevention were patients’ expectations (33%). There are positive perceptions towards Quaternary Preventions and Choosing Wisely recommendations in the family doctors of social security in Lima Peru.

The Devil's Hole Is In The Details

NASA Astrophysics Data System (ADS)

Wallace, M. G.

2012-12-01

As the granularity of Quaternary paleoclimatic proxy signatures from continental and oceanic sources continues to resolve, increasingly integrated studies such as Shakun et. al. (2012), and Kohfeld and Ridgewell (2009) have emerged, with far-reaching but sometimes conflicting paleo-global climate interpretations. Accordingly, none of the competing empirical and phenomenological narratives regarding the time series of Quaternary temperature patterns fit with sufficient fidelity to the observational record. Among other examples, the Shakun et al. study reviewed and processed 80 proxy sites worldwide for paleotemperature reconstruction, but left out the premier Devil's Hole poxy site in the continental Southwestern U.S. The Devil's Hole site presents a nominally earlier record of an interglacial warming signal (Landwehr and Winograd 2012). Both cite similar data (NOAA, 2005) as confirmation of their competing interpretations. Clearly both cannot be right. Epistemic origins of this apparent conflict may be rooted on the ongoing controversy concerning the importance of orbital forcings to the 100K year Quaternary glacial oscillations. Orbital forcings had been intrinsically posited as the only possible extraterrestrial driver of global temperature cycles over the Quaternary time frame. Yet other extraterrestrial climate forcing parameters are now conceivable. This paper reexamines past 3He marine core measurements conducted on two oceans and two hemispheres, and alternatives to the associated interpretations of researchers Patterson and Farley (1998). This study includes a new phenomenological and empirical exploration of an alternate extraterrestrial Quaternary global climate forcing model. This new interpretation is possible based on improved mapping of the Local Interstellar Medium (ISM), as documented in recent works such as those by Frisch and Mueller (2011). References: Frisch, P.C., and HR Mueller, 2011, Time-Variability in the Interstellar Boundary Conditions of the Heliosphere: Effect of the Solar Journey on the Galactic Cosmic Ray Flux at Earth. Space Science Review DOI 10.1007/s11214-011-9766-x. Kohfeld, Karen E., and Andy Ridgewell, 2009, "Glacial-Interglacial Variability in Atmospheric CO2", Surface Ocean-Lower Atmosphere Processes Geophysical Research Series 187, pp. 251-286. Landwehr, J.M., Sharp, W.D., Coplen, T.B., Ludwig, K.R., and Winograd, I.J., 2011, "The chronology for the δ18O record from Devil's Hole, Nevada, extended into the mid-Holocene: U.S. Geological Survey Open-File Report 2011-1082, 5 p. NOAA Paleoclimatology Program - Paleocean Site Data. tr163-19_ssts-fwc.txt # SST data only # File Created: 19-Jan-2005. ftp://ftp.ncdc.noaa.gov/pub/data/paleo/paleocean/sediment_files/sst/tr163-19_ssts-fwc.txt. Patterson, DB, and Farley, KA (1998): Extraterrestrial 3He in seafloor sediments: Evidence for correlated 100 kyr periodicity in the accretion rate of interplanetary dust, orbital parameters, and Quaternary climate. Geochimica et Cosmochimica Acta, 62(23-24), 3669-3682. Shakun, Jeremy D. , Peter U. Clark, Feng He, Shaun A. Marcott, Alan C. Mix, Zhengyu Liu, Bette Otto-Bliesner, Andreas Schmittner & Edouard Bard, 2012, "Global warming preceded by increasing carbon dioxide concentrations during the last deglaciation" Nature Vol 484. pp 49-55.

Topical nasal decongestant oxymetazoline (0.05%) provides relief of nasal symptoms for 12 hours.

PubMed

Druce, H M; Ramsey, D L; Karnati, S; Carr, A N

2018-05-22

Nasal congestion, often referred to as stuffy nose or blocked nose is one of the most prevalent and bothersome symptoms of an upper respiratory tract infection. Oxymetazoline, a widely used intranasal decongestant, offers fast symptom relief, but little is known about the duration of effect. The results of 2 randomized, double-blind, vehicle-controlled, single-dose, parallel, clinical studies (Study 1, n=67; Study 2, n=61) in which the efficacy of an oxymetazoline (0.05% Oxy) nasal spray in patients with acute coryzal rhinitis was assessed over a 12-hour time-period. Data were collected on both subjective relief of nasal congestion (6-point nasal congestion scale) and objective measures of nasal patency (anterior rhinomanometry) in both studies. A pooled study analysis showed statistically significant changes from baseline in subjective nasal congestion for 0.05% oxymetazoline and vehicle at each hourly time-point from Hour 1 through Hour 12 (marginally significant at Hour 11). An objective measure of nasal flow was statistically significant at each time-point up to 12 hours. Adverse events on either treatment were infrequent. The number of subjects who achieved an improvement in subjective nasal congestion scores of at least 1.0 was significantly higher in the Oxy group vs. vehicle at all hourly time-points on a 6-point nasal congestion scale. This study shows for the first time, that oxymetazoline provides both statistically significant and clinically meaningful relief of nasal congestion and improves nasal airflow for up to 12 hours following a single dose.

Time allocation shifts and pollutant exposure due to traffic congestion: an analysis using the national human activity pattern survey.

PubMed

Zhang, Kai; Batterman, Stuart A

2009-10-15

Traffic congestion increases air pollutant exposures of commuters and urban populations due to the increased time spent in traffic and the increased vehicular emissions that occur in congestion, especially "stop-and-go" traffic. Increased time in traffic also decreases time in other microenvironments, a trade-off that has not been considered in previous time activity pattern (TAP) analyses conducted for exposure assessment purposes. This research investigates changes in time allocations and exposures that result from traffic congestion. Time shifts were derived using data from the National Human Activity Pattern Survey (NHAPS), which was aggregated to nine microenvironments (six indoor locations, two outdoor locations and one transport location). After imputing missing values, handling outliers, and conducting other quality checks, these data were stratified by respondent age, employment status and period (weekday/weekend). Trade-offs or time-shift coefficients between time spent in vehicles and the eight other microenvironments were then estimated using robust regression. For children and retirees, congestion primarily reduced the time spent at home; for older children and working adults, congestion shifted the time spent at home as well as time in schools, public buildings, and other indoor environments. Changes in benzene and PM(2.5) exposure were estimated for the current average travel delay in the U.S. (9 min day(-1)) and other scenarios using the estimated time shifts coefficients, concentrations in key microenvironments derived from the literature, and a probabilistic analysis. Changes in exposures depended on the duration of the congestion and the pollutant. For example, a 30 min day(-1) travel delay was determined to account for 21+/-12% of current exposure to benzene and 14+/-8% of PM(2.5) exposure. The time allocation shifts and the dynamic approach to TAPs improve estimates of exposure impacts from congestion and other recurring events.

Analysis of Aircraft Clusters to Measure Sector-Independent Airspace Congestion

NASA Technical Reports Server (NTRS)

Bilimoria, Karl D.; Lee, Hilda Q.

2005-01-01

The Distributed Air/Ground Traffic Management (DAG-TM) concept of operations* permits appropriately equipped aircraft to conduct Free Maneuvering operations. These independent aircraft have the freedom to optimize their trajectories in real time according to user preferences; however, they also take on the responsibility to separate themselves from other aircraft while conforming to any local Traffic Flow Management (TFM) constraints imposed by the air traffic service provider (ATSP). Examples of local-TFM constraints include temporal constraints such as a required time of arrival (RTA), as well as spatial constraints such as regions of convective weather, special use airspace, and congested airspace. Under current operations, congested airspace typically refers to a sector(s) that cannot accept additional aircraft due to controller workload limitations; hence Dynamic Density (a metric that is indicative of controller workload) can be used to quantify airspace congestion. However, for Free Maneuvering operations under DAG-TM, an additional metric is needed to quantify the airspace congestion problem from the perspective of independent aircraft. Such a metric would enable the ATSP to prevent independent aircraft from entering any local areas of congestion in which the flight deck based systems and procedures may not be able to ensure separation. This new metric, called Gaggle Density, offers the ATSP a mode of control to regulate normal operations and to ensure safety and stability during rare-normal or off-normal situations (e.g., system failures). It may be difficult to certify Free Maneuvering systems for unrestricted operations, but it may be easier to certify systems and procedures for specified levels of Gaggle Density that could be monitored by the ATSP, and maintained through relatively minor flow-rate (RTA type) restrictions. Since flight deck based separation assurance is airspace independent, the challenge is to measure congestion independent of sector boundaries. Figure 1 , reproduced from Ref. 1, depicts an example traffic situation. When the situation is analyzed by sector boundaries (left side of figure), a Dynamic Density metric would identify excessive congestion in the central sector. When the same traffic situation is analyzed independent of sector boundaries (right side of figure), a Gaggle Density metric would identify congestion in two dynamically defined areas covering portions of several sectors. The first step towards measuring airspace-independent congestion is to identify aircraft clusters, i.e., groups of closely spaced aircraft. The objective of this work is to develop techniques to detect and classify clusters of aircraft.

Risk of venous congestion in live donors of extended right liver graft

PubMed Central

Radtke, Arnold; Sgourakis, George; Molmenti, Ernesto P; Beckebaum, Susanne; Cicinnati, Vito R; Schmidt, Hartmut; Peitgen, Heinz-Otto; Broelsch, Christoph E; Malagó, Massimo; Schroeder, Tobias

2015-01-01

AIM: To investigate middle hepatic vein (MHV) management in adult living donor liver transplantation and safer remnant volumes (RV). METHODS: There were 59 grafts with and 12 grafts without MHV (including 4 with MHV-5/8 reconstructions). All donors underwent our five-step protocol evaluation containing a preoperative protocol liver biopsy Congestive vs non-congestive RV, remnant-volume-body-weight ratios (RVBWR) and postoperative outcomes were evaluated in 71 right graft living donors. Dominant vs non-dominant MHV anatomy in total liver volume (d-MHV/TLV vs nd-MHV/TLV) was constellated with large/small congestion volumes (CV-index). Small for size (SFS) and non-SFS remnant considerations were based on standard cut-off- RVBWR and RV/TLV. Non-congestive RVBWR was based on non-congestive RV. RESULTS: MHV and non-MHV remnants showed no significant differences in RV, RV/TLV, RVBWR, total bilirubin, or INR. SFS-remnants with RV/TLV < 30% and non-SFS-remnants with RV/TLV ≥ 30% showed no significant differences either. RV and RVBWR for non-MHV (n = 59) and MHV-containing (n = 12) remnants were 550 ± 95 mL and 0.79 ± 0.1 mL vs 568 ± 97 mL and 0.79 ± 0.13, respectively (P = 0.423 and P = 0.919. Mean left RV/TLV was 35.8% ± 3.9%. Non-MHV (n = 59) and MHV-containing (n = 12) remnants (34.1% ± 3% vs 36% ± 4% respectively, P = 0.148. Eight SFS-remnants with RVBWR < 0.65 had a significantly smaller RV/TLV than 63 non-SFS-remnants with RVBWR ≥ 0.65 [SFS: RV/TLV 32.4% (range: 28%-35.7%) vs non-SFS: RV/TLV 36.2% (range: 26.1%-45.5%), P < 0.009. Six SFS-remnants with RV/TLV < 30% had significantly smaller RVBWR than 65 non-SFS-remnants with RV/TLV ≥ 30% (0.65 (range: 0.6-0.7) vs 0.8 (range: 0.6-1.27), P < 0.01. Two (2.8%) donors developed reversible liver failure. RVBWR and RV/TLV were concordant in 25%-33% of SFS and in 92%-94% of non-SFS remnants. MHV management options including complete MHV vs MHV-4A selective retention were necessary in n = 12 vs n = 2 remnants based on particularly risky congestive and non-congestive volume constellations. CONCLUSION: MHV procurement should consider individual remnant congestive- and non-congestive volume components and anatomy characteristics, RVBWR-RV/TLV constellation enables the identification of marginally small remnants. PMID:26019467

Stereocontrolled Alkylative Construction of Quaternary Carbon Centers

PubMed Central

Kummer, David A.; Chain, William J.; Morales, Marvin R.; Quiroga, Olga; Myers, Andrew G.

2009-01-01

Protocols for the stereodefined formation of α,α-disubstituted enolates of pseudoephedrine amides are presented followed by the implementation of these in diastereoselective alkylation reactions. Direct alkylation of α,α-disubstituted pseudoephedrine amide substrates is demonstrated to be both efficient and diastereoselective across a range of substrates, as exemplified by alkylation of the diastereomeric pseudoephedrine α-methylbutyramides, where both substrates are found to undergo stereospecific replacement of the α-C-H bond with α-C-alkyl, with retention of stereochemistry. This is shown to arise by sequential stereospecific enolization and alkylation reactions, with the alkyl halide attacking a common π-face of the E- and Z-enolates, proposed to be that opposite the pseudoephedrine alkoxide side-chain. Pseudoephedrine α-phenylbutyramides are found to undergo highly stereoselective but not stereospecific α-alkylation reactions, which evidence suggests is due to facile enolate isomerization. Also, we show that α, α-disubstituted pseudoephedrine amide enolates can be generated in a highly stereocontrolled fashion by conjugate addition of an alkyllithium reagent to the s-cis-conformer of an α-alkyl-α,β-unsaturated pseudoephedrine amide, providing α,α-disubstituted enolate substrates that undergo alkylation in the same sense as those formed by direct deprotonation. Methods are presented to transform the α-quaternary pseudoephedrine amide products into optically active carboxylic acids, ketones, primary alcohols, and aldehydes. PMID:18788739

Comparison of biodegradation performance of OECD test guideline 301C with that of other ready biodegradability tests.

PubMed

Kayashima, Takakazu; Taruki, Masanori; Katagiri, Kazuomi; Nabeoka, Ryosuke; Yoshida, Tomohiko; Tsuji, Toshiaki

2014-02-01

The Organisation for Economic Co-operatoin and development (OECD) Guidelines for the Testing of Chemicals list 7 types of tests for determining the ready biodegradability of chemical compounds (301A-F and 310). The present study compares the biodegradation performance of test guideline 301C, which is applied in Japan's Chemical Substances Control Law, with the performance of the other 6 ready biodegradability tests (RBTs) listed in the guidelines. Test guideline 301C specifies use of activated sludge precultured with synthetic sewage containing glucose and peptone (301C sludge) as a test inoculum; in the other RBTs, however, activated sludge from wastewater treatment plants (WWTP sludge) is frequently employed. Analysis based on percentage of biodegradation and pass levels revealed that the biodegradation intensity of test guideline 301C is relatively weak compared with the intensities of RBTs using WWTP sludge, and the following chemical compounds are probably not biodegraded under test guideline 301C conditions: phosphorus compounds; secondary, tertiary, and quaternary amines; and branched quaternary carbon compounds. The relatively weak biodegradation intensity of test guideline 301C may be related to the markedly different activities of the 301C and WWTP sludges. These findings will be valuable for evaluating RBT data in relation to Japan's Chemical Substances Control Law. © 2013 SETAC.

Involvement of systemic venous congestion in heart failure.

PubMed

Rubio Gracia, J; Sánchez Marteles, M; Pérez Calvo, J I

2017-04-01

Systemic venous congestion has gained significant importance in the interpretation of the pathophysiology of acute heart failure, especially in the development of renal function impairment during exacerbations. In this study, we review the concept, clinical characterisation and identification of venous congestion. We update current knowledge on its importance in the pathophysiology of acute heart failure and its involvement in the prognosis. We pay special attention to the relationship between abdominal congestion, the pulmonary interstitium as filtering membrane, inflammatory phenomena and renal function impairment in acute heart failure. Lastly, we review decongestion as a new therapeutic objective and the measures available for its assessment. Copyright © 2016 Elsevier España, S.L.U. and Sociedad Española de Medicina Interna (SEMI). All rights reserved.

Recent Progress on the Stereoselective Synthesis of Cyclic Quaternary α-Amino Acids

PubMed Central

Cativiela, Carlos; Ordóñez, Mario

2010-01-01

The most recent papers describing the stereoselective synthesis of cyclic quaternary α-amino acids are collected in this review. The diverse synthetic approaches are classified according to the size of the ring and taking into account the bond that is formed to complete the quaternary skeleton. PMID:20300486

The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

PubMed Central

Assumpção, Cindy M.; Quintela, Fernando M.; Corrêa, Fabiano; Loebmann, Daniel

2016-01-01

Abstract The Quaternary in the state of Rio Grande do Sul (RS), southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine). Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits. PMID:28174498

Analysis of multiple quaternary ammonium compounds in the brain using tandem capillary column separation and high resolution mass spectrometric detection.

PubMed

Falasca, Sara; Petruzziello, Filomena; Kretz, Robert; Rainer, Gregor; Zhang, Xiaozhe

2012-06-08

Endogenous quaternary ammonium compounds are involved in various physiological processes in the central nervous system. In the present study, eleven quaternary ammonium compounds, including acetylcholine, choline, carnitine, acetylcarnitine and seven other acylcarnitines of low polarity, were analyzed from brain extracts using a two dimension capillary liquid chromatography-Fourier transform mass spectrometry method. To deal with their large difference in hydrophobicities, tandem coupling between reversed phase and hydrophilic interaction chromatography columns was used to separate all the targeted quaternary ammonium compounds. Using high accuracy mass spectrometry in selected ion monitoring mode, all the compounds could be detected from each brain sample with high selectivity. The developed method was applied for the relative quantification of these quaternary ammonium compounds in three different brain regions of tree shrews: prefrontal cortex, striatum, and hippocampus. The comparative analysis showed that quaternary ammonium compounds were differentially distributed across the three brain areas. The analytical method proved to be highly sensitive and reliable for simultaneous determination of all the targeted analytes from brain samples. Copyright © 2012 Elsevier B.V. All rights reserved.

Origin and late quaternary tectonism of a western Canadian continental shelf trough

NASA Astrophysics Data System (ADS)

Moslow, Thomas F.; Luternauer, John L.; Rohr, Kristin

1991-08-01

Analyses of high resolution and multi-channel seismic profiles from the central continental shelf of western Canada ascribe a late Quaternary glacial origin to large-scale troughs. Along the margins of Moresby Trough, one of three large-scale cross-shelf bathymetric depressions in Queen Charlotte Sound, seismic profiles within Quaternary sediments show a divergence of reflectors, thickening and folding of seismic units, and concavity of reflectors suggestive of drag. Compactional subsidence, growth faulting, and compaction faulting are also observed. Fault traces commonly terminate below the seabed. Deformation of Quaternary sediments due to faulting is plastic in nature and maximum offset of reflectors is 2.5 m. The observed Quaternary deformation appears to be a product of rapid deposition, loading and subsidence of late Quaternary sediment, which is unrelated to seismic activity. In addition, Quaternary faulting was probably activated by post-glacial loading and isostatic rebound of consolidated Tertiary strata along the margins of continental shelf troughs. The presence of mass movement (slump or debris flow) deposits overlying lithified Tertiary strata along the flanks of Moresby Trough provides the only evidence of seismic activity in the study area. The lack of a mud drape over these deposits implies a late Holocene age for the timing of their emplacement. The Quaternary troughs are incised into Tertiary-aged sedimentary fill of the Queen Charlotte basin. Previous workers had interpreted seafloor escarpments paralleling the trough margins to indicate that the location of Moresby Trough was controlled by renewed or continued activity on Tertiary-aged faults. A multi-channel seismic line across Moresby Trough shows that such an escarpment on the seafloor does not correlate to faults either in the Tertiary basin fill or the underlying basement. Tertiary reflectors are continuous underneath Moresby Trough; the seafloor escarpment is an erosional feature and was not created by reactivation of Tertiary structures. Trough erosion and subsequent fill (up to 175 m thick) are entirely of Quaternary age.

Efficiency improvement of green light-emitting diodes by employing all-quaternary active region and electron-blocking layer

NASA Astrophysics Data System (ADS)

Usman, Muhammad; Saba, Kiran; Han, Dong-Pyo; Muhammad, Nazeer

2018-01-01

High efficiency of green GaAlInN-based light-emitting diode (LED) has been proposed with peak emission wavelength of ∼510 nm. By introducing quaternary quantum well (QW) along with the quaternary barrier (QB) and quaternary electron blocking layer (EBL) in a single structure, an efficiency droop reduction of up to 29% has been achieved in comparison to the conventional GaN-based LED. The proposed structure has significantly reduced electrostatic field in the active region. As a result, carrier leakage has been minimized and spontaneous emission rate has been doubled.

Spiro-(1,1‧)-bipyrrolidinium tetrafluoroborate salt as high voltage electrolyte for electric double layer capacitors

NASA Astrophysics Data System (ADS)

Yu, Xuewen; Ruan, Dianbo; Wu, Changcheng; Wang, Jing; Shi, Zhiqiang

2014-11-01

A novel quaternary ammonium salt based on spiro-(1,1‧)-bipyrolidinium tetrafluoroborate (SBP-BF4) has been synthesized and dissolved in propylene carbonate (PC) with 1.5 mol L-1 (M) concentration for electric double-layer capacitors (EDLCs). The physic-chemical properties and electrochemical performance of SBP-BF4/PC electrolyte are investigated. Compared with the standard electrolyte 1.5 M TEMA-BF4 in PC, the novel SBP-BF4/PC electrolyte exhibited much better electrochemical performance due to its smaller cation size, lower viscosity and higher conductivity. The specific discharge capacitance of activated carbon electrode based EDLCs using SBP-BF4/PC electrolyte is 120 F g-1, the energy density and power density can reach 31 kW kg-1 and 6938 W kg-1, respectively, when the working voltage is 2.7 V and current density is 50 mA g-1. The withstand voltage of activated carbon based EDLCs with SBP-BF4/PC electrolyte can reach to 3.2 V, where the stable discharge capacitance and energy density are 121 F g-1 and 43 Wh kg-1, respectively.

Quaternary complexes composed of plasmid DNA/protamine/fish sperm DNA/stearic acid grafted chitosan oligosaccharide micelles for gene delivery.

PubMed

Du, Yong-Zhong; Lu, Ping; Yuan, Hong; Zhou, Jian-Ping; Hu, Fu-Qiang

2011-01-01

Quaternary complexes with condensed core of plasmid DNA, protamine, fish sperm DNA and shell of stearic acid grafted chitosan oligosaccharide (CSO-SA), were prepared. The CSO-SA could self-assemble to form nano-sized micelles in aqueous solution and demonstrated excellent internalization ability of tumor cells. Dynamic light scattering (DLS) measurement and transmission electrostatic microscope (TEM) images showed that quaternary complexes had spherical shape with about 25 nm number average diameter, and the size of quaternary complexes was smaller than that of CSO-SA micelles and CSO-SA micelles/plasmid DNA binary complexes. The transfection efficiencies of quaternary complexes on HEK293 and MCF-7 cells increased with incubation time, and were significantly higher than that of CSO-SA micelles/plasmid DNA binary complexes. The optimal transfection efficiency of quaternary complexes on HEK293 and MCF-7 cells measured by flow cytometer after 96 h was 23.82% and 41.43%, respectively. Whereas, the transfection efficiency of Lipofectamine™ 2000 on HEK293 and MCF-7 cells after 96 h was 32.45% and 33.23%, respectively. The data of luciferease activity measurement showed that the optimal ratio of plasmid DNA:fish sperm DNA:protamine:CSO-SA was 1:1:5:5. The results indicated that the present quaternary complexes were potential non-viral gene delivery system. Copyright © 2010 Elsevier B.V. All rights reserved.

Accuracy of tissue Doppler echocardiography in the diagnosis of new-onset congestive heart failure in patients with levels of B-type natriuretic peptide in the midrange and normal left ventricular ejection fraction.

PubMed

Arques, Stephane; Roux, Emmanuel; Sbragia, Pascal; Pieri, Bertrand; Gelisse, Richard; Ambrosi, Pierre; Luccioni, Roger

2006-09-01

Based on the hypothesis that it reflects left ventricular (LV) diastolic pressures, B-type natriuretic peptide (BNP) is largely utilized as first-line diagnostic complement in the emergency diagnosis of congestive heart failure (HF). The incremental diagnostic value of tissue Doppler echocardiography, a reliable noninvasive estimate of LV filling pressures, has been reported in patients with preserved LV ejection fraction and discrepancy between BNP levels and the clinical judgment, however, its clinical validity in such patients in the presence of BNP concentrations in the midrange, which may reflect intermediate, nondiagnostic levels of LV filling pressures, is unknown. 34 patients without history of HF, presenting with acute dyspnea at rest, BNP levels of 100-400 pg/ml and normal LV ejection fraction were prospectively enrolled (17 with congestive HF and 17 with noncardiac cause). Tissue Doppler echocardiography was performed within 3 hours after admission. Unlike BNP (P = 0.78), Boston criteria (P = 0.0129), radiographic pulmonary edema (P = 0.0036) and average E/Ea ratio (P = 0.0032) were predictive of congestive HF by logistic regression analysis. In this clinical setting, radiographic pulmonary edema had a positive predictive value of 80% in the diagnosis of congestive HF. In patients without evidence of radiographic pulmonary edema, average E/Ea > 10 was a powerful predictor of congestive HF (area under the ROC curve of 0.886, P < 0.001, sensitivity 100% and specificity 78.6%). By better reflecting LV filling pressures, bedside tissue Doppler echocardiography accurately differentiates congestive HF from noncardiac cause in dyspneic patients with intermediate, nondiagnostic BNP levels and normal LV ejection fraction.

Cardiac Dysfunction, Congestion and Loop Diuretics: their Relationship to Prognosis in Heart Failure.

PubMed

Pellicori, Pierpaolo; Cleland, John G F; Zhang, Jufen; Kallvikbacka-Bennett, Anna; Urbinati, Alessia; Shah, Parin; Kazmi, Syed; Clark, Andrew L

2016-12-01

Diuretics are the mainstay of treatment for congestion but concerns exist that they adversely affect prognosis. We explored whether the relationship between loop diuretic use and outcome is explained by the underlying severity of congestion amongst patients referred with suspected heart failure. Of 1190 patients, 712 had a left ventricular ejection fraction (LVEF) ≤50 %, 267 had LVEF >50 % with raised plasma NTproBNP (>400 ng/L) and 211 had LVEF >50 % with NTproBNP ≤400 ng/L; respectively, 72 %, 68 % and 37 % of these groups were treated with loop diuretics including 28 %, 29 % and 10 % in doses ≥80 mg furosemide equivalent/day. Compared to patients with cardiac dysfunction (either LVEF ≤50 % or NT-proBNP >400 ng/L) but not taking a loop diuretic, those taking a loop diuretic were older and had more clinical evidence of congestion, renal dysfunction, anaemia and hyponatraemia. During a median follow-up of 934 (IQR: 513-1425) days, 450 patients were hospitalized for HF or died. Patients prescribed loop diuretics had a worse outcome. However, in multi-variable models, clinical, echocardiographic (inferior vena cava diameter), and biochemical (NTproBNP) measures of congestion were strongly associated with an adverse outcome but not the use, or dose, of loop diuretics. Prescription of loop diuretics identifies patients with more advanced features of heart failure and congestion, which may account for their worse prognosis. Further research is needed to clarify the relationship between loop diuretic agents and outcome; imaging and biochemical measures of congestion might be better guides to diuretic dose than symptoms or clinical signs.

The kidney in congestive heart failure: 'are natriuresis, sodium, and diuretics really the good, the bad and the ugly?'.

PubMed

Verbrugge, Frederik H; Dupont, Matthias; Steels, Paul; Grieten, Lars; Swennen, Quirine; Tang, W H Wilson; Mullens, Wilfried

2014-02-01

This review discusses renal sodium handling in heart failure. Increased sodium avidity and tendency to extracellular volume overload, i.e. congestion, are hallmark features of the heart failure syndrome. Particularly in the case of concomitant renal dysfunction, the kidneys often fail to elicit potent natriuresis. Yet, assessment of renal function is generally performed by measuring serum creatinine, which has inherent limitations as a biomarker for the glomerular filtration rate (GFR). Moreover, glomerular filtration only represents part of the nephron's function. Alterations in the fractional reabsorptive rate of sodium are at least equally important in emerging therapy-refractory congestion. Indeed, renal blood flow decreases before the GFR is affected in congestive heart failure. The resulting increased filtration fraction changes Starling forces in peritubular capillaries, which drive sodium reabsorption in the proximal tubules. Congestion further stimulates this process by augmenting renal lymph flow. Consequently, fractional sodium reabsorption in the proximal tubules is significantly increased, limiting sodium delivery to the distal nephron. Orthosympathetic activation probably plays a pivotal role in those deranged intrarenal haemodynamics, which ultimately enhance diuretic resistance, stimulate neurohumoral activation with aldosterone breakthrough, and compromise the counter-regulatory function of natriuretic peptides. Recent evidence even suggests that intrinsic renal derangements might impair natriuresis early on, before clinical congestion or neurohumoral activation are evident. This represents a paradigm shift in heart failure pathophysiology, as it suggests that renal dysfunction-although not by conventional GFR measurements-is driving disease progression. In this respect, a better understanding of renal sodium handling in congestive heart failure is crucial to achieve more tailored decongestive therapy, while preserving renal function. © 2013 The Authors. European Journal of Heart Failure © 2013 European Society of Cardiology.

Factors associated with health-related quality of life in stable ambulatory congestive heart failure patients: Systematic review.

PubMed

Baert, Anneleen; De Smedt, Delphine; De Sutter, Johan; De Bacquer, Dirk; Puddu, Paolo Emilio; Clays, Els; Pardaens, Sofie

2018-03-01

Background Since improved treatment of congestive heart failure has resulted in decreased mortality and hospitalisation rates, increasing self-perceived health-related quality of life (HRQoL) has become a major goal of congestive heart failure treatment. However, an overview on predictieve factors of HRQoL is currently lacking in literature. Purpose The aim of this study was to identify key factors associated with HRQoL in stable ambulatory patients with congestive heart failure. Methods A systematic review was performed. MEDLINE, Web of Science and Embase were searched for the following combination of terms: heart failure, quality of life, health perception or functional status between the period 2000 and February 2017. Literature screening was done by two independent reviewers. Results Thirty-five studies out of 8374 titles were included for quality appraisal, of which 29 were selected for further data extraction. Four distinct categories grouping different types of variables were identified: socio-demographic characteristics, clinical characteristics, health and health behaviour, and care provider characteristics. Within the above-mentioned categories the presence of depressive symptoms was most consistently related to a worse HRQoL, followed by a higher New York Heart Association functional class, younger age and female gender. Conclusion Through a systematic literature search, factors associated with HRQoL among congestive heart failure patients were investigated. Age, gender, New York Heart Association functional class and depressive symptoms are the most consistent variables explaining the variance in HRQoL in patients with congestive heart failure. These findings are partly in line with previous research on predictors for hard endpoints in patients with congestive heart failure.

Impact of surface processes and climate variability on clumped isotope thermometry of soil carbonates, southern Central Andes, Argentina (Invited)

NASA Astrophysics Data System (ADS)

Huntington, K. W.; Peters, N.; Roe, G.; Hoke, G. D.; Eiler, J.

2010-12-01

Soil carbonates archive a potentially rich record of past climate, but rates of pedogenic carbonate formation, erosion, and deposition impact how the isotopic composition and formation temperature of carbonate-bearing paleosols reflect the local environmental conditions under which they form. We investigate these processes using conventional stable isotope (δ18O and δ13C) and clumped isotope thermometry data for Quaternary pedogenic carbonates from the southern Central Andes at ~33°S, Argentina. The study area spans over 2 km of relief in the Río Mendoza and Río de las Cuevas valleys, accessing a range of mean annual temperature conditions and vegetative cover and exhibiting large seasonal variations in temperature, precipitation, and soil moisture. Variations in soil conditions influence carbonate precipitation and dissolution reactions and the rate and depth of pedogenic carbonate formation. Because soil temperature varies predictably as a function of depth in the soil and seasonal and secular variations in air temperature, clumped isotope thermometry of samples collected in soil pits offers a direct way to estimate the seasonality of pedogenic carbonate formation and potential biases in the long-term climate record. We explore potential complications due to the effects of radiative solar heating on the relationship between air and soil temperatures by examining clumped isotope thermometry results in the context of site-to-site variations in vegetative cover. Temperature estimates from clumped isotope thermometry of pedogenic carbonate collected 5-110 cm below geomorphically stable soil surfaces from 1200-3400 m a.s.l. are compared to temperature profiles predicted by simple rule-based models of soil carbonate formation. The models use climate reanalysis daily diagnostic data (soil temperature, soil moisture, and latent heat flux as a proxy for evaporation) and weather station data as input to assess how varying rates of pedogenic carbonate formation integrated over millennial timescales might impact the geologic record of temperature and isotopic composition.

Late Quaternary Upwelling Variations in the Eastern Equatorial Atlantic Ocean as Inferred from Dinoflagellate Cysts, Planktonic Foraminifera, and Organic Carbon Content

NASA Astrophysics Data System (ADS)

Höll, Christine; Kemle-von Mücke, Sylvia

2000-07-01

Analysis of multiple proxies shows that eastern equatorial Atlantic upwelling was subdued during isotope stage 5.5, more intense during stages 4, 5.2, 5.4, and 6, and most intense early in stage 2. These findings are based on proxy measures from a core site about 600 km southwest of Liberia. The proxies include total organic carbon content, the ratio of peridinoid and oceanic organic-walled dinoflagellate cyst species, accumulation rates of calcareous dinoflagellates, estimates of sea surface paleotemperatures, the difference in stable oxygen isotope composition between two species of planktonic foraminifera that live at different water depths, and the abundance of the planktonic foraminifera Neogloboquadrina dutertrei. Most of these parameters consistently vary directly or inversely with one another. Slight discrepancies between the individual parameters show the usefulness of a multiple proxy approach to reconstruct paleoenvironments. Our data confirm that northern summer insolation strongly influences upwelling in the eastern equatorial Atlantic Ocean.

Organic Pollutants in Shale Gas Flowback and Produced Waters: Identification, Potential Ecological Impact, and Implications for Treatment Strategies.

PubMed

Butkovskyi, Andrii; Bruning, Harry; Kools, Stefan A E; Rijnaarts, Huub H M; Van Wezel, Annemarie P

2017-05-02

Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses identification of individual organic contaminants in FPW, and stresses the gaps in the knowledge on FPW composition that exist so far. Furthermore, the risk quotient approach was applied to predict the toxicity of the quantified organic compounds for fresh water organisms in recipient surface waters. This resulted in an identification of a number of FPW related organic compounds that are potentially harmful namely those compounds originating from shale formations (e.g., polycyclic aromatic hydrocarbons, phthalates), fracturing fluids (e.g., quaternary ammonium biocides, 2-butoxyethanol) and downhole transformations of organic compounds (e.g., carbon disulfide, halogenated organic compounds). Removal of these compounds by FPW treatment processes is reviewed and potential and efficient abatement strategies are defined.

Stratigraphy and paleoenvironments of the Shell 410-1 well, Georges Bank Basin, US North Atlantic outer continental shelf

USGS Publications Warehouse

Poppe, L.J.; Poag, C.W.; Swift, B.A.

1995-01-01

The Shell 410-1 well is the most downdip (seaward) hydrocarbon exploratory well in the Georges Bank Basin. It was drilled to a total depth of 4745 m RKB, and penetrated a section composed of Middle Jurassic to Quaternary sedimentary rocks. The lithostratigraphy of the section is described. The strata penetrated by the Shell 410-1 well are more marine than rocks at the updip (landward) COST G-1, Exxon 975-1, COST G-2, and Conoco 145-1 well sites. Limestones and calcareous mudstones dominate at the Shell 410-1 site. Dolomite and anhydrite are much more abundant in the Bajocian-Callovian strata of the Shell 410-1 well, which is evidence that the carbonate-bank palaeoenvironments recorded in the Iroquois and Abenaki Formations were more restricted (less marine) here than 47 km to the west-northwest at the Mobil 312-1 well site near the edge of the Jurassic carbonate platform. -from Authors

Offshore S. Cuba -- Quaternary lobsters and Eocene reefs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rebora, M.

When Cuba is mentioned, the first image that comes to an explorationist's mind is one of complex imbricated thrust sheets, fractured carbonate reservoirs, volcanics and ophiolitic, and heavy and high sulfur oil. It is now known that this stimulating'' scenario does not apply to the whole of Cuba but only to the northern and central part where plate collisions and robust wrench tectonics exacted their toll on sediments and hydrocarbons alike. Seismic data recently acquired by Taurus Petroleum off the southern coast of Cuba reveal a rather different scenario: Mesozoic sediments several thousands of meters thick, deformed by moderate wrenchmore » tectonics into low-relief flower structures, and overlain by a variety of Paleogene shelf edge reefs, atolls, and banks that look as if reproduced from the pages of AAPG's Memoir 57. The whole is topped by Oligocene and Miocene evaporites, shales, and carbonates. The paper describes the southern shelf area, exploration in Cuba, reefs, oil and gas shows, source rocks, reservoir rocks, seals, and potential reserves.« less

Organic Pollutants in Shale Gas Flowback and Produced Waters: Identification, Potential Ecological Impact, and Implications for Treatment Strategies

PubMed Central

2017-01-01

Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses identification of individual organic contaminants in FPW, and stresses the gaps in the knowledge on FPW composition that exist so far. Furthermore, the risk quotient approach was applied to predict the toxicity of the quantified organic compounds for fresh water organisms in recipient surface waters. This resulted in an identification of a number of FPW related organic compounds that are potentially harmful namely those compounds originating from shale formations (e.g., polycyclic aromatic hydrocarbons, phthalates), fracturing fluids (e.g., quaternary ammonium biocides, 2-butoxyethanol) and downhole transformations of organic compounds (e.g., carbon disulfide, halogenated organic compounds). Removal of these compounds by FPW treatment processes is reviewed and potential and efficient abatement strategies are defined. PMID:28376616

Lithium Enolates in the Enantioselective Construction of Tetrasubstituted Carbon Centers with Chiral Lithium Amides as Noncovalent Stereodirecting Auxiliaries.

PubMed

Yu, Kai; Lu, Ping; Jackson, Jeffrey J; Nguyen, Thuy-Ai D; Alvarado, Joseph; Stivala, Craig E; Ma, Yun; Mack, Kyle A; Hayton, Trevor W; Collum, David B; Zakarian, Armen

2017-01-11

Lithium enolates derived from carboxylic acids are ubiquitous intermediates in organic synthesis. Asymmetric transformations with these intermediates, a central goal of organic synthesis, are typically carried out with covalently attached chiral auxiliaries. An alternative approach is to utilize chiral reagents that form discrete, well-defined aggregates with lithium enolates, providing a chiral environment conducive of asymmetric bond formation. These reagents effectively act as noncovalent, or traceless, chiral auxiliaries. Lithium amides are an obvious choice for such reagents as they are known to form mixed aggregates with lithium enolates. We demonstrate here that mixed aggregates can effect highly enantioselective transformations of lithium enolates in several classes of reactions, most notably in transformations forming tetrasubstituted and quaternary carbon centers. Easy recovery of the chiral reagent by aqueous extraction is another practical advantage of this one-step protocol. Crystallographic, spectroscopic, and computational studies of the central reactive aggregate, which provide insight into the origins of selectivity, are also reported.

Permafrost soils and carbon cycling

DOE PAGES

Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; ...

2014-10-30

Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon (OC) stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous OC stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global C cycle and the potential vulnerability of the region's soil OC stocks to changing climatic conditions. In this review,more » we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of OC stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this OC to permafrost thaw under a warming climate.« less

Increasing Intelligence in Inter-Vehicle Communications to Reduce Traffic Congestions: Experiments in Urban and Highway Environments.

PubMed

Meneguette, Rodolfo I; Filho, Geraldo P R; Guidoni, Daniel L; Pessin, Gustavo; Villas, Leandro A; Ueyama, Jó

2016-01-01

Intelligent Transportation Systems (ITS) rely on Inter-Vehicle Communication (IVC) to streamline the operation of vehicles by managing vehicle traffic, assisting drivers with safety and sharing information, as well as providing appropriate services for passengers. Traffic congestion is an urban mobility problem, which causes stress to drivers and economic losses. In this context, this work proposes a solution for the detection, dissemination and control of congested roads based on inter-vehicle communication, called INCIDEnT. The main goal of the proposed solution is to reduce the average trip time, CO emissions and fuel consumption by allowing motorists to avoid congested roads. The simulation results show that our proposed solution leads to short delays and a low overhead. Moreover, it is efficient with regard to the coverage of the event and the distance to which the information can be propagated. The findings of the investigation show that the proposed solution leads to (i) high hit rate in the classification of the level of congestion, (ii) a reduction in average trip time, (iii) a reduction in fuel consumption, and (iv) reduced CO emissions.

Increasing Intelligence in Inter-Vehicle Communications to Reduce Traffic Congestions: Experiments in Urban and Highway Environments

PubMed Central

Filho, Geraldo P. R.; Guidoni, Daniel L.; Pessin, Gustavo; Villas, Leandro A.; Ueyama, Jó

2016-01-01

Intelligent Transportation Systems (ITS) rely on Inter-Vehicle Communication (IVC) to streamline the operation of vehicles by managing vehicle traffic, assisting drivers with safety and sharing information, as well as providing appropriate services for passengers. Traffic congestion is an urban mobility problem, which causes stress to drivers and economic losses. In this context, this work proposes a solution for the detection, dissemination and control of congested roads based on inter-vehicle communication, called INCIDEnT. The main goal of the proposed solution is to reduce the average trip time, CO emissions and fuel consumption by allowing motorists to avoid congested roads. The simulation results show that our proposed solution leads to short delays and a low overhead. Moreover, it is efficient with regard to the coverage of the event and the distance to which the information can be propagated. The findings of the investigation show that the proposed solution leads to (i) high hit rate in the classification of the level of congestion, (ii) a reduction in average trip time, (iii) a reduction in fuel consumption, and (iv) reduced CO emissions PMID:27526048

Insomnia Self-Management in Heart Failure

ClinicalTrials.gov

2018-01-05

Cardiac Failure; Heart Failure; Congestive Heart Failure; Heart Failure, Congestive; Sleep Initiation and Maintenance Disorders; Chronic Insomnia; Disorders of Initiating and Maintaining Sleep; Fatigue; Pain; Depressive Symptoms; Sleep Disorders; Anxiety

On the Inefficiency of Equilibria in Linear Bottleneck Congestion Games

NASA Astrophysics Data System (ADS)

de Keijzer, Bart; Schäfer, Guido; Telelis, Orestis A.

We study the inefficiency of equilibrium outcomes in bottleneck congestion games. These games model situations in which strategic players compete for a limited number of facilities. Each player allocates his weight to a (feasible) subset of the facilities with the goal to minimize the maximum (weight-dependent) latency that he experiences on any of these facilities. We derive upper and (asymptotically) matching lower bounds on the (strong) price of anarchy of linear bottleneck congestion games for a natural load balancing social cost objective (i.e., minimize the maximum latency of a facility). We restrict our studies to linear latency functions. Linear bottleneck congestion games still constitute a rich class of games and generalize, for example, load balancing games with identical or uniformly related machines with or without restricted assignments.

Continuum modeling of cooperative traffic flow dynamics

NASA Astrophysics Data System (ADS)

Ngoduy, D.; Hoogendoorn, S. P.; Liu, R.

2009-07-01

This paper presents a continuum approach to model the dynamics of cooperative traffic flow. The cooperation is defined in our model in a way that the equipped vehicle can issue and receive a warning massage when there is downstream congestion. Upon receiving the warning massage, the (up-stream) equipped vehicle will adapt the current desired speed to the speed at the congested area in order to avoid sharp deceleration when approaching the congestion. To model the dynamics of such cooperative systems, a multi-class gas-kinetic theory is extended to capture the adaptation of the desired speed of the equipped vehicle to the speed at the downstream congested traffic. Numerical simulations are carried out to show the influence of the penetration rate of the equipped vehicles on traffic flow stability and capacity in a freeway.

Cogestion and recreation site demand: a model of demand-induced quality effects

USGS Publications Warehouse

Douglas, Aaron J.; Johnson, Richard L.

1993-01-01

This analysis focuses on problems of estimating site-specific dollar benefits conferred by outdoor recreation sites in the face of congestion costs. Encounters, crowding effects and congestion costs have often been treated by natural resource economists in a piecemeal fashion. In the current paper, encounters and crowding effects are treated systematically. We emphasize the quantitative impact of congestion costs on site-specific estimates of benefits conferred by improvements in outdoor recreation sites. The principal analytic conclusion is that techniques that streamline on data requirements produce biased estimates of benefits conferred by site improvements at facilities with significant crowding effects. The principal policy recommendation is that the Federal and state agencies should collect and store information on visitation rates, encounter levels and congestion costs at various outdoor recreation sites.

Polarized Infrared Reflectance Studies of Quaternary In0.04Al0.06Ga0.90N

NASA Astrophysics Data System (ADS)

Bakhori, S. K. Mohd; Lee, S. C.; Ahmad, M. A.; Ng, S. S.; Hassan, H. Abu

2010-07-01

Group III-nitride has re-gained considerable interest recently as wide direct band gap semiconductor materials for opto-electronic and high power devices. The quaternary InAlGaN have great flexibility in tailoring their band gap profile while maintaining their lattice-matching and structural integrity. In this study, we report for the first time the polarized infrared (IR) reflectance studies of quaternary In0.04Al0.06Ga0.90N by using Fourier transform infrared spectroscopy of Perkin-Elmer. The quaternary In0.04Al0.06Ga0.90N epilayers was grown on sapphire by molecular beam epitaxy. The polarized IR reflectance spectra obtained at incident angle of 15° were then compared with modeling spectrum of damped harmonic oscillator. Through this study, the transverse and longitudinal optical phonon modes of quaternary In0.04Al0.06Ga0.90N epilayers were obtained.

Multi-valued logic gates based on ballistic transport in quantum point contacts.

PubMed

Seo, M; Hong, C; Lee, S-Y; Choi, H K; Kim, N; Chung, Y; Umansky, V; Mahalu, D

2014-01-22

Multi-valued logic gates, which can handle quaternary numbers as inputs, are developed by exploiting the ballistic transport properties of quantum point contacts in series. The principle of a logic gate that finds the minimum of two quaternary number inputs is demonstrated. The device is scalable to allow multiple inputs, which makes it possible to find the minimum of multiple inputs in a single gate operation. Also, the principle of a half-adder for quaternary number inputs is demonstrated. First, an adder that adds up two quaternary numbers and outputs the sum of inputs is demonstrated. Second, a device to express the sum of the adder into two quaternary digits [Carry (first digit) and Sum (second digit)] is demonstrated. All the logic gates presented in this paper can in principle be extended to allow decimal number inputs with high quality QPCs.

Base-Controlled Completely Selective Linear or Branched Rhodium(I)-Catalyzed C-H ortho-Alkylation of Azines without Preactivation.

PubMed

Tran, Gaël; Hesp, Kevin D; Mascitti, Vincent; Ellman, Jonathan A

2017-05-15

A [Rh I ]/bisphosphine/base catalytic system for the ortho-selective C-H alkylation of azines by acrylates and acrylamides is reported. This catalytic system features an unprecedented complete linear or branched selectivity that is solely dependent on the catalytic base that is used. Complete branched selectivity is even achieved for ethyl methacrylate, which enables the introduction of a quaternary carbon center. Excellent functional group compatibility is demonstrated for both linear and branched alkylations. The operational simplicity and broad scope of this transformation allow for rapid access to functionalized azines of direct pharmaceutical and agrochemical relevance. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Carbofluoresceins and Carborhodamines as Scaffolds for High-Contrast Fluorogenic Probes

PubMed Central

2013-01-01

Fluorogenic molecules are important tools for advanced biochemical and biological experiments. The extant collection of fluorogenic probes is incomplete, however, leaving regions of the electromagnetic spectrum unutilized. Here, we synthesize green-excited fluorescent and fluorogenic analogues of the classic fluorescein and rhodamine 110 fluorophores by replacement of the xanthene oxygen with a quaternary carbon. These anthracenyl “carbofluorescein” and “carborhodamine 110” fluorophores exhibit excellent fluorescent properties and can be masked with enzyme- and photolabile groups to prepare high-contrast fluorogenic molecules useful for live cell imaging experiments and super-resolution microscopy. Our divergent approach to these red-shifted dye scaffolds will enable the preparation of numerous novel fluorogenic probes with high biological utility. PMID:23557713

Unified Total Syntheses of Fawcettimine Class Alkaloids: Fawcettimine, Fawcettidine, Lycoflexine, and Lycoposerramine B

PubMed Central

Pan, Guojun; Williams, Robert M.

2012-01-01

The total syntheses of the lycopodium alkaloids: fawcettimine, fawcettidine, lycoflexine, and lycoposerramine B have been accomplished through an efficient, unified, and stereocontrolled strategy, which relies on a Diels-Alder reaction to construct the cis-fused 6,5-carbocycles with one all-carbon quaternary center. Access to the enantioselective syntheses of both antipodes of those alkaloids can be achieved by kinetic resolution of the earliest intermediate via a Sharpless asymmetric dihydroxylation (Sharpless AD). Compared to existing approaches to these alkaloids, our synthetic route possesses superior stereocontrol over the C-4 and C-15 stereogenic centers as well as allowing for more functional variation on the 6-membered ring. PMID:22519642

Molecular design of high performance zwitterionic liquids for enhanced heavy-oil recovery processes.

PubMed

Martínez-Magadán, J M; Cartas-Rosado, A R; Oviedo-Roa, R; Cisneros-Dévora, R; Pons-Jiménez, M; Hernández-Altamirano, R; Zamudio-Rivera, L S

2018-03-01

Branched gemini zwitterionic liquids, which contain two zwitterionic moieties of linked quaternary-ammonium and carboxylate groups, are proposed as chemicals to be applied in the Enhanced Oil Recovery (EOR) from fractured carbonate reservoirs. The zwitterionic moieties are bridged between them through an alkyl chain containing 12 ether groups, and each zwitterionic moiety has attached a long alkyl tail including a CC double bond. A theoretical molecular mechanism over which EOR could rest, consisting on both the disaggregation of heavy oil and the reservoir-rock wettability alteration, was suggested. Results show that chemicals can both reduce the viscosity and remove heavy-oil molecules from the rock surface. Copyright © 2018. Published by Elsevier Inc.

Auctionable fixed transmission rights for congestion management

NASA Astrophysics Data System (ADS)

Alomoush, Muwaffaq Irsheid

Electric power deregulation has proposed a major change to the regulated utility monopoly. The change manifests the main part of engineers' efforts to reshape three components of today's regulated monopoly: generation, distribution and transmission. In this open access deregulated power market, transmission network plays a major role, and transmission congestion is a major problem that requires further consideration especially when inter-zonal/intra-zonal scheme is implemented. Declaring that engineering studies and experience are the criteria to define zonal boundaries or defining a zone based on the fact that a zone is a densely interconnected area (lake) and paths connecting these densely interconnected areas are inter-zonal lines will render insufficient and fuzzy definitions. Moreover, a congestion problem formulation should take into consideration interactions between intra-zonal and inter-zonal flows and their effects on power systems. In this thesis, we introduce a procedure for minimizing the number of adjustments of preferred schedules to alleviate congestion and apply control schemes to minimize interactions between zones. In addition, we give the zone definition a certain criterion based on the Locational Marginal Price (LMP). This concept will be used to define congestion zonal boundaries and to decide whether any zone should be merged with another zone or split into new zones. The thesis presents a unified scheme that combines zonal and FTR schemes to manage congestion. This combined scheme is utilized with LMPs to define zonal boundaries more appropriately. The presented scheme gains the best features of the FTR scheme, which are providing financial certainty, maximizing the efficient use of the system and making users pay for the actual use of congested paths. LMPs may give an indication of the impact of wheeling transactions, and calculations of and comparisons of LMPs with and without wheeling transactions should be adequate criteria to approve the transaction by the ISO, take a decision to expand the existing system, or retain the original structure of the system. Also, the thesis investigates the impact of wheeling transactions on congestion management, where we present a generalized mathematical model for the Fixed Transmission Right (FTR) auction. The auction guarantees FTR availability to all participants on a non-discriminatory basis, in which system users are permitted to buy, sell and trade FTRs through an auction. When FTRs are utilized with LMPs, they increase the efficient use of the transmission system and let a transmission customer gain advantageous features such as acquiring a mechanism to offset the extra cost due to congestion charges, providing financial and operational certainty and making system users pay for the actual use of the congested paths. The thesis also highlighted FTR trading in secondary markets to self-arrange access across different paths, create long-term transmission rights and provide more commercial certainty.

The importance of antipersistence for traffic jams

NASA Astrophysics Data System (ADS)

Krause, Sebastian M.; Habel, Lars; Guhr, Thomas; Schreckenberg, Michael

2017-05-01

Universal characteristics of road networks and traffic patterns can help to forecast and control traffic congestion. The antipersistence of traffic flow time series has been found for many data sets, but its relevance for congestion has been overseen. Based on empirical data from motorways in Germany, we study how antipersistence of traffic flow time-series impacts the duration of traffic congestion on a wide range of time scales. We find a large number of short-lasting traffic jams, which implies a large risk for rear-end collisions.

Congestive cardiomyopathy and endobronchial granulomas as manifestations of Churg-Strauss syndrome.

PubMed Central

Alvarez-Sala, R.; Prados, C.; Armada, E.; Del Arco, A.; Villamor, J.

1995-01-01

Churg-Strauss syndrome is a systemic vasculitis. Its most frequent complications are heart diseases and asthma. Usually, cardiological manifestations are pericarditis, cardiac failure and myocardial infarction. Endobronchial granulomas identified by bronchoscopy are unusual. We present the case of a man with congestive cardiomyopathy and endobronchial granulomas macroscopically visible at bronchoscopy. After a review of medical literature, we found one case of congestive cardiomyopathy and no cases of endobronchial granulomas observed by bronchoscopy associated with Churg-Strauss syndrome. Images Figure PMID:7644400

Algorithm and data support of traffic congestion forecasting in the controlled transport

NASA Astrophysics Data System (ADS)

Dmitriev, S. V.

2015-06-01

The topicality of problem of the traffic congestion forecasting in the logistic systems of product movement highways is considered. The concepts: the controlled territory, the highway occupancy by vehicles, the parking and the controlled territory are introduced. Technical realizabilityof organizing the necessary flow of information on the state of the transport system for its regulation has been marked. Sequence of practical implementation of the solution is given. An algorithm for predicting traffic congestion in the controlled transport system is suggested.

Deformation and Quaternary Faulting in Southeast Missouri across the Commerce Geophysical Lineament

USGS Publications Warehouse

Stephenson, W.J.; Odum, J.K.; Williams, R.A.; Pratt, T.L.; Harrison, R.W.; Hoffman, D.

1999-01-01

High-resolution seismic-reflection data acquired at three sites along the surface projection of the Commerce geophysical lineament in southeast Missouri reveal a complex history of post-Cretaceous faulting that has continued into the Quaternary. Near Qulin, Missouri, approximately 20 m of apparent vertical fault displacement has occurred in the Quaternary. Reflection data collected at Idalia Hill, about 45 km to the northeast, reveal a series of reverse and possibly right-lateral strike-slip faults with Quaternary displacement. In the Benton Hills, 45 km northeast of Idalia Hill, seismic data image a complicated series of anticlinal and synclinal fault-bounded blocks immediately north of the Commerce fault. We infer that most of the deformation imaged in the upper 400 m of these three data sets occurred since post-Cretaceous time, and a significant portion of it occurred during Quaternary time. Collectively, these seismic data along with geomorphic and surface-geologic evidence suggest (1) the existence of at least one potential seismogenic structure in southeastern Missouri outside the main zones of New Madrid seismicity, and (2) these structures have been active during the Quaternary. The geographic location of the imaged deformation suggests it is related to structures along with the Commerce geophysical lineament.

Versatile methods for synthesizing organic acid salts of quaternary berberine-type alkaloids as anti-ulcerative colitis agents.

PubMed

Zhang, Zhi-Hui; Li, Jing; Zhang, Hai-Jing; Deng, An-Jun; Wu, Lian-Qiu; Li, Zhi-Hong; Song, Hong-Rui; Wang, Wen-Jie; Qin, Hai-Lin

2016-06-01

Two versatile methods to synthesize kinds of organic acid salts of quaternary berberine-type alkaloids were investigated in order to determine which is more efficient to improve the liposolubility of the target compounds and to explore the efficacy of the target compounds as anti-ulcerative colitis (UC) agents. Overall evaluation according to the reaction results and yields of the final products indicated that the synthetic method using tertiary (±)-8-acylmethyldihydroberberine-type alkaloids as key intermediates is superior to that of using tertiary dihydroberberine-type alkaloids as intermediates. Ten target compounds were synthesized using quaternary berberine chloride and quaternary coptisine chloride as starting materials, respectively, and the anti-UC activity of some target compounds was evaluated in an in vitro x-box-binding protein 1 (XBP1) transcriptional activity assay using dual luciferase reporter detection. At 10 μM, the tested compounds were found to activate the transcription of XBP1 target at almost the same level as that of quaternary coptisine chloride. The synthesized target compounds were also found to share higher liposolubility than the inorganic acid salts of quaternary berberine-type alkaloid.

Quaternary extensional growth folding beneath Reno, Nevada, imaged by urban seismic profiling

USGS Publications Warehouse

Stephenson, William J.; Frary, Roxy N.; Louie, John; Odum, Jackson K.

2013-01-01

We characterize shallow subsurface faulting and basin structure along a transect through heavily urbanized Reno, Nevada, with high‐resolution seismic reflection imaging. The 6.8 km of P‐wave data image the subsurface to approximately 800 m depth and delineate two subbasins and basin uplift that are consistent with structure previously inferred from gravity modeling in this region of the northern Walker Lane. We interpret two primary faults that bound the uplift and deform Quaternary deposits. The dip of Quaternary and Tertiary strata in the western subbasin increases with greater depth to the east, suggesting recurrent fault motion across the westernmost of these faults. Deformation in the Quaternary section of the western subbasin is likely evidence of extensional growth folding at the edge of the Truckee River through Reno. This deformation is north of, and on trend with, previously mapped Quaternary fault strands of the Mt. Rose fault zone. In addition to corroborating the existence of previously inferred intrabasin structure, these data provide evidence for an active extensional Quaternary fault at a previously unknown location within the Truckee Meadows basin that furthers our understanding of both the seismotectonic framework and earthquake hazards in this urbanized region.

Connected vehicle freeway speed harmonization systems.

DOT National Transportation Integrated Search

2016-03-15

The capacity drop phenomenon, which reduces the maximum bottleneck discharge rate following the onset of congestion, is a critical restriction in transportation networks that causes additional traffic congestion. Consequently, preventing or reducing ...

Speed harmonization

DOT National Transportation Integrated Search

2015-01-01

Speed harmonization is a method to reduce congestion and improve traffic performance. This method is applied at points where lanes merge and form bottlenecks, the greatest cause of congestion nationwide. The strategy involves gradually lowering speed...

Synthesis of spiro quasi[1]catenanes and quasi[1]rotaxanes via a templated backfolding strategy

PubMed Central

Steemers, Luuk; Wanner, Martin J.; Lutz, Martin; Hiemstra, Henk; van Maarseveen, Jan H.

2017-01-01

Due to their well-defined three-dimensional geometry, spiro compounds are widely utilized in drug research. From the central tetrahedral carbon atom, besides the regular structure, an inverted spiro connectivity may be envisioned. Here we disclose the synthesis of this molecule class that we have coined quasi[1]catenanes. Next to their fascinating and aesthetic shape, the higher compactness as compared to regular spiro bicycles is noteworthy. To enable synthetic access to compact entangled multimacrocyclic molecules, we have developed a new strategy. The key element is a template, which is covalently connected to the linear precursors, and spatially directs the sterically congested backfolding macrocyclizations that are required to give quasi[1]catenanes. Similarly, quasi[1]rotaxanes are made. PMID:28541349

An Applied Ecological Framework for Evaluating Infrastructure to Promote Walking and Cycling: The iConnect Study

PubMed Central

Bull, Fiona; Powell, Jane; Cooper, Ashley R.; Brand, Christian; Mutrie, Nanette; Preston, John; Rutter, Harry

2011-01-01

Improving infrastructure for walking and cycling is increasingly recommended as a means to promote physical activity, prevent obesity, and reduce traffic congestion and carbon emissions. However, limited evidence from intervention studies exists to support this approach. Drawing on classic epidemiological methods, psychological and ecological models of behavior change, and the principles of realistic evaluation, we have developed an applied ecological framework by which current theories about the behavioral effects of environmental change may be tested in heterogeneous and complex intervention settings. Our framework guides study design and analysis by specifying the most important data to be collected and relations to be tested to confirm or refute specific hypotheses and thereby refine the underlying theories. PMID:21233429

Prognostic Significance of Creatinine Increases During an Acute Heart Failure Admission in Patients With and Without Residual Congestion: A Post Hoc Analysis of the PROTECT Data.

PubMed

Metra, Marco; Cotter, Gad; Senger, Stefanie; Edwards, Christopher; Cleland, John G; Ponikowski, Piotr; Cursack, Guillermo C; Milo, Olga; Teerlink, John R; Givertz, Michael M; O'Connor, Christopher M; Dittrich, Howard C; Bloomfield, Daniel M; Voors, Adriaan A; Davison, Beth A

2018-05-01

The importance of a serum creatinine increase, traditionally considered worsening renal function (WRF), during admission for acute heart failure has been recently debated, with data suggesting an interaction between congestion and creatinine changes. In post hoc analyses, we analyzed the association of WRF with length of hospital stay, 30-day death or cardiovascular/renal readmission and 90-day mortality in the PROTECT study (Placebo-Controlled Randomized Study of the Selective A1 Adenosine Receptor Antagonist Rolofylline for Patients Hospitalized With Acute Decompensated Heart Failure and Volume Overload to Assess Treatment Effect on Congestion and Renal Function). Daily creatinine changes from baseline were categorized as WRF (an increase of 0.3 mg/dL or more) or not. Daily congestion scores were computed by summing scores for orthopnea, edema, and jugular venous pressure. Of the 2033 total patients randomized, 1537 patients had both available at study day 14. Length of hospital stay was longer and 30-day cardiovascular/renal readmission or death more common in patients with WRF. However, these were driven by significant associations in patients with concomitant congestion at the time of assessment of renal function. The mean difference in length of hospital stay because of WRF was 3.51 (95% confidence interval, 1.29-5.73) more days ( P =0.0019), and the hazard ratio for WRF on 30-day death or heart failure hospitalization was 1.49 (95% confidence interval, 1.06-2.09) times higher ( P =0.0205), in significantly congested than nonsignificantly congested patients. A similar trend was observed with 90-day mortality although not statistically significant. In patients admitted for acute heart failure, WRF defined as a creatinine increase of ≥0.3 mg/dL was associated with longer length of hospital stay, and worse 30- and 90-day outcomes. However, effects were largely driven by patients who had residual congestion at the time of renal function assessment. URL: https://www.clinicaltrials.gov. Unique identifiers: NCT00328692 and NCT00354458. © 2018 American Heart Association, Inc.

Subsurface stratigraphy and geochemistry of late Quaternary evaporites, Searles Lake, California, with a section on radiocarbon ages of stratigraphic units

USGS Publications Warehouse

Smith, George I.; Stuiver, Minze

1979-01-01

Searles Lake is a dry salt pan, about 100 km 2 in area, that lies on the floor of Searles Valley, in the desert of southeast California. Several salt bodies of late Quaternary age lie beneath the surface, mostly composed of sodium and potassium carbonate, sulfate, chloride, and borate minerals. Mud layers separate the salt bodies, which contain interstitial brine that is the source of large quantities of industrial chemicals. The value of annual production from the deposit exceeds $30 million; total production to date exceeds $1 billion. The salts and muds were deposited during Pleistocene and Holocene times by a series of large lakes (200 m maximum depth, 1,000 km 2 maximum area) that fluctuated in size in response to climatic change. Salts were deposited during major dry (interpluvial) episodes, muds during wet (pluvial) episodes that correlate with glacial advances in other parts of North America and the world. Data based on cores from the deposit are used in this paper to establish the stratigraphy of the deposit, the chemical and mineral compositions of successive units, and the total quantities of components contained by them. These parameters are then used to determine the geochemical evolution of the sedimentary layers. The results provide a refined basis for reconstructing the limnology of Searles Lake and the regional climate during late Quaternary time. Six main stratigraphic units were distinguished and informally named earlier on the basis of their dominant composition: Unit Typical thickness 14C age, uncorrected (in meters) (years B.P.) Overburden Mud 7 0 to >3,500 Upper Salt 15 >3,500 to 10,500 Parting Mud 4 10,500 to 24,000 Lower Salt 12 24,000 to 32,500 Bottom Mud 30 32,500 to 130,000 Mixed Layer 200+ > 130,000 (The age of 130,000 years for the Mixed Layer is based on extrapolated sedimentation rates.) The Lower Salt is subdivided into seven salt units (S-l to S-7) and six mud units (M-2 to M-7), the Mixed Layer into six units (A to F). For each salt unit, the areal extent, volume, shape, mineralogy, and chemical composition of the solids and brines have been determined; for each mud unit (which originally extended over much of the basin), the shape and volume within a standard area, and the mineralogy, have been determined. The bulk compositions (brines plus salts) of the combined Lower Salt units S-l to S-5 and units S-6 and S-7, and the Upper Salt, were determined so that the total quantities and ratios of ions in the initial brines could be reconstructed. The 74 published HC dates on Searles Lake core samples from all but the oldest unit are supplemented by 14 new dates (determined by Minze Stuiver) on the Lower Salt. Most of the age control comes from dates based on disseminated organic carbon; two dates are on wood; dates on carbonate minerals are less reliable. Although the probable disequilibrium between the carbon in the lake and atmosphere (because of contamination, slow equilibrium rates, and other factors) causes disseminated carbon dates to be an estimated 500-2,500 years 'too old,' the ages of the major and minor units are relatively well established. The list above indicates rounded and uncorrected ages for the contacts of major units. The age of the only salt bed in the Lower Salt which indicates desiccation (S-5) is about 28,000 years. The average uncorrected sedimentation rate in the Parting Mud is 4

Lithological and Petrographic Analyses of Carbonates and Sandstones From the Southern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Garcia-Avendaño, A.; Urrutia-Fucugauchi, J.

2012-04-01

We present results of sedimentological and petrological studies of drill cores from the Bay of Campeche in the southern Gulf of Mexico. Based on reports on drill cores obtained from oil exploratory wells in the Cantarell Complex located 80 kilometres offshore in the Bay of Campeche and studies related to regional geology composite simplified stratigraphic columns for offshore Campeche region have been constructed up to depths of approximately 5000 m. The stratigraphic column is formed by a thick sediment sequence of Middle Jurassic age (evaporites, Callovian), Late Jurassic (terrigenous, calcareous clays and calcareous layers), Lower Cretaceous (carbonates), Upper Cretaceous-Paleogene (calcareous breccias), Paleogene-Neogene (terrigenous-carbonates intercalations) and Quaternary (terrigenous). The core samples studied come from wells in the Sihil and Akal fields in Cantarell. Analysis of reports on lithological descriptions indicates that these wells sample dolomitized sedimentary breccias from the Upper Cretaceous-Paleocene and fine-grained sandstones from the Late Jurassic Tithonian, respectively. Based on results of petrographic studies, the texture, cementing material and porosity of the units have been documented. The thin sections for carbonates were classified based on their texture according to Dunham (1962) for carbonate rocks, classified according to their components using the ternary diagrams of Folk (1974). Percentages refer to the data presented in tables, which were obtained by point-counting technique (with a total 250). Photomicrographs of scanning electron microscope (SEM) provide magnification for easy documentation of crystalline arrangements and description of micro-porous for different types of carbonates such as dolomite, in addition to the morphology of authigenic clays. Results of these studies and previous works in the area permit characterization of diagenetic processes of the carbonate sediments in the Campeche Bay, and provide information related to oil maturation, storage and potential flow in the Cantarell reservoirs.

Activity and Stability of Dispersed Multi Metallic Pt-based Catalysts for CO Tolerance in Proton Exchange Membrane Fuel Cell Anodes.

PubMed

Hassan, Ayaz; Ticianelli, Edson A

2018-01-01

Studies aiming at improving the activity and stability of dispersed W and Mo containing Pt catalysts for the CO tolerance in proton exchange membrane fuel cell (PEMFC) anodes are revised for the following catalyst systems: (1) a carbon supported PtMo electrocatalyst submitted to heat treatments; (2) Pt and PtMo nanoparticles deposited on carbon-supported molybdenum carbides (Mo2C/C); (3) ternary and quaternary materials formed by PtMoFe/C, PtMoRu/C and PtMoRuFe/C and; (4) Pt nanoparticles supported on tungsten carbide/carbon catalysts and its parallel evaluation with carbon supported PtW catalyst. The heat-treated (600 oC) Pt-Mo/C catalyst showed higher hydrogen oxidation activity in the absence and in the presence of CO and better stability, compared to all other Mo-containing catalysts. PtMoRuFe, PtMoFe, PtMoRu supported on carbon and Pt supported on Mo2C/C exhibited similar CO tolerances but better stability, as compared to as-prepared PtMo supported on carbon. Among the tungsten-based catalysts, tungsten carbide supported Pt catalyst showed reasonable performance and reliable stability in comparison to simple carbon supported PtW catalyst, though an uneven level of catalytic activity towards H2 oxidation in presence of CO is observed for the former as compared to Mo containing catalyst. However, a small dissolution of Mo, Ru, Fe and W from the anodes and their migration toward cathodes during the cell operation is observed. These results indicate that the fuel cell performance and stability has been improved but not yet totally resolved.

Analysis and Characterization of Organic Carbon in Early Holocene Wetland Paleosols using Ramped Pyrolysis 14C and Biomarkers

NASA Astrophysics Data System (ADS)

Vetter, L.; Schreiner, K. M.; Fernandez, A.; Rosenheim, B. E.; Tornqvist, T. E.

2014-12-01

Radiocarbon analyses are a key tool for quantifying the dynamics of carbon cycling and storage in both modern soils and Quaternary paleosols. Frequently, bulk 14C dates of paleosol organic carbon provide ages older than the time of soil burial, and 14C dates of geochemical fractions such as alkali and acid extracts (operationally defined as humic acids) can provide anomalously old ages when compared to coeval plant macrofossil dates. Ramped pyrolysis radiocarbon analysis of sedimentary organic material has been employed as a tool for investigating 14C age spectra in sediments with multiple organic carbon sources. Here we combine ramped pyrolysis 14C analysis and biomarker analysis (lignin-phenols and other cupric oxide products) to provide information on the source and diagenetic state of the paleosol organic carbon. We apply these techniques to immature early Holocene brackish wetland entisols from three sediment cores in southeastern Louisiana, along with overlying basal peats. Surprisingly, we find narrow 14C age spectra across all thermal aliquots from both paleosols and peats. The weighted bulk 14C ages from paleosols and overlying peats are within analytical error, and are comparable to independently analyzed 14C AMS dates from charcoal fragments and other plant macrofossils from each peat bed. Our results suggest high turnover rates of carbon in soils relative to input of exogenous carbon sources. These data raise broader questions about processes within the active soil and during pedogenesis and burial of paleosols that can effectively homogenize radiocarbon content in soils across the thermochemical spectrum. The concurrence of paleosol and peat 14C ages also suggests that, in the absence of peats with identifiable plant macrofossils, ramped pyrolysis 14C analyses of paleosols may be used to provide ages for sea-level indicators.

Micromorphological investigations of the Late Quaternary loess-paleosol sequences of the Kashmir Valley, India

NASA Astrophysics Data System (ADS)

Dar, Reyaz Ahmad; Chandra, Rakesh; Romshoo, Shakil Ahmad; Kowser, Nazia

2015-11-01

The loess-paleosol sequences of the Karewa Group preserve a valuable repository of the Late Quaternary climatic changes and the landscape evolution history of the Karewa Basin of Kashmir Valley in their lithological and pedogenic records. Three representative loess-paleosol sections at Shankerpora (SP), Khan Sahib (KS) and Pattan (PT) localities were chosen for detailed lithostratigraphic fieldwork and micromorphological observations of thin sections. Lithostratigraphic analysis revealed lateral and vertical variation in thickness and number of paleosol profiles from south-west to north-west of the Karewa Basin suggesting the availability of land-surface for periodic loess deposition. The SP section is marked by 6 (SP-S6, S7, S8, S9, S10, S12), KS section by 3 (KS-S2, S4, S5) and PT section by 2 (PT-S1, S3) thick mature paleosol profiles. Theses paleosols have well developed 'Ah' and 'Btk' horizons representing prolonged land-surface stability when pedogenic processes outpace loess deposition. On the other hand comparatively thin to thick paleosol profiles represent weak to moderate pedogenic maturity indicating short stratigraphic breaks with rapid loess deposition. Micromorphological observations of thin sections suggested that clay illuviation and CaCO3 accumulation have operated within the paleosol profiles. CaCO3 features are often associated with clay coatings suggesting decalcification of carbonates followed by clay illuviation. Pedogenic CaCO3 probably resulted from the precipitation of the soil solution near the average depth of wetting front. The pedogenic CaCO3, illuvial clay, mottles, iron manganese features, pedal microstructure and blocky aggregates reveal variation in the pedogenic maturity among and within the loess-paleosol sections. The morphological (both micro- and macro-morphological) attributes of loess-paleosols suggest variation of climatic conditions during the Late Quaternary period in the Karewa Basin of Kashmir Valley, India.

Composition of Sediment Inputs to the Hikurangi Subduction Margin: A Prelude to IODP Expedition 375

NASA Astrophysics Data System (ADS)

Underwood, M.

2017-12-01

Expedition 375 of the International Ocean Discovery Program is scheduled to begin drilling offshore New Zealand in March 2018. Two sites will be cored seaward of the Hikurangi subduction front (subduction inputs), plus one site at the toe of the accretionary prism, and one site in the forearc above a zone of well-documented slow-slip events. One of the challenges during planning for Expedition 375 has been the total absence of pre-existing compositional data from the region; that lack of basic information impacts such tasks as mixing and analysis of appropriate standards for X-ray diffraction, error analysis, computation of accurate normalization factors, and QA/QC. To help overcome those deficiencies, I analyzed a total of 152 samples from ODP Sites 1123 (Quaternary to Eocene), 1124 (Quaternary to Cretaceous), and 1125 (Quaternary to Miocene), plus piston/gravity-core samples from the repositories at Lamont-Doherty, Oregon State, and NIWA. The results reveal an unusually large range of compositions for the bulk sediments. The relative abundance of total clay minerals ranges from 3 to 64 wt%. Quartz ranges from 0 to 39 wt%. Feldspar ranges from 0 to 40 wt%, and calcite ranges from 0 to 93 wt%. Samples from the Hikurangi Plateau and Chatham Rise are carbonate-rich, with many bordering on almost-pure nannofossil chalk. Hemipelagic muds from the floor of Hikurangi Trough, Ruatoria slide, and the landward slope of the trench are fairly uniform, with averages of 36 wt% total clay minerals, 27 wt% quartz, 24 wt% feldspar, and 13 wt% calcite. Unlike many other subduction zones, this diversity of lithologies will save shipboard scientists from repetitive, mind-numbing descriptions and analyses, and shorebased experiments for frictional properties, permeability, and consolidation will need to pay close attention to the compositional attributes of the specimens. In addition, results from the four IODP boreholes can be interpreted within a broader, regional-scale framework of sediment provenance and dispersal.

Sequential character of low-energy ternary and quaternary nuclear fission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kadmensky, S. G., E-mail: kadmensky@phys.vsu.ru; Bulychev, A. O.

2016-09-15

An analysis of low-energy true ternary (quaternary) nuclear fission leads to the conclusion that these fission modes have a sequential two-step (three-step) character such that the emission of a third particle (third and fourth particles) and the separation of fission fragments occur at distinctly different instants, in contrast to the simultaneous emergence of all fission products in the case of onestep ternary (quaternary) fission. This conclusion relies on the following arguments. First, the emission of a third particle (third and fourth particles) from a fissile nucleus is due to a nonevaporative mechanism associated with a nonadiabatic character of the collectivemore » deformation motion of this nucleus at the stages preceding its scission. Second, the axial symmetry of the deformed fissile compound nucleus and the direction of its symmetry axis both remain unchanged at all stages of ternary (quaternary) fission. This circumstancemakes it possible to explain themechanism of the appearance of observed anisotropies and T — odd asymmeries in the angular distributions of products of ternary (quaternary) nuclear fission. Third, the T —odd asymmetry discovered experimentally in ternary nuclear fission induced by cold polarized neutrons obeys the T —invariance condition only in the case of a sequential two-step (three-step) character of true ternary (quaternary) nuclear fission. At the same time, this asymmetry is not a T —invariant quantity in the case of the simultaneous emission of products of true ternary (quaternary) nuclear fission from the fissile compound nucleus.« less

Influence of the Palaeo-Landslides on the Project of Rehabilitation of a National Road in the Southern Carpathian Area

NASA Astrophysics Data System (ADS)

Mihailescu, Daniel; Milutinovici, Emilia

2017-12-01

The mountain Paduchiosu is a part of the Southern Carpathians, in the South-Eastern Bucegi National Park. Significant palaeo-landslides occur on the Eastern slope of the mountain Paduchiosu, affecting the DN 71 alignment, between Valea Dorului and Valea Carpinis, on a length of approx. 10 km [1]. The palaeo-landslides occur along the tectonic contacts of various cretaceous formations. The landslides occur both at the level of Quaternary deposits, forming the alteration layer of the old geological formations (alluvial, deluvial and colluvial soil deposits), and at the level of Pre-Quaternary geological formations, whose structure is clayey-marl, or within the harder rocky formations, with seams of clayey - marl nature also. Two large palaeo-landslides can be distinguished: landslide I, affecting the national road alignment between pk 96 and 101+500, with sliding orientation towards South and South-West and landslide II, affecting the analysed alignment between pk 102+500 and 106 (with sliding orientation towards East and North-East). The landslides are significant and very old. The main cause of occurrence of these landslides is the tectonic nature of the area. The two main landslides occur on large surfaces. Generally, the sliding plan is under the „fissure clay” level, so it tends to be 12 to15 m deep. Numerous reactivations occur within their congestion, on narrow or large surfaces. Many of the reactivations occur due to the malfunctions of the systems of rainfall draining and taking over from the national road that runs South to North on the Southern slope of the mountain Paduchiosu. There are no underground waters, but considering the change of the natural water drainage due to the existing road works, there are areas where the drainage is impeded or slowed, leading to the water infiltration and rocks moistening under the deluvial formation. The local reactivations may also be influenced by the unarranged torrential valleys. The project of rehabilitation of DN 71 is strongly influenced by existence of these significant landslides. Acknowledgement of the risk of landslide and allocation of funds for maintenance and remedial of the arisen damages following reactivations, as well as monitorization of the road areas affected by the landslides both during the works and after their completion, during operation, is the rightest solution, and actually, the least expensive one.

Clinical, double-blind, placebo-controlled study investigating the combination of acetylsalicylic acid and pseudoephedrine for the symptomatic treatment of nasal congestion associated with common cold.

PubMed

Loose, Irene; Winkel, Matthias

2004-01-01

It was the aim of this clinical study to demonstrate the efficacy of 1000 mg acetylsalicylic acid (ASA, CAS 50-78-2) in combination with 60 mg pseudoephedrine (PSE, CAS 90-82-4), compared with placebo, in the symptomatic treatment of nasal congestion associated with the common cold. A further aim was to demonstrate the efficacy of 500 mg ASA + 30 mg PSE and of 1000 mg paracetamol (CAS 103-90-2) + 60 mg PSE (active control) in the symptomatic treatment of nasal congestion. The study was designed as a randomized, two-center, double-blind, double-dummy, placebo-controlled, parallel-group, single-dose efficacy and safety trial over 6 h and was carried out in the USA. In total, at two centers, 643 patients who had a history and diagnosis of acute upper respiratory tract infection (URTI), were included; they showed symptoms such as nasal congestion, scratchy/sore throat, headache, generalized muscle ache, earache, runny nose, fever, sneezing etc. The investigational drugs ASA and PSE were both provided as granules in sachets and the granules were dissolved in water before administration; the combined preparation of paracetamol + PSE was administered as commercially available tablets encapsulated for blinding. For all preparations, matching placebos were provided. The primary efficacy variable was the area under the curve for differences from baseline on a nasal congestion scale in the first 2 h after treatment. To be eligible for the study, otherwise healthy volunteers were to present with nasal stuffiness of recent onset that reached a score of at least 6 on the 11-point scale for nasal congestion (0 = not stuffy, 10 = very stuffy). The primary analysis of the primary efficacy variable was calculated by analysis of variance including treatment group, severity (moderate/severe) and center as main strata. The analysis was performed using the intent-to-treat population. All active treatments proved to be statistically significantly superior to placebo with regard to the primary efficacy variable. Significant superiority of active treatment compared with placebo could also be demonstrated for an interval of up to 6 h after intake of the drug and for the relief of nasal congestion. The lower dose did not reveal significant different results compared with placebo for relief of nasal congestion in patients with a severe nasal congestion score at baseline. As well in patients with moderate nasal congestion score (NCS) at start of the study the difference from baseline in the NCS compared with placebo was not statistically significant. Thus a trend towards better efficacy in the higher dose could be assumed. No difference was found between 1000 mg ASA + 60 mg PSE and the active control. There were no differences between the two centers. The treatment proved to be safe and well tolerated, without relevant differences between the four treatment groups. Main adverse events were found to be related to the upper respiratory tract infection or were of gastrointestinal nature. In conclusion, the combination of ASA with PSE can be considered as an effective and safe remedial for the symptomatic treatment of the nasal congestion during URTI.

Land use and traffic congestion.

DOT National Transportation Integrated Search

2012-03-01

"The study investigated the link between land use, travel behavior, and traffic congestion. Popular wisdom : suggests that higher-density development patterns may be beneficial in reducing private vehicle dependency : and use, which if true, could ho...

Guidelines for operating congested traffic signals.

DOT National Transportation Integrated Search

2010-08-01

The objective of this project was to develop guidelines for mitigating congestion in traffic signal systems. As : part of the project, researchers conducted a thorough review of literature and developed preliminary : guidelines for combating congesti...

I-55 integrated diversion traffic management benefit study.

DOT National Transportation Integrated Search

2014-11-01

Traffic congestion, recurrent and non-recurrent, creates significant economic losses and environmental impacts. : Integrated Corridor Management (ICM) is a U.S.DOT research initiative that has been proven to effectively relieve : recurrent congestion...

New entrant safety research

DOT National Transportation Integrated Search

1994-07-22

This study pursued five objectives. The first objective was the development of a study data base. Second, the study provided a general understanding of congestion. This understanding should include techniques for defining and measuring congestion as ...

Congestion information surveillance system

DOT National Transportation Integrated Search

1992-10-14

This document advances a proposal to implement a Congestion Information Surveillance System (CISS)for the Albuquerque metropolitan area. The CISS will offer agencies in the region responsible for transportation and air quality management a new capabi...

Modeling truck traffic volume growth congestion.

DOT National Transportation Integrated Search

2009-05-01

Modeling of the statewide transportation system is an important element in understanding issues and programming of funds to thwart potential congestion. As Alabama grows its manufacturing economy, the number of heavy vehicles traversing its highways ...

Measuring and improving performance in incident management.

DOT National Transportation Integrated Search

2010-03-01

Traffic incidents account for about 25 percent of traffic congestion and delay. Clearing incidents rapidly is crucial in : minimizing congestion, reducing secondary crashes and improving safety for both emergency responders and : travelers. Especiall...

Congestion Management System Process Report

DOT National Transportation Integrated Search

1996-03-01

In January 1995, the Indianapolis Metropolitan Planning Organization with the help of an interagency Study Review Committee began the process of developing a Congestion Management System (CMS) Plan resulting in this report. This report documents the ...

Developing a congestion mitigation toolbox.

DOT National Transportation Integrated Search

2011-09-30

Researchers created A Michigan Toolbox for Mitigating Traffic Congestion to be a useful desk reference for practitioners and an educational tool for elected officials acting through public policy boards to better understand the development, planning,...

Effect of alkyl side chain location and cyclicity on the aerobic biotransformation of naphthenic acids.

PubMed

Misiti, Teresa M; Tezel, Ulas; Pavlostathis, Spyros G

2014-07-15

Aerobic biodegradation of naphthenic acids is of importance to the oil industry for the long-term management and environmental impact of process water and wastewater. The effect of structure, particularly the location of the alkyl side chain as well as cyclicity, on the aerobic biotransformation of 10 model naphthenic acids (NAs) was investigated. Using an aerobic, mixed culture, enriched with a commercial NA mixture (NA sodium salt; TCI Chemicals), batch biotransformation assays were conducted with individual model NAs, including eight 8-carbon isomers. It was shown that NAs with a quaternary carbon at the α- or β-position or a tertiary carbon at the β- and/or β'-position are recalcitrant or have limited biodegradability. In addition, branched NAs exhibited lag periods and lower degradation rates than nonbranched or simple cyclic NAs. Two NA isomers used in a closed bottle, aerobic biodegradation assay were mineralized, while 21 and 35% of the parent compound carbon was incorporated into the biomass. The NA biodegradation probability estimated by two widely used models (BIOWIN 2 and 6) and a recently developed model (OCHEM) was compared to the biodegradability of the 10 model NAs tested in this study as well as other related NAs. The biodegradation probability estimated by the OCHEM model agreed best with the experimental data and was best correlated with the measured NA biodegradation rate.

Targeting congestion in allergic rhinitis: the importance of intranasal corticosteroids.

PubMed

Marple, Bradley F

2008-01-01

The cardinal nasal symptoms of allergic rhinitis (AR) are sustained by an underlying inflammatory process. Congestion is one of the most prominent and distressing symptoms for patients and is strongly associated with a broadly deteriorated quality of life and significant losses in productivity. The purpose of this study was to explore the role of intranasal corticosteroids (INSs) in down-regulating the inflammatory response to allergen and their clinical efficacy on AR symptoms, particularly congestion. AR is characterized by an influx of inflammatory cells and mediators into the nasal mucosa after antigen exposure. The response is biphasic, encompassing an early and a late phase. Antigen exposure has a priming effect, decreasing the threshold for subsequent allergic reaction on rechallenge and increasing the responsiveness of the nasal mucosa. INSs are a mainstay of therapy for AR and the most effective intervention for nasal congestion and other nasal symptoms, with established superiority to antihistamines, decongestants, and leukotriene antagonists. In addition to symptom relief, INSs suppress numerous stages of the inflammatory cascade, inhibiting the influx of inflammatory cells and mediators. Topical nasal corticosteroids have a low incidence of local adverse effects, negligible systemic absorption, and excellent safety. Congestion is one of the most bothersome symptoms of AR. INS therapy improves AR symptoms, with particular efficacy in relieving congestion, by attenuating nasal hyperresponsiveness. Pretreatment with INSs has been shown to relieve early and late-phase clinical symptoms of AR. Modification of the disease process results in significant relief of symptoms and leads to fewer disease exacerbations.

Random early detection for congestion avoidance in wired networks: a discretized pursuit learning-automata-like solution.

PubMed

Misra, Sudip; Oommen, B John; Yanamandra, Sreekeerthy; Obaidat, Mohammad S

2010-02-01

In this paper, we present a learning-automata-like The reason why the mechanism is not a pure LA, but rather why it yet mimics one, will be clarified in the body of this paper. (LAL) mechanism for congestion avoidance in wired networks. Our algorithm, named as LAL Random Early Detection (LALRED), is founded on the principles of the operations of existing RED congestion-avoidance mechanisms, augmented with a LAL philosophy. The primary objective of LALRED is to optimize the value of the average size of the queue used for congestion avoidance and to consequently reduce the total loss of packets at the queue. We attempt to achieve this by stationing a LAL algorithm at the gateways and by discretizing the probabilities of the corresponding actions of the congestion-avoidance algorithm. At every time instant, the LAL scheme, in turn, chooses the action that possesses the maximal ratio between the number of times the chosen action is rewarded and the number of times that it has been chosen. In LALRED, we simultaneously increase the likelihood of the scheme converging to the action, which minimizes the number of packet drops at the gateway. Our approach helps to improve the performance of congestion avoidance by adaptively minimizing the queue-loss rate and the average queue size. Simulation results obtained using NS2 establish the improved performance of LALRED over the traditional RED methods which were chosen as the benchmarks for performance comparison purposes.

Synthesis and Characterization of Perfluoro Quaternary Ammonium Anion Exchange Membranes

DTIC Science & Technology

2012-01-01

study, new alkaline exchange membranes were prepared from the perfluorinated 3M ionomer with various quaternary ammonium cations attached with...ammonium anion exchange membranes Report Title ABSTRACT In this study, new alkaline exchange membranes were prepared from the perfluorinated 3M ionomer...exchange membranes were prepared from the perfluorinated 3M ionomer with vari- ous quaternary ammonium cations attached with sulfonamide linkage. The

Self-Assembly of Helical Ribbons

DTIC Science & Technology

1999-07-01

detergent, a phosphatidylcholine or a fatty acid , and a steroid analog of cholesterol. In almost all systems, two different pitch types of helical...quater- nary sterol systems (QSS), on a quaternary fatty acid system (QFAS), and on two lipid concentrate systems, as defined below. In addition to high...lipid concentrate; QSS, quaternary sterol systems; QFAS, quaternary fatty acid system; NaTC, sodium taurocholate; DOPC, 1,2-dioleoyl-glycero- 3

Geomorphology of submerged river channels indicates Late Quaternary tectonic activity in the Gulf of Trieste, Northern Adriatic

NASA Astrophysics Data System (ADS)

Vrabec, M.; Slavec, P.; Poglajen, S.; Busetti, M.

2012-04-01

We use multibeam and parametric subbottom sonar data, complemented with multichannel and high-resolution single-channel seismic profiles, to investigate sea-bottom morphology and subbottom sediment structure in the south-eastern half of the Gulf of Trieste, northern Adriatic Sea. The study area comprises 180 km2 of predominantly flat seabed with the water depth from 20 to 25 m. Pre-Quaternary basement consists of Mesozoic-Paleogene carbonate platform unit, overlain by Eocene marls and sandstones, covered by up to 300 m thick Quaternary sediments of predominantly continental origin. The uppermost few meters of sediment consist of Holocene fine-grained marine deposits. Structurally, the investigated area belongs to the imbricated rim of the Adriatic microplate and is dissected by several NE-dipping low-angle thrusts with up to several kms of displacement. The thrusts are cut by younger NE-SW-trending steeply dipping faults with sinistral and/or normal offset, mapped onshore. The continuation of those faults into the offshore area is suggested by mismatch of thrust structures between parallel seismic profiles. Geodetic data on present-day tectonic activity is controversial. Whereas the Adriatic microplate is currently moving northwards towards Eurasia at the rate of 2-4 mm/yr, the GNSS data show no measurable deformation in the Gulf of Trieste. On the other hand, onshore precise-levelling data suggest localized vertical motions in the range of 1 mm/yr, interpreted as an indication of thrust activity. High-resolution swath bathymetry revealed several current-related erosional and depositional features such as gullies and megadunes with up to 5 m of relief. The most conspicuous seabed morphological features are pre-Holocene river channels preserved in low-erosion submarine environment, which make excellent markers for studying the long-term geomorphological evolution of the area. The WNW-ESE-trending paleo-Rižana river is characterized by highly sinuous meandering channels. Sequential profiles perpendicular to the river course suggest consistent ~NE-ward lateral shifting of channels, parallel with inclination of the present-day seabed and with the present-day lateral gradient in channel depth. A longitudinal profile of the Rižana river plain revealed downstream increase in elevation of the stream bed, visible both from seabed bathymetry and from vertical position of channel lag deposits in subbottom sonar profiles. These observations suggest post-depositional tectonic tilting of the fluvial sediments that could be related either to activation of NE-dipping thrusts in the pre-Quaternary basement, or to minor anticlinal folding associated with Quaternary transpressional faulting along NW-SE-trending zones, implied from seismic profiles NW-ward of our study area. An enigmatic low-sinuosity channel feature runs along the coastline in the NE-SW direction and crosses the paleo-Rižana channel. Subbottom sonar profiles show asymmetric channel geometry and strong reflectors (channel lag deposits?) at the channel bottom, typical of other documented river channels in the area. This feature is vertically offset by a NE-SW-trending linear morphological flexure that corresponds in location and orientation to the onshore Monte Spaccato fault. Subbottom profiling revealed in several places an abrupt truncation of horizontal reflectors that could be manifestation of faulting. These indications of Late Quaternary - Holocene tectonic activity may have important implications for seismic hazard in the heavily populated coastal area of the Gulf of Trieste.

Reconnaissance study of late quaternary faulting along cerro GoDen fault zone, western Puerto Rico

USGS Publications Warehouse

Mann, P.; Prentice, C.S.; Hippolyte, J.-C.; Grindlay, N.R.; Abrams, L.J.; Lao-Davila, D.

2005-01-01

The Cerro GoDen fault zone is associated with a curvilinear, continuous, and prominent topographic lineament in western Puerto Rico. The fault varies in strike from northwest to west. In its westernmost section, the fault is ???500 m south of an abrupt, curvilinear mountain front separating the 270- to 361-m-high La CaDena De San Francisco range from the Rio A??asco alluvial valley. The Quaternary fault of the A??asco Valley is in alignment with the bedrock fault mapped by D. McIntyre (1971) in the Central La Plata quadrangle sheet east of A??asco Valley. Previous workers have postulated that the Cerro GoDen fault zone continues southeast from the A??asco Valley and merges with the Great Southern Puerto Rico fault zone of south-central Puerto Rico. West of the A??asco Valley, the fault continues offshore into the Mona Passage (Caribbean Sea) where it is characterized by offsets of seafloor sediments estimated to be of late Quaternary age. Using both 1:18,500 scale air photographs taken in 1936 and 1:40,000 scale photographs taken by the U.S. Department of Agriculture in 1986, we iDentified geomorphic features suggestive of Quaternary fault movement in the A??asco Valley, including aligned and Deflected drainages, apparently offset terrace risers, and mountain-facing scarps. Many of these features suggest right-lateral displacement. Mapping of Paleogene bedrock units in the uplifted La CaDena range adjacent to the Cerro GoDen fault zone reveals the main tectonic events that have culminated in late Quaternary normal-oblique displacement across the Cerro GoDen fault. Cretaceous to Eocene rocks of the La CaDena range exhibit large folds with wavelengths of several kms. The orientation of folds and analysis of fault striations within the folds indicate that the folds formed by northeast-southwest shorTening in present-day geographic coordinates. The age of Deformation is well constrained as late Eocene-early Oligocene by an angular unconformity separating folDed, Deep-marine middle Eocene rocks from transgressive, shallow-marine rocks of middle-upper Oligocene age. Rocks of middle Oligocene-early Pliocene age above unconformity are gently folDed about the roughly east-west-trending Puerto Rico-Virgin Islands arch, which is well expressed in the geomorphology of western Puerto Rico. Arching appears ongoing because onshore and offshore late Quaternary oblique-slip faults closely parallel the complexly Deformed crest of the arch and appear to be related to exTensional strains focused in the crest of the arch. We estimate ???4 km of vertical throw on the Cerro GoDen fault based on the position of the carbonate cap north of the fault in the La CaDena De San Francisco and its position south of the fault inferred from seismic reflection data in Mayaguez Bay. Based on these observations, our interpretation of the kinematics and history of the Cerro GoDen fault zone incluDes two major phases of motion: (1) Eocene northeast-southwest shorTening possibly accompanied by left-lateral shearing as Determined by previous workers on the Great Southern Puerto Rico fault zone; and (2) post-early Pliocene regional arching of Puerto Rico accompanied by normal offset and right-lateral shear along faults flanking the crest of the arch. The second phase of Deformation accompanied east-west opening of the Mona rift and is inferred to continue to the present day. ?? 2005 Geological Society of America.

Containing air pollution and traffic congestion: Transport policy and the environment in Singapore

NASA Astrophysics Data System (ADS)

Chin, Anthony T. H.

Land transportation remains one of the main contributors of noise and air pollution in urban areas. This is in addition to traffic congestion and accidents which result in the loss of productive activity. While there is a close relationship between traffic volumes and levels of noise and air pollution, transport authorities often assume that solving traffic congestion would reduce noise and air pollutant levels. Tight control over automobile ownership and use in Singapore has contributed in improving traffic flows, travel speeds and air quality. The adoption of internationally accepted standards on automobile emissions and gasoline have been effective in reducing air pollution from motor vehicles. Demand management measures have largely focused on controlling the source of traffic congestion, i.e. private automobile ownership and its use especially within the Central Business District during the day. This paper reviews and analyzes the effectiveness of two measures which are instrumental in controlling congestion and automobile ownership, i.e. road pricing and the vehicle quota scheme (VQS). While these measures have been successful in achieving desired objectives, it has also led to the spreading of traffic externalities to other roads in the network, loss in consumer welfare and rent seeking by automobile traders.

Automated Flight Routing Using Stochastic Dynamic Programming

NASA Technical Reports Server (NTRS)

Ng, Hok K.; Morando, Alex; Grabbe, Shon

2010-01-01

Airspace capacity reduction due to convective weather impedes air traffic flows and causes traffic congestion. This study presents an algorithm that reroutes flights in the presence of winds, enroute convective weather, and congested airspace based on stochastic dynamic programming. A stochastic disturbance model incorporates into the reroute design process the capacity uncertainty. A trajectory-based airspace demand model is employed for calculating current and future airspace demand. The optimal routes minimize the total expected traveling time, weather incursion, and induced congestion costs. They are compared to weather-avoidance routes calculated using deterministic dynamic programming. The stochastic reroutes have smaller deviation probability than the deterministic counterpart when both reroutes have similar total flight distance. The stochastic rerouting algorithm takes into account all convective weather fields with all severity levels while the deterministic algorithm only accounts for convective weather systems exceeding a specified level of severity. When the stochastic reroutes are compared to the actual flight routes, they have similar total flight time, and both have about 1% of travel time crossing congested enroute sectors on average. The actual flight routes induce slightly less traffic congestion than the stochastic reroutes but intercept more severe convective weather.

Congestion control strategy on complex network with privilege traffic

NASA Astrophysics Data System (ADS)

Li, Shi-Bao; He, Ya; Liu, Jian-Hang; Zhang, Zhi-Gang; Huang, Jun-Wei

The congestion control of traffic is one of the most important studies in complex networks. In the previous congestion algorithms, all the network traffic is assumed to have the same priority, and the privilege of traffic is ignored. In this paper, a privilege and common traffic congestion control routing strategy (PCR) based on the different priority of traffic is proposed, which can be devised to cope with the different traffic congestion situations. We introduce the concept of privilege traffic in traffic dynamics for the first time and construct a new traffic model which taking into account requirements with different priorities. Besides, a new factor Ui is introduced by the theoretical derivation to characterize the interaction between different traffic routing selection, furthermore, Ui is related to the network throughput. Since the joint optimization among different kinds of traffic is accomplished by PCR, the maximum value of Ui can be significantly reduced and the network performance can be improved observably. The simulation results indicate that the network throughput with PCR has a better performance than the other strategies. Moreover, the network capacity is improved by 25% at least. Additionally, the network throughput is also influenced by privilege traffic number and traffic priority.

Allergic rhinitis-induced nasal congestion: its impact on sleep quality.

PubMed

Storms, William

2008-03-01

Allergic rhinitis (AR) is an extremely common health problem affecting 20 to 40 million Americans and between 10-25% of the world's population. Patients with AR suffer from both nasal symptoms (congestion, rhinorrhea, itching, and sneezing) and ocular symptoms (itching, redness, and tearing). The negative impact on sleep quality and quantity, and consequently on various aspects of the patient's life, is an under-recognised and under-treated component of AR morbidity. Nasal congestion, which is one of the most bothersome and prevalent symptoms of AR, is thought to be the leading symptom responsible for rhinitis-related sleep problems. In addition to reducing clinical symptoms, pharmacologic therapies for AR that specifically reduce inflammatory cells and mediators - and therefore nasal congestion and other symptoms - should also improve sleep quality and overall quality of life (QOL). Intranasal corticosteroids (INS) are the current mainstay of therapy for AR. Results of a number of clinical trials demonstrate that INS effectively reduce nasal congestion and ocular symptoms, improve sleep quality, and decrease daytime somnolence. Intranasal corticosteroids have also proved to be effective in reducing symptoms of acute rhinosinusitis and nasal polyposis, both of which also negatively impact on sleep quality. Intranasal corticosteroids are considered safe due to their low systemic bioavailability.

Understanding congestion in China's medical market: an incentive structure perspective.

PubMed

Sun, Zesheng; Wang, Shuhong; Barnes, Stephen R

2016-04-01

Congestion has become one of the most important factors leading to patient dissatisfaction and doctor-patient conflicts in the medical market of China. In this study, we explore the causes and effects of structural congestion in the Chinese medical market from an incentive structure perspective. Our analysis reveals that prior medical system reforms with price regulation in China have induced hospitals to establish incentives for capital-intensive investments, while ignoring human capital, and have driven medical staff and patients to higher-level hospitals, reinforcing an incentive structure in which congestion in higher-level hospitals and idle resources in lower-level hospitals coexist. The existing incentive structure has led to cost increases and degradation of human capital and specific factor effects. Recent reforms to reduce congestion in the Chinese medical market were not effective. Most of them had no impact on and did not involve the existing distorted incentive structure. Future reforms should consider rebalancing expectations for medical quality, free flow of human capital and price regulation reforms to rebuild a new incentive structure. © The Author 2015. Published by Oxford University Press. All rights reserved. For permissions, please email: journals.permissions@oup.com.

Glaciomarine sedimentation and bottom current activity on the north-western and northern continental margins of Svalbard during the late Quaternary

NASA Astrophysics Data System (ADS)

Chauhan, Teena; Noormets, Riko; Rasmussen, Tine L.

2016-04-01

Palaeo-bottom current strength of the West Spitsbergen Current (WSC) and the influence of the Svalbard-Barents Sea Ice Sheet (SBIS) on the depositional environment along the northern Svalbard margins are poorly known. Two gravity cores from the southern Yermak Plateau and the upper slope north of Nordaustlandet, covering marine isotope stage (MIS) 1 to MIS 5, are investigated. Five lithofacies, based on grain size distribution, silt/clay ratio, content and mean of sortable silt (SS), are distinguished to characterise the contourite-dominated sedimentary environments. In addition, depositional environments are described using total organic carbon (TOC), total sulphur (TS) and calcium carbonate (CaCO3) contents of sediments. Facies A, containing coarse SS, suggests strong bottom current activity and good bottom water ventilation conditions as inferred from low TOC content. This facies was deposited during the glacial periods MIS 4, MIS 2 and during the late Holocene. Facies B is dominated by fine SS indicating weak bottom current and poor ventilation (cf. high TOC content of 1.2-1.6%), and correlates with the MIS 4/3 and MIS 2/1 transition periods. With an equal amount of clay and sand, fine SS and high content of TOC, facies C indicates reduced bottom current strength for intervals with sediment supply from proximal sources such as icebergs, sea ice or meltwater discharge. This facies was deposited during the last glacial maximum. Facies D represents mass-flow deposits on the northern Svalbard margin attributed to the SBIS advance at or near the shelf edge. Facies E sediments indicating moderate bottom current strength were deposited during MIS 5 and MIS 3, and during parts of MIS 2. This first late Quaternary proxy record of the WSC flow and sedimentation history from the northern Svalbard margin suggests that the oceanographic conditions and ice sheet processes have exerted first-order control on sediment properties.

Mineral and energy resources of the Roswell Resource Area, East-Central New Mexico

USGS Publications Warehouse

Bartsch-Winkler, Susan B.; Donatich, Alessandro J.

1995-01-01

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari Basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-Valley-type lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called 'Pecos diamonds' and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, carbon dioxide, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, and clay. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum-group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver-tellurium veins, and thorium-rare-earth veins. Museum-quality quartz crystals are associated with Tertiary intrusive rocks. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and occurrences of silver and uranium. Important industrial commodities include caliche, limestone and dolomite, and aggregate. Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

Impact of distracted driving on congestion.

DOT National Transportation Integrated Search

2011-03-01

Studies have documented a link between distracted driving and diminished safety; however, an association : between distracted driving and traffic congestion has not been investigated in depth. The present study : examined the behavior of teens and yo...

Innovative contracting methods and construction traffic congestion.

DOT National Transportation Integrated Search

2012-01-01

Increasing travel demand and lack of sufficient highway capacity are serious problems in most : major metropolitan areas in the United States. Large metropolitan cities have been experiencing : increased traffic congestion problems over the past seve...

Atlanta congestion reduction demonstration national evaluation plan.

DOT National Transportation Integrated Search

2011-04-01

This report provides an analytic framework for evaluating the Atlanta Congestion Reduction Demonstration (CRD) under the United States Department of Transportation (U.S. DOT) Urban Partnership Agreement (UPA) and CRD Programs. The Atlanta CRD project...

A Michigan toolbox for mitigating traffic congestion.

DOT National Transportation Integrated Search

2011-09-30

"Researchers created A Michigan Toolbox for Mitigating Traffic Congestion to be a useful desk reference : for practitioners and an educational tool for elected officials acting through public policy boards to better : understand the development, plan...

Snoring and Nasal Congestion

MedlinePlus

... treat the various causes of nasal congestion include: Topical nasal steroid spray Topical nasal antihistamine spray Oral antibiotic (in case of ... include more than just the decrease in oxygen levels at night during the apnea episodes. They also ...

Improving intermodal connectivity in rural areas to enhance transportation efficiency : a case study.

DOT National Transportation Integrated Search

2011-05-01

Congested roadways in Texas metropolitan centers are important arteries for transporting : agricultural commodities into domestic and international markets. Truck transportation of these : commodities contributes to the observed congestion and del...

Congestion-based emergency vehicle preemption.

DOT National Transportation Integrated Search

2010-08-01

This research analyzed and evaluated a new strategy for preemption of emergency vehicles along a corridor, which is : route-based and adaptive to real-time traffic conditions. The method uses dynamic offsets which are adjusted using : congestion-leve...

Lessons learned from international experience in congestion pricing.

DOT National Transportation Integrated Search

2008-08-01

Large road pricing projects have been implemented in U.K., France, Norway, Sweden, : Germany, Switzerland, Singapore and Australia over the past three decades. Additionally, : congestion pricing has been analyzed and evaluated through numerous studie...