NASA Technical Reports Server (NTRS)
Donoughe, Patrick L; Livingood, John N B
1955-01-01
Exact solution of the laminar-boundary-layer equations for wedge-type flow with constant property values are presented for transpiration-cooled surfaces with variable wall temperatures. The difference between wall and stream temperature is assumed proportional to a power of the distance from the leading edge. Solutions are given for a Prandtl number of 0.7 and ranges of pressure-gradient, cooling-air-flow, and wall-temperature-gradient parameters. Boundary-layer profiles, dimensionless boundary-layer thicknesses, and convective heat-transfer coefficients are given in both tabular and graphical form. Corresponding results for constant wall temperature and for impermeable surfaces are included for comparison purposes.
Grain boundary oxidation and fatigue crack growth at elevated temperatures
NASA Technical Reports Server (NTRS)
Liu, H. W.; Oshida, Y.
1986-01-01
Fatigue crack growth rate at elevated temperatures can be accelerated by grain boundary oxidation. Grain boundary oxidation kinetics and the statistical distribution of grain boundary oxide penetration depth were studied. At a constant delta K-level and at a constant test temperature, fatigue crack growth rate, da/dN, is a function of cyclic frequency, nu. A fatigue crack growth model of intermittent micro-ruptures of grain boundary oxide is constructed. The model is consistent with the experimental observations that, in the low frequency region, da/dN is inversely proportional to nu, and fatigue crack growth is intergranular.
Natural convection of a two-dimensional Boussinesq fluid does not maximize entropy production.
Bartlett, Stuart; Bullock, Seth
2014-08-01
Rayleigh-Bénard convection is a canonical example of spontaneous pattern formation in a nonequilibrium system. It has been the subject of considerable theoretical and experimental study, primarily for systems with constant (temperature or heat flux) boundary conditions. In this investigation, we have explored the behavior of a convecting fluid system with negative feedback boundary conditions. At the upper and lower system boundaries, the inward heat flux is defined such that it is a decreasing function of the boundary temperature. Thus the system's heat transport is not constrained in the same manner that it is in the constant temperature or constant flux cases. It has been suggested that the entropy production rate (which has a characteristic peak at intermediate heat flux values) might apply as a selection rule for such a system. In this work, we demonstrate with Lattice Boltzmann simulations that entropy production maximization does not dictate the steady state of this system, despite its success in other, somewhat similar scenarios. Instead, we will show that the same scaling law of dimensionless variables found for constant boundary conditions also applies to this system.
Influence of free surface curvature on the Pearson instability in Marangoni convection
NASA Astrophysics Data System (ADS)
Hu, W. R.
The Peason instability in a liquid layer bounded by a plate solid boundary with higher constant temperature and a plane free surface with lower constant temperatures in the microgravity environment has by extensively studied The free surface in the microgravity environment tends to be curved in general as a spherical shape and the plane configuration of free surface is a special case In the present paper a system of liquid layer bounded by a plat solid boundary with higher constant temperature and a curved free surface with lower non-uniform temperature is studied The temperature gradient on the free surface will induce the thermocapillary convection and the onset of Marangoni convection is coupled with the thermocapillary convection The thermocapillary convection induced by the temperature gradient on the curved free surface and its influence on the Marangoni convection are studied in the present paper
On the Time Scale of Nocturnal Boundary Layer Cooling in Valleys and Basins and over Plains
NASA Astrophysics Data System (ADS)
de Wekker, Stephan F. J.; Whiteman, C. David
2006-06-01
Sequences of vertical temperature soundings over flat plains and in a variety of valleys and basins of different sizes and shapes were used to determine cooling-time-scale characteristics in the nocturnal stable boundary layer under clear, undisturbed weather conditions. An exponential function predicts the cumulative boundary layer cooling well. The fitting parameter or time constant in the exponential function characterizes the cooling of the valley atmosphere and is equal to the time required for the cumulative cooling to attain 63.2% of its total nighttime value. The exponential fit finds time constants varying between 3 and 8 h. Calculated time constants are smallest in basins, are largest over plains, and are intermediate in valleys. Time constants were also calculated from air temperature measurements made at various heights on the sidewalls of a small basin. The variation with height of the time constant exhibited a characteristic parabolic shape in which the smallest time constants occurred near the basin floor and on the upper sidewalls of the basin where cooling was governed by cold-air drainage and radiative heat loss, respectively.
Effect of Bi doping on morphotropic phase boundary and dielectric properties of PZT
DOE Office of Scientific and Technical Information (OSTI.GOV)
Joshi, Shraddha; Acharya, Smita, E-mail: saha275@yahoo.com
2016-05-23
In our present attempt, Pb{sub (1-x)}Bi{sub x}Zr{sub 0.52}Ti{sub 0.48}O{sub 3} [PBZT] {where x = 0, 0.05, 0.1} is synthesized by sol-gel route. Effect of Bi addition on structure, sinterability and dielectric properties are observed. The presence of morphotropic phase boundary (coexistence of tetragonal and rhombohedral symmetry) is confirmed by X-ray diffraction. Enhancement of sinterability after Bi doping is observed through a systematic sintering program. Frequency and temperature dependent dielectric constant are studied. Bi doping in PZT is found to enhance room temperature dielectric constant. However, at high temperature the dielectric constant of pure PZT is more than that of dopedmore » PZT.« less
Colossal dielectric constant in PrFeO 3 semiconductor ceramics
NASA Astrophysics Data System (ADS)
Prasad, Bandi Vittal; Rao, G. Narsinga; Chen, J. W.; Babu, D. Suresh
2012-02-01
The perovskite PrFeO 3 ceramics were synthesized via sol-gel method. The dielectric properties and impedance spectroscopy (IS) of these ceramics were studied in the frequency range from 100 Hz to 1000 kHz in the temperature range from 80 K to 300 K. These materials exhibited colossal dielectric constant value of ˜10 4 at room temperature. The response is similar to that observed for relaxorferroelectrics. IS data analysis indicates the ceramics to be electrically heterogeneous semiconductor consisting of semiconducting grains with dielectric constant 30 and more resistive grain boundaries with effective dielectric constant ˜10 4. We conclude, therefore that grain boundary effect is the primary source for the high effective permittivity in PrFeO 3 ceramics.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mallow, Anne M; Abdelaziz, Omar; Graham, Samuel
The thermal charging performance of phase change materials, specifically paraffin wax, combined with compressed expanded natural graphite foam is studied under constant heat flux and constant temperature conditions. By varying the heat flux between 0.39 W/cm2 and 1.55 W/cm2 or maintaining a boundary temperature of 60 C for four graphite foam bulk densities, the impact on the rate of thermal energy storage is discussed. Thermal charging experiments indicate that thermal conductivity of the composite is an insufficient metric to compare the influence of graphite foam on the rate of thermal energy storage of the PCM composite. By dividing the latentmore » heat of the composite by the time to melt for various boundary conditions and graphite foam bulk densities, it is determined that bulk density selection is dependent on the applied boundary condition. A greater bulk density is advantageous for samples exposed to a constant temperature near the melting temperature as compared to constant heat flux conditions where a lower bulk density is adequate. Furthermore, the anisotropic nature of graphite foam bulk densities greater than 50 kg/m3 is shown to have an insignificant impact on the rate of thermal charging. These experimental results are used to validate a computational model for future use in the design of thermal batteries for waste heat recovery.« less
Model for temperature-dependent magnetization of nanocrystalline materials
NASA Astrophysics Data System (ADS)
Bian, Q.; Niewczas, M.
2015-01-01
A magnetization model of nanocrystalline materials incorporating intragrain anisotropies, intergrain interactions, and texture effects has been extended to include the thermal fluctuations. The method relies on the stochastic Landau-Lifshitz-Gilbert theory of magnetization dynamics and permits to study the magnetic properties of nanocrystalline materials at arbitrary temperature below the Currie temperature. The model has been used to determine the intergrain exchange constant and grain boundary anisotropy constant of nanocrystalline Ni at 100 K and 298 K. It is found that the thermal fluctuations suppress the strength of the intergrain exchange coupling and also reduce the grain boundary anisotropy. In comparison with its value at 2 K, the interparticle exchange constant decreases by 16% and 42% and the grain boundary anisotropy constant decreases by 28% and 40% at 100 K and 298 K, respectively. An application of the model to study the grain size-dependent magnetization indicates that when the thermal activation energy is comparable to the free energy of grains, the decrease in the grain size leads to the decrease in the magnetic permeability and saturation magnetization. The mechanism by which the grain size influences the magnetic properties of nc-Ni is discussed.
Creep Behavior of Near-Stoichiometric Polycrystalline Binary NiAl
NASA Technical Reports Server (NTRS)
Raj, S. V.
2002-01-01
New and published constant load creep and constant engineering strain rate data on near-stoichiometric binary NiAl in the intermediate temperature range 700 to 1300 K are reviewed. Both normal and inverse primary creep curves are observed depending on stress and temperature. Other characteristics relating to creep of NiAl involving grain size, stress and temperature dependence are critically examined and discussed. At stresses below 25 MPa and temperatures above 1000 K, a new grain boundary sliding mechanism was observed with n approx. 2, Qc approx. 100 kJ/ mol and a grain size exponent of about 2. It is demonstrated that Coble creep and accommodated grain boundary sliding models fail to predict the experimental creep rates by several orders of magnitude.
Maxwell-Wagner effect in hexagonal BaTiO3 single crystals grown by containerless processing
NASA Astrophysics Data System (ADS)
Yu, Jianding; Paradis, Paul-François; Ishikawa, Takehiko; Yoda, Shinichi
2004-10-01
Oxygen-deficient hexagonal BaTiO3 single crystals, with dielectric constant ε '˜105 and loss component tan δ ˜0.13 at room temperature and a linear temperature dependence of ε' in the range 70-100K, was analyzed by impedance spectroscopy analysis. Two capacitors, bulk and interfacial boundary layer, were observed, and the colossal dielectric constant was mainly dominated by the interfacial boundary layers due to Maxwell-Wagner effect. After annealing the oxygen-deficient hexagonal BaTiO3 at 663K, the ε ' and tanδ became, respectively, 2×104 and 0.07 at room temperature. This work showed an important technological implication as annealing at lower temperatures would help to obtain materials with tailored dielectric properties.
NASA Technical Reports Server (NTRS)
Spina, Eric F.
1995-01-01
The primary objective in the two research investigations performed under NASA Langley sponsorship (Turbulence measurements in hypersonic boundary layers using constant temperature anemometry and Reynolds stress measurements in hypersonic boundary layers) has been to increase the understanding of the physics of hypersonic turbulent boundary layers. The study began with an extension of constant-temperature thermal anemometry techniques to a Mach 11 helium flow, including careful examinations of hot-wire construction techniques, system response, and system calibration. This was followed by the application of these techniques to the exploration of a Mach 11 helium turbulent boundary layer (To approximately 290 K). The data that was acquired over the course of more than two years consists of instantaneous streamwise mass flux measurements at a frequency response of about 500 kHz. The data are of exceptional quality in both the time and frequency domain and possess a high degree of repeatability. The data analysis that has been performed to date has added significantly to the body of knowledge on hypersonic turbulence, and the data reduction is continuing. An attempt was then made to extend these thermal anemometry techniques to higher enthalpy flows, starting with a Mach 6 air flow with a stagnation temperature just above that needed to prevent liquefaction (To approximately 475 F). Conventional hot-wire anemometry proved to be inadequate for the selected high-temperature, high dynamic pressure flow, with frequent wire breakage and poor system frequency response. The use of hot-film anemometry has since been investigated for these higher-enthalpy, severe environment flows. The difficulty with using hot-film probes for dynamic (turbulence) measurements is associated with construction limitations and conduction of heat into the film substrate. Work continues under a NASA GSRP grant on the development of a hot film probe that overcomes these shortcomings for hypersonic flows. Each of the research tasks performed during the NASA Langley research grants is discussed separately below.
An equivalent dipole analysis of PZT ceramics and lead-free piezoelectric single crystals
NASA Astrophysics Data System (ADS)
Bell, Andrew J.
2016-04-01
The recently proposed Equivalent Dipole Model for describing the electromechanical properties of ionic solids in terms of 3 ions and 2 bonds has been applied to PZT ceramics and lead-free single crystal piezoelectric materials, providing analysis in terms of an effective ionic charge and the asymmetry of the interatomic force constants. For PZT it is shown that, as a function of composition across the morphotropic phase boundary, the dominant bond compliance peaks at 52% ZrO2. The stiffer of the two bonds shows little composition dependence with no anomaly at the phase boundary. The effective charge has a maximum value at 50% ZrO2, decreasing across the phase boundary region, but becoming constant in the rhombohedral phase. The single crystals confirm that both the asymmetry in the force constants and the magnitude of effective charge are equally important in determining the values of the piezoelectric charge coefficient and the electromechanical coupling coefficient. Both are apparently temperature dependent, increasing markedly on approaching the Curie temperature.
Microstructures and dielectric properties of CaCu3Ti4O12 ceramics via combustion method
NASA Astrophysics Data System (ADS)
Yuan, W. X.; Li, Z. J.
2012-01-01
CaCu3Ti4O12 (CCTO) powder was synthesized by the combustion method. The effect of sintering temperature was studied on dielectric properties of the prepared ceramic samples. They have the dielectric constant of ~31 000 and 80 000 for the grain size of 0.3 and 30-100 μm. It is unusual for CCTO with a grain size of 0.3 μm to have a dielectric constant of ~31 000. Their giant dielectric constant could be explained by a two-step internal-barrier-layer-capacitor model, associated with grain boundaries and domain boundaries. The existence of domain boundaries helped to explain the contradiction of the dielectric mechanisms between polycrystalline and single-crystal CCTO.
Scale/Analytical Analyses of Freezing and Convective Melting with Internal Heat Generation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ali S. Siahpush; John Crepeau; Piyush Sabharwall
2013-07-01
Using a scale/analytical analysis approach, we model phase change (melting) for pure materials which generate constant internal heat generation for small Stefan numbers (approximately one). The analysis considers conduction in the solid phase and natural convection, driven by internal heat generation, in the liquid regime. The model is applied for a constant surface temperature boundary condition where the melting temperature is greater than the surface temperature in a cylindrical geometry. The analysis also consider constant heat flux (in a cylindrical geometry).We show the time scales in which conduction and convection heat transfer dominate.
Transport characteristics and colossal dielectric response of cadmium sulfide nanoparticles
NASA Astrophysics Data System (ADS)
Ahmad, Mushtaq; Rafiq, M. A.; Hasan, M. M.
2013-10-01
We report here the synthesis of ˜20 nm sized cadmium sulfide (CdS) nanoparticles via conventional solid state reaction at low temperature ˜200 °C and ambient pressure. X-ray diffraction and high resolution transmission electron microscopy analysis confirmed the synthesis of hexagonal phased nanoparticles. Impedance and electrical modulus investigations were carried out in the frequency range 20 Hz to 2 MHz and at temperature from 300 K to 400 K, which show the presence of bulk, grain boundary, and sub-grain boundary phases in CdS nanoparticles. Overlapped large polaron tunneling was the observed mechanism of charge carriers in used temperature range. The presence of colossal dielectric constant in the system is attributed to the Maxwell-Wagner type polarization. High and temperature dependent dielectric constants make the CdS nanoparticles efficient material to be used in capacitive energy storage devices.
NASA Technical Reports Server (NTRS)
Kandula, M.; Haddad, G. F.; Chen, R.-H.
2006-01-01
Three-dimensional Navier-Stokes computational fluid dynamics (CFD) analysis has been performed in an effort to determine thermal boundary layer correction factors for circular convective heat flux gauges (such as Schmidt-Boelter and plug type)mounted flush in a flat plate subjected to a stepwise surface temperature discontinuity. Turbulent flow solutions with temperature-dependent properties are obtained for a free stream Reynolds number of 1E6, and freestream Mach numbers of 2 and 4. The effect of gauge diameter and the plate surface temperature have been investigated. The 3-D CFD results for the heat flux correction factors are compared to quasi-21) results deduced from constant property integral solutions and also 2-D CFD analysis with both constant and variable properties. The role of three-dimensionality and of property variations on the heat flux correction factors has been demonstrated.
Ritchie, R.H.; Sakakura, A.Y.
1956-01-01
The formal solutions of problems involving transient heat conduction in infinite internally bounded cylindrical solids may be obtained by the Laplace transform method. Asymptotic series representing the solutions for large values of time are given in terms of functions related to the derivatives of the reciprocal gamma function. The results are applied to the case of the internally bounded infinite cylindrical medium with, (a) the boundary held at constant temperature; (b) with constant heat flow over the boundary; and (c) with the "radiation" boundary condition. A problem in the flow of gas through a porous medium is considered in detail.
NASA Astrophysics Data System (ADS)
Kassem, M.
2006-03-01
The problem of heat and mass transfer in an unsteady free-convection flow over a continuous moving vertical sheet in an ambient fluid is investigated for constant heat flux using the group theoretical method. The nonlinear coupled partial differential equation governing the flow and the boundary conditions are transformed to a system of ordinary differential equations with appropriate boundary conditions. The obtained ordinary differential equations are solved numerically using the shooting method. The effect of Prandlt number on the velocity and temperature of the boundary-layer is plotted in curves. A comparison with previous work is presented.
Boudys, M
1991-01-01
Variations of temperature coefficients of permittivity epsilon(33)(T), elastic compliances at constant electric fields s(11)(E), and constant polarization s(11)(P) with a Zr/Ti ratio of Pb(Zr(x)Ti(1-x))O(3) and Pb[(Sb(1/3)Mn(2/3))(0.05)Zr(x)Ti (0.95-x)]O(3) solid solutions, were investigated. Relations between temperature coefficients of epsilon(33)(T ), S(11)(E), and S(11) (P) were theoretically derived; a discrepancy was found between theoretical relations and experimental results. On the basis of the observed discrepancy, it is proposed that some extrinsic effects arising from the motion of interphase boundaries between the tetragonal and the rhombohedral phases which exist in grains contribute to values of both elastic compliances.
NASA Technical Reports Server (NTRS)
Siegel, R.; Goldstein, M. E.
1972-01-01
An analytical solution is obtained for flow and heat transfer in a three-dimensional porous medium. Coolant from a reservoir at constant pressure and temperature enters one portion of the boundary of the medium and exits through another portion of the boundary which is at a specified uniform temperature and uniform pressure. The variation with temperature of coolant density and viscosity are both taken into account. A general solution is found that provides the temperature distribution in the medium and the mass and heat fluxes along the portion of the surface through which the coolant is exiting.
Natural convection heat transfer in water near its density maximum
NASA Astrophysics Data System (ADS)
Yen, Yin-Chao
1990-12-01
This monograph reviews and summarizes to date the experimental and analytical results on the effect of water density near its maximum convection, transient flow and temperature structure characteristics: (1) in a vertical enclosure; (2) in a vertical annulus; (3) between horizontal concentric cylinders; (4) in a square enclosure; (5) in a rectangular enclosure; (6) in a horizontal layer; (7) in a circular confined melt layer; and (8) in bulk water during melting. In a layer of water containing a maximum density temperature of 4 C, the onset of convection (the critical number) is found not to be a constant value as in the classical normal fluid but one that varies with the imposed thermal and hydrodynamic boundaries. In horizontal layers, a nearly constant temperature zone forms and continuously expands between the warm and cold boundaries. A minimum heat transfer exists in most of the geometries studied and, in most cases, can be expressed in terms of a density distribution parameter. The effect of this parameter on a cells formation, disappearance and transient structure is discussed, and the effect of split boundary flow on heat transfer is presented.
On the penetration of a hot diapir through a strongly temperature-dependent viscosity medium
NASA Technical Reports Server (NTRS)
Daly, S. F.; Raefsky, A.
1985-01-01
The ascent of a hot spherical body through a fluid with a strongly temperature-dependent viscosity has been studied using an axisymmetric finite element method. Numerical solutions range over Peclet numbers of 0.1 - 1000 from constant viscosity up to viscosity variations of 100,000. Both rigid and stress-free boundary conditions were applied at the surface of the sphere. The dependence of drag on viscosity variation was shown to have no dependence on the stress boundary condition except for a Stokes flow scaling factor. A Nusselt number parameterization based on the stress-free constant viscosity functional dependence on the Peclet number scaled by a parameter depending on the viscosity structure fits both stress-free and rigid boundary condition data above viscosity variations of 100. The temperature scale height was determined as a function of sphere radius. For the simple physical model studied in this paper pre-heating is required to reduce the ambient viscosity of the country rock to less than 10 to the 22nd sq cm/s in order for a 10 km diapir to penetrate a distance of several radii.
Thermoelectric Generation Using Counter-Flows of Ideal Fluids
NASA Astrophysics Data System (ADS)
Meng, Xiangning; Lu, Baiyi; Zhu, Miaoyong; Suzuki, Ryosuke O.
2017-08-01
Thermoelectric (TE) performance of a three-dimensional (3-D) TE module is examined by exposing it between a pair of counter-flows of ideal fluids. The ideal fluids are thermal sources of TE module flow in the opposite direction at the same flow rate and generate temperature differences on the hot and cold surfaces due to their different temperatures at the channel inlet. TE performance caused by different inlet temperatures of thermal fluids are numerically analyzed by using the finite-volume method on 3-D meshed physical models and then compared with those using a constant boundary temperature. The results show that voltage and current of the TE module increase gradually from a beginning moment to a steady flow and reach a stable value. The stable values increase with inlet temperature of the hot fluid when the inlet temperature of cold fluid is fixed. However, the time to get to the stable values is almost consistent for all the temperature differences. Moreover, the trend of TE performance using a fluid flow boundary is similar to that of using a constant boundary temperature. Furthermore, 3-D contours of fluid pressure, temperature, enthalpy, electromotive force, current density and heat flux are exhibited in order to clarify the influence of counter-flows of ideal fluids on TE generation. The current density and heat flux homogeneously distribute on an entire TE module, thus indicating that the counter-flows of thermal fluids have high potential to bring about fine performance for TE modules.
A near-wall four-equation turbulence model for compressible boundary layers
NASA Technical Reports Server (NTRS)
Sommer, T. P.; So, R. M. C.; Zhang, H. S.
1992-01-01
A near-wall four-equation turbulence model is developed for the calculation of high-speed compressible turbulent boundary layers. The four equations used are the k-epsilon equations and the theta(exp 2)-epsilon(sub theta) equations. These equations are used to define the turbulent diffusivities for momentum and heat fluxes, thus allowing the assumption of dynamic similarity between momentum and heat transport to be relaxed. The Favre-averaged equations of motion are solved in conjunction with the four transport equations. Calculations are compared with measurements and with another model's predictions where the assumption of the constant turbulent Prandtl number is invoked. Compressible flat plate turbulent boundary layers with both adiabatic and constant temperature wall boundary conditions are considered. Results for the range of low Mach numbers and temperature ratios investigated are essentially the same as those obtained using an identical near-wall k-epsilon model. In general, the numerical predictions are in very good agreement with measurements and there are significant improvements in the predictions of mean flow properties at high Mach numbers.
Dielectric relaxation and magnetic properties of Ti and Zn co-doped GaFeO3
NASA Astrophysics Data System (ADS)
Raies, Imen; Dulmani, Shara A.; Amami, Mongi
2018-06-01
polycrystalline GaFeO3 and Ga0.98Zn0.02Fe0.98Ti0.02O3 were prepared by solid state reaction. They showed an orthorhombic crystal structure with Pc21n space group. The magnetic transition temperature decrease due to the dilution of the magnetic interaction. A noteworthy effect of substitution of multiple elements at the Ga and Fe-sites on dielectric constant and tangent loss of GaFeO3 has been observed. Complete studies of temperature (180-400 K) and frequency (10-107 Hz) dependence of dielectric constant and impedance have provided the effect of grains and grain boundaries on the conduction mechanism and dielectric relaxation of the material. Impedance spectroscopy results in the temperature range 160-400 K have revealed a distinct conduction process at grain and grain boundaries.
NASA Technical Reports Server (NTRS)
Eckert, E.R.G.; Livingood, John N.B.
1951-01-01
An approximate method for development of flow and thermal boundary layers in laminar regime on cylinders with arbitrary cross section and transpiration-cooled walls is obtained by use of Karman's integrated momentum equation and an analogous heat-flow equation. Incompressible flow with constant property values throughout boundary layer is assumed. Shape parameters for approximated velocity and temperature profiles and functions necessary for solution of boundary-layer equations are presented as charts, reducing calculations to a minimum. The method is applied to determine local heat-transfer coefficients and surface temperature-cooled turbine blades for a given flow rate. Coolant flow distributions necessary for maintaining uniform blade temperatures are also determined.
A PV view of the zonal mean distribution of temperature and wind in the extratropical troposphere
NASA Technical Reports Server (NTRS)
Sun, De-Zheng; Lindzen, Richard S.
1994-01-01
The dependence of the temperature and wind distribution of the zonal mean flow in the extratropical troposphere on the gradient of pontential vorticity along isentropes is examined. The extratropics here refer to the region outside the Hadley circulation. Of particular interest is whether the distribution of temperature and wind corresponding to a constant potential vorticity (PV) along isentropes resembles the observed, and the implications of PV homogenization along isentropes for the role of the tropics. With the assumption that PV is homogenized along isentropes, it is found that the temperature distribution in the extratropical troposphere may be determined by a linear, first-order partial differential equation. When the observed surface temperature distribution and tropical lapse rate are used as the boundary conditions, the solution of the equation is close to the observed temperature distribution except in the upper troposphere adjacent to the Hadley circulation, where the troposphere with no PV gradient is considerably colder. Consequently, the jet is also stronger. It is also found that the meridional distribution of the balanced zonal wind is very sensitive to the meridional distribution of the tropopause temperature. The result may suggest that the requirement of the global momentum balance has no practical role in determining the extratropical temperature distribution. The authors further investigated the sensitivity of the extratropical troposphere with constant PV along isentropes to changes in conditions at the tropical boundary (the edge of the Hadley circulation). It is found that the temperature and wind distributions in the extratropical troposphere are sensitive to the vertical distribution of PV at the tropical boundary. With a surface distribution of temperature that decreases linearly with latitude, the jet maximum occurs at the tropical boundary and moves with it. The overall pattern of wind distribution is not sensitive to the change of the position of the tropical boundary. Finally, the temperature and wind distributions of an extratropical troposphere with a finite PV gradient are calculated. It is found that the larger the isentropic PV gradient, the warmer the troposphere and the weaker the jet.
NASA Technical Reports Server (NTRS)
Orlando, A. F.; Moffat, R. J.; Kays, W. M.
1974-01-01
The relationship between the turbulent transport of heat and momentum in an adverse pressure gradient boundary layer was studied. An experimental study was conducted of turbulent boundary layers subject to strong adverse pressure gradients with suction. Near-equilibrium flows were attained, evidenced by outer-region similarity in terms of defect temperature and defect velocity profiles. The relationship between Stanton number and enthalpy thickness was shown to be the same as for a flat plate flow both for constant wall temperature boundary conditions and for steps in wall temperature. The superposition principle used with the step-wall-temperature experimental result was shown to accurately predict the Stanton number variation for two cases of arbitrarily varying wall temperature. The Reynolds stress tensor components were measured for strong adverse pressure gradient conditions and different suction rates. Two peaks of turbulence intensity were found: one in the inner and one in the outer regions. The outer peak is shown to be displaced outward by an adverse pressure gradient and suppressed by suction.
Dielectric and impedance study of praseodymium substituted Mg-based spinel ferrites
NASA Astrophysics Data System (ADS)
Farid, Hafiz Muhammad Tahir; Ahmad, Ishtiaq; Ali, Irshad; Ramay, Shahid M.; Mahmood, Asif; Murtaza, G.
2017-07-01
Spinel ferrites with nominal composition MgPryFe2-yO4 (y = 0.00, 0.025, 0.05, 0.075, 0.10) were prepared by sol-gel method. Temperature dependent DC electrical conductivity and drift mobility were found in good agreement with each other, reflecting semiconducting behavior. The dielectric properties of all the samples as a function of frequency (1 MHz-3 GHz) were measured at room temperature. The dielectric constant and complex dielectric constant of these samples decreased with the increase of praseodymium concentration. In the present spinel ferrite, Cole-Cole plots were used to separate the grain and grain boundary's effects. The substitution of praseodymium ions in Mg-based spinel ferrites leads to a remarkable rise of grain boundary's resistance as compared to the grain's resistance. As both AC conductivity and Cole-Cole plots are the functions of concentration, they reveal the dominant contribution of grain boundaries in the conduction mechanism. AC activation energy was lower than dc activation energy. Temperature dependence normalized AC susceptibility of spinel ferrites reveals that MgFe2O4 exhibits multi domain (MD) structure with high Curie temperature while on substitution of praseodymium, MD to SD transitions occurs. The low values of conductivity and low dielectric loss make these materials best candidate for high frequency application.
NASA Astrophysics Data System (ADS)
Manideep, P.; Raju, R. Srinivasa; Rao, T. Siva Nageswar; Reddy, G. Jithender
2018-05-01
This paper deals, an unsteady magnetohydrodynamic heat transfer natural convection flow of non-Newtonian Casson fluid over an inclined vertical plate embedded in a porous media with the presence of boundary conditions such as oscillating velocity, constant wall temperature. The governing dimensionless boundary layer partial differential equations are reduced to simultaneous algebraic linear equation for velocity, temperature of Casson fluid through finite element method. Those equations are solved by Thomas algorithm after imposing the boundary conditions through MATLAB for analyzing the behavior of Casson fluid velocity and temperature with various physical parameters. Also analyzed the local skin-friction and rate of heat transfer. Compared the present results with earlier reported studies, the results are comprehensively authenticated and robust FEM.
Development of buried wire gages for measurement of wall shear stress in Blastane experiments
NASA Technical Reports Server (NTRS)
Murthy, S. V.; Steinle, F. W.
1986-01-01
Buried Wire Gages operated from a Constant Temperature Anemometer System are among the special types of instrumentation to be used in the Boundary Layer Apparatus for Subsonic and Transonic flow Affected by Noise Environment (BLASTANE). These Gages are of a new type and need to be adapted for specific applications. Methods were developed to fabricate Gage inserts and mount those in the BLASTANE Instrumentation Plugs. A large number of Gages were prepared and operated from a Constant Temperature Anemometer System to derive some of the calibration constants for application to fluid-flow wall shear-stress measurements. The final stage of the calibration was defined, but could not be accomplished because of non-availability of a suitable flow simulating apparatus. This report provides a description of the Buried Wire Gage technique, an explanation of the method evolved for making proper Gages and the calibration constants, namely Temperature Coefficient of Resistance and Conduction Loss Factor.
NASA Technical Reports Server (NTRS)
Parsons, B.; Daly, S.
1983-01-01
Consideration is given to the relationship between the temperature structure of mantle convection and the resulting surface topography and gravity anomalies, which are used in its investigation. Integral expressions relating the three variables as a function of wavelength are obtained with the use of Green's function solutions to the equations of motion for the case of constant-viscosity convection in a plane layer subject to a uniform gravitational field. The influence of the boundary conditions, particularly at large wavelengths, is pointed out, and surface topographies and gravity produced by convection are illustrated for a number of simple temperature distributions. It is shown that the upper thermal boundary layer plays an important role in determining the surface observables, while temperatures near the bottom of the layer affect mainly that boundary. This result is consistent with an explanation of geoid anomalies over mid-ocean swells in terms of convection beneath the lithosphere.
NASA Technical Reports Server (NTRS)
Parker, Hermon M
1953-01-01
An analysis is made of the transient heat-conduction effects in three simple semi-infinite bodies: the flat insulated plate, the conical shell, and the slender solid cone. The bodies are assumed to have constant initial temperatures and, at zero time, to begin to move at a constant speed and zero angle of attack through a homogeneous atmosphere. The heat input is taken as that through a laminar boundary layer. Radiation heat transfer and transverse temperature gradients are assumed to be zero. The appropriate heat-conduction equations are solved by an iteration method, the zeroeth-order terms describing the situation in the limit of small time. The method is presented and the solutions are calculated to three orders which are sufficient to give reasonably accurate results when the forward edge has attained one-half the total temperature rise (nose half-rise time). Flight Mach number and air properties occur as parameters in the result. Approximate expressions for the extent of the conduction region and nose half-rise times as functions of the parameters of the problem are presented. (author)
Influence of Alloying upon Grain-Boundary Creep
NASA Technical Reports Server (NTRS)
Rhines, F N; Bond, W E; Kissel, M A
1957-01-01
Grain-boundary displacement, occurring in bicrystals during creep at elevated temperature (350 degrees c), has been measured as a function of the copper content (0.1 to 3 percent) in a series of aluminum-rich aluminum-copper solid-solution alloys. The minimums in stress and temperature, below which grain-boundary motion does not occur, increase regularly with the copper content as would be expected if recovery is necessary for movement. Otherwise, the effects, if any, of the copper solute upon grain-boundary displacement and its rate are too small for identification by the experimental technique employed. It was shown, additionally, that grain-boundary displacement appears regular and proceeds at a constant rate if observed parallel to the stress axis, whereas the motion is seen to occur in a sequence of surges and the rate to diminish with time if the observations are made perpendicular to the stress axis.
Numerical modeling of coronal mass ejections based on various pre-event model atmospheres
NASA Technical Reports Server (NTRS)
Suess, S. T.; Wang, A. H.; Wu, S. T.; Poletto, G.
1994-01-01
We examine how the initial state (pre-event corona) affects the numerical MHD simulation for a coronal mass ejection (CME). Earlier simulations based on a pre-event corona with a homogeneous density and temperature distribution at lower boundary (i.e. solar surface) have been used to analyze the role of streamer properties in determining the characteristics of loop-like transients. The present paper extends these studies to show how a broader class of global coronal properties leads not only to different types of CME's, but also modifies the adjacent quiet corona and/or coronal holes. We consider four pre-event coronal cases: (1) Constant boundary conditions and a polytropic gas with gamma = 1.05; (2) Non-constant (latitude dependent) boundary conditions and a polytropic gas with gamma = 1.05; (3) Constant boundary conditions with a volumetric energy source and gamma = 1.67; (4) Non-constant (latitude dependent) boundary conditions with a volumetric energy source and gamma = 1.67. In all models, the pre-event magnetic fields separate the corona into closed field regions (streamers) and open field regions. The CME's initiation is simulated by introducing at the base of the corona, within the streamer region, a standard pressure pulse and velocity change. Boundary values are determined using MHD characteristic theory. The simulations show how different CME's, including loop-like transients, clouds, and bright rays, might occur. There are significant new features in comparison to published results. We conclude that the pre-event corona is a crucial factor in dictating CME's properties.
Numerical Modeling of Coronal Mass Ejections Based on Various Pre-event Model Atmospheres
NASA Technical Reports Server (NTRS)
Wang, A. H.; Wu, S. T.; Suess, S. T.; Poletto, G.
1995-01-01
We examine how the initial state (pre-event corona) affects the numerical MHD simulation for a coronal mass ejection (CME). Earlier simulations based on a pre-event corona with a homogeneous density and temperature distribution, at the lower boundary (i.e., solar surface) have been used to analyze the role of streamer properties in determining the characteristics of loop-like transients. The present paper extends these studies to show how a broader class of global coronal properties leads not only to different types of CME's, but also modifies the adjacent quiet corona and/or coronal holes. We consider four pre-event coronal cases: (1) constant boundary conditions and a polytropic gas with gamma = 1.05; (2) non-constant (latitude dependent) boundary conditions and a polytropic gas with gamma = 1.05; (3) constant boundary conditions with a volumetric energy source and gamma = 1.67; (4) non-constant (latitude dependent) boundary conditions with a volumetric energy source and gamma = 1.67. In all models, the pre-event magnetic fields separate the corona into closed field regions (streamers) and open field regions. The CME's initiation is simulated by introducing at the base of the corona, within the streamer region, a standard pressure pulse and velocity change. Boundary values are determined using magnetohydrodynamic (MHD) characteristic theory. The simulations show how different CME's, including loop-like transients, clouds and bright rays, might occur. There are significant new features in comparison to published results. We conclude that the pre-event corona is a crucial factor in dictating CME's properties.
Transitional and turbulent boundary layer with heat transfer
NASA Astrophysics Data System (ADS)
Wu, Xiaohua; Moin, Parviz
2010-08-01
We report on our direct numerical simulation of an incompressible, nominally zero-pressure-gradient flat-plate boundary layer from momentum thickness Reynolds number 80-1950. Heat transfer between the constant-temperature solid surface and the free-stream is also simulated with molecular Prandtl number Pr=1. Skin-friction coefficient and other boundary layer parameters follow the Blasius solutions prior to the onset of turbulent spots. Throughout the entire flat-plate, the ratio of Stanton number and skin-friction St/Cf deviates from the exact Reynolds analogy value of 0.5 by less than 1.5%. Mean velocity and Reynolds stresses agree with experimental data over an extended turbulent region downstream of transition. Normalized rms wall-pressure fluctuation increases gradually with the streamwise growth of the turbulent boundary layer. Wall shear stress fluctuation, τw,rms'+, on the other hand, remains constant at approximately 0.44 over the range, 800
Two-Dimensional Thermal Boundary Layer Corrections for Convective Heat Flux Gauges
NASA Technical Reports Server (NTRS)
Kandula, Max; Haddad, George
2007-01-01
This work presents a CFD (Computational Fluid Dynamics) study of two-dimensional thermal boundary layer correction factors for convective heat flux gauges mounted in flat plate subjected to a surface temperature discontinuity with variable properties taken into account. A two-equation k - omega turbulence model is considered. Results are obtained for a wide range of Mach numbers (1 to 5), gauge radius ratio, and wall temperature discontinuity. Comparisons are made for correction factors with constant properties and variable properties. It is shown that the variable-property effects on the heat flux correction factors become significant
On estimating total daily evapotranspiration from remote surface temperature measurements
NASA Technical Reports Server (NTRS)
Carlson, Toby N.; Buffum, Martha J.
1989-01-01
A method for calculating daily evapotranspiration from the daily surface energy budget using remotely sensed surface temperature and several meteorological variables is presented. Vaules of the coefficients are determined from simulations with a one-dimensional boundary layer model with vegetation cover. Model constants are obtained for vegetation and bare soil at two air temperature and wind speed levels over a range of surface roughness and wind speeds. A different means of estimating the daily evapotranspiration based on the time rate of increase of surface temperature during the morning is also considered. Both the equations using our model-derived constants and field measurements are evaluated, and a discussion of sources of error in the use of the formulation is given.
An Innovative Flow-Measuring Device: Thermocouple Boundary Layer Rake
NASA Technical Reports Server (NTRS)
Hwang, Danny P.; Fralick, Gustave C.; Martin, Lisa C.; Wrbanek, John D.; Blaha, Charles A.
2001-01-01
An innovative flow-measuring device, a thermocouple boundary layer rake, was developed. The sensor detects the flow by using a thin-film thermocouple (TC) array to measure the temperature difference across a heater strip. The heater and TC arrays are microfabricated on a constant-thickness quartz strut with low heat conductivity. The device can measure the velocity profile well into the boundary layer, about 65 gm from the surface, which is almost four times closer to the surface than has been possible with the previously used total pressure tube.
Mohoric; Stepisnik
2000-11-01
This paper describes the influence of natural convection on NMR measurement of a self-diffusion constant of fluid in the earth's magnetic field. To get an estimation of the effect, the Lorenz model of natural convection in a horizontally oriented cylinder, heated from below, is derived. Since the Lorenz model of natural convection is derived for the free boundary condition, its validity is of a limited value for the natural no-slip boundary condition. We point out that even a slight temperature gradient can cause significant misinterpretation of measurements. The chaotic nature of convection enhances the apparent self-diffusion constant of the liquid.
NASA Technical Reports Server (NTRS)
Dunn, M. G.
1972-01-01
The rate coefficients for the reactions C(+) + e(-) + e(-) yields C + e(-) and CO(+) + e(-) yields C + O were measured over the electron temperature range of approximately 1500 deg K to 7000 deg K. The measurements were performed in CO that had expanded from equilibrium reservoir conditions of 7060 deg K at 17.3 atm pressure and from 6260 deg K at 10.0 atm pressure. Two RAM flight probes were used to measure electron density and electron temperature in the expanding flow of a shock tunnel. Experiments were performed in the inviscid flow with both probes and in the nozzle-wall boundary layer with the constant bias-voltage probe. The distributions of electron density and electron temperature were independently measured using voltage-swept thin-wire probes. Thin-wire Langmuir probes were also used to measure the electron-density and electron-temperature distributions in the boundary layer of a sharp flat plate located on the nozzle centerline. Admittance measurements were performed with the RAM C and RAM C-C S-band antennas in the presence of an ionized boundary layer.
Direct measurement of methane hydrate composition along the hydrate equilibrium boundary
Circone, S.; Kirby, S.H.; Stern, L.A.
2005-01-01
The composition of methane hydrate, namely nW for CH 4??nWH2O, was directly measured along the hydrate equilibrium boundary under conditions of excess methane gas. Pressure and temperature conditions ranged from 1.9 to 9.7 MPa and 263 to 285 K. Within experimental error, there is no change in hydrate composition with increasing pressure along the equilibrium boundary, but nW may show a slight systematic decrease away from this boundary. A hydrate stoichiometry of n W = 5.81-6.10 H2O describes the entire range of measured values, with an average composition of CH4??5.99(??0.07) H2O along the equilibrium boundary. These results, consistent with previously measured values, are discussed with respect to the widely ranging values obtained by thermodynamic analysis. The relatively constant composition of methane hydrate over the geologically relevant pressure and temperature range investigated suggests that in situ methane hydrate compositions may be estimated with some confidence. ?? 2005 American Chemical Society.
NASA Technical Reports Server (NTRS)
Hansen, C. Frederick; Early, Richard A.; Alzofon, Frederick E.; Witteborn, Fred C.
1959-01-01
Solutions are presented for the conduction of beat through a semi-infinite gas medium having a uniform initial temperature and a constant boundary temperature. The coefficients of thermal conductivity and diffusivity are treated as variables, and the solutions are extended to the case of air at temperatures where oxygen dissociation occurs. These solutions are used together with shock-tube measurements to evaluate the integral of thermal conductivity for air as a function of temperature.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Joye, D.D.
1996-07-01
Mixed convection heat transfer in a vertical tube with opposing flow (downflow heating) was studied experimentally for Reynolds numbers ranging from about 1,000 to 30,000 at constant Grashof numbers ranging about 1{1/2} orders of magnitude under constant wall temperature (CWT) conditions. Three correlations developed for opposing mixed convection flows in vertical conduits predicted the data reasonably well, except near and into the asymptote region for which these equations were not designed. A critical Reynolds number is developed here, above which these equations can be used for design purposes regardless of the boundary condition. Below Re{sub crit}, the correlations, the asymptotemore » equation should be used for the CWT boundary condition, which is more prevalent in process situations than the uniform heat flux (UHF) boundary condition.« less
On the dependence of the domain of values of functionals of hypersonic aerodynamics on controls
NASA Astrophysics Data System (ADS)
Bilchenko, Grigory; Bilchenko, Nataly
2018-05-01
The properties of mathematical model of control of heat and mass transfer in laminar boundary layer on permeable cylindrical and spherical surfaces of the hypersonic aircraft are considered. Dependences of hypersonic aerodynamics functionals (the total heat flow and the total Newton friction force) on controls (the blowing into boundary layer, the temperature factor, the magnetic field) are investigated. The domains of allowed values of functionals of hypersonic aerodynamics are obtained. The results of the computational experiments are presented: the dependences of total heat flow on controls; the dependences of total Newton friction force on controls; the mutual dependences of functionals (as the domains of allowed values "Heat and Friction"); the dependences of blowing system power on controls. The influences of magnetic field and dissociation on the domain of "Heat and Friction" allowed values are studied. It is proved that for any fixed constant value of magnetic field the blowing system power is a symmetric function of constant dimensionless controls (the blowing into boundary layer and the temperature factor). It is shown that the obtained domain of allowed values of functionals of hypersonic aerodynamics depending on permissible range of controls may be used in engineering.
Gravity Scaling of a Power Reactor Water Shield
NASA Technical Reports Server (NTRS)
Reid, Robert S.; Pearson, J. Boise
2007-01-01
A similarity analysis on a water-based reactor shield examined the effect of gravity on free convection between a reactor shield inner and outer vessel boundaries. Two approaches established similarity between operation on the Earth and the Moon: 1) direct scaling of Rayleigh number equating gravity-surface heat flux products, 2) temperature difference between the wall and thermal boundary layer held constant. Nusselt number for natural convection (laminar and turbulent) is assumed of form Nu = CRa(sup n).
An Engineering Approach to the Variable Fluid Property Problem in Free Convection
NASA Technical Reports Server (NTRS)
Gregg, J. L.; Sparrow, E. M.
1956-01-01
An analysis is made for the variable fluid property problem for laminar free convection on an isothermal vertical flat plate. For a number of specific cases, solutions of the boundary layer equations appropriate to the variable property situation were carried out for gases and liquid mercury. Utilizing these findings, a simple and accurate shorthand procedure is presented for calculating free convection heat transfer under variable property conditions. This calculation method is well established in the heat transfer field. It involves the use of results which have been derived for constant property fluids, and of a set of rules (called reference temperatures) for extending these constant property results to variable property situations. For gases, the constant property heat transfer results are generalized to the variable property situation by replacing beta (expansion coefficient) by one over T sub infinity and evaluating the other properties at T sub r equals T sub w minus zero point thirty-eight (T sub w minus T sub infinity). For liquid mercury, the generalization may be accomplished by evaluating all the properties (including beta) at this same T sub r. It is worthwhile noting that for these fluids, the film temperature (with beta equals one over T sub infinity for gases) appears to serve as an adequate reference temperature for most applications. Results are also presented for boundary layer thickness and velocity parameters.
The sensitivity of numerically simulated climates to land-surface boundary conditions
NASA Technical Reports Server (NTRS)
Mintz, Y.
1982-01-01
Eleven sensitivity experiments that were made with general circulation models to see how land-surface boundary conditions can influence the rainfall, temperature, and motion fields of the atmosphere are discussed. In one group of experiments, different soil moistures or albedos are prescribed as time-invariant boundary conditions. In a second group, different soil moistures or different albedos are initially prescribed, and the soil moisture (but not the albedo) is allowed to change with time according to the governing equations for soil moisture. In a third group, the results of constant versus time-dependent soil moistures are compared.
A computer program for the simulation of heat and moisture flow in soils
NASA Technical Reports Server (NTRS)
Camillo, P.; Schmugge, T. J.
1981-01-01
A computer program that simulates the flow of heat and moisture in soils is described. The space-time dependence of temperature and moisture content is described by a set of diffusion-type partial differential equations. The simulator uses a predictor/corrector to numerically integrate them, giving wetness and temperature profiles as a function of time. The simulator was used to generate solutions to diffusion-type partial differential equations for which analytical solutions are known. These equations include both constant and variable diffusivities, and both flux and constant concentration boundary conditions. In all cases, the simulated and analytic solutions agreed to within the error bounds which were imposed on the integrator. Simulations of heat and moisture flow under actual field conditions were also performed. Ground truth data were used for the boundary conditions and soil transport properties. The qualitative agreement between simulated and measured profiles is an indication that the model equations are reasonably accurate representations of the physical processes involved.
Simulation on Melting Process of Water Using Molecular Dynamics Method
NASA Astrophysics Data System (ADS)
Okawa, Seiji; Saito, Akio; Kang, Chaedong
Simulation on phase change from ice to water was presented using molecular dynamics method. 576molecules were placed in a cell at ice forming arrangement. The volume of the cell was fixed so that the density of ice was kept at 923 kg/m3. Periodic boundary condition was used. According to the phase diagram of water, melting point of ice at the density of 923 kg/m3 is about 400 K. In order to perform melting process from surface, only the molecules near the boundary were scaled at each time step to keep its average temperature at 420 K, and the average temperature of other molecules were set to 350 K as initial condition. By observing time variation of the change in molecular arrangement, it was found that the hydrogen bond network near the boundary surface started to break its configuration and the melting surface moved towards the center until no more ice forming configuration was observed. This phenomenon was also discussed in a form of temperature and energy variation. The total energy increased and reached to a steady state at the time around 6.5 ps. This increment was due to the energy supplied from the boundary at a constant temperature. The temperature in the cell kept almost constant at 380 K during the period between 0.6 and 5.5 ps. This period coincides with melting process observed in molecular arrangement. Hence, it can be said that 380 K corresponds to the melting point. The total energy stored in the cell consisted of sensible and latent heat. Specific heat of water and ice were calculated, and they were found to be 5.6 kJ/kg·K and 3.7 kJ/kg·K, respectively. Hence, latent heat was found to be 316kJ/kg. These values agreed quite well to the physical properties of water.
On the Henry constant and isosteric heat at zero loading in gas phase adsorption.
Do, D D; Nicholson, D; Do, H D
2008-08-01
The Henry constant and the isosteric heat of adsorption at zero loading are commonly used as indicators of the strength of the affinity of an adsorbate for a solid adsorbent. It is assumed that (i) they are observable in practice, (ii) the Van Hoff's plot of the logarithm of the Henry constant versus the inverse of temperature is always linear and the slope is equal to the heat of adsorption, and (iii) the isosteric heat of adsorption at zero loading is either constant or weakly dependent on temperature. We show in this paper that none of these three points is necessarily correct, first because these variables might not be observable since they are outside the range of measurability; second that the linearity of the Van Hoff plot breaks down at very high temperature, and third that the isosteric heat versus loading is a strong function of temperature. We demonstrate these points using Monte Carlo integration and Monte Carlo simulation of adsorption of various gases on a graphite surface. Another issue concerning the Henry constant is related to the way the adsorption excess is defined. The most commonly used equation is the one that assumes that the void volume is the volume extended all the way to a boundary passing through the centres of the outermost solid atoms. With this definition the Henry constant can become negative at high temperatures. Although adsorption at these temperatures may not be practical because of the very low value of the Henry constant, it is more useful to define the Henry constant in such a way that it is always positive at all temperatures. Here we propose the use of the accessible volume; the volume probed by the adsorbate when it is in nonpositive regions of the potential, to calculate the Henry constant.
NASA Astrophysics Data System (ADS)
Ahmad, Mohamad M.; Yamada, Koji
2014-04-01
In the present work, CaCu3Ti4O12 (CCTO) nanoceramics with different grain sizes were prepared by spark plasma sintering (SPS) at different temperatures (SPS-800, SPS-900, SPS-975, and SPS-1050) of the mechanosynthesized nano-powder. Structural and microstructural properties were studied by XRD and field-emission scanning electron microscope measurements. The grain size of CCTO nanoceramics increases from 80 nm to ˜200 nm for the ceramics sintered at 800 °C and 975 °C, respectively. Further increase of SPS temperature to 1050 °C leads to micro-sized ceramics of 2-3 μm. The electrical and dielectric properties of the investigated ceramics were studied by impedance spectroscopy. Giant dielectric constant was observed in CCTO nanoceramics. The dielectric constant increases with increasing the grain size of the nanoceramics with values of 8.3 × 103, 2.4 × 104, and 3.2 × 104 for SPS-800, SPS-900, and SPS-975, respectively. For the micro-sized SPS-1050 ceramics, the dielectric constant dropped to 2.14 × 104. The dielectric behavior is interpreted within the internal barrier layer capacitance picture due to the electrical inhomogeneity of the ceramics. Besides the resistive grain boundaries that are usually observed in CCTO ceramics, domain boundaries appear as a second source of internal layers in the current nanoceramics.
Tang, Liguo; Cao, Wenwu
2016-01-01
During the operation of high power electromechanical devices, a temperature rise is unavoidable due to mechanical and electrical losses, causing the degradation of device performance. In order to evaluate such degradations using computer simulations, full matrix material properties at elevated temperatures are needed as inputs. It is extremely difficult to measure such data for ferroelectric materials due to their strong anisotropic nature and property variation among samples of different geometries. Because the degree of depolarization is boundary condition dependent, data obtained by the IEEE (Institute of Electrical and Electronics Engineers) impedance resonance technique, which requires several samples with drastically different geometries, usually lack self-consistency. The resonant ultrasound spectroscopy (RUS) technique allows the full set material constants to be measured using only one sample, which can eliminate errors caused by sample to sample variation. A detailed RUS procedure is demonstrated here using a lead zirconate titanate (PZT-4) piezoceramic sample. In the example, the complete set of material constants was measured from room temperature to 120 °C. Measured free dielectric constants and were compared with calculated ones based on the measured full set data, and piezoelectric constants d15 and d33 were also calculated using different formulas. Excellent agreement was found in the entire range of temperatures, which confirmed the self-consistency of the data set obtained by the RUS. PMID:27168336
Correlation of nosetip boundary-layer transition data measured in ballistics-range experiments
DOE Office of Scientific and Technical Information (OSTI.GOV)
Reda, D.C.
1980-01-01
Preablated nosetips of various carbonaceous materials were tested in a ballistics range. Surface-temperature contours, measured with image-converter cameras, were used to define boundary-layer transition-front contours. Measurements of surface roughness, surface temperature, average transition-front location, and freestream environment were combined with calculations of nosetip flowfields, and with calculations of laminar boundary-layer development in these flowfields, to transform all data into various dimensionless parameters. These parameters were defined by previous attempts to correlate existing wind-tunnel data for transition on rough/blunt bodies. Of the available correlating techniques, only one, based on the concept of a constant (critical) roughness Reynolds number for transition, wasmore » found to successfully describe both the wind-tunnel and ballistics-range data, thereby validating the extrapolation of this concept to actual reentry-vehicle materials and environments.« less
Hawking temperature of constant curvature black holes
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cai Ronggen; Myung, Yun Soo; Institute of Basic Science and School of Computer Aided Science, Inje University, Gimhae 621-749
2011-05-15
The constant curvature (CC) black holes are higher dimensional generalizations of Banados-Teitelboim-Zanelli black holes. It is known that these black holes have the unusual topology of M{sub D-1}xS{sup 1}, where D is the spacetime dimension and M{sub D-1} stands for a conformal Minkowski spacetime in D-1 dimensions. The unusual topology and time-dependence for the exterior of these black holes cause some difficulties to derive their thermodynamic quantities. In this work, by using a globally embedding approach, we obtain the Hawking temperature of the CC black holes. We find that the Hawking temperature takes the same form when using both themore » static and global coordinates. Also, it is identical to the Gibbons-Hawking temperature of the boundary de Sitter spaces of these CC black holes.« less
2000-04-01
system, 8 - experiments on a study of boundary layer spectrum infrared window). before boiling of glass- silicide coating. This simple 3. SAMPLES AND...dependencies of surface temperature of tested materials and make conclusions concerned joint gllass- silicide coating and anode power of generator...obtained using test stagnation point configuration. glass- silicide coating vs anode power of HF-generator. Temperature peak at constant power
Nonequilibrium kinetic boundary condition at the vapor-liquid interface of argon
NASA Astrophysics Data System (ADS)
Ishiyama, Tatsuya; Fujikawa, Shigeo; Kurz, Thomas; Lauterborn, Werner
2013-10-01
A boundary condition for the Boltzmann equation (kinetic boundary condition, KBC) at the vapor-liquid interface of argon is constructed with the help of molecular dynamics (MD) simulations. The KBC is examined at a constant liquid temperature of 85 K in a wide range of nonequilibrium states of vapor. The present investigation is an extension of a previous one by Ishiyama, Yano, and Fujikawa [Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.95.084504 95, 084504 (2005)] and provides a more complete form of the KBC. The present KBC includes a thermal accommodation coefficient in addition to evaporation and condensation coefficients, and these coefficients are determined in MD simulations uniquely. The thermal accommodation coefficient shows an anisotropic behavior at the interface for molecular velocities normal versus tangential to the interface. It is also found that the evaporation and condensation coefficients are almost constant in a fairly wide range of nonequilibrium states. The thermal accommodation coefficient of the normal velocity component is almost unity, while that of the tangential component shows a decreasing function of the density of vapor incident on the interface, indicating that the tangential velocity distribution of molecules leaving the interface into the vapor phase may deviate from the tangential parts of the Maxwell velocity distribution at the liquid temperature. A mechanism for the deviation of the KBC from the isotropic Maxwell KBC at the liquid temperature is discussed in terms of anisotropic energy relaxation at the interface. The liquid-temperature dependence of the present KBC is also discussed.
NASA Astrophysics Data System (ADS)
Kozlov, V. V.; Katasonov, M. M.; Pavlenko, A. M.
2017-10-01
Downstream development of artificial disturbances were investigated experimentally using hot-wire constant temperature anemometry. It is shown that vibrations with high-amplitude of a three-dimensional surface lead to formation of two types of perturbations in the straight wing boundary layer: streamwise oriented localized structures and wave packets. The amplitude of streamwise structure is decay downstream. The wave packets amplitude grows in adverse pressure gradient area. The flow separation is exponentially intensified of the wave packet amplitude.
NASA Technical Reports Server (NTRS)
Morduchow, Morris
1955-01-01
A survey of integral methods in laminar-boundary-layer analysis is first given. A simple and sufficiently accurate method for practical purposes of calculating the properties (including stability) of the laminar compressible boundary layer in an axial pressure gradient with heat transfer at the wall is presented. For flow over a flat plate, the method is applicable for an arbitrarily prescribed distribution of temperature along the surface and for any given constant Prandtl number close to unity. For flow in a pressure gradient, the method is based on a Prandtl number of unity and a uniform wall temperature. A simple and accurate method of determining the separation point in a compressible flow with an adverse pressure gradient over a surface at a given uniform wall temperature is developed. The analysis is based on an extension of the Karman-Pohlhausen method to the momentum and the thermal energy equations in conjunction with fourth- and especially higher degree velocity and stagnation-enthalpy profiles.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Majeski, R.; Bell, R. E.; Boyle, D. P.
We measured high edge electron temperatures (200 eV or greater) at the wall-limited plasma boundary in the Lithium Tokamak Experiment (LTX). Flat electron temperature profiles are a long-predicted consequence of low recycling boundary conditions. Plasma density in the outer scrape-off layer is very low, 2-3 x 10(17) m(-3), consistent with a low recycling metallic lithium boundary. In spite of the high edge temperature, the core impurity content is low. Z(eff) is estimated to be similar to 1.2, with a very modest contribution (< 0.1) from lithium. Experiments are transient. Gas puffing is used to increase the plasma density. After gasmore » injection stops, the discharge density is allowed to drop, and the edge is pumped by the low recycling lithium wall. An upgrade to LTX-LTX-beta, which includes a 35A, 20 kV neutral beam injector (on loan to LTX from Tri-Alpha Energy) to provide core fueling to maintain constant density, as well as auxiliary heating, is underway. LTX-beta is briefly described.« less
Majeski, R.; Bell, R. E.; Boyle, D. P.; ...
2017-03-20
We measured high edge electron temperatures (200 eV or greater) at the wall-limited plasma boundary in the Lithium Tokamak Experiment (LTX). Flat electron temperature profiles are a long-predicted consequence of low recycling boundary conditions. Plasma density in the outer scrape-off layer is very low, 2-3 x 10(17) m(-3), consistent with a low recycling metallic lithium boundary. In spite of the high edge temperature, the core impurity content is low. Z(eff) is estimated to be similar to 1.2, with a very modest contribution (< 0.1) from lithium. Experiments are transient. Gas puffing is used to increase the plasma density. After gasmore » injection stops, the discharge density is allowed to drop, and the edge is pumped by the low recycling lithium wall. An upgrade to LTX-LTX-beta, which includes a 35A, 20 kV neutral beam injector (on loan to LTX from Tri-Alpha Energy) to provide core fueling to maintain constant density, as well as auxiliary heating, is underway. LTX-beta is briefly described.« less
NASA Astrophysics Data System (ADS)
Majeski, R.; Bell, R. E.; Boyle, D. P.; Kaita, R.; Kozub, T.; LeBlanc, B. P.; Lucia, M.; Maingi, R.; Merino, E.; Raitses, Y.; Schmitt, J. C.; Allain, J. P.; Bedoya, F.; Bialek, J.; Biewer, T. M.; Canik, J. M.; Buzi, L.; Koel, B. E.; Patino, M. I.; Capece, A. M.; Hansen, C.; Jarboe, T.; Kubota, S.; Peebles, W. A.; Tritz, K.
2017-05-01
High edge electron temperatures (200 eV or greater) have been measured at the wall-limited plasma boundary in the Lithium Tokamak Experiment (LTX). Flat electron temperature profiles are a long-predicted consequence of low recycling boundary conditions. Plasma density in the outer scrape-off layer is very low, 2-3 × 1017 m-3, consistent with a low recycling metallic lithium boundary. Despite the high edge temperature, the core impurity content is low. Zeff is estimated to be ˜1.2, with a very modest contribution (<0.1) from lithium. Experiments are transient. Gas puffing is used to increase the plasma density. After gas injection stops, the discharge density is allowed to drop, and the edge is pumped by the low recycling lithium wall. An upgrade to LTX-LTX-β, which includes a 35A, 20 kV neutral beam injector (on loan to LTX from Tri-Alpha Energy) to provide core fueling to maintain constant density, as well as auxiliary heating, is underway. LTX-β is briefly described.
NASA Technical Reports Server (NTRS)
Deissler, R. G.; Loeffler, A. L., Jr.
1959-01-01
A previous analysis of turbulent heat transfer and flow with variable fluid properties in smooth passages is extended to flow over a flat plate at high Mach numbers, and the results are compared with experimental data. Velocity and temperature distributions are calculated for a boundary layer with appreciative effects of frictional heating and external heat transfer. Viscosity and thermal conductivity are assumed to vary as a power or the temperature, while Prandtl number and specific heat are taken as constant. Skin-friction and heat-transfer coefficients are calculated and compared with the incompressible values. The rate of boundary-layer growth is obtained for various Mach numbers.
Diffusion mechanisms in chemical vapor-deposited iridium coated on chemical vapor-deposited rhenium
NASA Technical Reports Server (NTRS)
Hamilton, J. C.; Yang, N. Y. C.; Clift, W. M.; Boehme, D. R.; Mccarty, K. F.; Franklin, J. E.
1992-01-01
Radiation-cooled rocket thruster chambers have been developed which use CVD Re coated with CVD Ir on the interior surface that is exposed to hot combustion gases. The Ir serves as an oxidation barrier which protects the structural integrity-maintaining Re at elevated temperatures. The diffusion kinetics of CVD materials at elevated temperatures is presently studied with a view to the prediction and extension of these thrusters' performance limits. Line scans for Ir and Re were fit on the basis of a diffusion model, in order to extract relevant diffusion constants; the fastest diffusion process is grain-boundary diffusion, where Re diffuses down grain boundaries in the Ir overlayer.
Similarity solutions for unsteady free-convection flow from a continuous moving vertical surface
NASA Astrophysics Data System (ADS)
Abd-El-Malek, Mina B.; Kassem, Magda M.; Mekky, Mohammad L.
2004-03-01
The transformation group theoretic approach is applied to present an analysis of the problem of unsteady free convection flow over a continuous moving vertical sheet in an ambient fluid. The thermal boundary layer induced within a vertical semi-infinite layer of Boussinseq fluid by a constant heated bounding plate. The application of two-parameter groups reduces the number of independent variables by two, and consequently the system of governing partial differential equations with the boundary conditions reduces to a system of ordinary differential equations with appropriate boundary conditions. The obtained ordinary differential equations are solved analytically for the temperature and numerically for the velocity using the shooting method. Effect of Prandtl number on the thermal boundary-layer and velocity boundary-layer are studied and plotted in curves.
Advantageous grain boundaries in iron pnictide superconductors
Katase, Takayoshi; Ishimaru, Yoshihiro; Tsukamoto, Akira; Hiramatsu, Hidenori; Kamiya, Toshio; Tanabe, Keiichi; Hosono, Hideo
2011-01-01
High critical temperature superconductors have zero power consumption and could be used to produce ideal electric power lines. The principal obstacle in fabricating superconducting wires and tapes is grain boundaries—the misalignment of crystalline orientations at grain boundaries, which is unavoidable for polycrystals, largely deteriorates critical current density. Here we report that high critical temperature iron pnictide superconductors have advantages over cuprates with respect to these grain boundary issues. The transport properties through well-defined bicrystal grain boundary junctions with various misorientation angles (θGB) were systematically investigated for cobalt-doped BaFe2As2 (BaFe2As2:Co) epitaxial films fabricated on bicrystal substrates. The critical current density through bicrystal grain boundary (JcBGB) remained high (>1 MA cm−2) and nearly constant up to a critical angle θc of ∼9°, which is substantially larger than the θc of ∼5° for YBa2Cu3O7–δ. Even at θGB>θc, the decay of JcBGB was much slower than that of YBa2Cu3O7–δ. PMID:21811238
NASA Astrophysics Data System (ADS)
Day, B. M.; Clements, C. B.; Rappenglueck, B.
2007-12-01
High-temporal resolution tethersonde profiles taken during the TexAQS II field campaign in Houston were used to study the overnight development and progression of the nocturnal boundary layer (NBL) and the evolution of the convective boundary layer after sunrise. The measurements were made at the University of Houston campus, located approximately 4 km southeast of the downtown Houston central business district, and consisted of vertical profiles of potential temperature, water vapor mixing ratio, wind speed, wind direction, and ozone concentration. Profile heights averaged 250 m AGL with a few reaching 400 m AGL. Profiles were taken at approximately 30 min intervals throughout 4 nights during Intensive Observational Periods (IOPs), including both the evening and morning transitional periods. Tethersonde experiments also were performed during several additional morning break-up periods during the campaign. Preliminary results from the overnight experiments of Sept 7-8 and Sept 14-15, 2006 showed different NBL evolutions. Sept 7-8 exhibited a stronger and deeper inversion compared with Sept 14-15 when the inversion was weak with a fairly constant height throughout the night. The Sept 7-8 profiles showed elevated bluff-like structures in the virtual potential temperature profiles between 0300-0400 CDT, indicating neutral stability within the 40-90 m AGL level. And, just before sunrise a neutral layer with constant potential temperature developed between the surface and 75 m AGL reflecting horizontal cold air advection. Further analyses will be presented for other vertical profiles taken during the campaign, including the additional overnight profiles as well as the profiles taken during the morning transition to the convective boundary layer.
Giant dielectric constant in titania nanoparticles embedded in conducting polymer matrix.
Dey, Ashis; De, Sukanta; De, Amitabha; De, S K
2006-05-01
Complex impedance and dielectric permittivity of titania-polypyrrole nanocomposites have been investigated as a function of frequency and temperature at different compositions. A very large dielectric constant of about 13,000 at room temperature has been observed. The colossal dielectric constant is mainly dominated by interfacial polarization due to Maxwell-Wagner relaxation effect. Two completely separate groups of dielectric relaxation have been observed. The low frequency dielectric relaxation arises from surface defect states of titania nanoparticles. The broad peak at high frequency region is attributed to Maxwell-Wagner type polarization originating from the inhomogeneous property of nanocomposite. An abrupt change in grain boundary conductivity and dielectric relaxation associated with titania was observed at around 150 K. Anomalous behavior in conductivity and dielectric relaxation is qualitatively explained by band tail structure of titania nanoparticle.
Molecular Modeling for Calculation of Mechanical Properties of Epoxies with Moisture Ingress
NASA Technical Reports Server (NTRS)
Clancy, Thomas C.; Frankland, Sarah J.; Hinkley, J. A.; Gates, T. S.
2009-01-01
Atomistic models of epoxy structures were built in order to assess the effect of crosslink degree, moisture content and temperature on the calculated properties of a typical representative generic epoxy. Each atomistic model had approximately 7000 atoms and was contained within a periodic boundary condition cell with edge lengths of about 4 nm. Four atomistic models were built with a range of crosslink degree and moisture content. Each of these structures was simulated at three temperatures: 300 K, 350 K, and 400 K. Elastic constants were calculated for these structures by monitoring the stress tensor as a function of applied strain deformations to the periodic boundary conditions. The mechanical properties showed reasonably consistent behavior with respect to these parameters. The moduli decreased with decreasing crosslink degree with increasing temperature. The moduli generally decreased with increasing moisture content, although this effect was not as consistent as that seen for temperature and crosslink degree.
Schottky-type grain boundaries in CCTO ceramics
NASA Astrophysics Data System (ADS)
Felix, A. A.; Orlandi, M. O.; Varela, J. A.
2011-10-01
In this work we studied electrical barriers existing at CaCu 3Ti 4O 12 (CCTO) ceramics using dc electrical measurements. CCTO pellets were produced by solid state reaction method and X-ray diffractograms showed which single phase polycrystalline samples were obtained. The samples were electrically characterized by dc and ac measurements as a function of temperature, and semiconductor theory was applied to analyze the barrier at grain boundaries. The ac results showed the sample's permittivity is almost constant ( 104) as function of temperature at low frequencies and it changes from 100 to 104 as the temperature increases at high frequencies. Using dc measurements as a function of temperature, the behavior of barriers was studied in detail. Comparison between Schottky and Poole-Frenkel models was performed, and results prove that CCTO barriers are more influenced by temperature than by electric field (Schottky barriers). Besides, the behavior of barrier width as function of temperature was also studied and experimental results confirm the theoretical assumptions.
NASA Technical Reports Server (NTRS)
Liu, T.-M.; Davy, W. C.
1974-01-01
The nonequilibrium axisymmetric stagnation point boundary layer over an ablating graphite surface is considered. The external stream is a high temperature mixture of hydrogen and helium. Variable thermodynamic and transport properties are assumed. Lennard-Jones potential model is used to calculate the transport coefficients of each species. Although the mixture rules for viscosity of the gas mixture are used, the weighting functions are more sophisticated than those commonly employed. For the conductivity of the mixture, generalized Wassiljewa coefficients are used. Seven species with 28 dissociation/recombination reactions are considered. Hansen's model for the dissociation rate constants is employed. The recombination rate constants are obtained by invoking detailed balance principles assisted by the JANAF thermodynamic data and the Hansen-Pearson thermodynamic data for C3.
NASA Technical Reports Server (NTRS)
DelGenio, Anthony
1999-01-01
Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning, is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types. At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.5C lower limit for the equilibrium global climate sensitivity to a doubling of CO2 which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.
NASA Technical Reports Server (NTRS)
DelGenio, Anthony D.; Wolf, Audrey B.
1999-01-01
Satellite observations of low-level clouds have challenged the assumption that adiabatic liquid water content combined with constant physical thickness will lead to a negative cloud optics feedback in a decadal climate change. We explore the reasons for the satellite results using four years of surface remote sensing data from the Atmospheric Radiation Measurement Program Cloud and Radiation Testbed site in the Southern Great Plains of the United States. We find that low cloud liquid water path is approximately invariant with temperature in winter but decreases strongly with temperature in summer, consistent with the satellite inferences at this latitude. This behavior occurs because liquid water content shows no detectable temperature dependence while cloud physical thickness decreases with warming. Thinning of clouds with warming is observed on seasonal, synoptic, and diurnal time scales; it is most obvious in the warm sectors of baroclinic waves. Although cloud top is observed to slightly descend with warming, the primary cause of thinning is the ascent of cloud base due to the reduction in surface relative humidity and the concomitant increase in the lifting condensation level of surface air. Low cloud liquid water path is not observed to be a continuous function of temperature. Rather, the behavior we observe is best explained as a transition in the frequency of occurrence of different boundary layer types: At cold temperatures, a mixture of stratified and convective boundary layers is observed, leading to a broad distribution of liquid water path values, while at warm temperatures, only convective boundary layers with small liquid water paths, some of them decoupled, are observed. Our results, combined with the earlier satellite inferences, imply that the commonly quoted 1.50 C lower limit for the equilibrium global climate sensitivity to a doubling of CO2, which is based on models with near-adiabatic liquid water behavior and constant physical thickness, should be revised upward.
Small polaronic hole hopping mechanism and Maxwell-Wagner relaxation in NdFeO3
NASA Astrophysics Data System (ADS)
Ahmad, I.; Akhtar, M. J.; Younas, M.; Siddique, M.; Hasan, M. M.
2012-10-01
In the modern micro-electronics, transition metal oxides due to their colossal values of dielectric permittivity possess huge potential for the development of capacitive energy storage devices. In the present work, the dielectric permittivity and the effects of temperature and frequency on the electrical transport properties of polycrystalline NdFeO3, prepared by solid state reaction method, are discussed. Room temperature Mossbauer spectrum confirms the phase purity, octahedral environment for Fe ion, and high spin state of Fe3+ ion. From the impedance spectroscopic measurements, three relaxation processes are observed, which are related to grains, grain boundaries (gbs), and electrode-semiconductor contact in the measured temperature and frequency ranges. Decrease in resistances and relaxation times of the grains and grain boundaries with temperature confirms the involvement of thermally activated conduction mechanisms. Same type of charge carriers (i.e., small polaron hole hopping) have been found responsible for conduction and relaxation processes through the grain and grain boundaries. The huge value of the dielectric constant (˜8 × 103) at high temperature and low frequency is correlated to the Maxwell-Wagner relaxation due to electrode-sample contact.
Active thermal isolation for temperature responsive sensors
NASA Technical Reports Server (NTRS)
Martinson, Scott D. (Inventor); Gray, David L. (Inventor); Carraway, Debra L. (Inventor); Reda, Daniel C. (Inventor)
1994-01-01
The detection of flow transition between laminar and turbulent flow and of shear stress or skin friction of airfoils is important in basic research for validation of airfoil theory and design. These values are conventionally measured using hot film nickel sensors deposited on a polyimide substrate. The substrate electrically insulates the sensor and underlying airfoil but is prevented from thermally isolating the sensor by thickness constraints necessary to avoid flow contamination. Proposed heating of the model surface is difficult to control, requires significant energy expenditures, and may alter the basic flow state of the airfoil. A temperature responsive sensor is located in the airflow over the specified surface of a body and is maintained at a constant temperature. An active thermal isolator is located between this temperature responsive sensor and the specific surface of the body. The total thickness of the isolator and sensor avoid any contamination of the flow. The temperature of this isolator is controlled to reduce conductive heat flow from the temperature responsive sensor to the body. This temperature control includes (1) operating the isolator at the same temperature as the constant temperature of the sensor; and (2) establishing a fixed boundary temperature which is either less than or equal to, or slightly greater than the sensor constant temperature. The present invention accordingly thermally isolates a temperature responsive sensor in an energy efficient, controllable manner while avoiding any contamination of the flow.
Heat transfer analysis of skin during thermal therapy using thermal wave equation.
Kashcooli, Meisam; Salimpour, Mohammad Reza; Shirani, Ebrahim
2017-02-01
Specifying exact geometry of vessel network and its effect on temperature distribution in living tissues is one of the most complicated problems of the bioheat field. In this paper, the effects of blood vessels on temperature distribution in a skin tissue subjected to various thermal therapy conditions are investigated. Present model consists of counter-current multilevel vessel network embedded in a three-dimensional triple-layered skin structure. Branching angles of vessels are calculated using the physiological principle of minimum work. Length and diameter ratios are specified using length doubling rule and Cube law, respectively. By solving continuity, momentum and energy equations for blood flow and Pennes and modified Pennes bioheat equations for the tissue, temperature distributions in the tissue are measured. Effects of considering modified Pennes bioheat equation are investigated, comprehensively. It is also observed that blood has an impressive role in temperature distribution of the tissue, especially at high temperatures. The effects of different parameters such as boundary conditions, relaxation time, thermal properties of skin, metabolism and pulse heat flux on temperature distribution are investigated. Tremendous effect of boundary condition type at the lower boundary is noted. It seems that neither insulation nor constant temperature at this boundary can completely describe the real physical phenomena. It is expected that real temperature at the lower levels is somewhat between two predicted values. The effect of temperature on the thermal properties of skin tissue is considered. It is shown that considering temperature dependent values for thermal conductivity is important in the temperature distribution estimation of skin tissue; however, the effect of temperature dependent values for specific heat capacity is negligible. It is seen that considering modified Pennes equation in processes with high heat flux during low times is significant. Copyright © 2016 Elsevier Ltd. All rights reserved.
Transient thermal stresses in a reinforced hollow disk or cylinder containing a radial crack
NASA Technical Reports Server (NTRS)
Tang, R.; Erdogan, F.
1983-01-01
The transient thermal stress problem in a hollow cylinder or a disk containing a radial crack is considered. It is assumed that the cylinder is reinforced on its inner boundary by a membrane which has thermoelastic constants different than those of the base material. The transient temperature, thermal stresses and the crack tip stress intensity factors are calculated in a cylinder which is subjected to a sudden change of temperature on the inside surface. The results are obtained for various dimensionless parameters and material constants. The special cases of the crack terminating at the cylinder-membrane interface and of the broken membrane are separately considered and some examples are given.
Transient thermal stresses in a reinforced hollow disk or cylinder containing a radial crack
NASA Technical Reports Server (NTRS)
Tang, R.; Erdogan, F.
1984-01-01
The transient thermal stress problem in a hollow cylinder or a disk containing a radial crack is considered. It is assumed that the cylinder is reinforced on its inner boundary by a membrane which has thermoelastic constants different than those of the base material. The transient temperature, thermal stresses and the crack tip stress intensity factors are calculated in a cylinder which is subjected to a sudden change of temperature on the inside surface. The results are obtained for various dimensionless parameters and material constants. The special cases of the crack terminating at the cylinder-membrane interface and of the broken membrane are separately considered and some examples are given.
NASA Technical Reports Server (NTRS)
Avis, L. M.
1976-01-01
Tensor methods are used to express the continuum equations of motion in general curvilinear, moving, and deforming coordinate systems. The space-time tensor formulation is applicable to situations in which, for example, the boundaries move and deform. Placing a coordinate surface on such a boundary simplifies the boundary condition treatment. The space-time tensor formulation is also applicable to coordinate systems with coordinate surfaces defined as surfaces of constant pressure, density, temperature, or any other scalar continuum field function. The vanishing of the function gradient components along the coordinate surfaces may simplify the set of governing equations. In numerical integration of the equations of motion, the freedom of motion of the coordinate surfaces provides a potential for enhanced resolution of the continuum field function. An example problem of an incompressible, inviscid fluid with a top free surface is considered, where the surfaces of constant pressure (including the top free surface) are coordinate surfaces.
Ash level meter for a fixed-bed coal gasifier
Fasching, George E.
1984-01-01
An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.
Fourier Transform Ultrasound Spectroscopy for the determination of wave propagation parameters.
Pal, Barnana
2017-01-01
The reported results for ultrasonic wave attenuation constant (α) in pure water show noticeable inconsistency in magnitude. A "Propagating-Wave" model analysis of the most popular pulse-echo technique indicates that this is a consequence of the inherent wave propagation characteristics in a bounded medium. In the present work Fourier Transform Ultrasound Spectroscopy (FTUS) is adopted to determine ultrasonic wave propagation parameters, the wave number (k) and attenuation constant (α) at 1MHz frequency in tri-distilled water at room temperature (25°C). Pulse-echo signals obtained under same experimental conditions regarding the exciting input signal and reflecting boundary wall of the water container for various lengths of water columns are captured. The Fast Fourier Transform (FFT) components of the echo signals are taken to compute k, α and r, the reflection constant at the boundary, using Oak Ridge and Oxford method. The results are compared with existing literature values. Copyright © 2016 Elsevier B.V. All rights reserved.
A review of turbulent-boundary-layer heat transfer research at Stanford, 1958-1983
NASA Technical Reports Server (NTRS)
Moffat, R. J.; Kays, W. M.
1984-01-01
For the past 25 years, there has existed in the Thermosciences Laboratory of the Mechanical Engineering Department of Stanford University a research program, primarily experimental, concerned with heat transfer through turbulent boundary layers. In the early phases of the program, the topics considered were the simple zero-pressure-gradient turbulent boundary layer with constant and with varying surface temperature, and the accelerated boundary layer. Later equilibrium boundary layers were considered along with factors affecting the boundary layer, taking into account transpired flows, flows with axial pressure gradients, transpiration, acceleration, deceleration, roughness, full-coverage film cooling, surface curvature, free convection, and mixed convection. A description is provided of the apparatus and techniques used, giving attention to the smooth plate rig, the rough plate rig, the full-coverage film cooling rig, the curvature rig, the concave wall rig, the mixed convection tunnel, and aspects of data reduction and uncertainty analysis.
Normal stress effects on Knudsen flow
NASA Astrophysics Data System (ADS)
Eu, Byung Chan
2018-01-01
Normal stress effects are investigated on tube flow of a single-component non-Newtonian fluid under a constant pressure gradient in a constant temperature field. The generalized hydrodynamic equations are employed, which are consistent with the laws of thermodynamics. In the cylindrical tube flow configuration, the solutions of generalized hydrodynamic equations are exactly solvable and the flow velocity is obtained in a simple one-dimensional integral quadrature. Unlike the case of flow in the absence of normal stresses, the flow develops an anomaly in that the flow in the boundary layer becomes stagnant and the thickness of such a stagnant velocity boundary layer depends on the pressure gradient, the aspect ratio of the radius to the length of the tube, and the pressure (or density and temperature) at the entrance of the tube. The volume flow rate formula through the tube is derived for the flow. It generalizes the Knudsen flow rate formula to the case of a non-Newtonian stress tensor in the presence of normal stress differences. It also reduces to the Navier-Stokes theory formula in the low shear rate limit near equilibrium.
Development of numerical model for predicting heat generation and temperatures in MSW landfills.
Hanson, James L; Yeşiller, Nazli; Onnen, Michael T; Liu, Wei-Lien; Oettle, Nicolas K; Marinos, Janelle A
2013-10-01
A numerical modeling approach has been developed for predicting temperatures in municipal solid waste landfills. Model formulation and details of boundary conditions are described. Model performance was evaluated using field data from a landfill in Michigan, USA. The numerical approach was based on finite element analysis incorporating transient conductive heat transfer. Heat generation functions representing decomposition of wastes were empirically developed and incorporated to the formulation. Thermal properties of materials were determined using experimental testing, field observations, and data reported in literature. The boundary conditions consisted of seasonal temperature cycles at the ground surface and constant temperatures at the far-field boundary. Heat generation functions were developed sequentially using varying degrees of conceptual complexity in modeling. First a step-function was developed to represent initial (aerobic) and residual (anaerobic) conditions. Second, an exponential growth-decay function was established. Third, the function was scaled for temperature dependency. Finally, an energy-expended function was developed to simulate heat generation with waste age as a function of temperature. Results are presented and compared to field data for the temperature-dependent growth-decay functions. The formulations developed can be used for prediction of temperatures within various components of landfill systems (liner, waste mass, cover, and surrounding subgrade), determination of frost depths, and determination of heat gain due to decomposition of wastes. Copyright © 2013 Elsevier Ltd. All rights reserved.
Nonlinear dynamics of mushy layers induced by external stochastic fluctuations.
Alexandrov, Dmitri V; Bashkirtseva, Irina A; Ryashko, Lev B
2018-02-28
The time-dependent process of directional crystallization in the presence of a mushy layer is considered with allowance for arbitrary fluctuations in the atmospheric temperature and friction velocity. A nonlinear set of mushy layer equations and boundary conditions is solved analytically when the heat and mass fluxes at the boundary between the mushy layer and liquid phase are induced by turbulent motion in the liquid and, as a result, have the corresponding convective form. Namely, the 'solid phase-mushy layer' and 'mushy layer-liquid phase' phase transition boundaries as well as the solid fraction, temperature and concentration (salinity) distributions are found. If the atmospheric temperature and friction velocity are constant, the analytical solution takes a parametric form. In the more common case when they represent arbitrary functions of time, the analytical solution is given by means of the standard Cauchy problem. The deterministic and stochastic behaviour of the phase transition process is analysed on the basis of the obtained analytical solutions. In the case of stochastic fluctuations in the atmospheric temperature and friction velocity, the phase transition interfaces (mushy layer boundaries) move faster than in the deterministic case. A cumulative effect of these noise contributions is revealed as well. In other words, when the atmospheric temperature and friction velocity fluctuate simultaneously due to the influence of different external processes and phenomena, the phase transition boundaries move even faster. This article is part of the theme issue 'From atomistic interfaces to dendritic patterns'.This article is part of the theme issue 'From atomistic interfaces to dendritic patterns'. © 2018 The Author(s).
NASA Astrophysics Data System (ADS)
Guala, M.; Hu, S. J.; Chamorro, L. P.
2011-12-01
Turbulent boundary layer measurements in both wind tunnel and in the near-neutral atmospheric surface layer revealed in the last decade the significant contribution of the large scales of motions to both turbulent kinetic energy and Reynolds stresses, for a wide range of Reynolds number. These scales are known to grow throughout the logarithmic layer and to extend several boundary layer heights in the streamwise direction. Potentially, they are a source of strong unsteadiness in the power output of wind turbines and in the aerodynamic loads of wind turbine blades. However, the large scales in realistic atmospheric conditions deserves further study, with well controlled boundary conditions. In the atmospheric wind tunnel of the St. Anthony Falls Laboratory, with a 16 m long test section and independently controlled incoming flow and floor temperatures, turbulent boundary layers in a range of stability conditions, from the stratified to the convective case, can be reproduced and monitored. Measurements of fluctuating temperature, streamwise and wall normal velocity components are simultaneously obtained by an ad hoc calibrated and customized triple-wire sensor. A wind turbine model with constant loading DC motor, constant tip speed ratio, and a rotor diameter of 0.128m is used to mimic a large full scale turbine in the atmospheric boundary layer. Measurements of the fluctuating voltage generated by the DC motor are compared with measurements of the blade's angular velocity by laser scanning, and eventually related to velocity measurements from the triple-wire sensor. This study preliminary explores the effect of weak stability and complex terrain (through a set of spanwise aligned topographic perturbations) on the large scales of the flow and on the fluctuations in the wind turbine(s) power output.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Perez, R. B.; Carroll, R. M.; Sisman, O.
1971-02-01
A method to measure the thermal diffusivity of reactor fuels during irradiation is developed, based on a time-dependent heat diffusion equation. With this technique the temperature is measured at only one point in the fuel specimen. This method has the advantage that it is not necessary to know the heat generation (a difficult evaluation during irradiation). The theory includes realistic boundary conditions, applicable to actual experimental systems. The parameters are the time constants associated with the first two time modes in the temperature-vs-time curve resulting from a step change in heat input to the specimen. With the time constants andmore » the necessary material properties and dimensions of the specimen and specimen holder, the thermal diffusivity of the specimen can be calculated.« less
Rate of precipitation of calcium phosphate on heated surfaces.
Barton, K P; Chapman, T W; Lund, D
1985-03-01
Fouling of a heated stainless steel surface by calcium phosphate precipitation has been studied in an annular flow apparatus, instrumented to provide a constant heat flux while measuring local metal-surface temperatures. Models of the heat and mass-transfer boundary layers are used to estimate interfacial temperatures and concentrations, from which the heterogeneous reaction rate is inferred. The analysis indicates that the reaction rate is a function of both chemical kinetics and mass transfer limitations.
On the compressibility and temperature boundary of warm frozen soils
NASA Astrophysics Data System (ADS)
Qi, Jilin; Dang, Boxiang; Guo, Xueluan; Sun, Xiaoyu; Yan, Xu
2017-04-01
A silty-clay obtained along the Qinghai-Tibetan railway and a standard Chinese sand were taken as study objects. Saturated frozen soil samples were prepared for testing. Step-load was used and confined compression was carried out on the soils under different temperatures. Compression index and pseudo-preconsolidation pressure (PPC) were obtained. Unlike unfrozen soils, PPC is not associated with stress history. However, it is still the boundary of elastic and plastic deformations. Different compression indexes can be obtained from an individual compression curve under pressures before and after PPC. The parameters at different thermal and stress conditions were analyzed. It is found that temperature plays a critical role in mechanical behaviours of frozen soils. Efforts were then made on the silty-clay in order to suggest a convincing temperature boundary in defining warm frozen soil. Three groups of ice-rich samples with different ice contents were prepared and tested under confined compression. The samples were compressed under a constant load and with 5 stepped temperatures. Strain rates at different temperatures were examined. It was found that the strain rate at around -0.6°C increased abruptly. Analysis of compression index was performed on the data both from our own testing program and from the literature, which showed that at about -1°C was a turning point in the curves for compression index against temperature. Based on both our work and taking into account the unfrozen water content vs. temperature, the range of -1°C to -0.5°C seems to be the temperature where the mechanical properties change greatly. For convenience, -1.0°C can be defined as the boundary for warm frozen soils.
NASA Astrophysics Data System (ADS)
Gyergyek, T.; Kovačič, J.
2017-06-01
A one-dimensional, two-fluid, steady state model is used for the analysis of ion temperature effects to the plasma-wall transition. In this paper, the model is solved for a finite ratio ɛ between the Debye and the ionization length, while in Part II [T. Gyergyek and J. Kovačič, Phys Plasmas 24, 063506 (2017)], the solutions for ɛ = 0 are presented. Ion temperature is treated as a given, independent parameter and it is included in the model as a boundary condition. It is shown that when the ion temperature larger than zero is selected, the ion flow velocity and the electric field at the boundary must be consistent with the selected ion temperature. A numerical procedure, how to determine such "consistent boundary conditions," is proposed, and a simple relation between the ion temperature and ion velocity at the boundary of the system is found. The effects of the ion temperature to the pre-sheath length, potential, ion temperature, and ion density drops in the pre-sheath and in the sheath are investigated. It is concluded that larger ion temperature results in a better shielding of the plasma from the wall. An attempt is made to include the ion heat flux qi into the model in its simplest form q i = - K ' /d T i d x , where K ' is a constant heat conduction coefficient. It is shown that inclusion of such a term into the energy transfer equation introduces an additional ion heating mechanism into the system and the ion flow then becomes isothermal instead of adiabatic even in the sheath.
Gyergyek, T; Kovačič, J
2017-06-01
A one-dimensional, two-fluid, steady state model is used for the analysis of ion temperature effects to the plasma-wall transition. In this paper, the model is solved for a finite ratio ε between the Debye and the ionization length, while in Part II [T. Gyergyek and J. Kovačič, Phys Plasmas 24, 063506 (2017)], the solutions for [Formula: see text] are presented. Ion temperature is treated as a given, independent parameter and it is included in the model as a boundary condition. It is shown that when the ion temperature larger than zero is selected, the ion flow velocity and the electric field at the boundary must be consistent with the selected ion temperature. A numerical procedure, how to determine such "consistent boundary conditions," is proposed, and a simple relation between the ion temperature and ion velocity at the boundary of the system is found. The effects of the ion temperature to the pre-sheath length, potential, ion temperature, and ion density drops in the pre-sheath and in the sheath are investigated. It is concluded that larger ion temperature results in a better shielding of the plasma from the wall. An attempt is made to include the ion heat flux q i into the model in its simplest form [Formula: see text], where [Formula: see text] is a constant heat conduction coefficient. It is shown that inclusion of such a term into the energy transfer equation introduces an additional ion heating mechanism into the system and the ion flow then becomes isothermal instead of adiabatic even in the sheath.
Non-analyticity of holographic Rényi entropy in Lovelock gravity
NASA Astrophysics Data System (ADS)
Puletti, V. Giangreco M.; Pourhasan, Razieh
2017-08-01
We compute holographic Rényi entropies for spherical entangling surfaces on the boundary while considering third order Lovelock gravity with negative cosmological constant in the bulk. Our study shows that third order Lovelock black holes with hyperbolic event horizon are unstable, and at low temperatures those with smaller mass are favoured, giving rise to first order phase transitions in the bulk. We determine regions in the Lovelock parameter space in arbitrary dimensions, where bulk phase transitions happen and where boundary causality constraints are met. We show that each of these points corresponds to a dual boundary conformal field theory whose Rényi entropy exhibits a kink at a certain critical index n.
Entanglement entropy in a boundary impurity model.
Levine, G C
2004-12-31
Boundary impurities are known to dramatically alter certain bulk properties of (1+1)-dimensional strongly correlated systems. The entanglement entropy of a zero temperature Luttinger liquid bisected by a single impurity is computed using a novel finite size scaling or bosonization scheme. For a Luttinger liquid of length 2L and UV cutoff epsilon, the boundary impurity correction (deltaSimp) to the logarithmic entanglement entropy (Sent proportional, variant lnL/epsilon scales as deltaSimp approximately yrlnL/epsilon, where yr is the renormalized backscattering coupling constant. In this way, the entanglement entropy within a region is related to scattering through the region's boundary. In the repulsive case (g<1), deltaSimp diverges (negatively) suggesting that the entropy vanishes. Our results are consistent with the recent conjecture that entanglement entropy decreases irreversibly along renormalization group flow.
On the sensitivity of mesoscale models to surface-layer parameterization constants
NASA Astrophysics Data System (ADS)
Garratt, J. R.; Pielke, R. A.
1989-09-01
The Colorado State University standard mesoscale model is used to evaluate the sensitivity of one-dimensional (1D) and two-dimensional (2D) fields to differences in surface-layer parameterization “constants”. Such differences reflect the range in the published values of the von Karman constant, Monin-Obukhov stability functions and the temperature roughness length at the surface. The sensitivity of 1D boundary-layer structure, and 2D sea-breeze intensity, is generally less than that found in published comparisons related to turbulence closure schemes generally.
NASA Technical Reports Server (NTRS)
Dominguez, Anthony; Kleissl, Jan P.; Luvall, Jeffrey C.
2011-01-01
Large-eddy Simulation (LES) was used to study convective boundary layer (CBL) flow through suburban regions with both large and small scale heterogeneities in surface temperature. Constant remotely sensed surface temperatures were applied at the surface boundary at resolutions of 10 m, 90 m, 200 m, and 1 km. Increasing the surface resolution from 1 km to 200 m had the most significant impact on the mean and turbulent flow characteristics as the larger scale heterogeneities became resolved. While previous studies concluded that scales of heterogeneity much smaller than the CBL inversion height have little impact on the CBL characteristics, we found that further increasing the surface resolution (resolving smaller scale heterogeneities) results in an increase in mean surface heat flux, thermal blending height, and potential temperature profile. The results of this study will help to better inform sub-grid parameterization for meso-scale meteorological models. The simulation tool developed through this study (combining LES and high resolution remotely sensed surface conditions) is a significant step towards future studies on the micro-scale meteorology in urban areas.
Oxygen Permeability and Grain-Boundary Diffusion Applied to Alumina Scales
NASA Technical Reports Server (NTRS)
Smialek, James L.; Jacobson, Nathan S.; Gleeson, Brian; Hovis, David B.; Heuer, Arthur H.
2013-01-01
High-temperature oxygen permeability measurements had determined grain-boundary diffusivities (deltaD(sub gb)) in bulk polycrystalline alumina (Wada, Matsudaira, and Kitaoka). They predict that oxygen deltaD(sub gb,O) varies with oxygen pressure as P(O2)(sup -1/6) at low pressure whereas aluminum deltaD(sub gb),Al varies with P(O2)(sup +3/16) at high pressure. These relations were used to evaluate alumina scale growth in terms of diffusivity and grain size. A modified Wagner treatment for dominant inward oxygen growth produces the concise solution: ?(sub i) = k(sub p,i)×G(sub i) = 12 deltaD(sub gb,O,int), where ?(sub i) is a constant and k(sub p,i) and G(sub i) refer to instantaneous values of the scale parabolic growth constant and grain size, respectively. A commercial FeCrAl(Zr) alloy was oxidized at 1100 to 1400 degC to determine k(sub p,i), interfacial grain size, ?, and thus deltaD(sub gb,O,int). The deltaD(sub gb,O,int) values predicted from oxidation at (375 kJ/mole) were about 20 times less than those obtained above (at 298 kJ/mole), but closer than extrapolations from high-temperature bulk measurements. The experimental oxidation results agree with similar FeCrAl(X) studies, especially where both k(sub p,i) and G(sub i) were characterized. This complete approach accounts for temperature-sensitive oxidation effects of grain enlargement, equilibrium interface pressure variation, and grain-boundary diffusivity.
SEAWAT Version 4: A Computer Program for Simulation of Multi-Species Solute and Heat Transport
Langevin, Christian D.; Thorne, Daniel T.; Dausman, Alyssa M.; Sukop, Michael C.; Guo, Weixing
2008-01-01
The SEAWAT program is a coupled version of MODFLOW and MT3DMS designed to simulate three-dimensional, variable-density, saturated ground-water flow. Flexible equations were added to the program to allow fluid density to be calculated as a function of one or more MT3DMS species. Fluid density may also be calculated as a function of fluid pressure. The effect of fluid viscosity variations on ground-water flow was included as an option. Fluid viscosity can be calculated as a function of one or more MT3DMS species, and the program includes additional functions for representing the dependence on temperature. Although MT3DMS and SEAWAT are not explicitly designed to simulate heat transport, temperature can be simulated as one of the species by entering appropriate transport coefficients. For example, the process of heat conduction is mathematically analogous to Fickian diffusion. Heat conduction can be represented in SEAWAT by assigning a thermal diffusivity for the temperature species (instead of a molecular diffusion coefficient for a solute species). Heat exchange with the solid matrix can be treated in a similar manner by using the mathematically equivalent process of solute sorption. By combining flexible equations for fluid density and viscosity with multi-species transport, SEAWAT Version 4 represents variable-density ground-water flow coupled with multi-species solute and heat transport. SEAWAT Version 4 is based on MODFLOW-2000 and MT3DMS and retains all of the functionality of SEAWAT-2000. SEAWAT Version 4 also supports new simulation options for coupling flow and transport, and for representing constant-head boundaries. In previous versions of SEAWAT, the flow equation was solved for every transport timestep, regardless of whether or not there was a large change in fluid density. A new option was implemented in SEAWAT Version 4 that allows users to control how often the flow field is updated. New options were also implemented for representing constant-head boundaries with the Time-Variant Constant-Head (CHD) Package. These options allow for increased flexibility when using CHD flow boundaries with the zero-dispersive flux solute boundaries implemented by MT3DMS at constant-head cells. This report contains revised input instructions for the MT3DMS Dispersion (DSP) Package, Variable-Density Flow (VDF) Package, Viscosity (VSC) Package, and CHD Package. The report concludes with seven cases of an example problem designed to highlight many of the new features.
Transitional and turbulent flat-plate boundary layers with heat transfer
NASA Astrophysics Data System (ADS)
Wu, Xiaohua; Moin, Parviz
2010-11-01
We report on our direct numerical simulation of two incompressible, nominally zero-pressure-gradient flat-plate boundary layers from momentum thickness Reynolds number 80 to 1950. Heat transfer between the constant-temperature solid surface and the free-stream is also simulated with molecular Prandtl number=1. Throughout the entire flat-plate, the ratio of Stanton number and skin-friction St/Cfdeviates from the exact Reynolds analogy value of 0.5 by less than 1.5%. Turbulent Prandtl number t peaks at the wall. Preponderance of hairpin vortices is observed in both the transitional and turbulent regions of the boundary layers. In particular, the internal structure of merged turbulent spots is hairpin forest; the internal structure of infant turbulent spots is hairpin packet. Numerous hairpin vortices are readily detected in both the near-wall and outer regions of the boundary layers up to momentum thickness Reynolds number 1950. This suggests that the hairpin vortices in the turbulent region are not simply the aged hairpin forests convected from the upstream transitional region. Temperature iso-surfaces in the companion thermal boundary layers are found to be a useful tracer in identifying hairpin vortex structures.
Microstructure of Turbulence in the Stably Stratified Boundary Layer
NASA Astrophysics Data System (ADS)
Sorbjan, Zbigniew; Balsley, Ben B.
2008-11-01
The microstructure of a stably stratified boundary layer, with a significant low-level nocturnal jet, is investigated based on observations from the CASES-99 campaign in Kansas, U.S.A. The reported, high-resolution vertical profiles of the temperature, wind speed, wind direction, pressure, and the turbulent dissipation rate, were collected under nocturnal conditions on October 14, 1999, using the CIRES Tethered Lifting System. Two methods for evaluating instantaneous (1-sec) background profiles are applied to the raw data. The background potential temperature is calculated using the “bubble sort” algorithm to produce a monotonically increasing potential temperature with increasing height. Other scalar quantities are smoothed using a running vertical average. The behaviour of background flow, buoyant overturns, turbulent fluctuations, and their respective histograms are presented. Ratios of the considered length scales and the Ozmidov scale are nearly constant with height, a fact that can be applied in practice for estimating instantaneous profiles of the dissipation rate.
Modeling shock responses of plastic bonded explosives using material point method
NASA Astrophysics Data System (ADS)
Shang, Hailin; Zhao, Feng; Fu, Hua
2017-01-01
Shock responses of plastic bonded explosives are modeled using material point method as implemented in the Uintah Computational Framework. Two-dimensional simulation model was established based on the micrograph of PBX9501. Shock loading for the explosive was performed by a piston moving at a constant velocity. Unreactive simulation results indicate that under shock loading serious plastic strain appears on the boundary of HMX grains. Simultaneously, the plastic strain energy transforms to thermal energy, causing the temperature to rise rapidly on grain boundary areas. The influence of shock strength on the responses of explosive was also investigated by increasing the piston velocity. And the results show that with increasing shock strength, the distribution of plastic strain and temperature does not have significant changes, but their values increase obviously. Namely, the higher the shock strength is, the higher the temperature rise will be.
NASA Technical Reports Server (NTRS)
Frankl, F.; Voishel, V.
1943-01-01
In the present report an investigation is made on a flat plate in a two-dimensional compressible flow of the effect of compressibility and heating on the turbulent frictional drag coefficient in the boundary layer of an airfoil or wing radiator. The analysis is based on the Prandtl-Karman theory of the turbulent boundary later and the Stodola-Crocco, theorem on the linear relation between the total energy of the flow and its velocity. Formulas are obtained for the velocity distribution and the frictional drag law in a turbulent boundary later with the compressibility effect and heat transfer taken into account. It is found that with increase of compressibility and temperature at full retardation of the flow (the temperature when the velocity of the flow at a given point is reduced to zero in case of an adiabatic process in the gas) at a constant R (sub x), the frictional drag coefficient C (sub f) decreased, both of these factors acting in the same sense.
Kim, Seong K; Khodorov, Sergey; Chen, Chien-Ting; Kim, Sangtae; Lubomirsky, Igor
2013-06-14
A new model based on a linear diffusion equation is proposed to explain the current-voltage characteristics of blocking grain boundaries in Y-doped CeO2 in particular. One can also expect that the model can be applicable to the ionic conductors with blocking grain boundaries, in general. The model considers an infinitely long chain of identical grains separated by grain boundaries, which are treated as regions in which depletion layers of mobile ions are formed due to trapping of immobile charges that do not depend on the applied voltage as well as temperature. The model assumes that (1) the grain boundaries do not represent physical blocking layers, which implies that if there is a second phase at the grain boundaries, then it is too thin to impede ion diffusion and (2) the ions follow Boltzmann distribution throughout the materials. Despite its simplicity, the model successfully reproduces the "power law": current proportional to voltage power n and illustrated with the experimental example of Y-doped ceria. The model also correctly predicts that the product nT, where T is the temperature in K, is constant and is proportional to the grain boundary potential as long as the charge at the grain boundaries remains trapped. The latter allows its direct determination from the current-voltage characteristics and promises considerable simplification in the analysis of the electrical characteristics of the grain boundaries with respect to the models currently in use.
Glass transition temperature of polymer nano-composites with polymer and filler interactions
NASA Astrophysics Data System (ADS)
Hagita, Katsumi; Takano, Hiroshi; Doi, Masao; Morita, Hiroshi
2012-02-01
We systematically studied versatile coarse-grained model (bead spring model) to describe filled polymer nano-composites for coarse-grained (Kremer-Grest model) molecular dynamics simulations. This model consists of long polymers, crosslink, and fillers. We used the hollow structure as the filler to describe rigid spherical fillers with small computing costs. Our filler model consists of surface particles of icosahedra fullerene structure C320 and a repulsive force from the center of the filler is applied to the surface particles in order to make a sphere and rigid. The filler's diameter is 12 times of beads of the polymers. As the first test of our model, we study temperature dependence of volumes of periodic boundary conditions under constant pressures through NPT constant Andersen algorithm. It is found that Glass transition temperature (Tg) decrease with increasing filler's volume fraction for the case of repulsive interaction between polymer and fillers and Tg weakly increase for attractive interaction.
Mixed Convection Opposing Flow in a Vertical Porous Annulus-Two Temperature Model
NASA Astrophysics Data System (ADS)
Al-Rashed, Abdullah A. AA; J, Salman Ahmed N.; Khaleed, H. M. T.; Yunus Khan, T. M.; NazimAhamed, K. S.
2016-09-01
The opposing flow in a porous medium refers to a condition when the forcing velocity flows in opposite direction to thermal buoyancy obstructing the buoyant force. The present research refers to the effect of opposing flow in a vertical porous annulus embedded with fluid saturated porous medium. The thermal non-equilibrium approach with Darcy modal is considered. The boundary conditions are such that the inner radius is heated with constant temperature Tw the outer radius is maintained at constant temperature Tc. The coupled nonlinear partial differential equations such as momentum equation, energy equation for fluid and energy equation for solid are solved using the finite element method. The opposing flow variation of average Nusselt number with respect to radius ratio Rr, Aspect ratioAr and Radiation parameter Rd for different values of Peclet number Pe are investigated. It is found that the flow behavior is quite different from that of aiding flow.
Temperature dependent x-ray diffraction and dielectric studies of multiferroic GaFeO{sub 3}
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kumar, Rajeev; Mall, Ashish Kumar, E-mail: ashishm@iitk.ac.in; Gupta, Rajeev
2016-05-06
Polycrystalline GaFeO{sub 3} (GFO) samples were synthesized by sol-gel method. The structural and dielectric properties of GaFeO{sub 3} ceramic have been investigated by a combination of XRD and permittivity measurement. The X-ray diffraction spectra shows single phase orthorhombically distorted perovskite structure with Pc2{sub 1}n symmetry over a wide range of temperature 300 K to 600 K, with no evidence of any phase transition. Refined lattice parameters (a, b, c and V) increases with increasing temperature. Temperature dependent dielectric properties were investigated in the frequency range from 100Hz–5MHz. Impedance spectroscopy study on the sample showed that the dielectric constant and acmore » conductivity with frequency increases on increasing the temperature. Cole-Cole plots suggest that the response from grain is dominant at low temperature whereas grain boundary response overcomes as temperature increases. The relaxation activation energy (calculated from Cole-Cole plots) value is found to be 0.32 eV for the grain boundary. We believe that the oxygen ion vacancies play an important role in conduction processes at higher temperatures.« less
NASA Astrophysics Data System (ADS)
Hayat, T.; Muhammad, Taseer; Alsaedi, A.; Alhuthali, M. S.
2015-07-01
Magnetohydrodynamic (MHD) three-dimensional flow of couple stress nanofluid in the presence of thermophoresis and Brownian motion effects is analyzed. Energy equation subject to nonlinear thermal radiation is taken into account. The flow is generated by a bidirectional stretching surface. Fluid is electrically conducting in the presence of a constant applied magnetic field. The induced magnetic field is neglected for a small magnetic Reynolds number. Mathematical formulation is performed using boundary layer analysis. Newly proposed boundary condition requiring zero nanoparticle mass flux is employed. The governing nonlinear mathematical problems are first converted into dimensionless expressions and then solved for the series solutions of velocities, temperature and nanoparticles concentration. Convergence of the constructed solutions is verified. Effects of emerging parameters on the temperature and nanoparticles concentration are plotted and discussed. Skin friction coefficients and Nusselt number are also computed and analyzed. It is found that the thermal boundary layer thickness is an increasing function of radiative effect.
Development and Testing of DAVID: A Close-in EMP Coupling Code for Arbitrarily Shaped Objects
1975-11-07
5.OE-9 sec. (Ambient boundary condition, 0 = 0, Y - YAMAX ). 65 13 b. Approximate contours of constant Ex at T -5.8E-9 sec. (Ambient boundary...condition, 0 =0 Y -YMAX). 65 13 c. Appro<imate contours of constant Ex at T = 9.8E-9 sec. (Ambient boundary condition, 0 = 0 °, Y = YAMAX ). 66 13 d...Approximate contours of constant Ex at T 2.9E-8 sec. (Ambient boundary condition, 0% Y = YAMAX ). 66 - 14 a. Approximate contours of constant Ex at T = 9.8E-9
Autonomous Filling of Grain-Boundary Cavities during Creep Loading in Fe-Mo Alloys
NASA Astrophysics Data System (ADS)
Zhang, S.; Fang, H.; Gramsma, M. E.; Kwakernaak, C.; Sloof, W. G.; Tichelaar, F. D.; Kuzmina, M.; Herbig, M.; Raabe, D.; Brück, E.; van der Zwaag, S.; van Dijk, N. H.
2016-10-01
We have investigated the autonomous repair of creep damage by site-selective precipitation in a binary Fe-Mo alloy (6.2 wt pct Mo) during constant-stress creep tests at temperatures of 813 K, 823 K, and 838 K (540 °C, 550 °C, and 565 °C). Scanning electron microscopy studies on the morphology of the creep-failed samples reveal irregularly formed deposits that show a close spatial correlation with the creep cavities, indicating the filling of creep cavities at grain boundaries by precipitation of the Fe2Mo Laves phase. Complementary transmission electron microscopy and atom probe tomography have been used to characterize the precipitation mechanism and the segregation at grain boundaries in detail.
NASA Astrophysics Data System (ADS)
Mahajan, Sandeep; Haridas, Divya; Ali, S. T.; Munirathnam, N. R.; Sreenivas, K.; Thakur, O. P.; Prakash, Chandra
2014-10-01
In present study we have prepared ferroelectric BaZrxTi1-xO3 (x=0.05) ceramic by conventional solid state reaction route and studied its electrical properties as a function of temperature and frequency. X-ray diffraction (XRD) analysis shows single-phase formation of the compound with orthorhombic crystal structure at room temperature. Impedance and electric modulus spectroscopy analysis in the frequency range of 40 Hz-1 MHz at high temperature (200-600 °C) suggests two relaxation processes with different time constant are involved which are attributed to bulk and grain boundary effects. Frequency dependent dielectric plot at different temperature shows normal variation with frequency while dielectric loss (tanδ) peak was found to obey an Arrhenius law with activation energy of 1.02 eV. The frequency-dependent AC conductivity data were also analyzed in a wide temperature range. In present work we have studied the role of grain and grain boundaries on the electrical behaviour of Zr-doped BaTiO3 and their dependence on temperature and frequency by complex impedance and modulus spectroscopy (CIS) technique in a wide frequency (40 Hz-1 MHz) and high temperature range.
Observations of the Early Morning Boundary-Layer Transition with Small Remotely-Piloted Aircraft
NASA Astrophysics Data System (ADS)
Wildmann, Norman; Rau, Gerrit Anke; Bange, Jens
2015-12-01
A remotely-piloted aircraft (RPA), equipped with a high resolution thermodynamic sensor package, was used to investigate physical processes during the morning transition of the atmospheric boundary layer over land. Experiments were conducted at a test site in heterogeneous terrain in south-west Germany on 5 days from June to September 2013 in an evolving shallow convective boundary layer, which then developed into a well-mixed layer later in the day. A combination of vertical profiling and constant-altitude profiling (CAP) at 100 m height above ground level was chosen as the measuring strategy throughout the experiment. The combination of flight strategies allows the application of mixed-layer scaling using the boundary-layer height z_i, convective velocity scale w_* and convective temperature scale θ _*. The hypothesis that mixed-layer theory is valid during the whole transition was not confirmed for all parameters. A good agreement is found for temperature variances, especially in the upper half of the boundary layer, and the normalized heat-flux profile. The results were compared to a previous study with the helicopter-borne turbulence probe Helipod, and it was found that similar data quality can be achieved with the RPA. On all days, the CAP flight level was within the entrainment zone for a short time, and the horizontal variability of temperature and water vapour along the flight path is presented as an example of the inhomogeneity of layer interfaces in the boundary layer. The study serves as a case study of the possibilities and limitations with state-of-the-art RPA technology in micrometeorology.
Time-dependent boundary conditions for hyperbolic systems. II
NASA Technical Reports Server (NTRS)
Thompson, Kevin W.
1990-01-01
A general boundary condition formalism is developed for all types of boundary conditions to which hyperbolic systems are subject; the formalism makes possible a 'cookbook' approach to boundary conditions, by means of which novel boundary 'recipes' may be derived and previously devised ones may be consulted as required. Numerous useful conditions are derived for such CFD problems as subsonic and supersonic inflows and outflows, nonreflecting boundaries, force-free boundaries, constant pressure boundaries, and constant mass flux. Attention is given to the computation and integration of time derivatives.
Time-dependent boundary conditions for hyperbolic systems. II
NASA Astrophysics Data System (ADS)
Thompson, Kevin W.
1990-08-01
A general boundary condition formalism is developed for all types of boundary conditions to which hyperbolic systems are subject; the formalism makes possible a 'cookbook' approach to boundary conditions, by means of which novel boundary 'recipes' may be derived and previously devised ones may be consulted as required. Numerous useful conditions are derived for such CFD problems as subsonic and supersonic inflows and outflows, nonreflecting boundaries, force-free boundaries, constant pressure boundaries, and constant mass flux. Attention is given to the computation and integration of time derivatives.
Base Heating Sensitivity Study for a 4-Cluster Rocket Motor Configuration in Supersonic Freestream
NASA Technical Reports Server (NTRS)
Mehta, Manish; Canabal, Francisco; Tashakkor, Scott B.; Smith, Sheldon D.
2011-01-01
In support of launch vehicle base heating and pressure prediction efforts using the Loci-CHEM Navier-Stokes computational fluid dynamics solver, 35 numerical simulations of the NASA TND-1093 wind tunnel test have been modeled and analyzed. This test article is composed of four JP-4/LOX 500 lbf rocket motors exhausting into a Mach 2 - 3.5 wind tunnel at various ambient pressure conditions. These water-cooled motors are attached to a base plate of a standard missile forebody. We explore the base heating profiles for fully coupled finite-rate chemistry simulations, one-way coupled RAMP (Reacting And Multiphase Program using Method of Characteristics)-BLIMPJ (Boundary Layer Integral Matrix Program - Jet Version) derived solutions and variable and constant specific heat ratio frozen flow simulations. Variations in turbulence models, temperature boundary conditions and thermodynamic properties of the plume have been investigated at two ambient pressure conditions: 255 lb/sq ft (simulated low altitude) and 35 lb/sq ft (simulated high altitude). It is observed that the convective base heat flux and base temperature are most sensitive to the nozzle inner wall thermal boundary layer profile which is dependent on the wall temperature, boundary layer s specific energy and chemical reactions. Recovery shock dynamics and afterburning significantly influences convective base heating. Turbulence models and external nozzle wall thermal boundary layer profiles show less sensitivity to base heating characteristics. Base heating rates are validated for the highest fidelity solutions which show an agreement within +/-10% with respect to test data.
NASA Technical Reports Server (NTRS)
Basu, S.; Cetegen, B. M.
2005-01-01
An integral analysis of hydrodynamics and heat transfer in a thin liquid film flowing over a rotating disk surface is presented for both constant temperature and constant heat flux boundary conditions. The model is found to capture the correct trends of the liquid film thickness variation over the disk surface and compare reasonably well with experimental results over the range of Reynolds and Rossby numbers covering both inertia and rotation dominated regimes. Nusselt number variation over the disk surface shows two types of behavior. At low rotation rates, the Nusselt number exhibits a radial decay with Nusselt number magnitudes increasing with higher inlet Reynolds number for both constant wall temperature and heat flux cases. At high rotation rates, the Nusselt number profiles exhibit a peak whose location advances radially outward with increasing film Reynolds number or inertia. The results also compare favorably with the full numerical simulation results from an earlier study as well as with the reported experimental results.
Colossal dielectric behavior of semiconducting Sr2TiMnO6 ceramics
NASA Astrophysics Data System (ADS)
Meher, K. R. S. Preethi; Varma, K. B. R.
2009-02-01
Manganitelike double perovskite Sr2TiMnO6 (STMO) ceramics fabricated from the powders synthesized via the solid-state reaction route, exhibited dielectric constants as high as ˜105 in the low frequency range (100 Hz-10 kHz) at room temperature. The Maxwell-Wagner type of relaxation mechanism was found to be more appropriate to rationalize such high dielectric constant values akin to that observed in materials such as KxTiyNi(1-x-y)O and CaCu3Ti4O12. The dielectric measurements carried out on the samples with different thicknesses and electrode materials reflected the influence of extrinsic effects. The impedance studies (100 Hz-10 MHz) in the 180-300 K temperature range revealed the presence of two dielectric relaxations corresponding to the grain boundary and the electrode. The dielectric response of the grain boundary was found to be weakly dependent on the dc bias field (up to 11 V/cm). However, owing to the electrode polarization, the applied ac/dc field had significant effect on the low frequency dielectric response. At low temperatures (100-180 K), the dc conductivity of STMO followed a variable range hopping behavior. Above 180 K, it followed the Arrhenius behavior because of the thermally activated conduction process. The bulk conductivity relaxation owing to the localized hopping of charge carriers obeyed the typical universal dielectric response.
Oceanic lithosphere and asthenosphere - Thermal and mechanical structure
NASA Technical Reports Server (NTRS)
Schubert, G.; Yuen, D. A.; Froidevaux, C.
1976-01-01
A coupled thermomechanical subsolidus model of the oceanic lithosphere and asthenosphere is developed which includes vertical heat conduction, a temperature-dependent thermal conductivity, heat advection by a horizontal and vertical mass flow that depends on depth and age, contributions of viscous dissipation or shear heating, a linear or nonlinear deformation law relating shear stress and strain rate, as well as a temperature- and pressure-dependent viscosity. The model requires a constant horizontal velocity and temperature at the surface, but zero horizontal velocity and constant temperature at great depths. The depth- and age-dependent temperature, horizontal and vertical velocities, and viscosity structure of the lithosphere and asthenosphere are determined along with the age-dependent shear stress in those two zones. The ocean-floor topography, oceanic heat flow, and lithosphere thickness are deduced as functions of ocean-floor age; seismic velocity profiles which exhibit a marked low-velocity zone are constructed from the age-dependent geotherms and assumed values of the elastic parameters. It is found that simple boundary-layer cooling determines the thermal structure at young ages, while effects of viscous dissipation become more important at older ages.
Aspects of Turbulent / Non-Turbulent Interfaces
NASA Technical Reports Server (NTRS)
Bisset, D. K.; Hunt, J. C. R.; Rogers, M. M.; Koen, Dennis (Technical Monitor)
1999-01-01
A distinct boundary between turbulent and non-turbulent regions in a fluid of otherwise constant properties is found in many laboratory and engineering turbulent flows, including jets, mixing layers, boundary layers and wakes. Generally, the flow has mean shear in at least one direction within t he turbulent zone, but the non-turbulent zones have no shear (adjacent laminar shear is a different case, e.g. transition in a boundary layer). There may be purely passive differences between the turbulent and non-turbulent zones, e.g. small variations in temperature or scalar concentration, for which turbulent mixing is an important issue. The boundary has several major characteristics of interest for the present study. Firstly, the boundary advances into the non-turbulent fluid, or in other words, nonturbulent fluid is entrained. Secondly, the change in turbulence properties across the boundary is remarkably abrupt; strong turbulent motions come close to the nonturbulent fluid, promoting entrainment. Thirdly, the boundary is irregular with a continually changing convoluted shape, which produces statistical intermittency. Its shape is contorted at all scales of the turbulent motion.
Optical and dielectric properties of poly(vinyl-alcohol) - Cobalt oxide nanocomposite film
NASA Astrophysics Data System (ADS)
Das, Amit Kumar; Tripathi, Himadri Sekhar; Meikap, Ajit Kumar
2018-04-01
Highly crystalline cobalt oxide (Co3O4) have been synthesized via calcination method. The crystallite size of the nanoparticles is 28.5 nm. Two direct band gap of Co3O4 is observed. The temperature dependent dielectric spectroscopy of PVA-Co3O4 composite film shows ferroelectric behavior. The dielectric constant of the composite film is almost 2.5 times compare to pure PVA at a 1kHz frequency and room temperature. From the Nyquist plot grain and grain boundary effects are identified.
Long-time dynamic compatibility of elastomeric materials with hydrazine
NASA Technical Reports Server (NTRS)
Coulbert, C. D.; Cuddihy, E. F.; Fedors, R. F.
1973-01-01
The tensile property surfaces for two elastomeric materials, EPT-10 and AF-E-332, were generated in air and in liquid hydrazine environments using constant strain rate tensile tests over a range of temperatures and elongation rates. These results were used to predict the time-to-rupture for these materials in hydrazine as a function of temperature and amount of strain covering a span of operating times from less than a minute to twenty years. The results of limited sheet-folding tests and their relationship to the tensile failure boundary are presented and discussed.
NASA Astrophysics Data System (ADS)
Yuan, Ruihao; Xue, Deqing; Zhou, Yumei; Ding, Xiangdong; Sun, Jun; Xue, Dezhen
2017-07-01
We designed and synthesized a pseudo-binary Pb-free system, Ba(Ti0.7Zr0.3)O3-x(Ba0.82Ca0.18)TiO3, by combining a rhombohedral end (with only cubic to rhombohedral ferroelectric phase transition) and a tetragonal end (with only cubic to tetragonal ferroelectric phase transition). The established composition-temperature phase diagram is characterized by a tricritical point type morphotropic phase boundary (MPB), and the MPB composition has better ferroelectric, piezoelectric, and dielectric properties than the compositions deviating from MPB. Moreover, a full set of material constants (including elastic stiffness constants, elastic compliance constants, piezoelectric constants, dielectric constants, and electromechanical coupling factors) of the MPB composition are determined using a resonance method. The good piezoelectric performance of the MPB composition can be ascribed to the high dielectric constants, elastic softening, and large electromechanical coupling factor.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ahmad, Mohamad M., E-mail: mmohamad@kfu.edu.sa; Department of Physics, Faculty of Science, Assiut University in the New Valley, El-Kharga 72511; Yamada, Koji
2014-04-21
In the present work, CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) nanoceramics with different grain sizes were prepared by spark plasma sintering (SPS) at different temperatures (SPS-800, SPS-900, SPS-975, and SPS-1050) of the mechanosynthesized nano-powder. Structural and microstructural properties were studied by XRD and field-emission scanning electron microscope measurements. The grain size of CCTO nanoceramics increases from 80 nm to ∼200 nm for the ceramics sintered at 800 °C and 975 °C, respectively. Further increase of SPS temperature to 1050 °C leads to micro-sized ceramics of 2–3 μm. The electrical and dielectric properties of the investigated ceramics were studied by impedance spectroscopy. Giant dielectric constant was observed inmore » CCTO nanoceramics. The dielectric constant increases with increasing the grain size of the nanoceramics with values of 8.3 × 10{sup 3}, 2.4 × 10{sup 4}, and 3.2 × 10{sup 4} for SPS-800, SPS-900, and SPS-975, respectively. For the micro-sized SPS-1050 ceramics, the dielectric constant dropped to 2.14 × 10{sup 4}. The dielectric behavior is interpreted within the internal barrier layer capacitance picture due to the electrical inhomogeneity of the ceramics. Besides the resistive grain boundaries that are usually observed in CCTO ceramics, domain boundaries appear as a second source of internal layers in the current nanoceramics.« less
Effects of temperature distribution on boundary layer stability for a circular cone at Mach 10
NASA Astrophysics Data System (ADS)
Rigney, Jeffrey M.
A CFD analysis was conducted on a circular cone at 3 degrees angle of attack at Mach 10 using US3D and STABL 3D to determine the effect of wall temperature on the stability characteristics that lead to laminar-to-turbulent transition. Wall temperature distributions were manipulated while all other flow inputs and geometric qualities were held constant. Laminar-to-turbulent transition was analyzed for isothermal and adiabatic wall conditions, a simulated short-duration wind tunnel case, and several hot-nose temperature distributions. For this study, stability characteristics include maximum N-factor growth and the corresponding frequency range, disturbance spatial amplification rate and the corresponding modal frequency, and stability neutral point location. STABL 3D analysis indicates that temperature distributions typical of those in short-duration hypersonic wind tunnels do not result in any significant difference on the stability characteristics, as compared to an isothermal wall boundary condition. Hypothetical distributions of much greater temperatures at and past the nose tip do show a trend of dampening of second-mode disturbances, most notably on the leeward ray. The most pronounced differences existed between the isothermal and adiabatic cases.
NASA Astrophysics Data System (ADS)
Trautz, A.; Smits, K. M.; Illangasekare, T. H.; Schulte, P.
2014-12-01
The purpose of this study is to investigate the impacts of soil conditions (i.e. soil type, saturation) and atmospheric forcings (i.e. velocity, temperature, relative humidity) on the momentum, mass, and temperature boundary layers. The atmospheric conditions tested represent those typically found in semi-arid and arid climates and the soil conditions simulate the three stages of evaporation. The data generated will help identify the importance of different soil conditions and atmospheric forcings with respect to land-atmospheric interactions which will have direct implications on future numerical studies investigating the effects of turbulent air flow on evaporation. The experimental datasets generated for this study were performed using a unique climate controlled closed-circuit wind tunnel/porous media facility located at the Center for Experimental Study of Subsurface Environmental Processes (CESEP) at the Colorado School of Mines. The test apparatus consisting of a 7.3 m long porous media tank and wind tunnel, were outfitted with a sensor network to carefully measure wind velocity, air and soil temperature, relative humidity, soil moisture, and soil air pressure. Boundary layer measurements were made between the heights of 2 and 500 mm above the soil tank under constant conditions (i.e. wind velocity, temperature, relative humidity). The soil conditions (e.g. soil type, soil moisture) were varied between datasets to analyze their impact on the boundary layers. Experimental results show that the momentum boundary layer is very sensitive to the applied atmospheric conditions and soil conditions to a much less extent. Increases in velocity above porous media leads to momentum boundary layer thinning and closely reflect classical flat plate theory. The mass and thermal boundary layers are directly dependent on both atmospheric and soil conditions. Air pressure within the soil is independent of atmospheric temperature and relative humidity - wind velocity and soil moisture effects were observed. This data provides important insight into future work of accurately modeling the exchange processes associated with evaporation under various turbulent atmospheric conditions.
NASA Technical Reports Server (NTRS)
Houdeville, R.; Cousteix, J.
1979-01-01
The development of a turbulent unsteady boundary layer with a mean pressure gradient strong enough to induce separation, in order to complete the extend results obtained for the flat plate configuration is presented. The longitudinal component of the velocity is measured using constant temperature hot wire anemometer. The region where negative velocities exist is investigated with a laser Doppler velocimeter system with BRAGG cells. The boundary layer responds by forced pulsation to the perturbation of potential flow. The unsteady effects observed are very important. The average location of the zero skin friction point moves periodically at the perturbation frequency. Average velocity profiles from different instants in the cycle are compared. The existence of a logarithmic region enables a simple calculation of the maximum phase shift of the velocity in the boundary layer. An attempt of calculation by an integral method of boundary layer development is presented, up to the point where reverse flow starts appearing.
Investigation of electrical studies of spinel FeCo2O4 synthesized by sol-gel method
NASA Astrophysics Data System (ADS)
Lobo, Laurel Simon; Kalainathan, S.; Kumar, A. Ruban
2015-12-01
In this work, spinel FeCo2O4 is synthesized by sol-gel method using succinic acid as a chelating agent at 900 °C. The structural, spectroscopic and morphological characterization was carried out by using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy equipped with Energy Dispersive X-ray spectrometer (SEM-EDX). The M-H loop at room temperature confirms the ferromagnetic property of the sample. The frequency and temperature dependence of dielectric constant (εʹ) and dielectric loss (tan δ) shows the presence of Maxwell-Wagner relaxation in the sample due to the presence of oxygen vacancy. Nyquist plot for frequency and temperature domain signifies the presence of grain effect, grain boundary effect and electrode interface in the conduction process. Electric modulus under suppression of electrode polarization shows the grain and grain boundary effects. The electrode polarization is observed in the lower frequency range of the conductivity graph.
Methods for characterizing convective cryoprobe heat transfer in ultrasound gel phantoms.
Etheridge, Michael L; Choi, Jeunghwan; Ramadhyani, Satish; Bischof, John C
2013-02-01
While cryosurgery has proven capable in treating of a variety of conditions, it has met with some resistance among physicians, in part due to shortcomings in the ability to predict treatment outcomes. Here we attempt to address several key issues related to predictive modeling by demonstrating methods for accurately characterizing heat transfer from cryoprobes, report temperature dependent thermal properties for ultrasound gel (a convenient tissue phantom) down to cryogenic temperatures, and demonstrate the ability of convective exchange heat transfer boundary conditions to accurately describe freezing in the case of single and multiple interacting cryoprobe(s). Temperature dependent changes in the specific heat and thermal conductivity for ultrasound gel are reported down to -150 °C for the first time here and these data were used to accurately describe freezing in ultrasound gel in subsequent modeling. Freezing around a single and two interacting cryoprobe(s) was characterized in the ultrasound gel phantom by mapping the temperature in and around the "iceball" with carefully placed thermocouple arrays. These experimental data were fit with finite-element modeling in COMSOL Multiphysics, which was used to investigate the sensitivity and effectiveness of convective boundary conditions in describing heat transfer from the cryoprobes. Heat transfer at the probe tip was described in terms of a convective coefficient and the cryogen temperature. While model accuracy depended strongly on spatial (i.e., along the exchange surface) variation in the convective coefficient, it was much less sensitive to spatial and transient variations in the cryogen temperature parameter. The optimized fit, convective exchange conditions for the single-probe case also provided close agreement with the experimental data for the case of two interacting cryoprobes, suggesting that this basic characterization and modeling approach can be extended to accurately describe more complicated, multiprobe freezing geometries. Accurately characterizing cryoprobe behavior in phantoms requires detailed knowledge of the freezing medium's properties throughout the range of expected temperatures and an appropriate description of the heat transfer across the probe's exchange surfaces. Here we demonstrate that convective exchange boundary conditions provide an accurate and versatile description of heat transfer from cryoprobes, offering potential advantages over the traditional constant surface heat flux and constant surface temperature descriptions. In addition, although this study was conducted on Joule-Thomson type cryoprobes, the general methodologies should extend to any probe that is based on convective exchange with a cryogenic fluid.
NASA Technical Reports Server (NTRS)
Huron, Eric S.
1986-01-01
Directionally solidified (DS) MAR-M246+Hf was tested in tension and fatigue, at temperatures from 20 C to 1093 C. Tests were performed on (001) oriented specimens at strain rates of 50 % and 0.5 % per minute. In tension, the yield strength was constant up to 704 C, above which the strength dropped off rapidly. A strong dependence of strength on strain rate was seen at the higher temperatures. The deformation mode was observed to change from heterogeneous to homogeneous with increasing temperature. Low Cycle Fatigue tests were done using a fully reversed waveform and total strain control. For a given plastic strain range, lives increased with increasing temperature. For a given temperature strain rate had a strong effect on life. At 704 C, decreasing strain rates decreased life, while at the higher temperatures, decreasing strain rates increased life, for a given plastic strain range. These results could be explained through considerations of the deformation modes and stress levels. At the higher temperatures, marked coarsening caused beneficial stress reductions, but oxidation limited the life. The longitudinal grain boundaries were found to influence slip behavior. The degree of secondary slip adjacent to the boundaries was found to be related to the degree of misorientation between the grains.
Quantifying the effect of varying GHG's concentration in Regional Climate Models
NASA Astrophysics Data System (ADS)
López-Romero, Jose Maria; Jerez, Sonia; Palacios-Peña, Laura; José Gómez-Navarro, Juan; Jiménez-Guerrero, Pedro; Montavez, Juan Pedro
2017-04-01
Regional Climate Models (RCMs) are driven at the boundaries by Global Circulation Models (GCM), and in the particular case of Climate Change projections, such simulations are forced by varying greenhouse gases (GHGs) concentrations. In hindcast simulations driven by reanalysis products, the climate change signal is usually introduced in the assimilation process as well. An interesting question arising in this context is whether GHGs concentrations have to be varied within the RCMs model itself, or rather they should be kept constant. Some groups keep the GHGs concentrations constant under the assumption that information about climate change signal is given throughout the boundaries; sometimes certain radiation parameterization schemes do not permit such changes. Other approaches vary these concentrations arguing that this preserves the physical coherence respect to the driving conditions for the RCM. This work aims to shed light on this topic. For this task, various regional climate simulations with the WRF model for the 1954-2004 period have been carried out for using a Euro-CORDEX compliant domain. A series of simulations with constant and variable GHGs have been performed using both, a GCM (ECHAM6-OM) and a reanalysis product (ERA-20C) data. Results indicate that there exist noticeable differences when introducing varying GHGs concentrations within the RCM domain. The differences in 2-m temperature series between the experiments with varying or constant GHGs concentration strongly depend on the atmospheric conditions, appearing a strong interannual variability. This suggests that short-term experiments are not recommended if the aim is to assess the role of varying GHGs. In addition, and consistently in both GCM and reanalysis-driven experiments, the magnitude of temperature trends, as well as the spatial pattern represented by varying GHGs experiment, are closer to the driving dataset than in experiments keeping constant the GHGs concentration. These results point towards the need for the inclusion of varying GHGs concentration within the RCM itself when dynamically downscaling global datasets, both in GCM and hindcast simulations.
Temperature fluctuations in fully-developed turbulent channel flow with heated upper wall
NASA Astrophysics Data System (ADS)
Bahri, Carla; Mueller, Michael; Hultmark, Marcus
2013-11-01
The interactions and scaling differences between the velocity field and temperature field in a wall-bounded turbulent flow are investigated. In particular, a fully developed turbulent channel flow perturbed by a step change in the wall temperature is considered with a focus on the details of the developing thermal boundary layer. For this specific study, temperature acts as a passive scalar, having no dynamical effect on the flow. A combination of experimental investigation and direct numerical simulation (DNS) is presented. Velocity and temperature data are acquired with high accuracy where, the flow is allowed to reach a fully-developed state before encountering a heated upper wall at constant temperature. The experimental data is compared with DNS data where simulations of the same configuration are conducted.
Vallejo, Alba A; Velázquez, Jesús B; Fernández, Marta S
2007-10-01
The effect of the excitation or emission wavelengths on Laurdan generalized polarization (GP) can be evaluated by GPS, a quantitative, simplified determination of the GP spectrum slope, the thermotropic dependence of which allows the assessment of phospholipid lamellar membrane phase, as shown in a recent publication of our laboratory [J.B. Velázquez, M.S. Fernández, Arch. Biochem. Biophys. 455 (2006) 163-174]. In the present work, we applied Laurdan GPS to phase transition studies of mixed, two-phosphatidylcholine liposomes prepared from variable proportions of dimyristoyl- and dipalmitoylphosphatidylcholine (DMPC and DPPC, respectively). We have found that the GPS function reports a clear limit between the gel/liquid-crystalline phase coexistence region and the liquid-crystalline state, not only at a certain temperature T(c) for liposomes of constant composition submitted to temperature scans, but also at a defined mole fraction X(c), for two-component liposomes of variable composition at constant temperature. The T(c) or the X(c) values obtained from GPS vs. temperature or GPS vs. composition plots, respectively, allow the construction of a partial phase diagram for the DMPC-DPPC mixtures, showing the boundary between the two-phase coexisting region and the liquid-crystalline state. Likewise, at the onset of the transition region, i.e., the two-phase coexisting region as detected by GPS, it is possible to determine, although with less precision, a temperature T(o) or a mole fraction X(o) defining a boundary located below but near the limit between the gel and ripple phase, reported in the literature. These GPS results are consistent with the proposal by several authors that a fraction of L(alpha) phospholipids coexists with gel phospholipids in the rippled phase.
Heat Diffusion in Gases, Including Effects of Chemical Reaction
NASA Technical Reports Server (NTRS)
Hansen, C. Frederick
1960-01-01
The diffusion of heat through gases is treated where the coefficients of thermal conductivity and diffusivity are functions of temperature. The diffusivity is taken proportional to the integral of thermal conductivity, where the gas is ideal, and is considered constant over the temperature interval in which a chemical reaction occurs. The heat diffusion equation is then solved numerically for a semi-infinite gas medium with constant initial and boundary conditions. These solutions are in a dimensionless form applicable to gases in general, and they are used, along with measured shock velocity and heat flux through a shock reflecting surface, to evaluate the integral of thermal conductivity for air up to 5000 degrees Kelvin. This integral has the properties of a heat flux potential and replaces temperature as the dependent variable for problems of heat diffusion in media with variable coefficients. Examples are given in which the heat flux at the stagnation region of blunt hypersonic bodies is expressed in terms of this potential.
THE STUDY OF HIGH DIELECTRIC CONSTANT MECHANISM OF La-DOPED Ba0.67Sr0.33TiO3 CERAMICS
NASA Astrophysics Data System (ADS)
Xu, Jing; He, Bo; Liu, Han Xing
It is a common and effective method to enhance the dielectric properties of BST ceramics by adding rare-earth elements. In this paper, it is important to analyze the cause of the high dielectric constant behavior of La-doped BST ceramics. The results show that proper rare earth La dopant (0.2≤x≤0.7) may greatly increase the dielectric constant of BST ceramics, and also improve the temperature stability, evidently. According to the current-voltage (J-V) characteristics, the proper La-doped BST ceramics may reach the better semiconductivity, with the decrease and increase in La doping, the ceramics are insulators. By using the Schottky barrier model and electric microstructure model to find the surface or grain boundary potential barrier height, the width of the depletion layer and grain size do play an important role in impacting the dielectric constant.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bai, Xian-Ming; Zhang, Yongfeng; Tonks, Michael R.
2015-02-01
Strong thermal gradients in low-thermal-conductivity ceramics may drive extended defects, such as grain boundaries and voids, to migrate in preferential directions. In this work, molecular dynamics simulations are conducted to study thermal gradient driven grain boundary migration and to verify a previously proposed thermal gradient driving force equation, using uranium dioxide as a model system. It is found that a thermal gradient drives grain boundaries to migrate up the gradient and the migration velocity increases under a constant gradient owing to the increase in mobility with temperature. Different grain boundaries migrate at very different rates due to their different intrinsicmore » mobilities. The extracted mobilities from the thermal gradient driven simulations are compared with those calculated from two other well-established methods and good agreement between the three different methods is found, demonstrating that the theoretical equation of the thermal gradient driving force is valid, although a correction of one input parameter should be made. The discrepancy in the grain boundary mobilities between modeling and experiments is also discussed.« less
Hypersonic Boundary Layer Stability over a Flared Cone in a Quiet Tunnel
NASA Technical Reports Server (NTRS)
Lachowicz, Jason T.; Chokani, Ndaona; Wilkinson, Stephen P.
1996-01-01
Hypersonic boundary layer measurements were conducted over a flared cone in a quiet wind tunnel. The flared cone was tested at a freestream unit Reynolds number of 2.82x106/ft in a Mach 6 flow. This Reynolds number provided laminar-to-transitional flow over the model in a low-disturbance environment. Point measurements with a single hot wire using a novel constant voltage anemometry system were used to measure the boundary layer disturbances. Surface temperature and schlieren measurements were also conducted to characterize the laminar-to-transitional state of the boundary layer and to identify instability modes. Results suggest that the second mode disturbances were the most unstable and scaled with the boundary layer thickness. The integrated growth rates of the second mode compared well with linear stability theory in the linear stability regime. The second mode is responsible for transition onset despite the existence of a second mode sub-harmonic. The sub-harmonic wavelength also scales with the boundary layer thickness. Furthermore, the existence of higher harmonics of the fundamental suggests that non-linear disturbances are not associated with high free stream disturbance levels.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhai, Ziqing; Toloczko, Mychailo B.; Kruska, Karen
Long-term grain boundary (GB) damage evolution and stress corrosion crack initiation in alloy 690 are being investigated by constant load tensile testing in high-temperature, simulated PWR primary water. Six commercial alloy 690 heats are being tested in various cold work conditions loaded at their yield stress. This paper reviews the basic test approach and detailed characterizations performed on selected specimens after an exposure time of ~1 year. Intergranular crack nucleation was observed under constant stress in certain highly cold-worked (CW) alloy 690 heats and was found to be associated with the formation of GB cavities. Somewhat surprisingly, the heats mostmore » susceptible to cavity formation and crack nucleation were thermally treated materials with most uniform coverage of small GB carbides. Microstructure, % cold work and applied stress comparisons are made among the alloy 690 heats to better understand the factors influencing GB cavity formation and crack initiation.« less
National Aerospace Leadership Initiative - Phase I
2008-09-30
Devised and validated CFD code for operation of a micro-channel heat exchanger. The work was published at the 2008 AIAA Annual Meeting and Exposition...and (3) preparation to implement this algorithm in TURBO. Heat Transfer Capability In the short and medium term, the following plan has been adopted...to provide heat transfer capability to the TURBO code: • Incorporation of a constant wall temperature boundary condition. This capability will be
Numerical study on the thermo-chemically driven Geodynamo
NASA Astrophysics Data System (ADS)
Trümper, Tobias; Hansen, Ulrich
2014-05-01
In our numerical study we consider magneto-convection in the Earth's outer core driven by buoyancy induced by heterogeneities both in the thermal and the chemical field. The outer core is thus treated as a self-gravitating, rotating, spherical shell with unstable thermal and chemical gradients across its radius. The thermal gradient is maintained by secular cooling of the core and the release of latent heat at the inner core freezing front. Simultaneously, the concentration of the light constituents of the liquid phase increases at the inner core boundary since only a smaller fraction of the light elements can be incorporated during solidification. Thus, the inner core boundary constitutes a source of compositional buoyancy. The molecular diffusivities of the driving agents differ by some orders of magnitude so that a double-diffusive model is employed in order to study the flow dynamics of this system. We investigate the influence of different thermo-chemical driving scenarios on the structure of the flow and the internal magnetic field. A constant ratio of the diffusivities (Le=10) and a constant Ekman number (Ek=10-4) are adopted. Apart from testing different driving scenarios, the double-diffusive approach also allows to implement distinct boundary conditions on temperature and composition. Isochemical and fixed chemical flux boundary conditions are implemented in order to investigate their respective influence on the flow and magnetic field generation.
On the temperature prediction in a fire escape passage
NASA Astrophysics Data System (ADS)
Casano, G.; Piva, S.
2017-11-01
Fire safety engineering requires a detailed understanding of fire behaviour and of its effects on structures and people. Many factors may condition the fire scenario, as for example, heat transfer between the flame and the boundary structures. Currently advanced numerical codes for the prediction of the fire behaviour are available. However, these solutions often require heavy calculations and long times. In this context analytical solutions can be useful for a fast analysis of simplified schematizations. After that, it is more effective the final utilization of the advanced fire codes. In this contribution, the temperature in a fire escape passage, separated with a thermally resistant wall from a fire room, is analysed. The escape space is included in a building where the neighbouring rooms are at a constant undisturbed temperature. The presence of the neighbouring rooms is considered with an equivalent heat transfer coefficient, in a boundary condition of the third type. An analytical solution is used to predict the temperature distribution during the fire. It allows to obtain useful information on the temperature reached in the escape area in contact with a burning room; it is useful also for a fast choice of the thermal characteristics of a firewall.
NASA Technical Reports Server (NTRS)
Weilmuenster, K. J.
1974-01-01
Experimental measurements of boundary-layer transition in an expansion-tube test-gas flow are presented along with radial distributions of pitot pressure. An integral method for calculating constant Reynolds number lines for an expansion-tube flow is introduced. Comparison of experimental data and constant Reynolds number calculations has shown that for given conditions, wall boundary-layer transition occurs at a constant Reynolds number in an expansion-tube flow. Operating conditions in the expansion tube were chosen so that the effects of test-gas nonequilibrium on boundary-layer transition could be studied.
The upper critical field of filamentary Nb3Sn conductors
NASA Astrophysics Data System (ADS)
Godeke, A.; Jewell, M. C.; Fischer, C. M.; Squitieri, A. A.; Lee, P. J.; Larbalestier, D. C.
2005-05-01
We have examined the upper critical field of a large and representative set of present multifilamentary Nb3Sn wires and one bulk sample over a temperature range from 1.4 K up to the zero-field critical temperature. Since all present wires use a solid-state diffusion reaction to form the A15 layers, inhomogeneities with respect to Sn content are inevitable, in contrast to some previously studied homogeneous samples. Our study emphasizes the effects that these inevitable inhomogeneities have on the field-temperature phase boundary. The property inhomogeneities are extracted from field-dependent resistive transitions which we find broaden with increasing inhomogeneity. The upper 90%-99% of the transitions clearly separates alloyed and binary wires but a pure, Cu-free binary bulk sample also exhibits a zero-temperature critical field that is comparable to the ternary wires. The highest μ0Hc2 detected in the ternary wires are remarkably constant: The highest zero-temperature upper critical fields and zero-field critical temperatures fall within 29.5±0.3 and 17.8±0.3K, respectively, independent of the wire layout. The complete field-temperature phase boundary can be described very well with the relatively simple Maki-DeGennes model using a two-parameter fit, independent of composition, strain state, sample layout, or applied critical state criterion.
Numerical modeling of temperature and species distributions in hydrocarbon reservoirs
NASA Astrophysics Data System (ADS)
Bolton, Edward W.; Firoozabadi, Abbas
2014-01-01
We examine bulk fluid motion and diffusion of multicomponent hydrocarbon species in porous media in the context of nonequilibrium thermodynamics, with particular focus on the phenomenology induced by horizontal thermal gradients at the upper and lower horizontal boundaries. The problem is formulated with respect to the barycentric (mass-averaged) frame of reference. Thermally induced convection, with fully time-dependent temperature distributions, can lead to nearly constant hydrocarbon composition, with minor unmixing due to thermal gradients near the horizontal boundaries. Alternately, the composition can be vertically segregated due to gravitational effects. Independent and essentially steady solutions have been found to depend on how the compositions are initialized in space and may have implications for reservoir history. We also examine injection (to represent filling) and extraction (to represent leakage) of hydrocarbons at independent points and find a large distortion of the gas-oil contact for low permeability.
NASA Astrophysics Data System (ADS)
Mukherjee, Rupam; Garcia, Lucia; Lawes, Gavin; Nadgorny, Boris
2014-03-01
We have investigated the large dielectric enhancement at the percolation threshold by introducing metallic RuO2 grains into a matrix of CaCu3Ti4O12 (CCTO). The intrinsic response of the pure CCTO samples prepared by solid state and sol-gel processes results in a dielectric constant on the order of 104 and 103 respectively with low loss. Scanning electron microscopy and energy dispersive x-ray spectroscopy indicate that a difference in the thickness of the copper oxide enriched grain boundary is the main reason for the different dielectric properties between these two samples. Introducing RuO2 metallic fillers in these CCTO samples yields a sharp increase of the dielectric constant at percolation threshold fc, by a factor of 6 and 3 respectively. The temperature dependence of the dielectric constant shows that the dipolar relaxation plays an important role in enhancing dielectric constant in composite systems.
NASA Astrophysics Data System (ADS)
Majeski, Dick
2016-10-01
High edge electron temperatures (200 eV or greater) have been measured at the wall-limited plasma boundary in the Lithium Tokamak eXperiment (LTX). High edge temperatures, with flat electron temperature profiles, are a long-predicted consequence of low recycling boundary conditions. The temperature profile in LTX, measured by Thomson scattering, varies by as little as 10% from the plasma axis to the boundary, determined by the lithium-coated high field-side wall. The hydrogen plasma density in the outer scrape-off layer is very low, 2-3 x 1017 m-3 , consistent with a low recycling metallic lithium boundary. The plasma surface interaction in LTX is characterized by a low flux of high energy protons to the lithium PFC, with an estimated Debye sheath potential approaching 1 kV. Plasma-material interactions in LTX are consequently in a novel regime, where the impacting proton energy exceeds the peak in the sputtering yield for the lithium wall. In this regime, further increases in the edge temperature will decrease, rather than increase, the sputtering yield. Despite the high edge temperature, the core impurity content is low. Zeff is 1.2 - 1.5, with a very modest contribution (<0.1) from lithium. So far experiments are transient. Gas puffing is used to increase the plasma density. After gas injection stops, the discharge density is allowed to drop, and the edge is pumped by the low recycling lithium wall. An upgrade to LTX which includes a 35A, 20 kV neutral beam injector to provide core fueling to maintain constant density, as well as auxiliary heating, is underway. Two beam systems have been loaned to LTX by Tri Alpha Energy. Additional results from LTX, as well as progress on the upgrade - LTX- β - will be discussed. Work supported by US DOE contracts DE-AC02-09CH11466 and DE-AC05-00OR22725.
Chen, Juan; Cui, Baotong; Chen, YangQuan
2018-06-11
This paper presents a boundary feedback control design for a fractional reaction diffusion (FRD) system with a space-dependent (non-constant) diffusion coefficient via the backstepping method. The contribution of this paper is to generalize the results of backstepping-based boundary feedback control for a FRD system with a space-independent (constant) diffusion coefficient to the case of space-dependent diffusivity. For the boundary stabilization problem of this case, a designed integral transformation treats it as a problem of solving a hyperbolic partial differential equation (PDE) of transformation's kernel, then the well posedness of the kernel PDE is solved for the plant with non-constant diffusivity. Furthermore, by the fractional Lyapunov stability (Mittag-Leffler stability) theory and the backstepping-based boundary feedback controller, the Mittag-Leffler stability of the closed-loop FRD system with non-constant diffusivity is proved. Finally, an extensive numerical example for this closed-loop FRD system with non-constant diffusivity is presented to verify the effectiveness of our proposed controller. Copyright © 2018 ISA. Published by Elsevier Ltd. All rights reserved.
Sakiadis flow of Maxwell fluid considering magnetic field and convective boundary conditions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mustafa, M., E-mail: meraj-mm@hotmail.com; Khan, Junaid Ahmad; Hayat, T.
2015-02-15
In this paper we address the flow of Maxwell fluid due to constantly moving flat radiative surface with convective condition. The flow is under the influence of non-uniform transverse magnetic field. The velocity and temperature distributions have been evaluated numerically by shooting approach. The solution depends on various interesting parameters including local Deborah number De, magnetic field parameter M, Prandtl number Pr and Biot number Bi. We found that variation in velocity with an increase in local Deborah number De is non-monotonic. However temperature is a decreasing function of local Deborah number De.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ismail, Zulkhibri; Khan, Ilyas; Nasir, Nadirah Mohd
2015-02-03
An analysis of the exact solutions of second grade fluid problem for unsteady magnetohydrodynamic (MHD) flows past an infinite inclined plate in a porous medium is presented. It is assumed that the bounding infinite inclined plate has a constant temperature with radiation effects. Based on Boussinesq approximation the expressions for dimensionless velocity, temperature and concentration are obtained by using Laplace transform method. The derived solutions satisfying the involved differential equations, and all the boundary and initial conditions. The influence of various parameters on the velocity has been illustrated graphically and analyzed.
EFFECTS OF LASER RADIATION ON MATTER: Maximum depth of keyhole melting of metals by a laser beam
NASA Astrophysics Data System (ADS)
Pinsker, V. A.; Cherepanov, G. P.
1990-11-01
A calculation is reported of the maximum depth and diameter of a narrow crater formed in a stationary metal target exposed to high-power cw CO2 laser radiation. The energy needed for erosion of a unit volume is assumed to be constant and the energy losses experienced by the beam in the vapor-gas channel are ignored. The heat losses in the metal are allowed for by an analytic solution of the three-dimensional boundary-value heat-conduction problem of the temperature field in the vicinity of a thin but long crater with a constant temperature on its surface. An approximate solution of this problem by a method proposed earlier by one of the present authors was tested on a computer. The dimensions of the thin crater were found to be very different from those obtained earlier subject to a less rigorous allowance for the heat losses.
Room temperature magnetic and dielectric properties of cobalt doped CaCu3Ti4O12 ceramics
NASA Astrophysics Data System (ADS)
Mu, Chunhong; Song, Yuanqiang; Wang, Haibin; Wang, Xiaoning
2015-05-01
CaCu3Ti4-xCoxO12 (x = 0, 0.2, 0.4) ceramics were prepared by a conventional solid state reaction, and the effects of cobalt doping on the room temperature magnetic and dielectric properties were investigated. Both X-ray diffraction and energy dispersive X-ray spectroscopy confirmed the presence of Cu and Co rich phase at grain boundaries of Co-doped ceramics. Scanning electron microscopy micrographs of Co-doped samples showed a striking change from regular polyhedral particle type in pure CaCu3Ti4O12 (CCTO) to sheet-like grains with certain growth orientation. Undoped CaCu3Ti4O12 is well known for its colossal dielectric constant in a broad temperature and frequency range. The dielectric constant value was slightly changed by 5 at. % and 10 at. % Co doping, whereas the second relaxation process was clearly separated in low frequency region at room temperature. A multirelaxation mechanism was proposed to be the origin of the colossal dielectric constant. In addition, the permeability spectra measurements indicated Co-doped CCTO with good magnetic properties, showing the initial permeability (μ') as high as 5.5 and low magnetic loss (μ″ < 0.2) below 3 MHz. And the interesting ferromagnetic superexchange coupling in Co-doped CaCu3Ti4O12 was discussed.
Local patches of turbulent boundary layer behaviour in classical-state vertical natural convection
NASA Astrophysics Data System (ADS)
Ng, Chong Shen; Ooi, Andrew; Lohse, Detlef; Chung, Daniel
2016-11-01
We present evidence of local patches in vertical natural convection that are reminiscent of Prandtl-von Kármán turbulent boundary layers, for Rayleigh numbers 105-109 and Prandtl number 0.709. These local patches exist in the classical state, where boundary layers exhibit a laminar-like Prandtl-Blasius-Polhausen scaling at the global level, and are distinguished by regions dominated by high shear and low buoyancy flux. Within these patches, the locally averaged mean temperature profiles appear to obey a log-law with the universal constants of Yaglom (1979). We find that the local Nusselt number versus Rayleigh number scaling relation agrees with the logarithmically corrected power-law scaling predicted in the ultimate state of thermal convection, with an exponent consistent with Rayleigh-Bénard convection and Taylor-Couette flows. The local patches grow in size with increasing Rayleigh number, suggesting that the transition from the classical state to the ultimate state is characterised by increasingly larger patches of the turbulent boundary layers.
NASA Astrophysics Data System (ADS)
Zheng, Jun; Han, Xinyue; Wang, ZhenTao; Li, Changfeng; Zhang, Jiazhong
2017-06-01
For about a century, people have been trying to seek for a globally convergent and closed analytical solution (CAS) of the Blasius Equation (BE). In this paper, we proposed a formally satisfied solution which could be parametrically expressed by two power series. Some analytical results of the laminar boundary layer of a flat plate, that were not analytically given in former studies, e.g. the thickness of the boundary layer and higher order derivatives, could be obtained based on the solution. Besides, the heat transfer in the laminar boundary layer of a flat plate with constant temperature could also be analytically formulated. Especially, the solution of the singular situation with Prandtl number Pr=0, which seems impossible to be analyzed in prior studies, could be given analytically. The method for finding the CAS of Blasius equation was also utilized in the problem of the boundary layer regulation through wall injection and slip velocity on the wall surface.
Multiferroic properties of Indian natural ilmenite
NASA Astrophysics Data System (ADS)
Acharya, Truptimayee; Choudhary, R. N. P.
2017-03-01
In this communication, the main results and analysis of extensive studies of electric and magnetic characteristics (relative dielectric constant, tangent loss, electric polarization, electric transport, impedance, magnetic polarization and magneto-electric coupling coefficient) of Indian natural ilmenite (NI) have been presented. Preliminary structural analysis was studied by Rietveld refinement of room temperature XRD data, which suggests the rhombohedral crystal system of NI. Maxwell-Wagner mechanism was used to explain the nature of the frequency dependence of the relative dielectric constant. The impedance analysis reveals that below 270 °C, only the bulk contributes, whereas at higher temperature, both grain boundary and the bulk contribute to the resistive characteristics of the material. The magnitude of the depression angles of the semicircles in the Nyquist plot has been estimated. The correlated barrier hopping model has been used to explain the frequency dependence of ac conductivity of the material. The activation energy of the compound has been estimated using the temperature dependence of dc conductivity plot. The obtained polarization hysteresis loops manifest improper ferroelectric behavior of NI. The existence M-H hysteresis loop supports anti-ferromagnetism in the studied material. The magneto-electric voltage coupling coefficient is found to be 0.7 mV/cm Oe. Hence, other than dielectric constant, electric polarization, magnetization and magneto-electric studies support the existence of multiferroic properties in NI.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chen, B.C.J.; Sha, W.T.; Doria, M.L.
1980-11-01
The governing equations, i.e., conservation equations for mass, momentum, and energy, are solved as a boundary-value problem in space and an initial-value problem in time. BODYFIT-1FE code uses the technique of boundary-fitted coordinate systems where all the physical boundaries are transformed to be coincident with constant coordinate lines in the transformed space. By using this technique, one can prescribe boundary conditions accurately without interpolation. The transformed governing equations in terms of the boundary-fitted coordinates are then solved by using implicit cell-by-cell procedure with a choice of either central or upwind convective derivatives. It is a true benchmark rod-bundle code withoutmore » invoking any assumptions in the case of laminar flow. However, for turbulent flow, some empiricism must be employed due to the closure problem of turbulence modeling. The detailed velocity and temperature distributions calculated from the code can be used to benchmark and calibrate empirical coefficients employed in subchannel codes and porous-medium analyses.« less
NASA Astrophysics Data System (ADS)
Eliëns, I. S.; Ramos, F. B.; Xavier, J. C.; Pereira, R. G.
2016-05-01
We study the influence of reflective boundaries on time-dependent responses of one-dimensional quantum fluids at zero temperature beyond the low-energy approximation. Our analysis is based on an extension of effective mobile impurity models for nonlinear Luttinger liquids to the case of open boundary conditions. For integrable models, we show that boundary autocorrelations oscillate as a function of time with the same frequency as the corresponding bulk autocorrelations. This frequency can be identified as the band edge of elementary excitations. The amplitude of the oscillations decays as a power law with distinct exponents at the boundary and in the bulk, but boundary and bulk exponents are determined by the same coupling constant in the mobile impurity model. For nonintegrable models, we argue that the power-law decay of the oscillations is generic for autocorrelations in the bulk, but turns into an exponential decay at the boundary. Moreover, there is in general a nonuniversal shift of the boundary frequency in comparison with the band edge of bulk excitations. The predictions of our effective field theory are compared with numerical results obtained by time-dependent density matrix renormalization group (tDMRG) for both integrable and nonintegrable critical spin-S chains with S =1 /2 , 1, and 3 /2 .
NASA Astrophysics Data System (ADS)
Salje, Ekhard K. H.; Carpenter, Michael A.; Nataf, Guillaume F.; Picht, Gunnar; Webber, Kyle; Weerasinghe, Jeevaka; Lisenkov, S.; Bellaiche, L.
2013-01-01
The dynamic properties of elastic domain walls in BaTiO3 were investigated using resonance ultrasonic spectroscopy (RUS). The sequence of phase transitions is characterized by minima in the temperature dependence of RUS resonance frequencies and changes in Q factors (resonance damping). Damping is related to the friction of mobile twin boundaries (90° ferroelectric walls) and distorted polar nanoregions (PNRs) in the cubic phase. Damping is largest in the tetragonal phase of ceramic materials but very low in single crystals. Damping is also small in the low-temperature phases of the ceramic sample and slightly increases with decreasing temperature in the single crystal. The phase angle between the real and imaginary part of the dynamic response function changes drastically in the cubic and tetragonal phases and remains constant in the orthorhombic phase. Other phases show a moderate dependence of the phase angle on temperature showing systematic changes of twin microstructures. Mobile twin boundaries (or sections of twin boundaries such as kinks inside twin walls) contribute strongly to the energy dissipation of the forced oscillation while the reduction in effective modulus due to relaxing twin domains is weak. Single crystals and ceramics show strong precursor softening in the cubic phase related to polar nanoregions (PNRs). The effective modulus decreases when the transition point of the cubic-tetragonal transformation is approached from above. The precursor softening follows temperature dependence very similar to recent results from Brillouin scattering. Between the Burns temperature (≈586 K) and Tc at 405 K, we found a good fit of the squared RUS frequency [˜Δ (C11-C12)] to a Vogel-Fulcher process with an activation energy of ˜0.2 eV. Finally, some first-principles-based effective Hamiltonian computations were carried out in BaTiO3 single domains to explain some of these observations in terms of the dynamics of the soft mode and central mode.
Using Temperature Sensitive Paint Technology
NASA Technical Reports Server (NTRS)
Hamner, M. P.; Popernack, T. G., Jr.; Owens, L. R.; Wahls, R. A.
2002-01-01
New facilities and test techniques afford research aerodynamicists many opportunities to investigate complex aerodynamic phenomena. For example, NASA Langley Research Center's National Transonic Facility (NTF) can hold Mach number, Reynolds number, dynamic pressure, stagnation temperature and stagnation pressure constant during testing. This is important because the wing twist associated with model construction may mask important Reynolds number effects associated with the flight vehicle. Beyond this, the NTF's ability to vary Reynolds number allows for important research into the study of boundary layer transition. The capabilities of facilities such as the NTF coupled with test techniques such as temperature sensitive paint yield data that can be applied not only to vehicle design but also to validation of computational methods. Development of Luminescent Paint Technology for acquiring pressure and temperature measurements began in the mid-1980s. While pressure sensitive luminescent paints (PSP) were being developed to acquire data for aerodynamic performance and loads, temperature sensitive luminescent paints (TSP) have been used for a much broader range of applications. For example, TSP has been used to acquire surface temperature data to determine the heating due to rotating parts in various types of mechanical systems. It has been used to determine the heating pattern(s) on circuit boards. And, it has been used in boundary layer analysis and applied to the validation of full-scale flight performance predictions. That is, data acquired on the same model can be used to develop trends from off design to full scale flight Reynolds number, e.g. to show the progression of boundary layer transition. A discussion of issues related to successfully setting-up TSP tests and using TSP systems for boundary layer studies is included in this paper, as well as results from a variety of TSP tests. TSP images included in this paper are all grey-scale so that similar to pictures from sublimating chemical tests areas of laminar flow appear "lighter," or white, and areas of turbulent flow appear "darker."
Fe, Co, Ni: Electrical Resistivity Along their Melting Boundaries
NASA Astrophysics Data System (ADS)
Silber, R. E.; Ezenwa, I.; Secco, R.; Yong, W.
2017-12-01
Electrical resistivity of Fe, Co, and Ni was measured at pressures up to 11 GPa and temperatures into their liquid states in multi-anvil and cubic-anvil presses. Two thermocouples placed at opposite ends of the wire sample served as T probes as well as 4-wire resistance electrodes in a switched circuit. A polarity switch was also used to remove any bias associated with current flow and voltage measurement using thermocouple legs. Post experimental examination of recovered and sectioned samples was done using electron microprobe analyses to check for diffusion in our samples. The observed large jumps in resistivity at the high P melting T of each metal is consistent with its known P,T phase diagram and with post-run compositional analyses. The electrical resistivity behavior in these late transition metals as a function of increasing P and T shows expected trends consistent with 1atm data. Within the error of measurement, the resistivity values at the melting T at high P of Co and Ni appear to mimic their 1 atm value suggesting constant resistivity along the melting boundary. For liquid Fe, resistivity decreases along the melting boundary up to the triple point at 5.2 GPa, and then is nearly constant at higher pressures. The results are compared to prediction by Stacey and Loper (PEPI, 2007).
NASA Technical Reports Server (NTRS)
Penland, J. A.; Marcum, D. C., Jr.; Stack, S. H.
1983-01-01
Results are presented from two separate tests on the same blended wing-body hydrogen fueled transport model at a Mach number of about 8 and a range of Reynolds numbers (based on theoretical body length) of 0.597 x 10 to the 6th power to about 156.22 x 10 to the 6th power. Tests were made in conventional hypersonic blowdown tunnel and a hypersonic shock tunnel at angles of attack of -2 deg to about 8 deg, with an extensive study made at a constant angle of attack of 3 deg. The model boundary-layer flow varied from laminar at the lower Reynolds numbers to predominantly turbulent at the higher Reynolds numbers. Model wall temperatures and stream static temperatures varied widely between the two tests, particularly at the lower Reynolds numbers. These temperature differences resulted in marked variations of the axial-force coefficients between the two tests, due in part to the effects of induced pressure and viscous interaction variations. The normal-force coefficient was essentially independent of Reynolds number. Analysis of results utilized current theoretical computer programs and basic boundary-layer theory.
Konikow, Leonard F.; Sanford, W.E.; Campbell, P.J.
1997-01-01
In a solute-transport model, if a constant-concentration boundary condition is applied at a node in an active flow field, a solute flux can occur by both advective and dispersive processes. The potential for advective release is demonstrated by reexamining the Hydrologic Code Intercomparison (HYDROCOIN) project case 5 problem, which represents a salt dome overlain by a shallow groundwater system. The resulting flow field includes significant salinity and fluid density variations. Several independent teams simulated this problem using finite difference or finite element numerical models. We applied a method-of-characteristics model (MOCDENSE). The previous numerical implementations by HYDROCOIN teams of a constant-concentration boundary to represent salt release by lateral dispersion only (as stipulated in the original problem definition) was flawed because this boundary condition allows the release of salt into the flow field by both dispersion and advection. When the constant-concentration boundary is modified to allow salt release by dispersion only, significantly less salt is released into the flow field. The calculated brine distribution for case 5 depends very little on which numerical model is used, as long as the selected model is solving the proper equations. Instead, the accuracy of the solution depends strongly on the proper conceptualization of the problem, including the detailed design of the constant-concentration boundary condition. The importance and sensitivity to the manner of specification of this boundary does not appear to have been recognized previously in the analysis of this problem.
Application of the Remotely Piloted Aircraft (RPA) 'MASC' in Atmospheric Boundary Layer Research
NASA Astrophysics Data System (ADS)
Wildmann, Norman; Bange, Jens
2014-05-01
The remotely piloted aircraft (RPA) MASC (Multipurpose Airborne Sensor Carrier) was developed at the University of Tübingen in cooperation with the University of Stuttgart, University of Applied Sciences Ostwestfalen-Lippe and 'ROKE-Modelle'. Its purpose is the investigation of thermodynamic processes in the atmospheric boundary layer (ABL), including observations of temperature, humidity and wind profiles, as well as the measurement of turbulent heat, moisture and momentum fluxes. The aircraft is electrically powered, has a maximum wingspan of 3.40 m and a total weight of 5-8 kg, depending on battery- and payload. The standard meteorological payload consists of temperature sensors, a humidity sensor, a flow probe, an inertial measurement unit and a GNSS. In normal operation, the aircraft is automatically controlled by the ROCS (Research Onboard Computer System) autopilot to be able to fly predefined paths at constant altitude and airspeed. Since 2010 the system has been tested and improved intensively. In September 2012 first comparative tests could successfully be performed at the Lindenberg observatory of Germany's National Meteorological Service (DWD). In 2013, several campaigns were done with the system, including fundamental boundary layer research, wind energy meteorology and assistive measurements to aerosol investigations. The results of a series of morning transition experiments in summer 2013 will be presented to demonstrate the capabilities of the measurement system. On several convective days between May and September, vertical soundings were done to record the evolution of the ABL in the early morning, from about one hour after sunrise, until noon. In between the soundings, flight legs of up to 1 km length were performed to measure turbulent statistics and fluxes at a constant altitude. With the help of surface flux measurements of a sonic anemometer, methods of similarity theory could be applied to the RPA flux measurements to compare them to literature. The results show prospects and limitations of boundary layer research with a single RPA at the present state of the art.
NASA Technical Reports Server (NTRS)
Myers, Jerry G.; Hussey, Sam W.; Yee, Glenda F.; Kim, Jungho
2003-01-01
Investigations into single bubble pool boiling phenomena are often complicated by the difficulties in obtaining time and space resolved information in the bubble region. This usually occurs because the heaters and diagnostics used to measure heat transfer data are often on the order of, or larger than, the bubble characteristic length or region of influence. This has contributed to the development of many different and sometimes contradictory models of pool boiling phenomena and dominant heat transfer mechanisms. Recent investigations by Yaddanapyddi and Kim and Demiray and Kim have obtained time and space resolved heat transfer information at the bubble/heater interface under constant temperature conditions using a novel micro-heater array (10x10 array, each heater 100 microns on a side) that is semi-transparent and doubles as a measurement sensor. By using active feedback to maintain a state of constant temperature at the heater surface, they showed that the area of influence of bubbles generated in FC-72 was much smaller than predicted by standard models and that micro-conduction/micro-convection due to re-wetting dominated heat transfer effects. This study seeks to expand on the previous work by making time and space resolved measurements under bubbles nucleating on a micro-heater array operated under constant heat flux conditions. In the planned investigation, wall temperature measurements made under a single bubble nucleation site will be synchronized with high-speed video to allow analysis of the bubble energy removal from the wall.
Hypersonic Boundary Layer Stability Experiments in a Quiet Wind Tunnel with Bluntness Effects
NASA Technical Reports Server (NTRS)
Lachowicz, Jason T.; Chokani, Ndaona
1996-01-01
Hypersonic boundary layer measurements over a flared cone were conducted in a Mach 6 quiet wind tunnel at a freestream unit Reynolds number of 2.82 million/ft. This Reynolds number provided laminar-to-transitional flow over the cone model in a low-disturbance environment. Four interchangeable nose-tips, including a sharp-tip, were tested. Point measurements with a single hot-wire using a novel constant voltage anemometer were used to measure the boundary layer disturbances. Surface temperature and schlieren measurements were also conducted to characterize the transitional state of the boundary layer and to identify instability modes. Results suggest that second mode disturbances were the most unstable and scaled with the boundary layer thickness. The second mode integrated growth rates compared well with linear stability theory in the linear stability regime. The second mode is responsible for transition onset despite the existence of a second mode subharmonic. The subharmonic disturbance wavelength also scales with the boundary layer thickness. Furthermore, the existence of higher harmonics of the fundamental suggests that nonlinear disturbances are not associated with 'high' free stream disturbance levels. Nose-tip radii greater than 2.7% of the base radius completely stabilized the second mode.
NASA Astrophysics Data System (ADS)
Law, Richard
2015-04-01
Traced for ~ 1500 km along the foreland edge of the Himalaya from NW India to Bhutan published reports indicate a remarkable along-strike continuity of quartz recrystallization microstructures in the footwall and hanging wall to the Main Central Thrust (MCT). Recrystallization in Lesser Himalayan Series (LHS) rocks in the footwall to the MCT is dominated by grain boundary bulging (BLG) microstructures, while recrystallization in Greater Himalayan Series (GHS) rocks in the hanging wall is dominated by grain boundary migration microstructures that traced structurally upwards transition in to the anatectic core of the GHS. In foreland-positioned high-strain rocks adjacent to the MCT recrystallization is dominated by subgrain rotation (SGR) with transitional BLG-SGR and SGR-GBM microstructures being recorded at structural distances of up to a few hundred meters below and above the MCT, respectively. Correlation with available information on temperatures of metamorphism indicated by mineral phase equilibria and RSCM data suggests that recrystallization in the structural zones dominated by BLG, SGR and GBM occurred at temperatures of ~ 350-450, 450-550 and 550- > 650 °C, respectively. It should be kept in mind, however, that these temperatures are likely to be 'close-to-peak' temperatures of metamorphism, whereas penetrative shearing and recrystallization may have continued during cooling. The dominance of SGR along the more foreland-positioned exposures of the MCT intuitively suggests that shearing occurred under a relatively restricted range of deformation temperatures and strain rates. Plotting the 'close-to-peak' 450-500 °C temperatures of metamorphism indicated for SGR-dominated rocks located at up to a few hundred meters below/above the MCT on the quartz recrystallization map developed by Stipp et al. (2002) indicates 'ball-park' strain rates of ~ 10-13 to 10-10 sec-1. However, only strain rates slower than 10-12 sec-1 on the MCT are likely to be compatible with know convergence rates between the Indian and Asian plates. If shearing continued during retrograde cooling while remaining in the SGR field, then the recrystallization map suggests that a significant drop in deformation temperature (> ~75-100 °C) would result in a decrease in strain rate. In general, however, the presence of a single recrystallization microstructure traced over a large (regional scale) distance does not necessarily mean that deformation temperature (or strain rate) remains constant but could, for example, indicate that spatial variations in deformation temperature are compensated for by changes in strain rate, with grain-scale deformation remaining within a particular recrystallization regime. Constant stress conditions plot along a straight line in the 1/T versus log strain rate space used in the quartz recrystallization mechanism map. This suggests that the observed along-strike consistency of SGR-dominated recrystallization microstructures may indicate near to constant stress boundary conditions (albeit with varying temperatures and strain rates) prevailing along what are now the more foreland-positioned exposures of the MCT. Extrapolation of the Hirth et al. (2001) flow law suggests a flow stress of ~ 30-50 MPa based on the deformation temperatures and strain rates inferred for foreland-positioned exposures of the MCT, in agreement with flow stresses estimated from recrystallized quartz grain size data.
Nonlinear development and secondary instability of Gortler vortices in hypersonic flows
NASA Technical Reports Server (NTRS)
Fu, Yibin B.; Hall, Philip
1991-01-01
In a hypersonic boundary layer over a wall of variable curvature, the region most susceptible to Goertler vortices is the temperature adjustment layer over which the basic state temperature decreases monotonically to its free stream value. Except for a special wall curvature distribution, the evolution of Goertler vortices trapped in the temperature adjustment layer will in general be strongly affected by the boundary layer growth through the O(M sup 3/2) curvature of the basic state, where M is the free stream Mach number. Only when the local wavenumber becomes as large as of order M sup 3/8, do nonparallel effects become negligible in the determination of stability properties. In the latter case, Goertler vortices will be trapped in a thin layer of O(epsilon sup 1/2) thickness which is embedded in the temperature adjustment layer; here epsilon is the inverse of the local wavenumber. A weakly nonlinear theory is presented in which the initial nonlinear development of Goertler vortices in the neighborhood of the neutral position is studied and two coupled evolution equations are derived. From these, it can be determined whether the vortices are decaying or growing depending on the sign of a constant which is related to wall curvature and the basic state temperature.
NASA Technical Reports Server (NTRS)
Tripp, L. L.; Tamekuni, M.; Viswanathan, A. V.
1973-01-01
The use of the computer program BUCLASP3 is described. The code is intended for thermal stress and instability analyses of structures such as unidirectionally stiffened panels. There are two types of instability analyses that can be effected by PAINT; (1) thermal buckling, and (2) buckling due to a specified inplane biaxial loading. Any structure that has a constant cross section in one direction, that may be idealized as an assemblage of beam elements and laminated flat and curved plate strip-elements can be analyzed. The two parallel ends of the panel must be simply supported, whereas arbitrary elastic boundary conditions may be imposed along any one or both external longitudinal side. Any variation in the temperature rise (from ambient) through the cross section of a panel is considered in the analyses but it must be assumed that in the longitudinal direction the temperature field is constant. Load distributions for the externally applied inplane biaxial loads are similar in nature to the permissible temperature field.
NASA Astrophysics Data System (ADS)
Chattopadhyay, P.; Karim, B.; Guha Roy, S.
2013-12-01
The sub-band gap optical absorption in chemical bath deposited cadmium sulphide thin films annealed at different temperatures has been critically analyzed with special reference to Urbach relation. It has been found that the absorption co-efficient of the material in the sub-band gap region is nearly constant up to a certain critical value of the photon energy. However, as the photon energy exceeds the critical value, the absorption coefficient increases exponentially indicating the dominance of Urbach rule. The absorption coefficients in the constant absorption region and the Urbach region have been found to be sensitive to annealing temperature. A critical examination of the temperature dependence of the absorption coefficient indicates two different kinds of optical transitions to be operative in the sub-band gap region. After a careful analyses of SEM images, energy dispersive x-ray spectra, and the dc current-voltage characteristics, we conclude that the absorption spectra in the sub-band gap domain is possibly associated with optical transition processes involving deep levels and the grain boundary states of the material.
Mixed convection of magnetohydrodynamic nanofluids inside microtubes at constant wall temperature
NASA Astrophysics Data System (ADS)
Moshizi, S. A.; Zamani, M.; Hosseini, S. J.; Malvandi, A.
2017-05-01
Laminar fully developed mixed convection of magnetohydrodynamic nanofluids inside microtubes at a constant wall temperature (CWT) under the effects of a variable directional magnetic field is investigated numerically. Nanoparticles are assumed to have slip velocities relative to the base fluid owing to thermophoretic diffusion (temperature gradient driven force) and Brownian diffusion (concentration gradient driven force). The no-slip boundary condition is avoided at the fluid-solid mixture to assess the non-equilibrium region at the fluid-solid interface. A scale analysis is performed to estimate the relative significance of the pertaining parameters that should be included in the governing equations. After the effects of pertinent parameters on the pressure loss and heat transfer enhancement were considered, the figure of merit (FoM) is employed to evaluate and optimize the thermal performance of heat exchange equipment. The results indicate the optimum thermal performance is obtained when the thermophoresis overwhelms the Brownian diffusion, which is for larger nanoparticles. This enhancement boosts when the buoyancy force increases. In addition, increasing the magnetic field strength and slippage at the fluid-solid interface enhances the thermal performance.
1978-05-01
distribution unlimited. I REPORTS ":-- r , Prepared for ARNOLD ENGINEERING DEVELOPMENT CENTER/DOTR AiR FORCE SYSTEMS COMMAND ARNOLD AIR FORCE STATIONI...section and diffuser. The measurements used the JPL multlport measuring system , which simultaneously recorded the stag- nation temperature and...stagnation and static pressures were recorded by the data system . For. the experiments.at CIT, two techniques were employed. Within the first i00 cm from
Size effects on electrical properties of chemically grown zinc oxide nanoparticles
NASA Astrophysics Data System (ADS)
Rathod, K. N.; Joshi, Zalak; Dhruv, Davit; Gadani, Keval; Boricha, Hetal; Joshi, A. D.; Solanki, P. S.; Shah, N. A.
2018-03-01
In the present article, we study ZnO nanoparticles grown by cost effective sol–gel technique for various electrical properties. Structural studies performed by x-ray diffraction (XRD) revealed hexagonal unit cell phase with no observed impurities. Transmission electron microscopy (TEM) and particle size analyzer showed increased average particle size due to agglomeration effect with higher sintering. Dielectric constant (ε‧) decreases with increase in frequency because of the disability of dipoles to follow higher electric field. With higher sintering, dielectric constant reduced owing to the important role of increased formation of oxygen vacancy defects. Universal dielectric response (UDR) was verified by straight line fitting of log (fε‧) versus log (f) plots. All samples exhibit UDR behavior and with higher sintering more contribution from crystal cores. Impedance studies suggest an important role of boundary density while Cole–Cole (Z″ versus Z‧) plots have been studied for the relaxation behavior of the samples. Average normalized change (ANC) in impedance has been studied for all the samples wherein boundaries play an important role. Frequency dependent electrical conductivity has been understood on the basis of Jonscher’s universal power law. Jonscher’s law fits suggest that conduction of charge carrier is possible in the context of correlated barrier hopping (CBH) mechanism for lower temperature sintered sample while for higher temperature sintered ZnO samples, Maxwell–Wagner (M–W) relaxation process has been determined.
Three-dimensional, thermo-mechanical and dynamical analogue experiments of subduction: first results
NASA Astrophysics Data System (ADS)
Boutelier, D.; Oncken, O.
2008-12-01
We present a new analogue modeling technique developed to investigate the mechanics of the subduction process and the build-up of subduction orogenies. The model consists of a tank filled with water representing the asthenosphere and two lithospheric plates made of temperature-sensitive hydrocarbon compositional systems. These materials possess elasto-plastic properties allowing the scaling of thermal and mechanical processes. A conductive thermal gradient is imposed in the lithosphere prior to deformation. The temperature of the asthenosphere and model surface are imposed and controlled with an electric heater, two infrared ceramic heat emitters, two thermocouples and a thermo-regulator. This system allows an unobstructed view of the model surface, which is monitored using a stereoscopic particle image technique. This monitoring technique provides a precise quantification of the horizontal deformation and variations of elevation in the three-dimensional model. Convergence is imposed with a piston moving at a constant rate or pushing at a constant stress. The velocity is scaled using the dimensionless ratio of thermal conduction over advection. The experiments are first produced at a constant rate and the stress in the horizontal direction of the convergence is recorded. Then the experiment is reproduced with a constant stress boundary condition where the stress value is set to the averaged value obtained in the previous experiment. Therefore, an initial velocity allowing proper scaling of heat exchanges is obtained, but deformation in the model and spatial variations of parameters such as density or friction coefficient can produce variations of plate convergence velocity. This in turn impacts the strength of the model lithosphere because it changes the model thermal structure. In the first presented experiments the model lithosphere is one layer and the plate boundary is linear. The effects of variations of the subducting plate thickness, density and the lubrication of the interface between the plates are investigated.
The variability of atmospheric equivalent temperature for radar altimeter range correction
NASA Technical Reports Server (NTRS)
Liu, W. Timothy; Mock, Donald
1990-01-01
Two sets of data were used to test the validity of the presently used approximation for radar altimeter range correction due to atmospheric water vapor. The approximation includes an assumption of constant atmospheric equivalent temperature. The first data set includes monthly, three-dimensional, gridded temperature and humidity fields over global oceans for a 10-year period, and the second is comprised of daily or semidaily rawinsonde data at 17 island stations for a 7-year period. It is found that the standard method underestimates the variability of the equivalent temperature, and the approximation could introduce errors of 2 cm for monthly means. The equivalent temperature is found to have a strong meridional gradient, and the highest temporal variabilities are found over western boundary currents. The study affirms that the atmospheric water vapor is a good predictor for both the equivalent temperature and the range correction. A relation is proposed to reduce the error.
NASA Astrophysics Data System (ADS)
Wang, Wei; Huang, Jingyu; Murphy, Catherine; Cahill, David; University of Illinois At Urbana Champaign, Department of Materials Science; Engineering Team; Department Collaboration
2011-03-01
While heat transfer via phonons across solid-solid boundary has been a core field in condense matter physics for many years, vibrational energy transport across molecular layers has been less well elucidated. We heat rectangular-shaped gold nanocrystals (nanorods) with Ti-sapphire femtosecond pulsed laser at their longitudinal surface plasmon absorption wavelength to watch how their temperature evolves in picoseconds transient. We observed single exponential decay behavior, which suggests that the heat dissipation is only governed by a single interfacial conductance value. The ``RC'' time constant was 300ps, corresponding to a conductance value of 95MW/ m 2 K. This interfacial conductance value is also a function of ambient temperature since at temperatures as low as 80K, which are below the Debye temperature of organic layers, several phonon modes were quenched, which shut down the dominating channels that conduct heat at room temperature.
Cooling beyond the boundary value in supercritical fluids under vibration
NASA Astrophysics Data System (ADS)
Sharma, D.; Erriguible, A.; Amiroudine, S.
2017-12-01
Supercritical fluids when subjected to simultaneous quench and vibration have been known to cause various intriguing flow phenomena and instabilities depending on the relative direction of temperature gradient and vibration. Here we describe a surprising and interesting phenomenon wherein temperature in the fluid falls below the imposed boundary value when the walls are quenched and the direction of vibration is normal to the temperature gradient. We define these regions in the fluid as sink zones, because they act like sink for heat within the fluid domain. The formation of these zones is first explained using a one-dimensional (1D) analysis with acceleration in constant direction. Subsequently, the effect of various boundary conditions and the relative direction of the temperature gradient to acceleration are analyzed, highlighting the necessary conditions for the formation of sink zones. It is found that the effect of high compressibility and the action of self-weight (due to high acceleration) causes the temperature to change in the bulk besides the usual action of piston effect. This subsequently affects the overall temperature profile thereby leading to the formation of sink zones. Though the examined 1D cases differ from the current two-dimensional (2D) cases, owing to the direction of acceleration being normal as compared to parallel in case of former, the explanations pertaining to 1D cases are judiciously utilized to elucidate the formation of sink zones in 2D supercritical fluids subjected to thermal quench and vibrational acceleration. The appearance of sink zones is found to be dependent on several factors such as proximity to the critical point and acceleration. A surface three-dimensional plot illustrating the effect of these parameters on onset time of sink zones is presented to further substantiate these arguments.
Electrical Resistivity Measurement of Cu and Zn on the Pressure-Dependent Melting Boundary
NASA Astrophysics Data System (ADS)
Secco, R. A.; Ezenwa, I.; Yong, W.
2016-12-01
Understanding how the core cools through heat conduction and modelling the geodynamo requires knowledge of the thermal and electrical conductivity of solid and liquid Fe and its relevant alloys at high pressures. It has been proposed that electrical resistivity of a pure metal is constant along its P-dependent melting boundary (Stacey and Anderson, PEPI, 2001). If confirmed, this invariant behavior could serve as a practical tool for low P studies to assess electrical resistivity of Earth's core. Since Earth's inner core boundary (ICB) is a melting boundary of mainly Fe, measurements of electrical resistivity of Fe at the melting boundary, under any P, would serve as a proxy for the resistivity at the ICB. A revised treatment (Stacey and Loper, PEPI, 2007) accounted for s-d scattering in transition metals with unfilled d-bands and limited the proposal to metals with electrons of the same type in filled d-band metals. To test this proposal, we made high P, T measurements of electrical resistivity of d-band filled Cu and Zn in solid and liquid states. Experiments were carried out in a 1000 ton cubic anvil press up to 5 GPa and 300K above melting temperatures. Two thermocouples placed at opposite ends of the wire sample served as T probes as well as 4-wire resistance electrodes in a switched circuit. A polarity switch was used to remove any bias voltage measurement using thermocouple legs. Electron microprobe analyses were used to check the compositions of the recovered samples. The expected resistivity decrease with P and increase with T were found and comparisons with 1atm data are in very good agreement. Within the error of measurement, the resistivity values of Cu decrease along the melting boundary while Zn appears to support the hypothesis of constant resistivity along the melting boundary.
Analysis of the surface heat balance over the world ocean
NASA Technical Reports Server (NTRS)
Esbenson, S. K.
1981-01-01
The net surface heat fluxes over the global ocean for all calendar months were evaluated. To obtain a formula in the form Qs = Q2(T*A - Ts), where Qs is the net surface heat flux, Ts is the sea surface temperature, T*A is the apparent atmospheric equilibrium temperature, and Q2 is the proportionality constant. Here T*A and Q2, derived from the original heat flux formulas, are functions of the surface meteorological parameters (e.g., surface wind speed, air temperature, dew point, etc.) and the surface radiation parameters. This formulation of the net surface heat flux together with climatological atmospheric parameters provides a realistic and computationally efficient upper boundary condition for oceanic climate modeling.
Dielectric Properties of Tungsten Copper Barium Ceramic as Promising Colossal-Permittivity Material
NASA Astrophysics Data System (ADS)
Wang, Juanjuan; Chao, Xiaolian; Li, Guangzhao; Feng, Lajun; Zhao, Kang; Ning, Tiantian
2017-08-01
Ba(Cu0.5W0.5)O3 (BCW) ceramic has been fabricated and its dielectric properties investigated for use in energy-storage applications, revealing a very large dielectric constant (˜104) at 1 kHz. Moreover, the colossal-permittivity BCW ceramic exhibited fine microstructure and optimal temperature stability over a wide temperature range from room temperature to 500°C. The internal barrier layer capacitor mechanism was considered to be responsible for its high dielectric properties. Based on activation values, it is concluded that doubly ionized oxygen vacancies make a substantial contribution to the conduction and relaxation behaviors at grain boundaries. This study suggests that this kind of material has potential for use in high-density energy storage applications.
Computer programs for thermodynamic and transport properties of hydrogen (tabcode-II)
NASA Technical Reports Server (NTRS)
Roder, H. M.; Mccarty, R. D.; Hall, W. J.
1972-01-01
The thermodynamic and transport properties of para and equilibrium hydrogen have been programmed into a series of computer routines. Input variables are the pair's pressure-temperature and pressure-enthalpy. The programs cover the range from 1 to 5000 psia with temperatures from the triple point to 6000 R or enthalpies from minus 130 BTU/lb to 25,000 BTU/lb. Output variables are enthalpy or temperature, density, entropy, thermal conductivity, viscosity, at constant volume, the heat capacity ratio, and a heat transfer parameter. Property values on the liquid and vapor boundaries are conveniently obtained through two small routines. The programs achieve high speed by using linear interpolation in a grid of precomputed points which define the surface of the property returned.
Stoica, G. M.; Stoica, A. D.; Miller, M. K.; ...
2014-10-10
Nanostructured ferritic alloys (NFA) are a new class of ultrafine-grained oxide dispersion-strengthened steels, promising for service in extreme environments of high temperature and high irradiation in the next-generation of nuclear reactors. This is owing to the remarkable stability of their complex microstructures containing a high density of Y-Ti-O nanoclusters within grains and along the grain boundaries. While nanoclusters have been recognized to be the primary contributor to the exceptional resistance to irradiation and high-temperature creep, very little is known about the mechanical roles of the polycrystalline grains that constitute the bulk ferritic matrix. Here we report the mesoscale characterization ofmore » anisotropic responses of the ultrafine NFA grains to tensile stresses at various temperatures using the state-of-the-art in situ neutron diffraction. We show the first experimental determination of temperature-dependent single-crystal elastic constants for the NFA, and reveal a strong temperature-dependent elastic anisotropy due to a sharp decrease in the shear stiffness constant [c'=(c_11-c_12)/2] when a critical temperature ( T_c ) is approached, indicative of elastic softening and instability of the ferritic matrix. We also show, from anisotropy-induced intergranular strain/stress accumulations, that a common dislocation slip mechanism operates at the onset of yielding for low temperatures, while there is a deformation crossover from low-temperature lattice hardening to high temperature lattice softening in response to extensive plastic deformation.« less
NASA Astrophysics Data System (ADS)
Ramzan, M.; Bilal, M.; Kanwal, Shamsa; Chung, Jae Dong
2017-06-01
Present analysis discusses the boundary layer flow of Eyring Powell nanofluid past a constantly moving surface under the influence of nonlinear thermal radiation. Heat and mass transfer mechanisms are examined under the physically suitable convective boundary condition. Effects of variable thermal conductivity and chemical reaction are also considered. Series solutions of all involved distributions using Homotopy Analysis method (HAM) are obtained. Impacts of dominating embedded flow parameters are discussed through graphical illustrations. It is observed that thermal radiation parameter shows increasing tendency in relation to temperature profile. However, chemical reaction parameter exhibits decreasing behavior versus concentration distribution. Supported by the World Class 300 Project (No. S2367878) of the SMBA (Korea)
NASA Astrophysics Data System (ADS)
Fan, Longlong; Chen, Jun; Ren, Yang; Pan, Zhao; Zhang, Linxing; Xing, Xianran
2016-01-01
The origin of the excellent piezoelectric properties at the morphotropic phase boundary is generally attributed to the existence of a monoclinic phase in various piezoelectric systems. However, there exist no experimental studies that reveal the role of the monoclinic phase in the piezoelectric behavior in phase-pure ceramics. In this work, a single monoclinic phase has been identified in Pb (Zr ,Ti )O3 ceramics at room temperature by in situ high-energy synchrotron x-ray diffraction, and its response to electric field has been characterized for the first time. Unique piezoelectric properties of the monoclinic phase in terms of large intrinsic lattice strain and negligible domain switching have been observed. The extensional strain constant d33 and the transverse strain constant d31 are calculated to be 520 and -200 pm /V , respectively. These large piezoelectric coefficients are mainly due to the large intrinsic lattice strain, with very little extrinsic contribution from domain switching. The unique properties of the monoclinic phase provide new insights into the mechanisms responsible for the piezoelectric properties at the morphotropic phase boundary.
On the choice of boundary conditions in continuum models of continental deformation
NASA Technical Reports Server (NTRS)
Wdowinski, Shimon; O'Connell, Richard J.
1990-01-01
Recent studies of continental deformation have treated the lithosphere as a viscous medium and investigated the time evolution of the deformation caused by tectonic and buoyancy forces. This paper examines the differences between (1) continuum models that keep velocity boundary conditions constant with time and (2) models that keep stress boundary conditions constant with time. These differences are demonstrated by using a simple example of a continental lithosphere that is subjected to horizontal compression. The results show that in (2) the indentation velocity decreases with time, while in (1) the indentation velocity remains constant with time.
NASA Astrophysics Data System (ADS)
Gibanov, Nikita S.; Sheremet, Mikhail A.; Oztop, Hakan F.; Al-Salem, Khaled
2018-04-01
In this study, natural convection combined with entropy generation of Fe3O4-water nanofluid within a square open cavity filled with two different porous blocks under the influence of uniform horizontal magnetic field is numerically studied. Porous blocks of different thermal properties, permeability and porosity are located on the bottom wall. The bottom wall of the cavity is kept at hot temperature Th, while upper open boundary is at constant cold temperature Tc and other walls of the cavity are supposed to be adiabatic. Governing equations with corresponding boundary conditions formulated in dimensionless stream function and vorticity using Brinkman-extended Darcy model for porous blocks have been solved numerically using finite difference method. Numerical analysis has been carried out for wide ranges of Hartmann number, nanoparticles volume fraction and length of the porous blocks. It has been found that an addition of spherical ferric oxide nanoparticles can order the flow structures inside the cavity.
NASA Technical Reports Server (NTRS)
Sears, B.; Narayanan, R.; Anderson, T. J.; Fripp, A. L.
1992-01-01
An electrochemical titration method was used to investigate the dynamic states in a cylindrical layer of convecting tin. The liquid tin was contained in a cell, with curved boundaries made of quartz and flat boundaries made of a solid state electrolyte - yttria-stabilized zirconia (YSZ). The electrolyte acted as a window through which a trace amount of oxygen could be pumped in or out by the application of a constant voltage. The concentration at the YSZ interface was monitored by operating the electrochemical cell in the galvanic mode. Experimentally determined effective diffusivities of oxygen were compared with the molecular diffusivity. Dynamic states in the convective flow were thus inferred. Temperature measurements were simultaneously made in order to identify the onset of oscillations from a steady convective regime. The experiments were conducted for two different aspect ratios for various imposed temperature gradients and two different orientations with respect to gravity. Transcritical states were identified and comparison to two-dimensional numerical models were made.
Modelling the baroclinic circulation with tidal components in the Adriatic Sea
NASA Astrophysics Data System (ADS)
Guarnieri, A.; Pinardi, N.; Oddo, P.; Bortoluzzi, G.; Ravaioli, M.
2012-04-01
The impact of tides in the circulation of the Adriatic sea has been investigated by means of a nested baroclinic numerical ocean model. Tides have been introduced using a modified Flather boundary condition at the open side of the domain. The results show that tidal amplitudes and phases are reproduced correctly by the baroclinic model and the tidal harmonic constants errors are comparable with those resulting from the most consolidated barotropic models. Numerical experiments were conducted to estimate and assess the impact of (i) the modified Flather lateral boundary condition, (ii) the tides on temperature, salinity and stratification structures in the basin, and (iii) the tides on mixing and circulation in general. Tides induce a different momentum advective component in the basin which in turn produces a different distribution of water masses in the basin. Tides impact on mixing and stratification in the Po river region (north-western Adriatic) and induce fluctuations of salinity and temperature on semidiurnal frequencies in all seasons for the first and only winter for the second.
NASA Astrophysics Data System (ADS)
Ismail, M. A.; Mohamad, N. F.; Ilias, M. R.; Shafie, S.
2017-09-01
Magnetohydrodynamic (MHD) effect is a study on motion of electrical-conducting fluid under magnetic fields. This effect has great intention due to its applications such as design of heat exchanger and nuclear reactor. In the problem in fluid motion, flow of separation can reduced the effectiveness of the system as well as can increased the energy lost. This study will present the results on reducing the flow separation by considering magnetic effect. In this study, unsteady mixed convection boundary layer flow past a circular cylinder is given attention. Focus of study is on the separation times that affected by the magnetic fields. The mathematical models in the form of partial differential equations are transformed into nonlinear coupled ordinary differential equations and solved numerically using an implicit finite-difference scheme known as Keller-box method. The effect of magnetic parameter on velocity and temperature profiles as well as skin friction and Nusselt number are studied.
NASA Technical Reports Server (NTRS)
Throckmorton, D. A.
1976-01-01
An experimental investigation is presented that was performed to determine the effect of a surface-to-gap wall temperature discontinuity on the heat transfer within space shuttle, reusable surface insulation, tile gaps submerged in a thick turbulent boundary layer. Heat-transfer measurements were obtained on a flat-plate, single-gap model submerged in a turbulent tunnel wall boundary layer at a nominal free-stream Mach number of 10.3 and free-stream Reynolds numbers per meter of 1.5 million, 3.3 million and 7.8 million. Surface-to-gap wall temperature discontinuities of varying degree were created by heating the surface of the model upstream of the instrumented gap. The sweep angle of the gap was varied between 0 deg and 60 deg; gap width and depth were held constant. A surface-to-gap wall temperature discontinuity (surface temperature greater than gap wall temperature) results in increased heat transfer to the near-surface portion of the gap, as compared with the heat transfer under isothermal conditions, while decreasing the heat transfer to the deeper portions of the gap. The nondimensionalized heat transfer to the near-surface portion of the gap is shown to decrease with increasing Reynolds number; in the deeper portion of the gap, the heat transfer increases with Reynolds number.
NASA Astrophysics Data System (ADS)
Ye, Yin; Yu, Shuhui; Huang, Haitao; Zhou, Limin
2007-07-01
Polyethylene glycol (PEG)-assisted solid state reaction route is employed to prepare the relaxor-type ferroelectric powders and ceramics of (1-x)Pb(Ni 1/3Nb 2/3)O 3-xPbTiO 3 (PNN-PT) with the morphotropic phase boundary (MPB) composition at x=0.36 (0.64PNN-0.36PT). PEG additive with the molecular weight of 200 is introduced into PNN-PT oxide precursors in order to obtain the perovskite phase. The XRD and TG/DSC results demonstrate that the interactions between PbO and PEG favor the transformation from the lead-rich pyrochlore to the lead-deficient pyrochlore, thus facilitating the formation of the perovskite. Consequently, nearly pure perovskite 0.64PNN-0.36PT powders are synthesized at a relatively low temperature of 850 °C. A significant improvement of electric properties of the ceramics sintered at 1200 °C is achieved by PEG modification. The dielectric constant at room temperature and the maximum dielectric constant at T c reach 4987 and 24307, respectively, at a frequency of 1 kHz. The piezoelectric constant d 33 is 460 pC/N.
NASA Astrophysics Data System (ADS)
Podpirka, Adrian; Ramanathan, Shriram
2011-01-01
We have successfully synthesized the colossal dielectric constant oxide La2-xSrxNiO4 in thin film form by reactive cosputtering from metallic targets and careful annealing protocols. Composition and phase purity was determined through energy dispersive spectra and x-ray diffraction, respectively. The dielectric constant exceeds values of over 20 000 up to 1 kHz and the activation energy for the frequency-independent conductivity plateau was extracted to be approximately 155 meV from 300 to 473 K, both in agreement with measurements conducted on bulk single crystals. However, unlike in single crystals, we observe early onset of relaxation in thin films indicating the crucial role of grain boundaries in influencing the dielectric response. ac conductivity at varying temperatures is analyzed within the framework of the universal dielectric law leading to an exponent of approximately 0.3, dependent on the electrode material. Impedance spectroscopy with electrodes of different work function (Pt, Pd, and Ag) was further carried out as a function of temperature and applied bias to provide mechanistic insights into the nature of the dielectric response.
Energy storage properties of Dy3+ doped Sr0.5Ba0.5Nb2O6 thick film with nano-size grains
NASA Astrophysics Data System (ADS)
Yang, Daeyeol; Kang, Soo-Bin; Lim, Ji-Ho; Yoon, Songhyeon; Ryu, Jungho; Choi, Jong-Jin; Velayutham, Thamil Selvi; Kim, Hyungsun; Jeong, Dae-Yong
2017-09-01
We studied the temperature stable high-energy storage capacitors. Sr0.5Ba0.5Nb2O6 (SBN) is the lead-free ferroelectric solid solution between BaNb2O6 and SrNb2O6. By doping Dy into SBN, the Curie temperature was lowered and dielectric constant was increased. To improve the breakdown behavior of Dy-doped SBN, the aerosoldeposition(AD) was applied to fabricate the dense films with nano-sized grains. These nano-grain give a large number of grain boundaries, suppressing the electron conduction in ceramics. The dielectric constant and breakdown electric field of the AD films annealed at 650 °C were measured as 2307 and 9.9 MV/m, while bulk were 1080 and 4 MV/m. Energy density and efficiency of the AD films annealed at 650 °C were also enhanced as 0.65 J/cc and 90.2% and bulk were 0.08 J/cc and 72.1%, respectively. In addition, the dielectric constant of AD film annealed at 550 °C and 650 °C were quite stable up to 150 °C.
NASA Astrophysics Data System (ADS)
Huck, Thierry; Vallis, Geoffrey K.
2001-08-01
What can we learn from performing a linear stability analysis of the large-scale ocean circulation? Can we predict from the basic state the occurrence of interdecadal oscillations, such as might be found in a forward integration of the full equations of motion? If so, do the structure and period of the linearly unstable modes resemble those found in a forward integration? We pursue here a preliminary study of these questions for a case in idealized geometry, in which the full nonlinear behavior can also be explored through forward integrations. Specifically, we perform a three-dimensional linear stability analysis of the thermally-driven circulation of the planetary geostrophic equations. We examine the resulting eigenvalues and eigenfunctions, comparing them with the structure of the interdecadal oscillations found in the fully nonlinear model in various parameter regimes. We obtain a steady state by running the time-dependent, nonlinear model to equilibrium using restoring boundary conditions on surface temperature. If the surface heat fluxes are then diagnosed, and these values applied as constant flux boundary conditions, the nonlinear model switches into a state of perpetual, finite amplitude, interdecadal oscillations. We construct a linearized version of the model by empirically evaluating the tangent linear matrix at the steady state, under both restoring and constant-flux boundary conditions. An eigen-analysis shows there are no unstable eigenmodes of the linearized model with restoring conditions. In contrast, under constant flux conditions, we find a single unstable eigenmode that shows a striking resemblance to the fully-developed oscillations in terms of three-dimensional structure, period and growth rate. The mode may be damped through either surface restoring boundary conditions or sufficiently large horizontal tracer diffusion. The success of this simple numerical method in idealized geometry suggests applications in the study of the stability of the ocean circulation in more realistic configurations, and the possibility of predicting potential oceanic modes, even weakly damped, that might be excited by stochastic atmospheric forcing or mesoscale ocean eddies.
Heating rate effects in simulated liquid Al2O_3
NASA Astrophysics Data System (ADS)
van Hoang, Vo
2006-01-01
The heating rate effects in simulated liquid Al{2}O{3} have been investigated by Molecular Dynamics (MD) method. Simulations were done in the basic cube under periodic boundary conditions containing 3000 ions with Born-Mayer type pair potentials. The temperature of the system was increasing linearly in time from the zero temperature as T(t)=T0 +γ t, where γ is the heating rate. The heating rate dependence of density and enthalpy of the system was found. Calculations show that static properties of the system such as the coordination number distributions and bond-angle distributions slightly depend on γ . Structure of simulated amorphous Al{2}O{3} model with the real density at the ambient pressure is in good agreement with Lamparter's experimental data. The heating rate dependence of dynamics of the system has been studied through the diffusion constant, mean-squared atomic displacement and comparison of partial radial distribution functions (PRDFs) for 10% most mobile and immobile particles with the corresponding mean ones. Finally, the evolution of diffusion constant of Al and O particles and structure of the system upon heating for the smallest heating rate was studied and presented. And we find that the temperature dependence of self-diffusion constant in the high temperature region shows a crossover to one which can be described well by a power law, D∝ (T-Tc )^γ . The critical temperature Tc is about 3500 K and the exponent γ is close to 0.941 for Al and to 0.925 for O particles. The glass phase transition temperature Tg for the Al{2}O{3} system is at anywhere around 2000 K.
Computational Modeling and Simulation of Film-Condensation
2013-01-18
different cases considered in the present work. Table 2: Four different cases corresponding to various thermal boundary conditions ( CWT : constant wall...temperature; UHF: uniform heat flux; and CHT: convection heat transfer) on the channel walls. Cases (a) (b) (c) (d) Top wall BC CWT : Tw2>Tsat UHF: qw...CHT: h & T∞ >Tsat CHT Bottom Wall BC CWT : Tw1<Tsat CWT : Tw1<Tsat CWT : Tw1<Tsat UHF: qw Page 12 of 18 In the above table, T y
Transient Effects in Planar Solidification of Dilute Binary Alloys
NASA Technical Reports Server (NTRS)
Mazuruk, Konstantin; Volz, Martin P.
2008-01-01
The initial transient during planar solidification of dilute binary alloys is studied in the framework of the boundary integral method that leads to the non-linear Volterra integral governing equation. An analytical solution of this equation is obtained for the case of a constant growth rate which constitutes the well-known Tiller's formula for the solute transient. The more physically relevant, constant ramping down temperature case has been studied both numerically and analytically. In particular, an asymptotic analytical solution is obtained for the initial transient behavior. A numerical technique to solve the non-linear Volterra equation is developed and the solution is obtained for a family of the governing parameters. For the rapid solidification condition, growth rate spikes have been observed even for the infinite kinetics model. When recirculating fluid flow is included into the analysis, the spike feature is dramatically diminished. Finally, we have investigated planar solidification with a fluctuating temperature field as a possible mechanism for frequently observed solute trapping bands.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Liu Laijun; Fan Huiqing; Fang Pinyang
2008-07-01
The giant dielectric constant material CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) has been synthesized by sol-gel method, for the first time, using nitrate and alkoxide precursor. The electrical properties of CCTO ceramics, showing an enormously large dielectric constant {epsilon} {approx} 60,000 (100 Hz at RT), were investigated in the temperature range from 298 to 358 K at 0, 5, 10, 20, and 40 V dc. The phases, microstructures, and impedance properties of final samples were characterized by X-ray diffraction, scanning electron microscopy, and precision impedance analyzer. The dielectric permittivity of CCTO synthesized by sol-gel method is at least three times ofmore » magnitude larger than that synthesized by other low-temperature method and solid-state reaction method. Furthermore, the results support the internal barrier layer capacitor (IBLC) model of Schottky barriers at grain boundaries between semiconducting grains.« less
SteamTables: An approach of multiple variable sets
NASA Astrophysics Data System (ADS)
Verma, Mahendra P.
2009-10-01
Using the IAPWS-95 formulation, an ActiveX component SteamTablesIIE in Visual Basic 6.0 is developed to calculate thermodynamic properties of pure water as a function of two independent intensive variables: (1) temperature ( T) or pressure ( P) and (2) T, P, volume ( V), internal energy ( U), enthalpy ( H), entropy ( S) or Gibbs free energy ( G). The second variable cannot be the same as variable 1. Additionally, it calculates the properties along the separation boundaries (i.e., sublimation, saturation, critical isochor, ice I melting, ice III to ice IIV melting and minimum volume curves) considering the input parameter as T or P for the variable 1. SteamTablesIIE is an extension of the ActiveX component SteamTables implemented earlier considering T (190 to 2000 K) and P (3.23×10 -8 to 10000 MPa) as independent variables. It takes into account the following 27 intensive properties: temperature ( T), pressure ( P), fraction, state, volume ( V), density ( Den), compressibility factor ( Z0), internal energy ( U), enthalpy ( H), Gibbs free energy ( G), Helmholtz free energy ( A), entropy ( S), heat capacity at constant pressure ( C p), heat capacity at constant volume ( C v), coefficient of thermal expansion ( CTE), isothermal compressibility ( Z iso), speed of sound ( VelS), partial derivative of P with T at constant V ( dPdT), partial derivative of T with V at constant P ( dTdV), partial derivative of V with P at constant T ( dVdP), Joule-Thomson coefficient ( JTC), isothermal throttling coefficient ( IJTC), viscosity ( Vis), thermal conductivity ( ThrmCond), surface tension ( SurfTen), Prandtl number ( PrdNum) and dielectric constant ( DielCons).
Using Dielectric Relaxation Spectroscopy to Characterize the Glass Transition Time of Polydextrose.
Buehler, Martin G; Kindle, Michael L; Carter, Brady P
2015-06-01
Dielectric relaxation spectroscopy was used to characterize the glass transition time, tg , of polydextrose, where the glass transition temperature, Tg , and water activity, aw (relative humidity), were held constant during polydextrose relaxation. The tg was determined from a shift in the peak frequency of the imaginary capacitance spectrum with time. It was found that when the peak frequency reaches 30 mHz, polydextrose undergoes glass transition. Glass transition time, tg , is the time for polydextrose to undergo glass transition at a specific Tg and aw . Results lead to a modified state diagram, where Tg is depressed with increasing aw . This curve forms a boundary: (a) below the boundary, polydextrose does not undergo glass transition and (b) above the boundary, polydextrose rapidly undergoes glass transition. As the boundary curve is specified by a tg value, it can assist in the selection of storage conditions. An important point on the boundary curve is at aw = 0, where Tg0 = 115 °C. The methodology can also be used to calculate the stress-relaxation viscosity of polydextrose as a function of Tg and aw , which is important when characterizing the flow properties of polydextrose initially in powder form. © 2015 Institute of Food Technologists®
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gilot, P.; Bonnefoy, F.; Marcuccilli, F.
1993-10-01
Kinetic data concerning carbon black oxidation in the temperature range between 600 and 900 C have been obtained using thermogravimetric analysis. Modeling of diffusion in a boundary layer above the pan and inside the porous medium coupled to oxygen reaction with carbon black is necessary to obtain kinetic constants as a function of temperature. These calculations require the knowledge of the oxidation rate at a given constant temperature as a function of the initial mass loading m[sub o]. This oxidation rate, expressed in milligrams of soot consumed per second and per milligram of initial soot loading, decreases when m[sub o]more » increases, in agreement with a reaction in an intermediary regime where the kinetics and the oxygen diffusion operate. The equivalent diffusivity of oxygen inside the porous medium is evaluated assuming two degrees of porosity: between soot aggregates and inside each aggregate. Below 700 C an activation energy of about 103 kJ/mol can be related to a combustion reaction probably kinetically controlled. Beyond 700 C the activation energy of about 20 kJ/ mol corresponds to a reaction essentially controlled by oxygen diffusion leading to a constant density oxidation with oxygen consumption at or near the particle surface. To validate these data, they are used in the modeling of a Diesel particulate trap regeneration. In this particular case, the oxidizing flux is forced across the carbon black deposit, oxygen diffusion being insignificant. A good agreement between experimental results and model predictions is obtained, proving the rate constants validity.« less
Large-scale effects on the regulation of tropical sea surface temperature
NASA Technical Reports Server (NTRS)
Hartmann, Dennis L.; Michelsen, Marc L.
1993-01-01
The dominant terms in the surface energy budget of the tropical oceans are absorption of solar radiation and evaporative cooling. If it is assumed that relative humidity in the boundary layer remains constant, evaporative cooling will increase rapidly with sea surface temperature (SST) because of the strong temperature dependence of saturation water vapor pressure. The resulting stabilization of SST provided by evaporative cooling is sufficient to overcome positive feedback contributed by the decrease of surface net longwave cooling with increasing SST. Evaporative cooling is sensitive to small changes in boundary-layer relative humidity. Large and negative shortwave cloud forcing in the regions of highest SST are supported by the moisture convergence associated with largescale circulations. In the descending portions of these circulations the shortwave cloud forcing is suppressed. When the effect of these circulations is taken into account by spatial averaging, the area-averaged cloud forcing shows no sensitivity to area-averaged SST changes associated with the 1987 warming event in the tropical Pacific. While the shortwave cloud forcing is large and important in the convective regions, the importance of its role in regulating the average temperature of the tropics and in modulating temperature gradients within the tropics is less clear. A heuristic model of SST is used to illustrate the possible role of large-scale atmospheric circulations on SST in the tropics and the coupling between SST gradients and mean tropical SST. The intensity of large-scale circulations responds sensitivity to SST gradients and affects the mean tropical SST by supplying dry air to the planetary boundary layer. Large SST gradients generate vigorous circulations that increase evaporation and reduce the mean SST.
NASA Technical Reports Server (NTRS)
Rumsey, Charles B.; Lee, Dorothy B.
1961-01-01
Measurements of aerodynamic heat transfer have been made at several stations on the 15 deg total-angle conical nose of a rocket-propelled model in free flight at Mach numbers up to 5.2. Data are presented for a range of local Mach number just outside the boundary layer from 1.40 to 4.65 and a range of local Reynolds number from 3.8 x 10(exp 6) to 46.5 x 10(exp 6), based on length from the nose tip to a measurement station. Laminar, transitional, and turbulent heat-transfer coefficients were measured. The laminar data were in agreement with laminar theory for cones, and the turbulent data agreed well with turbulent theory for cones using Reynolds number based on length from the nose tip. At a nearly constant ratio of wall to local static temperature of 1.2 the Reynolds number of transition increased from 14 x 10(exp 6) to 30 x 10(exp 6) as Mach number increased from 1.4 to 2.9 and then decreased to 17 x 10(exp 6) as Mach number increased to 3.7. At Mach numbers near 3.5, transition Reynolds numbers appeared to be independent of skin temperature at skin temperatures very cold with respect to adiabatic wall temperature. The transition Reynolds number was 17.7 x 10(exp 6) at a condition of Mach number and ratio of wall to local static temperature near that for which three-dimensional disturbance theory has been evaluated and has predicted laminar boundary-layer stability to very high Reynolds numbers (approximately 10(exp 12)).
Analysis of high-speed rotating flow inside gas centrifuge casing
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
2017-10-01
The generalized analytical model for the radial boundary layer inside the gas centrifuge casing in which the inner cylinder is rotating at a constant angular velocity Ω_i while the outer one is stationary, is formulated for studying the secondary gas flow field due to wall thermal forcing, inflow/outflow of light gas along the boundaries, as well as due to the combination of the above two external forcing. The analytical model includes the sixth order differential equation for the radial boundary layer at the cylindrical curved surface in terms of master potential (χ) , which is derived from the equations of motion in an axisymmetric (r - z) plane. The linearization approximation is used, where the equations of motion are truncated at linear order in the velocity and pressure disturbances to the base flow, which is a solid-body rotation. Additional approximations in the analytical model include constant temperature in the base state (isothermal compressible Couette flow), high aspect ratio (length is large compared to the annular gap), high Reynolds number, but there is no limitation on the Mach number. The discrete eigenvalues and eigenfunctions of the linear operators (sixth-order in the radial direction for the generalized analytical equation) are obtained. The solutions for the secondary flow is determined in terms of these eigenvalues and eigenfunctions. These solutions are compared with direct simulation Monte Carlo (DSMC) simulations and found excellent agreement (with a difference of less than 15%) between the predictions of the analytical model and the DSMC simulations, provided the boundary conditions in the analytical model are accurately specified.
Analysis of high-speed rotating flow inside gas centrifuge casing
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
2017-09-01
The generalized analytical model for the radial boundary layer inside the gas centrifuge casing in which the inner cylinder is rotating at a constant angular velocity Ωi while the outer one is stationary, is formulated for studying the secondary gas flow field due to wall thermal forcing, inflow/outflow of light gas along the boundaries, as well as due to the combination of the above two external forcing. The analytical model includes the sixth order differential equation for the radial boundary layer at the cylindrical curved surface in terms of master potential (χ) , which is derived from the equations of motion in an axisymmetric (r - z) plane. The linearization approximation is used, where the equations of motion are truncated at linear order in the velocity and pressure disturbances to the base flow, which is a solid-body rotation. Additional approximations in the analytical model include constant temperature in the base state (isothermal compressible Couette flow), high aspect ratio (length is large compared to the annular gap), high Reynolds number, but there is no limitation on the Mach number. The discrete eigenvalues and eigenfunctions of the linear operators (sixth-order in the radial direction for the generalized analytical equation) are obtained. The solutions for the secondary flow is determined in terms of these eigenvalues and eigenfunctions. These solutions are compared with direct simulation Monte Carlo (DSMC) simulations and found excellent agreement (with a difference of less than 15%) between the predictions of the analytical model and the DSMC simulations, provided the boundary conditions in the analytical model are accurately specified.
Analysis of high-speed rotating flow inside gas centrifuge casing
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev
2017-11-01
The generalized analytical model for the radial boundary layer inside the gas centrifuge casing in which the inner cylinder is rotating at a constant angular velocity Ωi while the outer one is stationary, is formulated for studying the secondary gas flow field due to wall thermal forcing, inflow/outflow of light gas along the boundaries, as well as due to the combination of the above two external forcing. The analytical model includes the sixth order differential equation for the radial boundary layer at the cylindrical curved surface in terms of master potential (χ) , which is derived from the equations of motion in an axisymmetric (r - z) plane. The linearization approximation is used, where the equations of motion are truncated at linear order in the velocity and pressure disturbances to the base flow, which is a solid-body rotation. Additional approximations in the analytical model include constant temperature in the base state (isothermal compressible Couette flow), high aspect ratio (length is large compared to the annular gap), high Reynolds number, but there is no limitation on the Mach number. The discrete eigenvalues and eigenfunctions of the linear operators (sixth-order in the radial direction for the generalized analytical equation) are obtained. The solutions for the secondary flow is determined in terms of these eigenvalues and eigenfunctions. These solutions are compared with direct simulation Monte Carlo (DSMC) simulations and found excellent agreement (with a difference of less than 15%) between the predictions of the analytical model and the DSMC simulations, provided the boundary conditions in the analytical model are accurately specified.
Influence of Ti on the Hot Ductility of High-manganese Austenitic Steels
NASA Astrophysics Data System (ADS)
Liu, Hongbo; Liu, Jianhua; Wu, Bowei; Su, Xiaofeng; Li, Shiqi; Ding, Hao
2017-07-01
The influence of Ti addition ( 0.10 wt%) on hot ductility of as-cast high-manganese austenitic steels has been examined over the temperature range 650-1,250 °C under a constant strain rate of 10-3 s-1 using Gleeble3500 thermal simulation testing machine. The fracture surfaces and particles precipitated at different tensile temperatures were characterized by means of scanning electron microscope and X-ray energy dispersive spectrometry (SEM-EDS). Hot ductility as a function of reduction curves shows that adding 0.10 wt% Ti made the ductility worse in the almost entire range of testing temperatures. The phases' equilibrium diagrams of precipitates in Ti-bearing high-Mn austenitic steel were calculated by the Thermo-Calc software. The calculation result shows that 0.1 wt% Ti addition would cause Ti(C,N) precipitated at 1,499 °C, which is higher than the liquidus temperature of high-Mn austenitic steel. It indicated that Ti(C,N) particles start forming in the liquid high-Mn austenitic steel. The SEM-EDS results show that Ti(C,N) and TiC particles could be found along the austenite grain boundaries or at triple junction, and they would accelerate the extension of the cracks along the grain boundaries.
Experimental Characterization of Radiation Forcing due to Atmospheric Aerosols
NASA Astrophysics Data System (ADS)
Sreenivas, K. R.; Singh, D. K.; Ponnulakshmi, V. K.; Subramanian, G.
2011-11-01
Micro-meteorological processes in the nocturnal atmospheric boundary layer (NBL) including the formation of radiation-fog and the development of inversion layers are controlled by heat transfer and the vertical temperature distribution close to the ground. In a recent study, it has been shown that the temperature profile close to the ground in stably-stratified, NBL is controlled by the radiative forcing due to suspended aerosols. Estimating aerosol forcing is also important in geo-engineering applications to evaluate the use of aerosols to mitigate greenhouse effects. Modeling capability in the above scenarios is limited by our knowledge of this forcing. Here, the design of an experimental setup is presented which can be used for evaluating the IR-radiation forcing on aerosols under either Rayleigh-Benard condition or under conditions corresponding to the NBL. We present results indicating the effect of surface emissivities of the top and bottom boundaries and the aerosol concentration on the temperature profiles. In order to understand the observed enhancement of the convection-threshold, we have determined the conduction-radiation time constant of an aerosol laden air layer. Our results help to explain observed temperature profiles in the NBL, the apparent stability of such profiles and indicate the need to account for the effect of aerosols in climatic/weather models.
NASA Astrophysics Data System (ADS)
Gupta, Surbhi; Deshpande, S. K.; Sathe, V. G.; Siruguri, V.
2018-04-01
We present dielectric, complex impedance, modulus spectroscopy and AC conductivity studies of the compound BaFe10Sc2O19 as a function of temperature and frequency to understand the conduction mechanism. The variation in complex dielectric constant with frequency and temperature were analyzed on the basis of Maxwell-Wagner-Koop's theory and charge hopping between ferrous and ferric ions. The complex impedance spectroscopy study shows only grain contribution whereas complex modulus plot shows two semicircular arcs which indicate both grain and grain boundary contributions in conduction mechanism. AC conductivity has also been evaluated which follows the Jonscher's law. The activation energy calculated from temperature dependence of DC conductivity comes out to be Ea˜ 0.31eV.
Thermal enclosures for electronically scanned pressure modules operating in cryogenic environments
NASA Technical Reports Server (NTRS)
Mitchell, Michael; Sealey, Bradley S.
1989-01-01
Specific guidelines to design, construct, and test ESP thermal enclosures for applications at cryogenic temperatures are given. The enclosures maintain the ESP modules at a constant temperature (10 C plus or minus 1 C) to minimize thermal zero and sensitivity shifts, to minimize the frequency of expensive on-line calibrations, and to avoid adverse effects on tunnel and model boundary layers. The enclosures are constructed of a rigid closed-cell foam and are capable of withstanding the stagnation pressures to 932kPa (135 psia) without reduction in thermal insulation properties. This construction procedure has been used to construct several thermal packages which have been successfully used in National Transonic Facility.
NASA Astrophysics Data System (ADS)
Wan, Ling; Wang, Tao
2017-06-01
We consider the Navier-Stokes equations for compressible heat-conducting ideal polytropic gases in a bounded annular domain when the viscosity and thermal conductivity coefficients are general smooth functions of temperature. A global-in-time, spherically or cylindrically symmetric, classical solution to the initial boundary value problem is shown to exist uniquely and converge exponentially to the constant state as the time tends to infinity under certain assumptions on the initial data and the adiabatic exponent γ. The initial data can be large if γ is sufficiently close to 1. These results are of Nishida-Smoller type and extend the work (Liu et al. (2014) [16]) restricted to the one-dimensional flows.
Bubble dynamics in a compressible liquid in contact with a rigid boundary
Wang, Qianxi; Liu, Wenke; Zhang, A. M.; Sui, Yi
2015-01-01
A bubble initiated near a rigid boundary may be almost in contact with the boundary because of its expansion and migration to the boundary, where a thin layer of water forms between the bubble and the boundary thereafter. This phenomenon is modelled using the weakly compressible theory coupled with the boundary integral method. The wall effects are modelled using the imaging method. The numerical instabilities caused by the near contact of the bubble surface with the boundary are handled by removing a thin layer of water between them and joining the bubble surface with its image to the boundary. Our computations correlate well with experiments for both the first and second cycles of oscillation. The time history of the energy of a bubble system follows a step function, reducing rapidly and significantly because of emission of shock waves at inception of a bubble and at the end of collapse but remaining approximately constant for the rest of the time. The bubble starts being in near contact with the boundary during the first cycle of oscillation when the dimensionless stand-off distance γ = s/Rm < 1, where s is the distance of the initial bubble centre from the boundary and Rm is the maximum bubble radius. This leads to (i) the direct impact of a high-speed liquid jet on the boundary once it penetrates through the bubble, (ii) the direct contact of the bubble at high temperature and high pressure with the boundary, and (iii) the direct impingement of shock waves on the boundary once emitted. These phenomena have clear potential to damage the boundary, which are believed to be part of the mechanisms of cavitation damage. PMID:26442148
A methodology for constraining power in finite element modeling of radiofrequency ablation.
Jiang, Yansheng; Possebon, Ricardo; Mulier, Stefaan; Wang, Chong; Chen, Feng; Feng, Yuanbo; Xia, Qian; Liu, Yewei; Yin, Ting; Oyen, Raymond; Ni, Yicheng
2017-07-01
Radiofrequency ablation (RFA) is a minimally invasive thermal therapy for the treatment of cancer, hyperopia, and cardiac tachyarrhythmia. In RFA, the power delivered to the tissue is a key parameter. The objective of this study was to establish a methodology for the finite element modeling of RFA with constant power. Because of changes in the electric conductivity of tissue with temperature, a nonconventional boundary value problem arises in the mathematic modeling of RFA: neither the voltage (Dirichlet condition) nor the current (Neumann condition), but the power, that is, the product of voltage and current was prescribed on part of boundary. We solved the problem using Lagrange multiplier: the product of the voltage and current on the electrode surface is constrained to be equal to the Joule heating. We theoretically proved the equality between the product of the voltage and current on the surface of the electrode and the Joule heating in the domain. We also proved the well-posedness of the problem of solving the Laplace equation for the electric potential under a constant power constraint prescribed on the electrode surface. The Pennes bioheat transfer equation and the Laplace equation for electric potential augmented with the constraint of constant power were solved simultaneously using the Newton-Raphson algorithm. Three problems for validation were solved. Numerical results were compared either with an analytical solution deduced in this study or with results obtained by ANSYS or experiments. This work provides the finite element modeling of constant power RFA with a firm mathematical basis and opens pathway for achieving the optimal RFA power. Copyright © 2016 John Wiley & Sons, Ltd.
CFD simulation and experimental validation of a GM type double inlet pulse tube refrigerator
NASA Astrophysics Data System (ADS)
Banjare, Y. P.; Sahoo, R. K.; Sarangi, S. K.
2010-04-01
Pulse tube refrigerator has the advantages of long life and low vibration over the conventional cryocoolers, such as GM and stirling coolers because of the absence of moving parts in low temperature. This paper performs a three-dimensional computational fluid dynamic (CFD) simulation of a GM type double inlet pulse tube refrigerator (DIPTR) vertically aligned, operating under a variety of thermal boundary conditions. A commercial computational fluid dynamics (CFD) software package, Fluent 6.1 is used to model the oscillating flow inside a pulse tube refrigerator. The simulation represents fully coupled systems operating in steady-periodic mode. The externally imposed boundary conditions are sinusoidal pressure inlet by user defined function at one end of the tube and constant temperature or heat flux boundaries at the external walls of the cold-end heat exchangers. The experimental method to evaluate the optimum parameters of DIPTR is difficult. On the other hand, developing a computer code for CFD analysis is equally complex. The objectives of the present investigations are to ascertain the suitability of CFD based commercial package, Fluent for study of energy and fluid flow in DIPTR and to validate the CFD simulation results with available experimental data. The general results, such as the cool down behaviours of the system, phase relation between mass flow rate and pressure at cold end, the temperature profile along the wall of the cooler and refrigeration load are presented for different boundary conditions of the system. The results confirm that CFD based Fluent simulations are capable of elucidating complex periodic processes in DIPTR. The results also show that there is an excellent agreement between CFD simulation results and experimental results.
A molecular Rayleigh scattering setup to measure density fluctuations in thermal boundary layers
NASA Astrophysics Data System (ADS)
Panda, J.
2016-12-01
A Rayleigh scattering-based density fluctuation measurement system was set up inside a low-speed wind tunnel of NASA Ames Research Center. The immediate goal was to study the thermal boundary layer on a heated flat plate. A large number of obstacles had to be overcome to set up the system, such as the removal of dust particles using air filters, the use of photoelectron counting electronics to measure low intensity light, an optical layout to minimize stray light contamination, the reduction in tunnel vibration, and an expanded calibration process to relate photoelectron arrival rate to air density close to the plate surface. To measure spectra of turbulent density fluctuations, a two-PMT cross-correlation system was used to minimize the shot noise floor. To validate the Rayleigh measurements, temperature fluctuations spectra were calculated from density spectra and then compared with temperature spectra measured with a cold-wire probe operated in constant current mode. The spectra from the downstream half of the plate were found to be in good agreement with cold-wire probe, whereas spectra from the leading edge differed. Various lessons learnt are discussed. It is believed that the present effort is the first measurement of density fluctuations spectra in a boundary layer flow.
Uddin, Mohammed J.; Khan, Waqar A.; Amin, Norsarahaida S.
2014-01-01
The unsteady two-dimensional laminar g-Jitter mixed convective boundary layer flow of Cu-water and Al2O3-water nanofluids past a permeable stretching sheet in a Darcian porous is studied by using an implicit finite difference numerical method with quasi-linearization technique. It is assumed that the plate is subjected to velocity and thermal slip boundary conditions. We have considered temperature dependent viscosity. The governing boundary layer equations are converted into non-similar equations using suitable transformations, before being solved numerically. The transport equations have been shown to be controlled by a number of parameters including viscosity parameter, Darcy number, nanoparticle volume fraction, Prandtl number, velocity slip, thermal slip, suction/injection and mixed convection parameters. The dimensionless velocity and temperature profiles as well as friction factor and heat transfer rates are presented graphically and discussed. It is found that the velocity reduces with velocity slip parameter for both nanofluids for fluid with both constant and variable properties. It is further found that the skin friction decreases with both Darcy number and momentum slip parameter while it increases with viscosity variation parameter. The surface temperature increases as the dimensionless time increases for both nanofluids. Nusselt numbers increase with mixed convection parameter and Darcy numbers and decreases with the momentum slip. Excellent agreement is found between the numerical results of the present paper with published results. PMID:24927277
NASA Astrophysics Data System (ADS)
Rabbi, Kazi Fazle; Tamim, Saiful Islam; Faisal, A. H. M.; Mukut, K. M.; Hasan, Mohammad Nasim
2017-06-01
This study is a molecular dynamics investigation of phase change phenomena i.e. boiling of thin liquid films subjected to rapid linear heating at the boundary. The purpose of this study is to understand the phase change heat transfer phenomena at nano scale level. In the simulation, a thin film of liquid argon over a platinum surface has been considered. The simulation domain herein is a three-phase system consisting of liquid and vapor argon atoms placed over a platinum wall. Initially the whole system is brought to an equilibrium state at 90 K and then the temperature of the bottom wall is increased to a higher temperature (250K) within a finite time interval. Four different liquid argon film thicknesses have been considered (3 nm, 4 nm, 5 nm and 6 nm) in this study. The boundary heating rate (40×109 K/s) is kept constant in all these cases. Variation in system temperature, pressure, net evaporation number, spatial number density of the argon region with time for different film thickness have been demonstrated and analyzed. The present study indicates that the pattern of phase transition may be significantly different (i.e. evaporation or explosive boiling) depending on the liquid film thickness. Among the four cases considered in the present study, explosive boiling has been observed only for the liquid films of 5nm and 6nm thickness, while for the other cases, evaporation take place.
NASA Astrophysics Data System (ADS)
Roth, Connie B.; Kriisa, Annika
Understanding the phase behavior of polymer blends and block copolymers under the presence of electric fields is important for advanced applications containing electrodes such as organic photovoltaics and batteries, as well as for field-directed assembly and alignment of domains. We have recently demonstrated that electric fields enhance the miscibility of polystyrene (PS) / poly(vinyl methyl ether blends) (PVME) blends, shifting the phase separation temperature Ts(E) up by 13.5 +/- 1.4 K for electric field strengths of E = 1.7 MV/m. Experimentally this effect is much larger than the traditional predictions from adding the standard electrostatic energy term for mixtures to the free energy of mixing. However, accounting for the energy penalty of dielectric interfaces between domains created during phase separation, the primary factor that drives alignment of domains, may also be responsible for the change in miscibility. Here we investigate the dynamics of repeatedly jumping the system from the one-phase to the two-phase region and demonstrate that this can be done at a constant temperature simply by turning the electric field on and off, illustrating electric-field-induced remixing in the two-phase region.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mu, Chunhong; Song, Yuanqiang, E-mail: yuanqiangsong@uestc.edu.cn; Wang, Xiaoning
2015-05-07
CaCu{sub 3}Ti{sub 4−x}Co{sub x}O{sub 12} (x = 0, 0.2, 0.4) ceramics were prepared by a conventional solid state reaction, and the effects of cobalt doping on the room temperature magnetic and dielectric properties were investigated. Both X-ray diffraction and energy dispersive X-ray spectroscopy confirmed the presence of Cu and Co rich phase at grain boundaries of Co-doped ceramics. Scanning electron microscopy micrographs of Co-doped samples showed a striking change from regular polyhedral particle type in pure CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) to sheet-like grains with certain growth orientation. Undoped CaCu{sub 3}Ti{sub 4}O{sub 12} is well known for its colossal dielectric constant inmore » a broad temperature and frequency range. The dielectric constant value was slightly changed by 5 at. % and 10 at. % Co doping, whereas the second relaxation process was clearly separated in low frequency region at room temperature. A multirelaxation mechanism was proposed to be the origin of the colossal dielectric constant. In addition, the permeability spectra measurements indicated Co-doped CCTO with good magnetic properties, showing the initial permeability (μ′) as high as 5.5 and low magnetic loss (μ″ < 0.2) below 3 MHz. And the interesting ferromagnetic superexchange coupling in Co-doped CaCu{sub 3}Ti{sub 4}O{sub 12} was discussed.« less
NASA Astrophysics Data System (ADS)
Yadav, Abhinav; Mantry, Snigdha Paramita; Fahad, Mohd.; Sarun, P. M.
2018-05-01
Sodium niobate (NaNbO3) ceramics is prepared by conventional solid state reaction method at sintering temperature 1150 °C for 4 h. The structural information of the material has been investigated by X-ray diffraction (XRD) and Field emission scanning electron microscopy (FE-SEM). The XRD analysis of NaNbO3 ceramics shows an orthorhombic structure. The FE-SEM micrograph of NaNbO3 ceramics exhibit grains with grain sizes ranging between 1 μm to 5 μm. The surface coverage and average grain size of NaNbO3 ceramics are found to be 97.6 % and 2.5 μm, respectively. Frequency dependent electrical properties of NaNbO3 is investigated from room temperature to 500 °C in wide frequency range (100 Hz-5 MHz). Dielectric constant, ac-conductivity, impedance, modulus and Nyquist analysis are performed. The observed dielectric constant (1 kHz) at transition temperature (400 °C) are 975. From conductivity analysis, the estimated activation energy of NaNbO3 ceramics is 0.58 eV at 10 kHz. The result of Nyquist plot shows that the electrical behavior of NaNbO3 ceramics is contributed by grain and grain boundary responses. The impedance and modulus spectrum asserts that the negative temperature coefficient of resistance (NTCR) behavior and non-Debye type relaxation in NaNbO3.
Numerical simulation of the world ocean circulation
NASA Technical Reports Server (NTRS)
Takano, K.; Mintz, Y.; Han, Y. J.
1973-01-01
A multi-level model, based on the primitive equations, is developed for simulating the temperature and velocity fields produced in the world ocean by differential heating and surface wind stress. The model ocean has constant depth, free slip at the lower boundary, and neglects momentum advection; so that there is no energy exchange between the barotropic and baroclinic components of the motion, although the former influences the latter through temperature advection. The ocean model was designed to be coupled to the UCLA atmospheric general circulation model, for the study of the dynamics of climate and climate changes. But here, the model is tested by prescribing the observed seasonally varying surface wind stress and the incident solar radiation, the surface air temperature and humidity, cloudiness and the surface wind speed, which, together with the predicted ocean surface temperature, determine the surface flux of radiant energy, sensible heat and latent heat.
Liquid cooled plate heat exchanger for battery cooling of an electric vehicle (EV)
NASA Astrophysics Data System (ADS)
Rahman, M. M.; Rahman, H. Y.; Mahlia, T. M. I.; Sheng, J. L. Y.
2016-03-01
A liquid cooled plate heat exchanger was designed to improve the battery life of an electric vehicle which suffers from premature aging or degradation due to the heat generation during discharging and charging period. Computational fluid dynamics (CFD) was used as a tool to analyse the temperature distribution when a constant surface heat flux was set at the bottom surface of the battery. Several initial and boundary conditions were set based on the past studies on the plate heat exchanger in the simulation software. The design of the plate heat exchanger was based on the Nissan Leaf battery pack to analyse the temperature patterns. Water at different mass flow rates was used as heat transfer fluid. The analysis revealed the designed plate heat exchanger could maintain the surface temperature within the range of 20 to 40°C which is within the safe operating temperature of the battery.
On nonlinear thermo-electro-elasticity.
Mehnert, Markus; Hossain, Mokarram; Steinmann, Paul
2016-06-01
Electro-active polymers (EAPs) for large actuations are nowadays well-known and promising candidates for producing sensors, actuators and generators. In general, polymeric materials are sensitive to differential temperature histories. During experimental characterizations of EAPs under electro-mechanically coupled loads, it is difficult to maintain constant temperature not only because of an external differential temperature history but also because of the changes in internal temperature caused by the application of high electric loads. In this contribution, a thermo-electro-mechanically coupled constitutive framework is proposed based on the total energy approach. Departing from relevant laws of thermodynamics, thermodynamically consistent constitutive equations are formulated. To demonstrate the performance of the proposed thermo-electro-mechanically coupled framework, a frequently used non-homogeneous boundary-value problem, i.e. the extension and inflation of a cylindrical tube, is solved analytically. The results illustrate the influence of various thermo-electro-mechanical couplings.
On nonlinear thermo-electro-elasticity
Mehnert, Markus; Hossain, Mokarram
2016-01-01
Electro-active polymers (EAPs) for large actuations are nowadays well-known and promising candidates for producing sensors, actuators and generators. In general, polymeric materials are sensitive to differential temperature histories. During experimental characterizations of EAPs under electro-mechanically coupled loads, it is difficult to maintain constant temperature not only because of an external differential temperature history but also because of the changes in internal temperature caused by the application of high electric loads. In this contribution, a thermo-electro-mechanically coupled constitutive framework is proposed based on the total energy approach. Departing from relevant laws of thermodynamics, thermodynamically consistent constitutive equations are formulated. To demonstrate the performance of the proposed thermo-electro-mechanically coupled framework, a frequently used non-homogeneous boundary-value problem, i.e. the extension and inflation of a cylindrical tube, is solved analytically. The results illustrate the influence of various thermo-electro-mechanical couplings. PMID:27436985
NASA Astrophysics Data System (ADS)
Kozhevnikov, Danil A.; Sheremet, Mikhail A.
2018-01-01
The effect of surface tension on laminar natural convection in a vertical cylindrical cavity filled with a weak evaporating liquid has been analyzed numerically. The cylindrical enclosure is insulated at the bottom, heated by a constant heat flux from the side, and cooled by a non-uniform evaporative heat flux from the top free surface having temperature-dependent surface tension. Governing equations with corresponding boundary conditions formulated in dimensionless stream function, vorticity, and temperature have been solved by finite difference method of the second-order accuracy. The influence of Rayleigh number, Marangoni number, and aspect ratio on the liquid flow and heat transfer has been studied. Obtained results have revealed that the heat transfer rate at free surface decreases with Marangoni number and increases with Rayleigh number, while the average temperature inside the cavity has an opposite behavior; namely, it growths with Marangoni number and reduces with Rayleigh number.
NASA Technical Reports Server (NTRS)
Hagstrom, Thomas; Hariharan, S. I.; Maccamy, R. C.
1993-01-01
We consider the solution of scattering problems for the wave equation using approximate boundary conditions at artificial boundaries. These conditions are explicitly viewed as approximations to an exact boundary condition satisfied by the solution on the unbounded domain. We study the short and long term behavior of the error. It is provided that, in two space dimensions, no local in time, constant coefficient boundary operator can lead to accurate results uniformly in time for the class of problems we consider. A variable coefficient operator is developed which attains better accuracy (uniformly in time) than is possible with constant coefficient approximations. The theory is illustrated by numerical examples. We also analyze the proposed boundary conditions using energy methods, leading to asymptotically correct error bounds.
Biot number and thermos bottle effect: implications for magma-chamber convection
DOE Office of Scientific and Technical Information (OSTI.GOV)
Carrigan, C.R.
1988-09-01
Thermal boundary conditions model the coupling between a convecting magmatic body and its host. Such conditions need to be considered in models of igneous systems that involve thermal histories, crystallization and fractionation of melt, formation of aureoles by contact metamorphism, and any other processes in which transport of heat plays a role. Usually, investigations of magmatic systems have tended to emphasize modeling the interior convective regime relative to treatment of the thermal coupling. Yet it is found that the thermal nature of an intrusion is likely to be influenced more by coupling to its host than by the details ofmore » internal convective flows. Evaluation of a parameter having the form of a Biot number (Bi) provides a basis for estimating which boundary conditions are most appropriate. It is found that Bi less than or equal to 0.1 (constant heat-flux limit) for models of several caldera systems. For such values of the Biot number, the host regime behaves somewhat like a thermos bottle by limiting the flow of heat through the magma-host system so that convective stirring of magma has little effect on the cooling rate of the intrusion. Because of this insulating effect, boundary temperatures assumed in convection models should approach magmatic values even if an active hydrothermal system is present. However, high boundary temperatures do not imply that melting and assimilation of host rock by magma must occur. Despite the thermos bottle effect, magmatic convection can still be quite vigorous.« less
Fan, Longlong; Chen, Jun; Ren, Yang; Pan, Zhao; Zhang, Linxing; Xing, Xianran
2016-01-15
The origin of the excellent piezoelectric properties at the morphotropic phase boundary is generally attributed to the existence of a monoclinic phase in various piezoelectric systems. However, there exist no experimental studies that reveal the role of the monoclinic phase in the piezoelectric behavior in phase-pure ceramics. In this work, a single monoclinic phase has been identified in Pb(Zr,Ti)O_{3} ceramics at room temperature by in situ high-energy synchrotron x-ray diffraction, and its response to electric field has been characterized for the first time. Unique piezoelectric properties of the monoclinic phase in terms of large intrinsic lattice strain and negligible domain switching have been observed. The extensional strain constant d_{33} and the transverse strain constant d_{31} are calculated to be 520 and -200 pm/V, respectively. These large piezoelectric coefficients are mainly due to the large intrinsic lattice strain, with very little extrinsic contribution from domain switching. The unique properties of the monoclinic phase provide new insights into the mechanisms responsible for the piezoelectric properties at the morphotropic phase boundary.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mallow, Anne; Abdelaziz, Omar; Graham, Jr., Samuel
The thermal charging performance of paraffin wax combined with compressed expanded natural graphite foam was studied for different graphite bulk densities. Constant heat fluxes between 0.39 W/cm 2 and 1.55 W/cm 2 were applied, as well as a constant boundary temperature of 60 °C. Thermal charging experiments indicate that, in the design of thermal batteries, thermal conductivity of the composite alone is an insufficient metric to determine the influence of the graphite foam on the thermal energy storage. By dividing the latent heat of the composite by the time to end of melt for each applied boundary condition, the energymore » storage performance was calculated to show the effects of composite thermal conductivity, graphite bulk density, and latent heat capacity. For the experimental volume, the addition of graphite beyond a graphite bulk density of 100 kg/m 3 showed limited benefit on the energy storage performance due to the decrease in latent heat storage capacity. These experimental results are used to validate a numerical model to predict the time to melt and for future use in the design of heat exchangers with graphite-foam based phase change material composites. As a result, size scale effects are explored parametrically with the validated model.« less
A non-local computational boundary condition for duct acoustics
NASA Technical Reports Server (NTRS)
Zorumski, William E.; Watson, Willie R.; Hodge, Steve L.
1994-01-01
A non-local boundary condition is formulated for acoustic waves in ducts without flow. The ducts are two dimensional with constant area, but with variable impedance wall lining. Extension of the formulation to three dimensional and variable area ducts is straightforward in principle, but requires significantly more computation. The boundary condition simulates a nonreflecting wave field in an infinite duct. It is implemented by a constant matrix operator which is applied at the boundary of the computational domain. An efficient computational solution scheme is developed which allows calculations for high frequencies and long duct lengths. This computational solution utilizes the boundary condition to limit the computational space while preserving the radiation boundary condition. The boundary condition is tested for several sources. It is demonstrated that the boundary condition can be applied close to the sound sources, rendering the computational domain small. Computational solutions with the new non-local boundary condition are shown to be consistent with the known solutions for nonreflecting wavefields in an infinite uniform duct.
NASA Astrophysics Data System (ADS)
Zhang, Y. K.; Liang, X.
2014-12-01
Effects of aquifer heterogeneity and uncertainties in source/sink, and initial and boundary conditions in a groundwater flow model on the spatiotemporal variations of groundwater level, h(x,t), were investigated. Analytical solutions for the variance and covariance of h(x, t) in an unconfined aquifer described by a linearized Boussinesq equation with a white noise source/sink and a random transmissivity field were derived. It was found that in a typical aquifer the error in h(x,t) in early time is mainly caused by the random initial condition and the error reduces as time goes to reach a constant error in later time. The duration during which the effect of the random initial condition is significant may last a few hundred days in most aquifers. The constant error in groundwater in later time is due to the combined effects of the uncertain source/sink and flux boundary: the closer to the flux boundary, the larger the error. The error caused by the uncertain head boundary is limited in a narrow zone near the boundary but it remains more or less constant over time. The effect of the heterogeneity is to increase the variation of groundwater level and the maximum effect occurs close to the constant head boundary because of the linear mean hydraulic gradient. The correlation of groundwater level decreases with temporal interval and spatial distance. In addition, the heterogeneity enhances the correlation of groundwater level, especially at larger time intervals and small spatial distances.
NASA Astrophysics Data System (ADS)
Borgia, Andrea; Rutqvist, Jonny; Oldenburg, Curt M.; Hutchings, Lawrence; Garcia, Julio; Walters, Mark; Hartline, Craig; Jeanne, Pierre; Dobson, Patrick; Boyle, Katie
2013-04-01
The Enhanced Geothermal System (EGS) Demonstration Project, currently underway at the Northwest Geysers, California, aims to demonstrate the feasibility of stimulating a deep high-temperature reservoir (up to 400 °C) through water injection over a 2-year period. On October 6, 2011, injection of 25 l/s started from the Prati 32 well at a depth interval of 1850-2699 m below sea level. After a period of almost 2 months, the injection rate was raised to 63 l/s. The flow rate was then decreased to 44 l/s after an additional 3.5 months and maintained at 25 l/s up to August 20, 2012. Significant well-head pressure changes were recorded at Prati State 31 well, which is separated from Prati 32 by about 500 m at reservoir level. More subdued pressure increases occur at greater distances. The water injection caused induced seismicity in the reservoir in the vicinity of the well. Microseismic monitoring and interpretation shows that the cloud of seismic events is mainly located in the granitic intrusion below the injection zone, forming a cluster elongated SSE-NNW (azimuth 170°) that dips steeply to the west. In general, the magnitude of the events increases with depth and the hypocenter depth increases with time. This seismic cloud is hypothesized to correlate with enhanced permeability in the high-temperature reservoir and its variation with time. Based on the existing borehole data, we use the GMS™ GUI to construct a realistic three-dimensional (3D) geologic model of the Northwest Geysers geothermal field. This model includes, from the top down, a low permeability graywacke layer that forms the caprock for the reservoir, an isothermal steam zone (known as the normal temperature reservoir) within metagraywacke, a hornfels zone (where the high-temperature reservoir is located), and a felsite layer that is assumed to extend downward to the magmatic heat source. We then map this model onto a rectangular grid for use with the TOUGH2 multiphase, multicomponent, non-isothermal porous media numerical flow simulator in order to model the evolution and injection-related operational dynamics of The Geysers geothermal field. At the bottom of the domain in the felsite, we impose a constant temperature, constant saturation, low-permeability boundary. Laterally we set no-flow boundaries (no mass or heat flow), while at the top we use a fully aqueous-phase-saturated constant atmospheric pressure boundary condition. We compute initial conditions for two different conceptual models. The first conceptual model has two phases (gas and aqueous) with decreasing proportions of gas from the steam zone downward; the second model has dry steam all the way from the steam zone to the bottom. The first may be more similar to a pre-exploitation condition, before production reduced pressure and dried out the system, while the second is calibrated to the pressure and temperature actually measured in the reservoir today. Our preliminary results are in reasonable agreement with the pressure monitoring at Prati State 31. These results will be used in hydrogeomechanical modeling to plan, design, and validate the effects of injection in the system.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Viskanta, R.
1963-01-01
Laminar free-convection flow produced by a heated, vertical, circular cylinder for which the temperature at the outer surface of the cylinder is assumed to be uniform is analyzed. The solution of the boundary-layer equations was obtained by the perturbation method of Sparrow and Gregg, which is valid only for small values of the axial distance parameter xi ; and the integral method of Hama et al., for large values of the parameter xi . Heat-transfer results were calculated for Prandtl numbers (Pr) of 100, the Nusselt numbers (Nu) for the cylinder were higher than those for the flat plate, andmore » this difference increased as Pr decreased. It was also found that the perturbation method of solution of the free-convection boundary-layer equations becomes useless for small values of Pr because of the slow convergence of the series. The results obtained by the integral method were in good agreement with those calculated by the perturbation method for Pr approximately 1 and 0.1 < xi < 1 only; they deviated considerably for smaller values of xi . (auth)« less
Vacancy-type defects in TiO2/SiO2/SiC dielectric stacks
NASA Astrophysics Data System (ADS)
Coleman, P. G.; Burrows, C. P.; Mahapatra, R.; Wright, N. G.
2007-07-01
Open-volume (vacancy-type) point defects have been observed in ˜80-nm-thick titanium dioxide films grown on silicon dioxide/4H silicon carbide substrates as stacks with high dielectric constant for power device applications, using variable-energy positron annihilation spectroscopy. The concentration of vacancies decreases as the titanium dioxide growth temperature is increased in the range from 700to1000°C, whereas grain boundaries form in the polycrystalline material at the highest growth temperatures. It is proposed that the optimal electrical performance for films grown at 800°C reflects a balance between decreasing vacancy concentration and increasing grain boundary formation. The concentration of vacancies at the silicon dioxide/silicon carbide interface appears to saturate after 2.5h oxidation at 1150°C. A supplementary result suggests that the quality of the 10-μm-thick deposited silicon carbide epilayer is compromised at depths of about 2μm and beyond, possibly by the migration of impurities and/or other defects from the standard-grade highly doped 4H silicon carbide wafer beneath the epilayer during oxidation.
Impact of tides in a baroclinic circulation model of the Adriatic Sea
NASA Astrophysics Data System (ADS)
Guarnieri, A.; Pinardi, N.; Oddo, P.; Bortoluzzi, G.; Ravaioli, M.
2013-01-01
NASA Astrophysics Data System (ADS)
Abramov, Rafail V.
2018-06-01
For the gas near a solid planar wall, we propose a scaling formula for the mean free path of a molecule as a function of the distance from the wall, under the assumption of a uniform distribution of the incident directions of the molecular free flight. We subsequently impose the same scaling onto the viscosity of the gas near the wall and compute the Navier-Stokes solution of the velocity of a shear flow parallel to the wall. Under the simplifying assumption of constant temperature of the gas, the velocity profile becomes an explicit nonlinear function of the distance from the wall and exhibits a Knudsen boundary layer near the wall. To verify the validity of the obtained formula, we perform the Direct Simulation Monte Carlo computations for the shear flow of argon and nitrogen at normal density and temperature. We find excellent agreement between our velocity approximation and the computed DSMC velocity profiles both within the Knudsen boundary layer and away from it.
Multiverse understanding of cosmological coincidences
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bousso, Raphael; Hall, Lawrence J.; Nomura, Yasunori
2009-09-15
There is a deep cosmological mystery: although dependent on very different underlying physics, the time scales of structure formation, of galaxy cooling (both radiatively and against the CMB), and of vacuum domination do not differ by many orders of magnitude, but are all comparable to the present age of the universe. By scanning four landscape parameters simultaneously, we show that this quadruple coincidence is resolved. We assume only that the statistical distribution of parameter values in the multiverse grows towards certain catastrophic boundaries we identify, across which there are drastic regime changes. We find order-of-magnitude predictions for the cosmological constant,more » the primordial density contrast, the temperature at matter-radiation equality, the typical galaxy mass, and the age of the universe, in terms of the fine structure constant and the electron, proton and Planck masses. Our approach permits a systematic evaluation of measure proposals; with the causal patch measure, we find no runaway of the primordial density contrast and the cosmological constant to large values.« less
NASA Astrophysics Data System (ADS)
Aman, Sidra; Zuki Salleh, Mohd; Ismail, Zulkhibri; Khan, Ilyas
2017-09-01
This article focuses on the flow of Maxwell nanofluids with graphene nanoparticles over a vertical plate (static) with constant wall temperature. Possessing high thermal conductivity, engine oil is useful to be chosen as base fluid with free convection. The problem is modelled in terms of PDE’s with boundary conditions. Some suitable non-dimensional variables are interposed to transform the governing equations into dimensionless form. The generated equations are solved via Laplace transform technique. Exact solutions are evaluated for velocity and temperature. These solutions are significantly controlled by some parameters involved. Temperature rises with elevation in volume fraction while Velocity decreases with increment in volume fraction. A comparison with previous published results are established and discussed. Moreover, a detailed discussion is made for influence of volume fraction on the flow and heat profile.
Elasticity of Pargasite Amphibole: A Hydrous Phase at Mid Lithospheric Discontinuity
NASA Astrophysics Data System (ADS)
Peng, Y.; Mookherjee, M.
2017-12-01
Mid Lithospheric Discontinuity (MLD) is characterized by a low shear wave velocity ( 3 to 10 %). In cratons, the depth of MLD varies between 80 and 100 km. The reduction of the shear wave velocity at MLD is similar to what is observed in the lithosphere-asthenosphere boundary (LAB). Such low velocity at MLD could be caused by partial melting, temperature induced grain boundary sliding, changes in the elastic anisotropy, and/or metasomatism which may lead to the formation of hydrous phases including mica and amphibole. Thus, it is clear that in order to assess the role of metasomatism at MLD, we need better constraints on the elasticity of hydrous phases. However, such elasticity data are scarce. In this study, we explore elasticity of pargasite amphibole [NaCa2(Mg4Al)(Si6Al2)O22(OH)2] using density functional theory (DFT) with local density approximation (LDA) and generalized gradient approximation (GGA). We find that the pressure-volume results can be adequately described by a finite strain equation with the bulk modulus, K0 being 102 and 85 GPa for LDA and GGA respectively. We also determined the full elastic constant tensor (Cij) using the finite difference method. The bulk modulus, K0 determined from the full elastic constant tensor is 104 GPa for LDA and 87 GPa for GGA. The shear modulus, G0 determined from the full elastic constant tensor is 64 GPa for LDA and 58 GPa for GGA. The bulk and shear moduli predicted with LDA are 5 and 1 % stiffer than the recent results [1]. In contrast, the bulk and shear moduli predicted with GGA are 12 and 10 % softer compared to the recent results [1]. The full elastic constant tensor for pargasite shows significant anisotropy. For instance, LDA predicts compressional (AVP) and shear (AVS) wave anisotropy of 22 and 20 % respectively. At higher pressure, elastic moduli stiffen. However, temperature is likely to have an opposite effect on the elasticity and this remains largely unknown for pargasite. Compared to the major mantle minerals, pargasite has softer elastic constants and significant anisotropy and may explain the reduction in shear wave velocity at MLD. Reference: [1] Brown, J. M., Abramson, E. H.,2016, Phys. Earth Planet. Int., 261, 161-171. Acknowledgement: This work is supported by US NSF award EAR 1639552.
Phase evolution and grain-boundary contributions in CaCu3-xZnxTi4O12
NASA Astrophysics Data System (ADS)
Kwon, Oh Hyeon; Kim, Byeong Kon; Jo, Yeon Hwa; Sankar, Paul Gouri; Jung, Yul Gyo; Jung, Tae Sung; Lee, Jung Won; Cho, Yong Soo
2011-12-01
Extensive substitutions of Zn in Ca(Cu1-xZnx)3Ti4O12 (x = 0, 0.1, 0.5, 1.0 and 2.0) dielectrics are investigated in terms of the phase evolution, dielectric properties and grain boundary resistivity. The composition of CaCu2.9Zn0.1Ti4O12 (x = 0.1) densified at a relatively low sintering temperature of 1000°C showed a k value of approximately 7,000 and a tanδ value of approximately 0.07 at 10 kHz, which is better than the values for pure CaCu3Ti4O12 (CCTO). The improved dielectric properties are also believed to be related to the lower grain boundary resistivity of ˜1676 kΩ.cm, as obtained from a Cole-Cole plot. Beyond this level of Zn, the degradation of the dielectric constant was associated with unexpected crystalline phases, in this case Ca2Zn4Ti16O38, CaTiO3, and Zn2TiO4, which were observed as the level of Zn increased. Although the degradation does not match that of pure CCTO, an addition of Zn up to x=1.0 can hold the dielectric constant at the level of a few thousands, which is still promising compared to other high-k dielectric materials that must be densified below -1000°C to meet the subsequent microcircuit requirements.
NASA Astrophysics Data System (ADS)
Boehlert, C. J.; Dickmann, D. S.; Eisinger, Ny. N. C.
2006-01-01
The grain size, grain boundary character distribution (GBCD), creep, and tensile behavior of INCONEL alloy 718 (IN 718) were characterized to identify processing-microstructure-property relationships. The alloy was sequentially cold rolled (CR) to 0, 10, 20, 30, 40, 60, and 80 pct followed by annealing at temperatures between 954 °C and 1050 °C and the traditional aging schedule used for this alloy. In addition, this alloy can be superplastically formed (IN 718SPF) to a significantly finer grain size and the corresponding microstructure and mechanical behavior were evaluated. The creep behavior was evaluated in the applied stress (σ a ) range of 300 to 758 MPa and the temperature range of 638 °C to 670 °C. Constant-load tensile creep experiments were used to measure the values of the steady-state creep rate and the consecutive load reduction method was used to determine the values of backstress (σ0). The values for the effective stress exponent and activation energy suggested that the transition between the rate-controlling creep mechanisms was dependent on effective stresses (σ e =σ a σ0) and the transition occurred at σ e ≅ 135 MPa. The 10 to 40 pct CR samples exhibited the greatest 650 °C strength, while IN 718SPF exhibited the greatest room-temperature (RT) tensile strength (>1550 MPa) and ductility (ɛ f >16 pct). After the 954 °C annealing treatment, the 20 pct CR and 30 pct CR microstructures exhibited the most attractive combination of elevated-temperature tensile and creep strength, while the most severely cold-rolled materials exhibited the poorest elevated-temperature properties. After the 1050 °C annealing treatment, the IN 718SPF material exhibited the greatest backstress and best creep resistance. Electron backscattered diffraction was performed to identify the GBCD as a function of CR and annealing. The data indicated that annealing above 1010 °C increased the grain size and resulted in a greater fraction of twin boundaries, which in turn increased the fraction of coincident site lattice boundaries. This result is discussed in light of the potential to grain boundary engineer this alloy.
Direct simulation of isothermal-wall supersonic channel flow
NASA Technical Reports Server (NTRS)
Coleman, Gary N.
1993-01-01
The motivation for this work is the fact that in turbulent flows where compressibility effects are important, they are often poorly understood. A few examples of such flows are those associated with astrophysical phenomena and those found in combustion chambers, supersonic diffusers and nozzles, and over high-speed airfoils. For this project, we are primarily interested in compressibility effects near solid surfaces. Our main objective is an improved understanding of the fundamentals of compressible wall-bounded turbulence, which can in turn be used to cast light upon modeling concepts such as the Morkovin hypothesis and the Van Driest transformation. To this end, we have performed a direct numerical simulation (DNS) study of supersonic turbulent flow in a plane channel with constant-temperature walls. All of the relevant spatial and temporal scales are resolved so that no sub grid scale or turbulence model is necessary. The channel geometry was chosen so that finite Mach number effects can be isolated by comparing the present results to well established incompressible channel data. Here the fluid is assumed to be an ideal gas with constant specific heats, constant Prandtl number, and power-law temperature-dependent viscosity. Isothermal-wall boundary conditions are imposed so that a statistically stationary state may be obtained. The flow is driven by a uniform (in space) body force (rather than a mean pressure gradient) to preserve stream wise homogeneity, with the body force defined so that the total mass flux is constant.
NASA Astrophysics Data System (ADS)
Debnath, Rajesh; Mandal, S. K.; Dey, P.; Nath, A.
2018-04-01
We have investigated strain mediated magnetoelectric coupling and ac electrical properties of 0.5La0.7Sr0.3MnO3-0.5 Polyvinylidene Fluoride nanocomposites at room temperature. The sample has been prepared through low temperature pyrophoric chemical process. The detailed study of X-ray diffraction pattern shows simultaneous co-existence of two phases of nanometric grains. Field emission scanning electron micrograph shows the absence of any phase segregation and good chemical homogeneity in composites. The magnetoelectric voltage is measured in both longitudinal and transverse direction at a frequency of 73 Hz. The magnetoelectric coefficient in transverse direction is found to ˜0.17 mV/cmOe and in longitudinal direction it is found to ˜0.08 mV/cmOe. With the application of dc magnetic field the real and imaginary part of impedance are increased where the dielectric constant has been decreased. Nyquist plots have been fitted using two parallel combinations of resistances - constant phase element circuits considering dominant role of grains and grain boundaries resistance in the conduction process of the sample.
Wide-temperature integrated operational amplifier
NASA Technical Reports Server (NTRS)
Mojarradi, Mohammad (Inventor); Levanas, Greg (Inventor); Chen, Yuan (Inventor); Cozy, Raymond S. (Inventor); Greenwell, Robert (Inventor); Terry, Stephen (Inventor); Blalock, Benjamin J. (Inventor)
2009-01-01
The present invention relates to a reference current circuit. The reference circuit comprises a low-level current bias circuit, a voltage proportional-to-absolute temperature generator for creating a proportional-to-absolute temperature voltage (VPTAT), and a MOSFET-based constant-IC regulator circuit. The MOSFET-based constant-IC regulator circuit includes a constant-IC input and constant-IC output. The constant-IC input is electrically connected with the VPTAT generator such that the voltage proportional-to-absolute temperature is the input into the constant-IC regulator circuit. Thus the constant-IC output maintains the constant-IC ratio across any temperature range.
NASA Astrophysics Data System (ADS)
Song, H. Y.; An, M. R.; Li, Y. L.; Deng, Q.
2014-12-01
The mechanical properties of a super-lattice architecture composed of nanocrystalline Mg and Mg-Al amorphous alloy are investigated using molecular dynamics simulation. The results indicate that deformation mechanism of nanocrystalline Mg is obviously affected by the amorphous boundary spacing and temperature. The strength of the material increases with the decrease of amorphous boundary spacing, presenting a Hall-Petch effect at both 10 K and 300 K. A stress platform and following stiffness softening, as well as a linear strengthening in the plastic stage, are observed when the amorphous boundary spacing below 8.792 nm at 10 K. The implying reason may be that the amorphous boundary acts as the dislocations emission and absorption source. However, the second stress peak is not observed for the models at 300 K. Instead, the flow stress in plastic stage is a nearly constant value. The simulation demonstrates the emergence of the new grain, accompanied by the deformation twins and stacking faults associated with the plastic behaviors at 300 K. The general conclusions derived from this work may provide a guideline for the design of high-performance hexagonal close-packed metals.
NASA Astrophysics Data System (ADS)
Gélat, Pierre; Joly, Nicolas; de Podesta, Michael; Sutton, Gavin; Underwood, Robin
2009-11-01
iMERA/Euromet Project 885 is co-ordinating European effort towards a new determination of the Boltzmann constant kB to within 1 ppm with the aim of redefining the unit of thermodynamic temperature. This project will enable the National Physical Laboratory to perform primary thermometry in the region of -40 °C (Hg) to 156 °C (In) with sub-millikelvin uncertainties by 2012. The chosen technique relies on determining the speed of sound in a monatomic gas. Using the radial acoustic modes of a spherical resonator, consisting of a copper shell and filled with argon or helium, the speed of sound can be measured with great precision and from this measurement the Boltzmann constant can be inferred. This project draws on expertise in dimensional, density, microwave and acoustic measurements at the state-of-the-art. In order to gain further understanding of the experimental configuration a vibro-acoustic model has been developed using the finite element method. Initial calculations were carried out to ensure that predictions of the resonant frequency could be made with the required precision by comparing against an analytical model of a spherical shell filled with a gas. A more elaborate model better representing the experimental configuration was then developed. Thermo-viscous effects close to the fluid-structure boundary were accounted for using a linear acoustic formulation, from which a normal incidence admittance boundary condition was derived and imposed on the inner surface of the resonator. Acoustic pressure, particle velocity and temperature variation as a function of position may be obtained within the gas as a function of frequency. It is therefore possible to investigate how changes in the configuration affect the frequency of radial modes. It is hoped that this approach will shed a better understanding of the underlying complex physical phenomena allowing a minimization of the overall uncertainty.
NASA Astrophysics Data System (ADS)
Sasaki, Youhei; Takehiro, Shin-ichi; Ishiwatari, Masaki; Yamada, Michio
2018-03-01
Linear stability analysis of anelastic thermal convection in a rotating spherical shell with entropy diffusivities varying in the radial direction is performed. The structures of critical convection are obtained in the cases of four different radial distributions of entropy diffusivity; (1) κ is constant, (2) κT0 is constant, (3) κρ0 is constant, and (4) κρ0T0 is constant, where κ is the entropy diffusivity, T0 is the temperature of basic state, and ρ0 is the density of basic state, respectively. The ratio of inner and outer radii, the Prandtl number, the polytropic index, and the density ratio are 0.35, 1, 2, and 5, respectively. The value of the Ekman number is 10-3 or 10-5 . In the case of (1), where the setup is same as that of the anelastic dynamo benchmark (Jones et al., 2011), the structure of critical convection is concentrated near the outer boundary of the spherical shell around the equator. However, in the cases of (2), (3) and (4), the convection columns attach the inner boundary of the spherical shell. A rapidly rotating annulus model for anelastic systems is developed by assuming that convection structure is uniform in the axial direction taking into account the strong effect of Coriolis force. The annulus model well explains the characteristics of critical convection obtained numerically, such as critical azimuthal wavenumber, frequency, Rayleigh number, and the cylindrically radial location of convection columns. The radial distribution of entropy diffusivity, or more generally, diffusion properties in the entropy equation, is important for convection structure, because it determines the distribution of radial basic entropy gradient which is crucial for location of convection columns.
Thermocouple Boundary Layer Rake
NASA Technical Reports Server (NTRS)
Hwang, Danny P. (Inventor); Will, Herbert A. (Inventor); Fralick, Gustave C. (Inventor)
2002-01-01
Apparatus and method for providing a velocity flow profile near a reference surface. A measuring device utilizes a plurality of thermojunction pairs to provide the velocity flow profile in accordance with behavior of a gas relative to a constant thickness strut which stands vertically from the reference surface such that the span is normal to the surface, and the chord is parallel to the surface along the initial flow direction. Each thermojunction is carried on either side of a heater formed on a measuring surface in a constant thickness portion of a strut. Additionally, each thermojunction of a given pair is located at a predetermined height from the reference surface. Gas velocity data obtained from temperature differentials from one side of the heater to the other at each successive height is utilized to generate the velocity and turbulence level profiles.
NASA Astrophysics Data System (ADS)
Gryaznov, D.; Fleig, J.; Maier, J.
2008-03-01
Whipple's solution of the problem of grain boundary diffusion and Le Claire's relation, which is often used to determine grain boundary diffusion coefficients, are examined for a broad range of ratios of grain boundary to bulk diffusivities Δ and diffusion times t. Different reasons leading to errors in determining the grain boundary diffusivity (DGB) when using Le Claire's relation are discussed. It is shown that nonlinearities of the diffusion profiles in lnCav-y6/5 plots and deviations from "Le Claire's constant" (-0.78) are the major error sources (Cav=averaged concentration, y =coordinate in diffusion direction). An improved relation (replacing Le Claire's constant) is suggested for analyzing diffusion profiles particularly suited for small diffusion lengths (short times) as often required in diffusion experiments on nanocrystalline materials.
NASA Astrophysics Data System (ADS)
Pradhan, Lagen Kumar; Pandey, Rabichandra; Kumar, Sunil; Supriya, Sweety; Kar, Manoranjan
2018-04-01
Effect of lattice distortion on diffuse phase transition in BNBTO solid solutions near Morphotropic phase boundary (MPB) has been investigated. Solid solutions of (Bi0.5Na0.5)1-xBaxTiO3 (with mole % of x= 0.04, 0.05, 0.06, 0.07 and 0.08) were prepared by the planetary ball mill method in ethanol medium. Rietveld refinement technique with rhombohedral (R3c) and tetragonal (P4bm) crystal symmetry has been employed for structural as well as phase analysis of the solid solutions. Both rhombohedral and tetragonal lattice distortion (c/a) tends toward the pseudo-cubic crystal symmetry with the increase of mole fraction of Ba2+ near MPB (x= 6 mole %). Also, the average crystallite size and grain size decrease with increase of mole fraction of Ba2+ in BNT ceramic are due to larger ionic radius of Ba2+ and grain boundary pinning process in the solid solutions respectively. Additionally, depolarization temperature (Td) and maximum temperature (Tm) reduces due to the lattice distortion of both the phases in BNBTO solid solutions, which is explained extensively. Significant increase of dielectric constant has been observed near MPB composition (x=6%) in BNBTO solid solutions.
Transitional properties of supersolitons in a two electron temperature warm multi-ion plasma
DOE Office of Scientific and Technical Information (OSTI.GOV)
Varghese, Steffy S., E-mail: steffy13@iigs.iigm.res.in; Ghosh, S. S., E-mail: sukti@iigs.iigm.res.in
The existence domain of an ion acoustic supersoliton and its transition to a regular kind of solitary wave have been explored in detail using Sagdeev pseudopotential technique for a two electron temperature warm multi-ion plasma having two species of ions. It was found that both the cold to hot electron temperature ratio and their respective ambient densities play a deterministic role for the existence of a supersoliton, as well as its transitional processes to a regular solitary wave. Analogous to a double layer solution, which often marks the boundary of the existence domain of a regular solitary wave, a “curvemore » of inflection” determines the boundary of the existence domain of a supersoliton. The characteristics of the “curve of inflection,” in turn, depend on the respective concentrations of the two ion species. It is observed that the supersolitons are actually a subset of a more general kind of solutions which are characterized by a fluctuation in the corresponding charge separation which precedes their maximum amplitude. It is also observed that these novel kinds of solitary structures, including supersolitons, occur only for a very narrow range of parameters near constant amplitude beyond which the wave breaks.« less
Portrait of a Geothermal Spring, Hunter's Hot Springs, Oregon.
Castenholz, Richard W
2015-01-27
Although alkaline Hunter's Hot Springs in southeastern Oregon has been studied extensively for over 40 years, most of these studies and the subsequent publications were before the advent of molecular methods. However, there are many field observations and laboratory experiments that reveal the major aspects of the phototrophic species composition within various physical and chemical gradients of these springs. Relatively constant temperature boundaries demark the upper boundary of the unicellular cyanobacterium, Synechococcus at 73-74 °C (the world-wide upper limit for photosynthesis), and 68-70 °C the upper limit for Chloroflexus. The upper limit for the cover of the filamentous cyanobacterium, Geitlerinema (Oscillatoria) is at 54-55 °C, and the in situ lower limit at 47-48 °C for all three of these phototrophs due to the upper temperature limit for the grazing ostracod, Thermopsis. The in situ upper limit for the cyanobacteria Pleurocapsa and Calothrix is at ~47-48 °C, which are more grazer-resistant and grazer dependent. All of these demarcations are easily visible in the field. In addition, there is a biosulfide production in some sections of the springs that have a large impact on the microbiology. Most of the temperature and chemical limits have been explained by field and laboratory experiments.
Portrait of a Geothermal Spring, Hunter’s Hot Springs, Oregon
Castenholz, Richard W.
2015-01-01
Although alkaline Hunter’s Hot Springs in southeastern Oregon has been studied extensively for over 40 years, most of these studies and the subsequent publications were before the advent of molecular methods. However, there are many field observations and laboratory experiments that reveal the major aspects of the phototrophic species composition within various physical and chemical gradients of these springs. Relatively constant temperature boundaries demark the upper boundary of the unicellular cyanobacterium, Synechococcus at 73–74 °C (the world-wide upper limit for photosynthesis), and 68–70 °C the upper limit for Chloroflexus. The upper limit for the cover of the filamentous cyanobacterium, Geitlerinema (Oscillatoria) is at 54–55 °C, and the in situ lower limit at 47–48 °C for all three of these phototrophs due to the upper temperature limit for the grazing ostracod, Thermopsis. The in situ upper limit for the cyanobacteria Pleurocapsa and Calothrix is at ~47–48 °C, which are more grazer-resistant and grazer dependent. All of these demarcations are easily visible in the field. In addition, there is a biosulfide production in some sections of the springs that have a large impact on the microbiology. Most of the temperature and chemical limits have been explained by field and laboratory experiments. PMID:25633225
NASA Astrophysics Data System (ADS)
Duynkerke, P. G.
1988-03-01
In the E - turbulence model an eddy-exchange coefficient is evaluated from the turbulent kinetic energy E and viscous dissipation . In this study we will apply the E - model to the stable and neutral atmospheric boundary layer. A discussion is given on the equation for , which terms should be included and how we have evaluated the constants. Constant cooling rate results for the stable atmospheric boundary layer are compared with a second-order closure study. For the neutral atmospheric boundary layer a comparison is made with observations, large-eddy simulations and a second-order closure study. It is shown that a small stability effect can change the neutral atmospheric boundary layer quite drastically, and therefore, it will be difficult to observe a neutral boundary layer in the atmosphere.
Irreversible Brownian Heat Engine
NASA Astrophysics Data System (ADS)
Taye, Mesfin Asfaw
2017-10-01
We model a Brownian heat engine as a Brownian particle that hops in a periodic ratchet potential where the ratchet potential is coupled with a linearly decreasing background temperature. We show that the efficiency of such Brownian heat engine approaches the efficiency of endoreversible engine η =1-√{{Tc/Th}} [23]. On the other hand, the maximum power efficiency of the engine approaches η ^{MAX}=1-({Tc/Th})^{1\\over 4}. It is shown that the optimized efficiency always lies between the efficiency at quasistatic limit and the efficiency at maximum power while the efficiency at maximum power is always less than the optimized efficiency since the fast motion of the particle comes at the expense of the energy cost. If the heat exchange at the boundary of the heat baths is included, we show that such a Brownian heat engine has a higher performance when acting as a refrigerator than when operating as a device subjected to a piecewise constant temperature. The role of time on the performance of the motor is also explored via numerical simulations. Our numerical results depict that the time t and the external load dictate the direction of the particle velocity. Moreover, the performance of the heat engine improves with time. At large t (steady state), the velocity, the efficiency and the coefficient of performance of the refrigerator attain their maximum value. Furthermore, we study the effect of temperature by considering a viscous friction that decreases exponentially as the background temperature increases. Our result depicts that the Brownian particle exhibits a fast unidirectional motion when the viscous friction is temperature dependent than that of constant viscous friction. Moreover, the efficiency of this motor is considerably enhanced when the viscous friction is temperature dependent. On the hand, the motor exhibits a higher performance of the refrigerator when the viscous friction is taken to be constant.
Dielectric behavior and AC conductivity of Cr doped α-Mn2O3
NASA Astrophysics Data System (ADS)
Chandra, Mohit; Yadav, Satish; Singh, K.
2018-05-01
The complex dielectric behavior of polycrystalline α-Mn2-xCrxO3 (x = 0.10) has been investigated isothermally at wide frequency range (4Hz-1 MHz) at different temperatures (300-390K). The dielectric spectroscopy results have been discussed in different formulism like dielectric constant, impedance and ac conductivity. The frequency dependent dielectric loss (tanδ) exhibit a clear relaxation behavior in the studied temperature range. The relaxation frequency increases with increasing temperature. These results are fitted using Arrhenius equation which suggest thermally activated process and the activation energy is 0.173±0.0024 eV. The normalized tanδ curves at different temperatures merge as a single master curve which indicate that the relaxation process follow the similar relaxation dynamics in the studied temperature range. Further, the dielectric relaxation follows non-Debye behavior. The impedance results inference that the grain boundary contribution dominate at lower frequency whereas grain contribution appeared at higher frequencies and exhibit strong temperature dependence. The ac conductivity data shows that the ac conductivity increases with increasing temperature which corroborate the semiconducting nature of the studied sample.
NASA Astrophysics Data System (ADS)
Afonina, Natalie Petrovna
To withstand the high temperature (>700°C) and pressure demands of steam turbines and boilers used for energy applications, metal alloys must be economically viable and have the necessary material properties, such as high-temperature creep strength, oxidation and corrosion resistance, to withstand such conditions. One promising class of alloys potentially capable of withstanding the rigors of aggressive environments, are alumina-forming austenitic stainless steels (AFAs) alloyed with aluminum to improve corrosion and oxidation resistance. The effect of aging on the microstructure, high temperature constant-stress creep behavior and mechanical properties of the AFA-type alloy Fe-20Cr-30Ni-2Nb-5Al (at.%) were investigated in this study. The alloy's microstructural evolution with increased aging time was observed prior to creep testing. As aging time increased, the alloy exhibited increasing quantities of fine Fe2Nb Laves phase dispersions, with a precipitate-free zone appearing in samples with higher aging times. The presence of the L1 2 phase gamma'-Ni3Al precipitate was detected in the alloy's matrix at 760°C. A constant-stress creep rig was designed, built and its operation validated. Constant-stress creep tests were performed at 760°C and 35MPa, and the effects of different aging conditions on creep rate were investigated. Specimens aged for 240 h exhibited the highest creep rate by a factor of 5, with the homogenized sample having the second highest rate. Samples aged for 2.4 h and 24 h exhibited similar low secondary creep rates. Creep tests conducted at 700oC exhibited a significantly lower creep rate compared to those at 760oC. Microstructural analysis was performed on crept samples to explore high temperature straining properties. The quantity and size of Fe2Nb Laves phase and NiAl particles increased in the matrix and on grain boundaries with longer aging time. High temperature tensile tests were performed and compared to room temperature results. The high temperature results were significantly lower when compared to room temperature values. Higher creep rates were correlated with lower yield strengths.
Adjoint-based constant-mass partial derivatives
Favorite, Jeffrey A.
2017-09-01
In transport theory, adjoint-based partial derivatives with respect to mass density are constant-volume derivatives. Likewise, adjoint-based partial derivatives with respect to surface locations (i.e., internal interface locations and the outer system boundary) are constant-density derivatives. This study derives the constant-mass partial derivative of a response with respect to an internal interface location or the outer system boundary and the constant-mass partial derivative of a response with respect to the mass density of a region. Numerical results are given for a multiregion two-dimensional (r-z) cylinder for three very different responses: the uncollided gamma-ray flux at an external detector point, k effmore » of the system, and the total neutron leakage. Finally, results from the derived formulas compare extremely well with direct perturbation calculations.« less
FRACTURE BEHAVIOR OF ALLOY 600, ALLOY 690, EN82H WELDS AND EN52 WELDS IN WATER
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mills, W.J., Brown, C.M. and Burke, M.G.
2000-01-11
The cracking resistance of Alloy 600, Alloy 690 and their welds, EN82H and EN52, was characterized by conducting J{sub IC} rising load tests in air and hydrogenated water and cooldown testing in water under constant-displacement conditions. All test materials displayed excellent toughness in air and high temperature water, but Alloy 690 and the two welds were severely embrittled in low temperature water. In 54 C water with 150 cc H{sub 2}/kg H{sub 2}O, J{sub IC} values were reduced by 70% to 95%, relative to their air counterpart. The toughness degradation was associated with a fracture mechanism transition from microvoid coalescencemore » to intergranular fracture. Comparison of the cracking response in water with that for hydrogen-precharged specimens tested in air demonstrated that susceptibility to low temperature crack propagation (LTCP) is due to hydrogen embrittlement of grain boundaries. The effects of water temperature, hydrogen content and loading rate on LTCP were studied. In addition, testing of specimens containing natural weld defects and as-machined notches was performed to determine if low temperature cracking can initiate at these features. Unlike the other materials, Alloy 600 is not susceptible to LTCP as the toughness in 54 C water remained high and a microvoid coalescence mechanism was operative in both air and water. Cooldown testing of EN82H welds under constant-displacement conditions was performed to determine if LTCP data from rising load J{sub IC}/K{sub Pmax} tests predict the onset of LTCP for other load paths. In these tests, bolt-loaded CT specimens were subjected to 288 C water for up to 1 week, cooled to 54 C and held in 54 C hydrogenated water for 1 week. This cycle was repeated up to 6 times. For two of the three welds tested, critical K{sub I} levels for LTCP under constant-displacement conditions were much higher than rising load K{sub Pmax} values. Bolt-loaded specimens from a third weld were found to exhibit LTCP at K{sub I} levels comparable to K{sub Pmax} values. Although work to date indicates that rising load tests either accurately or conservatively predict the critical conditions for LTCP under constant displacement conditions, the potential for LTCP at K{sub I} levels less than K{sub Pmax} has not been fully evaluated. Annealing at 1093 C reduces or eliminates LTCP susceptibility. The microstructure and mechanical properties for susceptible and nonsusceptible EN82H welds were characterized to identify the key material parameters responsible for LTCP in the as-welded condition. The key microstructural feature associated with LTCP appears to be fine Nb- and Ti-rich carbonitrides decorating grain boundaries. In addition, the higher yield strength for the as-fabricated weld also promotes LTCP because it increases stresses and local hydrogen concentrations ahead of a crack.« less
On the Boundary Condition Between Two Multiplying Media
DOE R&D Accomplishments Database
Friedman, F. L.; Wigner, E. P.
1944-04-19
The transition region between two parts of a pile which have different compositions is investigated. In the case where the moderator is the same in both parts of the pile, it is found that the diffusion constant times thermal neutron density plus diffusion constant times fast neutron density satisfies the usual pile equations everywhere, right to the boundary. More complicated formulae apply in a more general case.
NASA Astrophysics Data System (ADS)
Shao, Yi; Liu, Chenxi; Yue, Tengxiao; Liu, Yongchang; Yan, Zesheng; Li, Huijun
2018-05-01
The 00Cr12 ferritic stainless steel samples were isothermally held at different temperatures in the range of 700 °C to 1000 °C to investigate the effect of static recrystallization and precipitation on mechanical properties, such as microhardness, tensile strength, and yield strength. The results show that the formation of the fine recrystallized grain, as well as precipitation, coarsening, and dissolution of the second-phase particles, influences the mechanical properties remarkably. The fine recrystallized grain can provide a positive grain boundary-strengthening effect in the sample under a relatively high holding temperature. Coarsening and dissolution of M23C6 result in partial depletion of precipitate hardening. In contrast, the size and number density of MX particles are almost constant, regardless of the holding temperature; therefore, it can provide a better precipitation-hardening effect.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parks, G. K.; Lin, N.; Lee, E.
2013-07-10
Two of the many features associated with nonlinear upstream structures are (1) the solar wind (SW) mean flow slows down and deviates substantially and (2) the temperature of the plasma increases in the structure. In this Letter, we show that the SW beam can be present throughout the entire upstream event maintaining a nearly constant beam velocity and temperature. The decrease of the velocity is due to the appearance of new particles moving in the opposite direction that act against the SW beam and reduce the mean velocity as computed via moments. The new population, which occupies a larger velocitymore » space, also contributes to the second moment, increasing the temperature. The new particles include the reflected SW beam at the bow shock and another population of lower energies, accelerated nearby at the shock or at the boundary of the nonlinear structures.« less
Effect of inhomogeneity due to temperature on the propagation of shear waves in an anisotropic layer
NASA Astrophysics Data System (ADS)
Prasad, Bishwanath; Pal, Prakash Chandra; Kundu, Santimoy; Prasad, Narayan
2017-07-01
The present paper is concerned with the propagation of shear waves in an anisotropic inhomogeneous layer whose elastic constants are functions of temperature. The dependence of material properties on temperature gives rise to inhomogeneity of the layer which is one of the trivial characteristics of the constituent layers of earth which may cause due to the presence of various types of elements and compounds beneath the earth. The layer is lying over a rigid foundation and there is no loading on the upper boundary. The dispersion equation of shear waves has been obtained in closed form. Numerical computations are performed and graphs are plotted to show the effect of inhomogeneity and anisotropy factors on the dimensionless phase velocity. It is found that the phase velocity is considerably influenced by the inhomogeneity and anisotropy of the layer.
Dynamics of a molecular glass former: Energy landscapes for diffusion in ortho-terphenyl
NASA Astrophysics Data System (ADS)
Niblett, S. P.; de Souza, V. K.; Stevenson, J. D.; Wales, D. J.
2016-07-01
Relaxation times and transport processes of many glass-forming supercooled liquids exhibit a super-Arrhenius temperature dependence. We examine this phenomenon by computer simulation of the Lewis-Wahnström model for ortho-terphenyl. We propose a microscopic definition for a single-molecule cage-breaking transition and show that, when correlation behaviour is taken into account, these rearrangements are sufficient to reproduce the correct translational diffusion constants over an intermediate temperature range in the supercooled regime. We show that super-Arrhenius behaviour can be attributed to increasing negative correlation in particle movement at lower temperatures and relate this to the cage-breaking description. Finally, we sample the potential energy landscape of the model and show that it displays hierarchical ordering. Substructures in the landscape, which may correspond to metabasins, have boundaries defined by cage-breaking transitions. The cage-breaking formulation provides a direct link between the potential energy landscape and macroscopic diffusion behaviour.
Thermal performance of a Concrete Cool Roof under different climatic conditions of Mexico
Hernández-Pérez, I.; Álvarez, G.; Gilbert, H.; ...
2014-11-27
A cool roof is an ordinary roof with a reflective coating on the exterior surface which has a high solar reflectance and high thermal emittance. These properties let the roof keep a lower temperature than a standard roof under the same conditions. In this work, the thermal performance of a concrete roof with and without insulation and with two colors has been analyzed using the finite volume method. The boundary conditions of the external roof surface were taken from hourly averaged climatic data of four cities. For the internal surface, it is considered that the building is air-conditioned and themore » inside air has a constant temperature. The interior surface temperature and the heat flux rates into the roofs were obtained for two consecutive days in order to assess the benefits of a cool roofs in different climates.« less
Heating-insensitive scale increase caused by convective precipitation
NASA Astrophysics Data System (ADS)
Haerter, Jan; Moseley, Christopher; Berg, Peter
2017-04-01
The origin of intense convective extremes and their unusual temperature dependence has recently challenged traditional thermodynamic arguments, based on the Clausius-Clapeyron relation. In a sequence of studies (Lenderink and v. Mejgaard, Nat Geosc, 2008; Berg, Haerter, Moseley, Nat Geosc, 2013; and Moseley, Hohenegger, Berg, Haerter, Nat Geosc, 2016) the argument of convective-type precipitation overcoming the 7%/K increase in extremes by dynamical, rather than thermodynamic, processes has been promoted. How can the role of dynamical processes be approached for precipitating convective cloud? One-phase, non-precipitating Rayleigh-Bénard convection is a classical problem in complex systems science. When a fluid between two horizontal plates is sufficiently heated from below, convective rolls spontaneously form. In shallow, non-precipitating atmospheric convection, rolls are also known to form under specific conditions, with horizontal scales roughly proportional to the boundary layer height. Here we explore within idealized large-eddy simulations, how the scale of convection is modified, when precipitation sets in and intensifies in the course of diurnal solar heating. Before onset of precipitation, Bénard cells with relatively constant diameter form, roughly on the scale of the atmospheric boundary layer. We find that the onset of precipitation then signals an approximately linear (in time) increase in horizontal scale. This scale increase progresses at a speed which is rather insensitive to changes in surface temperature or changes in the rate at which boundary conditions change, hinting at spatial characteristics, rather than temperature, as a possible control on spatial scales of convection. When exploring the depth of spatial correlations, we find that precipitation onset causes a sudden disruption of order and a subsequent complete disintegration of organization —until precipitation eventually ceases. Returning to the initial question of convective extremes, we conclude that the formation of extreme events is a highly nonlinear process. However, our results suggest that crucial features of convective organization throughout the day may be independent of temperature - with possible implications for large-scale model parameterizations. Yet, the timing of the onset of initial precipitation depends strongly on the temperature boundary conditions, where higher temperatures, or earlier, moderate heating, lead to earlier initiation of convection and hence allow for more time for development and the production of extremes.
Cyclic phase change in a cylindrical thermal energy storage capsule
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hasan, M.; Mujumdar, A.S.; Weber, M.E.
1983-12-01
This paper is concerned with a practical melting/freezing problem in conjunction with the more realistic case of a cyclic phase change thermal energy storage device. In this model the phase change medium is encapsulated in long cylindrical tubes, the surface temperature of which is allowed to vary sinusoidally with time about the discrete freezing temperature. Initial temperature of the medium is assumed to be constant at a temperature above or below the freezing/melting temperature. Natural convection in the melt is assumed to be negligible and the variations in the depth of freezing and/or melting in each half cycle is ignored.more » Depending on the half-cycle parameters the problem is simplified to either freezing or melting. The governing one-dimensional heat diffusion equations for both phases are solved by the Finite Integral Transform techniques. The kernels for the transformation are the time-dependent eigen functions separately defined for each phases. This extended transform method can accomodate any time-dependent surface temperature variation. The application of the transform generated a series of coupled, nonlinear first order differential equations, which are solved by Runge Kutta-Verner fifth and sixth order method. Dimensionless solutions of temperature variations in both phases, fusion front position and the fraction solidified (or melted) are displayed graphically to aid in practical calculations. For the special case of a constant surface temperature, comparisons are made between the present results and the existing integral and purely numerical results. The results are found to compare favourably. Results for fractional solidification (or melting and interface position are also compared with the simple Conduction Shape Factor method, after allowing for the time-dependent boundary conditions. Once again the results agree reasonably well.« less
Athermal brittle-to-ductile transition in amorphous solids.
Dauchot, Olivier; Karmakar, Smarajit; Procaccia, Itamar; Zylberg, Jacques
2011-10-01
Brittle materials exhibit sharp dynamical fractures when meeting Griffith's criterion, whereas ductile materials blunt a sharp crack by plastic responses. Upon continuous pulling, ductile materials exhibit a necking instability that is dominated by a plastic flow. Usually one discusses the brittle to ductile transition as a function of increasing temperature. We introduce an athermal brittle to ductile transition as a function of the cutoff length of the interparticle potential. On the basis of extensive numerical simulations of the response to pulling the material boundaries at a constant speed we offer an explanation of the onset of ductility via the increase in the density of plastic modes as a function of the potential cutoff length. Finally we can resolve an old riddle: In experiments brittle materials can be strained under grip boundary conditions and exhibit a dynamic crack when cut with a sufficiently long initial slot. Mysteriously, in molecular dynamics simulations it appeared that cracks refused to propagate dynamically under grip boundary conditions, and continuous pulling was necessary to achieve fracture. We argue that this mystery is removed when one understands the distinction between brittle and ductile athermal amorphous materials.
Diffusion induced atomic islands on the surface of Ni/Cu nanolayers
NASA Astrophysics Data System (ADS)
Takáts, Viktor; Csik, Attila; Hakl, József; Vad, Kálmán
2018-05-01
Surface islands formed by grain-boundary diffusion has been studied in Ni/Cu nanolayers by in-situ low energy ion scattering spectroscopy, X-ray photoelectron spectroscopy, scanning probe microscopy and ex-situ depth profiling based on ion sputtering. In this paper a new experimental approach of measurement of grain-boundary diffusion coefficients is presented. Appearing time of copper atoms diffused through a few nanometer thick nickel layer has been detected by low energy ion scattering spectroscopy with high sensitivity. The grain-boundary diffusion coefficient can be directly calculated from this appearing time without using segregation factors in calculations. The temperature range of 423-463 K insures the pure C-type diffusion kinetic regime. The most important result is that surface coverage of Ni layer by Cu atoms reaches a maximum during annealing and stays constant if the annealing procedure is continued. Scanning probe microscopy measurements show a Volmer-Weber type layer growth of Cu layer on the Ni surface in the form of Cu atomic islands. Depth distribution of Cu in Ni layer has been determined by depth profile analysis.
NASA Astrophysics Data System (ADS)
Sullivan, Peter P.; McWilliams, James C.; Melville, W. Kendall
2004-05-01
We devise a stochastic model for the effects of breaking waves and fit its distribution functions to laboratory and field data. This is used to represent the space time structure of momentum and energy forcing of the oceanic boundary layer in turbulence-resolving simulations. The aptness of this breaker model is evaluated in a direct numerical simulation (DNS) of an otherwise quiescent fluid driven by an isolated breaking wave, and the results are in good agreement with laboratory measurements. The breaker model faithfully reproduces the bulk features of a breaking event: the mean kinetic energy decays at a rate approaching t(-1) , and a long-lived vortex (eddy) is generated close to the water surface. The long lifetime of this vortex (more than 50 wave periods) makes it effective in energizing the surface region of oceanic boundary layers. Next, a comparison of several different DNS of idealized oceanic boundary layers driven by different surface forcing (i.e. constant current (as in Couette flow), constant stress, or a mixture of constant stress plus stochastic breakers) elucidates the importance of intermittent stress transmission to the underlying currents. A small amount of active breaking, about 1.6% of the total water surface area at any instant in time, significantly alters the instantaneous flow patterns as well as the ensemble statistics. Near the water surface a vigorous downwelling upwelling pattern develops at the head and tail of each three-dimensional breaker. This enhances the vertical velocity variance and generates both negative- and positive-signed vertical momentum flux. Analysis of the mean velocity and scalar profiles shows that breaking effectively increases the surface roughness z_o by more than a factor of 30; for our simulations z_o/lambda {≈} 0.04 to 0.06, where lambda is the wavelength of the breaking wave. Compared to a flow driven by a constant current, the extra mixing from breakers increases the mean eddy viscosity by more than a factor of 10 near the water surface. Breaking waves alter the usual balance of production and dissipation in the turbulent kinetic energy (TKE) budget; turbulent and pressure transports and breaker work are important sources and sinks in the budget. We also show that turbulent boundary layers driven by constant current and constant stress (i.e. with no breaking) differ in fundamental ways. The additional freedom provided by a constant-stress boundary condition permits finite velocity variances at the water surface, so that flows driven by constant stress mimic flows with weakly and statistically homogeneous breaking waves.
Mechanistic basis of temperature-dependent dwell fatigue in titanium alloys
NASA Astrophysics Data System (ADS)
Zheng, Zebang; Balint, Daniel S.; Dunne, Fionn P. E.
2017-10-01
The temperature-dependent dwell sensitivity of Ti-6242 and Ti-6246 alloys has been assessed over a temperature range from - 50∘ C to 390 °C using discrete dislocation plasticity which incorporates both thermal activation of dislocation escape from obstacles and slip transfer across grain boundaries. The worst-case load shedding in Ti-6242 alloy is found to be at or close to 120 °C under dwell fatigue loading, which diminishes and vanishes at temperatures lower than - 50∘ C or higher than 230 °C. Load shedding behaviour is predicted to occur in alloy Ti-6246 also but over a range of higher temperatures which are outside those relevant to in-service conditions. The key controlling dislocation mechanism with respect to load shedding in titanium alloys, and its temperature sensitivity, is shown to be the time constant associated with the thermal activation of dislocation escape from obstacles, with respect to the stress dwell time. The mechanistic basis of load shedding and dwell sensitivity in dwell fatigue loading is presented and discussed in the context of experimental observations.
Heat transfer enhancement by application of nano-powder
NASA Astrophysics Data System (ADS)
Mosavian, M. T. Hamed; Heris, S. Zeinali; Etemad, S. Gh.; Esfahany, M. Nasr
2010-09-01
In this investigation, laminar flow heat transfer enhancement in circular tube utilizing different nanofluids including Al2O3 (20 nm), CuO (50 nm), and Cu (25 nm) nanoparticles in water was studied. Constant wall temperature was used as thermal boundary condition. The results indicate enhancement of heat transfer with increasing nanoparticle concentrations, but an optimum concentration for each nanofluid suspension can be found. Based on the experimental results, metallic nanoparticles show better enhancement of heat transfer coefficient in comparison with oxide particles. The promotions of heat transfer due to utilizing nanoparticles are higher than the theoretical correlation prediction.
A Summary/Overview of Ejector Augmentor Theory and Performance. Volume 1. Technical Discussion
1979-09-01
P Tt ’ Pt m m P - tp pp ptm Pt P Pt Tt n CONSTANT PRESSURE MIXIN -,"--"MIXING INITIAL HEAT ADDITION TO THE PRIMARY w It s sm S Sm ENTROPY, s FfGURE 2...TEMPERATURE-ENTROPY DIAGRAM FOR AN EJECTOR CYCLE ........ . .. I.... ...T H NITIAL HEAT ADDITION TO THE PRIMARY s s sm s8 psi Pt s Tt s ex AIR Uu...s Sm = (8) This Increase in entropy drives the cycle performance to lower values of calcu- lated p, as shown in Figure 4. The only boundary condition
Application of two dimensional periodic molecular dynamics to interfaces.
NASA Astrophysics Data System (ADS)
Gay, David H.; Slater, Ben; Catlow, C. Richard A.
1997-08-01
We have applied two-dimensional molecular dynamics to the surface of a crystalline aspartame and the interface between the crystal face and a solvent (water). This has allowed us to look at the dynamic processes at the surface. Understanding the surface structure and properties are important to controlling the crystal morphology. The thermodynamic ensemble was constant Number, surface Area and Temperature (NAT). The calculations have been carried out using a 2D Ewald summation and 2D periodic boundary conditions for the short range potentials. The equations of motion integration has been carried out using the standard velocity Verlet algorithm.
Heat transfer to the transpired turbulent boundary layer.
NASA Technical Reports Server (NTRS)
Kays, W. M.
1972-01-01
This paper contains a summarization of five years work on an investigation on heat transfer to the transpired turbulent boundary layer. Experimental results are presented for friction coefficient and Stanton number over a wide range of blowing and suction for the case of constant free-stream velocity, holding certain blowing parameters constant. The problem of the accelerated turbulent boundary layer with transpiration is considered, experimental data are presented and discussed, and theoretical models for solution of the momentum equation under these conditions are presented. Data on turbulent Prandtl number are presented so that solutions to the energy equation may be obtained. Some examples of boundary layer heat transfer and friction coefficient predictions are presented using one of the models discussed, employing a finite difference solution method.
Thermal charging study of compressed expanded natural graphite/phase change material composites
Mallow, Anne; Abdelaziz, Omar; Graham, Jr., Samuel
2016-08-12
The thermal charging performance of paraffin wax combined with compressed expanded natural graphite foam was studied for different graphite bulk densities. Constant heat fluxes between 0.39 W/cm 2 and 1.55 W/cm 2 were applied, as well as a constant boundary temperature of 60 °C. Thermal charging experiments indicate that, in the design of thermal batteries, thermal conductivity of the composite alone is an insufficient metric to determine the influence of the graphite foam on the thermal energy storage. By dividing the latent heat of the composite by the time to end of melt for each applied boundary condition, the energymore » storage performance was calculated to show the effects of composite thermal conductivity, graphite bulk density, and latent heat capacity. For the experimental volume, the addition of graphite beyond a graphite bulk density of 100 kg/m 3 showed limited benefit on the energy storage performance due to the decrease in latent heat storage capacity. These experimental results are used to validate a numerical model to predict the time to melt and for future use in the design of heat exchangers with graphite-foam based phase change material composites. As a result, size scale effects are explored parametrically with the validated model.« less
Slip-Flow and Heat Transfer of a Non-Newtonian Nanofluid in a Microtube
Niu, Jun; Fu, Ceji; Tan, Wenchang
2012-01-01
The slip-flow and heat transfer of a non-Newtonian nanofluid in a microtube is theoretically studied. The power-law rheology is adopted to describe the non-Newtonian characteristics of the flow, in which the fluid consistency coefficient and the flow behavior index depend on the nanoparticle volume fraction. The velocity profile, volumetric flow rate and local Nusselt number are calculated for different values of nanoparticle volume fraction and slip length. The results show that the influence of nanoparticle volume fraction on the flow of the nanofluid depends on the pressure gradient, which is quite different from that of the Newtonian nanofluid. Increase of the nanoparticle volume fraction has the effect to impede the flow at a small pressure gradient, but it changes to facilitate the flow when the pressure gradient is large enough. This remarkable phenomenon is observed when the tube radius shrinks to micrometer scale. On the other hand, we find that increase of the slip length always results in larger flow rate of the nanofluid. Furthermore, the heat transfer rate of the nanofluid in the microtube can be enhanced due to the non-Newtonian rheology and slip boundary effects. The thermally fully developed heat transfer rate under constant wall temperature and constant heat flux boundary conditions is also compared. PMID:22615961
NASA Astrophysics Data System (ADS)
O'Brien, Paul
2017-01-01
Max Plank did not quantize temperature. I will show that the Plank temperature violates the Plank scale. Plank stated that the Plank scale was Natures scale and independent of human construct. Also stating that even aliens would derive the same values. He made a huge mistake, because temperature is based on the Kelvin scale, which is man-made just like the meter and kilogram. He did not discover natures scale for the quantization of temperature. His formula is flawed, and his value is incorrect. Plank's calculation is Tp = c2Mp/Kb. The general form of this equation is T = E/Kb Why is this wrong? The temperature for a fixed amount of energy is dependent upon the volume it occupies. Using the correct formula involves specifying the radius of the volume in the form of (RE). This leads to an inequality and a limit that is equivalent to the Bekenstein Bound, but using temperature instead of entropy. Rewriting this equation as a limit defines both the maximum temperature and Boltzmann's constant. This will saturate any space-time boundary with maximum temperature and information density, also the minimum radius and entropy. The general form of the equation then becomes a limit in BH thermodynamics T <= (RE)/(λKb) .
NASA Astrophysics Data System (ADS)
El-Ghazzawy, E. H.
2017-10-01
Nanocrystalline NiCr x Fe2- x O4 spinel samples with x = 0.1 and 0.2 have been synthesized by coprecipitation method and annealed at 620°C and 1175°C for 4 h. Their electrical properties were investigated as functions of frequency in the range of 100 Hz to 100 kHz and temperature in the range of 308 K to 358 K. The dielectric constant ( ɛ^' } ) and dielectric loss factor ( {tan} δ ) appeared to decrease with increasing frequency, while the alternating-current (AC) conductivity ( σ^' } ) increased. These dielectric parameters increased with increasing temperature. On the other hand, impedance spectroscopy gave Cole-Cole plots with only one semicircular arc for all the samples, indicating that the grain-boundary contribution was dominant in the conduction mechanism.
Influence of voids distribution on the deformation behavior of nanocrystalline palladium
NASA Astrophysics Data System (ADS)
Bachurin, D. V.
2018-07-01
Uniaxial deformation of three-dimensional nanocrystalline palladium containing porosity in the form of voids was investigated by means of molecular dynamics method. Simulations were performed at temperature of 300 K and at a constant strain rate of 108s-1. Two cases of voids distribution were considered: random and at triple or quadrupole junctions. It has been revealed that both the voids distribution and subsequent annealing at elevated temperature influence the deformation behavior of nanocrystalline palladium. In particular, the presence of voids at grain junctions results in a reduction of the Young's modulus and more pronounced softening effect during plastic deformation. The subsequent annealing evokes shrinkage of voids and strengthening effect. Contribution of grain boundary accommodation processes into both elastic and plastic deformation of nanocrystalline materials is discussed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ramudu, M., E-mail: macrams2@gmail.com; Raja, M. Manivel; Kamat, S. V.
2016-05-23
The partial substitution of Si with B on the structural and magnetic properties of Co{sub 2}FeSi{sub 1-x}Bx (x = 0-0.5) alloys was systematically investigated. X-ray and microstructural investigations show the presence of second phase at the grain boundaries which increases with increasing boron content. From thermal analysis studies, it was observed that L2{sub 1}-B2 ordering temperature remain constant whereas the melting point decreases with increase in boron addition and merges with ordering temperature at x = 0.5. The increase in T{sub C} for the alloys x ≥ 0.25 was attributed to the increase in second phase due to boron.
Electrical modulus and dielectric behavior of Cr3+ substituted Mg-Zn nanoferrites
NASA Astrophysics Data System (ADS)
Mansour, S. F.; Abdo, M. A.
2017-04-01
The dielectric parameters and ac electrical conductivity of Mg0.8Zn0.2CrxFe2-xO4; (0≤x≤0.025) nanoferrites synthesized citrate-nitrate auto-combustion method were studied using the complex impedance technique in the frequency and temperature ranges 4 Hz-5 MHz and 303-873 K respectively. Hopping of charge carriers plus interfacial polarization could interpret the behaviors of dielectric constant (ε‧), dielectric loss tangent (tanδ) and ac electrical conductivity (σac) with frequency, temperatures and composition. The up-normal behavior observed in tanδ trend with temperatures confirms the presence of relaxation loss (dipoles losses). Correlated barrier hopping (CBH) of electron is the conduction mechanism of the investigated nanoferrites. Cole-Cole plots at different temperatures emphasize the main role of grain and grain boundaries in the properties of the investigated nanoferrites. Cr3+ substitution can control the dielectric parameters and ac electrical conductivity of Mg-Zn nanoferrites making it candidates for versatile applications.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Li, Zhongyu; Shao, Lin, E-mail: lshao@tamu.edu; Chen, Di
Strong electronic stopping power of swift ions in a semiconducting or insulating substrate can lead to localized electron stripping. The subsequent repulsive interactions among charged target atoms can cause Coulomb explosion. Using molecular dynamics simulation, we simulate Coulomb explosion in silicon by introducing an ionization pulse lasting for different periods, and at different substrate temperatures. We find that the longer the pulse period, the larger the melting radius. The observation can be explained by a critical energy density model assuming that melting required thermal energy density is a constant value and the total thermal energy gained from Coulomb explosion ismore » linearly proportional to the ionization period. Our studies also show that melting radius is larger at higher substrate temperatures. The temperature effect is explained due to a longer structural relaxation above the melting temperature at original ionization boundary due to lower heat dissipation rates. Furthermore, simulations show the formation of shock waves, created due to the compression from the melting core.« less
Real-time atomistic observation of structural phase transformations in individual hafnia nanorods
Hudak, Bethany M.; Depner, Sean W.; Waetzig, Gregory R.; ...
2017-05-12
High-temperature phases of hafnium dioxide have exceptionally high dielectric constants and large bandgaps, but quenching them to room temperature remains a challenge. Scaling the bulk form to nanocrystals, while successful in stabilizing the tetragonal phase of isomorphous ZrO 2, has produced nanorods with a twinned version of the room temperature monoclinic phase in HfO 2. Here we use in situ heating in a scanning transmission electron microscope to observe the transformation of an HfO 2 nanorod from monoclinic to tetragonal, with a transformation temperature suppressed by over 1000°C from bulk. When the nanorod is annealed, we observe with atomic-scale resolutionmore » the transformation from twinned-monoclinic to tetragonal, starting at a twin boundary and propagating via coherent transformation dislocation; the nanorod is reduced to hafnium on cooling. Unlike the bulk displacive transition, nanoscale size-confinement enables us to manipulate the transformation mechanism, and we observe discrete nucleation events and sigmoidal nucleation and growth kinetics.« less
Local thermodynamic equilibrium for globally disequilibrium open systems under stress
NASA Astrophysics Data System (ADS)
Podladchikov, Yury
2016-04-01
Predictive modeling of far and near equilibrium processes is essential for understanding of patterns formation and for quantifying of natural processes that are never in global equilibrium. Methods of both equilibrium and non-equilibrium thermodynamics are needed and have to be combined. For example, predicting temperature evolution due to heat conduction requires simultaneous use of equilibrium relationship between internal energy and temperature via heat capacity (the caloric equation of state) and disequilibrium relationship between heat flux and temperature gradient. Similarly, modeling of rocks deforming under stress, reactions in system open for the porous fluid flow, or kinetic overstepping of the equilibrium reaction boundary necessarily needs both equilibrium and disequilibrium material properties measured under fundamentally different laboratory conditions. Classical irreversible thermodynamics (CIT) is the well-developed discipline providing the working recipes for the combined application of mutually exclusive experimental data such as density and chemical potential at rest under constant pressure and temperature and viscosity of the flow under stress. Several examples will be presented.
NASA Technical Reports Server (NTRS)
Hebsur, M. G.; Miner, R. V.
1986-01-01
The high temperature tensile and creep behavior of low pressure plasma-sprayed plates of a typical Ni-Co-Cr-Al-Y alloy has been studied. From room temperature to 800 K, the Ni-Co-Cr-Al-Y alloy studied has nearly a constant low ductility and a high strength. At higher temperatures, it becomes weak and highly ductile. At and above 1123 K, the behavior is highly dependent on strain rate and exhibits classic superplastic characteristics with a high ductility at intermediate strain rates and a strain rate sensitivity of about 0.5. At either higher or lower strain rates, the ductility decreases and the strain rate sensitivities are about 0.2. In the superplastic deformation range, the activation energy for creep is 120 + or - 20 kJ/mol, suggesting a diffusion-aided grain boundary sliding mechanism. Outside the superplastic range, the activation energy for creep is calculated to be 290 + or - 20 kJ/mol.
NASA Astrophysics Data System (ADS)
Motz, L. H.; Kalakan, C.
2013-12-01
Three problems regarding saltwater intrusion, namely the Henry constant dispersion and velocity-dependent dispersion problems and a larger, field-scale velocity-dependent dispersion problem, have been investigated to determine quantitatively how saltwater intrusion and the recirculation of seawater at a coastal boundary are related to the freshwater inflow and the density-driven buoyancy flux. Based on dimensional analysis, saltwater intrusion and the recirculation of seawater are dependent functions of the independent ratio of freshwater advective flux relative to the density-driven vertical buoyancy flux, defined as az (or a for an isotropic aquifer), and the aspect ratio of horizontal and vertical dimensions of the cross-section. For the Henry constant dispersion problem, in which the aquifer is isotropic, saltwater intrusion and recirculation are related to an additional independent dimensionless parameter that is the ratio of the constant dispersion coefficient treated as a scalar quantity, the porosity, and the freshwater advective flux, defined as b. For the Henry velocity-dependent dispersion problem, the ratio b is zero, and saltwater intrusion and recirculation are related to an additional independent dimensionless parameter that is the ratio of the vertical and horizontal dispersivities, or rα = αz/αx. For an anisotropic aquifer, saltwater intrusion and recirculation are also dependent on the ratio of vertical and horizontal hydraulic conductivities, or rK = Kz/Kx. For the field-scale velocity-dependent dispersion problem, saltwater intrusion and recirculation are dependent on the same independent ratios as the Henry velocity-dependent dispersion problem. In the two-dimensional cross-section for all three problems, freshwater inflow occurs at an upgradient boundary, and recirculated seawater outflow occurs at a downgradient coastal boundary. The upgradient boundary is a specified-flux boundary with zero freshwater concentration, and the downgradient boundary is a specified-head boundary with a specified concentration equal to seawater. Equivalent freshwater heads are specified at the downstream boundary to account for density differences between freshwater and saltwater at the downstream boundary. The three problems were solved using the numerical groundwater flow and transport code SEAWAT for two conditions, i.e., first for the uncoupled condition in which the fluid density is constant and thus the flow and transport equations are uncoupled in a constant-density flowfield, and then for the coupled condition in which the fluid density is a function of the total dissolved solids concentration and thus the flow and transport equations are coupled in a variable-density flowfield. A wide range of results for the landward extent of saltwater intrusion and the amount of recirculation of seawater at the coastal boundary was obtained by varying the independent dimensionless ratio az (or a in problem one) in all three problems. The dimensionless dispersion ratio b was also varied in problem one, and the dispersivity ratio rα and the hydraulic conductivity ratio rK were also varied in problems two and three.
Interfaces at equilibrium: A guide to fundamentals.
Marmur, Abraham
2017-06-01
The fundamentals of the thermodynamics of interfaces are reviewed and concisely presented. The discussion starts with a short review of the elements of bulk thermodynamics that are also relevant to interfaces. It continues with the interfacial thermodynamics of two-phase systems, including the definition of interfacial tension and adsorption. Finally, the interfacial thermodynamics of three-phase (wetting) systems is discussed, including the topic of non-wettable surfaces. A clear distinction is made between equilibrium conditions, in terms of minimizing energies (internal, Gibbs or Helmholtz), and equilibrium indicators, in terms of measurable, intrinsic properties (temperature, chemical potential, pressure). It is emphasized that the equilibrium indicators are the same whatever energy is minimized, if the boundary conditions are properly chosen. Also, to avoid a common confusion, a distinction is made between systems of constant volume and systems with drops of constant volume. Copyright © 2016 Elsevier B.V. All rights reserved.
Effect of Nd Doping on Dielectric and Impedance Properties of PZT Nanoceramics
NASA Astrophysics Data System (ADS)
Kour, P.; Pradhan, S. K.; Kumar, Pawan; Sinha, S. K.; Kar, Manoranjan
2018-02-01
Neodymium-doped lead zirconate tianate, i.e. Pb1-x Nd x Zr0.52Ti0.48O3 (PNZT) ceramics, with x = 0-10 mol.% has been prepared by the sol-gel process. X-ray diffraction pattern at room temperature shows the pyrochlore free phase for all samples. The structural analysis suggests the coexistence of both rhombohedral (R3m space group) and tetragonal (P4 mm space group) crystal symmetries. Scanning electron micrographs of the samples show uniform distribution of grain and grain boundaries. Dielectric constant increases with the increase in neodymium concentration in the crystal lattice. Degree of diffuse phase transition increases with the increase in Nd3+ concentration in the sample. Nd3+ incorporation into the lead zirconatetitanate (PZT) lattice enhances the spreading factor. Interaction between neighbouring dipoles decreases with the increase of Nd3+ in PZT lattice. The conduction mechanism of the sample can be attributed to the overlapping large polar tunnelling. Second-order dielectric phase transition has been observed at the Curie temperature. The electrical properties of the sample can be explained by considering grain and grain boundaries contributions. All the samples show the poly-dispersive non-Debye type relaxation.
EVIDENCE OF SPREADING LAYER EMISSION IN A THERMONUCLEAR SUPERBURST
DOE Office of Scientific and Technical Information (OSTI.GOV)
Koljonen, K. I. I.; Kajava, J. J. E.; Kuulkers, E., E-mail: karri.koljonen@nyu.edu
2016-10-01
When a neutron star (NS) accretes matter from a companion star in a low-mass X-ray binary, the accreted gas settles onto the stellar surface through a boundary/spreading layer. On rare occasions the accumulated gas undergoes a powerful thermonuclear superburst powered by carbon burning deep below the NS atmosphere. In this paper, we apply the non-negative matrix factorization spectral decomposition technique to show that the spectral variations during a superburst from 4U 1636–536 can be explained by two distinct components: (1) the superburst emission characterized by a variable temperature blackbody radiation component and (2) a quasi-Planckian component with a constant, ∼2.5more » keV, temperature varying by a factor of ∼15 in flux. The spectrum of the quasi-Planckian component is identical in shape and characteristics to the frequency-resolved spectra observed in the accretion/persistent spectrum of NS low-mass X-ray binaries and agrees well with the predictions of the spreading layer model by Inogamov and Sunyaev. Our results provide yet more observational evidence that superbursts—and possibly also normal X-ray bursts—induce changes in the disc–star boundary.« less
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
2017-04-01
The flow over a 2D leading-edge flat plate is studied at Mach number Ma =(Uinf / \\setmn √{kBTinf / m}) in the range
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
2016-11-01
The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
2017-01-01
The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev
2016-10-01
The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf / {kBTinf /m}) in the range
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev, , Dr.
The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf / ∖ sqrt{kBTinf / m})in the range
NASA Astrophysics Data System (ADS)
Wang, Lin; Blaha, Stephan; Kawazoe, Takaaki; Miyajima, Nobuyoshi; Katsura, Tomoo
2017-03-01
Dislocation recovery experiments were performed on predeformed olivine single crystals at pressures of 2, 7 and 12 GPa and a constant temperature of 1650 K to determine the pressure dependence of the annihilation rate constants for [100](010) edge dislocation (a dislocation) and [001](010) screw dislocation (c dislocation). The constants of both types of dislocations are comparable within 0.3 orders of magnitude. The activation volumes of a and c dislocations are small and identical within error: 2.7 ± 0.2 and 2.5 ± 0.9 cm3/mol, respectively. These values are slightly larger and smaller than those of Si lattice and grain-boundary diffusions in olivine, respectively. The small and identical activation volumes for the a and c dislocations suggest that the pressure-induced fabric transition is unlikely in the asthenosphere. The decrease in seismic anisotropy with depth down in the asthenosphere may be caused by the fabric transition from A type or B type to AG type with decreasing stress with depth.
Hot-Film and Hot-Wire Anemometry for a Boundary Layer Active Flow Control Test
NASA Technical Reports Server (NTRS)
Lenahan, Keven C.; Schatzman, David M.; Wilson, Jacob Samuel
2013-01-01
Unsteady active flow control (AFC) has been used experimentally for many years to minimize bluff-body drag. This technology could significantly improve performance of rotorcraft by cleaning up flow separation. It is important, then, that new actuator technologies be studied for application to future vehicles. A boundary layer wind tunnel was constructed with a 1ft-x-3ft test section and unsteady measurement instrumentation to study how AFC manipulates the boundary layer to overcome adverse pressure gradients and flow separation. This unsteady flow control research requires unsteady measurement methods. In order to measure the boundary layer characteristics, both hot-wire and hot-film Constant Temperature Anemometry is used. A hot-wire probe is mounted in the flow to measure velocity while a hot-film array lays on the test surface to measure skin friction. Hot-film sensors are connected to an anemometer, a Wheatstone bridge circuit with an output that corresponds to the dynamic flow response. From this output, the time varying flow field, turbulence, and flow reversal can be characterized. Tuning the anemometers requires a fan test on the hot-film sensors to adjust each output. This is a delicate process as several variables drastically affect the data, including control resistance, signal input, trim, and gain settings.
Giant dielectric constant in CaCu3Ti4O12 nanoceramics
NASA Astrophysics Data System (ADS)
Ahmad, Mohamad M.
2013-06-01
Nanoceramics of CaCu3Ti4O12 (CCTO) were synthesized by mechanosynthesis and spark plasma sintering with grain size of 150-200 nm. Giant dielectric constant properties are observed in the CCTO nanoceramics due to internal barrier layer capacitance (IBLC) effects. Impedance spectroscopy data suggest that the presence of resistive grain boundaries in addition to resistive domain boundaries is the origin of the IBLCs in CCTO nanoceramics.
Analytically-derived sensitivities in one-dimensional models of solute transport in porous media
Knopman, D.S.
1987-01-01
Analytically-derived sensitivities are presented for parameters in one-dimensional models of solute transport in porous media. Sensitivities were derived by direct differentiation of closed form solutions for each of the odel, and by a time integral method for two of the models. Models are based on the advection-dispersion equation and include adsorption and first-order chemical decay. Boundary conditions considered are: a constant step input of solute, constant flux input of solute, and exponentially decaying input of solute at the upstream boundary. A zero flux is assumed at the downstream boundary. Initial conditions include a constant and spatially varying distribution of solute. One model simulates the mixing of solute in an observation well from individual layers in a multilayer aquifer system. Computer programs produce output files compatible with graphics software in which sensitivities are plotted as a function of either time or space. (USGS)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kalinin, Sergei V; Shin, Junsoo; Veith, Gabriel M
2005-01-01
The origins of an ultrahigh dielectric constant in polycrystalline CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) were studied using the combination of impedance spectroscopy, electron microscopy, and scanning probe microscopy (SPM). Impedance spectra indicate that the transport properties in the 0.1 Hz-1 MHz frequency range are dominated by a single parallel resistive-capacitive (RC) element with a characteristic relaxation frequency of 16 Hz. dc potential distributions measurements by SPM illustrate that significant potential drops occur at the grain boundaries, which thus can be unambiguously identified as the dominant RC element. High frequency ac amplitude and phase distributions illustrate very weak grain boundary contrastmore » in SPM, indicative of strong capacitive coupling across the interfaces. These results demonstrate that the ultrahigh dielectric constant reported for polycrystalline CCTO materials is related to grain-boundary behavior.« less
The complex variable boundary element method: Applications in determining approximative boundaries
Hromadka, T.V.
1984-01-01
The complex variable boundary element method (CVBEM) is used to determine approximation functions for boundary value problems of the Laplace equation such as occurs in potential theory. By determining an approximative boundary upon which the CVBEM approximator matches the desired constant (level curves) boundary conditions, the CVBEM is found to provide the exact solution throughout the interior of the transformed problem domain. Thus, the acceptability of the CVBEM approximation is determined by the closeness-of-fit of the approximative boundary to the study problem boundary. ?? 1984.
Discontinuous precipitation in a Cd-6 at.% Ag alloy
DOE Office of Scientific and Technical Information (OSTI.GOV)
Manna, I.; Bala, P.K.; Pabi, S.K.
1996-11-01
Discontinuous precipitation (DP) in a Cd-6 at.% Ag alloy has been investigated for the first time. The precipitate phase maintains a lamellar morphology and statistically constant interlamellar spacing under a given isothermal condition in the temperature range studied (333--523 K). The interlamellar spacing increases with an increase in isothermal temperature. The reaction front velocity registers a typical C-curve variation with the inverse of temperature. The reaction rate is maximum at 470 K. The predicted upper limit of DP occurrence in this alloy is 23 K lower than the concerned equilibrium solvus temperature. Continuous precipitation accompanies DP at all temperatures, especiallymore » beyond a certain time, and adversely affects the growth kinetics of DP colonies by reducing the local chemical driving force and/or posing physical hindrance to the reaction front migration. An extensive kinetic analysis of DP using the models by Turnbull, Aaronson and Liu, and Petermann and Hornbogen has yielded the grain boundary chemical diffusivity data in Cd-6 At.% Ag for the first time, the activation energy of which lies in the range 55--77 kJ/mol.« less
NASA Astrophysics Data System (ADS)
Diestra Cruz, Heberth Alexander
The Green's functions integral technique is used to determine the conduction heat transfer temperature field in flat plates, circular plates, and solid spheres with saw tooth heat generating sources. In all cases the boundary temperature is specified (Dirichlet's condition) and the thermal conductivity is constant. The method of images is used to find the Green's function in infinite solids, semi-infinite solids, infinite quadrants, circular plates, and solid spheres. The saw tooth heat generation source has been modeled using Dirac delta function and Heaviside step function. The use of Green's functions allows obtain the temperature distribution in the form of an integral that avoids the convergence problems of infinite series. For the infinite solid and the sphere, the temperature distribution is three-dimensional and in the cases of semi-infinite solid, infinite quadrant and circular plate the distribution is two-dimensional. The method used in this work is superior to other methods because it obtains elegant analytical or quasi-analytical solutions to complex heat conduction problems with less computational effort and more accuracy than the use of fully numerical methods.
NASA Astrophysics Data System (ADS)
Liu, C. J.; Zheng, H. F.
2013-04-01
A new approach to the kinetics study of anhydrite (CaSO4) crystallization has been performed in situ using a hydrothermal diamond anvil cell with Raman spectroscopy in the pressure range 896-1322 MPa and a constant temperature of 373 K. Transformed volume fraction X(t) was determined from Raman peak intensity of the sulfate ion in aqueous solution. The transformation-time plots display a sigmoidal shape with time, which indicates that the reaction rate is different at each stage of anhydrite crystallization. At 373 K, the rate constant k increases from 1.14 × 10-4 s-1 to 1.86 × 10-3 s-1, demonstrating a positive effect of pressure on the overall rate at isothermal condition. We first achieved the molar volume change (ΔVm) equal to -1.82 × 10-5 m3/mol in the course of anhydrite crystallization through Avrami kinetic theory, showing a process of reduction in volume at high pressure and high temperature. According to the exponent n derived from our experiments, a grain-boundary nucleation and diffusion-controlled growth kinetically dominates the crystallization of anhydrite.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Leigh, A.; Sevanto, Sanna Annika; Close, J. D.
Laboratory studies on artificial leaves suggest that leaf thermal dynamics are strongly influenced by the two-dimensional size and shape of leaves and associated boundary layer thickness. Hot environments are therefore said to favour selection for small, narrow or dissected leaves. Empirical evidence from real leaves under field conditions is scant and traditionally based on point measurements that do not capture spatial variation in heat load. Here in this study, we used thermal imagery under field conditions to measure the leaf thermal time constant (τ) in summer and the leaf-to-air temperature difference (ΔT) and temperature range across laminae (T range) duringmore » winter, autumn and summer for 68 Proteaceae species. We investigated the influence of leaf area and margin complexity relative to effective leaf width (w e), the latter being a more direct indicator of boundary layer thickness. Normalized difference of margin complexity had no or weak effects on thermal dynamics, but w e strongly predicted τ and ΔT, whereas leaf area influenced T range. Unlike artificial leaves, however, spatial temperature distribution in large leaves appeared to be governed largely by structural variation. Therefore, we agree that small size, specifically we, has adaptive value in hot environments but not with the idea that thermal regulation is the primary evolutionary driver of leaf dissection.« less
Leigh, A.; Sevanto, Sanna Annika; Close, J. D.; ...
2016-11-05
Laboratory studies on artificial leaves suggest that leaf thermal dynamics are strongly influenced by the two-dimensional size and shape of leaves and associated boundary layer thickness. Hot environments are therefore said to favour selection for small, narrow or dissected leaves. Empirical evidence from real leaves under field conditions is scant and traditionally based on point measurements that do not capture spatial variation in heat load. Here in this study, we used thermal imagery under field conditions to measure the leaf thermal time constant (τ) in summer and the leaf-to-air temperature difference (ΔT) and temperature range across laminae (T range) duringmore » winter, autumn and summer for 68 Proteaceae species. We investigated the influence of leaf area and margin complexity relative to effective leaf width (w e), the latter being a more direct indicator of boundary layer thickness. Normalized difference of margin complexity had no or weak effects on thermal dynamics, but w e strongly predicted τ and ΔT, whereas leaf area influenced T range. Unlike artificial leaves, however, spatial temperature distribution in large leaves appeared to be governed largely by structural variation. Therefore, we agree that small size, specifically we, has adaptive value in hot environments but not with the idea that thermal regulation is the primary evolutionary driver of leaf dissection.« less
NASA Technical Reports Server (NTRS)
Pohorille, Andrew; Pratt, Lawrence
2006-01-01
"Follow the water" is the canonical strategy in searching for life in the universe. Conventionally, discussion of this topic is focused on how solvent supports organic chemistry sufficiently rich to seed life. Perhaps more importantly, solvent must promote self-organization of organic matter into functional structures capable of responding to environmental changes. This process is based on non-covalent interactions. They are constantly formed and broken in response to internal and external stimuli. This requires that their strength must be properly tuned. If they were too weak, the system would exhibit undesired, uncontrolled response to natural fluctuations of physical and chemical parameters. If they were too strong kinetics of biological processes would be slow and energetics costly. Non-covalent interactions are strongly mediated by the solvent. Specifically, high dielectric solvents for life are needed for solubility of polar species and flexibility of biological structures stabilized by electrostatic interactions. Water exhibits a remarkable trait that it promotes solvophobic interactions between non-polar species, which are responsible for self-organization phenomena such as the formation of cellular boundary structures, and protein folding and aggregation. Unusual temperature dependence of hydrophobic interactions - they often become stronger as temperature increases - is a consequence of the temperature insensitivity of properties of the liquid water. This contributes to the existence of robust life over a wide temperature range. Water is not the only liquid with favorable properties for supporting life. Other pure liquids or their mixtures that have high dielectric constants and simultaneously support some level of self-organization will be discussed.
NASA Astrophysics Data System (ADS)
Sharpe, Heather Joan
2007-05-01
Engineers constantly seek advancements in the performance of aircraft and power generation engines, including, lower costs and emissions, and improved fuel efficiency. Nickel-base superalloys are the material of choice for turbine discs, which experience some of the highest temperatures and stresses in the engine. Engine performance is proportional to operating temperatures. Consequently, the high-temperature capabilities of disc materials limit the performance of gas-turbine engines. Therefore, any improvements to engine performance necessitate improved alloy performance. In order to take advantage of improvements in high-temperature capabilities through tailoring of alloy microstructure, the overall objectives of this work were to establish relationships between alloy processing and microstructure, and between microstructure and mechanical properties. In addition, the projected aimed to demonstrate the applicability of neural network modeling to the field of Ni-base disc alloy development and behavior. The first phase of this work addressed the issue of how microstructure varies with heat treatment and by what mechanisms these structures are formed. Further it considered how superalloy composition could account for microstructural variations from the same heat treatment. To study this, four next-generation Ni-base disc alloys were subjected to various controlled heat-treatments and the resulting microstructures were then quantified. These quantitative results were correlated to chemistry and processing, including solution temperature, cooling rate, and intermediate hold temperature. A complex interaction of processing steps and chemistry was found to contribute to all features measured; grain size, precipitate distribution, grain boundary serrations. Solution temperature, above a certain threshold, and cooling rate controlled grain size, while cooling rate and intermediate hold temperature controlled precipitate formation and grain boundary serrations. Diffusion, both intergranular and grain boundary, was identified as the most pertinent mechanism. Variations in chemistry between alloys created different amounts of gamma/gamma' misfit strain, which affected precipitate size and morphology. Next the question of how a disc alloy with differing microstructures would respond to constant or cyclic stresses as a function of time was addressed. To this end, mechanical testing at elevated temperatures was conducted, including tensile, hardness, creep deformation, creep crack growth and fatigue crack growth. Overall, mechanical properties were primarily related to the cooling rate during processing with hold temperatures being secondary. Whether the impact was positive or negative depended on the behavior under consideration. Fast cooling rates improved yield strength and creep resistance, but were detrimental to creep crack growth rates. The ability of precipitate particles to impede dislocation motion was the most frequently cited mechanism behind structure-property interaction. Neural network models were successfully generated for processing-structure predictions, as well as for structure-property predictions. Training data was limited, none-the-less models were able to predict outputs with minimal relative errors. This was achieved through careful balance between the number of inputs and amount of training data. Despite the demonstrated correlation between microstructure and yield strength, microstructural quantities did not need to be directly inputted. Neural networks were sufficiently sensitive as to infer these effects from processing and chemistry inputs. This result improves the efficiency of this technique, while also demonstrating the capability of neural network techniques. A full program of heat-treatment, microstructure quantification, mechanical testing, and neural network modeling was successfully applied to next generation Ni-base disc alloys. From this work the mechanisms of processing-structure and structure-property relationships were studied. Further, testing results were used to demonstrate the applicability of machine-learning techniques to the development and optimization of this family of superalloys.
Near-critical fluid boiling: overheating and wetting films.
Hegseth, J; Oprisan, A; Garrabos, Y; Lecoutre-Chabot, C; Nikolayev, V S; Beysens, D
2008-08-01
The heating of coexisting gas and liquid phases of pure fluid through its critical point makes the fluid extremely compressible, expandable, slows the diffusive transport, and decreases the contact angle to zero (perfect wetting by the liquid phase). We have performed experiments on near-critical fluids in a variable volume cell in the weightlessness of an orbiting space vehicle, to suppress buoyancy-driven flows and gravitational constraints on the liquid-gas interface. The high compressibility, high thermal expansion, and low thermal diffusivity lead to a pronounced adiabatic heating called the piston effect. We have directly visualized the near-critical fluid's boundary layer response to a volume quench when the external temperature is held constant. We have found that when the system's temperature T is increased at a constant rate past the critical temperature T(c), the interior of the fluid gains a higher temperature than the hot wall (overheating). This extends previous results in temperature quenching experiments in a similarly prepared system when the gas is clearly isolated from the wall. Large elliptical wetting film distortions are also seen during these ramps. By ray tracing through the elliptically shaped wetting film, we find very thick wetting film on the walls. This wetting film is at least one order of magnitude thicker than films that form in the Earth's gravity. The thick wetting film isolates the gas bubble from the wall allowing gas overheating to occur due to the difference in the piston effect response between gas and liquid. Remarkably, this overheating continues and actually increases when the fluid is ramped into the single-phase supercritical phase.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sarver, J.M.; Doherty, P.E.; Doyle, D.M.
1995-12-31
Thermally treated Alloy 690 is the tubing material of choice for replacement steam generators in the United States. Throughout the world, it is manufactured using different melting and thermomechanical processing methods. The influence of different processing steps on the intergranular stress corrosion cracking (IGSCC) behavior of Alloy 690 has not been thoroughly evaluated. Evaluations were performed on Alloy 690 steam generator tubing produced using several different melting practices and thermomechanical processing procedures. The evaluations included extensive microstructural examinations as well as constant extension rate (CERT) tests. The CERT test results indicated that the thermally treated Alloy 690 tubing which wasmore » subjected to higher annealing temperatures displayed the highest degree of resistance to stress corrosion cracking (SCC). Examination of the microstructures indicated that the microstructural changes which are produced by increased annealing temperatures are subtle. In an attempt to further elucidate and quantify the effect of manufacturing processes on corrosion behavior, grain boundary character distribution (GBCD) measurements were performed on the same materials which were CERT tested. Analysis of GBCDs of the samples used in this study indicate that Alloy 690 exhibits a significantly larger fraction of special boundaries as compared to Alloy 600 and Alloy 800, regardless of the processing history of the tubing. Preliminary results indicate that a correlation may exist between processing method, GBCD`s and degree of IGSCC exhibited by the thermally treated samples examined in this study.« less
Acoustics of Jet Surface Interaction - Scrubbing Noise
NASA Technical Reports Server (NTRS)
Khavaran, Abbas
2014-01-01
Concepts envisioned for the future of civil air transport consist of unconventional propulsion systems in the close proximity to the structure or embedded in the airframe. While such integrated systems are intended to shield noise from the community, they also introduce new sources of sound. Sound generation due to interaction of a jet flow past a nearby solid surface is investigated here using the generalized acoustic analogy theory. The analysis applies to the boundary layer noise generated at and near a wall, and excludes the scattered noise component that is produced at the leading or the trailing edge. While compressibility effects are relatively unimportant at very low Mach numbers, frictional heat generation and thermal gradient normal to the surface could play important roles in generation and propagation of sound in high speed jets of practical interest. A general expression is given for the spectral density of the far field sound as governed by the variable density Pridmore-Brown equation. The propagation Green's function is solved numerically for a high aspect-ratio rectangular jet starting with the boundary conditions on the surface and subject to specified mean velocity and temperature profiles between the surface and the observer. It is shown the magnitude of the Green's function decreases with increasing source frequency and/or jet temperature. The phase remains constant for a rigid surface, but varies with source location when subject to an impedance type boundary condition. The Green's function in the absence of the surface, and flight effects are also investigated
Acoustics of Jet Surface Interaction-Scrubbing Noise
NASA Technical Reports Server (NTRS)
Khavaran, Abbas
2014-01-01
Concepts envisioned for the future of civil air transport consist of unconventional propulsion systems in the close proximity of the structure or embedded in the airframe. While such integrated systems are intended to shield noise from community, they also introduce new sources of sound. Sound generation due to interaction of a jet flow past a nearby solid surface is investigated here using the generalized acoustic analogy theory. The analysis applies to the boundary layer noise generated at and near a wall, and excludes the scattered noise component that is produced at the leading or the trailing edge. While compressibility effects are relatively unimportant at very low Mach numbers, frictional heat generation and thermal gradient normal to the surface could play important roles in generation and propagation of sound in high speed jets of practical interest. A general expression is given for the spectral density of the far field sound as governed by the variable density Pridmore-Brown equation. The propagation Greens function is solved numerically for a high aspect-ratio rectangular jet starting with the boundary conditions on the surface and subject to specified mean velocity and temperature profiles between the surface and the observer. It is shown the magnitude of the Greens function decreases with increasing source frequency andor jet temperature. The phase remains constant for a rigid surface, but varies with source location when subject to an impedance type boundary condition. The Greens function in the absence of the surface, and flight effect are also investigated.
Heat and mass transfer boundary conditions at the surface of a heated sessile droplet
NASA Astrophysics Data System (ADS)
Ljung, Anna-Lena; Lundström, T. Staffan
2017-12-01
This work numerically investigates how the boundary conditions of a heated sessile water droplet should be defined in order to include effects of both ambient and internal flow. Significance of water vapor, Marangoni convection, separate simulations of the external and internal flow, and influence of contact angle throughout drying is studied. The quasi-steady simulations are carried out with Computational Fluid Dynamics and conduction, natural convection and Marangoni convection are accounted for inside the droplet. For the studied conditions, a noticeable effect of buoyancy due to evaporation is observed. Hence, the inclusion of moisture increases the maximum velocities in the external flow. Marangoni convection will, in its turn, increase the velocity within the droplet with up to three orders of magnitude. Results furthermore show that the internal and ambient flow can be simulated separately for the conditions studied, and the accuracy is improved if the internal temperature gradient is low, e.g. if Marangoni convection is present. Simultaneous simulations of the domains are however preferred at high plate temperatures if both internal and external flows are dominated by buoyancy and natural convection. The importance of a spatially resolved heat and mass transfer boundary condition is, in its turn, increased if the internal velocity is small or if there is a large variation of the transfer coefficients at the surface. Finally, the results indicate that when the internal convective heat transport is small, a rather constant evaporation rate may be obtained throughout the drying at certain conditions.
Oops, You're Stepping on My Boundaries!
ERIC Educational Resources Information Center
Marshall, Anne
Boundaries are limits that define us as separate from others. Although this concept is a familiar one in personal and addictions counseling, it is seldom discussed in career development or career counseling. Yet boundary issues arise constantly in working relationships, in the job-application process, among employees, and especially with…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Favorite, Jeffrey A.
In transport theory, adjoint-based partial derivatives with respect to mass density are constant-volume derivatives. Likewise, adjoint-based partial derivatives with respect to surface locations (i.e., internal interface locations and the outer system boundary) are constant-density derivatives. This study derives the constant-mass partial derivative of a response with respect to an internal interface location or the outer system boundary and the constant-mass partial derivative of a response with respect to the mass density of a region. Numerical results are given for a multiregion two-dimensional (r-z) cylinder for three very different responses: the uncollided gamma-ray flux at an external detector point, k effmore » of the system, and the total neutron leakage. Finally, results from the derived formulas compare extremely well with direct perturbation calculations.« less
Franke, O. Lehn; Reilly, Thomas E.
1987-01-01
The most critical and difficult aspect of defining a groundwater system or problem for conceptual analysis or numerical simulation is the selection of boundary conditions . This report demonstrates the effects of different boundary conditions on the steady-state response of otherwise similar ground-water systems to a pumping stress. Three series of numerical experiments illustrate the behavior of three hypothetical groundwater systems that are rectangular sand prisms with the same dimensions but with different combinations of constant-head, specified-head, no-flow, and constant-flux boundary conditions. In the first series of numerical experiments, the heads and flows in all three systems are identical, as are the hydraulic conductivity and system geometry . However, when the systems are subjected to an equal stress by a pumping well in the third series, each differs significantly in its response . The highest heads (smallest drawdowns) and flows occur in the systems most constrained by constant- or specified-head boundaries. These and other observations described herein are important in steady-state calibration, which is an integral part of simulating many ground-water systems. Because the effects of boundary conditions on model response often become evident only when the system is stressed, a close match between the potential distribution in the model and that in the unstressed natural system does not guarantee that the model boundary conditions correctly represent those in the natural system . In conclusion, the boundary conditions that are selected for simulation of a ground-water system are fundamentally important to groundwater systems analysis and warrant continual reevaluation and modification as investigation proceeds and new information and understanding are acquired.
Application of a boundary element method to the study of dynamical torsion of beams
NASA Technical Reports Server (NTRS)
Czekajski, C.; Laroze, S.; Gay, D.
1982-01-01
During dynamic torsion of beam elements, consideration of nonuniform warping effects involves a more general technical formulation then that of Saint-Venant. Nonclassical torsion constants appear in addition to the well known torsional rigidity. The adaptation of the boundary integral element method to the calculation of these constants for general section shapes is described. The suitability of the formulation is investigated with some examples of thick as well as thin walled cross sections.
NASA Technical Reports Server (NTRS)
Kim, Jungho
2004-01-01
Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. Recently, time and space resolved heat transfer data were obtained in both earth and low gravity environments using an array of microheaters varying in size between 100 microns to 700 microns. These heaters were operated in both constant temperature as well as constant heat flux mode. Heat transfer under nucleating bubbles in earth gravity were directly measured using a microheater array with 100 m resolution operated in constant temperature mode with low and high subcooled bulk liquid along with images from below and from the side. The individual bubble departure diameter and energy transfer were larger with low subcooling but the departure frequency increased at high subcooling, resulting in higher overall heat transfer. The bubble growth for both subcoolings was primarily due to energy transfer from the superheated liquid layer relatively little was due to wall heat transfer during the bubble growth process. Oscillating bubbles and sliding bubbles were also observed in highly subcooled boiling. Transient conduction and/or microconvection was the dominant heat transfer mechanism in the above cases. A transient conduction model was developed and compared with the experimental data with good agreement. Data was also obtained with the heater array operated in a constant heat flux mode and measuring the temperature distribution across the array during boiling. The instantaneous heat transfer into the substrate was numerically determined and subtracted from the supplied heat to obtain the wall to liquid heat flux.
Diurnal forcing of planetary atmospheres
NASA Technical Reports Server (NTRS)
Houben, Howard C.
1991-01-01
The utility of the Mars Planetary Boundary Layer Model (MPBL) for calculations in support of the Mars 94 balloon mission was substantially enhanced by the introduction of a balloon equation of motion into the model. Both vertical and horizontal excursions of the balloon are calculated along with its volume, temperature, and pressure. The simulations reproduce the expected 5-min vertical oscillations of a constant density balloon at altitude on Mars. The results of these calculations are presented for the nominal target location of the balloon. A nonlinear balanced model was developed for the Martian atmosphere. It was used to initialize a primitive equation model for the simulations of the Earth's atmosphere at the time of the El Chichon eruption in 1982. It is also used as an assimilation model to update the temperature and wind fields at frequent intervals.
NASA Astrophysics Data System (ADS)
Linseis, V.; Völklein, F.; Reith, H.; Woias, P.; Nielsch, K.
2018-06-01
An analytical study has been performed on the measurement capabilities of a 100-nm thin suspended membrane setup for the in-plane thermal conductivity measurements of thin film samples using the 3 ω measurement technique, utilizing a COSMOL Multiphysics simulation. The maximum measurement range under observance of given boundary conditions has been studied. Three different exemplary sample materials, with a thickness from the nanometer to the micrometer range and a thermal conductivity from 0.4 W/mK up to 100 W/mK have been investigated as showcase studies. The results of the simulations have been compared to a previously published evaluation model, in order to determine the deviation between both and thereby the measurement limit. As thermal transport properties are temperature dependent, all calculations refer to constant room temperature conditions.
Turbulence structure of the near-surface boundary layer in complex terrain
NASA Astrophysics Data System (ADS)
Sfyri, Eleni; Rotach, Mathias Walter; Stiperski, Ivana; Bosveld, Fred; Lehner, Manuela; Obleitner, Friedrich
2017-04-01
Monin-Obukhov Similarity Theory (MOST) is evaluated in two cases: truly complex terrain (CT) and horizontally inhomogeneous and flat (HIF) terrain. CT data are derived from 5 measurement sites, which differ in terms of slope, orientation and surface roughness at the Inn Valley of Austria (i-Box) and HIF data come from one measurement site at the Cabauw experimental site (Netherlands). The applicability of the surface-layer, 'ideal' similarity relations is examined for both data-sets and the non-dimensional variances of temperature and humidity as a function of stability (z/L, where L is the Obukhov length) are compared for each type of terrain. Large deviations from the reference curves in case of temperature are observed in both CT and HIF, leading to the conclusion that these deviations are not due to the complex terrain but due to inappropriate near-neutral description of the reference curves. It is found here that the non-dimensional temperature variance exhibits a -1 slope in the near-neutral region, for both CT and HIF datasets. In addition, the constant-fluxes hypothesis of the MOST is evaluated at one i-Box site. It is found that only about 1% of the data show constant momentum, sensible and latent heat fluxes with height. Therefore, local scaling instead of surface layer scaling is being used in this study.
Corrosion of type 316L stainless steel in a mercury thermal convection loop
DOE Office of Scientific and Technical Information (OSTI.GOV)
DiStefano, J.R.; Manneschmidt, E.T.; Pawel, S.J.
1999-04-01
Two thermal convection loops fabricated from 316L stainless steel containing mercury (Hg) and Hg with 1000 wppm gallium (Ga), respectively, were operated continuously for about 5000 h. In each case, the maximum loop temperature was constant at about 305 degrees C and the minimum temperature was constant at about 242 degrees C. Coupons in the hot leg of the Hg-loop developed a posous surface layer substantially depleted of nickel and chromium, which resulted in a transformation to ferrite. The coupon exposed at the top of the hot leg in the Hg-loop experienced the maximum degradation, exhibiting a surface layer extendingmore » an average of 9-10 mu m after almost 5000 h. Analysis of the corrosion rate data as a function of temperature (position) in the Hg-loop suggests wetting by the mer cury occurred only above about 255 degrees C and that the rate limiting step in the corrosion process above 255 degrees C is solute diffusion through the saturated liquid boundary layer adjacent to the corroding surface. The latter factor suggests that the corrosion of 316L stainless steel in a mercury loop may be velocity dependent. No wetting and no corrosion were observed on the coupons and wall specimens removed from the Hg/Ga loop after 5000 h of operation.« less
Sea-ice cover in the Nordic Seas and the sensitivity to Atlantic water temperatures
NASA Astrophysics Data System (ADS)
Jensen, Mari F.; Nisancioglu, Kerim H.; Spall, Michael A.
2017-04-01
Changes in the sea-ice cover of the Nordic Seas have been proposed to play a key role for the dramatic temperature excursions associated with the Dansgaard-Oeschger events during the last glacial. However, with its proximity to the warm Atlantic water, how a sea-ice cover can persist in the Nordic Seas is not well understood. In this study, we apply an eddy-resolving configuration of the Massachusetts Institute of Technology general circulation model with an idealized topography to study the presence of sea ice in a Nordic Seas-like domain. We assume an infinite amount of warm Atlantic water present in the south by restoring the southern area to constant temperatures. The sea-surface temperatures are restored toward cold, atmospheric temperatures, and as a result, sea ice is present in the interior of the domain. However, the sea-ice cover in the margins of the Nordic Seas, an area with a warm, cyclonic boundary current, is sensitive to the amount of heat entering the domain, i.e., the restoring temperature in the south. When the temperature of the warm, cyclonic boundary current is high, the margins are free of sea ice and heat is released to the atmosphere. We show that with a small reduction in the temperature of the incoming Atlantic water, the Nordic Seas-like domain is fully covered in sea ice. Warm water is still entering the Nordic Seas, however, this happens at depths below a cold, fresh surface layer produced by melted sea ice. Consequently, the heat release to the atmosphere is reduced along with the eddy heat fluxes. Results suggest a threshold value in the amount of heat entering the Nordic Seas before the sea-ice cover disappears in the margins. We study the sensitivity of this threshold to changes in atmospheric temperatures and vertical diffusivity.
O’Brien, C. J.; Foiles, S. M.
2016-04-19
The temperature dependence of grain boundary mobility is complex, varied, and rarely fits ideal Arrhenius behavior. This work presents a series of case studies of planar grain boundaries in a model FCC system that were previously demonstrated to exhibit a variety of temperature-dependent mobility behaviors. It is demonstrated that characterization of the mobility versus temperature plots is not sufficient to predict the atomic motion mechanism of the grain boundaries. Herein, the temperature-dependent motion and atomistic motion mechanisms of planar grain boundaries are driven by a synthetic, orientation-dependent, driving force. The systems studied include CSL boundaries with Σ values of 5,more » 7, and 15, including both symmetric and asymmetric boundaries. These boundaries represent a range of temperature-dependent trends including thermally activated, antithermal, and roughening behaviors. Examining the atomic-level motion mechanisms of the thermally activated boundaries reveals that each involves a complex shuffle, and at least one atom that changes the plane it resides on. The motion mechanism of the antithermal boundary is qualitatively different and involves an in-plane coordinated shuffle that rotates atoms about a fixed atom lying on a point in the coincident site lattice. Furthermore, this provides a mechanistic reason for the observed high mobility, even at low temperatures, which is due to the low activation energy needed for such motion. However, it will be demonstrated that this mechanism is not universal, or even common, to other boundaries exhibiting non-thermally activated motion. This work concludes that no single atomic motion mechanism is sufficient to explain the existence of non-thermally activated boundary motion.« less
Grain boundary oxidation and its effects on high temperature fatigue life
NASA Technical Reports Server (NTRS)
Liu, H. W.; Oshida, Yoshiki
1986-01-01
Fatigue lives at elevated temperatures are often shortened by creep and/or oxidation. Creep causes grain boundary void nucleation and grain boundary cavitation. Grain boundary voids and cavities will accelerate fatigue crack nucleation and propagation, and thereby shorten fatigue life. The functional relationships between the damage rate of fatigue crack nucleation and propagation and the kinetic process of oxygen diffusion depend on the detailed physical processes. The kinetics of grain boundary oxidation penetration was investigated. The statistical distribution of grain boundary penetration depth was analyzed. Its effect on high temperature fatigue life are discussed. A model of intermittent micro-ruptures of grain boundary oxide was proposed for high temperature fatigue crack growth. The details of these studies are reported.
Davulis, Peter M; da Cunha, Mauricio Pereira
2013-04-01
A full set of langatate (LGT) elastic, dielectric, and piezoelectric constants with their respective temperature coefficients up to 900°C is presented, and the relevance of the dielectric and piezoelectric constants and temperature coefficients are discussed with respect to predicted and measured high-temperature SAW propagation properties. The set of constants allows for high-temperature acoustic wave (AW) propagation studies and device design. The dielectric constants and polarization and conductive losses were extracted by impedance spectroscopy of parallel-plate capacitors. The measured dielectric constants at high temperatures were combined with previously measured LGT expansion coefficients and used to determine the elastic and piezoelectric constants using resonant ultrasound spectroscopy (RUS) measurements at temperatures up to 900°C. The extracted LGT piezoelectric constants and temperature coefficients show that e11 and e14 change by up to 62% and 77%, respectively, for the entire 25°C to 900°C range when compared with room-temperature values. The LGT high-temperature constants and temperature coefficients were verified by comparing measured and predicted phase velocities (vp) and temperature coefficients of delay (TCD) of SAW delay lines fabricated along 6 orientations in the LGT plane (90°, 23°, Ψ) up to 900°C. For the 6 tested orientations, the predicted SAW vp agree within 0.2% of the measured vp on average and the calculated TCD is within 9.6 ppm/°C of the measured value on average over the temperature range of 25°C to 900°C. By including the temperature dependence of both dielectric and piezoelectric constants, the average discrepancies between predicted and measured SAW properties were reduced, on average: 77% for vp, 13% for TCD, and 63% for the turn-over temperatures analyzed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Soederlind, P.; Moriarty, J.A.; Wills, J.M.
1996-06-01
{ital Ab} {ital initio} electronic-structure calculations, based on density-functional theory and a full-potential linear-muffin-tin-orbital method, have been used to predict crystal-structure phase stabilities, elastic constants, and Brillouin-zone-boundary phonons for iron under compression. Total energies for five crystal structures, bcc, fcc, bct, hcp, and dhcp, have been calculated over a wide volume range. In agreement with experiment and previous theoretical calculations, a magnetic bcc ground state is obtained at ambient pressure and a nonmagnetic hcp ground state is found at high pressure, with a predicted bcc {r_arrow} hcp phase transition at about 10 GPa. Also in agreement with very recent diamond-anvil-cellmore » experiments, a metastable dhcp phase is found at high pressure, which remains magnetic and consequently accessible at high temperature up to about 50 GPa. In addition, the bcc structure becomes mechanically unstable at pressures above 2 Mbar (200 GPa) and a metastable, but still magnetic, bct phase ({ital c}/{ital a} {approx_equal} 0.875) develops. For high-pressure nonmagnetic iron, fcc and hcp elastic constants and fcc phonon frequencies have been calculated to above 4 Mbar. These quantities rise smoothly with pressure, but an increasing tendency towards elastic anisotropy as a function of compression is observed, and this has important implications for the solid inner-core of the earth. The fcc elastic-constant and phonon data have also been used in combination with generalized pseudopotential theory to develop many-body interatomic potentials, from which high-temperature thermodynamic properties and melting can be obtained. In this paper, these potentials have been used to calculate full fcc and hcp phonon spectra and corresponding Debye temperatures as a function of compression. {copyright} {ital 1996 The American Physical Society.}« less
Inlet Turbulence and Length Scale Measurements in a Large Scale Transonic Turbine Cascade
NASA Technical Reports Server (NTRS)
Thurman, Douglas; Flegel, Ashlie; Giel, Paul
2014-01-01
Constant temperature hotwire anemometry data were acquired to determine the inlet turbulence conditions of a transonic turbine blade linear cascade. Flow conditions and angles were investigated that corresponded to the take-off and cruise conditions of the Variable Speed Power Turbine (VSPT) project and to an Energy Efficient Engine (EEE) scaled rotor blade tip section. Mean and turbulent flowfield measurements including intensity, length scale, turbulence decay, and power spectra were determined for high and low turbulence intensity flows at various Reynolds numbers and spanwise locations. The experimental data will be useful for establishing the inlet boundary conditions needed to validate turbulence models in CFD codes.
Vortex multiplication in applied flow: A precursor to superfluid turbulence.
Finne, A P; Eltsov, V B; Eska, G; Hänninen, R; Kopu, J; Krusius, M; Thuneberg, E V; Tsubota, M
2006-03-03
A surface-mediated process is identified in 3He-B which generates vortices at a roughly constant rate. It precedes a faster form of turbulence where intervortex interactions dominate. This precursor becomes observable when vortex loops are introduced in low-velocity rotating flow at sufficiently low mutual friction dissipation at temperatures below 0.5Tc. Our measurements indicate that the formation of new loops is associated with a single vortex interacting in the applied flow with the sample boundary. Numerical calculations show that the single-vortex instability arises when a helical Kelvin wave expands from a reconnection kink at the wall and then intersects again with the wall.
Effective Methods for Solving Band SLEs after Parabolic Nonlinear PDEs
NASA Astrophysics Data System (ADS)
Veneva, Milena; Ayriyan, Alexander
2018-04-01
A class of models of heat transfer processes in a multilayer domain is considered. The governing equation is a nonlinear heat-transfer equation with different temperature-dependent densities and thermal coefficients in each layer. Homogeneous Neumann boundary conditions and ideal contact ones are applied. A finite difference scheme on a special uneven mesh with a second-order approximation in the case of a piecewise constant spatial step is built. This discretization leads to a pentadiagonal system of linear equations (SLEs) with a matrix which is neither diagonally dominant, nor positive definite. Two different methods for solving such a SLE are developed - diagonal dominantization and symbolic algorithms.
Rotational Diffusion Depends on Box Size in Molecular Dynamics Simulations.
Linke, Max; Köfinger, Jürgen; Hummer, Gerhard
2018-06-07
We show that the rotational dynamics of proteins and nucleic acids determined from molecular dynamics simulations under periodic boundary conditions suffer from significant finite-size effects. We remove the box-size dependence of the rotational diffusion coefficients by adding a hydrodynamic correction k B T/6 ηV with k B Boltzmann's constant, T the absolute temperature, η the solvent shear viscosity, and V the box volume. We show that this correction accounts for the finite-size dependence of the rotational diffusion coefficients of horse-heart myoglobin and a B-DNA dodecamer in aqueous solution. The resulting hydrodynamic radii are in excellent agreement with experiment.
Stress evolution and associated microstructure during transient creep of olivine at 1000-1200 °C
NASA Astrophysics Data System (ADS)
Thieme, M.; Demouchy, S.; Mainprice, D.; Barou, F.; Cordier, P.
2018-05-01
We study the mechanical response and correlated microstructure of axial deformed fine-grained olivine aggregates as a function of incremental finite strains. Deformation experiments were conducted in uniaxial compression in an internally heated gas-medium deformation apparatus at temperatures of 1000 and 1200 °C, at strain rates of 10-6 s-1 to 10-5 s-1 and at confining pressure of 300 MPa. Sample volumes are around 1.2 cm3. Finite strains range from 0.1 to 8.6% and corresponding maximal (final) differential stresses range from 80 to 1073 MPa for deformation at 1000 °C and from 71 to 322 MPa for deformation at 1200 °C. At 1200 °C, samples approach steady state deformation after about 8% of strain. At 1000 °C, significant strain hardening leads to stresses exceeding the confining pressure by a factor of 3.5 with brittle deformation after 3% of strain. Deformed samples were characterized by electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). EBSD maps with step sizes as low as 50 nm were acquired without introducing analytical artifacts for the first time. The grain size of deformed samples ranges from 2.1 to 2.6 μm. Despite clear strain hardening, texture or microstructure do not change as a function of stress or finite strain. This observation is supported by a constant texture strength (J-index) and symmetry (BA-index), constant grain shape and aspect ratio, constant density of geometrically necessary dislocations, grain orientation spread, and constant subgrain boundary spacing and misorientation in between samples. TEM shows that all samples exhibit unambiguous dislocation activity but with a highly heterogeneous dislocation distribution. Olivine grains display evidence of [1 0 0] and [0 0 1] slip activity, but there is no evidence of interaction between the dislocations from the different slip systems. Several observations of grain boundaries acting as dislocation sources have been found. We find no confirmation of increasing dislocation densities as the cause for strain hardening during transient creep. This suggests other, yet not fully understood mechanisms affecting the strength of deformed olivine. These mechanisms could possibly involve grain boundaries. Such mechanisms are relevant for the deformation of uppermost mantle rocks, where the Si diffusion rate is too slow and dislocation glide must be accommodated in another way to fulfill the von Mises criterion.
NASA Astrophysics Data System (ADS)
Alessandrini, Giovanni; de Hoop, Maarten V.; Gaburro, Romina
2017-12-01
We discuss the inverse problem of determining the, possibly anisotropic, conductivity of a body Ω\\subset{R}n when the so-called Neumann-to-Dirichlet map is locally given on a non-empty curved portion Σ of the boundary \\partialΩ . We prove that anisotropic conductivities that are a priori known to be piecewise constant matrices on a given partition of Ω with curved interfaces can be uniquely determined in the interior from the knowledge of the local Neumann-to-Dirichlet map.
The perturbed compound Poisson risk model with constant interest and a threshold dividend strategy
NASA Astrophysics Data System (ADS)
Gao, Shan; Liu, Zaiming
2010-03-01
In this paper, we consider the compound Poisson risk model perturbed by diffusion with constant interest and a threshold dividend strategy. Integro-differential equations with certain boundary conditions for the moment-generation function and the nth moment of the present value of all dividends until ruin are derived. We also derive integro-differential equations with boundary conditions for the Gerber-Shiu functions. The special case that the claim size distribution is exponential is considered in some detail.
Numerical Solutions for Laminar Boundary Layer Behind Blast Waves.
1980-05-01
DISTRIBUTION STATEMENT (of thle Report) Approved for public release; distribution unlimited. 17 . DISTRIBUTION STATEMENT (of the abstract entered in Block 20...Reference I ............. 41 5. Boundary-Layer Functions for Case A, B, C, and D ......... 98 3 NOMENCLATURE A constant, Eqs. (10) and ( 17 ) B...the constant A was chosen as follows to simplify the coefficients of f and g1 A = 2mF CZ(a+i) OPO/pCO ( The ( 17 ) The explicit dependence of the flow
NASA Astrophysics Data System (ADS)
Rahman, K. R.; Chowdhury, F.-U.-Z.; Khan, M. N. I.
2017-12-01
In this paper, the effect of Al3+ substitution on the electrical and dielectric properties of Ni0.25Cu0.20Zn0.55AlxFe2-xO4 ferrites with x = 0.0, 0.05. 0.10, 0.15 and 0.20, synthesized by solid state reaction has been reported. Using two probe method, the DC resistivity has been investigated in the temperature range from 30 °C to 300 °C. Activation energy was calculated from the Arrhenius plot. The electrical conduction is explained on the basis of the hopping mechanism. The frequency dependent dielectric properties of these spinel ferrites have been studied at room temperature by measuring AC resistivity, conductivity (σac), dielectric constant and dielectric loss tangent (tan δ) in the frequency range between 1 kHz and 120 MHz. The study of dielectric properties showed that the dielectric constant and dielectric loss increased with increasing non-magnetic Al ions. The dependence of dielectric constant with frequency has been explained by Maxwell-Wagner interfacial polarization. Cole-Cole plots show semicircular arc(s) for the samples, and equivalent RC circuits have been proposed to clarify the phenomena involved therein. The analysis of complex impedance spectroscopy has been used to distinguish between the grain and grain boundary contribution to the total resistance.
Samuvel, K; Ramachandran, K
2015-02-05
A comparative study of the surface morphology, dielectric and magnetic properties of the BaTi0.5Fe0.5O3 (BTFO) ceramics materials. This has been carried out by synthesizing the samples in different routes. BTFO samples have shown single phased 12R type hexagonal structure with R3m, P4mm space group. Interfacial effects on the dielectric properties of the samples have been understood by Cole-Cole plots in complex impedance and modulus formalism. It has been identified that huge dielectric constant (10(3)-10(6)) at lower frequencies is largely contributed by the heterogeneous electronic microstructure at the interfaces of grains. Modulus formalism has identified the effects of both grain and grain boundary microstructure on the dielectric properties, particularly in chemical routed samples. The order of grain boundary resistivity suggests the semiconductor/insulator class of the material. The grain boundary resistivity of the mechanical alloyed samples is remarkably lower than the solid state and chemical routed samples. Few samples have of the samples have exhibited signature of ferromagnetism at the room temperature. Copyright © 2014 Elsevier B.V. All rights reserved.
Thermal stability of static coronal loops: Part 1: Effects of boundary conditions
NASA Technical Reports Server (NTRS)
Antiochos, S. K.; Shoub, E. C.; An, C. H.; Emslie, A. G.
1985-01-01
The linear stability of static coronal-loop models undergoing thermal perturbations was investigated. The effect of conditions at the loop base on the stability properties of the models was considered in detail. The question of appropriate boundary conditions at the loop base was considered and it was concluded that the most physical assumptions are that the temperature and density (or pressure) perturbations vanish there. However, if the base is taken to be sufficiently deep in the chromosphere, either several chromospheric scale heights or several coronal loop lengths in depth, then the effect of the boundary conditions on loop stability becomes negligible so that all physically acceptable conditions are equally appropriate. For example, one could as well assume that the velocity vanishes at the base. The growth rates and eigenmodes of static models in which gravity is neglected and in which the coronal heating is a relatively simple function, either constant per-unit mass or per-unit volume were calculated. It was found that all such models are unstable with a growth rate of the order of the coronal cooling time. The physical implications of these results for the solar corona and transition region are discussed.
Did the formation of D″ cause the Archaean-Proterozoic transition?
NASA Astrophysics Data System (ADS)
Campbell, Ian H.; Griffiths, Ross W.
2014-02-01
The MgO content of the highest MgO plume-related komatiites and picrites remained constant at 32±2.5% between 3.5 and 2.7 Ga, then fell to 21±3% by ca. 2.0 Ga, a value similar to the present day value. Because there is a linear relationship between the liquidus temperature of dry magmas and their MgO content this observation implies that the temperature of mantle plumes changed little between 3.5 and 2.7 Ga, and then fell by 200-250 °C between 2.7 and 2.0 Ga to a temperature similar to that of present plumes. We suggest that Archaean plumes originate from the core-mantle boundary and that their temperature remained constant because the temperature of the outer core was buffered by solidification of the Fe-Ni inner core. At about 2.7 Ga dense former basaltic crust began to accumulate at the core and eventually covered it to produce an insulating layer that reduced the heat flux out of the core and lowered the temperature of mantle plumes. The temperature of mantle plumes fell as the dense layer above the core thickened until it exceeded the critical thickness required for convection. Because heat is transferred rapidly across the convecting part of the insulating layer, any further increase in its thickness by the addition more basaltic material has no influence on the temperature at the top of the layer, which is the source of Post-Archaean mantle plumes. We equate the dense layer above the core with the seismically identified layer D″. Our analyses suggest the drop in plume temperatures produced by a dense insulating layer above the core will be about 40% once it starts to convect, which is consistent with the observed drop inferred from the decrease in the MgO content of komatiites and picrites at that time.
Climatic changes resulting from mass extinctions at the K-T boundary (and other bio-events)
NASA Technical Reports Server (NTRS)
Rampino, Michael R.; Volk, Tyler
1988-01-01
The mass extinctions at the Cretaceous-Tertiary (K-T) boundary include about 90 percent of marine calcareous nannoplankton (coccoliths), and carbon-isotope data show that marine primary productivity was drastically reduced for about 500,000 years after the boundary event, the so-called Strangelove Ocean effect. One result of the elimination of most marine phytoplankton would have been a severe reduction in production of dimethyl sulfide (DMS), a biogenic gas that is believed to be the major precursor of cloud condensation nuclei (CCN) over the oceans. A drastic reduction in marine CCN should lead to a cloud canopy with significantly lower reflectivity, and hence cause a significant warming at the earth's surface. Calculations suggest that, all other things being held constant, a reduction in CCN of more than 80 percent (a reasonable value for the K-T extinctions) could have produced a rapid global warming of 6 C or more. Oxygen-isotope analyses of marine sediments, and other kinds of paleoclimatic data, have provided for a marked warming, and a general instability of climate coincident with the killoff of marine plankton at the K-T boundary. Similar reductions in phytoplankton abundance at other boundaries, as indicated by marked shifts in carbon-isotope curves, suggest that severe temperature changes may have accompanied other mass extinctions, and raises the intriguing possibility that the extinction events themselves could have contributed to the climatic instabilities at critical bio-events in the geologic record.
Electric Double-Layer Interaction between Dissimilar Charge-Conserved Conducting Plates.
Chan, Derek Y C
2015-09-15
Small metallic particles used in forming nanostructured to impart novel optical, catalytic, or tribo-rheological can be modeled as conducting particles with equipotential surfaces that carry a net surface charge. The value of the surface potential will vary with the separation between interacting particles, and in the absence of charge-transfer or electrochemical reactions across the particle surface, the total charge of each particle must also remain constant. These two physical conditions require the electrostatic boundary condition for metallic nanoparticles to satisfy an equipotential whole-of-particle charge conservation constraint that has not been studied previously. This constraint gives rise to a global charge conserved constant potential boundary condition that results in multibody effects in the electric double-layer interaction that are either absent or are very small in the familiar constant potential or constant charge or surface electrochemical equilibrium condition.
NASA Astrophysics Data System (ADS)
Chakraborty, Sarit; Mandal, S. K.; Dey, P.; Saha, B.
2018-04-01
Multiferroic magnetoelectric materials are very interesting for the researcher for the potential application in device preparation. We have prepared 0.3Ni0.5Co0.5Fe2O4 - 0.7PbZr0.58Ti0.42O3 magnetoelectric nanocomposites through chemical pyrophoric reaction process followed by solid state reaction and represented magnetoelectric coupling coefficient, thermally and magnetically tunable AC electrical properties. For the structural characterization XRD pattern and SEM micrograph have been analyzed. AC electrical properties reveal that the grain boundaries resistances are played dominating role in the conduction process in the system. Dielectric studies are represents that the dielectric polarization is decreased with frequency as well as magnetic field where it increases with increasing temperature. The dielectric profiles also represents the electromechanical resonance at a frequency of ˜183 kHz. High dielectric constant and low dielectric loss at room temperature makes the material very promising for the application of magnetic field sensor devices.
Supplemental multilayer insulation research facility
NASA Technical Reports Server (NTRS)
Dempsey, P. J.; Stochl, R. J.
1995-01-01
The Supplemental Multilayer Insulation Research Facility (SMIRF) provides a small scale test bed for conducting cryogenic experiments in a vacuum environment. The facility vacuum system is capable of simulating a Space Shuttle launch pressure profile as well as providing a steady space vacuum environment of 1.3 x 10(exp -4) Newton/sq meter (1 x 10(exp -6) torr). Warm side boundary temperatures can be maintained constant between 111 K (200 R) and 361 K (650 R) using a temperature controlled shroud. The shroud can also simulate a typical lunar day-night temperature profile. The test hardware consists of a cryogenic calorimeter supported by the lid of the vacuum chamber. A 0.45 cu meter (120 gallon) vacuum jacketed storage/supply tank is available for conditioning the cryogen prior to use in the calorimeter. The facility was initially designed to evaluate the thermal performance of insulation systems for long-term storage in space. The facility has recently been used to evaluate the performance of various new insulation systems for LH2 and LN2 ground storage dewars.
Water cycle and its management for plant habitats at reduced pressures
NASA Technical Reports Server (NTRS)
Rygalov, Vadim Y.; Fowler, Philip A.; Wheeler, Raymond M.; Bucklin, Ray A.
2004-01-01
Experimental and mathematical models were developed for describing and testing temperature and humidity parameters for plant production in bioregenerative life support systems. A factor was included for analyzing systems operating at low (10-101.3 kPa) pressure to reduce gas leakage and structural mass (e.g., inflatable greenhouses for space application). The expected close relationship between temperature and relative humidity was observed, along with the importance of heat exchanger coil temperature and air circulation rate. The presence of plants in closed habitats results in increased water flux through the system. Changes in pressure affect gas diffusion rates and surface boundary layers, and change convective transfer capabilities and water evaporation rates. A consistent observation from studies with plants at reduced pressures is increased evapotranspiration rates, even at constant vapor pressure deficits. This suggests that plant water status is a critical factor for managing low-pressure production systems. The approach suggested should help space mission planners design artificial environments in closed habitats.
Water cycle and its management for plant habitats at reduced pressures.
Rygalov, Vadim Y; Fowler, Philip A; Wheeler, Raymond M; Bucklin, Ray A
2004-01-01
Experimental and mathematical models were developed for describing and testing temperature and humidity parameters for plant production in bioregenerative life support systems. A factor was included for analyzing systems operating at low (10-101.3 kPa) pressure to reduce gas leakage and structural mass (e.g., inflatable greenhouses for space application). The expected close relationship between temperature and relative humidity was observed, along with the importance of heat exchanger coil temperature and air circulation rate. The presence of plants in closed habitats results in increased water flux through the system. Changes in pressure affect gas diffusion rates and surface boundary layers, and change convective transfer capabilities and water evaporation rates. A consistent observation from studies with plants at reduced pressures is increased evapotranspiration rates, even at constant vapor pressure deficits. This suggests that plant water status is a critical factor for managing low-pressure production systems. The approach suggested should help space mission planners design artificial environments in closed habitats.
Effects of grain size on the strength and ductility of Ni sub 3 Al and Ni sub 3 Al + boron
DOE Office of Scientific and Technical Information (OSTI.GOV)
Viens, D.V.; Weihs, T.P.; Baker, I.
Tensile and compression experiments have been performed on Ni{sub 3}Al and on Ni{sub 3}Al + B at 77K to 1023K at 1 {times} 10{sup {minus}4}s{sup {minus}1}. At low temperatures yielding occurs discontinuously and the yield strength obeys the relationship {sigma}{sub y} = {sigma}{sub i} + kd{sup {minus}3/4} where {sigma}{sub i} and k are constants. Grain refinement has little effect on the ductility of the binary alloy, but leads to a brittle to ductile transition in the alloy containing boron. At high temperatures, grain refinement weakens the material, owing to grain boundary sliding. Dynamic recrystalization occurs and leads to another brittlemore » to ductile transition upon refining the grains. Under all conditions investigated, fracture occurs intergranularly. An analysis based upon a work-hardening model is given for the d{sup {minus}3/4} dependence of the yield strength at low temperatures.« less
Miyake, Yusuke; Akai, Nobuyuki; Kawai, Akio; Shibuya, Kazuhiko
2011-06-23
Rotational motion of a nitroxide radical, peroxylamine disulfonate (PADS), dissolved in room temperature ionic liquids (RTILs) was studied by analyzing electron paramagnetic resonance spectra of PADS in various RTILs. We determined physical properties of PADS such as the hyperfine coupling constant (A), the temperature dependence of anisotropic rotational correlation times (τ(∥) and τ(⊥)), and rotational anisotropy (N). We observed that the A values remain unchanged for various RTILs, which indicates negligible interaction between the N-O PADS group and the cation of RTIL. Large N values suggest strong interaction of the negative sulfonyl parts of PADS with the cations of RTILs. Most of the τ(∥), τ(⊥), and (τ(∥)τ(⊥))(1/2) values are within the range calculated on the basis of a hydrodynamic theory with stick and slip boundary conditions. It was deduced that this theory could not adequately explain the measured results in some RTILs with smaller BF(4) and PF(6) anions.
Cho, Ahra; Han, Chan Su; Kang, Meenjoo; Choi, Wooseok; Lee, Jihwan; Jeon, Jaecheol; Yu, Sujae; Jung, Ye Seul; Cho, Yong Soo
2018-05-09
Colossal dielectric constant CaCu 3 Ti 4 O 12 has been recognized as one of the rare materials having intrinsic interfacial polarization and thus unusual dielectric characteristics, in which the electrical state of the grain boundary is critical. Here, the direct correlation between the grain boundary potential and relative permittivity is proposed for the CaCu 3 Ti 4 O 12 thin films doped with Zn, Ga, Mn, and Ag as characterized by Kelvin probe force microscopy. The dopants are intended to provide the examples of variable grain boundary potentials that are driven by chemical states including Cu + , Ti 3+ , and oxygen vacancy. Grain boundary potential is nearly linearly proportional to the dielectric constant. This effect is attributed to the increased charge accumulation near the grain boundary, depending on the choice of the dopant. As an example, 1 mol % Ag-doped CaCu 3 Ti 4 O 12 thin films demonstrate the best relative permittivity as associated with a higher grain boundary potential of 120.3 mV compared with 82.6 mV for the reference film. The chemical states across grain boundaries were further verified by using spherical aberration-corrected scanning transmission electron microscopy with the simultaneous electron energy loss spectroscopy.
NASA Technical Reports Server (NTRS)
Vanness, W.
1978-01-01
A summary report of boundary layer studies is presented. Preliminary results of experimental measurements show that: (1) A very thin layer (approximately 0.4 mm) of the boundary layer seems to be accelerated; (2) the static pressure of the outer flow does not remain exactly constant through the boundary layer; and (3) an oncoming boundary layer which is already turbulent at the suction point can again become laminar behind this point without being completely sucked off.
NASA Astrophysics Data System (ADS)
Wang, Lei; Dai, Cheng; Xue, Liang
2018-04-01
This study presents a Laplace-transform-based boundary element method to model the groundwater flow in a heterogeneous confined finite aquifer with arbitrarily shaped boundaries. The boundary condition can be Dirichlet, Neumann or Robin-type. The derived solution is analytical since it is obtained through the Green's function method within the domain. However, the numerical approximation is required on the boundaries, which essentially renders it a semi-analytical solution. The proposed method can provide a general framework to derive solutions for zoned heterogeneous confined aquifers with arbitrarily shaped boundary. The requirement of the boundary element method presented here is that the Green function must exist for a specific PDE equation. In this study, the linear equations for the two-zone and three-zone confined aquifers with arbitrarily shaped boundary is established in Laplace space, and the solution can be obtained by using any linear solver. Stehfest inversion algorithm can be used to transform it back into time domain to obtain the transient solution. The presented solution is validated in the two-zone cases by reducing the arbitrarily shaped boundaries to circular ones and comparing it with the solution in Lin et al. (2016, https://doi.org/10.1016/j.jhydrol.2016.07.028). The effect of boundary shape and well location on dimensionless drawdown in two-zone aquifers is investigated. Finally the drawdown distribution in three-zone aquifers with arbitrarily shaped boundary for constant-rate tests (CRT) and flow rate distribution for constant-head tests (CHT) are analyzed.
DSMC simulations of leading edge flat-plate boundary layer flows at high Mach number
NASA Astrophysics Data System (ADS)
Pradhan, Sahadev
2016-09-01
The flow over a 2D leading-edge flat plate is studied at Mach number Ma = (Uinf /√{kBTinf / m }) in the range
THE COUPLED EVOLUTION OF ELECTRONS AND IONS IN CORONAL MASS EJECTION-DRIVEN SHOCKS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Manchester IV, W. B.; Van der Holst, B.; Toth, G.
2012-09-01
We present simulations of coronal mass ejections (CMEs) performed with a new two-temperature coronal model developed at the University of Michigan, which is able to address the coupled thermodynamics of the electron and proton populations in the context of a single fluid. This model employs heat conduction for electrons, constant adiabatic index ({gamma} = 5/3), and includes Alfven wave pressure to accelerate the solar wind. The Wang-Sheeley-Arge empirical model is used to determine the Alfven wave pressure necessary to produce the observed bimodal solar wind speed. The Alfven waves are dissipated as they propagate from the Sun and heat protonsmore » on open magnetic field lines to temperatures above 2 MK. The model is driven by empirical boundary conditions that includes GONG magnetogram data to calculate the coronal field, and STEREO/EUVI observations to specify the density and temperature at the coronal boundary by the Differential Emission Measure Tomography method. With this model, we simulate the propagation of fast CMEs and study the thermodynamics of CME-driven shocks. Since the thermal speed of the electrons greatly exceeds the speed of the CME, only protons are directly heated by the shock. Coulomb collisions low in the corona couple the protons and electrons allowing heat exchange between the two species. However, the coupling is so brief that the electrons never achieve more than 10% of the maximum temperature of the protons. We find that heat is able to conduct on open magnetic field lines and rapidly propagates ahead of the CME to form a shock precursor of hot electrons.« less
Ackerman, Daniel J.; Rattray, Gordon W.; Rousseau, Joseph P.; Davis, Linda C.; Orr, Brennon R.
2006-01-01
Ground-water flow in the west-central part of the eastern Snake River Plain aquifer is described in a conceptual model that will be used in numerical simulations to evaluate contaminant transport at the Idaho National Laboratory (INL) and vicinity. The model encompasses an area of 1,940 square miles (mi2) and includes most of the 890 mi2 of the INL. A 50-year history of waste disposal associated with research activities at the INL has resulted in measurable concentrations of waste contaminants in the aquifer. A thorough understanding of the fate and movement of these contaminants in the subsurface is needed by the U.S. Department of Energy to minimize the effect that contaminated ground water may have on the region and to plan effectively for remediation. Three hydrogeologic units were used to represent the complex stratigraphy of the aquifer in the model area. Collectively, these hydrogeologic units include at least 65 basalt-flow groups, 5 andesite-flow groups, and 61 sedimentary interbeds. Three rhyolite domes in the model area extend deep enough to penetrate the aquifer. The rhyolite domes are represented in the conceptual model as low permeability, vertical pluglike masses, and are not included as part of the three primary hydrogeologic units. Broad differences in lithology and large variations in hydraulic properties allowed the heterogeneous, anisotropic basalt-flow groups, andesite-flow groups, and sedimentary interbeds to be grouped into three hydrogeologic units that are conceptually homogeneous and anisotropic. Younger rocks, primarily thin, densely fractured basalt, compose hydrogeologic unit 1; younger rocks, primarily of massive, less densely fractured basalt, compose hydrogeologic unit 2; and intermediate-age rocks, primarily of slightly-to-moderately altered, fractured basalt, compose hydrogeologic unit 3. Differences in hydraulic properties among adjacent hydrogeologic units result in much of the large-scale heterogeneity and anisotropy of the aquifer in the model area, and differences in horizontal and vertical hydraulic conductivity in individual hydrogeologic units result in much of the small-scale heterogeneity and anisotropy of the aquifer in the model area. The inferred three-dimensional geometry of the aquifer in the model area is very irregular. Its thickness generally increases from north to south and from west to east and is greatest south of the INL. The interpreted distribution of older rocks that underlie the aquifer indicates large changes in saturated thickness across the model area. The boundaries of the model include physical and artificial boundaries, and ground-water flows across the boundaries may be temporally constant or variable and spatially uniform or nonuniform. Physical boundaries include the water-table boundary, base of the aquifer, and northwest mountain-front boundary. Artificial boundaries include the northeast boundary, southeast-flowline boundary, and southwest boundary. Water flows into the model area as (1) underflow (1,225 cubic feet per second (ft3/s)) from the regional aquifer (northeast boundary-constant and nonuniform), (2) underflow (695 ft3/s) from the tributary valleys and mountain fronts (northwest boundary-constant and nonuniform), (3) precipitation recharge (70 ft3/s) (constant and uniform), streamflow-infiltration recharge (95 ft3/s) (variable and nonuniform), wastewater return flows (6 ft3/s) (variable and nonuniform), and irrigation-infiltration recharge (24 ft3/s) (variable and nonuniform) across the water table (water-table boundary-variable and nonuniform), and (4) upward flow across the base of the aquifer (44 ft3/s) (uniform and constant). The southeast-flowline boundary is represented as a no-flow boundary. Water flows out of the model area as underflow (2,037 ft3/s) to the regional aquifer (southwest boundary-variable and nonuniform) and as ground-water withdrawals (45 ft3/s) (water table boundary-variable and nonuniform). Ground-water flow i
NASA Technical Reports Server (NTRS)
Funaro, Daniele; Gottlieb, David
1989-01-01
A new method of imposing boundary conditions in the pseudospectral approximation of hyperbolic systems of equations is proposed. It is suggested to collocate the equations, not only at the inner grid points, but also at the boundary points and use the boundary conditions as penalty terms. In the pseudo-spectral Legrendre method with the new boundary treatment, a stability analysis for the case of a constant coefficient hyperbolic system is presented and error estimates are derived.
A theory for the atmospheric energy spectrum: depth-limited temperature anomalies at the tropopause.
Tulloch, R; Smith, K S
2006-10-03
The horizontal spectra of atmospheric wind and temperature at the tropopause have a steep -3 slope at synoptic scales, but transition to -5/3 at wavelengths of the order of 500-1,000 km [Nastrom, G. D. & Gage, K. S. (1985) J. Atmos. Sci. 42, 950-960]. Here we demonstrate that a model that assumes zero potential vorticity and constant stratification N over a finite-depth H in the troposphere exhibits the same type of spectra. In this model, temperature perturbations generated at the planetary scale excite a direct cascade of energy with a slope of -3 at large scales, -5/3 at small scales, and a transition near horizontal wavenumber k(t) = f/NH, where f is the Coriolis parameter. Ballpark atmospheric estimates for N, f, and H give a transition wavenumber near that observed, and numerical simulations of the previously undescribed model verify the expected behavior. Despite its simplicity, the model is consistent with a number of perplexing features in the observations and demonstrates that a complete theory for mesoscale dynamics must take temperature advection at boundaries into account.
NASA Technical Reports Server (NTRS)
Segal, Corin; Mcdaniel, James C.; Whitehurst, Robert B.; Krauss, Roland H.
1991-01-01
A study of transverse hydrogen injection behind a rearward facing step in a Mach 2 airflow was conducted to determine the combustion efficiency and the combustor/inlet interactions at the low temperature lean-mixture operational end of a scramjet combustor model. The fuel was injected at sonic conditions into the electrically heated airstream, which was maintained at 850 K or below. The static pressure delivered at the entrance of the combustor ranged between 0.25 to 0.5 atm. Injector configurations included single and staged injectors placed at 3 or 3-and-7 step-heights downstream of the step, respectively, with injector diameters of 1, 1.5, and 2 mm. Ignition was achieved by initially unstarting the test section. The constant area combustor and the low initial temperatures caused thermal choking and upstream interaction to occur at very low equivalence ratios. Typically, most of the fuel was burned in the recirculation region behind the step and around the jets. The effects of initial conditions (temperature and pressure), fuel-to-air dynamic pressure ratio, and boundaries (thermal vs adiabatic) are presented.
Charge density wave order in 1D mirror twin boundaries of single-layer MoSe 2
Barja, Sara; Wickenburg, Sebastian; Liu, Zhen-Fei; ...
2016-04-18
Here, We provide direct evidence for the existence of isolated, one-dimensional charge density waves at mirror twin boundaries (MTBs) of single-layer semiconducting MoSe 2. Such MTBs have been previously observed by transmission electron microscopy and have been predicted to be metallic in MoSe 2 and MoS 2. Our low-temperature scanning tunnelling microscopy/spectroscopy measurements revealed a substantial bandgap of 100 meV opening at the Fermi energy in the otherwise metallic one-dimensional structures. We found a periodic modulation in the density of states along the MTB, with a wavelength of approximately three lattice constants. In addition to mapping the energy-dependent densitymore » of states, we determined the atomic structure and bonding of the MTB through simultaneous high-resolution non-contact atomic force microscopy. Density functional theory calculations based on the observed structure reproduced both the gap opening and the spatially resolved density of states.« less
Steady state and a general scale law of deformation
NASA Astrophysics Data System (ADS)
Huang, Yan
2017-07-01
Steady state deformation has been characterized based on the experimental results for dilute single-phase aluminium alloys. It was found that although characteristic properties such as flow stress and grain size remained constant with time, a continuous loss of grain boundaries occurred as an essential feature at steady state. A physical model, which takes into account the activity of grain boundary dislocations, was developed to describe the kinetics of steady state deformation. According to this model, the steady state as a function of strain rate and temperature defines the limit of the conventional grain size and strength relationship, i.e., the Hall-Petch relation holds when the grain size is larger than that at the steady state, and an inverse Hall-Petch relation takes over if grain size is smaller than the steady state value. The transition between the two relationships relating grain size and strength is a phenomenon that depends on deformation conditions, rather than an intrinsic property as generally perceived. A general scale law of deformation is established accordingly.
Dynamical Defects in Rotating Magnetic Skyrmion Lattices
NASA Astrophysics Data System (ADS)
Pöllath, S.; Wild, J.; Heinen, L.; Meier, T. N. G.; Kronseder, M.; Tutsch, L.; Bauer, A.; Berger, H.; Pfleiderer, C.; Zweck, J.; Rosch, A.; Back, C. H.
2017-05-01
The chiral magnet Cu2 OSeO3 hosts a Skyrmion lattice that may be equivalently described as a superposition of plane waves or a lattice of particlelike topological objects. A thermal gradient may break up the Skyrmion lattice and induce rotating domains, raising the question of which of these scenarios better describes the violent dynamics at the domain boundaries. Here, we show that in an inhomogeneous temperature gradient caused by illumination in a Lorentz transmission electron microscope different parts of the Skyrmion lattice can be set into motion with different angular velocities. Tracking the time dependence, we show that the constant rearrangement of domain walls is governed by dynamic 5-7 defects arranging into lines. An analysis of the associated defect density is described by Frank's equation and agrees well with classical 2D Monte Carlo simulations. Fluctuations of boundaries show a surgelike rearrangement of Skyrmion clusters driven by defect rearrangement consistent with simulations treating Skyrmions as point particles. Our findings underline the particle character of the Skyrmion.
Effect of DC bias on dielectric properties of nanocrystalline CuAlO2
NASA Astrophysics Data System (ADS)
Prakash, T.; Ramasamy, S.; Murty, B. S.
2013-03-01
Grain boundary effect on the room temperature dielectric behavior in mechanically alloyed nanocrystalline CuAlO2 has been investigated using impedance spectroscopy under the applied DC bias voltages 0 V to 4.8 V in a periodic interval of 0.2 V. Analysis of impedance data confirms the existence of double Schottky potential barrier heights ( Φ b ) between two adjacent grains (left and right side) with grain boundary and its influences in dielectric relaxation time ( τ), dielectric constant ( ɛ') and dielectric loss (tan δ) factor. Also, clear evidence on the suppression of Φ b was demonstrated in the higher applied bias voltages with the parameter τ. At equilibrium state, τ is 0.63 ms and it was reduced to 0.13 ms after the 3.2 V applied DC bias. These observed DC bias voltage effects are obeying `brick layer model' and also elucidates Φ b is playing a crucial role in controlling dielectric properties of nanomaterials.
An approach to get thermodynamic properties from speed of sound
NASA Astrophysics Data System (ADS)
Núñez, M. A.; Medina, L. A.
2017-01-01
An approach for estimating thermodynamic properties of gases from the speed of sound u, is proposed. The square u2, the compression factor Z and the molar heat capacity at constant volume C V are connected by two coupled nonlinear partial differential equations. Previous approaches to solving this system differ in the conditions used on the range of temperature values [Tmin,Tmax]. In this work we propose the use of Dirichlet boundary conditions at Tmin, Tmax. The virial series of the compression factor Z = 1+Bρ+Cρ2+… and other properties leads the problem to the solution of a recursive set of linear ordinary differential equations for the B, C. Analytic solutions of the B equation for Argon are used to study the stability of our approach and previous ones under perturbation errors of the input data. The results show that the approach yields B with a relative error bounded basically by that of the boundary values and the error of other approaches can be some orders of magnitude lager.
Effect of Differential Diffusion in Two-Component Media
NASA Astrophysics Data System (ADS)
Ingel', L. Kh.
2017-03-01
Examples are presented of an exact solution of a nonstationary problem on the development of convection in a binary mixture (seawater) near an infinite vertical surface in which the buoyancy disturbances are determined both by the temperature and by the disturbances of the impurity (salt) concentration. Consideration is given to the development of convection in a homogeneous medium near an infinite vertical surface at whose boundary specification is made of constant (after ″switching on″ at the initial moment) heat fluxes and impurities or variations of these substances, i.e., problems with boundary conditions of 1st and 2nd kind are considered. The obtained analytical solutions demonstrate the possibility of a nontrivial effect associated with the difference in the values of the coefficients of transfer of two substances: the inflows of positive buoyancy may lead, contrary to intuitive notions, to the origination of descending motion of the medium rather than the ascending one. Clarification is provided for the physical meaning of such effects, which can be substantial, for example, in melting of sea ice.
Numerical Modeling of Hydrothermal Circulation at the Longqi-1 Field: Southwest Indian Ridge
NASA Astrophysics Data System (ADS)
Guo, Z.; Lowell, R. P.; Tao, C.; Rupke, L.; Lewis, K. C.
2017-12-01
The Longqi-1(Dragon Flag) hydrothermal field is the first high-temperature hydrothermal system observed on the ultra-slow spreading Southwest Indian Ridge. Hydrothermal vents with temperatures near 380 °C are localized by detachment faulting within which extensional deformation likely increases permeability to provide preferred pathways for hydrothermal discharge. To better understand the Longqi-1 circulation system, we construct a 2-D numerical simulations in a NaCl- H2O fluid constrained by key observational data, such as vent temperature and heat output, crust structure derived from seismic data, and fault zone geometry deduced from seismicity. Heat output from AUV surveys is estimated to be » 300 ± 100 MW, and this value, in conjunction with vent temperature was used with the single-pass modeling approach to obtain an average permeability of 10-13 m-2 within the fault zone. In analogy with other fault-controlled hydrothermal systems such as Logatchev-1 we assume a lower background permeability of 10-14 m-2. The top boundary of the system is permeable and maintained at constant seafloor pressure, which is divided into two parts by the detachment fault. The pressure of the southern part is lower than the northern part to simulate the effect of the seafloor topography. The top boundary is upstream weighted to allow high temperature fluid to exit, while recharging fluid is maintained at 10°C. The bottom boundary is impermeable and is given a fixed temperature distribution at a depth of 7 km below the seafloor. The highest value Tmax is maintained over a distance given lateral distance and decreases linearly towards two ends to 300 °C. The salinity is set to 3.2 wt. % NaCl, and the simulations are assumed to be single phase. The results show that with a 7 km deep circulation system, Tmax = 550 oC gives a reasonable temperature and heat output of venting plume.We infer that the observed high salinity results from serpentinization reactions. Assuming all salinity in excess of seawater comes from uptake of H2O during serpentinization, we can estimate the rate of reaction and heat release of serpentinezation based on a simplified reaction equation, observed heat output and salinity data. The estimated rate of heat release during serpentinization is 20 MW. This is approximately 10% of the heat output of Dragon Flag vent field.
NASA Astrophysics Data System (ADS)
Bourras, Denis; Eymard, Laurence; Liu, W. Timothy; Dupuis, Hélène
2002-03-01
A new technique was developed to retrieve near-surface instantaneous air temperatures and turbulent sensible heat fluxes using satellite data during the Structure des Echanges Mer-Atmosphere, Proprietes des Heterogeneites Oceaniques: Recherche Experimentale (SEMAPHORE) experiment, which was conducted in 1993 under mainly anticyclonic conditions. The method is based on a regional, horizontal atmospheric temperature advection model whose inputs are wind vectors, sea surface temperature fields, air temperatures around the region under study, and several constants derived from in situ measurements. The intrinsic rms error of the method is 0.7°C in terms of air temperature and 9 W m2 for the fluxes, both at 0.16° × 0.16° and 1.125° × 1.125° resolution. The retrieved air temperature and flux horizontal structures are in good agreement with fields from two operational general circulation models. The application to SEMAPHORE data involves the First European Remote Sensing Satellite (ERS-1) wind fields, Advanced Very High Resolution Radiometer (AVHRR) SST fields, and European Centre for Medium-Range Weather Forecasts (ECMWF) air temperature boundary conditions. The rms errors obtained by comparing the estimations with research vessel measurements are 0.3°C and 5 W m2.
New potassium-sodium niobate lead-free piezoceramic: Giant-d33 vs. sintering temperature
NASA Astrophysics Data System (ADS)
Wu, Jiagang; Wang, Xiaopeng; Cheng, Xiaojing; Zheng, Ting; Zhang, Binyu; Xiao, Dingquan; Zhu, Jianguo; Lou, Xiaojie
2014-03-01
The objective of this work is to achieve a giant piezoelectric constant in (K,Na)NbO3-based lead-free ceramics, and then 0.96K0.46Na0.54Nb0.95Sb0.05O3-0.04Bi0.5(Na0.82K0.18)0.5ZrO3 lead-free piezoceramics were designed and prepared by optimizing the sintering temperature (TS). The rhombohedral-tetragonal phase boundary is found in the ceramics sintered at 1070 ˜ 1105 °C and is suppressed when sintered at low TS of 1060 ˜ 1065 °C. The threshold for TS is 1070 °C in terms of their ferroelectric and piezoelectric properties owing to the difference in the phase boundary and the microstructure, and a large d33 of 388 ˜ 465 pC/N could be attained in a wide TS range of 1070 ˜ 1105 °C, benefiting their practical applications because of broad TS. More interestingly, the ceramic sintered at 1075 °C has a giant d33 of ˜465 pC/N. We think that such a giant d33 of this material system can benefit the development of (K,Na)NbO3-based piezoceramics.
Use of advanced particle methods in modeling space propulsion and its supersonic expansions
NASA Astrophysics Data System (ADS)
Borner, Arnaud
This research discusses the use of advanced kinetic particle methods such as Molecular Dynamics (MD) and direct simulation Monte Carlo (DSMC) to model space propulsion systems such as electrospray thrusters and their supersonic expansions. MD simulations are performed to model an electrospray thruster for the ionic liquid (IL) EMIM--BF4 using coarse-grained (CG) potentials. The model is initially featuring a constant electric field applied in the longitudinal direction. Two coarse-grained potentials are compared, and the effective-force CG (EFCG) potential is found to predict the formation of the Taylor cone, the cone-jet, and other extrusion modes for similar electric fields and mass flow rates observed in experiments of a IL fed capillary-tip-extractor system better than the simple CG potential. Later, one-dimensional and fully transient three-dimensional electric fields, the latter solving Poisson's equation to take into account the electric field due to space charge at each timestep, are computed by coupling the MD model to a Poisson solver. It is found that the inhomogeneous electric field as well as that of the IL space-charge improve agreement between modeling and experiment. The boundary conditions (BCs) are found to have a substantial impact on the potential and electric field, and the tip BC is introduced and compared to the two previous BCs, named plate and needle, showing good improvement by reducing unrealistically high radial electric fields generated in the vicinity of the capillary tip. The influence of the different boundary condition models on charged species currents as a function of the mass flow rate is studied, and it is found that a constant electric field model gives similar agreement to the more rigorous and computationally expensive tip boundary condition at lower flow rates. However, at higher mass flow rates the MD simulations with the constant electric field produces extruded particles with higher Coulomb energy per ion, consistent with droplet formation. Supersonic expansions to vacuum produce clusters of sufficiently small size that properties such as heat capacities and latent heat of evaporation cannot be described by bulk vapor thermodynamic values. Therefore, MD simulations are performed to compute the evaporation rate of small water clusters as a function of temperature and size and the rates are found to agree with Unimolecular Dissociation Theory (UDT) and Classical Nucleation Theory (CNT). The heat capacities and latent heat of vaporization obtained from Monte-Carlo Canonical-Ensemble (MCCE) simulations are used in DSMC simulations of two experiments that measured Rayleigh scattering and terminal dimer mole fraction of supersonic water-jet expansions. Water-cluster temperature and size are found to be influenced by the use of kinetic rather than thermodynamic heat-capacity and latent-heat values as well as the nucleation model. Additionally, MD simulations of water condensation in a one-dimensional free expansion are performed to simulate the conditions in the core of a plume. We find that the internal structure of the clusters formed depends on the stagnation temperature conditions. Clusters of sizes 21 and 324 are studied in detail, and their radial distribution functions (RDF) are computed and compared to reported RDFs for solid amorphous ice clusters. Dielectric properties of liquid water and water clusters are investigated, and the static dielectric constant, dipole moment autocorrelation function and relative permittivity are computed by means of MD simulations.
Modelling and analysis of creep deformation and fracture in a 1 Cr 1/2 Mo ferritic steel
NASA Astrophysics Data System (ADS)
Dyson, B. F.; Osgerby, D.
A quantitative model, based upon a proposed new mechanism of creep deformation in particle-hardened alloys, has been validated by analysis of creep data from a 13CrMo 4 4 (1Cr 1/2 Mo) material tested under a range of stresses and temperatures. The methodology that has been used to extract the model parameters quantifies, as a first approximation, only the main degradation (damage) processes - in the case of the 1CR 1/2 Mo steel, these are considered to be the parallel operation of particle-coarsening and a progressively increasing stress due to a constant-load boundary condition. These 'global' model parameters can then be modified (only slightly) as required to obtain a detailed description and 'fit' to the rupture lifetime and strain/time trajectory of any individual test. The global model parameter approach may be thought of as predicting average behavior and the detailed fits as taking account of uncertainties (scatter) due to variability in the material. Using the global parameter dataset, predictions have also been made of behavior under biaxial stressing; constant straining rate; constant total strain (stress relaxation) and the likely success or otherwise of metallographic and mechanical remanent lifetime procedures.
NASA Astrophysics Data System (ADS)
Chang, Kai-Shiun; Lin, Yi-Feng; Tung, Kuo-Lun
A molecular dynamics (MD) simulation is used to reveal the grain boundary effect on the ionic transport of yttria-stabilized zirconia (YSZ). The oxygen ion displacements and diffusivities of the ideal and grain boundary-inserted YSZ models are analyzed at elevated temperatures. An optimized Y 2O 3 concentration within YSZ for the best ionic conductivity is achieved by balancing the trade-off between the increased vacancies and the decreased accessible free space. The mass transfer resistance of the grain boundary in YSZ can be more easily found at higher temperatures by observing the oxygen ion diffusivities or traveling trajectories. At lower temperatures, the grain interior and the grain boundary control the ionic transport. In contrast, the grain boundary effect on the diffusion barrier is gradually eliminated at elevated temperatures. The modeled results in this work agree well with previous experimental data.
NASA Astrophysics Data System (ADS)
Palmieri, Vincenzo; Rossi, Antonio Alessandro; Stark, Sergey Yu; Vaglio, Ruggero
2014-08-01
The majority of the literature on superconducting cavities for particle accelerators concentrates on the interaction of a radiofrequency (RF) electromagnetic field with a superconductor cooled in liquid helium, generally either at a fixed temperature of 4.2 K or 1.8 K, basing the analysis of experimental results on the assumption that the superconductor is at the same temperature as the infinite reservoir of liquid helium. Only a limited number of papers have extended their analysis to the more complex overall system composed of an RF field, a superconductor and liquid helium. Only a few papers have analyzed, for example, the problem of the Kapitza resistance, i.e. the thermal boundary resistance between the superconductor and the superfluid helium. Among them, the general conclusion is that the Kapitza resistance, one of the most controversial and less understood topics in physics, is generally negligible, or not relevant for the performance enhancement of cavities. In our work presented here, studying the performance of 6 GHz niobium (Nb) test cavities, we have discovered and studied a new effect consisting of an abrupt change in the surface resistance versus temperature at the superfluid helium lambda transition Tλ. This abrupt change (or ‘jump’) clearly appears when the RF measurement of a cavity is performed at constant power rather than at a constant field. We have correlated this jump to a change in the thermal exchange regime across the lambda transition, and, through a simple thermal model and further reasonable assumptions, we have calculated the thermal boundary resistance between niobium and liquid helium in the temperature range between 4.2 K and 1.8 K. We find that the absolute values of the thermal resistance both above and below the lambda point are fully compatible with the data reported in the literature for heat transfer to pool boiling helium I (HeI) above Tλ and for the Kapitza interface resistance (below Tλ) between a polished metal surface and superfluid HeII. Finally, based on the well-documented evidence that the surface status of metal to liquid helium influences the heat exchange towards the fluid, and specifically the Kapitza resistance below Tλ, we have tested an anodization process external to the cavity, comparing the performances of the cavity before and after external anodization. The tests were done without breaking the vacuum inside the cavity or modifying the inner superconducting layer in any way, and were repeated on different samples. The results show that when the cavity is externally anodized, both the Q-factor and the maximum accelerating field increase. Again, when the oxide layer is removed, the Q-factor shifts towards a lower level and the maximum accelerating field is also reduced.
Processing and electrical properties of gallium-substituted lead zirconate titanate ceramics
NASA Astrophysics Data System (ADS)
Hajra, Sugato; Sharma, Pulkit; Sahoo, Sushrisangita; Rout, P. K.; Choudhary, R. N. P.
2017-12-01
In the present paper, the effect of gallium (Ga) substitution on structural, microstructural, electrical conductivity of Pb(ZrTi)O3 (PZT) in the morphotropic phase boundary (MPB) region (i.e., Pb0.96Ga0.04(Zr0.48Ti0.52)0.99O3 (PGaZT-4)) was investigated. Increased grain density increases the resistivity of the Ga-modified PZT system. Preliminary structural analysis using X-ray diffraction pattern and data showed the existence of two phases [major tetragonal (T) and minor monoclinic (M)]. Field emission scanning electron micrograph (FESEM) showed the distribution of spherical as well as platelet type grains with small pores. The behavior of dielectric constant with temperature of PGaZT-4 exhibited the suppression of the ferroelectric phase transition [i.e., disappearance of Curie temperature ( T c)]. The complex impedance spectroscopy (CIS) technique helped to investigate the impedance parameters of PGaZT-4 in MPB region in a wide range of temperature (250-500 °C) and frequency (1-1000 kHz) region. The impedance parameters of the material are found to be strongly dependent on frequency of AC electric field and temperature. The substitution of gallium at the Pb site of PZT generally enhances the dielectric constant and decreases loss tangent. The AC conductivity vs frequency ( f = ω2 π) in the region of dispersion follows the universal response of Jonscher's equation. Enhanced resistive characteristics were observed for Ga-substituted PZT in comparison to the pure PZT, which was well ensured from the studies of electrical parameters, such as impedance and AC conductivity.
Electromigration and the structure of metallic nanocontacts
NASA Astrophysics Data System (ADS)
Hoffmann-Vogel, R.
2017-09-01
This article reviews efforts to structurally characterize metallic nanocontacts. While the electronic characterization of such junctions is relatively straight forward, usually it is technically challenging to study the nanocontact's structure at small length scales. However, knowing that the structure is the basis for understanding the electronic properties of the nanocontact, for example, it is necessary to explain the electronic properties by calculations based on structural models. Besides using a gate electrode, controlling the structure is an important way of understanding how the electronic transport properties can be influenced. A key to make structural information directly accessible is to choose a fabrication method that is adapted to the structural characterization method. Special emphasis is given to transmission electron microscopy fabrication and to thermally assisted electromigration methods due to their potential for obtaining information on both electrodes of the forming nanocontact. Controlled electromigration aims at studying the contact at constant temperature of the contact during electromigration compared to studies at constant temperature of the environment as done previously. We review efforts to calculate electromigration forces. We describe how hot spots are formed during electromigration. We summarize implications for the structure obtained from studies of the ballistic transport regime, tunneling, and Coulomb-blockade. We review the structure of the nanocontacts known from direct structural characterization. Single-crystalline wires allow suppressing grain boundary electromigration. In thin films, the substrate plays an important role in influencing the defect and temperature distribution. Hot-spot formation and recrystallization are observed. We add information on the local temperature and current density and on alloys important for microelectronic interconnects.
O’Brien, Christopher J.; Medlin, Douglas L.; Foiles, Stephen M.
2016-03-30
Here, grain boundary-engineered materials are of immense interest for their corrosion resistance, fracture resistance and microstructural stability. This work contributes to a larger goal of understanding both the structure and thermodynamic properties of grain boundaries vicinal (within ±30°) to the Σ3(1 1 1) <1 1¯0> (coherent twin) boundary which is found in grain boundary-engineered materials. The misoriented boundaries vicinal to the twin show structural changes at elevated temperatures. In the case of nickel, this transition temperature is substantially below the melting point and at temperatures commonly reached during processing, making the existence of such boundaries very likely in applications. Thus,more » the thermodynamic stability of such features is thoroughly investigated in order to predict and fully understand the structure of boundaries vicinal to twins. Low misorientation angle grain boundaries (|θ| ≲ 16°) show distinct ±1/3(1 1 1) disconnections which accommodate misorientation in opposite senses. The two types of disconnection have differing low-temperature structures which show different temperature-dependent behaviours with one type undergoing a structural transition at approximately 600 K. At misorientation angles greater than approximately ±16°, the discrete disconnection nature is lost as the disconnections merge into one another. Free energy calculations demonstrate that these high-angle boundaries, which exhibit a transition from a planar to a faceted structure, are thermodynamically more stable in the faceted configuration.« less
Assessment of CFD Hypersonic Turbulent Heating Rates for Space Shuttle Orbiter
NASA Technical Reports Server (NTRS)
Wood, William A.; Oliver, A. Brandon
2011-01-01
Turbulent CFD codes are assessed for the prediction of convective heat transfer rates at turbulent, hypersonic conditions. Algebraic turbulence models are used within the DPLR and LAURA CFD codes. The benchmark heat transfer rates are derived from thermocouple measurements of the Space Shuttle orbiter Discovery windward tiles during the STS-119 and STS-128 entries. The thermocouples were located underneath the reaction-cured glass coating on the thermal protection tiles. Boundary layer transition flight experiments conducted during both of those entries promoted turbulent flow at unusually high Mach numbers, with the present analysis considering Mach 10{15. Similar prior comparisons of CFD predictions directly to the flight temperature measurements were unsatisfactory, showing diverging trends between prediction and measurement for Mach numbers greater than 11. In the prior work, surface temperatures and convective heat transfer rates had been assumed to be in radiative equilibrium. The present work employs a one-dimensional time-accurate conduction analysis to relate measured temperatures to surface heat transfer rates, removing heat soak lag from the flight data, in order to better assess the predictive accuracy of the numerical models. The turbulent CFD shows good agreement for turbulent fuselage flow up to Mach 13. But on the wing in the wake of the boundary layer trip, the inclusion of tile conduction effects does not explain the prior observed discrepancy in trends between simulation and experiment; the flight heat transfer measurements are roughly constant over Mach 11-15, versus an increasing trend with Mach number from the CFD.
NASA Astrophysics Data System (ADS)
Radchenko, V. P.; Saushkin, M. N.; Tsvetkov, V. V.
2016-05-01
This paper describes the effect of thermal exposure (high-temperature exposure) ( T = 675°C) on the residual creep stress relaxation in a surface hardened solid cylindrical sample made of ZhS6UVI alloy. The analysis is carried out with the use of experimental data for residual stresses after micro-shot peening and exposures to temperatures equal to T = 675°C during 50, 150, and 300 h. The paper presents the technique for solving the boundary-value creep problem for the hardened cylindrical sample with the initial stress-strain state under the condition of thermal exposure. The uniaxial experimental creep curves obtained under constant stresses of 500, 530, 570, and 600 MPa are used to construct the models describing the primary and secondary stages of creep. The calculated and experimental data for the longitudinal (axial) tensor components of residual stresses are compared, and their satisfactory agreement is determined.
NASA Technical Reports Server (NTRS)
Lin, K. M.; Moore, F. K.
1976-01-01
A new form of self-confined flow was investigated in which a recirculation zone forms away from any solid boundary. An inviscid flow analysis indicated that in a purely meridional axisymmetric flow a stationary, spherical, self-confined region should occur in the center of a streamlined divergent-convergent enlargement zone. The spherical confinement region would be at rest and at constant pressure. Experimental investigations were carried out in a specially built test apparatus to establish the desired confined flow. The streamlined divergent-convergent interior shape of the test section was fabricated according to the theoretical calculation for a particular streamline. The required inlet vorticity distribution was generated by producing a velocity profile with a shaped gauze screen in the straight pipe upstream of the test section. Fluid speed and turbulence intensity were measured with a constant-temperature hot-wire anemometer system. The measured results indicated a very orderly and stable flow field.
Effect of initial conditions on constant pressure mixing between two turbulent streams
NASA Astrophysics Data System (ADS)
Kangovi, S.
1983-02-01
It is pointed out that a study of the process of mixing between two dissimilar streams has varied applications in different fields. The applications include the design of an after burner in a high by-pass ratio aircraft engine and the disposal of effluents in a stream. The mixing process determines important quantities related to the energy transfer from main stream to the secondary stream, the temperature and velocity profiles, and the local kinematic and dissipative structure within the mixing region, and the growth of the mixing layer. Hill and Page (1968) have proposed the employment of an 'assumed epsilon' method in which the eddy viscosity model of Goertler (1942) is modified to account for the initial boundary layer. The present investigation is concerned with the application of the assumed epsilon technique to the study of the effect of initial conditions on the development of the turbulent mixing layer between two compressible, nonisoenergetic streams at constant pressure.
On the interaction between the external magnetic field and nanofluid inside a vertical square duct
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ali, Kashif; Ahmad, Shabbir; Ahmad, Shahzad, E-mail: shahzadahmadbzu@gmail.com
In this paper, we numerically study how the external magnetic field influences the flow and thermal characteristics of nanofluid inside a vertical square duct. The flow is considered to be laminar and hydrodynamically as well as thermally developed, whereas the thermal boundary condition of constant heat flux per unit axial length with constant peripheral temperature at any cross section, is assumed. The governing equations are solved using the spectral method and the finite difference method. Excellent comparison is noted in the numerical results given by the two methods but the spectral method is found to be superior in terms ofmore » both efficiency and accuracy. We have noted that the flow reversal due to high Raleigh number may be controlled by applying an external magnetic field of suitable strength. Moreover, the Nusselt number is found to be almost a linear function of the nanoparticle volume fraction parameter, for different values of the Raleigh number and the magnetic parameter.« less
NASA Astrophysics Data System (ADS)
Scuderi, M.; Marone, C.
2012-12-01
The seismic potential of faults, as well as mechanical strength and frictional instability are controlled by the evolution of the real contact area within the fault gouge. Fault gouge is characterized by granular and clay rich material, as the result of continuous wear produced by dynamic or quasi-static slip along the fault plane. In this context, water and thermally-activated physicochemical reactions play a fundamental role in controlling the evolution of friction, via asperity contact properties and processes including hydrolytic weakening, adsorption/desorption, and/or intergranular pressure-solution (IPS). To investigate the role of granular processes and temperature in faulting, we performed shear experiments in water-saturated simulated gouges. We sheared layers of synthetic fault gouge composed of soda-lime glass beads (dia. 105-149 mm) in a double direct shear configuration within a true-triaxial pressure vessel under controlled fluid pressure using DI water. Effective normal stress (σn) was kept constant during shear at 5 MPa, and layer thickness was constantly monitored via a DCDT attached to the ram. Shear stress (τ) was applied via a constant shear displacement rate at layers boundaries. We performed velocity step experiments, during which shearing velocity was increased stepwise from 0.3 to 300 μm/s, and slide-hold-slide tests, with hold times from 1 to 1000 s. During each experiment temperature was kept constant at values of 25, 50 and 75C. Our experiments were conducted in a stick-slip sliding regime. At the end of each run, simulated gouge layers were carefully collected and impregnated with epoxy resin for SEM analysis. For all experiments, stress drop (Δτ) decreases roughly linearly with the log of velocity. With increasing temperature Δτ increases and the velocity dependence varies. Frictional healing is characterized by β = 0.023 change in friction per decade at T = 25C, increasing to β = 0.037 at T = 50C. We find that maximum friction (μmax) increases with increasing temperature, as well as the amount of pre-seismic slip and the corresponding layers dilation. In agreement with previous studies, our data suggest that in water saturated simulated gouges, solid-fluid chemical reactions are enhanced by increasing temperature, which may induce plastic flow and/or intergranular pressure solution at grain junction, controlling μmax, stress drop magnitude and frictional healing. Future work will consider the connection between the observed mechanical behavior and the evolution of grain contact properties.
Temperature Dependence Of Elastic Constants Of Polymers
NASA Technical Reports Server (NTRS)
Simha, Robert; Papazoglou, Elisabeth
1989-01-01
Two papers extend theory of elastic constants of disordered solids to finite temperatures below glass-transition temperatures. First paper, entitled "Elastic Constants of Disordered Solids II: Temperature Dependence," applies to cryogenic temperatures. Second paper, entitled "Theory of Thermoelastic Properties for Polymer Glasses," develops unified treatment for static compressional and elongational properties at temperatures up to glass-transition temperatures.
Shower, Patrick T.; Roy, Shibayan; Hawkins, Charles Shane; ...
2017-06-08
Here in this study, the high temperature compressive response of cast aluminum alloys 319 and RR350 is compared in light of their microstructures. The 319 alloy is widely used in thermally critical automotive applications and provides a baseline for comparison with the RR350 alloy, whose microstructural stability at high homologous temperatures was recently reported. Cylindrical compression samples from each alloy were tested at four temperatures up to 300 °C at a constant true strain rate that was varied over four orders of magnitude. Although both alloys are strengthened by metastable precipitates (nominally Al 2Cu) in the as-aged condition, their mechanicalmore » response diverges at temperatures greater than 250 °C as the strengthening precipitates evolve in the 319 alloy and retain their as-aged morphology in the RR350 alloy. Deformation mechanisms of each alloy are examined using microstructural analysis and empirical activation energy calculations. The stability of the θ' phase in the RR350 alloy leads to effective precipitation hardening at homologous temperatures up to 0.6 and an extensive regime of grain boundary controlled deformation.« less
Study on the method of maintaining bathtub water temperature
NASA Astrophysics Data System (ADS)
Wang, Xiaoyan
2017-05-01
In order to make the water temperature constant and the spillage to its minimum, we use finite element method and grid transformation and have established an optimized model for people in the bathtub both in time and space, which is based on theories of heat convection and heat conduction and three-dimensional second-order equation. For the first question, we have worked out partial differential equations for three-dimensional heat convection. In the meantime, we also create an optimized temperature model in time and space by using initial conditions and boundary conditions. For the second question we have simulated the shape and volume of the tub and the human gestures in the tub based on the first question. As for the shape and volume of the tub, we draw conclusion that the tub whose surface area is little contains water with higher temperature. Thus, when we are designing bathtubs we can decrease the area so that we'll have less loss heat. For different gestures when people are bathing, we have found that gestures have no obvious influence on variations of water temperature. Finally, we did some simulating calculations, and did some analysis on precision and sensitivity
1974-07-01
AD/A-002 982 COMPARATIVE MEASUREMENTS CF TOTAL TEMPERATURE IN A SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIB- RIUM AND COMBINED...SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIORIUM AND COMBINED TEMPERATURE-PRESSURE PROBE H.L.P. Vowt R.E. L" 0H.U. M.i July 1974 NAVAL...1 ~~o iotaPRO eig ature In A Supersonic Turbulent Boundary ____________ Layer Using A Conical Equilibrium and 6. 111111ORWING OR. 0111001117,~t
NASA Astrophysics Data System (ADS)
Wang, Y. Q.; Kabra, S.; Zhang, S. Y.; Truman, C. E.; Smith, D. J.
2018-05-01
A long-term high-temperature testing stress rig has been designed and fabricated for performing in situ neutron diffraction tests at the ENGIN-X beamline, ISIS facility in the UK. It is capable of subjecting metals to high temperatures up to 800 °C and uniaxial loading under different boundary conditions including constant load, constant strain, and elastic follow-up, each with minimum of external control. Samples are held horizontally between grips and connected to a rigid rig frame, a soft aluminium bar, and a stepper motor with forces up to 20 kN. A new three zone split electrical resistance furnace which generates a stable and uniform heat atmosphere over 200 mm length was used to heat the samples. An 8 mm diameter port at 45° to the centre of the furnace was made in order to allow the neutron beam through the furnace to illuminate the sample. The entire instrument is mounted on the positioner at ENGIN-X and has the potential ability to operate continuously while being moved in and out of the neutron diffraction beam. The performance of the rig has been demonstrated by tracking the evolution of lattice strains in type 316H stainless steel under elastic follow-up control at 550 °C.
Wang, Y Q; Kabra, S; Zhang, S Y; Truman, C E; Smith, D J
2018-05-01
A long-term high-temperature testing stress rig has been designed and fabricated for performing in situ neutron diffraction tests at the ENGIN-X beamline, ISIS facility in the UK. It is capable of subjecting metals to high temperatures up to 800 °C and uniaxial loading under different boundary conditions including constant load, constant strain, and elastic follow-up, each with minimum of external control. Samples are held horizontally between grips and connected to a rigid rig frame, a soft aluminium bar, and a stepper motor with forces up to 20 kN. A new three zone split electrical resistance furnace which generates a stable and uniform heat atmosphere over 200 mm length was used to heat the samples. An 8 mm diameter port at 45° to the centre of the furnace was made in order to allow the neutron beam through the furnace to illuminate the sample. The entire instrument is mounted on the positioner at ENGIN-X and has the potential ability to operate continuously while being moved in and out of the neutron diffraction beam. The performance of the rig has been demonstrated by tracking the evolution of lattice strains in type 316H stainless steel under elastic follow-up control at 550 °C.
Effect of Reynolds number variation on aerodynamics of a hydrogen-fueled transport concept at Mach 6
NASA Technical Reports Server (NTRS)
Penland, Jim A.; Marcum, Don C., Jr.
1987-01-01
Two separate tests have been made on the same blended wing-body hydrogen-fueled transport model at a Mach number of about 6 and a range of Reynolds number (based on theoretical body length) of 1.577 to 55.36 X 10 to the 6th power. The results of these tests, made in a conventional hypersonic blowdown tunnel and a hypersonic shock tunnel, are presented through a range of angle of attack from -1 to 8 deg, with an extended study at a constant angle of attack of 3 deg. The model boundary layer flow appeared to be predominately turbulent except for the low Reynolds number shock tunnel tests. Model wall temperatures varied considerably; the blowdown tunnel varied from about 255 F to 340 F, whereas the shock tunnel had a constant 70 F model wall temperature. The experimental normal-force coefficients were essentially independent of Reynolds number. A current theoretical computer program was used to study the effect of Reynolds number. Theoretical predictions of normal-force coefficients were good, particularly at anticipated cruise angles of attack, that is 2 to 5 deg. Axial-force coefficients were generally underestimated for the turbulent skin friction conditions, and pitching-moment coefficients could not be predicted reliably.
Boundary-Work in Science Education: A Case Study of GM Food
ERIC Educational Resources Information Center
Lin, Yin-Ling
2016-01-01
The term "boundary-work" is used to refer to the constant effort to draw and re-draw the boundary of science; it has long been portrayed as constructed by the stakeholders of science to demarcate science from non-science to establish the authority of science. Twenty-nine semi-structured interviews were carried out with students from one…
Well-posedness of characteristic symmetric hyperbolic systems
NASA Astrophysics Data System (ADS)
Secchi, Paolo
1996-06-01
We consider the initial-boundary-value problem for quasi-linear symmetric hyperbolic systems with characteristic boundary of constant multiplicity. We show the well-posedness in Hadamard's sense (i.e., existence, uniqueness and continuous dependence of solutions on the data) of regular solutions in suitable functions spaces which take into account the loss of regularity in the normal direction to the characteristic boundary.
Thermal boundary resistance between sapphire and aluminum monocrystals at low temperature
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sahling, S.; Engert, J.; Gladun, A.
1981-12-01
The thermal boundary resistance at boundaries between monocrystalline sapphire and monocrystalline aluminum and between monocrystalline sapphire and polycrystalline aluminum has been measured in the temperature range from 0.1 to 6 K with aluminum in the superconducting and normal states. The ratio of the thermal boundary resistance of the aluminum monocrystals in the superconducting state to that in the normal state increases as the temperature is lowered, reaches a maximum at about 0.13 K, and decreases at still lower temperatures. At the maximum, the thermal boundary resistance in the superconducting state is two orders of magnitude larger than the resistance inmore » the normal state.« less
Fabrication of high-k dielectric Calcium Copper Titanate (CCTO) target by solid state route
NASA Astrophysics Data System (ADS)
Tripathy, N.; Das, K. C.; Ghosh, S. P.; Bose, G.; Kar, J. P.
2016-02-01
CaCu3Ti4O12 (CCTO) ceramic pellet of 10mm diameter has been synthesized by adopting solid state route. The structural and morphological characterization of the ceramics sample was carried out by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. XRD pattern revealed the CCTO phase formation, where as SEM micrograph shows the sample consisting of well defined grain and grain boundaries. The room temperature dielectric constant of the sample was found to be ∼ 5000 at 1kHz. After successful preparation of CCTO pellet, a 2 inch diameter CCTO sputtering target is also fabricated in order to deposit CCTO thin films for microelectronic applications.
High-temperature langatate elastic constants and experimental validation up to 900 degrees C.
Davulis, Peter M; da Cunha, Mauricio Pereira
2010-01-01
This paper reports on a set of langatate (LGT) elastic constants extracted from room temperature to 1100 degrees C using resonant ultrasound spectroscopy techniques and an accompanying assessment of these constants at high temperature. The evaluation of the constants employed SAW device measurements from room temperature to 900 degrees C along 6 different LGT wafer orientations. Langatate parallelepipeds and wafers were aligned, cut, ground, and polished, and acoustic wave devices were fabricated at the University of Maine facilities along specific orientations for elastic constant extraction and validation. SAW delay lines were fabricated on LGT wafers prepared at the University of Maine using 100-nm platinumrhodium- zirconia electrodes capable of withstanding temperatures up to 1000 degrees C. The numerical predictions based on the resonant ultrasound spectroscopy high-temperature constants were compared with SAW phase velocity, fractional frequency variation, and temperature coefficients of delay extracted from SAW delay line frequency response measurements. In particular, the difference between measured and predicted fractional frequency variation is less than 2% over the 25 degrees C to 900 degrees C temperature range and within the calculated and measured discrepancies. Multiple temperature-compensated orientations at high temperature were predicted and verified in this paper: 4 of the measured orientations had turnover temperatures (temperature coefficient of delay = 0) between 200 and 420 degrees C, and 2 had turnover temperatures below 100 degrees C. In summary, this work reports on extracted high-temperature elastic constants for LGT up to 1100 degrees C, confirmed the validity of those constants by high-temperature SAW device measurements up to 900 degrees C, and predicted and identified temperature-compensated LGT orientations at high temperature.
NASA Technical Reports Server (NTRS)
Maslen, Stephen H.
1959-01-01
An examination of the effects of compressibility, variable properties, and body forces on fully developed laminar flow has indicated several limitations on such streams. In the absence of a pressure gradient, but presence of a body force (e.g., gravity), an exact fully developed gas flow results. For a liquid this follows also for the case of a constant streamwise pressure gradient. These motions are exact in the sense of a Couette flow. In the liquid case two solutions (not a new result) can occur for the same boundary conditions. An approximate analytic solution was found which agrees closely with machine calculations.In the case of approximately exact flows, it turns out that for large temperature variations across the channel the effects of convection (due to, say, a wall temperature gradient) and frictional heating must be negligible. In such a case the energy and momentum equations are separated, and the solutions are readily obtained. If the temperature variations are small, then both convection effects and frictional heating can consistently be considered. This case becomes the constant-property incompressible case (or quasi-incompressible case for free-convection flows) considered by many authors. Finally there is a brief discussion of cases wherein streamwise variations of all quantities are allowed but only a such form that independent variables are separable. For the case where the streamwise velocity varies inversely as the square root distance along the channel a solution is given.
NASA Astrophysics Data System (ADS)
Zeh, Jeanne A.; Bonilla, Melvin M.; Su, Eleanor J.; Padua, Michael V.; Anderson, Rachel V.; Zeh, David W.
2014-01-01
Recent theory suggests that global warming may be catastrophic for tropical ectotherms. Although most studies addressing temperature effects in ectotherms utilize constant temperatures, Jensen's inequality and thermal stress considerations predict that this approach will underestimate warming effects on species experiencing daily temperature fluctuations in nature. Here, we tested this prediction in a neotropical pseudoscorpion. Nymphs were reared in control and high-temperature treatments under a constant daily temperature regime, and results compared to a companion fluctuating-temperature study. At constant temperature, pseudoscorpions outperformed their fluctuating-temperature counterparts. Individuals were larger, developed faster, and males produced more sperm, and females more embryos. The greatest impact of temperature regime involved short-term, adult exposure, with constant temperature mitigating high-temperature effects on reproductive traits. Our findings demonstrate the importance of realistic temperature regimes in climate warming studies, and suggest that exploitation of microhabitats that dampen temperature oscillations may be critical in avoiding extinction as tropical climates warm.
Determination of time of death in forensic science via a 3-D whole body heat transfer model.
Bartgis, Catherine; LeBrun, Alexander M; Ma, Ronghui; Zhu, Liang
2016-12-01
This study is focused on developing a whole body heat transfer model to accurately simulate temperature decay in a body postmortem. The initial steady state temperature field is simulated first and the calculated weighted average body temperature is used to determine the overall heat transfer coefficient at the skin surface, based on thermal equilibrium before death. The transient temperature field postmortem is then simulated using the same boundary condition and the temperature decay curves at several body locations are generated for a time frame of 24h. For practical purposes, curve fitting techniques are used to replace the simulations with a proposed exponential formula with an initial time delay. It is shown that the obtained temperature field in the human body agrees very well with that in the literature. The proposed exponential formula provides an excellent fit with an R 2 value larger than 0.998. For the brain and internal organ sites, the initial time delay varies from 1.6 to 2.9h, when the temperature at the measuring site does not change significantly from its original value. The curve-fitted time constant provides the measurement window after death to be between 8h and 31h if the brain site is used, while it increases 60-95% at the internal organ site. The time constant is larger when the body is exposed to colder air, since a person usually wears more clothing when it is cold outside to keep the body warm and comfortable. We conclude that a one-size-fits-all approach would lead to incorrect estimation of time of death and it is crucial to generate a database of cooling curves taking into consideration all the important factors such as body size and shape, environmental conditions, etc., therefore, leading to accurate determination of time of death. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Raut, Subhajit; Babu, P. D.; Sharma, R. K.; Pattanayak, Ranjit; Panigrahi, Simanchalo
2018-05-01
We investigated the anomalous behaviour in the dielectric properties, occurring nearly at room temperature and at elevated temperatures (near the Neel temperature TN) of the polycrystalline samples of YFeO3 (YFO) ceramics. On the prepared YFO ceramics, the magnetic measurements showed the Neel temperature of YFO to be 650 K, below which the compound exhibited the weak ferromagnetic behaviour. X-ray photoelectron spectroscopy (XPS) shows the presence of Fe ions (Fe2+ and Fe3+ states) and also revealed the formation of the oxygen vacancies. The frequency dependence of the complex dielectric constant within the frequency domain of 100 Hz-1 MHz shows the presence of grain dominated dielectric relaxation over the thermal window of 300-373 K. The activation energy Eact.ɛ=0.611 eV extracted from the imaginary permittivity spectrum indicates the involvement of oxygen vacancies in the relaxation process. Above 493 K, the ac conductivity, complex impedance, and modulus studies revealed appreciable conduction and relaxation processes occurring in YFO ceramics with respective activation energies Eac t . σ=1.362 eV and Eac t . Z=1.345 eV , which suggests that the oxygen vacancies are also involved for the anomalous behaviour of the dielectric constant at elevated temperatures. The temperature dependent Raman spectroscopic measurements within the thermal window of 298-698 K showed anomalous variations of the line widths and frequencies of several Raman active modes above 473 K up to the vicinity of TN pointing towards the presence of admixtures of the electron-phonon and spin-phonon coupling in the system. A further study on the thermal variation of the B2g(4) mode frequency with [M(T)/MS]2 shows the occurrence of strong spin-phonon (s-p) coupling, while the line shape shows the presence of the Fano asymmetry, suggesting spin dependent electron-phonon (e-p) coupling in the system below TN.
On mechanical waves and Doppler shifts from moving boundaries
Christov, Ivan C.; Christov, Christo I.
2017-02-01
We investigate the propagation of infinitesimal harmonic mechanical waves emitted from a boundary with variable velocity and arriving at a stationary observer. In the classical Doppler effect, X s(t)=vt is the location of the source with constant velocity v. In the present work, however, we consider a source co-located with a moving boundary x=X s(t), where X s(t) can have an arbitrary functional form. For ‘slowly moving’ boundaries (i.e., ones for which the timescale set by the mechanical motion is large in comparison to the inverse of the frequency of the emitted wave), we present a multiple-scale asymptotic analysis of the moving boundary problem for the linear wave equation. Here, we obtain a closed-form leading-order (with respect to the latter small parameter) solution and show that the variable velocity of the boundary results not only in frequency modulation but also in amplitude modulation of the received signal. Consequently, our results extend the applicability of two basic tenets of the theory of a moving source on a stationary domain, specifically that (i)more » $$.\\atop{x}_s$$ for non-uniform boundary motion can be inserted in place of the constant velocity v in the classical Doppler formula and (ii) that the non-uniform boundary motion introduces variability in the amplitude of the wave. The specific examples of decelerating and oscillatory boundary motion are worked out and illustrated.« less
An implicit-iterative solution of the heat conduction equation with a radiation boundary condition
NASA Technical Reports Server (NTRS)
Williams, S. D.; Curry, D. M.
1977-01-01
For the problem of predicting one-dimensional heat transfer between conducting and radiating mediums by an implicit finite difference method, four different formulations were used to approximate the surface radiation boundary condition while retaining an implicit formulation for the interior temperature nodes. These formulations are an explicit boundary condition, a linearized boundary condition, an iterative boundary condition, and a semi-iterative boundary method. The results of these methods in predicting surface temperature on the space shuttle orbiter thermal protection system model under a variety of heating rates were compared. The iterative technique caused the surface temperature to be bounded at each step. While the linearized and explicit methods were generally more efficient, the iterative and semi-iterative techniques provided a realistic surface temperature response without requiring step size control techniques.
NASA Astrophysics Data System (ADS)
Coogan, L. A.; Dosso, S. E.; Higgins, J. A.
2014-12-01
There are sharp rises in the Sr- and Li-isotopic composition of seawater at the Eocene-Oligocene boundary that are generally thought to be associated with Himalayan uplift and associated climatic changes and continental weathering variability. In modeling such data the norm is to hold the chemical fluxes associated with off-axis hydrothermal circulation through the oceanic crust constant while varying the river fluxes (and/or isotopic ratios). There is, however, no a priori reason to assume the chemical fluxes (or isotopic compositions) associated with off-axis hydrothermal systems should stay constant. Instead, changing environmental conditions (e.g. seawater composition and bottom water temperature) will lead to changes in these fluxes. An alternative model to explain the sharp rise in the Sr- and Li-isotopic composition of seawater at the Eocene-Oligocene boundary is cooling of the deep ocean. Decreased reaction rates in the oceanic crust, due to decreasing temperature, can be shown to lead to a decrease in the flux of unradiogenic Sr into the ocean. The magnitude matches, within uncertainty, that required to explain the increase in seawater Sr-isotopic composition [Coogan and Dosso, in review]. The story for Li is more uncertain. Two factors may lead to smaller effective fractionation factors between seawater and the (large) Li sink in the oceanic crust when bottom water is warmer: (i) higher temperature will decrease the isotopic fractionation factor; (ii) the more extensive fluid-rock reaction in the ocean crust when bottom water is warmer will make Li uptake by the oceanic crust more efficient. All other things being equal this will lead to a lower Li content of seawater. In turn, a lower Li content in seawater will mean that for a given Li-uptake rate by the crust the effective fractionation factor is smaller, due to Rayleigh distillation of Li-isotopes during fluid-rock reaction in the oceanic crust. In combination these factors predict a significant (many per mil), but poorly constrained, increase in the Li-isotopic composition of the ocean due to cooling bottom water. Models of many geochemical species, including carbon [Coogan and Gillis, 2013], should include environmentally dependent fluxes from off-axis hydrothermal systems.
NASA Technical Reports Server (NTRS)
Treybig, J. H.
1975-01-01
Thermal and equilibrium glide boundaries were used to analyze and/or design shuttle orbiter entry trajectories. Plots are presented of orbiter thermal and equilibrium glide boundaries in the drag/mass-relative velocity dynamic pressure-relative velocity, and altitude-relative velocity planes for an orbiter having a 32,000 pound payload and a 67.5% center of gravity location. These boundaries were defined for control points 1 through 4 of the shuttle orbiter for 40 deg-30 deg and 38 deg-28 deg ramped angle of attack entry profiles and 40 deg, 38 deg, 35 deg, 30 deg, 28 deg, and 25 deg constant angle of attack entry profiles each at 20 deg, 15 deg, and 10 deg constant body flap settings.
Vortex Formation During Unsteady Boundary-Layer Separation
NASA Astrophysics Data System (ADS)
Das, Debopam; Arakeri, Jaywant H.
1998-11-01
Unsteady laminar boundary-layer separation is invariably accompanied by the formation of vortices. The aim of the present work is to study the vortex formation mechanism(s). An adverse pressure gradient causing a separation can be decomposed into a spatial component ( spatial variation of the velocity external to the boundary layer ) and a temporal component ( temporal variation of the external velocity ). Experiments were conducted in a piston driven 2-D water channel, where the spatial component could be be contolled by geometry and the temporal component by the piston motion. We present results for three divergent channel geometries. The piston motion consists of three phases: constant acceleration from start, contant velocity, and constant deceleration to stop. Depending on the geometry and piston motion we observe different types of unsteady separation and vortex formation.
Figure-ground segregation by motion contrast and by luminance contrast.
Regan, D; Beverley, K I
1984-05-01
Some naturally camouflaged objects are invisible unless they move; their boundaries are then defined by motion contrast between object and background. We compared the visual detection of such camouflaged objects with the detection of objects whose boundaries were defined by luminance contrast. The summation field area is 0.16 deg2 , and the summation time constant is 750 msec for parafoveally viewed objects whose boundaries are defined by motion contrast; these values are, respectively, about 5 and 12 times larger than the corresponding values for objects defined by luminance contrast. The log detection threshold is proportional to the eccentricity for a camouflaged object of constant area. The effect of eccentricity on threshold is less for large objects than for small objects. The log summation field diameter for detecting camouflaged objects is roughly proportional to the eccentricity, increasing to about 20 deg at 32-deg eccentricity. In contrast to the 100:1 increase of summation area for detecting camouflaged objects, the temporal summation time constant changes by only 40% between eccentricities of 0 and 16 deg.
NASA Astrophysics Data System (ADS)
Kaganovich, Igor; Krstic, Predrag; Startsev, Edward
2014-10-01
It has been known that defects in tungsten, in particular at the grain boundaries, are preferable sites for deuterium and helium retention. For the case of the nano-grained boundaries, we study by classical molecular dynamics the cumulative retention of deuterium and helium at impact energies below 100 eV as functions of tungsten temperature at models of the dislocation boundaries. We obtain a strong preference of the retention of the impact particles at the boundaries at high temperature of 1000 K. Support of PPPL LDRD grant acknowledged.
Invited paper: Dielectric properties of CaCu3Ti4O12 polycrystalline ceramics
NASA Astrophysics Data System (ADS)
Lee, Sung Yun; Hong, Youn Woo; Yoo, Sang Im
2011-12-01
We investigated the relationship between the microstructures and dielectric properties of various CaCu3Ti4O12 (CCTO) polycrystalline ceramics sintered in air. An abrupt increase in the dielectric constant ( ɛ r) from ˜3,000 to ˜170,000 at 1 kHz occurred with increasing the sintering temperature from 980 to 1000°C for 12 h, respectively, which was accompanied by a very large increase in the average grain size from 5 to 300 µm, respectively, due to an abnormal grain growth. With further increasing the sintering temperature, the ɛ r value at 1 kHz was slightly decreased to ˜150,000 at 1020°C with no variation in the average grain size, significantly decreased to ˜77,000 at 1040°C with a large decrease in the average grain size (˜150 µm), and then maintained the values of ˜76,000 and ˜69,000 at 1060 and 1080°C, respectively, without noticeable variation in the average grain size. While no abnormal grain growth occurred in the CCTO samples sintered at 980°C for the holding time to 24 h and thus their ɛ r values showed relatively lower ɛ r values (< ˜4,000 at 1 kHz), the abnormal grain growth occurred in the samples after a certain holding time at a given sintering temperature of higher than 1000°C and thus their ɛ r values abruptly increased. Analyses by the complex impedance ( Z*) and modulus ( M*) spectroscopy revealed that the ɛ r values of the CCTO samples were dominantly affected by the electrical properties of grain boundary so that high ɛ r values over 10,000 at 1 kHz were attributable to the high capacitance ( C) of grain boundary, which is in good agreement with grain boundary internal barrier layer capacitor (IBLC) model.
NASA Astrophysics Data System (ADS)
Fedorovich, Evgeni; Kaiser, Rolf; Rau, Matthias; Plate, Erich
1996-05-01
Experiments on simulating the atmospheric convective boundary layer (CBL), capped by a temperature inversion and affected by surface shear, were carried out in the thermally stratified wind tunnel of the Institute of Hydrology and Water Resources, University of Karlsruhe. The tunnel is of the closed-circuit type, with a test section 10 m long, 1.5 m wide, and 1.5 m high. The return section of the tunnel is subdivided into 10 layers, each driven by its own fan and heating system. By this means, velocity and temperature profiles can be preshaped at the inlet of the test section, which allows for the reproduction of developed CBL over comparatively short fetches. The bottom heating is controlled to produce the constant heat flux through the floor of the test section. The flow velocity components in the tunnel are measured with a laser Doppler system; for temperature measurements, the resistance-wire technique is employed.A quasi-stationary, horizontally evolving CBL was reproduced in the tunnel, with convective Richardson numbers RiT and RiN up to 10 and 20, respectively, and the shear/buoyancy dynamic ratio u(/w( in the range of 0.2-0.5. Within the employed modeling approach, means and other statistics of the flow were calculated by temporal averaging. Deardorff mixed-layer scaling was used as a framework for processing and interpreting the experimental results. The comparison of the wind tunnel data with results of atmospheric, water tank, and numerical studies of the CBL shows the crucial dependence of the turbulence statistics in the upper part of the layer on the parameters of entrainment, as well as the modification of the CBL turbulence regime by the surface shear.
ON AERODYNAMIC AND BOUNDARY LAYER RESISTANCES WITHIN DRY DEPOSITION MODELS
There have been many empirical parameterizations for the aerodynamic and boundary layer resistances proposed in the literature, e.g. those of the Meyers Multi-Layer Deposition Model (MLM) used with the nation-wide dry deposition network. Many include arbitrary constants or par...
Comparison of Turbulent Thermal Diffusivity and Scalar Variance Models
NASA Technical Reports Server (NTRS)
Yoder, Dennis A.
2016-01-01
In this study, several variable turbulent Prandtl number formulations are examined for boundary layers, pipe flow, and axisymmetric jets. The model formulations include simple algebraic relations between the thermal diffusivity and turbulent viscosity as well as more complex models that solve transport equations for the thermal variance and its dissipation rate. Results are compared with available data for wall heat transfer and profile measurements of mean temperature, the root-mean-square (RMS) fluctuating temperature, turbulent heat flux and turbulent Prandtl number. For wall-bounded problems, the algebraic models are found to best predict the rise in turbulent Prandtl number near the wall as well as the log-layer temperature profile, while the thermal variance models provide a good representation of the RMS temperature fluctuations. In jet flows, the algebraic models provide no benefit over a constant turbulent Prandtl number approach. Application of the thermal variance models finds that some significantly overpredict the temperature variance in the plume and most underpredict the thermal growth rate of the jet. The models yield very similar fluctuating temperature intensities in jets from straight pipes and smooth contraction nozzles, in contrast to data that indicate the latter should have noticeably higher values. For the particular low subsonic heated jet cases examined, changes in the turbulent Prandtl number had no effect on the centerline velocity decay.
NASA Astrophysics Data System (ADS)
Singh Yadav, Raghvendra; Kuřitka, Ivo; Vilcakova, Jarmila; Havlica, Jaromir; Masilko, Jiri; Kalina, Lukas; Tkacz, Jakub; Švec, Jiří; Enev, Vojtěch; Hajdúchová, Miroslava
2017-12-01
In this work CoFe2O4 spinel ferrite nanoparticles were synthesized by honey mediated sol-gel combustion method and further annealed at higher temperature 500 °C, 700 °C, 900 °C and 1100 °C. The synthesized spinel ferrite nanoparticles is investigated by x-ray diffraction, Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis/differential scanning calorimetry (TGA/DSC), field emission scanning electron microscopy, x-ray photoelectron spectroscopy and vibrating sample magnetometer. The x-ray diffraction study reveals face-centered cubic spinel cobalt ferrite crystal phase formation. The crystallite size and lattice parameter are increased with annealing temperature. Raman and Fourier transform infrared spectra also confirm spinel ferrite crystal structure of synthesized nanoparticles. The existence of cation at octahedral and tetrahedral site in cobalt ferrite nanoparticles is confirmed by x-ray photoelectron spectroscopy. Magnetic measurement shows increased saturation magnetization 74.4 emu g-1 at higher annealing temperature 1100 °C, high coercivity 1347.3 Oe at lower annealing temperature 500 °C, and high remanent magnetization 32.3 emu g-1 at 900 °C annealing temperature. The magnetic properties of synthesized ferrite nanoparticles can be tuned by adjusting sizes through annealing temperature. Furthermore, the dielectric constant and ac conductivity shows variation with frequency (1-107 Hz), grain size and cation redistribution. The modulus spectroscopy study reveals the role of bulk grain and grain boundary towards the resistance and capacitance. The cole-cole plots in modulus formalism also well support the electrical response of nanoparticles originated from both grain and grain boundaries. The dielectric, electrical, magnetic, impedance and modulus spectroscopic characteristics of synthesized CoFe2O4 spinel ferrite nanoparticles demonstrate the applicability of these nanoparticles for magnetic recording, memory devices and for microwave applications.
An improved exceedance theory for combined random stresses
NASA Technical Reports Server (NTRS)
Lester, H. C.
1974-01-01
An extension is presented of Rice's classic solution for the exceedances of a constant level by a single random process to its counterpart for an n-dimensional vector process. An interaction boundary, analogous to the constant level considered by Rice for the one-dimensional case, is assumed in the form of a hypersurface. The theory for the numbers of boundary exceedances is developed by using a joint statistical approach which fully accounts for all cross-correlation effects. An exact expression is derived for the n-dimensional exceedance density function, which is valid for an arbitrary interaction boundary. For application to biaxial states of combined random stress, the general theory is reduced to the two-dimensional case. An elliptical stress interaction boundary is assumed and the exact expression for the density function is presented. The equations are expressed in a format which facilitates calculating the exceedances by numerically evaluating a line integral. The behavior of the density function for the two-dimensional case is briefly discussed.
Sturtevant, Blake T; Davulis, Peter M; da Cunha, Mauricio Pereira
2009-04-01
This work reports on the determination of langatate elastic and piezoelectric constants and their associated temperature coefficients employing 2 independent methods, the pulse echo overlap (PEO) and a combined resonance technique (CRT) to measure bulk acoustic wave (BAW) phase velocities. Details on the measurement techniques are provided and discussed, including the analysis of the couplant material in the PEO technique used to couple signal to the sample, which showed to be an order of magnitude more relevant than the experimental errors involved in the data extraction. At room temperature, elastic and piezoelectric constants were extracted by the PEO and the CRT methods and showed results consistent to within a few percent for the elastic constants. Both raw acquired data and optimized constants, based on minimization routines applied to all the modes involved in the measurements, are provided and discussed. Comparison between the elastic constants and their temperature behavior with the literature reveals the recent efforts toward the consistent growth and characterization of LGT, in spite of significant variations (between 1 and 30%) among the constants extracted by different groups at room temperature. The density, dielectric permittivity constants, and respective temperature coefficients used in this work have also been independently determined based on samples from the same crystal boule. The temperature behavior of the BAW modes was extracted using the CRT technique, which has the advantage of not relying on temperature dependent acoustic couplants. Finally, the extracted temperature coefficients for the elastic and piezoelectric constants between room temperature and 120 degrees C are reported and discussed in this work.
Ullah, Mohammad Shaef; Lim, Un Taek
2015-06-01
Frankliniella occidentalis (Pergande) and Frankliniella intonsa (Trybom) are sympatric pests of many greenhouse and field crops in Korea. We compared the influence of constant (27.3°C) and fluctuating temperatures (23.8-31.5°C, with an average of 27.3°C) on the life table characteristics of F. occidentalis and F. intonsa held at a photoperiod of 16:8 (L:D) h and 45±5% relative humidity. The development times of both F. occidentalis and F. intonsa were significantly affected by temperature fluctuation, species, and sex. The development time from egg to adult of F. intonsa was shorter than that for F. occidentalis at both constant and fluctuating temperatures. Survival of immature life stages was higher under fluctuating than constant temperature for both thrips species. The total and daily production of first instars was higher in F. intonsa (90.4 and 4.2 at constant temperature, and 95.7 and 3.9 at fluctuating temperatures) than that of F. occidentalis (58.7 and 3.3 at constant temperature, and 60.5 and 3.1 at fluctuating temperatures) under both constant and fluctuating temperatures. The percentage of female offspring was greater in F. intonsa (72.1-75.7%) than in F. occidentalis (57.4-58.7%) under both temperature regimes. The intrinsic rate of natural increase (rm) was higher at constant temperature than at fluctuating temperature for both thrips species. F. intonsa had a higher rm value (0.2146 and 0.2004) than did F. occidentalis (0.1808 and 0.1733), under both constant and fluctuating temperatures, respectively. The biological response of F. occidentalis and F. intonsa to constant and fluctuating temperature was found to be interspecifically different, and F. intonsa may have higher pest potential than F. occidentalis based on the life table parameters we are reporting first here. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
Thermal regulation of methane hydrate dissociation: Implications for gas production models
Circone, S.; Kirby, S.H.; Stern, L.A.
2005-01-01
Thermal self-regulation of methane hydrate dissociation at pressure, temperature conditions along phase boundaries, illustrated by experiment in this report, is a significant effect with potential relevance to gas production from gas hydrate. In surroundings maintained at temperatures above the ice melting point, the temperature in the vicinity of dissociating methane hydrate will decrease because heat flow is insufficient to balance the heat absorbed by the endothermic reaction: CH4??nH2O (s) = CH4 (g) + nH2O (l). Temperature decreases until either all of the hydrate dissociates or a phase boundary is reached. At pressures above the quadruple point, the temperature-limiting phase boundary is that of the dissociation reaction itself. At lower pressures, the minimum temperature is limited by the H2O solid/liquid boundary. This change in the temperature-limiting phase boundary constrains the pressure, temperature conditions of the quadruple point for the CH4-H2O system to 2.55 ?? 0.02 MPa and 272.85 ?? 0.03 K. At pressures below the quadruple point, hydrate dissociation proceeds as the liquid H2O produced by dissociation freezes. In the laboratory experiments, dissociation is not impeded by the formation of ice byproduct per se; instead rates are proportional to the heat flow from the surroundings. This is in contrast to the extremely slow dissociation rates observed when surrounding temperatures are below the H2O solid/liquid boundary, where no liquid water is present. This "anomalous" or "self" preservation behavior, most pronounced near 268 K, cannot be accessed when surrounding temperatures are above the H2O solid/liquid boundary. ?? 2005 American Chemical Society.
Applications of the Remotely Piloted Aircraft (RPA) 'MASC' in Atmospheric Boundary Layer Research
NASA Astrophysics Data System (ADS)
Wildmann, Norman; Platis, Andreas; Tupman, David-James; Bange, Jens
2015-04-01
The remotely piloted aircraft (RPA) MASC (Multipurpose Airborne Sensor Carrier) was developed at the University of Tübingen in cooperation with the University of Stuttgart, University of Applied Sciences Ostwestfalen-Lippe and 'ROKE-Modelle'. Its purpose is the investigation of thermodynamic processes in the atmospheric boundary layer (ABL), including observations of temperature, humidity and wind profiles, as well as the measurement of turbulent heat, moisture and momentum fluxes. The aircraft is electrically powered, has a maximum wingspan of 3.40~m and a total weight of 5-8~kg, depending on the battery- and payload. The standard meteorological payload consists of two temperature sensors, a humidity sensor, a flow probe, an inertial measurement unit and a GNSS. The sensors were optimized for the resolution of small-scale turbulence down to length scales in the sub-meter range. In normal operation, the aircraft is automatically controlled by the ROCS (Research Onboard Computer System) autopilot to be able to fly predefined paths at constant altitude and airspeed. Only take-off and landing are carried out by a human RC pilot. Since 2012, the system is operational and has since then been deployed in more than ten measurement campaigns, with more than 100 measurement flights. The fields of research that were tackled in these campaigns include sensor validation, fundamental boundary-layer research and wind-energy research. In 2014, for the first time, two MASC have been operated at the same time within a distance of a few kilometres, in order to investigate the wind field over an escarpment in the Swabian Alb. Furthermore, MASC was first deployed off-shore in October 2014, starting from the German island Heligoland in the North Sea, for the purpose of characterization of the marine boundary layer for offshore wind parks. Detailed descriptions of the experimental setup and first preliminary results will be presented.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ciraolo, Giulio, E-mail: g.ciraolo@math.unipa.it; Gargano, Francesco, E-mail: gargano@math.unipa.it; Sciacca, Vincenzo, E-mail: sciacca@math.unipa.it
2013-08-01
We study a new approach to the problem of transparent boundary conditions for the Helmholtz equation in unbounded domains. Our approach is based on the minimization of an integral functional arising from a volume integral formulation of the radiation condition. The index of refraction does not need to be constant at infinity and may have some angular dependency as well as perturbations. We prove analytical results on the convergence of the approximate solution. Numerical examples for different shapes of the artificial boundary and for non-constant indexes of refraction will be presented.
Instanton rate constant calculations close to and above the crossover temperature.
McConnell, Sean; Kästner, Johannes
2017-11-15
Canonical instanton theory is known to overestimate the rate constant close to a system-dependent crossover temperature and is inapplicable above that temperature. We compare the accuracy of the reaction rate constants calculated using recent semi-classical rate expressions to those from canonical instanton theory. We show that rate constants calculated purely from solving the stability matrix for the action in degrees of freedom orthogonal to the instanton path is not applicable at arbitrarily low temperatures and use two methods to overcome this. Furthermore, as a by-product of the developed methods, we derive a simple correction to canonical instanton theory that can alleviate this known overestimation of rate constants close to the crossover temperature. The combined methods accurately reproduce the rate constants of the canonical theory along the whole temperature range without the spurious overestimation near the crossover temperature. We calculate and compare rate constants on three different reactions: H in the Müller-Brown potential, methylhydroxycarbene → acetaldehyde and H 2 + OH → H + H 2 O. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.
Radiation forcing by the atmospheric aerosols in the nocturnal boundary layer
NASA Astrophysics Data System (ADS)
Singh, D. K.; Ponnulakshami, V. K.; Mukund, V.; Subramanian, G.; Sreenivas, K. R.
2013-05-01
We have conducted experimental and theoretical studies on the radiation forcing due to suspended aerosols in the nocturnal boundary layer. We present radiative, conductive and convective equilibrium profile for different bottom boundaries where calculated Rayleigh number is higher than the critical Rayleigh number in laboratory conditions. The temperature profile can be fitted using an exponential distribution of aerosols concentration field. We also present the vertical temperature profiles in a nocturnal boundary in the presence of fog in the field. Our results show that during the presence of fog in the atmosphere, the ground temperature is greater than the dew-point temperature. The temperature profiles before and after the formation of fog are also observed to be different.
A Statistical Approach for the Concurrent Coupling of Molecular Dynamics and Finite Element Methods
NASA Technical Reports Server (NTRS)
Saether, E.; Yamakov, V.; Glaessgen, E.
2007-01-01
Molecular dynamics (MD) methods are opening new opportunities for simulating the fundamental processes of material behavior at the atomistic level. However, increasing the size of the MD domain quickly presents intractable computational demands. A robust approach to surmount this computational limitation has been to unite continuum modeling procedures such as the finite element method (FEM) with MD analyses thereby reducing the region of atomic scale refinement. The challenging problem is to seamlessly connect the two inherently different simulation techniques at their interface. In the present work, a new approach to MD-FEM coupling is developed based on a restatement of the typical boundary value problem used to define a coupled domain. The method uses statistical averaging of the atomistic MD domain to provide displacement interface boundary conditions to the surrounding continuum FEM region, which, in return, generates interface reaction forces applied as piecewise constant traction boundary conditions to the MD domain. The two systems are computationally disconnected and communicate only through a continuous update of their boundary conditions. With the use of statistical averages of the atomistic quantities to couple the two computational schemes, the developed approach is referred to as an embedded statistical coupling method (ESCM) as opposed to a direct coupling method where interface atoms and FEM nodes are individually related. The methodology is inherently applicable to three-dimensional domains, avoids discretization of the continuum model down to atomic scales, and permits arbitrary temperatures to be applied.
Borner, Arnaud; Wang, Pengxiang; Levin, Deborah A
2014-12-01
Molecular dynamics (MD) simulations are coupled to solutions of Poisson's equation to study the effects of the electrical boundary conditions on the emission modes of an electrospray thruster fed with an ionic liquid. A comparison of a new tip boundary condition with an analytical model based on a semihyperboloidal shape offers good agreement, although the analytical model overestimates the maximum value of the tangential electric field since it does not take into account the space charge that reduces the field at the liquid surface. It is found that a constant electric field model gives similar agreement to the more rigorous and computationally expensive tip boundary condition at lower flow rates. However, at higher mass flow rates the constant electric field produces extruded particles with higher Coulomb energy per ion, consistent with droplet formation. Furthermore, the MD simulations show that ion emission sites differ based on the boundary condition and snapshots offer an explanation as to why some boundary condition models will predict emission in a purely ionic mode, whereas others suggest a mixed ion-droplet regime. Finally, specific impulses and thrusts are compared for the different models and are found to vary up to 30% due to differences in the average charge to mass ratio.
NASA Astrophysics Data System (ADS)
Borner, Arnaud; Wang, Pengxiang; Levin, Deborah A.
2014-12-01
Molecular dynamics (MD) simulations are coupled to solutions of Poisson's equation to study the effects of the electrical boundary conditions on the emission modes of an electrospray thruster fed with an ionic liquid. A comparison of a new tip boundary condition with an analytical model based on a semihyperboloidal shape offers good agreement, although the analytical model overestimates the maximum value of the tangential electric field since it does not take into account the space charge that reduces the field at the liquid surface. It is found that a constant electric field model gives similar agreement to the more rigorous and computationally expensive tip boundary condition at lower flow rates. However, at higher mass flow rates the constant electric field produces extruded particles with higher Coulomb energy per ion, consistent with droplet formation. Furthermore, the MD simulations show that ion emission sites differ based on the boundary condition and snapshots offer an explanation as to why some boundary condition models will predict emission in a purely ionic mode, whereas others suggest a mixed ion-droplet regime. Finally, specific impulses and thrusts are compared for the different models and are found to vary up to 30% due to differences in the average charge to mass ratio.
Chen, Z-Z; Xu, L-X; Li, L-L; Wu, H-B; Xu, Y-Y
2018-06-21
The oriental fruit moth, Grapholita molesta, is an important pest in many commercial orchards including apple, pear and peach orchards, and responsible for substantial economic losses every year. To help in attaining a comprehensive and thorough understanding of the ecological tolerances of G. molesta, we collected life history data of individuals reared on apples under different constant temperature regimes and compared the data with moths reared under a variable outdoor temperature environment. Because G. molesta individuals reared at a constant 25°C had the heaviest pupal weight, the highest survival rate from egg to adult, highest finite rate of increase, and greatest fecundity, 25°C was considered as the optimum developmental temperature. The G. molesta population reared at a constant 31°C had the shortest development time, lowest survival rate and fecundity, resulting in population parameters of r < 0, λ < 1, lead to negative population growth. The population parameters r and λ reared under fluctuating temperature were higher than that reared under constant temperatures, the mean generation time (T) was shorter than it was in all of the constant temperatures treatments. This would imply that the outdoor G. molesta population would have a higher population growth potential and faster growth rate than indoor populations raised at constant temperatures. G. molesta moths reared under fluctuating temperature also had a higher fertility than moths reared under constant temperatures (except at 25°C). Our findings indicated that the population raised under outdoor fluctuating temperature conditions had strong environment adaptiveness.
Pore and grain boundary migration under a temperature gradient: A phase-field model study
Biner, S. B.
2016-03-16
In this study, the collective migration behavior of pores and grain boundaries under a temperature gradient is studied for simple single crystal, bi-crystal and polycrystal configurations with a phase-field model formulism. For simulation of the microstructure of solids, composed of pores and grain boundaries, the results indicate that not only the volume fraction of pores, but also its spatial partitioning between the grain boundary junctions and the grain boundary segments appears to be important. In addition to various physical properties, the evolution kinetics, under given temperature gradients, will be strongly influenced with the initial morphology of a poly-crystalline microstructure.
Relational symplectic groupoid quantization for constant poisson structures
NASA Astrophysics Data System (ADS)
Cattaneo, Alberto S.; Moshayedi, Nima; Wernli, Konstantin
2017-09-01
As a detailed application of the BV-BFV formalism for the quantization of field theories on manifolds with boundary, this note describes a quantization of the relational symplectic groupoid for a constant Poisson structure. The presence of mixed boundary conditions and the globalization of results are also addressed. In particular, the paper includes an extension to space-times with boundary of some formal geometry considerations in the BV-BFV formalism, and specifically introduces into the BV-BFV framework a "differential" version of the classical and quantum master equations. The quantization constructed in this paper induces Kontsevich's deformation quantization on the underlying Poisson manifold, i.e., the Moyal product, which is known in full details. This allows focussing on the BV-BFV technology and testing it. For the inexperienced reader, this is also a practical and reasonably simple way to learn it.
Vacuum energy in Einstein-Gauss-Bonnet anti-de Sitter gravity
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kofinas, Georgios; Olea, Rodrigo
2006-10-15
A finite action principle for Einstein-Gauss-Bonnet anti-de Sitter gravity is achieved by supplementing the bulk Lagrangian by a suitable boundary term, whose form substantially differs in odd and even dimensions. For even dimensions, this term is given by the boundary contribution in the Euler theorem with a coupling constant fixed, demanding the spacetime to have constant (negative) curvature in the asymptotic region. For odd dimensions, the action is stationary under a boundary condition on the variation of the extrinsic curvature. A well-posed variational principle leads to an appropriate definition of energy and other conserved quantities using the Noether theorem, andmore » to a correct description of black hole thermodynamics. In particular, this procedure assigns a nonzero energy to anti-de Sitter spacetime in all odd dimensions.« less
Cu, Ag, Au: Electrical Resistivity Along their Melting Boundaries
NASA Astrophysics Data System (ADS)
Secco, R.; Littleton, J. A. H.; Berrada, M.; Ezenwa, I.; Yong, W.
2017-12-01
Electrical resistivity of Cu, Ag and Au was measured at pressures up to 5 GPa and temperatures up to 300 K above melting in a 1000-ton cubic anvil press. Two W/Re thermocouples placed at opposite ends of the wire sample served as T probes as well as 4-wire resistance electrodes in a switched circuit. A polarity switch was also used to remove any bias associated with current flow and voltage measurement using thermocouple legs. Examination of the composition of recovered and sectioned samples was carried out using electron microprobe analyses. Melting temperatures at high pressures were determined from the large jump in resistivity on heating at constant pressure and these agree well with previous experimental and theoretical phase diagram studies. With increasing P and T, electrical resistivity behavior in these noble metals is consistent with 1atm data. The resistivity values at the melting temperature of Cu and Ag decrease with increasing high pressure and Au seems to behave similarly. The results are compared to prediction by Stacey and Anderson (PEPI, 2001).
Heat transfer at a sapphire - indium interface in the 30 mK - 300 mK temperature range
NASA Astrophysics Data System (ADS)
Liberadzka, J.; Koettig, T.; Bremer, J.; van der Post, C. C. W.; ter Brake, H. J. M.
2017-02-01
Within the framework of the AEgIS (Antimatter Experiment: Gravity, Interferometry, Spectroscopy) project a direct measurement of the Earth’s gravitational acceleration on antihydrogen will be carried out. In order to obtain satisfactory precision of the measurement, the thermal movement of the particles should be reduced. Therefore a Penning trap, which is used to trap antiprotons and create antihydrogen, will be placed on a mixing chamber of an especially designed dilution refrigerator. The trap consists of 10 electrodes, which need to be electrically insulated, but thermally anchored. To ensure that the trap remains at a temperature below 100 mK, the heat transfer at the metallic-dielectric boundary is investigated. A copper - indium - sapphire - indium - copper sandwich setup was mounted on the CERN Cryolab dilution refrigerator. Keeping the mixing chamber at a constant low temperature in the range of 30 mK to 300 mK, steady-state measurements with indium in normal conducting and superconducting states have been performed. Obtained results along with a precise description of our setup are presented.
The Impact of Wet Soil and Canopy Temperatures on Daytime Boundary-Layer Growth.
NASA Astrophysics Data System (ADS)
Segal, M.; Garratt, J. R.; Kallos, G.; Pielke, R. A.
1989-12-01
The impact of very wet soil and canopy temperatures on the surface sensible heat flux, and on related daytime boundary-layer properties is evaluated. For very wet soils, two winter situations are considered, related to significant changes in soil surface temperature: (1) due to weather perturbations at a given location, and (2) due to the climatological north-south temperature gradient. Analyses and scaling of the various boundary-layer properties, and soil surface fluxes affecting the sensible beat flux, have been made; related evaluations show that changes in the sensible heat flux at a given location by a factor of 2 to 3 due to temperature changes related to weather perturbations is not uncommon. These changes result in significant alterations in the boundary-layer depth; in the atmospheric boundary-layer warming; and in the break-up time of the nocturnal surface temperature inversion. Investigation of the impact of the winter latitudinal temperature gradient on the above characteristics indicated that the relative increase in very wet soil sensible heat flux, due to the climatological reduction in the surface temperature in northern latitudes, moderates to some extent its reduction due to the corresponding decrease in solar radiation. Numerical model simulations confirmed these analytical evaluations.In addition, the impact of synoptic temperature perturbations during the transition seasons (fall and spring) on canopy sensible heal fluxes, and the related boundary-layer characteristics mentioned above, was evaluated. Analogous features to those found for very wet soil surfaces occurred also for the canopy situations. Likewise, evaluations were also carried out to explore the impact of high midlatitude foreste areas on the boundary-layer characteristics during the winter as compared to those during the summer. Similar impacts were found in both seasons, regardless of the substantial difference in the daily total solar radiation.
NASA Astrophysics Data System (ADS)
Vilella, Kenny; Kaminski, Edouard
2017-05-01
The long-term habitability of a planet rises from its ability to generate and maintain an atmosphere through partial melting and volcanism. This question has been mainly addressed in the framework of plate tectonics, which may be too specific to apply to the wide range of internal dynamics expected for exoplanets, and even to the thermal evolution of the early Earth. Here we propose a more general theoretical approach of convection to build a regime diagram giving the conditions for partial melting to occur, in planetary bodies, as a function of key parameters that can be estimated for exoplanets, their size and internal heating rate. To that aim, we introduce a refined view of the Thermal Boundary Layer (TBL) in a convective system heated from within, that focuses on the temperature and thickness of the TBL at the top of the hottest temperature profiles, along which partial melting shall first occur. This ;Hottest Thermal Boundary Layer; (HotTBL) is first characterized using fully theoretical scaling laws based on the dynamics of thermal boundary layers. These laws are the first ones proposed in the literature that do not rely on empirical determinations of dimensionless constants and that apply to both low Rayleigh and high Rayleigh convective regimes. We show that the scaling laws can be successfully applied to planetary bodies by comparing their predictions to full numerical simulations of the Moon. We then use the scaling laws to build a regime diagram for exoplanets. Combined with estimates of internal heating in exoplanets, the regime diagram predicts that in the habitable zone partial melting occurs in planets younger than the Earth.
NASA Astrophysics Data System (ADS)
Vilella, K.; Kaminski, E. C.
2016-12-01
The long-term habitability of a planet rises from its ability to generate and maintain an atmosphere through partial melting and volcanism. This question has been mainly addressed in the framework of plate tectonics, which may be too specific to apply to the wide range of internal dynamics expected for exoplanets, and even to the thermal evolution of the early Earth. Here we propose a more general theoretical approach of convection to build a regime diagram giving the conditions for partial melting to occur in planetary bodies, as a function of key parameters that can be estimated for exoplanets, their size and internal heating rate. To that aim, we introduce a refined view of the Thermal Boundary layer (TBL) in a convective system heated from within, that focuses on the temperature and thickness of the TBL at the top of the hottest temperature profiles, along which partial melting shall first occur. This "Hottest Thermal Boundary Layer" (HotTBL) is first characterized using fully theoretical scaling laws based on the dynamics of thermal boundary layers. These laws are the first ones proposed in the literature that do not rely on empirical determinations of dimensionless constants and that apply to both low Rayleigh and high Rayleigh convective regimes. We show that the scaling laws can be successfully applied to planetary bodies by comparing their predictions to full numerical simulations of the Moon. We then use the scaling laws to build a regime diagram for exoplanets. Combined with estimates of internal heating in exoplanets, the regime diagram predicts that in the habitable zone partial melting occurs in planets younger than the Earth.
NASA Astrophysics Data System (ADS)
Noguchi, Naoki; Kubo, Tomoaki; Durham, William B.; Kagi, Hiroyuki; Shimizu, Ichiko
2016-08-01
We have developed a high-resolution technique based on micro Raman spectroscopy to measure hydrogen isotope diffusion profiles in ice Ih. The calibration curve for quantitative analysis of deuterium in ice Ih was constructed using micro Raman spectroscopy. Diffusion experiments using diffusion couples composed of dense polycrystalline H2O and D2O ice were carried out under a gas confining pressure of 100 MPa (to suppress micro-fracturing and pore formation) at temperatures from 235 K to 245 K and diffusion times from 0.2 to 94 hours. Two-dimensional deuterium profiles across the diffusion couples were determined by Raman imaging. The location of small spots of frost from room air could be detected from the shapes of the Raman bands of OH and OD stretching modes, which change because of the effect of the molar ratio of deuterium on the molecular coupling interaction. We emphasize the validity for screening the impurities utilizing the coupling interaction. Some recrystallization and grain boundary migration occurred in recovered diffusion couples, but analysis of two-dimensional diffusion profiles of regions not affected by grain boundary migration allowed us to measure a volume diffusivity for ice at 100 MPa of (2.8 ± 0.4) ×10-3exp[ -57.0 ± 15.4kJ /mol RT ] m2 /s (R is the gas constant, T is temperature). Based on ambient pressure diffusivity measurements by others, this value indicates a high (negative) activation volume for volume diffusivity of -29.5 cm3/mol or more. We can also constrain the value of grain boundary diffusivity in ice at 100 MPa to be <104 that of volume diffusivity.
NASA Technical Reports Server (NTRS)
Santoro, G. J.; Kohl, F. J.; Stearns, C. A.; Gokoglu, S. A.; Rosner, D. E.
1984-01-01
Deposition rates on platinum-rhodium cylindrical collectors rotating in the cross streams of the combustion gases of a salt-seeded Mach 0.3 burner rig were determined. The collectors were internally air cooled so that their surface temperatures could be widely varied while they were exposed to constant combustion gas temperatures. The deposition rates were compared with those predicted by the chemically frozen boundary layer (CFBL) computer program, which is based on multicomponent vapor transport through the boundary layer. Excellent agreement was obtained between theory and experiment for the NaCl-seeded case, but the agreement lessened as the seed was changed to synthetic sea salt, NaNO3, and K2SO4, respectively, and was particularly poor in the case of Na2SO4. However, when inertial impaction was assumed to be the deposition mechanism for the Na2SO4 case, the predicted rates agreed well with the experimental rates. The former were calculated from a mean particle diameter that was derived from the measured intial droplet size distribution of the solution spray. Critical experiments showed that liquid phase deposits were blown off the smooth surface of the platinum-rhodium collectors by the aerodynamic shear forces of the high-velocity combustion gases but that rough or porous surfaces retained their liquid deposits.
Gravity Scaling of a Power Reactor Water Shield
NASA Technical Reports Server (NTRS)
Reid, Robert S.; Pearson, J. Boise
2008-01-01
Water based reactor shielding is being considered as an affordable option for use on initial lunar surface power systems. Heat dissipation in the shield from nuclear sources must be rejected by an auxiliary thermal hydraulic cooling system. The mechanism for transferring heat through the shield is natural convection between the core surface and an array of thermosyphon radiator elements. Natural convection in a 100 kWt lunar surface reactor shield design has been previously evaluated at lower power levels (Pearson, 2007). The current baseline assumes that 5.5 kW are dissipated in the water shield, the preponderance on the core surface, but with some volumetric heating in the naturally circulating water as well. This power is rejected by a radiator located above the shield with a surface temperature of 370 K. A similarity analysis on a water-based reactor shield is presented examining the effect of gravity on free convection between a radiation shield inner vessel and a radiation shield outer vessel boundaries. Two approaches established similarity: 1) direct scaling of Rayleigh number equates gravity-surface heat flux products, 2) temperature difference between the wall and thermal boundary layer held constant on Earth and the Moon. Nussult number for natural convection (laminar and turbulent) is assumed of form Nu = CRa(sup n). These combined results estimate similarity conditions under Earth and Lunar gravities. The influence of reduced gravity on the performance of thermosyphon heat pipes is also examined.
Thermocouple Rakes for Measuring Boundary Layer Flows Extremely Close to Surface
NASA Technical Reports Server (NTRS)
Hwang, Danny P.; Fralick, Gustave C.; Martin, Lisa C.; Blaha, Charles A.
2001-01-01
Of vital interest to aerodynamic researchers is precise knowledge of the flow velocity profile next to the surface. This information is needed for turbulence model development and the calculation of viscous shear force. Though many instruments can determine the flow velocity profile near the surface, none of them can make measurements closer than approximately 0.01 in. from the surface. The thermocouple boundary-layer rake can measure much closer to the surface than conventional instruments can, such as a total pressure boundary layer rake, hot wire, or hot film. By embedding the sensors (thermocouples) in the region where the velocity is equivalent to the velocity ahead of a constant thickness strut, the boundary-layer flow profile can be obtained. The present device fabricated at the NASA Glenn Research Center microsystem clean room has a heater made of platinum and thermocouples made of platinum and gold. Equal numbers of thermocouples are placed both upstream and downstream of the heater, so that the voltage generated by each pair at the same distance from the surface is indicative of the difference in temperature between the upstream and downstream thermocouple locations. This voltage differential is a function of the flow velocity, and like the conventional total pressure rake, it can provide the velocity profile. In order to measure flow extremely close to the surface, the strut is made of fused quartz with extremely low heat conductivity. A large size thermocouple boundary layer rake is shown in the following photo. The latest medium size sensors already provide smooth velocity profiles well into the boundary layer, as close as 0.0025 in. from the surface. This is about 4 times closer to the surface than the previously used total pressure rakes. This device also has the advantage of providing the flow profile of separated flow and also it is possible to measure simultaneous turbulence levels within the boundary layer.
Recent Developments Related To An Optically Controlled Microwave Phased Array Antenna.
NASA Astrophysics Data System (ADS)
Kittel, A.; Peinke, J.; Klein, M.; Baier, G.; Parisi, J.; Rössler, O. E.
1990-12-01
A generic 3-dimensional diffeomorphic map, with constant Jacobian determinant, is proposed and looked at numerically. It contains a lower-dimensional basin boundary along which a chaotic motion takes place. This boundary is nowhere differentiable in one direction. Therefore, nowhere differentiable limit sets exist generically in nature.
NASA Astrophysics Data System (ADS)
Meng, ZhuXuan; Fan, Hu; Peng, Ke; Zhang, WeiHua; Yang, HuiXin
2016-12-01
This article presents a rapid and accurate aeroheating calculation method for hypersonic vehicles. The main innovation is combining accurate of numerical method with efficient of engineering method, which makes aeroheating simulation more precise and faster. Based on the Prandtl boundary layer theory, the entire flow field is divided into inviscid and viscid flow at the outer edge of the boundary layer. The parameters at the outer edge of the boundary layer are numerically calculated from assuming inviscid flow. The thermodynamic parameters of constant-volume specific heat, constant-pressure specific heat and the specific heat ratio are calculated, the streamlines on the vehicle surface are derived and the heat flux is then obtained. The results of the double cone show that at the 0° and 10° angle of attack, the method of aeroheating calculation based on inviscid outer edge of boundary layer parameters reproduces the experimental data better than the engineering method. Also the proposed simulation results of the flight vehicle reproduce the viscid numerical results well. Hence, this method provides a promising way to overcome the high cost of numerical calculation and improves the precision.
Boundary layer temperature measurements of a noctual urban boundary layer
NASA Astrophysics Data System (ADS)
Holloway, Simon; Ricketts, Hugo; Vaughan, Geraint
2018-04-01
A low-power lidar system based in Manchester, United Kingdom has been developed to measure temperature profiles in the nocturnal urban boundary layer. The lidar transmitter uses a 355nm diode-pumped solid state Nd:YAG laser and two narrow-band interference filters in the receiver filter out rotational Raman lines that are dependent on temperature. The spectral response of the lidar is calibrated using a monochromator. Temperature profiles measured by the system are calibrated by comparison to co-located radiosondes.
Effect of grain size on the melting point of confined thin aluminum films
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wejrzanowski, Tomasz; Lewandowska, Malgorzata; Sikorski, Krzysztof
2014-10-28
The melting of aluminum thin film was studied by a molecular dynamics (MD) simulation technique. The effect of the grain size and type of confinement was investigated for aluminum film with a constant thickness of 4 nm. The results show that coherent intercrystalline interface suppress the transition of solid aluminum into liquid, while free-surface gives melting point depression. The mechanism of melting of polycrystalline aluminum thin film was investigated. It was found that melting starts at grain boundaries and propagates to grain interiors. The melting point was calculated from the Lindemann index criterion, taking into account only atoms near to grainmore » boundaries. This made it possible to extend melting point calculations to bigger grains, which require a long time (in the MD scale) to be fully molten. The results show that 4 nm thick film of aluminum melts at a temperature lower than the melting point of bulk aluminum (933 K) only when the grain size is reduced to 6 nm.« less
NASA Astrophysics Data System (ADS)
Gao, Siwen; Rajendran, Mohan Kumar; Fivel, Marc; Ma, Anxin; Shchyglo, Oleg; Hartmaier, Alexander; Steinbach, Ingo
2015-10-01
Three-dimensional discrete dislocation dynamics (DDD) simulations in combination with the phase-field method are performed to investigate the influence of different realistic Ni-base single crystal superalloy microstructures with the same volume fraction of {γ\\prime} precipitates on plastic deformation at room temperature. The phase-field method is used to generate realistic microstructures as the boundary conditions for DDD simulations in which a constant high uniaxial tensile load is applied along different crystallographic directions. In addition, the lattice mismatch between the γ and {γ\\prime} phases is taken into account as a source of internal stresses. Due to the high antiphase boundary energy and the rare formation of superdislocations, precipitate cutting is not observed in the present simulations. Therefore, the plastic deformation is mainly caused by dislocation motion in γ matrix channels. From a comparison of the macroscopic mechanical response and the dislocation evolution for different microstructures in each loading direction, we found that, for a given {γ\\prime} phase volume fraction, the optimal microstructure should possess narrow and homogeneous γ matrix channels.
Basu, Sohini; Sen, Srikanta
2013-02-25
Structure and dynamics both are known to be important for the activity of a protein. A fundamental question is whether a thermophilic protein and its mesophilic homologue exhibit similar dynamics at their respective optimal growth temperatures. We have addressed this question by performing molecular dynamics (MD) simulations of a natural mesophilic-thermophilic homologue pair at their respective optimal growth temperatures to compare their structural, dynamical, and solvent properties. The MD simulations were done in explicit aqueous solvent under periodic boundary and constant pressure and temperature (CPT) conditions and continued for 10.0 ns using the same protocol for the two proteins, excepting the temperatures. The trajectories were analyzed to compare the properties of the two proteins. Results indicated that the dynamical behaviors of the two proteins at the respective optimal growth temperatures were remarkably similar. For the common residues in the thermophilic protein, the rms fluctuations have a general trend to be slightly higher compared to that in the mesophilic counterpart. Lindemann parameter values indicated that only a few residues exhibited solid-like dynamics while the protein as a whole appeared as a molten globule in each case. Interestingly, the water-water interaction was found to be strikingly similar in spite of the difference in temperatures while, the protein-water interaction was significantly different in the two simulations.
Neutron inelastic scattering measurements of low-energy phonons in the multiferroic BiFeO 3
Schneeloch, John A.; Xu, Zhijun; Wen, Jinsheng; ...
2015-02-10
In this study, we present neutron inelastic scattering measurements of the low-energy phonons in single crystal BiFeO 3. The dispersions of the three acoustic phonon modes (LA along [100], TA 1 along [010], and TA 2 along [110]) and two low-energy optic phonon modes (LO and TO 1) have been mapped out between 300 and 700 K. Elastic constants are extracted from the phonon measurements. The energy linewidths of both TA phonons at the zone boundary clearly broaden when the system is warmed toward the magnetic ordering temperature T N=640 K. In conclusion, this suggests that the magnetic order andmore » low-energy lattice dynamics in this multiferroic material are coupled.« less
NASA Astrophysics Data System (ADS)
Das, Sananda; Sahoo, R. C.; Bera, K. P.; Nath, T. K.
2018-04-01
Doping at the post-transition metal site by trivalent rare-earth ions and 3d transition metal site by transition metal ions in perovskite lattice has observed a variety of magnetic and electronic orders with spatially correlated charge, spin and orbital degrees of freedom. Here, we report large ferromagnetism and enhanced dielectric constant (at ∼100 Hz) in chemically synthesized single phase multiferroic Bi1-xNdxFe1-yCoyO3 (x = 0, 0.10; y = 0, 0.10) nanoparticles (average particles size ∼45 nm). We have also examined the ferroelectric nature of our chemically synthesized samples. The Rietveld refinement of the XRD data reveals the structural symmetry breaking from distorted rhombohedral R3c structure of BiFeO3 to the triclinic P1 structure in Bi0.9Nd0.1Fe0.9Co0.1O3 (BNFCO) without having any iron rich impurity phase. The magnetization in these nanoceramics most likely originates from the coexistence of mixed valence states of Fe ion (Fe2+ and Fe3+). A high room temperature dielectric constant (∼1050) has been observed at 100 Hz of BNFCO sample. The frequency dependent anomalies near Neel temperature of antiferromagnet in temperature variation of dielectric study have been observed for all the doped and co-doped samples exhibiting typical characteristic of relaxor ferroelectrics. A spectacular enhancement of remanent magnetization MR (∼7.2 emu/gm) and noticeably large coercivity HC (∼17.4 kOe) at 5 K have been observed in this BNFCO sample. Such emergence of ferromagnetic ordering indicates the canting of the surface spins at the surface boundaries because of the reduction of particle size in nanodimension. We have also observed P-E hysteresis loops with a remanent polarization of 26 μC/cm2 and coercive field of 5.6 kV/cm of this sample at room temperature. From impedance spectroscopy study the estimated activation energy of 0.41 eV suggests the semiconducting nature of our nanoceramic BNCFO sample.
NASA Astrophysics Data System (ADS)
Huang, Shi-Di; Wang, Fei; Xi, Heng-Dong; Xia, Ke-Qing
2014-11-01
We report an experimental study of the influences of thermal boundary condition in turbulent thermal convection. Two configurations were examined: one was fixed heat flux at the bottom boundary and fixed temperature at the top (HC cells); the other was fixed temperature at both boundaries (CC cells). It is found that the flow strength in the CC cells is on average 9% larger than that in the HC ones, which could be understood as change in plume emission ability under different boundary conditions. It is further found, rather surprisingly, that flow reversals of the large-scale circulation occur more frequently in the CC cell, despite a stronger large-scale flow and more uniform temperature distribution over the boundaries. These findings provide new insights into turbulent thermal convection and should stimulate further studies, especially experimental ones. This work is supported by the Hong Kong Research Grants Council under Grant No. CUHK 403712.
a Steady Thermal State for the Earth's Interior
NASA Astrophysics Data System (ADS)
Andrault, D.; Monteux, J.; Le Bars, M.; Samuel, H.
2015-12-01
Large amounts of heat are permanently lost at the surface yielding the classic view of the Earth continuously cooling down. Contrary to this conventional depiction, we propose that the temperature profile in the deep Earth has remained almost constant for the last ~3 billion years (Ga) or more. The core-mantle boundary (CMB) temperature reached the mantle solidus of 4100 (+/-300) K after complete crystallization of the magma ocean not more than 1 Ga after the Moon-forming impact. The CMB remains at a similar temperature today; seismological evidences of ultra-low velocity zones suggest partial melting in the D"-layer and, therefore, a current temperature at, or just below, the mantle solidus. Such a steady thermal state of the CMB temperature excludes thermal buoyancy and compositional convection from being the predominant mechanisms to power the geodynamo over geological time. An alternative mechanism to produce motion in the outer core is mechanical forcing by tidal distortion and planetary precession. The conversion of gravitational and rotational energies of the Earth-Moon-Sun system to core motions could have supplied the lowermost mantle with a variable intensity heat source through geological time, due to the regime of core instabilities and/or changes in the astronomical forces. This variable heat source could explain the dramatic volcanic events that occurred in the Earth's history.
NASA Astrophysics Data System (ADS)
Fang, Pingping
1998-12-01
An extended numerical investigation of fully developed, forced convective laminar flows with heat transfer in eccentric annuli has been carried out. Both Newtonian and non-Newtonian (power-law or Ostwald-de Waele) fluids are studied, representing typical applications in petrochemical, bio-chemical, personal care products, polymer/plastic extrusion and food industries. For the heat transfer problem, with an insulated outer surface, two types of thermal boundary conditions have been considered: Constant wall temperature (T), and uniform axial heat flux with constant peripheral temperature (H1) on the inner surface of the annulus. The governing differential equations for momentum and energy conservation are solved by finite-difference methods. Velocity and temperature distributions in the flow cross section, the wall shear-stress distribution, and isothermal f Re, Nu i,T and Nu i,H1 values for different eccentric annuli (0/leɛ/*/le0.6,/ 0.2/le r/sp/*/le0.8) are presented. In Newtonian flows, the eccentricity is found to have a very strong influence on the flow and temperature fields. In an annulus with relatively large inner cylinder eccentricity, the flow tends to stagnate in the narrow section and has higher peak velocities in the wide section of the annulus. There is considerable flow maldistribution in the azimuthal direction, which in turn produces greater nonuniformity in the temperature field and a consequent degradation in the average heat transfer. Also, the H1 wall condition sustains higher heat transfer coefficients relative to the T boundary condition on the inner surface. For viscous, power-law type non-Newtonian flows, both shear thinning (n<1) and shear thickening (n>1) fluids are considered. Here, the non-linear shear behavior of the fluid is found to further aggravate the flow and temperature maldistribution, and once again the eccentricity is seen to exhibit a very strong influence on the friction and heat transfer behavior. Finally, the hydrodynamic characteristics of fully developed axial laminar flow of Newtonian fluids in eccentric annuli with a rotating inner cylinder are investigated. These are of significant importance to the design and operation of oil and gas drilling wells. Using finite-difference method to solve the governing flow equations in bipolar coordinates, computational results for a wide range of annulus geometry (0/le r/sp/*/le1,/ 0/le/varepsilon/sp/*/le0.8), and rotational Reynolds number (0/le Rer/le150) are presented, where the rotational speeds are restricted to the sub-critical Taylor number regime. The results delineate the effects of annuli r/sp/* and ɛsp/*, and inner cylinder rotation speed on the flow structure and frictional losses.
Terrestrial growth of lead-tin-telluride by techniques related to low G growth
NASA Technical Reports Server (NTRS)
Jesser, W. A.
1982-01-01
A modified Bridgman-Stockbarger furnace was constructed for a study of the solidification of silver, germanium and lead-tin-telluride. The melt-solid interface position with respect to the furnace and its temperature profile was determined by measuring the discontinuity in the slope of temperature as a function of position in the melt and in the solid. The results show that the interface position of the semiconductors germanium and lead-tin-telluride was essentially constant with respect to the furnace and hence the growth rate was constant and equal to the sample translation rate of 0.046 cm/min and 0.178 cm/min in each case. The metal, silver, on the other hand showed a continuous interface migration toward the hot zone of the furnace and always exhibited a growth rate which was higher than the ampoule translation rate. The K sub L/K sub S ratio of lead-tin-telluride was determined to be 2.33 + or - 0.06 where K sub L,S denotes the thermal conductivity of the liquid, solid respectively. The value of K sub L was calculated to be about 0.054 Watt 0.1 cm 0.1 K. The diffusion boundary layer thickness was calculated for lead-tin-telluride to be about 0.05 cm using a liquid diffusivity of .00007 sq cm/sec.
NASA Astrophysics Data System (ADS)
Laysandra, H.; Triyono, D.
2017-04-01
Dielectric properties of nano-crystalline material LaFeO3.xFe3O4 with x = 0, 0.1, 0.2, 0.3, and 0.4 at.% have been studied by impedance spectroscopy method. LaFeO3 was synthesized by sol-gel method resulting nano-particle. Then, it was mixed with Fe3O4 powder. The mixture powder was pressed to form pellet and then sintered at 1300°C for 1 h to form nano-crystalline of LaFeO3.xFe3O4. X-ray diffraction characterization at room temperature for all samples show two phases i.e. perovskite LaFeO3 (orthorhombic) as a main phase and Fe3O4 (cubic) as second phase. It is found that the crystallite size of main phase increases with addition of Fe3O4 until 0.3 at.%. The electrical properties as a function of temperature (300-500 K) and frequency (100 Hz - 1 MHz) are presented in Nyquist and Bode plots. It is observed that from equivalent circuit and their parameters, dielectrical properties are contributed by grain and grain boundary. The dielectric constant, ε‧ were calculated by parallel plate method and their values reach up to 107 exhibiting typical colossal dielectric constant (CDC) material like behavior.
NASA Astrophysics Data System (ADS)
Chand, Prakash; Vaish, Swapnil; Kumar, Praveen
2017-11-01
In the present work, transition metal spinel ferrite (MFe2O4; M = Co, Ni, Zn) nanostructures synthesized by chemical co-precipitation method. XRD analysis confirms the formation of cubic spinel-type structure with space group Fd3m and the average crystallite size calculated by Scherrer's formula found to be in 9-14 nm range. Scanning electron microscopy was used to study surface morphology of the samples. Moreover, Raman and PL spectra also confirm the formation of the cubic structure. The Raman spectra measured on cobalt, nickel and zinc ferrite revealed a larger number of phonon bands than expected for the cubic spinel structure. The calculated optical energy band gaps, obtained by Tauc's relation from UV-Vis absorption spectra are found to be as 2.44, 3.54 and 3.25 eV for CoFe2O4, NiFe2O4&ZnFe2O, respectively. The analysis of the complex impedance spectra of all ferrites samples shows the presence of one semicircular arc at all selected temperatures, signifying a key role of the grain boundary contribution. The dielectric constants (ε ‧) were measured in the frequency range from 10 Hz to 5 MHz at different temperatures and is found to be decreased suddenly with an increase in frequency and maintain a steady state or constant at higher frequencies for all the three samples. The AC conductivity is found to be increased with frequency and temperature of all the three samples which is explained on the basis of Koop's phenomenological theory.
Tectonic plates, D (double prime) thermal structure, and the nature of mantle plumes
NASA Technical Reports Server (NTRS)
Lenardic, A.; Kaula, W. M.
1994-01-01
It is proposed that subducting tectonic plates can affect the nature of thermal mantle plumes by determining the temperature drop across a plume source layer. The temperature drop affects source layer stability and the morphology of plumes emitted from it. Numerical models are presented to demonstrate how introduction of platelike behavior in a convecting temperature dependent medium, driven by a combination of internal and basal heating, can increase the temperature drop across the lower boundary layer. The temperature drop increases dramatically following introduction of platelike behavior due to formation of a cold temperature inversion above the lower boundary layer. This thermal inversion, induced by deposition of upper boundary layer material to the system base, decays in time, but the temperature drop across the lower boundary layer always remains considerably higher than in models lacking platelike behavior. On the basis of model-inferred boundary layer temperature drops and previous studies of plume dynamics, we argue that generally accepted notions as to the nature of mantle plumes on Earth may hinge on the presence of plates. The implication for Mars and Venus, planets apparently lacking plate tectonics, is that mantle plumes of these planets may differ morphologically from those of Earth. A corollary model-based argument is that as a result of slab-induced thermal inversions above the core mantle boundary the lower most mantle may be subadiabatic, on average (in space and time), if major plate reorganization timescales are less than those acquired to diffuse newly deposited slab material.
Bessel Plasmon-Polaritons at the Boundaries of Metamaterials with Near-Zero Dielectric Constants
NASA Astrophysics Data System (ADS)
Kurilkina, S. N.; Belyi, V. N.; Kazak, N. S.; Binhussain, M. A.
2015-07-01
The conditions for and features of the excitation of Bessel plasmon-polaritons (BPP) are examined at the boundary of a hyperbolic metamaterial with a near-zero dielectric constant made of a dielectric matrix with metal nanorods embedded in it normal to its surface. This material is compared with BPP that have traditional surface plasmons. The effect of the absorption of the metamaterial on the excitation of BPP is studied. The possibility of changes in the direction of the radial energy fl ows in BPP excited at the surface of an isotropic medium, a hyperbolic metamaterial, is demonstrated and the conditions for these changes are determined.
NASA Technical Reports Server (NTRS)
Bathel, Brett F.; Danehy, Paul M.; Jones, Stephen B.; Johansen, Craig T.; Goyne, Christopher P.
2013-01-01
Measurements of mean streamwise velocity, fluctuating streamwise velocity, and instantaneous streamwise velocity profiles in a hypersonic boundary layer were obtained over a 10-degree half-angle wedge model. A laser-induced fluorescence-based molecular tagging velocimetry technique was used to make the measurements. The nominal edge Mach number was 4.2. Velocity profiles were measured both in an untripped boundary layer and in the wake of a 4-mm diameter cylindrical tripping element centered 75.4 mm downstream of the sharp leading edge. Three different trip heights were investigated: k = 0.53 mm, k = 1.0 mm and k = 2.0 mm. The laminar boundary layer thickness at the position of the measurements was approximately 1 mm, though the exact thickness was dependent on Reynolds number and wall temperature. All of the measurements were made starting from a streamwise location approximately 18 mm downstream of the tripping element. This measurement region continued approximately 30 mm in the streamwise direction. Additionally, measurements were made at several spanwise locations. An analysis of flow features show how the magnitude, spatial location, and spatial growth of streamwise velocity instabilities are affected by parameters such as the ratio of trip height to boundary layer thickness and roughness Reynolds number. The fluctuating component of streamwise velocity measured along the centerline of the model increased from approximately 75 m/s with no trip to +/-225 m/s with a 0.53-mm trip, and to +/-240 m/s with a 1-mm trip, while holding the freestream Reynolds number constant. These measurements were performed in the 31-inch Mach 10 Air Tunnel at the NASA Langley Research Center.
Elastic Constants of Ni-Mn-Ga Magnetic Shape Memory Alloys
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stipcich, M.; Manosa, L.; Planes, A.
2004-01-01
We have measured the adiabatic second order elastic constants of two Ni-Mn-Ga magnetic shape memory crystals with different martensitic transition temperatures, using ultrasonic methods. The temperature dependence of the elastic constants has been followed across the ferromagnetic transition and down to the martensitic transition temperature. Within experimental errors no noticeable change in any of the elastic constants has been observed at the Curie point. The temperature dependence of the shear elastic constant C' has been found to be very different for the two alloys. Such a different behavior is in agreement with recent theoretical predictions for systems undergoing multi-stage structuralmore » transitions.« less
NASA Astrophysics Data System (ADS)
Semenov, S. V.; Balaev, D. A.
2018-07-01
Granular high-temperature superconductors (HTSs) are characterized by the hysteretic behavior of magnetoresistance. This phenomenon is attributed to the effective field in the intergrain medium of a granular HTS. At the grain boundaries, which are, in fact, weak Josephson couplings, the dissipation is observed. The effective field in the intergrain medium is a superposition of the external field and the field induced by magnetic moments of HTS grains. Meanwhile, analysis of the field width of the R(H) magnetoresistance hysteresis ΔH = Hdec - Hinc at Hdec = const, where Hinc and Hdec are increasing and decreasing branches of the R(H) hysteretic dependence, shows that the effective field in the intergrain medium exceeds by far both the external field and the field induced by magnetic moments of HTS grains. This situation suggests the magnetic flux compression in the intergrain medium because of the small length of grain boundaries, which amounts to ∼1 nm, i.e., is comparable with the coherence length and corresponds to Josephson tunneling in HTS materials. In this work, using the previously developed approach, we examine experimental data on the magnetoresistance and magnetization hysteresis in the granular YBa2Cu3O7 HTS compound in the range from 77 K to the critical temperature. According to the results obtained, the degree of magnetic flux compression determined by the parameter α in the expression for the effective field Beff(H) = H - 4π M(H) α in the intergrain medium remains constant over the investigated temperature range. All the features of the observed evolution of the R(H) hysteretic dependences are explained well within the proposed approach when the expression for Beff(H) contains the experimental M(H) magnetization data and the parameter α of about 20-25. The latter is indicative of the dominant effect of magnetic flux compression in the intergrain medium on the transport properties of granular HTS materials.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shyam, Amit; Lara-Curzio, Edgar
This paper reports on the langatate (LGT) elastic constants measured from room temperature (25 C) to 1100 C using resonant ultrasound spectroscopy (RUS). The constants were extracted by fitting the resonant peaks with those calculated by Lagrangian mechanics at each temperature where the RUS measurements were taken. In addition, the RUS technique was used to extract the piezoelectric constants in the 25 C to 120 C temperature range. This work also publishes a set of temperature coefficients for the elastic constants up to 1100 C. For the measurements, six parallelepiped LGT samples were aligned, cut, ground, and polished at themore » University of Maine. The samples were aligned to two different crystal orientations, to increase the reliability of the constant fitting. The extraction of LGT elastic constants up to 1100 C presented in this paper represents a critical step towards the design and fabrication of LGT acoustic wave devices for high temperature and harsh environment applications.« less
Holographic multiverse and the measure problem
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vilenkin, Alexander, E-mail: vilenkin@cosmos.phy.tufts.edu
2011-06-01
We discuss the duality, conjectured in earlier work, between the wave function of the multiverse and a 3D Euclidean theory on the future boundary of spacetime. In particular, we discuss the choice of the boundary metric and the relation between the UV cutoff scale ξ on the boundary and the hypersurface Σ on which the wave function is defined in the bulk. We propose that in the limit ξ → 0 this hypersurface should be used as the cutoff surface in the multiverse measure. Furthermore, we argue that in the inflating regions of spacetime with a slowly varying Hubble ratemore » H the hypersurfaces Σ are surfaces of constant comoving apparent horizon (CAH). Finally, we introduce a measure prescription (called CAH+) which appears to have no pathological features and coincides with the constant CAH cutoff in regions of slowly varying H.« less
Self-gravity, self-consistency, and self-organization in geodynamics and geochemistry
NASA Astrophysics Data System (ADS)
Anderson, Don L.
The results of seismology and geochemistry for mantle structure are widely believed to be discordant, the former favoring whole-mantle convection and the latter favoring layered convection with a boundary near 650 km. However, a different view arises from recognizing effects usually ignored in the construction of these models, including physical plausibility and dimensionality. Self-compression and expansion affect material properties that are important in all aspects of mantle geochemistry and dynamics, including the interpretation of tomographic images. Pressure compresses a solid and changes physical properties that depend on volume and does so in a highly nonlinear way. Intrinsic, anelastic, compositional, and crystal structure effects control seismic velocities; temperature is not the only parameter, even though tomographic images are often treated as temperature maps. Shear velocity is not a good proxy for density, temperature, and composition or for other elastic constants. Scaling concepts are important in mantle dynamics, equations of state, and wherever it is necessary to extend laboratory experiments to the parameter range of the Earth's mantle. Simple volume-scaling relations that permit extrapolation of laboratory experiments, in a thermodynamically self-consistent way, to deep mantle conditions include the quasiharmonic approximation but not the Boussinesq formalisms. Whereas slabs, plates, and the upper thermal boundary layer of the mantle have characteristic thicknesses of hundreds of kilometers and lifetimes on the order of 100 million years, volume-scaling predicts values an order of magnitude higher for deep-mantle thermal boundary layers. This implies that deep-mantle features are sluggish and ancient. Irreversible chemical stratification is consistent with these results; plausible temperature variations in the deep mantle cause density variations that are smaller than the probable density contrasts across chemical interfaces created by accretional differentiation and magmatic processes. Deep-mantle features may be convectively isolated from upper-mantle processes. Plate tectonics and surface geochemical cycles appear to be entirely restricted to the upper ˜1,000 km. The 650-km discontinuity is mainly an isochemical phase change but major-element chemical boundaries may occur at other depths. Recycling laminates the upper mantle and also makes it statistically heterogeneous, in agreement with high-frequency scattering studies. In contrast to standard geochemical models and recent modifications, the deeper layers need not be accessible to surface volcanoes. There is no conflict between geophysical and geochemical data, but a physical basis for standard geochemical and geodynamic mantle models, including the two-layer and whole-mantle versions, and qualitative tomographic interpretations has been lacking.
Lee, Abigail H; Eme, John; Mueller, Casey A; Manzon, Richard G; Somers, Christopher M; Boreham, Douglas R; Wilson, Joanna Y
2016-04-01
Increasing incubation temperatures, caused by global climate change or thermal effluent from industrial processes, may influence embryonic development of fish. This study investigates the cumulative effects of increased incubation temperature and repeated heat shocks on developing Lake Whitefish (Coregonus clupeaformis) embryos. We studied the effects of three constant incubation temperatures (2°C, 5°C or 8°C water) and weekly, 1-h heat shocks (+3°C) on hatching time, survival and morphology of embryos, as these endpoints may be particularly susceptible to temperature changes. The constant temperatures represent the predicted magnitude of elevated water temperatures from climate change and industrial thermal plumes. Time to the pre-hatch stage decreased as constant incubation temperature increased (148d at 2°C, 92d at 5°C, 50d at 8°C), but weekly heat shocks did not affect time to hatch. Mean survival rates and embryo morphometrics were compared at specific developmental time-points (blastopore, eyed, fin flutter and pre-hatch) across all treatments. Constant incubation temperatures or +3°C heat-shock exposures did not significantly alter cumulative survival percentage (~50% cumulative survival to pre-hatch stage). Constant warm incubation temperatures did result in differences in morphology in pre-hatch stage embryos. 8°C and 5°C embryos were significantly smaller and had larger yolks than 2°C embryos, but heat-shocked embryos did not differ from their respective constant temperature treatment groups. Elevated incubation temperatures may adversely alter Lake Whitefish embryo size at hatch, but weekly 1-h heat shocks did not affect size or survival at hatch. These results suggest that intermittent bouts of warm water effluent (e.g., variable industrial emissions) are less likely to negatively affect Lake Whitefish embryonic development than warmer constant incubation temperatures that may occur due to climate change. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Brutsaert, Wilfried; Sugita, Michiaki
1992-01-01
Evaporation from natural land surfaces often exhibits a strong variation during the course of a day, mostly in response to the daily variation of radiative energy input at the surface. This makes it difficult to derive the total daily evaporation, when only one or a few instantaneous estimates of evaporation are available. It is often possible to resolve this difficulty by assuming self-preservation in the diurnal evolution of the surface energy budget. Thus if the relative partition of total incoming energy flux among the different components remains the same, the ratio of latent heat flux and any other flux component can be taken as constant through the day. This concept of constant flux ratios is tested by means of data obtained during the First ISLSCP Field Experiment; the instantaneous evaporation values were calculated by means of the atmospheric boundary layer bulk similarity approach with radiosonde profiles and radiative surface temperatures. Good results were obtained for evaporative flux ratios with available energy flux, with net radiation, and with incoming shortwave radiation.
Expanding Taylor bubble under constant heat flux
NASA Astrophysics Data System (ADS)
Voirand, Antoine; Benselama, Adel M.; Ayel, Vincent; Bertin, Yves
2016-09-01
Modelization of non-isothermal bubbles expanding in a capillary, as a contribution to the understanding of the physical phenomena taking place in Pulsating Heat Pipes (PHPs), is the scope of this paper. The liquid film problem is simplified and solved, while the thermal problem takes into account a constant heat flux density applied at the capillary tube wall, exchanging with the liquid film surrounding the bubble and also with the capillary tube outside medium. The liquid slug dynamics is solved using the Lucas-Washburn equation. Mass and energy balance on the vapor phase allow governing equations of bubble expansion to be written. The liquid and vapor phases are coupled only through the saturation temperature associated with the vapor pressure, assumed to be uniform throughout the bubble. Results show an over-heating of the vapor phase, although the particular thermal boundary condition used here always ensures an evaporative mass flux at the liquid-vapor interface. Global heat exchange is also investigated, showing a strong decreasing of the PHP performance to convey heat by phase change means for large meniscus velocities.
NASA Technical Reports Server (NTRS)
Agnone, A. M.
1972-01-01
The factors affecting a tangential fuel injector design for scramjet operation are reviewed and their effect on the efficiency of the supersonic combustion process is evaluated using both experimental data and theoretical predictions. A description of the physical problem of supersonic combustion and method of analysis is followed by a presentation and evaluation of some standard and exotic types of fuel injectors. Engineering fuel injector design criteria and hydrogen ignition schemes are presented along with a cursory review of available experimental data. A two-dimensional tangential fuel injector design is developed using analyses as a guide in evaluating the effects on the combustion process of various initial and boundary conditions including splitter plate thickness, injector wall temperature, pressure gradients, etc. The fuel injector wall geometry is shaped so as to maintain approximately constant pressure at the flame as required by a cycle analysis. A viscous characteristics program which accounts for lateral as well as axial pressure variations due to the mixing and combustion process is used in determining the wall geometry.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Huang, Weijiu; Chongqing Municipal Key Laboratory of Institutions of Higher Education for Mould Technology, Chongqing University of Technology, Chongqing 400054; Chai, Linjiang, E-mail: chailinjiang@cqut.edu.cn
2016-04-15
Specimens cut from a rolled tin bronze sheet were annealed at 400–800 °C for 1 h and evolution of their microstructures was then characterized in details by electron channeling contrast imaging and electron backscatter diffraction techniques. Particularly, statistics on special boundaries (SBs) with Σ ≤ 29 and network connectivity of random high angle boundaries (HABs) in the annealed specimens were examined to probe optimization potentials of grain boundary character distribution (GBCD) for this material. Results show that the deformed microstructure in the as-received material begins to be recrystallized when the annealing temperature increase to 500 °C and average grain sizesmore » surge with further increasing temperatures. As a result of the recrystallization, a large number of annealing twins (with Σ3 misorientation) are produced, leading to remarkably increased fractions of SBs (f{sub SBs}). Thanks to preexisting dense low angle boundaries, the majority of SBs in the 500 °C specimen with only partial recrystallization are Σ3{sub ic} (incoherent) boundaries, which effectively disrupt connectivity of random HABs network. Although the f{sub SBs} can be further increased (up to 72.5%) in specimens with full recrystallization (at higher temperatures), the Σ3{sub ic} boundaries would be replaced to some extent by Σ3{sub c} (coherent) boundaries which do not contribute directly to optimizing the GBCD. This work should be able to provide clear suggestions on applying the concept of grain boundary engineering to tin bronze alloys. - Highlights: • The rolled tin bronze begins to be recrystallized as temperature increases to 500 °C. • A lot of SBs are produced after recrystallization and the highest f{sub SBs} is 72.5%. • Partially recrystallized specimen has the optimum GBCD due to more Σ3{sub ic} boundaries. • The Σ3{sub ic} boundaries are replaced by Σ3{sub c} boundaries after full recrystallization.« less
Edalati, Kaveh; Horita, Zenji; Valiev, Ruslan Z
2018-04-30
Recent developments of nanostructured materials with grain sizes in the nanometer to submicrometer range have provided ground for numerous functional properties and new applications. However, in terms of mechanical properties, bulk nanostructured materials typically show poor ductility despite their high strength, which limits their use for structural applications. The present article shows that the poor ductility of nanostructured alloys can be changed to room-temperature superplastisity by a transition in the deformation mechanism from dislocation activity to grain-boundary sliding. We report the first observation of room-temperature superplasticity (over 400% tensile elongations) in a nanostructured Al alloy by enhanced grain-boundary sliding. The room-temperature grain-boundary sliding and superplasticity was realized by engineering the Zn segregation along the Al/Al boundaries through severe plastic deformation. This work introduces a new boundary-based strategy to improve the mechanical properties of nanostructured materials for structural applications, where high deformability is a requirement.
Qu, Zhechao; Werhahn, Olav; Ebert, Volker
2018-06-01
The effects of thermal boundary layers on tunable diode laser absorption spectroscopy (TDLAS) measurement results must be quantified when using the line-of-sight (LOS) TDLAS under conditions with spatial temperature gradient. In this paper, a new methodology based on spectral simulation is presented quantifying the LOS TDLAS measurement deviation under conditions with thermal boundary layers. The effects of different temperature gradients and thermal boundary layer thickness on spectral collisional widths and gas concentration measurements are quantified. A CO 2 TDLAS spectrometer, which has two gas cells to generate the spatial temperature gradients, was employed to validate the simulation results. The measured deviations and LOS averaged collisional widths are in very good agreement with the simulated results for conditions with different temperature gradients. We demonstrate quantification of thermal boundary layers' thickness with proposed method by exploitation of the LOS averaged the collisional width of the path-integrated spectrum.
NASA Astrophysics Data System (ADS)
Tanny, Josef; Lukyanov, Victor; Neiman, Michael; Cohen, Shabtai; Teitel, Meir
2017-04-01
The area of agricultural crops covered by screens is constantly increasing worldwide. While irrigation requirements for open canopies are well documented, corresponding information for covered crops is scarce. Therefore much effort in recent years has focused on measuring and modeling evapotranspiration of screen-covered crops. One model that can be utilized for such estimations is the mixing length model. As a first step towards future application of this model, selected mean and turbulent properties of the boundary layer above and below a shading screen were measured and analyzed. Experiments were carried out in a large banana plantation, covered by a light-weight horizontal shading screen deployed 5.5 m high. During the measurement period, plant height increased from 2.5 to 4.1 m. A 3D ultrasonic anemometer and temperature and humidity sensors were mounted on a lifting tower with a manual crank that could measure between 2.8 and 10.2 m height, i.e., both below and above the screen. In each profile, the sensors measured at different heights during consecutive time intervals of about 15 min each. Vertical profiles were measured around noon when external meteorological conditions were relatively stable. An additional stationary tower installed within the screenhouse about 20 m to the north of the lifting tower, continuously measured corresponding reference values at 4.5 m height. Footprint analysis shows that out of the 62 measured time intervals, only in 4 cases the 90% flux contribution originated from outside the screenhouse. Both horizontal air velocity, Uh, and normalized horizontal air velocity increased with height. Air temperature generally decreased with height, indicating that the boundary layer was statically unstable. Specific humidity decreased with height, as is typical for a well irrigated crop. Friction velocity, u∗, was higher above than below the screen, illustrating the role of the screen as a momentum sink. The mean ratio between friction velocity below and above the screen was 0.55. Vertical profiles of the surface drag coefficientCd = (u∗/U h)2 showed a consistent decease of √Cd-with height, mainly above the screen. This result is expected since, with a constant flux layer, the surface drag is bound to decrease with height. The energy spectrum of each velocity component, both below and above the screen, was calculated separately and their sum, the 3D spectrum (Tennekes and Lumely, 1972), was plotted as a function of frequency. Slopes of linear fits to the spectra ranged between -1.42 and -1.68, with a mean value of -1.59±0.04. These slopes are close to -5/3 (-1.67), the value typical of the inertial subrange in steady state turbulent boundary layers (Stull, 1988).
Kinetics of cellular dissolution in a Cu-Cd alloy
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nakkalil, R.; Gupta, S.P.
1989-07-01
Dissolution of the cellular precipitate by cell boundary migration has been studied in a Cu-2 at.% Cd alloy in the temperature range 777--878 K. Microstructural observations have revealed that the process of dissolution begins at the original position of the grain boundary as well as the cell boundary. The steady state rate of cell boundary migration decreased with decreasing temperature of dissolution and became zero at approximately 770 K, which is about 30 K below the equilibrium solves temperature. The boundary diffusivities were determined at a number of temperatures by using the theory of Petermann and Hornbogen modified for dissolution.more » The diffusivity values calculated from the experimental data are seven orders of magnitude higher than the corresponding volume diffusivities. From the temperature dependence of the diffusivity, an activation energy of 157 kJ mol{sup {minus} 1} is obtained, which is bout three-quarters of the activation energy for the bulk diffusion of Cd into Cu. From the diffusivity and activation energy values, it is concluded that the diffusion of Cd along the migrating grain boundaries control the dissolution of the cellular precipitate in this alloy.« less
Discourse Appropriation and Category Boundary Work: Casual Teachers in the Market
ERIC Educational Resources Information Center
Charteris, Jennifer; Jenkins, Kathryn; Jones, Marguerite; Bannister-Tyrrell, Michelle
2017-01-01
With the increasing casualisation of the teacher labour force, there is little written on the experiences of casual teachers and the challenges they face in brokering professional identities within constantly shifting and uncertain work contexts. Being a category bound casual teacher (a product of category boundary work) is a complex subject…
NASA Astrophysics Data System (ADS)
Shamanaeva, L. G.; Krasnenko, N. P.; Kapegesheva, O. F.
2018-04-01
Diurnal dynamics of the standard deviation (SD) of three wind velocity components measured with a minisodar in the atmospheric boundary layer is analyzed. Statistical analysis of measurement data demonstrates that the SDs for x- and y-components σx and σy lie in the range from 0.2 to 4 m/s, and σz = 0.1-1.2 m/s. The increase of σx and σy with the altitude is described sufficiently well by a power law with exponent changing from 0.22 to 1.3 depending on time of day, and σz increases by a linear law. Approximation constants are determined and errors of their application are estimated. It is found that the maximal diurnal spread of SD values is 56% for σx and σy and 94% for σz. The established physical laws and the obtained approximation constants allow the diurnal dynamics of the SDs for three wind velocity components in the atmospheric boundary layer to be determined and can be recommended for application in models of the atmospheric boundary layer.
NASA Astrophysics Data System (ADS)
Semenycheva, Alexandra V.; Chuvil'deev, Vladimir N.; Nokhrin, Aleksey V.
2018-05-01
The paper offers a model describing the process of grain boundary self-diffusion in metals with phase transitions in the solid state. The model is based on ideas and approaches found in the theory of non-equilibrium grain boundaries. The range of application of basic relations contained in this theory is shown to expand, as they can be used to calculate the parameters of grain boundary self-diffusion in high-temperature and low-temperature phases of metals with a phase transition. The model constructed is used to calculate grain boundary self-diffusion activation energy in titanium and zirconium and an explanation is provided as to their abnormally low values in the low-temperature phase. The values of grain boundary self-diffusion activation energy are in good agreement with the experiment.
A theoretical study of non-adiabatic surface effects for a model in the NTF cryogenic wind tunnel
NASA Technical Reports Server (NTRS)
Macha, J. M.; Pare, L. A.; Landrum, D. B.
1985-01-01
A theoretical analysis was made of the severity and effect of nonadiabatic surface conditions for a model in the NTF cryogenic wind tunnel. The nonadiabatic condition arises from heaters that are used to maintain a constant thermal environment for instrumentation internal to the model. The analysis was made for several axi-symmetric representations of a fuselage cavity, using a finite element heat conduction code. Potential flow and boundary layer codes were used to calculate the convection condition for the exterior surface of the model. The results of the steady state analysis show that it is possible to maintain the surface temperature very near the adiabatic value, with the judicious use of insulating material. Even for the most severe nonadiabatic condition studied, the effects on skin friction drag and displacement thickness were only marginally significant. The thermal analysis also provided an estimate of the power required to maintain a specified cavity temperature.
Ferroelectric and optical properties of `Ba-doped' new double perovskites
NASA Astrophysics Data System (ADS)
Parida, B. N.; Panda, Niranjan; Padhee, R.; Parida, R. K.
2018-06-01
Solid solution of Pb1.5Ba0.5BiNbO6 ceramic is explored here to obtain its ferroelectric and optical properties. The polycrystalline sample was prepared by a standard solid state reaction route. Room temperature XRD and FTIR spectra of the compound exhibit an appreciable change in its crystal structure of Pb2BiNbO6 on addition of 'Ba' in A site. The surface morphology of the gold-plated sintered pellet sample recorded by SEM exhibits a uniform distribution of small grains with well-defined grain boundaries. Detailed studies on the nature of polarization and variation of dielectric constant, tangent loss with temperature as well as frequency indicate the existence of Ferro-electricity in the sample. Using UV-Vis spectroscopy, the optical band gap of the studied sample has been estimated as 2.1 eV, which is useful for photo catalytic devices. Photoluminescence analysis of the powder sample shows a strong red photoluminescence with blue excitation, which is basically useful for LED.
NASA Technical Reports Server (NTRS)
Gnoffo, Peter A.; Inger, George R.
1999-01-01
The local viscous-inviscid interaction field generated by a wall temperature jump on a flat plate in supersonic flow and on the windside of a Reusable Launch Vehicle in hypersonic flow is studied in detail by both a Navier-Stokes numerical code and an analytical triple-deck model. Treatment of the rapid heat transfer changes both upstream and downstream of the jump is included. Closed form relationships derived from the triple-deck theory are presented. The analytically predicted pressure and heating variations including upstream influence are found to be in generally good agreement with the Computational Fluid Dynamic (CFD) predictions. These analyses not only clarify the interactive physics involved but also are useful in preliminary design of thermal protection systems and as an insertable module to improve CFD code efficiency when applied to such small-scale interaction problems. The analyses only require conditions at the wall and boundary-layer edge which are easily extracted from a baseline, constant wall temperature, CFD solution.
Kim, Da Hye; Kim, Hyun You; Ryu, Ji Hoon; Lee, Hyuck Mo
2009-07-07
This report on the solid-to-liquid transition region of an Ag-Pd bimetallic nanocluster is based on a constant energy microcanonical ensemble molecular dynamics simulation combined with a collision method. By varying the size and composition of an Ag-Pd bimetallic cluster, we obtained a complete solid-solution type of binary phase diagram of the Ag-Pd system. Irrespective of the size and composition of the cluster, the melting temperature of Ag-Pd bimetallic clusters is lower than that of the bulk state and rises as the cluster size and the Pd composition increase. Additionally, the slope of the phase boundaries (even though not exactly linear) is lowered when the cluster size is reduced on account of the complex relations of the surface tension, the bulk melting temperature, and the heat of fusion. The melting of the cluster initially starts at the surface layer. The initiation and propagation of a five-fold icosahedron symmetry is related to the sequential melting of the cluster.
Minerals of the earth's deep interior
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schiferl, D.; Zhao, Y.; Shankland, T.J.
1998-11-01
This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The project addresses the major geophysical issue of the nature of the seismic velocity and density discontinuity at 670 km depth (the boundary between upper and lower mantle with temperature about 1,900 K and pressure about 23 GPa). A phase change at this depth would represent a relatively small barrier to mantle convection through the discontinuity, but compositional change would inhibit thermal convection throughout the mantle. To address this problem the authors measured equation of state parameters in mantlemore » minerals as functions of high P-T using single crystal x-ray diffraction with a unique, new diamond-anvil cell (DAC) at simultaneous high temperature and pressure. Single-crystal diffraction improves absolute accuracy in lattice constants over those from powder diffraction by a factor of 5 to 10. The authors have measured equations of state of orthoenstatite MgSiO{sub 3} and hexagonal boron nitride hBN.« less
NASA Technical Reports Server (NTRS)
Hergenrother, P. M.
1989-01-01
Polyimides belong to a class of polymers known as polyheterocyclics. Unlike most other high temperature polymers, polyimides can be prepared from a variety of inexpensive monomers by several synthetic routes. The glass transition and crystalline melt temperature, thermooxidative stability, toughness, dielectric constant, coefficient of thermal expansion, chemical stability, mechanical performance, etc. of polyimides can be controlled within certain boundaries. This versatility has permitted the development of various forms of polyimides. These include adhesives, composite matrices, coatings, films, moldings, fibers, foams and membranes. Polyimides are synthesized through both condensation (step-polymerization) and addition (chain growth polymerization) routes. The precursor materials used in addition polyimides or imide oligomers are prepared by condensation method. High molecular weight polyimide made via polycondensation or step-growth polymerization is studied. The various synthetic routes to condensation polyimides, structure/property relationships of condensation polyimides and composite properties of condensation polyimides are all studied. The focus is on the synthesis and chemical structure/property relationships of polyimides with particular emphasis on materials for composite application.
Integral method for transient He II heat transfer in a semi-infinite domain
NASA Astrophysics Data System (ADS)
Baudouy, B.
2002-05-01
Integral methods are suited to solve a non-linear system of differential equations where the non-linearity can be found either in the differential equations or in the boundary conditions. Though they are approximate methods, they have proven to give simple solutions with acceptable accuracy for transient heat transfer in He II. Taking in account the temperature dependence of thermal properties, direct solutions are found without the need of adjusting a parameter. Previously, we have presented a solution for the clamped heat flux and in the present study this method is used to accommodate the clamped-temperature problem. In the case of constant thermal properties, this method yields results that are within a few percent of the exact solution for the heat flux at the axis origin. We applied this solution to analyze recovery from burnout and find an agreement within 10% at low heat flux, whereas at high heat flux the model deviates from the experimental data suggesting the need for a more refined thermal model.
NASA Astrophysics Data System (ADS)
Li, Sazi; Li, Wei; Chen, Ziyu
2014-11-01
Using the tensor network approach, we investigate the monomer-dimer models on a checkerboard lattice, in which there are interactions (with strength v ) between the parallel dimers on half of the plaquettes. For the fully packed interacting dimer model, we observe a Kosterlitz-Thouless (KT) transition between the low-temperature symmetry breaking and the high-temperature critical phases; for the doped monomer-dimer case with finite chemical potential μ , we also find an order-disorder phase transition which is of second order instead. We use the boundary matrix product state approach to detect the KT and second-order phase transitions and obtain the phase diagrams v -T and μ -T . Moreover, for the noninteracting monomer-dimer model (setting μ =ν =0 ), we get an extraordinarily accurate determination of the free energy per site (negative of the monomer-dimer constant h2) as f =-0.662 798 972 833 746 with the dimer density n =0.638 123 109 228 547 , both of 15 correct digits.
NASA Astrophysics Data System (ADS)
Shahriari, Babak; Vafaei, Reza; Mohammad Sharifi, Ehsan; Farmanesh, Khosro
2018-03-01
The hot deformation behavior of a high strength low carbon steel was investigated using hot compression test at the temperature range of 850-1100 °C and under strain rates varying from 0.001 to 1 s-1. It was found that the flow curves of the steel were typical of dynamic recrystallization at the temperature of 950 °C and above; at tested strain rates lower than 1 s-1. A very good correlation between the flow stress and Zener-Hollomon parameter was obtained using a hyperbolic sine function. The activation energy of deformation was found to be around 390 kJ mol-1. The kinetics of dynamic recrystallization of the steel was studied by comparing it with a hypothetical dynamic recovery curve, and the dynamically fraction recrystallized was modeled by the Kolmogorov-Johnson-Mehl-Avrami relation. The Avrami exponent was approximately constant around 1.8, which suggested that the type of nucleation was one of site saturation on grain boundaries and edges.
On the state of lithospheric stress in the absence of applied tectonic forces
McGarr, A.
1988-01-01
Numerous published analyses of the nontectonic state of stress are based on Hooke's law and the boundary condition of zero horizontal deformation. This approach has been used to determine the gravitational stress state as well as the effects of processes such as erosion and temperature changes on the state of lithospheric stress. The major disadvantage of these analyses involves the assumption of lateral constraint which seems unrealistic in view of the observational fact that the crust can deform horizontally in response to applied loads. If the same problems are addressed by assuming that the remote stress state is constant, instead of the condition of zero horizontal deformation, then the resulting stress states are entirely different and in good accord with observations. The processes of erosion and sedimentation have slight tendencies to increase and decrease, respectively, the state of deviatoric stress. Temperature changes have only minor effects on the stress state, as averaged over the thickness of the lithosphere. -from Author
Effect of boundary heat flux on columnar formation in binary alloys: A phase-field study
NASA Astrophysics Data System (ADS)
Du, Lifei; Zhang, Peng; Yang, Shaomei; Chen, Jie; Du, Huiling
2018-02-01
A non-isothermal phase-field model was employed to simulate the columnar formation during rapid solidification in binary Ni-Cu alloy. Heat flux at different boundaries was applied to investigate the temperature gradient effect on the morphology, concentration and temperature distributions during directional solidifications. With the heat flux input/extraction from boundaries, coupling with latent heat release and initial temperature gradient, temperature distributions are significantly changed, leading to solute diffusion changes during the phase-transition. Thus, irregular columnar structures are formed during the directional solidification, and the concentration distribution in solid columnar arms could also be changed due to the different growing speeds and temperature distributions at the solid-liquid interfaces. Therefore, applying specific heat conditions at the solidifying boundaries could be an efficient way to control the microstructure during solidifications.
Fred L. Tobiason; Stephen S. Kelley; M. Mark Midland; Richard W. Hemingway
1997-01-01
The pyran ring proton coupling constants for (+)-catechin have been experimentally determined in deuterated methanol over a temperature range of 213 K to 313 K. The experimental coupling constants were simulated to 0.04 Hz on the average at a 90 percent confidence limit using a LAOCOON method. The temperature dependence of the coupling constants was reproduced from the...
Surface alteration and physical properties of glass from the Cretaceous-Tertiary boundary
Barkatt, A.; Sang, J.C.; Thorpe, A.N.; Senftle, F.E.; Talmy, I.G.; Norr, M.K.; Mazer, J.J.; Izett, G.; Sigurdsson, Haraldur
1994-01-01
The scalloped surface feature on Cretaceous-Tertiary boundary glass is often explained as being due to terrestrial aqueous leaching. Leaching of man-made glass results in a reduction in density of the glass. Also, Fe, because of its relative insolubility, is concentrated by the leaching process. Thus, the Haitian glass specimens which have been heavily altered should have a thin rim of less dense glass in which the Fe is concentrated compared to the core glass. The higher Fe concentration in the rim glass should cause it to have an enhanced Curie constant and a lower density compared to the unaltered glass. The magnetic Curie constant, density, and scanning electron microscopic studies were made on altered specimens of Haitian glass and also on specimens showing a minimum of alteration. The results show that the less altered samples have the highest density and the lowest Curie constant. The data substantiate the terrestrial hypothesis. ?? 1994.
NASA Technical Reports Server (NTRS)
Nordstrom, Jan; Carpenter, Mark H.
1998-01-01
Boundary and interface conditions for high order finite difference methods applied to the constant coefficient Euler and Navier-Stokes equations are derived. The boundary conditions lead to strict and strong stability. The interface conditions are stable and conservative even if the finite difference operators and mesh sizes vary from domain to domain. Numerical experiments show that the new conditions also lead to good results for the corresponding nonlinear problems.
Fernández, A S; Larsen, M; Wolstrup, J; Grønvold, J; Nansen, P; Bjørn, H
1999-08-01
The effect of temperature on radial growth and predatory activity of different isolates of nematode-trapping fungi was assessed. Four isolates of Duddingtonia flagrans and one isolate of Arthrobotrys oligospora were inoculated on petri dishes containing either cornmeal agar (CMA) or faecal agar and then incubated for 14 days under three different constant and fluctuating temperature regimes. The radial growth was similar on the two substrates at each temperature regime. All fungal isolates showed a higher growth rate at a constant 20 degrees C. At 10 degrees and 15 degrees C, all D. flagrans isolates showed very similar patterns of radial growth at both constant and fluctuating temperatures. At 20 degrees C, they grew significantly faster at constant than at fluctuating temperatures. A. oligospora grew significantly faster than all D. flagrans isolates except when incubated at a fluctuating 20 degrees C. Spores of each fungal isolate were added to faecal cultures containing eggs of Cooperia oncophora at a concentration of 6250 spores/g faeces. The cultures were incubated for 14 days at the same temperature regimes described above. Control faeces (without fungal material) were also cultured. More larvae were recovered from the fungus-treated cultures incubated at a constant 10 degrees or 15 degrees C than from those incubated at the respective fluctuating temperatures, except for one D. flagrans isolate. Incubation at 20 degrees C showed the opposite effect. The general reduction observed in the number of nematode larvae due to fungal trapping was 18-25% and 48-80% for a constant and fluctuating 10 degrees C, 70-96% and 93-95% for a constant and fluctuating 15 degrees C, and 63-98% and 0-25% for a constant and fluctuating 20 degrees C, respectively.
Determination of Henry’s Law Constants Using Internal Standards with Benchmark Values
It is shown that Henry’s law constants can be experimentally determined by comparing headspace content of compounds with known constants to interpolate the constants of other compounds. Studies were conducted over a range of water temperatures to identify temperature dependence....
Dielectric studies on PEG-LTMS based polymer composites
NASA Astrophysics Data System (ADS)
Patil, Ravikumar V.; Praveen, D.; Damle, R.
2018-02-01
PEG LTMS based polymer composites were prepared and studied for dielectric constant variation with frequency and temperature as a potential candidate with better dielectric properties. Solution cast technique is used for the preparation of polymer composite with five different compositions. Samples show variation in dielectric constant with frequency and temperature. Dielectric constant is large at low frequencies and higher temperatures. Samples with larger space charges have shown larger dielectric constant. The highest dielectric constant observed was about 29244 for PEG25LTMS sample at 100Hz and 312 K.
NASA Technical Reports Server (NTRS)
Kurylo, M. J.; Cornett, K. D.; Murphy, J. L.
1982-01-01
The rate constant for the reaction of hydroxyl radicals with nitric acid in the 225-443 K temperature range has been measured by means of the flash photolysis resonance fluorescence technique. Above 300 K, the rate constant levels off in a way that can only be explained by the occurrence of two reaction channels, of which one, operative at low temperatures, proceeds through the formation of an adduct intermediate. The implications of these rate constant values for stratospheric reaction constants is discussed.
Temperature measurement in a gas turbine engine combustor
DOE Office of Scientific and Technical Information (OSTI.GOV)
DeSilva, Upul
A method and system for determining a temperature of a working gas passing through a passage to a turbine section of a gas turbine engine. The method includes identifying an acoustic frequency at a first location in the engine upstream from the turbine section, and using the acoustic frequency for determining a first temperature value at the first location that is directly proportional to the acoustic frequency and a calculated constant value. A second temperature of the working gas is determined at a second location in the engine and, using the second temperature, a back calculation is performed to determinemore » a temperature value for the working gas at the first location. The first temperature value is compared to the back calculated temperature value to change the calculated constant value to a recalculated constant value. Subsequent first temperature values at the first location may be determined based on the recalculated constant value.« less
NASA Technical Reports Server (NTRS)
Cacio, Emanuela; Cohn, Stephen E.; Spigler, Renato
2011-01-01
A numerical method is devised to solve a class of linear boundary-value problems for one-dimensional parabolic equations degenerate at the boundaries. Feller theory, which classifies the nature of the boundary points, is used to decide whether boundary conditions are needed to ensure uniqueness, and, if so, which ones they are. The algorithm is based on a suitable preconditioned implicit finite-difference scheme, grid, and treatment of the boundary data. Second-order accuracy, unconditional stability, and unconditional convergence of solutions of the finite-difference scheme to a constant as the time-step index tends to infinity are further properties of the method. Several examples, pertaining to financial mathematics, physics, and genetics, are presented for the purpose of illustration.
NASA Astrophysics Data System (ADS)
Chougule, Abhijit; Mann, Jakob; Kelly, Mark; Larsen, Gunner C.
2018-06-01
A spectral-tensor model of non-neutral, atmospheric-boundary-layer turbulence is evaluated using Eulerian statistics from single-point measurements of the wind speed and temperature at heights up to 100 m, assuming constant vertical gradients of mean wind speed and temperature. The model has been previously described in terms of the dissipation rate ɛ , the length scale of energy-containing eddies L, a turbulence anisotropy parameter Γ, the Richardson number Ri, and the normalized rate of destruction of temperature variance η _θ ≡ ɛ _θ /ɛ . Here, the latter two parameters are collapsed into a single atmospheric stability parameter z / L using Monin-Obukhov similarity theory, where z is the height above the Earth's surface, and L is the Obukhov length corresponding to Ri,η _θ. Model outputs of the one-dimensional velocity spectra, as well as cospectra of the streamwise and/or vertical velocity components, and/or temperature, and cross-spectra for the spatial separation of all three velocity components and temperature, are compared with measurements. As a function of the four model parameters, spectra and cospectra are reproduced quite well, but horizontal temperature fluxes are slightly underestimated in stable conditions. In moderately unstable stratification, our model reproduces spectra only up to a scale ˜ 1 km. The model also overestimates coherences for vertical separations, but is less severe in unstable than in stable cases.
NASA Technical Reports Server (NTRS)
Wang, W. C.; Stone, P. H.
1979-01-01
The feedback between ice snow albedo and temperature is included in a one dimensional radiative convective climate model. The effect of this feedback on sensitivity to changes in solar constant is studied for the current values of the solar constant and cloud characteristics. The ice snow albedo feedback amplifies global climate sensitivity by 33% and 50%, respectively, for assumptions of constant cloud altitude and constant cloud temperature.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lehtikangas, O., E-mail: Ossi.Lehtikangas@uef.fi; Tarvainen, T.; Department of Computer Science, University College London, Gower Street, London WC1E 6BT
2015-02-01
The radiative transport equation can be used as a light transport model in a medium with scattering particles, such as biological tissues. In the radiative transport equation, the refractive index is assumed to be constant within the medium. However, in biomedical media, changes in the refractive index can occur between different tissue types. In this work, light propagation in a medium with piece-wise constant refractive index is considered. Light propagation in each sub-domain with a constant refractive index is modeled using the radiative transport equation and the equations are coupled using boundary conditions describing Fresnel reflection and refraction phenomena onmore » the interfaces between the sub-domains. The resulting coupled system of radiative transport equations is numerically solved using a finite element method. The approach is tested with simulations. The results show that this coupled system describes light propagation accurately through comparison with the Monte Carlo method. It is also shown that neglecting the internal changes of the refractive index can lead to erroneous boundary measurements of scattered light.« less
NASA Astrophysics Data System (ADS)
Turner, John; Wosnik, Martin
2015-11-01
Results from an experimental study of an array of up to 100 model wind turbines with 0.25 m diameter are reported. The study was conducted in the UNH Flow Physics Facility (FPF), which has test section dimensions of 6.0 m wide, 2.7 m high and 72.0 m long. For a given configuration (spacing, initial conditions, etc.), the model wind farm reaches a ``fully developed'' condition, in which turbulence statistics remain the same from one row to the next within and above the wind turbine array. Of interest is the transport of kinetic energy within the wind turbine array boundary layer (WTABL). Model wind farms of up to 20 rows are possible in the FPF at the wind turbine scale used. The present studies in the FPF are able to achieve the fully developed WTABL condition, which can provide valuable insight to the optimization of wind farm energy production. The FPF can achieve a boundary layer height on the order of 1 m at the beginning of the wind turbine array. The wind turbine array was constructed of porous disks, which where drag (thrust) matched to wind turbines at typical operating conditions and therefore act as momentum sinks similar to wind turbines. The flow in the WTABL was measured with constant temperature anemometry using an X-wire.
Stokes-Einstein relation for pure simple fluids.
Cappelezzo, M; Capellari, C A; Pezzin, S H; Coelho, L A F
2007-06-14
The authors employed the equilibrium molecular dynamics technique to calculate the self-diffusion coefficient and the shear viscosity for simple fluids that obey the Lennard-Jones 6-12 potential in order to investigate the validity of the Stokes-Einstein (SE) relation for pure simple fluids. They performed calculations in a broad range of density and temperature in order to test the SE relation. The main goal of this work is to exactly calculate the constant, here denominated by alpha, present in the SE relation. Also, a modified SE relation where a fluid density is raised to a power in the usual expression is compared to the classical expression. According to the authors' simulations slip boundary conditions (alpha=4) can be satisfied in some state points. An intermediate value of alpha=5 was found in some regions of the phase diagram confirming the mode coupling theory. In addition depending on the phase diagram point and the definition of hydrodynamics radius, stick boundary condition (alpha=6) can be reproduced. The authors investigated the role of the hydrodynamic radius in the SE relation using three different definitions. The authors also present calculations for alpha in a hard-sphere system showing that the slip boundary conditions hold at very high density. They discuss possible explanations for their results and the role of the hydrodynamic radius for different definitions in the SE relation.
Temperature dependence of the dynamics of zone boundary phonons in ZnO:Li
NASA Astrophysics Data System (ADS)
Yadav, Harish Kumar; Sreenivas, K.; Gupta, Vinay; Katiyar, R. S.
2008-12-01
Investigations of zone boundary phonons in ZnO:Li system (Li concentration: 10%) and their dynamics with temperature are reported. Additional modes at 127, 157, and 194 cm-1 are observed and assigned to zone boundary phonons at critical point M in the Brillouin zone [J. M. Calleja and M. Cardona, Phys. Rev. B 16, 3753 (1977)] due to breakdown of crystal translational symmetry with Li incorporation in ZnO. Anharmonicity in peak frequency and linewidth of the zone boundary phonons in a temperature range from 100 to 1000 K is also analyzed taking into account the decay of zone boundary phonons into three- and four-phonon modes (cubic and quadratic anharmonicities). The anharmonic behavior of peak frequency is found to be feebly dependent on three-phonon decay process but thermal expansion of lattice together with four-phonon decay process appropriately defines the temperature dependence. Linewidths, however, follow the simple four-phonon decay mechanism. E2(low) mode, on the other hand, shows a linear temperature dependency and therefore follows a three-phonon decay channel. The calculated values of phonon lifetimes at 100 K for the 127, 157, 194 cm-1, and E2(low) modes are 8.23, 6.54, 5.32, and 11.39 ps. Decay of the zone boundary phonon modes compared to E2(low) mode reveals that dopant induced disorder has a strong temperature dependency.
NASA Astrophysics Data System (ADS)
Di Girolamo, Paolo; Cacciani, Marco; Summa, Donato; Scoccione, Andrea; De Rosa, Benedetto; Behrendt, Andreas; Wulfmeyer, Volker
2017-01-01
Measurements carried out by the University of Basilicata Raman lidar system (BASIL) are reported to demonstrate the capability of this instrument to characterise turbulent processes within the convective boundary layer (CBL). In order to resolve the vertical profiles of turbulent variables, high-resolution water vapour and temperature measurements, with a temporal resolution of 10 s and vertical resolutions of 90 and 30 m, respectively, are considered. Measurements of higher-order moments of the turbulent fluctuations of water vapour mixing ratio and temperature are obtained based on the application of autocovariance analyses to the water vapour mixing ratio and temperature time series. The algorithms are applied to a case study (11:30-13:30 UTC, 20 April 2013) from the High Definition Clouds and Precipitation for Climate Prediction (HD(CP)2) Observational Prototype Experiment (HOPE), held in western Germany in the spring 2013. A new correction scheme for the removal of the elastic signal crosstalk into the low quantum number rotational Raman signal is applied. The noise errors are small enough to derive up to fourth-order moments for both water vapour mixing ratio and temperature fluctuations.To the best of our knowledge, BASIL is the first Raman lidar with a demonstrated capability to simultaneously retrieve daytime profiles of water vapour turbulent fluctuations up to the fourth order throughout the atmospheric CBL. This is combined with the capability of measuring daytime profiles of temperature fluctuations up to the fourth order. These measurements, in combination with measurements from other lidar and in situ systems, are important for verifying and possibly improving turbulence and convection parameterisation in weather and climate models at different scales down to the grey zone (grid increment ˜ 1 km; Wulfmeyer et al., 2016).For the considered case study, which represents a well-mixed and quasi-stationary CBL, the mean boundary layer height is found to be 1290 ± 75 m above ground level (a.g.l.). Values of the integral scale for water vapour and temperature fluctuations at the top of the CBL are in the range of 70-125 and 75-225 s, respectively; these values are much larger than the temporal resolution of the measurements (10 s), which testifies that the temporal resolution considered for the measurements is sufficiently high to resolve turbulent processes down to the inertial subrange and, consequently, to resolve the major part of the turbulent fluctuations. Peak values of all moments are found in the interfacial layer in the proximity of the top of the CBL. Specifically, water vapour and temperature second-order moments (variance) have maximum values of 0.29 g2 kg-2 and 0.26 K2; water vapour and temperature third-order moments have peak values of 0.156 g3 kg-3 and -0.067 K3, while water vapour and temperature fourth-order moments have maximum values of 0.28 g4 kg-4 and 0.24 K4. Water vapour and temperature kurtosis have values of ˜ 3 in the upper portion of the CBL, which indicate normally distributed humidity and temperature fluctuations. Reported values of the higher-order moments are in good agreement with previous measurements at different locations, thus providing confidence in the possibility of using these measurements for turbulence parameterisation in weather and climate models.In the determination of the temperature profiles, particular care was dedicated to minimise potential effects associated with elastic signal crosstalk on the rotational Raman signals. For this purpose, a specific algorithm was defined and tested to identify and remove the elastic signal crosstalk and to assess the residual systematic uncertainty affecting temperature measurements after correction. The application of this approach confirms that, for the present Raman lidar system, the crosstalk factor remains constant with time; consequently an appropriate assessment of its constant value allows for a complete removal of the leaking elastic signal from the rotational Raman lidar signals at any time (with a residual error on temperature measurements after correction not exceeding 0.18 K).
Boundary effects in a quasi-two-dimensional driven granular fluid.
Smith, N D; Smith, M I
2017-12-01
The effect of a confining boundary on the spatial variations in granular temperature of a driven quasi-two-dimensional layer of particles is investigated experimentally. The radial drop in the relative granular temperature ΔT/T exhibits a maximum at intermediate particle numbers which coincides with a crossover from kinetic to collisional transport of energy. It is also found that at low particle numbers, the distributions of radial velocities are increasingly asymmetric as one approaches the boundary. The radial and tangential granular temperatures split, and in the tails of the radial velocity distribution there is a higher population of fast moving particles traveling away rather than towards the boundary.
NASA Astrophysics Data System (ADS)
Hui, Jun; Feng, Zaixin; Fan, Wenxin; Wang, Pengfei
2018-04-01
Cu-Sn alloy was subjected to elevated-temperature isothermal compression with 0.01 s‑1 strain rate and 500 ∼ 700 °C temperature range. The thermal compression curve reflected a competing process of work hardening versus dynamic recovery (DRV) and recrystallization, which exhibited an obvious softening trend. Meanwhile, high-temperature deformation and microstructural features in different regions of the alloy was analyzed through EBSD. The results show that grains grow as the temperature rises, competition among recrystallization, substructural, and deformation regions tends to increase with the increase of temperature, and distribution frequency of recrystallization regions gradually increases and then drops suddenly at 650 °C. At 500 ∼ 550 °C, preferentially oriented texturing phenomenon occurs, low angle boundaries(LABs) are gradually transformed into high angle boundaries (HABs) and the Σ (CSL) boundaries turn gradually into Σ3 boundaries. In tensile test of tin bronze, elongation at break increases slowly, whereas yield strength (YS) and ultimate tensile strength (TS) decrease gradually.
NASA Technical Reports Server (NTRS)
Mcronald, A. D.
1975-01-01
Mean density and temperature fluctuations were measured across the turbulent, cooled-wall boundary layer in a continuous hypersonic (Mach 9.4) wind tunnel in air, using the nitrogen fluorescence excited by a 50 kV electron beam. Data were taken at three values of the tunnel stagnation pressure, the corresponding free stream densities being equivalent to 1.2, 4.0, and 7.4 torr at room temperature, and the boundary layer thicknesses about 4.0, 4.5, and 6.0 inches. The mean temperature and density profiles were similar to those previously determined in the same facility by conventional probes (static and pitot pressure, total temperature). A static pressure variation of about 50% across the boundary layer was found, the shape of the variation changing somewhat for the three stagnation pressure levels. The quadrupole model for rotational temperature spectra gave closer agreement with the free stream isentropic level (approximately 44 K) than the dipole model.
NASA Astrophysics Data System (ADS)
Chen, Hansheng; Yun, Fan; Qu, Jiangtao; Li, Yingfei; Cheng, Zhenxiang; Fang, Ruhao; Ye, Zhixiao; Ringer, Simon P.; Zheng, Rongkun
2018-05-01
Quantitative correlation between intrinsic coercivity and grain boundaries in three dimensions is critical to further improve the performance of sintered Nd-Fe-B permanent magnets. Here, we quantitatively reveal the local composition variation across and especially along grain boundaries using the powerful atomic-scale analysis technique known as atom probe tomography. We also estimate the saturation magnetization, magnetocrystalline anisotropy constant, and exchange stiffness of the grain boundaries on the basis of the experimentally determined structure and composition. Finally, using micromagnetic simulations, we quantify the intrinsic coercivity degradation caused by inhomogeneous grain boundaries. This approach can be applied to other magnetic materials for the analysis and optimization of magnetic properties.
Three-peat NREL Intern Pushes Boundaries of Early-Stage Fuels Research on
Early-Stage Fuels Research on Way to Master's Degree Three-peat NREL Intern Pushes Boundaries of Early -Stage Fuels Research on Way to Master's Degree January 4, 2018 Woman preparing a fuel evaluation in a constant volume combustion vessel Drew Cameron, Research Participant Program Intern, prepares a test for
1982-03-01
observed coherent structure of the wall layer flow and will now be briefly described. Over the past decade, it has been well documented (see, for example...D2, and x are all arbitrary constants. Equilibrium flows have been examined experimentally for a number of years and an equilibrium boundary layer...CP93, Paper No. 27, 6. Clauser, F.H. (1954). "Turbulent Boundary Layers in Adverse Pressure Gradients", J. Aeronaut. Sci., 21, pp. 91-108. 7. Clauser
NASA Astrophysics Data System (ADS)
Longhurst, G. R.
1991-04-01
Gas evolution from spherical solids or liquids where no convective processes are active is analyzed. Three problem classes are considered: (1) constant concentration boundary, (2) Henry's law (first order) boundary, and (3) Sieverts' law (second order) boundary. General expressions are derived for dimensionless times and transport parameters appropriate to each of the classes considered. However, in the second order case, the non-linearities of the problem require the presence of explicit dimensional variables in the solution. Sample problems are solved to illustrate the method.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhang, Kezhao; Ni, Longchang; Lei, Zhenglong, E-ma
The tensile deformation behavior of laser welded Ti{sub 2}AlNb joints was investigated using in situ analysis methods. The fracture mode of the single-B2-phase fusion zone was quasi-cleavage at room temperature and intergranular at 650 °C, while that of base metal was microvoid coalescence at both room temperature and 650 °C. Tensile deformation at room temperature was observed using in situ SEM tensile testing. In base metal, microcracks nucleated and propagated mainly within the O phase or along O/B2 phase boundaries. While both the cross- and multi-slips were found in the single-B2-phase fusion zone, a confocal laser scanning microscopy was usedmore » to observe the crack initiation and propagation process in situ at 650 °C. Cracks mainly formed along the B2/O phase boundaries in base metal, along the fragile grain boundaries of B2 phase in the fusion zone. The thermal simulation experiment and following TEM analysis indicated that the precipitation of continuous O-phase films along the B2 grain boundaries resulted in the high temperature brittleness of laser welded Ti{sub 2}AlNb joints. - Highlights: •Cracks formed within O phase or along B2/O boundaries in the base metal. •Cross- and multi-slips relieved stress in the fusion zone at room temperature. •Cracks mainly formed along the B2/O boundaries at 650 °C. •In the fusion zone, intergranular cracks were in situ observed at 650 °C. •O-phase films along B2 grain boundaries caused the high temperature brittleness.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shyam, Amit; Lara-Curzio, Edgar
This paper reports on the langatate (LGT) elastic constants and their temperature coefficients measured from room temperature (25degC) to 1100degC using resonant ultrasound spectroscopy (RUS). The constants were extracted by iteratively fitting the resonant peaks with those calculated by Lagrangian mechanics at each temperature where the RUS measurements were taken. In addition, the RUS technique was used to extract the elastic and piezoelectric constants in the 25degC to 120degC temperature range. The extraction of LGT elastic constants up to 1100degC presented in this paper represents a critical step towards the design and fabrication of LGT acoustic wave devices for highmore » temperature and harsh environment applications.« less
Performance of U3Si2 Fuel in a Reactivity Insertion Accident
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cheng, Lap Y.; Cuadra, Arantxa; Todosow, Michael
In this study we examined the performance of the U3Si2 fuel cladded with Zircaloy (Zr) in a reactivity insertion accident (RIA) in a PWR core. The power excursion as a result of a $1 reactivity insertion was calculated by a TRACE PWR plant model using point-kinetics, for alternative cores with UO2 and U3Si2 fuel assemblies. The point-kinetics parameters (feedback coefficients, prompt-neutron lifetime and group constants for six delayed-neutron groups) were obtained from beginning-of-cycle equilibrium full core calculations with PARCS. In the PARCS core calculations, the few-group parameters were developed utilizing the TRITON/NEWT tools in the SCALE package. In order tomore » assess the fuel response in finer detail (e.g. the maximum fuel temperature) the power shape and thermal boundary conditions from the TRACE/PARCS calculations were used to drive a BISON model of a fuel pin with U3Si2 and UO2 respectively. For a $1 reactivity transient both TRACE and BISON predicted a higher maximum fuel temperature for the UO2 fuel than the U3Si2 fuel. Furthermore, BISON is noted to calculate a narrower gap and a higher gap heat transfer coefficient than TRACE. This resulted in BISON predicting consistently lower fuel temperatures than TRACE. This study also provides a systematic comparison between TRACE and BISON using consistent transient boundary conditions. The TRACE analysis of the RIA only reflects the core-wide response in power. A refinement to the analysis would be to predict the local peaking in a three-dimensional core as a result of control rod ejection.« less
Sverdlova, Nina S; Lambertz, Markus; Witzel, Ulrich; Perry, Steven F
2012-01-01
Various parts of the respiratory system play an important role in temperature control in birds. We create a simplified computational fluid dynamics (CFD) model of heat exchange in the trachea and air sacs of the domestic fowl (Gallus domesticus) in order to investigate the boundary conditions for the convective and evaporative cooling in these parts of the respiratory system. The model is based upon published values for respiratory times, pressures and volumes and upon anatomical data for this species, and the calculated heat exchange is compared with experimentally determined values for the domestic fowl and a closely related, wild species. In addition, we studied the trachea histologically to estimate the thickness of the heat transfer barrier and determine the structure and function of moisture-producing glands. In the transient CFD simulation, the airflow in the trachea of a 2-dimensional model is evoked by changing the volume of the simplified air sac. The heat exchange between the respiratory system and the environment is simulated for different ambient temperatures and humidities, and using two different models of evaporation: constant water vapour concentration model and the droplet injection model. According to the histological results, small mucous glands are numerous but discrete serous glands are lacking on the tracheal surface. The amount of water and heat loss in the simulation is comparable with measured respiratory values previously reported. Tracheal temperature control in the avian respiratory system may be used as a model for extinct or rare animals and could have high relevance for explaining how gigantic, long-necked dinosaurs such as sauropoda might have maintained a high metabolic rate.
The elevated temperature mechanical properties of silicon nitride/boron nitride fibrous monoliths
NASA Astrophysics Data System (ADS)
Trice, Rodney Wayne
A unique, all-ceramic material capable of non-brittle fracture via crack deflection has been characterized from 25sp°C through 1400sp°C. This material, called fibrous monoliths (FMs), was comprised of unidirectionally aligned 250 mum diameter cells of silicon nitride surrounded by 10 mum thick cell boundaries of boron nitride. Six weight percent yttria and two weight percent alumina were added to the silicon nitride to aid in densification. TEM experiments revealed that the sintering aids used to densify the silicon nitride cells were migrating into the boron nitride cell boundary during hot-pressing and that a fine network of micro-cracks existed between basal planes of boron nitride. Elevated temperature four point bending tests were performed on fibrous monolith ceramics from room temperature through 1400sp°C. Peak strengths of FMs averaged 510 MPa for specimens tested at room temperature through 176 MPa at 1400sp°C. Work of fractures ranged from 7300 J/msp2 to 3200 J/msp2 under the same temperature conditions. The interfacial fracture energy of boron nitride, GammasbBN, as a function of temperature has been determined using the Charalambides method. The fracture energy of boron nitride is approximately 40 J/msp2 and remained constant from 25sp°C through 950sp°C. A sharp increase in GammasbBN, to about 60 J/msp2, was observed at 1000sp°C-1050sp°C. This increase in GammasbBN was attributed to interactions of the crack tip with the cell boundary glassy phase. Subsequent measurements at 1075sp°C indicated a marked decrease in GammasbBN to near 40 J/msp2 before plateauing at 17-20 J/msp2 in the 1200sp°C-1300sp°C regime. The Mode I fracture toughness of silicon nitride was also determined using the single edge precracked beam method as a function of temperature. The He and Hutchinson model relating crack deflection at an interface to the Dundurs' parameter was applied to the current data set using the temperature dependent fracture energies of the boron nitride and the silicon nitride. A more refractory fibrous monolith was fabricated in an effort to extend the high temperature properties of SN/BN fibrous monoliths. Only 4 wt.% yttria was added to the silicon nitride to aid in densification. The presence of residual carbon following binder burnout was proposed to be responsible for the formation of melilite, a phase known to undergo severe oxidation between 900sp°C-1100sp°C. When residual carbon was removed prior to hot-pressing with a post-binder burnout heat treatment at 400sp°C in air this phase was not present. A room temperature strength of 553 MPa and a work of fracture of 6700 J/msp2 was observed. A strength of 293 MPa was measured at 1400sp°C.