Ambient-temperature co-oxidation catalysts

NASA Technical Reports Server (NTRS)

Upchurch, Billy T.; Schryer, David R.; Brown, Kenneth G.; Kielin, Erik J.

1991-01-01

Oxidation catalysts which operate at ambient temperature were developed for the recombination of carbon monoxide (CO) and oxygen (O2) dissociation products which are formed during carbon dioxide (CO2) laser operation. Recombination of these products to regenerate CO2 allows continuous operation of CO2 lasers in a closed cycle mode. Development of these catalyst materials provides enabling technology for the operation of such lasers from space platforms or in ground based facilities without constant gas consumption required for continuous open cycle operation. Such catalysts also have other applications in various areas outside the laser community for removal of CO from other closed environments such as indoor air and as an ambient temperature catalytic converter for control of auto emissions.

A high-performance constant-temperature hot-wire anemometer

NASA Technical Reports Server (NTRS)

Watmuff, Jonathan H.

1994-01-01

A high-performance constant-temperature hot-wire anemometer has been designed based on a system theory analysis that can be extended to arbitrary order. A motivating factor behind the design was to achieve the highest possible frequency response while ensuring overall system stability. Based on these considerations, the design of the circuit and the selection of components is discussed in depth. Basic operating instructions are included in an operator's guide. The analysis is used to identify operating modes, observed in all anemometers, that are misleading in the sense that the operator can be deceived by interpreting an erroneous frequency response. Unlike other anemometers, this instrument provides front panel access to all the circuit parameters which affect system stability and frequency response. Instructions are given on how to identify and avoid these rather subtle and undesirable operating modes by appropriate adjustment of the controls. Details, such as fabrication drawings and a parts list, are provided to enable others to construct the instrument.

Study of the structure of turbulent shear flows at supersonic speeds and high Reynolds number

NASA Technical Reports Server (NTRS)

Smits, A. J.; Bogdonoff, S. M.

1984-01-01

A major effort to improve the accuracies of turbulence measurement techniques is described including the development and testing of constant temperature hot-wire anemometers which automatically compensate for frequency responses. Calibration and data acquisition techniques for normal and inclined wires operated in the constant temperature mode, flow geometries, and physical models to explain the observed behavior of flows are discussed, as well as cooperation with computational groups in the calculation of compression corner flows.

Low temperature ion source for calutrons

DOEpatents

Veach, Allen M.; Bell, Jr., William A.; Howell, Jr., George D.

1981-01-01

A new ion source assembly for calutrons has been provided for the efficient separation of elements having high vapor pressures. The strategic location of cooling pads and improved insulation permits operation of the source at lower temperatures. A vapor valve constructed of graphite and located in a constantly increasing temperature gradient provides reliable control of the vapor flow from the charge bottle to the arc chamber. A pronounced saving in calutron operating time and equipment maintenance has been achieved with the use of the present ion source.

Low temperature ion source for calutrons

DOEpatents

Veach, A.M.; Bell, W.A. Jr.; Howell, G.D. Jr.

1979-10-10

A new ion source assembly for calutrons has been provided for the efficient separation of elements having high vapor pressures. The strategic location of cooling pads and improved insulation permits operation of the source at lower temperatures. A vapor valve constructed of graphite and located in a constantly increasing temperature gradient provides reliable control of the vapor flow from the charge bottle to the arc chamber. A pronounced saving in calutron operating time and equipment maintenance has been achieved with the use of the present ion source.

Microgravity

NASA Image and Video Library

1992-10-01

MSFC Test Engineer performing a functional test on the TES. The TES can be operated as a refrigerator, with a minimum set point temperature of 4.0 degrees C, or as an incubator, with a maximum set point temperature 40.0 degrees C of the set point. The TES can be set to maintain a constant temperature or programmed to change temperature settings over time, internal temperature recorded by a date logger.

Pressure-Drop Considerations in the Characterization of Dew-Point Transfer Standards at High Temperatures

NASA Astrophysics Data System (ADS)

Mitter, H.; Böse, N.; Benyon, R.; Vicente, T.

2012-09-01

During calibration of precision optical dew-point hygrometers (DPHs), it is usually necessary to take into account the pressure drop induced by the gas flow between the "point of reference" and the "point of use" (mirror or measuring head of the DPH) either as a correction of the reference dew-point temperature or as part of the uncertainty estimation. At dew-point temperatures in the range of ambient temperature and below, it is sufficient to determine the pressure drop for the required gas flow, and to keep the volumetric flow constant during the measurements. In this case, it is feasible to keep the dry-gas flow into the dew-point generator constant or to measure the flow downstream the DPH at ambient temperature. In normal operation, at least one DPH in addition to the monitoring DPH are used, and this operation has to be applied to each instrument. The situation is different at high dew-point temperatures up to 95 °C, the currently achievable upper limit reported in this paper. With increasing dew-point temperatures, the reference gas contains increasing amounts of water vapour and a constant dry-gas flow will lead to a significant enhanced volume flow at the conditions at the point of use, and therefore, to a significantly varying pressure drop depending on the applied dew-point temperature. At dew-point temperatures above ambient temperature, it is also necessary to heat the reference gas and the mirror head of the DPH sufficiently to avoid condensation which will additionally increase the volume flow and the pressure drop. In this paper, a method is provided to calculate the dry-gas flow rate needed to maintain a known wet-gas flow rate through a chilled mirror for a range of temperature and pressures.

Functional Test on (TES) Thermal Enclosure System

NASA Technical Reports Server (NTRS)

1992-01-01

MSFC Test Engineer performing a functional test on the TES. The TES can be operated as a refrigerator, with a minimum set point temperature of 4.0 degrees C, or as an incubator, with a maximum set point temperature 40.0 degrees C of the set point. The TES can be set to maintain a constant temperature or programmed to change temperature settings over time, internal temperature recorded by a date logger.

Alpha-ray spectrometry at high temperature by using a compound semiconductor detector.

PubMed

Ha, Jang Ho; Kim, Han Soo

2013-11-01

The use of conventional radiation detectors in harsh environments is limited by radiation damage to detector materials and by temperature constraints. We fabricated a wide-band gap semiconductor radiation detector based on silicon carbide. All the detector components were considered for an application in a high temperature environment like a nuclear reactor core. The radiation response, especially to alpha particles, was measured using an (241)Am source at variable operating voltages at room temperature in the air. The temperature on detector was controlled from 30°C to 250°C. The alpha-particle spectra were measured at zero bias operation. Even though the detector is operated at high temperature, the energy resolution as a function of temperature is almost constant within 3.5% deviation. Copyright © 2013 Elsevier Ltd. All rights reserved.

New constant-temperature operating mode for graphite calorimeter at LNE-LNHB.

PubMed

Daures, J; Ostrowsky, A

2005-09-07

The realization of the unit of absorbed dose at LNE-LNHB is based on calorimetry with the present GR8 graphite calorimeter. For this reason the calorimetric technique must be maintained, developed and improved in the laboratory. The usual quasi-adiabatic operating mode at LNHB is based on the thermal feedback between the core (sensitive element) and the jacket (adjacent body). When a core-jacket temperature difference is detected, a commercially available analogue PID (Proportional, Integral, Derivative) controller sends to the jacket an amount of electrical power to reduce this difference. Nevertheless, the core and jacket temperatures increase with irradiations and electrical calibrations whereas the surrounding is maintained at a fixed temperature to shield against the room temperature variations. At radiotherapy dose rates, fewer than ten measurements, or electrical calibrations, per day can be performed. This paper describes the new constant-temperature operating mode which has been implemented recently to improve flexibility in use and, to some extent, accuracy. The core and the jacket temperatures are maintained at fixed temperatures. A steady state is achieved without irradiation. Then, under irradiation, the electrical power needed to maintain the assigned temperature in the core is reduced by the amount of heat generated by ionizing radiation. The difference between these electrical powers, without and with irradiation, gives the mean absorbed dose rate to the core. The quality of this electrical power substitution measurement is strongly dependent upon the quality of the core and jacket thermal control. The core temperature is maintained at the set value using a digital PID regulator developed at the laboratory with LabView software on PC for this purpose. This regulator is versatile and particularly well suited for calorimetry purposes. Measurements in a cobalt-60 beam have shown no significant difference (<0.09%) between the two operating modes, with an equivalent reproducibility (1sigma < 0.06%). These results corroborate the negligible difference of heat transfer between steady and irradiation periods when working in quasi-adiabatic mode with thermal feedback between the core and the jacket. The new constant-temperature mode allows numerous and fully automated measurements. The electrical calibration is an integral part of the measurement; no extra runs are needed. It also allows faster thermal equilibrium before starting runs. Moreover the quality of vacuum within the gaps between the bodies is less important.

Heating rates in furnace atomic absorption using the L'vov platform

USGS Publications Warehouse

Koirtyohann, S.R.; Giddings, R.C.; Taylor, Howard E.

1984-01-01

Heating rate profiles for the furnace tube wall, the furnace atmosphere, and a L'vov platform were established for a range of conditions in a cyclically heated graphite atomizer. The tube wall profile was made by direct observation with a recording optical pyrometer. The sodium line reversal method was used to establish the heating rate of the furnace atmosphere, and appearance temperatures for a series metals of differing volatility was used to establish platform profiles. The tube wall heating rate was nearly linear at 2240??C s- until the desired temperature was reached after which the temperature remained constant. The furnace atmosphere reached a given temperature 0.2-0.4 s later than the tube wall through most of the atomize cycle. The platform lagged the tube wall 0.5-0.8 s. Under typical operating conditions the furnace atmosphere was 100-200??C cooler than the tube wall and at nearly constant temperature when the analyte vaporized from the platform. The L'vov platform causes the cyclically heated commercial furnace to approximate the behavior of a constant temperature furnace during atomization. ?? 1984.

Feasibility study of solid oxide fuel cell engines integrated with sprinter gas turbines: Modeling, design and control

NASA Astrophysics Data System (ADS)

Jia, Zhenzhong; Sun, Jing; Dobbs, Herb; King, Joel

2015-02-01

Conventional recuperating solid oxide fuel cell (SOFC)/gas turbine (GT) system suffers from its poor dynamic capability and load following performance. To meet the fast, safe and efficient load following requirements for mobile applications, a sprinter SOFC/GT system concept is proposed in this paper. In the proposed system, an SOFC stack operating at fairly constant temperature provides the baseline power with high efficiency while the fast dynamic capability of the GT-generator is fully explored for fast dynamic load following. System design and control studies have been conducted by using an SOFC/GT system model consisting of experimentally-verified component models. In particular, through analysis of the steady-state simulation results, an SOFC operation strategy is proposed to maintain fairly constant SOFC power (less than 2% power variation) and temperature (less than 2 K temperature variation) over the entire load range. A system design procedure well-suited to the proposed system has also been developed to help determining component sizes and the reference steady-state operation line. In addition, control analysis has been studied for both steady-state and transient operations. Simulation results suggest that the proposed system holds the promise to achieve fast and safe transient operations by taking full advantage of the fast dynamics of the GT-generator.

Comparison of two total energy systems for a diesel power generation plant. [deep space network

NASA Technical Reports Server (NTRS)

Chai, V. W.

1979-01-01

The capabilities and limitations, as well as the associated costs for two total energy systems for a diesel power generation plant are compared. Both systems utilize waste heat from engine cooling water and waste heat from exhaust gases. Pressurized water heat recovery system is simple in nature and requires no engine modifications, but operates at lower temperature ranges. On the other hand, a two-phase ebullient system operates the engine at constant temperature, provides higher temperature water or steam to the load, but is more expensive.

Characterization of Full Set Material Constants and Their Temperature Dependence for Piezoelectric Materials Using Resonant Ultrasound Spectroscopy

PubMed Central

Tang, Liguo; Cao, Wenwu

2016-01-01

During the operation of high power electromechanical devices, a temperature rise is unavoidable due to mechanical and electrical losses, causing the degradation of device performance. In order to evaluate such degradations using computer simulations, full matrix material properties at elevated temperatures are needed as inputs. It is extremely difficult to measure such data for ferroelectric materials due to their strong anisotropic nature and property variation among samples of different geometries. Because the degree of depolarization is boundary condition dependent, data obtained by the IEEE (Institute of Electrical and Electronics Engineers) impedance resonance technique, which requires several samples with drastically different geometries, usually lack self-consistency. The resonant ultrasound spectroscopy (RUS) technique allows the full set material constants to be measured using only one sample, which can eliminate errors caused by sample to sample variation. A detailed RUS procedure is demonstrated here using a lead zirconate titanate (PZT-4) piezoceramic sample. In the example, the complete set of material constants was measured from room temperature to 120 °C. Measured free dielectric constants and  were compared with calculated ones based on the measured full set data, and piezoelectric constants d15 and d33 were also calculated using different formulas. Excellent agreement was found in the entire range of temperatures, which confirmed the self-consistency of the data set obtained by the RUS. PMID:27168336

Time dependent temperature distribution in pulsed Ti:sapphire lasers

NASA Technical Reports Server (NTRS)

Buoncristiani, A. Martin; Byvik, Charles E.; Farrukh, Usamah O.

1988-01-01

An expression is derived for the time dependent temperature distribution in a finite solid state laser rod for an end-pumped beam of arbitrary shape. The specific case of end pumping by circular (constant) or Gaussian beam is described. The temperature profile for a single pump pulse and for repetitive pulse operation is discussed. The particular case of the temperature distribution in a pulsed titanium:sapphire rod is considered.

Fully Electrical Modeling of Thermoelectric Generators with Contact Thermal Resistance Under Different Operating Conditions

NASA Astrophysics Data System (ADS)

Siouane, Saima; Jovanović, Slaviša; Poure, Philippe

2017-01-01

The Seebeck effect is used in thermoelectric generators (TEGs) to supply electronic circuits by converting the waste thermal into electrical energy. This generated electrical power is directly proportional to the temperature difference between the TEG module's hot and cold sides. Depending on the applications, TEGs can be used either under constant temperature gradient between heat reservoirs or constant heat flow conditions. Moreover, the generated electrical power of a TEG depends not only on these operating conditions, but also on the contact thermal resistance. The influence of the contact thermal resistance on the generated electrical power have already been extensively reported in the literature. However, as reported in Park et al. (Energy Convers Manag 86:233, 2014) and Montecucco and Knox (IEEE Trans Power Electron 30:828, 2015), while designing TEG-powered circuit and systems, a TEG module is mostly modeled with a Thévenin equivalent circuit whose resistance is constant and voltage proportional to the temperature gradient applied to the TEG's terminals. This widely used simplified electrical TEG model is inaccurate and not suitable under constant heat flow conditions or when the contact thermal resistance is considered. Moreover, it does not provide realistic behaviour corresponding to the physical phenomena taking place in a TEG. Therefore, from the circuit designer's point of view, faithful and fully electrical TEG models under different operating conditions are needed. Such models are mainly necessary to design and evaluate the power conditioning electronic stages and the maximum power point tracking algorithms of a TEG power supply. In this study, these fully electrical models with the contact thermal resistance taken into account are presented and the analytical expressions of the Thévenin equivalent circuit parameters are provided.

Accurate Measurements of the Dielectric Constant of Seawater at L Band

NASA Technical Reports Server (NTRS)

Lang, Roger H.; Utku, Cuneyt; Tarkocin, Yalcin; LeVine, David M.

2010-01-01

This report describes measurements of the dielectric constant of seawater at a frequency of 1.413 GHz that is at the center of the L-Sand radiometric protected frequency spectrum. Aquarius will be sensing the sea surface salinity from space in this band. The objective of the project is to refine the model function for the dielectric constant as a function of salinity and temperature so that remote sensing measurements can be made with the accuracy needed to meet the measurement goals (0.2 psu) of the Aquarius mission. The measurements were made, using a microwave cavity operated in the transmission configuration. The cavity's temperature was accurately regulated to 0.02 C by immersing it in a temperature controlled bath of distilled water and ethanol glycol. Seawater had been purchased from Ocean Scientific International Limited (OS1L) at salinities of 30, 35 and 38 psu. Measurements of these seawater samples were then made over a range of temperatures, from l0 C to 35 C in 5 C intervals. Repeated measurements were made at each temperature and salinity, Mean values and standard deviations were then computed. Total error budgets indicated that the real and imaginary parts of the dielectric constant had a relative accuracy of about l%.

Effect of Vaporizer Temperature on Ambient Non-Refractory Submicron Aerosol Composition and Mass Spectra Measured by the Aerosol Mass Spectrometer

EPA Science Inventory

Aerodyne Aerosol Mass Spectrometers (AMS) are routinely operated with a constant vaporizer temperature (Tvap) of 600^oC in order to facilitate quantitative detection of non-refractory submicron (NR-PM1) species. By analogy with other thermal desorption instrument...

Radiation Hardened Structured ASIC Platform with Compensation of Delay for Temperature and Voltage Variations for Multiple Redundant Temporal Voting Latch Technology

NASA Technical Reports Server (NTRS)

Ardalan, Sasan (Inventor)

2018-01-01

The invention relates to devices and methods of maintaining the current starved delay at a constant value across variations in voltage and temperature to increase the speed of operation of the sequential logic in the radiation hardened ASIC design.

Real Time Ferrograph Development.

DTIC Science & Technology

1979-11-01

differential temperature of 65 0 C. Since opteo- electronic devices (photodiodes, photoresistors, etc.) have a maximum operating temperature around 85 0 C, it is...flow during the precipitation cycle. This regulator must keep the flow rate constant at any given temperature regardless of the differential pressure...across the sensing head. The pressure regulator achieved this by using the differential pressure across a fixed re;7trictor to move a bellows diaphragm

Low-temperature creep of austenitic stainless steels

NASA Astrophysics Data System (ADS)

Reed, R. P.; Walsh, R. P.

2017-09-01

Plastic deformation under constant load (creep) in austenitic stainless steels has been measured at temperatures ranging from 4 K to room temperature. Low-temperature creep data taken from past and unreported austenitic stainless steel studies are analyzed and reviewed. Creep at cryogenic temperatures of common austenitic steels, such as AISI 304, 310 316, and nitrogen-strengthened steels, such as 304HN and 3116LN, are included. Analyses suggests that logarithmic creep (creep strain dependent on the log of test time) best describe austenitic stainless steel behavior in the secondary creep stage and that the slope of creep strain versus log time is dependent on the applied stress/yield strength ratio. The role of cold work, strain-induced martensitic transformations, and stacking fault energy on low-temperature creep behavior is discussed. The engineering significance of creep on cryogenic structures is discussed in terms of the total creep strain under constant load over their operational lifetime at allowable stress levels.

Thermal Modelling Analysis of Spiral Wound Supercapacitor under Constant-Current Cycling

PubMed Central

Wang, Kai; Li, Liwei; Yin, Huaixian; Zhang, Tiezhu; Wan, Wubo

2015-01-01

A three-dimensional modelling approach is used to study the effects of operating and ambient conditions on the thermal behaviour of the spiral wound supercapacitor. The transient temperature distribution during cycling is obtained by using the finite element method with an implicit predictor-multicorrector algorithm. At the constant current of 2A, the results show that the maximum temperature appears in core area. After 5 cycles, the maximum temperature is 34.5°C, while in steady state, it’s up to 42.5°C. This paper further studies the relationship between the maximum temperature and charge-discharge current. The maximum temperature will be more than 60°C after 5 cycles at the current of 4A, and cooling measurements should be taken at that time. It can provide thoughts on inner temperature field distribution and structure design of the spiral wound supercapacitor in working process. PMID:26444687

Active thermal isolation for temperature responsive sensors

NASA Technical Reports Server (NTRS)

Martinson, Scott D. (Inventor); Gray, David L. (Inventor); Carraway, Debra L. (Inventor); Reda, Daniel C. (Inventor)

1994-01-01

The detection of flow transition between laminar and turbulent flow and of shear stress or skin friction of airfoils is important in basic research for validation of airfoil theory and design. These values are conventionally measured using hot film nickel sensors deposited on a polyimide substrate. The substrate electrically insulates the sensor and underlying airfoil but is prevented from thermally isolating the sensor by thickness constraints necessary to avoid flow contamination. Proposed heating of the model surface is difficult to control, requires significant energy expenditures, and may alter the basic flow state of the airfoil. A temperature responsive sensor is located in the airflow over the specified surface of a body and is maintained at a constant temperature. An active thermal isolator is located between this temperature responsive sensor and the specific surface of the body. The total thickness of the isolator and sensor avoid any contamination of the flow. The temperature of this isolator is controlled to reduce conductive heat flow from the temperature responsive sensor to the body. This temperature control includes (1) operating the isolator at the same temperature as the constant temperature of the sensor; and (2) establishing a fixed boundary temperature which is either less than or equal to, or slightly greater than the sensor constant temperature. The present invention accordingly thermally isolates a temperature responsive sensor in an energy efficient, controllable manner while avoiding any contamination of the flow.

Microscopic theoretical study of frequency dependent dielectric constant of heavy fermion systems

NASA Astrophysics Data System (ADS)

Shadangi, Keshab Chandra; Rout, G. C.

2017-05-01

The dielectric polarization and the dielectric constant plays a vital role in the deciding the properties of the Heavy Fermion Systems. In the present communication we consider the periodic Anderson's Model which consists of conduction electron kinetic energy, localized f-electron kinetic energy and the hybridization between the conduction and localized electrons, besides the Coulomb correlation energy. We calculate dielectric polarization which involves two particle Green's functions which are calculated by using Zubarev's Green's function technique. Using the equations of motion of the fermion electron operators. Finally, the temperature and frequency dependent dielectric constant is calculated from the dielectric polarization function. The charge susceptibility and dielectric constant are computed numerically for different physical parameters like the position (Ef) of the f-electron level with respect to fermi level, the strength of the hybridization (V) between the conduction and localized f-electrons, Coulomb correlation potential temperature and optical phonon wave vector (q). The results will be discussed in a reference to the experimental observations of the dielectric constants.

Assessment of body mapping sportswear using a manikin operated in constant temperature mode and thermoregulatory model control mode

NASA Astrophysics Data System (ADS)

Wang, Faming; Del Ferraro, Simona; Molinaro, Vincenzo; Morrissey, Matthew; Rossi, René

2014-09-01

Regional sweating patterns and body surface temperature differences exist between genders. Traditional sportswear made from one material and/or one fabric structure has a limited ability to provide athletes sufficient local wear comfort. Body mapping sportswear consists of one piece of multiple knit structure fabric or of different fabric pieces that may provide athletes better wear comfort. In this study, the `modular' body mapping sportswear was designed and subsequently assessed on a `Newton' type sweating manikin that operated in both constant temperature mode and thermophysiological model control mode. The performance of the modular body mapping sportswear kit and commercial products were also compared. The results demonstrated that such a modular body mapping sportswear kit can meet multiple wear/thermal comfort requirements in various environmental conditions. All body mapping clothing (BMC) presented limited global thermophysiological benefits for the wearers. Nevertheless, BMC showed evident improvements in adjusting local body heat exchanges and local thermal sensations.

Assessment of body mapping sportswear using a manikin operated in constant temperature mode and thermoregulatory model control mode.

PubMed

Wang, Faming; Del Ferraro, Simona; Molinaro, Vincenzo; Morrissey, Matthew; Rossi, René

2014-09-01

Regional sweating patterns and body surface temperature differences exist between genders. Traditional sportswear made from one material and/or one fabric structure has a limited ability to provide athletes sufficient local wear comfort. Body mapping sportswear consists of one piece of multiple knit structure fabric or of different fabric pieces that may provide athletes better wear comfort. In this study, the 'modular' body mapping sportswear was designed and subsequently assessed on a 'Newton' type sweating manikin that operated in both constant temperature mode and thermophysiological model control mode. The performance of the modular body mapping sportswear kit and commercial products were also compared. The results demonstrated that such a modular body mapping sportswear kit can meet multiple wear/thermal comfort requirements in various environmental conditions. All body mapping clothing (BMC) presented limited global thermophysiological benefits for the wearers. Nevertheless, BMC showed evident improvements in adjusting local body heat exchanges and local thermal sensations.

Variable temperature performance of a fully screen printed transistor switch

NASA Astrophysics Data System (ADS)

Zambou, Serges; Magunje, Batsirai; Rhyme, Setshedi; Walton, Stanley D.; Idowu, M. Florence; Unuigbe, David; Britton, David T.; Härting, Margit

2016-12-01

This article reports on the variable temperature performance of a flexible printed transistor which works as a current driven switch. In this work, electronic ink is formulated from nanostructured silicon produced by milling polycrystalline silicon. The study of the silicon active layer shows that its conductivity is based on thermal activation of carriers, and could be used as active layers in active devices. We further report on the transistors switching operation and their electrical performance under variable temperature. The reliability of the transistors at constant current bias was also investigated. Analysis of the electrical transfer characteristics from 340 to 10 K showed that the printed devices' current ON/OFF ratio increases as temperature decreases making it a better switch at lower temperatures. A constant current bias on a terminal for up to six hours shows extraordinary stability in electrical performance of the device.

Solar-Thermal Engine Testing

NASA Technical Reports Server (NTRS)

Tucker, Stephen; Salvail, Pat; Haynes, Davy (Technical Monitor)

2001-01-01

A solar-thermal engine serves as a high-temperature solar-radiation absorber, heat exchanger, and rocket nozzle. collecting concentrated solar radiation into an absorber cavity and transferring this energy to a propellant as heat. Propellant gas can be heated to temperatures approaching 4,500 F and expanded in a rocket nozzle, creating low thrust with a high specific impulse (I(sub sp)). The Shooting Star Experiment (SSE) solar-thermal engine is made of 100 percent chemical vapor deposited (CVD) rhenium. The engine 'module' consists of an engine assembly, propellant feedline, engine support structure, thermal insulation, and instrumentation. Engine thermal performance tests consist of a series of high-temperature thermal cycles intended to characterize the propulsive performance of the engines and the thermal effectiveness of the engine support structure and insulation system. A silicone-carbide electrical resistance heater, placed inside the inner shell, substitutes for solar radiation and heats the engine. Although the preferred propellant is hydrogen, the propellant used in these tests is gaseous nitrogen. Because rhenium oxidizes at elevated temperatures, the tests are performed in a vacuum chamber. Test data will include transient and steady state temperatures on selected engine surfaces, propellant pressures and flow rates, and engine thrust levels. The engine propellant-feed system is designed to Supply GN2 to the engine at a constant inlet pressure of 60 psia, producing a near-constant thrust of 1.0 lb. Gaseous hydrogen will be used in subsequent tests. The propellant flow rate decreases with increasing propellant temperature, while maintaining constant thrust, increasing engine I(sub sp). In conjunction with analytical models of the heat exchanger, the temperature data will provide insight into the effectiveness of the insulation system, the structural support system, and the overall engine performance. These tests also provide experience on operational aspects of the engine and associated subsystems, and will include independent variation of both steady slate heat-exchanger temperature prior to thrust operation and nitrogen inlet pressure (flow rate) during thrust operation. Although the Shooting Star engines were designed as thermal-storage engines to accommodate mission parameters, they are fully capable of operating as scalable, direct-gain engines. Tests are conducted in both operational modes. Engine thrust and propellant flow rate will be measured and thereby I(sub sp). The objective of these tests is to investigate the effectiveness of the solar engine as a heat exchanger and a rocket. Of particular interest is the effectiveness of the support structure as a thermal insulator, the integrity of both the insulation system and the insulation containment system, the overall temperature distribution throughout the engine module, and the thermal power required to sustain steady state fluid temperatures at various flow rates.

Evaluation of System Architectures for the Army Aviation Ground Power Unit

DTIC Science & Technology

2014-12-01

this state of operation induces wear that reduces pump life. Variable capacity control methods using a constant displacement pump are drive speed...options for use with constant displacement pumps, the fluid or magnetic coupling devices are the most attractive. Variable frequency control cannot...compressor prior to the combustor. The cmTent system turbine exhaust temperature controls to 1250°F, much higher than the compressor exit

On-Orbit Performance of the TES Pulse Tube Cryocooler System and the Instrument - Six Years in Space

NASA Technical Reports Server (NTRS)

Rodriguez, J. I.; Na-Nakornpanom, A.

2011-01-01

The Tropospheric Emission Spectrometer (TES) instrument pulse tube cryocoolers began operation 36 days after launch of the NASA Earth Observing System (EOS) Aura spacecraft on July 15, 2004. TES is designed with four infrared Mercury Cadmium Telluride focal plane arrays in two separate housings cooled by a pair of Northrup Grumman Aerospace Systems (NGAS) single-stage pulse tube cryocoolers. The instrument also makes use of a two-stage passive cooler to cool the optical bench. The instrument is a high-resolution infrared imaging Fourier transform spectrometer with 3.3-15.4 micron spectral coverage. After four weeks of outgassing, the instrument optical bench and focal planes were cooled to their operating temperatures to begin science operations. During the early months of the mission, ice contamination of the cryogenic surfaces including the focal planes led to increased cryocooler loads and the need for periodic decontamination cycles. After a highly successful 5 years of continuous in-space operations, TES was granted a 2 year extension. This paper reports on the TES cryogenic system performance including the two-stage passive cooler. After a brief overview of the cryogenic design, the paper presents detailed data on the highly successful space operation of the pulse tube cryocoolers and instrument thermal design over the past six years since the original turn-on in 2004. The data shows the cryogenic contamination decreased substantially to where decontamination cycles are now performed every six months. The cooler stroke required for constant-temperature operation has not increased indicating near-constant cooler efficiency and the instrument's thermal design has also provided a nearly constant heat rejection sink. At this time TES continues to operate in space providing important Earth science data.

Preliminary low temperature electron irradiation of triple junction solar cells

NASA Technical Reports Server (NTRS)

Stella, Paul M.; Mueller, Robert L.; Scrivner, Roy L.; Helizon, Roger S.

2005-01-01

JPL has routinely performed radiation testing on commercial solar cells and has also performed LILT testing to characterize cell performance under far sun operating conditions. This research activity was intended to combine the features of both capabilities to investigate the possibility of any room temperature annealing that might influence the measured radiation damage. Although it was not possible to maintain the test cells at a constant low temperature between irradiation and electrical measurements, it was possible to obtain measurements with the cell temperature kept well below room temperature.

Thermal sensitivity of elastic coefficients of langasite and langatate.

PubMed

Bourquin, Roger; Dulmet, Bernard

2009-10-01

Thermal coefficients of elastic constants of langasite and langatate crystals have been determined from frequency-temperature curves of contoured resonators operating in thickness modes. The effect of the trapping of the vibration has been taken into account to improve the accuracy. In a first step, the thermal sensitivities of stiffness coefficients in Lagrangian description are obtained. Thermal sensitivities of the usual elastic constants are further deduced. Predictions of thermally compensated cuts are given.

Boiling Heat Transfer Mechanisms in Earth and Low Gravity: Boundary Condition and Heater Aspect Ratio Effects

NASA Technical Reports Server (NTRS)

Kim, Jungho

2004-01-01

Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. Recently, time and space resolved heat transfer data were obtained in both earth and low gravity environments using an array of microheaters varying in size between 100 microns to 700 microns. These heaters were operated in both constant temperature as well as constant heat flux mode. Heat transfer under nucleating bubbles in earth gravity were directly measured using a microheater array with 100 m resolution operated in constant temperature mode with low and high subcooled bulk liquid along with images from below and from the side. The individual bubble departure diameter and energy transfer were larger with low subcooling but the departure frequency increased at high subcooling, resulting in higher overall heat transfer. The bubble growth for both subcoolings was primarily due to energy transfer from the superheated liquid layer relatively little was due to wall heat transfer during the bubble growth process. Oscillating bubbles and sliding bubbles were also observed in highly subcooled boiling. Transient conduction and/or microconvection was the dominant heat transfer mechanism in the above cases. A transient conduction model was developed and compared with the experimental data with good agreement. Data was also obtained with the heater array operated in a constant heat flux mode and measuring the temperature distribution across the array during boiling. The instantaneous heat transfer into the substrate was numerically determined and subtracted from the supplied heat to obtain the wall to liquid heat flux.

Effect of temperature on solids reductions and on degradation kinetics during thermophilic aerobic digestion of a simulated sludge.

PubMed

Toki, C J

2008-07-01

Laboratory-scale experiments were conducted to determine the influence of higher thermophilic temperatures on thermophilic aerobic digestion treatment of a simulated sludge. The efficiency of the process was evaluated in respect of solids removal and degradation rate constants at four thermophilic temperatures. Batch runs were operated at a retention time of one day and temperatures of 65, 70, 72 and 75 degrees C. The results indicated that temperature increase did not impart any significant benefits to the digestion operation in terms of suspended solids and biochemichal oxygen demand reduction. The findings from this research also suggested that the treatment would not appear to benefit from temperatures higher than 65 degrees C, as classically suggested by Van't Hoff-Arrhenius. Therefore, increase of thermophilic temperature in the tested 65-75 degrees C range does not enhance the efficiency of thermophilic, aerobic sludge digestion treatment.

Safety aspects of cryochamber operation

NASA Astrophysics Data System (ADS)

Chorowski, M.; Piotrowska, A.; Sieron, A.; Stanek, A.

2014-01-01

Local and whole body cryotherapy is well recognized, developed and appreciated both from medical and technical point of view. Poland is a country with a highest number of medical cryochambers in operation (above 200) and more than 3 millions of whole body cryotherapeutic sessions have been performed since 1989. Cryogenic temperatures applied for whole-body apart from medical effects have also significant influence on patient's psyche. A number of cryochambers is constantly increasing in hospitals, sport centers and spas. A temperature inside a cryochamber should be below 150 K. To achieve and stabilize such low temperature, either cascade compressor unit or liquid cryogens evaporation (N2 or synthetic air) are used. This paper presents safety oriented review of cryochamber design and constructions.

Theory of noise equivalent power of a high-temperature superconductor far-infrared bolometer in a photo-thermoelectrical mode of operation

NASA Astrophysics Data System (ADS)

Kaila, M. M.; Russell, G. J.

2000-12-01

We present a theory of noise equivalent power (NEP) and related parameters for a high-temperature superconductor (HTSC) bolometer in which temperature and resistance are the noise sources for open circuit operation and phonon and resistance are the noise sources for voltage-biased operation of the bolometer. The bolometer is designed to use a photo-thermoelectrical mode of operation. A mathematical formulation for the open circuit operation is first presented followed by an analysis of the heterodyne case with a bias applied in constant voltage mode. For the first time electrothermal (ET) and thermoelectrical (TE) feedback are treated in the heat balance equation simultaneously. A parallel resistance geometry consisting of thermoelectric and HTSC material legs has been chosen for the device. Computations for the ET-TE feedback show that the response time improves by three orders of magnitude and the responsivity becomes double for the same TE feedback. In the heat balance equation we have included among the heat transfer processes the temperature dependence of the thermal conductance at the bolometer-substrate interface for the dynamic state.

Application of dielectric constant measurement in microwave sludge disintegration and wastewater purification processes.

PubMed

Kovács, Petra Veszelovszki; Lemmer, Balázs; Keszthelyi-Szabó, Gábor; Hodúr, Cecilia; Beszédes, Sándor

2018-05-01

It has been numerously verified that microwave radiation could be advantageous as a pre-treatment for enhanced disintegration of sludge. Very few data related to the dielectric parameters of wastewater of different origins are available; therefore, the objective of our work was to measure the dielectric constant of municipal and meat industrial wastewater during a continuous flow operating microwave process. Determination of the dielectric constant and its change during wastewater and sludge processing make it possible to decide on the applicability of dielectric measurements for detecting the organic matter removal efficiency of wastewater purification process or disintegration degree of sludge. With the measurement of dielectric constant as a function of temperature, total solids (TS) content and microwave specific process parameters regression models were developed. Our results verified that in the case of municipal wastewater sludge, the TS content has a significant effect on the dielectric constant and disintegration degree (DD), as does the temperature. The dielectric constant has a decreasing tendency with increasing temperature for wastewater sludge of low TS content, but an adverse effect was found for samples with high TS and organic matter contents. DD of meat processing wastewater sludge was influenced significantly by the volumetric flow rate and power level, as process parameters of continuously flow microwave pre-treatments. It can be concluded that the disintegration process of food industry sludge can be detected by dielectric constant measurements. From technical purposes the applicability of dielectric measurements was tested in the purification process of municipal wastewater, as well. Determination of dielectric behaviour was a sensitive method to detect the purification degree of municipal wastewater.

On-Orbit Operation and Performance of MODIS Blackbody

NASA Technical Reports Server (NTRS)

Xiong, X.; Chang, T.; Barnes, W.

2009-01-01

MODIS collects data in 36 spectral bands, including 20 reflective solar bands (RSB) and 16 thermal emissive bands (TES). The TEB on-orbit calibration is performed on a scan-by-scan basis using a quadratic algorithm that relates the detector response with the calibration radiance from the sensor on-board blackbody (BB). The calibration radiance is accurately determined each scan from the BB temperature measured using a set of 12 thermistors. The BB thermistors were calibrated pre-launch with traceability to the NIST temperature standard. Unlike many heritage sensors, the MODIS BB can be operated at a constant temperature or with the temperature continuously varying between instrument ambient (about 270K) and 315K. In this paper, we provide an overview of both Terra and Aqua MODIS on-board BB operations, functions, and on-orbit performance. We also examine the impact of key calibration parameters, such as BB emissivity and temperature (stability and gradient) determined from its thermistors, on the TEB calibration and Level I (LIB) data product uncertainty.

Thermal degradation of deoxynivalenol during maize bread baking.

PubMed

Numanoglu, E; Gökmen, V; Uygun, U; Koksel, H

2012-01-01

The thermal degradation of deoxynivalenol (DON) was determined at isothermal baking conditions within the temperature range of 100-250°C, using a crust-like model, which was prepared with naturally contaminated maize flour. No degradation was observed at 100°C. For the temperatures of 150, 200 and 250°C, thermal degradation rate constants (k) were calculated and temperature dependence of DON degradation was observed by using Arrhenius equation. The degradation of DON obeyed Arrhenius law with a regression coefficient of 0.95. A classical bread baking operation was also performed at 250°C for 70 min and the rate of DON degradation in the bread was estimated by using the kinetic data derived from the model study. The crust and crumb temperatures recorded during bread baking were used to calculate the thermal degradation rate constants (k) and partial DON degradations at certain time intervals. Using these data, total degradation at the end of the entire baking process was predicted for both crust and crumb. This DON degradation was consistent with the experimental degradation data, confirming the accuracy of kinetic constants determined by means of the crust-like model.

Information Product Quality in Network Centric Operations

DTIC Science & Technology

2005-05-01

Signori et al.’ s NCOCF .......................................................................................................1 Figure 2...NCW Conceptual Framework Figure 1. Signori et al.’ s NCOCF 1 perspective, having led to what is currently known as the Network Centric Operations...following equation: T QS δ≥∆ , where is the change in entropy, is the change in heat energy and T is some constant S ∆ Qδ 7 temperature. Whenever heat

Dual-mode, high energy utilization system concept for mars missions

NASA Astrophysics Data System (ADS)

El-Genk, Mohamed S.

2000-01-01

This paper describes a dual-mode, high energy utilization system concept based on the Pellet Bed Reactor (PeBR) to support future manned missions to Mars. The system uses proven Closed Brayton Cycle (CBC) engines to partially convert the reactor thermal power to electricity. The electric power generated is kept the same during the propulsion and the power modes, but the reactor thermal power in the former could be several times higher, while maintaining the reactor temperatures almost constant. During the propulsion mode, the electric power of the system, minus ~1-5 kWe for house keeping, is used to operate a Variable Specific Impulse Magnetoplasma Rocket (VASIMR). In addition, the reactor thermal power, plus more than 85% of the head load of the CBC engine radiators, are used to heat hydrogen. The hot hydrogen is mixed with the high temperature plasma in a VASIMR to provide both high thrust and Isp>35,000 N.s/kg, reducing the travel time to Mars to about 3 months. The electric power also supports surface exploration of Mars. The fuel temperature and the inlet temperatures of the He-Xe working fluid to the nuclear reactor core and the CBC turbine are maintained almost constant during both the propulsion and power modes to minimize thermal stresses. Also, the exit temperature of the He-Xe from the reactor core is kept at least 200 K below the maximum fuel design temperature. The present system has no single point failure and could be tested fully assembled in a ground facility using electric heaters in place of the nuclear reactor. Operation and design parameters of a 40-kWe prototype are presented and discussed to illustrate the operation and design principles of the proposed system. .

Design techniques for a stable operation of cryogenic field-programmable gate arrays.

PubMed

Homulle, Harald; Visser, Stefan; Patra, Bishnu; Charbon, Edoardo

2018-01-01

In this paper, we show how a deep-submicron field-programmable gate array (FPGA) can be operated more stably at extremely low temperatures through special firmware design techniques. Stability at low temperatures is limited through long power supply wires and reduced performance of various printed circuit board components commonly employed at room temperature. Extensive characterization of these components shows that the majority of decoupling capacitor types and voltage regulators are not well behaved at cryogenic temperatures, asking for an ad hoc solution to stabilize the FPGA supply voltage, especially for sensitive applications. Therefore, we have designed a firmware that enforces a constant power consumption, so as to stabilize the supply voltage in the interior of the FPGA. The FPGA is powered with a supply at several meters distance, causing significant resistive voltage drop and thus fluctuations on the local supply voltage. To achieve the stabilization, the variation in digital logic speed, which directly corresponds to changes in supply voltage, is constantly measured and corrected for through a tunable oscillator farm, implemented on the FPGA. The impact of the stabilization technique is demonstrated together with a reconfigurable analog-to-digital converter (ADC), completely implemented in the FPGA fabric and operating at 15 K. The ADC performance can be improved by at most 1.5 bits (effective number of bits) thanks to the more stable supply voltage. The method is versatile and robust, enabling seamless porting to other FPGA families and configurations.

Design techniques for a stable operation of cryogenic field-programmable gate arrays

NASA Astrophysics Data System (ADS)

Homulle, Harald; Visser, Stefan; Patra, Bishnu; Charbon, Edoardo

2018-01-01

In this paper, we show how a deep-submicron field-programmable gate array (FPGA) can be operated more stably at extremely low temperatures through special firmware design techniques. Stability at low temperatures is limited through long power supply wires and reduced performance of various printed circuit board components commonly employed at room temperature. Extensive characterization of these components shows that the majority of decoupling capacitor types and voltage regulators are not well behaved at cryogenic temperatures, asking for an ad hoc solution to stabilize the FPGA supply voltage, especially for sensitive applications. Therefore, we have designed a firmware that enforces a constant power consumption, so as to stabilize the supply voltage in the interior of the FPGA. The FPGA is powered with a supply at several meters distance, causing significant resistive voltage drop and thus fluctuations on the local supply voltage. To achieve the stabilization, the variation in digital logic speed, which directly corresponds to changes in supply voltage, is constantly measured and corrected for through a tunable oscillator farm, implemented on the FPGA. The impact of the stabilization technique is demonstrated together with a reconfigurable analog-to-digital converter (ADC), completely implemented in the FPGA fabric and operating at 15 K. The ADC performance can be improved by at most 1.5 bits (effective number of bits) thanks to the more stable supply voltage. The method is versatile and robust, enabling seamless porting to other FPGA families and configurations.

High-Temperature Piezoelectric Ceramic Developed

NASA Technical Reports Server (NTRS)

Sayir, Ali; Farmer, Serene C.; Dynys, Frederick W.

2005-01-01

Active combustion control of spatial and temporal variations in the local fuel-to-air ratio is of considerable interest for suppressing combustion instabilities in lean gas turbine combustors and, thereby, achieving lower NOx levels. The actuator for fuel modulation in gas turbine combustors must meet several requirements: (1) bandwidth capability of 1000 Hz, (2) operating temperature compatible with the fuel temperature, which is in the vicinity of 400 F, (3) stroke of approximately 4 mils (100 m), and (4) force of 300 lb-force. Piezoelectric actuators offer the fastest response time (microsecond time constants) and can generate forces in excess of 2000 lb-force. The state-of-the-art piezoceramic material in industry today is Pb(Zr,Ti)O3, called PZT. This class of piezoelectric ceramic is currently used in diesel fuel injectors and in the development of high-response fuel modulation valves. PZT materials are generally limited to operating temperatures of 250 F, which is 150 F lower than the desired operating temperature for gas turbine combustor fuel-modulation injection valves. Thus, there is a clear need to increase the operating temperature range of piezoceramic devices for active combustion control in gas turbine engines.

A comparison of calibration techniques for hot-wires operated in subsonic compressible slip flows

NASA Technical Reports Server (NTRS)

Jones, Gregory S.; Stainback, P. C.; Nagabushana, K. A.

1992-01-01

This paper focuses on the correlation of constant temperature anemometer voltages to velocity, density, and total temperature in the transonic slip flow regime. Three different calibration schemes were evaluated. The ultimate use of these hot-wire calibrations is to obtain fluctuations in the flow variables. Without the appropriate mean flow sensitivities of the heated wire, the measurements of these fluctuations cannot be accurately determined.

Ultrasound assisted transesterification of waste cooking oil using heterogeneous solid catalyst.

PubMed

Pukale, Dipak D; Maddikeri, Ganesh L; Gogate, Parag R; Pandit, Aniruddha B; Pratap, Amit P

2015-01-01

Transesterification based biodiesel production from waste cooking oil in the presence of heterogeneous solid catalyst has been investigated in the present work. The effect of different operating parameters such as type of catalyst, catalyst concentration, oil to methanol molar ratio and the reaction temperature on the progress of the reaction was studied. Some studies related to catalyst reusability have also been performed. The important physicochemical properties of the synthesized biodiesel have also been investigated. The results showed that tri-potassium phosphate exhibits high catalytic activity for the transesterification of waste cooking oil. Under the optimal conditions, viz. catalyst concentration of 3wt% K3PO4, oil to methanol molar ratio of 1:6 and temperature of 50°C, 92.0% of biodiesel yield was obtained in 90min of reaction time. Higher yield was obtained in the presence of ultrasound as compared to conventional approach under otherwise similar conditions, which can be attributed to the cavitational effects. Kinetic studies have been carried out to determine the rate constant at different operating temperatures. It was observed that the kinetic rate constant increased with an increase in the temperature and the activation energy was found to be 64.241kJ/mol. Copyright © 2014 Elsevier B.V. All rights reserved.

Investigation of the frequency response of constant voltage anemometers in turbulent flows

NASA Astrophysics Data System (ADS)

Sadeghi Hassanlouei, Atabak

A commercially available anemometer system considered as a prototype, the constant voltage anemometer (CVA), is presented and its working principle is studied and analyzed. We detail the different procedures and corrections that have to be applied to voltage signals to deduce corresponding velocity signals, including the effect of the thermal inertia of the sensor. Results are compared to another anemometer system widely used in research and industry, the constant temperature anemometer (CTA), for validation requirements. Measurements are performed in the turbulent region of a subsonic axisymmetric jet and include mean velocities, root-mean-square (rms) values of velocity fluctuations and power spectral densities. In the same range of operation, we show that the two instruments give similar results. The CVA anemometer slightly underestimates the rms velocity values given by the CTA anemometer which is attributed to a non-linear effect. We show that the cut-off frequency of the CVA system is higher than the more commonly used CTA system, and that the electronic noise level is lower. The constant voltage anemometer is thus an excellent alternative to the constant temperature anemometer for low turbulent flows with rich frequency content, such as supersonic and hypersonic flows.

Testing of a Loop Heat Pipe Subjective to Variable Accelerations. Part 2; Temperature Stability

NASA Technical Reports Server (NTRS)

Ku, Jentung; Ottenstein, Laura; Kaya, Taril; Rogers, Paul; Hoff, Craig

2000-01-01

The effect of accelerating forces on the performance of loop heat pipes (LHP) is of interest and importance to terrestrial and space applications. LHP's are being considered for cooling of military combat vehicles and for spinning spacecraft. In order to investigate the effect of an accelerating force on LHP operation, a miniature LHP was installed on a spin table. Variable accelerating forces were imposed on the LHP by spinning the table at different angular speeds. Several patterns of accelerating forces were applied, i.e. continuous spin at different speeds and periodic spin at different speeds and frequencies. The resulting accelerations ranged from 1.17 g's to 4.7 g's. This paper presents the second part of the experimental study, i.e. the effect of an accelerating force on the LHP operating temperature. It has been known that in stationary tests the LHP operating temperature is a function of the evaporator power and the condenser sink temperature when the compensation temperature is not actively controlled. Results of this test program indicate that any change in the accelerating force will result in a chance in the LHP operating temperature through its influence on the fluid distribution in the evaporator, condenser and compensation chamber. However, the effect is not universal, rather it is a function of other test conditions. A steady, constant acceleration may result in an increase or decrease of the operating temperature, while a periodic spin will lead to a quasi-steady operating temperature over a sufficient time interval. In addition, an accelerating force may lead to temperature hysteresis and changes in the temperature oscillation. In spite of all these effects, the LHP continued to operate without any problems in all tests.

Pumped two-phase heat transfer loop

NASA Technical Reports Server (NTRS)

Edelstein, Fred

1988-01-01

A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes several independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.

Pumped two-phase heat transfer loop

NASA Technical Reports Server (NTRS)

Edelstein, Fred (Inventor)

1987-01-01

A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes a plurality of independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.

Thermal anomalies of the transmitter experiment package on the communications technology satellite

NASA Technical Reports Server (NTRS)

Alexovich, R. E.; Curren, A. N.

1979-01-01

The causes of four temporary thermal-control-system malfunctions that gave rise to unexpected temperature excursions in the 12-gigahertz, 200-watt transmitter experiment package (TEP) on the Communications Technology Satellite were investigated. The TEP consists of a nominal 200-watt output stage tube (OST), a supporting power-processing system (PPS), and a variable-conductance heat-pipe system (VCHPS). The VCHPS, which uses three heat pipes to conduct heat from the body of the OST to a radiator fin, was designed to maintain the TEP at safe operating temperatures at all operating conditions. On four occasions during 1977, all near the spring and fall equinoxes, the OST body temperature and related temperatures displayed sudden, rapid, and unexpected rises above normal levels while the TEP was operating at essentially constant, normal conditions. The temperature excursions were terminated without TEP damage by reducing the radio frequency (RF) output power of the OST. Between the anomalies and since the fourth, the thermal control system has apparently functioned as designed. The results indicate the most probable cause of the temperature anomalies is depriming of the arteries in the variable-conductance heat pipes. A mode was identified in which the TEP, as presently configured, may operate with stable temperatures and with minimum change in performance level.

Platform for a Hydrocarbon Exhaust Gas Sensor Utilizing a Pumping Cell and a Conductometric Sensor

PubMed Central

Biskupski, Diana; Geupel, Andrea; Wiesner, Kerstin; Fleischer, Maximilian; Moos, Ralf

2009-01-01

Very often, high-temperature operated gas sensors are cross-sensitive to oxygen and/or they cannot be operated in oxygen-deficient (rich) atmospheres. For instance, some metal oxides like Ga2O3 or doped SrTiO3 are excellent materials for conductometric hydrocarbon detection in the rough atmosphere of automotive exhausts, but have to be operated preferably at a constant oxygen concentration. We propose a modular sensor platform that combines a conductometric two-sensor-setup with an electrochemical pumping cell made of YSZ to establish a constant oxygen concentration in the ambient of the conductometric sensor film. In this paper, the platform is introduced, the two-sensor-setup is integrated into this new design, and sensing performance is characterized. Such a platform can be used for other sensor principles as well. PMID:22423212

Safety aspects of cryochamber operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chorowski, M.; Piotrowska, A.; Sieron, A.

Local and whole body cryotherapy is well recognized, developed and appreciated both from medical and technical point of view. Poland is a country with a highest number of medical cryochambers in operation (above 200) and more than 3 millions of whole body cryotherapeutic sessions have been performed since 1989. Cryogenic temperatures applied for whole-body apart from medical effects have also significant influence on patient's psyche. A number of cryochambers is constantly increasing in hospitals, sport centers and spas. A temperature inside a cryochamber should be below 150 K. To achieve and stabilize such low temperature, either cascade compressor unit ormore » liquid cryogens evaporation (N{sub 2} or synthetic air) are used. This paper presents safety oriented review of cryochamber design and constructions.« less

Modeling and Simulation of the ITER First Wall/Blanket Primary Heat Transfer System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ying, Alice; Popov, Emilian L

2011-01-01

ITER inductive power operation is modeled and simulated using a thermal-hydraulics system code (RELAP5) integrated with a 3-D CFD (SC-Tetra) code. The Primary Heat Transfer System (PHTS) functions are predicted together with the main parameters operational ranges. The control algorithm strategy and derivation are summarized as well. The First Wall and Blanket modules are the primary components of PHTS, used to remove the major part of the thermal heat from the plasma. The modules represent a set of flow channels in solid metal structure that serve to absorb the radiation heat and nuclear heating from the fusion reactions and tomore » provide shield for the vacuum vessel. The blanket modules are water cooled. The cooling is forced convective with constant blanket inlet temperature and mass flow rate. Three independent water loops supply coolant to the three blanket sectors. The main equipment of each loop consists of a pump, a steam pressurizer and a heat exchanger. A major feature of ITER is the pulsed operation. The plasma does not burn continuously, but on intervals with large periods of no power between them. This specific feature causes design challenges to accommodate the thermal expansion of the coolant during the pulse period and requires active temperature control to maintain a constant blanket inlet temperature.« less

In-situ analysis of hydrazine decomposition products

NASA Technical Reports Server (NTRS)

Curran, Francis M.; Whalen, Margaret V.

1987-01-01

A gas analyzer utilizing a nondispersive infrared (NDIR) detection system was used to monitor the ammonia and water vapor content of the products of a previously unused hydrazine gas generator. This provided an in-situ measurement of the generator's efficiency difficult to obtain by other means. The analyzer was easily installed in both the calibration and hydrazine systems, required no maintenance other than periodic zero adjustments, and performed well for extended periods in the operating range tested. The catalyst bed operated smoothly and repeatably during the 28 hr of testing. No major transients were observed on startup or during steady state operation. The amount of ammonia in the output stream of the gas generator was found to be a strong function of temperature at catalyst bed temperatures below 450 C. At temperatures above this, the efficiency remained nearly constant. On startup the gas generator efficiency was found to decrease with time until a steady state value was attained. Elevated catalyst bed temperatures in the periods before steady state operation was found to be responsible for this phenomenon.

Physics Simulation Software for Autonomous Propellant Loading and Gas House Autonomous System Monitoring

NASA Technical Reports Server (NTRS)

Regalado Reyes, Bjorn Constant

2015-01-01

1. Kennedy Space Center (KSC) is developing a mobile launching system with autonomous propellant loading capabilities for liquid-fueled rockets. An autonomous system will be responsible for monitoring and controlling the storage, loading and transferring of cryogenic propellants. The Physics Simulation Software will reproduce the sensor data seen during the delivery of cryogenic fluids including valve positions, pressures, temperatures and flow rates. The simulator will provide insight into the functionality of the propellant systems and demonstrate the effects of potential faults. This will provide verification of the communications protocols and the autonomous system control. 2. The High Pressure Gas Facility (HPGF) stores and distributes hydrogen, nitrogen, helium and high pressure air. The hydrogen and nitrogen are stored in cryogenic liquid state. The cryogenic fluids pose several hazards to operators and the storage and transfer equipment. Constant monitoring of pressures, temperatures and flow rates are required in order to maintain the safety of personnel and equipment during the handling and storage of these commodities. The Gas House Autonomous System Monitoring software will be responsible for constantly observing and recording sensor data, identifying and predicting faults and relaying hazard and operational information to the operators.

Transient deformational properties of high temperature alloys used in solid oxide fuel cell stacks

NASA Astrophysics Data System (ADS)

Molla, Tesfaye Tadesse; Kwok, Kawai; Frandsen, Henrik Lund

2017-05-01

Stresses and probability of failure during operation of solid oxide fuel cells (SOFCs) is affected by the deformational properties of the different components of the SOFC stack. Though the overall stress relaxes with time during steady state operation, large stresses would normally appear through transients in operation including temporary shut downs. These stresses are highly affected by the transient creep behavior of metallic components in the SOFC stack. This study investigates whether a variation of the so-called Chaboche's unified power law together with isotropic hardening can represent the transient behavior of Crofer 22 APU, a typical iron-chromium alloy used in SOFC stacks. The material parameters for the model are determined by measurements involving relaxation and constant strain rate experiments. The constitutive law is implemented into commercial finite element software using a user-defined material model. This is used to validate the developed constitutive law to experiments with constant strain rate, cyclic and creep experiments. The predictions from the developed model are found to agree well with experimental data. It is therefore concluded that Chaboche's unified power law can be applied to describe the high temperature inelastic deformational behaviors of Crofer 22 APU used for metallic interconnects in SOFC stacks.

High-Temperature Adiabatic Calorimeter for Constant-Volume Heat Capacity Measurements of Compressed Gases and Liquids

PubMed Central

Magee, Joseph W.; Deal, Renee J.; Blanco, John C.

1998-01-01

A high-temperature adiabatic calorimeter has been developed to measure the constant-volume specific heat capacities (cV) of both gases and liquids, especially fluids of interest to emerging energy technologies. The chief design feature is its nearly identical twin bomb arrangement, which allows accurate measurement of energy differences without large corrections for energy losses due to thermal radiation fluxes. Operating conditions for the calorimeter cover a range of temperatures from 250 K to 700 K and at pressures up to 20 MPa. Performance tests were made with a sample of twice-distilled water. Heat capacities for water were measured from 300 K to 420 K at pressures to 20 MPa. The measured heat capacities differed from those calculated with an independently developed standard reference formulation with a root-mean-square fractional deviation of 0.48 %. PMID:28009375

Effect of solvent on crystallization behavior of xylitol

NASA Astrophysics Data System (ADS)

Hao, Hongxun; Hou, Baohong; Wang, Jing-Kang; Lin, Guangyu

2006-04-01

Effect of organic solvents content on crystallization behavior of xylitol was studied. Solubility and crystallization kinetics of xylitol in methanol-water system were experimentally determined. It was found that the solubility of xylitol at various methanol content all increases with increase of temperature. But it decreases when increasing methanol content at constant temperature. Based on the theory of population balance, the nucleation and growth rates of xylitol in methanol-water mixed solvents were calculated by moments method. From a series of experimental population density data of xylitol gotten from a batch-operated crystallizer, parameters of crystal nucleation and growth rate equations at different methanol content were got by the method of nonlinear least-squares. By analyzing, it was found that the content of methanol had an apparent effect on nucleation and growth rate of xylitol. At constant temperature, the nucleation and growth rate of xylitol all decrease with increase of methanol content.

Monitoring solar irradiance from L2 with Gaia

NASA Astrophysics Data System (ADS)

Serpell, E.

2017-09-01

Gaia is the European Space Agency's cornerstone astrometry mission to measure the positions of a billion stars in the Milky Way with unprecedented accuracy. Since early 2014 Gaia has been operating in a halo orbit around the second Sun-Earth Lagrange point that provides the stable thermal environment, without Earth eclipses, needed for the payload to function accurately. The spacecraft is equipped with a number of thermally isolated, sun-facing thermistors that provide a continuous measurement of the local equilibrium temperature. As a consequence of the spacecraft design and operational conditions these temperature measurements have been used to infer the solar output over a broad wavelength range. In this paper we present an analysis of temperature measurements made of the Gaia solar panels at frequencies of up to 1 Hz for the first 35 months of routine operations. We show that the Gaia solar panel temperature measurements are capable of precisely determining short term changes to the solar output at a level of better than 0.04% with time constants of a few minutes.

Tests of by-pass diodes at cryogenic temperatures for the KATRIN magnets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gil, W.; Bolz, H.; Jansen, A.

The Karlsruhe Tritium Neutrino experiment (KATRIN) requires a series of superconducting solenoid magnets for guiding beta-electrons from the source to the detector. By-pass diodes will operate at liquid helium temperatures to protect the superconducting magnets and bus bars in case of quenches. The operation conditions of the by-pass diodes depend on the different magnet systems of KATRIN. Therefore, different diode stacks are designed with adequate copper heat sinks assuming adiabatic conditions. The by-pass diode stacks have been submitted to cold tests both at liquid nitrogen and liquid helium temperatures for checking operation conditions. This report presents the test set upmore » and first results of the diode characteristics at 300 K and 77 K, as well as of endurance tests of the diode stacks at constant current load at 77 K and 4.2 K.« less

Fatigue design procedure for the American SST prototype

NASA Technical Reports Server (NTRS)

Doty, R. J.

1972-01-01

For supersonic airline operations, significantly higher environmental temperature is the primary new factor affecting structural service life. Methods for incorporating the influence of temperature in detailed fatigue analyses are shown along with current test indications. Thermal effects investigated include real-time compared with short-time testing, long-time temperature exposure, and stress-temperature cycle phasing. A method is presented which allows designers and stress analyzers to check fatigue resistance of structural design details. A communicative rating system is presented which defines the relative fatigue quality of the detail so that the analyst can define cyclic-load capability of the design detail by entering constant-life charts for varying detail quality. If necessary then, this system allows the designer to determine ways to improve the fatigue quality for better life or to determine the operating stresses which will provide the required service life.

Operating characteristics of a three-piece-inner-ring large-bore roller bearing to speeds of 3 million DN

NASA Technical Reports Server (NTRS)

Schuller, F. T.

1984-01-01

A 118 mm bore roller bearing with a three piece inner ring ran successfully at 300,000 DN for 20 hr. Provisions were made for lubrication and cooling through the inner ring. In some tests the outer ring was also cooled. Power loss within the bearing increased with both speed and total oil flow rate to the inner ring. Outer ring temperature decreased by as much as 22 K (40 F) when outer ring cooling was employed whereas inner ring temperature remained essentially constant. Cage slip was greatly reduced or even eliminated by using a bearing with a very tight clearance at operating speed. A three piece inner ring bearing had higher inner ring temperatures and less temperature difference between the inner and outer rings than a conventional one piece inner ring bearing.

Design data package and operating procedures for MSFC solar simulator test facility

NASA Technical Reports Server (NTRS)

1981-01-01

Design and operational data for the solar simulator test facility are reviewed. The primary goal of the facility is to evaluate the performance capacibility and worst case failure modes of collectors, which utilize either air or liquid transport media. The facility simulates environmental parameters such as solar radiation intensity, solar spectrum, collimation, uniformity, and solar attitude. The facility also simulates wind conditions of velocity and direction, solar system conditions imposed on the collector, collector fluid inlet temperature, and geometric factors of collector tilt and azimuth angles. Testing the simulator provides collector efficiency data, collector time constant, incident angle modifier data, and stagnation temperature values.

RELAP5 Model of the First Wall/Blanket Primary Heat Transfer System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Popov, Emilian L; Yoder Jr, Graydon L; Kim, Seokho H

2010-06-01

ITER inductive power operation is modeled and simulated using a system level computer code to evaluate the behavior of the Primary Heat Transfer System (PHTS) and predict parameter operational ranges. The control algorithm strategy and derivation are summarized in this report as well. A major feature of ITER is pulsed operation. The plasma does not burn continuously, but the power is pulsed with large periods of zero power between pulses. This feature requires active temperature control to maintain a constant blanket inlet temperature and requires accommodation of coolant thermal expansion during the pulse. In view of the transient nature ofmore » the power (plasma) operation state a transient system thermal-hydraulics code was selected: RELAP5. The code has a well-documented history for nuclear reactor transient analyses, it has been benchmarked against numerous experiments, and a large user database of commonly accepted modeling practices exists. The process of heat deposition and transfer in the blanket modules is multi-dimensional and cannot be accurately captured by a one-dimensional code such as RELAP5. To resolve this, a separate CFD calculation of blanket thermal power evolution was performed using the 3-D SC/Tetra thermofluid code. A 1D-3D co-simulation more realistically models FW/blanket internal time-dependent thermal inertia while eliminating uncertainties in the time constant assumed in a 1-D system code. Blanket water outlet temperature and heat release histories for any given ITER pulse operation scenario are calculated. These results provide the basis for developing time dependent power forcing functions which are used as input in the RELAP5 calculations.« less

A full set of langatate high-temperature acoustic wave constants: elastic, piezoelectric, dielectric constants up to 900°C.

PubMed

Davulis, Peter M; da Cunha, Mauricio Pereira

2013-04-01

A full set of langatate (LGT) elastic, dielectric, and piezoelectric constants with their respective temperature coefficients up to 900°C is presented, and the relevance of the dielectric and piezoelectric constants and temperature coefficients are discussed with respect to predicted and measured high-temperature SAW propagation properties. The set of constants allows for high-temperature acoustic wave (AW) propagation studies and device design. The dielectric constants and polarization and conductive losses were extracted by impedance spectroscopy of parallel-plate capacitors. The measured dielectric constants at high temperatures were combined with previously measured LGT expansion coefficients and used to determine the elastic and piezoelectric constants using resonant ultrasound spectroscopy (RUS) measurements at temperatures up to 900°C. The extracted LGT piezoelectric constants and temperature coefficients show that e11 and e14 change by up to 62% and 77%, respectively, for the entire 25°C to 900°C range when compared with room-temperature values. The LGT high-temperature constants and temperature coefficients were verified by comparing measured and predicted phase velocities (vp) and temperature coefficients of delay (TCD) of SAW delay lines fabricated along 6 orientations in the LGT plane (90°, 23°, Ψ) up to 900°C. For the 6 tested orientations, the predicted SAW vp agree within 0.2% of the measured vp on average and the calculated TCD is within 9.6 ppm/°C of the measured value on average over the temperature range of 25°C to 900°C. By including the temperature dependence of both dielectric and piezoelectric constants, the average discrepancies between predicted and measured SAW properties were reduced, on average: 77% for vp, 13% for TCD, and 63% for the turn-over temperatures analyzed.

Effect of operating temperature on styrene mass transfer characteristics in a biotrickling filter.

PubMed

Parnian, Parham; Zamir, Seyed Morteza; Shojaosadati, Seyed Abbas

2017-05-01

To study the effect of operating temperature on styrene mass transfer from gas to liquid phase in biotrickling filters (BTFs), overall mass transfer coefficient (K L a) was calculated through fitting test data to a general mass balance model under abiotic conditions. Styrene was used as the volatile organic compound and the BTF was packed with a mixture of pall rings and pumice. Operating temperature was set at 30°C and 50°C for mesophilic and thermophilic conditions, respectively. K L a values increased from 54 to 70 h -1 at 30°C and from 60 to 90 h -1 at 50°C, respectively, depending on the countercurrent gas to liquid flow ratio that varied in the range of 7.5-32. Evaluation of styrene mass transfer capacity (MTC) showed that liquid-phase mass transfer resistance decreased as the flow ratio increased at constant temperature. MTC also decreased with an increase in operating temperature. Both gas-liquid partition coefficient and K L a increased with increasing temperature; however the effect on gas-liquid partition coefficient was more significant and served to increase mass transfer limitations. Thermophilic biofiltration on the one hand increases mass transfer limitations, but on the other hand may enhance the biodegradation rate in favor of enhancing BTFs' performance.

Investigate the electrical and thermal properties of the low temperature resistant silver nanowire fabricated by two-beam laser technique

NASA Astrophysics Data System (ADS)

He, Gui-Cang; Dong, Xian-Zi; Liu, Jie; Lu, Heng; Zhao, Zhen-Sheng

2018-05-01

A two-beam laser fabrication technique is introduced to fabricate the single silver nanowire (AgNW) on polyethylene terephthalate (PET) substrate. The resistivity of the AgNW is (1.31 ± 0.05) × 10-7 Ω·m, which is about 8 times of the bulk silver resistivity (1.65 × 10-8 Ω·m). The AgNW electrical resistance is measured in temperature range of 10-300 K and fitted with the Bloch-Grüneisen formula. The fitting results show that the residue resistance is 153 Ω, the Debye temperature is 210 K and the electron-phonon coupling constant is (5.72 ± 0.24) × 10-8 Ω·m. Due to the surface scattering, the Debye temperature and the electron-phonon coupling constant are lower than those of bulk silver, and the residue resistance is bigger than that of bulk silver. Thermal conductivity of the single AgNW is calculated in the corresponding temperature range, which is the biggest at the temperature approaching the Debye temperature. The AgNW on PET substrate is the low temperature resistance material and is able to be operated stably at such a low temperature of 10 K.

Quality evaluation of onion bulbs during low temperature drying

NASA Astrophysics Data System (ADS)

Djaeni, M.; Asiah, N.; Wibowo, Y. P.; Yusron, D. A. A.

2016-06-01

A drying technology must be designed carefully by evaluating the foods' final quality properties as a dried material. Thermal processing should be operated with the minimum chance of substantial flavour, taste, color and nutrient loss. The main objective of this research was to evaluate the quality parameters of quercetin content, color, non-enzymatic browning and antioxidant activity. The experiments showed that heating at different temperatures for several drying times resulted in a percentage of quercetin being generally constant. The quercetin content maintained at the value of ±1.2 % (dry basis). The color of onion bulbs was measured by CIE standard illuminant C. The red color (a*) of the outer layer of onion bulbs changed significantly when the drying temperature was increased. However the value of L* and b* changed in a fluctuating way based on the temperature. The change of onion colors was influenced by temperature and moisture content during the drying process. The higher the temperature, the higher it affects the rate of non-enzymatic browning reaction. The correlation between temperature and reaction rate constant was described as Arrhenius equation. The rate of non-enzymatic browning increases along with the increase of drying temperature. The results showed that higher drying temperatures were followed by a lower IC10. This condition indicated the increase of antioxidant activity after the drying process.

Chemical preconcentrator with integral thermal flow sensor

DOEpatents

Manginell, Ronald P.; Frye-Mason, Gregory C.

2003-01-01

A chemical preconcentrator with integral thermal flow sensor can be used to accurately measure fluid flow rate in a microanalytical system. The thermal flow sensor can be operated in either constant temperature or constant power mode and variants thereof. The chemical preconcentrator with integral thermal flow sensor can be fabricated with the same MEMS technology as the rest of the microanlaytical system. Because of its low heat capacity, low-loss, and small size, the chemical preconcentrator with integral thermal flow sensor is fast and efficient enough to be used in battery-powered, portable microanalytical systems.

Evaluation of centrifugal compressor performance with water injection

NASA Technical Reports Server (NTRS)

Beede, William L; Hamrick, Joseph T; Withee, Joseph R , Jr

1951-01-01

The effects of water injection on a compressor are presented. To determine the effects of varying water-air ratio, the compressor was operated at a constant equivalent impeller speed over a range of water-air ratios and weight flows. Operation over a range of weight flows at one water-air ratio and two inlet air temperatures was carried out to obtain an indication of the effects of varying inlet air temperature. Beyond a water-air ratio of 0.03 there was no increase in maximum air-weight flow, a negligible rise in peak total-pressure ratio, and a decrease in peak adiabatic efficiency. An increase in inlet air temperature resulted in an increase in the magnitude of evaporation. An analysis of data indicated that the magnitude of evaporation within the compressor impeller was small.

Study of advanced radial outflow turbine for solar steam Rankine engines

NASA Technical Reports Server (NTRS)

Martin, C.; Kolenc, T.

1979-01-01

The performance characteristics of various steam Rankine engine configurations for solar electric power generation were investigated. A radial outflow steam turbine was investigated to determine: (1) a method for predicting performance from experimental data; (2) the flexibility of a single design with regard to power output and pressure ratio; and (3) the effect of varying the number of turbine stages. All turbine designs were restricted to be compatible with commercially available gearboxes and generators. A study of several operating methods and control schemes for the steam Rankine engine shows that from an efficiency and control simplicity standpoint, the best approach is to hold turbine inlet temperature constant, vary turbine inlet pressure to match load, and allow condenser temperature to float maintaining constant heat rejection load.

Durability of Polymer Electrolyte Membrane Fuel Cells Operated at Subfreezing Temperatures

DOE PAGES

Macauley, Natalia; Lujan, Roger W.; Spernjak, Dusan; ...

2016-09-15

The structure, composition, and interfaces of membrane electrode assemblies (MEA) and gas-diffusion layers (GDLs) have a significant effect on the performance of single-proton-exchange-membrane (PEM) fuel cells operated isothermally at subfreezing temperatures. During isothermal constant-current operation at subfreezing temperatures, water forming at the cathode initially hydrates the membrane, then forms ice in the catalyst layer and/or GDL. This ice formation results in a gradual decay in voltage. High-frequency resistance initially decreases due to an increase in membrane water content and then increases over time as the contact resistance increases. The water/ice holding capacity of a fuel cell decreases with decreasing subfreezingmore » temperature (-10°C vs. -20°C vs. -30°C) and increasing current density (0.02 A cm -2 vs. 0.04 A cm -2). Ice formation monitored using in-situ high-resolution neutron radiography indicated that the ice was concentrated near the cathode catalyst layer at low operating temperatures (≈-20°C) and high current densities (0.04 A cm -2). Significant ice formation was also observed in the GDLs at higher subfreezing temperatures (≈-10°C) and lower current densities (0.02 A cm -2). These results are in good agreement with the long-term durability observations that show more severe degradation at lower temperatures (-20°C and -30°C).« less

Thermal Vacuum Testing of a Novel Loop Heat Pipe Design for the Swift BAT Instrument

NASA Technical Reports Server (NTRS)

Ottenstein, Laura; Ku, Jentung; Feenan, David

2003-01-01

An advanced thermal control system for the Burst Alert Telescope on the Swift satellite has been designed and an engineering test unit (ETU) has been built and tested in a thermal vacuum chamber. The ETU assembly consists of a propylene loop heat pipe, two constant conductance heat pipes, a variable conductance heat pipe (VCHP), which is used for rough temperature control of the system, and a radiator. The entire assembly was tested in a thermal vacuum chamber at NASA/GSFC in early 2002. Tests were performed with thermal mass to represent the instrument and with electrical resistance heaters providing the heat to be transferred. Start-up and heat transfer of over 300 W was demonstrated with both steady and variable condenser sink temperatures. Radiator sink temperatures ranged from a high of approximately 273 K, to a low of approximately 83 K, and the system was held at a constant operating temperature of 278 K throughout most of the testing. A novel LHP temperature control methodology using both temperature-controlled electrical resistance heaters and a small VCHP was demonstrated. This paper describes the system and the tests performed and includes a discussion of the test results.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures ofmore » the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.« less

VOLUME COMPENSATING MEANS FOR PULSATING PUMPS

DOEpatents

Weaver, D.L.W.; MacCormack, R.S. Jr.

1959-12-01

A double diaphragm, two-liquid pulsating pump for remote control use, having as an improvement an apparatus for maintaining constant the volume of the liquid such as kerosene between the two diaphragms is described. Phase difficulties encountered in the operation of such pumps when the volume of the liquid is altered by changes in temperature are avoided.

Performance analysis on a large scale borehole ground source heat pump in Tianjin cultural centre

NASA Astrophysics Data System (ADS)

Yin, Baoquan; Wu, Xiaoting

2018-02-01

In this paper, the temperature distribution of the geothermal field for the vertical borehole ground-coupled heat pump was tested and analysed. Besides the borehole ground-coupled heat pump, the system composed of the ice storage, heat supply network and cooling tower. According to the operation data for nearly three years, the temperature constant zone is in the ground depth of 40m -120m with a temperature gradient of about 3.0°C/100m. The temperature of the soil dropped significantly in the heating season, increased significantly in the cooling season, and reinstated in the transitional season. With the energy balance design of the heating and cooling and the existence of the soil thermal inertia, the soil temperature stayed in a relative stable range and the ground source heat pump system was operated with a relative high efficiency. The geothermal source heat pump was shown to be applicable for large scale utilization.

Fatigue life characterization for piezoelectric macrofiber composites

NASA Astrophysics Data System (ADS)

Henslee, Isaac A.; Miller, David A.; Tempero, Tyler

2012-10-01

In an effort to aid the investigation into lightweight and reliable materials for actuator design, a study was developed to characterize the temperature-dependent lifetime performance of a piezoelectric macrofiber composite (MFC). MFCs are thin rectangular patches of polyimide film, epoxy and a single layer of rectangular lead zirconium titanate (PZT) fibers. In this study, the useful life of the MFC is characterized to determine the effect of temperature on the performance of the composite as it is fatigued by cyclic piezoelectric excitation. The test specimen consists of the MFC laminated to a cantilevered stainless steel beam. Beam strain and tip displacement measurements are used as a basis for determining the performance of the MFC as it is cyclically actuated under various operating temperatures. The temperature of the beam laminate is held constant and then cycled to failure, or 250 million cycles, in order to determine the useful life of the MFC over a temperature range from - 15 to 145 °C. The results of the experiments show a strong temperature dependence of the operational life for the MFC. Damage inside the composite was identified through in situ visual inspection and during post-test microstructural observation; however, no degradation in operational performance was identified as it was cyclically actuated up to the point of failure, regardless of temperature or actuation cycle number.

Temperature Dependence Of Elastic Constants Of Polymers

NASA Technical Reports Server (NTRS)

Simha, Robert; Papazoglou, Elisabeth

1989-01-01

Two papers extend theory of elastic constants of disordered solids to finite temperatures below glass-transition temperatures. First paper, entitled "Elastic Constants of Disordered Solids II: Temperature Dependence," applies to cryogenic temperatures. Second paper, entitled "Theory of Thermoelastic Properties for Polymer Glasses," develops unified treatment for static compressional and elongational properties at temperatures up to glass-transition temperatures.

Development of a Rayleigh Scattering Diagnostic for Time-Resolved Gas Flow Velocity, Temperature, and Density Measurements in Aerodynamic Test Facilities

NASA Technical Reports Server (NTRS)

Mielke, Amy F.; Elam, Kristie A.; Sung, Chih-Jen

2007-01-01

A molecular Rayleigh scattering technique is developed to measure time-resolved gas velocity, temperature, and density in unseeded turbulent flows at sampling rates up to 32 kHz. A high power continuous-wave laser beam is focused at a point in an air flow field and Rayleigh scattered light is collected and fiber-optically transmitted to the spectral analysis and detection equipment. The spectrum of the light, which contains information about the temperature and velocity of the flow, is analyzed using a Fabry-Perot interferometer. Photomultiplier tubes operated in the photon counting mode allow high frequency sampling of the circular interference pattern to provide time-resolved flow property measurements. An acoustically driven nozzle flow is studied to validate velocity fluctuation measurements, and an asymmetric oscillating counterflow with unequal enthalpies is studied to validate the measurement of temperature fluctuations. Velocity fluctuations are compared with constant temperature anemometry measurements and temperature fluctuations are compared with constant current anemometry measurements at the same locations. Time-series and power spectra of the temperature and velocity measurements are presented. A numerical simulation of the light scattering and detection process was developed and compared with experimental data for future use as an experiment design tool.

High voltage AC/AC electrochemical capacitor operating at low temperature in salt aqueous electrolyte

NASA Astrophysics Data System (ADS)

Abbas, Qamar; Béguin, François

2016-06-01

We demonstrate that an activated carbon (AC)-based electrochemical capacitor implementing aqueous lithium sulfate electrolyte in 7:3 vol:vol water/methanol mixture can operate down to -40 °C with good electrochemical performance. Three-electrode cell investigations show that the faradaic contributions related with hydrogen chemisorption in the negative AC electrode are thermodynamically unfavored at -40 °C, enabling the system to work as a typical electrical double-layer (EDL) capacitor. After prolonged floating of the AC/AC capacitor at 1.6 V and -40°C, the capacitance, equivalent series resistance and efficiency remain constant, demonstrating the absence of ageing related with side redox reactions at this temperature. Interestingly, when temperature is increased back to 24 °C, the redox behavior due to hydrogen storage reappears and the system behaves as a freshly prepared one.

Persistent-current switch for pancake coils of rare earth-barium-copper-oxide high-temperature superconductor: Design and test results of a double-pancake coil operated in liquid nitrogen (77–65 K) and in solid nitrogen (60–57 K)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qu, Timing; Michael, Philip C.; Bascuñán, Juan

2016-08-22

We present design and test results of a superconducting persistent current switch (PCS) for pancake coils of rare-earth-barium-copper-oxide, REBCO, high-temperature superconductor (HTS). Here, a REBCO double-pancake (DP) coil, 152-mm ID, 168-mm OD, 12-mm high, was wound with a no-insulation technique. We converted a ∼10-cm long section in the outermost layer of each pancake to a PCS. The DP coil was operated in liquid nitrogen (77–65 K) and in solid nitrogen (60–57 K). Over the operating temperature ranges of this experiment, the normal-state PCS enabled the DP coil to be energized; thereupon, the PCS resumed the superconducting state and the DP coil fieldmore » decayed with a time constant of 100 h, which would have been nearly infinite, i.e., persistent-mode operation, were the joint across the coil terminals superconducting.« less

Heat pipe cooling of power processing magnetics

NASA Technical Reports Server (NTRS)

Hansen, I. G.; Chester, M.

1979-01-01

The constant demand for increased power and reduced mass has raised the internal temperature of conventionally cooled power magnetics toward the upper limit of acceptability. The conflicting demands of electrical isolation, mechanical integrity, and thermal conductivity preclude significant further advancements using conventional approaches. However, the size and mass of multikilowatt power processing systems may be further reduced by the incorporation of heat pipe cooling directly into the power magnetics. Additionally, by maintaining lower more constant temperatures, the life and reliability of the magnetic devices will be improved. A heat pipe cooled transformer and input filter have been developed for the 2.4 kW beam supply of a 30-cm ion thruster system. This development yielded a mass reduction of 40% (1.76 kg) and lower mean winding temperature (20 C lower). While these improvements are significant, preliminary designs predict even greater benefits to be realized at higher power. This paper presents the design details along with the results of thermal vacuum operation and the component performance in a 3 kW breadboard power processor.

The maximum evaporative potential of constant wear immersion suits influences the risk of excessive heat strain for helicopter aircrew

PubMed Central

2018-01-01

The heat exchange properties of aircrew clothing including a Constant Wear Immersion Suit (CWIS), and the environmental conditions in which heat strain would impair operational performance, were investigated. The maximum evaporative potential (im/clo) of six clothing ensembles (three with a flight suit (FLY) and three with a CWIS) of varying undergarment layers were measured with a heated sweating manikin. Biophysical modelling estimated the environmental conditions in which body core temperature would elevate above 38.0°C during routine flight. The im/clo was reduced with additional undergarment layers, and was more restricted in CWIS compared to FLY ensembles. A significant linear relationship (r2 = 0.98, P<0.001) was observed between im/clo and the highest wet-bulb globe temperature in which the flight scenario could be completed without body core temperature exceeding 38.0°C. These findings provide a valuable tool for clothing manufacturers and mission planners for the development and selection of CWIS’s for aircrew. PMID:29723267

Development of HIDEC adaptive engine control systems

NASA Technical Reports Server (NTRS)

Landy, R. J.; Yonke, W. A.; Stewart, J. F.

1986-01-01

The purpose of NASA's Highly Integrated Digital Electronic Control (HIDEC) flight research program is the development of integrated flight propulsion control modes, and the evaluation of their benefits aboard an F-15 test aircraft. HIDEC program phases are discussed, with attention to the Adaptive Engine Control System (ADECS I); this involves the upgrading of PW1128 engines for operation at higher engine pressure ratios and the production of greater thrust. ADECS II will involve the development of a constant thrust mode which will significantly reduce turbine operating temperatures.

Noncontact true temperature measurement, 2

NASA Technical Reports Server (NTRS)

Lee, Mark C.; Allen, James L.

1988-01-01

A laser pyrometer was developed for acquiring the true temperature of a levitated sample. The reflectivity is measured by first expanding the laser beam to cover the entire cross-sectional surface of the diffuse target. The reflectivity calibration of this system is determined from the surface emissivity of a target with a blackbody cavity. The emissivity of the real target can then be calculated. The overall system constant is obtained by passively measuring the radiance of the blackbody cavity (emissivity = 1.0) at a known, arbitrary temperature. Since the photosensor used is highly linear over the entire operating temperature range, the true temperature of the target can then be computed. The latest results available from this on-going research indicate that true temperatures thus obtained are in very good quantitative agreement with thermocouple measured temperatures.

Use of Nanostructures in Fabrication of Large Scale Electrochemical Film

NASA Astrophysics Data System (ADS)

Chen, Chien Chon; Chen, Shih Hsun; Shyu, Sheang Wen; Hsieh, Sheng Jen

Control of electrochemical parameters when preparing small-scale samples for academic research is not difficult. In mass production environments, however, maintenance of constant current density and temperature become a critical issue. This article describes the design of several molds for large work pieces. These molds were designed to maintain constant current density and to facilitate the occurrence of electrochemical reactions in designated areas. Large-area thin films with fine nanostructure were successfully prepared using the designed electrochemical molds and containers. In addition, current density and temperature could be controlled well. This electrochemical system has been verified in many experimental operations, including etching of Al surfaces; electro-polishing of Al, Ti and stainless steel; and fabrication of anodic alumina oxide (AAO), Ti-TiO2 interference membrane, TiO2 nanotubes, AAO-TiO2 nanotubes, Ni nanowires and porous tungsten

Experimental evaluation of a unique radiometer for use in solar simulation testing

NASA Technical Reports Server (NTRS)

Richmond, R. G.

1978-01-01

The vane radiometer is designed to operate over the range 0-1 solar constant and is capable of withstanding temperatures over the range -200 to +175 C. Two of these radiometers, for use in the Johnson Space Center's largest space simulator, have been evaluated for: (1) thermal sensitivity with no solar input, (2) linearity as a function of solar simulation input, and (3) output drift as a function of time. The minimum sensitivity was measured to be approximately 25.5 mV/solar constant. An unusual effect in the pressure range 760 to 1.0 torr is discussed.

Effect of fabrication process on physical and mechanical properties of tungsten carbide - cobalt composite: A review

NASA Astrophysics Data System (ADS)

Mahaidin, Ahmad Aswad; Jaafar, Talib Ria; Selamat, Mohd Asri; Budin, Salina; Sulaiman, Zaim Syazwan; Hamid, Mohamad Hasnan Abdul

2017-12-01

WC-Co, which is also known as cemented carbide, is widely used in metal cutting industry and wear related application due to their excellent mechanical properties. Manufacturing industries are focusing on improving productivity and reducing operational cost with machining operation is considered as one of the factors. Thus, machining conditions are becoming more severe and required better cutting tool bit with improved mechanical properties to withstand high temperature operation. Numerous studies have been made over the generation for further improvement of cemented carbide properties to meet the constant increase in demand. However, the results of these studies vary due to different process parameters and manufacturing technology. This paper summarizes the studies to improve the properties of WC-Co composite using different consolidation (powder size, mixing method, formulation, etc) and sintering parameters (temperature, time, atmosphere, etc).

High-temperature langatate elastic constants and experimental validation up to 900 degrees C.

PubMed

Davulis, Peter M; da Cunha, Mauricio Pereira

2010-01-01

This paper reports on a set of langatate (LGT) elastic constants extracted from room temperature to 1100 degrees C using resonant ultrasound spectroscopy techniques and an accompanying assessment of these constants at high temperature. The evaluation of the constants employed SAW device measurements from room temperature to 900 degrees C along 6 different LGT wafer orientations. Langatate parallelepipeds and wafers were aligned, cut, ground, and polished, and acoustic wave devices were fabricated at the University of Maine facilities along specific orientations for elastic constant extraction and validation. SAW delay lines were fabricated on LGT wafers prepared at the University of Maine using 100-nm platinumrhodium- zirconia electrodes capable of withstanding temperatures up to 1000 degrees C. The numerical predictions based on the resonant ultrasound spectroscopy high-temperature constants were compared with SAW phase velocity, fractional frequency variation, and temperature coefficients of delay extracted from SAW delay line frequency response measurements. In particular, the difference between measured and predicted fractional frequency variation is less than 2% over the 25 degrees C to 900 degrees C temperature range and within the calculated and measured discrepancies. Multiple temperature-compensated orientations at high temperature were predicted and verified in this paper: 4 of the measured orientations had turnover temperatures (temperature coefficient of delay = 0) between 200 and 420 degrees C, and 2 had turnover temperatures below 100 degrees C. In summary, this work reports on extracted high-temperature elastic constants for LGT up to 1100 degrees C, confirmed the validity of those constants by high-temperature SAW device measurements up to 900 degrees C, and predicted and identified temperature-compensated LGT orientations at high temperature.

Constant diurnal temperature regime alters the impact of simulated climate warming on a tropical pseudoscorpion

NASA Astrophysics Data System (ADS)

Zeh, Jeanne A.; Bonilla, Melvin M.; Su, Eleanor J.; Padua, Michael V.; Anderson, Rachel V.; Zeh, David W.

2014-01-01

Recent theory suggests that global warming may be catastrophic for tropical ectotherms. Although most studies addressing temperature effects in ectotherms utilize constant temperatures, Jensen's inequality and thermal stress considerations predict that this approach will underestimate warming effects on species experiencing daily temperature fluctuations in nature. Here, we tested this prediction in a neotropical pseudoscorpion. Nymphs were reared in control and high-temperature treatments under a constant daily temperature regime, and results compared to a companion fluctuating-temperature study. At constant temperature, pseudoscorpions outperformed their fluctuating-temperature counterparts. Individuals were larger, developed faster, and males produced more sperm, and females more embryos. The greatest impact of temperature regime involved short-term, adult exposure, with constant temperature mitigating high-temperature effects on reproductive traits. Our findings demonstrate the importance of realistic temperature regimes in climate warming studies, and suggest that exploitation of microhabitats that dampen temperature oscillations may be critical in avoiding extinction as tropical climates warm.

SWIFT BAT Loop Heat Pipe Thermal System Characteristics and Ground/Flight Operation Procedure

NASA Technical Reports Server (NTRS)

Choi, Michael K.

2003-01-01

The SWIFT Burst Alert Telescope (BAT) Detector Array has a total power dissipation of 208 W. To meet the stringent temperature gradient and thermal stability requirements in the normal operational mode, and heater power budget in both the normal operational and safehold modes, the Detector Array is thermally well coupled to eight constant conductance heat pipes (CCHPs) embedded in the Detector Array Plate (DAP), and two loop heat pipes (LHPs) transport heat fiom the CCHPs to a radiator. The CCHPs have ammonia as the working fluid and the LHPs have propylene as the working fluid. Precision heater controllers, which have adjustable set points in flight, are used to control the LHP compensation chamber and Detector Array XA1 ASIC temperatures. The radiator has the AZ-Tek AZW-LA-II low-alpha white paint as the thermal coating and is located on the anti-sun side of the spacecraft. This paper presents the characteristics, ground operation and flight operation procedures of the LHP thermal system.

A Compact, Continuous Adiabatic Demagnetization Refrigerator with High Heat Sink Temperature

NASA Technical Reports Server (NTRS)

Shirron, P. J.; Canavan, E. R.; DiPirro, M. J.; Jackson, M.; Tuttle, J. G.

2003-01-01

In the continuous adiabatic demagnetization refrigerator (ADR), the existence of a constant temperature stage attached to the load breaks the link between the requirements of the load (usually a detector array) and the operation of the ADR. This allows the ADR to be cycled much faster, which yields more than an order of magnitude improvement in cooling power density over single-shot ADRs. Recent effort has focused on developing compact, efficient higher temperature stages. An important part of this work has been the development of passive gas-gap heat switches that transition (from conductive to insulating) at temperatures around 1 K and 4 K without the use of an actively heated getter. We have found that by carefully adjusting available surface area and the number of He-3 monolayers, gas-gap switches can be made to operate passively. Passive operation greatly reduces switching time and eliminates an important parasitic heat load. The current four stage ADR provides 6 micro W of cooling at 50 mK (21 micro W at 100 mK) and weighs less than 8 kg. It operates from a 4.2 K heat sink, which can be provided by an unpumped He bath or many commercially available mechanical cryocoolers. Reduction in critical current with temperature in our fourth stage NbTi magnet presently limits the maximum temperature of our system to approx. 5 K. We are developing compact, low-current Nb3Sn magnets that will raise the maximum heat sink temperature to over 10 K.

Time and Space Resolved Heat Transfer Measurements Under Nucleate Bubbles with Constant Heat Flux Boundary Conditions

NASA Technical Reports Server (NTRS)

Myers, Jerry G.; Hussey, Sam W.; Yee, Glenda F.; Kim, Jungho

2003-01-01

Investigations into single bubble pool boiling phenomena are often complicated by the difficulties in obtaining time and space resolved information in the bubble region. This usually occurs because the heaters and diagnostics used to measure heat transfer data are often on the order of, or larger than, the bubble characteristic length or region of influence. This has contributed to the development of many different and sometimes contradictory models of pool boiling phenomena and dominant heat transfer mechanisms. Recent investigations by Yaddanapyddi and Kim and Demiray and Kim have obtained time and space resolved heat transfer information at the bubble/heater interface under constant temperature conditions using a novel micro-heater array (10x10 array, each heater 100 microns on a side) that is semi-transparent and doubles as a measurement sensor. By using active feedback to maintain a state of constant temperature at the heater surface, they showed that the area of influence of bubbles generated in FC-72 was much smaller than predicted by standard models and that micro-conduction/micro-convection due to re-wetting dominated heat transfer effects. This study seeks to expand on the previous work by making time and space resolved measurements under bubbles nucleating on a micro-heater array operated under constant heat flux conditions. In the planned investigation, wall temperature measurements made under a single bubble nucleation site will be synchronized with high-speed video to allow analysis of the bubble energy removal from the wall.

Spacecraft Charging in Low Temperature Environments

NASA Technical Reports Server (NTRS)

Parker, Linda N.

2007-01-01

Spacecraft charging in plasma and radiation environments is a temperature dependent phenomenon due to the reduction of electrical conductivity in dielectric materials at low temperatures. Charging time constants are proportional to l/conductivity may become very large (on the order of days to years) at low temperatures and accumulation of charge densities in insulators in charging environments traditionally considered benign at ambient temperatures may be sufficient to produce charge densities and electric fields of concern in insulators at low temperatures. Low temperature charging is of interest because a number of spacecraft-primarily infrared astronomy and microwave cosmology observatories-are currently being design, built, and or operated at very cold temperatures on the order of 40K to 100K. This paper reviews the temperature dependence of spacecraft charging processes and material parameters important to charging as a function of temperature with an emphasis on low temperatures regimes.

Chiral symmetry restoration at finite temperature and chemical potential in the improved ladder approximation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taniguchi, Y.; Yoshida, Y.

1997-02-01

The chiral symmetry of QCD is studied at finite temperature and chemical potential using the Schwinger-Dyson equation in the improved ladder approximation. We calculate three order parameters: the vacuum expectation value of the quark bilinear operator, the pion decay constant, and the quark mass gap. We have a second order phase transition at the temperature T{sub c}=169 MeV along the zero chemical potential line, and a first order phase transition at the chemical potential {mu}{sub c}=598 MeV along the zero temperature line. We also calculate the critical exponents of the three order parameters. {copyright} {ital 1997} {ital The American Physicalmore » Society}« less

Combustion characteristics of gas turbine alternative fuels

NASA Technical Reports Server (NTRS)

Rollbuhler, R. James

1987-01-01

An experimental investigation was conducted to obtain combustion performance values for specific heavyend, synthetic hydrocarbon fuels. A flame tube combustor modified to duplicate an advanced gas turbine engine combustor was used for the tests. Each fuel was tested at steady-state operating conditions over a range of mass flow rates, fuel-to-air mass ratio, and inlet air temperatures. The combustion pressure, as well as the hardware, were kept nearly constant over the program test phase. Test results were obtained in regards to geometric temperature pattern factors as a function of combustor wall temperatures, the combustion gas temperature, and the combustion emissions, both as affected by the mass flow rate and fuel-to-air ratio. The synthetic fuels were reacted in the combustor such that for most tests their performance was as good, if not better, than the baseline gasoline or diesel fuel tests. The only detrimental effects were that at high inlet air temperature conditions, fuel decomposition occurred in the fuel atomizing nozzle passages resulting in blockage. And the nitrogen oxide emissions were above EPA limits at low flow rate and high operating temperature conditions.

Facile Quantification and Identification Techniques for Reducing Gases over a Wide Concentration Range Using a MOS Sensor in Temperature-Cycled Operation.

PubMed

Schultealbert, Caroline; Baur, Tobias; Schütze, Andreas; Sauerwald, Tilman

2018-03-01

Dedicated methods for quantification and identification of reducing gases based on model-based temperature-cycled operation (TCO) using a single commercial MOS gas sensor are presented. During high temperature phases the sensor surface is highly oxidized, yielding a significant sensitivity increase after switching to lower temperatures (differential surface reduction, DSR). For low concentrations, the slope of the logarithmic conductance during this low-temperature phase is evaluated and can directly be used for quantification. For higher concentrations, the time constant for reaching a stable conductance during the same low-temperature phase is evaluated. Both signals represent the reaction rate of the reducing gas on the strongly oxidized surface at this low temperature and provide a linear calibration curve, which is exceptional for MOS sensors. By determining these reaction rates on different low-temperature plateaus and applying pattern recognition, the resulting footprint can be used for identification of different gases. All methods are tested over a wide concentration range from 10 ppb to 100 ppm (4 orders of magnitude) for four different reducing gases (CO, H₂, ammonia and benzene) using randomized gas exposures.

Facile Quantification and Identification Techniques for Reducing Gases over a Wide Concentration Range Using a MOS Sensor in Temperature-Cycled Operation

PubMed Central

Schultealbert, Caroline; Baur, Tobias; Schütze, Andreas; Sauerwald, Tilman

2018-01-01

Dedicated methods for quantification and identification of reducing gases based on model-based temperature-cycled operation (TCO) using a single commercial MOS gas sensor are presented. During high temperature phases the sensor surface is highly oxidized, yielding a significant sensitivity increase after switching to lower temperatures (differential surface reduction, DSR). For low concentrations, the slope of the logarithmic conductance during this low-temperature phase is evaluated and can directly be used for quantification. For higher concentrations, the time constant for reaching a stable conductance during the same low-temperature phase is evaluated. Both signals represent the reaction rate of the reducing gas on the strongly oxidized surface at this low temperature and provide a linear calibration curve, which is exceptional for MOS sensors. By determining these reaction rates on different low-temperature plateaus and applying pattern recognition, the resulting footprint can be used for identification of different gases. All methods are tested over a wide concentration range from 10 ppb to 100 ppm (4 orders of magnitude) for four different reducing gases (CO, H2, ammonia and benzene) using randomized gas exposures. PMID:29494545

Advanced ceramic coating development for industrial/utility gas turbine applications

NASA Technical Reports Server (NTRS)

Andersson, C. A.; Lau, S. K.; Bratton, R. J.; Lee, S. Y.; Rieke, K. L.; Allen, J.; Munson, K. E.

1982-01-01

The effects of ceramic coatings on the lifetimes of metal turbine components and on the performance of a utility turbine, as well as of the turbine operational cycle on the ceramic coatings were determined. When operating the turbine under conditions of constant cooling flow, the first row blades run 55K cooler, and as a result, have 10 times the creep rupture life, 10 times the low cycle fatigue life and twice the corrosion life with only slight decreases in both specific power and efficiency. When operating the turbine at constant metal temperature and reduced cooling flow, both specific power and efficiency increases, with no change in component lifetime. The most severe thermal transient of the turbine causes the coating bond stresses to approach 60% of the bond strengths. Ceramic coating failures was studied. Analytic models based on fracture mechanics theories, combined with measured properties quantitatively assessed both single and multiple thermal cycle failures which allowed the prediction of coating lifetime. Qualitative models for corrosion failures are also presented.

BISON Fuel Performance Analysis of FeCrAl cladding with updated properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sweet, Ryan; George, Nathan M.; Terrani, Kurt A.

2016-08-30

In order to improve the accident tolerance of light water reactor (LWR) fuel, alternative cladding materials have been proposed to replace zirconium (Zr)-based alloys. Of these materials, there is a particular focus on iron-chromium-aluminum (FeCrAl) alloys due to much slower oxidation kinetics in high-temperature steam than Zr-alloys. This should decrease the energy release due to oxidation and allow the cladding to remain integral longer in the presence of high temperature steam, making accident mitigation more likely. As a continuation of the development for these alloys, suitability for normal operation must also be demonstrated. This research is focused on modeling themore » integral thermo-mechanical performance of FeCrAl-cladded fuel during normal reactor operation. Preliminary analysis has been performed to assess FeCrAl alloys (namely Alkrothal 720 and APMT) as a suitable fuel cladding replacement for Zr-alloys, using the MOOSE-based, finite-element fuel performance code BISON and the best available thermal-mechanical and irradiation-induced constitutive properties. These simulations identify the effects of the mechanical-stress and irradiation response of FeCrAl, and provide a comparison with Zr-alloys. In comparing these clad materials, fuel rods have been simulated for normal reactor operation and simple steady-state operation. Normal reactor operating conditions target the cladding performance over the rod lifetime (~4 cycles) for the highest-power rod in the highest-power fuel assembly under reactor power maneuvering. The power histories and axial temperature profiles input into BISON were generated from a neutronics study on full-core reactivity equivalence for FeCrAl using the 3D full core simulator NESTLE. Evolution of the FeCrAl cladding behavior over time is evaluated by using steady-state operating conditions such as a simple axial power profile, a constant cladding surface temperature, and a constant fuel power history. The fuel rod designs and operating conditions used are based off the Peach Bottom BWR and design consideration was given to minimize the neutronic penalty of the FeCrAl cladding by changing fuel enrichment and cladding thickness. As this study progressed, systematic parametric analysis of the fuel and cladding creep responses were also performed.« less

Pulse echo and combined resonance techniques: a full set of LGT acoustic wave constants and temperature coefficients.

PubMed

Sturtevant, Blake T; Davulis, Peter M; da Cunha, Mauricio Pereira

2009-04-01

This work reports on the determination of langatate elastic and piezoelectric constants and their associated temperature coefficients employing 2 independent methods, the pulse echo overlap (PEO) and a combined resonance technique (CRT) to measure bulk acoustic wave (BAW) phase velocities. Details on the measurement techniques are provided and discussed, including the analysis of the couplant material in the PEO technique used to couple signal to the sample, which showed to be an order of magnitude more relevant than the experimental errors involved in the data extraction. At room temperature, elastic and piezoelectric constants were extracted by the PEO and the CRT methods and showed results consistent to within a few percent for the elastic constants. Both raw acquired data and optimized constants, based on minimization routines applied to all the modes involved in the measurements, are provided and discussed. Comparison between the elastic constants and their temperature behavior with the literature reveals the recent efforts toward the consistent growth and characterization of LGT, in spite of significant variations (between 1 and 30%) among the constants extracted by different groups at room temperature. The density, dielectric permittivity constants, and respective temperature coefficients used in this work have also been independently determined based on samples from the same crystal boule. The temperature behavior of the BAW modes was extracted using the CRT technique, which has the advantage of not relying on temperature dependent acoustic couplants. Finally, the extracted temperature coefficients for the elastic and piezoelectric constants between room temperature and 120 degrees C are reported and discussed in this work.

Life History Characteristics of Frankliniella occidentalis and Frankliniella intonsa (Thysanoptera: Thripidae) in Constant and Fluctuating Temperatures.

PubMed

Ullah, Mohammad Shaef; Lim, Un Taek

2015-06-01

Frankliniella occidentalis (Pergande) and Frankliniella intonsa (Trybom) are sympatric pests of many greenhouse and field crops in Korea. We compared the influence of constant (27.3°C) and fluctuating temperatures (23.8-31.5°C, with an average of 27.3°C) on the life table characteristics of F. occidentalis and F. intonsa held at a photoperiod of 16:8 (L:D) h and 45±5% relative humidity. The development times of both F. occidentalis and F. intonsa were significantly affected by temperature fluctuation, species, and sex. The development time from egg to adult of F. intonsa was shorter than that for F. occidentalis at both constant and fluctuating temperatures. Survival of immature life stages was higher under fluctuating than constant temperature for both thrips species. The total and daily production of first instars was higher in F. intonsa (90.4 and 4.2 at constant temperature, and 95.7 and 3.9 at fluctuating temperatures) than that of F. occidentalis (58.7 and 3.3 at constant temperature, and 60.5 and 3.1 at fluctuating temperatures) under both constant and fluctuating temperatures. The percentage of female offspring was greater in F. intonsa (72.1-75.7%) than in F. occidentalis (57.4-58.7%) under both temperature regimes. The intrinsic rate of natural increase (rm) was higher at constant temperature than at fluctuating temperature for both thrips species. F. intonsa had a higher rm value (0.2146 and 0.2004) than did F. occidentalis (0.1808 and 0.1733), under both constant and fluctuating temperatures, respectively. The biological response of F. occidentalis and F. intonsa to constant and fluctuating temperature was found to be interspecifically different, and F. intonsa may have higher pest potential than F. occidentalis based on the life table parameters we are reporting first here. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Optimization of a HOT LWIR HgCdTe Photodiode for Fast Response and High Detectivity in Zero-Bias Operation Mode

NASA Astrophysics Data System (ADS)

Kopytko, M.; Kębłowski, A.; Madejczyk, P.; Martyniuk, P.; Piotrowski, J.; Gawron, W.; Grodecki, K.; Jóźwikowski, K.; Rutkowski, J.

2017-10-01

Fast response is an important property of infrared detectors for many applications. Currently, high-temperature long-wavelength infrared HgCdTe heterostructure photodiodes exhibit subnanosecond time constants while operating under reverse bias. However, nonequilibrium devices exhibit excessive low-frequency 1/ f noise that extends up to MHz range, representing a severe obstacle to their widespread application. Present efforts are focused on zero-bias operation of photodiodes. Unfortunately, the time constant of unbiased photodiodes is still at the level of several nanoseconds. We present herein a theoretical investigation of device design for improved response time and detectivity of long-wavelength infrared HgCdTe photodiodes operating at 230 K in zero-bias mode. The calculation results show that highly doped p-type HgCdTe is the absorber material of choice for fast photodiodes due to its high electron diffusion coefficient. The detectivity of such a device can also be optimized by using absorber doping of N A = 1 × 1017 cm-3. Reduction of the thickness is yet another approach to improve the device response. Time constant below 1 ns is achieved for an unbiased photodiode with absorber thickness below 4 μm. A tradeoff between the contradictory requirements of achieving high detectivity and fast response time is expected in an optically immersed photodiode with very small active area.

An acoustic backscatter thermometer for remotely mapping seafloor water temperature

NASA Astrophysics Data System (ADS)

Jackson, Darrell R.; Dworski, J. George

1992-01-01

A bottom-mounted, circularly scanning sonar operating at 40 kHz has been used to map changes in water sound speed over a circular region 150 m in diameter. If it is assumed that the salinity remains constant, the change in sound speed can be converted to a change in temperature. For the present system, the spatial resolution is 7.5 m and the temperature resolution is 0.05°C. The technique is based on comparison of successive sonar scans by means of a correlation algorithm. The algorithm is illustrated using data from the Sediment Transport Events on Slopes and Shelves (STRESS) experiment.

Transient performance and temperature field of a natural convection air dehumidifier loop

NASA Astrophysics Data System (ADS)

Fazilati, Mohammad Ali; Sedaghat, Ahmad; Alemrajabi, Ali-Akbar

2017-07-01

In this paper, transient performance of the previously introduced natural convection heat and mass transfer loop is investigated for an air dehumidifier system. The performance of the loop is studied in different conditions of heat source/heat sink temperature and different startup desiccant concentrations. Unlike conventional loops, it is observed that natural convection of the fluid originates from the heat sink towards the heat source. The proper operation of the cycle is highly dependent on the heat sink/heat source temperatures. To reduce the time constant of the system, a proper desiccant concentration should be adopted for charge of the loop.

Instanton rate constant calculations close to and above the crossover temperature.

PubMed

McConnell, Sean; Kästner, Johannes

2017-11-15

Canonical instanton theory is known to overestimate the rate constant close to a system-dependent crossover temperature and is inapplicable above that temperature. We compare the accuracy of the reaction rate constants calculated using recent semi-classical rate expressions to those from canonical instanton theory. We show that rate constants calculated purely from solving the stability matrix for the action in degrees of freedom orthogonal to the instanton path is not applicable at arbitrarily low temperatures and use two methods to overcome this. Furthermore, as a by-product of the developed methods, we derive a simple correction to canonical instanton theory that can alleviate this known overestimation of rate constants close to the crossover temperature. The combined methods accurately reproduce the rate constants of the canonical theory along the whole temperature range without the spurious overestimation near the crossover temperature. We calculate and compare rate constants on three different reactions: H in the Müller-Brown potential, methylhydroxycarbene → acetaldehyde and H 2  + OH → H + H 2 O. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

Temperature-dependent elastic anisotropy and mesoscale deformation in a nanostructured ferritic alloy

DOE PAGES

Stoica, G. M.; Stoica, A. D.; Miller, M. K.; ...

2014-10-10

Nanostructured ferritic alloys (NFA) are a new class of ultrafine-grained oxide dispersion-strengthened steels, promising for service in extreme environments of high temperature and high irradiation in the next-generation of nuclear reactors. This is owing to the remarkable stability of their complex microstructures containing a high density of Y-Ti-O nanoclusters within grains and along the grain boundaries. While nanoclusters have been recognized to be the primary contributor to the exceptional resistance to irradiation and high-temperature creep, very little is known about the mechanical roles of the polycrystalline grains that constitute the bulk ferritic matrix. Here we report the mesoscale characterization ofmore » anisotropic responses of the ultrafine NFA grains to tensile stresses at various temperatures using the state-of-the-art in situ neutron diffraction. We show the first experimental determination of temperature-dependent single-crystal elastic constants for the NFA, and reveal a strong temperature-dependent elastic anisotropy due to a sharp decrease in the shear stiffness constant [c'=(c_11-c_12)/2] when a critical temperature ( T_c ) is approached, indicative of elastic softening and instability of the ferritic matrix. We also show, from anisotropy-induced intergranular strain/stress accumulations, that a common dislocation slip mechanism operates at the onset of yielding for low temperatures, while there is a deformation crossover from low-temperature lattice hardening to high temperature lattice softening in response to extensive plastic deformation.« less

Temperature effects on MIPs in the BGO calorimeters of DAMPE

NASA Astrophysics Data System (ADS)

Wang, Yuan-Peng; Wen, Si-Cheng; Jiang, Wei; Yue, Chuan; Zhang, Zhi-Yong; Wei, Yi-Feng; Zhang, YunLong; Zang, Jing-Jing; Wu, Jian

2017-10-01

In this paper, we present a study of temperature effects on BGO calorimeters using proton MIPs collected in the first year of operation of DAMPE. By directly comparing MIP calibration constants used by the DAMPE data production pipe line, we find an experimental relation between the temperature and signal amplitudes of each BGO bar: a general deviation of -1.162%/°C, and -0.47%/°C to -1.60%/°C statistically for each detector element. During 2016, DAMPE’s temperature changed by ˜8°C due to solar elevation angle, and the corresponding energy scale bias is about 9%. By frequent MIP calibration operation, this kind of bias is eliminated to an acceptable value. This work was supported by National Key Program for Research and Development (No. 2016YFA0400200) and by NSFC (11303105, 11673021). The DAMPE mission was funded by the strategic priority science and technology projects in space science of the Chinese Academy of Sciences (No. XDA04040000 and No. XDA04040400)

Analysis of a Temperature-Controlled Exhaust Thermoelectric Generator During a Driving Cycle

NASA Astrophysics Data System (ADS)

Brito, F. P.; Alves, A.; Pires, J. M.; Martins, L. B.; Martins, J.; Oliveira, J.; Teixeira, J.; Goncalves, L. M.; Hall, M. J.

2016-03-01

Thermoelectric generators can be used in automotive exhaust energy recovery. As car engines operate under wide variable loads, it is a challenge to design a system for operating efficiently under these variable conditions. This means being able to avoid excessive thermal dilution under low engine loads and being able to operate under high load, high temperature events without the need to deflect the exhaust gases with bypass systems. The authors have previously proposed a thermoelectric generator (TEG) concept with temperature control based on the operating principle of the variable conductance heat pipe/thermosiphon. This strategy allows the TEG modules’ hot face to work under constant, optimized temperature. The variable engine load will only affect the number of modules exposed to the heat source, not the heat transfer temperature. This prevents module overheating under high engine loads and avoids thermal dilution under low engine loads. The present work assesses the merit of the aforementioned approach by analysing the generator output during driving cycles simulated with an energy model of a light vehicle. For the baseline evaporator and condenser configuration, the driving cycle averaged electrical power outputs were approximately 320 W and 550 W for the type-approval Worldwide harmonized light vehicles test procedure Class 3 driving cycle and for a real-world highway driving cycle, respectively.

Corrosion of type 316L stainless steel in a mercury thermal convection loop

DOE Office of Scientific and Technical Information (OSTI.GOV)

DiStefano, J.R.; Manneschmidt, E.T.; Pawel, S.J.

1999-04-01

Two thermal convection loops fabricated from 316L stainless steel containing mercury (Hg) and Hg with 1000 wppm gallium (Ga), respectively, were operated continuously for about 5000 h. In each case, the maximum loop temperature was constant at about 305 degrees C and the minimum temperature was constant at about 242 degrees C. Coupons in the hot leg of the Hg-loop developed a posous surface layer substantially depleted of nickel and chromium, which resulted in a transformation to ferrite. The coupon exposed at the top of the hot leg in the Hg-loop experienced the maximum degradation, exhibiting a surface layer extendingmore » an average of 9-10 mu m after almost 5000 h. Analysis of the corrosion rate data as a function of temperature (position) in the Hg-loop suggests wetting by the mer cury occurred only above about 255 degrees C and that the rate limiting step in the corrosion process above 255 degrees C is solute diffusion through the saturated liquid boundary layer adjacent to the corroding surface. The latter factor suggests that the corrosion of 316L stainless steel in a mercury loop may be velocity dependent. No wetting and no corrosion were observed on the coupons and wall specimens removed from the Hg/Ga loop after 5000 h of operation.« less

Long-time dynamic compatibility of elastomeric materials with hydrazine

NASA Technical Reports Server (NTRS)

Coulbert, C. D.; Cuddihy, E. F.; Fedors, R. F.

1973-01-01

The tensile property surfaces for two elastomeric materials, EPT-10 and AF-E-332, were generated in air and in liquid hydrazine environments using constant strain rate tensile tests over a range of temperatures and elongation rates. These results were used to predict the time-to-rupture for these materials in hydrazine as a function of temperature and amount of strain covering a span of operating times from less than a minute to twenty years. The results of limited sheet-folding tests and their relationship to the tensile failure boundary are presented and discussed.

A Description of Methodologies Used in Estimation of A-Weighted Sound Levels for FAA Advisory Circular AC-36-3B.

DTIC Science & Technology

1982-01-01

second) Dia propeller diameter (expressed in inches) T°F air temperature in degrees Farenheit T°C air temperature in degrees Celsius T:dBA total dBA...eMpiriC31 function to the absolute noise level ordinate. The term 240 log ( MH is the most sensitive and important part of the equation. The constant (240...standard day, zero wind, dry, zero gradient runway, at a sea level airport. 2. All aircraft operate at maximum takeoff gross weight. 3. All aircraft climb

Detection near 1-nm with a laminar-flow, water-based condensation particle counter

DOE PAGES

Hering, Susanne V.; Lewis, Gregory S.; Spielman, Steven R.; ...

2016-11-18

Presented is a laminar-flow, water-based condensation particle counter capable of particle detection near 1 nm. This instrument employs a three-stage, laminar-flow growth tube with a “moderator” stage that reduces the temperature and water content of the output flow without reducing the peak supersaturation, and makes feasible operation at the large temperature differences necessary for achieving high supersaturations. The instrument has an aerosol flow of 0.3 L/min, and does not use a filtered sheath flow. It is referred to as a “versatile” water condensation particle counter, or vWCPC, as operating temperatures can be adjusted in accordance with the cut-point desired. Whenmore » operated with wall temperatures of ~2°C, >90°C, and ~22°C for the three stages, respectively, the vWCPC detects particles generated from a heated nichrome wire with a 50% efficiency cut-point near 1.6 nm mobility diameter. At these operating temperatures, it also detects 10–20% of large molecular ions formed from passing filtered ambient air through a bipolar ion source. Decreasing the temperature difference between the first two stages, with the first and second stages operated at 10 and 90°C, respectively, essentially eliminates the response to charger ions, and raises the 50% efficiency cut-point for the nichrome wire particles to 1.9 nm mobility diameter. Here, the time response, as measured by rapid removal of an inlet filter, yields a characteristic time constant of 195 ms.« less

Performance Study of Fluidized Bed Dryer with Immersed Heater for Paddy Drying

NASA Astrophysics Data System (ADS)

Suherman, S.; Azaria, N. F.; Karami, S.

2018-03-01

This paper investigated the performance of fluidized bed dryer with immersed heater for paddy drying. The influence of drying temperature and the temperature of immersed heater on drying curve, thermal efficiency, and quality of paddy was investigated. The fixed operating conditions are drying time of 60 minutes, paddy weight of 200 grams and the air velocity of 0.4 m/s. The variables are drying temperature and the temperature immersed heater namely 50, 60, 70, 80, 90 (°C). The results show addition immersed heater will increase drying rates. No constant drying rate was found. Increasing the temperature will decrease the utilized energy. The thermal efficiency decreases with increasing temperature. The increasing temperature and use immersed heater will decrease the residual moisture content, increase damaged and yellow paddy grain, and increase red paddy grain.

Noncontact true temperature measurement. [of levitated sample using laser pyrometer

NASA Technical Reports Server (NTRS)

Lee, Mark C.; Allen, James L.

1987-01-01

A laser pyrometer has been developed for acquiring the true temperature of a levitated sample. The laser beam is first expanded to cover the entire cross-sectional surface of the target. For calibration of such a system, the reflectivity signal of an ideal 0.95 cm diameter gold-coated sphere (reflectivity = 0.99) is used as the reference for any other real targets. The emissivity of the real target can then be calculated. The overall system constant is obtained by passively measuring the radiance of a blackbody furnace (emissivity = 1.0) at a known, arbitrary temperature. Since the photo sensor used is highly linear over the entire operating temperature range, the true temperature of the target can then be computed. Preliminary results indicate that true temperatures thus obtained are in excellent correlation with thermocouple measured temperatures.

Optimizing the CSP Tower Air Brayton Cycle System to Meet the SunShot Objectives - Final Technical Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bryner, Elliott; Brun, Klaus; Coogan, Shane

The objective of this project is to increase Concentrated Solar Power (CSP) tower air receiver and gas turbine temperature capabilities to 1,000ºC by the development of a novel gas turbine combustor, which can be integrated on a megawatt-scale gas turbine, such as the Solar Turbines Mercury 50™. No combustor technology currently available is compatible with the CSP application target inlet air temperature of 1,000°C. Autoignition and flashback at this temperature prevent the use of conventional lean pre-mix injectors that are currently employed to manage NOx emissions. Additional challenges are introduced by the variability of the high-temperature heat source provided bymore » the field of solar collectors, the heliostat in CSP plants. For optimum energy generation from the power turbine, the turbine rotor inlet temperature (TRIT) should remain constant. As a result of changing heat load provided to the solar collector from the heliostat, the amount of energy input required from the combustion system must be adjusted to compensate. A novel multi-bank lean micro-mix injector has been designed and built to address the challenges of high-temperature combustion found in CSP applications. The multi-bank arrangement of the micro-mix injector selectively injects fuel to meet the heat addition requirements to maintain constant TRIT with changing solar load. To validate the design, operation, and performance of the multi-bank lean micro-mix injector, a novel combustion test facility has been designed and built at Southwest Research Institute® (SwRI®) in San Antonio, TX. This facility, located in the Turbomachinery Research Facility, provides in excess of two kilograms per second of compressed air at nearly eight bar pressure. A two-megawatt electric heater raises the inlet temperature to 800°C while a secondary gas-fired heater extends the operational temperature range of the facility to 1,000°C. A combustor test rig connected to the heater has been designed and built to test the multi-bank lean micro-mix injector over the range of CSP operating conditions. The fuel is controlled and selectively delivered to the banks of the injector based on combustor inlet conditions that correspond to turbine operating points. The combustor rig is equipped with a data acquisition system and a suite of instrumentation for measuring temperature, pressure, and species concentration. This unique test facility has been built and commissioned and a prototype of the multi-bank lean micro-mix injector design has been tested. Operation of the combustor and injector has been demonstrated over the full range of CSP inlet conditions and for the range of turbine load conditions specified. The multi-bank operation of the injector has been proven to be an effective design for managing the variable flow rates of air and fuel due to changing inlet conditions from the solar field and turbine loads.« less

Norbornylene-based polymer systems for dielectric applications

DOEpatents

Dirk, Shawn M [Albuquerque, NM; Wheeler, David R [Albuquerque, NM

2012-07-17

A capacitor having at least one electrode pair being separated by a dielectric component, with the dielectric component being made of a polymer such as a norbornylene-containing polymer with a dielectric constant greater than 3 and a dissipation factor less than 0.1 where the capacitor has an operating temperature greater than 100.degree. C. and less than 170.degree. C.

Calculations of rate constants for the three-body recombination of H2 in the presence of H2

NASA Technical Reports Server (NTRS)

Schwenke, David W.

1988-01-01

A new global potential energy hypersurface for H2 + H2 is constructed and quasiclassical trajectory calculations performed using the resonance complex theory and energy transfer mechanism to estimate the rate of three body recombination over the temperature range 100 to 5000 K. The new potential is a faithful representation of ab initio electron structure calculations, is unchanged under the operation of exchanging H atoms, and reproduces the accurate H3 potential as one H atom is pulled away. Included in the fitting procedure are geometries expected to be important when one H2 is near or above the dissociation limit. The dynamics calculations explicitly include the motion of all four atoms and are performed efficiently using a vectorized variable-stepsize integrator. The predicted rate constants are approximately a factor of two smaller than experimental estimates over a broad temperature range.

On the phase diagram of water with density functional theory potentials: the melting temperature of Ice I-h with the Perdew-Burke-Ernzerhof and Becke-Lee-Yang-Parr functionals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoo, Soohaeng; Zeng, Xiao Cheng; Xantheas, Sotiris S.

2009-06-11

The melting temperature (Tm) of ice Ih was determined from constant enthalphy (NPH) Born-Oppenheimer Molecular Dynamics (BOMD) simulations to be 417±3 K for the Perdew-Burke-Ernzerhof (PBE) and 411±4 K for the Becke-Lee-Yang-Parr (BLYP) density functionals using a coexisting ice (Ih)-liquid phase at constant pressures of P = 2,500 and 10,000 bar and a density ρ = 1 g/cm3, respectively. This suggests that ambient condition simulations at ρ = 1 g/cm3 will rather describe a supercooled state that is overstructured when compared to liquid water. This work was supported by the US Department of Energy Office of Basic Energy Sciences' Chemicalmore » Sciences program. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.« less

Effects of constant and fluctuating temperature on the development of the oriental fruit moth, Grapholita molesta (Lepidoptera: Tortricidae).

PubMed

Chen, Z-Z; Xu, L-X; Li, L-L; Wu, H-B; Xu, Y-Y

2018-06-21

The oriental fruit moth, Grapholita molesta, is an important pest in many commercial orchards including apple, pear and peach orchards, and responsible for substantial economic losses every year. To help in attaining a comprehensive and thorough understanding of the ecological tolerances of G. molesta, we collected life history data of individuals reared on apples under different constant temperature regimes and compared the data with moths reared under a variable outdoor temperature environment. Because G. molesta individuals reared at a constant 25°C had the heaviest pupal weight, the highest survival rate from egg to adult, highest finite rate of increase, and greatest fecundity, 25°C was considered as the optimum developmental temperature. The G. molesta population reared at a constant 31°C had the shortest development time, lowest survival rate and fecundity, resulting in population parameters of r < 0, λ < 1, lead to negative population growth. The population parameters r and λ reared under fluctuating temperature were higher than that reared under constant temperatures, the mean generation time (T) was shorter than it was in all of the constant temperatures treatments. This would imply that the outdoor G. molesta population would have a higher population growth potential and faster growth rate than indoor populations raised at constant temperatures. G. molesta moths reared under fluctuating temperature also had a higher fertility than moths reared under constant temperatures (except at 25°C). Our findings indicated that the population raised under outdoor fluctuating temperature conditions had strong environment adaptiveness.

Transport equations in an enzymatic glucose fuel cell

NASA Astrophysics Data System (ADS)

Jariwala, Soham; Krishnamurthy, Balaji

2018-01-01

A mathematical model is developed to study the effects of convective flux and operating temperature on the performance of an enzymatic glucose fuel cell with a membrane. The model assumes isothermal operating conditions and constant feed rate of glucose. The glucose fuel cell domain is divided into five sections, with governing equations describing transport characteristics in each region, namely - anode diffusion layer, anode catalyst layer (enzyme layer), membrane, cathode catalyst layer and cathode diffusion layer. The mass transport is assumed to be one-dimensional and the governing equations are solved numerically. The effects flow rate of glucose feed on the performance of the fuel cell are studied as it contributes significantly to the convective flux. The effects of operating temperature on the performance of a glucose fuel cell are also modeled. The cell performances are compared using cell polarization curves, which were found compliant with experimental observations.

A Polymer Optical Fiber Temperature Sensor Based on Material Features.

PubMed

Leal-Junior, Arnaldo; Frizera-Netoc, Anselmo; Marques, Carlos; Pontes, Maria José

2018-01-19

This paper presents a polymer optical fiber (POF)-based temperature sensor. The operation principle of the sensor is the variation in the POF mechanical properties with the temperature variation. Such mechanical property variation leads to a variation in the POF output power when a constant stress is applied to the fiber due to the stress-optical effect. The fiber mechanical properties are characterized through a dynamic mechanical analysis, and the output power variation with different temperatures is measured. The stress is applied to the fiber by means of a 180° curvature, and supports are positioned on the fiber to inhibit the variation in its curvature with the temperature variation. Results show that the sensor proposed has a sensitivity of 1.04 × 10 -3 °C -1 , a linearity of 0.994, and a root mean squared error of 1.48 °C, which indicates a relative error of below 2%, which is lower than the ones obtained for intensity-variation-based temperature sensors. Furthermore, the sensor is able to operate at temperatures up to 110 °C, which is higher than the ones obtained for similar POF sensors in the literature.

Virtual Instrument for Determining Rate Constant of Second-Order Reaction by pX Based on LabVIEW 8.0.

PubMed

Meng, Hu; Li, Jiang-Yuan; Tang, Yong-Huai

2009-01-01

The virtual instrument system based on LabVIEW 8.0 for ion analyzer which can measure and analyze ion concentrations in solution is developed and comprises homemade conditioning circuit, data acquiring board, and computer. It can calibrate slope, temperature, and positioning automatically. When applied to determine the reaction rate constant by pX, it achieved live acquiring, real-time displaying, automatical processing of testing data, generating the report of results; and other functions. This method simplifies the experimental operation greatly, avoids complicated procedures of manual processing data and personal error, and improves veracity and repeatability of the experiment results.

Pixelated Geiger-Mode Avalanche Photo-Diode Characterization Through Dark Current Measurement

NASA Astrophysics Data System (ADS)

Amaudruz, Pierre-Andre; Bishop, Daryl; Gilhully, Colleen; Goertzen, Andrew; James, Lloyd; Kozlowski, Piotr; Retiere, Fabrice; Shams, Ehsan; Sossi, Vesna; Stortz, Greg; Thiessen, Jonathan D.; Thompson, Christopher J.

2014-06-01

PIXELATED geiger-mode avalanche photodiodes (PPDs), often called silicon photomultipliers (SiPMs) are emerging as an excellent replacement for traditional photomultiplier tubes (PMTs) in a variety of detectors, especially those for subatomic physics experiments, which requires extensive test and operation procedures in order to achieve uniform responses from all the devices. In this paper, we show for two PPD brands, Hamamatsu MPPC and SensL SPM, that at room temperature, the dark noise rate, breakdown voltage and rate of correlated avalanches can be inferred from the sole measure of dark current as a function of operating voltage, hence greatly simplifying the characterization procedure. We introduce a custom electronics system that allows measurement for many devices concurrently, hence allowing rapid testing and monitoring of many devices at low cost. Finally, we show that the dark current of Hamamastu Multi-Pixel Photon Counter (MPPC) is rather independent of temperature at constant operating voltage, hence the current measure cannot be used to probe temperature variations. On the other hand, the MPPC current can be used to monitor light source conditions in DC mode without requiring strong temperature stability, as long as the integrated source brightness is comparable to the dark noise rate.

Impact of operating conditions on the acetylene contamination in the cathode of proton exchange membrane fuel cells

NASA Astrophysics Data System (ADS)

Zhai, Yunfeng; St-Pierre, Jean

2017-12-01

Realistically, proton exchange membrane fuel cells (PEMFCs) are operated under varying operating conditions that potentially impact the acetylene contamination reactions. In this paper, the effects of the cell operating conditions on the acetylene contamination in PEMFCs are investigated under different current densities and temperatures with different acetylene concentrations in the cathode. Electrochemical impedance spectroscopy is applied during the constant-current operation to analyze the impacts of the operating conditions on the acetylene electrochemical reactions. The experimental results indicate that higher acetylene concentrations, higher current densities and lower cell temperatures decrease the cell performance more. In particular, cathode poisoning becomes more severe at medium cell current densities. The cell cathode potentials at such current densities are not sufficient to completely oxidize the intermediate or sufficiently low to completely reduce the adsorbed acetylene. Based on these investigations, the possible condition-dependent limitations of the acetylene concentration and cell operating voltage are proposed for insight into the acetylene contamination mitigation stratagem. Regarding the barrier conditions, the acetylene reactions change abruptly, and adjusting the cell operation parameters to change the acetylene adsorbate and intermediate accumulation conditions to induce complete oxidation or reduction conditions may mitigate the severe acetylene contamination effects on PEMFCs.

Thermoelectric Exhaust Heat Recovery with Heat Pipe-Based Thermal Control

NASA Astrophysics Data System (ADS)

Brito, F. P.; Martins, Jorge; Hançer, Esra; Antunes, Nuno; Gonçalves, L. M.

2015-06-01

Heat pipe (HP)-based heat exchangers can be used for very low resistance heat transfer between a hot and a cold source. Their operating temperature depends solely on the boiling point of their working fluid, so it is possible to control the heat transfer temperature if the pressure of the HP can be adjusted. This is the case of the variable conductance HPs (VCHP). This solution makes VCHPs ideal for the passive control of thermoelectric generator (TEG) temperature levels. The present work assesses, both theoretically and experimentally, the merit of the aforementioned approach. A thermal and electrical model of a TEG with VCHP assist is proposed. Experimental results obtained with a proof of concept prototype attached to a small single-cylinder engine are presented and used to validate the model. It was found that the HP heat exchanger indeed enables the TEG to operate at a constant, optimal temperature in a passive and safe way, and with a minimal overall thermal resistance, under part load, it effectively reduces the active module area without deprecating the temperature level of the active modules.

Analysis of temperature rise for piezoelectric transformer using finite-element method.

PubMed

Joo, Hyun-Woo; Lee, Chang-Hwan; Rho, Jong-Seok; Jung, Hyun-Kyo

2006-08-01

Analysis of heat problem and temperature field of a piezoelectric transformer, operated at steady-state conditions, is described. The resonance frequency of the transformer is calculated from impedance and electrical gain analysis using a finite-element method. Mechanical displacement and electric potential of the transformer at the calculated resonance frequency are used to calculate the loss distribution of the transformer. Temperature distribution using discretized heat transfer equation is calculated from the obtained losses of the transformer. Properties of the piezoelectric material, dependent on the temperature field, are measured to recalculate the losses, temperature distribution, and new resonance characteristics of the transformer. Iterative method is adopted to recalculate the losses and resonance frequency due to the changes of the material constants from temperature increase. Computed temperature distributions and new resonance characteristics of the transformer at steady-state temperature are verified by comparison with experimental results.

Fiber-optic miniature sensor for in situ temperature monitoring of curing composite material

NASA Astrophysics Data System (ADS)

Sampath, Umesh; Kim, Dae-gil; Kim, Hyunjin; Song, Minho

2018-04-01

This study proposes a fiber-optic temperature sensor with a single-mode fiber tip covered with a thermo-sensitive polymer resin. The temperature is sensed by measuring the Fresnel reflection from the optical fiber/polymer interface. Because the thermo-optic coefficients differ between the optical fiber and the polymer, the in situ temperature can be measured even in curing composite materials. In initial experiments, the proposed sensor successfully measured and recovered the temperature information. The measured sensor data were linearly correlated, with an R2 exceeding 0.99. The standard deviation in the long-term measurements of constant temperature was 2.6%. The durability and stability of the sensor head material in long-term operation was validated by Fourier transform infrared spectroscopy and X-ray diffraction analysis. In further experiments, the suggested miniature temperature sensor obtained the internal temperatures of curing composite material over a wide range (30-110 °C).

Experiment and Modeling of Simultaneous Creep, Plasticity and Transformation of High Temperature Shape Memory Alloys During Cyclic Actuation

NASA Technical Reports Server (NTRS)

Kumar, Parikshith K.; Desai, Uri; Chatzigeorgiou, George; Lagoudas, Dimitris C.; Monroe, James; Karaman, Ibrahim; Noebe, Ron; Bigelow, Glen

2010-01-01

The present work is focused on studying the cycling actuation behavior of HTSMAs undergoing simultaneous creep and transformation. For the thermomechanical testing, a high temperature test setup was assembled on a MTS frame with the capability to test up to temperatures of 600 C. Constant stress thermal cycling tests were conducted to establish the actuation characteristics and the phase diagram for the chosen HTSMA. Additionally, creep tests were conducted at constant stress levels at different test temperatures to characterize the creep behavior of the alloy over the operational range. A thermodynamic constitutive model is developed and extended to take into account a) the effect of multiple thermal cycling on the generation of plastic strains due to transformation (TRIP strains) and b) both primary and secondary creep effects. The model calibration is based on the test results. The creep tests and the uniaxial tests are used to identify the viscoplastic behavior of the material. The parameters for the SMA properties, regarding the transformation and transformation induced plastic strain evolutions, are obtained from the material phase diagram and the thermomechanical tests. The model is validated by predicting the material behavior at different thermomechanical test conditions.

Heating-Rate-Coupled Model for Hydrogen Reduction of JSC-1A

NASA Technical Reports Server (NTRS)

Hegde, U.; Balasubramaniam, R.; Gokoglu, S. A.

2010-01-01

A previously developed and validated model for hydrogen reduction of JSC-1A for a constant reaction-bed temperature is extended to account for reaction during the bed heat-up period. A quasisteady approximation is used wherein an expression is derived for a single average temperature of reaction during the heat-up process by employing an Arrhenius expression for regolith conversion. Subsequently, the regolith conversion during the heat-up period is obtained by using this representative temperature. Accounting for the reaction during heat-up provides a better estimate of the reaction time needed at the desired regolith-bed operating temperature. Implications for the efficiency of the process, as measured by the energy required per unit mass of oxygen produced, are also indicated.

REFRIGERATION ESPECIALLY FOR VERY LOW TEMPERATURES

DOEpatents

Kennedy, P.B.; Smith, H.R. Jr.

1960-09-13

A refrigeration system for producing very low temperatures is described. The system of the invention employs a binary mixture refrigerant in a closed constant volume, e.g., Freon and ethylene. Such mixture is compressed in the gaseous state and is then separated in a fractionating column element of the system. Thenceforth, the first liquid to separate is employed stagewise to cool and liq uefy successive portions of the refrigerant at successively lower temperatures by means of heat exchangers coupled between the successive stages. When shut down, all of the volumes of the system are interconnected and a portion of the refrigerant remains liquid at ambient temperatures so that no dangerous overpressures develop. The system is therefore rugged, simple and dependable in operation.

Temperature-dependent electrochemical heat generation in a commercial lithium-ion battery

NASA Astrophysics Data System (ADS)

Bandhauer, Todd M.; Garimella, Srinivas; Fuller, Thomas F.

2014-02-01

Lithium-ion batteries suffer from inherent thermal limitations (i.e., capacity fade and thermal runaway); thus, it is critical to understand heat generation experienced in the batteries under normal operation. In the current study, reversible and irreversible electrochemical heat generation rates were measured experimentally on a small commercially available C/LiFePO4 lithium-ion battery designed for high-rate applications. The battery was tested over a wide range of temperatures (10-60 °C) and discharge and charge rates (∼C/4-5C) to elucidate their effects. Two samples were tested in a specially designed wind tunnel to maintain constant battery surface temperature within a maximum variation of ±0.88 °C. A data normalization technique was employed to account for the observed capacity fade, which was largest at the highest rates. The heat rate was shown to increase with both increasing rate and decreasing temperature, and the reversible heat rate was shown to be significant even at the highest rate and temperature (7.4% at 5C and 55 °C). Results from cycling the battery using a dynamic power profile also showed that constant-current data predict the dynamic performance data well. In addition, the reversible heat rate in the dynamic simulation was shown to be significant, especially for charge-depleting HEV applications.

Determination of kinetic data for soot oxidation: Modeling of competition between oxygen diffusion and reaction during thermogravimetric analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilot, P.; Bonnefoy, F.; Marcuccilli, F.

1993-10-01

Kinetic data concerning carbon black oxidation in the temperature range between 600 and 900 C have been obtained using thermogravimetric analysis. Modeling of diffusion in a boundary layer above the pan and inside the porous medium coupled to oxygen reaction with carbon black is necessary to obtain kinetic constants as a function of temperature. These calculations require the knowledge of the oxidation rate at a given constant temperature as a function of the initial mass loading m[sub o]. This oxidation rate, expressed in milligrams of soot consumed per second and per milligram of initial soot loading, decreases when m[sub o]more » increases, in agreement with a reaction in an intermediary regime where the kinetics and the oxygen diffusion operate. The equivalent diffusivity of oxygen inside the porous medium is evaluated assuming two degrees of porosity: between soot aggregates and inside each aggregate. Below 700 C an activation energy of about 103 kJ/mol can be related to a combustion reaction probably kinetically controlled. Beyond 700 C the activation energy of about 20 kJ/ mol corresponds to a reaction essentially controlled by oxygen diffusion leading to a constant density oxidation with oxygen consumption at or near the particle surface. To validate these data, they are used in the modeling of a Diesel particulate trap regeneration. In this particular case, the oxidizing flux is forced across the carbon black deposit, oxygen diffusion being insignificant. A good agreement between experimental results and model predictions is obtained, proving the rate constants validity.« less

Esterification of palm fatty acid distillate with epychlorohydrin using cation exchange resin catalyst

NASA Astrophysics Data System (ADS)

Budhijanto, Budhijanto; Subagyo, Albertus F. P. H.

2017-05-01

Palm Fatty Acid Distillate (PFAD) is one of the wastes from the conversion of crude palm oil (CPO) into cooking oil. The PFAD is currently only utilized as the raw material for low grade soap and biofuel. To improve the economic value of PFAD, it was converted into monoglyceride by esterification process. Furthermore, the monoglyceride could be polymerized to form alkyd resin, which is a commodity of increasing importance. This study aimed to propose a kinetics model for esterification of PFAD with epichlorohydrin using cation exchange resin catalyst. The reaction was the first step from a series of reactions to produce the monoglyceride. In this study, the reaction between PFAD and epichlorohydirne was run in a stirred batch reactor. The stirrer was operated at a constant speed of 400 RPM. The reaction was carried out for 180 minutes on varied temperatures of 60°C, 70°C, 80°C, dan 90°C. Cation exchange resin was applied as solid catalysts. Analysis was conducted periodically by measuring the acid number of the samples, which was further used to calculate PFAD conversion. The data were used to determine the rate constants and the equilibrium constants of the kinetics model. The kinetics constants implied that the reaction was reversible and controlled by the intrinsic surface reaction. Despite the complication of the heterogeneous nature of the reaction, the kinetics data well fitted the elementary rate law. The effect of temperature on the equilibrium constants indicated that the reaction is exothermic.

Isoprene/methyl acrylate Diels-Alder reaction in supercritical carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, B.; Akgerman, A.

1999-12-01

The Diels-Alder reaction between isoprene and methyl acrylate was carried out in supercritical carbon dioxide in the temperature range 110--140 C and the pressure range 95.2--176.9 atm in a 300 cm{sup 3} autoclave. The high-pressure phase behavior of the reaction mixture in the vicinity of its critical region was determined in a mixed vessel with a sight window to ensure that all the experiments were performed in the supercritical single-phase region. Kinetic data were obtained at different temperatures, pressures, and reaction times. It was observed that in the vicinity of the critical point the reaction rate constant decreases with increasingmore » pressure. It was also determined that the reaction selectivity does not change with operating conditions. Transition-state theory was used to explain the effect of pressure on reaction rate and product selectivity. Additional experiments were conducted at constant temperature but different phase behaviors (two-phase region, liquid phase, supercritical phase) by adjusting the initial composition and pressure. It was shown that the highest reaction rate is in the supercritical region.« less

On the sub-band gap optical absorption in heat treated cadmium sulphide thin film deposited on glass by chemical bath deposition technique

NASA Astrophysics Data System (ADS)

Chattopadhyay, P.; Karim, B.; Guha Roy, S.

2013-12-01

The sub-band gap optical absorption in chemical bath deposited cadmium sulphide thin films annealed at different temperatures has been critically analyzed with special reference to Urbach relation. It has been found that the absorption co-efficient of the material in the sub-band gap region is nearly constant up to a certain critical value of the photon energy. However, as the photon energy exceeds the critical value, the absorption coefficient increases exponentially indicating the dominance of Urbach rule. The absorption coefficients in the constant absorption region and the Urbach region have been found to be sensitive to annealing temperature. A critical examination of the temperature dependence of the absorption coefficient indicates two different kinds of optical transitions to be operative in the sub-band gap region. After a careful analyses of SEM images, energy dispersive x-ray spectra, and the dc current-voltage characteristics, we conclude that the absorption spectra in the sub-band gap domain is possibly associated with optical transition processes involving deep levels and the grain boundary states of the material.

The melting temperature of liquid water with the effective fragment potential

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brorsen, Kurt R.; Willow, Soohaeng Y.; Xantheas, Sotiris S.

2015-09-17

Direct simulation of the solid-liquid water interface with the effective fragment potential (EFP) via the constant enthalpy and pressure (NPH) ensemble was used to estimate the melting temperature (Tm) of ice-Ih. Initial configurations and velocities, taken from equilibrated constant pressure and temperature (NPT) simulations at T = 300 K, 350 K and 400 K, respectively, yielded corresponding Tm values of 378±16 K, 382±14 K and 384±15 K. These estimates are consistently higher than experiment, albeit to the same degree with previously reported estimates using density functional theory (DFT)-based Born-Oppenheimer simulations with the Becke-Lee-Yang-Parr functional plus dispersion corrections (BLYP-D). KRB wasmore » supported by a Computational Science Graduate Fellowship from the Department of Energy. MSG was supported by a U.S. National Science Foundation Software Infrastructure (SI2) grant (ACI – 1047772). SSX acknowledges support from the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.« less

Analysis of possibilities of waste heat recovery in off-road vehicles

NASA Astrophysics Data System (ADS)

Wojciechowski, K. T.; Zybala, R.; Leszczynski, J.; Nieroda, P.; Schmidt, M.; Merkisz, J.; Lijewski, P.; Fuc, P.

2012-06-01

The paper presents the preliminary results of the waste heat recovery investigations for an agricultural tractor engine (7.4 dm3) and excavator engine (7.2 dm3) in real operating conditions. The temperature of exhaust gases and exhaust mass flow rate has been measured by precise portable exhaust emissions analyzer SEMTECH DS (SENSORS Inc.). The analysis shows that engines of tested vehicles operate approximately at constant speed and load. The average temperature of exhaust gases is in the range from 300 to 400 °C for maximum gas mass flows of 1100 kg/h and 1400 kg/h for tractor and excavator engine respectively. Preliminary tests show that application of TEGs in tested off-road vehicles offers much more beneficial conditions for waste heat recovery than in case of automotive engines.

Elastic Constants of Ni-Mn-Ga Magnetic Shape Memory Alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stipcich, M.; Manosa, L.; Planes, A.

2004-01-01

We have measured the adiabatic second order elastic constants of two Ni-Mn-Ga magnetic shape memory crystals with different martensitic transition temperatures, using ultrasonic methods. The temperature dependence of the elastic constants has been followed across the ferromagnetic transition and down to the martensitic transition temperature. Within experimental errors no noticeable change in any of the elastic constants has been observed at the Curie point. The temperature dependence of the shear elastic constant C' has been found to be very different for the two alloys. Such a different behavior is in agreement with recent theoretical predictions for systems undergoing multi-stage structuralmore » transitions.« less

Manual of design and installation of Forest Service water spray dry kiln

Treesearch

L.V. Teesdale

1920-01-01

The best thing that can be said of any dry kiln is that when it is run by a properly informed operator the temperature, humidity, and circulation are constant and uniform. In an endeavor to produce a kiln in which each of these could be regulated independently of the others, the Forest Products Laboratory designed and developed the "Forest Service Humidity...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shyam, Amit; Lara-Curzio, Edgar

This paper reports on the langatate (LGT) elastic constants measured from room temperature (25 C) to 1100 C using resonant ultrasound spectroscopy (RUS). The constants were extracted by fitting the resonant peaks with those calculated by Lagrangian mechanics at each temperature where the RUS measurements were taken. In addition, the RUS technique was used to extract the piezoelectric constants in the 25 C to 120 C temperature range. This work also publishes a set of temperature coefficients for the elastic constants up to 1100 C. For the measurements, six parallelepiped LGT samples were aligned, cut, ground, and polished at themore » University of Maine. The samples were aligned to two different crystal orientations, to increase the reliability of the constant fitting. The extraction of LGT elastic constants up to 1100 C presented in this paper represents a critical step towards the design and fabrication of LGT acoustic wave devices for high temperature and harsh environment applications.« less

Loop Heat Pipe Operation with Thermoelectric Converters and Coupling Blocks

NASA Technical Reports Server (NTRS)

Ku, Jentung; Nagano, Hosei

2007-01-01

This paper presents theoretical and experimental studies on using thermoelectric converters (TECs) and coupling blocks to control the operating temperature of a miniature loop heat pipes (MLHP). The MLHP has two parallel evaporators and two parallel condensers, and each evaporator has its own integral compensation chamber (CC). A TEC is attached to each CC, and connected to the evaporator via a copper thermal strap. The TEC can provide both heating and cooling to the CC, therefore extending the LHP operating temperature over a larger range of the evaporator heat load. A bi-polar power supply is used for the TEC operation. The bipolar power supply automatically changes the direction of the current to the TEC, depending on whether the CC requires heating or cooling, to maintain the CC temperature at the desired set point. The TEC can also enhance the startup success by maintaining a constant CC temperature during the start-up transient. Several aluminum coupling blocks are installed between the vapor line and liquid line. The coupling blocks serve as a heat exchanger which preheats the cold returning liquid so as to reduce the amount of liquid subcooling, and hence the power required to maintain the CC at the desired set point temperature. This paper focuses on the savings of the CC control heater power afforded by the TECs when compared to traditional electric heaters. Tests were conducted by varying the evaporator power, the condenser sink temperature, the CC set point temperature, the number of coupling blocks, and the thermal conductance of the thermal strap. Test results show that the TECs are able to control the CC temperature within k0.5K under all test conditions, and the required TEC heater power is only a fraction of the required electric heater power.

The effects of increased constant incubation temperature and cumulative acute heat shock exposures on morphology and survival of Lake Whitefish (Coregonus clupeaformis) embryos.

PubMed

Lee, Abigail H; Eme, John; Mueller, Casey A; Manzon, Richard G; Somers, Christopher M; Boreham, Douglas R; Wilson, Joanna Y

2016-04-01

Increasing incubation temperatures, caused by global climate change or thermal effluent from industrial processes, may influence embryonic development of fish. This study investigates the cumulative effects of increased incubation temperature and repeated heat shocks on developing Lake Whitefish (Coregonus clupeaformis) embryos. We studied the effects of three constant incubation temperatures (2°C, 5°C or 8°C water) and weekly, 1-h heat shocks (+3°C) on hatching time, survival and morphology of embryos, as these endpoints may be particularly susceptible to temperature changes. The constant temperatures represent the predicted magnitude of elevated water temperatures from climate change and industrial thermal plumes. Time to the pre-hatch stage decreased as constant incubation temperature increased (148d at 2°C, 92d at 5°C, 50d at 8°C), but weekly heat shocks did not affect time to hatch. Mean survival rates and embryo morphometrics were compared at specific developmental time-points (blastopore, eyed, fin flutter and pre-hatch) across all treatments. Constant incubation temperatures or +3°C heat-shock exposures did not significantly alter cumulative survival percentage (~50% cumulative survival to pre-hatch stage). Constant warm incubation temperatures did result in differences in morphology in pre-hatch stage embryos. 8°C and 5°C embryos were significantly smaller and had larger yolks than 2°C embryos, but heat-shocked embryos did not differ from their respective constant temperature treatment groups. Elevated incubation temperatures may adversely alter Lake Whitefish embryo size at hatch, but weekly 1-h heat shocks did not affect size or survival at hatch. These results suggest that intermittent bouts of warm water effluent (e.g., variable industrial emissions) are less likely to negatively affect Lake Whitefish embryonic development than warmer constant incubation temperatures that may occur due to climate change. Copyright © 2016 Elsevier Ltd. All rights reserved.

Wide-Temperature-Range Integrated Operational Amplifier

NASA Technical Reports Server (NTRS)

Mojarradi, Mohammad; Levanas, Greg; Chen, Yuan; Kolawa, Elizabeth; Cozy, Raymond; Blalock, Benjamin; Greenwell, Robert; Terry, Stephen

2007-01-01

A document discusses a silicon-on-insulator (SOI) complementary metal oxide/semiconductor (CMOS) integrated- circuit operational amplifier to be replicated and incorporated into sensor and actuator systems of Mars-explorer robots. This amplifier is designed to function at a supply potential less than or equal to 5.5 V, at any temperature from -180 to +120 C. The design is implemented on a commercial radiation-hard SOI CMOS process rated for a supply potential of less than or equal to 3.6 V and temperatures from -55 to +110 C. The design incorporates several innovations to achieve this, the main ones being the following: NMOS transistor channel lengths below 1 m are generally not used because research showed that this change could reduce the adverse effect of hot carrier injection on the lifetimes of transistors at low temperatures. To enable the amplifier to withstand the 5.5-V supply potential, a circuit topology including cascade devices, clamping devices, and dynamic voltage biasing was adopted so that no individual transistor would be exposed to more than 3.6 V. To minimize undesired variations in performance over the temperature range, the transistors in the amplifier are biased by circuitry that maintains a constant inversion coefficient over the temperature range.

Irradiation creep and swelling of AISI 316 to exposures of 130 dpa at 385?400$deg;C

NASA Astrophysics Data System (ADS)

Garner, F. A.; Porter, D. L.

1988-07-01

The creep and swelling of AISI 316 stainless steel have been studied at 385 to 400°C in EBR-II to doses of 130 dpa. Most creep capsules were operated at constant stress and temperature but mid-life changes in these variables were also made. This paper concentrates on the behavior of the 20% cold-worked condition but five other conditions were also studied. Swelling at ⩽ 400° C was found to lose the sensitivity to stress exhibited at higher temperatures while the creep rate was found to retain linear dependencies on both stress and swelling rate. The creep coefficients extracted at 400°C agree with those found in other experiments conducted at higher temperatures. In the temperature range of ⩽ 400° C, swelling is in the recombinationdominated regime and the swelling rate falls strongly away from the ~1%/dpa rate observed at higher temperatures. These lower rates of creep and swelling, coupled with the attainment of high damage levels without failure, encourage the use of AISI 316 in the construction of water-cooled fusion first walls operating at temperatures below 400°C.

Temperature dependence of (+)-catechin pyran ring proton coupling constants as measured by NMR and modeled using GMMX search methodology

Treesearch

Fred L. Tobiason; Stephen S. Kelley; M. Mark Midland; Richard W. Hemingway

1997-01-01

The pyran ring proton coupling constants for (+)-catechin have been experimentally determined in deuterated methanol over a temperature range of 213 K to 313 K. The experimental coupling constants were simulated to 0.04 Hz on the average at a 90 percent confidence limit using a LAOCOON method. The temperature dependence of the coupling constants was reproduced from the...

Growth rate and trapping efficacy of nematode-trapping fungi under constant and fluctuating temperatures.

PubMed

Fernández, A S; Larsen, M; Wolstrup, J; Grønvold, J; Nansen, P; Bjørn, H

1999-08-01

The effect of temperature on radial growth and predatory activity of different isolates of nematode-trapping fungi was assessed. Four isolates of Duddingtonia flagrans and one isolate of Arthrobotrys oligospora were inoculated on petri dishes containing either cornmeal agar (CMA) or faecal agar and then incubated for 14 days under three different constant and fluctuating temperature regimes. The radial growth was similar on the two substrates at each temperature regime. All fungal isolates showed a higher growth rate at a constant 20 degrees C. At 10 degrees and 15 degrees C, all D. flagrans isolates showed very similar patterns of radial growth at both constant and fluctuating temperatures. At 20 degrees C, they grew significantly faster at constant than at fluctuating temperatures. A. oligospora grew significantly faster than all D. flagrans isolates except when incubated at a fluctuating 20 degrees C. Spores of each fungal isolate were added to faecal cultures containing eggs of Cooperia oncophora at a concentration of 6250 spores/g faeces. The cultures were incubated for 14 days at the same temperature regimes described above. Control faeces (without fungal material) were also cultured. More larvae were recovered from the fungus-treated cultures incubated at a constant 10 degrees or 15 degrees C than from those incubated at the respective fluctuating temperatures, except for one D. flagrans isolate. Incubation at 20 degrees C showed the opposite effect. The general reduction observed in the number of nematode larvae due to fungal trapping was 18-25% and 48-80% for a constant and fluctuating 10 degrees C, 70-96% and 93-95% for a constant and fluctuating 15 degrees C, and 63-98% and 0-25% for a constant and fluctuating 20 degrees C, respectively.

Determination of Henry’s Law Constants Using Internal Standards with Benchmark Values

EPA Science Inventory

It is shown that Henry’s law constants can be experimentally determined by comparing headspace content of compounds with known constants to interpolate the constants of other compounds. Studies were conducted over a range of water temperatures to identify temperature dependence....

An interactive computer code for calculation of gas-phase chemical equilibrium (EQLBRM)

NASA Technical Reports Server (NTRS)

Pratt, B. S.; Pratt, D. T.

1984-01-01

A user friendly, menu driven, interactive computer program known as EQLBRM which calculates the adiabatic equilibrium temperature and product composition resulting from the combustion of hydrocarbon fuels with air, at specified constant pressure and enthalpy is discussed. The program is developed primarily as an instructional tool to be run on small computers to allow the user to economically and efficiency explore the effects of varying fuel type, air/fuel ratio, inlet air and/or fuel temperature, and operating pressure on the performance of continuous combustion devices such as gas turbine combustors, Stirling engine burners, and power generation furnaces.

Dielectric studies on PEG-LTMS based polymer composites

NASA Astrophysics Data System (ADS)

Patil, Ravikumar V.; Praveen, D.; Damle, R.

2018-02-01

PEG LTMS based polymer composites were prepared and studied for dielectric constant variation with frequency and temperature as a potential candidate with better dielectric properties. Solution cast technique is used for the preparation of polymer composite with five different compositions. Samples show variation in dielectric constant with frequency and temperature. Dielectric constant is large at low frequencies and higher temperatures. Samples with larger space charges have shown larger dielectric constant. The highest dielectric constant observed was about 29244 for PEG25LTMS sample at 100Hz and 312 K.

Temperature measurement in a gas turbine engine combustor

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeSilva, Upul

A method and system for determining a temperature of a working gas passing through a passage to a turbine section of a gas turbine engine. The method includes identifying an acoustic frequency at a first location in the engine upstream from the turbine section, and using the acoustic frequency for determining a first temperature value at the first location that is directly proportional to the acoustic frequency and a calculated constant value. A second temperature of the working gas is determined at a second location in the engine and, using the second temperature, a back calculation is performed to determinemore » a temperature value for the working gas at the first location. The first temperature value is compared to the back calculated temperature value to change the calculated constant value to a recalculated constant value. Subsequent first temperature values at the first location may be determined based on the recalculated constant value.« less

Applications of high pressure differential scanning calorimetry to aviation fuel thermal stability research

NASA Technical Reports Server (NTRS)

Neveu, M. C.; Stocker, D. P.

1985-01-01

High pressure differential scanning calorimetry (DSC) was studied as an alternate method for performing high temperature fuel thermal stability research. The DSC was used to measure the heat of reaction versus temperature of a fuel sample heated at a programmed rate in an oxygen pressurized cell. Pure hydrocarbons and model fuels were studied using typical DSC operating conditions of 600 psig of oxygen and a temperature range from ambient to 500 C. The DSC oxidation onset temperature was determined and was used to rate the fuels on thermal stability. Kinetic rate constants were determined for the global initial oxidation reaction. Fuel deposit formation is measured, and the high temperature volatility of some tetralin deposits is studied by thermogravimetric analysis. Gas chromatography and mass spectrometry are used to study the chemical composition of some DSC stressed fuels.

Incorporation of surface albedo-temperature feedback in a one-dimensional radiative-connective climate model

NASA Technical Reports Server (NTRS)

Wang, W. C.; Stone, P. H.

1979-01-01

The feedback between ice snow albedo and temperature is included in a one dimensional radiative convective climate model. The effect of this feedback on sensitivity to changes in solar constant is studied for the current values of the solar constant and cloud characteristics. The ice snow albedo feedback amplifies global climate sensitivity by 33% and 50%, respectively, for assumptions of constant cloud altitude and constant cloud temperature.

Winds over Japan.

NASA Astrophysics Data System (ADS)

Plumley, William J.

1994-01-01

Before World War II, weather forecasters had little knowledge of upper-air wind patterns above 20000 feet. Data were seldom avai able at these heights, and the need was not great because commercial aircraft seldom flew at these altitudes. The war in the Pacific changed all that. Wind forecasts for 30000 feet plus became urgent to support the XXI Bomber Command in its bombing mission over Japan.The U.S. Army Air Force Pacific Ocean Area (AAFPOA) placed a Weather Central in the Marianas Islands in 1944 (Saipan in 1944 and Guam in 1945) to provide forecasting support for this mission. A forecasting procedure was put into operation that combined the elements known as "single-station forecasting" and an advanced procedure that used "altirmeter corrections" to analyze upper-airdata and make prognoses. Upper-air charts were drawn for constant pressure surfaces rather than constant height surfaces. The constant pressure surfaces were tied together by means of the atmospheric temperature field represented by specific temperature anomalies between pressure surfaces. Wind forecasts over the Marianas-Japan route made use of space cross sections that provided the data to forecast winds at each 5000-ft level to 35000 ft along the mission flight path. The new procedures allowed the forecaster to construct internally consistent meteorological charts in three dimensions in regions of sparse data.Army air force pilots and their crews from the Marianas were among the first to experience the extreme wind conditions now known as the "jet stream". Air force forecasters demonstrated that, with experience, such winds could reasonably be forecast under difficult operational conditions.

Estimations of temperature deviations in chromatographic columns using isenthalpic plots. I. Theory for isocratic systems.

PubMed

Tarafder, Abhijit; Iraneta, Pamela; Guiochon, Georges; Kaczmarski, Krzysztof; Poe, Donald P

2014-10-31

We propose to use constant enthalpy or isenthalpic diagrams as a tool to estimate the extent of the temperature variations caused by the mobile phase pressure drop along a chromatographic column, e.g. of its cooling in supercritical fluid and its heating in ultra-performance liquid chromatography. Temperature strongly affects chromatographic phenomena. Any of its variations inside the column, whether intended or not, can lead to significant changes in separation performance. Although instruments use column ovens in order to keep constant the column temperature, operating conditions leading to a high pressure drop may cause significant variations of the column temperature, both in the axial and the radial directions, from the set value. Different ways of measuring these temperature variations are available but they are too inconvenient to be employed in many practical situations. In contrast, the thermodynamic plot-based method that we describe here can easily be used with only a ruler and a pencil. They should be helpful in developing methods or in analyzing results in analytical laboratories. Although the most effective application area for this approach should be SFC (supercritical fluid chromatography), it can be applied to any chromatographic conditions in which temperature variations take place along the column due to the pressure drop, e.g. in ultra-high pressure liquid chromatography (UHPLC). The method proposed here is applicable to isocractic conditions only. Copyright © 2014 Elsevier B.V. All rights reserved.

Virtual Instrument for Determining Rate Constant of Second-Order Reaction by pX Based on LabVIEW 8.0

PubMed Central

Meng, Hu; Li, Jiang-Yuan; Tang, Yong-Huai

2009-01-01

The virtual instrument system based on LabVIEW 8.0 for ion analyzer which can measure and analyze ion concentrations in solution is developed and comprises homemade conditioning circuit, data acquiring board, and computer. It can calibrate slope, temperature, and positioning automatically. When applied to determine the reaction rate constant by pX, it achieved live acquiring, real-time displaying, automatical processing of testing data, generating the report of results; and other functions. This method simplifies the experimental operation greatly, avoids complicated procedures of manual processing data and personal error, and improves veracity and repeatability of the experiment results. PMID:19730752

Temperature stability limits for an isothermal demagnetization refrigerator

NASA Technical Reports Server (NTRS)

Kittel, P.

1984-01-01

It is pointed out that magnetic refrigeration can provide additional cooling for infrared detectors on space missions, taking into account the Shuttle Infrared Telescope Facility (SIRTF) and the Large Deployable Reflector (LDR). From a temperature of 2 K provided by the primary cryogens, magnetic refrigerators could cool bolometers or pumped photoconductors to 0.1 K or below. Such a reduction in operating temperature would increase the sensitivity for bolometers, while the response at longer wavelengths for pumped photoconductors would be improved. Two types of magnetic refrigeration cycles have been proposed. One type uses a complete demagnetization. The present investigation is concerned with the second type, which uses a feedback-controlled isothermal demagnetization, taking into account the temperature stability limits. Attention is given to control system resolution, thermometer noise, reaction time, and thermal time constants.

The performance of a reduced-order adaptive controller when used in multi-antenna hyperthermia treatments with nonlinear temperature-dependent perfusion.

PubMed

Cheng, Kung-Shan; Yuan, Yu; Li, Zhen; Stauffer, Paul R; Maccarini, Paolo; Joines, William T; Dewhirst, Mark W; Das, Shiva K

2009-04-07

In large multi-antenna systems, adaptive controllers can aid in steering the heat focus toward the tumor. However, the large number of sources can greatly increase the steering time. Additionally, controller performance can be degraded due to changes in tissue perfusion which vary non-linearly with temperature, as well as with time and spatial position. The current work investigates whether a reduced-order controller with the assumption of piecewise constant perfusion is robust to temperature-dependent perfusion and achieves steering in a shorter time than required by a full-order controller. The reduced-order controller assumes that the optimal heating setting lies in a subspace spanned by the best heating vectors (virtual sources) of an initial, approximate, patient model. An initial, approximate, reduced-order model is iteratively updated by the controller, using feedback thermal images, until convergence of the heat focus to the tumor. Numerical tests were conducted in a patient model with a right lower leg sarcoma, heated in a 10-antenna cylindrical mini-annual phased array applicator operating at 150 MHz. A half-Gaussian model was used to simulate temperature-dependent perfusion. Simulated magnetic resonance temperature images were used as feedback at each iteration step. Robustness was validated for the controller, starting from four approximate initial models: (1) a 'standard' constant perfusion lower leg model ('standard' implies a model that exactly models the patient with the exception that perfusion is considered constant, i.e., not temperature dependent), (2) a model with electrical and thermal tissue properties varied from 50% higher to 50% lower than the standard model, (3) a simplified constant perfusion pure-muscle lower leg model with +/-50% deviated properties and (4) a standard model with the tumor position in the leg shifted by 1.5 cm. Convergence to the desired focus of heating in the tumor was achieved for all four simulated models. The controller accomplished satisfactory therapeutic outcomes: approximately 80% of the tumor was heated to temperatures 43 degrees C and approximately 93% was maintained at temperatures <41 degrees C. Compared to the controller without model reduction, a approximately 9-25 fold reduction in convergence time was accomplished using approximately 2-3 orthonormal virtual sources. In the situations tested, the controller was robust to the presence of temperature-dependent perfusion. The results of this work can help to lay the foundation for real-time thermal control of multi-antenna hyperthermia systems in clinical situations where perfusion can change rapidly with temperature.

Experimental performance of an internal resistance heater for Langley 6-inch expansion tube driver

NASA Technical Reports Server (NTRS)

Creel, T. R., Jr.

1972-01-01

An experimental investigation of the heating characteristics of an internal resistance heating element was conducted in the driver of the Langley 6-inch expansion tube to obtain actual operating conditions, to compare these results to theory, and to determine whether any modification need be made to the heater element. The heater was operated in pressurized helium from 138. MN/sq m to 62.1 MN/sq m. This investigation revealed large temperature variations within the heater element caused primarily by area reductions at insulator locations. These large temperature variations were reduced by welding small tabs over all grooves. Previous predictions of heater element and driver gas temperature were unacceptable so new equations were derived. These equations predict element and gas temperature within 10 percent of the test data when either the constant power cycle or the interrupted power cycle is used. Visual observation of the heater element, when exposed to the atmosphere with power on, resulted in a decision to limit the heater element to 815 K. Experimental shock Mach numbers are in good agreement with theory.

Ferroelectric Polymers with Ultrahigh Energy Density, Low Loss, and Broad Operation Temperature for Navy Pulse Power Capacitors

DTIC Science & Technology

2014-02-01

by the electron hopping theory in the amorphous material. By further tailoring the molecular structures, meta-aromatic polyurea which possesses a...higher dipolar density than many polyureas reported in the literature has been synthesized. Preliminary experimental results show that an enhanced...dielectric constant and higher energy density can be achieved in the new meta-aromatic polyurea . Technical section; Technical Objective: The objective

National Aerospace Leadership Initiative - Phase I

DTIC Science & Technology

2008-09-30

Devised and validated CFD code for operation of a micro-channel heat exchanger. The work was published at the 2008 AIAA Annual Meeting and Exposition...and (3) preparation to implement this algorithm in TURBO. Heat Transfer Capability In the short and medium term, the following plan has been adopted...to provide heat transfer capability to the TURBO code: • Incorporation of a constant wall temperature boundary condition. This capability will be

A simple molecular mechanics integrator in mixed rigid body and dihedral angle space

PubMed Central

Vitalis, Andreas; Pappu, Rohit V.

2014-01-01

We propose a numerical scheme to integrate equations of motion in a mixed space of rigid-body and dihedral angle coordinates. The focus of the presentation is biomolecular systems and the framework is applicable to polymers with tree-like topology. By approximating the effective mass matrix as diagonal and lumping all bias torques into the time dependencies of the diagonal elements, we take advantage of the formal decoupling of individual equations of motion. We impose energy conservation independently for every degree of freedom and this is used to derive a numerical integration scheme. The cost of all auxiliary operations is linear in the number of atoms. By coupling the scheme to one of two popular thermostats, we extend the method to sample constant temperature ensembles. We demonstrate that the integrator of choice yields satisfactory stability and is free of mass-metric tensor artifacts, which is expected by construction of the algorithm. Two fundamentally different systems, viz., liquid water and an α-helical peptide in a continuum solvent are used to establish the applicability of our method to a wide range of problems. The resultant constant temperature ensembles are shown to be thermodynamically accurate. The latter relies on detailed, quantitative comparisons to data from reference sampling schemes operating on exactly the same sets of degrees of freedom. PMID:25053299

Lava tubes - Potential shelters for habitats

NASA Astrophysics Data System (ADS)

Horz, F.

Natural caverns occur on the moon in the form of 'lava tubes', which are the drained conduits of underground lava rivers. The inside dimensions of these tubes measure tens to hundreds of meters, and their roofs are expected to be thicker than 10 meters. Consequently, lava tube interiors offer an environment that is naturally protected from the hazards of radiation and meteorite impact. Further, constant, relatively benign temperatures of -20 C prevail. These are extremely favorable environmental conditions for human activities and industrial operations. Significant operational, technological, and economical benefits might result if a lunar base were constructed inside a lava tube.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shyam, Amit; Lara-Curzio, Edgar

This paper reports on the langatate (LGT) elastic constants and their temperature coefficients measured from room temperature (25degC) to 1100degC using resonant ultrasound spectroscopy (RUS). The constants were extracted by iteratively fitting the resonant peaks with those calculated by Lagrangian mechanics at each temperature where the RUS measurements were taken. In addition, the RUS technique was used to extract the elastic and piezoelectric constants in the 25degC to 120degC temperature range. The extraction of LGT elastic constants up to 1100degC presented in this paper represents a critical step towards the design and fabrication of LGT acoustic wave devices for highmore » temperature and harsh environment applications.« less

Entropy Production in Chemical Reactors

NASA Astrophysics Data System (ADS)

Kingston, Diego; Razzitte, Adrián C.

2017-06-01

We have analyzed entropy production in chemically reacting systems and extended previous results to the two limiting cases of ideal reactors, namely continuous stirred tank reactor (CSTR) and plug flow reactor (PFR). We have found upper and lower bounds for the entropy production in isothermal systems and given expressions for non-isothermal operation and analyzed the influence of pressure and temperature in entropy generation minimization in reactors with a fixed volume and production. We also give a graphical picture of entropy production in chemical reactions subject to constant volume, which allows us to easily assess different options. We show that by dividing a reactor into two smaller ones, operating at different temperatures, the entropy production is lowered, going as near as 48 % less in the case of a CSTR and PFR in series, and reaching 58 % with two CSTR. Finally, we study the optimal pressure and temperature for a single isothermal PFR, taking into account the irreversibility introduced by a compressor and a heat exchanger, decreasing the entropy generation by as much as 30 %.

The effect of water injection on nitric oxide emissions of a gas turbine combustor burning ASTM Jet-A fuel

NASA Technical Reports Server (NTRS)

Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

1973-01-01

Tests were conducted to determine the effect of water injection on oxides of nitrogen (NOx) emissions of a full annular, ram induction gas turbine combustor burning ASTM Jet-A fuel. The combustor was operated at conditions simulating sea-level takeoff and cruise conditions. Water at ambient temperature was injected into the combustor primary zone at water-fuel ratios up to 2. At an inlet-air temperature of 589 K (600 F) water injection decreased the NOx emission index at a constant exponential rate: NOx = NOx (o) e to the -15 W/F power (where W/F is the water-fuel ratio and NOx(o) indicates the value with no injection). The effect of increasing combustor inlet-air temperature was to decrease the effect of the water injection. Other operating variables such as pressure and reference Mach number did not appear to significantly affect the percent reduction in NOx. Smoke emissions were found to decrease with increasing water injection.

Modular Analysis of Automobile Exhaust Thermoelectric Power Generation System

NASA Astrophysics Data System (ADS)

Deng, Y. D.; Zhang, Y.; Su, C. Q.

2015-06-01

In this paper, an automobile exhaust thermoelectric power generation system is packaged into a model with its own operating principles. The inputs are the engine speed and power, and the output is the power generated by the system. The model is divided into two submodels. One is the inlet temperature submodel, and the other is the power generation submodel. An experimental data modeling method is adopted to construct the inlet temperature submodel, and a theoretical modeling method is adopted to construct the power generation submodel. After modeling, simulation is conducted under various engine operating conditions to determine the variation of the power generated by the system. Finally, the model is embedded into a Honda Insight vehicle model to explore the energy-saving effect of the system on the vehicle under Economic Commission for Europe and cyc-constant_60 driving cycles.

Effect of operating microscope light on brain temperature during craniotomy.

PubMed

Gayatri, Parthasarathi; Menon, Girish G; Suneel, Puthuvassery R

2013-07-01

Operating microscopes used during neurosurgery are fitted with xenon light. Burn injuries have been reported because of xenon microscope lighting as the intensity of xenon light is 300 W. We designed this study to find out if the light of operating microscope causes an increase in temperature of the brain tissue, which is exposed underneath. Twenty-one adult patients scheduled for elective craniotomies were enrolled. Distal esophageal temperature (T Eso), brain temperature under the microscope light (T Brain), and brain temperature under dura mater (T Dura) were measured continuously at 15-minute intervals during microscope use. The irrigation fluid temperature, room temperature, intensity of the microscope light, and the distance of the microscope from the brain surface were kept constant. The average age of the patients was 44±15 years (18 males and 3 females). The mean duration of microscope use was 140±39 minutes. There were no significant changes in T Brain and T Dura and T Eso over time. T Dura was significantly lower than T Brain both at time 0 and 60 minutes but not at 90 minutes. T Brain was significantly lower than T Eso both at time 0 and 60 minutes but not at 90 minutes. The T Dura remained significantly lower than T Eso at 0, 60, and 90 minutes. Our study shows that there is no significant rise in brain temperature under xenon microscope light up to 120 minutes duration, at intensity of 60% to 70%, from a distance of 20 to 25 cm from the brain surface.

Wide-Range Temperature Sensors with High-Level Pulse Train Output

NASA Technical Reports Server (NTRS)

Hammoud, Ahmad; Patterson, Richard L.

2009-01-01

Two types of temperature sensors have been developed for wide-range temperature applications. The two sensors measure temperature in the range of -190 to +200 C and utilize a thin-film platinum RTD (resistance temperature detector) as the temperature-sensing element. Other parts used in the fabrication of these sensors include NPO (negative-positive- zero) type ceramic capacitors for timing, thermally-stable film or wirewound resistors, and high-temperature circuit boards and solder. The first type of temperature sensor is a relaxation oscillator circuit using an SOI (silicon-on-insulator) operational amplifier as a comparator. The output is a pulse train with a period that is roughly proportional to the temperature being measured. The voltage level of the pulse train is high-level, for example 10 V. The high-level output makes the sensor less sensitive to noise or electromagnetic interference. The output can be read by a frequency or period meter and then converted into a temperature reading. The second type of temperature sensor is made up of various types of multivibrator circuits using an SOI type 555 timer and the passive components mentioned above. Three configurations have been developed that were based on the technique of charging and discharging a capacitor through a resistive element to create a train of pulses governed by the capacitor-resistor time constant. Both types of sensors, which operated successfully over the wide temperature range, have potential use in extreme temperature environments including jet engines and space exploration missions.

High-performance linear arrays of YBa2Cu3O7 superconducting infrared microbolometers on silicon

NASA Astrophysics Data System (ADS)

Johnson, Burgess R.; Foote, Marc C.; Marsh, Holly A.

1995-06-01

Single detectors and linear arrays of microbolometers utilizing the superconducting transition edge of YBa(subscript 2)Cu(subscript 3)O(subscript 7) have been fabricated by micromachining on silicon wafers. A D* of 8 +/- 2 X 10(superscript 9) cm Hz(superscript 1/2)/watt has been measured on a single detector. This is the highest D* reported on any superconducting microbolometer operating at temperatures higher than about 70 K. The NEP of this device was 1.5 X 10(superscript -12) watts/Hz(superscript HLF) at 2 Hz, at a temperature of 80.7 K. The thermal time constant was 105 msec, and the detector area was 140 micrometers X 105 micrometers . The use of batch silicon processing makes fabrication of linear arrays of these detectors relatively straightforward. The measured responsivity of detectors in one such array varied by less than 20% over the 6 mm length of the 64-element linear array. This measurement shows that good uniformity can be achieved at a single operating temperature in a superconductor microbolometer array, even when the superconducting resistive transition is a sharp function of temperature. The thermal detection mechanism of these devices gives them broadband response. This makes them especially useful at long wavelengths (e.g. (lambda) > 20 micrometers ), where they provide very high sensitivity at relatively high operating temperatures.

Semiclassical Calculation of Reaction Rate Constants for Homolytical Dissociations

NASA Technical Reports Server (NTRS)

Cardelino, Beatriz H.

2002-01-01

There is growing interest in extending organometallic chemical vapor deposition (OMCVD) to III-V materials that exhibit large thermal decomposition at their optimum growth temperature, such as indium nitride. The group III nitrides are candidate materials for light-emitting diodes and semiconductor lasers operating into the blue and ultraviolet regions. To overcome decomposition of the deposited compound, the reaction must be conducted at high pressures, which causes problems of uniformity. Microgravity may provide the venue for maintaining conditions of laminar flow under high pressure. Since the selection of optimized parameters becomes crucial when performing experiments in microgravity, efforts are presently geared to the development of computational OMCVD models that will couple the reactor fluid dynamics with its chemical kinetics. In the present study, we developed a method to calculate reaction rate constants for the homolytic dissociation of III-V compounds for modeling OMCVD. The method is validated by comparing calculations with experimental reaction rate constants.

Temperature environment for 9975 packages stored in KAC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W. L.

Plutonium materials are stored in the K Area Complex (KAC) in shipping packages, typically the 9975 shipping package. In order to estimate realistic degradation rates for components within the shipping package (i.e. the fiberboard overpack and O-ring seals), it is necessary to understand actual facility temperatures, which can vary daily and seasonally. Relevant facility temperature data available from several periods throughout its operating history have been reviewed. The annual average temperature within the Crane Maintenance Area has ranged from approximately 70 to 74 °F, although there is significant seasonal variation and lesser variation among different locations within the facility. Themore » long-term average degradation rate for 9975 package components is very close to that expected if the component were to remain continually at the annual average temperature. This result remains valid for a wide range of activation energies (which describes the variation in degradation rate as the temperature changes), if the activation energy remains constant over the seasonal range of component temperatures. It is recommended that component degradation analyses and service life estimates incorporate these results. Specifically, it is proposed that future analyses assume an average facility ambient air temperature of 94 °F. This value is bounding for all packages, and includes margin for several factors such as increased temperatures within the storage arrays, the addition of more packages in the future, and future operational changes.« less

The effects of gamma irradiation on micro-hotplates with integrated temperature sensing diodes

NASA Astrophysics Data System (ADS)

Francis, Laurent A.; André, Nicolas; Boufouss, El Hafed; Gérard, Pierre; Ali, Zeeshan; Udrea, Florin; Flandre, Denis

2014-06-01

Micro-hotplates are MEMS structures of interest for low-power gas sensing, lab-on-chips and space applications, such as micro-thrusters. Micro-hotplates usually consist in a Joule heater suspended on a thin-film membrane while thermopiles or thermodiodes are added as temperature sensors and for feedback control. The implementation of micro-hotplates using a Silicon-On-Insulator technology makes them suited for co-integration with analog integrated circuits and operation at elevated environmental temperatures in a range from 200 to 300 °C, while the heater allows thermal cycling in the kHz regime up to 700 °C, e.g. necessary for the activation of gas sensitive metal-oxide on top of the membrane, with mWrange electrical power. The demonstrated resistance of micro-hotplates to gamma radiations can extend their use in nuclear plants, biomedical sterilization and space applications. In this work, we present results from electrical tests on micro-hotplates during their irradiation by Cobalt-60 gamma rays with total doses up to 18.90 kGy. The micro-hotplates are fabricated using a commercial 1.0 μm Silicon-On-Insulator technology with a tungsten Joule heater, which allows power-controlled operation above 600 °C with less than 60 mW, and temperature sensing silicon diodes located on the membrane and on the bulk. We show the immunity of the sensing platform to the harsh radiation environment. Beside the good tolerance of the thermodiodes and the membrane materials to the total radiation dose, the thermodiode located on the heating membrane is constantly annealed during irradiation and keeps a constant sensitivity while post-irradiation annealing can restore the thermodiode.

Anodic Behavior of the Aluminum Current Collector in Imide-Based Electrolytes: Influence of Solvent, Operating Temperature, and Native Oxide-Layer Thickness.

PubMed

Meister, Paul; Qi, Xin; Kloepsch, Richard; Krämer, Elisabeth; Streipert, Benjamin; Winter, Martin; Placke, Tobias

2017-02-22

The inability of imide salts to form a sufficiently effective passivation layer on aluminum current collectors is one of the main obstacles that limit their broad application in electrochemical energy-storage systems. However, under certain circumstances, the use of electrolytes with imide electrolyte salts in combination with the aluminum current collector is possible. In this contribution, the stability of the aluminum current collector in electrolytes containing either lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) or lithium fluorosulfonyl-(trifluoromethanesulfonyl) imide (LiFTFSI) as conductive salt was investigated by electrochemical techniques, that is, cyclic voltammetry (CV) and chronocoulometry (CC) in either room-temperature ionic liquids or in ethyl methyl sulfone. In particular, the influence of the solvent, operating temperature, and thickness of the native oxide layer of aluminum on the pit formation at the aluminum current collector surface was studied by means of scanning electron microscopy. In general, a more pronounced aluminum dissolution and pit formation was found at elevated temperatures as well as in solvents with a high dielectric constant. An enhanced thickness of the native aluminum oxide layer increases the oxidative stability versus dissolution. Furthermore, we found a different reaction rate depending on dwell time at the upper cut-off potential for aluminum dissolution in TFSI- and FTFSI-based electrolytes during the CC measurements; the use of LiFTFSI facilitated the dissolution of aluminum compared to LiTFSI. Overall, the mechanism of anodic aluminum dissolution is based on: i) the attack of the Al 2 O 3 surface by acidic species and ii) the dissolution of bare aluminum into the electrolyte, which, in turn, is influenced by the electrolyte's dielectric constant. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Optimizing the Utility Power of a Geothermal Power Plant using Variable Frequency Drive (VFD) (Case Study: Sibayak Geothermal Power Plant)

NASA Astrophysics Data System (ADS)

Sinaga, R. H. M.; Manik, Y.

2018-03-01

Sibayak Geothermal Power Plant (SGPP) is one of the plants being developed by Pertamina Geothermal Energy (PGE) at the upstream phase. At the downstream phase, State - owned Electricity Company (PLN) through PT. Dizamatra Powerindo is the developer. The gross capacity of the power plant is 13.3 MW, consisting 1 unit of Monoblock (2 MW) developed by PGE and 2 units (2×5.65 MW) operated through Energy Sales Contract by PLN. During the development phase of a geothermal power plant, there is a chance to reduce the utility power in order to increase the overall plant efficiency. Reducing the utility power can be attempted by utilizing the wet bulb temperature fluctuation. In this study, a modeling process is developed by using Engineering Equation Solver (EES) software version 9.430. The possibility of energy saving is indicated by condenser pressure changes as a result of wet bulb temperature fluctuation. The result of this study indicates that the change of condenser pressure is about 50.8% on the constant liquid/gas (L/G) condition of the wet bulb temperature of 15°C to 25°C. Further result indicates that in this power plant, Cooling Tower Fan (CTF) is the facility that has the greatest utility load, followed by Hot Well Pump (HWP). The saving of the greatest utility load is applied trough Variable Frequency Drive (VFD) instrumentation. The result of this modeling has been validated by actual operations data (log sheet). The developed model has also been reviewed trough Specific Steam Consumption (SSC), resulting that constant L/G condition allows the optimum condition on of the wet bulb temperature of 15°C to 25°C.

Numerical calculations of temperature dependence of dielectric constant for an ordered assembly of BaTiO3 nanocubes with small tilt angles

NASA Astrophysics Data System (ADS)

Yasui, Kyuichi; Mimura, Ken-ichi; Izu, Noriya; Kato, Kazumi

2018-03-01

The dielectric constant of an ordered assembly of BaTiO3 nanocubes is numerically calculated as a function of temperature assuming a distribution of tilt angles of attached nanocubes. As the phase transition temperature from the tetragonal crystal structure to the cubic crystal structure of a BaTiO3 nanocube decreases as the tilt angle increases, the temperature at the peak of the dielectric constant of an ordered assembly is considerably lower than the Curie temperature of a free-standing BaTiO3 crystal. The peak of the dielectric constant as a function of temperature for an ordered assembly becomes considerably broader than that for a single crystal owing to the contribution of nanocubes with various tilt angles.

Thermal response of large area high temperature superconducting YBaCuO infrared bolometers

NASA Technical Reports Server (NTRS)

Khalil, Ali E.

1991-01-01

Thermal analysis of large area high temperature superconducting infrared detector operating in the equilibrium mode (bolometer) was performed. An expression for the temperature coefficient beta = 1/R(dR/dT) in terms of the thermal conductance and the thermal time constant of the detector were derived. A superconducting transition edge bolometer is a thermistor consisting of a thin film superconducting YBaCuO evaporated into a suitable thermally isolated substrate. The operating temperature of the bolometer is maintained close to the midpoint of the superconducting transition region where the resistance R has a maximum dynamic range. A detector with a strip configuration was analyzed and an expression for the temperature rise (delta T) above the ambient due to a uniform illumination with a source of power density was calculated. An expression for the thermal responsibility depends upon the spatial modulation frequency and the angular frequency of the incoming radiation. The problem of the thermal cross talk between different detector elements was addressed. In the case of monolithic HTS detector array with a row of square elements of dimensions 2a and CCD or CID readout electronics the thermal spread function was derived for different spacing between elements.

A study on die wear model of warm and hot forgings

NASA Astrophysics Data System (ADS)

Kang, J. H.; Park, I. W.; Jae, J. S.; Kang, S. S.

1998-05-01

Factors influencing service lives of tools in warm and hot forging processes are wear, mechanical fatigue, plastic deformation and thermal fatigue, etc. Wear is the predominant factor for tool failure among these. To predict tool life by wear, Archard's model where hardness is considered as constant or function of temperature is generally applied. Usually hardness of die is a function of not only temperature but operating time of die. To consider softening of die by repeated operation it is necessary to express hardness of die by a function of temperature and time. In this study wear coefficients were measured for various temperatures and heat treatment for H13 tool steel. Also by experiment of reheating of die, die softening curves were obtained. From experimental results, relationships between tempering parameters and hardness were established to investigate effects of hardness decrease by the effect of temperatures and time. Finally modified Archard's wear model in which hardness is considered to be a function of main tempering curve was proposed. And finite element analyses were conducted by adopting suggested wear model. By comparisons of simulations and real profiles of worn die, proposed wear model was verified.

Study of Creep of Alumina-Forming Austenitic Stainless Steel for High-Temperature Energy Applications

NASA Astrophysics Data System (ADS)

Afonina, Natalie Petrovna

To withstand the high temperature (>700°C) and pressure demands of steam turbines and boilers used for energy applications, metal alloys must be economically viable and have the necessary material properties, such as high-temperature creep strength, oxidation and corrosion resistance, to withstand such conditions. One promising class of alloys potentially capable of withstanding the rigors of aggressive environments, are alumina-forming austenitic stainless steels (AFAs) alloyed with aluminum to improve corrosion and oxidation resistance. The effect of aging on the microstructure, high temperature constant-stress creep behavior and mechanical properties of the AFA-type alloy Fe-20Cr-30Ni-2Nb-5Al (at.%) were investigated in this study. The alloy's microstructural evolution with increased aging time was observed prior to creep testing. As aging time increased, the alloy exhibited increasing quantities of fine Fe2Nb Laves phase dispersions, with a precipitate-free zone appearing in samples with higher aging times. The presence of the L1 2 phase gamma'-Ni3Al precipitate was detected in the alloy's matrix at 760°C. A constant-stress creep rig was designed, built and its operation validated. Constant-stress creep tests were performed at 760°C and 35MPa, and the effects of different aging conditions on creep rate were investigated. Specimens aged for 240 h exhibited the highest creep rate by a factor of 5, with the homogenized sample having the second highest rate. Samples aged for 2.4 h and 24 h exhibited similar low secondary creep rates. Creep tests conducted at 700oC exhibited a significantly lower creep rate compared to those at 760oC. Microstructural analysis was performed on crept samples to explore high temperature straining properties. The quantity and size of Fe2Nb Laves phase and NiAl particles increased in the matrix and on grain boundaries with longer aging time. High temperature tensile tests were performed and compared to room temperature results. The high temperature results were significantly lower when compared to room temperature values. Higher creep rates were correlated with lower yield strengths.

Enhanced detection of nitrogen dioxide via combined heating and pulsed UV operation of indium oxide nano-octahedra.

PubMed

Gonzalez, Oriol; Roso, Sergio; Vilanova, Xavier; Llobet, Eduard

2016-01-01

We report on the use of combined heating and pulsed UV light activation of indium oxide gas sensors for enhancing their performance in the detection of nitrogen dioxide in air. Indium oxide nano-octahedra were synthesized at high temperature (900 °C) via vapour-phase transport and screen-printed onto alumina transducers that comprised interdigitated electrodes and a heating resistor. Compared to the standard, constant temperature operation of the sensor, mild heating (e.g., 100 °C) together with pulsed UV light irradiation employing a commercially available, 325 nm UV diode (square, 1 min period, 15 mA drive current signal), results in an up to 80-fold enhancement in sensitivity to nitrogen dioxide. Furthermore, this combined operation method allows for making savings in power consumption that range from 35% to over 80%. These results are achieved by exploiting the dynamics of sensor response under pulsed UV light, which convey important information for the quantitative analysis of nitrogen dioxide.

21 CFR 1250.85 - Drinking fountains and coolers; ice; constant temperature bottles.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Drinking fountains and coolers; ice; constant... Drinking fountains and coolers; ice; constant temperature bottles. (a) Drinking fountains and coolers shall... prevent backflow. (b) Ice shall not be permitted to come in contact with water in coolers or constant...

21 CFR 1250.85 - Drinking fountains and coolers; ice; constant temperature bottles.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Drinking fountains and coolers; ice; constant... Drinking fountains and coolers; ice; constant temperature bottles. (a) Drinking fountains and coolers shall... prevent backflow. (b) Ice shall not be permitted to come in contact with water in coolers or constant...

21 CFR 1250.85 - Drinking fountains and coolers; ice; constant temperature bottles.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Drinking fountains and coolers; ice; constant... Drinking fountains and coolers; ice; constant temperature bottles. (a) Drinking fountains and coolers shall... prevent backflow. (b) Ice shall not be permitted to come in contact with water in coolers or constant...

21 CFR 1250.85 - Drinking fountains and coolers; ice; constant temperature bottles.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Drinking fountains and coolers; ice; constant... Drinking fountains and coolers; ice; constant temperature bottles. (a) Drinking fountains and coolers shall... prevent backflow. (b) Ice shall not be permitted to come in contact with water in coolers or constant...

21 CFR 1250.85 - Drinking fountains and coolers; ice; constant temperature bottles.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Drinking fountains and coolers; ice; constant... Drinking fountains and coolers; ice; constant temperature bottles. (a) Drinking fountains and coolers shall... prevent backflow. (b) Ice shall not be permitted to come in contact with water in coolers or constant...

Improvements on the stability and operation of a magnetron H - ion source

DOE PAGES

Sosa, A.; Bollinger, D. S.; Karns, P. R.; ...

2017-05-31

The magnetron H - ion sources developed in the 1970s currently in operation at Fermilab provide beam to the rest of the accelerator complex. A series of modifications to these sources have been tested in a dedicated offline test stand with the aim of improving different operational issues. The solenoid type gas valve was tested as an alternative to the piezoelectric gas valve in order to avoid its temperature dependence. A new cesium oven was designed and tested in order to avoid glass pieces that were present with the previous oven, improve thermal insulation and fine tune its temperature. Amore » current-regulated arc modulator was developed to run the ion source at a constant arc current, providing very stable beam outputs during operations. In order to reduce beam noise, the addition of small amounts of N 2 gas was explored, as well as testing different cathode shapes with increasing plasma volume. This study summarizes the studies and modifications done in the source over the last three years with the aim of improving its stability, reliability and overall performance.« less

Improvements on the stability and operation of a magnetron H- ion source

NASA Astrophysics Data System (ADS)

Sosa, A.; Bollinger, D. S.; Karns, P. R.; Tan, C. Y.

2017-05-01

The magnetron H- ion sources developed in the 1970s currently in operation at Fermilab provide beam to the rest of the accelerator complex. A series of modifications to these sources have been tested in a dedicated off-line test stand with the aim of improving different operational issues. The solenoid type gas valve was tested as an alternative to the piezoelectric gas valve in order to avoid its temperature dependence. A new cesium oven was designed and tested in order to avoid glass pieces that were present with the previous oven, improve thermal insulation and fine-tune its temperature. A current-regulated arc modulator was developed to run the ion source at a constant arc current, providing very stable beam outputs during operations. In order to reduce beam noise, the addition of small amounts of N2 gas was explored, as well as testing different cathode shapes with increasing plasma volume. This paper summarizes the studies and modifications done in the source over the past three years with the aim of improving its stability, reliability and overall performance.

Improvements on the stability and operation of a magnetron H - ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sosa, A.; Bollinger, D. S.; Karns, P. R.

The magnetron H - ion sources developed in the 1970s currently in operation at Fermilab provide beam to the rest of the accelerator complex. A series of modifications to these sources have been tested in a dedicated offline test stand with the aim of improving different operational issues. The solenoid type gas valve was tested as an alternative to the piezoelectric gas valve in order to avoid its temperature dependence. A new cesium oven was designed and tested in order to avoid glass pieces that were present with the previous oven, improve thermal insulation and fine tune its temperature. Amore » current-regulated arc modulator was developed to run the ion source at a constant arc current, providing very stable beam outputs during operations. In order to reduce beam noise, the addition of small amounts of N 2 gas was explored, as well as testing different cathode shapes with increasing plasma volume. This study summarizes the studies and modifications done in the source over the last three years with the aim of improving its stability, reliability and overall performance.« less

Molecular diversity of mesophilic and thermophilic bacteria in a membrane bioreactor determined by fluorescent in situ hybridization with mxaF- and rRNA-targeted probes.

PubMed

Dias, João Carlos T; Silva, Cláudio M; Mounteer, Ann H; Passos, Flavia M L; Linardi, Valter R

2003-01-01

An evaluation of the efficiency of treatment of kraft mill foul condensates in a membrane bioreactor was carried out in the laboratory. Efficiency and rate of methanol removal were quantified at operating temperatures of 35, 45 and 55 degrees C. The structure of the bacterial community present in the reactor biomass at the different operating temperatures was evaluated by in situ hybridization of the biomass samples with fluorescently-labelled probes (FISH) targeting the Eubacteria, the alpha, beta and gamma subclasses of the Proteobacteria, the low G + C content Gram-positive bacteria (Bacillus spp.), while community function was evaluated by in situ hybridization with a methanol dehydrogenase gene (mxaF) probe. Methanol removal efficiency decreased from 99.4 to 92%, and removal rate from 2.69 mg MeOH/l x min to 2.49 mg MeOH/l x min when the operating temperature was increased from 35 to 55 degrees C. This decrease in methanol removal was accompanied by a decrease (from 58% to 42%) in the relative proportion of cells that hybridized with the mxaF probe. The relative proportion of Bacillus spp. increased from 5 to 20% while the proportion of members of the alpha subclass of Proteobacteria decreased from 16% to 6% when the bioreactor operating temperature was raised from 35 to 55 degrees C. The relative proportions of bacteria belonging to the beta (22-25%) and gamma (18-20%) subclasses of the Proteobacteria remained relatively constant regardless of operating temperature. Proteobacteria (alpha, beta and gamma subclasses) and Bacillus spp. represented 61, 67 and 71% of the Eubacteria in the biomass sampled at 35, 45 and 55 degrees C, respectively. The FISH technique was shown to be an efficient method for detection of both structural and functional changes in the bacterial communities that could be related to efficiency of methanol removal in a membrane bioreactor operating at different temperatures.

Data mining of space heating system performance in affordable housing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, Xiaoxin; Yan, Da; Hong, Tianzhen

The space heating in residential buildings accounts for a considerable amount of the primary energy use. Therefore, understanding the operation and performance of space heating systems becomes crucial in improving occupant comfort while reducing energy use. This study investigated the behavior of occupants adjusting their thermostat settings and heating system operations in a 62-unit affordable housing complex in Revere, Massachusetts, USA. The data mining methods, including clustering approach and decision trees, were used to ascertain occupant behavior patterns. Data tabulating ON/OFF space heating states was assessed, to provide a better understanding of the intermittent operation of space heating systems inmore » terms of system cycling frequency and the duration of each operation. The decision tree was used to verify the link between room temperature settings, house and heating system characteristics and the heating energy use. The results suggest that the majority of apartments show fairly constant room temperature profiles with limited variations during a day or between weekday and weekend. Data clustering results revealed six typical patterns of room temperature profiles during the heating season. Space heating systems cycled more frequently than anticipated due to a tight range of room thermostat settings and potentially oversized heating capacities. In conclusion, from this study affirm data mining techniques are an effective method to analyze large datasets and extract hidden patterns to inform design and improve operations.« less

Data mining of space heating system performance in affordable housing

DOE PAGES

Ren, Xiaoxin; Yan, Da; Hong, Tianzhen

2015-02-16

The space heating in residential buildings accounts for a considerable amount of the primary energy use. Therefore, understanding the operation and performance of space heating systems becomes crucial in improving occupant comfort while reducing energy use. This study investigated the behavior of occupants adjusting their thermostat settings and heating system operations in a 62-unit affordable housing complex in Revere, Massachusetts, USA. The data mining methods, including clustering approach and decision trees, were used to ascertain occupant behavior patterns. Data tabulating ON/OFF space heating states was assessed, to provide a better understanding of the intermittent operation of space heating systems inmore » terms of system cycling frequency and the duration of each operation. The decision tree was used to verify the link between room temperature settings, house and heating system characteristics and the heating energy use. The results suggest that the majority of apartments show fairly constant room temperature profiles with limited variations during a day or between weekday and weekend. Data clustering results revealed six typical patterns of room temperature profiles during the heating season. Space heating systems cycled more frequently than anticipated due to a tight range of room thermostat settings and potentially oversized heating capacities. In conclusion, from this study affirm data mining techniques are an effective method to analyze large datasets and extract hidden patterns to inform design and improve operations.« less

Influence of environmental factors on activity patterns of Incisitermes minor (Isoptera: Kalotermitidae) in naturally infested logs.

PubMed

Lewis, Vernard R; Leighton, Shawn; Tabuchi, Robin; Baldwin, James A; Haverty, Michael I

2013-02-01

Acoustic emission (AE) activity patterns were measured from seven loquat [Eriobotrya japonica (Thunb.) Lindl.] logs, five containing live western drywood termite [Incisitermes minor (Hagen)] infestations, and two without an active drywood termite infestation. AE activity, as well as temperature, were monitored every 3 min under unrestricted ambient conditions in a small wooden building, under unrestricted ambient conditions but in constant darkness, or in a temperature-controlled cabined under constant darkness. Logs with active drywood termite infestations displayed similar diurnal cycles of AE activity that closely followed temperature with a peak of AE activity late in the afternoon (1700-1800 hours). When light was excluded from the building, a circadian pattern continued and apparently was driven by temperature. When the seven logs were kept at a relatively constant temperature (approximately 23 +/- 0.9 degrees C) and constant darkness, the pattern of activity was closely correlated with temperature, even with minimal changes in temperature. Temperature is the primary driver of activity of these drywood termites, but the effects are different when temperature is increasing or decreasing. At constant temperature, AE activity was highly correlated with the number of termites in the logs. The possible implications of these findings on our understanding of drywood termite biology and how this information may affect inspections and posttreatment evaluations are discussed.

Systematic error of diode thermometer.

PubMed

Iskrenovic, Predrag S

2009-08-01

Semiconductor diodes are often used for measuring temperatures. The forward voltage across a diode decreases, approximately linearly, with the increase in temperature. The applied method is mainly the simplest one. A constant direct current flows through the diode, and voltage is measured at diode terminals. The direct current that flows through the diode, putting it into operating mode, heats up the diode. The increase in temperature of the diode-sensor, i.e., the systematic error due to self-heating, depends on the intensity of current predominantly and also on other factors. The results of systematic error measurements due to heating up by the forward-bias current have been presented in this paper. The measurements were made at several diodes over a wide range of bias current intensity.

Simulated Seasonal Photoperiods and Fluctuating Temperatures Have Limited Effects on Blood Feeding and Life History in Aedes triseriatus (Diptera: Culicidae)

PubMed Central

Westby, K. M.

2015-01-01

Biotic and abiotic factors change seasonally and impact life history in temperate-zone ectotherms. Temperature and photoperiod are factors that change in predictable ways. Most studies testing for effects of temperature on vectors use constant temperatures and ignore potential correlated effects of photoperiod. In two experiments, we tested for effects of larval rearing environments creating ecologically relevant temperatures and photoperiods simulating early and late season conditions (June and August), or constant temperatures (cool and warm) with the June or August photoperiods, respectively. We determined effects on survivorship, development, size, and a composite performance index in a temperate-zone population of Aedes triseriatus (Say). We followed cohorts of resulting females, all held under the same environmental conditions, to assess carry-over effects of rearing conditions for larvae on longevity, blood feeding, and egg production. Larval survivorship was affected by treatment in one experiment. Development time was greater in the June and cool treatments, but the constant and fluctuating temperatures did not differ. Significantly larger mosquitoes were produced in fluctuating versus constant temperature treatments. There were no significant treatment effects on the composite performance index. Adult female longevity was lower after rearing at constant versus fluctuating temperature, but there was no difference between June and August, nor did size affect longevity. There was no effect of treatments on blood feeding and a limited effect on egg production. We conclude that seasonal temperatures and photoperiods during development have limited effects on this population of A. triseriatus and find little evidence of strong effects of fluctuating versus constant temperatures. PMID:26336255

Temperature and pressure dependence of the absolute rate constant for the reactions of NH2 radicals with acetylene and ethylene

NASA Technical Reports Server (NTRS)

Bosco, S. R.; Nava, D. F.; Brobst, W. D.; Stief, L. J.

1984-01-01

The absolute rate constants for the reaction between the NH2 free radical and acetylene and ethylene is measured experimentally using a flash photolysis technique. The constant is considered to be a function of temperature and pressure. At each temperature level of the experiment, the observed pseudo-first-order rate constants were assumed to be independent of flash intensity. The results of the experiment indicate that the bimolecular rate constant for the NH2 + C2H2 reaction increases with pressure at 373 K and 459 K but not at lower temperatures. Results near the pressure limit conform to an Arrhenius expression of 1.11 (+ or -) 0.36 x 10 to the -13th over the temperature range from 241 to 459 K. For the reaction NH2 + C2H4, a smaller rate of increase in the bimolecular rate constant was observed over the temperature range 250-465 K. The implications of these results for current theoretical models of NH2 + C2H2 (or H4) reactions in the atmospheres of Jupiter and Saturn are discussed.

Irreversible Brownian Heat Engine

NASA Astrophysics Data System (ADS)

Taye, Mesfin Asfaw

2017-10-01

We model a Brownian heat engine as a Brownian particle that hops in a periodic ratchet potential where the ratchet potential is coupled with a linearly decreasing background temperature. We show that the efficiency of such Brownian heat engine approaches the efficiency of endoreversible engine η =1-√{{Tc/Th}} [23]. On the other hand, the maximum power efficiency of the engine approaches η ^{MAX}=1-({Tc/Th})^{1\\over 4}. It is shown that the optimized efficiency always lies between the efficiency at quasistatic limit and the efficiency at maximum power while the efficiency at maximum power is always less than the optimized efficiency since the fast motion of the particle comes at the expense of the energy cost. If the heat exchange at the boundary of the heat baths is included, we show that such a Brownian heat engine has a higher performance when acting as a refrigerator than when operating as a device subjected to a piecewise constant temperature. The role of time on the performance of the motor is also explored via numerical simulations. Our numerical results depict that the time t and the external load dictate the direction of the particle velocity. Moreover, the performance of the heat engine improves with time. At large t (steady state), the velocity, the efficiency and the coefficient of performance of the refrigerator attain their maximum value. Furthermore, we study the effect of temperature by considering a viscous friction that decreases exponentially as the background temperature increases. Our result depicts that the Brownian particle exhibits a fast unidirectional motion when the viscous friction is temperature dependent than that of constant viscous friction. Moreover, the efficiency of this motor is considerably enhanced when the viscous friction is temperature dependent. On the hand, the motor exhibits a higher performance of the refrigerator when the viscous friction is taken to be constant.

A PC-based high temperature gas reactor simulator for Indonesian conceptual HTR reactor basic training

NASA Astrophysics Data System (ADS)

Syarip; Po, L. C. C.

2018-05-01

In planning for nuclear power plant construction in Indonesia, helium cooled high temperature reactor (HTR) is favorable for not relying upon water supply that might be interrupted by earthquake. In order to train its personnel, BATAN has cooperated with Micro-Simulation Technology of USA to develop a 200 MWt PC-based simulation model PCTRAN/HTR. It operates in Win10 environment with graphic user interface (GUI). Normal operation of startup, power maneuvering, shutdown and accidents including pipe breaks and complete loss of AC power have been conducted. A sample case of safety analysis simulation to demonstrate the inherent safety features of HTR was done for helium pipe break malfunction scenario. The analysis was done for the variation of primary coolant pipe break i.e. from 0,1% - 0,5 % and 1% - 10 % helium gas leakages, while the reactor was operated at the maximum constant power of 10 MWt. The result shows that the highest temperature of HTR fuel centerline and coolant were 1150 °C and 1296 °C respectively. With 10 kg/s of helium flow in the reactor core, the thermal power will back to the startup position after 1287 s of helium pipe break malfunction.

Comparative habitat ecology of Texas and masked bobwhites

USGS Publications Warehouse

Guthery, F.S.; King, N.M.; Nolte, K.R.; Kuvlesky, W.P.; DeStefano, S.; Gall, S.A.; Silvy, N.J.

2000-01-01

The habitat ecology of masked bobwhites (Colinus virginianus ridgwayi) is poorly understood, which hampers recovery efforts for this endangered bird. During 1994-96, we analyzed the habitat ecology of masked bobwhites in Sonora, Mexico, and Arizona, and compared these findings with the habitat ecology of Texas bobwhites (C. v. texanus) in southern Texas. Mean values for the quantity of low screening cover (<50 cm aboveground), operative temperature (??C), and exposure to aerial predators were relatively constant across regions (CV <14.2%), indicating these variables are important in adaptive habitat-use decisions by bobwhites. Bobwhites exhibited preference in all regions for higher canopy coverage of woody vegetation, lower exposure to aerial predators, and lower operative temperatures in comparison with randomly available conditions. The major habitat deficiencies for masked bobwhites were lack of woody and herbaceous cover, which led to high exposure to aerial predators in Sonora and Arizona. High operative temperatures at quail level were associated with the loss of ???24% of potential habitat space-time in Texas, Sonora, and Arizona. Management to improve habitat for masked bobwhites includes any practice that increases canopy coverage of woody vegetation, and height and coverage of herbaceous vegetation.

Microstructural analysis of 800H steel exposed at test operation in HTHL by using FIB-SEM and HRTEM techniques

NASA Astrophysics Data System (ADS)

Marušáková, Daniela; Bublíková, Petra; Berka, Jan; Vávrovcová, Zuzana; Burda, Jaroslav

2017-09-01

To understand the degradation process of metal materials which are used in power engineering, appropriate evaluation procedure is necessary to ensure. In that order, the degradation of alloy 800H during the first period of test operation in High Temperature Helium Loop (HTHL) was tested. Experiment was carried out in atmosphere of pure technical helium with purity 4.6 containing only residual concentration of moisture up to 300 vppm. Parameters during the operation test were not constant, process was interrupted several times. The maximum temperature on specimens during this period was 750 °C, average temperature was 460 °C, gas pressure ranged from 3 to 6 MPa and gas flow from 3 to 9 gs-1. Total duration of the test was 264 h. After the exposure the degradation of specimens was investigated by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). Using the technique of Focused Ion Beam (FIB) integrated within SEM the transparent samples with quality surface parameters were obtained for TEM analysis. FIB technique in combination with High Resolution TEM ensured the guaranteed methodology of exposed sample preparation and precise description of changes in this kind of material.

Advanced turbine study. [airfoil coling in rocket turbines

NASA Technical Reports Server (NTRS)

1982-01-01

Experiments to determine the available increase in turbine horsepower achieved by increasing turbine inlet temperature over a range of 1800 to 2600 R, while applying current gas turbine airfoil cling technology are discussed. Four cases of rocket turbine operating conditions were investigated. Two of the cases used O2/H2 propellant, one with a fuel flowrate of 160 pps, the other 80 pps. Two cases used O2/CH4 propellant, each having different fuel flowrates, pressure ratios, and inlet pressures. Film cooling was found to be the required scheme for these rocket turbine applications because of the high heat flux environments. Conventional convective or impingement cooling, used in jet engines, is inadequate in a rocket turbine environment because of the resulting high temperature gradients in the airfoil wall, causing high strains and low cyclic life. The hydrogen-rich turbine environment experienced a loss, or no gain, in delivered horsepower as turbine inlet temperature was increased at constant airfoil life. The effects of film cooling with regard to reduced flow available for turbine work, dilution of mainstream gas temperature and cooling reentry losses, offset the relatively low specific work capability of hydrogen when increasing turbine inlet temperature over the 1800 to 2600 R range. However, the methane-rich environment experienced an increase in delivered horsepower as turbine inlet temperature was increased at constant airfoil life. The results of a materials survey and heat transfer and durability analysis are discussed.

Reactivity Coefficient Calculation for AP1000 Reactor Using the NODAL3 Code

NASA Astrophysics Data System (ADS)

Pinem, Surian; Malem Sembiring, Tagor; Tukiran; Deswandri; Sunaryo, Geni Rina

2018-02-01

The reactivity coefficient is a very important parameter for inherent safety and stability of nuclear reactors operation. To provide the safety analysis of the reactor, the calculation of changes in reactivity caused by temperature is necessary because it is related to the reactor operation. In this paper, the temperature reactivity coefficients of fuel and moderator of the AP1000 core are calculated, as well as the moderator density and boron concentration. All of these coefficients are calculated at the hot full power condition (HFP). All neutron diffusion constant as a function of temperature, water density and boron concentration were generated by the SRAC2006 code. The core calculations for determination of the reactivity coefficient parameter are done by using NODAL3 code. The calculation results show that the fuel temperature, moderator temperature and boron reactivity coefficients are in the range between -2.613 pcm/°C to -4.657pcm/°C, -1.00518 pcm/°C to 1.00649 pcm/°C and -9.11361 pcm/ppm to -8.0751 pcm/ppm, respectively. For the water density reactivity coefficients, the positive reactivity occurs at the water temperature less than 190 °C. The calculation results show that the reactivity coefficients are accurate because the results have a very good agreement with the design value.

Immobilization of polyphenol oxidase in conducting copolymers and determination of phenolic compounds in wines with enzyme electrodes.

PubMed

Kiralp, Senem; Toppare, Levent; Yağci, Yusuf

2003-11-01

Polyphenol oxidase (PPO) was immobilized in copolymers of thiophene functionalized menthyl monomer (MM) with pyrrole. Immobilization of enzyme was performed via entrapment in conducting copolymers during electrochemical polymerization of pyrrole. Maximum reaction rates, Michaelis-Menten constants and temperature, pH and operational stabilities of enzyme electrodes were investigated. Total amount of phenolic compounds in red wines of Turkey were analyzed by using these electrodes.

Study of the performances of nano-case treatment cutting tools on carbon steel work material during turning operation

NASA Astrophysics Data System (ADS)

Afolalu, S. A.; Okokpujie, I. P.; Salawu, E. Y.; Abioye, A. A.; Abioye, O. P.; Ikumapayi, O. M.

2018-04-01

The degree of holding temperature and time play a major role in nano-case treatment of cutting tools which immensely contributed to its performance during machining operation. The objective of this research work is to carryout comparative study of performance of nano-case treatment tools developed using low and medium carbon steel as work piece. Turning operation was carried out under two different categories with specific work piece on universal lathe machine using HSS cutting tools 100 mm × 12mm × 12mm that has been nano-case treated under varying conditions of temperatures and timeof 800,850, 900, 950°C and 60, 90, 120 mins respectively. The turning parameters used in evaluating this experiment were cutting speed of 270, 380 and 560mm/min, feed rate of 0.15, 0.20 and 0.25 mm/min, depth of cut of 2mm, work piece diameter of 25mm and rake angle of 7° each at three levels. The results of comparative study of their performances revealed that the timespent in the machining of low carbon steel material at a minimum temperature and time of 800°C, 60 mins were1.50, 2.17 mins while at maximum temperature and time of 950°C, 120 mins were 1.19, 2.02 mins. It was also observed that at a corresponding constant speed of 270,380 and 560mm/min at higher temperature and time, a relative increased in the length of cut were observed. Critical observation of the result showed that at higher case hardening temperature and time (950°C/120mins), the HSS cutting tool gave a better performance as lesser time was consumed during the turning operation.

Characterization and evaluation of an aeolian-photovoltaic system in operation

NASA Astrophysics Data System (ADS)

Bonfatti, F.; Calzolari, P. U.; Cardinali, G. C.; Vivanti, G.; Zani, A.

Data management, analysis techniques and results of performance monitoring of a prototype combined photovoltaic (PV)-wind turbine farm power plant in northern Italy are reported. Emphasis is placed on the PV I-V characteristics and irradiance and cell temperatures. Automated instrumentation monitors and records meteorological data and generator variables such as voltages, currents, output, battery electrolyte temperature, etc. Analysis proceeds by automated selection of I-V data for specific intervals of the year when other variables can be treated as constants. The technique permits characterization of generator performance, adjusting the power plant set points for optimal output, and tracking performance degradation over time.

A continuous dry 300 mK cooler for THz sensing applications.

PubMed

Klemencic, G M; Ade, P A R; Chase, S; Sudiwala, R; Woodcraft, A L

2016-04-01

We describe and demonstrate the automated operation of a novel cryostat design that is capable of maintaining an unloaded base temperature of less than 300 mK continuously, without the need to recycle the gases within the final cold head, as is the case for conventional single shot sorption pumped (3)He cooling systems. This closed dry system uses only 5 l of (3)He gas, making this an economical alternative to traditional systems where a long hold time is required. During testing, a temperature of 365 mK was maintained with a constant 20 μW load, simulating the cooling requirement of a far infrared camera.

A capital cost comparison of commercial ground-source heat pump systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rafferty, K.

1994-06-01

The purpose of the report is to compare capital costs associated with the three designs of ground source heat pumps. Specifically, the costs considered are those associated with the heat source/heat sink or ground source portion of the system. In order to standardize the heat rejection over the three designs, it was assumed that the heat pump loop would operate at a temperature range of 85{degree} (to the heat pumps) to 95{degree} (from the heat pumps) under peak conditions. The assumption of constant loop temperature conditions for all three permits an apples-to-apples comparison of the alternatives.

Materials for high-temperature thermoelectric conversion

NASA Technical Reports Server (NTRS)

Feigelson, R. S.; Elwell, D.

1983-01-01

High boron materials of high efficiency for thermoelectric power generation and capable of prolonged operation at temperatures over 1200 C are discussed. Background theoretical studies indicated that the low carrier mobility of materials with beta boron and related structures is probably associated with the high density of traps. Experimental work was mainly concerned with silicon borides in view of promising data from European laboratories. A systematic study using structure determination and lattice constant measurements failed to confirm the existence of an SiBn phase. Only SiB6 and a solid solution of silicon in beta boron with a maximum solid solubility of 5.5-6 at % at 1650 C were found.

Disparate effects of constant and annually-cycling daylength and water temperature on reproductive maturation of striped bass (Morone saxatilis)

USGS Publications Warehouse

Clark, R.W.; Henderson-Arzapalo, A.; Sullivan, C.V.

2005-01-01

Adult striped bass (Morone saxatilis) were exposed to various combinations of constant or anually-cycling daylength and water temperature. Constant conditions (15 h days, 18??C) were those normally experienced at spawning and cycling conditions simulated natural changes at Chesapeake Bay latitude. Females exposed to constant long (15 h) days and cycling water temperature (TEMPERATURE group) had blood plasma levels of sex steroids (testosterone [T] and estradiol-17?? [E2]) and vitellogenin (Vg), and profiles of oocyte growth, that were nearly identical to those of females held under a natural photothermal cycle (CONTROL group). Several fish from these two groups were induced to spawn fertile eggs. Females constantly exposed to warm water (18??C), with or without a natural photoperiod cycle (PHOTOPERIOD and STATIC groups, respectively), had diminished circulating levels of gonadal steroid hormones and Vg, impaired deposition of yolk granules in their ooplasm, and decreased oocyte growth, and they underwent premature ovarian atresia. Males exposed to cycling water temperature (CONTROL and TEMPERATURE groups) spermiated synchronously during the natural breeding season, at which time they also had had high plasma androgen (T and 11-ketotestosterone [11-KT]) levels. The timing of spermiation was highly asynchronous among males in groups of fish held constantly at 18??C (STATIC and PHOTOPERIOD groups) and this asynchrony was associated with diminished plasma androgen levels. Termination of spermiation by males exposed to cycling water temperature coincided with a sharp decline in levels of plasma androgens about a month after water temperature rose above 18??C. In contrast, most males held constantly at 18??C sustained intermediate levels of plasma androgens and spermiated until the end of the study in late July. The annual cycle of water temperature clearly plays a prominent role in the initiation, maintenance, and termination of the striped bass reproductive cycle. In females, a decrease in water temperature below values experienced at spawning appears to be required for vitellogenesis and oocyte growth to proceed normally. Constant exposure of males to spawning temperature disrupts synchronous spermiation but also delays testicular regression, which may be useful for spawning fish after the natural reproductive season.

A New Type of Tea Baking Machine Based on Pro/E Design

NASA Astrophysics Data System (ADS)

Lin, Xin-Ying; Wang, Wei

2017-11-01

In this paper, the production process of wulong tea was discussed, mainly the effect of baking on the quality of tea. The suitable baking temperature of different tea was introduced. Based on Pro/E, a new type of baking machine suitable for wulong tea baking was designed. The working principle, mechanical structure and constant temperature timing intelligent control system of baking machine were expounded. Finally, the characteristics and innovation of new baking machine were discussed.The mechanical structure of this baking machine is more simple and reasonable, and can use the heat of the inlet and outlet, more energy saving and environmental protection. The temperature control part adopts fuzzy PID control, which can improve the accuracy and response speed of temperature control and reduce the dependence of baking operation on skilled experience.

On the room temperature multiferroic BiFeO3: magnetic, dielectric and thermal properties

NASA Astrophysics Data System (ADS)

Lu, J.; Günther, A.; Schrettle, F.; Mayr, F.; Krohns, S.; Lunkenheimer, P.; Pimenov, A.; Travkin, V. D.; Mukhin, A. A.; Loidl, A.

2010-06-01

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at mm-wavelengths, as well as ferroelectric polarization are reported for single crystalline BiFeO3. A well developed anomaly in the magnetic susceptibility signals the onset of antiferromagnetic order close to 635 K. Beside this anomaly no further indications of phase or glass transitions are indicated in the magnetic dc and ac susceptibilities down to the lowest temperatures. The heat capacity has been measured from 2 K up to room temperature and significant contributions from magnon excitations have been detected. From the low-temperature heat capacity an anisotropy gap of the magnon modes of the order of 6 meV has been determined. The dielectric constants measured in standard two-point configuration are dominated by Maxwell-Wagner like effects for temperatures T > 300 K and frequencies below 1 MHz. At lower temperatures the temperature dependence of the dielectric constant and loss reveals no anomalies outside the experimental errors, indicating neither phase transitions nor strong spin phonon coupling. The temperature dependence of the dielectric constant was measured contact free at microwave frequencies. At room temperature the dielectric constant has an intrinsic value of 53. The loss is substantial and strongly frequency dependent indicating the predominance of hopping conductivity. Finally, in small thin samples we were able to measure the ferroelectric polarization between 10 and 200 K. The saturation polarization is of the order of 40 μC/cm2, comparable to reports in literature.

Thermal characterizations analysis of high-power ThinGaN cool-white light-emitting diodes

NASA Astrophysics Data System (ADS)

Raypah, Muna E.; Devarajan, Mutharasu; Ahmed, Anas A.; Sulaiman, Fauziah

2018-03-01

Analysis of thermal properties plays an important role in the thermal management of high-power (HP) lighting-emitting diodes (LEDs). Thermal resistance, thermal capacitance, and thermal time constant are essential parameters for the optimal design of the LED device and system, particularly for dynamic performance study. In this paper, thermal characterization and thermal time constant of ThinGaN HP LEDs are investigated. Three HP cool-white ThinGaN LEDs from different manufacturers are used in this study. A forward-voltage method using thermal transient tester (T3Ster) system is employed to determine the LEDs' thermal parameters at various operating conditions. The junction temperature transient response is described by a multi-exponential function model to extract thermal time constants. The transient response curve is divided into three layers and expressed by three exponential functions. Each layer is associated with a particular thermal time constant, thermal resistance, and thermal capacitance. It is found that the thermal time constant of LED package is on the order of 22 to 100 ms. Comparison between the experimental results is carried out to show the design effects on thermal performance of the LED package.

System Would Regulate Low Gas Pressure

NASA Technical Reports Server (NTRS)

Frazer, Robert E.

1994-01-01

System intended to maintain gases in containers at pressures near atmospheric. Includes ballast volume in form of underinflated balloon that communicates with working volume. Balloon housed in rigid chamber not subjected to extremes of temperature of working volume. Pressure in chamber surrounding balloon regulated at ambient atmospheric pressure or at constant small differential pressure above or below ambient. Expansion and contraction of balloon accommodates expansion or contraction of gas during operational heating or cooling in working volume, maintaining pressure in working volume at ambient or constant differential above or below ambient. Gas lost from system due to leakage or diffusion, low-pressure sensor responds, signaling valve actuators to supply more gas to working volume. If pressure rises too high, overpressure relief valve opens before excessive pressure damages system.

Artwork visualization using a solid-state lighting engine with controlled photochemical safety.

PubMed

Tuzikas, Arūnas; Žukauskas, Artūras; Vaicekauksas, Rimantas; Petrulis, Andrius; Vitta, Pranciškus; Shur, Michael

2014-07-14

A concept of a solid-state lighting engine for artwork-specific illumination with controlled photochemical safety is introduced. The engine is based on a tetrachromatic cluster of colored light-emitting diodes wirelessly controlled via an external smart device. By using an instantaneous dimming functionality, the driving software allows for maintaining the damage irradiance relevant to a particular type of photosensitive artwork material at a constant value, while varying the chromaticity and color rendition properties of the generated light. The effect of the constant damage irradiance on the visual impression from artworks is demonstrated for the lighting engine operating in three modes, such as selecting color temperature, tuning color saturating ability, and shifting chromaticity outside white light locus, respectively.

Design of laser diode driver with constant current and temperature control system

NASA Astrophysics Data System (ADS)

Wang, Ming-cai; Yang, Kai-yong; Wang, Zhi-guo; Fan, Zhen-fang

2017-10-01

A laser Diode (LD) driver with constant current and temperature control system is designed according to the LD working characteristics. We deeply researched the protection circuit and temperature control circuit based on thermos-electric cooler(TEC) cooling circuit and PID algorithm. The driver could realize constant current output and achieve stable temperature control of LD. Real-time feedback control method was adopted in the temperature control system to make LD work on its best temperature point. The output power variety and output wavelength shift of LD caused by current and temperature instability were decreased. Furthermore, the driving current and working temperature is adjustable according to specific requirements. The experiment result showed that the developed LD driver meets the characteristics of LD.

Using Mason number to predict MR damper performance from limited test data

NASA Astrophysics Data System (ADS)

Becnel, Andrew C.; Wereley, Norman M.

2017-05-01

The Mason number can be used to produce a single master curve which relates MR fluid stress versus strain rate behavior across a wide range of shear rates, temperatures, and applied magnetic fields. As applications of MR fluid energy absorbers expand to a variety of industries and operating environments, Mason number analysis offers a path to designing devices with desired performance from a minimal set of preliminary test data. Temperature strongly affects the off-state viscosity of the fluid, as the passive viscous force drops considerably at higher temperatures. Yield stress is not similarly affected, and stays relatively constant with changing temperature. In this study, a small model-scale MR fluid rotary energy absorber is used to measure the temperature correction factor of a commercially-available MR fluid from LORD Corporation. This temperature correction factor is identified from shear stress vs. shear rate data collected at four different temperatures. Measurements of the MR fluid yield stress are also obtained and related to a standard empirical formula. From these two MR fluid properties - temperature-dependent viscosity and yield stress - the temperature-corrected Mason number is shown to predict the force vs. velocity performance of a full-scale rotary MR fluid energy absorber. This analysis technique expands the design space of MR devices to high shear rates and allows for comprehensive predictions of overall performance across a wide range of operating conditions from knowledge only of the yield stress vs. applied magnetic field and a temperature-dependent viscosity correction factor.

Temperature and size-dependent Hamaker constants for metal nanoparticles

NASA Astrophysics Data System (ADS)

Jiang, K.; Pinchuk, P.

2016-08-01

Theoretical values of the Hamaker constant have been calculated for metal nanoparticles using Lifshitz theory. The theory describes the Hamaker constant in terms of the permittivity of the interacting bodies. Metal nanoparticles exhibit an internal size effect that alters the dielectric permittivity of the particle when its size falls below the mean free path of the conducting electrons. This size dependence of the permittivity leads to size-dependence of the Hamaker constant for metal nanoparticles. Additionally, the electron damping and the plasma frequency used to model the permittivity of the particle exhibit temperature-dependence, which lead to temperature dependence of the Hamaker constant. In this work, both the size and temperature dependence for gold, silver, copper, and aluminum nanoparticles is demonstrated. The results of this study might be of interest for studying the colloidal stability of nanoparticles in solution.

Temperature and size-dependent Hamaker constants for metal nanoparticles.

PubMed

Jiang, K; Pinchuk, P

2016-08-26

Theoretical values of the Hamaker constant have been calculated for metal nanoparticles using Lifshitz theory. The theory describes the Hamaker constant in terms of the permittivity of the interacting bodies. Metal nanoparticles exhibit an internal size effect that alters the dielectric permittivity of the particle when its size falls below the mean free path of the conducting electrons. This size dependence of the permittivity leads to size-dependence of the Hamaker constant for metal nanoparticles. Additionally, the electron damping and the plasma frequency used to model the permittivity of the particle exhibit temperature-dependence, which lead to temperature dependence of the Hamaker constant. In this work, both the size and temperature dependence for gold, silver, copper, and aluminum nanoparticles is demonstrated. The results of this study might be of interest for studying the colloidal stability of nanoparticles in solution.

Application of the compensated arrhenius formalism to dielectric relaxation.

PubMed

Petrowsky, Matt; Frech, Roger

2009-12-17

The temperature dependence of the dielectric rate constant, defined as the reciprocal of the dielectric relaxation time, is examined for several groups of organic solvents. Early studies of linear alcohols using a simple Arrhenius equation found that the activation energy was dependent on the chain length of the alcohol. This paper re-examines the earlier data using a compensated Arrhenius formalism that assumes the presence of a temperature-dependent static dielectric constant in the exponential prefactor. Scaling temperature-dependent rate constants to isothermal rate constants so that the dielectric constant dependence is removed results in calculated energies of activation E(a) in which there is a small increase with chain length. These energies of activation are very similar to those calculated from ionic conductivity data using compensated Arrhenius formalism. This treatment is then extended to dielectic relaxation data for n-alkyl bromides, n-nitriles, and n-acetates. The exponential prefactor is determined by dividing the temperature-dependent rate constants by the Boltzmann term exp(-E(a)/RT). Plotting the prefactors versus the static dielectric constant places the data on a single master curve for each group of solvents.

1.9 THz Quantum-cascade Lasers with One-well Injector

NASA Technical Reports Server (NTRS)

Kumar, Sushil; Williams, Benjamin S.; Hu, Qing; Reno, John L.

2006-01-01

We report terahertz quantum-cascade lasers operating predominantly at 1.90 THz with side modes as low as 1.86 THz (lambda approx. equal to 161 micrometers, planck's constant omega approx. equal to 7.7 meV). This is the longest wavelength to date of any solid-state laser that operates without assistance of a magnetic field. Carriers are injected into the upper radiative state by using a single quantum-well injector, which resulted in a significant reduction of free-carrier losses. The laser operated up to a heat-sink temperature of 110 K in pulsed mode, 95 K in continuous wave (cw) mode, and the threshold current density at 5 K was approx. 140 A per square centimeters.

Selectivity of the gas sensor based on the 50%In2O3-50%Ga2O3 thin film in dynamic mode of operation

NASA Astrophysics Data System (ADS)

Demin, I. E.; Kozlov, A. G.

2018-01-01

The article considers the gas sensor with the sensitive layer based on the 50%In2O3 -50%Ga2O3 thin film. The temperature and concentration dependencies of gas-induced resistance response of this sensor and the dynamical dependencies of its resistance response on the test gases in air are investigated. The test gases were ethanol, acetone, ammonia and liquefied petroleum gas. The information parameters of the sensor in the dynamical mode of operation were considered to improve its selectivity. The presented results show that the selectivity of the sensor in this mode may be improved by using the following information parameters: gas-induced resistance response in steady state, activation energy of the response and pre-exponential factor of the temperature dependence of the response time constant.

Wavelength dependence of Verdet constant of Tb{sup 3+}:Y{sub 2}O{sub 3} ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snetkov, I. L., E-mail: snetkov@appl.sci-nnov.ru; Palashov, O. V.; Permin, D. A.

2016-04-18

Samples of the magneto-active material—Tb{sup 3+}:Y{sub 2}O{sub 3} ceramics with Tb{sup 3+} ion concentrations of 10%, 20%, 30%, and 100% (Tb{sub 2}O{sub 3})—were prepared and studied. The wavelength dependence of Verdet constant in the 380 nm–1750 nm range was approximated for all investigated ceramic samples and was predicted for a pure Tb{sub 2}O{sub 3} material. Tb{sub 2}O{sub 3} ceramics demonstrates a more than three times higher Verdet constant in comparison with terbium gallium garnet crystal or ceramics. The linear dependence of the Verdet constant on Tb{sup 3+} ion concentration in the Tb{sup 3+}:Y{sub 2}O{sub 3} ceramics was demonstrated. The obtained data willmore » be useful for fabricating magneto-optical elements of Faraday devices based on Tb{sup 3+}:Y{sub 2}O{sub 3} with arbitrary Tb{sup 3+} ion concentration operating at room temperature in the wavelength range of 380 nm–1750 nm.« less

Carbon nanotube vacuum gauges with wide-dynamic range and processes thereof

NASA Technical Reports Server (NTRS)

Manohara, Harish (Inventor); Kaul, Anupama B. (Inventor)

2013-01-01

A miniature thermal conductivity gauge employs a carbon single-walled-nanotube. The gauge operates on the principle of thermal exchange between the voltage-biased nanotube and the surrounding gas at low levels of power and low temperatures to measure vacuum across a wide dynamic range. The gauge includes two terminals, a source of constant voltage to the terminals, a single-walled carbon nanotube between the terminals, a calibration of measured conductance of the nanotube to magnitudes of surrounding vacuum and a current meter in electrical communication with the source of constant voltage. Employment of the nanotube for measuring vacuum includes calibrating the electrical conductance of the nanotube to magnitudes of vacuum, exposing the nanotube to a vacuum, applying a constant voltage across the nanotube, measuring the electrical conductance of the nanotube in the vacuum with the constant voltage applied and converting the measured electrical conductance to the corresponding calibrated magnitude of vacuum using the calibration. The nanotube may be suspended to minimize heat dissipation through the substrate, increasing sensitivity at even tower pressures.

Determination of temperature dependence of full matrix material constants of PZT-8 piezoceramics using only one sample.

PubMed

Zhang, Yang; Tang, Liguo; Tian, Hua; Wang, Jiyang; Cao, Wenwu; Zhang, Zhongwu

2017-08-15

Resonant ultrasound spectroscopy (RUS) was used to determine the temperature dependence of full matrix material constants of PZT-8 piezoceramics from room temperature to 100 °C. Property variations from sample to samples can be eliminated by using only one sample, so that data self-consistency can be guaranteed. The RUS measurement system error was estimated to be lower than 2.35%. The obtained full matrix material constants at different temperatures all have excellent self-consistency, which can help accurately predict device performance at high temperatures using finite element simulations.

Temperature-dependent inotropic and lusitropic indices based on half-logistic time constants for four segmental phases in isovolumic left ventricular pressure-time curve in excised, cross-circulated canine heart.

PubMed

Mizuno, Ju; Mohri, Satoshi; Yokoyama, Takeshi; Otsuji, Mikiya; Arita, Hideko; Hanaoka, Kazuo

2017-02-01

Varying temperature affects cardiac systolic and diastolic function and the left ventricular (LV) pressure-time curve (PTC) waveform that includes information about LV inotropism and lusitropism. Our proposed half-logistic (h-L) time constants obtained by fitting using h-L functions for four segmental phases (Phases I-IV) in the isovolumic LV PTC are more useful indices for estimating LV inotropism and lusitropism during contraction and relaxation periods than the mono-exponential (m-E) time constants at normal temperature. In this study, we investigated whether the superiority of the goodness of h-L fits remained even at hypothermia and hyperthermia. Phases I-IV in the isovolumic LV PTCs in eight excised, cross-circulated canine hearts at 33, 36, and 38 °C were analyzed using h-L and m-E functions and the least-squares method. The h-L and m-E time constants for Phases I-IV significantly shortened with increasing temperature. Curve fitting using h-L functions was significantly better than that using m-E functions for Phases I-IV at all temperatures. Therefore, the superiority of the goodness of h-L fit vs. m-E fit remained at all temperatures. As LV inotropic and lusitropic indices, temperature-dependent h-L time constants could be more useful than m-E time constants for Phases I-IV.

Finite-Temperature Behavior of PdH x Elastic Constants Computed by Direct Molecular Dynamics

DOE PAGES

Zhou, X. W.; Heo, T. W.; Wood, B. C.; ...

2017-05-30

In this paper, robust time-averaged molecular dynamics has been developed to calculate finite-temperature elastic constants of a single crystal. We find that when the averaging time exceeds a certain threshold, the statistical errors in the calculated elastic constants become very small. We applied this method to compare the elastic constants of Pd and PdH 0.6 at representative low (10 K) and high (500 K) temperatures. The values predicted for Pd match reasonably well with ultrasonic experimental data at both temperatures. In contrast, the predicted elastic constants for PdH 0.6 only match well with ultrasonic data at 10 K; whereas, atmore » 500 K, the predicted values are significantly lower. We hypothesize that at 500 K, the facile hydrogen diffusion in PdH 0.6 alters the speed of sound, resulting in significantly reduced values of predicted elastic constants as compared to the ultrasonic experimental data. Finally, literature mechanical testing experiments seem to support this hypothesis.« less

Shock tube measurements of growth constants in the branched-chain ethane-carbon monoxide-oxygen system

NASA Technical Reports Server (NTRS)

Brokaw, R. S.; Brabbs, T. A.; Snyder, C. A.

1985-01-01

Exponential free radical growth constants have been measured for ethane carbon monoxide oxygen mixtures by monitoring the growth of oxygen atom concentration as manifested by CO flame band emission. Data were obtained over the temperature range of 1200 to 1700 K. The data were analyzed using an ethane oxidation mechanism involving seven elementary reaction steps. Calculated growth constants were close to experimental values at lower temperatures, up to about 1400 K, but at higher temperatures computed growth constants were considerably smaller than experiment. In attempts to explain these results additional branching reactions were added to the mechanism. However, these additional reactions did not appreciably change calculated growth constants.

How two types of fluctuating temperature affect the growth of Fusarium solani

Treesearch

Keith F. Jensen; Phillip E. Reynolds

1969-01-01

Growth of six isolates of Fusarium solani on potato dextrose agar was determined with (1) continually changing temperature programs, (2) programs consisting of two alternating constant temperatures, and (3) a constant temperature program. All programs had a mean of 70º F. Growth increased with an increase in temperature fluctuation of 10 or...

Investigation of the I-40 Jet-Propulsion Engine in the Cleveland Altitude Wind Tunnel. V - Operational Characteristics. 5; Operational Characteristics

NASA Technical Reports Server (NTRS)

Golladay, Richard L.; Gendler, Stanley L.

1947-01-01

An investigation has been conducted in the Cleveland altitude wind tunnel to determine the operational characteristics of the I-40 jet-propulsion engine over a range of pressure altitudes from 10,000 to 50,000 feet and ram-pressure ratios from 1.00 to 1.76. Engine operational data were obtained with the engine in the standard configuration and with various modifications of the fuel system, the electrical system, and the combustion chambers. The effects of altitude and airspeed on operating speed range, starting, windmilli.ng, acceleration, speed regulation, cooling, and vibration of the standard and modified engines were determined, and damage to parts was noted. Maximum engine speed was obtainable at all altitudes and airspeeds wi th each fuel-control system investigated. The minimum idling speed was raised by increases in altitude and airspeed. The lowest minimum stable speeds were obtained with the standard configuration using 40-gallon nozzles with individual metering plugs. The engine was started normally at altitudes as high as 20,000 feet with all of the fuel systems and ignition combinations except one. Ignition at 70,000 feet was difficult and, although successful ignition occurred, acceleration was slow and usually characterized by excessive tail-pipe temperature. During windmilling investigations of the engine equipped with the standard fuel system, the engine could not be started at ram-pressure ratios of 1.1 to 1.7 at altitudes of 10,000, 20,000 and 30,000 feet. When equipped with the production barometric and Monarch 40-gallon nozzles, the engine accelerated in 12 seconds from an engine speed of 6000 rpm to 11,000 rpm at 20,000 feet and an average tail-pipe temperature of 11000 F. At the same altitude and temperature, all the engine configurations had approximately the same rate of acceleration. The Woodward governor produced the safest accelerations, inasmuch as it could be adjusted to automatically prevent acceleration blow out. The engine speed was held constant by the Woodward governor and the Edwards regulator during simulated dives and climbs at constant throttle position. The bearing cooling system was satisfactory at all altitudes and airspeeds. The engines operated without serious failure, although the exhaust cone, the tail pipe, and the airplane fuselage were damaged during altitude starts.

On the Henry constant and isosteric heat at zero loading in gas phase adsorption.

PubMed

Do, D D; Nicholson, D; Do, H D

2008-08-01

The Henry constant and the isosteric heat of adsorption at zero loading are commonly used as indicators of the strength of the affinity of an adsorbate for a solid adsorbent. It is assumed that (i) they are observable in practice, (ii) the Van Hoff's plot of the logarithm of the Henry constant versus the inverse of temperature is always linear and the slope is equal to the heat of adsorption, and (iii) the isosteric heat of adsorption at zero loading is either constant or weakly dependent on temperature. We show in this paper that none of these three points is necessarily correct, first because these variables might not be observable since they are outside the range of measurability; second that the linearity of the Van Hoff plot breaks down at very high temperature, and third that the isosteric heat versus loading is a strong function of temperature. We demonstrate these points using Monte Carlo integration and Monte Carlo simulation of adsorption of various gases on a graphite surface. Another issue concerning the Henry constant is related to the way the adsorption excess is defined. The most commonly used equation is the one that assumes that the void volume is the volume extended all the way to a boundary passing through the centres of the outermost solid atoms. With this definition the Henry constant can become negative at high temperatures. Although adsorption at these temperatures may not be practical because of the very low value of the Henry constant, it is more useful to define the Henry constant in such a way that it is always positive at all temperatures. Here we propose the use of the accessible volume; the volume probed by the adsorbate when it is in nonpositive regions of the potential, to calculate the Henry constant.

Comparison between variable and constant rotor speed operation on WINDMEL-II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sasamoto, Akira; Matsumiya, Hikaru; Kawamura, Shunji

1996-10-01

On a wind turbine control system for rotor revolution speed, it is believed that variable speed operation has the advantages over constant speed from a view point of both aerodynamics and mechanics. However, there is no experimental study which shows the differences. In this report, the authors intend to clarify the differences about shaft torque by using experimental data, from a new wind turbine system which has both variable and constant operation. The result in observation of the experimental data shows that variable speed operational shaft torque is lower than constant speed operational one.

Performance and component frontal areas of a hypothetical two-spool turbojet engine for three modes of operation

NASA Technical Reports Server (NTRS)

Dugan, James F , Jr

1955-01-01

Engine performance is better for constant outer-spool mechanical-speed operation than for constant inner-spool mechanical-speed operation over most of the flight range considered. Combustor and afterburner frontal areas are about the same for the two modes. Engine performance for a mode characterized by a constant outer-spool equivalent speed over part of the flight range and a constant outer-spool mechanical speed over the rest of the flight range is better that that for constant outer-spool mechanical speed operation. The former mode requires larger outer-spool centrifugal stresses and larger component frontal areas.

Restrictions on linear heat capacities from Joule-Brayton maximum-work cycle efficiency

NASA Astrophysics Data System (ADS)

Angulo-Brown, F.; Gonzalez-Ayala, Julian; Arias-Hernandez, L. A.

2014-02-01

This paper discusses the possibility of using the Joule-Brayton cycle to determine the accessible value range for the coefficients a and b of the heat capacity at constant pressure Cp, expressed as Cp=a+bT (with T the absolute temperature) by using the Carnot theorem. This is made for several gases which operate as the working fluids. Moreover, the landmark role of the Curzon-Ahlborn efficiency for this type of cycle is established.

Gravity Scaling of a Power Reactor Water Shield

NASA Technical Reports Server (NTRS)

Reid, Robert S.; Pearson, J. Boise

2007-01-01

A similarity analysis on a water-based reactor shield examined the effect of gravity on free convection between a reactor shield inner and outer vessel boundaries. Two approaches established similarity between operation on the Earth and the Moon: 1) direct scaling of Rayleigh number equating gravity-surface heat flux products, 2) temperature difference between the wall and thermal boundary layer held constant. Nusselt number for natural convection (laminar and turbulent) is assumed of form Nu = CRa(sup n).

Stage Effects on Stalling and Recovery of a High-Speed 10-Stage Axial- Flow Compressor

DTIC Science & Technology

1990-06-01

facility C Specific heat of air at constant pressureP Cx Axial velocity DC Direct current DAC Data acquisition computer DCS Design corrected compressor ...was designed to inve3tigate the component performance of an axial -flow compressor while stalling and operating in rotating stall. No attempt was made...Temperatures were measured from a probe configuration similar to the to - pressure design . 68 Table 4.2 Compressor instrumentation RADIAL PROPERTY AXIAL

Low pressure arc discharge lamp apparatus with magnetic field generating means

DOEpatents

Grossman, Mark W.; George, William A.; Maya, Jakob

1987-01-01

A low-pressure arc discharge apparatus having a magnetic field generating means for increasing the output of a discharge lamp is disclosed. The magnetic field generating means, which in one embodiment includes a plurality of permanent magnets, is disposed along the lamp for applying a constant transverse magnetic field over at least a portion of the positive discharge column produced in the arc discharge lamp operating at an ambient temperature greater than about 25.degree. C.

A simple molecular mechanics integrator in mixed rigid body and dihedral angle space

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vitalis, Andreas, E-mail: a.vitalis@bioc.uzh.ch; Pappu, Rohit V.

2014-07-21

We propose a numerical scheme to integrate equations of motion in a mixed space of rigid-body and dihedral angle coordinates. The focus of the presentation is biomolecular systems and the framework is applicable to polymers with tree-like topology. By approximating the effective mass matrix as diagonal and lumping all bias torques into the time dependencies of the diagonal elements, we take advantage of the formal decoupling of individual equations of motion. We impose energy conservation independently for every degree of freedom and this is used to derive a numerical integration scheme. The cost of all auxiliary operations is linear inmore » the number of atoms. By coupling the scheme to one of two popular thermostats, we extend the method to sample constant temperature ensembles. We demonstrate that the integrator of choice yields satisfactory stability and is free of mass-metric tensor artifacts, which is expected by construction of the algorithm. Two fundamentally different systems, viz., liquid water and an α-helical peptide in a continuum solvent are used to establish the applicability of our method to a wide range of problems. The resultant constant temperature ensembles are shown to be thermodynamically accurate. The latter relies on detailed, quantitative comparisons to data from reference sampling schemes operating on exactly the same sets of degrees of freedom.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dentz, Jordan; Ansanelli, Eric; Henderson, Hugh

Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperaturemore » modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7% after implementing the demand control technique, 2% after implementing temperature modulation, and 15% after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8%, 1%, and 14% for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.« less

The p- T phase diagram of KNbO 3 by a dielectric constant measurement

NASA Astrophysics Data System (ADS)

Kobayashi, Y.; Endo, S.; Deguchi, K.; Ming, L. C.; Zou, G.

2001-11-01

A dielectric constant measurement was carried out on perovskite-type ferroelectrics KNbO 3 over a wide range of temperature under high pressure. The temperature- and pressure-dependence of the dielectric constant clarified that all temperatures of the transitions from the ferroelectric rhombohedral to orthorhombic, to tetragonal and then to the paraelectric cubic phase, decrease with increasing pressure. These results indicate that the orthorhombic-tetragonal transition takes place at 8.5 GPa and the tetragonal-cubic transition at 11 GPa, at room temperature.

Carbon Nanotube Bolometer for Absolute FTIR Spectroscopy

NASA Astrophysics Data System (ADS)

Woods, Solomon; Neira, Jorge; Tomlin, Nathan; Lehman, John

We have developed and calibrated planar electrical-substitution bolometers which employ absorbers made from vertically-aligned carbon nanotube arrays. The nearly complete absorption of light by the carbon nanotubes from the visible range to the far-infrared can be exploited to enable a device with read-out in native units equivalent to optical power. Operated at cryogenic temperatures near 4 K, these infrared detectors are designed to have time constant near 10 ms and a noise floor of about 10 pW. Built upon a micro-machined silicon platform, each device has an integrated heater and thermometer, either a carbon nanotube thermistor or superconducting transition edge sensor, for temperature control. We are optimizing temperature-controlled measurement techniques to enable high resolution spectral calibrations using these devices with a Fourier-transform spectrometer.

Tensile properties of AZ11A-0 magnesium-alloy sheet under rapid-heating and constant temperature

NASA Technical Reports Server (NTRS)

Kurg, Ivo M

1956-01-01

Specimens of AZ31A-0 magnesium alloy sheet were heated to rupture at nominal rates of 0.2 F to 100 F per second under constant tensile load conditions. The data are presented and compared with the results of conventional tensile stress-strain tests at elevated temperatures after 1.2-hour exposure. A temperature-rate parameter was used to construct master curves from which stresses and temperatures for yield and rupture can be predicted under rapid-heating conditions. A comparison of the elevated-temperature tensile properties of AZ31A-0 and HK31XA-H24 magnesium-alloy sheet under both constant-temperature and rapid-heating conditions is included.

Thermal vacuum real-life test of an Marconi Space and Defence Systems (MSDS) solar-array drive mechanism (MSDS 002). First four years of operation

NASA Astrophysics Data System (ADS)

Parker, K.; Douglas, A.; Burke, W. R.

1981-01-01

The first part of a 7 yr life test on a mechanism which turns a satellite solar array at 1rev/day is reported. A thermal transfer shroud, surrounding the mechanism in a vacuum chamber, is held at a constant temperature of 22.5 C while the shaft temperature, measured near the top of the shaft at the large bearing, is changed at 6-monthly intervals so that it operates alternately at 60 and 10 C. At the beginning of each 6-monthly cycle, 30 eclipse simulations are performed, i.e., the shaft temperature is reduced from 60 C to 0 C in 72 min and is returned to 60 C in as short a time as possible. Apart from a very small increase in motor power during eclipse simulation, no changes in the mechanism parameters occur with temperature. The mechanism operates within motor power and angular rotation accuracy specifications. The electrical noise on all slip rings increased during the first two years, but then slowly decreased. Certain slip ring pairs show a noise level in excess of the arbitrary limits set at the start of the test, and two slip ring pairs give large periodic noise transients which may be due to mechanical damage to the slip rings or brushes.

Understanding post-operative temperature drop in cardiac surgery: a mathematical model.

PubMed

Tindall, M J; Peletier, M A; Severens, N M W; Veldman, D J; de Mol, B A J M

2008-12-01

A mathematical model is presented to understand heat transfer processes during the cooling and re-warming of patients during cardiac surgery. Our compartmental model is able to account for many of the qualitative features observed in the cooling of various regions of the body including the central core containing the majority of organs, the rectal region containing the intestines and the outer peripheral region of skin and muscle. In particular, we focus on the issue of afterdrop: a drop in core temperature following patient re-warming, which can lead to serious post-operative complications. Model results for a typical cooling and re-warming procedure during surgery are in qualitative agreement with experimental data in producing the afterdrop effect and the observed dynamical variation in temperature between the core, rectal and peripheral regions. The influence of heat transfer processes and the volume of each compartmental region on the afterdrop effect is discussed. We find that excess fat on the peripheral and rectal regions leads to an increase in the afterdrop effect. Our model predicts that, by allowing constant re-warming after the core temperature has been raised, the afterdrop effect will be reduced.

[Effect of temperature on performance of microbial fuel cell using beer wastewater].

PubMed

Wang, Xin; Feng, Yu-Jie; Qu, You-Peng; Li, Dong-Mei; Li, He; Ren, Nan-Qi

2008-11-01

The effects of temperature on performance and biological community structure were investigated in air-cathode microbial fuel cells (MFCs) using beer wastewater amended with 50 mmol/L phosphate buffer solution (PBS). The maximum power density decreased from 483 mW/m2 to 435 mW/m2 when the temperature varied from 30 degrees C to 20 degrees C, meanwhile just a little decreasing on coulombic efficiency and the COD removal rate were observed. Decreasing of temperature resulted in effects both on cathode potential and anode potential, but cathode potential behaved much more sensitive to temperature. The half-saturation constants (Ks) obtained from the fit of Monod-type equation were 228 mg/L (30 degrees C) and 293 mg/L (20 degrees C) respectively. Denaturing gradient gel electrophoresis (DGGE) analysis indicated that operating temperature not only affected the predominant population of the anodic bacterial community, but also had a great impact on the diversity of the cathodic microbial population.

Ram-Jet off Design Performances

NASA Astrophysics Data System (ADS)

Andriani, Roberto; Ghezzi, Umberto

2002-01-01

In this work it is intended to study the off-design performances of a ram jet engine. To this purpouse it has been analyzed in a first time the behaviour of an ideal engine, that means to not consider the losses in the various components, or, under a thermodynamic point of view, to consider the fluid transformation through the air intake and exhaust nozzle, remembering that in a ram jet there are not rotating components as compressor and turbine, isentropic. Referring to the ram-jet scheme of fig.1. we can say, neglecting the fuel introduced, that the air mass flow rate throughout the engine is constant. If we consider the two control sections 4 and 8, respectively the throat section of the converging-diverging supersonic inlet and the throat section of the discharge nozzle, the condition of constant mass flow leads to the relation: m4 =f (M 4 ) m8 = m 4 = m8 We can imaging that the throat section # 4 is always choked for any value of the flight Mach number M0. This means that the throat section 4 is adjusted at any value of M0 so that the flow Mach number in 4 is equal to unity. In this it follows: R. Andriani, U. Ghezzi1 Since in an ideal case T t8 The relation [1] allows to determine the T8 temperature, that represent the maximum cycle temperature, for different operating conditions, as flight Mach number and altitude. We then have two cases: the first is A8 (nozzle throat section) fixed, and the second is A8 variable. In the first case the maximum temperature T8 is univocally determined by the operating condition. In the second case A8 can be varied so to maintain T8 at a chosen value. The graphic of fig.2 shows the first case. In particular it has been considered as design point an altitude of 15000 meters and a flight Mach number equal to 2. In this condition it has been evaluated the section A8 for unity mass flow rate. At the same altitude, varying the flight Mach number, with the section A4 always choked, the graphic shows the variation of the maximum cycle temperature according to the equation *. We notice as the temperature raises to unacceptable levels as we accelerate from the design point. For instance we can see as if we move to flight Mach number 2.2 the maximum temperature raises from 1800 Kelvin degrees (design point) to more than 2900 [K], a value practically unreachable. This shows as the ramjet with fixed discharge nozzle allows very little variation of the operating conditions around the design point. If we consider instead the possibility to vary the nozzle section A8 we can imagine to adjust it so to maintain constant the temperature T8, according to the relation *. The graphics of fig.3 show the area variation required to the section A8 to maintain constant the temperature T8 at the same altitude for different values of the flight Mach number. Considering a circular section, on the same R. Andriani, U. Ghezzi2 picture is reported the corresponding variation of the diameter. On the Y-axis it is reported the ratio between the entity (section and diameter) at the considered condition and at the design point. For the case of A8 section variable it has also been evaluated the behavior of the specific fuel consumption, the mass flow rate and the thrust. In fig.4 they are reported the behavior TSFC and Fuel/air ratio at different flight Mach numbers, and the ratio between them and the design value. In fig .5 it is reported the ratio between the thrust and mass flow rate at different flight conditions and their value at design point. R. Andriani, U. Ghezzi3

Determination of model parameters for zinc (II) ion biosorption onto powdered waste sludge (PWS) in a fed-batch system.

PubMed

Kargi, Fikret; Cikla, Sinem

2007-12-01

Biosorption of zinc (II) ions onto pre-treated powdered waste sludge (PWS) was investigated using a completely mixed tank operating in fed-batch mode instead of an adsorption column. Experiments with variable feed flow rate (0.05-0.5 L h(-1)), feed Zn(II) ion concentrations (37.5-275 mg L(-1)) and amount of adsorbent (1-6 g PWS) were performed using fed-batch operation at pH 5 and room temperature (20-25 degrees C). Break-through curves describing variations of aqueous (effluent) zinc ion concentrations with time were determined for different operating conditions. Percent zinc removal from the aqueous phase decreased, but the biosorbed (solid phase) zinc ion concentration increased with increasing feed flow rate and zinc concentration. A modified Bohart-Adams equation was used to determine the biosorption capacity of PWS (q'(s)) and the rate constant (K) for zinc ion biosorption. Biosorption capacity (q'(s)=57.7 g Zn kg(-1) PWS) of PWS in fed-batch operation was found to be comparable with powdered activated carbon (PAC) in column operations. However, the adsorption rate constant (K=9.17 m(3) kg(-1) h(-1)) in fed-batch operation was an order of magnitude larger than those obtained in adsorption columns because of elimination of mass transfer limitations encountered in the column operations. Therefore, a completely mixed tank operated in fed-batch mode was proven to be more advantageous as compared to adsorption columns due to better contact between the phases yielding faster adsorption rates.

Human local and total heat losses in different temperature.

PubMed

Wang, Lijuan; Yin, Hui; Di, Yuhui; Liu, Yanfeng; Liu, Jiaping

2016-04-01

This study investigates the effects of operative temperature on the local and total heat losses, and the relationship between the heat loss and thermal sensation. 10 local parts of head, neck, chest, abdomen, upper arm, forearm, hand, thigh, leg and foot are selected. In all these parts, convection, radiation, evaporation, respiration, conduction and diffusion heat losses are analyzed when operative temperature is 23, 28, 33 and 37 °C. The local heat losses show that the radiation and convection heat losses are mainly affected by the area of local body, and the heat loss of the thigh is the most in the ten parts. The evaporation heat loss is mainly affected by the distribution of sweat gland, and the heat loss of the chest is the most. The total heat loss of the local body shows that in low temperature, the thigh, leg and chest have much heat loss, while in high temperature, the chest, abdomen, thigh and head have great heat loss, which are useful for clothing design. The heat losses of the whole body show that as the operative temperature increases, the radiation and convection heat losses decrease, the heat losses of conduction, respiration, and diffusion are almost constant, and the evaporation heat loss increases. By comparison, the heat loss ratios of the radiation, convection and sweat evaporation, are in agreement with the previous researches. At last, the formula about the heat loss ratio of convection and radiation is derived. It's useful for thermal comfort evaluation and HVAC (heating, ventilation and air conditioning) design. Copyright © 2016 Elsevier Inc. All rights reserved.

Rate Constant and Temperature Dependence for the Reaction of Hydroxyl Radicals with 2-Flouropropane (FC-281ea) and Comparison with an Estimated Rate Constant

NASA Technical Reports Server (NTRS)

DeMore, W.; Wilson, E., Jr.

1998-01-01

Relative rate experiments were used to measure the rate constant and temperature dependence of the reaction of OH radicals with 2-fluoropropane (HFC-281ea), using ethane, propane, ethyl chloride as reference standards.

Fundamental considerations in the effect of molecular weight on the glass transition of the gelatin/cosolute system.

PubMed

Jiang, Bin; Kasapis, Stefan; Kontogiorgos, Vassilis

2012-05-01

Four molecular fractions of gelatin produced by alkaline hydrolysis of collagen were investigated in the presence of cosolute to record the mechanical properties of the glass transition in high-solid preparations. Dynamic oscillatory and stress relaxation moduli in shear were recorded from 40°C to temperatures as low as -60°C. The small-deformation behavior of these linear polymers was separated by the method of reduced variables into a basic function of time alone and a basic function of temperature alone. The former allowed the reduction of isothermal runs into a master curve covering 17 orders of magnitude in the time domain. The latter follows the passage from the rubbery plateau through the glass transition region to the glassy state seen in the variation of shift factor, a(T) , as a function of temperature. The mechanical glass transition temperature (T(g) ) is pinpointed at the operational threshold of the free volume theory and the predictions of the reaction rate theory. Additional insights into molecular dynamics are obtained via the coupling model of cooperativity, which introduces the concept of coupling constant or interaction strength of local segmental motions that govern structural relaxation at the vicinity of T(g) . The molecular weight of the four gelatin fractions appears to have a profound effect on the transition temperature or coupling constant of vitrified matrices, as does the protein chemistry in relation to that of amorphous synthetic polymers or gelling polysaccharides. © 2011 Wiley Periodicals, Inc.

Results and analysis of the hot-spot temperature experiment for a cable-in-conduit conductor with thick conduit

NASA Astrophysics Data System (ADS)

Sedlak, Kamil; Bruzzone, Pierluigi

2015-12-01

In the design of future DEMO fusion reactor a long time constant (∼23 s) is required for an emergency current dump in the toroidal field (TF) coils, e.g. in case of a quench detection. This requirement is driven mainly by imposing a limit on forces on mechanical structures, namely on the vacuum vessel. As a consequence, the superconducting cable-in-conduit conductors (CICC) of the TF coil have to withstand heat dissipation lasting tens of seconds at the section where the quench started. During that time, the heat will be partially absorbed by the (massive) steel conduit and electrical insulation, thus reducing the hot-spot temperature estimated strictly from the enthalpy of the strand bundle. A dedicated experiment has been set up at CRPP to investigate the radial heat propagation and the hot-spot temperature in a CICC with a 10 mm thick steel conduit and a 2 mm thick glass epoxy outer electrical insulation. The medium size, ∅ = 18 mm, NbTi CICC was powered by the operating current of up to 10 kA. The temperature profile was monitored by 10 temperature sensors. The current dump conditions, namely the decay time constant and the quench detection delay, were varied. The experimental results show that the thick conduit significantly contributes to the overall enthalpy balance, and consequently reduces the amount of copper required for the quench protection in superconducting cables for fusion reactors.

Degeneracy and neuromodulation among thermosensory neurons contribute to robust thermosensory behaviors in C. elegans

PubMed Central

Beverly, Matthew; Anbil, Sriram; Sengupta, Piali

2011-01-01

Animals must ensure that they can execute behaviors important for physiological homeostasis under constantly changing environmental conditions. The neural mechanisms that regulate this behavioral robustness are not well understood. The nematode C. elegans thermoregulates primarily via modulation of navigation behavior. Upon encountering temperatures higher than its cultivation temperature (Tc), C. elegans exhibits negative thermotaxis towards colder temperatures using a biased random walk strategy. We find that C. elegans exhibits robust negative thermotaxis bias under conditions of varying Tc and temperature ranges. By cell ablation and cell-specific rescue experiments, we show that the ASI chemosensory neurons are newly identified components of the thermosensory circuit, and that different combinations of ASI and the previously identified AFD and AWC thermosensory neurons are necessary and sufficient under different conditions to execute a negative thermotaxis strategy. ASI responds to temperature stimuli within a defined operating range defined by Tc, and signaling from AFD regulates the bounds of this operating range, suggesting that neuromodulation among thermosensory neurons maintains coherence of behavioral output. Our observations demonstrate that a negative thermotaxis navigational strategy can be generated via different combinations of thermosensory neurons acting degenerately, and emphasize the importance of defining context when analyzing neuronal contributions to a behavior. PMID:21832201

Combined Effects of Temperature and Irradiation on Concrete Damage

DOE PAGES

Le Pape, Yann; Giorla, Alain; Sanahuja, Julien

2016-01-01

Aggregate radiation-induced volumetric expansion (RIVE) is a predominant mechanism in the formation of mechanical damage in the hardened cement paste (hcp) of irradiated concrete under fast-neutron flux (Giorla et al. 2015). Among the operating conditions difference between test reactors and light water reactors (LWRs), the difference of irradiation flux and temperature is significant. While a temperature increase is quite generally associated with a direct, or indirect (e.g., by dehydration) loss of mechanical properties (Maruyama et al. 2014), we found that it causes a partial annealing of irradiation amorphization of α-quartz, hence, reducing RIVE rate. Based on data collected by Bykovmore » et al. (1981), an incremental RIVE model coupling neutron fluence and temperature is developed. The elastic properties and coefficient of thermal expansion (CTE) of irradiated polycrystalline quartz are interpreted through analytical homogenization of experimental data on irradiated α-quartz published by Mayer and Lecomte (1960). Moreover, the proposed model, implemented in the meso-scale simulation code AMIE, is compared to experimental data obtained on ordinary concrete made of quartz/quartzite aggregate (Dubrovskii et al. 1967). Substantial discrepancy, in terms of damage and volumetric expansion developments, is found when comparing irradiation scenarios assuming constant flux and temperature, as opposed to more realistic test reactor operation conditions.« less

A fully integrated oven controlled microelectromechanical oscillator -- Part I. Design and fabrication

DOE PAGES

Wojciechowski, Kenneth E.; Baker, Michael S.; Clews, Peggy J.; ...

2015-06-24

Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift and electronic properties (Q, resistance) of both the resonant tank circuit and feedback electronics required to form an electronic oscillator. An OCMO is presented that takes advantage of high thermal isolation and monolithic integration of both micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. This was achieved by developing a processing technique where both silicon-on-insulator complementary metal-oxide-semiconductor (CMOS) circuitrymore » and piezoelectric aluminum nitride, AlN, micromechanical resonators are placed on a suspended platform within a standard CMOS integrated circuit. Operation at microscale sizes achieves high thermal resistances (~10 °C/mW), and hence thermal stabilization of the oscillators at very low-power levels when compared with the state-of-the-art ovenized crystal oscillators, OCXO. This constant resistance feedback circuit is presented that incorporates on platform resistive heaters and temperature sensors to both measure and stabilize the platform temperature. Moreover, the limits on temperature stability of the OCMO platform and oscillator frequency imposed by the gain of the constant resistance feedback loop, placement of the heater and temperature sensing resistors, as well as platform radiative and convective heat losses are investigated.« less

Non-trivial behavior of the low temperature maximum of dielectric constant and location of the end critical point in Na0.5Bi0.5TiO3-0.06BaTiO3 lead free relaxor ferroelectrics crystals detected by acoustic emission

NASA Astrophysics Data System (ADS)

Dul'kin, Evgeniy; Tiagunova, Jenia; Mojaev, Evgeny; Roth, Michael

2018-01-01

[001] lead free relaxor ferroelectrics crystals of Na0.5Bi0.5TiO3-0.06BaTiO3 were studied by means of dielectric and acoustic emission methods in the temperature range of 25-240 °C and under a dc bias electric field up to 0.4 kV/cm. A temperature maximum of the dielectric constant was found near 170 °C, as well as the acoustic emission bursts pointed out to both the depolarization temperature near 120 °C and the temperature, corresponding to the maximum of dielectric constant, near 170 °C. While the depolarization temperature increased linearly, the temperature of the dielectric constant maximum was shown to exhibit a V-shape behavior under an electric field: it initially decreases, reaches a sharp minimum at some small threshold electric field of 0.15 kV/cm, and then starts to increase similar to the Curie temperature of the normal ferroelectrics, as the field enhances. Acoustic emission bursts, accompanying the depolarization temperature, weakened with the enhancing field, whereas the ones accompanying the temperature of the dielectric constant maximum exhibited two maxima: near 0.1 kV/cm and near 0.3 kV/cm. The meaning of these two acoustic emission maxima is discussed.

Shock tube measurements of growth constants in the branched chain formaldehyde-carbon monoxide-oxygen system

NASA Technical Reports Server (NTRS)

Brabbs, T. A.; Brokaw, R. S.

1982-01-01

Exponential free radical growth constants were measured for formaldehyde carbon monoxide-oxygen systems by monitoring the growth of oxygen atom concentration as manifested by CO flame band emission. Data were obtained over the temperature range of 1200 to 2000 K. The data were analyzed using a formaldehyde oxidation mechanism involving 12 elementary reaction steps. The computed growth constants are roughly in accord with experimental values, but are much more temperature dependent. The data was also analyzed assuming formaldehyde is rapidly decomposed to carbon monoxide and hydrogen. Growth constants computed for the resulting carbon monoxide hydrogen oxygen mixtures have a temperature dependence similar to experiments; however, for most mixtures, the computed growth constants were larger than experimental values.

Liquid cooled plate heat exchanger for battery cooling of an electric vehicle (EV)

NASA Astrophysics Data System (ADS)

Rahman, M. M.; Rahman, H. Y.; Mahlia, T. M. I.; Sheng, J. L. Y.

2016-03-01

A liquid cooled plate heat exchanger was designed to improve the battery life of an electric vehicle which suffers from premature aging or degradation due to the heat generation during discharging and charging period. Computational fluid dynamics (CFD) was used as a tool to analyse the temperature distribution when a constant surface heat flux was set at the bottom surface of the battery. Several initial and boundary conditions were set based on the past studies on the plate heat exchanger in the simulation software. The design of the plate heat exchanger was based on the Nissan Leaf battery pack to analyse the temperature patterns. Water at different mass flow rates was used as heat transfer fluid. The analysis revealed the designed plate heat exchanger could maintain the surface temperature within the range of 20 to 40°C which is within the safe operating temperature of the battery.

Experiments with a pressure-driven Stirling refrigerator with flexible chambers

NASA Astrophysics Data System (ADS)

McFarlane, Patrick; Suire, Jonathan; Sen, Mihir; Semperlotti, Fabio

2014-06-01

We report on the design and experimental testing of a Stirling refrigerator that uses air as the working fluid, and where the conventional piston-cylinder assemblies are replaced by pressure-driven flexible chambers. The two chambers are periodically compressed by pneumatic actuators resulting in airflow through the regenerator and in a net temperature difference between the chambers. An experimental setup is used to investigate the performance of the refrigerator under different operating conditions with particular attention to actuation frequencies, driving pressure differences, and phase angles between the two inputs. The time constant of the temperature difference between the two chambers is determined, and the temperature difference is measured as a function of the system parameters. The results of several tests conducted under different operating conditions show that the refrigerating effect is very robust and allows good performance even for modulated inputs. The frequency response is radically different from that of a traditional motion-driven device. This work suggests that mechanical to thermal energy conversion devices based on this principle can be successfully powered by human motion.

Dynamic Performance of Maximum Power Point Trackers in TEG Systems Under Rapidly Changing Temperature Conditions

NASA Astrophysics Data System (ADS)

Man, E. A.; Sera, D.; Mathe, L.; Schaltz, E.; Rosendahl, L.

2016-03-01

Characterization of thermoelectric generators (TEG) is widely discussed and equipment has been built that can perform such analysis. One method is often used to perform such characterization: constant temperature with variable thermal power input. Maximum power point tracking (MPPT) methods for TEG systems are mostly tested under steady-state conditions for different constant input temperatures. However, for most TEG applications, the input temperature gradient changes, exposing the MPPT to variable tracking conditions. An example is the exhaust pipe on hybrid vehicles, for which, because of the intermittent operation of the internal combustion engine, the TEG and its MPPT controller are exposed to a cyclic temperature profile. Furthermore, there are no guidelines on how fast the MPPT must be under such dynamic conditions. In the work discussed in this paper, temperature gradients for TEG integrated in several applications were evaluated; the results showed temperature variation up to 5°C/s for TEG systems. Electrical characterization of a calcium-manganese oxide TEG was performed at steady-state for different input temperatures and a maximum temperature of 401°C. By using electrical data from characterization of the oxide module, a solar array simulator was emulated to perform as a TEG. A trapezoidal temperature profile with different gradients was used on the TEG simulator to evaluate the dynamic MPPT efficiency. It is known that the perturb and observe (P&O) algorithm may have difficulty accurately tracking under rapidly changing conditions. To solve this problem, a compromise must be found between the magnitude of the increment and the sampling frequency of the control algorithm. The standard P&O performance was evaluated experimentally by using different temperature gradients for different MPPT sampling frequencies, and efficiency values are provided for all cases. The results showed that a tracking speed of 2.5 Hz can be successfully implemented on a TEG system to provide ˜95% MPPT efficiency when the input temperature is changing at 5°C/s.

YBCO High-Temperature Superconducting Filters on M-Plane Sapphire Substrates

NASA Technical Reports Server (NTRS)

Sabataitis, J. C.; Mueller, C. H.; Miranda, F. A.; Warner, J.; Bhasin, K. B.

1996-01-01

Since the discovery of High Temperature Superconductors (HTS) in 1986, microwave circuits have been demonstrated using HTS films on various substrates. These HTS-based circuits have proven to operate with less power loss than their metallic film counterparts at 77 K. This translates into smaller and lighter microwave circuits for space communication systems such as multiplexer filter banks. High quality HTS films have conventionally been deposited on lanthanum aluminate (LaAlO3) substrates. However, LaAlO3 has a relative dielectric constant (epsilon(sub r)) of 24. With a epsilon(sub r) approx. 9.4-11.6, sapphire (Al2O3) would be a preferable substrate for the fabrication of HTS-based components since the lower dielectric constant would permit wider microstrip lines to be used in filter design, since the lower dielectric constant would permit wider microstrip lines to be used for a given characteristic impedance (Z(sub 0)), thus lowering the insertion losses and increasing the power handling capabilities of the devices. We report on the fabrication and characterization of YBa2Cu3O(7-delta) (YBCO) on M-plane sapphire bandpass filters at 4.0 GHz. For a YBCO 'hairpin' filter, a minimum insertion loss of 0.5 dB was measured at 77 K as compared with 1.4 dB for its gold counterpart. In an 'edge-coupled' configuration, the insertion loss went down from 0.9 dB for the gold film to 0.8 dB for the YBCO film at the same temperature.

Investigation of dynamic characteristics of a turbine-propeller engine

NASA Technical Reports Server (NTRS)

Oppenheimer, Frank L; Jacques, James R

1951-01-01

Time constants that characterize engine speed response of a turbine-propeller engine over the cruising speed range for various values of constant fuel flow and constant blade angle were obtained both from steady-state characteristics and from transient operation. Magnitude of speed response to changes in fuel flow and blade angle was investigated and is presented in the form of gain factors. Results indicate that at any given value of speed in the engine cruising speed range, time constants obtained both from steady-state characteristics and from transient operation agree satisfactorily for any given constant fuel flow, whereas time constants obtained from transient operation exceed time constants obtained from steady-state characteristics by approximately 14 percent for any given blade angle.

The statistical analysis of circadian phase and amplitude in constant-routine core-temperature data

NASA Technical Reports Server (NTRS)

Brown, E. N.; Czeisler, C. A.

1992-01-01

Accurate estimation of the phases and amplitude of the endogenous circadian pacemaker from constant-routine core-temperature series is crucial for making inferences about the properties of the human biological clock from data collected under this protocol. This paper presents a set of statistical methods based on a harmonic-regression-plus-correlated-noise model for estimating the phases and the amplitude of the endogenous circadian pacemaker from constant-routine core-temperature data. The methods include a Bayesian Monte Carlo procedure for computing the uncertainty in these circadian functions. We illustrate the techniques with a detailed study of a single subject's core-temperature series and describe their relationship to other statistical methods for circadian data analysis. In our laboratory, these methods have been successfully used to analyze more than 300 constant routines and provide a highly reliable means of extracting phase and amplitude information from core-temperature data.

Thermal enclosures for electronically scanned pressure modules operating in cryogenic environments

NASA Technical Reports Server (NTRS)

Mitchell, Michael; Sealey, Bradley S.

1989-01-01

Specific guidelines to design, construct, and test ESP thermal enclosures for applications at cryogenic temperatures are given. The enclosures maintain the ESP modules at a constant temperature (10 C plus or minus 1 C) to minimize thermal zero and sensitivity shifts, to minimize the frequency of expensive on-line calibrations, and to avoid adverse effects on tunnel and model boundary layers. The enclosures are constructed of a rigid closed-cell foam and are capable of withstanding the stagnation pressures to 932kPa (135 psia) without reduction in thermal insulation properties. This construction procedure has been used to construct several thermal packages which have been successfully used in National Transonic Facility.

A continuous dry 300 mK cooler for THz sensing applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klemencic, G. M., E-mail: Georgina.Klemencic@astro.cf.ac.uk; Ade, P. A. R.; Sudiwala, R.

We describe and demonstrate the automated operation of a novel cryostat design that is capable of maintaining an unloaded base temperature of less than 300 mK continuously, without the need to recycle the gases within the final cold head, as is the case for conventional single shot sorption pumped {sup 3}He cooling systems. This closed dry system uses only 5 l of {sup 3}He gas, making this an economical alternative to traditional systems where a long hold time is required. During testing, a temperature of 365 mK was maintained with a constant 20 μW load, simulating the cooling requirement ofmore » a far infrared camera.« less

Impact of different environmental conditions on lithium-ion batteries performance through the thermal monitoring with fiber sensors

NASA Astrophysics Data System (ADS)

Nascimento, Micael; Ferreira, Marta S.; Pinto, João. L.

2017-08-01

In this work, an optical fiber sensing network has been developed to assess the impact of different environmental conditions on lithium batteries performance through the real time thermal monitoring. The battery is submitted to constant current charge and different discharge C-rates, under normal and abusive operating conditions. The results show that for the discharge C-rate of 5.77C, the LiB under cold and dry climates had 32.5% and 27.2% lower temperature variations, when compared with temperate climates, respectively. The higher temperature shift detected in the temperate climate was related to the battery better performance regarding discharge capacity and power capabilities.

Electrical Noise and the Measurement of Absolute Temperature, Boltzmann's Constant and Avogadro's Number.

ERIC Educational Resources Information Center

Ericson, T. J.

1988-01-01

Describes an apparatus capable of measuring absolute temperatures of a tungsten filament bulb up to normal running temperature and measuring Botzmann's constant to an accuracy of a few percent. Shows that electrical noise techniques are convenient to demonstrate how the concept of temperature is related to the micro- and macroscopic world. (CW)

Response of Fusarium solani to Fluctuating Temperatures

Treesearch

Keith F. Jensen; Phillip E. Reynolds; Phillip E. Reynolds

1971-01-01

The purpose of this study was to measure growth under a range of constant temperatures and under a series of fluctuating temperature regimes, and to determine if growth in the fluctuating temperiture regimes could be predicted satisfactorily from the growth data collected in the constant temperature experiments. Growth was measured on both agar and liquid culture to...

Magnetic heat pumping

NASA Technical Reports Server (NTRS)

Brown, G. V. (Inventor)

1978-01-01

A ferromagnetic or ferrimagnetic element is used to control the temperature and applied magnetic field of the element to cause the state of the element as represented on a temperature-magnetic entropy diagram to repeatedly traverse a loop. The loop may have a first portion of concurrent substantially isothermal or constant temperature and increasing applied magnetic field, a second portion of lowering temperature and constant applied magnetic field, a third portion of isothermal and decreasing applied magnetic field, and a fourth portion of increasing temperature and constant applied magnetic field. Other loops may be four-sided, with two isotherms and two adiabats. Preferably, a regenerator is used to enhance desired cooling or heating effects, with varied magnetic fields, or varying temperatures including three-sided figures traversed by the representative point.

Tunable diode-laser heterodyne spectrometer for remote observations near 8 microns

NASA Technical Reports Server (NTRS)

Glenar, D.; Kostiuk, T.; Jennings, D. E.; Buhl, D.; Mumma, M. J.

1982-01-01

A diode-laser-based, ultrahigh resolution IR heterodyne spectrometer for laboratory and field use has been developed for operation between 7.5 and 8.5 microns. The local oscillator is a PbSe tunable diode laser kept continuously at operating temperatures of 12-60 K using a closed-cycle cooler. The laser output frequency is controlled and stabilized using a high-precision diode current supply, constant temperature controller, and a shock isolator mounted between the refrigerator cold tip and the diode mount. The system largely employs reflecting optics to minimize losses from internal reflection and absorption and to eliminate chromatic effects. Spectral analysis of the diode-laser output between 0 and 1 GHz reveals excess noise at many diode current settings, which limits the IR spectral regions over which useful heterodyne operation can be achieved. Observations have been made of atmospheric N2O, O3, and CH4 between 1170 and 1200/cm, using both a single-frequency swept IF channel and a 64-channel RF spectral line receiver with a total IF coverage of 1600 MHz.

Two-phase anaerobic digestion of source sorted OFMSW (organic fraction of municipal solid waste): performance and kinetic study.

PubMed

Pavan, P; Battistoni, P; Cecchi, F; Mata-Alvarez, J

2000-01-01

The results of a two-phase system operated in different conditions, treating the source-sorted organic fraction of municipal solid waste (SS-OFMSW), coming mainly from fruit and vegetable markets, are presented. Hydraulic retention time (HRT) in the hydrolytic reactor and in the methanogenic reactor and also the temperature in the hydrolytic reactor (mesophilic and thermophilic conditions) are varied in order to evaluate the effect of these factors. The methanogenic reactor is always operated within the thermophilic range. Optimum operating conditions are found to be around 12 days (total system) using the mesophilic range of temperature in the first reactor. Specific gas production (SGP) in these conditions is around 0.6 m3/kg TVS. A kinetic study is also carried out, using the first and the step diffusional models. The latter gives much better results, with fitted constants comparable to other studies. Finally, a comparison with a one-phase system is carried out, showing that a two-phase system is much more appropriate for the digestion of this kind of highly biodegradable substrate in thermophilic conditions.

Mechanism of bandwidth improvement in passively cooled SMA position actuators

NASA Astrophysics Data System (ADS)

Gorbet, R. B.; Morris, K. A.; Chau, R. C. C.

2009-09-01

The heating of shape memory alloy (SMA) materials leads to a thermally driven phase change which can be used to do work. An SMA wire can be thermally cycled by controlling electric current through the wire, creating an electro-mechanical actuator. Such actuators are typically heated electrically and cooled through convection. The thermal time constants and lack of active cooling limit the operating frequencies. In this work, the bandwidth of a still-air-cooled SMA wire controlled with a PID controller is improved through optimization of the controller gains. Results confirm that optimization can improve the ability of the actuator to operate at a given frequency. Overshoot is observed in the optimal controllers at low frequencies. This is a result of hysteresis in the wire's contraction-temperature characteristic, since different input temperatures can achieve the same output value. The optimal controllers generate overshoot during heating, in order to cause the system to operate at a point on the hysteresis curve where faster cooling can be achieved. The optimization results in a controller which effectively takes advantage of the multi-valued nature of the hysteresis to improve performance.

Wear and related characteristics of an aircraft tire during braking

NASA Technical Reports Server (NTRS)

Mccarty, J. L.

1972-01-01

Wear and related characteristics of friction and temperature developed during braking of size 22 x 5.5, type aircraft tires are studied. The testing technique involved gearing the tire to a driving wheel of a ground vehicle to provide operations at constant slip ratios on asphalt, concrete, and slurry-seal surfaces. Data were obtained over the range of slip ratios generally attributed to an aircraft braking system during dry runway operations. The results show that the cumulative tire wear varies linearly with distance traveled and the wear rate increases with increasing slip ratio and is influenced by the runway-surface character. Differences in the wear rates associated with the various surfaces suggest that runways can be rated on the basis of tire wear. The results also show that the friction coefficients developed during fixed-slip-ratio operations are in good agreement with those obtained by other investigators during cyclic braking, in that the dry friction is insensitive to the tire tread temperature is shown to increase with increasing slip ratio and, at the higher ratios, to be greater during braking on asphalt and slurry seal than on concrete.

Compensation of Verdet Constant Temperature Dependence by Crystal Core Temperature Measurement

PubMed Central

Petricevic, Slobodan J.; Mihailovic, Pedja M.

2016-01-01

Compensation of the temperature dependence of the Verdet constant in a polarimetric extrinsic Faraday sensor is of major importance for applying the magneto-optical effect to AC current measurements and magnetic field sensing. This paper presents a method for compensating the temperature effect on the Faraday rotation in a Bi12GeO20 crystal by sensing its optical activity effect on the polarization of a light beam. The method measures the temperature of the same volume of crystal that effects the beam polarization in a magnetic field or current sensing process. This eliminates the effect of temperature difference found in other indirect temperature compensation methods, thus allowing more accurate temperature compensation for the temperature dependence of the Verdet constant. The method does not require additional changes to an existing Δ/Σ configuration and is thus applicable for improving the performance of existing sensing devices. PMID:27706043

Effect of Ru thickness on spin pumping in Ru/Py bilayer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Behera, Nilamani; Singh, M. Sanjoy; Chaudhary, Sujeet

2015-05-07

We report the effect of Ru thickness (t{sub Ru}) on ferromagnetic resonance (FMR) line-width of Ru(t{sub Ru})/Py(23 nm) bilayer samples grown on Si(100)/SiO{sub 2} substrates at room temperature by magnetron sputtering. The FMR line-width is found to vary linearly with frequency for all thicknesses of Ru, indicating intrinsic origin of damping. For Ru thicknesses below 15 nm, Gilbert-damping parameter, α is almost constant. We ascribe this behavior to spin back flow that is operative for Ru thicknesses lower than the spin diffusion length in Ru, λ{sub sd}. For thicknesses >15 nm (>λ{sub sd}), the damping constant increases with Ru thickness, indicating spin pumpingmore » from Py into Ru.« less

The Impacts of Rising Temperatures on Aircraft Takeoff Performance

NASA Technical Reports Server (NTRS)

Coffel, Ethan; Thompson, Terence R.; Horton, Radley M.

2017-01-01

Steadily rising mean and extreme temperatures as a result of climate change will likely impact the air transportation system over the coming decades. As air temperatures rise at constant pressure, air density declines, resulting in less lift generation by an aircraft wing at a given airspeed and potentially imposing a weight restriction on departing aircraft. This study presents a general model to project future weight restrictions across a fleet of aircraft with different takeoff weights operating at a variety of airports. We construct performance models for five common commercial aircraft and 19 major airports around the world and use projections of daily temperatures from the CMIP5 model suite under the RCP 4.5 and RCP 8.5 emissions scenarios to calculate required hourly weight restriction. We find that on average, 10 - 30% of annual flights departing at the time of daily maximum temperature may require some weight restriction below their maximum takeoff weights, with mean restrictions ranging from 0.5 to 4% of total aircraft payload and fuel capacity by mid- to late century. Both mid-sized and large aircraft are affected, and airports with short runways and high temperatures, or those at high elevations, will see the largest impacts. Our results suggest that weight restriction may impose a non-trivial cost on airlines and impact aviation operations around the world and that adaptation may be required in aircraft design, airline schedules, and/or runway lengths.

Geometry effects on cooling in a standing wave cylindrical thermoacousic resonator

NASA Astrophysics Data System (ADS)

Mohd-Ghazali, Normah; Ghazali, Ahmad Dairobi; Ali, Irwan Shah; Rahman, Muhammad Aminullah A.

2012-06-01

Numerous reports have established the refrigeration applications of thermoacoustic cooling without compressors and refrigerants. Significant cooling effects can be obtained in a thermoacoustic resonator fitted with a heat exchanging stack and operated at resonance frequency. Past studies, however, have hardly referred to the fundamental relationship between resonant frequency and the resonator geometry. This paper reports the thermoacoustic cooling effects at resonance obtained by changing the diameter of the resonator while holding the length constant and vice versa. Experiments were completed at atmospheric pressure with air as the working fluid using a number of pvc tubes having parallel plate stack from Mylar. The temperature difference measured across the stack showed that a volume increase in the working fluid in general increases the temperature gradient for the quarter-and half-wavelength resonators. Doubling the diameter from 30 mm to 60 mm produced the highest temperature difference due to the greater number of stack plates resulting in a higher overall thermoacaoustic cooling. Increasing the resonator length only produced a small increase in temperature gradient since the resonant frequency at operation is only slightly changed. Investigation on the aspect ratio exhibits no influence on the temperature difference across the stack. This study have shown that the resonator length and diameter do affect the temperature difference across the thermoacoustic stack, and further research should be done to consider the contribution of the stack mass on the overall desired thermoacoustic cooling.

A simplified water temperature model for the Colorado River below Glen Canyon Dam

USGS Publications Warehouse

Wright, S.A.; Anderson, C.R.; Voichick, N.

2009-01-01

Glen Canyon Dam, located on the Colorado River in northern Arizona, has affected the physical, biological and cultural resources of the river downstream in Grand Canyon. One of the impacts to the downstream physical environment that has important implications for the aquatic ecosystem is the transformation of the thermal regime from highly variable seasonally to relatively constant year-round, owing to hypolimnetic releases from the upstream reservoir, Lake Powell. Because of the perceived impacts on the downstream aquatic ecosystem and native fish communities, the Glen Canyon Dam Adaptive Management Program has considered modifications to flow releases and release temperatures designed to increase downstream temperatures. Here, we present a new model of monthly average water temperatures below Glen Canyon Dam designed for first-order, relatively simple evaluation of various alternative dam operations. The model is based on a simplified heat-exchange equation, and model parameters are estimated empirically. The model predicts monthly average temperatures at locations up to 421 km downstream from the dam with average absolute errors less than 0.58C for the dataset considered. The modelling approach used here may also prove useful for other systems, particularly below large dams where release temperatures are substantially out of equilibrium with meteorological conditions. We also present some examples of how the model can be used to evaluate scenarios for the operation of Glen Canyon Dam.

Clausius inequality beyond the weak-coupling limit: the quantum Brownian oscillator.

PubMed

Kim, Ilki; Mahler, Günter

2010-01-01

We consider a quantum linear oscillator coupled at an arbitrary strength to a bath at an arbitrary temperature. We find an exact closed expression for the oscillator density operator. This state is noncanonical but can be shown to be equivalent to that of an uncoupled linear oscillator at an effective temperature T*(eff) with an effective mass and an effective spring constant. We derive an effective Clausius inequality deltaQ*(eff)< or =T*(eff)dS , where deltaQ*(eff) is the heat exchanged between the effective (weakly coupled) oscillator and the bath, and S represents a thermal entropy of the effective oscillator, being identical to the von-Neumann entropy of the coupled oscillator. Using this inequality (for a cyclic process in terms of a variation of the coupling strength) we confirm the validity of the second law. For a fixed coupling strength this inequality can also be tested for a process in terms of a variation of either the oscillator mass or its spring constant. Then it is never violated. The properly defined Clausius inequality is thus more robust than assumed previously.

Study on optical properties of L-valine doped ADP crystal

NASA Astrophysics Data System (ADS)

Shaikh, R. N.; Anis, Mohd.; Shirsat, M. D.; Hussaini, S. S.

2015-02-01

Single crystal of L-valine doped ammonium dihydrogen phosphate has been grown by slow evaporation method at room temperature. The crystalline nature of the grown crystal was confirmed using powder X-ray diffraction technique. The different functional groups of the grown crystal were identified using Fourier transform infrared analysis. The UV-visible studies were employed to examine the high optical transparency and influential optical constants for tailoring materials suitability for optoelectronics applications. The cutoff wavelength of the title crystal was found to be 280 nm with wide optical band gap of 4.7 eV. The dielectric measurements were carried to determine the dielectric constant and dielectric loss at room temperature. The grown crystal has been characterized by thermogravimetric analysis. The second harmonic generation efficiency of the grown crystal was determined by the classical Kurtz powder technique and it is found to be 1.92 times that of potassium dihydrogen phosphate. The grown crystal was identified as third order nonlinear optical material employing Z-scan technique using He-Ne laser operating at 632.8 nm.

Self-consistent phonon calculations of lattice dynamical properties in cubic SrTiO3 with first-principles anharmonic force constants

NASA Astrophysics Data System (ADS)

Tadano, Terumasa; Tsuneyuki, Shinji

2015-08-01

We present an ab initio framework to calculate anharmonic phonon frequency and phonon lifetime that is applicable to severely anharmonic systems. We employ self-consistent phonon (SCPH) theory with microscopic anharmonic force constants, which are extracted from density functional calculations using the least absolute shrinkage and selection operator technique. We apply the method to the high-temperature phase of SrTiO3 and obtain well-defined phonon quasiparticles that are free from imaginary frequencies. Here we show that the anharmonic phonon frequency of the antiferrodistortive mode depends significantly on the system size near the critical temperature of the cubic-to-tetragonal phase transition. By applying perturbation theory to the SCPH result, phonon lifetimes are calculated for cubic SrTiO3, which are then employed to predict lattice thermal conductivity using the Boltzmann transport equation within the relaxation-time approximation. The presented methodology is efficient and accurate, paving the way toward a reliable description of thermodynamic, dynamic, and transport properties of systems with severe anharmonicity, including thermoelectric, ferroelectric, and superconducting materials.

Defect-induced change of temperature-dependent elastic constants in BCC iron

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, N.; Setyawan, W.; Zhang, S. H.

2017-07-01

The effects of radiation-induced defects (randomly distributed vacancies, voids, and interstitial dislocation loops) on temperature-dependent elastic constants, C11, C12, and C44 in BCC iron, are studied with molecular dynamics method. The elastic constants are found to decrease with increasing temperatures for all cases containing different defects. The presence of vacancies, voids, or interstitial loops further decreases the elastic constants. For a given number of point defects, the randomly distributed vacancies show the strongest effect compared to voids or interstitial loops. All these results are expected to provide useful information to combine with experimental results for further understanding of radiation damage.

Investigation on de-trapping mechanisms related to non-monotonic kink pattern in GaN HEMT devices

NASA Astrophysics Data System (ADS)

Sharma, Chandan; Laishram, Robert; Amit, Rawal, Dipendra Singh; Vinayak, Seema; Singh, Rajendra

2017-08-01

This article reports an experimental approach to analyze the kink effect phenomenon which is usually observed during the GaN high electron mobility transistor (HEMT) operation. De-trapping of charge carriers is one of the prominent reasons behind the kink effect. The commonly observed non-monotonic behavior of kink pattern is analyzed under two different device operating conditions and it is found that two different de-trapping mechanisms are responsible for a particular kink behavior. These different de-trapping mechanisms are investigated through a time delay analysis which shows the presence of traps with different time constants. Further voltage sweep and temperature analysis corroborates the finding that different de-trapping mechanisms play a role in kink behavior under different device operating conditions.

IR-to-visible image upconverter under nonlinear crystal thermal gradient operation.

PubMed

Maestre, H; Torregrosa, A J; Fernández-Pousa, C R; Capmany, J

2018-01-22

In this work we study the enhancement of the field-of-view of an infrared image up-converter by means of a thermal gradient in a PPLN crystal. Our work focuses on compact upconverters, in which both a short PPLN crystal length and high numerical aperture lenses are employed. We found a qualitative increase in both wavelength and angular tolerances, compared to a constant temperature upconverter, which makes it necessary a correct IR wavelength allocation in order to effectively increase the up-converted area.

High internal free volume compositions for low-k dielectric and other applications

NASA Technical Reports Server (NTRS)

Bouffard, Jean (Inventor); Swager, Timothy M. (Inventor)

2010-01-01

The present invention provides materials, devices, and methods involving new heterocyclic, shape-persistent monomeric units with internal free volume. In some cases, materials the present invention may comprise monomers, oligomers, or polymers that incorporate a heterocyclic, shape-persistent iptycene. The present invention may provide materials having low dielectric constants and improved stability at high operating temperatures due to the electron-poor character of materials. In addition, compositions of the invention may be easily synthesized and readily modified to suit a particular application.

Direct Estimation of Power Distribution in Reactors for Nuclear Thermal Space Propulsion

NASA Astrophysics Data System (ADS)

Aldemir, Tunc; Miller, Don W.; Burghelea, Andrei

2004-02-01

A recently proposed constant temperature power sensor (CTPS) has the capability to directly measure the local power deposition rate in nuclear reactor cores proposed for space thermal propulsion. Such a capability reduces the uncertainties in the estimated power peaking factors and hence increases the reliability of the nuclear engine. The CTPS operation is sensitive to the changes in the local thermal conditions. A procedure is described for the automatic on-line calibration of the sensor through estimation of changes in thermal .conditions.

NMC stratospheric analyses during the 1987 Antarctic expedition

NASA Technical Reports Server (NTRS)

Gelman, Melvyn E.; Newman, Paul A.

1988-01-01

Stratospheric constant pressure analyses of geopotential height and temperature, produced as part of regular operations at the National Meteorological Center (NMC), were used by several participants of the Antarctic Ozone Expedition. A brief decription is given of the NMC stratospheric analyses and the data that are used to derive them. In addition, comparisons of the analysis values at the locations of radiosonde and aircraft data are presented to provide indications for assessing the representativeness of the NMC stratospheric analyses during the 1987 Antarctic winter-spring period.

Low pressure arc discharge lamp apparatus with magnetic field generating means

DOEpatents

Grossman, M.W.; George, W.A.; Maya, J.

1987-10-06

A low-pressure arc discharge apparatus having a magnetic field generating means for increasing the output of a discharge lamp is disclosed. The magnetic field generating means, which in one embodiment includes a plurality of permanent magnets, is disposed along the lamp for applying a constant transverse magnetic field over at least a portion of the positive discharge column produced in the arc discharge lamp operating at an ambient temperature greater than about 25 C. 3 figs.

Performance seeking control: Program overview and future directions

NASA Technical Reports Server (NTRS)

Gilyard, Glenn B.; Orme, John S.

1993-01-01

A flight test evaluation of the performance-seeking control (PSC) algorithm on the NASA F-15 highly integrated digital electronic control research aircraft was conducted for single-engine operation at subsonic and supersonic speeds. The model-based PSC system was developed with three optimization modes: minimum fuel flow at constant thrust, minimum turbine temperature at constant thrust, and maximum thrust at maximum dry and full afterburner throttle settings. Subsonic and supersonic flight testing were conducted at the NASA Dryden Flight Research Facility covering the three PSC optimization modes and over the full throttle range. Flight results show substantial benefits. In the maximum thrust mode, thrust increased up to 15 percent at subsonic and 10 percent at supersonic flight conditions. The minimum fan turbine inlet temperature mode reduced temperatures by more than 100 F at high altitudes. The minimum fuel flow mode results decreased fuel consumption up to 2 percent in the subsonic regime and almost 10 percent supersonically. These results demonstrate that PSC technology can benefit the next generation of fighter or transport aircraft. NASA Dryden is developing an adaptive aircraft performance technology system that is measurement based and uses feedback to ensure optimality. This program will address the technical weaknesses identified in the PSC program and will increase performance gains.

Exact solutions of laminar-boundary-layer equations with constant property values for porous wall with variable temperature

NASA Technical Reports Server (NTRS)

Donoughe, Patrick L; Livingood, John N B

1955-01-01

Exact solution of the laminar-boundary-layer equations for wedge-type flow with constant property values are presented for transpiration-cooled surfaces with variable wall temperatures. The difference between wall and stream temperature is assumed proportional to a power of the distance from the leading edge. Solutions are given for a Prandtl number of 0.7 and ranges of pressure-gradient, cooling-air-flow, and wall-temperature-gradient parameters. Boundary-layer profiles, dimensionless boundary-layer thicknesses, and convective heat-transfer coefficients are given in both tabular and graphical form. Corresponding results for constant wall temperature and for impermeable surfaces are included for comparison purposes.

Using solubility and Henry`s law constant data for ketones in water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yaws, C.L.; Sheth, S.D.; Han, M.

When a chemical spill occurs in water, the extent of chemical contamination is determined by the chemical`s solubility in the water. If contaminated water comes into contact with air, such as in a pond or a storage vessel, the contaminant`s emissions into the air can be determined based upon Henry`s law constant for that particular constituent. A high Henry`s law constant value translates into a greater emissions level. The engineering design and operation of strippers to remove contaminants from water require data for both water solubility and Henry`s law constant. A new correlation developed by researchers at Lamar University providesmore » reliable values down to very, very low concentrations for the solubility of ketones in water. The correlation is based on the boiling point temperature of the ketone and can be used for engineering studies involving health, safety and environmental considerations. Results for water solubility and Henry`s law constant are provided here for a wide variety of ketones. Representative values are about 249,000 parts per million (ppm) per weight (wt) for methyl ethyl ketone (C{sub 4}H{sub 8}O) and 360 ppm/wt for 5-nonanone (C{sub 9}H{sub 18}O).« less

Analysis and design of ferroelectric-based smart antenna structures

NASA Astrophysics Data System (ADS)

Ramesh, Prashanth; Washington, Gregory N.

2009-03-01

Ferroelectrics in microwave antenna systems offer benefits of electronic tunability, compact size and light weight, speed of operation, high power-handling, low dc power consumption, and potential for low loss and cost. Ferroelectrics allow for the tuning of microwave devices by virtue of the nonlinear dependence of their dielectric permittivity on an applied electric field. Experiments on the field-polarization dependence of ferroelectric thin films show variation in dielectric permittivity of up to 50%. This is in contrast to the conventional dielectric materials used in electrical devices which have a relatively constant permittivity, indicative of the linear field-polarization curve. Ferroelectrics, with their variable dielectric constant introduce greater flexibility in correction and control of beam shapes and beam direction of antenna structures. The motivation behind this research is applying ferroelectrics to mechanical load bearing antenna structures, but in order to develop such structures, we need to understand not just the field-permittivity dependence, but also the coupled electro-thermo-mechanical behavior of ferroelectrics. In this paper, two models are discussed: a nonlinear phenomenological model relating the applied fields, strains and temperature to the dielectric permittivity based on the Devonshire thermodynamic framework, and a phenomenological model relating applied fields and temperature to the dielectric loss tangent. The models attempt to integrate the observed field-permittivity, strain-permittivity and temperature-permittivity behavior into one single unified model and extend the resulting model to better fit experimental data. Promising matches with experimental data are obtained. These relations, coupled with the expression for operating frequency vs. the permittivity are then used to understand the bias field vs. frequency behavior of the antenna. Finally, the effect of the macroscopic variables on the antenna radiation efficiency is discussed.

Comparison of collision operators for the geodesic acoustic mode

NASA Astrophysics Data System (ADS)

Li, Yang; Gao, Zhe

2015-04-01

The collisional damping rate and real frequency of the geodesic acoustic mode (GAM) are solved from a drift kinetic model with different collision operators. As the ion collision rate increases, the damping rate increases at low collision rate but decays at high ion collision rate. Different collision operators do not change the overall trend but influence the magnitude of the damping rate. The collision damping is much overestimated with the number-conserving-only Krook operator; on the other hand, using the Lorentz operator with a constant collision rate, the damping is overestimated at low collision rate but underestimated at high collision rate. The results from the Krook operator with both number and energy conservation terms, the Lorentz operator with an energy-dependent collision rate and the full Hirshman-Sigmar-Clarke collision operator are very close. Meanwhile, as the ion collision rate increases, the GAM frequency decreases from the collisionless value, \\sqrt {7/4+τ} {vti}/R , to \\sqrt {1+τ} {vti}/R for the number-conserving-only Krook operator, but to \\sqrt {5/3+τ} {vti}/R for the other four operators, which conserve both number and energy, where τ, vti and R are the ratio of electron temperature to ion temperature, the ion thermal velocity and the major radius, respectively. The results imply that the property of energy conservation of the collision operator is important to the dynamics of the GAM as well as that of number conservation, which may provide guidance in choosing collision operators in further study of the zonal flow (ZF) dynamics, such as the nonlinear simulation of the ZF-turbulence system.

Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adam, Ahmad Y.; Jensen, Per, E-mail: jensen@uni-wuppertal.de; Yachmenev, Andrey

2015-12-28

We present the first variational calculation of the isotropic hyperfine coupling constant of the carbon-13 atom in the CH{sub 3} radical for temperatures T = 0, 96, and 300 K. It is based on a newly calculated high level ab initio potential energy surface and hyperfine coupling constant surface of CH{sub 3} in the ground electronic state. The ro-vibrational energy levels, expectation values for the coupling constant, and its temperature dependence were calculated variationally by using the methods implemented in the computer program TROVE. Vibrational energies and vibrational and temperature effects for coupling constant are found to be in verymore » good agreement with the available experimental data. We found, in agreement with previous studies, that the vibrational effects constitute about 44% of the constant’s equilibrium value, originating mainly from the large amplitude out-of-plane bending motion and that the temperature effects play a minor role.« less

A Simple Method to Calculate the Temperature Dependence of the Gibbs Energy and Chemical Equilibrium Constants

ERIC Educational Resources Information Center

Vargas, Francisco M.

2014-01-01

The temperature dependence of the Gibbs energy and important quantities such as Henry's law constants, activity coefficients, and chemical equilibrium constants is usually calculated by using the Gibbs-Helmholtz equation. Although, this is a well-known approach and traditionally covered as part of any physical chemistry course, the required…

Development of a temperature measurement system with application to a jet in a cross flow experiment

NASA Technical Reports Server (NTRS)

Wark, C.; Foss, J. F.

1985-01-01

A temperature measurement system, which allows the simultaneous sampling of up to 80 separate thermocouples, was developed. The minimum resolution for the system corresponds to + or - 0.16 C per least significant bit of the A/D converter. The time constant values lambda, for each of the 64 thermocouples, were determined experimentally at 7 mps. Software routines were used to correct the measured temperatures for the effect of lambda for each thermocouple. The temperature measurement system was utilized to study the thermal field of a heated jet discharging perpendicularly into a low and a high disturbance level cross stream for a given momentum flux ratio and for three overheated values. The peak instantaneous temperatures reveal that strong molecular diffusion was operative. Various measures of the thermal field, for the disturbed case, suggest that the jet column remains relatively compact while being buffeted by the ambient turbulence field and that its penetration, into the cross wind, is inhibited by the presence of the strong disturbance field.

Experimental test program for evaluation of solid lubricant coating as applied to compliant foil gas bearings to 315 deg C

NASA Technical Reports Server (NTRS)

Wagner, R. C.

1985-01-01

An experimental apparatus and test procedure was developed to compare the performance of two solid lubricant coatings for air lubricated compliant foil gas bearings in the temperature range of 25 to 315 C. Polyimide bonded additive (SBGC) were tested extensively for durability and frictional characteristics. A partial arc bearing constructed of Inconel X-750 was coated on the bore with one of these coatings. The foil was subjected to repeated start/stop cycles. Performance comparisons reveal that although both coatings survive thousands of start/stop cycles, only the PBGF coated bearing achieves the specified 9000 start/stops. There is enough wear on the SBGC coated bearing to warrant termination of the test prior to 9000 start/stop cycles due to coating failure. The frictional characteristics of the PBGF are better at the elevated temperatures than at lower temperatures; a marked increase in sliding friction occurs as the temperature decreases. The SBGC maintains relatively constant frictional characteristics independent of operating temperature.

Long-term frequency and amplitude stability of a solid-nitrogen-cooled, continuous wave THz quantum cascade laser

NASA Astrophysics Data System (ADS)

Danylov, Andriy A.; Waldman, Jerry; Light, Alexander R.; Goyette, Thomas M.; Giles, Robert H.; Qian, Xifeng; Chandrayan, Neelima; Goodhue, William D.; Nixon, William E.

2012-02-01

Operational temperature increase of CW THz QCLs to 77 K has enabled us to employ solid nitrogen (SN2) as the cryogen. A roughing pump was used to solidify liquid nitrogen and when the residual vapor pressure in the nitrogen reservoir reached the pumping system's minimum pressure the temperature equilibrated and remained constant until all the nitrogen sublimated. The hold time compared to liquid helium has thereby increased approximately 70-fold, and at a greatly reduced cost. The milliwatt CW QCL was at a temperature of approximately 60 K, dissipating 5 W of electrical power. To measure the long-term frequency, current, and temperature stability, we heterodyned the free-running 2.31 THz QCL with a CO2 pumped far-infrared gas laser line in methanol (2.314 THz) in a corner-cube Schottky diode and recorded the IF frequency, current and temperature. Under these conditions the performance characteristics of the QCL, which will be reported, exceeded that of a device mounted in a mechanical cryocooler.

Ion transport with charge-protected and non-charge-protected cations in alcohol-based electrolytes using the compensated Arrhenius formalism. Part I: ionic conductivity and the static dielectric constant.

PubMed

Petrowsky, Matt; Fleshman, Allison; Frech, Roger

2012-05-17

The temperature dependence of ionic conductivity and the static dielectric constant is examined for 0.30 m TbaTf- or LiTf-1-alcohol solutions. Above ambient temperature, the conductivity increases with temperature to a greater extent in electrolytes whose salt has a charge-protected cation. Below ambient temperature, the dielectric constant changes only slightly with temperature in electrolytes whose salt has a cation that is not charge-protected. The compensated Arrhenius formalism is used to describe the temperature-dependent conductivity in terms of the contributions from both the exponential prefactor σo and Boltzmann factor exp(-Ea/RT). This analysis explains why the conductivity decreases with increasing temperature above 65 °C for the LiTf-dodecanol electrolyte. At higher temperatures, the decrease in the exponential prefactor is greater than the increase in the Boltzmann factor.

Development of a low-pressure materials pre-treatment process for improved energy efficiency

NASA Astrophysics Data System (ADS)

Lee, Kwanghee; You, Byung Don

2017-09-01

Low pressure materials pre-treatment process has been developed as an alternative to the existing high-temperature sludge drying, limestone calcination, and limonite dehydroxylation. Using the thermodynamic equilibrium relationship between temperature and pressure represented by the Clausius-Clapeyron equation, the operational temperature of these reactions could be lowered at reduced pressure for increased energy efficiency. For industrial sludge drying, the evaporation rate was controlled by interfacial kinetics showing a constant rate with time and significant acceleration in the reaction could be observed with reduced pressure. At this modified reaction rate under low pressure, the rate was also partially controlled by mass transfer. Temperature of limestone calcination was lowered, but the reaction was limited at the calculated equilibrium temperature of the Clausius-Clapeyron equation and slightly higher temperatures were required. The energy consumption during limestone calcination and limonite dehydroxylation were evaluated, where lower processing pressures could enhance the energy efficiency for limestone calcination, but limonite dehydroxylation could not achieve energy-savings due to the greater power consumption of the vacuum pump under lower pressure and reduced temperatures.

Rotary engine performance computer program (RCEMAP and RCEMAPPC): User's guide

NASA Technical Reports Server (NTRS)

Bartrand, Timothy A.; Willis, Edward A.

1993-01-01

This report is a user's guide for a computer code that simulates the performance of several rotary combustion engine configurations. It is intended to assist prospective users in getting started with RCEMAP and/or RCEMAPPC. RCEMAP (Rotary Combustion Engine performance MAP generating code) is the mainframe version, while RCEMAPPC is a simplified subset designed for the personal computer, or PC, environment. Both versions are based on an open, zero-dimensional combustion system model for the prediction of instantaneous pressures, temperature, chemical composition and other in-chamber thermodynamic properties. Both versions predict overall engine performance and thermal characteristics, including bmep, bsfc, exhaust gas temperature, average material temperatures, and turbocharger operating conditions. Required inputs include engine geometry, materials, constants for use in the combustion heat release model, and turbomachinery maps. Illustrative examples and sample input files for both versions are included.

Field experience and performance evaluation of a medium-concentration CPV system

NASA Astrophysics Data System (ADS)

Norton, Matthew; Bentley, Roger; Georghiou, George E.; Chonavel, Sylvain; De Mutiis, Alfredo

2012-10-01

With the aim of gaining experience and performance data from location with a harsh summer climate, a 70 X concentrating photovoltaic (CPV) system was installed in Janurary 2009 in Nicosia, Cyprus. The performance of this system has been monitored using regular current-voltage characterisations for three years. Over this period, the output of the system has remained fairly constant. Measured performance ratios varied from 0.79 to 0.86 in the winter, but fell to 0.64 over the year when left uncleaned. Operating cell temperatures were modeled and found to be similar to those of flat plate modules. The most significant causes of energy loss have been identified as originating from tracking issues and soiling. Losses due to soiling could account for a drop in output of 0.2% per day. When cleaned and properly oriented, the normalized output of the system has remained constant, suggesting that this particular design is tolerant to the physical strain of long-term outdoor exposure in harsh summer conditions. Regular cleaning and reliable tracker operation are shown to be essential for maximizing energy yield.

Wide temperature range (T = 295 K and 770-1305 K) study of the kinetics of the reactions HCO + NO and HCO + NO2 using frequency modulation spectroscopy.

PubMed

Dammeier, J; Colberg, M; Friedrichs, G

2007-08-21

The rate constants for , HCO + NO --> HNO + CO, and , HCO + NO(2)--> products, have been measured at temperatures between 770 K < T < 1305 K behind reflected shock waves and, for the purpose of a consistency check, in a slow flow reactor at room temperature. HCO radicals were generated by 193 nm excimer laser photolysis of diluted gas mixtures containing glyoxal, (CHO)(2), and NO or NO(2) in argon and were monitored using frequency modulation (FM) absorption spectroscopy. Kinetic simulations based on a comprehensive reaction mechanism showed that the rate constants for the title reactions could be sensitively extracted from the measured HCO profiles. The determined high temperature rate constants are k(1)(769-1307 K) = (7.1 +/- 2.7) x 10(12) cm(3) mol(-1) s(-1) and k(2)(804-1186 K) = (3.3 +/- 1.8) x 10(13) cm(3) mol(-1) s(-1). The room temperature values were found to be in very good agreement with existing literature data and show that both reactions are essentially temperature independent. The weak temperature dependence of can be explained by the interplay of a dominating direct abstraction pathway and a complex-forming mechanism. Both pathways yield the products HNO + CO. In contrast to , no evidence for a significant contribution of a direct high temperature abstraction channel was found for . Here, the observed temperature independent overall rate constant can be described by a complex-forming mechanism with several product channels. Detailed information on the strongly temperature dependent channel branching ratios is provided. Moreover, the high temperature rate constant of , OH + (CHO)(2), has been determined to be k(7) approximately 1.1 x 10(13) cm(3) mol(-1) s(-1).

Effect of temperature on the protonation of N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid in aqueous solutions: Potentiometric and calorimetric studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Xingliang; Zhang, Zhicheng; Endrizzi, Francesco

2015-06-01

The TALSPEAK process (Trivalent Actinide Lanthanide Separations by Phosphorus-reagent Extraction from Aqueous Komplexes) has been demonstrated in several pilot-scale operations to be effective at separating trivalent actinides (An 3+) from trivalent lanthanides (Ln 3+). However, fundamental studies have revealed undesired aspects of TALSPEAK, such as the significant partitioning of Na +, lactic acid, and water into the organic phase, thermodynamically unpredictable pH dependence, and the slow extraction kinetics. In the modified TALSPEAK process, the combination of the aqueous holdback complexant HEDTA (N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid) with the extractant HEH[EHP] (2-ethyl(hexyl) phosphonic acid mono-2-ethylhexyl ester) in the organic phase has been found tomore » exhibit a nearly flat pH dependence between 2.5 and 4.5 and more rapid phase transfer kinetics for the heavier lanthanides. To help understand the speciation of Ln 3+ and An 3+ in the modified TALSPEAK, systematic studies are underway on the thermodynamics of major reactions in the HEDTA system under conditions relevant to the process (e.g., higher temperatures). Thermodynamics of the protonation and complexation of HEDTA with Ln 3+ were studied at variable temperatures. Equilibrium constants and enthalpies were determined by a combination of techniques including potentiometry and calorimetry. This paper presents the protonation constants of HEDTA at T = (25 to 70) °C. The potentiometric titrations have demonstrated that, stepwise, the first two protonation constants decrease and the third one slightly increases with the increase of temperature. This trend is in good agreement with the enthalpy of protonation directly determined by calorimetry. The results of NMR analysis further confirm that the first two protonation reactions occur on the diamine nitrogen atoms, while the third protonation reaction occurs on the oxygen of a carboxylate group. These data, in conjunction with the thermodynamic parameters of Ln 3+/An 3+ complexes with HEDTA at different temperatures, will help to predict the speciation and temperature-dependent behavior of Ln 3+/An 3+ in the modified TALSPEAK process.« less

Room-temperature and temperature-dependent QSRR modelling for predicting the nitrate radical reaction rate constants of organic chemicals using ensemble learning methods.

PubMed

Gupta, S; Basant, N; Mohan, D; Singh, K P

2016-07-01

Experimental determinations of the rate constants of the reaction of NO3 with a large number of organic chemicals are tedious, and time and resource intensive; and the development of computational methods has widely been advocated. In this study, we have developed room-temperature (298 K) and temperature-dependent quantitative structure-reactivity relationship (QSRR) models based on the ensemble learning approaches (decision tree forest (DTF) and decision treeboost (DTB)) for predicting the rate constant of the reaction of NO3 radicals with diverse organic chemicals, under OECD guidelines. Predictive powers of the developed models were established in terms of statistical coefficients. In the test phase, the QSRR models yielded a correlation (r(2)) of >0.94 between experimental and predicted rate constants. The applicability domains of the constructed models were determined. An attempt has been made to provide the mechanistic interpretation of the selected features for QSRR development. The proposed QSRR models outperformed the previous reports, and the temperature-dependent models offered a much wider applicability domain. This is the first report presenting a temperature-dependent QSRR model for predicting the nitrate radical reaction rate constant at different temperatures. The proposed models can be useful tools in predicting the reactivities of chemicals towards NO3 radicals in the atmosphere, hence, their persistence and exposure risk assessment.

Photovoltaic array: Power conditioner interface characteristics

NASA Technical Reports Server (NTRS)

Gonzalez, C. C.; Hill, G. M.; Ross, R. G., Jr.

1982-01-01

The electrical output (power, current, and voltage) of flat plate solar arrays changes constantly, due primarily to changes in cell temperature and irradiance level. As a result, array loads such as dc-to-ac power conditioners must be capable of accommodating widely varying input levels while maintaining operation at or near the maximum power point of the array. The array operating characteristics and extreme output limits necessary for the systematic design of array load interfaces under a wide variety of climatic conditions are studied. A number of interface parameters are examined, including optimum operating voltage, voltage energy, maximum power and current limits, and maximum open circuit voltage. The effect of array degradation and I-V curve fill factor or the array power conditioner interface is also discussed. Results are presented as normalized ratios of power conditioner parameters to array parameters, making the results universally applicable to a wide variety of system sizes, sites, and operating modes.

ELECTRIC HOLDING FURNACE IN THE MALLEABLE FOUNDRY MAINTAINS CONSTANT TEMPERATURES ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

ELECTRIC HOLDING FURNACE IN THE MALLEABLE FOUNDRY MAINTAINS CONSTANT TEMPERATURES FOR IRON PRIOR TO FILLING MOBILE LADLES. - Stockham Pipe & Fittings Company, Malleable Foundry, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL

Electrochemical characterization and control of triple-layer muscles

NASA Astrophysics Data System (ADS)

Otero, Toribio F.; Cortes, Maria T.

2000-06-01

The electrochemical characterization of triple-layers formed by a EPA (Electroactive Polymer)/double-sided tape/EPA, like artificial muscles is described. Those muscles were characterized working under constant potential or under constant current. Due to the electrochemical nature of the electrochemomechanical property, muscles working under constant current produce constant movements, consuming increasing energies at decreasing temperatures, decreasing concentrations of electrolytes or trailing increasing masses. Muscles working at constant potential response with a faster movement if the temperature or the concentration of the electrolyte increase, or if the trailed weight decreases. Specific charges and specific energies were determined for every experimental condition.

Accurate Measurements of the Dielectric Constant of Seawater at L Band

NASA Technical Reports Server (NTRS)

Lang, Roger; Zhou, Yiwen; Utku, Cuneyt; Le Vine, David

2016-01-01

This paper describes measurements of the dielectric constant of seawater at a frequency of 1.413 GHz, the center of the protected band (i.e., passive use only) used in the measurement of sea surface salinity from space. The objective of the measurements is to accurately determine the complex dielectric constant of seawater as a function of salinity and temperature. A resonant cylindrical microwave cavity in transmission mode has been employed to make the measurements. The measurements are made using standard seawater at salinities of 30, 33, 35, and 38 practical salinity units over a range of temperatures from 0 degree C to 35 degree C in 5 degree C intervals. Repeated measurements have been made at each temperature and salinity. Mean values and standard deviations are then computed. The total error budget indicates that the real and imaginary parts of the dielectric constant have a combined standard uncertainty of about 0.3 over the range of salinities and temperatures considered. The measurements are compared with the dielectric constants obtained from the model functions of Klein and Swift and those of Meissner and Wentz. The biggest differences occur at low and high temperatures.

Possible Economies in Air-Conditioning by Accepting Temperature Swings.

ERIC Educational Resources Information Center

Loudon, A. G.; Petherbridge, P.

Public building air conditioning systems, which use constant and varying heat and cooling loads, are compared and investigated. Experiments indicated that constant temperature controls based on outside air temperature alone were inefficient. Ventilating a building with outside air and the methods of doing so are cited as being the most economical…

The Effect of Temperature on the Enzyme-Catalyzed Reaction: Insights from Thermodynamics

ERIC Educational Resources Information Center

Aledo, Juan Carlos; Jimenez-Riveres, Susana; Tena, Manuel

2010-01-01

When teaching the effect of temperature on biochemical reactions, the problem is usually oversimplified by confining the thermal effect to the catalytic constant, which is identified with the rate constant of the elementary limiting step. Therefore, only positive values for activation energies and values greater than 1 for temperature coefficients…

Compaction of basin sediments as a function of time-temperature history

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schmoker, J.W.; Gautier, D.L.

1989-03-01

Processes that affect burial diagenesis are dependent on time-temperature history (thermal maturity). Therefore, the porosity loss of sedimentary rocks during burial may often be better treated as a function of time-temperature history than of depth. Loss of porosity in the subsurface for sandstones, carbonates, and shales can be represented by a power function /phi/ = A(M)/sup B/, where /phi/ is porosity, A and B are constants for a given sedimentary rock population of homogeneous properties, and M is a measure of thermal maturity such as vitrinite reflectance (R/sub 0/) or Lopatin's time-temperature index (TTI). Regression lines of carbonate porosity andmore » of sandstone porosity upon thermal maturity form an envelope whose axis is approximated by /phi/ = 7.5(R/sub 0/)/sup /minus/1.18/ or, equivalently, by /phi/ = 30(TTI)/sup /minus/0.33/. These equations are preliminary generic relations of use for the regional modeling of both carbonate and sandstone compaction in sedimentary basins. The dependence of porosity upon time-temperature history incorporates the hypothesis that porosity-reducing processes operate continuously in sedimentary basins and, consequently, that compaction of basin sediments continues as long as porosity exists. Calculations indicate that subsidence due to loss of porosity through time (with depth held constant) can produce a second-stage passively formed basin in which many hundreds of meters of sediments can accumulate and which conforms with the structure of the original underlying basin. Such sediment accumulation results from the thermal maturation of thick sequences of sedimentary rocks rather than from global sea level change or tectonic subsidence.« less

Pion decay constant and the {rho}-meson mass at finite temperature in hidden local symmetry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harada, M.; Shibata, A.

1997-06-01

We study the temperature dependence of the pion decay constant and {rho}-meson mass in the hidden local symmetry model at one loop. Using the standard imaginary time formalism, we include the thermal effect of the {rho} meson as well as that of the pion. We show that the pion gives a dominant contribution to the pion decay constant and the {rho}-meson contribution slightly decreases the critical temperature. The {rho}-meson pole mass increases as T{sup 4}/m{sub {rho}}{sup 2} at low temperature, dominated by the pion-loop effect. At high temperature, although the pion-loop effect decreases the {rho}-meson mass, the {rho}-loop contribution overcomesmore » the pion-loop contribution and the {rho}-meson mass increases with temperature. We also show that the conventional parameter a is stable as the temperature increases. {copyright} {ital 1997} {ital The American Physical Society}« less

Correction of Temperatures of Air-Cooled Engine Cylinders for Variation in Engine and Cooling Conditions

NASA Technical Reports Server (NTRS)

Schey, Oscar W; Pinkel, Benjamin; Ellerbrock, Herman H , Jr

1939-01-01

Factors are obtained from semiempirical equations for correcting engine-cylinder temperatures for variation in important engine and cooling conditions. The variation of engine temperatures with atmospheric temperature is treated in detail, and correction factors are obtained for various flight and test conditions, such as climb at constant indicated air speed, level flight, ground running, take-off, constant speed of cooling air, and constant mass flow of cooling air. Seven conventional air-cooled engine cylinders enclosed in jackets and cooled by a blower were tested to determine the effect of cooling-air temperature and carburetor-air temperature on cylinder temperatures. The cooling air temperature was varied from approximately 80 degrees F. to 230 degrees F. and the carburetor-air temperature from approximately 40 degrees F. to 160 degrees F. Tests were made over a large range of engine speeds, brake mean effective pressures, and pressure drops across the cylinder. The correction factors obtained experimentally are compared with those obtained from the semiempirical equations and a fair agreement is noted.

Building America Case Study: Control Retrofits for Multifamily Domestic Hot Water Recirculation Systems, Brooklyn, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperaturemore » modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7 percent after implementing the demand control technique, 2 percent after implementing temperature modulation, and 15 percent after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8 percent, 1 percent, and 14 percent for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.« less

Building America Case Study: Control Retrofits for Multifamily Domestic Hot Water Recirculation Systems, Brooklyn, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. Dentz; E. Ansanelli, H. Henderson, Jr.; K. Varshney

Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperaturemore » modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7% after implementing the demand control technique, 2% after implementing temperature modulation, and 15% after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8%, 1%, and 14% for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.« less

Control Strategies to Reduce the Energy Consumption of Central Domestic Hot Water Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dentz, Jordan; Ansanelli, Eric; Henderson, Hugh

Domestic hot water (DHW) heating is the second largest energy end use in U.S. buildings, exceeded only by space conditioning. Recirculation systems consisting of a pump and piping loop(s) are commonly used in multifamily buildings to reduce wait time for hot water at faucets; however, constant pumping increases energy consumption by exposing supply and return line piping to continuous heat loss, even during periods when there is no demand for hot water. In this study, ARIES installed and tested two types of recirculation controls in a pair of buildings in order to evaluate their energy savings potential. Demand control, temperaturemore » modulation controls, and the simultaneous operation of both were compared to the baseline case of constant recirculation. Additionally, interactive effects between DHW control fuel reductions and space conditioning (heating and cooling) were estimated in order to make more realistic predictions of the payback and financial viability of retrofitting DHW systems with these controls. Results showed that DHW fuel consumption reduced by 7% after implementing the demand control technique, 2% after implementing temperature modulation, and 15% after implementing demand control and temperature modulation techniques simultaneously; recirculation pump runtime was reduced to 14 minutes or less per day. With space heating and cooling interactions included, the estimated annual cost savings were 8%, 1%, and 14% for the respective control techniques. Possible complications in the installation, commissioning and operation of the controls were identified and solutions offered.« less

Control of continuous irradiation injury on potatoes with daily temperature cycling

NASA Technical Reports Server (NTRS)

Tibbitts, T. W.; Bennett, S. M.; Cao, W.

1990-01-01

Two controlled-environment experiments were conducted to determine the effects of temperature fluctuations under continuous irradiation on growth and tuberization of two potato (Solanum tuberosum L.) cultivars, Kennebec and Superior. These cultivars had exhibited chlorotic and stunted growth under continuous irradiation and constant temperatures. The plants were grown for 4 weeks in the first experiment and for 6 weeks in the second experiment. Each experiment was conducted under continuous irradiation of 400 micromoles per square meter per second of photosynthetic photon flux and included two temperature treatments: constant 18 degrees C and fluctuating 22 degrees C/14 degrees C on a 12-hour cycle. A common vapor pressure deficit of 0.62 kilopascal was maintained at all temperatures. Plants under constant 18 degrees C were stunted and had chlorotic and abscised leaves and essentially no tuber formation. Plants grown under the fluctuating temperature treatment developed normally, were developing tubers, and had a fivefold or greater total dry weight as compared with those under the constant temperature. These results suggest that a thermoperiod can allow normal plant growth and tuberization in potato cultivars that are unable to develop effectively under continuous irradiation.

Temperature-Ramped 129Xe Spin-Exchange Optical Pumping

PubMed Central

2015-01-01

We describe temperature-ramped spin-exchange optical pumping (TR-SEOP) in an automated high-throughput batch-mode 129Xe hyperpolarizer utilizing three key temperature regimes: (i) “hot”—where the 129Xe hyperpolarization rate is maximal, (ii) “warm”—where the 129Xe hyperpolarization approaches unity, and (iii) “cool”—where hyperpolarized 129Xe gas is transferred into a Tedlar bag with low Rb content (<5 ng per ∼1 L dose) suitable for human imaging applications. Unlike with the conventional approach of batch-mode SEOP, here all three temperature regimes may be operated under continuous high-power (170 W) laser irradiation, and hyperpolarized 129Xe gas is delivered without the need for a cryocollection step. The variable-temperature approach increased the SEOP rate by more than 2-fold compared to the constant-temperature polarization rate (e.g., giving effective values for the exponential buildup constant γSEOP of 62.5 ± 3.7 × 10–3 min–1 vs 29.9 ± 1.2 × 10–3 min–1) while achieving nearly the same maximum %PXe value (88.0 ± 0.8% vs 90.1% ± 0.8%, for a 500 Torr (67 kPa) Xe cell loading—corresponding to nuclear magnetic resonance/magnetic resonance imaging (NMR/MRI) enhancements of ∼3.1 × 105 and ∼2.32 × 108 at the relevant fields for clinical imaging and HP 129Xe production of 3 T and 4 mT, respectively); moreover, the intercycle “dead” time was also significantly decreased. The higher-throughput TR-SEOP approach can be implemented without sacrificing the level of 129Xe hyperpolarization or the experimental stability for automation—making this approach beneficial for improving the overall 129Xe production rate in clinical settings. PMID:25008290

Oxide Morphology of a FeCrAl Alloy, Kanthal APMT, following Extended Aging at 300-600C

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Nan; Parker, Stephen Scott; Wood, Elizabeth Sooby

Iron-chromium-aluminum (FeCrAl) alloys are of interest to the nuclear materials community due to their resistance to high temperature steam oxidation under accident conditions. The present work investigates oxide formation at temperatures relevant to light water reactor cladding operation following extended aging to assess growth kinetics, chemical composition, and microstructure of oxide formation on a commercial FeCrAl alloy, Fe-21wt.%Cr-5wt.%Al-3wt.%Mo (Kanthal APMT). Aging treatments were performed for 100-1000 hours in stagnant air at 300, 400, 500, and 600 °C, respectively. Oxide growth behavior under the investigated conditions follows a logarithmic time dependence. When the oxidization temperature is 400 °C or below, themore » oxide is amorphous. At 500 °C, isolated crystalline regions start to appear during short period aging time and expand with extended exposures. Crystalline α-Al2O3 oxide film develops at 600 °C and the correlated logarithmic rate constant decreases significantly, indicating enhanced oxidation resistance of the formed oxide film. In addition, Mo segregation at grain boundaries has been observed when the aging temperature exceeds 500 °C. The results of this study can be viewed as an upper bounding result for potential oxide coarsening during reactor operation.« less

Evaluation of current operating standards for chlorine dioxide in disinfection of dump tank and flume for fresh tomatoes.

PubMed

Tomás-Callejas, Alejandro; López-Velasco, Gabriela; Valadez, Angela M; Sbodio, Adrian; Artés-Hernández, Francisco; Danyluk, Michelle D; Suslow, Trevor V

2012-02-01

Standard postharvest unit operations that rely on copious water contact, such as fruit unloading and washing, approach the criteria for a true critical control point in fresh tomato production. Performance data for approved sanitizers that reflect commercial systems are needed to set standards for audit compliance. This study was conducted to evaluate the efficacy of chlorine dioxide (ClO(2)) for water disinfection as an objective assessment of recent industry-adopted standards for dump tank and flume management in fresh tomato packing operations. On-site assessments were conducted during eight temporally distinct shifts in two Florida packinghouses and one California packinghouse. Microbiological analyses of incoming and washed fruit and dump and flume system water were evaluated. Water temperature, pH, turbidity, conductivity, and oxidation-reduction potential (ORP) were monitored. Reduction in populations of mesophilic and coliform bacteria on fruit was not significant, and populations were significantly higher (P < 0.05) after washing. Escherichia coli was near the limit of detection in dump tanks but consistently below the detection limit in flumes. Turbidity and conductivity increased with loads of incoming tomatoes. Water temperature varied during daily operations, but pH and ORP mostly remained constant. The industry standard positive temperature differential of 5.5°C between water and fruit pulp was not maintained in tanks during the full daily operation. ORP values were significantly higher in the flume than in the dump tank. A positive correlation was found between ORP and temperature, and negative correlations were found between ORP and turbidity, total mesophilic bacteria, and coliforms. This study provides in-plant data indicating that ClO(2) can be an effective sanitizer in flume and spray-wash systems, but current operational limitations restrict its performance in dump tanks. Under current conditions, ClO(2) alone is unlikely to allow the fresh tomato industry to meet its microbiological quality goals under typical commercial conditions.

The Impact of Rising Temperatures on Aircraft Takeoff Performance

NASA Astrophysics Data System (ADS)

Coffel, E.; Horton, R. M.; Thompson, T. R.

2017-12-01

Steadily rising mean and extreme temperatures as a result of climate change will likely impact the air transportation system over the coming decades. As air temperatures rise at constant pressure, air density declines, resulting in less lift generation by an aircraft wing at a given airspeed and potentially imposing a weight restriction on departing aircraft. This study presents a general model to project future weight restrictions across a fleet of aircraft with different takeoff weights operating at a variety of airports. We construct performance models for five common commercial aircraft and 19 major airports around the world and use projections of daily temperatures from the CMIP5 model suite under the RCP 4.5 and RCP 8.5 emissions scenarios to calculate required hourly weight restriction. We find that on average, 10-30% of annual flights departing at the time of daily maximum temperature may require some weight restriction below their maximum takeoff weights, with mean restrictions ranging from 0.5 to 4% of total aircraft payload and fuel capacity by mid- to late century. Both mid-sized and large aircraft are affected, and airports with short runways and high tempera- tures, or those at high elevations, will see the largest impacts. Our results suggest that weight restriction may impose a non-trivial cost on airlines and impact aviation operations around the world and that adaptation may be required in aircraft design, airline schedules, and/or runway lengths.

C-H surface diamond field effect transistors for high temperature (400 °C) and high voltage (500 V) operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawarada, H., E-mail: kawarada@waseda.jp; Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555; Kagami Memorial Laboratory for Material Science and Technology, Waseda University, Shinjuku, Tokyo 169-0051

2014-07-07

By forming a highly stable Al{sub 2}O{sub 3} gate oxide on a C-H bonded channel of diamond, high-temperature, and high-voltage metal-oxide-semiconductor field-effect transistor (MOSFET) has been realized. From room temperature to 400 °C (673 K), the variation of maximum drain-current is within 30% at a given gate bias. The maximum breakdown voltage (V{sub B}) of the MOSFET without a field plate is 600 V at a gate-drain distance (L{sub GD}) of 7 μm. We fabricated some MOSFETs for which V{sub B}/L{sub GD} > 100 V/μm. These values are comparable to those of lateral SiC or GaN FETs. The Al{sub 2}O{sub 3} was deposited on the C-Hmore » surface by atomic layer deposition (ALD) at 450 °C using H{sub 2}O as an oxidant. The ALD at relatively high temperature results in stable p-type conduction and FET operation at 400 °C in vacuum. The drain current density and transconductance normalized by the gate width are almost constant from room temperature to 400 °C in vacuum and are about 10 times higher than those of boron-doped diamond FETs.« less

Post-deposition-annealing effect on current conduction in Al2O3 films formed by atomic layer deposition with H2O oxidant

NASA Astrophysics Data System (ADS)

Hiraiwa, Atsushi; Matsumura, Daisuke; Okubo, Satoshi; Kawarada, Hiroshi

2017-02-01

Atomic-layer-deposition (ALD) Al2O3 films are promising as gate insulators of non-Si semiconductor devices. Although they allow relatively small leakage currents just after deposition, ALD Al2O3 films formed at low temperatures are subject to high temperature during fabrication or operation of devices. Therefore, the effect of post-deposition annealing (PDA) on the properties of Al2O3 films is investigated in this study. ALD Al2O3 films formed using H2O oxidant at low temperatures are compacted by PDA, but their mass density and dielectric constant remain approximately unchanged or slightly decrease owing to the desorption of methyl groups contained in the films as impurities. In accordance with these results, the wet etching rate of Al2O3 films is not much reduced by PDA. The conduction current in ALD Al2O3 films formed on Si is reduced by PDA and becomes smaller than that in films formed at the same ALD temperatures as those of PDA. The conduction current for PDA temperatures above 250 °C, however, increases and, accordingly, spoils the merit of low-temperature ALD. Therefore, given that the dielectric constant of annealed films remains low, high-temperature ALD is practically more significant than applying PDA to low-temperature ALD Al2O3 films from the viewpoint of leakage current under the same thermal budget. Space-charge-controlled field emission analysis revealed that, at the aforementioned threshold temperature, PDA abruptly increases the Al2O3/SiO2 interfacial dipoles and simultaneously reduces the amount of the positive charge near the interface. The so-called negative-charge buildup by PDA might be caused by this decrease in the positive charge.

Enhancement of oxygen transfer and nitrogen removal in a membrane separation bioreactor for domestic wastewater treatment.

PubMed

Chiemchaisri, C; Yamamoto, K

2005-01-01

Biological nitrogen removal in a membrane separation bioreactor developed for on-site domestic wastewater treatment was investigated. The bioreactor employed hollow fiber membrane modules for solid-liquid separation so that the biomass could be completely retained within the system. Intermittent aeration was supplied with 90 minutes on and off cycle to achieve nitrification and denitrification reaction for nitrogen removal. High COD and nitrogen removal of more than 90% were achieved under a moderate temperature of 25 degrees C. As the temperature was stepwise decreased from 25 to 5 degrees C, COD removal in the system could be constantly maintained while nitrogen removal was deteriorated. Nevertheless, increasing aeration supply could enhance nitrification at low temperature with benefit from complete retention of nitrifying bacteria within the system by membrane separation. At low operating temperature range of 5 degrees C, nitrogen removal could be recovered to more than 85%. A mathematical model considering diffusion resistance of limiting substrate into the bio-particle is applied to describe nitrogen removal in a membrane separation bioreactor. The simulation suggested that limitation of the oxygen supply was the major cause of inhibition of nitrification during temperature decrease. Nevertheless, increasing aeration could promote oxygen diffusion into the bio-particle. Sufficient oxygen was supplied to the nitrifying bacteria and the nitrification could proceed. In the membrane separation bioreactor, biomass concentration under low temperature operation was allowed to increase by 2-3 times of that of moderate temperature to compensate for the loss of bacterial activities so that the temperature effect was masked.

Effect of ripples on the finite temperature elastic properties of hexagonal boron nitride using strain-fluctuation method

NASA Astrophysics Data System (ADS)

Thomas, Siby; Ajith, K. M.; Valsakumar, M. C.

2017-11-01

This work intents to put forth the results of a classical molecular dynamics study to investigate the temperature dependent elastic constants of monolayer hexagonal boron nitride (h-BN) between 100 and 1000 K for the first time using strain fluctuation method. The temperature dependence of out-of-plane fluctuations (ripples) is quantified and is explained using continuum theory of membranes. At low temperatures, negative in-plane thermal expansion is observed and at high temperatures, a transition to positive thermal expansion has been observed due to the presence of thermally excited ripples. The decrease of Young's modulus, bulk modulus, shear modulus and Poisson's ratio with increase in temperature has been analyzed. The thermal rippling in h-BN leads to strong anharmonic behaviour that causes large deviation from the isotropic elasticity. A detailed study shows that the strong thermal rippling in large systems is also responsible for the softening of elastic constants in h-BN. From the determined values of elastic constants and elastic moduli, it has been elucidated that 2D h-BN sheets meet the Born's mechanical stability criterion in the investigated temperature range. The variation of longitudinal and shear velocities with temperature is also calculated from the computed values of elastic constants and elastic moduli.

Thermal time constant: optimising the skin temperature predictive modelling in lower limb prostheses using Gaussian processes

PubMed Central

Buis, Arjan

2016-01-01

Elevated skin temperature at the body/device interface of lower-limb prostheses is one of the major factors that affect tissue health. The heat dissipation in prosthetic sockets is greatly influenced by the thermal conductive properties of the hard socket and liner material employed. However, monitoring of the interface temperature at skin level in lower-limb prosthesis is notoriously complicated. This is due to the flexible nature of the interface liners used which requires consistent positioning of sensors during donning and doffing. Predicting the residual limb temperature by monitoring the temperature between socket and liner rather than skin and liner could be an important step in alleviating complaints on increased temperature and perspiration in prosthetic sockets. To predict the residual limb temperature, a machine learning algorithm – Gaussian processes is employed, which utilizes the thermal time constant values of commonly used socket and liner materials. This Letter highlights the relevance of thermal time constant of prosthetic materials in Gaussian processes technique which would be useful in addressing the challenge of non-invasively monitoring the residual limb skin temperature. With the introduction of thermal time constant, the model can be optimised and generalised for a given prosthetic setup, thereby making the predictions more reliable. PMID:27695626

Thermal time constant: optimising the skin temperature predictive modelling in lower limb prostheses using Gaussian processes.

PubMed

Mathur, Neha; Glesk, Ivan; Buis, Arjan

2016-06-01

Elevated skin temperature at the body/device interface of lower-limb prostheses is one of the major factors that affect tissue health. The heat dissipation in prosthetic sockets is greatly influenced by the thermal conductive properties of the hard socket and liner material employed. However, monitoring of the interface temperature at skin level in lower-limb prosthesis is notoriously complicated. This is due to the flexible nature of the interface liners used which requires consistent positioning of sensors during donning and doffing. Predicting the residual limb temperature by monitoring the temperature between socket and liner rather than skin and liner could be an important step in alleviating complaints on increased temperature and perspiration in prosthetic sockets. To predict the residual limb temperature, a machine learning algorithm - Gaussian processes is employed, which utilizes the thermal time constant values of commonly used socket and liner materials. This Letter highlights the relevance of thermal time constant of prosthetic materials in Gaussian processes technique which would be useful in addressing the challenge of non-invasively monitoring the residual limb skin temperature. With the introduction of thermal time constant, the model can be optimised and generalised for a given prosthetic setup, thereby making the predictions more reliable.

Impact of cool versus warm temperatures on gestation in the aspic viper (Vipera aspis).

PubMed

Michel, Catherine Louise; Pastore, Jean-Henri; Bonnet, Xavier

2013-07-01

Previous experimental data suggested that digestion and growth rates are not impaired under cool constant temperature (23°C) in a viviparous snake (Vipera aspis). These results challenged the widespread notion that both elevated temperatures (e.g. 30°C) and temperature fluctuations are required for digestion and growth in temperate climate reptiles. Here, we investigated the impact of constant cool temperatures on another physiological performance that is crucial to population persistence: gestation. At the time when reproductive females were midway through vitellogenesis, we placed ten reproductive and two non-reproductive female aspic vipers at each of two contrasted constant temperature conditions: cool (23°C) versus warm (28°C). Sixty percent of the females placed at 28°C gave birth to healthy offspring, suggesting that constant warm body temperatures were compatible with normal offspring production. Conversely, none of the cool females gave birth to healthy offspring. A blister disease affected exclusively cool pregnant females. Apparently, the combination of cool temperatures plus gestation was too challenging for such females. Our results suggest that reproduction is more thermally sensitive than digestion or growth, indeed gestation faltered under moderately cool thermal constraints. This sensitivity could be a crucial factor determining the capacity of this species to colonize different habitats. Copyright © 2013 Elsevier Inc. All rights reserved.

Laser Raman diagnostics in subsonic and supersonic turbulent jet diffusion flames

NASA Technical Reports Server (NTRS)

Cheng, T. S.; Wehrmeyer, J. A.; Pitz, R. W.

1991-01-01

Ultraviolet (UV) spontaneous vibrational Raman scattering combined with laser-induced predissociative fluorescence (LIPF) is developed for temperature and multi-species concentration measurements. Simultaneous measurements of temperature, major species (H2, O2, N2, H2O), and minor species (OH) concentrations are made with a 'single' narrow band KrF excimer laser in subsonic and supersonic lifted turbulent hydrogen-air diffusion flames. The UV Raman system is calibrated with a flat-flame diffusion burner operated at several known equivalence ratios from fuel-lean to fuel-rich. Temperature measurements made by the ratio of Stokes/anti-Stokes signal and by the ideal gas law are compared. The single shot measurement precision for concentration and temperature measurement is 5 to 10 pct. Calibration constants and bandwidth factors are determined from the flat burner measurements and used in a data reduction program to arrive at temperature and species concentration measurements. These simultaneous measurements of temperature and multi-species concentrations allow a better understanding of the complex turbulence-chemistry interactions and provide information for the input and validation of CFD models.

Using the ferroelectric/ferroelastic effect at cryogenic temperatures for set-and-hold actuation

NASA Astrophysics Data System (ADS)

Steeves, J. B.; Golinveaux, F. S.; Lynch, C. S.

2018-06-01

The ferroelectric and ferroelastic properties of lead-zirconate-titanate (PZT) based stack actuators have been characterized at temperatures down to 25 K and under various levels of constant compressive stress. Experiments indicate that the coercive field and magnitude of strain at the coercive field display an inverse relationship with temperature. A factor of 5.5 increase in coercive field, and a factor of 4.3 increase in strain is observed at 25 K in comparison to the room-temperature conditions. This information was used to induce non-180° domain wall motion in the material through the application of electric fields at or near the coercive field. The change in remanent strain accompanying these effects was shown to increase in magnitude as temperature decreased, reaching values of 2000 ppm at 25 K. This behavior was also shown to be temporally stable even under compressive loads. Additionally, it was demonstrated that the material can be returned to its original strain state through a repolarizing electric field. This switchable behavior could be exploited for future set-and-hold type actuators operating at cryogenic temperatures.

Design of a pool boiler heat transport system for a 25 kWe advanced Stirling conversion system

NASA Technical Reports Server (NTRS)

Anderson, W. G.; Rosenfeld, J. H.; Noble, J.; Kesseli, J.

1991-01-01

The overall operating temperature and efficiency of solar-powered Stirling engines can be improved by adding a heat transport system to more uniformly supply heat to the heater head tubes. One heat transport system with favorable characteristics is an alkali metal pool boiler. An alkali metal pool boiler heat transport system was designed for a 25-kW advanced Stirling conversion system (ASCS). Solar energy concentrated on the absorber dome boils a eutectic mixture of sodium and potassium. The alkali metal vapors condense on the heater head tubes, supplying the Stirling engine with a uniform heat flux at a constant temperature. Boiling stability is achieved with the use of an enhanced boiling surface and noncondensible gas.

Smart catheter flow sensor for real-time continuous regional cerebral blood flow monitoring

NASA Astrophysics Data System (ADS)

Li, Chunyan; Wu, Pei-Ming; Hartings, Jed A.; Wu, Zhizhen; Ahn, Chong H.; LeDoux, David; Shutter, Lori A.; Narayan, Raj K.

2011-12-01

We present a smart catheter flow sensor for real-time, continuous, and quantitative measurement of regional cerebral blood flow using in situ temperature and thermal conductivity compensation. The flow sensor operates in a constant-temperature mode and employs a periodic heating and cooling technique. This approach ensures zero drift and provides highly reliable data with microelectromechanical system-based thin film sensors. The developed flow sensor has a sensitivity of 0.973 mV/ml/100 g/min in the range from 0 to 160 ml/100 g/min with a linear correlation coefficient of R2 = 0.9953. It achieves a resolution of 0.25 ml/100 g/min and an accuracy better than 5 ml/100 g/min.

Thermodynamic and transport properties of frozen and reacting pH2-oH2 mixtures

NASA Technical Reports Server (NTRS)

Carter, H. G.; Bullock, R. E.

1972-01-01

Application of experimental state data and spectroscopic term values shows that the thermodynamic and transport properties of reacting pH2-oH2 mixtures are considerably different than those of chemically frozen pH2 at temperatures below 300 R. Calculated H-S data also show that radiation-induced pH2-oH2 equilibration at constant enthalpy produces a temperature drop of at least 28 R, corresponding to an ideal shaft work loss of 15% or more for a turbine operating downstream from the point of conversion. Aside from differences in thermodynamic and transport properties, frozen pH2-oH2 mixtures may differ from pure pH2 on a purely hydrodynamical basis.

Effect of Cold Temperature on the Dielectric Constant of Soil

DTIC Science & Technology

2012-04-01

explosive device (IED) threats is ground-penetrating radar ( GPR ). Proper development of GPR technology for this application requires a unique...success or failure of GPR as a detection technique. One soil property of interest to radar engineers is the dielectric constant. Previous...results to temperatures, moisture levels, and frequencies relevant to GPR systems. 2. Dielectric Constant and the Ring-resonator Concept The two

Wigner functions for fermions in strong magnetic fields

NASA Astrophysics Data System (ADS)

Sheng, Xin-li; Rischke, Dirk H.; Vasak, David; Wang, Qun

2018-02-01

We compute the covariant Wigner function for spin-(1/2) fermions in an arbitrarily strong magnetic field by exactly solving the Dirac equation at non-zero fermion-number and chiral-charge densities. The Landau energy levels as well as a set of orthonormal eigenfunctions are found as solutions of the Dirac equation. With these orthonormal eigenfunctions we construct the fermion field operators and the corresponding Wigner-function operator. The Wigner function is obtained by taking the ensemble average of the Wigner-function operator in global thermodynamical equilibrium, i.e., at constant temperature T and non-zero fermion-number and chiral-charge chemical potentials μ and μ_5, respectively. Extracting the vector and axial-vector components of the Wigner function, we reproduce the currents of the chiral magnetic and separation effect in an arbitrarily strong magnetic field.

Transcriptome analysis of the Bombyx mori fat body after constant high temperature treatment shows differences between the sexes.

PubMed

Wang, Hua; Fang, Yan; Wang, Lipeng; Zhu, Wenjuan; Ji, Haipeng; Wang, Haiying; Xu, Shiqing; Sima, Yanghu

2014-09-01

Ambient temperature plays a large role in insect growth, development and even their distribution. The elucidation of the associated molecular mechanism that underlies the effect of constant high temperature will enables us to further understand the stress responses. We constructed four digital gene expression libraries from the fat body of female and male Bombyx mori. Differential gene expression was analyzed after constant high temperature treatment. The results showed that there were significant changes to the gene expression in the fat body after heat treatment, especially in binding, catalytic, cellular and metabolic processes. Constant high temperature may induce more traditional cryoprotectants, such as glycerol, glycogen, sorbitol and lipids, to protect cells from damage, and induce heat oxidative stress in conjunction with the heat shock proteins. The data also indicated a difference between males and females. The heat shock protein-related genes were up-regulated in both sexes but the expression of Hsp25.4 and DnaJ5 were down-regulated in the male fat body of B. mori. This is the first report of such a result. Constant high temperature also affected the expression of other functional genes and differences were observed between male and female fat bodies in the expression of RPS2, RPL37A and MREL. These findings provide abundant data on the effect of high temperature on insects at the molecular level. The data will also be beneficial to the study of differences between the sexes, manifested in variations in gene expression under high temperature.

High-Temperature Electromechanical Characterization of AlN Single Crystals.

PubMed

Kim, Taeyang; Kim, Jinwook; Dalmau, Rafael; Schlesser, Raoul; Preble, Edward; Jiang, Xiaoning

2015-10-01

Hexagonal AlN is a non-ferroelectric material and does not have any phase transition up to its melting point (>2000°C), which indicates the potential use of AlN for high-temperature sensing. In this work, the elastic, dielectric, and piezoelectric constants of AlN single crystals were investigated at elevated temperatures up to 1000°C by the resonance method. We used resonators of five different modes to obtain a complete set of material constants of AlN single crystals. The electrical resistivity of AlN at elevated temperature (1000°C) was found to be greater than 5 × 10(10) Ω · cm. The resonance frequency of the resonators, which was mainly determined by the elastic compliances, decreased linearly with increasing temperature, and was characterized by a relatively low temperature coefficient of frequency, in the range of -20 to -36 ppm/°C. For all the investigated resonator modes, the elastic constants and the electromechanical coupling factors exhibited excellent temperature stability, with small variations over the full temperature range, <11.2% and <17%, respectively. Of particular significance is that due to the pyroelectricity of AlN, both the dielectric and the piezoelectric constants had high thermal resistivity even at extreme high temperature (1000°C). Therefore, high electrical resistivity, temperature independence of electromechanical properties, as well as high thermal resistivity of the elastic, dielectric, and piezoelectric properties, suggest that AlN single crystals are a promising candidate for high-temperature piezoelectric sensing applications.

Kinetic Analysis of Isothermal Decomposition Process of Sodium Bicarbonate Using the Weibull Probability Function—Estimation of Density Distribution Functions of the Apparent Activation Energies

NASA Astrophysics Data System (ADS)

Janković, Bojan

2009-10-01

The decomposition process of sodium bicarbonate (NaHCO3) has been studied by thermogravimetry in isothermal conditions at four different operating temperatures (380 K, 400 K, 420 K, and 440 K). It was found that the experimental integral and differential conversion curves at the different operating temperatures can be successfully described by the isothermal Weibull distribution function with a unique value of the shape parameter ( β = 1.07). It was also established that the Weibull distribution parameters ( β and η) show independent behavior on the operating temperature. Using the integral and differential (Friedman) isoconversional methods, in the conversion (α) range of 0.20 ≤ α ≤ 0.80, the apparent activation energy ( E a ) value was approximately constant ( E a, int = 95.2 kJmol-1 and E a, diff = 96.6 kJmol-1, respectively). The values of E a calculated by both isoconversional methods are in good agreement with the value of E a evaluated from the Arrhenius equation (94.3 kJmol-1), which was expressed through the scale distribution parameter ( η). The Málek isothermal procedure was used for estimation of the kinetic model for the investigated decomposition process. It was found that the two-parameter Šesták-Berggren (SB) autocatalytic model best describes the NaHCO3 decomposition process with the conversion function f(α) = α0.18(1-α)1.19. It was also concluded that the calculated density distribution functions of the apparent activation energies ( ddfE a ’s) are not dependent on the operating temperature, which exhibit the highly symmetrical behavior (shape factor = 1.00). The obtained isothermal decomposition results were compared with corresponding results of the nonisothermal decomposition process of NaHCO3.

HgCdTe APDs for time-resolved space applications

NASA Astrophysics Data System (ADS)

Rothman, J.; Lasfargues, G.; Delacourt, B.; Dumas, A.; Gibert, F.; Bardoux, A.; Boutillier, M.

2017-12-01

The use of HgCdTe avalanche photodiodes (APDs) for resolving the temporal variation of faint light level signals is analyzed. The analysis is based on the performance characteristics such as the gain, the response time, and dark currents in the APDs, measured as a function of operating temperature and Cd composition, and on recently developed detector demonstrator modules. The choice of Cd composition in the APDs is strongly dependent on the application needs in terms of electrical bandwidth and signal-to-noise ratio. A performance model has been developed and used to predict the performance of the future detector modules for different applications such as high bandwidth and/or deep space free space optical telecommunications and lidar, associated with sensitivities down to single photon level at low operating temperature and close to single-photon operation at bandwidth of 10 GHz at room temperature. The predictions are corroborated by the results obtained on detector modules that have been developed and used in lidar and deep space optical communications. In a first lidar prototype, integrating a 200 µm APD, we obtained a maximum sensitivity of 25 fW/√Hz at T = 190 K operating temperature. The detector has been used for differential absorption lidar estimations of the absorption due to presence of CO2 in the atmosphere. A random error of 3-10% was obtained for the estimation of the optical thickness at a distance of 100-3000 m, for a range resolution of 100 m and using and averaging time of 4 s. The pursuit of this development is pending on the space qualification of the technology. Results from first proton and irradiation tests are reported that shows on a close to constant performance during and after the irradiation and endurance tests.

Performance characteristics of an electric vehicle lead-acid battery pack at elevated temperatures

NASA Technical Reports Server (NTRS)

Chapman, P.

1982-01-01

Discharge testing data electric car battery pack over initial electrolyte temperature variations between 27 and 55 C are presented. The tests were conducted under laboratory conditions and then compared to detailed electric vehicle simulation models. Battery discharge capacity increased with temperature for constant current discharges, and battery energy capacity increased with temperature for constant power discharges. Dynamometer tests of the electric test vehicle showed an increase in range of 25% for the higher electrolyte temperature.

The vibrational dependence of dissociative recombination: Rate constants for N{sub 2}{sup +}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guberman, Steven L., E-mail: slg@sci.org

Dissociative recombination rate constants are reported with electron temperature dependent uncertainties for the lowest 5 vibrational levels of the N{sub 2}{sup +} ground state. The rate constants are determined from ab initio calculations of potential curves, electronic widths, quantum defects, and cross sections. At 100 K electron temperature, the rate constants overlap with the exception of the third vibrational level. At and above 300 K, the rate constants for excited vibrational levels are significantly smaller than that for the ground level. It is shown that any experimentally determined total rate constant at 300 K electron temperature that is smaller thanmore » 2.0 × 10{sup −7} cm{sup 3}/s is likely to be for ions that have a substantially excited vibrational population. Using the vibrational level specific rate constants, the total rate constant is in very good agreement with that for an excited vibrational distribution found in a storage ring experiment. It is also shown that a prior analysis of a laser induced fluorescence experiment is quantitatively flawed due to the need to account for reactions with unknown rate constants. Two prior calculations of the dissociative recombination rate constant are shown to be inconsistent with the cross sections upon which they are based. The rate constants calculated here contribute to the resolution of a 30 year old disagreement between modeled and observed N{sub 2}{sup +} ionospheric densities.« less

Isotope analysis of diamond-surface passivation effect of high-temperature H{sub 2}O-grown atomic layer deposition-Al{sub 2}O{sub 3} films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hiraiwa, Atsushi, E-mail: hiraiwa@aoni.waseda.jp, E-mail: qs4a-hriw@asahi-net.or.jp; Saito, Tatsuya; Matsumura, Daisuke

2015-06-07

The Al{sub 2}O{sub 3} film formed using an atomic layer deposition (ALD) method with trimethylaluminum as Al precursor and H{sub 2}O as oxidant at a high temperature (450 °C) effectively passivates the p-type surface conduction (SC) layer specific to a hydrogen-terminated diamond surface, leading to a successful operation of diamond SC field-effect transistors at 400 °C. In order to investigate this excellent passivation effect, we carried out an isotope analysis using D{sub 2}O instead of H{sub 2}O in the ALD and found that the Al{sub 2}O{sub 3} film formed at a conventional temperature (100 °C) incorporates 50 times more CH{sub 3} groups thanmore » the high-temperature film. This CH{sub 3} is supposed to dissociate from the film when heated afterwards at a higher temperature (550 °C) and causes peeling patterns on the H-terminated surface. The high-temperature film is free from this problem and has the largest mass density and dielectric constant among those investigated in this study. The isotope analysis also unveiled a relatively active H-exchange reaction between the diamond H-termination and H{sub 2}O oxidant during the high-temperature ALD, the SC still being kept intact. This dynamic and yet steady H termination is realized by the suppressed oxidation due to the endothermic reaction with H{sub 2}O. Additionally, we not only observed the kinetic isotope effect in the form of reduced growth rate of D{sub 2}O-oxidant ALD but found that the mass density and dielectric constant of D{sub 2}O-grown Al{sub 2}O{sub 3} films are smaller than those of H{sub 2}O-grown films. This is a new type of isotope effect, which is not caused by the presence of isotopes in the films unlike the traditional isotope effects that originate from the presence of isotopes itself. Hence, the high-temperature ALD is very effective in forming Al{sub 2}O{sub 3} films as a passivation and/or gate-insulation layer of high-temperature-operation diamond SC devices, and the knowledge of the aforementioned new isotope effect will be a basis for further enhancing ALD technologies in general.« less

Charging performance of automotive batteries-An underestimated factor influencing lifetime and reliable battery operation

NASA Astrophysics Data System (ADS)

Sauer, Dirk Uwe; Karden, Eckhard; Fricke, Birger; Blanke, Holger; Thele, Marc; Bohlen, Oliver; Schiffer, Julia; Gerschler, Jochen Bernhard; Kaiser, Rudi

Dynamic charge acceptance and charge acceptance under constant voltage charging conditions are for two reasons essential for lead-acid battery operation: energy efficiency in applications with limited charging time (e.g. PV systems or regenerative braking in vehicles) and avoidance of accelerated ageing due to sulphation. Laboratory tests often use charge regimes which are beneficial for the battery life, but which differ significantly from the operating conditions in the field. Lead-acid batteries in applications with limited charging time and partial-state-of-charge operation are rarely fully charged due to their limited charge acceptance. Therefore, they suffer from sulphation and early capacity loss. However, when appropriate charging strategies are applied most of the lost capacity and thus performance for the user may be recovered. The paper presents several aspects of charging regimes and charge acceptance. Theoretical and experimental investigations show that temperature is the most critical parameter. Full charging within short times can be achieved only at elevated temperatures. A strong dependency of the charge acceptance during charging pulses on the pre-treatment of the battery can be observed, which is not yet fully understood. But these effects have a significant impact on the fuel efficiency of micro-hybrid electric vehicles.

Thermal Management of a Nitrogen Cryogenic Loop Heat Pipe

NASA Astrophysics Data System (ADS)

Gully, Ph.; Yan, T.

2010-04-01

Efficient thermal links are needed to ease the distribution of the cold power in satellites. Loop heat pipes are widely used at room temperature as passive thermal links based on a two-phase flow generated by capillary forces. Transportation of the cold power at cryogenic temperatures requires a specific design. In addition to the main loop, the cryogenic loop heat pipe (CLHP) features a hot reservoir and a secondary loop with a cold reservoir and a secondary evaporator which allows the cool down and the thermal management of the thermal link in normal cold operation. We have studied the influence of a heated cold reservoir and investigated the effect of parasitic heat loads on the performance of a nitrogen CLHP at around 80 K. It is shown that heating of the cold reservoir with a small amount of power (0.1 W) allows controlling the system temperature difference, which can be kept constant at a very low level (1 K) regardless of the transferred cold power (0-10 W). Parasitic heat loads have a significant effect on the thermal resistance, and the power applied on the secondary evaporator has to be increased up to 4 W to get stable operation.

Vibrational characteristics of a superconducting magnetic bearing employed for a prototype polarization modulator

NASA Astrophysics Data System (ADS)

Sakurai, Yuki; Matsumura, Tomotake; Sugai, Hajime; Katayama, Nobuhiko; Ohsaki, Hiroyuki; Terao, Yutaka; Terachi, Yusuke; Kataza, Hirokazu; Utsunomiya, Shin; Yamamoto, Ryo

2017-07-01

We present the vibrational characteristics of a levitating rotor in a superconducting magnetic bearing (SMB) system operating at below 10 K. We develop a polarization modulator that requires a continuously rotating optical element, called half-wave plate (HWP), for a cosmic microwave background polarization experiment. The HWP has to operate at the temperature below 10 K, and thus an SMB provides a smooth rotation of the HWP at the cryogenic temperature of about 10 K with minimal heat dissipation. In order to understand the potential interference to the cosmological observations due to the vibration of the HWP, it is essential to characterize the vibrational properties of the levitating rotor of the SMB. We constructed a prototype model that consists of an SMB with an array of high temperature superconductors, YBCO, and a permanent magnet ring, NdFeB. The rotor position is monitored by a laser displacement gauge, and a cryogenic Hall sensor via the magnetic field. In this presentation, we present the measurement results of the vibration characteristics using our prototype SMB system. We characterize the vibrational properties as the spring constant and the damping, and discuss the projected performance of this technology toward the use in future space missions.

Characterization and Performance of a Kilo-TES Sub-Array for ACTPol

NASA Technical Reports Server (NTRS)

Grace, E. A.; Beall, J.; Cho, H. M.; Devlin, M. J.; Fox, A.; Hilton, G.; Hubmayr, J.; Irwin, K.; Klein, J.; Li, D.;

The Master Equation for Two-Level Accelerated Systems at Finite Temperature

NASA Astrophysics Data System (ADS)

Tomazelli, J. L.; Cunha, R. O.

2016-10-01

In this work, we study the behaviour of two weakly coupled quantum systems, described by a separable density operator; one of them is a single oscillator, representing a microscopic system, while the other is a set of oscillators which perform the role of a reservoir in thermal equilibrium. From the Liouville-Von Neumann equation for the reduced density operator, we devise the master equation that governs the evolution of the microscopic system, incorporating the effects of temperature via Thermofield Dynamics formalism by suitably redefining the vacuum of the macroscopic system. As applications, we initially investigate the behaviour of a Fermi oscillator in the presence of a heat bath consisting of a set of Fermi oscillators and that of an atomic two-level system interacting with a scalar radiation field, considered as a reservoir, by constructing the corresponding master equation which governs the time evolution of both sub-systems at finite temperature. Finally, we calculate the energy variation rates for the atom and the field, as well as the atomic population levels, both in the inertial case and at constant proper acceleration, considering the two-level system as a prototype of an Unruh detector, for admissible couplings of the radiation field.

Flight evaluation of an extended engine life mode on an F-15 airplane

NASA Technical Reports Server (NTRS)

Myers, Lawrence P.; Conners, Timothy R.

1992-01-01

An integrated flight and propulsion control system designed to reduce the rate of engine deterioration was developed and evaluated in flight on the NASA Dryden F-15 research aircraft. The extended engine life mode increases engine pressure ratio while reducing engine airflow to lower the turbine temperature at constant thrust. The engine pressure ratio uptrim is modulated in real time based on airplane maneuver requirements, flight conditions, and engine information. The extended engine life mode logic performed well, significantly reducing turbine operating temperature. Reductions in fan turbine inlet temperature of up to 80 F were obtained at intermediate power and up to 170 F at maximum augmented power with no appreciable loss in thrust. A secondary benefit was the considerable reduction in thrust-specific fuel consumption. The success of the extended engine life mode is one example of the advantages gained from integrating aircraft flight and propulsion control systems.

Disk MHD generator study

NASA Technical Reports Server (NTRS)

Retallick, F. D.

1980-01-01

Directly-fired, separately-fired, and oxygen-augmented MHD power plants incorporating a disk geometry for the MHD generator were studied. The base parameters defined for four near-optimum-performance MHD steam power systems of various types are presented. The finally selected systems consisted of (1) two directly fired cases, one at 1920 K (2996F) preheat and the other at 1650 K (2500 F) preheat, (2) a separately-fired case where the air is preheated to the same level as the higher temperature directly-fired cases, and (3) an oxygen augmented case with the same generator inlet temperature of 2839 (4650F) as the high temperature directly-fired and separately-fired cases. Supersonic Mach numbers at the generator inlet, gas inlet swirl, and constant Hall field operation were specified based on disk generator optimization. System pressures were based on optimization of MHD net power. Supercritical reheat stream plants were used in all cases. Open and closed cycle component costs are summarized and compared.

Fast, temperature-sensitive and clathrin-independent endocytosis at central synapses

PubMed Central

Delvendahl, Igor; Vyleta, Nicholas P.; von Gersdorff, Henrique; Hallermann, Stefan

2016-01-01

The fusion of neurotransmitter-filled vesicles during synaptic transmission is balanced by endocytotic membrane retrieval. Despite extensive research, the speed and mechanisms of synaptic vesicle endocytosis have remained controversial. Here, we establish low-noise time-resolved membrane capacitance measurements that allow monitoring changes in surface membrane area elicited by single action potentials and stronger stimuli with high-temporal resolution at physiological temperature in individual bonafide mature central synapses. We show that single action potentials trigger very rapid endocytosis, retrieving presynaptic membrane with a time constant of 470 ms. This fast endocytosis is independent of clathrin, but mediated by dynamin and actin. In contrast, stronger stimuli evoke a slower mode of endocytosis that is clathrin-, dynamin-, and actin-dependent. Furthermore, the speed of endocytosis is highly temperature-dependent with a Q10 of ~3.5. These results demonstrate that distinct molecular modes of endocytosis with markedly different kinetics operate at central synapses. PMID:27146271

Temperature independent quantum well FET with delta channel doping

NASA Technical Reports Server (NTRS)

Young, P. G.; Mena, R. A.; Alterovitz, S. A.; Schacham, S. E.; Haugland, E. J.

1992-01-01

A temperature independent device is presented which uses a quantum well structure and delta doping within the channel. The device requires a high delta doping concentration within the channel to achieve a constant Hall mobility and carrier concentration across the temperature range 300-1.4 K. Transistors were RF tested using on-wafer probing and a constant G sub max and F sub max were measured over the temperature range 300-70 K.

Blind system identification of two-thermocouple sensor based on cross-relation method.

PubMed

Li, Yanfeng; Zhang, Zhijie; Hao, Xiaojian

2018-03-01

In dynamic temperature measurement, the dynamic characteristics of the sensor affect the accuracy of the measurement results. Thermocouples are widely used for temperature measurement in harsh conditions due to their low cost, robustness, and reliability, but because of the presence of the thermal inertia, there is a dynamic error in the dynamic temperature measurement. In order to eliminate the dynamic error, two-thermocouple sensor was used to measure dynamic gas temperature in constant velocity flow environments in this paper. Blind system identification of two-thermocouple sensor based on a cross-relation method was carried out. Particle swarm optimization algorithm was used to estimate time constants of two thermocouples and compared with the grid based search method. The method was validated on the experimental equipment built by using high temperature furnace, and the input dynamic temperature was reconstructed by using the output data of the thermocouple with small time constant.

Gas identification by dynamic measurements of SnO2 sensors

NASA Astrophysics Data System (ADS)

Vorobioff, Juan; Rodriguez, Daniel; Boselli, Alfredo; Lamagna, Alberto; Rinaldi, Carlos

2011-09-01

It is well know that the use of chambers with the sensors in the e-nose improves the measurements, due to a constant gas flow and the controlled temperature sensors[1]. Normally, the chamber temperature is above room temperature due to the heat generated by the heater of sensors. Also, the chamber takes a long time to reach a stable equilibrium temperature and it depends on enviromental conditions. Besides, the temperature variations modify the humidity producing variations in resistance measurements[2]. In this work using a heater system that controls the temperature of the chamber, the desorption process on SnO2 sensor array was study[3]. Also, it was fitted the data signal sensors using a two exponential decay functions in order to determine the desorbing constant process. These constants were used to classify and identify different alcohols and their concentrations.

Blind system identification of two-thermocouple sensor based on cross-relation method

NASA Astrophysics Data System (ADS)

Li, Yanfeng; Zhang, Zhijie; Hao, Xiaojian

2018-03-01

In dynamic temperature measurement, the dynamic characteristics of the sensor affect the accuracy of the measurement results. Thermocouples are widely used for temperature measurement in harsh conditions due to their low cost, robustness, and reliability, but because of the presence of the thermal inertia, there is a dynamic error in the dynamic temperature measurement. In order to eliminate the dynamic error, two-thermocouple sensor was used to measure dynamic gas temperature in constant velocity flow environments in this paper. Blind system identification of two-thermocouple sensor based on a cross-relation method was carried out. Particle swarm optimization algorithm was used to estimate time constants of two thermocouples and compared with the grid based search method. The method was validated on the experimental equipment built by using high temperature furnace, and the input dynamic temperature was reconstructed by using the output data of the thermocouple with small time constant.

Design of modular control system for grain dryers

NASA Astrophysics Data System (ADS)

He, Gaoqing; Liu, Yanhua; Zu, Yuan

In order to effectively control the temperature of grain drying bin, grain ,air outlet as well as the grain moisture, it designed the control system of 5HCY-35 which is based on MCU to adapt to all grains drying conditions, high drying efficiency, long life usage and less manually. The system includes: the control module of the constant temperature and the temperature difference control in drying bin, the constant temperature control of heating furnace, on-line testing of moisture, variety of grain-circulation speed control and human-computer interaction interface. Spatial curve simulation, which takes moisture as control objectives, controls the constant temperature and the temperature difference in drying bin according to preset parameter by the user or a list to reduce the grains explosive to ensure the seed germination percentage. The system can realize the intelligent control of high efficiency and various drying, the good scalability and the high quality.

Influence of free surface curvature on the Pearson instability in Marangoni convection

NASA Astrophysics Data System (ADS)

Hu, W. R.

The Peason instability in a liquid layer bounded by a plate solid boundary with higher constant temperature and a plane free surface with lower constant temperatures in the microgravity environment has by extensively studied The free surface in the microgravity environment tends to be curved in general as a spherical shape and the plane configuration of free surface is a special case In the present paper a system of liquid layer bounded by a plat solid boundary with higher constant temperature and a curved free surface with lower non-uniform temperature is studied The temperature gradient on the free surface will induce the thermocapillary convection and the onset of Marangoni convection is coupled with the thermocapillary convection The thermocapillary convection induced by the temperature gradient on the curved free surface and its influence on the Marangoni convection are studied in the present paper

Development of Pasteuria penetrans in Meloidogyne javanica females as affected by constantly high vs fluctuating temperature in an in-vivo system.

PubMed

Darban, D A; Gowen, S R; Pembroke, B; Mahar, A N

2005-03-01

Growth room and glasshouse experiment was conducted to investigate the effect of constant and fluctuating temperatures on the development of Pasteuria penetrans a hyperparasite of root-knot nematodes. Tomato plants (Lycopersicon esculentum Mill) were inoculated with Meloidogyne javanica second-stage juveniles attached with endospores of P. penetrans and were grown in growth room at 26-29 degrees C and in glasshouse at 20-32 degrees C. The tomato plants were sampled from the growth room after 600 degree-days based on 17 degrees C/d, accumulating each day above a base temperature of 10 degrees C and from the glasshouse after 36 calendar days. Temperature affected the development of P. penetrans directly. The rate of development at constant temperature in growth room was faster than that in the glasshouse at fluctuating temperatures.

Development of Pasteuria penetrans in Meloidogyne javanica females as affected by constantly high vs fluctuating temperature in an in-vivo system

PubMed Central

Darban, D.A.; Gowen, S.R.; Pembroke, B.; Mahar, A.N.

2005-01-01

Growth room and glasshouse experiment was conducted to investigate the effect of constant and fluctuating temperatures on the development of Pasteuria penetrans a hyperparasite of root-knot nematodes. Tomato plants (Lycopersicon esculentum Mill) were inoculated with Meloidogyne javanica second-stage juveniles attached with endospores of P. penetrans and were grown in growth room at 26–29 °C and in glasshouse at 20–32 °C. The tomato plants were sampled from the growth room after 600 degree-days based on 17 °C/d, accumulating each day above a base temperature of 10 °C and from the glasshouse after 36 calendar days. Temperature affected the development of P. penetrans directly. The rate of development at constant temperature in growth room was faster than that in the glasshouse at fluctuating temperatures. PMID:15682497

Scale/Analytical Analyses of Freezing and Convective Melting with Internal Heat Generation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ali S. Siahpush; John Crepeau; Piyush Sabharwall

2013-07-01

Using a scale/analytical analysis approach, we model phase change (melting) for pure materials which generate constant internal heat generation for small Stefan numbers (approximately one). The analysis considers conduction in the solid phase and natural convection, driven by internal heat generation, in the liquid regime. The model is applied for a constant surface temperature boundary condition where the melting temperature is greater than the surface temperature in a cylindrical geometry. The analysis also consider constant heat flux (in a cylindrical geometry).We show the time scales in which conduction and convection heat transfer dominate.

Non-polarizable force field of water based on the dielectric constant: TIP4P/ε.

PubMed

Fuentes-Azcatl, Raúl; Alejandre, José

2014-02-06

The static dielectric constant at room temperature and the temperature of maximum density are used as target properties to develop, by molecular dynamics simulations, the TIP4P/ε force field of water. The TIP4P parameters are used as a starting point. The key step, to determine simultaneously both properties, is to perform simulations at 240 K where a molecular dipole moment of minimum density is found. The minimum is shifted to larger values of μ as the distance between the oxygen atom and site M, lOM, decreases. First, the parameters that define the dipole moment are adjusted to reproduce the experimental dielectric constant and then the Lennard-Jones parameters are varied to match the temperature of maximum density. The minimum on density at 240 K allows understanding why reported TIP4P models fail to reproduce the temperature of maximum density, the dielectric constant, or both properties. The new model reproduces some of the thermodynamic and transport anomalies of water. Additionally, the dielectric constant, thermodynamics, and dynamical and structural properties at different temperatures and pressures are in excellent agreement with experimental data. The computational cost of the new model is the same as that of the TIP4P.

Electrochemical cell with high discharge/charge rate capability

DOEpatents

Redey, Laszlo

1988-01-01

A fully charged positive electrode composition for an electrochemical cell includes FeS.sub.2 and NiS.sub.2 in about equal molar amounts along with about 2-20 mole percent of the reaction product Li.sub.2 S. Through selection of appropriate electrolyte compositions, high power output or low operating temperatures can be obtained. The cell includes a substantially constant electrode impedance through most of its charge and discharge range. Exceptionally high discharge rates and overcharge protection are obtainable through use of the inventive electrode composition.

High-temperature fiber optic pressure sensor

NASA Technical Reports Server (NTRS)

Berthold, J. W.

1984-01-01

Attention is given to a program to develop fiber optic methods to measure diaphragm deflection. The end application is intended for pressure transducers capable of operating to 540 C. In this paper are reported the results of a laboratory study to characterize the performance of the fiber-optic microbend sensor. The data presented include sensitivity and spring constant. The advantages and limitations of the microbend sensor for static pressure measurement applications are described. A proposed design is presented for a 540 C pressure transducer using the fiber optic microbend sensor.

Developmental times and life table statistics of Aulacorthum solani (Hemiptera: Aphididae) at six constant temperatures, with recommendations on the application of temperature-dependent development models

USDA-ARS?s Scientific Manuscript database

Developmental rates and age-specific life tables were determined for Aulacorthum solani (Kaltenbach) (known as foxglove aphid or glasshouse potato aphid) at 6 constant temperatures feeding on pansy (Viola × wittrockiana) (Gams.). Previously, there were no complete life table studies of this species...

Describing Temperature-Dependent Self-Diffusion Coefficients and Fluidity of 1- and 3-Alcohols with the Compensated Arrhenius Formalism.

PubMed

Fleshman, Allison M; Forsythe, Grant E; Petrowsky, Matt; Frech, Roger

2016-09-22

The location of the hydroxyl group in monohydroxy alcohols greatly affects the temperature dependence of the liquid structure due to hydrogen bonding. Temperature-dependent self-diffusion coefficients, fluidity (the inverse of viscosity), dielectric constant, and density have been measured for several 1-alcohols and 3-alcohols with varying alkyl chain lengths. The data are modeled using the compensated Arrhenius formalism (CAF). The CAF follows a modified transition state theory using an Arrhenius-like expression to describe the transport property, which consists of a Boltzmann factor containing an energy of activation, Ea, and an exponential prefactor containing the temperature-dependent solution dielectric constant, εs(T). Both 1- and 3-alcohols show the Ea of diffusion coefficients (approximately 43 kJ mol(-1)) is higher than the Ea of fluidity (approximately 35 kJ mol(-1)). The temperature dependence of the exponential prefactor in these associated liquids is explained using the dielectric constant and the Kirkwood-Frölich correlation factor, gk. It is argued that the dielectric constant must be used to account for the additional temperature dependence due to variations in the liquid structure (e.g., hydrogen bonding) for the CAF to accurately model the transport property.

Molecular dynamics simulations of thermally activated edge dislocation unpinning from voids in α -Fe

NASA Astrophysics Data System (ADS)

Byggmästar, J.; Granberg, F.; Nordlund, K.

2017-10-01

In this study, thermal unpinning of edge dislocations from voids in α -Fe is investigated by means of molecular dynamics simulations. The activation energy as a function of shear stress and temperature is systematically determined. Simulations with a constant applied stress are compared with dynamic simulations with a constant strain rate. We found that a constant applied stress results in a temperature-dependent activation energy. The temperature dependence is attributed to the elastic softening of iron. If the stress is normalized with the softening of the specific shear modulus, the activation energy is shown to be temperature-independent. From the dynamic simulations, the activation energy as a function of critical shear stress was determined using previously developed methods. The results from the dynamic simulations are in good agreement with the constant stress simulations, after the normalization. This indicates that the computationally more efficient dynamic method can be used to obtain the activation energy as a function of stress and temperature. The obtained relation between stress, temperature, and activation energy can be used to introduce a stochastic unpinning event in larger-scale simulation methods, such as discrete dislocation dynamics.

Fuel Composition Effects at Constant RON and MON in an HCCI Engine Operated with Negative Valve Overlap

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bunting, Bruce G; Farrell, John T

2006-01-01

The effects of fuel properties on gasoline HCCI operation have been investigated in a single cylinder, 500 cc, 11.3 CR port fuel injected research engine, operated at lambda=1 and equipped with hydraulic valve actuation. HCCI is promoted by early exhaust valve closing to retain hot exhaust in the cylinder, thereby increasing the cylinder gas temperature. Test fuels were formulated with pure components to have the same RON, MON, and octane sensitivity as an indolene reference fuel, but with a wide range of fuel composition differences. Experiments have been carried out to determine if fuel composition plays a role in HCCImore » combustion properties, independent of octane numbers. Fuel economy, emissions, and combustion parameters have been measured at several fixed speed/load conditions over a range of exhaust valve closing angles. When the data are compared at constant combustion phasing, fuel effects on emissions and other combustion properties are small. However, when compared at constant exhaust valve closing angle, fuel composition effects are more pronounced, specifically regarding ignition. Operability range differences are also related to fuel composition. An all-paraffinic (normal, iso, and cycloparaffins) fuel exhibited distinctly earlier combustion phasing, increased rate of cylinder pressure rise, and increased rate of maximum heat release compared to the indolene reference fuel. Conversely, olefin-containing fuels exhibited retarded combustion phasing. The fuels with the most advanced ignition showed a wider operating range in terms of engine speed and load, irrespective of exhaust closing angle. These ignition differences reflect contributions from both fuel and EGR kinetics, the effects of which are discussed. The fuel composition variables are somewhat inter-correlated, which makes the experimental separation their effects imprecise with this small set of fuels, though clear trends are evident. The overall effects of fuel composition on engine performance and emissions are small. However, the results suggest that the effects on combustion phasing and engine operability range may need to be considered in the practical implementation of HCCI for fuels with large compositional variations.« less

Development and performance of a laser heterodyne spectrometer using tunable semiconductor lasers as local oscillators

NASA Technical Reports Server (NTRS)

Glenar, D.; Kostiuk, T.; Jennings, D. E.; Mumma, M. J.

1980-01-01

A diode laser based IR heterodyne spectrometer for laboratory and field use was developed for high efficiency operation between 7.5 and 8.5 microns. The local oscillator is a PbSSe tunable diode laser kept continuously at operating temperatures of 12-60 K using a closed cycle cooler. The laser output frequency is controlled and stabilized using a high precision diode current supply, constant temperature controller, and a shock isolator mounted between the refrigerator cold tip and the diode mount. Single laser modes are selected by a grating placed in the local oscillator beam. The system employs reflecting optics throughout to minimize losses from internal reflection and absorption, and to eliminate chromatic effects. Spectral analysis of the diode laser output between 0 and 1 GHz reveals excess noise at many diode current settings, which limits the infrared spectral regions over which useful heterodyne operation can be achieved. System performance has been studied by making heterodyne measurements of etalon fringes and several Freon 13 (CF3Cl) absorption lines against a laboratory blackbody source. Preliminary field tests have also been performed using the Sun as a source.

GaN-based superluminescent diodes with long lifetime

NASA Astrophysics Data System (ADS)

Castiglia, A.; Rossetti, M.; Matuschek, N.; Rezzonico, R.; Duelk, M.; Vélez, C.; Carlin, J.-F.; Grandjean, N.

2016-02-01

We report on the reliability of GaN-based super-luminescent light emitting diodes (SLEDs) emitting at a wavelength of 405 nm. We show that the Mg doping level in the p-type layers has an impact on both the device electro-optical characteristics and their reliability. Optimized doping levels allow decreasing the operating voltage on single-mode devices from more than 6 V to less than 5 V for an injection current of 100 mA. Furthermore, maximum output powers as high as 350 mW (for an injection current of 500 mA) have been achieved in continuous-wave operation (CW) at room temperature. Modules with standard and optimized p-type layers were finally tested in terms of lifetime, at a constant output power of 10 mW, in CW operation and at a case temperature of 25 °C. The modules with non-optimized p-type doping showed a fast and remarkable increase in the drive current during the first hundreds of hours together with an increase of the device series resistance. No degradation of the electrical characteristics was observed over 2000 h on devices with optimized p-type layers. The estimated lifetime for those devices was longer than 5000 h.

Studies of single-mode injection lasers and of quaternary materials. Volume 1: Single-mode constricted double-heterojunction AlGaAs diode lasers

NASA Technical Reports Server (NTRS)

Botez, D.

1982-01-01

Constricted double-heterojunction (CDH) lasers are presented as the class of single-mode nonplanar-substrate devices for which the lasing cavity is on the least resistive electrical path between the contact and the substrate. Various types of CDH structures are considered under three general topics: liquid-phase epitaxy over channeled substrates, lateral mode control, and current control in nonplanar-substrate devices. Ridge-guide CDH lasers have positive-index lateral-mode confinement and provide: single-mode CW operation to 7 mW/facet at room temperature and to 3 mW/facet at 150 C; light-current characteristics with second-harmonic distortion as low as -57 dB below the fundamental level; threshold-current temperature coefficients, as high as 375 C (pulsed) and 310 C (CW); constant external differential quantum efficiency to 100 C; and lasing operation to 170 C CW and 280 C pulsed. Semileakyguide CDH lasers have an asymmetric leaky cavity for lateral-mode confinement and provide single-mode operation to 15 to 20 mW/facet CW and to 50 mW/facet at 50% duty cycle. Modulation characteristics and preliminary reliability data are discussed.

Modeling and optimization of proton-conducting solid oxide electrolysis cell: Conversion of CO2 into value-added products

NASA Astrophysics Data System (ADS)

Namwong, Lawit; Authayanun, Suthida; Saebea, Dang; Patcharavorachot, Yaneeporn; Arpornwichanop, Amornchai

2016-11-01

Proton-conducting solid oxide electrolysis cells (SOEC-H+) are a promising technology that can utilize carbon dioxide to produce syngas. In this work, a detailed electrochemical model was developed to predict the behavior of SOEC-H+ and to prove the assumption that the syngas is produced through a reversible water gas-shift (RWGS) reaction. The simulation results obtained from the model, which took into account all of the cell voltage losses (i.e., ohmic, activation, and concentration losses), were validated using experimental data to evaluate the unknown parameters. The developed model was employed to examine the structural and operational parameters. It is found that the cathode-supported SOEC-H+ is the best configuration because it requires the lowest cell potential. SOEC-H+ operated favorably at high temperatures and low pressures. Furthermore, the simulation results revealed that the optimal S/C molar ratio for syngas production, which can be used for methanol synthesis, is approximately 3.9 (at a constant temperature and pressure). The SOEC-H+ was optimized using a response surface methodology, which was used to determine the optimal operating conditions to minimize the cell potential and maximize the carbon dioxide flow rate.

Effect of different constant incubation temperatures on egg survival and embryonic development in lake whitefish (Coregonus clupeaformis)

USGS Publications Warehouse

Brooke, L.T.

1975-01-01

Eggs of lake whitefish (Coregonus clupeaformis) were incubated in a constant-flow incubator at constant temperatures of 0.5, 2.0, 4.0, 5.9, 7.8, and 10.0 C. The time from fertilization to median hatch was inversely related to temperature, and ranged from 41.7 days at 10.0 C to 182 days at 0.5 C. The percentage hatch was highest (70.9-73.3%) at 4.0, 5.9, and 7.8 C, and was greatly reduced (6.0-28.4%) at 0.5, 2.0, and 10.0 C. The mortality of embryos was greatest during the early stages of development. Abnormally developed fry were most frequent (85.9% of the hatch) at 10.0 C, and least frequent (2.8%) at 4.0 C. Mean lengths of fry at hatching were shorter at 7.8 and 10.0 C (12.4 and 8.8 mm, respectively) than at lower temperatures (13.1 to 13.5 mm). The optimum temperature range for incubation of lake whitefish eggs was 3.2 to 8.1 C. Equations were derived for predicting development time to 20 successive stages, and to hatching, at constant incubation temperatures and at fluctuating daily mean water temperatures.

Microwave dielectric measurements of erythrocyte suspensions.

PubMed Central

Bao, J Z; Davis, C C; Swicord, M L

1994-01-01

Complex dielectric constants of human erythrocyte suspensions over a frequency range from 45 MHz to 26.5 GHz and a temperature range from 5 to 40 degrees C have been determined with the open-ended coaxial probe technique using an automated vector network analyzer (HP 8510). The spectra show two separate major dispersions (beta and gamma) and a much smaller dispersion between them. The two major dispersions are analyzed with a dispersion equation containing two Cole-Cole functions by means of a complex nonlinear least squares technique. The parameters of the equation at different temperatures have been determined. The low frequency behavior of the spectra suggests that the dielectric constant of the cell membrane increases when the temperature is above 35 degrees C. The real part of the dielectric constant at approximately 3.4 GHz remains almost constant when the temperature changes. The dispersion shifts with temperature in the manner of a thermally activated process, and the thermal activation enthalpies for the beta- and gamma-dispersions are 9.87 +/- 0.42 kcal/mol and 4.80 +/- 0.06 kcal/mol, respectively. PMID:8075351

Progress Toward a Compact 0.05 K Magnet Refrigerator Operating from 10 K

NASA Technical Reports Server (NTRS)

Canavan, Edgar; Shirron, Peter; DiPirro, Micheal; Tuttle, James; Jackson, Michael; King, Todd; Numazawa, Takenori

2003-01-01

Much of the most interesting information regarding our universe is hidden in the sub-millimeter, infrared, and x-rays bands of the spectrum, to which our atmosphere is largely opaque. Thus, missions exploring these bands are a very important part of NASA s Space Science program. Coincidentally, the most sensitive detectors in these spectral regions operate at extremely low temperatures, typically 0.05 - 0.10 K. Generally these temperatures will be achieved using magnetic refrigerators, also know as Adiabatic Demagnetization Refrigerators, or ADRs. Current ADRs, such as the one used in the XRS-II instrument on the Astro-E2 satellite, use a single-stage to cool detectors from 1.3 K to 0.06 K. The ADR is designed so that it can absorb the heat on the detector stage for at least 24 hours before it must stop, warm up to the helium bath temperature (1.3 K), and dump the accumulated heat. Future detector arrays will be much larger and will have higher heat dissipation. Furthermore, future missions will use mechanical cryocoolers to provide upper stage cooling, but they can only reach 4 - 10 K. Trying to scale heavy (-15 kg) single stage ADRs up to the higher heat loads and higher heat rejection temperatures required leads to unacceptably large systems. The GSFC Cryogenics Branch has developed the Continuous ADR (CADR) to solve this problem. The CADR consists of a series of ADR stages that sequentially pass heat from the load up to the high temperature heat sink. The stage connected to the load remains at a constant temperature. The continuous stage effectively decouples detector operation from ADR operation, allowing the ADR stages to be cycled much more rapidly. Rapid cycling leads to higher cooling power density. The cascading, multistage arrangement allows the magnetic refrigerant of each stage to be optimized for its own temperature swing. In the past year, we have made good progress toward a 0.05 to 10K system. A four-stage system that operates from 4.2 K was demonstrated. Magnetic shielding was added to eliminate inter-stage coupling. Improvements were made to superconducting and passive gas-gap heat switches. A second type of passive gas gap switch, one meant for use at higher temperature, was demonstrated. The presentation will focus primarily on these recent design improvements, and on the challenges that remain on the progress toward a system that will operate from 10 K or higher.

Polaronic Charge Carrier-Lattice Interactions in Lead Halide Perovskites.

PubMed

Wolf, Christoph; Cho, Himchan; Kim, Young-Hoon; Lee, Tae-Woo

2017-10-09

Almost ten years after the renaissance of the popular perovskite-type semiconductors based on lead salts with the general formula AMX 3 (A=organic or inorganic cation; M=divalent metal; X=halide), many facets of photophysics continue to puzzle researchers. In this Minireview, light is shed on the low mobilities of charge carriers in lead halide perovskites with special focus on the lattice properties at non-zero temperature. The polar and soft lattice leads to pronounced electron-phonon coupling, limiting carrier mobility and retarding recombination. We propose that the proper picture of excited charge carriers at temperature ranges that are relevant for device operations is that of a polaron, with Fröhlich coupling constants between 1<α<3. Under the aspect of light-emitting diode application, APbX 3 perovskite show moderate second order (bimolecular) recombination rates and high third-order (Auger) rate constants. It has become apparent that this is a direct consequence of the anisotropic polar A-site cation in organic-inorganic hybrid perovskites and might be alleviated by replacing the organic moiety with an isotropic cation. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electronic clinical predictive thermometer using logarithm for temperature prediction

NASA Technical Reports Server (NTRS)

Cambridge, Vivien J. (Inventor); Koger, Thomas L. (Inventor); Nail, William L. (Inventor); Diaz, Patrick (Inventor)

1998-01-01

A thermometer that rapidly predicts body temperature based on the temperature signals received from a temperature sensing probe when it comes into contact with the body. The logarithms of the differences between the temperature signals in a selected time frame are determined. A line is fit through the logarithms and the slope of the line is used as a system time constant in predicting the final temperature of the body. The time constant in conjunction with predetermined additional constants are used to compute the predicted temperature. Data quality in the time frame is monitored and if unacceptable, a different time frame of temperature signals is selected for use in prediction. The processor switches to a monitor mode if data quality over a limited number of time frames is unacceptable. Determining the start time on which the measurement time frame for prediction is based is performed by summing the second derivatives of temperature signals over time frames. When the sum of second derivatives in a particular time frame exceeds a threshold, the start time is established.

Time temperature transformation diagram for secondary crystal products of Co-based Co-Fe-B-Si-Nb-Mn soft magnetic nanocomposite

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeGeorge, V., E-mail: vdegeorge@cmu.edu; Zoghlin, E.; Keylin, V.

2015-05-07

Secondary crystallization is the subject of much investigation in magnetic amorphous and nanocomposites (MANCs) as it limits the long term and thermal stability of their operation in device applications, including power electronics, sensors, and electric motors. Secondary crystal products [Blazquez et al., Philos. Mag. Lett. 82(7), 409–417 (2002); Ohodnicki et al., Phys. Rev. B 78, 144414 (2008); Willard et al., Metall. Mater. Trans. A 38, 725 (2007)], nanostructure and crystallization kinetics [Hsiao et al., IEEE Trans. Magn. 38(5), 3039 (2002); McHenry et al., Scr. Mater. 48(7), 881 (2003)], and onset temperatures and activation energies [Ohodnicki et al., Acta. Mater. 57,more » 87 (2009); Long et al., J. Appl. Phys. 101, 09N114 (2007)] at constant heating have been reported for similar alloys. However, a time-temperature-transformation (TTT) diagram for isothermal crystallization, more typical of application environments, has not been reported in literature. Here, a TTT diagram for the Co based, Co-Fe-Si-Nb-B-Mn MANC system is presented, along with a method for determining such. The method accounts for the presence of primary crystal phases and yields crystal fraction of secondary phase(s) by using a novel four stage heating profile. The diagram, affirmed by Kissinger activation energy analysis, reports thermal stability of the MANC for millennia at conventional device operating temperatures, and stability limits less than a minute at elevated temperatures. Both extremes are necessary to be able to avoid secondary crystalline products and establish operating limits for this mechanically attractive, high induction soft magnetic nanocomposite.« less

Estimated Viscosities and Thermal Conductivities of Gases at High Temperatures

NASA Technical Reports Server (NTRS)

Svehla, Roger A.

1962-01-01

Viscosities and thermal conductivities, suitable for heat-transfer calculations, were estimated for about 200 gases in the ground state from 100 to 5000 K and 1-atmosphere pressure. Free radicals were included, but excited states and ions were not. Calculations for the transport coefficients were based upon the Lennard-Jones (12-6) potential for all gases. This potential was selected because: (1) It is one of the most realistic models available and (2) intermolecular force constants can be estimated from physical properties or by other techniques when experimental data are not available; such methods for estimating force constants are not as readily available for other potentials. When experimental viscosity data were available, they were used to obtain the force constants; otherwise the constants were estimated. These constants were then used to calculate both the viscosities and thermal conductivities tabulated in this report. For thermal conductivities of polyatomic gases an Eucken-type correction was made to correct for exchange between internal and translational energies. Though this correction may be rather poor at low temperatures, it becomes more satisfactory with increasing temperature. It was not possible to obtain force constants from experimental thermal conductivity data except for the inert atoms, because most conductivity data are available at low temperatures only (200 to 400 K), the temperature range where the Eucken correction is probably most in error. However, if the same set of force constants is used for both viscosity and thermal conductivity, there is a large degree of cancellation of error when these properties are used in heat-transfer equations such as the Dittus-Boelter equation. It is therefore concluded that the properties tabulated in this report are suitable for heat-transfer calculations of gaseous systems.

Effect of Temperature on the Protonation of the TALSPEAK Ligands: Lactic and Diethylenetrinitropentaacetic Acids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tian, Guoxin; Rao, Linfeng

2009-10-20

The protonation reactions of two ligands that play important roles in the TALSPEAK process for the separation of trivalent actinides from lanthanides, lactic acid and diethylenetrinitropentaacetic acid (DTPA), have been studied at variable temperatures. The protonation constants at 10-70 C were determined by titration potentiometry and the protonation enthalpies were determined at 25 C by titration microcalorimetry. The protonation constants remain essentially unchanged (25-70 C) within the experimental uncertainties, indicating that the effect of temperature on the protonation of lactate is insignificant. In contrast, the protonation constants of DTPA (log {beta}H's) generally decrease as the temperature is increased. Results frommore » this study indicate that the effect of temperature on the protonation of DTPA could alter the speciation of metal ions (actinides and lanthanides) in the TALSPEAK system, since lower values of log{beta}H at higher temperatures suggest that the hydrogen ions would compete less strongly with the metal ions for the complexation of DTPA at higher temperatures.« less

Determination of the Temperature Dependence of Heat Capacity for Some Molecular Crystals of Nitro Compounds

NASA Astrophysics Data System (ADS)

Kovalev, Yu. M.; Kuropatenko, V. F.

2018-05-01

An analysis of the existing approximations used for describing the dependence of heat capacity at a constant volume on the temperature of a molecular crystal has been carried out. It is shown that the considered Debye and Einstein approximations do not enable one to adequately describe the dependence of heat capacity at a constant volume on the temperature of the molecular crystals of nitro compounds. This inference requires the development of special approximations that would describe both low-frequency and high-frequency parts of the vibrational spectra of molecular crystals. This work presents a universal dependence allowing one to describe the dependence of heat capacity at a constant volume on temperature for a number of molecular crystals of nitro compounds.

An equivalent method of mixed dielectric constant in passive microwave/millimeter radiometric measurement

NASA Astrophysics Data System (ADS)

Su, Jinlong; Tian, Yan; Hu, Fei; Gui, Liangqi; Cheng, Yayun; Peng, Xiaohui

2017-10-01

Dielectric constant is an important role to describe the properties of matter. This paper proposes This paper proposes the concept of mixed dielectric constant(MDC) in passive microwave radiometric measurement. In addition, a MDC inversion method is come up, Ratio of Angle-Polarization Difference(RAPD) is utilized in this method. The MDC of several materials are investigated using RAPD. Brightness temperatures(TBs) which calculated by MDC and original dielectric constant are compared. Random errors are added to the simulation to test the robustness of the algorithm. Keywords: Passive detection, microwave/millimeter, radiometric measurement, ratio of angle-polarization difference (RAPD), mixed dielectric constant (MDC), brightness temperatures, remote sensing, target recognition.

Improving the High Temperature Creep and Rupture Resistance of Oxide- Dispersion-Strengthened Alloys

DTIC Science & Technology

1982-04-30

more ready availability and its es - tablished high temperature data base. When work was formally initiated, an order was placed for a billet of...between the specimen heads and grips. -. The test apparatus used to perform the tensile tests was an Instron- Satec furnace combination, Temperature...12,000 lb. capacity) modified to produce constant stress rather than constant load. The furnaces were of the Satec tube-type, with a maximum temperature

Bioclimatic Thresholds, Thermal Constants and Survival of Mealybug, Phenacoccus solenopsis (Hemiptera: Pseudococcidae) in Response to Constant Temperatures on Hibiscus

PubMed Central

Sreedevi, Gudapati; Prasad, Yenumula Gerard; Prabhakar, Mathyam; Rao, Gubbala Ramachandra; Vennila, Sengottaiyan; Venkateswarlu, Bandi

2013-01-01

Temperature-driven development and survival rates of the mealybug, Phenacoccussolenopsis Tinsley (Hemiptera: Pseudococcidae) were examined at nine constant temperatures (15, 20, 25, 27, 30, 32, 35 and 40°C) on hibiscus ( Hibiscus rosa -sinensis L.). Crawlers successfully completed development to adult stage between 15 and 35°C, although their survival was affected at low temperatures. Two linear and four nonlinear models were fitted to describe developmental rates of P . solenopsis as a function of temperature, and for estimating thermal constants and bioclimatic thresholds (lower, optimum and upper temperature thresholds for development: Tmin, Topt and Tmax, respectively). Estimated thresholds between the two linear models were statistically similar. Ikemoto and Takai’s linear model permitted testing the equivalence of lower developmental thresholds for life stages of P . solenopsis reared on two hosts, hibiscus and cotton. Thermal constants required for completion of cumulative development of female and male nymphs and for the whole generation were significantly lower on hibiscus (222.2, 237.0, 308.6 degree-days, respectively) compared to cotton. Three nonlinear models performed better in describing the developmental rate for immature instars and cumulative life stages of female and male and for generation based on goodness-of-fit criteria. The simplified β type distribution function estimated Topt values closer to the observed maximum rates. Thermodynamic SSI model indicated no significant differences in the intrinsic optimum temperature estimates for different geographical populations of P . solenopsis . The estimated bioclimatic thresholds and the observed survival rates of P . solenopsis indicate the species to be high-temperature adaptive, and explained the field abundance of P . solenopsis on its host plants. PMID:24086597

Composite polymer membranes for proton exchange membrane fuel cells operating at elevated temperatures and reduced humidities

NASA Astrophysics Data System (ADS)

Zhang, Tao

Proton Exchange Membrane Fuel Cells (PEMFCs) are the leading candidate in the fuel cell technology due to the high power density, solid electrolyte, and low operational temperature. However, PEMFCs operating in the normal temperature range (60-80°C) face problems including poor carbon monoxide tolerance and heat rejection. The poisoning effect can be significantly relieved by operating the fuel cell at elevated temperature, which also improves the heat rejection and electrochemical kinetics. Low relative humidity (RH) operation is also desirable to simplify the reactant humidification system. However, at elevated temperatures, reduced RH PEMFC performance is seriously impaired due to irreversible water loss from presently employed state-of-the-art polymer membrane, Nafion. This thesis focuses on developing polymer electrolyte membranes with high water retention ability for operation in elevated temperature (110-150°C), reduced humidity (˜50%RH) PEMFCs. One approach is to alter Nafion by adding inorganic particles such as TiO2, SiO2, Zr(HPO 4)2, etc. While the presence of these materials in Nafion has proven beneficial, a reduction or no improvement in the PEMFC performance of Nafion/TiO2 and Nafion/Zr(HPO4)2 membranes is observed with reduced particle sizes or increased particle loadings in Nafion. It is concluded that the PEMFC performance enhancement associated with addition of these inorganic particles was not due to the particle hydrophilicity. Rather, the particle, partially located in the hydrophobic region of the membrane, benefits the cell performance by altering the membrane structure. Water transport properties of some Nafion composite membranes were investigated by NMR methods including pulsed field gradient spin echo diffusion, spin-lattice relaxation, and spectral measurements. Compared to unmodified Nafion, composite membranes materials exhibit longer longitudinal relaxation time constant T1. In addition to the Nafion material, sulfonated styrene-ethylene/butylene-styrene triblock copolymer (sSEBS) was investigated as an alternate membrane candidate. sSEBS was modified through introduction of polymer crosslinks using benzephenone as a photoinitiator and addition of a titania co-phase. A photocrosslinked membrane initially containing 15% benzophenone and 3% titania laminated with a 10 mum Nafion layer was found to produce the best PEMFC performance (120°C, 50%RH).

Numerical Study on Natural Vacuum Solar Desalination System with Varying Heat Source Temperature

NASA Astrophysics Data System (ADS)

Ambarita, H.

2017-03-01

A natural vacuum desalination unit with varying low grade heat source temperature is investigated numerically. The objective is to explore the effects of the variable temperature of the low grade heat source on performances and characteristics of the desalination unit. The specifications of the desalination unit are naturally vacuumed with surface area of seawater in evaporator and heating coil are 0.2 m2 and 0.188 m2, respectively. Temperature of the heating coil is simulated based on the solar radiation in the Medan city. A program to solve the governing equations in forward time step marching technique is developed. Temperature of the evaporator, fresh water production rate, and thermal efficiency of the desalination unit are analysed. Simulation is performed for 9 hours, it starts from 8.00 and finishes at 17.00 of local time. The results show that, the desalination unit with operation time of 9 hours can produce 5.705 L of freshwater and thermal efficiency is 81.8 %. This reveals that varying temperature of the heat source of natural vacuum desalination unit shows better performance in comparison with constant temperature of the heat source.

Radiometric Thermometry for Wearable Deep Tissue Monitoring

NASA Astrophysics Data System (ADS)

Momenroodaki, Parisa

Microwave thermometry is an attractive non-invasive method for measuring internal body temperature. This approach has the potential of enabling a wearable device that can continuously monitor core body temperature. There are a number of health-related applications in both diagnostics and therapy, which can benefit from the knowledge of core body temperature. However,there are a limited number of device solutions, which are usually not wearable or cannot continuously monitor internal body temperature non-invasively. In this thesis, a possible path toward implementing such a thermometer is presented. The device operates in the "quiet" frequency band of 1.4 GHz which is chosen as a compromise between sensing depth and radio frequency interference (RFI). A major challenge in microwave thermometry is detecting small temperature variations of deep tissue layers from surface (skin) measurements. The type and thickness of tissue materials significantly affect the design of the probe, which has the function of receiving black-body radiation from tissues beneath it and coupling the power to a sensitive radiometric receiver. High dielectric constant contrast between skin, fat (/bone), and muscle layers suggests structures with dominant tangential component of the electric field, such as a patch or slot. Adding a layer of low-loss,low-dielectric constant superstrate can further reduce the contribution of superficial tissue layers in the received thermal noise. Several probe types are designed using a full-wave electromagnetic simulator, with a goal of maximizing the power reception from deep tissue layers. The designs are validated with a second software tool and various measurements. A stable, narrow-band, and highly sensitive radiometer is developed, enabling the device to operate in a non-shielded RF environment.To use the microwave thermometer in a RF congested environment, not only narrow-band probe and radiometers are used but an additional probe is introduced for observing the environmental interference. By applying an adaptive filter, the effect of RFI is mitigated in long-term measurements. Several solid and liquid tissue phantoms, required for accurate modeling of the probe and human body interaction, are also developed. The concept of human body microwave thermometry is validated through several measurements on the single-layer and multiple-layer tissue phantoms as well as on the surface of the human body, specifically on the cheek where the internal temperature can easily be changed and independently measured with a thermocouple. Measurement results prove the capability of the device in tracking the temperature of buried tissue layer phantoms to within 0.2K, as well as monitoring internal human body temperature.

Corrosion Resistant FBG-Based Quasi-Distributed Sensor for Crude Oil Tank Dynamic Temperature Profile Monitoring

PubMed Central

da Silva Marques, Rogério; Prado, Adilson Ribeiro; da Costa Antunes, Paulo Fernando; de Brito André, Paulo Sérgio; Ribeiro, Moisés R. N.; Frizera-Neto, Anselmo; Pontes, Maria José

2015-01-01

This article presents a corrosion resistant, maneuverable, and intrinsically safe fiber Bragg grating (FBG)-based temperature optical sensor. Temperature monitoring is a critical activity for the oil and gas industry. It typically involves acquiring the desired parameters in a hazardous and corrosive environment. The use of polytetrafluoroethylene (PTFE) was proposed as a means of simultaneously isolating the optical fiber from the corrosive environment and avoiding undesirable mechanical tensions on the FBGs. The presented sensor head is based on multiple FBGs inscribed in a lengthy single mode fiber. The sensor presents an average thermal sensitivity of 8.82 ± 0.09 pm/°C, resulting in a typical temperature resolution of ~0.1 °C and an average time constant value of 6.25 ± 0.08 s. Corrosion and degradation resistance were verified by infrared spectroscopy and scanning electron microscopy during 90 days exposure to high salinity crude oil samples. The developed sensor was tested in a field pilot test, mimicking the operation of an inland crude tank, demonstrating its abilities to dynamically monitor temperature profile. PMID:26690166

Corrosion Resistant FBG-Based Quasi-Distributed Sensor for Crude Oil Tank Dynamic Temperature Profile Monitoring.

PubMed

Marques, Rogério da Silva; Prado, Adilson Ribeiro; Antunes, Paulo Fernando da Costa; André, Paulo Sérgio de Brito; Ribeiro, Moisés R N; Frizera-Neto, Anselmo; Pontes, Maria José

2015-12-05

This article presents a corrosion resistant, maneuverable, and intrinsically safe fiber Bragg grating (FBG)-based temperature optical sensor. Temperature monitoring is a critical activity for the oil and gas industry. It typically involves acquiring the desired parameters in a hazardous and corrosive environment. The use of polytetrafluoroethylene (PTFE) was proposed as a means of simultaneously isolating the optical fiber from the corrosive environment and avoiding undesirable mechanical tensions on the FBGs. The presented sensor head is based on multiple FBGs inscribed in a lengthy single mode fiber. The sensor presents an average thermal sensitivity of 8.82 ± 0.09 pm/°C, resulting in a typical temperature resolution of ~0.1 °C and an average time constant value of 6.25 ± 0.08 s. Corrosion and degradation resistance were verified by infrared spectroscopy and scanning electron microscopy during 90 days exposure to high salinity crude oil samples. The developed sensor was tested in a field pilot test, mimicking the operation of an inland crude tank, demonstrating its abilities to dynamically monitor temperature profile.

Temperature Prediction in High Speed Bone Grinding using Motor PWM Signal

PubMed Central

Tai, Bruce L.; Zhang, Lihui; Wang, Anthony C.; Sullivan, Stephen; Wang, Guangjun; Shih, Albert J.

2013-01-01

This research explores the feasibility of using motor electrical feedback to estimate temperature rise during a surgical bone grinding procedure. High-speed bone grinding is often used during skull base neurosurgery to remove cranial bone and approach skull base tumors through the nasal corridor. Grinding-induced heat could propagate and potentially injure surrounding nerves and arteries, and therefore, predicting the temperature in the grinding region would benefit neurosurgeons during the operation. High-speed electric motors are controlled by pulse-width-modulation (PWM) to alter the current input and thus maintain the rotational speed. Assuming full mechanical to thermal power conversion in the grinding process, PWM can be used as feedback for heat generation and temperature prediction. In this study, the conversion model was established from experiments under a variety of grinding conditions and an inverse heat transfer method to determine heat flux. Given a constant rotational speed, the heat conversion was represented by a linear function, and could predict temperature from the experimental data with less than 20% errors. Such results support the advance of this technology for practical application. PMID:23806419

Electronic polarizability of light crude oil from optical and dielectric studies

NASA Astrophysics Data System (ADS)

George, A. K.; Singh, R. N.

2017-07-01

In the present paper we report the temperature dependence of density, refractive indices and dielectric constant of three samples of crude oils. The API gravity number estimated from the temperature dependent density studies revealed that the three samples fall in the category of light oil. The measured data of refractive index and the density are used to evaluate the polarizability of these fluids. Molar refractive index and the molar volume are evaluated through Lorentz-Lorenz equation. The function of the refractive index, FRI , divided by the mass density ρ, is a constant approximately equal to one-third and is invariant with temperature for all the samples. The measured values of the dielectric constant decrease linearly with increasing temperature for all the samples. The dielectric constant estimated from the refractive index measurements using Lorentz-Lorentz equation agrees well with the measured values. The results are promising since all the three measured properties complement each other and offer a simple and reliable method for estimating crude oil properties, in the absence of sufficient data.

Rate constant for the fraction of atomic chlorine with formaldehyde from 200 to 500K

NASA Technical Reports Server (NTRS)

Michael, J. V.; Nava, D. F.; Payne, W. A.; Stief, L. J.

1978-01-01

A flash photolysis - resonance fluorescence technique was used to measure rate constant. The results were independent of substantial variations in H2CO, total pressure (Ar), and flash intensity (i.e., initial Cl). The rate constant was shown to be invariant with temperature, the best representation for this temperature range being K = (7.48 + or - 0.50) x 10 to the minus 11 power cu cm molecule-1 s-1 where the error is one standard deviation. The rate constant is theoretically discussed and the potential importance of the reaction in stratospheric chemistry is considered.

Method and apparatus for providing a precise amount of gas at a precise humidity

DOEpatents

Hallman, Jr., Russell L.; Truett, James C.

2001-02-06

A fluid transfer system includes a permeable fluid carrier, a constant temperature source of a first fluid, and a constant pressure source of a second fluid. The fluid carrier has a length, an inlet end, and an outlet end. The constant pressure source connects to the inlet end and communicates the second fluid into the fluid carrier, and the constant temperature source surrounds a least of portion of the length. A mixture of the first fluid and the second fluid exits via the outlet end A method of making a mixture of two fluids is also disclosed.

Implications of possible interpretations of ‘greenhouse gas balance’ in the Paris Agreement

PubMed Central

Millar, R. J.; Allen, M.; Boucher, O.; Cain, M.; Forster, P. M.; Shindell, D.

2018-01-01

The main goal of the Paris Agreement as stated in Article 2 is ‘holding the increase in the global average temperature to well below 2°C above pre-industrial levels and pursuing efforts to limit the temperature increase to 1.5°C’. Article 4 points to this long-term goal and the need to achieve ‘balance between anthropogenic emissions by sources and removals by sinks of greenhouse gases'. This statement on ‘greenhouse gas balance’ is subject to interpretation, and clarifications are needed to make it operational for national and international climate policies. We study possible interpretations from a scientific perspective and analyse their climatic implications. We clarify how the implications for individual gases depend on the metrics used to relate them. We show that the way in which balance is interpreted, achieved and maintained influences temperature outcomes. Achieving and maintaining net-zero CO2-equivalent emissions conventionally calculated using GWP100 (100-year global warming potential) and including substantial positive contributions from short-lived climate-forcing agents such as methane would result in a sustained decline in global temperature. A modified approach to the use of GWP100 (that equates constant emissions of short-lived climate forcers with zero sustained emission of CO2) results in global temperatures remaining approximately constant once net-zero CO2-equivalent emissions are achieved and maintained. Our paper provides policymakers with an overview of issues and choices that are important to determine which approach is most appropriate in the context of the Paris Agreement. This article is part of the theme issue ‘The Paris Agreement: understanding the physical and social challenges for a warming world of 1.5°C above pre-industrial levels'. PMID:29610378

Implications of possible interpretations of 'greenhouse gas balance' in the Paris Agreement.

PubMed

Fuglestvedt, J; Rogelj, J; Millar, R J; Allen, M; Boucher, O; Cain, M; Forster, P M; Kriegler, E; Shindell, D

2018-05-13

The main goal of the Paris Agreement as stated in Article 2 is 'holding the increase in the global average temperature to well below 2°C above pre-industrial levels and pursuing efforts to limit the temperature increase to 1.5°C'. Article 4 points to this long-term goal and the need to achieve 'balance between anthropogenic emissions by sources and removals by sinks of greenhouse gases'. This statement on 'greenhouse gas balance' is subject to interpretation, and clarifications are needed to make it operational for national and international climate policies. We study possible interpretations from a scientific perspective and analyse their climatic implications. We clarify how the implications for individual gases depend on the metrics used to relate them. We show that the way in which balance is interpreted, achieved and maintained influences temperature outcomes. Achieving and maintaining net-zero CO 2 -equivalent emissions conventionally calculated using GWP 100 (100-year global warming potential) and including substantial positive contributions from short-lived climate-forcing agents such as methane would result in a sustained decline in global temperature. A modified approach to the use of GWP 100 (that equates constant emissions of short-lived climate forcers with zero sustained emission of CO 2 ) results in global temperatures remaining approximately constant once net-zero CO 2 -equivalent emissions are achieved and maintained. Our paper provides policymakers with an overview of issues and choices that are important to determine which approach is most appropriate in the context of the Paris Agreement.This article is part of the theme issue 'The Paris Agreement: understanding the physical and social challenges for a warming world of 1.5°C above pre-industrial levels'. © 2018 The Authors.

Atmospheric leakage and condensate production in NASA's biomass production chamber. Effect of diurnal temperature cycles

NASA Technical Reports Server (NTRS)

Wheeler, Raymond M.; Drese, John H.; Sager, John C.

1991-01-01

A series of tests were conducted to monitor atmospheric leakage rate and condensate production in NASA's Biomass Production Chamber (BPC). Water was circulated through the 64 plant culture trays inside the chamber during the tests but no plants were present. Environmental conditions were set to a 12-hr photoperiod with either a matching 26 C (light)/20 C (dark) thermoperiod, or a constant 23 C temperature. Leakage, as determined by carbon dioxide decay rates, averaged about 9.8 percent for the 26 C/20 C regime and 7.3 percent for the constant 23 C regime. Increasing the temperature from 20 C to 26 C caused a temporary increase in pressure (up to 0.5 kPa) relative to ambient, while decreasing the temperature caused a temporary decrease in pressure of similar magnitude. Little pressure change was observed during transition between 23 C (light) and 23 C (dark). The lack of large pressure events under isothermal conditions may explain the lower leakage rate observed. When only the plant support inserts were placed in the culture trays, condensate production averaged about 37 liters per day. Placing acrylic germination covers over the tops of culture trays reduced condensate production to about 7 liters per day. During both tests, condensate production from the lower air handling system was 60 to 70 percent greater than from the upper system, suggesting imbalances exist in chilled and hot water flows for the two air handling systems. Results indicate that atmospheric leakage rates are sufficiently low to measure CO2 exchange rates by plants and the accumulation of certain volatile contaminants (e.g., ethylene). Control system changes are recommended in order to balance operational differences (e.g., humidity and temperature) between the two halves of the chamber.

Implications of possible interpretations of `greenhouse gas balance' in the Paris Agreement

NASA Astrophysics Data System (ADS)

Fuglestvedt, J.; Rogelj, J.; Millar, R. J.; Allen, M.; Boucher, O.; Cain, M.; Forster, P. M.; Kriegler, E.; Shindell, D.

2018-05-01

The main goal of the Paris Agreement as stated in Article 2 is `holding the increase in the global average temperature to well below 2°C above pre-industrial levels and pursuing efforts to limit the temperature increase to 1.5°C'. Article 4 points to this long-term goal and the need to achieve `balance between anthropogenic emissions by sources and removals by sinks of greenhouse gases'. This statement on `greenhouse gas balance' is subject to interpretation, and clarifications are needed to make it operational for national and international climate policies. We study possible interpretations from a scientific perspective and analyse their climatic implications. We clarify how the implications for individual gases depend on the metrics used to relate them. We show that the way in which balance is interpreted, achieved and maintained influences temperature outcomes. Achieving and maintaining net-zero CO2-equivalent emissions conventionally calculated using GWP100 (100-year global warming potential) and including substantial positive contributions from short-lived climate-forcing agents such as methane would result in a sustained decline in global temperature. A modified approach to the use of GWP100 (that equates constant emissions of short-lived climate forcers with zero sustained emission of CO2) results in global temperatures remaining approximately constant once net-zero CO2-equivalent emissions are achieved and maintained. Our paper provides policymakers with an overview of issues and choices that are important to determine which approach is most appropriate in the context of the Paris Agreement. This article is part of the theme issue `The Paris Agreement: understanding the physical and social challenges for a warming world of 1.5°C above pre-industrial levels'.

Simulation of light-induced degradation of μc-Si in a-Si/μc-Si tandem solar cells by the diode equivalent circuit

NASA Astrophysics Data System (ADS)

Weicht, J. A.; Hamelmann, F. U.; Behrens, G.

2016-02-01

Silicon-based thin film tandem solar cells consist of one amorphous (a-Si) and one microcrystalline (μc-Si) silicon solar cell. The Staebler - Wronski effect describes the light- induced degradation and temperature-dependent healing of defects of silicon-based solar thin film cells. The solar cell degradation depends strongly on operation temperature. Until now, only the light-induced degradation (LID) of the amorphous layer was examined in a-Si/μc-Si solar cells. The LID is also observed in pc-Si single function solar cells. In our work we show the influence of the light-induced degradation of the μc-Si layer on the diode equivalent circuit. The current-voltage-curves (I-V-curves) for the initial state of a-Si/pc-Si modules are measured. Afterwards the cells are degraded under controlled conditions at constant temperature and constant irradiation. At fixed times the modules are measured at standard test conditions (STC) (AM1.5, 25°C cell temperature, 1000 W/m2) for controlling the status of LID. After the degradation the modules are annealed at dark conditions for several hours at 120°C. After the annealing the dangling bonds in the amorphous layer are healed, while the degradation of the pc-Si is still present, because the healing of defects in pc-Si solar cells needs longer time or higher temperatures. The solar cells are measured again at STC. With this laboratory measured I-V-curves we are able to separate the values of the diode model: series Rs and parallel resistance Rp, saturation current Is and diode factor n.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sen, Ramazan Sonat; Hummel, Andrew John; Hiruta, Hikaru

The deterministic full core simulators require homogenized group constants covering the operating and transient conditions over the entire lifetime. Traditionally, the homogenized group constants are generated using lattice physics code over an assembly or block in the case of prismatic high temperature reactors (HTR). For the case of strong absorbers that causes strong local depressions on the flux profile require special techniques during homogenization over a large volume. Fuel blocks with burnable poisons or control rod blocks are example of such cases. Over past several decades, there have been a tremendous number of studies performed for improving the accuracy ofmore » full-core calculations through the homogenization procedure. However, those studies were mostly performed for light water reactor (LWR) analyses, thus, may not be directly applicable to advanced thermal reactors such as HTRs. This report presents the application of SuPer-Homogenization correction method to a hypothetical HTR core.« less

Thermodynamic Modeling and Optimization of the Copper Flash Converting Process Using the Equilibrium Constant Method

NASA Astrophysics Data System (ADS)

Li, Ming-zhou; Zhou, Jie-min; Tong, Chang-ren; Zhang, Wen-hai; Chen, Zhuo; Wang, Jin-liang

2018-05-01

Based on the principle of multiphase equilibrium, a mathematical model of the copper flash converting process was established by the equilibrium constant method, and a computational system was developed with the use of MetCal software platform. The mathematical model was validated by comparing simulated outputs, industrial data, and published data. To obtain high-quality blister copper, a low copper content in slag, and increased impurity removal rate, the model was then applied to investigate the effects of the operational parameters [oxygen/feed ratio (R OF), flux rate (R F), and converting temperature (T)] on the product weights, compositions, and the distribution behaviors of impurity elements. The optimized results showed that R OF, R F, and T should be controlled at approximately 156 Nm3/t, within 3.0 pct, and at approximately 1523 K (1250 °C), respectively.

Potential of solar-simulator-pumped alexandrite lasers

NASA Technical Reports Server (NTRS)

Deyoung, Russell J.

1990-01-01

An attempt was made to pump an alexandrite laser rod using a Tamarak solar simulator and also a tungsten-halogen lamp. A very low optical laser cavity was used to achieve the threshold minimum pumping-power requirement. Lasing was not achieved. The laser threshold optical-power requirement was calculated to be approximately 626 W/sq cm for a gain length of 7.6 cm, whereas the Tamarak simulator produces 1150 W/sq cm over a gain length of 3.3 cm, which is less than the 1442 W/sq cm required to reach laser threshold. The rod was optically pulsed with 200 msec pulses, which allowed the alexandrite rod to operate at near room temperature. The optical intensity-gain-length product to achieve laser threshold should be approximately 35,244 solar constants-cm. In the present setup, this product was 28,111 solar constants-cm.

The NICMOS Cooling SYSTEM-5 Years of Successful On-Orbit Operation

NASA Astrophysics Data System (ADS)

Swift, W. L.; Dolan, F. X.; Zagarola, M. V.

2008-03-01

The NICMOS Cooling System consists of a closed-loop turbo-Brayton cryocooler coupled with a cryogenic circulator that provides refrigeration to the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) on the Hubble Space Telescope (HST). The cryocooler heat is rejected to space through a capillary pumped loop connected to radiators mounted on the side of the telescope. The system was deployed and integrated with NICMOS by astronauts during STS-109 (Space Shuttle Columbia) in March 2002. It has operated nearly continuously without performance degradation since that time, maintaining NICMOS detectors at a constant temperature of 77 K. Miniature, high-speed turbomachines are used in the cryocooler and the circulator loop to provide vibration-free, long-life operation. A small centrifugal compressor and miniature turboalternator are key elements of the closed loop cryocooler. A miniature cryogenic centrifugal circulator in a separate pressurized neon loop transports heat from the NICMOS instrument to the cryocooler interface heat exchanger. This paper describes the development of the system, key operational features, ground and orbital tests prior to its deployment, and operational results during its five-year operational history on orbit.

A fast and low-power microelectromechanical system-based non-volatile memory device

PubMed Central

Lee, Sang Wook; Park, Seung Joo; Campbell, Eleanor E. B.; Park, Yung Woo

2011-01-01

Several new generation memory devices have been developed to overcome the low performance of conventional silicon-based flash memory. In this study, we demonstrate a novel non-volatile memory design based on the electromechanical motion of a cantilever to provide fast charging and discharging of a floating-gate electrode. The operation is demonstrated by using an electromechanical metal cantilever to charge a floating gate that controls the charge transport through a carbon nanotube field-effect transistor. The set and reset currents are unchanged after more than 11 h constant operation. Over 500 repeated programming and erasing cycles were demonstrated under atmospheric conditions at room temperature without degradation. Multinary bit programming can be achieved by varying the voltage on the cantilever. The operation speed of the device is faster than a conventional flash memory and the power consumption is lower than other memory devices. PMID:21364559

Experimental simulation of latent heat thermal energy storage and heat pipe thermal transport for dish concentrator solar receiver

NASA Technical Reports Server (NTRS)

Narayanan, R.; Zimmerman, W. F.; Poon, P. T. Y.

1981-01-01

Test results on a modular simulation of the thermal transport and heat storage characteristics of a heat pipe solar receiver (HPSR) with thermal energy storage (TES) are presented. The HPSR features a 15-25 kWe Stirling engine power conversion system at the focal point of a parabolic dish concentrator operating at 827 C. The system collects and retrieves solar heat with sodium pipes and stores the heat in NaF-MgF2 latent heat storage material. The trials were run with a single full scale heat pipe, three full scale TES containers, and an air-cooled heat extraction coil to replace the Stirling engine heat exchanger. Charging and discharging, constant temperature operation, mixed mode operation, thermal inertial, etc. were studied. The heat pipe performance was verified, as were the thermal energy storage and discharge rates and isothermal discharges.

The effect of temperature on development of Sarconesia chlorogaster, a blowfly of forensic importance.

PubMed

Lecheta, Melise Cristine; Thyssen, Patricia Jacqueline; Moura, Mauricio Osvaldo

2015-12-01

The blowfly Sarconesia chlorogaster (Diptera: Calliphoridae) is of limited forensic use in South America, due to the poorly known relationship between development time and temperature. The purpose of this study was to determine development time of S. chlorogaster at different constant temperatures, thereby enabling the forensic use of this fly. Development time of this species was examined by observing larval development at six temperatures (10, 15, 20, 25, 30, 35 °C). The thermal constant (K), the minimum development threshold (t 0), and development rate were calculated using linear regressions of the development time interval at five temperatures (10-30 °C). Development interval from egg to adult varied from 14.2 to 95.2 days, depending on temperature. The t0 calculated for total immature development is 6.33 °C and the overall thermal constant is 355.51 degree-days (DD). Temperature affected the viability of pupae, at 35 °C 100 % mortality was observed. Understanding development rate across these temperatures now makes development of S. chlorogaster a forensically useful tool for estimating postmortem interval.

Dielectric and Excess Properties of Glycols with Formamide Binary Mixtures at Different Temperatures

NASA Astrophysics Data System (ADS)

Navarkhele, V. V.

2018-07-01

Dielectric constant measurements of glycol-formamide binary solutions with various concentrations have been carried out at different temperatures. The dielectric measurement has been achieved at 100 MHz frequency using a sensor which is based on frequency domain reflectomery technique. The excess dielectric constant, Kirkwood correlation factor and Bruggeman factor has also been reported for the binary mixtures. The results show that the dielectric constant of the mixtures increases with increase in the volume fraction of formamide and decreases with increase in temperature. The study also confirms the presence of intermolecular interaction, hydrogen bonding and orientation of the dipoles in the binary mixtures.

Spatially resolved quantitative mapping of thermomechanical properties and phase transition temperatures using scanning probe microscopy

DOEpatents

Jesse, Stephen; Kalinin, Sergei V; Nikiforov, Maxim P

2013-07-09

An approach for the thermomechanical characterization of phase transitions in polymeric materials (polyethyleneterephthalate) by band excitation acoustic force microscopy is developed. This methodology allows the independent measurement of resonance frequency, Q factor, and oscillation amplitude of a tip-surface contact area as a function of tip temperature, from which the thermal evolution of tip-surface spring constant and mechanical dissipation can be extracted. A heating protocol maintained a constant tip-surface contact area and constant contact force, thereby allowing for reproducible measurements and quantitative extraction of material properties including temperature dependence of indentation-based elastic and loss moduli.

A universal reduced glass transition temperature for liquids

NASA Technical Reports Server (NTRS)

Fedors, R. F.

1979-01-01

Data on the dependence of the glass transition temperature on the molecular structure for low-molecular-weight liquids are analyzed in order to determine whether Boyer's reduced glass transition temperature (1952) is a universal constant as proposed. It is shown that the Boyer ratio varies widely depending on the chemical nature of the molecule. It is pointed out that a characteristic temperature ratio, defined by the ratio of the sum of the melting temperature and the boiling temperature to the sum of the glass transition temperature and the boiling temperature, is a universal constant independent of the molecular structure of the liquid. The average value of the ratio obtained from data for 65 liquids is 1.15.

Aquarius L-Band Microwave Radiometer: Three Years of Radiometric Performance and Systematic Effects

NASA Technical Reports Server (NTRS)

Piepmeier, Jeffrey R.; Hong, Liang; Pellerano, Fernando A.

2015-01-01

The Aquarius L-band microwave radiometer is a three-beam pushbroom instrument designed to measure sea surface salinity. Results are analyzed for performance and systematic effects over three years of operation. The thermal control system maintains tight temperature stability promoting good gain stability. The gain spectrum exhibits expected orbital variations with 1f noise appearing at longer time periods. The on-board detection and integration scheme coupled with the calibration algorithm produce antenna temperatures with NEDT 0.16 K for 1.44-s samples. Nonlinearity is characterized before launch and the derived correction is verified with cold-sky calibration data. Finally, long-term drift is discovered in all channels with 1-K amplitude and 100-day time constant. Nonetheless, it is adeptly corrected using an exponential model.

Creep Laboratory manual

NASA Astrophysics Data System (ADS)

Osgerby, S.; Loveday, M. S.

1992-06-01

A manual for the NPL Creep Laboratory, a collective name given to two testing laboratories, the Uniaxial Creep Laboratory and the Advanced High Temperature Mechanical Testing Laboratory, is presented. The first laboratory is devoted to uniaxial creep testing and houses approximately 50 high sensitivity creep machines including 10 constant stress cam lever machines. The second laboratory houses a low cycle fatigue testing machine of 100 kN capacity driven by a servo-electric actuator, five machines for uniaxial tensile creep testing of engineering ceramics at temperatures up to 1600C, and an electronic creep machine. Details of the operational procedures for carrying out uniaxial creep testing are given. Calibration procedures to be followed in order to comply with the specifications laid down by British standards, and to provide traceability back to the primary standards are described.

Automated Heat-Flux-Calibration Facility

NASA Technical Reports Server (NTRS)

Liebert, Curt H.; Weikle, Donald H.

1989-01-01

Computer control speeds operation of equipment and processing of measurements. New heat-flux-calibration facility developed at Lewis Research Center. Used for fast-transient heat-transfer testing, durability testing, and calibration of heat-flux gauges. Calibrations performed at constant or transient heat fluxes ranging from 1 to 6 MW/m2 and at temperatures ranging from 80 K to melting temperatures of most materials. Facility developed because there is need to build and calibrate very-small heat-flux gauges for Space Shuttle main engine (SSME).Includes lamp head attached to side of service module, an argon-gas-recirculation module, reflector, heat exchanger, and high-speed positioning system. This type of automated heat-flux calibration facility installed in industrial plants for onsite calibration of heat-flux gauges measuring fluxes of heat in advanced gas-turbine and rocket engines.

Applications technology satellites battery and power system design

NASA Technical Reports Server (NTRS)

Ford, F. E.; Bemis, B.

1977-01-01

A summary of the ATS battery design which is onboard the Applications Technology Satellite (ATS) is provided. The 15 ampere hour nickel cadmium cells were manufactured by Gulton, 19 series connected cells per battery, and there are two batteries in each spacecraft. The operating design life was two years in a synchronous orbit, and a maximum depth of discharge of 50 percent. The design temperature for the batteries in the spacecraft was 0 to 25 C, and the charge control consisted of 1 volt versus temperature on a constant percentage voltage. Also, C/10 current limit, and a commandable trickle charge rate, using C/20 or C/60. The undervoltage was sent across a 9 cell and a 10 cell group, and it was set at one volt average per group on either group.

Development of procedures for calculating stiffness and damping properties of elastomers in engineering applications. Part 2: Elastomer characteristics at constant temperature

NASA Technical Reports Server (NTRS)

Gupta, P. K.; Tessarzik, J. M.; Cziglenyi, L.

1974-01-01

Dynamic properties of a commerical polybutadiene compound were determined at a constant temperature of 32 C by a forced-vibration resonant mass type of apparatus. The constant thermal state of the elastomer was ensured by keeping the ambient temperature constant and by limiting the power dissipation in the specimen. Experiments were performed with both compression and shear specimens at several preloads (nominal strain varying from 0 to 5 percent), and the results are reported in terms of a complex stiffness as a function of frequency. Very weak frequency dependence is observed and a simple power law type of correlation is shown to represent the data well. Variations in the complex stiffness as a function of preload are also found to be small for both compression and shear specimens.

Model-based estimation of adiabatic flame temperature during coal gasification

NASA Astrophysics Data System (ADS)

Sarigul, Ihsan Mert

Coal gasification temperature distribution in the gasifier is one of the important issues. High temperature may increase the risk of corrosion of the gasifier wall or it may cause an increase in the amount of volatile compounds. At the same time, gasification temperature is a dominant factor for high conversion of products and completing the reactions during coal gasification in a short time. In the light of this information it can be said that temperature is one of key parameters of coal gasification to enhance the production of high heating value syngas and maximize refractory longevity. This study aims to predict the adiabatic flame temperatures of Australian bituminous coal and Indonesian roto coal in an entrained flow gasifier using different operating conditions with the ChemCAD simulation and design program. To achieve these objectives, two types of gasification parameters were carried out using simulation of a vertical entrained flow reactor: oxygen-to-coal feed ratio by kg/kg and pressure and steam-to-coal feed ratio by kg/kg and pressure. In the first part of study the adiabatic flame temperatures, coal gasification products and other coal characteristics of two types of coals were determined using ChemCAD software. During all simulations, coal feed rate, coal particle size, initial temperature of coal, water and oxygen were kept constant. The relationships between flame temperature, coal gasification products and operating parameters were fundamentally investigated. The second part of this study addresses the modeling of the flame temperature relation to methane production and other input parameters used previous chapter. The scope of this work was to establish a reasonable model in order to estimate flame temperature without any theoretical calculation. Finally, sensitivity analysis was performed after getting some basic correlations between temperature and input variables. According to the results, oxygen-to-coal feed ratio has the most influential effect on adiabatic flame temperature.

Size- and temperature-dependent Hamaker constants for heterogeneous systems of interacting nanoparticles

NASA Astrophysics Data System (ADS)

Pinchuk, P.; Pinchuk, A. O.

2016-09-01

Hamaker-Lifshitz constants are used to calculate van der Waals interaction forces between small particles in solution. Typically, these constants are size-independent and material specific. According to the Lifshitz theory, the Hamaker-Lifshitz constants can be calculated by taking integrals that include the dielectric permittivity, as a function of frequency, of the interacting particles and the medium around particles. The dielectric permittivity of interacting metal nanoparticles can be calculated using the free-electron Drude model for metals. For bulk metals, the Drude model does is size independent. However, the conducting electrons in small metal nanoparticles exhibit surface scattering, which changes the complex dielectric permittivity function. Additionally, the Drude model can be modified to include temperature dependence. That is, an increase in temperature leads to thermal volume expansion and increased phonon population, which affect the scattering rate of the electrons and the plasma frequency. Both of these terms contribute significantly to the Drude model for the dielectric permittivity of the particles. In this work, we show theoretically that scattering of the free conducting electrons inside noble metal nanoparticles with the size of 1 - 50 nm leads to size-dependent dielectric permittivity and Hamaker-Lifshitz constants. In addition, we calculate numerically the Hamaker-Lifshitz constants for a variety of temperatures. The results of the study might be of interest for understanding colloidal stability of metal nanoparticles.

Novel nitrogen-based organosulfur electrodes for advanced intermediate temperature batteries

NASA Technical Reports Server (NTRS)

Visco, S. J.; Dejonghe, L. C.

1989-01-01

Advanced secondary batteries operating at intermediate temperatures (100 to 200 C) have attracted considerable interest due to their inherent advantages (reduced corrosion and safety risks) over higher temperature systems. Current work in this laboratory has involved research on a class of intermediate temperature Na/beta double prime- alumina/RSSR batteries conceptually similar to Na/S cells, but operating within a temperature range of 100 to 150 C, and having an organosulfur rather than inorganic sulfur positive electrode. The organosulfur electrodes are based on the reversible, two electron eduction of organodisulfides to the corresponding thiolate anions, RSSR + 2 electrons yield 2RS(-), where R is an organic moiety. Among the advantages of such a generic redox couple for battery research is the ability to tailor the physical, chemical, and electrochemical properties of the RSSR molecule through choice of the organic moiety. The viscosity, liquidus range, dielectric constant, equivalent weight, and redox potential can in fact be verified in a largely predictable manner. The current work concerns the use of multiple nitrogen organosulfur molecules, chosen for application in Na/RSSR cells for their expected oxidizing character. In fact, a Na/RSSR cell containing one of these materials, the sodium salt of 5-mercapto 1-methyltetrazole, yielded the highest open circuit voltage obtained yet in the laboratory; 3.0 volts in the charged state and 2.6 volts at 100 percent discharge. Accordingly, the cycling behavior of a series of multiple nitrogen organodisulfides as well as polymeric organodisulfides are presented in this manuscript.

Investigation of the hydrochlorination of SiCl4

NASA Technical Reports Server (NTRS)

Mui, J. Y. P.

1983-01-01

A basic, experimental study on the hydrochlorination of silicon tetrachloride and metallurgical grade silicon with hydrogen gas to form trichlorosilane was carried out to greatly expand the range of reaction conditions. The equilibrium constant, K sub p, for the hydrochlorination reaction was measured as a function of temperature, pressure and concentration. The variation of the equilibrium constant as a function of temperature provided the measurement on the heat of reaction, delta H, by the Second Law Method. The value of delta H was measured to give 10.6 Kcal/mole. The equilibrium constant was also studied as a function of concentration. In agreement with the theory, the equilibrium constant remained constant with respect to the varying H2/SiCl4 feed ratios. On the other hand, the effect of pressure on the equilibrium constant was found to be more complex.

Circadian rhythm of body temperature in an ectotherm (Iguana iguana).

PubMed

Tosini, G; Menaker, M

1995-09-01

Ectothermic animals regulate their body temperatures primarily by behavioral adjustment in relation to the thermal characteristics of the environment. Several studies have shown that some vertebrate ectotherms may show a daily pattern of body temperature selection when given a choice of environmental temperature. The pattern of body temperature selection free-runs when the animals are kept in constant darkness, demonstrating the existence of circadian regulation. To test whether there might also be a low amplitude circadian rhythm of body temperature itself, we examined the pattern of body temperature and locomotor activity of the lizard Iguana iguana held in a constant environmental temperature. Both variables were recorded for 3 days in a light:dark cycle and then for 10 days in constant dim light (0.1 lux). Under these conditions the body temperature of the lizard oscillates with a circadian period as does the locomotor behavior. These results demonstrate for the first time that ectothermic animals may display physiologically generated circadian rhythms of body temperature similar to those recorded in endotherms. In some animals the circadian rhythms of body temperature and locomotor activity showed different free-running periods, demonstrating that the body temperature rhythm was not caused by locomotor activity and suggesting internal desyncronization of the two rhythms.

Oxide Morphology of a FeCrAl Alloy, Kanthal APMT, Following Extended Aging in Air at 300 °C to 600 °C

NASA Astrophysics Data System (ADS)

Li, Nan; Parker, Stephen S.; Wood, Elizabeth S.; Nelson, Andrew T.

2018-05-01

Iron-chromium-aluminum (FeCrAl) alloys are of interest to the nuclear materials community due to their resistance to high-temperature steam oxidation under accident conditions. The present work investigates oxide formation at temperatures relevant to light water reactor cladding operation following extended aging to assess growth kinetics, chemical composition, and microstructure of oxide formation on a commercial FeCrAl alloy, Fe-21 wt pct Cr-5 wt pct Al-3 wt pct Mo (Kanthal APMT). Aging treatments were performed for 100 to 1000 hours in stagnant air at 300 °C, 400 °C, 500 °C, and 600 °C, respectively. Oxide growth behavior under the investigated conditions follows a logarithmic time dependence. When the oxidization temperature is 400 °C or below, the oxide is amorphous. At 500 °C, isolated crystalline regions start to appear during short period aging time and expand with extended exposures. Crystalline α-Al2O3 oxide film develops at 600 °C and the correlated logarithmic rate constant decreases significantly, indicating enhanced oxidation resistance of the formed oxide film. In addition, Mo segregation at grain boundaries has been observed when the aging temperature exceeds 500 °C. The results of this study can be viewed as an upper bounding result for potential oxide coarsening during reactor operation.

Oxide Morphology of a FeCrAl Alloy, Kanthal APMT, Following Extended Aging in Air at 300 °C to 600 °C

NASA Astrophysics Data System (ADS)

Li, Nan; Parker, Stephen S.; Wood, Elizabeth S.; Nelson, Andrew T.

2018-07-01

Iron-chromium-aluminum (FeCrAl) alloys are of interest to the nuclear materials community due to their resistance to high-temperature steam oxidation under accident conditions. The present work investigates oxide formation at temperatures relevant to light water reactor cladding operation following extended aging to assess growth kinetics, chemical composition, and microstructure of oxide formation on a commercial FeCrAl alloy, Fe-21 wt pct Cr-5 wt pct Al-3 wt pct Mo (Kanthal APMT). Aging treatments were performed for 100 to 1000 hours in stagnant air at 300 °C, 400 °C, 500 °C, and 600 °C, respectively. Oxide growth behavior under the investigated conditions follows a logarithmic time dependence. When the oxidization temperature is 400 °C or below, the oxide is amorphous. At 500 °C, isolated crystalline regions start to appear during short period aging time and expand with extended exposures. Crystalline α-Al2O3 oxide film develops at 600 °C and the correlated logarithmic rate constant decreases significantly, indicating enhanced oxidation resistance of the formed oxide film. In addition, Mo segregation at grain boundaries has been observed when the aging temperature exceeds 500 °C. The results of this study can be viewed as an upper bounding result for potential oxide coarsening during reactor operation.

Determination of kinetic and equilibrium parameters of the batch adsorption of Mn(II), Co(II), Ni(II) and Cu(II) from aqueous solution by black carrot (Daucus carota L.) residues.

PubMed

Güzel, Fuat; Yakut, Hakan; Topal, Giray

2008-05-30

In this study, the effect of temperature on the adsorption of Mn(II), Ni(II), Co(II) and Cu(II) from aqueous solution by modified carrot residues (MCR) was investigated. The equilibrium contact times of adsorption process for each heavy metals-MCR systems were determined. Kinetic data obtained for each heavy metal by MCR at different temperatures were applied to the Lagergren equation, and adsorption rate constants (kads) at these temperatures were determined. These rate constants related to the adsorption of heavy metal by MCR were applied to the Arrhenius equation, and activation energies (Ea) were determined. In addition, the isotherms for adsorption of each heavy metal by MCR at different temperatures were also determined. These isothermal data were applied to linear forms of isotherm equations that they fit the Langmuir adsorption isotherm, and the Langmuir constants (qm and b) were calculated. b constants determined at different temperatures were applied to thermodynamic equations, and thermodynamic parameters such as enthalpy (Delta H), free energy (Delta G), and entropy (Delta S) were calculated and these values show that adsorption of heavy metal on MCR was an endothermic process and process of adsorption was favoured at high temperatures.

Mechanical and Thermal Properties of Praseodymium Monopnictides: AN Ultrasonic Study

NASA Astrophysics Data System (ADS)

Bhalla, Vyoma; Kumar, Raj; Tripathy, Chinmayee; Singh, Devraj

2013-09-01

We have computed ultrasonic attenuation, acoustic coupling constants and ultrasonic velocities of praseodymium monopnictides PrX(X: N, P, As, Sb and Bi) along the <100>, <110>, <111> in the temperature range 100-500 K using higher order elastic constants. The higher order elastic constants are evaluated using Coulomb and Born-Mayer potential with two basic parameters viz. nearest-neighbor distance and hardness parameter in the temperature range of 0-500 K. Several other mechanical and thermal parameters like bulk modulus, shear modulus, Young's modulus, Poisson ratio, anisotropic ratio, tetragonal moduli, Breazeale's nonlinearity parameter and Debye temperature are also calculated. In the present study, the fracture/toughness (B/G) ratio is less than 1.75 which implies that PrX compounds are brittle in nature at room temperature. The chosen material fulfilled Born criterion of mechanical stability. We also found the deviation of Cauchy's relation at higher temperatures. PrN is most stable material as it has highest valued higher order elastic constants as well as the ultrasonic velocity. Further, the lattice thermal conductivity using modified approach of Slack and Berman is determined at room temperature. The ultrasonic attenuation due to phonon-phonon interaction and thermoelastic relaxation mechanisms have been computed using modified Mason's approach. The results with other well-known physical properties are useful for industrial applications.

Method and apparatus for measuring surface contour on parts with elevated temperatures

DOEpatents

Horvath, Mark S.; Nance, Roy A.; Cohen, George H.; Fodor, George

1991-01-01

The invention is directed to a method and apparatus for measuring the surface contour of a test piece, such as the bow of a radioactive fuel rod, which is completely immersed in water. The invention utilizes ultrasonic technology and is capable of measuring surface contours of test pieces which are at a higher temperature than the surrounding water. The presence of a test piece at a higher temperature adversely affects the distance measurements by causing thermal variations in the water near the surface of the test piece. The contour measurements depend upon a constant temperature of the water in the path of the ultrasonic wave to provide a constant acoustical velocity (the measurement is made by the time of flight measurement for an ultrasonic wave). Therefore, any variations of water temperature near the surface will introduce errors degrading the measurement. The present invention overcomes these problems by assuring that the supply of water through which the ultrasonic waves travel is at a predetermined and constant temperature.

Henry's law constant for phosphine in seawater: determination and assessment of influencing factors

NASA Astrophysics Data System (ADS)

Fu, Mei; Yu, Zhiming; Lu, Guangyuan; Song, Xiuxian

2013-07-01

The Henry's Law constant ( k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23°C). This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry's Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.

Dielectric constant of liquid alkanes and hydrocarbon mixtures

NASA Technical Reports Server (NTRS)

Sen, A. D.; Anicich, V. G.; Arakelian, T.

1992-01-01

The complex dielectric constants of n-alkanes with two to seven carbon atoms have been measured. The measurements were conducted using a slotted-line technique at 1.2 GHz and at atmospheric pressure. The temperature was varied from the melting point to the boiling point of the respective alkanes. The real part of the dielectric constant was found to decrease with increasing temperature and correlate with the change in the molar volume. An upper limit to all the loss tangents was established at 0.001. The complex dielectric constants of a few mixtures of liquid alkanes were also measured at room temperature. For a pentane-octane mixture the real part of the dielectric constant could be explained by the Clausius-Mosotti theory. For the mixtures of n-hexane-ethylacetate and n-hexane-acetone the real part of the dielectric constants could be explained by the Onsager theory extended to mixtures. The dielectric constant of the n-hexane-acetone mixture displayed deviations from the Onsager theory at the highest fractions of acetone. The dipole moments of ethylacetate and acetone were determined for dilute mixtures using the Onsager theory and were found to be in agreement with their accepted gas-phase values. The loss tangents of the mixtures exhibited a linear relationship with the volume fraction for low concentrations of the polar liquids.

Analysis of the auger recombination rate in P+N-n-N-N HgCdTe detectors for HOT applications

NASA Astrophysics Data System (ADS)

Schuster, J.; Tennant, W. E.; Bellotti, E.; Wijewarnasuriya, P. S.

2016-05-01

Infrared (IR) photon detectors must be cryogenically cooled to provide the highest possible performance, usually to temperatures at or below ~ 150K. Such low operating temperatures (Top) impose very stringent requirements on cryogenic coolers. As such, there is a constant push in the industry to engineer new detector architectures that operate at higher temperatures, so called higher operating temperature (HOT) detectors. The ultimate goal for HOT detectors is room temperature operation. While this is not currently possibly for photon detectors, significant increases in Top are nonetheless beneficial in terms of reduced size, weight, power and cost (SWAP-C). The most common HgCdTe IR detector architecture is the P+n heterostructure photodiode (where a capital letter indicates a wide band gap relative to the active layer or "AL"). A variant of this architecture, the P+N-n-N-N heterostructure photodiode, should have a near identical photo-response to the P+n heterostructure, but with significantly lower dark diffusion current. The P+N-n-N-N heterostructure utilizes a very low doped AL, surrounded on both sides by wide-gap layers. The low doping in the AL, allows the AL to be fully depleted, which drastically reduces the Auger recombination rate in that layer. Minimizing the Auger recombination rate reduces the intrinsic dark diffusion current, thereby increasing Top. Note when we use the term "recombination rate" for photodiodes, we are actually referring to the net generation and recombination of minority carriers (and corresponding dark currents) by the Auger process. For these benefits to be realized, these devices must be intrinsically limited and well passivated. The focus of this proceeding is on studying the fundamental physics of the intrinsic dark currents in ideal P+N-n-N-N heterostructures, namely Auger recombination. Due to the complexity of these devices, specifically the presence of multiple heterojunctions, numerical device modeling techniques must be utilized to predict and understand the device operation, as analytical models do not exist for heterojunction devices.

21 CFR 1250.42 - Water systems; constant temperature bottles.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Water systems; constant temperature bottles. 1250.42 Section 1250.42 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) REGULATIONS UNDER CERTAIN OTHER ACTS ADMINISTERED BY THE FOOD AND DRUG ADMINISTRATION...

Temperature dependencies of Henry’s law constants for different plant sesquiterpenes

PubMed Central

Copolovici, Lucian; Niinemets, Ülo

2018-01-01

Sesquiterpenes are plant-produced hydrocarbons with important ecological functions in plant-to-plant and plant-to-insect communication, but due to their high reactivity they can also play a significant role in atmospheric chemistry. So far, there is little information of gas/liquid phase partition coefficients (Henry’s law constants) and their temperature dependencies for sesquiterpenes, but this information is needed for quantitative simulation of the release of sesquiterpenes from plants and modeling atmospheric reactions in different phases. In this study, we estimated Henry’s law constants (Hpc) and their temperature responses for 12 key plant sesquiterpenes with varying structure (aliphatic, mono-, bi- and tricyclic sesquiterpenes). At 25 °C, Henry’s law constants varied 1.4-fold among different sesquiterpenes, and the values were within the range previously observed for monocyclic monoterpenes. Hpc of sesquiterpenes exhibited a high rate of increase, on average ca. 1.5-fold with a 10 °C increase in temperature (Q10). The values of Q10 varied 1.2-fold among different sesquiterpenes. Overall, these data demonstrate moderately high variation in Hpc values and Hpc temperature responses among different sesquiterpenes. We argue that these variations can importantly alter the emission kinetics of sesquiterpenes from plants. PMID:26291755

The effect of addition of primary positive salts, complex salt, on the ionic strength and rate constant at various temperatures by reaction kinetics

NASA Astrophysics Data System (ADS)

Kurade, S. S.; Ramteke, A. A.

2018-05-01

In this work, we have investigated the rate of reaction by using ionic strength at different temperatures. The main goal of this experiment is to determine the relation between ionic strength with reaction rate, reaction time and rate constant with temperature. It is observed that the addition of positive salt indicate the increasing ionic strength with increase in run time at various temperatures. Thus the temperature affects the speed of reaction and mechanism by which chemical reaction occurs and time variable plays vital role in the progress of reaction at different temperatures.

Tensile properties of HK31XA-H24 magnesium-alloy sheet under rapid-heating conditions and constant elevated temperatures

NASA Technical Reports Server (NTRS)

Gibbs, Thomas W

1956-01-01

Specimens of HK31XA-H24 magnesium-alloy sheet from an experimental batch were heated to failure at nominal temperature rates from 0.2 F to 100 F per second under constant-load conditions. Rapid-heating yield and rupture stresses are presented and compared with the yield and ultimate stresses from elevated-temperature tensile stress-strain tests for 1/2-hour exposure. Linear temperature-rate parameters were used to correlate rapid-heating results by constructing master curves which can be used for predicting yield stresses and temperatures and for estimating rupture stresses and temperatures.

Temperature-Dependent Estimation of Gibbs Energies Using an Updated Group-Contribution Method.

PubMed

Du, Bin; Zhang, Zhen; Grubner, Sharon; Yurkovich, James T; Palsson, Bernhard O; Zielinski, Daniel C

2018-06-05

Reaction-equilibrium constants determine the metabolite concentrations necessary to drive flux through metabolic pathways. Group-contribution methods offer a way to estimate reaction-equilibrium constants at wide coverage across the metabolic network. Here, we present an updated group-contribution method with 1) additional curated thermodynamic data used in fitting and 2) capabilities to calculate equilibrium constants as a function of temperature. We first collected and curated aqueous thermodynamic data, including reaction-equilibrium constants, enthalpies of reaction, Gibbs free energies of formation, enthalpies of formation, entropy changes of formation of compounds, and proton- and metal-ion-binding constants. Next, we formulated the calculation of equilibrium constants as a function of temperature and calculated the standard entropy change of formation (Δ f S ∘ ) using a model based on molecular properties. The median absolute error in estimating Δ f S ∘ was 0.013 kJ/K/mol. We also estimated magnesium binding constants for 618 compounds using a linear regression model validated against measured data. We demonstrate the improved performance of the current method (8.17 kJ/mol in median absolute residual) over the current state-of-the-art method (11.47 kJ/mol) in estimating the 185 new reactions added in this work. The efforts here fill in gaps for thermodynamic calculations under various conditions, specifically different temperatures and metal-ion concentrations. These, to our knowledge, new capabilities empower the study of thermodynamic driving forces underlying the metabolic function of organisms living under diverse conditions. Copyright © 2018 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Development of a new mini-invasive tumour hyperthermia probe using high-temperature water vapour.

PubMed

Yu, Tian-Hua; Zhou, Yi-Xin; Liu, Jing

2004-01-01

A new mini-invasive hyperthermia probe using high-temperature water vapour for deep regional tumour treatment was developed in this paper. The vacuum insulation mechanism was incorporated into the probe to avoid heating damage to the normal tissues around the edge of the insertion path. To better understand the heat transfer behaviour in living tissues due to operation of the probe, theoretical models based on the Pennes' equation were established and two closed form analytical solutions under constant flux or temperature heating at the tip of probe were obtained. Parametric studies were performed to investigate the influence of various parameters on the temperature response of tissues heated by the probe. Further, several simulating experiments on the actual heating performance of the probe fabricated in this paper were conducted on the in vitro biological materials (fresh pork) and phantom gel. It was demonstrated that the probe can cause a high enough temperature over the treatment area to thermally destroy the tumour tissue in due time, while the temperature over the surrounding healthy tissues can be kept below a safe threshold value. This mini-invasive heating probe may have significant applications in future clinical tumour hyperthermia.

Effects of constant and cyclical thermal regimes on growth and feeding of juvenile cutthroat trout of variable sizes

Treesearch

M. H. Meeuwig; J. B. Dunham; J. P. Hayes; G. L. Vinyard

2004-01-01

The effects of constant (12, 18, and 24°C) and cyclical (daily variation of 15–21 and 12–24 °C) thermal regimes on the growth and feeding of Lahontan cutthroat trout (Oncorhynchus clarki henshawi) of variable sizes were examined. Higher constant temperatures (i.e., 24°C) and more variable daily temperatures (i.e., 12–24°C daily cycle) negatively...

Acid-base regulation during heating and cooling in the lizard, Varanus exanthematicus.

PubMed

Wood, S C; Johansen, K; Glass, M L; Hoyt, R W

1981-04-01

Current concepts of acid-base balance in ectothermic animals require that arterial pH vary inversely with body temperature in order to maintain a constant OH-/H+ and constant net charge on proteins. The present study evaluates acid-base regulation in Varanus exanthematicus under various regimes of heating and cooling between 15 and 38 degrees C. Arterial blood was sampled during heating and cooling at various rates, using restrained and unrestrained animals with and without face masks. Arterial pH was found to have a small temperature dependence, i.e., pH = 7.66--0.005 (T). The slope (dpH/dT = -0.005), while significantly greater than zero (P less than 0.05), is much less than that required for a constant OH-/H+ or a constant imidazole alphastat (dpH/dT congruent to 0.018). The physiological mechanism that distinguishes this species from most other ectotherms is the presence of a ventilatory response to temperature-induced changes in CO2 production and O2 uptake, i.e., VE/VO2 is constant. This results in a constant O2 extraction and arterial saturation (approx. 90%), which is adaptive to the high aerobic requirements of this species.

Temperature-Dependent Rate Constants and Substituent Effects for the Reactions of Hydroxyl Radicals With Three Partially Fluorinated Ethers

NASA Technical Reports Server (NTRS)

Hsu, K.-J.; DeMore, W. B.

1995-01-01

Rate constants and temperature dependencies for the reactions of OH with CF3OCH3 (HFOC-143a), CF2HOCF2H (HFOC-134), and CF3OCF2H (HFOC-125) were studied using a relative rate technique in the temperature range 298-393 K. The following absolute rate constants were derived: HFOC-143a, 1.9E-12 exp(-1555/T); HFOC-134, 1.9E-12 exp(-2006/T); HFOC-125, 4.7E-13 exp(-2095/T). Units are cm(exp 3)molecule(exp -1) s(exp -1). Substituent effects on OH abstraction rate constants are discussed, and it is shown that the CF3O group has an effect on the OH rate constants similar to that of a fluorine atom. The effects are related to changes in the C-H bond energies of the reactants (and thereby the activation energies) rather than changes in the preexponential factors. On the basis of a correlation of rate constants with bond energies, the respective D(C-H) bond strengths in the three ethers are found to be 102, 104, and 106 kcal/mol, with an uncertainty of about 1 kcal/mol.

Ultrasonication Assisted Production of Biodiesel from Sunflower Oil by Using CuO: Mg Heterogeneous Nanocatalyst

NASA Astrophysics Data System (ADS)

Varghese, Rintu; Jose, Sony; Joyprabu, H.; Johnson, I.

2017-08-01

Biodiesel is a clean, renewable, biodegradable, eco-friendly and alternative fuel used in the diesel engine. The present work was carried out at constant operational conditions such as methanol to oil molar ratio 6:1, catalyst concentration 0.25%, 30 minute reaction time and the reaction temperature at 60°C. Biodiesel was synthesized by transesterification of sunflower oil (SFO) with methanol, using CuO: Mgas nanocatalyst. This nanocatalyst was prepared by quick precipitation method. The biodiesel yield of 71.78% was achieved under reaction condition. The presence of methyl ester groups at the produced biodiesel was confirmed using the Gas Chromatography-Mass Spectrometry (GC-MS). The FAME conversion yield up to 82.83 % could be obtained under the operating conditions.

Characterization of the electrical output of flat-plate photovoltaic arrays

NASA Technical Reports Server (NTRS)

Gonzalez, C. C.; Hill, G. M.; Ross, R. G., Jr.

1982-01-01

The electric output of flat-plate photovoltaic arrays changes constantly, due primarily to changes in cell temperature and irradiance level. As a result, array loads such as direct-current to alternating-current power conditioners must be able to accommodate widely varying input levels, while maintaining operation at or near the array maximum power point.The results of an extensive computer simulation study that was used to define the parameters necessary for the systematic design of array/power-conditioner interfaces are presented as normalized ratios of power-conditioner parameters to array parameters, to make the results universally applicable to a wide variety of system sizes, sites, and operating modes. The advantages of maximum power tracking and a technique for computing average annual power-conditioner efficiency are discussed.

Efficient protocols for Stirling heat engines at the micro-scale

NASA Astrophysics Data System (ADS)

Muratore-Ginanneschi, Paolo; Schwieger, Kay

2015-10-01

We investigate the thermodynamic efficiency of sub-micro-scale Stirling heat engines operating under the conditions described by overdamped stochastic thermodynamics. We show how to construct optimal protocols such that at maximum power the efficiency attains for constant isotropic mobility the universal law η=2 ηC/(4-ηC) , where ηC is the efficiency of an ideal Carnot cycle. We show that these protocols are specified by the solution of an optimal mass transport problem. Such solution can be determined explicitly using well-known Monge-Ampère-Kantorovich reconstruction algorithms. Furthermore, we show that the same law describes the efficiency of heat engines operating at maximum work over short time periods. Finally, we illustrate the straightforward extension of these results to cases when the mobility is anisotropic and temperature dependent.

Low-voltage organic transistors on plastic comprising high-dielectric constant gate insulators

PubMed

Dimitrakopoulos; Purushothaman; Kymissis; Callegari; Shaw

1999-02-05

The gate bias dependence of the field-effect mobility in pentacene-based insulated gate field-effect transistors (IGFETs) was interpreted on the basis of the interaction of charge carriers with localized trap levels in the band gap. This understanding was used to design and fabricate IGFETs with mobility of more than 0.3 square centimeter per volt per second and current modulation of 10(5), with the use of amorphous metal oxide gate insulators. These values were obtained at operating voltage ranges as low as 5 volts, which are much smaller than previously reported results. An all-room-temperature fabrication process sequence was used, which enabled the demonstration of high-performance organic IGFETs on transparent plastic substrates, at low operating voltages for organic devices.

Very high pressure liquid chromatography using core-shell particles: quantitative analysis of fast gradient separations without post-run times.

PubMed

Stankovich, Joseph J; Gritti, Fabrice; Stevenson, Paul G; Beaver, Lois A; Guiochon, Georges

2014-01-17

Five methods for controlling the mobile phase flow rate for gradient elution analyses using very high pressure liquid chromatography (VHPLC) were tested to determine thermal stability of the column during rapid gradient separations. To obtain rapid separations, instruments are operated at high flow rates and high inlet pressure leading to uneven thermal effects across columns and additional time needed to restore thermal equilibrium between successive analyses. The purpose of this study is to investigate means to minimize thermal instability and obtain reliable results by measuring the reproducibility of the results of six replicate gradient separations of a nine component RPLC standard mixture under various experimental conditions with no post-run times. Gradient separations under different conditions were performed: constant flow rates, two sets of constant pressure operation, programmed flow constant pressure operation, and conditions which theoretically should yield a constant net heat loss at the column's wall. The results show that using constant flow rates, programmed flow constant pressures, and constant heat loss at the column's wall all provide reproducible separations. However, performing separations using a high constant pressure with programmed flow reduces the analysis time by 16% compared to constant flow rate methods. For the constant flow rate, programmed flow constant pressure, and constant wall heat experiments no equilibration time (post-run time) was required to obtain highly reproducible data. Copyright © 2013 Elsevier B.V. All rights reserved.

Friedberg-Lee model at finite temperature and density

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mao Hong; CCAST; Yao Minjie

2008-06-15

The Friedberg-Lee model is studied at finite temperature and density. By using the finite temperature field theory, the effective potential of the Friedberg-Lee model and the bag constant B(T) and B(T,{mu}) have been calculated at different temperatures and densities. It is shown that there is a critical temperature T{sub C}{approx_equal}106.6 MeV when {mu}=0 MeV and a critical chemical potential {mu}{approx_equal}223.1 MeV for fixing the temperature at T=50 MeV. We also calculate the soliton solutions of the Friedberg-Lee model at finite temperature and density. It turns out that when T{<=}T{sub C} (or {mu}{<=}{mu}{sub C}), there is a bag constant B(T) [ormore » B(T,{mu})] and the soliton solutions are stable. However, when T>T{sub C} (or {mu}>{mu}{sub C}) the bag constant B(T)=0 MeV [or B(T,{mu})=0 MeV] and there is no soliton solution anymore, therefore, the confinement of quarks disappears quickly.« less

History dependent crystallization of Zr41Ti14Cu12Ni10Be23 melts

NASA Astrophysics Data System (ADS)

Schroers, Jan; Johnson, William L.

2000-07-01

The crystallization of Zr41Ti14Cu12Ni10Be23 (Vit 1) melts during constant heating is investigated. (Vit 1) melts are cooled with different rates into the amorphous state and the crystallization temperature upon subsequent heating is studied. In addition, Vit 1 melts are cooled using a constant rate to different temperatures and subsequently heated from this temperature with a constant rate. We investigate the influence of the temperature to which the melt was cooled on the crystallization temperature measured upon heating. In both cases the onset temperature of crystallization shows strong history dependence. This can be explained by an accumulating process during cooling and heating. An attempt is made to consider this process in a simple model by steady state nucleation and subsequent growth of the nuclei which results in different crystallization kinetics during cooling or heating. Calculations show qualitative agreement with the experimental results. However, calculated and experimental results differ quantitatively. This difference can be explained by a decomposition process leading to a nonsteady nucleation rate which continuously increases with decreasing temperature.

Effect of temperature on postillumination isoprene emission in oak and poplar.

PubMed

Li, Ziru; Ratliff, Ellen A; Sharkey, Thomas D

2011-02-01

Isoprene emission from broadleaf trees is highly temperature dependent, accounts for much of the hydrocarbon emission from plants, and has a profound effect on atmospheric chemistry. We studied the temperature response of postillumination isoprene emission in oak (Quercus robur) and poplar (Populus deltoides) leaves in order to understand the regulation of isoprene emission. Upon darkening a leaf, isoprene emission fell nearly to zero but then increased for several minutes before falling back to nearly zero. Time of appearance of this burst of isoprene was highly temperature dependent, occurring sooner at higher temperatures. We hypothesize that this burst represents an intermediate pool of metabolites, probably early metabolites in the methylerythritol 4-phosphate pathway, accumulated upstream of dimethylallyl diphosphate (DMADP). The amount of this early metabolite(s) averaged 2.9 times the amount of plastidic DMADP. DMADP increased with temperature up to 35°C before starting to decrease; in contrast, the isoprene synthase rate constant increased up to 40°C, the highest temperature at which it could be assessed. During a rapid temperature switch from 30°C to 40°C, isoprene emission increased transiently. It was found that an increase in isoprene synthase activity is primarily responsible for this transient increase in emission levels, while DMADP level stayed constant during the switch. One hour after switching to 40°C, the amount of DMADP fell but the rate constant for isoprene synthase remained constant, indicating that the high temperature falloff in isoprene emission results from a reduction in the supply of DMADP rather than from changes in isoprene synthase activity.

An Integrated Approach to Estimate Instantaneous Near-Surface Air Temperature and Sensible Heat Flux Fields during the SEMAPHORE Experiment.

NASA Astrophysics Data System (ADS)

Bourras, Denis; Eymard, Laurence; Liu, W. Timothy; Dupuis, Hélène

2002-03-01

A new technique was developed to retrieve near-surface instantaneous air temperatures and turbulent sensible heat fluxes using satellite data during the Structure des Echanges Mer-Atmosphere, Proprietes des Heterogeneites Oceaniques: Recherche Experimentale (SEMAPHORE) experiment, which was conducted in 1993 under mainly anticyclonic conditions. The method is based on a regional, horizontal atmospheric temperature advection model whose inputs are wind vectors, sea surface temperature fields, air temperatures around the region under study, and several constants derived from in situ measurements. The intrinsic rms error of the method is 0.7°C in terms of air temperature and 9 W m2 for the fluxes, both at 0.16° × 0.16° and 1.125° × 1.125° resolution. The retrieved air temperature and flux horizontal structures are in good agreement with fields from two operational general circulation models. The application to SEMAPHORE data involves the First European Remote Sensing Satellite (ERS-1) wind fields, Advanced Very High Resolution Radiometer (AVHRR) SST fields, and European Centre for Medium-Range Weather Forecasts (ECMWF) air temperature boundary conditions. The rms errors obtained by comparing the estimations with research vessel measurements are 0.3°C and 5 W m2.

Temperature-controlled optical stimulation of the rat prostate cavernous nerves

NASA Astrophysics Data System (ADS)

Tozburun, Serhat; Hutchens, Thomas C.; McClain, Michael A.; Lagoda, Gwen A.; Burnett, Arthur L.; Fried, Nathaniel M.

2013-06-01

Optical nerve stimulation (ONS) may be useful as a diagnostic tool for intraoperative identification and preservation of the prostate cavernous nerves (CN), responsible for erectile function, during prostate cancer surgery. Successful ONS requires elevating the nerve temperature to within a narrow range (˜42 to 47°C) for nerve activation without thermal damage to the nerve. This preliminary study explores a prototype temperature-controlled optical nerve stimulation (TC-ONS) system for maintaining a constant (±1°C) nerve temperature during short-term ONS of the rat prostate CNs. A 150-mW, 1455-nm diode laser was operated in continuous-wave mode, with and without temperature control, during stimulation of the rat CNs for 15 to 30 s through a fiber optic probe with a 1-mm-diameter spot. A microcontroller opened and closed an in-line mechanical shutter in response to an infrared sensor, with a predetermined temperature set point. With TC-ONS, higher laser power settings were used to rapidly and safely elevate the CNs to a temperature necessary for a fast intracavernous pressure response, while also preventing excessive temperatures that would otherwise cause thermal damage to the nerve. With further development, TC-ONS may provide a rapid, stable, and safe method for intraoperative identification and preservation of the prostate CNs.

Aerobic sludge digestion under low dissolved oxygen concentrations.

PubMed

Arunachalam, RaviSankar; Shah, Hemant K; Ju, Lu-Kwang

2004-01-01

Low dissolved oxygen (DO) concentrations occur commonly in aerobic digesters treating thickened sludge, with benefits of smaller digester size, much reduced aeration cost, and higher digestion temperature (especially important for plants in colder areas). The effects of low DO concentrations on digestion kinetics were studied using the sludge from municipal wastewater treatment plants in Akron, Ohio, and Los Lunas, New Mexico. The experiments were conducted in both batch digestion and a mixed mode of continuous, fed-batch, and batch operations. The low DO condition was clearly advantageous in eliminating the need for pH control because of the simultaneous occurrence of nitrification and denitrification. However, when compared with fully aerobic (high DO) systems under constant pH control (rare in full-scale plants), low DO concentrations and a higher solids loading had a negative effect on the specific volatile solids (VS) digestion kinetics. Nonetheless, the overall (volumetric) digestion performance depends not only on the specific digestion kinetics, but also the solids concentration, pH, and digester temperature. All of the latter factors favor the low DO digestion of thickened sludge. The significant effect of temperature on low DO digestion was confirmed in the mixed-mode study with the Akron sludge. When compared with the well-known empirical correlation between VS reduction and the product (temperature x solids retention time), the experimental data followed the same trend, but were lower than the correlation predictions. The latter was attributed to the lower digestible VS in the Akron sludge, the slower digestion at low DO concentrations, or both. Through model simulation, the first-order decay constant (kd) was estimated as 0.004 h(-1) in the mixed-mode operations, much lower than those (0.011 to 0.029 h(-1)) obtained in batch digestion. The findings suggested that the interactions among sludges with different treatment ages may have a substantially negative effect on digestion kinetics. The use of multistage digesters, especially with small front-end reactors, may be advantageous in both "process" kinetics and "biological reaction" kinetics for sludge digestion.

Effect of Spray Cone Angle on Flame Stability in an Annular Gas Turbine Combustor

NASA Astrophysics Data System (ADS)

Mishra, R. K.; Kumar, S. Kishore; Chandel, Sunil

2016-04-01

Effect of fuel spray cone angle in an aerogas turbine combustor has been studied using computational fluid dynamics (CFD) and full-scale combustor testing. For CFD analysis, a 22.5° sector of an annular combustor is modeled and the governing equations are solved using the eddy dissipation combustion model in ANSYS CFX computational package. The analysis has been carried out at 125 kPa and 303 K inlet conditions for spray cone angles from 60° to 140°. The lean blowout limits are established by studying the behavior of combustion zone during transient engine operation from an initial steady-state condition. The computational study has been followed by testing the practical full-scale annular combustor in an aerothermal test facility. The experimental result is in a good agreement with the computational predictions. The lean blowout fuel-air ratio increases as the spray cone angle is decreased at constant operating pressure and temperature. At higher spray cone angle, the flame and high-temperature zone moves upstream close to atomizer face and a uniform flame is sustained over a wide region causing better flame stability.

Development of a Phasor Diagram Creator to Visualize the Piston and Displacer Forces in an Advanced Stirling Convertor

NASA Technical Reports Server (NTRS)

Saha, Dipanjan; Lewandowski, Edward J.

2013-01-01

The steady-state, nearly sinusoidal behavior of the components in a free-piston Stirling engine allows for visualization of the forces in the system using phasor diagrams. Based on Newton's second law, F = ma, any phasor diagrams modeling a given component in a system should close if all of the acting forces have been considered. Since the Advanced Stirling Radioisotope Generator (ASRG), currently being developed for future NASA deep space missions, is made up of such nearly sinusoidally oscillating components, its phasor diagrams would also be expected to close. A graphical user interface (GUI) has been written in MATLAB (MathWorks), which takes user input data, passes it to Sage (Gedeon Associates), a one-dimensional thermodynamic modeling program used to model the Stirling convertor, runs Sage, and then automatically plots the phasor diagrams. Using this software tool, the effect of varying different Sage inputs on the phasor diagrams was determined. The parameters varied were piston amplitude, hot-end temperature, cold-end temperature, operating frequency, and displacer spring constant. These phasor diagrams offer useful insight into convertor operation and performance.

A rechargeable lithium metal battery operating at intermediate temperatures using molten alkali bis(trifluoromethylsulfonyl)amide mixture as an electrolyte

NASA Astrophysics Data System (ADS)

Watarai, Atsushi; Kubota, Keigo; Yamagata, Masaki; Goto, Takuya; Nohira, Toshiyuki; Hagiwara, Rika; Ui, Koichi; Kumagai, Naoaki

The physicochemical properties of molten alkali bis(trifluoromethylsulfonyl)amide, MTFSI (M = Li, K, Cs), mixture (x LiTFSI = 0.20, x KTFSI = 0.10, x CsTFSI = 0.70) were studied to develop a new rechargeable lithium battery operating at intermediate temperature (100-180 °C). The viscosity and ionic conductivity of this melt at 150 °C are 87.2 cP and 14.2 mS cm -1, respectively. The cyclic voltammetry revealed that the electrochemical window at 150 °C is as wide as 5.0 V, and that the electrochemical deposition/dissolution of lithium metal occurs at the cathode limit. A Li/MTFSI (M = Li, K, Cs)/LiFePO 4 cell showed an excellent cycle performance at a constant current rate of C/10 at 150 °C; 95% of the initial discharge capacity was maintained after 50 cycles. Except for the initial few cycles, the coulombic efficiencies were approximately 100% for all the cycles, indicating the stabilities of the molten MTFSI mixture and all the electrode materials.

In vitro metabolic engineering for the salvage synthesis of NAD(.).

PubMed

Honda, Kohsuke; Hara, Naoya; Cheng, Maria; Nakamura, Anna; Mandai, Komako; Okano, Kenji; Ohtake, Hisao

2016-05-01

Excellent thermal and operational stabilities of thermophilic enzymes can greatly increase the applicability of biocatalysis in various industrial fields. However, thermophilic enzymes are generally incompatible with thermo-labile substrates, products, and cofactors, since they show the maximal activities at high temperatures. Despite their pivotal roles in a wide range of enzymatic redox reactions, NAD(P)(+) and NAD(P)H exhibit relatively low stabilities at high temperatures, tending to be a major obstacle in the long-term operation of biocatalytic chemical manufacturing with thermophilic enzymes. In this study, we constructed an in vitro artificial metabolic pathway for the salvage synthesis of NAD(+) from its degradation products by the combination of eight thermophilic enzymes. The enzymes were heterologously produced in recombinant Escherichia coli and the heat-treated crude extracts of the recombinant cells were directly used as enzyme solutions. When incubated with experimentally optimized concentrations of the enzymes at 60°C, the NAD(+) concentration could be kept almost constant for 15h. Copyright © 2016 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved.

System for improving measurement accuracy of transducer by measuring transducer temperature and resistance change using thermoelectric voltages

NASA Technical Reports Server (NTRS)

Anderson, Karl F. (Inventor); Parker, Allen R., Jr. (Inventor)

1993-01-01

A constant current loop measuring system measures a property including the temperature of a sensor responsive to an external condition being measured. The measuring system includes thermocouple conductors connected to the sensor, sensing first and second induced voltages responsive to the external condition. In addition, the measuring system includes a current generator and reverser generating a constant current, and supplying the constant current to the thermocouple conductors in forward and reverse directions generating first and second measured voltages, and a determining unit receiving the first and second measured voltages from the current generator and reverser, and determining the temperature of the sensor responsive to the first and second measured voltages.

A Fiber Bragg grating based tilt sensor suitable for constant temperature room

NASA Astrophysics Data System (ADS)

Tang, Guoyu; Wei, Jue; Zhou, Wei; Wu, Mingyu; Yang, Meichao; Xie, Ruijun; Xu, Xiaofeng

2015-07-01

Constant-temperature rooms have been widely used in industrial production, quality testing, and research laboratories. This paper proposes a high-precision tilt sensor suitable for a constant- temperature room, which has achieved a wide-range power change while the fiber Bragg grating (FBG) reflection peak wavelength shifted very little, thereby demonstrating a novel method for obtaining a high-precision tilt sensor. This paper also studies the effect of the reflection peak on measurement precision. The proposed sensor can distinguish the direction of tilt with an excellent sensitivity of 403 dBm/° and a highest achievable resolution of 2.481 × 10-5 ° (that is, 0.08% of the measuring range).

The Boiling eXperiment Facility (BXF) for the Microgravity Science Glovebox (MSG)

NASA Technical Reports Server (NTRS)

McQuillen, John; Chao, David; Vergilii, Frank

2006-01-01

Boiling is an effective means of cooling by removing heat from surfaces through vaporization of a working fluid. It is also affected by both the magnitude and direction of gravity. By conducting pool boiling tests in microgravity, the effect of buoyancy n the overall boiling process and the relative magnitude of other phenomena can be assessed. The Boiling eXperiment Facility (BXF) is being built for the Microgravity Science Glovebox. This facility will conduct two pool boiling studies. The first study the Microheater Array Boiling Experiment (MABE) uses two 96 element microheater arrays, 2.7 mm and 7.0 mm in size, to measure localized hear fluxes while operating at a constant temperature. The other experiment, the Nucleate Pool Boiling eXperiment (NPBX) uses a 85 mm diameter heater wafer that has been "seeded" with five individually-controlled nucleation sites to study bubble nucleation, growth, coalescence and departure. The BXF uses normal-perfluorohexane as the test fluid and will operate between pressures of 60 to 244 Pa. and temperatures of 35 to 60 C. Both sets of experimental heaters are highly instrumented. Pressure and bulk fluid temperature measurements will be made with standard rate video. A high speed video system will be used to visualize the boiling process through the bottom of the MABE heater arrays. The BXF is currently scheduled to fly on Utilization Flight-13A.1 to the ISS with facility integration into the MSG and operation during Increment 15

Evaluation of enhanced thermostability and operational stability of carbonic anhydrase from Micrococcus species.

PubMed

Bhattacharya, Abhishek; Shrivastava, Ankita; Sharma, Anjana

2013-06-01

Carbonic anhydrase (CA) was purified from Micrococcus lylae and Micrococcus luteus with 49.90 and 53.8 % yield, respectively, isolated from calcium carbonate kilns. CA from M. lylae retained 80 % stability in the pH and temperature range of 6.0-8.0 and 35-45 °C, respectively. However, CA from M. luteus was stable in the pH and temperature range of 7.5-10.0 and 35-55 °C, respectively. Cross-linked enzyme aggregates (CLEAs) raised the transition temperature of M. lylae and M. luteus CA up to 67.5 and 74.0 °C, while the operational stability (T(1/20) of CA at 55 °C was calculated to be 7.7 and 12.0 h, respectively. CA from both the strains was found to be monomeric in nature with subunit molecular weight and molecular mass of 29 kDa. Ethoxozolamide was identified as the most potent inhibitor based on both IC(50) values and inhibitory constant measurement (K(i)). The K(m) and V(max) for M. lylae CA (2.31 mM; 769.23 μmol/mg/min) and M. luteus CA (2.0 mM; 1,000 μmol/mg/min) were calculated from Lineweaver-Burk plots in terms of esterase activity. Enhanced thermostability of CLEAs alleviates its role in operational stability for application at an on-site scrubber. The characteristic profile of purified CA from Micrococcus spp. advocates its effective application in biomimetic CO(2) sequestration.

Estimation of the engineering elastic constants of a directionally solidified superalloy for finite element structural analysis

NASA Technical Reports Server (NTRS)

Abdul-Aziz, Ali; Kalluri, Sreeramesh

1991-01-01

The temperature-dependent engineering elastic constants of a directionally solidified nickel-base superalloy were estimated from the single-crystal elastic constants of nickel and MAR-MOO2 superalloy by using Wells' method. In this method, the directionally solidified (columnar-grained) nickel-base superalloy was modeled as a transversely isotropic material, and the five independent elastic constants of the transversely isotropic material were determined from the three independent elastic constants of a cubic single crystal. Solidification for both the single crystals and the directionally solidified superalloy was assumed to be along the (001) direction. Temperature-dependent Young's moduli in longitudinal and transverse directions, shear moduli, and Poisson's ratios were tabulated for the directionally solidified nickel-base superalloy. These engineering elastic constants could be used as input for performing finite element structural analysis of directionally solidified turbine engine components.

High-Temperature Slow Crack Growth of Silicon Carbide Determined by Constant-Stress-Rate and Constant-Stress Testing

NASA Technical Reports Server (NTRS)

Choi, Sung H.; Salem, J. A.; Nemeth, N. N.

1998-01-01

High-temperature slow-crack-growth behaviour of hot-pressed silicon carbide was determined using both constant-stress-rate ("dynamic fatigue") and constant-stress ("static fatigue") testing in flexure at 1300 C in air. Slow crack growth was found to be a governing mechanism associated with failure of the material. Four estimation methods such as the individual data, the Weibull median, the arithmetic mean and the median deviation methods were used to determine the slow crack growth parameters. The four estimation methods were in good agreement for the constant-stress-rate testing with a small variation in the slow-crack-growth parameter, n, ranging from 28 to 36. By contrast, the variation in n between the four estimation methods was significant in the constant-stress testing with a somewhat wide range of n= 16 to 32.

Co and Fe doping effect on negative temperature coefficient characteristics of nano-grained NiMn2O4 thick films fabricated by aerosol-deposition.

PubMed

Ryu, Jungho; Han, Guifang; Lee, Jong-Pil; Lim, Dong-Soo; Park, Yun-Soo; Jeong, Dae-Yong

2013-05-01

Spinel structured highly dense NiMn2O4-based (NMO) negative temperature coefficient (NTC) thermistor thick films were fabricated by aerosol-deposition at room temperature. To enhance the thermistor B constant, which represents the temperature sensitivity of the NMO thermistor material, Co and Co-Fe doping was applied. In the case of single element doping of Co, 5 mol% doped NMO showed a high B constant of over 5000 K, while undoped NMO showed -4000 K. By doping Fe to the 5 mol% Co doped NMO, the B constant was more enhanced at over 5600 K. The aging effect on the NTC characteristics of Co doped and Fe-Co co-doped NMO thick film showed very stable resistivity-time characteristics because of the highly dense microstructure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saha, J.; Chaudhary, S.; Majumdar, P.

We report a study on potential multiferroic characteristics of Yttrium Iron Garnet (YIG). The emergence of ferroelectricity in YIG is in debate but we provide evidence for strong magneto-electric coupling above room temperature from dielectric constant measurement with and without magnetic field. We find that the apparent pseudo-ferroelectric crossover temperature in YIG varies with frequency. For higher frequency the transition shifts towards higher temperature. This is indicative of relaxor behavior. We have also measured the dielectric constant in the presence of external magnetic field at high temperature that confirms interdependence of magnetic and dielectric properties.

In situ fluorescence spectroscopy correlates ionomer degradation to reactive oxygen species generation in an operating fuel cell.

PubMed

Prabhakaran, Venkateshkumar; Arges, Christopher G; Ramani, Vijay

2013-11-21

The rate of generation of reactive oxygen species (ROS) within the polymer electrolyte membrane (PEM) of an operating proton exchange member fuel cell (PEMFC) was monitored using in situ fluorescence spectroscopy. A modified barrier layer was introduced between the PEM and the electrocatalyst layer to eliminate metal-dye interactions and fluorescence resonance energy transfer (FRET) effects during measurements. Standard fuel cell operating parameters (temperature, relative humidity, and electrode potential) were systematically varied to evaluate their influence on the rate of ROS generation during PEMFC operation. Independently, the macroscopic rate of PEM degradation was measured by monitoring the fluoride ion emission rate (FER) in the effluent stream at each operating condition. The ROS generation reaction rate constant (estimated from the in situ fluorescence experiments) correlated perfectly with the measured FER across all conditions, demonstrating unequivocally for the first time that a direct correlation exists between in situ ROS generation and PEM macroscopic degradation. The activation energy for ROS generation within the PEM was estimated to be 12.5 kJ mol(-1).

Physical Analysis of an Electric Resistor Heating

ERIC Educational Resources Information Center

Perea Martins, J. E. M.

2018-01-01

This work describes a simple experiment to measure the resistor temperature as a function of the applied power and proves that it is an efficient way to introduce some important physical concepts in classroom, including the Joule's first law, hot-spot temperature, thermal resistance, thermal dissipation constant, time constant and the Newton's law…

21 CFR 1250.42 - Water systems; constant temperature bottles.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Water systems; constant temperature bottles. 1250.42 Section 1250.42 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) REGULATIONS UNDER CERTAIN OTHER ACTS ADMINISTERED BY THE FOOD AND DRUG ADMINISTRATION INTERSTATE CONVEYANCE SANITATION Equipment and...

Crossflow vorticity sensor

NASA Technical Reports Server (NTRS)

Holmes, Bruce J. (Inventor); Carraway, Debra L. (Inventor); Holmes, Harlan K. (Inventor); Moore, Thomas C. (Inventor)

1988-01-01

A crossflow vorticity sensor for the detection of crossflow vorticity characteristics is described. The sensor is comprised of crossflow sensors which are noninvasively adhered to a swept wing laminar surface either singularly, in multi-element strips, in polar patterns, or in orthogonal patterns. These crossflow sensors are comprised of hot-film sensor elements which operate as a constant temperature anemometer circuit to detect heat transfer rate changes. Accordingly, crossflow vorticity characteristics are determined via cross-correlation. In addition, the crossflow sensors have a thickness which does not exceed a maximum value h in order to avoid contamination of downstream crossflow sensors.

Heating Analysis in Constant-pressure Hydraulic System based on Energy Analysis

NASA Astrophysics Data System (ADS)

Wu, Chao; Xu, Cong; Mao, Xuyao; Li, Bin; Hu, Junhua; Liu, Yiou

2017-12-01

Hydraulic systems are widely used in industrial applications, but the problem of heating has become an important reason to restrict the promotion of hydraulic technology. The high temperature, will seriously affect the operation of the hydraulic system, even cause stuck and other serious failure. Based on the analysis of the heat damage of the hydraulic system, this paper gives the reasons for this problem, and it is showed by the application that the energy analysis can accurately locate the main reasons for the heating of the hydraulic system, which can give strong practical guidance.

Present capabilities and future requirements for computer-aided geometric modeling in the design and manufacture of gas turbine

NASA Technical Reports Server (NTRS)

Caille, E.; Propen, M.; Hoffman, A.

1984-01-01

Gas turbine engine design requires the ability to rapidly develop complex structures which are subject to severe thermal and mechanical operating loads. As in all facets of the aerospace industry, engine designs are constantly driving towards increased performance, higher temperatures, higher speeds, and lower weight. The ability to address such requirements in a relatively short time frame has resulted in a major thrust towards integrated design/analysis/manufacturing systems. These computer driven graphics systems represent a unique challenge, with major payback opportunities if properly conceived, implemented, and applied.

High voltage solar cell power generating system

NASA Technical Reports Server (NTRS)

Levy, E., Jr.; Opjorden, R. W.; Hoffman, A. C.

1974-01-01

A laboratory solar power system regulated by on-panel switches has been delivered for operating high power (3 kW), high voltage (15,000 volt) loads (communication tubes, ion thrusters). The modular system consists of 26 solar arrays, each with an integral light source and cooling system. A typical array contains 2,560 series-connected cells. Each light source consists of twenty 500-watt tungsten iodide lamps providing plus or minus 5 percent uniformity at one solar constant. An array temperature of less than 40 C is achieved using an infrared filter, a water-cooled plate, a vacuum hold-down system, and air flushing.

Development of emission factors for polycarbonate processing.

PubMed

Rhodes, Verne L; Kriek, George; Lazear, Nelson; Kasakevich, Jean; Martinko, Marie; Heggs, R P; Holdren, M W; Wisbith, A S; Keigley, G W; Williams, J D; Chuang, J C; Satola, J R

2002-07-01

Emission factors for selected volatile organic compounds (VOCs) and particulate emissions were developed while processing eight commercial grades of polycarbonate (PC) and one grade of a PC/acrylonitrile-butadiene-styrene (ABS) blend. A small commercial-type extruder was used, and the extrusion temperature was held constant at 304 degrees C. An emission factor was calculated for each substance measured and is reported as pounds released to the atmosphere/million pounds of polymer resin processed [ppm (wt/wt)]. Scaled to production volumes, these emission factors can be used by processors to estimate emission quantities from similar PC processing operations.

[Absence of blood circulation following toe-hand transplantation in a 7-year-old girl with monodactyle form of symbrachydactyly].

PubMed

Coenen, L; Brouwers, J

1990-03-01

In a toe transplantation in a child with symbrachydactyly the authors were faced with a no-reflow phenomenon. The medication they used in prophylaxis was not an absolute guarantee to prevent this problem. Success also depends on some general measures, as a stable blood pressure, a constant blood volume, normal body temperature, short operation time, and an early revision in case of a no-reflow phenomenon. Some questions about the appearance of spasm still remain: are they provoked by pain, stress, medication as anaesthetics, or is a congenital structural vessel problem responsible?

Three-dimensional ordering of cold ion beams in a storage ring: A molecular-dynamics simulation study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuri, Yosuke, E-mail: yuri.yosuke@jaea.go.jp

Three-dimensional (3D) ordering of a charged-particle beams circulating in a storage ring is systematically studied with a molecular-dynamics simulation code. An ion beam can exhibit a 3D ordered configuration at ultralow temperature as a result of powerful 3D laser cooling. Various unique characteristics of the ordered beams, different from those of crystalline beams, are revealed in detail, such as the single-particle motion in the transverse and longitudinal directions, and the dependence of the tune depression and the Coulomb coupling constant on the operating points.

Behavior data of battery and battery pack SOC estimation under different working conditions.

PubMed

Zhang, Xu; Wang, Yujie; Yang, Duo; Chen, Zonghai

2016-12-01

This article provides the dataset of operating conditions of battery behavior. The constant current condition and the dynamic stress test (DST) condition were carried out to analyze the battery discharging and charging features. The datasets were achieved at room temperature, in April, 2016. The shared data contributes to clarify the battery pack state-of-charge (SOC) and the battery inconsistency, which is also shown in the article of "An on-line estimation of battery pack parameters and state-of-charge using dual filters based on pack model" (X. Zhang, Y. Wang, D. Yang, et al., 2016) [1].

Improved Performance in Mammalian Cell Perfusion Cultures by Growth Inhibition.

PubMed

Wolf, Moritz K F; Closet, Aurélie; Bzowska, Monika; Bielser, Jean-Marc; Souquet, Jonathan; Broly, Hervé; Morbidelli, Massimo

2018-05-21

Mammalian cell perfusion cultures represent a promising alternative to the current fed-batch technology for the production of various biopharmaceuticals. Long-term operation at a fixed viable cell density (VCD) requires a viable culture and a constant removal of excessive cells. Product loss in the cell removing bleed stream deteriorates the process yield. In this study, the authors investigate the use of chemical and environmental growth inhibition on culture performance by either adding valeric acid (VA) to the production media or by reducing the culture temperature (33.0 °C) with respect to control conditions (36.5 °C, no VA). Low temperature significantly reduces cellular growth, thus, resulting in lower bleed rates accompanied by a reduced product loss of 11% compared to 26% under control conditions. Additionally, the cell specific productivity of the target protein improves and maintained stable leading to media savings per mass of product. VA shows initially an inhibitory effect on cellular growth. However, cells seemed to adapt to the presence of the inhibitor resulting in a recovery of the cellular growth. Cell cycle and Western blot analyses support the observed results. This work underlines the role of temperature as a key operating variable for the optimization of perfusion cultures. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The effects of surface evaporation parameterizations on climate sensitivity to solar constant variations

NASA Technical Reports Server (NTRS)

Chou, S.-H.; Curran, R. J.; Ohring, G.

1981-01-01

The effects of two different evaporation parameterizations on the sensitivity of simulated climate to solar constant variations are investigated by using a zonally averaged climate model. One parameterization is a nonlinear formulation in which the evaporation is nonlinearly proportional to the sensible heat flux, with the Bowen ratio determined by the predicted vertical temperature and humidity gradients near the earth's surface (model A). The other is the formulation of Saltzman (1968) with the evaporation linearly proportional to the sensible heat flux (model B). The computed climates of models A and B are in good agreement except for the energy partition between sensible and latent heat at the earth's surface. The difference in evaporation parameterizations causes a difference in the response of temperature lapse rate to solar constant variations and a difference in the sensitivity of longwave radiation to surface temperature which leads to a smaller sensitivity of surface temperature to solar constant variations in model A than in model B. The results of model A are qualitatively in agreement with those of the general circulation model calculations of Wetherald and Manabe (1975).

Trends in electron-ion dissociative recombination of benzene analogs with functional group substitutions: Negative Hammett σpara values

NASA Astrophysics Data System (ADS)

Osborne, David; Lawson, Patrick Andrew; Adams, Nigel; Dotan, Itzhak

2014-06-01

An in-depth study of the effects of functional group substitution on benzene's electron-ion dissociative recombination (e-IDR) rate constant has been conducted. The e-IDR rate constants for benzene, biphenyl, toluene, ethylbenzene, anisole, phenol, and aniline have been measured using a Flowing Afterglow equipped with an electrostatic Langmuir probe (FALP). These measurements have been made over a series of temperatures from 300 to 550 K. A relationship between the Hammett σpara values for each compound and rate constant has indicated a trend in the e-IDR rate constants and possibly in their temperature dependence data. The Hammett σpara value is a method to describe the effect a functional group substituted to a benzene ring has upon the reaction rate constant.

Improved analysis of transient temperature data from permanent down-hole gauges (PDGs)

NASA Astrophysics Data System (ADS)

Zhang, Yiqun; Zheng, Shiyi; Wang, Qi

2017-08-01

With the installation of permanent down-hole gauges (PDGs) during oil field development, large volumes of high resolution and continuous down-hole information are obtainable. The interpretation of these real-time temperature and pressure data can optimize well performance, provide information about the reservoir and continuously calibrate the reservoir model. Although the dynamic temperature data have been interpreted in practice to predict flow profiling and provide characteristic information of the reservoir, almost all of the approaches rely on established non-isothermal models which depend on thermodynamic parameters. Another problem comes from the temperature transient analysis (TTA), which is underutilized compared with pressure transient analysis (PTA). In this study, several model-independent methods of TTA were performed. The entire set of PDG data consists of many flow events. By utilizing the wavelet transform, the exact points of flow-rate changes can be located. The flow regime changes, for example, from early time linear flow to later time pseudo-radial flow, among every transient period with constant flow-rate. For the early time region (ETR) that is caused by flow-rate change operations, the TTA, along with the PTA can greatly reduce the uncertainties in flow regime diagnosis. Then, the temperature variations during ETR were examined to infer the true reservoir temperature history, and the relationships between the wavelet detailed coefficients and the flow-rate changes were analysed. For the scenarios with constant reservoir-well parameters, the detailed flow-rate history can be generated by calculating the coefficient of relationship in advance. For later times, the flow regime changes to pseudo-radial flow. An analytical solution was introduced to describe the sand-face temperature. The formation parameters, such as permeability and skin factor, were estimated with the previously calculated flow-rate. It is necessary to analyse temperature variation to overcome data limitation problems when information from other down-hole tools (e.g. expensive but unstable flow meters) is insufficient. This study shows the success in wellbore storage regime diagnosis, flow-rate history reconstruction, and formation parameters estimation using transient temperature data.

A laser flash photolysis-resonance fluorescence kinetics study of the reaction Cl/2P/ + CH4 yields CH3 + HCl

NASA Technical Reports Server (NTRS)

Ravishankara, A. R.; Wine, P. H.

1980-01-01

The technique of laser flash photolysis-resonance fluorescence is employed to study the kinetics of the reaction Cl(2P) + CH4 yields CH3 + HCl over the temperature range 221-375 K. At temperatures less than or equal to 241 K the apparent bimolecular rate constant is found to be dependent upon the identity of the chemically inert gases in the reaction mixture. For Cl2/CH4/He reaction mixtures (total pressure = 50 torr) different bimolecular rate constants are measured at low and high methane concentrations. For Cl2/CH4/CCl/He and Cl2/CH4/Ar reaction mixtures, the bimolecular rate constant is independent of methane concentration, being approximately equal to the rate constant measured at low methane concentrations for Cl2/CH4/He mixtures. These rate constants are in good agreement with previous results obtained using the discharge flow-resonance fluorescence and competitive chlorination techniques. At 298 K the measured bimolecular rate constant is independent of the identity of the chemically inert gases in the reaction mixture and in good agreement with all previous investigations. The low-temperature results obtained in this investigation and all previous investigations can be rationalized in terms of a model which assumes that the Cl(2P 1/2) state reacts with CH4 much faster than the Cl(2P 3/2) state. Extrapolation of this model to higher temperatures, however, is not straightforward.

Discovery of a Significant Acetone•Hydroperoxy Adduct Chaperone Effect and Its Impact on the Determination of Room Temperature Rate Constants for Acetonylperoxy/Hydroperoxy Self-Reactions and Cross Reaction Via Infrared Kinetic Spectroscopy.

NASA Astrophysics Data System (ADS)

Grieman, F. J.; Hui, A. O.; Okumura, M.; Sander, S. P.

2017-12-01

In order to model the upper troposphere/lower stratosphere in regions containing acetone properly, the kinetics of the acetonylperoxy/hydroperoxy self-reactions and cross reaction have been studied over a wide temperature range using Infrared Kinetic Spectroscopy. We report here the determination of different rate constants for the acetonylperoxy chemistry that we obtained at 298 K compared to currently accepted values. A considerable increase in the observed HO2 self-reaction rate constant due to rate enhancement via the chaperone effect from the reaction between HO2 and the (CH3)2CO•HO2 hydrogen-bonded adduct, even at room temperature, was discovered that was previously ignored. Correct determination of the acetonylperoxy and hydroperoxy kinetics must include this dependence of the HO2 self-reaction rate on acetone concentration. Via excimer laser flash photolysis to create the radical reactants, HO2 absorption was monitored in the infrared by diode laser wavelength modulation detection simultaneously with CH3C(O)CH2O2absorption monitored in the ultraviolet at 300 nm as a function of time. Resulting decay curves were fit concurrently first over a short time scale to obtain the rate constants minimizing subsequent product reactions. Modeling/fitting with a complete reaction scheme was then performed to refine the rate constants and test their veracity. Experiments were carried out over a variety of concentrations of acetone and methanol. Although no effect due to methanol concentration was found at room temperature, the rate constant for the hydroperoxy self-reaction was found to increase linearly with acetone concentration which is interpreted as the adduct being formed and resulting in a chaperone mechanism that enhances the self-reaction rate: (CH3)2CO·HO2 + HO2 → H2O2 + O2 + (CH3)2CO Including this effect, the resulting room temperature rate constants for the cross reaction and the acetonylperoxy self-reaction were found to be 2-3 times smaller than previously reported. This complex formation/chaperone mechanism is similar to that found for methanol, but different in that it occurs at room temperature. No precursor concentration dependence was found for the acetonylperoxy radical reactions. The equilibrium constant for the complex formation will also be presented.

Thermal requirements of Dermanyssus gallinae (De Geer, 1778) (Acari: Dermanyssidae).

PubMed

Tucci, Edna Clara; do Prado, Angelo P; de Araújo, Raquel Pires

2008-01-01

The thermal requirements for development of Dermanyssus gallinae were studied under laboratory conditions at 15, 20, 25, 30 and 35 degrees C, a 12h photoperiod and 60-85% RH. The thermal requirements for D. gallinae were as follows. Preoviposition: base temperature 3.4 degrees C, thermal constant (k) 562.85 degree-hours, determination coefficient (R(2)) 0.59, regression equation: Y= -0.006035 + 0.001777x. Egg: base temperature 10.60 degrees C, thermal constant (k) 689.65 degree-hours, determination coefficient (R(2)) 0.94, regression equation: Y= -0.015367 + 0.001450x. Larva: base temperature 9.82 degrees C, thermal constant (k) 464.91 degree-hours, determination coefficient (R(2)) 0.87, regression equation: Y= -0.021123 + 0.002151x. Protonymph: base temperature 10.17 degrees C, thermal constant (k) 504.49 degree-hours, determination coefficient (R(2)) 0.90, regression equation: Y= -0.020152 + 0.001982x. Deutonymph: base temperature 11.80 degrees C, thermal constant (k) 501.11 degree-hours, determination coefficient (R(2)) 0.99, regression equation: Y= -0.023555 + 0.001996x. The results obtained showed that 15 to 42 generations of Dermanyssus gallinae may occur during the year in the State of São Paulo, as estimated based on isotherm charts. Dermanyssus gallinae may develop continually in the State of São Paulo, with a population decrease in the winter. There were differences between the developmental stages of D. gallinae in relation to thermal requirements.

Numerical modeling of the thermoelectric cooler with a complementary equation for heat circulation in air gaps

NASA Astrophysics Data System (ADS)

Fang, En; Wu, Xiaojie; Yu, Yuesen; Xiu, Junrui

2017-03-01

In this paper, a numerical model is developed by combining thermodynamics with heat transfer theory. Taking inner and external multi-irreversibility into account, it is with a complementary equation for heat circulation in air gaps of a steady cooling system with commercial thermoelectric modules operating in refrigeration mode. With two modes concerned, the equation presents the heat flowing through air gaps which forms heat circulations between both sides of thermoelectric coolers (TECs). In numerical modelling, a TEC is separated as two temperature controlled constant heat flux reservoirs in a thermal resistance network. In order to obtain the parameter values, an experimental apparatus with a commercial thermoelectric cooler was built to characterize the performance of a TEC with heat source and sink assembly. At constant power dissipation, steady temperatures of heat source and both sides of the thermoelectric cooler were compared with those in a standard numerical model. The method displayed that the relationship between Φf and the ratio Φ_{c}'/Φ_{c} was linear as expected. Then, for verifying the accuracy of proposed numerical model, the data in another system were recorded. It is evident that the experimental results are in good agreement with simulation(proposed model) data at different heat transfer rates. The error is small and mainly results from the instabilities of thermal resistances with temperature change and heat flux, heat loss of the device vertical surfaces and measurements.

Application of the two-film model to the volatilization of acetone and t-butyl alcohol from water as a function of temperature

USGS Publications Warehouse

Rathbun, R.E.; Tai, D.Y.

1988-01-01

The two-film model is often used to describe the volatilization of organic substances from water. This model assumes uniformly mixed water and air phases separated by thin films of water and air in which mass transfer is by molecular diffusion. Mass-transfer coefficients for the films, commonly called film coefficients, are related through the Henry's law constant and the model equation to the overall mass-transfer coefficient for volatilization. The films are modeled as two resistances in series, resulting in additive resistances. The two-film model and the concept of additivity of resistances were applied to experimental data for acetone and t-butyl alcohol. Overall mass-transfer coefficients for the volatilization of acetone and t-butyl alcohol from water were measured in the laboratory in a stirred constant-temperature bath. Measurements were completed for six water temperatures, each at three water mixing conditions. Wind-speed was constant at about 0.1 meter per second for all experiments. Oxygen absorption coefficients were measured simultaneously with the measurement of the acetone and t-butyl alcohol mass-transfer coefficients. Gas-film coefficients for acetone, t-butyl alcohol, and water were determined by measuring the volatilization fluxes of the pure substances over a range of temperatures. Henry's law constants were estimated from data from the literature. The combination of high resistance in the gas film for solutes with low values of the Henry's law constants has not been studied previously. Calculation of the liquid-film coefficients for acetone and t-butyl alcohol from measured overall mass-transfer and gas-film coefficients, estimated Henry's law constants, and the two-film model equation resulted in physically unrealistic, negative liquid-film coefficients for most of the experiments at the medium and high water mixing conditions. An analysis of the two-film model equation showed that when the percentage resistance in the gas film is large and the gas-film resistance approaches the overall resistance in value, the calculated liquid-film coefficient becomes extremely sensitive to errors in the Henry's law constant. The negative coefficients were attributed to this sensitivity and to errors in the estimated Henry's law constants. Liquid-film coefficients for the absorption of oxygen were correlated with the stirrer Reynolds number and the Schmidt number. Application of this correlation with the experimental conditions and a molecular-diffusion coefficient adjustment resulted in values of the liquid-film coefficients for both acetone and t-butyl alcohol within the range expected for all three mixing conditions. Comparison of Henry's law constants calculated from these film coefficients and the experimental data with the constants calculated from literature data showed that the differences were small relative to the errors reported in the literature as typical for the measurement or estimation of Henry's law constants for hydrophilic compounds such as ketones and alcohols. Temperature dependence of the mass-transfer coefficients was expressed in two forms. The first, based on thermodynamics, assumed the coefficients varied as the exponential of the reciprocal absolute temperature. The second empirical approach assumed the coefficients varied as the exponential of the absolute temperature. Both of these forms predicted the temperature dependence of the experimental mass-transfer coefficients with little error for most of the water temperature range likely to be found in streams and rivers. Liquid-film and gas-film coefficients for acetone and t-butyl alcohol were similar in value. However, depending on water mixing conditions, overall mass-transfer coefficients for acetone were from two to four times larger than the coefficients for t-butyl alcohol. This difference in behavior of the coefficients resulted because the Henry's law constant for acetone was about three times larger than that of

Influence of temperature during grain filling on gluten viscoelastic properties and gluten protein composition.

PubMed

Koga, Shiori; Böcker, Ulrike; Moldestad, Anette; Tosi, Paola; Shewry, Peter R; Mosleth, Ellen F; Uhlen, Anne Kjersti

2016-01-15

The aim of this study was to investigate the effects of low to moderate temperatures on gluten functionality and gluten protein composition. Four spring wheat cultivars were grown in climate chambers with three temperature regimes (day/night temperatures of 13/10, 18/15 and 23/20 °C) during grain filling. The temperature strongly influenced grain weight and protein content. Gluten quality measured by maximum resistance to extension (Rmax ) was highest in three cultivars grown at 13 °C. Rmax was positively correlated with the proportion of sodium dodecyl sulfate-unextractable polymeric proteins (%UPP). The proportions of ω-gliadins and D-type low-molecular-weight glutenin subunits (LMW-GS) increased and the proportions of α- and γ-gliadins and B-type LMW-GS decreased with higher temperature, while the proportion of high-molecular-weight glutenin subunits (HMW-GS) was constant between temperatures. The cultivar Berserk had strong and constant Rmax between the different temperatures. Constant low temperature, even as low as 13 °C, had no negative effects on gluten quality. The observed variation in Rmax related to temperature could be explained more by %UPP than by changes in the proportions of HMW-GS or other gluten proteins. The four cultivars responded differently to temperature, as gluten from Berserk was stronger and more stable over a wide range of temperatures. © 2015 Society of Chemical Industry.

Monte Carlo Study of Melting of a Model Bulk Ice.

NASA Astrophysics Data System (ADS)

Han, Kyu-Kwang

The methods of NVT (constant number, volume and temperature) and NPT (constant number, pressure and temperature) Monte Carlo computer simulations are used to examine the melting of a periodic hexagonal ice (ice Ih) sample with a unit cell of 192 (rigid) water molecules interacting via the revised central force potentials of Stillinger and Rahman (RSL2). In NVT Monte Carlo simulation of P-T plot for a constant density (0.904g/cm^3) is used to locate onset of the liquid-solid coexistence region (where the slope of the pressure changes sign) and estimate the (constant density) melting point. The slope reversal is a natural consequence of the constant density condition for substances which expand upon freezing and it is pointed out that this analysis is extremely useful for substances such as water. In this study, a sign reversal of the pressure slope is observed near 280 K, indicating that the RSL2 potentials reproduce the freezing expansion expected for water and support a bulk ice Ih system which melts <280 K. The internal energy, specific heat, and two dimensional structure factors for the constant density H_2O system are also examined at a range of temperatures between 100 and 370 K and support the P-T analysis for location of the melting point. This P-T analysis might likewise be useful for determining a (constant density) freezing point, or, with multiple simulations at appropriate densities, the triple point. For NPT Monte Carlo simulations preliminary results are presented. In this study the density, enthalpy, specific heat, and structure factor dependences on temperature are monitored during a sequential heating of the system from 100 to 370 K at a constant pressure (1 atm.). A jump in density upon melting is observed and indicates that the RSL2 potentials reproduce the melting contraction of ice. From the dependences of monitored physical properties on temperature an upper bound on the melting temperature is estimated. In this study we made the first analysis and calculation of the P-T curve for ice Ih melting at constant volume and the first NPT study of ice and of ice melting. In the NVT simulation we found for rho = 0.904g/cm^3 T_ {rm m} ~eq 280 K which is much closer to physical T_ {rm m} than any other published NVT simulation of ice. Finally it is shown that RSL2 potentials do a credible job of describing the thermodynamic properties of ice Ih near its melting point.

Rail-to-rail differential input amplification stage with main and surrogate differential pairs

DOEpatents

Britton, Jr., Charles Lanier; Smith, Stephen Fulton

2007-03-06

An operational amplifier input stage provides a symmetrical rail-to-rail input common-mode voltage without turning off either pair of complementary differential input transistors. Secondary, or surrogate, transistor pairs assume the function of the complementary differential transistors. The circuit also maintains essentially constant transconductance, constant slew rate, and constant signal-path supply current as it provides rail-to-rail operation.

The Rate Constant for the Reaction H + C2H5 at T = 295 - 150K

NASA Technical Reports Server (NTRS)

Pimentel, Andre S.; Payne, Walter A.; Nesbitt, Fred L.; Cody, Regina J.; Stief, Louis J.

2004-01-01

The reaction between the hydrogen atom and the ethyl (C2H3) radical is predicted by photochemical modeling to be the most important loss process for C2H5 radicals in the atmospheres of Jupiter and Saturn. This reaction is also one of the major sources for the methyl radicals in these atmospheres. These two simplest hydrocarbon radicals are the initial species for the synthesis of larger hydrocarbons. Previous measurements of the rate constant for the H + C2H5 reaction varied by a factor of five at room temperature, and some studies showed a dependence upon temperature while others showed no such dependence. In addition, the previous studies were at higher temperatures and generally higher pressures than that needed for use in planetary atmospheric models. The rate constant for the reaction H + C2H5 has been measured directly at T = 150, 202 and 295 K and at P = 1.0 Torr He for all temperatures and additionally at P = 0.5 and 2.0 Torr He at T = 202 K. The measurements were performed in a discharge - fast flow system. The decay of the C2H5 radical in the presence of excess hydrogen was monitored by low-energy electron impact mass spectrometry under pseudo-first order conditions. H atoms and C2H5 radicals were generated rapidly and simultaneously by the reaction of fluorine atoms with H2 and C2H6, respectively. The total rate constant was found to be temperature and pressure independent. The measured total rate constant at each temperature are: k(sub 1)(295K) = (1.02+/-0.24)x10(exp -10), k(sub 1)(202K) = (1.02+/-0.22)x10(exp -10) and k(sub 1)(150K) = (0.93+/-0.21)x10(exp -10), all in units of cu cm/molecule/s. The total rate constant derived from all the combined measurements is k(sub 1) = (l.03+/-0.17)x10(exp -10) cu cm/molecule/s. At room temperature our results are about a factor of two higher than the recommended rate constant and a factor of three lower than the most recently published study.

High temperature sensor/microphone development for active noise control

NASA Technical Reports Server (NTRS)

Shrout, Thomas R.

1993-01-01

The industrial and scientific communities have shown genuine interest in electronic systems which can operate at high temperatures, among which are sensors to monitor noise, vibration, and acoustic emissions. Acoustic sensing can be accomplished by a wide variety of commercially available devices, including: simple piezoelectric sensors, accelerometers, strain gauges, proximity sensors, and fiber optics. Of the several sensing mechanisms investigated, piezoelectrics were found to be the most prevalent, because of their simplicity of design and application and, because of their high sensitivity over broad ranges of frequencies and temperature. Numerous piezoelectric materials are used in acoustic sensors today; but maximum use temperatures are imposed by their transition temperatures (T(sub c)) and by their resistivity. Lithium niobate, in single crystal form, has the highest operating temperature of any commercially available material, 650 C; but that is not high enough for future requirements. Only two piezoelectric materials show potential for use at 1000 C; AlN thin film reported to be piezoactive at 1150 C, and perovskite layer structure (PLS) materials, which possess among the highest T(sub c) (greater than 1500 C) reported for ferroelectrics. A ceramic PLS composition was chosen. The solid solution composition, 80% strontium niobate (SN) and 20% strontium tantalate (STa), with a T(sub c) approximately 1160 C, was hot forged, a process which concurrently sinters and renders the plate-like grains into a highly oriented configuration to enhance piezo properties. Poled samples of this composition showed coupling (k33) approximately 6 and piezoelectric strain constant (d33) approximately 3. Piezoactivity was seen at 1125 C, the highest temperature measurement reported for a ferroelectric ceramic. The high temperature piezoelectric responses of this, and similar PLS materials, opens the possibility of their use in electronic devices operating at temperatures up to 1000 C. Concurrent with the materials study was an effort to define issues involved in the development of a microphone capable of operation at temperatures up to 1000 C; important since microphones capable of operation above 260 C are not generally available. The distinguishing feature of a microphone is its diaphragm which receives sound from the atmosphere: whereas, most other acoustic sensors receive sound through the solid structure on which they are installed. In order to gain an understanding of the potential problems involved in designing and testing a high temperature microphone, a prototype was constructed using a commercially available lithium niobate piezoelectric element in a stainless steel structure. The prototype showed excellent frequency response at room temperature, and responded to acoustic stimulation at 670 C, above which temperature the voltage output rapidly diminished because of decreased resistivity in the element. Samples of the PLS material were also evaluated in a simulated microphone configuration, but their voltage output was found to be a few mV compared to the 10 output of the prototype.