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Sample records for contaminated dredged material

  1. Assessment/management of dredged material to minimize contaminant-related impacts: An international perspective

    SciTech Connect

    Nauke, M.K.

    1995-12-31

    Close attention must be given to the effects of dredging and disposal operations on the marine environment. The globally applicable Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter (London Convention 1972), in conjunction with resolutions adopted there under, provides regulations and guidance regarding sea disposal of dredged material. For this purpose the Dredged Material Assessment Framework developed in 1995 provides advice to decision-makers in the field of management of dredged material, incorporating knowledge and experience gained by Contracting Parties to the Convention on potential environmental impacts of dredging operations. Characterization of dredged material is requested with regard to physical and chemical characteristics, including geochemical parameters, potential routes and previous soils of contaminants in the area, and biological characteristics, including tests to determine acute and chronic toxicity, the potential for bioaccumulation and the potential for tainting aquatic living resources. The results of the physical/chemical/biological characterization will indicate whether the dredged material is suitable for disposal at sea. For material found to be unsuitable for beneficial uses, disposal at sea or disposal on land, disposal management techniques will have to be used to reduce or control impacts to a level that-will not constitute an unacceptable risk to human health, or harm living resources, damage amenities or interfere with legitimate uses of the sea. Disposal management techniques may include burial in the sea floor followed by clean sediment capping, selection of special sites, or methods of containment. The Assessment Framework further includes criteria for selection of sea disposal sites, advice for the conduct of impact assessments, and of post-operational monitoring.

  2. Model and assessment of the contribution of dredged material disposal to sea-surface contamination in Puget Sound

    SciTech Connect

    Hardy, J.T.; Cowan, C.E.

    1986-02-01

    Hydrophobic or floatable materials released to the water column during dredge disposal operations may accumulate in high concentrations on the water surface. If such surface accumulations occur, they could impact the reproduction of fish and shellfish with neustonic (floating) eggs or larvae. Also, floatable surface contaminants could deposit on nearby beaches. In order to examine the potential impacts of such processes, an interactive computer (IBM PC) model was developed. The FORTRAN model allows input of contaminant concentrations on the dredge material, the surface area of the disposal site, the floatable fraction of the contaminated material, and the baseline concentrations of contaminants present in the sea-surface microlayer. The model then computes the resultant concentrations of each contaminant in the microlayer and the potential impact on floating fish eggs. The utility of the model would be greatly improved by empirical data, not yeat available, on the vertical upward and lateral movement of contaminants during dredge material disposal.

  3. Air emissions from exposed contaminated sediments and dredged material

    SciTech Connect

    Valsaraj, K.T.; Ravikrishna, R.; Reible, D.D.; Thibodeaux, L.J.; Choy, B.; Price, C.B.; Brannon, J.M.; Myers, T.E.; Yost, S.

    1999-01-01

    The sediment-to-air fluxes of two polycyclic aromatic hydrocarbons (phenanthrene and pyrene) and a heterocyclic aromatic hydrocarbon (dibenzofuran) from a laboratory-contaminated sediment and those of three polycyclic aromatic hydrocarbons (naphthalene, phenanthrene, and pyrene) from three field sediments were investigated in experimental microcosms. The flux was dependent on the sediment moisture content, air-filled porosity, and the relative humidity of the air flowing over the sediment surface. The mathematical model predictions of flux from the laboratory-spiked sediment agreed with observed values. The fluxes of compounds with higher hydrophobicity were more air-side resistance controlled. Conspicuous differences were observed between the fluxes from the laboratory-spiked and two of the three field sediments. Two field sediments showed dramatic increases in mass-transfer resistances with increasing exposure time and had significant fractions of oil and grease. The proposed mathematical model was inadequate for predicting the flux from the latter field sediments. Sediment reworking enhanced the fluxes from the field sediments due to exposure of fresh solids to the air. Variations in flux from the lab-spiked sediment as a result of change in air relative humidity were due to differences in retardation of chemicals on a dry or wet surface sediment. High moisture in the air over the dry sediment increased the competition for sorption sites between water and contaminant and increased the contaminant flux.

  4. Ecotoxicity Assessment of Contaminated Dredged Material with the Marine Amphipod Corophium volutator

    PubMed

    Ciarelli; Vonck; van Straalen NM; Stronkhorst

    1998-05-01

    The incorporation of toxicological data from bioassays can improve the present system of sediment quality criteria in the Netherlands. The use of acute lethality toxicity tests alone does not however provide sufficient discrimination and sensitivity for predicting ecological effects of slightly and moderately contaminated dredged material. Sublethal endpoints are needed for the assessment of environmental hazards of such dredged material. In this study, two approaches were used to identify toxicity of marine sediments collected from 16 locations classified as "slightly and moderately contaminated" on the basis of chemical data: (1) a comparison of growth vs. mortality as different endpoints in the marine amphipod Corophium volutator (Pallas); (2) an investigation on the use of sediment dilutions to characterize the degree of toxicity. The influence of sediment storage time on toxicity was also evaluated. In four out of 16 locations, mortality over 10 days of exposure ranged 80-100%; in two out of 16 locations mortality ranged 40-60%. In the other 10 locations, mortality was below 15%. Results on growth showed that in all locations final dry weight values were significantly lower (a factor of 1.5 to 3) than in controls. Results of dilution experiments showed that if sediments were diluted with a reference sediment of similar physicochemical characteristics, total concentrations of metals, mineral oil, and PAHs decreased as expected and so did the effects on C. volutator. In the 100% contaminated sediments growth was reduced by 32-60% compared to controls. The dilution rate necessary to reduce toxicity to the EC10 value for growth of C. volutator was considered an appropriate endpoint for the evaluation. When sediments were stored for a period of 3-5 months at 4 degreesC and retested, effects on mortality and growth decreased, although some effects on growth were still measured after 5 months of storage. The experiments illustrate the usefulness of ecotoxicity

  5. Effects of contaminants in dredge material from the Lower Savannah River

    USGS Publications Warehouse

    Winger, P.V.; Lasier, P.J.; White, D.H.; Seginak, J.T.

    2000-01-01

    Contaminants entering aquatic systems from agricultural, industrial, and municipal activities are generally sequestered in bottom sediments. The environmental significance of contaminants associated with sediments dredged from Savannah Harbor, Georgia, USA, are unknown. To evaluate potential effects of contaminants in river sediments and sediments dredged and stored in upland disposal areas on fish and wildlife species, solid-phase sediment and sediment pore water from Front River, Back River, an unnamed Tidal Creek on Back River, and Middle River of the distributary system of the lower Savannah River were tested for toxicity using the freshwater amphipod Hyalella azteca. In addition, bioaccumulation of metals from sediments collected from two dredge-disposal areas was determined using the freshwater oligochaete Lumbriculus variegatus. Livers from green-winged teals (Anas crecca) and lesser yellowlegs (Tringa flavipes) foraging in the dredge-spoil areas and raccoons (Procyon lotor) from the dredge-disposal/river area and an upland site were collected for metal analyses. Survival of H. azteca was not reduced in solid-phase sediment exposures, but was reduced in pore water from several locations receiving drainage from dredge-disposal areas. Basic water chemistry (ammonia, alkalinity, salinity) was responsible for the reduced survival at several sites, but PAHs, metals, and other unidentified factors were responsible at other sites. Metal residues in sediments from the Tidal Creek and Middle River reflected drainage or seepage from adjacent dredge-disposal areas, which could potentially reduce habitat quality in these areas. Trace metals increased in L. variegatus exposed in the laboratory to dredge-disposal sediments; As, Cu, Hg, Se, and Zn bioaccumulated to concentrations higher than those in the sediments. Certain metals (Cd, Hg, Mo, Se) were higher in livers of birds and raccoons than those in dredge-spoil sediments suggesting bioavailability. Cadmium, Ct, Hg, Pb

  6. Contaminant Area Aquaculture Program. Determination of the chemical suitability of a dredged material containment area for aquaculture. Final technical report

    SciTech Connect

    Tatem, H.E.

    1990-12-01

    This concerns use of dredged material containment areas (DMCA) for aquaculture, specifically for production of a crop intended for human consumption. New DMCA's used only periodically for dredged material disposal could be managed to produce valuable crops. Previous studies conducted by the Corps of Engineers, including one where shrimp was raised at a DMCA, and others relating to the effects of sediment contaminants on aquatic organisms, are reviewed. The literature indicated that most dredged material is uncontaminated and that many sediment constituents such as metal are relatively unavailable to aquatic animals; DMCAs containing parts-per-million levels of organic contaminants such as pesticides, polychlorinated biphenyls, or petroleum hydrocarbons should not be used for aquaculture without extensive testing.

  7. Use of hydrocyclone and flotation column for reducing the volume of contaminated dredged material.

    PubMed

    Park, K H; Lee, J H; Bae, B H; Kim, Y H; Choung, Y K

    2006-01-01

    As sediment contamination problems have recently been raised in Korea, the need for technologies to clean contaminants in sediments has increased. Although the recalcitrant organic matters and heavy metals in the contaminated sediments are of primary concern, large amounts of sediment makes the removal of the contaminants in them more difficult. In this study, the performance of hydrocyclone and flotation column was tested to reduce the volume of contaminated dredged materials (CDMs) prior to treating recalcitrant matters, such as various organic chemicals and heavy metals, in an integrated treatment system. When hydrocyclone was operated with 10% (w/v) solids concentration of the feed slurry, the total solids of upflow products were 4 to 7% (w/v) when the inlet pressure was changed from 1.0 to 2.0 kg/cm2. The volume reduction ratio of CDMs by hydrocyclone was approximately 90% (v/v). When the upflow products in hydrocyclone was then spiked with automobile transmission oil and fed to the flotation colum to see the performance of the column flotation on the volume reduction and the TPH removal, 44% of the TPHs in feed were removed at the tails and the volume reduction ratio of CDMs by column flotation was 18% at 200 L/min of wash water. The flotation column could be proposed as a potential preliminary treatment process of CDMs prior to subsequent biological treatments.

  8. Beneficial Use of Dredged Material

    EPA Pesticide Factsheets

    An important goal of managing dredged material is to ensure that the material is used or disposed of in an environmentally sound manner.Most of this dredged material could be used in a beneficial manner instead.

  9. Heavy Metal Uptake, Translocation, and Bioaccumulation Studies of Triticum aestivum Cultivated in Contaminated Dredged Materials

    PubMed Central

    Shumaker, Ketia L.; Begonia, Gregorio

    2005-01-01

    Phytoremediation is a technology that uses vegetation to remediate contaminants from water, soil, and sediments. Unlike traditional remediation techniques such as soil washing or vitrification, phytoremediation offers a technology that is solar-driven, aesthetically pleasing, and cost effective. Recent studies indicate that winter wheat (Triticum aestivum L.) is a potential accumulator for heavy metals such as lead (Pb) and cadmium (Cd) in hydroponic systems. Based on these findings, a laboratory study was conducted with the primary objective of determining the phytoaccumulation capability of this plant species for heavy metals from contaminated dredged materials (DMs) originating from two confined disposal facilities (CDF). The United States Army Corps of Engineers (USACE) manages several hundred million cubic meters of DMs each year, and 5 to 10 % of these DMs require special handling because they are contaminated with hazardous substances that can move from the substrates into food webs causing unacceptable risk outside CDFs. Phytoremediation may offer an alternative to decrease this risk. Chemical analyses by USACE personnel identified 17 metals in various DMs, but in this present study, only zinc (Zn) and Cd were investigated. Pre-germinated seeds of the test plants were planted under laboratory conditions in pots containing the various DMs and reference soil. Four weeks after planting, plants were harvested and separated into roots and shoots for biomass production and tissue metal concentrations analyses. Results showed that T. aestivum plants have the capacity to tolerate and grow in multiple-metal contaminated DMs with the potential of accumulating various amounts of Zn and Cd. Root and shoot biomass of T. aestivum were not significantly affected by the DMs on which the plants were grown suggesting that this plant species can grow just as well on DMs contaminated by various metals as in the reference soil. No significant differences in the Zn tissue

  10. Ocean Disposal of Dredged Material

    EPA Pesticide Factsheets

    Permits and authorizations for the ocean dumping of dredged material is issued by U.S. Army Corps of Engineers. Information is provided about where to dispose dredged material and the process for obtaining an ocean dumping permit for dredged material.

  11. Environmental effects of dredging. Long-term evaluation of plants and animals colonizing contaminated esturaine dredged material placed in an upland environment. Technical notes

    SciTech Connect

    Lee, C.R.; Brandon, D.L.

    1991-09-01

    Contaminated sediment was dredged from Black Rock Harbor, Connecticut, in October 1983 and placed in aquatic, upland, and wetland environments as part of the US Army Corps of Engineers/Environmental Protection Agency Field Verification Program (FVP), 1981-1986 (Peddicord 1988). Upland tests (plant and earthworm bioassays) were conducted on the sediment before dredging to evaluate potential contaminant mobility under the upland disposal alternative. Laboratory test results were subsequently field verified at the field test site at `Tongue Point,` Bridgeport, Connecticut. The results of the upland disposal portion of the FVP and the changes occurring since the completion of the FVP for the upland disposal environment are summarized herein. This technical note emphasizes the contaminant mobility of heavy metals. Contaminant mobility and the progressive development of the upland ecosystem at this site will be evaluated until September 1995.

  12. Informational Webinar on Dredging and Dredged Material Management in Long Island Sound

    EPA Pesticide Factsheets

    EPA Region 1 and Region 2 informational webinar on dredging and dredged material management in Long Island Sound. Topics include: dredging permit process, dredged material testing, and dredged material disposal.

  13. Dredged Material Management in Long Island Sound

    EPA Pesticide Factsheets

    Information on Western and Central Long Island Sound Dredged Material Disposal Sites including the Dredged Material Management Plan and Regional Dredging Team. Information regarding the Eastern Long Island Sound Selected Site including public meetings.

  14. 40 CFR 227.13 - Dredged materials.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... not been contaminated by such pollution. (c) When dredged material proposed for ocean dumping does not....13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact §...

  15. 40 CFR 227.13 - Dredged materials.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... not been contaminated by such pollution. (c) When dredged material proposed for ocean dumping does not....13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact §...

  16. 40 CFR 227.13 - Dredged materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... not been contaminated by such pollution. (c) When dredged material proposed for ocean dumping does not....13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact §...

  17. 40 CFR 227.13 - Dredged materials.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... not been contaminated by such pollution. (c) When dredged material proposed for ocean dumping does not....13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact §...

  18. 40 CFR 227.13 - Dredged materials.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... not been contaminated by such pollution. (c) When dredged material proposed for ocean dumping does not....13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact §...

  19. Methods To Characterize Contaminant Residuals After Environmental Dredging

    EPA Science Inventory

    Environmental dredging is a common remedial action for managing contaminated sediments. However, post dredging contaminant concentrations in surface sediment are difficult to predict prior to initiating dredging actions. In some cases, post surface concentrations have been high...

  20. Long-Term Effects of Dredging Operations Program. Long-Term Evaluation of Plants and Animals Colonizing Contaminated Estuarine Dredged Material Placed in Both Upland and Wetland Environments

    DTIC Science & Technology

    1991-09-01

    into the surface of the dredged material, enhancing plant growth and establishment. The lime and lime + manure plots showed 51 and 28 percent cover...have greatly improved plant growth and vegetative cover. Vegetative cover plays a significant role in improving surface runoff water quality (Skogerboe...large portion of tie wetland (Figure 9f, left side). As the wetland extended across the marsh creation site, the most robust plant growth was observed

  1. Environmental Effects of Dredging. Engineering Considerations for Capping Subaqueous Dredged Material Deposits -- Background and Preliminary Planning.

    DTIC Science & Technology

    1987-02-01

    Marine Pollution by Dumping of Wastes and Other Matter (the London Dumping Convention) accepted the capping concept, subject to monitoring, as an appropriate technology for rapidly rendering harmless the contaminants of concern in dredged material. Subsequent detailed investigations (e.g., Brannon et al. 1985, O’Connor and O’Connor 1983) have confirmed that capping can be effective in chemically and biologically isolating contaminated dredged material from the overlying aquatic environment. However, in order to ensure this effectiveness, capping projects cannot

  2. Dredging and dewatering sediment containing hazardous and toxic materials

    SciTech Connect

    Askin, R.C.

    1996-12-31

    Dredging is a common method of remediating ponds containing contaminated wastes. However, dewatering of the dredged solids is usually not well integrated with the dredging phase. As a result, overall project efficiency can be poor. Specifically, since dredges deliver material in a widely varying slurry form and since dewatering presses require the delivered material to be uniform, union of the two systems often results in inconsistent operation of the overall process. In an effort to enhance overall dredging and dewatering process production rates as well as minimize the return of suspended solids in the decant water, a new process was developed to provide a consistent dredged sludge for delivery to the press. This paper discusses modifications made to a conventional dredging and dewatering process to improve production rates and dewatering capabilities. These modifications are applicable to any project where efficient solids dewatering is required and where returning decant water must be visually free of suspended solids. 4 figs.

  3. DREDGED MATERIAL RECLAMATION AT THE JONES ISLAND CONFINED DISPOSAL FACILITY SITE CAPSULE

    EPA Science Inventory

    In this SITE demonstration, phytoremediation technology was applied to contaminated dredged materials from the Jones Island Confined Disposal Facility (CDF) located in Milwaukee Harbor, Wisconsin. The Jones Island CDF receives dredged materials from normal maintenance of Milwauke...

  4. DREDGED MATERIAL RECLAMATION AT THE JONES ISLAND CONFINED DISPOSAL FACILITY - ITER

    EPA Science Inventory

    In this SITE demonstration, phytoremediation technology was applied to contaminated dredged materials from the Jones Island Confined Disposal Facility (CDF) located in Milwaukee Harbor, Wisconsin. The Jones Island CDF receives dredged materials from normal maintenance of Milwauke...

  5. Comprehensive Analysis of Migration Pathways (CAMP): Contaminant Migration Pathways at Confined Dredged Material Disposal Facilities

    DTIC Science & Technology

    1990-09-01

    longer a contaminant loss pathway. 64. Suspended sediment/water interactions are difficult to model because of the complex nature of sediment...Brannon et al. 1976) and the sediment-specific interactions that contaminants exhibit (O’Connor and Connolly 1980). The complexity of the sediment matrix...water interactions in nonequilibrium situations. However, rate processes are much more complex than equilibrium approaches because they require knowledge

  6. Guidelines for Selecting Control and Treatment Options for Contaminated Dredged Material.

    DTIC Science & Technology

    1986-09-01

    site. g. Soil properties. pH is an important variable in evaluating mobility of many metal contaminants, as well as organic acids and bases and in...requiring removal and the viscosity of the water. How- ever, ideal settling conditions are never achieved and the actual design of the required surface...exhibit high pseudoplasticity or high viscosity and cannot be effectively removed using r - cyclones or hydrocyclones (Oklahoma State University 1973

  7. Mercury-contaminated sludge treatment by dredging in Minamata Bay

    SciTech Connect

    Yoshinaga, Kiyoto

    1995-12-31

    To eradicate Minamata Disease, caused by the discharge of sewage containing methyl mercury and its accumulation in fish and shellfish through the food cycle, a large-scale sediment disposal project was conducted with special care taken to prevent new pollution resulting from the project itself. The basic approach to sediment disposal was to construct a highly watertight revetment to reclaim the inner area of the bay and then confine sediment dredged from the remaining contaminated area in the reclamation area through surface treatment. Before sediment disposal, boundary nets were installed to enclose the work area to prevent the mixing of contaminated and noncontaminated fish. Dredging work was successfully carried out by using four cutterless suction dredgers, newly developed in advance for minimizing resuspension of sediments. Dredged material was discharged into the reclamation area, filled up to sea level, and covered with a sandproof membrane, lightweight volcanic ash earth, and mountain soil.

  8. Ocean Dumping Report for Calendar Year 1982. Dredged Material.

    DTIC Science & Technology

    1983-10-01

    VA. 4. a. Description: Fine sand and silt, non-cohesive. b. Mode of dredging: Trailing hopper dredges, PADRE ISLAND and SUGR s ISLAND. ... c. Mode...material, dredging, and transportation made: a. Description: Noncohesive sand to cohesive muds b. Mode of dredging: Trailing hopper dredge PADRE ISLAND c...Dredging Mode: Hopper Dredge c. Transporting Mode: Hopper Dredge ( PADRE ISLAND) 5. Material Disposal Form: Slurry, non-cohesive 6. Quantity and Dates

  9. Dredged Material Research: Notes, News, Reviews, etc

    DTIC Science & Technology

    1976-02-01

    MARRIAGE OF MARICULTURE AND MATERIAL (DREDGED THAT IS!) In August 1974 the Dow Chemical Company submitted an unsolicited proposal to the DMRP for an...34Investigation of Mariculture as an Alternative Use of Dredged Material Containment Areas." Since the unique, innovative approach proposed was...advantages and disadvantages for the landowners and the Government f80880 of combining dredged material disposal with mariculture , and evaluate

  10. Comparison of the ames assay and mutatox in assessing the mutagenic potential of contaminated dredged material. Final technical report

    SciTech Connect

    Jarvis, A.S.

    1995-04-01

    The Ames assay and Mutatox were evaluated to compare their ability to identify the genotoxic potential of dredged sediments. The Ames assay has been used extensively in the testing of environmental contaminants. Mutatox, a bacterial bioluminescence test, was developed as a genotoxicity bioassay. Ten sediments with varying degrees of contamination were soxhlet extracted. These extracts were divided into crude and clean samples. Cleaned samples were prepared using silica-gel chromatography resulting in 20 extract samples. Both the Ames test (TA98 and TAl00) and Mutatox were conducted with and without S9 metabolic activation. TA98+S9 and TA1OO+S9 indicated a positive mutagenic response in 80 and 50 percent, respectively, of the sediment extracts. Half of the extracts indicated a positive mutagenic response with TA98-S9, while only 10 percent did so with TAlOO-S9. Mutatox indicated a positive mutagenic response with S9 activation in 75 percent of the extracts and no mutagenic response in any of the sediment extracts without metabolic activation. In a side-by-side comparison of the Ames assay (TA98+S9) and Mutatox, 80 percent of the sediment extracts had similar responses, both positive and negative. Fifty percent of the sediment extracts had similar responses when tested with TAlOO+S9 and Mutatox. Mutatox compared favorably with the Ames assay and shows promise as a screening tool to assess sediment genotoxicity when used with Ames assay as a confirmation.

  11. Survey and evaluation of contaminants in earthworms and in soils derived from dredged material at confined disposal facilities in the Great Lakes region

    USGS Publications Warehouse

    Beyer, W.N.; Stafford, C.

    1993-01-01

    Soils derived from dredged material were collected, together with earthworms from nine confined disposal facilities located in the Great Lakes Region. These samples were analyzed for 18 elements, 11 organochlorine pesticides, PCBs, and 24 polycyclic aromatic hydrocarbons. The concentrations detected in earthworms were evaluated in terms of their potential hazard to wildlife, which for the sake of the evaluation were assumed to prey entirely either on earthworms or on other soil invertebrates having similar concentrations. The soil concentrations (dry wt.) of the contaminants of greatest concern were < 1.9 to 32 ppm Cd, < 0.053 to 0.94 ppm Hg, 4.6 to 550 ppm Pb, and < 0.1 to 1.0 ppm PCBs. The concentrations in earthworms (dry wt., ingested soil included) were as high as 91 ppm Cd, 1.6 ppm Hg, 200 ppm Pb, and 1.8 ppm PCBs. Based on laboratory toxicity studies of relatively sensitive species, and on concentration factors calculated from the earthworm and soil data, we estimated that lethal or serious sublethal effects on wildlife might be expected at concentrations of 10 ppm Cd, 3 ppm Hg, 670 ppm Pb, and 1.7 ppm PCBs in alkaline surface soils derived from dredged material. Concentrations of polycyclic aromatic hydrocarbons in earthworms were well below those in soil.

  12. Environmental effects of dredging: Wetland animal bioassay of saltwater dredged material

    SciTech Connect

    1986-01-01

    The Clean Water Act requires that the environmental evaluation of dredged material prior to discharge or impacting the waters of the United States include the effects of disposal on contaminant concentrations through biological processes. This resulted in a need for Corps of Engineers Districts to be able to predict the potential contamination of animals that may be associated with each of these potential disposal alternatives: open-water disposal, upland disposal, and/or wetland creation. The following is a summary of a wetland animal solid-phase bioassay test applied to sediment collected from the waterway at Black Rock Harbor (BRH), Bridgeport, Connecticut. This test procedure was designed to evaluate the potential movement of toxic heavy metals and other contaminants from dredged material placed in a wetland (reduced) environment into sediment-dwelling intertidal invertebrates as a first step that may be used to evaluate contaminant mobility to animals that may colonize the dredged material. No inference on the movement of contaminants through the wetland food web is offered at this time.

  13. Federal Standard: Beneficial Use of Dredged Material

    EPA Pesticide Factsheets

    The purpose of this document is to provide national guidance that explains the role of the Federal Standard in implementing beneficial uses of dredged material from U.S. Army Corps of Engineers’ new and maintenance navigation projects.

  14. Long-term effects of dredging operations program. long-term evaluation of plants and animals colonizing contaminated estuarine dredged material placed in both upland and wetland environments. Final report

    SciTech Connect

    Brandon, D.L.; Lee, C.R.; Simmers, J.W.; Skogerboe, J.G.; Wilhelm, G.S.

    1991-09-01

    Contaminated sediment was dredged from Black Rock Harbor, Connecticut, in October 1983 and placed in aquatic, upland, and wetland environments as part of the Field Verification Program (FVP), conducted during the period 1981-1986. Laboratory tests were conducted on the sediment prior to dredging to evaluate potential contaminant mobility under each of the disposal alternatives. Prior to dredging for upland disposal and wetland creation at the FVP field site, upland tests (i.e., plant and earthworm bioassays) and wetland tests (i.e., plant, sandworm, snail, and mussel bioassays) were conducted. Laboratory test results were sub-subsequently field verified at the field test site at Tongue Point, Bridgeport, CT. The results of the upland disposal and wetland creation portions of the FVP, and the changes occurring since completion of the FVP for each disposal environment, are summarized herein. The emphasis of this report is on the contaminant mobility of heavy metals. This interim report includes data collected through 1989. Contaminant mobility and the progressive development of the upland and wetland ecosystems at this site will be evaluated until September 1985.

  15. Dredging and contaminant exposure to tree swallows nesting on the upper Mississippi River.

    PubMed

    Custer, Thomas W; Dummer, Paul M; Custer, Christine M; Warburton, David

    2013-11-01

    In 2008 and 2009, dredge material from the Mississippi River in Pool 8 south of Brownsville, Minnesota was used to construct nearby islands. Chemical analysis of sediment in 2001 and 2002 in the area to be dredged indicated detectable concentrations of organic and inorganic contaminants. Tree swallows (Tachycineta bicolor), whose diet is mainly aquatic invertebrates, were used to evaluate contaminant exposure in both the dredged and newly created habitat. Organic and inorganic contaminant data were collected from tree swallows in 2007 through 2010 at one study site near the dredging operation, a reference study site upriver from the dredging activity, one study site down river from the dredging activity, and one study site on a newly created island (2009 and 2010 only). Organic and element concentrations were at background levels in all samples. Polychlorinated biphenyl and p,p'-dichlorodiphenyldichloroethylene concentrations in tree swallow nestlings decreased at all study sites over the period 2007 to 2010 including the island study site between 2009 and 2010. Element concentrations in tree swallow livers for the non-island study sites did not show a trend among years in relation to the dredging. Selenium concentrations at the newly created island were higher and cadmium concentrations were lower in 2010 than 2009. Hatching success of eggs in successful nests was not associated with dredging activities.

  16. Dredging and contaminant exposure to tree swallows nesting on the upper Mississippi River

    USGS Publications Warehouse

    Custer, Thomas W.; Dummer, Paul; Custer, Christine M.; Warburton, David

    2013-01-01

    n 2008 and 2009, dredge material from the Mississippi River in Pool 8 south of Brownsville, Minnesota was used to construct nearby islands. Chemical analysis of sediment in 2001 and 2002 in the area to be dredged indicated detectable concentrations of organic and inorganic contaminants. Tree swallows (Tachycineta bicolor), whose diet is mainly aquatic invertebrates, were used to evaluate contaminant exposure in both the dredged and newly created habitat. Organic and inorganic contaminant data were collected from tree swallows in 2007 through 2010 at one study site near the dredging operation, a reference study site upriver from the dredging activity, one study site down river from the dredging activity, and one study site on a newly created island (2009 and 2010 only). Organic and element concentrations were at background levels in all samples. Polychlorinated biphenyl and p,p′-dichlorodiphenyldichloroethylene concentrations in tree swallow nestlings decreased at all study sites over the period 2007 to 2010 including the island study site between 2009 and 2010. Element concentrations in tree swallow livers for the non-island study sites did not show a trend among years in relation to the dredging. Selenium concentrations at the newly created island were higher and cadmium concentrations were lower in 2010 than 2009. Hatching success of eggs in successful nests was not associated with dredging activities.

  17. Management of dredge material in the Republic of Ireland - A review.

    PubMed

    Sheehan, C; Harrington, J

    2012-05-01

    As an island nation the Republic of Ireland's ports and harbours are key to the economic wellbeing of the country as they are the primary transport link to the United Kingdom, mainland Europe and beyond. This paper examines the main aspects of the Irish dredging industry with comparison to international practice and standards, including the source of the dredge material and volumes generated annually, the dredging plant employed and the management processes currently practised. Relevant European and Irish legislation governing dredging, disposal at sea and waste licensing are presented. The potential impacts of disposal at sea are discussed with the implications for the Irish dredging industry of recently introduced European Directives assessed. Beneficial use rates for dredge material and the techniques implemented in Ireland are examined and compared with international practice. Recent notable beneficial use projects for dredge material and proposed innovative dredge material management techniques for specific dredging projects in Ireland are presented. Proposals to encourage greater beneficial use of dredge material and minimise disposal at sea for Ireland are presented including the introduction of environmental credits, tax breaks and a grant system for pilot schemes. An alternative disposal at sea charge fee structure is also recommended to encourage alternative dredge material management practices. Ireland's management of contaminated sediment is also presented with recent projects described highlighting the current practice of primarily exporting contaminated sediment to mainland Europe. Alternative methods of treatment of contaminated sediment are assessed in an Irish context. Future issues and challenges facing the Irish dredging industry are assessed and a critical analysis of the current approaches to dredge material management is presented.

  18. Modeling of Nearshore-Placed Dredged Material

    DTIC Science & Technology

    2015-07-01

    Research Program Modeling of Nearshore- Placed Dredged Material Co as ta l a nd H yd ra ul ic s La bo ra to ry Ernest R. Smith, Rusty Permenter...COVERED 00-00-2015 to 00-00-2015 4. TITLE AND SUBTITLE Modeling of Nearshore- Placed Dredged Material 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c...PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) U.S

  19. Stakeholder engagement in dredged material management decisions.

    PubMed

    Collier, Zachary A; Bates, Matthew E; Wood, Matthew D; Linkov, Igor

    2014-10-15

    Dredging and disposal issues often become controversial with local stakeholders because of their competing interests. These interests tend to manifest themselves in stakeholders holding onto entrenched positions, and deadlock can result without a methodology to move the stakeholder group past the status quo. However, these situations can be represented as multi-stakeholder, multi-criteria decision problems. In this paper, we describe a case study in which multi-criteria decision analysis was implemented in a multi-stakeholder setting in order to generate recommendations on dredged material placement for Long Island Sound's Dredged Material Management Plan. A working-group of representatives from various stakeholder organizations was formed and consulted to help prioritize sediment placement sites for each dredging center in the region by collaboratively building a multi-criteria decision model. The resulting model framed the problem as several alternatives, criteria, sub-criteria, and metrics relevant to stakeholder interests in the Long Island Sound region. An elicitation of values, represented as criteria weights, was then conducted. Results show that in general, stakeholders tended to agree that all criteria were at least somewhat important, and on average there was strong agreement on the order of preferences among the diverse groups of stakeholders. By developing the decision model iteratively with stakeholders as a group and soliciting their preferences, the process sought to increase stakeholder involvement at the front-end of the prioritization process and lead to increased knowledge and consensus regarding the importance of site-specific criteria.

  20. Mobility of Soil Contaminants in an Ecosystem of Trees Growing on Dredged Material - The Broekpolder (Rotterdam, The Netherlands)

    DTIC Science & Technology

    1988-12-27

    and Ormrod, 1982; Van den Burg, 1983). Likewise, metals are retained in the leaves and appear in the litterfall to different degrees, depending both...contaminants in soils also followed this pattern . Two com- pounds analyzed, o,p’-DDE and PCB 28, were consistently near or below detec- tion limits in...from elsewhere and may also have been the result of sample contamina- tion. There were no obvious patterns for bioaccumulation of organochlorine

  1. Environmental effects of dredging: Upland animal bioassays of dredged materials. Technical note

    SciTech Connect

    Simmers, J.W.; Rhett, R.G.; Lee, C.R.

    1986-01-01

    The Clean Water Act in the United States requires that the environmental evaluation of dredged material prior to discharge or impacting the waters of the United States include the effects of disposal on concentrations of contaminants through biological processes. This results in a need for Corps of Engineers districts to be able to predict the contamination of animals that may be associated with potential disposal alternatives: open-water disposal, upland disposal, and wetland creation. The following is a summary of the results of bioassay procedures using the earthworm Eisenia foetida to evaluate the potential contaminant mobility into soil-dwelling animals. These tests were derived from proposed Organization for European Common Development (OECD) and European Economics Commission (EEC) test procedures (evaluating the effects of new chemicals) and modified to consider accumulation and sublethal effects rather than toxicity.

  2. Managing dredged material in the coastal zone of the Baltic Sea.

    PubMed

    Staniszewska, Marta; Boniecka, Helena

    2017-01-01

    This article deals with the legal and practical recommendations for the management of dredged material in the riparian countries of the Baltic Sea. The recommendations are contained in three conventions: LC, 2000. London Convention (1972), Convention on the Protection of the Marine Environment of the Baltic Sea area (Helsinki Convention) (1992), the OSPAR Convention (1972). Different approaches to evaluating the contamination level of dredge spoils, used by the Baltic Sea riparian countries, have been characterized. The differences in those approaches manifest themselves by various concentration limits for contaminants, which form a basis for the classification of dredged material as either contaminated or non-contaminated, and thus determine how the spoils will be processed further. Based on the collected information about the concentration limits for contaminants of surface sediments in the coastal ports, it was pointed out that it is necessary to conduct routine monitoring of heavy metals, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, tributyltin, and petroleum hydrocarbons in dredged sediments in all the Baltic Sea states. On the other hand, the monitoring of polychlorinated dibenzo-p-dioxins/furans, organochlorine, and organophosphoric pesticides is only needed in locations that are suspected of historical or being the local contamination sources. Due to significant economic limitations of chemical determinations, it is important to consider a simple screening test of sediment that would say whether sediment may be "contaminated" and qualifies for more detailed and costly chemical research. It may be typical basic physical-chemical analysis of sediments or ecotoxicological classification of sediments.Despite environmentally friendly tendencies, the practical application of dredged material within the Baltic Sea area is very limited. Dredged material is most frequently stored at the specifically designated sites. From among the practical uses of

  3. Recycled Glass and Dredged Materials

    DTIC Science & Technology

    2007-03-01

    stations, and is either source-separated or co-mingled with plastics , aluminum cans, ceramics, or colored glass containers. In the United States in...cullet (for new bottles and other containers) or non-container glass cullet (all other uses), and non-container processed cullet production is...aggregates (i.e. opposition to change), cost, and regulations. Contamination and Safety Issues. Recycled container glass may contain debris (defined as

  4. Innovative Technologies for Dredging Contaminated Sediments

    DTIC Science & Technology

    1991-09-01

    1215 leflerson Davs Hghway, Suie 1204 Arington. VA 22202 430:. and to the Office of Management and Budget Paperwork Reduction Project (0704-018S...UNCLASSIFIED NSN 7540-01-280-5500 Standaro Pinrm 298 (Rev 2-89) r s (’rh,-d bV Arnli Mtd c 9 18 298 102 A-A~alloa For Contents Ie’ ~ Preface...September 1991 Contents Figures Figure 1. Cutterhead dredge .. .. .. .. .. ... ... ... .. ... .. 6 Figure 2. Conventional cutterhead

  5. Technical Guidelines for Environmental Dredging of Contaminated Sediments

    DTIC Science & Technology

    2008-09-01

    Desrosiers, R., C. Patmont, E. Appy , and P. LaRosa. 2005. Effectively managing dredging residuals: Balancing remedial goals and construction costs...Remediation of Contaminated Sediments, January 22-25, 2007, Savannah, GA. Barth, R., E. Appy , D. Templeton, B. McDonald, and E. Bershinski. 2004

  6. Liquid versus solid phase bioassays for dredged material toxicity assessment.

    PubMed

    Casado-Martínez, M C; Fernández, N; Forja, J M; DelValls, T A

    2007-05-01

    Since 1994 the results of the analyses of key chemical compounds (trace metals, polychlorinated biphenyls and polycyclic aromatic hydrocarbons) and the comparison with the corresponding sediment quality guidelines (SQGs) are used in decision-making for dredged material management in Spain. Nonetheless in the last decades a tiered testing approach is promoted for assessing the physical and chemical characteristics of dredged sediments and their potential biological effects in the environment. Bioassays have been used for sediment toxicity assessment in Spain but few or no experiences are reported on harbour sediments. We studied the incidence of toxicity in the 7 d bioassay using rotifers (Brachionus plicatilis) and the 48 h bioassay using sea urchin (Paracentrotus lividus) embryos over a series of experiments employing 22 different elutriates. The relative performance of this exposure phase was not comparable to data on the 10-d acute toxicity test using the burrowing amphipod Corophium volutator and the polychaete Arenicola marina, carried out on the whole sediments. These results evidence the importance of the exposure route and the test selected in decision-making, as the toxicity registered for the undiluted elutriates was largely due to the different solubility of sediment-bound contaminants. This work and other studies indicate that for many sediments, a complete battery of test is recommended together with physico-chemical analyses to decide whether dredged sediments are suitable for open water disposal or not.

  7. Using sediment quality guidelines for dredged material management in commercial ports from Spain.

    PubMed

    Casado-Martínez, M C; Buceta, J L; Belzunce, M J; Delvalls, T A

    2006-04-01

    Dredged material contamination was assessed in different commercial ports from Spain: Port of Cádiz and Huelva, South West; Bilbao and Pasajes, North; Cartagena and Barcelona, East; Coruña, North West. Sediment from different locations of these ports was sampled and was characterized following the Spanish recommendations for dredged material management. This characterization included grain size distribution, organic matter content and concentration of the chemical compounds included in the list of pollutants and hazardous substances (As, Cd, Cu, Cr, Hg, Ni, Pb and Zn; PCB congeners IUPAC number 28, 52, 101, 118, 138, 153 and 180; PAHs were also analyzed). The results were compared to the limit values of Spanish Action Levels that define the different categories for assessment and management. A set of empirically derived sediment quality guidelines (SQG) was used to assess the possible toxicity of the dredged materials and to improve the use of the chemical approach to characterize dredged material for its management.

  8. Impact of roadside ditch dredging on bacterial communities and biological contamination of a tidal creek

    NASA Astrophysics Data System (ADS)

    Jones, Chance E.; Barkovskii, Andrei L.

    2017-03-01

    Tidal creek networks form the primary hydrologic link between estuaries and land-based activities on barrier islands. A possible impact from the excavation of drainage ditch systems on bacterial communities and biological contamination was studied in the water column and sediments of headwater, mid-stream, and mouth sites of the intertidal Oakdale Creek on Sapelo Island, GA. Community analysis was performed using the MiSeq Illumina platform and revealed that dredging was the cause of a significant rise in Proteobacteria, especially γ-proteobacteria. Targeted biological contaminants included fecal indicator bacteria, Enterococcus spp. (Entero-1), pathogens, Shigella spp. (ipaH), and Salmonella spp (invA), virulence associated genes (VG's) of pathogenic E. coli (eaeA, hlyD, stx1, stx2, and set1B), integrons (intI1, intI2), and tetracycline resistance genes (TRGs). Incidence and gene concentrations of Shigella spp., eaeA and set1B, and of TRGs increased 3-20 folds after the onset of dredging, and followed the dredging schedule. Principal Component Analysis suggested possible common carriers for Shigella spp., some TRGs, and the pathogenic E. coli eaeA gene. At the site of dredging, all of the above contaminants were detected at high concentrations. We concluded that excavation of roadside ditches caused significant changes in bacterial composition and a rise in incidence and concentrations of biological contaminants in the creek. The authors suggest a different approach for the maintenance of this material be explored.

  9. 40 CFR 225.2 - Review of Dredged Material Permits.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... DUMPING CORPS OF ENGINEERS DREDGED MATERIAL PERMITS § 225.2 Review of Dredged Material Permits. (a) The... proposed disposal site; (5) Existence and documented effects of other authorized dumpings that have been made in the dumping area (e.g., heavy metal background reading and organic carbon content); (6)...

  10. Behavior of subaqueous sediment mounds: Effect on dredged material disposal site capacity

    SciTech Connect

    Poindexter, M.E.

    1988-01-01

    Dredging of contaminated sediments and subsequent disposal at legally designated disposal sites is an internationally accepted disposal alternative when adherence to strict disposal practices is maintained. As more highly contaminated sediments in the heavily industrialized harbors of the world must be dredged to maintain navigation and economic viability, use of subaqueous dredged material disposal sites is expected to increase. Use of these subaqueous sites has necessitated development of procedures to analyze disposal site capacity based upon physical, chemical, and biological considerations. A methodology of analysis was developed in this study to investigate the behavior of the crated subaqueous sediment mounds. Emphasis was placed upon the geotechnical engineering aspects of mound behavior although the methodology also includes chemical and biological aspects. This methodology was applied to four field sites at which dredged material mounds have been created. The procedure successfully predicted the geotechnical engineering behavior of the constructed dredged material mounds. This methodology of analysis provides a useful tool for evaluation of subaqueous disposal sites and the dredged materials mounds created within these sites.

  11. Long-term effects of dredging operations program: Assessing bioaccumulation in aquatic organisms exposed to contaminated sediments. Final report

    SciTech Connect

    Clarke, J.U.; McFarland, V.A.

    1991-07-01

    This paper synthesizes previous work on bioaccumulation to provide a working document for the environmental impact on the aquatic environment due to bioaccumulation of sediment contaminants resulting from dredging operations and dredged material placement. Emphasis is placed on explanation of basic concepts concerning, and factors influencing, sediment contaminant bioaccumulation and bioavailability. The paper presents several numerical methods for assessing bioaccumulation, including a simple method for estimating theoretical bioaccumulation potential (TBP) from sediment chemistry for neutral organic chemicals. Methods are also given for projecting contaminant concentrations in organism tissues when steady state is achieved, based on laboratory or field exposures to contaminated sediments. These assessments are presented in the context of the US Environmental Protection Agency's tiered testing approach for dredged material evaluation. The various numerical methods for bioaccumulation assessment are illustrated and compared using step-by-step example calculations with hypothetical and actual data.

  12. Ecological evaluation of proposed dredged material from the Point Frazer Bend Reach, Winyah Bay, South Carolina

    SciTech Connect

    Gardiner, W.W.; Ward, J.A.; Word, J.Q.

    1995-02-01

    The port of Georgetown, South Carolina, is served by navigational channels within Winyah Bay and the lower Sampit River. Dredging is required to maintain these waterways and to facilitate normal shipping traffic. Prior to dredging, ecological evaluations must be conducted to determine the suitability of the proposed dredged material for open-ocean disposal. These evaluations are to be performed under Section 103 of the Marine Protection, Research, and, Sanctuaries Act of 1972 (MPRSA), following the testing protocols presented in Evaluation of Dredged Material Proposed for Ocean Disposal Testing Manual, hereafter referred to as the 1991 Implementation Manual. The Charleston Intensive Project is a reevaluation of sediments collected from two stations (IH-2 and IH-3) in the Frazier Point Bend reach of the Winyah Bay channel. Reference sediment was also collected from site IH-R2, just south of Hare Island. The results of physical/chemical analyses indicated that some contaminants of concern were present in test treatments representing dredged material when compared with the reference treatment IH-R2. The results of this study indicate that, based on the acute toxicity and chemical analyses, dredged material represented by these test treatments is suitable for open-ocean disposal.

  13. Environmental effects of dredging. Engineering considerations for capping subaqueous dredged material deposits -- background and preliminary planning. Technical notes

    SciTech Connect

    1987-02-01

    In recent years, the search for alternatives to expensive and limited upland containment areas for contaminated sediment has centered on in-water capped disposal. This interest was further reinforced when the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter (the London Dumping Convention) accepted the capping concept, subject to monitoring, as an appropriate technology for rapidly rendering harmless the contaminants of concern in dredged material. Subsequent detailed investigations (e.g., Brannon et al. 1985, O`Connor and O`Connor 1983) have confirmed that capping can be effective in chemically and biologically isolating contaminated dredged material from the overlying aquatic environment. However, in order to ensure this effectiveness, capping projects cannot be treated simply as a modification of conventional disposal practices. A capping project must be thought of as an engineered structure with design and construction requirements that must be met, verified, and maintained over the design life. This is not to say that traditional equipment and operational methods cannot be applied to capping contaminated materials. In fact, they have been used with good success. Technologies must, however, be applied in a systems context and with careful control and monitoring.

  14. Dredged Material Testing and Evaluation for Ocean Disposal

    EPA Pesticide Factsheets

    Evaluation and testing of dredged material proposed for ocean dumping is conducted to help protect human health and the marine environment. National guidance is provided by the Green Book. Regional Implementation Manuals are provided.

  15. Ecological evaluation of proposed dredged material from St. Andrew Bay, Florida

    SciTech Connect

    Mayhew, H.L.; Word, J.Q.; Kohn, N.P.; Pinza, M.R.; Karle, L.M.; Ward, J.A.

    1993-10-01

    The US Army Corps of Engineers (USACE), Mobile District, requested that the Battelle/Marine Sciences Laboratory (MSL) conduct field sampling and chemical and biological testing to determine the suitability of potential dredged material for open ocean disposal. Sediment from St. Andrew Bay was chemically characterized and evaluated for biological toxicity and bioaccumulation of contaminants. The Tier III guidance for ocean disposal testing requires tests of water column effects (following dredged material disposal), deposited sediment toxicity, and bioaccumulation of contaminants from deposited sediment (dredged material). To meet these requirements, the MSL conducted suspended-particulate-phase (SPP) toxicity tests, solid-phase toxicity tests, and bioaccumulation testing on sediment representing potential dredged material from Panama City Harbor. Physical and chemical characterization of sediment to support toxicity and bioaccumulation results was also conducted on both the test and reference sediments. The MSL collected sediment samples from five sites in St. Andrew Bay and one reference site near Lands End Peninsula. The five test sediments and the reference sediment were analyzed for physical and chemical sediment characteristics, SPP chemical contaminants, solid-phase toxicity, SPP toxicity, and bioaccumulation of contaminants.

  16. Ocean Dumping Report for Calendar Year 1984. Dredged Material.

    DTIC Science & Technology

    1985-07-01

    PUERTO RICO PORT AUTHORITY 118 P-41 PORT OF LOS ANGELES 120 P-42 U.S. AIR FORCE / VANDENBERG 122 P-43 U.S. NAVY / SAN DIEGO 124 P-44 U.S. NAVY / SAN DIEGO...Parmittee: Puerto Rico Port Authority Date Issued: May 5, 1984 permit No. 84J-0678 Start Date: May 25,1984 Expiry Date: March 5, 1987 3. Country of origin...Dredges PADRE ISLAND and MANHATTAN ISLAND c. Mode of transportation: Hopper Dredge 5. Form in which dredged material is presented for disposal: Slurry

  17. Linking sediment chemical and biological guidelines for characterization of dredged material.

    PubMed

    Casado-Martínez, M C; Riba, I; Blasco, J; DelValls, T A

    2005-01-01

    Dredged material management in Spain and possible options for the different categories is discussed according to chemical sediment quality guidelines. Also an approach using an integrated assessment that includes biological end points as part of a tiered testing schema is discussed for future implementation in Spanish recommendations. To establish the feasibility of using both kinds of guidelines, an example of the utility and validity of the approach that links both chemical and biological guidelines proposed for the management of dredged material characterization processes data from a particular case study associated with a port in the north of Spain are discussed. The use of both kinds of methodologies, together with the necessity of assessing the bioavailability of some contaminants, has been shown as a powerful tool for the best selection of different disposal options of dredged material in the case study described.

  18. The suitability evaluation of dredged soil from reservoirs as embankment material.

    PubMed

    Park, Jaesung; Son, Younghwan; Noh, Sookack; Bong, Taeho

    2016-12-01

    We assessed the suitability of soil dredged from reservoirs as embankment material and investigated its physical and geochemical properties and strength parameters, as well as its environmental stability. The dredged soil samples were taken from the Ansung, Jechon, and Mulwang Reservoirs in Korea. To evaluate their environmental stability and geochemical properties, we examined their levels of heavy metal contamination, pH, and electrical conductivity. We also conducted X-ray fluorescence and X-ray diffraction analyses. Furthermore, we determined the geotechnical characteristics, such as the compaction characteristics, and permeability coefficient, and we performed consolidated undrained triaxial compression tests to evaluate the recycling potential of dredged soil as embankment material. The concentrations of heavy metals in the sediment samples were lower than those of the standard samples. The pH value of the soil samples ranged from 4.25 to 5.39, and the electrical conductivity ranged between 83.3 and 265.0 μS/cm, indicating suitability for use as construction material with steel and concrete. Based on the values of the mechanical properties of the dredged soil, analysis of slope stability was performed for various cases and water level conditions. Our results indicate that the dredged soil has sufficient stability for substitution of embankment material and also as new embankment material for expansion.

  19. Improvement of Operations and Maintenance Techniques Program. Literature Review and Technical Evaluation of Sediment Resuspension during Dredging

    DTIC Science & Technology

    1991-01-01

    FIELD GROUP SUB-GROUP Contaminated sediments Sediment resuspension Dredging Turbidity Dredging equipment 19. ABSTRACT (Continue on reverse if necessary...have, in many instances, become contaminated over the years, resulting in a concern that dredging and disposal of the dredged material may adversely...dredges share the burden of dredging. Most dredges in the United States are old and are not designed to handle highly contaminated sediments. The

  20. Quality of dredged material in the river Seine basin (France). II. Micropollutants.

    PubMed

    Carpentier, S; Moilleron, R; Beltran, C; Hervé, D; Thévenot, D

    2002-11-01

    Dredging rivers is needed to ensure safe navigable waters, rivers and waterways. To anticipate the management of dredged materials in the case of the river Seine basin, the quality of the sediments in the river is checked every 3 years before dredging operations. The river Seine Basin is heavily submitted to pollution pressure from nearby industrial activities and urban expansion of Paris and its region. Here, the micropollutant content of the sediment sampled in 1996, 1999 and 2000 before dredging is discussed compared to regulatory standards. The results indicate that most of the sediment samples from the river Seine basin are lightly to moderately contaminated with organic and inorganic micropollutants (heavy metals, PAH, PCB), which makes the management after dredging easier. This pollution is strongly correlated with the organic matter content and to the fine fraction (<50 microm) of the sediment. These results can lead to other management options than the ones already used in the river Seine basin: (1) dumping of lightly to moderately polluted sediments in quarries; and (2) physical treatment (sieving, hydrocycloning) of contaminated sediments issued from 'hot spots'.

  1. Quality of dredged material in the River Seine basin (France). I. Physico-chemical properties.

    PubMed

    Carpentier, S; Moilleron, R; Beltran, C; Hervé, D; Thévenot, D

    2002-08-05

    In rivers, sediments are frequently accumulating persistent chemicals, especially for those that are more contaminated as a consequence of pressure related to environmental pollution and human activity. The Seine river basin (France) is heavily polluted from nearby industrial activities, and the urban expansion of Paris and its suburbs within the Ile de France region and the sediments present in the Seine river basin are contaminated. To ensure safe, navigable waters, rivers and waterways must be dredged. In this paper, the quality of the sediment dredged in 1996, 1999 and 2000 is discussed. Physico-chemical characteristics of the sediment itself and of the pore-water are presented. Seine basin sediments show very diverse compositions depending on the sampling site. Nevertheless, a geographic distribution study illustrated that the Paris impact is far from being the only explanation to this diversity, the quality of this sediment is also of great concern. The sediment once dredged is transported via barges to a wet disposal site, where the dredged material is mixed with Seine water in order to be pumped into the receiving site. This sort of dumping might be responsible for the potential release of contaminants to the overlying water from the significantly contaminated sediments.

  2. Effects of contaminated dredge spoils on wetland plant communities: A literature review

    USGS Publications Warehouse

    Stewart, Paul M.; Garza, Eric L.; Butcher, Jason T.; Simon, Thomas P.

    2003-01-01

    Contaminated dredge spoil is a national concern due to its scope and effects on biota, water quality, and the physical environment. This literature review discusses the effects of contaminated dredge spoils on wetland plant communities. Plant communities naturally shift over time with changing environmental conditions. Addition of toxins and nutrients and changes in hydrology may influence plant community structure. The storage and disposal of nutrient and metal contaminated dredge spoils may cause shifts in nearby plant communities. Shifts in species composition and diversity may not be observed for decades after nutrient enrichment, causing any disturbance to remain undetected. Plant community shifts often have great amounts of inertia and are difficult to reverse.

  3. Tier 1 ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters

    SciTech Connect

    Shreffler, D.K.; Thorn, R.M.; Walls, B.E.; Word, J.Q.

    1994-01-01

    The Water Resources Development Act of 1986 (Public Law 99--662) authorized the U.S. Army Corps of Engineers (USACE) -- San Francisco District, to accommodate larger, deeper draft vessels in Oakland inner and Outer Harbors by deepening and widening the existing navigation channel, and providing turning basins and maneuvering areas in Oakland inner Harbor. The suitability of the resulting dredged material for disposal into ocean waters was subject to the procedures of the 1991 Testing Manual, Evaluation of Dredged Material Proposed for Ocean Disposal, known as the ``Green Book``. The Green Book provides a tiered approach for testing the suitability of dredged materials through chemical, physical, and biological evaluations. The first level of investigation, or Tier 1 evaluation, is used to determine whether a decision on LPC compliance can be made on the basis of readily available information. The Tier 1 report primarily summarizes existing information on sediment contamination and toxicity potential, identifies contaminants of concern, and determines the need for further testing. To assist the USACE in determining the suitability of dredged material from Oakland inner and Outer Harbors for ocean disposal, Battelle/Marine Sciences Laboratory prepared this Tier 1 report based upon information and data provided by USACE. Because this Tier 1 report originated well after an LPC determination was made to require testing of project sediments in Tier 3, the primary purpose of this report was to identify contaminants of concern (if any) in that particular dredged material. In addition, this Tier 1 report summarizes available information on chemical, physical, and biological characterization of the sediments in Oakland inner and Outer Harbors.

  4. Dredging Operations Technical Support Program: Guidance for Contracting Biological and Chemical Evaluations of Dredged Material

    DTIC Science & Technology

    1990-09-01

    to allowing disposal of dredged material in waters of the United States. Compli- ance requires the avoidance of "unacceptable adverse effects " to the...costs. This may result in increases in cost- effectiveness , although this varies greatly and cannot be assumed. The private firm, which operates at a...BAA is published annually by the US Army Engineer Waterways Experiment Station (WES) and remains in effect until superseded by the latest edition. The

  5. EPA Proposes Changes to Use of Two Long Island Sound Dredged Material Disposal Sites

    EPA Pesticide Factsheets

    EPA is proposing to amend its 2005 rule that designated the Central & Western Long Island Sound Dredged Material Disposal Sites. The proposed amendments will help meet the goal of reducing or eliminating dredged material disposal in the Sound's open waters

  6. DECONTAMINATING AND PROCESSING DREDGED MATERIAL FOR BENEFICIAL USE

    SciTech Connect

    CLESCERI,N.L.; STERN,E.A.; FENG,H.; JONES,K.W.

    2000-07-01

    Management of contaminated dredged material is a major problem in the Port of New York and New Jersey. One component of an overall management plan can be the application of a decontamination technology followed by creation of a product suitable for beneficial use. This concept is the focus of a project now being carried out by the US Environmental Protection Agency-Region 2, the US Army Corps of Engineers-New York District, the US Department of Energy-Brookhaven National Laboratory, and regional university groups that have included Rensselaer Polytechnic Institute, Rutgers University, New Jersey Institute of Technology, and Stevens Institute of Technology. The project has gone through phased testing of commercial technologies at the bench scale (15 liters) and pilot scale (1.5--500 m{sup 3}) levels. Several technologies are now going forward to large-scale demonstrations that are intended to treat from 23,000 to 60,000 m{sup 3}. Selections of the technologies were made based on the effectiveness of the treatment process, evaluation of the possible beneficial use of the treated materials, and other factors. Major elements of the project are summarized here.

  7. 78 FR 37759 - Ocean Dumping; Atchafalaya-West Ocean Dredged Material Disposal Site Designation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-24

    ... AGENCY 40 CFR Part 228 Ocean Dumping; Atchafalaya-West Ocean Dredged Material Disposal Site Designation... designate the Atchafalaya-West Ocean Dredged Material Disposal Site pursuant to the draft EIS, ``Designation of the Atchafalaya River Bar Channel Ocean Dredged Material Disposal Site Pursuant to Section...

  8. Lake-dredged materials for beef cattle pasture establishment in subtropics

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The ability to reuse dredge materials for agricultural purposes is important because it reduces offshore disposal and provides an alternative to disposal of the materials in landfills that are already overtaxed. Beneficial uses of dredging or dredged materials are both economical and environmental. ...

  9. New Federal Regulations for Dredged and Fill Material

    ERIC Educational Resources Information Center

    Smith, David D.

    1976-01-01

    Aided by Environmental Protection Agency (EPA) guidelines, the United States Army Corps of Engineers regulates the discharge of dredged and fill material, through a permit program, to all waters of the United States. This feature summarizes the key points of the Corps regulations and the EPA guidelines. (BT)

  10. Chemical Clarification Methods for Confined Dredged Material Disposal.

    DTIC Science & Technology

    1983-07-01

    SCHEDULE 16. DISTRIBUTION STATEMENT (of this Report) Approvedl for publico release; distribution unlimited. 17. DISTRIBUTION STATEMENT (of the...136. Salinity. The salinity of the sediment water and the bottom water used to suspend and transport the dredged material must be mea- sured or

  11. Field Verification Program (Aquatic Disposal): Comparison of Field and Laboratory Bioaccumulation of Organic and Inorganic Contaminants from Black Rock Harbor Dredged Material

    DTIC Science & Technology

    1988-05-01

    contaminants are likely, both synergis- tic and antagonistic effects may render these relationships inadequate for predicting bioaccumulation. 17. In an...weight for the statistic CENTROID. ** These are the 12 contaminant measurements used for calculating BRH exposure. C42 0 Table C40 Tissue Residue

  12. Dredging as remediation for white phosphorus contamination at Eagle River Flats, Alaska

    SciTech Connect

    Walsh, M.R.; Collins, C.M.

    1998-08-01

    The Eagle River Flats impact area is a Ft. Richardson Superfund site. It is a salt marsh that is contaminated with white phosphorus (WP), and remediation of sediments in permanently ponded areas may require dredging. A remotely piloted dredging system was designed, constructed, and deployed at the Flats as part of the overall site remediation feasibility study. Experience gained over two years of engineering study and contract operation indicates that, although feasible and effective, this alternative is slow, difficult, and very expensive.

  13. Verification of Design and Construction Techniques for Gaillard Island Dredged Material Disposal Area, Mobile, Alabama.

    DTIC Science & Technology

    1986-08-01

    pumping and barge hauling dredged material over distances up to 7 miles. A dust pan dredge was used to dredge the soft clayey bottom mate- rial and deposit...Docks and the city of Mobile acquired 1800 acres to form the nucleus of the pirk. The State Docks dredged a 12-ft barge canal up the mid- dle fork of the...Mobile, set up biomonitoring stations to measure changes in such things as siltation, salinity, water temperature, dissolved oxygen, and benthic

  14. Environmental effects of dredging, technical notes. Technical notes

    SciTech Connect

    1996-08-01

    Biomagnification of Contaminants in Aquatic Food Webs as a Result of Open-Water Disposal of Dredged Material ; Fate of Dredged Material During Open-Water Disposal; Engineering Considerations for Capping Subaqueous Dredged Material Deposits-Background and Preliminary Planning; Engineering Considerations for Capping Subaqueous Dredged Material Deposits-Design Concepts and Placement Techniques; Monitoring Dredged Material Consolidation and Settlement at Aquatic Disposal Sites; Computerized Database for Interpretation of the Relationship Between Contaminant Tissue Residues and Biological Effects in Aquatic Organisms; Use of Daphnia Magna to Predict Consequences of Bioaccumulation; Simplified Approach for Evaluating Bioavailability of Neutral Organic Chemicals in Sediment; A Procedure for Determining Cap Thickness for Capping Subaqueous Dredged Material Deposits; Acoustic Tools and Techniques for Physical Monitoring of Aquatic Dredged Material Disposal Sites; Contaminant Modeling; Use of Seabed Drifters for Locating and Monitoring Dredged Material Placement Sites.

  15. DECONTAMINATION OF DREDGED MATERIAL FROM THE PORT OF NEW YORK AND NEW JERSEY.

    SciTech Connect

    JONES,K.W.; STERN,E.A.; DONATO,K.R.; CLESCERI,N.L.

    1999-06-01

    The Port of New York and New Jersey ranks first in the United States in volume of petroleum products handled each year. In addition, many refineries are in operation on the New Jersey side of the Port. These activities have led to the discharge of significant amounts of petroleum hydrocarbons into the waters of the New York/New Jersey region. Intense industrial and commercial activities have also brought about major inputs of other organic and inorganic contaminants as would be expected in an industrialized, heavily populated urban port. Sediments that then are contaminated are a major problem for the region since they can no longer be disposed of by the traditional method of ocean disposal following the dredging operations required for the efficient operation of the Port. Decontamination and beneficial reuse of the dredged materials is one component of a comprehensive dredged material management plan being developed by the US Army Corps of Engineers. A demonstration decontamination project extending from bench- to field-scale operations is now in progress in the Port, and its current status and relevance for other regions is summarized.

  16. DECONTAMINATION OF DREDGED MATERIAL FROM THE PORT OF NEW YORK AND NEW JERSEY

    SciTech Connect

    JONES,K.W.; STERN,E.A.; DONATO,K.R.; CLESCERI,N.L.

    1999-06-01

    The Port of New York and New Jersey ranks first in the US in volume of petroleum products handled each year. In addition, many refineries are in operation on the New Jersey side of the Port. These activities have led to the discharge of significant amounts of petroleum hydrocarbons into the waters of the New York/New Jersey region. Intense industrial and commercial activities have also brought about major inputs of other organic and inorganic contaminants as would be expected in an industrialized, heavily populated urban port. Sediments that then are contaminated are a major problem for the region since they can no longer be disposed of by the traditional method of ocean disposal following the dredging operations required for the efficient operation of the Port. Decontamination and beneficial reuse of the dredged materials is one component of a comprehensive dredged material management plan being developed by the US Army Corps of Engineers. A demonstration decontamination project extending from bench- to field-scale operations is now in progress in the Port, and its current status and relevance for other regions is summarized.

  17. Guidance for Subaqueous Dredged Material Capping.

    DTIC Science & Technology

    1998-06-01

    rjynC QUALITY INSPECTED 1 Prepared for Headquarters, U.S. Army Corps of Engineers The contents of this report are not to be used for advertising...locally, as needed. Contents Preface xii Conversion Factors, Non-SI to SI Units of Measurement xiv 1—Introduction 1 Background 1 Purpose and Scope...material properties, and com- puter models for predicting mound development and spreading behavior are available. c. Long-term cap integrity

  18. Evaluation of hydrocyclone and post-treatment technologies for remediation of contaminated dredged sediments.

    PubMed

    Kim, Jong-Oh; Choi, Jeongyun; Lee, Seongeon; Chung, Jinwook

    2016-01-15

    There are many disposal and treatment methods for contaminated dredged sediments, depending on their properties. In this study, treatment methods for the remediation of dredged sediments as well as the reduction of pore water generated from dredged sediments were optimized. The efficiency of separation using hydrocyclone as the pre-treatment increased with greater inflow velocity of hydrocyclone, deeper insertion of the vortex finder, and smaller hydrocyclone diameter. In the post-treatment of hydrocyclone overflow, the chemical coagulation and membrane filtration methods had high efficiency with regard to the removal of solid and organic compounds, but the former was less feasible, due to its excessive operation and sludge disposal costs. The membrane filtration was easily applicable in the field, based on its convenience of installation and lower cost of operation despite low removal efficiency of trace organic contaminants.

  19. Dredging Operations Technical Support Program. Planning-Level Cost Estimates of Dredged Material Containment Islands in New York Harbor.

    DTIC Science & Technology

    1988-04-01

    WES). Three sites are ... *considered: a. A--East Bank (off East Bank and Coney Island ). .. b. B--West Bank (Lower Bay west to Chapel Hill Channel). c...PROGRAM "P." US~~o ArCop MISCELLANEOUS PAPER D-88 3 PLANNING-LEVEL COST ESTIMATES OF AD-A194 812 DREDGED MATERIAL CONTAINMENT ISLANDS IN NEW YORK HARBOR...10278-0090 11. TITLE (include Security Classification) -’.. Planning-Level Cost Estimates of Dredged Material Containment Islands in New York Harbor

  20. Evaluation of dredged material proposed for ocean disposal from MOTBY

    SciTech Connect

    Barrows, E.S.; Mayhew, H.L.; Word, J.Q.

    1996-09-01

    The National Park Service, US Department of the Interior requested U.S. Army Corps of Engineers/New York District (USACE-NYD) to evaluate sediments around the Military Ocean Terminal (MOTBY) in Bayonne, New Jersey for unconfined ocean disposal at the Mud Dump Site. Sediment samples were collected from MOTBY. Tests and analyses were conducted on MOTBY sediment core samples. The evaluation of proposed dredged material from MOTBY included grain size and total organic carbon (TOC) analyses and one acute toxicity test with the amphipod Ampelisca abdita. In addition to this benthic toxicity test, a bioaccumulation test (28-day exposure) was conducted.

  1. New Bedford Harbor Superfund Project Acushnet River Estuary Engineering Feasibility Study of Dredging and Dredged Material Disposal Alternatives. Report 10. Evaluation of Dredging and Dredging Control Technologies

    DTIC Science & Technology

    1988-11-01

    concluded that the cutterhead showed very little resuspension when operated properly (Hayes, McLellan , and Truitt 1988). DIRECTION OF SWING TO PU M P...Illinois (Hayes, McLellan , and Truitt 1988). Controls for Sediment Resuspension 87. Careful planning, dredging techniques, and monitoring practices...Station, Vicksburg, MS. Hayes, D. F., McLellan , T. N., and Truitt, C. L. 1988. "Demonstrations of Innovative and Conventional Dredging Equipment at Calumet

  2. GREAT I: A Study of the Upper Mississippi River. Volume 2. Floodplain Management, Dredged Material Uses, Dredging Requirements.

    DTIC Science & Technology

    1980-09-01

    Disposal, Thalwep. The disposal of dredged material into the main channel. Diversion. The taking of water from a stream or other body of water into a...REQUIREMENTS ions will be in bleok 40 white’ VOLUME 3 D. MATERIAL AND EQUIPMENT NEEDS E. COMMERCIAL TRANSPORTATION VOLUME 4 F. WATER QUALITY G. SEDIMENT...acceptable on a temporary basis. The material must be removed from the floodway before seasonal high water . 3. The FPMWG recommends that lands along

  3. Ecological evaluation of proposed dredged material from the John F. Baldwin Ship Channel: Phase 3 -- biological testing

    SciTech Connect

    Kohn, N.P.; Karle, L.M.; Pinza, M.R.; Mayhew, H.L.; White, P.J.; Gruendell, B.D.; Word, J.Q.

    1993-10-01

    The John F. Baldwin Ship Channel is a 28-mile-long portion of the San Francisco Bay to Stockton Ship Channel, the primary shipping lane through San Francisco Bay and Delta. The San Francisco District of the US Army Corps of Engineers (USACE) is responsible for construction of the John F. Baldwin Ship Channel, which is authorized to be deepened to a project depth of {minus}45 ft relative to mean lower low water (MLLW). Approximately 8.5 million cubic yards (mcy) of sediment will be removed from the channel to reach this project depth. The USACE requested Battelle/Marine Sciences Laboratory (MSL) to conduct testing for ocean disposal under the guidelines in Evaluation of Dredged Material Proposed for Ocean Disposal-Testing Manual (EPA/USACE 1991). This testing manual contains a tiered evaluation approach developed specifically for ocean disposal of dredged material at a selected site. In this study, John F. Baldwin Ship Channel sediments were evaluated under the Tier III (biological) testing guidance, which is considered to be highly stringent and protective of the environment. The Tier III guidance for ocean disposal testing requires tests of water column effects, (following dredged material disposal), deposited sediment toxicity, and bioaccumulation of contaminants from deposited sediment (dredged material).

  4. 15 CFR Appendix C to Subpart M of... - Dredged Material Disposal Sites Within the Sanctuary

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 15 Commerce and Foreign Trade 3 2011-01-01 2011-01-01 false Dredged Material Disposal Sites Within the Sanctuary C Appendix C to Subpart M of Part 922 Commerce and Foreign Trade Regulations Relating to... National Marine Sanctuary Pt. 922, Subpt. M, App. C Appendix C to Subpart M of Part 922—Dredged...

  5. 78 FR 29687 - Ocean Dumping; Atchafalaya-West Ocean Dredged Material Disposal Site Designation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-21

    ... the ARBC, and thus, decreases the overall annual maintenance dredging effort needed for the ARBC while providing vessels with a longer period of safe navigation access prior to a maintenance dredging event... maintenance and 2 feet of allowable overdepth. Material removed from the ARBC suitable for beneficial use...

  6. Environmental impact and recovery at two dumping sites for dredged material in the North Sea.

    PubMed

    Stronkhorst, J; Ariese, F; van Hattum, B; Postma, J F; de Kluijver, M; Den Besten, P J; Bergman, M J N; Daan, R; Murk, A J; Vethaak, A D

    2003-01-01

    The environmental impact and recovery associated with the long and uninterrupted disposal of large volumes of moderately contaminated dredged material from the port of Rotterdam was studied at nearby dumping sites in the North Sea. Observations were made on sediment contamination, ecotoxicity, biomarker responses and benthic community changes shortly after dumping at the 'North' site had ceased and at the start of disposal at the new dumping site 'Northwest'. During the period of dumping, very few benthic invertebrates were found at the North site. Concentrations of cadmium, mercury, polychlorinated biphenyls (PCBs), polyaromatic hydrocarbons (PAHs) and tributyltin (TBT) in the fine sediment fraction (<63 microm) from this site were 2-3 times higher than at the reference site. In four different bioassays with marine invertebrates the sediments showed no acute toxic effects. In tissue (pyloric caeca) of resident starfish Asterias rubens, residual levels of mercury, zinc, PCBs and dioxin-like activity were never more than twice those at the reference site. Four different biomarkers (DNA integrity, cytochrome P450 content, benzo[a]pyrene hydroxylase activity and acetylcholinesterase inhibition) were used on the starfish tissues, but no significant differences were found between North and the reference site. Minor pathological effects were observed in resident dab Limanda limanda. One year after dumping had ceased at the North site, a significant increase in the species richness and abundance of benthic invertebrates and a concomitant decrease in the fine sediment fraction of the seabed were observed. After 8.2 million m3 of moderately contaminated dredged material had been dumped at the new dumping site Northwest, the species richness and abundance of benthic invertebrates declined over an area extending about 1-2 km eastwards. This correlated with a shift in sediment texture from sand to silt. The contamination of the fine sediment fraction at the Northwest location

  7. Beneficial Uses of Dredged Material Fact Sheet: Project Partners and Decision Makers

    EPA Pesticide Factsheets

    Disposal of dredged material is managed and conducted by federal, state, and local governments; private entities; and semi-private entities. Cooperation among these groups strengthens the possibility that suitable materials will be used beneficially.

  8. Dredging Operations Technical Support Program. General Decisionmaking Framework for Management of Dredged Material: Example Application to Commencement Bay, Washington.

    DTIC Science & Technology

    1991-06-01

    Nieuwenhuize, Delta Institute of Hydrobiological Research, The Netherlands; Dr. M. Johnson, University of Liverpool, United Kingdom; Dr. J. Marquenie...effects. 65. Hill, Myers, and Brannon (1988) reviewed state-of-the-art leaching procedures for potential application to dredged material. Various topics ...Two-level Approach," USAE Commit- tee on Water Quality, Sixth Seminar - Proceedings, 25-27 February, 1986, New Orleans, LA (in preparation), Hydrologic

  9. Dredging Operations Technical Support Program. Mathematical Model of the Consolidation/Desiccation Processes in Dredged Material.

    DTIC Science & Technology

    1985-07-01

    W. Cargill Geotechnical Laboratory DEPARTMENT OF THE ARMY Waterways Experiment Station, Corps of Engineers PO Box 631 Vicksburg, Mississippi 39180... Engineer Waterways Experiment Station Dredging Operations Geotechnical Laboratory PO Box 631, Vicksburg, Mississippi 39180-0631 Technical Support...improve the mainly empirical methods used in the past for containment area design. This report focuses on one of the primary factors in a well- engineered

  10. Determination and fractionation of sulphur in a contaminated dredged sediment.

    PubMed

    Tack, F M; Lapauw, F; Verloo, M G

    1997-12-01

    Conversion of sulphur compounds in reduced, contaminated sediments that are brought in upland conditions may largely affect the potential mobility of heavy metal contaminants. We applied selected methods for the determination of total sulphur and sulphur fractions in a contaminated sediment in the reduced state and after gradual drying and oxidation during 1 month. Dry ashing, followed by ion chromatographic detection, was reliable for the determination of total sulphur. Good recoveries were obtained in both reference samples and spiked samples. Total sulphur was 14.5+/-0.6 g kg(-1) relative to dry sediment. Wet chemical methods that involve the determination of acid-volatile, Zn-HCl-reducible, chromium-reducible, acetone-soluble and HI-reducible sulphur were used to estimate specific sulphur forms. Results for acetone-soluble sulphur were to high and not consistent with results for other fractions. Major part of sulphur in the sediment (90%) was inorganic. Sulphides were converted partially to sulphate and to intermediary oxidised sulphur compounds upon oxidation of the sediment. The results suggested that the intermediary oxidised sulphur pool in the reduced sediment (2.5 g kg(-1)) mainly consisted of pyrite, that was not converted during drying and oxidation. No significant changes in organic sulphur were detected.

  11. Dredged Material Management Categories for Tracking Beneficial Use

    DTIC Science & Technology

    2015-06-01

    during navigation projects. Although the NDC does not differentiate disposal and beneficial use, the database is currently the most comprehensive...ecosystem preservation and sustainable development (ASCE Policy Statement 522 ASCE 2010). ASCE Policy Statement 522 states, “Regional sediment management...dredges and Corps contract dredges between 1995 and 2011 (DIS database 29-Feb-2012 with “actual cy” sorted as preferred volume estimate). Navigational

  12. Tylers Beach, Virginia, dredged material plume monitoring project, September 27 to October 4, 1991. Final report

    SciTech Connect

    thevenot, M.M.; Prickett, T.L.; Kraus, N.C.

    1992-12-01

    The Tylers Beach, Virginia, Dredged Material Plume Monitoring Project (TBMP) was conducted during the period 27 September to 4 October 1991. The project was conducted under the Dredging Research Program Technical Area 1, entitled 'Analysis of Dredged Material Placed in Open Water,' in support of the U.S. Army Engineer District, Norfolk. The objectives of the TBMP were to (a) collect suspended material concentration data and current data to determine the potential for dredged material issuing from a pipeline discharge to reach environmentally sensitive areas adjacent to the placement site, and (b) continue development of PLUmes MEasurement System (PLUMES) for monitoring dredged material plumes. This report provides an overview of the equipment and procedures used during the TBMP, together with a presentation of the TBMP data and analysis results. The TBMP produced an extensive, high-quality data set from 12 acoustic surveys and numerous suspended material and bottom grab samples.... Acoustic Doppler Current Profiler (ADCP), PLUme MEasurement System (PLUMES), Dredged material, Point of-Shoals, James River, Suspended material.

  13. Beneficial Uses of Dredged Material Case Study: San Francisco Bay Region

    EPA Pesticide Factsheets

    A major interagency, regional planning effort led to the development of the Long-Term Management Strategy and other planning programs in the San Francisco Bay area. These programs incorporate beneficial uses of dredged material into local projects.

  14. The Role of the Federal Standard in the Beneficial Use of Dredged Material

    EPA Pesticide Factsheets

    A guide for USACE Districts, other federal agencies, state agencies, local governments, and private interest groups. The Federal Standard Paper provides guidance on using dredged material as a resource to achieve environmental and economic benefits.

  15. D2M2 Dredged-Material Disposal Management Model. User’s Manual

    DTIC Science & Technology

    1984-07-01

    developed by Rochelle Barkin and the network model and the branch-and-bound algorithm were formulated by David Ford and Darryl Davis, Chief, Planning...10 Appendix I: Reprint of "Dredged-material Disposal Management Model" by David T. Ford...By David T. Ford,’ M. ASCE Aae•mA: To identify efficient dredged-material disposal management strat- egies for the Delaware River navigation system

  16. Bioassays on Illinois waterway dredged material. Final report

    SciTech Connect

    Moore, D.W.; Gibson, A.B.; Dillon, T.M.

    1992-12-01

    Sediment from the Illinois Waterway navigation channel is hydraulically dredged by the US Army Engineer District, Rock Island, and placed in the nearshore environment via pipeline. Water returning to the river can have a high-suspended solids load approaching fluid mud consistency. There is a concern that this return water may exceed the State of Illinois water quality standards for ammonia and have adverse effects on aquatic life. To address these concerns, composite sediment samples and site water collected from selected sites in the Illinois Waterway were evaluated in toxicity tests. Acute (48-hr) toxicity tests were conducted with two species, Pimephales promelas (the fathead minnow) and Daphnia magna (a freshwater cladoceran). A chronic (21-day) toxicity test was also conducted using Daphnia magna. Animals were exposed separately to different concentrations of filtered and unfiltered elutriates prepared from Acute, Cadmium, Daphnia magna, Pimephales promela, Ammonia, Chronic, Elutriate, Sediment, Bioassay, Cladoceran, Fathead minnow. Illinois Waterway edged material. Total ammonia concentrations were measured in all tests and the un-ionized fraction was calculated by adjusting for temperature and pH. Tests were conducted at the US Army Engineer Waterways Experiment Station, Vicksburg, MS. In addition, as part of an interlaboratory effort, a 48-hr acute toxicity test with Pimephales pomelas fry was conducted concurrently by the Hygienic Laboratory of the University of Iowa, Des Moines, IA.

  17. Evaluation of dredged material proposed for ocean disposal from Buttermilk Channel, New York

    SciTech Connect

    Gardiner, W.W.; Barrows, E.S.; Antrim, L.D; Gruendell, B.D.; Word, J.Q.; Tokos, J.J.S.

    1996-08-01

    Buttermilk Channel was one of seven waterways that was sampled and evaluated for dredging and sediment disposal. Sediment samples were collected and analyses were conducted on sediment core samples. The evaluation of proposed dredged material from the channel included bulk sediment chemical analyses, chemical analyses of site water and elutriate, water column and benthic acute toxicity tests, and bioaccumulation studies. Individual sediment core samples were analyzed for grain size, moisture content, and total organic carbon. A composite sediment samples, representing the entire area proposed for dredging, was analyzed for bulk density, polynuclear aromatic hydrocarbons, and 1,4-dichlorobenzene. Site water and elutriate were analyzed for metals, pesticides, and PCBs.

  18. Potential contaminants at a dredged spoil placement site, Charles City County, Virginia, as revealed by sequential extraction

    PubMed Central

    Tang, Jianwu; Whittecar, G Richard; Johannesson, Karen H; Daniels, W Lee

    2004-01-01

    Backfills of dredged sediments onto a former sand and gravel mine site in Charles City County, VA may have the potential to contaminate local groundwater. To evaluate the mobility of trace elements and to identify the potential contaminants from the dredged sediments, a sequential extraction scheme was used to partition trace elements associated with the sediments from the local aquifer and the dredged sediments into five fractions: exchangeable, acidic, reducible, oxidizable, and residual phases. Sequential extractions indicate that, for most of the trace elements examined, the residual phases account for the largest proportion of the total concentrations, and their total extractable fractions are mainly from reducible and oxidizable phases. Only Cd, Pb, and Zn have an appreciable extractable proportion from the acidic phase in the filled dredged sediments. Our groundwater monitoring data suggest that the dredged sediments are mainly subject to a decrease in pH and a series of oxidation reactions, when exposed to the atmosphere. Because the trace elements released by carbonate dissolution and the oxidation (e.g., organic matter degradation, iron sulfide and, ammonia oxidation) are subsequently immobilized by sorption to iron, manganese, and aluminum oxides, no potential contaminants to local groundwater are expected by addition of the dredged sediments to this site.

  19. Evaluation of dredged material proposed for ocean disposal from Shark River Project area

    SciTech Connect

    Antrim, L.D.; Gardiner, W.W.; Barrows, E.S.; Borde, A.B.

    1996-09-01

    The objective of the Shark River Project was to evaluate proposed dredged material to determine its suitability for unconfined ocean disposal at the Mud Dump Site. Tests and analyses were conducted on the Shark River sediments. The evaluation of proposed dredged material consisted of bulk sediment chemical and physical analysis, chemical analyses of dredging site water and elutriate, water-column and benthic acute toxicity tests, and bioaccumulation tests. Individual sediment core samples collected from the Shark River were analyzed for grain size, moisture content, and total organic carbon (TOC). One sediment composite was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAHs), and 1,4- dichlorobenzene. Dredging site water and elutriate, prepared from suspended-particulate phase (SPP) of the Shark River sediment composite, were analyzed for metals, pesticides, and PCBs. Benthic acute toxicity tests and bioaccumulation tests were performed.

  20. Birds of the Savannah Harbor Navigation Project, Dredged Material Disposal Areas, 19942012

    DTIC Science & Technology

    2016-03-01

    additional mitigation requirement, another bird island was created nearshore called Tomkins Island. This island provides approxi- mately 5 acres of...use vocalizations (e.g., pishing sounds or a mimicked or recorded screech owl call , or a combination of both). If no birds were detected within 15...ER D C/ EL T R- 16 -4 Dredging Operations Technical Support Program Birds of the Savannah Harbor Navigation Project, Dredged Material

  1. Polycyclic aromatic hydrocarbons in sediments at dredged material disposal sites around England: concentrations in 2013 and time trend information at selected sites 2008-2013.

    PubMed

    Rumney, Heather S; Bolam, Stefan G; Law, Robin J

    2015-03-15

    The maintenance of navigation channels to ports and the development of their facilities present a need to conduct dredging operations, and the subsequent disposal of dredged material at sea. Contaminant concentrations in candidate dredged material are determined and their possible impacts considered during the licensing process, which can result in the exclusion of some material from sea disposal. Monitoring of disposal sites is conducted in order to ensure that no undesirable impacts are occurring. In this study we consider the levels of polycyclic aromatic hydrocarbons (PAHs) in sediments at a number of disposal sites monitored in 2013 and variations in concentrations over time at three sites during the period 2008-2013. These were assessed using established sediment quality guidelines. Elevated PAH concentrations were generally observed only within the boundaries of the disposal sites studied.

  2. Removal and Re-use of Tar-contaminated Sediment by Freeze-dredging at a Coking Plant Luleå, Sweden.

    PubMed

    Rostmark, Susanne C; Colombo, Manuel; Knutsson, Sven; Öberg, Gunilla

      Submerged tar-contaminated sediment are generally very loose, which makes remediation challenging. We tested if a modified version of freeze-dredging could be used to remove and dewater such sediment in a canal down-stream a coking plant. PVC hoses carrying a heat medium were placed horizontally in the submerged sediment. Five days of freezing allowed straightforward removal of most of the sediment. Flat freeze cells were placed side by side in the canal to remove the rest. The freeze-thaw process increased the dry substance content from approximately 50 to 80%. Outdoors storage under rainy conditions did not re-wet the dried sediment. The material was successfully used as feed-stock in the coking plant, with the double cost-benefit of avoided transportation to deposit and reduced use of coal. The study demonstrates that freeze-dredging can facilitate removal, storage and beneficial re-use of submerged tar-contaminated sediment.

  3. Dredged material decontamination demonstration for the port of New York/New Jersey.

    PubMed

    Jones, K W; Feng, H; Stern, E A; Lodge, J; Clesceri, N L

    2001-07-30

    Management of contaminated dredged material is a significant challenge in the Port of New York and New Jersey as a result of more stringent regional ocean placement regulations with escalating costs for upland placement. One component of an overall management plan can be the application of a decontamination technology followed by creation of a product suitable for beneficial use. This concept is the focus of a project now being carried out by the US Environmental Protection Agency, Region 2, the US Army Corps of Engineers, New York District, the US Department of Energy, Brookhaven National Laboratory, and regional university groups that have included Rensselaer Polytechnic Institute, Rutgers University, New Jersey Institute of Technology, and Stevens Institute of Technology. The project has progressed through phased testing of commercial technologies at the bench scale (15 liters) (Marcor, Metcalf & Eddy, Gas Technology Institute, Westinghouse Science & Technology, BioGenesis, International Technology, and BioSafe) and pilot-scale (1.5-500m(3)) (BioGenesis, Gas Technology Institute, and Westinghouse Science & Technology) levels. The technologies developed by Gas Technology Institute and BioGenesis are now going forward to commercial demonstration facilities that are intended to treat from 23000 to 60000m(3) of dredged material during their first operational period in 2001-2002. Beneficial use products are soils and cement. Treatment costs for the final commercial facilities are estimated at US$ 39 per m(3). Selection of the technologies was made based on the effectiveness of the treatment process, evaluation of the possible beneficial use of the treated materials, and other factors. Major elements of the project are summarized here.

  4. Evaluation of dredged material proposed for ocean disposal from Westchester Creek project area, New York

    SciTech Connect

    Pinza, M.R.; Gardiner, W.W.; Barrows, E.S.; Borde, A.B.

    1996-11-01

    The objective of the Westchester Creek project was to evaluate proposed dredged material from this area to determine its suitability for unconfined ocean disposal at the Mud Dump Site. Westchester Creek was one of five waterways that the US Army Corps of Engineers- New York District (USACE-NYD) requested the Battelle/Marine Sciences Laboratory (MSL) to sample and evaluate for dredging and disposal in May 1995. The evaluation of proposed dredged material from the Westchester Creek project area consisted of bulk sediment chemical analyses, chemical analyses of dredging site water and elutriate, benthic acute and water-column toxicity tests, and bioaccumulation studies. Thirteen individual sediment core samples were collected from this area and analyzed for grain size, moisture content, and total organic carbon (TOC). One composite sediment sample representing the Westchester Creek area to be dredged, was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAHs), and 1,4-dichlorobenzene. Dredging site water and elutriate water, which is prepared from the suspended- particulate phase (SPP) of the Westchester Creek sediment composite, was analyzed for metals, pesticides, and PCBS.

  5. Trace elements in soil and biota in confined disposal facilities for dredged material.

    PubMed

    Beyer, W N; Miller, G; Simmers, J W

    1990-01-01

    We studied the relation of trace element concentrations in soil to those in house mice (Mus musculus), common reed (Phragmites australis) and ladybugs (Coccinella septempunctata at five disposal facilities for dredged material. The sites had a wide range of soil trace element concentrations, acid soils and a depauperate fauna. They were very poor wildlife habitat because they were dominated by the common reed. Bioassay earthworms exposed to surface soils from three of the five sites died, whereas those exposed to four of five soils collected a meter deep survived, presumably because the deeper, unoxidized soil, was not as acid. Concentrations of Ni and Cr in the biota from each of the sites did not seem to be related to the concentrations of the same elements in soil. Although Pb, Zn and Cu concentrations in biota were correlated with those in soil, the range of concentrations in the biota was quite small compared to that in soil. The concentrations of Pb detected in mice were about as high as the concentrations previously reported in control mice from other studies. Mice from the most contaminated site (530 ppm Pb in soil) contained only slightly more Pb (8 ppm dry wt) than did mice (2-6 ppm dry wt) from sites containing much less Pb (22-92 ppm in soil). Despite the acid soil conditions, very little Cd was incorporated into food chains. Rather, Cd was leaching from the surface soil. We concluded that even the relatively high concentrations of trace elements in the acid dredged material studied did not cause high concentrations of trace elements in the biota.

  6. Trace elements in soil and biota in confined disposal facilities for dredged material

    USGS Publications Warehouse

    Beyer, W.N.; Miller, G.; Simmers, J.W.

    1990-01-01

    We studied the relation of trace element concentrations in soil to those in house mice (Mus musculus), common reed (Phragmites australis) and ladybugs (Coccinella septempunctata) at five disposal facilities for dredged material. The sites had a wide range of soil trace element concentrations, acid soils and a depauperate fauna. They were very poor wildlife habitat because they were dominated by the common reed. Bioassay earthworms exposed to surface soils from three of the five sites died, whereas those exposed to four of five soils collected a meter deep survived, presumably because the deeper, unoxidized soil, was not as acid. Concentrations of Ni and Cr in the biota from each of the sites did not seem to be related to the concentrations of the same elements in soil. Although Pb, Zn and Cu concentrations in biota were correlated with those in soil, the range of concentrations in the biota was quite small compared to that in soil. The concentrations of Pb detected in mice were about as high as the concentrations previously reported in control mice from other studies. Mice from the most contaminated site (530 ppm Pb in soil) contained only slightly more Pb (8 ppm dry wt) than did mice (2-6 ppm dry wt) from sites containing much less Pb (22-92 ppm in soil). Despite the acid soil conditions, very little Cd was incorporated into food chains. Rather, Cd was leaching from the surface soil. We concluded that even the relatively high concentrations of trace elements in the acid dredged material studied did not cause high, concentrations of trace elements in the biota.

  7. A multi-criteria approach for the dumping of dredged material in the Thermaikos Gulf, Northern Greece.

    PubMed

    Kapsimalis, Vasilios; Panagiotopoulos, Ioannis; Kanellopoulos, Theodore; Hatzianestis, Ioannis; Antoniou, Panayota; Anagnostou, Christos

    2010-12-01

    A multi-criteria approach was applied for the disposal into the sea of ∼1,100,000 m(3) of sediment, dredged from a coastal area in the northeastern part of the Thermaikos Gulf. This sediment (classified as muddy) is distributed vertically into two distinct Layers (A and B) with the thickness of the surficial sedimentary unit ranging from 7 to 54 cm. Its geochemistry reveals increased Cr and Ni concentrations, which may be attributed to natural enrichment through the erosion of the adjacent igneous and metamorphic rocks. In addition, a low to moderate contamination from urban-originated heavy metals, like Cu, Pb and Zn as well as from aliphatic and polycyclic hydrocarbons was identified for the upper Layer A. However, the limited proportion (5.5%) of the polluted Layer A in the total volume of the dredged material could not affect the good quality (assessed by the Sediment Quality Guidelines) of the bulk sediment. The identification of the optimum marine dumping site was based on (a) the physicochemical similarity (detected by the application of a cluster analysis) of the dredged material with the surficial deposits of potential dumping sites in the Outer Thermaikos Gulf, and (b) the consideration, based on previous studies, of various criteria related to the disposal area such as deep-water circulation, influence on living resources, impact on economical (aquaculture, fishing, navigation), recreational (fishing) and military activities.

  8. Summary of a workshop on interpreting bioaccumulation data collected during regulatory evaluations of dredged material. Final report

    SciTech Connect

    Bridges, T.S.; Moore, D.W.; Landrum, P.; Neff, J.; Cura, J.

    1996-07-01

    Evaluating the environmental consequences of contaminant bioaccumulation resulting from dredged material disposal is a complex technical and regulatory problem. This problem is exacerbated by the high cost of bioaccumulation testing and the lack of explicit guidance on how bioaccumulation data should be interpreted and used within a regulatory program. Bioaccumulation is a measurable phenomenon, rather than an effect. Without specific information about biological effects (e.g., reduced survival, growth, reproduction in animals, cancer risk in humans) resulting from bioaccumulation, it is difficult if not impossible from a regulatory standpoint to objectively determine what level of bioaccumulation constitutes an `unacceptable adverse effect.` Existing regulatory guidance attempts to overcome this with two approaches, both of which use low aquatic trophic level organisms and a reference-based comparison. In the first approach, the level of bioaccumulation of a specific contaminant is compared with a numerical effect limit, such as a Food and Drug Administration action level or a fish advisory. If the level of the contaminant in the organism exceeds the numerical limit, it is equated to an unacceptable adverse effect. If it does not, or there is no numerical limit, the second approach involves a comparison with animals exposed to a reference sediment. If bioaccumulation in the animals exposed to the dredged material exceeds that of animals exposed to the reference, a number of subjective factors are then evaluated to determine whether or not dredged material disposal will result in an `unacceptable adverse effect` (U.S. Environmental Protection Agency (USEPA)/U.S. Army Corps of Engineers (USACE) 1991, 1994).

  9. Biosolids and dredged materials: alternative sources of nutrients for crop productivity and sustainability of pasture-based agroecosystem

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Domestic sewage sludge or “biosolids” and lake-dredged materials are examples of materials that can be used to cut fertilizer costs in pasture-based animal agriculture. Sustainable biosolids and lake-dredged materials management is based upon controlling and influencing the quantity, quality and cha...

  10. Effects of long-term dumping of harbor-dredged material on macrozoobenthos at four disposal sites along the Emilia-Romagna coast (Northern Adriatic Sea, Italy).

    PubMed

    Simonini, R; Ansaloni, I; Cavallini, F; Graziosi, F; Iotti, M; Massamba N'siala, G; Mauri, M; Montanari, G; Preti, M; Prevedelli, D

    2005-12-01

    Sediment from harbors of the Emilia-Romagna (Northern Adriatic Sea) were dredged and dumped in four disposal areas characterized by muddy bottoms. The long-term effects of the dumping on macrozoobenthic communities were investigated before and after 6 month, 8 month, 2 years and 4 years. The disposal of dredged material did not influence the granulometry and %TOC in the sediment, and no alterations in the structure of the macrobenthic communities were observed in the four areas. The lack of impact could be ascribed to the environmental characteristics and precautionary measures taken to minimize the effects of the dumping. It appears that: (1) the communities of the dumping areas are well adapted to unstable environments; (2) the sediments were disposed gradually and homogeneously over relatively large areas; Other factors that help to reduce the impact of sediment disposal are the low concentrations of contaminants in dredged materials and the similarity of sediment in the dredged and disposal areas. Off-shore discharge appears a sustainable strategy for the management of uncontaminated dredged sediments from the Northern Adriatic Sea harbors.

  11. 78 FR 73097 - Ocean Dumping; Sabine-Neches Waterway (SNWW) Ocean Dredged Material Disposal Site Designation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-05

    ... material exists, and if analysis of the dredged material indicates that it is suitable for open-water... perturbations in water quality or other environmental conditions during initial mixing caused by disposal... SNWW CIP. Specific Selection Criteria 1. Geographical position, depth of water, bottom topography,...

  12. Analysis of environmental effects of the use of stabilized dredged material from New York/New Jersey Harbor, USA, for construction of roadway embankments.

    PubMed

    Douglas, W Scott; Maher, Ali; Jafari, Farhad

    2005-11-01

    Since the 1997 local ban on ocean dumping of dredged sediments, the state of New Jersey has pursued a policy of environmentally sound solutions to the controversial problem of dredged material management, including beneficial use of dredged material stabilized with pozzolanic additives (SDM). A pilot study was initiated in 1998 to evaluate the use of SDM in the construction of highway embankments. Using 80,000 cubic yards of silty dredged material, 2 embankments were constructed from SDM on a commercial development area adjacent to the New York/New Jersey Harbor. This article presents the evaluation of the environmental effects of the SDM, including fugitive air emissions, leachate, and stormwater quality. Engineering properties, handling and management techniques of the SDM, constructability, and performance were also evaluated, the results of which are published elsewhere. The findings demonstrate that although there are measurable releases of contaminants to the environment from the SDM, these releases are not significant long-term threats to human health or the environment. Policies currently in place to regulate the management of SDM that include limiting placement options to previously contaminated sites with institutional and engineering controls will further reduce the potential for environmental impact and, in fact, have the potential to produce significant environmental benefit.

  13. Evaluation of dredged material proposed for ocean Disposal from Shoal Harbor/Compton Creek Project Area

    SciTech Connect

    Gardiner, W.W.; Borde, A.B.; Nieukirk, S.L.; Barrows, E.S.; Gruendell, B.D.; Word, J.Q.

    1996-10-01

    The objective of the Shoal Harbor/Compton Creek Project was to evaluate proposed dredged material from the Shoal harbor/Compton Creek Project Area in Belford and Monmouth, New Jersey to determine its suitability for unconfined ocean disposal at the Mud Dump Site. This was one of five waterways that the US Army Corps of Engineers- New York District requested the Battelle Marine Sciences Laboratory (MSL) to sample and evaluate for dredging and disposal in May 1995. The evaluation of proposed dredged material from the Shoal Harbor/Compton Creek Project area consisted of bulk chemical analyses, chemical analyses of dredging site water and elutriate, benthic and water-column acute toxicity tests and bioaccumulation studies. Eleven core samples were analyzed or grain size, moisture content, and total organic carbon. Other sediments were evaluated for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congers, polynuclear aromatic hydrocarbons, and 1,4- dichlorobenzene. Dredging site water and elutriate water were analyzed for metals, pesticides, and PCBs.

  14. Evaluation of Dredged Material Proposed for Ocean Disposal from Port Chester, New York

    SciTech Connect

    Barrows, E.S.; Mayhew, H.L.; Word, J.Q.; Tokos, J.J.S.

    1996-08-01

    Port Chester was one of seven waterways that the US Army Corps of Engineers-New York District requested the Battelle Marine Sciences Laboratory to sample and evaluate for dredging and disposal in March 1994. Tests and analyses were conducted on Port Chester sediment core samples. Because the Port Chester area is located on the border between New York and southeast Connecticut, its dredged material may also be considered for disposal at the Central Long Island Sound Disposal Site. The sediment evaluation consisted of bulk sediment chemical analyses, chemical analyses of site water and dredged material elutriate preparations, water-column and benthic acute toxicity tests, and bioaccumulation studies. Individual sediment core samples collected from Port Chester were analyzed for grain size, moisture content, and total organic carbon. In addition, sediment was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl congers, polynuclear aromatic hydrocarbons and 1,4-dichlorobenzene.

  15. Valorization of unauthorized sea disposal dredged sediments as a road foundation material.

    PubMed

    Achour, Raouf; Abriak, Nor-Edine; Zentar, Rachid; Rivard, Patrice; Gregoire, Pascal

    2014-08-01

    The main objective of this study is to show the ability of fine dredged material (mainly silty material) to be used in road construction project. This paper is divided into three parts. In the first part, the physical, the mineralogical and the mechanical characteristics of the used fine dredged sediments, as well as their chemical composition and environmental impacts are presented. In the second part, the methodology developed to design the road made from dredged fine sediment is developed. The third part of the paper focuses on the presentation of the road construction and the interpretation of analyses made on cores drilled samples from the road and measurements of the deflection of the road. The environmental assessment, based on leaching tests, is also performed at different issues.

  16. Prediction of Heavy Metal Uptake by Marsh Plants Based on Chemical Extraction of Heavy Metals from Dredged Material.

    DTIC Science & Technology

    1978-02-01

    A field and laboratory study was conducted to establish the extent of heavy metal absorption and uptake by marsh plant species from dredged material...emphasizes the need for a method to predict heavy metal availability from dredged material to plants. DTPA extraction of heavy metals gave the best correlations with actual heavy metal concentrations in marsh plants.

  17. Evaluation of dredged material proposed for ocean disposal from Hackensack River Project Area, New York

    SciTech Connect

    Gruendell, B.D.; Barrows, E.S.; Borde, A.B.

    1997-01-01

    The objective of the bioassay reevaluation of the Hackensack River Federal Project was to reperform toxicity testing on proposed dredged material with current ammonia reduction protocols. Hackensack River was one of four waterways sampled and evaluated for dredging and disposal in April 1993. Sediment samples were re-collected from the Hackensack River Project area in August 1995. Tests and analyses were conducted according to the manual developed by the USACE and the U.S. Environmental Protection Agency (EPA), Evaluation of Dredged Material Proposed for Ocean Disposal (Testing Manual), commonly referred to as the {open_quotes}Green Book,{close_quotes} and the regional manual developed by the USACE-NYD and EPA Region II, Guidance for Performing Tests on Dredged Material to be Disposed of in Ocean Waters. The reevaluation of proposed dredged material from the Hackensack River project area consisted of benthic acute toxicity tests. Thirty-three individual sediment core samples were collected from the Hackensack River project area. Three composite sediments, representing each reach of the area proposed for dredging, were used in benthic acute toxicity testing. Benthic acute toxicity tests were performed with the amphipod Ampelisca abdita and the mysid Mysidopsis bahia. The amphipod and mysid benthic toxicity test procedures followed EPA guidance for reduction of total ammonia concentrations in test systems prior to test initiation. Statistically significant acute toxicity was found in all three Hackensack River composites in the static renewal tests with A. abdita, but not in the static tests with M. bahia. Statistically significant acute toxicity and a greater than 20% increase in mortality over the reference sediment was found in the static renewal tests with A. abdita. Statistically significant mortality 10% over reference sediment was observed in the M. bahia static tests. 5 refs., 2 figs., 2 tabs.

  18. Evaluation of dredged material proposed for ocean disposal from Arthur Kill Project Area, New York

    SciTech Connect

    Gruendell, B.D.; Barrows, E.S.; Borde, A.B.

    1997-01-01

    The objective of the bioassay reevaluation of Arthur Kill Federal Project was to reperform toxicity testing on proposed dredged material following current ammonia reduction protocols. Arthur Kill was one of four waterways sampled and evaluated for dredging and disposal in April 1993. Sediment samples were recollected from the Arthur Kill Project areas in August 1995. Tests and analyses were conducted according to the manual developed by the USACE and the U.S. Environmental Protection Agency (EPA), Evaluation of Dredged Material Proposed for Ocean Disposal (Testing Manual), commonly referred to as the {open_quotes}Green Book,{close_quotes} and the regional manual developed by the USACE-NYD and EPA Region II, Guidance for Performing Tests on Dredged Material to be Disposed of in Ocean Waters. The reevaluation of proposed dredged material from the Arthur Kill project areas consisted of benthic acute toxicity tests. Thirty-three individual sediment core samples were collected from the Arthur Kill project area. Three composite sediments, representing each reach of the area proposed for dredging, was used in benthic acute toxicity testing. Benthic acute toxicity tests were performed with the amphipod Ampelisca abdita and the mysid Mysidopsis bahia. The amphipod and mysid benthic toxicity test procedures followed EPA guidance for reduction of total ammonia concentrations in test systems prior to test initiation. Statistically significant acute toxicity was found in all Arthur Kill composites in the static renewal tests with A. abdita, but not in the static tests with M. bahia. Statistically significant acute toxicity and a greater than 20% increase in mortality over the reference sediment was found in the static renewal tests with A. abdita. M. bahia did not show statistically significant acute toxicity or a greater than 10% increase in mortality over reference sediment in static tests. 5 refs., 2 figs., 2 tabs.

  19. Evaluation of dredged material proposed for ocean disposal from Bronx River Project Area, New York

    SciTech Connect

    Gruendell, B.D.; Gardiner, W.W.; Antrim, L.D.; Pinza, M.R.; Barrows, E.S.; Borde, A.B.

    1996-12-01

    The objective of the Bronx River project was to evaluate proposed dredged material from the Bronx River project area in Bronx, New York, to determine its suitability for unconfined ocean disposal at the Mud Dump Site. Bronx River was one of five waterways that the US Army Corps of Engineers-New York District (USAGE-NYD) requested the Battelle Marine Sciences Laboratory (MSL) to sample and to evaluate for dredging and disposal. Sediment samples were submitted for physical and chemical analyses, chemical analyses of dredging site water and elutriate, benthic and water-column acute toxicity tests, and bioaccumulation studies. Fifteen individual sediment core samples collected from the Bronx River project area were analyzed for grain size, moisture content, and total organic carbon (TOC). One composite sediment sample, representing the entire reach of the area proposed for dredging, was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAH), and 1,4- dichlorobenzene. Dredging site water and elutriate water, which was prepared from the suspended-particulate phase (SPP) of the Bronx River sediment composite, were analyzed for metals, pesticides, and PCBS.

  20. Evaluation of dredged material proposed for ocean disposal from Eastchester Project Area, New York

    SciTech Connect

    Antrim, L.D.; Pinza, M.R.; Barrows, E.S.; Gardiner, W.W.; Tokos, J.J.S.; Gruendell, B.D.; Word, J.Q.

    1996-07-01

    The objective of the Eastchester project (Federal Project [FP] No. 6) was to evaluate proposed dredged material from the Eastchester project area in the Hutchinson River to determine its suitability for unconfined ocean disposal at the Mud Dump Site. Eastchester was one of seven waterways that the U. S. Army Corps of Engineers-New York District (USACE-NYD) requested the Battelle/Marine Sciences Laboratory (MSL) to sample and evaluate for dredging and disposal in March 1994. The evaluation of proposed dredged material from the Eastchester project area consisted of bulk sediment chemical analyses, chemical analyses of dredging site water and elutriate, water- column and benthic acute toxicity tests, and bioaccumulation studies. Eighteen individual sediment core samples collected from the Eastchester project area were analyzed for grain size, moisture content, and total organic carbon (TOC). Two composite sediment samples, representing the upstream and lower reaches of the area proposed for dredging, were analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAHs), and 1,4- dichlorobenzene. Dredging site water and elutriate water, which is prepared from the suspended-particulate phase (SPP) of the two Eastchester sediment composites, were analyzed for metals, pesticides, and PCBS. An additional 1 1 composite samples were created for the USACE-New England Division (USACE-NED) using the same 18 Eastchester core samples but combined into different composites. These composites were analyzed for metals, chlorinated pesticides, PCB congeners, PAHS, and 1,4-dichlorobenzene. Water-column or SPP toxicity tests were performed along with bioaccumulation tests.

  1. 40 CFR 230.60 - General evaluation of dredged or fill material.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false General evaluation of dredged or fill material. 230.60 Section 230.60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN... examined in order to assess whether it is sufficiently removed from sources of pollution to...

  2. Evaluating Environmental Effects of Dredged Material Management Alternatives: A Technical Framework

    DTIC Science & Technology

    1992-11-01

    the beach. 6.2.3 Aquaculture/ Mariculture Because of the increasing difficulty and expense of obtaining CDFs for use as single purpose disposal areas...the development of a multiple-use strategy such as aquaculture or mariculture is desir- able. Dredged material containment sites commonly possess

  3. Chemical gradients in sediment cores from an EPA reference site off the Farallon Islands - Assessing chemical indicators of dredged material disposal in the deep sea

    USGS Publications Warehouse

    Bothner, Michael H.; Gill, P.W.; Boothman, W.S.; Taylor, B.B.; Karl, Herman A.

    1998-01-01

    Heavy metal and organic contaminants have been determined in undisturbed sediment cores from the US Environmental Protection Agency reference site for dredged material on the continental slope off San Francisco. As expected, the concentrations are significantly lower than toxic effects guidelines, but concentrations of PCBs, PAHs, Hg, Pb, and Clostridium perfringens (a bacterium spore found in sewage) were nearly two or more times greater in the surface sediments than in intervals deeper in the cores. These observations indicate the usefulness of measuring concentration gradients in sediments at the San Francisco deep ocean disposal site (SF-DODS) where a thin (0.5 cm thick) layer of dredged material has been observed beyond the boundary. This thin layer has not been chemically characterized by the common practice of homogenizing over the top 10 cm. An estimated 300 million cubic yards of dredged material from San Francisco Bay are expected to be discharged at the SF-DODS site during the next 50 years. Detailed depth analysis of sediment cores would add significant new information about the fate and effects of dredged material in the deep sea.

  4. Ecological evaluation of proposed dredged material from Richmond Harbor

    SciTech Connect

    Pinza, M R; Ward, J A; Mayhew, H L; Word, J Q; Niyogi, D K; Kohn, N P

    1992-10-01

    During the summer of 1991, Battelle/Marine Sciences Laboratory (MSL) was contracted to conduct sampling and testing of sediments proposed for dredging of Richmond Harbor, California. The MSL collected sediment cores to a depth of [minus]40 ft MLLW ([minus]38 ft + 2 ft overdepth) from 28 (12-in. core) and 30 (4-in. core) stations. The sediment cores were allocated to six composite samples referred to as sediment treatments, which were then subjected to physical, chemical, toxicological, and bioaccumulation testing. Physical and chemical parameters included grain size, total organic carbon (TOC), total volatile solids (TVS), oil and grease, total petroleum hydrocarbons (TPH), polynuclear aromatic hydrocarbons (PAH), chlorinated pesticides, polychlorinated biphenyis (PCBs), priority pollutant metals, and butyltins. The results from the test treatments were compared to results from five reference treatments representative of potential in-bay and offshore disposal sites.

  5. Ecological evaluation of proposed dredged material from Richmond Harbor

    SciTech Connect

    Pinza, M.R.; Ward, J.A.; Mayhew, H.L.; Word, J.Q.; Niyogi, D.K.; Kohn, N.P.

    1992-10-01

    During the summer of 1991, Battelle/Marine Sciences Laboratory (MSL) was contracted to conduct sampling and testing of sediments proposed for dredging of Richmond Harbor, California. The MSL collected sediment cores to a depth of {minus}40 ft MLLW ({minus}38 ft + 2 ft overdepth) from 28 (12-in. core) and 30 (4-in. core) stations. The sediment cores were allocated to six composite samples referred to as sediment treatments, which were then subjected to physical, chemical, toxicological, and bioaccumulation testing. Physical and chemical parameters included grain size, total organic carbon (TOC), total volatile solids (TVS), oil and grease, total petroleum hydrocarbons (TPH), polynuclear aromatic hydrocarbons (PAH), chlorinated pesticides, polychlorinated biphenyis (PCBs), priority pollutant metals, and butyltins. The results from the test treatments were compared to results from five reference treatments representative of potential in-bay and offshore disposal sites.

  6. Guidance for Performing Tests on Dredged Material Proposed for Ocean Disposal at the Historic Area Remediation Site

    EPA Pesticide Factsheets

    Guidance presents the sediment testing guidelines and requirements to be used by applicants who wish to obtain a Department of the Army permit from the USACE-New York District for dredging and placement of dredged material at the HARS in the Atlantic Ocean

  7. Reclamation of abandoned mined lands along th Upper Illinois Waterway using dredged material

    SciTech Connect

    Van Luik, A; Harrison, W

    1982-01-01

    Sediments were sampled and characterized from 28 actual or proposed maintenance-dredging locations in the Upper Illinois Waterway, that is, the Calumet-Sag Channel, the Des Plaines River downstream of its confluence with the Calumet-Sag Channel, and the Illinois River from the confluence of the Kankakee and Des Plaines rivers to Havana, Illinois. Sufficient data on chemical constituents and physical sediments were obtained to allow the classification of these sediments by currently applicable criteria of the Illinois Environmental Protection Agency for the identification of hazardous, persistent, and potentially hazardous wastes. By these criteria, the potential dredged materials studied were not hazardous, persistent, or potentially hazardous; they are a suitable topsoil/ reclamation medium. A study of problem abandoned surface-mined land sites (problem lands are defined as being acidic and/or sparsely vegetated) along the Illinois River showed that three sites were particularly well suited to the needs of the Corps of Engineers (COE) for a dredged material disposal/reclamation site. Thes sites were a pair of municipally owned sites in Morris, Illinois, and a small corporately owned site east of Ottawa, Illinois, and adjacent to the Illinois River. Other sites were also ranked as to suitability for COE involvement in their reclamation. Reclamation disposal was found to be an economically competitive alternative to near-source confined disposal for Upper Illinois Waterway dredged material.

  8. Economical Treatment of Dredged Material to Facilitate Beneficial Use

    DTIC Science & Technology

    2014-08-01

    contaminated sediments in beneficial use applications; • developing new management approaches exploiting the natural chemical, geochemical and...to the nature of the chemicals. Containment was determined to be the management mode of choice for highly contaminated sediments. Multiple treatment...attributed to the affinity of these compounds for natural organic matter and the competition of organic matter for the oxidizing agents. Most

  9. Recovery of floral and faunal communities after placement of dredged material on seagrasses in Laguna Madre, Texas

    NASA Astrophysics Data System (ADS)

    Sheridan, P.

    2004-03-01

    The objectives of this project were to determine how long alterations in habitat characteristics and use by fishery and forage organisms were detectable at dredged material placement sites in Laguna Madre, Texas. Water, sediment, seagrass, benthos, and nekton characteristics were measured and compared among newly deposited sediments and nearby and distant seagrasses each fall and spring over three years. Over this period, 75% of the estimated total surface area of the original deposits was either re-vegetated by seagrass or dispersed by winds and currents. Differences in water and sediment characteristics among habitat types were mostly detected early in the study. There were signs of steady seagrass re-colonization in the latter half of the study period, and mean seagrass coverage of deposits had reached 48% approximately three years after dredging. Clovergrass Halophila engelmannii was the initial colonist, but shoalgrass Halodule wrightii predominated after about one year. Densities of annelids and non-decapod crustaceans were generally significantly greater in close and distant seagrass habitats than in dredged material habitat, whereas densities of molluscs were not significantly related to habitat type. Nekton (fish and decapod) densities were almost always significantly greater in the two seagrass habitats than in dredged material deposits. Benthos and nekton communities in dredged material deposits were distinct from those in seagrass habitats. Recovery from dredged material placement was nearly complete for water column and sediment components after 1.5 to 3 years, but recovery of seagrasses, benthos, and nekton was predicted to take 4 to 8 years. The current 2 to 5 years dredging cycle virtually insures no time for ecosystem recovery before being disturbed again. The only way to ensure permanent protection of the high primary and secondary productivity of seagrass beds in Laguna Madre from acute and chronic effects of maintenance dredging, while ensuring

  10. Annual Reports Regarding Progress in Developing a Dredged Material Management Plan for the Long Island Sound Region

    EPA Pesticide Factsheets

    The site designation for the Western and Central Long Island Sound disposal sites requires the completion of a Dredged Material Management Plan (DMMP) and EPA to conduct an annual review of progress toward completion of the DMMP.

  11. Macrofaunal recovery following the intertidal recharge of dredged material: a comparison of structural and functional approaches.

    PubMed

    Bolam, S G

    2014-06-01

    There is a growing need to understand the functional implications of anthropogenic pressures, such as those following coastal disposal of dredged material. Current assessments, based on taxonomic structure of benthic organisms, only provide a limited capacity to determine functional impacts or recovery. This study assesses recovery of two intertidal dredged material recharge schemes, comparing results obtained based on taxonomic structure (univariate and multivariate approaches) and function (biological trait composition, functional diversity, secondary production) of the benthic assemblages. The assemblages recolonising both schemes were consistently less speciose, less densely-populated and exhibited multivariate community structures that differed from those of the reference areas. However, for both schemes metrics of functionality converged to those of reference areas, although some differences in trait composition persisted for up to 3 years. These data support the proposition that impacts of, and recovery from, anthropogenic disturbance should be assessed using a combination of both functional and taxonomic structural approaches.

  12. Application of a hazard assessment research strategy to the ocean disposal of a dredged material: Overview

    SciTech Connect

    Gentile, J.H.; Pesch, G.G.; Dillon, T.M.

    1989-01-01

    Under the Marine Protection, Research and Sanctuaries Act the U.S. Environmental Protection Agency (EPA) has responsibility for establishing and applying criteria for reviewing and evaluating permits for dumping wastes into the ocean, and the U.S. Army Corps of Engineers (COE) has responsibility for issuing permits for the disposal of dredged material into the ocean. After several years of operational experience, the EPA and the COE have reexamined the strengths and weaknesses of the permit program and the general state of the art in sediment testing for the evaluation of the disposal of dredged material into the marine environment. The chapter describes a predictive hazard assessment strategy and decision rationale for disposal that can be used as the basis for revisions both in the ocean dumping regulations and in the permitting program.

  13. Identifying, Planning, and Financing Beneficial Use Projects Using Dredged Material: Beneficial Use Planning Manual

    DTIC Science & Technology

    2007-10-01

    project spon- sors are active decision makers in the activities discussed in the Tech- nical Framework . In particular, it assumes that beneficial use...access. Recreational uses of dredged material tend to be heavily dependent on acquiring local funding. The innovative funding opportu- nities discussed ...having varying degrees of interest in beneficial use projects. For a more extensive discussion of public involvement planning, see Framework for

  14. Impacts of dredged material disposal on a tropical soft-bottom benthic assemblage.

    PubMed

    Cruz-Motta, J J; Collins, J

    2004-02-01

    The soft-bottom benthic macrofauna in a spoil-ground of dredged material in Cleveland Bay, North Queensland, Australia, was studied to detect possible impacts of the disposal of sediments. The spatial distribution of the assemblage was studied in relation to the source of the impact at 28 stations on four occasions during 1998 and 1999. Additionally, environmental variables were measured on each occasion at each station. Macrobenthic assemblages inside the spoil-ground were different from assemblages outside the spoil ground only immediately after (15 days) the disposal of dredged material. Given the decrease in the abundance of organisms and number of species, it is suggested that this effect was due to direct burial of the macrobenthic assemblage inside the spoil-ground. Macrobenthic assemblages inside the spoil ground were not different from assemblages outside the spoil ground 3 months after dumping. These results suggest that the soft-bottom macrobenthic assemblages may respond quickly to the disturbance associated with the dumping of dredged material.

  15. Reducing the effects of dredged material levees on coastal marsh function: sediment deposition and nekton utilization.

    PubMed

    Reed, Denise J; Peterson, Mark S; Lezina, Brian J

    2006-05-01

    Dredged material levees in coastal Louisiana are normally associated with pipeline canals or, more frequently, canals dredged through the wetlands to allow access to drilling locations for mineral extraction. The hydrologic impact on marshes behind the levee is of concern to coastal resource managers because of the potential impact on sediment transport and deposition, and the effect on estuarine organism access to valuable nursery habitat. This study examined the effects of gaps in dredged material levees, compared to continuous levees and natural channel banks, on these two aspects of marsh function. Field studies for sediment deposition were conducted biweekly for a year, and nekton samples were collected in spring and fall. Variation in nekton density among study areas and landscape types was great in part because of the inherent sampling gear issues and in part because of differences in characteristics among areas. Nekton densities were generally greater in natural compared to leveed and gapped landscapes. Differences in landscape type did not explain patterns in sediment deposition. The gaps examined appear to be too restrictive of marsh flooding to provide efficient movements of floodwaters onto the marsh during moderate flooding events. The "trapping" effect of the levees increases sediment deposition during extreme events. Gapping material levees may be an effective method of partially restoring upper marsh connection to nekton, but this method may work best in lower elevation marshes where nekton use is greater.

  16. A field study on phytoremediation of dredged sediment contaminated by heavy metals and nutrients: the impacts of sediment aeration.

    PubMed

    Wu, Juan; Yang, Lihua; Zhong, Fei; Cheng, Shuiping

    2014-12-01

    Compared to traditional chemical or physical treatments, phytoremediation has proved to be a cost-effective and environmentally sound alternative for remediation of contaminated dredged sediment. A field study was conducted in a sediment disposal site predominantly colonized by Typha angustifolia under different sediment moisture conditions to estimate the phytoremediation effects of dredged sediment. The moisture content was 37.30 % and 48.27 % in aerated and waterlogged sediment, respectively. Total nitrogen (TN) content was higher in the waterlogged sediment than in the aerated sediment. The total Cd contents were lower in aerated sediment, which was mainly resulted from the lower exchangeable fraction of Cd. The bioaccumulation of P, Cu and Pb in T. angustifolia was promoted by waterlogging, and the belowground tissue concentrations and accumulation factors (AFs) of Cu were higher than that of other metals, which can be explained by that Cu is an essential micronutrient for plants. Consistent with many previous studies, T. angustifolia showed higher metal levels in roots than in above-ground tissues at both the sediment conditions. Due to the improved biomass produced in the aerated sediment, the removals of nutrients and the metals by plant harvest were higher from aerated sediment than from waterlogged sediment. It was indicated that maintaining the dredged sediment aerated can avoid release risk and plant uptake of metals, while the opposite management option can promote phytoextraction of these contaminants.

  17. DETERMINING THE EFFECTIVENESS OF DREDGING: FIELD STUDY FOR EVALUATING DREDGING RESIDUALS

    EPA Science Inventory

    Dredging is a commonly selected remedy for the risk management of contaminated sediments. Even so, there are questions regarding both the short-term and long-term effectiveness of dredging. A significant aspect in the performance of dredging is dredging residuals. Post-dredging ...

  18. Dredging Operations Technical Support Program. Long-Term Monitoring of Eleven Corps of Engineers Habitat Development Field Sites Built of Dredged Material, 1974-1987

    DTIC Science & Technology

    1989-12-01

    landowner. Ranching, oil , and commercial and recreational fishing are the primary land and water uses adjacent to the BP site. 219. The BP site was selected... refined because the dredged material was applied too deep in most parts of both sites. This significantly affected vegetation survival and recovery...Techniques refined at the BP site for marsh development can be applied to other sites along the northern gulf coast where long wind fetches and bare

  19. Buffalo river dredging demonstration. Final report

    SciTech Connect

    Averett, D.E.; Zappi, P.A.; Tatem, H.E.; Gibson, A.C.; Tominey, E.A.

    1996-02-01

    The Corps of Engineers Buffalo District conducted a demonstration of equipment for dredging contaminated sediments. Several thousand cubic yards of sediment were removed from outside the Buffalo River Federal navigation channel limits using three dredge types: (1) open bucket, (2) enclosed bucket, and (3) submersible pump. The effectiveness of a silt screen deployed downstream of the dredge to reduce suspended sediment transport was also evaluated. Extensive sediment and water column monitoring and sampling were conducted during the 2-week demonstration as part of the effort to determine sediment resuspension rates and contaminant releases associated with the dredging operations. Water column samples were analyzed for total suspended solids, total organic carbon, PCBs, PAHs, metals, ammonia, and pH. A water column bioassay test using Daphnia magna was also performed to assess toxicity effects of the dredging operation. Results of this study were used to assess and refine techniques and laboratory tests that have been previously developed by the Corps of Engineers to predict sediment resuspension rates and contaminant releases. In another phase of the study, the Bureau of Mines demonstrated the use of polyelectrolytes for rapid removal of suspended solids from a dilute dredged material slurry.

  20. Evaluation of dredged material proposed for ocean disposal from South Brother Island Channel, New York

    SciTech Connect

    Barrows, E.S.; Gardiner, W.W.; Antrim, L.D.; Gruendell, B.D.; Word, J.Q.; Tokos, J.J.S.

    1996-09-01

    South Brother Island Channel was one of seven waterways that the US Army Crops of Engineers-New York District requested the Battelle/Marine Sciences Laboratory to sample and evaluate for dredging and disposal. Tests and analyses were conducted on South Brother Island Channel sediment core samples and evaluations were performed. The evaluation of proposed dredged material from South Brother Island Channel included bulk sediment chemical analyses, chemical analyses of site water and elutriate, water-column and benthic acute toxicity tests, and bioaccumulation studies. Individual sediment core samples collected from Souther Brother Island Channel were analyzed for grain size, moisture content, and total organic carbon. a composite sediment sample, representing the entire area proposed for dredging, was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl congers, polynuclear aromatic hydrocarbons, and 1,4- dichlorobenzene. Site water and elutriate water, prepared from the suspended-particle phase of South Brother Island Channel sediment, were analyzed for metals, pesticides, and PCBs.

  1. Evaluation of dredged material proposed for ocean disposal from Hudson River, New York

    SciTech Connect

    Gardiner, W.W.; Barrows, E.S.; Antrim, L.D.; Gruendell, B.D.; Word, J.Q.; Tokos, J.J.S.

    1996-09-01

    The Hudson River (Federal Project No. 41) was one of seven waterways that the U.S. Army Corps of Engineers-New York District (USACE-NYD) requested the Battelle Marine Sciences Laboratory (MSL) to sample and evaluate for dredging and disposal in March 1994. Sediment samples were collected from the Hudson River. Tests and analyses were conducted on Hudson River sediment core samples. The evaluation of proposed dredged material from the Hudson River included bulk sediment chemical analyses, chemical analyses of site water and elutriate, water-column and benthic acute toxicity tests, and bioaccumulation studies. Individual sediment core samples collected from Hudson River were analyzed for grain size, moisture content, and total organic carbon (TOC). A composite sediment sample, representing the entire area proposed for dredging, was analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAH), and 1,4-dichlorobenzene. Site water and elutriate water, prepared from the suspended-particulate phase (SPP) of Hudson River sediment, were analyzed for metals, pesticides, and PCBS. Water-column or SPP toxicity tests were performed with three species. Benthic acute toxicity tests were performed. Bioaccumulation tests were also conducted.

  2. Evaluation of Dredged Material Proposed for Ocean Disposal from Federal Projects in New York and New Jersey and the Military Ocean Terminal (MOTBY)

    SciTech Connect

    Barrows, E.S.; Antrim, L.D.; Pinza, M.R.; Gardiner, W.W.; Kohn, N.P.; Gruendell, B.D.; Mayhew, H.L.; Word, J.Q.; Rosman, L.B.

    1996-08-01

    The U.S. Army Corps of Engineers (USACE) is authorized by Section 103 of the Marine Protection, Research, and Sanctuaries Act of 1972 (MPRSA), Public Law 92-532, and by the Clean Water Act of 1972 (CWA) and Amendments of 1977 to permit, evaluate, and regulate the disposal of dredged material in ocean waters to minimize adverse environmental effects. Compliance with the regulations of the MPRSA calls for physical and biological testing of sediment proposed for dredging prior to its disposal in ocean waters. The testing required by the MPRSA criteria is conducted under a testing manual developed by the USACE and the U.S. Environmental Protection Agency (EPA), Evaluation of Dredged Material Proposed for Ocean Disposal (Testing Manual), commonly referred to as the `Green Book.` Testing protocols in the Green Book include bulk sediment analysis, grain size analysis, elutriate testing, and biological testing. The biological testing includes bioassays for acute toxicity as well as analysis to determine bioaccumulation of certain contaminants by marine organisms. The objective of the USACE-NYD Federal Projects Program was to evaluate sediment proposed for dredging and unconfined ocean disposal at the Mud Dump Site. The results of analytical measurements and bioassays performed on the test sediments were compared with analyses of sediment from the Mud Dump Reference Site to determine whether the test sediments were acutely toxic to marine organisms or resulted in statistically significantly greater bioaccumulation of contaminants in marine organisms, relative to the reference sediment. Testing for the federal project areas was performed according to the requirements.

  3. Bacteriological water quality effects of hydraulically dredging contaminated upper Mississippi River bottom sediment.

    PubMed Central

    Grimes, D J

    1980-01-01

    Bacteriological effects of hydraulically dredging polluted bottom sediment in the navigation channel of the Upper Mississippi River (river mile 827.5 [about 1,332 km] to 828.1 [about 1,333 km]) were investigated. Bottom sediment in the dredging site contained high total coliform densities (about 6,800 most-probable-number total coliform index per g [dry weight] and 3,800 membrane filter total coliforms per g [dry weight]), and fecal coliforms comprised an average 32% of each total coliform count. Total coliform and fecal coliform densities in water samples taken immediately below the dredge discharge pipe were each approximately four times corresponding upstream values; fecal streptococcus densities were approximately 50 times corresponding upstream values. Correlation analysis indicated that mean turbidity values downstream to the dredging operation were directly and significantly (r greater than 0.94) related to corresponding total coliform, fecal coliform, and fecal streptococcus densities. Salmonellae and shigellae were not recovered from either upstream or downstream water samples. Turbidity and indicator bacteria levels had returned to predredge values within less than 2 km below the dredge spoil discharge area at the prevailing current velocity (about 0.15 m/s). PMID:7377776

  4. Laboratory Assessment of Potential Impacts to Dungeness Crabs from Disposal of Dredged Material from the Columbia River

    SciTech Connect

    Vavrinec, John; Pearson, Walter H.; Kohn, Nancy P.; Skalski, J. R.; Lee, Cheegwan; Hall, Kathleen D.; Romano, Brett A.; Miller, Martin C.; Khangaonkar, Tarang P.

    2007-05-07

    Dredging of the Columbia River navigation channel has raised concerns about dredging-related impacts on Dungeness crabs (Cancer magister) in the estuary, mouth of the estuary, and nearshore ocean areas adjacent to the Columbia River. The Portland District, U.S. Army Corps of Engineers engaged the Marine Sciences Laboratory (MSL) of the U.S. Department of Energy’s Pacific Northwest National Laboratory to review the state of knowledge and conduct studies concerning impacts on Dungeness crabs resulting from disposal during the Columbia River Channel Improvement Project and annual maintenance dredging in the mouth of the Columbia River. The present study concerns potential effects on Dungeness crabs from dredged material disposal specific to the mouth of the Columbia River.

  5. Phytoremediation of metals contaminated dredged sediments: Use of synthetic chelates in metals phytoextraction

    NASA Astrophysics Data System (ADS)

    Sahut, C.; Geniaut, G.; Lillo, M. P.

    2003-05-01

    (in Times 10 points) The waterways maintenance leads to a large volume of dredged polluted sediments, to be disposed of, every year. As the economic disposal of dredged sediment is a single line along the stream they can behave as a sink of pollutant and a migration in the environment is observed. Chelate-enhanced phytoremediation has been proposed as an effective tool for the extraction of heavy metals from dredged sediment by plants. Lysimeters studies were conducted to study the phytoremediation of sediments with EDTA and lactic acid used as synthetic chelators. EDTA appeared to enhance metal solubility by plant uptake did not increase accordingly. Futhermore EDTA enhance metal leaching which could lead 10 groungwater pollution. To prevent these unwanted side-effects, careful management of phytoremediation and of the use of EDTA seems necessary.

  6. Beneficial use of dredged material for habitat creation, enhancement, and restoration in New York-New Jersey Harbor.

    PubMed

    Yozzo, David J; Wilber, Pace; Will, Robert J

    2004-10-01

    A comprehensive Dredged Material Management Plan (DMMP) has been developed by the US Army Corps of Engineers, New York District (USACE-NYD) and the Port Authority of New York and New Jersey (PANY/NJ). The primary objective of the DMMP is to identify cost-effective and environmentally acceptable alternatives for the placement of dredged material derived from ongoing and proposed navigation improvements within the PANY/NJ. A significant portion of this dredged material is classified as unsuitable for open-ocean disposal. One suite of alternatives presented within the DMMP is the beneficial use of dredged material for habitat creation, enhancement, and restoration within the NY/NJ Harbor Estuary. Proposed beneficial use/habitat development projects include the use of dredged material for construction of artificial reefs, oyster reef restoration, intertidal wetland and mudflat creation, bathymetric recontouring, filling dead-end canals/basins, creation of bird/wildlife islands, and landfill/brownfields reclamation. Preliminary screening of the proposed beneficial use alternatives identified advantages, disadvantages, potential volumes, and estimated costs associated with each project type. Continued study of the proposed beneficial use alternatives has identified areas of environmental research or technology development where further investigation is warranted.

  7. Mechanical and chemical properties of composite materials made of dredged sediments in a fly-ash based geopolymer.

    PubMed

    Lirer, S; Liguori, B; Capasso, I; Flora, A; Caputo, D

    2017-04-15

    Dredging activity in harbours and channels produces huge quantities of sediments, generally considered as waste soil (WS) to be disposed: the management of such sediments is a great environmental problem for many countries worldwide. Among the recycling possibilities, the use of dredged sediments for the manufacture of geopolymer-based materials seems to be an interesting alternative to disposal, due to their low cost and easy availability. In order to analyse the possibility to use these geopolymer materials as building materials - for instance as precast construction elements in maritime projects - a multi-disciplinary research activity has been developed at the Federico II University of Napoli (Italy). Some experimental tests have been carried out on different geopolymeric specimens made by mixing sediments from Napoli 'harbour and industrial fly ashes produced by a power plant in the South of Italy. A siliceous sand was used for comparison as an inert reference material. Chemical, morphological and mechanical properties of different specimens have been studied by X-ray diffraction, Scanning Electron Microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR) and finally unconfined compression tests. The experimental results highlight that the use of dredged sediments in combination with fly ash can lead to geopolymeric matrices with interesting mechanical performances. Some differences in the microstructure of the geocomposite built with the siliceous sand or the dredged materials were found. In terms of environmental impacts, on the basis of standard leaching tests and according to Italian thresholds, the adopted dredged mixtures satisfy the prescribed limit for inert or non hazardous waste.

  8. Surgical dredging controls turbidity

    SciTech Connect

    Seagren, E.H.

    1994-06-01

    The need to remove contaminated and uncontaminated sediments located under a column of water is increasing. Small hydraulic dredges offer flexibility in the removal of sediments in industrial lagoons, wetlands, drinking water ponds, and environmentally sensitive areas.

  9. Recycling biosolids and lake-dredged materials to pasture-based animal agriculture: Alternative nutrient sources for forage productivity and sustainability

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Domestic sewage sludge or biosolids and lake-dredged materials are examples of materials that can be used to cut fertilizer costs in pasture-based animal agriculture. Sustainable biosolids and lake-dredged materials management is based upon controlling and influencing the quantity, quality and chara...

  10. Beneficial reuse of Brest Harbor (France) dredged sediment as alternative material in road building: laboratory investigations.

    PubMed

    Maherzi, Walid; Benzerzour, Mahfoud; Mamindy-Pajany, Yannick; Van Veen, Eleanor; Boutouil, Mohamed; Abriak Nor, Edine

    2017-03-17

    ABSRACT The scarcity of natural aggregates promotes waste reuse as secondary raw material in the field of civil engineering. This article focuses on the beneficial reuse of marine dredged sediments in road building. Thus, mixtures of raw sediments and dredged sand collected from Brest Harbour (Bretagne, France) were treated with road hydraulic binders. Formulation were prepared and characterized as recommended by the French Technical Guidelines for soil treatment with lime and/or hydraulic binders. Mechanical resistance results are quite similar for the both hydraulic binders suggesting a similar reactivity with the studied sediment sample. However, some discrepancies can be noted on sustainability parameters. Indeed, water resistance after immersion at 40°C is significantly better for the mixtures treated with cement containing more glass forming oxides (SiO2 + Al2O3) and fluxing (Fe2O3+CaO+MgO+K2O+Na2O). Moreover, the both hydraulic binders can lead to swelling in the road materials as observed in Scanning electron microscopy (SEM) analyses. Indeed, microscopic observations indicated volumetric swelling of treated samples which is greatly influenced on one side by ettringite quantity and on the other hand by the presence of water in pores material.

  11. Possible production of ceramic tiles from marine dredging spoils alone and mixed with other waste materials.

    PubMed

    Baruzzo, Daniela; Minichelli, Dino; Bruckner, Sergio; Fedrizzi, Lorenzo; Bachiorrini, Alessandro; Maschio, Stefano

    2006-06-30

    Dredging spoils, due to their composition could be considered a new potential source for the production of monolithic ceramics. Nevertheless, abundance of coloured oxides in these materials preclude the possibility of obtaining white products, but not that of producing ceramics with a good mechanical behaviour. As goal of the present research we have produced and studied samples using not only dredging spoils alone, but also mixtures with other waste materials such as bottom ashes from an incinerator of municipal solid waste, incinerated seawage sludge from a municipal seawage treatment plant and steelworks slag. Blending of different components was done by attrition milling. Powders were pressed into specimens which were air sintered in a muffle furnace and their shrinkage on firing was determined. Water absorption, density, strength, hardness, fracture toughness, thermal expansion coefficient of the fired bodies were measured; XRD and SEM images were also examined. The fired samples were finally tested in acidic environment in order to evaluate their elution behaviour and consequently their environmental compatibility. It is observed that, although the shrinkage on firing is too high for the production of tiles, in all the compositions studied the sintering procedure leads to fine microstructures, good mechanical properties and to a limitation of the release of many of the most hazardous metals contained in the starting powders.

  12. 33 CFR 336.1 - Discharges of dredged or fill material into waters of the U.S.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... material into waters of the U.S. (2) Section 307 of the Coastal Zone Management Act (CZMA) requires that... seek state water quality certification for dredged material disposal into waters of the U.S. The state... state water quality standards. The district engineer will use the technical manual “Management...

  13. 33 CFR 336.2 - Transportation of dredged material for the purpose of disposal into ocean waters.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... material for the purpose of disposal into ocean waters. 336.2 Section 336.2 Navigation and Navigable Waters... WATERS OF THE U.S. AND OCEAN WATERS § 336.2 Transportation of dredged material for the purpose of disposal into ocean waters. (a) Applicable law. Section 103(a) of the ODA provides that the Corps...

  14. 33 CFR 336.2 - Transportation of dredged material for the purpose of disposal into ocean waters.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... material for the purpose of disposal into ocean waters. 336.2 Section 336.2 Navigation and Navigable Waters... WATERS OF THE U.S. AND OCEAN WATERS § 336.2 Transportation of dredged material for the purpose of disposal into ocean waters. (a) Applicable law. Section 103(a) of the ODA provides that the Corps...

  15. Evaluation of dredged material proposed for ocean disposal from Red Hook/Bay Ridge project areas, New York

    SciTech Connect

    Pinza, M.R.; Barrows, E.S.; Borde, A.B.

    1996-09-01

    The objective of the Red HookIBay Ridge project was to evaluate proposed dredged material from these two areas to determine its suitability for unconfined ocean disposal at the Mud Dump Site. Sediment samples were collected from the Red Hook/Bay Ridge project areas. Tests and analyses were conducted. The evaluation of proposed dredged material from the Red Hook/Bay Ridge project areas consisted of bulk sediment chemical analyses, chemical analyses of dredging site water and elutriate, water-column and benthic acute toxicity tests. Twenty-four individual sediment core samples were collected from these two areas and analyzed for grain size, moisture content, and total organic carbon (TOC). Three composite sediment samples, representing Red Hook Channel and the two Bay Ridge Reaches to be dredged, were analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAH), and 1,4-dichlorobenzene. Dredging site water and elutriate water, which is prepared from the suspended-particulate phase (SPP) of the three Red Hook Bay Ridge sediment composites, were analyzed for metals, pesticides, and PCBS. Benthic acute toxicity tests were performed. Water-column or SPP toxicity tests were performed. Bioaccumulation tests were also conducted.

  16. Impact of the Charleston Ocean Dredged Material Disposal Site on nearby hard bottom reef habitats.

    PubMed

    Crowe, Stacie E; Gayes, Paul T; Viso, Richard F; Bergquist, Derk C; Jutte, Pamela C; Van Dolah, Robert F

    2010-05-01

    The deepening of shipping and entrance channels in Charleston Harbor (South Carolina, USA) was completed in April 2002 and placed an estimated 22 million cubic yards (mcy) of material in the offshore Charleston Ocean Dredged Material Disposal Site (ODMDS). To determine if sediments dispersed from the ODMDS were negatively affecting invertebrate and/or finfish communities at hard bottom reef areas around the disposal area, six study sites were established: three close to and downdrift of the ODMDS and three upcurrent and farther from the ODMDS. These sites were monitored biannually from 2000 to 2005 using diver surveys and annually using simultaneous underwater video tows and detailed sidescan-sonar. In general, the sediment characteristics of downdrift sites and reference sites changed similarly over time. Overall, the hard bottom reef areas and their associated communities showed little evidence of degradation resulting from the movement of sediments from the Charleston ODMDS during the study period.

  17. Management Plan Report. Unconfined Open-Water Disposal of Dredged Material. Phase 2. (North and South Puget Sound)

    DTIC Science & Technology

    1989-09-01

    Analysis 2-2 2.2 Historical Trend in Dredged Material Testing Costs 2-10 2.3 Historical Trend in Dredging and Disposal Costs 2-12 3.1 Organization, Puget...and ML) and Human Health (Bioaccumulation) Lists 5-2 5.3 Clarifications and Modifications of Bioassay Testing Procedures, Performance and Interpretive...Guidelines, and Statistical Testing 5-16 5., Clarification of Recommended Procedures and Limits of Detection for Organic Compounds 5-27 5.5

  18. Restoring marsh elevation in a rapidly subsiding salt marsh by thin-layer deposition of dredged material

    USGS Publications Warehouse

    Ford, M.A.; Cahoon, D.R.; Lynch, J.C.

    1999-01-01

    Thin-layer deposition of dredged material on coastal marsh by means of high-pressure spray dredging (Jet-Spray??2) technology has been proposed as a mechanism to minimize wetland impacts associated with traditional bucket dredging technologies and to restore soil elevations in deteriorated marshes of the Mississippi River delta. The impact of spray dredging on vegetated marsh and adjacent shallow-water habitat (formerly vegetated marsh that deteriorated to open water) was evaluated in a 0.5-ha Spartina alterniflora-dominated salt marsh in coastal Louisiana. The thickness of dredged sediment deposits was determined from artificial soil marker horizons and soil elevation change was determined from sedimentation-erosion tables (SET) established prior to spraying in both sprayed and reference marshes. The vertical accretion and elevation change measurements were made simultaneously to allow for calculation of shallow (~5 m depth) subsidence (accretion minus elevation change). Measurements made immediately following spraying in July 1996 revealed that stems of S. alterniflora were knocked down by the force of the spray and covered with 23 mm of dredged material. Stems of S. alterniflora soon recovered, and by July 1997 the percent cover of S. alterniflora had increased three-fold over pre-project conditions. Thus, the layer of dredged material was thin enough to allow for survival of the S. alterniflora plants, with no subsequent colonization by plant species typical of higher marsh zones. By February 1998, 62 mm of vertical accretion accumulated at this site, and little indication of disturbance was noted. Although not statistically significant, soil elevation change was greater than accretion on average at both the spray and reference marshes, suggesting that subsurface expansion caused by increased root biomass production and/or pore water storage influence elevation in this marsh region. In the adjacent shallow water pond, 129 mm of sediment was deposited in July

  19. Materials surface contamination analysis

    NASA Technical Reports Server (NTRS)

    Workman, Gary L.; Arendale, William F.

    1992-01-01

    The original research objective was to demonstrate the ability of optical fiber spectrometry to determine contamination levels on solid rocket motor cases in order to identify surface conditions which may result in poor bonds during production. The capability of using the spectral features to identify contaminants with other sensors which might only indicate a potential contamination level provides a real enhancement to current inspection systems such as Optical Stimulated Electron Emission (OSEE). The optical fiber probe can easily fit into the same scanning fixtures as the OSEE. The initial data obtained using the Guided Wave Model 260 spectrophotometer was primarily focused on determining spectra of potential contaminants such as HD2 grease, silicones, etc. However, once we began taking data and applying multivariate analysis techniques, using a program that can handle very large data sets, i.e., Unscrambler 2, it became apparent that the techniques also might provide a nice scientific tool for determining oxidation and chemisorption rates under controlled conditions. As the ultimate power of the technique became recognized, considering that the chemical system which was most frequently studied in this work is water + D6AC steel, we became very interested in trying the spectroscopic techniques to solve a broad range of problems. The complexity of the observed spectra for the D6AC + water system is due to overlaps between the water peaks, the resulting chemisorbed species, and products of reaction which also contain OH stretching bands. Unscrambling these spectral features, without knowledge of the specific species involved, has proven to be a formidable task.

  20. 75 FR 39523 - Notice of Intent: Designation of an Ocean Dredged Material Disposal Site (ODMDS) Off the Mouth of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-07-09

    ... AGENCY Notice of Intent: Designation of an Ocean Dredged Material Disposal Site (ODMDS) Off the Mouth of... Intent to prepare an Environmental Impact Statement (EIS) for the designation of an ODMDS off the mouth... an EIS to designate a new ODMDS offshore the mouth of the St. Johns River. The EIS will provide...

  1. 76 FR 43685 - Designation of an Ocean Dredged Material Disposal Site (ODMDS) in the Gulf of Mexico Off the...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-21

    ... AGENCY Designation of an Ocean Dredged Material Disposal Site (ODMDS) in the Gulf of Mexico Off the Mouth... of an ODMDS in the Gulf of Mexico off the mouth of the Atchafalaya River, St. Mary Parish, LA... the designation of an ODMDS in the Gulf of Mexico off the mouth of the Atchafalaya River, St....

  2. 15 CFR Appendix D to Subpart M of... - Dredged Material Disposal Sites Adjacent to the Monterey Bay National Marine Sanctuary

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 15 Commerce and Foreign Trade 3 2014-01-01 2014-01-01 false Dredged Material Disposal Sites Adjacent to the Monterey Bay National Marine Sanctuary D Appendix D to Subpart M of Part 922 Commerce and... SANCTUARY PROGRAM REGULATIONS Monterey Bay National Marine Sanctuary Pt. 922, Subpt. M, App. D Appendix D...

  3. 77 FR 20590 - Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of Yaquina Bay, OR

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-05

    ... physical movement of sediment through the water column. All dredged material proposed for disposal will be... pelagic and demersal fish species, including salmon, green sturgeon, and flatfish, as well as Dungeness... southern green sturgeon (Acipenser medirostris) but is likely to adversely affect Oregon Coast coho...

  4. 15 CFR Appendix D to Subpart M of... - Dredged Material Disposal Sites Adjacent to the Monterey Bay National Marine Sanctuary

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Adjacent to the Monterey Bay National Marine Sanctuary D Appendix D to Subpart M of Part 922 Commerce and... SANCTUARY PROGRAM REGULATIONS Monterey Bay National Marine Sanctuary Pt. 922, Subpt. M, App. D Appendix D to Subpart M of Part 922—Dredged Material Disposal Sites Adjacent to the Monterey Bay National...

  5. Harbor Beach Harbor Dredging and Dredged Material Disposal, Huron County, Michigan: The Detroit Edison Company Permit Application and Corps of Engineers’ Maintenance Operations.

    DTIC Science & Technology

    1981-12-01

    recharged by direct infiltration, this aquifer unit is subject to contamination from decaying organic material in the ponded areas on the west side of...State Highway M-25, contamination from seepage from barnyard areas, and contamination from fertilizers used in the cultivated areas. Also, the... contamination and the lack of local sponsorship caused the Corps to eliminate this site from consideration. c. Corps Site 4. Site 4 is a gravel pit

  6. Ecological evaluation of proposed dredged material from Oakland Harbor intensive study, IC-1 and OC4-B

    SciTech Connect

    Pinza, M.R.; Mayhew, H.L.; Karle, L.M.; Word, J.Q.

    1993-11-01

    Oakland Harbor is located on the eastern shoreline of central San Francisco Bay in Alameda County, between the cities of Oakland and Alameda, California. Oakland Harbor and its access channels are no longer wide or deep enough to accommodate modern deeper-draft vessels. The Water Resources Development Act of 1986 (Public Law 99-662) authorized the US Army Corps of Engineers (USACE), San Francisco District to deepen and widen the navigation channels to {minus}44 ft mean lower low water (MLLW) ({minus}42 ft MLLW plus 2 ft of overdraft) in Oakland Harbor. Several options for disposal of the material from this dredging project are under consideration by USACE. Those options include disposal within San Francisco Bay, at open-ocean sites, or at upland disposal sites. Section 103 of the Marine Protection, Research, and Sanctuaries Act of 1972 (MPRSA), Public Law 92-532, specifies that all proposed disposal of dredged material into open water be evaluated to determine the potential environmental impacts to those activities. To comply with those requirements, the potential environmental impacts of the dredged material must be evaluated by chemical characterization, toxicity testing, and bioaccumulation testing prior to dredging and disposal. Test results are described.

  7. Changes in speciation and leaching behaviors of heavy metals in dredged sediment solidified/stabilized with various materials.

    PubMed

    Bao, Jianping; Wang, Liang; Xiao, Man

    2016-05-01

    Solidification/stabilization (S/S) of sediments is frequently used to treat contaminants in dredged sediments. In this study, sediment collected from the Pearl River Delta (China) was solidified/stabilized with three different kinds of functional materials: cement, lime and bentonite. Lime primarily acted via induced increases in pH, while cements stabilization occurred through their silicate-based systems and the main function of bentonite was adsorption. The speciation and leaching behaviors of specific heavy metals before and after S/S were analyzed and the results showed that the residual speciation of Cd, Cr, Ni, Pb and Zn increased in all treatments except for Cu, as the exchangeable speciation, carbonate-bound speciation and Fe-Mn-oxide-bound speciation of Cu (all of which could be stabilized) were less than 2 % of the total amount. Pb leaching only decreased when pH increased, while the mobility of Cr and Ni only decreased in response to the silicate-based systems. The leached portion of the Fe-Mn-oxide-bound speciation followed the order Zn > Cu > Ni/Cd > Pb > Cr. The leached portion of organic-matter-bound species was less than 4 % for Cd, Cr, Ni and Pb, but 35.1 % and 20.6 % for Cu and Zn, respectively.

  8. Impacts of dredged-material disposal on the coastal soft-bottom macrofauna, Saronikos Gulf, Greece.

    PubMed

    Katsiaras, N; Simboura, N; Tsangaris, C; Hatzianestis, I; Pavlidou, A; Kapsimalis, V

    2015-03-01

    Dredged sediments derived by the low course and estuary of the metropolitan river of Athens (Kifissos River) were dumped every day for 21 months to an open-sea site in the Saronikos Gulf. The spoil-ground and surrounding area was monitored prior, during and post to dumping for 24 months, over 6-month intervals. Dumping significantly changed the granulometry of the pre-existing superficial sediments to finer-grained only in the spoil ground and increased the sediment contamination load (aliphatic, polycyclic aromatic hydrocarbons and heavy metals) throughout the study area. Microtox® SPT showed that sediment toxicity levels were high at almost all sampling stations. During dumping, burial of natural soft-bottom habitats degraded severely the communities of the spoil-ground resulting in an almost azoic state, as well as significantly declined the species number and abundance of benthic communities in locations up to 3.2 km away from the spoil-ground, due to dispersion of the spoil and smothering. Benthic indices on the surrounding sites were significantly correlated with hydrocarbon concentrations and sediment toxicity levels. Post to dumping, the macrofauna communities of the spoil-ground were still significantly degraded, but the surrounding areas showed patterns of recovery. However, the high concentrations of aliphatic, polycyclic aromatic hydrocarbons and levels of toxicity persisted in the sediments after the ceasing of dumping operations in the study area, implying the ecological hazard imposed on the area.

  9. Ecological evaluation of proposed dredged material from Winyah Bay, South Carolina

    SciTech Connect

    Ward, J.A.; Gardiner, W.W.; Pinza, M.R.; Word, J.Q.

    1993-10-01

    The navigational channels of Winyah Bay, Georgetown Harbor, South Carolina require dredging to enable normal shipping traffic to use these areas. Before dredging, environmental assessments must be conducted to determine the suitability of this dredged sediment for unconfined, open-water disposal. The Charleston, South Carolina District Office of the US Army Corps of Engineers (USACE) requested that the Battelle/Marine Science Laboratory (MSL) collect sediment samples and conduct the required physical/chemical, toxicological, and bioaccumulation evaluations as required in the 1991 Implementation Manual. This report is intended to provide information required to address potential ecological effects of the Entrance Channel and Inner Harbor sediments proposed disposal in the ocean.

  10. GREAT II. Great River Environmental Action Team II. Upper Mississippi River. Guttenberg, Iowa to Saverton, Missouri. Dredged Material Uses Work Group. Appendix.

    DTIC Science & Technology

    1980-12-01

    Ohio (GREAT III). The study programs and recommendations of the three GREAT Teams will be brought together in to a river management strategy for the...material and what effect the availability of dredged material will have on their market. 5 3. Support Staff: The duties of the support staff were to process...each site, material transport limitations, and the inability to accurately predict when and where dredging will occur, very few of the requests have

  11. Satellite material contaminant optical properties

    NASA Technical Reports Server (NTRS)

    Wood, B. E.; Bertrand, W. T.; Seiber, B. L.; Kiech, E. L.; Falco, P. M.; Holt, J. D.

    1990-01-01

    The Air Force Wright Research and Development Center and the Arnold Engineering Development Center are continuing a program for measuring optical effects of satellite material outgassing products on cryo-optic surfaces. Presented here are infrared (4000 to 700 cm(-1)) transmittance data for contaminant films condensed on a 77 K geranium window. From the transmittance data, the contaminant film refractive and absorptive indices (n, k) were derived using an analytical thin-film interference model with a nonlinear least-squares algorithm. To date 19 materials have been studied with the optical contents determined for 13 of those. The materials include adhesives, paints, composites, films, and lubricants. This program is continuing and properties for other materials will be available in the future.

  12. Site Management and Monitoring Plan (SMMP) for the Los Angeles/Long Beach, Newport and San Diego Ocean Dredged Material Disposal Sites, CA

    EPA Pesticide Factsheets

    This SMMP is intended to provide management and monitoring strategies for disposal in the Los Angeles/Long Beach (LA-2), Newport (LA-3) and San Diego (LA-5) Ocean Dredged Material Disposal Sites in California.

  13. Reports of Public Scoping Meetings for the Supplemental Environmental Impact Statement for the Designation of Dredged Material Disposal Sites in Eastern Long Island Sound

    EPA Pesticide Factsheets

    These reports provide summaries of the scoping meetings as part of the Supplemental Environmental Impact Statement (SEIS) process for the designation of dredged material disposal sites in Eastern Long Island Sound.

  14. Design of a GIS-based rating protocol to assess the potential for landfill closure using dredge material in post Hurricane Sandy New Jersey.

    PubMed

    Miskewitz, Robert J; Barone, Daniel; Guterl, Sar J; Uchrin, Christopher G

    2017-02-22

    New Jersey is rapidly running out of capacity for storage of dredged material. A potential solution to this lack of storage space is to remove and reuse the dredged material for some beneficial use. Results from a Rutgers University project performed for the New Jersey Department of Transportation, Office of Maritime Resources, designed to assess the potential for closure of New Jersey landfills using dredge material from existing Confined Disposal Facilities (CDFs) are presented and discussed. The project included an update of the existing NJDEP landfill database, the development of a rating system to identify landfills with the highest potential to utilize dredged material for their closure, and the identification and preliminary investigation of the top candidate landfills based on this rating system.

  15. Southeast Regional Implementation Manual for Requirements and Procedures for Evaluation of the Ocean Disposal of Dredged Material in Southeastern U.S. Atlantic and Gulf Coast Waters

    EPA Pesticide Factsheets

    This Regional Implementation Manual was prepared by EPA Region 4 to provide guidance for applicants proposing open-water disposal of dredged material in southeastern U.S. coastal waters of the Atlantic Ocean and the Gulf of Mexico.

  16. Site Management and Monitoring Plan (SMMP) for the Mouth of Columbia River- Deep and Shallow Water Ocean Dredged Material Disposal Sites, OR/WA

    EPA Pesticide Factsheets

    This SMMP is intended to provide management and monitoring strategies for disposal in the Mouth of Columbia River- Deep and Shallow Ocean Dredged Material Disposal Sites on the border of Oregon and Washington.

  17. Long-term benthic infaunal monitoring at a deep-ocean dredged material disposal site off Northern California

    NASA Astrophysics Data System (ADS)

    Blake, James A.; Maciolek, Nancy J.; Ota, Allan Y.; Williams, Isabelle P.

    2009-09-01

    One hundred and thirty-five benthic infaunal samples were collected from the San Francisco Deep-Ocean Disposal Site (SF-DODS) over a 10-year period from January 1996 to September 2004. Each sample was 0.1 m 2, cut to a depth of 10 cm, and sieved through a 300-μm mesh. A total of 810 species of benthic invertebrates were identified; the majority of taxa (65.4%) new to science. The fauna represents a rich lower slope infaunal assemblage that rivals similarly studied locations in the western North Atlantic. No regional impact or degradation of benthic infauna due to dredged material disposal was detected. All reference stations and stations on the site boundary maintained high species richness and diversity during the monitoring period. Exceptions included an occasional sample with anomalously high numbers of one or two species that reduced the diversity and/or equitability. Within SF-DODS species richness and diversity were often reduced. Stations within the disposal site were recolonized by the same taxa that normally occurred in adjacent reference areas. Initial colonizers of fresh dredged material included spionid and paraonid polychaetes that were typical dominants at the site. At least one polychaete species, Ophelina sp. 1, sometimes colonized dredged materials containing coarse sand. One sample at Station 13, located in the middle of SF-DODS (September 2002), contained 57 species of benthic invertebrates, suggesting that colonization of fresh dredged material is rapid. It seems unlikely that larval dispersal and settlement account for this rapid recolonization; therefore it is postulated that adult organisms from adjacent areas move to the disturbed sites via boundary layer currents. The steep continental slope adjacent to SF-DODS is subject to turbidity flows and the resident fauna are likely pre-adapted to rapidly colonize disturbed sediments. Larval dispersal, especially by spionid polychaetes such as Prionospio delta, may also be important in colonizing

  18. Comparison of the Direct Scoring Method and Multi-Criteria Decision Analysis for Dredged Material Management Decision Making

    DTIC Science & Technology

    2009-09-01

    regulations is required. There are three main concerns with this approach: lack of weighting, categorical scores, and subjectivity. An initial concern...provided as they may fit into the hypothetical upland disposal site selection for dredged material example below. Three main criteria were identified...cost, environmental, and social (Figure 2). Each main crite- rion is divided into sub-criteria. The cost criterion is divided into construction

  19. Sampling, Testing, and Test Interpretation of Dredged Material Proposed for Unconfined, Open-Water Disposal in Central Puget Sound. Volume 5. Evaluation Procedures Technical Appendix. Phase 1

    DTIC Science & Technology

    1988-06-01

    in developing guidelines and criteria for regulating dredged and fill material discharge. The focal point for the developmental research fon these...Identification and Assessment and Research Program Development ." Technical Report H-72-8 (U. S . Army Engineer Waterways Experiment Station, CE, Vicksburg... Development of Dredged Material Disposal Criteria," Contract Report D-74-1 (U. S . Army Engineer Waterways Experiment Station, CE, Vicksburg, Mississippi

  20. GREAT I Study of the Upper Mississippi River. Technical Appendixes. Volume 2. Floodplain Management, Dredged Material Uses, Dredging Requirements.

    DTIC Science & Technology

    1980-09-01

    EQUIPMENT NEEDS E. COMMERCIAL TRANSPORTATION AceSson For-" j VOLUME 4 F . WATER QUALITY NSDTIC 6. G. SEDIMENT AND EROSION Un8nnoumced Jt ict VOLUME 5 H...11988 APPENDIX D: BASE MAP FEASIBILITY REPORT APPENDIX 9: FLOODPLAIN-FLOODWAY MAPS APPENDIX F : MATERIAL PLACEMEN EVALUATION FORMS APPENDIX G: HM MODEL...PILOT STUDY CONTRACTOR’ S REPORT Note: Appendixes A, B, C, D, F , and G are on file with PlonnIfn Bear St. Paul District, Corps of Engineers, 1135 U.S

  1. Ecological evaluation of proposed dredged material from Richmond Harbor Deepening Project and the intensive study of the Turning Basin

    SciTech Connect

    Pinza, M.R.; Mayhew, H.L.; Karle, L.M.; Kohn, N.P.; White, P.J.; Word, J.Q.; Michaels, L.L.

    1995-06-01

    Richmond Harbor is on the eastern shoreline of central San Francisco Bay and its access channels and several of the shipping berths are no longer wide or deep enough to accommodate modem deeper-draft vessels. The Water Resources Development Act of 1986 (PL99-662) authorized the US Army Corps of Engineers (USACE), San Francisco District to deepen and widen the navigation channels in Richmond Harbor. Several options for disposal of the material from this dredging project are under consideration by USACE: disposal within San Francisco Bay, at open-ocean disposal sites, or at uplands disposal sites. Purpose of this study was to conduct comprehensive evaluations, including chemical, biological, and bioaccumulation testing of sediments in selected areas of Richmond Harbor. This information was required by the Environmental Protection Agency (EPA) and USACE. Battelle/Marine Sciences Laboratory collected 20 core samples, both 4-in. and 12-in., to a project depth of -40 ft mean lower low water (MLLW) (-38 ft MLLW plus 2 ft of overdepth) using a vibratory-hammer core. These 20 field samples were combined to form five test composites plus an older bay mud (OBM) composite that were analyzed for physical/chemical parameters, biological toxicity, and tissue chemistry. Solid-phase tests were conducted with the amphipod, Rhepoxynius abronius; the clam, Macoma nasuta; and the polychaete worm, Nephtys caecoides. Suspended-particulate-phase (SPP) tests were conducted with the sanddab, Citharichthys stigmaeus; the mysid, Holmesimysis costata; and the bivalve, Mytilus galloprovincialis. Bioaccumulation of contaminants was measured in tissues of Macoma nasuta and Nereis virens. Sediments from one ocean reference sediment, and two in-bay reference sediments, were tested concurrently. Results from analysis of the five test treatments were statistically compared with the reference sediment R-OS in the first five sections of this report.

  2. Physiological and proteomic responses of different willow clones (Salix fragilis x alba) exposed to dredged sediment contaminated by heavy metals.

    PubMed

    Evlard, Aricia; Sergeant, Kjell; Ferrandis, Salvador; Printz, Bruno; Renaut, Jenny; Guignard, Cedric; Paul, Roger; Hausman, Jean-Francois; Campanella, Bruno

    2014-01-01

    High biomass producing species are considered as tools for remediation of contaminated soils. Willows (Salix spp.) are prominent study subjects in this regard. In this study, different willow clones (Salix fragilis x alba) were planted on heavy-metal polluted dredging sludge. A first objective was assessment of the biomass production for these clones. Using a Gupta statistic, four clones were identified as high biomass producers (HBP). For comparison, a group of four clones with lowest biomass production were selected (LBP). A second objective was to compare metal uptake as well as the physiological and proteomic responses of these two groups. All these complementary data's allow us to have a better picture of the health of the clones that would be used in phytoremediation programs. Cd, Zn, and Ni total uptake was higher in the HBPs but Pb total uptake was higher in LBPs. Our proteomic and physiological results showed that the LBPs were able to maintain cellular activity as much as the HBPs although the oxidative stress response was more pronounced in the LBPs. This could be due to the high Pb content found in this group although a combined effect of the other metals cannot be excluded.

  3. Environmental effects of dredging: Methods for the assessment of the genotoxic effects of environmental contaminants. Glossary and references. Technical notes

    SciTech Connect

    Honeycutt, M.E.; Jarvis, A.S.; McFarland, V.A.

    1995-07-01

    This technical note is the third in a series of three that outline and describe the principal methods that have been developed to test the potential of environmental contaminants to cause mutagenic, carcinogenic, and teratogenic effects. The first in this series (EEDP-04-24) describes methods used to discern genotoxic effects at the sub cellular level, while the second (EEDP-04-25) describes methods used to discern genotoxic effects at the cellular and organ/organism level. Recent literature citations for each topic referenced in this series of technical notes are provided in this technical note, in addition to a glossary of terms. The information in these technical notes is intended to provide Corps of Engineers personnel with a working knowledge of the terminology and conceptual basis of genotoxicity testing. To develop an improved understanding of the concepts of genotoxicity, readers are encouraged to review A Primer in Genotoxicity (Jarvis, Reilly, and Lutz 1993), presented in Volume D-93-3 of the Environmental Effects of Dredging information exchange bulletin.

  4. Zn speciation in a soil contaminated by the deposition of a dredged sediment by synchrotron X-ray techniques

    SciTech Connect

    Isaure, Marie-Pierre; Manceau, Alain; Laboudigue, Agnes; Tamura, Nobumichi; Marcus, Matthew A.

    2003-09-01

    The nature and proportion of Zn species present in an agricultural soil overlaid by a dredged contaminated sediment have been untangled by the novel combination of three non-invasive synchrotron-based x-ray techniques: x-ray microfluorescence ({mu}SXRF), microdiffraction ({mu}XRD), and absorption spectroscopy (EXAFS). One primary (franklinite) and two secondary (phyllomanganate and phyllosilicate) Zn-containing minerals were identified in the initial soil, and another primary (ZnS) and a new secondary (Fe-(oxyhydr)oxide) Zn species in the covered soil. The quantitative analysis of EXAFS spectra recorded on bulk samples indicated that ZnS and Zn-Fe (oxyhydr)oxides amounted to 71+-10 percent and 27+-10 percent, respectively, and the other Zn species to less than 10 percent. The two new Zn species found in the covered soil result from the gravitational migration of ZnS particles initially present in the sediment, and from their further oxidative dissolution and fixation of leached Zn on F e (oxyhydr) oxides.

  5. Fishery resource utilization of a restored estuarine borrow pit: a beneficial use of dredged material case study.

    PubMed

    Reine, Kevin; Clarke, Douglas; Ray, Gary; Dickerson, Charles

    2013-08-15

    Numerous pits in coastal waters are subject to degraded water quality and benthic habitat conditions, resulting in degraded fish habitat. A pit in Barnegat Bay, New Jersey (USA) was partially filled with dredged sediment to increase flushing, alleviate hypoxia, and enhance benthic assemblages. Restoration objectives were assessed in terms of benthic community parameters and fishery resource occupation. Restoration resulted in increased benthic diversity (bottom samples) and the absence of water column stratification. Fisheries resources occupied the entire water column, unlike pre-restoration conditions where finfish tended to avoid the lower water column. The partial restoration option effectively reproduced an existing borrow pit configuration (Hole #5, control), by decreasing total depth from -11 m to -5.5 m, thereby creating a habitat less susceptible to hypoxic/anoxic conditions, while retaining sufficient vertical relief to maintain associations with juvenile weakfish and other forage fishes. Partially filling pits using dredged material represents a viable restoration alternative.

  6. Application of neutral red retention assay to caged clams (Ruditapes decussatus) and crabs (Carcinus maenas) in the assessment of dredged material.

    PubMed

    Buratti, Sara; Ramos-Gómez, Julia; Fabbri, Elena; DelValls, T Angel; Martín-Díaz, M Laura

    2012-01-01

    Dredged material management is a key issue for the protection of aquatic environments. The in situ approach using caged bioindicator species has been chosen lately as a new methodology for the assessment of dredged material. In a tier testing approach, neutral red retention (NRR) assay has been applied as a screening tool to detect adverse changes in health status associated with contamination. Nevertheless, to authors' knowledge, little is known about the application and validation of this technique in sediment bioindicator species and under field conditions. Caged Ruditapes decussatus and Carcinus maenas were exposed during 28 days to potentially contaminated sediments at three sites in Algeciras Bay (SW Spain) and one site in Cádiz Bay (SW Spain). Lysosomal membrane stability was measured over time in haemolymph samples of exposed clams and crabs using the NRR assay. Sediment characterization of the study sites was performed in parallel. NRR time did not vary significantly (p > 0.05) over time in organisms from Cádiz Bay. Conversely, significant differences (p < 0.05) in NRR time were found in clams and crabs exposed to sediments from Algeciras Bay, which exhibited a 30-70% decrease in haemocyte lysosome membrane stability compared to day 0. Statistical analysis showed a strong correlation between the drop of haemocyte lysosome membrane stability, in both crabs and clams, and the presence of metals (p < 0.05) and PAHs (p < 0.01) in the studied sediments. The results obtained confirmed the use of NRR assay as a suitable and sensitive method to be used in the assessment of sediment quality using as bioindicator species the clam R. philippinarum and the crab C. maenas.

  7. Effects of burial by the disposal of dredged materials from the Columbia River on Pacific razor clams (Siliqua patula)

    SciTech Connect

    Vavrinec, John; Kohn, Nancy P.; Hall, Kathleen D.; Romano, Brett A.

    2007-05-07

    Annual maintenance of the Columbia River navigation channel requires the U.S. Army Corps of Engineers (Corps) to dredge sediment from the river and dispose of the sediment in coastal areas at the mouth of the Columbia River. Some of these disposal areas can be as shallow as 12 m deep in waters off the coastal beaches, and dredged material disposal activities have therefore raised concerns of impacts to local razor clam (Siliqua patula) populations that are prevalent in the area. The Corps’ Portland District requested that the Marine Sciences Laboratory of the U.S. Department of Energy’s Pacific Northwest National Laboratory conduct laboratory experiments to evaluate the potential impacts of burial by dredged material to razor clams during disposal. Prior modeling of disposal events indicates three stresses that could have an impact on benthic invertebrates: convective descent and bottom encounter (compression forces due to bottom impact), dynamic collapse and spreading (surge as material washes over the bottom), and mounding (burial by material). Because the razor clam is infaunal, the effects of the first two components should be minimal, because the clams should be protected by substrate that is not eroded in the event and by the clams’ rapid digging capabilities. The mound resulting from the disposal, however, would bury any clams remaining in the footprint under as much as 12 cm of new sediment according to modeling, and the clams’ reaction to such an event and to burial is not known. Although the literature suggests that razor clams may be negatively affected by siltation and therefore perhaps by dredging and disposal activity, as well, impacts of this type have not been demonstrated. The primary purpose of this study was to evaluate the potential impacts of dredge material disposal on adult subtidal razor clam populations at the mouth of the Columbia River. Using the parameters defined in a previous model, a laboratory study was created in which a

  8. A screening procedure for selecting the most suitable dredged material placement site at the sea. The case of the South Euboean Gulf, Greece.

    PubMed

    Kapsimalis, V; Panagiotopoulos, I P; Hatzianestis, I; Kanellopoulos, T D; Tsangaris, C; Kaberi, E; Kontoyiannis, H; Rousakis, G; Kyriakidou, C; Hatiris, G A

    2013-12-01

    The selection of the best site for the placement of dredged sedimentary material (∼7,000 m(3)) from the Aliveri coastal area in the adjacent South Euboean Gulf (Greece) was accomplished through a screening procedure. The initial stage comprised the determination of physical, chemical, and biological characteristics of the dredged sediment before the commencement of any dredging operation. Grain size measurements, geochemical analyses together with the use of pollution/toxicity indices and empirical sediment quality guidelines, and the conduct of an acute toxicity test showed that the dredged material consisted of "unpolluted to slightly polluted" silty sands and sandy silts. However, the local authorities planned to place this sediment in the neighboring open sea area, i.e., the South Euboean Gulf, due to the absence of any beneficial use or alternative dumping option (i.e., dumping on public lands). Therefore, the next stage of the screening procedure, based on criteria such as the national legislation, seabed and seawater column characteristics, influence of the water mass circulation pattern on the post-placement migration of dredged sediment, impact on living resources and human activities (i.e., aquaculture and fishing), effect on significant marine sites (i.e., sites of scientific, ecological, and historical importance, navigation routes, military zones), and seafloor engineering uses, led to the evaluation of the suitability of the South Euboean Gulf as a potential dumping area. Then, the identification of the appropriate dredged material placement sites in the South Euboean Gulf was based on a cluster analysis, which tested the physicochemical resemblance of the dredged material and the surface sediments of 19 potential placement locations in the gulf. After the statistical process, only four sites situated near the north shoreline of the South Euboean Gulf were qualified as the best dredged material placement locations.

  9. Impact of dredged urban river sediment on a Saronikos Gulf dumping site (Eastern Mediterranean): sediment toxicity, contaminant levels, and biomarkers in caged mussels.

    PubMed

    Tsangaris, Catherine; Strogyloudi, Evangelia; Hatzianestis, Ioannis; Catsiki, Vassiliki-Angelique; Panagiotopoulos, Ioannis; Kapsimalis, Vasilios

    2014-05-01

    Impacts of chemical contaminants associated with dumping of dredged urban river sediments at a coastal disposal area in Saronikos Gulf (Eastern Mediterranean) were investigated through a combined approach of sediment toxicity testing and active biomonitoring with caged mussels. Chemical analyses of aliphatic hydrocarbons (AHs), polycyclic aromatic hydrocarbons (PAHs), Cu, and Zn in combination with the solid phase Microtox® test were performed on sediments. Concentrations of PAHs, AHs, Cu, and Zn as well as multiple biomarkers of contaminant exposure and/or effects were measured in caged mussels. Sediments in the disposal and neighboring area showed elevated PAHs and AHs concentrations and were characterized as toxic by the solid-phase Microtox® test during and after dumping operations. Biomarker results in the caged mussels indicated sublethal effects mainly during dumping operations, concomitantly with high concentrations of PAHs and AHs in the caged mussel tissues. Cu and Zn concentrations in sediments and caged mussels were generally not elevated except for sediments at the site in the disposal area that received the major amount of dredges. High PAHs and AHs levels as well as sublethal effects in the caged mussels were not persistent after termination of operations. The combined bioassay-biomarker approach proved useful for detecting toxicological impacts of dredged river sediment disposal in sediments and the water column. Nevertheless, further research is needed to evaluate whether sediment toxicity will have long-term effects on benthic communities of the disposal area.

  10. Commencement Bay Nearshore/Tideflats Superfund Site, Tacoma, Washington Remedial Investigations. Evaluation of Alternative Dredging Methods and Equipment, Disposal Methods and Sites, and Site Control and Treatment Practices for Contaminated Sediments.

    DTIC Science & Technology

    1985-06-01

    sediment resuspension at the dredge site, special-purpose hydraulic dredges produce less resuspension than conventional hydraulic dredges, and with...the exception of hopper dredge overflow, conventional hydraulic dredges produce less resuspension than mechanical dredges. In terms of slurry water that...dredges produce less water than conventional hydraulic dredges. Hydraulic dredges produce less solids resuspension at the dredging site and have a

  11. Sustainable Confined Disposal Facilities for Long-term Management of Dredged Material

    DTIC Science & Technology

    2010-07-01

    a hydroseparator or a hydrocyclone , both of which exploit differences in size and density of the particles. In some operations, combinations of...capacity, low-tech separation method that could be economically employed during disposal of hydraulically dredged sediments. Hydrocyclones are simple

  12. Effect of sulphur concentration on bioleaching of heavy metals from contaminated dredged sediments.

    PubMed

    Fang, D; Zhao, L; Yang, Z Q; Shan, H X; Gao, Y; Yang, Q

    2009-11-01

    The sulphur-based bioleaching process using sulphur-oxidizing bacteria (SOB) has been demonstrated to be a feasible technology for removing heavy metals from contaminated sediments, but the excess sulphur application will lead to the re-acidification of bioleached sediments. The objective of the present study was to examine the effect of sulphur concentration on the bioleaching of heavy metals from contaminated sediments, with the ultimate purpose of minimizing the sulphur addition. The results showed that the inoculation of 7% of indigenous SOB, containing 3.6 x 10(8) colony forming units (CFU) mL(-1), and addition of elemental sulphur as a substrate (0.5 to 7.0 g L(-1)) resulted in a sharp decrease in sediment pH from an initial pH 8.0 to pH 1.4-2.4 and an increase in ORP (oxidation-reduction potential) from -10 mV to 500 mV within 10 days of bioleaching. Although the increase in sulphur concentration enhanced the rates of pH reduction and ORP elevation, the bioleaching process with the addition of 3.0 g L(-1) of sulphur was already sufficient to reach conditions of acidity (pH < 2.0) and ORP (500 mV) necessary for a satisfactory removal of metals, and, at day 10, 71.8% of Cu, 58.2% of Zn, and 25.3% of Cr were removed from the sediments. During the bioleaching process, Zn removal increased with a reduction in pH, whereas the removal of Cu and Cr increased not only with a reduction in pH but also with an increase in ORP. Results of sequential selective extraction indicated that the final levels of metal removals were dependent on their speciation distribution in the original sediments, and after bioleaching those unremoved metals in the bioleached sediments mainly existed in the residual fraction.

  13. Probe for contamination detection in recyclable materials

    DOEpatents

    Taleyarkhan, Rusi

    2003-08-05

    A neutron detection system for detection of contaminants contained within a bulk material during recycling includes at least one neutron generator for neutron bombardment of the bulk material, and at least one gamma ray detector for detection of gamma rays emitted by contaminants within the bulk material. A structure for analyzing gamma ray data is communicably connected to the gamma ray detector, the structure for analyzing gamma ray data adapted. The identity and concentration of contaminants in a bulk material can also be determined. By scanning the neutron beam, discrete locations within the bulk material having contaminants can be identified. A method for recycling bulk material having unknown levels of contaminants includes the steps of providing at least one neutron generator, at least one gamma ray detector, and structure for analyzing gamma ray data, irradiating the bulk material with neutrons, and then determining the presence of at least one contaminant in the bulk material from gamma rays emitted from the bulk material.

  14. The stability of butyltin compounds in a dredged heavily-contaminated sediment.

    PubMed

    Saeki, Kazutoshi; Nabeshima, Akiko; Kunito, Takashi; Oshima, Yuji

    2007-06-01

    A treatment process for marine sediment heavily contaminated with tributyltin (TBT) was designed that included dehydrating, sunlight drying and dumping processes. The time course in butyltin (BTs) compounds, TBT, dibutyltin (DBT) and monobutyltin concentrations were investigated in the sediment treated under various conditions (light (UV, sunlight and light exclusion), moisture (air-drying and water saturation) and wetting and drying cycles). Significant changes in all the BT compound concentrations with time were not found regardless of the sediment conditions for light and moisture. The results indicated the high stabilities of TBT and DBT in the sediments versus light and moisture condition changes, probably taking place in the treatment process. It is also estimated that the BTs in the sediment are resistant to photo-degradation and biochemical degradation and their half lives are relatively long. In contrast, the decreases in the TBT and DBT were observed during the wetting and drying cycle treatment for the water saturated sediment both during exposure to sunlight and under a dark condition. This result suggested the hypothesis that the TBT degradation could be accelerated by the high microbial activity induced by the moisture changing treatments.

  15. Physical oceanographic processes at candidate dredged-material disposal sites B1B and 1M offshore San Francisco

    SciTech Connect

    Sherwood, C.R.; Denbo, D.W.; Downing, J.P. ); Coats, D.A. )

    1990-10-01

    The US Army Corps of Engineers (USACE), San Francisco District, has identified two candidate sites for ocean disposal of material from several dredging projects in San Francisco Bay. The disposal site is to be designated under Section 103 of the Ocean Dumping Act. One of the specific criteria in the Ocean Dumping Act is that the physical environments of the candidate sites be considered. Toward this goal, the USACE requested that the Pacific Northwest Laboratory conduct a study of physical oceanographic and sediment transport processes at the candidate sites, B1B and 1M. The results of that study are presented in this report. 40 refs., 27 figs., 10 tabs.

  16. Dredged sediments as a resource for brick production: Possibilities and barriers from a consumers’ perspective

    SciTech Connect

    Cappuyns, Valérie Deweirt, Valentine; Rousseau, Sandra

    2015-04-15

    Highlights: • Consumers are suspicious towards bricks produced from dredged sediments. • Technical quality, safety and environmental impacts are considered key characteristics. • Public has insufficient knowledge on bricks produced from dredged sediments. • Sensitization and provision of information to customers are of primary importance. - Abstract: A possible solution for the oversupply of dredged sediments is their use as a raw material in brick production. Despite the fact that several examples (e.g., Agostini et al., 2007; Hamer and Karius, 2002; Xu et al., 2014) show that this application is feasible, some economic, technical and social limitations interfere with the development of a market of dredged materials in brick production in Flanders. While we describe the main characteristics of the supply side, we focus on the limitations and barriers from the demand side in the present study. Based on a consumers survey we analyze consumers’ risk perceptions and attitudes towards bricks produced from dredged sediments. Consumers in Flanders are rather suspicious with respect to bricks produced from dredged sediments and their risk perception is mainly determined by the possibility of a bad bargain (brick of inferior quality) and the connotation with chemical contamination. The willingness to pay for bricks made from dredged sediments is mainly influenced by the age of the respondents, as well environmental awareness, and the respondents’ belief in their ability to influence environmental problems. Sensitization and information of customers seems to be of primary importance to make dredged-sediment-derived bricks a successful product.

  17. Ecological consequences of dredged material disposal in the marine environment: a holistic assessment of activities around the England and Wales coastline.

    PubMed

    Bolam, S G; Rees, H L; Somerfield, P; Smith, R; Clarke, K R; Warwick, R M; Atkins, M; Garnacho, E

    2006-04-01

    This study provides a holistic perspective on the ecological effects of dredged material disposal, both intertidally and subtidally. A number of numerical techniques (univariate, distributional, multivariate and meta-analysis) were used to assess impacts at 18 different disposal sites. The analyses revealed that ecological effects associated with dredged material disposal were dependent on the numerical techniques used, and that impacts were disposal-site specific. Disposal-site communities were generally faunistically impoverished to varying degrees, and impacts following intertidal placement were comparable to those of subtidal placement. We conclude that any assessment of the consequences of dredged material disposal to the coastal environment must take account of site-specific variation in prevailing hydrographic regimes and in ecological status, along with information on the disposal activity itself (mode, timing, quantity, frequency and type of material). As would be expected, variability in the latter presents a significant challenge in attempts to generalise about environmental and ecological impacts.

  18. Impacts of maintenance channel dredging in a northern Adriatic coastal lagoon. I: Effects on sediment properties, contamination and toxicity

    NASA Astrophysics Data System (ADS)

    Guerra, Roberta; Pasteris, Andrea; Ponti, Massimo

    2009-10-01

    Conservation and management of coastal lagoons envisage direct human intervention. To prevent siltation and to preserve the hydrodynamics features of the lagoon system, the inner channels undergo regular maintenance dredging. Sediment properties (RDP, organic matter, grain size), trace metals (Cd, Cu, Cr, Hg, Ni, and Pb), and toxicity vs. the amphipod Corophium insidiosum and the luminescent bacterium Vibrio fischeri, were analysed before and after dredging operations in a coastal lagoon (Pialassa Baiona, Italy). To detect the actual impacts, disturbed sites were contrasted with multiple controls in two distinct times, i.e. before and after disturbance, according to a sampling design based on Beyond BACI principles. The integrated methodology here adopted suggests that dredging operations carried out are not likely to pose dramatic effects on environmental quality of the lagoon.

  19. Dredged Material Evaluations: Review of Zooplankton Toxicity Test Methods for Marine Water Quality Evaluations

    DTIC Science & Technology

    2016-09-01

    Toxicity Test Methods for Marine Water Quality Evaluations by Alan J Kennedy, Guilherme Lotufo, Jennifer G. Laird, and J. Daniel Farrar PURPOSE: The...first objective of this Dredging Operations and Engineering (DOER) technical note is to summarize currently available estuarine and marine water ...suitable for unrestricted open water placement, beneficial use, or if management strategies are necessary. Open water placement of DM into inland

  20. Modeling the transport of PCDD/F compounds in a contaminated river and the possible influence of restoration dredging on calculated fluxes.

    PubMed

    Malve, Olli; Salo, Simo; Verta, Matti; Forsius, John

    2003-08-01

    River Kymijoki, the fourth largest river in Finland, has been heavily polluted by pulp mill effluents as well as by chemical industry. Loading has been reduced considerably, although remains of past emissions still exist in river sediments. The sediments are highly contaminated with polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated diphenyl ethers (PCDEs), and mercury originating from production of the chlorophenolic wood preservative (Ky-5) and other sources. The objective of this study was to simulate the transport of these PCDD/F compounds with a one-dimensional flow and transport model and to assess the impact of restoration dredging. Using the estimated trend in PCDD/F loading, downstream concentrations were calculated until 2020. If contaminated sediments are removed by dredging, the temporary increase of PCDD/F concentrations in downstream water and surface sediments will be within acceptable limits. Long-term predictions indicated only a minor decrease in surface sediment concentrations but a major decrease if the most contaminated sediments close to the emission source were removed. A more detailed assessment of the effects is suggested.

  1. Field Evaluations of the Quality of Effluent from Confined Dredged Material Disposal Areas. Long-Term Effects of Dredging Operations Program.

    DTIC Science & Technology

    1988-02-01

    acknowledged. This work was performed under the general supervison of Dr. Raymond L. Montgomery, Chief, EED, and Dr. John Harrison, Chief, EL. Managers of the...material discharge under Section 404 of the Clean Water Act. The Corps of Engineers has recently developed modified elutriate testing procedures for...ABSTRACT (Continued). showed that all five disposal areas were very efficient in retaining suspended solids. The relative retention of contaminants

  2. Analyses of native water, bottom material, elutriate samples, and dredged material from selected southern Louisiana waterways and selected areas in the Gulf of Mexico, 1979-81

    USGS Publications Warehouse

    Lurry, Dee L.

    1983-01-01

    The U.S. Geological Survey was requested by the U.S. Army Corps of Engineers, New Orleans District, to provide water-quality data to evaluate environmental effects of dredging activities in selected reaches of the Calcasieu River in southwestern Louisiana. Samples were collected from the upper and lower Calcasieu River between January 1980 and March 1981. Thirty-three samples (22 native-water and 11 effluent) were collected from eleven dredging sites. In addition, a series of elutriate studies were conducted between July 1979 and July 1981 to determine water quality as a basis for assessing possible environmental effects of proposed dredging activities in the following areas: Grand Bayou and Martins Canal near Happy Jack, unnamed bayou near Port Sulphur, Grand Bayou and Pipeline Canal near Port Sulphur and Bayou des Plantins near Empire; Mississippi River Gulf Outlet and Inner Harbor Navigation Canal; Southwest Pass; Barataria Bay; Atchafalaya Bay at Eugene Island; Calcasieu Ship Channel. Samples of native water and samples of bottom material were collected from 22 different sites and elutriate (mixtures of native water and bottom material) samples were prepared and analyzed. Four proposed ocean-disposal sites were sampled for bottom material only. Samples were analyzed for selected chemical and biological constituents and physical properties. (USGS)

  3. Preliminary Assessment of Potential Impacts to Dungeness Crabs from Disposal of Dredged Materials from the Columbia River

    SciTech Connect

    Pearson, Walter H.; Miller, Martin C.; Williams, Greg D.; Kohn, Nancy P.; Skalski, John R.

    2006-02-01

    Dredging of the Columbia River navigation channel has raised concerns about dredging-related impacts on Dungeness crabs (Cancer magister). The overall objectives of this effort are to synthesize what is known about disposal effects on Dungeness crabs (Phase 1) and to offer approaches to quantify the effects, including approaches to gain a population-level perspective on any effects found in subsequent studies (Phase 2). This report documents Phase 1, which included (1) development of a conceptual model to integrate knowledge about crab biology and the physical processes occurring during disposal, (2) application of physics-based numerical modeling of the disposal event to understand the physical forces and processes to which a crab might be exposed during disposal, (3) conduct of a vulnerability analysis to identify the potential mechanisms by which crabs may be injured, and (4) recommendations of topics and approaches for future studies to assess the potential population-level effects of disposal on Dungeness crabs. The conceptual model first recognizes that disposal of dredged materials is a physically dynamic process with three aspects: (1) convective descent and bottom encounter, (2) dynamic collapse and spreading, and (3) mounding. Numerical modeling was used to assess the magnitude of the potentially relevant forces and extent of mounding in single disposal events. The modeling outcomes show that predicted impact pressure, shear stress, and mound depth are greatly reduced by discharge in deep water, and somewhat reduced at longer discharge duration. The analysis of numerical modeling results and vulnerabilities indicate that the vulnerability of crabs to compression forces under any of the disposal scenarios is low. For the deep-water disposal scenarios, the maximum forces and mounding do not appear to be sufficiently high enough to warrant concern for surge currents or burial at the depths involved (over 230 ft). For the shallow-water (45 to 65 ft), short

  4. Utilizing gamma isotope tracers to determine sediment source at reef sites near the Charleston Ocean Dredged Material Disposal Site.

    PubMed

    Noakes, Scott E; Jutte, Pamela C

    2006-06-01

    The Charleston, South Carolina Ocean Dredged Material Disposal Site (ODMDS) has been heavily utilized as a disposal site for dredged material resulting from maintenance and channel deepening in the Charleston Harbor. Continuous monitoring by the South Carolina Department of Natural Resources at the ODMDS has indicated the presence of fine-grained sediment within the monitoring zones. However, since the Charleston Harbor is formed by the conjunction of three rivers, it has been suggested that some of the fine-grained sediment surrounding the ODMDS could be due to river transport rather than solely by disposal activities. In order to trace the outflow of sediment from the harbor, natural and man-made isotopes were utilized. (7)Be (natural cosmogenic isotope) and (137)Cs (man-made isotope) are often associated with estuarine sediments. Both isotopes were used as tracers in an attempt to determine the extent of density driven sediment flow from the Charleston Harbor. (7)Be was detected in many of the offshore sampling stations indicating a direct correlation to the harbor. (137)Cs was only found in one sediment trap sample offshore, but none the less indicated some transport from the harbor. Further study for utilizing isotopic tracers in determining offshore sediment transport is still being conducted at the disposal site. It is anticipated that further (7)Be and (137)Cs isotopic monitoring offshore Charleston will aid in determining the role that tidal and density driven sediments play in the sediment budgets at the hard bottom reef sites.

  5. An environmental assessment of the Charleston Ocean Dredged Material Disposal Site and surrounding areas after partial completion of the Charleston Harbor Deepening Project.

    PubMed

    Zimmerman, Lynn E; Jutte, Pamela C; Van Dolah, Robert F

    2003-11-01

    A project to deepen shipping and entrance channels in Charleston Harbor was conducted from 1999 to 2002. This generated approximately 22 million cubic yards of sediment for offshore disposal. Assessments of biological and physical conditions in the Charleston Ocean Dredged Material Disposal Site and surrounding areas were conducted prior to deepening (1993-94), and partway through the disposal period (2000). Results from the 2000 survey are presented and compared to the baseline survey. The study area was composed of the disposal zone and surrounding areas and divided into 20 one square mile strata. Within each stratum, benthic grab samples were collected from ten random sites for analysis of sediment composition and contaminants and macrobenthic assemblages. No contaminant levels were above effects range low levels. Results revealed that sediments in the western strata had significantly higher silt/clay content in the 2000 survey when compared to baseline sediments, while sediments east of the disposal zone were similar to baseline. Analyses were performed on a subset of the benthic data that compared baseline to 2000 conditions in western and eastern strata. The benthic communities in western strata were altered following disposal operations. The benthic community east of the disposal area was not different from baseline conditions. These alterations in the benthic community were attributed to changes in bottom habitat characteristics rather than pollution effects.

  6. Social and Economic Impacts of Selected Potential Dredged Material Containment Facilities in Long Island Sound.

    DTIC Science & Technology

    1981-09-01

    DREDGING/DISPOSAL PERMlITS Pt/TaIm/Cfty pemitI~ ~ Suft. Aaajaav S . rtf M~l M9?3 0 Rover I". -I IlS to1 e~ cftI1 for ____ bwimimd. 196 10182 of Tida w~et...NORTHRDP SEP RI UNCLASSIFED CEM _4280-0OR735 DACW33-AG0-C 61 F/ S 13/2 NL .EIIIIIIIIIIIl EIIIIIIIIIIIIl IIfhhffffflllf L3= L2 11111 1. I iiiii 18...8217AGE ("oen Date &.**d) READ INSTRUCTIONSREPORT DOCU AENTATION PAGE BEFORE COMPLETING FORM 1. REPORT NUMBER z.OT ACCESSION No . Ot TS CATALOG NUMISER S

  7. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 of 38-Foot Project)

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Kohn, N.P.; Lefkovitz, L.F. )

    1992-01-01

    At the request of the US Army Corps of Engineers (USACE), environmental studies were conducted by Battelle/Marine Science Laboratory (MSL) to evaluate the suitability of sediments from Oakland Inner Harbor for dredging and ocean disposal. During the Phase 3 38-Foot Project, sediment cores were collected from mudline to {minus}39 ft mean lower low water at various locations in Oakland Inner Harbor channel and allocated to six composite samples. These composites were evaluated through physical/chemical analyses, acute toxicity to sensitive marine organisms, and bioaccumulation potential. Sediment samples from individual locations were tested for physical/chemical parameters only. The results of toxicological and bioaccumulation testing may be used by USACE to determine the amount of potential dredged material from Oakland Inner Harbor channel acceptable for open-water disposal as defined by the Draft Implementation Manual (EPA/USACE 1990) and consistent with the Water Resources Development Act of 1986 (Public Law 99-662). This is Volume 2 of a two-volume data report that represents the data gathered during the Oakland Harbor Phase 3 38-Foot Project, conducted in the Fall of 1990. This data report does not include interpretation or statistical analysis of the 38-Foot data. Volume 1 includes the project background as well as data and results presented in Appendixes A through H. Volume 2 includes the remaining data presented in Appendixes I through L.

  8. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 of 38-Foot Project)

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Kohn, N.P.; Lefkovitz, L.F. )

    1992-01-01

    At the request of the US Army Corps of Engineering (USACE), environmental studies were conducted by Battelle/Marine Sciences Laboratory (MSL) to evaluate the suitability of sediments from Oakland Inner Harbor for dredging and ocean disposal. During the Phase 3 38-Foot Project, sediment cores were collected from mudline to {minus}39 ft mean lower low water at various locations in Oakland Inner Harbor channel and allocated to six composite samples. These composites were evaluated through physical/chemical analyses, acute toxicity to sensitive marine organisms, and bioaccumulation potential. Sediment samples from individual locations were tested for physical/chemical parameters only. The results of toxicological and bioaccumulation testing may be used by USACE to determine the amount of potential dredged material from Oakland Inner Harbor channel acceptable for open-water disposal as defined by the Draft Implementation Manual (EPA/USACE 1990) and consistent with the Water Resources Development Act of 1986 (Public Law 99-662). This is Volume 1 of a two-volume data report that presents the data gathered during the Oakland Harbor Phase 3 38-Foot Project, conducted in the Fall of 1990. This data report does not include interpretation or statistical analysis of the 38-Foot data. Volume 1 includes the project background as well as a full presentation of data and results in Appendixes A through H. Volume 2 contains the remaining data in Appendixes I through L.

  9. Ecological evaluation of proposed dredged material from Wilmington Harbor and Military Ocean Terminal, Sunny Point, North Carolina

    SciTech Connect

    Ward, J.A.; Pinza, M.R.; Barrows, M.E.; Word, J.Q.

    1993-07-01

    This report is intended to provide information required to address potential ecological effects of the proposed disposal of Wilmington Harbor and Military Ocean Terminal, Sunny Point (MOTSU), North Carolina, sediments in the ocean. The report is divided into five sections. Section 1.0 is the introduction containing a brief overview of the study and the study objectives. Section 2.0 describes the methods and materials used for sample collection, processing, toxicological and bioaccumulation testing, physical/chemical analysis of sediments and tissues, data analysis, and quality assurance procedures. Section 3.0 presents the results of field collections, sediment chemistry, toxicological testing, and tissue chemistry resulting from bioaccumulation exposures. Section 4.0 presents a discussion of the results and summary conclusions concerning the acceptability of the Wilmington Harbor and MOTSU dredged material for ocean disposal. Section 5.0 lists the literature cited in support of this document. A series of appendixes contain detailed data listings.

  10. Long-Term Effects of Dredging Operations Program: Assessing Bioaccumulation in Aquatic Organisms Exposed to Contaminated Sediments

    DTIC Science & Technology

    1991-07-01

    Bioconcentration of Hydrophobic Chemicals by Fish ," Ecotoxicology and Environmental Safety. Vol 16, pp 242-257. Connolly, J. P., and Pedersen, C. J...Ocean Disposal of Wastes," Chapter 12 in Fate and Effects of Sediment-Bound Chemicals in Aauatic Systems , K. C. Dickson, A. W. Maki, and W. A. Brungs...AD-A239 551 LONG-TERM EFFECTS OF DREDGING{Tf I IIIID . OPERATIONS PROGRAM MISCELLANEOUS PAPER D-91-2 ASSESSING BIOACCUMULATION IN AQUATIC ORGANISMS

  11. Changes in the geochemistry and ecotoxicity of a Zn and Cd contaminated dredged sediment over time after land disposal.

    PubMed

    Piou, Stéphanie; Bataillard, Philippe; Laboudigue, Agnès; Férard, Jean-François; Masfaraud, Jean-François

    2009-08-01

    The management of dredged sediments is of environmental concern worldwide since they may be overloaded with myriads of pollutants. For inland waters' sediments, disposal on land is a common practice. For the long-term risks assessment of such a management, a better understanding of the fate of pollutants over time and an assessment of possible associated biological consequences are needed. Here, we studied the geochemical distribution of Fe, Mn, Zn and Cd in sediment dredged from the Scarpe canal (Nord-Pas-de-Calais Region, France). Analyses were carried out immediately after dredging and 12, 18 and 24 months after disposal in field conditions. In parallel, ecotoxicity of sediment leachates was assessed using standardized bioassays. The results reflected an initial oxidation of sulphides (first year) followed by changes explained by a reversible binding of metals to organic matter in winter and to Fe oxihydroxides in summer. The water-leachable fraction represented less than 2% of the total metal and its ecotoxicity was higher for deposited sediments than for the fresh one. After first year of disposal, sediment ecotoxicity remained stable. A long-term natural attenuation of metals within disposed sediment seemed unlikely since their speciation seemed to fluctuate seasonally without any time trend over years.

  12. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 2 of -42-foot project)

    SciTech Connect

    Word, J.Q.; Ward, J.A.; Strand, J.A.; Kohn, N.P.; Squires, A.L. )

    1990-09-01

    The US Army Corps of Engineers (USACE), San Francisco District, was authorized by the Water Resources Development Act of 1986 to deepen and widen the navigation channels of Inner and Outer Oakland Harbor, California, to accommodate modern deep-draft vessels. The recommended plan consists of deepening the harbor channels from the presently authorized water depth of {minus}35 ft mean lower low water (MLLW) to {minus}42 ft MLLW and supplying the harbor with adequate turning basins and berthing areas. Offshore ocean disposal of the dredged sediment is being considered, provided there is no evident of harmful ecological effects. It harmful ecological effects are not evident then the appropriate certifications from state environmental quality agencies and concurrence from the Environmental Protection Agency can be obtained to allow disposal of sediment. To help provide the scientific basis for determining whether Oakland Harbor sediments are suitable for offshore disposal, the Battelle/Marine Sciences Laboratory (MSL) collected sediment cores from 23 stations in Inner and Outer Oakland Harbor, evaluated these sediment cores geologically, performed chemical analyses for selected contaminants in sediments, conducted a series of solid phase toxicity tests with four sensitive marine invertebrates and assessed the bioaccumulation potential of sediment-associated contaminants in the tissues of Macoma Nasuta. 43 refs., 26 figs., 61 tabs.

  13. Recycling biosolids and lake-dredged materials to pasture-based animal agriculture: Alternative nutrient sources for forage productivity and sustainability.

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The prohibition of dumping dredged and domestic sewage sludge (DSS) materials in streams and oceans, diminishing land fill space, skyrocketing landfill costs, and concerns over air pollution from incineration of wastes have contributed to a strong public interest in finding alternative, environmenta...

  14. Evaluation of dredged material proposed for ocean disposal from Gravesend Bay Anchorage, New York

    SciTech Connect

    Barrows, E.S.; Gruendell, B.D.

    1996-09-01

    The Gravesend Bay Anchorage was one of seven waterways that the US Army Corps of Engineers-New York District (USACE-NYD) requested the Battelle Marine Sciences Laboratory (MSL) to sample and evaluate for dredging and disposal in February 1994. Sediment samples were submitted for physical and chemical analyses to provide baseline sediment chemistry data on the Gravesend Bay Anchorage. Individual sediment core samples collected at the Gravesend Bay Anchorage were analyzed for grain size, moisture content, and total organic carbon (TOC). Two samples, one of composited sediment cores representing the southeast corner of the anchorage (COMP GR), and one sediment core representing the northeast corner of the anchorage (Station GR-1 0), were analyzed for bulk density, specific gravity, metals, chlorinated pesticides, polychlorinated biphenyl (PCB) congeners, polynuclear aromatic hydrocarbons (PAH), and 1,4-dichlorobenzene.

  15. A temporal and spatial assessment of TBT concentrations at dredged material disposal sites around the coast of England and Wales.

    PubMed

    Bolam, Thi; Barry, Jon; Law, Robin J; James, David; Thomas, Boby; Bolam, Stefan G

    2014-02-15

    Despite legislative interventions since the 1980s, contemporary concentrations of organotin compounds in marine sediments still impose restrictions on the disposal of dredged material in the UK. Here, we analyse temporal and spatial data to assess the effectiveness of the ban on the use of TBT paints in reducing concentrations at disposal sites. At a national scale, there was a statistically significant increase in the proportion of samples in which the concentration was below the limit of detection (LOD) from 1998 to 2010. This was observed for sediments both inside and outside the disposal sites. However, this temporal decline in organotin concentration is disposal site-specific. Of the four sites studied in detail, two displayed significant increases in proportion of samples below LOD over time. We argue that site-specificity in the effectiveness of the TBT ban results from variations in historical practices at source and unique environmental characteristics of each site.

  16. Evaluation of Metals Release from Oxidation of Fly Ash during Dredging of the Emory River, TN

    DTIC Science & Technology

    2011-08-01

    Figure 18. Selenium speciation of the spots defined in (Figure 17) for the original source pile fly ash material using µ-XANES...37 Figure 22. Textural triangle showing the percentages of sand-, silt-, and clay-sized particle in the ash materials ...confined disposal facility – a structure designed to receive sediments dredged from a navigation channel and safely contain the contaminants d

  17. PHYTOREMEDIATION OF DREDGED SEDIMENTS: A CASE STUDY AT THE JONES ISLAND CDF

    EPA Science Inventory

    The Jones Island Confined Disposal Facility (CDF) is a 44 acre in-lake area that receives dredged material from Milwaukee Harbor and the surrounding waterways. Some of those materials are contaminated with industrial waste and urban run-off. The CDF is nearing the end of its desi...

  18. Dredging Operations Technical Support Program. Effectiveness of Capping in Isolating Dutch Kills Sediment from Biota and the Overlying Water.

    DTIC Science & Technology

    1986-06-01

    Identify by block num ber) Marine pollution --Experiments (LC) Environmental engineering (LC) Contamination (Technology) (LC) Dredged material (WES...Harbor Sediments and Dredging Spoil," Marine Pollution Bulletin, Vol 12, No. 10 pp 351-353. Babinchak, J. A., Graikoski, J. T., Dudley, S., and...Vol 34, No. 1, pp 38-41. ___-___ 1977b. "Distribution of Fecal Coliforms in Bottom Sediments fromEl the New York Bight," Marine Pollution Bulletin, Vol

  19. Potential of Remote Sensing in the Corps of Engineers Dredging Program.

    DTIC Science & Technology

    1985-11-01

    The potential of remote sensing in the Corps of Engineers Dredging Program for providing data on channel surveys, sediment drift and dispersion...Aerial photography; Army Corps of engineers; Dredged materials; Dredging; Remote sensing .

  20. Ecological evaluation of proposed dredged material from Bulls Head Channel (lower Suisun Bay)

    SciTech Connect

    Kohn, N.P.; White, P.J.; Gardiner, W.W.; Word, J.Q.

    1994-07-01

    This report describes the sampling and testing program conducted for USACE by Battelle/Marine Sciences Laboratory (MSL) to address (1) exclusion from further testing for ocean disposal, (2) suitability of open-water disposal within San Francisco Bay, and (3) beneficial uses, based on open-water and upland (leaching) disposal criteria, for the estimated 1.86 million cubic yards of sediment to be dredged from Bulls Head Channel and turning basin. To meet these objectives, core samples were collected from 28 locations to a depth of -47 ft mean lower low water (MLLW), which is -45 ft MLLW plus 2 ft overdepth. One to three samples per coring location were characterized physically and chemically; sediment from groups of locations and from various depth strata were combined into composite samples for biological toxicity characterization in addition to physical and chemical characterization. The chemical and biological tests were conducted following the guidance of USACE, the US Environmental Protection Agency (EPA), and state regulatory agencies.

  1. Environmental impacts and regulatory policy implications of spray disposal of dredged material in Louisiana wetlands

    USGS Publications Warehouse

    Cahoon, D.R.; Cowan, J.H.

    1988-01-01

    The capabilities of a new wetland dredging technology were assessed along with associated newly developed state and federal regulatory policies to determine if policy expectations realistically match the technological achievement. Current regulatory practices require amelioration of spoil bank impacts upon abandonment of an oil/gas well, but this may not occur for many years or decades, if at all. Recently, a dreding method (high-pressure spray spoil disposal) was developed that does not create a spoil bank in the traditional sense. Its potential for reducing environmental impacts was recognized immediately by regulatory agencies for whom minimizing spoil bank impacts is a major concern. The use of high-pressure spray disposal as a suitable alternative to traditional dreding technology has been adopted as policy even though its value as a management tool has never been tested or verified. A qualitative evaluation at two spoil disposal sites in saline marsh indicates that high-pressure spray disposal may indeed have great potential to minimize impacts, but most of this potential remains unverified. Also, some aspects of current regulatory policy may be based on unrealistic expectations as to the ability of this new technology to minimize or eliminate spoil bank impacts.

  2. Environmental effects of dredging. Use of daphnia magna to predict consequences of bioaccumulation

    SciTech Connect

    1987-03-01

    Results reported herein represent a portion of the laboratory research evaluating the relationship between mercury and cadmium tissue residues and biological effects in the freshwater crustacean, Daphnia magna (commonly known as the water flea). Procedures presented here for a 28-day Daphnia magna toxicity test could be used in screening for water-column toxicity resulting from open-water disposal of a specific dredged material. As a part of its regulatory and dredging programs, the U. S. Army Corps of Engineers often conducts, or requires to be conducted, an assessment of the potential for bioaccumulation of environmental contaminants from sediment scheduled for dredging and open-water disposal. There is, at present, no generally accepted guidance available to aid in the interpretation of the biological consequences of bioaccumulation. To provide an initial basis for such guidance, the Environmental Laboratory is conducting both literature database analyses and experimental laboratory studies as part of the Long-Term Effects of Dredging Operations (LEDO) Program.

  3. Surface contamination on LDEF exposed materials

    NASA Technical Reports Server (NTRS)

    Hemminger, Carol S.

    1992-01-01

    X-ray photoelectron spectroscopy (XPS) has been used to study the surface composition and chemistry of Long Duration Exposure Facility (LDEF) exposed materials including silvered Teflon (Ag/FEP), Kapton, S13GLO paint, quartz crystal monitors (QCM's), carbon fiber/organic matrix composites, and carbon fiber/Al Alloy composites. In each set of samples, silicones were the major contributors to the molecular film accumulated on the LDEF exposed surfaces. All surfaces analyzed have been contaminated with Si, O, and C; most have low levels (less than 1 atom percent) of N, S, and F. Occasionally observed contaminants included Cl, Na, K, P, and various metals. Orange/brown discoloration observed near vent slots in some Ag/FEP blankets were higher in carbon, sulfur, and nitrogen relative to other contamination types. The source of contamination has not been identified, but amine/amide functionalities were detected. It is probable that this same source of contamination account for the low levels of sulfur and nitrogen observed on most LDEF exposed surfaces. XPS, which probes 50 to 100 A in depth, detected the major sample components underneath the contaminant film in every analysis. This probably indicates that the contaminant overlayer is patchy, with significant areas covered by less that 100 A of molecular film. Energy dispersive x-ray spectroscopy (EDS) of LDEF exposed surfaces during secondary electron microscopy (SEM) of the samples confirmed contamination of the surfaces with Si and O. In general, particulates were not observed to develop from the contaminant overlayer on the exposed LDEF material surfaces. However, many SiO2 submicron particles were seen on a masked edge of an Ag/FEP blanket. In some cases such as the carbon fiber/organic matrix composites, interpretation of the contamination data was hindered by the lack of good laboratory controls. Examination of laboratory controls for the carbon fiber/Al alloy composites showed that preflight contamination was

  4. Measurements of radioactive contaminants in semiconductor materials

    NASA Astrophysics Data System (ADS)

    Gordon, Michael S.; Rodbell, Kenneth P.; Murray, Conal E.; McNally, Brendan D.

    2016-12-01

    The emission of alpha particles from materials used to manufacture semiconductors can contribute substantially to the single-event upset rate. The alpha particles originate from contamination in the materials, or from radioactive isotopes, themselves. In this review paper, we discuss the sources of the radioactivity and the measurement methods to detect the emitted particles.

  5. Effect of EDTA, EDDS, NTA and citric acid on electrokinetic remediation of As, Cd, Cr, Cu, Ni, Pb and Zn contaminated dredged marine sediment.

    PubMed

    Song, Yue; Ammami, Mohamed-Tahar; Benamar, Ahmed; Mezazigh, Salim; Wang, Huaqing

    2016-06-01

    In recent years, electrokinetic (EK) remediation method has been widely considered to remove metal pollutants from contaminated dredged sediments. Chelating agents are used as electrolyte solutions to increase metal mobility. This study aims to investigate heavy metal (HM) (As, Cd, Cr, Cu, Ni, Pb and Zn) mobility by assessing the effect of different chelating agents (ethylenediaminetetraacetic acid (EDTA), ethylenediaminedisuccinic acid (EDDS), nitrilotriacetic acid (NTA) or citric acid (CA)) in enhancing EK remediation efficiency. The results show that, for the same concentration (0.1 mol L(-1)), EDTA is more suitable to enhance removal of Ni (52.8 %), Pb (60.1 %) and Zn (34.9 %). EDDS provides effectiveness to increase Cu removal efficiency (52 %), while EDTA and EDDS have a similar enhancement removal effect on As EK remediation (30.5∼31.3 %). CA is more suitable to enhance Cd removal (40.2 %). Similar Cr removal efficiency was provided by EK remediation tests (35.6∼43.5 %). In the migration of metal-chelate complexes being directed towards the anode, metals are accumulated in the middle sections of the sediment matrix for the tests performed with EDTA, NTA and CA. But, low accumulation of metal contamination in the sediment was observed in the test using EDDS.

  6. Effects of Black Rock Harbor Dredged Material on the Scope for Growth of the Blue Mussel, Mytilus edulis after Laboratory and Field Exposures

    DTIC Science & Technology

    1987-09-01

    34Effects of Black Robk Harbor Dredged Material oil the Scope for Growth of the Blue Mussel, Mytilus Edulis, after Laboratory and Field Exposures" 5. In...Experiments ....... . ....... ....... .. ..... ... . .......... ....... . 37 8 Clearance Rates of Mussels in Dosing System Exposure Tanks .... 45 9...increasing concentra- tions of the water-soluble fraction of crude oil . Widdows et al. (1982) also reported a dose-response effect between SF0 and

  7. Beneficial Uses of Dredged Material. Proceedings of the Gulf Coast Regional Workshop Held on 26-28 April 1988 in Galveston, Texas

    DTIC Science & Technology

    1990-02-01

    East Africa I. Status, Morphology and Distributions," Investigation Report No. 35, South African Association for Marine Biological Research, Durban...Hanley K. Smith .......................... 143 Environmental Assessment of Dredged Material Disposal on Grazing Lands at East Matagorda Bay, Texas...Texas Environmental Coalition, PO Box 2859, South Padre Island, TX 78597 (512-761-4635) BRADLEY, Paul, USAED, Mobile District, 109 St. Joseph St., Rm

  8. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 B of -42-foot project). Volume 1, Analyses and discussion

    SciTech Connect

    Kohn, N.P.; Ward, J.A.; Mayhew, H.L.; Word, J.Q.; Barrows, E.S.; Goodwin, S.M.; Lefkovitz, L.F.

    1992-06-01

    The Water Resources Development Act of 1986 (Public Law 99-662) authorized the US Army Corps of Engineers (USACE) San Francisco District, to deepen and widen the navigational channels of the Oakland Inner and Outer Harbors to accomodate deeper-draft vessels. The USACE is considering several disposal options for the dredged material removed during these channel improvements including open-water disposal. Dredged material proposed for open-water disposal must be evaluated to determine the potential impacts of the disposal activity on the water column and disposal site enviromments. The USACE requested that Battelle/Marine Sciences Laboratory (MSL) conduct studies to evaluate open-water disposal options for Oakland Harbor sediments. This request developed into the Oakland Harbor Phase III Program. This is Volume 1 of a two-volume report that presents information gathered to determine the suitability of ocean disposal of sediments dredged from Oakland Harbor. This volume contains project background, materials and methods, results, discussion, and conclusions.

  9. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 B of -42-foot project)

    SciTech Connect

    Kohn, N.P.; Ward, J.A.; Mayhew, H.L.; Word, J.Q.; Barrows, E.S.; Goodwin, S.M.; Lefkovitz, L.F. )

    1992-06-01

    The Water Resources Development Act of 1986 (Public Law 99-662) authorized the US Army Corps of Engineers (USACE) San Francisco District, to deepen and widen the navigational channels of the Oakland Inner and Outer Harbors to accomodate deeper-draft vessels. The USACE is considering several disposal options for the dredged material removed during these channel improvements including open-water disposal. Dredged material proposed for open-water disposal must be evaluated to determine the potential impacts of the disposal activity on the water column and disposal site enviromments. The USACE requested that Battelle/Marine Sciences Laboratory (MSL) conduct studies to evaluate open-water disposal options for Oakland Harbor sediments. This request developed into the Oakland Harbor Phase III Program. This is Volume 1 of a two-volume report that presents information gathered to determine the suitability of ocean disposal of sediments dredged from Oakland Harbor. This volume contains project background, materials and methods, results, discussion, and conclusions.

  10. Physical oceanographic processes at candidate dredged-material disposal sites B1B and 1M offshore San Francisco

    SciTech Connect

    Sherwood, C.R.; Denbo, D.W.; Downing, J.P. ); Coats, D.A. )

    1990-10-01

    The US Army Corps of Engineers (USACE), San Francisco District, has identified two candidate sites for ocean disposal of material from several dredging projects in San Francisco Bay. The disposal site is to be designated under Section 103 of the Ocean Dumping Act. One of the specific criteria in the Ocean Dumping Act is that the physical environments of the candidate sites be considered. Toward this goal, the USACE requested that the Pacific Northwest Laboratory conduct studies of physical oceanographic and sediment transport processes at the candidate sites. Details of the methods and complete listing or graphical representation of the results are contained in this second volume of the two-volume report. Appendix A describes the methods and results of a pre-disposal bathymetric survey of Site B1B, and provides an analysis of the accuracy and precision of the survey. Appendix B describes the moorings and instruments used to obtain physical oceanographic data at the candidate sites, and also discussed other sources of data used in the analyses. Techniques used to analyze the formation, processed data, and complete results of various analyses are provided in tabular and graphical form. Appendix C provides details of the sediment transport calculations. Appendix D describes the format of the archived current meter data, which is available through the National Oceanographic Data Center. 43 refs., 54 figs., 58 tabs.

  11. Potential of kenaf (Hibiscus cannabinus L.) and corn (Zea mays L.) for phytoremediation of dredging sludge contaminated by trace metals.

    PubMed

    Arbaoui, Sarra; Evlard, Aricia; Mhamdi, Mohamed El Wafi; Campanella, Bruno; Paul, Roger; Bettaieb, Taoufik

    2013-07-01

    The potential of kenaf (Hibiscus cannabinus L.) and corn (Zea mays L.) for accumulation of cadmium and zinc was investigated. Plants have been grown in lysimetres containing dredging sludge, a substratum naturally rich in trace metals. Biomass production was determined. Sludge and water percolating from lysimeters were analyzed by atomic absorption spectrometry. No visible symptoms of toxicity were observed during the three- month culture. Kenaf and corn tolerate trace metals content in sludge. Results showed that Zn and Cd were found in corn and kenaf shoots at different levels, 2.49 mg/kg of Cd and 82.5 mg/kg of Zn in kenaf shoots and 2.1 mg/kg of Cd and 10.19 mg/kg in corn shoots. Quantities of extracted trace metals showed that decontamination of Zn and Cd polluted substrates is possible by corn and kenaf crops. Tolerance and bioaccumulation factors indicated that both species could be used in phytoremediation.

  12. Satellite Contamination and Materials Outgassing Knowledge base

    NASA Technical Reports Server (NTRS)

    Minor, Jody L.; Kauffman, William J. (Technical Monitor)

    2001-01-01

    Satellite contamination continues to be a design problem that engineers must take into account when developing new satellites. To help with this issue, NASA's Space Environments and Effects (SEE) Program funded the development of the Satellite Contamination and Materials Outgassing Knowledge base. This engineering tool brings together in one location information about the outgassing properties of aerospace materials based upon ground-testing data, the effects of outgassing that has been observed during flight and measurements of the contamination environment by on-orbit instruments. The knowledge base contains information using the ASTM Standard E- 1559 and also consolidates data from missions using quartz-crystal microbalances (QCM's). The data contained in the knowledge base was shared with NASA by government agencies and industry in the US and international space agencies as well. The term 'knowledgebase' was used because so much information and capability was brought together in one comprehensive engineering design tool. It is the SEE Program's intent to continually add additional material contamination data as it becomes available - creating a dynamic tool whose value to the user is ever increasing. The SEE Program firmly believes that NASA, and ultimately the entire contamination user community, will greatly benefit from this new engineering tool and highly encourages the community to not only use the tool but add data to it as well.

  13. Analyses of water and dredged material from selected southern Louisiana waterways and selected areas in the Gulf of Mexico, 1976-78

    USGS Publications Warehouse

    Stallworth, Geraldine R.; Jordan, Helen F.

    1980-01-01

    The U.S. Geological Survey was requested by the U.S. Army Corps of Engineers to provide water-quality data to evaluate the potential environmental effects of (1) dredging activities in selected navigable waterways of southern Louisiana and (2) the disposal of dredged material at selected areas in the Gulf of Mexico. Areas studied from September 1976 to May 1978 included five ocean disposal sites in the Gulf of Mexico, in addition to the following waterways: Baptiste, Collette Bayou, Mississippi River at Head of Passes and Southwest Pass, Mississippi River at Tiger Pass, Bayou Black, Intracoastal Waterway (Port Allen to Morgan City), and Calcasieu River and Ship Channel. Samples were analyzed for selected chemical, physical, and biological constituents. (USGS)

  14. Three-year summary report of biological monitoring at the Southwest Ocean dredged-material disposal site and additional locations off Grays Harbor, Washington, 1990--1992

    SciTech Connect

    Antrim, L.D.; Shreffler, D.K.; Pearson, W.H.; Cullinan, V.I. )

    1992-12-01

    The Grays Harbor Navigation Improvement Project was initiated to improve navigation by widening and deepening the federal channel at Grays Harbor. Dredged-material disposal sites were selected after an extensive review process that included inter-agency agreements, biological surveys, other laboratory and field studies, and preparation of environmental impact statements The Southwest Site, was designated to receive materials dredged during annual maintenance dredging as well as the initial construction phase of the project. The Southwest Site was located, and the disposal operations designed, primarily to avoid impacts to Dungeness crab. The Final Environmental Impact Statement Supplement for the project incorporated a Site Monitoring Plan in which a tiered approach to disposal site monitoring was recommended. Under Tier I of the Site Monitoring Plan, Dungeness crab densities are monitored to confirm that large aggregations of newly settled Dungeness crab have not moved onto the Southwest Site. Tier 2 entails an increased sampling effort to determine whether a change in disposal operations is needed. Four epibenthic surveys using beam trawls were conducted in 1990, 1991, and 1992 at the Southwest Site and North Reference area, where high crab concentrations were found in the spring of 1985. Survey results during these three years prompted no Tier 2 activities. Epibenthic surveys were also conducted at two nearshore sites where construction of sediment berms has been proposed. This work is summarized in an appendix to this report.

  15. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 B of -42-foot project). Volume 2, Appendixes

    SciTech Connect

    Kohn, N.P.; Ward, J.A.; Mayhew, H.L.; Word, J.Q.; Barrows, E.S.; Goodwin, S.M.; Lefkovitz, L.F.

    1992-06-01

    The Water Resources Development Act of 1986 (Public Law 99-662) authorized the US Army Corps of Engineers (USACE) San Francisco District, to deepen and widen the navigational channels of the Oakland Inner and Outer Harbors to accommodate deeper-draft vessels. The USACE is considering several disposal options for the dredged material removed during these channel improvements including open-water disposal. Dredged material proposed for open-water disposal must be evaluated to determine the potential impacts of the disposal activity on the water column and disposal site environments. The USACE requested that Battelle/Marine Sciences Laboratory (MSL) conduct studies to evaluate open-water disposal options for Oakland Harbor sediments. This request developed into the Oakland Harbor Phase III Program. This is Volume 2 of a two-volume report that presents information gathered to determine the suitability of ocean disposal of sediments dredged from Oakland Harbor. This volume contains the Appendixes (A through N), which provide details of the data analyses and full presentation of the data and results.

  16. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 B of -42-foot project)

    SciTech Connect

    Kohn, N.P.; Ward, J.A.; Mayhew, H.L.; Word, J.Q.; Barrows, E.S.; Goodwin, S.M.; Lefkovitz, L.F. )

    1992-06-01

    The Water Resources Development Act of 1986 (Public Law 99-662) authorized the US Army Corps of Engineers (USACE) San Francisco District, to deepen and widen the navigational channels of the Oakland Inner and Outer Harbors to accommodate deeper-draft vessels. The USACE is considering several disposal options for the dredged material removed during these channel improvements including open-water disposal. Dredged material proposed for open-water disposal must be evaluated to determine the potential impacts of the disposal activity on the water column and disposal site environments. The USACE requested that Battelle/Marine Sciences Laboratory (MSL) conduct studies to evaluate open-water disposal options for Oakland Harbor sediments. This request developed into the Oakland Harbor Phase III Program. This is Volume 2 of a two-volume report that presents information gathered to determine the suitability of ocean disposal of sediments dredged from Oakland Harbor. This volume contains the Appendixes (A through N), which provide details of the data analyses and full presentation of the data and results.

  17. Chemical characterisation of dredged sediments in relation to their potential use in civil engineering.

    PubMed

    Zuliani, Tea; Mladenovič, Ana; Ščančar, Janez; Milačič, Radmila

    2016-04-01

    During capital and/or maintenance dredging operations, large amounts of material are produced. Instead of their discharge, dredged sediments may be a valuable natural resource if not contaminated. One of the possible areas of application is civil engineering. In the present work, the environmental status of seaport dredged sediment was evaluated in order to investigate its potential applicability as a secondary raw material. Sediments were analysed for element concentrations in digested samples, aqueous extracts and fractions from sequential extraction; for fluoride, chloride and sulphate concentrations in aqueous extracts; and for tributyltin (TBT). Granulometric and mineralogical compositions were also analysed. The elemental impact was evaluated by calculation of the enrichment factors. The total element concentrations determined showed moderate contamination of the dredged sediments as was confirmed also by their moderate enrichment factors, presumably as a result of industrial and port activities. Elemental concentrations in the aqueous extract were very low and therefore do not represent any hazard for the environment. The water-soluble element concentrations were under the threshold levels set by the EU Directive on the landfill of waste, on the basis of which the applicability of dredged sediments in civil engineering is evaluated, while the content of chloride and sulphate were above the threshold levels. It was found out that due to the large amounts of sediment available, civil engineering applications such as the construction of embankments and backfilling is the most beneficial recycling solution at present.

  18. Puget Sound Dredged Disposal Analysis (PSDDA). Management Plan Report (MPR), Unconfined, Open-Water Disposal of Dredged Material. Phase 1 (Central Puget Sound)

    DTIC Science & Technology

    1988-06-01

    additional sediment loading. Key Regulatory Authorities. Section 404 of the Federal Water Pollution Control Act (FWPCA) Amendments of 1972 established a...continue. Puget Sound Pollution and Contaminated Sediments. The past practice of cis- charging untreated or only partially treated industrial and municipal...degradation over time of the water and sediment quality in some areas of Puget Sound. Increasing scientific evidence about the harmful effects of pollution

  19. San Francisco Bay Long Term Management Strategy for Dredging

    EPA Pesticide Factsheets

    The San Francisco Bay Long Term Management Strategy (LTMS) is a cooperative effort to develop a new approach to dredging and dredged material disposal in the San Francisco Bay area. The LTMS serves as the Regional Dredging Team for the San Francisco area.

  20. Applications of Dredging and Beach Fills in GenCade

    DTIC Science & Technology

    2016-06-01

    which dredging can be associated: ebb shoal, flood shoal, left and right attachment bars, and left and right bypassing bars. A dredging event in...equilibrium volumes were equal for all of the inlet shoals. The ebb and flood shoal volumes were 1,000,000 yd3/year while all other shoals (left and...10 years after dredging the ebb shoal, flood shoal, or right bypassing bar (removing the material entirely from the model) to dredging each shoal

  1. Dredging: Technology and environmental aspects. (Latest citations from the Life Sciences Collection data base). Published Search

    SciTech Connect

    Not Available

    1992-10-01

    The bibliography contains citations concerning the technology and environmental impacts of dredging. Equipment, including semi-submersible cutter platforms, is described. Other topics include sediment movement, factors affecting sediment movement, the disposal of dredged material, and computer models predicting the fate of the dredged materials. The environmental impacts of the dredged areas and the effects of ocean dumping of dredged material are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  2. Dredging: Technology and environmental aspects. (Latest citations from the Life Sciences collection database). Published Search

    SciTech Connect

    1996-03-01

    The bibliography contains citations concerning the technology and environmental impacts of dredging. Equipment, including semi-submersible cutter platforms, is described. Other topics include sediment movement, factors affecting sediment movement, the disposal of dredged material, and computer models predicting the fate of the dredged materials. The environmental impacts of the dredged areas and the effects of ocean dumping of dredged material are also discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. Dispersion Analysis of Charleston, South Carolina, Ocean Dredged Material Disposal Site.

    DTIC Science & Technology

    1994-03-01

    coral reef areas. Two levels of investigation were employed. A short-term analysis of the disposal operation was conducted to examine the immediate fate of material following release from the barge and subsequent descent to the ocean bottom. The second phase examines the long-term fate to determine whether local ocean currents are capable of eroding and transporting deposited material from the site to the reef area. Results of this study indicate the site to be dispersive and recommendations are made as to locations within the designated limits which will minimize the

  4. Coastal Modeling System: Dredging Module

    DTIC Science & Technology

    2016-06-01

    present version, the DM assumes a uniform bed composition and therefore is only recommended to be used with a single sediment size class. This...environmental forcing. MODEL SETUP: Dredging simulations are organized into dredge operations. Each dredging operation is characterized by a single ...DREDGE_OPERATION_BEGIN, name=DredgeOpBlock] Begin a dredging operation block structure. Name of dredg- ing operation [card=NAME, parent =DredgeOpBlock, optional

  5. Nonmetallic materials contamination studies. [space telescope

    NASA Technical Reports Server (NTRS)

    Muscari, J. A.; Beverlin, G.

    1980-01-01

    In order to impose adequate contamination control requirements in the selection of Wide Field Planetary Camera (WFPC) materials and to develop a data base of potential optical degradation of the WFPC charge-couple device window, the outgassing properties of WFPC materials and the collected volatile condensed material (CVCM) effects on MgF2 transmittance were measured. Changes in the transmittance were monitored in the wavelength region from 115 nm to 300 nm for selected CVCM thicknesses up to 150 nm. The outgassing properties of reemitted CVCM were also studied.

  6. Environmental effects of dredging, initial comparisons of six assays for the assessment of sediment genotoxicity. Technical note

    SciTech Connect

    McFarland, V.A.; Honeycutt, M.; Jarvis, S.

    1995-01-01

    This technical note reports and compares initial results of six genotoxicity bioassays applied to dredged sediments and describes progress toward development of a testing protocol to aid in regulatory decisionmaking when genotoxic chemicals are an issue of concern. The Long-term Effects of Dredging Operations Program work unit Genotoxicity of Contaminated Dredged Material was initiated in fiscal year 1990 to develop methods for assessing the genotoxic potential of dredged sediments. The impetus driving this new research and development effort was specific regulatory language in section 103 of the Ocean Dumping Act (Marine Protection, Research, and Sanctuaries Act (MPRSA) of 1972) prohibiting the open-water discharge of mutagenic, carcinogenic, or teratogenic substances in other than trace amounts, and language less specific but of similar intent in section 404 of the Clean Water Act (CWA).

  7. The effects of trawling, dredging and ocean dumping on the eastern Canadian continental shelf seabed

    NASA Astrophysics Data System (ADS)

    Messieh, S. N.; Rowell, T. W.; Peer, D. L.; Cranford, P. J.

    1991-08-01

    This paper presents an overview of current knowledge on the effects of trawling, dredging and ocean dumping on the eastern Canadian continental shelf seabed. The impact of trawling and dredging for fish and shellfish on marine habitats has recently attracted international attention among fisheries and environmental scientists. In Atlantic Canada, trawling and dredging are the principal methods of harvesting groundfish and scallops and ocean clams, respectively. It is estimated that fish trawlers and scallop dredges have swept tracks, cris-crossing the Canadian continental shelf, approximately 4.3 million km in length in 1985. In the past few years several studies were carried out by scientists from Canada, the United States and Europe to assess the impacts of trawling and dredging but results were inconclusive. Some studies showed physical damage as well as biological effects, whereas others indicated that the adverse effects were not considered to be serious. Fishermen are not the only potential users of the resources of the continental shelf. There is an increasing demand for good-quality sand and gravel aggregate and the ocean seabed is being seen as a possible source. The eastern Canadian continental shelf also exhibits hydrocarbon potential and operational and accidental discharges are an environmental concern. Increased marine transportation and expansion of the fishing fleet have resulted in a greater need for harbour dredging. Dredging and dredge spoil disposal were controlled by the Ocean Dumping Control Act and now the Canadian Environmental Protection Act which places restrictions on the composition of material that can be disposed of in the sea. Nevertheless some harbours contain contaminant concentrations exceeding the maximum allowable limits. It is concluded that the impacts of human activities on the continental shelf seabed environment are inevitable and the long-term effects, while difficult to determine, must be assessed. The sub-lethal effects

  8. Removal of organic contaminants from lithographic materials

    NASA Astrophysics Data System (ADS)

    Lytle, Wayne M.

    One of the critical issues still facing the implementation of extreme ultraviolet lithography (EUVL) into mainstream manufacturing for integrated circuit (IC) production is cleanliness. EUV photons at 13.5 nm are easily absorbed by many species, including dust, thin-film layers, and other debris present in the path of the photons. Carrying out EUVL inside a vacuum helps reduce the amount of photon loss for illumination, however contamination in the sys- tem is unavoidable, especially due to carbon growth on the multilayer mirror collectors and to soft defects in the form of organic contamination on the mask. Traditional cleaning methods employ the use of wet chemicals to etch contamination off of a surface, however this is limited in the sub-micron range of contaminant particles due to lack of transport of sufficient liquid chemical to the surface in order to achieve satisfactory particle removal. According to the International Technology Roadmap for Semiconductors (ITRS), the photomask must be particle free at inspection below 30 nm. However, when analyzing the ability of traditional methods to meet the cleaning needs set forth by the ITRS, these methods fall short and often add more contamination to the surface targeted for cleaning. With that in mind, a new cleaning method is being developed to supplant these traditional methods. Preliminary research into a plasma-based method to clean organic contaminants from lithographic materials constructed an experimental device that demonstrated the removal of both polystyrene latex nanoparticles (representing hydrocarbon contamination) in the range of 30 nm to 500 nm, as well as the removal of 30 nm carbon film layers on silicon wafers. This research, called the Plasma-Assisted Cleaning by Metastable Atomic Neutralization (PACMAN) process is being developed with semiconductor manufacturing cleaning in mind. A model of the helium metastable density within the processing chamber has been developed in addition to

  9. Material Placement Site for Maintenance Dredging, Treats Island, Illinois Waterway, Will County, Illinois

    DTIC Science & Technology

    1993-06-23

    Mft U.S. Army Engineer District, Rock Island w Ohm C•OT- as VO 4 s a Caw" b I A Material Placement Site for Maintenance A Will County. 4E. u mm D...34 .! DEPARTMENT OF THE ARMY ROCK ISLAND DISTRICT. CORPS OF ENGINEERS CLOCK TOWER BUILDING - P.O. BOX 2004 ROCK ISLAND. ILLINOIS...61204-2004 6RPLV 1TO 1i.,.,4LtToft OF: June 23, 1993 Planning Division SEE DOCUMENT DISTRIBUTION LIST The Rock Island District of the U.S. Army Corps of

  10. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 A of -42-foot project)

    SciTech Connect

    Ward, J A; Word, J Q; Pinza, M R; Mayhew, H L; Barrows, E S; Lefkovitz, L F

    1992-09-01

    The Battelle/Marine Sciences Laboratory (MSL) conducted a study to determine whether dredged sediments from Oakland Inner and Outer Harbors were suitable for ocean disposal. Nineteen test treatments, six reference treatments, and three control treatments were tested for physical/chemical parameters, water column effects, dredged- sediment toxicity, and bioaccumulation potential. Physical/chemical parameters were analyzed at each site and each composite sediment to a depth of -44 ft MLLW. These parameters included analysis for geological characteristics, conventional sediment measurements (grain size, total volatile solids, total organic carbon, oil and grease, and total petroleum hydrocarbons), metals,, polynuclear aromatic hydrocarbons (PAHs), pesticides, butyltins, and polychlorinated biphenyls (PCBs). Physical/chemical data were used in support of the toxicological and bioaccumulation testing, but were not used in the decision-making criteria described in the Draft Implementation manual under Tier III testing. To evaluate water column effects, MSL conducted suspended-particulate-phase (SPP) test using the mysid shrimp Holmesimysis sculpta, speckled sanddab citharichtys stigmaeus, and larvae of the pacific oyster Crassostrea gigas. Both a 48-h and a 96-h test were performed. The MSL evaluated dredged-sediment toxicity by conducting a total of eight solid-phase toxicity tests using the following organisms: the bivalve clam Macoma nasuta, the polychaete worm Nepthys caecoides, the speckled sanddab C. stigmaeus, and the amphipod Rhepoxynius abronius. Test duration ranged from 10 to 28 days. Bioaccumulation potential was evaluated in the 28-day M. Nasuta and N. caecoides solid-phase exposures by measuring the contaminants of concern present in their tissues after exposure to test, reference, and control sediments. This report contains the data and test results.

  11. Three-dimensional visualization maps of suspended-sediment concentrations during placement of dredged material in 21st Avenue West Channel Embayment, Duluth-Superior Harbor, Duluth, Minnesota, 2015

    USGS Publications Warehouse

    Groten, Joel T.; Ellison, Christopher A.; Mahoney, Mollie H.

    2016-06-30

    Excess sediment in rivers and estuaries poses serious environmental and economic challenges. The U.S. Army Corps of Engineers (USACE) routinely dredges sediment in Federal navigation channels to maintain commercial shipping operations. The USACE initiated a 3-year pilot project in 2013 to use navigation channel dredged material to aid in restoration of shoreline habitat in the 21st Avenue West Channel Embayment of the Duluth-Superior Harbor. Placing dredged material in the 21st Avenue West Channel Embayment supports the restoration of shallow bay aquatic habitat aiding in the delisting of the St. Louis River Estuary Area of Concern.The U.S. Geological Survey, in cooperation with the USACE, collected turbidity and suspended-sediment concentrations (SSCs) in 2014 and 2015 to measure the horizontal and vertical distribution of SSCs during placement operations of dredged materials. These data were collected to help the USACE evaluate the use of several best management practices, including various dredge material placement techniques and a silt curtain, to mitigate the dispersion of suspended sediment.Three-dimensional visualization maps are a valuable tool for assessing the spatial displacement of SSCs. Data collection was designed to coincide with four dredged placement configurations that included periods with and without a silt curtain as well as before and after placement of dredged materials. Approximately 230 SSC samples and corresponding turbidity values collected in 2014 and 2015 were used to develop a simple linear regression model between SSC and turbidity. Using the simple linear regression model, SSCs were estimated for approximately 3,000 turbidity values at approximately 100 sampling sites in the 21st Avenue West Channel Embayment of the Duluth-Superior Harbor. The estimated SSCs served as input for development of 12 three-dimensional visualization maps.

  12. Analysis of Organic Contaminants in Dredged Material using a Field-Portable GC-MS

    DTIC Science & Technology

    2009-09-01

    Acenaphthene 0.013 0.010 Fluorene 4.906 7.517 Fluoranthene 0.134 0.010 Anthracene 0.372 15.092 Pyrene 0.024 0.010 Fluoranthene 0.305 111.566 Acenapthene...however, the technology was originally developed for explosives, and therefore can be modified to analyze for a wide variety of organic compounds...For example, during the instrumentation’s original prove-out deployment for explosives in groundwater analysis, an unknown chromatographic peak in

  13. Puget Sound Dredged Disposal Analysis (PSDDA). Final Environmental Impact Statement Unconfined Open-Water Disposal for Dredged Material, Phase 2. (North and South Puget Sound)

    DTIC Science & Technology

    1989-09-01

    recent years, as public policy has been to protect environmentally important tidal areas, wetlands , and marshes. Consequently, nearshore disposal options...Material into Puget Sound 4-24 (5) Executive Order 11990, Protection of Wetlands 4-24 (6) Executive Order 11988, Flood Plain Management 4-24 v vii...TABLE OF CONTENTS (con.) Paragraph Page (5) Executive Order 11990, Protection of Wetlands !i-l,7 (6) Executive Order 11988, Flood Plain Management 4-47 (7

  14. Creation Of Constructed Tidal Flats Using Ocean Dredged Sediment

    NASA Astrophysics Data System (ADS)

    Park, S.; Yi, B.; Lee, I.; Sung, K.

    2007-12-01

    The enforcement of London dumping convention (1972) and protocols (1996) which are comprehensive assessment system for ocean dumping wastes needs environmentally sound treatment and/or reuse of dredged sediment. Creation of constructed tidal flats using dredged sediments could be one of the useful alternatives among other dredged sediment treatments. In this study, the pilot-scale constructed tidal flats with 4 different mixing ratio of ocean dredged sediment were constructed in Nakdong river estuary, Korea. The reed was transplanted from the adjacent reed community after construction, and then the survival and growth rate of the planted reed was measured. Also the changes of Chemical Oxygen Demand (COD), Ignition loss (IL), and the heterotrophic microbial numbers were monitored. The survival rate of the planted reed decreased as the mixing ratio of dredged sediment increased. The survival rate of reed in the constructed tidal flat with 100% dredged sediment was 54% while that in the tidal flat with 0% dredged sediment (original soil of Nakdong river estuary) was 90%. There was little difference of length and diameter of the reed shoot among the 4 different constructed tidal flats. 30% of COD and 9% of IL in the tidal flat with 100% dredged sediment decreased after 202 day, however, the consistent tendency in the change of COD and IL in the other tidal flats was not found possibly due to the open system. It was suggested that the construction of tidal flats using ocean dredged sediment can be possible considering the growth rate of transplanted reeds and the contaminated ocean dredged sediment might be biologically remediated considering the results of decrease of organic matter and increased heterotrophic microbial number in the tidal flat with 100% dredged sediment. However, the continuous monitoring on the vegetation and various environmental factors in the constructed tidal flats should be necessary to evaluate the success of creation of constructed flats using

  15. The effect of phytostabilization on Zn speciation in a dredged contaminated sediment using scanning electron microscopy, X-ray fluorescence, EXAFS spectroscopy, and principal components analysis

    NASA Astrophysics Data System (ADS)

    Panfili, Frédéric; Manceau, Alain; Sarret, Géraldine; Spadini, Lorenzo; Kirpichtchikova, Tatiana; Bert, Valérie; Laboudigue, Agnès; Marcus, Matthew A.; Ahamdach, Noureddine; Libert, Marie-Françoise

    2005-05-01

    The maintenance of waterways generates large amounts of dredged sediments, which are deposited on adjacent land surfaces. These sediments are often rich in metal contaminants and present a risk to the local environment. Understanding how the metals are immobilized at the molecular level is critical for formulating effective metal containment strategies such as phytoremediation. In the present work, the mineralogical transformations of Zn-containing phases induced by two graminaceous plants (A grostis tenuis and Festuca rubra) in a contaminated sediment ([Zn] = 4700 mg kg -1, [P 2O 5] = 7000 mg kg -1, pH = 7.8), untreated or amended with hydroxylapatite (AP) or Thomas basic slag (TS), were investigated after two yr of pot experiment by scanning electron microscopy coupled with energy-dispersive spectrometry (SEM-EDS), synchrotron-based X-ray microfluorescence (μ-SXRF), and powder and laterally resolved extended X-ray absorption fine structure (μ-EXAFS) spectroscopy. The number and nature of Zn species were evaluated by principal component (PCA) and least-squares fitting (LSF) analysis of the entire set of μ-EXAFS spectra, which included up to 32 individual spectra from regions of interest varying in chemical composition. Seven Zn species were identified at the micrometer scale: sphalerite, gahnite, franklinite, Zn-containing ferrihydrite and phosphate, (Zn-Al)-hydrotalcite, and Zn-substituted kerolite-like trioctahedral phyllosilicate. Bulk fractions of each species were quantified by LSF of the powder EXAFS spectra to linear combinations of the identified Zn species spectra. In the untreated and unvegetated sediment, Zn was distributed as ˜50% (mole ratio of total Zn) sphalerite, ˜40% Zn-ferrihydrite, and ˜10 to 20% (Zn-Al)-hydrotalcite plus Zn-phyllosilicate. In unvegetated but amended sediments (AP and TS), ZnS and Zn-ferrihydrite each decreased by 10 to 20% and were replaced by Zn-phosphate (˜30˜40%). In the presence of plants, ZnS was almost completely

  16. Long-term effects of dredging operations program. Effects of sediment organic-matter composition on bioaccumulation of sediment organic contaminants: Interim results. Final report

    SciTech Connect

    Brannon, J.M.; Price, C.B.; Reilly, F.J.; Pennington, J.C.; McFarland, V.A.

    1991-06-01

    The relationship of sediment-bound polychlorinated biphenyl (PCB) 153 and fluoranthene to bioaccumulation by worms and clams and the relationship of sediment-bound PCB 153 and fluoranthene to concentrations in the interstitial water were examined. Bioaccumulation by both worms and clams was observed in all sediments. Apparent preference factor (APF) values showed that steady state was reached between sediment-bound contaminants and organism lipid pools. The APF values of organisms were close to the theoretical value for both contaminants in all sediments. These results showed that sediment total organic carbon (TOC) in conjunction with octanol water partition coefficients of nonpolar organic contaminants is a viable approach for predicting bioaccumulation of such compounds by infaunal organisms. Actual concentrations of contaminants in interstitial water were either overestimated or underestimated by the relationship between TOC and humic + fulvic acid organic matter fractions and sediment contaminant concentrations. Prediction of interstitial water concentrations was not as successful as use of APFs. The lack of agreement between predicted and actual interstitial water results was due to factors such as the presence of interstitial water contaminants bounds to microparticulates and dissolved organic material and the kind of organic material in the sediment.

  17. Review of technical documents supporting revisions to the portion of EPA (Environmental Protection Agency) ocean-dumping regulations relating to the ocean disposal of dredged materials. Report of the Environmental Engineering Committee. Final report

    SciTech Connect

    Not Available

    1987-01-14

    Although the Committee is in agreement with the EPA that there are significant differences in the properties of most sewage sludge and dredged materials, significant exceptions exist. Clearly defined, consistent, rigorous, and peer-reviewed procedures must exist to identify these exceptions. The EPS Office of Marine and Estuarine Protection maintains that existing procedures for evaluating dredged materials (under Part 227.13) are adequate; however, based on the documents provided to the Committee, a rigorous protocol for identifying exceptions do not appear to exist.

  18. 9. DREDGE ARRANGEMENT ALLOWS FOR TWO DREDGE BASKETS TO BE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. DREDGE ARRANGEMENT ALLOWS FOR TWO DREDGE BASKETS TO BE OUT AT ALTERNATING TIMES. WHILE STARBOARD IS HAULED IN, PORT IS RELEASED OUT TO DREDGE. - KATHRYN-Two-sail Bateau "Skipjack", Dogwood Harbor, Chesapeake Bay, Tilghman, Talbot County, MD

  19. Sixth Season of Hudson River Dredging Begins, Historic Dredging Project Draws to a Close, Next Up: Cleaning Up Floodplains

    EPA Pesticide Factsheets

    (Albany, NY) Today, U.S. Environmental Protection Agency Regional Administrator Judith A. Enck announced the start of the sixth, and final, season of dredging of PCB-contaminated sediments from the bottom of the Hudson River. The historic dredging project

  20. Theoretical Models for Evaluation of Volatile Emissions to Air During Dredged Material Disposal with Applications to New Bedford Harbor, Massachusetts

    DTIC Science & Technology

    1989-05-01

    vIODELS F OR EVAL.UATION OF VOL Fr-,,-0,lS JO AIR DURING DREDGED ,M, -L SrUSAL wiTH APLICATIONS TO D: , .... HARBOR. M,,;ASSACHUSETTS -t-S May 1989...resulted in the release/generation of VOCs to air. Following a section that considers the thermodynamic basis of chemical vapor equi- librium and...branch of the science of thermodynamics . The general criteria for chemical equilibrium as it applies to pollutants in the natural environment are presented

  1. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 of 38-Foot Project). Volume 2, Appendixes I through L

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Kohn, N.P.; Lefkovitz, L.F.

    1992-01-01

    At the request of the US Army Corps of Engineers (USACE), environmental studies were conducted by Battelle/Marine Science Laboratory (MSL) to evaluate the suitability of sediments from Oakland Inner Harbor for dredging and ocean disposal. During the Phase 3 38-Foot Project, sediment cores were collected from mudline to {minus}39 ft mean lower low water at various locations in Oakland Inner Harbor channel and allocated to six composite samples. These composites were evaluated through physical/chemical analyses, acute toxicity to sensitive marine organisms, and bioaccumulation potential. Sediment samples from individual locations were tested for physical/chemical parameters only. The results of toxicological and bioaccumulation testing may be used by USACE to determine the amount of potential dredged material from Oakland Inner Harbor channel acceptable for open-water disposal as defined by the Draft Implementation Manual (EPA/USACE 1990) and consistent with the Water Resources Development Act of 1986 (Public Law 99-662). This is Volume 2 of a two-volume data report that represents the data gathered during the Oakland Harbor Phase 3 38-Foot Project, conducted in the Fall of 1990. This data report does not include interpretation or statistical analysis of the 38-Foot data. Volume 1 includes the project background as well as data and results presented in Appendixes A through H. Volume 2 includes the remaining data presented in Appendixes I through L.

  2. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 of 38-Foot Project). Volume 1, Background and appendixes A through H

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Kohn, N.P.; Lefkovitz, L.F.

    1992-01-01

    At the request of the US Army Corps of Engineering (USACE), environmental studies were conducted by Battelle/Marine Sciences Laboratory (MSL) to evaluate the suitability of sediments from Oakland Inner Harbor for dredging and ocean disposal. During the Phase 3 38-Foot Project, sediment cores were collected from mudline to {minus}39 ft mean lower low water at various locations in Oakland Inner Harbor channel and allocated to six composite samples. These composites were evaluated through physical/chemical analyses, acute toxicity to sensitive marine organisms, and bioaccumulation potential. Sediment samples from individual locations were tested for physical/chemical parameters only. The results of toxicological and bioaccumulation testing may be used by USACE to determine the amount of potential dredged material from Oakland Inner Harbor channel acceptable for open-water disposal as defined by the Draft Implementation Manual (EPA/USACE 1990) and consistent with the Water Resources Development Act of 1986 (Public Law 99-662). This is Volume 1 of a two-volume data report that presents the data gathered during the Oakland Harbor Phase 3 38-Foot Project, conducted in the Fall of 1990. This data report does not include interpretation or statistical analysis of the 38-Foot data. Volume 1 includes the project background as well as a full presentation of data and results in Appendixes A through H. Volume 2 contains the remaining data in Appendixes I through L.

  3. Geotechnical and mineralogical characterisations of marine-dredged sediments before and after stabilisation to optimise their use as a road material.

    PubMed

    Saussaye, L; van Veen, E; Rollinson, G; Boutouil, M; Andersen, J; Coggan, J

    2017-02-15

    Dredging activities to extend, deepen and maintain access to harbours generate significant volumes of waste dredged material. Some ways are investigated to add value to these sediments. One solution described here is their use in road construction following treatment with hydraulic binders. This paper presents the characterisation of four sediments, in their raw state and after 90 days of curing following stabilisation treatment with lime and cement, using a combination of novel and established analytical techniques to investigate subsequent changes in mineralogy. These sediments are classified as fine, moderately to highly organic and highly plastic and their behaviour is linked to the presence of smectite clays. The main minerals found in the sediments using X-ray diffraction (XRD) and automated mineralogy are quartz, calcite, feldspars, aluminium silicates, pyrite and halite. Stabilisation was found to improve the mechanical performances of all the sediments. The formation of cementitious hydrates was not specifically detected using automated mineralogy or XRD. However, a decrease in the percentage volume of aluminium silicates and aluminium-iron silicates and an increase of the percentage volume of feldspars and carbonates was observed.

  4. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 A of -42-foot project). Volume 1, Analyses and discussion

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Lefkovitz, L.F.

    1992-09-01

    The Battelle/Marine Sciences Laboratory (MSL) conducted a study to detemine whether dredged sediments from Oakland Inner and Outer Harbors were, suitable for ocean disposal. Nineteen test treatments, six reference treatments, and control treatments were tested for physical/chemical parameters, water column effects, dredged sediment-toxicity, and bioaccumulation potential. Physical/chemical parameters were analyzed at each site and each composite sediment to a depth of -44 ft MLLW. These parameters included analysis for geological characteristics, conventional sediment measurements (grain size, total volatile solids, total organic carbon, oil and grease, and total petroleum hydrocarbons), metals, polynuclear aromatic hydrocarbons (PAHs), pesticides, butyltins, and polychlorinated biphenyls (PCBs). Physical/chemical data were used in support of the toxicological and bioaccumulation testing, but were not used in the decision-making criteria described iti the Draft Implementation Manual under Tier III testing. To evaluate water column effects, MSL conducted suspended-particulate-phase (SPP) tests using the mysid shrimp Holmesimysis sculpta, speckled sanddab Citharichtys stigmaeus, and larvae of the pacific oyster Crassostrea gigas- Both a 48-h and a 96-h test were performed. The MSL evaluated dredgedsediment toxicity by conducting a total of eight solid-phase toxicity tests using the following organisms: the bivalve clam Macoma nasuta, the polychaste worm Nepthys caecoides, the speckled sanddab C. stigmaeus, and the arnphipod Rhepoxynius abronius. Test duration ranged From 10 to 28 days. Bioaccumulation potential was evaluated in the 28-day M. nasuta and N. caecoides solid-phase exposures by measuring the Contaminants of concern present in their tissues after exposure to test, reference, and control sediments.

  5. Ecological evaluation of proposed discharge of dredged material from Oakland Harbor into ocean waters (Phase 3 A of -42-foot project)

    SciTech Connect

    Ward, J.A.; Word, J.Q.; Pinza, M.R.; Mayhew, H.L.; Barrows, E.S.; Lefkovitz, L.F. )

    1992-09-01

    The Battelle/Marine Sciences Laboratory (MSL) conducted a study to detemine whether dredged sediments from Oakland Inner and Outer Harbors were, suitable for ocean disposal. Nineteen test treatments, six reference treatments, and control treatments were tested for physical/chemical parameters, water column effects, dredged sediment-toxicity, and bioaccumulation potential. Physical/chemical parameters were analyzed at each site and each composite sediment to a depth of -44 ft MLLW. These parameters included analysis for geological characteristics, conventional sediment measurements (grain size, total volatile solids, total organic carbon, oil and grease, and total petroleum hydrocarbons), metals, polynuclear aromatic hydrocarbons (PAHs), pesticides, butyltins, and polychlorinated biphenyls (PCBs). Physical/chemical data were used in support of the toxicological and bioaccumulation testing, but were not used in the decision-making criteria described iti the Draft Implementation Manual under Tier III testing. To evaluate water column effects, MSL conducted suspended-particulate-phase (SPP) tests using the mysid shrimp Holmesimysis sculpta, speckled sanddab Citharichtys stigmaeus, and larvae of the pacific oyster Crassostrea gigas- Both a 48-h and a 96-h test were performed. The MSL evaluated dredgedsediment toxicity by conducting a total of eight solid-phase toxicity tests using the following organisms: the bivalve clam Macoma nasuta, the polychaste worm Nepthys caecoides, the speckled sanddab C. stigmaeus, and the arnphipod Rhepoxynius abronius. Test duration ranged From 10 to 28 days. Bioaccumulation potential was evaluated in the 28-day M. nasuta and N. caecoides solid-phase exposures by measuring the Contaminants of concern present in their tissues after exposure to test, reference, and control sediments.

  6. Contamination Barrier For Contour-Molding Material

    NASA Technical Reports Server (NTRS)

    Adams, James F.

    1988-01-01

    Release agent prevents molding compound from adhering to or contaminating surface. Cleaning agent, Turco 4215 NCLT, forms barrier preventing silicone molding compound from sticking to surface and leaving contaminating residue. Also see MFS-29243.

  7. Environmental effects of dredging: Wetland animal bioassays/biomonitoring. Technical note

    SciTech Connect

    Simmers, J.W.; Kay, S.H.; Rhett, R.G.; Lee, C.R.

    1987-03-01

    This note follows Technical Note EEDP-O3-1 and adds support to the concept of using wetland animals as Indicators of bioavailable contaminants in dredged material used to create intertidal wetlands. The text of this tech note was taken from a paper by Kay, Marquenie, and Simmers (1986). Animal bioassay test procedures are being evaluated (field tested) and verified under the Interagency Field Verification of Testing and Predictive Methodologies for Dredged Material Disposal Alternatives in the Field Verification Program (FVP). Bioassays have been shown to be a relatively simple tool for ecological evaluation and environmental assessment of potential contaminant movement within permanent or temporary wetlands, and with field verification, it will be a useful biomonitoring tool as well.

  8. ECOLOGICAL EVALUATION OF PROPOSED DISCHARGE OF DREDGED MATERIAL INTO OCEAN WATERS; IMPLEMENTATION MANUAL FOR SECTION 103 OF PUBLIC LAW 92-532 (MARINE PROTECTION, RESEARCH, AND SANCTUARIES ACT OF 1972)

    EPA Science Inventory

    According to Section 103 of Public Law 92-532 (Marine Protection ,Research, and Sanctuaries Act of 1972), any proposed dumping of dredged material into ocean waters must be evaluated through the use of criteria published by the Environmental Protection Agency (EPA) i n the Federa...

  9. Methods for removing contaminant matter from a porous material

    DOEpatents

    Fox, Robert V [Idaho Falls, ID; Avci, Recep [Bozeman, MT; Groenewold, Gary S [Idaho Falls, ID

    2010-11-16

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  10. Dredging: Key Link in the Strategic National Defense

    DTIC Science & Technology

    1993-04-15

    Ravenhill and Donald Rothchild, Politics and Society in Contempori.rv Africa. (Boulder, CO: Lynne Riehner Publishers, 1992), 279. 91nternational...Navigation Improvements on the Pacific Coast. Washington: Institute for Water Resources, 1983. Beeman & Associates. 1988. Detailed Study of Dredged Material...Land Disposal Alternatives. Ogden Beeman & Associates, Inc., Portland, Oregon. Beeman & Associates. 1990. Investigation of Dredged Material

  11. Direct comparison of amphipod sensitivities to dredged sediments from Spanish ports.

    PubMed

    Casado-Martinez, M C; Forja, J M; DelValls, T A

    2007-06-01

    The sensitivity of the benthic amphipod species Ampelisca brevicornis and Corophium volutator to dredged sediments was compared through simultaneous testing on the standard 10 days sediment toxicity test. The results of mortality obtained for 22 harbor sediments sampled at several Spanish ports were studied together with the physico-chemical characteristics of the samples to obtain the incidence of toxicity in terms of dredged material categories and to identify possible differences in the amphipod mortality results when using one or another test species. The results showed a similar incidence of toxicity for medium-high and highly contaminated sediments for both amphipod species, similar to that obtained through the comparison of the chemical concentrations measured in sediments with the single limit values used in Spain for dredged material characterization and management. On the contrary, C. volutator presented a higher mortality and a higher incidence of toxicity when exposed to low and medium-low contaminated sediments, which may have been caused by the lower sensitivity of A. brevicornis when exposed to sediments from its natural environment. When compared to other amphipod species used for whole sediment toxicity assessment, both amphipod species used in this study reported slightly higher sensitivities although these differences could have been associated to the different set of chemical compounds considered when characterizing the sediment samples. In this sense, the amphipod mortality results were better predicted through the use of mean quotients than just by comparing the measured chemical concentrations with the single limit values used in Spain, which indicates that the toxic response of both species was caused by the cocktail of contaminants present in the sediments. Finally, the correlation analysis identified a higher association between A. brevicornis mortality and the metallic contaminants while C. volutator was more correlated with the organic

  12. Scrubbing of contaminants from contaminated air streams with aerogel materials with optional photocatalytic destruction

    DOEpatents

    Attia, Yosry A.

    2000-01-01

    Disclosed is a method for separating a vaporous or gaseous contaminant from an air stream contaminated therewith. This method includes the steps of: (a) passing said contaminated air into a contact zone in which is disposed an aerogel material capable of selecting adsorbing said contaminant from air and therein contacting said contaminated air with an aerogel material; and (b) withdrawing from said zone, air depleted of said contaminant. For present purposes, "contaminant" means a material not naturally occurring in ambient air and/or a material naturally occurring in air but present at a concentration above that found in ambient air. Thus, the present invention scrubs (or treats) air for the purpose of returning it to its ambient composition. Also disclosed herein is a process for the photocatalytic destruction of contaminants from an air stream wherein the contaminated air stream is passed into a control cell or contact zone in which is disposed a photocatalytic aerogel and exposing said aerogel to ultraviolet (UV) radiation for photocatalytically destroying the adsorbed contaminant, and withdrawing from said cell an exhaust air stream depleted in said contaminant.

  13. Environmental management for dredging sediments - the requirement of developing nations.

    PubMed

    Manap, Norpadzlihatun; Voulvoulis, Nikolaos

    2015-01-01

    Scientific research has characterized the effects of dredging, an underwater excavation process for navigational purposes or material extraction, and has shown its association with a number of chemical, physical and biological impacts. Due to this, much environmental management has been applied in the dredging industry in order to manage its detrimental effects. However, developing nations may have different approaches towards their dredging environmental management to compare to their companions with higher economic strength. Moreover, scientific evidence to make an informed decision is often lacking, hence affecting the number of research executed at these nations, limiting their efforts to preserve the environment. This paper reviews the dredging environmental impacts and its two important factors, dredging technology and sediment characteristic, that determine the magnitude of impacts through literature review, and discusses the need for a more integrated dredging environmental management to be developed for developing nations.

  14. The Influence of Organic Material and Temperature on the Burial Tolerance of the Blue Mussel, Mytilus edulis: Considerations for the Management of Marine Aggregate Dredging

    PubMed Central

    Cottrell, Richard S.; Black, Kenny D.; Hutchison, Zoë L.; Last, Kim S.

    2016-01-01

    consideration for the role of organic matter and temperature during sedimentation events may lead to an overestimation of the tolerance of benthic species to smothering from dredged material. PMID:26809153

  15. Methods and Metrics for Evaluating Environmental Dredging ...

    EPA Pesticide Factsheets

    This report documents the objectives, approach, methodologies, results, and interpretation of a collaborative research study conducted by the National Risk Management Research Laboratory (NRMRL) and the National Exposure Research laboratory (NERL) of the U.S. Environmental Protection Agency’s (U.S. EPA’s) Office of Research and Development (ORD) and the U.S. EPA’s Great Lakes National Program Office (GLNPO). The objectives of the research study were to: 1) evaluate remedy effectiveness of environmental dredging as applied to contaminated sediments in the Ashtabula River in northeastern Ohio, and 2) monitor the recovery of the surrounding ecosystem. The project was carried out over 6 years from 2006 through 2011 and consisted of the development and evaluation of methods and approaches to assess river and ecosystem conditions prior to dredging (2006), during dredging (2006 and 2007), and following dredging, both short term (2008) and long term (2009-2011). This project report summarizes and interprets the results of this 6-year study to develop and assess methods for monitoring pollutant fate and transport and ecosystem recovery through the use of biological, chemical, and physical lines of evidence (LOEs) such as: 1) comprehensive sampling of and chemical analysis of contaminants in surface, suspended, and historic sediments; 2) extensive grab and multi-level real time water sampling and analysis of contaminants in the water column; 3) sampling, chemi

  16. The effects of dredge-spoil dumping on a shallow water soft-sediment community in the Solitary Islands Marine Park, NSW, Australia.

    PubMed

    Smith, S D; Rule, M J

    2001-11-01

    In December 1999, 28,000 m3 of sediment was dredged from two sites within the harbour at Coffs Harbour, NSW. Dredging was carried out using a trailing suction hopper-dredge which transported the spoil to a shallow (6 m) site within the adjacent Solitary Islands Marine Park for disposal. Evaluation of the effects of the dredge-spoil dumping at the receiving site was conducted by taking replicated van Veen grab samples at the disposal site and at two control sites, before, immediately after, and three months after dumping. The results indicated that dredge-spoil dumping had no detectable effect on either the structure of the invertebrate community or the physical characteristics of sediment at the receiving site. Although there were some significant faunistic differences between samples from the disposal site and the control sites immediately following dumping, these were related to pre-existing differences between sites rather than to the effects of dredge-spoil disposal. Four principal factors are likely to have contributed to the lack of impact: (i) dredged material had similar sedimentary characteristics to those at the receiving site; (ii) dredged material was free from contaminants; (iii) the disposal method systematically distributed a number of shallow layers of sediment over the disposal site and thus motile macrofauna had the opportunity to migrate upwards between passes of the barge; and (iv) the disposal site was in a high energy environment where the resident biota are likely to be adapted to dynamic sedimentary conditions. The lack of detectable effects suggests that the disposal strategy was one which minimized impacts within an area which has high conservation value and should thus be adopted as a model for future works within the region.

  17. Determination of contamination character of materials in space technology testing

    NASA Technical Reports Server (NTRS)

    Haynes, D. L.; Coulson, D. M.

    1972-01-01

    The contamination character of selected materials used in space technology testing is presented. Many of these materials contain components that become volatile in a space environment. Most previous data were limited to weight loss or vapor pressure. However, these parameters are not necessarily a direct measure of the contamination character of these materials. Selected materials were exposed to a thermal-vacuum environment, and the degree of contamination was measured by collecting the outgases from these materials on a cold test mirror surface. The degradation of reflectivity of the mirror was measured over a spectral range from 1100 A to 2.5 microns. Half the mirror's surface was also exposed to UV irradiation to determine its effects on the contaminative character of the depositing outgases. The amount of deposit per unit area was measured by microbalances mounted near the mirror; the sensor of one microbalance was UV irradiated. A quadrupole mass spectrometer was used to determine the composition of the outgases.

  18. Dredging: Technology and environmental aspects. May 1978-July 1989 (Citations from the Life Sciences Collection data base). Report for May 1978-July 1989

    SciTech Connect

    Not Available

    1989-12-01

    This bibliography contains citations concerning the technology and environmental impacts of dredging. Equipment, including semi-submersible cutter platforms, is described. Sediment movement, factors affecting sediment movement, and the disposal of dredged material, are discussed, and computer models predicting the fate of the dredged materials are considered. The environmental impacts of the dredged areas and the effects of ocean dumping of dredged material are also discussed. (This updated bibliography contains 352 citations, 22 of which are new entries to the previous edition.)

  19. Outgassing study of spacecraft materials and contaminant transport simulations

    NASA Astrophysics Data System (ADS)

    Wong, Chung M.; Labatete-Goeppinger, Aura C.; Fowler, Jesse D.; Easton, Myriam P.; Liu, De-Ling

    2016-09-01

    Contamination control plays an important role in sustaining spacecraft performance. One spacecraft degradation mechanism involves long-term on-orbit molecular outgassing from spacecraft materials. The outgassed molecules may accumulate on thermal control surfaces and/or optics, causing degradation. In this study, we performed outgassing measurements of multiple spacecraft materials, including adhesives, Nylon Velcro, and other assembly materials through a modified ASTM E595 test method. The modified ASTM E595 test had the source and receiver temperature remained at 125°C and 25°C, respectively, but with prolonged outgassing periods of two weeks. The condensable contaminants were analyzed by Fourier Transform Infrared Spectroscopy (FTIR) and Gas Chromatography/Mass Spectrometry (GC/MS) to determine their spectral transmission and chemical composition. The FTIR spectra showed several spacecraft materials, primarily adhesives and potting materials, exhibiting slight absorption from contaminants consisting of hydroxyl groups and carboxylic acids. To gain insight into molecular contaminant transport, simulations were conducted to characterize contaminant accumulation inside a hypothetical space system cavity. The simulation indicated that contaminant molecules bouncing inside the hypothetical payload cavity can lead to deposition on colder surfaces, even though large openings are available to provide venting pathways for escaping to space. The newly established molecular contaminant transport simulation capability holds the promise of providing quantitative guidance for future spacecraft and its venting design.

  20. PROCESS OF DECONTAMINATING MATERIAL CONTAMINATED WITH RADIOACTIVITY

    DOEpatents

    Overholt, D.C.; Peterson, M.D.; Acken, M.F.

    1958-09-16

    A process is described for decontaminating metallic objects, such as stainless steel equipment, which consists in contacting such objects with nltric acid in a concentration of 35 to 60% to remove the major portion of the contamination; and thereafter contacting the partially decontaminated object with a second solution containing up to 20% of alkali metal hydroxide and up to 20% sodium tartrate to remove the remaining radioactive contaminats.

  1. Hydrogeologic framework, hydrology, and water quality in the Pearce Creek Dredge Material Containment Area and vicinity, Cecil County, Maryland, 2010-11

    USGS Publications Warehouse

    Dieter, Cheryl A.; Koterba, Michael T.; Zapecza, Otto S.; Walker, Charles W.; Rice, Donald E.

    2013-01-01

    In 2009, to support an evaluation of the feasibility of reopening the Pearce Creek Dredge Material Containment Area (DMCA) in Cecil County, Maryland, for dredge-spoil disposal, the U.S. Geological Survey (USGS) began to implement a comprehensive study designed to improve the understanding of the hydrogeologic framework, hydrology, and water quality of shallow aquifers underlying the DMCA and adjacent communities, to determine whether or not the DMCA affected groundwater quality, and to assess whether or not groundwater samples contained chemical constituents at levels greater than maximum allowable or recommended levels established by the U.S. Environmental Protection Agency Safe Drinking Water Act. The study, conducted in 2010-11 by USGS in cooperation with the U.S. Army Corps of Engineers, included installation of observation wells in areas where data gaps led earlier studies to be inconclusive. The data from new wells and existing monitoring locations were interpreted and show the DMCA influences the groundwater flow and quality. Groundwater flow in the two primary aquifers used for local supplies-the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone)-is radially outward from the DMCA toward discharge areas, including West View Shores, the Elk River, and Pearce Creek Lake. In addition to horizontal flow outward from the DMCA, vertical gradients primarily are downward in most of the study area, and upward near the Elk River on the north side of the DMCA property, and the western part of West View Shores. Integrating groundwater geochemistry data in the analysis, the influence of the DMCA is not only a source of elevated concentrations of dissolved solids but also a geochemical driver of redox processes that enhances the mobilization and transport of redox-sensitive metals and nutrients. Groundwater affected by the DMCA is in the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone). Based on minimal data, the water quality

  2. Risk-based decision-making framework for the selection of sediment dredging option.

    PubMed

    Manap, Norpadzlihatun; Voulvoulis, Nikolaos

    2014-10-15

    The aim of this study was to develop a risk-based decision-making framework for the selection of sediment dredging option. Descriptions using case studies of the newly integrated, holistic and staged framework were followed. The first stage utilized the historical dredging monitoring data and the contamination level in media data into Ecological Risk Assessment phases, which have been altered for benefits in cost, time and simplicity. How Multi-Criteria Decision Analysis (MCDA) can be used to analyze and prioritize dredging areas based on environmental, socio-economic and managerial criteria was described for the next stage. The results from MCDA will be integrated into Ecological Risk Assessment to characterize the degree of contamination in the prioritized areas. The last stage was later described using these findings and analyzed using MCDA, in order to identify the best sediment dredging option, accounting for the economic, environmental and technical aspects of dredging, which is beneficial for dredging and sediment management industries.

  3. Materials SIG quantification and characterization of surface contaminants

    NASA Technical Reports Server (NTRS)

    Crutcher, E. Russ

    1992-01-01

    When LDEF entered orbit its cleanliness was approximately a MIL-STD-1246B Level 2000C. Its burden of contaminants included particles from every part of its history including a relatively small contribution from the shuttle bay itself. Although this satellite was far from what is normally considered clean in the aerospace industry, contaminating events in orbit and from processing after recovery were easily detected. The molecular contaminants carried into orbit were dwarfed by the heavy deposition of UV polymerized films from outgassing urethane paints and silicone based materials. Impacts by relatively small objects in orbit could create particulate contaminants that easily dominated the particle counts within a centimeter of the impact site. During the recovery activities LDEF was 'sprayed' with a liquid high in organics and water soluble salts. With reentry turbulence, vibration, and gravitational loading particulate contaminants were redistributed about LDEF and the shuttle bay.

  4. Multicriteria decision analysis to assess options for managing contaminated sediments: Application to Southern Busan Harbor, South Korea.

    PubMed

    Kim, Jongbum; Kim, Suk Hyun; Hong, Gi Hoon; Suedel, Burton C; Clarke, Joan

    2010-01-01

    Many years of untreated effluent discharge from residential areas, a shipyard, a marina, and a large fish market resulted in substantial contamination of bottom sediment in Southern Busan Harbor, South Korea. Contaminants in these sediments include heavy metals and organic compounds. Newly introduced regulations for ocean disposal of dredged material in South Korea pose significant challenges, because the previous practice of offshore disposal of contaminated dredged material was no longer possible after August 2008. The South Korean government has mandated that such sediments be assessed in a way that identifies the most appropriate dredged material management alternative, addressing environmental, social, and cost objectives. An approach using multicriteria decision analysis (MCDA) in combination with comparative risk assessment was used as a systematic and transparent framework for prioritizing several dredged sediment management alternatives. We illustrate how MCDA can recognize the multiple goals of contaminated sediment management. Values used in weighting decision criteria were derived from surveys of stakeholders who were sediment management professionals, business owners, or government decision makers. The results of the analysis showed that land reclamation was the preferred alternative among cement-lock, sediment washing, 3 contained aquatic disposal alternatives (one in combination with a hopper dredge), geotextile tubes, solidification, and land reclamation after solidification treatment. Land reclamation was the preferred alternative, which performed well across all MCDA objectives, because of the availability of a near-shore confined disposal facility within a reasonable distance from the dredging area.

  5. Geological and geochemical criteria for the continental nature of the Mendeleev Rise (the Arctic Ocean) from the data of drilling and dredging of seabed rock material

    NASA Astrophysics Data System (ADS)

    Morozov, Andrey; Petrov, Oleg; Kremenetskiy, Alexander; Kashubin, Sergey; Rekant, Pavel; Gusev, Eugene; Shokalskiy, Sergey; Shevchenko, Sergey; Sergeev, Sergey; Artyushkov, Eugene

    2013-04-01

    The results are presented of geological and geophysical studies on the Mendeleev Rise at 10 test sites at 79°N to 83°N (expedition "Arktika-2012" in August-September 2012). During the expedition, for the first time, three boreholes were drilled in the bedrocks of the Mendeleev Rise basement at a depth of 1700-2600 m, and more than 20 thousand fragments of seabed rock material were dredged. Among them carbonate-bearing rocks including dolomite with relicts of trilobites and ostracoderms (D3-C) constitute up 65 %. Up to 20% are terrigenous rocks with a predominance of quartz sandstones. Magmatic rocks constitute 10-15% of the samples (including 8% of gabbro-dolerite and 2 % of granite) with 5% of metamorphic rocks. The boreholes revealed magmatic mafic rocks of basalt to basaltic andesite to trachyandesite series (SiO2-48-58% K2O+Na2O-3,4-9,2%) including epigenically altered volcanic breccias. All fragments of magmatic mafic rocks have a similar mineral and chemical composition and are grouped with gabbro dolerite (SiO2-49-51%, K2O+Na2O-2,5-3,0%). Preliminary results of mineralogic, geochemical and of isotopic geochemical (ICP-OEC, ICP-MS, RFA, Sm-Nd, Rb-Sr, EPMA and others) analyses suggest the continental nature of the studied rocks and show a distinct difference from rocks of the Gakkel Ridge in the Eurasian part of the ocean, which are of the oceanic origin. U-Pb dating of zircons from the core rocks and seabed rock material (SIMS SHRIMP II) indicate a wide range of their formation age: 2940-995, 639-385 and 303-203 Ma and thus suggest that they belong to volcanogenic terrigeneous carbonate-bearing bed of the ancient platform composing the floor of Amerasian part of the Arctic Ocean.

  6. 75 FR 22524 - Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of the Siuslaw River...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-29

    ... disposal location during disposal. This method of release is expected to spread material at the Sites to... suspended by wave action near the seafloor. The Sites are not expected to change these characteristics....

  7. 75 FR 5708 - Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of the Siuslaw River...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-04

    ... disposal. This method of release is expected to spread material at the Sites to minimize mounding and to... action near the seafloor. The proposed Sites are not expected to change these characteristics....

  8. Characterization of Underwater Sounds Produced by Trailing Suction Hopper Dredges During Sand Mining and Pump-out Operations

    DTIC Science & Technology

    2014-03-01

    that hydraulically remove sediment from the seafloor through dragheads. The dragheads are “trailed” beneath the dredge and held in contact with the...substrate as the dredge advances. Large suction pumps transport the sediment from the seafloor and deposit the dredged material into one or more... seafloor ; 2) sounds produced by suction pipes and pumps, and the movement of dredged material through the dragarm riser to the hopper; 3) deposition sounds

  9. Controlling Beryllium Contaminated Material And Equipment For The Building 9201-5 Legacy Material Disposition Project

    SciTech Connect

    Reynolds, T. D.; Easterling, S. D.

    2010-10-01

    This position paper addresses the management of beryllium contamination on legacy waste. The goal of the beryllium management program is to protect human health and the environment by preventing the release of beryllium through controlling surface contamination. Studies have shown by controlling beryllium surface contamination, potential airborne contamination is reduced or eliminated. Although there are areas in Building 9201-5 that are contaminated with radioactive materials and mercury, only beryllium contamination is addressed in this management plan. The overall goal of this initiative is the compliant packaging and disposal of beryllium waste from the 9201-5 Legacy Material Removal (LMR) Project to ensure that beryllium surface contamination and any potential airborne release of beryllium is controlled to levels as low as practicable in accordance with 10 CFR 850.25.

  10. Emergency department management of patients internally contaminated with radioactive material

    SciTech Connect

    Kazzi, Ziad; Buzzell, Jennifer; Bertelli, Luiz; Christensen, Doran

    2014-11-15

    After a radiation emergency that involves the dispersal of radioactive material, patients can become externally and internally contaminated with one or more radionuclides. Internal contamination can lead to the delivery of harmful ionizing radiation doses to various organs and tissues or the whole body. The clinical consequences can range from acute radiation syndrome (ARS) to the long term development of cancer. Estimating the amount of radioactive material absorbed into the body can guide the management of patients. Treatment includes, in addition to supportive care and long term monitoring, certain medical countermeasures like Prussian blue, Calcium DTPA and Zinc DTPA.

  11. Interpretative Analysis of Surficial Sediments as an Aid in Transport Studies of Dredged Materials Cape Canaveral, Florida.

    DTIC Science & Technology

    1984-03-01

    of Cocoa leech, nornda, to 40-55 ft of uster, on the inner continental shelf. Drefte isposal material io composed of clay, silt, ad fine send remved...of Cape Canaveral and 4.5 miles east of Cocoa Beach, Florida (Site B, Figure 1), has been in use since 1974. During the past 9 years, approximately...and direction diagrams, calculated for Cocoa Beach for the 10-year period (1945-1947 and 1950-1958), were located on project plansheets (SM 1979). A

  12. 26. Plutonium Recovery From Contaminated Materials, Architectural Elevations, Sections & ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    26. Plutonium Recovery From Contaminated Materials, Architectural Elevations, Sections & Dets., Building 232-Z, U.S. Atomic Energy Commission, Hanford Atomic Products Operation, General Electric Company, Dwg. No. H-2-23106, 1959. - Plutonium Finishing Plant, Waste Incinerator Facility, 200 West Area, Richland, Benton County, WA

  13. 25. Plutonium Recovery From Contaminated Materials, Architectural Plans & Details, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    25. Plutonium Recovery From Contaminated Materials, Architectural Plans & Details, Building 232-Z, U.S. Atomic Energy Commission, Hanford Atomic Products Operation, General Electric Company, Dwg. No. H-2-23105, 1959. - Plutonium Finishing Plant, Waste Incinerator Facility, 200 West Area, Richland, Benton County, WA

  14. LAND TREATMENT OF TWO PLATEAU MATERIALS CONTAMINATED WITH PAHS

    EPA Science Inventory

    This study was designed to evaluate several treatments for their ability to enhance the biological removal of polycyclic aromatic hydrocarbons (PAHs) from contaminated soil and sediment. Previously land-treated material was used to test the treatments in a 13 week bench scale stu...

  15. Acoustic mapping of the regional seafloor geology in and around Hawaiian ocean dredged-material disposal sites

    USGS Publications Warehouse

    Torresan, Michael E.; Gardner, James V.

    2000-01-01

    During January and February 1998 the U.S. Geological Survey Coastal and Marine Geology Team (USGS) conducted regional high-resolution multibeam mapping surveys of the area surrounding EPA-designated ocean disposal sites located offshore of the Hawaiian Islands of Oahu, Kauai, Maui, and Hawaii. The sites are all located within 5 nautical miles of shore on insular shelves or slopes. Regional maps were required of areas much larger than the disposal sites themselves to assess both the regional seafloor geology and the immediate vicinity of the disposal sites. The purpose of the disposal site surveys was to delimit the extent of disposal material by producing detailed bathymetric and backscatter maps of the seafloor with a ± 1 m spatial accuracy and <1% depth error. The advantage of using multibeam over conventional towed, single-beam sidescan sonar is that the multibeam data are accurately georeferenced for precise location of all imaged features. The multibeam produces a coregistered acoustic-backscatter map that is often required to locate individual disposal deposits. These data were collected by the USGS as part of its regional seafloor mapping and in support of ocean disposal site monitoring studies conducted in cooperation with the US Environmental Protection Agency (EPA) and the US Army Corps of Engineers (COE).

  16. Rapid Development of Microbial Strains for Bioremediation of Military Soils and Dredged Materials Contaminated with Polycyclic Aromatic Hydrocarbons.

    DTIC Science & Technology

    1993-09-01

    products . Wh PWR 1D OW RECYCLED PAPER Technical Report EL-93-18 September 1993 Rapid Development of Microbial Strains for Bioremediation of Military Soils... examined . Objectives The study had the following objectives: (a) to develop a technology to rapidly obtain native microorganisms or consrotia with the...are also found in emissions from automobile exhausts and power production , in soils from gas manufacturing plants (Erickson, Loehr, and Neuhauser

  17. Behavior of radioactive materials and safety stock of contaminated sludge.

    PubMed

    Tsushima, Ikuo

    2017-01-28

    The radioactive fallout from the Fukushima Dai-ichi nuclear power plant disaster in 2011 has flowed into and accumulated in many wastewater treatment plants (WWTPs) via sewer systems; this has had a negative impact on WWTPs in eastern Japan. The behavior of radioactive materials was analyzed at four WWTPs in the Tohoku and Kanto regions to elucidate the mechanism by which radioactive materials are concentrated during the sludge treatment process from July 2011 to March 2013. Furthermore, numerical simulations were conducted to study the safe handling of contaminated sewage sludge stocked temporally in WWTPs. Finally, a dissolution test was conducted by using contaminated incinerated ash and melted slag derived from sewage sludge to better understand the disposal of contaminated sewage sludge in landfills. Measurements indicate that a large amount of radioactive material accumulates in aeration tanks and is becoming trapped in the concentrated sludge during the sludge condensation process. The numerical simulation indicates that a worker's exposure around contaminated sludge is less than 1 µSv/h when maintaining an isolation distance of more than 10 m, or when shielding with more than 20-cm-thick concrete. The radioactivity level of the eluate was undetectable in 9 out of 12 samples; in the remaining three samples, the dissolution rates were 0.5-2.7%.

  18. Method for removing hydrocarbon contaminants from solid materials

    DOEpatents

    Bala, Gregory A.; Thomas, Charles P.

    1995-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  19. Apparatus for removing hydrocarbon contaminants from solid materials

    DOEpatents

    Bala, Gregory A.; Thomas, Charles P.

    1996-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  20. Apparatus for removing hydrocarbon contaminants from solid materials

    DOEpatents

    Bala, G.A.; Thomas, C.P.

    1996-02-13

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  1. Method for removing hydrocarbon contaminants from solid materials

    DOEpatents

    Bala, G.A.; Thomas, C.P.

    1995-10-03

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  2. Ocean Dredged Material Disposal Site (ODMDS) Authorization and Short-Term FATE (STFATE) Model Analysis: 2014-2015 Working Group Findings Report

    DTIC Science & Technology

    2016-03-01

    engineering, geospatial sciences, water resources, and environmental sciences for the Army, the Department of Defense, civilian agencies, and our... waters of the United States and ocean waters is a shared responsibility of the USACE and U.S. Environmental Protection Agency (USEPA) under the Marine...Protection, Research, and Sanctuaries Act (MPRSA, also called the Ocean Dumping Act) and the Clean Water Act (CWA). Dredged sediments placed

  3. Polyethylene passive samplers to determine sediment-pore water distribution coefficients of persistent organic pollutants in five heavily contaminated dredged sediments.

    PubMed

    Charrasse, Benoit; Tixier, Céline; Hennebert, Pierre; Doumenq, Pierre

    2014-02-15

    Pore concentration and partition coefficients of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were determined in sediments from five distinct contaminated sites in France (marine harbour, rivers canals and highway sedimentation tank). The assessment of the risk caused by such micropollutants requires, in most cases, the measurement of their availability. To assess this availability, low density polyethylene (LDPE) membrane samplers were exposed to these sediments under constant and low-level agitation over a period of 46 days. Freely dissolved pore water contaminant concentrations were estimated from the concentration at equilibrium in the LDPE membrane. The depletion of contaminants in the sediments was monitored by the use of performance reference compounds (PRCs). Marked differences in freely dissolved PAH and PCB concentrations and resulting sediment-pore water partition coefficients between these five sediments were observed. Data set was tested onto different empirical and mechanistic models. As final findings, triple domain sorption (a total organic carbon, black carbon and oil phase model) could model PCB data successfully whereas the best fitting for PAH partitioning was obtained by Raoult's Law model.

  4. Sediment Engineering thru Dredging and with Nature (SETDWN) - Fate of Fines in the Dredging and Placement Process

    DTIC Science & Technology

    2015-05-15

    OUSLEY2, JENNIFER L. COOR3 1. U.S. Army Engineer Research and Development Center, Coastal and Hydraulics Laboratory, 3909 Halls Ferry Road...the natural coastal system. The goal of this study is to determine the percentage of fine material reduction that occurs throughout the dredging...Construction, Inc., and Great Lakes Dredge and Dock, Inc. 117 18/03/2015 10 pp 10 References Ousley, J.D., Kromhout, E., Schrader, M.W

  5. Environmental Variation in Contamination Outgas Testing of a Composite Material

    DTIC Science & Technology

    2009-03-15

    not the same as the ex-situ TML and CVCM measurements determined through ASTM E595 testing.3 The QCM-to-effusion cell orifice view factor (cm2) is...International, West Conshohocken, PA, www.astm.org. 3. ASTM Standard E595 , 2007, "Standard Test Method for Total Mass Loss and Collected Volatile Condensable...can provide a valuable array of outgassing information. 15. SUBJECT TERMS Outgassing, Molecular contamination, Spacecraft materials, Composite, ASTM

  6. Characterization of outgassed contaminants from polymeric spacecraft materials

    NASA Astrophysics Data System (ADS)

    Villahermosa, Randy M.; Joseph, Paul L.

    2004-10-01

    Silicones and polyolefins are versatile polymeric materials that are often used for spacecraft applications but can produce considerable amounts of non-volatile residue (NVR) contamination. Outgassing properties of a commercial off-the-shelf (COTS) polyolefin tubing and GE RTV615 silicone potting, both of which are known to outgas at high levels, were characterized using ASTM E595 testing and infrared (IR) absorption spectroscopy. The total mass loss (TML) values for the polyolefin tubing varied between 1.8 and 2.5%, while the collected volatile condensable material (CVCM) was between 0.7 and 1.2%. The silicone potting had somewhat lower outgassing levels, with TML values between 1.0 and 1.7% and CVCM ranging from 0.7 to 1.3%. IR analysis of the outgassed residue indicates the materials produce NVR contamination through different mechanisms. The polyolefin tubing, which was composed of a hydrocarbon co-polymer mixed with additives, disproportionately outgassed low-weight molecular compounds containing ester functional groups. In contrast, RTV615 outgassing appeared to proceed through the release of shorter chain silicone polymers or oligomers. Combining outgassing test data with the chemical characterization of NVR residue provides a better understanding of contamination processes and will contribute to the development of more efficient mitigation strategies.

  7. Satellite Contamination and Materials Outgassing Knowledgebase - An Interactive Database Reference

    NASA Technical Reports Server (NTRS)

    Green, D. B.; Burns, Dewitt (Technical Monitor)

    2001-01-01

    The goal of this program is to collect at one site much of the knowledge accumulated about the outgassing properties of aerospace materials based on ground testing, the effects of this outgassing observed on spacecraft in flight, and the broader contamination environment measured by instruments on-orbit. We believe that this Web site will help move contamination a step forward, away from anecdotal folklore toward engineering discipline. Our hope is that once operational, this site will form a nucleus for information exchange, that users will not only take information from our knowledge base, but also provide new information from ground testing and space missions, expanding and increasing the value of this site to all. We urge Government and industry users to endorse this approach that will reduce redundant testing, reduce unnecessary delays, permit uniform comparisons, and permit informed decisions.

  8. Contaminant Transport Through Subsurface Material from the DOE Hanford Reservation

    SciTech Connect

    Pace, M.N.; Mayes, M.A.; Jardine, P.M.; Fendorf, S.E.; Nehlhorn, T.L.; Yin, X.P.; Ladd, J.; Teerlink, J.; Zachara, J.M.

    2003-03-26

    Accelerated migration of contaminants in the vadose zone has been observed beneath tank farms at the U.S. Department of Energy's Hanford Reservation. This paper focuses on the geochemical processes controlling the fate and transport of contaminants in the sediments beneath the Hanford tank farms. Laboratory scale batch sorption experiments and saturated transport experiments were conducted using reactive tracers U(VI), Sr, Cs, Co and Cr(VI) to investigate geochemical processes controlling the rates and mechanisms of sorption to Hanford subsurface material. Results indicate that the rate of sorption is influenced by changes in solution chemistry such as ionic strength, pH and presence of competing cations. Sediment characteristics such as mineralogy, iron content and cation/anion exchange capacity coupled with the dynamics of flow impact the number of sites available for sorption. Investigative approaches using a combination of batch and transport experiments will contribute to the conceptual and Hanford vadose zone.

  9. Material Cycles and Chemicals: Dynamic Material Flow Analysis of Contaminants in Paper Recycling.

    PubMed

    Pivnenko, Kostyantyn; Laner, David; Astrup, Thomas F

    2016-11-15

    This study provides a systematic approach for assessment of contaminants in materials for recycling. Paper recycling is used as an illustrative example. Three selected chemicals, bisphenol A (BPA), diethylhexyl phthalate (DEHP) and mineral oil hydrocarbons (MOHs), are evaluated within the paper cycle. The approach combines static material flow analysis (MFA) with dynamic material and substance flow modeling. The results indicate that phasing out of chemicals is the most effective measure for reducing chemical contamination. However, this scenario was also associated with a considerable lag phase (between approximately one and three decades) before the presence of chemicals in paper products could be considered insignificant. While improved decontamination may appear to be an effective way of minimizing chemicals in products, this may also result in lower production yields. Optimized waste material source-segregation and collection was the least effective strategy for reducing chemical contamination, if the overall recycling rates should be maintained at the current level (approximately 70% for Europe). The study provides a consistent approach for evaluating contaminant levels in material cycles. The results clearly indicate that mass-based recycling targets are not sufficient to ensure high quality material recycling.

  10. Genesis Concentrator Target Particle Contamination Mapping and Material Identification

    NASA Technical Reports Server (NTRS)

    Calaway, Michael J.; Rodriquez, M. C.; Allton, J. H.

    2007-01-01

    The majority of surface particles were found to be < 5 microns in diameter with increasing numbers close to the optical resolution limit of 0.3 microns. Acceleration grid EDS results show that the majority of materials appear to be from the SRC shell and SLA materials which include carbon-carbon fibers and Si-rich microspheres in a possible silicone binder. Other major debris material from the SRC included white paint, kapton, collector array fragments, and Al. Image analysis also revealed that SRC materials were also found mixed with the Utah mud and salt deposits. The EDS analysis of the acceleration grid showed that particles < 1 m where generally carbon based particles. Chemical cleaning techniques with Xylene and HF in an ultrasonic bath are currently being investigated for removal of small particles by the Genesis science team as well as ultra-pure water megasonic cleaning by the JSC team [4]. Removal of organic contamination from target materials is also being investigated by the science team with the use of UV-ozone cleaning devices at JSC and Open University [5]. In preparation for solar wind oxygen analyses at UCLA and Open University [1, 2], surface particle contamination on three Genesis concentrator targets was closely examined to evaluate cleaning strategies. Two silicon carbide (Genesis sample # 60001 and 60003) and one chemical vapor deposited (CVD) 13C concentrator target (60002) were imaged and mosaic mapped with optical microscopes. The resulting full target mosaic images and particle feature maps were subsequently compared with non-flight, but flight-like, concentrator targets and sample return capsule (SRC) materials. Contamination found on the flown concentrator acceleration grid was further examined using a scanning electron microscope (SEM). Energy dispersive X-ray spectroscopy (EDS) for particle identification was subsequently compared with the optical images from the flown targets. Figure 1 show that all three targets imaged in this report

  11. Effects of surfactants on the desorption of organic contaminants from aquifer materials. Doctoral thesis

    SciTech Connect

    Brickell, J.L.

    1989-08-01

    The efficiency of removing organic contaminants from groundwater aquifers by the pump and treat process is adversely affected by the retardation of the contaminant's mobility due to adsorption onto aquifer material. The use of surfactants in conjunction with the pump and treat process has the potential for improving contaminant mobility by solubilizing the adsorbed contaminant.

  12. Decontaminating materials used in ground water sampling devices: Organic contaminants

    SciTech Connect

    Parker, L.V.; Ranney, T.A.

    2000-12-31

    In these studies, the efficiency of various decontamination protocols was tested on small pieces of materials commonly used in ground water sampling devices. Three materials, which ranged in ability to sorb organic solutes, were tested: stainless steel (SS), rigid polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE). The test pieces were exposed to two aqueous test solutions: One contained three volatile organic compounds (VOCs) and one nitroaromatic compound, and the other contained four pesticides. Also, three types of polymetic tubing were exposed to pesticide solutions. Generally, the contact times were 10 minutes and 24 hours for sorption and desorption. The contaminants were removed from the nonpermeable SS and the less-sorptive rigid PVC test pieces simply by washing with a hot detergent solution and rinsing with hot water. Additional treatment was required for the PTFE test pieces exposed to the VOCs and for the low-density polyethylene (LDPE) tubing exposed to the pesticide test solution. Solvent rinsing did not improve removal of the three VOCs form the PTFE and only marginally improved removal of the residual pesticides from the LDPE. However, a hot water and detergent wash and rinse followed by oven drying at approximately 105 C was effective for removing the VOCs from the PTFE and substantially reduced pesticide contamination from the LDPE.

  13. The release of lindane from contaminated building materials.

    PubMed

    Volchek, Konstantin; Thouin, Geneviève; Kuang, Wenxing; Li, Ken; Tezel, F Handan; Brown, Carl E

    2014-10-01

    The release of the organochlorine pesticide lindane (γ-hexachlorocyclohexane) from several types of contaminated building materials was studied to assess inhalation hazard and decontamination requirements in response to accidental and/or intentional spills. The materials included glass, polypropylene carpet, latex-painted drywall, ceramic tiles, vinyl floor tiles, and gypsum ceiling tiles. For each surface concentration, an equilibrium concentration was determined in the vapour phase of the surrounding air. Vapor concentrations depended upon initial surface concentration, temperature, and type of building material. A time-weighted average (TWA) concentration in the air was used to quantify the health risk associated with the inhalation of lindane vapors. Transformation products of lindane, namely α-hexachlorocyclohexane and pentachlorocyclohexene, were detected in the vapour phase at both temperatures and for all of the test materials. Their formation was greater on glass and ceramic tiles, compared to other building materials. An empiric Sips isotherm model was employed to approximate experimental results and to estimate the release of lindane and its transformation products. This helped determine the extent of decontamination required to reduce the surface concentrations of lindane to the levels corresponding to vapor concentrations below TWA.

  14. Review of Removal, Containment and Treatment Technologies for Remediation of Contaminated Sediment in the Great Lakes

    DTIC Science & Technology

    1990-12-01

    this report under the thermal technology type are incineration processes, pyrolytic processes, vitrification processes, supercritical and wet air...more expensive. 103. A number of alternative incineration processes are available: fluidized bed, circulating bed combustor, high-temperature slagging...program for hazardous wastes. Incinerators have not been applied to contaminated dredged material to date, but they have been selected for remediation of

  15. Environmental Effects of Dredging Program: Inland Waterways: Proceedings of a National Workshop on the Beneficial Uses of Dredged Material Held in St. Paul, Minnesota on 27-30 October 1987

    DTIC Science & Technology

    1988-11-01

    were graded to match elevations suitable for estuarine vascular plants, and a layer of fine material (mostly sand and silt) was mixed with the...to 30 years! Example: Redbank-Fancher Creeks, CA. A $65 million investment to pro- tect 38,000 acres in the Fresno-Clovis area valued at $3 billion...a long time. We felt that the silt layer was so thick in the designated oyster bed that the seeded shells sank to a level where the spats could not

  16. Impacts of maintenance channel dredging in a northern Adriatic coastal lagoon. II: Effects on macrobenthic assemblages in channels and ponds

    NASA Astrophysics Data System (ADS)

    Ponti, Massimo; Pasteris, Andrea; Guerra, Roberta; Abbiati, Marco

    2009-10-01

    Coastal lagoons are ephemeral habitats whose conservation requires human intervention, such as maintenance dredging of inner channels. Dredging can reduce the abundance of benthic species due to the removal of individuals with the sediment, modify sediment properties, and resuspend fine sediment, nutrients and pollutants, which can lead to eutrophication, hypoxic events and increasing toxicity. Both direct effects in the dredged channel and possible indirect effects in surrounding shallow areas could be expected. This study assesses the effects of the channel maintenance dredging, performed between October 2004 and August 2005, on the invertebrate assemblages both in channels and adjacent ponds in the northern Adriatic coastal lagoon of Pialassa Baiona. The lagoon is affected by eutrophication, chemical and thermal pollution from wastewater treatment and power plants. Three impacted sites were located in the dredged channel and three in the adjacent interconnected shallow water ponds, while three non-impacted sites were located in a channel and in a pond far from the dredged area. Replicate samples were collected from each site one time before and one time after the dredging operations. Despite the extent of the intervention, effects of the dredging on macrobenthic assemblages were detected only within the dredged channel, while in the surrounding ponds no clear and unequivocal effects were found. In particular the dredging could have promoted the increase of the abundance of the polychaete Streblospio shrubsolii in the southern and central parts of the dredged channel and the increase in abundance of the amphipod Corophium insidiosum in the northern side, compared to the controls. Instead, species diversity was reduced in the central and northern parts of the dredged channel. These effects on the macrobenthic invertebrate assemblages could be related to the observed changes of sediment characteristics, contamination and toxicity. Overall, direct effects on benthic

  17. MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT

    SciTech Connect

    M.A. Ebadian, Ph.D.

    2001-01-01

    Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

  18. MAINTAINING ACCESS TO AMERICA'S INTERMODAL PORTS/TECHNOLOGIES FOR DECONTAMINATION OF DREDGED SEDIMENT: NEW YORK/NEW JERSEY HARBOR.

    SciTech Connect

    STERN,E.A.; JONES,K.; DONATO,K.; PAULING,J.D.; SONTAG,J.G.; CLESCERI,N.L.; MENSINGER,M.C.; WILDE,C.L.

    1998-05-01

    One of the greatest drivers for maintaining access to America's Intermodal ports and related infrastructure redevelopment efforts over the next several years will be the control and treatment of contaminated sediments dredged from our nation's waterways. More than 306 million cubic meters (m{sup 3}) (400 million cubic yards [cy]) of sediments are dredged annually from U.S. waterways, and each year close to 46 million m{sup 3} (60 million cy) of this material is disposed of in the ocean (EPA 842-F-96-003). The need to protect our environment against undesirable effects from sediment dredging and disposal practices is gaining increased attention from the public and governmental agencies. Meeting this need is a challenging task not only from the standpoint of solving formidable scientific and engineering problems, but also, and more importantly, from the need to implement complex collaborations among the many different parties concerned with the problem. Some 40 years ago, C.P. Snow pointed out the problems involved in communicating between the two cultures of the sciences and the humanities (Snow, 1993). Today, it is necessary to extend Snow's concept to a multicultural realm with groups that include governmental, industrial, environmental, academic, and the general public communicating in different languages based on widely different fundamental assumptions.

  19. Beneficial use of dredged sediments in public works.

    PubMed

    Zentar, R; Abriak, N E; Dubois, V; Miraoui, M

    2009-07-01

    With the increase in environmental awareness, in combination with a more restrictive legislation, traditional solutions to the management of dredged sediments, such as dumping at sea or disposal to landfills, become more and more inadequate. In order to improve the management of dredged marine sediments, alternative solutions such as beneficial use in civil engineering, manufacture or agriculture have been proposed. Reuse solutions have to fulfil economical, technical and environmental criteria. At present, the proposed solutions are relatively costly and not adaptable to all types of sediments. In particular, fine sediments are difficult to reuse in comparison to sands because of their high water content, the presence of organic matters, their mechanical behaviour and the presence of pollutants in some cases. In this context, this study aims to design a road material that includes dredged fine sediments from a harbour in the north of France. With an initial water content higher than 100%, the first operation consisted in preparing the dredged sediments by reducing its initial water content and, as a consequence, the content of dissolved salts. Then the sediments were characterized and finally a material with the required properties was designed. This material included fine marine sediments, traditional granular materials and hydraulic binders. This paper focuses on the methodology used to design the road material.

  20. Environmental effects of dredging program: Leachate testing of Hamlet City Lake, North Carolina, sediment. Final report

    SciTech Connect

    Brannon, J.M.; Myers, T.E.; Price, C.B.

    1992-11-01

    Sediment leaching studies of Hamlet City Lake, Hamlet, NC, were conducted in laboratories at the U.S. Army Engineer Waterways Experiment Station. The purpose of these studies was to provide quantitative information on the potential for leachate impacts on groundwaters if dredged material from Hamlet City Lake were placed in a confined disposal facility (CDF) or under disposal conditions similar to land-farming. The study involved three elements: batch leach tests, column leach tests, and simulations using the Hydrologic Evaluation of Landfill Performance (HELP) model. Batch tests were conducted to determine intrinsic leaching characteristics of solids in Hamlet City Lake sediment. Column tests were conducted as a physical analog of continuous flow leaching in a CDF. HELP model simulations were conducted to simulate the generation of leachate by infiltration and to evaluate the relative effectiveness of a disposal site liner. Results of this study showed that, under disposal conditions similar to land-farming, organic contaminants such as polycyclic aromatic hydrocarbons (PAHs) and total recoverable petroleum hydrocarbons (TRPHs) will decrease in concentration as the result of volatilization and or biodegradation.... Dredged material, Leachate, Permeameter, Hamlet city lake, Leaching, Heavy metals, Mass transport.

  1. Estuarine dredge and fill activities: A review of impacts

    NASA Astrophysics Data System (ADS)

    Johnston, Sam A.

    1981-09-01

    Dredge and fill activities in estuaries have many environmental effects, most, although not all, of them deleterious. These effects include reduced light penetration by increased turbidity; altered tidal exchange, mixing, and circulation; reduced nutrient outflow from marshes and swamps; increased saltwater intrusion; and creation of an environment highly susceptible to recurrent low dissolved oxygen levels. Coral, oysters, and barnacles are particularly vulnerable to the effects of siltation. Both estuarine flora and fauna may be harmed by contaminants released into the water column by dredging operations. Ways to mitigate the effects of dredge and fill operations include careful pre- and post-construction environmental studies; use of bridging to create roadbeds where coastal wetlands cannot be avoided; use of a turbidity diaper and other means to control turbidity; dredging during periods of low benthic populations or during tides that would carry coarser sediments away from productive areas such as oyster reefs; and thoughtful disposal of spoil, such as locating spoil sites on the uplands with proper diking.

  2. TOXICITY TESTING, RISK ASSESSMENT, AND OPTIONS FOR DREDGED MATRIAL MANAGEMENT

    EPA Science Inventory

    The U.S. Environmental Protection Agency (U.S. EPA), in conjunction with the U.S. Army Corps of Engineers (U.S. ACE), has lead responsibility for developing guidelines that provide environmental criteria for evaluating proposed discharges of dredged material into U.S. waters. To ...

  3. Increased bioavailability of mercury in the lagoons of Lomb, Togo: the possible role of dredging.

    PubMed

    Gnandi, Kissao; Han, Seunghee; Rezaie-Boroon, M Hassan; Porrachia, Magali; Deheyn, Dimitri D

    2011-02-01

    Surface sediments of the lagoons of Lomé, Togo, were analyzed for mercury, methylmercury, and trace elements. Concentrations were greater than typical for natural lagoon sediments, and with greater variability within the Eastern lagoon compared to the Western one. The Eastern lagoon is larger and has been dredged in the past, while the Western lagoon, which also receives major waste inputs, has not been dredged and shows less tidal flushing. Accordingly, one naturally believes that the Eastern lagoon is cleaner and probably safe to use due to its natural resources, including fishes to eat. Unexpectedly, we describe here that mercury methylation was greater in the Eastern lagoon, indicating increased bioavailability of mercury, as probably facilitated by past dredging that decreased solid-phase retention of inorganic mercury. Urbanization has historically been more developed in the southern part of the lagoons, which is still reflected in contamination levels of sediment despite dredging, probably because sources of contamination are still more important there today. Such urban contamination emphasizes the need to regulate waste discharges and possible airborne contamination in growing cities of developing countries, and implements environmental and public health monitoring, especially in relation to misbelieves systematically associated with the cleansing effect of dredging activity.

  4. INVESTIGATION OF CONTACT VACUUMING FOR REMEDIATION OF FUNGALLY CONTAMINATED DUCT MATERIALS

    EPA Science Inventory

    Environmental fungi become a potential Indoor Air Quality (IAQ) problem when adequate moisture and nutrients are present in building materials. Because of their potential to rapidly spread contamination throughout a building, ventilation system materials are of particular signifi...

  5. Organizational change and marine environmental protection: The dredge spoil siting record

    NASA Astrophysics Data System (ADS)

    Burroughs, R. H.

    1991-07-01

    Dredge spoil siting activities are reviewed over a decade to determine whether organizational changes within the Corps of Engineers produced changes in the environmental performance of the agency. Over the period neither the total amount of marine and estuarine dredging nor the incidence of siting spoil inside the baseline declined. Therefore, internal organizational changes do not appear to have affected the above measures of agency performance concerning protection of the marine environment. Furthermore, at least 3% of the spoil is estimated to be highly contaminated. In recent years this magnitude of contaminated spoils has been equivalent to ocean-dumped sewage sludge.

  6. Electrokinetic removal of charged contaminant species from soil and other media using moderately conductive adsorptive materials

    DOEpatents

    Lindgren, Eric R.; Mattson, Earl D.

    2001-01-01

    Method for collecting and concentrating charged species, specifically, contaminant species in a medium, preferably soil. The method utilizes electrokinesis to drive contaminant species into and through a bed adjacent to a drive electrode. The bed comprises a moderately electrically conductive adsorbent material which is porous and is infused with water or other solvent capable of conducting electrical current. The bed material, preferably activated carbon, is easily removed and disposed of. Preferably, where activated carbon is used, after contaminant species are collected and concentrated, the mixture of activated carbon and contaminant species is removed and burned to form a stable and easily disposable waste product.

  7. MAINTAINING ACCESS TO AMERICA'S INTERMODAL PORTS/TECHNOLOGIES FOR DECONTAMINATION OF DREDGED SEDIMENT: NEW YORK/NEW JERSEY HARBOR

    SciTech Connect

    STERN,E.A.; JONES,K.; DONATO,K.; PAULING,J.D.; SONTAG,J.G.; CLESCERI,N.L.; MENSINGER,M.C.; WILDE,C.L.

    1998-05-01

    One of the greatest drivers for maintaining access to America's Intermodal ports and related infrastructure redevelopment efforts over the next several years will be the control and treatment of contaminated sediments dredged from the nation's waterways. More than 306 million cubic meters (m{sup 3}) (400 million cubic yards [cy]) of sediments are dredged annually from US waterways, and each year close to 46 million m{sup 3} (60 million cy) of this material is disposed of in the ocean (EPA 842-F-96-003). The need to protect the environment against undesirable effects from sediment dredging and disposal practices is gaining increased attention from the public and governmental agencies. Meeting this need is a challenging task not only from the standpoint of solving formidable scientific and engineering problems, but also, and more importantly, from the need to implement complex collaborations among the many different parties concerned with the problem. Some 40 years ago, C.P. Snow pointed out the problems involved in communicating between the two cultures of the sciences and the humanities (Snow, 1993). Today, it is necessary to extend Snow's concept to a multicultural realm with groups that include governmental, industrial, environmental, academic, and the general public communicating in different languages based on widely different fundamental assumptions. The handling of contaminated sediments in the Port of New York/New Jersey (Port) exemplifies this problem. This paper describes a multicultural team that has formed as the result of a Congressional mandate for the development of procedures suitable for the decontamination of sediments in the Port under the Water Resources Development Act (WRDA) of 1992 (Section 405C) and 1996 (Section 226).

  8. Transfer of bacteria-contaminated particles in a karst aquifer: evolution of contaminated materials from a sinkhole to a spring

    NASA Astrophysics Data System (ADS)

    Dussart-Baptista, L.; Massei, N.; Dupont, J.-P.; Jouenne, T.

    2003-12-01

    The transport of particle-associated bacteria during rain events in karst waters has been investigated. In this aim, we studied the correlations between water turbidity and enumerations of sessile (attached) and planktonic (non-attached) bacteria. We monitored physicochemical, i.e. turbidity, electrical conductivity, size and nature of the transported particles, and bacteriological properties of waters since their infiltration on a karst plateau to their discharge at a karstic spring. Results showed a decrease of the concentration of sessile bacteria at the sinkhole for high turbidities. This phenomenon might be explained by the arrival of lower contaminated material. On the other hand, the amount of sessile bacteria at the spring was not influenced by the turbidity values. These data demonstrated that slightly contaminated larger particles were not recovered, whereas small-size particles, which exhibited a higher bacterial contamination, were directly transferred (i.e. not affected by intra-karstic deposition) through the aquifer. Our study highlighted some significant differences between the bacteriological time series at the sinkhole and at the spring, which characterizes the storage/resuspension function of the considered karst system. Moreover, we show a decrease of the concentration of planktonic bacteria after transport through the system whereas no reduction of the sessile population occurred. The present data confirm that turbidity does not constitute a good indicator for bacterial contamination: if high turbidity corresponds to high bacterial contamination, low turbidity does not systematically exclude a risk of contamination by sessile organisms.

  9. Treatment of Dredged Sludge By Mechanical Dehydration,

    DTIC Science & Technology

    there is an urgent need to reduce both the volume of dredged sludge and the size of the disposal area. This mechanical method is different from the...conventional engineering dehydration by loading, consolidation, and drainage in that the dredged sludge is separated into sludge cakes and clean water...turbidity in water. This mechanical sludge treatment technique can be most efficient when used in combination with a pump dredge. This method offers

  10. Method and apparatus for heat treating materials to remove contaminants

    SciTech Connect

    Evans, M.; Miller, D.H.

    1980-05-06

    A method and apparatus are disclosed for heat treating metals to remove contaminants. Contaminated scrap metal is fed into one end of a rotating inclined retort. Heat is applied to the retort as the scrap metal is conveyed therein to remove the contaminant, and the processed metal is discharged from the opposite end of the retort. Combustible waste gases generated through the processing are fed to an afterburner where the combustible gases are burned and are discharged from the afterburner into a stack. A portion of the hot combusted gases are returned from the stack to the discharge end of the retort to thereby minimize oxidation of the scrap metal being treated as well as conserving fuel.

  11. Novel Application of Cyclolipopeptide Amphisin: Feasibility Study as Additive to Remediate Polycyclic Aromatic Hydrocarbon (PAH) Contaminated Sediments

    PubMed Central

    Groboillot, Anne; Portet-Koltalo, Florence; Le Derf, Franck; Feuilloley, Marc J. G.; Orange, Nicole; Poc, Cécile Duclairoir

    2011-01-01

    To decontaminate dredged harbor sediments by bioremediation or electromigration processes, adding biosurfactants could enhance the bioavailability or mobility of contaminants in an aqueous phase. Pure amphisin from Pseudomonas fluorescens DSS73 displays increased effectiveness in releasing polycyclic aromatic hydrocarbons (PAHs) strongly adsorbed to sediments when compared to a synthetic anionic surfactant. Amphisin production by the bacteria in the natural environment was also considered. DSS73’s growth is weakened by three model PAHs above saturation, but amphisin is still produced. Estuarine water feeding the dredged material disposal site of a Norman harbor (France) allows both P. fluorescens DSS73 growth and amphisin production. PMID:21673923

  12. Spectroscopic ellipsometry as a sensitive monitor of materials contamination

    NASA Technical Reports Server (NTRS)

    Hale, Jeffrey S.; Hilfiker, James N.; Spady, Blaine; Synowicki, R.; Woollam, John A.

    1995-01-01

    Spectroscopic ellipsometry is demonstrated to be extremely sensitive to contamination layers in the thickness range from 0.1 nm to 10 microns. In the present experiments we deposit either a thin lubricating oil (WD-40) or mineral oil continuously onto Ir, Cu, Al, Au, and V substrates from a bubbler, and monitor its thickness growth from sub-nanometer to tens of nanometers as a function of time. Re-evaporation of contaminant oils is also monitored in real-time by ellipsometry.

  13. Capabilities of the Materials Contamination Team at Marshall Space Flight Center

    NASA Technical Reports Server (NTRS)

    Burns, Howard; Albyn, Keith; Edwards, David; Boothe, Richard; Finchum, Charles; Finckenor, Miria

    2003-01-01

    The Materials Contamination Team at the Marshall Space Flight Center (MSFC) has been recognized for its contributions supporting the National Aeronautics and Space Administration (NASA) spacecraft development programs. These programs include the Reusable Solid Rocket Motor (RSRM), Chandra X-Ray Observatory, and the International Space Station (ISS). The Environmental Effects Group, with the Materials Contamination Team and the Space Environmental Effects Team has been an integral part of NASA's success by the testing, evaluation, and qualification of materials, hardware, and processes. This paper focuses on the capabilities of the Materials Contamination Team. The Materials Contamination Team's realm of responsibility includes establishing contamination control during all phases of hardware development, including design, manufacturing, assembly, test, transportation, launch site processing, on-orbit exposure, return, and refurbishment. The team continues its mission of reducing the risk of equipment failure due to molecular or particulate contamination. Contamination is a concern in the Space Shuttle with sensitive bond-lines and reactive fluid (liquid oxygen) compatibility as well as for spacecraft with sensitive optics, such as Hubble Space Telescope and Chandra X-ray Observatory. The Materials Contamination Team has a variety of facilities and instrumentation capable of contaminant detection, identification, and monitoring. The team addresses material applications dealing with environments, including production facilities, clean rooms, and on-orbit exposure. The optically stimulated electron emission (OSEE) system, the Ultraviolet (UV) fluorescence (UVF) surface contamination detection, and the Surface Optics Corporation 400 (SOC 400) portable hand-held Fourier Transform Infrared (FTIR) spectrometer are state-of-the-art tools for in-process molecular contamination detection. The team of engineers and technicians also develop contamination calibration standards

  14. BUILDING MATERIAL CHARACTERIZATION USING A CONCRETE FLOOR AND WALL CONTAMINATION PROFILING TECHNOLOGY

    SciTech Connect

    Aggarwal, Dr. S.,; Charters, G.; Thacker, Dr. D.

    2003-02-27

    Certain radioisotopes can penetrate concrete and contaminate the concrete well below the surface. The challenge is to determine the extent and magnitude of the contamination problem in real-time. The concrete profiling technology, TRUPROSM in conjunction with portable radiometric instrumentation produces a profile of radiological or chemical contamination through the material being studied. The data quality, quantity, and representativeness may be used to produce an activity profile from the hot spot surface into the material being sampled. This activity profile may then be expanded to ultimately characterize the facility and expedite waste segregation and facility closure at a reduced cost and risk. Performing a volumetric concrete or metal characterization safer and faster (without lab intervention) is the objective of this characterization technology. This way of determining contamination can save considerable time and money. Currently, concrete core bores are shipped to certified laboratories where the concrete residue is run through a battery of tests to determine the contaminants. The existing core boring operation volatilizes or washes out some of the contaminants (like tritium) and oftentimes cross-contaminates the area around the core bore site. The volatilization of the contaminants can lead to airborne problems in the immediate vicinity of the core bore. Cross-contamination can increase the contamination area and thereby increase the amount of waste generated. The goal is to avoid those field activities that could cause this type of release.

  15. Commencement Bay Nearshore/Tideflats Superfund Site, Tacoma, Washington Remedial Investigations. Decisionmaking Framework for Management of Dredged Material: Application to Commencement Bay, Washington. Methods and Sites, and Site Control and Treatment Practices.

    DTIC Science & Technology

    1985-02-01

    should be utilized to test effects on a finfish, a crustacean , a mollusk, and an annelid acceptable to all local interests as sufficiently sensitive...harmless contaminated material disposed in the ocean . The physical means are essentially to seal or sequester the unacceptable material from the aquatic...conditions, planting vegetation to stabilize the surface, liming the surface to prevent acidification and to reduce dis- * solution, covering the

  16. Effect of artificial saliva contamination on adhesion of dental restorative materials.

    PubMed

    Shimazu, Kisaki; Karibe, Hiroyuki; Ogata, Kiyokazu

    2014-01-01

    The purpose of this study was to evaluate the effects of artificial saliva contamination on three restorative materials, namely, a glass ionomer cement (GIC), a resin-modified GIC (RMGIC), and a composite resin (CR), for which two different etching adhesive systems were used. Thus, three surface conditions were created on bovine teeth using artificial saliva: control, mild saliva contamination, and severe saliva contamination. The dentin bond strength for CR was significantly lower after artificial saliva contamination. There were, however, no significant differences among the three surface conditions in terms of the dentin and enamel bond strengths of GIC and RMGIC. Moreover, CR exhibited significantly greater microleakage after artificial saliva contamination, whereas no significant differences were found in GIC and RMGIC. The results showed that artificial saliva contamination did not affect the shear bond strengths of GIC and RMGIC or their degrees of microleakage.

  17. Effects of dredged sediment disposal on the coastal marine macrobenthic assemblage in Southern Brazil.

    PubMed

    Angonesi, L G; Bemvenuti, C E; Gandra, M S

    2006-05-01

    The aim of this study was to evaluate the deposition impact of dredged material from Patos lagoon estuary on a benthic macroinvertebrate assemblage structure in an adjacent coastal marine area. Nine sampling stations were chosen at random in the disposal area, and nine others in the same way in an adjacent control area. Samples were collected at a 19 m depth before sediment disposal (11 July 2000), during dredging and disposal operations (25 Oct. 2000), and three months thereafter (24 Aug. 2001). Statistical analysis indicated that sampling periods presented similar characteristics in both the control and disposal sites. Disposal of dredged sediment from Patos lagoon had no detectable detrimental effects upon macrobenthic faunal assemblage at the dumping site. This result is attributed both to adaptation of resident biota to dynamic sedimentary conditions and to the fine estuarine sediment dredged, the dispersion of which in the water column might have minimized sediment deposition and consequent damage to the benthic fauna.

  18. Characterization and Removal of Deposited Surface Contamination on Materials for Use in Low-Background Environments

    NASA Astrophysics Data System (ADS)

    Larson, Alex; Khizar, Muhammad; Mei, Dongming; Cubed Collaboration

    2013-10-01

    Materials used in Low-Background experiments, such as PTFE and Germanium crystals, require high levels of cleanliness to avoid false positives and noise in experiments. The storage and standard process of preparing these materials for use causes this contamination, such as organic material from photoresist treatment of germanium samples or dust from the environment. The purpose of this study is to determine the most effective way to remove these surface contaminants from the materials through the development of certain procedures for use with each material. The procedures use a combination of treatment techniques involving the use of acids, bases, oxidizers, and solvents. These different procedures target certain contaminants, such as removing surface grease and oxidizing and removing organic films. Testing the different procedures with contaminated samples of material and analyzing the result yields the most cost and time effective methods for cleaning these materials. The number of particles counted on the surface before and after the cleaning procedure determines the effectiveness of the procedure for a given material. In this project I have discovered a method that can reach near 100% particulate removal from PTFE for levels of contamination from a normal lab environment.

  19. Application of Bioassays in Toxicological Hazard, Risk and Impact Assessment of Dredged Sediments

    EPA Science Inventory

    Given the potential environmental consequences of dumped dredged harbour sediments it is vital to establish the potential risks from exposure before disposal at sea. Currently, European legislation for disposal of contaminated sediments at sea is based on chemical analysis of a l...

  20. Ultraviolet stability and contamination analysis of Spectralon diffuse reflectance material

    NASA Technical Reports Server (NTRS)

    Stiegman, Albert E.; Bruegge, Carol J.; Springsteen, Arthur W.

    1993-01-01

    A detailed chemical analysis was carried out on Spectralon, a highly Lambertian, diffuse reflectance material. Results of this investigation unambiguously identified the presence of an organic (hydrocarbon) impurity intrinsic to the commercial material. This impurity could be removed by a vacuum bake-out procedure and was identified as the cause of optical changes (degradation) that occur in the material when exposed to UV light. It was found that when this impurity was removed, the Spectralon material was photochemically stable and maintained its reflectance properties even after extensive solar UV exposure.

  1. Admixture enhanced controlled low-strength material for direct underwater injection with minimal cross-contamination

    SciTech Connect

    Hepworth, H.K.; Davidson, J.S.; Hooyman, J.L.

    1997-03-01

    Commercially available admixtures have been developed for placing traditional concrete products under water. This paper evaluates adapting anti-washout admixture (AWA) and high range water reducing admixture (HRWRA) products to enhance controlled low-strength materials (CLSMs) for underwater placement. A simple experimental scale model (based on dynamic and geometric similitude) of typical grout pump emplacement equipment has been developed to determine the percentage of cementing material washed out. The objective of this study was to identify proportions of admixtures and underwater CLSM emplacement procedures which would minimize the cross-contamination of the displaced water while maintaining the advantages of CLSM. Since the displaced water from radioactively contaminated systems must be subsequently treated prior to release to the environment, the amount of cross-contamination is important for cases in which cementing material could form hard sludges in a water treatment facility and contaminate the in-place CLSM stabilization medium.

  2. Dredging Operations Technical Support Program. Update of the Corps’ Environmental Effects of Dredging Programs (FY 89)

    DTIC Science & Technology

    1990-02-01

    B. L., Jr., Lee, C. R., and Bates, D. J. 1981. "Field Survey of Heavy Metal Uptake by Naturally Occurring Saltwater and Freshwater Marsh Plants...on Availability and Plant Uptake of Heavy Metals in Dredged Material," Technical Report EL-81-12, US Army Engineer Waterways Experiment Station... Metal Uptake of and of Agronomic Plants Grown on Contami- nated Dutch Sediments," Miscellaneous Paper D-83-1, Institute for Soil Fer- tility, 8, Fhe

  3. Assessment of Filter Materials for Removal of Contaminants From Agricultural Drainage Waters

    NASA Astrophysics Data System (ADS)

    Allred, B. J.

    2007-12-01

    Fertilizer nutrients and pesticides applied on farm fields, especially in the Midwest U.S., are commonly intercepted by buried agricultural drainage pipes and then discharged into local streams and lakes, oftentimes resulting in an adverse environmental impact on these surface water bodies. Low cost filter materials have the potential to remove nutrient and pesticide contaminants from agricultural drainage waters before these waters are released from the farm site. Batch tests were conducted to find filter materials potentially capable of removing nutrient (nitrate and phosphate) and pesticide (atrazine) contaminants from subsurface drainage waters. For each batch test, stock solution (40 g) and filter material (5 g) were combined in 50 mL Teflon centrifuge tubes and mixed with a rotator for 24 hours. The stock solution contained 50 mg/L nitrate-N, 0.25 mg/L phosphate-P, 0.4 mg/L atrazine, 570 mg/L calcium sulfate, and 140 mg/L potassium chloride. Calcium sulfate and potassium chloride were added so that the stock solution would contain anions and cations normally found in agricultural drainage waters. There were six replicate batch tests for each filter material. At the completion of each test, solution was removed from the centrifuge tube and analyzed for nitrate-N, phosphate-P, and atrazine. A total of 38 filter materials were tested, which were divided into five classes; high carbon content substances, high iron content substances, high aluminum content substances, surfactant modified clay/zeolite, and coal combustion products. Batch test results generally indicate, that with regard to the five classes of filter materials; high carbon content substances adsorbed atrazine very effectively; high iron content substances worked especially well removing almost all of the phosphate present; high aluminum content substances lowered phosphate levels; surfactant modified clay/zeolite substantially reduced both nitrate and atrazine; and coal combustion products

  4. Pentachlorophenol and phenanthrene biodegradation in creosote contaminated aquifer material.

    PubMed

    Mohammed, S A; Sorensen, D L; Sims, R C; Sims, J L

    1998-07-01

    Contamination of the subsurface environment at the Libby Superfund Site, Montana, includes polycyclic aromatic hydrocarbons and f1p4achlorophenol due to accidental spills and improper disposal of wood preserving wastes. Biodegradation is a treatment technology gaining wide application in the treatment of hazardous waste sites. A microcosm study was conducted to evaluate the effect of temperature, sampling depth, nutrient addition, and oxygen on the biodegradation potential of phenanthrene and pentachlorophenol in aquifer samples using radiolabeled chemicals. Mineralization of phenanthrene reached 14% but was less than 1% for pentachlorophenol over the 56 day incubation period. Phenanthrene mineralization in microcosms at 10 degrees C was not significantly different from those at 20 degrees C. This may have been due to microbial community acclimation to lower temperatures at the site. Average volatilization was less than 2% for both phenanthrene and pentachlorophenol. After 56 days, most of the radiolabeled chemical was either solvent extractable or soil bound.

  5. Capabilities of the Materials Contamination Team at Marshall Space Flight Center

    NASA Technical Reports Server (NTRS)

    Burns, H. D.; Finckenor, M. M.; Boothe, R. E.; Albyn, K. C.; Finchum, C. A.

    2003-01-01

    The Materials Contamination Team of the Environmental Effects Group, Materials, Processes, and Manufacturing Department, has been recognized for its contribution to space flight, including space transportation, space science and flight projects, such as the reusable solid rocket motor, Chandra X-Ray Observatory, and the International Space Station. The Materials Contamination Team s realm of responsibility encompasses all phases of hardware development including design, manufacturing, assembly, test, transportation, launch-site processing, on-orbit exposure, return, and refurbishment if required. Contamination is a concern in the Space Shuttle with sensitivity bondlines and reactive fluid (liquid oxygen) compatibility as well as for sensitive optics, particularly spacecraft such as Hubble Space Telescope and Chandra X-Ray Observatory. The Materials Contamination Team has a variety of facilities and instrumentation capable of contaminant detection identification, and monitoring. The team addresses material applications dealing with environments, including production facilities, clean rooms, and on-orbit exposure. The team of engineers and technicians also develop and evaluates new surface cleanliness inspection technologies. Databases are maintained by the team for proces! materials as well as outgassing and optical compatibility test results for specific environments.

  6. Hospital preparedness for hazardous materials incidents and treatment of contaminated patients.

    PubMed Central

    Burgess, J L; Blackmon, G M; Brodkin, C A; Robertson, W O

    1997-01-01

    Hospital-based facilities providing emergency care in the state of Washington were surveyed to determine their level of preparedness for hazardous materials incidents including the treatment of contaminated patients. Responses to a faxed questionnaire were received from 95 (94%) of the 101 emergency care facilities in Washington State. Only 42 (44%) of the facilities reported the ability to receive any chemically exposed patient. Of the 95 responding emergency care facilities, 39 (41%) had no designated decontamination facilities; 67 (70%) had protocols for handling chemical contamination and possible evacuation from hazardous materials spills, and 52 (55%) had protocols for handling medical facility contamination and possible evacuation from treating chemically contaminated patients. Twelve (13%) facilities had evacuated their emergency department or other part of the hospital for contamination incidents in the past 5 years. Despite the frequent occurrence of hazardous materials incidents, most emergency care facilities in Washington State are not fully prepared to handle contaminated patients and chemical spills. This may have important implications for the care of persons with exposure to hazardous materials and for implementing Joint Commission on Accreditation of Healthcare Organizations standards and federal Occupational Safety and Health Administration regulations. PMID:9426476

  7. Combustion aerosols formed during burning of radioactively contaminated materials: Experimental results

    SciTech Connect

    Halverson, M.A.; Ballinger, M.Y.; Dennis, G.W.

    1987-03-01

    Safety assessments and environmental impact statements for nuclear fuel cycle facilities require an estimate of potential airborne releases. Radioactive aerosols generated by fires were investigated in experiments in which combustible solids and liquids were contaminated with radioactive materials and burned. Uranium in powder and liquid form was used to contaminate five fuel types: polychloroprene, polystyrene, polymethylmethacrylate, cellulose, and a mixture of 30% tributylphosphate (TBP) in kerosene. Heat flux, oxygen concentration, air flow, contaminant concentration, and type of ignition were varied in the experiments. The highest release (7.1 wt %) came from burning TBP/kerosene over contaminated nitric acid. Burning cellulose contaminated with uranyl nitrate hexahydrate liquid gave the lowest release (0.01 wt %). Rate of release and particle size distribution of airborne radioactive particles were highly dependent on the type of fuel burned.

  8. Laboratory comparison of four iron-based filter materials for water treatment of trace element contaminants

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A laboratory investigation was conducted to evaluate four iron-based filter materials for trace element contaminant water treatment. The iron-based filter materials evaluated were zero valent iron (ZVI), porous iron composite (PIC), sulfur modified iron (SMI), and iron oxide/hydroxide (IOH). Only fi...

  9. TOOLS FOR ASSESSING MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS

    EPA Science Inventory

    Management of contaminated sediments poses many challenges due to varied contaminants and volumes of sediments to manage. dredging, capping, and monitored natural recovery (MNR) are the primary approaches at this time for managing contaminated sediment risks. Understanding how we...

  10. Novel materials for environmental remediation of oil sands contaminants.

    PubMed

    Wilson, Lee D; Mohamed, Mohamed H; Headley, John V

    2014-01-01

    The incorporation of β-cyclodextrin (β-CD) within the framework structure of copolymer sorbent materials, represents a novel modular design approach with significant potential for controlled tuning of the textural mesoporosity of such sorbent frameworks. β-CD copolymers represent an innovative design strategy for the development of "smart" or "functional" porous materials with improved solid phase extraction (SPE) and molecular recognition properties because of the porogen characteristics and their unique host-guest properties. Carbohydrate-based copolymers containing cyclodextrins (CDs) are of interest, in part, because of their ability to form stable inclusion complexes in aqueous solution. The inclusion properties of β-CD copolymers are determined by the surface area, pore structure, and site accessibility of inclusion sites within the copolymer framework. A mini-review of recent research in our group concerning the use of copolymers containing β-CD as sorbent materials for naphthenic acids is presented herein.

  11. Milk and serum standard reference materials for monitoring organic contaminants in human samples.

    PubMed

    Schantz, Michele M; Eppe, Gauthier; Focant, Jean-François; Hamilton, Coreen; Heckert, N Alan; Heltsley, Rebecca M; Hoover, Dale; Keller, Jennifer M; Leigh, Stefan D; Patterson, Donald G; Pintar, Adam L; Sharpless, Katherine E; Sjödin, Andreas; Turner, Wayman E; Vander Pol, Stacy S; Wise, Stephen A

    2013-02-01

    Four new Standard Reference Materials (SRMs) have been developed to assist in the quality assurance of chemical contaminant measurements required for human biomonitoring studies, SRM 1953 Organic Contaminants in Non-Fortified Human Milk, SRM 1954 Organic Contaminants in Fortified Human Milk, SRM 1957 Organic Contaminants in Non-Fortified Human Serum, and SRM 1958 Organic Contaminants in Fortified Human Serum. These materials were developed as part of a collaboration between the National Institute of Standards and Technology (NIST) and the Centers for Disease Control and Prevention (CDC) with both agencies contributing data used in the certification of mass fraction values for a wide range of organic contaminants including polychlorinated biphenyl (PCB) congeners, chlorinated pesticides, polybrominated diphenyl ether (PBDE) congeners, and polychlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) congeners. The certified mass fractions of the organic contaminants in unfortified samples, SRM 1953 and SRM 1957, ranged from 12 ng/kg to 2200 ng/kg with the exception of 4,4'-DDE in SRM 1953 at 7400 ng/kg with expanded uncertainties generally <14 %. This agreement suggests that there were no significant biases existing among the multiple methods used for analysis.

  12. Occurrence of rhodamine B contamination in capsicum caused by agricultural materials during the vegetation process.

    PubMed

    Gao, Wei; Wu, Naiying; Du, Jingjing; Zhou, Li; Lian, Yunhe; Wang, Lei; Liu, Dengshuai

    2016-08-15

    This paper reports on the environmental rhodamine B (RhB) contamination in capsicum caused by agricultural materials during the vegetation process. Ultra-performance liquid chromatography tandem mass spectrometry (UPLC-MS/MS) was applied to detect 64 capsicum samples from China, Peru, India and Burma. Results demonstrated that RhB was found in all samples at low concentrations (0.11-0.98 μg/kg), indicating RhB contamination in capsicums is probably a ubiquitous phenomenon. In addition, studies into soils, roots, stems and leaves in Handan of Hebei province, China showed that the whole ecologic chain had been contaminated with RhB with the highest levels in leaves. The investigation into the agricultural environment in Handan of Hebei province and Korla of Xinjiang province, China demonstrated that the appearances of RhB contamination in the tested capsicums are mainly due to the agricultural materials contamination. The study verified that environmental contamination should be an important origin for the RhB contamination in capsicum fruits.

  13. A poorly graphitised carbon contaminant in studies of extraterrestrial materials

    NASA Astrophysics Data System (ADS)

    Rietmeijer, F. J. M.

    1985-03-01

    Poorly-graphitised carbon particles are formed during manufacture of sample substrates (holey carbon films) for Analytical Electron Microscopy studies of small particles. The particles form during heat treatment of cellulose acetobutyrate at about 975°C and 1050°C. In AEM studies of fine-grained carbonaceous extraterrestrial materials, these particles are easily recognised.

  14. Chemical, Biological, and Radiological Contamination Survivability: Material Effects Testing

    DTIC Science & Technology

    2012-06-22

    compatibility X 23 Lubricity X 24 Solubility X 25 Melting point/boiling point X 26 Viscosity X Ph...MATERIAL PROPERTIES MATRIX AND DATA TEMPLATE. TABLE 2. CONTINUED Petroleum, Oils , and Lubricants Properties (cite method, SOP, ASTM, etc...used) Sample Name/Product Number Thermal Stability Chemical Compatibility Lubricity Solubility Melting Point/Boiling Point Viscosity

  15. Electroosmotic dewatering of dredged sediments: bench-scale investigation.

    PubMed

    Reddy, Krishna R; Urbanek, Adam; Khodadoust, Amid P

    2006-01-01

    The Indiana Harbor (Indiana, USA) has not been dredged since 1972 due to lack of a suitable disposal site for dredged sediment. As a result of this, over a million cubic yards of highly contaminated sediment has accumulated in the harbor. Recently, the United States Army Corps of Engineers (USACE) has selected a site for the confined disposal facility (CDF) and is in the process of designing it. Although dredging can be accomplished rapidly, the disposal in the CDF has to be done slowly to allow adequate time for consolidation to occur. The sediment possesses very high moisture content and very low hydraulic conductivity, which cause consolidation to occur slowly. Consolidation of the sediment is essential in order to achieve adequate shear strength of sediments and also to provide enough air space to accommodate the large amount of sediment that requires disposal. Currently, it has been estimated that if a one 3-foot (0.9-m) thick layer of sediment was disposed of at the CDF annually, it would take approximately 10 years to dispose of all the sediment that is to be dredged from the Indiana Harbor. This study investigated the feasibility of using an electroosmotic dewatering technology to accelerate dewatering and consolidation of sediment, thereby allowing more rapid disposal of sediment into the CDF. Electroosmotic dewatering essentially involves applying a small electric potential across the sediment layer, thereby inducing rapid flow as a result of physico-chemical and electrochemical processes. A series of bench-scale electrokinetic experiments were conducted on actual dredged sediment samples from the Indiana Harbor to investigate dewatering rates caused by gravity alone, dewatering rates caused by gravity and electric potential, and the effects of the addition of polymer flocculants on dewatering of the sediments. The results showed that electroosmotic dewatering under an applied electric potential of 1.0VDC/cm could increase the rate of dewatering and

  16. AIR EMISSIONS FROM EXPOSED SEDIMENTS AND CONTAMINATED DREDGED MATERIAL 2. DIFFUSION FROM LABORATORY-SPIKED AND AGED FIELD SEDIMENTS. (R825513C017)

    EPA Science Inventory

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  17. Finding of No Significant Impact, Skiffes Creek Federal Navigation Channel Maintenance Dredging, Joint Base Langley-Eustis, Fort Eustis, Virginia

    DTIC Science & Technology

    2014-06-06

    p011ion of Skiffes Creek affecting operation of milita>y watercraft/ 3d Pmt and disposing the dredge materials in the Fort Eustis Dredged Material...Model Inputs: Skiffs Creek DU 01/02 INPUT PARAMETER UNITS VALUE Convective descent output Collapse phase output option Number of print times for...STFATE Model Inputs: Skiffs Creek DU 03/04 INPUT PARAMETER UNITS VALUE Convective descent output Collapse phase output option Number of print times for

  18. Characterization of Contamination Generation Characteristics of Satellite Materials

    DTIC Science & Technology

    1989-11-22

    sample temperature, and collector temperature. These tests became standardized first informally by Stanford Research Institute, and then forrmally by the...provides no information on the individual behavior of the several different :pecies outgassed by most materials. Because the screc ling appro-( h uses test...This information was then assessed to determine its relevance to the program objectives. Based on the results of this assessment, a test method

  19. Tools for modeling radioactive contaminants in chip materials

    NASA Astrophysics Data System (ADS)

    Wrobel, F.; Kaouache, A.; Saigné, F.; Touboul, A. D.; Schrimpf, R. D.; Warot, G.; Bruguier, O.

    2017-03-01

    Radioactive pollutants are naturally present in microelectronic device materials and can be an issue for the reliability of devices. The main concern is alpha emitters that produce high-energy particles (a few MeV) that ionize the semiconductor and then trigger soft errors. The question is to know what kinds of radionuclides are present in the device, their location in the device and the abundance of each species. In this paper we describe tools that are required to address the issue of radioactive pollutants in electronic devices.

  20. Mobilization of PAHs and PCBs from In-Place Contaminated Marine Sediments During Simulated Resuspension Events

    NASA Astrophysics Data System (ADS)

    Latimer, J. S.; Davis, W. R.; Keith, D. J.

    1999-10-01

    A particle entrainment simulator was used to experimentally produce representative estuarine resuspension conditions to investigate the resulting transport of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) to the overlying water column. Contaminants were evaluated in bulk sediments, size fractionated sediments, resuspended particulate material and in some cases, dissolved phases during the experiments. The two types of sediments used in the experiments, dredged material and bedded estuarine sediment, represented gradients in contaminant loadings and sediment textural characteristics. For the bedded sediment, resuspension tended to winnow the sediments of finer particles. However, in the case of the more highly contaminated dredge material, non-selective resuspension was most common. Resuspension resulted in up to orders of magnitude higher particle-bound organic contaminant concentrations in the overlying water column. Dissolved phase PAH changes during resuspension were variable and at most, increased by a factor of three. The sifting process resulted in the partitioning of fine and coarse particle contaminant loading. For bedded sediments, accurate predictions of PAH and PCB loadings on resuspended particles were made using the mass of resuspended particles of different sizes and the concentrations of contaminants in the particle pools of the bulk sediment. However, due possibly to contributions from other unmeasured particles (e.g. colloids), predictions were not possible for the dredge material. Thus, knowledge of the redistribution and fate of colloids may be important. The partitioning of PAHs between the dissolved and particulate phases during resuspension events was predicted to within a factor of two from the amount of organic carbon in each of the resuspended samples. These experiments show that contaminant transport is a function of the chemistry and textural characteristics of the bulk sediment and the winnowing action

  1. A United States perspective on long-term management of areas contaminated with radioactive materials.

    PubMed

    Jones, C Rick

    2004-01-01

    The US has far-reaching and extensive experience in the long-term management of areas contaminated with radioactive materials. This experience base includes the Department of Energy's continued follow-up with Hiroshima and Nagasaki from the 1940s at the Radiological Effects Research Foundation in Hiroshima, Japan, the long-term management of the Marshall Islands Programme, the clean-up of the US nuclear weapons complex and the ongoing management of accident sites such as in Palomares, Spain. This paper discusses the lessons learnt and best practices gained from this far-reaching and extensive experience in the long-term management of areas contaminated with radioactive materials.

  2. Dredged Material Containment in Long Island Sound.

    DTIC Science & Technology

    1979-01-01

    one factor such as biological value, but the fact that these sites are American oyster ( Crassostrea virginica ) seeding grounds would eliminate them...1 N v’ Iuz3 96s N I ~ ~ U r m ICCIO S is I U IC 41 I-E z b .. I u. CU . Ia Q Ix. -’A-6 6, W~ ) 61a U𔃻 L’L L 0 ’o. ’L .I C - I~A Ia. 16161 uv. -d...presented the criteria. He gave a figure of about $3 to $5/ cu . yd. for a barge hauling distance of about 30 miles. An increase of hauling distance from

  3. Effects of Dredged Materials on Zooplankton.

    DTIC Science & Technology

    1984-06-01

    VI. Biology of Acartia clausi and A. tonsa. Bull. Bingham Oceanogr. Coll., 15: 156-7 . "b Darby, 0. A., R. W. Alden III, J. H. Rule, C. H. Blair...block number) Elutriate bioassays with Acartia tonsa suggest that sediments from the Southern Branch lower reaches could significantly impact the...REFERENCES ..................................................... 15 -’ LIST OF TABLES Table 1 Multiple regression table for Acartia tonsa survival

  4. Bioassays on Illinois Waterway Dredged Material.

    DTIC Science & Technology

    1992-12-01

    48-hr) toxicity tests were conducted with two species, Pimephales promelas (the fathead minnow) and Daphnia magna (a freshwater cladoceran). A...chronic (21-day) toxicity test was also conducted using Daphnia magna . Animals were exposed separately to different concentrations of filtered and...unfiltered elutriates prepared from Acute, Cadmium, Daphnia magna , Pimephales promela, Ammonia, Chronic, Elutriate, Sediment, Bioassay, Cladoceran, Fathead

  5. Assessment of resist outgassing related EUV optics contamination for CAR and non-CAR material chemistries

    NASA Astrophysics Data System (ADS)

    Pollentier, I.; Neira, I.; Gronheid, R.

    2011-04-01

    EUV lithography is expected to be the key lithography option for sub-22nm device manufacturing. In order to meet the required imaging capability, resist performance improvements are being investigated by exploring both chemically amplified resists (CAR) and non-CAR chemistries. Another critical item related to resist chemistry is the EUV irradiation induced outgassing and its risk for optics contamination, especially towards high source power (pre-) productions tools. In this area it is important to characterize for the different chemistries which resist components are critical for EUV induced outgassing and - more important - which can result in non-cleanable mirror contamination. In this paper, we will explore the outgassing and contamination behavior of CAR and non-CAR resist by using Residual Gas Analysis (RGA) for identifying the resist outgassing characteristics, and by Witness Sample (WS) testing to evaluate the tendency for contamination. For CAR resists, it has been found that the PAG cation is a key component contributing to the contamination, but its impact can be changed by changing the resist formulation. In this investigation several model resists have been evaluated in order to understand which chemical components have - or don't have - an impact on the contamination. This has led to a proposal of a definition for a resist family. For non-CAR materials, the investigation has focused to a number of example resists. Most results are related to poly(-olefin sulfones), which have been proven to be good candidate materials for outgassing and contamination learning. The tests have confirmed that aromatic groups present in resist outgassing are playing an important role. As an opposite example of non-CAR material, the inorganic Inpria resist was tested, which revealed that its resist outgassing (water and oxygen) can remove carbon contamination. The combined work on CAR and non-CAR outgassing and contamination has learned significantly on the relationship

  6. Plausible role of nanoparticle contamination in the synthesis and properties of organic electronic materials

    NASA Astrophysics Data System (ADS)

    Ananikov, Valentine P.

    2016-12-01

    Traceless transition metal catalysis (Pd, Ni, Cu, etc.) is very difficult to achieve. Metal contamination in the synthesized products is unavoidable and the most important questions are: How to control metal impurities? What amount of metal impurities can be tolerated? What is the influence of metal impurities? In this brief review, the plausible origins of nanoparticle contamination are discussed in the framework of catalytic synthesis of organic electronic materials. Key factors responsible for increasing the probability of contamination are considered from the point of view of catalytic reaction mechanisms. The purity of the catalyst may greatly affect the molecular weight of a polymer, reaction yield, selectivity and several other parameters. Metal contamination in the final polymeric products may induce some changes in the electric conductivity, charge transport properties, photovoltaic performance and other important parameters.

  7. Study of abyssal seafloor isolation of contaminated sediments concluded

    SciTech Connect

    Valent, P.

    1998-12-31

    Recognizing the rapidly decreasing availability of disposal sites on land, in 1993 Congress directed the Department of Defense to assess the technical and scientific feasibility of isolating contaminated dredged material on the abyssal seafloor. The Naval Research Laboratory (NRL) conducted and managed the assessment, which was funded during its first year by the Strategic Environmental Research and Development Program and in the following two years by the Defense Advanced Research Projects Agency. NRL carried out the projects in collaboration with participants from academic institutions and industrial organizations. The seafloor isolation concept is an attractive management option for contaminated dredged material because, if abyssal isolation is feasible and environmentally sound, air, land, or water supplies would not be contaminated. The participants concluded that it is technically and environmentally feasible. In ports where shipping costs are high, abyssal seafloor isolation is a cost-competitive strategy. They also outlined the architecture of a system to monitor conditions at the site and to detect and measure possible leaks of contaminated material.

  8. REAL-TIME IDENTIFICATION AND CHARACTERIZATION OF ASBESTOS AND CONCRETE MATERIALS WITH RADIOACTIVE CONTAMINATION

    SciTech Connect

    XU, X. George; Zhang, X.C.

    2002-05-10

    Concrete and asbestos-containing materials were widely used in DOE building construction in the 1940s and 1950s. Over the years, many of these porous materials have been contaminated with radioactive sources, on and below the surface. To improve current practice in identifying hazardous materials and in characterizing radioactive contamination, an interdisciplinary team from Rensselaer has conducted research in two aspects: (1) to develop terahertz time-domain spectroscopy and imaging system that can be used to analyze environmental samples such as asbestos in the field, and (2) to develop algorithms for characterizing the radioactive contamination depth profiles in real-time in the field using gamma spectroscopy. The basic research focused on the following: (1) mechanism of generating of broadband pulsed radiation in terahertz region, (2) optimal free-space electro-optic sampling for asbestos, (3) absorption and transmission mechanisms of asbestos in THz region, (4) the role of asbestos sample conditions on the temporal and spectral distributions, (5) real-time identification and mapping of asbestos using THz imaging, (7) Monte Carlo modeling of distributed contamination from diffusion of radioactive materials into porous concrete and asbestos materials, (8) development of unfolding algorithms for gamma spectroscopy, and (9) portable and integrated spectroscopy systems for field testing in DOE. Final results of the project show that the combination of these innovative approaches has the potential to bring significant improvement in future risk reduction and cost/time saving in DOE's D and D activities.

  9. Use of neutralized industrial residue to stabilize trace elements (Cu, Cd, Zn, As, Mo, and Cr) in marine dredged sediment from South-East of France.

    PubMed

    Taneez, Mehwish; Marmier, Nicolas; Hurel, Charlotte

    2016-05-01

    Management of marine dredged sediments polluted with trace elements is prime issue in the French Mediterranean coast. The polluted sediments possess ecological threats to surrounding environment on land disposal. Therefore, stabilization of contaminants in multi-contaminated marine dredged sediment is a promising technique. Present study aimed to assess the effect of gypsum neutralized bauxaline(®) (bauxite residue) to decrease the availability of pollutants and inherent toxicity of marine dredged sediment. Bauxaline(®), (alumia industry waste) contains high content of iron oxide but its high alkalinity makes it not suitable for the stabilization of all trace elements from multi-contaminated dredged sediments. In this study, neutralized bauxaline(®) was prepared by mixing bauxaline(®) with 5% of plaster. Experiments were carried out for 3 months to study the effect of 5% and 20% amendment rate on the availability of Cu, Cd, Zn, As, Mo, and Cr. Trace elements concentration, pH, EC and dissolved organic carbon were measured in all leachates. Toxicity of leachates was assessed against marine rotifers Brachionus plicatilis. The Results showed that both treatments have immobilization capacity against different pollutants. Significant stabilization of contaminants (Cu, Cd, Zn) was achieved with 20% application rate whereas As, Mo, and Cr were slightly stabilized. Toxicity results revealed that leachates collected from treated sediment were less toxic than the control sediment. These results suggest that application of neutralized bauxaline(®) to dredged sediment is an effective approach to manage large quantities of dredged sediments as well as bauxite residue itself.

  10. Real-Time Identification and Characterization of Asbestos and Concrete Materials with Radioactive Contamination

    SciTech Connect

    Xu, George; Zhang, Xi-Cheng

    2000-06-01

    Concrete and asbestos-containing materials were widely used in U.S. Department of Energy (DOE) building construction in the 1940s and 1950s. Over the years, many of these porous building materials have been contaminated with radioactive sources, on and below the surface. This intractable radioactive-and-hazardous-asbestos mixed-waste stream has created a tremendous challenge to DOE decontamination and decommissioning (D&D) project managers. The current practice to identify asbestos and to characterize radioactive contamination depth profiles in based solely on bore sampling, which is inefficient, costly, and unsafe. A three-year research project was started 1998 at Rensselaer with the following ultimate goals: (1) development of novel non-destructive methods for identifying the hazardous asbestos in real-time and in-situ, and (2) development of new algorithms and apparatus for characterizing the radioactive contamination depth profile in real-time and in-situ.

  11. Real-Time Identification and Characterization of Asbestos and Concrete Materials with Radioactive Contamination

    SciTech Connect

    Xu, George; Zhang, Xi-Cheng

    1999-06-01

    Concrete and asbestos-containing materials were widely used in U.S. Department of Energy (DOE) building construction in the 1940s and 1950s. Over the years, many of these porous building materials have been contaminated with radioactive sources, on and below the surface. This intractable radioactive-and-hazardous- asbestos mixed-waste-stream has created a tremendous challenge to DOE decontamination and decommissioning (D&D) project managers. The current practice to identify asbestos and to characterize radioactive contamination depth profiles involve bore sampling, and is inefficient, costly, and unsafe. A three-year research project was started on 10/1/98 at Rensselaer with the following ultimate goals: (1) development of novel non-destructive methods for identifying the hazardous asbestos in real-time and in-situ, and (2) development of new algorithms and apparatus for characterizing the radioactive contamination depth profile in real-time and in-situ.

  12. Standard reference materials (SRMs) for determination of organic contaminants in environmental samples.

    PubMed

    Wise, Stephen A; Poster, Dianne L; Kucklick, John R; Keller, Jennifer M; Vanderpol, Stacy S; Sander, Lane C; Schantz, Michele M

    2006-10-01

    For the past 25 years the National Institute of Standards and Technology (NIST) has developed certified reference materials (CRMs), known as standard reference materials (SRMs), for determination of organic contaminants in environmental matrices. Assignment of certified concentrations has usually been based on combining results from two or more independent analytical methods. The first-generation environmental-matrix SRMs were issued with certified concentrations for a limited number (5 to 10) of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). Improvements in the analytical certification approach significantly expanded the number and classes of contaminants determined. Environmental-matrix SRMs currently available include air and diesel particulate matter, coal tar, marine and river sediment, mussel tissue, fish oil and tissue, and human serum, with concentrations typically assigned for 50 to 90 organic contaminants, for example PAHs, nitro-substituted PAHs, PCBs, chlorinated pesticides, and polybrominated diphenyl ethers (PBDEs).

  13. 24. Plutonium Recovery From Contaminated Materials, Architectural Details, Building 232z, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    24. Plutonium Recovery From Contaminated Materials, Architectural Details, Building 232-z, U.S. Atomic Energy Commission, Hanford Atomic Products Operation, General Electric Company, Dwg. No. H-2-23106, 1959. - Plutonium Finishing Plant, Waste Incinerator Facility, 200 West Area, Richland, Benton County, WA

  14. Closure Report for Corrective Action Unit 210: Storage Areas and Contaminated Material, Nevada Test Site, Nevada

    SciTech Connect

    U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office; Bechtel Nevada

    2004-06-01

    Corrective Action Unit 210, Storage Areas and Contaminated Material, is identified in the Federal Facilities Agreement and Consent Order. This Corrective Action Unit consists of four Corrective Action Sites located in Areas 10, 12, and 15 of the Nevada Test Site. This report documents that the closure activities conducted meet the approved closure standards.

  15. Determination of contamination in rare earth materials by promptgamma activation analysis (PGAA)

    SciTech Connect

    Perry, D.L.; English, G.A.; Firestone, R.B.; Molnar, G.L.; Revay,Zs.

    2004-11-09

    Prompt gamma activation analysis (PGAA) has been used to detect and quantify impurities in the analyses of rare earth (RE) oxides. The analytical results are discussed with respect to the importance of having a thorough identification and understanding of contaminant elements in these compounds regarding the function of the materials in their various applications. Also, the importance of using PGAA to analyze materials in support of other physico-chemical studies of the materials is discussed, including the study of extremely low concentrations of ions such as the rare earth ions themselves in bulk material matrices.

  16. The Use of Haz-Flote to Efficiently Remove Mercury from Contaminated Materials

    SciTech Connect

    Terry Brown

    2009-03-03

    There are thousands of known contaminated sites in the United Stated, including Superfund sites (1500 to 2100 sites), RCRA corrective action sites (1500 to 3500 sites), underground storage tanks (295,000 sites), U.S. Department of Defense sites (7300 sites), U.S. Department of Energy sites (4,000 sites), mining refuse piles, and numerous other hazardous metals and organic contamination sites. Only a small percentage of these sites has been cleaned up. The development of innovative technologies to handle the various clean-up problems on a national and international scale is commonplace. Many innovative technologies have been developed that can be used to effectively remediate contaminated materials. Unfortunately, many of these technologies are only effective for materials coarser than approximately 200 mesh. In addition, these technologies usually require considerable investment in equipment, and the clean-up costs of soil material are relatively high - in excess of $100 to $500 per yd{sup 3}. These costs result from the elaborate nature of the processes, the costs for power, and the chemical cost. The fine materials are disposed of or treated at considerable costs. As a result, the costs often associated with amelioration of contaminated sites are high. Western Research institute is in the process of developing an innovative soil washing technology that addresses the removal of contaminants from the fine size-fraction materials located at many of the contaminated sites. This technology has numerous advantages over the other ex-situ soil washing techniques. It requires a low capital investment, low operating costs and results in high levels of re-emplacement of the cleaned material on site. The process has the capability to clean the fine fraction (<200 mesh) of the soil resulting in a replacement of 95+% of the material back on-side, reducing the costs of disposal. The Haz-Flote{trademark} technology would expand the application of soil washing technology to heavy

  17. A PHYSICAL, CHEMICAL, AND BIOLOGICAL ASSESSMENT OF MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, NC

    EPA Science Inventory

    Management of contaminated sediments poses significant challenges due to varied contaminants and volumes of sediments to manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks. Understanding how eff...

  18. PHYSICAL, CHEMICAL AND BIOLOGICAL TOOLS FOR EVALUATING, MONITORED NATURAL RECOVERY OF PCB CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, SC

    EPA Science Inventory

    Management of contaminated sediments poses significant challenges due to varied contaminants and volumes of sediments to
    manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks.
    Understanding ho...

  19. IMPACT OF TARGET MATERIAL ACTIVATION ON PERSONNEL EXPOSURE AND RADIOACTIVE CONTAMINATION IN THE NATIONAL IGNITION FACILITY

    SciTech Connect

    Khater, H; Epperson, P; Thacker, R; Beale, R; Kohut, T; Brereton, S

    2009-06-30

    Detailed activation analyses are performed for the different materials under consideration for use in the target capsules and hohlraums used during the ignition campaign on the National Ignition Facility. Results of the target material activation were additionally used to estimate the levels of contamination within the NIF target chamber and the workplace controls necessary for safe operation. The analysis examined the impact of using Be-Cu and Ge-doped CH capsules on the external dose received by workers during maintenance activities. Five days following a 20 MJ shot, dose rates inside the Target Chamber (TC) due to the two proposed capsule materials are small ({approx} 1 {micro}rem/h). Gold and depleted-uranium (DU) are considered as potential hohlraum materials. Following a shot, gold will most probably get deposited on the TC first wall. On the other hand, while noble-gas precursors from the DU are expected to stay in the TC, most of the noble gases are pumped out of the chamber and end up on the cryopumps. The dose rates inside the TC due to activated gold or DU, at 5 days following a 20 MJ shot, are about 1 mrem/h. Dose rates in the vicinity of the cryo-pumps (containing noble 'fission' gases) drop-off to about 1 mrem/h during the first 12 hours following the shot. Contamination from activation of NIF targets will result in the NIF target chamber exceeding DOE surface contamination limits. Objects removed from the TC will need to be managed as radioactive material. However, the results suggest that airborne contamination from resuspension of surface contamination will not be significant and is at levels that can be managed by negative ventilation when accessing the TC attachments.

  20. Effects of Contamination, UV Radiation, and Atomic Oxygen on ISS Thermal Control Materials

    NASA Technical Reports Server (NTRS)

    Visentine, Jim; Finckenor, Miria; Zwiener, Jim; Munafo, Paul (Technical Monitor)

    2001-01-01

    Thermal control surfaces on the International Space Station (ISS) have been tailored for optimum optical properties. The space environment, particularly contamination, ultraviolet (UV) radiation, and atomic oxygen (AO) may have a detrimental effect on these optical properties. These effects must be quantified for modeling and planning. Also of interest was the effect of porosity on the reaction to simulated space environment. Five materials were chosen for this study based on their use on ISS. The thermal control materials were Z-93 white coating, silverized Teflon, chromic acid anodized aluminum, sulfuric acid anodized aluminum, and 7075-T6 aluminum. Some of the samples were exposed to RTV 560 silicone; others were exposed to Tefzel offgassing products. Two samples of Z-93 were not exposed to contamination as clean "controls". VUV radiation was used to photo-fix the contaminant to the material surface, then the samples were exposed to AO. All samples were exposed to 1000 equivalent sun-hours (ESH) of vacuum ultraviolet radiation (VUV) at the AZ Technology facility and a minimum of 1.5 x 10(exp 20) atoms/sq cm of AO at Marshall Space Flight Center. Half of the samples were exposed to an additional 2000 ESH of VUV at Huntington Beach prior to sent to AZ Technology. Darkening of the Z-93 white coating was noted after VUV exposure. AO exposure did bleach the Z-93 but not back to its original brightness. Solar absorptance curves show the degradation due to contamination and VUV and the recovery with AO exposure. More bleaching was noted on the Tefzel-contaminated samples than with the RTV-contaminated samples.

  1. The influence of raw material contamination with mycotoxins on alcoholic fermentation indicators.

    PubMed

    Kłosowski, Grzegorz; Mikulski, Dawid; Grajewski, Jan; Błajet-Kosicka, Anna

    2010-05-01

    The aim of the research was to describe the influence of selected mycotoxins on major factors (alcohol concentration, productivity, yield and energy) that are characteristic of the fermentation process of maize mashes. Indicators of the alcoholic fermentation of mashes made from raw material with low contaminations levels were compared with mashes obtained from raw material that was selectively contaminated with mycotoxins on the following concentrations: aflatoxin B(1)-11.65 ppb, B(2)-12.60 ppb, G(1)-12.34 ppb, G(2)-12.04 ppb; ochratoxin A-177.5 ppb; zearalenone-352 ppb; deoxynivalenol-2274 ppb; fumonisin B(1)-1875 ppb, B(2)-609 ppb, B(3)-195 ppb. It was found that, apart from fumonisin, all mycotoxins substantially affected the course of subsequent fermentation phases, in particular the first and the main fermentation phases. The highest drop in alcohol concentration at the main stage of the process amounted to 1% v/v and it was achieved by contamination with zearalenone. The statistically significant drop in the final fermentation yield was observed; this was caused by raw material contaminated with all studied mycotoxins, except for fumonisin. The decrease in ethanol yield in reference to the control variant ranged from 1.42 to 3.20 dm(3) of absolute alcohol out of 100 kg of starch, depending on a toxin.

  2. The effects of surfactants on the desorption of organic contaminants from aquifer materials

    SciTech Connect

    Brickell, J.L.

    1989-01-01

    The efficiency of removing organic contaminants from groundwater aquifers by the pump and treat process is adversely affected by the retardation of the contaminant's mobility due to adsorption onto aquifer material. The use of surfactants in conjunction with the pump and treat process has the potential for improving contaminant mobility by solubilizing the adsorbed contaminant. An experimental program was conducted to screen various types of commercially available nonionic and anionic surfactants for solubilizing adsorbed naphthalene from one type of aquifer material. Two additional types of aquifer materials were obtained, and the surfactant mixture, Tween 20 and Aerosol AY-65, selected during the screening process was used at various concentrations for equilibrium desorption studies to quantify surfactant effects on naphthalene desorption. Column studies subsequently were conducted to determine surfactant effects in a flow through system. Equilibrium desorption studies showed that a 0.125% surfactant solution decreased the partition coefficient 65% compared with water alone for one soil type, while greater surfactant concentrations resulted in less effective mobilization. However, the same surfactant mixture markedly increased the partition coefficient when used with another soil type, and had negligible effects for the third soil type. It was shown that the clay mineralogy significantly influenced the effect of the surfactant solution. Column studies showed that mass removal efficiencies were increased by approximately 40 to 60% using the surfactant solution as compared with water alone. Varying flow rates did not influence the effectiveness of either the surfactant or water solutions.

  3. Test program on the contamination of ultraviolet region mirrors by Apollo Telescope Mount materials

    NASA Technical Reports Server (NTRS)

    Austin, J. D.

    1974-01-01

    Results are presented of testing performed to measure the effects of material outgas products on the reflectances of ultraviolet-region mirrors. These tests were to provide data on changes of ultraviolet reflectances of first-surface mirrors which had been exposed to the outgas products of selected materials under specific time and thermal-vacuum conditions. The requirement for such data was based on the extreme sensitivity of the sophisticated optical instruments in the Skylab mission's Apollo Telescope Mount (ATM) to condensed outgas products from materials, and on the desire to insure that no serious hazard of contaminating these instruments existed.

  4. U.S. Navy Harbor Maintenance Dredging Atlas.

    DTIC Science & Technology

    1980-12-01

    Yorktown; and Naval Supply Center - Cheatham Annex, Williamsburg. However, 90% of the composite dredging at these facilities is done at the Norfolk Naval...upland spoil site. The offshore spoil site is still open and EPA approved, but the EPA permit is for land disposal only. See DREDGING COSTS section of... Composite baseline dredging report. Port Hueneme, Calif., 1976. 12. . NESO Report 11-005: Philadelphia baseline dredging report vol 1. Port Hueneme, Calif

  5. Basalts Dredged from the Northeastern Pacific Ocean.

    PubMed

    Engel, C G; Engel, A E

    1963-06-21

    Volcanic rocks dredged from seamounts, fault ridges, and other major geological features of the northeast Pacific Ocean include a wide variety of basalts. Most of these are vesicular, porphyritic types with near analogues in the Hawaiian and other oceanic islands. In addition, aluminous basalts and diabasic theoleiites impoverished in potassium also occur. There is no simple correlation of composition, degree of oxidation, vesiculation, or hydration of these basalts with texture, or depth of dredge site. Most samples appear to have been extruded at much shallower depths than those now pertaining at the dredge site. The distribution of these basalts suggests that the andesite line coincides with or lies on the continent side of the foot of the continental slope.

  6. Basalts dredged from the northeastern Pacific Ocean

    USGS Publications Warehouse

    Engel, C.G.; Engel, A.E.J.

    1963-01-01

    Volcanic rocks dredged from seamounts, fault ridges, and other major geological features of the northeast Pacific Ocean include a wide variety of basalts. Most of these are vesicular, porphyritic types with near analogues in the Hawaiian and other oceanic islands. in addition, aluminous basalts and diabasic tholeiites impoverished in potassium also occur. There is no simple correlation of composition, degree of oxidation, vesiculation, or hydration of these basalts with texture, or depth of dredge site. Most samples appear to have been extruded at much shallower depths than those now pertaining at the dredge site. the distribution of these basalts suggests that the andesite line coincides with or lies on the continent side of the foot of the continental slope.

  7. An overview of dredging operations in the Chesapeake Bay. [environment effects and coastal ecology

    NASA Technical Reports Server (NTRS)

    Silver, R. H.

    1978-01-01

    Maintenance of the Baltimore and the Newport News/Norfolk harbors as well as of the Chesapeake and Delaware Canal is accomplished by different dredging operations which depend on the amount and type of material to be moved, water depth, and location of disposal sites. Methods for determining the physical or chemical-biological interactive effects of these activities on the environment and on the shellfish and finfish industries on the Bay are discussed. The types of dredges used are classed according to their mode of operation.

  8. 33 CFR 88.15 - Lights on dredge pipelines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 1 2014-07-01 2014-07-01 false Lights on dredge pipelines. 88.15... NAVIGATION RULES ANNEX V: PILOT RULES § 88.15 Lights on dredge pipelines. Dredge pipelines that are floating or supported on trestles shall display the following lights at night and in periods of...

  9. 33 CFR 88.15 - Lights on dredge pipelines.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 1 2013-07-01 2013-07-01 false Lights on dredge pipelines. 88.15... NAVIGATION RULES ANNEX V: PILOT RULES § 88.15 Lights on dredge pipelines. Dredge pipelines that are floating or supported on trestles shall display the following lights at night and in periods of...

  10. 33 CFR 88.15 - Lights on dredge pipelines.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Lights on dredge pipelines. 88.15... NAVIGATION RULES ANNEX V: PILOT RULES § 88.15 Lights on dredge pipelines. Dredge pipelines that are floating or supported on trestles shall display the following lights at night and in periods of...

  11. Understanding the effects of PEMFC contamination from balance of plant assembly aids materials: In situ studies

    DOE PAGES

    Opu, Md.; Bender, G.; Macomber, Clay S.; ...

    2015-06-29

    In this study, in situ performance data were measured to assess the degree of contamination from leachates of five families of balance of plant (BOP) materials (i.e., 2-part adhesive, grease, thread lock/seal, silicone adhesive/seal and urethane adhesive/seal) broadly classified as assembly aids that may be used as adhesives and lubricants in polymer electrolyte membrane fuel cell (PEMFC) systems. Leachate solutions, derived from soaking the materials in deionized (DI) water at elevated temperature, were infused into the fuel cell to determine the effect of the leachates on fuel cell performance. During the contamination phase of the experiments, leachate solution was introducedmore » through a nebulizer into the cathode feed stream of a 50 cm2 PEMFC operating at 0.2 A/cm2 at 80°C and 32%RH. Voltage loss and high frequency resistance (HFR) were measured as a function of time and electrochemical surface area (ECA) before and after contamination were compared. Two procedures of recovery, one self-induced recovery with DI water and one driven recovery through cyclic voltammetry (CV) were investigated. Finally, performance results measured before and after contamination and after CV recovery are compared and discussed.« less

  12. Understanding the effects of PEMFC contamination from balance of plant assembly aids materials: In situ studies

    SciTech Connect

    Opu, Md.; Bender, G.; Macomber, Clay S.; Van Zee, J. W.; Dinh, Huyen N.

    2015-06-29

    In this study, in situ performance data were measured to assess the degree of contamination from leachates of five families of balance of plant (BOP) materials (i.e., 2-part adhesive, grease, thread lock/seal, silicone adhesive/seal and urethane adhesive/seal) broadly classified as assembly aids that may be used as adhesives and lubricants in polymer electrolyte membrane fuel cell (PEMFC) systems. Leachate solutions, derived from soaking the materials in deionized (DI) water at elevated temperature, were infused into the fuel cell to determine the effect of the leachates on fuel cell performance. During the contamination phase of the experiments, leachate solution was introduced through a nebulizer into the cathode feed stream of a 50 cm2 PEMFC operating at 0.2 A/cm2 at 80°C and 32%RH. Voltage loss and high frequency resistance (HFR) were measured as a function of time and electrochemical surface area (ECA) before and after contamination were compared. Two procedures of recovery, one self-induced recovery with DI water and one driven recovery through cyclic voltammetry (CV) were investigated. Finally, performance results measured before and after contamination and after CV recovery are compared and discussed.

  13. Method and apparatus for in-cell vacuuming of radiologically contaminated materials

    DOEpatents

    Spadaro, Peter R.; Smith, Jay E.; Speer, Elmer L.; Cecconi, Arnold L.

    1987-01-01

    A vacuum air flow operated cyclone separator arrangement for collecting, handling and packaging loose contaminated material in accordance with acceptable radiological and criticality control requirements. The vacuum air flow system includes a specially designed fail-safe prefilter installed upstream of the vacuum air flow power supply. The fail-safe prefilter provides in-cell vacuum system flow visualization and automatically reduces or shuts off the vacuum air flow in the event of an upstream prefilter failure. The system is effective for collecting and handling highly contaminated radiological waste in the form of dust, dirt, fuel element fines, metal chips and similar loose material in accordance with radiological and criticality control requirements for disposal by means of shipment and burial.

  14. Synthetic routes contaminate graphene materials with a whole spectrum of unanticipated metallic elements

    PubMed Central

    Wong, Colin Hong An; Sofer, Zdeněk; Kubešová, Marie; Kučera, Jan; Matějková, Stanislava; Pumera, Martin

    2014-01-01

    The synthesis of graphene materials is typically carried out by oxidizing graphite to graphite oxide followed by a reduction process. Numerous methods exist for both the oxidation and reduction steps, which causes unpredictable contamination from metallic impurities into the final material. These impurities are known to have considerable impact on the properties of graphene materials. We synthesized several reduced graphene oxides from extremely pure graphite using several popular oxidation and reduction methods and tracked the concentrations of metallic impurities at each stage of synthesis. We show that different combinations of oxidation and reduction introduce varying types as well as amounts of metallic elements into the graphene materials, and their origin can be traced to impurities within the chemical reagents used during synthesis. These metallic impurities are able to alter the graphene materials’ electrochemical properties significantly and have wide-reaching implications on the potential applications of graphene materials. PMID:25201990

  15. Strike-through of moist contamination by woven and nonwoven surgical materials.

    PubMed

    Laufman, H; Eudy, W W; Vandernoot, A M; Harris, C A; Liu, D

    1975-06-01

    A test is described which correlates the stress of stretching surgical gown and drape material with moist bacterial strike-through. By application of this test to a number of woven and nonwoven surgical gown and drape materials, it was found that not all of these materials, either woven or nonwoven, are impermeable to moist contamination for equal periods of time. Nonwoven disposable materials now in use range from those which remain impermeable to moist bacterial permeation through all tests while some remain impermeable for limited periods of time, and others almost immediately permeable to moist bacterial penetration. The same situation holds for woven materials. Under conditions of our test, Quarpel treated Pima tight-woven cotton cloth was impermeable to moist bacterial strike-through, through up to 75 washing and sterilizing cyclings, while ordinary linen and untreated Pima cloth permitted bacterial permeation almost immediately. These results have significance in lengthy wet surgical operations.

  16. Remediation technologies for contaminated sediments

    SciTech Connect

    Swanson, L.M.

    1995-09-01

    Although soil and groundwater remediation has been conducted for many years, sediment remediation is still in its infancy. Regulatory agencies are now beginning to identify areas where contaminated sediments exist and evaluate their environmental impact. As these evaluations are completed, the projects must shift focus to how these sediments can be remediated. Also as the criteria for aquatic disposal of dredged sediments become more stringent, remediation technologies must be developed to address contaminated sediments generated by maintenance dredging.This report describes the various issues and possible technologies for sediment remediation.

  17. Minutes of the workshop on off-site release criteria for contaminated materials

    SciTech Connect

    Singh, S.P.N.

    1989-11-01

    A one and one-half-day workshop was held May 2-3, 1989, at the Pollard Auditorium in Oak Ridge, Tennessee, with the objective of formulating a strategy for developing reasonable and uniform criteria for releasing radioactively contaminated materials from the US Department of Energy (DOE) sites. This report contains the minutes of the workshop. At the conclusion of the workshop, a plan was formulated to facilitate the development of the above-mentioned off-site release criteria.

  18. Environmental Effects of Dredging. Use of Daphnia Magna to Predict Consequences of Bioaccumulation.

    DTIC Science & Technology

    1987-03-01

    and biological effects in the freshwater crustacean, Daphnia magna (commonly known as the water flea). Procedures presented here for a 28-day Daphnia ... magna toxicity test could be used in screening for water-column toxicity resulting from open-water disposal of a specific dredged material. As a part

  19. Resrad-recycle: a computer model for analyzing radiation exposures resulting from recycling radioactively contaminated scrap metals or reusing radioactively surface-contaminated materials and equipment.

    PubMed

    Cheng, Jing-Jy; Kassas, Bassel; Yu, Charley; Amish, John; LePoire, Dave; Chen, Shih-Yew; Williams, W A; Wallo, A; Peterson, H

    2004-11-01

    RESRAD-RECYCLE is a computer code designed by Argonne National Laboratory (ANL) to be used in making decisions about the disposition of radioactively contaminated materials and scrap metals. It implements a pathway analysis methodology to evaluate potential radiation exposures resulting from the recycling of contaminated scrap metals and the reuse of surface-contaminated materials and equipment. For modeling purposes, it divides the entire metal recycling process into six steps: (1) scrap delivery, (2) scrap melting, (3) ingot delivery, (4) product fabrication, (5) product distribution, and (6) use of finished product. RESRAD-RECYCLE considers the reuse of surface-contaminated materials in their original forms. It contains representative exposure scenarios for each recycling step and the reuse process; users can also specify scenarios if desired. The model calculates individual and collective population doses for workers involved in the recycling process and for the public using the finished products. The results are then used to derive clearance levels for the contaminated materials on the basis of input dose restrictions. The model accounts for radiological decay and ingrowth, dilution and partitioning during melting, and distribution of refined metal in the various finished products, as well as the varying densities and geometries of the radiation sources during the recycling process. A complete material balance in terms of mass and radioactivity during the recycling process can also be implemented. In an international validation study, the radiation doses calculated by RESRAD-RECYCLE were shown to agree fairly well with actual measurement data.

  20. RESRAD-RECYCLE : a computer model for analyzing radiation exposures resulting from recycling radioactively contaminated scrap metals or reusing ratioactively surface-contaminated materials and equipment.

    SciTech Connect

    Cheng, J. J.; Kassas, B.; Yu, C.; Arnish, J. J.; LePoire, D.; Chen, S.-Y.; Williams, W. A.; Wallo, A.; Peterson, H.; Environmental Assessment; DOE; Univ. of Texas

    2004-11-01

    RESRAD-RECYCLE is a computer code designed by Argonne National Laboratory (ANL) to be used in making decisions about the disposition of radioactively contaminated materials and scrap metals. It implements a pathway analysis methodology to evaluate potential radiation exposures resulting from the recycling of contaminated scrap metals and the reuse of surface-contaminated materials and equipment. For modeling purposes, it divides the entire metal recycling process into six steps: (1) scrap delivery, (2) scrap melting, (3) ingot delivery, (4) product fabrication, (5) product distribution, and (6) use of finished product. RESRAD-RECYCLE considers the reuse of surface-contaminated materials in their original forms. It contains representative exposure scenarios for each recycling step and the reuse process; users can also specify scenarios if desired. The model calculates individual and collective population doses for workers involved in the recycling process and for the public using the finished products. The results are then used to derive clearance levels for the contaminated materials on the basis of input dose restrictions. The model accounts for radiological decay and ingrowth, dilution and partitioning during melting, and distribution of refined metal in the various finished products, as well as the varying densities and geometries of the radiation sources during the recycling process. A complete material balance in terms of mass and radioactivity during the recycling process can also be implemented. In an international validation study, the radiation doses calculated by RESRAD-RECYCLE were shown to agree fairly well with actual measurement data.

  1. Environmental effects of dredging: The use of population modeling to interpret chronic sublethal sediment bioassays. Technical notes

    SciTech Connect

    Bridges, T.S.; Dillon, T.M.

    1993-08-01

    This technical note provides a brief introduction to population modeling and describes the application and utility of such techniques for dredged material bioassays. The use of population modeling as a source of interpretive guidance for chronic sublethal dredged material bioassays is emphasized. Current laws and regulations governing the discharge of dredged material stress the importance of assessing the chronic (long-term) sublethal effects of dredging operations. Regulations implementing section 103 of the Marine Protection, Research and Sanctuaries Act (PL 92-532) state that, `Materials shall be deemed environmentally acceptable for ocean dumping only when . . . no significant undesirable effects will occur due either to chronic toxicity or to bioaccumulation........`. Similar language is used in regulations implementing section 404(b)(1) of the Clean Water Act (FL 92-500) which reads: `The permitting authority shall determine in writing the potential short-term or long-term effects of a proposed discharge of dredged or fill material on the physical, chemical, and biological components of the aquatic environment.........It also stipulates that tests may be required to provide information on the effect of the discharge material on communities or populations of organisms.`

  2. International policies and strategies for the remediation of land contaminated by radioactive material residues.

    PubMed

    González, Abel J

    2013-05-01

    The paper addresses the international policies and strategies for the remediation of land contaminated by radioactive material residue, its main aim being to describe the misunderstandings, evolution and status of the international paradigms in this area. Thus, the denotation and connotation of the 'remediation' and 'contamination' concepts are explored, including the ambiguity they produce in understanding of the issues by a sceptical public. Then, the international radiation protection approaches for remediation are portrayed. They derive from the recommendations of the International Commission on Radiological Protection (ICRP), which are described including their basic principles and characterization of exposure situations. Prolonged exposure situations, which are typical in cases of contaminated land, are analysed with particular detail. The newer ICRP general recommendations, as well as recent ICRP recommendations for excluding and exempting exposure situations from regulatory control and for living in long-term contaminated territories after a nuclear accident or a radiation emergency, are examined. Remediation vis-à-vis environmental protection is discussed and the non-technical factors usually involved in decision-making on remediation are examined. Finally, the international safety standards on remediation, which are being established under the aegis of the International Atomic Energy Agency (IAEA), are explored. These include the well established International Basic Safety Standards for Protection against Ionizing Radiation and for the Safety of Radiation Sources, or BSS, as well as the specific international safety requirements for remediation; a brief overview of the current process of revising the BSS is also included. In its outcome the paper suggests that the time is ripe for a simple and clear international agreement on the levels of radioactivity in territorial contamination with radioactive material that may be considered unambiguously safe.

  3. Sorption interactions of biochars and pyrogenic carbonaceous materials with anionic contaminants

    NASA Astrophysics Data System (ADS)

    Fristak, Vladimir; Moreno-Jimenez, Eduardo; Micháleková-Richveisová, Barbora; Schmidt, Hans-Peter; Bucheli, Thomas; Soja, Gerhard

    2016-04-01

    Biochar as a highly porous and carbon-rich material with a large surface area is a new player in the system of environmental remediation techniques. A wide range of valuable sorption properties of this carbonaceous pyrolysis product provides new options to solve contaminant problems in soil and water and thus may reduce the number of contaminated sites. The sorption capacity of agricultural wastes and wood processing-derived biochars has been found to be excellent due to high surface area, pore volume, and surface functional groups. However, sorption interactions and separation of xenobiotics from waste water, soil solutions or polluted surface water is very often affected by the concentration of contaminant, contact time, effects of competitive substances and mainly by the chemical form of the respective contaminant. The negative surface charge of biochar-based sorption materials supports significant sorption in particular for cationic forms of pollutants. On the other hand many environmentally critical substances occur in anionic forms (e.g. As, P, Mo, Tc). Therefore their retention and immobilization by biochar is frequently considered as problematic or limited. Besides, details about the mechanism of biochar interactions with anionic compounds and the options for surface modification are largely unexplored. This contribution presents a comparative study about production and characterization of unmodified, chemically pre-treated and post-treated biochars with respect to sorption processes of model anionic compounds (PO43-, AsO43-). The obtained results confirmed the crucial role of altering biochar properties (pH) and of surface modification for improving biochar sorption efficiency for anionic contaminants.

  4. WODA Technical Guidance on Underwater Sound from Dredging.

    PubMed

    Thomsen, Frank; Borsani, Fabrizio; Clarke, Douglas; de Jong, Christ; de Wit, Pim; Goethals, Fredrik; Holtkamp, Martine; Martin, Elena San; Spadaro, Philip; van Raalte, Gerard; Victor, George Yesu Vedha; Jensen, Anders

    2016-01-01

    The World Organization of Dredging Associations (WODA) has identified underwater sound as an environmental issue that needs further consideration. A WODA Expert Group on Underwater Sound (WEGUS) prepared a guidance paper in 2013 on dredging sound, including a summary of potential impacts on aquatic biota and advice on underwater sound monitoring procedures. The paper follows a risk-based approach and provides guidance for standardization of acoustic terminology and methods for data collection and analysis. Furthermore, the literature on dredging-related sounds and the effects of dredging sounds on marine life is surveyed and guidance on the management of dredging-related sound risks is provided.

  5. A MULTI-ORD LAB AND REGIONAL ASSESSMENT OF MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, SC

    EPA Science Inventory

    Management of contaminated sediments poses many challenges due to varied contaminants and volumes of sediments to manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks. Understanding how well the ...

  6. On the conservation of easel paintings: evaluation of microbial contamination and artists materials

    NASA Astrophysics Data System (ADS)

    Salvador, Cátia; Bordalo, Rui; Silva, Mara; Rosado, Tânia; Candeias, António; Caldeira, Ana Teresa

    2017-01-01

    Easel paintings have been considered one of the most important art expressions, constituting today outstanding works of art with important historic and cultural value. Unfortunately, due to the presence of several organic materials, these artworks have been affected by microbial contamination that among other factors can be responsible for different aesthetic and structural alterations. For this study, four easel paintings from the late nineteenth century by Giorgio Marini with evident chromatic and structural alterations due to biocontamination were analysed in order to better understand the materials used and the source of high microbial contamination within a focused conservation intervention process. For this end, both the biofilms and the painting materials were characterised by several analytical techniques. Fungal communities were found to prevail in areas with evident structural and aesthetic damages, which were confirmed by scanning electron microscopy analyses that allowed the observation of the fungal hyphae proliferation capacity. Energy-dispersive X-ray spectroscopy, μ-X-ray diffraction, μ-Raman, μ-FTIR and optical microscopy were used to further identify the painting materials. Immunological assays revealed the presence of a mixture of proteins of ovalbumin, collagen and casein, suggesting that the presence of these proteinaceous materials in these paintings is one of the main reasons of microbial biofilms appearance on the painting's surface. These approaches contribute for a better knowledge of these artworks providing at the same time relevant information for the ongoing conservation-restoration intervention.

  7. Chemical immobilization of Pb, Cu, and Cd by phosphate materials and calcium carbonate in contaminated soils.

    PubMed

    Huang, Guoyong; Su, Xiaojuan; Rizwan, Muhammad Shahid; Zhu, Yifei; Hu, Hongqing

    2016-08-01

    Soil contamination with toxic metals has increasingly become a global concern over the past few decades. Phosphate and carbonate compounds are good passivation materials for Pb immobilization, while the effect of phosphate and carbonate on the immobilization of multiple heavy metals (Pb, Cu, and Cd) in contaminated soils was seldom investigated. In this study, bone meal (BM), phosphate rock (PR), oxalic acid-activated phosphate rock (APR), super phosphate (SP), and calcium carbonate (CC) were added to the contaminated soils to evaluate the effect of phosphate materials and calcium carbonate on the immobilization of Pb, Cu, and Cd. The results showed that the pH of the treated soils increased 1.3-2.7, except SP which decreased 0.5 at most. Compared to the control treatment, all phosphates and calcium carbonate added to the polluted soils increased the fraction of residual metals, and the application of APR, PR, BM, and CC significantly reduced exchangeable and carbonate-bound fraction metals. PR and APR were the most effective for the immobilization of Pb, Cu, and Cd in the soils among these materials. Moreover, the concentrations of all metals in the toxicity characteristic leaching procedure (TCLP) leachate decreased with increasing amounts of amendments, and the concentrations of Pb in the TCLP leachate for soils treated with PR and APR were below the nonhazardous regulatory limit of 5 mg L(-1) (US Environmental Protection Agency). Based on our results, phosphate rock and oxalic acid-activated phosphate rock are effective in the immobilization of multiple metals by reducing their mobility in the co-contaminated soils.

  8. Moving fluid mud sondes, optical and acoustic sensing methods in support of coastal waterway dredging

    NASA Astrophysics Data System (ADS)

    Bostater, Charles R.; Rotkiske, Tyler

    2015-10-01

    Airborne, Satellite and In-Situ optical and acoustical imaging provides a means to characterize surface and subsurface water conditions in shallow marine systems. An important research topic to be studied during dredging operations in harbors and navigable waterways is the movement of fluidized muds before, during and after dredging operations. The fluid movement of the surficial sediments in the form of flocs, muck and mud is important to estimate in order to model the transport of solids material during dredging operations. Movement of highly turbid bottom material creates a lutocline or near bottom nephelometric layers, reduces the penetration of light reaching the water bottom. Monitoring and measurement systems recently developed for use in shallow marine areas, such as the Indian River Lagoon are discussed. Newly developed passive sondes and subsurface imaging are described. Methods and techniques for quantifying the mass density flux of total particulate matter demonstrate the use of multiple sensor systems for environmental monitoring and provide directional fluxes and movement of the fluidized solids. Airborne imaging of dredge site provide wide area surveillance during these activities. Passive sondes, optical imaging and acoustical sensors are used to understand horizontal and vertical mass flux processes. The passive sondes can be directionally oriented and are deployed during optical particle velocimetry system (OPVS) imaging of the flocs, particles and colloidal material motion. Comparison of the image based particle velocities are compared to electromagnetic and acoustic velocity imaging results. The newly developed imaging system provides a pathway for integration of subsurface hyperspectral imaging for particle compositional analysis.

  9. Bioaccumulation of metals in three freshwater mussel species exposed in situ during and after dredging at a coal ash spill site (Tennessee Valley Authority Kingston Fossil Plant).

    PubMed

    Otter, Ryan R; McKinney, David; Brown, Bobby; Lainer, Susan; Monroe, William; Hubbs, Don; Read, Bob

    2015-06-01

    On December 22, 2008, a dike containing coal fly ash at the Tennessee Valley Authority Kingston Fossil Plant (TN, USA) failed, and within months, dredging operations began to remove ash-contaminated sediments. The purpose of this study was to investigate differences in the bioaccumulation of metals in three mussel species during and after dredging operations. Mussels were caged for approximately 1 year during dredging and after, and then mussel condition index values and As, Cd, Cr, Pb, Ni, Se, Hg, U, Fe, Mg, Al, Sb, Ba, Be, Co, Cu, Mn, Mo, Ag, Sr, Tl, V, and Zn concentrations in soft tissue were determined via inductively coupled plasma-mass spectrometery. Overall, the differences observed in metal bioaccumulation and mussel health suggest that mussels in the immediate downstream area of the dredging site may have been impacted, as evidenced by a significant decrease in mussel condition index values, but that this impact did not result in increased tissue concentrations of metals.

  10. Performance of three resin-based materials for treating uranium-contaminated groundwater within a PRB.

    PubMed

    Barton, Catherine S; Stewart, Douglas I; Morris, Katherine; Bryant, David E

    2004-12-31

    Three materials that are designed to treat uranium-contaminated water were investigated. These are a cation exchange resin, IRN 77; an anion exchange resin, Varion AP; and a recently developed material called PANSIL (quartz sand coated with 2% amidoxime resin by weight). The reaction rate, capacity, and effective pH range of the three materials are reported. The capacity and conditional distribution coefficient in neutral, uranyl-contaminated synthetic groundwater containing carbonate are also reported. The suitability of each material for treating uranium-contaminated groundwater using a permeable reactive barrier (PRB) approach is then discussed. All three materials react rapidly in the pH range 5-7, reaching equilibrium in less than 4h at approximately 23 degrees C. The unconditioned cation exchange resin removed 8 g UO2 2+ per kg of resin from neutral synthetic groundwater containing 30 mg/l of UO2 2+, but a lower capacity is anticipated in groundwater with either higher ionic strength or lower UO2 2 concentrations. It operates by first acidifying the solution, then sorbing UO2 2, and can release UO2 2 when its buffering capacity has been exhausted. The anion exchange resin is very effective at removing anionic uranyl carbonate species from solutions with a pH above 5, with good specificity. Up to 50 g/kg of uranium is removed from contaminated groundwater at neutral pH. PANSIL is effective at sequestering cationic and neutral uranyl species from solutions in the pH range 4.5-7.5, with very good specificity. The capacity of PANSIL is pH-dependent, increasing from about 0.4 g/kg at pH 4.5, to about 1 g/kg at pH 6, and 1.5 g/kg around pH 7.5. In neutral groundwater containing carbonate, both the anion exchange resin and PANSIL exhibit conditional distribution coefficients exceeding 1470 ml/g, which is about an order of magnitude higher than comparable reactive barrier materials reported in the literature.

  11. Contaminant tailing in highly heterogeneous porous formations: Sensitivity on model selection and material properties

    NASA Astrophysics Data System (ADS)

    Maghrebi, Mahdi; Jankovic, Igor; Weissmann, Gary S.; Matott, L. Shawn; Allen-King, Richelle M.; Rabideau, Alan J.

    2015-12-01

    Coupled impacts of slow advection, diffusion and sorption were investigated using two heterogeneity models that differ in structure and in the mathematical framework that was used to simulate flow and transport and to quantify contaminant tailing. Both models were built using data from a highly heterogeneous exposure of the Borden Aquifer at a site located 2 km north-west of the Stanford-Waterloo experimental site at Canadian Forces Base Borden, Ontario, Canada. The inclusions-based model used a simplified representation of the different materials found at the site, while the second model was based on transitional probability geostatistics of the formation. These two models were used to investigate sensitivity of contaminant tailing on model selection and on geometric and material properties. While simulations were based on data collected at Borden, models were exercised beyond the geometric and material properties that characterize the site. Various realizations have identified very low conductive silty clay, found at volume fraction of 23.4%, as the material with dominant influence on tailing, and vertical diffusion in and out of low conductive units, affected by sorption, as the dominant transport mechanism causing tailing. The two models yielded almost identical transport results when vertical correlation lengths of silty clay were matched. Several practical implications relevant for characterization of low conductive units were identified and briefly discussed.

  12. PAMAM dendrimers and graphene: Materials for removing aromatic contaminants from water

    SciTech Connect

    DeFever, Ryan S.; Geitner, Nicholas K.; Bhattacharya, Priyanka; Ding, Feng; Ke, Pu Chun; Sarupria, Sapna

    2015-04-07

    We present results from experiments and atomistic molecular dynamics simulations on the association of naphthalene with polyamidoamine (PAMAM) dendrimers and graphene oxide (GrO). Specifically, we investigate 3rd-6th generation (G3-G6) PAMAM dendrimers and GrO with different levels of oxidation. The work is motivated by the potential applications of these materials in removing polycyclic aromatic hydrocarbon contaminants from water. Our experimental results indicate that graphene oxide outperforms dendrimers in removing naphthalene from water. Molecular dynamics simulations suggest that the prominent factors driving naphthalene association to these seemingly disparate materials are similar. Interestingly, we find that cooperative interactions between the naphthalene molecules play a significant role in enhancing their association to the dendrimers and graphene oxide. Our findings highlight that while selection of appropriate materials is important, the interactions between the contaminants themselves can also be important in governing the effectiveness of a given material. The combined use of experiments and molecular dynamics simulations allows us to comment on the possible factors resulting in better performance of graphene oxide in removing naphthalene from water.

  13. A new type of environment-friendly material and its removal efficiency for nitrate contaminated groundwater

    NASA Astrophysics Data System (ADS)

    Zhang, H.; Guo, H.

    2014-12-01

    Recently, nitrate contaminated groundwater problem is a growing concern for scholars both at home and abroad. This study developed a new type of environment-friendly material which has the ability to remove nitrate from contaminated groundwater. The material has a certain degree of mechanical strength and uniform sphericity, with waste wood and straw as raw material, to achieve the purpose of using waste treat waste. In this study, the material and fine sand are mixed and filled in glass column, which is wrapped by black tape in order to avoid light, to test the removal ability toward nitrate nitrogen with influent nitrate nitrogen concentration of 50 mg N/L. The material surface is porous, which could facilitate the reaction between the active sites in the material and nitrate in polluted groundwater, and facilitate microbes implanting on the surface. After running for two months, the nitrate nitrogen removal rate is greater than 90%, and the nitrate nitrogen and nitrite nitrogen of effluent are lower than the EPA prescribed maximum limit concentration of nitrate in drinking water(N03--N<10mg N/L, NO2--N<1mg N/L), while the ammonia nitrogen in the effluent is less than 1 mg N/L, lower than the maximum limit concentration of ammonia nitrogen in drinking water made by WHO(NH4+-N<1.5mg N/L), indicating its effective removal rate for nitrate and the absence of serious nitrite and ammonia accumulation. The developed material will have a good prospect in removing nitrate from polluted groundwater.

  14. USING SPMDS TO ASSESS MANAGEMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS.

    EPA Science Inventory

    Abstract: Dredging in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an...

  15. USING SPMDS TO ACCESS MANAGEMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS

    EPA Science Inventory

    Dredging, in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an appropria...

  16. USING SPMDS TO ACCESS MANAGMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS

    EPA Science Inventory

    Dredging, in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an appropria...

  17. An 'Early Warning System' for the prevention of dredging potential impacts on sensitive areas

    NASA Astrophysics Data System (ADS)

    Piermattei, Viviana; Martellucci, Riccardo; Pierattini, Alberto; Bonamano, Simone; Paladini de Mendoza, Francesco; Albani, Marta; Stefanì, Chiara; Madonia, Alice; Fersini, Giorgio; Marcelli, Marco

    2016-04-01

    Coastal marine ecosystems are increasingly subject to multiple pressures and stressors produced by the effects of human activities. Intense and frequent disturbances which affect marine environment can derive from dredging activity, which is a fundamental management for most ports and harbours. The potential environmental effects of dredging procedures are generally due to the excavation of material from the sea bottom and the relocation elsewhere for disposal, overflow from the dredger and loss of material from pipelines during transport. Depending on the location and the intensity of these activities the marine environment, particularly sensitive areas, may be affected by dredging. The main environmental effects can be associated with suspended sediments and increases in turbidity into the water column, which can have adverse effects on marine animals and plants by reducing light penetration and by physical disturbance. For this reason it is fundamental to implement a real time monitoring system to control and prevent negative effects, enabling a rapid response to adverse water quality conditions and a fast activation of mitigation procedures, in agreement with all the reference authorities. In this work we present the development of an innovative 'Early Warning System' based on fixed stations, ad hoc in situ surveys and forecasting models, which was applied to a dredging activity carried out in the Gulf of Gaeta (Latium, Italy). It represents an extension of the C-CEMS (Civitavecchia Coastal Environmental Monitoring System) network, which is operative in the Tyrrhenian sea since 2005.

  18. Designing open water disposal for dredged muddy sediments

    NASA Astrophysics Data System (ADS)

    McAnally, William H.; Adamec, Stephen A.

    1987-11-01

    Open water disposal of muddy sediments in the estuarine environment is practiced to minimize dredging costs and to preserve contained disposal site capacity. Open water sites are usually either dispersive or retentive. Dispersive sites are used in the expectation that disposed sediments will not remain there, but will be transported out of the site, leaving room for additional disposal. Retentive sites are designed to ensure that disposed sediments mostly remain within the site. Choice of one of these approaches depends on the site character, sediment character, and disposal quantities. Design of disposal management plans for both site types is accomplished by use of field observations, laboratory tests, and numerical modeling. Three disposal site studies illustrate the methods used. At the Alcatraz site in San Francisco Bay, a dispersive condition is maintained by use of constraints on dredged mud characteristics that were developed from laboratory tests on erosion rates and from numerical modeling of the dump process. Field experiments were designed to evaluate the management procedure. In Corpus Christi Bay a numerical model was used to determine how much disposed sediment returns to the navigation channel, and to devise a location for disposal that will minimize that return. In Puget Sound a model has been used to ensure that most of the disposed material remains in the site. New techniques, including a piped disposal through 60 m of water, were investigated.

  19. The effect of contaminant desorption on assimilation of sediment-sorbed hydrophobic contaminants by deposit-feeders

    SciTech Connect

    Brownawell, B.; Lamoureux, E.; McElroy, A.; Lopez, G.; Ahrens, M.

    1995-12-31

    The literature shows that assimilation efficiencies of lab-spiked nonpolar contaminants by deposit-feeders are generally much greater than the assimilation of the organic carbon sorbent matrix. Thus the rate and extent of contaminant desorption into the aqueous gut environment is likely to play a significant role in uptake from sediments. Contaminated New York Harbor sediments were examined in parallel desorption kinetic and bioaccumulation studies with the clam Yoldia limatula. A clear relationship was observed between the contaminant desorption rates over the first two days and organism/sediment bioaccumulation factors (BAF) determined across a wide range of individual PCBs, PAHs, and linear alkylbenzenes. Bioavailability was affected by hydrophobicity, shape of the contaminant, and contaminant class/source. Lower bioavailability of PAH may be the result of matrix associations with soot or fine coal particles. Interestingly, contaminant desorption/bioavailability were not influenced greatly by depth in the sediment core. The authors have initiated a study to determine the critical chemical and biological factors that control contaminant assimilation. They hope that it will become possible to replace expensive biological exposure studies with simple desorption tests when assessing the risk associated with contaminated sediments or dredge materials.

  20. Influence of fermentation and drying materials on the contamination of cocoa beans by ochratoxin A.

    PubMed

    Dano, Sébastien Djédjé; Manda, Pierre; Dembélé, Ardjourma; Kouassi Abla, Ange Marie-Joseph; Bibaud, Joel Henri; Gouet, Julien Zroh; Ze Maria Sika, Charles Bruno

    2013-11-28

    Ochratoxin A (OTA) is a mycotoxin produced mainly by species of Aspergillus and Penicillium. Contamination of food with OTA is a major consumer health hazard. In Cote D'Ivoire, preventing OTA contamination has been the subject of extensive study. The current study was conducted to evaluate the influence of fermentation and drying materials on the OTA content in cocoa. For each test, 7000 intact cocoa pods were collected, split open to remove the beans, fermented using 1 of 3 different materials, sun-dried on 1 of 3 different platform types and stored for 30 days. A total of 22 samples were collected at each stage of post-harvesting operations. The OTA content in the extracted samples was then quantified by high-performance liquid chromatography. OTA was detected in beans at all stages of post-harvesting operations at varying levels: pod-opening (0.025 ± 0.02 mg/kg), fermentation (0.275 ± 0.2 mg/kg), drying (0.569 ± 0.015 mg/kg), and storage (0.558 ± 0.04 mg/kg). No significant relationships between the detected OTA level and the materials used in the fermentation and drying of cocoa were observed.

  1. Impact of nanoscale zero valent iron on geochemistry and microbial populations in trichloroethylene contaminated aquifer materials.

    PubMed

    Kirschling, Teresa L; Gregory, Kelvin B; Minkley, Edwin G; Lowry, Gregory V; Tilton, Robert D

    2010-05-01

    Nanoscale zerovalent iron (NZVI) particles are a promising technology for reducing trichloroethylene (TCE) contamination in the subsurface. Prior to injecting large quantities of nanoparticles into the groundwater it is important to understand what impact the particles will have on the geochemistry and indigenous microbial communities. Microbial populations are important not only for nutrient cycling, but also for contaminant remediation and heavy metal immobilization. Microcosms were used to determine the effects of NZVI addition on three different aquifer materials from TCE contaminated sites in Alameda Point, CA, Mancelona, MI, and Parris Island, SC. The oxidation and reduction potential of the microcosms consistently decreased by more than 400 mV when NZVI was added at 1.5 g/L concentrations. Sulfate concentrations decreased in the two coastal aquifer materials, and methane was observed in the presence of NZVI in Alameda Point microcosms, but not in the other two materials. Denaturing gradient gel electrophoresis (DGGE) showed significant shifts in Eubacterial diversity just after the Fe(0) was exhausted, and quantitative polymerase chain reaction (qPCR) analyses showed increases of the dissimilatory sulfite reductase gene (dsrA) and Archaeal 16s rRNA genes, indicating that reducing conditions and hydrogen created by NZVI stimulate both sulfate reducer and methanogen populations. Adding NZVI had no deleterious effect on total bacterial abundance in the microcosms. NZVI with a biodegradable polyaspartate coating increased bacterial populations by an order of magnitude relative to controls. The lack of broad bactericidal effect, combined with the stimulatory effect of polyaspartate coatings, has positive implications for NZVI field applications.

  2. The Performance of Nearshore Dredge Disposal at Ocean Beach, San Francisco, California, 2005-2007

    USGS Publications Warehouse

    Barnard, Patrick L.; Erikson, Li H.; Hansen, Jeff E.; Elias, Edwin

    2009-01-01

    Ocean Beach, California, contains an erosion hot spot in the shadow of the San Francisco ebb tidal delta that threatens valuable public infrastructure as well as the safe recreational use of the beach. In an effort to reduce the erosion at this location a new plan for the management of sediment dredged annually from the main shipping channel at the mouth of San Francisco Bay was implemented in May 2005 by the United States Army Corps of Engineers, San Francisco District (USACE). The USACE designated a temporary nearshore dredge disposal site for the annual disposal of about 230,000 m3 (300,000 yd3) of sand about 750 m offshore and slightly south of the erosion hot spot, in depths between approximately 9 and 14 m. The site has now been used three times for a total sediment disposal of about 690,000 m3 (about 900,000 yds3). The disposal site was chosen because it is in a location where strong tidal currents and open-ocean waves can potentially feed sediment toward the littoral zone in the reach of the beach that is experiencing critical erosion, as well as prevent further scour on an exposed outfall pipe. The onshore migration of sediment from the target disposal location might feed the primary longshore bar or the nearshore zone, and provide a buffer to erosion that peaks during winter months when large waves impact the region. The United States Geological Survey (USGS) has been monitoring and modeling the bathymetric evolution of the test dredge disposal site and the adjacent coastal region since inception in May 2005. This paper reports on the first 2.5 years of this monitoring program effort (May 2005 to December 2007) and assesses the short-term coastal response. Here are the key findings of this report: *Approximately half of the sediment that has been placed in the nearshore dredge-disposal site during the 2.5 years of this study remains within the dredge focus area. *In the winter of 2006-7, large waves transported the dredge-mound material onshore. *High

  3. The dynamics of fine-grain sediment dredged from Santa Cruz Harbor

    USGS Publications Warehouse

    Storlazzi, Curt D.; Conaway, Christopher H.; Presto, M. Katherine; Logan, Joshua B.; Cronin, Katherine; van Ormondt, Maarten; Lescinski, Jamie; Harden, E. Lynne; Lacy, Jessica R.; Tonnon, Pieter K.

    2011-01-01

    In the fall and early winter of 2009, a demonstration project was done at Santa Cruz Harbor, California, to determine if 450 m3/day of predominantly (71 percent) mud-sized sediment could be dredged from the inner portion of the harbor and discharged to the coastal ocean without significant impacts to the beach and inner shelf. During the project, more than 7600 m3 of sediment (~5400 m3 of fine-grain material) was dredged during 17 days and discharged approximately 60 m offshore of the harbor at a depth of 2 m on the inner shelf. The U.S. Geological Survey's Pacific Coastal and Marine Science Center was funded by the U.S. Army Corps of Engineers and the Santa Cruz Port District to do an integrated mapping and process study to investigate the fate of the mud-sized sediment dredged from the inner portion of Santa Cruz Harbor and to determine if any of the fine-grain material settled out on the shoreline and/or inner shelf during the fall and early winter of 2009. This was done by collecting highresolution oceanographic and sediment geochemical measurements along the shoreline and on the continental shelf of northern Monterey Bay to monitor the fine-grain sediment dredged from Santa Cruz Harbor and discharged onto the inner shelf. These in place measurements, in conjunction with beach, water column, and seabed surveys, were used as boundary and calibration information for a three-dimensional numerical circulation and sediment dynamics model to better understand the fate of the fine-grain sediment dredged from Santa Cruz Harbor and the potential consequences of disposing this type of material on the beach and on the northern Monterey Bay continental shelf.

  4. Estimation of Internal Radiation Dose from both Immediate Releases and Continued Exposures to Contaminated Materials

    SciTech Connect

    Napier, Bruce A.

    2012-03-26

    A brief description is provided of the basic concepts related to 'internal dose' and how it differs from doses that result from radioactive materials and direct radiation outside of the body. The principles of radiation dose reconstruction, as applied to both internal and external doses, is discussed based upon a recent publication prepared by the US National Council on Radiation Protection and Measurements. Finally, ideas are introduced related to residual radioactive contamination in the environment that has resulted from the releases from the damaged reactors and also to the management of wastes that may be generated in both regional cleanup and NPP decommissioning.

  5. Distribution of chlorinated organic pollutants in harbor sediments of Livorno (Italy): a multivariate approach to evaluate dredging sediments.

    PubMed

    Cicero, A M; Mecozzi, M; Morlino, R; Pellegrini, D; Veschetti, E

    2001-10-01

    Dredging is a very important procedure for harbor management. In Italy the guidelines for the offshore dumping of dredged materials are issued by the Ministry of Environment. They described a few steps of dredging activities, such as the sampling strategy, but do not deal with limits or guide-values for the chemical, physical and biological composition of the resulting sediments. The quality of dredged materials is mainly dependent on the presence of inorganic and organic pollutants. In particular, polychlorinated biphenyls (PCBs) and organo-chlorinated pesticides are seen as a high priority in marine environment by international organizations because of their persistence, toxicity and bioaccumulation capacity. In this article the presence of some PCBs and organo-chlorinated pesticides in sediment samples collected from the harbor of Livorno (Northern Tyrrhenian Sea) was investigated. The concentration of HCHs, Aldrin, Chlordanes, DDEs, DDTs, and PCBs in 12 representative sites ranged between <1 microg kg(-1) and 95, 19, 32, 35, 107, and 111 microg kg(-1), respectively. The application of univariate and multivariate statistical techniques, such as linear regression analysis and principal component analysis, to the experimental data showed a different distribution of PCBs in the two sediment layers. On the contrary, the vertical distribution of the other investigated pollutants was more homogeneous and affected by random variability. The multivariate approach was an important tool to establish more rational criteria for the management of dredged materials.

  6. Influence of material and tube size on DUWLs contamination in a pilot plant.

    PubMed

    Sacchetti, Rossella; De Luca, Giovanna; Zanetti, Franca

    2007-01-01

    Numerous studies have shown that the water discharged from dental unit waterlines (DUWLs) contains high densities of bacteria, especially non-fermenting Gram negative bacteria. The aim of the present study was to investigate how the material (polyethylene-PE and polytetrafluorethylene-PTFE) and size (1.6 and 4.0 mm) of 4 waterlines in a pilot plant influence the level of contamination in the output water. The water contamination was assessed by analyzing the trend of the heterotrophic plate counts at 22 degrees C as a function of time and by testing for non-fermenting Gram negative bacteria. In all waterlines, the bacterial density increased exponentially during the first months and thereafter remained between 10(4) and 10(6) cfu/ml. However, the plate count at 22 degrees C was lower in the water from PTFE tubes and from larger size tubes. Comamonas acidovorans, Pseudomonas aeruginosa and Pseudomonas fluorescens were isolated. Pseudomonas aeruginosa, responsible for infections associated with dental practice, was never isolated in the output water from PTFE tubes. In order to control bacterial contamination the results suggest the use of waterlines made of PTFE on account of their ability to inhibit the colonization and growth of Pseudomonas aeruginosa.

  7. Appearance and water quality of turbidity plumes produced by dredging in Tampa Bay, Florida

    USGS Publications Warehouse

    Goodwin, Carl R.; Michaelis, D.M.

    1984-01-01

    Turbidity plumes in Tampa Bay, Florida, produced during ship-channel dredging operations from February 1977 to August 1978, were monitored in order to document plume appearance and water quality, evaluate plume influence on the characteristics of Tampa Bay water, and provide a data base for comparison with other areas that have similar sediment, dredge, placement, containment, and tide conditions. The plumes investigated originated from the operation of one hopper dredge and three cutterhead-pipeline dredges. Composition of bottom sediment was found to vary from 85 percent sand and shell fragments to 60 percent silt and clay. Placement methods for dredged sediment included beach nourishment, stationary submerged discharge, oscillating surface discharge, and construction of emergent dikes. Tidal currents ranged from slack water to flow velocities of 0.60 meter per second. Plumes were monitored simultaneously by (1) oblique and vertical 35-millimeter aerial photography and (2) water-quality sampling to determine water clarity and concentrations of nutrients, metals, pesticides, and industrial compounds. Forty-nine photographs depict plumes ranging in length from a few tens of meters to several kilometers and ranging in turbidity level from <10 to 200,000 nephelometric turbidity units. The most visible turbidity plumes were produced by surface discharge of material with high sand content into unconfined placement areas during times of strong tidal currents. The least visible turbidity plumes were produced by discharge of material with high silt and clay content into areas enclosed by floating turbidity barriers during times of weak tidal currents. Beach nourishment from hopper-dredge unloading operations also produced plumes of low visibility. Primary turbidity plumes were produced directly by dredging and placement operations; secondary plumes were produced indirectly by resuspension of previously deposited material. Secondary plumes were formed both by erosion, in

  8. Instrumentation of dredge spoil for landfill construction

    SciTech Connect

    Byle, M.J.; McCullough, M.L.; Alexander, R.; Vasuki, N.C.; Langer, J.A.

    1999-07-01

    The Delaware Solid Waste Authority's Northern Solid Waste Management Center is located outside of Wilmington Delaware at Cherry Island, a former dredge disposal site. Dredge spoils, of very low permeability, range in depths up to 30 m (100 feet) which form a natural liner and the foundation for the 140 ha (350-acre) municipal solid waste landfill. The soils beneath the landfill have been extensively instrumented to measure pore pressure, settlement and deflections, using inclinometer casings, standpipe piezometers, vibrating wire piezometers, pneumatic piezometers, settlement plates, liquid settlement gages, total pressure cells and thermistors. The nature of the existing waste and anticipated settlements (up to 6 m (19 feet)) have required some unique installation details. The instrumentation data has been integral in planning the landfilling sequence to maintain perimeter slope stability and has provided key geotechnical parameters needed for operation and construction of the landfill. The performance of the instrumentation and monitoring results are discussed.

  9. Sorption/Desorption and Transport of Trichloroethene in Freshly-amended, Synthetically- aged, and Field-contaminated Aquifer Material

    NASA Astrophysics Data System (ADS)

    Johnson, G. R.; Norris, D. K.; Brusseau, M. L.

    2008-12-01

    This study investigates the effect of long-term contaminant aging on the sorption/desorption and transport of trichloroethene in a low organic-carbon content aquifer material collected from the source zone of a chlorinated-solvent contaminated federal Superfund site in Arizona. This was accomplished by comparing elution behavior for field-contaminated, synthetically-aged (contact times of approximately four years), and freshly-amended aquifer material. Elution of trichloroethene exhibited extensive low-concentration tailing, despite minimal retention of trichloroethene by the aquifer material. The observed nonideal behavior indicates significant mass-transfer constraints influenced trichloroethene transport in this aquifer material. The elution behavior of trichloroethene for the field-contaminated and aged treatments was essentially identical to that observed for the fresh treatments. In addition, the results of three independent mass- balance analyses, total mass eluted, solvent-extraction analysis of residual sorbed mass, and flow- interruption rebound, showed equivalent recoveries for the aged and fresh treatments. These results indicate that long-term contaminant aging did not significantly influence the transport and fate behavior of trichloroethene in this low organic-carbon aquifer material. The observed nonideal behavior of trichloroethene (i.e., nonlinear sorption and significantly rate-limited sorption/desorption) suggests physically condensed carbonaceous material, comprising 61% of this media's organic-carbon content, mediates the transport and fate behavior of trichloroethene in this low organic-carbon content aquifer material.

  10. Decimeter Positioning For Dredging and Hydrographic Surveying

    DTIC Science & Technology

    1991-01-01

    Torrence, CA. Leick, Alfred and Liu, Quanjiang, 1991: Investigation of the Use of the Global Positioning System ( GPS ) to Determine Tides and Water Level...ABSTRACT (Maximum 200 words) The U. S. Army Corps of Engineers initiated development of a prototype decimeter defferential GPS positioning system for...ABSTRACT The U.S. Army Corps of Engineers initiated development of a prototype decimeter differential GPS positioning system for dredging and

  11. Contamination control in hybrid microelectronic modules. Part 2: Selection and evaluation of coating materials

    NASA Technical Reports Server (NTRS)

    Himmel, R. P.

    1975-01-01

    The selection, test, and evaluation of organic coating materials for contamination control in hybrid circuits is reported. The coatings were evaluated to determine their suitability for use as a conformal coating over the hybrid microcircuit (including chips and wire bonds) inside a hermetically sealed package. Evaluations included ease of coating application and repair and effect on thin film and thick film resistors, beam leads, wire bonds, transistor chips, and capacitor chips. The coatings were also tested for such properties as insulation resistance, voltage breakdown strength, and capability of immobilizing loose particles inside the packages. The selected coatings were found to be electrically, mechanically, and chemically compatible with all components and materials normally used in hybrid microcircuits.

  12. Strike-through of moist contamination by woven and nonwoven surgical materials.

    PubMed Central

    Laufman, H; Eudy, W W; Vandernoot, A M; Harris, C A; Liu, D

    1975-01-01

    A test is described which correlates the stress of stretching surgical gown and drape material with moist bacterial strike-through. By application of this test to a number of woven and nonwoven surgical gown and drape materials, it was found that not all of these materials, either woven or nonwoven, are impermeable to moist contamination for equal periods of time. Nonwoven disposable materials now in use range from those which remain impermeable to moist bacterial permeation through all tests while some remain impermeable for limited periods of time, and others almost immediately permeable to moist bacterial penetration. The same situation holds for woven materials. Under conditions of our test, Quarpel treated Pima tight-woven cotton cloth was impermeable to moist bacterial strike-through, through up to 75 washing and sterilizing cyclings, while ordinary linen and untreated Pima cloth permitted bacterial permeation almost immediately. These results have significance in lengthy wet surgical operations. Images Fig. 1. Fig. 2. Fig. 3. Fig. 4. PMID:1094972

  13. Development of a standard reference material for Cr(vi) in contaminated soil

    USGS Publications Warehouse

    Nagourney, S.J.; Wilson, S.A.; Buckley, B.; Kingston, H.M.S.; Yang, S.-Y.; Long, S.E.

    2008-01-01

    Over the last several decades, considerable contamination by hexavalent chromium has resulted from the land disposal of Chromite Ore Processing Residue (COPR). COPR contains a number of hexavalent chromium-bearing compounds that were produced in high temperature industrial processes. Concern over the carcinogenic potential of this chromium species, and its environmental mobility, has resulted in efforts to remediate these waste sites. To provide support to analytical measurements of hexavalent chromium, a candidate National Institute of Standards and Technology (NIST) Standard Reference Material?? (SRM 2701), having a hexavalent chromium content of approximately 500 mg kg -1, has been developed using material collected from a waste site in Hudson County, New Jersey, USA. The collection, processing, preparation and preliminary physico-chemical characterization of the material are discussed. A two-phase multi-laboratory testing study was carried out to provide data on material homogeneity and to assess the stability of the material over the duration of the study. The study was designed to incorporate several United States Environmental Protection Agency (USEPA) determinative methods for hexavalent chromium, including Method 6800 which is based on speciated isotope dilution mass spectrometry (SIDMS), an approach which can account for chromium species inter-conversion during the extraction and measurement sequence. This journal is ?? The Royal Society of Chemistry 2008.

  14. Screening-level risk assessment applied to dredging of polluted sediments from Guanabara Bay, Rio de Janeiro, Brazil.

    PubMed

    Silveira, Ana Elisa F; Nascimento, Juliana R; Sabadini-Santos, Elisamara; Bidone, Edison D

    2017-03-16

    Guanabara Bay is characterized by predominant eutrophication and anoxic sediments with a mixture of pollutants. The risk prognosis associated with the dumping of its dredged sediments into the open ocean was addressed by our algorithm. Our algorithm could prioritize areas, characterize major processes related to dredging, measure the potential risk of sediments, and predict the effects of sediment mixing. The estimated risk of dredged sediment was >10-fold than that of ocean sediments. Among metals, mercury represented 50-90% of the total risk. The transfer of dredged material into the ocean or internal dumping in the bay requires a 1:10 dilution to mitigate the risk and bring the risk levels close to that in the EPA criteria, below which there is less likelihood of adverse effects to the biota, and a 1:100 dilution to maintain the original characteristics of the ocean disposal control area. Our algorithm indicator can be used in the design of both aquatic and continental disposal of dredged materials and their management.

  15. Monitoring contamination due to materials outgassing by QCM-based sensors

    NASA Astrophysics Data System (ADS)

    Dirri, Fabrizio

    2016-07-01

    F. Dirri, E. Palomba, A. Longobardo, D. Biondi, A. Boccaccini, E. Zampetti, B. Saggin, D. Scaccabarozzi, A. Tortora, A. Nanni, J. Alves, A. Tighe Outgassing from spacecraft materials often occurs and degassing contaminants can degrade critical spacecraft surfaces, such as optical systems, solar panels, thermal radiators and thermal management systems. The main contaminants are the water adsorbed by cold surface, organics from spacecraft structure, electronics, insulation and thrusters firings [1]. Thus, it is fundamental to monitor these low-outgassing rates especially in a long duration mission: Quartz Crystal Microbalance (QCM) based sensors (i.e. single and double crystal configurations) are a suitable instruments to monitor step by step these degradation processes which occur in space conditions. The Contamination Assessment Microbalance (CAM) is a device aimed at monitoring in-orbit contamination of sensitive surfaces and payloads on ESA's future satellites. The device, developed by a consortium of Italian research Institutes, is based on QCM technology, previously considered by NASA and ESA experiments performed on Space Shuttle and satellite missions [2,3,4]. CAM is a low mass (200 grams for the sensor head), low volume (smaller than 5x5x5 cm3 for the sensor head) and low power consumption (less than 1.5 W) sensor. The device is composed by: 1) the Sensor Head, containing a sensing crystal (which measures the deposited contaminant mass), a reference crystal (used as frequency reference), their related Proximity Electronics (PE) and a Temperature Control System (TCS); 2) the Main Electronics Unit (MEU), which acquires the signal in output from Sensor Head unit; 3) the Harness connecting Sensor Head and MEU; 4) the User Interface (UI) to read and display the data. The device shows several improvements, i.e. possibility to measure directly the crystal temperature (with an accuracy better than 0.1°C), large measurable mass range (from 5•10-9 to 7•10-4 g/cm2

  16. Influencing factors on particle-bound contaminant transport in the Elbe estuary

    NASA Astrophysics Data System (ADS)

    Kleisinger, Carmen; Haase, Holger; Schubert, Birgit

    2016-04-01

    contaminants and remove them temporarily or in long term from further transport. In the past, highly contaminated sediments were deposited in these retention areas. The estimated total contamination load in these areas exceeds the annual contamination load entering the estuary by a factor up to 11 (BfG, 2014). Monitoring in sedimentation areas by the means of sediment cores gave no indications for current distinct sedimentation or erosion. It is assumed that the highly contaminated sediments in greater depths are most likely to be resuspended only due to extreme events or human intervention (BfG, 2014). Additionally, dredging and depositing of dredged sediments in the Elbe estuary influence the transport of contaminated sediments. Deposition of dredged material further downstream the dredging site accelerates the transport of particulate matter towards the sea. As the residence time of particulate matter within the estuary varies by many influencing factors, mass balances are associated with large uncertainties and accordingly, annual particle-bound contaminant loads released into the North Sea cannot be calculated reliable. Ackermann, F. and Schubert, B. (2007): Trace metals as indicators for the dynamics of (suspended) particulate matter in the tidal reach of the River Elbe. Sediment Dynamics and Pollutant Mobility in Rivers. U. Förstner and B. Westrich. Heidelberg, Springer Verlag, 296-304. BfG (2014). Sedimentmanagement Tideelbe - Strategien und Potenziale - Systemstudie II. Ökologische Auswirkungen der Unterbringung von Feinmaterial. BfG-1763. Kappenberg, J. and Fanger, H.-U. (2007): "Sedimenttransportgeschehen in der tidebeeinflussten Elbe, der Deutschen Bucht und in der Nordsee." 2007/20, 123. Kowalewska, G., Belzunce-Segarra, M. J., Schubert, B., Heininger, P. and Heise, S. (2011): The Role of Sediments in Coastal Monitoring. Chemical Marine Monitoring. P. Quevauviller, P. Roose and G. Verreet. Chichester, West Sussex, UK, John Wiley & Sons Ltd., 384-388.

  17. Assessment of the Use of Natural Materials for the Remediation of Cadmium Soil Contamination

    PubMed Central

    de O. Pinto, Tatiana; García, Andrés C.; Guedes, Jair do N.; do A. Sobrinho, Nelson M. B.; Tavares, Orlando C. H.

    2016-01-01

    Rice plants accumulate cadmium (Cd2+) within the grain, increasing the danger of human exposure. Natural materials have been used in soil remediation, but few studies have examined the risks (based on the bioavailability of these metals to plants) of using these materials, so the practice remains controversial. In the present study, we evaluated the effectiveness of biochar produced from sugarcane bagasse, vermicompost (VC), vermicompost solid residue (VCR) and humin for remediation of Cd2+-contaminated soils. We characterized the interactions between these materials and Cd2+ and evaluated their capacity to alter Cd2+ availability to rice plants. Our results show that under the conditions in this study, biochar and humin were not effective for soil remediation. Although biochar had high Cd2+ retention, it was associated with high Cd2+ bioavailability and increased Cd2+ accumulation in rice plants. VC and VCR had high Cd2+ retention capacity as well as low Cd2+ availability to plants. These characteristics were especially notable for VCR, which was most effective for soil remediation. The results of our study demonstrate that in the tested materials, the bioavailability of Cd2+ to plants is related to their structural characteristics, which in turn determine their retention of Cd2+. PMID:27341440

  18. Attenuation of landfill leachate by clay liner materials in laboratory columns: 2. Behaviour of inorganic contaminants.

    PubMed

    Thornton, S F; Lerner, D N; Tellam, J H

    2001-02-01

    The chemical attenuation of inorganic contaminants in methanogenic landfill leachate, spiked with heavy metals (Cd, Cd, Ni and Zn), by two UK clay liner materials was compared in laboratory columns over 15 months. Ammonium was attenuated by ion-exchange but this attenuation was finite and when exhausted, NH4 passed through the liners at concentrations found in the leachate. The breakthrough behaviour of NH4 could be described by a simple distribution coefficient. Heavy metals were attenuated by sorption and precipitation of metal sulphide and carbonate compounds near the top of the liner. Adequate SO4 and CaCO3 in the liner is necessary to ensure the long term retention of heavy metals, and pH buffering agents added to stabilise reactive metal fractions should be admixed with the liner. Some metals may not be chemically attenuated by clay liners due to the formation of stable complexes with organic and/or colloidal fractions in leachate. Flushing of the liners with oxygenated water after leachate caused mobilisation of attenuated contaminants. Sorbed NH4 was released by the liners but groundwater loadings were manageable. Re-oxidation of metal sulphides under these conditions resulted in the release of heavy metals from the liners when the pH buffering capacity was poor. Contaminant attenuation by the clay liners was similar and the attenuation of NH4 and heavy metals could be predicted from the geochemical properties of the liner using simple tests. A conceptual model of clay liner performance is presented. Chemical attenuation of inorganic pollutants can be included in containment liner design to produce a dual reactive-passive barrier for landfills.

  19. Evaluation of the Contamination in Vacuum Due to Plume Effects and Materials Outgassing

    NASA Astrophysics Data System (ADS)

    Delamare, B.; Palerm, S. Carrat, J.-M.

    2009-01-01

    This paper is devoted to the methodoloy and techniques used by ASTRIUM-ST to estimate the contamination in vacuum. This estimation is particularly important for the proper operation of the optical instruments and solar arrays of space vehicles such as the international space station (ISS). The contamination in vacuum has two main sources: plume effects and materials outgassing. Regarding the estimation of plume effects, the gas flow inside the nozzel is first computer using a parabolized Navier-Stokes turbulent numerical code (PNSTURDI). The resulting flow at the nozzel exit section is then used as an input to simulate the plume expansion in vacuum with the Direct Simulation Monte Carlo (DSMC) technique (IEMC code). The Plume is next approximated by a classical form of radial straight streamlines coming from a common source point. The resulting fitting function is implemented in the RAYJET code with uses a "ray launch" technique. Indeed, the impacted body is decribed by simple elementary surfaces, and when a ray coming from the nozzle impacts on one of these surfaces, the impingement effects (pressure, thermal and molecular fluxes) are evaluated through local models. Since the relative motion of the body with regard to the nozzle is taken into account, the integrated plume effects (energy, mass deposits) are estimated along its whole trajectory. As an application of this technique, the evaluation of the contamination on the ISS during the approach phase of the automatic transfer vehicle (ATV) is presented. As for the estimation of outgassing, two calculation methods are used. The first on considers the view factors theory based on the Lambertian law and uses the RAYOUT code. In the second technique, the intermolecular collisions between the molecules emitted by the materials and their interactions with the walls are computed using a DSMC approach. As an application, the case of the ATV solar generation system (SGS) outgassing is presented with input data supplied

  20. Printed paper and board food contact materials as a potential source of food contamination.

    PubMed

    Van Bossuyt, Melissa; Van Hoeck, Els; Vanhaecke, Tamara; Rogiers, Vera; Mertens, Birgit

    2016-11-01

    Food contact materials (FCM) are estimated to be the largest source of food contamination. Apart from plastics, the most commonly used FCM are made of printed paper and board. Unlike their plastic counterparts, these are not covered by a specific European regulation. Several contamination issues have raised concerns towards potential adverse health effects caused by exposure to substances migrating from printed paper and board FCM. In the current study, an inventory combining the substances which may be used in printed paper and board FCM, was created. More than 6000 unique compounds were identified, the majority (77%) considered non-evaluated in terms of potential toxicity. Based on a preliminary study of their physicochemical properties, it is estimated that most of the non-evaluated single substances have the potential to migrate into the food and become bioavailable after oral intake. Almost all are included in the FACET tool, indicating that their use in primary food packaging has been confirmed by industry. Importantly, 19 substances are also present in one of the lists with substances of concern compiled by the European Chemicals Agency (ECHA). To ensure consumer safety, the actual use of these substances in printed paper and board FCM should be investigated urgently.

  1. Background in the context of land contaminated with naturally occurring radioactive material.

    PubMed

    Read, D; Read, G D; Thorne, M C

    2013-06-01

    The financial implications of choosing a particular threshold for clearance of radioactively contaminated land are substantial, particularly when one considers the volume of naturally occurring radioactive material (NORM) created each year by the production and combustion of fossil fuels and the exploitation of industrial minerals. Inevitably, a compromise needs to be reached between the level of environmental protection sought and the finite resources available for remediation. In the case of natural series radionuclides, any anthropogenic input is always superimposed on the inventory already present in the soil; this 'background' inventory is conventionally disregarded when assessing remediation targets. Unfortunately, the term is not well defined and the concept of 'background dose' is open to alternative interpretations. In this paper, we address the issue of natural background from a geochemical rather than from a solely radiological perspective, illustrating this with an example from the china clay industry. We propose a simple procedure for decision making based on activity concentrations of primordial radionuclides and their progeny. Subsequent calculations of dose need to take into account the mineralogical and chemical characteristics of the contamination, which in the case of NORM are invariably reflected in uranium series disequilibrium.

  2. The presence of asbestos-contaminated vermiculite attic insulation or other asbestos-containing materials in homes and the potential for living space contamination.

    PubMed

    Spear, Terry M; Hart, Julie F; Spear, Tessa E; Loushin, Molly M; Shaw, Natalie N; Elashhab, Mohamed I

    2012-10-01

    Asbestos-contaminated vermiculite attic insulation (VAI) produced from a mine near Libby, Montana, may be present in millions of homes along with other commercial asbestos-containing materials (ACM). The primary goal of the research described here was to develop and test procedures that would allow for the safe and effective weatherization of low-income homes with asbestos. The presence of asbestos insulation was confirmed by bulk sampling of the suspect asbestos material. The homes were then tested for the presence of asbestos fibers in the living spaces. All 40 homes containing VAI revealed the presence of amphibole asbestos in bulk samples. Asbestos (primarily chrysotile) was confirmed in bulk samples of ACM collected from 18 homes. Amphibole asbestos was detected in the living space of 12 (26%) homes, while chrysotile asbestos was detected in the living space of 45 (98%) homes. These results suggest that asbestos sources in homes can contribute to living space contamination.

  3. Recyclability of bottom ash mixed with dredged soils according to the transportation distance and mixing ratio through the estimation of CO2 emissions.

    PubMed

    Noh, Sookack; Son, Younghwan; Yoon, Taegang; Bong, Taeho

    2015-06-01

    Bottom ash and dredged soils can be used as construction materials because they are similar in physical characteristics to natural aggregates. However, whenever such byproducts as bottom ash and dredged soils are used, the energy efficiency of recycling is offset to a certain degree by emissions from transportation. The objective of this study is to analyze the environmental efficiency of recycling bottom ash and dredged soils through the estimation of CO2 emissions, considering both transportation distance and the mixing ratio. Agricultural reservoirs were selected as the final destinations of these recycled materials. This analysis demonstrated that using 100% bottom ash emits less CO2 than using natural aggregates when the ash is transported less than 35.15 km. This breakeven distance increases exponentially with the mass fraction of admixed dredged soil. However, admixture with natural soils does not affect the breakeven distance. Using the breakeven distances, the effective area with which it is efficient to recycle bottom ash was delineated. When dredged soil is admixed to a mass fraction of 70%, the effective area covers most of South Korea. In addition, 100% bottom ash was efficient in 1622 reservoirs (9.45%) in terms of CO2 emissions, and the mixture with 30% bottom ash and 70% dredged soils is efficient in 98.83% of all of the reservoirs in Korea. Bottom ash is most useful for reducing CO2 emissions when it is mixed with dredged soils, which are a byproduct of construction found on-site. This result is meaningful because bottom ash and dredged soils are complementary in their physical characteristics, and they need to be mixed before use as construction materials. The recycling of bottom ash becomes even more attractive with anticipated improvements in fuel efficiency.

  4. Contribution of Two Different Packaging Material to Microbial Contamination of Peaches: Implications in Their Microbiological Quality

    PubMed Central

    Patrignani, Francesca; Siroli, Lorenzo; Gardini, Fausto; Lanciotti, Rosalba

    2016-01-01

    Aim: Aim of this work was understanding the microbial transfer dynamics from packaging to packed peaches in relation to the packaging used. Method and Results: A challenge test was performed, inoculating Escherichia coli, Pseudomonas spp. and Saccharomyces cerevisiae on cardboards and RPC (Reusable Plastic Containers), and monitoring their cell loads on fruits according to a probabilistic model and a Response Surface Methodology (RSM) in relation to several independent variables (number of fruit lesions, fruit temperature storage and commercialization time). The data recorded on packed peaches for Pseudomonas and S. cerevisiae were modeled to fit the second order model to study the main, interactive and quadratic effects of the independent variables on the cell loads of target microorganisms as well as on the shelf-life of the fruits in relation to packaging material used. The data collected for E. coli were codified as presence (1) or absence (0) and modeled with a logistic regression analysis to assess the probability of E. coli transferring from packaging to fruits in relation to the adopted variables. The data showed a higher contamination frequency of the fruits packed in plastic than in cardboard. Increasing the storage temperature and the number of lesions, the probability of transferring of E. coli from packaging materials to fruits increased, independently on commercialization time or packaging used. For Pseudomonas, the contamination levels detected on fruits packaged in plastic were significantly higher compared to those found on fruits packed in cardboard, independently on the considered variables. The polynomial equations showed the S. cerevisiae cell loads of fruits stored in plastic was positively affected by the quadratic term of temperature. Conclusions: the use of cardboard, compared to plastic, can significantly reduce the potential of microbial transferring from packaging to fruits. The probabilistic and kinetic models used showed a higher

  5. Environmental assessment of physical/chemical impacts related to the dredging and disposal of spoil from the proposed trench tube crossing of the Anacostia River

    NASA Astrophysics Data System (ADS)

    Pine, F. W.; Yost, J. C.; Saul, S. W.; Wood, S. G.

    1981-03-01

    Environmental sampling and testing was conducted to identify specified chemical pollutants in river-bottom material to be dredged during construction of the Metro subway tube tunnel crossing of the Anacostia River. Constituent concentrations is sediments, elutriates, and surface waters at the site and defined and compared with federal, state, and District of Columbia criteria and guidelines to identify potential problem areas and to evaluate potential chemical and physical impacts of dredging and spoil disposal. The results indicate sediment-bound concentrations of chlordane, DDT and PCBs which fail to meet federal criteria. High surface water concentrations of iron and mercury were identified which would prevent regulatory compliances of dredging operations for these constituents. It was concluded that the dredging would be minimal. Potential impacts upon groundwater were identified, bur further analyses of hydrogeology at the proposed disposal sites would be needed to define the potential for problems.

  6. 44. Photocopied August 1978. DREDGES WORKING AT POWER HOUSE LOCATION, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    44. Photocopied August 1978. DREDGES WORKING AT POWER HOUSE LOCATION, DECEMBER 10, 1898. BY SPECIAL AGREEMENT, CONTRACTORS MASON & HODGE WERE PERMITTED TO BEGIN EXCAVATION OVER THE POWER HOUSE LOCATION WITH DREDGES, COMPLETING THE WORK LATER BEHIND THE COFFER DAM BEING CONSTRUCTED ON THE FAR RIGHT SIDE OF THE PICTURE. (21) - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  7. Silt Curtains as a Dredging Project Management Practice

    DTIC Science & Technology

    2005-09-01

    current, accurate technical guidance on environmental controls for dredging operations. Remaining challenges include rigorous examination of silt or...turbidity curtains as a temporary control measure to better define performance criteria and identification of technical guidelines for their selection...and use in navigation and environmental dredging projects. PURPOSE: This technical note reviews the basic types of silt curtains used in navigation and

  8. 21. DREDGING POND USED TO TEST THE ADAPTABILITY OF JET ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    21. DREDGING POND USED TO TEST THE ADAPTABILITY OF JET PUMPS FOR PUMPING SAND, AND WEAR RATES OF DIFFERENT TYPES OF DREDGING PIPE. - Waterways Experiment Station, Hydraulics Laboratory, Halls Ferry Road, 2 miles south of I-20, Vicksburg, Warren County, MS

  9. 22. VIEW LOOKING FROM FRONT LEFT OF DREDGE TOWARDS GEAR ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. VIEW LOOKING FROM FRONT LEFT OF DREDGE TOWARDS GEAR DRIVE OF MAIN (HOISTING) ENGINE. ARM ON RIGHT IS PART OF VALVE LINKAGE. BOX ABOVE THAT IS THE CYLINDER OIL LUBRICATOR. - Dredge CINCINNATI, Docked on Ohio River at foot of Lighthill Street, Pittsburgh, Allegheny County, PA

  10. Catalytic transformation of persistent contaminants using a new composite material based on nanosized zero-valent iron.

    PubMed

    Dror, Ishai; Jacov, Osnat Merom; Cortis, Andrea; Berkowitz, Brian

    2012-07-25

    A new composite material based on deposition of nanosized zerovalent iron (nZVI) particles and cyanocobalamine (vitamin B12) on a diatomite matrix is presented, for catalytic transformation of organic contaminants in water. Cyanocobalamine is known to be an effective electron mediator, having strong synergistic effects with nZVI for reductive dehalogenation reactions. This composite material also improves the reducing capacity of nZVI by preventing agglomeration of iron nanoparticles, thus increasing their active surface area. The porous structure of the diatomite matrix allows high hydraulic conductivity, which favors channeling of contaminated water to the reactive surface of the composite material resulting in faster rates of remediation. The composite material rapidly degrades or transforms completely a large spectrum of water contaminants, including halogenated solvents like TCE, PCE, and cis-DCE, pesticides like alachlor, atrazine and bromacyl, and common ions like nitrate, within minutes to hours. A field experiment where contaminated groundwater containing a mixture of industrial and agricultural persistent pollutants was conducted together with a set of laboratory experiments using individual contaminant solutions to analyze chemical transformations under controlled conditions.

  11. Studies on the dissolution of polycyclic aromatic hydrocarbons from contaminated materials using a novel dialysis tubing experimental method

    SciTech Connect

    Woolgar, P.J. Scottish Environment Protection Agency, Stirling ); Jones, K.C. )

    1999-06-15

    Assessment of risk and remediation strategies at contaminated sites requires that both the amounts of contaminants present and their potential for release from materials and soils be evaluated. The release, or dissolution, of polycyclic aromatic hydrocarbons (PAHs) from contaminated materials to water was therefore investigated. To facilitate investigations of PAH dissolution from physically disparate materials such as solid coal tars, creosote, oil, and spent oxide, an experimental method for measuring dissolved PAHs was developed employing dialysis tubing in batch-type system. This was validated and compared to aqueous-phase PAH concentrations measured using more traditional techniques and also predicted using Raoult's law. The experimental procedure was successfully used to determine near equilibrium aqueous concentrations of PAHs, but it could only be used to determine relative rates of approach to equilibrium as the dialysis tubing effected the rate constants. It was found that the contaminant materials influenced dissolution, in particular the close to equilibrium concentrations. For materials chemically similar to PAHs, such as nonaqueous-phase liquids (NAPLs), the concentrations could be predicted using Raoult's law. For materials that were chemically dissimilar to PAHs, such as spent oxide, release was more thermodynamically favorable than for NAPLs.

  12. Effects of the use of fly ash as a binder on the mechanical behaviour of treated dredged sediments.

    PubMed

    Silitonga, E; Levacher, D; Mezazigh, S

    2009-07-01

    The objective of this work was to evaluate the suitability of dredged sediments treated with pozzolanic binders as a pavement base material, and to assess the usefulness of fly ash as a soil mixture/binder with the aim of improving the engineering properties of the stabilized dredged sediments in order to make them capable of taking more load from the foundation structures. Comparing the results with other binders currently used in road construction, the addition of fly ash shows significant positive advantages. The present study covers the characterization of the dredged sediments and fly ash, compaction behaviour, pH measurement, effect on unconfined compressive strength, and the effect of cyclic wet-dry and freeze-thaw tests.

  13. Maintenance Dredging at Mianus River, Greenwich, Connecticut.

    DTIC Science & Technology

    1977-01-01

    8217RNUSM11ER LQ ’ M ~. Cenrnescfreut Io DOCUMENT IDENTIFICATION DISTRIBUTION STATEMENT A Approved for public release, Distribution Unlimited DISTRIBUTION...PROCESSING SHEET DTIC OCT 7 70A MAINTENANCE DREDGING m MIANUS RIVER MIANUS, CONNECTICUT DRAFT ENVIRONMENTAL STATEMENT DEPARTMENT OF THE ARMY NEW ENGLAND...13 . .’ to 3 ./.?o" ""I C " .I m 4 4- A AD .- .P1 10 . 2 -- o"., ,-R, : ’? ’" 3 3 " ( ’ % t ," ....... , r. , Y." - / 6 , " .-- 33 . , ,’I .. n

  14. The radium legacy: Contaminated land and the committed effective dose from the ingestion of radium contaminated materials.

    PubMed

    Tyler, A N; Dale, P; Copplestone, D; Bradley, S; Ewen, H; McGuire, C; Scott, E M

    2013-09-01

    The manufacture and use of radium in the early to mid-20th century within industrial, medicinal and recreational products have resulted in a large number of contaminated sites across a number of countries with notable examples in the USA and Europe. These sites, represent a significant number of unregulated sources of potential radiological exposure that have collectively and hitherto not been well characterised. In 2007, the Radioactive Contaminated Land (RCL) Regulations came into force in the UK, providing the statutory guidance for regulators to classify and deal with RCL. Here we report on results derived from digestion experiments to estimate committed effective dose, a key aspect of the RCL Regulations, from the ingestion of radium contaminated sources that can be found in the environment. This case study includes particles, clinker and artefacts that arise from past military activities on a site that was once an airfield at Dalgety Bay on the Firth of Forth, UK. Since 2011 the number of radium contaminated finds has increased by one order of magnitude on the foreshore areas of Dalgety Bay. The increase in finds may in large part be attributed to a change in monitoring practice. A subsample of sixty sources was selected, on the basis of their activity and dimensions, and subjected to digestion in simulated stomach and lower intestine solutions. The study demonstrated that more radium-226 ((226)Ra) and lead-210 ((210)Pb; driven by Polonium solubility) are dissolved from sources in artificial 'stomach' solutions compared with 'lower intestine' solutions. The combined 'gut' solubility for (226)Ra and apparent (210)Pb varied from less than 1% to up to 35% ICRP 72 conversion factors were used to convert the activities measured in solution to committed effective dose. A little over 10% of the sources tested dissolved sufficient radioactivity to result in 100mSv committed effective dose to an infant. Using the solubility of 35% as a worst case, minimum source

  15. Engineering evaluation/cost analysis for the proposed removal of contaminated materials at the Elza Gate site, Oak Ridge, Tennessee

    SciTech Connect

    Not Available

    1991-06-01

    This engineering evaluation/cost analysis (EE/CA) has been prepared in support of the proposed removal action for cleanup of radioactive and chemically contaminated soil at the Elza Gate site in Oak Ridge, Tennessee. This property became contaminated as a result of storage of ore residues, equipment, and other materials for the US Atomic Energy Commission. The US Department of Energy is responsible for cleanup of portions of the site under its Formerly Utilized Sites Remedial Action Program. In December 1990 an area known as Pad 1 was abrasively scoured to remove surface contamination, and in March 1991 removal of Pad 1 contamination was begun under a separate EE/CA. This EE/CA is intended to cover the remaining portions of the site for which the Department of Energy has responsibility. It has been determined that an EE/CA report is appropriate documentation for the proposed removal action. This EE/CA covers removal of contaminated soils and contaminated concrete rubble from the Elza Gate site. The primary objectives of this EE/CA report are to identify and describe the preferred removal action, and to document the selection of response activities that will mitigate the potential for release of contaminants from the property into the environment and that will minimize the associated threats to human health or welfare and the environment. The preferred alternative is disposition on the Oak Ridge Reservation. 30 refs., 7 figs., 12 tabs.

  16. Dredging Research Program: Practices and Problems Associated with Economic Loading and Overflow of Dredge Hoppers and Scows

    DTIC Science & Technology

    1990-10-01

    of hopper dredges at any of the coastal entrances, the Columbia River , the Umpqua River , or in most of Coos Bay. Overflow is restricted at river mile...Valley Division................................... 32 Ohio River Division................................................. 32 North Atlantic Division...transported and permanently deposited outside the navigation 10 Figure 2. Clamshell dredge filling scow with overflow channel by tidal, river , or

  17. COPING WITH CONTAMINATED SEDIMENTS AND SOILS IN THE URBAN ENVIRONMENT.

    SciTech Connect

    JONES,K.W.; VAN DER LELIE,D.; MCGUIGAN,M.; ET AL.

    2004-05-25

    Soils and sediments contaminated with toxic organic and inorganic compounds harmful to the environment and to human health are common in the urban environment. We report here on aspects of a program being carried out in the New York/New Jersey Port region to develop methods for processing dredged material from the Port to make products that are safe for introduction to commercial markets. We discuss some of the results of the program in Computational Environmental Science, Laboratory Environmental Science, and Applied Environmental Science and indicate some possible directions for future work. Overall, the program elements integrate the scientific and engineering aspects with regulatory, commercial, urban planning, local governments, and community group interests. Well-developed connections between these components are critical to the ultimate success of efforts to cope with the problems caused by contaminated urban soils and sediments.

  18. Cementitious encapsulation of waste materials and/or contaminated soils containing heavy metals, to render them immobile

    SciTech Connect

    Stark, J.N.

    1994-01-04

    The present invention relates to the cementitious encapsulation of waste materials and/or contaminated soils containing heavy metals, to render them immobile, and particularly to the immobilization of metals, in regulated amounts, in the wastes. A waste product comprising the metals is provided. A mixture is prepared comprising the wastes and/or contaminated soils containing heavy metals, water, and a cementitious composition. The cementitious composition comprises magnesium oxide and magnesium chloride in proportions effective to produce, with the water, a magnesium oxychloride cement. The cementitious composition is present in an amount which, on setting, is effective to immobilize the metals in the waste and/or contaminated soils. The mixture of waste and/or contaminated soils and cementitious composition is introduced to a disposition site, and allowed to set and harden at the site. The present invention is particularly useful for the remedial treatment of landfill sites. No Drawings

  19. Closure Report for Corrective Action Unit 166: Storage Yards and Contaminated Materials, Nevada Test Site, Nevada

    SciTech Connect

    NSTec Environmental Restoration

    2009-08-01

    Corrective Action Unit (CAU) 166 is identified in the Federal Facility Agreement and Consent Order (FFACO) as 'Storage Yards and Contaminated Materials' and consists of the following seven Corrective Action Sites (CASs), located in Areas 2, 3, 5, and 18 of the Nevada Test Site: CAS 02-42-01, Condo Release Storage Yd - North; CAS 02-42-02, Condo Release Storage Yd - South; CAS 02-99-10, D-38 Storage Area; CAS 03-42-01, Conditional Release Storage Yard; CAS 05-19-02, Contaminated Soil and Drum; CAS 18-01-01, Aboveground Storage Tank; and CAS 18-99-03, Wax Piles/Oil Stain. Closure activities were conducted from March to July 2009 according to the FF ACO (1996, as amended February 2008) and the Corrective Action Plan for CAU 166 (U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, 2007b). The corrective action alternatives included No Further Action and Clean Closure. Closure activities are summarized. CAU 166, Storage Yards and Contaminated Materials, consists of seven CASs in Areas 2, 3, 5, and 18 of the NTS. The closure alternatives included No Further Action and Clean Closure. This CR provides a summary of completed closure activities, documentation of waste disposal, and confirmation that remediation goals were met. The following site closure activities were performed at CAU 166 as documented in this CR: (1) At CAS 02-99-10, D-38 Storage Area, approximately 40 gal of lead shot were removed and are currently pending treatment and disposal as MW, and approximately 50 small pieces of DU were removed and disposed as LLW. (2) At CAS 03-42-01, Conditional Release Storage Yard, approximately 7.5 yd{sup 3} of soil impacted with lead and Am-241 were removed and disposed as LLW. As a BMP, approximately 22 ft{sup 3} of asbestos tile were removed from a portable building and disposed as ALLW, approximately 55 gal of oil were drained from accumulators and are currently pending disposal as HW, the portable building was removed and disposed as

  20. Brownfield reuse of dredged New York Harbor sediment by cement-based solidification/stabilization

    SciTech Connect

    Loest, K.; Wilk, C.M.

    1998-12-31

    Newly effective federal regulations restrict the ocean disposal of sediments dredged from the harbors of New York and Newark. The New York Port Authority is faced with a critical situation: find land-based disposal/uses for 10`s of millions cubic yards of sediments or lose standing as a commercial port for ocean-going ships. One of the technologies now being employed to manage the sediments is portland cement-based solidification/stabilization (S/S) treatment. At least 4 million cubic yards of the sediments will undergo cement-based S/S treatment. This treatment will immobilize heavy metals, dioxin, PCBs and other organic contaminants in the sediment. The treatment changes the sediment from a environmental liability into a valuable structural fill. This structural fill is being used at two properties. The first property is an old municipal landfill in Port Newark, New Jersey. The treated sediments are being used as structural fill to cover about 20 acres of the landfill. This will allow planned redevelopment of the landfill property into a shopping mall. The second property called the Seaboard site, was the location of a coal gasification facility and later a wood preservation facility. This 160-acre property has been designated for brownfield redevelopment. Over 4 million cubic yards of treated sediments will eventually cover this site. Portland cement is the selected S/S binding reagent. Nearly 500,000 tons of cement will eventually be used to treat the sediments. Cement was selected for its ability to (a) change the peanut butter-like consistency of the sediments into a structural material and (b) to physically and chemically immobilize hazardous constituents in the sediment.

  1. Gender difference in walleye PCB concentrations persists following remedial dredging

    USGS Publications Warehouse

    Madenjian, Charles P.; Jude, David J.; Rediske, Richard R.; O'Keefe, James P.; Noguchi, George E.

    2009-01-01

    Eleven male walleyes (Sander vitreus) and 10 female walleyes from the Saginaw Bay (Lake Huron) population were caught during the spawning run at Dow Dam (Midland, Michigan) in the Tittabawassee River during April 1996, and individual whole-fish polychlorinated biphenyl (PCB) determinations were made. Total PCB concentrations averaged 7.95 and 3.17??mg/kg for males and females, respectively. As part of the Natural Resource Damage Assessment remediation process, contaminated sediments from the Saginaw River, the main tributary to Saginaw Bay, were removed during 2000 and 2001. Total PCB concentrations of 10 male and 10 female walleyes caught at Dow Dam during April 2007 averaged 1.58 and 0.55??mg/kg, respectively. Thus, dredging of the Saginaw River appeared to be effective in reducing PCB concentrations of Saginaw Bay adult walleyes, as both males and females decreased in PCB concentration by more than 80% between 1996 and 2007. However, the ratio of male PCB concentration to female PCB concentration did not decline between 1996 and 2007. This persistent gender difference in PCB concentrations was apparently due to a gender difference in habitat utilization coupled with a persistent spatial gradient in prey fish PCB concentrations from the Saginaw River to Lake Huron.

  2. Jamu Gendong, a kind of traditional medicine in Indonesia: the microbial contamination of its raw materials and endproduct.

    PubMed

    Limyati, D A; Juniar, B L

    1998-12-01

    An examination on the microbiological quality of seven kinds of Jamu Gendong (JG) and their raw materials has been conducted according to the requirements of microbial contamination in traditional medicine, issued by the Department of Health of Indonesia in 1986. Samples of JG and their raw materials were taken from producers in three districts of Surabaya. The samples were subject to the following examinations: total plate count (TPC), MPN coliform, the enumeration of molds and yeasts, the presence or absence of Staphylococcus aureus, Salmonella and Vibrio. Each time the JG samples were taken from different producers together with their raw materials. The results of this investigation showed that most of the JG samples were heavily contaminated with bacteria, yeasts and molds. For bacteria, taken from the TPC results, their numbers were ranging from 7.7 x 10(2) microorganisms/ml to too many to count (TMTC). For yeasts and molds the numbers showed variations from 0 microorganisms/ml to TMTC. Contamination with Coliform in 1 ml of JG were ranged from 0 to > 2.4 x 10(6) microorganisms. In most of the samples pathogenic Staphylococci, Salmonella sp. and Vibrio sp. were not detected, so that a conclusion can be drawn that most of the contamination in JG are saprophytic, only a few pathogenic. The results also show that it is possible to have JG which fulfill the government's requirements. Similar results were obtained with the plant material constituents of JG such as rhizomes, leaves, herbs and fruits of Piper nigrum and Piper retrofractum, with the exception of Piper betle leaves and P. retrofractum fruits, both showing low contamination of Coliform bacteria. However, the fruits of Citrus aurantifolia and Morinda citrifolia were less contaminated, just like seeds of Oryza sativa, Parkia roxburghii, bulbs of Allium sativum and the pulp of Tamarindus indica. With these plant constituents of JG, it might be of interest to screen their antibacterial and antifungal

  3. Catalytic transformation of persistent contaminants using a new composite material based on nanosized zero-valent metal - field experiment results

    NASA Astrophysics Data System (ADS)

    Dror, I.; Merom Jacov, O.; Berkowitz, B.

    2010-12-01

    A new composite material based on deposition of nanosized zero valent iron (ZVI) particles and cyanocobalamine (vitamin B12) on a diatomite matrix is presented. Cyanocobalamine is known to be an effective electron mediator, having strong synergistic effects with ZVI for reductive dehalogenation reactions. This composite material also improves the reducing capacity of nanosized ZVI by preventing agglomeration of iron particles, thus increasing their active surface area. The porous structure of the diatomite matrix allows high hydraulic conductivity, which favors channeling of contaminated water to the reactive surface of the composite material and in turn faster rates of remediation. The ability of the material to degrade or transform rapidly and completely a large spectrum of water pollutants will be demonstrated, based on results from two field site experiments where polluted groundwater containing a mixture of industrial and agricultural persistent pollutants was treated. In addition a set of laboratory experiments using individual contaminant solutions to analyze chemical transformations under controlled conditions will be presented.

  4. Development and evaluation of novel sensing materials for detecting food contamination

    NASA Astrophysics Data System (ADS)

    Sankaran, Sindhuja

    evaluated as sensor material for the detection of alcohols at low concentrations. The results indicated that the QCM sensors exhibited a good sensitivity to 1-hexanol and 1-pentanol with the estimated LDLs in the range of 2-3 ppm and 3-5 ppm, respectively. This research work was successful in developing multiple novel sensing materials to detect alcohols and acid associated with meat contaminations at low concentrations.

  5. More than scratching the surface: dredge-up in simulations of double white dwarf mergers

    NASA Astrophysics Data System (ADS)

    Motl, Patrick M.; Staff, J. E.; Raskin, C.; Marcello, D.; Clayton, G. C.; Fryer, C.; Frank, J.

    2014-01-01

    Previous studies have shown that the strange isotopic abundances of R Corona Borealis stars (e.g. 16O / 18O ~ 1) as well as other properties of these unusual stars may naturally be explained if they originate from the merger of a He white dwarf with a CO white dwarf. However, the merger process that reignites these stellar remnants is highly dynamic and violent. Hydrodynamic instabilities in the accreting star will dredge up oxygen 16 from the accretor at the same time that material from the donor star is fusing to form oxygen 18. Recent stellar evolution calculations have indicated that if dredge up is strongly suppressed, the merger remnant will appear as an R Corona Borealis star but it is not clear how or if dredge up can be shut down. In this presentation we will compare double white dwarf merger simulations performed with three independent codes (SPH, fixed grid Eulerian and adaptive mesh refinement) to ascertain how much accretor material is lifted into the proto-envelope of the merged object.

  6. Estimating source terms for far field dredge plume modelling.

    PubMed

    Becker, Johannes; van Eekelen, Erik; van Wiechen, Joost; de Lange, William; Damsma, Thijs; Smolders, Tijmen; van Koningsveld, Mark

    2015-02-01

    Far field modelling of dredging induced suspended sediment plumes is important while assessing the environmental aspects of dredging. Realistic estimation of source terms, that define the suspended sediment input for far field dredge plume modelling, is key to any assessment. This paper describes a generic method for source term estimation as it is used in practice in the dredging industry. It is based on soil characteristics and dredge production figures, combined with empirically derived, equipment and condition specific 'source term fractions'. A source term fraction relates the suspended fine sediment that is available for dispersion, to the amount of fine sediment that is present in the soil and the way it is dredged. The use of source term fractions helps to circumvent modelling of complicated near field processes, at least initially, enabling quick assessments. When further detail is required and extra information is available, the applicability of the source term fractions can/should be evaluated by characterisation monitoring and/or near field modelling. An example of a fictitious yet realistic dredging project demonstrates how two different work methods can trigger two distinctly different types of stress to the environmental system in terms of sediment concentration and duration.

  7. DEVELOPING TOOLS FOR MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS AT LAKE HARTWELL, SC

    EPA Science Inventory

    Contaminated sediments pose a risk to human health and the environment . The management of this risk is currently limited practically to three technologies: dredging, capping, and natural recovery. Monitored natural recovery relies on the natural burial and removal mechanisms to...

  8. Mechanical impact tests of materials in oxygen effects of contamination. [Teflon, stainless steel, and aluminum

    NASA Technical Reports Server (NTRS)

    Ordin, P. M.

    1980-01-01

    The effect of contaminants on the mechanical impact sensitivity of Teflon, stainless steel, and aluminum in a high-pressure oxygen environment was investigated. Uncontaminated Teflon did not ignite under the test conditions. The liquid contaminants - cutting oil, motor lubricating oil, and toolmaker dye - caused Teflon to ignite. Raising the temperature lowered the impact energy required for ignition. Stainless steel was insensitive to ignition under the test conditions with the contaminants used. Aluminum appeared to react without contaminants under certain test conditions; however, contamination with cutting oil, motor lubricating oil, and toolmakers dye increased the sensitivity of aluminum to mechanical impact. The grit contaminants silicon dioxide and copper powder did not conclusively affect the sensitivity of aluminum.

  9. Recycled paper-paperboard for food contact materials: contaminants suspected and migration into foods and food simulant.

    PubMed

    Suciu, Nicoleta A; Tiberto, Francesca; Vasileiadis, Sotirios; Lamastra, Lucrezia; Trevisan, Marco

    2013-12-15

    Contaminant residues in food packaging is a new challenge of our time, as it may pose a threat for consumers. Higher levels of contaminants were observed in food packaging made by recycled materials, even if little information is available for some groups of contaminants. The present study proposes a procedure for analyzing three different groups of organic contaminants in recycled paper and paperboard. Seventeen commercial samples were analyzed for the presence of bisphenol A (BPA), bis (2-ethylhexyl) phthalate (DEHP), nonylphenol monoethoxylate (NMP) and nonylphenol di-ethoxilate (NDP). Not all the samples contained all the contaminants; BPA was the only substance present in all the samples. The concentrations detected were quite high and, in most of the cases, in agreement with results reported in previous studies. Substance migration tests from spiked/non-spiked samples for two dry foods and Tenax® food simulant were undertaken. BPA migration quotients were always lower than 1%, whereas the migration quotients of DEHP were higher than 2.0%. The highest nonylphenols migration quotients were 6.5% for NMP and 8.2% for NDP. Tenax® simulates well the contaminants migration from paperboard to dry food, in some cases being even more severe than the food.

  10. Assessment of sediment quality in dredged and undredged areas of the Trenton Channel of the Detroit River, Michigan USA, using the sediment quality triad

    USGS Publications Warehouse

    Besser, John M.; Giesy, John P.; Kubitz, Jody A.; Verbrugge, David A.; Coon, Thomas G.; Braselton, W. Emmett

    1996-01-01

    The “sediment quality triad” approach was used to assess the effects of dredging on the sediment quality of a new marina in the Trenton Channel of the Detroit River, and to evaluate spatial and temporal variation in sediment quality in the Trenton Channel. Samples were collected in November of 1993 (10 months after dredging) and characterized by chemical analysis, sediment bioassays, and assessment of benthic invertebrate communities. The three study components indicated little difference in sediment quality at dredged sites in the marina relative to nearby areas in the Trenton Channel, and little change in sediment quality of Trenton Channel sites relative to conditions reported in the mid-1980s. These results suggest that improvement in sediment quality in the Trenton Channel, due to dredging or natural processes, will depend on elimination of sediment “hot spots” and other upstream contaminant sources. Concentrations of chemical contaminants, especially metals and polycyclic aromatic hydrocarbons, exceeded concentrations associated with effects on biota and were significantly correlated with results of sediment bioassays and characteristics of benthic communities. Laboratory sediment bioassays with Hyalella azteca andChironomus tentans produced better discrimination among sites with differing degrees of contamination than did characterization of benthic communities, which were dominated by oligochaetes at all sites in the marina and the Trenton Channel.

  11. Reclamation with Recovery of Radionuclides and Toxic Metals from Contaminated Materials, Soils, and Wastes

    NASA Technical Reports Server (NTRS)

    Francis, A. J.; Dodge, C. J.

    1993-01-01

    A process has been developed at Brookhaven National Laboratory (BNL) for the removal of metals and radionuclides from contaminated materials, soils, and waste sites. In this process, citric acid, a naturally occurring organic complexing agent, is used to extract metals such as Ba, Cd, Cr, Ni, Zn, and radionuclides Co, Sr, Th, and U from solid wastes by formation of water soluble, metal-citrate complexes. Citric acid forms different types of complexes with the transition metals and actinides, and may involve formation of a bidentate, tridentate, binuclear, or polynuclear complex species. The extract containing radionuclide/metal complex is then subjected to microbiological degradation followed by photochemical degradation under aerobic conditions. Several metal citrate complexes are biodegraded, and the metals are recovered in a concentrated form with the bacterial biomass. Uranium forms binuclear complex with citric acid and is not biodegraded. The supernatant containing uranium citrate complex is separated and upon exposure to light, undergoes rapid degradation resulting in the formation of an insoluble, stable polymeric form of uranium. Uranium is recovered as a precipitate (polyuranate) in a concentrated form for recycling or for appropriate disposal. This treatment process, unlike others which use caustic reagents, does not create additional hazardous wastes for disposal and causes little damage to soil which can then be returned to normal use.

  12. Temporal Patterns in Seawater Quality from Dredging in Tropical Environments

    PubMed Central

    Jones, Ross; Fisher, Rebecca; Stark, Clair; Ridd, Peter

    2015-01-01

    Maintenance and capital dredging represents a potential risk to tropical environments, especially in turbidity-sensitive environments such as coral reefs. There is little detailed, published observational time-series data that quantifies how dredging affects seawater quality conditions temporally and spatially. This information is needed to test realistic exposure scenarios to better understand the seawater-quality implications of dredging and ultimately to better predict and manage impacts of future projects. Using data from three recent major capital dredging programs in North Western Australia, the extent and duration of natural (baseline) and dredging-related turbidity events are described over periods ranging from hours to weeks. Very close to dredging i.e. <500 m distance, a characteristic features of these particular case studies was high temporal variability. Over several hours suspended sediment concentrations (SSCs) can range from 100–500 mg L-1. Less turbid conditions (10–80 mg L-1) can persist over several days but over longer periods (weeks to months) averages were <10 mg L-1. During turbidity events all benthic light was sometimes extinguished, even in the shallow reefal environment, however a much more common feature was very low light ‘caliginous’ or daytime twilight periods. Compared to pre-dredging conditions, dredging increased the intensity, duration and frequency of the turbidity events by 10-, 5- and 3-fold respectively (at sites <500 m from dredging). However, when averaged across the entire dredging period of 80–180 weeks, turbidity values only increased by 2–3 fold above pre-dredging levels. Similarly, the upper percentile values (e.g., P99, P95) of seawater quality parameters can be highly elevated over short periods, but converge to values only marginally above baseline states over longer periods. Dredging in these studies altered the overall probability density distribution, increasing the frequency of extreme values. As such

  13. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  14. Environmental materials for remediation of soils contaminated with lead and cadmium using maize (Zea mays L.) growth as a bioindicator.

    PubMed

    Shi, Yu; Huang, Zhanbin; Liu, Xiujie; Imran, Suheryani; Peng, Licheng; Dai, Rongji; Deng, Yulin

    2016-04-01

    Heavy metal pollution is a severe environmental problem. Remediation of contaminated soils can be accomplished using environmental materials that are low cost and environmentally friendly. We evaluated the individual and combination effects of humic acid (HA), super absorbent polymer (SAP), zeolite (ZE), and fly ash composites (FC) on immobilization of lead (Pb) and cadmium (Cd) in contaminated soils. We also investigated long-term practical approaches for remediation of heavy metal pollution in soil. The biochemical and morphological properties of maize (Zea mays L.) were selected as biomarkers to assess the effects of environmental materials on heavy metal immobilization. The results showed that addition of test materials to soil effectively reduced heavy metal accumulation in maize foliage, improving chlorophyll levels, plant growth, and antioxidant enzyme activity. The test materials reduced heavy metal injury to maize throughout the growth period. A synergistic effect from combinations of different materials on immobilization of Pb and Cd was determined based on the reduction of morphological and biochemical injuries to maize. The combination of zeolite and humic acid was especially effective. Treatment with a combination of HA + SAP + ZE + FC was superior for remediation of soils contaminated with high levels of Pb and Cd.

  15. Treatment Of Arsenic-Contaminated Materials Using Selected Stabilization And Solidification Technologies

    EPA Science Inventory

    Arsenic contamination of soil, sediment and groundwater is a widespread problem in certain areas and has caused great public concern due to increased awareness of the health risks. Often the contamination is naturally occurring, but it can also be a result of waste generated fro...

  16. Short-term response of subadult white sturgeon to hopper dredge disposal operations

    USGS Publications Warehouse

    Parsley, Michael J.; Popoff, Nicholas D.; Romine, Jason G.

    2011-01-01

    The effect of dredged-material disposal operations on the behavior of seven white sturgeon Acipenser transmontanus (50–101 cm fork length) was examined by analysis of the movements and depth use of these fish before, during, and after a series of hopper dredge disposal operations in the lower Columbia River. Analyses of fish locations showed that 12 flow-lane disposal operations within a 24-h period had minimal effect on subadult white sturgeon behavior; six of the seven fish showed slight attraction to the disposal area during disposals, and one fish increased its distance from the disposal area. The core area for all fish combined shifted toward the disposal area during disposals. In the 24 h after completion of the disposal operations the fish core areas shifted back toward those areas occupied before the disposals. The rates of movement, depths used, and diel movement patterns of the white sturgeon showed little change over all periods, suggesting that natural behaviors were not altered during and immediately after hopper dredge disposal operations.

  17. Ross Sea Mollusca from the Latitudinal Gradient Program: R/V Italica 2004 Rauschert dredge samples.

    PubMed

    Ghiglione, Claudio; Alvaro, Maria Chiara; Griffiths, Huw J; Linse, Katrin; Schiaparelli, Stefano

    2013-01-01

    Information regarding the molluscs in this dataset is based on the Rauschert dredge samples collected during the Latitudinal Gradient Program (LGP) on board the R/V "Italica" in the Ross Sea (Antarctica) in the austral summer 2004. A total of 18 epibenthic dredge deployments/samplings have been performed at four different locations at depths ranging from 84 to 515m by using a Rauschert dredge with a mesh size of 500μm. In total 8,359 specimens have been collected belonging to a total of 161 species. Considering this dataset in terms of occurrences, it corresponds to 505 discrete distributional records (incidence data). Of these, in order of abundance, 5,965 specimens were Gastropoda (accounting for 113 species), 1,323 were Bivalvia (accounting for 36 species), 949 were Aplacophora (accounting for 7 species), 74 specimens were Scaphopoda (3 species), 38 were Monoplacophora (1 species) and, finally, 10 specimens were Polyplacophora (1 species). This data set represents the first large-scale survey of benthic micro-molluscs for the area and provides important information about the distribution of several species, which have been seldom or never recorded before in the Ross Sea. All vouchers are permanently stored at the Italian National Antarctic Museum (MNA), Section of Genoa, enabling future comparison and crosschecking. This material is also currently under study, from a molecular point of view, by the barcoding project "BAMBi" (PNRA 2010/A1.10).

  18. Ross Sea Mollusca from the Latitudinal Gradient Program: R/V Italica 2004 Rauschert dredge samples

    PubMed Central

    Ghiglione, Claudio; Alvaro, Maria Chiara; Griffiths, Huw J.; Linse, Katrin; Schiaparelli, Stefano

    2013-01-01

    Abstract Information regarding the molluscs in this dataset is based on the Rauschert dredge samples collected during the Latitudinal Gradient Program (LGP) on board the R/V “Italica” in the Ross Sea (Antarctica) in the austral summer 2004. A total of 18 epibenthic dredge deployments/samplings have been performed at four different locations at depths ranging from 84 to 515m by using a Rauschert dredge with a mesh size of 500μm. In total 8,359 specimens have been collected belonging to a total of 161 species. Considering this dataset in terms of occurrences, it corresponds to 505 discrete distributional records (incidence data). Of these, in order of abundance, 5,965 specimens were Gastropoda (accounting for 113 species), 1,323 were Bivalvia (accounting for 36 species), 949 were Aplacophora (accounting for 7 species), 74 specimens were Scaphopoda (3 species), 38 were Monoplacophora (1 species) and, finally, 10 specimens were Polyplacophora (1 species). This data set represents the first large-scale survey of benthic micro-molluscs for the area and provides important information about the distribution of several species, which have been seldom or never recorded before in the Ross Sea. All vouchers are permanently stored at the Italian National Antarctic Museum (MNA), Section of Genoa, enabling future comparison and crosschecking. This material is also currently under study, from a molecular point of view, by the barcoding project “BAMBi” (PNRA 2010/A1.10). PMID:24146597

  19. Bioaccumulation of toxic substances associated with dredging and dredged material disposal: a literature review

    USGS Publications Warehouse

    Seelye, James G.; Mac, Michael J.

    1984-01-01

    A literature review of sediment bioassessment was conducted as the first step in the development of a more standardized and ecologically sound test procedure for evaluating sediment quality. Based on the review, the authors concluded that 1) a standardized laboratory bioassessment test should consist of flowthrough exposure of at least 10 days duration using more than one aquatic organism including at least an infaunal benthic invertebrate and a fish species. 2) Before adoption of a laboratory sediment bioassessment procedure, the laboratory results should be evaluated by comparison with field conditions. 3) Most current sediment bioassessment regulatory tests measure acute toxicity or bioaccumulation. Development of tests to evaluate chronic, sublethal effects is needed.

  20. Puget Sound Dredged Disposal Analysis: Management Plan Assessment Report. Dredged Material Management Year 1990.

    DTIC Science & Technology

    1991-03-01

    A. 4.3 Other PSDDA Program Topics Laboratory Accreditation Ecology presented during the DY 1989 ARM a summary of: o the legal authority to establish...a laboratory accreditation program (RCW 43.21 A.230 (1987)); o the purpose in establishing such a program; o the state rules which establish such a...and documenting best professional judgment considerations. Page A-1 Page A-2 CLARIFICATION ENVIRONMENTAL LABORATORY ACCREDITATION Prepared by Toi Jries

  1. Evaluation of the Submerged Discharge of Dredged Material Slurry During Pipeline Dredge Operations

    DTIC Science & Technology

    1978-08-01

    turbulentI flow of the fluid mud wave the friction factor becomes virtually independent of Reynolds number and is determined solely by the relative...viscosity of the fluid mud. In the laboratory test program, head wave Reynolds numbers fell in the turbulent regime, and the bottom friction factor was...to prototype, the bottom friction factor was constant. Friction conditions at the upper inter- face are governed primarily by Froude number with little

  2. Dredging displaces bottlenose dolphins from an urbanised foraging patch.

    PubMed

    Pirotta, Enrico; Laesser, Barbara Eva; Hardaker, Andrea; Riddoch, Nicholas; Marcoux, Marianne; Lusseau, David

    2013-09-15

    The exponential growth of the human population and its increasing industrial development often involve large scale modifications of the environment. In the marine context, coastal urbanisation and harbour expansion to accommodate the rising levels of shipping and offshore energy exploitation require dredging to modify the shoreline and sea floor. While the consequences of dredging on invertebrates and fish are relatively well documented, no study has robustly tested the effects on large marine vertebrates. We monitored the attendance of common bottlenose dolphins (Tursiops truncatus) to a recently established urbanised foraging patch, Aberdeen harbour (Scotland), and modelled the effect of dredging operations on site usage. We found that higher intensities of dredging caused the dolphins to spend less time in the harbour, despite high baseline levels of disturbance and the importance of the area as a foraging patch.

  3. 1. STARBOARD PROFILE WITH DREDGE BASKET BEING RAISEDNOTE 'LAZYJACK' RIGGING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. STARBOARD PROFILE WITH DREDGE BASKET BEING RAISED-NOTE 'LAZYJACK' RIGGING TO GUIDE SAILS DOWN TO BOOM AND CLUB (REQUIRES LESS CREW) - KATHRYN-Two-sail Bateau "Skipjack", Dogwood Harbor, Chesapeake Bay, Tilghman, Talbot County, MD

  4. DISSIPATION OF PAHs IN SATURATED, DREDGED SEDIMENTS: A FIELD TRIAL

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Sediments dredged from navigable rivers often contain elevated concentrations of recalcitrant, potentially toxic organic compounds such as polychlorinated biphenyls (PCBs) and polyaromatic hydrocarbons (PAHs). The presence of these compounds often requires that the sediments be stored in fully conta...

  5. 14. DREDGING MAP. United Engineering Company Ltd., Alameda Shipyard. Ship ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. DREDGING MAP. United Engineering Company Ltd., Alameda Shipyard. Ship repair facilities dredging map. No architect noted. Drawn by "J.H." (John Hudspeth?). Sheet 1. Plan no. 10,529. Scale one inch to 50 feet. September 22, 1943. U.S. Navy, Bureau of Yards & Docks, Contract no. bs 76. Approved for construction October 18, 1943. blueprint - United Engineering Company Shipyard, 2900 Main Street, Alameda, Alameda County, CA

  6. Management of Dredging Projects; Summary Repot for Technical Area 5

    DTIC Science & Technology

    1996-02-01

    Donald L. Robey, Chief, EPED; Dr. John W. Keeley, Director, EL; and Dr. John Har- rison, former Director, EL. Hydraulics Laboratory (HL)-Mr. Mitch...one on the Gulf Coast (Wheeler). For FY92, the Corps 1 Chapter 3 was extracted from Ogden Beeman and Associates, Inc. (in preparation). Chapter 3...and maintenance dredging was per- formed by private industry. The purpose of Corps of Engineers Hopper Dredging, 1954-1994 (Og- den Beeman and

  7. SEDIMENTS: A RESERVOIR OF HISTORIC CONTAMINATION OF THE ENVIRONMENT

    EPA Science Inventory

    Sediments contain contaminants derived from past activities that seriously degraded the environment.

    During low water, sediments are subject to natural erosion or removal for navigation.

    Erosion or dredging of sediment will release contaminants into the environment ...

  8. Ex-situ evaluation of bauxite residues as amendment for trace elements stabilization in dredged sediment from Mediterranean Sea: A case study.

    PubMed

    Taneez, Mehwish; Hurel, Charlotte; Marmier, Nicolas

    2015-09-15

    Stabilization of marine dredged sediments contaminated with multi-elements is a challenging task in choosing the appropriate sorbent and application dosage. The present study investigates the possibility of using bauxite residues (Bauxaline® and Bauxsol) as amendment for the treatment of contaminated sediment. A pilot scale experiment was conducted for three months to stabilize trace elements in composted contaminated sediment sample using 5% by-product amendment. The results showed that after 3months of treatment, cationic trace elements were effectively immobilized but increased leaching of anionic pollutants was observed. Increased leaching of anionic pollutants could be limited by addition of higher quantities of amendments. The total content of available pollutants decreased in stabilized sediments but this treatment has no effect on the classification of waste. The leachates were then evaluated for acute toxicity using estuarine rotifers Brachionus plicatilis. Bauxite residues can be inexpensive choices for the stabilization of cationic pollutants in dredged sediments.

  9. Contamination control in hybrid microelectronic modules. Part 3: Specifications for coating material and process controls

    NASA Technical Reports Server (NTRS)

    Himmel, R. P.

    1975-01-01

    Resin systems for coating hybrids prior to hermetic sealing are described. The resin systems are a flexible silicone junction resin system and a flexible cycloaliphatic epoxy resin system. The coatings are intended for application to the hybrid after all the chips have been assembled and wire bonded, but prior to hermetic sealing of the package. The purpose of the coating is to control particulate contamination by immobilizing particles and by passivating the hybrid. Recommended process controls for the purpose of minimizing contamination in hybrid microcircuit packages are given. Emphasis is placed on those critical hybrid processing steps in which contamination is most likely to occur.

  10. Characterization of Underwater Sounds Produced by a Hydraulic Cutterhead Dredge during Maintenance Dredging in the Stockton Deepwater Shipping Channel, California

    DTIC Science & Technology

    2014-03-01

    Hydraulic Cutterhead Dredge during Maintenance Dredging in the Stockton Deepwater Shipping Channel, California by Kevin J. Reine and Charles Dickerson...contact Kevin J. Reine (601 634-3436), Kevin.J.Reine@usace.army.mil, or Charles Dickerson (601 634-3484), Charles.Dickerson@ usace.army.mil of the...Monitoring the effects of conventional pile driving on three species of fish. Richmond, CA: Manson Construction Company. American National Standards

  11. Organic adlayer on inorganic materials: XPS analysis selectivity to cope with adventitious contamination

    NASA Astrophysics Data System (ADS)

    Landoulsi, Jessem; Genet, Michel J.; Fleith, Sandrine; Touré, Yetioman; Liascukiene, Irma; Méthivier, Christophe; Rouxhet, Paul G.

    2016-10-01

    This work addresses the ubiquitous presence of organic contaminants at inorganic solid surfaces and the improvement of XPS analysis selectivity to cope with it. Water contact angle measurements showed that the adsorption of organic contaminants occurs readily in ambient air, and faster and more extensively under high vacuum. It is stronger on stainless steel (SS) compared to silica and is significantly reduced when SS is sterilized by autoclaving. The reliability of XPS data was evaluated (selectivity, precision, accuracy) by correlations between spectral data incorporating a large amount of results obtained with different XPS spectrometers on SS and glass samples cleaned in different ways and conditioned with several biomacromolecules. The methodology used allows a discrimination to be made between contaminants and deliberately adsorbed biomacromolecules, and offers perspectives for tracking the source of contamination. Furthermore, a discrimination can be made between oxygen from the organic adlayer and oxygen from the substrate, and the O 1s component above 532.0 eV observed for SS is shown to be due to organic contaminants rather than adsorbed water. This approach offers new perspectives to examine the interactions (displacement or not) between contaminants and compounds of interest, e.g. proteins, at the stage of the adsorption process.

  12. Food contamination with organic materials in perspective: packaging materials as the largest and least controlled source? A view focusing on the European situation.

    PubMed

    Grob, Koni; Biedermann, Maurus; Scherbaum, Ellen; Roth, Maria; Rieger, Karl

    2006-01-01

    The comparison of the various sources of food contamination with organic chemicals suggests that in the public, but also among experts, the perception of risk is often distorted. Firstly, neither pesticides nor environmental pollutants contribute the most; the amount of material migrating from food packaging into food may well be 100 times higher. Secondly, control of these large migrants is often lagging behind the standards set up for other sources, since many of the components (particularly those not being "starting materials") have not been identified and, thus, not toxicologically evaluated. Finally, attitudes towards different types of food contaminants are divergent, also reflected by the legal measures: for most sources of food contamination there are strict rules calling for minimization, whereas the European packaging industry has even requested a further increase in the tolerance to as close as possible to the limit set by the toxicologists. This paper calls for a more realistic perception and more coherent legal measures-and improvements in the control of migration from packaging material.

  13. Energetic Materials Effects on Essential Soil Processes: Decomposition of Orchard Grass (Dactylis glomerata) Litter in Soil Contaminated with Energetic Materials

    DTIC Science & Technology

    2014-02-01

    ADDRESS(ES) Strategic Environmental Research and Development Program (SERDP), 901 North Stuart Street, Suite 303, Arlington, VA 22203-1821 10. SPONSOR...Analysis of Contaminated Sites (Sunahara, G., Renoux, A., Thellen, C., Gaudet, C. and Pilon, A. eds.). John Wiley and Sons, Ltd., 2002, pp 45-60...Production Industry; ORNL-6202; Oak Ridge National Laboratory: Oak Ridge, TN, 1986. Spanggord, R.J.; Mill , T.; Chou, T.W.; Smith, J.H.; Lee, S

  14. Comparing Polychaete Bioaccumulation and Passive Sampler Uptake to Assess the Effect of Sediment Resuspension on Contaminant Bioavailability

    EPA Science Inventory

    Increased bioavailability of polychlorinated biphenyls (PCBs) from resettled sediments following remedial dredging is suspected of contributing to elevated organism tissue concentrations at contaminated sites. However, little data exists to evaluate whether increases in bioavaila...

  15. Sediment pass-through, an alternative to reservoir dredging

    SciTech Connect

    Harrison, L.L.; Lee, W.H.; Tu, S.

    1995-12-31

    Pacific Gas and Electric Company (PG&E) is studying an alternative {open_quotes}Sediment Management Plan{close_quotes} (SMP) to control sediments at Rock Creek Reservoir and the downstream Cresta Reservoir on the North Fork Feather River in Plumas County. The reservoirs are part of the 182,000 kW Rock Creek-Cresta Project hydroelectric development. Approximately 5.4 million cubic meters of sediments, deposited in the two reservoirs since they were placed in service in 1949 and 1950, partially obstruct the dams` low level outlets and pipe inlets supplying water for spillway gate operations. The sediments jeopardize the reliable and efficient operation of the dams and powerhouses. The SMP includes retrofitting Rock Creek and Cresta Dams with additional low-level gated outlets and modification of trash racks at the existing low level outlet pipes at each dam to improve sediment pass-through (SPT) capacity during high flows. Also, to enable construction of the dam modifications and to facilitate the initiation of SPT operation, dredging of approximately 46,000 cubic meters at Rock Creek Reservoir and 57,000 cubic meters at Cresta Reservoir can be accomplished using a new slurry pump dredging technology to minimize turbidity and re-suspension of solids during dredging. It is proposed to deposit the sediment on the reservoir bottoms, upstream of the areas to be dredged. The dredged sediments subsequently would be flushed from the reservoirs during SPT operations to ultimately be deposited in the dead storage volume of a large downstream reservoir, Lake Oroville. The SPT management plan supersedes more costly plans for major dredging, and may preclude the need for future maintenance dredging at the reservoirs.

  16. Bioremediation of oil contaminated beach material in Prince William Sound, Alaska

    SciTech Connect

    Pritchard, P.H. )

    1990-01-01

    The Office of Research and Development within the Environmental Protection Agency has been evaluating bioremediation to help clean up beaches in Alaska's Prince William Sound following the March 24, 1989 Exxon Valdez oil spill. Bioremediation techniques have been used elsewhere to accelerate the natural biological degradation of environmental contaminants. The purpose of EPA's project was to determine the best bioremediation approach for the oil contaminated shoreline of Prince William Sound. The major portion of the EPA study, therefore, has been a field demonstration to determine if nutrient (fertilizer) addition to contaminated beaches will effectively stimulate hydrocarbon breakdown by indigenous bacteria. Concurrently, a monitoring program has been instituted to check for any possible adverse environmental effects from nutrient addition. Techniques of applying nutrient mixtures to the beaches have been investigated.

  17. Assessment of chemical and material contamination in waste wood fuels--A case study ranging over nine years.

    PubMed

    Edo, Mar; Björn, Erik; Persson, Per-Erik; Jansson, Stina

    2016-03-01

    The increased demand for waste wood (WW) as fuel in Swedish co-combustion facilities during the last years has increased the import of this material. Each country has different laws governing the use of chemicals and therefore the composition of the fuel will likely change when combining WW from different origins. To cope with this, enhanced knowledge is needed on WW composition and the performance of pre-treatment techniques for reduction of its contaminants. In this study, the chemical and physical characteristics of 500 WW samples collected at a co-combustion facility in Sweden between 2004 and 2013 were investigated to determine the variation of contaminant content over time. Multivariate data analysis was used for the interpretation of the data. The concentrations of all the studied contaminants varied widely between sampling occasions, demonstrating the highly variable composition of WW fuels. The efficiency of sieving as a pre-treatment measure to reduce the levels of contaminants was not sufficient, revealing that sieving should be used in combination with other pre-treatment methods. The results from this case study provide knowledge on waste wood composition that may benefit its management. This knowledge can be applied for selection of the most suitable pre-treatments to obtain high quality sustainable WW fuels.

  18. [Evaluation of the migration of contaminants from building materials produced on the base of blast-furnace slags].

    PubMed

    Pugin, K G; Vaysman, Ya I

    2014-01-01

    There is experimentally established the change of the migratory activity of pollutants from building materials produced from blast furnace slag throughout their life cycle in the form of a nonlinear wave-like nature as there are appeared newly opened surfaces of a contact with aggressive waters in the process of gradual crushing of materials as a result of destructive mechanical effects on him and corrosive waters with varying pH values. There are established regularities of the migration activity ofpollutants (on the example of heavy metals) as directly dependent on the newly opening surface of the contact of the material with water having a various pH value. There is shown an expediency of introduction of alterations in the procedure for sanitary hygienic assessment of building materials with the addition of industrial waste (Methodical Instructions 2.1.674-97), allowing to take into account the migration of contaminants from them throughout the life cycle.

  19. Immobilization of Cu, Pb and Zn in mine-contaminated soils using reactive materials.

    PubMed

    Navarro, Andrés; Cardellach, Esteve; Corbella, Mercé

    2011-02-28

    Immobilization processes were used to chemically stabilize soil contaminated with Cu, Pb and Zn from mine tailings and industrial impoundments. We examined the effectiveness of ordinary Portland cement (OPC), phosphoric acid and MgO at immobilizing Cu, Pb and Zn in soil contaminated by either mine tailings or industrial and mine wastes. The effectiveness was evaluated using column leaching experiments and geochemical modelling, in which we assessed possible mechanisms for metal immobilization using PHREEQC and Medusa numerical codes. Experimental results showed that Cu was mobilized in all the experiments, whereas Pb immobilization with H(3)PO(4) may have been related to the precipitation of chloropyromorphite. Thus, the Pb concentrations of leachates of pure mining and industrial contaminated soils (32-410 μg/l and 430-1000 μg/l, respectively) were reduced to 1-60 and 3-360 μg/l, respectively, in the phosphoric acid experiment. The mobilization of Pb at high alkaline conditions, when Pb(OH)(4)(-) is the most stable species, may be the main obstacle to the use of OPC and MgO in the immobilization of this metal. In the mining- and industry-contaminated soil, Zn was retained by OPC but removed by MgO. The experiments with OPC showed the Zn decrease in the leachates of mining soil from 226-1960 μg/l to 92-121 μg/l. In the industrial contaminated soil, the Zn decrease in the leachates was most elevated, showing >2500 μg/l in the leachates of contaminated soil and 76-173 μg/l in the OPC experiment. Finally, when H(3)PO(4) was added, Zn was mobilized.

  20. Sensitivity of sediment contamination in the Elbe Estuary to climate change

    NASA Astrophysics Data System (ADS)

    Kleisinger, Carmen; Haase, Holger; Hentschke, Uwe; Schubert, Birgit

    2015-04-01

    the far future exceed the national assessment criteria for the handling of dredged material within coastal waterways more distinct than today. Therefore, adaptations of practices for the management of dredged material to higher particulate matter contaminations should be considered there in the medium or long-term perspective. On the one hand, e.g. the practices of depositing dredged- material within the water system might be adapted (BfG 2014). On the other hand, the implementation of remediation measures like those planned under the Water Framework Directive could mitigate the climate-induced increase of contaminants. However, before the planning of adaption measures begins, the respectively prevailing contamination status should be verified, as climate-induced changes of contaminant concentrations might be superimposed by direct anthropogenic activities, e.g. remediation measures to reduce contamination or construction works in waterways. Literature: BfG - Bundesanstalt für Gewässerkunde (2014) Sedimentmanagement Tideelbe - Strategien und Potenziale - Systemstudie II. Ökologische Auswirkungen der Unterbringung von Feinmaterial. Band 1, Endbericht. Im Auftrag des Wasser- und Schifffahrtsamtes Hamburg. Bundesanstalt für Gewässerkunde, Koblenz, BfG-Bericht 1763 IPCC (2007) Climate Change 2007 The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change [Solomon, S., D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor and H.L. Miller (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 996 pp.