40 CFR 63.2163 - If I monitor fermenter exhaust, what are my monitoring installation, operation, and maintenance...

Code of Federal Regulations, 2010 CFR

2010-07-01

...-accuracy test PS 8 requires. (3) If you continuously monitor VOC emissions using gas chromatography, you... percent of the span value (or more than 10 percent of the calibration gas value if your CEMS is a gas... calibration drift exceeds 5 percent of the span value (or more than 20 percent of the calibration gas value...

40 CFR 63.2163 - If I monitor fermenter exhaust, what are my monitoring installation, operation, and maintenance...

Code of Federal Regulations, 2011 CFR

2011-07-01

...-accuracy test PS 8 requires. (3) If you continuously monitor VOC emissions using gas chromatography, you... percent of the span value (or more than 10 percent of the calibration gas value if your CEMS is a gas... calibration drift exceeds 5 percent of the span value (or more than 20 percent of the calibration gas value...

Continuous CO2 gas monitoring to clarify natural pattern and artificial leakage signals

NASA Astrophysics Data System (ADS)

Joun, W.; Ha, S. W.; Joo, Y. J.; Lee, S. S.; Lee, K. K.

2017-12-01

Continuous CO2 gas monitoring at shallow aquifer is significant for early detection and immediate handling of an aquifer impacted by leaking CO2 gas from the sequestration reservoir. However, it is difficult to decide the origin of CO2 gas because detected CO2 includes not only leaked CO2 but also naturally emitted CO2. We performed CO2 injection and monitoring tests in a shallow aquifer. Before the injection of CO2 infused water, we have conducted continuous monitoring of multi-level soil CO2 gas concentration and physical parameters such as temperature, humidity, pressure, wind speed and direction, and precipitation. The monitoring data represented that CO2 gas concentrations in unsaturated soil zone borehole showed differences at depths and daily variation (360 to 6980 ppm volume). Based on the observed data at 5 m and 8 m depths, vertical flux of gas was calculated as 0.471 L/min (LPM) for inflow from 5 m to 8 m and 9.42E-2 LPM for outflow from 8 m to 5 m. The numerical and analytical models were used to calculate the vertical flux of gas and to compare with observations. The results showed that pressure-based modeling could not explain the rapid change of CO2 gas concentration in borehole. Acknowledgement Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003)

40 CFR 98.364 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... or operator shall document the procedures used to ensure the accuracy of gas flow rate, gas... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Manure Management § 98.364 Monitoring and QA/QC requirements... fraction of total manure managed in each system component. (c) The CH4 concentration of gas from digesters...

40 CFR 98.364 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... or operator shall document the procedures used to ensure the accuracy of gas flow rate, gas... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Manure Management § 98.364 Monitoring and QA/QC requirements... fraction of total manure managed in each system component. (c) The CH4 concentration of gas from digesters...

40 CFR 98.364 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... or operator shall document the procedures used to ensure the accuracy of gas flow rate, gas... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Manure Management § 98.364 Monitoring and QA/QC requirements... fraction of total manure managed in each system component. (c) The CH4 concentration of gas from digesters...

40 CFR Table Hh-4 to Subpart Hh of... - Landfill Methane Oxidation Fractions

Code of Federal Regulations, 2014 CFR

2014-07-01

... gas sent off-site). If a single monitoring location is used to monitor volumetric flow and CH4... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Landfill Methane Oxidation Fractions... (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Municipal Solid Waste Landfills Pt...

EPA Protocol Gas Verification Program - Presented at NIST Gas Panel Meeting

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensure that c...

40 CFR 63.3968 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

...: (1) For a thermal oxidizer, install a gas temperature monitor in the firebox of the thermal oxidizer...) For a catalytic oxidizer, install gas temperature monitors upstream and/or downstream of the catalyst... the requirements in paragraphs (a) and (c)(3)(i) through (v) of this section for each gas temperature...

40 CFR 63.3968 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

...: (1) For a thermal oxidizer, install a gas temperature monitor in the firebox of the thermal oxidizer...) For a catalytic oxidizer, install gas temperature monitors upstream and/or downstream of the catalyst... the requirements in paragraphs (a) and (c)(3)(i) through (v) of this section for each gas temperature...

Microfabricated fuel heating value monitoring device

DOEpatents

Robinson, Alex L [Albuquerque, NM; Manginell, Ronald P [Albuquerque, NM; Moorman, Matthew W [Albuquerque, NM

2010-05-04

A microfabricated fuel heating value monitoring device comprises a microfabricated gas chromatography column in combination with a catalytic microcalorimeter. The microcalorimeter can comprise a reference thermal conductivity sensor to provide diagnostics and surety. Using microfabrication techniques, the device can be manufactured in production quantities at a low per-unit cost. The microfabricated fuel heating value monitoring device enables continuous calorimetric determination of the heating value of natural gas with a 1 minute analysis time and 1.5 minute cycle time using air as a carrier gas. This device has applications in remote natural gas mining stations, pipeline switching and metering stations, turbine generators, and other industrial user sites. For gas pipelines, the device can improve gas quality during transfer and blending, and provide accurate financial accounting. For industrial end users, the device can provide continuous feedback of physical gas properties to improve combustion efficiency during use.

40 CFR Appendix E to Part 52 - Performance Specifications and, Specification Test Procedures for Monitoring Systems for Effluent...

Code of Federal Regulations, 2011 CFR

2011-07-01

..., Specification Test Procedures for Monitoring Systems for Effluent Stream Gas Volumetric Flow Rate E Appendix E... Stream Gas Volumetric Flow Rate 1. Principle and applicability. 1.1Principle. Effluent stream gas... method is applicable to subparts which require continuous gas volumetric flow rate measurement...

40 CFR Appendix E to Part 52 - Performance Specifications and, Specification Test Procedures for Monitoring Systems for Effluent...

Code of Federal Regulations, 2010 CFR

2010-07-01

..., Specification Test Procedures for Monitoring Systems for Effluent Stream Gas Volumetric Flow Rate E Appendix E... Stream Gas Volumetric Flow Rate 1. Principle and applicability. 1.1Principle. Effluent stream gas... method is applicable to subparts which require continuous gas volumetric flow rate measurement...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX...

In-line real time air monitor

DOEpatents

Wise, Marcus B.; Thompson, Cyril V.

1998-01-01

An in-line gas monitor capable of accurate gas composition analysis in a continuous real time manner even under strong applied vacuum conditions operates by mixing an air sample with helium forming a sample gas in two complementary sample loops embedded in a manifold which includes two pairs of 3-way solenoid valves. The sample gas is then analyzed in an ion trap mass spectrometer on a continuous basis. Two valve drivers actuate the two pairs of 3-way valves in a reciprocating fashion, so that there is always flow through the in-line gas monitor via one or the other of the sample loops. The duty cycle for the two pairs of 3-way valves is varied by tuning the two valve drivers to a duty cycle typically between 0.2 to 0.7 seconds.

40 CFR 60.1745 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2010 CFR

2010-07-01

... carbon dioxide instead of oxygen as a diluent gas? 60.1745 Section 60.1745 Protection of Environment... choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous emission monitoring...

40 CFR 60.1745 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2012 CFR

2012-07-01

... carbon dioxide instead of oxygen as a diluent gas? 60.1745 Section 60.1745 Protection of Environment... choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous emission monitoring...

40 CFR 60.1745 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2014 CFR

2014-07-01

... carbon dioxide instead of oxygen as a diluent gas? 60.1745 Section 60.1745 Protection of Environment... choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous emission monitoring...

40 CFR 60.1745 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2011 CFR

2011-07-01

... carbon dioxide instead of oxygen as a diluent gas? 60.1745 Section 60.1745 Protection of Environment... choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous emission monitoring...

40 CFR 60.1745 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2013 CFR

2013-07-01

... carbon dioxide instead of oxygen as a diluent gas? 60.1745 Section 60.1745 Protection of Environment... choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous emission monitoring...

76 FR 18415 - Continuous Emission Monitoring

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-04

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 75 Continuous Emission Monitoring CFR Correction In... Sec. 75.11, paragraph (f) is added to read as follows: Sec. 75.11 Specific provisions for monitoring... wood, refuse, or other material in addition to oil or gas shall comply with the monitoring provisions...

40 CFR 98.394 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.394 Monitoring and QA/QC requirements. (a) Determination of quantity. (1) The quantity of petroleum products, natural gas liquids, and... each petroleum product or natural gas liquid on any day of each calendar month of the reporting year in...

40 CFR 98.394 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.394 Monitoring and QA/QC requirements. (a) Determination of quantity. (1) The quantity of petroleum products, natural gas liquids, and... each petroleum product or natural gas liquid on any day of each calendar month of the reporting year in...

40 CFR 98.394 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.394 Monitoring and QA/QC requirements. (a) Determination of quantity. (1) The quantity of petroleum products, natural gas liquids, and... or natural gas liquid on any day of each calendar month of the reporting year in which the quantity...

40 CFR 98.394 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.394 Monitoring and QA/QC requirements. (a) Determination of quantity. (1) The quantity of petroleum products, natural gas liquids, and... each petroleum product or natural gas liquid on any day of each calendar month of the reporting year in...

40 CFR 98.394 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.394 Monitoring and QA/QC requirements. (a) Determination of quantity. (1) The quantity of petroleum products, natural gas liquids... product or natural gas liquid on any day of each calendar month of the reporting year in which the...

EPA Protocol Gas Verification Program

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensure that co...

40 CFR 60.5407 - What are the requirements for monitoring of emissions and operations from my sweetening unit...

Code of Federal Regulations, 2013 CFR

2013-07-01

... concentration in the acid gas from the sweetening unit for each 24-hour period. At least one sample per 24-hour... sampling schedule. (3) The average acid gas flow rate from the sweetening unit. You must install and operate a monitoring device to continuously measure the flow rate of acid gas. The monitoring device...

40 CFR 60.5407 - What are the requirements for monitoring of emissions and operations from my sweetening unit...

Code of Federal Regulations, 2014 CFR

2014-07-01

... concentration in the acid gas from the sweetening unit for each 24-hour period. At least one sample per 24-hour... sampling schedule. (3) The average acid gas flow rate from the sweetening unit. You must install and operate a monitoring device to continuously measure the flow rate of acid gas. The monitoring device...

A novel in-situ method for real-time monitoring of gas transport in soil

NASA Astrophysics Data System (ADS)

Laemmel, Thomas; Maier, Martin; Schack-Kirchner, Helmer; Lang, Friederike

2017-04-01

Gas exchange between soil and atmosphere is important for the biogeochemistry of soils. Gas transport in soil is commonly assumed to be governed by molecular diffusion and is usually described by the soil gas diffusion coefficient DS characterizing the ability of the soil to "transport passively" gas through the soil. One way to determine DS is sampling soil cores in the field and measuring DS in the lab. Unfortunately this method is destructive and laborious. Moreover, a few previous field studies identified other gas transport processes in soil to significantly enhance the diffusive gas transport. However, until now, no method is available to measure gas transport in situ in the soil. We developed a novel method to monitor gas transport in soil in situ. The method includes a custom made gas sampling device, the continuous injection of an inert tracer gas and inverse gas transport modelling in the soil. The gas sampling device has several sampling depths and can be easily installed into a vertical hole drilled by an auger, which allows for fast installation of the system. Helium (He) as inert tracer gas was injected continuously at the lower end of the device. The resulting steady state distribution of He was used to deduce the depth profile of DS. Gas transport in the soil surrounding the gas-sampling-device/soil system was modeled using the Finite Element Modeling program COMSOL . We tested our new method both in the lab and during two short field studies and compared the results with a reference method using soil cores. DS profiles obtained by our in-situ method were consistent with DS profiles determined based on soil core analyses. During a longer monitoring field campaign, typical soil-moisture effects upon gas diffusivity such as an increase during a drying period or a decrease after rain could be observed consistently. Under windy conditions we additionally measured for the first time the direct enhancement of gas transport in soil due to wind-induced pressure-pumping which could increase the effective DS up to 30% in the topsoil. Our novel monitoring method can be quickly and easily installed and allows for monitoring continuously soil gas transport over a long time. It allows monitoring physical modifications of soil gas diffusivity due to rain events or evaporation but it also allows studying non-diffusive gas transport processes in the soil.

40 CFR 60.1365 - What records must I keep for continuously monitored pollutants or parameters?

Code of Federal Regulations, 2010 CFR

2010-07-01

... diluent gas, document the relationship between oxygen and carbon dioxide, as specified in § 60.1255. (h... continuously monitored pollutants or parameters? 60.1365 Section 60.1365 Protection of Environment... Recordkeeping § 60.1365 What records must I keep for continuously monitored pollutants or parameters? You must...

40 CFR 60.1365 - What records must I keep for continuously monitored pollutants or parameters?

Code of Federal Regulations, 2011 CFR

2011-07-01

... diluent gas, document the relationship between oxygen and carbon dioxide, as specified in § 60.1255. (h... continuously monitored pollutants or parameters? 60.1365 Section 60.1365 Protection of Environment... Recordkeeping § 60.1365 What records must I keep for continuously monitored pollutants or parameters? You must...

40 CFR 60.1365 - What records must I keep for continuously monitored pollutants or parameters?

Code of Federal Regulations, 2013 CFR

2013-07-01

... diluent gas, document the relationship between oxygen and carbon dioxide, as specified in § 60.1255. (h... continuously monitored pollutants or parameters? 60.1365 Section 60.1365 Protection of Environment... Recordkeeping § 60.1365 What records must I keep for continuously monitored pollutants or parameters? You must...

40 CFR 60.1365 - What records must I keep for continuously monitored pollutants or parameters?

Code of Federal Regulations, 2012 CFR

2012-07-01

... diluent gas, document the relationship between oxygen and carbon dioxide, as specified in § 60.1255. (h... continuously monitored pollutants or parameters? 60.1365 Section 60.1365 Protection of Environment... Recordkeeping § 60.1365 What records must I keep for continuously monitored pollutants or parameters? You must...

40 CFR 60.1365 - What records must I keep for continuously monitored pollutants or parameters?

Code of Federal Regulations, 2014 CFR

2014-07-01

... diluent gas, document the relationship between oxygen and carbon dioxide, as specified in § 60.1255. (h... continuously monitored pollutants or parameters? 60.1365 Section 60.1365 Protection of Environment... Recordkeeping § 60.1365 What records must I keep for continuously monitored pollutants or parameters? You must...

In-line real time air monitor

DOEpatents

Wise, M.B.; Thompson, C.V.

1998-07-14

An in-line gas monitor capable of accurate gas composition analysis in a continuous real time manner even under strong applied vacuum conditions operates by mixing an air sample with helium forming a sample gas in two complementary sample loops embedded in a manifold which includes two pairs of 3-way solenoid valves. The sample gas is then analyzed in an ion trap mass spectrometer on a continuous basis. Two valve drivers actuate the two pairs of 3-way valves in a reciprocating fashion, so that there is always flow through the in-line gas monitor via one or the other of the sample loops. The duty cycle for the two pairs of 3-way valves is varied by tuning the two valve drivers to a duty cycle typically between 0.2 to 0.7 seconds. 3 figs.

40 CFR 60.343 - Monitoring of emissions and operations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... device for the continuous measurement of the pressure loss of the gas stream through the scrubber. The monitoring device must be accurate within ±250 pascals (one inch of water). (2) A monitoring device for continuous measurement of the scrubbing liquid supply pressure to the control device. The monitoring device...

40 CFR 65.161 - Continuous records and monitoring system data handling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Routing to a Fuel Gas System or a Process § 65.161 Continuous records and monitoring system data handling...) Monitoring system breakdowns, repairs, preventive maintenance, calibration checks, and zero (low-level) and... section unless an alternative monitoring or recordkeeping system has been requested and approved under...

40 CFR 65.161 - Continuous records and monitoring system data handling.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Routing to a Fuel Gas System or a Process § 65.161 Continuous records and monitoring system data handling...) Monitoring system breakdowns, repairs, preventive maintenance, calibration checks, and zero (low-level) and... section unless an alternative monitoring or recordkeeping system has been requested and approved under...

40 CFR 63.114 - Process vent provisions-monitoring requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., temperature monitoring devices shall be installed in the gas stream immediately before and after the catalyst... but not limited to a thermocouple, ultra-violet beam sensor, or infrared sensor) capable of... monitoring device in the firebox equipped with a continuous recorder. This requirement does not apply to gas...

40 CFR 63.114 - Process vent provisions-monitoring requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., temperature monitoring devices shall be installed in the gas stream immediately before and after the catalyst... but not limited to a thermocouple, ultra-violet beam sensor, or infrared sensor) capable of... monitoring device in the firebox equipped with a continuous recorder. This requirement does not apply to gas...

40 CFR 98.94 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electronics Manufacturing § 98.94 Monitoring and QA/QC...-specific heel factors for each container type for each gas used, according to the procedures in paragraphs...

40 CFR 98.154 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... equipment and methods (e.g., gas chromatography) with an accuracy and precision of 5 percent or better at... equipment and methods (e.g., gas chromatography) with an accuracy and precision of 5 percent or better at... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING HCFC-22 Production and HFC-23 Destruction § 98.154 Monitoring...

Current Status of EPA Protocol Gas Verification Program

EPA Science Inventory

Accurate compressed gas reference standards are needed to calibrate and audit continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensur...

49 CFR 193.2635 - Monitoring corrosion control.

Code of Federal Regulations, 2010 CFR

2010-10-01

....2635 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2635 Monitoring corrosion control...

49 CFR 193.2507 - Monitoring operations.

Code of Federal Regulations, 2010 CFR

2010-10-01

... Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY LIQUEFIED NATURAL GAS FACILITIES... watching or listening from an attended control center for warning alarms, such as gas, temperature...

CURRENT STATUS OF THE EPA PROTOCOL GAS PROGRAM

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. EPA has published a protocol to establish the traceability of these standards to national refer...

40 CFR 98.44 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Monitoring and QA/QC requirements. 98.44 Section 98.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.44 Monitoring and QA/QC...

40 CFR 98.44 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98.44 Section 98.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.44 Monitoring and QA/QC...

40 CFR 98.44 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98.44 Section 98.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.44 Monitoring and QA/QC...

40 CFR 98.44 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98.44 Section 98.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.44 Monitoring and QA/QC...

40 CFR 98.44 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98.44 Section 98.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electricity Generation § 98.44 Monitoring and QA/QC...

40 CFR 98.64 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Monitoring and QA/QC requirements. 98.64 Section 98.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Aluminum Production § 98.64 Monitoring and QA/QC requirements...

40 CFR 98.64 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98.64 Section 98.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Aluminum Production § 98.64 Monitoring and QA/QC requirements...

40 CFR 98.84 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98.84 Section 98.84 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.84 Monitoring and QA/QC requirements...

40 CFR 63.4768 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... requirements in paragraphs (c)(1) through (3) of this section: (1) For a thermal oxidizer, install a gas... firebox before any substantial heat exchange occurs. (2) For a catalytic oxidizer, you must install a gas temperature monitor in the gas stream immediately before the catalyst bed, and if you established operating...

40 CFR 63.4768 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... requirements in paragraphs (c)(1) through (3) of this section: (1) For a thermal oxidizer, install a gas... firebox before any substantial heat exchange occurs. (2) For a catalytic oxidizer, you must install a gas temperature monitor in the gas stream immediately before the catalyst bed, and if you established operating...

40 CFR 63.4168 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... paragraphs (a) and (c)(1) through (3) of this section: (1) For a thermal oxidizer, install a gas temperature... any substantial heat exchange occurs. (2) For a catalytic oxidizer, install a gas temperature monitor in the gas stream immediately before the catalyst bed, and if you establish operating limits...

40 CFR 63.4168 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... paragraphs (a) and (c)(1) through (3) of this section: (1) For a thermal oxidizer, install a gas temperature... any substantial heat exchange occurs. (2) For a catalytic oxidizer, install a gas temperature monitor in the gas stream immediately before the catalyst bed, and if you establish operating limits...

40 CFR 65.156 - General monitoring requirements for control and recovery devices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONSOLIDATED FEDERAL AIR RULE Closed Vent Systems, Control Devices, and Routing to a Fuel Gas System or a Process § 65.156 General monitoring requirements for... systems. (1) All monitoring equipment shall be installed, calibrated, maintained, and operated according...

40 CFR 63.4168 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling... regeneration desorbing gas mass flow monitor must be an integrating device having a measurement sensitivity of...

[Application of continuous intra-arterial blood gas monitoring system "Paratrend 7" for pulmonary lavage of a patient with alveolar proteinosis].

PubMed

Harigae, M; Hirose, Y; Gamo, M; Hirose, M; Fujiwara, C; Matsuo, K

1999-03-01

We applied a continuous intra-arterial blood gas monitoring system (Paratrend 7) to a patient with pulmonary alveolar proteinosis during pulmonary lavage. Lavage was performed under general anesthesia with one lung ventilation. We inserted the sensor of Patatrend 7 through a 20 G catheter into the radial artery, and monitored pH, PaCO2 and PaO2 continuously throughout the procedure. SpO2 and EtCO2 were also monitored. Saline 1000-1500 ml was instilled and drained repeatedly by volume limited methods. PaO2 values by Paratrend 7 increased during instillation and decreased during drainage of the irrigating fluid. In contrast, PaCO2 value by Paratrend 7 decreased slightly during instillation and increased during drainage. The change of SpO2 was almost the same as that by Paratrend 7, but the response time of pulse oxymetry was a little quicker than Paratrend 7. During the lavage procedure, respiratory and circulatory condition changed very rapidly, and it is necessary to monitor blood gas change intensively. Paratrend 7 is useful as a perioperative monitoring system, but pulse oxymetry might be sufficient during pulmonary lavage considering its cost.

An Integrated Architecture for On-Board Aircraft Engine Performance Trend Monitoring and Gas Path Fault Diagnostics

NASA Technical Reports Server (NTRS)

Simon, Donald L.

2010-01-01

Aircraft engine performance trend monitoring and gas path fault diagnostics are closely related technologies that assist operators in managing the health of their gas turbine engine assets. Trend monitoring is the process of monitoring the gradual performance change that an aircraft engine will naturally incur over time due to turbomachinery deterioration, while gas path diagnostics is the process of detecting and isolating the occurrence of any faults impacting engine flow-path performance. Today, performance trend monitoring and gas path fault diagnostic functions are performed by a combination of on-board and off-board strategies. On-board engine control computers contain logic that monitors for anomalous engine operation in real-time. Off-board ground stations are used to conduct fleet-wide engine trend monitoring and fault diagnostics based on data collected from each engine each flight. Continuing advances in avionics are enabling the migration of portions of the ground-based functionality on-board, giving rise to more sophisticated on-board engine health management capabilities. This paper reviews the conventional engine performance trend monitoring and gas path fault diagnostic architecture commonly applied today, and presents a proposed enhanced on-board architecture for future applications. The enhanced architecture gains real-time access to an expanded quantity of engine parameters, and provides advanced on-board model-based estimation capabilities. The benefits of the enhanced architecture include the real-time continuous monitoring of engine health, the early diagnosis of fault conditions, and the estimation of unmeasured engine performance parameters. A future vision to advance the enhanced architecture is also presented and discussed

Air Quality Monitor

NASA Technical Reports Server (NTRS)

1996-01-01

The Stak-Tracker CEM (Continuous Emission Monitor) Gas Analyzer is an air quality monitor capable of separating the various gases in a bulk exhaust stream and determining the amounts of individual gases present within the stream. The monitor is produced by GE Reuter- Stokes, a subsidiary of GE Corporate Research & Development Center. The Stak-Tracker uses a Langley Research Center software package which measures the concentration of a target gas by determining the degree to which molecules of that gas absorb an infrared beam. The system is environmental-friendly, fast and has relatively low installation and maintenance costs. It is applicable to gas turbines and various industries including glass, paper and cement.

Long-term autonomous volcanic gas monitoring with Multi-GAS at Mount St. Helens, Washington, and Augustine Volcano, Alaska

NASA Astrophysics Data System (ADS)

Kelly, P. J.; Ketner, D. M.; Kern, C.; Lahusen, R. G.; Lockett, C.; Parker, T.; Paskievitch, J.; Pauk, B.; Rinehart, A.; Werner, C. A.

2015-12-01

In recent years, the USGS Volcano Hazards Program has worked to implement continuous real-time in situ volcanic gas monitoring at volcanoes in the Cascade Range and Alaska. The main goal of this ongoing effort is to better link the compositions of volcanic gases to other real-time monitoring data, such as seismicity and deformation, in order to improve baseline monitoring and early detection of volcanic unrest. Due to the remote and difficult-to-access nature of volcanic-gas monitoring sites in the Cascades and Alaska, we developed Multi-GAS instruments that can operate unattended for long periods of time with minimal direct maintenance from field personnel. Our Multi-GAS stations measure H2O, CO2, SO2, and H2S gas concentrations, are comprised entirely of commercial off-the-shelf components, and are powered by small solar energy systems. One notable feature of our Multi-GAS stations is that they include a unique capability to perform automated CO2, SO2, and H2S sensor verifications using portable gas standards while deployed in the field, thereby allowing for rigorous tracking of sensor performances. In addition, we have developed novel onboard data-processing routines that allow diagnostic and monitoring data - including gas ratios (e.g. CO2/SO2) - to be streamed in real time to internal observatory and public web pages without user input. Here we present over one year of continuous data from a permanent Multi-GAS station installed in August 2014 in the crater of Mount St. Helens, Washington, and several months of data from a station installed near the summit of Augustine Volcano, Alaska in June 2015. Data from the Mount St. Helens Multi-GAS station has been streaming to a public USGS site since early 2015, a first for a permanent Multi-GAS site. Neither station has detected significant changes in gas concentrations or compositions since they were installed, consistent with low levels of seismicity and deformation.

40 CFR Appendix D to Part 52 - Determination of Sulfur Dioxide Emissions From Stationary Sources by Continuous Monitors

Code of Federal Regulations, 2011 CFR

2011-07-01

... Emissions From Stationary Sources by Continuous Monitors D Appendix D to Part 52 Protection of Environment... equipment required for the continuous determination of SO2 gas concentration in a given source effluent. 1... Drift. The change in measurement system output over a stated period of time of normal continuous...

2014 ICHLNRRA intercomparison of radon/thoron gas and radon short-lived decay products measuring instruments in the NRPI Prague.

PubMed

Jílek, K; Timková, J

2015-06-01

During the Eighth International Conference on High Levels of Natural Radiation and Radon Areas held in autumn 2014 at Prague, the third intercomparison of radon/thoron gas and radon short-lived decay products measurement instruments was organised by and held at the Natural Radiation Division of the National Radiation Protection Institute (NRPI; SÚRO v.v.i.) in Prague. The intercomparison was newly focussed also on continuous monitors with active sampling adapters capable to distinguish radon/thoron gas in their mix field.The results of radon gas measurements carried out in the big NRPI radon chamber indicated very well an average deviation of up to 5 % from the reference NRPI value for 80 % of all the exposed instruments. The results of equilibrium equivalent concentration continuous monitors indicated an average deviation of up to 5 % from the reference NRPI value for 40 % of all the exposed instruments and their ~8-10 % shift compared with the NRPI. The results of investigated ambient conditions upon response of exposed continuous monitors indicated influence of aerosol changes upon response of radon monitors with an active air sampling adapters through the filter, only. The exposures of both radon/thoron gas discriminative continuous monitors and passive detectors have been indicated inconsistent results: on one hand, their excellent agreement up to several per cent for both the gases, and on the other hand, systematic unsatisfactory differences up to 40 %. Additional radon/thoron exercises are recommended to improve both the instruments themselves and quality of their operators. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

40 CFR Appendix A to Part 75 - Specifications and Test Procedures

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specifications and Test Procedures A... (CONTINUED) CONTINUOUS EMISSION MONITORING Pt. 75, App. A Appendix A to Part 75—Specifications and Test... concentration monitor and diluent gas monitor) will pass the relative accuracy test (see section 6 of this...

40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... wood and 14.0% for natural gas (boilers, only); or (2) Install, operate, maintain, and quality assure a continuous moisture monitoring system for measuring and recording the moisture content of the flue gases, in... monitoring systems are acceptable: a continuous moisture sensor; an oxygen analyzer (or analyzers) capable of...

40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... wood and 14.0% for natural gas (boilers, only); or (2) Install, operate, maintain, and quality assure a continuous moisture monitoring system for measuring and recording the moisture content of the flue gases, in... monitoring systems are acceptable: a continuous moisture sensor; an oxygen analyzer (or analyzers) capable of...

40 CFR 63.3547 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2012 CFR

2012-07-01

... adsorber as an add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and... regeneration desorbing gas mass flow monitor must be an integrating device having an accuracy of ±10 percent...

40 CFR 63.3547 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2013 CFR

2013-07-01

... adsorber as an add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and... regeneration desorbing gas mass flow monitor must be an integrating device having an accuracy of ±10 percent...

40 CFR 63.3547 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... adsorber as an add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and... regeneration desorbing gas mass flow monitor must be an integrating device having an accuracy of ±10 percent...

Applicability of Monte-Carlo Simulation to Equipment Design of Radioactive Noble Gas Monitor

NASA Astrophysics Data System (ADS)

Sakai, Hirotaka; Hattori, Kanako; Umemura, Norihiro

In the nuclear facilities, radioactive noble gas is continuously monitored by using the radioactive noble gas monitor with beta-sensitive plastic scintillation radiation detector. The detection efficiency of the monitor is generally calibrated by using a calibration loop and standard radioactive noble gases such as 85Kr. In this study, the applicability of PHITS to the equipment design of the radioactive noble gas monitor was evaluated by comparing the calculated results to the test results obtained by actual calibration loop tests to simplify the radiation monitor design evaluation. It was confirmed that the calculated results were well matched to the test results of the monitor after the modeling. In addition, the key parameters for equipment design, such as thickness of detector window or depth of the sampler, were also specified and evaluated.

40 CFR 62.15200 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2012 CFR

2012-07-01

... carbon dioxide instead of oxygen as a diluent gas? 62.15200 Section 62.15200 Protection of Environment... I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous...

40 CFR 62.15200 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2010 CFR

2010-07-01

... carbon dioxide instead of oxygen as a diluent gas? 62.15200 Section 62.15200 Protection of Environment... I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous...

40 CFR 62.15200 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2011 CFR

2011-07-01

... carbon dioxide instead of oxygen as a diluent gas? 62.15200 Section 62.15200 Protection of Environment... I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous...

40 CFR 62.15200 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2014 CFR

2014-07-01

... carbon dioxide instead of oxygen as a diluent gas? 62.15200 Section 62.15200 Protection of Environment... I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous...

40 CFR 62.15200 - What must I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas?

Code of Federal Regulations, 2013 CFR

2013-07-01

... carbon dioxide instead of oxygen as a diluent gas? 62.15200 Section 62.15200 Protection of Environment... I do if I choose to monitor carbon dioxide instead of oxygen as a diluent gas? You must establish the relationship between oxygen and carbon dioxide during the initial evaluation of your continuous...

Continuous analysis of nitrogen dioxide in gas streams of plants

NASA Technical Reports Server (NTRS)

Durkin, W. T.; Kispert, R. C.

1969-01-01

Analyzer and sampling system continuously monitors nitrogen dioxide concentrations in the feed and tail gas streams of a facility recovering nitric acid. The system, using a direct calorimetric approach, makes use of readily available equipment and is flexible and reliable in operation.

AN ADVANCED FLUE GAS MONITOR FOR SO2 - PHASE I

EPA Science Inventory

The development of an instrument for continuously monitoring SO2 levels in flue gas is proposed. The SO2 will be detected by means of an electrochemical sensor cell, which operates in a three-electrode potentiostatic mode. The proposed innovation is develop-ment of an advan...

40 CFR 98.404 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.404... determine the quantity of NGLs and natural gas using methods in common use in the industry for billing... National Standards Institute (ANSI), the American Gas Association (AGA), the American Society of Mechanical...

40 CFR 98.404 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.404... determine the quantity of NGLs and natural gas using methods in common use in the industry for billing... National Standards Institute (ANSI), the American Gas Association (AGA), the American Society of Mechanical...

40 CFR 98.404 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.404... determine the quantity of NGLs and natural gas using methods in common use in the industry for billing... National Standards Institute (ANSI), the American Gas Association (AGA), the American Society of Mechanical...

40 CFR 98.404 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.404... determine the quantity of NGLs and natural gas using methods in common use in the industry for billing... National Standards Institute (ANSI), the American Gas Association (AGA), the American Society of Mechanical...

40 CFR 98.404 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Natural Gas and Natural Gas Liquids § 98.404... determine the quantity of NGLs and natural gas using methods in common use in the industry for billing... National Standards Institute (ANSI), the American Gas Association (AGA), the American Society of Mechanical...

40 CFR 98.434 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98.434 Section 98.434 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Importers and Exporters of Fluorinated Greenhouse Gases...

Fluidized Bed Boiler Assessment for Navy Applications

DTIC Science & Technology

1986-11-01

rather than removing it from the flue gas later with "scrubbing" devices. Intro- duction of limestone in the bed will reduce SO emissions; two...boiler in a satisfactory manner, the bed level, combustion temperature, and the flue gas composition and temperature should be continuously monitored...The flue gas composition should be c^-ɝely monitored for pollutants and combustion efficiency. EVOLUTION OF FBC BOILERS The performance of FBC

75 FR 33391 - Amendments to the Protocol Gas Verification Program and Minimum Competency Requirements for Air...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-11

...Recent EPA gas audit results indicate that some gas cylinders used to calibrate continuous emission monitoring systems on stationary sources do not meet EPA's performance specification. Reviews of stack test reports in recent years indicate that some stack testers do not properly follow EPA test methods or do not correctly calculate test method results. Therefore, EPA is proposing to amend its Protocol Gas Verification Program (PGVP) and the minimum competency requirements for air emission testing (formerly air emission testing body requirements) to improve the accuracy of emissions data. EPA is also proposing to amend other sections of the Acid Rain Program continuous emission monitoring system regulations by adding and clarifying certain recordkeeping and reporting requirements, removing the provisions pertaining to mercury monitoring and reporting, removing certain requirements associated with a class-approved alternative monitoring system, disallowing the use of a particular quality assurance option in EPA Reference Method 7E, adding an incorporation by reference that was inadvertently left out of the January 24, 2008 final rule, and clarifying the language and applicability of certain provisions.

Continuous haematic pH monitoring in extracorporeal circulation using a disposable florescence sensing element

NASA Astrophysics Data System (ADS)

Ferrari, Luca; Rovati, Luigi; Fabbri, Paola; Pilati, Francesco

2013-02-01

During extracorporeal circulation (ECC), blood is periodically sampled and analyzed to maintain the blood-gas status of the patient within acceptable limits. This protocol has well-known drawbacks that may be overcome by continuous monitoring. We present the characterization of a new pH sensor for continuous monitoring in ECC. This monitoring device includes a disposable fluorescence-sensing element directly in contact with the blood, whose fluorescence intensity is strictly related to the pH of the blood. In vitro experiments show no significant difference between the blood gas analyzer values and the sensor readings; after proper calibration, it gives a correlation of R>0.9887, and measuring errors were lower than the 3% of the pH range of interest (RoI) with respect to a commercial blood gas analyzer. This performance has been confirmed also by simulating a moderate ipothermia condition, i.e., blood temperature 32°C, frequently used in cardiac surgery. In ex vivo experiments, performed with animal models, the sensor is continuously operated in an extracorporeal undiluted blood stream for a maximum of 11 h. It gives a correlation of R>0.9431, and a measuring error lower than the 3% of the pH RoI with respect to laboratory techniques.

Continuous haematic pH monitoring in extracorporeal circulation using a disposable florescence sensing element.

PubMed

Ferrari, Luca; Rovati, Luigi; Fabbri, Paola; Pilati, Francesco

2013-02-01

During extracorporeal circulation (ECC), blood is periodically sampled and analyzed to maintain the blood-gas status of the patient within acceptable limits. This protocol has well-known drawbacks that may be overcome by continuous monitoring. We present the characterization of a new pH sensor for continuous monitoring in ECC. This monitoring device includes a disposable fluorescence-sensing element directly in contact with the blood, whose fluorescence intensity is strictly related to the pH of the blood. In vitro experiments show no significant difference between the blood gas analyzer values and the sensor readings; after proper calibration, it gives a correlation of R>0.9887, and measuring errors were lower than the 3% of the pH range of interest (RoI) with respect to a commercial blood gas analyzer. This performance has been confirmed also by simulating a moderate ipothermia condition, i.e., blood temperature 32°C, frequently used in cardiac surgery. In ex vivo experiments, performed with animal models, the sensor is continuously operated in an extracorporeal undiluted blood stream for a maximum of 11 h. It gives a correlation of R>0.9431, and a measuring error lower than the 3% of the pH RoI with respect to laboratory techniques.

40 CFR 63.1350 - Monitoring requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., operate, calibrate, and maintain an instrument for continuously measuring and recording the exhaust gas... continuous monitor to record the temperature of the exhaust gases from the kiln, in-line kiln/raw mill, and... Administrator. (iii) The calibration of all thermocouples and other temperature sensors must be verified at...

49 CFR 192.477 - Internal corrosion control: Monitoring.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 49 Transportation 3 2012-10-01 2012-10-01 false Internal corrosion control: Monitoring. 192.477 Section 192.477 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELIN...

49 CFR 192.477 - Internal corrosion control: Monitoring.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 49 Transportation 3 2014-10-01 2014-10-01 false Internal corrosion control: Monitoring. 192.477 Section 192.477 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELIN...

49 CFR 192.477 - Internal corrosion control: Monitoring.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 49 Transportation 3 2013-10-01 2013-10-01 false Internal corrosion control: Monitoring. 192.477 Section 192.477 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELIN...

40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

Code of Federal Regulations, 2010 CFR

2010-07-01

... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

40 CFR 75.22 - Reference test methods.

Code of Federal Regulations, 2011 CFR

2011-07-01

... recertification of continuous emission monitoring Systems; NOX emission tests of low mass emission units under... continuous moisture monitoring systems are conducted. For the purpose of determining the stack gas molecular... traverse requirement of the method; (iv) Section 8.6 of the method allowing for the use of “Dynamic Spiking...

40 CFR 98.144 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.144 Monitoring and QA/QC requirements. (a) You must measure annual amounts of carbonate-based raw materials charged to each continuous glass... calibrated scales or weigh hoppers. Total annual mass charged to glass melting furnaces at the facility shall...

Monte Carlo Uncertainty Quantification for an Unattended Enrichment Monitor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jarman, Kenneth D.; Smith, Leon E.; Wittman, Richard S.

As a case study for uncertainty analysis, we consider a model flow monitor for measuring enrichment in gas centrifuge enrichment plants (GCEPs) that could provide continuous monitoring of all declared gas flow and provide high-accuracy gas enrichment estimates as a function of time. The monitor system could include NaI(Tl) gamma-ray spectrometers, a pressure signal-sharing device to be installed on an operator\\rq{}s pressure gauge or a dedicated inspector pressure sensor, and temperature sensors attached to the outside of the header pipe, to provide pressure, temperature, and gamma-ray spectra measurements of UFmore » $$_6$$ gas flow through unit header pipes. Our study builds on previous modeling and analysis methods development for enrichment monitor concepts and a software tool that was developed at Oak Ridge National Laboratory to generate and analyze synthetic data.« less

40 CFR 63.3557 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling cycle, and comply with paragraphs (a)(3) through (5) and (d)(1) and (2) of this section. (1) The regeneration desorbing gas mass flow...

40 CFR 63.3557 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling cycle, and comply with paragraphs (a)(3) through (5) and (d)(1) and (2) of this section. (1) The regeneration desorbing gas mass flow...

40 CFR 63.3557 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling cycle, and comply with paragraphs (a)(3) through (5) and (d)(1) and (2) of this section. (1) The regeneration desorbing gas mass flow...

LOWLY CHLORINATED DIBENZODIOXINS AS TEQ INDICATORS. A COMBINED APPROACH USING SPECTROSCOPIC MEASUREMENTS WITH DLR JET-REMPI AND STATISTICAL CORRELATIONS WITH WASTE COMBUSTOR EMISSIONS

EPA Science Inventory

Continuous monitoring of trace gas species in incineration processes can serve two purposes: (i) monitoring precursors of polychlorinated dibenzodioxin and polychlorinated dibenzofuran (PCDD/F) or other indicator species in the raw gas will enable use of their on-line signals for...

40 CFR 63.6125 - What are my monitor installation, operation, and maintenance requirements?

Code of Federal Regulations, 2014 CFR

2014-07-01

... emission control device, you must monitor on a continuous basis your catalyst inlet temperature in order to... combustion turbine which fires landfill gas or digester gas equivalent to 10 percent or more of the gross... the major source with a non-resettable hour meter to measure the number of hours that distillate oil...

40 CFR 63.6125 - What are my monitor installation, operation, and maintenance requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... control device, you must monitor on a continuous basis your catalyst inlet temperature in order to comply... combustion turbine which fires landfill gas or digester gas equivalent to 10 percent or more of the gross... the major source with a non-resettable hour meter to measure the number of hours that distillate oil...

40 CFR 63.6125 - What are my monitor installation, operation, and maintenance requirements?

Code of Federal Regulations, 2011 CFR

2011-07-01

... control device, you must monitor on a continuous basis your catalyst inlet temperature in order to comply... combustion turbine which fires landfill gas or digester gas equivalent to 10 percent or more of the gross... the major source with a non-resettable hour meter to measure the number of hours that distillate oil...

40 CFR 63.6125 - What are my monitor installation, operation, and maintenance requirements?

Code of Federal Regulations, 2013 CFR

2013-07-01

... emission control device, you must monitor on a continuous basis your catalyst inlet temperature in order to... combustion turbine which fires landfill gas or digester gas equivalent to 10 percent or more of the gross... the major source with a non-resettable hour meter to measure the number of hours that distillate oil...

Sensitive gas analysis system on a microchip and application for on-site monitoring of NH3 in a clean room.

PubMed

Hiki, Shinichiro; Mawatari, Kazuma; Aota, Arata; Saito, Maki; Kitamori, Takehiko

2011-06-15

A portable, highly sensitive, and continuous ammonia gas monitoring system was developed with a microfluidic chip. The system consists of a main unit, a gas pumping unit, and a computer which serves as an operation console. The size of the system is 45 cm width × 30 cm depth × 30 cm height, and the portable system was realized. A highly efficient and stable extraction method was developed by utilizing an annular gas/liquid laminar flow. In addition, a stable gas/liquid separation method with a PTFE membrane was developed by arranging a fluidic network in three dimensions to achieve almost zero dead volume at the gas/liquid extraction part. The extraction rate was almost 100% with a liquid flow rate of 3.5 μL/min and a gas flow rate of 100 mL/min (contact time of ~15 ms), and the concentration factor was 200 times by calculating the NH(3) concentration (w/w unit) in the gas and liquid phases. Stable phase separation and detection was sustained for more than 3 weeks in an automated operation, which was sufficient for the monitoring application. The lower limit of detection calculated based on a signal-to-noise ratio of 3 was 84 ppt, which showed good detectability for NH(3) analysis. We believe that our system is a very powerful tool for gas analysis due to the advantages of portable size, high sensitivity, and continuous monitoring, and it is particularly useful in the semiconductor field.

Vapor spill monitoring method

DOEpatents

Bianchini, Gregory M.; McRae, Thomas G.

1985-01-01

Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

Design and Testing of Trace Contaminant Injection and Monitoring Systems

NASA Technical Reports Server (NTRS)

Broerman, Craig D.; Sweterlitsch, Jeff

2009-01-01

In support of the Carbon dioxide And Moisture Removal Amine Swing-bed (CAMRAS) testing, a contaminant injection system as well as a contaminant monitoring system has been developed by the Johnson Space Center Air Revitalization Systems (JSC-ARS) team. The contaminant injection system has been designed to provide trace level concentrations of contaminants generated by humans in a closed environment during space flight missions. The contaminant injection system continuously injects contaminants from three gas cylinders, two liquid reservoirs and three permeation ovens. The contaminant monitoring system has been designed to provide real time gas analysis with accurate flow, humidity and gas concentration measurements for collection during test. The contaminant monitoring system consists of an analytical real time gas analyzer, a carbon monoxide sensor, and an analyzer for ammonia and water vapor.

40 CFR 75.10 - General operating requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... continuous emission monitoring system and a flow monitoring system with an automated data acquisition and handling system for measuring and recording SO2 concentration (in ppm), volumetric gas flow (in scfh), and... emission monitoring system and a flow monitoring system with an automated data acquisition and handling...

40 CFR Appendix D to Part 75 - Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units D Appendix D to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Pt. 75, App. D Appendix D to Part 75—Optional SO2 Emissions Data...

Beat frequency quartz-enhanced photoacoustic spectroscopy for fast and calibration-free continuous trace-gas monitoring

PubMed Central

Wu, Hongpeng; Dong, Lei; Zheng, Huadan; Yu, Yajun; Ma, Weiguang; Zhang, Lei; Yin, Wangbao; Xiao, Liantuan; Jia, Suotang; Tittel, Frank K.

2017-01-01

Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a sensitive gas detection technique which requires frequent calibration and has a long response time. Here we report beat frequency (BF) QEPAS that can be used for ultra-sensitive calibration-free trace-gas detection and fast spectral scan applications. The resonance frequency and Q-factor of the quartz tuning fork (QTF) as well as the trace-gas concentration can be obtained simultaneously by detecting the beat frequency signal generated when the transient response signal of the QTF is demodulated at its non-resonance frequency. Hence, BF-QEPAS avoids a calibration process and permits continuous monitoring of a targeted trace gas. Three semiconductor lasers were selected as the excitation source to verify the performance of the BF-QEPAS technique. The BF-QEPAS method is capable of measuring lower trace-gas concentration levels with shorter averaging times as compared to conventional PAS and QEPAS techniques and determines the electrical QTF parameters precisely. PMID:28561065

PIGC™ - A low cost fugitive emissions and methane detection system using advanced gas filter correlation techniques for local and wide area monitoring

NASA Astrophysics Data System (ADS)

Lachance, R. L.; Gordley, L. L.; Marshall, B. T.; Fisher, J.; Paxton, G.; Gubeli, J. F.

2015-12-01

Currently there is no efficient and affordable way to monitor gas releases over small to large areas. We have demonstrated the ability to accurately measure key greenhouse and pollutant gasses with low cost solar observations using the breakthrough sensor technology called the "Pupil Imaging Gas Correlation", PIGC™, which provides size and complexity reduction while providing exceptional resolution and coverage for various gas sensing applications. It is a practical implementation of the well-known Gas Filter Correlation Radiometry (GFCR) technique used for the HALOE and MOPITT satellite instruments that were flown on successful NASA missions in the early 2000s. This strong space heritage brings performance and reliability to the ground instrument design. A methane (CH4) abundance sensitivity of 0.5% or better of ambient column with uncooled microbolometers has been demonstrated with 1 second direct solar observations. These under $10 k sensors can be deployed in precisely balanced autonomous grids to monitor the flow of chosen gasses, and infer their source locations. Measureable gases include CH4, 13CO2, N2O, NO, NH3, CO, H2S, HCN, HCl, HF, HDO and others. A single instrument operates in a dual operation mode, at no additional cost, for continuous (real-time 24/7) local area perimeter monitoring for the detection of leaks for safety & security needs, looking at an artificial light source (for example a simple 60 W light bulb placed 100 m away), while simultaneously allowing solar observation for quasi-continuous wide area total atmospheric column scanning (3-D) for environmental monitoring (fixed and mobile configurations). The second mode of operation continuously quantifies the concentration and flux of specific gases over different ground locations, determined the amount of targeted gas being released from the area or getting into the area from outside locations, allowing better tracking of plumes and identification of sources. This paper reviews the measurement technique, performance demonstration and grid deployment strategy.

40 CFR 98.94 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electronics Manufacturing § 98.94 Monitoring and QA/QC requirements. (a) For calendar year 2011 monitoring, you may follow the provisions in paragraphs (a)(1) through...

40 CFR 98.94 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electronics Manufacturing § 98.94 Monitoring and QA/QC requirements. (a) For calendar year 2011 monitoring, you may follow the provisions in paragraphs (a)(1) through...

40 CFR 98.94 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Electronics Manufacturing § 98.94 Monitoring and QA/QC requirements. (a) For calendar year 2011 monitoring, you may follow the provisions in paragraphs (a)(1) through...

Tritium monitor

DOEpatents

Chastagner, Philippe

1994-01-01

A system for continuously monitoring the concentration of tritium in an aqueous stream. The system pumps a sample of the stream to magnesium-filled combustion tube which reduces the sample to extract hydrogen gas. The hydrogen gas is then sent to an isotope separation device where it is separated into two groups of isotopes: a first group of isotopes containing concentrations of deuterium and tritium, and a second group of isotopes having substantially no deuterium and tritium. The first group of isotopes containing concentrations of deuterium and tritium is then passed through a tritium detector that produces an output proportional to the concentration of tritium detected. Preferably, the detection system also includes the necessary automation and data collection equipment and instrumentation for continuously monitoring an aqueous stream.

Tritium monitor

DOEpatents

Chastagner, P.

1994-06-14

A system is described for continuously monitoring the concentration of tritium in an aqueous stream. The system pumps a sample of the stream to magnesium-filled combustion tube which reduces the sample to extract hydrogen gas. The hydrogen gas is then sent to an isotope separation device where it is separated into two groups of isotopes: a first group of isotopes containing concentrations of deuterium and tritium, and a second group of isotopes having substantially no deuterium and tritium. The first group of isotopes containing concentrations of deuterium and tritium is then passed through a tritium detector that produces an output proportional to the concentration of tritium detected. Preferably, the detection system also includes the necessary automation and data collection equipment and instrumentation for continuously monitoring an aqueous stream. 1 fig.

40 CFR Table 24 to Subpart Uuu of... - Continuous Monitoring Systems for Inorganic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... entering the scrubber during coke burn-off and catalyst rejuvenation; and continuous parameter monitoring system to measure and record gas flow rate entering or exiting the scrubber during coke burn-off and... alkalinity of the water (or scrubbing liquid) exiting the scrubber during coke burn-off and catalyst...

An in situ method for real-time monitoring of soil gas diffusivity

NASA Astrophysics Data System (ADS)

Laemmel, Thomas; Maier, Martin; Schack-Kirchner, Helmer; Lang, Friederike

2016-04-01

Soil aeration is an important factor for the biogeochemistry of soils. Generally, gas exchange between soil and atmosphere is assumed to be governed by molecular diffusion and by this way fluxes can be calculated using by Fick's Law. The soil gas diffusion coefficient DS represents the proportional factor between the gas flux and the gas concentration gradient in the soil and reflects the ability of the soil to "transport passively" gas through the soil. One common way to determine DS is taking core samples in the field and measuring DS in the lab. Unfortunately this method is destructive and laborious and it can only reflect a small fraction of the whole soil. As a consequence, uncertainty about the resulting effective diffusivity on the profile scale, i.e. the real aeration status remains. We developed a method to measure and monitor DS in situ. The set-up consists of a custom made gas sampling device, the continuous injection of an inert tracer gas and inverse gas transport modelling in the soil. The gas sampling device has seven sampling depths (from 0 to -43 cm of depth) and can be easily installed into vertical holes drilled by an auger, which allows for fast installation of the system. Helium (He) as inert tracer gas was injected continuously at the lower end of the device. The resulting steady state distribution of He was used to deduce the DS depth distribution of the soil. For Finite Element Modeling of the gas-sampling-device/soil system the program COMSOL was used. We tested our new method both in the lab and in a field study and compared the results with a reference lab method using soil cores. DS profiles obtained by our in-situ method were consistent with DS profiles determined based on soil core analyses. Soil gas profiles could be measured with a temporal resolution of 30 minutes. During the field study, there was an important rain event and we could monitor the decrease in soil gas diffusivity in the top soil due to water infiltration. The effect of soil water infiltration deeper into the soil on soil gas diffusivity could be observed during the following hours. Our new DS determination device can be quickly and easily installed and allows for monitoring continuously soil gas transport over a long time. It allows following modifications of soil gas diffusivity due to rain events. In addition it enables the analysis of non-diffusive soil gas transport processes.

Gas Sensor for Volatile Anesthetic Agents Based on Raman Scattering

NASA Astrophysics Data System (ADS)

Schlüter, Sebastian; Popovska-Leipertz, Nadejda; Seeger, Thomas; Leipertz, Alfred

Continuous monitoring of respiratory and anesthetic gases during a surgery is of vital importance for the patient safety. Commonly the gas composition is determined by gas chromatography or a combination of IR-spectroscopy and electrochemical sensors. This study presents a concept for an optical sensor based on spontaneous Raman scattering which offers several advantages compared to established systems. All essential components can be detected simultaneously, no sample preparation is necessary and it provides fast response times. To reach the performance of a commonly used gas monitor signal gain has to be increased e.g. by using a multi pass setup.

40 CFR 98.74 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.74 Monitoring and QA/QC... (c)(8) of this section. (f) [Reserved] (g) If CO2 from ammonia production is used to produce urea at...

40 CFR 98.74 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.74 Monitoring and QA/QC... (c)(8) of this section. (f)[Reserved] (g) If CO2 from ammonia production is used to produce urea at...

40 CFR 98.74 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.74 Monitoring and QA/QC... (c)(8) of this section. (f)[Reserved] (g) If CO2 from ammonia production is used to produce urea at...

40 CFR 98.74 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.74 Monitoring and QA/QC... (c)(8) of this section. (f) [Reserved] (g) If CO2 from ammonia production is used to produce urea at...

Monitoring environmental effects of shale gas exploitation at Wysin in Poland.

NASA Astrophysics Data System (ADS)

Lasocki, Stanislaw; Mirek, Janusz; Bialon, Wojciech; Cielesta, Szymon; Lasak, Mateusz; Cesca, Simone; Lopez Comino, Jose Angel; Dahm, Torsten; Scarpa, Roberto; Gunning, Andrew; Montcoudiol, Nelly; Isherwood, Catherine; Jaroslawski, Janusz; Guzikowski, Jakub

2017-04-01

Environmental effects of shale gas exploration and exploitation are extensively studied in the framework of "Shale Gas Exploration and Exploitation Induced Risks" project (SHEER, H2020-LCE 16-2014-1). One of the main component of this study is on-site monitoring of the effects at Wysin shale-gas play of Polish Oil and Gas Company in Poland. This includes monitoring of seismicity and water and air quality. Surface seismic monitoring network consists of 6 surface broadband (BB) seismometers and 25 surface short-period (SP) seismometers The SPs are assembled into three small aperture arrays with 9, 8 and 8 stations, respectively, distributed in a triangle geometry at a distance of about 2-4 km from the hydrofracturing rig. Each array is complemented with one BB station. The three remaining BBs are located up to about 5 km from the rig. In addition 3 borehole broadband seismometers are located in three shallow boreholes. The groundwater monitoring makes use of four wells, which reach a main underground water reservoir. Three complementary datasets are collected: continuous monitoring of borehole data, laboratory analyses of water samples and field monitoring of water quality parameters. The continuous monitoring makes use of down-hole probes, which have been installed in each borehole. The probes record absolute pressure, temperature and electrical conductivity. In addition, a barometric probe has been installed above ground to record atmospheric pressure in order to allow conversion of absolute pressure to a water level. After collection, water samples are sent to an accredited laboratory for analysis. The field monitoring is undertaken during the sampling visits. Whilst the borehole is being purged, physico-chemical parameters are monitored using a multi-parameter probe. This measures and records temperature, specific conductivity, pH, dissolved oxygen and oxidation-reduction potential within the water. Hydrocarbon gas content within the water is below detection limits for methane, ethane, ethene and propane gases. Air pollution monitoring is performed by means of an automatic station. The station is situated east from the Wysin rig at the distance of some 1200 m. This distance is appropriate in order not to measure a direct emission of pollutants. The station monitors the content of NO, NO2, NOx, CO, PM10, O3, CO2, CH4, NMHC and Radon. At the beginning of SHEER project in May 2015, there was one vertical well at the site, reaching gas-bearing shale formations at the nearly 4km depth. Further on two horizontal wells, each of about 1.7km length, were drilled (late Autumn 2015) and fracked (June - August, 2016). This time table has provided the opportunity to record background seismicity and baseline levels of water and air quality, and then to record the immediate and delayed effects of hydrofracturing operations. The monitoring will continue at least 1.5 year after completion of technological activity at the site. This work was supported within SHEER: "Shale Gas Exploration and Exploitation Induced Risks" project funded from Horizon 2020 - R&I Framework Programme, call H2020-LCE-2014-1 and within statutory activities No3841/E-41/S/2016 of Ministry of Science and Higher Education of Poland.

Development of the Fabry-Perot Spectrometer Application

NASA Technical Reports Server (NTRS)

Browne, Kathryn

2015-01-01

Methane is a greenhouse gas with global warming effects 20 times more detrimental than carbon dioxide. Currently, only aircraft missions measure methane and do not provide continuous monitoring, This presentation will cover the Fabry-Perot spectrometer which will provide continuous monitoring of methane. It will also cover the development of the software used to extract and process the data the spectrometer collects.

On Line Enrichment Monitor (OLEM) UF 6 Tests for 1.5" Sch40 SS Pipe, Revision 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

March-Leuba, José A.; Garner, Jim; Younkin, Jim

As global uranium enrichment capacity under international safeguards expands, the International Atomic Energy Agency (IAEA) is challenged to develop effective safeguards approaches at gaseous centrifuge enrichment plants while working within budgetary constraints. The “Model Safeguards Approach for Gas Centrifuge Enrichment Plants” (GCEPs) developed by the IAEA Division of Concepts and Planning in June 2006, defines the three primary Safeguards objectives to be the timely detection of: 1) diversion of significant quantities of natural (NU), depleted (DU) or low-enriched uranium (LEU) from declared plant flow, 2) facility misuse to produce undeclared LEU product from undeclared feed, and 3) facility misuse tomore » produce enrichments higher than the declared maximum, in particular, highly enriched uranium (HEU). The ability to continuously and independently (i.e. with a minimum of information from the facility operator) monitor not only the uranium mass balance but also the 235U mass balance in the facility could help support all three verification objectives described above. Two key capabilities required to achieve an independent and accurate material balance are 1) continuous, unattended monitoring of in-process UF 6 and 2) monitoring of cylinders entering and leaving the facility. The continuous monitoring of in-process UF 6 would rely on a combination of load-cell monitoring of the cylinders at the feed and withdrawal stations, online monitoring of gas enrichment, and a high-accuracy net weight measurement of the cylinder contents. The Online Enrichment Monitor (OLEM) is the instrument that would continuously measure the time-dependent relative uranium enrichment, E(t), in weight percent 235U, of the gas filling or being withdrawn from the cylinders. The OLEM design concept combines gamma-ray spectrometry using a collimated NaI(Tl) detector with gas pressure and temperature data to calculate the enrichment of the UF 6 gas within the unit header pipe as a function of time. The OLEM components have been tested on ORNL UF 6 flow loop. Data were collected at five different enrichment levels (0.71%, 2.97%, 4.62%, 6.0%, and 93.7%) at several pressure conditions. The test data were collected in the standard OLEM N.4242 file format for each of the conditions with a 10-minute sampling period and then averaged over the span of constant pressures. Analysis of the collected data has provided enrichment constants that can be used for 1.5” stainless steel schedule 40 pipe measurement sites. The enrichment constant is consistent among all the wide range of enrichment levels and pressures used.« less

Method and means of monitoring the effluent from nuclear facilities

DOEpatents

Lattin, Kenneth R.; Erickson, Gerald L.

1976-01-01

Radioactive iodine is detected in the effluent cooling gas from a nuclear reactor or nuclear facility by passing the effluent gas through a continuously moving adsorbent filter material which is then purged of noble gases and conveyed continuously to a detector of radioactivity. The purging operation has little or no effect upon the concentration of radioactive iodine which is adsorbed on the filter material.

40 CFR 98.444 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Geologic Sequestration of Carbon Dioxide § 98.444 Monitoring... volume of contents in all containers if you receive CO2 in containers by following the most appropriate...

40 CFR 98.424 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.424 Monitoring and QA/QC... determine quantity in accordance with this paragraph. (i) Reporters that supply CO2 in containers using...

40 CFR 98.424 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.424 Monitoring and QA/QC... determine quantity in accordance with this paragraph. (i) Reporters that supply CO2 in containers using...

40 CFR 98.334 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.334 Monitoring and QA/QC requirements. If..., belt weigh feeders, weighed purchased quantities in shipments or containers, combination of bulk...

40 CFR 98.424 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.424 Monitoring and QA/QC... determine quantity in accordance with this paragraph. (i) Reporters that supply CO2 in containers using...

40 CFR 98.414 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Industrial Greenhouse Gases § 98.414 Monitoring... or better. If the mass in paragraph (a) of this section is measured by weighing containers that...

40 CFR 98.334 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.334 Monitoring and QA/QC requirements. If..., belt weigh feeders, weighed purchased quantities in shipments or containers, combination of bulk...

40 CFR 98.444 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Geologic Sequestration of Carbon Dioxide § 98.444 Monitoring... volume of contents in all containers if you receive CO2 in containers by following the most appropriate...

40 CFR 98.334 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.334 Monitoring and QA/QC requirements. If..., belt weigh feeders, weighed purchased quantities in shipments or containers, combination of bulk...

40 CFR 98.424 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.424 Monitoring and QA/QC... determine quantity in accordance with this paragraph. (i) Reporters that supply CO2 in containers using...

40 CFR 98.334 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.334 Monitoring and QA/QC requirements. If..., belt weigh feeders, weighed purchased quantities in shipments or containers, combination of bulk...

40 CFR 98.444 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Geologic Sequestration of Carbon Dioxide § 98.444 Monitoring... volume of contents in all containers if you receive CO2 in containers by following the most appropriate...

Physiological response of rats to delivery of helium and xenon: implications for hyperpolarized noble gas imaging

NASA Technical Reports Server (NTRS)

Ramirez, M. P.; Sigaloff, K. C.; Kubatina, L. V.; Donahue, M. A.; Venkatesh, A. K.; Albert, M. S.; ALbert, M. S. (Principal Investigator)

2000-01-01

The physiological effects of various hyperpolarized helium and xenon MRI-compatible breathing protocols were investigated in 17 Sprague-Dawley rats, by continuous monitoring of blood oxygen saturation, heart rate, EKG, temperature and endotracheal pressure. The protocols included alternating breaths of pure noble gas and oxygen, continuous breaths of pure noble gas, breath-holds of pure noble gas for varying durations, and helium breath-holds preceded by two helium rinses. Alternate-breath protocols up to 128 breaths caused a decrease in oxygen saturation level of less than 5% for either helium or xenon, whereas 16 continuous-breaths caused a 31.5% +/- 2.3% decrease in oxygen saturation for helium and a 30.7% +/- 1. 3% decrease for xenon. Breath-hold protocols up to 25 s did not cause the oxygen saturation to fall below 90% for either of the noble gases. Oxygen saturation values below 90% are considered pathological. At 30 s of breath-hold, the blood oxygen saturation dropped precipitously to 82% +/- 0.6% for helium, and to 76.5% +/- 7. 4% for xenon. Breath-holds longer than 10 s preceded by pre-rinses caused oxygen saturation to drop below 90%. These findings demonstrate the need for standardized noble gas inhalation procedures that have been carefully tested, and for continuous physiological monitoring to ensure the safety of the subject. We find short breath-hold and alternate-breath protocols to be safe procedures for use in hyperpolarized noble gas MRI experiments. Copyright 2000 John Wiley & Sons, Ltd.

[Open-path online monitoring of ambient atmospheric CO2 based on laser absorption spectrum].

PubMed

He, Ying; Zhang, Yu-Jun; Kan, Rui-Feng; Xia, Hui; Geng, Hui; Ruan, Jun; Wang, Min; Cui, Xiao-Juan; Liu, Wen-Qing

2009-01-01

With the conjunction of tunable diode laser absorption spectroscopy technology (TDLAS) and the open long optical path technology, the system designing scheme of CO2 on-line monitoring based on near infrared tunable diode laser absorption spectroscopy technology was discussed in detail, and the instrument for large-range measurement was set up. By choosing the infrared absorption line of CO2 at 1.57 microm whose line strength is strong and suitable for measurement, the ambient atmospheric CO2 was measured continuously with a 30 s temporal resolution at an suburb site in the autumn of 2007. The diurnal atmospheric variations of CO2 and continuous monitoring results were presented. The results show that the variation in CO2 concentration has an obvious diurnal periodicity in suburb where the air is free of interference and contamination. The general characteristic of diurnal variation is that the concentration is low in the daytime and high at night, so it matches the photosynthesis trend. The instrument can detect gas concentration online with high resolution, high sensitivity, high precision, short response time and many other advantages, the monitoring requires no gas sampling, the calibration is easy, and the detection limit is about 4.2 x 10(-7). It has been proved that the system and measurement project are feasible, so it is an effective method for gas flux continuous online monitoring of large range in ecosystem based on TDLAS technology.

Highlights and Opportunities from Continuous Access to Gas Hydrates Sites at Ocean Networks Canada's NEPTUNE Observatory

NASA Astrophysics Data System (ADS)

Scherwath, M.; Heesemann, M.; Riedel, M.; Thomsen, L.; Roemer, M.; Chatzievangelou, D.; Purser, A.

2017-12-01

Since 2009 Ocean Networks Canada provides permanent access and continuous data in near real-time from two prominent gas hydrates research sites at the Northern Cascadia Margin, Barkley Canyon and Clayoquot Slope off Vancouver Island, through power and communication cables directly from shore. We show data highlights from the seafloor crawler Wally, the world's first internet operated vehicle, in a field of hydrate mounds and outcropping gas hydrates, and its co-located sonars and state-of-the-ocean sensors and Barkley Canyon. For example, spectacular views from the benthic communities and their changes over time are captured by video. At Clayoquot Slope highly active gas seep fields are monitored with a rotating multibeam sonar and various other environmental sensors. In addition, newly installed geodetic sensors as well as an instrumented borehole in that area are now online and provide additional data on subduction-related deformation and potential links to gas discharge. These show-case examples highlight the benefits of co-located experiments that enable interdisciplinary research and also the ability for high-power and -bandwidth long-term monitoring at remote seafloor locations, that over time will provide baselines for environmental monitoring together with natural variability and potential long-term trends.

10 CFR Appendix D to Subpart B of... - Uniform Test Method for Measuring the Energy Consumption of Clothes Dryers

Code of Federal Regulations, 2010 CFR

2010-01-01

... clothes drying cycle when the added gas or electric heat is terminated and the clothes continue to tumble... termination control” means a dryer control system with a sensor which monitors either the dryer load... highest voltage specified by the manufacturer. 2.3.2Gas supply. 2.3.2.1Natural gas. Maintains the gas...

Establishing Long-term Observations of Gas Hydrate Systems: Results from Ocean Networks Canada's NEPTUNE Observatory

NASA Astrophysics Data System (ADS)

Scherwath, M.; Riedel, M.; Roemer, M.; Heesemann, M.; Chun, J. H.; Moran, K.; Spence, G.; Thomsen, L.

2016-12-01

The key for a scientific understanding of natural environments and the determination of baselines is the long-term monitoring of environmental factors. For seafloor environments including gas hydrate systems, cabled ocean observatories are important platforms for the remote acquisition of a comprehensive suite of datasets. This is particularly critical for those datasets that are difficult to acquire with autonomous, battery-powered systems, such as cameras or high-bandwidth sonar because cable connections provide continuous power and communication from shore to the seafloor. Ocean Networks Canada is operating the NEPTUNE cabled undersea observatory in the Northeast Pacific with two nodes at gas hydrate sites, Barkley Canyon and Clayoquot Slope. With up to seven years of continuous data from these locations we are now beginning to understand the dynamics of the natural systems and are able to classify the variations within the gas hydrate system. For example, the long-term monitoring of gas vent activity has allowed us to classify phases of low, intermittent and high activity that seem to reoccur periodically. Or, by recording the speeds of bacterial mat growth or detecting periods of increased productivity of flora and fauna at hydrates sites we can start to classify benthic activity and relate that to outside environmental parameters. This will eventually allow us to do enhanced environmental monitoring, establish baselines, and potentially detect anthropogenic variations or events for example during gas hydrate production.

Stark effect spectrophone for continuous absorption spectra monitoring. [a technique for gas analysis

NASA Technical Reports Server (NTRS)

Kavaya, M. J. (Inventor)

1981-01-01

A Stark effect spectrophone using a pulsed or continuous wave laser having a beam with one or more absorption lines of a constituent of an unknown gas is described. The laser beam is directed through windows of a closed cell while the unknown gas to be modified flows continuously through the cell between electric field plates disposed in the cell on opposite sides of the beam path through the cell. When the beam is pulsed, energy absorbed by the gas increases at each point along the beam path according to the spectral lines of the constituents of the gas for the particular field strengths at those points. The pressure measurement at each point during each pulse of energy yields a plot of absorption as a function of electric field for simultaneous detection of the gas constituents. Provision for signal averaging and modulation is included.

Biochemical gas sensor (bio-sniffer) for ultrahigh-sensitive gaseous formaldehyde monitoring.

PubMed

Kudo, Hiroyuki; Suzuki, Yuki; Gessei, Tomoko; Takahashi, Daishi; Arakawa, Takahiro; Mitsubayashi, Kohji

2010-10-15

An ultrahigh-sensitive fiber-optic biochemical gas sensor (bio-sniffer) for continuous monitoring of indoor formaldehyde was constructed and tested. The bio-sniffer measures gaseous formaldehyde as fluorescence of nicotinamide adenine dinucleotide (NADH), which is the product of formaldehyde dehydrogenase (FALDH) reaction. The bio-sniffer device was constructed by attaching a flow cell with a FALDH immobilized membrane onto a fiber-optic NADH measurement system. The NADH measurement system utilizes an ultraviolet-light emitting diode (UV-LED) with peak emission of 335 nm as an excitation light source. The excitation light was introduced to an optical fiber probe, and fluorescence emission of neighboring NADH, which was produced by applying formaldehyde vapor to the FALDH membrane, was concentrically measured with a photomultiplier tube. Assessment of the bio-sniffer was carried out using a standard gas generator. Response, calibration range and selectivity to other chemical substances were investigated. Circulating phosphate buffer, which contained NAD+, available for continuous monitoring of formaldehyde vapor. The calibration range of the bio-sniffer was 2.5 ppb to 10 ppm, which covers the guideline value of the World Health Organization (80 ppb). High selectivity to other gaseous substances due to specific activity of FALDH was also confirmed. Considering its high sensitivity, a possible application of the bio-sniffer is continuous indoor formaldehyde monitoring to provide healthy residential atmosphere. Copyright © 2010 Elsevier B.V. All rights reserved.

49 CFR 192.465 - External corrosion control: Monitoring.

Code of Federal Regulations, 2010 CFR

2010-10-01

... Section 192.465 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion...

Development and validation of inexpensive, automated, dynamic flux chambers

EPA Science Inventory

We developed and validated an automated, inexpensive, and continuous multiple-species gas-flux monitoring system that can provide data for a variety of relevant atmospheric pollutants, including O3, CO2, and NOx. Validation consisted of conducting concurrent gas-phase dry deposit...

Current Status of EPA Verification Program for EPA Protocol Gases

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensure that c...

Custom ultrasonic instrumentation for flow measurement and real-time binary gas analysis in the CERN ATLAS experiment

NASA Astrophysics Data System (ADS)

Alhroob, M.; Battistin, M.; Berry, S.; Bitadze, A.; Bonneau, P.; Boyd, G.; Crespo-Lopez, O.; Degeorge, C.; Deterre, C.; Di Girolamo, B.; Doubek, M.; Favre, G.; Hallewell, G.; Katunin, S.; Lombard, D.; Madsen, A.; McMahon, S.; Nagai, K.; O'Rourke, A.; Pearson, B.; Robinson, D.; Rossi, C.; Rozanov, A.; Stanecka, E.; Strauss, M.; Vacek, V.; Vaglio, R.; Young, J.; Zwalinski, L.

2017-01-01

The development of custom ultrasonic instrumentation was motivated by the need for continuous real-time monitoring of possible leaks and mass flow measurement in the evaporative cooling systems of the ATLAS silicon trackers. The instruments use pairs of ultrasonic transducers transmitting sound bursts and measuring transit times in opposite directions. The gas flow rate is calculated from the difference in transit times, while the sound velocity is deduced from their average. The gas composition is then evaluated by comparison with a molar composition vs. sound velocity database, based on the direct dependence between sound velocity and component molar concentration in a gas mixture at a known temperature and pressure. The instrumentation has been developed in several geometries, with five instruments now integrated and in continuous operation within the ATLAS Detector Control System (DCS) and its finite state machine. One instrument monitors C3F8 coolant leaks into the Pixel detector N2 envelope with a molar resolution better than 2ṡ 10-5, and has indicated a level of 0.14 % when all the cooling loops of the recently re-installed Pixel detector are operational. Another instrument monitors air ingress into the C3F8 condenser of the new C3F8 thermosiphon coolant recirculator, with sub-percent precision. The recent effect of the introduction of a small quantity of N2 volume into the 9.5 m3 total volume of the thermosiphon system was clearly seen with this instrument. Custom microcontroller-based readout has been developed for the instruments, allowing readout into the ATLAS DCS via Modbus TCP/IP on Ethernet. The instrumentation has many potential applications where continuous binary gas composition is required, including in hydrocarbon and anaesthetic gas mixtures.

40 CFR 60.403 - Monitoring of emissions and operations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... measurement of the pressure loss of the gas stream through the scrubber. The monitoring device must be certified by the manufacturer to be accurate within ±250 pascals (±1 inch water) gauge pressure. (2) A monitoring device for the continuous measurement of the scrubbing liquid supply pressure to the control...

40 CFR 98.474 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Injection of Carbon Dioxide § 98.474 Monitoring and QA/QC.... (2) You must determine the quarterly mass or volume of contents in all containers if you receive CO2...

40 CFR 98.474 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Injection of Carbon Dioxide § 98.474 Monitoring and QA/QC.... (2) You must determine the quarterly mass or volume of contents in all containers if you receive CO2...

40 CFR 98.474 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Injection of Carbon Dioxide § 98.474 Monitoring and QA/QC.... (2) You must determine the quarterly mass or volume of contents in all containers if you receive CO2...

40 CFR 98.424 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Monitoring and QA/QC requirements. 98... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Carbon Dioxide § 98.424 Monitoring and QA/QC... containers shall measure the mass in each CO2 container using weigh bills, scales, or load cells and sum the...

Continuous TDEM for monitoring shale hydraulic fracturing

NASA Astrophysics Data System (ADS)

Yan, Liang-Jun; Chen, Xiao-Xiong; Tang, Hao; Xie, Xing-Bing; Zhou, Lei; Hu, Wen-Bao; Wang, Zhong-Xin

2018-03-01

Monitoring and delineating the spatial distribution of shale fracturing is fundamentally important to shale gas production. Standard monitoring methods, such as time-lapse seismic, cross-well seismic and micro-seismic methods, are expensive, timeconsuming, and do not show the changes in the formation with time. The resistivities of hydraulic fracturing fluid and reservoir rocks were measured. The results suggest that the injection fluid and consequently the injected reservoir are characterized by very low resistivity and high chargeability. This allows using of the controlled-source electromagnetic method (CSEM) to monitor shale gas hydraulic fracturing. Based on the geoelectrical model which was proposed according to the well-log and seismic data in the test area the change rule of the reacted electrical field was studied to account for the change of shale resistivity, and then the normalized residual resistivity method for time lapse processing was given. The time-domain electromagnetic method (TDEM) was used to continuously monitor the shale gas fracturing at the Fulin shale gas field in southern China. A high-power transmitter and multi-channel transient electromagnetic receiver array were adopted. 9 h time series of Ex component of 224 sites which were laid out on the surface and over three fracturing stages of a horizontal well at 2800 m depth was recorded. After data processing and calculation of the normalized resistivity residuals, the changes in the Ex signal were determined and a dynamic 3D image of the change in resistivity was constructed. This allows modeling the spatial distribution of the fracturing fluid. The model results suggest that TDEM is promising for monitoring hydraulic fracturing of shale.

A feasibility study on the predictive emission monitoring system applied to the Hsinta power plant of Taiwan Power Company.

PubMed

Chien, T W; Chu, H; Hsu, W C; Tseng, T K; Hsu, C H; Chen, K Y

2003-08-01

The continuous emission monitoring system (CEMS) can monitor flue gas emissions continuously and instantaneously. However, it has the disadvantages of enormous cost, easily producing errors in sampling periods of bad weather, lagging response in variable ambient environments, and missing data in daily zero and span tests and maintenance. The concept of a predictive emission monitoring system (PEMS) is to use the operating parameters of combustion equipment through thermodynamic or statistical methods to construct a mathematic model that can predict emissions by a computer program. The goal of this study is to set up a PEMS in a gas-fired combined cycle power generation unit at the Hsinta station of Taiwan Power Co. The emissions to be monitored include nitrogen oxides (NOx) and oxygen (O2) in flue gas. The major variables of the predictive model were determined based on the combustion theory. The data of these variables then were analyzed to establish a regression model. From the regression results, the influences of these variables are discussed and the predicted values are compared with the CEMS data for accuracy. In addition, according to the cost information, the capital and operation and maintenance costs for a PEMS can be much lower than those for a CEMS.

Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

DOEpatents

Hagans, Karla; Berzins, Leon; Galkowski, Joseph; Seng, Rita

1996-01-01

The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer's law.

Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

DOEpatents

Hagans, K.; Berzins, L.; Galkowski, J.; Seng, R.

1996-08-27

The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer`s law. 6 figs.

Commercialization Issues For Catheter-Based Electrochemical Sensors

NASA Astrophysics Data System (ADS)

Nikolchev, Julian; Gaisford, Scott

1989-08-01

The need for continuous monitoring of key clinical parameters in hospitals is well recognized. Figure 1 shows typical time constants for blood gases, ions and enzymes in response to acute ventilatory changes and interventions. Although it can be seen that relatively low rates of data collection are necessary for many medical measurements, it is also clear that intermittent measurement of P02, PCO2 and pH are not sufficient to provide safe and effective management of the patient. Very frequent or continuous monitoring is often essential. This figure also shows why the emphasis of a large number of research efforts in this country and in Europe and Japan have as their goal the development of continuous blood gas sensors, i.e., sensors that continuously monitor blood pH, partial pressure of oxygen and partial pressure of carbon dioxide. These are three (3) of the most frequent parameters measured in hospitals and the ones having the shortest time constant. Considering that in the United States alone close to 25 million blood gas samples per year are taken from patients, the potential market for continuous monitoring sensors is enormous. The emergence of microelectronics and microfabrication technologies over the past 30 years are now pointing to a possible resolution of the well recognized need for real time monitoring of critically ill patients through catheter-based sensors. Although physicians will always prefer non-invasive monitoring techniques, there are a number of parameters that presently can only be monitored by invasive method. The emerging ability to miniaturize chemical sensors using silicon microfabrication or fiber-optic techniques offer an excellent opportunity to solve this need. In fact, the development of in vivo biomedical sensors with satisfactory performance characteristics has long been considered the ultimate application of these emerging technologies.

40 CFR 63.1573 - What are my monitoring alternatives?

Code of Federal Regulations, 2014 CFR

2014-07-01

... operate a continuous gas analyzer to measure and record the concentration of carbon dioxide, carbon... control room instrumentations, dscm/min (dscf/min); %CO2 = Carbon dioxide concentration in regenerator... catalytic regenerator atmospheric exhaust gas flow rate for your catalytic reforming unit during the coke...

40 CFR 63.1573 - What are my monitoring alternatives?

Code of Federal Regulations, 2012 CFR

2012-07-01

... operate a continuous gas analyzer to measure and record the concentration of carbon dioxide, carbon... control room instrumentations, dscm/min (dscf/min); %CO2 = Carbon dioxide concentration in regenerator... catalytic regenerator atmospheric exhaust gas flow rate for your catalytic reforming unit during the coke...

Monitoring System for the Gold Target by Radiation Detectors in Hadron Experimental Facility at J-PARC

NASA Astrophysics Data System (ADS)

Muto, Ryotaro; Agari, Keizo; Aoki, Kazuya; Bessho, Kotaro; Hagiwara, Masayuki; Hirose, Erina; Ieiri, Masaharu; Iwasaki, Ruri; Katoh, Yohji; Kitagawa, Jun-ichi; Minakawa, Michifumi; Morino, Yuhei; Saito, Kiwamu; Sato, Yoshinori; Sawada, Shin'ya; Shirakabe, Yoshihisa; Suzuki, Yoshihiro; Takahashi, Hitoshi; Tanaka, Kazuhiro; Toyoda, Akihisa; Watanabe, Hiroaki; Yamanoi, Yutaka

2017-09-01

At the Hadron Experimental Facility in J-PARC, we inject a 30-GeV proton beam into a gold target to produce secondary particle beams required for various particle and nuclear physics experiments. The gold target is placed in a hermetic chamber, and helium gas is circulated in the chamber to monitor the soundness of the target. The radioactivity in helium gas is continuously monitored by gamma-ray detectors such as a germanium detector and a NaI(Tl) detector. Beam operations with those target-monitoring systems were successfully performed from April to June and October to December 2015, and from May to June 2016. In this paper, the details of the helium gas circulation system and gamma-ray detectors and the analysis results of the obtained gamma-ray spectra are reported.

40 CFR 60.73 - Emission monitoring.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the applicable standard (kg/metric ton, lb/ton). The conversion factor shall be established by...., kg/metric ton per ppm (lb/ton per ppm). The conversion factor shall be reestablished during any... continuous monitoring system for measuring nitrogen oxides (NOX). The pollutant gas mixtures under...

40 CFR 60.73 - Emission monitoring.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the applicable standard (kg/metric ton, lb/ton). The conversion factor shall be established by...., kg/metric ton per ppm (lb/ton per ppm). The conversion factor shall be reestablished during any... continuous monitoring system for measuring nitrogen oxides (NOX). The pollutant gas mixtures under...

40 CFR 60.73 - Emission monitoring.

Code of Federal Regulations, 2012 CFR

2012-07-01

... the applicable standard (kg/metric ton, lb/ton). The conversion factor shall be established by...., kg/metric ton per ppm (lb/ton per ppm). The conversion factor shall be reestablished during any... continuous monitoring system for measuring nitrogen oxides (NOX). The pollutant gas mixtures under...

40 CFR 60.73 - Emission monitoring.

Code of Federal Regulations, 2014 CFR

2014-07-01

... the applicable standard (kg/metric ton, lb/ton). The conversion factor shall be established by...., kg/metric ton per ppm (lb/ton per ppm). The conversion factor shall be reestablished during any... continuous monitoring system for measuring nitrogen oxides (NOX). The pollutant gas mixtures under...

Near-real-time combustion monitoring for PCDD/PCDF indicators by CG-REMPI-TOFMS

EPA Science Inventory

The boiler exit flue gas of a municipal waste combustor was sampled to evaluate an on-line monitoring system for chlorobenzene congeners as indicators of polychlorinated dibenzodioxin and dibenzofuran (PCDD/PCDF) concentrations. Continuous measurements of chlorobenzene congeners ...

A new approach for biological online testing of stack gas condensate from municipal waste incinerators.

PubMed

Elsner, Dorothea; Fomin, Anette

2002-01-01

A biological testing system for the monitoring of stack gas condensates of municipal waste incinerators has been developed using Euglena gracilis as a test organism. The motility, velocity and cellular form of the organisms were the endpoints, calculated by an image analysis system. All endpoints showed statistically significant changes in a short time when organisms were exposed to samples collected during combustion situations with increased pollutant concentrations. The velocity of the organisms proved to be the most appropriate endpoint. A semi-continuous system with E. gracilis for monitoring stack gas condensate is proposed, which could result in an online system for testing stack gas condensates in the future.

Real-Time N2O Gas Detection System for Agricultural Production Using a 4.6-μm-Band Laser Source Based on a Periodically Poled LiNbO3 Ridge Waveguide

PubMed Central

Tokura, Akio; Asobe, Masaki; Enbutsu, Koji; Yoshihara, Toshihiro; Hashida, Shin-nosuke; Takenouchi, Hirokazu

2013-01-01

This article describes a gas monitoring system for detecting nitrous oxide (N2O) gas using a compact mid-infrared laser source based on difference-frequency generation in a quasi-phase-matched LiNbO3 waveguide. We obtained a stable output power of 0.62 mW from a 4.6-μm-band continuous-wave laser source operating at room temperature. This laser source enabled us to detect atmospheric N2O gas at a concentration as low as 35 parts per billion. Using this laser source, we constructed a new real-time in-situ monitoring system for detecting N2O gas emitted from potted plants. A few weeks of monitoring with the developed detection system revealed a strong relationship between nitrogen fertilization and N2O emission. This system is promising for the in-situ long-term monitoring of N2O in agricultural production, and it is also applicable to the detection of other greenhouse gases. PMID:23921829

Real-time N2O gas detection system for agricultural production using a 4.6-µm-band laser source based on a periodically poled LiNbO3 ridge waveguide.

PubMed

Tokura, Akio; Asobe, Masaki; Enbutsu, Koji; Yoshihara, Toshihiro; Hashida, Shin-nosuke; Takenouchi, Hirokazu

2013-08-05

This article describes a gas monitoring system for detecting nitrous oxide (N2O) gas using a compact mid-infrared laser source based on difference-frequency generation in a quasi-phase-matched LiNbO3 waveguide. We obtained a stable output power of 0.62 mW from a 4.6-μm-band continuous-wave laser source operating at room temperature. This laser source enabled us to detect atmospheric N2O gas at a concentration as low as 35 parts per billion. Using this laser source, we constructed a new real-time in-situ monitoring system for detecting N2O gas emitted from potted plants. A few weeks of monitoring with the developed detection system revealed a strong relationship between nitrogen fertilization and N2O emission. This system is promising for the in-situ long-term monitoring of N2O in agricultural production, and it is also applicable to the detection of other greenhouse gases.

Seismo-Geochemical Variations in SW Taiwan: Multi-Parameter Automatic Gas Monitoring Results

NASA Astrophysics Data System (ADS)

Yang, T. F.; Fu, C.-C.; Walia, V.; Chen, C.-H.; Chyi, L. L.; Liu, T.-K.; Song, S.-R.; Lee, M.; Lin, C.-W.; Lin, C.-C.

2006-04-01

Gas variations of many mud volcanoes and hot springs distributed along the tectonic sutures in southwestern Taiwan are considered to be sensitive to the earthquake activity. Therefore, a multi-parameter automatic gas station was built on the bank of one of the largest mud-pools at an active fault zone of southwestern Taiwan, for continuous monitoring of CO2, CH4, N2 and H2O, the major constituents of its bubbling gases. During the year round monitoring from October 2001 to October 2002, the gas composition, especially, CH4 and CO2, of the mud pool showed significant variations. Taking the CO2/CH4 ratio as the main indicator, anomalous variations can be recognized from a few days to a few weeks before earthquakes and correlated well with those with a local magnitude >4.0 and local intensities >2. It is concluded that the gas composition in the area is sensitive to the local crustal stress/strain and is worthy to conduct real-time monitoring for the seismo-geochemical precursors.

40 CFR 63.1573 - What are my monitoring alternatives?

Code of Federal Regulations, 2013 CFR

2013-07-01

... continuous gas analyzer to measure and record the concentration of carbon dioxide, carbon monoxide, and... instrumentations, dscm/min (dscf/min); %CO2 = Carbon dioxide concentration in regenerator exhaust, percent by... regenerator atmospheric exhaust gas flow rate for your catalytic reforming unit during the coke burn and...

FUEL RICH SULFUR CAPTURE IN A COMBUSTION ENVIRONMENT

EPA Science Inventory

A refractory-lined, natural gas furnace was used to study fuel rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel rich sulfur species H2S and COS were monitored in a near-continuous fashion using a gas chromatograph equipped with a fl...

Residual gas analysis for long-pulse, advanced tokamak operation.

PubMed

Klepper, C C; Hillis, D L; Bucalossi, J; Douai, D; Oddon, P; Vartanian, S; Colas, L; Manenc, L; Pégourié, B

2010-10-01

A shielded residual gas analyzer (RGA) system on Tore Supra can function during plasma operation and is set up to monitor the composition of the neutral gas in one of the pumping ducts of the toroidal pumped limited. This "diagnostic RGA" has been used in long-pulse (up to 6 min) discharges for continuous monitoring of up to 15 masses simultaneously. Comparison of the RGA-measured evolution of the H(2)/D(2) isotopic ratio in the exhaust gas to that measured by an energetic neutral particle analyzer in the plasma core provides a way to monitor the evolution of particle balance. RGA monitoring of corrective H(2) injection to maintain proper minority heating is providing a database for improved ion cyclotron resonance heating, potentially with RGA-base feedback control. In very long pulses (>4 min) absence of significant changes in the RGA-monitored, hydrocarbon particle pressures is an indication of proper operation of the actively cooled, carbon-based plasma facing components. Also H(2) could increase due to thermodesorption of overheated plasma facing components.

Gas monitoring onboard ISS using FTIR spectroscopy

NASA Astrophysics Data System (ADS)

Gisi, Michael; Stettner, Armin; Seurig, Roland; Honne, Atle; Witt, Johannes; Rebeyre, Pierre

2017-06-01

In the confined, enclosed environment of a spacecraft, the air quality must be monitored continuously in order to safeguard the crew's health. For this reason, OHB builds the ANITA2 (Analysing Interferometer for Ambient Air) technology demonstrator for trace gas monitoring onboard the International Space Station (ISS). The measurement principle of ANITA2 is based on the Fourier Transform Infrared (FTIR) technology with dedicated gas analysis software from the Norwegian partner SINTEF. This combination proved to provide high sensitivity, accuracy and precision for parallel measurements of 33 trace gases simultaneously onboard ISS by the precursor instrument ANITA1. The paper gives a technical overview about the opto-mechanical components of ANITA2, such as the interferometer, the reference Laser, the infrared source and the gas cell design and a quick overview about the gas analysis. ANITA2 is very well suited for measuring gas concentrations specifically but not limited to usage onboard spacecraft, as no consumables are required and measurements are performed autonomously. ANITA2 is a programme under the contract of the European Space Agency, and the air quality monitoring system is a stepping stone into the future, as a precursor system for manned exploration missions.

40 CFR 98.164 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.164 Monitoring and QA/QC requirements. The GHG emissions data for hydrogen production process units must be quality-assured as specified in... Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Petroleum Products and Lubricants (incorporated...

Remotely Sensed Density Measurements of Volcanic Sulfur Dioxide Plumes Using a Spectral Long Wave Infrared Imager

DTIC Science & Technology

2002-09-01

USGS). (Tilling, R., Heliker, C., and Wright, T., “ Eruptions of Hawaiian Volcanoes ”) The mission of HVO is to monitor Hawaii’s Mauna Loa and Kilauea ...Hendley, J., “Living on Active Volcanoes ”) Hawaii’s Kilauea Volcano is unique in its long-term (1983 – present), nearly continuous eruptive ...monitoring the gas emission process of Kilauea Volcano . During periods of sustained eruption , Kilauea emits about 2,000 tons of sulfur dioxide gas (SO2

PROTECTING DRINKING WATER BY REDUCING UNCERTAINTIES ASSOCIATED WITH GEOLOGIC CARBON SEQUESTRATION IN DEEP SALINE AQUIFERS

EPA Science Inventory

30 CFR 250.1629 - Additional production and fuel gas system requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... structure. (4) Fire- and gas-detection system. (i) Fire (flame, heat, or smoke) sensors shall be installed... explosive limit. One approved method of providing adequate ventilation is a change of air volume each 5... detection systems shall be capable of continuous monitoring. Fire-detection systems and portions of...

30 CFR 250.1629 - Additional production and fuel gas system requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... structure. (4) Fire- and gas-detection system. (i) Fire (flame, heat, or smoke) sensors shall be installed... explosive limit. One approved method of providing adequate ventilation is a change of air volume each 5... detection systems shall be capable of continuous monitoring. Fire-detection systems and portions of...

40 CFR 503.40 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SEWAGE SLUDGE STANDARDS FOR THE USE OR... sewage sludge incinerator stack is monitored continuously for carbon monoxide. (2) The monthly average concentration of carbon monoxide in the exit gas from a sewage sludge incinerator stack, corrected for zero...

ANITA Air Monitoring on the International Space Station: Results Compared to Other Measurements

NASA Technical Reports Server (NTRS)

Honne, A.; Schumann-Olsen, H.; Kaspersen, K.; Limero, T.; Macatangay, A.; Mosebach, H.; Kampf, D.; Mudgett, P. D.; James, J. T.; Tan, G.;

40 CFR 60.1325 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false How do I monitor the temperature of... June 6, 2001 Other Monitoring Requirements § 60.1325 How do I monitor the temperature of flue gases at... a device to continuously measure the temperature of the flue gas stream at the inlet of each...

40 CFR 60.1325 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false How do I monitor the temperature of... June 6, 2001 Other Monitoring Requirements § 60.1325 How do I monitor the temperature of flue gases at... a device to continuously measure the temperature of the flue gas stream at the inlet of each...

40 CFR 60.1325 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false How do I monitor the temperature of... June 6, 2001 Other Monitoring Requirements § 60.1325 How do I monitor the temperature of flue gases at... a device to continuously measure the temperature of the flue gas stream at the inlet of each...

Methods and techniques for measuring gas emissions from agricultural and animal feeding operations.

PubMed

Hu, Enzhu; Babcock, Esther L; Bialkowski, Stephen E; Jones, Scott B; Tuller, Markus

2014-01-01

Emissions of gases from agricultural and animal feeding operations contribute to climate change, produce odors, degrade sensitive ecosystems, and pose a threat to public health. The complexity of processes and environmental variables affecting these emissions complicate accurate and reliable quantification of gas fluxes and production rates. Although a plethora of measurement technologies exist, each method has its limitations that exacerbate accurate quantification of gas fluxes. Despite a growing interest in gas emission measurements, only a few available technologies include real-time, continuous monitoring capabilities. Commonly applied state-of-the-art measurement frameworks and technologies were critically examined and discussed, and recommendations for future research to address real-time monitoring requirements for forthcoming regulation and management needs are provided.

Method and apparatus for monitoring mercury emissions

DOEpatents

Durham, Michael D.; Schlager, Richard J.; Sappey, Andrew D.; Sagan, Francis J.; Marmaro, Roger W.; Wilson, Kevin G.

1997-01-01

A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

Method and apparatus for monitoring mercury emissions

DOEpatents

Durham, M.D.; Schlager, R.J.; Sappey, A.D.; Sagan, F.J.; Marmaro, R.W.; Wilson, K.G.

1997-10-21

A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber. 15 figs.

Continued Development of Compact Multi-gas Monitor for Life Support Systems Control in Space

NASA Technical Reports Server (NTRS)

Delgado-Alonso, Jesús; Phillips, Straun; Chullen, Cinda; Quinn, Gregory

2016-01-01

Miniature optic gas sensors (MOGS) based on luminescent materials have shown great potential as alternatives to Near-Infrared-based gas sensor systems for the advanced space suit portable life support system (PLSS). The unique capability of MOGS for carbon dioxide and oxygen monitoring under wet conditions has been reported, as has the fast recovery of MOGS humidity sensors after long periods of being wet. Lower volume and power requirements are also potential advantages of MOGS over both traditional and advanced Non-Dispersive Infrared (NDIR) gas sensors, which have shown so far longer life than luminescent sensors. This paper presents the most recent results in the development and analytical validation of a compact multi-gas sensor unit based on luminescent sensors for the PLSS. Results of extensive testing are presented, including studies conducted at Intelligent Optical Systems laboratories, a United Technology Corporation Aerospace Systems (UTAS) laboratory, and a Johnson Space Center laboratory. The potential of this sensor technology for gas monitoring in PLSSs and other life support systems and the advantages and limitations found through detailed sensor validation are discussed.

Continued Development of Compact Multi-Gas Monitor for Life Support Systems Control in Space

NASA Technical Reports Server (NTRS)

Delgado, Jesus; Phillips, Straun; Chullen, Cinda

2015-01-01

Miniature optic gas sensors (MOGS) based on luminescent materials have shown great potential as alternatives to NIR-based gas sensor systems for the Portable Life Support System (PLSS). The unique capability of MOGS for carbon dioxide and oxygen monitoring under wet conditions has been reported, as has the fast recovery of MOGS humidity sensors after long periods of being wet. Lower volume and power requirements are also potential advantages of MOGS over both traditional and advanced Non-Dispersive Infrared (NDIR) gas sensors, which have shown so far longer life than luminescent sensors. In this paper we present the most recent results in the development and analytical validation of a compact multi-gas sensor unit based on luminescent sensors for the PLSS. Results of extensive testing are presented, including studies conducted at Intelligent Optical Systems laboratories, a United Technology Corporation Aerospace Systems (UTAS) laboratory, and a Johnson Space Center laboratory. The potential of this sensor technology for gas monitoring in PLSSs and other life support systems and the advantages and limitations found through detailed sensor validation are discussed.

Continued Development of Compact Multi-Gas Monitor for Life Support Systems Control in Space

NASA Technical Reports Server (NTRS)

Delgado-Alonso, Jesus; Phillips, Straun; Berry, David; DiCarmine, Paul; Chullen, Cinda; Quinn, Gregory

2016-01-01

Miniature optical gas sensors based on luminescent materials have shown great potential as alternatives to NIR-based gas sensor systems for the Portable Life Support System (PLSS). The unique capability of luminescent sensors for carbon dioxide and oxygen monitoring under wet conditions has been reported, as has the fast recovery of humidity sensors after long periods of being wet. Lower volume and power requirements are also potential advantages over both traditional and advanced non-dispersive infrared (NDIR) gas sensors, which have so far shown longer life than luminescent sensors. In this paper we present the most recent results in the development and analytical validation of a compact multi-gas sensor unit based on luminescent sensors for the PLSS. Results of extensive testing are presented, including studies conducted in Intelligent Optical Systems laboratories, a United Technologies Corporation Aerospace Systems (UTC) laboratory, and a Johnson Space Center laboratory. The potential of this sensor technology for gas monitoring in PLSSs and other life support systems, and the advantages and limitations found through detailed sensor validation are discussed.

40 CFR 146.91 - Reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 146.91 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED... integrity; or. (5) Pursuant to compliance with the requirement at § 146.90(h) for surface air/soil gas... deliver the records to the Director at the conclusion of the retention period. (3) Monitoring data...

40 CFR 146.91 - Reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 146.91 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED... integrity; or. (5) Pursuant to compliance with the requirement at § 146.90(h) for surface air/soil gas... deliver the records to the Director at the conclusion of the retention period. (3) Monitoring data...

40 CFR 146.91 - Reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 146.91 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED... integrity; or. (5) Pursuant to compliance with the requirement at § 146.90(h) for surface air/soil gas... deliver the records to the Director at the conclusion of the retention period. (3) Monitoring data...

40 CFR 98.84 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.84 Monitoring and QA/QC requirements..., shale, iron oxide, and alumina). Facilities that opt to use the default total organic carbon factor... quantity of each category of raw materials consumed by the facility (e.g., limestone, sand, shale, iron...

40 CFR 98.84 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.84 Monitoring and QA/QC requirements..., shale, iron oxide, and alumina). Facilities that opt to use the default total organic carbon factor... quantity of each category of raw materials consumed by the facility (e.g., limestone, sand, shale, iron...

40 CFR 98.84 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Cement Production § 98.84 Monitoring and QA/QC requirements..., shale, iron oxide, and alumina). Facilities that opt to use the default total organic carbon factor... quantity of each category of raw materials consumed by the facility (e.g., limestone, sand, shale, iron...

40 CFR 98.164 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.164 Monitoring and QA/QC requirements. The GHG emissions data for hydrogen production process units must be quality-assured as specified in..., Hydrogen, and Nitrogen in Petroleum Products and Lubricants (incorporated by reference, see § 98.7). (xi...

NEAR-REAL-TIME MEASUREMENT OF TRACE VOLATILE ORGANIC COMPOUNDS FROM COMBUSTION PROCESSES USING AN ON-LINE GAS CHROMATOGRAPH

EPA Science Inventory

The U.S. EPA's current regulatory approach for combustion and incineration sources emphasizes the use of real-time continuous emission monitors (CEMs) for particulate, Metals, and volatile, semivolatile, and of nonvolatile organic compounds to monitor source emissions. Currently...

Enhanced Raman Monitor Project

NASA Technical Reports Server (NTRS)

Westenskow, Dwayne

1996-01-01

Monitoring of gaseous contaminants stems from the need to ensure a healthy and safe environment. NASA/Ames needs sensors that are able to monitor common atmospheric gas concentrations as well as trace amounts of contaminant gases. To provide an accurate assessment of air quality, a monitoring system would need to be continuous and on-line with full spectrum capabilities, allowing simultaneous detection of all gas components in a sample, including both combustible and non-combustible gases. The system demands a high degree of sensitivity to detect low gas concentrations in the low-ppm and sub-ppm regions. For clean and healthy air ('good' category), criteria established by the EPA requires that contaminant concentrations not exceed 4 ppm of carbon monoxide (CO) in an 8 hour period, 60 ppb of ozone(O3) in a one hour period and 30 ppb of sulfur dioxide (SO2) in a 24 hour period. One step below this is the National Ambient Air Quality Standard ('moderate' category) which requires that contaminant concentrations not exceed 9 ppm of carbon monoxide (CO), 120 ppb of ozone (O3) and 140 ppb of sulfur dioxide (SO2) for their respective time periods. Ideally a monitor should be able to detect the concentrations specified in the 'good' category. To benchmark current abilities of Raman technology in gas phase analysis, laboratory experiments were performed to evaluate the RASCAL II anesthetic gas monitor.

Tube bundle system: for monitoring of coal mine atmosphere.

PubMed

Zipf, R Karl; Marchewka, W; Mohamed, K; Addis, J; Karnack, F

2013-05-01

A tube bundle system (TBS) is a mechanical system for continuously drawing gas samples through tubes from multiple monitoring points located in an underground coal mine. The gas samples are drawn via vacuum pump to the surface and are typically analyzed for oxygen, methane, carbon dioxide and carbon monoxide. Results of the gas analyses are displayed and recorded for further analysis. Trends in the composition of the mine atmosphere, such as increasing methane or carbon monoxide concentration, can be detected early, permitting rapid intervention that prevents problems, such as a potentially explosive atmosphere behind seals, fire or spontaneous combustion. TBS is a well-developed technology and has been used in coal mines around the world for more than 50 years. Most longwall coal mines in Australia deploy a TBS, usually with 30 to 40 monitoring points as part of their atmospheric monitoring. The primary uses of a TBS are detecting spontaneous combustion and maintaining sealed areas inert. The TBS might also provide mine atmosphere gas composition data after a catastrophe occurs in an underground mine, if the sampling tubes are not damaged. TBSs are not an alternative to statutory gas and ventilation airflow monitoring by electronic sensors or people; rather, they are an option to consider in an overall mine atmosphere monitoring strategy. This paper describes the hardware, software and operation of a TBS and presents one example of typical data from a longwall coal mine.

ENVIRONMENTAL ASSESSMENT OF A FIRETUBE BOILER FIRING COAL/OIL/WATER MIXTURES. VOLUME 1. TECHNICAL RESULTS

EPA Science Inventory

This volume describes emission results from sampling of flue gas from a firetube boiler burning a coal/oil/water (COW) mixture and COW with soda ash added (COW+SA) to control SO2 emissions. Measurements included: continuous monitoring of flue gas emissions; source assessment samp...

A modified commercial gas chromatograph for the continuous monitoring of the thermal degradation of sunflower oil and off-line solid phase extraction gas-chromatography-mass spectrometry characterization of released volatiles.

PubMed

Ontañon, I; Sanz, J; Escudero, A; de Marcos, S; Ferreira, V; Galbán, J

2015-04-03

A homemade flow cell attached to a commercial Gas Chromatograph equipped with a Flame Ionization Detector (FID) has been designed for the continuous monitoring of volatile compounds released during heating edible oils. Analytical parameters such as mass of sample, temperature and flow rates have been optimized and the obtained results have been compared with the corresponding thermographs from standard TG systems. Results show that under optimum conditions, the profiles of volatiles released upon heating are comparable to the profiles of TG curves, suggesting that the FID based system could be an alternative to TGA. Additionally, volatiles have been retained in a Lichrolut EN(®) resin, eluted and analyzed by Gas Chromatography-Mass Spectrometry. In this case, forty five compounds have been identified (acids, alcohols, alkanes, aldehydes, ketones and furans) and compared with the FID signals, working both in air or nitrogen atmosphere. It has been concluded that the oxidative thermal degradation is prevented in the presence of a nitrogen atmosphere. Copyright © 2015 Elsevier B.V. All rights reserved.

Monitoring and Control of an Adsorption System Using Electrical Properties of the Adsorbent for Organic Compound Abatement.

PubMed

Hu, Ming-Ming; Emamipour, Hamidreza; Johnsen, David L; Rood, Mark J; Song, Linhua; Zhang, Zailong

2017-07-05

Adsorption systems typically need gas and temperature sensors to monitor their adsorption/regeneration cycles to separate gases from gas streams. Activated carbon fiber cloth (ACFC)-electrothermal swing adsorption (ESA) is an adsorption system that has the potential to be controlled with the electrical properties of the adsorbent and is studied here to monitor and control the adsorption/regeneration cycles without the use of gas and temperature sensors and to predict breakthrough before it occurs. The ACFC's electrical resistance was characterized on the basis of the amount of adsorbed organic gas/vapor and the adsorbent temperature. These relationships were then used to develop control logic to monitor and control ESA cycles on the basis of measured resistance and applied power values. Continuous sets of adsorption and regeneration cycles were performed sequentially entirely on the basis of remote electrical measurements and achieved ≥95% capture efficiency at inlet concentrations of 2000 and 4000 ppm v for isobutane, acetone, and toluene in dry and elevated relative humidity gas streams, demonstrating a novel cyclic ESA system that does not require gas or temperature sensors. This contribution is important because it reduces the cost and simplifies the system, predicts breakthrough before its occurrence, and reduces emissions to the atmosphere.

Continuous Monitoring of CH4 Emissions from Marcellus Shale Gas Extraction in South West Pennsylvania Using Top Down Methodology

NASA Astrophysics Data System (ADS)

Sarmiento, D. P.; Belmecheri, S.; Lauvaux, T.; Sowers, T. A.; Bryant, S.; Miles, N. L.; Richardson, S.; Aikins, J.; Sweeney, C.; Petron, G.; Davis, K. J.

2012-12-01

Natural gas extraction from shale formations via hydraulic-fracturing (fracking) is expanding rapidly in several regions of North America. In Pennsylvania, the number of wells drilled to extract natural gas from the Marcellus shale has grown from 195 in 2008 to 1,386 in 2010. The gas extraction process using the fracking technology results in the escape of methane (CH4), a potent greenhouse gas and the principal component of natural gas, into the atmosphere. Emissions of methane from fracking operations remain poorly quantified, leading to a large range of scenarios for the contribution of fracking to climate change. A mobile measurement campaign provided insights on methane leakage rates and an improved understanding of the spatio-temporal variability in active drilling areas in the South West of Pennsylvania. Two towers were then instrumented to monitor fugitive emissions of methane from well pads, pipelines, and other infrastructures in the area. The towers, one within a drilling region and one upwind of active drilling, measured atmospheric CH4 mixing ratios continuously. Isotopic measurements from air flasks were also collected. Data from the initial mobile campaign were used to estimate emission rates from single sites such as wells and compressor stations. Tower data will be used to construct a simple atmospheric inversion for regional methane emissions. Our results show the daily variability in emissions and allow us to estimate leakage rates over a one month period in South West Pennsylvania. We discuss potential deployment strategies in drilling zones to monitor emissions of methane over longer periods of time.

49 CFR 192.16 - Customer notification.

Code of Federal Regulations, 2011 CFR

2011-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS... serve yard lanterns, pool heaters, or other types of secondary equipment. Also, “maintain” means monitor...

Continuous monitoring of Mount St. Helens Volcano

USGS Publications Warehouse

Spall, H.

1980-01-01

Day by day monitoring of the Mount St. Helens Volcano. These are four scenarios, very different scenarios, that can occur in a average week at Mount St. Helens. Ranging from eruptions of gas and to steam to eruptions of ash and pyroclastic flows to even calm days. This example of monitoring illustrates the differences from day to day volcanic activities at Mount St. Helens. 

Fluorometric biosniffer (biochemical gas sensor) for breath acetone as a volatile indicator of lipid metabolism

NASA Astrophysics Data System (ADS)

Mitsubayashi, Kohji; Chien, Po-Jen; Ye, Ming; Suzuki, Takuma; Toma, Koji; Arakawa, Takahiro

2016-11-01

A fluorometric acetone biosniffer (biochemical gas sensor) for assessment of lipid metabolism utilizing reverse reaction of secondary alcohol dehydrogenase was constructed and evaluated. The biosniffer showed highly sensitivity and selectivity for continuous monitoring of gaseous acetone. The measurement of breath acetone concentration during fasting and aerobic exercise were also investigated. The acetone biosniffer provides a novel analytical tool for noninvasive evaluation of human lipid metabolism and it is also expected to use for the clinical and physiological applications such as monitoring the progression of diabetes.

Breast tumor hemodynamic response during a breath-hold as a biomarker to predict chemotherapeutic efficacy: preclinical study

NASA Astrophysics Data System (ADS)

Lee, Songhyun; Kim, Jae Gwan

2018-04-01

Continuous wave diffuse optical tomographic/spectroscopic system does not provide absolute concentrations of chromophores in tissue and monitor only the changes of chromophore concentration. Therefore, it requires a perturbation of physiological signals, such as blood flow and oxygenation. In that sense, a few groups reported that monitoring a relative hemodynamic change during a breast tissue compression or a breath-hold to a patient can provide good contrast between tumor and nontumor. However, no longitudinal study reports the utilization of a breath-hold to predict tumor response during chemotherapy. A continuous wave near-infrared spectroscopy was employed to monitor hemodynamics in rat breast tumor during a hyperoxic to normoxic inhalational gas intervention to mimic a breath-hold during tumor growth and chemotherapy. The reduced oxyhemoglobin concentration during inhalational gas intervention correlated well with tumor growth, and it responded one day earlier than the change of tumor volume after chemotherapy. In conclusion, monitoring tumor hemodynamics during a breath-hold may serve as a biomarker to predict chemotherapeutic efficacy of tumor.

[Intraoperative monitoring in artificial respiration of premature and newborn infants. I. Monitoring of respiratory parameters and alveolar ventilation].

PubMed

Lenz, G; Heipertz, W; Leidig, E; Madee, S

1986-06-01

Monitoring of ventilation serves to ensure adequate alveolar ventilation and arterial oxygenation, and to avoid pulmonary damage due to mechanical ventilation. Basic clinical monitoring, i.e., inspection, auscultation (including precordial or oesophageal stethoscope) and monitoring of heart rate and blood pressure, is mandatory. Mechanical ventilation is monitored by ventilation pressures (peak pressure, plateau pressure and endexpiratory pressure), ventilation volumes (measured at the in/expiratory valve of the respirator and by hot-wire anemometry at the tube connector), ventilation rate, and inspiratory oxygen concentration (FiO2). Alveolar ventilation should be continuously and indirectly recorded by capnometry (pECO2) and by measurement of transcutaneous pCO2 (tcpCO2), whereas oxygenation is determined via measurement of transcutaneous pO2 (tcpO2). Invasive monitoring of gas exchange is essential in prolonged or intrathoracic interventions as well as in neonates with cardiopulmonary problems. paCO2 may be estimated by capillary or venous blood gas analysis; arterial blood gas analysis is required for exact determination of paCO2 as well as arteriocutaneous pCO2 (atcDCO2) and arterio-end-expiratory (aEDCO2) gradients.

Vapor spill pipe monitor

DOEpatents

Bianchini, G.M.; McRae, T.G.

1983-06-23

The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

Broadband spectroscopic sensor for real-time monitoring of industrial SO(2) emissions.

PubMed

Xu, Feng; Zhang, Yungang; Somesfalean, Gabriel; Wang, Huashan; Wu, Shaohua; Zhang, Zhiguo

2007-05-01

A spectroscopic system for continuous real-time monitoring of SO(2) concentrations in industrial emissions was developed. The sensor is well suited for field applications due to simple and compact instrumental design, and robust data evaluation based on ultraviolet broadband absorption without the use of any calibration cell. The sensor has a detection limit of 1 ppm, and was employed both for gas-flow simulations with and without suspended particles, and for in situ measurement of SO(2) concentrations in the flue gas emitted from an industrial coal-fired boiler. The price/performance ratio of the instrument is expected to be superior to other comparable real-time monitoring systems.

Tube bundle system

PubMed Central

Marchewka, W.; Mohamed, K.; Addis, J.; Karnack, F.

2015-01-01

A tube bundle system (TBS) is a mechanical system for continuously drawing gas samples through tubes from multiple monitoring points located in an underground coal mine. The gas samples are drawn via vacuum pump to the surface and are typically analyzed for oxygen, methane, carbon dioxide and carbon monoxide. Results of the gas analyses are displayed and recorded for further analysis. Trends in the composition of the mine atmosphere, such as increasing methane or carbon monoxide concentration, can be detected early, permitting rapid intervention that prevents problems, such as a potentially explosive atmosphere behind seals, fire or spontaneous combustion. TBS is a well-developed technology and has been used in coal mines around the world for more than 50 years. Most longwall coal mines in Australia deploy a TBS, usually with 30 to 40 monitoring points as part of their atmospheric monitoring. The primary uses of a TBS are detecting spontaneous combustion and maintaining sealed areas inert. The TBS might also provide mine atmosphere gas composition data after a catastrophe occurs in an underground mine, if the sampling tubes are not damaged. TBSs are not an alternative to statutory gas and ventilation airflow monitoring by electronic sensors or people; rather, they are an option to consider in an overall mine atmosphere monitoring strategy. This paper describes the hardware, software and operation of a TBS and presents one example of typical data from a longwall coal mine PMID:26306052

Shale gas impacts on groundwater resources: insights from monitoring a fracking site in Poland

NASA Astrophysics Data System (ADS)

Montcoudiol, Nelly; Isherwood, Catherine; Gunning, Andrew; Kelly, Thomas; Younger, Paul

2017-04-01

Exploitation of shale gas by hydraulic fracturing (fracking) is highly controversial and concerns have been raised regarding induced risks from this technique. The SHEER project, an EU Horizon 2020-funded project, is looking into developing best practice to understand, prevent and mitigate the potential short- and long-term environmental impacts and risks from shale gas exploration and exploitation. Three major potential impacts were identified: groundwater contamination, air pollution and induced seismicity. This presentation will deal with the hydrogeological aspect. As part of the SHEER project, four monitoring wells were installed at a shale gas exploration site in Northern Poland. They intercept the main drinking water aquifer located in Quaternary sediments. Baseline monitoring was carried out from mid-December 2015 to beginning of June 2016. Fracking operations occurred in two horizontal wells, in two stages, in June and July 2016. The monitoring has continued after fracking was completed, with site visits every 4-6 weeks. Collected data include measurements of groundwater level, conductivity and temperature at 15-minute intervals, frequent sampling for laboratory analyses and field measurements of groundwater physico-chemical parameters. Groundwater samples are analysed for a range of constituents including dissolved gases and isotopes. The presentation will focus on the interpretation of baseline monitoring data. The insights gained into the behaviour of the Quaternary aquifer will allow a greater perspective to be place on the initial project understanding draw from previous studies. Short-term impacts will also be discussed in comparison with the baseline monitoring results. The presentation will conclude with discussion of challenges regarding monitoring of shale gas fracking sites.

33 CFR 127.201 - Sensing and alarm systems.

Code of Federal Regulations, 2012 CFR

2012-07-01

... systems. (a) Fixed sensors must have audio and visual alarms in the control room and audio alarms nearby. (b) Fixed sensors that continuously monitor for LNG vapors must— (1) Be in each enclosed area where vapor or gas may accumulate; and (2) Meet Section 9-4 of NFPA 59A. (c) Fixed sensors that continuously...

33 CFR 127.201 - Sensing and alarm systems.

Code of Federal Regulations, 2013 CFR

2013-07-01

... systems. (a) Fixed sensors must have audio and visual alarms in the control room and audio alarms nearby. (b) Fixed sensors that continuously monitor for LNG vapors must— (1) Be in each enclosed area where vapor or gas may accumulate; and (2) Meet Section 9-4 of NFPA 59A. (c) Fixed sensors that continuously...

33 CFR 127.201 - Sensing and alarm systems.

Code of Federal Regulations, 2014 CFR

2014-07-01

... systems. (a) Fixed sensors must have audio and visual alarms in the control room and audio alarms nearby. (b) Fixed sensors that continuously monitor for LNG vapors must— (1) Be in each enclosed area where vapor or gas may accumulate; and (2) Meet Section 9-4 of NFPA 59A. (c) Fixed sensors that continuously...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2011 CFR

2011-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2013 CFR

2013-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2010 CFR

2010-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2012 CFR

2012-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR Table 3 to Subpart Oooo of... - Applicability of General Provisions to Subpart OOOO

Code of Federal Regulations, 2013 CFR

2013-07-01

... of Performance for Crude Oil and Natural Gas Production, Transmission and Distribution Pt. 60, Subpt... Yes. § 60.4 Address Yes. § 60.5 Determination of construction or modification Yes. § 60.6 Review of... in subpart OOOO. § 60.12 Circumvention Yes. § 60.13 Monitoring requirements Yes Continuous monitors...

40 CFR Table 3 to Subpart Oooo of... - Applicability of General Provisions to Subpart OOOO

Code of Federal Regulations, 2014 CFR

2014-07-01

... of Performance for Crude Oil and Natural Gas Production, Transmission and Distribution Pt. 60, Subpt... Yes. § 60.4 Address Yes. § 60.5 Determination of construction or modification Yes. § 60.6 Review of... in subpart OOOO. § 60.12 Circumvention Yes. § 60.13 Monitoring requirements Yes Continuous monitors...

40 CFR 63.3168 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2012 CFR

2012-07-01

... regenerative carbon adsorber as an add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling cycle, and comply with paragraphs (a)(3) through (5) and (d)(1) and (2...

Method for Continuous Monitoring of Electrospray Ion Formation

NASA Astrophysics Data System (ADS)

Metzler, Guille; Crathern, Susan; Bachmann, Lorin; Fernández-Metzler, Carmen; King, Richard

2017-10-01

A method for continuously monitoring the performance of electrospray ionization without the addition of hardware or chemistry to the system is demonstrated. In the method, which we refer to as SprayDx, cluster ions with solvent vapor natively formed by electrospray are followed throughout the collection of liquid chromatography-selected reaction monitoring data. The cluster ion extracted ion chromatograms report on the consistency of the ion formation and detection system. The data collected by the SprayDx method resemble the data collected for postcolumn infusion of analyte. The response of the cluster ions monitored reports on changes in the physical parameters of the ion source such as voltage and gas flow. SprayDx is also observed to report on ion suppression in a fashion very similar to a postcolumn infusion of analyte. We anticipate the method finding utility as a continuous readout on the performance of electrospray and other atmospheric pressure ionization processes. [Figure not available: see fulltext.

Continuous Turbidity Monitoring in the Indian Creek Watershed, Tazewell County, Virginia, 2006-08

USGS Publications Warehouse

Moyer, Douglas; Hyer, Kenneth

2009-01-01

Thousands of miles of natural gas pipelines are installed annually in the United States. These pipelines commonly cross streams, rivers, and other water bodies during pipeline construction. A major concern associated with pipelines crossing water bodies is increased sediment loading and the subsequent impact to the ecology of the aquatic system. Several studies have investigated the techniques used to install pipelines across surface-water bodies and their effect on downstream suspended-sediment concentrations. These studies frequently employ the evaluation of suspended-sediment or turbidity data that were collected using discrete sample-collection methods. No studies, however, have evaluated the utility of continuous turbidity monitoring for identifying real-time sediment input and providing a robust dataset for the evaluation of long-term changes in suspended-sediment concentration as it relates to a pipeline crossing. In 2006, the U.S. Geological Survey, in cooperation with East Tennessee Natural Gas and the U.S. Fish and Wildlife Service, began a study to monitor the effects of construction of the Jewell Ridge Lateral natural gas pipeline on turbidity conditions below pipeline crossings of Indian Creek and an unnamed tributary to Indian Creek, in Tazewell County, Virginia. The potential for increased sediment loading to Indian Creek is of major concern for watershed managers because Indian Creek is listed as one of Virginia's Threatened and Endangered Species Waters and contains critical habitat for two freshwater mussel species, purple bean (Villosa perpurpurea) and rough rabbitsfoot (Quadrula cylindrical strigillata). Additionally, Indian Creek contains the last known reproducing population of the tan riffleshell (Epioblasma florentina walkeri). Therefore, the objectives of the U.S. Geological Survey monitoring effort were to (1) develop a continuous turbidity monitoring network that attempted to measure real-time changes in suspended sediment (using turbidity as a surrogate) downstream from the pipeline crossings, and (2) provide continuous turbidity data that enable the development of a real-time turbidity-input warning system and assessment of long-term changes in turbidity conditions. Water-quality conditions were assessed using continuous water-quality monitors deployed upstream and downstream from the pipeline crossings in Indian Creek and the unnamed tributary. These paired upstream and downstream monitors were outfitted with turbidity, pH (for Indian Creek only), specific-conductance, and water-temperature sensors. Water-quality data were collected continuously (every 15 minutes) during three phases of the pipeline construction: pre-construction, during construction, and post-construction. Continuous turbidity data were evaluated at various time steps to determine whether the construction of the pipeline crossings had an effect on downstream suspended-sediment conditions in Indian Creek and the unnamed tributary. These continuous turbidity data were analyzed in real time with the aid of a turbidity-input warning system. A warning occurred when turbidity values downstream from the pipeline were 6 Formazin Nephelometric Units or 15 percent (depending on the observed range) greater than turbidity upstream from the pipeline crossing. Statistical analyses also were performed on monthly and phase-of-construction turbidity data to determine if the pipeline crossing served as a long-term source of sediment. Results of this intensive water-quality monitoring effort indicate that values of turbidity in Indian Creek increased significantly between the upstream and downstream water-quality monitors during the construction of the Jewell Ridge pipeline. The magnitude of the significant turbidity increase, however, was small (less than 2 Formazin Nephelometric Units). Patterns in the continuous turbidity data indicate that the actual pipeline crossing of Indian Creek had little influence of downstream water quality; co

Protocol Gas Verification Program Audit Reports

EPA Pesticide Factsheets

View the full reports from 2010 and 2013 of the PGVP audits, which tested the EPA Protocol gases that are used to calibrate continuous emission monitoring systems (CEMS), and the instruments used in EPA reference methods.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alhroob, M.; Boyd, G.; Hasib, A.

Precision ultrasonic measurements in binary gas systems provide continuous real-time monitoring of mixture composition and flow. Using custom micro-controller-based electronics, we have developed an ultrasonic instrument, with numerous potential applications, capable of making continuous high-precision sound velocity measurements. The instrument measures sound transit times along two opposite directions aligned parallel to - or obliquely crossing - the gas flow. The difference between the two measured times yields the gas flow rate while their average gives the sound velocity, which can be compared with a sound velocity vs. molar composition look-up table for the binary mixture at a given temperature andmore » pressure. The look-up table may be generated from prior measurements in known mixtures of the two components, from theoretical calculations, or from a combination of the two. We describe the instrument and its performance within numerous applications in the ATLAS experiment at the CERN Large Hadron Collider (LHC). The instrument can be of interest in other areas where continuous in-situ binary gas analysis and flowmetry are required. (authors)« less

Invisible CO2 gas killing trees at Mammoth Mountain, California

USGS Publications Warehouse

Sorey, Michael L.; Farrar, Christopher D.; Evans, William C.; Hill, David P.; Bailey, Roy A.; Hendley, James W.; Stauffer, Peter H.

1996-01-01

Since 1980, scientists have monitored geologic unrest in Long Valley Caldera and at adjacent Mammoth Mountain, California. After a persistent swarm of earthquakes beneath Mammoth Mountain in 1989, earth scientists discovered that large volumes of carbon dioxide (CO2) gas were seeping from beneath this volcano. This gas is killing trees on the mountain and also can be a danger to people. The USGS continues to study the CO2 emissions to help protect the public from this invisible potential hazard.

Invisible CO2 gas killing trees at Mammoth Mountain, California

USGS Publications Warehouse

Sorey, Michael L.; Farrar, Christopher D.; Gerlach, Terrance M.; McGee, Kenneth A.; Evans, William C.; Colvard, Elizabeth M.; Hill, David P.; Bailey, Roy A.; Rogie, John D.; Hendley, James W.; Stauffer, Peter H.

2000-01-01

Since 1980, scientists have monitored geologic unrest in Long Valley Caldera and at adjacent Mammoth Mountain, California. After a persistent swarm of earthquakes beneath Mammoth Mountain in 1989, geologists discovered that large volumes of carbon dioxide (CO2 ) gas were seeping from beneath this volcano. This gas is killing trees on the mountain and also can be a danger to people. The U.S. Geological Survey (USGS) continues to study the CO2 emissions to help protect the public from this invisible potential hazard.

FIELD METHOD COMPARISON BETWEEN PASSIVE AIR SAMPLERS AND CONTINUOUS MONITORS FOR VOLATILE ORGANIC COMPOUNDS AND NO2 IN EL PASO, TEXAS, USA

EPA Science Inventory

Passive sampling of gas-phase air toxics and criteria pollutants has become an attractive monitoring method in human exposure studies due to the relatively low sampling cost and ease of use. This study evaluates the performance of Model 3300 Ogawa(TM) Passive NO2 Samplers and 3...

40 CFR 63.4768 - What are the requirements for continuous parameter monitoring system installation, operation, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... using a carbon adsorber as an add-on control device, you must monitor the total regeneration desorbing gas (e.g., steam or nitrogen) mass flow for each regeneration cycle, the carbon bed temperature after each regeneration and cooling cycle, and comply with paragraphs (a)(3) through (5) and (d)(1) and (2...

Implementation of a dynamic data entry system for the PHENIX gas system

NASA Astrophysics Data System (ADS)

Hagiwara, Masako

2003-10-01

The PHENIX detector at the BNL RHIC facility uses multiple detector technologies that require a precise gas delivery system, including flammable gases that require additional monitoring. During operation of the detector, it is crucial to maintain stable and safe operating conditions by carefully monitoring flows, pressures, and various other gas properties. These systems are monitored during running periods on a continuous basis. For the most part, these records were kept by hand, filling out a paper logsheet every four hours. A dynamic data entry system was needed to replace the paper logsheets. The solution created was to use a PDA or laptop computer with a wireless connection to enter the data directly into a MySQL database. The system uses PHP to dynamically create and update the data entry pages. The data entered can be viewed in graphs as well as tables. As a result, the data recorded will be easily accessible during PHENIX's next running period. It also allows for long term archiving, making the data available during the analysis phase, providing knowledge of the operating conditions of the gas system.

Long-Term Outdoor Reliability Assessment of a Wireless Unit for Air-Quality Monitoring Based on Nanostructured Films Integrated on Micromachined Platforms

PubMed Central

Leccardi, Matteo; Decarli, Massimiliano; Lorenzelli, Leandro; Milani, Paolo; Mettala, Petteri; Orava, Risto; Barborini, Emanuele

2012-01-01

We have fabricated and tested in long-term field operating conditions a wireless unit for outdoor air quality monitoring. The unit is equipped with two multiparametric sensors, one miniaturized thermo-hygrometer, front-end analogical and digital electronics, and an IEEE 802.15.4 based module for wireless data transmission. Micromachined platforms were functionalized with nanoporous metal-oxides to obtain multiparametric sensors, hosting gas-sensitive, anemometric and temperature transducers. Nanoporous metal-oxide layer was directly deposited on gas sensing regions of micromachined platform batches by hard-mask patterned supersonic cluster beam deposition. An outdoor, roadside experiment was arranged in downtown Milan (Italy), where one wireless sensing unit was continuously operated side by side with standard gas chromatographic instrumentation for air quality measurements. By means of a router PC, data from sensing unit and other instrumentation were collected, merged, and sent to a remote data storage server, through an UMTS device. The whole-system robustness as well as sensor dataset characteristics were continuously characterized over a run-time period of 18 months. PMID:22969394

A method for estimation of bias and variability of continuous gas monitor data: application to carbon monoxide monitor accuracy.

PubMed

Shulman, Stanley A; Smith, Jerome P

2002-01-01

A method is presented for the evaluation of the bias, variability, and accuracy of gas monitors. This method is based on using the parameters for the fitted response curves of the monitors. Thereby, variability between calibrations, between dates within each calibration period, and between different units can be evaluated at several different standard concentrations. By combining variability information with bias information, accuracy can be assessed. An example using carbon monoxide monitor data is provided. Although the most general statistical software required for these tasks is not available on a spreadsheet, when the same number of dates in a calibration period are evaluated for each monitor unit, the calculations can be done on a spreadsheet. An example of such calculations, together with the formulas needed for their implementation, is provided. In addition, the methods can be extended by use of appropriate statistical models and software to evaluate monitor trends within calibration periods, as well as consider the effects of other variables, such as humidity and temperature, on monitor variability and bias.

One year continuous soil gas monitoring above an EGR test site

NASA Astrophysics Data System (ADS)

Furche, Markus; Schlömer, Stefan; Faber, Eckhard; Dumke, Ingolf

2010-05-01

Setup and first results of an ongoing research activity are presented, which is funded by the German Geotechnologien program within in the joint project CLEAN (CO2 Large Scale Enhanced Gas Recovery in the Altmark Natural Gas Field). The task is to establish several soil gas monitoring stations above a partly exhausted gas field in the Altmark which will be used for an enhanced gas recovery (EGR) test by injecting CO2 into the reservoir. The aim is to optimize the monitoring technique including automatic data transfer and data exploitation and to understand mechanisms of natural variations of soil gas concentrations in the specific area. Furthermore the suitability of these measurements as a contribution to leakage detection shall be evaluated. A network of 13 gauging stations for the measurement of CO2 is working continuously for about one year. They are spread over an area of 8 x 3 km and are situated in direct vicinity of existing deep boreholes as the most likely locations for possible leakage. In addition one station is placed far outside the gasfield as a reference point. The technique applied to measure soil gas concentrations uses a gas stream circulating in a tube going down a shallow borehole where the circulating gas is in contact with the soil gas phase via a gas permeable membrane. Above surface, moisture is removed from the gas stream before it reaches several gas sensors for CO2. Besides these, several other parameters are determined as well, e.g. soil moisture and soil temperature, water level, gas flow and gas moisture. In addition a meteorological station gives information about precipitation, air humidity, temperature and pressure, global radiation, wind direction and velocity in the area. Data are continuously collected by dataloggers at each station (5 minutes interval), transferred via GSM routers to the BGR server in Hannover and are stored in a specially designed database. The database does not only contain the measurements but also information about hardware configurations at the stations, maintenance carried out and special events which might have influenced the results. An interactive database application has been developed to allow versatile graphical output and statistical processing of the collected time series. On a large scale CO2 concentrations show natural seasonal variations with higher values during summer (July to September) and lower values during winter. This behaviour is expected and mainly caused by temperature dependent activities of bacterial CO2 production. Absolute concentrations however vary extremely between different locations. While several stations show more than 10% CO2 during summer, others stay below 0.1% at the same time. The conclusion is that individual baselines at all sites for a sufficient time without CO2 sequestration are necessary. The CLEAN project is financed by the German Federal Ministry of Education and Research (BMBF) within the special program Geotechnologien. We would like to thank GDF SUEZ E&P Deutschland GmbH for supporting our field work at the well sites.

Development of a Prototype Optical Hydrogen Gas Sensor Using a Getter-Doped Polymer Transducer for Monitoring Cumulative Exposure: Preliminary Results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Small IV, W; Maitland, D J; Wilson, T S

2008-06-05

A novel prototype optical sensor for monitoring cumulative hydrogen gas exposure was fabricated and evaluated. Chemical-to-optical transduction was accomplished by detecting the intensity of 670 nm laser light transmitted through a hydrogen getter-doped polymer film mounted at the end of an optical fiber; the transmittance of the composite film increased with uptake of hydrogen by the embedded getter. The composite film consisted of the hydrogen getter 1,4-bis(phenylethynyl)benzene, also known as DEB, with carbon-supported palladium catalyst embedded in silicone elastomer. Because the change in transmittance was irreversible and occurred continuously as the getter captured hydrogen, the sensor behaved like a dosimeter,more » providing a unique indication of the cumulative gas exposure.« less

Multicapillary Gas Chromatography-Temperature Modulated Metal Oxide Semiconductor Sensors Array Detector for Monitoring of Volatile Organic Compounds in Closed Atmosphere Using Gaussian Apodization Factor Analysis.

PubMed

Alinoori, Amir Hossein; Masoum, Saeed

2018-05-22

A unique metal oxide semiconductor sensor (MOS) array detector with eight sensors was designed and fabricated in a PTFE chamber as an interface for coupling with multicapillary gas chromatography. This design consists of eight transfer lines with equal length between the multicapillary columns (MCC) and sensors. The deactivated capillary columns were passed through each transfer line and homemade flow splitter to distribute the same gas flow on each sensor. Using the eight ports flow splitter design helps us to equal the length of carrier gas path and flow for each sensor, minimizing the dead volume of the sensor's chamber and increasing chromatographic resolution. In addition to coupling of MCC to MOS array detector and other considerations in hardware design, modulation of MOS temperature was used to increase sensitivity and selectivity, and data analysis was enhanced with adapted Gaussian apodization factor analysis (GAFA) as a multivariate curve resolution algorithm. Continues air sampling and injecting system (CASI) design provides a fast and easily applied method for continues injection of air sample with no additional sample preparation. The analysis cycle time required for each run is less than 300 s. The high sample load and sharp injection with the fast separation by MCC decrease the peak widths and improve detection limits. This homemade customized instrument is an alternative to other time-consuming and expensive technologies for continuous monitoring of outgassing in air samples.

Continuous neonatal blood gas monitoring using a multiparameter intra-arterial sensor

PubMed Central

Morgan, C; Newell, S; Ducker, D; Hodgkinson, J; White, D; Morley, C; Church, J

1999-01-01

AIMS—To compare arterial blood gas (ABG) readings obtained with a multiparameter intra-arterial sensor with those from an ABG analyser.
METHODS—An MPIAS with the ability to measure continuously pH, PaCO2, and PaO2 was introduced via an umbilical arterial catheter in 27 neonates requiring intensive care. They underwent 3260 hours of MPIAS monitoring, during which 753 ABG readings were performed.
RESULTS—Overall bias (mean difference: MPIAS-ABG) and precision (standard deviation of differences) values were: −0.002 and 0.022,respectively, for pH; +0.26 and 0.52 for PaCO2 (kPa); and −0.19 and 0.99 for PaO2 (kPa). This gave 95% limits of agreement as: −0.047 to +0.042 for pH, −0.76 to +1.28 kPa for PaCO2, and −2.13 to +1.75 kPa for PaO2. For each variable, precision across readings from the same individual was better than overall precision for all data. No complications related to the use of the catheter were observed.
CONCLUSIONS—Continuous MPIAS ABG monitoring is an exciting development, with the potential to reduce blood transfusions and improve ABG homeostasis.

 PMID:10325783

On the development of a methodology for extensive in-situ and continuous atmospheric CO2 monitoring

NASA Astrophysics Data System (ADS)

Wang, K.; Chang, S.; Jhang, T.

2010-12-01

Carbon dioxide is recognized as the dominating greenhouse gas contributing to anthropogenic global warming. Stringent controls on carbon dioxide emissions are viewed as necessary steps in controlling atmospheric carbon dioxide concentrations. From the view point of policy making, regulation of carbon dioxide emissions and its monitoring are keys to the success of stringent controls on carbon dioxide emissions. Especially, extensive atmospheric CO2 monitoring is a crucial step to ensure that CO2 emission control strategies are closely followed. In this work we develop a methodology that enables reliable and accurate in-situ and continuous atmospheric CO2 monitoring for policy making. The methodology comprises the use of gas filter correlation (GFC) instrument for in-situ CO2 monitoring, the use of CO2 working standards accompanying the continuous measurements, and the use of NOAA WMO CO2 standard gases for calibrating the working standards. The use of GFC instruments enables 1-second data sampling frequency with the interference of water vapor removed from added dryer. The CO2 measurements are conducted in the following timed and cycled manner: zero CO2 measurement, two standard CO2 gases measurements, and ambient air measurements. The standard CO2 gases are calibrated again NOAA WMO CO2 standards. The methodology is used in indoor CO2 measurements in a commercial office (about 120 people working inside), ambient CO2 measurements, and installed in a fleet of in-service commercial cargo ships for monitoring CO2 over global marine boundary layer. These measurements demonstrate our method is reliable, accurate, and traceable to NOAA WMO CO2 standards. The portability of the instrument and the working standards make the method readily applied for large-scale and extensive CO2 measurements.

An integrated GPS-FID system for airborne gas detection of pipeline right-of-ways

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gehue, H.L.; Sommer, P.

1996-12-31

Pipeline integrity, safety and environmental concerns are of prime importance in the Canadian natural gas industry. Terramatic Technology Inc. (TTI) has developed an integrated GPS/FID gas detection system known as TTI-AirTrac{trademark} for use in airborne gas detection (AGD) along pipeline right-of-ways. The Flame Ionization Detector (FID), which has traditionally been used to monitor air quality for gas plants and refineries, has been integrated with the Global Positioning System (GPS) via a 486 DX2-50 computer and specialized open architecture data acquisition software. The purpose of this technology marriage is to be able to continuously monitor air quality during airborne pipeline inspection.more » Event tagging from visual surveillance is used to determine an explanation of any delta line deviations (DLD). These deviations are an indication of hydrocarbon gases present in the plume that the aircraft has passed through. The role of the GPS system is to provide mapping information and coordinate data for ground inspections. The ground based inspection using a handheld multi gas detector will confirm whether or not a leak exists.« less

Online gas monitoring and sampling during drilling of the INFLUINS borehole EF-FB 1/12 into the Thuringian Syncline, Germany

NASA Astrophysics Data System (ADS)

Görlitz, Marco; Abratis, Michael; Wiersberg, Thomas

2014-05-01

Online monitoring and sampling of drill mud gas (OLGA) was conducted during standard rotary drilling and core drilling of the INFLUINS borehole EF-FB 1/12 to gain information on the composition of gases and their distribution at depth within the Thuringian Syncline (Germany). The method can help to identify areas of enhanced permeability and/or porosity, open fractures, and other strata associated with gases at depth. The gas-loaded drill mud was continuously degassed in a modified gas-water separator, which was installed in the mud ditch in close distance to the drill mud outlet. The extracted gas phase was pumped in a nearby field laboratory for continuous on-line analysis. First information on the gas composition (H2, He, N2, O2, CO2, CH4, Ar, Kr) was available only few minutes after gas extraction. More than 40 gas samples were taken from the gas line during drilling and pumping tests for further laboratory studies. Enhanced concentration of methane, helium, hydrogen and carbon dioxide were detected in drill mud when the drill hole encountered gas-rich strata. Down to a depth of 620 m, the drill mud contained maximum concentration of 55 ppmv He, 1400 ppmv of CH4, 400 ppmv of hydrogen and 1.1 vol-% of CO2. The drilling mud gas composition is linked with the drilled strata. Buntsandstein and Muschelkalk show different formation gas composition and are therefore hydraulically separated. Except for helium, the overall abundance of formation gases in drilling mud is relatively low. We therefore consider the INFLUINS borehole to be dry. The correlation between hydrogen and helium and the relatively high helium abundance rules out any artificial origin of hydrogen and suggest a radiolytic origin of hydrogen. Values CH4/(C2H6/C3H8)

Further development and testing of the metabolic gas analyzer

NASA Technical Reports Server (NTRS)

1973-01-01

Continued development of a metabolic monitor utilizing a mass spectrometer and digital computer to perform measurements and data reduction, is reported. The device prints-out breath-by-breath values for 02 consumption, C02 production, minute volume and tidal volume. The flow is measured by introduction of a tracer gas to the expired gas stream. Design modifications to reduce pressure drop in the flow splitter to one inch of water at 600 liters/min flow and to extend the range of linear flow measurement to 1000 liters/min are discussed.

Report: Response to Congressional Inquiry Regarding the EPA’s Emergency Order to the Range Resources Gas Drilling Company

EPA Pesticide Factsheets

Report #14-P-0044, December 20, 2013. The EPA withdrew its emergency order regarding Range Resources hydraulic fracturing operations, but continues to monitor the situation for evidence of widespread contamination.

Method for monitoring stack gases for uranium activity

DOEpatents

Beverly, C.R.; Ernstberger, E.G.

1985-07-03

A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

Method for monitoring stack gases for uranium activity

DOEpatents

Beverly, Claude R.; Ernstberger, Harold G.

1988-01-01

A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

Spatial and temporal anomalies of soil gas in northern Taiwan and its tectonic and seismic implications

NASA Astrophysics Data System (ADS)

Fu, Ching-Chou; Yang, Tsanyao Frank; Chen, Cheng-Hong; Lee, Lou-Chuang; Wu, Yih-Min; Liu, Tsung-Kwei; Walia, Vivek; Kumar, Arvind; Lai, Tzu-Hua

2017-11-01

In this paper, we study (1) the spatial anomalies and (2) the temporal anomalies of soil gas in northern Taiwan. The spatial anomalies of soil gas are related to tectonic faults, while the temporal anomalies of soil gas are associated with pre-earthquake activities. Detailed soil gas sampling was systematically performed, and the analysis of the collected gas species shows that high helium and nitrogen concentrations appear in samples from specific sites, which coincide with the structural setting of the area studied. This analysis indicates the possibility of using these soil gases to determine fault zones in the studied area. Based on the soil gas data, a station (Tapingti) for automatic soil gas monitoring was constructed on an appropriate site at the fault zone. Some anomalous high radon concentrations at certain times can be identified from the dataset, which was generated by the continuous monitoring of soil gas for over a year. Notably, many of these anomalies were observed several hours to a few days before the earthquakes (ML > 3) that occurred in northern Taiwan. By combining the information of epicenters and fault plane solutions of these earthquakes, we find that the shallow earthquakes (<15 km) were mainly strike-slip and normal-type earthquakes, and concentrated within a distance of 30 km to the monitoring site (Group A). The deep earthquakes (>20 km) were mainly thrust-type earthquakes and distributed in greater distances (>45 km) east of the monitoring site (Group B). Such focal mechanisms of earthquakes suggest an extensional and compressional structural domain in the continental crust for Group A and Group B earthquakes, respectively. It is suggested that the pre-earthquake activities associated with the seismicity of Group B may be transmitted along the major decollement in the region below the Tapingti station, leading to the observed soil gas enhancements.

Online Monitoring System of Air Distribution in Pulverized Coal-Fired Boiler Based on Numerical Modeling

NASA Astrophysics Data System (ADS)

Żymełka, Piotr; Nabagło, Daniel; Janda, Tomasz; Madejski, Paweł

2017-12-01

Balanced distribution of air in coal-fired boiler is one of the most important factors in the combustion process and is strongly connected to the overall system efficiency. Reliable and continuous information about combustion airflow and fuel rate is essential for achieving optimal stoichiometric ratio as well as efficient and safe operation of a boiler. Imbalances in air distribution result in reduced boiler efficiency, increased gas pollutant emission and operating problems, such as corrosion, slagging or fouling. Monitoring of air flow trends in boiler is an effective method for further analysis and can help to appoint important dependences and start optimization actions. Accurate real-time monitoring of the air distribution in boiler can bring economical, environmental and operational benefits. The paper presents a novel concept for online monitoring system of air distribution in coal-fired boiler based on real-time numerical calculations. The proposed mathematical model allows for identification of mass flow rates of secondary air to individual burners and to overfire air (OFA) nozzles. Numerical models of air and flue gas system were developed using software for power plant simulation. The correctness of the developed model was verified and validated with the reference measurement values. The presented numerical model for real-time monitoring of air distribution is capable of giving continuous determination of the complete air flows based on available digital communication system (DCS) data.

40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

...-gas ratio above the limit established during the performance test. 4. Option 3: Ni lb/hr not subject to the NSPS for PM in 40 CFR 60.102. a. Continuous opacity monitoring system. The daily average Ni operating value must not exceed the site-specific Ni operating limit established during the performance test...

40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

...-gas ratio above the limit established during the performance test. 4. Option 3: Ni lb/hr not subject to the NSPS for PM in 40 CFR 60.102. a. Continuous opacity monitoring system. The daily average Ni operating value must not exceed the site-specific Ni operating limit established during the performance test...

A Low-Power and Portable Biomedical Device for Respiratory Monitoring with a Stable Power Source

PubMed Central

Yang, Jiachen; Chen, Bobo; Zhou, Jianxiong; Lv, Zhihan

2015-01-01

Continuous respiratory monitoring is an important tool for clinical monitoring. Associated with the development of biomedical technology, it has become more and more important, especially in the measuring of gas flow and CO2 concentration, which can reflect the status of the patient. In this paper, a new type of biomedical device is presented, which uses low-power sensors with a piezoresistive silicon differential pressure sensor to measure gas flow and with a pyroelectric sensor to measure CO2 concentration simultaneously. For the portability of the biomedical device, the sensors and low-power measurement circuits are integrated together, and the airway tube also needs to be miniaturized. Circuits are designed to ensure the stability of the power source and to filter out the existing noise. Modulation technology is used to eliminate the fluctuations at the trough of the waveform of the CO2 concentration signal. Statistical analysis with the coefficient of variation was performed to find out the optimal driving voltage of the pressure transducer. Through targeted experiments, the biomedical device showed a high accuracy, with a measuring precision of 0.23 mmHg, and it worked continuously and stably, thus realizing the real-time monitoring of the status of patients. PMID:26270665

The Oxidative Stability of Deuterated Lubricants

DTIC Science & Technology

1982-01-01

through the fluid at some elevated temperature Iand following the increase of viscosity, acidity , or peroxide concentration with time, or monitoring the...1to use, the cells were cleaned in a hot nitric/sulfuric acid bath, rinsed repeatedly with distilled water, and baked overnight in an oven. All sample J...detection), and acidity (by base titration). The gas evolution rate of the lubricant was measured continuously with the gas sensor and displayed on a

Measured Plume Dispersion Parameters Over Water. Volume 1.

DTIC Science & Technology

1984-09-01

meteorlogical parameters were continuously monitored at various locations. Tracer gas concentrations were measured by a variety of methods at...addition, this step added a header . to the data set containing a variety of averaged meteorlogical quantities. The basic procedure in this step was

Ratiometric Gas Reporting: A Nondisruptive Approach To Monitor Gene Expression in Soils.

PubMed

Cheng, Hsiao-Ying; Masiello, Caroline A; Del Valle, Ilenne; Gao, Xiaodong; Bennett, George N; Silberg, Jonathan J

2018-03-16

Fluorescent proteins are ubiquitous tools that are used to monitor the dynamic functions of natural and synthetic genetic circuits. However, these visual reporters can only be used in transparent settings, a limitation that complicates nondisruptive measurements of gene expression within many matrices, such as soils and sediments. We describe a new ratiometric gas reporting method for nondisruptively monitoring gene expression within hard-to-image environmental matrices. With this approach, C 2 H 4 is continuously synthesized by ethylene forming enzyme to provide information on viable cell number, and CH 3 Br is conditionally synthesized by placing a methyl halide transferase gene under the control of a conditional promoter. We show that ratiometric gas reporting enables the creation of Escherichia coli biosensors that report on acylhomoserine lactone (AHL) autoinducers used for quorum sensing by Gram-negative bacteria. Using these biosensors, we find that an agricultural soil decreases the bioavailable concentration of a long-chain AHL up to 100-fold. We also demonstrate that these biosensors can be used in soil to nondisruptively monitor AHLs synthesized by Rhizobium leguminosarum and degraded by Bacillus thuringiensis. Finally, we show that this new reporting approach can be used in Shewanella oneidensis, a bacterium that lives in sediments.

Comparison study and thoron interference test of different radon monitors.

PubMed

Sumesh, C G; Kumar, A Vinod; Tripathi, R M; Puranik, V D

2013-03-01

A comparison study and thoron interference test for different continuous radon monitors were carried out. The comparison study includes three passive diffusion monitors [one pulse ionisation chamber based-Alpha Guard and two silicon semi-conductor based-Radon Scout Plus (RSP)] and one silicon semi-conductor-based active radon thoron discriminating monitor--RAD 7. Radon emanation standard, supplied by National Institute of Science and Technology, has been utilised for the comparison study to qualify the calibration of the continuous radon monitors. All the instruments showed good agreement with the estimated radon concentration using (226)Ra/(222)Rn emanation standard. It was found that the active radon monitoring system is having a higher initial response towards the transient radon concentration than the passive radon monitors studied. The instruments measuring radon concentration without energy discrimination are likely to have some sensitivity towards the thoron concentration. Thus, thoron interference study was carried out in the above monitors. Nine percent interference in measured radon concentration in the Alpha Guard monitor and 4 % interference in the semi-conductor-based RSP monitors was observed. Study indicates that the interference of thoron in radon monitors depends on the area of diffusion of gas, volume of detection and sensitivity factor.

46 CFR 154.1810 - Cargo manual.

Code of Federal Regulations, 2012 CFR

2012-10-01

... with inert gas and air. (13) A description of hull and cargo tank temperature monitoring systems. (14... GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1810 Cargo manual. (a) No person...

46 CFR 154.1810 - Cargo manual.

Code of Federal Regulations, 2011 CFR

2011-10-01

... with inert gas and air. (13) A description of hull and cargo tank temperature monitoring systems. (14... GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1810 Cargo manual. (a) No person...

46 CFR 154.1810 - Cargo manual.

Code of Federal Regulations, 2014 CFR

2014-10-01

... with inert gas and air. (13) A description of hull and cargo tank temperature monitoring systems. (14... GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1810 Cargo manual. (a) No person...

46 CFR 154.1810 - Cargo manual.

Code of Federal Regulations, 2013 CFR

2013-10-01

... with inert gas and air. (13) A description of hull and cargo tank temperature monitoring systems. (14... GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1810 Cargo manual. (a) No person...

33 CFR 155.710 - Qualifications of person in charge.

Code of Federal Regulations, 2012 CFR

2012-07-01

... SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL POLLUTION PREVENTION REGULATIONS FOR VESSELS... control and monitoring systems, the procedures for reporting pollution incidents, and, if installed, the Crude-Oil Washing (COW), inert-gas, and vapor-control systems—to safely conduct a transfer of fuel oil...

33 CFR 155.710 - Qualifications of person in charge.

Code of Federal Regulations, 2011 CFR

2011-07-01

... SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL POLLUTION PREVENTION REGULATIONS FOR VESSELS... control and monitoring systems, the procedures for reporting pollution incidents, and, if installed, the Crude-Oil Washing (COW), inert-gas, and vapor-control systems—to safely conduct a transfer of fuel oil...

Functionalized multi-walled carbon nanotube based sensors for distributed methane leak detection

EPA Science Inventory

This paper presents a highly sensitive, energy efficient and low-cost distributed methane (CH4) sensor system (DMSS) for continuous monitoring, detection and localization of CH4 leaks in natural gas infrastructure such as transmission and distribution pipelines, wells, and produc...

Monitoring and manipulating Higgs and Goldstone modes in a supersolid quantum gas.

PubMed

Léonard, Julian; Morales, Andrea; Zupancic, Philip; Donner, Tobias; Esslinger, Tilman

2017-12-15

Higgs and Goldstone modes are collective excitations of the amplitude and phase of an order parameter that is related to the breaking of a continuous symmetry. We directly studied these modes in a supersolid quantum gas created by coupling a Bose-Einstein condensate to two optical cavities, whose field amplitudes form the real and imaginary parts of a U(1)-symmetric order parameter. Monitoring the cavity fields in real time allowed us to observe the dynamics of the associated Higgs and Goldstone modes and revealed their amplitude and phase nature. We used a spectroscopic method to measure their frequencies, and we gave a tunable mass to the Goldstone mode by exploring the crossover between continuous and discrete symmetry. Our experiments link spectroscopic measurements to the theoretical concept of Higgs and Goldstone modes. Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

Cabin Atmosphere Monitoring System (CAMS), pre-prototype model development continuation

NASA Technical Reports Server (NTRS)

Bursack, W. W.; Harris, W. A.

1975-01-01

The development of the Cabin Atmosphere Monitoring System (CAMS) is described. Attention was directed toward improving stability and reliability of the design using flight application guidelines. Considerable effort was devoted to the development of a temperature-stable RF/DC generator used for excitation of the quadrupole mass filter. Minor design changes were made in the preprototype model. Specific gas measurement examples are included along with a discussion of the measurement rationale employed.

Automated Monitoring of Pipeline Rights-of-Way

NASA Technical Reports Server (NTRS)

Frost, Chard Ritchie

2010-01-01

NASA Ames Research Center and the Pipeline Research Council International, Inc. have partnered in the formation of a research program to identify and develop the key technologies required to enable automated detection of threats to gas and oil transmission and distribution pipelines. This presentation describes the Right-of-way Automated Monitoring (RAM) program and highlights research successes to date, continuing challenges to implementing the RAM objectives, and the program's ongoing work and plans.

Development of advanced Czochralski growth process to produce low cost 150 kg silicon ingots from a single crucible for technology readiness. [crystal growth

NASA Technical Reports Server (NTRS)

Lane, R. L.

1981-01-01

Six growth runs used the Kayex-Hameo Automatic Games Logic (AGILE) computer based system for growth from larger melts in the Mod CG2000. The implementation of the melt pyrometer sensor allowed for dip temperature monitoring and usage by the operator/AGILE system. Use of AGILE during recharge operations was successfully evaluated. The tendency of crystals to lose cylindrical shape (spiraling) continued to be a problem. The hygrometer was added to the Furnace Gas Analysis System and used on several growth runs. The gas chromatograph, including the integrator, was also used for more accurate carbon monoxide concentration measurements. Efforts continued for completing the automation of the total Gas Analysis System. An economic analysis, based on revised achievable straight growth rate, is presented.

The first five years of Kīlauea’s summit eruption in Halema‘uma‘u Crater, 2008–2013

USGS Publications Warehouse

Patrick, Matthew R.; Orr, Tim R.; Sutton, A.J.; Elias, Tamar; Swanson, Donald A.

2013-01-01

The eruption in Halema‘uma‘u Crater that began in March 2008 is the longest summit eruption of Kīlauea Volcano, on the Island of Hawai‘i, since 1924. From the time the eruption began, the new "Overlook crater" inside Halema‘uma‘u has exhibited fluctuating lava lake activity, occasional small explosive events, and a persistent gas plume. The beautiful nighttime glow impresses and thrills visitors in Hawai‘i Volcanoes National Park, but the continuous emission of sulfur dioxide gas produces "vog" (volcanic smog) that can severely affect communities and local agriculture downwind. U.S. Geological Survey scientists continue to closely monitor the eruption and assess ongoing hazards.

Laser Spectroscopy Multi-Gas Monitor: Results of Technology Demonstration on ISS

NASA Technical Reports Server (NTRS)

Mudgett, Paul D.; Pilgrim, Jeffrey S.

2015-01-01

Tunable diode laser spectroscopy (TDLS) is an up and coming trace and major gas monitoring technology with unmatched selectivity, range and stability. The technology demonstration of the 4 gas Multi-Gas Monitor (MGM), reported at the 2014 ICES conference, operated continuously on the International Space Station (ISS) for nearly a year. The MGM is designed to measure oxygen, carbon dioxide, ammonia and water vapor in ambient cabin air in a low power, relatively compact device. While on board, the MGM experienced a number of challenges, unplanned and planned, including a test of the ammonia channel using a commercial medical ammonia inhalant. Data from the unit was downlinked once per week and compared with other analytical resources on board, notably the Major Constituent Analyzer (MCA), a magnetic sector mass spectrometer. MGM spent the majority of the time installed in the Nanoracks Frame 2 payload facility in front breathing mode (sampling the ambient environment of the Japanese Experiment Module), but was also used to analyze recirculated rack air. The capability of the MGM to be operated in portable mode (via internal rechargeable lithium ion polymer batteries or by plugging into any Express Rack 28VDC connector) was a part of the usability demonstration. Results to date show unprecedented stability and accuracy of the MGM vs. the MCA for oxygen and carbon dioxide. The ammonia challenge (approx. 75 ppm) was successful as well, showing very rapid response time in both directions. Work on an expansion of capability in a next generation MGM has just begun. Combustion products and hydrazine are being added to the measurable target analytes. An 8 to 10 gas monitor (aka Gas Tricorder 1.0) is envisioned for use on ISS, Orion and Exploration missions.

40 CFR 65.2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... approach; (2) Decreased frequency for non-continuous parameter monitoring or physical inspections; (3... stream components, not carbon equivalents. Car-seal means a seal that is placed on a device that is used..., flow inducing devices that transport gas or vapor from an emission point to a control device. A closed...

Low-Cost, Distributed Environmental Monitors for Factory Worker Health

PubMed Central

Thomas, Geb W.; Sousan, Sinan; Tatum, Marcus; Liu, Xiaoxing; Zuidema, Christopher; Fitzpatrick, Mitchell; Koehler, Kirsten A.; Peters, Thomas M.

2018-01-01

An integrated network of environmental monitors was developed to continuously measure several airborne hazards in a manufacturing facility. The monitors integrated low-cost sensors to measure particulate matter, carbon monoxide, ozone and nitrogen dioxide, noise, temperature and humidity. The monitors were developed and tested in situ for three months in several overlapping deployments, before a full cohort of 40 was deployed in a heavy vehicle manufacturing facility for a year of data collection. The monitors collect data from each sensor and report them to a central database every 5 min. The work includes an experimental validation of the particle, gas and noise monitors. The R2 for the particle sensor ranges between 0.98 and 0.99 for particle mass densities up to 300 μg/m3. The R2 for the carbon monoxide sensor is 0.99 for concentrations up to 15 ppm. The R2 for the oxidizing gas sensor is 0.98 over the sensitive range from 20 to 180 ppb. The noise monitor is precise within 1% between 65 and 95 dBA. This work demonstrates the capability of distributed monitoring as a means to examine exposure variability in both space and time, building an important preliminary step towards a new approach for workplace hazard monitoring. PMID:29751534

Industrial chimney monitoring - contemporary methods

NASA Astrophysics Data System (ADS)

Kaszowska, Olga; Gruchlik, Piotr; Mika, Wiesław

2018-04-01

The paper presents knowledge acquired during the monitoring of a flue-gas stack, performed as part of technical and scientific surveillance of mining activity and its impact on industrial objects. The chimney is located in an area impacted by mining activity since the 1970s, from a coal mine which is no longer in existence. In the period of 2013-16, this area was subject to mining carried out by a mining entrepreneur who currently holds a license to excavate hard coal. Periodic measurements of the deflection of the 113-meter chimney are performed using conventional geodetic methods. The GIG used 3 methods to observe the stack: landbased 3D laser scanning, continuous deflection monitoring with a laser sensor, and drone-based visual inspections. The drone offered the possibility to closely inspect the upper sections of the flue-gas stack, which are difficult to see from the ground level.

Diamondoid synthesis in atmospheric pressure adamantane-argon-methane-hydrogen mixtures using a continuous flow plasma microreactor

NASA Astrophysics Data System (ADS)

Stauss, Sven; Ishii, Chikako; Pai, David Z.; Urabe, Keiichiro; Terashima, Kazuo

2014-06-01

Due to their small size, low-power consumption and potential for integration with other devices, microplasmas have been used increasingly for the synthesis of nanomaterials. Here, we have investigated the possibility of using dielectric barrier discharges generated in continuous flow glass microreactors for the synthesis of diamondoids, at temperatures of 300 and 320 K, and applied voltages of 3.2-4.3 kVp-p, at a frequency of 10 kHz. The microplasmas were generated in gas mixtures containing argon, methane, hydrogen and adamantane, which was used as a precursor and seed. The plasmas were monitored by optical emission spectroscopy measurements and the synthesized products were characterized by gas chromatography—mass spectrometry (GC-MS). Depending on the gas composition, the optical emission spectra contained CH and C2 bands of varying intensities. The GC-MS measurements revealed that diamantane can be synthesized by microplasmas generated at atmospheric pressure, and that the yields highly depend on the gas composition and the presence of carbon sources.

Research on calibration method of downhole optical fiber temperature measurement and its application in SAGD well

NASA Astrophysics Data System (ADS)

Lu, Zhiwei; Han, Li; Hu, Chengjun; Pan, Yong; Duan, Shengnan; Wang, Ningbo; Li, Shijian; Nuer, Maimaiti

2017-10-01

With the development of oil and gas fields, the accuracy and quantity requirements of real-time dynamic monitoring data needed for well dynamic analysis and regulation are increasing. Permanent, distributed downhole optical fiber temperature and pressure monitoring and other online real-time continuous data monitoring has become an important data acquisition and transmission technology in digital oil field and intelligent oil field construction. Considering the requirement of dynamic analysis of steam chamber developing state in SAGD horizontal wells in F oil reservoir in Xinjiang oilfield, it is necessary to carry out real-time and continuous temperature monitoring in horizontal section. Based on the study of the principle of optical fiber temperature measurement, the factors that cause the deviation of optical fiber temperature sensing are analyzed, and the method of fiber temperature calibration is proposed to solve the problem of temperature deviation. Field application in three wells showed that it could attain accurate measurement of downhole temperature by temperature correction. The real-time and continuous downhole distributed fiber temperature sensing technology has higher application value in the reservoir management of SAGD horizontal wells. It also has a reference for similar dynamic monitoring in reservoir production.

Rapid monitoring of intermediate states and mass balance of nitrogen during denitrification by means of cavity enhanced Raman multi-gas sensing.

PubMed

Keiner, Robert; Herrmann, Martina; Küsel, Kirsten; Popp, Jürgen; Frosch, Torsten

2015-03-15

The comprehensive investigation of changes in N cycling has been challenging so far due to difficulties with measuring gases such as N2 and N2O simultaneously. In this study we introduce cavity enhanced Raman gas spectroscopy as a new analytical methodology for tracing the stepwise reduction of (15)N-labelled nitrate by the denitrifying bacteria Pseudomonas stutzeri. The unique capabilities of Raman multi-gas analysis enabled real-time, continuous, and non-consumptive quantification of the relevant gases ((14)N2, (14)N2O, O2, and CO2) and to trace the fate of (15)N-labeled nitrate substrate ((15)N2, (15)N2O) added to a P. stutzeri culture with one single measurement. Using this new methodology, we could quantify the kinetics of the formation and degradation for all gaseous compounds (educts and products) and thus study the reaction orders. The gas quantification was complemented with the analysis of nitrate and nitrite concentrations for the online monitoring of the total nitrogen element budget. The simultaneous quantification of all gases also enabled the contactless and sterile online acquisition of the pH changes in the P. stutzeri culture by the stoichiometry of the redox reactions during denitrification and the CO2-bicarbonate equilibrium. Continuous pH monitoring - without the need to insert an electrode into solution - elucidated e.g. an increase in the slope of the pH value coinciding with an accumulation of nitrite, which in turn led to a temporary accumulation of N2O, due to an inhibition of nitrous oxide reductase. Cavity enhanced Raman gas spectroscopy has a high potential for the assessment of denitrification processes and can contribute substantially to our understanding of nitrogen cycling in both natural and agricultural systems. Copyright © 2015 Elsevier B.V. All rights reserved.

Field Test Report: NETL Portable Raman Gas Composition Monitor - Initial Industrial tests at NETL and General Electric (GE)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michael, Buric; Jessica, Mullen; Steven, Woodruff

2012-02-24

NETL has developed new technology which enables the use of Raman spectroscopy in the real-time measurement of gas mixtures. This technology uses a hollow reflective metal-lined capillary waveguide as a gas sampling cell which contains the sample gas, and efficiently collects optical Raman scattering from the gas sample, for measurement with a miniature spectrometer. The result is an optical Raman “fingerprint” for each gas which is tens or hundreds of times larger than that which can be collected with conventional free-space optics. In this manner, the new technology exhibits a combination of measurement speed and accuracy which is unprecedented formore » spontaneous Raman measurements of gases. This makes the system especially well-suited to gas turbine engine control based on a-priori measurement of incoming fuel composition. The system has been developed to produce a measurement of all of the common components of natural gas, including the lesser nitrogen, oxygen, carbon-dioxide, and carbon monoxide diluents to better than 1% concentration accuracy each second. The objective of this task under CRADA 10-N100 was to evaluate the capability of a laser Raman capillary gas sensor for combustion fuels. A portable version of the Raman gas sensor, constructed at NETL, was used for field-trials conducted in a cooperative research effort at a GE facility. Testing under the CRADA was performed in 5 parts. Parts 1-4 were successful in testing of the Raman Gas Composition Monitor with bottled calibration gases, and in continuous monitoring of several gas streams at low pressure, in comparison with an online mass spectrometer. In part 5, the Raman Gas Composition Monitor was moved outdoors for testing with high pressure gas supplies. Some difficulties were encountered during industrial testing including the condensation of heavy hydrocarbons inside the sample cell (in part 5), communication with the GE data collection system, as well as some drift in the optical noise background. The difficulties with liquid contaminants will be overcome through the use of prodigious sample-cell heating and additional line filtration including liquid ingress-protection. The communication problem was resolved through site-specific troubleshooting of the MODBUS data tags.« less

40 CFR 75.57 - General recordkeeping provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... stack gas (percent H2O, rounded to the nearest tenth). If the continuous moisture monitoring system... record daily the following information for CO2 mass emissions: (i) Date; (ii) Daily combustion-formed CO2... whether optional procedure to adjust combustion-formed CO2 mass emissions for carbon retained in flyash...

40 CFR 75.57 - General recordkeeping provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... stack gas (percent H2O, rounded to the nearest tenth). If the continuous moisture monitoring system... record daily the following information for CO2 mass emissions: (i) Date; (ii) Daily combustion-formed CO2... whether optional procedure to adjust combustion-formed CO2 mass emissions for carbon retained in flyash...

40 CFR 75.57 - General recordkeeping provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... stack gas (percent H2O, rounded to the nearest tenth). If the continuous moisture monitoring system... record daily the following information for CO2 mass emissions: (i) Date; (ii) Daily combustion-formed CO2... whether optional procedure to adjust combustion-formed CO2 mass emissions for carbon retained in flyash...

40 CFR 75.57 - General recordkeeping provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... stack gas (percent H2O, rounded to the nearest tenth). If the continuous moisture monitoring system... record daily the following information for CO2 mass emissions: (i) Date; (ii) Daily combustion-formed CO2... whether optional procedure to adjust combustion-formed CO2 mass emissions for carbon retained in flyash...

40 CFR 60.1885 - What must I include in my annual report?

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitoring system (§ 60.1850(a)(1)). (d) For municipal waste combustion units that use activated carbon for... diluent gas, documentation of the relationship between oxygen and carbon dioxide, as specified in § 60...? 60.1885 Section 60.1885 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...

40 CFR 60.1885 - What must I include in my annual report?

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitoring system (§ 60.1850(a)(1)). (d) For municipal waste combustion units that use activated carbon for... diluent gas, documentation of the relationship between oxygen and carbon dioxide, as specified in § 60...? 60.1885 Section 60.1885 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...

40 CFR 60.1885 - What must I include in my annual report?

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitoring system (§ 60.1850(a)(1)). (d) For municipal waste combustion units that use activated carbon for... diluent gas, documentation of the relationship between oxygen and carbon dioxide, as specified in § 60...? 60.1885 Section 60.1885 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...

Sourcing methane and carbon dioxide emissions from a small city: Influence of natural gas leakage and combustion.

PubMed

Chamberlain, Samuel D; Ingraffea, Anthony R; Sparks, Jed P

2016-11-01

Natural gas leakage and combustion are major sources of methane (CH 4 ) and carbon dioxide (CO 2 ), respectively; however, our understanding of emissions from cities is limited. We mapped distribution pipeline leakage using a mobile CH 4 detection system, and continuously monitored atmospheric CO 2 and CH 4 concentrations and carbon isotopes (δ 13 C-CO 2 and δ 13 C-CH 4 ) for one-year above Ithaca, New York. Pipeline leakage rates were low (<0.39 leaks mile -1 ), likely due to the small extent of cast iron and bare steel within the distribution pipeline system (2.6%). Our atmospheric monitoring demonstrated that the isotopic composition of locally emitted CO 2 approached the δ 13 C range of natural gas combustion in winter, correlating to natural gas power generation patterns at Cornell's Combined Heat and Power Plant located 600 m southeast of the monitoring site. Atmospheric CH 4 plumes were primarily of natural gas origin, were observed intermittently throughout the year, and were most frequent in winter and spring. No correlations between the timing of atmospheric natural gas CH 4 plumes and Cornell Plant gas use patterns could be drawn. However, elevated CH 4 and CO 2 concentrations were observed coincident with high winds from the southeast, and the plant is the only major emission source in that wind sector. Our results demonstrate pipeline leakage rates are low in cities with a low extent of leak prone pipe, and natural gas power facilities may be an important source of urban and suburban emissions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Field studies: Test method for on-line continuous measurement of total hydrocarbons (THC) and non-methane hydrocarbons (NMHC) in stack gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsiao, H.H.; Lai, C.C.; Chu, H.W.

A new method for on-line monitoring of total hydrocarbons and non-methane hydrocarbons in stack gas simultaneously was developed in this study. Based on the principle of on-line GC/FID, the method was developed and can be considered as a new modification of the Method 25 and 25A of US EPA. Major advantages of the method included (1) capability of distinguishing methane as Method 25; (2) near-real-time results; (3) broad species coverage; (4) monitoring methane in straightforward manner; (5) low operation and maintenance costs. In the proposed method, test samples were continuously pumped from detection sources and loaded with a two-loop samplingmore » valve. The samples were then injected into two GC columns-empty and molecular sieve columns. The empty column was used for detection of THC, and the molecular sieve column was for methane. The detector in this GC was FID. NMHC concentration was obtained by subtracting methane from THC. The tests were carried out to measure the THC and methane in waste gas in various industries, including surface coating, semiconductor manufacturing, synthetic leather industries. Recovery rates of THC in the samples were between 86% to 114% for about 100 m of transfer line of samples. For the standard gas, the recovery rate was about 101%, 6.6 % of measurement precision, and 88%--114% of accuracy. The results showed the promising and reliable measurement of the test method for THC and methane in waste gas.« less

Snowpack Chemistry of Reactive Gases at Station Concordia, Antarctica

NASA Astrophysics Data System (ADS)

Helmig, Detlev; Mass, Alex; Hueber, Jacques; Fain, Xavier; Dommergue, Aurelien; Barbero, Albane; Savarino, Joel

2013-04-01

During December 2012 a new experiment for the study of snow photochemical processes and surface gas exchange was installed at Dome Concordia, Antarctica. The experiment consists of two sampling manifolds ('snow tower') which facilitate the withdrawal of interstitial firn air from four depths in the snowpack and from above the surface. One of these snow towers can be shaded for investigation of the dependency of snow chemistry on solar radiation. A nearby 12 m meteorological tower facilitates above surface turbulence and trace gas gradient measurements. Temperature profiles and UV and IR light penetration are monitored in the snowpack. Air samples are directed through sampling lines to a nearby underground laboratory that houses the experiment control system and gas monitors. The system is fully automated, sampling gases from the array of inlet ports sequentially, and is intended to be operated continuously for a full annual cycle. The computerized control system can be accessed remotely for data retrieval and quality control and for configuring experimental details. Continuous gas measurements include ozone, nitrogen oxides, methane, carbon monoxide, and gaseous elemental mercury. Whole air samples were sampled on four occasions for volatile organic compound analysis. The objective of this research is the study of the year-round snowpack gas chemistry and its dependency on snowpack and above surface physical and environmental conditions. A particular emphasis will be the investigation of the effects of increased UV radiation during the occurrence of the stratospheric ozone hole. We will present the conceptual design of the experiment and data examples from the first three months of the experiment.

No vintage year ahead, but it will be better than '89

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garb, F.A.

1989-12-01

Activities in the upstream petroleum industry react to prices received for hydrocarbons and related products. Prices, in turn, are the result of supply, demand, politics and emotions. The author presents a forecast of 1990 oil industry activities and reviews the status of the pressures establishing oil and gas. According to this analysis, 1990 should be the first of a series of transition years. Oil and gas prices should be more stable than in the past. It will not be good drilling year, but will not be as bad as 1989. Gas exploration will again dominate exploration drilling. Development drilling willmore » account for more wells, if not for more budget dollars than exploration, with horizontal drilling developments being monitored closely industry-wide. Consolidation of mature producing properties into independent oil companies will continue. Decline in domestic production and an increase in hydrocarbon use and in imports should continue.« less

Gasometer: An inexpensive device for continuous monitoring of dissolved gases and supersaturation

USGS Publications Warehouse

Bouck, G.R.

1982-01-01

The “gasometer” is a device that measures differential dissolved-gas pressures (δP) in water relative to barometric pressure (as does the “Weiss saturometer”), but operates continuously without human attention. The gasometer can be plumbed into a water-supply system and requires 8 liters/minute of water or more at 60 kilopascals. The gasometer's surfaces are nontoxic, and flow-through water can be used for fish culture. The gasometer may be connected to a small submersible pump and operated as a portable unit. The gasometer can activate an alarm system and thus protect fish from hyperbaric (supersaturation) or hypobaric gas pressures (usually due to low dissolved oxygen). Instructions are included for calculating and reporting data including the pressure and saturation of individual gases. Construction and performance standards are given for the gasometer. Occasional cleaning is required to remove biofouling from the gas-permeable tubing.PDF

Microwave plasma monitoring system for the elemental composition analysis of high temperature process streams

DOEpatents

Woskov, Paul P.; Cohn, Daniel R.; Titus, Charles H.; Surma, Jeffrey E.

1997-01-01

Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, high temperature capability refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury. The invention may be incorporated into a high temperature process device and implemented in situ for example, such as with a DC graphite electrode plasma arc furnace. The invention further provides a system for the elemental analysis of process streams by removing particulate and/or droplet samples therefrom and entraining such samples in the gas flow which passes through the plasma flame. Introduction of and entraining samples in the gas flow may be facilitated by a suction pump, regulating gas flow, gravity or combinations thereof.

On-Site Detection as a Countermeasure to Chemical Warfare/Terrorism.

PubMed

Seto, Y

2014-01-01

On-site monitoring and detection are necessary in the crisis and consequence management of wars and terrorism involving chemical warfare agents (CWAs) such as sarin. The analytical performance required for on-site detection is mainly determined by the fatal vapor concentration and volatility of the CWAs involved. The analytical performance for presently available on-site technologies and commercially available on-site equipment for detecting CWAs interpreted and compared in this review include: classical manual methods, photometric methods, ion mobile spectrometry, vibrational spectrometry, gas chromatography, mass spectrometry, sensors, and other methods. Some of the data evaluated were obtained from our experiments using authentic CWAs. We concluded that (a) no technologies perfectly fulfill all of the on-site detection requirements and (b) adequate on-site detection requires (i) a combination of the monitoring-tape method and ion-mobility spectrometry for point detection and (ii) a combination of the monitoring-tape method, atmospheric pressure chemical ionization mass spectrometry with counterflow introduction, and gas chromatography with a trap and special detectors for continuous monitoring. The basic properties of CWAs, the concept of on-site detection, and the sarin gas attacks in Japan as well as the forensic investigations thereof, are also explicated in this article. Copyright © 2014 Central Police University.

Direct monitoring of wind-induced pressure-pumping on gas transport in soil

NASA Astrophysics Data System (ADS)

Laemmel, Thomas; Mohr, Manuel; Schindler, Dirk; Schack-Kirchner, Helmer; Maier, Martin

2017-04-01

Gas exchange between soil and atmosphere is important for the biogeochemistry of soils and is commonly assumed to be governed by molecular diffusion. Yet a few previous field studies identified other gas transport processes such as wind-induced pressure-pumping to enhance soil-atmosphere fluxes significantly. However, since these wind-induced non-diffusive gas transport processes in soil often occur intermittently, the quantification of their contribution to soil gas emissions is challenging. To quantify the effects of wind-induced pressure-pumping on soil gas transport, we developed a method for in situ monitoring of soil gas transport. The method includes the use of Helium (He) as a tracer gas which was continuously injected into the soil. The resulting He steady-state concentration profile was monitored. Gas transport parameters of the soil were inversely modelled. We used our method during a field campaign in a well-aerated forest soil over three months. During periods of low wind speed, soil gas transport was modelled assuming diffusion as transport process. During periods of high wind speed, the previously steady diffusive He concentration profile showed temporary concentration decreases in the topsoil, indicating an increase of the effective gas transport rate in the topsoil up to 30%. The enhancement of effective topsoil soil gas diffusivity resulted from wind-induced air pressure fluctuations which are referred to as pressure-pumping. These air pressure fluctuations had frequencies between 0.1 and 0.01 Hz and amplitudes up to 10 Pa and occurred at above-canopy wind speeds greater than 5 m s-1. We could show the importance of the enhancement of the gas transport rate in relation with the wind intensity and corresponding air pressure fluctuations characteristics. We directly detected and quantified the pressure-pumping effect on gas transport in soil in a field study for the first time, and could thus validate and underpin the importance of this non-diffusive gas transport process. Our method can also be used to study other non-diffusive gas transport processes occurring in soil and snow, and their possible feedbacks or interactions with biogeochemical processes.

Automated gas chromatography

DOEpatents

Mowry, C.D.; Blair, D.S.; Rodacy, P.J.; Reber, S.D.

1999-07-13

An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute. 7 figs.

Automated gas chromatography

DOEpatents

Mowry, Curtis D.; Blair, Dianna S.; Rodacy, Philip J.; Reber, Stephen D.

1999-01-01

An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute.

Hg0 and HgCl2 Reference Gas Standards: ?NIST Traceability ...

EPA Pesticide Factsheets

EPA and NIST have collaborated to establish the necessary procedures for establishing the required NIST traceability of commercially-provided Hg0 and HgCl2 reference generators. This presentation will discuss the approach of a joint EPA/NIST study to accurately quantify the true concentrations of Hg0 and HgCl2 reference gases produced from high quality, NIST-traceable, commercial Hg0 and HgCl2 generators. This presentation will also discuss the availability of HCl and Hg0 compressed reference gas standards as a result of EPA's recently approved Alternative Methods 114 and 118. Gaseous elemental mercury (Hg0) and oxidized mercury (HgCl2) reference standards are integral to the use of mercury continuous emissions monitoring systems (Hg CEMS) for regulatory compliance emissions monitoring. However, a quantitative disparity of approximately 7-10% has been observed between commercial Hg0 and HgCl2 reference gases which currently limits the use of (HgCl2) reference gas standards. Resolving this disparity would enable the expanded use of (HgCl2) reference gas standards for regulatory compliance purposes.

Current and emerging laser sensors for greenhouse gas sensing and leak detection

NASA Astrophysics Data System (ADS)

Frish, Michael B.

2014-05-01

To reduce atmospheric accumulation of the greenhouse gases methane and carbon dioxide, networks of continuously operating sensors that monitor and map their sources are desirable. In this paper, we discuss advances in laser-based open-path leak detectors, as well as technical and economic challenges inhibiting widespread sensor deployment for "ubiquitous monitoring". We describe permanently-installed, wireless, solar-powered sensors that overcome previous installation and maintenance difficulties while providing autonomous real-time leak reporting without false alarms.

Continuous glucose monitoring on the ICU using a subcutaneous sensor.

PubMed

Punke, M A; Decker, C; Wodack, K; Reuter, D A; Kluge, S

2015-06-01

Hypoglycemia is a frequent and feared complication of insulin therapy on the intensive care unit (ICU). Sedated patients in particular are at risk for hypoglycemia due to the absence of clinical symptoms. Furthermore, recent studies point to a correlation between the variability of blood glucose and mortality. Therefore, continuous glucose monitoring has the potential to influence outcome due to a better control of blood glucose in critically ill patients. We evaluated the efficacy, accuracy and safety of a new commercially available subcutaneous continuous glucose monitoring system (sCGM; Sentrino®, Medtronic) in a pilot study in critically ill adult patients. sCGM data were recorded for up to 72 h and values were compared with blood glucose values measured by cassette-based blood gas analyzer (BGA). A total of 14 patients (eight male, six female), with a mean age of 62.1 ± 9.8 years, referred to the ICU after major abdominal surgery were studied. The average simplified acute physiology score (SAPS II) was 35 ± 9. Three patients had known type II diabetes. The average runtime of sensors was 44.1 ± 22.1 h. In comparison to BGA, measurement of blood glucose by sCGM revealed an accuracy of 1.5 mg/dl, and a precision of +34.2 mg/dl to -31.2 mg/dl. Linn's concordance correlation coefficient yielded 0.74 with a 95% confidence interval of 0.68-0.78. No hypoglycemic events, defined as a blood glucose level below 70 mg/dl, occurred during treatment. sCGM monitoring via a subcutaneous sensor demonstrated high accuracy and considerable variability compared to blood gas samples, even in critically ill patients.

Continuous time-resolved regional methane leak detection with on-line background estimation using a novel combination of dual frequency comb laser spectroscopy and atmospheric inversions

NASA Astrophysics Data System (ADS)

Alden, C. B.; Coburn, S.; Wright, R.; Baumann, E.; Cossel, K.; Sweeney, C.; Ghosh, S.; Newbury, N.; Prasad, K.; Coddington, I.; Rieker, G. B.

2017-12-01

Advances in natural gas extraction technology have led to increased US production and transport activity, and as a consequence, an increased need for monitoring of methane leaks. Current leak detection methods provide time snapshots, and not continuous, time-varying estimates of emissions. Most approaches also require specific atmospheric conditions, operators, or the use of a tracer gas, requiring site access. Given known intermittency in fugitive methane emissions, continuous monitoring is a critical need for emissions mitigation. We present a novel leak detection method that employs dual frequency comb spectrometry to offer continuous, autonomous, leak detection and quantification over square-km scale areas. The spectrometer is situated in a field of natural gas pads, and a series of retroreflectors around the field direct light back to a detector. The laser light spans 1620-1680 nm with 0.002 nm line spacing, measuring thousands of individual absorption features from multiple species. The result is high-stability trace gas (here CH4, CO2, and H2O) measurements over long (1 km+) open paths through the atmosphere. Measurements are used in an atmospheric inversion to estimate the time variability of emissions at each location of interest. Importantly, the measurement framework and inversion solve explicitly for background concentrations, which vary rapidly in fields of active oil and gas production. We present the results of controlled-leak field tests in rural Colorado. We demonstrate the ability to locate and size a leak located 1 km away from the spectrometer and varying in strength from 1.5 to 7.7 g/min, resulting in mean atmospheric enhancements of 20 ppb. The inversion correctly identifies when the leak turned on and off over a 24-hour period, and determines the mean leak strength to within 10% of the true controlled rate. We further demonstrate the ability of the system to correctly locate and size the start and end of simultaneous 2.7 to 4.8 g/min leaks from 2 sources in a field of 5 potential leak locations. Finally, we present the results of leak-detection tests in active oil and gas fields in the Denver Julesburg Basin, where background methane is complex.

40 CFR 63.11395 - What are the standards and compliance requirements for existing sources?

Code of Federal Regulations, 2013 CFR

2013-07-01

... routine and long-term maintenance) and continuous monitoring system. (4) A list of operating parameters... polymerization process equipment and monomer recovery process equipment and convey the collected gas stream.... (2) 0.05 lb/hr of AN from the control device for monomer recovery process equipment. (3) If you do...

40 CFR 63.11395 - What are the standards and compliance requirements for existing sources?

Code of Federal Regulations, 2012 CFR

2012-07-01

... routine and long-term maintenance) and continuous monitoring system. (4) A list of operating parameters... polymerization process equipment and monomer recovery process equipment and convey the collected gas stream.... (2) 0.05 lb/hr of AN from the control device for monomer recovery process equipment. (3) If you do...

40 CFR 63.11395 - What are the standards and compliance requirements for existing sources?

Code of Federal Regulations, 2014 CFR

2014-07-01

... routine and long-term maintenance) and continuous monitoring system. (4) A list of operating parameters... polymerization process equipment and monomer recovery process equipment and convey the collected gas stream.... (2) 0.05 lb/hr of AN from the control device for monomer recovery process equipment. (3) If you do...

THE EFFECT OF OPENING WINDOWS ON AIR CHANGE RATES IN TWO HOMES

EPA Science Inventory

Over 300 air change rate experiments were completed in two occupied residences: a two-story detached house in Redwood City, CA and a three-story townhouse in Reston, VA. A continuous monitor was used to measure the decay of sulfur hexafluoride tracer gas over periods of 1 to 1...

Continuous non-invasive end-tidal CO2 monitoring in pediatric inpatients with diabetic ketoacidosis.

PubMed

Agus, Michael S D; Alexander, Jamin L; Mantell, Patricia A

2006-08-01

Pediatric inpatients with diabetic ketoacidosis (DKA) are routinely subjected to frequent blood draws in order to closely monitor degree of acidosis and response to therapy. The typical level of acidosis monitoring is less than ideal, however, because of the high cost and invasiveness of frequent blood labs. Previous studies have validated end-tidal carbon dioxide (EtCO2) monitoring in the emergency department (ED) for varying periods of time. We extend these findings to the inpatient portion of the hospitalization during which the majority of blood tests are sent. All patients admitted to an intermediate care unit in (InCU) a large children's hospital were fitted with an appropriately sized oral/nasal cannula capable of sensing EtCO2. Laboratory studies were obtained according to hospital clinical practice guidelines. In a retrospective analysis, EtCO2 values were correlated with serum total CO2 (stCO2), venous pH (vpH), venous pCO2 (vpCO2), and calculated bicarbonate from venous blood gas (vHCO3-). A total of 78 consecutive episodes of DKA in 72 patients aged 1-21 yr were monitored for 3-38 h with both capnography and laboratory testing, producing 334 comparisons. Initial values were as follows, reported as median (range): stCO2, 11 (4-22) mmol/L; vpH, 7.281 (6.998-7.441); vpCO2, 28.85 (9.3-43.3) mmHg; and vHCO3-, 14 (3-25) mmol/L. EtCO2 was correlated well with stCO2 (r = 0.84, p < 0.001), vHCO3- (r = 0.84, p < 0.001), and vpCO2 (r = 0.79, p < 0.001). These data support the findings of previous studies limited to ED populations and suggest that non-invasive EtCO2 monitoring is a valuable and reliable tool to continuously follow acidosis in the setting of the acutely ill pediatric patient with DKA. Continuous EtCO2 monitoring offers the practitioner an early warning system for unexpected changes in acidosis that augments the utility of intermittent blood gas determinations.

Optical Multi-Gas Monitor Technology Demonstration on the International Space Station

NASA Technical Reports Server (NTRS)

Pilgrim, Jeffrey S.; Wood, William R.; Casias, Miguel E.; Vakhtin, Andrei B,; Johnson, Michael D.; Mudgett, Paul D.

2014-01-01

There are a variety of both portable and fixed gas monitors onboard the International Space Station (ISS). Devices range from rack-mounted mass spectrometers to hand-held electrochemical sensors. An optical Multi-Gas Monitor has been developed as an ISS Technology Demonstration to evaluate long-term continuous measurement of 4 gases. Based on tunable diode laser spectroscopy, this technology offers unprecedented selectivity, concentration range, precision, and calibration stability. The monitor utilizes the combination of high performance laser absorption spectroscopy with a rugged optical path length enhancement cell that is nearly impossible to misalign. The enhancement cell serves simultaneously as the measurement sampling cell for multiple laser channels operating within a common measurement volume. Four laser diode based detection channels allow quantitative determination of ISS cabin concentrations of water vapor (humidity), carbon dioxide, ammonia and oxygen. Each channel utilizes a separate vertical cavity surface emitting laser (VCSEL) at a different wavelength. In addition to measuring major air constituents in their relevant ranges, the multiple gas monitor provides real time quantitative gaseous ammonia measurements between 5 and 20,000 parts-per-million (ppm). A small ventilation fan draws air with no pumps or valves into the enclosure in which analysis occurs. Power draw is only about 3 W from USB sources when installed in Nanoracks or when connected to 28V source from any EXPRESS rack interface. Internal battery power can run the sensor for over 20 hours during portable operation. The sensor is controlled digitally with an FPGA/microcontroller architecture that stores data internally while displaying running average measurements on an LCD screen and interfacing with the rack or laptop via USB. Design, construction and certification of the Multi-Gas Monitor were a joint effort between Vista Photonics, Nanoracks and NASA-Johnson Space Center (JSC). Vista Photonics developed the core technology and built the sensor. Nanoracks designed, constructed the enclosure, interfaces, and battery power management circuitry, integrated all subsystems into the enclosure, and then managed the certification tests, documentation and manifesting. The unit was calibrated in the JSC Toxicology Laboratory. The Multi-Gas Monitor is manifested to fly as a technology demonstration to the ISS in November 2013 and will operate for at least 6 months with data sent to the ground for evaluation. The primary goal is to demonstrate long term interference free operation in the real spacecraft environment.

Results of a Long-Term Demonstration of an Optical Multi-Gas Monitor on ISS

NASA Technical Reports Server (NTRS)

Mudgett, Paul; Pilgrim, Jeffrey S.

2015-01-01

Previously at SAMAP we reported on the development of tunable diode laser spectroscopy (TDLS) based instruments for measuring small gas molecules in real time. TDLS technology has matured rapidly over the last 5 years as a result of advances in low power diode lasers as well as better detection schemes. In collaboration with two small businesses Vista Photonics, Inc. and Nanoracks LLC, NASA developed a 4 gas TDLS based monitor for an experimental demonstration of the technology on the International Space Station (ISS). Vista invented and constructed the core TDLS sensor. Nanoracks designed and built the enclosure, and certified the integrated monitor as a payload. The device, which measures oxygen, carbon dioxide, ammonia and water vapor, is called the Multi-Gas Monitor (MGM). MGM measures the 4 gases every few seconds and records a 30 second moving average of the concentrations. The relatively small unit draws only 2.5W. MGM was calibrated at NASA-Johnson Space Center in July 2013 and launched to ISS on a Soyuz vehicle in November 2013. Installation and activation of MGM occurred in February 2014, and the unit has been operating nearly continuously ever since in the Japanese Experiment Module. Data is downlinked from ISS about once per week. Oxygen and carbon dioxide data is compared with that from the central Major Constituents Analyzer. Water vapor data is compared with dew point measurements made by sensors in the Columbus module. The ammonia channel was tested by the crew using a commercial ammonia inhalant. MGM is remarkably stable to date. Results of 18 months of operation are presented and future applications including combustion product monitoring are discussed.

Monitoring fluidized bed drying of pharmaceutical granules.

PubMed

Briens, Lauren; Bojarra, Megan

2010-12-01

Placebo granules consisting of lactose monohydrate, corn starch, and polyvinylpyrrolidone were prepared using de-ionized water in a high-shear mixer and dried in a conical fluidized bed dryer at various superficial gas velocities. Acoustic, vibration, and pressure data obtained over the course of drying was analyzed using various statistical, frequency, fractal, and chaos techniques. Traditional monitoring methods were also used for reference. Analysis of the vibration data showed that the acceleration levels decreased during drying and reached a plateau once the granules had reached a final moisture content of 1–2 wt.%; this plateau did not differ significantly between superficial gas velocities, indicating a potential criterion to support drying endpoint identification. Acoustic emissions could not reliably identify the drying endpoint. However, high kurtosis values of acoustic emissions measured in the filtered air exhaust corresponded to high entrainment rates. This could be used for process control to adjust the fluidization gas velocity to allow drying to continue rapidly while minimizing entrainment and possible product losses.

Public health assessment for waste management of Wisconsin-Brookfield, Brookfield, Waukesha County, Wisconsin, Region 5. Cerclis No. WID980901235. Preliminary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-01-14

The Waste Management-Brookfield Landfill was a former gravel pit used to dispose of municipal, commercial, and industrial wastes. Methane gas migration has been a problem at the site in the past. A gas extraction system was installed within the landfill. Gas probes that measure total combustible gas have also been installed on site. Continuous methane/combustible gas monitors were placed in two residential basements; relatively high levels of gas were measured in one residence in 1985. Groundwater beneath the site has been contaminated from the site. The landfill does not have a liner. Waste Management has constructed a new clay capmore » that is well vegetated and maintained regularly. The site poses an indeterminate public health hazard from inhalation exposure to contaminated indoor air migrating into the basements of nearby residences.« less

Impacts of gas drilling on human and animal health.

PubMed

Bamberger, Michelle; Oswald, Robert E

2012-01-01

Environmental concerns surrounding drilling for gas are intense due to expansion of shale gas drilling operations. Controversy surrounding the impact of drilling on air and water quality has pitted industry and lease-holders against individuals and groups concerned with environmental protection and public health. Because animals often are exposed continually to air, soil, and groundwater and have more frequent reproductive cycles, animals can be used as sentinels to monitor impacts to human health. This study involved interviews with animal owners who live near gas drilling operations. The findings illustrate which aspects of the drilling process may lead to health problems and suggest modifications that would lessen but not eliminate impacts. Complete evidence regarding health impacts of gas drilling cannot be obtained due to incomplete testing and disclosure of chemicals, and nondisclosure agreements. Without rigorous scientific studies, the gas drilling boom sweeping the world will remain an uncontrolled health experiment on an enormous scale.

Controlled assembly of organic whispering-gallery-mode microlasers as highly sensitive chemical vapor sensors.

PubMed

Gao, Miaomiao; Wei, Cong; Lin, Xianqing; Liu, Yuan; Hu, Fengqin; Zhao, Yong Sheng

2017-03-09

We demonstrate the fabrication of organic high Q active whispering-gallery-mode (WGM) resonators from π-conjugated polymer by a controlled emulsion-solvent-evaporation method, which can simultaneously provide optical gain and act as an effective resonant cavity. By measuring the shift of their lasing modes on exposure to organic vapor, we successfully monitored the slight concentration variation in the chemical gas. These microlaser sensors demonstrated high detection sensitivity and good signal repeatability under continuous chemical gas treatments. The results offer an effective strategy to design miniaturized optical sensors.

A new device for continuous monitoring the CO2 dissolved in water

NASA Astrophysics Data System (ADS)

de Gregorio, S.; Camarda, M.; Cappuzzo, S.; Giudice, G.; Gurrieri, S.; Longo, M.

2009-04-01

The measurements of dissolved CO2 in water are common elements of industrial processes and scientific research. In order to perform gas dissolved measurements is required to separate the dissolved gaseous phase from water. We developed a new device able to separate the gases phase directly in situ and well suitable for continuous measuring the CO2 dissolved in water. The device is made by a probe of a polytetrafluorethylene (PTFE) tube connected to an I.R. spectrophotometer (I.R.) and a pump. The PTFE is a polymeric semi-permeable membrane and allows the permeation of gas in the system. Hence, this part of the device is dipped in water in order to equilibrate the probe headspace with the dissolved gases. The partial pressure of the gas i in the headspace at equilibrium (Pi) follows the Henry's law: Pi=Hi•Ci, where Hi is the Henry's constant and Ci is the dissolved concentration of gas i. After the equilibrium is achieved, the partial pressure of CO2 inside the tube is equal to the partial pressure of dissolved CO2. The concentration of CO2 is measured by the I.R. connected to the tube. The gas is moved from the tube headspace to the I.R. by using the pump. In order to test the device and assess the best operating condition, several experimental were performed in laboratory. All the test were executed in a special apparatus where was feasible to create controlled atmospheres. Afterward the device has been placed in a draining tunnel sited in the Mt. Etna Volcano edifice (Italy). The monitored groundwater intercepts the Pernicana Fault, along which degassing phenomena are often observed. The values recorded by the station result in agreement with monthly directly measurements of dissolved CO2 partial pressure.

Recent observations of carbon and sulfur gas emissions from Tavurvur, Bagana and Ulawun (Papua New Guinea) with a combination of ground- and air-borne direct and remote sensing techniques

NASA Astrophysics Data System (ADS)

Arellano, Santiago; Galle, Bo; Mulina, Kila; Wallius, Julia; McCormick, Brendan; Salem, Lois; D'aleo, Roberto; Itikarai, Ima; Tirpitz, Lukas; Bobrowski, Nicole; Aiuppa, Alessandro

2017-04-01

Satellite observations reveal that volcanoes from Papua New Guinea contributed with ca. 15{%} of the global emission of volcanic sulfur dioxide (SO2) during the period 2005-2014. Relatively little is known about their carbon dioxide (CO2) outputs and more recent levels and dynamics of degassing activity. During September 2016 we conducted measurements of the CO2/SO2 ratio and the SO2 flux from Tavurvur, Bagana and Ulawun volcanoes using a combination of remote sensing and direct sampling techniques. Tavurvur exhibits low-level passive degassing from a modestly active vent and few other intra-crater fumaroles, which made access possible for direct measurements of the CO2/SO2 ratio with a compact Multi-GAS instrument. A wide-field of view pointing DOAS monitor was deployed for longer term monitoring of the SO2 flux from a distance of about 2 km. Bagana degasses continuously with occasional emissions of ash, and its SO2 flux, plume velocity and height was constrained by simultaneous scanning and dual-beam DOAS measurements. Molar ratios in the plume of Bagana were measured by the compact Multi-GAS aboard a multi-rotor UAV, up to a height of 1.6 km above ground. Ulawun showed continuous passive degassing and measurements with the UAV, up to an altitude of ca. 1.8 km, and mobile-DOAS traverses from a car were used to constrain its gas emission. Here we present an overview of the challenging conditions, measurement strategies and results of this campaign that forms part of the ongoing international effort DECADE aiming to better quantify the global gas emission of carbon- and sulfur containing species from volcanoes.

The utilization of the microflora indigenous to and present in oil-bearing formations to selectively plug the more porous zones thereby increasing oil recovery during waterflooding. Sixteenth quarterly progress report, October 1--December 31, 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, L.R.; Vadie, A.A.

1998-01-20

There are ten injection wells receiving nutrients and twenty producing wells in test patterns are being monitoring for responses. Petrophysical studies of recovered core sample from the 3 newly drilled wells are still in progress. Monthly collection of produced fluids from the test and control wells in all patterns continued with the following tasks being performed: aliphatic profile (gas chromatographic analysis); API gravity and absolute viscosity under reservoir temperature; pH of produced water; surface tension (ST) of produced water (water-air); interfacial tension (IFT) for produced oil-water system; microbiological population; and inorganic analyses (nitrate, phosphate, sulfate, sulfide, chloride, potassium, and hardness).more » Production data on all wells in all patterns continues to be evaluated. Increased gas production that has been noted in some wells could be the result of microbial activity or from previous unswept areas of the reservoir. Samples of gas were collected from selected production wells and analyzed by gas chromatography using a Fisher Model No. 12 Gas Partitioner. The results of analyses from four sets of samples are given.« less

New experience in atmospheric monitoring in Moscow city on the base of WSN technology

NASA Astrophysics Data System (ADS)

Asavin, Alex; Litvinov, Artur; Baskakov, Sergey; Chesalova, Elena

2016-04-01

The aim of this report is to present the gas emission of H2 in the general composition of atmospheric pollution of Moscow city. We start the project at the beginning of 2015 year in two Moscow academicals organization -Vernadsky Institute of Geochemistry and Analytical Chemistry and Moscow Geological State Museum. One place is in the center of Moscow, near the Kremlin and other one is in the most clear zone of Moscow - Moscow State University place, Vorobyevy Mountains (high point of Moscow). We plan to compare these regions by the concentration of H2 and other gases (CH4, SO2) for green gas pollution. Application network of monitoring is composed of gas sensors (H2, CH4), complex autonomous equipment for measurement temperature, pressure, humidity and network of telecommunications (used ZigBee protocol). Our project offer the technical solutions for monitoring network on the base of WSN (wireless sensor network) technology and the high-sensitive sensors of hydrogen and methane, software and electronic equipment with a transmitter network. This work is the first project in Russia. Gas sensors for monitoring system were developed on the base of MIS-structures (metal-insulator-semiconductor). MIS-sensors are suitable for measuring the concentrations of the following gases: hydrogen, hydrogen sulphide, nitrogen dioxide, ethylmercaptan, chlorine and ammonia. The basis of the sensor is MIS - structure Pd-Ta2O5-SiO2-Si,), which capacitance changes when reaction with gases occurs. The sensor fabrication technology is based on the microelectronics device fabrication technologies and the thin film laser deposition technique. Sensor can be used for measuring the concentration of any gas among noted before, in ambient temperature range -30..+40°C and RH 30-90% (30°C).Three gas sensors with analog interface were made for our experimental monitoring system. Original calibration was made using calibration by special standard mixture of H2 and atmosphere. There are 10-15 points on the each calibration graphics with different H2 concentration in standard gas mixtures. The graphics represent the power functions. The accuracy of the approximating functions is 3-18 %. At low concentrations (H2 <3 ppm) - error is rather high (about 20%).So we think that 2 ppm is the low limit of measurement. The essential factor is a temperature drift. We estimate this drift as 20mV per 1 degree and make corrections, because measurements were made in wide temperature range (+29 - -20 C). To take this factor we added our network by meteorological sensors. Each sensor network node has a radio transceiver with an internal antenna or connection to an external antenna, a microcontroller, an electronic circuit for interfacing with the sensors and an energy source, usually a battery or an embedded form of energy harvesting. All nodes are equal and serve as routers, so there is no need to plan nodes placement in advance Mesh Network protocol. Every node maintains a local routing table with information about one or several neighbors. The signal transmission between nodes and router used radio channel 2.6 GHz. Communication between router and IT server used two methods: cable RS486 and GPRS modem. GPRS connection is unstable and influence on operating stability. There are some problems in using of directional antenna because of the high level of city's radio noises and radio interferences. Nevertheless, a number of experiments with use of different technical solutions allowed us to perform continuous monitoring during 2 months. As a result about 3 million data records were obtained during experimental works. This information provided an opportunity to develop the structure of database management systems to store data and the technology of online data collection from remote sensors. Using the abilities of program software a periodical (12h) automatic export/import was realized. Access to file on remote computers is opened using FTP protocol. Database forms derived tables for each sensors. We use triggers to modify data, for example, to modify signal from gas sensors to gas concentration, in depend of unique sensor name. Additional table gives geographical coordinates of each node. We use GIS project for visualization and data analysis. Experiences revealed the inverse relationship between H2 concentration and temperature and pressure. Also we revealed periodicity of gas concentration with different harmonics. We could not find in literatures the similar works of H2 monitoring in cites. Exclusion is the work of (Necki et al., 2014) to organize continue monitoring in Krakow and it neighborhood. Authors also note periodicity in gas concentration affected by the seasons (increase in wintertime), day time (auto traffic). The received data we consider as first experiments in organization of long time monitoring of cites atmosphere, using new technologies (WSN). This results we consider to be the first methodological experiments in the field of monitoring the atmosphere of the city by WSN technic. It is planned to update the correctness of the analysis based on a comparison with other gas analysis methods. Acknowledgements This study was supported by the program 44 presidium RAS "Search basic research for the development of the Russian Arctic" Reference Necki, Jaroslaw M.; Chmura, Lukasz; Bielewski, Jaroslaw; et al. Variability of Molecular Hydrogen in the Urban Atmosphere Based on Continuous Measurements in Krakow //Polish Journal of Environmental Studies 2014, V.23, Iss. 2, P. 427-434.

76 FR 17287 - Protocol Gas Verification Program and Minimum Competency Requirements for Air Emission Testing

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-28

...EPA is finalizing rule revisions that modify existing requirements for sources affected by the federally administered emission trading programs including the NOX Budget Trading Program, the Acid Rain Program, and the Clean Air Interstate Rule. EPA is amending its Protocol Gas Verification Program (PGVP) and the minimum competency requirements for air emission testing (formerly air emission testing body requirements) to improve the accuracy of emissions data. EPA is also amending other sections of the Acid Rain Program continuous emission monitoring system regulations by adding and clarifying certain recordkeeping and reporting requirements, removing the provisions pertaining to mercury monitoring and reporting, removing certain requirements associated with a class-approved alternative monitoring system, disallowing the use of a particular quality assurance option in EPA Reference Method 7E, adding two incorporation by references that were inadvertently left out of the January 24, 2008 final rule, adding two new definitions, revising certain compliance dates, and clarifying the language and applicability of certain provisions.

Pneumatic gap sensor and method

DOEpatents

Bagdal, Karl T.; King, Edward L.; Follstaedt, Donald W.

1992-01-01

An apparatus and method for monitoring and maintaining a predetermined width in the gap between a casting nozzle and a casting wheel, wherein the gap is monitored by means of at least one pneumatic gap sensor. The pneumatic gap sensor is mounted on the casting nozzle in proximity to the casting surface and is connected by means of a tube to a regulator and a transducer. The regulator provides a flow of gas through a restictor to the pneumatic gap sensor, and the transducer translates the changes in the gas pressure caused by the proximity of the casting wheel to the pneumatic gap sensor outlet into a signal intelligible to a control device. The relative positions of the casting nozzle and casting wheel can thereby be selectively adjusted to continually maintain a predetermined distance between their adjacent surfaces. The apparatus and method enables accurate monitoring of the actual casting gap in a simple and reliable manner resistant to the extreme temperatures and otherwise hostile casting environment.

Pneumatic gap sensor and method

DOEpatents

Bagdal, K.T.; King, E.L.; Follstaedt, D.W.

1992-03-03

An apparatus and method for monitoring and maintaining a predetermined width in the gap between a casting nozzle and a casting wheel, wherein the gap is monitored by means of at least one pneumatic gap sensor. The pneumatic gap sensor is mounted on the casting nozzle in proximity to the casting surface and is connected by means of a tube to a regulator and a transducer. The regulator provides a flow of gas through a restictor to the pneumatic gap sensor, and the transducer translates the changes in the gas pressure caused by the proximity of the casting wheel to the pneumatic gap sensor outlet into a signal intelligible to a control device. The relative positions of the casting nozzle and casting wheel can thereby be selectively adjusted to continually maintain a predetermined distance between their adjacent surfaces. The apparatus and method enables accurate monitoring of the actual casting gap in a simple and reliable manner resistant to the extreme temperatures and otherwise hostile casting environment. 6 figs.

Performance of an electrochemical carbon monoxide monitor in the presence of anesthetic gases.

PubMed

Dunning, M; Woehlck, H J

1997-11-01

The passage of volatile anesthetic agents through accidentally dried CO2 absorbents in anesthesia circuits can result in the chemical breakdown of anesthetics with production of greater than 10000 ppm carbon monoxide (CO). This study was designed to evaluate a portable CO monitor in the presence of volatile anesthetic agents. Two portable CO monitors employing electrochemical sensors were tested to determine the effects of anesthetic agents, gas sample flow rates, and high CO concentrations on their electrochemical sensor. The portable CO monitors were exposed to gas mixtures of 0 to 500 ppm CO in either 70% nitrous oxide, 1 MAC concentrations of contemporary volatile anesthetics, or reacted isoflurane or desflurane (containing CO and CHF3) in oxygen. The CO measurements from the electrochemical sensors were compared to simultaneously obtained samples measured by gas chromatography (GC). Data were analyzed by linear regression. Overall correlation between the portable CO monitors and the GC resulted in an r2 value >0.98 for all anesthetic agents. Sequestered samples produced an exponential decay of measured CO with time, whereas stable measurements were maintained during continuous flow across the sensor. Increasing flow rates resulted in higher CO readings. Exposing the CO sensor to 3000 and 19000 ppm CO resulted in maximum reported concentrations of approximately 1250 ppm, with a prolonged recovery. Decrease in measured concentration of the sequestered samples suggests destruction of the sample by the sensor, whereas a diffusion limitation is suggested by the dependency of measured value upon flow. Any value over 500 ppm must be assumed to represent dangerous concentrations of CO because of the non-linear response of these monitors at very high CO concentrations. These portable electrochemical CO monitors are adequate to measure CO concentrations up to 500 ppm in the presence of typical clinical concentrations of anesthetics.

40 CFR 63.11940 - What continuous monitoring requirements must I meet for control devices required to install CPMS...

Code of Federal Regulations, 2012 CFR

2012-07-01

... consistent with the manufacturer's recommendations within 15 days or by the next time any process vent stream... the manufacturer's recommendations within 15 days or by the next time any process vent stream is...) Determine gas stream flow using the design blower capacity, with appropriate adjustments for pressure drop...

STATUS OF SEMI-CONTINUOUS MONITORING INSTRUMENTATION FOR GAS AND WATER SOLUBLE PARTICLE COMPONENTS NEEDED FOR DIAGNOSTIC TESTING OF AMBIENT AIR QUALITY SIMULATION MODELS

EPA Science Inventory

This status report documents the effort by the National Exposure Research Laboratory (NERL), Office of Research and Development (ORD) of the U.S. Environmental Protection Agency (U.S. EPA) to provide methods of measurement, including calibration procedures, that meet the requir...

IDENTIFICATION OF FMC EMISSION SOURCES CONTRIBUTING TO AMBIENT PM10 ON THE FORT HALL RESERVATION

EPA Science Inventory

More than 300 air change rate experiments were completed in two occupied residences: a two-story detached house in Redwood City, CA, and a three-story townhouse in Reston, VA. A continuous monitor was used to measure the decay of SF6 tracer gas over periods of 1-18 hr. Each e...

21 CFR 870.4330 - Cardiopulmonary bypass on-line blood gas monitor.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Cardiopulmonary bypass on-line blood gas monitor... Cardiopulmonary bypass on-line blood gas monitor. (a) Identification. A cardiopulmonary bypass on-line blood gas monitor is a device used in conjunction with a blood gas sensor to measure the level of gases in the blood...

21 CFR 870.4330 - Cardiopulmonary bypass on-line blood gas monitor.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Cardiopulmonary bypass on-line blood gas monitor... Cardiopulmonary bypass on-line blood gas monitor. (a) Identification. A cardiopulmonary bypass on-line blood gas monitor is a device used in conjunction with a blood gas sensor to measure the level of gases in the blood...

21 CFR 870.4330 - Cardiopulmonary bypass on-line blood gas monitor.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Cardiopulmonary bypass on-line blood gas monitor... Cardiopulmonary bypass on-line blood gas monitor. (a) Identification. A cardiopulmonary bypass on-line blood gas monitor is a device used in conjunction with a blood gas sensor to measure the level of gases in the blood...

21 CFR 870.4330 - Cardiopulmonary bypass on-line blood gas monitor.

Code of Federal Regulations, 2011 CFR

2011-04-01

... Cardiopulmonary bypass on-line blood gas monitor. (a) Identification. A cardiopulmonary bypass on-line blood gas monitor is a device used in conjunction with a blood gas sensor to measure the level of gases in the blood... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Cardiopulmonary bypass on-line blood gas monitor...

21 CFR 870.4330 - Cardiopulmonary bypass on-line blood gas monitor.

Code of Federal Regulations, 2010 CFR

2010-04-01

... Cardiopulmonary bypass on-line blood gas monitor. (a) Identification. A cardiopulmonary bypass on-line blood gas monitor is a device used in conjunction with a blood gas sensor to measure the level of gases in the blood... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Cardiopulmonary bypass on-line blood gas monitor...

Pulsed-laser excitation of acoustic modes in open high-Q photoacoustic resonators for trace gas monitoring: results for C2H4

NASA Astrophysics Data System (ADS)

Brand, Christian; Winkler, Andreas; Hess, Peter; Miklós, András; Bozóki, Zoltán; Sneider, János

1995-06-01

The pulsed excitation of acoustic resonances was studied with a continuously monitoring photoacoustic detector system. Acoustic waves were generated in C2H4/N 2 gas mixtures by light absorption of the pulses from a transversely excited atmospheric CO2 laser. The photoacoustic part consisted of high-Q cylindrical resonators (Q factor 820 for the first radial mode in N2) and two adjoining variable acoustic filter systems. The time-resolved signal was Fourier transformed to a frequency spectrum of high resolution. For the first radial mode a Lorentzian profile was fitted to the measured data. The outside noise suppression and the signal-to-noise ratio were investigated in a normal laboratory environment in the flow-through mode. The acoustic and electric filter system combined with the

Real-time electronic monitoring of a pitted and leaking gas gathering pipeline

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asperger, R.G.; Hewitt, P.G.

1986-08-01

Hydrogen patch, flush electrical resistance, and flush linear polarization proves wre used with flush coupons to monitor corrosion rates in a pitted and leaking sour gas gathering line. Four inhibitors were evaluated in stopping the leaks. Inhibitor residuals and the amount and ratio of water and condensate in the lines were measured at five locations along the line. The best inhibitor reduced reduced the pit-leak frequency by over a factor of 10. Inhibitor usage rate was optimized using the hydrogen patch current as a measure of the instantaneous corrosion rate. Improper pigging was identified as a cause of corrosion transients.more » This problem is discussed in relation to the pigging of pipelines in stratified flow where moving fluids are the carriers for continuously injected corrosion inhibitors.« less

Monitoring industrial facilities using principles of integration of fiber classifier and local sensor networks

NASA Astrophysics Data System (ADS)

Korotaev, Valery V.; Denisov, Victor M.; Rodrigues, Joel J. P. C.; Serikova, Mariya G.; Timofeev, Andrey V.

2015-05-01

The paper deals with the creation of integrated monitoring systems. They combine fiber-optic classifiers and local sensor networks. These systems allow for the monitoring of complex industrial objects. Together with adjacent natural objects, they form the so-called geotechnical systems. An integrated monitoring system may include one or more spatially continuous fiber-optic classifiers based on optic fiber and one or more arrays of discrete measurement sensors, which are usually combined in sensor networks. Fiber-optic classifiers are already widely used for the control of hazardous extended objects (oil and gas pipelines, railways, high-rise buildings, etc.). To monitor local objects, discrete measurement sensors are generally used (temperature, pressure, inclinometers, strain gauges, accelerometers, sensors measuring the composition of impurities in the air, and many others). However, monitoring complex geotechnical systems require a simultaneous use of continuous spatially distributed sensors based on fiber-optic cable and connected local discrete sensors networks. In fact, we are talking about integration of the two monitoring methods. This combination provides an additional way to create intelligent monitoring systems. Modes of operation of intelligent systems can automatically adapt to changing environmental conditions. For this purpose, context data received from one sensor (e.g., optical channel) may be used to change modes of work of other sensors within the same monitoring system. This work also presents experimental results of the prototype of the integrated monitoring system.

Oxygen sensor for monitoring gas mixtures containing hydrocarbons

DOEpatents

Ruka, Roswell J.; Basel, Richard A.

1996-01-01

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Oxygen sensor for monitoring gas mixtures containing hydrocarbons

DOEpatents

Ruka, R.J.; Basel, R.A.

1996-03-12

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

ELECTRICITY GENERATION FROM LANDFILL GAS IN TURKEY.

PubMed

Salihoglu, Nezih Kamil

2018-05-08

Landfill gas (LFG)-to-energy plants in Turkey were investigated, and the LFG-to-energy plant of a metropolitan municipal landfill was monitored for 3 years. Installed capacities and actual gas engine working hours were determined. An equation was developed to estimate the power capacity for LFG-to-energy plants for a given amount of landfilled waste. Monitoring the actual gas generation rates enabled determination of LFG generation factors for Turkish municipal waste. A significant relationship (R = 0.524, p < 0.01, 2-tailed) was found between the amounts of landfilled waste and the ambient temperature, which can be attributed to food consumption and kitchen waste generation behaviors influenced by the ambient temperature. However, no significant correlation was found between the ambient temperature and the generated LFG. A temperature buffering capacity was inferred to exist within the landfill, which enables the anaerobic reactions to continue functioning even during cold seasons. The average LFG and energy generation rates were 45 m 3 LFG/ton waste landfilled and 0.08 MWh/ton waste landfilled, respectively. The mean specific LFG consumption for electricity generation was 529 ± 28 m 3 /MWh.

An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

USGS Publications Warehouse

Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Robert Lopaka; Kamibayashi, Kevan P.; Antolik, Loren; Werner, Cynthia A.

2015-01-01

SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely “off-the-shelf” components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

NASA Astrophysics Data System (ADS)

Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Lopaka; Kamibayashi, Kevan; Antolik, Loren; Werner, Cynthia

2015-07-01

SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely ;off-the-shelf; components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

Environmental assessment of a crude-oil heater using staged air lances for NOx reduction. Volume 1. Technical results. Final report June 1981-November 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.

1984-07-01

This volume of the report gives emission results from field tests of a crude-oil process heater burning a combination of oil and refinery gas. The heater had been modified by adding a system for injecting secondary air to reduce NOx emissions. One test was conducted with the staged air system (low NOx), and the other, without (baseline). Tests included continuous monitoring of flue gas emissions and source assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of the samples utilizing gas chromatography (GC), infrared spectrometry (IR), gas chromatography/mass spectroscopy (GC/MS), and low resolution mass spectrometry (SSMS)more » for trace metals. LRMS analysis suggested the presence of eight compound categories in the organic emissions during the baseline test and four in the low-NOx test.« less

In-situ formation compaction monitoring in deep reservoirs by use of fiber optics

NASA Astrophysics Data System (ADS)

Murai, Daisuke; Kunisue, Shoji; Higuchi, Tomoyuki; Kokubo, Tatsuo

2013-04-01

1. Background The Southern Kanto gas field, the largest field of natural gas dissolved in water in Japan, is located primarily under the Chiba Prefecture. In this field 8 companies produce 460*10^6m3/y of natural gas. In addition, the concentration of the iodine in the brine is almost 2000 times that in seawater and the iodine as well as natural gas is collected from the brine. Iodine is industrially useful and essential for the human body. About 30% of world production is produced in this area in recent years. On the other hand, the land subsidence has become the big problem since 1965 and more than 10cm/mm of land subsidence was observed by leveling in 1972. The natural gas and iodine producers in this area have made a land subsidence prevention agreement with the local government and made effort to prevent and control land subsidence. Although their pumping brine for the gas and the iodine production is inferred to be the main cause of land subsidence from that time, the ratio of the formation compaction caused by pumping brine in the total land subsidence hasn't been well known. Therefore, the measurement of the actual formation compaction has become an important technological issue for the companies and they jointly have developed a new monitoring system for the formation compaction. 2. Contents (1) By using fiber optics technology, we have developed a world's first monitoring system which measures each of the in-situ formation compactions continuously without running tools into the well. (2) In order to check a reliability of this system and the problems when construction, we carried out the preliminary test. We installed the prototype system in the shallow observation well with a depth of 80 m and measured the actual formation compaction. The water well was drilled at the 10m away from the observation well and the formation was artificially compacted by pumping groundwater from it. (3) We installed the monitoring system in the deep observation well with a depth of about 800m, and have been measuring the formation compaction of the natural gas reservoir now. 3. Conclusions (1) We succeeded in installing the monitoring system into the observation well and measure the each of 6 formation compactions in the gas reservoir. (2) As a result of the preliminary test we confirmed that the monitoring system run without big problems even in the field. The formation compacted/expanded with the groundwater level fallen/risen according to the pump rate. (3) We improved the monitoring system based on the knowledge acquired by the demonstration test and installed it into the deep observation well. We are carrying out the long term observation now. 4. Acknowledgements This research was carried out by the support for application of new technologies and technical studies program which Japan Oil, Gas and Metals National Corporation (JOGMEC) undertook.

Assessment of long-term gas sampling design at two commercial manure-belt layer barns.

PubMed

Chai, Li-Long; Ni, Ji-Qin; Chen, Yan; Diehl, Claude A; Heber, Albert J; Lim, Teng T

2010-06-01

Understanding temporal and spatial variations of aerial pollutant concentrations is important for designing air quality monitoring systems. In long-term and continuous air quality monitoring in large livestock and poultry barns, these systems usually use location-shared analyzers and sensors and can only sample air at limited number of locations. To assess the validity of the gas sampling design at a commercial layer farm, a new methodology was developed to map pollutant gas concentrations using portable sensors under steady-state or quasi-steady-state barn conditions. Three assessment tests were conducted from December 2008 to February 2009 in two manure-belt layer barns. Each barn was 140.2 m long and 19.5 m wide and had 250,000 birds. Each test included four measurements of ammonia and carbon dioxide concentrations at 20 locations that covered all operating fans, including six of the fans used in the long-term sampling that represented three zones along the lengths of the barns, to generate data for complete-barn monitoring. To simulate the long-term monitoring, gas concentrations from the six long-term sampling locations were extracted from the 20 assessment locations. Statistical analyses were performed to test the variances (F-test) and sample means (t test) between the 6- and 20-sample data. The study clearly demonstrated ammonia and carbon dioxide concentration gradients that were characterized by increasing concentrations from the west to east ends of the barns following the under-cage manure-belt travel direction. Mean concentrations increased from 7.1 to 47.7 parts per million (ppm) for ammonia and from 2303 to 3454 ppm for carbon dioxide from the west to east of the barns. Variations of mean gas concentrations were much less apparent between the south and north sides of the barns, because they were 21.2 and 20.9 ppm for ammonia and 2979 and 2951 ppm for carbon dioxide, respectively. The null hypotheses that the variances and means between the 6- and 20-sample data were equal at alpha = 0.05 (P > 0.05) were accepted for both gases. The results proved that the long-term gas sampling design was valid in this instance and suggested that the gas sampling design in these two barns was one of the best on the basis of available long-term monitoring instrumentation at reasonable cost.

Field evaluation of Fourier transform infrared continuous emissions monitoring (FTIR CEM) systems

NASA Astrophysics Data System (ADS)

Dunder, Thomas A.; Geyer, Thomas J.; Kinner, Laura L.; Plummer, Grant M.

1995-02-01

Recent environmental regulations, including the Clean Air Act and the Enhanced Monitoring Regulations, may require continuous emissions monitoring (CEM) of hazardous air pollutants (HAPs). A promising technique for this application is Fourier transform infrared spectroscopy (FTIR). FTIR spectroscopy can, in principle, be used to monitor virtually any gas phase species. Two evaluations of FTIR CEM systems are discussed. The first study, performed in 1993 - 94, compared two FTIR CEM systems on a side-by-side basis in an extended field test at two coal-fired electric power plants. The FTIR CEM systems monitored the legally mandated criteria pollutants and diluents (CO, CO2, NO, NO2, and SO2) as well as H2O. In addition, one system monitored two HAPs (HCl and HF) and NH3. The FTIR CEM measurements were compared with those from the compliance CEM systems at the facilities. Several relative accuracy test audits were also performed to verify the FTIR CEM accuracy. The second evaluation was recently commenced on behalf of the Environmental Protection Agency. In this study, FTIR CEM systems are evaluated specifically for the monitoring of HAP species by conducting laboratory and field tests. The evaluation culminates in the development of proposed performance specifications and protocols for FTIR CEM systems.

Monitoring CCS Sites: Lessons Learned Studying Natural Laboratories.

NASA Astrophysics Data System (ADS)

Tartarello, M. C.; Beaubien, S. E.; Graziani, S.; Lombardi, S.; Ruggiero, L.

2016-12-01

Monitoring is one of the most important aspects of Carbon Capture and Storage (CCS), both for early recognition of leaks from the reservoir and for public safety. Natural analogues could be useful to understand the potential impact of a leakage on the local ecosystem and to develop new techniques of monitoring. These sites, called also "natural laboratories", are characterized by natural, geologically-produced CO2 constantly leaking from the seafloor or from the groundsurface. In the last 10 years, our group as partner of some EC funded projects focused on CCS (NASCENT (2000-2003), CO2GeoNet (2004-2009), CO2ReMoVe (2006-2011), RISCS (2010-2013), and ECO2 (2011-2015)), studied gas migration mechanisms in these "natural laboratories", applying near-surface geochemistry to monitoring. This method provides one of the most powerful tools to assess whether a CCS site is leaking and, if it is, to quantify that leakage. This is because rather than being a remote method that estimates amounts based on proxy associations, such as some geophysical tools, it is an exact measurement of the item of interest (in this case CO2) in the accessible biosphere where there is concern regarding its potential impact. In particular, we have been studied two sites in Italy, characterized by significant emissions of CO2, related to volcanic emissions: the Latera Caldera (in Central Italy) and the offshore emissions near Panarea Island. We combined continuous and discontinuous monitoring, structural surveys and gas flux measurements. The results show a strong correlation between fault architecture and leakage rates. Moreover, the monitoring of an area for long periods allows defining the baseline, which is the fluctuation of gas concentrations both spatially and temporally as a function of biological, chemical, geological, land-use and meteorological processes.

Microfabricated gas chromatograph for on-site determinations of TCE in indoor air arising from vapor intrusion. 2. Spatial/temporal monitoring.

PubMed

Kim, Sun Kyu; Burris, David R; Bryant-Genevier, Jonathan; Gorder, Kyle A; Dettenmaier, Erik M; Zellers, Edward T

2012-06-05

We demonstrate the use of two prototype Si-microfabricated gas chromatographs (μGC) for continuous, short-term measurements of indoor trichloroethylene (TCE) vapor concentrations related to the investigation of TCE vapor intrusion (VI) in two houses. In the first house, with documented TCE VI, temporal variations in TCE air concentrations were monitored continuously for up to 48 h near the primary VI entry location under different levels of induced differential pressure (relative to the subslab). Concentrations ranged from 0.23 to 27 ppb by volume (1.2-150 μg/m(3)), and concentration trends agreed closely with those determined from concurrent reference samples. The sensitivity and temporal resolution of the measurements were sufficiently high to detect transient fluctuations in concentration resulting from short-term changes in variables affecting the extent of VI. Spatial monitoring showed a decreasing TCE concentration gradient with increasing distance from the primary VI entry location. In the second house, with no TCE VI, spatial profiles derived from the μGC prototype data revealed an intentionally hidden source of TCE within a closet, demonstrating the capability for locating non-VI sources. Concentrations measured in this house ranged from 0.51 to 56 ppb (2.7-300 μg/m(3)), in good agreement with reference method values. This first field demonstration of μGC technology for automated, near-real-time, selective VOC monitoring at low- or subppb levels augurs well for its use in short- and long-term on-site analysis of indoor air in support of VI assessments.

Imputing forest carbon stock estimates from inventory plots to a nationally continuous coverage

Treesearch

Barry Tyler Wilson; Christopher W. Woodall; Douglas M. Griffith

2013-01-01

The U.S. has been providing national-scale estimates of forest carbon (C) stocks and stock change to meet United Nations Framework Convention on Climate Change (UNFCCC) reporting requirements for years. Although these currently are provided as national estimates by pool and year to meet greenhouse gas monitoring requirements, there is growing need to disaggregate these...

Environmental assessment of a wood-waste-fired industrial firetube boiler. Volume 1. Technical results. Final report, January 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.; Waterland, L.R.

1987-03-01

The report gives emission results from field tests of a wood-waste-fired industrial firetube boiler. Emission measurements included: continuous monitoring of flue gas emissions: source assessment sampling system (SASS) sampling of the flue-gas with subsequent laboratory analysis of samples to give total flue gas organics in two boiling point ranges, compound category information within these ranges, specific quantitation of the semivolatile organic priority pollutants, and flue gas concentrations of 65 trace elements; Method 5 sampling for particulates; controlled condensation system (CSS) sampling for SO/sub 2/ and SO/sub 3/; and grab sampling of boiler bottom ash for trace element content determinations. Totalmore » organic emissions from the boiler were 5.7 mg/dscm, about 90% of which consisted of volatile compounds.« less

Using Signal Detection Theory and Time Window-based Human-In-The-Loop simulation as a tool for assessing the effectiveness of different qualitative shapes in continuous monitoring tasks.

PubMed

Kim, Jung Hyup; Rothrock, Ling; Laberge, Jason

2014-05-01

This paper provides a case study of Signal Detection Theory (SDT) as applied to a continuous monitoring dual-task environment. Specifically, SDT was used to evaluate the independent contributions of sensitivity and bias to different qualitative gauges used in process control. To assess detection performance in monitoring the gauges, we developed a Time Window-based Human-In-The-Loop (TWHITL) simulation bed. Through this test bed, we were able to generate a display similar to those monitored by console operators in oil and gas refinery plants. By using SDT and TWHITL, we evaluated the sensitivity, operator bias, and response time of flow, level, pressure, and temperature gauge shapes developed by Abnormal Situation Management(®) (ASM(®)) Consortium (www.asmconsortium.org). Our findings suggest that display density influences the effectiveness of participants in detecting abnormal shapes. Furthermore, results suggest that some shapes elicit better detection performance than others. Copyright © 2013 Elsevier Ltd and The Ergonomics Society. All rights reserved.

Five-Channel Infrared Laser Absorption Spectrometer for Combustion Product Monitoring Aboard Manned Spacecraft

NASA Technical Reports Server (NTRS)

Briggs, Ryan M.; Frez, Clifford; Borgentun, Carl E.; Bagheri, Mahmood; Forouhar, Siamak; May, Randy D.

2014-01-01

Continuous combustion product monitoring aboard manned spacecraft can prevent chronic exposure to hazardous compounds and also provides early detection of combustion events. As future missions extend beyond low-Earth orbit, analysis of returned environmental samples becomes impractical and safety monitoring should be performed in situ. Here, we describe initial designs of a five-channel tunable laser absorption spectrometer to continuously monitor combustion products with the goal of minimal maintenance and calibration over long-duration missions. The instrument incorporates dedicated laser channels to simultaneously target strong mid-infrared absorption lines of CO, HCl, HCN, HF, and CO2. The availability of low-power-consumption semiconductor lasers operating in the 2 to 5 micron wavelength range affords the flexibility to select absorption lines for each gas with maximum interaction strength and minimal interference from other gases, which enables the design of a compact and mechanically robust spectrometer with low-level sensitivity. In this paper, we focus primarily on absorption line selection based on the availability of low-power single-mode semiconductor laser sources designed specifically for the target wavelength range.

Real-time monitoring of particles, PAH, and CO in an occupied townhouse.

PubMed

Wallace, L

2000-01-01

Beginning in October 1996, indoor and sometimes outdoor air at an occupied house in a suburban area of Virginia has been monitored continuously for particles, PAH, and CO. Two Climet monitors have been used to count particles in six size ranges between 0.3 and > 10 microns, with 1-minute averages being collected every 5 minutes. Two Ecochem PAH monitors have been used to sample for particle-bound PAHs once every minute. Also, two Langan CO monitor-data loggers have measured CO once each minute while logging the PAH data. Two Aethalometers measure black carbon. A single Scanning Mobility Particle Sizer (SMPS) measures ultrafine particles. The pairs of monitors are set up either to provide an indoor/outdoor or an upstairs office/downstairs kitchen comparison. Air exchange is occasionally measured using a Bruel & Kjaer 1302 SF6 monitor, as a parameter necessary for estimating deposition rates for particles and PAH. Results from the first 16 months of monitoring (approximately 10 M observations) include: neighborhood woodburning and morning rush hour traffic are the most important sources of PAH and black carbon outdoors; candles, matches, incense, and frying, sauteeing, broiling, deep-frying, and stir-frying are additional important indoor sources of PM. One citronella candle was an extremely powerful PAH source. Neither woodburning nor vehicles appears to be an important source of particles indoors, but frying, grilling, and sauteeing are extremely strong indoor sources, together with combustion events such as use of matches and candles. Physical movement was an important source of coarse but not fine particles. Use of the gas stove for extended periods of time led to increased CO concentrations--vehicles and woodburning were relatively minor sources in comparison. The gas oven, gas burners, and electric toaster oven were important sources of ultrafine particles (< 0.1 micron). A source-proximity effect was noted with the kitchen monitor reading two to five times higher than the upstairs monitor for particles from kitchen events, while the upstairs monitor often read higher than the kitchen monitor for events caused by physical activity alone.

Breath acetone monitoring by portable Si:WO3 gas sensors

PubMed Central

Righettoni, Marco; Tricoli, Antonio; Gass, Samuel; Schmid, Alex; Amann, Anton; Pratsinis, Sotiris E.

2013-01-01

Breath analysis has the potential for early stage detection and monitoring of illnesses to drastically reduce the corresponding medical diagnostic costs and improve the quality of life of patients suffering from chronic illnesses. In particular, the detection of acetone in the human breath is promising for non-invasive diagnosis and painless monitoring of diabetes (no finger pricking). Here, a portable acetone sensor consisting of flame-deposited and in situ annealed, Si-doped epsilon-WO3 nanostructured films was developed. The chamber volume was miniaturized while reaction-limited and transport-limited gas flow rates were identified and sensing temperatures were optimized resulting in a low detection limit of acetone (~20 ppb) with short response (10–15 s) and recovery times (35–70 s). Furthermore, the sensor signal (response) was robust against variations of the exhaled breath flow rate facilitating application of these sensors at realistic relative humidities (80–90%) as in the human breath. The acetone content in the breath of test persons was monitored continuously and compared to that of state-of-the-art proton transfer reaction mass spectrometry (PTR-MS). Such portable devices can accurately track breath acetone concentration to become an alternative to more elaborate breath analysis techniques. PMID:22790702

Dynamic monitoring of horizontal gene transfer in soil

NASA Astrophysics Data System (ADS)

Cheng, H. Y.; Masiello, C. A.; Silberg, J. J.; Bennett, G. N.

2015-12-01

Soil microbial gene expression underlies microbial behaviors (phenotypes) central to many aspects of C, N, and H2O cycling. However, continuous monitoring of microbial gene expression in soils is challenging because genetically-encoded reporter proteins widely used in the lab are difficult to deploy in soil matrices: for example, green fluorescent protein cannot be easily visualized in soils, even in the lab. To address this problem we have developed a reporter protein that releases small volatile gases. Here, we applied this gas reporter in a proof-of-concept soil experiment, monitoring horizontal gene transfer, a microbial activity that alters microbial genotypes and phenotypes. Horizontal gene transfer is central to bacterial evolution and adaptation and is relevant to problems such as the spread of antibiotic resistance, increasing metal tolerance in superfund sites, and bioremediation capability of bacterial consortia. This process is likely to be impacted by a number of matrix properties not well-represented in the petri dish, such as microscale variations in water, nutrients, and O2, making petri-dish experiments a poor proxy for environmental processes. We built a conjugation system using synthetic biology to demonstrate the use of gas-reporting biosensors in safe, lab-based biogeochemistry experiments, and here we report the use of these sensors to monitor horizontal gene transfer in soils. Our system is based on the F-plasmid conjugation in Escherichia coli. We have found that the gas signal reports on the number of cells that acquire F-plasmids (transconjugants) in a loamy Alfisol collected from Kellogg Biological Station. We will report how a gas signal generated by transconjugants varies with the number of F-plasmid donor and acceptor cells seeded in a soil, soil moisture, and soil O2 levels.

A New Meteo-oceanographic and Environmental Monitoring Laboratory in Brazil

NASA Astrophysics Data System (ADS)

Fontes, Roberto F. C.; Dottori, Marcelo; Silveira, Ilson C. A.; Castro, Belmiro M.

2013-04-01

The newer oil provinces in the pre-salt regions off the Brazilian Coast have raised the necessity of the creation of monitoring and observational centers, regarding the best comprehension on the ocean and atmosphere dynamics. The relation between industry and university is a concept based on collaboration, and it is an innovative social experiment in Brazil. The sustainability of that collaboration depends on the balance of mutual interests on private business and public academic institutions. The entrepreneur needs continuous accesses to the new academic researches, and the greatest benefit, for the academy, are funding complementation and personnel qualification. We need to establish a thread of new challenges, some of them based on disruption of paradigms in the Brazilian academic culture, and removal of obstructive clauses from the entrepreneur. Questioning and methods revalidation, in the oceanic environment areas, also requires a collaborative and interdisciplinary effort, congregating the physical aspects along with others compartments of the environmental monitoring. We proposed the creation of a Meteo-oceanographic and Environmental Monitoring Laboratory - LAMMOA (Portuguese acronym), which will be installed in a new facility funded by PETROBRAS (the Brazilian leading oil company) and ruled by USP, UNESP and UNICAMP, the state public universities in Santos (São Paulo State, Brazil). The new facility will be a research center in oil and gas activities, named CENPEG-BS (Portuguese acronym for Research Center of Oil and Gas in the Bay of Santos). Several laboratories and groups will work together, in a highly collaborative environment and so, capable of quickly respond to sudden demands on offshore activities and logistic operations, as well as in contingency situations. LAMMOA will continuous monitor oceanic regions where the pre-salt activities of oil exploitation occur. It will monitor meteo-oceanographic parameters like winds, waves and currents, providing suitable data for offshore and transportation activities. For such, LAMMOA will operate a system of moored acoustic current meters and others environmental sensors, applying analytical and numerical methods for improving comprehension of the oceanic environment. Oceanographic gliders, satellite measurements and newer observational technics should replace expensive hydrographic surveys, and enhance the efforts on the knowledge of oceanographic processes as those that occur in the Brazil Current. We hope these actions create a new culture on continuous monitoring the ocean, along and offshore the 8,000-km Brazilian coast, including its continental shelf and coastal regions.

Monitoring unrest in a large silicic caldera, the long Valley-inyo craters volcanic complex in east-central California

NASA Astrophysics Data System (ADS)

Hill, D. P.

1984-06-01

Recent patterns of geologic unrest in long Valley caldera in east-central California emphasize that this large, silicic volcanic system and the adjacent, geologically youthful Inyo-Mono Craters volcanic chain are still active and capable of producing locally hazardous volcanic eruptions. A series of four magnitude -6 earthquakes in May 1980 called attention to this current episode of unrest, and subsequent activity has included numerous earthquake swarms in the south moat of the caldera accompanied by inflation of the resurgent dome by more than 50 cm over the last five years. The seismicity associated with this unrest is currently monitored by a network of 31 telemetered seismic stations with an automatic processing system that yelds hypocentral locations and earthquake magnitudes in near-real time. Deformation of the ground is monitored by a) a series of overlapping trilateration networks that provide coverage ranging from annual measurements of regional deformation to daily measurements of deformation local to the active, southern section of the caldera, b) a regional network of level lines surveyed annually, c) a regional network of precise gravity stations occupied annually, d) local, L-shaped level figures surveyed every few months, and e) a network of fourteen borehole tiltmeter clusters (two instruments in each cluster) and a borehole dilatometer, the telemetered signals from which provide continuous data on deformation rates. Additional telemetered data provide continuous information on fluctuations in the local magnetic field, hydrogen gas emission rates at three sites, and water level and temperatures in three wells. Continuous data on disharge rates and temperatures from hot springs and fumaroles are collected by several on-site recorders within the caldera, and samples for liquid and gas chemistry are collected several times per year from selected hot springs and fumaroles.

Distributed acoustic fibre optic sensors for condition monitoring of pipelines

NASA Astrophysics Data System (ADS)

Hussels, Maria-Teresa; Chruscicki, Sebastian; Habib, Abdelkarim; Krebber, Katerina

2016-05-01

Industrial piping systems are particularly relevant to public safety and the continuous availability of infrastructure. However, condition monitoring systems based on many discrete sensors are generally not well-suited for widespread piping systems due to considerable installation effort, while use of distributed fibre-optic sensors would reduce this effort to a minimum. Specifically distributed acoustic sensing (DAS) is employed for detection of third-party threats and leaks in oil and gas pipelines in recent years and can in principle also be applied to industrial plants. Further possible detection routes amenable by DAS that could identify damage prior to emission of medium are subject of a current project at BAM, which aims at qualifying distributed fibre optic methods such as DAS as a means for spatially continuous monitoring of industrial piping systems. Here, first tests on a short pipe are presented, where optical fibres were applied directly to the surface. An artificial signal was used to define suitable parameters of the measurement system and compare different ways of applying the sensor.

Real-time indoor monitoring system based on wireless sensor networks

NASA Astrophysics Data System (ADS)

Wu, Zhengzhong; Liu, Zilin; Huang, Xiaowei; Liu, Jun

2008-10-01

Wireless sensor networks (WSN) greatly extend our ability to monitor and control the physical world. It can collaborate and aggregate a huge amount of sensed data to provide continuous and spatially dense observation of environment. The control and monitoring of indoor atmosphere conditions represents an important task with the aim of ensuring suitable working and living spaces to people. However, the comprehensive air quality, which includes monitoring of humidity, temperature, gas concentrations, etc., is not so easy to be monitored and controlled. In this paper an indoor WSN monitoring system was developed. In the system several sensors such as temperature sensor, humidity sensor, gases sensor, were built in a RF transceiver board for monitoring indoor environment conditions. The indoor environmental monitoring parameters can be transmitted by wireless to database server and then viewed throw PC or PDA accessed to the local area networks by administrators. The system, which was also field-tested and showed a reliable and robust characteristic, is significant and valuable to people.

Monitoring concentration and isotopic composition of methane in groundwater in the Utica Shale hydraulic fracturing region of Ohio.

PubMed

Claire Botner, E; Townsend-Small, Amy; Nash, David B; Xu, Xiaomei; Schimmelmann, Arndt; Miller, Joshua H

2018-05-03

Degradation of groundwater quality is a primary public concern in rural hydraulic fracturing areas. Previous studies have shown that natural gas methane (CH 4 ) is present in groundwater near shale gas wells in the Marcellus Shale of Pennsylvania, but did not have pre-drilling baseline measurements. Here, we present the results of a free public water testing program in the Utica Shale of Ohio, where we measured CH 4 concentration, CH 4 stable isotopic composition, and pH and conductivity along temporal and spatial gradients of hydraulic fracturing activity. Dissolved CH 4 ranged from 0.2 μg/L to 25 mg/L, and stable isotopic measurements indicated a predominantly biogenic carbonate reduction CH 4 source. Radiocarbon dating of CH 4 in combination with stable isotopic analysis of CH 4 in three samples indicated that fossil C substrates are the source of CH 4 in groundwater, with one 14 C date indicative of modern biogenic carbonate reduction. We found no relationship between CH 4 concentration or source in groundwater and proximity to active gas well sites. No significant changes in CH 4 concentration, CH 4 isotopic composition, pH, or conductivity in water wells were observed during the study period. These data indicate that high levels of biogenic CH 4 can be present in groundwater wells independent of hydraulic fracturing activity and affirm the need for isotopic or other fingerprinting techniques for CH 4 source identification. Continued monitoring of private drinking water wells is critical to ensure that groundwater quality is not altered as hydraulic fracturing activity continues in the region. Graphical abstract A shale gas well in rural Appalachian Ohio. Photo credit: Claire Botner.

MOPITT Mechanisms 16 Years In-Orbit Operation on TERRA

NASA Technical Reports Server (NTRS)

Gibson, Andrew S.; Nichitiu, Florian; Caldwell, Dwight

2016-01-01

The 16th anniversary of the launch of NASA's Terra Spacecraft was marked on December 18, 2015, with the Measurements of Pollution in the Troposphere (MOPITT) instrument being a successful contributor to the NASA EOS flagship. MOPITT has been enabled by a large suite of mechanisms, allowing the instrument to perform long-duration monitoring of atmospheric carbon monoxide, providing global measurements of this important greenhouse gas for 16 years. Mechanisms have been successfully employed for scanning, cooling of detectors, and to optically modulate the gas path length within the instrument by means of pressure and gas cell length variation. The instrument utilizes these devices to perform correlation spectroscopy, enabling measurements with vertical resolution from the nadir view, and has thereby furthered understanding of source and global transport effects of carbon monoxide. Given the design requirement for a 5.25-year lifetime, the stability and performance of the majority of mechanisms have far surpassed design goals. With 16 continuously operating mechanisms in service on MOPITT, including 12 rotating mechanisms and 4 with linear drive elements, the instrument was an ambitious undertaking. The long life requirements combined with demands for cleanliness and optical stability made for difficult design choices including that of the selection of new lubrication processes. Observations and lessons learned with regards to many aspects of the mechanisms and associated monitoring devices are discussed here. Mechanism behaviors are described, including anomalies, long-term drive current/power, fill pressure, vibration and cold-tip temperature trends. The effectiveness of particular lubrication formulations and the screening method implemented is discussed in relation to continuous rotating mechanisms and stepper motors, which have exceeded 15 billon rotations and 2.5 billion steps respectively. Aspects of gas cell hermeticity, optical cleanliness, heater problems and SEU effects on accelerometers are also discussed.

Measurements of soil, surface water, and groundwater CO2 concentration variability within Earth's critical zone: low-cost, long-term, high-temporal resolution monitoring

NASA Astrophysics Data System (ADS)

Blackstock, J. M.; Covington, M. D.; Williams, S. G. W.; Myre, J. M.; Rodriguez, J.

2017-12-01

Variability in CO2 fluxes within Earth's Critical zone occurs over a wide range of timescales. Resolving this and its drivers requires high-temporal resolution monitoring of CO2 both in the soil and aquatic environments. High-cost (> 1,000 USD) gas analyzers and data loggers present cost-barriers for investigations with limited budgets, particularly if high spatial resolution is desired. To overcome high-costs, we developed an Arduino based CO2 measuring platform (i.e. gas analyzer and data logger). The platform was deployed at multiple sites within the Critical Zone overlying the Springfield Plateau aquifer in Northwest Arkansas, USA. The CO2 gas analyzer used in this study was a relatively low-cost SenseAir K30. The analyzer's optical housing was covered by a PTFE semi-permeable membrane allowing for gas exchange between the analyzer and environment. Total approximate cost of the monitoring platform was 200 USD (2% detection limit) to 300 USD (10% detection limit) depending on the K30 model used. For testing purposes, we deployed the Arduino based platform alongside a commercial monitoring platform. CO2 concentration time series were nearly identical. Notably, CO2 cycles at the surface water site, which operated from January to April 2017, displayed a systematic increase in daily CO2 amplitude. Preliminary interpretation suggests key observation of seasonally increasing stream metabolic function. Other interpretations of observed cyclical and event-based behavior are out of the scope of the study; however, the presented method describes an accurate near-hourly characterization of CO2 variability. The new platform has been shown to be operational for several months, and we infer reliable operation for much longer deployments (> 1 year) given adequate environmental protection and power supply. Considering cost-savings, this platform is an attractive option for continuous, accurate, low-power, and low-cost CO2 monitoring for remote locations, globally.

A brief clinical case of monitoring of oxygenator performance and patient-machine interdependency during prolonged veno-venous extracorporeal membrane oxygenation.

PubMed

Belliato, Mirko; Degani, Antonella; Buffa, Antonino; Sciutti, Fabio; Pagani, Michele; Pellegrini, Carlo; Iotti, Giorgio Antonio

2017-10-01

Monitoring veno-venous extracorporeal membrane oxygenation (vvECMO) during 76 days of continuous support in a 42-years old patient with end-stage pulmonary disease, listed for double-lung transplantation. Applying a new monitor (Landing ® , Eurosets, Medolla, Italy) and describing how measured and calculated parameters can be used to understand the variable interdependency between artificial membrane lung (ML) and patient native lung (NL). During vvECMO, in order to understand how the respiratory function is shared between ML and NL, ideally we should obtain data about oxygen transfer and CO 2 removal, both by ML and NL. Measurements for NL can be made on the mechanical ventilator. Measurements for ML are typically made from gas analysis on blood samples drawn from the ECMO system before and after the oxygenator, and therefore are non-continuous. Differently, the Landing monitor provides a continuous measurement of the oxygen transfer from the ML, combined with hemoglobin level, saturation of drained blood and saturation of reinfused blood. Moreover, the Landing monitor provides hemodynamics data about circulation through the ECMO system, with blood flow, pre-oxygenator pressure and post-oxygenator pressure. Of note, measurements include the drain negative pressure, whose monitoring may be particularly useful to prevent hemolysis. Real-time monitoring of vvECMO provides data helpful to understand the complex picture of a patient with severely damaged lungs on one side and an artificial lung on the other side. Data from vvECMO monitoring may help to adapt the settings of both mechanical ventilator and vvECMO. Data about oxygen transfer by the oxygenator are important to evaluate the performance of the device and may help to avoid unnecessary replacements, thus reducing risks and costs.

40 CFR Appendix D to Part 52 - Determination of Sulfur Dioxide Emissions From Stationary Sources by Continuous Monitors

Code of Federal Regulations, 2010 CFR

2010-07-01

... cyclic analyzers, the response time test shall include one cycle. 5.3.2Introduce a zero concentration of... operation when the pollutant concentration at the time for the measurement is zero. 1.6Calibration Drift...%, and 30%) calibration gas mixture. 3. Zero Drift (2-hours) a ≤2 percent of emission standard. 4. Zero...

30 CFR 70.1900 - Exhaust Gas Monitoring.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900... MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES DIESEL EXHAUST GAS MONITORING § 70.1900 Exhaust Gas... ®) adopted by the American Conference of Governmental Industrial Hygienists, the mine operator shall...

Microseismicity Linked to Gas Migration and Leakage on the Western Svalbard Shelf

NASA Astrophysics Data System (ADS)

Franek, Peter; Plaza-Faverola, Andreia; Mienert, Jürgen; Buenz, Stefan; Ferré, Bénédicte; Hubbard, Alun

2017-12-01

The continental margin off Prins Karls Forland, western Svalbard, is characterized by widespread natural gas seepage into the water column at and upslope of the gas hydrate stability zone. We deployed an ocean bottom seismometer integrated into the MASOX (Monitoring Arctic Seafloor-Ocean Exchange) automated seabed observatory at the pinch-out of this zone at 389 m water depth to investigate passive seismicity over a continuous 297 day period from 13 October 2010. An automated triggering algorithm was applied to detect over 220,000 short duration events (SDEs) defined as having a duration of less than 1 s. The analysis reveals two different types of SDEs, each with a distinctive characteristic seismic signature. We infer that the first type consists of vocal signals generated by moving mammals, likely finback whales. The second type corresponds to signals with a source within a few hundred meters of the seismometer, either due east or west, that vary on short (˜tens of days) and seasonal time scales. Based on evidence of prevalent seafloor seepage and subseafloor gas accumulations, we hypothesize that the second type of SDEs is related to subseafloor fluid migration and gas seepage. Furthermore, we postulate that the observed temporal variations in microseismicity are driven by transient fluid release and due to the dynamics of thermally forced, seasonal gas hydrate decomposition. Our analysis presents a novel technique for monitoring the duration, intensity, and periodicity of fluid migration and seepage at the seabed and can help elucidate the environmental controls on gas hydrate decomposition and release.

Application of Allan Deviation to Assessing Uncertainties of Continuous-measurement Instruments, and Optimizing Calibration Schemes

NASA Astrophysics Data System (ADS)

Jacobson, Gloria; Rella, Chris; Farinas, Alejandro

2014-05-01

Technological advancement of instrumentation in atmospheric and other geoscience disciplines over the past decade has lead to a shift from discrete sample analysis to continuous, in-situ monitoring. Standard error analysis used for discrete measurements is not sufficient to assess and compare the error contribution of noise and drift from continuous-measurement instruments, and a different statistical analysis approach should be applied. The Allan standard deviation analysis technique developed for atomic clock stability assessment by David W. Allan [1] can be effectively and gainfully applied to continuous measurement instruments. As an example, P. Werle et al has applied these techniques to look at signal averaging for atmospheric monitoring by Tunable Diode-Laser Absorption Spectroscopy (TDLAS) [2]. This presentation will build on, and translate prior foundational publications to provide contextual definitions and guidelines for the practical application of this analysis technique to continuous scientific measurements. The specific example of a Picarro G2401 Cavity Ringdown Spectroscopy (CRDS) analyzer used for continuous, atmospheric monitoring of CO2, CH4 and CO will be used to define the basics features the Allan deviation, assess factors affecting the analysis, and explore the time-series to Allan deviation plot translation for different types of instrument noise (white noise, linear drift, and interpolated data). In addition, the useful application of using an Allan deviation to optimize and predict the performance of different calibration schemes will be presented. Even though this presentation will use the specific example of the Picarro G2401 CRDS Analyzer for atmospheric monitoring, the objective is to present the information such that it can be successfully applied to other instrument sets and disciplines. [1] D.W. Allan, "Statistics of Atomic Frequency Standards," Proc, IEEE, vol. 54, pp 221-230, Feb 1966 [2] P. Werle, R. Miicke, F. Slemr, "The Limits of Signal Averaging in Atmospheric Trace-Gas Monitoring by Tunable Diode-Laser Absorption Spectroscopy (TDLAS)," Applied Physics, B57, pp 131-139, April 1993

Environmental assessment of a wood-waste-fired industrial firetube boiler. Volume 2. Data supplement. Final report, January 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.; Waterland, L.R.

1987-03-01

The report gives emission results from field tests of a wood-waste-fired industrial firetube boiler. Emission measurements included: continuous monitoring of flue-gas emissions; source assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semivolatile organic priority pollutants, and flue-gas concentrations of 65 trace elements; Method 5 sampling for particulates; controlled condensation system (CSS) sampling for SO/sub 2/ and SO/sub 3/; and grab sampling of boiler bottom ash for trace-element-content determinations. Emission levels of five polycyclic organicmore » matter species and phenol were quantitated: except for naphthalene, all were emitted at less than 0.4 microgram/dscm.« less

Tube bundle system studies at Signal Peak Energy Bull Mountains #1 Mine

PubMed Central

Zipf, R.K.; Ochsner, R.; Krog, R.; Marchewka, W.; Valente, M.; Jensen, R.

2015-01-01

A tube bundle system (TBS) is a mechanical system for continuously drawing gas samples through tubes from multiple monitoring points located in an underground coal mine for analysis and display on the surface. The U.S. National Institute for Occupational Safety and Health (NIOSH), in collaboration with Signal Peak Energy (SPE), LLC, Bull Mountains No. 1 Mine, operated a TBS during mining of two bleederless, longwall panels. This paper describes the gas analysis data and its interpretation. As verified by the TBS, coal at the SPE mine tends to oxidize slowly. It was known that a reservoir of low-oxygen concentration atmosphere developed about 610 m (2,000 ft) behind the longwall face. A bleederless ventilation system facilitates formation of an inert atmosphere in this longwall gob and decreases the likelihood of spontaneous combustion. Connections of the mine atmosphere to the surface through subsidence cracks could allow airflow into the longwall gob, revive coal oxidation and increase spontaneous combustion risk. The atmospheric composition of the sealed areas was homogeneous, except in the immediate vicinity of suspected ingassing points. The TBS verified that gases within the partially sealed, bleederless longwall gob expanded into the longwall tailgate area when barometric pressure decreased. The concentration of carbon dioxide in the back return airflow at the longwall tailgate was observed to increase by a factor of three and possibly up to 10 times the typical background concentration of 0.5 to 1.0%, depending on the size of the longwall gob and the magnitude of barometric pressure decrease. TBS have the inherent disadvantage of slow response time due to travel time of the gas samples and sequential gas analyses. A TBS or similar continuous monitoring system could be beneficial in detecting and providing warning of potentially hazardous gas concentrations, if the slow response time of the system is always understood. PMID:26306075

Tube bundle system studies at Signal Peak Energy Bull Mountains #1 Mine.

PubMed

Zipf, R K; Ochsner, R; Krog, R; Marchewka, W; Valente, M; Jensen, R

2014-03-01

A tube bundle system (TBS) is a mechanical system for continuously drawing gas samples through tubes from multiple monitoring points located in an underground coal mine for analysis and display on the surface. The U.S. National Institute for Occupational Safety and Health (NIOSH), in collaboration with Signal Peak Energy (SPE), LLC, Bull Mountains No. 1 Mine, operated a TBS during mining of two bleederless, longwall panels. This paper describes the gas analysis data and its interpretation. As verified by the TBS, coal at the SPE mine tends to oxidize slowly. It was known that a reservoir of low-oxygen concentration atmosphere developed about 610 m (2,000 ft) behind the longwall face. A bleederless ventilation system facilitates formation of an inert atmosphere in this longwall gob and decreases the likelihood of spontaneous combustion. Connections of the mine atmosphere to the surface through subsidence cracks could allow airflow into the longwall gob, revive coal oxidation and increase spontaneous combustion risk. The atmospheric composition of the sealed areas was homogeneous, except in the immediate vicinity of suspected ingassing points. The TBS verified that gases within the partially sealed, bleederless longwall gob expanded into the longwall tailgate area when barometric pressure decreased. The concentration of carbon dioxide in the back return airflow at the longwall tailgate was observed to increase by a factor of three and possibly up to 10 times the typical background concentration of 0.5 to 1.0%, depending on the size of the longwall gob and the magnitude of barometric pressure decrease. TBS have the inherent disadvantage of slow response time due to travel time of the gas samples and sequential gas analyses. A TBS or similar continuous monitoring system could be beneficial in detecting and providing warning of potentially hazardous gas concentrations, if the slow response time of the system is always understood.

Simultaneous atmospheric nitrous oxide, methane and water vapor detection with a single continuous wave quantum cascade laser.

PubMed

Cao, Yingchun; Sanchez, Nancy P; Jiang, Wenzhe; Griffin, Robert J; Xie, Feng; Hughes, Lawrence C; Zah, Chung-en; Tittel, Frank K

2015-02-09

A continuous wave (CW) quantum cascade laser (QCL) based absorption sensor system was demonstrated and developed for simultaneous detection of atmospheric nitrous oxide (N(2)O), methane (CH(4)), and water vapor (H(2)O). A 7.73-µm CW QCL with its wavelength scanned over a spectral range of 1296.9-1297.6 cm(-1) was used to simultaneously target three neighboring strong absorption lines, N(2)O at 1297.05 cm(-1), CH(4) at 1297.486 cm(-1), and H(2)O at 1297.184 cm(-1). An astigmatic multipass Herriott cell with a 76-m path length was utilized for laser based gas absorption spectroscopy at an optimum pressure of 100 Torr. Wavelength modulation and second harmonic detection was employed for data processing. Minimum detection limits (MDLs) of 1.7 ppb for N(2)O, 8.5 ppb for CH(4), and 11 ppm for H(2)O were achieved with a 2-s integration time for individual gas detection. This single QCL based multi-gas detection system possesses applications in environmental monitoring and breath analysis.

Measurement of greenhouse gases in UAE by using Unmanned Aerial Vehicle (UAV)

NASA Astrophysics Data System (ADS)

Abou-Elnour, Ali; Odeh, Mohamed; Abdelrhman, Mohammed; Balkis, Ahmed; Amira, Abdelraouf

2017-04-01

In the present work, a reliable and low cost system has been designed and implemented to measure greenhouse gases (GHG) in United Arab Emirates (UAE) by using unmanned aerial vehicle (UAV). A set of accurate gas, temperature, pressure, humidity sensors are integrated together with a wireless communication system on a microcontroller based platform to continuously measure the required data. The system instantaneously sends the measured data to a center monitoring unit via the wireless communication system. In addition, the proposed system has the features that all measurements are recorded directly in a storage device to allow effective monitoring in regions with weak or no wireless coverage. The obtained data will be used in all further sophisticated calculations for environmental research and monitoring purposes.

77 FR 62224 - Hanford Tank Farms Flammable Gas Safety Strategy

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-12

... believes that actions are necessary to install real time monitoring to measure tank ventilation flowrates... monitoring. In its August letter, the Board noted that DOE's SAC for flammable gas monitoring exhibited a... flammable gas monitoring, it remained inadequate as a credited safety control. The SAC is less reliable than...

CO2 leakage monitoring and analysis to understand the variation of CO2 concentration in vadose zone by natural effects

NASA Astrophysics Data System (ADS)

Joun, Won-Tak; Ha, Seung-Wook; Kim, Hyun Jung; Ju, YeoJin; Lee, Sung-Sun; Lee, Kang-Kun

2017-04-01

Controlled ex-situ experiments and continuous CO2 monitoring in the field are significant implications for detecting and monitoring potential leakage from CO2 sequestration reservoir. However, it is difficult to understand the observed parameters because the natural disturbance will fluctuate the signal of detections in given local system. To identify the original source leaking from sequestration reservoir and to distinguish the camouflaged signal of CO2 concentration, the artificial leakage test was conducted in shallow groundwater environment and long-term monitoring have been performed. The monitoring system included several parameters such as pH, temperature, groundwater level, CO2 gas concentration, wind speed and direction, atmospheric pressure, borehole pressure, and rainfall event etc. Especially in this study, focused on understanding a relationship among the CO2 concentration, wind speed, rainfall and pressure difference. The results represent that changes of CO2 concentration in vadose zone could be influenced by physical parameters and this reason is helpful in identifying the camouflaged signal of CO2 concentrations. The 1-D column laboratory experiment also was conducted to understand the sparking-peak as shown in observed data plot. The results showed a similar peak plot and could consider two assumptions why the sparking-peak was shown. First, the trapped CO2 gas was escaped when the water table was changed. Second, the pressure equivalence between CO2 gas and water was broken when the water table was changed. These field data analysis and laboratory experiment need to advance due to comprehensively quantify local long-term dynamics of the artificial CO2 leaking aquifer. Acknowledgement Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003)

Hydrogen and Oxygen Gas Monitoring System Design and Operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee C. Cadwallader; Kevin G. DeWall; J. Stephen Herring

2007-06-01

This paper describes pertinent design practices of selecting types of monitors, monitor unit placement, setpoint selection, and maintenance considerations for gas monitors. While hydrogen gas monitors and enriched oxygen atmosphere monitors as they would be needed for hydrogen production experiments are the primary focus of this paper, monitors for carbon monoxide and carbon dioxide are also discussed. The experiences of designing, installing, and calibrating gas monitors for a laboratory where experiments in support of the DOE Nuclear Hydrogen Initiative (NHI) are described along with codes, standards, and regulations for these monitors. Information from the literature about best operating practices ismore » also presented. The NHI program has two types of activities. The first, near-term activity is laboratory and pilot-plant experimentation with different processes in the kilogram per day scale to select the most promising types of processes for future applications of hydrogen production. Prudent design calls for indoor gas monitors to sense any hydrogen leaks within these laboratory rooms. The second, longer-term activity is the prototype, or large-scale plants to produce tons of hydrogen per day. These large, outdoor production plants will require area (or “fencepost”) monitoring of hydrogen gas leaks. Some processes will have oxygen production with hydrogen production, and any oxygen releases are also safety concerns since oxygen gas is the strongest oxidizer. Monitoring of these gases is important for personnel safety of both indoor and outdoor experiments. There is some guidance available about proper placement of monitors. The fixed point, stationary monitor can only function if the intruding gas contacts the monitor. Therefore, monitor placement is vital to proper monitoring of the room or area. Factors in sensor location selection include: indoor or outdoor site, the location and nature of potential vapor/gas sources, chemical and physical data of the gases or vapors, liquids with volatility need sensors near the potential sources of release, nature and concentration of gas releases, natural and mechanical ventilation, detector installation locations not vulnerable to mechanical or water damage from normal operations, and locations that lend themselves to convenient maintenance and calibration. The guidance also states that sensors should be located in all areas where hazardous accumulations of gas may occur. Such areas might not be close to release points but might be areas with restricted air movement. Heavier than air gases are likely to accumulate in pits, trenches, drains, and other low areas. Lighter than air gases are more likely to accumulate in overhead spaces, above drop ceilings, etc. In general, sensors should be located close to any potential sources of major release of gas. The paper gives data on monitor sensitivity and expected lifetimes to support the monitor selection process. Proper selection of indoor and outdoor locations for monitors is described, accounting for the vapor densities of hydrogen and oxygen. The latest information on monitor alarm setpoint selection is presented. Typically, monitors require recalibration at least every six months, or more frequently for inhospitable locations, so ready access to the monitors is an important issue to consider in monitor siting. Gas monitors, depending on their type, can be susceptible to blockages of the detector element (i.e., dus« less

Tunable photonic cavities for in-situ spectroscopic trace gas detection

DOEpatents

Bond, Tiziana; Cole, Garrett; Goddard, Lynford

2012-11-13

Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

Simultaneous multi-laser, multi-species trace-level sensing of gas mixtures by rapidly swept continuous-wave cavity-ringdown spectroscopy.

PubMed

He, Yabai; Kan, Ruifeng; Englich, Florian V; Liu, Wenqing; Orr, Brian J

2010-09-13

The greenhouse-gas molecules CO(2), CH(4), and H(2)O are detected in air within a few ms by a novel cavity-ringdown laser-absorption spectroscopy technique using a rapidly swept optical cavity and multi-wavelength coherent radiation from a set of pre-tuned near-infrared diode lasers. The performance of various types of tunable diode laser, on which this technique depends, is evaluated. Our instrument is both sensitive and compact, as needed for reliable environmental monitoring with high absolute accuracy to detect trace concentrations of greenhouse gases in outdoor air.

FutureGen 2.0 Monitoring Program: An Overview of the Monitoring Approach and Technologies Selected for Implementation

DOE PAGES

Vermeul, Vince R.; Strickland, Chris E.; Thorne, Paul D.; ...

2014-12-31

The FutureGen 2.0 Project will design and build a first-of-its-kind, near-zero emissions coal-fueled power plant with carbon capture and storage (CCS). To assess storage site performance and meet the regulatory requirements of the Class VI Underground Injection Control (UIC) Program for CO2 Geologic Sequestration, the FutureGen 2.0 project will implement a suite of monitoring technologies designed to 1) evaluate CO2 mass balance and 2) detect any unforeseen loss in CO2 containment. The monitoring program will include direct monitoring of the injection stream and reservoir, and early-leak-detection monitoring directly above the primary confining zone. It will also implement an adaptive monitoringmore » strategy whereby monitoring results are continually evaluated and the monitoring network is modified as required, including the option to drill additional wells in out-years. Wells will be monitored for changes in CO2 concentration and formation pressure, and other geochemical/isotopic signatures that provide indication of CO2 or brine leakage. Indirect geophysical monitoring technologies that were selected for implementation include passive seismic, integrated surface deformation, time-lapse gravity, and pulsed neutron capture logging. Near-surface monitoring approaches that have been initiated include surficial aquifer and surface- water monitoring, soil-gas monitoring, atmospheric monitoring, and hyperspectral data acquisition for assessment of vegetation conditions. Initially, only the collection of baseline data sets is planned; the need for additional near- surface monitoring will be continually evaluated throughout the design and operational phases of the project, and selected approaches may be reinstituted if conditions warrant. Given the current conceptual understanding of the subsurface environment, early and appreciable impacts to near-surface environments are not expected.« less

International intercomparison of measuring instruments for radon/thoron gas and radon short-lived daughter products in the NRPI Prague.

PubMed

Jílek, K; Hýža, M; Kotík, L; Thomas, J; Tomášek, L

2014-07-01

During the 7th European Conference on Protection Against Radon at Home and at Work held in the autumn of 2013 in Prague, the second intercomparison of measuring instruments for radon and its short-lived decay products and the first intercomparison of radon/thoron gas discriminative passive detectors in mix field of radon/thoron were organised by and held at the Natural Radiation Division of the National Radiation Protection Institute (NRPI) in Prague. In total, 14 laboratories from 11 different countries took part in the 2013 NRPI intercomparison. They submitted both continuous monitors for the measurement of radon gas and equivalent equilibrium radon concentration in a big NRPI chamber (48 m3) and sets of passive detectors including radon/thoron discriminative for the measurement of radon gas in the big chamber and thoron gas in a small thoron chamber (150 dm3). © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Gas-driven pump for ground-water samples

USGS Publications Warehouse

Signor, Donald C.

1978-01-01

Observation wells installed for artificial-recharge research and other wells used in different ground-water programs are frequently cased with small-diameter steel pipe. To obtain samples from these small-diameter wells in order to monitor water quality, and to calibrate solute-transport models, a small-diameter pump with unique operating characteristics is required that causes a minimum alternation of samples during field sampling. A small-diameter gas-driven pump was designed and built to obtain water samples from wells of two-inch diameter or larger. The pump is a double-piston type with the following characteristics: (1) The water sample is isolated from the operating gas, (2) no source of electricity is ncessary, (3) operation is continuous, (4) use of compressed gas is efficient, and (5) operation is reliable over extended periods of time. Principles of operation, actual operation techniques, gas-use analyses and operating experience are described. Complete working drawings and a component list are included. Recent modifications and pump construction for high-pressure applications also are described. (Woodard-USGS)

CFD gas distribution analysis for different continuous-miner scrubber redirection configurations

PubMed Central

Zheng, Y.; Organiscak, J.A.; Zhou, L.; Beck, T.W.; Rider, J.P.

2018-01-01

The U.S. National Institute for Occupational Safety and Health (NIOSH)’s Pittsburgh Mining Research Division (PMRD) recently developed a series of models using computational fluid dynamics (CFD) to study gas distribution around a continuous mining machine with various fan-powered flooded bed scrubber discharge configurations in an exhaust curtain working face. CFD models utilizing species transport model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The study illustrates the gas distribution in the slab (second) cut. The following scenarios are considered in this study: 100 percent of the discharge redirected back toward the face on the off-curtain side; 100 percent of the discharge redirected back toward the face, but divided equally to both sides; and 15 percent of the discharge redirected toward the face on the off-curtain side, with 85 percent directed toward the return curtain. These models are compared against a model with a conventional scrubber discharge where air is directed away from the face into the return. The models were validated against experimental data, proving to accurately predict sulfur hexafluoride (SF6) gas levels at four gas monitoring locations. This study includes a predictive simulation examining a 45° scrubber angle compared with the 23° angle for the 100 percent redirected, equally divided case. This paper describes the validation of the CFD models based on experimental data of the gas distribution results. PMID:29375242

CFD gas distribution analysis for different continuous-miner scrubber redirection configurations.

PubMed

Zheng, Y; Organiscak, J A; Zhou, L; Beck, T W; Rider, J P

2017-01-01

The U.S. National Institute for Occupational Safety and Health (NIOSH)'s Pittsburgh Mining Research Division (PMRD) recently developed a series of models using computational fluid dynamics (CFD) to study gas distribution around a continuous mining machine with various fan-powered flooded bed scrubber discharge configurations in an exhaust curtain working face. CFD models utilizing species transport model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The study illustrates the gas distribution in the slab (second) cut. The following scenarios are considered in this study: 100 percent of the discharge redirected back toward the face on the off-curtain side; 100 percent of the discharge redirected back toward the face, but divided equally to both sides; and 15 percent of the discharge redirected toward the face on the off-curtain side, with 85 percent directed toward the return curtain. These models are compared against a model with a conventional scrubber discharge where air is directed away from the face into the return. The models were validated against experimental data, proving to accurately predict sulfur hexafluoride (SF 6 ) gas levels at four gas monitoring locations. This study includes a predictive simulation examining a 45° scrubber angle compared with the 23° angle for the 100 percent redirected, equally divided case. This paper describes the validation of the CFD models based on experimental data of the gas distribution results.

Helium gas purity monitor based on low frequency acoustic resonance

NASA Astrophysics Data System (ADS)

Kasthurirengan, S.; Jacob, S.; Karunanithi, R.; Karthikeyan, A.

1996-05-01

Monitoring gas purity is an important aspect of gas recovery stations where air is usually one of the major impurities. Purity monitors of Katherometric type are commercially available for this purpose. Alternatively, we discuss here a helium gas purity monitor based on acoustic resonance of a cavity at audio frequencies. It measures the purity by monitoring the resonant frequency of a cylindrical cavity filled with the gas under test and excited by conventional telephone transducers fixed at the ends. The use of the latter simplifies the design considerably. The paper discusses the details of the resonant cavity and the electronic circuit along with temperature compensation. The unit has been calibrated with helium gas of known purities. The unit has a response time of the order of 10 minutes and measures the gas purity to an accuracy of 0.02%. The unit has been installed in our helium recovery system and is found to perform satisfactorily.

Insights into the origins of drumbeat earthquakes, periodic low frequency seismicity, and plug degradation from multi-instrument monitoring at Tungurahua volcano, Ecuador, April 2015

NASA Astrophysics Data System (ADS)

Bell, Andrew; Hernandez, Stephen; Gaunt, Elizabeth; Mothes, Patricia; Hidalgo, Silvana; Ruiz, Mario

2016-04-01

Highly-periodic repeating 'drumbeat' earthquakes have been reported from several andesitic and dacitic volcanoes. Physical models for the origin of drumbeat earthquakes incorporate, to different extents, the incremental upward movement of viscous magma. However, the roles played by stick-slip friction, brittle failure, and fluid flow, and the relations between drumbeat earthquakes and other low-frequency seismic signals, remain controversial. Here we report the results of analysis of three weeks of geophysical data recorded during an unrest episode at Tungurahua, an andesitic stratovolcano in Ecuador, during April 2015, by the monitoring network of the Instituto Geofisico of Ecuador. Combined seismic, geodetic, infrasound, and gas monitoring has provided new insights into the origins of periodic low-frequency seismic signals, conduit processes, and the nature of current unrest. Over the three-week period, the relative seismic amplitude (RSAM) correlated closely with short-term deformation rates and gas fluxes. However, the characteristics of the seismic signals, as recorded at a short-period station closest to the summit crater, changed considerably with time. Initially high RSAM and gas fluxes, with modest ash emissions, were associated with continuous and 'pulsed' tremor signals (amplitude modulated, with 30-100 second periods). As activity levels decreased over several days, tremor episodes became increasingly intermittent, and short-lived bursts of low-frequency earthquakes with quasiperiodic inter-event times were observed. Following one day of quiescence, the onset of pronounced low frequency drumbeat earthquakes signalled the resumption of elevated unrest, initially with mean inter-event times of 32 seconds, and later increasing to 74 seconds and longer, with periodicity progressively breaking down over several days. A reduction in RSAM was then followed by one week of persistent, quasiperiodic, longer-duration emergent low-frequency pulses, including 'double events'. The unrest finished with a series of minor explosions and ash emissions, and a reduction in RSAM. None of the seismic events were associated with significant infrasound or ground-coupled acoustic waves. The persistent and steadily evolving periodicity of seismic signals, and contemporaneous inflation-deflation tilt cycle, suggest that incremental upward movement of a viscous magma plug determines the system periodicity, likely controlled by the balance between magma ascent rate, magma compressibility beneath the plug, and resisting forces at the plug margin. However, relations between a range of observations, including waveform similarity, periodicity, and amplitudes of contemporaneous discrete and continuous signals, suggest that the detected seismic signals are predominantly generated by gas flow that is largely decoupled from the magma ascent rate. Signals are generated by both continuous flow through longer-lived pathways, and by gas pulses passing through transient pathways generated by slip at the plug margins. The nature and amplitude of signals is therefore a product of the rate of gas flux and the evolving state of the degassing pathway, controlled in part by degradation and healing of the plug margins.

Land Disturbance Associated with Oil and Gas Development and Effects of Development-Related Land Disturbance on Dissolved-Solids Loads in Streams in the Upper Colorado River Basin, 1991, 2007, and 2025

USGS Publications Warehouse

Buto, Susan G.; Kenney, Terry A.; Gerner, Steven J.

2010-01-01

Oil and gas resource development in the Upper Colorado River Basin (UCRB) has increased substantially since the year 2000. The UCRB encompasses several significant oil and gas producing areas that have the potential for continued oil and gas resource development. Land disturbance associated with oil and gas resource development is caused by activities related to constructing drill pads to contain drilling and well maintenance equipment and roads to access the drill pad. Land disturbed by oil and gas development has the potential to cause increased erosion, stream degradation, habitat fragmentation and alteration, and increase public use of areas that may be environmentally sensitive. Land disturbance resulting from oil and gas resource development has not been monitored and mapped on a regional scale in the UCRB. However, information on the location and age of oil and gas wells in the UCRB is available. These data combined with geographic data analysis and modeling techniques were used to estimate the total area of disturbed land associated with oil and gas resource development in 1991 and in 2007 in the UCRB. Additional information about anticipated oil and gas development in the UCRB was used to project land disturbance to the year 2025. Results of the analysis indicate that approximately 117,500 acres (183 mi2) of total land disturbance was associated with drill pads and related roads in the UCRB in 1991. The estimated area of disturbed land associated with oil and gas development increased 53 percent to 179,400 acres (280 mi2) in 2007. Projecting oil and gas development through 2025 results in a potential near doubling of the land surface disturbance to approximately 319,300 acres (500 mi2). Estimated land disturbance for 1991 and 2007 were input to a contaminant transport model developed for the UCRB to assess the statistical significance of energy-related land disturbance to contributing dissolved solids to basin streams. The statistical assessment was an observational study based on an existing model and available water-quality monitoring data for the basin. No new data were collected for the analysis. The source coefficient calibrated for the disturbed lands associated with oil and gas development in 2007 was zero, which indicated that estimated land disturbance from oil and gas development is not statistically significant in explaining dissolved solids in UCRB streams. The lack of significance in the contaminant transport modeling framework may be due to the amount of available monitoring data, the spatial distribution of monitoring sites with respect to land disturbance, or the overall quantity of land disturbance associated with oil and gas development basin wide. Finally, dissolved-solids loads derived from natural landscapes may be similar to loads derived from lands disturbed by oil and gas resource development. The model recalibration done for this study confirms calibration results from Kenney and others (2009): the most significant contributor to dissolved solids in the UCRB is irrigated agricultural land, which covers an area substantially larger than the estimated area disturbed by oil and gas development and is subjected to artificially applied water.

Origins and trends in ethane and propane in the United Kingdom from 1993 to 2012

NASA Astrophysics Data System (ADS)

Derwent, R. G.; Field, R. A.; Dumitrean, P.; Murrells, T. P.; Telling, S. P.

2017-05-01

Continuous, high frequency in situ observations of ethane and propane began in the United Kingdom in 1993 and have continued through to the present day at a range of kerbside, urban background and rural locations. Whilst other monitored C2 - C8 hydrocarbons have shown dramatic declines in concentrations by close to or over an order of magnitude, ethane and propane levels have remained at or close to their 1993 values. Urban ethane sources appear to be dominated by natural gas leakage. Background levels of ethane associated with long range transport are rising. However, natural gas leakage is not the sole source of urban propane. Oil and gas operations lead to elevated propane levels in urban centres when important refinery operations are located nearby. Weekend versus weekday average diurnal curves for ethane and propane at an urban background site in London show the importance of natural gas leakage for both ethane and propane, and road traffic sources for propane. The road traffic source of propane was tentatively identified as arising from petrol-engined motor vehicle refuelling and showed a strong downwards trend at the long-running urban background and rural sites. The natural gas leakage source of ethane and propane in the observations exhibits an upwards trend whereas that in the UK emission inventory trends downwards. Also, inventory emissions for natural gas leakage appeared to be significantly underestimated compared with the observations. In addition, the observed ethane to propane ratio found here for natural gas leakage strongly disagreed with the inventory ratio.

Atomizing, continuous, water monitoring module

DOEpatents

Thompson, C.V.; Wise, M.B.

1997-07-08

A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid. 3 figs.

Atomizing, continuous, water monitoring module

DOEpatents

Thompson, Cyril V.; Wise, Marcus B.

1997-01-01

A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid.

40 CFR 63.1023 - Instrument and sensory monitoring for leaks.

Code of Federal Regulations, 2012 CFR

2012-07-01

... be used during that day's monitoring. (ii) A calibration gas other than methane in air may be used if...) Instrument monitoring for leaks. (i) Valves in gas and vapor service and in light liquid service shall be....1026(b). (iii) Connectors in gas and vapor service and in light liquid service shall be monitored...

40 CFR 63.1023 - Instrument and sensory monitoring for leaks.

Code of Federal Regulations, 2014 CFR

2014-07-01

... be used during that day's monitoring. (ii) A calibration gas other than methane in air may be used if...) Instrument monitoring for leaks. (i) Valves in gas and vapor service and in light liquid service shall be....1026(b). (iii) Connectors in gas and vapor service and in light liquid service shall be monitored...

[Group A streptococcus-induced toxic shock syndrome in pregnancy: a case report of cesarean section].

PubMed

Yamada, Kumiko; Fukuda, Taeko; Kimura, Maiko; Hagiya, Keiichi; Danmura, Masato; Nakayama, Shin; Ogura, Tsuyoshi; Tanaka, Makoto

2012-12-01

Group A streptococcus (GAS)-induced toxic shock syndrome (TSS) in pregnancy is rare, but its clinical course is fulminant. The mortality rates of mother and fetus are reported to be 58 and 66%, respectively. We report a case of GAS-TSS after cesarean section. A 38-year-old pregnant woman of 38 weeks gestation was admitted to our hospital because of vomiting, fever of 39 degrees C, and continuous abdominal pain with scanty genital bleeding. She had complained of sore throat several days before. One hour after admission, external fetal monitoring revealed periodic pulse deceleration to 90 x beats min(-1). The emergent cesarean section was performed under general anesthesia. Approximately 8 hours after the cesarean section, she developed coma, shock and respiratory insufficiency requiring intubation. Streptococcus pyogens were isolated from her blood sample and the patient met criteria for GAS-TSS. She was treated with antibiotics (penicillin and clindamycin), antithrombin III, recomodulin, catecholamins, and continuous hemodialysis with filtration of toxins. Although the patient recovered and was discharged on 63rd day, the infant died on postpartum day 4. Early recognition and intensive treatment for GAS is recommended in a late stage pregnancy with an episode of sore throat, vomiting, high fever, strong labor pain, and DIC signs.

Unconventional Reservoirs: Ideas to Commercialization

NASA Astrophysics Data System (ADS)

Tinker, S. W.

2015-12-01

There is no shortage of coal, oil, and natural gas in the world. What are sometimes in short supply are fresh ideas. Scientific innovation combined with continued advances in drilling and completion technology revitalized the natural gas industry in North America by making production from shale economic. Similar advances are now happening in shale oil. The convergence of ideas and technology has created a commercial environment in which unconventional reservoirs could supply natural gas to the North American consumer for 50 years or more. And, although not as far along in terms of resource development, oil from the Eagle Ford and Bakken Shales and the oil sands in Alberta could have a similar impact. Without advanced horizontal drilling, geosteering, staged hydraulic-fracture stimulation, synthetic and natural proppants, evolution of hydraulic fluid chemistry, and high-end monitoring and simulation, many of these plays would not exist. Yet drilling and completion technology cannot stand alone. Also required for success are creative thinking, favorable economics, and a tolerance for risk by operators. Current understanding and completion practices will leave upwards of 80% of oil and natural gas in the shale reservoirs. The opportunity to enhance recovery through advanced reservoir understanding and imaging, as well as through recompletions and infill drilling, is considerable. The path from ideas to commercialization will continue to provide economic results in unconventional reservoirs.

A Gas Chromatographic Continuous Emissions Monitoring System for the Determination of VOCs and HAPs.

PubMed

Coleman, William M; Gordon, Bert M

1996-01-01

This article describes a new gas chromatography-based emissions monitoring system for measuring volatile organic compounds (VOCs) and hazardous air pollutants (HAPs). The system is composed of a dual-column gas chromatograph equipped with thermal conductivity detectors, in which separation is optimized for fast chromatography. The system has the necessary valving for stream selection, which allows automatic calibration of the system at predetermined times and successive measurement of individual VOCs before and after a control device. Nine different VOCs (two of which are HAPs), plus methane (CH4) and carbon dioxide (CO2) are separated and quantified every two minutes. The accuracy and precision of this system has been demonstrated to be greater than 95%. The system employs a mass flow measurement device and also calculates and displays processed emission data, such as control device efficiency and total weight emitted during given time periods. Two such systems have been operational for one year in two separate gravure printing facilities; minimal upkeep is required, about one hour per month. One of these systems, used before and after a carbon adsorber, has been approved by the pertinent local permitting authority.

A Lab Assembled Microcontroller-Based Sensor Module for Continuous Oxygen Measurement in Portable Hypoxia Chambers

PubMed Central

Mathupala, Saroj P.; Kiousis, Sam; Szerlip, Nicholas J.

2016-01-01

Background Hypoxia-based cell culture experiments are routine and essential components of in vitro cancer research. Most laboratories use low-cost portable modular chambers to achieve hypoxic conditions for cell cultures, where the sealed chambers are purged with a gas mixture of preset O2 concentration. Studies are conducted under the assumption that hypoxia remains unaltered throughout the 48 to 72 hour duration of such experiments. Since these chambers lack any sensor or detection system to monitor gas-phase O2, the cell-based data tend to be non-uniform due to the ad hoc nature of the experimental setup. Methodology With the availability of low-cost open-source microcontroller-based electronic project kits, it is now possible for researchers to program these with easy-to-use software, link them to sensors, and place them in basic scientific apparatus to monitor and record experimental parameters. We report here the design and construction of a small-footprint kit for continuous measurement and recording of O2 concentration in modular hypoxia chambers. The low-cost assembly (US$135) consists of an Arduino-based microcontroller, data-logging freeware, and a factory pre-calibrated miniature O2 sensor. A small, intuitive software program was written by the authors to control the data input and output. The basic nature of the kit will enable any student in biology with minimal experience in hobby-electronics to assemble the system and edit the program parameters to suit individual experimental conditions. Results/Conclusions We show the kit’s utility and stability of data output via a series of hypoxia experiments. The studies also demonstrated the critical need to monitor and adjust gas-phase O2 concentration during hypoxia-based experiments to prevent experimental errors or failure due to partial loss of hypoxia. Thus, incorporating the sensor-microcontroller module to a portable hypoxia chamber provides a researcher a capability that was previously available only to labs with access to sophisticated (and expensive) cell culture incubators. PMID:26862760

A Lab Assembled Microcontroller-Based Sensor Module for Continuous Oxygen Measurement in Portable Hypoxia Chambers.

PubMed

Mathupala, Saroj P; Kiousis, Sam; Szerlip, Nicholas J

2016-01-01

Hypoxia-based cell culture experiments are routine and essential components of in vitro cancer research. Most laboratories use low-cost portable modular chambers to achieve hypoxic conditions for cell cultures, where the sealed chambers are purged with a gas mixture of preset O2 concentration. Studies are conducted under the assumption that hypoxia remains unaltered throughout the 48 to 72 hour duration of such experiments. Since these chambers lack any sensor or detection system to monitor gas-phase O2, the cell-based data tend to be non-uniform due to the ad hoc nature of the experimental setup. With the availability of low-cost open-source microcontroller-based electronic project kits, it is now possible for researchers to program these with easy-to-use software, link them to sensors, and place them in basic scientific apparatus to monitor and record experimental parameters. We report here the design and construction of a small-footprint kit for continuous measurement and recording of O2 concentration in modular hypoxia chambers. The low-cost assembly (US$135) consists of an Arduino-based microcontroller, data-logging freeware, and a factory pre-calibrated miniature O2 sensor. A small, intuitive software program was written by the authors to control the data input and output. The basic nature of the kit will enable any student in biology with minimal experience in hobby-electronics to assemble the system and edit the program parameters to suit individual experimental conditions. We show the kit's utility and stability of data output via a series of hypoxia experiments. The studies also demonstrated the critical need to monitor and adjust gas-phase O2 concentration during hypoxia-based experiments to prevent experimental errors or failure due to partial loss of hypoxia. Thus, incorporating the sensor-microcontroller module to a portable hypoxia chamber provides a researcher a capability that was previously available only to labs with access to sophisticated (and expensive) cell culture incubators.

Biological treatment of habitation waste streams using full scale MABRs

NASA Astrophysics Data System (ADS)

Jackson, William; Barta, Daniel J.; Morse, Audra; Christenson, Dylan; Sevanthi, Ritesh

Recycling waste water is a critical step to support sustainable long term habitation in space. Water is one of the largest contributors to life support requirements. In closed loop life support systems, membrane aerated biological reactors (MABRs) can reduce the dissolved organic carbon (DOC) and ammonia (NH3) concentration as well as decrease the pH, leading to a more stable solution with less potential to support biological growth or promote carryover of unionized ammonia as well as producing a higher quality brine. Over the last three years we have operated 3 full size MABRs ( 120L) treating a habitation type waste stream composed of urine, hygiene, and laundry water. The reactors varied in the specific surface area (260, 200, and 150 m2/m3) available for biofilm growth and gas transfer. The liquid side system was continually monitored for pH, TDS, and DO, and the influent and effluent monitored daily for DOC, TN, NOx, and NH4. The gas side system was continuously monitored for O2, CO2, and N2O in the effluent gas as well as pressure and flow rates. These systems have all demonstrated greater than 90% DOC reductions and ammonium conversion rates of 50-70% over a range of loading rates with effluent pH from 5-7.5. We have evaluated. In addition, to evaluating the impact of loading rates (10-70 l/d) we have also evaluated the impact of forced hibernation, the use of pure O2 on performance, the impact of pressurize operation to prevent de-gassing of N2 and to promote higher O2 transfer and a discontinuous feeding cycle to allow integration with desalination. Our analysis includes quantification of consumables (power and O2), waste products such as CO2 and N2O as well as solids production. Our results support the use of biological reactors to treat habitation waste streams as an alternative to the use of pretreatment and desalination alone.

Onboard measurement system of atmospheric carbon monoxide in the Pacific by voluntary observing ships

NASA Astrophysics Data System (ADS)

Nara, H.; Tanimoto, H.; Nojiri, Y.; Mukai, H.; Machida, T.; Tohjima, Y.

2011-11-01

Long-term monitoring of carbon monoxide (CO) mixing ratios in the atmosphere over the Pacific Ocean is being carried out on commercial cargo vessels participating in the National Institute for Environmental Studies Voluntary Observing Ships program. The program provides a regular platform for measurement of atmospheric CO along four cruise routes: from Japan to Oceania, the United States, Canada, and Southeast Asia. Flask samples are collected during every cruise for subsequent analysis in the laboratory, and in 2005, continuous shipboard CO measurements were initiated on three of the routes. Here, we describe the system we developed for onboard measurement of CO mixing ratios with a commercially available gas filter correlation CO analyzer. The fully automated system measures CO in ambient air, and the detector sensitivity and background signals are calibrated by referencing the measurements to a CO-in-air standard gas (~1 ppmv) and to CO-free air scrubbed with a catalyst, respectively. We examined the artificial production of CO in the high-pressure working gas standards during storage by referencing the measurements to CO standard gases maintained as our primary scale before and after use on the ships. The onboard performance of the continuous CO measurement system was evaluated by comparing its data with data from laboratory analyses of flask samples using gas chromatography with a reduction gas detector. The reasonably good consistency between the two independent measurement methods demonstrated the good performance of both methods over the course of 3-5 years. The continuous measurement system was more useful than the flask sampling method for regionally polluted air masses, which were often encountered on Southeast Asian cruises.

Onboard measurement system of atmospheric carbon monoxide over the Pacific Ocean by voluntary observing ships

NASA Astrophysics Data System (ADS)

Nara, H.; Tanimoto, H.; Nojiri, Y.; Mukai, H.; Machida, T.; Tohjima, Y.

2011-07-01

Long-term monitoring of carbon monoxide (CO) mixing ratios in the atmosphere over the Pacific Ocean is being carried out on commercial cargo vessels participating in the National Institute for Environmental Studies Voluntary Observing Ships program. The program provides a regular platform for measurement of atmospheric CO along four cruising routes: from Japan to Oceania, from Japan to the United States, from Japan to Canada, and from Japan to Southeast Asia. Flask samples are collected during every cruise for subsequent analysis in the laboratory, and in 2005, continuous shipboard CO measurements were initiated on three of the routes. Here, we describe the system we developed for onboard measurement of CO mixing ratios with a commercially available gas filter correlation CO analyzer. The fully automated system measures CO in ambient air, and the detector sensitivity and background signals are calibrated by referencing the measurements to a CO-in-air standard gas (~1 ppmv) and to CO-free air scrubbed with a catalyst, respectively. We examined the artificial production of CO in the high-pressure working gas standards (CO balanced with purified air at ppmv levels) during storage by referencing the measurements to CO standard gases maintained as our primary scale before and after use on the ships. The onboard performance of the continuous CO measurement system was evaluated by comparing its data with data from laboratory analyses of flask samples using gas chromatography with a reduction gas detector. The reasonably good consistency between the two independent measurement methods demonstrated the good performance of both methods over the course of 3-5 yr. The continuous measurement system was more useful than the flask sampling method for regionally polluted air masses, which were often encountered on Southeast Asian cruises.

Bird interactions with offshore oil and gas platforms: review of impacts and monitoring techniques.

PubMed

Ronconi, Robert A; Allard, Karel A; Taylor, Philip D

2015-01-01

Thousands of oil and gas platforms are currently operating in offshore waters globally, and this industry is expected to expand in coming decades. Although the potential environmental impacts of offshore oil and gas activities are widely recognized, there is limited understanding of their impacts on migratory and resident birds. A literature review identified 24 studies and reports of bird-platform interactions, most being qualitative and half having been peer-reviewed. The most frequently observed effect, for seabirds and landbirds, is attraction and sometimes collisions associated with lights and flares; episodic events have caused the deaths of hundreds or even thousands of birds. Though typically unpredictable, anecdotally, it is known that poor weather, such as fog, precipitation and low cloud cover, can exacerbate the effect of nocturnal attraction to lights, especially when coincidental with bird migrations. Other effects include provision of foraging and roosting opportunities, increased exposure to oil and hazardous environments, increased exposure to predators, or repulsion from feeding sites. Current approaches to monitoring birds at offshore platforms have focused on observer-based methods which can offer species-level bird identification, quantify seasonal patterns of relative abundance and distribution, and document avian mortality events and underlying factors. Observer-based monitoring is time-intensive, limited in spatial and temporal coverage, and suffers without clear protocols and when not conducted by trained, independent observers. These difficulties are exacerbated because deleterious bird-platform interaction is episodic and likely requires the coincidence of multiple factors (e.g., darkness, cloud, fog, rain conditions, occurrence of birds in vicinity). Collectively, these considerations suggest a need to implement supplemental systems for monitoring bird activities around offshore platforms. Instrument-based approaches, such as radar, cameras, acoustic recordings, and telemetry, hold promise for continuous monitoring. Recommendations are provided for a rigorous and comprehensive monitoring approach within an adaptive management framework. Copyright © 2014 Elsevier Ltd. All rights reserved.

[Evaluation of vaporizers by anesthetic gas monitors corrected with a new method for preparation of calibration gases].

PubMed

Kurashiki, T

1996-11-01

For resolving the discrepancy of concentrations found among anesthetic gas monitors, the author proposed a new method using a vaporizer as a standard anesthetic gas generator for calibration. In this method, the carrier gas volume is measured by a mass flow meter (SEF-510 + FI-101) installed before the inlet of the vaporizer. The vaporized weight of volatile anesthetic agent is simultaneously measured by an electronic force balance (E12000S), on which the vaporizer is placed directly. The molar percent of the anesthetic is calculated using these data and is transformed into the volume percent. These gases discharging from the vaporizer are utilized for calibrating anesthetic gas monitors. These monitors are normalized by the linear equation describing the relationship between concentrations of calibration gases and readings of the anesthetic gas monitors. By using normalized monitors, flow rate-concentration performance curves of several anesthetic vaporizers were obtained. The author concludes that this method can serve as a standard in evaluating anesthetic vaporizers.

In-airway molecular flow sensing: A new technology for continuous, noninvasive monitoring of oxygen consumption in critical care.

PubMed

Ciaffoni, Luca; O'Neill, David P; Couper, John H; Ritchie, Grant A D; Hancock, Gus; Robbins, Peter A

2016-08-01

There are no satisfactory methods for monitoring oxygen consumption in critical care. To address this, we adapted laser absorption spectroscopy to provide measurements of O2, CO2, and water vapor within the airway every 10 ms. The analyzer is integrated within a novel respiratory flow meter that is an order of magnitude more precise than other flow meters. Such precision, coupled with the accurate alignment of gas concentrations with respiratory flow, makes possible the determination of O2 consumption by direct integration over time of the product of O2 concentration and flow. The precision is illustrated by integrating the balance gas (N2 plus Ar) flow and showing that this exchange was near zero. Measured O2 consumption changed by <5% between air and O2 breathing. Clinical capability was illustrated by recording O2 consumption during an aortic aneurysm repair. This device now makes easy, accurate, and noninvasive measurement of O2 consumption for intubated patients in critical care possible.

In-airway molecular flow sensing: A new technology for continuous, noninvasive monitoring of oxygen consumption in critical care

PubMed Central

Ciaffoni, Luca; O’Neill, David P.; Couper, John H.; Ritchie, Grant A. D.; Hancock, Gus; Robbins, Peter A.

2016-01-01

There are no satisfactory methods for monitoring oxygen consumption in critical care. To address this, we adapted laser absorption spectroscopy to provide measurements of O2, CO2, and water vapor within the airway every 10 ms. The analyzer is integrated within a novel respiratory flow meter that is an order of magnitude more precise than other flow meters. Such precision, coupled with the accurate alignment of gas concentrations with respiratory flow, makes possible the determination of O2 consumption by direct integration over time of the product of O2 concentration and flow. The precision is illustrated by integrating the balance gas (N2 plus Ar) flow and showing that this exchange was near zero. Measured O2 consumption changed by <5% between air and O2 breathing. Clinical capability was illustrated by recording O2 consumption during an aortic aneurysm repair. This device now makes easy, accurate, and noninvasive measurement of O2 consumption for intubated patients in critical care possible. PMID:27532048

Multi-species trace gas sensing with dual-wavelength QCLs

NASA Astrophysics Data System (ADS)

Hundt, P. Morten; Tuzson, Béla; Aseev, Oleg; Liu, Chang; Scheidegger, Philipp; Looser, Herbert; Kapsalidis, Filippos; Shahmohammadi, Mehran; Faist, Jérôme; Emmenegger, Lukas

2018-06-01

Instrumentation for environmental monitoring of gaseous pollutants and greenhouse gases tends to be complex, expensive, and energy demanding, because every compound measured relies on a specific analytical technique. This work demonstrates an alternative approach based on mid-infrared laser absorption spectroscopy with dual-wavelength quantum cascade lasers (QCLs). The combination of two dual- and one single-DFB QCL yields high-precision measurements of CO (0.08 ppb), CO2 (100 ppb), NH3 (0.02 ppb), NO (0.4 ppb), NO2 (0.1 ppb), N2O (0.045 ppb), and O3 (0.11 ppb) simultaneously in a compact setup (45 × 45 cm2). The lasers are driven time-multiplexed in intermittent continuous wave mode with a repetition rate of 1 kHz. The individual spectra are real-time averaged (1 s) by an FPGA-based data acquisition system. The instrument was assessed for environmental monitoring and benchmarked with reference instrumentation to demonstrate its potential for compact multi-species trace gas sensing.

Multi-Gas Monitor (MGM)

NASA Technical Reports Server (NTRS)

Pilgrim, Jeff; Limero, Thomas

2015-01-01

Multi-Gas Monitor is a flight experiment, a technology demonstration to test the ability of tunable diode laser spectroscopy based instrument to stay in calibration long term and follow events and dynamics occurring with the cabin atmosphere. MGM measures 4 gases: oxygen, carbon monoxide, ammonia and water vapor, as well as temperature and pressure. This month marked one year of successful and continuous MGM operation on ISS. The crew successfully tested the ammonia channel using a commercially available inhalant. MGM has detected some interesting dynamics inside Japanese Experiment Module (JEM) as a result of CO2 thruster firings from the SPHERES/RINGS payload and water spikes from dry out cycling of the JEM heat exchangers. Results to date have given us high confidence in the technology such that we believe this could have applications in the energy and medical sectors. This presentation will summarize the testing and results of the unit on ISS and suggest areas of use within the energy and medical arenas.

Integration of continuous-flow sampling with microchip electrophoresis using poly(dimethylsiloxane)-based valves in a reversibly sealed device.

PubMed

Li, Michelle W; Martin, R Scott

2007-07-01

Here we describe a reversibly sealed microchip device that incorporates poly(dimethylsiloxane) (PDMS)-based valves for the rapid injection of analytes from a continuously flowing stream into a channel network for analysis with microchip electrophoresis. The microchip was reversibly sealed to a PDMS-coated glass substrate and microbore tubing was used for the introduction of gas and fluids to the microchip device. Two pneumatic valves were incorporated into the design and actuated on the order of hundreds of milliseconds, allowing analyte from a continuously flowing sampling stream to be injected into an electrophoresis separation channel. The device was characterized in terms of the valve actuation time and pushback voltage. It was also found that the addition of sodium dodecyl sulfate (SDS) to the buffer system greatly increased the reproducibility of the injection scheme and enabled the analysis of amino acids derivatized with naphthalene-2,3-dicarboxaldehyde/cyanide. Results from continuous injections of a 0.39 nL fluorescein plug into the optimized system showed that the injection process was reproducible (RSD of 0.7%, n = 10). Studies also showed that the device was capable of monitoring off-chip changes in concentration with a device lag time of 90 s. Finally, the ability of the device to rapidly monitor on-chip concentration changes was demonstrated by continually sampling from an analyte plug that was derivatized upstream from the electrophoresis/continuous flow interface. A reversibly sealed device of this type will be useful for the continuous monitoring and analysis of processes that occur either off-chip (such as microdialysis sampling) or on-chip from other integrated functions.

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2014 CFR

2014-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2012 CFR

2012-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2013 CFR

2013-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2011 CFR

2011-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

METHOD AND APPARATUS FOR EXAMINING FUEL ELEMENTS FOR LEAKAGE

DOEpatents

Smith, R.R.; Echo, M.W.; Doe, C.B.

1963-12-31

A process and a device for the continuous monitoring of fuel elements while in use in a liquid-metal-cooled, argonblanketed nuclear reactor are presented. A fraction of the argon gas is withdrawn, contacted with a negative electrical charge for attraction of any alkali metal formed from argon by neutron reaction, and recycled into the reactor. The electrical charge is introduced into water, and the water is examined for radioactive alkali metals. (AEC)

Effects of shallow natural gas well structures and associated roads on grassland songbird reproductive success in Alberta, Canada

PubMed Central

Koper, Nicola

2017-01-01

Grassland songbird populations across North America have experienced dramatic population declines due to habitat loss and degradation. In Canada, energy development continues to fragment and disturb prairie habitat, but effects of oil and gas development on reproductive success of songbirds in North American mixed-grass prairies remains largely unknown. From 2010–2012, in southeastern Alberta, Canada, we monitored 257 nests of two ground-nesting grassland songbird species, Savannah sparrow (Passerculus sandwichensis) and chestnut-collared longspur (Calcarius ornatus). Nest locations varied with proximity to and density of conventional shallow gas well structures and associated roads in forty-two 258-ha mixed-grass prairie sites. We estimated the probabilities of nest success and clutch size relative to gas well structures and roads. There was little effect of distance to or density of gas well structure on nest success; however, Savannah sparrow experienced lower nest success near roads. Clutch sizes were lower near gas well structures and cattle water sources. Minimizing habitat disturbance surrounding gas well structures, and reducing abundance of roads and trails, would help minimize impacts on reproductive success for some grassland songbirds. PMID:28355241

Effects of shallow natural gas well structures and associated roads on grassland songbird reproductive success in Alberta, Canada.

PubMed

Yoo, Jenny; Koper, Nicola

2017-01-01

Grassland songbird populations across North America have experienced dramatic population declines due to habitat loss and degradation. In Canada, energy development continues to fragment and disturb prairie habitat, but effects of oil and gas development on reproductive success of songbirds in North American mixed-grass prairies remains largely unknown. From 2010-2012, in southeastern Alberta, Canada, we monitored 257 nests of two ground-nesting grassland songbird species, Savannah sparrow (Passerculus sandwichensis) and chestnut-collared longspur (Calcarius ornatus). Nest locations varied with proximity to and density of conventional shallow gas well structures and associated roads in forty-two 258-ha mixed-grass prairie sites. We estimated the probabilities of nest success and clutch size relative to gas well structures and roads. There was little effect of distance to or density of gas well structure on nest success; however, Savannah sparrow experienced lower nest success near roads. Clutch sizes were lower near gas well structures and cattle water sources. Minimizing habitat disturbance surrounding gas well structures, and reducing abundance of roads and trails, would help minimize impacts on reproductive success for some grassland songbirds.

78 FR 11585 - Greenhouse Gas Reporting Rule: Revision to Best Available Monitoring Method Request Submission...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-19

... facilities. 211 Extractors of crude petroleum and natural gas. 211112 Natural gas liquid extraction... Greenhouse Gas Reporting Rule: Revision to Best Available Monitoring Method Request Submission Deadline for Petroleum and Natural Gas Systems Source Category AGENCY: Environmental Protection Agency (EPA). ACTION...

Construction of a newly designed small-size mass spectrometer for helium isotope analysis: toward the continuous monitoring of (3)he/(4)he ratios in natural fluids.

PubMed

Bajo, Ken-Ichi; Sumino, Hirochika; Toyoda, Michisato; Okazaki, Ryuji; Osawa, Takahito; Ishihara, Morio; Katakuse, Itsuo; Notsu, Kenji; Igarashi, George; Nagao, Keisuke

2012-01-01

The construction of a small-size, magnetic sector, single focusing mass spectrometer (He-MS) for the continuous, on-site monitoring of He isotope ratios ((3)He/(4)He) is described. The instrument is capable of measuring (4)He/(20)Ne ratios dissolved in several different types of natural fluids of geochemical interest, such as groundwater and gas from hot springs, volcanoes and gas well fields. The ion optics of He-MS was designed using an ion trajectory simulation program "TRIO," which permits the simultaneous measurement of (3)He and (4)He with a double collector system under a mass resolution power (M/ΔM) of >700. The presently attained specifications of He-MS are; (1) a mass resolving power of ca. 430, sufficient to separate (3)He(+) from interfering ions, HD(+) and H3 (+), (2) ultra-high vacuum conditions down to 3×10(-8) Pa, and (3) a sufficiently high sensitivity to permit amounts of (3)He to be detected at levels as small as 10(-13) cm(3) STP (3×10(6) atoms). Long term stability for (3)He/(4)He analysis was examined by measuring the (3)He/(4)He standard gas (HESJ) and atmospheric He, resulting in ∼3% reproducibility and ≤5% experimental error for various amounts of atmospheric He from 0.3 to 2.3×10(-6) cm(3) STP introduced into the instrument. A dynamic range of measurable (3)He/(4)He ratios with He-MS is greater than 10(3) which was determined by measuring various types of natural fluid samples from continental gas (with a low (3)He/(4)He ratio down to 2×10(-8)) to volcanic gas (with a high (3)He/(4)He ratio up to 3×10(-5)). The accuracy and precision of (3)He/(4)He and (4)He/(20)Ne ratios were evaluated by comparing the values with those measured using well established noble gas mass spectrometers (modified VG5400/MS-III and -IV) in our laboratory, and were found to be in good agreement within analytical errors. Usefulness of the selective extraction of He from water/gas using a high permeability of He through a silica glass wall at high temperature (700°C) is demonstrated.

Monitoring Welding-Gas Quality

NASA Technical Reports Server (NTRS)

Huddleston, Kevin L.

1988-01-01

System monitors welding gas to ensure characteristics within predetermined values. Responds to changes that might go unnoticed by human operator and acts quickly to prevent weld defects. Electronic pressure controller employs various amounts of gain, equalization, and compensation to respond to changes in gas-supply pressure. Works in conjuction with pressure/oxygen/moisture monitor.

Western Canada study of animal health effects associated with exposure to emissions from oil and natural gas field facilities. Study design and data collection III. Methods of assessing animal exposure to contaminants from the oil and gas industry.

PubMed

Waldner, Cheryl L

2008-01-01

Researchers measured exposure to oil and gas industry emissions in 205 cow-calf herds located in Western Canada. They measured airborne concentrations of sulfur dioxide, hydrogen sulfide, and volatile organic compounds with passive monitors placed in each pasture, wintering, or calving area that contained study animals from the start of the breeding season in the spring of 2001 until June 30, 2002. Researchers continued air monitoring in a subset of herds to the end of the study in fall 2002. Each sampling device was exposed for 1 month and then shipped to the laboratory for analysis. New samplers were installed and the shelters relocated, as necessary, to follow the movements of herd-management groups between pastures. Researchers linked the results of the air-monitoring analysis to individual animals for the relevant month. For the 205 herds examined at pregnancy testing in 2001, monthly mean exposures on the basis of all available data were as follows: sulfur dioxide, geometric mean (GM)=0.5 ppb, geometric standard deviation (GSD)=2.2; hydrogen sulfide, GM=0.14 ppb, GSD=2.3; benzene, GM=0.247 microg/m3, GSD=2.5; and toluene, GM=0.236 microg/m3, GSD=2.7. Benzene and toluene were surrogates for volatile organic compound exposure. In addition to passive measurements of air quality, researchers obtained data from provincial regulatory agencies on the density of oil and gas field facilities and on flaring and venting from the surrounding facilities. They developed the data into additional measures of exposure that were linked to each animal at each location for each month of the study.

Ultra-sensitive Trace-Water Optical Sensor with In situ- synthesized Metal-Organic Framework in Glass Paper.

PubMed

Ohira, Shin-Ichi; Nakamura, Nao; Endo, Masaaki; Miki, Yusuke; Hirose, Yasuo; Toda, Kei

2018-01-01

Monitoring of trace water in industrial gases is strongly recommended because contaminants cause serious problems during use, especially in the semiconductor industry. An ultra-sensitive trace-water sensor was developed with an in situ-synthesized metal-organic framework as the sensing material. The sample gas is passed through the sensing membrane and efficiently and rapidly collected by the sensing material in the newly designed gas collection/detection cell. The sensing membrane, glass paper impregnated with copper 1,3,5-benzenetricarboxylate (Cu-BTC), is also newly developed. The amount and density of the sensing material in the sensing membrane must be well balanced to achieve rapid and sensitive responses. In the present study, Cu-BTC was synthesized in situ in glass paper. The developed system gave high sensing performances with a limit of detection (signal/noise ratio = 3) of 9 parts per billion by volume (ppbv) H 2 O and a 90% response time of 86 s for 200 ppbv H 2 O. The reproducibility of the responses within and between lots had relative standard deviations for 500 ppbv H 2 O of 0.8% (n = 10) and 1.5% (n = 3), respectively. The long-term (2 weeks) stability was 7.3% for 400 ppbv H 2 O and one-year continuous monitoring test showed the sensitivity change of <∼3% before and after the study. Furthermore, the system response was in good agreement with the response achieved in cavity ring-down spectroscopy. These performances are sufficient for monitoring trace water in industrial gases. The integrated system with light and gas transparent structure for gas collection/absorbance detection can also be used for other target gases, using specific metal-organic frameworks.

Evaluation of low-cost electro-chemical sensors for environmental monitoring of ozone, nitrogen dioxide, and carbon monoxide.

PubMed

Afshar-Mohajer, Nima; Zuidema, Christopher; Sousan, Sinan; Hallett, Laura; Tatum, Marcus; Rule, Ana M; Thomas, Geb; Peters, Thomas M; Koehler, Kirsten

2018-02-01

Development of an air quality monitoring network with high spatio-temporal resolution requires installation of a large number of air pollutant monitors. However, state-of-the-art monitors are costly and may not be compatible with wireless data logging systems. In this study, low-cost electro-chemical sensors manufactured by Alphasense Ltd. for detection of CO and oxidative gases (predominantly O 3 and NO 2 ) were evaluated. The voltages from three oxidative gas sensors and three CO sensors were recorded every 2.5 sec when exposed to controlled gas concentrations in a 0.125-m 3 acrylic glass chamber. Electro-chemical sensors for detection of oxidative gases demonstrated sensitivity to both NO 2 and O 3 with similar voltages recorded when exposed to equivalent environmental concentrations of NO 2 or O 3 gases, when evaluated separately. There was a strong linear relationship between the recorded voltages and target concentrations of oxidative gases (R 2 > 0.98) over a wide range of concentrations. Although a strong linear relationship was also observed for CO concentrations below 12 ppm, a saturation effect was observed wherein the voltage only changes minimally for higher CO concentrations (12-50 ppm). The nonlinear behavior of the CO sensors implied their unsuitability for environments where high CO concentrations are expected. Using a manufacturer-supplied shroud, sensors were tested at 2 different flow rates (0.25 and 0.5 Lpm) to mimic field calibration of the sensors with zero air and a span gas concentration (2 ppm NO2 or 15 ppm CO). As with all electrochemical sensors, the tested devices were subject to drift with a bias up to 20% after 9 months of continuous operation. Alphasense CO sensors were found to be a proper choice for occupational and environmental CO monitoring with maximum concentration of 12 ppm, especially due to the field-ready calibration capability. Alphasense oxidative gas sensors are usable only if it is valuable to know the sum of the NO 2 and O 3 concentrations.

CFD analysis on gas distribution for different scrubber redirection configurations in sump cut.

PubMed

Zheng, Y; Organiscak, J A; Zhou, L; Beck, T W; Rider, J P

2015-01-01

The National Institute for Occupational Safety and Health's Office of Mine Safety and Health Research recently developed a series of models using computational fluid dynamics (CFD) to study the gas distribution around a continuous mining machine with various fan-powered flooded bed scrubber discharge configurations. CFD models using Species Transport Model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The following scenarios are considered in this study: 100 percent of the discharge redirected back toward the face on the off-curtain side of the continuous miner; 100 percent of the discharge redirected back toward the face, but divided equally to both sides of the machine; and 15 percent of the discharge redirected toward the face on the off-curtain side of the machine, with 85 percent directed into the return. These models were compared against a model with a conventional scrubber discharge, where air is directed away from the face into the return. The CFD models were calibrated and validated based on experimental data and accurately predicted sulfur hexafluoride (SF 6 ) gas levels at four gas monitoring locations. One additional prediction model was simulated to consider a different scrubber discharge angle for the 100 percent redirected, equally divided case. These models identified relatively high gassy areas around the continuous miner, which may not warrant their use in coal mines with medium to high methane liberation rates. This paper describes the methodology used to develop the CFD models, and the validation of the models based on experimental data.

Development of the Los Alamos continuous high average-power microsecond pulser ion accelerator

NASA Astrophysics Data System (ADS)

Bitteker, L. J.; Wood, B. P.; Davis, H. A.; Waganaar, W. J.; Boyd, I. D.; Lovberg, R. H.

2000-10-01

The continuous high average-power microsecond pulser (CHAMP) ion accelerator is being constructed at Los Alamos National Laboratory. Progress on the testing of the CHAMP diode is discussed. A direct simulation Monte Carlo computer code is used to investigate the puffed gas fill of the CHAMP anode. High plenum pressures and low plenum volumes are found to be desirable for effective gas puffs. The typical gas fill time is 150-180 μs from initiation of valve operation to end of fill. Results of anode plasma production at three stages of development are discussed. Plasma properties are monitored with electric and magnetic field probes. From this data, the near coil plasma density under nominal conditions is found to be on the order of 1×1016 cm-3. Large error is associated with this calculation due to inconsistencies between tests and the limitations of the instrumentation used. The diode insulating magnetic field is observed to result in lower density plasma with a more diffuse structure than for the cases when the insulating field is not applied. The importance of these differences in plasma quality on the beam production is yet to be determined.

Changes in CO2 diffuse degassing induced by the passing of seismic waves

NASA Astrophysics Data System (ADS)

Gresse, M.; Vandemeulebrouck, J.; Byrdina, S.; Chiodini, G.; Bruno, P. P.

2016-06-01

Solfatara crater, located in the Campi Flegrei caldera, is a volcano with one of the highest degassing rates on Earth, more than 1500 t of CO2 released by diffusion or through vents. Here, we investigated how this gas release can be disrupted by the passage of seismic waves. We performed continuous soil CO2 flux measurements during the propagation of seismic vibrations in the range of 5 Hz to 200 Hz induced by a vibroseis truck. The CO2 flux was continuously recorded using the accumulation chamber method. The data show a temporary and drastic (up to two-fold) increase in CO2 flux exclusively during the vibrations, before returning to the initial flux values. These transient variations are interpreted as fluidization of the surficial granular layer that releases the stored gas. Similar degassing processes might occur at a larger scale during earthquakes, to cause temporary increases in the total gas outflow in volcanic or tectonic areas. Our findings are useful to better assess and monitor the potential hazard from sudden CO2 flux release during earthquakes as several cases of intoxication or death have already been related to volcanic degassing.

Need for Robust Sensors for Inherently Fail-Safe Gas Turbine Engine Controls, Monitoring, and Prognostics (Postprint)

DTIC Science & Technology

2006-09-01

MONITORING , AND PROGNOSTICS Alireza R. Behbahani Controls / Engine Health Management Turbine Engine Division / PRTS U.S. Air Force Research...Technical Report 2005. 8. Greitzer, Frank et al, “Gas Turbine Engine Health Monitoring and Prognostics ”, International Society of Logistics (SOLE...AFRL-PR-WP-TP-2007-217 NEED FOR ROBUST SENSORS FOR INHERENTLY FAIL-SAFE GAS TURBINE ENGINE CONTROLS, MONITORING , AND PROGNOSTICS (POSTPRINT

Monitoring unrest in a large silicic caldera, the long Valley-inyo craters volcanic complex in east-central California

USGS Publications Warehouse

Hill, D.P.

1984-01-01

Recent patterns of geologic unrest in long Valley caldera in east-central California emphasize that this large, silicic volcanic system and the adjacent, geologically youthful Inyo-Mono Craters volcanic chain are still active and capable of producing locally hazardous volcanic eruptions. A series of four magnitude -6 earthquakes in May 1980 called attention to this current episode of unrest, and subsequent activity has included numerous earthquake swarms in the south moat of the caldera accompanied by inflation of the resurgent dome by more than 50 cm over the last five years. The seismicity associated with this unrest is currently monitored by a network of 31 telemetered seismic stations with an automatic processing system that yelds hypocentral locations and earthquake magnitudes in near-real time. Deformation of the ground is monitored by a) a series of overlapping trilateration networks that provide coverage ranging from annual measurements of regional deformation to daily measurements of deformation local to the active, southern section of the caldera, b) a regional network of level lines surveyed annually, c) a regional network of precise gravity stations occupied annually, d) local, L-shaped level figures surveyed every few months, and e) a network of fourteen borehole tiltmeter clusters (two instruments in each cluster) and a borehole dilatometer, the telemetered signals from which provide continuous data on deformation rates. Additional telemetered data provide continuous information on fluctuations in the local magnetic field, hydrogen gas emission rates at three sites, and water level and temperatures in three wells. Continuous data on disharge rates and temperatures from hot springs and fumaroles are collected by several on-site recorders within the caldera, and samples for liquid and gas chemistry are collected several times per year from selected hot springs and fumaroles. ?? 1984 Intern. Association of Volcanology and Chemistry of the Earth's Interior.

Low-cost, portable open-source gas monitoring device based on chemosensory technology

NASA Astrophysics Data System (ADS)

Gotor, Raúl; Gaviña, Pablo; Costero, Ana M.

2015-08-01

We report herein the construction of an electronic device to perform the real-time digitalization of the color state of the optical chemosensors used in the detection of dangerous gases. To construct the device, we used open-source modular electronics, such as Arduino and Sparkfun components, as well as free and open-source software (FOSS). The basic principle of the operation of this device is the continuous color measurement of a chemosensor-doped sensing film, whose color changes in the presence of a specific gas. The chemosensor-sensing film can be prepared by using any of the widely available chemosensors for the desired gas. Color measurement is taken by two TCS230 color sensor ICs, reported to the microcontroller, and the results are displayed on an LCD display and pushed through a USB serial port. By using a cyanide optical chemosensor, we demonstrated the operation of the device as a HCN gas detector at low concentrations.

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 1. Technical results. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue-gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 2. Data supplement. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue-gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic and organic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

Integrated control system and method

DOEpatents

Wang, Paul Sai Keat; Baldwin, Darryl; Kim, Myoungjin

2013-10-29

An integrated control system for use with an engine connected to a generator providing electrical power to a switchgear is disclosed. The engine receives gas produced by a gasifier. The control system includes an electronic controller associated with the gasifier, engine, generator, and switchgear. A gas flow sensor monitors a gas flow from the gasifier to the engine through an engine gas control valve and provides a gas flow signal to the electronic controller. A gas oversupply sensor monitors a gas oversupply from the gasifier and provides an oversupply signal indicative of gas not provided to the engine. A power output sensor monitors a power output of the switchgear and provide a power output signal. The electronic controller changes gas production of the gasifier and the power output rating of the switchgear based on the gas flow signal, the oversupply signal, and the power output signal.

TIGER TM : Intelligent continuous monitoring of gas turbines

DOE Office of Scientific and Technical Information (OSTI.GOV)

McKay, I.; Hibbert, J.; Milne, R.

1998-07-01

The field of condition monitoring has been an area of rapid growth, with many specialized techniques being developed to measure or predict the health of a particular item of plant. Much of the most recent work has gone into the diagnosis of problems on rotating machines through the application of vibration analysis techniques. These techniques though useful can have a number of limiting factors, such as the need to install specialized sensors and measurement equipment, or the limited scope of the type of data measured. It was recognized in 1992, that the surveillance and condition monitoring procedures available for criticalmore » plant, such as gas turbines, were not as comprehensive as they might be and that a novel approach was required to give the operator the necessary holistic view of the health of the plant. This would naturally provide an assessment of the maintenance practices required to yield the highest possible availability without the need to install extensive new instrumentation. From the above objective, the TIGER system was designed which utilizes available data from the gas turbine control system or additionally the plant DCS to measure the behavior of the gas turbine and its associated sub systems. These measured parameters are then compared with an internal model of the turbine system and used to diagnose incorrect responses and therefore the item that is at fault, allowing the operator to quickly restart the turbine after a trip or perform condition based maintenance at the next scheduled outage. This philosophy has been built into the TIGER system and the purpose of this paper is to illustrate its functionality and some of the innovative techniques used in the diagnosis of real gas turbine problems. This is achieved by discussing three case studies where TIGER was integral in returning the plant to operation more quickly than can normally be expected.« less

Environmental assessment of an enhanced-oil-recovery steam generator equipped with a low-NOx burner. Volume 2. Data supplement. Final report, January 1984-January 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.; Lips, H.I.

1986-02-01

The report is a compendium of detailed test sampling and analysis data obtained in field tests of an enhanced-oil-recovery steam generator (EOR steamer) equipped with a MHI PM low-NOx crude oil burner. Test data reported include equipment calibration records, steamer operating data, and complete flue-gas emission results. Flue-gas emission measurements included continuous monitoring for criteria pollutants; onsite gas chromatography (GC) for volatile hydrocarbons (Cl-C6); Methods 5/8 sampling for particulate and SO/sub 2/ and SO/sub 3/ emissions; source assessment sampling system (SASS) for total organics in two boiling-point ranges (100 to 300 C and greater than or equal to 300 C),more » organic compound category information using infrared spectrometry (IR), and specific quantitation of the semivolatile organic priority pollutants using gas chromatography/mass spectrometry (GC/MS); Andersen impactor train measurements of emitted particle-size distribution; and N/sub 2/O emissions by gas chromatography/electron-capture detector (GC/ECD).« less

Environmental assessment of a watertube boiler firing a coal-water slurry. Volume 2. Data supplement. Final report, January 1984-March 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.; Waterland, L.R.

1986-02-01

This report is a compendium of detailed test sampling and analysis data obtained in field tests of a watertube industrial boiler burning a coal/water slurry (CWS). Test data reported include preliminary stack test data, boiler operating data, and complete flue-gas emission results. Flue-gas emission measurements included continuous monitoring for criteria pollutants; onsite gas chromatography (GC) for volatile hydrocarbons (Cl-C6); Methods 5/8 sampling for particulate, SO/sub 2/, and SO/sub 3/ emissions; source assessment sampling system (SASS) for total organics in two boiling point ranges (100 to 300 C and > 300 C), organic compound category information using infrared spectrometry (IR), liquidmore » column (LC) chromatography separation, and low-resolution mass spectrometry (LRMS), specific quantitation of the semivolatile organic priority pollutants using gas chromatography/mass spectrometry (GC/MS), and trace-element emissions using spark-source mass spectrometry (SSMS) and atomic absorption spectroscopy (AAS); N/sub 2/O emissions by gas chromatography/electron-capture detector (GC/ECD); and biological assay testing of SASS and ash-stream samples.« less

Subsurface Monitoring of CO2 Sequestration - A Review and Look Forward

NASA Astrophysics Data System (ADS)

Daley, T. M.

2012-12-01

The injection of CO2 into subsurface formations is at least 50 years old with large-scale utilization of CO2 for enhanced oil recovery (CO2-EOR) beginning in the 1970s. Early monitoring efforts had limited measurements in available boreholes. With growing interest in CO2 sequestration beginning in the 1990's, along with growth in geophysical reservoir monitoring, small to mid-size sequestration monitoring projects began to appear. The overall goals of a subsurface monitoring plan are to provide measurement of CO2 induced changes in subsurface properties at a range of spatial and temporal scales. The range of spatial scales allows tracking of the location and saturation of the plume with varying detail, while finer temporal sampling (up to continuous) allows better understanding of dynamic processes (e.g. multi-phase flow) and constraining of reservoir models. Early monitoring of small scale pilots associated with CO2-EOR (e.g., the McElroy field and the Lost Hills field), developed many of the methodologies including tomographic imaging and multi-physics measurements. Large (reservoir) scale sequestration monitoring began with the Sleipner and Weyburn projects. Typically, large scale monitoring, such as 4D surface seismic, has limited temporal sampling due to costs. Smaller scale pilots can allow more frequent measurements as either individual time-lapse 'snapshots' or as continuous monitoring. Pilot monitoring examples include the Frio, Nagaoka and Otway pilots using repeated well logging, crosswell imaging, vertical seismic profiles and CASSM (continuous active-source seismic monitoring). For saline reservoir sequestration projects, there is typically integration of characterization and monitoring, since the sites are not pre-characterized resource developments (oil or gas), which reinforces the need for multi-scale measurements. As we move beyond pilot sites, we need to quantify CO2 plume and reservoir properties (e.g. pressure) over large scales, while still obtaining high resolution. Typically the high-resolution (spatial and temporal) tools are deployed in permanent or semi-permanent borehole installations, where special well design may be necessary, such as non-conductive casing for electrical surveys. Effective utilization of monitoring wells requires an approach of modular borehole monitoring (MBM) were multiple measurements can be made. An example is recent work at the Citronelle pilot injection site where an MBM package with seismic, fluid sampling and distributed fiber sensing was deployed. For future large scale sequestration monitoring, an adaptive borehole-monitoring program is proposed.

Feasibility of an on-line fission-gas-leak detection system

NASA Technical Reports Server (NTRS)

Lustig, P. H.

1973-01-01

Calculations were made to determine if a cladding failure could be detected in a 100-kW zirconium hydride reactor primary system by monitoring the highly radioactive NaK coolant for the presence of I-131. The system is to be completely sealed. A leak of 0.01 percent from a single fuel pin was postulated. The 0.364-MeV gamma of I-131 could be monitored on an almost continuous basis, while its presence could be varified by using a longer counting time for the 0.638-MeV gamma. A lithium-drifted germanium detector would eliminate radioactive corrosion product interference that could occur with a sodium iodide scintillation detector.

International Space Station Major Constituent Analyzer On-Orbit Performance

NASA Technical Reports Server (NTRS)

Gardner, Ben D.; Erwin, Phillip M.; Thoresen, Souzan; Wiedemann, Rachel; Matty, Chris

2015-01-01

The Major Constituent Analyzer is a mass spectrometer based system that measures the major atmospheric constituents on the International Space Station. A number of limited-life components require periodic change-out, including the ORU 02 analyzer and the ORU 08 Verification Gas Assembly. Improvements to ion pump operation and ion source tuning have improved lifetime performance of the current ORU 02 design. The most recent ORU 02 analyzer assemblies, as well as ORU 08, have operated nominally. For ORU 02, the ion source filaments and ion pump lifetime continue to be key determinants of MCA performance and logistical support. Monitoring several key parameters provides the capacity to monitor ORU health and properly anticipate end of life.

Applicability of interferometric SAR technology to ground movement and pipeline monitoring

NASA Astrophysics Data System (ADS)

Grivas, Dimitri A.; Bhagvati, Chakravarthy; Schultz, B. C.; Trigg, Alan; Rizkalla, Moness

1998-03-01

This paper summarizes the findings of a cooperative effort between NOVA Gas Transmission Ltd. (NGTL), the Italian Natural Gas Transmission Company (SNAM), and Arista International, Inc., to determine whether current remote sensing technologies can be utilized to monitor small-scale ground movements over vast geographical areas. This topic is of interest due to the potential for small ground movements to cause strain accumulation in buried pipeline facilities. Ground movements are difficult to monitor continuously, but their cumulative effect over time can have a significant impact on the safety of buried pipelines. Interferometric synthetic aperture radar (InSAR or SARI) is identified as the most promising technique of those considered. InSAR analysis involves combining multiple images from consecutive passes of a radar imaging platform. The resulting composite image can detect changes as small as 2.5 to 5.0 centimeters (based on current analysis methods and radar satellite data of 5 centimeter wavelength). Research currently in progress shows potential for measuring ground movements as small as a few millimeters. Data needed for InSAR analysis is currently commercially available from four satellites, and additional satellites are planned for launch in the near future. A major conclusion of the present study is that InSAR technology is potentially useful for pipeline integrity monitoring. A pilot project is planned to test operational issues.

A fence line noble gas monitoring system for nuclear power plants.

PubMed

Grasty, R L; Hovgaard, J; LaMarre, J R

2001-01-01

A noble gas monitoring system has been installed at Ontario Power Generation's Pickering Nuclear Generating Station (PNGS) near Toronto, Canada. This monitoring system allows a direct measure of air kerma from external radiation instead of calculating this based on plant emission data and meteorological models. This has resulted in a reduction in the reported effective dose from external radiation by a factor of at least ten. The system consists of nine self-contained units, each with a 7.6 cm x 7.6 cm (3 inch x 3 inch) NaI(TI) detector that is calibrated for air kerma. The 512-channel gamma ray spectral information is downloaded daily from each unit to a central computer where the data are stored and processed. A spectral stripping procedure is used to remove natural background variations from the spectral windows used to monitor xenon-133 (133Xe), xenon-135 (135Xe), argon-41 (41Ar), and skyshine radiation from the use of radiography sources. Typical monthly minimum detection limits in air kerma are 0.3 nGy for 133Xe, 0.7 nGy for 35Xe, 3 nGy for 41Ar and 2 nGy for skyshine radiation. Based on 9 months of continuous operation, the annualised air kerma due to 133Xe, 135Xe and 41Ar and skyshine radiation were 7 nGy, 8 nGy, 26 nGy and 107 nGy respectively.

Effect of biogas sparging on the performance of bio-hydrogen reactor over a long-term operation.

PubMed

Nualsri, Chatchawin; Kongjan, Prawit; Reungsang, Alissara; Imai, Tsuyoshi

2017-01-01

This study aimed to enhance hydrogen production from sugarcane syrup by biogas sparging. Two-stage continuous stirred tank reactor (CSTR) and upflow anaerobic sludge blanket (UASB) reactor were used to produce hydrogen and methane, respectively. Biogas produced from the UASB was used to sparge into the CSTR. Results indicated that sparging with biogas increased the hydrogen production rate (HPR) by 35% (from 17.1 to 23.1 L/L.d) resulted from a reduction in the hydrogen partial pressure. A fluctuation of HPR was observed during a long term monitoring because CO2 in the sparging gas and carbon source in the feedstock were consumed by Enterobacter sp. to produce succinic acid without hydrogen production. Mixed gas released from the CSTR after the sparging can be considered as bio-hythane (H2+CH4). In addition, a continuous sparging biogas into CSTR release a partial pressure in the headspace of the methane reactor. In consequent, the methane production rate is increased.

Effect of biogas sparging on the performance of bio-hydrogen reactor over a long-term operation

PubMed Central

Nualsri, Chatchawin; Kongjan, Prawit; Imai, Tsuyoshi

2017-01-01

This study aimed to enhance hydrogen production from sugarcane syrup by biogas sparging. Two-stage continuous stirred tank reactor (CSTR) and upflow anaerobic sludge blanket (UASB) reactor were used to produce hydrogen and methane, respectively. Biogas produced from the UASB was used to sparge into the CSTR. Results indicated that sparging with biogas increased the hydrogen production rate (HPR) by 35% (from 17.1 to 23.1 L/L.d) resulted from a reduction in the hydrogen partial pressure. A fluctuation of HPR was observed during a long term monitoring because CO2 in the sparging gas and carbon source in the feedstock were consumed by Enterobacter sp. to produce succinic acid without hydrogen production. Mixed gas released from the CSTR after the sparging can be considered as bio-hythane (H2+CH4). In addition, a continuous sparging biogas into CSTR release a partial pressure in the headspace of the methane reactor. In consequent, the methane production rate is increased. PMID:28207755

Online gas composition estimation in solid oxide fuel cell systems with anode off-gas recycle configuration

NASA Astrophysics Data System (ADS)

Dolenc, B.; Vrečko, D.; Juričić, Ð.; Pohjoranta, A.; Pianese, C.

2017-03-01

Degradation and poisoning of solid oxide fuel cell (SOFC) stacks are continuously shortening the lifespan of SOFC systems. Poisoning mechanisms, such as carbon deposition, form a coating layer, hence rapidly decreasing the efficiency of the fuel cells. Gas composition of inlet gases is known to have great impact on the rate of coke formation. Therefore, monitoring of these variables can be of great benefit for overall management of SOFCs. Although measuring the gas composition of the gas stream is feasible, it is too costly for commercial applications. This paper proposes three distinct approaches for the design of gas composition estimators of an SOFC system in anode off-gas recycle configuration which are (i.) accurate, and (ii.) easy to implement on a programmable logic controller. Firstly, a classical approach is briefly revisited and problems related to implementation complexity are discussed. Secondly, the model is simplified and adapted for easy implementation. Further, an alternative data-driven approach for gas composition estimation is developed. Finally, a hybrid estimator employing experimental data and 1st-principles is proposed. Despite the structural simplicity of the estimators, the experimental validation shows a high precision for all of the approaches. Experimental validation is performed on a 10 kW SOFC system.

Continuous in situ measurements of volcanic gases with a diode-laser-based spectrometer: CO2 and H2O concentration and soil degassing at Vulcano (Aeolian islands: Italy).

PubMed

De Rosa, Maurizio; Gagliardi, Gianluca; Rocco, Alessandra; Somma, Renato; De Natale, Paolo; De Natale, Giuseppe

2007-04-20

We report on a continuous-measurement campaign carried out in Vulcano (Aeolian islands, Sicily), devoted to the simultaneous monitoring of CO2 and H2O concentrations. The measurements were performed with an absorption spectrometer based on a semiconductor laser source emitting around a 2-microm wavelength. The emitted radiation was selectively absorbed by two molecular ro-vibrational transitions specific of the investigated species. Data for CO2 and H2O concentrations, and CO2 soil diffusive flux using an accumulation chamber configuration, were collected at several interesting sampling points on the island (Porto Levante beach- PLB, Fossa Grande Crater - FOG- and Valley of Palizzi, PAL). CO2/H2O values, measured on the ground, are very similar (around 0.019 (+/- 0.006)) and comparable to the previous discrete detected values of 0.213 (Fumarole F5-La Fossa crater rim) and 0.012 (Fumarole VFS - Baia Levante beach) obtaid during the 1977-1993 heating phase of the crater fumaroles. In this work much more homogeneous values are found in different points of the three sites investigated. The field work, although carried out in a limited time window (25th-28th August 2004), pointed out the new apparatus is suitable for continuous gas monitoring of the two species and their ratios, which are important geochemical indicators of volcanic activity, for which other reliable continuous monitoring systems are not yet available.

Novel Wireless Sensor System for Monitoring Oxygen, Temperature and Respiration Rate of Horticultural Crops Post Harvest

PubMed Central

Løkke, Mette Marie; Seefeldt, Helene Fast; Edwards, Gareth; Green, Ole

2011-01-01

In order to design optimal packages, it is of pivotal importance to determine the rate at which harvested fresh fruits and vegetables consume oxygen. The respiration rate of oxygen (RRO2) is determined by measuring the consumed oxygen per hour per kg plant material, and the rate is highly influenced by temperature and gas composition. Traditionally, RRO2 has been determined at discrete time intervals. In this study, wireless sensor networks (WSNs) were used to determine RRO2 continuously in plant material (fresh cut broccoli florets) at 5 °C, 10 °C and 20 °C and at modified gas compositions (decreasing oxygen and increasing carbon dioxide levels). Furthermore, the WSN enabled concomitant determination of oxygen and temperature in the very close vicinity of the plant material. This information proved a very close relationship between changes in temperature and respiration rate. The applied WSNs were unable to determine oxygen levels lower than 5% and carbon dioxide was not determined. Despite these drawbacks in relation to respiration analysis, the WSNs offer a new possibility to do continuous measurement of RRO2 in post harvest research, thereby investigating the close relation between temperature and RRO2. The conclusions are that WSNs have the potential to be used as a monitor of RRO2 of plant material after harvest, during storage and packaging, thereby leading to optimized consumer products. PMID:22164085

Engineering considerations for corrosion monitoring of gas gathering pipeline systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Braga, T.G.; Asperger, R.G.

1987-01-01

Proper corrosion monitoring of gas gathering pipelines requires a system review to determine the appropriate monitor locations and types of monitoring techniques. This paper develops and discusses a classification of conditions such as flow regime and gas composition. Also discussed are junction categories which, for corrosion monitoring, need to be considered from two points of view. The first is related to fluid flow in the line and the second is related corrosion inhibitor movement along the pipeline. The appropriate application of the various monitoring techniques such as coupons, hydrogen detectors, electrical resistance probe and linear polarization probes are discussed inmore » relation to flow regime and gas composition. Problems caused by semi-conduction from iron sulfide are considered. Advantages and disadvantages of fluid gathering methods such as pots and flow-through drips are discussed in relation to their reliability as on-line monitoring locations.« less

Use of Cometabolic Air Sparging to Remediate Chloroethene-Contaminated Groundwater Aquifers

DTIC Science & Technology

2001-07-31

sampling event, the temperature, dew point , and relative humidity of the soil gas were analyzed using a Control Company Digital Hygrometer/Thermometer...4.2.1.3 Groundwater and Soil- Gas Multi-Level Monitoring Points .................... 20 4.2.1.4 Groundwater Monitoring Wells...C-1 APPENDIX D: SOIL- GAS MONITORING POINT DATA........................................................D-1 APPENDIX E: HISTORICAL

Optical detection of blade flutter. [in YF-100 turbofan engine

NASA Technical Reports Server (NTRS)

Nieberding, W. C.; Pollack, J. L.

1977-01-01

The paper examines the capabilities of photoelectric scanning (PES) and stroboscopic imagery (SI) as optical monitoring tools for detection of the onset of flutter in the fan blades of an aircraft gas turbine engine. Both optical techniques give visual data in real time as well as video-tape records. PES is shown to be an ideal flutter monitor, since a single cathode ray tube displays the behavior of all the blades in a stage simultaneously. Operation of the SI system continuously while searching for a flutter condition imposes severe demands on the flash tube and affects its reliability, thus limiting its use as a flutter monitor. A better method of operation is to search for flutter with the PES and limit the use of SI to those times when the PES indicates interesting blade activity.

Determination of in vivo carbon monoxide production in laboratory animals via exhaled air.

PubMed

Dercho, Ryan A; Nakatsu, Kanji; Wong, Ronald J; Stevenson, David K; Vreman, Hendrik J

2006-01-01

In vitro assays play an important role in the understanding of the heme oxygenase (HO)/carbon monoxide (CO) pathway. However, because physiological roles for the products of this pathway are hypothesized, it is becoming increasingly important to perform in vivo studies. Since CO production is primarily mediated by HO and is excreted mainly by the lungs, measurements of total body CO excretion (VeCO) via the breath allow continuous, noninvasive monitoring of heme degradation and CO and bilirubin production. Here, we describe a modified flow-through method for the collection and quantitation of CO from small laboratory animals. Mice and rats were studied in gas-tight chambers supplied with a continuous flow of CO-free air. CO in the exhaust air was measured by gas chromatography with a reduction gas analyzer. After establishing baseline VeCO levels, animals were administered various xenobiotics known to alter HO activity and further monitored for changes in CO production for up to 12 h without observable distress. Administration of heme (substrate for HO) resulted in reproducible increases in CO production; whereas, prior administration of zinc protoporphyrin (ZnPP, HO inhibitor) or cobalt protoporphyrin (CoPP, HO inducer) resulted in respective dose-dependent decreases and increases in the heme-induced CO production. We have demonstrated that this noninvasive method of CO quantitation reliably estimates heme degradation with sensitivity to distinguish between different types of HO-manipulating xenobiotics in a dose-dependant manner in both mouse and rat models. Furthermore, VeCO measurements allow nearly real-time determinations of CO and bilirubin formation, which helps to illustrate the time course of drug action.

Chasing Sources and Transports of Methane Plumes in the Northern Gulf of Mexico Using In Situ Sensors on Untethered Landers

NASA Astrophysics Data System (ADS)

Martens, C. S.; Mendlovitz, H.; Seim, H.; Lapham, L.; Magen, C.; Joye, S. B.; MacDonald, I. R.; Asper, V. L.; Diercks, A. R.

2016-02-01

In situ time-series measurements of light hydrocarbons, oxygen, temperature and bottom currents from landers and elevators in the benthic boundary layer (BBL) at multiple sites in the northern Gulf of Mexico reveal spatial and temporal variability in methane concentrations controlled by horizontal advection of methane-rich plumes originating from nearby natural oil and gas seeps. Multi-sensor systems deployed for several weeks within 1m of the seafloor at depths from 882 to 1622m revealed methane concentrations ranging from near atmospheric saturation (<3 nM) to over 4000 nM depending on seep proximity, current speed and direction. Methane concentrations observed in the BBL equal or exceed maximum near-bottom values seen in shipboard water column profiles analyzed by conventional gas chromatography. Continuous laser sensor methane measurements from mini-landers deployed in September 2015 at our Horn Dome and Bush Hill sites featuring numerous gas seeps revealed methane concentrations ranging from <3 to over 300 nM over two-week periods. Net current speeds in the BBL at our six lander sites in blocks GC600, OC26 and MC118 ranged from near zero to over 5 cm/s; instantaneous speeds ranged from near zero to over 30 cm/s. Near real-time acquisition of continuous hydrocarbon concentration and current data within the BBL and friction layer from untethered platforms provides important new opportunities for monitoring the impacts of natural seeps and accidental hydrocarbon releases. The instrumented approaches we have developed to simultaneously monitor methane sources and physical processes controlling plume development and transport will enable more effective responses to further accidental hydrocarbon releases.

Magma Vesiculation and Infrasonic Activity in Open Conduit Volcanoes

NASA Astrophysics Data System (ADS)

Colo', L.; Baker, D. R.; Polacci, M.; Ripepe, M.

2007-12-01

At persistently active basaltic volcanoes such as Stromboli, Italy degassing of the magma column can occur in "passive" and "active" conditions. Passive degassing is generally understood as a continuous, non explosive release of gas mainly from the open summit vents and subordinately from the conduit's wall or from fumaroles. In passive degassing generally gas is in equilibrium with atmospheric pressure, while in active degassing the gas approaches the surface at overpressurized conditions. During active degassing (or puffing), the magma column is interested by the bursting of small gas bubbles at the magma free surface and, as a consequence, the active degassing process generates infrasonic signals. We postulated, in this study, that the rate and the amplitude of infrasonic activity is somehow linked to the rate and the volume of the overpressured gas bubbles, which are generated in the magma column. Our hypothesis is that infrasound is controlled by the quantities of gas exsolved in the magma column and then, that a relationship between infrasound and the vesiculation process should exist. In order to achieve this goal, infrasonic records and bubble size distributions of scoria samples from normal explosive activity at Stromboli processed via X ray tomography have been compared. We observed that the cumulative distribution for both data sets follow similar power laws, indicating that both processes are controlled by a scale invariant phenomenon. However the power law is not stable but changes in different scoria clasts, reflecting when gas bubble nucleation is predominant over bubbles coalescence and viceversa. The power law also changes for the infrasonic activity from time to time, suggesting that infrasound may be controlled also by a different gas exsolution within the magma column. Changes in power law distributions are the same for infrasound and scoria indicating that they are linked to the same process acting in the magmatic system. We suggest that monitoring infrasound on an active volcano could represent an alternative way to monitor the vesiculation process of an open conduit system.

Real-time drilling mud gas monitoring for qualitative evaluation of hydrocarbon gas composition during deep sea drilling in the Nankai Trough Kumano Basin.

PubMed

Hammerschmidt, Sebastian B; Wiersberg, Thomas; Heuer, Verena B; Wendt, Jenny; Erzinger, Jörg; Kopf, Achim

2014-01-01

Integrated Ocean Drilling Program Expedition 338 was the second scientific expedition with D/V Chikyu during which riser drilling was conducted as part of the Nankai Trough Seismogenic Zone Experiment. Riser drilling enabled sampling and real-time monitoring of drilling mud gas with an onboard scientific drilling mud gas monitoring system ("SciGas"). A second, independent system was provided by Geoservices, a commercial mud logging service. Both systems allowed the determination of (non-) hydrocarbon gas, while the SciGas system also monitored the methane carbon isotope ratio (δ(13)CCH4). The hydrocarbon gas composition was predominated by methane (> 1%), while ethane and propane were up to two orders of magnitude lower. δ(13)CCH4 values suggested an onset of thermogenic gas not earlier than 1600 meter below seafloor. This study aims on evaluating the onboard data and subsequent geological interpretations by conducting shorebased analyses of drilling mud gas samples. During shipboard monitoring of drilling mud gas the SciGas and Geoservices systems recorded up to 8.64% and 16.4% methane, respectively. Ethane and propane concentrations reached up to 0.03 and 0.013%, respectively, in the SciGas system, but 0.09% and 0.23% in the Geoservices data. Shorebased analyses of discrete samples by gas chromatography showed a gas composition with ~0.01 to 1.04% methane, 2 - 18 ppmv ethane, and 2 - 4 ppmv propane. Quadruple mass spectrometry yielded similar results for methane (0.04 to 4.98%). With δD values between -171‰ and -164‰, the stable hydrogen isotopic composition of methane showed little downhole variability. Although the two independent mud gas monitoring systems and shorebased analysis of discrete gas sample yielded different absolute concentrations they all agree well with respect to downhole variations of hydrocarbon gases. The data point to predominantly biogenic methane sources but suggest some contribution from thermogenic sources at depth, probably due to mixing. In situ thermogenic gas production at depths shallower 2000 mbsf is unlikely based on in situ temperature estimations between 81°C and 85°C and a cumulative time-temperature index of 0.23. In conclusion, the onboard SciGas data acquisition helps to provide a preliminary, qualitative evaluation of the gas composition, the in situ temperature and the possibility of gas migration.

78 FR 25392 - Greenhouse Gas Reporting Rule: Revision to Best Available Monitoring Method Request Submission...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-01

.... 211112 Natural gas liquid extraction facilities. Table 1 of this preamble is not intended to be... Greenhouse Gas Reporting Rule: Revision to Best Available Monitoring Method Request Submission Deadline for Petroleum and Natural Gas Systems Source Category AGENCY: Environmental Protection Agency (EPA). ACTION...

Long-times series of infrasonic records at open-vents volcanoes (Yasur volcano, Vanuatu, 2003-2014): the remarkable temporal stability of magma viscosity

NASA Astrophysics Data System (ADS)

Vergniolle, S.; Souty, V.; Zielinski, C.; Bani, P.; LE Pichon, A.; Lardy, M.; Millier, P.; Herry, P.; Todman, S.; Garaebiti, E.

2017-12-01

Open-vents volcanoes, often presenting series of Strombolian explosions of various intensity, are responding, although with a delay, to any changes in the degassing pattern, providing a quasi-direct route to processes at depth. Open-vents volcanoes display a persistent volcanic activity, although of variable intensity. Long-times series at open-vents volcanoes could therefore be key measurements to unravel physical processes at the origin of Strombolian explosions and be crucial for monitoring. Continuous infrasonic records can be used to estimate the gas volume expelled at the vent during explosions (bursting of a long slug). The gas volume of each explosion is deduced from a series of two successive integrations of acoustic pressure (monopole). Here we analysed more than 4 years of infrasonic records at Yasur volcano (Vanuatu), spanning between 2003 and 2014 and organised into 8 main quasi-continuous periods. The relationship between the gas volume of each explosion and its associated maximum positive acoustic pressure, a proxy for the inner gas overpressure at bursting, shows a remarkably stable trend over the 8 periods. Two main trends exists, one which covers the full range of acoustic pressures (called « strong explosions ») and the second which represents explosions with a large gas volume and mild acoustic pressure. The class of « strong explosions » clearly follows the model of Del Bello et al. (2012), which shows that the inner gas overpressure at bursting, here empirically measured by the maximum acoustic pressure, is proportional to the gas volume. Constrains on magma viscosity and conduit radius, are deduced from this trend and from the gas volume at the transition passive-active degassing. The remarkable stability of this trend over time suggests that 1) the magma viscosity is stable at the depth where gas overpressure is produced within the slug and 2) any potential changes in magma viscosity occur very close to the top of the magma column.

Gas-Permeable Membrane-Based Conductivity Probe Capable of In Situ Real-Time Monitoring of Ammonia in Aquatic Environments.

PubMed

Li, Tianling; Panther, Jared; Qiu, Yuan; Liu, Chang; Huang, Jianyin; Wu, Yonghong; Wong, Po Keung; An, Taicheng; Zhang, Shanqing; Zhao, Huijun

2017-11-21

Aquatic ammonia has toxic effects on aquatic life. This work reports a gas-permeable membrane-based conductivity probe (GPMCP) developed for real-time monitoring of ammonia in aquatic environments. The GPMCP innovatively combines a gas-permeable membrane with a boric acid receiving phase to selectively extract ammonia from samples and form ammonium at the inner membrane interface. The rate of the receiving phase conductivity increase is directly proportional to the instantaneous ammonia concentration in the sample, which can be rapidly and sensitively determined by the embedded conductivity detector. A precalibration strategy was developed to eliminate the need for an ongoing calibration. The analytical principle and GPMCP performance were systematically validated. The laboratory results showed that ammonia concentrations ranging from 2 to 50 000 μg L -1 can be detected. The field deployment results demonstrated the GPMCP's ability to obtain high-resolution continuous ammonia concentration profiles and the absolute average ammonia concentration over a prolonged deployment period. By inputting the temperature and pH data, the ammonium concentration can be simultaneously derived from the corresponding ammonia concentration. The GPMCP embeds a sophisticated analytical principle with the inherent advantages of high selectivity, sensitivity, and accuracy, and it can be used as an effective tool for long-term, large-scale, aquatic-environment assessments.

Upgrade to the Cryogenic Hydrogen Gas Target Monitoring System

NASA Astrophysics Data System (ADS)

Slater, Michael; Tribble, Robert

2013-10-01

The cryogenic hydrogen gas target at Texas A&M is a vital component for creating a secondary radioactive beam that is then used in experiments in the Momentum Achromat Recoil Spectrometer (MARS). A stable beam from the K500 superconducting cyclotron enters the gas cell and some incident particles are transmuted by a nuclear reaction into a radioactive beam, which are separated from the primary beam and used in MARS experiments. The pressure in the target chamber is monitored so that a predictable isotope production rate can be assured. A ``black box'' received the analog pressure data and sent RS232 serial data through an outdated serial connection to an outdated Visual Basic 6 (VB6) program, which plotted the chamber pressure continuously. The black box has been upgraded to an Arduino UNO microcontroller [Atmel Inc.], which can receive the pressure data and output via USB to a computer. It has been programmed to also accept temperature data for future upgrade. A new computer program, with updated capabilities, has been written in Python. The software can send email alerts, create audible alarms through the Arduino, and plot pressure and temperature. The program has been designed to better fit the needs of the users. Funded by DOE and NSF-REU Program.

Actively Disintegrating Astroids around a White Dwarf

NASA Astrophysics Data System (ADS)

Xu, Siyi

2017-08-01

Recent studies show that planetary systems can be widespread around white dwarfs. It has been proposed that planetary systems are responsible for the pollution observed in a white dwarf's atmosphere and the excess infrared radiation. This scenario is greatly strengthened by the recent discovery of actively disintegrating bodies orbiting around the white dwarf WD 1145+017. In addition, this system has a heavily polluted atmosphere, a dust disk, and circumstellar gas. Our team has been monitoring this system since its discovery and our recent COS data have revealed many new surprises. We propose to continue studying this system for the next two cycles and further constrain the evolution of the disintegrating bodies: what are the main mechanisms responsible for its destruction? How is circumstellar gas produced and maintained?

40 CFR 65.104 - Instrument and sensory monitoring for leaks.

Code of Federal Regulations, 2012 CFR

2012-07-01

... calibration gas other than methane in air may be used if the instrument does not respond to methane or if the.... (i) Valves in gas/vapor service and in light liquid service shall be monitored pursuant to § 65.106(b). (ii) Pumps in light liquid service shall be monitored pursuant to § 65.107(b). (iii) Connectors in gas...

40 CFR 65.104 - Instrument and sensory monitoring for leaks.

Code of Federal Regulations, 2014 CFR

2014-07-01

... calibration gas other than methane in air may be used if the instrument does not respond to methane or if the.... (i) Valves in gas/vapor service and in light liquid service shall be monitored pursuant to § 65.106(b). (ii) Pumps in light liquid service shall be monitored pursuant to § 65.107(b). (iii) Connectors in gas...

Applications of Ground-based Mobile Atmospheric Monitoring: Real-time Characterization of Source Emissions and Ambient Concentrations

NASA Astrophysics Data System (ADS)

Goetz, J. Douglas

Gas and particle phase atmospheric pollution are known to impact human and environmental health as well as contribute to climate forcing. While many atmospheric pollutants are regulated or controlled in the developed world uncertainty still remains regarding the impacts from under characterized emission sources, the interaction of anthropogenic and naturally occurring pollution, and the chemical and physical evolution of emissions in the atmosphere, among many other uncertainties. Because of the complexity of atmospheric pollution many types of monitoring have been implemented in the past, but none are capable of perfectly characterizing the atmosphere and each monitoring type has known benefits and disadvantages. Ground-based mobile monitoring with fast-response in-situ instrumentation has been used in the past for a number of applications that fill data gaps not possible with other types of atmospheric monitoring. In this work, ground-based mobile monitoring was implemented to quantify emissions from under characterized emission sources using both moving and portable applications, and used in a novel way for the characterization of ambient concentrations. In the Marcellus Shale region of Pennsylvania two mobile platforms were used to estimate emission rates from infrastructure associated with the production and transmission of natural gas using two unique methods. One campaign investigated emissions of aerosols, volatile organic compounds (VOCs), methane, carbon monoxide (CO), nitrogen dioxide (NO2), and carbon dioxide (CO 2) from natural gas wells, well development practices, and compressor stations using tracer release ratio methods and a developed fenceline tracer release correction factor. Another campaign investigated emissions of methane from Marcellus Shale gas wells and infrastructure associated with two large national transmission pipelines using the "Point Source Gaussian" method described in the EPA OTM-33a. During both campaigns ambient concentrations of methane, CO and other pollutants were continuously monitored while driving throughout the region. A smoothing technique was developed to remove contributions of direct unmixed emissions to produce a dataset that can be used in comparison with other monitoring techniques (e.g. stationary, aircraft). Finally, a portable mobile lab equipped with fast-response aerosol instrumentation including an Aerosol Mass Spectrometer (AMS) was used to characterize non-refractory aerosol and black carbon emissions from common, but under characterized emission sources in South Asia (i.e. brick kilns, cookstoves, open garbage burning, irrigation pumps). Speciated submicron aerosol emission factors, size distributions, and mass spectral profiles were retrieved for each emission source. This work demonstrates that ground-based mobile laboratory measurements are useful for characterizing emissions and ambient concentrations in authentic conditions outside of the conventional laboratory environment, and in ways not possible with other atmospheric monitoring platforms.

Leakage detection of Marcellus Shale natural gas at an Upper Devonian gas monitoring well: a 3-d numerical modeling approach.

PubMed

Zhang, Liwei; Anderson, Nicole; Dilmore, Robert; Soeder, Daniel J; Bromhal, Grant

2014-09-16

Potential natural gas leakage into shallow, overlying formations and aquifers from Marcellus Shale gas drilling operations is a public concern. However, before natural gas could reach underground sources of drinking water (USDW), it must pass through several geologic formations. Tracer and pressure monitoring in formations overlying the Marcellus could help detect natural gas leakage at hydraulic fracturing sites before it reaches USDW. In this study, a numerical simulation code (TOUGH 2) was used to investigate the potential for detecting leaking natural gas in such an overlying geologic formation. The modeled zone was based on a gas field in Greene County, Pennsylvania, undergoing production activities. The model assumed, hypothetically, that methane (CH4), the primary component of natural gas, with some tracer, was leaking around an existing well between the Marcellus Shale and the shallower and lower-pressure Bradford Formation. The leaky well was located 170 m away from a monitoring well, in the Bradford Formation. A simulation study was performed to determine how quickly the tracer monitoring could detect a leak of a known size. Using some typical parameters for the Bradford Formation, model results showed that a detectable tracer volume fraction of 2.0 × 10(-15) would be noted at the monitoring well in 9.8 years. The most rapid detection of tracer for the leak rates simulated was 81 days, but this scenario required that the leakage release point was at the same depth as the perforation zone of the monitoring well and the zones above and below the perforation zone had low permeability, which created a preferred tracer migration pathway along the perforation zone. Sensitivity analysis indicated that the time needed to detect CH4 leakage at the monitoring well was very sensitive to changes in the thickness of the high-permeability zone, CH4 leaking rate, and production rate of the monitoring well.

Soil radon as a possible earthquake precursor: Preliminary results from Ileia (Greece)

NASA Astrophysics Data System (ADS)

Petraki, Ermioni; Nikolopoulos, Dimitrios; Louizi, Anna; Zisos, Athanasios

2010-05-01

Radon (222Rn) is a naturally occurring radioactive gas which is directly produced by the decay of the 238U series. It is significant for the studies of Earth, in hydrogeology and atmosphere. Radon is used as a trace gas due to the long half-life (3.82-days) which allows migration at long distances. In addition, it is an alpha emitter, fact which enables detection of low levels of radon. Anomalies of radon impending earthquakes of a variety of magnitudes have been observed in soil gas, ground- and thermal-waters and in underground tunnels. Increasing is the scientific interest in this field during the last two years. However, the majority of the published papers refer to data of rather long time intervals between sequential measurements (~2-4 weeks).On the other hand, it is justified, both on laboratory and geophysical scale, that when a heterogeneous material is strained acoustic and electromagnetic (EM) emissions occur in a wide frequency spectrum, ranging from very low to very high frequencies. These emissions are considered as precursors of general fracture. In the search of soil radon as a possible earthquake precursor, a station for quick and continuous monitoring of soil radon has been installed in a very active tectonic site in Greece (Ileia, Peloponnese, SW Greece). The monitoring site is Kardamas Ileias, located 3 km south from Amaliada which is the second highly populated city. The instrumental and felt seismicity of Ileia is dominated by extensional active seismicity structures (e.g. Alfeios, Neda, Melpeia, Kiparissia-Aetos) and has shown more than 600 earthquakes of magnitude greater than 4.0 R in the last 100 years. Two earthquakes were very destructive (5.8 R on 26/3/93 and 6.8 R on 8/6/08 respectively). The station consists of a high precision active instrument (Alpha Guard-AG, Genitron Ltd.), equipped with an appropriate unit designed for pumping and measurement of radon in soil gas (Soil gas Unit, Genitron Ltd.). Soil radon is continuously pumped into AG at a rate of 1 L/min. Pumping is performed via a 1-m soil probe to minimize meteorological influences and a 25-m radon proof 25-mm tube to avoid simultaneous measurement of soil 220Rn. Proper dust and moisture filters are employed. Radon is monitored every 10 minutes. This interval can be reduced to 1 minute, however with lower accuracy and data storage capacity. For comparison purposes, calibrated passive radon dosimeters based on CR-39 Solid State Nuclear Track Detectors (SSNTD's) were periodically installed and exposed to soil radon in 50 cm holes were dug near the 1-m probe. The exposures lasted 1-2 weeks. Afterwards, the SSNTD's were removed, etched and measured via standard methods (optical microscopy track counting). The period of comparison measurements was 6 months. Continuous monitoring and passive measurements were cross-calibrated and found to provide similar estimates of mean soil radon concentration. Active techniques are much more precise and quick, however, they indicated the necessity of periodical checks for the pumping and measurement status, especially after strong rainfalls.The mean soil radon concentration was found fairly constant (~ 25-30 kBq m-3). Numerous soil radon concentration anomalies were detected. These were arbitrarily corresponded in terms of magnitude and duration to seismic events of the near area. All detected anomalies were sudden, significantly (p

Miniaturized Planar Room Temperature Ionic Liquid Electrochemical Gas Sensor for Rapid Multiple Gas Pollutants Monitoring.

PubMed

Wan, Hao; Yin, Heyu; Lin, Lu; Zeng, Xiangqun; Mason, Andrew J

2018-02-01

The growing impact of airborne pollutants and explosive gases on human health and occupational safety has escalated the demand of sensors to monitor hazardous gases. This paper presents a new miniaturized planar electrochemical gas sensor for rapid measurement of multiple gaseous hazards. The gas sensor features a porous polytetrafluoroethylene substrate that enables fast gas diffusion and room temperature ionic liquid as the electrolyte. Metal sputtering was utilized for platinum electrodes fabrication to enhance adhesion between the electrodes and the substrate. Together with carefully selected electrochemical methods, the miniaturized gas sensor is capable of measuring multiple gases including oxygen, methane, ozone and sulfur dioxide that are important to human health and safety. Compared to its manually-assembled Clark-cell predecessor, this sensor provides better sensitivity, linearity and repeatability, as validated for oxygen monitoring. With solid performance, fast response and miniaturized size, this sensor is promising for deployment in wearable devices for real-time point-of-exposure gas pollutant monitoring.

Continuous monitoring of the C isotope composition of CO_{2}-rich subsurface degassing at Tenerife, Canary Islands

NASA Astrophysics Data System (ADS)

Melián, Gladys; Asensio-Ramos, María; Padrón, Eleazar; Barrancos, José; Hernández, Pedro A.; Pérez, Nemesio M.

2017-04-01

Tenerife is the largest island of the Canarian archipelago and several volcanic eruptions have occurred in the last 500 years, the last one in 1909. The main volcano-tectonic features of Tenerife Island are three main volcano-tectonic rifts trending N-E, N-W and N-S where, at the interception center is located Las Cañadas caldera and the stratovolcano Teide-Pico Viejo. Due to the approximately 1,500 wells and water galleries (1650 km) drilled during the last 150 years tapping the island's volcanic aquifer at different depths, Tenerife is a unique natural-scale laboratory for hydrological studies in oceanic volcanic islands. Ground waters are mainly Na+-HCO3- water type, mainly due to the continuous volcanic CO2 supply from the volcanic-hydrothermal system. A signi?cant number of these galleries show a CO2-rich inner atmosphere, and gas bubbling has also been detected inside some galleries. Since 2002, an automatic geochemical station installed at the entrance of the horizontal drilling "Fuente del Valle" (TFE02 station), Arona, Tenerife, measures the activities of 222Rn and 220Rn in the gas discharged from a CO2-rich gas bubbling spot located at 2.850 m depth. Interesting variations were recorded in the 222Rn/220Rn ratio after the period of 2004 anomalous seismicity and it has been demonstrated that this is a good control spot for volcanic surveillance (Pérez et al., 2007). Thus, in November 2016, a new type of laser based isotopic analyzer, a DeltaRayTM (Thermo Fisher Scientific) was installed in the TFE02 station to measure δ13C(CO2) directly in the gas discharged from the water. The gas, collected by means of an inverted funnel, is pumped (3 L min-1) towards the gallery entrance, where the instrumentation is located, through a polyamide pipe. During the study period the recorded data show a range of δ13C(CO2) from -6.2 to -4.2‰ vs. VPDB, with an average value of -5.1‰Ṫhese values are comparable to those ones measured in the gas sampled directly at the gas bubbling spot (˜-4.7‰ unpublished data) and analyzed with a Thermo Finnigan MAT 253 isotope ratio mass spectrometer, which supports the validity of the analytical method used. This is the first time that this type of instrumentation is used to continuously monitor the δ13C(CO2) isotopic composition of the gas discharged from a gas bubbling in a horizontal drill as a geochemical tool to evaluate the volcanic activity, in particular in Tenerife, a unique natural-scale laboratory for hydrological studies in oceanic volcanic islands. To correlate temporal variations in the δ13C(CO2) isotopic composition with changes in the seismic-volcanic activity of Tenerife, a longer observation period will be required. References: Pérez et al., 2007. Pure Appl. Geophys. DOI 10.1007/s00024-007-0280

The Gas Monitoring of the Besiii Drift Chamber

NASA Astrophysics Data System (ADS)

Wang, Xianggao; Chen, Chang; Chen, Yuanbo; Wu, Zhi; Gu, Yunting; Ma, Xiaoyan; Jin, Yan; Liu, Rongguang; Tang, Xiao; Wang, Lan; Zhu, Qiming

Two monitoring proportional counters (MPCs), installed at the inlet and outlet of the gas system of BESIII drift chamber (DC), were used to monitor the operation of the BESIII DC successfully and effectively as reported in this paper. The ratio of Gout/Gin (full energy photoelectron peak position of 55Fe 5.9 keV X-ray in inlet MPC as Gin and outlet MPC as Gout) is used as the main monitoring parameter. The MPC method is very useful for the gas detector system.

Quantitative decoding of the response a ceramic mixed potential sensor array for engine emissions control and diagnostics

DOE PAGES

Tsui, Lok-kun; Benavidez, Angelica; Palanisamy, Ponnusamy; ...

2017-04-13

The development of on-board sensors for emissions monitoring is necessary for continuous monitoring of the performance of catalytic systems in automobiles. We have fabricated mixed potential electrochemical gas sensing devices with Pt, La 0.8Sr 0.2CrO 3 (LSCO), and Au/Pd alloy electrodes and a porous yttria-stabilized zirconia electrolyte. The three-electrode design takes advantage of the preferential selectivity of the Pt + Au/Pd and Pt + LSCO pairs towards different species of gases and has additional tunable selectivity achieved by applying a current bias to the latter pair. Voltages were recorded in single, binary, and ternary gas streams of NO, NO 2,more » C 3H 8, and CO. We have also trained artificial neural networks to examine the voltage output from sensors in biased and unbiased modes to both identify which single test gas or binary mixture of two test gases is present in a gas stream as well as extract concentration values. We were then able to identify single and binary mixtures of these gases with accuracy of at least 98%. For determining concentration, the peak in the error distribution for binary mixtures was 5% and 80% of test data fell under <12% error. The sensor stability was also evaluated over the course of over 100 days and the ability to retrain ANNs with a small dataset was demonstrated.« less

Quantitative decoding of the response a ceramic mixed potential sensor array for engine emissions control and diagnostics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsui, Lok-kun; Benavidez, Angelica; Palanisamy, Ponnusamy

The development of on-board sensors for emissions monitoring is necessary for continuous monitoring of the performance of catalytic systems in automobiles. We have fabricated mixed potential electrochemical gas sensing devices with Pt, La 0.8Sr 0.2CrO 3 (LSCO), and Au/Pd alloy electrodes and a porous yttria-stabilized zirconia electrolyte. The three-electrode design takes advantage of the preferential selectivity of the Pt + Au/Pd and Pt + LSCO pairs towards different species of gases and has additional tunable selectivity achieved by applying a current bias to the latter pair. Voltages were recorded in single, binary, and ternary gas streams of NO, NO 2,more » C 3H 8, and CO. We have also trained artificial neural networks to examine the voltage output from sensors in biased and unbiased modes to both identify which single test gas or binary mixture of two test gases is present in a gas stream as well as extract concentration values. We were then able to identify single and binary mixtures of these gases with accuracy of at least 98%. For determining concentration, the peak in the error distribution for binary mixtures was 5% and 80% of test data fell under <12% error. The sensor stability was also evaluated over the course of over 100 days and the ability to retrain ANNs with a small dataset was demonstrated.« less

Future volcanic lake research: revealing secrets from poorly studied lakes

NASA Astrophysics Data System (ADS)

Rouwet, D.; Tassi, F.; Mora-Amador, R. A.

2012-04-01

Volcanic lake research boosted after the 1986 Lake Nyos lethal gas burst, a limnic rather than volcanic event. This led to the formation of the IAVCEI-Commission on Volcanic Lakes, which grew out into a multi-disciplinary scientific community since the 1990's. At Lake Nyos, a degassing pipe is functional since 2001, and two additional pipes were added in 2011, aimed to prevent further limnic eruption events. There are between 150 and 200 volcanic lakes on Earth. Some acidic crater lakes topping active magmatic-hydrothermal systems are monitored continuously or discontinuously. Such detailed studies have shown their usefulness in volcanic surveillance (e.g. Ruapehu, Yugama-Kusatsu-Shiran, Poás). Others are "Nyos-type" lakes, with possible gas accumulation in bottom waters and thus potentially hazardous. "Nyos-type" lakes tend to remain stably stratified in tropical and sub-tropical climates (meromictic), leading to long-term gas build-up and thus higher potential risk. In temperate climates, such lakes tend to turn over in winter (monomictic), and thus liberating its gas charge yearly. We line out research strategies for the different types of lakes. We believe a complementary, multi-disciplinary approach (geochemistry, geophysics, limnology, biology, statistics, etc.) will lead to new insights and ideas, which can be the base for future following-up and monitoring. After 25 years of pioneering studies on rather few lakes, the scientific community should be challenged to study the many poorly studied volcanic lakes, in order to better constrain the related hazard, based on probabilistic approaches.

In-situ continuous water analyzing module

DOEpatents

Thompson, Cyril V.; Wise, Marcus B.

1998-01-01

An in-situ continuous liquid analyzing system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectometer and the volatile components are continuously analyzed by the mass spectrometer.

Further Evidence of Severe Allergic Contact Dermatitis From Isobornyl Acrylate While Using a Continuous Glucose Monitoring System.

PubMed

Kamann, Stefanie; Aerts, Olivier; Heinemann, Lutz

2018-05-01

In the past decade, new diabetes technologies, including continuous glucose monitoring (CGM) systems, support patients with diabetes in their daily struggle with achieving a good glucose control. However, shortly after the first CGM systems appeared on the market, also the first concerns about adverse skin reactions were raised. Most patients claimed to suffer from (sometimes severe) skin irritation, or even allergy, which they related to the (acrylate-based) adhesive part of the device. For a long time the actual substance that caused these skin reactions with, for example, the Flash Glucose Monitoring system (iscCGM; Freestyle® Libre) could not be identified; however, recently Belgian and Swedish dermatologists reported that the majority of their patients that have developed a contact-allergic while using iscCGM react sensitively to a specific acrylate, that is, isobornyl acrylate (IBOA). Subsequently they showed by means of gas chromatography-mass spectrometry that this substance is present in the case of the glucose sensor attached by an adhesive to the skin. We report three additional cases from Germany, including a 10-year-old boy, suffering from severe allergic contact dermatitis to IBOA.

Radon entry into basements: Approach, experimental structures, and instrumentation of the small structures research project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fisk, W.J.; Modera, M.P.; Sextro, R.G.

1992-02-01

We describe the experimental approach, structures, and instrumentation of a research project on radon generation and transport in soil and entry into basements. The overall approach is to construct small precisely-fabricated basements in areas of different geology and climate, to control the pressures and ventilation rates in the structures, and to monitor radon concentrations and other relevant parameters over a period of one year or more. Two nearly air-tight structures have been constructed at the first site. The floor of each structure contains adjustable-width slots that serve as the only significant pathway for advective entry of radon. A layer ofmore » gravel underlays the floor of one structure; otherwise they are identical. The structures are instrumented for continuous or periodic monitoring of soil, structural, and meteorological parameters that affect radon entry. The pressure difference that drives advective radon entry can be maintained constant or varied over time. Soil gas and radon entry rates and associated parameters, such as soil gas pressures and radon concentrations, have been monitored for a range of steady-state and time-varying pressure differences between the interior of the structure and the soil. Examples of the experimentally-measured pressure and permeability fields in the soil around a structure are presented and discussed.« less

O absorption measurements in an engineering-scale high-pressure coal gasifier

NASA Astrophysics Data System (ADS)

Sun, Kai; Sur, Ritobrata; Jeffries, Jay B.; Hanson, Ronald K.; Clark, Tommy; Anthony, Justin; Machovec, Scott; Northington, John

2014-10-01

A real-time, in situ water vapor (H2O) sensor using a tunable diode laser near 1,352 nm was developed to continuously monitor water vapor in the synthesis gas of an engineering-scale high-pressure coal gasifier. Wavelength-scanned wavelength-modulation spectroscopy with second harmonic detection (WMS-2 f) was used to determine the absorption magnitude. The 1 f-normalized, WMS-2 f signal (WMS-2 f/1 f) was insensitive to non-absorption transmission losses including beam steering and light scattering by the particulate in the synthesis gas. A fitting strategy was used to simultaneously determine the water vapor mole fraction and the collisional-broadening width of the transition from the scanned 1 f-normalized WMS-2 f waveform at pressures up to 15 atm, which can be used for large absorbance values. This strategy is analogous to the fitting strategy for wavelength-scanned direct absorption measurements. In a test campaign at the US National Carbon Capture Center, the sensor demonstrated a water vapor detection limit of ~800 ppm (25 Hz bandwidth) at conditions with more than 99.99 % non-absorption transmission losses. Successful unattended monitoring was demonstrated over a 435 h period. Strong correlations between the sensor measurements and transient gasifier operation conditions were observed, demonstrating the capability of laser absorption to monitor the gasification process.

Portable spectrometer monitors inert gas shield in welding process

NASA Technical Reports Server (NTRS)

Grove, E. L.

1967-01-01

Portable spectrometer using photosensitive readouts, monitors the amount of oxygen and hydrogen in the inert gas shield of a tungsten-inert gas welding process. A fiber optic bundle transmits the light from the welding arc to the spectrometer.

Reduction of operations and maintenance costs at geothermal power plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bruton, C.J.; Stevens, C.G.; Rard, J.A.

1997-12-31

To reduce chemical costs at geothermal power plants, we are investigating: (a) improved chemical processes associated with H{sub 2}S abatement techniques, and (b) the use of cross dispersive infrared spectrometry to monitor accurately, reliably, and continuously H{sub 2}S emissions from cooling towers. The latter is a new type of infrared optical technology developed by LLNL for non-proliferation verification. Initial work is focused at The Geysers in cooperation with Pacific Gas and Electric. Methods for deploying the spectrometer on-site at The Geysers are being developed. Chemical analysis of solutions involved in H{sub 2}S abatement technologies is continuing to isolate the chemicalmore » forms of sulfur produced.« less

Application of thoron interference as a tool for simultaneous measurement of radon and thoron with a pulse ionisation chamber.

PubMed

Tripathi, R M; Sumesh, C G; Vinod Kumar, A; Puranik, V D

2013-07-01

Pulse ionisation chamber (PIC)-based monitors measuring radioactive gas radon ((222)Rn) without energy discrimination will have interference due to thoron ((220)Rn) present in the atmosphere. A technique has been developed to use this property of interference for simultaneous measurement of radon and thoron gas. These monitors work on the principle of counting of gross alphas emitted from radon and its progeny. A theoretical model has been developed for the variation of thoron sensitivity with respect to the flow rate of gas through the monitor. The thoron sensitivity of the monitor is found to vary with the flow rate of gas through the monitor. Using this sensitivity, the sampling procedure has been developed and verified for simultaneous measurement of radon and thoron. The PIC-measured radon and thoron concentration using this procedure agrees well with those measured by using standard radon and thoron discriminating monitor.

A Fully Redundant On-Line Mass Spectrometer System Used to Monitor Cryogenic Fuel Leaks on the Space Shuttle

NASA Technical Reports Server (NTRS)

Griffin, Timothy P.; Naylor, Guy R.; Haskell, William D.; Breznik, Greg S.; Mizell, Carolyn A.; Helms, William R.; Voska, N. (Technical Monitor)

2002-01-01

An on-line gas monitoring system was developed to replace the older systems used to monitor for cryogenic leaks on the Space Shuttles before launch. The system uses a mass spectrometer to monitor multiple locations in the process, which allows the system to monitor all gas constituents of interest in a nearly simultaneous manner. The system is fully redundant and meets all requirements for ground support equipment (GSE). This includes ruggedness to withstand launch on the Mobile Launcher Platform (MLP), ease of operation, and minimal operator intervention. The system can be fully automated so that an operator is notified when an unusual situation or fault is detected. User inputs are through personal computer using mouse and keyboard commands. The graphical user for detecting cryogenic leaks, many other gas constituents could be monitored using the Hazardous Gas Detection System (HGDS) 2000.

Tilapia fish microbial spoilage monitored by a single optical gas sensor.

PubMed

Semeano, Ana T S; Maffei, Daniele F; Palma, Susana; Li, Rosamaria W C; Franco, Bernadette D G M; Roque, Ana C A; Gruber, Jonas

2018-07-01

As consumption of fish and fish-based foods increases, non-destructive monitoring of fish freshness also becomes more prominent. Fish products are very perishable and prone to microbiological growth, not always easily detected by organoleptic evaluation. The analysis of the headspace of fish specimens through gas sensing is an interesting approach to monitor fish freshness. Here we report a gas sensing method for monitoring Tilapia fish spoilage based on the application of a single gas sensitive gel material coupled to an optical electronic nose. The optical signals of the sensor and the extent of bacterial growth were followed over time, and results indicated good correlation between the two determinations, which suggests the potential application of this simple and low cost system for Tilapia fish freshness monitoring.

40 CFR 49.4166 - Monitoring requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... burning pilot flame, electronically controlled automatic igniters, and monitoring system failures, using a... failure, electronically controlled automatic igniter failure, or improper monitoring equipment operation... and natural gas emissions in the event that natural gas recovered for pipeline injection must be...

40 CFR 49.4166 - Monitoring requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... burning pilot flame, electronically controlled automatic igniters, and monitoring system failures, using a... failure, electronically controlled automatic igniter failure, or improper monitoring equipment operation... and natural gas emissions in the event that natural gas recovered for pipeline injection must be...

Remote monitoring of sub ppb levels of vinyl chloride, dichloroethylene and trichloroethylene via modem operated automated GC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Linenberg, A.; Lander, N.J.

1994-12-31

The need for remote monitoring of certain compounds in a sparsely populated area with limited user assistance led to the development and manufacture of a self contained, portable gas chromatography with the appropriate software. Part per billion levels of vinyl chloride, cis 1,2 dichloroethylene and trichloroethylene were detected in air using a trap for preconcentration of the compounds. The units were continuously calibrated with certified standards from Scott Specialty Gases, which in one case was 1 part per billion of the aforementioned compounds. The entire operation of the units, including monitoring instrument responses, changing operating parameters, data transfer, data reviewmore » and data reporting was done entirely on a remote basis from approximately 600 miles away using a remote computer with a modem and remote operating software. The entire system concept promises the availability of highly sensitive remote monitoring in sparsely populated areas for long periods of time.« less

The perspective of the permanent monitoring with an FBG sensor network in oil and gas production in China

NASA Astrophysics Data System (ADS)

Zhang, Yuanzhong; Xiao, Lizhi; Fu, Jianwei; Chen, Haifeng; Zhao, Xiaoliang

2005-12-01

Most of the onshore oilfields in China are in the middle and late development stages, and great deals of residual oil are waiting for exploitation. Downhole permanent sensor monitoring technology is an effective means to enhance oil and gas recovery. The concept of the downhole permanent sensor network is introduced, and the research status was reviewed. The measurement principle, application and some issues of the Distribute Temperature System (DTS) and Fiber Bragg Grating (FBG) sensor are discussed. Some potential applications of permanent monitoring with FBG sensors in oil and gas production, including enhancing oil and gas recovery and realtime monitoring of casing damaging were reviewed.

Juvenile magma recognition and eruptive dynamics inferred from the analysis of ash time series: The 2015 reawakening of Cotopaxi volcano

USGS Publications Warehouse

Gaunt, H. Elizabeth; Bernard, Benjamin; Hidalgo, Silvana; Proano, Antonio; Wright, Heather M.; Mothes, Patricia; Criollo, Evelyn; Kueppers, Ulrich

2016-01-01

Forecasting future activity and performing hazard assessments during the reactivation of volcanoes remain great challenges for the volcanological community. On August 14, 2015 Cotopaxi volcano erupted for the first time in 73 years after approximately four months of precursory activity, which included an increase in seismicity, gas emissions, and minor ground deformation. Here we discuss the use of near real-time petrological monitoring of ash samples as a complementary aid to geophysical monitoring, in order to infer eruption dynamics and evaluate possible future eruptive activity at Cotopaxi. Twenty ash samples were collected between August 14 and November 23, 2015 from a monitoring site on the west flank of the volcano. These samples contain a range of grain types that we classified as: hydrothermal/altered, lithic, juvenile, and free crystals. The relative proportions of theses grains evolved as the eruption progressed, with increasing amounts of juvenile material and a decrease in hydrothermally altered material. In samples from the initial explosion, juvenile grains are glassy, microlite-poor and contain hydrothermal minerals (opal and alunite). The rising magma came in contact with the hydrothermal system under confinement, causing hydro-magmatic explosions that cleared the upper part of the plumbing system. Subsequently, the magmatic column produced a thermal aureole in the conduit and dried out the hydrothermal system, allowing for dry eruptions. Magma ascent rates were low enough to allow for efficient outgassing and microlite growth. Constant supply of magma from below caused quasi-continuous disruption of the uppermost magma volume through a combination of shear-deformation and gas expansion. The combination of increasing crystallinity of juvenile grains, and high measured SO2 flux indicate decreasing integrated magma ascent rates and clearing of the hydrothermal system along transport pathways in a system open to gas loss. The near real-time monitoring of ash samples combined with traditional geophysical monitoring techniques during the reawakening of Cotopaxi allowed us to gain a much clearer understanding of events than when using traditional geophysical monitoring alone.

Low Power Operation of Temperature-Modulated Metal Oxide Semiconductor Gas Sensors.

PubMed

Burgués, Javier; Marco, Santiago

2018-01-25

Mobile applications based on gas sensing present new opportunities for low-cost air quality monitoring, safety, and healthcare. Metal oxide semiconductor (MOX) gas sensors represent the most prominent technology for integration into portable devices, such as smartphones and wearables. Traditionally, MOX sensors have been continuously powered to increase the stability of the sensing layer. However, continuous power is not feasible in many battery-operated applications due to power consumption limitations or the intended intermittent device operation. This work benchmarks two low-power, duty-cycling, and on-demand modes against the continuous power one. The duty-cycling mode periodically turns the sensors on and off and represents a trade-off between power consumption and stability. On-demand operation achieves the lowest power consumption by powering the sensors only while taking a measurement. Twelve thermally modulated SB-500-12 (FIS Inc. Jacksonville, FL, USA) sensors were exposed to low concentrations of carbon monoxide (0-9 ppm) with environmental conditions, such as ambient humidity (15-75% relative humidity) and temperature (21-27 °C), varying within the indicated ranges. Partial Least Squares (PLS) models were built using calibration data, and the prediction error in external validation samples was evaluated during the two weeks following calibration. We found that on-demand operation produced a deformation of the sensor conductance patterns, which led to an increase in the prediction error by almost a factor of 5 as compared to continuous operation (2.2 versus 0.45 ppm). Applying a 10% duty-cycling operation of 10-min periods reduced this prediction error to a factor of 2 (0.9 versus 0.45 ppm). The proposed duty-cycling powering scheme saved up to 90% energy as compared to the continuous operating mode. This low-power mode may be advantageous for applications that do not require continuous and periodic measurements, and which can tolerate slightly higher prediction errors.

Methods and approaches of utilizing ionic liquids as gas sensing materials

PubMed Central

Rehman, Abdul

2017-01-01

Gas monitoring is of increasing significance for a broad range of applications in the fields of environmental and civil infrastructures, climate and energy, health and safety, industry and commerce. Even though there are many gas detection devices and systems available, the increasing needs for better detection technologies that not only satisfy the high analytical standards but also meet additional device requirements (e.g., being robust to survive under field conditions, low cost, small, smart, more mobile), demand continuous efforts in developing new methods and approaches for gas detection. Ionic Liquids (ILs) have attracted a tremendous interest as potential sensing materials for the gas sensor development. Being composed entirely of ions and with a broad structural and functional diversity, i.e., bifunctional (organic/inorganic), biphasic (solid/liquid) and dual-property (solvent/electrolyte), they have the complementing attributes and the required variability to allow a systematic design process across many sensing components to enhance sensing capability especially for miniaturized sensor system implementation. The emphasis of this review is to describe molecular design and control of IL interface materials to provide selective and reproducible response and to synergistically integrate IL sensing materials with low cost and low power electrochemical, piezoelectric/QCM and optical transducers to address many gas detection challenges (e.g., sensitivity, selectivity, reproducibility, speed, stability, cost, sensor miniaturization, and robustness). We further show examples to justify the importance of understanding the mechanisms and principles of physicochemical and electrochemical reactions in ILs and then link those concepts to developing new sensing methods and approaches. By doing this, we hope to stimulate further research towards the fundamental understanding of the sensing mechanisms and new sensor system development and integration, using simple sensing designs and flexible sensor structures both in terms of scientific operation and user interface that can be miniaturized and interfaced with modern wireless monitoring technologies to achieve specifications heretofore unavailable on current markets for the next generation of gas sensor applications. PMID:29142738