DOE Office of Scientific and Technical Information (OSTI.GOV)

Blanpied, G.D.

Trees of seedling apple (Malus domesticas borkh.) received 2.5 cm of artificial rain at pH 3.3 or 4.2, each with 0.4 or 1.4 mg Ca/liter of rain water during 7-hour periods. In the early summer period (June 19-July 10) artificial rain reduced Ca in apple leaves, but there were no significant differences due to pH or Ca concentration in the rain. Ca losses during rain treatment appeared to be recovered during 1 week holding periods after treatment. In the autumn period (September 25-October 16) the reduction in leaf Ca was greatest wih low pH, low Ca rain and least withmore » high pH, high Ca rain, which increased Ca in the leaves. K in the leaves was reduced more than Ca, but was not affected by pH or Ca in the rain during either period of observation.« less

Effects of acid rain on grapevines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forsline, P.L.; Musselman, R.C.; Dee, R.J.

1983-01-01

Mature vineyard-growing Concord grapevines were sprayed with simulated acid rain solutions ranging from pH 2.5 to 5.5 both as acute treatments at anthesis and chronically throughout the season in 1980 and 1981. In 1981, 8 additional varieties were also treated with simulated acid rain solutions at pH 2.75 and 3.25. With Concord in 1981, few foliar lesions on leaves were visible at pH 2.75. In contrast, many leaf lesions with decreased fruit soluble solids were observed at pH 2.5 in 1980. The relationship between acid-rain and oxidant stipple, chlorosis, and soluble solids in the absence of acid rain leaf lesionsmore » at pH>2.5 remains unclear. Acute sprays (pH2.75) at anthesis reduced pollen germination in four grape cultivars. However, fruit set was reduced in only one of these. Grape yields were not influenced by acid rain treatments. There was no evidence that acid-rain at ambient pH levels had negative effects on grape production or fruit quality.« less

Effects of simulated acid rain on soil fauna community composition and their ecological niches.

PubMed

Wei, Hui; Liu, Wen; Zhang, Jiaen; Qin, Zhong

2017-01-01

Acid rain is one of the severest environmental issues globally. Relative to other global changes (e.g., warming, elevated atmospheric [CO 2 ], and nitrogen deposition), however, acid rain has received less attention than its due. Soil fauna play important roles in multiple ecological processes, but how soil fauna community responds to acid rain remains less studied. This microcosm experiment was conducted using latosol with simulated acid rain (SAR) manipulations to observe potential changes in soil fauna community under acid rain stress. Four pH levels, i.e., pH 2.5, 3.5, 4.5, and 5.5, and a neutral control of pH 7.0 were set according to the current pH condition and acidification trend of precipitation in southern China. As expected, we observed that the SAR treatments induced changes in soil fauna community composition and their ecological niches in the tested soil; the treatment effects tended to increase as acidity increased. This could be attributable to the environmental stresses (such as acidity, porosity and oxygen supply) induced by the SAR treatments. In addition to direct acidity effect, we propose that potential changes in permeability and movability of water and oxygen in soils induced by acid rain could also give rise to the observed shifts in soil fauna community composition. These are most likely indirect pathways of acid rain to affect belowground community. Moreover, we found that nematodes, the dominating soil fauna group in this study, moved downwards to mitigate the stress of acid rain. This is probably detrimental to soil fauna in the long term, due to the relatively severer soil conditions in the deep than surface soil layer. Our results suggest that acid rain could change soil fauna community and the vertical distribution of soil fauna groups, consequently changing the underground ecosystem functions such as organic matter decomposition and greenhouse gas emissions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Acid Rain, pH & Acidity: A Common Misinterpretation.

ERIC Educational Resources Information Center

Clark, David B.; Thompson, Ronald E.

1989-01-01

Illustrates the basis for misleading statements about the relationship between pH and acid content in acid rain. Explains why pH cannot be used as a measure of acidity for rain or any other solution. Suggests that teachers present acidity and pH as two separate and distinct concepts. (RT)

[Effects of simulated acid rain on decomposition of soil organic carbon and crop straw].

PubMed

Zhu, Xue-Zhu; Huang, Yao; Yang, Xin-Zhong

2009-02-01

To evaluate the effects of acid rain on the organic carbon decomposition in different acidity soils, a 40-day incubation test was conducted with the paddy soils of pH 5.48, 6.70 and 8.18. The soils were amended with 0 and 15 g x kg(-1) of rice straw, adjusted to the moisture content of 400 g x kg(-1) air-dried soil by using simulated rain of pH 6.0, 4.5, and 3.0, and incubated at 20 degrees C. The results showed that straw, acid rain, and soil co-affected the CO2 emission from soil system. The amendment of straw increased the soil CO2 emission rate significantly. Acid rain had no significant effects on soil organic carbon decomposition, but significantly affected the straw decomposition in soil. When treated with pH 3.0 acid rain, the amount of decomposed straw over 40-day incubation in acid (pH 5.48) and alkaline (pH 8.18) soils was 8% higher, while that in neutral soil (pH 6.70) was 15% lower, compared to the treatment of pH 6.0 rain. In the treatment of pH 3.0 acid rain, the decomposition rate of soil organic C in acid (pH 5.48) soil was 43% and 50% (P < 0.05) higher than that in neutral (pH 6.70) and alkaline (pH 8.18) soils, while the decomposition rate of straw in neutral soil was 17% and 16% (P < 0.05) lower than that in acid and alkaline soils, respectively.

[Relationship between simulated acid rain stress and leaf reflectance].

PubMed

Song, Xiao-dong; Jiang, Hong; Yu, Shu-quan; Zhou, Guo-mo; Jiang, Zi-shan

2010-01-01

Acid rain is a worldwide environmental problem. Serious acid rain pollution in subtropical China has constituted a potential threat to the health of the local forest. In the present paper, the changing properties of the chlorophyll concentration and spectral reflectance at the visible wavelengths for the six subtropical broad-leaved tree species leaves under simulated acid rain (SAR) treatment with different pH levels were studied. With the increasing strength of the SAR, the chlorophyll concentrations of the experimental species under pH 2.5 and pH 4.0 treatment were higher than that under pH 5.6; the spectral reflectance at the visible wavelengths for pH 2.5 and pH 4.0 were lower than that for pH 5.6 in general; while there weren't significant differences between pH 2.5 and pH 4.0. After the treatment with different levels of SAR, the differences in spectral reflectance at the visible wavelengths mainly focused around the green peak and red edge on the reflectance curve. The subtropical broad-leaved tree species studied were relatively not sensitive to acid rain stresses; some stronger acid rain may accelerate the growth of the tree species used here to some extent.

Acid rain phenomenon in niger delta region of Nigeria: economic, biodiversity, and public health concern.

PubMed

Nduka, J K C; Orisakwe, O E; Ezenweke, L O; Ezenwa, T E; Chendo, M N; Ezeabasili, N G

2008-08-28

Rain samples were collected from Warri and Port Harcourt, two major oil-producing cities of Nigeria in April-June, July-August, and September-October 2005 and 2006. Awka, a "non-oil" city was used as control. Samples were collected from three points, using clean plastic basins fastened to a table, 2 m above ground level and 115 m away from tall buildings and trees. Water samples were filtered and acidity determined using digital pH meter. The results show that the rain samples were acidic. The pH values for the 2 years under study show that the rainfall in Warri was more acidic than that of Port Harcourt. Oil exploration and other anthropogenic sources may be responsible for the acid rain in the Niger Delta region of Nigeria.

Effects of acid rain on grapevines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forsline, P.L.; Musselman, R.C.; Dee, R.J.

1983-01-01

Mature vineyard-growing Concord grapevines (Vitis labrusca, Bailey) were sprayed with simulated acid rain solutions ranging from pH 2.5 to pH 5.5 both as acute treatments at anthesis and chronically throughout the season in 1980 and 1981. In 1981, eight additional varieties were also treated with simulated acid rain solutions at pH 2.75 and pH 3.25. With Concord in 1981, few foliar lesions on leaves were visible at pH 2.75. In contrast, many leaf lesions with decreased fruit soluble solids in the absence of acid rain leaf lesions at pH>2.5 remains unclear. Acute sprays (pH 2.75) at anthesis reduced pollen germinationmore » in four grape cultivars. However, fruit set was reduced in only one of these. Only the cultivars de Chaunac and Ives had reduced berry soluble solids with chronic weekly sprays at pH 2.75. Reduction in soluble solids was not associated with increased oxidant stipple (ozone injury) in Concord and de Chaunac cultivars, but this association was observed in Ives. There was no evidence that acid rain in combination with ozone increased oxidant stipple as occurs when ozone and SO/sub 2/ are combined. Grape yields were not influenced by acid rain treatments. There was no evidence that acid rain at ambient pH levels had negative effects on grape production or fruit quality.« less

[Effects of simulated acid rain on oilseed rape (Brassica napus) physiological characteristics at flowering stage and yield].

PubMed

Cao, Chun-Xin; Zhou, Qin; Han, Liang-Liang; Zhang, Pei; Jiang, Hai-Dong

2010-08-01

A pot experiment was conducted to study the effects of different acidity simulated acid rain on the physiological characteristics at flowering stage and yield of oilseed rape (B. napus cv. Qinyou 9). Comparing with the control (pH 6.0), weak acidity (pH = 4.0-5.0) simulated acid rain stimulated the rape growth to some extent, but had less effects on the plant biomass, leaf chlorophyll content, photosynthetic characteristics, and yield. With the further increase of acid rain acidity, the plant biomass, leaf chlorophyll content, photosynthetic rate, antioxidative enzyme activities, and non-enzyme antioxidant contents all decreased gradually, while the leaf malonyldialdehyde (MDA) content and relative conductivity increased significantly. As the results, the pod number per plant, seed number per pod, seed weight, and actual yield decreased. However, different yield components showed different sensitivity to simulated acid rain. With the increasing acidity of simulated acid rain, the pod number per plant and the seed number per pod decreased significantly, while the seed weight was less affected.

Comparative effects of simulated acid rain of different ratios of SO42- to NO3- on fine root in subtropical plantation of China.

PubMed

Liu, Xin; Zhao, Wenrui; Meng, Miaojing; Fu, Zhiyuan; Xu, Linhao; Zha, Yan; Yue, Jianmin; Zhang, Shuifeng; Zhang, Jinchi

2018-03-15

The influence of acid rain on forest trees includes direct effects on foliage as well as indirect soil-mediated effects that cause a reduction in fine-root growth. In addition, the concentration of NO 3 - in acid rain increases with the rapidly growing of nitrogen deposition. In this study, we investigated the impact of simulated acid rain with different SO 4 2- /NO 3 - (S/N) ratios, which were 5:1 (S), 1:1 (SN) and 1:5 (N), on fine-root growth from March 2015 to February 2016. Results showed that fine roots were more sensitive to the effects of acid rain than soils in the short-term. Both soil pH and fine root biomass (FRB) significantly decreased as acid rain pH decreased, and also decreased with the percentage of NO 3 - increased in acid rain. Acid rain pH significantly influenced soil total carbon and available potassium in summer. Higher acidity level (pH=2.5), especially of the N treatments, had the strongest inhibitory impact on soil microbial activity after summer. The structural equation modelling results showed that acid rain S/N ratio and pH had stronger direct effects on FRB than indirect effects via changed soil and fine root properties. Fine-root element contents and antioxidant enzymes activities were significantly affected by acid rain S/N ratio and pH during most seasons. Fine-root Al ion content, Ca/Al, Mg/Al ratios and catalase activity were used as better indicators than soil parameters for evaluating the effects of different acid rain S/N ratios and pH on forests. Our results suggest that the ratio of SO 4 2- to NO 3 - in acid rain is an important factor which could affect fine-root growth in subtropical forests of China. Copyright © 2017. Published by Elsevier B.V.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forsline, P.L.; Musselman, R.C.; Kender, W.J.

Mature 'McIntosh', 'Empire', and 'Golden Delicious' apple trees (Malus domestica Borkh.) were sprayed with simulated acid rain solutions in the pH range of 2.5 to 5.5 at full bloom in 1980 and in 1981. In 1981, weekly sprays were applied at pH 2.75 and pH 3.25. Necrotic lesions developed on apple petals at pH 2.5 with slight injury appearing at pH 3.0 and pH 3.5. Apple foliage had no acid rain lesions at any of the pH levels tested. Pollen germination was reduced at ph 2.5 in 'Empire'. Slight fruit set reduction at pH 2.5 was observed in 'McIntosh'. Themore » incidence of russetting on 'Golden Delicious' fruits was ameliorated by the presence of rain-exclusion chambers but was not affected by acid rain. With season-long sprays at pH 2.75, there was a slight delay in maturity and lower weight of 'McIntosh' apples. Even at the lowest pH levels no detrimental effects of simulated acid rain were found on apple tree productivity and fruit quality when measured as fruit set, seed number per fruit, and fruit size and appearance.« less

Time dependence of the pH of rain

Treesearch

John A. Kadlecek; Volkar A. Mohnen

1976-01-01

Standard procedures for determining the pH of rain samples usually involve substantial delays from the time of rainfall to the time of analysis. This assumes that no change in pH occurs during the storage period. We have found that this is not always true. We have determined that individual rain water samples possess a time dependent pH which can be correlated with the...

[Effects of simulated acid rain on seed germination and seedling growth of different type corn Zea mays].

PubMed

Zhang, Hai-Yan

2013-06-01

Taking normal corn, waxy corn, pop corn, and sweet corn as test materials, this paper studied their seed germination and seedling growth under effects of simulated acid rain (pH 6.0, 5.0, 4.0, 3.0, 2.0, and 1.0). Simulated acid rain at pH 2.0-5.0 had no significant effects on the seed germination and seedling growth, but at pH 1.0, the germination rate of normal corn, waxy corn, pop corn, and sweet corn was 91.3%, 68.7%, 27.5%, and 11.7%, respectively. As compared with those at pH 6.0 (CK), the germination rate, germination index, vigor index, germination velocity, shoot height, root length, shoot and root dry mass, and the transformation rate of stored substances at pH 1.0 had significant decrease, and the average germination time extended apparently. At pH 1.0, the effects of acid rain were greater at seedling growth stage than at germination stage, and greater on underground part than on aboveground part. Due to the differences in gene type, normal corn and waxy corn had the strongest capability against acid rain, followed by pop corn, and sweet corn. It was suggested that corn could be categorized as an acid rain-tolerant crop, the injury threshold value of acid rain was likely between pH 1.0 and pH 2.0, and normal corn and waxy corn would be prioritized for planting in acid rain-stricken area.

Influence of simulated acidic rain on bacterial speck of tomato. [Lycopersicon esculentum Mill var. 'Chico III', Pseudomonas tomato

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bisessar, S.; Palmer, K.T.; Kuja, A.L.

Ambient rain in southern Ontario has a volume-weighted average pH of approximately 4.2. Tomato (Lycopersicon esculentum Mill var. 'Chico III') seedlings were exposed to simulated acidic rain in specially designed chambers. The inoculum of Pseudomonas tomato (Okabe) Alstatt, causal agent of bacterial speck, was sprayed on plants before or after exposure to acidic rain of pH 2.5, 3.5, and 4.5, as well as on plants not exposed to the simulated acidic rain. Speck symptoms (small, dark, brown spots with yellow halos) were found on all inoculated plants. Exposure of plants to simulted acidic rain inhibited speck development, but the inhibitionmore » was greater on plants exposed to acidic rain after inoculation. Spot necrosis, a typical response to acid rain, occurred on up to 15 to 20% of the leaf area on all tomato plants treated with acidic rain at pH 2.5. Plants alos showed a decrease in growth (height and fresh and dry weights) with an increase in rain acidity. Leaves injured by simulated acidic rain and examined histopathologically displayed cellular malformations including hyperplasia and hypertrophy. Pseudomonas tomato failed to grow on acidified King B medium or Difco nutrient broth adjusted to pH 3.5 or lower.« less

Effects of sulfuric, nitric, and mixed acid rain on Chinese fir sapling growth in Southern China.

PubMed

Liu, Xin; Fu, Zhiyuan; Zhang, Bo; Zhai, Lu; Meng, Miaojing; Lin, Jie; Zhuang, Jiayao; Wang, G Geoff; Zhang, Jinchi

2018-09-30

The influence of acid rain on plant growth includes direct effects on foliage as well as indirect soil-mediated effects that cause a reduction in root growth. In addition, the concentration of NO 3 - in acid rain increases along with the rapid growth of nitrogen deposition. In this study, we investigated the impact of simulated acid rain with different SO 4 2- /NO 3 - (S/N) ratios, which were 1:0, 5:1, 1:1, 1:5 and 0:1, on Chinese fir sapling growth from March 2015 to April 2016. Results showed that Chinese fir sapling height growth rate (HGR) and basal diameter growth rate (DGR) decreased as acid rain pH decreased, and also decreased as the percentage of NO 3 - increased in acid rain. Acid rain pH significantly decreased the Chlorophyll a (Chla) and Chlorophyll b (Chlb) content, and Chla and Chlb contents with acid rain S/N 1:5 were significantly lower than those with S/N 1:0 at pH 2.5. The chlorophyll fluorescence parameters, maximal efficiency of Photosystem II photochemistry (Fv/Fm) and non-photochemical quenching coefficient (NPQ), with most acid rain treatments were significantly lower than those with CK treatments. Root activities first increased and then decreased as acid rain pH decreased, when acid rain S/N ratios were 1:1, 1:5 and 0:1. Redundancy discriminant analysis (RDA) showed that the Chinese fir DGR and HGR had positive correlations with Chla, Chlb, Fv/Fm ratio, root activity, catalase and superoxide dismutase activities in roots under the stress of acid rain with different pH and S/N ratios. The structural equation modelling (SEM) results showed that acid rain NO 3 - concentration and pH had stronger direct effects on Chinese fir sapling HGR and DGR, and the direct effects of acid rain NO 3 - concentration and pH on HGR were lower than those on DGR. Our results suggest that the ratio of SO 4 2- to NO 3 - in acid rain is an important factor which could affect the sustainable development of monoculture Chinese fir plantations in southern China. Copyright © 2018. Published by Elsevier Inc.

Acid-rain induced changes in streamwater quality during storms on Catoctin Mountain, Maryland

USGS Publications Warehouse

Rice, Karen C.; Bricker, O.P.

1992-01-01

Catoctin Mountain receives some of the most acidic (lowest pH) rain in the United States. In 1990, the U.S. Geological Survey (USGS), in cooperation with the Maryland Department of the Environment (MDE) and the Maryland Department of Natural Resources (DNR), began a study of the effects of acid rain on the quality of streamwater on the part of Catoctin Mountain within Cunningham Falls State Park, Maryland (fig. 1). Samples of precipitation collected on the mountain by the USGS since 1982 have been analyzed for acidity and concentration of chemical constituents. During 1982-91, the volume-weighted average pH of precipitation was 4.2. (Volume weighting corrects for the effect of acids being washed out of the atmosphere at the beginning of rainfall). The pH value is measured on a logarithmic scale, which means that for each whole number change, the acidity changes by a factor of 10. Thus rain with a pH of 4.2 is more than 10 times as acidic as uncontaminated rain, which has a pH of about 5.6. The acidity of rain during several rainstorms on Catoctin Mountain was more than 100 times more acidic than uncontaminated rain.

Study on the relationship between meteorological conditions and acid rain in mid-eastern Fujian.

PubMed

Lin, C C; Liu, J X; Cai, Y Y; Li, B L; Wang, Z L; Chen, B B

2009-08-01

Based on the acid rain observation data and the contemporaneous historical synoptic charts of Mid-Eastern Fujian during the period of 1991 to 2003, we analyzed the distribution characteristics of acid rain in different seasons, weather types, precipitation grades and wind directions. The results showed that the acid pollution in Mid-Eastern Fujian was still serious. In winter, the precipitation pH value was 4.79, and the acid rain frequency was 60.62% which was twice higher than that in summer. The pH value of warm shear-type precipitation at 850 hPa was 4.79. Nearly half of these precipitations had the problems of acid rain pollution. The acid rain frequency of the inverted trough type was only 26.11% which was the lowest one in all types. There was no marked difference of the acid rain distribution characteristics between ahead-of-trough and behind-the-trough. The precipitation pH values of the five grades were lower than 5.30 and the acid rain frequency changed as an inverted U shape with the increasing of the rainfall. The pH values of precipitations in the eight wind directions were generally below 5.20, and the acid rain frequencies were about 40%.

Leaching Characteristics of Calcium and Strontium from Phosphogypsum Under Acid Rain.

PubMed

Wang, Mei; Luo, Houqiao; Chen, Yong; Yang, Jinyan

2018-02-01

Phosphogypsum (PG) stored close to phosphorus chemical plants has caused worldwide environmental problems. Column leaching experiments were conducted to evaluate Ca and Sr leaching from PG under simulated acid rain at pH levels typical for rain in the study region (Shifang, China). High concentrations of Ca and Sr in leachates in the first five leaching events could pollute the soil and groundwater around the PG. Leachates pH was lower than and had no correlation with simulated rain pH. No correlations between simulated rain pH and cumulative Ca and Sr content in leachates were noted. Around 2.0%-2.2% of Ca and 0.5%-0.6% of Sr were leached out from PG by the simulated summer rainfall in Shifang. Electrical conductivity values, Ca and Sr concentrations at bottom sections of PG columns were higher than those of top sections, while pH values showed a reverse trend. More precautions should be taken to protect the environment around PG stacks.

Effects of acidic precipitation on host-parasite interactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shriner, D.S.

1974-01-01

During the past decade, the average acidity of rain and snow increased by 1-2 pH units in many parts of Europe and North America. Little is known of the effects of acid rain resulting from dissolution of sulfur dioxide on biological systems. The effects of simulated sulfuric acid rain on four host-pathogen system were studied. Plants were exposed in greenhouse and field to simulated rain of pH 3.2 or pH 6.0 in amounts and intervals common to weather patterns of the eastern United States. Simulated acid rain resulted in: (1) an 86% inhibition in telia production of Cronartium fusiforme onmore » willow oak (Quercus phellos); (2) a 66% inhibition in the production of root-knot nematodes (Meloidogyne hapla) on field grown kidney beans (Phaseolus vulgaris Red Kidney); (3) a 20% decrease in the severity of Uromyces phaseoli infection of field grown kidney beans; and (4) either stimulated or inhibited development of halo blight on kidney bean (caused by Pseudomonas phaseolicola) depending upon the segment of the disease cycle in which the stress occurred: (a) simulated acid rain before inoculation stimulated disease development; (b) suspension of inoculum in acid rain decreased inoculum potential; and (c) acid rain after infection inhibited disease development. Results suggest that the pH of rain is a new environmental parameter of concern to plant pathologists.« less

Comparative Analysis of Nitrate Levels in Pensacola Area Rain Water

NASA Astrophysics Data System (ADS)

Jacobs, J.; Caffrey, J. M.; Maestre, A.; Landing, W. M.

2017-12-01

Nitrate is an important constituent of acid rain and often correlated with atmospheric NOx levels. This link between air and water quality was tested over a course of summer 2017 and compared to data from 2005-2012. Rain water samples collected from late May through early July of 2017 were tested for pH and nitrate concentrations. These months were among the stormiest on record for the Northwest Florida region with a total rainfall of 648 mm. The data analyzed from these rain events was compared to previous data to show the trends of nitrate and pH levels in the rainwater. Median pH for this study was 5.2, higher than the medians between 2015-2012 which ranged from 4.2 to 5.0, while nitrate concentrations for this study were 15.2 µM. This contrasts with a significant drop in nitrate concentrations from 41 µM in 2005 and 2006 to around 12 µM between 2007 and 2012. The drop between 2006-7 was suspected to be a result of implementation of NOx controls at Plant Crist coal fired power plant and other Clean Air Act requirements. These inputs of nitrate and H+ ions from rainwater can have a significant influence water quality throughout the region.

Leaching behavior of heavy metals and transformation of their speciation in polluted soil receiving simulated acid rain.

PubMed

Zheng, Shun-an; Zheng, Xiangqun; Chen, Chun

2012-01-01

Heavy metals that leach from contaminated soils under acid rain are of increasing concern. In this study, simulated acid rain (SAR) was pumped through columns of artificially contaminated purple soil. Column leaching tests and sequential extraction were conducted for the heavy metals Cu, Pb, Cd, and Zn to determine the extent of their leaching as well as to examine the transformation of their speciation in the artificially contaminated soil columns. Results showed that the maximum leachate concentrations of Cu, Pb, Cd, and Zn were less than those specified in the Chinese Quality Standards for Groundwater (Grade IV), thereby suggesting that the heavy metals that leached from the polluted purple soil receiving acid rain may not pose as risks to water quality. Most of the Pb and Cd leachate concentrations were below their detection limits. By contrast, higher Cu and Zn leachate concentrations were found because they were released by the soil in larger amounts as compared with those of Pb and Cd. The differences in the Cu and Zn leachate concentrations between the controls (SAR at pH 5.6) and the treatments (SAR at pH 3.0 and 4.5) were significant. Similar trends were observed in the total leached amounts of Cu and Zn. The proportions of Cu, Pb, Cd, and Zn in the EXC and OX fractions were generally increased after the leaching experiment at three pH levels, whereas those of the RES, OM, and CAR fractions were slightly decreased. Acid rain favors the leaching of heavy metals from the contaminated purple soil and makes the heavy metal fractions become more labile. Moreover, a pH decrease from 5.6 to 3.0 significantly enhanced such effects.

Leaching Behavior of Heavy Metals and Transformation of Their Speciation in Polluted Soil Receiving Simulated Acid Rain

PubMed Central

Zheng, Shun-an; Zheng, Xiangqun; Chen, Chun

2012-01-01

Heavy metals that leach from contaminated soils under acid rain are of increasing concern. In this study, simulated acid rain (SAR) was pumped through columns of artificially contaminated purple soil. Column leaching tests and sequential extraction were conducted for the heavy metals Cu, Pb, Cd, and Zn to determine the extent of their leaching as well as to examine the transformation of their speciation in the artificially contaminated soil columns. Results showed that the maximum leachate concentrations of Cu, Pb, Cd, and Zn were less than those specified in the Chinese Quality Standards for Groundwater (Grade IV), thereby suggesting that the heavy metals that leached from the polluted purple soil receiving acid rain may not pose as risks to water quality. Most of the Pb and Cd leachate concentrations were below their detection limits. By contrast, higher Cu and Zn leachate concentrations were found because they were released by the soil in larger amounts as compared with those of Pb and Cd. The differences in the Cu and Zn leachate concentrations between the controls (SAR at pH 5.6) and the treatments (SAR at pH 3.0 and 4.5) were significant. Similar trends were observed in the total leached amounts of Cu and Zn. The proportions of Cu, Pb, Cd, and Zn in the EXC and OX fractions were generally increased after the leaching experiment at three pH levels, whereas those of the RES, OM, and CAR fractions were slightly decreased. Acid rain favors the leaching of heavy metals from the contaminated purple soil and makes the heavy metal fractions become more labile. Moreover, a pH decrease from 5.6 to 3.0 significantly enhanced such effects. PMID:23185399

Effect of simulated acid rain on the mutualism between tall fescue (Festuca arundinacea) and an endophytic fungus (Acremonium coenophialum)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheplick, G.P.

Biotic interactions between plants and microorganisms have the potential to be affected by acidic precipitation. I examined the effect of simulated sulfuric acid rain on the mutualism between a perennial forage grass (Festuca arundinacea) and a fungal endophyte (Acremonium coenophialum). Acid water was supplied as mists sprayed onto leaf surfaces or as water added to the soil for two groups in a greenhouse: one group had high levels of endophyte infection, while the other was predominantly noninfected. Control plants received distilled water (pH 6), while others received sulfuric acid water at pH 4.5 or pH 3. Plants were harvested aftermore » 4, 6, 8, and 23 wk. Leaf endophyte infection intensity as measured by hyphal counts was not affected by acid water treatment. Root mass and root: shoot ratios generally decreased with increasing acidity of both foliar sprays and soil water, but shoot mass was mostly not affected. There was a significant pH x infection interaction for plants exposed to acidic foliar sprays for 4 wk; root and shoot mass decreased with acidity, but only for infected plants. It was found that acid rain may be deleterious to tall fescue growth at specific stages of development, but biomass production in response to acid rain is not likely to be influenced by fungal endophytes within mature plants. 55 refs., 2 figs., 3 tabs.« less

ACID RAIN AND SOIL MICROBIAL ACTIVITY: EFFECTS AND THEIR MECHANISMS

EPA Science Inventory

In the investigation, our aim was to determine if acid rain affects soil microbial activity and to identify possible mechanisms of observed effects. A Sierran forest soil (pH 6.4) planted with Ponderosa pine seedlings was exposed to simulated rain (pH 2.0, 3.0, 4.0 and 5.6) with ...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forsline, P.L.; Musselman, R.C.; Kender, W.J.

Mature McIntosh, Empire, and Golden Delicious apple trees (Malus domestica) were sprayed with simulated acid rain solutions in the pH range of 2.5 to 5.5 at full bloom in 1980 and 1981. In 1981, weekly sprays were applied at pH 2.75 and pH 3.25. Necrotic lesions developed on apple petals at pH 2.5 with slight injury appearing at pH 3.0 and 3.5. Apple foliage had no acid rain lesions at any of the pH levels tested. Pollen germination was reduced at pH 2.5 in Empire. Slight fruit set reduction at pH 2.5 was observed in McIntosh. Even at the lowestmore » pH levels no detrimental effects of simulated acid rain were found on apple tree productivity and fruit quality when measured as fruit set, seed number per fruit, and fruit size and appearance.« less

Growth of ponderosa pine seedlings as affected by air pollution

NASA Astrophysics Data System (ADS)

Momen, B.; Anderson, P. D.; Houpis, J. L. J.; Helms, J. A.

The effect of air pollution on seedling survival and competitive ability is important to natural and artificial regeneration of forest trees. Although biochemical and physiological processes are sensitive indicators of pollution stress, the cumulative effects of air pollutants on seedling vigor and competitive ability may be assessed directly from whole-plant growth characteristics such as diameter, height, and photosynthetic area. A few studies that have examined intraspecific variation in seedling response to air pollution indicate that genotypic differences are important in assessing potential effects of air pollution on forest regeneration. Here, we studied the effects of acid rain (no-rain, pH 5.1 rain, pH 3.0 rain) and ozone (filtered, ambient, twice-ambient) in the field on height, diameter, volume, the height:diameter ratio, maximum needle length, and time to reach maximum needle length in seedlings of three families of ponderosa pine ( Pinus ponderosa Dougl. ex Laws). Seedling diameter, height, volume, and height:diameter ratio related significantly to their pre-treatment values. Twice-ambient ozone decreased seedling diameter compared with ozone-filtered air. A significant family-by-ozone interaction was detected for seedling height, as the height of only one of the three families was decreased by twice-ambient ozone compared with the ambient level. Seedling diameter was larger and the height:diameter ratio was smaller under pH 3.0 rain compared to either the no-rain or the pH 5.1-rain treatment. This suggests greater seedling vigor, perhaps due to a foliar fertilization effect of the pH 3.0 rain.

Non-linear direct effects of acid rain on leaf photosynthetic rate of terrestrial plants.

PubMed

Dong, Dan; Du, Enzai; Sun, Zhengzhong; Zeng, Xuetong; de Vries, Wim

2017-12-01

Anthropogenic emissions of acid precursors have enhanced global occurrence of acid rain, especially in East Asia. Acid rain directly suppresses leaf function by eroding surface waxes and cuticle and leaching base cations from mesophyll cells, while the simultaneous foliar uptake of nitrates in rainwater may directly benefit leaf photosynthesis and plant growth, suggesting a non-linear direct effect of acid rain. By synthesizing data from literature on acid rain exposure experiments, we assessed the direct effects of acid rain on leaf photosynthesis across 49 terrestrial plants in China. Our results show a non-linear direct effect of acid rain on leaf photosynthetic rate, including a neutral to positive effect above pH 5.0 and a negative effect below that pH level. The acid rain sensitivity of leaf photosynthesis showed no significant difference between herbs and woody species below pH 5.0, but the impacts above that pH level were strongly different, resulting in a significant increase in leaf photosynthetic rate of woody species and an insignificant effect on herbs. Our analysis also indicates a positive effect of the molar ratio of nitric versus sulfuric acid in the acid solution on leaf photosynthetic rate. These findings imply that rainwater acidity and the composition of acids both affect the response of leaf photosynthesis and therefore result in a non-linear direct effect. Copyright © 2017 Elsevier Ltd. All rights reserved.

Acid rain research program. Annual progress report, September 1975--June 1976

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evans, L.S.; Raynor, G.S.

1976-09-01

The aims of the research program are: (a) to observe the minimum threshold dose of simulated acid rain to produce visual and histological effects on plant foliage, (b) approach threshold limits of simulated sulfate acid rain that affect plant growth and reproduction, and (c) to measure chemical and meteorological parameters of incident rain. Acute leaf injury to several plant species resulted from exposure of foliage to simulated sulfate acid rain of pH level 2.3 to 2.9. Only slight injury occurred at 3.1. Scanning electron micrographs showed that injury to upper leaf surfaces occurred mostly at the base of trichomes (leafmore » hairs) and near stomata. An association of lesion development near vascular tissue was also noted. Histologically, lesions are characterized by an initial collapse of the epidermis with eventual lysis and collapse of more internal leaf tissues on the upper leaf surface of pinto beans which complemented detailed descriptions of visual lesion development after daily exposures to simulated rain. Initial experiments with gametophytes of Pteridium aquilinum show that reproduction of this fern species is very sensitive to solutions of pH 5.2 while vegetative development is not affected at pH levels of 2.2. Initial rain samples from the sequential sampler have been obtained. Initial portions of rain events exhibit a pH near 3.0 in some cases. More complete chemical analyses are anticipated.« less

Effects of simulated acid rain on microbial characteristics in a lateritic red soil

Treesearch

Hua-qin Xu; Jia-en Zhang; Ying Ouyang; Ling Lin; Guo-ming Quan; Ben-liang Zhao; Jia-yu Yu

2015-01-01

A laboratory experiment was performed to examine the impact of simulated acid rain (SAR) on nutrient leaching, microbial biomass, and microbial activities in a lateritic red soil in South China. The soil column leaching experiment was conducted over a 60-day period with the following six SAR pH treatments (levels): 2.5, 3.0, 3.5, 4.0, 4.5, and 5.0 and one control...

Effects of simulated acid rain on pollen physiology and ultrastructure in the apple.

PubMed

Bellani, L M; Rinallo, C; Muccifora, S; Gori, P

1997-01-01

Viability, germination and tube length were investigated in pollen grains of field-grown 'Summerred' apple trees (Malus domestica Borkh) exposed to deionized water, rainfall or simulated acid rain at pH 5.6, 4.0 and 3.0. Pollen viability and germination significantly decreased with lower values of pH and with increasing number of treatments. The effects of pH 5.6 and natural rainfall were not significant. Electron microscope investigation of vegetative pollen cells of plants exposed to acid rain at pH 4.0 and 3.0 showed modified features in mitochondria, plastids and endoplasmic reticulum.

Low pH affects survival, growth, size distribution, and carapace quality of the postlarvae and early juveniles of the freshwater prawn Macrobrachium rosenbergii de Man

NASA Astrophysics Data System (ADS)

Kawamura, Gunzo; Bagarinao, Teodora; Yong, Annita Seok Kian; Chen, Chiau Yu; Noor, Siti Norasidah Mat; Lim, Leong Seng

2015-06-01

Acidification of rain water caused by air pollutants is now recognized as a serious threat to aquatic ecosystems. We examined the effects of low pH (control pH 7.5, pH 6, pH 5, pH 4) on the survival, growth, and shell quality of Macrobrachium rosenbergii postlarvae and early juveniles in the laboratory. Hatcheryproduced postlarvae (PL 5) were stocked at 250 PL per aquarium, acclimated over 7 d to experimental pH adjusted with hydrochloric acid, and reared for 30 d. Dead specimens were removed and counted twice a day. After 27 d rearing, all specimens were measured for total length and body weight. Carapace quality was assessed by spectrophotometry. Survival of juveniles was highest at pH 6 (binomial 95% confidence interval 79 - 89%) followed by control pH 7.5 (56 - 68%) and pH 5 (50 - 60%) and was lowest for unmetamorphosed postlarvae and juveniles at pH 4 (43 - 49%). The final median total length and body weight of juveniles were similar at control pH 7.5 (18.2 TL, 50.2 mg BW) and pH 6 (17.7 mm TL, 45.0 mg BW) but significantly less at pH 5 (16.7 mm TL, 38.2 mg BW); at pH 4, the postlarvae did not metamorphose and measured only 9.8 mm TL, 29.3 mg BW. Length frequency distribution showed homogeneous growth at pH 6, positive skew at control pH 7.5 and pH 5, and extreme heterogeneity at pH 4. The carapace showed different transmittance spectra and lower total transmittance (i.e. thicker carapace) in juveniles at pH 7.5, pH 6, and pH 5 than in unmetamorphosed postlarvae and juveniles with thinner carapace at pH 4. Thus, survival, growth, size distribution, and carapace quality of M. rosenbergii postlarvae and early juveniles were negatively affected by pH 5 and especially pH 4. The thinner carapace of the survivors at pH 4 was mostly due to their small size and failure to metamorphose. Natural waters affected by acid rain could decimate M. rosenbergii populations in the wild.

[Responses of rhizosphere nitrogen and phosphorus transformations to different acid rain intensities in a hilly red soil tea plantation].

PubMed

Chen, Xi; Chen, Fu-sheng; Ye, Su-qiong; Yu, Su-qin; Fang, Xiang-min; Hu, Xiao-fei

2015-01-01

Tea (Camellia sinensis) plantation in hilly red soil region has been long impacted by acid deposition, however its effects on nitrogen (N) and phosphorus (P) transformations in rhizosphere soils remain unclear. A 25-year old tea plantation in a typical hilly red soil region was selected for an in situ simulation experiment treated by pH 4.5, pH 3.5, pH 2.5 and control. Rhizosihere and bulk soils were collected in the third year from the simulated acid deposition experiment. Soil mineral N, available P contents and major enzyme activities were analyzed using the chemical extraction and biochemical methods, and N and P mineralization rates were estimated using the indoor aerobic incubation methods. Our results showed that compared to the control, the treatments of pH 4.5, pH 3.5 and pH 2.5, respectively decreased 7.1%, 42.1% and 49.9% NO3(-)-N, 6.4%, 35.9% and 40.3% mineral N, 10.5%, 41.1% and 46.9% available P, 18.7%, 30.1% and 44.7% ammonification rate, 3.6%, 12.7% and 38.8% net N-mineralization rate, and 31.5%, 41.8% and 63.0% P mineralization rate in rhizosphere soils; however, among the 4 treatments, rhizosphere soil nitrification rate was not significantly different, the rhizosphere soil urease and acid phosphatase activities generally increased with the increasing intensity of acid rain (P<0.05). In bulk soil, compared with the control, the treatments of pH 4.5, pH 3.5 and pH 2.5 did not cause significant changes in NO3(-)-N, mineral N, available P as well as in the rates of nitrification, ammonification, net N-mineralization and P mineralization. With increasing the acid intensity, the rhizosphere effects of NH4+-N, NO3(-)-N, mineral N, ammonification and net N-mineralization rates were altered from positive to negative effects, those of urease and acid phosphatease showed the opposite trends, those of available P and P mineralization were negative and that of nitrification was positive. In sum, prolonged elevated acid rain could reduce N and P transformation rates, decrease their availability, alter their rhizosphere effects, and have impact on nutrient cycling in tea plantation.

Impacts of simulated acid rain on recalcitrance of two different soils.

PubMed

Dai, Zhongmin; Liu, Xingmei; Wu, Jianjun; Xu, Jianming

2013-06-01

Laboratory experiments were conducted to estimate the impacts of simulated acid rain (SAR) on recalcitrance in a Plinthudult and a Paleudalfs soil in south China, which were a variable and a permanent charge soil, respectively. Simulated acid rains were prepared at pH 2.0, 3.5, 5.0, and 6.0, by additions of different volumes of H2SO4 plus HNO3 at a ratio of 6 to 1. The leaching period was designed to represent 5 years of local annual rainfall (1,200 mm) with a 33 % surface runoff loss. Both soils underwent both acidification stages of (1) cation exchange and (2) mineral weathering at SAR pH 2.0, whereas only cation exchange occurred above SAR pH 3.5, i.e., weathering did not commence. The cation exchange stage was more easily changed into that of mineral weathering in the Plinthudult than in the Paleudalfs soil, and there were some K(+) and Mg(2+) ions released on the stages of mineral weathering in the Paleudalfs soil. During the leaching, the release of exchangeable base cations followed the order Ca(2+) >K(+) >Mg(2+) >Na(+) for the Plinthudult and Ca(2+) >Mg(2+) >Na(+) >K(+) for the Paleudalfs soil. The SARs above pH 3.5 did not decrease soil pH or pH buffering capacity, while the SAR at pH 2.0 decreased soil pH and the buffering capacity significantly. We conclude that acid rain, which always has a pH from 3.5 to 5.6, only makes a small contribution to the acidification of agricultural soils of south China in the short term of 5 years. Also, Paleudalfs soils are more resistant to acid rain than Plinthudult soils. The different abilities to prevent leaching by acid rain depend upon the parent materials, types of clay minerals, and soil development degrees.

EFFECTS OF ACID RAIN ON APPLE TREE PRODUCTIVITY AND FRUIT QUALITY

EPA Science Inventory

Mature 'McIntosh', 'Empire', and 'Golden Delicious' apple trees (Malus domestica) were sprayed with simulated acid rain solutions in the pH range of 2.5 to 5.5 at full bloom in 1980 and 1981. In 1981, weekly sprays were applied at pH 2.75 and pH 3.25. Necrotic lesions developed o...

[Effects of simulated acid rain on respiration rate of cropland system with different soil pH].

PubMed

Zhu, Xue-zhu; Zhang, Gao-chuan; Li, Hui

2009-10-15

To evaluate the effects of acid rain on the respiration rate of cropland system, an outdoor pot experiment was conducted with paddy soils of pH 5.48 (S1), pH 6.70 (S1) and pH 8.18 (S3) during the 2005-2007 wheat-growing seasons. The cropland system was exposed to acid rain by spraying the wheat foliage and irrigating the soil with simulated rainwater of T1 (pH 6.0), T2 (pH 6.0, ionic concentration was twice as rainwater T1), and T3 (pH 4.4, ionic concentration was twice as rainwater T1), respectively. The static opaque chamber-gas chromatograph method was used to measure CO2 fluxes from cropland system. The results showed that acid rain affected the respiration rate of cropland system through crop plant, and the cropland system could adapt to acid rain. Acid rainwater significantly increased the average respiration rate in alkaline soil (S3) cropland system, while it had no significant effects on the average respiration rate in neutral soil (S2) and acidic soil (S1) cropland systems. During 2005-2006, after the alkaline soil cropland system was treated with rainwater T3, the average respiration rate was 23.6% and 27.6% higher than that of alkaline soil cropland system treated with rainwater T1 and T2, respectively. During March to April, the respiration rate was enhanced with the increase of rainwater ionic concentration, while it was dropped with the decrease of rainwater pH value in acidic soil cropland system. It was demonstrated that soil pH and crop plant played important roles on the respiration rate of cropland system.

Activity of earthworm in Latosol under simulated acid rain stress.

PubMed

Zhang, Jia-En; Yu, Jiayu; Ouyang, Ying

2015-01-01

Acid rain is still an issue of environmental concerns. This study investigated the impacts of simulated acid rain (SAR) upon earthworm activity from the Latosol (acidic red soil). Laboratory experiment was performed by leaching the soil columns grown with earthworms (Eisenia fetida) at the SAR pH levels ranged from 2.0 to 6.5 over a 34-day period. Results showed that earthworms tended to escape from the soil and eventually died for the SAR at pH = 2.0 as a result of acid toxicity. The catalase activity in the earthworms decreased with the SAR pH levels, whereas the superoxide dismutases activity in the earthworms showed a fluctuate pattern: decreasing from pH 6.5 to 5.0 and increasing from pH 5.0 to 4.0. Results implied that the growth of earthworms was retarded at the SAR pH ≤ 3.0.

Biochemical responses of the mycorrhizae in Pinus massoniana to combined effects of Al, Ca and low pH.

PubMed

Kong, F X; Liu, Y; Hu, W; Shen, P P; Zhou, C L; Wang, L S

2000-02-01

Biochemical responses of Pinus massoniana, with and without the inoculation mycorrhizal fungus Pisolithus tinctorius at the root, to artificial acid rain (pH 2.0) and various Ca/Al ratios were investigated. Some enzymes associated with the nutritive metabolism, such as acid phosphatase, alkaline phosphatase, nitrate reductase, mannitol dehydrogenase and trehalase, in the roots, stems and leaves of plant were obviously inhibited by the artificial acid rain and Al. After treatment with pH 2.0 + Ca/Al (0/1 or 1/10) artificial acid rain, the protein content in the organs was decreased. However, the activities of superoxide dismutase (SOD) and peroxidase (POD) and glutathione (GSH) concentrations were induced. It demonstrated that acid rain and Al could induce oxygen radicals in plant. Compared with the treatments with lower pH or Al, respectively, the combination of lower pH and Al concentration was more toxic to P. massoniana. Al toxicity could be ameliorated by the addition of Ca and the amelioration was the most when the ratio was 1/1 among the various Ca/Al ratio. Infection with mycorrhizal fungus P. tinctorius at the root of P. massoniana increased the ability of the plant to resist the toxicity of artificial acid rain and Al stress.

Selenium speciation in acidic environmental samples: application to acid rain-soil interaction at Mount Etna volcano.

PubMed

Floor, Geerke H; Iglesías, Mònica; Román-Ross, Gabriela; Corvini, Philippe F X; Lenz, Markus

2011-09-01

Speciation plays a crucial role in elemental mobility. However, trace level selenium (Se) speciation analyses in aqueous samples from acidic environments are hampered due to adsorption of the analytes (i.e. selenate, selenite) on precipitates. Such solid phases can form during pH adaptation up till now necessary for chromatographic separation. Thermodynamic calculations in this study predicted that a pH<4 is needed to prevent precipitation of Al and Fe phases. Therefore, a speciation method with a low pH eluent that matches the natural sample pH of acid rain-soil interaction samples from Etna volcano was developed. With a mobile phase containing 20mM ammonium citrate at pH 3, selenate and selenite could be separated in different acidic media (spiked water, rain, soil leachates) in <10 min with a LOQ of 0.2 μg L(-1) using (78)Se for detection. Applying this speciation analysis to study acid rain-soil interaction using synthetic rain based on H(2)SO(4) and soil samples collected at the flanks of Etna volcano demonstrated the dominance of selenate over selenite in leachates from samples collected close to the volcanic craters. This suggests that competitive behavior with sulfate present in acid rain might be a key factor in Se mobilization. The developed speciation method can significantly contribute to understand Se cycling in acidic, Al/Fe rich environments. Copyright © 2011 Elsevier Ltd. All rights reserved.

Occurrence of acid rain in Baton Rouge, Louisiana, Summer 1981. The role of the catalytic converter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robinson, J.W.; Ghane, H.

1982-01-01

Between June and October 1981, acid rain falling in Baton Rouge, LA was studied. The acidity of the rain ranged for pH 3.9 to pH 5.8. Preliminary data showed that rain associated with thermal cumulo nimbus tended to be more acidic, but rain associated with active cold fronts were less acid. This may relate to dispersion and dilution of the acid aerosols by the cold front. It is proposed that exhaust from automobiles fitted with catalytic converters is a substantial contributor to the acid rain problem, and that their net value to the abatement of pollution must be questioned, particularlymore » in regions of the country where smog is not a problem. (JMT)« less

Analysis of the combined effects of lanthanum and acid rain, and their mechanisms, on nitrate reductase transcription in plants.

PubMed

Xia, Binxin; Sun, Zhaoguo; Wang, Lihong; Zhou, Qing; Huang, Xiaohua

2017-04-01

Rare earth element (REE) pollution and acid rain are major global environmental concerns, and their spatial distributions overlap. Thus, both forms of pollution combine to act on plants. Nitrogen is important for plant growth, and nitrate reductase (NR) is a key plant enzyme that catalyzes nitrogen assimilation. Studying the combined effects of REEs and acid rain on plant nitrogen-based nutrients has important environmental significance. Here, soybean (Glycine max) plants, commonly used for toxicological studies, were exposed to lanthanum (La), a REE, and acid rain to study the NR activities and NR transcriptional levels in the roots. To explain how the pollution affected the NR transcriptional level, we simultaneously observed the contents of intracellular La and nutrient elements, protoplast morphology, membrane lipid peroxidation and intracellular pH. A combined treatment of 0.08mmol/L La and pH 4.5 acid rain increased the NR activity, decreased the NR transcriptional level, increased the intracellular nutrient elements' contents and caused deformations in membrane structures. Other combined treatments significantly decreased the aforementioned parameters and caused serious damage to the membrane structures. The variation in the amplitudes of combined treatments was greater than those of individual treatments. Compared with the control and individual treatments, combined treatments increased membrane permeability, the malondialdehyde content, and intracellular H + and La contents, and with an increasing La concentration or acid strength, the change in amplitude increased. Thus, the combined effects on NR gene transcription in soybean seedling roots were related to the intracellular nutrient elements' contents, protoplast morphology, membranous lipid peroxidation, intracellular pH and La content. Copyright © 2016 Elsevier Inc. All rights reserved.

Acid rain stimulation of Lake Michigan phytoplankton growth

USGS Publications Warehouse

Manny, Bruce A.; Fahnenstiel, G.L.; Gardner, W.S.

1987-01-01

Three laboratory experiments demonstrated that additions of rainwater to epilimnetic lake water collected in southeastern Lake Michigan stimulated chlorophyll a production more than did additions of reagent-grade water during incubations of 12 to 20 d. Chlorophyll a production did not begin until 3–5 d after the rain and lake water were mixed. The stimulation caused by additions of rain acidified to pH 3.0 was greater than that caused by additions of untreated rain (pH 4.0–4.5). Our results support the following hypotheses: (1) Acid rain stimulates the growth of phytoplankton in lake water; (2) phosphorus in rain appears to be the factor causing this stimulation. We conclude that acid rain may accelerate the growth of epilimnetic phytoplankton in Lake Michigan (and other similar lakes) during stratification when other sources of bioavailable phosphorus to the epilimnion are limited

Characterizing the release of different composition of dissolved organic matter in soil under acid rain leaching using three-dimensional excitation-emission matrix spectroscopy.

PubMed

Liu, Li; Song, Cunyi; Yan, Zengguang; Li, Fasheng

2009-09-01

Although excitation-emission matrix spectroscopy (EEMS) has been widely used to characterize dissolved organic matter (DOM), there has no report that EEMS has been used to study the effects of acid rain on DOM and its composition in soil. In this work, we employed three-dimensional EEMS to characterize the compositions of DOM leached by simulated acid rain from red soil. The red soil was subjected to leaching of simulated acid rain of different acidity, and the leached DOM presented five main peaks in its EEMS: peak-A, related to humic acid-like (HA-like) material, at Ex/Em of 310-330/395-420nm; peak-B, related to UV fulvic acid-like (FA-like) material, at Ex/Em of 230-280/400-435nm; peak-C and peak-D, both related to microbial byproduct-like material, at Ex/Em of 250-280/335-355nm and 260-280/290-320nm, respectively; and peak-E, related to simple aromatic proteins, at Ex/Em of 210-240/290-340nm. EEMS analysis results indicated that most DOM could be lost from red soil in the early phase of acid rain leaching. In addition to the effects of the pH of acid rain, the loss of DOM also depended on the properties of its compositions and the solubility of their complexes with aluminum. HA-like and microbial byproduct-like materials could be more easily released from red soil by acid rain at both higher pH (4.5 and 5.6) and lower pH (2.5 and 3) than that at middle pH (3.5). On the contrary, FA-like material lost in a similar manner under the action of different acid rains with pH ranging from 2.5 to 5.6.

Effects of acidic rain and ozone on nitrogen fixation and photosynthesis in the lichen lobaria pulmonaria (L. ) Hoffm

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sigal, L.L.; Johnston, J.W.

1986-01-01

The lichen Lobaria pulmonaria was subjected to ozone fumigations at 118, 235 and 353 mcg/cu m and simulated acidic rain at pH levels of 2.6, 4.2 and 5.6 for 5 days (M,W,F,M,W) during a 10-day period. Acidic rain at pH 2.6 caused significant reduction in nitrogen fixation and gross photosynthesis of 100 and 90%, respectively, and thallus bleaching was apparent. There were no significant differences between the pH 5.6 and 4.2 treatments in either gross photosynthesis or nitrogen fixation, and the color of the lichen thalli was unchanged. The effect of ozone on nitrogen fixation and photosynthesis over the rangemore » of concentrations used was not significant, but there was a trend toward reduced nitrogen fixation with increasing O/sub 3/ concentration. There were no significant ozone-acidic rain interactions. The threshold for response to rain acidity for L. pulmonaria lies between pH 2.6 and 4.2, and the acidity of wet deposition in parts of the United States may fall in the range.« less

[Characteristics and the impact factors of acid rain in Fuzhou and Xiamen 1992-2012].

PubMed

Zheng, Qiu-Ping; Wang, Hong; Chen, Bin-Bin; Sui, Ping; Lin, Wen

2014-10-01

Based on the observed acid rain data, synoptic situations and mass concentrations of atmospheric pollutants data from 1992 to 2012, the temporal variation characteristics and the impact factors of acid rain were analyzed in Fuzhou and Xiamen. The results showed that acid rain and non-acid rain accounted for 38.1% and 61.9% respectively in Fuzhou, 40.6% and 59.4% respectively in Xiamen. The annual average pH was 4.1-5.5 in Fuzhou. Acid rain pollution alleviated after 2007 in Fuzhou, and alleviated after 2006 in Xiamen. Acid rain was more serious in winter and spring than in summer and autumn. Precipitation intensity could affect the acidity of rain. Acid rain was observed more serious in southeast, southwest, west and northwest wind in Fuzhou, and more serious in northeast, southwest, west and northwest wind in Xiamen. Acid rain was most severe under the condition of transformed surface cold high, while most light under the conditions of typhoon (intertropical convergence zone) and outside of typhoon (intertropical convergence zone). There was a negative correlation between the mass concentrations of atmospheric pollutants, such as SO2, NO2, PM10, and the pH of rain in Fuzhou.

Effects of acid deposition on dissolution of carbonate stone during summer storms in the Adirondack Mountains, New York, 1987-89

USGS Publications Warehouse

Schuster, Paul F.; Reddy, Michael M.; Sherwood, S.I.

1994-01-01

This study is part of a long-term research program designed to identify and quantify acid rain damage to carbonate stone. Acidic deposition accelerates the dissolution of carbonate-stone monuments and building materials. Sequential sampling of runoff from carbonate-stone (marble) and glass (reference) microcatchments in the Adirondack Mountains in New York State provided a detailed record of the episodic fluctuations in rain rate and runoff chemistry during individual summer storms. Rain rate and chemical concentrations from carbonate-stone and glass runoff fluctuated three to tenfold during storms. Net calcium-ion concentrations from the carbonatestone runoff, a measure of stone dissolution, typically fluctuated twofold during these storms. High net sulfate and net calcium concentrations in the first effective runoff at the start of a storm indicated that atmospheric pollutants deposited on the stone surface during dry periods formed calcium sulfate minerals, an important process in carbonate stone dissolution. Dissolution of the carbonate stone generally increased up to twofold during coincident episodes of low rain rate (less than 5 millimeters per hour) and decreased rainfall (glass runoff) pH (less than 4.0); episodes of high rain rate (cloudbursts) were coincident with a rapid increase in rainfall pH and also a rapid decrease in the dissolution of carbonate-stone. During a storm, it seems the most important factors causing increased dissolution of carbonate stone are coincident periods of low rain rate and decreased rainfall pH. Dissolution of the carbonate stone decreased slightly as the rain rate exceeded about 5 millimeters per hour, probably in response to rapidly increasing rainfall pH during episodes of high rain rate and shorter contact time between the runoff and the stone surface. High runoff rates resulting from cloudbursts remove calcium sulfate minerals formed during dry periods prior to storms and also remove dissolution products formed in large measure by chemical weathering as a result of episodes of low rain rate and decreased rainfall pH during a storm.

Acid Rain Phenomenon in Niger Delta Region of Nigeria: Economic, Biodiversity, and Public Health Concern

PubMed Central

Nduka, J. K. C.; Orisakwe, O. E.; Ezenweke, L. O.; Ezenwa, T. E.; Chendo, M. N.; Ezeabasili, N. G.

2008-01-01

Rain samples were collected from Warri and Port Harcourt, two major oil-producing cities of Nigeria in April-June, July-August, and September-October 2005 and 2006. Awka, a “non-oil” city was used as control. Samples were collected from three points, using clean plastic basins fastened to a table, 2 m above ground level and 115 m away from tall buildings and trees. Water samples were filtered and acidity determined using digital pHmeter. The results show that the rain samples were acidic. The pH values for the 2 years under study show that the rainfall in Warri was more acidic than that of Port Harcourt. Oil exploration and other anthropogenic sources may be responsible for the acid rain in the Niger Delta region of Nigeria. PMID:18758657

Combined effects of lanthanum (III) chloride and acid rain on photosynthetic parameters in rice.

PubMed

Wang, Lihong; Wang, Wen; Zhou, Qing; Huang, Xiaohua

2014-10-01

Rare earth elements (REEs) pollution and acid rain are environmental issues, and their deleterious effects on plants attract worldwide attention. These two issues exist simultaneously in many regions, especially in some rice-growing areas. However, little is known about the combined effects of REEs and acid rain on plants. Here, the combined effects of lanthanum chloride (LaCl3), one type of REE salt, and acid rain on photosynthesis in rice were investigated. We showed that the combined treatment of 81.6 μM LaCl3 and acid rain at pH 4.5 increased net photosynthetic rate (Pn), stomatic conductance (Gs), intercellular CO2 concentration (Ci), Hill reaction activity (HRA), apparent quantum yield (AQY) and carboxylation efficiency (CE) in rice. The combined treatment of 81.6 μM LaCl3 and acid rain at pH 3.5 began to behave toxic effects on photosynthesis (decreasing Pn, Gs, HRA, AQY and CE, and increasing Ci), and the maximally toxic effects were observed in the combined treatment of 2449.0 μM LaCl3 and acid rain at pH 2.5. Moreover, the combined effects of LaCl3 and acid rain on photosynthesis in rice depended on the growth stage of rice, with the maximal effects occurring at the booting stage. Furthermore, the combined treatment of high-concentration LaCl3 and low-pH acid rain had more serious effects on photosynthesis in rice than LaCl3 or acid rain treatment alone. Finally, the combined effect of LaCl3 and acid rain on Pn in rice resulted from the changes in stomatic (Gs, Ci) and non-stomatic (HRA, AQY and CE) factors. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effects of simulated acid rain on the morphology, phenology and dry biomass of a local variety of maize (Suwan-1) in Southwestern Nigeria.

PubMed

Macaulay, Babajide Milton; Enahoro, Gloria Ebarunosen

2015-10-01

Effects of acid rain on the morphology, phenology and dry biomass of maize (Suwan-1 variety) were investigated. The maize seedlings were subjected to different pH treatments (1.0, 2.0, 3.0, 4.0, 5.0 and 6.0) of simulated acid rain (SAR) with pH 7.0 as the control for a period of 90 days. The common morphological defects due to SAR application were necrosis and chlorosis. It was observed that necrosis increased in severity as the acidity increased whilst chlorosis was dominant as the acidity decreased. SAR encouraged rapid floral and cob growth but with the consequence of poor floral and cob development in pH 1.0 to 3.0 treatments. The result for the dry biomass indicates that pH treatments 2.0 to 7.0 for total plant biomass were not significantly different (P > 0.05) from one another, but were all significantly higher (P < 0.05) than pH 1.0. Therefore, it may be deduced that Suwan-1 has the potential to withstand acid rain but with pronounced morphological and phenological defects which, however, have the capacity to reduce drastically the market value of the crop. Therefore, it may be concluded that Suwan-1 tolerated acid rain in terms of the parameters studied at pH 4.0 to 7.0 which makes it a suitable crop in acid rain-stricken climes. This research could also serve as a good reference for further SAR studies on maize or other important cereals.

Comparative effects of sulfuric and nitric acid rain on litter decomposition and soil microbial community in subtropical plantation of Yangtze River Delta region.

PubMed

Liu, Xin; Zhang, Bo; Zhao, Wenrui; Wang, Ling; Xie, Dejin; Huo, Wentong; Wu, Yanwen; Zhang, Jinchi

2017-12-01

Acid rain is mainly caused by dissolution of sulfur dioxide and nitrogen oxides in the atmosphere, and has a significant negative effect on ecosystems. The relative composition of acid rain is changing gradually from sulfuric acid rain (SAR) to nitric acid rain (NAR) with the rapidly growing amount of nitrogen deposition. In this study, we investigated the impact of simulated SAR and NAR on litter decomposition and the soil microbial community over four seasons since March 2015. Results first showed that the effects of acid rain on litter decomposition and soil microbial were positive in the early period of the experiment, except for SAR on soil microbes. Second, soil pH with NAR decreased more rapidly with the amount of acid rain increased in summer than with SAR treatments. Only strongly acid rain (both SAR and NAR) was capable of depressing litter decomposition and its inhibitory effect was stronger on leaf than on fine root litter. Meanwhile, NAR had a higher inhibitory effect on litter decomposition than SAR. Third, in summer, autumn and winter, PLFAs were negatively impacted by the increased acidity level resulting from both SAR and NAR. However, higher acidity level of NAR (pH=2.5) had the strongest inhibitory impact on soil microbial activity, especially in summer. In addition, Gram-negative bacteria (cy19:0) and fungi (18:1ω9) were more sensitive to both SAR and NAR, and actinomycetes was more sensitive to SAR intensity. Finally, soil total carbon, total nitrogen and pH were the most important soil property factors affecting soil microbial activity, and high microbial indices (fungi/bacteria) with high soil pH. Our results suggest that the ratio of SO 4 2- to NO 3 - in acid rain is an important factor which could affect litter decomposition and soil microbial in subtropical forest of China. Copyright © 2017. Published by Elsevier B.V.

[Relationship between atmospheric particles and rain water chemistry character].

PubMed

Huo, Ming-Qun; Sun, Qian; Xie, Peng; Bai, Yu-Hua; Liu, Zhao-Rong; Li, Ji-Long; Lu, Si-Hua

2009-11-01

Rain and atmospheric particle samples were collected in the rural area of Taian and Shenzhen in 2007, respectively. Rain sampling was carried out during the precipitation process and several samples were got from the beginning of one precipitation to the end. The chemical character changes during precipitation and the changes of concentration of particles before and after rain were studied in this research to understand the contribution of particles on the rain chemical character and the rain-out effect for particles. The volume-weighted mean pH of rainwater in Taian was 5.97 and the total concentration of ions was 1 187.96 microeq x L(-1). The mass concentration of PM10 in Taian was 131.76 microg/m3 and that of PM2.5 was 103.84 microg/m3. The volume-weighted mean pH of rainwater in Shenzhen was 4.72 and the total concentration of ions was 175.89 microeq x L(-1). The mass concentration of PM10 in Shenzhen was 56.66 microg/m3 and that of PM2.5 was 41.52 microg/m3. During precipitation process pH and ion concentration of rain decrease and it is shown the neutralizing effect happens. The difference between rainwater of Taian and Shenzhen is due to cloud water acidity, atmospheric particles character and atmospheric acid-basic gases concentration. The clean-up effect of Na+ and Ca2+ by rain is high and which of NH4+ and NO3- is low. The clean-up effect for mass concentration, ions concentration and element concentration of particles by rain are significant.

Antioxidant response of soybean seedlings to joint stress of lanthanum and acid rain.

PubMed

Liang, Chanjuan; Wang, Weimin

2013-11-01

Excess of rare earth elements in soil can be a serious environmental stress on plants, in particular when acid rain coexists. To understand how such a stress affects plants, we studied antioxidant response of soybean leaves and roots exposed to lanthanum (0.06, 0.18, and 0.85 mmol L(-1)) under acid rain conditions (pH 4.5 and 3.0). We found that low concentration of La3+ (0.06 mmol L(-1)) did not affect the activity of antioxidant enzymes (catalase and peroxidase) whereas high concentration of La3+ (≥0.18 mmol L(-1)) did. Compared to treatment with acid rain (pH 4.5 and pH 3.0) or La3+ alone, joint stress of La3+ and acid rain affected more severely the activity of catalase and peroxidase, and induced more H2O2 accumulation and lipid peroxidation. When treated with high level of La3+ (0.85 mmol L(-1)) alone or with acid rain (pH 4.5 and 3.0), roots were more affected than leaves regarding the inhibition of antioxidant enzymes, physiological function, and growth. The severity of oxidative damage and inhibition of growth caused by the joint stress associated positively with La3+ concentration and soil acidity. These results will help us understand plant response to joint stress, recognize the adverse environmental impact of rare earth elements in acidic soil, and develop measures to eliminate damage caused by such joint stress.

The Acid Rain Reader.

ERIC Educational Resources Information Center

Stubbs, Harriett S.; And Others

A topic which is often not sufficiently dealt with in elementary school textbooks is acid rain. This student text is designed to supplement classroom materials on the topic. Discussed are: (1) "Rain"; (2) "Water Cycle"; (3) "Fossil Fuels"; (4) "Air Pollution"; (5) "Superstacks"; (6) "Acid/Neutral/Bases"; (7) "pH Scale"; (8) "Acid Rain"; (9)…

Effects and mechanism of acid rain on plant chloroplast ATP synthase.

PubMed

Sun, Jingwen; Hu, Huiqing; Li, Yueli; Wang, Lihong; Zhou, Qing; Huang, Xiaohua

2016-09-01

Acid rain can directly or indirectly affect plant physiological functions, especially photosynthesis. The enzyme ATP synthase is the key in photosynthetic energy conversion, and thus, it affects plant photosynthesis. To clarify the mechanism by which acid rain affects photosynthesis, we studied the effects of acid rain on plant growth, photosynthesis, chloroplast ATP synthase activity and gene expression, chloroplast ultrastructure, intracellular H(+) level, and water content of rice seedlings. Acid rain at pH 4.5 remained the chloroplast structure unchanged but increased the expression of six chloroplast ATP synthase subunits, promoted chloroplast ATP synthase activity, and increased photosynthesis and plant growth. Acid rain at pH 4.0 or less decreased leaf water content, destroyed chloroplast structure, inhibited the expression of six chloroplast ATP synthase subunits, decreased chloroplast ATP synthase activity, and reduced photosynthesis and plant growth. In conclusion, acid rain affected the chloroplast ultrastructure, chloroplast ATPase transcription and activity, and P n by changing the acidity in the cells, and thus influencing the plant growth and development. Finally, the effects of simulated acid rain on the test indices were found to be dose-dependent.

[Spatiotemporal trends and the impact factors of acid rain in Anhui Province].

PubMed

Shi, Chun-E; Qiu, Ming-Yan; Zhang, Ai-Min; Zhang, Hao; Zhang, Su; Wang, Zi-Fa

2010-06-01

The observational data of acid rain at seven stations in Anhui province operated by China Meteorological Administration (CMA), as well as the coal consumptions in Anhui and some surrounding provinces along with satellite measured tropospheric NO2 columns, were used to analyze the spatiotemporal trends of acid rain in Anhui and the potential reasons of the increasing occurrence frequency of acid rain. In addition, the technique of back-trajectory-cluster analysis was used to examine the impacts of transport patterns on the precipitation acidity in Anhui. The occurrence frequency shows the lowest in summer and the highest in autumn, with 3-year average pH < 5.6 during 2006-2008 at all stations, hereinto, pH values are between 5.0 and 4.5 in Hefei, Anqing, Maanshan and Bengbu. In spatial, acid rain were the most severe in southern to middle Anhui and mitigated to north. The distributions of pH were concentrative at Fuyang, Tongling and Huangshan, with more than 75% occurred between 6.00-7.50 (Fuyang), 5.00-6.00 (Tongling) and 5.00-6.50 (Huangshan); quite dispersive at other stations, with the maximum at 4.00-4.50 (Hefei and Anqing), 5.00-5.50 (Maanshan) and 5.50-6.00 (Bengbu). The occurrence frequencies of acid rain increased evidently at all stations comparing with those in the end of 1990s. The results of back-trajectories-cluster analysis show that the acid rain is closely related with the regional-range transport of acid rain precursors at each station. The air-masses from southeast and northeast, especially those passing through Jiangsu and Zhejiang, associated with the highest frequencies of acid rain with pH < 5.0, indicating that the industrial emissions in the economy developed areas of Yangtze Delta play key roles in acid rain in Anhui province. In addition, statistics shows that the occurrence frequency of acid rain in Hefei was highly correlated with the trends of the provincial coal consumptions in Anhui, Jiangsu and Zhejiang, also tropospheric NO2 column content over Anhui province and surrounding areas with all correlation coefficients > 0.7, suggesting the close relationship between the quick increasing acid rain in Hefei and the regional pollutant emissions.

[THE EFFECT OF ACID RAIN ON ULTRASTRUCTURE AND FUNCTIONAL PARAMETERS OF PHOTOSYNTHETIC APPARATUS OF PEA LEAVES].

PubMed

Polishchuk, A V; Vodka, M V; Belyavskaya, N A; Khomochkin, A P; Zolotareva, E K

2016-01-01

The effects of simulated acid rain (SAR) on the ultrastructure and functional parameters of the photosynthetic apparatus were studied using 14-day-old pea leaves as test system. Pea plants were sprayed with an aqueous solution containing NaNO₃(0.2 mM) and Na₂SO₄(0.2 mM) (pH 5.6, a control variant), or with the same solution, which was acidified to pH 2.5 (acid variant). Functional characteristics were determined by chlorophyll fluorescence analysis. Acid rain application caused reduction in the efficiency of the photosynthetic electron transport by 25%, which was accompanied by an increase by 85% in the quantum yield of thermal dissipation of excess light quanta. Ultrastructural changes in chloroplast were registered by transmission electron microscopy (TEM) after two days of the SAR-treatment of pea leaves. In this case, the changes in the structure of grana, heterogeneity of thylakoids packaging in granum, namely, the increase of intra-thylakoid gaps and thickness of granal thylakoids compared to the control were found. The migration of protein complexes in thylakoid membranes of chloroplasts isolated from leaves treated with SAR was suppressed. It was shown also that carbonic anhydrase activity was inhibited in chloroplast preparations isolated from SAR-treated pea leaves. We proposed a hypothesis on the possible inactivation of thylakoid carbonic anhydrase under SAR and its involvement in the inhibition of photochemical activity of chloroplasts. The data obtained allows to suggest that acid rains negatively affect the photosynthetic apparatus disrupting the membrane system of chloroplast.

[Combined effects of copper and simulated acid rain on copper accumulation, growth, and antioxidant enzyme activities of Rumex acetosa].

PubMed

He, Shan-Ying; Gao, Yong-Jie; Shentu, Jia-Li; Chen, Kun-Bai

2011-02-01

A pot experiment was conducted to study the combined effects of Cu (0-1500 mg x kg(-1)) and simulated acid rain (pH 2.5-5.6) on the copper accumulation, growth, and antioxidant enzyme activities of Rumex acetosa. With the increasing concentration of soil Cu, the Cu accumulation in R. acetosa increased, being higher in root than in stem and leaf. The exposure to low pH acid rain promoted the Cu uptake by R. acetosa. With the increase of soil Cu concentration and/or of acid rain acidity, the biomass of R. acetosa decreased, leaf and root MDA contents increased and had good correlation with soil Cu concentration, and the SOD and POD activities in leaf and root displayed a decreasing trend after an initial increase. This study showed that R. acetosa had a strong adaptive ability to Cu and acid rain stress, exhibiting a high application potential in the remediation of Cu-contaminated soil in acid rain areas.

CR@BaSO4: an acid rain-indicating material.

PubMed

Gao, Hong-Wen; Xu, Xin-Hui

2011-12-28

The CR@BaSO(4) hybrid was synthesized, characterized and used as an acid rain-indicating (ARI) material. A painted ARI umbrella was discolored after exposure to simulated acid rain of pH 5 or less and returned to the initial color after the rain stopped. Such a functionalized material may make acid rain visual to remind people in real-time. This journal is © The Royal Society of Chemistry 2011

Pyrite oxidation under simulated acid rain weathering conditions.

PubMed

Zheng, Kai; Li, Heping; Wang, Luying; Wen, Xiaoying; Liu, Qingyou

2017-09-01

We investigated the electrochemical corrosion behavior of pyrite in simulated acid rain with different acidities and at different temperatures. The cyclic voltammetry, polarization curve, and electrochemical impedance spectroscopy results showed that pyrite has the same electrochemical interaction mechanism under different simulated acid rain conditions, regardless of acidity or environmental temperature. Either stronger acid rain acidity or higher environmental temperature can accelerate pyrite corrosion. Compared with acid rain having a pH of 5.6 at 25 °C, the prompt efficiency of pyrite weathering reached 104.29% as the acid rain pH decreased to 3.6, and it reached 125.31% as environmental temperature increased to 45 °C. Increasing acidity dramatically decreases the charge transfer resistance, and increasing temperature dramatically decreases the passivation film resistance, when other conditions are held constant. Acid rain always causes lower acidity mine drainage, and stronger acidity or high environmental temperatures cause serious acid drainage. The natural parameters of latitude, elevation, and season have considerable influence on pyrite weathering, because temperature is an important influencing factor. These experimental results are of direct significance for the assessment and management of sulfide mineral acid drainage in regions receiving acid rain.

Effects of intermittent acid rain on proline and antioxidant content on medicinal plant “Pereskia bleo”

NASA Astrophysics Data System (ADS)

Sulandjari; Dewi, W. S.

2018-03-01

Global warming due to CO2 and other greenhouse gas emissions from human activities have led to climate change and environmental degradation. The acid rain, with the pH of rainwater below 5.6, is a serious environmental problem. Arising from air pollution and potentially harmful to health, it can damage old buildings and distract the growth and physiological metabolism of sensitive plants. How does the influence of climate change on medicinal plants such as Pereskia bleo? The leaf of Pereskia bleo (Kunth) DC. contains high antioxidants with benefits for anti-cancer, anti-tumor, anti-rheumatic, and anti-inflammatory. This research aims to investigate the influence of acid rain on the proline level and antioxidant content of Pereskia bleo. Having been carried out from June to August in Jogjakarta, this study was conducted through the use of artificial acid rain with pH 5.8, 4.9, 3.7 and 2.9, by adding sulfate acid (H2SO4) to rainwater. The interval of intermittent watering acid rain to the plants is once a day, twice a day, and once in three days with three replications for six weeks. The results showed that Acid rain with a pH less than 4.9 and the intermittent interval of acid rain twice a day and once in three days significantly suppresses growth and chlorophyll content. In contrast, it increases the proline and antioxidant levels as a tolerant action of the plant.

Acid Rain: An Educational Opportunity?

ERIC Educational Resources Information Center

Marion, James I.

1984-01-01

Deals with how educators can handle the subject of acid rain; illustrates suggestions with experiences of grade nine students visiting Frost Valley Environmental Education Center (Oliverea, New York) to learn scientific concepts through observation of outdoor phenomena, including a stream; and discusses acid rain, pH levels, and pollution control…

Efficient inhibition of heavy metal release from mine tailings against acid rain exposure by triethylenetetramine intercalated montmorillonite (TETA-Mt).

PubMed

Gong, Beini; Wu, Pingxiao; Huang, Zhujian; Li, Yuanyuan; Yang, Shanshan; Dang, Zhi; Ruan, Bo; Kang, Chunxi

2016-11-15

The potential application of triethylenetetramine intercalated montmorillonite (TETA-Mt) in mine tailings treatment and AMD (acid mine drainage) remediation was investigated with batch experiments. The structural and morphological characteristics of TETA-Mt were analyzed with XRD, FTIR, DTG-TG and SEM. The inhibition efficiencies of TETA-Mt against heavy metal release from mine tailings when exposed to acid rain leaching was examined and compared with that of triethylenetetramine (TETA) and Mt. Results showed that the overall inhibition by TETA-Mt surpassed that by TETA or Mt for various heavy metal ions over an acid rain pH range of 3-5.6 and a temperature range of 25-40°C. When mine tailings were exposed to acid rain of pH 4.8 (the average rain pH of the mining site where the mine tailings were from), TETA-Mt achieved an inhibition efficiency of over 90% for Cu(2+), Zn(2+), Cd(2+) and Mn(2+) release, and 70% for Pb(2+) at 25°C. It was shown that TETA-Mt has a strong buffering capacity. Moreover, TETA-Mt was able to adsorb heavy metal ions and the adsorption process was fast, suggesting that coordination was mainly responsible. These results showed the potential of TETA-Mt in AMD mitigation, especially in acid rain affected mining area. Copyright © 2016 Elsevier B.V. All rights reserved.

Effects of simulated acid rain on soil and soil solution chemistry in a monsoon evergreen broad-leaved forest in southern China.

PubMed

Qiu, Qingyan; Wu, Jianping; Liang, Guohua; Liu, Juxiu; Chu, Guowei; Zhou, Guoyi; Zhang, Deqiang

2015-05-01

Acid rain is an environmental problem of increasing concern in China. In this study, a laboratory leaching column experiment with acid forest soil was set up to investigate the responses of soil and soil solution chemistry to simulated acid rain (SAR). Five pH levels of SAR were set: 2.5, 3.0, 3.5, 4.0, and 4.5 (as a control, CK). The results showed that soil acidification would occur when the pH of SAR was ≤3.5. The concentrations of NO₃(-)and Ca(2+) in the soil increased significantly when the pH of SAR fell 3.5. The concentration of SO₄(2-) in the soil increased significantly when the pH of SAR was <4.0. The effects of SAR on soil solution chemistry became increasingly apparent as the experiment proceeded (except for Na(+) and dissolved organic carbon (DOC)). The net exports of NO₃(-), SO₄(2-), Mg(2+), and Ca(2+) increased about 42-86% under pH 2.5 treatment as compared to CK. The Ca(2+) was sensitive to SAR, and the soil could release Ca(2+) through mineral weathering to mitigate soil acidification. The concentration of exchangeable Al(3+) in the soil increased with increasing the acidity of SAR. The releases of soluble Al and Fe were SAR pH dependent, and their net exports under pH 2.5 treatment were 19.6 and 5.5 times, respectively, higher than that under CK. The net export of DOC was reduced by 12-29% under SAR treatments as compared to CK. Our results indicate the chemical constituents in the soil are more sensitive to SAR than those in the soil solution, and the effects of SAR on soil solution chemistry depend not only on the intensity of SAR but also on the duration of SAR addition. The soil and soil solution chemistry in this region may not be affected by current precipitation (pH≈4.5) in short term, but the soil and soil leachate chemistry may change dramatically if the pH of precipitation were below 3.5 and 3.0, respectively.

Direct effect of acid rain on leaf chlorophyll content of terrestrial plants in China.

PubMed

Du, Enzai; Dong, Dan; Zeng, Xuetong; Sun, Zhengzhong; Jiang, Xiaofei; de Vries, Wim

2017-12-15

Anthropogenic emissions of acid precursors in China have resulted in widespread acid rain since the 1980s. Although efforts have been made to assess the indirect, soil mediated ecological effects of acid rain, a systematic assessment of the direct foliage injury by acid rain across terrestrial plants is lacking. Leaf chlorophyll content is an important indicator of direct foliage damage and strongly related to plant productivity. We synthesized data from published literature on experiments of simulated acid rain, by directly exposing plants to acid solutions with varying pH levels, to assess the direct effect of acid rain on leaf chlorophyll content across 67 terrestrial plants in China. Our results indicate that acid rain substantially reduces leaf chlorophyll content by 6.71% per pH unit across the recorded plant species. The direct reduction of leaf chlorophyll content due to acid rain exposure showed no significant difference across calcicole, ubiquist or calcifuge species, implying that soil acidity preference does not influence the sensitivity to leaf injury by acid rain. On average, the direct effects of acid rain on leaf chlorophyll on trees, shrubs and herbs were comparable. The effects, however varied across functional groups and economic use types. Specifically, leaf chlorophyll content of deciduous species was more sensitive to acid rain in comparison to evergreen species. Moreover, vegetables and fruit trees were more sensitive to acid rain than other economically used plants. Our findings imply a potential production reduction and economic loss due to the direct foliage damage by acid rain. Copyright © 2017 Elsevier B.V. All rights reserved.

Evidence for multiple hydrogen-ion donor systems in rain

Treesearch

Sagar V. Krupa; M. R., Jr. Coscio; F. A. Wood

1976-01-01

An integrated analytical system consisting of combined scanning electron microscopy and x-ray analysis, atomic absorption, colorimetry and coulometry was used to study rain water chemistry. The coulometry facilitated the determination in molarities of strong and non-volatile and volatile weak acids. The pH of individual rains in St. Paul - Minneapolis, Minnesota ranged...

The effect of simulated acid rain on the stabilization of cadmium in contaminated agricultural soils treated with stabilizing agents.

PubMed

Zhu, Hao; Wu, Chunfa; Wang, Jun; Zhang, Xumei

2018-04-16

Stabilization technology is one of widely used remediation technologies for cadmium (Cd)-contaminated agricultural soils, but stabilized Cd in soil may be activated again when external conditions such as acid rain occurred. Therefore, it is necessary to study the effect of acid rain on the performance of different stabilizing agents on Cd-polluted agriculture soils. In this study, Cd-contaminated soils were treated with mono-calcium phosphate (MCP), mono-ammonium phosphate (MAP), and artificial zeolite (AZ) respectively and incubated 3 months. These treatments were followed by two types of simulated acid rain (sulfuric acid rain and mixed acid rain) with three levels of acidity (pH = 3.0, 4.0, and 5.6). The chemical forms of Cd in the soils were determined by Tessier's sequential extraction procedure, and the leaching toxicities of Cd in the soils were assessed by toxicity characteristic leaching procedure (TCLP). The results show that the three stabilizing agents could decrease the mobility of Cd in soil to some degree with or without simulated acid rain (SAR) treatment. The stabilization performances followed the order of AZ < MAP < MCP. Acid rain soaking promoted the activation of Cd in stabilized soil, and both anion composition and pH of acid rain were two important factors that influenced the stabilization effect of Cd.

Theory and practice in the electrometric determination of pH in precipitation

NASA Astrophysics Data System (ADS)

Brennan, Carla Jo; Peden, Mark E.

Basic theory and laboratory investigations have been applied to the electrometric determination of pH in precipitation samples in an effort to improve the reliability of the results obtained from these low ionic strength samples. The theoretical problems inherent in the measurement of pH in rain have been examined using natural precipitation samples with varying ionic strengths and pH values. The importance of electrode design and construction has been stressed. The proper choice of electrode can minimize or eliminate problems arising from residual liquid junction potentials, streaming potentials and temperature differences. Reliable pH measurements can be made in precipitation samples using commercially available calibration buffers providing low ionic strength quality control solutions are routinely used to verify electrode and meter performance.

Effect of acid rain pH on leaching behavior of cement stabilized lead-contaminated soil.

PubMed

Du, Yan-Jun; Wei, Ming-Li; Reddy, Krishna R; Liu, Zhao-Peng; Jin, Fei

2014-04-30

Cement stabilization is a practical approach to remediate soils contaminated with high levels of lead. However, the potential for leaching of lead out of these stabilized soils under variable acid rain pH conditions is a major environmental concern. This study investigates the effects of acid rain on the leaching characteristics of cement stabilized lead contaminated soil under different pH conditions. Clean kaolin clay and the same soil spiked with 2% lead contamination are stabilized with cement contents of 12 and 18% and then cured for 28 days. The soil samples are then subjected to a series of accelerated leaching tests (or semi-dynamic leaching tests) using a simulated acid rain leachant prepared at pH 2.0, 4.0 or 7.0. The results show that the strongly acidic leachant (pH ∼2.0) significantly altered the leaching behavior of lead as well as calcium present in the soil. However, the differences in the leaching behavior of the soil when the leachant was mildly acidic (pH ∼4.0) and neutral (pH ∼7.0) prove to be minor. In addition, it is observed that the lead contamination and cement content levels can have a considerable impact on the leaching behavior of the soils. Overall, the leachability of lead and calcium is attributed to the stability of the hydration products and their consequent influence on the soil buffering capacity and structure. Copyright © 2014 Elsevier B.V. All rights reserved.

Acid Rain. LC Science Tracer Bullet.

ERIC Educational Resources Information Center

Hollmann, Pauline, Comp.

The term "acid rain," also called "acid precipitation," generally refers to any precipitation having a pH value of less than 5.6. This guide to the literature on acid rain in the collections of the Library of Congress is not necessarily intended to be a comprehensive bibliography. It is designed to provide the reader with a set…

Acid rain attack on outdoor sculpture in perspective

NASA Astrophysics Data System (ADS)

Livingston, Richard A.

2016-12-01

A major concern motivating research in acid rain materials effects has been the potential for damage to cultural heritage, particularly outdoor marble and bronze sculpture. However, a combination of field and laboratory studies has failed to show a correlation between rain pH and loss of materials. In order to understand this counterintuitive lack of acid rain effect, an aqueous geochemical modeling approach was used to analyze rain runoff chemistry for the relative importance of acid rain neutralization, dry deposition, and in the case of marble, natural carbonate dissolution. This approach involved the development of pH - SO42- phase diagrams for marble (calcium carbonate) and bronze (copper) under ambient environmental conditions. This then enabled reaction path modeling of the acid neutralization process using the pH range typically found in wet deposition (3.5-6). The results were for marble that the theoretical maximum amount of Ca2+ ion that could be lost due acid rain neutralization would be 0.158 mmol/l compared to 10.5 mmol/l by dry deposition, and for bronze, the Cu2+ ion losses would be 0.21 mmol/l and 47.3 mmol/l respectively. Consequently dry deposition effects on these materials have the potential to dominate over wet deposition effects. To test these predictions the geochemical models were applied to examples of data sets from mass balance (runoff vs rainfall) studies on a marble statue in New York City and some bronze memorial plaques at Gettysburg PA. Although these data sets were collected in the early 1980s they remain valid for demonstrating the mass balance method. For the marble statue, the mean Ca2+ losses by dry deposition was about 69% of the total compared 0.3% for acid rain neutralization, which was less than the natural carbonate dissolution losses of 0.8%. For the bronze, the mean Cu2+ losses were 70.6% by SO42- dry deposition and 23% by NO3- dry deposition compared to 6.4% by acid rain neutralization. Thus for both cases the wet deposition component was less than the variability of the dry deposition components, which explains the observed lack of correlation between the rain pH and the material losses. In addition, for the marble case, there was evidence for HCl acid vapor attack resulting from nitric acid/sea salt interactions and for bronze, ammonium ion may be important. In both cases, significant imbalances suggested that unmeasured organic acids may have a significant effect.

Effects of simulated acid rain and ozone on foliar chemistry of field-grown Pinus ponderosa seedlings and mature trees.

PubMed

Momen, B; Helms, J A

1996-01-01

We investigated the additive and interactive effects of simulated acid rain and elevated ozone on C and N contents, and the C:N ratio of one-year-old and current-year foliage of field-grown mature trees and their half-sib seedlings of a stress tolerant genotype of ponderosa pine. Acid rain levels (pH 5.1 and 3.0) were applied weekly to foliage only (no soil acidification or N addition), from January to April, 1992. Plants were exposed to two ozone levels (ambient and twice-ambient) during the day from September 1991 to November 1992. The sequential application of acid rain and elevated ozone mimicked the natural conditions. Twice-ambient ozone significantly decreased foliar N content (by 12-14%) and increased the C:N ratio of both one-year-old and current-year foliage of seedlings. Although similar ozone effects were also observed on one-year-old foliage of mature trees, the only statistically significant effect was an increased C:N ratio when twice-ambient ozone combined with pH 3.0 rain (acid rain by ozone interaction). Enhancing the effect of twice-ambient ozone in increasing the C:N ratio of one-year-old foliage of mature trees in June was the only significant effect of acid rain.

Activity of earthworm in Latosol under simulated acid rain stress

Treesearch

Jia-En Zhang; Jiayu Yu; Ying Ouyang

2015-01-01

Acid rain is still an issue of environmental concerns. This study investigated the impacts of simulated acid rain (SAR) upon earthworm activity from the Latosol (acidic red soil). Laboratory experiment was performed by leaching the soil columns grown with earthworms (Eisenia fetida) at the SAR pH levels ranged from 2.0 to 6.5 over a 34-day period....

Effects of lanthanum and acid rain stress on the bio-sequestration of lanthanum in phytoliths in germinated rice seeds

PubMed Central

Si, Yong; Wang, Lihong; Huang, Xiaohua

2018-01-01

REEs in the environment can be absorbed by plants and sequestered by plant phytoliths. Acid rain can directly or indirectly affect plant physiological functions. Currently, the effects of REEs and acid rain on phytolith-REEs complex in plants are not yet fully understood. In this study, a high-silicon accumulation crop, rice (Oryza sativa L.), was selected as a representative of plants, and orthogonal experiments were conducted under various levels of lanthanum [La(III)] and pH. The results showed that various La(III) concentrations could significantly improve the efficiency and sequestration of phytolith La(III) in germinated rice seeds. A pH of 4.5 promoted phytolith La(III) sequestration, while a pH of 3.5 inhibited sequestration. Compared with the single treatment with La(III), the combination of La(III) and acid rain inhibited the efficiency and sequestration of phytolith La(III). Correlation analysis showed that the efficiency of phytolith La(III) sequestration had no correlation with the production of phytolith but was closely correlated with the sequestration of phytolith La(III) and the physiological changes of germinated rice seeds. Phytolith morphology was an important factor affecting phytolith La(III) sequestration in germinated rice seeds, and the effect of tubes on sequestration was more significant than that of dumbbells. This study demonstrated that the formation of the phytolith and La(III) complex could be affected by exogenous La(III) and acid rain in germinated rice seeds. PMID:29763463

Spread of acid rain over India

NASA Astrophysics Data System (ADS)

Khemani, L. T.; Momin, G. A.; Rao, P. S. Prakasa; Safai, P. D.; Singh, G.; Kapoor, R. K.

Rain water and aerosol samples were collected at a few locations representative of urban and non-urban regions in India. Also, rain water samples were collected in and around a coal-fired power plant. All the rain water and aerosol samples were analyzed for major chemical components along with pH. The rain water at all the places of measurement, except near the industrial sources, has been found to be alkaline and was characterized by the presence of excess cations, particularly by Ca 2+. The acid rain near the industrial sources was associated with excess anions, especially SO 42-. The atmospheric aerosols at all the places of measurement were found rich with basic components, suggesting that the alkaline soil dust and fly ash are responsible at present for preventing the spread of acid rain in India.

Impact of simulated acid rain on trace metals and aluminum leaching in latosol from Guangdong Province, China

Treesearch

Jia-En Zhang; Jiayu Yu; Ying Ouyang; Huaqin Xu

2014-01-01

Acid rain is one of the most serious ecological and environmental problems worldwide. This study investigated the impacts of simulated acid rain (SAR) upon leaching of trace metals and aluminum (Al) from a soil. Soil pot leaching experiments were performed to investigate the impacts of SAR at five different pH levels (or treatments) over a 34-day period upon the...

Continued studies of acid rain and its effects on the Baton Rouge area

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robinson, J.W.; Ghane, H.

1983-01-01

The acidity of rain water was measured in the Baton Rouge, Louisiana area from June 1981 to September 1982. Coordinated measurements were taken of the dissolved oxygen concentration in two local lakes before and after each rainfall. About 50% of the rainfall observed was quite acidic, with about 25% of the rain having a pH of 4 or less. Rain was more acidic during warm summers than in the winter weather. Rainfall during 1982 was, on a month to month comparison, more acidic than in 1981. Attempts were also made to discover any possible correlation of pH values with windmore » direction. The acidity of each of the two lakes increased over the time of the study. The dissolved oxygen content in each lake increased after periods of rain, probably due to a high concentration of oxygen in the rainwater. The buffering capacities of the lakes was measurable. However, it is noted that the larger lake was undergoing dredging at the time of the study and showed considerably less buffer capacity than the smaller lake. The smaller lake was far more affected by surface drainage and thus should have been more influenced by the acid rain. 7 references, 7 figures, 1 table.« less

Chemical characterization of fog and rain water collected at the eastern Andes cordillera

NASA Astrophysics Data System (ADS)

Beiderwieden, E.; Wrzesinsky, T.; Klemm, O.

2005-09-01

During a three month period in 2003 and 2004, the chemistry of fog and rainwater were studied at the "El Tiro" site in a tropical mountain forest ecosystem in Ecuador, South America. The fogwater samples were collected using a passive fog collector, and for the rain water, a standard rain sampler was employed. For all samples, electric conductivity, pH, and the concentrations of NH4+, K+, Na+, Ca2+, Mg2+, Cl-, NO3-, PO43-, and SO42- were measured. For each fog sample, a 5 day back trajectory was calculated by the use of the HYSPLIT model. Two types of trajectories occurred. One type was characterized by advection of air masses from the East over the Amazonian basin, the other trajectory arrived one from the West after significant travel time over the Pacific Ocean. We found considerably higher ion concentrations in fogwater samples than in rain samples. Median pH values are 4.58 for fog water, and 5.26 for the rain samples, respectively. The median electric conductivity was 23 μS cm-1 for the fog and 6 μS cm-1 for the rain. The continent samples exhibit higher concentrations of most ions as compared to the pacific samples, but these differences could not be detected statistically.

EFFECTS OF ACID RAIN ON GRAPEVINES

EPA Science Inventory

Mature vineyard-growing Concord grapevines were sprayed with simulated acid rain solutions ranging from pH 2.5 to 5.5 both as acute treatments at anthesis and chronically throughout the season in 1980 and 1981. In 1981, 8 additional varieties were also treated with simulated acid...

Vermicompost and biochar as bio-conditioners to immobilize heavy metal and improve soil fertility on cadmium contaminated soil under acid rain stress.

PubMed

Wang, Ying; Xu, YongAn; Li, Dan; Tang, BiCong; Man, ShuLei; Jia, YiFan; Xu, Heng

2018-04-15

This experiment was conducted to investigate the remediation effects of bio-conditioners vermicompost (VC) and biochar (BC) on cadmium contaminated soil under the threat of acid rain, individually and associatively. With the application of soil conditioners, the percentages of HOAc-extractable Cd decreased 5.2-6.8%, 9.0-13.5% and 7.9-12.1% in the groups amended with VC, BC and VC combined BC, respectively. When the pH of rain decreased from 7.0 to 4.0, the activity of acid phosphatase decreased 2.0%, 12.3%, 3.2%, 14.8% in VC, BC, VC combined BC and control groups, individually. This study affirmed that with the application of soil conditioners, the threat of heavy metal along with bioavailability of Cd was depressed, and the properties of soil biochemical indictors were enhanced. Oppositely, the bioavailability of Cd was promoted, and soil microbial viability as well as nutrient contents was inhibited with the spraying of acid rain. The findings indicated that acid deposition played a restrain effect on soil remediation process. Meanwhile, soil conditioners showed potentials to improve soil fertilities and alleviate the stress of acid rain. Copyright © 2017. Published by Elsevier B.V.

Influence of acid rain upon water plumbosolvency.

PubMed Central

Moore, M R

1985-01-01

The West of Scotland has had particular problems in the past associated with soft acidic water supplies and uptake of lead from domestic plumbing systems by such water. As a consequence of this, health problems related to overexposure to lead have been identified. The current debate on acidification of ground waters by acid rain is therefore particularly pertinent to this area. Studies have shown that even a modest decrease in pH will result in very substantial increase in plumbosolvency. This was found to be of particular importance in the city of Glasgow and town of Ayr, where prior to water treatment, pH values were 6.3 and 5.4, respectively, and where, consequentially, large numbers of homes did not comply with lead in water standards. Closed-loop lime-dosing systems were introduced in both Glasgow and Ayr to increase the pH with immediate decrease in the lead content of the water and, subsequently, blood lead concentrations of the subjects living in these areas. Such closed-loop systems will compensate for any acidity in water supplies, whether of natural origin or originating from acid rain precipitation. However, when such treatment has not been applied, any increase in water acidity due to acid rain which is, in many cases, already unacceptable. which is, in many cases, already unacceptable. PMID:4076078

Effect of simulated acid rain on nitrate and ammonium production in soils from three ecosystems of Camels Hump Mountain, Vermont

DOE Office of Scientific and Technical Information (OSTI.GOV)

Like, D.E.; Klein, R.M.

1985-11-01

The authors removed intact soil columns from the Harwood (550 to 790 m), Transition (790 to 1050 m), and Conifer (1050 to 1160 m) ecological zones of Camels Hump Mountain, Vermont, treated them with simulated acid rain (pH 4.0) or nonacidic (pH 5.6) rain, and examined the percolates for ammonium and nitrate ions. Nitrification in soils from all three ecosystems was unaffected by acidic treatments, but mineralization was stimulated by acidic treatment of soil from the Transition Zone. Irrespective of treatment, Conifer Zone soils released less nitrate than did either Transition or Hardwood Zone soils. Soil columns from the Hardwoodmore » Zone were treated with acidic or nonacidic simulated rainfall supplemented with nitrate, ammonium, or both N sources. NO3-N in percolates increased when acidic simulated rain was supplemented with ammonium ion or both ammonium and nitrate ions. Efflux of NH4-N was unaffected by supplementing precipitation with either ammonium or nitrate ions.« less

An evaluation of the effects of acid rain on low conductivity headwater streams in Pennsylvania

USGS Publications Warehouse

Ritter, John R.; Brown, Ann E.

1981-01-01

Analyses of water collected at 32 sites on headwater streams in Pennsylvania during low-flow conditions in 1970-80 were compared to pre-1971 data to evaluate whether acid rain had changed the chemistry of the streams in the previous decade. Most pH, alkalinity, and sulfate values of the samples collected in 1970-80 fell within the ranges of values for samples collected before 1971. The limited data indicate, however, that pH may have increased and alkalinity and sulfate may have decreased with time.

Urban dew and rain in Paris, France: Occurrence and physico-chemical characteristics

NASA Astrophysics Data System (ADS)

Beysens, D.; Mongruel, A.; Acker, K.

2017-06-01

This paper summarizes one year (April 2011 to March 2012) measurements on planar condensing surfaces of dew and rain events and related physico-chemical characteristics in the urban environment of Paris (city center). Yearly collected water was 3.48 mm for dew (63 events) and 593 mm for rain (146 events). The latter value compares well with rain data (547 mm and 107 events) collected within 12 km at Paris-Orly airport. An estimation of dew yield based on meteo data gives 2.35 mm and 74 events, to be compared with 17.11 mm and 196 events at Paris-Orly. These differences highlight the large reduction in dew events and dew yields in an urban area as compared to a close rural-like area. This reduction is not due to a sky view reduction but to heat island that increases air temperature and decreases relative humidity. Analysis of dew (34) and rain (77) samples were done concerning pH, electrical conductivity (EC), major anions and cations as well as selected trace metals and other minor ions. Mean pH values are found similar for both, dew (6.5) and rain (6.1), rain being slightly more acidic than dew. The mean dew total ionic content (TIC 1.8 meq/l) and EC value (124 μS/cm) are about four times that of rain (0.45 meq/l; 35 μS/cm), meaning that total dissolved solids in dew is nearly four times that in rain. Sulfate and nitrate are the most acidifying components, calcium the most neutralizing constituent with ratio of mean total acidity/total alkalinity comparable for dew and rain ( 0.9). Sulfate and nitrate have mainly anthropogenic sources, whereas chloride and magnesium are mostly connected with marine air masses. Dew is a considerable factor of wet deposition of pollutants; dew and rain ion concentrations, however, meet the WHO requirements for drinking water.

Effects of silicon on Oryza sativa L. seedling roots under simulated acid rain stress.

PubMed

Ju, Shuming; Yin, Ningning; Wang, Liping; Zhang, Cuiying; Wang, Yukun

2017-01-01

Silicon (Si) has an important function in reducing the damage of environmental stress on plants. Acid rain is a serious abiotic stress factor, and Si can alleviate the stress induced by acid rain on plants. Based on these assumptions, we investigated the effects of silicon on the growth, root phenotype, mineral element contents, hydrogen peroxide (H2O2) and antioxidative enzymes of rice (Oryza sativa L.) seedling roots under simulated acid rain (SAR) stress. The results showed that the combined or single effects of Si and/or SAR on rice roots depend on the concentration of Si and the pH of the SAR. The combined or single effects of a low or moderate concentration of Si (1.0 or 2.0 mM) and light SAR (pH 4.0) enhanced the growth of rice roots, and the combined effects were stronger than those of the single treatment. A high concentration of Si (4.0 mM) or severe SAR (pH 2.0) exerted deleterious effects. The incorporation of Si (1.0, 2.0 or 4.0 mM) into SAR with pH 3.0 or 2.0 promoted the rice root growth, decreased the H2O2 content, increased the Si concentration and the superoxide dismutase (SOD), catalase (CAT), peroxidase (POD) and ascorbate peroxidase (APX) activities, maintained the balance of mineral element (K, Ca, Mg, Fe, Zn, and Cu) concentrations in the roots of rice seedlings compared with SAR alone. The alleviatory effects observed with a moderate concentration of Si (2.0 mM) were better than the effects obtained with a low or high concentration of Si (1.0 or 4.0 mM). The observed effects were due to disruptions in the absorption and utilization of mineral nutrients and impacts on the activity of antioxidant enzymes in roots, and this conclusion suggests that the degree of rice root damage caused by acid rain might be attributed to not only acid rain but also the level of Si in the soil.

Effects of silicon on Oryza sativa L. seedling roots under simulated acid rain stress

PubMed Central

Wang, Liping; Zhang, Cuiying; Wang, Yukun

2017-01-01

Silicon (Si) has an important function in reducing the damage of environmental stress on plants. Acid rain is a serious abiotic stress factor, and Si can alleviate the stress induced by acid rain on plants. Based on these assumptions, we investigated the effects of silicon on the growth, root phenotype, mineral element contents, hydrogen peroxide (H2O2) and antioxidative enzymes of rice (Oryza sativa L.) seedling roots under simulated acid rain (SAR) stress. The results showed that the combined or single effects of Si and/or SAR on rice roots depend on the concentration of Si and the pH of the SAR. The combined or single effects of a low or moderate concentration of Si (1.0 or 2.0 mM) and light SAR (pH 4.0) enhanced the growth of rice roots, and the combined effects were stronger than those of the single treatment. A high concentration of Si (4.0 mM) or severe SAR (pH 2.0) exerted deleterious effects. The incorporation of Si (1.0, 2.0 or 4.0 mM) into SAR with pH 3.0 or 2.0 promoted the rice root growth, decreased the H2O2 content, increased the Si concentration and the superoxide dismutase (SOD), catalase (CAT), peroxidase (POD) and ascorbate peroxidase (APX) activities, maintained the balance of mineral element (K, Ca, Mg, Fe, Zn, and Cu) concentrations in the roots of rice seedlings compared with SAR alone. The alleviatory effects observed with a moderate concentration of Si (2.0 mM) were better than the effects obtained with a low or high concentration of Si (1.0 or 4.0 mM). The observed effects were due to disruptions in the absorption and utilization of mineral nutrients and impacts on the activity of antioxidant enzymes in roots, and this conclusion suggests that the degree of rice root damage caused by acid rain might be attributed to not only acid rain but also the level of Si in the soil. PMID:28291806

Acid Rain Analysis by Standard Addition Titration.

ERIC Educational Resources Information Center

Ophardt, Charles E.

1985-01-01

The standard addition titration is a precise and rapid method for the determination of the acidity in rain or snow samples. The method requires use of a standard buret, a pH meter, and Gran's plot to determine the equivalence point. Experimental procedures used and typical results obtained are presented. (JN)

Acid Precipitation Awareness Curriculum Materials in the Life Sciences.

ERIC Educational Resources Information Center

Stubbs, Harriett S.

1983-01-01

Provides an outline of course content for acid precipitation and two acid rain activities (introduction to pH and effects of acid rain on an organism). Information for obtaining 20 additional activities as well as an information packet containing booklets, pamphlets, and articles are also provided. (JN)

Modeling estimates of the effect of acid rain on background radiation dose.

PubMed Central

Sheppard, S C; Sheppard, M I

1988-01-01

Acid rain causes accelerated mobilization of many materials in soils. Natural and anthropogenic radionuclides, especially 226Ra and 137Cs, are among these materials. Okamoto is apparently the only researcher to date who has attempted to quantify the effect of acid rain on the "background" radiation dose to man. He estimated an increase in dose by a factor of 1.3 following a decrease in soil pH of 1 unit. We reviewed literature that described the effects of changes in pH on mobility and plant uptake of Ra and Cs. Generally, a decrease in soil pH by 1 unit will increase mobility and plant uptake by factors of 2 to 7. Thus, Okamoto's dose estimate may be too low. We applied several simulation models to confirm Okamoto's ideas, with most emphasis on an atmospherically driven soil model that predicts water and nuclide flow through a soil profile. We modeled a typical, acid-rain sensitive soil using meteorological data from Geraldton, Ontario. The results, within the range of effects on the soil expected from acidification, showed essentially direct proportionality between the mobility of the nuclides and dose. This supports some of the assumptions invoked by Okamoto. We conclude that a decrease in pH of 1 unit may increase the mobility of Ra and Cs by a factor of 2 or more. Our models predict that this will lead to similar increases in plant uptake and radiological dose to man. Although health effects following such a small increase in dose have not been statistically demonstrated, any increase in dose is probably undesirable. PMID:3203639

Response of soil respiration to acid rain in forests of different maturity in southern China.

PubMed

Liang, Guohua; Liu, Xingzhao; Chen, Xiaomei; Qiu, Qingyan; Zhang, Deqiang; Chu, Guowei; Liu, Juxiu; Liu, Shizhong; Zhou, Guoyi

2013-01-01

The response of soil respiration to acid rain in forests, especially in forests of different maturity, is poorly understood in southern China despite the fact that acid rain has become a serious environmental threat in this region in recent years. Here, we investigated this issue in three subtropical forests of different maturity [i.e. a young pine forest (PF), a transitional mixed conifer and broadleaf forest (MF) and an old-growth broadleaved forest (BF)] in southern China. Soil respiration was measured over two years under four simulated acid rain (SAR) treatments (CK, the local lake water, pH 4.5; T1, water pH 4.0; T2, water pH 3.5; and T3, water pH 3.0). Results indicated that SAR did not significantly affect soil respiration in the PF, whereas it significantly reduced soil respiration in the MF and the BF. The depressed effects on both forests occurred mostly in the warm-wet seasons and were correlated with a decrease in soil microbial activity and in fine root biomass caused by soil acidification under SAR. The sensitivity of the response of soil respiration to SAR showed an increasing trend with the progressive maturity of the three forests, which may result from their differences in acid buffering ability in soil and in litter layer. These results indicated that the depressed effect of acid rain on soil respiration in southern China may be more pronounced in the future in light of the projected change in forest maturity. However, due to the nature of this field study with chronosequence design and the related pseudoreplication for forest types, this inference should be read with caution. Further studies are needed to draw rigorous conclusions regarding the response differences among forests of different maturity using replicated forest types.

Response of Soil Respiration to Acid Rain in Forests of Different Maturity in Southern China

PubMed Central

Chen, Xiaomei; Qiu, Qingyan; Zhang, Deqiang; Chu, Guowei; Liu, Juxiu; Liu, Shizhong; Zhou, Guoyi

2013-01-01

The response of soil respiration to acid rain in forests, especially in forests of different maturity, is poorly understood in southern China despite the fact that acid rain has become a serious environmental threat in this region in recent years. Here, we investigated this issue in three subtropical forests of different maturity [i.e. a young pine forest (PF), a transitional mixed conifer and broadleaf forest (MF) and an old-growth broadleaved forest (BF)] in southern China. Soil respiration was measured over two years under four simulated acid rain (SAR) treatments (CK, the local lake water, pH 4.5; T1, water pH 4.0; T2, water pH 3.5; and T3, water pH 3.0). Results indicated that SAR did not significantly affect soil respiration in the PF, whereas it significantly reduced soil respiration in the MF and the BF. The depressed effects on both forests occurred mostly in the warm-wet seasons and were correlated with a decrease in soil microbial activity and in fine root biomass caused by soil acidification under SAR. The sensitivity of the response of soil respiration to SAR showed an increasing trend with the progressive maturity of the three forests, which may result from their differences in acid buffering ability in soil and in litter layer. These results indicated that the depressed effect of acid rain on soil respiration in southern China may be more pronounced in the future in light of the projected change in forest maturity. However, due to the nature of this field study with chronosequence design and the related pseudoreplication for forest types, this inference should be read with caution. Further studies are needed to draw rigorous conclusions regarding the response differences among forests of different maturity using replicated forest types. PMID:23626790

Effects of rare earth and acid rain pollution on plant chloroplast ATP synthase and element contents at different growth stages.

PubMed

Zhang, Fan; Hu, Huiqing; Wang, Lihong; Zhou, Qing; Huang, Xiaohua

2018-03-01

Combined rare earth and acid rain pollution has become a new environmental problem, seriously affecting plant survival. The effects of these two kinds of pollutants on plant photosynthesis have been reported, but the micro mechanisms are not very clear. In this research, we studied the effects of lanthanum [La(III), 0.08, 1.20 and 2.40 mM] and acid rain (pH value = 2.5, 3.5 and 4.5) on the ATPase activity and gene transcription level and the functional element contents in rice leaf chloroplasts. The results showed that the combined 0.08 mM La(III) and pH 4.5 acid rain increased the ATPase activity and gene transcription level as well as contents of some functional elements. But other combined treatments of acid rain and La(III) reduced the ATPase activity and gene transcription level as well as functional element contents. The change magnitude of the above indexes at rice booting stage was greater than that in seedling stage or grain filling stage. These results reveal that effects of La(III) and acid rain on ATPase activity and functional element contents in rice leaf chloroplasts are related to the combination of La(III) dose and acid rain intensity and the plant growth stage. In addition, the changes in the ATPase activity were related to ATPase gene transcription level. This study would provide a reference for understanding the microcosmic mechanism of rare earth and acid rain pollution on plant photosynthesis and contribute to evaluate the possible environmental risks associated with combined La(III) and acid rain pollution. The effects of La(III) and acid rain on activity and gene transcription level of rice chloroplast ATPase and contents of functional elements were different at different growth stages. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effect of simulated acid rain on the litter decomposition of Quercus acutissima and Pinus massoniana in forest soil microcosms and the relationship with soil enzyme activities.

PubMed

Wang, Congyan; Guo, Peng; Han, Guomin; Feng, Xiaoguang; Zhang, Peng; Tian, Xingjun

2010-06-01

With the continuing increase in human activities, ecologists are increasingly interested in understanding the effects of acid rain on litter decomposition. Two dominant litters were chosen from Zijin Mountain in China: Quercus acutissima from a broad-leaved forest and Pinus massoniana from a coniferous forest. The litters were incubated in microcosms and treated with simulated acid rain (gradient pH levels). During a six-month incubation, changes in chemical composition (i.e., lignin, total carbohydrate, and nitrogen), litter mass losses, soil pH values, and activities of degradative enzymes were determined. Results showed that litter mass losses were depressed after exposure to acid rain and the effects of acid rain on the litter decomposition rates of needles were higher than on those of leaves. Results also revealed that simulated acid rain restrained the activities of cellulase, invertase, nitrate reductase, acid phosphatase, alkaline phosphatase, polyphenol oxidase, and urease, while it enhanced the activities of catalase in most cases during the six-month decomposition process. Catalase and polyphenol oxidase were primarily responsible for litter decomposition in the broad-leaved forest, while invertase, nitrate reductase, and urease were primarily responsible for litter decomposition in the coniferous forest. The results suggest acid rain-restrained litter decomposition may be due to the depressed enzymatic activities. According to the results of this study, soil carbon in subtropical forests would accumulate as a long-term consequence of continued acid rain. This may presumably alter the balance of ecosystem carbon flux, nutrient cycling, and humus formation, which may, in turn, have multiple effects on forest ecosystems. Copyright (c) 2010 Elsevier B.V. All rights reserved.

Acid Rain

USGS Publications Warehouse

Bricker, Owen P.; Rice, Karen C.

1995-01-01

Although acid rain is fading as a political issue in the United States and funds for research in this area have largely disappeared, the acidity of rain in the Eastern United States has not changed significantly over the last decade, and it continues to be a serious environmental problem. Acid deposition (commonly called acid rain) is a term applied to all forms of atmospheric deposition of acidic substances - rain, snow, fog, acidic dry particulates, aerosols, and acid-forming gases. Water in the atmosphere reacts with certain atmospheric gases to become acidic. For example, water reacts with carbon dioxide in the atmosphere to produce a solution with a pH of about 5.6. Gases that produce acids in the presence of water in the atmosphere include carbon dioxide (which converts to carbonic acid), oxides of sulfur and nitrogen (which convert to sulfuric and nitric acids}, and hydrogen chloride (which converts to hydrochloric acid). These acid-producing gases are released to the atmosphere through natural processes, such as volcanic emissions, lightning, forest fires, and decay of organic matter. Accordingly, precipitation is slightly acidic, with a pH of 5.0 to 5.7 even in undeveloped areas. In industrialized areas, most of the acid-producing gases are released to the atmosphere from burning fossil fuels. Major emitters of acid-producing gases include power plants, industrial operations, and motor vehicles. Acid-producing gases can be transported through the atmosphere for hundreds of miles before being converted to acids and deposited as acid rain. Because acids tend to build up in the atmosphere between storms, the most acidic rain falls at the beginning of a storm, and as the rain continues, the acids "wash out" of the atmosphere.

[Combined injured effects of acid rain and lanthanum on growth of soybean seedling].

PubMed

Liang, Chan-juan; Pan, Dan-yun; Xu, Qiu-rong; Zhou, Qing

2010-07-01

Combined effects of acid rain and lanthanum on growth of soybean seedling (Glycine max) and its inherent mechanism were studied in this paper. Compared with treatments by simulated acid rain (pH 3.0, 3.5, 4.5) or rare earth La(III) (60, 100 and 300 mg x L(-1)), the decrease degree of growth parameters in combined treatments was higher, indicating that there were a synergistic effects between acid rain and La. Moreover,the inhibition effects of acid rain and La(III) were more obvious when pH value of acid rain was lower or the concentration of La(III) was higher. The changes of photosynthetic parameters were similar to those of growth, but the decrease degree of each parameter was not same in the same treatment group. The decrease degree of optimal PSII photochemical efficiency (Fv/Fm) and chlorophyll content (Chl) were 9.35%-22.75% and 9.14%-24.53%, respectively, lower than that of photosynthetic rate Pn (22.78%-84.7%), Hill reaction rate (15.52%-73.38%) and Mg2+ -ATPase activity (14.51%-71.54%), showing that the sensitivity of photosynthetic parameters to the combined factors was different. Furthermore, relative analysis showed that the change of Pn were mainly affected by Hill reaction rate and Mg2+ -ATPase activity, and was less influenced by Chl and Fv/Fm. It indicates that the effect of acid rain and La on each reaction in photosynthesis was different, and the inhibition of combined treatments on photosynthesis in plants was one of the main factors affecting growth of plant.

A numerical study of the acid rain in northern Taiwan in winter season

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Ching-Sen; Deng, Zen-Sing

1996-12-31

Two-thirds of the land mass of Taiwan island is covered by mountains. In winter precipitation could occur in northern Taiwan when the prevailing wind was from northeastern direction. In northern Taiwan the acid rain (pH value less than 5.0) in winter time could contribute about 30 rain in the whole year. A three-dimensional numerical model with terrain following coordinated system was used to simulate the precipitation system and the characteristics of acid rain. A smooth terrain was assumed in the model. A mean sounding was used to initialize the numerical model when acid rain occurred in northern Taiwan during wintermore » time from 1991 to 1993. Investigations of the effect of pollutions from abroad on the acid rain in northern Taiwan in winter are considered for the future.« less

Chemical characterization of fog and rain water collected at the eastern Andes cordillera

NASA Astrophysics Data System (ADS)

Beiderwieden, E.; Wrzesinsky, T.; Klemm, O.

2005-06-01

During a three month period in 2003 and 2004, the chemistry of fog and rainwater were studied at the "El Tiro" site in a tropical mountain forest ecosystem in Ecuador, South America. The fogwater samples were collected using a passive fog collector, and for the rain water, a standard rain sampler was employed. For all samples, electric conductivity, pH, and the concentrations of NH4+, K+, Na+, Ca2+, Mg2+, Cl-, NO3-, PO43-, and SO42-, were measured. For each fog sample, a 5 day back trajectory was calculated by the use of the HYSPLIT model. Two types of trajectories occurred. One type was characterized by advection of air masses from the East over the Amazonian basin, the other trajectory arrived one from the West after significant travel time over the Pacific Ocean. We found considerably higher ion concentrations in fogwater samples than in rain samples. Median pH values are 4.58 for fog water, and 5.26 for the rain samples, respectively. The median electric conductivity was 23 µS cm-1 for the fog and 6 µS cm-1 for the rain. The concentrations of all analysed ions were relatively low compared to other mountainous sites (Weathers et al., 1988; Elias et al., 1995; Schemenauer et al., 1995; Wrzesinsky and Klemm, 2000; Zimmermann and Zimmermann, 2002). The continent samples exhibit higher concentrations of most ions as compared to the pacific samples.

Temporal and spatial variability of rainfall pH

Treesearch

Richard G. Semonin

1977-01-01

The distribution of average rainwater pH over an area of 1,800 km² containing 81 collectors was determined from 25 storm events. The areal average of the data was pH 4.9, with a range of values from 4.3 to 6.8. A single storm event was studied to determine the change of pH as a function of time. The initial rain was pH 7.1, decreasing to 4.1. An excellent...

Experimental investigation of influence of acid rain on leaching and hydraulic characteristics of cement-based solidified/stabilized lead contaminated clay.

PubMed

Du, Yan-Jun; Jiang, Ning-Jun; Shen, Shui-Long; Jin, Fei

2012-07-30

Remediation of contaminated lands in China urban areas is of great concern. Degradation of construction facilities caused by acid rain is a serious environmental pollution issue in China. This paper presents an investigation of the effects of acid rain on leaching and hydraulic properties of cement-based solidified/stabilized lead contaminated soil. Laboratory tests including infiltration test and soaking test are conducted. It is found that the soil hydraulic conductivity decreases with increase in the pore volume of flow of permeant liquids (acid rain and distilled water). The decreasing rate in the case of the acid rain is lower than that in the case of the distilled water. The soaking test results show that pH and the presence of sulfate ions of acid rain have considerable influence on the leached concentrations and leaching rate of calcium. Copyright © 2012 Elsevier B.V. All rights reserved.

Developmental and anatomical changes in leaves of yellow birch and red kidney bean exposed to simulated acid precipitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paparozzi, E.T.; Tukey, H.B. Jr.

Leaves of Betula alleghaniensis Britt. (yellow birch) and Phaseolus vulgaris L cv. Red Kidney (bean) were examined microscopically during development and after exposure to simulated rain of pH 5.5, 4.3, 3.2, and 2.8. Yellow birch leaves attained maximal leaf area, midvein length, and cuticle thickness at 21 days. Trichomes were either long, unicellular, or multicellular with caplike head and stalk. Epicuticular wax was a bumpy and amorphous layer. The 2nd trifoliolate leaf of red kidney bean attained maximal leaf area, midvein length, and cuticle thickness when the 3rd trifoliolate leaf was expanding. Trichomes present were long, with a unicellular headmore » and a multicellular base; long, unicellular, and terminally hooked; and small and multicellular. Epicuticular wax was present as small irregular flakes. After 2 days of pH 2.8 and 4 days of pH 3.2 simulated acid rain, round yellow and small tan lesions appeared on birch and bean leaves, respectively. Most injury occurred on or between small veins. Most trichome types were uninjured. Lesions formed as a result of collapsed epidermal and highly plasmolyzed palisade cells. The cuticle was still present over injured epidermal cells and epicuticular waxes were unchanged. There was not statistical difference in mean cuticle thickness due to pH of simulated rain. 25 references, 10 figures, 4 tables.« less

Effects of surface-active organic matter on carbon dioxide nucleation in atmospheric wet aerosols: a molecular dynamics study.

PubMed

Daskalakis, Vangelis; Charalambous, Fevronia; Panagiotou, Fostira; Nearchou, Irene

2014-11-21

Organic matter (OM) uptake in cloud droplets produces water-soluble secondary organic aerosols (SOA) via aqueous chemistry. These play a significant role in aerosol properties. We report the effects of OM uptake in wet aerosols, in terms of the dissolved-to-gas carbon dioxide nucleation using molecular dynamics (MD) simulations. Carbon dioxide has been implicated in the natural rainwater as well as seawater acidity. Variability of the cloud and raindrop pH is assumed in space and time, as regional emissions, local human activities and geophysical characteristics differ. Rain scavenging of inorganic SOx, NOx and NH3 plays a major role in rain acidity in terms of acid-base activity, however carbon dioxide solubility also remains a key parameter. Based on the MD simulations we propose that the presence of surface-active OM promotes the dissolved-to-gas carbon dioxide nucleation in wet aerosols, even at low temperatures, strongly decreasing carbon dioxide solubility. A discussion is made on the role of OM in controlling the pH of a cloud or raindrop, as a consequence, without involving OM ionization equilibrium. The results are compared with experimental and computational studies in the literature.

Impacts of acid precipitation on coniferous forest ecosystems

Treesearch

Gunnar Abrahamsen; Richard Horntvedt; Bjorn Tveite

1976-01-01

This paper summarizes the results from current studies in Norway. One main approach is the application of artificial acid "rain" and of lime to field plots and lysimeters. Application during two growth seasons of 50 mm per month of "rain water" of pH 3 to a podzol soil increased the acidity of the humus and decreased the base saturation. The...

Chemical characterization of rain water in a seasonally dry tropical region (Varanasi), India.

PubMed

Pandey, Jitendra; Singh, Ashima

2012-05-01

Rain water samples, covering 44 rain events of 2008 and 52 rain events of 2009, were collected at urban and suburban locations of Varanasi and analyzed for pH, conductivity and for metal and nutrient ions. The pH of rainwater varied between 6.3 and 7.9, with over 70% of samples having alkaline range. Volume weighed mean concentration of ions indicated Ca2+ (11.62- 41.60 microeq l(-1)) to be the most dominant species followed by SO4(2-) (4.7-25.2 microeq I(-1)), Na+ (1.60-10.25 microeq l(-1)), Mg2+ (0.22-7.21 microeq I(-1)), (NO3(-) (0.73-4.02 microeq l(-1)), K+(0.50-3.70 microeq l(-1)) and PO4(3-) (0.02-0.97 microeq l(-1)) respectively. Among the heavy metals, Cr (12.60 to 44.60 microg l(-1)), Zn (4.25 to 34.55 microg l(-1)) and Mn (10.62 to 28.40 microg l(-1)) were found to be the dominant component of rain water. The varimax rotation of PCA results extracted four major factors namely urban-industrial emission, crustal aerosols, wind transport and biomass burning accounting for 80% of the total variance. The study has relevance in establishing cause-effect relationships for terrestrial as well as for aquatic ecosystems.

[Analysis of acid rain characteristics of Lin'an Regional Background Station using long-term observation data].

PubMed

Li, Zheng-Quan; Ma, Hao; Mao, Yu-Ding; Feng, Tao

2014-02-01

Using long-term observation data of acid rain at Lin'an Regional Background Station (Lin'an RBS), this paper studied the interannual and monthly variations of acid rain, the reasons for the variations, and the relationships between acid rain and meteorological factors. The results showed that interannual variation of acid rain at Lin'an RBS had a general increasing trend in which there were two obvious intensifying processes and two distinct weakening processes, during the period ranging from 1985 to 2012. In last two decades, the monthly variation of acid rain at Lin'an RBS indicated that rain acidity and frequency of severe acid rain were increasing but the frequency of weak acid rain was decreasing when moving towards bilateral side months of July. Acid rain occurrence was affected by rainfall intensity, wind speed and wind direction. High frequency of severe acid rain and low frequency of weak acid rain were on days with drizzle, but high frequency of weak acid rain and low frequency of severe acid rain occurred on rainstorm days. With wind speed upgrading, the frequency of acid rain and the proportion of severe acid rain were declining, the pH value of precipitation was reducing too. Another character is that daily dominant wind direction of weak acid rain majorly converged in S-W section ,however that of severe acid rain was more likely distributed in N-E section. The monthly variation of acid rain at Lin'an RBS was mainly attributed to precipitation variation, the increasing and decreasing of monthly incoming wind from SSE-WSW and NWN-ENE sections of wind direction. The interannual variation of acid rain could be due to the effects of energy consumption raising and significant green policies conducted in Zhejiang, Jiangsu and Shanghai.

System Chemistry to Control Potential Environmental and Safety Hazards of Recycled Concrete Aggregate With Lead-Based Paint

DTIC Science & Technology

2010-01-01

will usually buffer the TCLP test so it would not be classified as a hazardous waste. Acidification of soil does change the chemistry and mobility...crushed concrete product from around the stockpile at Fort Jackson (Figure 8). Each sample of a few kilograms was placed in a plastic “zip-lock...Jackson, rainfall quantity and pH for Columbia, SC first had to be determined. 5.2 Columbia rain data A review of data from National Oceanic and

Response of soybean seed germination to cadmium and acid rain.

PubMed

Liu, Ting Ting; Wu, Peng; Wang, Li Hong; Zhou, Qing

2011-12-01

Cadmium (Cd) pollution and acid rain are the main environmental issues, and they often occur in the same agricultural region. Nevertheless, up to now, little information on the combined pollution of Cd(2+) and acid rain action on crops were presented. Here, we investigated the combined effect of Cd(2+) and acid rain on the seed germination of soybean. The results indicated that the single treatment with the low level of Cd(2+) (0.18, 1.0, 3.0 mg L(-1)) or acid rain (pH ≥3.0) could not affect the seed germination of soybean, which was resulted in the increased activities of peroxidase and catalase. The single treatment with the high concentration of Cd(2+) (>6 mg L(-1)) or acid rain at pH 2.5 decreased the activities of peroxidase and catalase, damaged the cell membrane and then decreased the seed germination of soybean. Meanwhile, the same toxic effect was observed in the combined treatment with Cd(2+) and acid rain, and the combined treatment had more toxic effect than the single treatment with Cd(2+) or acid rain. Thus, the combined pollution of Cd(2+) and acid rain had more potential threat to the seed germination of soybean than the single pollution of Cd(2+) or acid rain.

Effects of acid rain and sulfur dioxide on marble dissolution

USGS Publications Warehouse

Schuster, Paul F.; Reddy, Michael M.; Sherwood, Susan I.

1994-01-01

Acid precipitation and the dry deposition of sulfur dioxide (SO2) accelerate damage to carbonate-stone monuments and building materials. This study identified and quantified environmental damage to a sample of Vermont marble during storms and their preceding dry periods. Results from field experiments indicated the deposition of SO2 gas to the stone surface during dry periods and a twofold increase in marble dissolution during coincident episodes of low rain rate and decreased rainfall pH. The study is widely applicable to the analysis of carbonate-stone damage at locations affected by acid rain and air pollution.

The erosion of carbonate stone by acid rain: Laboratory and field investigations

USGS Publications Warehouse

Baedecker, P.A.; Reddy, M.M.

1993-01-01

One of the goals of research on the effects of acidic deposition on carbonate stone surfaces is to define the incremental impact of acidic deposition relative to natural weathering processes on the rate of carbonate stone erosion. If rain that impacts carbonate stone surfaces is resident on the surface long enough to approach chemical equilibrium, the incremental effect of hydrogen ion is expected to be small (i.e., 6% for a rain of pH 4.0). Under nonequilibrium (i.e., high flow rate) conditions, kinetic considerations suggest that the incremental effect of hydrogen ion deposition could be quite significant. Field run-off experiments involving the chemical analysis of rain collected from inclined stone slabs have been used to evaluate stone dissolution processes under ambient conditions of wet and dry deposition of acidic species. The stoichiometry of the reaction of stone with hydrogen ion is difficult to define from the field data due to scatter in the data attributed to hydrodynamic effects. Laboratory run-off experiments show that the stoichiometry is best defined by a reaction with H+ in which CO2 is released from the system. The baseline effect caused by water in equilibrium with atmospheric CO2 is identical in the field and in laboratory simulation. The experiments show that the solutions are close enough to equilibrium for the incremental effect of hydrogen ion to be minor (i.e., 24% for marble for a rain of pH 4.0) relative to dissolution due to water and carbonic acid reactions. Stone erosion rates based on physical measurement are approximately double the recession rates that are due to dissolution (estimated from the observed calcium content of the run-off solutions). The difference may reflect the loss of granular material not included in recession estimates based on the run-off data. Neither the field nor the laboratory run-off experiments indicate a pH dependence for the grain-removal process.

Effects of simulated acid rain on soil respiration and its components in a subtropical mixed conifer and broadleaf forest in southern China.

PubMed

Liang, Guohua; Hui, Dafeng; Wu, Xiaoying; Wu, Jianping; Liu, Juxiu; Zhou, Guoyi; Zhang, Deqiang

2016-02-01

Soil respiration is a major pathway in the global carbon cycle and its response to environmental changes is an increasing concern. Here we explored how total soil respiration (RT) and its components respond to elevated acid rain in a mixed conifer and broadleaf forest, one of the major forest types in southern China. RT was measured twice a month in the first year under four treatment levels of simulated acid rain (SAR: CK, the local lake water, pH 4.7; T1, water pH 4.0; T2, water pH 3.25; and T3, water pH 2.5), and in the second year, RT, litter-free soil respiration (RS), and litter respiration (RL) were measured simultaneously. The results indicated that the mean rate of RT was 2.84 ± 0.20 μmol CO2 m(-2) s(-1) in the CK plots, and RS and RL contributed 60.7% and 39.3% to RT, respectively. SAR marginally reduced (P = 0.08) RT in the first year, but significantly reduced RT and its two components in the second year (P < 0.05). The negative effects were correlated with the decrease in soil microbial biomass and fine root biomass due to soil acidification under the SAR. The temperature coefficients (Q10) of RT and its two components generally decreased with increasing levels of the SAR, but only the decrease of RT and RL was significant (P < 0.05). In addition, the contribution of RL to RT decreased significantly under the SAR, indicating that RL was more sensitive to the SAR than RS. In the context of elevated acid rain, the decline trend of RT in the forests in southern China appears to be attributable to the decline of soil respiration in the litter layer.

Short-term effects of a simulated acid rain upon the growth and nutrient relations of Pinus strobus, L.

Treesearch

Tim Wood; F. H. Bormann

1976-01-01

Acidified precipitation may affect the productivity of forests by altering the availability of plant nutrients of by affecting the ability of trees to absorb and assimilate those nutrients. In this study, the short-term effects of simulated acid rain (pH range 5.6 - 2.3) upon the growth and nutrient relations of Eastern White Pine seedlings (Pinus strobus...

Contaminant removal and hydraulic conductivity of laboratory rain garden systems for stormwater treatment.

PubMed

Good, J F; O'Sullivan, A D; Wicke, D; Cochrane, T A

2012-01-01

In order to evaluate the influence of substrate composition on stormwater treatment and hydraulic effectiveness, mesocosm-scale (180 L, 0.17 m(2)) laboratory rain gardens were established. Saturated (constant head) hydraulic conductivity was determined before and after contaminant (Cu, Zn, Pb and nutrients) removal experiments on three rain garden systems with various proportions of organic topsoil. The system with only topsoil had the lowest saturated hydraulic conductivity (160-164 mm/h) and poorest metal removal efficiency (Cu ≤ 69.0% and Zn ≤ 71.4%). Systems with sand and a sand-topsoil mix demonstrated good metal removal (Cu up to 83.3%, Zn up to 94.5%, Pb up to 97.3%) with adequate hydraulic conductivity (sand: 800-805 mm/h, sand-topsoil: 290-302 mm/h). Total metal amounts in the effluent were <50% of influent amounts for all experiments, with the exception of Cu removal in the topsoil-only system, which was negligible due to high dissolved fraction. Metal removal was greater when effluent pH was elevated (up to 7.38) provided by the calcareous sand in two of the systems, whereas the topsoil-only system lacked an alkaline source. Organic topsoil, a typical component in rain garden systems, influenced pH, resulting in poorer treatment due to higher dissolved metal fractions.

Responses of tropical legumes from the Brazilian Atlantic Rainforest to simulated acid rain.

PubMed

Andrade, Guilherme C; Silva, Luzimar C

2017-07-01

We investigated the morphological and anatomical effects of simulated acid rain on leaves of two species native to the Brazilian Atlantic Rainforest: Paubrasilia echinata and Libidibia ferrea var. leiostachya. Saplings were subjected to acid rain in a simulation chamber during 10 days for 15 min daily, using H 2 SO 4 solution pH 3.0 and, in the control, deionized water. At the end of the experiment, fragments from young and expanding leaves were anatomically analyzed. Although L. ferrea var. leiostachya leaves are more hydrophobic, rain droplets remained in contact with them for a longer time, as in the hydrophilic P. echinata leaves, droplets coalesce and rapidly run off. Visual symptomatology consisted in interveinal and marginal necrotic dots. Microscopic damage found included epicuticular wax flaking, turgor loss and epidermal cell shape alteration, hypertrophy of parenchymatous cells, and epidermal and mesophyll cell collapse. Formation of a wound tissue was observed in P. echinata, and it isolated the necrosis to the adaxial leaf surface. Acid rain increased thickness of all leaf tissues except spongy parenchyma in young leaves of L. ferrea var. leiostachya, and such thickness was maintained throughout leaf expansion. To our knowledge, this is the first report of acidity causing increase in leaf tissue thickness. This could represent the beginning of cell hypertrophy, which was seen in visually affected leaf regions. Paubrasilia echinata was more sensitive, showing earlier symptoms, but the anatomical damage in L. ferrea var. leiostachya was more severe, probably due to the higher time of contact with acid solution in this species.

Transport and fate of acid rains out of North America. Final report, April 14, 1982-April 13, 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knap, A.H.

1983-06-01

A program to determine the transport of acid rain has been undertaken at Bermuda. The results indicate that precipitation at Bermuda is acidified to a pH of 4.8 over a one-year period with a seasonal component of greater acidity (pH 4.4) corresponding to back trajectories of the North American air mass. A detailed study of the composition of Bermuda rainwater compared to a North American coastal site has been carried out as well as a shipboard collection program between eastern North America and Bermuda. The results indicate that the strong acid acidity is due to long-range transport of the Northmore » American air mass.« less

Effects of roof and rainwater characteristics on copper concentrations in roof runoff.

PubMed

Bielmyer, Gretchen K; Arnold, W Ray; Tomasso, Joseph R; Isely, Jeff J; Klaine, Stephen J

2012-05-01

Copper sheeting is a common roofing material used in many parts of the world. However, copper dissolved from roof sheeting represents a source of copper ions to watersheds. Researchers have studied and recently developed a simple and efficient model to predict copper runoff rates. Important input parameters include precipitation amount, rain pH, and roof angle. We hypothesized that the length of a roof also positively correlates with copper concentration (thus, runoff rates) on the basis that runoff concentrations should positively correlate with contact time between acidic rain and the copper sheet. In this study, a novel system was designed to test and model the effects of roof length (length of roof from crown to the drip edge) on runoff copper concentrations relative to rain pH and roof angle. The system consisted of a flat-bottom copper trough mounted on an apparatus that allowed run length and slope to be varied. Water of known chemistry was trickled down the trough at a constant rate and sampled at the bottom. Consistent with other studies, as pH of the synthetic rainwater decreased, runoff copper concentrations increased. At all pH values tested, these results indicated that run length was more important in explaining variability in copper concentrations than was the roof slope. The regression equation with log-transformed data (R(2) = 0.873) accounted for slightly more variability than the equation with untransformed data (R(2) = 0.834). In log-transformed data, roof angle was not significant in predicting copper concentrations.

Acidity of Lakes and Impoundments in North-Central Minnesota

Treesearch

Elon S. Verry

1981-01-01

Measurements of lake and impoundment pH for several years, intensive sampling within years, and pH-calcium plots verify normal pH levels and do not show evidence of changes due to acid precipitation. These data in comparison with general lake data narrow the northern Lake States area in which rain or snow may cause lake acidification.

Advanced communications technology satellite high burst rate link evaluation terminal power control and rain fade software test plan, version 1.0

NASA Technical Reports Server (NTRS)

Reinhart, Richard C.

1993-01-01

The Power Control and Rain Fade Software was developed at the NASA Lewis Research Center to support the Advanced Communications Technology Satellite High Burst Rate Link Evaluation Terminal (ACTS HBR-LET). The HBR-LET is an experimenters terminal to communicate with the ACTS for various experiments by government, university, and industry agencies. The Power Control and Rain Fade Software is one segment of the Control and Performance Monitor (C&PM) Software system of the HBR-LET. The Power Control and Rain Fade Software automatically controls the LET uplink power to compensate for signal fades. Besides power augmentation, the C&PM Software system is also responsible for instrument control during HBR-LET experiments, control of the Intermediate Frequency Switch Matrix on board the ACTS to yield a desired path through the spacecraft payload, and data display. The Power Control and Rain Fade Software User's Guide, Version 1.0 outlines the commands and procedures to install and operate the Power Control and Rain Fade Software. The Power Control and Rain Fade Software Maintenance Manual, Version 1.0 is a programmer's guide to the Power Control and Rain Fade Software. This manual details the current implementation of the software from a technical perspective. Included is an overview of the Power Control and Rain Fade Software, computer algorithms, format representations, and computer hardware configuration. The Power Control and Rain Fade Test Plan provides a step-by-step procedure to verify the operation of the software using a predetermined signal fade event. The Test Plan also provides a means to demonstrate the capability of the software.

Acid rain and its ecological consequences.

PubMed

Singh, Anita; Agrawal, Madhoolika

2008-01-01

Acidification of rain-water is identified as one of the most serious environmental problems of transboundary nature. Acid rain is mainly a mixture of sulphuric and nitric acids depending upon the relative quantities of oxides of sulphur and nitrogen emissions. Due to the interaction of these acids with other constituents of the atmosphere, protons are released causing increase in the soil acidity Lowering of soil pH mobilizes and leaches away nutrient cations and increases availability of toxic heavy metals. Such changes in the soil chemical characteristics reduce the soil fertility which ultimately causes the negative impact on growth and productivity of forest trees and crop plants. Acidification of water bodies causes large scale negative impact on aquatic organisms including fishes. Acidification has some indirect effects on human health also. Acid rain affects each and every components of ecosystem. Acid rain also damages man-made materials and structures. By reducing the emission of the precursors of acid rain and to some extent by liming, the problem of acidification of terrestrial and aquatic ecosystem has been reduced during last two decades.

Acid rain at Kennedy Space Center, Florida - Recent observations

NASA Technical Reports Server (NTRS)

Madsen, B. C.

1981-01-01

During the period July, 1977 to September, 1979, rainfall was collected in the vicinity of the Kennedy Space Center and subjected to appropriate chemical analysis for purposes of characterization of general composition and acidity. Results obtained form the basis for future comparisons, should significant alteration of the chemical composition of rain occur during the space shuttle era. Acidity extremes calculated on a monthly basis from event samples collected from five sites within a 200 sq km area varied from pH 5.1 in November, 1977, and April, 1978 to pH 4.3 in July, 1978 and July, 1979. Weighted average pH for the entire period was 4.55. Acidity was due to the presence of sulfuric and nitric acids. The mole ratio of excess SO4(-2):NO3(-) was typically greater than one. Monthly weighted average Cl(-) concentrations ranged from 20-240 micromoles/liter. The Cl(-):Na(+) ratio was slightly lower than that present in sea water.

Modeled dosage-response relationship on the net photosynthetic rate for the sensitivity to acid rain of 21 plant species.

PubMed

Deng, Shihuai; Gou, Shuzhen; Sun, Baiye; Lv, Wenlin; Li, Yuanwei; Peng, Hong; Xiao, Hong; Yang, Gang; Wang, Yingjun

2012-08-01

This study investigated the sensitivity of plant species to acid rain based on the modeled dosage-response relationship on the net photosynthetic rate (P (N)) of 21 types of plant species, subjected to the exposure of simulated acid rain (SAR) for 5 times during a period of 50 days. Variable responses of P (N) to SAR occurred depending on the type of plant. A majority (13 species) of the dosage-response relationship could be described by an S-shaped curve and be fitted with the Boltzmann model. Model fitting allowed quantitative evaluation of the dosage-response relationship and an accurate estimation of the EC(10), termed as the pH of the acid rain resulting in a P (N) 10 % lower than the reference value. The top 9 species (Camellia sasanqua, Cinnamomum camphora, etc. EC(10) ≤ 3.0) are highly endurable to very acid rain. The rare, relict plant Metasequoia glyptostroboides was the most sensitive species (EC(10) = 5.1) recommended for protection.

Worldwide Report, Environmental Quality, No. 388, China Addresses Environmental Issues -- IV

DTIC Science & Technology

1983-03-04

resources and collaborate in a joint effort, the large helping the small, and the strong leading the weak. The Hanxiang Plant which produces fermented bean...1981 the rain falling on Chongqing had an average pH of 4.64 and a minimum value of 3. A pH of 3 is similar to that of vinegar . This minimum value is

Cyber Flag: A Realistic Cyberspace Training Construct

DTIC Science & Technology

2008-03-27

sincere appreciation to my research committee, Dr Mark Kanko, Dr Bob Bills , and Dr Rick Raines, as well as my faculty advisor, Major Paul Williams ...Graduate School of Engineering and Management Air Force Institute of Technology Air University Air Education and Training Command In Partial... Williams , Ph.D. (Chairman) date ___________//SIGNED//________________ 22 Jan 08 Mark A. Kanko, Ph.D. (Member) date

Analytic model for washout of HCl(g) from dispersing rocket exhaust clouds

NASA Technical Reports Server (NTRS)

Pellett, G. L.

1981-01-01

The potential is investigated that precipitation scavenging of HCl from large solid rocket exhaust clouds may result in unacceptably acidic rain in the Cape Canaveral, Florida, area before atmospheric dispersion reduces HCl concentrations to safe limits. Several analytic expressions for HCl(g) and HCl(g + aq) washout are derived; a geometric mean washout coefficient is recommended. A previous HCl washout model is refined and applied to a space shuttle case (70 t HCl exhausted up to 4 km) and eight Titan 3 (60 percent less exhaust) dispersion cases. The vertical column density (sigma) decays were deduced by application of a multilayer Gaussian diffusion model to seven standard meteorological regimes for overland advection. The Titan 3 decays of sigma and initial rain pH differed greatly among regimes; e.g., a range of 2 pH units was spanned at x 100 km downwind and t = 2 hr. Environmentally significant pH's .5 for infrequent exposures were shown possible at X = 50 km and t 5 hr for the two least dispersive Titan 3 cases. Representative examples of downwind rainwater pH and G(X) are analyzed. Factors affecting the validity of the results are discussed.

The role of urban forest to reduce rain acid in urban industrial areas

NASA Astrophysics Data System (ADS)

Slamet, B.; Agustiarni, Y.; Hidayati; Basyuni, M.

2018-03-01

Urban forest has many functions mainly on improving the quality of the urban environment. One of the functions is to increase pH and reduce dangerous chemical content. The aim of the research is to find out the role of vegetation density of urban forest around the industrial area in reducing the acid rain. The condition of land cover was classified into four classes which are dense, medium, sparse and open area. The water of the throughfall and stemflow was taken from each type of land cover except in the open area. Parameters measured in this study are water acidity (pH), anion content (SO4 2- and NO3 -), cation content (Ca2+, Mg2+, and NH4 +) and electrical conductivity (EC). The results indicated that urban forest vegetation was able to increase the pH of rain water from 5.42 which is in an open area without vegetation to be 7.13 and 7.32 in dense and moderate vegetation cover by throughfall mechanism, respectively. Rain water acidity also decreased through stemflow mechanism with a pH ranged from 5.92 - 6.43. Urban forest vegetation decreased sulfate content (SO42-) from 528.67 mg/l in open area to 44 - 118 mg/l by throughfall mechanism and ranged from 90 to 366.67 mg/l through stemflow mechanism. Urban forest vegetation significantly decreased the rainwater nitrate content from 27 mg/l to 0.03 - 0.70 mg/l through the mechanism of throughfall and between 1.53 - 8.82 mg/l through the stemflow mechanism. Urban forest vegetation also increased the concentration of cations (NH4+, Ca2+, Mg2+, Na+) compared with open areas. Urban forest vegetation showed increased the electrical conductivity (EC) from 208.12 μmhos/cm to 344.67 - 902.17 μmhos/cm through the through fall mechanism and 937.67 - 1058.70 μmhos/cm through the stemflow mechanism. The study suggested that urban forests play a significant role in reducing rainwater acidity and improving the quality of rainwater that reached the soil surface.

Structure of a microbial community in soil after prolonged addition of low levels of simulated acid rain

PubMed

Pennanen; Fritze; Vanhala; Kiikkila; Neuvonen; Baath

1998-06-01

Humus samples were collected 12 growing seasons after the start of a simulated acid rain experiment situated in the subarctic environment. The acid rain was simulated with H2SO4, a combination of H2SO4 and HNO3, and HNO3 at two levels of moderate acidic loads close to the natural anthropogenic pollution levels of southern Scandinavia. The higher levels of acid applications resulted in acidification, as defined by humus chemistry. The concentrations of base cations decreased, while the concentrations of exchangeable H+, Al, and Fe increased. Humus pH decreased from 3.83 to 3.65. Basal respiration decreased with decreasing humus pH, and total microbial biomass, measured by substrate-induced respiration and total amount of phospholipid fatty acids (PLFA), decreased slightly. An altered PLFA pattern indicated a change in the microbial community structure at the higher levels of acid applications. In general, branched fatty acids, typical of gram-positive bacteria, increased in the acid plots. PLFA analysis performed on the bacterial community growing on agar plates also showed that the relative amount of PLFA specific for gram-positive bacteria increased due to the acidification. The changed bacterial community was adapted to the more acidic environment in the acid-treated plots, even though bacterial growth rates, estimated by thymidine and leucine incorporation, decreased with pH. Fungal activity (measured as acetate incorporation into ergosterol) was not affected. This result indicates that bacteria were more affected than fungi by the acidification. The capacity of the bacterial community to utilize 95 different carbon sources was variable and only showed weak correlations to pH. Differences in the toxicities of H2SO4 and HNO3 for the microbial community were not found.

Stability of immobilization remediation of several amendments on cadmium contaminated soils as affected by simulated soil acidification.

PubMed

Guo, Fuyu; Ding, Changfeng; Zhou, Zhigao; Huang, Gaoxiang; Wang, Xingxiang

2018-06-04

Chemical immobilization is a practical approach to remediate heavy metal contamination in agricultural soils. However, the potential remobilization risks of immobilized metals are a major environmental concern, especially in acid rain zones. In the present study, changes in the immobilization efficiency of several amendments as affected by simulated soil acidification were investigated to evaluate the immobilization remediation stability of several amendments on two cadmium (Cd) contaminated soils. Amendments (hydrated lime, hydroxyapatite and biochar) effectively immobilized Cd, except for organic fertilizer, and their immobilizations were strongly decreased by the simulated soil acidification. The ratio of changes in CaCl 2 -extractable Cd: pH (△CaCl 2 -Cd/△pH) can represent the Cd remobilization risk of different amended soils. Hydroxyapatite and biochar had a stronger durable immobilizing effect than did hydrated lime, particularly in soil with a lower pH buffering capacity, which was further confirmed by the Cd concentration and accumulation in lettuce. These results can be attributed to that hydroxyapatite and biochar transformed greater proportions of exchangeable Cd to other more stable fractions than lime. After 48 weeks of incubation, in soil with a lower pH buffering capacity, the immobilization efficiencies of lime, hydroxyapatite, biochar and organic fertilizer in the deionized water group (pH 6.5) were 71.7%, 52.7%, 38.6% and 23.9%, respectively, and changed to 19.1%, 33.6%, 26.5% and 5.0%, respectively, in the simulated acid rain group (pH 2.5). The present study provides a simple method to preliminarily estimate the immobilization efficiency of amendments and predict their stability in acid rain regions before large-scale field application. In addition, hydrated lime is recommended to be combined with other acid-stable amendments (such as hydroxyapatite or biochar) to remediate heavy metal-contaminated agricultural soils in acid precipitation zones. Copyright © 2018 Elsevier Inc. All rights reserved.

Corrosion of 85-5-5-5 bronze in natural and synthetic acid rain

NASA Astrophysics Data System (ADS)

Morselli, L.; Bernardi, E.; Chiavari, C.; Brunoro, G.

In order to investigate the decay of bronzes exposed to acid wet depositions, a comparative study has been performed by following the corrosion behaviour of different sets of bronze specimens exposed either to natural rain or to a similar solution, without organic compounds, artificially reproduced in laboratory. The as cast G85 bronze specimens were exposed to aggressive solutions for different periods through a wet-dry technique. The pH trend of the solutions and the amount of metals transferred into the solutions were periodically monitored. OM, SEM, XRD, RAMAN analyses and ac electrochemical measurements were performed on the artificially weathered specimens. Preliminary results, showing the difference between the ageing in natural and synthetic rain, suggest the influence of the organic components on the corrosion process. In particular, the growth of a more uniform protective layer of corrosion products on the metal surface exposed to the natural rain could be attributed to these components.

The chemistry of the severe acidic precipitation in Shanghai, China

NASA Astrophysics Data System (ADS)

Huang, Kan; Zhuang, Guoshun; Xu, Chang; Wang, Ying; Tang, Aohan

2008-07-01

Seventy-six rain samples from forty-seven rain events and TSP aerosol samples throughout the entire year of 2005 were collected in Shanghai, China. The annual mean pH in rain was 4.49 with the lowest pH of 2.95, and the frequency of acid rain was 71% in 2005. The acidity of rain increased more than 15 times in the past 8 years compared to 1997. The volume-weighted mean ionic concentrations of the acidic ions, SO 42- and NO 3- in rainwater were 199.59 and 49.80 μeq/L with maximum of 832.67 and 236.59 μeq/L, respectively. The concentration of SO 42- was higher than the most polluted cities abroad, indicating Shanghai has been a severe polluted city over the world. The high coal/fuel consumption from urbanization and the rapid increase of vehicles resulted in the high emission of SO 2 and NO x, the precursor of the high concentration of acidic ions, SO 42- and NO 3-, which were the main reason of the severe acid rain in Shanghai. The major ions showed clear temporal variations with higher concentrations of SO 42-, NO 3-, NH 4+, and Ca 2+ in spring/winter, of Na +, Cl -, K +, and Mg 2+ in autumn, and the lowest of all the ions in summer. SO 42- and NO 3- were mainly in the form of CaSO 4 and Ca(NO 3) 2, which showed the dominant neutralization effect of Ca 2+ over NH 4+. Source identification indicated that SO 42-, NO 3-, NH 4+ and most Ca 2+ derived from anthropogenic sources, K +, Mg 2+ and partial Ca 2+ originated from mineral, and almost all the Cl - and Na + from the sea. The chemistry of precipitation in Shanghai was under the influence of local pollution sources and the long- and moderate-range transport through back trajectory analysis.

Alterations in cytosol free calcium in horseradish roots simultaneously exposed to lanthanum(III) and acid rain.

PubMed

Zhang, Xuanbo; Wang, Lihong; Zhou, Anhua; Zhou, Qing; Huang, Xiaohua

2016-04-01

The extensive use of rare earth elements (REEs) has increased their environmental levels. REE pollution concomitant with acid rain in many agricultural regions can affect crop growth. Cytosol free calcium ions (Ca(2+)) play an important role in almost all cellular activities. However, no data have been reported regarding the role of cytosol free Ca(2+) in plant roots simultaneously exposed to REE and acid rain. In this study, the effects of exposures to lanthanum(III) and acid rain, independently and in combination, on cytosol free Ca(2+) levels, root activity, metal contents, biomass, cytosol pH and La contents in horseradish roots were investigated. The simultaneous exposures to La(III) and acid rain increased or decreased the cytosol free Ca(2+) levels, depending on the concentration of La(III), and these effects were more evident than independent exposure to La(III) or acid rain. In combined exposures, cytosol free Ca(2+) played an important role in the regulation of root activity, metal contents and biomass. These roles were closely related to La(III) dose, acid rain strength and treatment mode (independent exposure or simultaneous exposure). A low concentration of La(III) (20 mg L(-1)) could alleviate the adverse effects on the roots caused by acid rain, and the combined exposures at higher concentrations of La(III) and acid rain had synergic effects on the roots. Copyright © 2015 Elsevier Inc. All rights reserved.

Experimental chemical weathering of various bedrock types at different pH-values. 1. Sandstone and granite

USGS Publications Warehouse

Afifi, A.A.; Bricker, O.P.; Chemerys, J.C.

1985-01-01

Experimental chemical weathering of the so-called Old Rag Granite and Massanutten Sandstone, Virginia, U.S.A., has produced a comparison with the natural environment, and prediction of the effect of acid precipitation. The experimental results of the release of elements, dissolution of minerals, total rock weathered and the degree of weathering as function of volume of leachate were plotted. These data were compared with the natural environment. The use of the plots to predict the effect of high levels of rain acidity on weathering of these rocks is demonstrated. A nonexpandable 14-A?? clay was developed from the alteration of biotite during the experimental chemical weathering of the granite at pH 4. This interstratified Al(OH)-mica clay resembles those of the soil developed on the granite and sandstone. Hydroxy-Al may be precipitating between the mica interlayers and producing a 14-A?? spacing. Development of this clay by chemical alteration of biotite may change the current hypotheses about its origin in the soils of northeastern U.S.A. While Al-hydroxide seems to regulate Al concentrations in stream waters at the present level of rain acidity, it was found that at lower pH and in the presence of high sulfate concentrations, Al solubility may be controlled by Al-sulfate phase(s). ?? 1985.

Elution of lead from lead zirconate titanate ceramics to acid rain

NASA Astrophysics Data System (ADS)

Tsurumi, Takaaki; Takezawa, Shuhei; Hoshina, Takuya; Takeda, Hiroaki

2017-10-01

The amount of lead that eluted from lead zirconate titanate (PZT) ceramics to artificial acid rain was evaluated. Four kinds of PZT ceramics, namely, pure PZT at MPB composition, CuO-added PZT, PZT with 10 mol % substitution of Ba for Pb, and CuO-added PZT with 10 mol % substitution of Ba for Pb, were used as samples of the elution test. These PZT ceramics of 8 mm2 and 1.1-1.2 mm thickness were suspended in 300 ml of H2SO4 solution of pH 4.0. The concentration of lead eluted from PZT was in the range from 0.2 to 0.8 ppm. It was found that both liquid phase formation by the addition of CuO and the substitution of Ba for Pb were effective to reduce the amount of lead that eluted. By fitting the leaching out curve with a classical equation, a master curve assuming no sampling effect was obtained. The lead concentration evaluated from the amount of lead that eluted from a commercial PZT plate to H2SO4 solution of pH 5.3 was almost the same as the limit in city water. It is concluded that PZT is not harmful to health and the environment and the amount of lead that eluted from PZT can be controlled by modifying PZT composition.

Environmental factors affecting corrosion of munitions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bundy, K.; Bricka, M.; Morales, A.

1995-12-31

Spent small arms munitions have accumulated for years at outdoor firing ranges operated by the DoD and other groups. Used bullets are often subjected to moisture sources. There is increasing concern that accumulations of lead-based munitions represent potential sources of water and soil pollution. To understand both the severity of and solutions to this problem, it is necessary to measure how rapidly bullets corrode and to determine the soil variables affecting the process. In this study M16 bullets were buried in samples of soil taken from Louisiana army firing ranges. Four environmental conditions were simulated; rain water, acid rain, seamore » water, and 50% sea water/50% acid rain. The three electrode technique was used to measure the bullet corrosion. Graphite rods served as counter electrodes. A saturated calomel reference electrode was used along with a specially constructed salt bridge. Electrochemical measurements were conducted using a computer-controlled potentiostat to determine corrosion potential, soil resistance, and corrosion current. The rate of corrosion was found to markedly increase with decreasing soil pH and increasing chloride and moisture contents, with the chloride content being the most influential variable. High soil resistance and noble corrosion potential were found to be associated with low corrosion rates. This is important since both parameters can be readily measured in the field.« less

Acidification of experimental wetlands: Effects on wetland productivity and survival of juvenile black ducks

USGS Publications Warehouse

Haramis, G.M.; Chu, D.S.; Bunck, C.M.; Mingo, T.M.; Schaffner, W.W.R.

1997-01-01

Six man-made wetlands (0.02 ha each) and pen-reared broods of American black ducks (Anas rubripes) were used to assess the effects of reduced pH on the quality of fish- free, palustrine habitat for brood rearing. Acid treatment was assigned randomly among newly constructed wetlands during April through June 1984-85, to simulate depressed pH from snowmelt and spring rain. Sampling of chlorophyll epiphytic growth, zooplankton and macroinvertebrates confirmed reduced productivity of acidified (pH 5.0) versus control (pH 6.8) wetlands. Primary productivity was particularly reduced in acidified wetlands in early spring as indicated by high water transparency and low chlorophyll a concentrations. Chlrophyll a concentrations showed treatment (p = 0.01) and date (p = 0.05) effects, but no interaction, and dry weight of epiphytic growth was lower (p = 0.03) in acidified versus control wetlands. Numbers of zooplankton were similar in experimental wetlands, although controls generally exceeded acidified wetlands in abundance; only a single treatment effect for cladocerans (p = 0.1) was detected. Sweep net samples yielded greater numbers (p = 0.03), taxa (p = 0.01) and biomass (p = 0.07) of macroinvertebrates in control wetlands with gastropods, pelecypods and leeches notably reduced by acidification. Placement of 18 broods (female with four 10-day-old ducklings) for 10-day trials on experimental wetlands revealed limited growth, altered behaviour and marked reduction in survival of ducklings on acidified wetlands. An inadequate number of invertebrates is indicated as the cause for poor duckling productivity on acidified wetlands

Quantity and quality of runoff reduction and recharge enhancement from constructed rain gardens and vegetated retention ponds in Austin, Texas

NASA Astrophysics Data System (ADS)

Eljuri, A. G.; Moffett, K. B.

2013-12-01

Rain gardens and retention ponds are intended to reduce storm water and pollutant runoff to rivers and streams, rain gardens by enhancing infiltration and retention ponds by promoting evaporation. The City of Austin, Texas is actively investing money and time into these storm water management solutions, but there are no data comparing their effectiveness. In particular, comparisons of rain gardens against control plots and new wetland-vegetated retention pond designs against traditional grassy pond designs are lacking. This study quantifies the quantity and quality of storm runoff to and from five sites: three engineered sites, two rain gardens receiving direct runoff from the same residential roof and a planted retention pond receiving municipal parking lot runoff, and two control sites, a mulched residential lawn receiving direct roof runoff and a grassy municipal retention pond receiving parking lot runoff. A locally installed rain gauge monitors precipitation rates and we collect and analyze rainwater chemistry. Each site is instrumented with bottles to collect direct runoff samples and suction lysimeters within and below the root zone, at 10 cm and 40 cm depth, from which to collect soil water. Soil moisture sensors at 5 cm, 25 cm, and 50 cm depth are used to monitor changes in soil moisture profiles over time. Evapotranspiration rates were determined using local meteorological data and stomatal conductance measurements at the sites. Infiltrometer tests, soil characterizations, and vegetation surveys were also conducted at each site. The soil at the rain gardens are highly mixed with pebbles at the top and become a more uniform soil towards the bottom of the root zone. This differs from the control site where the soil is uniform except for the thin layer of wood chips at the surface. The water samples were analyzed for pH, dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), and cations (incl. cadmium, iron, zinc, and lead) and anions (incl. ammonia and nitrate). Samples of waters are taken immediately after rain events and soil moisture is taken both immediately after and two days after events. Austin summers experience fewer rainy days than the spring, fall, and winter, but summer storms are usually high-intensity and short-duration, increasing the potential for flooding. Seasonally, rainfall is somewhat more concentrated around May and October. We find that the negligible constituent concentrations of rainfall quickly become enriched in metals and nutrients from contact with impervious surfaces and that the presence of vegetation is critical, both as canopy over the surface, which promotes substantially higher nutrient levels in runoff (e.g., 1.45 ppm ammonia and 1.68 ppm nitrate under an overhanging tree compared to 0.57 ppm and 0.13 ppm not under the tree), and as plantings in the pond and gardens, which promote infiltration. These field data and a GIS study comparing different possible distributions of future rain gardens and vegetated retention ponds across the city provide much needed data and analysis to support decision making regarding these green storm water management solutions in central Texas.

Chemical composition of precipitation in a Mexican Maya region

NASA Astrophysics Data System (ADS)

Bravo, H. A.; Saavedra, M. I. R.; Sánchez, P. A.; Torres, R. J.; Granada, L. M. M.

The chemical characteristics of wet precipitation in Puerto Morelos, Quintana Roo State, Mexico, were measured from April 1994 to December 1995. Puerto Morelos is located in the Caribbean Mayan coastal region of the Peninsula of Yucatan, and is normally exposed to winds from the Caribbean region. Wetfall was analyzed for pH, conductivity and Cl -, NO 3-, SO 42-, Na +, NH 4+, K +, Mg 2+ and Ca 2+ ion concentrations. Volume-weighted mean pH for the whole sampling period was 5.35, although values as low as 4.6 were measured in several rain samples. Concentrations of all species correlated negatively with rain volume. Sea-salt aerosols contributed with most of the Na +, Cl -, Mg 2+, K + and SO 42- found in wet precipitation. The mean [SO 42-excess] was 9.7 μEq l -1, which agrees with the background hemispheric values of ≈10 μEq l -1 reported elsewhere. The mean [NO 3-] was 11.4 μEq l -1, almost four times higher than the background hemispheric value of ≈2.5 μEq l -1 reported elsewhere. However, a major component causing the slight acidity character of rain in Puerto Morelos seems to be H 2SO 4.

Production of Alkaline Cellulase by Fungi Isolated from an Undisturbed Rain Forest of Peru

PubMed Central

Vega, Karin; Villena, Gretty K.; Sarmiento, Victor H.; Ludeña, Yvette; Vera, Nadia; Gutiérrez-Correa, Marcel

2012-01-01

Alkaline cellulase producing fungi were isolated from soils of an undisturbed rain forest of Peru. The soil dilution plate method was used for the enumeration and isolation of fast growing cellulolytic fungi on an enriched selective medium. Eleven out of 50 different morphological colonies were finally selected by using the plate clearing assay with CMC as substrate at different pH values. All 11 strains produced cellulases in liquid culture with activities at alkaline pH values without an apparent decrease of them indicating that they are true alkaline cellulase producers. Aspergillus sp. LM-HP32, Penicillium sp. LM-HP33, and Penicillium sp. LM-HP37 were the best producers of FP cellulase (>3 U mL−1) with higher specific productivities (>30 U g−1 h−1). Three strains have been found suitable for developing processes for alkaline cellulase production. Soils from Amazonian rain forests are good sources of industrial fungi with particular characteristics. The results of the present study are of commercial and biological interest. Alkaline cellulases may be used in the polishing and washing of denim processing of the textile industry. PMID:23213539

Assessing acid rain and climate effects on the temporal variation of dissolved organic matter in the unsaturated zone of a karstic system from southern China

NASA Astrophysics Data System (ADS)

Liao, Jin; Hu, Chaoyong; Wang, Miao; Li, Xiuli; Ruan, Jiaoyang; Zhu, Ying; Fairchild, Ian J.; Hartland, Adam

2018-01-01

Acid rain has the potential to significantly impact the quantity and quality of dissolved organic matter (DOM) leached from soil to groundwater. Yet, to date, the effects of acid rain have not been investigated in karstic systems, which are expected to strongly buffer the pH of atmospheric rainfall. This study presents a nine-year DOM fluorescence dataset from a karst unsaturated zone collected from two drip sites (HS4, HS6) in Heshang Cave, southern China between 2005 and 2014. Cross-correlograms show that fluorescence intensity of both dripwaters lagged behind rainfall by ∼1 year (∼11 months lag for HS4, and ∼13 months for HS6), whereas drip rates responded quite quickly to rainfall (0 months lag for HS4, and ∼3 months for HS6), based on optimal correlation coefficients. The rapid response of drip rates to rainfall is related to the change of reservoir head pressure in summer, associated with higher rainfall. In winter, low rainfall has a limited effect on head pressure, and drip rates gradually slow to a constant value associated with base flow from the overlying reservoir- this effect being most evident on inter-annual timescales (R2 = 0.80 for HS4 and R2 = 0.86 for HS6, n = 9, p < 0.01). We ascribed the ∼1 year lag of fluorescence intensity to the effect of the soil moisture deficit and the karst process on delaying water and solute transport. After eliminating the one year lag, the congruent seasonal pacing and amplitude between fluorescence intensity and rainfall observed suggests that the seasonality of fluorescence intensity was mainly controlled by the monsoonal rains which can govern the output of DOM from the soil, as well as the residence time of water in the unsaturated zone. On inter-annual timescales, a robust linear relationship between fluorescence intensity and annual (effective) precipitation amount (R2 = 0.86 for HS4 and R2 = 0.77 for HS6, n = 9, p < 0.01) was identified, implying that annual (effective) precipitation is the main determinant of DOM concentration in the aquifer. Conversely, the insensitivity of fluorescence intensity and fluorescence wavelength maxima to variations in the pH of local rainfall suggests that acid rain over the study period (∼pH 5.6 to ∼ 4.5) had no discernable effect on the quantity and quality of DOM in karst soil and soil solution, likely being strongly buffered by soil carbonates. Therefore, despite large increases in anthropogenic acid rain in recent Chinese history, hydrologic forcing is the predominant factor driving variations in DOM in karst aquifers.

Indicators: Acidification

EPA Pesticide Factsheets

Acidification is a broad term that refers to the process by which aquatic ecosystems become more acidic. Acid rain and acid mine drainage are major sources of acidifying compounds, lowering the pH below the range where most living organisms function.

Leaf surface and histological perturbations of leaves of Phaseolus vulgaris and Helianthus annuus after exposure to simulated acid rain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evans, L.S.; Gmur, N.F.; Da Costa, F.

1977-08-01

Initial injury to adaxial leaf surfaces of Phaseolus vulgaris and Helianthus annuus occurred near trichomes and stomata after exposure to simulated sulfate acid rain. Lesion frequency was not correlated with density of either stomata or trichomes but was correlated with degree of leaf expansion. The number of lesions per unit area increased with total leaf area. Results suggest that characteristics of the leaf indumentum such as development of trichomes and guard cells and/or cuticle thickness near these structures may be involved in lesion development. Adaxial epidermal cell collapse was the first event in lesion development. Palisade cells and eventually spongymore » mesophyll cells collapsed after continued, daily exposure to simulated rain of low pH. Lesion development on Phaseolus vulgaris followed a specific course of events after exposure to simulated rain of known composition, application rate, drop size frequency, drop velocities, and frequency of exposures. These results allow development of further experiments to observe accurately other parameters, such as nutrient inputs and nutrient leaching from foliage, after exposure to simulated sulfate acid rain.« less

Photosynthesis and oxidative stress in the restinga plant species Eugenia uniflora L. exposed to simulated acid rain and iron ore dust deposition: potential use in environmental risk assessment.

PubMed

Neves, Natália Rust; Oliva, Marco Antonio; da Cruz Centeno, Danilo; Costa, Alan Carlos; Ribas, Rogério Ferreira; Pereira, Eduardo Gusmão

2009-06-01

The Brazilian sandy coastal plain named restinga is frequently subjected to particulate and gaseous emissions from iron ore factories. These gases may come into contact with atmospheric moisture and produce acid rain. The effects of the acid rain on vegetation, combined with iron excess in the soil, can lead to the disappearance of sensitive species and decrease restinga biodiversity. The effects of iron ore dust deposition and simulated acid rain on photosynthesis and on antioxidant enzymes were investigated in Eugenia uniflora, a representative shrub species of the restinga. This study aimed to determine the possible utility of this species in environmental risk assessment. After the application of iron ore dust as iron solid particulate matter (SPM(Fe)) and simulated acid rain (pH 3.1), the 18-month old plants displayed brown spots and necrosis, typical symptoms of iron toxicity and injuries caused by acid rain, respectively. The acidity of the rain intensified leaf iron accumulation, which reached phytotoxic levels, mainly in plants exposed to iron ore dust. These plants showed the lowest values for net photosynthesis, stomatal conductance, transpiration, chlorophyll a content and electron transport rate through photosystem II (PSII). Catalase and superoxide dismutase activities were decreased by simulated acid rain. Peroxidase activity and membrane injury increased following exposure to acid rain and simultaneous SPM(Fe) application. Eugenia uniflora exhibited impaired photosynthetic and antioxidative metabolism in response to combined iron and acid rain stresses. This species could become a valuable tool in environmental risk assessment in restinga areas near iron ore pelletizing factories. Non-invasive evaluations of visual injuries, photosynthesis and chlorophyll a fluorescence, as well as invasive biochemical analysis could be used as markers.

Combined effects of simulated acid rain and lanthanum chloride on chloroplast structure and functional elements in rice.

PubMed

Hu, Huiqing; Wang, Lihong; Zhou, Qing; Huang, Xiaohua

2016-05-01

Acid rain and rare earth element (REE) pollution exist simultaneously in many agricultural regions. However, how REE pollution and acid rain affect plant growth in combination remains largely unknown. In this study, the combined effects of simulated acid rain and lanthanum chloride (LaCl3) on chloroplast morphology, chloroplast ultrastructure, functional element contents, chlorophyll content, and the net photosynthetic rate (P n) in rice (Oryza sativa) were investigated by simulating acid rain and rare earth pollution. Under the combined treatment of simulated acid rain at pH 4.5 and 0.08 mM LaCl3, the chloroplast membrane was smooth, proteins on this membrane were uniform, chloroplast structure was integrated, and the thylakoids were orderly arranged, and simulated acid rain and LaCl3 exhibited a mild antagonistic effect; the Mg, Ca, Mn contents, the chlorophyll content, and the P n increased under this combined treatment, with a synergistic effect of simulated acid rain and LaCl3. Under other combined treatments of simulated acid rain and LaCl3, the chloroplast membrane surface was uneven, a clear "hole" was observed on the surface of chloroplasts, and the thylakoids were dissolved and loose; and the P n and contents of functional elements (P, Mg, K, Ca, Mn, Fe, Ni, Cu, Zn and Mo) and chlorophyll decreased. Under these combined treatments, simulated acid rain and LaCl3 exhibited a synergistic effect. Based on the above results, a model of the combined effects of simulated acid rain and LaCl3 on plant photosynthesis was established in order to reveal the combined effects on plant photosynthesis, especially on the photosynthetic organelle-chloroplast. Our results would provide some references for further understanding the mechanism of the combined effects of simulated acid rain and LaCl3 on plant photosynthesis.

Characterization of heavy metal desorption from road-deposited sediment under acid rain scenarios.

PubMed

Zhao, Bo; Liu, An; Wu, Guangxue; Li, Dunzhu; Guan, Yuntao

2017-01-01

Road-deposited sediments (RDS) on urban impervious surfaces are important carriers of heavy metals. Dissolved heavy metals that come from RDS influenced by acid rain, are more harmful to urban receiving water than particulate parts. RDS and its associated heavy metals were investigated at typical functional areas, including industrial, commercial and residential sites, in Guangdong, Southern China, which was an acid rain sensitive area. Total and dissolved heavy metals in five particle size fractions were analyzed using a shaking method under acid rain scenarios. Investigated heavy metals showed no difference in the proportion of dissolved fraction in the solution under different acid rain pHs above 3.0, regardless of land use. Dissolved loading of heavy metals related to organic carbon content were different in runoff from main traffic roads of three land use types. Coarse particles (>150μm) that could be efficiently removed by conventional street sweepers, accounted for 55.1%-47.1% of the total dissolved metal loading in runoff with pH3.0-5.6. The obtained findings provided a significant scientific basis to understand heavy metal release and influence of RDS grain-size distribution and land use in dissolved heavy metal pollution affected by acid rain. Copyright © 2016. Published by Elsevier B.V.

Pollution problem: acid rain and beekeeping

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hayes, B.

1979-11-01

Some of the problems caused by acid rain are presented with emphasis on the effects on bees, especially in the Northeast. Scientists believe that rain east of the Mississippi is below 5.6 and average Northeastern rainfall is now down to pH 4. Trace minerals are being leached out of the soils and nectar that lacks calcium is being passed by when the bees forage. The first plants to show the effects will be the wild varieties of the legumes, such as clover. This leaves only plants on the extreme end of the acid scale such as the blueberry for beemore » forage. This leads to the side effect of the movement of calcium in nectar which will be restricted due to a lack of calcium-lime.« less

Acid Rain: Science Projects.

ERIC Educational Resources Information Center

Stubbs, Harriett S.

1989-01-01

Presented is a science activity designed to help students monitor the pH of rainfall. Materials, procedures and follow-up activities are listed. A list of domestic and foreign sources of information is provided. Topics which relate to acid precipitation are outlined. (CW)

An evaluation of rain chemistry data for the John F. Kennedy Space Center, Florida and the University of Central Florida, Orlando

NASA Technical Reports Server (NTRS)

Madsen, Brooks C.; Dreschel, Thomas W.; Hinkle, C. Ross

1986-01-01

Concern over the effects of Space Shuttle launches prompted the initiation of a rather intense environmental monitoring program. The program included a precipitation monitoring network with 13 precipitation collection sites which were operated for various time periods to baseline precipitation chemistry at the John F. Kennedy Space Center (KSC). One additional site was also established as a remote background site on the Univ. of Central Florida (UCF) campus. One of the 13 sites was converted to a National Atmospheric Deposition Program (NADP) station. Collections and analyses of samples were performed using a number of methodologies during the monitoring period. An evaluation of the data for comparability and utility for acid rain research was performed using the anion/cation, measured conductivity, calculated conductivity, Cl/Na, and Mg/Na ratios. Data collected at all KSC sites between 1977 and 1981, from 1983 to 1985 at the NADP site and at UCF to 1985 are comparable and appropriate for determining acid rain trends. Examination of those comparable data showed a fairly stable pH between 1977 and 1982 and an increase of 0.2 pH units which was observed as an incremental increase between 1982 and 1983 at KSC and UCF.

The combined effects of urea application and simulated acid rain on soil acidification and microbial community structure.

PubMed

Liu, Xingmei; Zhou, Jian; Li, Wanlu; Xu, Jianming; Brookes, Philip C

2014-05-01

Our aim was to test the effects of simulated acid rain (SAR) at different pHs, when applied to fertilized and unfertilized soils, on the leaching of soil cations (K, Ca, Mg, Na) and Al. Their effects on soil pH, exchangeable H(+) and Al(3+) and microbial community structure were also determined. A Paleudalfs soil was incubated for 30 days, with and without an initial application of urea (200 mg N kg(-1)soil) as nitrogen (N) fertilizer. The soil was held in columns and leached with SAR at three pH levels. Six treatments were tested: SAR of pH 2.5, 4.0 and 5.6 leaching on unfertilized soil (T1, T2 and T3), and on soils fertilized with urea (T4, T5 and T6). Increasing acid inputs proportionally increased cation leaching in both unfertilized and fertilized soils. Urea application increased the initial Ca and Mg leaching, but had no effect on the total concentrations of Ca, Mg and K leached. There was no significant difference for the amount of Na leached between the different treatments. The SAR pH and urea application had significant effects on soil pH, exchangeable H(+) and Al(3+). Urea application, SAR treated with various pH, and the interactions between them all had significant impacts on total phospholipid fatty acids (PLFAs). The highest concentration of total PLFAs occurred in fertilized soils with SAR pH5.6 and the lowest in soils leached with the lowest SAR pH. Soils pretreated with urea then leached with SARs of pH 4.0 and 5.6 had larger total PLFA concentrations than soil without urea. Bacterial, fungal, actinomycete, Gram-negative and Gram-positive bacterial PLFAs had generally similar trends to total PLFAs.

Combined acid rain and lanthanum pollution and its potential ecological risk for nitrogen assimilation in soybean seedling roots.

PubMed

Zhang, Fan; Cheng, Mengzhu; Sun, Zhaoguo; Wang, Lihong; Zhou, Qing; Huang, Xiaohua

2017-12-01

Rare earth elements (REEs) are used in various fields, resulting in their accumulation in the environment. This accumulation has affected the survival and distribution of crops in various ways. Acid rain is a serious global environmental problem. The combined effects on crops from these two types of pollution have been reported, but the effects on crop root nitrogen assimilation are rarely known. To explore the impact of combined contamination from these two pollutants on crop nitrogen assimilation, the soybean seedlings were treated with simulated environmental pollution from acid rain and a representative rare earth ion, lanthanum ion (La 3+ ), then the indexes related to plant nitrogen assimilation process in roots were determined. The results showed that combined treatment with pH 4.5 acid rain and 0.08 mM La 3+ promoted nitrogen assimilation synergistically, while the other combined treatments all showed inhibitory effects. Moreover, acid rain aggravated the inhibitory effect of 1.20 or 0.40 mM La 3+ on nitrogen assimilation in soybean seedling roots. Thus, the effects of acid rain and La 3+ on crops depended on the combination levels of acid rain intensity and La 3+ concentration. Acid rain increases the bioavailability of La 3+ , and the combined effects of these two pollutants were more serious than that of either pollutant alone. These results provide new evidence in favor of limiting overuse of REEs in agriculture. This work also provides a new framework for ecological risk assessment of combined acid rain and REEs pollution on soybean crops. Copyright © 2017 Elsevier Ltd. All rights reserved.

Why Isn't My Rain as Acidic as Yours?

ERIC Educational Resources Information Center

Zajicek, O. T.

1985-01-01

Discusses three topics that have been improperly applied to the acidic precipitation issue. They are: (1) use of the pH scale; (2) acidity; and (3) solution equilibria of strong and weak acids. Implications for instruction are considered. (JN)

Vertical nutrient and trace element migration in cambisoils after application of residues from anaerobic digestion of pig manure

NASA Astrophysics Data System (ADS)

Sager, Manfred; Unterfrauner, Hans

2013-04-01

Cambisols sampled in alpine pastures were packed into soil columns in order to monitor downward migration of nutrient and trace elements, applied within the residue from anaerobic digestion of a pig manure. 2 rain events per week were simulated. The manure added substantial amounts of K, ammonium, Na, Ca, P, S, Cl, B, Zn and Cu to the soil, whereas Mg, Mn, Ni, Cr, Pb, Cd and V were at the same level. In the eluates, total elemental composition as well as nitrate and ammonium were monitored. Addition of soluble Fe (at 1000 mg/l as FeCl3) decreased the release of soluble sulphate, but had no significant effect on the release of Fe and P. During subsequent rain events, exchangeable K remained enriched in the topsoil, wheras total sulfur moved to deeper layers. After 8 weeks, the columns were dismantled and analyzed for quasi-total and mobile fractions. Both in topsoils and subsoils, manure addition finally increased soil pH in case of low P soils, but decreased soil pH in case of high pH soils. Effects of manure applications on groundwater formation processes will be discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohnen, V.A.; Aneja, V.; Bailey, B.

The report summarizes the results of the four year field measurement and data analysis program of MCCP. The MCCP is sponsored by the U.S. Environmental Protection Agency as part of the joint U.S. Forest Service-EPA Spruce-Fir Research Cooperative. The objectives of the project have been met and the result is an assessment of principal atmospheric constituents as they impact the high elevation forests of the Eastern U.S. Deposition of SO4(-2), NO3(-), H(+), and NH(4+) in cloud water represents a significant input to forest canopies with elevations greater than 1000m. Cloud water deposition can exceed wet (rain) deposition and may bemore » the dominant process for input of sulfate and nitrate compounds during the growing season in high elevation forests frequently exposed to clouds. Cloud water pH concentrations may be as much as 0.6pH units lower than pH in rain. SO(4+) and NO3(-) concentrations are also higher in cloud water than in precipitation. Ozone data reveals that significant differences exist between ozone concentrations at high elevation and low elevation sites. The primary effect of the difference is to produce higher mean ozone concentrations and longer episodes at the higher elevation sites.« less

[Characteristics of precipitation pH and conductivity at Mt. Huang].

PubMed

Shi, Chun-e; Deng, Xue-liang; Wu, Bi-wen; Hong, Jie; Zhang, Su; Yang, Yuan-jian

2013-05-01

To understand the general characteristics of pH distribution and pollution in precipitation at Mt. Huang, statistical analyses were conducted for the routine measurements of pH and conductivity (K) at Mt. Huang during 2006-2011. The results showed that: (1) Over the period of study, the annual volume weighted mean (VWM) precipitation pH varied from 4.81 to 5.57, with precipitation acidity strengthening before 2009 and weakening thereafter. The precipitation acidity showed evident seasonal variations, with the VWM pH lowest in winter (4.78), and highest in summer (5.33). The occurrence frequency of acid rain was 46% , accounting for 45% of total rainfalls and with the most frequent pH falling into weak acid to neutral rain. (2) The annual VWM K varied from 16.91 to 27.84 microS x cm(-1), with no evident trend. As for ions pollution, the precipitation was relatively clean at Mt. Huang, with the most frequent K range being below 15 microS x cm(-1), followed by 15-25 microS x cm(-1). From February 2010 to December 2011, precipitation samples were collected on daily basis for ions analysis, as well as pH and K measurement in lab. Detailed comparisons were conducted between the two sets of pH and K, one set from field measurement and the other from lab measurement. The results indicated: (1) The lab measured pH (K) was highly correlated with the field pH (K); however, the lab pH tended to move towards neutral comparing with the corresponding field pH, and the shift range was closely correlated with the field pH and rainfall. The shift range of K from field to lab was highly correlated with the total ion concentration of precipitation. The field K showed evident negative correlation with the field pH with a correlation coefficient of -0.51. (2) When sampling with nylon-polyethylene bags, the statistics showed smaller bias between two sets of pH, with higher correlation coefficient between two sets of K. Furthermore, the lab K also showed evident negative correlation with the lab pH. Comparing with the observations at other alpine sites in central to eastern China, the natural precipitation at Mt. Huang was weaker in acidity and contains lower ion concentration.

Francis E. Walter Dam and Reservoir Project, Water Quality Data Report (RCS-DAEN-CWE-15).

DTIC Science & Technology

1980-12-01

downstream, as well as within, the lake. Analysis of these samples rives an understanding of the effect of the lake on water quality: • . The...regulation, are available for analysis . Water quality data;I (temperature, dissolved oxygen, conductivity, pH, phosphorous, total dissolved solids...depresses the pH following a rain storm. If the source of tre acid water is Fhallow lakes and swamps~lignin and tannin concentrations would be high

Weather Instruments.

ERIC Educational Resources Information Center

Brantley, L. Reed, Sr.; Demanche, Edna L.; Klemm, E. Barbara; Kyselka, Will; Phillips, Edwin A.; Pottenger, Francis M.; Yamamoto, Karen N.; Young, Donald B.

This booklet presents some activities to measure various weather phenomena. Directions for constructing a weather station are included. Instruments including rain gauges, thermometers, wind vanes, wind speed devices, humidity devices, barometers, atmospheric observations, a dustfall jar, sticky-tape can, detection of gases in the air, and pH of…

Desorption of 137Cs from Brachythecium mildeanum moss using acid solutions with pH 4.60-6.50

NASA Astrophysics Data System (ADS)

Čučulović, Ana; Veselinović, Dragan

2015-12-01

The desorption of 137Cs from the moss Brachythecium mildeanum (Schimp.) was performed using the following solutions: H2SO4 ( I), HNO3 ( II), H2SO4 + HNO3 ( III) with pH values of 4.60, 5.15, and 5.75, respectively, as well as distilled water (D) with pH 6.50. After five successive desorptions, each lasting 24 h, 20.5-37.6% 137Cs was desorbed from the moss using these solutions, while 30.7% of the starting content was desorbed using distilled water. The first desorption removed the highest percent of the original content of 137Cs in the moss (11.3-18.4%). This was determined by measuring 137Cs activity. If the current results are compared with those obtained earlier it may be concluded that 137Cs desorption from mosses is not species-dependent. The obtained results indicate the necessity of investigating the influence of acid rain, or rather, of H+ ions, on desorption of other ions from biological systems, i.e., the role of H+ ions in spreading other polluting compounds and thus producing secondary environmental pollution. From the results of this study it follows that acid rain will lead, through H+ ion action, to a similar increasing pollution of fallout waters with other ionic compounds which may not be present in the water before the contact with the plants and thus enable the pollution spreading. In the investigated system, the replacement of H+ ions from acid rains by more dangerous radioactive ions occured, increasing the concentration of the radioactive ions in the water, which demonstrates that the same process takes place in fallout water.

Alleviatory effects of silicon on the foliar micromorphology and anatomy of rice (Oryza sativa L.) seedlings under simulated acid rain

PubMed Central

Ju, Shuming; Wang, Liping; Zhang, Cuiying; Yin, Tingchao; Shao, Siliang

2017-01-01

Silicon (Si) is a macroelement in plants. The biological effects and mitigation mechanisms of silicon under environmental stress have become hot topics. The main objectives of this study were to elucidate the roles of Si in alleviating the effects on the phenotype, micromorphology and anatomy of the leaves of rice seedlings under acid rain stress. The results indicated that the combined or single effects of Si and simulated acid rain (SAR) stress on rice roots depended on the concentration of Si and the intensity of the SAR stress. The combined or single effects of the moderate concentration of Si (2.0 mM) and light SAR (pH 4.0) enhanced the growth of the rice leaves and the development of the mesophyll cells, and the combined effects were stronger than those of the single treatments. The high concentration of Si (4.0 mM) and severe SAR (pH 3.0 or 2.0) exerted deleterious effects. The incorporation of Si (2.0 or 4.0 mM) into SAR at pH values of 3.0 or 2.0 promoted rice leaf growth, decreased necrosis spots, maintained the structure and function of the mesophyll cells, increased the epicuticular wax content and wart-like protuberance (WP) density, and improved the stomatal characteristics of the leaves of rice seedlings more than the SAR only treatments. The alleviatory effects observed with a moderate concentration of Si (2.0 mM) were better than the effects obtained with the high concentration of Si (4.0 mM). The alleviatory effects were due to the enhancement of the mechanical barriers in the leaf epidermis. PMID:29065171

Alleviatory effects of silicon on the foliar micromorphology and anatomy of rice (Oryza sativa L.) seedlings under simulated acid rain.

PubMed

Ju, Shuming; Wang, Liping; Zhang, Cuiying; Yin, Tingchao; Shao, Siliang

2017-01-01

Silicon (Si) is a macroelement in plants. The biological effects and mitigation mechanisms of silicon under environmental stress have become hot topics. The main objectives of this study were to elucidate the roles of Si in alleviating the effects on the phenotype, micromorphology and anatomy of the leaves of rice seedlings under acid rain stress. The results indicated that the combined or single effects of Si and simulated acid rain (SAR) stress on rice roots depended on the concentration of Si and the intensity of the SAR stress. The combined or single effects of the moderate concentration of Si (2.0 mM) and light SAR (pH 4.0) enhanced the growth of the rice leaves and the development of the mesophyll cells, and the combined effects were stronger than those of the single treatments. The high concentration of Si (4.0 mM) and severe SAR (pH 3.0 or 2.0) exerted deleterious effects. The incorporation of Si (2.0 or 4.0 mM) into SAR at pH values of 3.0 or 2.0 promoted rice leaf growth, decreased necrosis spots, maintained the structure and function of the mesophyll cells, increased the epicuticular wax content and wart-like protuberance (WP) density, and improved the stomatal characteristics of the leaves of rice seedlings more than the SAR only treatments. The alleviatory effects observed with a moderate concentration of Si (2.0 mM) were better than the effects obtained with the high concentration of Si (4.0 mM). The alleviatory effects were due to the enhancement of the mechanical barriers in the leaf epidermis.

The Green Pages: Environmental Education Activities K-12.

ERIC Educational Resources Information Center

Clearing, 1990

1990-01-01

Presented are 37 environmental science activities for students in grades K-12. Topics include water pollution, glaciers, protective coloration, shapes in nature, environmental impacts, recycling, creative writing, litter, shapes found in nature, color, rain cycle, waste management, plastics, energy, pH, landfills, runoff, watersheds,…

Characterization and Evaluation of Acid Rain in East Central Florida from 1978 to 1995 and Evaluation of Some Chromatographic/Spectroscopic Results from Leachate Samples from CELSS

NASA Technical Reports Server (NTRS)

Madsen, Brooks C.

1996-01-01

The results of monitoring the chemical composition of rain in east-central Florida have shown that the rain is moderately acid. The measured acidity of rain is less than that observed in other regions of the U. S., however, it does suggest that the level of acidity is substantial. The annual chemical composition of rain at UCF and at KSC has shown moderate variability. Extreme daily and monthly variations are observed, however these variations are not addressed here. The total ionic composition of rain collected at FL99 is greater than that for rain collected at UCF, however this can be accounted for by site proximity to the ocean with the accompanying marine influence. Difference in acidity data collected from the UCF and FL99 sites which are separated by 50 km may be due in part to the differences that have been observed between laboratory and field pH measurements. Trend assessment for precipitation composition requires evaluation of data that covers some minimum time period. In fact, the subdivision of the multi-year UCF record into individual 10 year records as described above can lead to the conclusion that a significant increase, a significant decrease or no trend exists for acidity depending upon the time period chosen for evaluation. Trend evaluation has also been accomplished by linear and nonlinear regression analysis using monthly volume weighted average concentrations and deposition using the UCF data set and some of the Florida NADP data set.

Protective effect of Mn(III)-desferrioxamine B upon oxidative stress caused by ozone and acid rain in the Brazilian soybean cultivar Glycine max "Sambaiba".

PubMed

Esposito, Jéssica Bordotti Nobre; Esposito, Breno Pannia; Azevedo, Ricardo Antunes; Cruz, Luciano Soares; da Silva, Luzimar Campos; de Souza, Silvia Ribeiro

2015-04-01

This study aimed to investigate the effects of the Mn complex (Mn(III)-desferrioxamine B (MnDFB)) on oxidative stress in the Brazilian soybean cultivar Glycine max "Sambaiba" following exposure to ozone and acid rain. We determined the suitable dose of MnDFB to apply to G. max seedlings using a dose-response curve. The highest superoxide dismutase (SOD) activity and Mn content in leaves were found upon the application of 8 μM MnDFB. Thus, G. max seedlings pretreated with 8 μM MnDFB were individually exposed to ozone and acid rain simulated. Pretreatment with MnDFB reduced lipid peroxidation upon ozone exposure and increased SOD activity in leaves; it did not alter the metal content in any part of the plant. Conversely, following acid rain exposure, neither the metal content in leaves nor SOD enzyme activity were directly affected by MnDFB, unlike pH. Our findings demonstrated that exogenous MnDFB application before ozone exposure may modulate the MnSOD, Cu/ZnSOD, and FeSOD activities to combat the ROS excess in the cell. Here, we demonstrated that the applied dose of MnDFB enhances antioxidative defenses in soybean following exposure to acid rain and especially to ozone.

Effect of nanohydroxyapatite on cadmium leaching and environmental risks under simulated acid rain.

PubMed

Zhao, Chenchen; Ren, Shuxia; Zuo, Qingqing; Wang, Shutao; Zhou, Yapeng; Liu, Wei; Liang, Shuxuan

2018-06-15

Cadmium (Cd) contamination in soil is a global environmental pollution issue. Nanohydroxyapatite (NHAP) has been used in soil remediation to immobilize cadmium in contaminated soils. However, the effect of acid rain on the export of cadmium from topsoil and its behavior in deep soil and leachate is unclear. In this study, column experiments and development of parsimonious model were performed to estimate Cd leaching behavior from topsoil and environmental risk of groundwater after 0.5% NHAP remediation. Four leaching events were performed and total Cd, different fractions of Cd determined by sequential extraction procedure and pH were determined for each leaching. The results show that with the export of Cd in topsoil, the total Cd concentration in soil at different depths had the following vertical distributions: 0-5 cm > 5-10 cm > 10-15 cm > 15-20 cm. NHAP treatment increased the soil pH and decreased Cd leaching loss by 56.45% compared to the control, and the results fit the parabolic diffusion model. With sequential extraction it was observed that NHAP application increased the residual fraction of cadmium in soil. After leaching, there was a positive correlation between soil pH and Cd concentration with regards to the exchangeable, reducible, oxidizable and residual Cd fractions. The parabolic diffusion model showed that Cd-contaminated soil with NHAP remediation is harmless to humans after sufficient remediation duration, whereas the resultant concentrations from the CK treatment could be toxic. The results indicate that nanohydroxyapatite could significantly reduce the bioavailability of cadmium and the environmental risk. However, the release of Ca and P from the dissolution of NHAP should be carefully studied as this will impact the mobilization of Cd or colloid Cd, and high leaching of P may result in P-induced eutrophication risk. Copyright © 2018 Elsevier B.V. All rights reserved.

Influence of temporal variations and climatic conditions on the physical and chemical characteristics of dew and rain in South-West Morocco

NASA Astrophysics Data System (ADS)

Lekouch, I.; Kabbachi, B.; Milimouk-Melnytchouk, I.; Muselli, M.; Beysens, D.

2010-07-01

In order to be used as alternative or supplemental sources of water, the physical and physico-chemical characteristics of rain, fog and dew water were investigated at Mirleft in the arid coastal environment of south-west Morocco. A site was instrumented on a terrace with a fog net collector, four 1 m2 inclined (30° ) test dew condenser, together with a weather station providing standard meteorological data. The study was carried out between May 1, 2007 and Avril 30, 2008. Over the one year period were noted 178 dew events (49% yearly occurrence), 31 rain events (8.5 % yearly occurrence) and 7 significant fog events (2 % yearly occurrence). The total quantity of collected water was 48.7 mm (rain), 18.9 mm (dew) and 1.4 mm (fog). Then collecting dew increases almost 40% the water yield although fog contributes to only 3%. A number of physico-chemical and biological parameters were also measured for dew and rain water: pH, electrical conductivity (EC), major anions (HCO3-,Cl-, SO42-,NO3-), major cations (NH4+, Na+, K+, Ca2+, Mg2+). It is found that the mean dew and rain pH are equal to 7.4 and 6.9, respectively and the mean EC are 730 ? S/cm and 316 ? S/cm, respectively, corresponding to large total mineralization. The ratio TA/TC < 1 indicates the alkaline nature of dew and rain water. The analysis of the major ions shows that the concentration of Cl- and Na+ is high compared to that of the other elements. To consider the marine and nonmarine origin of these ions, the fraction of salt coming from sea (SSF) was also calculated. While in dew Cl-, Na+ et Mg2+ are clearly of marine origine, the small SSF value for Ca2+, K+, SO4- et NO3- in dew suggests a considerable contribution of nonmarine origin for these components. In contrast, in rainwater, the values of the No Sea Salt Fraction (NSSF) indicates that only Ca2+ et NO3-are of non marine origin. The dry and transition seasons (spring, summer, fall) correspond to a water more concentrated in elements than during the wet season (winter), in relation to the water yield. The ions concentration agrees with the World Health Organization requirements for potable water. The biological analysis shows harmless vegetal spores and little contamination by animal/human bacteria.

Direct damage to vegetation caused by acid rain and polluted cloud: definition of critical levels for forest trees.

PubMed

Cape, J N

1993-01-01

The concept of critical levels was developed in order to define short-term and long-term average concentrations of gaseous pollutants above which plants may be damaged. Although the usual way in which pollutants in precipitation (wet deposition) influence vegetation is by affecting soil processes, plant foliage exposed to fog and cloud, which often contain much greater concentrations of pollutant ions than rain, may be damaged directly. The idea of a critical level has been extended to define concentrations of pollutants in wet deposition above which direct damage to plants is likely. Concentrations of acidity and sulphate measured in mountain and coastal cloud are summarised. Vegetation at risk of injury is identified as montane forest growing close to the cloud base, where ion concentrations are highest. The direct effects of acidic precipitation on trees are reviewed, based on experimental exposure of plants to simulated acidic rain, fog or mist. Although most experiments have reported results in terms of pH (H(+) concentration), the accompanying anion is important, with sulphate being more damaging than nitrate. Both conifers and broadleaved tree seedlings showing subtle changes in the structural characteristics of leaf surfaces after exposure to mist or rain at or about pH 3.5, or sulphate concentration of 150 micromol litre(-1). Visible lesions on leaf surfaces occur at around pH 3 (500 micromol litre(-1) sulphate), broadleaved species tending to be more sensitive than conifers. Effects on photosynthesis and water relations, and interactions with other stresses (e.g. frost), have usually been observed only for treatments which have also caused visible injury to the leaf surface. Few experiments on the direct effects of polluted cloud have been conducted under field conditions with mature trees, which unlike seedlings in controlled conditions, may suffer a growth reduction in the absence of visible injury. Although leaching of cations (Ca(2+), Mg(2+), K(+)) is stimulated by acidic precipitation, amounts leached are small compared with root uptake, unless soils have been impoverished. This aspect of the potential effects of acidic precipitation is best considered in terms of the long-term critical-load of pollutants to the soil. Given the practical difficulties in monitoring cloud water composition, a method for defining critical levels is proposed, which uses climatological average data to identify the duration and frequency of hill cloud, and combines this information with measured or modelled concentrations of particulate sulphate in the atmosphere, to derive cloud water concentrations as a function of cloud liquid water content. For forests within 100 m of the cloud base the critical levels of particulate sulphate, corresponding to solution concentrations in the range 150-500 micromol litre(-1), are in the range 1-3.3 microg S m(-3). These concentrations are observed over much of central Europe, suggesting that many montane forests are at risk of direct effects of fossil-fuel-derived pollutants in cloud.

[Spatiotemporal variation of soil pH in Guangdong Province of China in past 30 years].

PubMed

Guo, Zhi-Xing; Wang, Jing; Chai, Min; Chen, Ze-Peng; Zhan, Zhen-Shou; Zheng, Wu-Ping; Wei, Xiu-Guo

2011-02-01

Based on the 1980s' soil inventory data and the 2002-2007 soil pH data of Guangdong Province, the spatiotemporal variation of soil pH in the Province in past 30 years was studied. In the study period, the spatial distribution pattern of soil pH in the Province had less change (mainly acidic), except that in Pearl River Delta and parts of Qingyuan and Shaoguan (weak alkaline). The overall variation of soil pH was represented as acidification, with the average pH value changed from 5.70 to 5.44. Among the soil types in the Province, alluvial soil had an increased pH, lateritic red soil, paddy soil, and red soil had a large decrement of pH value, and lime soil was most obvious in the decrease of pH value and its area percentage. The soil acidification was mainly induced by soil characteristics, some natural factors such as acid rain, and human factors such as unreasonable fertilization and urbanization. In addition, industrialization and mining increased the soil pH in some areas.

An Eulerian model for scavenging of pollutants by raindrops

NASA Astrophysics Data System (ADS)

Kumar, Sudarshan

An Eulerian model for simulating the coupled processes of gas-phase depletion and aqueousphase accumulation of the pollutant species during a rain event has been formulated. The model is capable of taking into account any realistic vertical profile of pollutant species concentrations and time-dependent initial aqueous-phase concentrations at the cloud base. The model considers the processes of single species absorption and dissociation in the aqueous phase. The coupled partial differential equations constituting the model are discretized into a set of ordinary differential equations by using the Galerkin method with chapeau functions as the basis functions. These equations are solved to obtain the pollutant concentrations of the gas phase and raindrops as well as the pH of raindrops as a function of time and distance below cloud-base. Simulations are performed for scavenging of gaseous HNO 3, H 2O 2, SO 2, formaldehyde and NH 3. For the case of highly soluble HNO 3 and H 2O 2, raindrops are far from equilibrium with the gas phase and their capacity for absorption of these gases is undiminished even as they reach ground level. The gas-phase concentrations for these species decrease exponentially with time and the washout is determined primarily by the rain intensity and mass-transfer coefficient of the gaseous species to the raindrops. The pollutant species concentrations in raindrops are an almost linear function of the distance below the cloud base. For the simulation conditions considered in this study, the half-life periods of these gases for removal from the atmosphere range from 15 to 40 min. For SO 2 and formaldehyde, the aqueous-phase concentrations approach equilibrium as the drops fall to ground level and the gas-phase concentrations show large gradients in the vertical. Half-life periods for SO 2 range from 1.3 to 13 h depending on the initial raindrop pH and rain intensity. For formaldehyde, the half-life ranges from 19 to 63 min. Solubility of NH 3 is a strong function of the raindrop pH. As NH 3 is absorbed, the raindrop pH increases and NH 3 solubility decreases. For pre-acidified drops (pH = 4.6), ammonia solubility is very high and the drops are far from equilibrium with the gas phase throughout the falling period. The half-life for ammonia ranges from 11 min to over 3 h in our simulations.

CO2 driven weathering vs plume driven weathering as inferred from the groundwater of a persistently degassing basaltic volcano: Mt. Etna

NASA Astrophysics Data System (ADS)

Liotta, Marcello; D'Alessandro, Walter

2016-04-01

At Mt. Etna the presence of a persistent volcanic plume provides large amounts of volcanogenic elements to the bulk deposition along its flanks. The volcanic plume consists of solid particles, acidic droplets and gaseous species. After H2O and CO2, S, Cl and F represent the most abundant volatile elements emitted as gaseous species from the craters. During rain events acidic gases interact rapidly with droplets lowering the pH of rain. This process favors the dissolution and dissociation of the most acidic gases. Under these conditions, the chemical weathering of volcanic rocks and ashes is promoted by the acid rain during its infiltration. Subsequently during groundwater circulation, chemical weathering of volcanic rocks is also driven by the huge amount of deep magmatic carbon dioxide (CO2) coming up through the volcanic edifice and dissolving in the water. These two different weathering steps occur under very different conditions. The former occurs in a highly acidic environment (pH < 4) and the reaction rates depend strongly on the pH, while the latter usually occurs under slightly acidic conditions since the pH has been already neutralized by the interaction with volcanics rocks. The high content of chlorine is mainly derived from interactions between the plume and rainwater, while the total alkalinity can be completely ascribed to the dissociation of carbonic acid (H2CO3) after the hydration of CO2. The relative contributions of plume-derived elements/weathering and CO2-driven weathering has been computed for each element. In addition, the comparison between the chemical compositions of the bulk deposition and of groundwater provides a new understanding about the mobility of volatile elements. Other processes such as ion exchange, iddingsite formation, and carbonate precipitation can also play roles, but only to minor extents. The proposed approach has revealed that the persistent plume strongly affects the chemical composition of groundwater at Mt. Etna and probably also at other volcanoes characterized by huge open-conduit degassing activity.

Nature in the Classroom: Acid Rain.

ERIC Educational Resources Information Center

Doyle, Charles

1982-01-01

As a lesson topic, acid rain is defined, its chemistry given, and its development since the 1950s described. The worldwide effects of acid rain are discussed along with the available technology for controlling the problem. (CM)

Application of four watershed acidification models to Batchawana Watershed, Canada.

PubMed

Booty, W G; Bobba, A G; Lam, D C; Jeffries, D S

1992-01-01

Four watershed acidification models (TMWAM, ETD, ILWAS, and RAINS) are reviewed and a comparison of model performance is presented for a common watershed. The models have been used to simulate the dynamics of water quantity and quality at Batchawana Watershed, Canada, a sub-basin of the Turkey Lakes Watershed. The computed results are compared with observed data for a four-year period (Jan. 1981-Dec. 1984). The models exhibit a significant range in the ability to simulate the daily, monthly and seasonal changes present in the observed data. Monthly watershed outflows and lake chemistry predictions are compared to observed data. pH and ANC are the only two chemical parameters common to all four models. Coefficient of efficiency (E), linear (r) and rank (R) correlation coefficients, and regression slope (s) are used to compare the goodness of fit of the simulated with the observed data. The ILWAS, TMWAM and RAINS models performed very well in predicting the monthly flows, with values of r and R of approximately 0.98. The ETD model also showed strong correlations with linear (r) and rank (R) correlation coefficients of 0.896 and 0.892, respectively. The results of the analyses showed that TMWAM provided the best simulation of pH (E=0.264, r=0.648), which is slightly better than ETD (E=0.240, r=0.549), and much better than ILWAS (E=-2.965, r=0.293), and RAINS (E=-4.004, r=0.473). ETD was found to be superior in predicting ANC (E=0.608, r=0.781) as compared to TMWAM (E=0.340, r=0.598), ILWAS (E=0.275, r=0.442), and RAINS (E=-1.048, r=0.356). The TMWAM model adequately simulated SO4 over the four-year period (E=0.423, r=0.682) but the ETD (E=-0.904, r=0.274), ILWAS (E=-4.314, r=0.488), and RAINS (E=-6.479, r=0.126) models all performed poorer than the benchmark model (mean observed value).

[Effects of exogenous nitric oxide on physiological characteristics of longan (Dimocarpus longana) seedlings under acid rain stress].

PubMed

Liu, Jian-fu; Wang, Ming-yuan; Yang, Chen; Zhu, Ai-jun

2013-08-01

This paper studied the effects of exogenous nitric oxide donor sodium nitroprusside (SNP) on the chlorophyll content, antioxidant enzyme activities, and osmotic regulation substances of longan (Dimocarpus longana 'Fuyan') seedlings under acid rain (pH 3.0) stress. Under the acid rain stress, the seedling leaf superoxide dismutase (SOD), peroxidase (POD) and catalase (CAT) activities and chlorophyll, soluble protein and soluble sugar contents decreased obviously, while the leaf malondialdedyde content had a remarkable increase, suggesting the toxic effect of the acid rain on the seedlings. Exogenous nitric oxide had dual nature on the physiological characteristics of longan seedlings under acid rain stress. Applying 0.1-0.5 mmol x L(-1) of SNP improved the SOD, POD and CAT activities and the chlorophyll, soluble protein and soluble sugar contents significantly, and decreased the malondialdedyde content. Low concentrations SNP reduced the oxidative damage caused by the acid rain stress, and 0.5 mmol x L(-1) of SNP had the best effect. Under the application of 0.5 mmol x L(-1) of SNP, the total chlorophyll, soluble protein, and soluble sugar contents and the SOD, POD and CAT activities increased by 76.0%, 107.0%, 216.1%, 150. 0%, 350.9% and 97.1%, respectively, and the malondialdedyde content decreased by 46.4%. It was suggested that low concentration (0.1-0.5 mmol x L(-1)) SNP could alleviate the toxic effect of acid rain stress on longan seedlings via activating the leaf antioxidant enzyme activities and reducing oxidative stress, while high concentration SNP (1.0 mmol x L(-1)) lowered the mitigation effect.

Biomass Burning:Significant Source of Nitrate and Sulfate for the Andean Rain Forest in Ecuador

NASA Astrophysics Data System (ADS)

Fabian, P.; Rollenbeck, R.; Spichtinger, N.

2009-04-01

Forest fires are significant sources of carbon, sulfur and nitrogen compounds which, along with their photochemically generated reaction products, can be transported over very long distances, even traversing oceans. Chemical analyses of rain and fogwater samples collected on the wet eastern slopes of the Ecuadorian Andes show frequent episodes of high sulfate and nitrate concentration, from which annual deposition rates of about14 kg/ha and 7 kg/ha ,respectively, are derived. These are comparable to those observed in polluted central Europe. Regular rain and fogwater sampling along an altitude profile between 1800 and 3185 m, has been carried out since 2002.The research area located at 30 58'S ,790 5' W is dominated by trade winds from easterly directions. The samples, generally accumulated over 1-week intervals, were analysed for pH, conductivity and major ions(K+,Na+,NH4+,Ca2+,Mg 2+,SO42-,NO3-,PO43-).For all components a strong seasonal variation is observed, while the altitudinal gradient is less pronounced. About 65 % of the weekly samples were significantly loaded with cations and anions, with pH often as low 3.5 to 4.0 and conductivity up to 50 uS/cm. Back trajectories (FLEXTRA) showed that respective air masses had passed over areas of intense biomass burning, sometimes influenced by volcanoes, ocean spray, or even episodic Sahara and/or Namib desert dust interference not discussed here. Enhanced SO4 2-and NO3- were identified, by combining satellite-based fire pixels with back trajectories, as predominantly resulting from biomass burning. For most cases, by using emission inventories, anthropogenic precursor sources other than forest fires play a minor role, thus leaving biomass burning as the main source of nitrate and sulphate in rain and fogwater. Some SO4 2- , about 10 % of the total input, could be identified to originate from active volcanoes, whose plumes were sometimes encountered by the respective back trajectories. While volcanic, oceanic and desert sources are natural, large scale biomass burning is an anthropogenic source which adds about 7 kg/ha of NO3- and 14 kg/ha of SO4 2- per year to the forest which has developed on poor acidic soil conditions. Controlled fertilizing experiments within an interdisciplinary research consortium are presently carried out to investigate the impact of this disturbance on the forest ecosystem and its biodiversity.

Pollen selection under acid rain stress

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Y.

To investigate whether acid rain stress induces pollen selection in nature, three different approaches were used, based on the assumption that the response of pollen grains to acid rain is controlled by an acid sensitive gene product. Germination of pollen from homozygous and heterozygous individuals under acid rain stress was examined to detect any differences in rate of germination between populations of homogeneous and heterogeneous pollen grains. In vitro and in vivo bulked segregant analysis using RAPDs was used to search for differences in DNA constitution between the survivors of acid rain stressed and non-acid rain stressed pollen populations inmore » vitro and between the progenies of acid rain stressed and non-acid rain stressed populations during pollination, respectively. No evidence for the pollen selection under acid rain stress was obtained in any of the test systems. Inhibition of protein synthesis using cycloheximide led to significant reduction of tube elongation at 4 hr and had no effect on pollen germination at any time interval tested. Total proteins extracted from control and acid rain stressed pollen grain populations exhibited no differences. The reduction of corn pollen germination in vitro under acid rain stress was mainly due to pollen rupture. The present data indicates the reduction of pollen germination and tube growth under acid rain stress may be a physiological response rather than a genetic response. A simple, nontoxic, and effective method to separate germinated from ungerminated pollen grains has been developed using pollen from corn (Zea mays, L. cv. Pioneer 3747). The separated germinated pollen grains retained viability and continued tube growth when placed in culture medium.« less

Characterization of Rain Attenuation and Depolarization at W/V Bands

DTIC Science & Technology

2015-07-30

AIR FORCE BASE , NM 87117-5776 DTIC COPY NOTICE AND SIGNATURE PAGE Using Government drawings, specifications, or other data included in this...WITH ASSIGNED DISTRIBUTION STATEMENT. //SIGNED// //SIGNED// STEVEN A. LANE PAUL HAUSGEN, Ph.D. Program Manager Technical Advisor, Space Based Advanced... Stations ........................................................................................ 11  Figure 3. Transmitter Block Diagram

The influence of SO4 and NO3 to the acidity (pH) of rainwater using minimum variance quadratic unbiased estimation (MIVQUE) and maximum likelihood methods

NASA Astrophysics Data System (ADS)

Dilla, Shintia Ulfa; Andriyana, Yudhie; Sudartianto

2017-03-01

Acid rain causes many bad effects in life. It is formed by two strong acids, sulfuric acid (H2SO4) and nitric acid (HNO3), where sulfuric acid is derived from SO2 and nitric acid from NOx {x=1,2}. The purpose of the research is to find out the influence of So4 and NO3 levels contained in the rain to the acidity (pH) of rainwater. The data are incomplete panel data with two-way error component model. The panel data is a collection of some of the observations that observed from time to time. It is said incomplete if each individual has a different amount of observation. The model used in this research is in the form of random effects model (REM). Minimum variance quadratic unbiased estimation (MIVQUE) is used to estimate the variance error components, while maximum likelihood estimation is used to estimate the parameters. As a result, we obtain the following model: Ŷ* = 0.41276446 - 0.00107302X1 + 0.00215470X2.

TECHNOLOGICAL OPTIONS FOR ACID RAIN CONTROL

EPA Science Inventory

The paper discusses technological options for acid rain control. Compliance with Title IV of the Clean Air Act Amendments of 1990 will require careful scrutiny of a number of issues before selecting control options to reduce sulfur dioxide (SO2) and nitrogen oxide (NOx) emissions...

An Open-Source Arduino-based Controller for Mechanical Rain Simulators

NASA Astrophysics Data System (ADS)

Cantilina, K. K.

2017-12-01

Many commercial rain simulators currently used in hydrology rely on inflexible and outdated controller designs. These analog controllers typically only allow a handful of discrete parameter options, and do not support internal timing functions or continuously-changing parameters. A desire for finer control of rain simulation events necessitated the design and construction of a microcontroller-based controller, using widely available off-the-shelf components. A menu driven interface allows users to fine-tune simulation parameters without the need for training or experience with microcontrollers, and the accessibility of the Arduino IDE allows users with a minimum of programming and hardware experience to modify the controller program to suit the needs of individual experiments.

TECHNOLOGICAL OPTIONS FOR ACID RAIN CONTROL

EPA Science Inventory

Discussed are acid rain control options available to the electric utility industry. They include coal switching, flue gas desulfurization, and such emerging lower cost technologies as Limestone Injection Multistage Burners (LIMB) and Advanced Silicate (ADVACATE), both developed ...

[Effects of simulating acid rain on photosynthesis and chlorophyll fluorescence parameters of Quercus glauca Quercus glauca].

PubMed

Wang, Sai; Yi, Li-Ta; Yu, Shu-Quan; Zhang, Chao; Shi, Jing-Jing

2014-08-01

At three levels of simulated acid rainfall intensities with pH values of 2.5 (severe), 40 (medium) and 5.6 (light) respectively, the responses of chlorophyll fluorescence and photosynthetic parameters of Quercus glauca seedlings were studied in three acid rainfall treatments, i. e. only the aboveground of seedlings exposed to acid rain (T1), both of the seedlings and soil exposed to acid rain (T2), only the soil exposed to acid rain (T3) compared with blank control (CK). Under the severe acid rainfall, T1 significantly inhibited chlorophyll synthesis, and thus reduced the primary photochemical efficiency of PS II ( F(v)/F(m)), potential activity of PS II (F(v)/F(o)) , apparent quantum (Y), net photosynthetic rate (P(n)), and transpiration rate (T(r)), but increased the light compensation point (LCP) and dark respiration rate (R(d)) of Q. glauca seedlings. T2 inhibited, but T3 played a little enhancement on the aforementioned parameters of Q. glauca seedlings. Under the conditions of medium and light acid rainfall intensities, the above parameters in the three treatments were higher than that of CK, except with lower R(d). The chlorophyll fluorescence and photosynthetic parameters showed a similar tendency in the three treatments, i. e. T2>T3 >T1. It indicated that T1 had the strongest inhibition on seedlings in condition of the severe acid rainfall, while T2 had the most dramatic facilitating effect on seedlings under the medium and light acid rainfall. Intensity of acid rainfall had significant influences on SPAD, F(v)/F(m), F(v)/F(o), Y, P(n), T(r), and maximum photosynthetic rate (A(max)), whereas treatments of acid rainfall affected SPAD, F(v)/F(m), Y, P(n), T(r), A(max) and light saturation point (LSP). The interaction of acid rainfall intensities and treatments played significant effects on SPAD, F(v)/F(m), Y, P(n) and A(max).

Fade Mitigation Techniques at Ka-Band

NASA Technical Reports Server (NTRS)

Dissanayake, Asoka (Editor)

1996-01-01

Rain fading is the dominant propagation impairment affecting Ka-band satellite links and rain fade mitigation is a key element in the design of Ka-band satellite networks. Some of the common fade mitigation techniques include: power control, diversity, adaptive coding, and resource sharing. The Advanced Communications Technology Satellite (ACTS) provides an excellent opportunity to develop and test Ka-band rain impairment amelioration techniques. Up-link power control and diversity are discussed in this paper.

Rain Fade Compensation for Ka-Band Communications Satellites

NASA Technical Reports Server (NTRS)

Mitchell, W. Carl; Nguyen, Lan; Dissanayake, Asoka; Markey, Brian; Le, Anh

1997-01-01

This report provides a review and evaluation of rain fade measurement and compensation techniques for Ka-band satellite systems. This report includes a description of and cost estimates for performing three rain fade measurement and compensation experiments. The first experiment deals with rain fade measurement techniques while the second one covers the rain fade compensation techniques. The third experiment addresses a feedback flow control technique for the ABR service (for ATM-based traffic). The following conclusions were observed in this report; a sufficient system signal margin should be allocated for all carriers in a network, that is a fixed clear-sky margin should be typically in the range of 4-5 dB and should be more like 15 dB in the up link for moderate and heavy rain zones; to obtain a higher system margin it is desirable to combine the uplink power control technique with the technique that implements the source information rate and FEC code rate changes resulting in a 4-5 dB increase in the dynamic part of the system margin. The experiments would assess the feasibility of the fade measurements and compensation techniques, and ABR feedback control technique.

Use of NEXRAD radar-based observations for quality control of in-situ rain gauge measurements

NASA Astrophysics Data System (ADS)

Nelson, B. R.; Prat, O.; Leeper, R.

2017-12-01

Rain gauge quality control is an often over looked important step in the archive of historical precipitation estimates. We investigate the possibilities that exist for using ground based radar networks for quality control of rain gauge measurements. This process includes the point to pixel comparisons of the rain gauge measurements with NEXRAD observations. There are two NEXRAD based data sets used for reference; the NCEP stage IV and the NWS MRMS gridded data sets. The NCEP stage IV data set is available at 4km hourly for the period 2002-present and includes the radar-gauge bias adjusted precipitation estimate. The NWS MRMS data set includes several different variables such as reflectivity, radar-only estimates, precipitation flag, and radar-gauge bias adjusted precipitation estimates. The latter product provides for much more information to apply quality control such as identification of precipitation type, identification of storm type and Z-R relation. In addition, some of the variables are available at 5-minute scale. The rain gauge networks that are investigated are the Climate Reference Network (CRN), the Fischer-Porter Hourly Precipitation Database (HPD), and the Hydrometeorological Automated Data System (HADS). The CRN network is available at the 5-minute scale, the HPD network is available at the 15-minute and hourly scale, and HADS is available at the hourly scale. The varying scales present challenges for comparisons. However given the higher resolution radar-based products we identify an optimal combination of rain gauge observations that can be compared to the radar-based information. The quality control process focuses on identifying faulty gauges in direct comparison while a deeper investigation focuses on event-based differences from light rain to extreme storms.

Capping hazardous red mud using acidic soil with an embedded layer of zeolite for plant growth.

PubMed

Ma, Yingqun; Si, Chunhua; Lin, Chuxia

2014-01-01

A nearly three-year microcosm experiment was conducted to test the effectiveness of capping red mud using acidic soil with an embedded layer of zeolite in sustaining the growth of a grass species. This 'sandwich-structured' design allowed self-sustaining growth of the plants under rain-fed conditions no matter whether the underlying red mud was neutralized or not. During the initial stage, the plants grew better when the red mud was not neutralized with MgCl2 probably due to pH rise in the root zone. Neutralization of red mud led to salinization and pH decrease in the root zone. However, the difference in plant growth performance between these scenarios became less remarkable over time due to gradual improvement of soil conditions in the neutralized scenarios. Continuous leaching of soluble salts and alkali by rainwater extended the root zone to the red mud layer. As a result of vegetative production, soil organic matter rapidly accumulated. This, combined with increase in pH and decrease in salinity, markedly facilitated microbial activities and consequently improved the supply of nutrients. This study provides abasis for field-scale experimental design that will have implications for effectively establishing vegetative cover in red mud disposal sites to control dust hazards.

Economic, Environmental, and Coal Market Impacts of Sulfur Dioxide Emissions Trading under Alternative Acid Rain Control Proposals (1989)

EPA Pesticide Factsheets

This report examines the ramifications of diferent levels of emissions trading in the context of tro representative electric utility sulfur dioxide emisson reduction proposals designed to control acid rain, and in the absence of any new control program.

Unraveling the Role of Sulfur Compounds in Acid Rain Formation: Experiments on a Wetted Glass pH Electrode

ERIC Educational Resources Information Center

Lopes, Fernando S.; Coelho, Lucia H. G.; Gutz, Ivano G. R.; Vitz, Ed

2010-01-01

Vast quantities, on the order of megatons, of pollutants are emitted monthly to the atmosphere both by natural and anthropogenic sources. The evaluation of rainwater composition has great importance in understanding the atmospheric chemical composition, as water drops scavenge particles and soluble atmospheric pollutants. Most students are aware…

Acid precipitation and reproductive success of Ambystoma salamanders

Treesearch

F. Harvey Pough; Richard E. Wilson

1976-01-01

The two species of mole salamander that occur in the Ithaca, New York, region (Ambystoma maculatum and A. jeffersonianum) breed in temporary ponds that are formed by accumulation of melted snow and spring rains. Water in many of these pools during the breeding season is acid; pH values as low as 3.5 have been measured. In...

Acid rain controls through the back door

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The paper briefly discusses the regulatory policy changes being proposed for acid rain control. Court rulings requiring the EPA to order reductions of sulfur dioxide emissions from power plants are described. Costs to utilities, and ultimately consumers, are also considered.

A statistical rain attenuation prediction model with application to the advanced communication technology satellite project. Part 2: Theoretical development of a dynamic model and application to rain fade durations and tolerable control delays for fade countermeasures

NASA Technical Reports Server (NTRS)

Manning, Robert M.

1987-01-01

A dynamic rain attenuation prediction model is developed for use in obtaining the temporal characteristics, on time scales of minutes or hours, of satellite communication link availability. Analagous to the associated static rain attenuation model, which yields yearly attenuation predictions, this dynamic model is applicable at any location in the world that is characterized by the static rain attenuation statistics peculiar to the geometry of the satellite link and the rain statistics of the location. Such statistics are calculated by employing the formalism of Part I of this report. In fact, the dynamic model presented here is an extension of the static model and reduces to the static model in the appropriate limit. By assuming that rain attenuation is dynamically described by a first-order stochastic differential equation in time and that this random attenuation process is a Markov process, an expression for the associated transition probability is obtained by solving the related forward Kolmogorov equation. This transition probability is then used to obtain such temporal rain attenuation statistics as attenuation durations and allowable attenuation margins versus control system delay.

Fiscal Year 2013 Net Zero Energy-Water-Waste Portfolio for Fort Leonard Wood

DTIC Science & Technology

2014-12-01

rain sensor /evapotran- spiration central control system. Witnesses said they have seen the system ERDC/CERL SR-14-11 77 in use during rains so it...is possible the system settings and sensors need to be reassessed. Building 6100 The building is an administrative trainee company headquarters...CERL SR-14-11 108 ensure that each watering event is optimally performed during the day. A centrally controlled system with rain sensors should also

Evaluation of TRMM Ground-Validation Radar-Rain Errors Using Rain Gauge Measurements

NASA Technical Reports Server (NTRS)

Wang, Jianxin; Wolff, David B.

2009-01-01

Ground-validation (GV) radar-rain products are often utilized for validation of the Tropical Rainfall Measuring Mission (TRMM) spaced-based rain estimates, and hence, quantitative evaluation of the GV radar-rain product error characteristics is vital. This study uses quality-controlled gauge data to compare with TRMM GV radar rain rates in an effort to provide such error characteristics. The results show that significant differences of concurrent radar-gauge rain rates exist at various time scales ranging from 5 min to 1 day, despite lower overall long-term bias. However, the differences between the radar area-averaged rain rates and gauge point rain rates cannot be explained as due to radar error only. The error variance separation method is adapted to partition the variance of radar-gauge differences into the gauge area-point error variance and radar rain estimation error variance. The results provide relatively reliable quantitative uncertainty evaluation of TRMM GV radar rain estimates at various times scales, and are helpful to better understand the differences between measured radar and gauge rain rates. It is envisaged that this study will contribute to better utilization of GV radar rain products to validate versatile spaced-based rain estimates from TRMM, as well as the proposed Global Precipitation Measurement, and other satellites.

Effect of irrigation with treated wastewater on soil chemical properties and infiltration rate.

PubMed

Bedbabis, Saida; Ben Rouina, Béchir; Boukhris, Makki; Ferrara, Giuseppe

2014-01-15

In Tunisia, water scarcity is one of the major constraints for agricultural activities. The reuse of treated wastewater (TWW) in agriculture can be a sustainable solution to face water scarcity. The research was conducted for a period of four years in an olive orchard planted on a sandy soil and subjected to irrigation treatments: a) rain-fed conditions (RF), as control b) well water (WW) and c) treated wastewater (TWW). In WW and TWW treatments, an annual amount of 5000 m(3) ha(-1) of water was supplied to the orchard. Soil samples were collected at the beginning of the study and after four years for each treatment. The main soil properties such as electrical conductivity (EC), pH, soluble cations, chloride (Cl(-)), sodium adsorption ratio (SAR), organic matter (OM) as well as the infiltration rate were investigated. After four years, either a significant decrease of pH and infiltration rate or a significant increase of OM, SAR and EC were observed in the soil subjected to treated wastewater treatment. Copyright © 2013. Published by Elsevier Ltd.

Industrial ecotoxicology "acid rain".

PubMed

Astolfi, E; Gotelli, C; Higa, J

1986-01-01

The acid rain phenomenon was studied in the province of Cordoba, Argentina. This study, based on a previously outlined framework, determined the anthropogenic origin of the low pH due to the presence of industrial hydrochloric acid wastage. This industrial ecotoxicological phenomenon seriously affected the forest wealth, causing a great defoliation of trees and shrubs, with a lower effect on crops. A survey on its effects on human beings has not been carried out, but considering the corrosion caused to different metals and its denouncing biocide effect on plants and animals, we should expect to find some kind of harm to the health of the workers involved or others engaged in farming, and even to those who are far away from the polluting agent.

A Unified Statistical Rain-Attenuation Model for Communication Link Fade Predictions and Optimal Stochastic Fade Control Design Using a Location-Dependent Rain-Statistic Database

NASA Technical Reports Server (NTRS)

Manning, Robert M.

1990-01-01

A static and dynamic rain-attenuation model is presented which describes the statistics of attenuation on an arbitrarily specified satellite link for any location for which there are long-term rainfall statistics. The model may be used in the design of the optimal stochastic control algorithms to mitigate the effects of attenuation and maintain link reliability. A rain-statistics data base is compiled, which makes it possible to apply the model to any location in the continental U.S. with a resolution of 0-5 degrees in latitude and longitude. The model predictions are compared with experimental observations, showing good agreement.

Feasibility of conducting wetfall chemistry investigations around the Bowen Power Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, N.C.J.; Patrinos, A.A.N.

1979-10-01

The feasibility of expanding the Meteorological Effects of Thermal Energy Releases - Oak Ridge National Laboratory (METER-ORNL) research at Bower Power Plant, a coal-fired power plant in northwest Georgia, to include wetfall chemistry is evaluated using results of similar studies around other power plants, several atmospheric washout models, analysis of spatial variability in precipitation, and field logistical considerations. An optimal wetfall chemistry network design is proposed, incorporating the inner portion of the existing rain-gauge network and augmented by additional sites to ensure adequate coverage of probable target areas. The predicted sulfate production rate differs by about four orders of magnitudemore » among the models reviewed with a pH of 3. No model can claim superiority over any other model without substantive data verification. The spatial uniformity in rain amount is evaluated using four storms that occurred at the METER-ORNL network. Values of spatial variability ranged from 8 to 31% and decreased as the mean rainfall increased. The field study of wetfall chemistry will require a minimum of 5 persons to operate the approximately 50 collectors covering an area of 740 km/sup 2/. Preliminary wetfall-only samples collected on an event basis showed lower pH and higher electrical conductivity of precipitation collected about 5 km downwind of the power plant relative to samples collected upwind. Wetfall samples collected on a weekly basis using automatic samplers, however, showed variable results, with no consistent pattern. This suggests the need for event sampling to minimize variable rain volume and multiple-source effects often associated with weekly samples.« less

Impact of volcanic plume emissions on rain water chemistry during the January 2010 Nyamuragira eruptive event: implications for essential potable water resources.

PubMed

Cuoco, Emilio; Tedesco, Dario; Poreda, Robert J; Williams, Jeremy C; De Francesco, Stefano; Balagizi, Charles; Darrah, Thomas H

2013-01-15

On January 2, 2010 the Nyamuragira volcano erupted lava fountains extending up to 300 m vertically along an ~1.5 km segment of its southern flank cascading ash and gas on nearby villages and cities along the western side of the rift valley. Because rain water is the only available potable water resource within this region, volcanic impacts on drinking water constitutes a major potential hazard to public health within the region. During the 2010 eruption, concerns were expressed by local inhabitants about water quality and feelings of physical discomfort (e.g. nausea, bloating, indigestion, etc.) after consuming rain water collected after the eruption began. We present the elemental and ionic chemistry of drinking water samples collected within the region on the third day of the eruption (January 5, 2010). We identify a significant impact on water quality associated with the eruption including lower pH (i.e. acidification) and increases in acidic halogens (e.g. F(-) and Cl(-)), major ions (e.g. SO(4)(2-), NH(4)(+), Na(+), Ca(2+)), potentially toxic metals (e.g. Al(3+), Mn(2+), Cd(2+), Pb(2+), Hf(4+)), and particulate load. In many cases, the water's composition significantly exceeds World Health Organization (WHO) drinking water standards. The degree of pollution depends upon: (1) ash plume direction and (2) ash plume density. The potential negative health impacts are a function of the water's pH, which regulates the elements and their chemical form that are released into drinking water. Copyright © 2012 Elsevier B.V. All rights reserved.

Alkaline precipitation in Bahia Blanca, Argentina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Piccolo, M.C.; Perillo, G.M.E.; Varela, P.

1988-02-01

The spatial, meteorological, and seasonal factors associated with precipitation pH in Bahia Blanca and its surroundings are presented. From April 1984 to April 1985, 85 rain events were studied from 12 sites that represent significant land-use sectors of the city. Mean pH for all sites ranged from 6.5 to 7.2. The area is characterized by alkaline precipitation since most stations reported maximum values in excess of 7.6. The highest values of pH were observed under the influence of continental air masses, which have traveled over the pampas soil, thus introducing large amounts of alkaline cations. The lowest pH values weremore » obtained during the winter season when marine advection introduces high concentrations of spray. Stations located close to the estuary and the industrial park present the larger effect of sea spray but also of the incidence of an incipient atmospheric contamination.« less

Flying in the rain: hovering performance of Anna's hummingbirds under varied precipitation.

PubMed

Ortega-Jimenez, Victor Manuel; Dudley, Robert

2012-10-07

Flight in rain represents a greater challenge for smaller animals because the relative effects of water loading and drop impact are greater at reduced scales given the increased ratios of surface area to mass. Nevertheless, it is well known that small volant taxa such as hummingbirds can continue foraging even in extreme precipitation. Here, we evaluated the effect of four rain intensities (i.e. zero, light, moderate and heavy) on the hovering performance of Anna's hummingbirds (Calypte anna) under laboratory conditions. Light-to-moderate rain had only a marginal effect on flight kinematics; wingbeat frequency of individuals in moderate rain was reduced by 7 per cent relative to control conditions. By contrast, birds hovering in heavy rain adopted more horizontal body and tail positions, and also increased wingbeat frequency substantially, while reducing stroke amplitude when compared with control conditions. The ratio between peak forces produced by single drops on a wing and on a solid surface suggests that feathers can absorb associated impact forces by up to approximately 50 per cent. Remarkably, hummingbirds hovered well even under heavy precipitation (i.e. 270 mm h(-1)) with no apparent loss of control, although mechanical power output assuming perfect and zero storage of elastic energy was estimated to be about 9 and 57 per cent higher, respectively, compared with normal hovering.

Aggregation Kinetics of Diesel Soot Nanoparticles in Wet Environments.

PubMed

Chen, Chengyu; Huang, Weilin

2017-02-21

Soot produced during incomplete combustion consists mainly of carbonaceous nanoparticles (NPs) with severe adverse environmental and health effects, and its environmental fate and transport are largely controlled by aggregation. In this study, we examined the aggregation behavior for diesel soot NPs under aqueous condition in an effort to elucidate the fundamental processes that govern soot particle-particle interactions in wet environments such as rain droplets or surface aquatic systems. The influence of electrolytes and aqueous pH on colloidal stability of these NPs was investigated by measuring their aggregation kinetics in different aqueous solution chemistries. The results showed that the NPs had negatively charged surfaces and exhibited both reaction- and diffusion-limited aggregation regimes with rates depended upon solution chemistry. The aggregation kinetics data were in good agreement with the classic Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. The critical coagulation concentrations (CCC) were quantified and the Hamaker constant was derived for the soot (1.4 × 10 -20 J) using the colloidal chemistry approach. The study indicated that, depending upon local aqueous chemistry, single soot NPs could remain stable against self-aggregation in typical freshwater environments and in neutral cloud droplets but are likely to aggregate under salty (e.g., estuaries) or acidic (e.g., acid rain droplets) aquatic conditions or both.

Moving Stormwater Infrastructure from Real-time Control to Smart Systems

NASA Astrophysics Data System (ADS)

Wadzuk, B.; Bryant, S.; Lewellyn, C.; Zaremba, G.; Traver, R.

2017-12-01

Urban areas, especially combined sewer communities, are using green infrastructure (GI) systems (e.g. rain gardens, green roofs) to mitigate stormwater runoff volume, rate, and quality issues. Most municipal guidance and regulation limits these systems to static, passive designs that neither fully utilize the active hydrology of a GI system during and after a rainfall event, nor enable dynamic operational control. Real-time control (RTC) applied to GI is emerging, and under ideal model conditions has shown improved performance (i.e., greater volumes managed while minimizing downstream impact). There are a few RTC pilot field projects with promising results, such as on a cistern - green roof system there were only 30 overflow events out of 126 rain events and at a rain garden - cistern system only 1 of 81 events resulted in overflow. However, RTC does not get to a fully dynamic system as the initiation and consequent action is preset and static. In stormwater RTC systems, the initiation is typically a rain forecast or a sensor reading. At a rain garden - cistern system, a cistern that fills when raining is hard set to pump water to the rain garden 24 hours after the predicted rain ends. There have been instances where there is rain occurring or only a minimal amount of dry time for the rain garden to reestablish capacity for the pumped stored water. There is also no mechanism to automatically change the pump initiation time based on season or ambient conditions. A cistern - green roof system that uses stored water in an upstream cistern for green roof irrigation is initiated on a set soil moisture reading or a set irrigation volume daily. The soil moisture reading was rarely reached, so irrigation was often not initiated and the set daily irrigation volume did not vary over season. Moving from RTC to a smart system uses longer term and/or historical data to inform decisions beyond what a short-term forecast or real-time sensor can provide to give more context and flexibility in the initiation - consequent action logic. The use of the Standardized Precipitation Evapotranspiration Index as a back-cast and forecast tool to calculate an appropriate irrigation volume based on what rainfall is pending and whether the system is in drought state is used and discussed to move the GI systems into smart control.

The carbon cycle and biogeochemical dynamics in lake sediments

USGS Publications Warehouse

Dean, W.E.

1999-01-01

The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.

Oxidation of Fe(II) in rainwater.

PubMed

Willey, J D; Whitehead, R F; Kieber, R J; Hardison, D R

2005-04-15

Photochemically produced Fe(II) is oxidized within hours under environmentally realistic conditions in rainwater. The diurnal variation between photochemical production and reoxidation of Fe(II) observed in our laboratory accurately mimics the behavior of ferrous iron observed in field studies where the highest concentrations of dissolved Fe(ll) occur in afternoon rain during the period of maximum sunlight intensity followed by gradually decreasing concentrations eventually returning to early morning pre-light values. The experimental work presented here, along with the results of kinetics studies done by others, suggests thatthe primary process responsible for the decline in photochemically produced Fe(II) concentrations is oxidation by hydrogen peroxide. This reaction is first order with respect to both the concentrations of Fe(II) and H2O2. The second-order rate constant determined for six different authentic rain samples varied over an order of magnitude and was always less than or equal to the rate constant determined for this reaction in simple acidic solutions. Oxidation of photochemically produced ferrous iron by other oxidants including molecular oxygen, ozone, hydroxyl radical, hydroperoxyl/superoxide radical, and hexavalent chromium were found to be insignificant under the conditions present in rainwater. This study shows that Fe(II) occurs as at least two different chemical species in rain; photochemically produced Fe(II) that is oxidized over time periods of hours, and a background Fe(II) that is protected against oxidation, perhaps by organic complexation, and is stable against oxidation for days. Because the rate of oxidation of photochemically produced Fe(II) does not increase with increasing rainwater pH, the speciation of this more labile form of Fe(II) is also not controlled by simple hydrolysis reactions.

Using Economic Incentives to Manage Stormwater Runoff in ...

EPA Pesticide Factsheets

Communities nationwide are facing increased responsibility for controlling stormwater runoff, and, subsequently, rising costs of stormwater management. In this report we describe and test a methodology that can be used by communities to focus limited budgets on the most efficient and ecologically-effective installation of stormwater management practices. The overall project has two primary objectives: (1) to test the use of an auction to cost-effectively allocate stormwater management practices among landowners, and (2) to determine the effectiveness of the resulting implementation in terms of hydrological, water quality, and ecological measures. Here, we describe the theories, methods, and criteria used to distribute rain gardens and rain barrels to homeowners in a small, midwestern watershed. The first round of the reverse auction in 2007 resulted in 50 rain gardens and 100 rain barrels installed at 67 of the approximately 350 residential properties in the experimental watershed. In 2008, the auction was repeated and we accepted bids for an additional 35 rain gardens and 74 rain barrels. Stormwater management practices were distributed relatively evenly throughout the watershed and are expected to result in significant improvements in stream quality. We describe our monitoring approach, including 1) parcel-scale hydrology and water quality monitoring of selected rain gardens, and 2) stream monitoring following before-after-control-impact approach for as

KSC-02pd0996

NASA Image and Video Library

2002-06-18

KENNEDY SPACE CENTER, FLA. - Dark, rain-filled clouds blanket the sky over the Vehicle Assembly Building and Launch Control Center, bringing thunder and heavy rain to the area. This type of weather convinced flight control managers to wave off the two scheduled landing attempts at KSC for Endeavour, returning from mission STS-111

Effects of acid rain on plant microbial associations in California. Research report (final)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, D.; Paul, E.A.

1984-04-13

The effects of simulated acid rain of pH 5.6 to 3.0, with ionic composition similar to that found in California, on Trifolium repens, Lupinus densiflorus and L. benthamii grown in two soils were tested. The interactions of treatment intensity, soil type, phosphorus uptake and mycorrhizal influences on growth, carbon fixation and allocation and nitrogen fixation were determined. Acidic treatments generally decreased plant growth, nodulation and nitrogenase activity. The exposure of plants to a large number of simulated rainfall conditions of shorter duration did not result in the negative growth effects. Plants adequately supplied with P, either as fertilizer or bymore » mycorrhizal fungi, were much more resistant to conditions caused by acidic precipitation and in some cases growth increases were found.« less

Flying in the rain: hovering performance of Anna's hummingbirds under varied precipitation

PubMed Central

Ortega-Jimenez, Victor Manuel; Dudley, Robert

2012-01-01

Flight in rain represents a greater challenge for smaller animals because the relative effects of water loading and drop impact are greater at reduced scales given the increased ratios of surface area to mass. Nevertheless, it is well known that small volant taxa such as hummingbirds can continue foraging even in extreme precipitation. Here, we evaluated the effect of four rain intensities (i.e. zero, light, moderate and heavy) on the hovering performance of Anna's hummingbirds (Calypte anna) under laboratory conditions. Light-to-moderate rain had only a marginal effect on flight kinematics; wingbeat frequency of individuals in moderate rain was reduced by 7 per cent relative to control conditions. By contrast, birds hovering in heavy rain adopted more horizontal body and tail positions, and also increased wingbeat frequency substantially, while reducing stroke amplitude when compared with control conditions. The ratio between peak forces produced by single drops on a wing and on a solid surface suggests that feathers can absorb associated impact forces by up to approximately 50 per cent. Remarkably, hummingbirds hovered well even under heavy precipitation (i.e. 270 mm h−1) with no apparent loss of control, although mechanical power output assuming perfect and zero storage of elastic energy was estimated to be about 9 and 57 per cent higher, respectively, compared with normal hovering. PMID:22810431

Calcium affecting protein expression in longan under simulated acid rain stress.

PubMed

Pan, Tengfei; Li, Yongyu; Ma, Cuilan; Qiu, Dongliang

2015-08-01

Longan (Dimocarpus longana Lour. cv. Wulongling) of uniform one-aged seedlings grown in pots were selected to study specific proteins expressed in leaves under simulated acid rain (SiAR) stress and exogenous Ca(2+) regulation. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) results showed that there was a protein band specifically expressed under SiAR of pH 2.5 stress for 15 days with its molecular weight of about 23 kD. A 17 kD protein band specifically expressed after SiAR stress 5 days. Compared with pH 2.5, the pH 3.5 of SiAR made a less influence to protein expression. Two-dimensional electrophoresis (2-DE) results showed that six new specific proteins including C4 (20.2 kD pI 6.0), F (24 kD pI 6.35), B3 (22.3 kD pI 6.35), B4 (23.5 kD pI 6.5), C5 (21.8 kD pI 5.6), and C6 (20.2 kD pI 5.6) specifically expressed. C4 always expressed during SiAR stress. F expressed under the stress of pH 2.5 for 15 days and expressed in all pH SiAR stress for 20 days. The expression of proteins including B3, C5, and C6 was related to pH value and stress intensity of SiAR. The expression of B4 resulted from synergistic effects of SiAR and Ca. The expression of G1 (Mr 19.3 kD, pI 4.5), G2 (Mr 17.8 kD, pI 4.65), G3 (Mr 16.6 kD, pI 4.6), and G4 (Mr 14.7 kD, pI 4.4) enhanced under the treatment of 5 mM ethylene glycol tetraacetic acid (EGTA) and 2 mM chlorpromazine (CPZ). These proteins showed antagonistic effects and might be relative to the Ca-calmodulin (Ca-CaM) system of longan in response to SiAR stress.

Rain Basin Design Implications for Soil Microbial Activity and N-mineralization in a Semi-arid Environment

NASA Astrophysics Data System (ADS)

Stern, C.; Pavao-Zuckerman, M.

2014-12-01

Rain basins have been an increasingly popular Green Infrastructure (GI) solution to the redistribution of water flow caused by urbanization. This study was conducted to examine how different approaches to basin design, specifically mulching (gravel vs. compost and gravel), influence the water availability of rain basins and the effects this has on the soil microbial activity of the basins. Soil microbes are a driving force of biogeochemical process and may impact the carbon and nitrogen dynamics of rain basin GI. In this study we sampled 12 different residential-scale rain basins, differing in design established at Biosphere 2, Arizona in 2013. Soil samples and measurements were collected before and after the onset of the monsoon season in 2014 to determine how the design of basins mediates the transition from dry to wet conditions. Soil abiotic factors were measured, such as moisture content, soil organic matter (SOM) content, texture and pH, and were related to the microbial biomass size within the basins. Field and lab potential N-mineralization and soil respiration were measured to determine how basin design influences microbial activity and N dynamics. We found that pre-monsoon basins with compost had higher moisture contents and that there was a positive correlation between the moisture content and the soil microbial biomass size of the basins. Pre-monsoon data also suggests that N-mineralization rates for basins with compost were higher than those with only gravel. These design influences on basin-scale biogeochemical dynamics and nitrogen retention may have important implications for urban biogeochemistry at neighborhood and watershed scales.

Constructed Rain Garden Systems for Stormwater Quality Control under Tropical Climates

NASA Astrophysics Data System (ADS)

Mohd Sidek, Lariyah; Elyza Muha, Norshafa; Noor, Nur Asmaliza Md; Basri, Hidayah

2013-06-01

Malaysia has taken an integrated approach to manage storm water that is increasingly becoming a problem in big cities. Rain gardens are recommended as green technology for a new storm water management in Malaysia. The approach is applied in urban planning and design that integrates the total water cycle management into the development process areas. Rain gardens have been effective in reducing peak discharge and consistently reduce the number of storm water pollutants. This paper will examine some of guidelines, laboratory studies and field monitoring that shows great potential and benefit of rain garden. The preliminary results for rain garden performance were reported in this paper. The findings from this research will open avenues for researchers to advance the knowledge in rain garden systems to achieve the sustainable development in Malaysia.

Effects of ozone and acidic deposition on carbon allocation and mycorrhizal colonization of Pinus taeda L. seedlings

Treesearch

M.B. Adams; E.G. O' Neill

1991-01-01

Patterns of carbon allocation and mycorrhizal colonization were examined in loblolly pine seedlings from two half-sib families exposed to three ozone treatments (charcoal-filtered air, ambient air + 80 ppb 03 , and ambient air + 160 ppb 03) and three rain pH levels (5.2, 4.5, and 3.3) for 12 weeks in open-topped chambers in...

One year water chemistry monitoring of the flooding of the Meirama open pit (NW Spain)

NASA Astrophysics Data System (ADS)

Delgado, J.; Juncosa, R.; Vázquez, A.; Fernández-Bogo, S.

2009-04-01

In December, 2007, after 30 years of operations, the mine of Meirama finished the extraction of brown lignite. Starting in April 2008, the flooding of the open pit has started and this is leading to the formation of a large mining lake (~2 km2 surface and up to 180 m depth) in which surface (river and rain water) and ground waters are involved. Since the beginning of the flooding, lake waters are weekly sampled and analyzed for temperature, pH, redox, EC, TDS, TSS, DO,DIC, DOC, turbidity, alkalinity/acidity as well as nearly 40 inorganic chemical components. Stable water isotopes (deuterium and oxygen) are also being recorded. In order to better understand the dynamic chemical evolution of lake waters, the chemical characteristics of rain water as well as a series of lake tributaries and ground waters are also being measured. Since the beginning of the flooding process, the chemical quality of lake water has experienced an interesting evolution that obeys to a variety of circumstances. The silicic geologic substratum of the catchment determines that both ground and surface waters have a rather low alkalinity. Moreover, the presence of disseminated sulfides (mainly pyrite) within the schistous materials of the mine slopes and internal rock dumps provokes a significant acidic load. From April to October 2008, the lake waters had only the contribution of rain and ground waters. Since the beginning of October, a significant volume of surface waters has been derived to the mine hole. Taking pH as indicator, the first water body had a rather acidic pH (~3) which was progressively amended with the addition of a certain amount of lime to reach an upper value of ~8 by late August. The diminution in the addition of lime up to its elimination, in December, has conducted to the progressive acidification of the lake. At present, an instrumented floating deck is being deployed in the lake. This device will serve as a base point where it is planned to locate a series of instrumentation (complete weather monitoring station, multiparametric probe, sediment trap line) that will complement with depth profiles the surficial sampling performed so far.

Leachability of uranium and other elements from freshly erupted volcanic ash

USGS Publications Warehouse

Smith, D.B.; Zielinski, R.A.; Rose, W.I.

1982-01-01

A study of leaching of freshly erupted basaltic and dacitic air-fall ash and bomb fragment samples, unaffected by rain, shows that glass dissolution is the dominant process by which uranium is initially mobilized from air-fall volcanic ash. Si, Li, and V are also preferentially mobilized by glass dissolution. Gaseous transfer followed by fixation of soluble uranium species on volcanic-ash particles is not an important process affecting uranium mobility. Gaseous transfer, however, may be important in forming water-soluble phases, adsorbed to ash surfaces, enriched in the economically and environmentally important elements Zn, Cu, Cd, Pb, B, F, and Ba. Quick removal of these adsorbed elements by the first exposure of freshly erupted ash to rain and surface water may pose short-term hazards to certain forms of aquatic and terrestrial life. Such rapid release of material may also represent the first step in transportation of economically important elements to environments favorable for precipitation into deposits of commercial interest. Ash samples collected from the active Guatemalan volcanoes Fuego and Pacaya (high-Al basalts) and Santiaguito (hornblende-hypersthene dacite); bomb fragments from Augustine volcano (andesite-dacite), Alaska, and Heimaey (basalt), Vestmann Islands, Iceland; and fragments of "rhyolitic" pumice from various historic eruptions were subjected to three successive leaches with a constant water-to-ash weight ratio of 4:1. The volcanic material was successively leached by: (1) distilled-deionized water (pH = 5.0-5.5) at room temperature for 24 h, which removes water-soluble gases and salts adsorbed on ash surfaces during eruption; (2) dilute HCl solution (pH = 3.5-4.0) at room temperature for 24 h, which continues the attack initiated by the water and also attacks acid-soluble sulfides and oxides; (3) a solution 0.05 M in both Na,CO, and NaHCO, (pH = 9.9) at 80°C for one week, which preferentially dissolves volcanic glass. The first two leaches mimic interaction of ash with rain produced in the vicinity of an active eruption. The third leach accelerates the effect of prolonged contact of volcanic ash with alkaline ground water present during ash diagenesis.

Effects of local emission sources on the acidification of rainwater in an industrial city in Taiwan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chung-Shin Yuan; Der-Yuan Wu

1996-12-31

This study investigated the acidification of precipitation in an industrial city in Taiwan Island. The purposes of this study is two fold. The first is to characterize the status of add precipitation around the industrial city. Rainwater samples were collected by automatic rainwater samplers-located at five sampling sites which covered the entire city. The second is to investigate the potential sources of acidic species in the acid rainwater. Further study was taken to ascertain the effects of local emissions as well as long range transportation on the acidification of precipitation. Investigation of acid rain on the Island of Taiwan hasmore » been conducted since 1984. Most of these researches were short-term and/or large-scale investigations. Long-term sampling of acid rain at heavy polluted region has never been investigated yet. In this investigation, Kaohsiung was selected as the city for the intensive acid rain sampling since it is the largest industrial city as well as the largest harbor in Taiwan Island. Both dry and wet acid samples were collected daily by the automatic rainwater samplers. Major cations (H{sup +}, NH{sub 4}{sup +}, K{sup +}, Ca{sup +2}, and Mg{sup +2}), anions (F{sup -}, Cl{sup -}, NO3{sup -}, and SO4{sup -2}), and conductivity of acid samples were measured simultaneously. Actually, both pH value and conductivity were measured on site. During the period of investigation, 325 collected rainwater samples demonstrated an average pH value of 5.2 with the range of 3.1 to 6.3. This investigation revealed that emissions from local sources such as power plants, petrochemical plants, and cement plants play important roles on the acidification of rainwater in the industrial city in Taiwan.« less

Correlation between microstructural characteristics and weight loss of natural stones exposed to simulated acid rain.

PubMed

Franzoni, Elisa; Sassoni, Enrico

2011-12-15

The correlation between stone microstructural characteristics and material degradation (in terms of weight loss), in given environmental conditions, was investigated. Seven lithotypes, having very different microstructural characteristics, were used. Four acidic aqueous solutions were prepared to simulate acid rain (two adding H(2)SO(4) and two adding HNO(3) to deionized water, in order to reach, for each acid, pH values of 5.0 and 4.0), and deionized water at pH=5.6 was used to simulate clean rain. Stone samples were then immersed in such aqueous solutions, the surface alteration being periodically inspected and the weight loss periodically measured. After 14 days of immersion, a good correlation was found between weight loss and the product of carbonate content and specific surface area in the starting materials. This was explained considering that this product accounts for the weight loss owing to the sample's fraction actually composed of calcite (the most soluble fraction) and the effective surface area exposed to dissolving solution (which depends on stone porosity and pore size distribution). Such correlation between stone microstructure and degradation may be useful for comparing the durability of different lithotypes, in given environmental conditions, and quantitatively predicting the weight loss of a lithotype, compared to another one. Hence, the correlation found in this study may be used to specifically tailor to various stone types, with different microstructural characteristics, some results that have been calculated in literature for specific stone types and then proposed as possibly representative for a broad category of stones with similar characteristics. Copyright © 2011 Elsevier B.V. All rights reserved.

[Seasonality and contribution to acid rain of the carbon abundance in rainwater].

PubMed

Xu, Tao; Song, Zhi-guang; Liu, Jun-feng; Wang, Cui-ping

2008-02-01

This paper reports the results from a study of the carbon abundance in rainwater of Guangzhou city, China. The determination of TOC, DOC, POC and PEC helps to study the seasonality of carbon abundance and its contribution to the acid rain. The results display the fact that the average contents of TOC, DOC, POC and PEC are 7.10 mg/L, 3.58 mg/L, 3.60 mg/L and 0.72 mg/L, respectively. These results confirm the deep effect of the organic pollutant to the rain. The seasonality exists in the carbon abundance of rainwater. The contents of TOC and DOC are up to the maximum in spring and the minimum in summer; the contribution of POC to TOC in summer is obviously higher than that in other seasons; and the relative content of POC is clearly higher in dry season than that in wet season. The seasonality reflects the more emission of the total pollutant in spring and the solid particle pollutant in summer than those in other seasons. Moreover, the emission of the organic pollutant from the mobile vehicles is more obvious in dry season than that in wet season. The contents of TOC and DOC have the negative correlation to the pH values, which confirms the contribution effect of the organic pollutant, such as vehicle emission, to the acid rain.

The Microphysical Structure of Extreme Precipitation as Inferred from Ground-Based Raindrop Spectra.

NASA Astrophysics Data System (ADS)

Uijlenhoet, Remko; Smith, James A.; Steiner, Matthias

2003-05-01

The controls on the variability of raindrop size distributions in extreme rainfall and the associated radar reflectivity-rain rate relationships are studied using a scaling-law formalism for the description of raindrop size distributions and their properties. This scaling-law formalism enables a separation of the effects of changes in the scale of the raindrop size distribution from those in its shape. Parameters controlling the scale and shape of the scaled raindrop size distribution may be related to the microphysical processes generating extreme rainfall. A global scaling analysis of raindrop size distributions corresponding to rain rates exceeding 100 mm h1, collected during the 1950s with the Illinois State Water Survey raindrop camera in Miami, Florida, reveals that extreme rain rates tend to be associated with conditions in which the variability of the raindrop size distribution is strongly number controlled (i.e., characteristic drop sizes are roughly constant). This means that changes in properties of raindrop size distributions in extreme rainfall are largely produced by varying raindrop concentrations. As a result, rainfall integral variables (such as radar reflectivity and rain rate) are roughly proportional to each other, which is consistent with the concept of the so-called equilibrium raindrop size distribution and has profound implications for radar measurement of extreme rainfall. A time series analysis for two contrasting extreme rainfall events supports the hypothesis that the variability of raindrop size distributions for extreme rain rates is strongly number controlled. However, this analysis also reveals that the actual shapes of the (measured and scaled) spectra may differ significantly from storm to storm. This implies that the exponents of power-law radar reflectivity-rain rate relationships may be similar, and close to unity, for different extreme rainfall events, but their prefactors may differ substantially. Consequently, there is no unique radar reflectivity-rain rate relationship for extreme rain rates, but the variability is essentially reduced to one free parameter (i.e., the prefactor). It is suggested that this free parameter may be estimated on the basis of differential reflectivity measurements in extreme rainfall.

Embedded micro-sensor for monitoring pH in concrete structures

NASA Astrophysics Data System (ADS)

Srinivasan, Rengaswamy; Phillips, Terry E.; Bargeron, C. Brent; Carlson, Micah A.; Schemm, Elizabeth R.; Saffarian, Hassan M.

2000-04-01

Three major causes of corrosion of steel in concrete are chloride ions (Cl-), temperature (T) and acidity (pH). Under normal operating temperatures and with pH above 13, steel does not undergo pitting corrosion. In presence of Cl-, if the pH decreases below 12, the probability of pitting increases. Acid rain and atmospheric carbon dioxide cause the pH to drop in concrete, often leading to corrosion of the structure with the concomitant cost of repair or replacement. Currently, the pH level in concrete is estimated through destructive testing of the structures. Glass ISFET, and other pH sensors that need maintenance and calibration cannot be embedded in concrete. In this paper, we describe an inexpensive solid state pH sensor that can be embedded in concrete, to detect pH changes at the early stages. It employs a chemical reagent, trinitrobenzenesulfonic acid (TNBS) that exhibits changes in optical properties in the 12 - 14 pH range, and is held in a film of a sol-gel/TNBS composite on an optically transparent surface. A simple LED/filter/photodiode transducer monitors pH-induced changes in TNBS. Such a device needs no periodic calibration or maintenance. The optical window, the light-source and sensor can be easily housed and encapsulated in a chemically inert structure, and embedded in concrete.

Variation in pH optima of hydrolytic enzyme activities in tropical rain forest soils.

PubMed

Turner, Benjamin L

2010-10-01

Extracellular enzymes synthesized by soil microbes play a central role in the biogeochemical cycling of nutrients in the environment. The pH optima of eight hydrolytic enzymes involved in the cycles of carbon, nitrogen, phosphorus, and sulfur, were assessed in a series of tropical forest soils of contrasting pH values from the Republic of Panama. Assays were conducted using 4-methylumbelliferone-linked fluorogenic substrates in modified universal buffer. Optimum pH values differed markedly among enzymes and soils. Enzymes were grouped into three classes based on their pH optima: (i) enzymes with acidic pH optima that were consistent among soils (cellobiohydrolase, β-xylanase, and arylsulfatase), (ii) enzymes with acidic pH optima that varied systematically with soil pH, with the most acidic pH optima in the most acidic soils (α-glucosidase, β-glucosidase, and N-acetyl-β-glucosaminidase), and (iii) enzymes with an optimum pH in either the acid range or the alkaline range depending on soil pH (phosphomonoesterase and phosphodiesterase). The optimum pH values of phosphomonoesterase were consistent among soils, being 4 to 5 for acid phosphomonoesterase and 10 to 11 for alkaline phosphomonoesterase. In contrast, the optimum pH for phosphodiesterase activity varied systematically with soil pH, with the most acidic pH optima (3.0) in the most acidic soils and the most alkaline pH optima (pH 10) in near-neutral soils. Arylsulfatase activity had a very acidic optimum pH in all soils (pH ≤3.0) irrespective of soil pH. The differences in pH optima may be linked to the origins of the enzymes and/or the degree of stabilization on solid surfaces. The results have important implications for the interpretation of hydrolytic enzyme assays using fluorogenic substrates.

Causes of acidification of four streams on Laurel Hilld in southwestern Pennsylvania

USGS Publications Warehouse

Sharpe, William E.; DeWalle, David R.; Leibfried, Robert T.; Dinicola, Richard S.; Kimmel, William G.; Sherwin, Lysle S.

1984-01-01

Atmospheric deposition, soils developed from bedrock, a natural bog, gas wells, and a ski area were all investigated as possible sources of water quality degradation for four streams on Laurel Hill in southwestern Pennsylvania where fish kills have been reported since 1960. An intensive study of the chemistry of atmospheric deposition, soil leachate, and stream water and fish populations was conducted on these basins during 1980–1981 with emphasis on dormant season periods with runoff from snowmelt and rain. Although bedrock geology was found to control the natural buffering capacity of these streams, only acid precipitation could be linked to sharp drops in pH and increases in total Al concentrations observed during stormflows in the poorly buffered streams. Three poorly buffered streams exhibited drops to pH 4.4 to 4.5 and increases in total Al concentrations up to 1.5 mg/L during observed peak flows. Mineral soil leachate from the three major soil series on the basins during this time exhibited a low pH of 4.3 and mean total Al concentrations of 3.6 mg/L, indicating stream response during storms was closely linked to chemistry of soil leachate. Poorly buffered streams did not support reproducing populations of trout (Salmonidae sp.) or other fishes. In contrast, one well-buffered stream (20 mg/L CaCO3) exhibited drops to pH 5.5 during peak flow and supported reproducing trout and sculpin (Cottus bairdi) populations. The acidification of the four streams studied was attributed to atmospheric deposition.

USGS Tracks Acid Rain

USGS Publications Warehouse

Gordon, John D.; Nilles, Mark A.; Schroder, LeRoy J.

1995-01-01

The U.S. Geological Survey (USGS) has been actively studying acid rain for the past 15 years. When scientists learned that acid rain could harm fish, fear of damage to our natural environment from acid rain concerned the American public. Research by USGS scientists and other groups began to show that the processes resulting in acid rain are very complex. Scientists were puzzled by the fact that in some cases it was difficult to demonstrate that the pollution from automobiles and factories was causing streams or lakes to become more acidic. Further experiments showed how the natural ability of many soils to neutralize acids would reduce the effects of acid rain in some locations--at least as long as the neutralizing ability lasted (Young, 1991). The USGS has played a key role in establishing and maintaining the only nationwide network of acid rain monitoring stations. This program is called the National Atmospheric Deposition Program/National Trends Network (NADP/NTN). Each week, at approximately 220 NADP/NTN sites across the country, rain and snow samples are collected for analysis. NADP/NTN site in Montana. The USGS supports about 72 of these sites. The information gained from monitoring the chemistry of our nation's rain and snow is important for testing the results of pollution control laws on acid rain.

Non-invasive technique to measure biogeochemical parameters (pH and O2) in a microenvironment: Design and applications

NASA Astrophysics Data System (ADS)

Li, Biting; Seliman, Ayman; Pales, Ashley; Liang, Weizhen; Sams, Allison; Darnault, Christophe; Devol, Timothy

2017-04-01

The primary objectives of this research are to do the pH and O2 sensor foils calibration and then to test them in applications. Potentially, this project can be utilized to monitor the fate and transport of radionuclides in porous media. The information for physical and chemical parameters (e.g. pH and O2) is crucial to know when determining contaminants' behavior and transport in the environment. As a non-invasive method, optical imaging technique using a DSLR camera could capture data on the foil when it fluoresces, and gives a high temporal and spatial resolution during the experimental period. The calibration procedures were done in cuvettes in a row. The preliminary experiments could measure pH value in the range from 4.5 to 7.5, and O2 concentration from 0 mg/L to 20.74 mg/L. Applications of sensor foils have involved nano zero valent and acid rain experiments in order to obtain a gradient of parameter changes.

Biosignatures of Kerala red rain cells: Implications in understanding their origin

NASA Astrophysics Data System (ADS)

Gangappa, R.; Thomas, M.; Hogg, S.

2013-09-01

The red rain that fell over Kerala, southern India (2001-2012) was characterised by the red pigmented particles. Earlier proposal claiming that these are known algal bloom blown from trees (Sampath et al, 2001; DiGregorio, 2007) has been studied by us and disproved. Also, further investigation reporting their extraordinary properties including a suggestion that they lack DNA (Louis and Kumar 2003; 2006; 2008) has been invalidated (Gangappa and Hogg, 2013). However, their claim regarding the growth and replication of these cells at 300ºC needs more investigation if it is to gain acceptance. Current study provide evidences regarding the biological properties of Kerala red rain cells to gain insights into environmental conditions from which they may have originated. Combined with various research strategies and high resolution instruments, we have demonstrated the following interesting properties of Kerala red rain cells: (1) unusually thick external envelope enclosing the central core; (2)stability of red pigment at temperatures about 100ºC and pH variations; (3) absence of eukaryotic ultrastructures; (4) possible replication at 121ºC with nanostructures (possible daughter cells) having similar morphological features inside the large mother cells at such high temperature. They contain high percentage of carbon, iron, silicon and aluminum and often enclosed in a silicon rich biofilms. Further investigation shows that the positive detection of DNA in these cells was possible only after the complete removal of red pigment, thereby providing an explanation for the negative outcome of earlier studies in this regard. Moreover, evidences are shown to support that these cells contain high amounts of UV absorbing compounds, porphyrin complexes and possible scytonemin. Kerala red rain cells may prove to be polyextermophiles belonging to prokaryotes and may have possibly originated from the environment containing above mentioned chemical elements, high energy UV exposure and possible high temperatures. This may be of high interest and red rain cells can be viewed as a possible candidate in future Astrobiological investigations.

Impact of biomass burning on rainwater acidity and composition in Singapore

NASA Astrophysics Data System (ADS)

Balasubramanian, R.; Victor, T.; Begum, R.

1999-11-01

The Indonesian forest fires that took place from August through October 1997 released large amounts of gaseous and particulate pollutants into the atmosphere. The particulate emissions produced a plume that was easily visible by satellite and significantly affected regional air quality in Southeast Asia. This prolonged haze episode provided an unprecedented opportunity to examine the effects of biomass burning on regional atmospheric chemistry. We undertook a comprehensive field study to assess the influence of biomass burning impacted air masses on precipitation chemistry in Singapore. Major inorganic and organic ions were determined in 104 rain samples collected using an automated wet-only sampler from July through December 1997. Mean pH values ranged from 3.79 to 6.20 with a volume-weighted mean of 4.35. There was a substantially large number of rain events with elevated concentrations of these ions during the biomass burning period. The relatively high concentrations of SO2-4, NO-3, and NH+4 observed during the burning period are attributed to a long residence time of air masses, leading to progressive gas to particle conversion of biomass burning emission components. The decrease in pH of precipitation in response to the increased concentrations of acids is only marginal, which is ascribed to neutralization of acidity by NH3 and CaCO3.

Sequestering CO(2) by mineral carbonation: stability against acid rain exposure.

PubMed

Allen, Daniel J; Brent, Geoff F

2010-04-01

Mineral carbonation is a potentially attractive alternative to storage of compressed CO(2) in underground repositories, known as geosequestration. Processes for the conversion of basic ores, such as magnesium silicates, to carbonates have been proposed by various researchers, with storage of the carbonate as backfill in the original mine representing a solid carbon sink. The stability of such carbon sinks against acid rain and other sources of strong acids is examined here. It is acknowledged that in the presence of strong acid, carbonates will dissolve and release carbon dioxide. A sensitivity analysis covering annual average rainfall and pH that may be encountered in industrialized areas of the United States, China, Europe, and Australia was conducted to determine maximum CO(2) rerelease rates from mineral carbonation carbon sinks. This analysis is based on a worst-case premise that is equivalent to assuming infinitely rapid kinetics of dissolution of the carbonate. The analysis shows that under any likely conditions of pH and rainfall, leakage rates of stored CO(2) are negligible. This is illustrated in a hypothetical case study under Australian conditions. It is thus proposed that sequestration by mineral carbonation can be considered to be permanent on practical human time scales. Other possible sources of acid have also been considered.

A High Precision $3.50 Open Source 3D Printed Rain Gauge Calibrator

NASA Astrophysics Data System (ADS)

Lopez Alcala, J. M.; Udell, C.; Selker, J. S.

2017-12-01

Currently available rain gauge calibrators tend to be designed for specific rain gauges, are expensive, employ low-precision water reservoirs, and do not offer the flexibility needed to test the ever more popular small-aperture rain gauges. The objective of this project was to develop and validate a freely downloadable, open-source, 3D printed rain gauge calibrator that can be adjusted for a wide range of gauges. The proposed calibrator provides for applying low, medium, and high intensity flow, and allows the user to modify the design to conform to unique system specifications based on parametric design, which may be modified and printed using CAD software. To overcome the fact that different 3D printers yield different print qualities, we devised a simple post-printing step that controlled critical dimensions to assure robust performance. Specifically, the three orifices of the calibrator are drilled to reach the three target flow rates. Laboratory tests showed that flow rates were consistent between prints, and between trials of each part, while the total applied water was precisely controlled by the use of a volumetric flask as the reservoir.

Contribution and loading estimation of organochlorine pesticides from rain and canopy throughfall to runoff in an urban environment.

PubMed

Zhang, Wei; Ye, Youbin; Tong, Yindong; Ou, Langbo; Hu, Dan; Wang, Xuejun

2011-01-30

Concentrations of OCPs in rain, canopy throughfall, and runoff water were measured in the Beijing metropolitan area during the rainy seasons from 2006 to 2007. This study was conducted to calculate the fluxes of OCPs in rain and canopy throughfall, as well as their contributions to runoff. At urban sites, the contribution of HCB and ΣHCHs from rainfall accounted for approximately 50% of the mass in runoff. At the site with significant coverage of landscaping trees, the HCB, ΣHCHs, and ΣDDTs from the net canopy throughfall accounted for approximately 10% of the mass in the runoff. Based on the data obtained in this study, loadings of OCPs (in μg) in rain, net canopy throughfall, and runoff water were calculated. The input of OCPs from rain and canopy throughfall water accounted for a significant portion of urban runoff. In cities undergoing rapid urban sprawl, monitoring and control of the transport of OCPs in urban runoff are essential for effective control of environmental hazards in surface water bodies. Copyright © 2010 Elsevier B.V. All rights reserved.

Critical review: Copper runoff from outdoor copper surfaces at atmospheric conditions.

PubMed

Hedberg, Yolanda S; Hedberg, Jonas F; Herting, Gunilla; Goidanich, Sara; Odnevall Wallinder, Inger

2014-01-01

This review on copper runoff dispersed from unsheltered naturally patinated copper used for roofing and facades summarizes and discusses influencing factors, available literature, and predictive models, and the importance of fate and speciation for environmental risk assessment. Copper runoff from outdoor surfaces is predominantly governed by electrochemical and chemical reactions and is highly dependent on given exposure conditions (size, inclination, geometry, degree of sheltering, and orientation), surface parameters (age, patina composition, and thickness), and site-specific environmental conditions (gaseous pollutants, chlorides, rainfall characteristics (amount, intensity, pH), wind direction, temperature, time of wetness, season). The corrosion rate cannot be used to assess the runoff rate. The extent of released copper varies largely between different rain events and is related to dry and wet periods, dry deposition prior to the rain event and prevailing rain and patina characteristics. Interpretation and use of copper runoff data for environmental risk assessment and management need therefore to consider site-specific factors and focus on average data of long-term studies (several years). Risk assessments require furthermore that changes in copper speciation, bioavailability aspects, and potential irreversible retention on solid surfaces are considered, factors that determine the environmental fate of copper runoff from outdoor surfaces.

Aircraft Landing Gear, Ice and Rain Control Systems (Course Outline), Aviation Mechanics 3 (Air Frame):9067.02.

ERIC Educational Resources Information Center

Dade County Public Schools, Miami, FL.

This document presents an outline for a 135-hour course designed to familiarize the student with operation, inspection, troubleshooting, and repair of aircraft landing gear, ice and rain control systems. It is designed to help the trainee master the knowledge and skills necessary to become an aviation airframe mechanic. The aviation airframe…

Chemical Composition of Rainwater in Córdoba City, Argentina

NASA Astrophysics Data System (ADS)

López, M. L.; Asar, M. L.; Ceppi, S.; Bürgesser, R. E.; Avila, E.

2013-05-01

Sampling and chemical analysis of rainwater has proved to be a useful technique for studying its chemical composition and provides a greater understanding of local and regional dispersion of pollutants and their potential impacts to ecosystems through deposition processes. Samples of rainwater were collected during 2009-2012, in Córdoba city, Argentina. Two kind of sampling were performed: event-specific and sequential. The objective of the first of these was to determine the chemical concentration of the total rain, while the objective of the second one was to analyze the variability of the chemical concentration during an individual rain event. The total volume of each sample was divided in halves. One half was filtered through 0.45 μm membrane filter. After this, all the samples were reduced by evaporation to a final volume of 10 ml. The non-filtered samples were acidified and digested in accordance to the method 3050B of the Environmental Protection Agency (EPA) for acid digestion of sediments. Multi-elemental standard solutions in different concentrations were prepared by adequate dilutions. Gallium was added as an internal standard in all standard solutions and samples. Exactly 5 μL of these solutions were deposited on acrylic supports. When these droplets were dried, Synchrotron Radiation Total Reflection X-Ray Fluorescence technique was used for determining the chemical elements. Spectra were analyzed with the AXIL package for spectrum analysis. Due to the intrinsic characteristics of the total reflection technique, the background of the measurements is significantly reduced and there are no matrix effects, therefore quantification can be obtained from the linear correlation between fluorescence intensity and the concentration of the element of interest. The elements quantified were S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sr, and Pb. For all of them a calibration curve was performed in order to quantify their concentrations on the samples. The results show that the average pH in city rainwater was pH=6.5; the elements found in the samples were S, Ca, Cu, Cr, Sr, P, Fe, Mn, Pb, K, Ti, V, Zn and the average concentrations of these elements were below the limits established by World Health Organization for drinking water, and show a high natural variability. The temporal evolution of inorganic ion concentration during rain events was analyzed and the scavenging coefficients were calculated and compared with data from literature. A comparison was made between the rainwater chemical composition and chemical composition in the aerosols scavenging during the rain. This study is the first in Córdoba city to analyze the chemical composition of rainwater and constitute a base for future comparison of variability in pH and elemental composition.

Effects of acidity on tree Pollen germination and tube growth. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Ryn, D.M.; Jacobson, J.S.

Most of the northeastern hardwood forests in North America are exposed repeatedly to acidic rainfall at pH values below 5.0. Pollen germination, tube growth and fertilization, important parts of the reproductive process, are sensitive to changes in their chemical environment. Accordingly, the authors investigated the effects of acidity on pollen germination and tube elongation of four northeastern tree species: flowering dogwood, black birch, yellow birch, and sugar maple. Pollen was collected and germinated in a growth medium acidified to pH values ranging from 5.0 to 2.6. Pollen was found to be sensitive to acidification of the germination medium to belowmore » pH 4.2. These results suggest that acidic rain that now occurs in eastern North America may influence reproductive processes that are necessary for seed set and regeneration in northern hardwood forests.« less

Effect of exogenous abscisic acid on morphology, growth and nutrient uptake of rice (Oryza sativa) roots under simulated acid rain stress.

PubMed

Liu, Hongyue; Ren, Xiaoqian; Zhu, Jiuzheng; Wu, Xi; Liang, Chanjuan

2018-05-31

Application of proper ABA can improve acid tolerance of rice roots by balancing endogenous hormones and promoting nutrient uptake. Abscisic acid (ABA) has an important signaling role in enhancing plant tolerance to environmental stress. To alleviate the inhibition on plant growth and productivity caused by acid rain, it is crucial to clarify the regulating mechanism of ABA on adaptation of plants to acid rain. Here, we studied the effects of exogenously applied ABA on nutrients uptake of rice roots under simulated acid rain (SAR) stress from physiological, biochemical and molecular aspects. Compared to the single SAR treatment (pH 4.5 or 3.5), exogenous 10 μM ABA alleviated the SAR-induced inhibition of root growth by balancing endogenous hormones (abscisic acid, indole-3-acetic acid, gibberellic acid and zeatin), promoting nutrient uptake (nitrate, P, K and Mg) in rice roots, and increasing the activity of the plasma membrane H + -ATPase by up-regulating expression levels of genes (OSA2, OSA4, OSA9 and OSA10). However, exogenous 100 μM ABA exacerbated the SAR-caused inhibition of root growth by disrupting the balance of endogenous hormones, and inhibiting nutrient uptake (nitrate, P, K, Ca and Mg) through decreasing the activity of the plasma membrane H + -ATPase. These results indicate that proper concentration of exogenous ABA could enhance tolerance of rice roots to SAR stress by promoting nutrients uptake and balancing endogenous hormones.

Adaptive data rate control TDMA systems as a rain attenuation compensation technique

NASA Technical Reports Server (NTRS)

Sato, Masaki; Wakana, Hiromitsu; Takahashi, Takashi; Takeuchi, Makoto; Yamamoto, Minoru

1993-01-01

Rainfall attenuation has a severe effect on signal strength and impairs communication links for future mobile and personal satellite communications using Ka-band and millimeter wave frequencies. As rain attenuation compensation techniques, several methods such as uplink power control, site diversity, and adaptive control of data rate or forward error correction have been proposed. In this paper, we propose a TDMA system that can compensate rain attenuation by adaptive control of transmission rates. To evaluate the performance of this TDMA terminal, we carried out three types of experiments: experiments using a Japanese CS-3 satellite with Ka-band transponders, in house IF loop-back experiments, and computer simulations. Experimental results show that this TDMA system has advantages over the conventional constant-rate TDMA systems, as resource sharing technique, in both bit error rate and total TDMA burst lengths required for transmitting given information.

Temporal variation and the effect of rainfall on metals flux from the historic Beatson mine, Prince William Sound, Alaska, USA

USGS Publications Warehouse

Stillings, L.L.; Foster, A.L.; Koski, R.A.; Munk, L.; Shanks, Wayne C.

2008-01-01

Several abandoned Cu mines are located along the shore of Prince William Sound, AK, where the effect of mining-related discharge upon shoreline ecosystems is unknown. To determine the magnitude of this effect at the former Beatson mine, the largest Cu mine in the region and a Besshi-type massive sulfide ore deposit, trace metal concentration and flux were measured in surface run-off from remnant, mineralized workings and waste. Samples were collected from seepage waters; a remnant glory hole which is now a pit lake; a braided stream draining an area of mineralized rock, underground mine workings, and waste piles; and a background location upstream of the mine workings and mineralized rock. In the background stream pH averaged ???7.3, specific conductivity (SC) was ???40 ??S/cm, and the aqueous components indicative of sulfide mineral weathering, SO4 and trace metals, were at detection limits or lower. In the braided stream below the mine workings and waste piles, pH usually varied from 6.7 to 7.1, SC varied from 40 to 120 ??S/cm, SO4 had maximum concentrations of 32 mg/L, and the trace metals Cu, Ni, Pb, and Zn showed maximum total acid extractable concentrations of 186, 5.9, 6.2 and 343 ??g/L, respectively. With an annual rainfall of ???340 cm (estimated from the 2006 water year) it was expected that rain water would have a large effect on the chemistry of the braided stream draining the mine site. A linear mixing model with two end members, seepage water from mineralized rock and background water, estimated that the braided stream contained 10-35% mine drainage. After rain events the braided stream showed a decrease in pH, SC, Ca + Mg, SO4, and alkalinity, due to dilution. The trace metals Ni and Zn followed this same pattern. Sodium + K and Cl did not vary between the background and braided stream, nor did they vary with rainfall. At approximately 2 and 3 mg/L, respectively, these concentrations are similar to concentrations found in rainfall on the coasts of North America. High concentrations of total acid extractable Al and Fe were found at near-neutral pH in most of the waters collected at the site. Equilibrium solubility simulations, performed with PHREEQC, show that the stream waters are saturated with respect to Al, Fe and SiO2 solid phases. Because the "dissolved" sample fractions (acid preserved and filtered to 0.45 ??m) show significant concentrations of Al and Fe it is presumed that these are present as colloids. The relationship between concentrations of Al and Fe, and rainfall was the opposite of that observed for the major ions Ca + Mg, SO4, and alkalinity, in that Al and Fe concentrations increased with increasing rainfall. Concentrations of Cu and Pb followed the same pattern. Adsorption calculations were performed with Visual MINTEQ, using the diffuse double layer electrostatic model and surface complexation constants for the ferrihydrite surface. These results suggest that 30-93% of Cu and 58-97% of Pb was adsorbed to ferrihydrite precipitates in the stream waters. Ni and Zn showed little adsorption in this pH range. Flux calculations show that the total mass of trace metals transported from the mine site, during the 60 day study period, was ranked as Zn (196 kg) > Cu (87 kg) > Pb(1.9 kg) ??? Ni(1.9 kg). Nickel and Zn were transported mostly as dissolved species while Cu and Pb were transported mostly as adsorbed species. pH control on adsorption was evident when Cu and Pb isotherms were normalized by ferrihydrite flux. Decreased stream water pH due to periods of frequent and high volume rain events would cause desorption of Cu and Pb from the ferrihydrite surface, thus changing not only their speciation in solution but also their mechanism of transport. ?? 2007 Elsevier Ltd. All rights reserved.

Improved Gradation for Rain Garden of Low Impact Development

NASA Astrophysics Data System (ADS)

Lee, Sandra; Chang, Fu-Ming

2016-04-01

With rapid urban and economic development, living standard improves in urban areas but urban ecological environments deteriorate rapidly. Urban waterlogging and flooding have become a serious problem for urban water security. As urbanization continues, sustainability is the key to balance between urban development and healthy environment. Rain garden is recommended to be one of the best ways to reduce urban pollutants. It not only diminishes runoff flooding but also purify water in the urban area. The studies on rain gardens are mainly about how to incorporate rain garden to purify water quality, but lack of researches on runoff control. This project focuses on rain garden under Low Impact Development using indoor laboratory to test and quantify the water holding capacities of two different Taiwan indigenous rain garden plants, Taiwan Cyclosorus and Sour Grass. The results show that the water holding capacity of Sour Grass (10%-37%) is better than that of Taiwan Cyclosorus (6.8%-17.3%). The results could be a helpful reference for Low Impact Development in urban flood prevention and urban planning. Keywords: Low Impact Development; rain garden; indoor laboratory experiments; water holding capacity; porosity

Controls of streamflow generation in small catchments across the snow-rain transition in the southern Sierra Nevada, California

Treesearch

Fengjing Liu; Carolyn Hunsaker; Roger C. Bales

2012-01-01

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snowdominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca2+...

Predicting recovery from acid rain using the micro-spatial heterogeneity of soil columns downhill the infiltration zone of beech stemflow: introduction of a hypothesis.

PubMed

Berger, Torsten W; Muras, Alexander

Release of stored sulfur may delay the recovery of soil pH from Acid Rain. It is hypothesized that analyzing the micro-spatial heterogeneity of soil columns downhill of a beech stem enables predictions of soil recovery as a function of historic acid loads and time. We demonstrated in a very simplified approach, how these two different factors may be untangled from each other using synthetic data. Thereafter, we evaluated the stated hypothesis based upon chemical soil data with increasing distance from the stem of beech trees. It is predicted that the top soil will recover from acid deposition, as already recorded in the infiltration zone of stemflow near the base of the stem. However, in the between trees areas and especially in deeper soil horizons recovery may be highly delayed.

[Epiphytic communities of arboreal formations in Southern Vietnam: an analysis of species composition and synusias structure in dependence on the extent of anthropogenic impact].

PubMed

Es'kov, A K

2013-01-01

Species composition of epiphytic communities within different formations of Phú Quôc Island (Southern Vietnam) is studied. The dependence of species composition and structural complexity of epiphytic communities on formation quality is demonstrated. Representatives of different families differ notably in their sensitivity to disturbances. Most vulnerable are Orchidaceae which represent the dominant group in epiphytic community of rain forest and which drop out almost completely under anthropogenic impacts. In less disturbed forests, epiphyte species diversity increases mainly at the expense of "lower" synusias and directly depends on the formation layering. Diminishing of layering numbers leads to dropping out of species belonging to "lower" synusias. Among epiphytes, the indicators of disturbed communities can be detected, namely species of ruderal strategy (explerents). In primal rain forest, they are absent or barely noticeable. An index is proposed for estimation of epiphytic communitiy complexity.

The influence of polarization on millimeter wave propagation through rain. Ph.D Thesis. Interim Report

NASA Technical Reports Server (NTRS)

Wiley, P. H.; Bostian, C. W.; Stutzman, W. L.

1973-01-01

The influence of polarization on millimeter wave propagation is investigated from both an experimental and a theoretical viewpoint. First, previous theoretical and experimental work relating to the attenuation and depolarization of millimeter waves by rainfall is discussed. Considerable detail is included in the literature review. Next, a theoretical model is developed to predict the cross polarization level during rainfall from the path average rain rate and the scattered field from a single raindrop. Finally, data from the VPI and SU depolarization experiment are presented as verification of the new model, and a comparison is made with other theories and experiments. Aspects of the new model are: (1) spherical rather than plane waves are assumed, (2) the average drop diameter is used rather than a drop size distribution, and (3) it is simple enough so that the effect which changing one or more parameters has on the crosspolarization level is easily seen.

Processes regulating nitric oxide emissions from soils.

PubMed

Pilegaard, Kim

2013-07-05

Nitric oxide (NO) is a reactive gas that plays an important role in atmospheric chemistry by influencing the production and destruction of ozone and thereby the oxidizing capacity of the atmosphere. NO also contributes by its oxidation products to the formation of acid rain. The major sources of NO in the atmosphere are anthropogenic emissions (from combustion of fossil fuels) and biogenic emission from soils. NO is both produced and consumed in soils as a result of biotic and abiotic processes. The main processes involved are microbial nitrification and denitrification, and chemodenitrification. Thus, the net result is complex and dependent on several factors such as nitrogen availability, organic matter content, oxygen status, soil moisture, pH and temperature. This paper reviews recent knowledge on processes forming NO in soils and the factors controlling its emission to the atmosphere. Schemes for simulating these processes are described, and the results are discussed with the purpose of scaling up to global emission.

A Qualitative Evidence of the Breeding Sites of Anopheles arabiensis Patton (Diptera: Culicidae) in and Around Kassala Town, Eastern Sudan

PubMed Central

Hamza, Asma Mahmoud; El Rayah, El Amin

2016-01-01

Anopheles arabiensis Patton (Diptera: Culicidae) is considered the most efficient malaria vector in eastern Sudan. This study aims to characterize the breeding sites of An. arabiensis throughout the year in and around Kassala town, eastern Sudan. Diverse larval habitat types were visited and characterized based on the habitat type and chemical composition. Mosquito larvae were found in many diverse habitats. During the rainy season, rain pools and water bodies created by the seasonal Gash River serve as the main breeding sites. In the dry season, irrigation canals, seepage from water pipes, neglected wells, artificial containers, and man-made ditches serve as the main breeding sites. Breeding water showed a pH of 7.9 and a low concentration of the total dissolved salts. The results of this study may be considered in planning and implementing larval control programs in the area. PMID:27547039

Transport of carbon-bearing dusts from Iraq to Japan during Iraq's War

NASA Astrophysics Data System (ADS)

Tazaki, Kazue; Wakimoto, Rie; Minami, Yukiya; Yamamoto, Masayoshi; Miyata, Koshirou; Sato, Kazuhiro; Saji, Ichiro; Chaerun, S. Khodijah; Zhou, Guoping; Morishita, Tomoaki; Asada, Ryuji; Segawa, Hiromi; Imanishi, Hiroki; Kato, Rie; Otani, Yusuke; Watanabe, Tomoko

Rainwater collected during the period of February-April, 2003 in Kanazawa University and Hakui, Ishikawa Prefecture, Japan, was investigated by ion chromatography of the dissolved ions, and Scanning electron microscopy equipped with energy dispersive analyzer (SEM-EDX), electron microprobe analyzer (EPMA), transmission electron microscopy, and X-ray powder diffraction (XRD) analyses of the filtered samples. The pH, Eh, EC, dissolved oxygen (DO) and depleted U (DU) of the rainwater were also measured. The results show a rare case with low pH value of rain and high value of electrical conductivity (EC) in the rainwater during certain period. The NO 3-, SO 42- and NH 4+ concentrations on 26th March, show quite high values after oil field fires on 21st March 2003. The powdery dust and carbon-bearing nm sized particles contained in the rainwater have characteristics different from that of the Asian dust (Kosa). Since 21 March, 2003 the Iraq plunged into the war, the 9 oil field fires were reported on 25 March, 2003 in Rumaylah oil field near the borderline of Kuwait. The first precipitation was caught in Kanazawa on 24 March, 2003. The pH value of the rainwater indicated a strong acid rain (pH 3.6) with black powdery dusts. The acid rain on 27th March to 2nd April (pH 3.4-4.3; 5-17 mm) associated with WNW wind (2.7-4.1 m/s) has continued to the first 10 days of April in Kanazawa, during the 9 oil fields were burning in Iraq. The EC in rainwater collected from 24 March to 15 April, 2003, shows high concentrations of ions, suggesting high contents of water soluble-carbon particles and soot. In the meantime, it was the highest season of sandstorms at bare dried land in Iraq from the end of March to the beginning of April. Westerly wind blew around 5500 m high, and the sandstorm with 2000 m wide was transported by strong wind to Zagros 3000 m high mountains. The hot wind hit the Zagros Mountains and easily to join and rise to Westerly wind high by a rising air current. The 234U/ 238U activity (around 0.2) in typical depleted uranium (DU) is quite low compared with that (around 1.0) in natural uranium. The contamination of DU from the Iraq conflict may be, if any, negligibly small on undetectable level. On the other hand, the powdery dusts and carbon-bearing particles of rainwater have been produced by combustion of oil field in Iraq and they are directly cycling in our planet by Westerly wind. Black carbon particles are a product of incomplete combustion, and are the principal light-absorbing atmospheric aerosol. The result reminds us of the scientific values of short-term atmospheric environment records during Iraq's War. This has consequences for primary production of powdery dusts coming from Iraq to the atmosphere over half the globe away.

Effects of different CO2 concentration on growth and photosynthetic of rain tree plants (Albizia saman jacq.Merr)

NASA Astrophysics Data System (ADS)

Fathurrahman, F.; Nizam, M. S.; Wan Juliana, W. A.; Doni, Febri; NorLailatul, W. M.; Che Radziah, C. M. Z.

2016-11-01

A preliminary study was conducted to determine the effect of elevated carbon dioxide (CO2) in rain tree growth under controllable growth chamber. The tolerance towards CO2 absorption in the photosynthesis process for the growth of tree rain is still unknown. In this study, rain tree seedlings were incubated for three months in a growth chamber with three different CO2 concentration treatment: GC1 (300 ppm), GC2 (600 ppm) and GC3 (900 ppm) at similar condition of temperature (28°C), humidity (60%) and lighting (1200 lux). The results showed that increased CO2 significantly increase the growth rate and chlorophyll content in rain tree. The results of this study add to the further understanding of how the improvement of the growth and physiological characteristics of rain tree was affected by CO2 enrichment treatment. This research can for used for global warming mitigation in the future.

Trace elements in urban and suburban rainfall, Mersin, Northeastern Mediterranean

NASA Astrophysics Data System (ADS)

Özsoy, Türkan; Örnektekin, Sermin

2009-10-01

Spatial/temporal variabilities of rainwater constituents are examined based on soluble/insoluble trace elements, pH and electrical conductivity measurements in rainfall sampled during December 2003-May 2005 at two urban and two suburban sites in Mersin, an industrialized city of 850,000 inhabitants on the southern coast of Turkey. In the analyses, backward air mass trajectories for rainy days were used in addition to factor analyses, enrichment factors, phase distributions and correlations between trace elements. The pH varied from 4.8 to 8.5 with an average value of 6.2, reflecting a mainly alkaline regime. Mean concentrations of trace elements collected from urban and suburban sites are spatially variable. Based on the overall data, total concentrations of trace elements were ordered as Ca > Na > Fe > Al > Mg > K > Zn > Mn > Sr > Pb > Ni > Cr > Ba > Cu > Co > Cd. Mainly terrigeneous (Ca, Fe, Al) and, to a lesser extent, sea salt particles (Na, Mg) were shown to be the major source of trace elements. Excluding major cations, the solubilities of trace elements were found to be ordered as Sr > Zn > Ba > Mn > Cu > Ni > Cr > Fe > Al, confirming the lower solubility of crustal elements. Cd, Co and Pb were excluded from the above evaluation because of the low numbers of soluble samples allowing quantitative measurements. The solubilities of Al, Fe, Mn and particularly of Ni were found to be considerably lower than those reported for various sites around the world, most likely due to the effect of pH. During the entire sampling period, a total of 28 dust transport episodes associated with 31 red rain events were identified. Extremely high mean concentration ratios of Al (8.2), Fe (14.4) and Mn (13.1) were observed in red rain, compared to normal rain. The degree of this enhancement displayed a decrease from crustal to anthropogenic origin elements and the lowest enhancements were found for anthropogenic origin elements of Zn and Cd (both having a ratio of 1.1). Aerosol dust was found to be the main source of almost all analyzed elements in Mersin precipitation, regardless that they are crustal or anthropic derived elements. The magnitude of crustal source contribution to trace element budget of precipitation was at its highest levels for crustal originated elements, most probably due to much higher scavenging ratios of crustal elements compared to anthropogenic ones.

Combined effects of lead and acid rain on photosynthesis in soybean seedlings.

PubMed

Hu, Huiqing; Wang, Lihong; Liao, Chenyu; Fan, Caixia; Zhou, Qing; Huang, Xiaohua

2014-10-01

To explore how lead (Pb) and acid rain simultaneously affect plants, the combined effects of Pb and acid rain on the chlorophyll content, chlorophyll fluorescence reaction, Hill reaction rate, and Mg(2+)-ATPase activity in soybean seedlings were investigated. The results indicated that, when soybean seedlings were treated with Pb or acid rain alone, the chlorophyll content, Hill reaction rate, Mg(2+)-ATPase activity, and maximal photochemical efficiency (F(v)/F(m)) were decreased, while the initial fluorescence (F 0) and maximum quantum yield (Y) were increased, compared with those of the control. The combined treatment with Pb and acid rain decreased the chlorophyll content, Hill reaction rate, Mg(2+)-ATPase activity, F(v)/F(m), and Y and increased F 0 in soybean seedlings. Under the combined treatment with Pb and acid rain, the two factors showed additive effects on the chlorophyll content in soybean seedlings and exhibited antagonistic effects on the Hill reaction rate. Under the combined treatment with high-concentration Pb and acid rain, the two factors exhibited synergistic effects on the Mg(2+)-ATPase activity, F 0, F v/F m, as well as Y. In summary, the inhibition of the photosynthetic process is an important physiological basis for the simultaneous actions of Pb and acid rain in soybean seedlings.

Seasonal and diel variation in xylem CO2 concentration and sap pH in sub-Mediterranean oak stems.

PubMed

Salomón, Roberto; Valbuena-Carabaña, María; Teskey, Robert; McGuire, Mary Anne; Aubrey, Doug; González-Doncel, Inés; Gil, Luis; Rodríguez-Calcerrada, Jesús

2016-04-01

Since a substantial portion of respired CO2 remains within the stem, diel and seasonal trends in stem CO2 concentration ([CO2]) are of major interest in plant respiration and carbon budget research. However, continuous long-term stem [CO2] studies are scarce, and generally absent in Mediterranean climates. In this study, stem [CO2] was monitored every 15min together with stem and air temperature, sap flow, and soil water storage during a growing season in 16 stems of Quercus pyrenaica to elucidate the main drivers of stem [CO2] at different temporal scales. Fluctuations in sap pH were also assessed during two growing seasons to evaluate potential errors in estimates of the concentration of CO2 dissolved in xylem sap ([CO2*]) calculated using Henry's law. Stem temperature was the best predictor of stem [CO2] and explained more than 90% and 50% of the variability in stem [CO2] at diel and seasonal scales, respectively. Under dry conditions, soil water storage was the main driver of stem [CO2]. Likewise, the first rains after summer drought caused intense stem [CO2] pulses, suggesting enhanced stem and root respiration and increased resistance to radial CO2 diffusion. Sap flow played a secondary role in controlling stem [CO2] variations. We observed night-time sap pH acidification and progressive seasonal alkalinization. Thus, if the annual mean value of sap pH (measured at midday) was assumed to be constant, night-time sap [CO2*] was substantially overestimated (40%), and spring and autumn sap [CO2*] were misestimated by 25%. This work highlights that diel and seasonal variations in temperature, tree water availability, and sap pH substantially affect xylem [CO2] and sap [CO2*]. © The Author 2016. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

Role of tropical cyclones in determining the fate of Bay of Bengal vapor contributed rain δ18O values

NASA Astrophysics Data System (ADS)

Sanyal, Prasanta; Basu, Sayak

2016-04-01

The evaluation of robust future climate prediction is well dependent on the cognition of past and present hydrological systems which could be traced through the oxygen isotopic composition (δ18O) of rain. Compared to Peninsular and Southern India, explanation for the variability in δ18O values of monsoonal rain is sparse for the Eastern India. Analysis (and published records) of Indian summer monsoon (ISM) rain at the entry point of Bay of Bengal (BoB) vapor into the continent showed the gradual depletion of 18O in the ISM rain is determined by the surface run-off and location of cyclone generation in BoB. The timing and density of cyclones control the maxima in amount and minima in δ18O value of ISM rain and possibly also responsible for the long-term (last 10 years) decrease in rain δ18O values (and amount). Large spatial variation and temporally robustness of weak and insignificant amount effect suggested reconsideration of reconstructed past climate records along the track of BoB vapor. The memory effect of atmospheric vapor is found to lower the amount effect.

A laboratory system for the investigation of rain fade compensation techniques for Ka-band satellites

NASA Technical Reports Server (NTRS)

Svoboda, James S.; Kachmar, Brian A.

1993-01-01

The design and performance of a rain fade simulation/counteraction system on a laboratory simulated 30/20 GHz, time division multiple access (TDMA) satellite communications testbed is evaluated. Severe rain attenuation of electromagnetic radiation at 30/20 GHz occurs due to the carrier wavelength approaching the water droplet size. Rain in the downlink path lowers the signal power present at the receiver, resulting in a higher number of bit errors induced in the digital ground terminal. The laboratory simulation performed at NASA Lewis Research Center uses a programmable PIN diode attenuator to simulate 20 GHz satellite downlink geographic rain fade profiles. A computer based network control system monitors the downlink power and informs the network of any power threshold violations, which then prompts the network to issue commands that temporarily increase the gain of the satellite based traveling wave tube (TWT) amplifier. After the rain subsides, the network returns the TWT to the normal energy conserving power mode. Bit error rate (BER) data taken at the receiving ground terminal serves as a measure of the severity of rain degradation, and also evaluates the extent to which the network can improve the faded channel.

Feasibility for Application of Soil Bioengineering Techniques to Natural Wastewater Treatment Systems

DTIC Science & Technology

1992-12-01

surface erosion control technique, providing shallow soil protection against the impact of heavy rains and running water. As adventitious rooting... soil protection against the impact of heavy rains and running water (Schiechtl, 1980). Figure 13 shows a typical brushmattress used as streambank

Effect of Olive mill wastewater spreading on soil wettability and acidity under different season in a semi humid area: A field study in Bait Reema - West Bank - Palestine

NASA Astrophysics Data System (ADS)

Tamimi, Nesreen; Marei Sawalha, Amer; Schaumann, Gabriele E.

2014-05-01

Olive mill wastewater (OMW) is generated seasonally in large amounts during the olive oil production in Palestine, and it is often disposal of in uncontrolled manner into the open environment. OMW has a high amount of phototoxic compounds, high salinity and acidity and therefore is challenging when disposed on soil. The objective of this study was to study the persistence and degree of water repellency during different season of OMW application in soil samples (0-5 cm deep), and to elucidate how extent this phenomenon is associated with soil acidity, to analyze the relationships between soil water repellency and environmental factors including, temperature and moisture and to describe the seasonal variation in the phenol concentration of the soil. In order to understand how climatic conditions at the time of OMW disposal affect the development of soil water repelleny in field, soil acidity and phenol content in soil, we conducted a field study in Bait Reema village in the West Bank - Palestine. The study site is characterized by 1.5 m thick brown rendzina and has an annual average rainfall of 550 mm. On an extensively used olive orchard field, we implemented 16 plots (2.5 x 3.5 m). OMW application (14 L / m2) was conducted either in winter, spring or summer on two replicate plots distributed randomly among the 16 plots. To test the effect of soil moisture on the persistence of OMW effects, we implemented an OMW application in summer on two additional plots, but kept those plots moist before and after OMW application until start of the rain season. For each of the treatment variants, we implemented two control plots which were treated in the same way as their counterparts, but with tap water. Soil samples (0-5 cm) were collected after 2 days, 3 weeks, 6 weeks, 3 months, 6 months , 9 months, 12 months , and 18 months. pH was determined and analyzed in aqueous soil extracts (1:5), the total phenol content was determined by using Folin-Ciocalteu's reagent, soil water repellency was measured in the field by using the water drop penetration time (WDPT) for control and treated plots. Persistence and intensity of water repellency varied between different times of OMW application. While all control plots remained wettable during the whole year, OMW induced water repellency in all treatments. A high initial WDPT on the (wet) field following OMW winter application rather indicates limitation in hydraulic conductivity than water repellency, but repellency developed gradually during the hot summer time following OMW application (spring and summer plots) and the extent of hydrophobization was strongest in the dry summer application plots, intermediate in the spring application plots and weakest in the moist summer application. Water repellency in all treatements disappeared during the first rain season following OMW. pH was s reduced by OMW application and resulted in significant soil acidification. Soil pH was initially reduced by up to 0.5 pH units. In addition, we found the high initial phenol concentration on the (wet) field following OMW winter application indicates limitation in infiltration rate, while it was higher in summer OMW application when compared to spring OMW application. Keywords: Olive mill wastewater, Tap water, Water drop penetration time, Acidity, Total phenol.

Degradation of Root Community Traits as Indicator for Transformation of Tropical Lowland Rain Forests into Oil Palm and Rubber Plantations

PubMed Central

Edy, Nur; Meyer, Marike; Corre, Marife D.; Polle, Andrea

2015-01-01

Conversion of tropical forests into intensely managed plantations is a threat to ecosystem functions. On Sumatra, Indonesia, oil palm (Elaeis guineensis) plantations are rapidly expanding, displacing rain forests and extensively used rubber (Hevea brasiliensis) agro-forests. Here, we tested the influence of land use systems on root traits including chemical traits (carbon, nitrogen, mineral nutrients, potentially toxic elements [aluminium, iron] and performance traits (root mass, vitality, mycorrhizal colonization). Traits were measured as root community-weighed traits (RCWTs) in lowland rain forests, in rubber agro-forests mixed with rain forest trees, in rubber and oil palm plantations in two landscapes (Bukit Duabelas and Harapan, Sumatra). We hypothesized that RCWTs vary with land use system indicating increasing transformation intensity and loss of ecosystem functions. The main factors found to be related to increasing transformation intensity were declining root vitality and root sulfur, nitrogen, carbon, manganese concentrations and increasing root aluminium and iron concentrations as well as increasing spore densities of arbuscular mycorrhizas. Mycorrhizal abundance was high for arbuscular and low for ectomycorrhizas and unrelated to changes in RCWTs. The decline in RCWTs showed significant correlations with soil nitrogen, soil pH and litter carbon. Thus, our study uncovered a relationship between deteriorating root community traits and loss of ecosystem functionality and showed that increasing transformation intensity resulted in decreasing root nutrition and health. Based on these results we suggest that land management that improves root vitality may enhance the ecological functions of intense tropical production systems. PMID:26366576

Degradation of Root Community Traits as Indicator for Transformation of Tropical Lowland Rain Forests into Oil Palm and Rubber Plantations.

PubMed

Sahner, Josephine; Budi, Sri Wilarso; Barus, Henry; Edy, Nur; Meyer, Marike; Corre, Marife D; Polle, Andrea

2015-01-01

Conversion of tropical forests into intensely managed plantations is a threat to ecosystem functions. On Sumatra, Indonesia, oil palm (Elaeis guineensis) plantations are rapidly expanding, displacing rain forests and extensively used rubber (Hevea brasiliensis) agro-forests. Here, we tested the influence of land use systems on root traits including chemical traits (carbon, nitrogen, mineral nutrients, potentially toxic elements [aluminium, iron] and performance traits (root mass, vitality, mycorrhizal colonization). Traits were measured as root community-weighed traits (RCWTs) in lowland rain forests, in rubber agro-forests mixed with rain forest trees, in rubber and oil palm plantations in two landscapes (Bukit Duabelas and Harapan, Sumatra). We hypothesized that RCWTs vary with land use system indicating increasing transformation intensity and loss of ecosystem functions. The main factors found to be related to increasing transformation intensity were declining root vitality and root sulfur, nitrogen, carbon, manganese concentrations and increasing root aluminium and iron concentrations as well as increasing spore densities of arbuscular mycorrhizas. Mycorrhizal abundance was high for arbuscular and low for ectomycorrhizas and unrelated to changes in RCWTs. The decline in RCWTs showed significant correlations with soil nitrogen, soil pH and litter carbon. Thus, our study uncovered a relationship between deteriorating root community traits and loss of ecosystem functionality and showed that increasing transformation intensity resulted in decreasing root nutrition and health. Based on these results we suggest that land management that improves root vitality may enhance the ecological functions of intense tropical production systems.

A statistical rain attenuation prediction model with application to the advanced communication technology satellite project. 1: Theoretical development and application to yearly predictions for selected cities in the United States

NASA Technical Reports Server (NTRS)

Manning, Robert M.

1986-01-01

A rain attenuation prediction model is described for use in calculating satellite communication link availability for any specific location in the world that is characterized by an extended record of rainfall. Such a formalism is necessary for the accurate assessment of such availability predictions in the case of the small user-terminal concept of the Advanced Communication Technology Satellite (ACTS) Project. The model employs the theory of extreme value statistics to generate the necessary statistical rainrate parameters from rain data in the form compiled by the National Weather Service. These location dependent rain statistics are then applied to a rain attenuation model to obtain a yearly prediction of the occurrence of attenuation on any satellite link at that location. The predictions of this model are compared to those of the Crane Two-Component Rain Model and some empirical data and found to be very good. The model is then used to calculate rain attenuation statistics at 59 locations in the United States (including Alaska and Hawaii) for the 20 GHz downlinks and 30 GHz uplinks of the proposed ACTS system. The flexibility of this modeling formalism is such that it allows a complete and unified treatment of the temporal aspects of rain attenuation that leads to the design of an optimum stochastic power control algorithm, the purpose of which is to efficiently counter such rain fades on a satellite link.

Seed dispersal limitations shift over time in tropical forest restoration.

PubMed

Reid, J Leighton; Holl, Karen D; Zahawi, Rakan A

2015-06-01

Past studies have shown that tropical forest regeneration on degraded farmlands is initially limited by lack of seed dispersal, but few studies have tracked changes in abundance and composition of seed rain past the first few years after land abandonment. We measured seed rain for 12 months in 10 6-9-year-old restoration sites and five mature, reference forests in southern Costa Rica in order to learn (1) if seed rain limitation persists past the first few years of regeneration; (2) how restoration treatments influence seed community structure and composition; and (3) whether seed rain limitation is contingent on landscape context. Each restoration site contained three 0.25-ha treatment plots: (1) a naturally regenerating control, (2) tree islands, and (3) a mixed-species tree plantation. Sites spanned a deforestation gradient with 9-89% forest area within 500 m around the treatment plots. Contrary to previous studies, we found that tree seeds were abundant and ubiquitous across all treatment plots (585.1 ± 142.0 seeds · m(-2) · yr(-1) [mean ± SE]), indicating that lack of seed rain ceased to limit forest regeneration within the first decade of recovery. Pioneer trees and shrubs comprised the vast majority of seeds, but compositional differences between restoration sites and reference forests were driven by rarer, large-seeded species. Large, animal-dispersed tree seeds were more abundant in tree islands (4.6 ± 2.9 seeds · m(-2) · yr(-1)) and plantations (5.8 ± 3.0 seeds · m(-2) · yr(-1)) than control plots (0.2 ± 0.1 seeds · m(-2) · yr(-1)), contributing to greater tree species richness in actively restored plots. Planted tree species accounted for < 1% of seeds. We found little evidence for landscape forest cover effects on seed rain, consistent with previous studies. We conclude that seed rain limitation shifted from an initial, complete lack of tree seeds to a specific limitation on large-seeded, mature forest species over the first decade. Although total seed abundance was equal among restoration treatments, tree plantations and tree islands continued to diversify seed rain communities compared to naturally regenerating controls. Compositional differences between regenerating plots and mature forests suggest that large-seeded tree species are appropriate candidates for enrichment planting.

Implications of Warm Rain in Shallow Cumulus and Congestus Clouds for Large-Scale Circulations

NASA Astrophysics Data System (ADS)

Nuijens, Louise; Emanuel, Kerry; Masunaga, Hirohiko; L'Ecuyer, Tristan

2017-11-01

Space-borne observations reveal that 20-40% of marine convective clouds below the freezing level produce rain. In this paper we speculate what the prevalence of warm rain might imply for convection and large-scale circulations over tropical oceans. We present results using a two-column radiative-convective model of hydrostatic, nonlinear flow on a non-rotating sphere, with parameterized convection and radiation, and review ongoing efforts in high-resolution modeling and observations of warm rain. The model experiments investigate the response of convection and circulation to sea surface temperature (SST) gradients between the columns and to changes in a parameter that controls the conversion of cloud condensate to rain. Convection over the cold ocean collapses to a shallow mode with tops near 850 hPa, but a congestus mode with tops near 600 hPa can develop at small SST differences when warm rain formation is more efficient. Here, interactive radiation and the response of the circulation are crucial: along with congestus a deeper moist layer develops, which leads to less low-level radiative cooling, a smaller buoyancy gradient between the columns, and therefore a weaker circulation and less subsidence over the cold ocean. The congestus mode is accompanied with more surface precipitation in the subsiding column and less surface precipitation in the deep convecting column. For the shallow mode over colder oceans, circulations also weaken with more efficient warm rain formation, but only marginally. Here, more warm rain reduces convective tops and the boundary layer depth—similar to Large-Eddy Simulation (LES) studies—which reduces the integrated buoyancy gradient. Elucidating the impact of warm rain can benefit from large-domain high-resolution simulations and observations. Parameterizations of warm rain may be constrained through collocated cloud and rain profiling from ground, and concurrent changes in convection and rain in subsiding and convecting branches of circulations may be revealed from a collocation of space-borne sensors, including the Global Precipitation Measurement (GPM) and upcoming Aeolus missions.

Humid tropical rain forest has expanded into eucalypt forest and savanna over the last 50 years

PubMed Central

Tng, David Y P; Murphy, Brett P; Weber, Ellen; Sanders, Gregor; Williamson, Grant J; Kemp, Jeanette; Bowman, David M J S

2012-01-01

Tropical rain forest expansion and savanna woody vegetation thickening appear to be a global trend, but there remains uncertainty about whether there is a common set of global drivers. Using geographic information techniques, we analyzed aerial photography of five areas in the humid tropics of northeastern Queensland, Australia, taken in the 1950s and 2008, to determine if changes in rain forest extent match those reported for the Australian monsoon tropics using similar techniques. Mapping of the 1950s aerial photography showed that of the combined study area (64,430 ha), 63% was classified as eucalypt forests/woodland and 37% as rain forest. Our mapping revealed that although most boundaries remained stable, there was a net increase of 732 ha of the original rain forest area over the study period, and negligible conversion of rain forest to eucalypt forest/woodland. Statistical modeling, controlling for spatial autocorrelation, indicated distance from preexisting rain forest as the strongest determinant of rain forest expansion. Margin extension had a mean rate across the five sites of 0.6 m per decade. Expansion was greater in tall open forest types but also occurred in shorter, more flammable woodland vegetation types. No correlations were detected with other local variables (aspect, elevation, geology, topography, drainage). Using a geographically weighted mean rate of rain forest margin extension across the whole region, we predict that over 25% of tall open forest (a forest type of high conservation significance) would still remain after 2000 years of rain forest expansion. This slow replacement is due to the convoluted nature of the rain forest boundary and the irregular shape of the tall open forest patches. Our analyses point to the increased concentration of atmospheric CO2 as the most likely global driver of indiscriminate rain forest expansion occurring in northeastern Australia, by increasing tree growth and thereby overriding the effects of fire disturbance. PMID:22408724

Can salt on an optical rain gauge lens affect performance?

NASA Technical Reports Server (NTRS)

Bliven, Larry F.

1994-01-01

The optical rain gauge (ORG) by ScTI is designed to be tolerant to reduction of infrared beam intensity due to a dirty lens. Recently there is interest in long term use of optical gauges onboard buoys at sea. Because of logistics, these systems are serviced infrequently, i.e., every several months. Due to the proximity of the gauges to the sea surface, salt can be expected to be deposited on the lens. To obtain an indication of the potential for dirty lens to affect the ORG calibration, two simple experiments were conducted. In the control experiment, a sample ORG was compared to three other ORG's during natural rain events. Next a translucent mask was placed on the transmitter lens of the sample ORG and again data were collected under natural rain conditions. The mask reduced the gain of the perturbed ORG by about 30%. The perturbed ORG operated rather well in that the mask only causes a change in the gain and does not cause data drop out at low rain rates. However, the reduced gain would seriously impact an assessment of rain statistics.

Aerosol and precipitation chemistry in the southwestern United States: spatiotemporal trends and interrelationships

PubMed Central

Sorooshian, A.; Shingler, T.; Harpold, A.; Feagles, C. W.; Meixner, T.; Brooks, P. D.

2013-01-01

This study characterizes the spatial and temporal patterns of aerosol and precipitation composition at six sites across the United States Southwest between 1995 and 2010. Precipitation accumulation occurs mostly during the wintertime (December–February) and during the monsoon season (July–September). Rain and snow pH levels are usually between 5–6, with crustal-derived species playing a major role in acid neutralization. These species (Ca2+, Mg2+, K+, Na+) exhibit their highest concentrations between March and June in both PM2.5 and precipitation due mostly to dust. Crustal-derived species concentrations in precipitation exhibit positive relationships with SO42−, NO3−, and Cl–, suggesting that acidic gases likely react with and partition to either crustal particles or hydrometeors enriched with crustal constituents. Concentrations of particulate SO42− show a statistically significant correlation with rain SO42− unlike snow SO42−, which may be related to some combination of the vertical distribution of SO42− (and precursors) and the varying degree to which SO42−-enriched particles act as cloud condensation nuclei versus ice nuclei in the region. The coarse : fine aerosol mass ratio was correlated with crustal species concentrations in snow unlike rain, suggestive of a preferential role of coarse particles (mainly dust) as ice nuclei in the region. Precipitation NO3− : SO42− ratios exhibit the following features with potential explanations discussed: (i) they are higher in precipitation as compared to PM2.5; (ii) they exhibit the opposite annual cycle compared to particulate NO3− : SO42− ratios; and (iii) they are higher in snow relative to rain during the wintertime. Long-term trend analysis for the monsoon season shows that the NO3− : SO42− ratio in rain increased at the majority of sites due mostly to air pollution regulations of SO42− precursors. PMID:24432030

Aerosol and precipitation chemistry in the southwestern United States: spatiotemporal trends and interrelationships.

PubMed

Sorooshian, A; Shingler, T; Harpold, A; Feagles, C W; Meixner, T; Brooks, P D

2013-08-01

This study characterizes the spatial and temporal patterns of aerosol and precipitation composition at six sites across the United States Southwest between 1995 and 2010. Precipitation accumulation occurs mostly during the wintertime (December-February) and during the monsoon season (July-September). Rain and snow pH levels are usually between 5-6, with crustal-derived species playing a major role in acid neutralization. These species (Ca 2+ , Mg 2+ , K + , Na + ) exhibit their highest concentrations between March and June in both PM 2.5 and precipitation due mostly to dust. Crustal-derived species concentrations in precipitation exhibit positive relationships with [Formula: see text], [Formula: see text], and Cl - , suggesting that acidic gases likely react with and partition to either crustal particles or hydrometeors enriched with crustal constituents. Concentrations of particulate [Formula: see text] show a statistically significant correlation with rain [Formula: see text] unlike snow [Formula: see text], which may be related to some combination of the vertical distribution of [Formula: see text] (and precursors) and the varying degree to which [Formula: see text]-enriched particles act as cloud condensation nuclei versus ice nuclei in the region. The coarse : fine aerosol mass ratio was correlated with crustal species concentrations in snow unlike rain, suggestive of a preferential role of coarse particles (mainly dust) as ice nuclei in the region. Precipitation [Formula: see text] : [Formula: see text] ratios exhibit the following features with potential explanations discussed: (i) they are higher in precipitation as compared to PM 2.5 ; (ii) they exhibit the opposite annual cycle compared to particulate [Formula: see text] : [Formula: see text] ratios; and (iii) they are higher in snow relative to rain during the wintertime. Long-term trend analysis for the monsoon season shows that the [Formula: see text] : [Formula: see text] ratio in rain increased at the majority of sites due mostly to air pollution regulations of [Formula: see text] precursors.

Seasonal and spatial patterns of metals at a restored copper mine site. I. Stream copper and zinc

USGS Publications Warehouse

Bambic, D.G.; Alpers, Charles N.; Green, P.G.; Fanelli, E.; Silk, W.K.

2006-01-01

Seasonal and spatial variations in metal concentrations and pH were found in a stream at a restored copper mine site located near a massive sulfide deposit in the Foothill copper-zinc belt of the Sierra Nevada, California. At the mouth of the stream, copper concentrations increased and pH decreased with increased streamflow after the onset of winter rain and, unexpectedly, reached extreme values 1 or 2 months after peaks in the seasonal hydrographs. In contrast, aqueous zinc and sulfate concentrations were highest during low-flow periods. Spatial variation was assessed in 400 m of reach encompassing an acidic, metal-laden seep. At this seep, pH remained low (2-3) throughout the year, and copper concentrations were highest. In contrast, the zinc concentrations increased with downstream distance. These spatial patterns were caused by immobilization of copper by hydrous ferric oxides in benthic sediments, coupled with increasing downstream supply of zinc from groundwater seepage.

Breeding biology of the spotted salamander Ambystoma maculatum (Shaw) in acidic temporary ponds at Cape Cod, USA

USGS Publications Warehouse

Portnoy, J.W.

1990-01-01

The relationship between water chemistry and breeding success of spotted salamanders Ambystoma maculatum (Shaw) was examined in temporary woodland ponds on outer Cape Cod, Massachusetts in 1985 and 1986. Most pond waters were dilute (3median coductivity = 57 umhos cm-1 (1 umhos cm-1 = 0?1 mSm-1)), acidic (median pH = 4?82), and highly colored (median = 140 Pt-Co units). Most acidity was due to abundant organic acids. Salamander survival to hatching was over 80% at 8 of 12 ponds monitored. Complete mortality, preceded by gross abnormalities, was observed only among embryos in the most acidic spawning pond (pH 4?3-4?5) in both years. Embryo transfers between ponds and laboratory studies indicated that reduced survival was due to the interaction of low pH with high tannin-lignin concentration. The use of amphibian embryonic survival to indicate acid rain effects is complicated by multiple habitat parameters and should only be attempted in conjunction with long-term population monitoring.

Combined effects of lanthanum ion and acid rain on growth, photosynthesis and chloroplast ultrastructure in soybean seedlings.

PubMed

Wen, Kejia; Liang, Chanjuan; Wang, Lihong; Hu, Gang; Zhou, Qing

2011-07-01

Rare earth elements (REEs) have been accumulated in the agricultural environment. Acid rain is a serious environmental issue. In the present work, the effects of lanthanum ion (La(3+)) and acid rain on the growth, photosynthesis and chloroplast ultrastructure in soybean seedlings were investigated using the gas exchange measurements system, chlorophyll fluorometer, transmission electron microscopy and some biochemical techniques. It was found that although the growth and photosynthesis of soybean seedlings treated with the low concentration of La(3+) was improved, the growth and photosynthesis of soybean seedlings were obviously inhibited in the combined treatment with the low concentration of La(3+) and acid rain. At the same time, the chloroplast ultrastructure in the cell of soybean seedlings was destroyed. Under the combined treatment with the high concentration of La(3+) and acid rain, the chloroplast ultrastructure in the cell of soybean seedlings was seriously destroyed, and the growth and of photosynthesis were greatly decreased compared with those of the control, the single treatment with the high concentration of La(3+) and the single treatment with acid rain, respectively. The degree of decrease and destruction on chloroplast ultrastructure depended on the increases in the concentration of La(3+) and acid rain (H(+)). In conclusion, the combined pollution of La(3+) and acid rain obviously destroyed the chloroplast ultrastructure of cell and aggravated the harmful effect of the single La(3+) and acid rain on soybean seedlings. As a new combined pollutant, the harmful effect of REEs ions and acid rain on plant should be paid attention to. Copyright © 2011 Elsevier Ltd. All rights reserved.

Phytolacca americana from contaminated and noncontaminated soils of South Korea: Effects of elevated temperature, CO2 and simulated acid rain on plant growth response

USGS Publications Warehouse

Kim, Y.-O.; Rodriguez, R.J.; Lee, E.J.; Redman, R.S.

2008-01-01

Chemical analyses performed on the invasive weed Phytolacca americana (pokeweed) growing in industrially contaminated (Ulsan) and noncontaminated (Suwon) sites in South Korea indicated that the levels of phenolic compounds and various elements that include some heavy metals (Al, As, B, Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn) were statistically higher in Ulsan soils compared to Suwon soils with Al being the highest (>1,116 mg/l compared to 432 mg/l). Analysis of metals and nutrients (K, Na, Ca, Mg, Cl, NH4, N, P, S) in plant tissues indicated that accumulation occurred dominantly in plant leaves with Al levels being 33.8 times higher in Ulsan plants (PaU) compared to Suwon plants (PaS). The ability of PaU and PaS to tolerate stress was evaluated under controlled conditions by varying atmospheric CO2 and temperature and soil pH. When grown in pH 6.4 soils, the highest growth rate of PaU and PaS plants occurred at elevated (30??C) and non-elevated (25??C) temperatures, respectively. Both PaU and PaS plants showed the highest and lowest growth rates when exposed to atmospheric CO2 levels of 360 and 650 ppm, respectively. The impact of soil pH (2-6.4) on seed germination rates, plant growth, chlorophyll content, and the accumulation of phenolics were measured to assess the effects of industrial pollution and global-warming-related stresses on plants. The highest seed germination rate and chlorophyll content occurred at pH 2.0 for both PaU and PaS plants. Increased pH from 2-5 correlated to increased phenolic compounds and decreased chlorophyll content. However, at pH 6.4, a marked decrease in phenolic compounds, was observed and chlorophyll content increased. These results suggest that although plants from Ulsan and Suwon sites are the same species, they differ in the ability to deal with various stresses. ?? 2008 Springer Science+Business Media, LLC.

Rain-fed fig yield as affected by rainfall distribution

NASA Astrophysics Data System (ADS)

Bagheri, Ensieh; Sepaskhah, Ali Reza

2014-08-01

Variable annual rainfall and its uneven distribution are the major uncontrolled inputs in rain-fed fig production and possibly the main cause of yield fluctuation in Istahban region of Fars Province, I.R. of Iran. This introduces a considerable risk in rain-fed fig production. The objective of this study was to find relationships between seasonal rainfall distribution and rain-fed fig production in Istahban region to determine the critical rainfall periods for rain-fed fig production and supplementary irrigation water application. Further, economic analysis for rain-fed fig production was considered in this region to control the risk of production. It is concluded that the monthly, seasonal and annual rainfall indices are able to show the effects of rainfall and its distribution on the rain-fed fig yield. Fig yield with frequent occurrence of 80 % is 374 kg ha-1. The internal rates of return for interest rate of 4, 8 and 12 % are 21, 58 and 146 %, respectively, that are economically feasible. It is concluded that the rainfall in spring especially in April and in December has negatively affected fig yield due to its interference with the life cycle of Blastophaga bees for pollination. Further, it is concluded that when the rainfall is limited, supplementary irrigation can be scheduled in March.

Effects of Carbon Addition on Iron and Phosphorus in a Highly Weathered Tropical Soil

NASA Astrophysics Data System (ADS)

Liptzin, D.; Silver, W. L.

2008-12-01

In the highly weathered iron (Fe)-rich soils of wet tropical forests, Fe may play a key role in controlling ecosystem processes because of its interactions with carbon (C) and phosphorus (P). The high NPP typical of tropical forests contributes significantly to the global C cycle. In Fe-rich tropical soils, NPP is thought to be limited by P. The periodic reducing conditions that occur in upland tropical soils may be associated with pulses of increased P availability because of the release of Fe-bound P during iron reduction. While little is known about the factors controlling Fe reduction in soils, it is likely that C availability plays a role. Typically, only simple C sources like acetate or glucose have been used to examine this limitation. However, the source of much of the C in nature is the complex mixture of organic compounds leached from leaves and litter. To investigate the linkages between Fe, C, and P, we compared the effects adding either acetate (200 mg C/L) or leaf leachate in low (50-100 mg C/L) or high (150-200 mg C/L) concentrations to incubated soils from a tropical rain forest in Puerto Rico under ambient atmospheric conditions. We measured pools of iron and phosphorus as well as pH at four time points over a month. Both Fe(II) and pH exhibited significant treatment effects, but not until the last sampling date. At this time, the Fe(II) concentration could explain 49% of the variability in soil pH. The pH was significantly higher in the acetate treatments than both the leaf leachate treatments. While Fe(II) concentration was significantly higher in the acetate treatment than the control and low leaf leachate treatment, there was no difference compared to the high leaf leachate treatment After one month microbial biomass P had increased significantly while the NaOH extractable organic P had decreased significantly. These changes suggest the rapid microbial uptake of P liberated from Fe. In conclusion, microbes appear to utilize more complex C in leaf leachate at a similar rate as acetate to promote Fe reduction. The simultaneous immobilization of P by microbes during the incubation suggests that periodic reducing conditions in the field may be associated with enhanced microbial activity and carbon cycling in these highly productive ecosystems.

The effect of poultry manure application rate and AlCl(3) treatment on bacterial fecal indicators in runoff.

PubMed

Brooks, J P; Adeli, A; McLaughlin, M R; Miles, D M

2012-12-01

Increasing costs associated with inorganic fertilizer have led to widespread use of broiler litter. Proper land application, typically limiting nutrient loss, is essential to protect surface water. This study was designed to evaluate litter-borne microbial runoff (heterotrophic plate count bacteria, staphylococci, Escherichia coli, enterococci, and Clostridium perfringens) while applying typical nutrient-control methods. Field studies were conducted in which plots with high and low litter rates, inorganic fertilizer, AlCl(3)-treated litter, and controls were rained on five times using a rain generator. Overall, microbial runoff from poultry litter applied plots was consistently greater (2-5 log(10) plot(-1)) than controls. No appreciable effect on microbial runoff was noted from variable litter application rate or AlCl(3) treatments, though rain event, not time, significantly affected runoff load. C. perfringens and staphylococci runoff were consistently associated with poultry litter application, during early rain events, while other indicators were unreliable. Large microbial runoff pulses were observed, ranging from 10(2) to 10(10) CFU plot(-1); however, only a small fraction of litter-borne microbes were recoverable in runoff. This study indicated that microbial runoff from litter-applied plots can be substantial, and that methods intended to reduce nutrient losses do not necessarily reduce microbial runoff.

Drivers of spatio-temporal changes in paddy soil pH in Jiangxi Province, China from 1980 to 2010.

PubMed

Guo, Xi; Li, Hongyi; Yu, Huimin; Li, Weifeng; Ye, Yingcong; Biswas, Asim

2018-02-09

The spatio-temporal distribution soil pH is critical for understanding the productivity and long-term sustainability of our agri-ecosystem. This study quantified the spatio-temporal distribution of paddy soil pH in Jiangxi province, China, and the potential driver of the change between 1980 and 2010. Data from the Soil Survey Information of Jiangxi province (1980s) and Jiangxi Soil Testing and Fertilizer Recommendation study (2010s) were collected and categorized into six pH ranges from strongly-acidic to strongly-alkaline with unit pH differences. Changes were calculated from the maps developed using the Pedological Knowledge base for 1980s data (without geolocation) and geostatistical methods for the 2010s data (geolocated). An overall 0.6-unit decrease and a major shift of soil pH from weakly-acidic (54% → 18%) to acidic (35% → 74%) was observed over the province in a scattered fashion with concentration in the central part and the Poyang Lake area. About half of the area under paddy cultivation went through acidification by at least one pH unit and 7% by at least 2 pH units, while 40% of the area remained unchanged. Excessive fertilizer application and acid-rain intensity contributed to the acidification. Thus, a more knowledge-based and comprehensive fertilizer management should be adopted to make paddy production sustainable in the province.

Introduction and analysis of several FY3C-MWHTS cloud/rain screening methods

NASA Astrophysics Data System (ADS)

Li, Xiaoqing

2017-04-01

Data assimilation of satellite microwave sounders are very important for numerical weather prediction. Fengyun-3C (FY-3C),launched in September, 2013, has two such sounders: MWTS (MicroWave Temperature Sounder) and MWHTS (MicroWave Humidity and Temperature Sounder). These data should be quality-controlled before assimilation and cloud/rain detection is one of the crucial steps. This paper introduced different cloud/rain detection methods based on MWHTS, VIRR (Visible and InfraRed Radiometer) and MWRI (Microwave Radiation Imager) observations. We designed 6 cloud/rain detection combinations and then analyzed the application effect of these schemes. The difference between observations and model simulations for FY-3C MWHTS channels were calculated as a parameter for analysis. Both RTTOV and CRTM were used to fast simulate radiances of MWHTS channels.

The effect of water on the ground nesting habits of the giant tropical ant, Paraponera clavata.

PubMed

Elahi, Robin

2005-11-18

The large predatory ant, Paraponera clavata, exerts measurable top-down effects in wet and moist Neotropical forests, and therefore its distribution has potential ecological implications. To determine how water affects the presence of this important predator, the ground nesting ecology of P. clavata was examined with respect to various habitat characteristics. Four hectares of disturbed Costa Rican lowland rain forest were surveyed for ant colonies to determine nest distribution patterns in wet and dry habitat; significantly more colonies were found in dry habitat. Seventeen of 19 nests built on slopes of > 5 degrees inclination were positioned on the downward side of the tree, possibly using the trunk as a shield against runoff during rain showers. Moisture and pH inside nests were significantly different from adjacent soil. These results suggest that water influences the ground nesting habits of P. clavata, thus ecological differences between comparatively wet and dry portions of tropical forests may arise from the relative abundance of this ant species.

Measurements of rain effects on an 18-GHz dual-polarized propagation link

NASA Technical Reports Server (NTRS)

Bostian, C. W.; Stutzman, W. L.; Wiley, P. H.; Marshall, R. E.

1976-01-01

The paper presents highlights of rain attenuation and depolarization data collected between August 1972 and March 1974 in an experimental setup consisting of a 1.43-km line-of-sight path with 1.22-m diam dual-polarized parabolic reflector antennas at each end. The antennas used question-mark mounted scalar feeds oriented to transmit or receive linearly polarized 17.65-GHz signals having electric field vectors at +45 deg and -45 deg from the vertical. Rain data were collected and analyzed for 24 individual storms in which the rain rate exceeded 10 mm/hr. Received signal levels were sampled once each second and stored by a small digital computer which controlled the experiment and performed preliminary data processing. The results are compared with a theoretical model presented by Wiley et al. (1974). Experimental cross-polarization isolation data are found to agree well with theoretical values, especially at high rain rates where the antenna effects are the least significant.

Consumer demand for green stormwater management technology in an urban setting: The case of Chicago rain barrels

NASA Astrophysics Data System (ADS)

Ando, Amy W.; Freitas, Luiz P. C.

2011-12-01

Hydrological disruption and water pollution from urbanization can be reduced if households in urban areas adopt decentralized storm water controls. We study a citywide municipal subsidized rain-barrel program in the third biggest city in the United States, Chicago, to explore what factors influence whether households purchase this sort of green storm water management technology in an urban setting. Specifically, we regress census-tract level data on the number of rain barrels adopted in different parts of the city on socioeconomic variables, data on local flood frequency, and features of the housing stock. We find that rain-barrel purchases are not correlated with local levels of flooding, even though city residents were told by program managers that rain barrels could alleviate local flooding. Instead, rain barrels are heavily concentrated in places with high-income attitudinally green populations. We do find more rain barrels were adopted in places close to rain-barrel distribution points and near sites of hydrological information campaigns; thus, policy makers might increase green-technology adoption in areas where they can do the most good by reducing transaction costs and providing education programs to those areas. Finally, our results indicate that owner occupancy is positively correlated with green-technology adoption. Low-rise rental housing may have inefficiently low levels of adoption, such that city managers might want to develop programs to encourage storm water management investments by landlords who do not live in their own properties.

Comparison of Mosquito Abundance From Biogents Sentinel 2.0 Traps With and Without Rain Covers.

PubMed

Cilek, James E; Weston, Joshua R; Richardson, Alec G

2017-06-01

Biogents Sentinel (BGS) traps have rapidly become a standard for adult Aedes aegypti surveillance. Several investigators have found that trap collections can be damaged easily by heavy dew or rain entering the trap intake port. In addition, water entering the trap may temporarily stop the fan, thus reducing the collection potential of the trap. We evaluated the effectiveness of a rain cover designed to minimize damage to mosquito trap collections from BGS 2.0 traps in a residential backyard in Jacksonville, FL. Rain covers consisted of white fiberglass 51-cm 2 sheets positioned 19, 29, and 39 cm above the air intake of the traps. One BGS trap did not have a rain cover and was used as a control standard for comparison. All traps were baited with the BG-Lure. Generally, traps with rain covers resulted in higher mosquito counts when compared with collections from uncovered traps. Overall mosquito abundance was greater from traps with the rain cover positioned at 29 cm, but this difference was not significantly different when compared with the other cover heights. Covers spaced 29 or 39 cm collected significantly more Culex quinquefasciatus compared with traps at 19 cm and no cover. Species diversity was greatest for BGS traps with the rain cover positioned at 29 cm followed by 39 cm, 19 cm, and no cover; however, differences in diversity among the traps, with or without covers, were not significant.

The Survival of Burkholderia pseudomallei in Liquid Media

PubMed Central

Robertson, Jeannie; Levy, Avram; Sagripanti, Jose-Luis; Inglis, Timothy J. J.

2010-01-01

We studied the effect of environmental parameters on the survival of Burkholderia pseudomallei. There was a small increase in bacterial count for up to 28 days in sterilized distilled water or rain water, in water at 20°C or 40°C, and in buffered solutions of pH 4 or higher. Counts of culturable B. pseudomallei declined at pH 3, in the presence of seawater or water with concentrations of 4% salt or higher, and under refrigeration. The morphological appearances of B. pseudomallei changed under conditions that maintained culturable numbers from bacilli to coccoid cells and spiral forms under pH or salt stress. These observations indicate that B. pseudomallei can endure nutrient-depleted environments as well as a wide range of pH, salt concentrations, and temperatures for periods of up to 28 days. The relative stability of B. pseudomallei under these conditions underlines the tenacity of this species and its potential for natural dispersal in water: in surface water collections, in managed water distribution systems, and through rainfall. These survival properties help explain the recent expansion of the known melioidosis endemic zone in Australia and may have played a part in recent melioidosis outbreaks. PMID:20065001

Evaluation of land use and water quality in an agricultural watershed in the USA indicates multiple sources of bacterial impairment.

PubMed

Wittman, Jacob; Weckwerth, Andrew; Weiss, Chelsea; Heyer, Sharon; Seibert, Jacob; Kuennen, Ben; Ingels, Chad; Seigley, Lynette; Larsen, Kirk; Enos-Berlage, Jodi

2013-12-01

Pathogens are the number one cause of impairments of assessed rivers and streams in the USA and pose a significant human health hazard. The Dry Run Creek Watershed in Northeast Iowa has been designated as impaired by the State of Iowa because of high levels of Escherichia coli bacteria. To investigate the nature of this impairment, land use and stream bank assessments were coupled with comprehensive water quality monitoring. Physical, chemical, and biological parameters were measured at 13 different sites in the watershed, including pH, temperature, conductivity, dissolved oxygen, turbidity, total Kjeldahl nitrogen, ammonia-N, nitrate + nitrite-N, total phosphorus, and E. coli. In addition, benthic macroinvertebrate communities were analyzed at seven sites, and optical brightener tests were performed late in the season. Results identified segments of the watershed that were more prominent contributors of E. coli, and correlations were observed between levels of E. coli and several chemical parameters, including ammonia-N, total Kjeldahl nitrogen, and total phosphorus. Interestingly, distinct sites emerged as more prominent contributors of these elements during rain vs. non-rain events, suggesting different types of sources. Both the amount of rainfall and the time elapsed between the rain event and the sampling influenced E. coli levels during wet weather conditions. Nitrate + nitrite-N displayed a unique response to rain events compared with the other parameters, suggesting a different delivery route. Analyses of benthic macroinvertebrate communities were consistent with pollution trends. Collectively, these data suggest distinct agriculturally related E. coli contributions, as well as specific areas and practices for water quality improvement strategies. This study can serve as a resource for evaluating agricultural watersheds that are impaired for bacteria.

Space communication link propagation data for selected cities within the multiple beam and steerable antenna coverage areas of the advanced communications technology satellite

NASA Technical Reports Server (NTRS)

Manning, Robert M.

1988-01-01

Rain attenuation propagation data for 68 cities within the coverage area of the multiple beam and steerable antennas of the Advanced Communications Technology Satellite (ACTS) are presented. These data provide the necessary data base for purposes of communication link power budgeting and rain attenuation mitigation controller design. These propagation parameters are derived by applying the ACTS Rain Attenuation Prediction Model to these 68 locations. The propagation parameters enumerated in tabular form for each location are as follows: (1) physical description of the link and location (e.g., latitude, longitude, antenna elevation angle, etc.), link availability versus attenuation margin (also in graphical form), fading time across fade depths of 3, 5, 8, and 15 dB versus fade duration, and required fade control response time for controller availabilities of 99.999, 99.99, 99.9, and 99 percent versus sub-threshold attenuation levels. The data for these specific locations can be taken to be representative of regions near these locations.

Phosphorus loading to tropical rain forest streams after clear-felling and burning in Sabah, Malaysia

NASA Astrophysics Data System (ADS)

Malmer, Anders

1996-07-01

Most estimates of P export from natural or disturbed humid tropical ecosystems by streams have been based only on export of dissolved P, even though P often is limiting and can be expected to be strongly associated to particles. Therefore loss of ignition (LOI) and particulate P (Ppart) analyses were made on organic and inorganic detritus resulting from surface erosion and on stream-suspended sediments in an undisturbed rain forest (control), as well as during and after conversion of rain forest into forest plantation. Control forest surface erosion and stream sediments consisted mainly of organics, and dissolved P (Pdiss) dominated over Ppart in stream water. The same relation was found after conversion, with a maximum mean Pdiss/Ppart ratio of up to 10 after burning, compared with 2-2.5 for control forests. This larger difference was assumed to depend on PO4 dissolved from ashes to larger concentrations than could be adsorbed during the short time (<1 hour) to reach peak flow during rainstorms.

Rain sampling device

DOEpatents

Nelson, D.A.; Tomich, S.D.; Glover, D.W.; Allen, E.V.; Hales, J.M.; Dana, M.T.

1991-05-14

The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of the precipitation from the chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device. 11 figures.

Rain sampling device

DOEpatents

Nelson, Danny A.; Tomich, Stanley D.; Glover, Donald W.; Allen, Errol V.; Hales, Jeremy M.; Dana, Marshall T.

1991-01-01

The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of said precipitation from said chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device.

Investigating Wind-Driven Rain Intrusion in Walls with the CARWASh

Treesearch

C.R. Boardman; Samuel V. Glass

2013-01-01

Wind-driven rain provides the primary external moisture load for exterior walls.Water absorption by the cladding, runoff, and penetration through the cladding or at details determine how a wall system performs. In this paper we describe a new laboratory facility that can create controlled outdoor and indoor conditions and use it to investigate the water...

Herbicides for site preparation...broadcast spray by mist blower tested against understory in Hawaii rain forest

Treesearch

Stanley B. Carpenter

1966-01-01

Two studies started in 1964 tested control of dense understory vegetation in Hawaii rain forests with herbicides applied by a large turbine blower spraying from widely spaced bulldozer lines. Brushkiller and Tordon 101 were effective on shrubs. Results on treefern were poor, but encouraging enough to merit additional study.

Environmental and biotic controls over aboveground biomass throughout a tropical rainforest

Treesearch

G.P. Asner; R.F. Hughes; T.A. Varga; D.E. Knapp; T. Kennedy-Bowdoin

2009-01-01

The environmental and biotic factors affecting spatial variation in canopy three-dimensional (3-D) structure and aboveground tree biomass (AGB) are poorly understood in tropical rain forests. We combined field measurements and airborne light detection and ranging (lidar) to quantify 3-D structure and AGB across a 5,016 ha rain forest reserve on the...

Spatial and Temporal Patterns of Throughfall Amounts and Solutes in a Tropical Montane Forest - Comparisons with Findings From Lowland Rain Forests

NASA Astrophysics Data System (ADS)

Zimmermann, A.

2007-05-01

The diverse tree species composition, irregular shaped tree crowns and a multi-layered forest structure affect the redistribution of rainfall in lower montane rain forests. In addition, abundant epiphyte biomass and associated canopy humus influence spatial patterns of throughfall. The spatial variability of throughfall amounts controls spatial patterns of solute concentrations and deposition. Moreover, the living and dead biomass interacts with the rainwater during the passage through the canopy and creates a chemical variability of its own. Since spatial and temporal patterns are intimately linked, the analysis of temporal solute concentration dynamics is an important step to understand the emerging spatial patterns. I hypothesized that: (1) the spatial variability of volumes and chemical composition of throughfall is particularly high compared with other forests because of the high biodiversity and epiphytism, (2) the temporal stability of the spatial pattern is high because of stable structures in the canopy (e.g. large epiphytes) that show only minor changes during the short term observation period, and (3) the element concentrations decrease with increasing rainfall because of exhausting element pools in the canopy. The study area at 1950 m above sea level is located in the south Ecuadorian Andes far away from anthropogenic emission sources and marine influences. Rain and throughfall were collected from August to October 2005 on an event and within-event basis for five precipitation periods and analyzed for pH, K, Na, Ca, Mg, NH4+, Cl-, NO3-, PO43-, TN, TP and TOC. Throughfall amounts and most of the solutes showed a high spatial variability, thereby the variability of H+, K, Ca, Mg, Cl- and NO3- exceeded those from a Brazilian tropical rain forest. The temporal persistence of the spatial patterns was high for throughfall amounts and varied depending on the solute. Highly persistent time stability patterns were detected for K, Mg and TOC concentrations. Time stability patterns of solute deposition were somewhat weaker than for concentrations for most of the solutes. Epiphytes strongly affected time stability patterns in that collectors situated below thick moss mats or arboreal bromeliads were in large part responsible for the extreme persistence with low throughfall amounts and high ion concentrations (H+ showed low concentrations). Rainfall solute concentrations were low compared with a variety of other tropical lowland and montane forest sites and showed a small temporal variability during the study period for both between and within-event dynamics, respectively. Throughfall solute concentrations were more within the range when compared with other sites and showed highly variable within-event dynamics. For most of the solutes, within-event concentrations did not reach low, constant concentrations in later event stages, rather concentrations fluctuated (e.g. Cl-) or increased (e.g. K and TOC). The within-event throughfall solute concentration dynamics in this lower montane rain forest contrast to recent observations from lowland tropical rain forests in Panama and Brazil. The observed within-event patterns are attributed (1) to the influence of epiphytes and associated canopy humus, and (2) to low rainfall intensities.

Aerosol deposition in the human respiratory tract

NASA Astrophysics Data System (ADS)

Winchester, John W.; Jones, Donald L.; Mu-tian, Bi

1984-04-01

Rising sulfur dioxide emissions from increased coal combustion present risks, not only of acid rain, but also to health by inhalation of the SO 2 and acid to the lung. We are investigating human inhalation of ppm SO 2 concentrations mixed with aerosol of submicrometer aqueous salt droplets to determine the effects on lung function and body chemistry. Unlike some investigators, we emphasize ammonium sulfate and trace element aerosol composition which simulates ambient air; aerosol pH, relative humidity, and temperature control to reveal gas-particle reaction mechanisms; and dose estimates from length of exposure, SO 2 concentration, and a direct measurement of respiratory deposition of aerosol as a function of particle size by cascade impactor sampling and elemental analysis by PIXE. Exposures, at rest or during exercise, are in a walk-in chamber at body temperature and high humidity to simulate Florida's summer climate. Lung function measurement by spirometry is carried out immediately after exposure. The results are significant in relating air quality to athletic performance and to public health in the southeastern United States.

A statistical rain attenuation prediction model with application to the advanced communication technology satellite project. 3: A stochastic rain fade control algorithm for satellite link power via non linear Markow filtering theory

NASA Technical Reports Server (NTRS)

Manning, Robert M.

1991-01-01

The dynamic and composite nature of propagation impairments that are incurred on Earth-space communications links at frequencies in and above 30/20 GHz Ka band, i.e., rain attenuation, cloud and/or clear air scintillation, etc., combined with the need to counter such degradations after the small link margins have been exceeded, necessitate the use of dynamic statistical identification and prediction processing of the fading signal in order to optimally estimate and predict the levels of each of the deleterious attenuation components. Such requirements are being met in NASA's Advanced Communications Technology Satellite (ACTS) Project by the implementation of optimal processing schemes derived through the use of the Rain Attenuation Prediction Model and nonlinear Markov filtering theory.

Can salvage logging affect seed dispersal by birds into burned forests?

NASA Astrophysics Data System (ADS)

Rost, J.; Pons, P.; Bas, J. M.

2009-09-01

The recovery of vegetation in Mediterranean ecosystems after wildfire is mostly a result of direct regeneration, since the same species existing before the fire regenerate on-site by seeding or resprouting. However, the possibility of plant colonization by dispersal of seeds from unburned areas remains poorly studied. We addressed the role of the frugivorous, bird-dependent seed dispersal (seed rain) of fleshy-fruited plants in a burned and managed forest in the second winter after a fire, before on-site fruit production had begun. We also assessed the effect on seed rain of different microhabitats resulting from salvage logging (erosion barriers, standing snags, open areas), as well as the microhabitats of unlogged patches and an unburned control forest, taking account of the importance of perches as seed rain sites. We found considerable seed rain by birds in the burned area. Seeds, mostly from Olive trees Olea europaea and Evergreen pistaches Pistacia lentiscus, belonged to plants fruiting only in surrounding unburned areas. Seed rain was heterogeneous, and depended on microhabitat, with the highest seed density in the unburned control forest but closely followed by the wood piles of erosion barriers. In contrast, very low densities were found under perches of standing snags. Furthermore, frugivorous bird richness seemed to be higher in the erosion barriers than elsewhere. Our results highlight the importance of this specific post-fire management in bird-dependent seed rain and also may suggest a consequent heterogeneous distribution of fleshy-fruited plants in burned and managed areas. However, there needs to be more study of the establishment success of dispersed seeds before an accurate assessment can be made of the role of bird-mediated seed dispersal in post-fire regeneration.

A new method for automated dynamic calibration of tipping-bucket rain gauges

USGS Publications Warehouse

Humphrey, M.D.; Istok, J.D.; Lee, J.Y.; Hevesi, J.A.; Flint, A.L.

1997-01-01

Existing methods for dynamic calibration of tipping-bucket rain gauges (TBRs) can be time consuming and labor intensive. A new automated dynamic calibration system has been developed to calibrate TBRs with minimal effort. The system consists of a programmable pump, datalogger, digital balance, and computer. Calibration is performed in two steps: 1) pump calibration and 2) rain gauge calibration. Pump calibration ensures precise control of water flow rates delivered to the rain gauge funnel; rain gauge calibration ensures precise conversion of bucket tip times to actual rainfall rates. Calibration of the pump and one rain gauge for 10 selected pump rates typically requires about 8 h. Data files generated during rain gauge calibration are used to compute rainfall intensities and amounts from a record of bucket tip times collected in the field. The system was tested using 5 types of commercial TBRs (15.2-, 20.3-, and 30.5-cm diameters; 0.1-, 0.2-, and 1.0-mm resolutions) and using 14 TBRs of a single type (20.3-cm diameter; 0.1-mm resolution). Ten pump rates ranging from 3 to 154 mL min-1 were used to calibrate the TBRs and represented rainfall rates between 6 and 254 mm h-1 depending on the rain gauge diameter. All pump calibration results were very linear with R2 values greater than 0.99. All rain gauges exhibited large nonlinear underestimation errors (between 5% and 29%) that decreased with increasing rain gauge resolution and increased with increasing rainfall rate, especially for rates greater than 50 mm h-1. Calibration curves of bucket tip time against the reciprocal of the true pump rate for all rain gauges also were linear with R2 values of 0.99. Calibration data for the 14 rain gauges of the same type were very similar, as indicated by slope values that were within 14% of each other and ranged from about 367 to 417 s mm h-1. The developed system can calibrate TBRs efficiently, accurately, and virtually unattended and could be modified for use with other rain gauge designs. The system is now in routine use to calibrate TBRs in a large rainfall collection network at Yucca Mountain, Nevada.

Biomass burning in the Amazon-fertilizer for the mountaineous rain forest in Ecuador.

PubMed

Fabian, Peter; Kohlpaintner, Michael; Rollenbeck, Ruetger

2005-09-01

Biomass burning is a source of carbon, sulfur and nitrogen compounds which, along with their photochemically generated reaction products, can be transported over very long distances, even traversing oceans. Chemical analyses of rain and fogwater samples collected in the mountaineous rain forest of south Ecuador show frequent episodes of high sulfate and nitrate concentration, from which annual deposition rates are derived comparable to those found in polluted central Europe. As significant anthropogenic sources are lacking at the research site it is suspected that biomass burning upwind in the Amazon basin is the major source of the enhanced sulfate and nitrate imput. Regular rain and fogwater sampling along an altitude profile between 1800 and 3185 m has been carried out in the Podocarpus National Park close to the Rio SanFrancisco (3 degrees 58'S, 79 degrees 5'W) in southern Ecuador. pH values, electrical conductivity and chemical ion composition were measured at the TUM-WZW using standard methods. Results reported cover over one year from March 2002 until May 2003. Annual deposition rates of sulfate were calculated ranging between 4 and 13 kg S/ha year, almost as high as in polluted central Europe. Nitrogen deposition via ammonia (1.5-4.4 kg N/ha year) and nitrate (0.5-0.8 kg N/ha year) was found to be lower but still much higher than to be expected in such pristine natural forest environment. By means of back trajectory analyses it can be shown that most of the enhanced sulfur and nitrogen deposition is most likely due to forest fires far upwind of the ecuadorian sampling site, showing a seasonal variation, with sources predominantly found in the East/North East during January-March (Colombia, Venezuala, Northern Brazil) and East/SouthEast during July-September (Peru, Brazil). Our results show that biomass burning in the Amazon basin is the predominant source of sulfur and nitrogen compounds that fertilize the mountaineous rain forest in south Ecuador. The mountaineous rain forest in south Ecuador has developed on poor and acid soils, with low nutrient availability. The additional ferilization resulting from anthropogenic biomass burning constitutes a significant disturbance of this ecosystem, its functioning and biodiversity. Thus it is planned to employ isotope analyses for quantifying the pathways. of nitrate and sulfate deposition in these natural forests.

Cloud deposition of PAHs at Mount Lushan in southern China.

PubMed

Wang, Ruixia; Wang, Yan; Li, Hongli; Yang, Minmin; Sun, Lei; Wang, Tao; Wang, Wenxing

2015-09-01

Cloud water samples were collected from Mount Lushan, a high alpine area of southern China, and analyzed using GC-MS to investigate the concentration levels, seasonal variations, particle-dissolved phase partitioning, ecological risk of PAHs and its relationship to the atmosphere and rainwater. The average concentration of total (dissolved+particle) PAHs in cloud water was 819.90 ng/L, which ranged from 2.30 ng/L for DbA to 295.38 ng/L for PhA. PhA (33.11%) contributed the most individual PAHs, followed by Flu (28.24%). Distinct seasonal variations in the total PAHs measured in this research had a higher concentration during the spring and a lower concentration during the summer. When cloud events occurred, the concentration of the atmospheric PAHs of the two phases decreased. The contribution from the gaseous phase of total PAHs in the air to the dissolved phase in cloud water was up to 60.43%, but the particulate phase in the air only contributed 39.57% to the total scavenging. The contribution of total PAHs from the atmosphere to clouds is higher in the gaseous phase than in the particulate phase. A comparative study of the concentrations of cloud water and the closest rain water revealed that the PAH concentration in rainwater was 1.80 times less than that of cloud water and that the dominant individual compounds in cloud water and rainwater were PhA and Flu. A total of 81.27% of the PAHs in cloud samples and 72.21% of the PAHs in rain samples remained in the dissolved phase. Ecological risk assessment indicated that PAHs in cloud water in spring and summer caused a certain degree of ecosystem risk and the mean ecosystem risk in spring was higher than that in summer. Copyright © 2015 Elsevier B.V. All rights reserved.

Monsoon rain chemistry and source apportionment using receptor modeling in and around National Capital Region (NCR) of Delhi, India

NASA Astrophysics Data System (ADS)

Tiwari, Suresh; Kulshrestha, U. C.; Padmanabhamurty, B.

Studies on monsoon precipitation chemistry were carried out to understand the nature of rainwater and sources of pollution at eight different locations in and around the National Capital Region (NCR) of Delhi during southwest monsoon in the years 2003-2005. These sites were Bulandshahr (BUL), Garhmuktesar (GAR), Muradnagar (MUR), Sardhana (SAR), Panipat (PAN), Charkhi Dadri (CHA), Hodal (HOD) and Bahror (BAH). The rainwater samples, collected at these locations, were analyzed for major anions, cations and pH. The data were assessed for its quality. In general, the order of concentrations of major ions was observed to be: Ca 2+>SO 42->HCO 3->NH 4+>Cl ->NO 3->Na +>Mg 2+>K +>F -. The average pH of rainwater at these stations was observed to be 6.39, ranging from 5.77 to 6.62, indicating alkaline nature. However, a few rain events, 31% at Panipat, 12% at Muradnagar and 29% at Sardhana, were observed to be acidic (pH<5.6). Acidity observed at Panipat and Muradnagar is attributed to industrial influence but at Sardhana to weak organic acids contributed by surrounding vegetation. No definite trends are found for most of the components at all the sites. However, concentrations of Cl - at Bulandshahr; NO 3- at Muradnagar and Hodal; F - at Panipat and Bahror; Na + at Bulandshahr; K + at Bahror and Bulandshahr; Ca 2+ at Bulandshahr, Muradnagar, Charkhi Dadri and Sardhana; Mg 2+ at Panipat, Bahror, Bulandshahr, Hodal and Sardhana have increased from 2003 to 2005. For source identification, principal component analysis (PCA) was made, which showed that in general, at all the sites; suspended soil-dust and sea salts which are natural sources, were identified as the most dominating. Sources like agriculture including cattle, brick kilns and industries were reflected in third or fourth PC indicating moderate influence of anthropogenic activities in this region.

Fast-growing Acer rubrum differs from slow-growing Quercus alba in leaf, xylem and hydraulic trait coordination responses to simulated acid rain.

PubMed

Medeiros, Juliana S; Tomeo, Nicholas J; Hewins, Charlotte R; Rosenthal, David M

2016-08-01

We investigated the effects of historic soil chemistry changes associated with acid rain, i.e., reduced soil pH and a shift from nitrogen (N)- to phosphorus (P)-limitation, on the coordination of leaf water demand and xylem hydraulic supply traits in two co-occurring temperate tree species differing in growth rate. Using a full-factorial design (N × P × pH), we measured leaf nutrient content, water relations, leaf-level and canopy-level gas exchange, total biomass and allocation, as well as stem xylem anatomy and hydraulic function for greenhouse-grown saplings of fast-growing Acer rubrum (L.) and slow-growing Quercus alba (L.). We used principle component analysis to characterize trait coordination. We found that N-limitation, but not P-limitation, had a significant impact on plant water relations and hydraulic coordination of both species. Fast-growing A. rubrum made hydraulic adjustments in response to N-limitation, but trait coordination was variable within treatments and did not fully compensate for changing allocation across N-availability. For slow-growing Q. alba, N-limitation engendered more strict coordination of leaf and xylem traits, resulting in similar leaf water content and hydraulic function across all treatments. Finally, low pH reduced the propensity of both species to adjust leaf water relations and xylem anatomical traits in response to nutrient manipulations. Our data suggest that a shift from N- to P-limitation has had a negative impact on the water relations and hydraulic function of A. rubrum to a greater extent than for Q. alba We suggest that current expansion of A. rubrum populations could be tempered by acidic N-deposition, which may restrict it to more mesic microsites. The disruption of hydraulic acclimation and coordination at low pH is emphasized as an interesting area of future study. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Test method for assessing resistance of pine lumber and waferboard to mold

Treesearch

Carol A. Clausen; Michael West

2005-01-01

Methods are needed to evaluate the ability of framing lumber and composite construction materials to withstand mold growth when they are exposed to rain between manufacture and installation. A laboratory-controlled rain chamber was developed to expose biocide-treated specimens of pine lumber and waferboard to bi-weekly wetting followed by re-inoculation with test fungi...

Rain pollination provides reproductive assurance in a deceptive orchid.

PubMed

Fan, Xu-Li; Barrett, Spencer C H; Lin, Hua; Chen, Ling-Ling; Zhou, Xiang; Gao, Jiang-Yun

2012-10-01

Abiotic pollination by wind or water is well established in flowering plants. In some species pollination by rain splashes, a condition known as ombrophily, has been proposed as a floral strategy. However, evidence for this type of abiotic pollination has remained controversial and many reported cases have subsequently been shown to be false. This study investigates ombrophily in the deceptive orchid Acampe rigida to determine the mechanism by which this species is able to maintain high fecundity, despite flowering during the rainy season in south-west China when pollinators are scarce. The floral mechanisms promoting rain pollination in A. rigida were observed and described in detail. Controlled pollination experiments and observations of floral visitors were conducted. A field experiment using rain shelters at 14 sites in Guangxi, south-west China, evaluated the contribution of rain pollination to fruit-set. During rainfall, raindrops physically flicked away the anther cap exposing the pollinarium. Raindrops then caused pollinia to be ejected upwards with the strap-like stipe pulling them back and causing them to fall into the stigmatic cavity, resulting in self-pollination. Neither flower nor pollen function were damaged by water. Although A. rigida is self-compatible, it is incapable of autonomous self-pollination without the assistance of rain splashes. The results of the rain-sheltering experiment indicated that rain pollination contributed substantially to increasing fruit-set, although there was variation among sites in the intensity of this effect. A. rigida flowers during the rainy season, when pollinators are scarce, and ombrophily functions to provide reproductive assurance without compromising opportunities for outcrossing.

Rain pollination provides reproductive assurance in a deceptive orchid

PubMed Central

Fan, Xu-Li; Barrett, Spencer C. H.; Lin, Hua; Chen, Ling-Ling; Zhou, Xiang; Gao, Jiang-Yun

2012-01-01

Background and Aims Abiotic pollination by wind or water is well established in flowering plants. In some species pollination by rain splashes, a condition known as ombrophily, has been proposed as a floral strategy. However, evidence for this type of abiotic pollination has remained controversial and many reported cases have subsequently been shown to be false. This study investigates ombrophily in the deceptive orchid Acampe rigida to determine the mechanism by which this species is able to maintain high fecundity, despite flowering during the rainy season in south-west China when pollinators are scarce. Methods The floral mechanisms promoting rain pollination in A. rigida were observed and described in detail. Controlled pollination experiments and observations of floral visitors were conducted. A field experiment using rain shelters at 14 sites in Guangxi, south-west China, evaluated the contribution of rain pollination to fruit-set. Key Results During rainfall, raindrops physically flicked away the anther cap exposing the pollinarium. Raindrops then caused pollinia to be ejected upwards with the strap-like stipe pulling them back and causing them to fall into the stigmatic cavity, resulting in self-pollination. Neither flower nor pollen function were damaged by water. Although A. rigida is self-compatible, it is incapable of autonomous self-pollination without the assistance of rain splashes. The results of the rain-sheltering experiment indicated that rain pollination contributed substantially to increasing fruit-set, although there was variation among sites in the intensity of this effect. Conclusions A. rigida flowers during the rainy season, when pollinators are scarce, and ombrophily functions to provide reproductive assurance without compromising opportunities for outcrossing. PMID:22851311

Field site leaching from recycled concrete aggregates applied as sub-base material in road construction.

PubMed

Engelsen, Christian J; Wibetoe, Grethe; van der Sloot, Hans A; Lund, Walter; Petkovic, Gordana

2012-06-15

The release of major and trace elements from recycled concrete aggregates used in an asphalt covered road sub-base has been monitored for more than 4 years. A similar test field without an asphalt cover, directly exposed to air and rain, and an asphalt covered reference field with natural aggregates in the sub-base were also included in the study. It was found that the pH of the infiltration water from the road sub-base with asphalt covered concrete aggregates decreased from 12.6 to below pH 10 after 2.5 years of exposure, whereas this pH was reached within only one year for the uncovered field. Vertical temperature profiles established for the sub-base, could explain the measured infiltration during parts of the winter season. When the release of major and trace elements as function of field pH was compared with pH dependent release data measured in the laboratory, some similar pH trends were found. The field concentrations of Cd, Ni, Pb and Zn were found to be low throughout the monitoring period. During two of the winter seasons, a concentration increase of Cr and Mo was observed, possibly due to the use of de-icing salt. The concentrations of the trace constituents did not exceed Norwegian acceptance criteria for ground water and surface water Class II. Copyright © 2012 Elsevier B.V. All rights reserved.

The influence of dual-substrate-layer extensive green roofs on rainwater runoff quantity and quality.

PubMed

Wang, Xiaoou; Tian, Yimei; Zhao, Xinhua

2017-08-15

This study investigates the ability of dual-substrate-layer extensive green roofs to retain rainwater and reduce pollutant leaching. The substrates in dual-substrate-layer green roofs consist of an upper organic nutrition layer for plant growth and a lower inorganic adsorption layer for water retention and pollutant reduction. One traditional single-substrate-layer extensive green roof was built for comparison with dual-substrate-layer green roofs. During the experimental period, dual-substrate-layer green roofs supported better natural vegetation growth, with coverage exceeding 90%, while the coverage in single-substrate-layer green roof was over 80%. Based on the average retention value of the total rainfall for four types of simulated rains (the total rainfall depth (mm) was 43.2, 54.6, 76.2 and 86.4, respectively), the dual-substrate-layer green roofs, which used the mixture of activated charcoal with perlite and vermiculite as the adsorption substrate, possessed better rainfall retention performance (65.9% and 55.4%) than the single-substrate-layer green roof (52.5%). All of the dual-substrate-layer green roofs appeared to be sinks for organics, heavy metals and all forms of nitrogen in all cases, while acted as sources of phosphorus contaminants in the case of heavy rains. In consideration of the factors of water retention, pollution reduction and service life of the green roof, a mixture of activated charcoal and/or pumice with perlite and vermiculite is recommended as the adsorption substrate. The green roofs were able to mitigate mild acid rain, raising the pH from approximately 5.6 in rainfall to 6.5-7.6 in green roof runoff. No signs of a first flush effect for phosphate, total phosphorus, ammonia nitrogen, nitrate nitrogen, total nitrogen, organics, zinc, lead, chromium, manganese, copper, pH or turbidity were found in the green roof runoff. Cost analysis further proved the practicability of dual-substrate-layer green roofs in retaining rainwater, and their long-term rainwater runoff quantity and quality performance in urban environments merit further investigation. Copyright © 2017 Elsevier B.V. All rights reserved.

Stabilization of Cr(VI) from fine ferrochrome dust using exfoliated vermiculite.

PubMed

Mulange Wa Mulange, Delphin; Garbers-Craig, Andrie Mariana

2012-07-15

This study proved that vermiculite, a natural occurring mineral, can effectively remove and stabilize Cr(VI) from fine ferrochrome dust leachate. Batch adsorption studies were carried out to determine the effect of pH, contact time and adsorbent dose on the removal of Cr(VI). The process was found to be highly pH dependent. The optimum conditions for the Cr(VI) removal are at a pH of 1.5, contact time of 2h and adsorbent dose of 10gL(-1). The stability of the Cr(VI)-loaded vermiculite remained unchanged after 12 months, when the vermiculite was evaluated with the ASTM and TCLP Cr(VI) leach methods. However, Cr(VI) desorption did take place when the Acid Rain Test was used. The adsorption kinetic data fits the pseudo-second order model, while the equilibrium data of Cr(VI) adsorption onto vermiculite are best described by the Langmuir isotherm. The presence of hydrobiotite and biotite in the industrial vermiculite slightly decreased the degree of adsorption of Cr(VI). Copyright © 2012 Elsevier B.V. All rights reserved.

Rain, temperature, and child-adolescent height among Native Amazonians in Bolivia.

PubMed

Godoy, R; Goodman, E; Reyes-Garcia, V; Eisenberg, D T A; Leonard, W R; Huanca, T; McDade, T W; Tanner, S; Jha, N

2008-01-01

Global climate change and recent studies on early-life origins of well-being suggest that climate events early in life might affect health later in life. The study tested hypotheses about the association between the level and variability of rain and temperature early in life on the height of children and adolescents in a foraging-farming society of native Amazonians in Bolivia (Tsimane'). Measurements were taken for 525 children aged 2-12 and 218 adolescents aged 13-23 in 13 villages in 2005. Log of standing height was regressed on mean annual level and mean intra-annual monthly coefficient of variation (CV) of rain and mean annual level of temperature during gestation, birth year, and ages 2-4. Controls include age, quinquennium and season of birth, parent's attributes, and dummy variables for surveyors and villages. Climate variables were only related with the height of boys age 2-12. The level and CV of rain during birth year and the CV of rain and level of temperature during ages 2-4 were associated with taller stature. There were no secular changes in temperature (1973-2005) or rain (1943-2005). The height of young females and males is well protected from climate events, but protection works less well for boys ages 2-12.

Hydrological and geochemical factors affecting leachate composition in municipal solid waste incinerator bottom ash. Part II. The geochemistry of leachate from Landfill Lostorf, Switzerland

NASA Astrophysics Data System (ADS)

Johnson, C. Annette; Kaeppeli, Michael; Brandenberger, Sandro; Ulrich, Andrea; Baumann, Werner

1999-12-01

The leachate composition of the Landfill Lostorf, Buchs, Switzerland has been examined as a function rain events and dry periods between November 1994 and November 1996. Discharge and electrical conductivity of the central drainage discharge were monitored continuously, whilst samples for chemical analysis were taken at discrete intervals. The average total concentrations of Na, Cl, K, Mg, Ca and SO 4 are 44.5, 47.1, 11.8, 0.63, 8.2 and 12.4 mM, respectively. During rain events, the leachate is diluted by the preferential flow of rainwater into the drainage discharge. Drainage discharge pH values range between 8.68 and 11.28, the latter under dry conditions. Thermodynamic calculations indicate that CaSO 4, ettringite (3CaOAl 2O 3CaSO 4·32H 2O) and Al(OH) 3 may control the concentrations of the components Ca, SO 4 and Al. Dissolved Si may be in thermodynamic equilibrium with either Ca silicate hydrate or imogolite. Cadmium, Mo, V, Mn and Zn are also diluted during rain events and concentration changes agree with those of conductivity (representing the major constituents). Average concentrations are 0.012, 5.4, 2.3, 0.085, and 0.087 μM, respectively. Components such as Al, Cu, Sb and Cr increase in concentration with increased discharge. Average concentrations are 1.6, 0.27 and 0.21 μM, respectively. For Cu, the explanation lies in its affinity for total organic carbon (TOC). Thermodynamic calculations indicate that whilst dissolution/precipitation reactions with metal hydroxides and carbonates can explain the observed concentrations of Cd, sorption and complexation reactions probably influence the concentrations of Cu, Pb (average measurable concentration 0.013 μM), Zn and Mn. For the oxyanion species such as MoO 4 and WO 4 (average concentration 0.61 μM), it is probable that Ca metallate formation plays a dominant role in determining concentration ranges. Geochemical processes appear to determine concentration ranges and the hydrological factors, the fluctuations in concentration.

Based on the rainfall system platform raindrops research and analysis of pressure loss

NASA Astrophysics Data System (ADS)

Cao, Gang; Sun, Jian

2018-01-01

With the rapid development of China’s military career, land, sea and air force all services and equipment of modern equipment need to be in the rain test, and verify its might suffer during transportation, storage or use a different environment temperature lower water or use underwater, the water is derived from the heavy rain, the wind and rain, sprinkler system, splash water, water wheel, a violent shock waves or use underwater, etcTest the product performance and quality, under the condition of rainfall system platform in the process of development, how to control the raindrops pressure loss becomes the key to whether the system can simulate the real rainfall [1], this paper is according to the rainfall intensity, nozzle flow resistance, meet water flow of rain pressure loss calculation and analysis, and system arrangement of the optimal solution of rainfall is obtained [2].

Spatial and temporal variation in soil CO2 efflux in an old-growth neotropical rain forest, LA Selva, Costa Rica

Treesearch

Luitgard Schwendenmann; Edzo Veldkamp; Tania Brenes; Joseph J. O' Brien; Jens Mackensen

2003-01-01

Our objectives were to quantify and compare soil CO2, efflux of two doininant soil types in an old-growth neotropical rain forest in the Atlantic zone of Costa Rica, and to evaluate the control of environmental Factors on CO2, release. We measured soil CO2 efflux from eight permanent soil chamhers on...

Reliability of the Forest Service type rain gage

Treesearch

G. L. Hayes

1942-01-01

The Forest Service type rain-gage was originated by W. B. Osborne of the Portland, Oreg., office of the U. S. Forest Service to meet a need for reliable rainfall measurements at low cost. Many hundreds of them, over 700 on the national forests of northern Idaho and western Montana alone, are now being used during the summer months as aids to forest-fire control...

Influence of amount of oxidizing slag discharged from stainless steelmaking process of electric arc furnace on elution behavior into fresh water

NASA Astrophysics Data System (ADS)

Yokoyama, S.; Shimomura, T.; Hisyamudin, M. N. N.; Takahashi, T.; Izaki, M.

2012-03-01

Fundamental study was carried out for provision for acidification of soil due to acid rain. The influence of weight of the additive slag on elution behavior of the slag into water was studied in this study. Elution experiment was carried out on a basis of JIS K 0058-1. Generally, the pH in the aqueous solution increased with an increase in weight of the additive slag. The pH converged to approximately eight. Calcium, magnesium and manganese, which were essential elements for plants, were eluted from the slag irrespective to elution condition. The eluted concentrations of Ca and Mg increased with an increase in weight of the additive slag. Silicon and zinc were also eluted depending on the conditions. Aluminum that was harmful for plants was not eluted from the used slag.

Soil-calcium depletion linked to acid rain and forest growth in the eastern United States

USGS Publications Warehouse

Lawrence, Gregory B.; Huntington, T.G.

1999-01-01

Since the discovery of acid rain in the 1970's, scientists have been concerned that deposition of acids could cause depletion of calcium in forest soils. Research in the 1980's showed that the amount of calcium in forest soils is controlled by several factors that are difficult to measure. Further research in the 1990's, including several studies by the U.S. Geological Survey, has shown that (1) calcium in forest soils has decreased at locations in the northeastern and southeastern U.S., and (2) acid rain and forest growth (uptake of calcium from the soil by roots) are both factors contributing to calcium depletion.

Batch leaching tests of motherboards to assess environmental contamination by bromine, platinum group elements and other selected heavy metals.

PubMed

Almeida, César; Grosselli, Melina; González, Patricia; Martínez, Dante; Gil, Raúl

2016-02-01

In this study, a batch leaching test was executed to evaluate the toxicity associated with chemicals contained in motherboards. The leaching solutions used were distilled water, nitric acid, acetic acid and synthetic acid rain solution. A total of 21 elements including Ag, As, Au, Br, Cd, Co, Cr, Cu, Hf, Ir, Mn, Ni, Os, Pb, Pd, Pt, Rd, Rh, Se, U and Zn were analyzed. In this study, the pH values of all the leachates fell within the range of 2.33-4.88. The highest concentrations of metals were obtained from the acid rain solution, whilst the maximum value of bromine was achieved with solution of acetic acid. Appreciable concentrations of platinum group elements were detected with concentrations around 3.45, 1.43, 1.21 and 22.19 µg L(-1) for Ir, Pd, Pt and Rh, respectively. The different leaching of the motherboards revealed the predominant presence of the toxic substances in the leached from the e-waste. Copyright © 2015 Elsevier Ltd. All rights reserved.

Isotopic equilibrium between precipitation and water vapor: evidence from continental rains in central Kenya

NASA Astrophysics Data System (ADS)

Soderberg, K.; Gerlein, C.; Kemeny, P. C.; Caylor, K. K.

2013-12-01

An accurate understanding of the relationships between the isotopic composition of liquid water and that of water vapor in the environment can help describe hydrologic processes across many scales. One such relationship is the isotopic equilibrium between falling raindrops and the surrounding vapor. The degree of equilibration is used to model the isotopic composition of precipitation in isotope-enable general circulation models and land-atmosphere exchange models. Although this equilibrium has been a topic of isotope hydrology research for more than four decades, few studies have included vapor measurements to validate modeling efforts. Recent advances in laser technology have allowed for in situ vapor measurements at high temporal resolution (e.g., >1 Hz). Here we present concomitant rain and vapor measurements for a series of 17 rain events during the 'Continental' rainy season (June through August) at Mpala Research Center in central Kenya. Rain samples (n=218) were collected at intervals of 2 to 35 minutes (median of 3 minutes) depending on the rain rate (0.4 to 10.5 mm/hr). The volume-weighted mean rain values for δ18O, δ2H and D-excess (δ2H - 8* δ18O) were 0.1 ‰, 10.7 ‰, and 10.1 ‰. These values are more enriched than the annual weighted means reported for the area (-2.2 ‰, -7.6 ‰, and 11.0 ‰, respectively). Vapor was measured continuously at ~2Hz (DLT-100, Los Gatos Research), with an inverted funnel intake 4m above the ground surface. The mean vapor isotopic composition during the rain events was -10.0 +/- 1.2 ‰ (1 σ) for δ18O and -73.9 +/- 7.0 ‰ for δ2H. The difference between the rain sample isotopic composition and that of liquid in isotopic equilibrium with the corresponding vapor at the ambient temperature was 0.8 +/- 2.2 ‰ for δ18O and 6.2 +/- 7.0 ‰ for δ2H. This disequilibrium was found to correlate with the natural log of rain rate (R2 of 0.26 for δ18O and 0.46 for δ2H), with lower rain rates having larger disequilibrium. There was also a temporal pattern in the disequilibrium for δ18O, with the first five rain events having significantly larger (p < 0.01) disequilibrium (4.4 ‰) than the subsequent rain events (0.6 ‰). The temporal pattern suggests that, in addition to the relationship with rain rate, there is some relationship between rain-vapor equilibrium and larger-scale controls such as vapor source region, precipitation recycling and air mass trajectory.

Rain pulses - how different data streams provide insight in response-times and help to attribute biophysical properties to ecosystem processes.

NASA Astrophysics Data System (ADS)

El-Madany, T. S.; Migliavacca, M.; Perez-Priego, O.; Luo, Y.; Kolle, O.; Carrara, A.; Moreno, G.; Reichstein, M.

2017-12-01

Rain pulses play a major role for the carbon cycle in semiarid ecosystems, as they can release large amounts of stored carbon. Physical and biological processes, triggered by the availability of water start to develop on various time scales and are dependent on the amount of available water. Especially, in savanna type ecosystems with an herbaceous understory and sparsely distributed trees the response time of the two plant functional types to rain pulses might be different. We present results from an ongoing large-scale nutrient manipulation experiment (MANIP) in a Mediterranean savanna type ecosystem and its response to rain pulses. Within MANIP the footprint areas from two out of three ecosystem eddy co-variance (EC) sites were fertilized with nitrogen (NT) and nitrogen plus phosphorous (NPT), the third served as the control (CT). The analysis combines EC data to determine the net ecosystem exchange, PhenoCam data to define the senescence and re-greening period, SAP-flow measurements to evaluate the response of trees to rain pulses, high frequency (1 Hz) CO2-concentration measurements to estimate the response time to of the ecosystem to rain pulses, and meteorological measurements to quantify the intensity of the rain pulses. Additionally, at NT canopy reflectance and SIF are measured continuously for trees and grasses. The combination of SIF and SAP-flow measurements allows to separate the contribution of trees to ecosystem fluxes and can be utilized to partition NEE into ecosystem respiration and gross primary productivity during the senescence period. The analyses focus on three topics; (i) utilizing high frequency dynamics of CO2 concentration to disentangle physical and biological responses to water availability; (ii) fertilization effect of respiration pulses on ecosystem fluxes; (iii) response of tree transpiration to rain pulses. CO2 concentrations show an instantaneous reaction to rain fall. Within minutes concentrations increase strongly and follow distinct patterns. The fertilization effect is not clear in terms of respiration magnitude triggered by the rain pulse but the fertilized areas show slightly more carbon uptake during daytime after a precipitation pulse. Sap-flow measurements indicate a response of the trees to the rain pulses which effect nocturnal and daytime sap velocities.

Rain gauge calibration and testing

NASA Technical Reports Server (NTRS)

Wilkerson, John

1994-01-01

Prior to the Tropical Oceans Global Atmosphere-Coupled Ocean Atmosphere Response Experiment (TOGA-COARE), 42 Model 100 series optical gauges were tested in the rain simulator facility at Wallops Island before shipment to the field. Baseline measurements at several rain rates were made simultaneously with collector cans, tipping bucket, and a precision weighing gauge and held for post-COARE evaluation with a repeat set of measurements that were to be recorded after the instruments were returned. This was done as a means of detecting any calibration changes that might have occurred while deployed. Although it was known that the artificial rain in the simulator did not contain the required exponential distribution for accurate optical rain gauge rate measurements, use of the facility was necessary because it was the only means available for taking controlled observations with instruments that were received, tested, and shipped out in groups over a period of months. At that point, it was believed that these measurements would be adequately precise for detecting performance changes over time. However, analysis of the data by STI now indicates that this may not be true. Further study of the data will be undertaken to resolve this.

Natural weathering in dry disposed ash dump: Insight from chemical, mineralogical and geochemical analysis of fresh and unsaturated drilled cores.

PubMed

Akinyemi, S A; Akinlua, A; Gitari, W M; Khuse, N; Eze, P; Akinyeye, R O; Petrik, L F

2012-07-15

Some existing alternative applications of coal fly ash such as cement manufacturing; road construction; landfill; and concrete and waste stabilisation use fresh ash directly collected from coal-fired power generating stations. Thus, if the rate of usage continues, the demand for fresh ash for various applications will exceed supply and use of weathered dry disposed ash will become necessary alternative. As a result it's imperative to understand the chemistry and pH behaviour of some metals inherent in dry disposed fly ash. The bulk chemical composition as determined by XRF analysis showed that SiO2, Al2O3 and Fe2O3 were the major oxides in fresh ash and unsaturated weathered ashes. The unsaturated weathered ashes are relatively depleted in CaO, Fe2O3, TiO2, SiO2, Na2O and P2O5 due to dissolution and hydrolysis caused by chemical interaction with ingressing CO2 from the atmosphere and infiltrating rain water. Observed accumulations of Fe2O3, TiO2, CaO, K2O, Na2O and SO3 and Zn, Zr, Sr, Pb, Ni, Cr and Co in the lower layers indicate progressive downward movement through the ash dump though at a slow rate. The bulk mineralogy of unsaturated weathered dry disposed ash, as determined by XRD analysis, revealed quartz and mullite as the major crystalline phases; while anorthite, hematite, enstatite, lime, calcite, and mica were present as minor mineral phases. Pore water chemistry revealed a low concentration of readily soluble metals in unsaturated weathered ashes in comparison with fresh ash, which shows high leachability. This suggests that over time the precipitation of transient minor secondary mineral phases; such as calcite and mica might retard residual metal release from unsaturated weathered ash. Chloride and sulphate species of the water soluble extracts of weathered ash are at equilibrium with Na+ and K+; these demonstrate progressive leaching over time and become supersaturated at the base of unsaturated weathered ash. This suggests that the ash dump does not encapsulate the salt or act as a sustainable salt sink due to over time reduction in pore water pH. The leaching behaviours of Ca, Mg, Na+, K+, Se, Cr and Sr are controlled by the pH of the leachant in both fresh and unsaturated weathered ash. Other trace metals like As, Mo and Pb showed amphoteric behaviour with respect to the pH of the leachant. The precipitation of minor quantities of secondary mineral phases in the unsaturated weathered ash has significant effects on the acid susceptibility and leaching patterns of chemical species in comparison with fresh ash. The unsaturated weathered ash had lower buffering capacity at neutral pH (7.94-8.00) compared to fresh (unweathered) ash. This may be due to the initial high leaching/flushing of soluble basic buffering constituents from fly ash after disposal. The overall results of the acid susceptibility tests suggest that both fresh ash and unsaturated weathered ash would release a large percentage of their chemical species when in contact with slightly acidified rain. Proper management of ash dumps is therefore essential to safeguard the environmental risks of water percolation in different fly ashes behaviour. Copyright © 2012 Elsevier Ltd. All rights reserved.

Performance of alum and assorted coagulants in turbidity removal of muddy water

NASA Astrophysics Data System (ADS)

Malik, Qasim H.

2018-03-01

Coagulation is a primary and cost effective process in water treatment plants. Under optimum conditions, not only it effectively removes turbidity but also results in reduced sludge volume and subsequently minimizes sludge management costs. Highly turbid water from streams, canals, rivers and rain run offs was run through jar test for turbidity removal. The brown water with 250NTU turbidity when coagulated with alum and assorted coagulants proved that maximum turbidity removal was witnessed using alum dose of 0.25 g/l at ph 6 with a sedimentation time of 30 min.

Monsoonal vs. glacial control on erosion and sediment storage in the Himalayan rain shadow, Zanskar River, northwest India

NASA Astrophysics Data System (ADS)

Jonell, Tara; Clift, Peter; Carter, Andrew; Böning, Philipp; Wittmann, Hella

2016-04-01

Summer monsoon precipitation strongly controls erosion and sediment storage in the frontal Himalaya but the relationship between monsoonal variability and erosion is less well-constrained beyond the High Himalayan topographic divide in the rain shadow. Here we establish a Quaternary erosional history for a rain shadow tributary of the upper Indus River system, the Zanskar River, by applying several sediment provenance techniques to modern and dated terrace river sediments. We evaluate if there are temporal links between sediment storage and moisture supply to the rain shadow and if regions like the Zanskar River basin play a significant role in controlling total sediment flux to the Indus River. We compile bulk sediment petrography and Sr and Nd isotope geochemistry, detrital U-Pb zircon and apatite fission track dating with in-situ 10Be cosmogenic radionuclide techniques to identify patterns of erosion and sediment production across Zanskar. Bulk petrography, Sr and Nd isotope geochemistry, and U-Pb detrital zircon spectra of modern and older terrace sediments indicate high rates of erosion along the Greater Himalaya in the Zanskar River basin. We find that the wettest and most glaciated subcatchment dominates the bulk sediment provenance signal, with only moderate input from other tributaries, and that other basin parameters cannot explain our observations. Catchment-averaged in-situ 10Be cosmogenic nuclide concentrations of modern sediments indicate erosion rates up to ˜1.2 mm y-1 but show strong dilution attributed to glacial sediment recycling into the modern river, suggesting rates nearer 0.4-0.6 mm•y-1. These rates are consistent with longer-term rates of incision (0.3-0.7 mm•y-1) calculated from detrital apatite fission track ages, and incision rates inferred from Late Glacial and Holocene terraces near the Zanskar-Indus confluence. Our findings suggest that sediment production in glaciated Himalayan rain shadow environments like Zanskar is largely controlled by internal glacial fluctuations coupled with periodic dissection and reworking of terrace material during strong monsoonal precipitation phases.

Assessing the controls of the snow energy balance and water available for runoff in a rain-an-snow environment

Treesearch

Adam B. Mazurkiewicz; David G. Callery; Jeffrey J. McDonnell

2008-01-01

Rain-on-snow (ROS) melt production and its contribution to water available for runoff is poorly understood. In the Pacific Northwest (PNW) of the USA, ROS drives many runoff events with turbulent energy exchanges dominating the snow energy balance (EB). While previous experimental work in the PNW (most notably the H.J. Andrews Experimental Forest (HJA» has quantified...

A rain splash transport equation assimilating field and laboratory measurements

USGS Publications Warehouse

Dunne, T.; Malmon, D.V.; Mudd, S.M.

2010-01-01

Process-based models of hillslope evolution require transport equations relating sediment flux to its major controls. An equation for rain splash transport in the absence of overland flow was constructed by modifying an approach developed by Reeve (1982) and parameterizing it with measurements from single-drop laboratory experiments and simulated rainfall on a grassland in East Africa. The equation relates rain splash to hillslope gradient, the median raindrop diameter of a storm, and ground cover density; the effect of soil texture on detachability can be incorporated from other published results. The spatial and temporal applicability of such an equation for rain splash transport in the absence of overland flow on uncultivated hillslopes can be estimated from hydrological calculations. The predicted transport is lower than landscape-averaged geologic erosion rates from Kenya but is large enough to modify short, slowly eroding natural hillslopes as well as microtopographic interrill surfaces between which overland flow transports the mobilized sediment. Copyright 2010 by the American Geophysical Union. Copyright 2010 by the American Geophysical Union.

Effect of heavy rain to the total received power

NASA Technical Reports Server (NTRS)

Iguchi, Toshio

1994-01-01

If the average power at the receiver is substantially reduced by heavy rain, the AGC (automatic gain control) circuit of the rain gauge will try to compensate this reduction by increasing the gain. If this happens, then the pulses created by rain drops are amplified more than they should be and the rainfall rate may be overestimated. If the effective diameter (blocking efficiency) of a particle is 2 mm and if the beam width is 2 cm, each particle will reduce the received power by 10 percent when it crosses the beam. Since the beam is blocked by water drops 75 percent of the total time according to the above calculation, the total received power may be reduced by 7.5 percent. To compensate this reduction to the reference value, the gain of amplifier will be increased by 8.1 percent. This increase of gain will increase all pulse sizes by the same fraction and result in the overestimate of the rainfall rate.

Rain concentration and sheltering effect of solar panels on cultivated plots

NASA Astrophysics Data System (ADS)

Elamri, Yassin; Cheviron, Bruno; Mange, Annabelle; Dejean, Cyril; Liron, François; Belaud, Gilles

2018-02-01

Agrivoltaism is the association of agricultural and photovoltaic energy production on the same land area, coping with the increasing pressure on land use and water resources while delivering clean and renewable energy. However, the solar panels located above the cultivated plots also have a seemingly yes unexplored effect on rain redistribution, sheltering large parts of the plot but redirecting concentrated fluxes on a few locations. The spatial heterogeneity in water amounts observed on the ground is high in the general case; its dynamical patterns are directly attributable to the mobile panels through their geometrical characteristics (dimensions, height, coverage percentage) and the strategies selected to rotate them around their support tube. A coefficient of variation is used to measure this spatial heterogeneity and to compare it with the coefficient of uniformity that classically describes the efficiency of irrigation systems. A rain redistribution model (AVrain) was derived from literature elements and theoretical grounds and then validated from experiments in both field and controlled conditions. AVrain simulates the effective rain amounts on the plot from a few forcing data (rainfall, wind velocity and direction) and thus allows real-time strategies that consist in operating the panels so as to limit the rain interception mainly responsible for the spatial heterogeneities. Such avoidance strategies resulted in a sharp decrease in the coefficient of variation, e.g. 0.22 vs. 2.13 for panels held flat during one of the monitored rain events, which is a fairly good uniformity score for irrigation specialists. Finally, the water amounts predicted by AVrain were used as inputs to Hydrus-2D for a brief exploratory study on the impact of the presence of solar panels on rain redistribution at shallow depths within soils: similar, more diffuse patterns were simulated and were coherent with field measurements.

Challenges for Planning and Maintaining of Urban Rain Harvesting Systems- the case of Hammarby Sjöstad and Årstafältet in Stockholm

NASA Astrophysics Data System (ADS)

Suleiman, Lina

2017-04-01

Planners and policymakers' concern escalates over conventional systems dealing with rains in cities based on domination and control of nature rather than harmony and design with nature. A new spatial planning paradigm is needed to put in place systems which mimic natural water systems and promise multiple values instead of systems consider rain as a source of problem. However, such approach embodies significant planning challenges. Urban rain harvesting systems (URHs) are inherently viewed as 'sociotechnical' systems. As such, planning processes should consider the interdependence of 'social' and 'technical' aspects as essential elements if a transition towards sustainable urban water systems is to be realised. Drawing on a common understanding for what urban rain harvesting systems should deliver in terms of 'functions' and 'added values', a generic planning framework is developed to inform practitioners on how the 'socio' and 'technical' elements should be assimilated in a long-term and integrated planning processes of URHs. Using the developed framework, the paper examines the planning and maintenance processes of urban rain harvesting systems in Årstafältet and Hammarby Sjöstad respectively. Results show that planners lack a common operational understanding on how these systems should be designed holistically in a long term and integrated planning processes creating working gabs or positional conflicts. In practice, urban planners and water engineers look at these systems as either urban design component or water drainage system to deal with technical functions hindering a smooth transition path towards urban rain harvesting systems. The paper concludes on the urgency for reordering roles and relations within a new set-up organisation to incubate these systems in long-term planning and maintenance processes. Key words: 'Sociotechnical' system, Water, Planning, Urban Rain Harvesting systems (URHs), Hammarby Sjostad and Årstafältet

Air-pollution emission control in China: impacts on soil acidification recovery and constraints due to drought.

PubMed

Duan, Lei; Liu, Jing; Xin, Yan; Larssen, Thorjørn

2013-10-01

The Chinese government has established compulsory targets to reduce sulfur dioxide (SO2) and nitrogen oxide (NOx) emissions by 8% and 10%, respectively, during 2010-2015. In this study, the effect of the policy was evaluated by predicting the recovery of acidified forest soil in Chongqing, an area severely impacted by acid rain in southwest China. Since precipitation has decreased significantly in this area in recent years, the impact of drought on soil acidification was also considered. A dynamic acidification model, MAGIC, was used to predict future trends in soil chemistry under different scenarios for deposition reduction as well as drought. We found that the current regulation of SO2 emission abatement did not significantly increase soil water pH values, the Ca2+ to Al3+ molar ratio (Ca/Al), or soil base saturation to the level of 2000 before 2050. NOx emission control would have less of an effect on acidification recovery, while emission reduction of particulate matter could offset the benefits of SO2 reduction by greatly decreasing the deposition of base cations, particularly Ca(2+). Continuous droughts in the future might also delay acidification recovery. Therefore, more stringent SO2 emission control should be implemented to facilitate the recovery of seriously acidified areas in China. © 2013 Elsevier B.V. All rights reserved.

Study and interpretation of chemical composition of rainwater in selected urban and rural locations in India using multivariate analysis

NASA Astrophysics Data System (ADS)

Chakraborty, Bidisha; Gupta, Abhik

2018-04-01

Rainwater is an important untapped resource for all water managers and can be collected and used personally for all uses and simultaneously diverted to ground for recharge of depleting aquifers. Rain water is the most purest form of water until it is contaminated by the atmospheric pollution. Evaluation of rainwater quality analysis is also essential for non-potable applications and to match quality to specific uses. Rainwater quality analysis is, therefore, carried out to understand the problems of rainwater contamination with various pollutants. Rainwater samples were collected from the pre-monsoon season of March 2010 to post-monsoon of October 2013, from seven sampling sites namely Irongmara, Badarpur, Bongaigaon, Dolaigaon, BGR Township, Kolkata and Kharagpur, which characterised typical suburban, urban and industrialised locations respectively. A total of 943 samples were collected during this period from the sampling sites, taking utmost care in sampling and storage were analysed for heavy metals determination. Results for pH, EC, Pb, Cd, Ni, Zn, Cr and Co were reported in this study. The samples were collected using PVC bottles. The highest concentration of elements was observed at the beginning of the rainfall season when large amounts of dust accumulated in the atmosphere scavenged by rain. The values of pH in rainwater samples were relatively within the World Health Organization (WHO) standard for drinking water. Multivariate statistical analysis especially varimax rotation was applied to bring to focus the hidden yet important variables which influence the rainwater quality. It is also observed that rainwater contamination may not be restricted to industrial areas alone but vehicular emission may also contribute significantly in certain areas.

Loss of ecosystem services due to chronic pollution of forests and surface waters in the Adirondack region (USA)

USGS Publications Warehouse

Beier, Colin M.; Caputo, Jesse; Lawrence, Gregory B.; Sullivan, Timothy J.

2017-01-01

Sustaining recent progress in mitigating acid pollution could require lower emissions caps that will give rise to real or perceived tradeoffs between healthy ecosystems and inexpensive energy. Because most impacts of acid rain affect ecosystem functions that are poorly understood by policy-makers and the public, an ecosystem services (ES) framework can help to measure how pollution affects human well-being. Focused on the Adirondack region (USA), a global ‘hot-spot’ of acid pollution, we measured how the chronic acidification of the region's forests, lakes, and streams has affected the potential economic and cultural benefits they provide to society. We estimated that acid-impaired hardwood forests provide roughly half of the potential benefits of forests on moderate to well-buffered soils – an estimated loss of ∼ $10,000 ha−1 in net present value of wood products, maple syrup, carbon sequestration, and visual quality. Acidic deposition has had only nominal impact – relative to the effects of surficial geology and till depth – on the capacity of Adirondack lakes and streams to provide water suitable for drinking. However, as pH declines in lakes, the estimated value of recreational fishing decreases significantly due to loss of desirable fish such as trout. Hatchery stocking programs have partially offset the pollution-mediated losses of fishery value, most effectively in the pH range 4.8–5.5, but are costly and limited in scope. Although any estimates of the monetary ‘damages’ of acid rain have significant uncertainties, our findings highlight some of the more tangible economic and cultural benefits of pollution mitigation efforts, which continue to face litigation and political opposition.

Loss of ecosystem services due to chronic pollution of forests and surface waters in the Adirondack region (USA).

PubMed

Beier, Colin M; Caputo, Jesse; Lawrence, Gregory B; Sullivan, Timothy J

2017-04-15

Sustaining recent progress in mitigating acid pollution could require lower emissions caps that will give rise to real or perceived tradeoffs between healthy ecosystems and inexpensive energy. Because most impacts of acid rain affect ecosystem functions that are poorly understood by policy-makers and the public, an ecosystem services (ES) framework can help to measure how pollution affects human well-being. Focused on the Adirondack region (USA), a global 'hot-spot' of acid pollution, we measured how the chronic acidification of the region's forests, lakes, and streams has affected the potential economic and cultural benefits they provide to society. We estimated that acid-impaired hardwood forests provide roughly half of the potential benefits of forests on moderate to well-buffered soils - an estimated loss of ∼ $10,000 ha -1 in net present value of wood products, maple syrup, carbon sequestration, and visual quality. Acidic deposition has had only nominal impact - relative to the effects of surficial geology and till depth - on the capacity of Adirondack lakes and streams to provide water suitable for drinking. However, as pH declines in lakes, the estimated value of recreational fishing decreases significantly due to loss of desirable fish such as trout. Hatchery stocking programs have partially offset the pollution-mediated losses of fishery value, most effectively in the pH range 4.8-5.5, but are costly and limited in scope. Although any estimates of the monetary 'damages' of acid rain have significant uncertainties, our findings highlight some of the more tangible economic and cultural benefits of pollution mitigation efforts, which continue to face litigation and political opposition. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Size-resolved Chemical Composition of Cloud and Rain Water Collected during the Puerto Rico African Dust and Clouds Study (PRADACS) Campaign

NASA Astrophysics Data System (ADS)

Torres, E.; Valle Diaz, C. J.; Zurcher, F.; Lee, T.; Collett, J. L.; Fitzgerald, E.; Cuadra, L.; Prather, K. A.; Mayol-Bracero, O. L.

2011-12-01

The underlying physico-chemical processes of dust-aerosol interactions are poorly understood; even less understood is how aging impacts cloud properties and climate as the particles travel from Africa to the Caribbean region. Caribbean landmasses have tropical montane cloud forests (TMCFs) that are tightly coupled to the atmospheric hydrologic cycle. Small-scale shifts in temperature and precipitation could have serious ecological consequences. Therefore, this makes TMCFs an interesting ecosystem to see the effects African Dust (AD) might have on cloud formation and precipitation. As part of the Puerto Rico African Dust and Clouds Study (PRADACS) cloud and rain water samples for subsequent chemical analysis were collected at Pico del Este (PE) station in Luquillo, PR (1051 masl) during summer 2011. At PE, two cloud collectors (i.e., single stage (Aluminum version) and 2-stage (Teflon version) Caltech Active Strand Cloudwater Collector (CASCC)), and a rainwater collector were operated. Measurements such as the liquid water content (LWC), pH, conductivity., and composition of single particles using an aerosol time of flight mass spectrometer (ATOFMS) were performed. Preliminary results showed that days with the influence of African dust (AD), had LWC values that ranged from 300 to 500 mg/m3, pH values up to 5.7,, and conductivity up to 180 μS/cm. The ATOFMS showed titanium and iron ions, suggesting the presence of AD as well as, occasionally, sulfate and nitrate ions suggesting the influence of anthropogenic pollution. Results on the chemical composition and the physical properties of cloud, rainwater, and aerosol for the inorganic as well as the organic fraction and how these properties change for the different air masses observed will also be presented.

Long-term atmospheric nutrient inputs to the Eastern Mediterranean: sources, solubility and comparison with riverine inputs

NASA Astrophysics Data System (ADS)

Koçak, M.; Kubilay, N.; Tuǧrul, S.; Mihalopoulos, N.

2010-07-01

Aerosol and rain samples were collected at a rural site located on the coastline of the Eastern Mediterranean, Erdemli, Turkey between January 1999 and December 2007. Riverine sampling was carried out at five Rivers (Ceyhan, Seyhan, Göksu, Berdan and Lamas) draining into the Northeastern Levantine Basin (NLB) between March 2002 and July 2007. Samples were analyzed for macronutrients of phosphate, silicate, nitrate and ammonium (PO43-, Sidiss, NO3- and NH4+). Phosphate and silicate in aerosol and rainwater showed higher and larger variation during the transitional period (March-May, September) when air flows predominantly originate from North Africa and Middle East/Arabian Peninsula. Deficiency of alkaline material were found to be the main reason of the acidic rain events whilst high pH values (>7) were associated with high Sidiss concentrations due to sporadic dust events. In general, lowest nitrate and ammonium concentrations in aerosol and rainwater were associated with air flow from the Mediterranean Sea. Unlike NO3- and NH4+ (Dissolved Inorganic Nitrogen, DIN), there were statistical differences for PO43- and Sidiss solubilities in sea-water and pure-water. Solubilities of PO43- and Sidiss were found to be related with air mass back trajectories and pH. Comparison of atmospheric with riverine fluxes demonstrated that DIN and PO43- fluxes to NLB were dominated by atmosphere (~90% and ~60% respectively) whereas the input of Si was mainly derived from riverine runoff (~90%). N/P ratios (atmosphere ~233; riverine ~28) revealed that NLB receives excessive amounts of DIN and this unbalanced P and N inputs may provoke even more phosphorus deficiency. Molar Si/N ratios (atmosphere + riverine) suggested Si limitation which might cause a switch from diatom dominated phytoplankton communities to non-siliceous populations in NLB.

Laboratory exposure systems to simulate atmospheric degradation of building stone under dry and wet deposition conditions

NASA Astrophysics Data System (ADS)

Johnson, J. B.; Haneef, S. J.; Hepburn, B. J.; Hutchinson, A. J.; Thompson, G. E.; Wood, G. C.

The design philosophy, construction and use of two exposure test systems are described, in which the objective is to simulate the degradation of stone samples under, respectively, the 'dry' and 'wet' deposition of atmospheric pollutants. Some element of realistic acceleration is possible in certain experiments. Particular emphasis is placed upon using known presentation rates of the pollutants, both in respect of typical depositions of pollutants and their oxidation products appropriate for an industrial atmosphere. In the dry deposition rig, SO 2, NO 2, NO, HCl and the oxidant O 3 are presented individually or together at realistic deposition rates. In the wet deposition apparatus, SO 2-4, NO -3 and Cl - at a pH of 3.5, simulating 'acid rain' but in a more concentrated form, are deposited. The dry deposition chamber can be operated at constant relative humidity (typically 84%) with pre-dried or precisely wetted stones to simulate episodic rain wetting, or using other methods of wet/dry cycling, which are also a feature of the wet deposition chamber. Heating and cooling of the samples is also possible, as is the use of shaped or coupled stones of different kinds such as are found in a building facade. The results are illustrated in terms of data on the weight change, the anion content of stone and run-off, the pH change of run-off and the total calcium reacted, using Portland stone, as a prelude to later papers in which behaviour of a whole matrix of stone types and environments is presented and discussed. Such an approach permits the eventual production of 'pollutant-material response' relationships and damage functions for comparison with and prediction of external exposure results.

A generic methodology for the optimisation of sewer systems using stochastic programming and self-optimizing control.

PubMed

Mauricio-Iglesias, Miguel; Montero-Castro, Ignacio; Mollerup, Ane L; Sin, Gürkan

2015-05-15

The design of sewer system control is a complex task given the large size of the sewer networks, the transient dynamics of the water flow and the stochastic nature of rainfall. This contribution presents a generic methodology for the design of a self-optimising controller in sewer systems. Such controller is aimed at keeping the system close to the optimal performance, thanks to an optimal selection of controlled variables. The definition of an optimal performance was carried out by a two-stage optimisation (stochastic and deterministic) to take into account both the overflow during the current rain event as well as the expected overflow given the probability of a future rain event. The methodology is successfully applied to design an optimising control strategy for a subcatchment area in Copenhagen. The results are promising and expected to contribute to the advance of the operation and control problem of sewer systems. Copyright © 2015 Elsevier Ltd. All rights reserved.

Survival of spotted salamander eggs in temporary woodland ponds of coastal Maryland

USGS Publications Warehouse

Albers, P.H.; Prouty, R.M.

1987-01-01

Temporary ponds on the Atlantic Coastal Plain in maryland were characterized according to water chemistry, rain input, phytoplankton, zooplankton and use by the spotted salamander Ambystoma maculatum during March-October 1983-1984. Neither the number of egg masses per unit of pond surface (abundance) nor the survival of spotted salamander embryos was significantly correlated (P>0.05) with pond pH. Rainfall during May-July significantly increased the hydrogen ion concentration of 5 of 11 ponds evaluated for the impact of rainfall during the previous 48h and the previous week. Survival of egg masses transferred among eight ponds with pH3.66-4.45 and one pond with pH5.18 was significantly reduced (P

Rainfall Product Evaluation for the TRMM Ground Validation Program

NASA Technical Reports Server (NTRS)

Amitai, E.; Wolff, D. B.; Robinson, M.; Silberstein, D. S.; Marks, D. A.; Kulie, M. S.; Fisher, B.; Einaudi, Franco (Technical Monitor)

2000-01-01

Evaluation of the Tropical Rainfall Measuring Mission (TRMM) satellite observations is conducted through a comprehensive Ground Validation (GV) Program. Standardized instantaneous and monthly rainfall products are routinely generated using quality-controlled ground based radar data from four primary GV sites. As part of the TRMM GV program, effort is being made to evaluate these GV products and to determine the uncertainties of the rainfall estimates. The evaluation effort is based on comparison to rain gauge data. The variance between the gauge measurement and the true averaged rain amount within the radar pixel is a limiting factor in the evaluation process. While monthly estimates are relatively simple to evaluate, the evaluation of the instantaneous products are much more of a challenge. Scattegrams of point comparisons between radar and rain gauges are extremely noisy for several reasons (e.g. sample volume discrepancies, timing and navigation mismatches, variability of Z(sub e)-R relationships), and therefore useless for evaluating the estimates. Several alternative methods, such as the analysis of the distribution of rain volume by rain rate as derived from gauge intensities and from reflectivities above the gauge network will be presented. Alternative procedures to increase the accuracy of the estimates and to reduce their uncertainties also will be discussed.

[Hydrology and water quality of rainfall-runoff in combined sewerage system along Suzhou Creek in central Shanghai].

PubMed

Cheng, Jiang; Yang, Kai; Huang, Xiao-Fang; Lü, Yong-Peng

2009-07-15

In order to obtain the processes of hydrology and water quality of urban combined sewerage system (CSS) in highly urbanized region, the precipitation, discharge and pollutant concentration of four different intensity rainfall (light rain, moderate rain, heavy rain and storm) were measured from Jul. to Sep. 2007 in the Chendulu CSS along Suzhou Creek in Shanghai. The results show that the shapes of runoff graph are similar to rainfall graph, with a weaker fluctuation range and a 15-25 min delay between rainfall and runoff graph. Runoff coefficients of the four different rainfall are 0.33, 0.62, 0.67 and 0.73, respectively. The 30/30 first flush phenomenon is found in Chendulu CSS. The peak of pollutant concentration graph lags rainfall peak about 30-40 min. The pH and event mean concentration (EMC) of Cu, Zn, Cr, Cd, Pb and Ni totally measure up to environmental quality standards V for surface water of China besides COD, BOD5, NH4(+) -N and TP, and the EMC of COD, BOD5, NH4(+) -N and TP are 225.0-544.1, 31.5-98.9, 8.9-44.2 and 1.98-3.52 mg x L(-1), respectively. The rainfall-runoff pollutant concentration in Chendulu CSS is close to those of other foreign cites. At the confidence level of p < 0.01, good relationships exist between SS and COD, BOD5, NH4(+) -N and TP, respectively, and the average proportion of particulate organic pollutant and nutrient is 70.21%.

Mechanistic study of lead desorption during the leaching process of ion-absorbed rare earths: pH effect and the column experiment

NASA Astrophysics Data System (ADS)

Xue, Q.; Tang, J., Sr.; Chen, H.

2017-12-01

High concentrations of ammonium sulfate, often used in the in-situ mining process, can result in a decrease of pH in the environment and dissolution of rare earth metals. Ammonium sulfate can also cause desorption of toxic heavy metals, leading to environmental and human health implications. In this study, the desorption behavior and fraction changes of lead in the ion-absorbed rare earth ore were studied using batch desorption experiments and column leaching tests. Results from batch desorption experiments showed that the desorption process of lead included fast and slow stages, and followed an Elovich model well. The desorption rate and the proportion of lead content in the solution to the total lead in the soil were observed to increase with a decrease in the initial pH of the ammonium sulfate solution. The lead in soil included an acid extractable fraction, reducible fraction, oxidizable fraction, and a residual fraction, with the predominant fractions being the reducible and acid extractable fractions. 96% of the extractable fraction in soil were desorbed into solution at pH=3.0, and the content of the reducible fraction was observed to initially increase (when pH>4.0) and then decrease (when pH<4.0) with a decrease in pH. Column leaching tests indicated that the content of lead in the different fractions of soil followed the trend of reducible fraction > oxidizable fraction > acid extractable fraction > residual fraction after the simulating leaching mining process. The change in pH was also found to have a larger influence on the acid extractable and reducible fractions than the other two fractions. The proportion of the extractable fraction being leached was ca. 86%, and the reducible fraction was enriched along the migration direction of the leaching liquid. These results suggest that certain lead fractions may desorb again and contaminate the environment via acid rain, which provides significant information for environmental assessment and remediation after mining process.

Estimation of Rain Intensity Spectra over the Continental US Using Ground Radar-Gauge Measurements

NASA Technical Reports Server (NTRS)

Lin, Xin; Hou, Arthur Y.

2013-01-01

A high-resolution surface rainfall product is used to estimate rain characteristics over the continental US as a function of rain intensity. By defining each data at 4-km horizontal resolutions and 1-h temporal resolutions as an individual precipitating/nonprecipitating sample, statistics of rain occurrence and rain volume including their geographical and seasonal variations are documented. Quantitative estimations are also conducted to evaluate the impact of missing light rain events due to satellite sensors' detection capabilities. It is found that statistics of rain characteristics have large seasonal and geographical variations across the continental US. Although heavy rain events (> 10 mm/hr.) only occupy 2.6% of total rain occurrence, they may contribute to 27% of total rain volume. Light rain events (< 1.0 mm/hr.), occurring much more frequently (65%) than heavy rain events, can also make important contributions (15%) to the total rain volume. For minimum detectable rain rates setting at 0.5 and 0.2 mm/hr which are close to sensitivities of the current and future space-borne precipitation radars, there are about 43% and 11% of total rain occurrence below these thresholds, and they respectively represent 7% and 0.8% of total rain volume. For passive microwave sensors with their rain pixel sizes ranging from 14 to 16 km and the minimum detectable rain rates around 1 mm/hr., the missed light rain events may account for 70% of train occurrence and 16% of rain volume. Statistics of rain characteristics are also examined on domains with different temporal and spatial resolutions. Current issues in estimates of rain characteristics from satellite measurements and model outputs are discussed.

Geochemical and mineralogical study of a site severely polluted with heavy metals (Maatheide, Lommel, Belgium)

NASA Astrophysics Data System (ADS)

Horckmans, L.; Swennen, R.; Deckers, J.

2006-07-01

The former zinc smelter site ‘de Maatheide’ in Lommel (Belgium) was severely polluted with heavy metals and the pollution spread into the surroundings by rain water leaching and wind transportation. This study focuses on the processes of immobilization and natural attenuation that took place on the site. Three important factors were found. Firstly, the high pH values (pH 7-8) in the topsoil influence the mobility of heavy metals. Secondly, the spodic horizons below the polluted top layer seem to accumulate heavy metals, thereby slowing down their release into the environment. Finally, the glassy phases and iron oxi/hydroxides that are present can encapsulate heavy metals during their formation/recrystallization, thereby immobilizing them. An additional shielding effect results from the reaction rims of goethite around the contaminant phases, which partially inhibit the weathering process and release of contaminants. This shielding effect is an important factor to take into account when modelling contaminant release.

Acid rain monitoring in East-Central Florida from 1977 to present

NASA Technical Reports Server (NTRS)

Madsen, B. C.; Kheoh, T.; Hinkle, C. R.; Dreschel, T. W.

1990-01-01

Rainfall has been collected on the University of Central Florida campus and at the Kennedy Space Center over a 12 year period. The chemical composition has been determined and summarized by monthly, annual periods, and for the entire 12 year period at both locations. The weighted average pH at each site is 4.58; however, annual weighted average pH has been equal to or above the 12 year average during six of the past eight years. Nitrate concentrations have increased slightly during recent years while excess sulfate concentrations have remained below the 12 year weighted average during six of the past seven years. Stepwise regression suggests that sulfate, nitrate, ammonium ion and calcium play major roles in the description of rainwater acidity. Annual acid deposition and annual rainfall have varied from 20 to 50 meg/(m(exp 2) year) and 100 to 180 cm/year, respectively. Sea salt comprises at least 25 percent of the total ionic composition.

Health Status of Women in the Army.

DTIC Science & Technology

1987-08-10

arta Bel, N, m coinvstigtorprovdedthe ontnua encoragmen an atenton t de iltha maes his epot te podut i is Althughnot rignall asig e tothe tud, sh...4oO BRCNCHITIS, ACUTE 44 44 703 INGrOwN TOENAIL 41 45 692 DE -MATiTiS. CONTACT, NOS 4: 46 76v NAuSEA;VOMITING 34 50 47 4u1 mPERTENSiON, ESSENTIAL ’- 48...77.59X 4 :55b NEUROMA, MORTON’S iPLANTAR NERVE) 0.424 7E.07% A -I;9o FATELLA SiNDROME 0.48Z 78.551 4 7:44 RAIN. bPH, NRADIATING SYMPTOMS 0.45% 7t0: 4

Response of transpiration to rain pulses for two tree species in a semiarid plantation.

PubMed

Chen, Lixin; Zhang, Zhiqiang; Zeppel, Melanie; Liu, Caifeng; Guo, Junting; Zhu, Jinzhao; Zhang, Xuepei; Zhang, Jianjun; Zha, Tonggang

2014-09-01

Responses of transpiration (Ec) to rain pulses are presented for two semiarid tree species in a stand of Pinus tabulaeformis and Robinia pseudoacacia. Our objectives are to investigate (1) the environmental control over the stand transpiration after rainfall by analyzing the effect of vapor pressure deficit (VPD), soil water condition, and rainfall on the post-rainfall Ec development and recovery rate, and (2) the species responses to rain pulses and implications on vegetation coverage under a changing rainfall regime. Results showed that the sensitivity of canopy conductance (Gc) to VPD varied under different incident radiation and soil water conditions, and the two species exhibited the same hydraulic control (-dG c/dlnVPD to Gcref ratio) over transpiration. Strengthened physiological control and low sapwood area of the stand contributed to low Ec. VPD after rainfall significantly influenced the magnitude and time series of post-rainfall stand Ec. The fluctuation of post-rainfall VPD in comparison with the pre-rainfall influenced the Ec recovery. Further, the stand Ec was significantly related to monthly rainfall, but the recovery was independent of the rainfall event size. Ec enhanced with cumulative soil moisture change (ΔVWC) within each dry-wet cycle, yet still was limited in large rainfall months. The two species had different response patterns of post-rainfall Ec recovery. Ec recovery of P. tabulaeformis was influenced by the pre- and post-rainfall VPD differences and the duration of rainless interval. R. pseudoacacia showed a larger immediate post-rainfall Ec increase than P. tabulaeformis did. We, therefore, concluded that concentrated rainfall events do not trigger significant increase of transpiration unless large events penetrate the deep soil and the species differences of Ec in response to pulses of rain may shape the composition of semiarid woodlands under future rainfall regimes.

Tropical stormwater floods: a sustainable solution

NASA Astrophysics Data System (ADS)

Molinie, Jack; Bade, Francois; Nagau, Jimmy; Nuiro, Paul

2017-04-01

Stormwater management is one of the most difficult problem of urban and suburban area. The urban runoff volume related to rain intensity and surfaces properties can lead to flood. Thereby, urban flooding creates considerable infrastructure problem, economics and human damages. In tropical countries, burgeoning human population coupled with unplanned urbanization altered the natural drainage. Consequently, classical intense rain around 100 cm/h produces frequent street flooding. In our case, we study the management of intense tropical rain, by using a network of individual rain storage tanks. The study area is economical and industrial zone installed in a coastal plain , with seventy per cent of impermeable surface (roads, parking lots, building roof, …) and thirty per cent of wetland (mangrove, …). Our solution is to delay the routes and parking lots runoff to the roof one. We propose sustainable individual water storage and a real time dynamical management, which permit to control the roof water arrival in the stormwater culvert. During the remaining time, the stored rainwater can be used for domestic activities instead of the use of drinking water.

Contamination content introduced with rain water to the rivers after they have been cleaned in separators of petroleum compounds

NASA Astrophysics Data System (ADS)

Łapiński, Dawid; Wiater, Józefa

2018-02-01

The article presents the results of rainwater quality studies. The rainwater flowing from the surface of urbanized areas of the city of Białystok discharged into the river after they have been cleansed with separators petroleum compounds. Also discussed are issues related to with rain water and the problem to need develop them. Contaminated flushes from sealed surfaces such as street squares, sidewalks, parking lots, etc., during periods of rain or thawing, pose a serious threat to the natural environment. The work presents analyzes of such pollutants as general slurry, heavy metals, chlorides, BOD5, COD, etc., which once penetrate rainwater into Biała River. Five measurement and control points located in a typical urban drainage basin were selected for the study. The tests were taken in the spring of 2017 in two measuring series. The first series was taken during the long-term precipitation, while the second was after the almost one-month rain-free period, at the time of the first precipitation.

Calculation of Individual Tree Water Use in a Bornean Tropical Rain Forest Using Individual-Based Dynamic Vegetation Model SEIB-DGVM

NASA Astrophysics Data System (ADS)

Nakai, T.; Kumagai, T.; Saito, T.; Matsumoto, K.; Kume, T.; Nakagawa, M.; Sato, H.

2015-12-01

Bornean tropical rain forests are among the moistest biomes of the world with abundant rainfall throughout the year, and considered to be vulnerable to a change in the rainfall regime; e.g., high tree mortality was reported in such forests induced by a severe drought associated with the ENSO event in 1997-1998. In order to assess the effect (risk) of future climate change on eco-hydrology in such tropical rain forests, it is important to understand the water use of trees individually, because the vulnerability or mortality of trees against climate change can depend on the size of trees. Therefore, we refined the Spatially Explicit Individual-Based Dynamic Global Vegetation Model (SEIB-DGVM) so that the transpiration and its control by stomata are calculated for each individual tree. By using this model, we simulated the transpiration of each tree and its DBH-size dependency, and successfully reproduced the measured data of sap flow of trees and eddy covariance flux data obtained in a Bornean lowland tropical rain forest in Lambir Hills National Park, Sarawak, Malaysia.

Rain core structure statistics derived from radar and disdrometer measurements in the mid-Atlantic coast of the US

NASA Technical Reports Server (NTRS)

Goldhirsh, Julius; Musiani, Bert H.

1989-01-01

During a period spanning more than 5 years, low elevation radar measurements of rain were systematically obtained in the mid-Atlantic coast of the U.S. Drop size distribution measurements with a disdrometer were also acquired on the same rain days. The drop size data were utilized to convert the radar reflectivity factors to estimated rain rates for the respective rain days of operation. Applying high level algorithms to the rain data, core values of rain intensities were identified (peak rain rates), and families of rain rate isopleths analyzed. In particular, equicircle diameters of the family of isopleths enveloping peak rain intensities were statistically characterized. The presented results represents the analysis of two rain days, 12 radar scans, corresponding to 430 culled rain rate isopleths from an available data base of 22,000 contours, approximately 100 scans encompassing 17 rain days. The results presented show trends of the average rain rate vs. contour scale dimensions, and cumulative distributions of rain cell dimensions which belong to core families of precipitation.

Why Devil's town has Devil's water

NASA Astrophysics Data System (ADS)

Jovic, Sladjana; Mitriceski, Bojana

2015-04-01

Why Devil's town has Devil's water In the south of Serbia, lies a first-class natural landmark "Devil's Town" at an altitude of 660-700 m. Earthen figures or "towers" as the locals call them, are located in the watershed between two gullies, whose sources joined together create a unique erosive formation, tremendously demolished by the erosive processes. The gullies also have strange names: "Devil's Gully" and "Hell's Gully". There are two rare natural phenomena at the same spot: 202 earthen figures of different shape and dimension, from 2 m to 15 m in height, and from 0.5 m to 3 m in width, with stone caps on the top. They are an outcome of a specific erosive process that lasts for centuries. When figures are formed, they grow, change, shorten, gradually (very slowly) disappear and reappear. The loose soil is dissolved and washed away by the rain. However, the material under the stone caps is protected from the "bombardment" of the rain drops and washout, and remains in place in the form of the rising earthen pillars - figures. Another natural rarity in "Devil's Town" are two springs of extraordinary properties "Devil's Water", which is located in vicinity of these earthen figures, is a cold and extremely acid spring (pH 1.5) of high mineral concentration (15 g/l of water), springing out in "Devil's Gully". In comparison to drinking water, it is 10 to 1000 times richer in minerals (aluminium, iron, potassium, copper, nickel, sulphur, and alaun). "Red Well" is another spring located downstream, in the alluvial plain, 400 m away from the first spring. Its water (pH 3.5) is less acid and has a lower general mineral concentration (4.372 mg/l of water). Due to the oxidation of iron, which is contained in water in large amounts, an attractive red terrace in the form of a fan is created. The main assessment for students is to take some examples of water from Devils Gully and the others from Red Well . Second part is to find out content of minerals in water examples and this part should be done in laboratory while measured of PH with PH meters should be done on the spot. At the same time students can analyze erosion process which is developed in this place. This type of public classes is very popular and teaching and learning process are taking place at the same time.

Further emissions cuts needed for speedier acid rain recovery

NASA Astrophysics Data System (ADS)

Showstack, Randy

Some people may have thought that the problem of acid deposition, commonly referred to as acid rain, had been solved in the United States with the passage of the Acid Deposition Control Program under Title IV of the 1990 Clean Air Act Amendments (CAAA).Although that legislation has helped to dramatically limit emissions of sulfur dioxide and nitrogen oxide—gases that can react in the atmosphere and form acidic compounds, including fine particles of sulfates and nitrates— much steeper cuts are needed for a quicker recovery from acid rain in the north-eastern United States, according to a new scientific appraisal of the effectiveness of measures called for in that law. The appraisal was issued on March 26 and is entitled “Acidic Deposition in the Northeastern United States: Sources and Inputs, Ecosystem Effects, and Management Strategies.”

European views on controlling acid rain. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fay, J.A.

The National Governors Association (NGA) will be considering a plan for alleviating acid rain effects by reduction of emissions of sulfur and nitrogen oxides. This plan, in some respects similar to current legislative proposals in Congress, was formulated by the northeastern governors with administrative support from the Commonwealth of Massachusetts. Lt. Governor John Kerry has undertaken to prepare this plan for consideration by the NGA. In order to provide a better understanding of how other industrialized nations are dealing with the acid rain problem, the office of Lt. Gov. Kerry arranged for a tour of European countries during the weekmore » beginning 10 January 1984. Norway, Sweden, the Federal Republic of Germany (FRG), Belgium and the United Kingdom (UK) were visited, as well as the Commission of the European Communities (EEC) in Brussels.« less

N2O emission characteristics and its affecting factors in rain-fed potato fields in Wuchuan County, China

NASA Astrophysics Data System (ADS)

Wang, Liwei; Wang, Cheng; Pan, Zhihua; Xu, Hui; Gao, Lin; Zhao, Peiyi; Dong, Zhiqiang; Zhang, Jingting; Cui, Guohui; Wang, Sen; Han, Guolin; Zhao, hui

2017-05-01

Representing an important greenhouse gas, nitrous oxide (N2O) emission from cultivated land is a hot topic in current climate change research. This study examined the influences of nitrogen fertilisation, temperature and soil moisture on the ammonia monooxygenase subunit A ( amoA) gene copy numbers and N2O emission characteristics. The experimental observation of N2O fluxes was based on the static chamber-gas chromatographic method. The ammonia-oxidising bacteria (AOB) and ammonia-oxidising archaea (AOA) gene copy numbers in different periods were measured by real-time polymerase chain reaction (PCR). The results indicated that rain-fed potato field was a N2O source, and the average annual N2O emission was approximately 0.46 ± 0.06 kgN2O-N/ha/year. N2O emissions increased significantly with increase in fertilisation, temperatures below 19.6 °C and soil volumetric water content under 15%. Crop rotation appreciably decreases N2O emissions by 34.4 to 52.4% compared to continuous cropping in rain-fed potato fields. The significant correlation between N2O fluxes and AOB copy numbers implied that N2O emissions were primarily controlled by AOB in rain-fed potato fields. The research has important theoretical and practical value for understanding N2O emissions from rain-fed dry farmland fields.

N2O emission characteristics and its affecting factors in rain-fed potato fields in Wuchuan County, China.

PubMed

Wang, Liwei; Wang, Cheng; Pan, Zhihua; Xu, Hui; Gao, Lin; Zhao, Peiyi; Dong, Zhiqiang; Zhang, Jingting; Cui, Guohui; Wang, Sen; Han, Guolin; Zhao, Hui

2017-05-01

Representing an important greenhouse gas, nitrous oxide (N 2 O) emission from cultivated land is a hot topic in current climate change research. This study examined the influences of nitrogen fertilisation, temperature and soil moisture on the ammonia monooxygenase subunit A (amoA) gene copy numbers and N 2 O emission characteristics. The experimental observation of N 2 O fluxes was based on the static chamber-gas chromatographic method. The ammonia-oxidising bacteria (AOB) and ammonia-oxidising archaea (AOA) gene copy numbers in different periods were measured by real-time polymerase chain reaction (PCR). The results indicated that rain-fed potato field was a N 2 O source, and the average annual N 2 O emission was approximately 0.46 ± 0.06 kgN 2 O-N/ha/year. N 2 O emissions increased significantly with increase in fertilisation, temperatures below 19.6 °C and soil volumetric water content under 15%. Crop rotation appreciably decreases N 2 O emissions by 34.4 to 52.4% compared to continuous cropping in rain-fed potato fields. The significant correlation between N 2 O fluxes and AOB copy numbers implied that N 2 O emissions were primarily controlled by AOB in rain-fed potato fields. The research has important theoretical and practical value for understanding N 2 O emissions from rain-fed dry farmland fields.

Estimating Rain Rates from Tipping-Bucket Rain Gauge Measurements

NASA Technical Reports Server (NTRS)

Wang, Jianxin; Fisher, Brad L.; Wolff, David B.

2007-01-01

This paper describes the cubic spline based operational system for the generation of the TRMM one-minute rain rate product 2A-56 from Tipping Bucket (TB) gauge measurements. Methodological issues associated with applying the cubic spline to the TB gauge rain rate estimation are closely examined. A simulated TB gauge from a Joss-Waldvogel (JW) disdrometer is employed to evaluate effects of time scales and rain event definitions on errors of the rain rate estimation. The comparison between rain rates measured from the JW disdrometer and those estimated from the simulated TB gauge shows good overall agreement; however, the TB gauge suffers sampling problems, resulting in errors in the rain rate estimation. These errors are very sensitive to the time scale of rain rates. One-minute rain rates suffer substantial errors, especially at low rain rates. When one minute rain rates are averaged to 4-7 minute or longer time scales, the errors dramatically reduce. The rain event duration is very sensitive to the event definition but the event rain total is rather insensitive, provided that the events with less than 1 millimeter rain totals are excluded. Estimated lower rain rates are sensitive to the event definition whereas the higher rates are not. The median relative absolute errors are about 22% and 32% for 1-minute TB rain rates higher and lower than 3 mm per hour, respectively. These errors decrease to 5% and 14% when TB rain rates are used at 7-minute scale. The radar reflectivity-rainrate (Ze-R) distributions drawn from large amount of 7-minute TB rain rates and radar reflectivity data are mostly insensitive to the event definition.

FLUSHING FOR SEWER SEDIMENT, CORROSION, AND POLLUTION CONTROL

EPA Science Inventory

This presentation overviews causes of sewer deterioration and heavy pollutant discharges caused by rain events together with a discussion of their control methods. In particular, it covers in-sewer- and combined sewer overflow- (CSO-) storage-tank-flushing systems for removal of ...

Acid Rain: What It Is -- How You Can Help!

ERIC Educational Resources Information Center

National Wildlife Federation, Washington, DC.

This publication discusses the nature and consequences of acid precipitation (commonly called acid rain). Topic areas include: (1) the chemical nature of acid rain; (2) sources of acid rain; (3) geographic areas where acid rain is a problem; (4) effects of acid rain on lakes; (5) effect of acid rain on vegetation; (6) possible effects of acid rain…

[Export of Total Organic Carbon (TOC) from Karst Watershed and Its Influencing Factors: An Example from Xueyudong Underground River System, Chongqing].

PubMed

Wang, Qiao-lian; Jiang, Yong-jun; Chen, Yu

2016-05-15

High time-resolution auto-monitoring techniques were used to obtain the data for TOC and hydrogeochemistry of groundwater, and air temperature and precipitation from August 2014 to September 2015 in Xueyu Cave karst watershed, Southwest China, and then the principal component regression model was used to reveal the variation of TOC in groundwater and its influencing factors. The results indicated that there were significant variations of the TOC and hydrogeochemistry of groundwater in seasonal timescale. The temperature and specific conductance (SpC) of groundwater showed higher values in summer and lower values in winter; while an opposite variation pattern for pH in groundwater was observed, and the TOC and turbidity of groundwater showed higher values in winter and summer seasons and lower values in spring and autumn seasons. Meanwhile, high time-resolution data revealed that the TOC of groundwater responded quickly to rainfall events with different intensities. Generally, an increasing trend for TOC in groundwater was observed during raining and a decreasing trend for TOC in groundwater was shown after rainfall events, especially after storm events due to the dilution effect of rainfall. The export and variations of the TOC in groundwater were mainly controlled by the precipitation and discharge of underground river in the study area, as revealed by the principal component regression model. The TOC increased with the increase of the precipitation, discharge and turbidity of groundwater, and declined with the increase of air temperature and pH of groundwater.

Seasonal variations in water quality of an oxbow lake in response to multiple short-time pulses of flooding (Jataí Ecological Station--Mogi-Guaçu River, Luiz Antonio, SP-Brazil).

PubMed

Krusche, A V; Mozeto, A A

1999-01-01

Mogi-Guaçu River is a six-order floodplain river in the upper Paraná River Basin, Southern Brazil. Its yearly discharge varies from a minimum of 100 m3.s-1 to a maximum of 600 m3.s-1. Diogo Lake is a shallow lake located at its floodplain within the Jataí Ecological Station (Luiz Antonio, São Paulo State) and is connected throughout the year to the river through a narrow and shallow channel. The main finding of this study is that the river hidrology controls the annual variations in lake hydrochemistry through a series of hydraulic effects related to oscillations in river discharge. Lake water quality is a resultant of differential contribution from local and regional watersheds. During the low water period, lake water quality is determined by inputs from Cafundó Creek, which drains the local watershed into the lake. Raising the river level during the rain season results in the damming of lake and culminates with the entrance of river waters into the plain. The geochemistry of waters in this system is determined by weathering of sandstones with basalt intrusions. Waters are acidic (river pH = 6.00 to 7.02 and stream-lake pH = 5.15 to 6.7) and dominant cations are Na+ and K+. Major anions are almost exclusively represented by bicarbonate and an unknown concentration of organic acid anions. The overall ionic load of these soft waters in the system is therefore very low.

On Utilization of NEXRAD Scan Strategy Information to Infer Discrepancies Associated With Radar and Rain Gauge Surface Volumetric Rainfall Accumulations

NASA Technical Reports Server (NTRS)

Roy, Biswadev; Datta, Saswati; Jones, W. Linwood; Kasparis, Takis; Einaudi, Franco (Technical Monitor)

2000-01-01

To evaluate the Tropical Rainfall Measuring Mission (TRMM) monthly Ground Validation (GV) rain map, 42 quality controlled tipping bucket rain gauge data (1 minute interpolated rain rates) were utilized. We have compared the gauge data to the surface volumetric rainfall accumulation of NEXRAD reflectivity field, (converting to rain rates using a 0.5 dB resolution smooth Z-R table). The comparison was carried out from data collected at Melbourne, Florida during the month of July 98. GV operational level 3 (L3 monthly) accumulation algorithm was used to obtain surface volumetric accumulations for the radar. The gauge records were accumulated using the 1 minute interpolated rain rates while the radar Volume Scan (VOS) intervals remain less than or equal to 75 minutes. The correlation coefficient for the radar and gauge totals for the monthly time-scale remain at 0.93, however, a large difference was noted between the gauge and radar derived rain accumulation when the radar data interval is either 9 minute, or 10 minute. This difference in radar and gauge accumulation is being explained in terms of the radar scan strategy information. The discrepancy in terms of the Volume Coverage Pattern (VCP) of the NEXRAD is being reported where VCP mode is ascertained using the radar tilt angle information. Hourly radar and gauge accumulations have been computed using the present operational L3 method supplemented with a threshold period of +/- 5 minutes (based on a sensitivity analysis). These radar and gauge accumulations are subsequently improved using a radar hourly scan weighting factor (taking ratio of the radar scan frequency within a time bin to the 7436 total radar scans for the month). This GV procedure is further being improved by introducing a spatial smoothing method to yield reasonable bulk radar to gauge ratio for the hourly and daily scales.

Rain Simulation for the Test of Automotive Surround Sensors

NASA Astrophysics Data System (ADS)

Hasirlioglu, Sinan; Riener, Andreas; Doric, Igor

2017-04-01

The WHO Global Health Observatory data indicates that over 1.25 million people die in traffic accidents annually. To save lives, car manufacturers spend lot of efforts on the development of novel safety systems aiming to avoid or mitigate accidents and provide maximum protection for vehicle occupants as well as vulnerable road users. All the safety features mainly rely on data from surround sensors such as radar, lidar and camera and intelligent vehicles today use these environmental data for instant decision making and vehicle control. As already small errors in sensor data measurements could lead to catastrophes like major injuries or road traffic fatalities, it is of utmost importance to ensure high reliability and accuracy of sensors and safety systems. This work focuses on the influence of environmental factors such as rain conditions, as it is known that rain drops scatter the electromagnetic waves. The result is incorrect measurements with a direct negative impact on environment detection. To identify potential problems of sensors under varying environmental conditions, systems are today tested in real-world settings with two main problems: First, tests are time-consuming and second, environmental conditions are not reproducible. Our approach to test the influence of weather on automotive sensors is to use an indoor rain simulator. Our artificial rain maker, installed at CARISSMA (Center of Automotive Research on Integrated Safety Systems and Measurement Area), is parametrized with rain characteristics measured in the field using a standard disdrometer. System behavior on artificial rain is compared and validated with natural rainfall. With this simulator it is finally possible to test environmental influence at various levels and under reproducible conditions. This saves lot of efforts required for the test process itself and furthermore has a positive impact on the reliability of sensor systems due to the fact that test driven development is enabled.

Tropical warm pool rainfall variability and impact on upper ocean variability throughout the Madden-Julian oscillation

NASA Astrophysics Data System (ADS)

Thompson, Elizabeth J.

Heating and rain freshening often stabilize the upper tropical ocean, bringing the ocean mixed layer depth to the sea surface. Thin mixed layer depths concentrate subsequent fluxes of heat, momentum, and freshwater in a thin layer. Rapid heating and cooling of the tropical sea surface is important for controlling or triggering atmospheric convection. Ocean mixed layer depth and SST variability due to rainfall events have not been as comprehensively explored as the ocean's response to heating or momentum fluxes, but are very important to understand in the tropical warm pool where precipitation exceeds evaporation and many climate phenomena such as ENSO and the MJO (Madden Julian Oscillation) originate. The first part of the dissertation investigates tropical, oceanic convective and stratiform rainfall variability and determines how to most accurately estimate rainfall accumulation with radar from each rain type. The second, main part of the dissertation uses central Indian Ocean salinity and temperature microstructure measurements and surrounding radar-derived rainfall maps throughout two DYNAMO MJO events to determine the impact of precipitating systems on upper-ocean mixed layer depth and resulting SST variability. The ocean mixed layer was as shallow as 0-5 m during 528/1071 observation hours throughout 2 MJOs (54% of the data record). Out of 43 observation days, thirty-eight near-surface mixed layer depth events were attributed to freshwater stabilization, called rain-formed mixed layers (RFLs). Thirty other mixed layer stratification events were classified as diurnal warm layers (DWLs) due to stable temperature stratification by daytime heating. RFLs and DWLs were observed to interact in two ways: 1) RFLs fill preexisting DWLs and add to total near-surface mixed layer stratification, which occurred ten times; 2) RFLs last long enough to heat, creating a new DWL on top of the RFL, which happened nine times. These combination stratification events were responsible for the highest SST warming rates and some of the highest SSTs leading up to the most active precipitation and wind stage of the each MJO. DWLs without RFL interaction helped produce the highest SSTs in suppressed MJO conditions. As storm intensity, frequency, duration, and the ability of storms to maintain stratiform rain areas increased, RFLS became more common in the disturbed and active MJO phases. Along with the barrier layer, DWL and RFL stratification events helped suppress wind-mixing, cooling, and mixed layer deepening throughout the MJO. We hypothesize that both salinity and temperature stratification events, and their interactions, are important for controlling SST variability and therefore MJO initiation in the Indian Ocean. Most RFLs were caused by submesoscale and mesoscale convective systems with stratiform rain components and local rain accumulations above 10 mm but with winds mostly below 8 m s-1. We hypothesize that the stratiform rain components of storms helped stratify the ocean by providing weak but widespread, steady, long-lived freshwater fluxes. Although generally limited to rain rates ≤ 10 mm hr-1, it is demonstrated that stratiform rain can exert a strong buoyancy flux into the ocean, i.e. as high as maximum daytime solar heating. Storm morphology and the preexisting vertical structure of ocean stability were critical in determining ocean mixed layer depth variability in the presence of rain. Therefore, we suggest that high spatial and temporal resolution coupled ocean-atmosphere models that can parameterize or resolve storm morphology as well as ocean mixed layer and barrier layer evolution are needed to reproduce the diurnal and intraseasonal SST variability documented throughout the MJO.

Proton Transport and pH Control in Fungi.

PubMed

Kane, Patricia M

2016-01-01

Despite diverse and changing extracellular environments, fungi maintain a relatively constant cytosolic pH and numerous organelles of distinct lumenal pH. Key players in fungal pH control are V-ATPases and the P-type proton pump Pma1. These two proton pumps act in concert with a large array of other transporters and are highly regulated. The activities of Pma1 and the V-ATPase are coordinated under some conditions, suggesting that pH in the cytosol and organelles is not controlled independently. Genomic studies, particularly in the highly tractable S. cerevisiae, are beginning to provide a systems-level view of pH control, including transcriptional responses to acid or alkaline ambient pH and definition of the full set of regulators required to maintain pH homeostasis. Genetically encoded pH sensors have provided new insights into localized mechanisms of pH control, as well as highlighting the dynamic nature of pH responses to the extracellular environment. Recent studies indicate that cellular pH plays a genuine signaling role that connects nutrient availability and growth rate through a number of mechanisms. Many of the pH control mechanisms found in S. cerevisiae are shared with other fungi, with adaptations for their individual physiological contexts. Fungi deploy certain proton transport and pH control mechanisms not shared with other eukaryotes; these regulators of cellular pH are potential antifungal targets. This review describes current and emerging knowledge proton transport and pH control mechanisms in S. cerevisiae and briefly discusses how these mechanisms vary among fungi.

Proton Transport and pH Control in Fungi

PubMed Central

Kane, Patricia M.

2018-01-01

Despite diverse and changing extracellular environments, fungi maintain a relatively constant cytosolic pH and numerous organelles of distinct lumenal pH. Key players in fungal pH control are V-ATPases and the P-type proton pump Pma1. These two proton pumps act in concert with a large array of other transporters and are highly regulated. The activities of Pma1 and the V-ATPaseare coordinated under some conditions, suggesting that pH in the cytosol and organelles is not controlled independently. Genomic studies, particularly in the highly tractable S. cerevisiae, are beginning to provide a systems-level view of pH control, including transcriptional responses to acid or alkaline ambient pH and definition of the full set of regulators required to maintain pH homeostasis. Genetically encoded pH sensors have provided new insights into localized mechanisms of pH control, as well as highlighting the dynamic nature of pH responses to the extracellular environment. Recent studies indicate that cellular pH plays a genuine signaling role that connects nutrient availability and growth rate through a number of mechanisms. Many of the pH control mechanisms found in S. cerevisiae are shared with other fungi, with adaptations for their individual physiological contexts. Fungi deploy certain proton transport and pH control mechanisms not shared with other eukaryotes; these regulators of cellular pH are potential antifungal targets. This re view describes current and emerging knowledge proton transport and pH control mechanisms in S. cerevisiae and briefly discusses how these mechanisms vary among fungi. PMID:26721270

Seasonal patterns in the transmission of Schistosoma haematobium in Rhodesia, and its control by winter application of molluscicide.

PubMed

Shiff, C J; Coutts, W C; Yiannakis, C; Holmes, R W

1979-01-01

Surveys of snails occurring at water contact points used by rural people in Rhodesia show that transmission of Schistosoma haematobium is very high during the spring and early summer seasons. Although infected snails are found in all seasons, fewest occur in winter and during the heavy rains. It is suggested that the bionomics of this parasite depends on pre-rain transmission because destruction of infected snails during winter reduces the reservoir of infection in the area and also the level of parasitaemia in local schoolchildren.

A laboratory rainfall simulator to study the soil erosion and runoff water

NASA Astrophysics Data System (ADS)

Cancelo González, Javier; Rial, M. E.; Díaz-Fierros, Francisco

2010-05-01

The soil erosion and the runoff water composition in some areas affected by forest fires or submitted to intensive agriculture are an important factor to keep an account, particularly in sensitive areas like estuary and rias that have a high importance in the socioeconomic development of some regions. An understanding of runoff production indicates the processes by which pollutants reach streams and also indicates the management techniques that might be uses to minimize the discharge of these materials into surface waters. One of the most methodology implemented in the soil erosion studies is a rainfall simulation. This method can reproduce the natural soil degradation processes in field or laboratory experiences. With the aim of improve the rainfall-runoff generation, a laboratory rainfall simulator which incorporates a fan-like intermittent water jet system for rainfall generation were modified. The major change made to the rainfall simulator consist in a system to coupling stainless steel boxes, whose dimensions are 12 x 20 x 45 centimeters, and it allows to place soil samples under the rainfall simulator. Previously these boxes were used to take soil samples in field with more of 20 centimeters of depth, causing the minimum disturbance in their properties and structure. These new implementations in the rainfall simulator also allow collect water samples of runoff in two ways: firstly, the rain water that constituted the overland flow or direct runoff and besides the rain water seeps into the soil by the process of infiltration and contributed to the subsurface runoff. Among main the variables controlled in the rainfall simulations were the soil slope and the intensity and duration of rainfall. With the aim of test the prototype, six soil samples were collected in the same sampling point and subjected to rainfall simulations in laboratory with the same intensity and duration. Two samples will constitute the control test, and they were fully undisturbed, and four samples were subjected to controlled burnings with different fire severity: two samples burnt to 250°C and the other two samples burnt to 450°C. Preliminary laboratory data of soil erosion and surface and subsurface runoff were obtained. The water parameters analysed were: pH, electrical conductivity, temperature (in the moment of sampling) and suspended sediments, ammonium, nitrates, total nitrogen (Kjeldahl method), within 24 hours after sampling.

Effects of acidic solutions on element dynamics in the monsoon evergreen broad-leaved forest at Dinghushan, China. Part 2: dynamics of Fe, Cu, Mn and Al.

PubMed

Liu, Juxiu; Zhou, Guoyi; Zhang, Deqiang

2007-05-01

Soil metal dynamics are affected by acid deposition. Little knowledge is available about the process in the lateritic soils under the monsoon forest in south China. Samplings of Acmera acuminatissima, Cryptocarya concinna and Schima superba were grown from October, 2000 to July, 2002 in pots with a natural acid lateritic forest soil from Dinghushan. Pots were watered weekly with an acid solution (pH 3.05, 3.52, 4.00 or 4.40) or with tap water. Fe, Mn, Cu and Al were measured in soils, leachates and sapling leaves. Soil extractable Fe and leachate Al and Mn concentrations increased with a decreasing treatment pH. Soil reactive Al exhibited the opposite trend and decreased over time. The Ca/Al and Mg/ (Al+Mn) ratios did not decrease in the leaves of Schima superba, but decreased with a decreasing treatment pH for Cryptocaria concinna. Both ratios only decreased in the pH 3.05 treatment for Acmena Cu will not be toxic for plants since soil extractable Cu was not high and Fe will not be toxic either given that its root uptake was inhibited by Mn. Acid rains will lead to increased Mn and Al mobility in soil. Cryptocaria concinna will be the most sensible species to these changes (nutrient deficiency and direct Mn toxicity), while Schima superba should retain a good growth.

Assessment of the in vitro bioactive properties of lactic acid bacteria isolated from native ecological niches of Ecuador.

PubMed

Benavides, Ana B; Ulcuango, Mario; Yépez, Lucía; Tenea, Gabriela N

Lactic acid bacteria are known for their biotechnological potential. In various regions of Ecuador numerous indigenous biological resources are largely undocumented. In this study, we evaluated the potential probiotic characteristics and antagonistic in vitro properties of some lactic acid bacteria from native niches of the subtropical rain forests of Ecuador. These isolates were identified according to their morphological properties, standard API50CH fermentation profile and RAPD-DNA polymorphism pattern. The selected isolates were further evaluated for their probiotic potential. The isolates grew at 15°C and 45°C, survived at a pH ranging from 2.5 to 4.5 in the presence of 0.3% bile (>90%) and grew under sodium chloride conditions. All selected isolates were sensitive to ampicillin, amoxicillin and cefuroxime and some showed resistance to gentamicin, kanamycin and tetracycline. Moreover, the agar well diffusion assay showed that the supernatant of each strain at pH 3.0 and pH 4.0, but not at pH 7.0 exhibited increased antimicrobial activity (inhibition zone >15mm) against two foodborne pathogens, Escherichia coli and Salmonella spp. To our knowledge, this is the first report describing the antagonistic activity against two foodborne pathogens and the probiotic in vitro potential of lactic acid bacteria isolated from native biota of Ecuador. Copyright © 2016 Asociación Argentina de Microbiología. Publicado por Elsevier España, S.L.U. All rights reserved.

Organic Carbon Loading in Tropical Near-Shore Ecosystems: the Role of Mangrove Lagoons and Channels in Coastal Ocean Acidification

NASA Astrophysics Data System (ADS)

García, E.; Morell, J. M.

2016-02-01

Low energy tropical Caribbean shores are often dominated by highly productive mangrove ecosystems that thrive on land borne inorganic nutrient inputs and whose net production results in significant export of litter and dissolved organic compounds (DOC). These organic matrixes can be effectively transported to nearby ecosystems, including coral reefs whose vulnerability to excessive organic loading has been widely documented. This study documents the seaward transport and transformation of organic carbon from mangrove bays, trough near-shore reef ecosystems and out to open waters in the La Parguera Marine Reserve (LPMR). Considering in-situ colored dissolved organic matter (CDOM) as a tracer for DOC, absorption coefficient values (a350) were observed in the 6.13-0.02 m-1 and 14.08-0.06 m-1 during the dry (from 0 to 0.18 inches of rain) and wet seasons (from 0.68 to 4.76 inches of rain), respectively. Spectral properties (S275-295 and SR) calculations indicate that DOC is predominantly of terrestrial origin and found in high concentrations in enclosed mangrove bays and canals. Data evidences a strong gradient in CDOM concentration decreasing t from inshore to outer shelf waters. Rain precipitation correlated well with high CDOM values (aλ values doubled) and forced LPMR to behave similarly to a river influenced estuary as shown when CDOM is correlated with salinity, contrary to its predominant negative estuary profile. When correlating CDOM with pH and dissolved oxygen concentrations, it is evident that high organic matter content is driving ocean acidification in the nearshore areas. The non-conservative behavior of CDOM implies that other processes besides dilution may play a significant role in its spatial distribution.

[Species composition and diversity of soil mesofauna in the 'Holy Hills' fragmentary tropical rain forest of Xishuangbanna, China].

PubMed

Yang, X; Sha, L

2001-04-01

The species composition and diversity of soil mesofauna were examined in fragmented dry tropical seasonal rainforest of tow 'Holy Hills' of Dai nationality, compared with the continuous moist tropical seasonal rain forest of Nature Reserve in Xishuangbanna area. 5 sample quadrats were selected along the diagonal of 20 m x 20 m sampling plot, and the samples of litterfall and 0-3 cm soil were collected from each 50 cm x 10 cm sample quadrat. Animals in soil sample were collected by using dry-funnel(Tullgren's), were identified to their groups according to the order. The H' index, D.G index and the pattern of relative abundance of species were used to compare the diversity of soil mesofauna. The results showed that the disturbance of vegetation and soil resulted by tropical rainforest fragmentation was the major factor affecting the diversity of soil mesofauna. Because the fragmented forest was intruded by some pioneer tree species and the "dry and warm" effect operated, this forest had more litterfall on the floor and more humus in the soil than the continuous moist rain forest. The soil condition with more soil organic matter, total N and P, higher pH value and lower soil bulk density became more favorable to the soil mesofauna. Therefore, the species richness, abundance and diversity of soil mesofauna in fragmented forests were higher than those in continuous forest, but the similarity of species composition in fragmented forest to the continuous forest was minimal. Soil mesofauna diversity in fragmented forests did not change with decreasing fragmented area, indicating that there was no species-area effect operation in this forest. The pattern of relative abundance of species in these forest soils was logarithmic series distribution.

Source tagging modeling study of regional contributions to acid rain in summer over Liaoning Province, Northeastern China.

PubMed

Gbaguidi, Alex E; Wang, Zifa; Wang, Wei; Yang, Ting; Chen, Huan-Sheng

2018-04-01

Strong acid rain was recently observed over Northeastern China, particularly in summer in Liaoning Province where alkaline dust largely neutralized acids in the past. This seems to be related to the regional transboundary pollution and poses new challenges in acid rain control scheme in China. In order to delve into the regional transport impact, and quantify its potential contributions to such an "eruption" of acid rain over Liaoning, this paper employs an online source tagging model in coupling with the Nested Air Quality Prediction Modeling System (NAQPMS). Validation of predictions shows the model capability in reproducing key meteorological and chemical features. Acid concentration over Liaoning is more pronounced in August (average of 0.087 mg/m 3 ) with strong pollutant import from regional sources against significant depletion of basic species. Seasonal mean contributions from regional sources are assessed at both lower and upper boundary layers to elucidate the main pathways of the impact of regional sources on acid concentration over Liaoning. At the upper layer (1.2 km), regional sources contribute to acid concentration over Liaoning by 67%, mainly from Shandong (16%), Hebei (13%), Tianjin (11%) and Korean Peninsula (9%). Identified main city-receptors in Liaoning are Dandong, Dalian, Chaohu, Yingkou, Liaoyang, Jinfu, Shengyang, Panjin, Tieling, Benxi, Anshan and Fushun. At lower layer (120 m) where Liaoning local contribution is dominant (58%), regional sources account for 39% in acid concentration. However, inter-municipal acid exchanges are prominent at this layer and many cities in Liaoning are revealed as important sources of local acid production. Seasonal acid contribution average within 1.2 km-120 m attains 55%, suggesting dominance of vertical pollutant transport from regional sources towards lower boundary layer in Liaoning. As direct environmental implication, this study provides policy makers with a perspective of regulating the regional transboundary environmental impact assessment in China with application to acid rain control. Copyright © 2018 Elsevier Ltd. All rights reserved.

NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

EPA Science Inventory

The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

FLUSHING FOR SEWER SEDIMENT, CORROSION, AND POLLUTION CONTROL

EPA Science Inventory

This paper overviews causes of combined-sewer deterioration and their heavy pollutant discharges caused by rain events together with a discussion of their control methods. In particular, it covers in-sewer and combined-sewer overflow (CSO) storage-tank-flushing systems for removi...

National Scale Rainfall Map Based on Linearly Interpolated Data from Automated Weather Stations and Rain Gauges

NASA Astrophysics Data System (ADS)

Alconis, Jenalyn; Eco, Rodrigo; Mahar Francisco Lagmay, Alfredo; Lester Saddi, Ivan; Mongaya, Candeze; Figueroa, Kathleen Gay

2014-05-01

In response to the slew of disasters that devastates the Philippines on a regular basis, the national government put in place a program to address this problem. The Nationwide Operational Assessment of Hazards, or Project NOAH, consolidates the diverse scientific research being done and pushes the knowledge gained to the forefront of disaster risk reduction and management. Current activities of the project include installing rain gauges and water level sensors, conducting LIDAR surveys of critical river basins, geo-hazard mapping, and running information education campaigns. Approximately 700 automated weather stations and rain gauges installed in strategic locations in the Philippines hold the groundwork for the rainfall visualization system in the Project NOAH web portal at http://noah.dost.gov.ph. The system uses near real-time data from these stations installed in critical river basins. The sensors record the amount of rainfall in a particular area as point data updated every 10 to 15 minutes. The sensor sends the data to a central server either via GSM network or satellite data transfer for redundancy. The web portal displays the sensors as a placemarks layer on a map. When a placemark is clicked, it displays a graph of the rainfall data for the past 24 hours. The rainfall data is harvested by batch determined by a one-hour time frame. The program uses linear interpolation as the methodology implemented to visually represent a near real-time rainfall map. The algorithm allows very fast processing which is essential in near real-time systems. As more sensors are installed, precision is improved. This visualized dataset enables users to quickly discern where heavy rainfall is concentrated. It has proven invaluable on numerous occasions, such as last August 2013 when intense to torrential rains brought about by the enhanced Southwest Monsoon caused massive flooding in Metro Manila. Coupled with observations from Doppler imagery and water level sensors along the Marikina River, the local officials used this information and determined that the river would overflow in a few hours. It gave them a critical lead time to evacuate residents along the floodplain and no casualties were reported after the event.

Hydrological modelling of snail dispersal patterns in Msambweni, Kenya and potential resurgence of Schistosoma haematobium transmission.

PubMed

Clennon, J A; King, C H; Muchiri, E M; Kitron, U

2007-05-01

Urinary schistosomiasis is an important source of human morbidity in Msambweni, Kenya, where the intermediate host snail, Bulinus nasutus is found in ponds and water pools. In the past, aquatic habitats in the area have been studied separately; however, recent collections of B. nasutus snails and shells indicated that many of these ponds are in fact connected during and following sufficient rains. Satellite imagery and a geographical information system (GIS) were used to survey the main water courses and potential drainage routes, to locate potential source populations of snails and to determine probable snail dispersal routes. The 2 water bodies implicated as being the most important Schistosoma haematobium transmission foci in the area were found to differ in their degree of connectivity to other B. nasutus source habitats. One pond becomes connected even after normal rains, while the other pond requires prolonged rains or flooding to become connected with source habitats. Consequently, the transmission foci differ in their susceptibility to snail population control measures. Spatially explicit dispersal models that consider the spatial and temporal patterns of connectivity between aquatic habitats will contribute to improved snail surveillance and more focused control for urinary schistosomiasis at a local level.

State-space adjustment of radar rainfall and skill score evaluation of stochastic volume forecasts in urban drainage systems.

PubMed

Löwe, Roland; Mikkelsen, Peter Steen; Rasmussen, Michael R; Madsen, Henrik

2013-01-01

Merging of radar rainfall data with rain gauge measurements is a common approach to overcome problems in deriving rain intensities from radar measurements. We extend an existing approach for adjustment of C-band radar data using state-space models and use the resulting rainfall intensities as input for forecasting outflow from two catchments in the Copenhagen area. Stochastic grey-box models are applied to create the runoff forecasts, providing us with not only a point forecast but also a quantification of the forecast uncertainty. Evaluating the results, we can show that using the adjusted radar data improves runoff forecasts compared with using the original radar data and that rain gauge measurements as forecast input are also outperformed. Combining the data merging approach with short-term rainfall forecasting algorithms may result in further improved runoff forecasts that can be used in real time control.

Biomass and carbon dynamics of a tropical mountain rain forest in China.

PubMed

Chen, DeXiang; Li, YiDe; Liu, HePing; Xu, Han; Xiao, WenFa; Luo, TuShou; Zhou, Zhang; Lin, MingXian

2010-07-01

Biometric inventories for 25 years, from 1983 to 2005, indicated that the Jianfengling tropical mountain rain forest in Hainan, China, was either a source or a modest sink of carbon. Overall, this forest was a small carbon sink with an accumulation rate of (0.56+/-0.22) Mg C ha(-1)yr(-1), integrated from the long-term measurement data of two plots (P9201 and P8302). These findings were similar to those for African and American rain forests ((0.62+/-0.23) Mg C ha(-1)yr(-1)). The carbon density varied between (201.43+/-29.38) Mg C ha(-1) and (229.16+/-39.2) Mg C ha(-1), and averaged (214.17+/-32.42) Mg C ha(-1) for plot P9201. Plot P8302, however, varied between (223.95+/-45.92) Mg C ha(-1) and (254.85+/-48.86) Mg C ha(-1), and averaged (243.35+/-47.64) Mg C ha(-1). Quadratic relationships were found between the strength of carbon sequestration and heavy rainstorms and dry months. Precipitation and evapotranspiration are two major factors controlling carbon sequestration in the tropical mountain rain forest.

Student Science Research Associates (SSRA) 1996 Research Journal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knezovich, J.

The following student projects are reported: SSRA water research projects, various effects on polliwogs` growth and development, effects of Willow Park Golf Course on nitrate and phosphate levels in San Leandro Creek, water quality evaluation using color infrared photography, biochemical analysis of aquatic insects, effects of miracid/calcium chloride/liquid plant food on stringless bush beans, effects of vegetable oil on bean growth, effect of river water on lima beans, effect of storm water runoff on pH and phosphate levels of Dry Creek, acid rain in Modesto, use of random amplified polymorphic DNA to study Egeria Densa, and effect of marination onmore » formation of heterocyclic aromatic amines in cooked chicken meat.« less

MENU OF NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

EPA Science Inventory

The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

CONTROLLING EMISSIONS FROM FUEL AND WASTE COMBUSTION

EPA Science Inventory

Control of emissions from combustion of fuels and wastes has been a traditional focus of air pollution regulations. Significant technology developments of the '50s and '60s have been refined into reliable chemical and physical process unit operations. In the U.S., acid rain legis...

Effects of natural and simulated rainfall on indicators of ensilability and nutritive value for wilting alfalfa forages sampled before preservation as silage.

PubMed

Coblentz, W K; Muck, R E

2012-11-01

The frustrations of forage producers attempting to conserve high-quality alfalfa (Medicago sativa L.) silage during periods of unstable or inclement weather are widely known. Our objectives for this series of studies were to (1) assess indicators of ensilability, such as pH, buffering capacity, water-soluble carbohydrates (WSC), and starch for wilting alfalfa forages receiving no rainfall or damaged by simulated or natural rainfall events; (2) use these data as inputs to calculate the threshold moisture concentration that would prohibit a clostridially dominated fermentation; and (3) further evaluate the effects of rain damage or no rain damage on measures of forage nutritive value. Rainfall events were applied to wilting forages by both simulated and natural methods over multiple studies distributed across 4 independent forage harvests. Generally, simulated rainfall was applied to alfalfa under controlled conditions in which forages were relatively wet at the time of application, and subsequently were dried to final moisture endpoints under near ideal conditions within a constant temperature/humidity environmental chamber, thereby limiting postwetting wilting time to ≤21 h. As a result, indicators of ensilability, as well as measures of nutritive value, changed only marginally as a result of treatment. Consistently, reductions in concentrations of WSC and starch occurred, but changes in WSC were relatively modest, and postwetting concentrations of WSC may have been buoyed by hydrolysis of starch. When forages were subjected to natural rainfall events followed by prolonged exposure under field conditions, indicators of ensilability were much less desirable. In one study in which alfalfa received 49.3mm of natural rainfall over a prolonged (8-d) field-exposure period, fresh pH increased from 6.48 to 7.43 within all forages exposed to these extended, moist wilting conditions. Furthermore, sharp reductions were observed in buffering capacity (410 vs. 337 meq/kg of DM), WSC (6.13 vs. 2.90%), starch (2.28 vs. 0.45%), and clostridially dominated fermentation (62.7 vs. 59.4%). Based on these experiments, the potential for good fermentation is affected only minimally by single rainfall events applied to relatively wet forages, provided these events are followed by rapid dehydration; however, attaining acceptable silage fermentations with forages subjected to prolonged exposure under poor drying conditions is likely to be far more problematic. Copyright © 2012 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Verification of Satellite Rainfall Estimates from the Tropical Rainfall Measuring Mission over Ground Validation Sites

NASA Astrophysics Data System (ADS)

Fisher, B. L.; Wolff, D. B.; Silberstein, D. S.; Marks, D. M.; Pippitt, J. L.

2007-12-01

The Tropical Rainfall Measuring Mission's (TRMM) Ground Validation (GV) Program was originally established with the principal long-term goal of determining the random errors and systematic biases stemming from the application of the TRMM rainfall algorithms. The GV Program has been structured around two validation strategies: 1) determining the quantitative accuracy of the integrated monthly rainfall products at GV regional sites over large areas of about 500 km2 using integrated ground measurements and 2) evaluating the instantaneous satellite and GV rain rate statistics at spatio-temporal scales compatible with the satellite sensor resolution (Simpson et al. 1988, Thiele 1988). The GV Program has continued to evolve since the launch of the TRMM satellite on November 27, 1997. This presentation will discuss current GV methods of validating TRMM operational rain products in conjunction with ongoing research. The challenge facing TRMM GV has been how to best utilize rain information from the GV system to infer the random and systematic error characteristics of the satellite rain estimates. A fundamental problem of validating space-borne rain estimates is that the true mean areal rainfall is an ideal, scale-dependent parameter that cannot be directly measured. Empirical validation uses ground-based rain estimates to determine the error characteristics of the satellite-inferred rain estimates, but ground estimates also incur measurement errors and contribute to the error covariance. Furthermore, sampling errors, associated with the discrete, discontinuous temporal sampling by the rain sensors aboard the TRMM satellite, become statistically entangled in the monthly estimates. Sampling errors complicate the task of linking biases in the rain retrievals to the physics of the satellite algorithms. The TRMM Satellite Validation Office (TSVO) has made key progress towards effective satellite validation. For disentangling the sampling and retrieval errors, TSVO has developed and applied a methodology that statistically separates the two error sources. Using TRMM monthly estimates and high-resolution radar and gauge data, this method has been used to estimate sampling and retrieval error budgets over GV sites. More recently, a multi- year data set of instantaneous rain rates from the TRMM microwave imager (TMI), the precipitation radar (PR), and the combined algorithm was spatio-temporally matched and inter-compared to GV radar rain rates collected during satellite overpasses of select GV sites at the scale of the TMI footprint. The analysis provided a more direct probe of the satellite rain algorithms using ground data as an empirical reference. TSVO has also made significant advances in radar quality control through the development of the Relative Calibration Adjustment (RCA) technique. The RCA is currently being used to provide a long-term record of radar calibration for the radar at Kwajalein, a strategically important GV site in the tropical Pacific. The RCA technique has revealed previously undetected alterations in the radar sensitivity due to engineering changes (e.g., system modifications, antenna offsets, alterations of the receiver, or the data processor), making possible the correction of the radar rainfall measurements and ensuring the integrity of nearly a decade of TRMM GV observations and resources.

How regulation based on a common stomach leads to economic optimization of honeybee foraging.

PubMed

Schmickl, Thomas; Karsai, Istvan

2016-01-21

Simple regulatory mechanisms based on the idea of the saturable 'common stomach' can control the regulation of protein foraging and protein allocation in honeybee colonies and colony-level responses to environmental changes. To study the economic benefits of pollen and nectar foraging strategies of honeybees to both plants and honeybees under different environmental conditions, a model was developed and analyzed. Reallocation of the foraging workforce according to the quality and availability of resources (an 'adaptive' strategy used by honeybees) is not only a successful strategy for the bees but also for plants, because intensified pollen foraging after rain periods (when nectar quality is low) compensates a major fraction of the pollination flights lost during the rain. The 'adaptive' strategy performed better than the'fixed' (steady, minimalistic, and non-adaptive foraging without feedback) or the 'proactive' (stockpiling in anticipation of rain) strategies in brood survival and or in nectar/sugar economics. The time pattern of rain periods has profound effect on the supply-and-demand of proteins. A tropical rain pattern leads to a shortage of the influx of pollen and nectar, but it has a less profound impact on brood mortality than a typical continental rainfall pattern. Allocating more bees for pollen foraging has a detrimental effect on the nectar stores, therefore while saving larvae from starvation the 'proactive' strategy could fail to collect enough nectar for surviving winter. Copyright © 2015 Elsevier Ltd. All rights reserved.

Thunder and Lightning and Rain: a Latino/Hispanic diabetes media awareness campaign.

PubMed

Almendarez, Isabel S; Boysun, Michael; Clark, Kathleen

2004-01-01

The prevalence rates of diabetes in communities of color are higher than in Caucasian populations. Social marketing can be an effective approach to educating communities and encouraging visits to health care providers. This article describes Thunder and Lightning and Rain, a diabetes media awareness campaign implemented in a 5-county area in central Washington State with a large Latino/Hispanic population. The Washington State Department of Health's Diabetes Prevention and Control Program, along with national and community partners and focus groups, used a social marketing model to reach those with uncontrolled diabetes. A telephone survey-based evaluation, conducted in Spanish, provided data on demographics, media access, calls to a toll-free information line, provider visits, and recall of the campaign's central message: "Control your diabetes. For Life."

A simple model for the estimation of rain-induced attenuation along earth-space paths at millimeter wavelengths

NASA Technical Reports Server (NTRS)

Stutzman, W. L.; Dishman, W. K.

1982-01-01

A simple attenuation model (SAM) is presented for estimating rain-induced attenuation along an earth-space path. The rain model uses an effective spatial rain distribution which is uniform for low rain rates and which has an exponentially shaped horizontal rain profile for high rain rates. When compared to other models, the SAM performed well in the important region of low percentages of time, and had the lowest percent standard deviation of all percent time values tested.

KSC-02pd0995

NASA Image and Video Library

2002-06-18

KENNEDY SPACE CENTER, FLA. -- Black storm clouds hang over the Vehicle Assembly Building and Launch Control Center, bringing thunder and heavy rain to the area. This type of weather convinced flight control managers to wave off the two scheduled landing attempts at KSC for Endeavour, returning from mission STS-111

A Method to Retrieve Rainfall Rate over Land from TRMM Observations

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Iacovazzi, R., Jr.; Yoo, J.-M.

2002-01-01

Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) observations over mesoscale convective systems (MCSs) reveal that there are localized maxima in the rain rate with a scale of about 10 to 20 km that represent thunderstorms (Cbs). Some of these Cbs are developing or intense, while others are decaying or weak. These Cbs constitute only about 20 % of the rain area of a given MCS. Outside of Cbs, the average rain rate is much weaker than that within Cbs. From an analysis of the PR data, we find that the spatial distribution of rain and its character, convective or stratiform, is highly inhomogeneous. This complex nature of rain exists on a scale comparable to that of a Cb. The 85 GHz brightness temperature, T85, observations of the TRMM Microwave Imager (TMI) radiometer taken over an MCS reflect closely the PR rain rate pattern over land. Local maxima in rain rate shown by PR are observed as local minima in T85. Where there are no minima in T85, PR observations indicate there is light rain. However, the TMI brightness temperature measurements (Tbs) have poor ability to discriminate convective rain from stratiform rain. For this reason, a TMI rain retrieval procedure that depends primarily on the magnitude of Tbs performs poorly. In order to retrieve rain rate from TMI data on land one has to include the spatial distribution information deduced from the T85 data in the retrieval method. Then, quantitative estimation of rain rate can be accomplished. A TMI rain retrieval method developed along these lines can yield estimates of rain rate and its frequency distribution which agree closely with that given by PR. We find the current TRMM project TMI (Version 5) rain retrieval algorithm on land could be improved with the retrieval scheme developed here. To support the conceptual frame work of the rain retrieval method developed here, a theoretical analysis of the TMI brightness temperatures in convective and stratiform regions is presented.

Computer model of hydroponics nutrient solution pH control using ammonium.

PubMed

Pitts, M; Stutte, G

1999-01-01

A computer simulation of a hydroponics-based plant growth chamber using ammonium to control pH was constructed to determine the feasibility of such a system. In nitrate-based recirculating hydroponics systems, the pH will increase as plants release hydroxide ions into the nutrient solution to maintain plant charge balance. Ammonium is an attractive alternative to traditional pH controls in an ALSS, but requires careful monitoring and control to avoid overdosing the plants with ammonium. The primary advantage of using NH4+ for pH control is that it exploits the existing plant nutrient uptake charge balance mechanisms to maintain solution pH. The simulation models growth, nitrogen uptake, and pH of a l-m2 stand of wheat. Simulation results indicated that ammonium-based control of nutrient solution pH is feasible using a proportional integral controller. Use of a 1 mmol/L buffer (Ka = 1.6 x 10(-6)) in the nutrient solution is required.

Self-Consistency of Rain Event Definitions

NASA Astrophysics Data System (ADS)

Teves, J. B.; Larsen, M.

2014-12-01

A dense optical rain disdrometer array was constructed to study rain variability on spatial scales less than 100 meters with temporal resolution of 1 minute. Approximately two months of data were classified into rain events using methods common in the literature. These methods were unable to identify an array-wide consensus as to the total number of rain events; instruments as little as 2 meters apart with similar data records sometimes identified different rain event totals. Physical considerations suggest that these differing event totals are likely due to instrument sampling fluctuations that are typically not accounted for in rain event studies. Detection of varying numbers of rain events impact many commonly used storm statistics including storm duration distributions and mean rain rate. A summary of the results above and their implications are presented.

Observational and modeling studies of chemical species concentrations as a function of raindrop size

NASA Astrophysics Data System (ADS)

Wai, K. M.; Tam, C. W. F.; Tanner, P. A.

The Guttalgor method has been used to determine the chemical species concentrations in size-selected raindrops in nine rain events at Hong Kong from 1999 to 2001. The curve (concentration against raindrop radius) patterns for all the species are similar but depend on the starting time of sampling within a rain event. In these plots, the maximum concentration occurs at the same range of droplet radius, irrespective of the species, and this indicates the importance of coalescence and breakup processes. The maximum is located at a smaller droplet radius than was found in previous studies in Germany. All results show almost constant concentrations with size for large raindrops, and these indicate the in-cloud contributions. The pH of raindrops of similar size is linearly correlated with a function of the sulfate, nitrate, acetate, formate, calcium and ammonium ion species concentrations. Within a single raindrop, chloride depletion is not significant, and sulfate, ammonium and hydrogen ions are found in ratios compatible with the precursor solid-phase mixture of ammonium sulfate and ammonium bisulphate. When simulated by a below-cloud model, good agreement between the modeled and measured sodium and sulfate concentrations has been found. Below-cloud sulfur dioxide scavenging contributes at most 60% of the sulfate concentration in a single raindrop.

Health Hazards Associated with Consumption of Roof-Collected Rainwater in Urban Areas in Emergency Situations

PubMed Central

Stewart, Carol; Kim, Nick D.; Johnston, David M.; Nayyerloo, Mostafa

2016-01-01

The greater Wellington region, New Zealand, is highly vulnerable to large earthquakes because it is cut by active faults. Bulk water supply pipelines cross the Wellington Fault at several different locations, and there is considerable concern about severe disruption of the provision of reticulated water supplies to households and businesses in the aftermath of a large earthquake. A number of policy initiatives have been launched encouraging householders to install rainwater tanks to increase post-disaster resilience. However, little attention has been paid to potential health hazards associated with consumption of these supplies. To assess health hazards for householders in emergency situations, six 200-litre emergency water tanks were installed at properties across the Wellington region, with five tanks being allowed to fill with roof-collected rainwater and one tank being filled with municipal tapwater as a control. Such tanks are predominantly set aside for water storage and, once filled, feature limited drawdown and recharge. Sampling from these tanks was carried out fortnightly for one year, and samples were analysed for E. coli, pH, conductivity, a range of major and trace elements, and organic compounds, enabling an assessment of the evolution of water chemistry in water storage tanks over time. Key findings were that the overall rate of E. coli detections in the rain-fed tanks was 17.7%, which is low in relation to other studies. We propose that low incidences of may be due to biocidal effects of high zinc concentrations in tanks, originating from unpainted galvanised steel roof cladding. Lead concentrations were high compared to other studies, with 69% of rain-fed tank samples exceeding the World Health Organisation’s health-based guideline of 0.01 mg/L. Further work is required to determine risks of short-term consumption of this water in emergency situations. PMID:27754454

Changes in soil carbon and nutrients following 6 years of litter removal and addition in a tropical semi-evergreen rain forest

NASA Astrophysics Data System (ADS)

Tanner, Edmund Vincent John; Sheldrake, Merlin W. A.; Turner, Benjamin L.

2016-11-01

Increasing atmospheric CO2 and temperature may increase forest productivity, including litterfall, but the consequences for soil organic matter remain poorly understood. To address this, we measured soil carbon and nutrient concentrations at nine depths to 2 m after 6 years of continuous litter removal and litter addition in a semi-evergreen rain forest in Panama. Soils in litter addition plots, compared to litter removal plots, had higher pH and contained greater concentrations of KCl-extractable nitrate (both to 30 cm); Mehlich-III extractable phosphorus and total carbon (both to 20 cm); total nitrogen (to 15 cm); Mehlich-III calcium (to 10 cm); and Mehlich-III magnesium and lower bulk density (both to 5 cm). In contrast, litter manipulation did not affect ammonium, manganese, potassium or zinc, and soils deeper than 30 cm did not differ for any nutrient. Comparison with previous analyses in the experiment indicates that the effect of litter manipulation on nutrient concentrations and the depth to which the effects are significant are increasing with time. To allow for changes in bulk density in calculation of changes in carbon stocks, we standardized total carbon and nitrogen on the basis of a constant mineral mass. For 200 kg m-2 of mineral soil (approximately the upper 20 cm of the profile) about 0.5 kg C m-2 was "missing" from the litter removal plots, with a similar amount accumulated in the litter addition plots. There was an additional 0.4 kg C m-2 extra in the litter standing crop of the litter addition plots compared to the control. This increase in carbon in surface soil and the litter standing crop can be interpreted as a potential partial mitigation of the effects of increasing CO2 concentrations in the atmosphere.

Superficial alteration mineralogy in active volcanic systems: An example of Poás volcano, Costa Rica

NASA Astrophysics Data System (ADS)

Rodríguez, Alejandro; van Bergen, Manfred J.

2017-10-01

The alteration mineralogy in the crater area of Poás volcano (Costa Rica) has been studied to constrain acid fluid-rock interaction processes and conditions relevant for the formation of sulphate-bearing mineral assemblages found on the surface of Mars. Individual sub-environments, which include the hyperacid lake (Laguna Caliente), ephemeral hot springs, fumarole vents and areas affected by acid rain and/or spray from the lake, are marked by distinct secondary mineral associations, with sulphates commonly as prevailing component. The sulphates occur in a wide mineralogical diversity comprising gypsum/anhydrite, various polyhydrated Al-sulphates, alunite-jarosite group minerals, halotrichite-, voltaite- and copiapite-group minerals, epsomite and römerite. Depending on the sub-environment, they are variably associated with clay minerals (kaolinite-group and smectite-group), zeolites, SiO2-polymorphs, Fe-(hydro)oxides, Ti-oxides, native sulphur, sulphides, chlorides, fluorides, phosphates and carbonates. Geochemical modelling was performed to identify mechanisms responsible for the formation of the secondary minerals found in the field, and to predict their possible stability under conditions not seen at the surface. The results indicate that the appearance of amorphous silica, hematite, anhydrite/gypsum, pyrite, anatase and kaolinite is relatively insensitive to the degree of acidity of the local aqueous system. On the other hand, alunite-jarosite group minerals, elemental sulphur and Al(OH)SO4 only form under acidic conditions (pH < 4). The presence of polyhydrated Mg- and Fe2 +-sulphates is restricted to olivine-bearing rocks exposed to acid rain or brine spray. Modelling suggests that their formation required a repetitive sequence of olivine dissolution and evaporation in an open system involving limited amounts of fluid. The mineral variety in the crater of Poás is remarkably similar to sulphate-bearing assemblages considered to be the product of acid-sulphate alteration on Mars. The analogy suggests that comparable fluid-rock interaction controls operated in Martian volcanic environments.

A meteorological potential forecast model for acid rain in Fujian Province, China.

PubMed

Cai, Yi Yong; Lin, Chang Cheng; Liu, Jing Xiong; Wu, De Hui; Lian, Dong Ying; Chen, Bin Bin

2010-05-01

Based on the acid rain and concurrent meteorological observational data during the past 10 years in Fujian Province, China, the dependence of distribution characteristics of acid rain on season, rain rate, weather pattern and dominant airflow in four regions of Fujian Province is analyzed. On the annual average, the acid rain frequency is the highest (above 40%) in the southern and mid-eastern regions, and the lowest (16.2%) in the western region. The acid rain occurs most frequently in spring and winter, and least frequent in summer. The acid rain frequency in general increases with the increase of precipitation. It also depend on the direction of dominant airflows at 850 hPa. In the mid-eastern region, more than 40% acid rains appear when the dominant wind directions are NW, W, SW, S and SE. In the southern region, high acid rain occurrence happens when the dominant wind directions are NW, W, SW and S. In the northern region, 41.8% acid rains occur when the southwesterly is pronounced. In the western region, the southwesterly is associated with a 17% acid rain rate. The examination of meteorological sounding conditions over Fuzhou, Xiamen and Shaowu cities shows that the acid rain frequency increases with increased inversion thickness. Based on the results above, a meteorological potential forecast model for acid rain is established and tested in 2007. The result is encouraging. The model provides an objective basis for the development of acid rain forecasting operation in the province.

On the nature of rainfall in dry climate: Space-time patterns of convective rain cells over the Dead Sea region and their relations with synoptic state and flash flood generation

NASA Astrophysics Data System (ADS)

Belachsen, Idit; Marra, Francesco; Peleg, Nadav; Morin, Efrat

2017-04-01

Space-time patterns of rainfall are important climatic characteristics that influence runoff generation and flash flood magnitude. Their derivation requires high-resolution measurements to adequately represent the rainfall distribution, and is best provided by remote sensing tools. This need is further emphasized in dry climate regions, where rainfall is scarce and, often, local and highly variable. Our research is focused on understanding the nature of rainfall events in the dry Dead Sea region (Eastern Mediterranean) by identifying and characterizing the spatial structure and the dynamics of convective storm cores (known as rain cells). To do so, we take advantage of 25 years of corrected and gauge-adjusted weather radar data. A statistical analysis of convective rain-cells spatial and temporal characteristics was performed with respect to synoptic pattern, geographical location, and flash flood generation. Rain cells were extracted from radar data using a cell segmentation method and a tracking algorithm and were divided into rain events. A total of 10,500 rain cells, 2650 cell tracks and 424 rain events were elicited. Rain cell properties, such as mean areal and maximal rain intensity, area, life span, direction and speed, were derived. Rain events were clustered, according to several ERA-Interim atmospheric parameters, and associated with three main synoptic patterns: Cyprus Low, Low to the East of the study region and Active Red Sea Trough. The first two originate from the Mediterranean Sea, while the third is an extension of the African monsoon. On average, the convective rain cells in the region are 90 km2 in size, moving from West to East in 13 ms-1 and living 18 minutes. Several significant differences between rain cells of the various synoptic types were observed. In particular, Active Red Sea Trough rain cells are characterized by higher rain intensities and lower speeds, suggesting a higher flooding potential for small catchments. The north-south negative gradient of mean annual rainfall in the study region was found to be negatively correlated with rain cells intensity and positively correlated with rain cells area. Additional analysis was done for convective rain cells over two nearby catchments located in the central part of the study region, by ascribing some of the rain events to observed flash-flood events. It was found that rain events associated with flash-floods have higher maximal rain cell intensity and lower minimal cell speed than rain events that did not lead to a flash-flood in the watersheds. This information contributes to our understanding of rain patterns over the dry area of the Dead Sea and their connection to flash-floods. The statistical distributions of rain cells properties can be used for high space-time resolution stochastic simulations of rain storms that can serve as an input to hydrological models.

Flux frequency analysis of seasonally dry ecosystem fluxes in two unique biomes of Sonora Mexico

NASA Astrophysics Data System (ADS)

Verduzco, V. S.; Yepez, E. A.; Robles-Morua, A.; Garatuza, J.; Rodriguez, J. C.; Watts, C.

2013-05-01

Complex dynamics from the interactions of ecosystems processes makes difficult to model the behavior of ecosystems fluxes of carbon and water in response to the variation of environmental and biological drivers. Although process oriented ecosystem models are critical tools for studying land-atmosphere fluxes, its validity depends on the appropriate parameterization of equations describing temporal and spatial changes of model state variables and their interactions. This constraint often leads to discrepancies between model simulations and observed data that reduce models reliability especially in arid and semiarid ecosystems. In the semiarid north western Mexico, ecosystem processes are fundamentally controlled by the seasonality of water and the intermittence of rain pulses which are conditions that require calibration of specific fitting functions to describe the response of ecosystem variables (i.e. NEE, GPP, ET, respiration) to these wetting and drying periods. The goal is to find functions that describe the magnitude of ecosystem fluxes during individual rain pulses and the seasonality of the ecosystem. Relaying on five years of eddy covariance flux data of a tropical dry forest and a subtropical shrubland we present a flux frequency analysis that describe the variation of net ecosystem exchange (NEE) of CO2 to highlight the relevance of pulse driven dynamics controlling this flux. Preliminary results of flux frequency analysis of NEE indicate that these ecosystems are strongly controlled by the frequency distribution of rain. Also, the output of fitting functions for NEE, GPP, ET and respiration using semi-empirical functions applied at specific rain pulses compared with season-long statistically generated simulations do not agree. Seasonality and the intrinsic nature of individual pulses have different effects on ecosystem flux responses. This suggests that relationships between the nature of seasonality and individual pulses can help improve the parameterization of process oriented ecosystem models.

Survival of the biological control agent Candida sake CPA-1 on grapes under the influence of abiotic factors.

PubMed

Calvo-Garrido, C; Viñas, I; Usall, J; Rodríguez-Romera, M; Ramos, M C; Teixidó, N

2014-09-01

As reliability of preharvest applications of biological control agents (BCAs) to control fruit pathogens is highly dependent on the survival of the selected organism, this study aimed to describe the population dynamics of the yeast-BCA Candida sake (Saito & Ota) CPA-1 on grape berries under the effect of abiotic factors such as temperature, relative humidity, sunlight and rainfall. Candida sake (5 × 10(7) CFU ml(-1)), combined with different concentrations of the food additive Fungicover(®), was applied on grape berry clusters. Treated clusters were then exposed to abiotic factors in field or laboratory conditions, recovering populations to describe C. sake population dynamics. The addition of Fungicover significantly increased C. sake multiplication under optimal growth conditions and improved survival under fluctuating abiotic factors. After field applications, significant differences in populations on grape bunches exposed or covered by fine foliage were detected. Simulated rainfall washed off C. sake populations by 0·6-0·9 log units after 20 mm of rain volume. Allowing populations to establish for 24 h or more, prior to a rain event, persistence on grape berries significantly increased and the effect of rain intensity was not observable. Candida sake demonstrated high survival ability under unfavourable environmental conditions and persistence under intense rain. The study evidenced the importance of the first period just after application for C. sake survival on grape tissues and also the protective effect of the additive Fungicover. This research provides new information on the survival of C. sake under field conditions and its practical implications for recommending timing of spray with this antagonist. Our results could be useful for other yeast antagonists applied before harvest. This work, for the first time, defines population dynamics of a yeast BCA using simulated rainfall. © 2014 The Society for Applied Microbiology.

Response of transpiration to rain pulses for two tree species in a semiarid plantation

NASA Astrophysics Data System (ADS)

Chen, Lixin; Zhang, Zhiqiang; Zeppel, Melanie; Liu, Caifeng; Guo, Junting; Zhu, Jinzhao; Zhang, Xuepei; Zhang, Jianjun; Zha, Tonggang

2014-09-01

Responses of transpiration ( E c) to rain pulses are presented for two semiarid tree species in a stand of Pinus tabulaeformis and Robinia pseudoacacia. Our objectives are to investigate (1) the environmental control over the stand transpiration after rainfall by analyzing the effect of vapor pressure deficit (VPD), soil water condition, and rainfall on the post-rainfall E c development and recovery rate, and (2) the species responses to rain pulses and implications on vegetation coverage under a changing rainfall regime. Results showed that the sensitivity of canopy conductance ( G c) to VPD varied under different incident radiation and soil water conditions, and the two species exhibited the same hydraulic control (-d G c/dlnVPD to G cref ratio) over transpiration. Strengthened physiological control and low sapwood area of the stand contributed to low E c. VPD after rainfall significantly influenced the magnitude and time series of post-rainfall stand E c. The fluctuation of post-rainfall VPD in comparison with the pre-rainfall influenced the E c recovery. Further, the stand E c was significantly related to monthly rainfall, but the recovery was independent of the rainfall event size. E c enhanced with cumulative soil moisture change (ΔVWC) within each dry-wet cycle, yet still was limited in large rainfall months. The two species had different response patterns of post-rainfall E c recovery. E c recovery of P. tabulaeformis was influenced by the pre- and post-rainfall VPD differences and the duration of rainless interval. R. pseudoacacia showed a larger immediate post-rainfall E c increase than P. tabulaeformis did. We, therefore, concluded that concentrated rainfall events do not trigger significant increase of transpiration unless large events penetrate the deep soil and the species differences of E c in response to pulses of rain may shape the composition of semiarid woodlands under future rainfall regimes.

Acidification and Acid Rain

NASA Astrophysics Data System (ADS)

Norton, S. A.; Veselã½, J.

2003-12-01

Air pollution by acids has been known as a problem for centuries (Ducros, 1845; Smith, 1872; Camuffo, 1992; Brimblecombe, 1992). Only in the mid-1900s did it become clear that it was a problem for more than just industrially developed areas, and that precipitation quality can affect aquatic resources ( Gorham, 1955). The last three decades of the twentieth century saw tremendous progress in the documentation of the chemistry of the atmosphere, precipitation, and the systems impacted by acid atmospheric deposition. Chronic acidification of ecosystems results in chemical changes to soil and to surface waters and groundwater as a result of reduction of base cation supply or an increase in acid (H+) supply, or both. The most fundamental changes during chronic acidification are an increase in exchangeable H+ or Al3+ (aluminum) in soils, an increase in H+ activity (˜concentration) in water in contact with soil, and a decrease in alkalinity in waters draining watersheds. Water draining from the soil is acidified and has a lower pH (=-log [H+]). As systems acidify, their biotic community changes.Acidic surface waters occur in many parts of the world as a consequence of natural processes and also due to atmospheric deposition of strong acid (e.g., Canada, Jeffries et al. (1986); the United Kingdom, Evans and Monteith (2001); Sweden, Swedish Environmental Protection Board (1986); Finland, Forsius et al. (1990); Norway, Henriksen et al. (1988a); and the United States (USA), Brakke et al. (1988)). Concern over acidification in the temperate regions of the northern hemisphere has been driven by the potential for accelerating natural acidification by pollution of the atmosphere with acidic or acidifying compounds. Atmospheric pollution ( Figure 1) has resulted in an increased flux of acid to and through ecosystems. Depending on the ability of an ecosystem to neutralize the increased flux of acidity, acidification may increase only imperceptibly or be accelerated at a rate that endangers the existing biota. Concerns about acid (or acidic) rain in its modern sense were publicized by the Swedish soil scientist Svante Odén (1968). He argued, initially in the Swedish press, that long-term increases in the atmospheric deposition of acid could lower the pH of surface waters, cause a decline in fish stocks, deplete soils of nutrients, and accelerate damage to materials. By the 1970s, acidification of surface waters was reported in many countries in Europe as well as in North America. The late twentieth-century rush to understand the impact of acid rain was driven by: (i) reports of damaged or threatened freshwater fisheries and (ii) damaged forests. Perhaps the earliest linkage between acidic surface water and damage to fish was made by Dahl (1921) in southern Norway. There, spring runoff was sufficiently acidic to kill trout. It was not until the 1970s that a strong link was established between depressed pH, mobilization of aluminum from soil, and fish status ( Schofield and Trojnar,1980). The relationship between acidification of soils and forest health started with hypotheses in the 1960s and has slowly developed. Acid rain enhances the availability of some nutrients (e.g., nitrogen), and may either enhance or diminish the availability of others (e.g., calcium, magnesium, potassium, and phosphorus). Damage to anthropogenic structures, human health, and visibility have also raised concerns. The history of these early developments was summarized by Cowling (1982). Since the 1970s, sulfur and nitrogen emissions to the atmosphere have been reduced by 50-85% and 0-30%, respectively, both in North America and Europe. The emission reductions have occurred as a consequence of knowledge gained and economic factors. While recovery of water quality is underway in some areas, problems of acidification persist, and are now complicated by the effects of climate change ( Schindler, 1997).

Markets for Clean Air

NASA Astrophysics Data System (ADS)

Ellerman, A. Denny; Joskow, Paul L.; Schmalensee, Richard; Montero, Juan-Pablo; Bailey, Elizabeth M.

2000-06-01

Markets for Clean Air provides a comprehensive, in-depth description and evaluation of the first three years' experience with the U.S. Acid Rain Program. This environmental control program is the world's first large-scale use of a tradable emission permit system for achieving environmental goals. The book analyzes the behavior and performance of the market for emissions permits, called allowances in the Acid Rain Program, and quantifies emission reductions, compliance costs, and cost savings associated with the trading program. The book also includes chapters on the historical context in which this pioneering program developed and the political economy of allowance allocations.

Rain Impact Model Assessment of Near-Surface Salinity Stratification Following Rainfall

NASA Astrophysics Data System (ADS)

Drushka, K.; Jones, L.; Jacob, M. M.; Asher, W.; Santos-Garcia, A.

2016-12-01

Rainfall over oceans produces a layer of fresher surface water, which can have a significant effect on the exchanges between the surface and the bulk mixed layer and also on satellite/in-situ comparisons. For satellite sea surface salinity (SSS) measurements, the standard is the Hybrid Coordinate Ocean Model (HYCOM), but there is a significant difference between the remote sensing sampling depth of 0.01 m and the typical range of 5-10 m of in-situ instruments. Under normal conditions the upper layer of the ocean is well mixed and there is uniform salinity; however, under rainy conditions, there is a dilution of the near-surface salinity that mixes downward by diffusion and by mechanical mixing (gravity waves/wind speed). This significantly modifies the salinity gradient in the upper 1-2 m of the ocean, but these transient salinity stratifications dissipate in a few hours, and the upper layer becomes well mixed at a slightly fresher salinity. Based upon research conducted within the NASA/CONAE Aquarius/SAC-D mission, a rain impact model (RIM) was developed to estimate the change in SSS due to rainfall near the time of the satellite observation, with the objective to identify the probability of salinity stratification. RIM uses HYCOM (which does not include the short-term rain effects) and a NOAA global rainfall product CMORPH to model changes in the near-surface salinity profile in 0.5 h increments. Based upon SPURS-2 experimental near-surface salinity measurements with rain, this paper introduces a term in the RIM model that accounts for the effect of wind speed in the mechanical mixing, which translates into a dynamic vertical diffusivity; whereby a Generalized Ocean Turbulence Model (GOTM) is used to investigate the response to rain events of the upper few meters of the ocean. The objective is to determine how rain and wind forcing control the thickness, stratification strength, and lifetime of fresh lenses and to quantify the impacts of rain-formed fresh lenses on the fresh bias in satellite retrievals of salinity. Results will be presented of comparisons of RIM measurements at depth of a few meters with measurements from in-situ salinity instruments. Also, analytical results will be shown, which assess the accuracy of RIM salinity profiles under a variety of rain rate, wind/wave conditions.

Rainwater as a chemical agent of geologic processes; a review

USGS Publications Warehouse

Carroll, Dorothy

1962-01-01

Chemical analyses of the rainwater collected at several localities are given to show the variations of the principal constitutents. In rock weathering and soil-forming processes, the chemical composition of rainwater has an important effect which has been evaluated for only a few arid areas. In humid regions the important amounts of calcium, magnesium, sodium, and potassium added yearly by rain may be expected to influence the composition of the soil water and thereby the cations in the exchange positions of soil clay minerals. The acquisition of cations by clay minerals may slow down chemical weathering. The stability of soil clay minerals is influenced by the constant accession of cations from rainwater. Conversely, the clay minerals modify the amounts and kinds of cations that are leached out by drainage waters. The stability of micaceous minerals in soils may be partly due to accessions of K +1 ions from rainwater. The pH of rainwater in any area varies considerably and seems to form a seasonal and regional pattern. The recorded pH values range from 3.0 to 9.8.

Late Pleistocene and Holocene paleolimnology of two mountain lakes in western Tasmania.

USGS Publications Warehouse

Platt, Bradbury J.

1986-01-01

The analysis of diatoms from two lake-sediment cores from southwestern Tasmania that span the Pleistocene-Holocene boundary provides insight about paleolimnological and paleoclimatic change in this region. Both Lake Vera and Eagle Tarn have lacustrine records that begin about 12 000 yr ago. Both lakes have had similar limnological histories. Each appears to have been larger and more alkaline 12 000 yr ago and both became shallower through time. Fossil diatom assemblages about 11 000 yr old indicate shallow- water environments that fluctuated in pH, and between dilute and possibly slightly saline hydrochemical conditions. Beginning 11 500 yr ago, limnological conditions of shallow, dilute water of neutral pH prevailed, indicating reduction of moisture stress. A subsequent transition to diatom assemblages indicative of acidic conditions about 10 000 yr ago parallels the establishment of rain-forest vegetation and essentially modern climatic conditions with excess precipitation over evaporation. Changes at these separate and distinctive sites suggests a regional paleoclimatic cause rather than local environmental effects. Latest Pleistocene climates were apparently more continental and drier than Holocene climates in southwestern Tasmania.-from Author

Rainfall and runoff quantity and quality data collected at four urban land-use catchments in Fresno, California, October 1981-April 1983

USGS Publications Warehouse

Oltmann, R.N.; Guay, J.R.; Shay, J.M.

1987-01-01

Data were collected as part of the National Urban Runoff Program to characterize urban runoff in Fresno, California. Rainfall-runoff quantity and quality data are included along with atmospheric dry-deposition and street-surface particulate quality data. The data are presented in figures and tables that reflect four land uses: industrial, single-dwelling residential, multiple-dwelling residential, and commercial. A total of 255 storms were monitored for rainfall and runoff quantity. Runoff samples from 112 of these storms were analyzed for physical, organic, inorganic, and biological constituents. The majority of the remaining storms have pH and specific conductance data only. Ninety-two composite rain samples were collected. Of these, 63 were analyzed for physical, inorganic, and (or) organic constituents. The remaining rainfall samples have pH and specific conductance data only. Nineteen atmospheric deposition and 21 street-particulate samples were collected and analyzed for inorganic and organic constituents. The report also details equipment utilization and operation, and discusses data collection methods. (USGS)

Characterization and evaluation of acid rain in East Central Florida from 1978 to 1987: Ten year summary report

NASA Technical Reports Server (NTRS)

Madsen, Brooks C.; Dreschel, Thomas W.; Hinkle, C. Ross

1989-01-01

Rainfall was collected on the University of Central Florida (UCF) campus near Orlando since July 1977 and at the Kennedy Space Center (KSC), Florida since August 1977. Since November 1983, the KSC site has been affiliated with the National Atmospheric Deposition Network. Annual volume weighted pH was slightly above the 10 year mean of 4.58 during four of the past five years. Nitrate concentrations have risen somewhat during recent years while excess sulfate concentrations have remained below the 10 year mean during four of the past years. These observations hold for both the UCF and KSC data. The distribution of individual sample pH was nearly identical at UCF and KSC. Stepwise regression suggests that sulfate, nitrate, ammonium ion, and calcium play major roles in the description of rainwater acidity. Annual acid deposition and annual rainfall have varied from 30 to 50 meq/m2-yr and 100 to 180 cm/yr, respectively. Sea salt comprises about 25 percent (UCF) and greater than 50 percent (KSC) of total ionic composition.

Random Forest Application for NEXRAD Radar Data Quality Control

NASA Astrophysics Data System (ADS)

Keem, M.; Seo, B. C.; Krajewski, W. F.

2017-12-01

Identification and elimination of non-meteorological radar echoes (e.g., returns from ground, wind turbines, and biological targets) are the basic data quality control steps before radar data use in quantitative applications (e.g., precipitation estimation). Although WSR-88Ds' recent upgrade to dual-polarization has enhanced this quality control and echo classification, there are still challenges to detect some non-meteorological echoes that show precipitation-like characteristics (e.g., wind turbine or anomalous propagation clutter embedded in rain). With this in mind, a new quality control method using Random Forest is proposed in this study. This classification algorithm is known to produce reliable results with less uncertainty. The method introduces randomness into sampling and feature selections and integrates consequent multiple decision trees. The multidimensional structure of the trees can characterize the statistical interactions of involved multiple features in complex situations. The authors explore the performance of Random Forest method for NEXRAD radar data quality control. Training datasets are selected using several clear cases of precipitation and non-precipitation (but with some non-meteorological echoes). The model is structured using available candidate features (from the NEXRAD data) such as horizontal reflectivity, differential reflectivity, differential phase shift, copolar correlation coefficient, and their horizontal textures (e.g., local standard deviation). The influence of each feature on classification results are quantified by variable importance measures that are automatically estimated by the Random Forest algorithm. Therefore, the number and types of features in the final forest can be examined based on the classification accuracy. The authors demonstrate the capability of the proposed approach using several cases ranging from distinct to complex rain/no-rain events and compare the performance with the existing algorithms (e.g., MRMS). They also discuss operational feasibility based on the observed strength and weakness of the method.

Numerical modeling of benthic processes in the deep Arabian Sea

NASA Astrophysics Data System (ADS)

Luff, Roger; Wallmann, Klaus; Grandel, Sibylle; Schlüter, Michael

Aerobic and anaerobic degradation of particulate organic carbon (POC) and carbonate equilibria in deep-sea surface sediments were studied at five stations located in the western (WAST), northern (NAST), eastern (EAST), central (CAST), and southern (SAST) Arabian Sea. In situ oxygen fluxes, porewater profiles of dissolved oxygen, nitrate, and Mn, pH profiles and solid-phase profiles of particulate organic carbon, Mn, and Fe were measured at each station. An early diagenesis model was applied to simulate the degradation and dissolution processes and to determine the benthic fluxes of POC, oxygen, nitrate, phosphate, CO 2, HCO 3-, and CO 32-. The benthic data sets were evaluated to constrain the POC input and the kinetics of organic matter degradation used in the model. The modeling showed that the POC rain rate to the seafloor is high at the western and northern stations, and decreases towards the southeast. At stations located in the vicinity of continental margins (WAST, NAST, EAST), 5-7% of the primary production sinks to the deep-sea floor. This unusually high POC rain is either caused by dust particles that accelerate and amplify the particle export from the euphotic zone or by rapid lateral transport processes. At the more remote stations (CAST, SAST) that receive lower dust inputs, the rain efficiency decreases to 1-4%. In the model, organic matter was separated into three fractions (3-G-model) that differ considerably in reactivity. At stations WAST, NAST, EAST, and CAST the bulk of organic matter is composed of extremely labile organic matter with a first order degradation constant ( k) of 15-30 yr -1. The moderately labile fraction with a kinetic constant of 0.2-0.6 yr -1 dominates the POC input at the oligotrophic station in the southern Arabian Sea (SAST). The third fraction that has a very low reactivity ( k=2-5×10 -4 yr -1) is only a minor component of the POC rain at all investigated stations. More than 95% of the organic matter is consumed in aerobic degradation processes. Denitrification and metal oxide reduction only contribute 1-2% to the total POC degradation. At the western station (WAST) a non-negligible portion (2%) of organic matter is consumed via sulfate reduction. The modeling demonstrates that carbonate dissolution is a major process in the deep Arabian Sea; 52-83% of the carbonate rain to the seafloor is dissolved within the surface sediments. In the western Arabian Sea, the monsoon systems produce a strong seasonality in the primary production. Non-steady-state modeling indicates that the benthic oxygen, nutrient, and inorganic carbon fluxes closely follow the seasonal dynamics in primary and export production. This very close benthic-pelagic coupling is established by the extremely labile organic matter fraction that dominates the POC rain to the seafloor. The metabolically released CO 2 induces a seasonal change in carbonate dissolution and carbonate alkalinity fluxes.

Acid Rain and Mercury Control Act

THOMAS, 111th Congress

Rep. McHugh, John M. [R-NY-23

2009-04-01

House - 04/28/2009 Referred to the Subcommittee on Department Operations, Oversight, Nutrition and Forestry. (All Actions) Tracker: This bill has the status IntroducedHere are the steps for Status of Legislation:

Effects of rainfall exclusion on leaf gas exchange traits and osmotic adjustment in mature canopy trees of Dryobalanops aromatica (Dipterocarpaceae) in a Malaysian tropical rain forest.

PubMed

Inoue, Yuta; Ichie, Tomoaki; Kenzo, Tanaka; Yoneyama, Aogu; Kumagai, Tomo'omi; Nakashizuka, Tohru

2017-10-01

Climate change exposes vegetation to unusual levels of drought, risking a decline in productivity and an increase in mortality. It still remains unclear how trees and forests respond to such unusual drought, particularly Southeast Asian tropical rain forests. To understand leaf ecophysiological responses of tropical rain forest trees to soil drying, a rainfall exclusion experiment was conducted on mature canopy trees of Dryobalanops aromatica Gaertn.f. (Dipterocarpaceae) for 4 months in an aseasonal tropical rain forest in Sarawak, Malaysia. The rainfall was intercepted by using a soft vinyl chloride sheet. We compared the three control and three treatment trees with respect to leaf water use at the top of the crown, including stomatal conductance (gsmax), photosynthesis (Amax), leaf water potential (predawn: Ψpre; midday: Ψmid), leaf water potential at turgor loss point (πtlp), osmotic potential at full turgor (π100) and a bulk modulus of elasticity (ε). Measurements were taken using tree-tower and canopy-crane systems. During the experiment, the treatment trees suffered drought stress without evidence of canopy dieback in comparison with the control trees; e.g., Ψpre and Ψmid decreased with soil drying. Minimum values of Ψmid in the treatment trees decreased during the experiment, and were lower than πtlp in the control trees. However, the treatment trees also decreased their πtlp by osmotic adjustment, and the values were lower than the minimum values of their Ψmid. In addition, the treatment trees maintained gs and Amax especially in the morning, though at midday, values decreased to half those of the control trees. Decreasing leaf water potential by osmotic adjustment to maintain gs and Amax under soil drying in treatment trees was considered to represent anisohydric behavior. These results suggest that D. aromatica may have high leaf adaptability to drought by regulating leaf water consumption and maintaining turgor pressure to improve its leaf water relations. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Chemical Speciation of Water Soluble Ions and Metals of Cloud and Rain Water During the Puerto Rico African Dust and Clouds Study (PRADACS) Campaigns

NASA Astrophysics Data System (ADS)

Torres, E.; Valle Diaz, C. J.; Lee, T.; Collett, J. L.; Fitzgerald, E.; Cuadra-Rodriguez, L. A.; Prather, K. A.; Sánchez, M.; McDowell, W. H.; Mayol-Bracero, O. L.

2013-05-01

The underlying physico-chemical processes of dust particles interactions are poorly understood; even less understood is how aging impacts cloud properties and climate as the particles travel from Africa to the Caribbean region. Caribbean landmasses have tropical montane cloud forests (TMCFs) that are tightly coupled to the atmospheric hydrologic cycle. TMCFs are ecosystems to study the effects African Dust (AD) on cloud formation and precipitation as these are very sensitive ecosystems that respond to small changes in climate. As part of the Puerto Rico African Dust and Clouds Study (PRADACS), chemical analyses were performed on cloud and rain water samples collected at Pico del Este (PE) station in Luquillo, PR (1051 masl) during campaigns held from 2010 to 2012. At PE, two cloud collectors (i.e., single stage (Aluminum version), a 2-stage (Teflon version) Caltech Active Strand Cloudwater Collector (CASCC)), a rainwater collector, and anAerosol Time-Of-Flight Mass Spectrometer (ATOFMS) were operated. Chemical analyses performed on collected samples include pH, conductivity, ion chromatography (IC), and inductive coupled plasma (ICP). Results from these campaigns showed that on days that had air masses with the influence of AD, cloud water samples had higher conductivity and pH values on average (up to 5.7 and 180μS/cm, respectively) than those with air masses without AD influence. An increase in the concentrations of water-soluble ions like non-sea salt calcium and magnesium, and metals like magnesium, calcium and aluminum was observed and the appearance of iron was seen on ICP analyses. The ATOFMS, showed an increase on the amount of particles during AD influence with composition of aluminum, silicates, potassium, iron and titanium aerosols. The increase on the aforementioned species was constant in the three years of sampling, which give us confidence in the identification of the chemical species that are present during the influence of AD.

Chemical composition of aerosol, sea fog, and rainwater in the marine boundary layer of the northwestern North Pacific and its marginal seas

NASA Astrophysics Data System (ADS)

Sasakawa, Motoki; Uematsu, Mitsuo

2002-12-01

Samples of aerosol, sea fog, and rainwater were collected during a research cruise in the northwestern North Pacific, the Sea of Okhotsk, and the Sea of Japan in the summer of 1998. High concentrations of NO3-, nss-SO42- and NH4+ in aerosol over the Sea of Japan suggest that anthropogenic substances were transported to this region. Although the Sea of Okhotsk was covered with a clean marine air mass, the concentration of nss-SO42- was comparatively high in the aerosol samples. This nss-SO42- is probably of marine biogenic origin. The pH values of fogwater samples were measured to be <3.0 over the Sea of Okhotsk and the Sea of Japan. The concentrations of NO3- and NH4+ in the fogwater collected over the Sea of Japan were higher than those in the other regions, suggesting that the sea fog scavenged anthropogenic substances. The concentration of nss-SO42- in fogwater over the Sea of Okhotsk was equivalent to that over the Sea of Japan, probably because nss-SO42- and SO2 of marine biogenic origin were scavenged by the sea fog over the Sea of Okhotsk. The pH values of rainwater samples ranged from 6.1 to 7.2 during the cruise, and acidification of the rain was not significant. The concentrations of nss-Ca2+ in the rainwater were higher than those of the fogwater. This suggests that the rain-scavenged continental CaCO3 may have existed above the lower marine boundary layer, where sea fog appeared. Comparisons of the composition of aerosol and fogwater indicated that coarse particles, such as sea salts predominantly act as condensation nuclei of sea fog droplets rather than fine particles such as (NH4)2SO4.

Acid rain recovery may help to mitigate the impacts of climate change on thermally sensitive fish in lakes across eastern North America.

PubMed

Warren, Dana R; Kraft, Clifford E; Josephson, Daniel C; Driscoll, Charles T

2017-06-01

From the 1970s to 1990s, more stringent air quality regulations were implemented across North America and Europe to reduce chemical emissions that contribute to acid rain. Surface water pH slowly increased during the following decades, but biological recovery lagged behind chemical recovery. Fortunately, this situation is changing. In the past few years, northeastern US fish populations have begun to recover in lakes that were historically incapable of sustaining wild fish due to acidic conditions. As lake ecosystems across the eastern United States recover from acid deposition, the stress to the most susceptible populations of native coldwater fish appears to be shifting from acidification effects to thermal impacts associated with changing climate. Extreme summer temperature events - which are expected to occur with increasing frequency in the coming century - can stress and ultimately kill native coldwater fish in lakes where thermal stratification is absent or highly limited. Based on data from northeastern North America, we argue that recovery from acid deposition has the potential to improve the resilience of coldwater fish populations in some lakes to impacts of climate change. This will occur as the amount of dissolved organic carbon (DOC) in the water increases with increasing lake pH. Increased DOC will reduce water clarity and lead to shallower and more persistent lake thermoclines that can provide larger areas of coldwater thermal refuge habitat. Recovery from acidification will not eliminate the threat of climate change to coldwater fish, but secondary effects of acid recovery may improve the resistance of coldwater fish populations in lakes to the effects of elevated summer temperatures in historically acidified ecosystems. This analysis highlights the importance of considering the legacy of past ecosystem impacts and how recovery or persistence of those effects may interact with climate change impacts on biota in the coming decades. © 2016 John Wiley & Sons Ltd.

Leaching of cadmium, chromium, copper, lead, and zinc from two slag dumps with different environmental exposure periods under dynamic acidic condition.

PubMed

Jin, Zhisheng; Liu, Taoze; Yang, Yuangen; Jackson, Daniel

2014-06-01

Over the past few decades, zinc smelting activities in Guizhou, China have produced numerous slag dumps, which are often dispersed on roadsides and hill slopes throughout the region. During periods of acid rain, these exposed slags release heavy metals into surface water bodies. A column leaching study was designed to test the potential release of the heavy metals cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) under simulated acid rain events. Two slags with varying environmental exposure periods were packed in columns and subjected to leaching solutions of pH 3.5, 5.5, or DI H2O at intervals of 1, 7, 14, 28, 56d. Pulse concentrations of Cd in leachate were found above 5μg/L, Cr, Pb, and Zn >10μg/L, whereas, Cu reached 10μg/L. After five leaching events, the leachability (percentage of cumulative heavy metal leached after five leaching events as in its respective total concentration in slags) of Cd was 0.05 percent and 0.035 percent from the old and young slag, respectively. Cr (0.035 percent and 0.05 percent) was greater than Cu (0.002 percent and 0.005 percent) and Zn (0.006 percent and 0.003 percent), while the lowest leachability was observed for Pb (0.0005 percent and 0.0002 percent) from the old and young slags, respectively. Reaction rates (release amount of heavy metals in certain period of leaching) of heavy metals in the leachates demonstrated the sequence of Zn>Cr>Cd, Cu>Pb. Leaching release of heavy metals was jointly affected by the pH of leaching solution and mineral composition of slags (including chemical forms of Cd, Cr, Cu, Pb, and Zn). Environmental exposure period of slags, resulting in the alteration of minerals, could affect the release process of heavy metals in leaching as well. Copyright © 2014 Elsevier Inc. All rights reserved.

Deposition of acidifying species in the Waterberg region of South Africa and the potential for stream chemistry impacts

NASA Astrophysics Data System (ADS)

Piketh, S.; Curtis, C.; Pienaar, K.; Khuzwayo, L.; van Zyl, P. G.; Conradie, E.

2016-12-01

South Africa is rich in natural resources that include large deposits of coal. As a result more than 90% of the energy in the country is generated by 13 coal fired power stations located on the Highveld region. Over the past 7 years South Africa has experienced severe power shortages which has resulted in the approval of two new mega coal fired power stations each with a 4800 Mw generating capacity. One of these power stations is at Lephalale in the Waterberg. This region is largely dominated by a natural to semi-natural landscape, but some areas have acid sensitive sub-soils (pH < 5.5) rendering their headwater streams vulnerable to acidification. There are only three other important sources of emissions close to Lephalale, a second coal fired power station, a char plant and domestic coal combustion. In an attempt to determine baseline conditions of air pollution, deposition and stream chemistry impacts prior to the commissioning of the new PS the following measurements have been undertaken, ambient concentrations of SO2, NOx, NH3 and O3 (at seven sites since 2010), rain water chemistry ( at one site for 2015 and 2016) and headwater stream vulnerability (2015 and 2016). Concentrations of sodium (Na+), ammonium (NH4+), potassium (K+), calcium (Ca2+), magnesium (Mg2+), nitrate 21 (NO3-), chloride (Cl-), sulphate (SO42-) in the rain water will be presented and compared to other long term sites around South Africa. Total deposition of S and N will in the Lephalale region will be presented. At least 30 acid-sensitive headwater streams, many with low pH <6 and low acid neutralizing capacity that are extremely sensitive to acid deposition inputs have been identified. Future deposition in the area of acidifying species will be modelled by including emissions from the new Power station and estimates of the potential impact will be assessed.

Adsorption by and artificial release of zinc and lead from porous concrete for recycling of adsorbed zinc and lead and of porous concrete to reduce urban non-point heavy metal runoff.

PubMed

Harada, Shigeki; Yanbe, Miyu

2018-04-01

This report describes the use of porous concrete at the bottom of a sewage trap to prevent runoff of non-point heavy metals into receiving waters, and, secondarily, to reduce total runoff volume during heavy rains in urbanized areas while simultaneously increasing the recharge volume of heavy-metal-free water into underground aquifers. This idea has the advantage of preventing clogging, which is fundamentally very important when using pervious materials. During actual field experiments, two important parameters were identified: maximum adsorption weight of lead and zinc by the volume of porous concrete, and heavy metal recovery rate by artificial acidification after adsorption. To understand the effect of ambient heavy metal concentration, a simple mixing system was used to adjust the concentrations of lead and zinc solutions. The concrete blocks used had been prepared for a previous study by Harada & Komuro (2010). The results showed that maximum adsorption depended on the ambient concentration, expressed as the linear isothermal theory, and that recovery depended on the final pH value (0.5 or 0.0). The dependence on pH is very important for recycling the porous concrete. A pH of 0.5 is important for recycling both heavy metals, especially zinc, (8.0-22.1% of lead and 42-74% of zinc) and porous concrete because porous concrete has not been heavily damaged by acid. However, at a pH of 0.0, the heavy metals could be recovered: 30-60% of the lead and 75-125% of the zinc. At a higher pH, such as 2.0, no release of heavy metals occurred, indicating the safety to the environment of using porous concrete, because the lowest recorded pH of rainfall in Japan is. 4.0. Copyright © 2018 Elsevier Ltd. All rights reserved.

Resource Aware Intelligent Network Services (RAINS) Final Technical Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lehman, Tom; Yang, Xi

The Resource Aware Intelligent Network Services (RAINS) project conducted research and developed technologies in the area of cyber infrastructure resource modeling and computation. The goal of this work was to provide a foundation to enable intelligent, software defined services which spanned the network AND the resources which connect to the network. A Multi-Resource Service Plane (MRSP) was defined, which allows resource owners/managers to locate and place themselves from a topology and service availability perspective within the dynamic networked cyberinfrastructure ecosystem. The MRSP enables the presentation of integrated topology views and computation results which can include resources across the spectrum ofmore » compute, storage, and networks. The RAINS project developed MSRP includes the following key components: i) Multi-Resource Service (MRS) Ontology/Multi-Resource Markup Language (MRML), ii) Resource Computation Engine (RCE), iii) Modular Driver Framework (to allow integration of a variety of external resources). The MRS/MRML is a general and extensible modeling framework that allows for resource owners to model, or describe, a wide variety of resource types. All resources are described using three categories of elements: Resources, Services, and Relationships between the elements. This modeling framework defines a common method for the transformation of cyber infrastructure resources into data in the form of MRML models. In order to realize this infrastructure datification, the RAINS project developed a model based computation system, i.e. “RAINS Computation Engine (RCE)”. The RCE has the ability to ingest, process, integrate, and compute based on automatically generated MRML models. The RCE interacts with the resources thru system drivers which are specific to the type of external network or resource controller. The RAINS project developed a modular and pluggable driver system which facilities a variety of resource controllers to automatically generate, maintain, and distribute MRML based resource descriptions. Once all of the resource topologies are absorbed by the RCE, a connected graph of the full distributed system topology is constructed, which forms the basis for computation and workflow processing. The RCE includes a Modular Computation Element (MCE) framework which allows for tailoring of the computation process to the specific set of resources under control, and the services desired. The input and output of an MCE are both model data based on MRS/MRML ontology and schema. Some of the RAINS project accomplishments include: Development of general and extensible multi-resource modeling framework; Design of a Resource Computation Engine (RCE) system which includes the following key capabilities; Absorb a variety of multi-resource model types and build integrated models; Novel architecture which uses model based communications across the full stack for all Flexible provision of abstract or intent based user facing interfaces; Workflow processing based on model descriptions; Release of the RCE as an open source software; Deployment of RCE in the University of Maryland/Mid-Atlantic Crossroad ScienceDMZ in prototype mode with a plan under way to transition to production; Deployment at the Argonne National Laboratory DTN Facility in prototype mode; Selection of RCE by the DOE SENSE (SDN for End-to-end Networked Science at the Exascale) project as the basis for their orchestration service.« less

Holiday Perspectives on Air Traffic Control

NASA Image and Video Library

2016-12-14

As America travels over the holidays, NASA’s FutureFlight Central (FFC) is working to help passengers get to their destinations on time. The 360-degree virtual air traffic control tower is capable of simulating traffic and weather conditions to include snow, sleet and rain at almost any airport in the United States.

High-density mammalian cell cultures in stirred-tank bioreactor without external pH control.

PubMed

Xu, Sen; Chen, Hao

2016-08-10

Maintaining desired pH is a necessity for optimal cell growth and protein production. It is typically achieved through a two-sided pH control loop on the bioreactor controller. Here we investigated cell culture processes with minimum or no pH control and demonstrated that high-density mammalian cell cultures could be maintained for long-term protein production without pH control. The intrinsic interactions between pCO2, lactate, and pH were leveraged to maintain culture pH. Fed-batch cultures at the same lower pH limit of 6.75 but different upper pH limits (7.05, 7.30, 7.45, 7.65) were evaluated in the 3L bioreactors and comparable results were obtained. Neither CO2 sparging nor base addition was required to control pH in the pH range of 6.75-7.65. The impact of sparger configurations (drilled hole sparger vs. frit sparger) and scales (3L vs. 200L) on CO2 accumulation and culture pH was also demonstrated. The same principle was applied in two perfusion cultures with steady state cell densities at 42.5±3.3 or 68.3±6.0×10(6)cells/mL with low cell specific perfusion rates (15±2 to 23±3pL/cell/day), achieving up to 1.9±0.1g/L/day bioreactor productivity. Culture pH level in the 3L perfusion bioreactors was steadily maintained by controlling the residual lactate and pCO2 levels without the requirement of external pH control for up to 40days with consistent productivity and product quality. Furthermore, culture pH could be potentially modulated via adjusting residual glucose levels and CO2 stripping capability in perfusion cultures. To the best of our knowledge, this is the first time a systematic study was performed to evaluate the long-term cell cultivation and protein production in stirred-tank bioreactors without external pH control. Copyright © 2016 Elsevier B.V. All rights reserved.

A System for Distributing Real-Time Customized (NEXRAD-Radar) Geosciences Data

NASA Astrophysics Data System (ADS)

Singh, Satpreet; McWhirter, Jeff; Krajewski, Witold; Kruger, Anton; Goska, Radoslaw; Seo, Bongchul; Domaszczynski, Piotr; Weber, Jeff

2010-05-01

Hydrometeorologists and hydrologists can benefit from (weather) radar derived rain products, including rain rates and accumulations. The Hydro-NEXRAD system (HNX1) has been in operation since 2006 at IIHR-Hydroscience and Engineering at The University of Iowa. It provides rapid and user-friendly access to such user-customized products, generated using archived Weather Surveillance Doppler Radar (WSR-88D) data from the NEXRAD weather radar network in the United States. HNX1 allows researchers to deal directly with radar-derived rain products, without the burden of the details of radar data collection, quality control, processing, and format conversion. A number of hydrologic applications can benefit from a continuous real-time feed of customized radar-derived rain products. We are currently developing such a system, Hydro-NEXRAD 2 (HNX2). HNX2 collects real-time, unprocessed data from multiple NEXRAD radars as they become available, processes them through a user-configurable pipeline of data-processing modules, and then publishes processed products at regular intervals. Modules in the data processing pipeline encapsulate algorithms such as non-meteorological echo detection, range correction, radar-reflectivity-rain rate (Z-R) conversion, advection correction, merging products from multiple radars, and grid transformations. HNX2's implementation presents significant challenges, including quality-control, error-handling, time-synchronization of data from multiple asynchronous sources, generation of multiple-radar metadata products, distribution of products to a user base with diverse needs and constraints, and scalability. For content management and distribution, HNX2 uses RAMADDA (Repository for Archiving, Managing and Accessing Diverse Data), developed by the UCAR/Unidata Program Center in the Unites States. RAMADDA allows HNX2 to publish products through automation and gives users multiple access methods to the published products, including simple web-browser based access, and OpenDAP access. The latter allows a user to set up automation at his/her end, and fetch new data from HNX2 at regular intervals. HNX2 uses a two-dimensional metadata structure called a mosaic for managing metadata of the rain products. Currently, HNX2 is in pre-production state and is serving near real-time rain-rate map data-products for individual radars and merged data-products from seven radars covering the state of Iowa in the United States. These products then drive a rainfall-runoff model called CUENCAS, which is used as part of the Iowa Flood Center (housed at The University of Iowa) real-time flood forecasting system. We are currently developing a generalized scalable framework that will run on inexpensive hardware and will provide products for basins anywhere in the continental United States.

Characteristics of rain penetration through a gravity ventilator used for natural ventilation.

PubMed

Kim, Taehyeung; Lee, Dong Ho; Ahn, Kwangseog; Ha, Hyunchul; Park, Heechang; Piao, Cheng Xu; Li, Xiaoyu; Seo, Jeoungyoon

2008-01-01

Gravity ventilators rely simply on air buoyancy to extract air and are widely used to exhaust air contaminants and heat from workplaces using minimal energy. They are designed to maximize the exhaust flow rate, but the rain penetration sometimes causes malfunctioning. In this study, the characteristics of rain penetration through a ventilator were examined as a preliminary study to develop a ventilator with the maximum exhaust capacity while minimizing rain penetration. A model ventilator was built and exposed to artificial rain and wind. The paths, intensities and amounts of penetration through the ventilator were observed and measured in qualitative and quantitative fashions. In the first phase, the pathways and intensities of rain penetration were visually observed. In the second phase, the amounts of rain penetration were quantitatively measured under the different configurations of ventilator components that were installed based on the information obtained in the first-phase experiment. The effects of wind speed, grill direction, rain drainage width, outer wall height, neck height and leaning angle of the outer wall from the vertical position were analyzed. Wind speed significantly affected rain penetration. Under the low crosswind conditions, the rain penetration intensities were under the limit of detection. Under the high crosswind conditions, grill direction and neck height were the most significant factors in reducing rain penetration. The installation of rain drainage was also important in reducing rain penetration. The experimental results suggest that, with proper configurations of its components, a gravity ventilator can be used for natural ventilation without significant rain penetration problems.

Real-time pH monitoring of industrially relevant enzymatic reactions in a microfluidic side-entry reactor (μSER) shows potential for pH control.

PubMed

Gruber, Pia; Marques, Marco P C; Sulzer, Philipp; Wohlgemuth, Roland; Mayr, Torsten; Baganz, Frank; Szita, Nicolas

2017-06-01

Monitoring and control of pH is essential for the control of reaction conditions and reaction progress for any biocatalytic or biotechnological process. Microfluidic enzymatic reactors are increasingly proposed for process development, however typically lack instrumentation, such as pH monitoring. We present a microfluidic side-entry reactor (μSER) and demonstrate for the first time real-time pH monitoring of the progression of an enzymatic reaction in a microfluidic reactor as a first step towards achieving pH control. Two different types of optical pH sensors were integrated at several positions in the reactor channel which enabled pH monitoring between pH 3.5 and pH 8.5, thus a broader range than typically reported. The sensors withstood the thermal bonding temperatures typical of microfluidic device fabrication. Additionally, fluidic inputs along the reaction channel were implemented to adjust the pH of the reaction. Time-course profiles of pH were recorded for a transketolase and a penicillin G acylase catalyzed reaction. Without pH adjustment, the former showed a pH increase of 1 pH unit and the latter a pH decrease of about 2.5 pH units. With pH adjustment, the pH drop of the penicillin G acylase catalyzed reaction was significantly attenuated, the reaction condition kept at a pH suitable for the operation of the enzyme, and the product yield increased. This contribution represents a further step towards fully instrumented and controlled microfluidic reactors for biocatalytic process development. © 2017 The Authors. Biotechnology Journal published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rainfall Estimation over the Nile Basin using an Adapted Version of the SCaMPR Algorithm

NASA Astrophysics Data System (ADS)

Habib, E. H.; Kuligowski, R. J.; Elshamy, M. E.; Ali, M. A.; Haile, A.; Amin, D.; Eldin, A.

2011-12-01

Management of Egypt's Aswan High Dam is critical not only for flood control on the Nile but also for ensuring adequate water supplies for most of Egypt since rainfall is scarce over the vast majority of its land area. However, reservoir inflow is driven by rainfall over Sudan, Ethiopia, Uganda, and several other countries from which routine rain gauge data are sparse. Satellite-derived estimates of rainfall offer a much more detailed and timely set of data to form a basis for decisions on the operation of the dam. A single-channel infrared algorithm is currently in operational use at the Egyptian Nile Forecast Center (NFC). This study reports on the adaptation of a multi-spectral, multi-instrument satellite rainfall estimation algorithm (Self-Calibrating Multivariate Precipitation Retrieval, SCaMPR) for operational application over the Nile Basin. The algorithm uses a set of rainfall predictors from multi-spectral Infrared cloud top observations and self-calibrates them to a set of predictands from Microwave (MW) rain rate estimates. For application over the Nile Basin, the SCaMPR algorithm uses multiple satellite IR channels recently available to NFC from the Spinning Enhanced Visible and Infrared Imager (SEVIRI). Microwave rain rates are acquired from multiple sources such as SSM/I, SSMIS, AMSU, AMSR-E, and TMI. The algorithm has two main steps: rain/no-rain separation using discriminant analysis, and rain rate estimation using stepwise linear regression. We test two modes of algorithm calibration: real-time calibration with continuous updates of coefficients with newly coming MW rain rates, and calibration using static coefficients that are derived from IR-MW data from past observations. We also compare the SCaMPR algorithm to other global-scale satellite rainfall algorithms (e.g., 'Tropical Rainfall Measuring Mission (TRMM) and other sources' (TRMM-3B42) product, and the National Oceanographic and Atmospheric Administration Climate Prediction Center (NOAA-CPC) CMORPH product. The algorithm has several potential future applications such as: improving the performance accuracy of hydrologic forecasting models over the Nile Basin, and utilizing the enhanced rainfall datasets and better-calibrated hydrologic models to assess the impacts of climate change on the region's water availability.

Improvement of the Performance of an Electrocoagulation Process System Using Fuzzy Control of pH.

PubMed

Demirci, Yavuz; Pekel, Lutfiye Canan; Altinten, Ayla; Alpbaz, Mustafa

2015-12-01

The removal efficiencies of electrocoagulation (EC) systems are highly dependent on the initial value of pH. If an EC system has an acidic influent, the pH of the effluent increases during the treatment process; conversely, if such a system has an alkaline influent, the pH of the effluent decreases during the treatment process. Thus, changes in the pH of the wastewater affect the efficiency of the EC process. In this study, we investigated the dynamic effects of pH. To evaluate approaches for preventing increases in the pH of the system, the MATLAB/Simulink program was used to develop and evaluate an on-line computer-based system for pH control. The aim of this work was to study Proportional-Integral-Derivative (PID) control and fuzzy control of the pH of a real textile wastewater purification process using EC. The performances and dynamic behaviors of these two control systems were evaluated based on determinations of COD, colour, and turbidity removal efficiencies.

40 CFR 72.31 - Information requirements for Acid Rain permit applications.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Information requirements for Acid Rain... (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Acid Rain Permit Applications § 72.31 Information requirements for Acid Rain permit applications. A complete Acid Rain permit application shall include the...

40 CFR 72.31 - Information requirements for Acid Rain permit applications.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Information requirements for Acid Rain... (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Acid Rain Permit Applications § 72.31 Information requirements for Acid Rain permit applications. A complete Acid Rain permit application shall include the...

40 CFR 72.31 - Information requirements for Acid Rain permit applications.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Information requirements for Acid Rain... (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Acid Rain Permit Applications § 72.31 Information requirements for Acid Rain permit applications. A complete Acid Rain permit application shall include the...

40 CFR 72.31 - Information requirements for Acid Rain permit applications.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Information requirements for Acid Rain... (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Acid Rain Permit Applications § 72.31 Information requirements for Acid Rain permit applications. A complete Acid Rain permit application shall include the...

40 CFR 72.31 - Information requirements for Acid Rain permit applications.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Information requirements for Acid Rain... (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Acid Rain Permit Applications § 72.31 Information requirements for Acid Rain permit applications. A complete Acid Rain permit application shall include the...

Inter-comparison of automatic rain gauges

NASA Technical Reports Server (NTRS)

Nystuen, Jeffrey A.

1994-01-01

The Ocean Acoustics Division (OAD) of the Atlantic Oceanographic and Meteorological Laboratory (AOML), in cooperation with NOAA/NESDIS and NASA, has deployed six rain gauges for calibration and intercomparison purposes. These instruments include: (1) a weighing rain gauge, (2) a RM Young Model 50202 capacitance rain gauge, (3) a ScTI ORG-705 (long path) optical rain gauge, (4) a ScTI ORG-105 (mini-ORG) optical rain gauge, (5) a Belfort Model 382 tipping bucket rain gauge, and (6) a Distromet RD-69 disdrometer. The system has been running continuously since July 1993. During this time period, roughly 150 events with maximum rainfall rate over 10 mm/hr and 25 events with maximum rainfall rates over 100 mm/hr have been recorded. All rain gauge types have performed well, with intercorrelations 0.9 or higher. However, limitations for each type of rain gauge have been observed.

Comparing the impact of time displaced and biased precipitation estimates for online updated urban runoff models.

PubMed

Borup, Morten; Grum, Morten; Mikkelsen, Peter Steen

2013-01-01

When an online runoff model is updated from system measurements, the requirements of the precipitation input change. Using rain gauge data as precipitation input there will be a displacement between the time when the rain hits the gauge and the time where the rain hits the actual catchment, due to the time it takes for the rain cell to travel from the rain gauge to the catchment. Since this time displacement is not present for system measurements the data assimilation scheme might already have updated the model to include the impact from the particular rain cell when the rain data is forced upon the model, which therefore will end up including the same rain twice in the model run. This paper compares forecast accuracy of updated models when using time displaced rain input to that of rain input with constant biases. This is done using a simple time-area model and historic rain series that are either displaced in time or affected with a bias. The results show that for a 10 minute forecast, time displacements of 5 and 10 minutes compare to biases of 60 and 100%, respectively, independent of the catchments time of concentration.

A comparative assessment of R. M. Young and tipping bucket rain gauges

NASA Technical Reports Server (NTRS)

Goldhirsh, Julius; Gebo, Norman E.

1992-01-01

Rain rates as derived from standard tipping bucket rain gauges have variable integration times corresponding to the interval between bucket tips. For example, the integration time for the Weathertronics rain gauge is given by delta(T) = 15.24/R (min), where R is the rain rate expressed in mm/h and delta(T) is the time between tips expressed in minutes. It is apparent that a rain rate of 1 mm/h has an integration time in excess of 15 minutes. Rain rates larger than 15.24 mm/h will have integration times smaller than 1 minute. The integration time is dictated by the time it takes to fill a small tipping bucket where each tip gives rise to 0.254 mm of rainfall. Hence, a uniform rain rate of 1 mm/h over a 15 minute period will give rise to the same rain rate as 0 mm/h rainfall over the first 14 minutes and 15 mm/h between 14 to 15 minutes from the reference tip. Hence, the rain intensity fluctuations may not be captured with the tipping bucket rain gauge for highly variable rates encompassing lower and higher values over a given integration time. The objective of this effort is to provide an assessment of the features of the R. M. Young capacitive gauge and to compare these features with those of the standard tipping bucket rain gauge. A number of rain rate-time series derived from measurements with approximately co-located gauges are examined.

Freshwater salinization syndrome on a continental scale.

PubMed

Kaushal, Sujay S; Likens, Gene E; Pace, Michael L; Utz, Ryan M; Haq, Shahan; Gorman, Julia; Grese, Melissa

2018-01-23

Salt pollution and human-accelerated weathering are shifting the chemical composition of major ions in fresh water and increasing salinization and alkalinization across North America. We propose a concept, the freshwater salinization syndrome, which links salinization and alkalinization processes. This syndrome manifests as concurrent trends in specific conductance, pH, alkalinity, and base cations. Although individual trends can vary in strength, changes in salinization and alkalinization have affected 37% and 90%, respectively, of the drainage area of the contiguous United States over the past century. Across 232 United States Geological Survey (USGS) monitoring sites, 66% of stream and river sites showed a statistical increase in pH, which often began decades before acid rain regulations. The syndrome is most prominent in the densely populated eastern and midwestern United States, where salinity and alkalinity have increased most rapidly. The syndrome is caused by salt pollution (e.g., road deicers, irrigation runoff, sewage, potash), accelerated weathering and soil cation exchange, mining and resource extraction, and the presence of easily weathered minerals used in agriculture (lime) and urbanization (concrete). Increasing salts with strong bases and carbonates elevate acid neutralizing capacity and pH, and increasing sodium from salt pollution eventually displaces base cations on soil exchange sites, which further increases pH and alkalinization. Symptoms of the syndrome can include: infrastructure corrosion, contaminant mobilization, and variations in coastal ocean acidification caused by increasingly alkaline river inputs. Unless regulated and managed, the freshwater salinization syndrome can have significant impacts on ecosystem services such as safe drinking water, contaminant retention, and biodiversity. Copyright © 2018 the Author(s). Published by PNAS.

Freshwater salinization syndrome on a continental scale

PubMed Central

Likens, Gene E.; Pace, Michael L.; Utz, Ryan M.; Haq, Shahan; Gorman, Julia; Grese, Melissa

2018-01-01

Salt pollution and human-accelerated weathering are shifting the chemical composition of major ions in fresh water and increasing salinization and alkalinization across North America. We propose a concept, the freshwater salinization syndrome, which links salinization and alkalinization processes. This syndrome manifests as concurrent trends in specific conductance, pH, alkalinity, and base cations. Although individual trends can vary in strength, changes in salinization and alkalinization have affected 37% and 90%, respectively, of the drainage area of the contiguous United States over the past century. Across 232 United States Geological Survey (USGS) monitoring sites, 66% of stream and river sites showed a statistical increase in pH, which often began decades before acid rain regulations. The syndrome is most prominent in the densely populated eastern and midwestern United States, where salinity and alkalinity have increased most rapidly. The syndrome is caused by salt pollution (e.g., road deicers, irrigation runoff, sewage, potash), accelerated weathering and soil cation exchange, mining and resource extraction, and the presence of easily weathered minerals used in agriculture (lime) and urbanization (concrete). Increasing salts with strong bases and carbonates elevate acid neutralizing capacity and pH, and increasing sodium from salt pollution eventually displaces base cations on soil exchange sites, which further increases pH and alkalinization. Symptoms of the syndrome can include: infrastructure corrosion, contaminant mobilization, and variations in coastal ocean acidification caused by increasingly alkaline river inputs. Unless regulated and managed, the freshwater salinization syndrome can have significant impacts on ecosystem services such as safe drinking water, contaminant retention, and biodiversity. PMID:29311318

Should precipitation influence dust emission in global dust models?

NASA Astrophysics Data System (ADS)

Okin, Gregory

2016-04-01

Soil moisture modulates the threshold shear stress required to initiate aeolian transport and dust emission. Most of the theoretical and laboratory work that has confirmed the impact of soil moisture has appropriately acknowledged that it is the soil moisture of a surface layer a few grain diameters thick that truly controls threshold shear velocity. Global and regional models of dust emission include the effect of soil moisture on transport threshold, but most ignore the fact that only the moisture of the very topmost "active layer" matters. The soil moisture in the active layer can differ greatly from that integrated through the top 2, 5, 10, or 100 cm (surface layers used by various global models) because the top 2 mm of heavy texture soils dries within ~1/2 day while sandy soils dry within less than 2 hours. Thus, in drylands where dust emission occurs, it is likely that this top layer is drier than the underlying soil in the days and weeks after rain. This paper explores, globally, the time between rain events in relation to the time for the active layer to dry and the timing of high wind events. This analysis is carried out using the same coarse reanalyses used in global dust models and is intended to inform the soil moisture controls in these models. The results of this analysis indicate that the timing between events is, in almost all dust-producing areas, significantly longer than the drying time of the active layer, even when considering soil texture differences. Further, the analysis shows that the probability of a high wind event during the period after a rain where the surface is wet is small. Therefore, in coarse global models, there is little reason to include rain-derived soil moisture in the modeling scheme.

An assessment of the impact of ATMS and CrIS data assimilation on precipitation prediction over the Tibetan Plateau

NASA Astrophysics Data System (ADS)

Xue, Tong; Xu, Jianjun; Guan, Zhaoyong; Chen, Han-Ching; Chiu, Long S.; Shao, Min

2017-07-01

Using the National Oceanic and Atmospheric Administration's Gridpoint Statistical Interpolation data assimilation system and the National Center for Atmospheric Research's Advanced Research Weather Research and Forecasting (WRF-ARW) regional model, the impact of assimilating Advanced Technology Microwave Sounder (ATMS) and Cross-track Infrared Sounder (CrIS) satellite data on precipitation prediction over the Tibetan Plateau in July 2015 was evaluated. Four experiments were designed: a control experiment and three data assimilation experiments with different data sets injected: conventional data only, a combination of conventional and ATMS satellite data, and a combination of conventional and CrIS satellite data. The results showed that the monthly mean of precipitation is shifted northward in the simulations and showed an orographic bias described as an overestimation upwind of the mountains and an underestimation in the south of the rain belt. The rain shadow mainly influenced prediction of the quantity of precipitation, although the main rainfall pattern was well simulated. For the first 24 h and last 24 h of accumulated daily precipitation, the model generally overestimated the amount of precipitation, but it was underestimated in the heavy-rainfall periods of 3-5, 13-16, and 22-25 July. The observed water vapor conveyance from the southeastern Tibetan Plateau was larger than in the model simulations, which induced inaccuracies in the forecast of heavy rain on 3-5 July. The data assimilation experiments, particularly the ATMS assimilation, were closer to the observations for the heavy-rainfall process than the control. Overall, based on the experiments in July 2015, the satellite data assimilation improved to some extent the prediction of the precipitation pattern over the Tibetan Plateau, although the simulation of the rain belt without data assimilation shows the regional shifting.

Mechanisms affecting the transition from shallow to deep convection over land: Inferences from observations collected at the ARM Southern Great Plains site

NASA Astrophysics Data System (ADS)

Zhang, Y.; Klein, S. A.

2009-12-01

11 years of summertime observations at the Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site are used to investigate mechanisms controlling the transition from shallow to deep convection over land. A more humid environment above the boundary layer favors the occurrence of late-afternoon heavy precipitation events. The higher moisture content is brought by wind from south. Greater boundary layer inhomogeneity in moist static energy (MSE) is correlated to larger rain rates at the initial stage of precipitation. MSE inhomogeneity is attributed to both moisture and temperature fields, and is correlated with westerly winds. In an examination of afternoon rain statistics, higher relative humidity above the boundary layer is correlated to an earlier onset and longer duration of precipitation, while greater boundary layer inhomogeneity and atmospheric instability are positively correlated to the total rain amount and the maximum rain rate. On balance, these observations favor theories for the transition that involve a moist free troposphere and boundary layer heterogeneity in preference to those that involve convective available potential energy or convective inhibition. Thus the evidence presented here supports the current emphasis in the modeling community on the entraining nature of convection and the role of boundary layer cold pools in triggering new convection.

Field data collection, analysis, and adaptive management of green infrastructure in the urban water cycle in Cleveland and Columbus, OH

NASA Astrophysics Data System (ADS)

Darner, R.; Shuster, W.

2016-12-01

Expansion of the urban environment can alter the landscape and creates challenges for how cities deal with energy and water. Large volumes of stormwater in areas that have combined septic and stormwater systems present on challenge. Managing the water as near to the source as possible by creates an environment that allows more infiltration and evapotranspiration. Stormwater control measures (SCM) associated with this type of development, often called green infrastructure, include rain gardens, pervious or porous pavements, bioswales, green or blue roofs, and others. In this presentation, we examine the hydrology of green infrastructure in urban sewersheds in Cleveland and Columbus, OH. We present the need for data throughout the water cycle and challenges to collecting field data at a small scale (single rain garden instrumented to measure inflows, outflow, weather, soil moisture, and groundwater levels) and at a macro scale (a project including low-cost rain gardens, highly engineered rain gardens, groundwater wells, weather stations, soil moisture, and combined sewer flow monitoring). Results will include quantifying the effectiveness of SCMs in intercepting stormwater for different precipitation event sizes. Small scale deployment analysis will demonstrate the role of active adaptive management in the ongoing optimization over multiple years of data collection.

Exogenous Melatonin Mitigates Acid Rain Stress to Tomato Plants through Modulation of Leaf Ultrastructure, Photosynthesis and Antioxidant Potential.

PubMed

Debnath, Biswojit; Hussain, Mubasher; Irshad, Muhammad; Mitra, Sangeeta; Li, Min; Liu, Shuang; Qiu, Dongliang

2018-02-11

Acid rain (AR) is a serious global environmental issue causing physio-morphological changes in plants. Melatonin, as an indoleamine molecule, has been known to mediate many physiological processes in plants under different kinds of environmental stress. However, the role of melatonin in acid rain stress tolerance remains inexpressible. This study investigated the possible role of melatonin on different physiological responses involving reactive oxygen species (ROS) metabolism in tomato plants under simulated acid rain (SAR) stress. SAR stress caused the inhibition of growth, damaged the grana lamella of the chloroplast, photosynthesis, and increased accumulation of ROS and lipid peroxidation in tomato plants. To cope the detrimental effect of SAR stress, plants under SAR condition had increased both enzymatic and nonenzymatic antioxidant substances compared with control plants. But such an increase in the antioxidant activities were incapable of inhibiting the destructive effect of SAR stress. Meanwhile, melatonin treatment increased SAR-stress tolerance by repairing the grana lamella of the chloroplast, improving photosynthesis and antioxidant activities compared with those in SAR-stressed plants. However, these possible effects of melatonin are dependent on concentration. Moreover, our study suggests that 100-μM melatonin treatment improved the SAR-stress tolerance by increasing photosynthesis and ROS scavenging antioxidant activities in tomato plants.

Low-Energy Electron Effects on the Polar Wind Observed by the POLAR Spacecraft

NASA Technical Reports Server (NTRS)

Horwitz, J. L.; Su, Y.-J.; Dors, E. E.; Moore, Thomas E.; Giles, Barbara L.; Chandler, Michael O.; Craven, Paul D.; Chang, S.-W.; Scudder, J.

1998-01-01

Large ion outflow velocity variation at POLAR apogee have been observed. The observed H+ flow velocities were in the range of 23-110 km/s and 0+ flow velocities were in the range of 5-25 km/s. These velocity ranges lie between those predicted by simulations of the photoelectron-driven polar wind and "baseline" polar wind. The electric current contributions of the photoelectrons and polar rain are expected to control the size and altitude of an electric potential drop which accelerates the polar wind at relatively high altitudes. In this presentation, we compare polar wind characteristics observed near 5000 km and 8 RE altitudes by the Thermal Ion Dynamics Experiment (TIDE) with measurements of low-energy electrons sampled by HYDRA, both from the POLAR spacecraft, to examine possible effects of the polar rain and photoelectrons on the polar wind. Both correlations and anti-correlations are found between the polar wind velocities and the polar rain fluxes at POLAR apogee during different polar cap crossings. Also, the low-altitude upward/downward photoelectron spectra are used to estimates the potential drops above the spacecraft. We interpret these observations in terms of the effects that both photoelectrons and polar rain may have on the electric potential and polar wind acceleration along polar cap magnetic field lines.

The future of emissions trading in light of the acid rain experience

DOE Office of Scientific and Technical Information (OSTI.GOV)

McLean, B.J.; Rico, R.

1995-12-31

The idea of emissions trading was developed more than two decades ago by environmental economists eager to provide new ideas for how to improve the efficiency of environmental protection. However, early emissions trading efforts were built on the historical {open_quotes}command and control{close_quotes} infrastructure which has dominated U.S. environmental protection until today. The {open_quotes}command and control{close_quotes} model initially had advantages that were of a very pragmatic character: it assured large pollution reductions in a time when large, cheap reductions were available and necessary; and it did not require a sophisticated government infrastructure. Within the last five years, large-scale emission trading programsmore » have been successfully designed and started that are fundamentally different from the earlier efforts, creating a new paradigm for environmental control just when our understanding of environmental problems is changing as well. The purpose of this paper is to focus on the largest national-scale program--the Acid Rain Program--and from that experience, forecast when emission trading programs may be headed based on our understanding of the factors currently influencing environmental management. The first section of this paper will briefly review the history of emissions trading programs, followed by a summary of the features of the Acid Rain Program, highlighting those features that distinguish it from previous efforts. The last section addresses the opportunities for emissions trading (and its probable future directions).« less

Electrochemical control of pH in a hydroponic nutrient solution

NASA Technical Reports Server (NTRS)

Schwartzkopf, S. H.

1986-01-01

The electrochemical pH control system described was found to provide a feasible alternative method of controlling nutrient solution pH for CELSS applications. The plants grown in nutrient solution in which the pH was controlled electrochemically showed no adverse effects. Further research into the design of a larger capacity electrode bridge for better control is indicated by the results of this experiment, and is currently under way.

Clinical profile of pneumonia and its association with rain wetting in patients admitted at a tertiary care institute during pandemic of influenza A (H1N1) pdm09 virus infection.

PubMed

Singh, Virendra; Sharma, Bharat Bhushan; Patel, Vivek; Poonia, Surendra

2014-01-01

Influenza pneumonia often occurs as epidemics in the Asian countries and have significant impact on the health of world population. We studied the association of rain-wetting with occurrence of pneumonia during the outbreak of the influenza A (H1N1) pdm09 virus infection. All patients admitted with community-acquired pneumonia during the period 13th September to 10th October 2010 were recruited in the present study. The diagnosis of influenza was established by real-time polymerase chain reaction (RT-PCR). The demographic data and clinical profile of the patients were recorded with a special consideration to record of possible risk factors. Of the 123 patients studied, 39 (32%) patients had tested positive for influenza A (H1N1) pdm09; 12 (10%) tested positive for influenza A and remaining 72 (58%) patients were negative for influenza virus. Pattern of illness was almost identical in H1N1-positive and-negative groups. History of rain-wetting was present in 48 patients (39%) preceding the onset of illness. Getting wet in the rain was significantly higher in patients with pneumonia than control subjects [odds ratio 2.53, 95% confidence intervals (CI) 1.301-4.91; p=0.009)]. The number of pneumonia patients was also higher on rainy days and the numbers started declining a week later. More pneumonia patients are admitted during the periods of greater rainfall and rain-wetting may be an important risk factor for the occurrence of pneumonia.

Chemical composition of rainwater in a tropical urban area of northern India

NASA Astrophysics Data System (ADS)

Jawad Al Obaidy, Abdul Hameed M.; Joshi, Himanshu

Rainwater samples during the monsoon of 2001 and 2002 were collected from Roorkee urban area, a medium sized "town group" situated on the right bank of Solani River, a tributary of the Ganga River, near the Himalayan foothills and analyzed for EC, pH, TSS, TDS and major ions. The median value of pH was 7.05, well above 5.6, which is the reference pH. The ratios of SO 42-+NO 3- and Ca 2++Mg 2+ (TA/TC) have been considered for acidity. In this study, ratio of TA/TC is quite below 1.0, indicating alkaline nature of rainwater. The concentration of ions in rain water have been observed to follow the pattern Ca 2+>HCO 3->Cl ->NO 3->Na +>Mg 2+>SO 42->K +. In order to estimate the marine and non-marine contribution, sea salt fraction has been calculated taking Na + as reference. All ionic ratios have been found to be higher than the recommended sea water ratios in all three types of land use, viz. residential, commercial and industrial, suggesting a significant contribution of non-marine origin for these components. A comparison with the data of the other Indian sites validates the inverse relation of Cl - and Na + with distance from the sea and highlights higher Ca 2+ concentration and lower SO 42- concentration.

Thermodynamic Driving Force of Hydrogen on Rumen Microbial Metabolism: A Theoretical Investigation

PubMed Central

van Lingen, Henk J.; Plugge, Caroline M.; Fadel, James G.; Kebreab, Ermias; Bannink, André; Dijkstra, Jan

2016-01-01

Hydrogen is a key product of rumen fermentation and has been suggested to thermodynamically control the production of the various volatile fatty acids (VFA). Previous studies, however, have not accounted for the fact that only thermodynamic near-equilibrium conditions control the magnitude of reaction rate. Furthermore, the role of NAD, which is affected by hydrogen partial pressure (PH2), has often not been considered. The aim of this study was to quantify the control of PH2 on reaction rates of specific fermentation pathways, methanogenesis and NADH oxidation in rumen microbes. The control of PH2 was quantified using the thermodynamic potential factor (FT), which is a dimensionless factor that corrects a predicted kinetic reaction rate for the thermodynamic control exerted. Unity FT was calculated for all glucose fermentation pathways considered, indicating no inhibition of PH2 on the production of a specific type of VFA (e.g., acetate, propionate and butyrate) in the rumen. For NADH oxidation without ferredoxin oxidation, increasing PH2 within the rumen physiological range decreased FT from unity to zero for different NAD+ to NADH ratios and pH of 6.2 and 7.0, which indicates thermodynamic control of PH2. For NADH oxidation with ferredoxin oxidation, increasing PH2 within the rumen physiological range decreased FT from unity at pH of 7.0 only. For the acetate to propionate conversion, FT increased from 0.65 to unity with increasing PH2, which indicates thermodynamic control. For propionate to acetate and butyrate to acetate conversions, FT decreased to zero below the rumen range of PH2, indicating full thermodynamic suppression. For methanogenesis by archaea without cytochromes, FT differed from unity only below the rumen range of PH2, indicating no thermodynamic control. This theoretical investigation shows that thermodynamic control of PH2 on individual VFA produced and associated yield of hydrogen and methane cannot be explained without considering NADH oxidation. PMID:27783615

40 CFR 72.69 - Issuance and effective date of acid rain permits.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Federal Acid Rain Permit Issuance Procedures § 72.69 Issuance and effective date of acid rain permits. (a) After the close of the public comment period, the Administrator will issue or deny an Acid Rain permit. The Administrator will serve a copy of any Acid Rain...

40 CFR 72.69 - Issuance and effective date of acid rain permits.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Federal Acid Rain Permit Issuance Procedures § 72.69 Issuance and effective date of acid rain permits. (a) After the close of the public comment period, the Administrator will issue or deny an Acid Rain permit. The Administrator will serve a copy of any Acid Rain...

40 CFR 72.69 - Issuance and effective date of acid rain permits.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Federal Acid Rain Permit Issuance Procedures § 72.69 Issuance and effective date of acid rain permits. (a) After the close of the public comment period, the Administrator will issue or deny an Acid Rain permit. The Administrator will serve a copy of any Acid Rain...

40 CFR 72.69 - Issuance and effective date of acid rain permits.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Federal Acid Rain Permit Issuance Procedures § 72.69 Issuance and effective date of acid rain permits. (a) After the close of the public comment period, the Administrator will issue or deny an Acid Rain permit. The Administrator will serve a copy of any Acid Rain...

40 CFR 72.69 - Issuance and effective date of acid rain permits.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Federal Acid Rain Permit Issuance Procedures § 72.69 Issuance and effective date of acid rain permits. (a) After the close of the public comment period, the Administrator will issue or deny an Acid Rain permit. The Administrator will serve a copy of any Acid Rain...

Comparison of Imerg Half Hourly Final GPM data with Rain Gauge for Riyadh City, Kingdom of Saudi Arabia

NASA Astrophysics Data System (ADS)

Tekeli, E.; Dönmez, S.

2016-12-01

Being launched in 1997 with the main goal of measuring moderate to heavy rainfall, TRMM enabled invaluable service to remote sensing and hydrology community with data more than 17 years. Based on TRMM experience, GPM was launched in 2014. GPM with increased radar sensitivity and higher spatial resolutions, is expected to enable better light rain and snowfall detection. In here, light rainfall detection capacity of IMERG Half hourly final GPM (IFHH) product is investigated for Riyadh City in Kingdom of Saudi Arabia. A tipping bucket rain gauge located on the roof of King Saud University Civil Engineering Department provided rainfall measurements in 10 minute intervals from 22 November 2014 till 11 Jun 2015. Obtained rain gauge data indicated 72 light rain (rain rate [rr] ≤2.5mm/h) 5 medium rain (2.5mm/hPreliminary results indicate that IFHH overestimate most of the light rain. For the medium and heavy rain rates, IFHH showed under estimations. As one of the major goals of GPM is accurate light rain detection, similar studies should be continued and databases should be formed.

A Robust, Microwave Rain Gauge

NASA Astrophysics Data System (ADS)

Mansheim, T. J.; Niemeier, J. J.; Kruger, A.

2008-12-01

Researchers at The University of Iowa have developed an all-electronic rain gauge that uses microwave sensors operating at either 10 GHz or 23 GHz, and measures the Doppler shift caused by falling raindrops. It is straightforward to interface these sensors with conventional data loggers, or integrate them into a wireless sensor network. A disadvantage of these microwave rain gauges is that they consume significant power when they are operating. However, this may be partially negated by using data loggers' or sensors networks' sleep-wake-sleep mechanism. Advantages of the microwave rain gauges are that one can make them very robust, they cannot clog, they don't have mechanical parts that wear out, and they don't have to be perfectly level. Prototype microwave rain gauges were collocated with tipping-bucket rain gauges, and data were collected for two seasons. At higher rain rates, microwave rain gauge measurements compare well with tipping-bucket measurements. At lower rain rates, the microwave rain gauges provide more detailed information than tipping buckets, which quantize measurement typically in 1 tip per 0.01 inch, or 1 tip per mm of rainfall.

Millimeter wave propagation modeling of inhomogeneous rain media for satellite communications systems

NASA Technical Reports Server (NTRS)

Persinger, R. R.; Stutzman, W. L.

1978-01-01

A theoretical propagation model that represents the scattering properties of an inhomogeneous rain often found on a satellite communications link is presented. The model includes the scattering effects of an arbitrary distribution of particle type (rain or ice), particle shape, particle size, and particle orientation within a given rain cell. An associated rain propagation prediction program predicts attenuation, isolation and phase shift as a function of ground rain rate. A frequency independent synthetic storm algorithm is presented that models nonuniform rain rates present on a satellite link. Antenna effects are included along with a discussion of rain reciprocity. The model is verified using the latest available multiple frequency data from the CTS and COMSTAR satellites. The data covers a wide range of frequencies, elevation angles, and ground site locations.

Evaluation of Turf-Grass and Prairie-Vegetated Rain Gardens in a Clay and Sand Soil, Madison, Wisconsin, Water Years 2004-08

USGS Publications Warehouse

Selbig, William R.; Balster, Nicholas

2010-01-01

The U.S. Geological Survey, in cooperation with a consortium of 19 cities, towns, and villages in Dane County, Wis., undertook a study to compare the capability of rain gardens with different vegetative species and soil types to infiltrate stormwater runoff from the roof of an adjacent structure. Two rain gardens, one planted with turf grass and the other with native prairie species, were constructed side-by-side in 2003 at two locations with different dominant soil types, either sand or clay. Each rain garden was sized to a ratio of approximately 5:1 contributing area to receiving area and to a depth of 0.5 foot. Each rain garden, regardless of vegetation or soil type, was capable of storing and infiltrating most of the runoff over the 5-year study period. Both rain gardens in sand, as well as the prairie rain garden in clay, retained and infiltrated 100 percent of all precipitation and snowmelt events during water years 2004-07. The turf rain garden in clay occasionally had runoff exceed its confining boundaries, but was still able to retain 96 percent of all precipitation and snowmelt events during the same time period. Precipitation intensity and number of antecedent dry days were important variables that influenced when the storage capacity of underlying soils would become saturated, which resulted in pooled water in the rain gardens. Because the rooftop area that drained runoff to each rain garden was approximately five times larger than the area of the rain garden itself, evapotranspiration was a small percentage of the annual water budget. For example, during water year 2005, the maximum evapotranspiration of total influent volume ranged from 21 percent for the turf rain garden in clay to 25 percent for the turf rain garden in sand, and the minimum ranged from 12 percent for the prairie rain garden in clay to 19 percent for the prairie rain garden in sand. Little to no runoff left each rain garden as effluent and a small percentage of runoff returned to the atmosphere through evapotranspiration; therefore, the remainder was considered recharge. During water year 2005, recharge was 81 to 75 percent of total influent volume for the prairie- and turf-rain gardens in sand and 87 to 78 percent for the prairie- and turf-rain gardens in clay, respectively. Maximum recharge volumes ranged from 90 to 94 percent of the total influent volume in the turf and prairie rain gardens in sand and occurred during water year 2004. Maximum recharge in the turf and prairie rain gardens in clay ranged from 89 percent during water year 2007 to 98 percent during water year 2004. Median infiltration rates were an order of magnitude greater for rain gardens planted in sand than for those in clay, regardless of vegetation type. Under similar soil conditions, rain gardens planted with turf grass had lower median infiltration rates than those planted with prairie species. Median infiltration rates were 0.28 and 0.88 inches per hour in the turf and prairie rain gardens in clay, respectively, and 2.5 and 4.2 inches per hour in the turf and prairie rain gardens in sand, respectively. In general, infiltration rates were greater during spring (April and May) and summer (June through August) months. Of the six observed exceedences of the storage capacity of the turf rain garden in clay between April-November during 2004-07, five were predicted by use of a combination of the normalized surface storage volume, the median infiltration rate, and an estimate of specific yield for soils under the rain garden to a depth equal to the uppermost limiting layer. By use of the same criteria, in water year 2008, when the contributing drainage area to the prairie rain garden in clay was doubled, all four observed exceedences of the total storage capacity were predicted. The accuracy of the predictions of when the total storage capacity of the rain gardens would be exceeded indicates that by applying measurements of the appropriate soil properties to rain g

Fortuitous consequence: The domestic politics of the 1991 Canada-United States agreement on air quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allison, J.E.

1999-07-01

Following more than a decade of negotiations, the Canada-United States Agreement on Air Quality entered into force on March 13, 1991, with the signatures of then-Canadian Prime Minister Brian Mulroney and US President George Bush. Why was it so difficult for Canadian and US negotiators to reach agreement? The author argues that Canadian and US domestic politics were the primary impediments to resolving the US-Canada acid rain dispute. This article thus casts the dispute in terms of a pair of domestic environmental policy problems, whose timely and complementary solution, furthermore, required executive initiative as the handmaiden of ecological crisis. Heightenedmore » public concern about the threat of acidic air pollution in Canada prompted Mulroney's efforts to reduce acid rain. In the US, a likewise critical change in the public's perception of air quality as a national emergency created the mass support necessary for Bush's federal acid rain control initiative.« less

Detecting Rhythms in Time Series with RAIN

PubMed Central

Thaben, Paul F.; Westermark, Pål O.

2014-01-01

A fundamental problem in research on biological rhythms is that of detecting and assessing the significance of rhythms in large sets of data. Classic methods based on Fourier theory are often hampered by the complex and unpredictable characteristics of experimental and biological noise. Robust nonparametric methods are available but are limited to specific wave forms. We present RAIN, a robust nonparametric method for the detection of rhythms of prespecified periods in biological data that can detect arbitrary wave forms. When applied to measurements of the circadian transcriptome and proteome of mouse liver, the sets of transcripts and proteins with rhythmic abundances were significantly expanded due to the increased detection power, when we controlled for false discovery. Validation against independent data confirmed the quality of these results. The large expansion of the circadian mouse liver transcriptomes and proteomes reflected the prevalence of nonsymmetric wave forms and led to new conclusions about function. RAIN was implemented as a freely available software package for R/Bioconductor and is presently also available as a web interface. PMID:25326247

Comparisons of Rain Estimates from Ground Radar and Satellite Over Mountainous Regions

NASA Technical Reports Server (NTRS)

Lin, Xin; Kidd, Chris; Tao, Jing; Barros, Ana

2016-01-01

A high-resolution rainfall product merging surface radar and an enhanced gauge network is used as a reference to examine two operational surface radar rainfall products over mountain areas. The two operational rainfall products include radar-only and conventional-gauge-corrected radar rainfall products. Statistics of rain occurrence and rain amount including their geographical, seasonal, and diurnal variations are examined using 3-year data. It is found that the three surface radar rainfall products in general agree well with one another over mountainous regions in terms of horizontal mean distributions of rain occurrence and rain amount. Frequency of rain occurrence and fraction of rain amount also indicate similar distribution patterns as a function of rain intensity. The diurnal signals of precipitation over mountain ridges are well captured and joint distributions of coincident raining samples indicate reasonable correlations during both summer and winter. Factors including undetected low-level precipitation, limited availability of gauges for correcting the Z-R relationship over the mountains, and radar beam blocking by mountains are clearly noticed in the two conventional radar rainfall products. Both radar-only and conventional-gauge-corrected radar rainfall products underestimate the rain occurrence and fraction of rain amount at intermediate and heavy rain intensities. Comparison of PR and TMI against a surface radar-only rainfall product indicates that the PR performs equally well with the high-resolution radar-only rainfall product over complex terrains at intermediate and heavy rain intensities during the summer and winter. TMI, on the other hand, requires improvement to retrieve wintertime precipitation over mountain areas.

The Impacts of Altered Precipitation Frequency and Amount on Carbon, Nitrogen, and Hydrological Processes in Subalpine Ecosystems

NASA Astrophysics Data System (ADS)

Gill, R. A.; Campbell, C. S.; McQueen, S.; Isupov, T.; Walker, B. J.

2011-12-01

Forecasts predict that precipitation regimes in the western US will become more variable, with dry periods becoming more frequent and with individual rainfall events becoming more extreme. In water-limited ecosystems, increased event size may reduce soil moisture stress and increase net primary production (NPP), N mineralization (Nmin), and soil water content (Θ) and potential (Ψ). In more mesic systems, the increased time between rain events may increase soil moisture stress and reduce NPP, Nmin, Θ, and Ψ. To test this hypothesis, we experimentally altered the timing and size of rainfall events and reduced ambient rainfall during the growing season for xeric, low-elevation sites and mesic high-elevation sites. Research was conducted at the Great Basin Experimental Range in Ephraim Canyon, UT, USA. The experimental treatments were (1) ambient rain, (2) 30% reduction in ambient rain, (3) 70% reduction in ambient rain, (4) reapplication of ambient rain weekly, and (5) reapplication of ambient rain every 3 weeks. During this 3-year experiment (2009-2011), we monitored soil temperature and Θ, leaf area index and NDVI, N-mineralization, soil respiration, and aboveground NPP. We calculated Ψ using soil moisture release curves. To increase the temporal scope of our results we used the DAY-CENT ecosystem model to simulate century-long impacts of precipitation changes. We found production increased with larger, less-frequent precipitation events for both our xeric and mesic sites. Large rainfall events increased the duration of production where Ψ is more negative than critical water thresholds. There were no significant changes in N-availability with altered precipitation, but the modeling results suggest that drought is a much stronger control over N-availability than precipitation timing. Our results demonstrate that both xeric and mesic systems are highly sensitive to the timing and amount of precipitation.

Application of automated measurement stations for continuous water quality monitoring of the Dender river in Flanders, Belgium.

PubMed

Vandenberghe, V; Goethals, P L M; Van Griensven, A; Meirlaen, J; De Pauw, N; Vanrolleghem, P; Bauwens, W

2005-09-01

During the summer of 1999, two automated water quality measurement stations were installed along the Dender river in Belgium. The variables dissolved oxygen, temperature, conductivity, pH, rain-intensity, flow and solar radiation were measured continuously. In this paper these on-line measurement series are presented and interpreted using also additional measurements and ecological expert-knowledge. The purpose was to demonstrate the variability in time and space of the aquatic processes and the consequences of conducting and interpreting discrete measurements for river quality assessment and management. The large fluctuations of the data illustrated the importance of continuous measurements for the complete description and modelling of the biological processes in the river.

Trace-metal concentrations, waters from selected sky lakes, streams and springs, northern Shawangunk Mountains, New York: geologic and ecologic implications

USGS Publications Warehouse

Friedman, J.D.; Huth, P.C.; Smiley, D.

1990-01-01

Reconnaissance sampling and chemical analysis of water from selected lakes, streams and springs of the northern Shawangunk Mountains in 1987 to 1988 to determine the influence of lithology on trace-metal concentrations in surface water, and to establish a base level of concentration of 27 selected metals by ICP-AES and Hg by cold-vapor AAS methods, for geochemical exploration, ecologic, acid-rain, and climatic-change studies, have yielded trace-metal concentrations greater than detection limits for 10 metallic elements. Eighteen additional metallic elements were also present in trace quantities below the quantitative detection limit. Two distinct geochemical populations are related to source lithology and pH. -from Authors

Scattering by Artificial Wind and Rain Roughened Water Surfaces at Oblique Incidences

NASA Technical Reports Server (NTRS)

Craeye, C.; Sobieski, P. W.; Bliven, L. F.

1997-01-01

Rain affects wind retrievals from scatterometric measurements of the sea surface. To depict the additional roughness caused by rain on a wind driven surface, we use a ring-wave spectral model. This enables us to analyse the rain effect on K(u) band scatterometric observations from two laboratory experiments. Calculations based on the small perturbation method provide good simulation of scattering measurements for the rain-only case, whereas for combined wind and rain cases, the boundary perturbation method is appropriate.

Road deicing salt irreversibly disrupts osmoregulation of salamander egg clutches.

PubMed

Karraker, Nancy E; Gibbs, James P

2011-03-01

It has been postulated that road deicing salts are sufficiently diluted by spring rains to ameliorate any physiological impacts to amphibians breeding in wetlands near roads. We tested this conjecture by exposing clutches of the spotted salamander (Ambystoma maculatum) to three chloride concentrations (1 mg/L, 145 mg/L, 945 mg/L) for nine days, then transferred clutches to control water for nine days, and measured change in mass at three-day intervals. We measured mass change because water uptake by clutches reduces risks to embryos associated with freezing, predation, and disease. Clutches in controls sequestered water asymptotically. Those in the moderate concentrations lost 18% mass initially and regained 14% after transfer to control water. Clutches in high concentration lost 33% mass and then lost an additional 8% after transfer. Our results suggest that spring rains do not ameliorate the effects of deicing salts in wetlands with extremely high chloride concentrations. Copyright © 2010 Elsevier Ltd. All rights reserved.

Rainfall estimation over oceans from scanning multichannel microwave radiometer and special sensor microwave/imager microwave data

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Dalu, G.; Liberti, G. L.; Nucciarone, J. J.; Suhasini, R.

1991-01-01

The brightness temperature (T sub b) measured at 37 GHz shows fairly strong emission from rain, and only slight effects caused by scattering by ice above the rain clouds. At frequencies below 37 GHz, were the fov is larger and the volume extinction coefficient is weaker, it is found that the observations do not yield appreciable additional information about rain. At 85 GHz (fov = 15 km), where the volume extinction is considerably larger, direct information about rain below the clouds is usually masked. Based on the above ideas, 37 GHz observations with a 30 km fov from SMMR and SSM/I are selected to develop an empirical method for the estimation of rain rate. In this method, the statistics of the observed T sub b's at 37 GHz in a rain storm are related to the rain rate statistics in that storm. The underestimation of rain rate, arising from the inability of the radiometer to respond sensitively to rain rate above a given threshold, is rectified in this technique with the aid of two parameters that depend on the total water vapor content in the atmosphere. The retrieved rain rates compare favorably with radar observations and monthly mean global maps of rain derived from this technique over the oceans.

Rainfall estimation over oceans from SMMR and SSM/I microwave data

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Dalu, G.; Liberti, G. L.; Nucciarone, J. J.; Suhasini, R.

1992-01-01

The brightness temperature (T sub b) measured at 37 GHz shows fairly strong emission from rain, and only slight effects caused by scattering by ice above the rain clouds. At frequencies below 37 GHz, where the FOV is larger and the volume extinction coefficient is weaker, it is found that the observations do not yield appreciable additional information about rain. At 85 GHz (FOV = 15 km), where the volume extinction is considerably larger, direct information about rain below the clouds is usually masked. Based on the above idea, 37 GHz observations with a 30 km FOV from SMMR and SSM/I are selected to develop an empirical method for the estimation of rain rate. In this method, the statistics of the observed T sub b's at 37 GHz in a rain storm are related to the rain rate statistics in that storm. The underestimation of rain rate, arising from the inability of the radiometer to respond sensitively to rain rate above a given threshold is rectified in this technique with the aid of two parameters that depend on the total water vapor content in the atmosphere. The retrieved rain rates compare favorably with radar observations and monthly mean global maps of rain derived from this technique over the oceans.

A TRMM Rainfall Estimation Method Applicable to Land Areas

NASA Technical Reports Server (NTRS)

Prabhakara, C.; Iacovazzi, R.; Weinman, J.; Dalu, G.

1999-01-01

Methods developed to estimate rain rate on a footprint scale over land with the satellite-borne multispectral dual-polarization Special Sensor Microwave Imager (SSM/1) radiometer have met with limited success. Variability of surface emissivity on land and beam filling are commonly cited as the weaknesses of these methods. On the contrary, we contend a more significant reason for this lack of success is that the information content of spectral and polarization measurements of the SSM/I is limited. because of significant redundancy. As a result, the complex nature and vertical distribution C, of frozen and melting ice particles of different densities, sizes, and shapes cannot resolved satisfactorily. Extinction in the microwave region due to these complex particles can mask the extinction due to rain drops. Because of these reasons, theoretical models that attempt to retrieve rain rate do not succeed on a footprint scale. To illustrate the weakness of these models, as an example we can consider the brightness temperature measurement made by the radiometer in the 85 GHz channel (T85). Models indicate that T85 should be inversely related to the rain rate, because of scattering. However, rain rate derived from 15-minute rain gauges on land indicate that this is not true in a majority of footprints. This is also supported by the ship-borne radar observations of rain in the Tropical Oceans and Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE) region over the ocean. Based on these observations. we infer that theoretical models that attempt to retrieve rain rate do not succeed on a footprint scale. We do not follow the above path of rain retrieval on a footprint scale. Instead, we depend on the limited ability of the microwave radiometer to detect the presence of rain. This capability is useful to determine the rain area in a mesoscale region. We find in a given rain event that this rain area is closely related to the mesoscale-average rain rate. Based on this observation, in this study we have developed a method to estimate the mesoscale-average rain rate over land utilizing microwave radiometer data. Because of the high degree of geographic and seasonal variability in the nature and intensity of rain, this method requires some tuning with 15-minute rain gauge data on land. After tuning the method, it can be applied to an independent set of rain events that are close in time and space. We find that the mesoscale rain rates retrieved over the period of a month on land with this method shows a correlation of about 0.85 with respect to the surface rain-gauge observations. This mesoscale-average rain rate estimation method can be useful to extend the spatial and temporal coverage of the rainfall data provided by the Precipitation Radar on board the Tropical Rainfall Measuring Mission (TRMM) satellite.

Acid Rain: A Teacher's Guide. Activities for Grades 4 to 12.

ERIC Educational Resources Information Center

National Wildlife Federation, Washington, DC.

This guide on acid rain for elementary and secondary students is divided into three study areas: (1) What Causes Acid Rain; (2) What Problems Acid Rain Has Created; (3) How You and Your Students Can Help Combat Acid Rain. Each section presents background information and a series of lessons pertaining to the section topic. Activities include…

Acid Rain. Activities for Grades 4 to 12. A Teacher's Guide.

ERIC Educational Resources Information Center

Wood, David; Bryant, Jeannette

This teacher's guide on acid rain is divided into three study areas to explain: (1) what causes acid rain; (2) what problems acid rain has created; and (3) what teachers and students can do to help combat acid rain. Instructions for activities within the study areas include suggested grade levels, objectives, materials needed, and directions for…

Rain Rate Statistics in Southern New Mexico

NASA Technical Reports Server (NTRS)

Paulic, Frank J., Jr.; Horan, Stephen

1997-01-01

The methodology used in determining empirical rain-rate distributions for Southern New Mexico in the vicinity of White Sands APT site is discussed. The hardware and the software developed to extract rain rate from the rain accumulation data collected at White Sands APT site are described. The accuracy of Crane's Global Model for rain rate predictions is analyzed.

Development of an economical, autonomous pHstat system for culturing phytoplankton under steady state or dynamic conditions.

PubMed

Golda, Rachel L; Golda, Mark D; Hayes, Jacqueline A; Peterson, Tawnya D; Needoba, Joseph A

2017-05-01

Laboratory investigations of physiological processes in phytoplankton require precise control of experimental conditions. Chemostats customized to control and maintain stable pH levels (pHstats) are ideally suited for investigations of the effects of pH on phytoplankton physiology, for example in context of ocean acidification. Here we designed and constructed a simple, flexible pHstat system and demonstrated its operational capabilities under laboratory culture conditions. In particular, the system is useful for simulating natural cyclic pH variability within aquatic ecosystems, such as diel fluctuations that result from metabolic activity or tidal mixing in estuaries. The pHstat system operates in two modes: (1) static/set point pH, which maintains pH at a constant level, or (2) dynamic pH, which generates regular, sinusoidal pH fluctuations by systematically varying pH according to user-defined parameters. The pHstat is self-regulating through the use of interchangeable electronically controlled reagent or gas-mediated pH-modification manifolds, both of which feature flow regulation by solenoid valves. Although effective pH control was achieved using both liquid reagent additions and gas-mediated methods, the liquid manifold exhibited tighter control (±0.03pH units) of the desired pH than the gas manifold (±0.10pH units). The precise control provided by this pHstat system, as well as its operational flexibility will facilitate studies that examine responses by marine microbiota to fluctuations in pH in aquatic ecosystems. Copyright © 2017 Elsevier B.V. All rights reserved.

Hydrologic Characteristics of Low-Impact Stormwater Control Measures at Two Sites in Northeastern Ohio, 2008-13 (USGS Scientific Investigations Report 2015-5030)

EPA Science Inventory

This report updates and examines hydrologic data gathered to characterize the performance of two stormwater control measures (SCM) sites in the Chagrin River watershed, Ohio. At the Sterncrest Drive site, roadside bioswales and rain gardens were used to alleviate drainage problem...

Cost Comparison of Conventional Gray Combined Sewer Overflow Control Infrastructure versus a Green/Gray Combination

EPA Science Inventory

This paper outlines a life-cycle cost analysis comparing a green (rain gardens) and gray (tunnels) infrastructure combination to a gray-only option to control combined sewer overflow in the Turkey Creek Combined Sewer Overflow Basin, in Kansas City, MO. The plan area of this Bas...

Factors influencing efficacy of plastic shelters for control of bacterial blight of lilac

USDA-ARS?s Scientific Manuscript database

Plastic shelters are thought to manage bacterial blight by protecting plants from rain and/or frost. In February to April 2008 and 2009, we studied the contribution of frost protection to efficacy of this cultural control practice. Lilacs in 1-gallon pots were exposed to four treatments: 1) plants...

Mechanistic study of lead desorption during the leaching process of ion-absorbed rare earths: pH effect and the column experiment.

PubMed

Tang, Jie; Xue, Qiang; Chen, Honghan; Li, Wenting

2017-05-01

High concentrations of ammonium sulfate, often used in the in situ mining process, can result in a decrease of pH in the environment and dissolution of rare earth metals. Ammonium sulfate can also cause desorption of toxic heavy metals, leading to environmental and human health implications. In this study, the desorption behavior and fraction changes of lead in the ion-absorbed rare earth ore were studied using batch desorption experiments and column leaching tests. Results from batch desorption experiments showed that the desorption process of lead included fast and slow stages and followed an Elovich model well. The desorption rate and the proportion of lead content in the solution to the total lead in the soil were observed to increase with a decrease in the initial pH of the ammonium sulfate solution. The lead in soil included an acid-extractable fraction, reducible fraction, oxidizable fraction, and a residual fraction, with the predominant fractions being the reducible and acid-extractable fractions. Ninety-six percent of the extractable fraction in soil was desorbed into solution at pH = 3.0, and the content of the reducible fraction was observed to initially increase (when pH >4.0) and then decrease (when pH <4.0) with a decrease in pH. Column leaching tests indicated that the content of lead in the different fractions of soil followed the trend of reducible fraction > oxidizable fraction > acid-extractable fraction > residual fraction after the simulating leaching mining process. The change in pH was also found to have a larger influence on the acid-extractable and reducible fractions than the other two fractions. The proportion of the extractable fraction being leached was ca. 86%, and the reducible fraction was enriched along the migration direction of the leaching liquid. These results suggest that certain lead fractions may desorb again and contaminate the environment via acid rain, which provides significant information for environmental assessment and remediation after mining process. Graphical abstract ᅟ.

9 CFR 3.77 - Sheltered housing facilities.

Code of Federal Regulations, 2012 CFR

2012-01-01

... from the elements at all times. They must provide protection from the sun, rain, snow, wind, and cold... trainer at all times during the contact. (Approved by the Office of Management and Budget under control...

9 CFR 3.77 - Sheltered housing facilities.

Code of Federal Regulations, 2013 CFR

2013-01-01

... from the elements at all times. They must provide protection from the sun, rain, snow, wind, and cold... trainer at all times during the contact. (Approved by the Office of Management and Budget under control...

Application of Statistical Methods of Rain Rate Estimation to Data From The TRMM Precipitation Radar

NASA Technical Reports Server (NTRS)

Meneghini, R.; Jones, J. A.; Iguchi, T.; Okamoto, K.; Liao, L.; Busalacchi, Antonio J. (Technical Monitor)

2000-01-01

The TRMM Precipitation Radar is well suited to statistical methods in that the measurements over any given region are sparsely sampled in time. Moreover, the instantaneous rain rate estimates are often of limited accuracy at high rain rates because of attenuation effects and at light rain rates because of receiver sensitivity. For the estimation of the time-averaged rain characteristics over an area both errors are relevant. By enlarging the space-time region over which the data are collected, the sampling error can be reduced. However. the bias and distortion of the estimated rain distribution generally will remain if estimates at the high and low rain rates are not corrected. In this paper we use the TRMM PR data to investigate the behavior of 2 statistical methods the purpose of which is to estimate the rain rate over large space-time domains. Examination of large-scale rain characteristics provides a useful starting point. The high correlation between the mean and standard deviation of rain rate implies that the conditional distribution of this quantity can be approximated by a one-parameter distribution. This property is used to explore the behavior of the area-time-integral (ATI) methods where fractional area above a threshold is related to the mean rain rate. In the usual application of the ATI method a correlation is established between these quantities. However, if a particular form of the rain rate distribution is assumed and if the ratio of the mean to standard deviation is known, then not only the mean but the full distribution can be extracted from a measurement of fractional area above a threshold. The second method is an extension of this idea where the distribution is estimated from data over a range of rain rates chosen in an intermediate range where the effects of attenuation and poor sensitivity can be neglected. The advantage of estimating the distribution itself rather than the mean value is that it yields the fraction of rain contributed by the light and heavy rain rates. This is useful in estimating the fraction of rainfall contributed by the rain rates that go undetected by the radar. The results at high rain rates provide a cross-check on the usual attenuation correction methods that are applied at the highest resolution of the instrument.

Soak Up the Rain

EPA Pesticide Factsheets

Soak Up the Rain promotes green infrastructure practices such as rain barrels, rain gardens, permeable pavements and green roofs to reduce stormwater runoff and prevent water pollution while bringing about a broad range of community benefits.

Comparison of Instantaneous Frequency Scaling from Rain Attenuation and Optical Disdrometer Measurements at K/Q bands

NASA Technical Reports Server (NTRS)

Nessel, James; Zemba, Michael; Luini, Lorenzo; Riva, Carlo

2015-01-01

Rain attenuation is strongly dependent on the rain rate, but also on the rain drop size distribution (DSD). Typically, models utilize an average drop size distribution, such as those developed by Laws and Parsons, or Marshall and Palmer. However, individual rain events may possess drop size distributions which could be significantly different from the average and will impact, for example, fade mitigation techniques which utilize channel performance estimates from a signal at a different frequency. Therefore, a good understanding of the characteristics and variability of the raindrop size distribution is extremely important in predicting rain attenuation and instantaneous frequency scaling parameters on an event-toevent basis. Since June 2014, NASA Glenn Research Center (GRC) and the Politecnico di Milano (POLIMI) have measured the attenuation due to rain in Milan, Italy, on the 20/40 GHz beacon signal broadcast from the Alphasat TDP#5 Aldo Paraboni Q/V-band Payload. Concomitant with these measurements are the measurements of drop size distribution and rain rate utilizing a Thies Clima laser precipitation monitor (disdrometer). In this paper, we discuss the comparison of the predicted rain attenuation at 20 and 40 GHz derived from the drop size distribution data with the measured rain attenuation. The results are compared on statistical and real-time bases. We will investigate the performance of the rain attenuation model, instantaneous frequency scaling, and the distribution of the scaling factor. Further, seasonal rain characteristics will be analysed.

The role of pH control on biohydrogen production by single stage hybrid dark- and photo-fermentation.

PubMed

Zagrodnik, R; Laniecki, M

2015-10-01

The role of pH control on biohydrogen production by co-culture of dark-fermentative Clostridium acetobutylicum and photofermentative Rhodobacter sphaeroides was studied. Single stage dark fermentation, photofermentation and hybrid co-culture systems were studied at different values of controlled and uncontrolled pH. Increasing pH during dark fermentation resulted in lower hydrogen production rate (HPR) and longer lag time for both controlled and uncontrolled conditions. However, it only slightly affected cumulative H2 volume. Results have shown that pH control at pH 7.5 increased photofermentative hydrogen production from 0.966 to 2.502 L H2/L(medium) when compared to uncontrolled process. Fixed pH value has proven to be an important control strategy also for the hybrid process and resulted in obtaining balanced co-culture of dark and photofermentative bacteria. Control of pH at 7.0 was found optimum for bacteria cooperation in the co-culture what resulted in obtaining 2.533 L H2/L(medium) and H2 yield of 6.22 mol H2/mol glucose. Copyright © 2015 Elsevier Ltd. All rights reserved.

9-year distributions of rain intensities measured in Prague and their utilization in telecommunications

NASA Astrophysics Data System (ADS)

Kvicera, V.; Grabner, M.

2012-04-01

Experimental research in the Department of Frequency Engineering of the Czech Metrology Institute (CMI) in Prague, the Czech Republic, is focused on stability of received signals on terrestrial radio and optical communication paths. Hydrometeors (rain, snow, fog, hails) can cause serious attenuation of electromagnetic waves in the frequency bands above 10 GHz and the availability performances of terrestrial radio communication systems are seriously affected by heavy hydrometeors events. The rain intensity data is usually used for the calculations of attenuation due to rain on terrestrial radio links in accordance with either the relevant ITU-R Recommendation or other methods. Therefore, our experimental research is also focused on our own meteorological measurements in the vicinity of experimental radio and optical paths. The heated tipping-bucket rain gauge with the collector area of 500 cm2 and the rain amount per tip of 0.1 mm is used at CMI for the measurements of intensities of hydrometeors. The time of tips is recorded with uncertainty of 1 second. Hydrometeors intensity data obtained from January 2003 to December 2011 (9 years of observation) was statistically processed over the individual years. All the recorded individual hydrometeor events were compared with the concurrent meteorological conditions and were carefully categorized according to the types of individual hydrometeors, i.e. rain, rain with snow, rain with hails, snow, fog, fog with rain, fog with snow, and fog with rain and snow. The obtained cumulative distributions (CDs) of intensities of individual hydrometeors over 9 years of observation will be presented and compared with the CD of intensities of all hydrometeors together. The rain amounts were examined too. The obtained rain amounts for individual years and the average rain amounts for individual months over the 9-year period will be given. The obtained CD of average 1-minute rain intensities for the average year over the 9-year period of observation was used for the calculations of CDs of attenuation due to rain on terrestrial radio paths in accordance with the relevant recommendation of the ITU-R. The examples of the calculated CDs of attenuation due to rain will be presented for radio communication links with different path lengths working in different frequency bands. The obtained CDs can be used for the assessment of availability performances of terrestrial radio communication links in the climatic region where the rain intensities were measured. The examples will be given. Ministry of Education, Youth and Sports of the Czech Republic under the Project No. OC09076 supported the described work.

EFFECTS OF SIMULATED ACIDIC RAIN APPLIED ALONE AND IN COMBINATION WITH AMBIENT RAIN ON GROWTH AND YIELD OF FIELD-GROWN SNAP BEAN

EPA Science Inventory

Field-grown snap bean plants were treated with simulated acidic rain applied either alone or in combination with ambient rain and the effects on growth and yield were determined. In plots where ambient rain was excluded, a retractable canopy was activated to shield the crop. Four...

Discussions on the Design of the Pool Landscape in the Rain Garden Construction

NASA Astrophysics Data System (ADS)

Zou, Shuzhen; Zhu, Yirong; Wei, Chaojun; Tao, Biaohong

2018-03-01

With rapid urbanization, the environmental problems are becoming increasingly prominent and diversified ecological landscape designs consequently appear with the rain garden landscape design as a typical. Based on the introduction to rain garden ecological functions and in combination with domestic and international rain garden landscape design cases, this paper discussed the rain garden pool landscape design.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qian, Yun; Gong, Daoyi; Leung, Ruby

Long-term daily precipitation data from NCDC are used to investigate the changes of light rain events from 1973-2009 over North America, Europe and Asia. Results reveal that the trend of light rain events presents a remarkably diverse feature in different regions, while an overall decrease trend can be found over the continents in northern hemisphere. In North America, most of stations show a decrease trend for light rain on the annual basis but a decrease trend can also be found for moderate and heavy rain. The opposite trends are observed over the stations in Europe and the trend of lightmore » rain is not significant when averaged for all the stations. In Asia, especially East Asia, the light rain days show an overwhelming decrease trend with high spatial coherency. Meanwhile the moderate and heavy rain events (> 10 mm/day) have increased, suggesting a remarkable shift of precipitation from light to heavy rain in East Asia. While both the warming at a global scale and increased atmospheric aerosols due to air pollution at a regional scale (e.g. East Asia) may have affected the light rain changes, it remains a challenging task to quantitatively detect and separate the cause of light rain changes in different regions.« less

Effects of wind and rain on thermal responses of humans in a mildly cold environment.

PubMed

Yamane, Motoi; Oida, Yukio; Ohnishi, Norikazu; Matsumoto, Takaaki; Kitagawa, Kaoru

2010-05-01

The purpose of the present study was to clarify the effects of wind and rain on peripheral heat loss by non-exercising minimally clothed humans in a mildly cold environment. Seven healthy young male subjects wearing only shorts rested in a standing position for 20 min at an ambient temperature of 15 degrees C under three conditions: without exposure to wind or rain (CON), with exposure to wind (3 m/s) (WIND) and with exposure to wind (3 m/s) and rain (40 mm/h) (WIND + RAIN). Mean heat loss measured using a heat flux transducer was significantly greater in the subjects exposed to WIND + RAIN compared to those exposed to CON and WIND conditions (p < 0.01). Metabolic heat production was significantly greater under WIND + RAIN than under CON and WIND (p < 0.01). Decrease in heat storage was significantly larger at WIND + RAIN compared with CON and WIND (p < 0.01). Mean skin temperature was significantly lower under WIND + RAIN than under CON and WIND conditions (p < 0.01). These results indicate that peripheral heat loss significantly increases when humans are exposed to wind and rain for a short period (20 min) under a mildly cold condition.

Comparisons of Instantaneous TRMM Ground Validation and Satellite Rain Rate Estimates at Different Spatial Scales

NASA Technical Reports Server (NTRS)

Wolff, David B.; Fisher, Brad L.

2007-01-01

This study provides a comprehensive inter-comparison of instantaneous rain rates observed by the two rain sensors aboard the TRMM satellite with ground data from two regional sites established for long-term ground validation: Kwajalein Atoll and Melbourne, Florida. The satellite rain algorithms utilize remote observations of precipitation collected by the TRMM microwave imager (TMI) and the Precipitation Radar (PR) aboard the TRMM satellite. Three standard Level I1 rain products are generated from operational applications of the TMI, PR and Combined (COM) rain algorithms using rain information collected from the TMI and the PR along the orbital track of the TRMM satellite. In the first part of the study, 0.25 x 0.25 instantaneous rain rates obtained from the TRMM 3668 product were analyzed and compared to instantaneous GV rain rates gridded at a scale of 0.5deg x 0.5. In the second part of the study, TMI, PR, COM and GV rain rates were spatio-temporally matched and averaged at the scale of TMI footprint (- 150 sq km). This study covered a six-year period 1999-2004 and consisted of over 50,000 footprints for each GV site. In the first analysis our results showed that all of the respective rain rate estimates agree well, with some exceptions. The more salient differences were associated with heavy rain events in which one or more of the algorithms failed to properly retrieve these extreme events. Also, it appears that there is a preferred mode of precipitation for TMI rain rates at or near 2 mm/hr over the ocean. This mode was noted over ocean areas of Kwajalein and Melbourne and has been observed in TRMM tropical-global ocean areas as well.

Large-scale modeling of rain fields from a rain cell deterministic model

NASA Astrophysics Data System (ADS)

FéRal, Laurent; Sauvageot, Henri; Castanet, Laurent; Lemorton, JoëL.; Cornet, FréDéRic; Leconte, Katia

2006-04-01

A methodology to simulate two-dimensional rain rate fields at large scale (1000 × 1000 km2, the scale of a satellite telecommunication beam or a terrestrial fixed broadband wireless access network) is proposed. It relies on a rain rate field cellular decomposition. At small scale (˜20 × 20 km2), the rain field is split up into its macroscopic components, the rain cells, described by the Hybrid Cell (HYCELL) cellular model. At midscale (˜150 × 150 km2), the rain field results from the conglomeration of rain cells modeled by HYCELL. To account for the rain cell spatial distribution at midscale, the latter is modeled by a doubly aggregative isotropic random walk, the optimal parameterization of which is derived from radar observations at midscale. The extension of the simulation area from the midscale to the large scale (1000 × 1000 km2) requires the modeling of the weather frontal area. The latter is first modeled by a Gaussian field with anisotropic covariance function. The Gaussian field is then turned into a binary field, giving the large-scale locations over which it is raining. This transformation requires the definition of the rain occupation rate over large-scale areas. Its probability distribution is determined from observations by the French operational radar network ARAMIS. The coupling with the rain field modeling at midscale is immediate whenever the large-scale field is split up into midscale subareas. The rain field thus generated accounts for the local CDF at each point, defining a structure spatially correlated at small scale, midscale, and large scale. It is then suggested that this approach be used by system designers to evaluate diversity gain, terrestrial path attenuation, or slant path attenuation for different azimuth and elevation angle directions.

Expression pattern of four storage xyloglucan mobilization-related genes during seedling development of the rain forest tree Hymenaea courbaril L.

PubMed

Brandão, A D; Del Bem, L E V; Vincentz, M; Buckeridge, M S

2009-01-01

During seedling establishment, cotyledons of the rain forest tree Hymenaea courbaril mobilize storage cell wall xyloglucan to sustain growth. The polysaccharide is degraded and its products are transported to growing sink tissues. Auxin from the shoot controls the level of xyloglucan hydrolytic enzymes. It is not yet known how important the expression of these genes is for the control of storage xyloglucan degradation. In this work, partial cDNAs of the genes xyloglucan transglycosylase hydrolase (HcXTH1) and beta-galactosidase (HcBGAL1), both related to xyloglucan degradation, and two other genes related to sucrose metabolism [alkaline invertase (HcAlkIN1) and sucrose synthase (HcSUS1)], were isolated. The partial sequences were characterized by comparison with sequences available in the literature, and phylogenetic trees were assembled. Gene expression was evaluated at intervals of 6 h during 24 h in cotyledons, hypocotyl, roots, and leaves, using 45-d-old plantlets. HcXTH1 and HcBGAL1 were correlated to xyloglucan degradation and responded to auxin and light, being down-regulated when transport of auxin was prevented by N-1-naphthylphthalamic acid (NPA) and stimulated by constant light. Genes related to sucrose metabolism, HcAlkIN1 and HcSUS1, responded to inhibition of auxin transport in consonance with storage mobilization in the cotyledons. A model is proposed suggesting that auxin and light are involved in the control of the expression of genes related to storage xyloglucan mobilization in seedlings of H. courbaril. It is concluded that gene expression plays a role in the control of the intercommunication system of the source-sink relationship during seeding growth, favouring its establishment in the shaded environment of the rain forest understorey.

Expression pattern of four storage xyloglucan mobilization-related genes during seedling development of the rain forest tree Hymenaea courbaril L.

PubMed Central

Brandão, A. D.; Del Bem, L. E. V.; Vincentz, M.; Buckeridge, M. S.

2009-01-01

During seedling establishment, cotyledons of the rain forest tree Hymenaea courbaril mobilize storage cell wall xyloglucan to sustain growth. The polysaccharide is degraded and its products are transported to growing sink tissues. Auxin from the shoot controls the level of xyloglucan hydrolytic enzymes. It is not yet known how important the expression of these genes is for the control of storage xyloglucan degradation. In this work, partial cDNAs of the genes xyloglucan transglycosylase hydrolase (HcXTH1) and β-galactosidase (HcBGAL1), both related to xyloglucan degradation, and two other genes related to sucrose metabolism [alkaline invertase (HcAlkIN1) and sucrose synthase (HcSUS1)], were isolated. The partial sequences were characterized by comparison with sequences available in the literature, and phylogenetic trees were assembled. Gene expression was evaluated at intervals of 6 h during 24 h in cotyledons, hypocotyl, roots, and leaves, using 45-d-old plantlets. HcXTH1 and HcBGAL1 were correlated to xyloglucan degradation and responded to auxin and light, being down-regulated when transport of auxin was prevented by N-1-naphthylphthalamic acid (NPA) and stimulated by constant light. Genes related to sucrose metabolism, HcAlkIN1 and HcSUS1, responded to inhibition of auxin transport in consonance with storage mobilization in the cotyledons. A model is proposed suggesting that auxin and light are involved in the control of the expression of genes related to storage xyloglucan mobilization in seedlings of H. courbaril. It is concluded that gene expression plays a role in the control of the intercommunication system of the source–sink relationship during seeding growth, favouring its establishment in the shaded environment of the rain forest understorey. PMID:19221141

Research on the effect of rainfall flood regulation and control of wetland park based on SWMM model—a case study of wetland park in Yuanjia village, Qishan county, Shaanxi province

NASA Astrophysics Data System (ADS)

Xu, Da; Liu, Yijie

2018-02-01

Taking the wetland park of Yuan Village in Qishan County of Shaanxi Province as the research object, this paper makes a reasonable generalization of the study area, and establishes two models of low impact development (LID) and traditional development in the park. Meantime, rainwater in the surrounding built up area is introduced to into the park for digestion. SWMM model is used to simulate the variation of the total runoff, peak flow and peak time of two development models in Wetland Park under one-hour rainfall at different recurrence periods.The runoff control effect in each single LID facility in the one-hour rainfall once during five years in the built-up area is simulated. The simulation results show that the SWMM model can not only quantify the runoff reduction effect of different LID facilities, but also provide theoretical basis and data support for the urban rainfall flood problem. LID facilities have effects on runoff reduction and peak delay. However, the combined LID facility has obvious advantages for the peak time delay and peak flow control. A single LID facility is more efficient in a single runoff volume control. The order of runoff reduction by various LID facilities is as follows: Rain garden>combined LID facility> vegetative swale> bio-retention cell > permeable pavement. The order of peak time delay effect by the LID facilities is as follows: combined LID facility> Rain garden> vegetative swale> bio-retention cell > permeable pavement. The order of peak flow reduction efficiency by various LID facilities is: combined LID facility> Rain garden> bio-retention cell > vegetative swale> permeable pavement.

SSM/I Rain Retrievals Within a Unified All-Weather Ocean Algorithm

NASA Technical Reports Server (NTRS)

Wentz, Frank J.; Spencer, Roy W.

1996-01-01

A new method for the physical retrieval of rain rates from satellite microwave radiometers is presented and compared to two other rainfall climatologies derived from satellites. The method is part of a unified ocean parameter retrieval algorithm that is based on the fundamental principles of radiative transfer. The algorithm simultaneously finds near-surface wind speed W, columnar water vapor V, columnar cloud liquid water L, rain rate R, and effective radiating temperature T(sub U) for the upwelling radiation. The performance of the algorithm in the absence of rain is discussed in Wentz, and this paper focuses on the rain component of the algorithm. A particular strength of the unified algorithm is its ability to 'orthogonalize' the retrievals so that there is minimum cross-talk between the retrieved parameters. For example, comparisons of the retrieved water vapor with radiosonde observations show that there is very little correlation between the water vapor retrieval error and rain rate. For rain rates from 1 to 15 mm/h, the rms difference between the retrieved water vapor and the radiosonde value is 5 mm. A novel feature of the rain retrieval method is a beamfilling correction that is based upon the ratio of the retrieved liquid water absorption coefficients at 37 GHz and 19.35 GHz. This ratio decreases by about 40% when heavy and light rain co-exist within the SSM/I footprint as compared to the case of uniform rain. This correction has the effect of increasing the rain rate when the spectral ratio of the absorption coefficients is small. Even with this beamfilling correction, tropical rainfall is still unrealistically low when the freezing level in the tropics (approx. 5 km) is used to specify the rain layer thickness. We restore realism by reducing the assumed averaged tropical rain layer thickness to 3 km, thereby accounting for the existence of warm rain processes in which the rain layer does not extend to the freezing level. Global rain rates are produced for the 1991 through 1994 period from observations taken by microwave radiometers (SSM/I) that are aboard two polar-orbiting satellites. We find that approximately 6% of the SSM/I observations detect measurable rain rates (R greater than 0.2 mm/h). Zonal averages of the rain rates show the peak at the intertropical convergence zone (ITCZ) is quite narrow in meridional extent and varies from about 7 mm/day in the winter to a maximum 11 mm/day in the summer. Very low precipitation rates (less than 0.3 mm/day) are observed in those areas of subsidence influenced by the large semipermanent anticyclones. In general, these features are similar to those reported in previously published rain climatologies. However, significant differences do exists between our rain rates and those produced by Spencer. These differences seem to be related to non-precipitating cloud water.

Rain attenuation studies from radiometric and rain DSD measurements at two tropical locations

NASA Astrophysics Data System (ADS)

Halder, Tuhina; Adhikari, Arpita; Maitra, Animesh

2018-05-01

Efficient use of satellite communication in tropical regions demands proper characterization of rain attenuation, particularly, in view of the available popular propagation models which are mostly based on temperate climatic data. Thus rain attenuations at frequencies 22.234, 23.834 and 31.4/30 GHz over two tropical locations Kolkata (22.57°N, 88.36°E, India) and Belem (1.45°S, 48.49° W, Brazil), have been estimated for the year 2010 and 2011, respectively. The estimation has been done utilizing ground-based disdrometer observations and radiometric measurements over Earth-space path. The results show that rain attenuation estimations from radiometric data are reliable only at low rain rates (<30 mm/h). However, the rain attenuation estimations from disdrometer measurements show good agreement with the ITU-R model, even at high rain rates (upto100 mm/h). Despite having significant variability in terms of drop size distribution (DSD), the attenuation values calculated from DSD data (disdrometer measurements) at Kolkata and Belem differ a little for the rain rates below 30 mm/h. However, the attenuation values, obtained from radiometric measurements at the two places, show significant deviations ranging from 0.54 dB to 3.2 dB up to a rain rate of 30 mm/h, on account of different rain heights, mean atmospheric temperatures and climatology of the two locations.

Performance analysis of rain attenuation on earth-to-satellite microwave links design in Libya

NASA Astrophysics Data System (ADS)

Rafiqul Islam, Md; Hussein Budalal, Asma Ali; Habaebi, Mohamed H.; Badron, Khairayu; Fadzil Ismail, Ahmad

2017-11-01

Performances of earth-to-satellite microwave links operating in Ku, Ka, and V-bands are degraded by the environment and strongly attenuated by rain. Rain attenuation is the most significant consideration and challenge to design a reliable earth-to-satellite microwave links for these frequency bands. Hence, it is essential for satellite link designer to take into account rain fade margin accurately before system implementation. Rain rate is the main measured parameter to predict of rain attenuation. Rainfall statistical data measured and recorded in Libya for the period of 30 years are collected from 5 locations. The prediction methods require one minute integration time rain intensity. Therefore, collected data were analyzed and processed to convert into one-minute rain rate cumulative distribution in Libya. The model proposed by ITU-R is used to predict and investigate rain fade based on converted 1-minute rain rate data. Rain fade predicted at two locations are used for performance analysis in terms of link spectral efficiency and throughput. V-band downlink shows that 99.99% availability is possible in all the Southern part stations in Libya at 0.29 bps/Hz spectral efficiency and 20.74 Mbps throughput when 72 MHz transponder band width is used which is not feasible in Northern part. Results of this paper will be a very useful resource to design highly reliable earth-to-satellite communication links in Libya.

Characterization of tropical precipitation using drop size distribution and rain rate-radar reflectivity relation

NASA Astrophysics Data System (ADS)

Das, Saurabh; Maitra, Animesh

2018-04-01

Characterization of precipitation is important for proper interpretation of rain information from remotely sensed data. Rain attenuation and radar reflectivity (Z) depend directly on the drop size distribution (DSD). The relation between radar reflectivity/rain attenuation and rain rate (R) varies widely depending upon the origin, topography, and drop evolution mechanism and needs further understanding of the precipitation characteristics. The present work utilizes 2 years of concurrent measurements of DSD using a ground-based disdrometer at five diverse climatic conditions in Indian subcontinent and explores the possibility of rain classification based on microphysical characteristics of precipitation. It is observed that both gamma and lognormal distributions are performing almost similar for Indian region with a marginally better performance by one model than other depending upon the locations. It has also been found that shape-slope relationship of gamma distribution can be a good indicator of rain type. The Z-R relation, Z = ARb, is found to vary widely for different precipitation systems, with convective rain that has higher values of A than the stratiform rain for two locations, whereas the reverse is observed for the rest of the three locations. Further, the results indicate that the majority of rainfall (>50%) in Indian region is due to the convective rain although the occurrence time of convective rain is low (<10%).

Acid Rain: A Teaching Focus for the Intermediate Grades.

ERIC Educational Resources Information Center

Adams, Renee B.; Adams, Neil D.

1992-01-01

The study of acid rain provides ample opportunities for active, interdisciplinary learning. This article describes 12 hands-on activities designed to expand students' understanding of acid rain. Background information on acid rain is included. (LB)

Life in Tropical Rain Forests.

ERIC Educational Resources Information Center

NatureScope, 1989

1989-01-01

Discusses the diversity of rain forest life, the adaptations of rain forest plants and animals, and ways these organisms interact. Includes activities on canopy critters with a copyable sheet, rain forest revue, design a plant, and jungle sleuths. (RT)

A rain pixel recovery algorithm for videos with highly dynamic scenes.

PubMed

Jie Chen; Lap-Pui Chau

2014-03-01

Rain removal is a very useful and important technique in applications such as security surveillance and movie editing. Several rain removal algorithms have been proposed these years, where photometric, chromatic, and probabilistic properties of the rain have been exploited to detect and remove the rainy effect. Current methods generally work well with light rain and relatively static scenes, when dealing with heavier rainfall in dynamic scenes, these methods give very poor visual results. The proposed algorithm is based on motion segmentation of dynamic scene. After applying photometric and chromatic constraints for rain detection, rain removal filters are applied on pixels such that their dynamic property as well as motion occlusion clue are considered; both spatial and temporal informations are then adaptively exploited during rain pixel recovery. Results show that the proposed algorithm has a much better performance for rainy scenes with large motion than existing algorithms.

Effect of rain on Ku-band scatterometer wind measurements

NASA Technical Reports Server (NTRS)

Spencer, Michael; Shimada, Masanobu

1991-01-01

The impact of precipitation on scatterometer wind measurements is investigated. A model is developed which includes the effects of rain attenuation, rain backscatter, and storm horizontal structure. Rain attenuation is found to be the dominant error source at low radar incidence angles and high wind speeds. Volume backscatter from the rain-loaded atmosphere, however, is found to dominate for high incidence angles and low wind speeds.

Rain Splash Dispersal of Gibberella zeae Within Wheat Canopies in Ohio.

PubMed

Paul, P A; El-Allaf, S M; Lipps, P E; Madden, L V

2004-12-01

ABSTRACT Rain splash dispersal of Gibberella zeae, causal agent of Fusarium head blight of wheat, was investigated in field studies in Ohio between 2001 and 2003. Samplers placed at 0, 30, and 100 cm above the soil surface were used to collect rain splash in wheat fields with maize residue on the surface and fields with G. zeae-infested maize kernels. Rain splash was collected during separate rain episodes throughout the wheat-growing seasons. Aliquots of splashed rain were transferred to petri dishes containing Komada's selective medium, and G. zeae was identified based on colony and spore morphology. Dispersed spores were measured in CFU/ml. Intensity of splashed rain was highest at 100 cm and ranged from 0.2 to 10.2 mm h(-1), depending on incident rain intensity and sampler height. Spores were recovered from splash samples at all heights in both locations for all sampled rain events. Both macroconidia and ascospores were found based on microscopic examination of random samples of splashed rain. Spore density and spore flux density per rain episode ranged from 0.4 to 40.9 CFU cm(-2) and 0.4 to 84.8 CFU cm(-2) h(-1), respectively. Spore flux density was higher in fields with G. zeae-infested maize kernels than in fields with maize debris, and generally was higher at 0 and 30 cm than at 100 cm at both locations. However, on average, spore flux density was only 30% lower at 100 cm (height of wheat spikes) than at the other heights. The log of spore flux density was linearly related to the log of splashed rain intensity and the log of incident rain intensity. The regression slopes were not significantly affected by year, location, height, and their interactions, but the intercepts were significantly affected by both sampler height and location. Thus, our results show that spores of G. zeae were consistently splash dispersed to spike heights within wheat canopies, and splashed rain intensity and spore flux density could be predicted based on incident rain intensity in order to estimate inoculum dispersal within the wheat canopy.

Radar derived spatial statistics of summer rain. Volume 3: Appendices

NASA Technical Reports Server (NTRS)

Ronnenburg, C.; Bassnett, A.; Knapp, H.; Vann, W. A.

1975-01-01

A collection of selected important memoranda written during the course of the experiment. It contains detailed information on: (1) frequency diversity, (2) radar controller and radar video processor, (3) SPANDAR calibration, and (4) meteorological summaries.

Strategies for Involvement in Wildlife Issues.

ERIC Educational Resources Information Center

Kennedy, Carolyn L.; Nye, Donna I.

1984-01-01

Highlights a workshop with children focusing on the treatment of controversial issues and guidelines typically provided by school districts or organizations. Activities designed to stimulate discussion on three issues (endangered species, acid rain, and predator control) are included. (BC)

Green infrastructure monitoring in Camden, NJ

EPA Science Inventory

The Camden County Municipal Utilities Authority (CCMUA) installed green infrastructure Stormwater Control Measures (SCMs) at multiple locations around the city of Camden, NJ. The SCMs include raised downspout planter boxes, rain gardens, and cisterns. The cisterns capture water ...

Quality control algorithms for rainfall measurements

NASA Astrophysics Data System (ADS)

Golz, Claudia; Einfalt, Thomas; Gabella, Marco; Germann, Urs

2005-09-01

One of the basic requirements for a scientific use of rain data from raingauges, ground and space radars is data quality control. Rain data could be used more intensively in many fields of activity (meteorology, hydrology, etc.), if the achievable data quality could be improved. This depends on the available data quality delivered by the measuring devices and the data quality enhancement procedures. To get an overview of the existing algorithms a literature review and literature pool have been produced. The diverse algorithms have been evaluated to meet VOLTAIRE objectives and sorted in different groups. To test the chosen algorithms an algorithm pool has been established, where the software is collected. A large part of this work presented here is implemented in the scope of the EU-project VOLTAIRE ( Validati on of mu ltisensors precipit ation fields and numerical modeling in Mediter ran ean test sites).