Geochemical Controls on the Partitioning and Hydrological Transport of Metals in a Human Impacted, Non-Acidic, River System

NASA Astrophysics Data System (ADS)

Thorslund, J.; Jarsjo, J.; Wällstedt, T.; Morth, C. M.; Lychagin, M.; Chalov, S.

2014-12-01

The knowledge of coupled processes controlling the spreading and fate of metals in non-acidic river systems is currently much more limited than the knowledge of metal behavior under acidic conditions (e.g., in acid mine drainage systems). Critical geochemical controls governing metal speciation may thus differ substantially between acidic and non-acidic hydrological systems. We here aim at expanding the knowledge of metals in non-acidic river systems, by considering a high pH river, influenced by mining by the largest gold mining area in the Mongolian part of the transboundary Lake Baikal drainage basin. The combined impact of geochemical and hydrological processes is investigated, to be able to understand the solubility of various heavy metals, their partitioning between particulate and dissolved phase and its impact on overall transport. We show, through site specific measurements and a geochemical modelling approach, that the combined effects of precipitation of ferrihydrite and gibbsite and associated sorption complexes of several metals can explain the high impact of suspended transport relative to total transport often seen under non-acidic conditions. Our results also identifies the phosphate mineral Hydroxyapatite as a potential key sorption site for many metals, which has both site specific and general relevance for metal partitioning under non-acidic conditions. However, an adsorption database, which is currently unavailable for hydroxyapatite, needs to be developed for appropriate sorption quantification. Furthermore, Cd, Fe, Pb and Zn were particularly sensitive to increasing DOC concentrations, which increased the solubility of these metals due to metal-organic complexation. Modeling the sensitivity to changes in geochemical parameters showed that decreasing pH and increasing DOC concentrations in downstream regions would increase the dissolution and hence the toxicity and bioavailability of many pollutants of concern in the downstream ecosystem. In general, this study suggests that in non-acidic hydrological systems, both seasonality of DOC concentrations (which could vary by several 100%), changing DOC concentrations (resulting from climate and land use changes) and potential phosphate solids can majorly influence on the spreading and toxicity of several metals.

An integrated geophysical and geochemical exploration of critical zone weathering on opposing montane hillslope

NASA Astrophysics Data System (ADS)

Singha, K.; Navarre-Sitchler, A.; Bandler, A.; Pommer, R. E.; Novitsky, C. G.; Holbrook, S.; Moore, J.

2017-12-01

Quantifying coupled geochemical and hydrological properties and processes that operate in the critical zone is key to predicting rock weathering and subsequent transmission and storage of water in the shallow subsurface. Geophysical data have the potential to elucidate geochemical and hydrologic processes across landscapes over large spatial scales that are difficult to achieve with point measurements alone. Here, we explore the connections between weathering and fracturing, as measured from integrated geochemical and geophysical borehole data and seismic velocities on north- and south-facing aspects within one watershed in the Boulder Creek Critical Zone Observatory. We drilled eight boreholes up to 13 m deep on north- and south-facing aspects within Upper Gordon Gulch, and surface seismic refraction data were collected near these wells to explore depths of regolith and bedrock, as well as anisotropic characteristics of the subsurface material due to fracturing. Optical televiewer data were collected in these wells to infer the dominant direction of fracturing and fracture density in the near surface to corroborate with the seismic data. Geochemical samples were collected from four of these wells and a series of shallow soil pits for bulk chemistry, clay fraction, and exchangeable cation concentrations to identify depths of chemically altered saprolite. Seismic data show that depth to unweathered bedrock, as defined by p-wave seismic velocity, is slightly thicker on the north-facing slopes. Geochemical data suggest that the depth to the base of saprolite ranges from 3-5 m, consistent with a p-wave velocity value of 1200 m/s. Based on magnitude and anisotropy of p-wave velocities together with optical televiewer data, regolith on north-facing slopes is thought to be more fractured than south-facing slopes, while geochemical data indicate that position on the landscape is another important characteristic in determining depths of weathering. We explore the importance of fracture opening in controlling both saprolite and regolith thickness within this watershed.

Is rhizosphere remediation sufficient for sustainable revegetation of mine tailings?

PubMed Central

Huang, Longbin; Baumgartl, Thomas; Mulligan, David

2012-01-01

Background Revegetation of mine tailings (fine-grained waste material) starts with the reconstruction of root zones, consisting of a rhizosphere horizon (mostly topsoil and/or amended tailings) and the support horizon beneath (i.e. equivalent to subsoil – mostly tailings), which must be physically and hydro-geochemically stable. This review aims to discuss key processes involved in the development of functional root zones within the context of direct revegetation of tailings and introduces a conceptual process of rehabilitating structure and function in the root zones based on a state transition model. Scope Field studies on the revegetation of tailings (from processing base metal ore and bauxite residues) are reviewed. Particular focus is given to tailings' properties that limit remediation effectiveness. Aspects of root zone reconstruction and vegetation responses are also discussed. Conclusions When reconstructing a root zone system, it is critical to restore physical structure and hydraulic functions across the whole root zone system. Only effective and holistically restored systems can control hydro-geochemical mobility of acutely and chronically toxic factors from the underlying horizon and maintain hydro-geochemical stability in the rhizosphere. Thereafter, soil biological capacity and ecological linkages (i.e. carbon and nutrient cycling) may be rehabilitated to integrate the root zones with revegetated plant communities into sustainable plant ecosystems. A conceptual framework of system transitions between the critical states of root zone development has been proposed. This will illustrate the rehabilitation process in root zone reconstruction and development for direct revegetation with sustainable plant communities. Sustainable phytostabilization of tailings requires the systematic consideration of hydro-geochemical interactions between the rhizosphere and the underlying supporting horizon. It further requires effective remediation strategies to develop hydro-geochemically stable and biologically functional root zones, which can facilitate the recovery of the microbial community and ecological linkages with revegetated plant communities. PMID:22648878

Multivariate analysis of the heterogeneous geochemical processes controlling arsenic enrichment in a shallow groundwater system.

PubMed

Huang, Shuangbing; Liu, Changrong; Wang, Yanxin; Zhan, Hongbin

2014-01-01

The effects of various geochemical processes on arsenic enrichment in a high-arsenic aquifer at Jianghan Plain in Central China were investigated using multivariate models developed from combined adaptive neuro-fuzzy inference system (ANFIS) and multiple linear regression (MLR). The results indicated that the optimum variable group for the AFNIS model consisted of bicarbonate, ammonium, phosphorus, iron, manganese, fluorescence index, pH, and siderite saturation. These data suggest that reductive dissolution of iron/manganese oxides, phosphate-competitive adsorption, pH-dependent desorption, and siderite precipitation could integrally affect arsenic concentration. Analysis of the MLR models indicated that reductive dissolution of iron(III) was primarily responsible for arsenic mobilization in groundwaters with low arsenic concentration. By contrast, for groundwaters with high arsenic concentration (i.e., > 170 μg/L), reductive dissolution of iron oxides approached a dynamic equilibrium. The desorption effects from phosphate-competitive adsorption and the increase in pH exhibited arsenic enrichment superior to that caused by iron(III) reductive dissolution as the groundwater chemistry evolved. The inhibition effect of siderite precipitation on arsenic mobilization was expected to exist in groundwater that was highly saturated with siderite. The results suggest an evolutionary dominance of specific geochemical process over other factors controlling arsenic concentration, which presented a heterogeneous distribution in aquifers. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of Environmental Science and Health, Part A, to view the supplemental file.

Generation of Acid Mine Lakes Associated with Abandoned Coal Mines in Northwest Turkey.

PubMed

Sanliyuksel Yucel, Deniz; Balci, Nurgul; Baba, Alper

2016-05-01

A total of five acid mine lakes (AMLs) located in northwest Turkey were investigated using combined isotope, molecular, and geochemical techniques to identify geochemical processes controlling and promoting acid formation. All of the investigated lakes showed typical characteristics of an AML with low pH (2.59-3.79) and high electrical conductivity values (1040-6430 μS/cm), in addition to high sulfate (594-5370 mg/l) and metal (aluminum [Al], iron [Fe], manganese [Mn], nickel [Ni], and zinc [Zn]) concentrations. Geochemical and isotope results showed that the acid-generation mechanism and source of sulfate in the lakes can change and depends on the age of the lakes. In the relatively older lakes (AMLs 1 through 3), biogeochemical Fe cycles seem to be the dominant process controlling metal concentration and pH of the water unlike in the younger lakes (AMLs 4 and 5). Bacterial species determined in an older lake (AML 2) indicate that biological oxidation and reduction of Fe and S are the dominant processes in the lakes. Furthermore, O and S isotopes of sulfate indicate that sulfate in the older mine lakes may be a product of much more complex oxidation/dissolution reactions. However, the major source of sulfate in the younger mine lakes is in situ pyrite oxidation catalyzed by Fe(III) produced by way of oxidation of Fe(II). Consistent with this, insignificant fractionation between δ(34) [Formula: see text] and δ(34) [Formula: see text] values indicated that the oxidation of pyrite, along with dissolution and precipitation reactions of Fe(III) minerals, is the main reason for acid formation in the region. Overall, the results showed that acid generation during early stage formation of an AML associated with pyrite-rich mine waste is primarily controlled by the oxidation of pyrite with Fe cycles becoming the dominant processes regulating pH and metal cycles in the later stages of mine lake development.

Controls of streamflow generation in small catchments across the snow-rain transition in the southern Sierra Nevada, California

Treesearch

Fengjing Liu; Carolyn Hunsaker; Roger C. Bales

2012-01-01

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snowdominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca2+...

Geochemical patterns and microbial contribution to iron plaque formation in the rice plant rhizosphere

NASA Astrophysics Data System (ADS)

Maisch, Markus; Murata, Chihiro; Unger, Julia; Kappler, Andreas; Schmidt, Caroline

2015-04-01

Rice is the major food source for more than half of the world population and 80 percent of the worldwide rice cultivation is performed on water logged paddy soils. The establishment of reducing conditions in the soil and across the soil-water interface not only stimulates the microbial production and release of the greenhouse gas methane. These settings also create optimal conditions for microbial iron(III) reduction and therefore saturate the system with reduced ferrous iron. Through the reduction and dissolution of ferric minerals that are characterized by their high surface activity, sorbed nutrients and contaminants (e.g. arsenic) will be mobilized and are thus available for uptake by plants. Rice plants have evolved a strategy to release oxygen from their roots in order to prevent iron toxification in highly ferrous environments. The release of oxygen to the reduced paddy soil causes ferric iron plaque formation on the rice roots and finally increases the sorption capacity for toxic metals. To this date the geochemical and microbiological processes that control the formation of iron plaque are not deciphered. It has been hypothesized that iron(II)-oxidizing bacteria play a potential role in the iron(III) mineral formation along the roots. However, not much is known about the actual processes, mineral products, and geochemical gradients that establish within the rhizosphere. In the present study we have developed a growth set-up that allows the co-cultivation of rice plants and iron(II)-oxidizing bacteria, as well as the visual observation and in situ measurement of geochemical parameters. Oxygen and dissolved iron(II) gradients have been measured using microelectrodes and show geochemical hot spots that offer optimal growth conditions for microaerophilic iron(II) oxidizers. First mineral identification attempts of iron plaque have been performed using Mössbauer spectroscopy and microscopy. The obtained results on mineraology and crystallinity have been compared to mineralogical data from purely biotic (microaerophilic) and abiotic iron mineral formation processes.

Geochemical distinctions between igneous carbonate, calcite cements, and limestone xenoliths (Polino carbonatite, Italy): spatially resolved LAICPMS analyses

NASA Astrophysics Data System (ADS)

Rosatelli, G.; Wall, F.; Stoppa, F.; Brilli, M.

2010-11-01

Petrography-controlled laser ablation inductively coupled plasma mass spectrometry (LAICPMS) analyses of carbonate in fresh shallow level sub-volcanic Polino monticellite calcio-carbonatite tuffisite have been performed to assess the geochemical differences between fresh igneous, epigenetic carbonates and sedimentary accidental fragments. Igneous calcite has consistently high LREE/HREE ratios (La/Yb N , 15-130) due to high LREE (ΣLREE, 425-1,269 ppm). Secondary calcite cements are characterized by progressively lower and more variable trace element contents, with lower LREE/HREE ratios. A distinguishing geochemical feature is progressively increasing negative Ce anomalies observed through coarse secondary calcite that can be related to the surface environment processes. The limestone accidental fragments in the tuffisite have trace element contents almost two orders of magnitude lower than igneous carbonate and low LREE (ΣLREE < 9.5 ppm) with low LREE/HREE fractionation (La/Yb N ratios < 18). The stable isotope composition of different carbonate types is consistent with their formation in different environments. The tuffisitization processes during diatreme formation under high CO2-OH fugacity conditions may account for the differences noted in the igneous carbonates.

Hydrologic functioning of the deep Critical Zone and contributions to streamflow in a high elevation catchment: testing of multiple conceptual models

NASA Astrophysics Data System (ADS)

Dwivedi, R.; Meixner, T.; McIntosh, J. C.; Ferre, T. P. A.; Eastoe, C. J.; Minor, R. L.; Barron-Gafford, G.; Chorover, J.

2017-12-01

The composition of natural mountainous waters maintains important control over the water quality available to downstream users. Furthermore, the geochemical constituents of stream water in the mountainous catchments represent the result of the spatial and temporal evolution of critical zone structure and processes. A key problem is that high elevation catchments involve rugged terrain and are subject to extreme climate and landscape gradients; therefore, high density or high spatial resolution hydro-geochemical observations are rare. Despite such difficulties, the Santa Catalina Mountains Critical Zone Observatory (SCM-CZO), Tucson, AZ, generates long-term hydrogeochemical data for understanding not only hydrological processes and their seasonal characters, but also the geochemical impacts of such processes on streamflow chemical composition. Using existing instrumentation and hydrogeochemical observations from the last 9+ years (2009 through 2016 and an initial part of 2017), we employed a multi-tracer approach along with principal component analysis to identify water sources and their seasonal character. We used our results to inform hydrological process understanding (flow paths, residence times, and water sources) for our study site. Our results indicate that soil water is the largest contributor to streamflow, which is ephemeral in nature. Although a 3-dimensional mixing space involving precipitation, soil water, interflow, and deep groundwater end-members could explain most of the streamflow chemistry, geochemical complexity was observed to grow with catchment storage. In terms of processes and their seasonal character, we found soil water and interflow were the primary end-member contributors to streamflow in all seasons. Deep groundwater only contributes to streamflow at high catchment storage conditions, but it provides major ions such as Na, Mg, and Ca that are lacking in other water types. In this way, our results indicate that any future efforts aimed at explaining concentration-discharge behavior of our field site should consider at least three-dimensional mixing space or 4 end-members.

An array processing system for lunar geochemical and geophysical data

NASA Technical Reports Server (NTRS)

Eliason, E. M.; Soderblom, L. A.

1977-01-01

A computerized array processing system has been developed to reduce, analyze, display, and correlate a large number of orbital and earth-based geochemical, geophysical, and geological measurements of the moon on a global scale. The system supports the activities of a consortium of about 30 lunar scientists involved in data synthesis studies. The system was modeled after standard digital image-processing techniques but differs in that processing is performed with floating point precision rather than integer precision. Because of flexibility in floating-point image processing, a series of techniques that are impossible or cumbersome in conventional integer processing were developed to perform optimum interpolation and smoothing of data. Recently color maps of about 25 lunar geophysical and geochemical variables have been generated.

Development and Application of a Paleomagnetic/Geochemical Method for Constraining the Timing of Burial Diagenetic and Fluid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmore, Richard D.; Engel, Michael H.

2005-03-10

Studies of diagenesis caused by fluid migration or other events are commonly hindered by a lack of temporal control. Our results to date demonstrate that a paleomagnetic/geochemical approach can be used to date fluid migration as well as burial diagenetic events. Our principal working hypothesis is that burial diagenetic processes (e.g., maturation of organic-rich sediments and clay diagenesis) and the migration of fluids can trigger the authigenesis of magnetic mineral phases. The ages of these events can be constrained by comparing chemical remanent magnetizations (CRMs) to independently established Apparent Polar Wander Paths. While geochemical (e.g. stable isotope and organic analyses)more » and petrographic studies provide important clues for establishing these relationships, the ultimate test of this hypothesis requires the application of independent dating methods to verify the paleomagnetic ages. Towards this end, we have used K-Ar dating of illitization as an alternative method for constraining the ages of magnetic mineral phases in our field areas.« less

Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

USGS Publications Warehouse

Klassen, R.A.

2009-01-01

As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, 1996-2006

USGS Publications Warehouse

Musgrove, MaryLynn; Fahlquist, Lynne; Houston, Natalie A.; Lindgren, Richard J.; Ging, Patricia B.

2010-01-01

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Chemical characterisation of meltwater draining from Gangotri Glacier, Garhwal Himalaya, India

NASA Astrophysics Data System (ADS)

Singh, Virendra Bahadur; Ramanathan, Al; Pottakkal, Jose George; Sharma, Parmanand; Linda, Anurag; Azam, Mohd Farooq; Chatterjee, C.

2012-06-01

A detailed analytical study of major cations (Ca2 + , Mg2 + , Na + , K + ) and anions (SO4^{2-}, HCO3-, Cl - , NO3-) of meltwater draining from Gangotri Glacier was carried out to understand major ion chemistry and to get an insight into geochemical weathering processes controlling hydrochemistry of the glacier. In the meltwater, the abundance order of cations and anions varied as follows: Ca2 + > Mg2 + > K + > Na + and SO4^{2-} > HCO3- > Cl - > NO3-, respectively. Calcium and magnesium are dominant cations while sulphate and bicarbonate are dominant anions. Weathering of rocks is the dominant mechanism controlling the hydrochemistry of drainage basin. The relative high contribution of (Ca+Mg) to the total cations (TZ + ), high (Ca+Mg)/(Na+K) ratio (2.63) and low (Na+K)/TZ + ratio (0.29) indicate the dominance of carbonate weathering as a major source for dissolved ions in the glacier meltwater. Sulphide oxidation and carbonation are the main proton supplying geochemical reactions controlling the rock weathering in the study area. Statistical analysis was done to identify various factors controlling the dissolved ionic strength of Gangotri Glacier meltwater.

Contaminant source identification using semi-supervised machine learning

NASA Astrophysics Data System (ADS)

Vesselinov, Velimir V.; Alexandrov, Boian S.; O'Malley, Daniel

2018-05-01

Identification of the original groundwater types present in geochemical mixtures observed in an aquifer is a challenging but very important task. Frequently, some of the groundwater types are related to different infiltration and/or contamination sources associated with various geochemical signatures and origins. The characterization of groundwater mixing processes typically requires solving complex inverse models representing groundwater flow and geochemical transport in the aquifer, where the inverse analysis accounts for available site data. Usually, the model is calibrated against the available data characterizing the spatial and temporal distribution of the observed geochemical types. Numerous different geochemical constituents and processes may need to be simulated in these models which further complicates the analyses. In this paper, we propose a new contaminant source identification approach that performs decomposition of the observation mixtures based on Non-negative Matrix Factorization (NMF) method for Blind Source Separation (BSS), coupled with a custom semi-supervised clustering algorithm. Our methodology, called NMFk, is capable of identifying (a) the unknown number of groundwater types and (b) the original geochemical concentration of the contaminant sources from measured geochemical mixtures with unknown mixing ratios without any additional site information. NMFk is tested on synthetic and real-world site data. The NMFk algorithm works with geochemical data represented in the form of concentrations, ratios (of two constituents; for example, isotope ratios), and delta notations (standard normalized stable isotope ratios).

Contaminant source identification using semi-supervised machine learning

DOE PAGES

Vesselinov, Velimir Valentinov; Alexandrov, Boian S.; O’Malley, Dan

2017-11-08

Identification of the original groundwater types present in geochemical mixtures observed in an aquifer is a challenging but very important task. Frequently, some of the groundwater types are related to different infiltration and/or contamination sources associated with various geochemical signatures and origins. The characterization of groundwater mixing processes typically requires solving complex inverse models representing groundwater flow and geochemical transport in the aquifer, where the inverse analysis accounts for available site data. Usually, the model is calibrated against the available data characterizing the spatial and temporal distribution of the observed geochemical types. Numerous different geochemical constituents and processes may needmore » to be simulated in these models which further complicates the analyses. In this paper, we propose a new contaminant source identification approach that performs decomposition of the observation mixtures based on Non-negative Matrix Factorization (NMF) method for Blind Source Separation (BSS), coupled with a custom semi-supervised clustering algorithm. Our methodology, called NMFk, is capable of identifying (a) the unknown number of groundwater types and (b) the original geochemical concentration of the contaminant sources from measured geochemical mixtures with unknown mixing ratios without any additional site information. NMFk is tested on synthetic and real-world site data. Finally, the NMFk algorithm works with geochemical data represented in the form of concentrations, ratios (of two constituents; for example, isotope ratios), and delta notations (standard normalized stable isotope ratios).« less

Contaminant source identification using semi-supervised machine learning

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vesselinov, Velimir Valentinov; Alexandrov, Boian S.; O’Malley, Dan

Identification of the original groundwater types present in geochemical mixtures observed in an aquifer is a challenging but very important task. Frequently, some of the groundwater types are related to different infiltration and/or contamination sources associated with various geochemical signatures and origins. The characterization of groundwater mixing processes typically requires solving complex inverse models representing groundwater flow and geochemical transport in the aquifer, where the inverse analysis accounts for available site data. Usually, the model is calibrated against the available data characterizing the spatial and temporal distribution of the observed geochemical types. Numerous different geochemical constituents and processes may needmore » to be simulated in these models which further complicates the analyses. In this paper, we propose a new contaminant source identification approach that performs decomposition of the observation mixtures based on Non-negative Matrix Factorization (NMF) method for Blind Source Separation (BSS), coupled with a custom semi-supervised clustering algorithm. Our methodology, called NMFk, is capable of identifying (a) the unknown number of groundwater types and (b) the original geochemical concentration of the contaminant sources from measured geochemical mixtures with unknown mixing ratios without any additional site information. NMFk is tested on synthetic and real-world site data. Finally, the NMFk algorithm works with geochemical data represented in the form of concentrations, ratios (of two constituents; for example, isotope ratios), and delta notations (standard normalized stable isotope ratios).« less

Geochemistry and the Understanding of Groundwater Systems

NASA Astrophysics Data System (ADS)

Glynn, P. D.; Plummer, L. N.; Weissmann, G. S.; Stute, M.

2009-12-01

Geochemical techniques and concepts have made major contributions to the understanding of groundwater systems. Advances continue to be made through (1) development of measurement and characterization techniques, (2) improvements in computer technology, networks and numerical modeling, (3) investigation of coupled geologic, hydrologic, geochemical and biologic processes, and (4) scaling of individual observations, processes or subsystem models into larger coherent model frameworks. Many applications benefit from progress in these areas, such as: (1) understanding paleoenvironments, in particular paleoclimate, through the use of groundwater archives, (2) assessing the sustainability (recharge and depletion) of groundwater resources, and (3) their vulnerability to contamination, (4) evaluating the capacity and consequences of subsurface waste isolation (e.g. geologic carbon sequestration, nuclear and chemical waste disposal), (5) assessing the potential for mitigation/transformation of anthropogenic contaminants in groundwater systems, and (6) understanding the effect of groundwater lag times in ecosystem-scale responses to natural events, land-use changes, human impacts, and remediation efforts. Obtaining “representative” groundwater samples is difficult and progress in obtaining “representative” samples, or interpreting them, requires new techniques in characterizing groundwater system heterogeneity. Better characterization and simulation of groundwater system heterogeneity (both physical and geochemical) is critical to interpreting the meaning of groundwater “ages”; to understanding and predicting groundwater flow, solute transport, and geochemical evolution; and to quantifying groundwater recharge and discharge processes. Research advances will also come from greater use and progress (1) in the application of environmental tracers to ground water dating and in the analysis of new geochemical tracers (e.g. compound specific isotopic analyses, noble gas isotopes, analyses of natural organic tracers), (2) in inverse geochemical and hydrological modeling, (3) in the understanding and simulation of coupled biological, geological, geochemical and hydrological processes, and (4) in the description and quantification of processes occurring at the boundaries of groundwater systems (e.g. unsaturated zone processes, groundwater/surface water interactions, impacts of changing geomorphology and vegetation). Improvements are needed in the integration of widely diverse information. Better techniques are needed to construct coherent conceptual frameworks from individual observations, simulated or reconstructed information, process models, and intermediate scale models. Iterating between data collection, interpretation, and the application of forward, inverse, and statistical modeling tools is likely to provide progress in this area. Quantifying groundwater system processes by using an open-system thermodynamic approach in a common mass- and energy-flow framework will also facilitate comparison and understanding of diverse processes.

From mantle peridotites to hybrid troctolites: Textural, structural and geochemical evolution during multi-stage melt-rock interaction history

NASA Astrophysics Data System (ADS)

Basch, V.; Rampone, E.; Crispini, L.; Ferrando, C.; Ildefonse, B.; Godard, M.

2017-12-01

Recent studies investigate the replacive formation of hybrid troctolites from mantle peridotites after multiple stages of melt-rock reactions. However, none of these studies are conducted in a field-controlled geological setting displaying the clear evolution from peridotite to dunite to troctolite. We investigated the Mt.Maggiore and Erro Tobbio ophiolitic peridotites. They both preserve structural and chemical records of two distinct melt-rock interaction stages, from a reactive melt percolation at spinel facies to plagioclase-bearing melt impregnation at shallower lithospheric depths. We performed EBSD and in situ geochemical analyses to document the textural, structural and geochemical variations of the olivine matrix during melt-rock interactions and the associated evolution from peridotite to dunite to troctolite. The olivine-saturated reactive melt percolation leads to the dissolution of mantle pyroxenes in peridotite, and to the formation of replacive dunite. At shallower level, melt impregnation leads to the crystallization of plagioclase in the dunite, and to the formation of hybrid troctolite. The latter is characterized by textural, structural and geochemical features acquired during dunitization and impregnation processes. We documented a textural evolution of the olivine matrix (decrease in grain area, tortuosity and aspect ratio) during impregnation, with a progressive corrosion of mantle olivines by a reactive melt. As a result, olivine in the hybrid troctolites occurs both as coarse deformed relicts and disrupted undeformed grains. During melt-rock interactions, the variation in olivine Crystallographic Preferred Orientation is related to the local melt/rock ratio involved in the percolation process. At high melt/rock ratio, a change from axial-[100] to axial-[010] is observed, with the disaggregation of the solid matrix. REE-enriched compositions are observed in olivine of dunites and troctolites. A geochemical modeling of melt-rock interactions (Plate Model) fits the observed evolution of modal composition with the measured trace element composition variability. The combined field, structural, and geochemical investigation of the evolution from a mantle protolith to the product of the reactions truly supports the hybrid origin of an olivine-rich troctolite.

Regional Geochemistry - an Introduction

NASA Astrophysics Data System (ADS)

Reimann, Clemens

2017-04-01

Building on the pioneering ideas and work of V. Vernadsky (1883-1945) and V.M. Goldschmidt (1888-1947) the Geological Surveys of Europe have more than 60 years experience with geochemical mapping at a large variety of scales. Surveys using hundreds of samples per km2 for mineral exploration projects, 1 to 4 sites per km2 for mapping the urban environment, 1 site per 2 to 10 km2 in county or country-wide mapping projects to 1 site per 1000 to 5000 km2 for mapping at the continental scale have been successfully completed. Sample materials for these surveys include groundwater, surface water, stream sediments, floodplain sediments, different soil horizons (preferably soil O, A, B and C horizon) and plant materials from moss to trees. Surveys combining several sample materials from local to sub-continental scale in multi-media, multi-element geochemical investigations reflecting the interplay of chemical elements between the different compartments (lithosphere, pedosphere, biosphere and hydrosphere) of the ecosystem have also been carried out. These surveys provide ample empirical evidence that different geochemical processes become visible at different scales. Not all sample materials are suitable for all scales. A variety of scales in combination with a variety of different sample materials are needed to fully understand geochemical processes in the critical zone. Examples are shown that highlight the importance of a strategy to optimize sampling density and design for the chosen scale already during the planning stages of a project. Anthropogenic element sources are visible at a local scale and the major impact of geology, mineralogy and climate (as a driving force for weathering) dominates geochemical maps at the continental scale. Interestingly, mineralisation can generate features which are visible at a variety of scales. Some further issues that need attention when carrying out geochemical surveys at a variety of scales are (a) the need for an excellent and well documented analytical quality control, (b) the choice of the elements to be analysed (as many as possible) (c) the required detection limits (the lowest possible) and (d) the choice of extraction (several if feasible).

Assessing the Biological Contribution to Mineralized Cap Formation in the Little Hot Creek Hot Spring System

NASA Astrophysics Data System (ADS)

Floyd, J. G.; Beeler, S. R.; Mors, R. A.; Kraus, E. A.; 2016, G.; Piazza, O.; Frantz, C. M.; Loyd, S. J.; Berelson, W.; Stevenson, B. S.; Marenco, P. J.; Spear, J. R.; Corsetti, F. A.

2016-12-01

Hot spring environments exhibit unique redox/physical gradients that may create favorable conditions for the presence of life and commonly contain mineral precipitates that could provide a geologic archive of such ecosystems on Earth and potentially other planets. However, it is critical to discern biologic from abiotic formation mechanisms if hot spring-associated minerals are to be used as biosignatures. The study of modern hot spring environments where mineral formation can be directly observed is necessary to better interpret the biogenicity of ancient/extraterrestrial examples. Little Hot Creek (LHC), a hot spring located in the Long Valley Caldera, California, contains mineral precipitates composed of a carbonate base covered with amorphous silica and minor carbonate in close association with microbial mats/biofilms. Geological, geochemical, and microbiological techniques were integrated to investigate the role of biology in mineral formation at LHC. Geochemical measurements indicate that the waters of the spring are near equilibrium with respect to carbonate and undersaturated with respect to silica, implying additional processes are necessary to initiate cap formation. Geochemical modeling, integrating elemental and isotopic data from hot spring water and mineral precipitates, indicate that the abiotic processes of degassing and evaporation drive mineral formation at LHC, without microbial involvement. However, petrographic analysis of LHC caps revealed microbial microfabrics within silica mineral phases, despite the fact that microbial metabolism was not required for mineral precipitation. Our results show that microorganisms in hot spring environments can shape mineral precipitates even in the absence of a control on authigenesis, highlighting the need for structural as well as geochemical investigation in similar systems.

A Geochemical Reaction Model for Titration of Contaminated Soil and Groundwater at the Oak Ridge Reservation

NASA Astrophysics Data System (ADS)

Zhang, F.; Parker, J. C.; Gu, B.; Luo, W.; Brooks, S. C.; Spalding, B. P.; Jardine, P. M.; Watson, D. B.

2007-12-01

This study investigates geochemical reactions during titration of contaminated soil and groundwater at the Oak Ridge Reservation in eastern Tennessee. The soils and groundwater exhibits low pH and high concentrations of aluminum, calcium, magnesium, manganese, various trace metals such as nickel and cobalt, and radionuclides such as uranium and technetium. The mobility of many of the contaminant species diminishes with increasing pH. However, base additions to increase pH are strongly buffered by various precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior and associated geochemical effects is thus critical to evaluate remediation performance of pH manipulation strategies. This study was undertaken to develop a practical but generally applicable geochemical model to predict aqueous and solid-phase speciation during soil and groundwater titration. To model titration in the presence of aquifer solids, an approach proposed by Spalding and Spalding (2001) was utilized, which treats aquifer solids as a polyprotic acid. Previous studies have shown that Fe and Al-oxyhydroxides strongly sorb dissolved Ni, U and Tc species. In this study, since the total Fe concentration is much smaller than that of Al, only ion exchange reactions associated with Al hydroxides are considered. An equilibrium reaction model that includes aqueous complexation, precipitation, ion exchange, and soil buffering reactions was developed and implemented in the code HydroGeoChem 5.0 (HGC5). Comparison of model results with experimental titration curves for contaminated groundwater alone and for soil- water systems indicated close agreement. This study is expected to facilitate field-scale modeling of geochemical processes under conditions with highly variable pH to develop practical methods to control contaminant mobility at geochemically complex sites.

Geochemical and geological factors controlling the spatial distribution of sulfate-methane transition zone in the Ría de Vigo (NW Spain)

NASA Astrophysics Data System (ADS)

Martínez-Carreño, N.; García-Gil, S.; Cartelle, V.; de Blas, E.; Ramírez-Pérez, A. M.; Insua, T. L.

2017-05-01

High-resolution seismic profiles, gravity core analysis and radiocarbon data have been used to identify the factors behind the methane production and free gas accumulation in the Ría de Vigo. Lithological and geochemical parameters (sulfate and methane concentration) from seventeen gravity cores were analyzed to characterize the sediment of the ria. The distribution of methane-charged sediments is mainly controlled by the quantity and quality of organic matter. Geochemical analyses reveal minimum methane concentrations ranging between 1 μM and 1 mM in sediments located outside the acoustic gas field, while gas-bearing sediments, show methane concentrations up to 5 mM. A shallowing of the sulfate-methane transition zone (SMTZ) is observed from the outer to the inner area of the ria. The presence of methane in the sulfate reduction zone (SRZ) likely to reflect the existence of methylotropic methanogenesis and/or migration processes of deeper methane gas in the sediments of the Ría de Vigo. The presence of an 'anomalous' high-sulfate concentration layer below the SMTZ in the inner and middle area of the ria, is attributed to the intrusion of sulfate-rich waters from adjacent areas that could be transported laterally through more porous layers.

Experimental Investigations of the Weathering of Suspended Sediment by Alpine Glacial Meltwater

NASA Astrophysics Data System (ADS)

Brown, Giles H.; Tranter, M.; Sharp, M. J.

1996-04-01

The magnitude and processes of solute acquisition by dilute meltwater in contact with suspended sediment in the channelized component of the hydroglacial system have been investigated through a suite of controlled laboratory experiments. Constrained by field data from Haut Glacier d'Arolla, Valais, Switzerland the effects of the water to rock ratio, particle size, crushing, repeated wetting and the availability of protons on the rate of solute acquisition are demonstrated. These free-drift experiments suggest that the rock flour is extremely geochemically reactive and that dilute quickflow waters are certain to acquire solute from suspended sediment. These data have important implications for hydrological interpretations based on the solute content of glacial meltwater, mixing model calculations, geochemical denudation rates and solute provenance studies.

Evapotranspiration And Geochemical Controls On Groundwater Plumes At Arid Sites: Toward Innovative Alternate End-States For Uranium Processing And Tailings Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Looney, Brian B.; Denham, Miles E.; Eddy-Dilek, Carol A.

2014-01-08

Management of legacy tailings/waste and groundwater contamination are ongoing at the former uranium milling site in Tuba City AZ. The tailings have been consolidated and effectively isolated using an engineered cover system. For the existing groundwater plume, a system of recovery wells extracts contaminated groundwater for treatment using an advanced distillation process. The ten years of pump and treat (P&T) operations have had minimal impact on the contaminant plume – primarily due to geochemical and hydrological limits. A flow net analysis demonstrates that groundwater contamination beneath the former processing site flows in the uppermost portion of the aquifer and exitsmore » the groundwater as the plume transits into and beneath a lower terrace in the landscape. The evaluation indicates that contaminated water will not reach Moenkopi Wash, a locally important stream. Instead, shallow groundwater in arid settings such as Tuba City is transferred into the vadose zone and atmosphere via evaporation, transpiration and diffuse seepage. The dissolved constituents are projected to precipitate and accumulate as minerals such as calcite and gypsum in the deep vadose zone (near the capillary fringe), around the roots of phreatophyte plants, and near seeps. The natural hydrologic and geochemical controls common in arid environments such as Tuba City work together to limit the size of the groundwater plume, to naturally attenuate and detoxify groundwater contaminants, and to reduce risks to humans, livestock and the environment. The technical evaluation supports an alternative beneficial reuse (“brownfield”) scenario for Tuba City. This alternative approach would have low risks, similar to the current P&T scenario, but would eliminate the energy and expense associated with the active treatment and convert the former uranium processing site into a resource for future employment of local citizens and ongoing benefit to the Native American Nations.« less

Numerical Modelling of Speleothem and Dripwater Chemistry: Interpreting Coupled Trace Element and Isotope Proxies for Climate Reconstructions

NASA Astrophysics Data System (ADS)

Owen, R.; Day, C. C.; Henderson, G. M.

2016-12-01

Speleothem palaeoclimate records are widely used but are often difficult to interpret due to the geochemical complexity of the soil-karst-cave system. Commonly analysed proxies (e.g. δ18O, δ13C and Mg/Ca) may be affected by multiple processes along the water flow path from atmospheric moisture source through to the cave drip site. Controls on speleothem chemistry include rainfall and aerosol chemistry, bedrock chemistry, temperature, soil pCO2, the degree of open-system dissolution and prior calcite precipitation. Disentangling the effects of these controls is necessary to fully interpret speleothem palaeoclimate records. To quantify the effects of these processes, we have developed an isotope-enabled numerical model based on the geochemical modelling software PHREEQC. The model calculates dripwater chemistry and isotopes through equilibrium bedrock dissolution and subsequent iterative CO2 degassing and calcite precipitation. This approach allows forward modelling of dripwater and speleothem proxies, both chemical (e.g. Ca concentration, pH, Mg/Ca and Sr/Ca ratios) and isotopic (e.g. δ18O, δ13C, δ44Ca and radiocarbon content), in a unified framework. Potential applications of this model are varied and the model may be readily expanded to include new isotope systems or processes. Here we focus on calculated proxy co-variation due to changes in model parameters. Examples include: - The increase in Ca concentration, decrease in δ13C and increase in radiocarbon content as bedrock dissolution becomes more open-system. - Covariation between δ13C, δ44Ca and trace metal proxies (e.g. Mg/Ca) predicted by changing prior calcite precipitation. - The effect of temperature change on all proxies through the soil-karst-cave system. Separating the impact of soil and karst processes on geochemical proxies allows more quantitative reconstruction of the past environment, and greater understanding in modern cave monitoring studies.

Tin-tungsten mineralizing processes in tungsten vein deposits: Panasqueira, Portugal

NASA Astrophysics Data System (ADS)

Lecumberri-Sanchez, P.; Pinto, F.; Vieira, R.; Wälle, M.; Heinrich, C. A.

2015-12-01

Tungsten has a high heat resistance, density and hardness, which makes it widely applied in industry (e.g. steel, tungsten carbides). Tungsten deposits are typically magmatic-hydrothermal systems. Despite the economic significance of tungsten, there are no modern quantitative analytical studies of the fluids responsible for the formation of its highest-grade deposit type (tungsten vein deposits). Panasqueira (Portugal) is a tungsten vein deposit, one of the leading tungsten producers in Europe and one of the best geologically characterized tungsten vein deposits. In this study, compositions of the mineralizing fluids at Panasqueira have been determined through combination of detailed petrography, microthermometric measurements and LA-ICPMS analyses, and geochemical modeling has been used to determine the processes that lead to tungsten mineralization. We characterized the fluids related to the various mineralizing stages in the system: the oxide stage (tin and tungsten mineralization), the sulfide stage (chalcopyrite and sphalerite mineralization) and the carbonate stage. Thus, our results provide information on the properties of fluids related with specific paragenetic stages. Furthermore we used those fluid compositions in combination with host rock mineralogy and chemistry to evaluate which are the controlling factors in the mineralizing process. This study provides the first quantitative analytical data on fluid composition for tungsten vein deposits and evaluates the controlling mineralization processes helping to determine the mechanisms of formation of the Panasqueira tin-tungsten deposit and providing additional geochemical constraints on the local distribution of mineralization.

Hydrological and Geochemical Influences on the Dissolved Silica Concentrations in Natural Water in a Steep Headwater Catchment

NASA Astrophysics Data System (ADS)

Asano, Y.; Uchida, T.; Ohte, N.

2002-12-01

Dissolved silica has been used as a useful indicator of a chemical weathering in many geochemical studies in natural environment. Previous hydrological studies indicated that various hydrological processes affect the dissolution and precipitation of silica in hillslope and transport of this silica to stream; however, information is still limited to link this knowledge to understand geochemical processes. The observations of dissolved silica concentration in groundwater, spring and stream water was conducted at the unchannelled hillslope in the Tanakami Mountains of central Japan; (1) to clarify the effects of preferential flowpaths including lateral and vertical flow in soil layer and flow through bedrock fracture in the variation of dissolved silica concentration in runoff and groundwater, and (2) to isolate the effects of mixing of water from geochemically diverse water sources on the dissolved silica concentration. The mean dissolved silica concentrations in soil water at 40 cm depth and transient groundwater formed in upslope area were relatively constant independent of the variation in the new water ratio. The mean dissolved silica concentrations were similar regardless of the sampling depth in soil although the mean residence times of water increase with depth. These results indicated that dissolved silica concentrations in soil water and transient groundwater were defined almost independent of contact time of water with minerals. While the mean dissolved silica concentration in perennial groundwater, which was recharged by infiltrating water through soil and water emerging from bedrock in a area near to spring, was more than twice that of transient groundwater and the variation was relatively large. The mean dissolved silica concentration increased significantly at downslope from perennial groundwater, spring to the stream and the spring and stream concentrations also showed large variation. The dissolved silica concentrations of those perennial groundwater, the spring and the stream was controlled by the mixing of water from soil and bedrock. Our results demonstrated that in most areas of this headwater catchment, the preferential flowpaths give only small effect on dissolved silica concentrations. While in a small area (less than 10% of the longitudinal axis of the hollow near the spring), the dissolved silica concentration were controlled by the mixing of water from geochemically diverse water sources.

A COMSOL-GEMS interface for modeling coupled reactive-transport geochemical processes

NASA Astrophysics Data System (ADS)

Azad, Vahid Jafari; Li, Chang; Verba, Circe; Ideker, Jason H.; Isgor, O. Burkan

2016-07-01

An interface was developed between COMSOL MultiphysicsTM finite element analysis software and (geo)chemical modeling platform, GEMS, for the reactive-transport modeling of (geo)chemical processes in variably saturated porous media. The two standalone software packages are managed from the interface that uses a non-iterative operator splitting technique to couple the transport (COMSOL) and reaction (GEMS) processes. The interface allows modeling media with complex chemistry (e.g. cement) using GEMS thermodynamic database formats. Benchmark comparisons show that the developed interface can be used to predict a variety of reactive-transport processes accurately. The full functionality of the interface was demonstrated to model transport processes, governed by extended Nernst-Plank equation, in Class H Portland cement samples in high pressure and temperature autoclaves simulating systems that are used to store captured carbon dioxide (CO2) in geological reservoirs.

Microfluidic Experiments Studying Pore Scale Interactions of Microbes and Geochemistry

NASA Astrophysics Data System (ADS)

Chen, M.; Kocar, B. D.

2016-12-01

Understanding how physical phenomena, chemical reactions, and microbial behavior interact at the pore-scale is crucial to understanding larger scale trends in groundwater chemistry. Recent studies illustrate the utility of microfluidic devices for illuminating pore-scale physical-biogeochemical processes and their control(s) on the cycling of iron, uranium, and other important elements 1-3. These experimental systems are ideal for examining geochemical reactions mediated by microbes, which include processes governed by complex biological phenomenon (e.g. biofilm formation, etc.)4. We present results of microfluidic experiments using a model metal reducing bacteria and varying pore geometries, exploring the limitations of the microorganisms' ability to access tight pore spaces, and examining coupled biogeochemical-physical controls on the cycling of redox sensitive metals. Experimental results will provide an enhanced understanding of coupled physical-biogeochemical processes transpiring at the pore-scale, and will constrain and compliment continuum models used to predict and describe the subsurface cycling of redox-sensitive elements5. 1. Vrionis, H. A. et al. Microbiological and geochemical heterogeneity in an in situ uranium bioremediation field site. Appl. Environ. Microbiol. 71, 6308-6318 (2005). 2. Pearce, C. I. et al. Pore-scale characterization of biogeochemical controls on iron and uranium speciation under flow conditions. Environ. Sci. Technol. 46, 7992-8000 (2012). 3. Zhang, C., Liu, C. & Shi, Z. Micromodel investigation of transport effect on the kinetics of reductive dissolution of hematite. Environ. Sci. Technol. 47, 4131-4139 (2013). 4. Ginn, T. R. et al. Processes in microbial transport in the natural subsurface. Adv. Water Resour. 25, 1017-1042 (2002). 5. Scheibe, T. D. et al. Coupling a genome-scale metabolic model with a reactive transport model to describe in situ uranium bioremediation. Microb. Biotechnol. 2, 274-286 (2009).

Laboratory simulation of organic geochemical processes.

NASA Technical Reports Server (NTRS)

Eglinton, G.

1972-01-01

Discussion of laboratory simulations that are important to organic geochemistry in that they provide direct evidence relating to geochemical cycles involving carbon. Reviewed processes and experiments include reactions occurring in the geosphere, particularly, short-term diagenesis of biolipids and organochlorine pesticides in estuarine muds, as well as maturation of organic matter in ancient sediments.

Induced and catalysed mineral precipitation in the deep biosphere

NASA Astrophysics Data System (ADS)

Meister, Patrick

2017-04-01

Authigenic and early diagenetic minerals provide archives of past (bio)geochemical processes. In particular, isotopic signatures preserved in the diagenetic phases have been shown to document drastic changes of subsurface microbial activity (the deep biosphere) over geological time periods (Contreras et al., 2013; Meister, 2015). Geochemical and isotopic signatures in authigenic minerals may also document surface conditions and past climate. Nevertheless, such use of authigenic mineral phases as (bio)geochemical archives is often hampered by the insufficient understanding of mineral precipitation mechanisms. Accordingly the time, place and rate of mineral precipitation are often not well constrained. Also, element partitioning and isotopic fractionation may be modified as a result of the precipitation mechanism. Early diagenetic dolomite and quartz from drilled sequences in the Pacific were compared with adjacent porewater compositions and isotope signatures to gain fundamental insight into the factors controlling mineral precipitation. The formation of dolomite in carbonate-free organic carbon-rich ocean margin sediments (e.g. Peru Margin; Ocean Drilling Program, ODP, Site 1229; Meister et al., 2007) relies on the alkalinity-increase driven by anaerobic oxidation of methane and, perhaps, by alteration of clay minerals. In contrast, quartz is often significantly oversaturated in marine porewaters as the dissolved silica concentration is buffered by more soluble opal-A. For example, quartz does not form throughout a 400 metre thick sedimentary sequence in the Eastern Equatorial Pacific (ODP Site 1226; Meister et al., 2014) because it is kinetically inhibited. This behaviour can be explained by Ostwald's step rule, which suggests that the metastable phase forms faster. However, hard-lithified quartz readily forms where silica concentration drops sharply below opal-saturation. This violation of Ostwald's step rule must be driven by an auxiliary process, such as the adsorption of silica to freshly precipitated iron oxides along a deep iron oxidation front. In conclusion, two different modes of precipitation can be observed in modern sub-seafloor porewater systems. Dolomite precipitation is thermodynamically controlled through microbially induced supersaturation. Quartz formation is controlled through an auxiliary process that helps it to overcome a kinetic barrier. These observations exemplify the importance to distinguish between kinetic and thermodynamic effects on mineral formation under Earth surface conditions. To evaluate geochemical signatures, these modes of precipitation need to be taken into account. Contreras et al. (2013) Proc. Natl. Acad. Sci., doi/10.1073/pnas.1305981110 Meister, et al. (2007) Sedimentology 54, 1007-1032. Meister, et al. (2014) Geochim. Cosmochim. Acta 137, 188-207. Meister, P. (2015) Terra Nova, Focus Article, 00, 1-9.

Chemical and U-Sr isotopic variations of stream and source waters at a small catchment scale (the Strengbach case; Vosges mountains; France)

NASA Astrophysics Data System (ADS)

Pierret, M. C.; Stille, P.; Prunier, J.; Viville, D.; Chabaux, F.

2014-03-01

This is the first comprehensive study dealing with major and trace element data as well as 87Sr/86Sr isotope and (234U/238U) activity ratios (AR) determined on the totality of springs and brooks of the Strengbach catchment. It shows that the small and more or less monolithic catchment drains different sources and streamlets with very different isotopic and geochemical signatures. Different parameters control the diversity of the source characteristics. Of importance is especially the hydrothermal overprint of the granitic bedrock, which was stronger for the granite from the northern than from the southern slope; also significant are the different meteoric alteration processes of the bedrock causing the formation of 0.5 to 9 m thick saprolite and above the formation of an up to 1 m thick soil system. These processes mainly account for springs and brooks from the northern slope having higher Ca/Na, Mg/Na, Sr/Na ratios but lower 87Sr/86Sr isotopic ratios than those from the southern slope. The chemical compositions of the source waters in the Strengbach catchment are only to a small extent the result of alteration of primary bedrock minerals and rather reflect dissolution/precipitation processes of secondary mineral phases like clay minerals. The (234U/238U) AR, however, are decoupled from the 87Sr/86Sr isotope system and reflect to some extent the level of altitude of the source and, thus, the degree of alteration of the bedrock. The sources emerging at high altitudes have circulated through already weathered materials (saprolite and fractured rock depleted in 234U) implying (234U/238U) AR < 1, which is uncommon for surface waters. Preferential flow paths along constant fractures in the bedrocks might explain the over time homogeneous U AR of the different spring waters. However, the geochemical and isotopic variations of stream waters at the outlet of the catchment are controlled by variable contributions of different springs depending on the hydrological conditions. It appears that the (234U/238U) AR is an appropriate very important tracer for studying and deciphering the contribution of the different source fluxes at the catchment scale because this unique geochemical parameter is different for each individual spring and at the same time remains unchanged for each of the springs with changing discharge and fluctuating hydrological conditions. This study further highlights the important impact of different and independent water pathways in fractured granite controlling the different geochemical and isotopic signatures of the waters.

Chemical Structure and Molecular Dimension As Controls on the Inherent Stability of Charcoal in Boreal Forest Soil

NASA Astrophysics Data System (ADS)

Hockaday, W. C.; Kane, E. S.; Ohlson, M.; Huang, R.; Von Bargen, J.; Davis, R.

2014-12-01

Efforts have been made by various scientific disciplines to study hyporheic zones and characterize their associated processes. One way to approach the study of the hyporheic zone is to define facies, which are elements of a (hydrobio) geologic classification scheme that groups components of a complex system with high variability into a manageable set of discrete classes. In this study, we try to classify the hyporheic zone based on the geology, geochemistry, microbiology, and understand their interactive influences on the integrated biogeochemical distributions and processes. A number of measurements have been taken for 21 freeze core samples along the Columbia River bank in the Hanford 300 Area, and unique datasets have been obtained on biomass, pH, number of microbial taxa, percentage of N/C/H/S, microbial activity parameters, as well as microbial community attributes/modules. In order to gain a complete understanding of the geological control on these variables and processes, the explanatory variables are set to include quantitative gravel/sand/mud/silt/clay percentages, statistical moments of grain size distributions, as well as geological (e.g., Folk-Wentworth) and statistical (e.g., hierarchical) clusters. The dominant factors for major microbial and geochemical variables are identified and summarized using exploratory data analysis approaches (e.g., principal component analysis, hierarchical clustering, factor analysis, multivariate analysis of variance). The feasibility of extending the facies definition and its control of microbial and geochemical properties to larger scales is discussed.

TReacLab: An object-oriented implementation of non-intrusive splitting methods to couple independent transport and geochemical software

NASA Astrophysics Data System (ADS)

Jara, Daniel; de Dreuzy, Jean-Raynald; Cochepin, Benoit

2017-12-01

Reactive transport modeling contributes to understand geophysical and geochemical processes in subsurface environments. Operator splitting methods have been proposed as non-intrusive coupling techniques that optimize the use of existing chemistry and transport codes. In this spirit, we propose a coupler relying on external geochemical and transport codes with appropriate operator segmentation that enables possible developments of additional splitting methods. We provide an object-oriented implementation in TReacLab developed in the MATLAB environment in a free open source frame with an accessible repository. TReacLab contains classical coupling methods, template interfaces and calling functions for two classical transport and reactive software (PHREEQC and COMSOL). It is tested on four classical benchmarks with homogeneous and heterogeneous reactions at equilibrium or kinetically-controlled. We show that full decoupling to the implementation level has a cost in terms of accuracy compared to more integrated and optimized codes. Use of non-intrusive implementations like TReacLab are still justified for coupling independent transport and chemical software at a minimal development effort but should be systematically and carefully assessed.

Using Tidal Fluctuation-Induced Dynamics of Radium Isotopes (224Ra, 223Ra, and 228Ra) to Trace the Hydrodynamics and Geochemical Reactions in a Coastal Groundwater Mixing Zone

NASA Astrophysics Data System (ADS)

Liu, Yi; Jiao, Jiu Jimmy; Liang, Wenzhao; Luo, Xin

2018-04-01

The reactive transport of radium isotopes (224Ra, 223Ra, and 228Ra) in coastal groundwater mixing zones (CGMZs) is sensitive to shifts of redox conditions and geochemical reactions induced by tidal fluctuation. This study presents a spatial distribution and temporal variation of radium isotopes in the CGMZ for the first time. Results show that the activity of radium isotopes in the upper saline plume (USP) is comparatively low due to a short residence time and mixing loss induced by the infiltration of low radium seawater whereas the activity of radium isotopes in the salt wedge (SW) is comparatively high due to a long residence time in the aquifer. The spatial distribution of radium isotopes is determined by the partitioning of radium isotopes, groundwater residence time, and relative ingrowth rates of radium isotopes. In addition, the variation of radium isotopes in the USP lags slightly (˜0 h) whereas the fluctuation of radium isotopes in the SW lags significantly (˜12 h) behind sea level oscillation. Tidal fluctuation affects the partitioning of radium isotopes through controlling seawater infiltration and subsequently influences the dynamics of radium isotopes in the USP. Concurrently, seawater infiltration significantly affects geochemical processes such as the production of nutrients and total alkalinity. Therefore, radium dynamics in the USP have implications for these geochemical processes. The variation of radium isotopes in the USP also has potential implications for transformation of trace metals such as iron and manganese because of the close affinity of radium isotopes to manganese and iron oxides.

A strong enrichment of potentially toxic elements (PTEs) in Nord-Trøndelag (central Norway) forest soil.

PubMed

Reimann, C; Fabian, K; Schilling, J; Roberts, D; Englmaier, P

2015-12-01

Analysis of soil C and O horizon samples in a recent regional geochemical survey of Nord-Trøndelag, central Norway (752 sample sites covering 25,000 km2), identified a strong enrichment of several potentially toxic elements (PTEs) in the O horizon. Of 53 elements analysed in both materials, Cd concentrations are, on average, 17 times higher in the O horizon than in the C horizon and other PTEs such as Ag (11-fold), Hg (10-fold), Sb (8-fold), Pb (4-fold) and Sn (2-fold) are all strongly enriched relative to the C horizon. Geochemical maps of the survey area do not reflect an impact from local or distant anthropogenic contamination sources in the data for O horizon soil samples. The higher concentrations of PTEs in the O horizon are the result of the interaction of the underlying geology, the vegetation zone and type, and climatic effects. Based on the general accordance with existing data from earlier surveys in other parts of northern Europe, the presence of a location-independent, superordinate natural trend towards enrichment of these elements in the O horizon relative to the C horizon soil is indicated. The results imply that the O and C horizons of soils are different geochemical entities and that their respective compositions are controlled by different processes. Local mineral soil analyses (or published data for the chemical composition of the average continental crust) cannot be used to provide a geochemical background for surface soil. At the regional scale used here surface soil chemistry is still dominated by natural sources and processes. Copyright © 2015 Elsevier B.V. All rights reserved.

Nanostructures and radionuclide transport in clay formations (Invited)

NASA Astrophysics Data System (ADS)

Wang, Y.

2010-12-01

Nanostructures are widely present in geologic materials and are expected to directly affect the interactions of these materials with geologic fluids. The study of mineral-water interface chemistry as controlled by nanostructures is a necessary step to bridge the existing gap between the molecular level understanding of a geochemical process and the macro-scale laboratory and field observations. In this presentation, I will review the recent progresses in nanoscience and provide a perspective on how these progresses can potentially impact geochemical studies. My presentation will be focused the following areas: (1) the characterization of nanostructures in natural systems, (2) the study of water and chemical species in nanoconfinement, (3) the effects of nanopores on geochemical reaction and mass transfers, and (4) the use nanostructured materials for environmental remediation and cleanup. Specifically, I will demonstrate that the nanopore confinement can significantly modify geochemical reactions in porous geologic media. As the pore size is reduced to a few nanometers, the difference between surface acidity constants (pK2 - pK1) decreases, giving rise to a higher surface charge density on a nanopore surface than that on an unconfined mineral-water interface. The change in surface acidity constants results in a shift of ion sorption edges and enhances ion sorption on nanopore surfaces. This effect causes preferential enrichment of trace elements in nanopores and therefore directly impacts the bioavailability of these elements. The implication of these processes to radionuclide transport in clay formations will be discussed. This work was performed at Sandia National Laboratories, which is a multiprogram laboratory operated by Sandia Corporation, a Lockheed-Martin Company, for the DOE under contract DE-AC04-94AL8500.

Decreasing Kd uncertainties through the application of thermodynamic sorption models.

PubMed

Domènech, Cristina; García, David; Pękala, Marek

2015-09-15

Radionuclide retardation processes during transport are expected to play an important role in the safety assessment of subsurface disposal facilities for radioactive waste. The linear distribution coefficient (Kd) is often used to represent radionuclide retention, because analytical solutions to the classic advection-diffusion-retardation equation under simple boundary conditions are readily obtainable, and because numerical implementation of this approach is relatively straightforward. For these reasons, the Kd approach lends itself to probabilistic calculations required by Performance Assessment (PA) calculations. However, it is widely recognised that Kd values derived from laboratory experiments generally have a narrow field of validity, and that the uncertainty of the Kd outside this field increases significantly. Mechanistic multicomponent geochemical simulators can be used to calculate Kd values under a wide range of conditions. This approach is powerful and flexible, but requires expert knowledge on the part of the user. The work presented in this paper aims to develop a simplified approach of estimating Kd values whose level of accuracy would be comparable with those obtained by fully-fledged geochemical simulators. The proposed approach consists of deriving simplified algebraic expressions by combining relevant mass action equations. This approach was applied to three distinct geochemical systems involving surface complexation and ion-exchange processes. Within bounds imposed by model simplifications, the presented approach allows radionuclide Kd values to be estimated as a function of key system-controlling parameters, such as the pH and mineralogy. This approach could be used by PA professionals to assess the impact of key geochemical parameters on the variability of radionuclide Kd values. Moreover, the presented approach could be relatively easily implemented in existing codes to represent the influence of temporal and spatial changes in geochemistry on Kd values. Copyright © 2015 Elsevier B.V. All rights reserved.

Micromechanical Tests and Geochemical Modeling to Evaluate Evolution of Rock Alteration by CO2-Water Mixtures

NASA Astrophysics Data System (ADS)

Aman, M.; Sun, Y.; Ilgen, A.; Espinoza, N.

2015-12-01

Injection of large volumes of CO2 into geologic formations can help reduce the atmospheric CO2 concentration and lower the impact of burning fossil fuels. However, the injection of CO2 into the subsurface shifts the chemical equilibrium between the mineral assemblage and the pore fluid. This shift will situationally facilitate dissolution and reprecipitation of mineral phases, in particular intergranular cements, and can potentially affect the long term mechanical stability of the host formation. The study of these coupled chemical-mechanical reservoir rock responses can help identify and control unexpected emergent behavior associated with geological CO2 storage.Experiments show that micro-mechanical methods are useful in capturing a variety of mechanical parameters, including Young's modulus, hardness and fracture toughness. In particular, micro-mechanical measurements are well-suited for examining thin altered layers on the surfaces of rock specimens, as well as capturing variability on the scale of lithofacies. We performed indentation and scratching tests on sandstone and siltstone rocks altered in natural CO2-brine environments, as well as on analogous samples altered under high pressure, temperature, and dissolved CO2 conditions in a controlled laboratory experiment. We performed geochemical modeling to support the experimental observations, in particular to gain the insight into mineral dissolution/precipitation as a result of the rock-water-CO2reactions. The comparison of scratch measurements performed on specimens both unaltered and altered by CO2 over geologic time scales results in statistically different values for fracture toughness and scratch hardness, indicating that long term exposure to CO2 caused mechanical degradation of the reservoir rock. Geochemical modeling indicates that major geochemical change caused by CO2 invasion of Entrada sandstone is dissolution of hematite cement, and its replacement with siderite and dolomite during the alteration process.

Geochemical differentiation processes for arc magma of the Sengan volcanic cluster, Northeastern Japan, constrained from principal component analysis

NASA Astrophysics Data System (ADS)

Ueki, Kenta; Iwamori, Hikaru

2017-10-01

In this study, with a view of understanding the structure of high-dimensional geochemical data and discussing the chemical processes at work in the evolution of arc magmas, we employed principal component analysis (PCA) to evaluate the compositional variations of volcanic rocks from the Sengan volcanic cluster of the Northeastern Japan Arc. We analyzed the trace element compositions of various arc volcanic rocks, sampled from 17 different volcanoes in a volcanic cluster. The PCA results demonstrated that the first three principal components accounted for 86% of the geochemical variation in the magma of the Sengan region. Based on the relationships between the principal components and the major elements, the mass-balance relationships with respect to the contributions of minerals, the composition of plagioclase phenocrysts, geothermal gradient, and seismic velocity structure in the crust, the first, the second, and the third principal components appear to represent magma mixing, crystallizations of olivine/pyroxene, and crystallizations of plagioclase, respectively. These represented 59%, 20%, and 6%, respectively, of the variance in the entire compositional range, indicating that magma mixing accounted for the largest variance in the geochemical variation of the arc magma. Our result indicated that crustal processes dominate the geochemical variation of magma in the Sengan volcanic cluster.

Geochemical processes and the effects of natural organic solutes on the solubility of selenium in coal-mine backfill samples from the Powder River basin, Wyoming

USGS Publications Warehouse

See, R.B.; Reddy, K.J.; Vance, G.F.; Fadlelmawla, A.A.; Blaylock, M.J.

1995-01-01

Geochemical processes and the effects of natural organic solutes on the solubility of selenium in coal-mine backfill aquifers were investigated. Backfill and ground-water samples were collected at coal mines in the Powder River Basin, Wyoming. Backfill was generally dominated by aluminum (14,400 to 49,000 mg/kg (milligrams per kilogram)), iron (3,330 to 23,200 mg/kg), and potassium (7,950 to 18,000 mg/kg). Backfill saturated-paste selenium concentrations ranged from 1 to 156 mg/kg (microsiemens per kilogram). Ground-water total selenium concentrations ranged from 3 to 125 mg/L. Dissolved organic carbon in all ground-water samples was dominated by hydrophobic and hydrophilic acids (38 to 84 percent). Selenite sorption/desorption experiments were conducted using background solutions of distilled-deionized water, 0.1 molar calcium chloride, and isolated hydrophobic and hydrophilic acids. Selenite sorption was larger when 0.1 molar calcium chloride was used. The addition of hydrophilic acid decreased selenite sorption more than the addition of hydrophobic acids. Geochemical modelling was used to predict the solid phases controlling dissolved selenium concentrations and to evaluate the effects of dissolved organic carbon on selenium solubility. Results suggested that 55 to 90 percent of selenium in backfill precipitation/dissolution extracts was dominated by magnesium selenate ion pairs. Dissolved organic carbon had little effect on selenium speciation. A redox chamber was constructed to control Eh and pH in water and backfill-core sample suspensions. The response of selenite and selenate in water samples to redox conditions did not follow thermodynamic predictions. Reduction of selenate in water samples did not occur at any of the redox levels tested.

Investigation of the geochemical evolution of groundwater under agricultural land: A case study in northeastern Mexico

NASA Astrophysics Data System (ADS)

Ledesma-Ruiz, Rogelio; Pastén-Zapata, Ernesto; Parra, Roberto; Harter, Thomas; Mahlknecht, Jürgen

2015-02-01

Zona Citrícola is an important area for Mexico due to its citriculture activity. Situated in a sub-humid to humid climate adjacent to the Sierra Madre Oriental, this valley hosts an aquifer system that represents sequences of shales, marls, conglomerates, and alluvial deposits. Groundwater flows from mountainous recharge areas to the basin-fill deposits and provides base flows to supply drinking water to the adjacent metropolitan area of Monterrey. Recent studies examining the groundwater quality of the study area urge the mitigation of groundwater pollution. The objective of this study was to characterize the physical and chemical properties of the groundwater and to assess the processes controlling the groundwater's chemistry. Correlation was used to identify associations among various geochemical constituents. Factor analysis was applied to identify the water's chemical characteristics that were responsible for generating most of the variability within the dataset. Hierarchical cluster analysis was employed in combination with a post-hoc analysis of variance to partition the water samples into hydrochemical water groups: recharge waters (Ca-HCO3), transition zone waters (Ca-HCO3-SO4 to Ca-SO4-HCO3) and discharge waters (Ca-SO4). Inverse geochemical models of these groups were developed and constrained using PHREEQC to elucidate the chemical reactions controlling the water's chemistry between an initial (recharge) and final water. The primary reactions contributing to salinity were the following: (1) water-rock interactions, including the weathering of evaporitic rocks and dedolomitization; (2) dissolution of soil gas carbon dioxide; and (3) input from animal/human wastewater and manure in combination with by denitrification processes. Contributions from silicate weathering to salinity ranged from less important to insignificant. The findings suggest that it may not be cost-effective to regulate manure application to mitigate groundwater pollution.

Highlights of some environmental problems of geomedical significance in Nigeria.

PubMed

Lar, U A; Tejan, A B

2008-08-01

This paper attempts to discuss the links between the geochemical composition of rocks and minerals and the geographical distribution of diseases in human beings in Nigeria. We know that the natural composition of elements in our environment (in the bedrock, soils, water, and vegetation) may be the major cause of enrichment or depletion in these elements and may become a direct risk to human health. Similarly, anthropogenic activities such as mining and mineral processes, industrial waste disposal, agriculture, etc., could distort the natural geochemical equilibrium of the environment. Thus, the enrichment or depletion of geochemical elements in the environment are controlled either by natural and/or anthropogenic processes. The increased ingestion of toxic trace elements such as As, Cd, Hg, Pb, and F, whether directly or indirectly, adversely affects human health. Of these, Cd has most dangerous long-term effect on human health. Environmental exposure to As and Hg is a causal factor in human carcinogenesis and numerous cancer health disorders. Available information on iodine deficiency disorder (IDD) in Nigeria indicates goiter prevalence rates of between 15% and 59% in several affected areas. There have been reported cases of dental fluorosis resulting from intake of water with fluoride content >1.5 ppm. Dental caries among children shows an overall prevalence rate of 39.9%. Within the Younger Granite province in central Nigeria, cases of cancer and miscarriages in pregnant women have been linked to natural radiation These examples and a number of others from the existing literature underscore the pressing need for the development of collaborative research to increase our understanding of the relationship between the geographical distribution of human and animal diseases in Nigeria and environmental factors. We submit that such knowledge is essential for the control and management of these diseases.

Small-scale geochemical cycles and the distribution of uranium in central and north Florida organic deposits

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bond, P.A.

1993-03-01

The global geochemical cycle for an element tracks its path from its various sources to its sinks via processes of weathering and transportation. The cycle may then be quantified in a necessarily approximate manner. The geochemical cycle (thus quantified) reveals constraints (known and unknown) on an element's behavior imposed by the various processes which act on it. In the context of a global geochemical cycle, a continent becomes essentially a source term. If, however, an element's behavior is examined in a local or regional context, sources and their related sinks may be identified. This suggests that small-scale geochemical cycles maymore » be superimposed on global geochemical cycles. Definition of such sub-cycles may clarify the distribution of an element in the earth's near-surface environment. In Florida, phosphate minerals of the Hawthorn Group act as a widely distributed source of uranium. Uranium is transported by surface- and ground-waters. Florida is the site of extensive wetlands and peatlands. The organic matter associated with these deposits adsorbs uranium and may act as a local sink depending on its hydrogeologic setting. This work examines the role of organic matter in the distribution of uranium in the surface and shallow subsurface environments of central and north Florida.« less

Integration of Geophysical and Geochemical Data

NASA Astrophysics Data System (ADS)

Yamagishi, Y.; Suzuki, K.; Tamura, H.; Nagao, H.; Yanaka, H.; Tsuboi, S.

2006-12-01

Integration of geochemical and geophysical data would give us a new insight to the nature of the Earth. It should advance our understanding for the dynamics of the Earth's interior and surface processes. Today various geochemical and geophysical data are available on Internet. These data are stored in various database systems. Each system is isolated and provides own format data. The goal of this study is to display both the geochemical and geophysical data obtained from such databases together visually. We adopt Google Earth as the presentation tool. Google Earth is virtual globe software and is provided free of charge by Google, Inc. Google Earth displays the Earth's surface using satellite images with mean resolution of ~15m. We display any graphical features on Google Earth by KML format file. We have developed softwares to convert geochemical and geophysical data to KML file. First of all, we tried to overlay data from Georoc and PetDB and seismic tomography data on Google Earth. Georoc and PetDB are both online database systems for geochemical data. The data format of Georoc is CSV and that of PetDB is Microsoft Excel. The format of tomography data we used is plain text. The conversion software can process these different file formats. The geochemical data (e. g. compositional abundance) is displayed as a three-dimensional column on the Earth's surface. The shape and color of the column mean the element type. The size and color tone vary according to the abundance of the element. The tomography data can be converted into a KML file for each depth. This overlay plot of geochemical data and tomography data should help us to correlate internal temperature anomalies to geochemical anomalies, which are observed at the surface of the Earth. Our tool can convert any geophysical and geochemical data to a KML as long as the data is associated with longitude and latitude. We are going to support more geophysical data formats. In addition, we are currently trying to obtain scientific insights for the Earth's interior based on the view of both geophysical and geochemical data on Google Earth.

Hydrochemical evaluation and identification of geochemical processes in the shallow and deep wells in the Ramganga Sub-Basin, India.

PubMed

Rajmohan, Natarajan; Patel, Neelam; Singh, Gaurav; Amarasinghe, Upali A

2017-09-01

Groundwater samples were collected from 44 wells in the Ramganga Sub-Basin (RSB), India, and analysed for major ions, nutrients and trace metals. The primary goal of this study is to evaluate the hydrochemistry and to identify the geochemical processes that govern the water chemistry in the shallow and deep tube wells in the study area using geochemical methods. The knowledge of changes in hydrochemistry of the aquifers is important for both groundwater recharge and use in the region. This study found that there are substantial differences of water chemistry between shallow and deep wells. In the shallow wells, the average concentrations of total dissolved solid (TDS), Na, K, Ca, Mg, HCO 3 , Cl, SO 4 , NO 3 , PO 4 , F, Cu, Mn, Fe and Cr are twofold higher than the deep wells. The concentrations of dissolved silica in the groundwater do not vary with the depth, which implies that the variation in the water chemistry is not due to mineral dissolution alone. Major ion ratios and saturation indices suggest that the water chemistry is predominantly controlled by dissolution of carbonate minerals, silicate weathering and ion exchange reactions. Thermodynamic evaluation (ion activity ratios and stability filed diagrams) indicates that the kaolinite and gibbsite controlled the water chemistry in the both shallow and deep wells. In addition, the groundwater chemistry in the shallow wells is affected by the vertical infiltration of contaminated water from surface contamination sources and nitrification process. In the deep wells, absence of NO 3 and low concentrations of Cl, SO 4 , PO 4 and F imply the role of regional flow and denitrification in the groundwater. Results concluded that proper management plan is necessary to protect the shallow aquifer in the RSB since shallow aquifer pumping is less expensive than the deeper one.

Geochemistry of surface sediments from the fjords of Northern Chilean Patagonia (44-47°S): Spatial variability and implications for paleoclimate reconstructions

NASA Astrophysics Data System (ADS)

Bertrand, Sébastien; Hughen, Konrad A.; Sepúlveda, Julio; Pantoja, Silvio

2012-01-01

The Patagonian fjords have a clear potential to provide high-resolution sedimentary and geochemical records of past climate and environmental change in the Southern Andes. To improve our ability to interpret these proxy records, we investigated the processes that control fjord sediment inorganic geochemistry through a geochemical, mineralogical and sedimentological analysis of surface sediment samples from the fjords of Northern Chilean Patagonia. A simple Terrestrial Index based on measurements of salinity and Fraction of Terrestrial Carbon was used to estimate the terrestrial input/river discharge at each site. Our results demonstrate that, under the cold climate conditions of Patagonia, chemical weathering is weak and the inorganic geochemical composition of the fjord sediments is primarily controlled by hydrodynamic mineralogical sorting, i.e., the intensity of river discharge. Our results suggest that the distribution of Fe, Ti and Zr in surface sediments is controlled by their association with heavy and/or coarse minerals, whereas Al is independent of hydrodynamic processes. The elemental ratios Fe/Al, Ti/Al and Zr/Al are therefore well suited for estimating changes in the energy of terrestrial sediment supply into the fjords through time. Zr/Al is particularly sensitive in proximal environments, while Fe/Al is most useful in the outer fjords and on the continental margin. In the most proximal environments, however, Fe/Al is inversely related to hydrodynamic conditions. Caution should therefore be exercised when interpreting Fe/Al ratios in terms of past river discharge. The application of these proxies to long sediment cores from Quitralco fjord and Golfo Elefantes validates our interpretations. Our results also emphasize the need to measure Al-based elemental ratios at high precision, which can be achieved using simultaneous acquisition ICP-AES technology. This study therefore constitutes a strong basis for the interpretation of sedimentary records from the Chilean Fjords.

Kinetically Controlled Alteration of the Chemical Record During Diagenesis: An Experimental Study on Hydrothermal Carbonate Replacement

NASA Astrophysics Data System (ADS)

Mueller, T.; Dohmen, R.; Jonas, L.; Immenhauser, A.

2016-12-01

The geological record stored in the geochemical composition of carbonates provides a direct source of information on the Earth systems. However, the robustness and accuracy of these key records can be compromised by post-depositional alteration of sediments, such as dolomitization during diagenesis or low temperature metamorphism. Hence, knowledge on the mechanisms and rates of these processes hold the key to evaluate the robustness of proxies or to evaluate the extent of geochemical alteration. Previously, we presented experimental results of hydrothermal alteration of single calcite crystals and aragonitic coral fragments leading to replacement of the original carbonate by a Ca-Mg carbonate phase of variable composition. The experiments revealed the formation of a multiphase reaction rim with multiple replacement fronts [1]. Here, the reaction rate as well as composition of the reaction products is controlled by element transport in the pore fluid. In this study we focus on the reaction path of the replacement reaction and its effect on the recorded Mg-isotope composition. XRD diffraction patterns suggest the initial precipitation of non-ordered protodolomite that is subsequently continuously recrystallizing over the duration of the experiments to form an ordered, albeit non-stoichiometric dolomite. These observations are in agreement with Mg-isotope composition measured of the bulk reaction rim showing a systematic evolution over time that cannot be explained by simple Rayleigh or equilibrium fractionation. We interpret these findings as additional, but delayed reaction fronts affecting the microstructure and chemical composition of the newly formed carbonate rim that are essentially decoupled from the initial replacement front. Our results highlight the need to quantitatively understand alteration processes during diagenesis in order to accurately interpret the preserved geochemical record stored in element and isotope ratios of carbonates. [1] Jonas L., Mueller T., Dohmen R., Baumgartner L., and Putlitz B. (2015): Transport-controlled hydrothermal replacement of calcite by Mg-carbonates, Geology, 43, 779-782.

Anthropogenic Increase Of Soil Erosion In The Gangetic Plain Revealed By Geochemical Budget Of Erosion

NASA Astrophysics Data System (ADS)

Galy, V.; France-Lanord, C.; Galy, A.; Gaillardet, J.

2007-12-01

Tectonic and climatic factors are the key natural variables controlling the erosion through complex interactions. Nonetheless, over the last few hundred years, human activity also exerts a dominant control in response to extensive land use. The geochemical budget of erosion allows the balance between the different erosion processes to be quantified. The chemical composition of river sediment results from the chemical composition of the source rock modified by (1) weathering reactions occurring during erosion and (2) physical segregation during transport. If erosion is at steady state, the difference between the chemical composition of source rocks and that of river sediments must therefore be counterbalanced by the dissolved flux. However, climatic variations or anthropic impact can induce changes in the erosion distribution in a given basin resulting in non steady state erosion. Using a mass balance approach, the comparison of detailed geochemical data on river sediments with the current flux of dissolved elements allows the steady state hypothesis to be tested. In this study, we present a geochemical budget of weathering for the Ganga basin, one of the most densely populated basin in the world, based on detailed sampling of Himalayan rivers and of the Ganga in the delta. Sampling includes depth profile in the river, to assess the variability generated by transport processes. Himalayan river sediments are described by the dilution of an aluminous component (micas + clays + feldspars) by quartz. Ganga sediments on the other hand correspond to the mixing of bedload, similar to coarse Himalayan sediments, with an aluminous component highly depleted in alkaline elements. Compared with the dissolved flux, the depletion of alkaline elements in Ganga sediments shows that the alkaline weathering budget is imbalanced. This imbalance results from an overabundance of fine soil material in the Ganga sediment relative to other less weathered material directly derived from Himalaya. Based on the average composition of the suspended load and of floodplain soils, we estimate that 250x106 t/yr i.e. 5 t/ha/yr is eroded from soil surfaces of the Ganga floodplain. This enhanced soil erosion is likely triggered by intense deforestation and change in land use due to increasing human activity in the basin.

A graphical method to evaluate predominant geochemical processes occurring in groundwater systems for radiocarbon dating

USGS Publications Warehouse

Han, Liang-Feng; Plummer, Niel; Aggarwal, Pradeep

2012-01-01

A graphical method is described for identifying geochemical reactions needed in the interpretation of radiocarbon age in groundwater systems. Graphs are constructed by plotting the measured 14C, δ13C, and concentration of dissolved inorganic carbon and are interpreted according to specific criteria to recognize water samples that are consistent with a wide range of processes, including geochemical reactions, carbon isotopic exchange, 14C decay, and mixing of waters. The graphs are used to provide a qualitative estimate of radiocarbon age, to deduce the hydrochemical complexity of a groundwater system, and to compare samples from different groundwater systems. Graphs of chemical and isotopic data from a series of previously-published groundwater studies are used to demonstrate the utility of the approach. Ultimately, the information derived from the graphs is used to improve geochemical models for adjustment of radiocarbon ages in groundwater systems.

The effects of sorting by aeolian processes on the geochemical characteristics of surface materials: a wind tunnel experiment

NASA Astrophysics Data System (ADS)

Wang, Xunming; Lang, Lili; Hua, Ting; Zhang, Caixia; Li, Hui

2018-03-01

The geochemical characteristics of aeolian and surface materials in potential source areas of dust are frequently employed in environmental reconstructions as proxies of past climate and as source tracers of aeolian sediments deposited in downwind areas. However, variations in the geochemical characteristics of these aeolian deposits that result from near-surface winds are currently poorly understood. In this study, we collected surface samples from the Ala Shan Plateau (a major potential dust source area in Central Asia) to determine the influence of aeolian processes on the geochemical characteristics of aeolian transported materials. Correlation analyses show that compared with surface materials, the elements in transported materials (e.g., Cu, As, Pb, Mn, Zn, Al, Ca, Fe, Ga, K, Mg, P, Rb, Co, Cr, Na, Nb, Si, and Zr) were subjected to significant sorting by aeolian processes, and the sorting also varied among different particle size fractions and elements. Variations in wind velocity were significantly correlated with the contents of Cr, Ga, Sr, Ca, Y, Nd, Zr, Nb, Ba, and Al, and with the Zr/Al, Zr/Rb, K/Ca, Sr/Ca, Rb/Sr, and Ca/Al ratios. Given the great variation in the geochemical characteristics of materials transported under different aeolian processes relative to those of the source materials, these results indicate that considerable uncertainty may be introduced to analyses by using surface materials to trace the potential source areas of aeolian deposits that accumulate in downwind areas.

Uncertainty quantification and experimental design based on unsupervised machine learning identification of contaminant sources and groundwater types using hydrogeochemical data

NASA Astrophysics Data System (ADS)

Vesselinov, V. V.

2017-12-01

Identification of the original groundwater types present in geochemical mixtures observed in an aquifer is a challenging but very important task. Frequently, some of the groundwater types are related to different infiltration and/or contamination sources associated with various geochemical signatures and origins. The characterization of groundwater mixing processes typically requires solving complex inverse models representing groundwater flow and geochemical transport in the aquifer, where the inverse analysis accounts for available site data. Usually, the model is calibrated against the available data characterizing the spatial and temporal distribution of the observed geochemical species. Numerous geochemical constituents and processes may need to be simulated in these models which further complicates the analyses. As a result, these types of model analyses are typically extremely challenging. Here, we demonstrate a new contaminant source identification approach that performs decomposition of the observation mixtures based on Nonnegative Matrix Factorization (NMF) method for Blind Source Separation (BSS), coupled with a custom semi-supervised clustering algorithm. Our methodology, called NMFk, is capable of identifying (a) the number of groundwater types and (b) the original geochemical concentration of the contaminant sources from measured geochemical mixtures with unknown mixing ratios without any additional site information. We also demonstrate how NMFk can be extended to perform uncertainty quantification and experimental design related to real-world site characterization. The NMFk algorithm works with geochemical data represented in the form of concentrations, ratios (of two constituents; for example, isotope ratios), and delta notations (standard normalized stable isotope ratios). The NMFk algorithm has been extensively tested on synthetic datasets; NMFk analyses have been actively performed on real-world data collected at the Los Alamos National Laboratory (LANL) groundwater sites related to Chromium and RDX contamination.

Geochemical Monitoring Considerations for the FutureGen 2.0 Project

DOE PAGES

Amonette, James E.; Johnson, Timothy A.; Spencer, Clayton F.; ...

2014-12-31

Geochemical monitoring is an essential component of a suite of monitoring technologies designed to evaluate CO2 mass balance and detect possible loss of containment at the FutureGen 2.0 geologic sequestration site near Jacksonville, IL. This presentation gives an overview of the potential geochemical approaches and tracer technologies that were considered, and describes the evaluation process by which the most cost-effective and robust of these were selected for implementation

Geochemical baseline distribution of harmful elements in the surface soils of Campania region.

NASA Astrophysics Data System (ADS)

Albanese, Stefano; Lima, Annamaria; Qu, Chengkai; Cicchella, Domenico; Buccianti, Antonella; De Vivo, Benedetto

2015-04-01

Environmental geochemical mapping has assumed an increasing relevance and the separation of values to discriminate between anthropogenic pollution and natural (geogenic) sources has become crucial to address environmental problems affecting the quality of life of human beings. In the last decade, a number of geochemical prospecting projects, mostly focused on surface soils (topsoils), were carried out at different scales (from regional to local) across the whole Campania region (Italy) to characterize the distribution of both harmful elements and persistent organic pollutants (POP) in the environment and to generating a valuable database to serve as reference in developing geomedical studies. During the 2014, a database reporting the distribution of 53 chemical elements in 3536 topsoil samples, collected across the whole region, was completed. The geochemical data, after necessary quality controls, were georeferenced and processed in a geochemistry dedicated GIS software named GEODAS. For each considered element a complete set of maps was generated to depict both the discrete and the spatially continuous (interpolated) distribution of elemental concentrations across the region. The interpolated maps were generated using the Multifractal Inverse Distance eighted (MIDW) algorithm. Subsequently, the S-A method, also implemented in GEODAS, was applied to MIDW maps to eliminate spatially limited anomalies from the original grid and to generate the distribution patterns of geochemical baselines for each element. For a selected group of elements geochemical data were also treated by means of a Compositional Data Analysis (CoDA) aiming at investigating the regionalised structure of the data by considering the joint behaviour of several elements constituting for each sample its whole composition. A regional environmental risk assessment was run on the basis of the regional distribution of heavy metals in soil, land use types and population. The risk assessment produced a ranking of priorities and located areas of regional territory where human health risk is more relevant and follow-up activities are required.

Geochemistry of serpentinites in subduction zones: A review

NASA Astrophysics Data System (ADS)

Deschamps, Fabien; Godard, Marguerite; Guillot, Stéphane; Hattori, Kéiko

2013-04-01

Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zones geodynamics. Their presence and effective role in this environment is acknowledged notably by geophysical, geochemical and field observations of (paleo-) subduction zones. In this context, with the increasing amount of studies concerning serpentinites in subduction environments, a huge geochemical database was created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical analyses of abyssal, mantle wedge and subducted serpentinites. The aim was to better understand the geochemical evolution of these rocks during their subduction history as well as their impact in the global geochemical cycle. When studying serpentinites, it is often a challenge to determine the nature of the protolith and their geological history before serpentinisation. The present-day (increasing) geochemical database for serpentinites indicates little to no mobility of incompatible elements at the scale of the hand-sample in most serpentinized peridotites. Thus, Rare Earth Elements (REE) distribution can be used to identify the initial protolith for abyssal and mantle wedge serpentinites, as well as magmatic processes such as melt/rock interactions taking place before serpentinisation. In the case of subducted serpentinites, the interpretation of trace element data is more difficult due to secondary enrichments independent of the nature of the protolith, notably in (L)REE. We propose that these enrichments reflect complex interactions probably not related to serpentinisation itself, but mostly to fluid/rock or sediment/rock interactions within the subduction channel, as well as intrinsic feature of the mantle protolith which could derive from the continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous studies have been carried out, notably using in situ approaches, to better constrain the geochemical budget of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) stored in serpentinites and serpentine phases. These elements are good markers of the fluid/rock interactions taking place during serpentinisation. Today, the control of serpentinites on the behaviour of these elements, from their incorporation to their gradually release during subduction, is better understood. Serpentinites must be considered as a component of the FME budget in subduction zones and their role, notably on arc magmas composition, is undoubtedly underestimated presently in the global geochemical cycle.

A geochemical examination of humidity cell tests

USGS Publications Warehouse

Maest, Ann; Nordstrom, D. Kirk

2017-01-01

Humidity cell tests (HCTs) are long-term (20 to >300 weeks) leach tests that are considered by some to be the among the most reliable geochemical characterization methods for estimating the leachate quality of mined materials. A number of modifications have been added to the original HCT method, but the interpretation of test results varies widely. We suggest that the HCTs represent an underutilized source of geochemical data, with a year-long test generating approximately 2500 individual chemical data points. The HCT concentration peaks and valleys can be thought of as a “chromatogram” of reactions that may occur in the field, whereby peaks in concentrations are associated with different geochemical processes, including sulfate salt dissolution, sulfide oxidation, and dissolution of rock-forming minerals, some of which can neutralize acid. Some of these reactions occur simultaneously, some do not, and geochemical modeling can be used to help distinguish the dominant processes. Our detailed examination, including speciation and inverse modeling, of HCTs from three projects with different geology and mineralization shows that rapid sulfide oxidation dominates over a limited period of time that starts between 40 and 200 weeks of testing. The applicability of laboratory tests results to predicting field leachate concentrations, loads, or rates of reaction has not been adequately demonstrated, although early flush releases and rapid sulfide oxidation rates in HCTs should have some relevance to field conditions. Knowledge of possible maximum solute concentrations is needed to design effective treatment and mitigation approaches. Early flush and maximum sulfide oxidation results from HCTs should be retained and used in environmental models. Factors that complicate the use of HCTs include: sample representation, time for microbial oxidizers to grow, sample storage before testing, geochemical reactions that add or remove constituents, and the HCT results chosen for use in modeling the environmental performance at mine sites. Improved guidance is needed for more consistent interpretation and use of HCT results that rely on identifying: the geochemical processes; the mineralogy, including secondary mineralogy; the available surface area for reactions; and the influence of hydrologic processes on leachate concentrations in runoff, streams, and groundwater.

Resource Management Technology: Los Alamos Technical Capabilities for Emergency Management,

DTIC Science & Technology

1983-07-18

synthetic fuels from coal (analogous to the Fischer-Tropsch process), olefin polymerization, and flue - gas desulfurization . In order to successfully...world. It has been a major research effort here for decades. Also, in the area of desulfurization of flue gases, Los Alamos scientists have been...Tectonic and Geochemical Controls on Copper-Molybdenum Porphyry Mineralization in the Southwestern United States (M. J. Aldrich and A. W. Laughlin) 1.0.6

Geochemical Modeling of Carbon Sequestration, MMV, and EOR in the Illinois Basin

USGS Publications Warehouse

Berger, P.M.; Roy, W.R.; Mehnert, E.

2009-01-01

The Illinois State Geologic Survey is conducting several ongoing CO2 sequestration projects that require geochemical models to gain an understanding of the processes occurring in the subsurface. The ISGS has collected brine and freshwater samples associated with an enhanced oil recovery project in the Loudon oil field. Geochemical modeling allows us to understand reactions with carbonate and silicate minerals in the reservoir, and the effects they have had on brine composition. For the Illinois Basin Decatur project, geochemical models should allow predictions of the reactions that will take place before CO2 injection begins. ?? 2009 Elsevier Ltd. All rights reserved.

Electrical characterization of non‐Fickian transport in groundwater and hyporheic systems

USGS Publications Warehouse

Singha, Kamini; Pidlisecky, Adam; Day-Lewis, Frederick D.; Gooseff, Michael N.

2008-01-01

Recent work indicates that processes controlling solute mass transfer between mobile and less mobile domains in porous media may be quantified by combining electrical geophysical methods and electrically conductive tracers. Whereas direct geochemical measurements of solute preferentially sample the mobile domain, electrical geophysical methods are sensitive to changes in bulk electrical conductivity (bulk EC) and therefore sample EC in both the mobile and immobile domains. Consequently, the conductivity difference between direct geochemical samples and remotely sensed electrical geophysical measurements may provide an indication of mass transfer rates and mobile and immobile porosities in situ. Here we present (1) an overview of a theoretical framework for determining parameters controlling mass transfer with electrical resistivity in situ; (2) a review of a case study estimating mass transfer processes in a pilot‐scale aquifer storage recovery test; and (3) an example application of this method for estimating mass transfer in watershed settings between streams and the hyporheic corridor. We demonstrate that numerical simulations of electrical resistivity studies of the stream/hyporheic boundary can help constrain volumes and rates of mobile‐immobile mass transfer. We conclude with directions for future research applying electrical geophysics to understand field‐scale transport in aquifer and fluvial systems subject to rate‐limited mass transfer.

Sediment transport dynamics in the Central Himalaya: assessing during monsoon the erosion processes signature in the daily suspended load of the Narayani river

NASA Astrophysics Data System (ADS)

Morin, Guillaume; Lavé, Jérôme; Lanord, Christian France; Prassad Gajurel, Ananta

2017-04-01

The evolution of mountainous landscapes is the result of competition between tectonic and erosional processes. In response to the creation of topography by tectonics, fluvial, glacial, and hillslope denudation processes erode topography, leading to rock exhumation and sediment redistribution. When trying to better document the links between climate, tectonic, or lithologic controls in mountain range evolution, a detailed understanding of the influence of each erosion process in a given environment is fundamental. At the scale of a whole mountain range, a systematic survey and monitoring of all the geomorphologic processes at work can rapidly become difficult. An alternative approach can be provided by studying the characteristics and temporal evolution of the sediments exported out of the range. In central Himalaya, the Narayani watershed presents contrasted lithologic, geochemical or isotopic signatures of the outcropping rocks as well as of the erosional processes: this particular setting allows conducting such type of approach by partly untangling the myopic vision of the spatial integration at the watershed scale. Based on the acquisition and analysis of a new dataset on the daily suspended load concentration and geochemical characteristics at the mountain outlet of one of the largest Himalayan rivers (drainage area = 30000 km2) bring several important results on Himalayan erosion, and on climatic and process controls. 1. Based on discrete depth sampling and on daily surface sampling of suspended load associated to flow characterization through ADCP measurements, we were first able to integrate sediment flux across a river cross-section and over time. We estimate for 2010 year an equivalent erosion rate of 1.8 +0.35/-0.2 mm/yr, and over the last 15 years, using past sediment load records from the DHM of Nepal, an equivalent erosion rate of 1.6 +0.3/-0.2 mm/yr. These rates are also in close agreement with the longer term ( 500 yrs) denudation rates of 1.7 mm/yr obtained from cosmonuclides in Narayani river sands (Lupker et al. 2012). Such stability of the erosion rates suggests that either buffering behaviour of this large watershed or broad spatial integration dampen the variability in monsoon strength or the sporadic nature of extreme mass-wasting events. 2. Paradoxically, the relatively high variability of the daily geochemical signature in suspended load and the apparent absence of delay between high rainfall episodes and sediment export suggest very short transfer time for silt and medium sand load, despite fluvial transfer distance of hundreds of kilometres between the sediment sources and the mountain outlet. This implies the absence of a buffering behaviour of the fluvial network and a very reactive fluvial system, which would be strongly supply limited relative to the fine sediment fraction. 3. By analysing sediments fluxes and using geochemical compositions in deltaD, carbonates content and TOC, which we propose as possible tracers for glacier- and soil-derived material, we show that glacier and soil erosion contribute to annual erosion budget to less than 10% and a few % respectively. Their imprints in Narayani sediment is only visible during the pre- and early monsoon before being overwhelmed by landslide-derived material during the monsoon. 4. Hillslope erosion by landslides appears therefore as the dominant erosional process in central Himalaya, and by comparing the sediment export history to a rainfall/runoff model, we confirm Gabet et al.'s (2004) inference that sediment export and possibly landslide triggering on Himalayan hillslopes are controlled both by pore pressure (depending on cumulated precipitation) and daily rainfall intensity.

Selected Geochemical Data for Modeling Near-Surface Processes in Mineral Systems

USGS Publications Warehouse

Giles, Stuart A.; Granitto, Matthew; Eppinger, Robert G.

2009-01-01

The database herein was initiated, designed, and populated to collect and integrate geochemical, geologic, and mineral deposit data in an organized manner to facilitate geoenvironmental mineral deposit modeling. The Microsoft Access database contains data on a variety of mineral deposit types that have variable environmental effects when exposed at the ground surface by mining or natural processes. The data tables describe quantitative and qualitative geochemical analyses determined by 134 analytical laboratory and field methods for over 11,000 heavy-mineral concentrate, rock, sediment, soil, vegetation, and water samples. The database also provides geographic information on geology, climate, ecoregion, and site contamination levels for over 3,000 field sites in North America.

The use of multifractal modelling for targeting resources from soil and stream geochemistry data: the case of the Variscan basement of the Iberian Peninsula

NASA Astrophysics Data System (ADS)

Gonçalves, Mario; Mateus, Antonio

2016-04-01

The safeguarding of access/use of many critical raw materials for Society requires that much of previously dismissed areas for exploration must be re-evaluated with new criteria in which the significance of "anomaly" should not be treated independently of the geochemical signals of the ore-forming processes and how the different chemical elements are interrelated. For much of the previous decade, several multifractal methods were methodically being refined as automatic tools to analyze and detect geochemical anomalies. These included the early concentration-area method (Cheng et al., 1994), singularity mapping (Cheng, 2007), and spectrum-area (Cheng et al., 2000), which has been recently combined with the bi-dimensional empirical mode decomposition (Xu et al., 2016) as a tool to separate different contributing sources of an otherwise complex geochemical pattern. We propose yet another approach, the use of geochemical indexes, which links to the geological and ore-forming processes known to define a given region in order to assess much of these numerical approaches. Therefore, we picked several areas from the Variscan basement in Portugal, with different geologic and metallogentic contexts, some of them previously analyzed with multifractal methods (Gonçalves et al., 2001; Jesus et al., 2013) and a multi-element geochemical campaign on which to test the different multifractal methods combined with the geochemical indexes, as an advantageous alternative to principal component mapping, for example. Some preliminary essays with stochastic models similar to those reported in Gonçalves (2001) and Agterberg (2007), with different overprinted pulses are presented as well. Acknowledgments: This is a contribution from UID/GEO/50019/2013 - Instituto Dom Luiz, supported by FCT. Agterberg, 2007, Math. Geol., 39, 1. Cheng et al, 1994, J. Geochem. Explor., 51, 109. Cheng et al., 2000, Nat. Resour. Res, 9, 43. Cheng, 2007, Ore Geol. Rev., 32, 314. Gonçalves, 2001, Math. Geol., 33, 41. Gonçalves et al., 2001, J. Geochem. Explor., 72, 91. Jesus et al., 2013, J. Geochem. Explor., 126-127, 23. Xu et al., 2016, J. Geochem. Explor., in press

Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas, West Bengal, India

NASA Astrophysics Data System (ADS)

Sahu, Paulami; Sikdar, P. K.; Chakraborty, Surajit

2016-02-01

Detailed geochemical analysis of groundwater beneath 1223 km2 area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: `excellent', `good' and `poor' and seven hydrochemical facies are assigned to three broad types: `fresh', `mixed' and `brackish' waters. The `fresh' water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich `brackish' groundwater represents freshening of modified connate water. The `mixed' type groundwater has possibly evolved due to hydraulic mixing of `fresh' and `brackish' waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.

TAPIR--Finnish national geochemical baseline database.

PubMed

Jarva, Jaana; Tarvainen, Timo; Reinikainen, Jussi; Eklund, Mikael

2010-09-15

In Finland, a Government Decree on the Assessment of Soil Contamination and Remediation Needs has generated a need for reliable and readily accessible data on geochemical baseline concentrations in Finnish soils. According to the Decree, baseline concentrations, referring both to the natural geological background concentrations and the diffuse anthropogenic input of substances, shall be taken into account in the soil contamination assessment process. This baseline information is provided in a national geochemical baseline database, TAPIR, that is publicly available via the Internet. Geochemical provinces with elevated baseline concentrations were delineated to provide regional geochemical baseline values. The nationwide geochemical datasets were used to divide Finland into geochemical provinces. Several metals (Co, Cr, Cu, Ni, V, and Zn) showed anomalous concentrations in seven regions that were defined as metal provinces. Arsenic did not follow a similar distribution to any other elements, and four arsenic provinces were separately determined. Nationwide geochemical datasets were not available for some other important elements such as Cd and Pb. Although these elements are included in the TAPIR system, their distribution does not necessarily follow the ones pre-defined for metal and arsenic provinces. Regional geochemical baseline values, presented as upper limit of geochemical variation within the region, can be used as trigger values to assess potential soil contamination. Baseline values have also been used to determine upper and lower guideline values that must be taken into account as a tool in basic risk assessment. If regional geochemical baseline values are available, the national guideline values prescribed in the Decree based on ecological risks can be modified accordingly. The national geochemical baseline database provides scientifically sound, easily accessible and generally accepted information on the baseline values, and it can be used in various environmental applications. Copyright 2010 Elsevier B.V. All rights reserved.

Numerical investigation of coupled density-driven flow and hydrogeochemical processes below playas

NASA Astrophysics Data System (ADS)

Hamann, Enrico; Post, Vincent; Kohfahl, Claus; Prommer, Henning; Simmons, Craig T.

2015-11-01

Numerical modeling approaches with varying complexity were explored to investigate coupled groundwater flow and geochemical processes in saline basins. Long-term model simulations of a playa system gain insights into the complex feedback mechanisms between density-driven flow and the spatiotemporal patterns of precipitating evaporites and evolving brines. Using a reactive multicomponent transport model approach, the simulations reproduced, for the first time in a numerical study, the evaporite precipitation sequences frequently observed in saline basins ("bull's eyes"). Playa-specific flow, evapoconcentration, and chemical divides were found to be the primary controls for the location of evaporites formed, and the resulting brine chemistry. Comparative simulations with the computationally far less demanding surrogate single-species transport models showed that these were still able to replicate the major flow patterns obtained by the more complex reactive transport simulations. However, the simulated degree of salinization was clearly lower than in reactive multicomponent transport simulations. For example, in the late stages of the simulations, when the brine becomes halite-saturated, the nonreactive simulation overestimated the solute mass by almost 20%. The simulations highlight the importance of the consideration of reactive transport processes for understanding and quantifying geochemical patterns, concentrations of individual dissolved solutes, and evaporite evolution.

Chemical and U-Sr isotopic variations in stream and source waters of the Strengbach watershed (Vosges mountains, France)

NASA Astrophysics Data System (ADS)

Pierret, M. C.; Stille, P.; Prunier, J.; Viville, D.; Chabaux, F.

2014-10-01

This is the first comprehensive study dealing with major and trace element data as well as 87Sr/86Sr isotope and (234U/238U) activity ratios (AR) determined on the totality of springs and brooks of the Strengbach catchment. It shows that the small and more or less monolithic catchment drains different sources and streamlets with very different isotopic and geochemical signatures. Different parameters control the diversity of the source characteristics. Of importance is especially the hydrothermal overprint of the granitic bedrock, which was stronger for the granite from the northern slope; also significant are the different meteoric alteration processes of the bedrock causing the formation of 0.5 to 9 m thick saprolite and above the formation of an up to 1m thick soil system. These processes mainly account for springs and brooks from the northern slope having higher Ca / Na, Mg / Na, and Sr / Na ratios, but lower 87Sr/86Sr isotopic ratios than those from the southern slope. The chemical compositions of the source waters in the Strengbach catchment are only to a small extent the result of alteration of primary bedrock minerals, and rather reflect dissolution/precipitation processes of secondary mineral phases like clay minerals. The (234U/238U) AR, however, are decoupled from the 87Sr/86Sr isotope system, and reflect to some extent the level of altitude of the source and, thus, the degree of alteration of the bedrock. The sources emerging at high altitudes have circulated through already weathered materials (saprolite and fractured bedrock depleted in 234U), implying (234U/238U) AR below 1, which is uncommon for surface waters. Preferential flow paths along constant fractures in the bedrocks might explain the - over time - homogeneous U AR of the different spring waters. However, the geochemical and isotopic variations of stream waters at the outlet of the catchment are controlled by variable contributions of different springs, depending on the hydrological conditions. It appears that the (234U/238U) AR are a very appropriate, important tracer for studying and deciphering the contribution of the different source fluxes at the catchment scale, because this unique geochemical parameter is different for each individual spring and at the same time remains unchanged for each of the springs with changing discharge and fluctuating hydrological conditions. This study further highlights the important impact of different and independent water pathways on fractured granite controlling the different geochemical and isotopic signatures of the waters. Despite the fact that soils and vegetation cover have a great influence on the water cycle balance (evapotranspiration, drainage, runoff), the chemical compositions of waters are strongly modified by processes occurring in deep saprolite and bedrock rather than in soils along the specific water pathways.

Effects of carbon dioxide variations in the unsaturated zone on water chemistry in a glacial-outwash aquifer

USGS Publications Warehouse

Lee, R.W.

1997-01-01

The research site at Otis Air Base, Cape Cod, Massachusetts, has been developed for hydrogeological and geochemical studies of sewage-effluent contaminated groundwater since 1982. Research of hydrologic properties, transport, and chemical and biological processes is ongoing, but the origin of background water chemistry has not been determined. The principal geochemical process giving rise to the observed background water chemistry is CO2-controlled hydrolysis of Na feldspar. Geochemical modeling demonstrated that CO2 sources could vary over the project area. Analyses of unsaturated zone gases showed variations in CO2 which were dependent on land use and vegetative cover in the area of groundwater recharge. Measurements of CO2 in unsaturated-zone gases showed that concentrations of total inorganic C in recharge water should range from about 0.035 to 1.0 mmoles/L in the vicinity of Otis Air Base. Flux of CO2 from the unsaturated zone varied for a principal land uses, ranging from 86 gC/m2/yr for low vegetated areas to 1630 gC/m2/yr for a golf course. Carbon dioxide flux from woodlands was 220 gC/m2/yr, lower than reported fluxes of 500 to 600 gC/m2/yr for woodlands in a similar climate. Carbon dioxide flux from grassy areas was 540 gC/m2/yr, higher than reported fluxes of 230 to 490 gC/m2/yr for grasslands in a similar climate.

Hyporheic zone influences on concentration-discharge relationships in a headwater sandstone stream

NASA Astrophysics Data System (ADS)

Hoagland, Beth; Russo, Tess A.; Gu, Xin; Hill, Lillian; Kaye, Jason; Forsythe, Brandon; Brantley, Susan L.

2017-06-01

Complex subsurface flow dynamics impact the storage, routing, and transport of water and solutes to streams in headwater catchments. Many of these hydrogeologic processes are indirectly reflected in observations of stream chemistry responses to rain events, also known as concentration-discharge (CQ) relations. Identifying the relative importance of subsurface flows to stream CQ relationships is often challenging in headwater environments due to spatial and temporal variability. Therefore, this study combines a diverse set of methods, including tracer injection tests, cation exchange experiments, geochemical analyses, and numerical modeling, to map groundwater-surface water interactions along a first-order, sandstone stream (Garner Run) in the Appalachian Mountains of central Pennsylvania. The primary flow paths to the stream include preferential flow through the unsaturated zone ("interflow"), flow discharging from a spring, and groundwater discharge. Garner Run stream inherits geochemical signatures from geochemical reactions occurring along each of these flow paths. In addition to end-member mixing effects on CQ, we find that the exchange of solutes, nutrients, and water between the hyporheic zone and the main stream channel is a relevant control on the chemistry of Garner Run. CQ relationships for Garner Run were compared to prior results from a nearby headwater catchment overlying shale bedrock (Shale Hills). At the sandstone site, solutes associated with organo-mineral associations in the hyporheic zone influence CQ, while CQ trends in the shale catchment are affected by preferential flow through hillslope swales. The difference in CQ trends document how the lithology and catchment hydrology control CQ relationships.

Strategies to predict metal mobility in surficial mining environments

USGS Publications Warehouse

Smith, Kathleen S.

2007-01-01

This report presents some strategies to predict metal mobility at mining sites. These strategies are based on chemical, physical, and geochemical information about metals and their interactions with the environment. An overview of conceptual models, metal sources, and relative mobility of metals under different geochemical conditions is presented, followed by a discussion of some important physical and chemical properties of metals that affect their mobility, bioavailability, and toxicity. The physical and chemical properties lead into a discussion of the importance of the chemical speciation of metals. Finally, environmental and geochemical processes and geochemical barriers that affect metal speciation are discussed. Some additional concepts and applications are briefly presented at the end of this report.

Temporal dynamics of biogeochemical processes at the Norman Landfill site

USGS Publications Warehouse

Arora, Bhavna; Mohanty, Binayak P.; McGuire, Jennifer T.; Cozzarelli, Isabelle M.

2013-01-01

The temporal variability observed in redox sensitive species in groundwater can be attributed to coupled hydrological, geochemical, and microbial processes. These controlling processes are typically nonstationary, and distributed across various time scales. Therefore, the purpose of this study is to investigate biogeochemical data sets from a municipal landfill site to identify the dominant modes of variation and determine the physical controls that become significant at different time scales. Data on hydraulic head, specific conductance, δ2H, chloride, sulfate, nitrate, and nonvolatile dissolved organic carbon were collected between 1998 and 2000 at three wells at the Norman Landfill site in Norman, OK. Wavelet analysis on this geochemical data set indicates that variations in concentrations of reactive and conservative solutes are strongly coupled to hydrologic variability (water table elevation and precipitation) at 8 month scales, and to individual eco-hydrogeologic framework (such as seasonality of vegetation, surface-groundwater dynamics) at 16 month scales. Apart from hydrologic variations, temporal variability in sulfate concentrations can be associated with different sources (FeS cycling, recharge events) and sinks (uptake by vegetation) depending on the well location and proximity to the leachate plume. Results suggest that nitrate concentrations show multiscale behavior across temporal scales for different well locations, and dominant variability in dissolved organic carbon for a closed municipal landfill can be larger than 2 years due to its decomposition and changing content. A conceptual framework that explains the variability in chemical concentrations at different time scales as a function of hydrologic processes, site-specific interactions, and/or coupled biogeochemical effects is also presented.

Geochemical evolution of groundwater in the Western Delta region of River Godavari, Andhra Pradesh, India

NASA Astrophysics Data System (ADS)

Nageswara Rao, P. V.; Appa Rao, S.; Subba Rao, N.

2017-05-01

The present study on geochemical evolution of groundwater is taken up to assess the controlling processes of water chemistry in the Western Delta region of the River Godavari (Andhra Pradesh), which is one of the major rice-producing centers in India. The study region is underlain by coarse sand with black clay (buried channels), black silty clay of recent origin (floodplain) and gray/white fine sand of modern beach sediment of marine source (coastal zone), including brown silty clay with fine sand (paleo-beach ridges). Groundwater is mostly brackish and very hard. It is characterized by Na+ > Mg2+ > Ca2+:HCO3 - > Cl- > SO4 2- > NO3 -, Na+ > Mg2+ > Ca2+:Cl- > HCO3 - > SO4 2-, and Mg2+ > Na+ > Ca2+ > or < K+:HCO3 - > Cl- > or > SO4 2- facies. The ionic relations (Ca2+ + Mg2+:HCO3 -, Ca2+ + Mg2+:SO4 2- + HCO3 -, Na+ + K+:TC, Na+ + K+:Cl- + SO4 2-, HCO3 -:TC, HCO3 -:Ca2+ + Mg2+, Na+:Cl- and Na+:Ca2+) indicate that the rock weathering, mineral dissolution, evaporation and ion exchange are the processes to control the aquifer chemistry. Anthropogenic and marine sources are also the supplementary factors for brackish water quality. These observations are further supported by Gibbs mechanisms that control the water chemistry. Thus, the study suggests that the initial quality of groundwater of geogenic origin has been subsequently modified by the influences of anthropogenic and marine sources.

Geochemical and modal data for igneous rocks associated with epithermal mineral deposits

USGS Publications Warehouse

du Bray, Edward A.

2014-01-01

The purposes of this report are to (1) present available geochemical and modal data for igneous rocks associated with epithermal mineral deposits and (2) to make those data widely and readily available for subsequent, more in-depth consideration and interpretation. Epithermal precious and base-metal deposits are commonly associated with subduction-related calc-alkaline to alkaline arc magmatism as well as back-arc continental rift magmatism. These deposits form in association with compositionally diverse extrusive and intrusive igneous rocks. Temperature and depth regimes prevailing during deposit formation are highly variable. The deposits form from hydrothermal fluids that range from acidic to near-neutral pH, and they occur in a variety of structural settings. The disparate temperature, pressure, fluid chemistry, and structural controls have resulted in deposits with wide ranging characteristics. Economic geologists have employed these characteristics to develop classification schemes for epithermal deposits and to constrain the important genetic processes responsible for their formation.

Geochemical and Mineralogical Indicators for Aqueous Processes on the West Spur of the Columbia Hills in Gusev Crater

NASA Technical Reports Server (NTRS)

Ming, D. W.; Morris, R. V.; Gellert, R.; Yen, A.; Bell, J. F., III; Blaney, D.; Christensen, P. R.; Crumpler, L.; Chu, P.; Farrand, W. H.

2005-01-01

The primary objective of the MER Spirit and Opportunity Rovers is to identify and investigate rocks, outcrops, and soils that have the highest possible chance of preserving evidence of water activity on Mars. The Athena Science Instrument Payload onboard the two rovers has provided geochemical and mineralogical information that indicates a variety of aqueous processes and various degrees of alteration at the two landing sites.

Methane related changes in prokaryotic activity along geochemical profiles in sediments of Lake Kinneret (Israel)

NASA Astrophysics Data System (ADS)

Bar Or, I.; Ben-Dov, E.; Kushmaro, A.; Eckert, W.; Sivan, O.

2014-06-01

Microbial methane oxidation process (methanotrophy) is the primary control on the emission of the greenhouse gas methane (CH4) to the atmosphere. In terrestrial environments, aerobic methanotrophic bacteria are mainly responsible for oxidizing the methane. In marine sediments the coupling of the anaerobic oxidation of methane (AOM) with sulfate reduction, often by a consortium of anaerobic methanotrophic archaea (ANME) and sulfate reducing bacteria, was found to consume almost all the upward diffusing methane. Recently, we showed geochemical evidence for AOM driven by iron reduction in Lake Kinneret (LK) (Israel) deep sediments and suggested that this process can be an important global methane sink. The goal of the present study was to link the geochemical gradients found in the porewater (chemical and isotope profiles) with possible changes in microbial community structure. Specifically, we examined the possible shift in the microbial community in the deep iron-driven AOM zone and its similarity to known sulfate driven AOM populations. Screening of archaeal 16S rRNA gene sequences revealed Thaumarchaeota and Euryarchaeota as the dominant phyla in the sediment. Thaumarchaeota, which belongs to the family of copper containing membrane-bound monooxgenases, increased with depth while Euryarchaeota decreased. This may indicate the involvement of Thaumarchaeota, which were discovered to be ammonia oxidizers but whose activity could also be linked to methane, in AOM in the deep sediment. ANMEs sequences were not found in the clone libraries, suggesting that iron-driven AOM is not through sulfate. Bacterial 16S rRNA sequences displayed shifts in community diversity with depth. Proteobacteria and Chloroflexi increased with depth, which could be connected with their different dissimilatory anaerobic processes. The observed changes in microbial community structure suggest possible direct and indirect mechanisms for iron-driven AOM in deep sediments.

Long-Term Data Reveal Patterns and Controls on Stream Water Chemistry in a Forested Stream: Walker Branch, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lutz, Brian D; Mulholland, Patrick J; Bernhardt, Emily

2012-01-01

We present 20 years of weekly stream water chemistry, hydrology, and climate data for the Walker Branch watershed in eastern Tennessee, USA. Since 1989, the watershed has experienced a similar to 1.08 degrees C increase in mean annual temperature, a similar to 20% decline in precipitation, and a similar to 30% increase in forest evapotranspiration rates. As a result, stream runoff has declined by similar to 34%. We evaluate long-term trends in stream water concentrations and fluxes for nine solutes and use wet deposition data to calculate approximate watershed input-output budgets. Dissolved constituents were classified as geochemical solutes (Ca2+, Mg2+,more » and SO42-) or nutrients (NH4+, NO3-, soluble reactive phosphorus [SRP], total soluble nitrogen [TSN], total soluble phosphorus [TSP], and dissolved organic carbon [DOC]). Geochemical solutes are predominantly controlled by discharge, and the long-term changes in catchment hydrology have led to significant trends in the concentrations and fluxes of these solutes. Further, the trends in geochemical solute concentrations indicate shifting soil flowpath contributions to streamflow generation through time, with deep groundwater having a greater proportional contribution in recent years. Despite dramatic changes in watershed runoff, there were no trends in inorganic nutrient concentrations (NH4+, NO3-, and SRP). While most nutrients entering the watershed are retained, stream fluxes of nutrient solutes have declined significantly as a result of decreasing runoff. Nutrient concentrations in the stream exhibit large seasonality controlled by in-stream biological uptake. Stream benthic communities are sensitive to hydrologic disturbance, and changes in the frequency or intensity of storm events through time can affect nutrient fluxes. Stream NO3- concentrations are also sensitive to drought, with concentrations decreasing (increasing) if conditions during the three years prior to the time of sampling were drier (wetter) than the long-term mean. Future changes in the incidence of storm events, as well as the number and duration of droughts, have the potential to significantly alter watershed nutrient losses. Our analysis indicates that changing climates can differentially affect watershed element cycles either through changes in biogeochemical process rates or through changes in catchment hydrology. Furthermore, climate change can include both long-term trending in mean climate variables, as well as changes in the frequency and intensity of storms and droughts, with each of these types of change having distinct effects on the biological and geochemical processes governing different solutes.« less

Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Jinsong

2013-05-01

Development of a hierarchical Bayesian model to estimate the spatiotemporal distribution of aqueous geochemical parameters associated with in-situ bioremediation using surface spectral induced polarization (SIP) data and borehole geochemical measurements collected during a bioremediation experiment at a uranium-contaminated site near Rifle, Colorado. The SIP data are first inverted for Cole-Cole parameters including chargeability, time constant, resistivity at the DC frequency and dependence factor, at each pixel of two-dimensional grids using a previously developed stochastic method. Correlations between the inverted Cole-Cole parameters and the wellbore-based groundwater chemistry measurements indicative of key metabolic processes within the aquifer (e.g. ferrous iron, sulfate, uranium)more » were established and used as a basis for petrophysical model development. The developed Bayesian model consists of three levels of statistical sub-models: 1) data model, providing links between geochemical and geophysical attributes, 2) process model, describing the spatial and temporal variability of geochemical properties in the subsurface system, and 3) parameter model, describing prior distributions of various parameters and initial conditions. The unknown parameters are estimated using Markov chain Monte Carlo methods. By combining the temporally distributed geochemical data with the spatially distributed geophysical data, we obtain the spatio-temporal distribution of ferrous iron, sulfate and sulfide, and their associated uncertainity information. The obtained results can be used to assess the efficacy of the bioremediation treatment over space and time and to constrain reactive transport models.« less

Re-evaluating across-axis geochemical variations at the East Pacific Rise and Juan de Fuca Ridge: on- and off-axis melt delivery

NASA Astrophysics Data System (ADS)

Perfit, M. R.; Walters, R. L.

2014-12-01

High spatial density geochemical data sets from the N-EPR and S-JdFR are used to re-evaluate the across-axis geochemical variations in major and trace elements at mid-ocean ridges (MORs). At two axial melt lens (AML) segments, north and south, at the 9-10°N EPR, N-MORB MgO varies across-axis from the most primitive above the AML to more evolved away from the axis. This trend is distinct at the northern (magmatically more robust) segment with an axial MgO range of 8-9 wt% and off-axis (>2km) range of 6.5-8 wt%. This decrease is also reflected in E-MORB MgO variation. There is more variability at the southern segment but, off-axis progression to more evolved MgO is still evident. Interestingly, the Cleft segment, JdFR, displays similar geochemical behavior to the EPR with an axial MgO range of 7-8.5 wt% and off-axis (>2km) range of 6-7.5 wt%. EPR geochemical studies over the past 30 years have described models of upper crustal accumulation ranging from eruptions limited to the axis, to temporal variation in the composition of magma in the AML, to multiple eruption sites across the ridge crest and flanks (<5km). Eruptions limited to the axis, with topographically controlled flow off-axis, cannot reproduce the observed off-axis change to more evolved N-MORB. Time-dependence could explain one instance of evolved lavas off-axis but, similar geochemical behavior is observed at two separate AML segments. Multiple instances of consistent compositional variability at multiple AML segments, and at different ridges, point to a common process of crustal accretion at MORs. In light of recent geophysical discoveries of Off-axis AMLs (OAMLs) at the EPR and JdFR, we propose that the trend of more evolved lavas for the majority of N-MORB lavas with distance from the axis is controlled by thermal distribution in the underlying crystal mush zone (CMZ). Higher magma flux beneath the axis facilitates higher temperatures and high porosity melt pathways, reducing crustal residence times, and erupting more primitive lava compositions. OAMLs at the edges of the CMZ, where it is cooler, feed more evolved off-axis eruptions. Lower magma flux at the edges increases crustal residence time and the extent to which magmas crystallize. OAMLs outside of the CMZ host magmas that may escaped any central mixing and erupt a greater range of compositions.

The formation and stability of saline minerals at the Martian surface

NASA Astrophysics Data System (ADS)

Tosca, Nicholas James, III

Evaporite minerals have been identified throughout the martian sedimentary record. Because evaporites can record detailed paleo-environmental information and often host fossil biosignatures on Earth, they are priority targets for future exploration. However, understanding processes that control the formation of these minerals on Mars requires an understanding of the behavior of Fe in highly concentrated evaporating fluids. In this study, a model is developed using the Pitzer ion interaction approach that accurately describes thermodynamic properties of the Fe2(SO4)3-H2SO4-H 2O system. Incorporating this model into a multicomponent thermodynamic database enables detailed study of evaporite mineral formation and stability on Mars. From geochemical modeling, the variation in evaporite mineralogy on Mars may be traced to volatile-anion input -- a variable intimately tied to pH. Using the "chemical divide" concept, evaporites at the martian surface can be used as sensitive probes of pH, atmospheric composition, and cation proportion in solution. Applying this approach to saline assemblages in Nakhlite meteorites and in Meridiani Planum sediments reveals two geochemical systems; each characterized by different pH and anion proportion. A complicating factor however is the concomitant oxidation of soluble Fe-bearing minerals. Such a process may have contributed to complex Fe mineralogy observed at Meridiani Planum through diagenesis. Fe-oxidation experiments at high ionic strength show a progression of mineral phases that begins with the formation of schwertmannite and subsequent ageing to jarosite and nano-crystalline goethite; a process strongly controlled by pH. Low water activity and small particle size drive the ageing of goethite to hematite which provides the final step of a mechanism that is consistent with the distribution of Fe-minerals at Meridiani Planum. These results show that the instability of Fe2+-sulfate minerals at the martian surface may lead to the association of Fe-oxide and Fe-hydroxysulfate minerals with evaporite salts. Indeed, such a geologic association has been observed through remote sensing techniques. Thus, as the Fe-sulfates are sensitive to pH, Fe-oxidation and relative humidity, understanding these phase relationships in greater detail will ultimately exploit the presence of these minerals as a unique set of geochemical probes.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Tonsina area, Valdez Quadrangle, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 128 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Tonsina area in the Chugach Mountains, Valdez quadrangle, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies

Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.

Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24-48 h) fluid enrichment of certainmore » elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales.« less

Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

DOE PAGES

Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.; ...

2016-11-09

Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24-48 h) fluid enrichment of certainmore » elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales.« less

Volatile abundances and oxygen isotopes in basaltic to dacitic lavas on mid-ocean ridges: The role of assimilation at spreading centers

USGS Publications Warehouse

Wanless, V.D.; Perfit, M.R.; Ridley, W.I.; Wallace, P.J.; Grimes, Craig B.; Klein, E.M.

2011-01-01

Most geochemical variability in MOR basalts is consistent with low- to moderate-pressure fractional crystallization of various mantle-derived parental melts. However, our geochemical data from MOR high-silica glasses, including new volatile and oxygen isotope data, suggest that assimilation of altered crustal material plays a significant role in the petrogenesis of dacites and may be important in the formation of basaltic lavas at MOR in general. MOR high-silica andesites and dacites from diverse areas show remarkably similar major element trends, incompatible trace element enrichments, and isotopic signatures suggesting similar processes control their chemistry. In particular, very high Cl and elevated H2O concentrations and relatively light oxygen isotope ratios (~ 5.8‰ vs. expected values of ~ 6.8‰) in fresh dacite glasses can be explained by contamination of magmas from a component of ocean crust altered by hydrothermal fluids. Crystallization of silicate phases and Fe-oxides causes an increase in δ18O in residual magma, but assimilation of material initially altered at high temperatures results in lower δ18O values. The observed geochemical signatures can be explained by extreme fractional crystallization of a MOR basalt parent combined with partial melting and assimilation (AFC) of amphibole-bearing altered oceanic crust. The MOR dacitic lavas do not appear to be simply the extrusive equivalent of oceanic plagiogranites. The combination of partial melting and assimilation produces a distinct geochemical signature that includes higher incompatible trace element abundances and distinct trace element ratios relative to those observed in plagiogranites.

Performance of a Zerovalent Iron Reactive Barrier for the Treatment of Arsenic in Groundwater: Part 2. Geochemical Modeling and Solid Phase Studies

EPA Science Inventory

Arsenic uptake processes were evaluated in a zerovalent iron reactive barrier installed at a lead smelting facility using geochemical modeling, solid-phase analysis, and X-ray absorption spectroscopy techniques. Aqueous speciation of arsenic plays a key role in directing arsenic...

CO2 flux from Javanese mud volcanism

NASA Astrophysics Data System (ADS)

Queißer, M.; Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A.

2017-06-01

Studying the quantity and origin of CO2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s-1 (117 t d-1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d-1, comparable with the expected back-arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO2 fluxes.

Geochemical processes in ground water resulting from surface mining of coal at the Big Sky and West Decker Mine areas, southeastern Montana

USGS Publications Warehouse

Clark, D.W.

1995-01-01

A potential hydrologic effect of surface mining of coal in southeastern Montana is a change in the quality of ground water. Dissolved-solids concen- trations in water in spoils aquifers generally are larger than concentrations in water in the coal aquifers they replaced; however, laboratory experiments have indicated that concentrations can decrease if ground water flows from coal-mine spoils to coal. This study was conducted to determine if decreases in concentrations occur onsite and, if so, which geochemical processes caused the decreases. Solid-phase core samples of spoils, unmined over- burden, and coal, and ground-water samples were collected from 16 observation wells at two mine areas. In the Big Sky Mine area, changes in ground- water chemistry along a flow path from an upgradient coal aquifer to a spoils aquifer probably were a result of dedolomitization. Dissolved-solids concentrations were unchanged as water flowed from a spoils aquifer to a downgradient coal aquifer. In the West Decker Mine area, dissolved-solids concentrations apparently decreased from about 4,100 to 2,100 milligrams per liter as water moved along an inferred flow path from a spoils aquifer to a downgradient coal aquifer. Geochemical models were used to analyze changes in water chemistry on the basis of results of solid-phase and aqueous geochemical characteristics. Geochemical processes postulated to result in the apparent decrease in dissolved-solids concentrations along this inferred flow path include bacterial reduction of sulfate, reverse cation exchange within the coal, and precipitation of carbonate and iron-sulfide minerals.

Advances in the hydrogeochemistry and microbiology of acid mine waters

USGS Publications Warehouse

Nordstrom, D. Kirk

2000-01-01

The last decade has witnessed a plethora of research related to the hydrogeochemistry and microbiology of acid mine waters and associated tailings and waste-rock waters. Numerous books, reviews, technical papers, and proceedings have been published that examine the complex bio-geochemical process of sulfide mineral oxidation, develop and apply geochemical models to site characterization, and characterize the microbial ecology of these environments. This review summarizes many of these recent works, and provides references for those investigating this field. Comparisons of measured versus calculated Eh and measured versus calculated pH for water samples from several field sites demonstrate the reliability of some current geochemical models for aqueous speciation and mass balances. Geochemical models are not, however, used to predict accurately time-dependent processes but to improve our understanding of these systems and to constrain possible processes that contribute to actual or potential water quality issues. Microbiological studies are demonstrating that there is much we have yet to learn about the types of different microorganisms and their function and ecology in mine-waste environments. A broad diversity of green algae, bacteria, archaea, yeasts, and fungi are encountered in acid mine waters, and a better understanding of their ecology and function may potentially enhance remediation possibilities as well as our understanding of the evolution of life.

Merging metagenomics and geochemistry reveals environmental controls on biological diversity and evolution.

PubMed

Alsop, Eric B; Boyd, Eric S; Raymond, Jason

2014-05-28

The metabolic strategies employed by microbes inhabiting natural systems are, in large part, dictated by the physical and geochemical properties of the environment. This study sheds light onto the complex relationship between biology and environmental geochemistry using forty-three metagenomes collected from geochemically diverse and globally distributed natural systems. It is widely hypothesized that many uncommonly measured geochemical parameters affect community dynamics and this study leverages the development and application of multidimensional biogeochemical metrics to study correlations between geochemistry and microbial ecology. Analysis techniques such as a Markov cluster-based measure of the evolutionary distance between whole communities and a principal component analysis (PCA) of the geochemical gradients between environments allows for the determination of correlations between microbial community dynamics and environmental geochemistry and provides insight into which geochemical parameters most strongly influence microbial biodiversity. By progressively building from samples taken along well defined geochemical gradients to samples widely dispersed in geochemical space this study reveals strong links between the extent of taxonomic and functional diversification of resident communities and environmental geochemistry and reveals temperature and pH as the primary factors that have shaped the evolution of these communities. Moreover, the inclusion of extensive geochemical data into analyses reveals new links between geochemical parameters (e.g. oxygen and trace element availability) and the distribution and taxonomic diversification of communities at the functional level. Further, an overall geochemical gradient (from multivariate analyses) between natural systems provides one of the most complete predictions of microbial taxonomic and functional composition. Clustering based on the frequency in which orthologous proteins occur among metagenomes facilitated accurate prediction of the ordering of community functional composition along geochemical gradients, despite a lack of geochemical input. The consistency in the results obtained from the application of Markov clustering and multivariate methods to distinct natural systems underscore their utility in predicting the functional potential of microbial communities within a natural system based on system geochemistry alone, allowing geochemical measurements to be used to predict purely biological metrics such as microbial community composition and metabolism.

Koster van Groos, A F

NASA Astrophysics Data System (ADS)

Guggenheim, S.

2008-12-01

The deep-ocean environment, including the ocean floor and crust, represents one of the last scientific frontiers on earth. The surprising lack of information on the mineralogy, the geochemical processes, or the biota of the ocean floor is the result of the inability to simulate ocean-floor conditions and to study geochemical systems at these conditions. A proto-type high-pressure environmental chamber (HPEC) has been constructed for use on a transmission- mode X-ray diffractometer to study geochemical processes at the deep-ocean sediment cover and crust. The HPEC has a designed pressure range to 1000 bars and temperature range from -20 oC to 200 oC. In this chamber, a liquid (e.g., sea water) plus sample in suspension can be pressurized either by gas or liquid. A cell-pump system continuously agitates the liquid to keep particles in suspension, thereby allowing the examination of mineral phases, including clays minerals. A major feature of the HPEC is that the mineral component moves freely and can react with its environment while being illuminated by the X-ray beam. The cell-pump also allows applied gas, such as CH4 or CO2, or O2, to interact efficiently with the aqueous liquid so that the system may rapidly reach equilibrium. In addition, mixing these gases with inert gases, e.g. He or Ar, allows control of the fugacity of these gas components. The design components and how data are manipulated to remove X-ray dispersion effects caused by the liquid will be discussed, along with examples showing the effects of temperature, pressure, and salt content on smectite clay.

Adaptive Multiscale Modeling of Geochemical Impacts on Fracture Evolution

NASA Astrophysics Data System (ADS)

Molins, S.; Trebotich, D.; Steefel, C. I.; Deng, H.

2016-12-01

Understanding fracture evolution is essential for many subsurface energy applications, including subsurface storage, shale gas production, fracking, CO2 sequestration, and geothermal energy extraction. Geochemical processes in particular play a significant role in the evolution of fractures through dissolution-driven widening, fines migration, and/or fracture sealing due to precipitation. One obstacle to understanding and exploiting geochemical fracture evolution is that it is a multiscale process. However, current geochemical modeling of fractures cannot capture this multi-scale nature of geochemical and mechanical impacts on fracture evolution, and is limited to either a continuum or pore-scale representation. Conventional continuum-scale models treat fractures as preferential flow paths, with their permeability evolving as a function (often, a cubic law) of the fracture aperture. This approach has the limitation that it oversimplifies flow within the fracture in its omission of pore scale effects while also assuming well-mixed conditions. More recently, pore-scale models along with advanced characterization techniques have allowed for accurate simulations of flow and reactive transport within the pore space (Molins et al., 2014, 2015). However, these models, even with high performance computing, are currently limited in their ability to treat tractable domain sizes (Steefel et al., 2013). Thus, there is a critical need to develop an adaptive modeling capability that can account for separate properties and processes, emergent and otherwise, in the fracture and the rock matrix at different spatial scales. Here we present an adaptive modeling capability that treats geochemical impacts on fracture evolution within a single multiscale framework. Model development makes use of the high performance simulation capability, Chombo-Crunch, leveraged by high resolution characterization and experiments. The modeling framework is based on the adaptive capability in Chombo which not only enables mesh refinement, but also refinement of the model-pore scale or continuum Darcy scale-in a dynamic way such that the appropriate model is used only when and where it is needed. Explicit flux matching provides coupling betwen the scales.

Interpolity exchange of basalt tools facilitated via elite control in Hawaiian archaic states

PubMed Central

Kirch, Patrick V.; Mills, Peter R.; Lundblad, Steven P.; Sinton, John; Kahn, Jennifer G.

2012-01-01

Ethnohistoric accounts of late precontact Hawaiian archaic states emphasize the independence of chiefly controlled territories (ahupua‘a) based on an agricultural, staple economy. However, elite control of unevenly distributed resources, such as high-quality volcanic rock for adze production, may have provided an alternative source of economic power. To test this hypothesis we used nondestructive energy-dispersive X-ray fluorescence (ED-XRF) analysis of 328 lithic artifacts from 36 archaeological features in the Kahikinui district, Maui Island, to geochemically characterize the source groups. This process was followed by a limited sampling using destructive wavelength-dispersive X-ray fluorescence (WD-XRF) analysis to more precisely characterize certain nonlocal source groups. Seventeen geochemical groups were defined, eight of which represent extra-Maui Island sources. Although the majority of stone tools were derived from Maui Island sources (71%), a significant quantity (27%) of tools derived from extraisland sources, including the large Mauna Kea quarry on Hawai‘i Island as well as quarries on O‘ahu, Moloka‘i, and Lāna‘i islands. Importantly, tools quarried from extralocal sources are found in the highest frequency in elite residential features and in ritual contexts. These results suggest a significant role for a wealth economy based on the control and distribution of nonagricultural goods and resources during the rise of the Hawaiian archaic states. PMID:22203984

Modeling Low-temperature Geochemical Processes

NASA Astrophysics Data System (ADS)

Nordstrom, D. K.

2003-12-01

Geochemical modeling has become a popular and useful tool for a wide number of applications from research on the fundamental processes of water-rock interactions to regulatory requirements and decisions regarding permits for industrial and hazardous wastes. In low-temperature environments, generally thought of as those in the temperature range of 0-100 °C and close to atmospheric pressure (1 atm=1.01325 bar=101,325 Pa), complex hydrobiogeochemical reactions participate in an array of interconnected processes that affect us, and that, in turn, we affect. Understanding these complex processes often requires tools that are sufficiently sophisticated to portray multicomponent, multiphase chemical reactions yet transparent enough to reveal the main driving forces. Geochemical models are such tools. The major processes that they are required to model include mineral dissolution and precipitation; aqueous inorganic speciation and complexation; solute adsorption and desorption; ion exchange; oxidation-reduction; or redox; transformations; gas uptake or production; organic matter speciation and complexation; evaporation; dilution; water mixing; reaction during fluid flow; reaction involving biotic interactions; and photoreaction. These processes occur in rain, snow, fog, dry atmosphere, soils, bedrock weathering, streams, rivers, lakes, groundwaters, estuaries, brines, and diagenetic environments. Geochemical modeling attempts to understand the redistribution of elements and compounds, through anthropogenic and natural means, for a large range of scale from nanometer to global. "Aqueous geochemistry" and "environmental geochemistry" are often used interchangeably with "low-temperature geochemistry" to emphasize hydrologic or environmental objectives.Recognition of the strategy or philosophy behind the use of geochemical modeling is not often discussed or explicitly described. Plummer (1984, 1992) and Parkhurst and Plummer (1993) compare and contrast two approaches for modeling groundwater chemistry: (i) "forward modeling," which predicts water compositions from hypothesized reactions and user assumptions and (ii) "inverse modeling," which uses water, mineral, and isotopic compositions to constrain hypothesized reactions. These approaches simply reflect the amount of information one has to work with. With minimal information on a site, a modeler is forced to rely on forward modeling. Optimal information would include detailed mineralogy on drill cores or well cuttings combined with detailed water analyses at varying depths and sufficient spatial distribution to follow geochemical reactions and mixing of waters along defined flow paths. With optimal information, a modeler will depend on inverse modeling.This chapter outlines the main concepts and key developments in the field of geochemical modeling for low-temperature environments and illustrates their use with examples. It proceeds with a short discussion of what modeling is, continues with concepts and definitions commonly used, and follows with a short history of geochemical models, a discussion of databases, the codes that embody models, and recent examples of how these codes have been used in water-rock interactions. An important new stage of development seems to have been reached in this field with questions of reliability and validity of models. Future work will be obligated to document ranges of certainty and sources of uncertainty, sensitivity of models and codes to parameter errors and assumptions, propagation of errors, and delineation of the range of applicability.

Project Report: Undergraduate Student Research Program (USRP)

NASA Technical Reports Server (NTRS)

Gavin, Patricia

2011-01-01

To better understand geochemical processes occurring on Europa's seafloor, we investigated the effects of varying Fe?content in the seafloor rock and varying temperature. Iron is important in such geochemical processes as the production of methane through serpentinization (e.g. Allen and Seyfried, 2003) and can be a nutrient for microbes (Russell and Hall, 2006; Park and Kim, 2001). It can also offer clues as to the state of differentiation of Europa's core/mantle. If Europa is fully differentiated and contains an iron core, we would expect there to be little iron in the mantle and ocean floor whereas a homogeneous Europa would have iron evenly dispersed throughout the ocean floor. Furthermore, the composition of the ocean is a result of water?rock interactions at the seafloor. This project investigated the effects of temperature on geochemical processes, comparing high temperature (> 250oC) hydrothermal vents (Kelley et al., 2001) to lower temperature (20oC) cold seeps (e.g. Orphan et al., 2002).

Release behavior of uranium in uranium mill tailings under environmental conditions.

PubMed

Liu, Bo; Peng, Tongjiang; Sun, Hongjuan; Yue, Huanjuan

2017-05-01

Uranium contamination is observed in sedimentary geochemical environments, but the geochemical and mineralogical processes that control uranium release from sediment are not fully appreciated. Identification of how sediments and water influence the release and migration of uranium is critical to improve the prevention of uranium contamination in soil and groundwater. To understand the process of uranium release and migration from uranium mill tailings under water chemistry conditions, uranium mill tailing samples from northwest China were investigated with batch leaching experiments. Results showed that water played an important role in uranium release from the tailing minerals. The uranium release was clearly influenced by contact time, liquid-solid ratio, particle size, and pH under water chemistry conditions. Longer contact time, higher liquid content, and extreme pH were all not conducive to the stabilization of uranium and accelerated the uranium release from the tailing mineral to the solution. The values of pH were found to significantly influence the extent and mechanisms of uranium release from minerals to water. Uranium release was monitored by a number of interactive processes, including dissolution of uranium-bearing minerals, uranium desorption from mineral surfaces, and formation of aqueous uranium complexes. Considering the impact of contact time, liquid-solid ratio, particle size, and pH on uranium release from uranium mill tailings, reducing the water content, decreasing the porosity of tailing dumps and controlling the pH of tailings were the key factors for prevention and management of environmental pollution in areas near uranium mines. Copyright © 2017 Elsevier Ltd. All rights reserved.

Geochemical processes controlling fate and transport of arsenic in acid mine drainage (AMD) and natural systems.

PubMed

Cheng, Hefa; Hu, Yuanan; Luo, Jian; Xu, Bin; Zhao, Jianfu

2009-06-15

Acid mine drainage (AMD) is often accompanied with elevated concentrations of arsenic, in the forms of arsenite, As(III), and/or arsenate, As(V), due to the high affinity of arsenic for sulfide mineral ores. This review summarizes the major geochemical processes controlling the release, speciation, fate, and distribution of inorganic arsenic in mine drainage and natural systems. Arsenic speciation depends highly on redox potential and pH of the solution, and arsenite can be oxidized to the less toxic arsenate form. Homogeneous oxidation of arsenite occurs rather slowly while its heterogeneous oxidation on mineral surfaces can greatly enhance the reaction rates. Little evidence suggests that precipitation reaction limits the concentrations of arsenic in natural water, while co-precipitation may lead to rapid arsenic removal when large amount of iron hydroxides precipitate out of the aqueous phase upon neutralization of the mine drainage. Both arsenate and arsenite adsorb on common metal oxides and clay minerals through formation of inner-sphere and/or outer-sphere complexes, controlling arsenic concentration in natural water bodies. Arsenite adsorbs less strongly than arsenate in the typical pH range of natural water and is more mobile. Part of the adsorbed arsenic species can be exchanged by common anions (e.g., PO(4)(3-) and SO(4)(2-)), especially phosphate, which leads to their re-mobilization. Understanding the geochemistry of arsenic is helpful for predicting its mobility and fate in AMD and natural systems, and for designing of cost-effective remediation/treatment strategies to reduce the occurrence and risk of arsenic contamination.

Composition of natural gas and crude oil produced from 14 wells in the Lower Silurian "Clinton" Sandstone and Medina Group Sandstones, northeastern Ohio and northwestern Pennsylvania: Chapter G.6 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Burruss, Robert A.; Ryder, Robert T.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

The geochemical processes that control the distribution of hydrocarbons in the regional accumulation of natural gas and crude oil in reservoirs of Early Silurian age in the central Appalachian basin are not well understood. Gas and oil samples from 14 wells along a down-dip transect through the accumulation in northeastern Ohio and northwestern Pennsylvania were analyzed for molecular and stable isotopic compositions to look for evidence of hydrocarbon source, thermal maturation, migration, and alteration parameters. The correlation of carbon and hydrogen stable isotopic composition of methane with thermal maturation indicates that the deepest gases are more thermally mature than independent estimates of thermal maturity of the reservoir horizon based on the conodont alteration index. This correlation indicates that the natural gas charge in the deepest parts of the regional accumulation sampled in this study originated in deeper parts of the Appalachian basin and migrated into place. Other processes, including mixing and late-stage alteration of hydrocarbons, may also impact the observed compositions of natural gases and crude oils.

X-ray driven reaction front dynamics at calcite-water interfaces

DOE PAGES

Laanait, Nouamane; Callagon, Erika Blanca R.; Zhang, Zhan; ...

2015-09-18

The interface of minerals with aqueous solutions is central to geochemical reactivity, hosting processes that span multiple spatiotemporal scales. Understanding such processes requires spatially and temporally resolved observations, and experimental controls that precisely manipulate the interfacial thermodynamic state. Using the intense radiation fields of a focused synchrotron X-ray beam, we drove dissolution at the calcite-aqueous interface and simultaneously probed the dynamics of the propagating reaction fronts using surface X-ray microscopy. Evolving surface structures are controlled by the time-dependent solution composition as characterized by a kinetic reaction model. At extreme disequilibria, the onset of reaction front instabilities was observed with velocitiesmore » of >30 nanometers per second. As a result, these instabilities are identified as a signature of transport-limited dissolution of calcite under extreme disequilibrium.« less

Geochemical and textural constraints on degassing processes in sub-Plinian eruptions: case-study of the Greenish Pumice eruption of Mount Somma-Vesuvius

NASA Astrophysics Data System (ADS)

Zdanowicz, G.; Boudon, G.; Balcone-Boissard, H.; Cioni, R.; Mundula, F.; Orsi, G.; Civetta, L.; Agrinier, P.

2018-04-01

Plinian eruptions are characterized by high intensity and an overall steady character, and result in a stable convective column. The main processes controlling the dynamics of such steady and stable plume systems have been extensively investigated. Conversely, sub-Plinian eruptions are unsteady, as recorded by the large variability of the products and deposits. Our knowledge of the processes creating this unsteadiness on various timescales remains limited, and still requires more observations as well as theoretical and experimental investigation. Here, we focus on the sub-Plinian eruption of the Greenish Pumice (GP, 19,265 ± 105 BP), Mt. Somma-Vesuvius (Italy). On the basis of coupled geochemical and textural analyses of samples from the well-established stratigraphy of the GP deposits, we investigate volatiles (H2O, CO2, F, Cl) to better constrain the unsteady sub-Plinian eruptive style. This allows us to carry out a detailed study of the degassing processes in relation to the eruption dynamics. We find that degassing by open-system processes generally dominates throughout the entire eruption, but alternates with episodes of closed-system degassing. The fluctuating degassing regimes, responsible for the variable magma ascent rate within the conduit, are also responsible for the eruptive column instability. Volatile behavior is well correlated with textural heterogeneities of the eruptive products. Both reflect higher conduit heterogeneity than for Plinian eruptions, where we find a higher horizontal gradient in magma ascent velocity due to a smaller conduit diameter.

Exploratory and spatial data analysis (EDA-SDA) for determining regional background levels and anomalies of potentially toxic elements in soils from Catorce-Matehuala, Mexico

USGS Publications Warehouse

Chiprés, J.A.; Castro-Larragoitia, J.; Monroy, M.G.

2009-01-01

The threshold between geochemical background and anomalies can be influenced by the methodology selected for its estimation. Environmental evaluations, particularly those conducted in mineralized areas, must consider this when trying to determinate the natural geochemical status of a study area, quantifying human impacts, or establishing soil restoration values for contaminated sites. Some methods in environmental geochemistry incorporate the premise that anomalies (natural or anthropogenic) and background data are characterized by their own probabilistic distributions. One of these methods uses exploratory data analysis (EDA) on regional geochemical data sets coupled with a geographic information system (GIS) to spatially understand the processes that influence the geochemical landscape in a technique that can be called a spatial data analysis (SDA). This EDA-SDA methodology was used to establish the regional background range from the area of Catorce-Matehuala in north-central Mexico. Probability plots of the data, particularly for those areas affected by human activities, show that the regional geochemical background population is composed of smaller subpopulations associated with factors such as soil type and parent material. This paper demonstrates that the EDA-SDA method offers more certainty in defining thresholds between geochemical background and anomaly than a numeric technique, making it a useful tool for regional geochemical landscape analysis and environmental geochemistry studies.

Evaluation of CO 2 -Fluid-Rock Interaction in Enhanced Geothermal Systems: Field-Scale Geochemical Simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Feng; McPherson, Brian J.; Kaszuba, John

Recent studies suggest that using supercritical CO 2 (scCO 2 ) instead of water as a heat transmission fluid in Enhanced Geothermal Systems (EGS) may improve energy extraction. While CO 2 -fluid-rock interactions at “typical” temperatures and pressures of subsurface reservoirs are fairly well known, such understanding for the elevated conditions of EGS is relatively unresolved. Geochemical impacts of CO 2 as a working fluid (“CO 2 -EGS”) compared to those for water as a working fluid (H 2 O-EGS) are needed. The primary objectives of this study are (1) constraining geochemical processes associated with CO 2 -fluid-rock interactions undermore » the high pressures and temperatures of a typical CO 2 -EGS site and (2) comparing geochemical impacts of CO 2 -EGS to geochemical impacts of H 2 O-EGS. The St. John’s Dome CO 2 -EGS research site in Arizona was adopted as a case study. A 3D model of the site was developed. Net heat extraction and mass flow production rates for CO 2 -EGS were larger compared to H 2 O-EGS, suggesting that using scCO 2 as a working fluid may enhance EGS heat extraction. More aqueous CO 2 accumulates within upper- and lower-lying layers than in the injection/production layers, reducing pH values and leading to increased dissolution and precipitation of minerals in those upper and lower layers. Dissolution of oligoclase for water as a working fluid shows smaller magnitude in rates and different distributions in profile than those for scCO 2 as a working fluid. It indicates that geochemical processes of scCO 2 -rock interaction have significant effects on mineral dissolution and precipitation in magnitudes and distributions.« less

Evaluation of CO 2 -Fluid-Rock Interaction in Enhanced Geothermal Systems: Field-Scale Geochemical Simulations

DOE PAGES

Pan, Feng; McPherson, Brian J.; Kaszuba, John

2017-01-01

Recent studies suggest that using supercritical CO 2 (scCO 2 ) instead of water as a heat transmission fluid in Enhanced Geothermal Systems (EGS) may improve energy extraction. While CO 2 -fluid-rock interactions at “typical” temperatures and pressures of subsurface reservoirs are fairly well known, such understanding for the elevated conditions of EGS is relatively unresolved. Geochemical impacts of CO 2 as a working fluid (“CO 2 -EGS”) compared to those for water as a working fluid (H 2 O-EGS) are needed. The primary objectives of this study are (1) constraining geochemical processes associated with CO 2 -fluid-rock interactions undermore » the high pressures and temperatures of a typical CO 2 -EGS site and (2) comparing geochemical impacts of CO 2 -EGS to geochemical impacts of H 2 O-EGS. The St. John’s Dome CO 2 -EGS research site in Arizona was adopted as a case study. A 3D model of the site was developed. Net heat extraction and mass flow production rates for CO 2 -EGS were larger compared to H 2 O-EGS, suggesting that using scCO 2 as a working fluid may enhance EGS heat extraction. More aqueous CO 2 accumulates within upper- and lower-lying layers than in the injection/production layers, reducing pH values and leading to increased dissolution and precipitation of minerals in those upper and lower layers. Dissolution of oligoclase for water as a working fluid shows smaller magnitude in rates and different distributions in profile than those for scCO 2 as a working fluid. It indicates that geochemical processes of scCO 2 -rock interaction have significant effects on mineral dissolution and precipitation in magnitudes and distributions.« less

Geochemical Insights Into Lithospheric Melting and Instability in the Bufumbira Volcanic Field of the Western Rift, Uganda

NASA Astrophysics Data System (ADS)

Pitcavage, E.; Furman, T.; Nelson, W. R.

2016-12-01

The East African Rift System (EARS) is the earth's largest continental divergent boundary and is an unparalleled natural laboratory for understanding magmatic processes related to continental rifting. A fundamental unresolved question in EARS magmatism is the degree to which volcanism and rifting are influenced by Cenozoic plume-related melting rather than older, tectonically-driven metasomatism. In the latter scenario, metasomatism by carbonatite or silicate magmas and/or fluids that accompanies tectonic events such as the Proterozoic Pan-African Orogeny will create geochemical heterogeneities and rheological weaknesses in the sub-continental lithospheric mantle (SCLM). In the Western Rift, abundant alkaline mafic lavas record significant contributions from metasomatized SCLM. Modification, destabilization and foundering of metasomatized SCLM has an increasingly recognized role in continental magmatism worldwide. Lithospheric drip magmatism occurs when foundered lithosphere devolatilizes and melts on descent. Lithospheric thinning is one consequence of this process, and may play a role in physical aspects of rifting. Geochemical and geophysical evidence that drip magmatism has occurred in several areas of the EARS, including Turkana, Chyulu Hills, and Oligocene HT2 flood basalts in Afar, suggests that this process is fundamentally related to the onset of successful rifting. We use geochemical characteristics of primitive lavas from the Bufumbira volcanic field in the Western Rift's Virunga Province to demonstrate that ancient, tectonically-driven metasomatism modified the SCLM and contributes to recent volcanism. Further, we identify geochemical signatures which indicate that lithospheric drip melting is the primary petrogenetic process generating these lavas. Sr-Nd-Pb-Hf isotopic data show that the northern portion of the Western Rift, including Bufumbira, requires magma sources distinct from the rest of the EARS. Trace element data show that Bufumbira lavas are derived from depths within the garnet stability field and that source mineralogy includes phlogopite with potential amphibole and zircon; and that extent of melting increased with depth of melting, a signature of lithospheric drip.

Cross-correlation analysis of 2012-2014 seismic events in Central-Northern Italy: insights from the geochemical monitoring network of Tuscany

NASA Astrophysics Data System (ADS)

Pierotti, Lisa; Facca, Gianluca; Gherardi, Fabrizio

2015-04-01

Since late 2002, a geochemical monitoring network is operating in Tuscany, Central Italy, to collect data and possibly identify geochemical anomalies that characteristically occur before regionally significant (i.e. with magnitude > 3) seismic events. The network currently consists of 6 stations located in areas already investigated in detail for their geological setting, hydrogeological and geochemical background and boundary conditions. All these stations are equipped for remote, continuous monitoring of selected physicochemical parameters (temperature, pH, redox potential, electrical conductivity), and dissolved concentrations of CO2 and CH4. Additional information are obtained through in situ discrete monitoring. Field surveys are periodically performed to guarantee maintenance and performance control of the sensors of the automatic stations, and to collect water samples for the determination of the chemical and stable isotope composition of all the springs investigated for seismic precursors. Geochemical continuous signals are numerically processed to remove outliers, monitoring errors and aseismic effects from seasonal and climatic fluctuations. The elaboration of smoothed, long-term time series (more than 200000 data available today for each station) allows for a relatively accurate definition of geochemical background values. Geochemical values out of the two-sigma relative standard deviation domain are inspected as possible indicators of physicochemical changes related to regional seismic activity. Starting on November 2011, four stations of the Tuscany network located in two separate mountainous areas of Northern Apennines separating Tuscany from Emilia-Romagna region (Equi Terme and Gallicano), and Tuscany from Emilia-Romagna and Umbria regions (Vicchio and Caprese Michelangelo), started to register anomalous values in pH and CO2 partial pressure (PCO2). Cross-correlation analysis indicates an apparent relationship between the most important seismic events (magnitude >3 up to 5.4) experienced in the Tuscany, Emilia-Romagna and Umbria regions during the period 2012-2014, and these geochemical anomalies. Changes in pH (decreasing) and PCO2 (increasing) are generally observed from a few months to a few weeks before the main shock. This trend has been recognized for the Parma quake of 27 January 2012 (M = 5.4), for the Pieve Fosciana quake of 13 January 2013 (M = 4.8), for the Garfagnana-Lunigiana seismic sequence started June 21, 2013 (Mmax = 5.2), for the Montefeltro seismic sequence started July 11, 2013 (Mmax = 3.9), for the Gubbio seismic sequences of July and December 2013 (Mmax = 3.9), for the Città di Castello seismic sequences of April 2013 and December 2013 (Mmax = 3.9), for the Casentino seismic sequence started October 17, 2014 (Mmax = 3.5), and for the Chianti seismic sequence started December 19, 2014 (Mmax = 4.1). These features suggest that the selected mineral springs can be considered as appropriate sites for the search of geochemical earthquake precursors. Further investigations focused on in-depth analysis of signals are currently in progress.

Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

NASA Astrophysics Data System (ADS)

Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

2017-01-01

Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

Modeling biogechemical reactive transport in a fracture zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang

2005-01-14

A coupled model of groundwater flow, reactive solute transport and microbial processes for a fracture zone of the Aspo site at Sweden is presented. This is the model of the so-called Redox Zone Experiment aimed at evaluating the effects of tunnel construction on the geochemical conditions prevailing in a fracture granite. It is found that a model accounting for microbially-mediated geochemical processes is able to reproduce the unexpected measured increasing trends of dissolved sulfate and bicarbonate. The model is also useful for testing hypotheses regarding the role of microbial processes and evaluating the sensitivity of model results to changes inmore » biochemical parameters.« less

New Geochemical Analyses Reveal Crustal Accretionary Processes at The Overlapping Spreading Center Near 3 N East Pacific Rise

NASA Astrophysics Data System (ADS)

Smithka, I. N.; Perfit, M. R.

2013-12-01

Mid-ocean ridges (MORs) are the sites of oceanic lithosphere creation and construction. Ridge discontinuities are a global phenomenom but are not as well understood as ridge axes. Geochemical analyses provide insights into upper mantle processes since elements fractionate with melting and freezing as well as reside in material to retain source signature. Lavas collected from ridge discontinuities consist of greater chemical diversity and represent variations in source, melting parameters, and local crustal processes. The small overlapping spreading center (OSC) near the third parallel north on the East Pacific Rise has been superficially analyzed previously, but here we present new isotope analyses and expand our understanding of MOR processes and processes near OSCs. Initial analyses of lavas collected in 2000 on AHA-NEMO2 revealed normal MOR basalt trends in rare earth element enrichments as well as in major element concentrations. Crystal fractionation varies along the tips of both axes, with MgO and TiO2 concentrations increasing towards the OSC basin. Newly analyzed Sr, Nd, and Pb isotope ratios will further constrain the nature of geochemical diversity along axis. As the northern tip seems to be propagating and the southern tip dying, lavas collected from each may reflect two different underlying mantle melting and magma storage processes.

Geochemical and isotopic data for restricting seawater intrusion and groundwater circulation in a series of typical volcanic islands in the South China Sea.

PubMed

Zhang, Wenjie; Chen, Xi; Tan, Hongbing; Zhang, Yanfei; Cao, Jifu

2015-04-15

The decline of groundwater table and deterioration of water quality related to seawater have long been regarded as a crucial problem in coastal regions. In this work, a hydrogeologic investigation using combined hydrochemical and isotopic approaches was conducted in the coastal region of the South China Sea near the Leizhou peninsular to provide primary insight into seawater intrusion and groundwater circulation. Hydrochemical and isotopic data show that local groundwater is subjected to anthropogenic activities and geochemical processes, such as evaporation, water-rock interaction, and ion exchange. However, seawater intrusion driven by the over-exploitation of groundwater and insufficient recharge is the predominant factor controlling groundwater salinization. Systematic and homologic isotopic characteristics of most samples suggest that groundwater in volcanic area is locally recharged and likely caused by modern precipitation. However, very depleted stable isotopes and extremely low tritium of groundwater in some isolated aquifers imply a dominant role of palaeowater. Copyright © 2015 Elsevier Ltd. All rights reserved.

Unraveling the role of liquids during chondrule formation processes

NASA Astrophysics Data System (ADS)

Varela, Maria Eugenia; Zinner, Ernst

2018-01-01

The process/es involved in chondrule formation cover a wide range of mechanisms whose nature is still unknown. Our attention is focused on solar nebula processes mainly in untangling the origin of the initial liquid droplets that turn into chondrules. To do this, we start deciphering the processes under which the chondritic constituents of glass-rich, PO and POP chondrules from the Unequilibrated Ordinary Chondrite (UOC) Tieschitz L/H3.6 could have been formed. One constituent is the initial refractory liquid. This chilled liquid, presented as primary glass inclusions in olivine or as glass mesostasis, has trace element abundances with unfractionated patterns and lacks the chemical signature that is expected from a geochemical (liquid-crystal) fractionation. The unfractionated crystal-liquid distribution coefficients observed in the glass-rich, PO and POP chondrules indicate that formation of these objects was not dominated by an igneous process. In addition, the good correlation of elements with different geochemical and cosmochemical properties (e.g., Yb and La-Ce) that spread around the primordial ratio, indicate that a cosmochemical (condensation) instead of a geochemical process may have been involved in the origin of this refractory liquid. We end up discussing a secondary process: the alkali-Ca exchange reaction that could have taken place within a cooling nebula at sub-solidus temperatures. The extent to which these solid/gas exchange reactions took place will determine the final composition of the chondrules.

Pore-Scale Geochemical Reactivity Associated with CO2 Storage: New Frontiers at the Fluid-Solid Interface.

PubMed

Noiriel, Catherine; Daval, Damien

2017-04-18

The reactivity of carbonate and silicate minerals is at the heart of porosity and pore geometry changes in rocks injected with CO 2 , which ultimately control the evolution of flow and transport properties of fluids in porous and/or fractured geological reservoirs. Modeling the dynamics of CO 2 -water-rock interactions is challenging because of the resulting large geochemical disequilibrium, the reservoir heterogeneities, and the large space and time scales involved in the processes. In particular, there is a lack of information about how the macroscopic properties of a reservoir, e.g., the permeability, will evolve as a result of geochemical reactions at the molecular scale. Addressing this point requires a fundamental understanding of how the microstructures influence the macroscopic properties of rocks. The pore scale, which ranges from a few nanometers to centimeters, has stood out as an essential scale of observation of geochemical processes in rocks. Transport or surface reactivity limitations due to the pore space architecture, for instance, are best described at the pore scale itself. It can be also considered as a mesoscale for aggregating and increasing the gain of fundamental understanding of microscopic interfacial processes. Here we focus on the potential application of a combination of physicochemical measurements coupled with nanoscale and microscale imaging techniques during laboratory experiments to improve our understanding of the physicochemical mechanisms that occur at the fluid-solid interface and the dynamics of the coupling between the geochemical reactions and flow and transport modifications at the pore scale. Imaging techniques such as atomic force microscopy, vertical scanning interferometry, focused ion beam transmission electron microscopy, and X-ray microtomography, are ideal for investigating the reactivity dynamics of these complex materials. Minerals and mineral assemblages, i.e., rocks, exhibit heterogeneous and anisotropic reactivity, which challenges the continuum description of porous media and assumptions required for reactive transport modeling at larger scales. The conventional approach, which consists of developing dissolution rate laws normalized to the surface area, should be revisited to account for both the anisotropic crystallographic structure of minerals and the transport of chemical species near the interface, which are responsible for the intrinsic evolution of the mineral dissolution rate as the reaction progresses. In addition, the crystal morphology and the mineral assemblage composition, texture, and structural heterogeneities are crucial in determining whether the permeability and transport properties of the reservoir will be altered drastically or maintain the sealing properties required to ensure the safe sequestration of CO 2 for hundreds of years. Investigating the transport properties in nanometer- to micrometer-thick amorphous Si-rich surface layers (ASSLs), which develop at the fluid-mineral interface in silicates, provides future direction, as ASSLs may prevent contact between the dissolving solids and the pore fluid, potentially inhibiting the dissolution/carbonation process. Equally, at a larger scale, the growth of micrometer- to millimeter-thick alteration layers, which result from the difference in reactivity between silicates and carbonates, slows the transport in the vicinity of the fluid-solid interface in polymineralic rocks, thus limiting the global reactivity of the carbonate matrix. In contrast, in pure limestone, the global reactivity of the monomineralic rock decreases because the flow localization promotes the local reactivity within the forming channels, thus enhancing permeability changes compared with more homogeneous dissolution of the rock matrix. These results indicate that the transformation of the rock matrix should control the evolution of the transport properties in reservoirs injected with CO 2 to the same extent as the intrinsic chemical reactivity of the minerals and the reservoir hydrodynamics. This process, which is currently not captured by large-scale modeling of reactive transport, should benefit from the increasing capabilities of noninvasive and nondestructive characterization tools for pore-scale processes, ultimately constraining reactive transport modeling and improving the reliability of predictions.

Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

USGS Publications Warehouse

Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

2011-01-01

The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons, are included here in the AGDB and will be added to the NGDB. The AGDB data provided here are the most accurate and complete to date, and should be useful for a wide variety of geochemical studies. The AGDB data provided in the linked database may be updated or changed periodically. The data on the DVD and in the data downloads provided with this report are current as of date of publication.

Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattson, Earl; Smith, Robert; Fujita, Yoshiko

2015-03-01

The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoirmore » temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.« less

The Influence of Surface Coal Mining on Runoff Processes and Stream Chemistry in the Elk Valley, British Colubmbia, Canada

NASA Astrophysics Data System (ADS)

Carey, S. K.; Wellen, C. C.; Shatilla, N. J.

2015-12-01

Surface mining is a common method of accessing coal. In high-elevation environments, vegetation and soils are typically removed prior to the blasting of overburden rock, thereby allowing access to mineable ore. Following this, the removed overburden rock is deposited in adjacent valleys as waste rock spoils. Previous research has identified that areas downstream of surface coal mining have impaired water quality, yet there is limited information about the interaction of hydrology and geochemistry across a range of mining conditions, particularly at the headwater scale. Here, we provide an analysis of an extensive long-term data set of geochemistry and flows across a gradient of coal mining in the Elk Valley, British Columbia, Canada. This work is part of a broader R&D program examining the influence of surface coal mining on hydrological and water quality responses in the Elk Valley aimed at informing effective management responses. Results indicate that water from waste rock piles has an ionic profile distinct from unimpacted catchments. While the concentration of geochemicals increased with the degree of mine impact, the control of hydrological transport capacity over geochemical export did not vary with degree of mine impact. Geochemical export in mine-influenced catchments was limited more strongly by transport capacity than supply, implying that more water moving through the waste rock mobilized more geochemicals. Placement of waste rock within the catchment (headwaters or outlet) did not affect chemical concentrations but did alter the timing with which chemically distinct water mixed. This work advances on results reported earlier using empirical models of selenium loading and further highlights the importance of limiting water inputs into waste rock piles.

Geochemical drivers of organic matter decomposition in Arctic tundra soils

DOE PAGES

Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; ...

2015-12-07

Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO 2) and methane (CH 4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonalmore » patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH 4 increased relative to dissolved CO 2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

Analysis of the geochemical gradient created by surface-groundwater interactions within riverbanks of the East River in Crested Butte, Colorado

NASA Astrophysics Data System (ADS)

Lunzer, J.; Williams, K. H.; Malenda, H. F.; Nararne-Sitchler, A.

2016-12-01

An improved understanding of the geochemical gradient created by the mixing of surface and groundwater of a river system will have considerable impact on our understanding of microorganisms, organic cycling and biogeochemical processes within these zones. In this study, the geochemical gradient in the hyporheic zone is described using a variety of geochemical properties. A system of shallow groundwater wells were installed in a series of transects along a stream bank. Each transect consists of several wells that progress away from the river bank in a perpendicular fashion. From these wells, temperature, conductivity and pH of water samples were obtained via hand pumping or bailing. These data show a clear geochemical gradient that displays a distinct zone in the subsurface where the geochemical conditions change from surface water dominated to groundwater dominated. For this study, the East River near Crested Butte, Colorado has been selected as the river of interest due the river being a relatively undisturbed floodplain. Additionally, the specific section chosen on the East River displays relatively high sinuosity meaning that these meandering sections will produce hyporheic zones that are more laterally expansive than what would be expected on a river of lower sinuosity. This increase in lateral extension of the hyporheic zone will make depicting the subtle changes in the geochemical gradient much easier than that of a river system in which the hyporheic zone is not as laterally extensive. Data has been and will be continued to be collected at different river discharges to evaluate the geochemical gradient at differing rates. Overall, this characterization of the geochemical gradient along stream banks will produce results that will aid in the further use of geochemical methods to classify and understand hyporheic exchange zones and the potential expansion of these techniques to river systems of differing geologic and geographic conditions.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Zane Hills, Hughes and Shungnak quadrangles, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential.The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska.For this report, DGGS funded reanalysis of 105 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Zane Hills area in the Hughes and Shungnak quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Reanalysis of historical U.S. Geological Survey sediment samples for geochemical data from the western part of the Wrangellia terrane, Anchorage, Gulkana, Healy, Mt. Hayes, Nabesna, and Talkeetna Mountains quadrangles, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Azain, Jaime S.; Granitto, Matthew

2014-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. For the geochemical part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 1,682 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from an area covering the western half of the Wrangellia Terrane in the Anchorage, Gulkana, Healy, Mt. Hayes, Nabesna, and Talkeetna Mountains quadrangles of south-central Alaska (fig. 1). USGS was responsible for sample retrieval from the Denver warehouse through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Kougarok area, Bendeleben and Teller quadrangles, Seward Peninsula, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 302 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Kougarok River drainage as well as smaller adjacent drainages in the Bendeleben and Teller quadrangles, Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Haines area, Juneau and Skagway quadrangles, southeast Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 212 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Chilkat, Klehini, Tsirku, and Takhin river drainages, as well as smaller drainages flowing into Chilkat and Chilkoot Inlets near Haines, Skagway Quadrangle, Southeast Alaska. Additionally some samples were also chosen from the Juneau gold belt, Juneau Quadrangle, Southeast Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the northeastern Alaska Range, Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 670 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the northeastern Alaska Range, in the Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

The evolution of the magmatic arc of Southern Peru (200-60 Ma), Arequipa area: insight from geochemical modeling

NASA Astrophysics Data System (ADS)

Demouy, S.; Benoit, M.; De Saint Blanquat, M.; Brunet, P.

2012-12-01

Cordilleran-type batholiths are built by prolonged arc activity along continental margins and may provide detailed magmatic records of the subduction system evolution. The magmas produced in subduction context involve both mantellic and crustal end members and are subject to various petrological processes. The MASH zones (Hildreth and Moorbath, 1988), at the basis of the continental crust, are the best places for the genesis of such hybrid magmas. The various geochemical signatures observed in the plutonic rocks, may also be attributed to source heterogeneities or generated by subsequent petrological processes. This study has focused in the Arequipa section of the Coastal Batholith of Southern Peru (200-60 Ma), in an area extending over 80x40 km. Major and trace elements as well as Sr and Nd isotopic analyses were performed in a set of 100 samples ranging from gabbro to granite. The obtained data highlight the wide heterogeneity of the geochemical signatures that is not related to the classification of the rocks. In first step, Rb/Sr systematic was used to isolate a set of samples plotting along a Paleocene isochron and defining a cogenetic suite. This suite appears to have evolved by simple fractional crystallization. By using reverse modeling, the parameters controlling the fractional crystallization process were defined, as partition coefficients, initial concentrations and amount of fractional crystallization. The other magmatic suites display a wide range of isotopic and geochemical signatures. To explain this heterogeneity, a model involving competition between fractional crystallization and magma mixing into MASH zones was proposed. A large range of hybrid magma types is potentially generated during the maturation of the system, but this range tends to disappear as fractionation and mixing occurs. Finally the model predicts the genesis of a homogeneous reservoir created at depth, from which magmas may evolve only by fractional crystallization. Therefore stabilization of this reservoir is directly related to the thermal conditions present at the basis of the continental crust, and allows the production of large volumes at the batholiths level, known as flare-up events. These results are critical in order to estimate the amount of crustal growth and thickening in the Arequipa area, as they provide the basis for the estimation of the mantle versus crustal contribution during the magma genesis.

A Cloud Based Framework For Monitoring And Predicting Subsurface System Behaviour

NASA Astrophysics Data System (ADS)

Versteeg, R. J.; Rodzianko, A.; Johnson, D. V.; Soltanian, M. R.; Dwivedi, D.; Dafflon, B.; Tran, A. P.; Versteeg, O. J.

2015-12-01

Subsurface system behavior is driven and controlled by the interplay of physical, chemical, and biological processes which occur at multiple temporal and spatial scales. Capabilities to monitor, understand and predict this behavior in an effective and timely manner are needed for both scientific purposes and for effective subsurface system management. Such capabilities require three elements: Models, Data and an enabling cyberinfrastructure, which allow users to use these models and data in an effective manner. Under a DOE Office of Science funded STTR award Subsurface Insights and LBNL have designed and implemented a cloud based predictive assimilation framework (PAF) which automatically ingests, controls quality and stores heterogeneous physical and chemical subsurface data and processes these data using different inversion and modeling codes to provide information on the current state and evolution of subsurface systems. PAF is implemented as a modular cloud based software application with five components: (1) data acquisition, (2) data management, (3) data assimilation and processing, (4) visualization and result delivery and (5) orchestration. Serverside PAF uses ZF2 (a PHP web application framework) and Python and both open source (ODM2) and in house developed data models. Clientside PAF uses CSS and JS to allow for interactive data visualization and analysis. Client side modularity (which allows for a responsive interface) of the system is achieved by implementing each core capability of PAF (such as data visualization, user configuration and control, electrical geophysical monitoring and email/SMS alerts on data streams) as a SPA (Single Page Application). One of the recent enhancements is the full integration of a number of flow and mass transport and parameter estimation codes (e.g., MODFLOW, MT3DMS, PHT3D, TOUGH, PFLOTRAN) in this framework. This integration allows for autonomous and user controlled modeling of hydrological and geochemical processes. In our presentation we will discuss our software architecture and present the results of using these codes and the overall developed performance of our framework using hydrological, geochemical and geophysical data from the LBNL SFA2 Rifle field site.

Quantifying Linkages between Biogeochemical Processes in a Contaminated Aquifer-Wetland System Using Multivariate Statistics and HP1

NASA Astrophysics Data System (ADS)

Arora, B.; Mohanty, B. P.; McGuire, J. T.

2009-12-01

Fate and transport of contaminants in saturated and unsaturated zones in the subsurface is controlled by complex biogeochemical processes such as precipitation, sorption-desorption, ion-exchange, redox, etc. In dynamic systems such as wetlands and anaerobic aquifers, these processes are coupled and can interact non-linearly with each other. Variability in measured hydrological, geochemical and microbiological parameters thus corresponds to multiple processes simultaneously. To infer the contributing processes, it is important to eliminate correlations and to identify inter-linkages between factors. The objective of this study is to develop quantitative relationships between hydrological (initial and boundary conditions, hydraulic conductivity ratio, and soil layering), geochemical (mineralogy, surface area, redox potential, and organic matter) and microbiological factors (MPN) that alter the biogeochemical processes at the column scale. Data used in this study were collected from controlled flow experiments in: i) two homogeneous soil columns, ii) a layered soil column, iii) a soil column with embedded clay lenses, and iv) a soil column with embedded clay lenses and one central macropore. The soil columns represent increasing level of soil structural heterogeneity to better mimic the Norman Landfill research site. The Norman Landfill is a closed municipal facility with prevalent organic contamination. The sources of variation in the dataset were explored using multivariate statistical techniques and dominant biogeochemical processes were obtained using principal component analysis (PCA). Furthermore, artificial neural networks (ANN) coupled with HP1 was used to develop mathematical rules identifying different combinations of factors that trigger, sustain, accelerate/decelerate, or discontinue the biogeochemical processes. Experimental observations show that infiltrating water triggers biogeochemical processes in all soil columns. Similarly, slow release of water from low permeability clay lenses sustain biogeochemical cycling for a longer period of time than in homogeneous soil columns. Preliminary results indicate: i) certain variables (anion, cation concentrations, etc.) do not follow normal or lognormal distributions even at the column scale, ii) strong correlations exist between parameters related to redox geochemistry (pH with S2- concentrations), and iii) PCA can identify dominant processes (e.g. iron and sulfate reduction) occurring in the system by grouping together causative variables (e.g. dominant TEAPs).

Reactive transport modeling at uranium in situ recovery sites: uncertainties in uranium sorption on iron hydroxides

USGS Publications Warehouse

Johnson, Raymond H.; Tutu, Hlanganani; Brown, Adrian; Figueroa, Linda; Wolkersdorfer, Christian

2013-01-01

Geochemical changes that can occur down gradient from uranium in situ recovery (ISR) sites are important for various stakeholders to understand when evaluating potential effects on surrounding groundwater quality. If down gradient solid-phase material consists of sandstone with iron hydroxide coatings (no pyrite or organic carbon), sorption of uranium on iron hydroxides can control uranium mobility. Using one-dimensional reactive transport models with PHREEQC, two different geochemical databases, and various geochemical parameters, the uncertainties in uranium sorption on iron hydroxides are evaluated, because these oxidized zones create a greater risk for future uranium transport than fully reduced zones where uranium generally precipitates.

Geochemistry of Fine-grained Sediments and Sedimentary Rocks

NASA Astrophysics Data System (ADS)

Sageman, B. B.; Lyons, T. W.

2003-12-01

The nature of detrital sedimentary (siliciclastic) rocks is determined by geological processes that occur in the four main Earth surface environments encountered over the sediment's history from source to final sink: (i) the site of sediment production (provenance), where interactions among bedrock geology, tectonic uplift, and climate control weathering and erosion processes; (ii) the transport path, where the medium of transport, gradient, and distance to the depositional basin may modify the texture and composition of weathered material; (iii) the site of deposition, where a suite of physical, chemical, and biological processes control the nature of sediment accumulation and early burial modification; and (iv) the conditions of later burial, where diagenetic processes may further alter the texture and composition of buried sediments. Many of these geological processes leave characteristic geochemical signatures, making detrital sedimentary rocks one of the most important archives of geochemical data available for reconstructions of ancient Earth surface environments. Although documentation of geochemical data has long been a part of the study of sedimentation (e.g., Twenhofel, 1926, 1950; Pettijohn, 1949; Trask, 1955), the development and application of geochemical methods specific to sedimentary geological problems blossomed in the period following the Second World War ( Degens, 1965; Garrels and Mackenzie, 1971) and culminated in recent years, as reflected by the publication of various texts on marine geochemistry (e.g., Chester, 1990, 2000), biogeochemistry (e.g., Schlesinger, 1991; Libes, 1992), and organic geochemistry (e.g., Tissot and Welte, 1984; Engel and Macko, 1993).Coincident with the growth of these subdisciplines a new focus has emerged in the geological sciences broadly represented under the title of "Earth System Science" (e.g., Kump et al., 1999). Geochemistry has played the central role in this revolution (e.g., Berner, 1980; Garrels and Lerman, 1981; Berner et al., 1983; Kump et al., 2000), with a shifting emphasis toward sophisticated characterization of the linkages among solid Earth, oceans, biosphere, cryosphere, atmosphere, and climate, mediated by short- and long-term biogeochemical cycles. As a result, one of the primary objectives of current geological inquiry is improved understanding of the interconnectedness and associated feedback among the cycles of carbon, nitrogen, phosphorous, oxygen, and sulfur, and their relationship to the history of Earth's climate. This "Earth System" approach involves uniformitarian extrapolations of knowledge gained from modern environments to proxy-based interpretations of environmental change recorded in ancient strata. The strength of modern data lies with direct observations of pathways and products of physical, chemical, and biological processes, but available time-series are short relative to the response times of many of the biogeochemical systems under study. By contrast, stratigraphically constrained geological data offer time-series that encompass a much fuller range of system response. But with the enhanced breadth of temporal resolution and signal amplitude provided by ancient sedimentary records comes a caveat - we must account for the blurring of primary paleo-environmental signals by preservational artifacts and understand that proxy calibrations are extended from the modern world into a nonsubstantively uniformitarian geological past.Fortunately, detrital sedimentary rocks preserve records of multiple proxies (dependent and independent) that illuminate the processes and conditions of sediment formation, transport, deposition, and burial. An integrated multiproxy approach offers an effective tool for deconvolving the history of biogeochemical cycling of, among other things, carbon and sulfur, and for understanding the range of associated paleo-environmental conditions (e.g., levels of atmospheric oxygen and carbon dioxide, oceanic paleoredox, and paleosalinity). Authors of a single chapter can hope, at best, to present a cursory glance at the many biogeochemical proxies currently used and under development in sedimentary studies. Our goal, instead, is to focus on a selected suite of tools of particular value in the reconstruction of paleo-environments preserved in fine-grained siliciclastic sedimentary rocks.Fine-grained, mixed siliciclastic-biogenic sedimentary facies - commonly termed hemipelagic (mainly calcareous or siliceous mudrocks containing preserved organic matter (OM)) - are ideal for unraveling the geological past and are thus the focus of this chapter. These strata accumulate in predominantly low-energy basinal environments where the magnitude (and frequency) of lacunae is diminished, resulting in relatively continuous, though generally condensed sequences. Fortunately, condensation tends to benefit geochemical analysis as it helps to amplify some subtle environmental signals. Because hemipelagic facies include contributions from both terrigenous detrital and pelagic biogenic systems, as well as from authigenic components reflecting the burial environment (Figure 1), they are rich archives of geochemical information. In this chapter we present a conceptual model linking the major processes of detrital, biogenic, and authigenic accumulation in fine-grained hemipelagic settings. This model is intended to be a fresh synthesis of decades of prior research on the geochemistry of modern and ancient mudrocks, including our own work.

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation

PubMed Central

2011-01-01

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH4+ production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface. PMID:21943229

Assessing the biological contribution to microbialite growth and morphogenesis utilizing lipid biomarkers

NASA Astrophysics Data System (ADS)

Beeler, S. R.; Gomez, F. J.; Bradley, A. S.

2016-12-01

Microbialites are sedimentary structures that arise from the interaction of microbial, geochemical, and physical processes. These structures are among the oldest evidence for life on Earth, and are abundant through much of the Proterozoic before declining in the Phanerozoic. Microbialites are of great importance geobiologically as they provide a record of microbial life and its interaction with the environment throughout Earth history. Yet, our capacity to use microbialites to reconstruct biological processes on ancient Earth is complicated by our lack of understanding of the mechanisms controlling the formation of these structures. The modern microbialites of Laguna Negra in northeastern Argentina [1] offer an opportunity to examine the biological and geochemical differences among microbialites displaying distinct morphological diversity in a single setting. Three broad types of microbialites are found at this site: oncoids, stromatolites, and laminar crusts. Each of these types of microbialites are associated with visually distinct microbial mats. We have examined the structural and isotopic composition of lipid biomarkers from each of these microbialite types, and their associated mats. Sterol profiles detected from microbial mats and microbialites showed abundant C27 to C29 sterols and indicate that primary producers are dominated by algae. Decreased abundances of more labile unsaturated fatty acids relative to more recalcitrant saturated fatty acids were observed in microbialites compared to extant mats suggesting preferential loss of these compounds during diagenesis. Among the three different microbialite morphologies, no statistically discernable differences in biomarker profiles were detected. This implies that morphological changes are due to either geochemical/physical changes across the zone of microbialite formation or changes in community structure that are not observable in the present biomarker set. [1] Gomez et al. (2014) Palaios 29, 233-249

Geochemical evolution of groundwater in the Culebra dolomite near the Waste Isolation Pilot Plant, southeastern New Mexico, USA

USGS Publications Warehouse

Siegel, M.D.; Anderholm, S.

1994-01-01

The Culebra Dolomite Member of the Rustler Formation, a thin (10 m) fractured dolomite aquifer, lies approximately 450 m above the repository horizon of the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico, USA. Salinities of water in the Culebra range roughly from 10,000 to 200,000 mg/L within the WIPP site. A proposed model for the post-Pleistocene hydrochemical evolution of the Culebra tentatively identifies the major sources and sinks for many of the groundwater solutes. Reaction-path simulations with the PHRQPITZ code suggest that the Culebra dolomite is a partial chemical equilibrium system whose composition is controlled by an irreversible process (dissolution of evaporites) and equilibrium with gypsum and calcite. Net geochemical reactions along postulated modern flow paths, calculated with the NETPATH code, include dissolution of halite, carbonate and evaporite salts, and ion exchange. R-mode principal component analysis revealed correlations among the concentrations of Si, Mg, pH, Li, and B that are consistent with several clay-water reactions. The results of the geochemical calculations and mineralogical data are consistent with the following hydrochemical model: 1. (1) solutes are added to the Culebra by dissolution of evaporite minerals 2. (2) the solubilities of gypsum and calcite increase as the salinity increases; these minerals dissolve as chemical equilibrium is maintained between them and the groundwater 3. (3) equilibrium is not maintained between the waters and dolomite; sufficient Mg is added to the waters by dissolution of accessory carnallite or polyhalite such that the degree of dolomite supersaturation increases with ionic strength 4. (4) clays within the fractures and rock matrix exert some control on the distribution of Li, B, Mg, and Si via sorption, ion exchange, and dissolution. ?? 1994.

CO2 flux from Javanese mud volcanism.

PubMed

Queißer, M; Burton, M R; Arzilli, F; Chiarugi, A; Marliyani, G I; Anggara, F; Harijoko, A

2017-06-01

Studying the quantity and origin of CO 2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO 2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO 2 with a volume fraction of at least 16 vol %. A lower limit CO 2 flux of 1.4 kg s -1 (117 t d -1 ) was determined, in line with the CO 2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO 2 flux of 3 kt d -1 , comparable with the expected back-arc efflux of magmatic CO 2 . After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO 2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO 2 , with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO 2 fluxes.

CO2 flux from Javanese mud volcanism

PubMed Central

Burton, M. R.; Arzilli, F.; Chiarugi, A.; Marliyani, G. I.; Anggara, F.; Harijoko, A.

2017-01-01

Abstract Studying the quantity and origin of CO2 emitted by back‐arc mud volcanoes is critical to correctly model fluid‐dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO2 with a volume fraction of at least 16 vol %. A lower limit CO2 flux of 1.4 kg s−1 (117 t d−1) was determined, in line with the CO2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO2 flux of 3 kt d−1, comparable with the expected back‐arc efflux of magmatic CO2. After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO2, with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man‐portable active remote sensing instruments for probing natural gas releases, enabling bottom‐up quantification of CO2 fluxes. PMID:28944134

Dissecting the Hydrobiogeochemical Box

NASA Astrophysics Data System (ADS)

Wang, Y.; Alves Meira Neto, A.; Sengupta, A.; Root, R. A.; Dontsova, K.; Troch, P. A. A.; Chorover, J.

2015-12-01

Soil genesis is a coupled hydrologic and biogeochemical process that involves the interaction of weathering rock surfaces and water. Due to strong nonlinear coupling, it is extremely difficult to predict biogeochemical changes from hydrological modeling in natural field systems. A fully controlled and monitored system with known initial conditions could be utilized to isolate variables and simplify these natural processes. To investigate the initial weathering of host rock to soil, we employed a 10° sloping soil lysimeter containing one cubic meter of crushed and homogenized basaltic rock. A major experiment of the Periodic Tracer Hierarchy (PERTH) method (Harman and Kim, 2014) coupled with its bonus experiment were performed in the past two years. These experimental applications successfully described the transit-time distribution (TTD) of a tracer-enriched water breakthrough curve in this unique hydrological system (Harman, 2015). With intensive irrigation and high volume of water storage throughout the experiments, rapid biological changes have been observed on the soil surface, such as algal and grass growth. These observations imply that geochemical hotspots may be established within the soil lysimeter. To understand the detailed 2D spatial distribution of biogeochemical changes, 100 selected and undisturbed soil blocks, among a total 1000 sub-gridded equal sized, are tested with several geochemical tools. Each selected soil block was subjected to elemental analysis by pXRF to determine if elemental migration is detectable in the dynamic proto-soil development. Synchrotron XRD quantification with Reitveld refinement will follow to clarify mineralogical transformations in the soil blocks. The combined techniques aim to confirm the development of geochemical hotspots; and link these findings with previous hydrological findings from the PERTH experiment as well as other hydrological modeling, such as conducted with Hydrus and CATHY. This work provides insight to the detailed correlations between hydrological and biogeochemical processes during incipient soil formation, as well as aiding the development of advanced tools and methods to study complex Earth-system dynamics.

Magnesium isotope fractionation in bacterial mediated carbonate precipitation experiments

NASA Astrophysics Data System (ADS)

Parkinson, I. J.; Pearce, C. R.; Polacskek, T.; Cockell, C.; Hammond, S. J.

2012-12-01

Magnesium is an essential component of life, with pivotal roles in the generation of cellular energy as well as in plant chlorophyll [1]. The bio-geochemical cycling of Mg is associated with mass dependant fractionation (MDF) of the three stable Mg isotopes [1]. The largest MDF of Mg isotopes has been recorded in carbonates, with foraminiferal tests having δ26Mg compositions up to 5 ‰ lighter than modern seawater [2]. Magnesium isotopes may also be fractionated during bacterially mediated carbonate precipitation and such carbonates are known to have formed in both modern and ancient Earth surface environments [3, 4], with cyanobacteria having a dominant role in carbonate formation during the Archean. In this study, we aim to better constrain the extent to which Mg isotope fractionation occurs during cellular processes, and to identify when, and how, this signal is transferred to carbonates. To this end we have undertaken biologically-mediated carbonate precipitation experiments that were performed in artificial seawater, but with the molar Mg/Ca ratio set to 0.6 and with the solution spiked with 0.4% yeast extract. The bacterial strain used was marine isolate Halomonas sp. (gram-negative). Experiments were run in the dark at 21 degree C for two to three months and produced carbonate spheres of various sizes up to 300 μm in diameter, but with the majority have diameters of ~100 μm. Control experiments run in sterile controls (`empty` medium without bacteria) yielded no precipitates, indicating a bacterial control on the precipitation. The carbonate spheres are produced are amenable to SEM, EMP and Mg isotopic analysis by MC-ICP-MS. Our new data will shed light on tracing bacterial signals in carbonates from the geological record. [1] Young & Galy (2004). Rev. Min. Geochem. 55, p197-230. [2] Pogge von Strandmann (2008). Geochem. Geophys. Geosys. 9 DOI:10.1029/2008GC002209. [3] Castanier, et al. (1999). Sed. Geol. 126, 9-23. [4] Cacchio, et al. (2003). Geomicrobiol. J. 20, 85-98.

Adjustment of geochemical background by robust multivariate statistics

USGS Publications Warehouse

Zhou, D.

1985-01-01

Conventional analyses of exploration geochemical data assume that the background is a constant or slowly changing value, equivalent to a plane or a smoothly curved surface. However, it is better to regard the geochemical background as a rugged surface, varying with changes in geology and environment. This rugged surface can be estimated from observed geological, geochemical and environmental properties by using multivariate statistics. A method of background adjustment was developed and applied to groundwater and stream sediment reconnaissance data collected from the Hot Springs Quadrangle, South Dakota, as part of the National Uranium Resource Evaluation (NURE) program. Source-rock lithology appears to be a dominant factor controlling the chemical composition of groundwater or stream sediments. The most efficacious adjustment procedure is to regress uranium concentration on selected geochemical and environmental variables for each lithologic unit, and then to delineate anomalies by a common threshold set as a multiple of the standard deviation of the combined residuals. Robust versions of regression and RQ-mode principal components analysis techniques were used rather than ordinary techniques to guard against distortion caused by outliers Anomalies delineated by this background adjustment procedure correspond with uranium prospects much better than do anomalies delineated by conventional procedures. The procedure should be applicable to geochemical exploration at different scales for other metals. ?? 1985.

Sr/Ca and Mg/Ca in Glycymeris glycymeris (Bivalvia) shells from the Iberian upwelling system: Ontogeny and environmental control

NASA Astrophysics Data System (ADS)

Freitas, Pedro; Richardson, Christopher; Chenery, Simon; Monteiro, Carlos; Butler, Paul; Reynolds, David; Scourse, James; Gaspar, Miguel

2017-04-01

Bivalve shells have a great potential as high-resolution geochemical proxy archives of marine environmental conditions. In addition, sclerochronology of long-lived bivalve species (e.g. Arctica islandica) provides a timeline of absolutely dated shell material for geochemical analysis that can extend into the past beyond the lifetime of single individuals through the use of replicated crossmatched centennial to millennial chronologies. However, the interpretation of such records remains extremely challenging and complex, with multiple environmental and biological processes affecting element incorporation in the shell (e.g. crystal fabrics, organic matrix, biomineralization mechanisms and physiological processes). As a result, the effective use of bivalve shell elemental/Ca ratios as palaeoenvironmental proxies has been limited, often to species-specific applications or applications restricted to particular environmental settings. The dog-cockle, Glycymeris glycymeris, is a relatively long-lived bivalve (up to 200 years) that occurs in coarse-grained subtidal sediments of coastal shelf seas of Europe and North West Africa. Glycymeris glycymeris shells provide a valuable, albeit not fully explored, archive to reconstruct past environmental variability in an area lacking sclerochronological studies due to the rarity of long-lived bivalves and lack of coral reefs. In this study, we evaluate the potential of Sr/Ca and Mg/Ca ratios in G. glycymeris shells as geochemical proxies of upwelling conditions in the Iberian Upwelling System, the northern section of the Canary Current Eastern Boundary Upwelling System. Sr/Ca and Mg/Ca generally co-varied significantly and a clear ontogenetic, non-environmental related change in Sr/Ca and Ba/Ca variability was observed. High Sr/Ca and Mg/Ca ratios in older shells (> 10 years old) were found to be associated with the occurrence of growth lines deposited during the winter reduction in shell growth. Nevertheless, Sr/Ca and Mg/Ca variation in older shells was synchronous with contemporary environmental conditions, i.e. upwelling intensity and salinity. The use of Sr or Mg in G. glycymeris shells as valid geochemical environmental proxies in the Iberian Upwelling System remains complex and requires further research to unravel environmental and physiological/biomineralization controls. This study was financed by the Portuguese Fundação para a Ciência e Tecnologia (FCT) GLYCY Project (contract PTDC/AAC-CLI/118003/2010) and a sabbatical grant to PSF (Ref: SFRH/BSAB/127786/2016), co-supported by POCH and the European Social Fund. Funding for consumable costs was provided by Bangor University.

Modeling low-temperature geochemical processes: Chapter 2

USGS Publications Warehouse

Nordstrom, D. Kirk; Campbell, Kate M.

2014-01-01

This chapter provides an overview of geochemical modeling that applies to water–rock interactions under ambient conditions of temperature and pressure. Topics include modeling definitions, historical background, issues of activity coefficients, popular codes and databases, examples of modeling common types of water–rock interactions, and issues of model reliability. Examples include speciation, microbial redox kinetics and ferrous iron oxidation, calcite dissolution, pyrite oxidation, combined pyrite and calcite dissolution, dedolomitization, seawater–carbonate groundwater mixing, reactive-transport modeling in streams, modeling catchments, and evaporation of seawater. The chapter emphasizes limitations to geochemical modeling: that a proper understanding and ability to communicate model results well are as important as completing a set of useful modeling computations and that greater sophistication in model and code development is not necessarily an advancement. If the goal is to understand how a particular geochemical system behaves, it is better to collect more field data than rely on computer codes.

Hawai'i and Gale Crater: A Mars Analogue Study of Igneous, Sedimentary, Weathering, and Alteration Trends in Geochemistry

NASA Technical Reports Server (NTRS)

Berger, J. A.; Flemming, R. L.; Schmidt, M. E.; Gellert, R.; Morris, R. V.; Ming, D. W.

2017-01-01

Sedimentary rocks in Gale Crater on Mars indicate a varied provenance with a range of alteration and weathering [1, 2]. Geochemical trends identified in basaltic and alkalic sedimentary rocks by the Alpha Particle X-ray Spectrometer (APXS) on the Mars rover Curiosity represent a complex interplay of igneous, sedimentary, weathering, and alteration processes. Assessing the relative importance of these processes is challenging with unknown compositions for parent sediment sources and with the constraints provided by Curiosity's instruments. We therefore look to Mars analogues on Earth where higher-resolution analyses and geologic context can constrain interpretations of Gale Crater geochemical observations. We selected Maunakea (AKA Mauna Kea) and Kohala volcanoes, Hawai'i, for an analogue study because they are capped by post-shield transitional basalts and alkalic lavas (hawaiites, mugearites) with compositions similar to Gale Crater [1, 3]. Our aim was to characterize Hawaiian geochemical trends associated with igneous processes, sediment transport, weathering, and alteration. Here, we present initial results and discuss implications for selected trends observed by APXS in Gale Crater.

Early dolomitization in the Lower Cretaceous shallow-water carbonates of Southern Apennines (Italy): Clues about palaeoclimatic fluctuations in western Tethys

NASA Astrophysics Data System (ADS)

Vinci, Francesco; Iannace, Alessandro; Parente, Mariano; Pirmez, Carlos; Torrieri, Stefano; Giorgioni, Maurizio

2017-12-01

A multidisciplinary study of the dolomitized bodies present in the Lower Cretaceous platform carbonates of Mt. Faito (Southern Apennines - Italy) was carried out in order to explore the connection between early dolomite formation and fluctuating climate conditions. The Berriasian-Aptian investigated succession is 466 m thick and mainly consists of shallow-water lagoonal limestones with frequent dolomite caps. The dolomitization intensity varies along the succession and reaches its peak in the upper Hauterivian-lower Barremian interval, where it is present a completely dolomitized interval about 100-m-thick. Field relations, petrography, mineralogy, and geochemistry of the analyzed dolomite bodies allowed identifying two populations of early dolomites, a fine-medium crystalline (FMdol) and a coarse crystalline dolomite (Cdol), both interpreted as the product of mesohaline water reflux. According to our interpretation, FMdol precipitated from concentrated brines in the very early stage of the reflux process, producing typical sedimentary features as dolomite caps. In the successive step of the process, the basin-ward 'latent' reflux precipitated Cdol from less concentrated brines. A peculiar feature of the studied succession is the great consistency between stratigraphic distribution of dolomite bodies and their geochemical signature. The completely dolomitized Hauterivian-Barremian interval, in fact, is characterized by geochemical values suggesting an origin from distinctly saltier brines. Considering that the observed near-surface dolomitization process is controlled by physical and chemical parameters reflecting the paleoenvironmental and paleoclimatic conditions during dolomite formation, we propose that the stratigraphically controlled dolomitization intensity reflects periodic fluctuations in the salinity of dolomitizing fluid, in turn controlled by long-term climate oscillations. The present work highlights that the stratigraphic distribution of early diagenetic dolomite may be used as proxy to define the climatic fluctuations that have influenced the sedimentary dynamics in the Early Cretaceous. Moreover, considering that a comparable early dolomite distribution is present also in the Dinaric Platform, we suggest that a regional scale climate control acted on early dolomite formation and distribution. Refining the knowledge of such a key control may have a significative impact on hydrocarbon reservoir characterization and exploration in the Periadriatic area.

Alaska Geochemical Database, Version 2.0 (AGDB2)--including “best value” data compilations for rock, sediment, soil, mineral, and concentrate sample media

USGS Publications Warehouse

Granitto, Matthew; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

2013-01-01

The Alaska Geochemical Database Version 2.0 (AGDB2) contains new geochemical data compilations in which each geologic material sample has one “best value” determination for each analyzed species, greatly improving speed and efficiency of use. Like the Alaska Geochemical Database (AGDB, http://pubs.usgs.gov/ds/637/) before it, the AGDB2 was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This relational database, created from the Alaska Geochemical Database (AGDB) that was released in 2011, serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables in several different formats describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey personnel and analyzed in U.S. Geological Survey laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various U.S. Geological Survey programs and projects from 1962 through 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy-mineral concentrate samples are included in this database. The AGDB2 includes historical geochemical data originally archived in the U.S. Geological Survey Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the U.S. Geological Survey PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all U.S. Geological Survey geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest U.S. Geological Survey geochemical databases, or were once excluded for programmatic reasons, are included here in the AGDB2 and will be added to the NGDB. The AGDB2 data provided here are the most accurate and complete to date, and should be useful for a wide variety of geochemical studies. The AGDB2 data provided in the linked database may be updated or changed periodically.

Complex resistivity signatures of ethanol biodegradation in porous media

USGS Publications Warehouse

Personna, Yves Robert; Slater, Lee; Ntarlagiannis, Dimitrios; Werkema, Dale D.; Szabo, Zoltan

2013-01-01

Numerous adverse effects are associated with the accidental release of ethanol (EtOH) and its persistence in the subsurface. Geophysical techniques may permit non-invasive, real time monitoring of microbial degradation of hydrocarbon. We performed complex resistivity (CR) measurements in conjunction with geochemical data analysis on three microbial-stimulated and two control columns to investigate changes in electrical properties during EtOH biodegradation processes in porous media. A Debye Decomposition approach was applied to determine the chargeability (m), normalized chargeability (mn) and time constant (τ) of the polarization magnitude and relaxation length scale as a function of time. The CR responses showed a clear distinction between the bioaugmented and control columns in terms of real (σ′) and imaginary (σ″) conductivity, phase (ϕ) and apparent formation factor (Fapp). Unlike the control columns, a substantial decrease in σ′ and increase in Fapp occurred at an early time (within 4 days) of the experiment for all three bioaugmented columns. The observed decrease in σ′ is opposite to previous studies on hydrocarbon biodegradation. These columns also exhibited increases in ϕ (up to ~ 9 mrad) and σ″ (up to two order of magnitude higher) 5 weeks after microbial inoculation. Variations in m and mn were consistent with temporal changes in ϕ and σ″ responses, respectively. Temporal geochemical changes and high resolution scanning electron microscopy imaging corroborated the CR findings, thus indicating the sensitivity of CR measurements to EtOH biodegradation processes. Our results offer insight into the potential application of CR measurements for long-term monitoring of biogeochemical and mineralogical changes during intrinsic and induced EtOH biodegradation in the subsurface.

GIS Methodic and New Database for Magmatic Rocks. Application for Atlantic Oceanic Magmatism.

NASA Astrophysics Data System (ADS)

Asavin, A. M.

2001-12-01

There are several geochemical Databases in INTERNET available now. There one of the main peculiarities of stored geochemical information is geographical coordinates of each samples in those Databases. As rule the software of this Database use spatial information only for users interface search procedures. In the other side, GIS-software (Geographical Information System software),for example ARC/INFO software which using for creation and analyzing special geological, geochemical and geophysical e-map, have been deeply involved with geographical coordinates for of samples. We join peculiarities GIS systems and relational geochemical Database from special software. Our geochemical information system created in Vernadsky Geological State Museum and institute of Geochemistry and Analytical Chemistry from Moscow. Now we tested system with data of geochemistry oceanic rock from Atlantic and Pacific oceans, about 10000 chemical analysis. GIS information content consist from e-map covers Wold Globes. Parts of these maps are Atlantic ocean covers gravica map (with grid 2''), oceanic bottom hot stream, altimeteric maps, seismic activity, tectonic map and geological map. Combination of this information content makes possible created new geochemical maps and combination of spatial analysis and numerical geochemical modeling of volcanic process in ocean segment. Now we tested information system on thick client technology. Interface between GIS system Arc/View and Database resides in special multiply SQL-queries sequence. The result of the above gueries were simple DBF-file with geographical coordinates. This file act at the instant of creation geochemical and other special e-map from oceanic region. We used more complex method for geophysical data. From ARC\\View we created grid cover for polygon spatial geophysical information.

Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaplan, Daniel I.

The Savannah River Site (SRS) disposes of low-level radioactive waste (LLW) and stabilizes high-level radioactive waste (HLW) tanks in the subsurface environment. Calculations used to establish the radiological limits of these facilities are referred to as Performance Assessments (PA), Special Analyses (SA), and Composite Analyses (CA). The objective of this document is to revise existing geochemical input values used for these calculations. This work builds on earlier compilations of geochemical data (2007, 2010), referred to a geochemical data packages. This work is being conducted as part of the on-going maintenance program of the SRS PA programs that periodically updates calculationsmore » and data packages when new information becomes available. Because application of values without full understanding of their original purpose may lead to misuse, this document also provides the geochemical conceptual model, the approach used for selecting the values, the justification for selecting data, and the assumptions made to assure that the conceptual and numerical geochemical models are reasonably conservative (i.e., bias the recommended input values to reflect conditions that will tend to predict the maximum risk to the hypothetical recipient). This document provides 1088 input parameters for geochemical parameters describing transport processes for 64 elements (>740 radioisotopes) potentially occurring within eight subsurface disposal or tank closure areas: Slit Trenches (ST), Engineered Trenches (ET), Low Activity Waste Vault (LAWV), Intermediate Level (ILV) Vaults, Naval Reactor Component Disposal Areas (NRCDA), Components-in-Grout (CIG) Trenches, Saltstone Facility, and Closed Liquid Waste Tanks. The geochemical parameters described here are the distribution coefficient, Kd value, apparent solubility concentration, k s value, and the cementitious leachate impact factor.« less

Chain of custody; recommendations for acceptance and analysis of evidentiary geochemical samples

USGS Publications Warehouse

Murphy, Christine M.; Briggs, Paul H.; Adrian, Betty M.; Wilson, Steve A.; Hageman, Phil L.; Theodorakos, Pete M.

1997-01-01

Personnel from the Analytical Chemistry Services Group (ACSG), Mineral Resource Survey Program, formed a team to determine the policies for acceptance and analysis of geochemical samples. This team contacted law enforcement agencies that handle litigious samples, laboratories that work with samples of special nature, and the Solicitor General, Department of the Interior. Using the knowledge from these agencies as well as the expertise of ACSG personnel, sample control routine procedures, sample control evidentiary procedures, personnel policy governing chain-of-custody samples, and the general polices governing physical security of chain-of custody samples have been enacted.

Biological reduction of chlorinated solvents: Batch-scale geochemical modeling

NASA Astrophysics Data System (ADS)

Kouznetsova, Irina; Mao, Xiaomin; Robinson, Clare; Barry, D. A.; Gerhard, Jason I.; McCarty, Perry L.

2010-09-01

Simulation of biodegradation of chlorinated solvents in dense non-aqueous phase liquid (DNAPL) source zones requires a model that accounts for the complexity of processes involved and that is consistent with available laboratory studies. This paper describes such a comprehensive modeling framework that includes microbially mediated degradation processes, microbial population growth and decay, geochemical reactions, as well as interphase mass transfer processes such as DNAPL dissolution, gas formation and mineral precipitation/dissolution. All these processes can be in equilibrium or kinetically controlled. A batch modeling example was presented where the degradation of trichloroethene (TCE) and its byproducts and concomitant reactions (e.g., electron donor fermentation, sulfate reduction, pH buffering by calcite dissolution) were simulated. Local and global sensitivity analysis techniques were applied to delineate the dominant model parameters and processes. Sensitivity analysis indicated that accurate values for parameters related to dichloroethene (DCE) and vinyl chloride (VC) degradation (i.e., DCE and VC maximum utilization rates, yield due to DCE utilization, decay rate for DCE/VC dechlorinators) are important for prediction of the overall dechlorination time. These parameters influence the maximum growth rate of the DCE and VC dechlorinating microorganisms and, thus, the time required for a small initial population to reach a sufficient concentration to significantly affect the overall rate of dechlorination. Self-inhibition of chlorinated ethenes at high concentrations and natural buffering provided by the sediment were also shown to significantly influence the dechlorination time. Furthermore, the analysis indicated that the rates of the competing, nonchlorinated electron-accepting processes relative to the dechlorination kinetics also affect the overall dechlorination time. Results demonstrated that the model developed is a flexible research tool that is able to provide valuable insight into the fundamental processes and their complex interactions during bioremediation of chlorinated ethenes in DNAPL source zones.

Review of the impacts of leaking CO 2 gas and brine on groundwater quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qafoku, Nikolla P.; Lawter, Amanda R.; Bacon, Diana H.

2017-06-01

This review paper provides a synthetic view of the existing knowledge and summarizes data and findings of the recent literature on the subject of the potential leaking of CO2 from the deep subsurface storage reservoirs and the effects on aquifer quality. New ideas and concepts are developed and insights are also provided. The objectives of this paper are to: 1) present and discuss potential risks for groundwater degradation due to CO2 gas and brine exposure; 2) identify the set of geochemical data required to assess and predict aquifer responses to CO2 and brine leakage. Specifically, this paper will discuss themore » following issues: 1) Aquifer responses (such as changes in aqueous phase/groundwater chemical composition; changes in solid phase chemistry and mineralogy; changes in the extent and rate of reactions and processes and possible establishment of a new network of reactions and processes affecting or controlling overall mobility of major, minor, and trace elements; development of conceptual and reduced order models (ROMs) to describe and predict aquifer responses); 2) The degree of impact such as significant or insignificant changes in pH and major, minor, and trace element release that depend on the following controlling variables; the effect of leaking plume characteristics (gas composition, pure CO2 and/or CO2 -CH4 -H2S mixtures and brine concentration and composition (trace metals); aquifer properties [such as initial aqueous phase conditions and mineralogy: minerals controlling sediments’ response (e.g., calcite, Si bearing minerals, etc.)]; overview of relevant hydrogeological and geochemical processes related to the impact of CO2 gas and brine on groundwater quality; the fate of the elements released from sediments or transported with brine (such as precipitation/incorporation into minerals (calcite and other minerals), adsorption, electron transfer reactions, the role of natural attenuation; whether or not the release of metals following exposure to CO2 harmful (risk assessment).« less

Geochemical data for Colorado soils-Results from the 2006 state-scale geochemical survey

USGS Publications Warehouse

Smith, David B.; Ellefsen, Karl J.; Kilburn, James E.

2010-01-01

In 2006, soil samples were collected at 960 sites (1 site per 280 square kilometers) throughout the state of Colorado. These samples were collected from a depth of 0-15 centimeters and, following a near-total multi-acid digestion, were analyzed for a suite of more than 40 major and trace elements. The resulting data set provides a baseline for the natural variation in soil geochemistry for Colorado and forms the basis for detecting changes in soil composition that might result from natural processes or anthropogenic activities. This report describes the sampling and analytical protocols used and makes available all the soil geochemical data generated in the study.

Mercury Slovenian soils: High, medium and low sample density geochemical maps

NASA Astrophysics Data System (ADS)

Gosar, Mateja; Šajn, Robert; Teršič, Tamara

2017-04-01

Regional geochemical survey was conducted in whole territory of Slovenia (20273 km2). High, medium and low sample density surveys were compared. High sample density represented the regional geochemical data set supplemented by local high-density sampling data (irregular grid, n=2835). Medium-density soil sampling was performed in a 5 x 5 km grid (n=817) and low-density geochemical survey was conducted in a sampling grid 25 x 25 km (n=54). Mercury distribution in Slovenian soils was determined with models of mercury distribution in soil using all three data sets. A distinct Hg anomaly in western part of Slovenia is evident on all three models. It is a consequence of 500-years of mining and ore processing in the second largest mercury mine in the world, the Idrija mine. The determined mercury concentrations revealed an important difference between the western and the eastern parts of the country. For the medium scale geochemical mapping is the median value (0.151 mg /kg) for western Slovenia almost 2-fold higher than the median value (0.083 mg/kg) in eastern Slovenia. Besides the Hg median for the western part of Slovenia exceeds the Hg median for European soil by a factor of 4 (Gosar et al., 2016). Comparing these sample density surveys, it was shown that high sampling density allows the identification and characterization of anthropogenic influences on a local scale, while medium- and low-density sampling reveal general trends in the mercury spatial distribution, but are not appropriate for identifying local contamination in industrial regions and urban areas. The resolution of the pattern generated is the best when the high-density survey on a regional scale is supplemented with the geochemical data of the high-density surveys on a local scale. References: Gosar, M, Šajn, R, Teršič, T. Distribution pattern of mercury in the Slovenian soil: geochemical mapping based on multiple geochemical datasets. Journal of geochemical exploration, 2016, 167/38-48.

Development of a Model of Geophysical and Geochemical Controls on Abiotic Carbon Cycling on Earth-Like Planets

NASA Astrophysics Data System (ADS)

Neveu, M.; Felton, R.; Domagal-Goldman, S. D.; Desch, S. J.; Arney, G. N.

2017-12-01

About 20 Earth-sized planets (0.6-1.6 Earth masses and radii) have now been discovered beyond our solar system [1]. Although such planets are prime targets in the upcoming search for atmospheric biosignatures, their composition, geology, and climate are essentially unconstrained. Yet, developing an understanding of how these factors influence planetary evolution through time and space is essential to establishing abiotic backgrounds against which any deviations can provide evidence for biological activity. To this end, we are building coupled geophysical-geochemical models of abiotic carbon cycling on such planets. Our models are controlled by atmospheric factors such as temperature and composition, and compute interior inputs to atmospheric species. They account for crustal weathering, ocean-atmosphere equilibria, and exchange with the deep interior as a function of planet composition and size (and, eventually, age).Planets in other solar systems differ from the Earth not only in their bulk physical properties, but also likely in their bulk chemical composition [2], which influences key parameters such as the vigor of mantle convection and the near-surface redox state. Therefore, simulating how variations in such parameters affect carbon cycling requires us to simulate the above processes from first principles, rather than by using arbitrary parameterizations derived from observations as is often done with models of carbon cycling on Earth [3] or extrapolations thereof [4]. As a first step, we have developed a kinetic model of crustal weathering using the PHREEQC code [5] and kinetic data from [6]. We will present the ability of such a model to replicate Earth's carbon cycle using, for the time being, parameterizations for surface-interior-atmosphere exchange processes such as volcanism (e.g., [7]).[1] exoplanet.eu, 7/28/2017.[2] Young et al. (2014) Astrobiology 14, 603-626.[3] Lerman & Wu (2008) Kinetics of Global Geochemical Cycles. In Kinetics of Water-Rock Interaction (Brantley et al., eds.), Springer, New York.[4] Edson et al. (2012) Astrobiology 12, 562-571.[5] Parkhurst & Appelo (2013) USGS Techniques and Methods 6-A43.[6] Palandri & Kharaka (2008) USGS Report 2004-1068.[7] Kite et al. (2009) ApJ 700, 1732-1749.

Spatial patterns and controls of soil chemical weathering rates along a transient hillslope

USGS Publications Warehouse

Yoo, K.; Mudd, S.M.; Sanderman, J.; Amundson, Ronald; Blum, A.

2009-01-01

Hillslopes have been intensively studied by both geomorphologists and soil scientists. Whereas geomorphologists have focused on the physical soil production and transport on hillslopes, soil scientists have been concerned with the topographic variation of soil geochemical properties. We combined these differing approaches and quantified soil chemical weathering rates along a grass covered hillslope in Coastal California. The hillslope is comprised of both erosional and depositional sections. In the upper eroding section, soil production is balanced by physical erosion and chemical weathering. The hillslope then transitions to a depositional slope where soil accumulates due to a historical reduction of channel incision at the hillslope's base. Measurements of hillslope morphology and soil thickness were combined with the elemental composition of the soil and saprolite, and interpreted through a process-based model that accounts for both chemical weathering and sediment transport. Chemical weathering of the minerals as they moved downslope via sediment transport imparted spatial variation in the geochemical properties of the soil. Inverse modeling of the field and laboratory data revealed that the long-term soil chemical weathering rates peak at 5 g m- 2 yr- 1 at the downslope end of the eroding section and decrease to 1.5 g m- 2 yr- 1 within the depositional section. In the eroding section, soil chemical weathering rates appear to be primarily controlled by the rate of mineral supply via colluvial input from upslope. In the depositional slope, geochemical equilibrium between soil water and minerals appeared to limit the chemical weathering rate. Soil chemical weathering was responsible for removing 6% of the soil production in the eroding section and 5% of colluvial influx in the depositional slope. These were among the lowest weathering rates reported for actively eroding watersheds, which was attributed to the parent material with low amount of weatherable minerals and intense coating of the primary minerals by secondary clay and iron oxides. We showed that both the morphologic disequilibrium of the hillslope and the spatial heterogeneity of soil properties are due to spatial variations in the physical and chemical processes that removed mass from the soil. ?? 2009 Elsevier B.V.

Low-oxygen and chemical kinetic constraints on the geochemical niche of neutrophilic iron(II) oxidizing microorganisms

NASA Astrophysics Data System (ADS)

Druschel, Gregory K.; Emerson, David; Sutka, R.; Suchecki, P.; Luther, George W., III

2008-07-01

Neutrophilic iron oxidizing bacteria (FeOB) must actively compete with rapid abiotic processes governing Fe(II) oxidation and as a result have adapted to primarily inhabit low-O 2 environments where they can more successfully compete with abiotic Fe(II) oxidation. The spatial distribution of these microorganisms can be observed through the chemical gradients they affect, as measured using in situ voltammetric analysis for dissolved Fe(II), Fe(III), O 2, and FeS (aq). Field and laboratory determination of the chemical environments inhabited by the FeOB were coupled with detailed kinetic competition studies for abiotic and biotic oxidation processes using a pure culture of FeOB to quantify the geochemical niche these organisms inhabit. In gradient culture tubes, the maximum oxygen levels, which were associated with growth bands of Sideroxydans lithotrophicus (ES-1, a novel FeOB), were 15-50 μM. Kinetic measurements made on S. lithotrophicus compared biotic/abiotic (killed control) Fe oxidation rates. The biotic rate can be a significant and measurable fraction of the total Fe oxidation rate below O 2 concentrations of approximately 50 μM, but biotic Fe(II) oxidation (via the biotic/abiotic rate comparison) becomes difficult to detect at higher O 2 levels. These results are further supported by observations of conditions supporting FeOB communities in field settings. Variablity in cell densities and cellular activity as well as variations in hydrous ferrous oxide mineral quantities significantly affect the laboratory kinetic rates. The microbial habitat (or geochemical niche) where FeOB are active is thus largely controlled by the competition between abiotic and biotic kinetics, which are dependent on Fe(II) concentration, P O2, temperature and pH in addition to the surface area of hydrous ferric oxide minerals and the cell density/activity of FeOB. Additional field and lab culture observations suggest a potentially important role for the iron-sulfide aqueous molecular cluster, FeS (aq), in the overall cycling of iron associated with the environments these microorganisms inhabit.

Bacterial communities associated with subsurface geochemical processes in continental serpentinite springs.

PubMed

Brazelton, William J; Morrill, Penny L; Szponar, Natalie; Schrenk, Matthew O

2013-07-01

Reactions associated with the geochemical process of serpentinization can generate copious quantities of hydrogen and low-molecular-weight organic carbon compounds, which may provide energy and nutrients to sustain subsurface microbial communities independently of the photosynthetically supported surface biosphere. Previous microbial ecology studies have tested this hypothesis in deep sea hydrothermal vents, such as the Lost City hydrothermal field. This study applied similar methods, including molecular fingerprinting and tag sequencing of the 16S rRNA gene, to ultrabasic continental springs emanating from serpentinizing ultramafic rocks. These molecular surveys were linked with geochemical measurements of the fluids in an interdisciplinary approach designed to distinguish potential subsurface organisms from those derived from surface habitats. The betaproteobacterial genus Hydrogenophaga was identified as a likely inhabitant of transition zones where hydrogen-enriched subsurface fluids mix with oxygenated surface water. The Firmicutes genus Erysipelothrix was most strongly correlated with geochemical factors indicative of subsurface fluids and was identified as the most likely inhabitant of a serpentinization-powered subsurface biosphere. Both of these taxa have been identified in multiple hydrogen-enriched subsurface habitats worldwide, and the results of this study contribute to an emerging biogeographic pattern in which Betaproteobacteria occur in near-surface mixing zones and Firmicutes are present in deeper, anoxic subsurface habitats.

Bacterial Communities Associated with Subsurface Geochemical Processes in Continental Serpentinite Springs

PubMed Central

Morrill, Penny L.; Szponar, Natalie; Schrenk, Matthew O.

2013-01-01

Reactions associated with the geochemical process of serpentinization can generate copious quantities of hydrogen and low-molecular-weight organic carbon compounds, which may provide energy and nutrients to sustain subsurface microbial communities independently of the photosynthetically supported surface biosphere. Previous microbial ecology studies have tested this hypothesis in deep sea hydrothermal vents, such as the Lost City hydrothermal field. This study applied similar methods, including molecular fingerprinting and tag sequencing of the 16S rRNA gene, to ultrabasic continental springs emanating from serpentinizing ultramafic rocks. These molecular surveys were linked with geochemical measurements of the fluids in an interdisciplinary approach designed to distinguish potential subsurface organisms from those derived from surface habitats. The betaproteobacterial genus Hydrogenophaga was identified as a likely inhabitant of transition zones where hydrogen-enriched subsurface fluids mix with oxygenated surface water. The Firmicutes genus Erysipelothrix was most strongly correlated with geochemical factors indicative of subsurface fluids and was identified as the most likely inhabitant of a serpentinization-powered subsurface biosphere. Both of these taxa have been identified in multiple hydrogen-enriched subsurface habitats worldwide, and the results of this study contribute to an emerging biogeographic pattern in which Betaproteobacteria occur in near-surface mixing zones and Firmicutes are present in deeper, anoxic subsurface habitats. PMID:23584766

An early-branching microbialite cyanobacterium forms intracellular carbonates.

PubMed

Couradeau, Estelle; Benzerara, Karim; Gérard, Emmanuelle; Moreira, David; Bernard, Sylvain; Brown, Gordon E; López-García, Purificación

2012-04-27

Cyanobacteria have affected major geochemical cycles (carbon, nitrogen, and oxygen) on Earth for billions of years. In particular, they have played a major role in the formation of calcium carbonates (i.e., calcification), which has been considered to be an extracellular process. We identified a cyanobacterium in modern microbialites in Lake Alchichica (Mexico) that forms intracellular amorphous calcium-magnesium-strontium-barium carbonate inclusions about 270 nanometers in average diameter, revealing an unexplored pathway for calcification. Phylogenetic analyses place this cyanobacterium within the deeply divergent order Gloeobacterales. The chemical composition and structure of the intracellular precipitates suggest some level of cellular control on the biomineralization process. This discovery expands the diversity of organisms capable of forming amorphous calcium carbonates.

Crustal contamination and crystal entrapment during polybaric magma evolution at Mt. Somma-Vesuvius volcano, Italy: Geochemical and Sr isotope evidence

USGS Publications Warehouse

Piochi, M.; Ayuso, R.A.; de Vivo, B.; Somma, R.

2006-01-01

New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma-Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Sr-isotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation-Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC-AFC) formulation. J. Petrol. 999-1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energy-constrained assimilation-fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol. 1019-1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9-10 km) is a fundamental process controlling magma compositions at Mt. Somma-Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions. ?? 2005 Elsevier B.V. All rights reserved.

Infiltration processes in karstic chalk investigated through a spatial analysis of the geochemical properties of the groundwater: The effect of the superficial layer of clay-with-flints

NASA Astrophysics Data System (ADS)

Valdes, Danièle; Dupont, Jean-Paul; Laignel, Benoît; Slimani, Smaïl; Delbart, Célestine

2014-11-01

In the Paris Basin in Upper Normandy (France), the chalk plateaus are covered with thick deposits of loess and clay-with-flints, from a few meters to approximately 40 m thick locally. A perched groundwater is sometimes observed in the superficial layers in which evapotranspiration processes seem to occur. This study's objective was to understand the effects of the thick clay-with-flints layers on the infiltration processes. To achieve this, we adopted a spatial approach comparing the maps of the geochemical properties of the Chalk groundwater and the maps of the thickness of clay-with-flints. The French national groundwater database, ADES (Accès aux Données des Eaux, BRGM), provided the mean geochemical properties in the Chalk aquifer of Upper Normandy. This database was used to prepare maps of the environmental tracers: Ca2+, HCO3-, Mg2+, Cl-, Na+, NO3-, and SO42. The data are spatially well organized. Using principal component analysis (PCA), these maps were compared with the maps of the thickness of clay-with-flints. A focus on the coastal basins (northern Upper Normandy) shows a very strong spatial correlation between the maps of clay-with-flints thickness and all of the maps of the major ions. The thickness of clay-with-flints is negatively correlated with the autochthonous ions (HCO3- and Ca2+) and is positively correlated with the allochthonous ions (Cl-, Na+, SO42-, and NO3-). These results highlight that the thickness of clay-with-flints controls recharge. Two types of infiltration processes are proposed: (1) Thicker clay-with-flints allows storage in the perched groundwater, which allows evapotranspiration, resulting in high concentrations of allochthonous ions and a decrease in the dissolution potential of water and low concentrations of autochthonous ions. The infiltration of the perched groundwater is thus delayed and concentrated. (2) Thinner clay-with-flints causes the infiltration to be more diffuse, with low evapotranspiration and thus low concentrations of allochthonous ions in the Chalk groundwater; more, there is more dissolution and higher concentrations of autochthonous ions in the Chalk groundwater.

Electrical and geochemical properties of tufa deposits as related to mineral composition in the South Western Desert, Egypt

NASA Astrophysics Data System (ADS)

Gomaa, Mohamed M.; Abou El-Anwar, Esmat A.

2015-06-01

The geochemical, petrographical, and electrical properties of rocks are essential to the investigation of the properties of minerals. In this paper we will try to present a study of the A. C. electrical properties of carbonate rock samples and their relation to petrographical and geochemical properties. Samples were collected from four formations from the Bir Dungul area, in the South Western Desert, Egypt. The electrical properties of the samples were measured using a non-polarizing electrode, at room temperature (~28 °C), and at a relative atmospheric humidity of (~45%), in the frequency range from 42 Hz to 5 MHz. The changes in the electrical properties were argued to the change in mineral composition. Generally, the electrical properties of rocks are changed due to many factors e.g., grain size, mineral composition, grain shape and inter-granular relations between grains. The dielectric constant of samples decreases with frequency, and increases with conductor concentration. Also, the conductivity increases with an increase of continuous conductor paths between electrodes. The petrographical and geochemical studies reveal that the deposition of the tufa deposits occurred in shallow lakes accompanied by a high water table, an alkaline spring recharge and significant vegetation cover. Diagenetically, tufa deposits were subjected to early and late diagenesis. Petrography and geochemistry studies indicated that the area of tufa deposits was deposited under the control of bacterial activity. Geochemically, the Sr content indicates that the tufa deposits formed from dissolved bicarbonate under the control of microbes and bacterial activity.

Geochemical signals of progressive continental rupture in the Main Ethiopian Rift

NASA Astrophysics Data System (ADS)

Furman, T.; Bryce, J.; Yirgu, G.; Ayalew, D.; Cooper, L.

2003-04-01

Mafic volcanics of the Main Ethiopian Rift record the development of magmatic rift segments during continental extension. The Ethiopian Rift is one arm of a triple junction that formed above a Paleogene mantle plume, concurrent with eruption of flood basalts ca. 30 Ma across northern Ethiopian and Yemen. The geochemistry of Ethiopian Rift lavas thus provides insight into processes associated with the shift from mechanical (lithospheric) to magmatic (asthenospheric) segmentation in the transitional phase of continental rifting. Quaternary basalts from five volcanic centers representing three magmatic segments display along-axis geochemical variations that likely reflect the degree of rifting and magma supply, which increase abruptly with proximity to the highly-extended Afar region. To first order, the geochemical data indicate a decreasing degree of shallow-level fractionation and greater involvement of depleted or plume-like mantle source materials in basalts sampled closer to the Afar. These spatially controlled geochemical signatures observed in contemporaneous basalts are similar to temporal variations documented in southern Ethiopia, where Quaternary lavas indicate a greater degree of crustal extension than those erupted at the onset of plume activity. Primitive Ethiopian Rift basalts have geochemical signatures (e.g., Ce/Pb, La/Nb, Ba/Nb, Ba/Rb, U/Th) that overlap ocean island basalt compositions, suggesting involvement of sub-lithospheric source materials. The estimated depth of melting (65-75 km) is shallower than values obtained for young primitive mafic lavas from the Western Rift and southern Kenya as well as Oligocene Ethiopian flood basalts from the onset of plume-driven activity. Basalts from the Turkana region (N. Kenya) and Erta 'Ale (Danakil depression) reflect melting at shallower levels, corresponding to the greater degree of crustal extension in these provinces. Preliminary Sr and Nd isotopic data trend towards primitive earth values, consistent with values observed previously in central Ethiopia that are associated with moderately high 3He/4He values (<19 RA; Marty et al. 1996) and interpreted as reflecting involvement of a mantle plume. Taken together, these data support a model in which upwelling plume material sampled in central Ethiopia incorporates depleted mantle during ascent beneath the more highly extended portions of the African Rift.

Iron and Sulfur Species and Sulfur Isotopic Compositions of Authigenic Pyrite in Gas Hydrate-Bearing Sediments from Hydrate Ridge, Cascadia Margin (ODP Leg 204): A Proposal of Conceptual Models to Indicate the Non-Steady State Depositional and Diagenetic Processes

NASA Astrophysics Data System (ADS)

Liu, C.; Jiang, S. Y.; Su, X.

2017-12-01

Two accretionary sediment sequences from Sites 1245 and 1252 recovered during Ocean Drilling Program (ODP) Leg 204 at Hydrate Ridge, Cascadia Margin were investigated to explore the non-steady state depositional and diagenetic history. Five iron species and three sulfur species were chemically extracted, and their concentrations and the sulfur isotopic compositions of pyrite were determined. After the mineral recognitions of these species and detailed comparative analyses, the aerobic history of bottom seawater has been determined. The formation of pyrite is thought to be controlled by the limited production of hydrogen sulfide relative to the supply of reactive iron. Also, the intrusion of oxygen by bioturbation would oxidize the reduced sulfur species and further suppress pyritization. To explain the geochemical relationship between pyrite and siderite and the sulfur isotope characteristics of pyrite, we propose seven conceptual models based on the variations in depositional rate and methane flux, and the models succeed in explaining the geochemical results and are validated by the observed non-steady state events. These models may contribute to the reconstruction of the non-steady state processes in other research areas in the future.

Chemical trends in ocean islands explained by plume–slab interaction

NASA Astrophysics Data System (ADS)

Dannberg, Juliane; Gassmöller, Rene

2018-04-01

Earth's surface shows many features, of which the genesis can be understood only through their connection with processes in Earth's deep interior. Recent studies indicate that spatial geochemical patterns at oceanic islands correspond to structures in the lowermost mantle inferred from seismic tomographic models. This suggests that hot, buoyant upwellings can carry chemical heterogeneities from the deep lower mantle toward the surface, providing a window to the composition of the lowermost mantle. The exact nature of this link between surface and deep Earth remains debated and poorly understood. Using computational models, we show that subducted slabs interacting with dense thermochemical piles can trigger the ascent of hot plumes that inherit chemical gradients present in the lowermost mantle. We identify two key factors controlling this process: (i) If slabs induce strong lower-mantle flow toward the edges of these piles where plumes rise, the pile-facing side of the plume preferentially samples material originating from the pile, and bilaterally asymmetric chemical zoning develops. (ii) The composition of the melt produced reflects this bilateral zoning if the overlying plate moves roughly perpendicular to the chemical gradient in the plume conduit. Our results explain some of the observed geochemical trends of oceanic islands and provide insights into how these trends may originate.

Stochastic modelling of deep magmatic controls on porphyry copper deposit endowment.

PubMed

Chiaradia, Massimo; Caricchi, Luca

2017-03-15

Porphyry deposits, our main source of copper and of significant amounts of Mo, Re and Au, form at convergent margins in association with intermediate-felsic magmas. Although it is accepted that copper is transported and precipitated by fluids released by these magmas, the magmatic processes leading to the formation of economic deposits remain elusive. Here we perform Monte Carlo petrological and geochemical modelling to quantitatively link crustal magmatic processes and the geochemical signatures of magmas (i.e., Sr/Y) to the formation of porphyry Cu deposits of different sizes. Our analysis shows that economic deposits (particularly the largest ones) may only form in association with magma accumulated in the lower-middle crust (P > ~0.5 GPa) during ≥2-3 Ma, and subsequently transferred to and degassed in the upper crust over periods of up to ~2.0 Ma. Magma accumulation and evolution at shallower depths (<~0.4 GPa) dramatically reduces the potential of magmatic systems to produce economic deposits. Our modelling also predicts the association of the largest porphyry deposits with a specific Sr/Y interval (~100 ± 50) of the associated magmatic rocks, which is virtually identical to the range measured in giant porphyry copper deposits.

Stochastic modelling of deep magmatic controls on porphyry copper deposit endowment

PubMed Central

Chiaradia, Massimo; Caricchi, Luca

2017-01-01

Porphyry deposits, our main source of copper and of significant amounts of Mo, Re and Au, form at convergent margins in association with intermediate-felsic magmas. Although it is accepted that copper is transported and precipitated by fluids released by these magmas, the magmatic processes leading to the formation of economic deposits remain elusive. Here we perform Monte Carlo petrological and geochemical modelling to quantitatively link crustal magmatic processes and the geochemical signatures of magmas (i.e., Sr/Y) to the formation of porphyry Cu deposits of different sizes. Our analysis shows that economic deposits (particularly the largest ones) may only form in association with magma accumulated in the lower-middle crust (P > ~0.5 GPa) during ≥2–3 Ma, and subsequently transferred to and degassed in the upper crust over periods of up to ~2.0 Ma. Magma accumulation and evolution at shallower depths (<~0.4 GPa) dramatically reduces the potential of magmatic systems to produce economic deposits. Our modelling also predicts the association of the largest porphyry deposits with a specific Sr/Y interval (~100 ± 50) of the associated magmatic rocks, which is virtually identical to the range measured in giant porphyry copper deposits. PMID:28295045

Geochemical appraisal of fluoride-laden groundwater in Suri I and II blocks, Birbhum district, West Bengal

NASA Astrophysics Data System (ADS)

Das, Shreya; Nag, S. K.

2017-09-01

The present study has been carried out covering two blocks—Suri I and II in Birbhum district, West Bengal, India. The evaluation focuses on occurrence, distribution and geochemistry in 26 water samples collected from borewells spread across the entire study area homogeneously. Quantitative chemical analysis of groundwater samples collected from the present study area has shown that samples from two locations—Gangta and Dhalla contain fluoride greater than the permissible limit prescribed by WHO during both post-monsoon and pre-monsoon sampling sessions. Significant factor controlling geochemistry of groundwater has been identified to be rock-water interaction processes during both sampling sessions based on the results of Gibb's diagrams. Geochemical modeling studies have revealed that fluorite (CaF2) is, indeed, present as a significant fluoride-bearing mineral in the groundwaters of this study area. Calcite or CaCO3 is one of the most common minerals with which fluorite remains associated, and saturation index calculations have revealed that the calcite-fluorite geochemistry is the dominant factor controlling fluoride concentration in this area during both post- and pre-monsoon. High fluoride waters have also been found to be of `bicarbonate' type showing increase of sodium in water with decrease of calcium.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Inmachuk, Kugruk, Kiwalik, and Koyuk River drainages, Granite Mountain, and the northern Darby Mountains, Bendeleben, Candle, Kotzebue, and Solomon quadrangles, Alaska

USGS Publications Warehouse

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 653 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from an area covering portions of the Inmachuk, Kugruk, Kiwalik, and Koyuk river drainages, Granite Mountain, and the northern Darby Mountains, located in the Bendeleben, Candle, Kotzebue, and Solomon quadrangles of eastern Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Modelling radionuclide transport in fractured media with a dynamic update of K d values

DOE PAGES

Trinchero, Paolo; Painter, Scott L.; Ebrahimi, Hedieh; ...

2015-10-13

Radionuclide transport in fractured crystalline rocks is a process of interest in evaluating long term safety of potential disposal systems for radioactive wastes. Given their numerical efficiency and the absence of numerical dispersion, Lagrangian methods (e.g. particle tracking algorithms) are appealing approaches that are often used in safety assessment (SA) analyses. In these approaches, many complex geochemical retention processes are typically lumped into a single parameter: the distribution coefficient (Kd). Usually, the distribution coefficient is assumed to be constant over the time frame of interest. However, this assumption could be critical under long-term geochemical changes as it is demonstrated thatmore » the distribution coefficient depends on the background chemical conditions (e.g. pH, Eh, and major chemistry). In this study, we provide a computational framework that combines the efficiency of Lagrangian methods with a sound and explicit description of the geochemical changes of the site and their influence on the radionuclide retention properties.« less

Tectono-seismic characteristics of faults in the shallow portion of an accretionary prism

NASA Astrophysics Data System (ADS)

Hirono, Tetsuro; Ishikawa, Tsuyoshi

2018-01-01

To understand the tectono-seismic evolution of faults in the shallow part of a subduction-accretion system, we examined major faults in a fossil accretionary prism, the Emi Group (Hota Group), Boso Peninsula, Japan, by performing multiple structural, geochemical, and mineralogical analyses. Because the strata are relatively shallow (burial depth, 1-4 km), early stage deformation related to subduction, accretion, and uplifting processes is well preserved in three dominant fault zones. On the basis of both previous findings and our geochemical and mineralogical results, we inferred that early stage faulting in a near-trench setting under high pore fluid pressure and second stage faulting at relatively deep along subduction corresponded to aseismic deformations, as shown by velocity strengthening characteristics; and during late stage faulting, probably in association with accretion and uplift processes, a high-temperature fluid, revealed by a geochemical temperature proxy, triggered fault weakening by a thermal pressurization mechanism, and potentially led to the generation of a tsunami.

The curved 14C vs. δ13C relationship in dissolved inorganic carbon: A useful tool for groundwater age- and geochemical interpretations

USGS Publications Warehouse

Han, Liang-Feng; Plummer, Niel; Aggarwal, Pradeep

2014-01-01

Determination of the 14C content of dissolved inorganic carbon (DIC) is useful for dating of groundwater. However, in addition to radioactive decay, the 14C content in DIC (14CDIC) can be affected by many geochemical and physical processes and numerous models have been proposed to refine radiocarbon ages of DIC in groundwater systems. Changes in the δ13C content of DIC (δ13CDIC) often can be used to deduce the processes that affect the carbon isotopic composition of DIC and the 14C value during the chemical evolution of groundwater. This paper shows that a curved relationship of 14CDIC vs. δ13CDIC will be observed for groundwater systems if (1) the change in δ13C value in DIC is caused by a first-order or pseudo-first-order process, e.g. isotopic exchange between DIC and solid carbonate, (2) the reaction/process progresses with the ageing of the groundwater, i.e. with decay of 14C in DIC, and (3) the magnitude of the rate of change in δ13C of DIC is comparable with that of 14C decay. In this paper, we use a lumped parameter method to derive a model based on the curved relationship between 14CDICand δ13CDIC. The derived model, if used for isotopic exchange between DIC and solid carbonate, is identical to that derived by Gonfiantini and Zuppi (2003). The curved relationship of 14CDIC vs. δ13CDIC can be applied to interpret the age of the DIC in groundwater. Results of age calculations using the method discussed in this paper are compared with those obtained by using other methods that calculate the age of DIC based on adjusted initial radiocarbon values for individual samples. This paper shows that in addition to groundwater age interpretation, the lumped parameter method presented here also provides a useful tool for geochemical interpretations, e.g. estimation of apparent rates of geochemical reactions and revealing the complexity of the geochemical environment.

Hydrologic and geochemical data assimilation at the Hanford 300 Area

NASA Astrophysics Data System (ADS)

Chen, X.; Hammond, G. E.; Murray, C. J.; Zachara, J. M.

2012-12-01

In modeling the uranium migration within the Integrated Field Research Challenge (IFRC) site at the Hanford 300 Area, uncertainties arise from both hydrologic and geochemical sources. The hydrologic uncertainty includes the transient flow boundary conditions induced by dynamic variations in Columbia River stage and the underlying heterogeneous hydraulic conductivity field, while the geochemical uncertainty is a result of limited knowledge of the geochemical reaction processes and parameters, as well as heterogeneity in uranium source terms. In this work, multiple types of data, including the results from constant-injection tests, borehole flowmeter profiling, and conservative tracer tests, are sequentially assimilated across scales within a Bayesian framework to reduce the hydrologic uncertainty. The hydrologic data assimilation is then followed by geochemical data assimilation, where the goal is to infer the heterogeneous distribution of uranium sources using uranium breakthrough curves from a desorption test that took place at high spring water table. We demonstrate in our study that Ensemble-based data assimilation techniques (Ensemble Kalman filter and smoother) are efficient in integrating multiple types of data sequentially for uncertainty reduction. The computational demand is managed by using the multi-realization capability within the parallel PFLOTRAN simulator.

Concerning initial and secondary character of radionuclide distribution in elementary landscape geochemical systems

NASA Astrophysics Data System (ADS)

Korobova, Elena; Romanov, Sergey

2017-04-01

Specificity of radionuclide distribution in elementary landscape geochemical systems (ELGS) treated as local system of geochemically linked elementary terrestrial units (in toposequence: watershed-slope-closing depression), belongs to one of the less investigated but practically significant problems of current geochemistry. First measurements after the Chernobyl accident showed a considerable variation of Cs-137 distribution in all examined ELGS (Shcheglov et al, 2001; Romanov, 1989; Korobova, Korovaykov, 1990; Linnik, 2008). The results may be interpreted in frames of two alternative hypotheses: 1) irregularity of the initial contamination; 2) secondary redistribution of the initially regular level of fallout. But herewith only a disproof of the first hypothesis automatically justifies the second one. Factors responsible for initial irregularity of surface contamination included: 1) the presence of the so-called "hot" particles in the initial fallout; 2) interception of radionuclides by forest canopy; 3) irregular aerial particles deposition; 4) uneven initial precipitation. Basing on monitoring Cs-137 spatial distribution that has been performed since 2005, we demonstrate that the observed spatial irregularity in distribution of Cs-137 in ELGS reflects a purely secondary distribution of initial reserves of radionuclides in fallout matter due to its migration with water in local geochemical systems. This statement has some significant consequences. 1. Mechanism of migration of matter in ELGS is complicated and could not be reduced solely to a primitive moving from watershed to closing depression. 2. The control of migration of "labeled atoms" (Cs-137) permits to understand common mechanism of migration of water in all systems on the level of ELGS. 3. Understanding formation of the structure of contamination zones in ELGS permits to use mathematical model to solve the inverse problem of restoration of the initially equable level of their contamination. Performed study confirms that Cs-137 as a label helps to trace processes and patterns of chemical elements' migration on the level of ELGS that are numerously reproduced elsewhere in natural systems. The study is aimed at and believed to provide solution for a number of important problems related to generation and evolution of soil structure, spatial redistribution of fertilizers and pesticides, other important processes of matter redistribution on the level of local LGS. References Korobova E.M., Korovaykov P.A., 1990. Landscape and geochemical approach to drawing up a soil distribution profile for Chernobyl radionuclides in distant areas //Seminar "Comparative assessment of the environmental impact of radionuclides released during three major nuclear accidents: Kyshtum, Windscale, Chernobyl". V. 1. Luxembourg, 309-327. Linnik V.G., 2008. Landscape differentiation of technogenic radionuclides: geoinformation systems and models. Thesis. Moscow: Moscow State University, 42 p. Romanov S.L., 1989. Principles of formation of radionuclide dispersion and concentration fields // Abstracts of the All-Union Conference "Principles and methods of landscape geochemical studies of radionuclide migration". Moscow: Vernadsky Institute, p. 46. Shcheglov A.I., Tsvetnova O.B., KlyashtorinA.L., 2001. Biogeochemical migration of technogenic radionuclides in forest ecosystems. Moscow: Nauka, 235 p.

Geochemical modeling of trivalent chromium migration in saline-sodic soil during Lasagna process: impact on soil physicochemical properties.

PubMed

Lukman, Salihu; Bukhari, Alaadin; Al-Malack, Muhammad H; Mu'azu, Nuhu D; Essa, Mohammed H

2014-01-01

Trivalent Cr is one of the heavy metals that are difficult to be removed from soil using electrokinetic study because of its geochemical properties. High buffering capacity soil is expected to reduce the mobility of the trivalent Cr and subsequently reduce the remedial efficiency thereby complicating the remediation process. In this study, geochemical modeling and migration of trivalent Cr in saline-sodic soil (high buffering capacity and alkaline) during integrated electrokinetics-adsorption remediation, called the Lasagna process, were investigated. The remedial efficiency of trivalent Cr in addition to the impacts of the Lasagna process on the physicochemical properties of the soil was studied. Box-Behnken design was used to study the interaction effects of voltage gradient, initial contaminant concentration, and polarity reversal rate on the soil pH, electroosmotic volume, soil electrical conductivity, current, and remedial efficiency of trivalent Cr in saline-sodic soil that was artificially spiked with Cr, Cu, Cd, Pb, Hg, phenol, and kerosene. Overall desirability of 0.715 was attained at the following optimal conditions: voltage gradient 0.36 V/cm; polarity reversal rate 17.63 hr; soil pH 10.0. Under these conditions, the expected trivalent Cr remedial efficiency is 64.75%.

Geochemical Modeling of Trivalent Chromium Migration in Saline-Sodic Soil during Lasagna Process: Impact on Soil Physicochemical Properties

PubMed Central

Bukhari, Alaadin; Al-Malack, Muhammad H.; Mu'azu, Nuhu D.; Essa, Mohammed H.

2014-01-01

Trivalent Cr is one of the heavy metals that are difficult to be removed from soil using electrokinetic study because of its geochemical properties. High buffering capacity soil is expected to reduce the mobility of the trivalent Cr and subsequently reduce the remedial efficiency thereby complicating the remediation process. In this study, geochemical modeling and migration of trivalent Cr in saline-sodic soil (high buffering capacity and alkaline) during integrated electrokinetics-adsorption remediation, called the Lasagna process, were investigated. The remedial efficiency of trivalent Cr in addition to the impacts of the Lasagna process on the physicochemical properties of the soil was studied. Box-Behnken design was used to study the interaction effects of voltage gradient, initial contaminant concentration, and polarity reversal rate on the soil pH, electroosmotic volume, soil electrical conductivity, current, and remedial efficiency of trivalent Cr in saline-sodic soil that was artificially spiked with Cr, Cu, Cd, Pb, Hg, phenol, and kerosene. Overall desirability of 0.715 was attained at the following optimal conditions: voltage gradient 0.36 V/cm; polarity reversal rate 17.63 hr; soil pH 10.0. Under these conditions, the expected trivalent Cr remedial efficiency is 64.75 %. PMID:25152905

Compilation of field methods used in geochemical prospecting by the U.S. Geological Survey

USGS Publications Warehouse

Lakin, Hubert William; Ward, Frederick Norville; Almond, Hy

1952-01-01

The field methods described in this report are those currently used in geochemical prospecting by the U. S. Geological Survey. Some have been published, others are being processed for publication, while others are still being investigated. The purpose in compiling these methods is to make them readily available in convenient form. The methods have not been thoroughly tested and none is wholly satisfactory. Research is being continued.

Groundwater quality assessment in semi-arid regions using integrated approaches: the case of Grombalia aquifer (NE Tunisia).

PubMed

Kammoun, Siwar; Trabelsi, Rim; Re, Viviana; Zouari, Kamel; Henchiri, Jihed

2018-01-19

As many arid and semi-arid regions in the Mediterranean Basin, the Grombalia coastal aquifer (NE Tunisia) is affected by severe groundwater exploitation and contamination. Therefore, quality assessments are becoming increasingly important as the long-term protection of water resources is at stake. Multidisciplinary investigations, like the one presented in this paper, are particularly effective in identifying the different origins of mineralization within an aquifer and investigating the impact of anthropogenic activities on groundwater quality. An integrated assessment, focused on the combined use of geostatistical, geochemical and isotopic (δ 18 O, δ 2 H and 3 H) tools, was performed in the Grombalia aquifer between February and March 2014. The overall goal was to study the main processes controlling aquifer salinization, with special focus to nitrate contamination. Results indicate a persisting deterioration of water quality over the whole basin except the south-eastern zone juxtaposing the recharge area of the aquifer. Nitrate contents exceed the drinking water standard (50 mg/l) in 70% of groundwater samples, mainly due to the excessive use of fertilizers and urban activities. Stable isotope measurements showed the contribution of modern rainwater to aquifer recharge and proved the presence of evaporation contributing to the salinity increase. Tritium values of groundwater samples suggested two hypotheses: the existence of mixture between old and recent water or/and the existence of two recharge periods of the aquifer, pre- and post-nuclear weapons test. Principal component analysis confirmed the geochemical interpretation, highlighting that water-rock interaction evaporation effect and intensive anthropogenic activities constitute the main processes controlling the regional groundwater mineralization.

Coupled S and Sr isotope evidences for elevated arsenic concentrations in groundwater from the world's largest antimony mine, Central China

NASA Astrophysics Data System (ADS)

Wen, Bing; Zhou, Aiguo; Zhou, Jianwei; Liu, Cunfu; Huang, Yuliu; Li, Ligang

2018-02-01

The Xikuangshan(XKS) mine, the world's largest antimony mine, was chosen for a detailed arsenic hydrogeochemical study because of the elevated arsenic in bedrock aquifers used by local residents. Hydrochemical data, δ34S values of dissolved SO42- and 87Sr/86Sr ratios have been analyzed to identify the predominant geochemical processes that control the arsenic mobilization within the aquifers. Groundwater samples can be divided into three major types: low arsenic groundwater (0-50 μg/L), high arsenic groundwater (50-1000 μg/L) and anomalous high arsenic groundwater (>1000 μg/L). Arsenic occurs under oxidizing conditions at the XKS Sb mine as the HAsO42- anion. The Ca/Na ratio correlates significantly with HCO3-/Na and Sr/Na ratios, indicating that carbonate dissolution and silicate weathering are the dominant processes controlling groundwater hydrochemistry. The δ34S values of the groundwater indicate that dissolved SO42- in groundwater is mainly sourced from the oxidation of sulfide minerals, and elevated As concentrations in groundwater are influenced by the mixing of mine water and surface water. Furthermore, the δ34S values are not correlated with dissolved As concentrations and Fe concentrations, suggesting that the reduction dissolution of Fe(III) hydroxides is not the dominant process controlling As mobilization. The 87Sr/86Sr ratios imply that elevated As concentrations in groundwater are primarily derived from the interaction with the stibnite and silicified limestone. More specifically, the excess-Na ion, the feature of Ca/Na ratio, and the spatial association of elevated As concentrations in groundwater collectively suggest that high and anomalous high arsenic groundwater are associated with smelting slags and, in particular, the arsenic alkali residue. In general, the hydrochemistry analysis, especially the S and Sr isotope evidences elucidate that elevated As concentrations and As mobilization are influenced by several geochemical processes, including: (1) bedrock weathering; (2) oxidation of arsenopyrite and the dominant sulfides in the ores; (3) mixing of mine drainage and surface water; (4) leaching of the arsenic alkali residue; and (5) sorption-desorption from Fe/Mn oxides/hydroxides.

Chemical elements in the environment: multi-element geochemical datasets from continental to national scale surveys on four continents

USGS Publications Warehouse

Caritat, Patrice de; Reimann, Clemens; Smith, David; Wang, Xueqiu

2017-01-01

During the last 10-20 years, Geological Surveys around the world have undertaken a major effort towards delivering fully harmonized and tightly quality-controlled low-density multi-element soil geochemical maps and datasets of vast regions including up to whole continents. Concentrations of between 45 and 60 elements commonly have been determined in a variety of different regolith types (e.g., sediment, soil). The multi-element datasets are published as complete geochemical atlases and made available to the general public. Several other geochemical datasets covering smaller areas but generally at a higher spatial density are also available. These datasets may, however, not be found by superficial internet-based searches because the elements are not mentioned individually either in the title or in the keyword lists of the original references. This publication attempts to increase the visibility and discoverability of these fundamental background datasets covering large areas up to whole continents.

Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan

This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

Investigating Processes of Materials Formation via Liquid Phase and Cryogenic TEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Yoreo, James J.; Sommerdijk, Nico

2016-06-14

The formation of materials in solutions is a widespread phenomenon in synthetic, biological and geochemical systems, occurring through dynamic processes of nucleation, self-assembly, crystal growth, and coarsening. The recent advent of liquid phase TEM and advances in cryogenic TEM are transforming our understanding of these phenomena by providing new insights into the underlying physical and chemical mechanisms. The techniques have been applied to metallic and semiconductor nanoparticles, geochemical and biological minerals, electrochemical systems, macromolecular complexes, and selfassembling systems, both organic and inorganic. New instrumentation and methodologies currently on the horizon promise new opportunities for advancing the science of materials synthesis.

Phylogenetic and Functional Analysis of Metagenome Sequence from High-Temperature Archaeal Habitats Demonstrate Linkages between Metabolic Potential and Geochemistry

PubMed Central

Inskeep, William P.; Jay, Zackary J.; Herrgard, Markus J.; Kozubal, Mark A.; Rusch, Douglas B.; Tringe, Susannah G.; Macur, Richard E.; Jennings, Ryan deM.; Boyd, Eric S.; Spear, John R.; Roberto, Francisco F.

2013-01-01

Geothermal habitats in Yellowstone National Park (YNP) provide an unparalleled opportunity to understand the environmental factors that control the distribution of archaea in thermal habitats. Here we describe, analyze, and synthesize metagenomic and geochemical data collected from seven high-temperature sites that contain microbial communities dominated by archaea relative to bacteria. The specific objectives of the study were to use metagenome sequencing to determine the structure and functional capacity of thermophilic archaeal-dominated microbial communities across a pH range from 2.5 to 6.4 and to discuss specific examples where the metabolic potential correlated with measured environmental parameters and geochemical processes occurring in situ. Random shotgun metagenome sequence (∼40–45 Mb Sanger sequencing per site) was obtained from environmental DNA extracted from high-temperature sediments and/or microbial mats and subjected to numerous phylogenetic and functional analyses. Analysis of individual sequences (e.g., MEGAN and G + C content) and assemblies from each habitat type revealed the presence of dominant archaeal populations in all environments, 10 of whose genomes were largely reconstructed from the sequence data. Analysis of protein family occurrence, particularly of those involved in energy conservation, electron transport, and autotrophic metabolism, revealed significant differences in metabolic strategies across sites consistent with differences in major geochemical attributes (e.g., sulfide, oxygen, pH). These observations provide an ecological basis for understanding the distribution of indigenous archaeal lineages across high-temperature systems of YNP. PMID:23720654

Statistical tables and charts showing geochemical variation in the Mesoproterozoic Big Creek, Apple Creek, and Gunsight formations, Lemhi group, Salmon River Mountains and Lemhi Range, central Idaho

USGS Publications Warehouse

Lindsey, David A.; Tysdal, Russell G.; Taggart, Joseph E.

2002-01-01

The principal purpose of this report is to provide a reference archive for results of a statistical analysis of geochemical data for metasedimentary rocks of Mesoproterozoic age of the Salmon River Mountains and Lemhi Range, central Idaho. Descriptions of geochemical data sets, statistical methods, rationale for interpretations, and references to the literature are provided. Three methods of analysis are used: R-mode factor analysis of major oxide and trace element data for identifying petrochemical processes, analysis of variance for effects of rock type and stratigraphic position on chemical composition, and major-oxide ratio plots for comparison with the chemical composition of common clastic sedimentary rocks.

Geochemical evidence for the formation of the Moon by impact induced fission of the proto-Earth

NASA Technical Reports Server (NTRS)

Waenke, H.; Dreibus, G.

1984-01-01

Geochemical evidence is discussed which advocates the theory that the Moon was formed by impact induced fission of the Earth. The Earth's mantle exhibits a number of geochemical peculiarities which make our planet a unique object in the solar system. Terrestrial basalts are compared with those from the Eucrite parent body and the Shergotty parent body. Also the Moon's composition is very close to the Earth's in all details except the lower FeO content which is explained. Evidence is discussed for the plausible physical process of formation of the Moon by impact induced fission. Also the theory that impact induced fission occurred at the moment at which accretion of the Earth was not totally complete is briefly discussed.

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas, Kansas, Missouri and Oklahoma, USA

USGS Publications Warehouse

Adamski, J.C.

2000-01-01

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate-rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field-measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water-rock interactions. Water from wells flow through small fractures, which restrict flow and increase water-rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright (C) 2000 John Wiley and Sons, Ltd.Geochemical data indicate that the Springfield Plateau carbonate aquifer has two distinct hydrochemical zones. With each hydrochemical zone, water from springs is geochemically and isotopically different from the water from wells. Spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Factors affecting the differences in the geochemical composition of groundwater between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zones.

Integrating Geochemical and Morphologic Evolution of Soil-Covered Hillslopes in a Transient Tributary Basin

NASA Astrophysics Data System (ADS)

Weinman, B. A.; Yoo, K.; Mudd, S. M.; Hurst, M. D.; Maher, K.; Mayer, K.; Andersen, C.

2010-12-01

When hillslopes respond to incision triggered by tectonic uplift, there is a competition between chemical and physical processes in shaping the landscape. We are studying a tributary basin of the Middle Folk Feather River (FR) in Sierra Nevada CA, where an incision signal is still propagating throughout the basin. Soils were sampled along 3 hillslope transects: POMD (30% slope at 766m), FTA (56% slope at 673m), and BRC (63% slope at 684m). Given their different elevations, slopes, and proximities to the rejuvenating channel, these hillslopes presumably reflect a wide range of denudation. To capture how the basin’s geophysical and geochemical signals propagate upslope, transects were chosen so that POMD is above the knickpoint, FTA is proximal to the knickpoint, and BRC captures erosion below the knickpoint transition. Surprisingly, the hillslopes--despite their varying rates of denudation--show a constant soil thicknesses along all transects (50cm). Despite this similarity, geochemical differences between the soils do exist, indicating a connection between soil geochemistry and the turnover time of the soils (i.e., soil thickness divided by physical erosion rate). For instance, POMD (with a residence time ~30kyr) visually and chemically had the highest degree of weathering based on soil color (10YR 5/4) and the abundance of pedogenic iron oxides (0.3-0.7%). FTA and BRC, on the other hand, had residence times ~2 & 4kyr, and were less red and less Fe-oxide enriched than the POMD soils (10YR 7/4, ND-0.5%). Geochemical differences were further shown by Zr enrichments in the fine fractions of POMD and FTA soils. In general, POMD soils show 20% more mass-loss of major elements, such as Fe, Al, Na, and K in the upper horizons. However, it’s important to note that despite this difference, the geochemical profiles of FTA and POMD show strikingly similar levels of element depletion. While we are working on understanding if this similarity is due to weathering rate differences or chemical weathering occurring below the soil-saprolite boundary, the transect chemical differences, combined with grainsize results, indicate that the breakdown of coarse fractions in the regolith (>2mm) can be responsible for much of the weathering in the FR basin. This is important because our findings indicate that despite order of magnitude differences in denudation rates and soil residence times, soils with relatively fast residence times can display remarkable similarities to those exhibited by long-residence time soils. These findings are consistent with the view that soils with shorter residence times do occur on steeper hillslopes, however they contrast original expectations that soils would thin and be more physically dominated along hillslopes with steeper gradients. We think, therefore, that another control beside the dynamic chemical and physical processes we report here--namely tree throw--is a key factor in the soil formation processes in both the older and newly incising areas of FR.

Biologically mediated isotope fractionations - Biochemistry, geochemical significance and preservation in the earth's oldest sediments

NASA Technical Reports Server (NTRS)

Schidlowski, M.

1983-01-01

Preferential metabolization of isotopically light carbon and sulfur has resulted in a fractionation of the stable isotopes of these elements on a global scale, with the light species (C-12, S-32) markedly concentrated in biogenic materials. Since the biological effects are basically retained when carbon and sulfur are incorporated in sediments, the respective fractionations are propagated into the rock section of the geochemical cycle, this having consequently caused a characteristic bipartition of both elements between 'light' and 'heavy' crustal reservoirs. Preservation of the biological isotope effects in sedimentary rocks makes it possible to trace the underlying biochemical processes back over most of the geological record. According to the available evidence, biological (autotrophic) carbon fixation arose prior to 3.5(if not 3.8) billion years ago, while the emergence of dissimilatory sulfate reduction antedates the appearance of the oldest presumably bacteriogenic sulfur isotope patterns in rocks between 2.7 and 2.8 billion years old. Hence, biological control of the terrestrial carbon and sulfur cycles has been established very early in the earth's history.

Unraveling Vital Effects: Photosynthesis of Symbiotic Algae in Foraminifera Hosts

NASA Astrophysics Data System (ADS)

Fish, C.; Phelps, S. R.; Goes, J. I.; Hoenisch, B.

2015-12-01

B/Ca and boron isotope proxies recorded in the calcium carbonate shells of planktic foraminifera are sensitive to seawater acidity. We seek to understand how the biology of the organism affects the geochemical signals, as planktic foraminifera shells differ in their chemical composition from inorganic calcite and also between foraminifer species. These differences are most likely related to physiological processes like respiration, calcification, and photosynthesis in symbiont-bearing foraminifera. The modifications of geochemical signals by these biological parameters are termed vital effects. Our study is based on the hypothesis that the B/Ca and δ11B offsets observed in planktic foraminifer shells are primarily due to the photosynthetic activity of their symbionts, which may elevate the microenvironmental pH to different degrees in different foraminifer species. Using fast repetition rate fluorometry, chlorophyll α analyses and symbiont counts, we investigated the symbiont-photosynthetic activity associated with three foraminifera species - Globigerinoides ruber, G. sacculifer, and Orbulina universa. Boron proxy systematics in these species suggest that photosynthetic activity should be greater in G. ruber compared to G. sacculifer and O. universa, but this is not confirmed by our study. While symbiont photosynthesis undoubtedly explains microenvironmental pH-elevation and boron proxy systematics in symbiont-bearing compared to symbiont-barren foraminifer species, additional processes must be responsible for the boron geochemical offsets between symbiont-bearing species. Respiration of the symbiont-host association and the calcification process are most likely candidates that require further analysis. Our study highlights the potential danger of misinterpreting geochemical signals in biological organisms when the biology of the organism in question is not entirely understood.

Linking geochemical processes in mud volcanoes with arsenic mobilization driven by organic matter.

PubMed

Liu, Chia-Chuan; Kar, Sandeep; Jean, Jiin-Shuh; Wang, Chung-Ho; Lee, Yao-Chang; Sracek, Ondra; Li, Zhaohui; Bundschuh, Jochen; Yang, Huai-Jen; Chen, Chien-Yen

2013-11-15

The present study deals with geochemical characterization of mud fluids and sediments collected from Kunshuiping (KSP), Liyushan (LYS), Wushanting (WST), Sinyangnyuhu (SYNH), Hsiaokunshui (HKS) and Yenshuikeng (YSK) mud volcanoes in southwestern Taiwan. Chemical constituents (cations, anions, trace elements, organic carbon, humic acid, and stable isotopes) in both fluids and mud were analyzed to investigate the geochemical processes and spatial variability among the mud volcanoes under consideration. Analytical results suggested that the anoxic mud volcanic fluids are highly saline, implying connate water as the probable source. The isotopic signature indicated that δ(18)O-rich fluids may be associated with silicate and carbonate mineral released through water-rock interaction, along with dehydration of clay minerals. Considerable amounts of arsenic in mud irrespective of fluid composition suggested possible release through biogeochemical processes in the subsurface environment. Sequential extraction of As from the mud indicated that As was mostly present in organic and sulphidic phases, and adsorbed on amorphous Mn oxyhydroxides. Volcanic mud and fluids are rich in organic matter (in terms of organic carbon), and the presence of humic acid in mud has implications for the binding of arsenic. Functional groups of humic acid also showed variable sources of organic matter among the mud volcanoes being examined. Because arsenate concentration in the mud fluids was found to be independent from geochemical factors, it was considered that organic matter may induce arsenic mobilization through an adsorption/desorption mechanism with humic substances under reducing conditions. Organic matter therefore plays a significant role in the mobility of arsenic in mud volcanoes. Copyright © 2012 Elsevier B.V. All rights reserved.

Magma transport and metasomatism in the mantle: a critical review of current geochemical models

USGS Publications Warehouse

Nielson, J.E.; Wilshire, H.G.

1993-01-01

Conflicting geochemical models of metasomatic interactions between mantle peridotite and melt all assume that mantle reactions reflect chromatographic processes. Examination of field, petrological, and compositional data suggests that the hypothesis of chromatographic fractionation based on the supposition of large-scale percolative processes needs review and revision. Well-constrained rock and mineral data from xenoliths indicate that many elements that behave incompatibly in equilibrium crystallization processes are absorbed immediately when melts emerge from conduits into depleted peridotite. After reacting to equilibrium with the peridotite, melt that percolates away from the conduit is largely depleted of incompatible elements. Continued addition of melts extends the zone of equilibrium farther from the conduit. Such a process resembles ion-exchange chromatography for H2O purification, rather than the model of chromatographic species separation. -from Authors

Biogeographic congruency among bacterial communities from terrestrial sulfidic springs

PubMed Central

Headd, Brendan; Engel, Annette S.

2014-01-01

Terrestrial sulfidic springs support diverse microbial communities by serving as stable conduits for geochemically diverse and nutrient-rich subsurface waters. Microorganisms that colonize terrestrial springs likely originate from groundwater, but may also be sourced from the surface. As such, the biogeographic distribution of microbial communities inhabiting sulfidic springs should be controlled by a combination of spring geochemistry and surface and subsurface transport mechanisms, and not necessarily geographic proximity to other springs. We examined the bacterial diversity of seven springs to test the hypothesis that occurrence of taxonomically similar microbes, important to the sulfur cycle, at each spring is controlled by geochemistry. Complementary Sanger sequencing and 454 pyrosequencing of 16S rRNA genes retrieved five proteobacterial classes, and Bacteroidetes, Chlorobi, Chloroflexi, and Firmicutes phyla from all springs, which suggested the potential for a core sulfidic spring microbiome. Among the putative sulfide-oxidizing groups (Epsilonproteobacteria and Gammaproteobacteria), up to 83% of the sequences from geochemically similar springs clustered together. Abundant populations of Hydrogenimonas-like or Sulfurovum-like spp. (Epsilonproteobacteria) occurred with abundant Thiothrix and Thiofaba spp. (Gammaproteobacteria), but Arcobacter-like and Sulfurimonas spp. (Epsilonproteobacteria) occurred with less abundant gammaproteobacterial populations. These distribution patterns confirmed that geochemistry rather than biogeography regulates bacterial dominance at each spring. Potential biogeographic controls were related to paleogeologic sedimentation patterns that could control long-term microbial transport mechanisms that link surface and subsurface environments. Knowing the composition of a core sulfidic spring microbial community could provide a way to monitor diversity changes if a system is threatened by anthropogenic processes or climate change. PMID:25250021

Springwater geochemistry at Honey Creek State Natural Area, central Texas: Implications for surface water and groundwater interaction in a karst aquifer

NASA Astrophysics Data System (ADS)

Musgrove, M.; Stern, L. A.; Banner, J. L.

2010-06-01

SummaryA two and a half year study of two adjacent watersheds at the Honey Creek State Natural Area (HCSNA) in central Texas was undertaken to evaluate spatial and temporal variations in springwater geochemistry, geochemical evolution processes, and potential effects of brush control on karst watershed hydrology. The watersheds are geologically and geomorphologically similar, and each has springs discharging into Honey Creek, a tributary to the Guadalupe River. Springwater geochemistry is considered in a regional context of aquifer components including soil water, cave dripwater, springwater, and phreatic groundwater. Isotopic and trace element variability allows us to identify both vadose and phreatic groundwater contributions to surface water in Honey Creek. Spatial and temporal geochemical data for six springs reveal systematic differences between the two watersheds. Springwater Sr isotope values lie between values for the limestone bedrock and soils at HCSNA, reflecting a balance between these two primary sources of Sr. Sr isotope values for springs within each watershed are consistent with differences between soil compositions. At some of the springs, consistent temporal variability in springwater geochemistry (Sr isotopes, Mg/Ca, and Sr/Ca values) appears to reflect changes in climatic and hydrologic parameters (rainfall/recharge) that affect watershed processes. Springwater geochemistry was unaffected by brush removal at the scale of the HCSNA study. Results of this study build on previous regional studies to provide insight into watershed hydrology and regional hydrologic processes, including connections between surface water, vadose groundwater, and phreatic groundwater.

Long Term Geoelectrical Monitoring of Deep-water Horizon Oil Spill in the Gulf Coast

NASA Astrophysics Data System (ADS)

Heenan, J. W.; Ntarlagiannis, D.; Slater, L. D.; Atekwana, E. A.; Ross, C.; Nolan, J. T.; Atekwana, E. A.

2011-12-01

In the aftermath of the catastrophic Deep-water Horizon (DWH) spill in the Gulf Coast, opportunities exist to study the evolution of fresh crude oil contamination in beach sediments and marshes. Grand Terre 1 Island, off the coast of Grand Isle in southern Louisiana, is an uninhabited barrier island, heavily impacted by the DWH spill, and ideal for undisturbed long term monitoring of crude oil degradation processes. A 10 channel Syscal-Pro resistivity / IP instrument (IRIS Instruments, France) is the heart of the fully autonomous geoelectrical monitoring system; the system, which is housed in a weatherproof container, relies solely on solar power, is controlled by an energy efficient PC and can be accessed remotely via web tools. The monitoring scheme involves collecting bi-daily resistivity measurements from surface and shallow boreholes, ranging from January 2011 to the present; environmental parameters, such as T, are continuously recorded at several depths. During regular field trips we perform larger scale geophysical surveys, and geochemical measurements (pH, DO, T, fluid C) to support the continuous geophysical monitoring. The contaminated layer on site is a visually distinctive layer of crude oil, isolated by cleaner sands above and below which is identified by a clear and obvious resistive anomaly in preliminary surveys. Early results show a decrease in average of the resistance values of each dataset over time. Further processing of the data yields a linearly shaped resistive anomaly, which coincides with the location of the oil layer. The changes in subsurface resistivity appear to be focused within this anomaly. Time filtering of the data by the time that they were collected, morning or evening, reveals a diurnal variation. While both time frames follow the same overall trend, the measurements in the morning are slightly more resistive than those in the evening. This indicates that there are environmental factors, such as temperature, that need to be accounted for when analyzing the data for evidence of biological processes. These preliminary findings indicate changes in the subsurface properties of the contaminated area and suggest that geoelectrical methods are sensitive to contamination evolution processes. Such geophysical data, constrained by geochemical and microbiological information, have the potential to be used as a long term monitoring tool for biological and geochemical processes in the subsurface.

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada

USGS Publications Warehouse

Seiler, R.L.; Stollenwerk, K.G.; Garbarino, J.R.

2005-01-01

An investigation of a childhood leukemia cluster by US Centers for Disease Control and Prevention revealed that residents of the Carson Desert, Nevada, are exposed to high levels of W and this prompted an investigation of W in aquifers used as drinking water sources. Tungsten concentrations in 100 ground water samples from all aquifers used as drinking water sources in the area ranged from 0.27 to 742 ??g/l. Ground water in which W concentrations exceed 50 ??g/l principally occurs SE of Fallon in a geothermal area. The principal sources of W in ground water are natural and include erosion of W-bearing mineral deposits in the Carson River watershed upstream of Fallon, and, possibly, upwelling geothermal waters. Ground water in the Fallon area is strongly reducing and reductive dissolution of Fe and Mn oxyhydroxides may be releasing W; however, direct evidence that the metal oxides contain W is not available. Although W and Cl concentrations in the Carson River, a lake, and water from many wells, appear to be controlled by evaporative concentration, evaporation alone cannot explain the elevated W concentrations found in water from some of the wells. Concentrations of W exceeding 50 ??g/l are exclusively associated with Na-HCO3 and Na-Cl water types and pH > 8.0; in these waters, geochemical modeling indicates that W exhibits <10% adsorption. Tungsten concentrations are strongly and positively correlated with As, B, F, and P, indicating either common sources or common processes controlling their concentrations. Geochemical modeling indicates W concentrations are consistent with pH-controlled adsorption of W. The geochemical model PHREEQC was used to calculate IAP values, which were compared with published Ksp values for primary W minerals. FeWO4, MnWO4, Na2WO4, and MgWO4 were undersaturated and CaWO4 and SrWO 4 were approaching saturation. These conclusions are tentative because of uncertainty in the thermodynamic data. The similar behavior of As and W observed in this study suggests ground water in areas where elevated As concentrations are present also may contain elevated W concentrations, particularly if there is a mineral or geothermal source of W and reducing conditions develop in the aquifer.

Garnets within geode-like serpentinite veins: Implications for element transport, hydrogen production and life-supporting environment formation

NASA Astrophysics Data System (ADS)

Plümper, Oliver; Beinlich, Andreas; Bach, Wolfgang; Janots, Emilie; Austrheim, Håkon

2014-09-01

Geochemical micro-environments within serpentinizing systems can abiotically synthesize hydrocarbons and provide the ingredients required to support life. Observations of organic matter in microgeode-like hydrogarnets found in Mid-Atlantic Ridge serpentinites suggest these garnets possibly represent unique nests for the colonization of microbial ecosystems within the oceanic lithosphere. However, little is known about the mineralogical and geochemical processes that allow such unique environments to form. Here we present work on outcrop-scale vein networks from an ultramafic massif in Norway that contain massive amounts of spherulitic garnets (andradite), which help to constrain such processes. Vein andradite spherulites are associated with polyhedral serpentine, brucite, Ni-Fe alloy (awaruite), and magnetite indicative of low temperature (<200 °C) alteration under low fO2 and low aSiO2,aq geochemical conditions. Together with the outcrop- and micro-scale analysis geochemical reaction path modeling shows that there was limited mass transport and fluid flow over a large scale. Once opened the veins remained isolated (closed system), forming non-equilibrium microenvironments that allowed, upon a threshold supersaturation, the rapid crystallization (seconds to weeks) of spherulitic andradite. The presence of polyhedral serpentine spheres indicates that veins were initially filled with a gel-like protoserpentine phase. In addition, massive Fe oxidation associated with andradite formation could have generated as much as 600 mmol H2,aq per 100 cm3 vein. Although no carboneous matter was detected, the vein networks fulfill the reported geochemical criteria required to generate abiogenic hydrocarbons and support microbial communities. Thus, systems similar to those investigated here are of prime interest when searching for life-supporting environments within the deep subsurface.

Nanogeochemistry: Size-dependent mineral-fluid interface chemistry

NASA Astrophysics Data System (ADS)

Wang, Y.

2012-12-01

Nanostructures and nanometer mineral phases, both widely present in geologic materials, can potentially affect many geochemical processes. It is known that at nanometer scales a material tends to exhibit chemical properties distinct from the corresponding bulk phase. Understanding of this size-dependent property change will help us to bridge the existing knowledge gap between the molecular level understanding and the macro-scale laboratory/field observations of a geochemical process. In this presentation, I will review of the recent progresses in nanoscience and provide a perspective on how these progresses can potentially impact geochemical studies. My presentation will be focused the following areas: (1) the characterization of nanostructures in natural systems, (2) the study of fluids and chemical species in nanoconfinement, (3) the effects of nanopores on geochemical reaction and mass transfers, and (4) the use nanostructured materials for environmental management. I will demonstrate that the nanopore confinement can significantly modify geochemical reactions in porous geologic media. As the pore size is reduced to a few nanometers, the difference between surface acidity constants of a mineral (pK2 - pK1) decreases, giving rise to a higher surface charge density on a nanopore surface than that on an unconfined mineral-water interface. The change in surface acidity constants results in a shift of ion sorption edges and enhances ion sorption on nanopore surfaces. This effect causes preferential enrichment of trace elements in nanopores. I will then discuss the implications of this emergent nanometer-scale property to radionuclide transport and carbon dioxide storage in geologic media. This work was performed at Sandia National Laboratories, which is a multiprogram laboratory operated by Sandia Corporation, a Lockheed-Martin Company, for the DOE under contract DE-AC04-94AL8500.

A review of single-sample-based models and other approaches for radiocarbon dating of dissolved inorganic carbon in groundwater

USGS Publications Warehouse

Han, L. F; Plummer, Niel

2016-01-01

Numerous methods have been proposed to estimate the pre-nuclear-detonation 14C content of dissolved inorganic carbon (DIC) recharged to groundwater that has been corrected/adjusted for geochemical processes in the absence of radioactive decay (14C0) - a quantity that is essential for estimation of radiocarbon age of DIC in groundwater. The models/approaches most commonly used are grouped as follows: (1) single-sample-based models, (2) a statistical approach based on the observed (curved) relationship between 14C and δ13C data for the aquifer, and (3) the geochemical mass-balance approach that constructs adjustment models accounting for all the geochemical reactions known to occur along a groundwater flow path. This review discusses first the geochemical processes behind each of the single-sample-based models, followed by discussions of the statistical approach and the geochemical mass-balance approach. Finally, the applications, advantages and limitations of the three groups of models/approaches are discussed.The single-sample-based models constitute the prevailing use of 14C data in hydrogeology and hydrological studies. This is in part because the models are applied to an individual water sample to estimate the 14C age, therefore the measurement data are easily available. These models have been shown to provide realistic radiocarbon ages in many studies. However, they usually are limited to simple carbonate aquifers and selection of model may have significant effects on 14C0 often resulting in a wide range of estimates of 14C ages.Of the single-sample-based models, four are recommended for the estimation of 14C0 of DIC in groundwater: Pearson's model, (Ingerson and Pearson, 1964; Pearson and White, 1967), Han & Plummer's model (Han and Plummer, 2013), the IAEA model (Gonfiantini, 1972; Salem et al., 1980), and Oeschger's model (Geyh, 2000). These four models include all processes considered in single-sample-based models, and can be used in different ranges of 13C values.In contrast to the single-sample-based models, the extended Gonfiantini & Zuppi model (Gonfiantini and Zuppi, 2003; Han et al., 2014) is a statistical approach. This approach can be used to estimate 14C ages when a curved relationship between the 14C and 13C values of the DIC data is observed. In addition to estimation of groundwater ages, the relationship between 14C and δ13C data can be used to interpret hydrogeological characteristics of the aquifer, e.g. estimating apparent rates of geochemical reactions and revealing the complexity of the geochemical environment, and identify samples that are not affected by the same set of reactions/processes as the rest of the dataset. The investigated water samples may have a wide range of ages, and for waters with very low values of 14C, the model based on statistics may give more reliable age estimates than those obtained from single-sample-based models. In the extended Gonfiantini & Zuppi model, a representative system-wide value of the initial 14C content is derived from the 14C and δ13C data of DIC and can differ from that used in single-sample-based models. Therefore, the extended Gonfiantini & Zuppi model usually avoids the effect of modern water components which might retain ‘bomb’ pulse signatures.The geochemical mass-balance approach constructs an adjustment model that accounts for all the geochemical reactions known to occur along an aquifer flow path (Plummer et al., 1983; Wigley et al., 1978; Plummer et al., 1994; Plummer and Glynn, 2013), and includes, in addition to DIC, dissolved organic carbon (DOC) and methane (CH4). If sufficient chemical, mineralogical and isotopic data are available, the geochemical mass-balance method can yield the most accurate estimates of the adjusted radiocarbon age. The main limitation of this approach is that complete information is necessary on chemical, mineralogical and isotopic data and these data are often limited.Failure to recognize the limitations and underlying assumptions on which the various models and approaches are based can result in a wide range of estimates of 14C0 and limit the usefulness of radiocarbon as a dating tool for groundwater. In each of the three generalized approaches (single-sample-based models, statistical approach, and geochemical mass-balance approach), successful application depends on scrutiny of the isotopic (14C and 13C) and chemical data to conceptualize the reactions and processes that affect the 14C content of DIC in aquifers. The recently developed graphical analysis method is shown to aid in determining which approach is most appropriate for the isotopic and chemical data from a groundwater system.

Lead Isotopes in Olivine-Phyric Shergottite Tissint: Implications for the Geochemical Evolution of the Shergottite Source Mantle

NASA Technical Reports Server (NTRS)

Moriwaki, R.; Usui, T.; Simon, J. I.; Jones, J. H.; Yokoyama, T.

2015-01-01

Geochemically-depleted shergottites are basaltic rocks derived from a martian mantle source reservoir. Geochemical evolution of the martian mantle has been investigated mainly based on the Rb-Sr, Sm-Nd, and Lu-Hf isotope systematics of the shergottites [1]. Although potentially informative, U-Th- Pb isotope systematics have been limited because of difficulties in interpreting the analyses of depleted meteorite samples that are more susceptible to the effects of near-surface processes and terrestrial contamination. This study conducts a 5-step sequential acid leaching experiment of the first witnessed fall of the geochemically-depleted olivinephyric shergottite Tissint to minimize the effect of low temperature distrubence. Trace element analyses of the Tissint acid residue (mostly pyroxene) indicate that Pb isotope compositions of the residue do not contain either a martian surface or terrestrial component, but represent the Tissint magma source [2]. The residue has relatively unradiogenic initial Pb isotopic compositions (e.g., 206Pb/204Pb = 10.8136) that fall within the Pb isotope space of other geochemically-depleted shergottites. An initial µ-value (238U/204Pb = 1.5) of Tissint at the time of crystallization (472 Ma [3]) is similar to a time-integrated mu- value (1.72 at 472 Ma) of the Tissint source mantle calculated based on the two-stage mantle evolution model [1]. On the other hand, the other geochemically-depleted shergottites (e.g., QUE 94201 [4]) have initial µ-values of their parental magmas distinctly lower than those of their modeled source mantle. These results suggest that only Tissint potentially reflects the geochemical signature of the shergottite mantle source that originated from cumulates of the martian magma ocean

Secular variations of iron isotopes in ferromanganese crusts: evidences for deeply sourced iron in the Pacific Ocean?

NASA Astrophysics Data System (ADS)

Rouxel, O. J.; Gueguen, B.

2016-12-01

Ferromanganese (Fe-Mn) crusts are potential archive of the Fe isotope composition of deep seawater through time. Here, we report Fe isotope composition of two pairs of Fe-Mn crusts collected on two volcanic seamounts from the Northern Pacific Ocean (Apuupuu Seamount, Hawaii) and the Southern Pacific Ocean (near Rurutu Island, Austral archipelago of French Polynesia). This approach allows (a) a direct comparison of the Fe isotope record in Fe-Mn crusts from the same seamount in order to address local effects, and (b) a comparison of geochemical composition of crusts between North and South Pacific in order to address the effect of more global geochemical processes. The results show that, despite different growth rates, diagenetic history, textures and geochemical patterns, Fe-Mn crusts from both North and South Pacific Oceans have fairly homogenous Fe isotope compositions over the last 17 Ma, yielding average δ56Fe values of -0.22 ± 0.20‰ (1sd, n = 54). The results also show striking correlations between Fe and Pb isotope ratios, indicating that local mixing between water masses is the main factor controlling Fe isotope composition in FeMn crusts. Recently, Horner et al. (2015) reported a range of δ56Fe values from -1.12‰ to 1.54‰ along a 76 Ma-old FeMn crust from the central pacific. However, secular variations of Fe isotopes inferred from other FeMn crusts in the Central North Pacific and Western Pacific (Yang and Rouxel, unpublished) show different patterns over the last 40 Ma, with δ56Fe ranging from -0.07 to -0.61‰ (n=81). Hence, the application of Fe isotopes as paleoceanographic proxies to trace deeply sourced iron at the scale of oceanic basins should be used with caution, prompting for an integrative approach combining diverse yet complimentary geochemical proxies.

Role of Dissolved Organic Matter and Geochemical Controls on Arsenic Cycling from Sediments to Groundwater along the Meghna River, Bangladesh: Tracking possible links to permeable natural reactive barrier

NASA Astrophysics Data System (ADS)

Datta, S.; Berube, M.; Knappett, P.; Kulkarni, H. V.; Vega, M.; Jewell, K.; Myers, K.

2017-12-01

Elevated levels of dissolved arsenic (As), iron (Fe) and manganese (Mn) are seen in the shallow groundwaters of southeast Bangladesh on the Ganges Brahmaputra Meghna River delta. This study takes a multi disciplinary approach to understand the extent of the natural reactive barrier (NRB) along the Meghna River and evaluate the role of the NRB in As sequestration and release in groundwater aquifers. Shallow sediment cores, and groundwater and river water samples were collected from the east and west banks of the Meghna. Groundwater and river water samples were tested for FeT, MnT, and AsT concentrations. Fluorescence spectroscopic characterization of groundwater dissolved organic matter (DOM) provided insight into the hydro geochemical reactions active in the groundwater and the hyporheic zones. Eight sediment cores of 1.5 m depth were collected 10 m away from the edge of the river. Vertical solid phase concentration profiles of Fe, Mn and As were measured via 1.2 M HCl digestion which revealed solid phase As accumulation along the riverbanks up to concentrations of 1500 mg/kg As. Microbial interactions with DOM prompts the reduction of Fe3+ to Fe2+, causing As to mobilize into groundwater and humic-like DOM present in the groundwater may catalyze this process. The extent to which microbially mediated release of As occurs is limited by labile dissolved organic carbon (DOC) availability. Aqueous geochemical results showed the highest dissolved As concentrations in shallow wells (<30 m depth), where organic matter was fresh, humic-like, and aromatic. Based on fluorescence characterization, shallow groundwater was found to contain microbial and terrestrial derived DOC, and decomposed, humified and aromatic DOM. Deeper aquifers had a significantly larger microbial OM signature than the shallower aquifers and was less aromatic, decomposed and humified. The results from this study illustrate the potential for humic substances to contribute to As cycling and quantify the extent of As accumulation in the sediments and groundwater along a 1 km stretch of the Meghna. These findings contribute to the overall understanding of geochemical processes involved in As release into groundwaters from sediments within a fluvial deltaic environment and close proximity to a possible permeable natural reactive barrier.

Gemas: Geochemical mapping of the agricultural and grasing land soils of Europe

NASA Astrophysics Data System (ADS)

Reimann, Clemens; Fabian, Karl; Birke, Manfred; Demetriades, Alecos; Matschullat, Jörg; Gemas Project Team

2017-04-01

Geochemical Mapping of Agricultural and grazing land Soil (GEMAS) is a cooperative project between the Geochemistry Expert Group of EuroGeoSurveys and Eurometaux. During 2008 and until early 2009, a total of 2108 samples of agricultural (ploughed land, 0-20 cm, Ap-samples) and 2023 samples of grazing land (0-10 cm, Gr samples)) soil were collected at a density of 1 site/2500 km2 each from 33 European countries, covering an area of 5,600,000 km2. All samples were analysed for 52 chemical elements following an aqua regia extraction, 42 elements by XRF (total), and soil properties, like CEC, TOC, pH (CaCl2), following tight external quality control procedures. In addition, the Ap soil samples were analysed for 57 elements in a mobile metal ion (MMI®) extraction, Pb isotopes, magnetic susceptibility and total C, N and S. The results demonstrate that robust geochemical maps of Europe can be constructed based on low density sampling, the two independent sample materials, Ap and Gr, show very comparable distribution patterns across Europe. At the European scale, element distribution patterns are governed by natural processes, most often a combination of geology and climate. The geochemical maps reflect most of the known metal mining districts in Europe. In addition, a number of new anomalies emerge that may indicate mineral potential. The size of some anomalies is such that they can only be detected when mapping at the continental scale. For some elements completely new geological settings are detected. An anthropogenic impact at a much more local scale is discernible in the immediate vicinity of some major European cities (e.g., London, Paris) and some metal smelters. The impact of agriculture is visible for Cu (vineyard soils) and for some further elements only in the mobile metal ion (MMI) extraction. For several trace elements deficiency issues are a larger threat to plant, animal and finally human health at the European scale than toxicity. Taking the famous step back to see the whole picture at the continental scale and to understand the relative importance of the processes leading to element enrichment/depletion in soil may hold unexpected promise for mineral exploration as well as for environmental sciences.

Chemical modeling constraints on Martian surface mineralogies formed in an early, warm, wet climate, and speculations on the occurrence of phosphate minerals in the Martian regolith

NASA Technical Reports Server (NTRS)

Plumlee, Geoffrey S.; Ridley, W. Ian; Debraal, Jeffrey D.

1992-01-01

This is one in a series of reports summarizing our chemical modeling studies of water-rock-gas interactions at the martian surface through time. The purpose of these studies is to place constraints on possible mineralogies formed at the martian surface and to model the geochemical implications of martian surficial processes proposed by previous researchers. Plumlee and Ridley summarize geochemical processes that may have occurred as a result of inferred volcano- and impact-driven hydrothermal activity on Mars. DeBraal et al. model the geochemical aspects of water-rock interactions and water evaporation near 0 C, as a prelude to future calculations that will model sub-0 C brine-rock-clathrate interactions under the current martian climate. In this report, we discuss reaction path calculations that model chemical processes that may have occurred at the martian surface in a postulated early, warm, wet climate. We assume a temperature of 25 C in all our calculations. Processes we model here include (1) the reaction of rainwater under various ambient CO2 and O2 pressures with basaltic rocks at the martian surface, (2) the formation of acid rain by volcanic gases such as HCl and SO2, (3) the reactions of acid rain with basaltic surficial materials, and (4) evaporation of waters resulting from rainwater-basalt interactions.

Quantifying reactive transport processes governing arsenic mobility in a Bengal Delta aquifer

NASA Astrophysics Data System (ADS)

Rawson, Joey; Neidhardt, Harald; Siade, Adam; Berg, Michael; Prommer, Henning

2017-04-01

Over the last few decades significant progress has been made to characterize the extent and severity of groundwater arsenic pollution in S/SE Asia, and to understand the underlying geochemical processes. However, comparably little effort has been made to merge the findings from this research into quantitative frameworks that allow for a process-based quantitative analysis of observed arsenic behavior and predictions of its future fate. Therefore, this study developed and tested field-scale numerical modelling approaches to represent the primary and secondary geochemical processes associated with the reductive dissolution of Fe-oxy(hydr)oxides and the concomitant release of sorbed arsenic. We employed data from an in situ field experiment in the Bengal Delta Plain, which investigated the influence of labile organic matter (sucrose) on the mobility of Fe, Mn, and As. The data collected during the field experiment were used to guide our model development and to constrain the model parameterisation. Our results show that sucrose oxidation coupled to the reductive dissolution of Fe-oxy(hydr)oxides was accompanied by multiple secondary geochemical reactions that are not easily and uniquely identifiable and quantifiable. Those secondary reactions can explain the disparity between the observed Fe and As behavior. Our modelling results suggest that a significant fraction of the released As is scavenged through (co-)precipitation with newly formed Fe-minerals, specifically magnetite, rather than through sorption to pre-existing and freshly precipitated iron minerals.

Preliminary evaluation of the ground-water-flow system in the Twin Cities Metropolitan area, Minnesota

USGS Publications Warehouse

Guswa, John H.; Siegel, Donald I.; Gillies, Daniel C.

1982-01-01

Areal distribution of calcium, sodium, sulfate, and chloride concentrations were analyzed to provide information on the hydrologic and geochemical relationships between aquifers. Ground water is generally of the calcium magnesium bicarbonate type. Concentration of dissolved solids in water from the Jordan Sandstone and Mount Simon-Hinckley aquifer generally decreases from southwest to northeast across the study area. This decrease probably reflects differences in the quality of recharge water and geochemical processes within the aquifers, such as ion exchange.

Significance of elevated K/Rb ratios in lower crustal rocks

NASA Technical Reports Server (NTRS)

Frost, B. Ronald; Frost, Carol D.

1988-01-01

The granulite uncertainty principle, which states that it is difficult or impossible to determine with certainty the maximum geopressure and geotemperature that a granulite has experienced, is addressed. Also, geochemical fingerprinting cannot always be used reliably in the nebulous region that is transitional between metamorphic and igneous environments. Ion exchange thermometers are typically useful to approximately 800 C in slowly cooled plutonic rocks unless one uses a reintegration technique on unmixed minerals, or unless a metastable mineral assemblage can be observed. It is argued that in most granulites, fossil temperatures are typically obliterated by reequilibration and/or deformation during slow cooling. Granulite metamorphism may be further complicated by the common association with igneous activity. The previously-used geochemical indicators such as high K/Rb ratios and LIL depletion may not be strictly the result of granulite facies metamorphic depletion, but also may result from igneous processes, which depend on bulk and mineral compositions and on the mineralogy of the protolith. Detailed geologic mapping will be the ultimate arbitrator of whether a given geochemical signature is the result of igneous or metamorphic processes.

Bioavailability of pollutants in bacterial communities of Rodrigo de Freitas Lagoon, Rio de Janeiro, Brazil

PubMed Central

da Fonseca, E.M.; Neto, J.A. Baptista; McAlister, J.J.; Smith, B.J.; Crapez, M.A.C.

2014-01-01

Processes involving heavy metals and other contaminants continue to present unsolved environmental questions. To advance the understanding of geochemical processes that involve the bioavailability of contaminants, cores where collected in the Rodrigo de Freitas lagoon, and analyzed for bacterial activity and metal concentrations. Results would suggest an extremely reducing environment where organic substances seem to be the predominant agents responsible for this geochemical process. Analytical data showed sulphate reduction to be the main agent driving this process, since this kind of bacteria was found to be active in all of the samples analyzed. Esterase enzyme production did not signal the influence of heavy metals and hydrocarbon concentrations and heavy metals were found to be unavailable for biota. However, correlation between results for bacterial biomass and the potentially mobile percentage of the total Ni concentrations would suggest a negative impact. PMID:25477931

Influence of hydrological and geochemical processes on the transport of chelated metals and chromate in fractured shale bedrock

NASA Astrophysics Data System (ADS)

Jardine, P. M.; Mehlhorn, T. L.; Larsen, I. L.; Bailey, W. B.; Brooks, S. C.; Roh, Y.; Gwo, J. P.

2002-03-01

Field-scale processes governing the transport of chelated radionuclides in groundwater remain conceptually unclear for highly structured, heterogeneous environments. The objectives of this research were to provide an improved understanding and predictive capability of the hydrological and geochemical mechanisms that control the transport behavior of chelated radionuclides and metals in anoxic subsurface environments that are complicated by fracture flow and matrix diffusion. Our approach involved a long-term, steady-state natural gradient field experiment where nonreactive Br - and reactive 57Co(II)EDTA 2-, 109CdEDTA 2-, and 51Cr(VI) were injected into a fracture zone of a contaminated fractured shale bedrock. The spatial and temporal distribution of the tracer and solutes was monitored for 500 days using an array of groundwater sampling wells instrumented within the fast-flowing fracture regime and a slower flowing matrix regime. The tracers were preferentially transported along strike-parallel fractures coupled with the slow diffusion of significant tracer mass into the bedrock matrix. The chelated radionuclides and metals were significantly retarded by the solid phase with the mechanisms of retardation largely due to redox reactions and sorption coupled with mineral-induced chelate-radionuclide dissociation. The formation of significant Fe(III)EDTA - byproduct that accompanied the dissociation of the radionuclide-chelate complexes was believed to be the result of surface interactions with biotite which was the only Fe(III)-bearing mineral phase present in these Fe-reducing environments. These results counter current conceptual models that suggest chelated contaminants move conservatively through Fe-reducing environments since they are devoid of Fe-oxyhydroxides that are known to aggressively compete for chelates in oxic regimes. Modeling results further demonstrated that chelate-radionuclide dissociation reactions were most prevalent along fractures where accelerated weathering processes are expected to expose more primary minerals than the surrounding rock matrix. The findings of this study suggest that physical retardation mechanisms (i.e. diffusion) are dominant within the matrix regime, whereas geochemical retardation mechanisms are dominant within the fracture regime.

Land-use change and managed aquifer recharge effects on the hydrogeochemistry of two contrasting atoll island aquifers, Roi-Namur Island, Republic of the Marshall Islands

USGS Publications Warehouse

Hejazian, Mehrdad; Gurdak, Jason J.; Swarzenski, Peter W.; Odigie, Kingsley; Storlazzi, Curt

2017-01-01

Freshwater resources on low-lying atoll islands are highly vulnerable to climate change and sea-level rise. In addition to rainwater catchment, groundwater in the freshwater lens is a critically important water resource on many atoll islands, especially during drought. Although many atolls have high annual rainfall rates, dense natural vegetation and high evapotranspiration rates can limit recharge to the freshwater lens. Here we evaluate the effects of land-use/land-cover change and managed aquifer recharge on the hydrogeochemistry and supply of groundwater on Roi-Namur Island, Republic of the Marshall Islands. Roi-Namur is an artificially conjoined island that has similar hydrogeology on the Roi and Namur lobes, but has contrasting land-use/land-cover and managed aquifer recharge only on Roi. Vegetation removal and managed aquifer recharge operations have resulted in an estimated 8.6 x 105 m3 of potable groundwater in the freshwater lens on Roi, compared to only 1.6 x 104 m3 on Namur. We use groundwater samples from a suite of 33 vertically nested monitoring wells, statistical testing, and geochemical modeling using PHREEQC to show that the differences in land-use/land-cover and managed aquifer recharge on Roi and Namur have a statistically significant effect on several groundwater-quality parameters and the controlling geochemical processes. Results also indicate a seven-fold reduction in the dissolution of carbonate rock in the freshwater lens and overlying vadose zone of Roi compared to Namur. Mixing of seawater and the freshwater lens is a more dominant hydrogeochemical process on Roi because of the greater recharge and flushing of the aquifer with freshwater as compared to Namur. In contrast, equilibrium processes and dissolution-precipitation non-equilibrium reactions are more dominant on Namur because of the longer residence times relative to the rate of geochemical reactions. Findings from Roi-Namur Island support selective land-use/land-cover change and managed aquifer recharge as a promising management approach for communities on other low-lying atoll islands to increase the resilience of their groundwater supplies and help them adapt to future climate change related stresses.

Dacite petrogenesis on mid-ocean ridges: Evidence for oceanic crustal melting and assimilation

USGS Publications Warehouse

Wanless, V.D.; Perfit, M.R.; Ridley, W.I.; Klein, E.

2010-01-01

Whereas the majority of eruptions at oceanic spreading centers produce lavas with relatively homogeneous mid-ocean ridge basalt (MORB) compositions, the formation of tholeiitic andesites and dacites at mid-ocean ridges (MORs) is a petrological enigma. Eruptions of MOR high-silica lavas are typically associated with ridge discontinuities and have produced regionally significant volumes of lava. Andesites and dacites have been observed and sampled at several locations along the global MOR system; these include propagating ridge tips at ridge-transform intersections on the Juan de Fuca Ridge and eastern Gal??pagos spreading center, and at the 9??N overlapping spreading center on the East Pacific Rise. Despite the formation of these lavas at various ridges, MOR dacites show remarkably similar major element trends and incompatible trace element enrichments, suggesting that similar processes are controlling their chemistry. Although most geochemical variability in MOR basalts is consistent with low-pressure fractional crystallization of various mantle-derived parental melts, our geochemical data for MOR dacitic glasses suggest that contamination from a seawater-altered component is important in their petrogenesis. MOR dacites are characterized by elevated U, Th, Zr, and Hf, low Nb and Ta concentrations relative to rare earth elements (REE), and Al2O3, K2O, and Cl concentrations that are higher than expected from low-pressure fractional crystallization alone. Petrological modeling of MOR dacites suggests that partial melting and assimilation are both integral to their petrogenesis. Extensive fractional crystallization of a MORB parent combined with partial melting and assimilation of amphibole-bearing altered crust produces a magma with a geochemical signature similar to a MOR dacite. This supports the hypothesis that crustal assimilation is an important process in the formation of highly evolved MOR lavas and may be significant in the generation of evolved MORB in general. Additionally, these processes are likely to be more common in regions of episodic magma supply and enhanced magma-crust interaction such as at the ends of ridge segments. ?? The Author 2010. Published by Oxford University Press. All rights reserved.

Seasonal hyporheic dynamics control coupled microbiology and geochemistry in Colorado River sediments

DOE PAGES

Danczak, Robert E.; Sawyer, Audrey H.; Williams, Kenneth H.; ...

2016-12-03

Riverbed microbial communities play an oversized role in many watershed ecosystem functions, including the processing of organic carbon, cycling of nitrogen, and alterations to metal mobility. The structure and activity of microbial assemblages depend in part on geochemical conditions set by river-groundwater exchange or hyporheic exchange. In order to assess how seasonal changes in river-groundwater mixing affect these populations in a snowmelt-dominated fluvial system, vertical sediment and pore water profiles were sampled at three time points at one location in the hyporheic zone of the Colorado River and analyzed by using geochemical measurements, 16S rRNA gene sequencing, and ecological modeling.more » Oxic river water penetrated deepest into the subsurface during peak river discharge, while under base flow conditions, anoxic groundwater dominated shallower depths. Over a 70 cm thick interval, riverbed sediments were therefore exposed to seasonally fluctuating redox conditions and hosted microbial populations statistically different from those at both shallower and deeper locations. Additionally, microbial populations within this zone were shown to be the most dynamic across sampling time points, underlining the critical role that hyporheic mixing plays in constraining microbial abundances. Given such mixing effects, we anticipate that future changes in river discharge in mountainous, semiarid western U.S. watersheds may affect microbial community structure and function in riverbed environments, with potential implications for biogeochemical processes in riparian regions.« less

The Geochemical Earth Reference Model (GERM)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Staudigel, H.; Albarede, F.; Shaw, H.

The Geochemical Earth Reference Model (GERM) initiative is a grass- roots effort with the goal of establishing a community consensus on a chemical characterization of the Earth, its major reservoirs, and the fluxes between them. Long term goal of GERM is a chemical reservoir characterization analogous to the geophysical effort of the Preliminary Reference Earth Model (PREM). Chemical fluxes between reservoirs are included into GERM to illuminate the long-term chemical evolution of the Earth and to characterize the Earth as a dynamic chemical system. In turn, these fluxes control geological processes and influence hydrosphere-atmosphere-climate dynamics. While these long-term goals aremore » clearly the focus of GERM, the process of establishing GERM itself is just as important as its ultimate goal. The GERM initiative is developed in an open community discussion on the World Wide Web (GERM home page is at http://www-ep.es.llnl. gov/germ/germ-home.html) that is mediated by a series of editors with responsibilities for distinct reservoirs and fluxes. Beginning with the original workshop in Lyons (March 1996) GERM is continued to be developed on the Internet, punctuated by workshops and special sessions at professional meetings. It is planned to complete the first model by mid-1997, followed by a call for papers for a February 1998 GERM conference in La Jolla, California.« less

Seasonal hyporheic dynamics control coupled microbiology and geochemistry in Colorado River sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Danczak, Robert E.; Sawyer, Audrey H.; Williams, Kenneth H.

Riverbed microbial communities play an oversized role in many watershed ecosystem functions, including the processing of organic carbon, cycling of nitrogen, and alterations to metal mobility. The structure and activity of microbial assemblages depend in part on geochemical conditions set by river-groundwater exchange or hyporheic exchange. In order to assess how seasonal changes in river-groundwater mixing affect these populations in a snowmelt-dominated fluvial system, vertical sediment and pore water profiles were sampled at three time points at one location in the hyporheic zone of the Colorado River and analyzed by using geochemical measurements, 16S rRNA gene sequencing, and ecological modeling.more » Oxic river water penetrated deepest into the subsurface during peak river discharge, while under base flow conditions, anoxic groundwater dominated shallower depths. Over a 70 cm thick interval, riverbed sediments were therefore exposed to seasonally fluctuating redox conditions and hosted microbial populations statistically different from those at both shallower and deeper locations. Additionally, microbial populations within this zone were shown to be the most dynamic across sampling time points, underlining the critical role that hyporheic mixing plays in constraining microbial abundances. Given such mixing effects, we anticipate that future changes in river discharge in mountainous, semiarid western U.S. watersheds may affect microbial community structure and function in riverbed environments, with potential implications for biogeochemical processes in riparian regions.« less

Seasonal hyporheic dynamics control coupled microbiology and geochemistry in Colorado River sediments

NASA Astrophysics Data System (ADS)

Danczak, Robert E.; Sawyer, Audrey H.; Williams, Kenneth H.; Stegen, James C.; Hobson, Chad; Wilkins, Michael J.

2016-12-01

Riverbed microbial communities play an oversized role in many watershed ecosystem functions, including the processing of organic carbon, cycling of nitrogen, and alterations to metal mobility. The structure and activity of microbial assemblages depend in part on geochemical conditions set by river-groundwater exchange or hyporheic exchange. To assess how seasonal changes in river-groundwater mixing affect these populations in a snowmelt-dominated fluvial system, vertical sediment and pore water profiles were sampled at three time points at one location in the hyporheic zone of the Colorado River and analyzed by using geochemical measurements, 16S rRNA gene sequencing, and ecological modeling. Oxic river water penetrated deepest into the subsurface during peak river discharge, while under base flow conditions, anoxic groundwater dominated shallower depths. Over a 70 cm thick interval, riverbed sediments were therefore exposed to seasonally fluctuating redox conditions and hosted microbial populations statistically different from those at both shallower and deeper locations. Additionally, microbial populations within this zone were shown to be the most dynamic across sampling time points, underlining the critical role that hyporheic mixing plays in constraining microbial abundances. Given such mixing effects, we anticipate that future changes in river discharge in mountainous, semiarid western U.S. watersheds may affect microbial community structure and function in riverbed environments, with potential implications for biogeochemical processes in riparian regions.

Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan.

PubMed

Al Lawati, Wafa M; Jean, Jiin-Shuh; Kulp, Thomas R; Lee, Ming-Kuo; Polya, David A; Liu, Chia-Chuan; van Dongen, Bart E

2013-11-15

Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release. Copyright © 2012 Elsevier B.V. All rights reserved.

Geochemical behaviour of dissolved trace elements in a monsoon-dominated tropical river basin, Southwestern India.

PubMed

Gurumurthy, G P; Balakrishna, K; Tripti, M; Audry, Stéphane; Riotte, Jean; Braun, J J; Udaya Shankar, H N

2014-04-01

The study presents a 3-year time series data on dissolved trace elements and rare earth elements (REEs) in a monsoon-dominated river basin, the Nethravati River in tropical Southwestern India. The river basin lies on the metamorphic transition boundary which separates the Peninsular Gneiss and Southern Granulitic province belonging to Archean and Tertiary-Quaternary period (Western Dharwar Craton). The basin lithology is mainly composed of granite gneiss, charnockite and metasediment. This study highlights the importance of time series data for better estimation of metal fluxes and to understand the geochemical behaviour of metals in a river basin. The dissolved trace elements show seasonality in the river water metal concentrations forming two distinct groups of metals. First group is composed of heavy metals and minor elements that show higher concentrations during dry season and lesser concentrations during the monsoon season. Second group is composed of metals belonging to lanthanides and actinides with higher concentration in the monsoon and lower concentrations during the dry season. Although the metal concentration of both the groups appears to be controlled by the discharge, there are important biogeochemical processes affecting their concentration. This includes redox reactions (for Fe, Mn, As, Mo, Ba and Ce) and pH-mediated adsorption/desorption reactions (for Ni, Co, Cr, Cu and REEs). The abundance of Fe and Mn oxyhydroxides as a result of redox processes could be driving the geochemical redistribution of metals in the river water. There is a Ce anomaly (Ce/Ce*) at different time periods, both negative and positive, in case of dissolved phase, whereas there is positive anomaly in the particulate and bed sediments. The Ce anomaly correlates with the variations in the dissolved oxygen indicating the redistribution of Ce between particulate and dissolved phase under acidic to neutral pH and lower concentrations of dissolved organic carbon. Unlike other tropical and major world rivers, the effect of organic complexation on metal variability is negligible in the Nethravati River water.

New geochemical insights into volcanic degassing.

PubMed

Edmonds, Marie

2008-12-28

Magma degassing plays a fundamental role in controlling the style of volcanic eruptions. Whether a volcanic eruption is explosive, or effusive, is of crucial importance to approximately 500 million people living in the shadow of hazardous volcanoes worldwide. Studies of how gases exsolve and separate from magma prior to and during eruptions have been given new impetus by the emergence of more accurate and automated methods to measure volatile species both as volcanic gases and dissolved in the glasses of erupted products. The composition of volcanic gases is dependent on a number of factors, the most important being magma composition and the depth of gas-melt segregation prior to eruption; this latter parameter has proved difficult to constrain in the past, yet is arguably the most critical for controlling eruptive style. Spectroscopic techniques operating in the infrared have proved to be of great value in measuring the composition of gases at high temporal resolution. Such methods, when used in tandem with microanalytical geochemical investigations of erupted products, are leading to better constraints on the depth at which gases are generated and separated from magma. A number of recent studies have focused on transitions between explosive and effusive activity and have led to a better understanding of gas-melt segregation at basaltic volcanoes. Other studies have focused on degassing during intermediate and silicic eruptions. Important new results include the recognition of fluxing by deep-derived gases, which buffer the amount of dissolved volatiles in the melt at shallow depths, and the observation of gas flow up permeable conduit wall shear zones, which may be the primary mechanism for gas loss at the cusp of the most explosive and unpredictable volcanic eruptions. In this paper, I review current and future directions in the field of geochemical studies of volcanic degassing processes and illustrate how the new insights are beginning to change the way in which we understand and classify volcanic eruptions.

Using an intelligent system to aid in tephra layer correlation of the tephra beds of the Mono-Inyo Craters, California

NASA Astrophysics Data System (ADS)

Hanson-Hedgecock, S.; Bursik, M.; Rogova, G.

2008-12-01

We are developing an intelligent system to correlate tephra layers by using the lithologic and geochemical characteristics of field samples, to aid geologists in interpreting eruption patterns in volcanic fields. Understanding the eruption history of a volcanic field from stratigraphic studies is important for forecasting future eruptive behavior and hazards. The intelligent system is used to define groups of tephra source vents and to correlate tephra layers based on a combination of geochemical data and lithostratigraphic characteristics. The tephra beds of the Mono-Inyo Craters, California, are used to test the ability of the intelligent system for tephra layer correlation. The data processing is performed by a suite of both unsupervised and supervised classifiers, built and combined within the framework of the Dempster-Shafer theory of evidence. We have developed algorithms to calculate isopleth maps of thickness, lithic and pumice size that are used in the processing of the lithostratigraphic data. This spatial information is important in the determination of eruption patterns and is used by an evidential nearest neighbor classifier to correlate tephra layers. Integrating a better isopleth approximation function and expert knowledge about stratigraphic order of the tephra layers into the classifier improves the lithostratigraphic correlation from 56% to 87% of layers correctly identified. Geochemical data for defining groups of tephra sources are processed by a suit of fuzzy k-means classifiers. Improved clustering results of geochemical data are achieved by the fusion of individual clustering results with an evidential combination method. The intelligent system aids correlation by showing matches and disparities between data patterns from different outcrops that may have been overlooked. The intelligent system produces a useful recognition result, while dealing with the uncertainty from sparse data and the imprecise description of layer characteristics.

Equine grass sickness in Scotland: A case-control study of environmental geochemical risk factors.

PubMed

Wylie, C E; Shaw, D J; Fordyce, F M; Lilly, A; Pirie, R S; McGorum, B C

2016-11-01

We hypothesised that the apparent geographical distribution of equine grass sickness (EGS) is partly attributable to suboptimal levels of soil macro- and trace elements in fields where EGS occurs. If proven, altering levels of particular elements could be used to reduce the risk of EGS. To determine whether the geographical distribution of EGS cases in eastern Scotland is associated with the presence or absence of particular environmental chemical elements. Retrospective time-matched case-control study. This study used data for 455 geo-referenced EGS cases and 910 time-matched controls in eastern Scotland, and geo-referenced environmental geochemical data from the British Geological Survey Geochemical Baseline Survey of the Environment stream sediment (G-BASE) and the James Hutton Institute, National Soil Inventory of Scotland (NSIS) datasets. Multivariable statistical analyses identified clusters of three main elements associated with cases from (i) the G-BASE dataset - higher environmental Ti and lower Zn, and (ii) the NSIS dataset - higher environmental Ti and lower Cr. There was also some evidence from univariable analyses for lower Al, Cd, Cu, Ni and Pb and higher Ca, K, Mo, Na and Se environmental concentrations being associated with a case. Results were complicated by a high degree of correlation between most geochemical elements. The work presented here would appear to reflect soil- not horse-level risk factors for EGS, but due to the complexity of the correlations between elements, further work is required to determine whether these associations reflect causality, and consequently whether interventions to alter concentrations of particular elements in soil, or in grazing horses, could potentially reduce the risk of EGS. The effect of chemical elements on the growth of those soil microorganisms implicated in EGS aetiology also warrants further study. © 2015 The The Authors Equine Veterinary Journal © 2015 EVJ Ltd.

Resolving the Multi-scale Behavior of Geochemical Weathering in the Critical Zone Using High Resolution Hydro-geochemical Models

NASA Astrophysics Data System (ADS)

Pandey, S.; Rajaram, H.

2015-12-01

This work investigates hydrologic and geochemical interactions in the Critical Zone (CZ) using high-resolution reactive transport modeling. Reactive transport models can be used to predict the response of geochemical weathering and solute fluxes in the CZ to changes in a dynamic environment, such as those pertaining to human activities and climate change in recent years. The scales of hydrology and geochemistry in the CZ range from days to eons in time and centimeters to kilometers in space. Here, we present results of a multi-dimensional, multi-scale hydro-geochemical model to investigate the role of subsurface heterogeneity on the formation of mineral weathering fronts in the CZ, which requires consideration of many of these spatio-temporal scales. The model is implemented using the reactive transport code PFLOTRAN, an open source subsurface flow and reactive transport code that utilizes parallelization over multiple processing nodes and provides a strong framework for simulating weathering in the CZ. The model is set up to simulate weathering dynamics in the mountainous catchments representative of the Colorado Front Range. Model parameters were constrained based on hydrologic, geochemical, and geophysical observations from the Boulder Creek Critical Zone Observatory (BcCZO). Simulations were performed in fractured rock systems and compared with systems of heterogeneous and homogeneous permeability fields. Tracer simulations revealed that the mean residence time of solutes was drastically accelerated as fracture density increased. In simulations that include mineral reactions, distinct signatures of transport limitations on weathering arose when discrete flow paths were included. This transport limitation was related to both advective and diffusive processes in the highly heterogeneous systems (i.e. fractured media and correlated random permeability fields with σlnk > 3). The well-known time-dependence of mineral weathering rates was found to be the most pronounced in the fractured systems, with a departure from the maximum system-averaged dissolution rate occurring after ~100 kyr followed by a gradual decrease in the reaction rate with time that persists beyond 104 kyr.

High-temperature life without photosynthesis as a model for Mars

NASA Technical Reports Server (NTRS)

Shock, E. L.

1997-01-01

Discoveries in biology and developments in geochemistry over the past two decades have lead to a radical revision of concepts relating to the upper temperature at which life thrives, the genetic relationships among all life on Earth, links between organic and inorganic compounds in geologic processes, and the geochemical supply of metabolic energy. It is now apparent that given a source of geochemical energy, in the form of a mixture of compounds that is far from thermodynamic equilibrium, microorganisms can take advantage of the energy and thrive without the need for photosynthesis as a means of primary productivity. This means that life can exist in the subsurface of a planet such as Mars without necessarily exhibiting a surface expression. Theoretical calculations quantify the geochemically provided metabolic energy available to hyperthermophilic organisms in submarine hydrothermal systems on the Earth, and help to explain the enormous biological productivity of these systems. Efforts to place these models in the context of the early Earth reveal that substantial geochemical energy would have been available and that organic synthesis would have been thermodynamically favored as hydrothermal fluids mix with seawater.

A kinetics database and scripts for PHREEQC

NASA Astrophysics Data System (ADS)

Hu, B.; Zhang, Y.; Teng, Y.; Zhu, C.

2017-12-01

Kinetics of geochemical reactions has been increasingly used in numerical models to simulate coupled flow, mass transport, and chemical reactions. However, the kinetic data are scattered in the literature. To assemble a kinetic dataset for a modeling project is an intimidating task for most. In order to facilitate the application of kinetics in geochemical modeling, we assembled kinetics parameters into a database for the geochemical simulation program, PHREEQC (version 3.0). Kinetics data were collected from the literature. Our database includes kinetic data for over 70 minerals. The rate equations are also programmed into scripts with the Basic language. Using the new kinetic database, we simulated reaction path during the albite dissolution process using various rate equations in the literature. The simulation results with three different rate equations gave difference reaction paths at different time scale. Another application involves a coupled reactive transport model simulating the advancement of an acid plume in an acid mine drainage site associated with Bear Creek Uranium tailings pond. Geochemical reactions including calcite, gypsum, and illite were simulated with PHREEQC using the new kinetic database. The simulation results successfully demonstrated the utility of new kinetic database.

Particle Fluxes and Bulk Geochemical Characterization of the Cabo Frio Upwelling System in Southeastern Brazil: Sediment Trap Experiments between Spring 2010 and Summer 2012.

PubMed

Albuquerque, Ana Luiza S; Belém, André L; Zuluaga, Francisco J B; Cordeiro, Livia G M; Mendoza, Ursula; Knoppers, Bastiaan A; Gurgel, Marcio H C; Meyers, Philip A; Capilla, Ramsés

2014-05-14

Physical and biogeochemical processes in continental shelves act synergistically in both transporting and transforming suspended material, and ocean dynamics control the dispersion of particles by the coastal zone and their subsequent mixing and dilution within the shelf area constrained by oceanic boundary currents, followed by their gradual settling in a complex sedimentary scenario. One of these regions is the Cabo Frio Upwelling System located in a significantly productive area of Southeastern Brazil, under the control of the nutrient-poor western boundary Brazil Current but also with a wind-driven coastal upwelling zone, inducing cold-water intrusions of South Atlantic Central Water on the shelf. To understand these synergic interactions among physical and biogeochemical processes in the Cabo Frio shelf, a series of four experiments with a total of 98 discrete samples using sediment traps was performed from November 2010 to March 2012, located on the 145 m isobath on the edge of the continental shelf. The results showed that lateral transport might be relevant in some cases, especially in deep layers, although no clear seasonal cycle was detected. Two main physical-geochemical coupling scenarios were identified: singular downwelling events that can enhance particles fluxes and are potentially related to the Brazil Current oscillations; and events of significant fluxes related to the intrusion of the 18°C isotherm in the euphotic zone. The particulate matter settling in the Cabo Frio shelf area seems to belong to multiple marine and terrestrial sources, in which both Paraiba do Sul River and Guanabara Bay could be potential land-sources, although the particulate material might subject intense transformation (diagenesis) during its trajectory to the shelf edge.

Geobiochemistry: Placing Biochemistry in Its Geochemical Context

NASA Astrophysics Data System (ADS)

Shock, E.; Boyer, G. M.; Canovas, P. A., III; Prasad, A.; Dick, J. M.

2014-12-01

Goals of geobiochemistry include simultaneously evaluating the relative stabilities of microbial cells and minerals, and predicting how the composition of biomolecules can change in response to the progress of geochemical reactions. Recent developments in theoretical geochemistry make it possible to predict standard thermodynamic properties of proteins, nucleotides, lipids, and many metabolites including the constituents of the citric acid cycle, at all temperatures and pressures where life is known to occur, and beyond. Combining these predictions with constraints from geochemical data makes it possible to assess the relative stabilities of biomolecules. Resulting independent predictions of the environmental occurrence of homologous proteins and lipid side-chains can be compared with observations from metagenomic and metalipidomic data to quantify geochemical driving forces that shape the composition of biomolecules. In addition, the energetic costs of generating biomolecules from within a diverse range of habitable environments can be evaluated in terms of prevailing geochemical variables. Comparisons of geochemical bioenergetic calculations across habitats leads to the generalization that the availability of H2 determines the cost of autotrophic biosynthesis relative to the aquatic environment external to microbial cells, and that pH, temperature, pressure, and availability of C, N, P, and S are typically secondary. Increasingly reduced conditions, which are determined by reactions of water with mineral surfaces and mineral assemblages, allow many biosynthetic reactions to shift from costing energy to releasing energy. Protein and lipid synthesis, as well as the reverse citric acid cycle, become energy-releasing processes under these conditions. The resulting energy balances that determine habitability contrast dramatically with assumptions derived from oxic surface conditions, such as those where human biochemistry operates.

Patterns and variability in geochemical signatures and microbial activity within and between diverse cold seep habitats along the lower continental slope, Northern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Bowles, Marshall; Hunter, Kimberley S.; Samarkin, Vladimir; Joye, Samantha

2016-07-01

We collected 69 sediment cores from distinct ecological and geological settings along the deep slope in the Northern Gulf of Mexico to evaluate whether specific geochemical- or habitat-related factors correlated with rates of microbial processes and geochemical signatures. By collecting replicate cores from distinct habitats across multiple sites, we illustrate and quantify the heterogeneity of cold seep geochemistry and microbial activity. These data also document the factors driving unique aspects of the geochemistry of deep slope gas, oil and brine seeps. Surprisingly little variation was observed between replicate (n=2-5) cores within sites for most analytes (except methane), implying that the common practice of collecting one core for geochemical analysis can capture the signature of a habitat in most cases. Depth-integrated concentrations of methane, dissolved inorganic carbon (DIC), and calcium were the predominant geochemical factors that correlated with a site's ecological or geological settings. Pore fluid methane concentration was related to the phosphate and DIC concentration, as well as to rates of sulfate reduction. While distinctions between seep habitats were identified from geochemical signatures, habitat specific geochemistry varied little across sites. The relative concentration of dissolved inorganic nitrogen versus phosphorus suggests that phosphorus availability limits biomass production at cold seeps. Correlations between calcium, chloride, and phosphate concentrations were indicative of brine-associated phosphate transport, suggesting that in addition to the co-migration of methane, dissolved organic carbon, and ammonium with brine, phosphate delivery is also associated with brine advection.

Hydrogeochemical processes and geochemical modeling in a coastal aquifer: Case study of the Marathon coastal plain, Greece

NASA Astrophysics Data System (ADS)

Papazotos, Panagiotis; Koumantakis, Ioannis; Kallioras, Andreas; Vasileiou, Eleni; Perraki, Maria

2017-04-01

Determining the hydrogeochemical processes has always been a challenge for scientists. The aim of this work is the study of the principal hydrogeochemical processes controlling groundwater quality in the Marathon coastal plain, Greece, with emphasis on the origin of the solutes. Various physicochemical parameters and major ions of twenty-five groundwater samples were analyzed. The hydrogeochemical data of groundwater were studied in order to determine the major factors controlling the chemical composition and hydrogeochemical evolution. In the Marathon coastal plain, three different zones of the alluvial granular aquifer system have been detected, considering the geochemical processes and recharge, which affect its hydrochemical characteristics. The alluvial granular aquifer system is divided eastwards into three zones: a) the natural recharge zone, b) the reverse ion exchange zone and c) the diffusion sea water zone. Cl-is the dominant anion and Na+and Ca2+ are the dominant cations, as determined by plotting the analyses on the respective Piper diagram. Near the coastline high concentrations of Na+ and Cl- were observed indicating a zone of seawater intrusion. On the other hand, westward there is increasing concentration of HCO3- with simultaneous decrease of Na+is indication of a recharge zone from karstic aquifers of the study area. Between the aforementioned zones there is an intermediate one, where reverse ion exchange takes place due to high concentrations of dissolved Na+ and Ca2+ adsorption. The saturation indices (SI) were calculated using the geochemical modeling software PHREEQC. Mineral phases of halite, sylvite, gypsum and anhydrite were estimated to be undersaturated in the water samples, suggesting these phases are minor or absent in the host rock. On the other hand, calcite, aragonite and dolomite are close to equilibrium; these minerals are present in the host rocks or in the unsaturated zone, possibly increasing the Ca2+, Mg2+ and HCO3- concentrations when carbonates are dissolved. The analyses of the bivariate scatter plots, the ionic ratios, the Indices of Base Exchange (IBE), the Gibbs diagram and the dissolution/precipitation reactions show that evaporation and water-rock interaction mechanisms such as dissolution of carbonates, followed by reverse ion exchange, have affected the groundwater chemistry in the study area. The results revealed that groundwater chemistry and therefore the origin of the solutes in the coastal alluvial granular aquifer system of the Marathon coastal plain is primarily affected by a number of factors such as groundwater and mineral equilibrium, seawater intrusion, reverse ion exchange and nitrate concentration. A possible future research could focus on the interaction among hydrogeochemistry, mineral phases and chemical thermodynamic modeling.

Tracing Marine Cryptotephras in the North Atlantic during the Last Glacial Period

NASA Astrophysics Data System (ADS)

Abbott, Peter; Davies, Siwan; Griggs, Adam; Bourne, Anna

2017-04-01

Tephrochronology is a powerful technique that can be utilised for the independent correlation and synchronisation of disparate palaeoclimatic records from different depositional environments. There is a high potential to utilise this technique to integrate ice, marine and terrestrial records to study climatic phasing within the North Atlantic region due to the high eruptive frequency of Icelandic volcanic systems. However, until now North Atlantic marine records have been relatively understudied. Here we report on investigations to define a tephra framework integrating new studies of cryptotephra horizons within a wide network of North Atlantic marine cores with horizons identified in prior work. This framework has the potential to underpin the correlation of the marine records to the Greenland ice-core records and European terrestrial sequences. Tephrochronological investigations were conducted on 13 marine sequences from a range of locations and depositional settings using cryptotephra extraction techniques, including density and magnetic separation, to gain high resolution glass shard concentration profiles and rigorous single-shard major element geochemical analysis to characterise identified deposits. Cryptotephras with an Icelandic source were identified in many records and displayed diversity in shard concentration profiles and the geochemical homo/heterogeneity of shards within the deposits. These differences reflect spatial and temporal variability in the operation of a range of transport processes, e.g. airfall, sea-ice and iceberg rafting, and post-depositional processes, e.g. bioturbation and secondary redeposition. The operation of these processes within the marine environment can potentially impart a temporal delay on tephra deposition and hamper the placement of the isochron, therefore, it is crucial to assess their influence. To aid this assessment a range of deposit types with common transport and depositional histories have been defined. Spatial patterns in the occurrence of these deposit types have been detected, the dominant controls at different sites explored and key regions of the North Atlantic with a greater likelihood for preserving isochronous deposits identified. Overall, these investigations have allowed a framework of isochronous marine cryptotephras to be defined for the last glacial period. The most widespread deposit is the rhyolitic phase of North Atlantic Ash Zone II, identified in 9 of the marine sequences and providing a direct tie-line to the Greenland ice-cores records. The framework is dominated by horizons with a basaltic composition, predominantly sourced from the Icelandic Grímsvötn volcanic system but horizons with Katla, Hekla, Kverkfjöll, Veidivötn and Vestmannaeyjar like compositions have also been isolated. Correlations to horizons in the Greenland ice-core tephra framework are being explored, however, this is a challenging process due to the large number of horizons with similar geochemical signatures in the records and the difference in temporal resolution and stratigraphic control between the ice and marine sequences.

The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey.

PubMed

Zhang, Lingyan; Guo, Shuhai; Wu, Bo

2015-01-01

The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD) were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb) were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As.

The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey

PubMed Central

Zhang, Lingyan; Guo, Shuhai; Wu, Bo

2015-01-01

The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD) were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb) were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As. PMID:26230506

Magma mixing and high fountaining during the 1959 Kīlauea Iki eruption, Hawai‘i

USGS Publications Warehouse

Sides, I.; Edmonds, M.; Maclennan, J.; Houghton, Bruce F.; Swanson, Don; Steele-MacInnis, M.J.

2014-01-01

The 1959 Kīlauea Iki eruption provides a unique opportunity to investigate the process of shallow magma mixing, its impact on the magmatic volatile budget and its role in triggering and driving episodes of Hawaiian fountaining. Melt inclusions hosted by olivine record a continuous decrease in H2O concentration through the 17 episodes of the eruption, while CO2 concentrations correlate with the degree of post-entrapment crystallization of olivine on the inclusion walls. Geochemical data, when combined with the magma budget and with contemporaneous eruption observations, show complex mixing between episodes involving hot, geochemically heterogeneous melts from depth, likely carrying exsolved vapor, and melts which had erupted at the surface, degassed and drained-back into the vent. The drained-back melts acted as a coolant, inducing rapid cooling of the more primitive melts and their olivines at shallow depths and inducing crystallization and vesiculation and triggering renewed fountaining. A consequence of the mixing is that the melts became vapor-undersaturated, so equilibration pressures cannot be inferred from them using saturation models. After the melt inclusions were trapped, continued growth of vapor bubbles, caused by enhanced post-entrapment crystallization, sequestered a large fraction of CO2 from the melt within the inclusions. This study, while cautioning against accepting melt inclusion CO2 concentrations “as measured” in mixed magmas, also illustrates that careful analysis and interpretation of post-entrapment modifications can turn this apparent challenge into a way to yield novel useful insights into the geochemical controls on eruption intensity.

The massive dolomitization of platformal and basinal sequences: proposed models from the Paleocene, Northeast Sirte Basin, Libya

NASA Astrophysics Data System (ADS)

Mresah, Mohamed H.

1998-03-01

The Paleocene carbonate succession in the Northeast Sirte Basin is composed of two shallowing-upward ramp cycles, where each cycle is under- and overlain by deeper-water, pelagic facies. A significant proportion of each of these two cycles is dolomitized. Petrographic study, supported by geochemical data (stoichiometry, stable isotopes, trace elements, and fluid inclusions), and integrated with broader tectono-sedimentary information, has provided the basis for interpreting these Paleocene dolomites. The use of this integrated approach in the study of dolomites suggests that, despite the much publicized uncertainties in interpreting geochemical analyses of ancient dolomites, the results of the Paleocene dolomites show that the geochemical characteristics are generally consistent with regional stratigraphic distribution and petrographic observations. Four distinct types of dolomite have been recognized in this part of the Sirte Basin. Based on the stratigraphic position and petrographic criteria, two of these types have a platformal setting and the other two are basinal. The platform varieties consist of dolomicrites and pervasive stratal dolomites. The dolomicrites, interpreted to be of syn-sedimentary origin, were probably a product of reflux of seawater, with elevated salinity, as suggested by palaeoenvironmental analysis and supported by geochemical evidence (the average S'80 value is -0.1‰ PDB; the average Sr content is 639 ppm). The pervasive dolomites were formed during the progradation of the platform sequences, and probably stabilized and augmented during shallow burial. A meteoric-marine mixing-zone is thought to have been the most likely process for the formation of these dolomites. This interpretation is supported by geochemical evidence (the average δ18O is -2.4‰ PDB; the average Sr content is 72 ppm) combined with a favourable stratigraphic position. The most characteristic feature related to both mixing-zone and reflux dolomitization is the basinward movement of the dolomitizing fluids, which suggests that the formation of these platform dolomites was related to a lowstand system tract. The two basinal varieties comprise thick (over 300 m) basinal dolomudstones and fracture-filling, sparry dolomites. The stratigraphic position of the finely crystalline basinal dolomudstones, within very thick shale successions (as a result of being very close to the depocentre of the Sirte Basin) combined with geochemical evidence (the average δ18O is -6.4‰ PDB), suggest that the dolomitizing fluids were basin-derived, with Mg 2+ released from dewatering through compaction of basinal shales. The occurrence of this type of dolomite provides one of the rare examples of large-scale dolomitization of thick, basinal sequences. Late diagenetic fracture-filling dolomites exhibit a structural control on their distribution. Geochemical evidence (including fluid inclusion analysis and the lightest oxygen isotopic signature of -7.3‰ PDB) suggests that highly saline formation brines were the solutions responsible for their formation.

Geomechanical/Geochemical Modeling Studies Conducted within theInternational DECOVALEX Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Birkholzer, J.T.; Rutqvist, J.; Sonnenthal, E.L.

2005-10-19

The DECOVALEX project is an international cooperative project initiated by SKI, the Swedish Nuclear Power Inspectorate, with participation of about 10 international organizations. The general goal of this project is to encourage multidisciplinary interactive and cooperative research on modeling coupled thermo-hydro-mechanical-chemical (THMC) processes in geologic formations in support of the performance assessment for underground storage of radioactive waste. One of the research tasks, initiated in 2004 by the U.S. Department of Energy (DOE), addresses the long-term impact of geomechanical and geochemical processes on the flow conditions near waste emplacement tunnels. Within this task, four international research teams conduct predictive analysismore » of the coupled processes in two generic repositories, using multiple approaches and different computer codes. Below, we give an overview of the research task and report its current status.« less

Geomechanical/ Geochemical Modeling Studies onducted Within the International DECOVALEX Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

J.T. Birkholzer; J. Rutqvist; E.L. Sonnenthal

2006-02-01

The DECOVALEX project is an international cooperative project initiated by SKI, the Swedish Nuclear Power Inspectorate, with participation of about 10 international organizations. The general goal of this project is to encourage multidisciplinary interactive and cooperative research on modeling coupled thermo-hydro-mechanical-chemical (THMC) processes in geologic formations in support of the performance assessment for underground storage of radioactive waste. One of the research tasks, initiated in 2004 by the U.S. Department of Energy (DOE), addresses the long-term impact of geomechanical and geochemical processes on the flow conditions near waste emplacement tunnels. Within this task, four international research teams conduct predictive analysismore » of the coupled processes in two generic repositories, using multiple approaches and different computer codes. Below, we give an overview of the research task and report its current status.« less

Geochemical studies of rare earth elements in the Portuguese pyrite belt, and geologic and geochemical controls on gold distribution

USGS Publications Warehouse

Grimes, David J.; Earhart, Robert L.; de Carvalho, Delfim; Oliveira, Vitor; Oliveira, Jose T.; Castro, Paulo

1998-01-01

This report describes geochemical and geological studies which were conducted by the U.S. Geological Survey (USGS) and the Servicos Geologicos de Portugal (SPG) in the Portuguese pyrite belt (PPB) in southern Portugal. The studies included rare earth element (REE) distributions and geological and geochemical controls on the distribution of gold. Rare earth element distributions were determined in representative samples of the volcanic rocks from five west-trending sub-belts of the PPB in order to test the usefulness of REE as a tool for the correlation of volcanic events, and to determine their mobility and application as hydrothermal tracers. REE distributions in felsic volcanic rocks show increases in the relative abundances of heavy REE and a decrease in La/Yb ratios from north to south in the Portuguese pyrite belt. Anomalous amounts of gold are distributed in and near massive and disseminated sulfide deposits in the PPB. Gold is closely associated with copper in the middle and lower parts of the deposits. Weakly anomalous concentrations of gold were noted in exhalative sedimentary rocks that are stratigraphically above massive sulfide deposits in a distal manganiferous facies, whereas anomalously low concentrations were detected in the barite-rich, proximal-facies exhalites. Altered and pyritic felsic volcanic rocks locally contain highly anomalous concentrations of gold, suggesting that disseminated sulfide deposits and the non-ore parts of massive sulfide deposits should be evaluated for their gold potential.

Major hydrogeochemical processes in an acid mine drainage affected estuary.

PubMed

Asta, Maria P; Calleja, Maria Ll; Pérez-López, Rafael; Auqué, Luis F

2015-02-15

This study provides geochemical data with the aim of identifying and quantifying the main processes occurring in an Acid Mine Drainage (AMD) affected estuary. With that purpose, water samples of the Huelva estuary were collected during a tidal half-cycle and ion-ion plots and geochemical modeling were performed to obtain a general conceptual model. Modeling results indicated that the main processes responsible for the hydrochemical evolution of the waters are: (i) the mixing of acid fluvial water with alkaline ocean water; (ii) precipitation of Fe oxyhydroxysulfates (schwertmannite) and hydroxides (ferrihydrite); (iii) precipitation of Al hydroxysulfates (jurbanite) and hydroxides (amorphous Al(OH)3); (iv) dissolution of calcite; and (v) dissolution of gypsum. All these processes, thermodynamically feasible in the light of their calculated saturation states, were quantified by mass-balance calculations and validated by reaction-path calculations. In addition, sorption processes were deduced by the non-conservative behavior of some elements (e.g., Cu and Zn). Copyright © 2014 Elsevier Ltd. All rights reserved.

Using stable isotopes and major ions to identify hydrological processes and geochemical characteristics in a typical karstic basin, Guizhou, Southwest China.

PubMed

Han, Zhiwei; Tang, Changyuan; Wu, Pan; Zhang, Ruixue; Zhang, Chipeng

2014-01-01

The investigation of hydrological processes is very important for water resource development in karst basins. In order to understand these processes associated with complex hydrogeochemical evolution, a typical basin was chosen in Houzai, southwest China. The basin was hydrogeologically classified into three zones based on hydrogen and oxygen isotopes as well as the field surveys. Isotopic values were found to be enriched in zone 2 where paddy fields were prevailing with well-developed underground flow systems, and heavier than those in zone 1. Zone 3 was considered as the mixture of zones 1 and 2 with isotopic values falling in the range between the two zones. A conceptual hydrological model was thus proposed to reveal the probable hydrological cycle in the basin. In addition, major processes of long-term chemical weathering in the karstic basin were discussed, and reactions between water and carbonate rocks proved to be the main geochemical processes in karst aquifers.

Effects of physical and biogeochemical processes on aquatic ecosystems at the groundwater-surface water interface: An evaluation of a sulfate-impacted wild rice stream in Minnesota (USA)

NASA Astrophysics Data System (ADS)

Ng, G. H. C.; Yourd, A. R.; Myrbo, A.; Johnson, N.

2015-12-01

Significant uncertainty and variability in physical and biogeochemical processes at the groundwater-surface water interface complicate how surface water chemistry affects aquatic ecosystems. Questions surrounding a unique 10 mg/L sulfate standard for wild rice (Zizania sp.) waters in Minnesota are driving research to clarify conditions controlling the geochemistry of shallow sediment porewater in stream- and lake-beds. This issue raises the need and opportunity to carry out in-depth, process-based analysis into how water fluxes and coupled C, S, and Fe redox cycles interact to impact aquatic plants. Our study builds on a recent state-wide field campaign that showed that accumulation of porewater sulfide from sulfate reduction impairs wild rice, an annual grass that grows in shallow lakes and streams in the Great Lakes region of North America. Negative porewater sulfide correlations with organic C and Fe quantities also indicated that lower redox rates and greater mineral precipitation attenuate sulfide. Here, we focus on a stream in northern Minnesota that receives high sulfate loading from iron mining activity yet maintains wild rice stands. In addition to organic C and Fe effects, we evaluate the degree to which streambed hydrology, and in particular groundwater contributions, accounts for the active biogeochemistry. We collect field measurements, spanning the surrounding groundwater system to the stream, to constrain a reactive-transport model. Observations from seepage meters, temperature probes, and monitoring wells delineate upward flow that may lessen surface water impacts below the stream. Geochemical analyses of groundwater, porewater, and surface water samples and of sediment extractions reveal distinctions among the different domains and stream banks, which appear to jointly control conditions in the streambed. A model based on field conditions can be used to evaluate the relative the importance and the spatiotemporal scales of diverse flux and geochemical factors affecting aquatic root zones.

Fingerprinting captured CO2 using natural tracers: Determining CO2 fate and proving ownership

NASA Astrophysics Data System (ADS)

Flude, Stephanie; Gilfillan, Stuart; Johnston, Gareth; Stuart, Finlay; Haszeldine, Stuart

2016-04-01

In the long term, captured CO2 will most likely be stored in large saline formations and it is highly likely that CO2 from multiple operators will be injected into a single saline formation. Understanding CO2 behavior within the reservoir is vital for making operational decisions and often uses geochemical techniques. Furthermore, in the event of a CO2 leak, being able to identify the owner of the CO2 is of vital importance in terms of liability and remediation. Addition of geochemical tracers to the CO2 stream is an effective way of tagging the CO2 from different power stations, but may become prohibitively expensive at large scale storage sites. Here we present results from a project assessing whether the natural isotopic composition (C, O and noble gas isotopes) of captured CO2 is sufficient to distinguish CO2 captured using different technologies and from different fuel sources, from likely baseline conditions. Results include analytical measurements of CO2 captured from a number of different CO2 capture plants and a comprehensive literature review of the known and hypothetical isotopic compositions of captured CO2 and baseline conditions. Key findings from the literature review suggest that the carbon isotope composition will be most strongly controlled by that of the feedstock, but significant fractionation is possible during the capture process; oxygen isotopes are likely to be controlled by the isotopic composition of any water used in either the industrial process or the capture technology; and noble gases concentrations will likely be controlled by the capture technique employed. Preliminary analytical results are in agreement with these predictions. Comparison with summaries of likely storage reservoir baseline and shallow or surface leakage reservoir baseline data suggests that C-isotopes are likely to be valuable tracers of CO2 in the storage reservoir, while noble gases may be particularly valuable as tracers of potential leakage.

Pleistocene hydrology of North America: The role of ice sheets in reorganizing groundwater flow systems

NASA Astrophysics Data System (ADS)

Person, Mark; McIntosh, Jennifer; Bense, Victor; Remenda, V. H.

2007-09-01

While the geomorphic consequences of Pleistocene megafloods have been known for some time, it has been only in the past 2 decades that hydrogeologists and glaciologists alike have begun to appreciate the important impact that ice sheet-aquifer interactions have had in controlling subsurface flow patterns, recharge rates, and the distribution of fresh water in confined aquifer systems across North America. In this paper, we document the numerous lines of geochemical, isotopic, and geomechanical evidence of ice sheet hydrogeology across North America. We also review the mechanical, thermal, and hydrologic processes that control subsurface fluid migration beneath ice sheets. Finite element models of subsurface fluid flow, permafrost formation, and ice sheet loading are presented to investigate the coupled nature of transport processes during glaciation/deglaciation. These indicate that recharge rates as high as 10 times modern values occurred as the Laurentide Ice Sheet overran the margins of sedimentary basins. The effects of ice sheet loading and permafrost formation result in complex transient flow patterns within aquifers and confining units alike. Using geochemical and environmental isotopic data, we estimate that the volume of glacial meltwater emplaced at the margins of sedimentary basins overrun by the Laurentide Ice Sheet totals about 3.7 × 104 km3, which is about 0.2% of the volume of the Laurentide Ice Sheet. Subglacial infiltration estimates based on continental-scale hydrologic models are even higher (5-10% of meltwater generated). These studies in sum call into question the widely held notion that groundwater flow patterns within confined aquifer systems are controlled primarily by the water table configuration during the Pleistocene. Rather, groundwater flow patterns were likely much more complex and transient in nature than has previously been thought. Because Pleistocene recharge rates are believed to be highly variable, these studies have profound implications for water resource managers charged with determining sustainable pumping rates from confined aquifers that host ice sheet meltwater.

Export fluxes of geochemical solutes in the meltwater stream of Sutri Dhaka Glacier, Chandra basin, Western Himalaya.

PubMed

Singh, Ajit T; Laluraj, C M; Sharma, Parmanand; Patel, Lavkush K; Thamban, Meloth

2017-10-12

The hydrochemistry of meltwater from the Sutri Dhaka Glacier, Western Himalaya, has been studied to understand the influence of the factors controlling the weathering processes of the glaciers during the peak ablation period. The high solar irradiance prompted intense melting, which has raised the stream flow of the glacier. The meltwater has been observed as slightly alkaline (mean pH 8.2) and contains the major anions (HCO 3 -  > SO 4 2-  > NO 3 -  > Cl - ) and cations (Ca 2+  > Mg 2+  > K +  > Na +  > NH 4 + ) with Ca 2+ (78.5%) and HCO 3 - (74.5%) as the dominant species. The piper diagram indicates the category of stream meltwater as Ca 2+ -HCO 3 - type. In addition, it is evident from the Gibbs diagram that the interaction between the meltwater and bedrock controls the ionic concentrations of the glacial meltwater. The high ratio value (~ 0.75) of HCO 3 - /(HCO 3 -  + SO 4 2- ) indicates that the carbonate weathering is dominant. Fe and Al followed by Mn, Sr, and Ti are the most dominant trace elements present in the meltwater. The significant negative correlation exhibited by the major ions and Sr with the discharge is recommended for the enrichment of these solutes during the lean discharge periods. However, the insignificant correlation of Fe, Al, Mn, and Ti with discharge suggests their physicochemical control. The principal component analysis (PCA) carried has highlighted three dominant composites, i.e., the water-rock interaction, atmospheric dust inputs, and physicochemical changes in the meltwater. Hence, the present study elucidates the export of geochemical solutes from Sutri Dhaka Glacier and factors governing the water chemistry, which helps in the better understanding of hydrochemical processes of the Himalayan glaciers and substantial improvement of our understanding about the glacio-hydrological environments and their response in the scenario of global warming.

The U.S. geological survey rass-statpac system for management and statistical reduction of geochemical data

USGS Publications Warehouse

VanTrump, G.; Miesch, A.T.

1977-01-01

RASS is an acronym for Rock Analysis Storage System and STATPAC, for Statistical Package. The RASS and STATPAC computer programs are integrated into the RASS-STATPAC system for the management and statistical reduction of geochemical data. The system, in its present form, has been in use for more than 9 yr by scores of U.S. Geological Survey geologists, geochemists, and other scientists engaged in a broad range of geologic and geochemical investigations. The principal advantage of the system is the flexibility afforded the user both in data searches and retrievals and in the manner of statistical treatment of data. The statistical programs provide for most types of statistical reduction normally used in geochemistry and petrology, but also contain bridges to other program systems for statistical processing and automatic plotting. ?? 1977.

Numerical Modeling of Arsenic Mobility during Reductive Iron-Mineral Transformations.

PubMed

Rawson, Joey; Prommer, Henning; Siade, Adam; Carr, Jackson; Berg, Michael; Davis, James A; Fendorf, Scott

2016-03-01

Millions of individuals worldwide are chronically exposed to hazardous concentrations of arsenic from contaminated drinking water. Despite massive efforts toward understanding the extent and underlying geochemical processes of the problem, numerical modeling and reliable predictions of future arsenic behavior remain a significant challenge. One of the key knowledge gaps concerns a refined understanding of the mechanisms that underlie arsenic mobilization, particularly under the onset of anaerobic conditions, and the quantification of the factors that affect this process. In this study, we focus on the development and testing of appropriate conceptual and numerical model approaches to represent and quantify the reductive dissolution of iron oxides, the concomitant release of sorbed arsenic, and the role of iron-mineral transformations. The initial model development in this study was guided by data and hypothesized processes from a previously reported,1 well-controlled column experiment in which arsenic desorption from ferrihydrite coated sands by variable loads of organic carbon was investigated. Using the measured data as constraints, we provide a quantitative interpretation of the processes controlling arsenic mobility during the microbial reductive transformation of iron oxides. Our analysis suggests that the observed arsenic behavior is primarily controlled by a combination of reductive dissolution of ferrihydrite, arsenic incorporation into or co-precipitation with freshly transformed iron minerals, and partial arsenic redox transformations.

Lead Isotope Compositions of Acid Residues from Olivine-Phyric Shergottite Tissint: Implications for Heterogeneous Shergottite Source Reservoirs

NASA Technical Reports Server (NTRS)

Moriwaki, R.; Usui, T.; Yokoyama, T.; Simon, J. I.; Jones, J. H.

2015-01-01

Geochemical studies of shergottites suggest that their parental magmas reflect mixtures between at least two distinct geochemical source reservoirs, producing correlations between radiogenic isotope compositions and trace element abundances. These correlations have been interpreted as indicating the presence of a reduced, incompatible element- depleted reservoir and an oxidized, incompatible- element-enriched reservoir. The former is clearly a depleted mantle source, but there is ongoing debate regarding the origin of the enriched reservoir. Two contrasting models have been proposed regarding the location and mixing process of the two geochemical source reservoirs: (1) assimilation of oxidized crust by mantle derived, reduced magmas, or (2) mixing of two distinct mantle reservoirs during melting. The former requires the ancient Martian crust to be the enriched source (crustal assimilation), whereas the latter requires isolation of a long-lived enriched mantle domain that probably originated from residual melts formed during solidification of a magma ocean (heterogeneous mantle model). This study conducts Pb isotope and trace element concentration analyses of sequential acid-leaching fractions (leachates and the final residues) from the geochemically depleted olivine-phyric shergottite Tissint. The results suggest that the Tissint magma is not isotopically uniform and sampled at least two geochemical source reservoirs, implying that either crustal assimilation or magma mixing would have played a role in the Tissint petrogenesis.

A batch sliding window method for local singularity mapping and its application for geochemical anomaly identification

NASA Astrophysics Data System (ADS)

Xiao, Fan; Chen, Zhijun; Chen, Jianguo; Zhou, Yongzhang

2016-05-01

In this study, a novel batch sliding window (BSW) based singularity mapping approach was proposed. Compared to the traditional sliding window (SW) technique with disadvantages of the empirical predetermination of a fixed maximum window size and outliers sensitivity of least-squares (LS) linear regression method, the BSW based singularity mapping approach can automatically determine the optimal size of the largest window for each estimated position, and utilizes robust linear regression (RLR) which is insensitive to outlier values. In the case study, tin geochemical data in Gejiu, Yunnan, have been processed by BSW based singularity mapping approach. The results show that the BSW approach can improve the accuracy of the calculation of singularity exponent values due to the determination of the optimal maximum window size. The utilization of RLR method in the BSW approach can smoothen the distribution of singularity index values with few or even without much high fluctuate values looking like noise points that usually make a singularity map much roughly and discontinuously. Furthermore, the student's t-statistic diagram indicates a strong spatial correlation between high geochemical anomaly and known tin polymetallic deposits. The target areas within high tin geochemical anomaly could probably have much higher potential for the exploration of new tin polymetallic deposits than other areas, particularly for the areas that show strong tin geochemical anomalies whereas no tin polymetallic deposits have been found in them.

Uranium plume persistence impacted by hydrologic and geochemical heterogeneity in the groundwater and river water interaction zone of Hanford site

NASA Astrophysics Data System (ADS)

Chen, X.; Zachara, J. M.; Vermeul, V. R.; Freshley, M.; Hammond, G. E.

2015-12-01

The behavior of a persistent uranium plume in an extended groundwater- river water (GW-SW) interaction zone at the DOE Hanford site is dominantly controlled by river stage fluctuations in the adjacent Columbia River. The plume behavior is further complicated by substantial heterogeneity in physical and geochemical properties of the host aquifer sediments. Multi-scale field and laboratory experiments and reactive transport modeling were integrated to understand the complex plume behavior influenced by highly variable hydrologic and geochemical conditions in time and space. In this presentation we (1) describe multiple data sets from field-scale uranium adsorption and desorption experiments performed at our experimental well-field, (2) develop a reactive transport model that incorporates hydrologic and geochemical heterogeneities characterized from multi-scale and multi-type datasets and a surface complexation reaction network based on laboratory studies, and (3) compare the modeling and observation results to provide insights on how to refine the conceptual model and reduce prediction uncertainties. The experimental results revealed significant spatial variability in uranium adsorption/desorption behavior, while modeling demonstrated that ambient hydrologic and geochemical conditions and heterogeneities in sediment physical and chemical properties both contributed to complex plume behavior and its persistence. Our analysis provides important insights into the characterization, understanding, modeling, and remediation of groundwater contaminant plumes influenced by surface water and groundwater interactions.

First Principle Estimation of Geochemically Important Transition Metal Oxide Properties: Structure and Dynamics of the Bulk, Surface and Mineral/Aqueous Fluid Interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Ying; Bylaska, Eric J.; Weare, John H.

Reactions in the mineral surface/reservoir fluid interface control many geochemical processes such as the dissolution and growth of minerals (Yanina and Rosso 2008), heterogeneous oxidation/reduction (Hochella 1990, Brown 2001, Hochella, Lower et al. 2008, Navrotsky, Mazeina et al. 2008), and inorganic respiration (Newman 2010). Key minerals involved in these processes are the transition metal oxides and oxyhydroxides (e.g., hematite, Fe2O3, and goethite, FeOOH)(Brown, Henrich et al. 1999, Brown 2001, Hochella, Lower et al. 2008, Navrotsky, Mazeina et al. 2008). To interpret and predict these processes, it is necessary to have a high level of understanding of the interactions between themore » formations containing these minerals and their reservoir fluids. However, these are complicated chemical events occurring under a wide range of T, P, and X conditions and the interpretation is complicated by the highly heterogeneous nature of natural environments (Hochella 1990, Hochella, Lower et al. 2008, Navrotsky, Mazeina et al. 2008) and the electronic and structural complexity of the oxide materials involved(Cox 1992, Kotliar and Vollhardt 2004, Navrotsky, Mazeina et al. 2008). In addition, also because of the complexity of the minerals involved and the heterogeneous nature of natural systems, the direct observation of these reactions at the atomic level is experimentally extremely difficult. Theoretical simulations will provide important support for analysis of the geochemistry of the mineral surface/fluid region as well as provide essential tools to extrapolate laboratory measurements to the field environment.« less

Mineralogical determination and geo-chemical modeling of chromium release from AOD slag: Distribution and leachability aspects.

PubMed

Li, Junguo; Liu, Bao; Zeng, Yanan; Wang, Ziming

2017-01-01

AOD (argon oxygen decarburization) slag, which is the by-product of the stainless steel refining process, is a recyclable slag because of its high content of calcium and silicon. The leaching toxicity cannot be ignored in the recycling process because the slag contains a certain amount of Cr. In this study, the mineral analysis, batch leaching tests and thermodynamic and kinetic modeling by PHREEQC combined with FactSage software were performed to explore the influence of the dissolution of primary minerals and the precipitation of secondary minerals on the elution of Cr from AOD slag. The results indicated that the main minerals in the original AOD slag are larnite, merwinite, pyroxene and periclase. Cr was dispersed in the mineral phases mentioned above. The simulation of Cr leaching controlled by Cr(III)-hydroxide corresponded better to the batch leaching tests, while the Cr leaching controlled by chromite or double control was underestimated. Increasing the L/S ratio enhances the pH of the leachate and restrains the elution of Cr from the AOD slag. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geochemistry of subduction zone serpentinites: A review

NASA Astrophysics Data System (ADS)

Deschamps, Fabien; Godard, Marguerite; Guillot, Stéphane; Hattori, Kéiko

2013-09-01

Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zone geodynamics. Their presence and role in subduction environments are recognized through geophysical, geochemical and field observations of modern and ancient subduction zones and large amounts of geochemical database of serpentinites have been created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical data of abyssal, mantle wedge and exhumed serpentinites after subduction. The aim was to better understand the geochemical evolution of these rocks during their subduction as well as their impact in the global geochemical cycle. When studying serpentinites, it is essential to determine their protoliths and their geological history before serpentinization. The geochemical data of serpentinites shows little mobility of compatible and rare earth elements (REE) at the scale of hand-specimen during their serpentinization. Thus, REE abundance can be used to identify the protolith for serpentinites, as well as magmatic processes such as melt/rock interactions before serpentinization. In the case of subducted serpentinites, the interpretation of trace element data is difficult due to the enrichments of light REE, independent of the nature of the protolith. We propose that enrichments are probably not related to serpentinization itself, but mostly due to (sedimentary-derived) fluid/rock interactions within the subduction channel after the serpentinization. It is also possible that the enrichment reflects the geochemical signature of the mantle protolith itself which could derive from the less refractory continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous analyses have been carried out, notably using in situ approaches, to better constrain the behavior of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) incorporated in serpentine phases. The abundance of these elements provides information related to the fluid/rock interactions during serpentinization and the behavior of FME, from their incorporation to their gradual release during subduction. Serpentinites are considered as a reservoir of the FME in subduction zones and their role, notably on arc magma composition, is underestimated presently in the global geochemical cycle.

Archean cherts: field, petrographic and geochemical criteria to determine their origin

NASA Astrophysics Data System (ADS)

Ledevin, Morgane; Arndt, Nicholas T.; Simionovici, Alexandre

2013-04-01

Archean cherts provide valuable information about conditions on the sea floor during the early history of Earth. We conducted field, petrological and geochemical studies on examples from different environments in the Barberton Greenstone Belt (3.2-3.5 Ga), South Africa, with the aim of improving our understanding of these enigmatic rocks. We distinguish three different origins for cherts: direct precipitation from seawater (C-cherts); precipitation in fractures from silica-rich fluids (F-cherts); and replacement of preexisting rocks (silicification) either at or near the surface (S-cherts). The three types were distinguished using a combination of sedimentary and deformation structures, petrological observations (RAMAN, electron microprobe, X-Ray microfluorescence, cathodoluminescence) and geochemical data. C-cherts best record the composition and physical conditions in primitive oceans and the depositional environment because they precipitated from seawater. Based on sedimentary structures, we show that the silica was deposited as a siliceous ooze or amorphous gel on the seafloor, with variable precipitation rates that depend on the amount and nature of co-precipitated phases (called here the "contaminant"), such as detrital grains, carbonates, carbonaceous matter and oxides. We observe a complex rheology of C-cherts, which show both ductile to brittle deformation structures, sometimes in the same layer. We infer that the cherts underwent extremely rapid diagenetic induration at or near the surface, a process that proceeded faster when contaminants are lacking. Geochemical data (ICP-MS/ICP-AES) indicate that whole rock chemistries are dominated by the contaminant phases. Detrital grains with continental signatures dominate the compositions of cherts in the turbidite sequence of the Komati River whereas carbonates preserving modern, seawater-like compositions control the compositions of cherts of Fig Tree Fm in the Barite Valley. The silica minerals do not contribute significantly to the trace-element composition, but acts as a diluent. Buck Reef cherts have extremely low contents of most trace elements due to low contents of detrital minerals and carbonates. S-cherts result from the silicification of preexisting rocks: under the action of circulating fluids, primary minerals are replaced by silica minerals and the porosity of the protolith is significantly reduced. Such process occurs even at the surface and persist downward the sedimentary units until after the rocks are indurated. F-cherts were observed in the Barite Valley, where chert dykes cross-cut surrounding units at high angle. The fractures often display jigsaw-puzzle textures, suggesting hydraulic fracturation, and their near-vertical orientation points to emplacement at shallow levels in the sediment pile. The dykes are filled with a black chert that contains variable amounts of host rock fragments that vary in shape (angular to rounded) and size (dm to µm). They control the whole-rock chemistry of cherts, and obscure the chemical composition of the primary, precipitating fluid. We believe that this fluid had a thixotropic behavior, i.e. it was fluid enough during the intrusion to fill very fine <1mm fractures but viscous enough when the velocity decreased to suspend decimetric host rock fragments. Based on our observations, we conclude that (1) field and petrological studies are more reliable than geochemical analyses for the recognition of various chert types; (2) the composition of cherts strongly depends on the type and amount of mineral phases other than silica, especially clays and carbonates; (3) C-cherts might be more abundant than previously thought and deposited as an amorphous, siliceous gel onto the seafloor before being rapidly indurated.

Discriminating sediment archives and sedimentary processes in the arid endorheic Ejina Basin, NW China using a robust geochemical approach

NASA Astrophysics Data System (ADS)

Yu, Kaifeng; Hartmann, Kai; Nottebaum, Veit; Stauch, Georg; Lu, Huayu; Zeeden, Christian; Yi, Shuangwen; Wünnemann, Bernd; Lehmkuhl, Frank

2016-04-01

Geochemical characteristics have been intensively used to assign sediment properties to paleoclimate and provenance. Nonetheless, in particular concerning the arid context, bulk geochemistry of different sediment archives and corresponding process interpretations are hitherto elusive. The Ejina Basin, with its suite of different sediment archives, is known as one of the main sources for the loess accumulation on the Chinese Loess Plateau. In order to understand mechanisms along this supra-regional sediment cascade, it is crucial to decipher the archive characteristics and formation processes. To address these issues, five profiles in different geomorphological contexts were selected. Analyses of X-ray fluorescence and diffraction, grain size, optically stimulated luminescence and radiocarbon dating were performed. Robust factor analysis was applied to reduce the attribute space to the process space of sedimentation history. Five sediment archives from three lithologic units exhibit geochemical characteristics as follows: (i) aeolian sands have high contents of Zr and Hf, whereas only Hf can be regarded as a valuable indicator to discriminate the coarse sand proportion; (ii) sandy loess has high Ca and Sr contents which both exhibit broad correlations with the medium to coarse silt proportions; (iii) lacustrine clays have high contents of felsic, ferromagnesian and mica source elements e.g., K, Fe, Ti, V, and Ni; (iv) fluvial sands have high contents of Mg, Cl and Na which may be enriched in evaporite minerals; (v) alluvial gravels have high contents of Cr which may originate from nearby Cr-rich bedrock. Temporal variations can be illustrated by four robust factors: weathering intensity, silicate-bearing mineral abundance, saline/alkaline magnitude and quasi-constant aeolian input. In summary, the bulk-composition of the late Quaternary sediments in this arid context is governed by the nature of the source terrain, weak chemical weathering, authigenic minerals, aeolian sand input, whereas pedogenesis and diagenesis exert only limited influences. Hence, this study demonstrates a practical geochemical strategy supplemented by grain size and mineralogical data, to discriminate sediment archives and thereafter enhance our ability to offer more intriguing information about the sedimentary processes in the arid central Asia.

Horizontal insulating barriers as a way to protect groundwater

NASA Astrophysics Data System (ADS)

Cicha-Szot, Renata; Labus, Krzysztof; Falkowicz, Sławomir; Madetko, Norbert

2018-06-01

Trenchless Technology of Forming Horizontal Insulating Barriers (TFHB) can be considered a method of groundwater protection against inflow of pollutants. In TFHB technology, the working fluid (sodium silicate solution) and the gelling agent (CO2) are injected separately, using one tool, to different zones of the aquifer profile. Carbon dioxide injected into the saturation zone rises due to buoyancy forces and reaches the silicate which was injected at the water table level. This initiates the process of silicate gelation, resulting in the formation of an insulating barrier. For technological purposes, the gelation time must be controlled, and the resulting gel must have certain mechanical properties. In order to apply THFB in real conditions it was necessary to identify important technological and technical parameters, as well as to define interactions between the injected fluid and the aquifer rocks. Geochemical modelling (equilibrium, reaction path and reactive transport) was used to identify potential geochemical effects of the application of TFHB in sandy aquifers. Certain petrophysical parameters and mineralogical assemblages of aquifers were addressed, taking into account both low and strongly mineralized groundwater. The simulations revealed that TFHB does not have a negative impact on the chemistry of rock-water systems described in this work.

Seasonal Hydrologic Controls on Uranium and Iron Biogeochemistry in a Riparian Aquifer

NASA Astrophysics Data System (ADS)

Wilkins, M.; Williams, K. H.; Danczak, R. E.; Yabusaki, S.; Fang, Y.; Hobson, C.

2015-12-01

The maintenance of geochemically reducing conditions is generally optimal for the formation and preservation of reduced metals and mineral phases that can limit contaminant fate and transport. At a riparian aquifer near Rifle, CO, we tracked over six months the biogeochemical response within the aquifer to an annual pulse of dissolved oxygen (DO) that results from snowmelt-driven changes in Colorado River stage. In reduced portions of the aquifer (naturally reduced zones; NRZs) the re-oxidation of abundant iron sulfide minerals was the dominant oxygen-consuming process, and resulted in little DO intrusion into the deeper aquifer. In less reduced areas, DO intruded through the entire vertical profile of the aquifer. Across both regions, these perturbations resulted in changes to the microbial community structure, and aqueous metal pools. Two potentially different mechanisms of uranium mobilization were observed; (1) re-oxidation of reduced U(IV) phases in response to DO intrusion, and (2) mobilization of U(VI) from the vadose zone during water table rise. This high-resolution, long-term monitoring of aquifer biogeochemistry at the Rifle site has revealed dynamic microbial and geochemical responses to predictable, annual hydrologic perturbations, and offers an opportunity to further refine modeling approaches for such regions.

Exploration computer applications to primary dispersion halos: Kougarok tin prospect, Seward Peninsula, Alaska, USA

USGS Publications Warehouse

Reid, Jeffrey C.

1989-01-01

Computer processing and high resolution graphics display of geochemical data were used to quickly, accurately, and efficiently obtain important decision-making information for tin (cassiterite) exploration, Seward Peninsula, Alaska (USA). Primary geochemical dispersion patterns were determined for tin-bearing intrusive granite phases of Late Cretaceous age with exploration bedrock lithogeochemistry at the Kougarok tin prospect. Expensive diamond drilling footage was required to reach exploration objectives. Recognition of element distribution and dispersion patterns was useful in subsurface interpretation and correlation, and to aid location of other holes.

Geochemical and hydrologic controls on phosphorus transport in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts

USGS Publications Warehouse

Walter, Donald A.; Rea, Brigid A.; Stollenwerk, Kenneth G.; Savoie, Jennifer G.

1996-01-01

Currently (1993), about 170 kg/yr of phosphorus discharges into Ashumet Pond on Cape Cod from a plume of sewage-contaminated ground water. Phosphorus in the plume is mobile in two distinct geochemical environments--an anoxic zone containing dissolved iron and a suboxic zone containing dissolved oxygen. Phosphorus mobility in the suboxic zone is due to saturation of available sorption sites. Phosphorus loading to Ashumet Pond may increase significantly after sewage disposal is stopped due to phosphorus desorption from sediment surfaces.

A Centimeter-Scale Investigation of Geochemical Hotspots in a Soil Lysimeter

NASA Astrophysics Data System (ADS)

Umanzor, M.; Wang, Y.; Dontsova, K.; Chorover, J.; Troch, P. A. A.

2016-12-01

Studying the co-evolution of hydrological and biogeochemical processes in the subsurface of natural landscapes can enhance the understanding of coupled Earth-system processes. Such knowledge is imperative for improving predictions of hydro-biogeochemical cycles, especially under climate change scenarios. Hotspots may form in porous media that is undergoing biogeochemical weathering at locations where reactants accumulate to threshold values along hydrologic flow paths. This is expected to occur in weatherable silicate media, like granular basalt. To examine such processes during incipient soil formation, we constructed a sloping weighing lysimeter 2-m in length, 0.5-m in width and 1-m in depth. Mini-LEO was filled with crushed granular basalt rock with a known initial chemical composition. After 18 months of irrigation and intensive hydrological study, the model "landscape" was divided into a 3D matrix of 324 voxels and excavated. Collected samples were subjected to detailed hydro-bio-geochemical analysis to assess the formation of geochemical heterogeneity. A five-step sequential extraction was employed to characterize incongruent mineral weathering, and its relation to the spatial distribution of microbial composition (in a related study). The changes in Fe and Mn concentration and speciation along the lysimeter length and depth (as measured by each step of the sequential extraction) was quantified to characterize spatial distribution of weathering processes. Results are being used to assist in understanding not only spatial and temporal distribution of basalt weathering on the slope, but also, connections between hydrological and biogeochemical cycles that lead to formation of hotspots.

Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks

DOE PAGES

Garcia del Real, Pablo; Maher, Kate; Kluge, Tobias; ...

2016-08-19

Here, magnesium carbonate minerals produced by reaction of H 2O–CO 2 with ultramafic rocks occur in a wide range of paragenetic and tectonic settings and can thus provide insights into a variety of geologic processes, including deposition of ore-grade, massive-vein cryptocrystalline magnesite; formation of hydrous magnesium carbonates in weathering environments; and metamorphic carbonate alteration of ultramafic rocks. However, the application of traditional geochemical and isotopic methods to infer temperatures of mineralization, the nature of mineralizing fluids, and the mechanisms controlling the transformation of dissolved CO 2 into magnesium carbonates in these settings is difficult because the fluids are usually notmore » preserved.« less

Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garcia del Real, Pablo; Maher, Kate; Kluge, Tobias

Here, magnesium carbonate minerals produced by reaction of H 2O–CO 2 with ultramafic rocks occur in a wide range of paragenetic and tectonic settings and can thus provide insights into a variety of geologic processes, including deposition of ore-grade, massive-vein cryptocrystalline magnesite; formation of hydrous magnesium carbonates in weathering environments; and metamorphic carbonate alteration of ultramafic rocks. However, the application of traditional geochemical and isotopic methods to infer temperatures of mineralization, the nature of mineralizing fluids, and the mechanisms controlling the transformation of dissolved CO 2 into magnesium carbonates in these settings is difficult because the fluids are usually notmore » preserved.« less

Controls on O2 Production in Cyanobacterial Mats and Implications for Earth's Oxygenation

NASA Astrophysics Data System (ADS)

Dick, Gregory J.; Grim, Sharon L.; Klatt, Judith M.

2018-05-01

Cyanobacterial mats are widely assumed to have been globally significant hot spots of biogeochemistry and evolution during the Archean and Proterozoic, but little is known about their quantitative contributions to global primary productivity or Earth's oxygenation. Modern systems show that mat biogeochemistry is the outcome of concerted activities and intimate interactions between various microbial metabolisms. Emerging knowledge of the regulation of oxygenic and sulfide-driven anoxygenic photosynthesis by versatile cyanobacteria, and their interactions with sulfur-oxidizing bacteria and sulfate-reducing bacteria, highlights how ecological and geochemical processes can control O2 production in cyanobacterial mats in unexpected ways. This review explores such biological controls on O2 production. We argue that the intertwined effects of light availability, redox geochemistry, regulation and competition of microbial metabolisms, and biogeochemical feedbacks result in emergent properties of cyanobacterial mat communities that are all critical yet largely overlooked mechanisms to potentially explain the protracted nature of Earth's oxygenation.

Current State of an Intelligent System to Aid in Tephra Layer Correlation

NASA Astrophysics Data System (ADS)

Hanson-Hedgecock, S.; Bursik, M.; Rogova, G.

2007-12-01

We are developing a computer based intelligent system to correlate tephra layers by using the lithologic, mineralogic, and geochemical characteristics of field samples, to aid geologists in interpreting eruption patterns of volcanic chains and fields. The intelligent system is used to define groups of tephra source vents by utilizing geochemical data, and to correlate tephra layers based on lithostratigraphic characteristics. Understanding the eruption history of a volcano from stratigraphic studies is important for forecasting future eruptive behavior and hazards. In volcanic chains and fields with a complex eruptive history and no central vent, determining the spatio- temporal eruption patterns is difficult. Sedimentologic and chemical variability, and sparse sampling often result in relatively large variances and imprecision in the dataset. Lithostratigraphic and geochemical interpretation also depends on ones' level of expertise and can be subjective. The processing of lithostratigraphic features is conducted by a hybrid classifier, composed of supervised artificial neural networks (ANNs) combined within the framework of the Dempster-Shafer theory of evidence. Since lithostratigraphic features vary with distance from source, hypothetical vent locations are determined by using expert domain knowledge and geostatistical methods. Geochemical data are processed by a suit of fuzzy k- means classifiers. Each fuzzy k-means classifier assigns observations to multiple clusters with various degrees, called membership coefficients. The assignment minimizes a function of the total distance between the centers of clusters and the individual geochemical data patterns weighed by the membership coefficients. Improved clustering results of geochemical data are achieved by the fusion of individual clustering results with an evidential combination method. Lithostratigraphic data from individual tephra beds of the North Mono eruption sequence are used to test the effectiveness of the intelligent system for tephra layer correlation. Geochemical data from tephra bedsets of the Mono and Inyo Craters, CA, are used to test the effectiveness of the intelligent system for eruption sequence correlation. The intelligent system aids correlation by showing matches and disparities between data patterns from different outcrops that may have been overlooked in initial interpretations. Initial results show that the lithostratigraphic classifier is able to accurately differentiate known layers 76% of the time. Output from the lithostratigraphic classifier can furthermore be plotted directly as isopleth maps that can aid in rapid recognition of tephra layers as well as determination of eruption characteristics, e.g. eruption volume, plume height, etc. The intelligent system produces a useful recognition result, while dealing with the uncertainty from sparse data and the imprecise description of layer characteristics.

Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field-Scale Subsurface Research Challenge Site at Rifle, Colorado, Quality Assurance Project Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fix, N. J.

The U.S. Department of Energy (DOE) is cleaning up and/or monitoring large, dilute plumes contaminated by metals, such as uranium and chromium, whose mobility and solubility change with redox status. Field-scale experiments with acetate as the electron donor have stimulated metal-reducing bacteria to effectively remove uranium [U(VI)] from groundwater at the Uranium Mill Tailings Site in Rifle, Colorado. The Pacific Northwest National Laboratory and a multidisciplinary team of national laboratory and academic collaborators has embarked on a research proposed for the Rifle site, the object of which is to gain a comprehensive and mechanistic understanding of the microbial factors andmore » associated geochemistry controlling uranium mobility so that DOE can confidently remediate uranium plumes as well as support stewardship of uranium-contaminated sites. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Rifle Integrated Field-Scale Subsurface Research Challenge Project.« less

A Geological Model for the Evolution of Early Continents (Invited)

NASA Astrophysics Data System (ADS)

Rey, P. F.; Coltice, N.; Flament, N. E.; Thébaud, N.

2013-12-01

Geochemical probing of ancient sediments (REE in black shales, strontium composition of carbonates, oxygen isotopes in zircons...) suggests that continents were a late Archean addition at Earth's surface. Yet, geochemical probing of ancient basalts reveals that they were extracted from a mantle depleted of its crustal elements early in the Archean. Considerations on surface geology, the early Earth hypsometry and the rheology and density structure of Archean continents can help solve this paradox. Surface geology: The surface geology of Archean cratons is characterized by thick continental flood basalts (CFBs, including greenstones) emplaced on felsic crusts dominated by Trondhjemite-Tonalite-Granodiorite (TTG) granitoids. This simple geology is peculiar because i/ most CFBs were emplaced below sea level, ii/ after their emplacement, CFBs were deformed into relatively narrow, curviplanar belts (greenstone basins) wrapping around migmatitic TTG domes, and iii/ Archean greenstone belts are richly endowed with gold and other metals deposits. Flat Earth hypothesis: From considerations on early Earth continental geotherm and density structure, Rey and Coltice (2008) propose that, because of the increased ability of the lithosphere to flow laterally, orogenic processes in the Archean produced only subdued topography (

Effects of Land-Use Change and Managed Aquifer Recharge on Geochemical Reactions with Implications for Groundwater Quantity and Quality in Atoll Island Aquifers, Roi-Namur, Republic of the Marshall Islands

NASA Astrophysics Data System (ADS)

Hejazian, M.; Swarzenski, P. W.; Gurdak, J. J.; Odigie, K. O.; Storlazzi, C. D.

2015-12-01

This study compares the hydrogeochemistry of two contrasting atoll groundwater systems in Roi-Namur, Republic of the Marshall Islands. Roi-Namur houses a U.S. Department of Defense military installation and presents an ideal study location where a human impacted aquifer is co-located next to a natural aquifer as part of two artificially conjoined atoll islands. The hydrogeology and geochemistry of carbonate atoll aquifers has been well studied, particularly because of its small, well-defined hydrologic system that allows for relatively precise modeling. However, it is unknown how changes in land-use/land cover and managed aquifer recharge (MAR) alters natural geochemical processes in atoll aquifers. A better understanding of this has implications on groundwater quantity and quality, carbonate dissolution, and best aquifer management practices in the context of rising sea level and saltwater intrusion. Roi has been heavily modified to house military and civilian operations; here, lack of vegetation and managed recharge has increased the volume of potable groundwater and affected the geochemical processes in the freshwater lens and saltwater transition zone. Namur is heavily vegetated and the hydrogeology is indicative of a natural atoll island. A suite of monitoring wells were sampled across both island settings for major ions, nutrients, trace elements, DOC/DIC, δ13C and δ18O/2H isotopes. By modeling geochemical reactions using a conservative mixing approach, we measure deviations from expected reactions and compare the two contrasting settings using derived geochemical profiles through a wide salinity spectrum. Results indicate that groundwater on Namur is more heavily depleted in δ13C and has greater dissolved inorganic carbon, suggesting higher microbial oxidation and greater dissolution within the carbonate aquifer. This suggests MAR and reduction of vegetation makes the groundwater supply on atoll islands more resilient to sea level rise.

The use of decision tree induction and artificial neural networks for recognizing the geochemical distribution patterns of LREE in the Choghart deposit, Central Iran

NASA Astrophysics Data System (ADS)

Zaremotlagh, S.; Hezarkhani, A.

2017-04-01

Some evidences of rare earth elements (REE) concentrations are found in iron oxide-apatite (IOA) deposits which are located in Central Iranian microcontinent. There are many unsolved problems about the origin and metallogenesis of IOA deposits in this district. Although it is considered that felsic magmatism and mineralization were simultaneous in the district, interaction of multi-stage hydrothermal-magmatic processes within the Early Cambrian volcano-sedimentary sequence probably caused some epigenetic mineralizations. Secondary geological processes (e.g., multi-stage mineralization, alteration, and weathering) have affected on variations of major elements and possible redistribution of REE in IOA deposits. Hence, the geochemical behaviors and distribution patterns of REE are expected to be complicated in different zones of these deposits. The aim of this paper is recognizing LREE distribution patterns based on whole-rock chemical compositions and automatic discovery of their geochemical rules. For this purpose, the pattern recognition techniques including decision tree and neural network were applied on a high-dimensional geochemical dataset from Choghart IOA deposit. Because some data features were irrelevant or redundant in recognizing the distribution patterns of each LREE, a greedy attribute subset selection technique was employed to select the best subset of predictors used in classification tasks. The decision trees (CART algorithm) were pruned optimally to more accurately categorize independent test data than unpruned ones. The most effective classification rules were extracted from the pruned tree to describe the meaningful relationships between the predictors and different concentrations of LREE. A feed-forward artificial neural network was also applied to reliably predict the influence of various rock compositions on the spatial distribution patterns of LREE with a better performance than the decision tree induction. The findings of this study could be effectively used to visualize the LREE distribution patterns as geochemical maps.

Baseline studies to select the most sound and sensitive sites to install continuous monitoring per sismo-geochemical networks. The case history of the Norcia-Amatrice-Spoleto seismic sequences (2016-2017)

NASA Astrophysics Data System (ADS)

Quattrocchi, F.; Gallo, F.

2017-12-01

The paper review methodologically and historically - in the frame of seismo-geochemical studies in Italy and abroad to select the most "sensitive" sites along active faults, mostly where structural geology is not able to discover "blind" faults or complex fault crossing systems, with maximum fluids-faults interaction. The paper is highlighting the "site specific" case histories and processes helping in networks design, gathered in occasion of strong-moderate earthquakes, gas-burst or groundwater evolution in geothermal-hydrocarbons field during EU projects (i.e., Geochemical Seismic Zonation, 3F-Faults-Fractures-Fluids Corinth). Some concepts are highlighted based on gather experimental data in 25 years: - if the network is in soil gas is necessary a preliminary study on groundwater too, to understand the sectors of shallow aquifers, as "buffer" bodies, more prone to be oversaturated by geogas from depth; a preliminary grid should consider both the CO2-CH4-Rn fluxes, all gas concentrations and isotopes analyses (TDIC, CH4 CO2 , rare gas) case by case described here, mostly where the regional faults are crossing each other and where a carrier gas is acting i.e., CO2. It is very un-correct to install mono-parametric stations, i.e. only Radon to understand the real WRI processes. - if the network is in groundwater is very important a preliminary study before, during and after seismic sequences, to realize where the maximum anomalies (i.e., anomalous animal behavior, temperature increasing, geochemical anomalies, new gas relase) are and will be envisaged, as found for the Umbria-Marche border (the Colfiorito 1997-1998 and the 2016-2017 Norcia-Amatrice seismic sequences), where a deep pore-pressure dominated situation could be constrained by seismo-geochemistry, along "still silent" close fault segments too. if the network is in groundwater is very important a geochemical multidisciplinary approach to constrain the segment length and relative maximum magnitude.

Characterizing Microbe-Environment Interactions Through Experimental Evolution: The Autonomous Adaptive Directed Evolution Chamber

NASA Astrophysics Data System (ADS)

Ibanez, C. R.; Blaich, J.; Owyang, S.; Storrs, A.; Moffet, A.; Wong, N.; Zhou, J.; Gentry, D.

2015-12-01

We are developing a laboratory system for studying micro- to meso-scale interactions between microorganisms and their physicochemical environments. The Autonomous Adaptive Directed Evolution Chamber (AADEC) cultures microorganisms in controlled,small-scale geochemical environments. It observes corresponding microbial interactions to these environments and has the ability to adjust thermal, chemical, and other parameters in real time in response to these interactions. In addition to the sensed data, the system allows the generation of time-resolved ecological, genomic, etc. samples on the order of microbial generations. The AADEC currently houses cultures in liquid media and controls UVC radiation, heat exposure, and nutrient supply. In a proof-of-concept experimental evolution application, it can increase UVC radiation resistance of Escherichia coli cultures by iteratively exposing them to UVC and allowing the surviving cells to regrow. A baseline characterization generated a million fold resistance increase. This demonstration uses a single-well growth chamber prototype, but it was limited by scalability. We have expanded upon this system by implementing a microwell plate compatible fluidics system and sensor housing. This microwell plate system increases the diversity of microbial interactions seen in response to the geochemical environments generated by the system, allowing greater control over individual cultures' environments and detection of rarer events. The custom microfluidic card matches the footprint of a standard microwell plate. This card enables controllable fluid flow between wells and introduces multiple separate exposure and sensor chambers, increasing the variety of sensors compatible with the system. This gives the device control over scale and the interconnectedness of environments within the system. The increased controllability of the multiwell system provides a platform for implementing machine learning algorithms that will autonomously adjust geochemical environmental parameters.

K, U, and Th behavior in Martian environmental conditions

NASA Technical Reports Server (NTRS)

Zolotov, M. YU.; Krot, T. V.; Moroz, L. V.

1993-01-01

The possibility of K, U, and Th content determination from orbit and in situ allows consideration of those elements as geochemical indicators in the planetary studies. In the case of Mars the unambiguous interpretations of such data in terms of igneous rocks are remarkably constrained by the widespread rock alteration and the existence of exogenic deposits. Besides, the terrestrial experience indicates that K, U, and Th contents could be used as indicators of environmental geochemical processes. Thus the determination of K, U, and Th contents in the Martian surface materials could provide the indirect data on the conditions of some exogenic geological processes. The speculations on the K, U, and Th behavior in the Martian environments show that aeolian and aqueous processes leads to the preferential accumulation of K, U, and Th in fine dust material. The separation of K, U, and Th on Mars is smaller in scale to that on Earth.

Use of dissolved H2 concentrations to determine distribution of microbially catalyzed redox reactions in anoxic groundwater

USGS Publications Warehouse

Lovley, D.R.; Chapelle, F.H.; Woodward, J.C.

1994-01-01

The potential for using concentrations of dissolved H2 to determine the distribution of redox processes in anoxic groundwaters was evaluated. In pristine aquifers in which standard geochemical measurements indicated that Fe-(III) reduction, sulfate reduction, or methanogenesis was the terminal electron accepting process (TEAP), the H2 concentrations were similar to the H2 concentrations that have previously been reported for aquatic sediments with the same TEAPs. In two aquifers contaminated with petroleum products, it was impossible with standard geochemical analyses to determine which TEAPs predominated in specific locations. However, the TEAPs predicted from measurements of dissolved H2 were the same as those determined directly through measurements of microbial processes in incubated aquifer material. These results suggest that H2 concentrations may be a useful tool for analyzing the redox chemistry of nonequilibrium groundwaters.

Fluid geochemistry of Fault zone hydrothermal system in the Yidun-Litang area, eastern Tibetan Plateau geothermal belt

NASA Astrophysics Data System (ADS)

Shi, Z.; Wang, G.

2017-12-01

Understanding the geochemical and geothermal characteristic of the hydrothermal systems provide useful information in appropriate evaluating the geothermal potential in this area. In this paper, we investigate the chemical and isotopic composition of thermal water in an underexploited geothermal belt, Yidun-Litang area, in eastern Tibetan Plateau geothermal belt. 24 hot springs from the Yidun and Litang area were collected and analyzed. The chemical facies of the hot springs are mainly Na-HCO3 type water. Water-rock interaction, cation exchange are the dominant hydrogeochemical processes in the hydrothermal evolution. All the hot springs show long-time water-rock interaction and significant 18O shift occurred in the Yindun area. Tritium data indicate the long-time water-rock interaction time in the hydrothermal system. According to the isotope and geochemical data, the hydrothermal systems in Yidun and Litang area may share a common deep parent geothermal liquid but receive different sources of meteoric precipitation and undergone different geochemical processes. The Yidun area have relative high reservoir equilibrium temperature (up to 230 °C) while the reservoir temperature at Litang area is relative low (up to 128 °C).

Multivariate analysis of the geochemistry and mineralogy of soils along two continental-scale transects in North America

USGS Publications Warehouse

Drew, L.J.; Grunsky, E.C.; Sutphin, D.M.; Woodruff, L.G.

2010-01-01

Soils collected in 2004 along two North American continental-scale transects were subjected to geochemical and mineralogical analyses. In previous interpretations of these analyses, data were expressed in weight percent and parts per million, and thus were subject to the effect of the constant-sum phenomenon. In a new approach to the data, this effect was removed by using centered log-ratio transformations to 'open' the mineralogical and geochemical arrays. Multivariate analyses, including principal component and linear discriminant analyses, of the centered log-ratio data reveal the effects of soil-forming processes, including soil parent material, weathering, and soil age, at the continental-scale of the data arrays that were not readily apparent in the more conventionally presented data. Linear discriminant analysis of the data arrays indicates that the majority of the soil samples collected along the transects can be more successfully classified with Level 1 ecological regional-scale classification by the soil geochemistry than soil mineralogy. A primary objective of this study is to discover and describe, in a parsimonious way, geochemical processes that are both independent and inter-dependent and manifested through compositional data including estimates of the elements and corresponding mineralogy. ?? 2010.

30 CFR 551.11 - Submission, inspection, and selection of geological data and information collected under a permit...

Code of Federal Regulations, 2014 CFR

2014-07-01

..., or interpretation of any geological data and information. Initial analysis and processing are the stages of analysis or processing where the data and information first become available for in-house... geochemical) data and information describing each operation of analysis, processing, and interpretation; (2...

30 CFR 551.11 - Submission, inspection, and selection of geological data and information collected under a permit...

Code of Federal Regulations, 2012 CFR

2012-07-01

..., or interpretation of any geological data and information. Initial analysis and processing are the stages of analysis or processing where the data and information first become available for in-house... geochemical) data and information describing each operation of analysis, processing, and interpretation; (2...

30 CFR 551.11 - Submission, inspection, and selection of geological data and information collected under a permit...

Code of Federal Regulations, 2013 CFR

2013-07-01

..., or interpretation of any geological data and information. Initial analysis and processing are the stages of analysis or processing where the data and information first become available for in-house... geochemical) data and information describing each operation of analysis, processing, and interpretation; (2...

Large-Scale In-situ Experiments to Determine Geochemical Alterations and Microbial Activities at the Geological Repository

NASA Astrophysics Data System (ADS)

Choung, S.; Francis, A. J.; Um, W.; Choi, S.; Kim, S.; Park, J.; Kim, S.

2013-12-01

The countries that have generated nuclear power have facing problems on the disposal of accumulated radioactive wastes. Geological disposal method has been chosen in many countries including Korea. A safety issue after the closure of geological repository has been raised, because microbial activities lead overpressure in the underground facilities through gas production. In particular, biodegradable organic materials derived from low- and intermediate-level radioactive wastes play important role on microbial activities in the geological repository. This study performed large scale in-situ experiments using organic wastes and groundwater, and investigated geochemical alteration and microbial activities at early stage (~63 days) as representative of the period, after closure of the geological repository. The geochemical alteration controlled significantly the microorganism types and populations. Database of the biogeochemical alteration facilitates prediction of radionuclides' mobility and establishment of remedial strategy against unpredictable accidents and hazards at early stage right after closure of the geological repository.

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

USGS Publications Warehouse

Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

1997-01-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post-1950s concentrations of 3H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.The water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface water. Chemical and isotopic analyses, tritium, and strontium-87/strontium-86 along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of groundwater. Differences in the composition of water isotopes in rainfall, groundwater and surface water were used to develop mixing models of surface water and groundwater. Even though mixing is likely between groundwater and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, showing little impact from trace elements present in surface waters.

THE FORMATION OF PB(IV) OXIDES IN CHLORINATED WATER

EPA Science Inventory

Recent research has shown that Pb(IV) oxides can play an important geochemical role in drinking water distribution systems. The basis of most guidance for lead control in drinking water, however, presumes that Pb(II) solids control lead solubility. Therefore, it is important that...

Manual hierarchical clustering of regional geochemical data using a Bayesian finite mixture model

USGS Publications Warehouse

Ellefsen, Karl J.; Smith, David

2016-01-01

Interpretation of regional scale, multivariate geochemical data is aided by a statistical technique called “clustering.” We investigate a particular clustering procedure by applying it to geochemical data collected in the State of Colorado, United States of America. The clustering procedure partitions the field samples for the entire survey area into two clusters. The field samples in each cluster are partitioned again to create two subclusters, and so on. This manual procedure generates a hierarchy of clusters, and the different levels of the hierarchy show geochemical and geological processes occurring at different spatial scales. Although there are many different clustering methods, we use Bayesian finite mixture modeling with two probability distributions, which yields two clusters. The model parameters are estimated with Hamiltonian Monte Carlo sampling of the posterior probability density function, which usually has multiple modes. Each mode has its own set of model parameters; each set is checked to ensure that it is consistent both with the data and with independent geologic knowledge. The set of model parameters that is most consistent with the independent geologic knowledge is selected for detailed interpretation and partitioning of the field samples.

Mineralogical and geochemical anomalous data of the K-T boundary samples

NASA Technical Reports Server (NTRS)

Miura, Y.; Shibya, G.; Imai, M.; Takaoka, N.; Saito, S.

1988-01-01

Cretaceous-Tertiary boundary problem has been discussed previously from the geological research, mainly by fossil changes. Although geochemical bulk data of Ir anomaly suggest the extraterrestrial origin of the K-T boundary, the exact formation process discussed mainly by mineralogical and geochemical study has been started recently, together with noble gas contents. The K-T boundary sample at Kawaruppu River, Hokkaido was collected, in order to compare with the typical K-T boundary samples of Bubbio, Italy, Stevns Klint, Denmark, and El Kef, Tunisia. The experimental data of the silicas and calcites in these K-T boundary samples were obtained from the X-ray unit-cell dimension (i.e., density), ESR signal and total linear absorption coefficient, as well as He and Ne contents. The K-T boundary samples are usually complex mixture of the terrestrial activities after the K-T boundary event. The mineralogical and geochemical anomalous data indicate special terrestrial atmosphere at the K-T boundary formation probably induced by asteroid impact, followed the many various terrestrial activities (especially the strong role of sea-water mixture, compared with terrestrial highland impact and impact craters in the other earth-type planetary bodies).

Critical Safe Disposal of Spent Fuel: Behavior of Neutron Poisons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kienzler, Bernhard; Gmal, Bernhard

2007-07-01

In contrast to Yucca Mountain, European repository concepts rely on deep underground conditions which guarantee permanently a reducing geochemical environment. As long as no water comes into contact with the disposed nuclear fuel, criticality is excluded by compliance with the disposal conditions (limitation of U/Pu in the canisters). Penetration of water into the canister may also be considered as a scenario. However, water in a disposal results in geochemical reactions proceeding over very long periods of time: (1) Presence of water allows the corrosion of the steel of the canister material forming hydrogen and iron corrosion products. (2) Hydrogen pressuresmore » affect the zircaloy cladding even at low temperatures. Failure of fuel cladding and spacers leads to changes in the geometrical configuration. (3) UO{sub 2} matrix corrosion results in geochemically controlled reformation of secondary phase. (4) Even if the dissolution rate of UO{sub 2} is low, elements accounting for burnup credit do not behave similar as uranium. Geochemical reactions are analyzed in detail and compositions are presented which have a high probability to be formed in the long-term needing to be analyzed with respect to K{sub eff}. (authors)« less

In Situ Rates of Sulfate Reduction in Response to Geochemical Perturbations

USGS Publications Warehouse

Kneeshaw, T.A.; McGuire, J.T.; Cozzarelli, I.M.; Smith, E.W.

2011-01-01

Rates of in situ microbial sulfate reduction in response to geochemical perturbations were determined using Native Organism Geochemical Experimentation Enclosures (NOGEEs), a new in situ technique developed to facilitate evaluation of controls on microbial reaction rates. NOGEEs function by first trapping a native microbial community in situ and then subjecting it to geochemical perturbations through the introduction of various test solutions. On three occasions, NOGEEs were used at the Norman Landfill research site in Norman, Oklahoma, to evaluate sulfate-reduction rates in wetland sediments impacted by landfill leachate. The initial experiment, in May 2007, consisted of five introductions of a sulfate test solution over 11 d. Each test stimulated sulfate reduction with rates increasing until an apparent maximum was achieved. Two subsequent experiments, conducted in October 2007 and February 2008, evaluated the effects of concentration on sulfate-reduction rates. Results from these experiments showed that faster sulfate-reduction rates were associated with increased sulfate concentrations. Understanding variability in sulfate-reduction rates in response to perturbations may be an important factor in predicting rates of natural attenuation and bioremediation of contaminants in systems not at biogeochemical equilibrium. Copyright ?? 2011 The Author(s). Journal compilation ?? 2011 National Ground Water Association.

Hydrocarbon degassing of the earth and origin of oil-gas fields (isotope-geochemical and geodynamic aspects)

NASA Astrophysics Data System (ADS)

Valyaev, Boris; Dremin, Ivan

2016-04-01

More than half a century ago, Academician PN Kropotkin substantiated the relationship of the formation and distribution of oil and gas fields with the processes of emanation hydrocarbon degassing of the Earth. Over the years, the concept of PN Kropotkin received further development and recognition of studies based on new factual material. Of particular importance are the following factors: a) the results of studies on global and regional uneven processes of traditional oil and gas and the role of deep faults in controlling the spread of oil and gas fields; b) the results of the research on gigantic volumes and localization of the discharges of hydrocarbon fluids (mud volcanoes, seeps) on land and into the atmosphere and through the bottom of the World ocean; c) the results of the studies on grand volumes of the spread of unconventional hydrocarbon resources in their non-traditional fields, especially on near-surface interval of unconventional oil and gas accumulation with gas hydrates, heavy oil and bitumen, as well as extraordinary resources of oil and gas in the shale and tight rocks. Deep mantle-crust nature of oil and gas in traditional and nontraditional deposits thus received further substantiation of geological and geophysical data and research results. However, isotopic and geochemical data are still interpreted in favor of the concept of the genesis of oil and gas in the processes of thermal catalytic conversion of organic matter of sedimentary rocks, at temperatures up to 200°C. In this report an alternative interpretation of the isotope carbon-hydrogen system (δ13C-δD) for gas and of oil deposits, isotope carbon system for methane and carbon dioxide (δ13C1-δ13C0) will be presented. An alternative interpretation will also be presented for the data on carbon-helium isotope geochemical system for oil and gas fields, volcanoes and mud volcanoes. These constructions agree with the geological data on the nature of deep hydrocarbon fluids involved in the formation of traditional and nontraditional hydrocarbon accumulations. The genesis of hydrocarbon fluids turn up to be associated with a hydrocarbon branch of deep degassing and recycling of crustal materials and processes of crust-mantle interaction [1,2,3]. The study was supported by the Russian Foundation for Basic Research (RFBR), grant № 14-05-00869. 1. Valyaev B.M., Dremin I.S. Deep Roots of the Fluid Systems and Oil-Gas Fields (Isotope Geochemical and Geodynamic Aspects) // International Conference Goldschmidt2015, Prague, Czech Republic, August 16-21, 2015. Abstracts. P. 3221. 2. Valyaev B., Dremin I. Recycling of crustal matter and the processes of mantle-crust interaction in the genesis of hydrocarbon fluids // International Conference on Gas Geochemistry 2013, Patras, Greece, 1-7 September 2013, Book of abstracts. P. 32. 3. Degassing of the Earth: Geotectonics, Geodynamics, Geofluids; Oil and Gas; Hydrocarbon and Life. Proceedings of the all-Russian with International Participation Conference, devoted the centenary of Academician P.N. Kropotkin, October 18-22, 2010, Moscow. Responsible editors: Academician A.N. Dmitrievsky, senior doctorate B.M. Valyaev. -Moscow: GEOS, 2010. 712 p.

Understanding the ecocline at shallow coasts of the Baltic Sea

NASA Astrophysics Data System (ADS)

Lenartz, B.; Jurasinski, G.; Voss, M.; Janssen, M.

2017-12-01

We report on results of the Research Training Group Baltic TRANSCOAST. The overall aim of Baltic TRANSCOAST is to enhance our knowledge of the shallow coast ecocline. How is the marine coastal zone influenced by terrestrial processes? How is the terrestrial coastal zone influenced by marine processes? These questions lead our research within the three research fields covering hydro-dynamic, (bio)geochemical and biological processes. Regarding the hydro-dynamics we assess how the peatland's water balance, the current dynamics and hydraulic properties of the marine sediments and the subsoil influence sea water intrusions into the peatland and/or submarine groundwater discharge into the Baltic Sea. With respect to (bio)geochemical processes we address how (bio)geochemical transformation processes both in the marine and the terrestrial part of the coast are influenced by water and matter inputs from the respective other coastal domain. Finally, reagrding the biological processes, we are interested in revealing how the primary production and the composition of the micro- and macro-phytobenthos in the shallow Baltic Sea influence matter transformation processes. The integrative approach of Baltic TRANSCOAST allows us to get to grips with questions that are otherwise hard to tackle. For instance, we address how the pore water constituents drive microbial processes and the deposition of nutrients and and how they are impacted by sediment resuspension and translocation. We investigate how the hydrology of the peat layers interferes with the generation of trace gases and investigate the role of the nearby Warnow river and its plume and how this changes under the impact of wind direction and wind strength. For the latter we rely on data and models. Further, as a common basis for all topics addressed in Baltic TRANSCOAST we established the geology of the study area and learned that regional variability may play a major role in shaping the processes under study.

Relation of compositions of deep fluids in geothermal activity of Pleistocene-Holocene volcanic fields of Lesser Caucasus

NASA Astrophysics Data System (ADS)

Meliksetian, Khachatur; Lavrushin, Vassily; Shahinyan, Hrach; Aidarkozhina, Altin; Navasardyan, Gevorg; Ermakov, Alexander; Zakaryan, Shushan; Prasolov, Edward; Manucharyan, Davit; Gyulnazaryan, Shushan; Grigoryan, Edmond

2017-04-01

It is widely accepted, that geothermal activity in the conductive heat flow processes, such as volcanism and hydrothermal activity, is manifestation of the thermal mass transfer process in the Earth's crust, where geothermal and geochemical processes are closely connected. Therefore, geochemistry and isotope compositions of thermal mineral waters within and on periphery of volcanic clusters may represent key indicators for better understanding of geothermal activity in geodynamically active zones. Geochemical features of heat and mass transport in hydrothermal systems related to active volcanic and fault systems in continental collision related orogenic elevated plateaus such as Anatolian-Armenian-Iranian highlands are still poorly understood. In this contribution we attempt to fill these gaps in our knowledge of relations of geochemical and geothermal processes in collision zones. We present new data on chemical compositions, trace element geochemistry of thermal waters of Lesser Caucasus, (Armenia) as well as isotope analysis of free gases such as {}3He/{}4He, {}40Ar/{}36Ar, δ{}13?(CO{}2), nitrogen δ{}15N(N{}2) and oxygen and hydrogen isotopes in water phases (δD, δ{}18O). To reveal some specific features of formation of fluid systems related to thermal activity in the areas of collision related active volcanism and active geodynamics a complex geochemical (SiO{}2, K-Na, Na-Li, Li-Mg) and isotope geothermometers (δ{}18O(CaCO{}3) - δ{}18O(H{}2O)) were applied. The distribution of δ{}13?(??{}2) values in free gases of mineral waters of Armenia demonstrates that gases related to Quaternary volcanic fields are characterized by relatively light δ{}13?(CO{}2) values close to mantle derived gases, while on periphery of volcanic systems relatively heavy values of δ{}13?(CO{}2) indicate strong influence of metamorphic and sedimentary derived carbon dioxide. Distribution of nitrogen isotopes δ{}15N(N{}2) demonstrate an inverse correlation with δ{}13?(CO{}2) values and similarly to carbon dioxide indicate presence of metamorphic nitrogen on the periphery and strong influence of atmospheric (and mantle derived) nitrogen within volcanic fields. Results of geochemical and isotope investigations, as well as estimated temperatures of the formation of the mineral compositions of thermal waters demonstrate, that these studied hydrothermal systems originated within thermal anomaly fields associated with young (Pleistocene-Holocene) volcanic fields in Armenia. Basing on geochemical and isotope data, as well as on estimations of temperatures of water formation, calculated using various geothermometers, thermal anomaly fields, related to young volcanic activity and faults, within Armenian and neighboring areas of Lesser Caucasus are outlined. These results are used to reveal potential and promising areas for geothermal energy exploration in Armenia. This research is completed in framework of joint Armenian-Russian research grant funded by State Committee of Science of Armenia (grant #15RF-076) and Russian Foundation for Basic Research (grant#15-55-05069).

COTHERM: Modelling fluid-rock interactions in Icelandic geothermal systems

NASA Astrophysics Data System (ADS)

Thien, Bruno; Kosakowski, Georg; Kulik, Dmitrii

2014-05-01

Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced geothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. We model the mineralogical and porosity evolution of Icelandic geothermal systems with 1D and 2D reactive transport models. These geothermal systems are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. The shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. We investigate two contrasting geothermal systems: Krafla, for which the water recharge consists of meteoritic water; and Reykjanes, for which the water recharge mainly consists of seawater. The initial rock composition is a fresh basalt. We use the GEM-Selektor geochemical modeling package [1] for calculation of kinetically controlled mineral equilibria between the rock and the ingression water. We consider basalt minerals dissolution kinetics according to Palandri & Kharaka [2]. Reactive surface areas are assumed to be geometric surface areas, and are corrected using a spherical-particle surface/mass relationship. For secondary minerals, we consider the partial equilibrium assuming that the primary mineral dissolution is slow, and the secondary mineral precipitation is fast. Comparison of our modeling results with the mineralogical assemblages observed in the field by Gudmundsson & Arnorsson [3] and by Icelandic partners of the COTHERM project suggests that the concept of partial equilibrium with instantaneous precipitation of secondary minerals is not sufficient to satisfactorily describe the experimental data. Considering kinetic controls also for secondary minerals appears as indispensable to properly describe the geothermal system evolution using a reactive transport modelling approach [4]. [1] Kulik D.A., Wagner T., Dmytrieva S.V., Kosakowski G., Hingerl F.F., Chudnenko K.V., Berner U., 2013. GEM-Selektor geochemical modeling package: revised algorithm and GEMS3K numerical kernel for coupled simulation codes. Computational Geosciences 17, 1-24. http://gems.web.psi.ch. [2] Palandri, J.L., Kharaka, Y.K., 2004. A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modelling. U.S.Geological Survey, Menlo Park, CA, pp. 1-64. [3] Gudmundsson B.T., Arnorsson S., 2005. Secondary mineral-fluid equilibria in the Krafla and Namafjall geothermal systems, Iceland. Applied Geochememistry 20, 1607-1625. [4] Kosakowski, G., & Watanabe, N., 2013. OpenGeoSys-Gem: A numerical tool for calculating geochemical and porosity changes in saturated and partially saturated media. Physics and Chemistry of the Earth, Parts A/B/C. doi:10.1016/j.pce.2013.11.008

Evolution of chemical and isotopic composition of inorganic carbon in a complex semi-arid zone environment: Consequences for groundwater dating using radiocarbon

NASA Astrophysics Data System (ADS)

Meredith, K. T.; Han, L. F.; Hollins, S. E.; Cendón, D. I.; Jacobsen, G. E.; Baker, A.

2016-09-01

Estimating groundwater age is important for any groundwater resource assessment and radiocarbon (14C) dating of dissolved inorganic carbon (DIC) can provide this information. In semi-arid zone (i.e. water-limited environments), there are a multitude of reasons why 14C dating of groundwater and traditional correction models may not be directly transferable. Some include; (1) the complex hydrological responses of these systems that lead to a mixture of different ages in the aquifer(s), (2) the varied sources, origins and ages of organic matter in the unsaturated zone and (3) high evaporation rates. These all influence the evolution of DIC and are not easily accounted for in traditional correction models. In this study, we determined carbon isotope data for; DIC in water, carbonate minerals in the sediments, sediment organic matter, soil gas CO2 from the unsaturated zone, and vegetation samples. The samples were collected after an extended drought, and again after a flood event, to capture the evolution of DIC after varying hydrological regimes. A graphical method (Han et al., 2012) was applied for interpretation of the carbon geochemical and isotopic data. Simple forward mass-balance modelling was carried out on key geochemical processes involving carbon and agreed well with observed data. High values of DIC and δ13CDIC, and low 14CDIC could not be explained by a simple carbonate mineral-CO2 gas dissolution process. Instead it is suggested that during extended drought, water-sediment interaction leads to ion exchange processes within the top ∼10-20 m of the aquifer which promotes greater calcite dissolution in saline groundwater. This process was found to contribute more than half of the DIC, which is from a mostly 'dead' carbon source. DIC is also influenced by carbon exchange between DIC in water and carbonate minerals found in the top 2 m of the unsaturated zone. This process occurs because of repeated dissolution/precipitation of carbonate that is dependent on the water salinity driven by drought and periodic flooding conditions. This study shows that although 14C cannot be directly applied as a dating tool in some circumstances, carbon geochemical/isotopic data can be useful in hydrological investigations related to identifying groundwater sources, mixing relations, recharge processes, geochemical evolution, and interaction with surface water.

Enrichment of fluoride in groundwater under the impact of saline water intrusion at the salt lake area of Yuncheng basin, northern China

NASA Astrophysics Data System (ADS)

Gao, Xubo; Wang, Yanxin; Li, Yilian; Guo, Qinghai

2007-12-01

Long-term intake of high-fluoride groundwater causes endemic fluorosis. This study, for the first time, discovered that the salt lake water intrusion into neighboring shallow aquifers might result in elevation of fluoride content of the groundwater. Two cross-sections along the groundwater flow paths were selected to study the geochemical processes controlling fluoride concentration in Yuncheng basin, northern China. There are two major reasons for the observed elevation of fluoride content: one is the direct contribution of the saline water; the other is the undersaturation of the groundwater with respect to fluorite due to salt water intrusion, which appears to be more important reason. The processes of the fluorine activity reduction and the change of Na/Ca ratio in groundwater induced by the intrusion of saline water favor further dissolution of fluorine-bearing mineral, and it was modeled using PHREEQC. With the increase in Na concentration (by adding NaCl or Na2SO4 as Na source, calcium content kept invariable), the increase of NaF concentration was rapid at first and then became slower; and the concentrations of HF, HF{2/-}, CaF+, and MgF+ were continuously decreasing. The geochemical conditions in the study area are advantageous to the complexation of F- with Na+ and the decline of saturation index of CaF2, regardless of the water type (Cl-Na or SO4-Na type water).

Cerium and Neodymium Isotope Fractionation in Geochemical Samples

NASA Astrophysics Data System (ADS)

Ohno, T.; Ishibashi, T.

2014-12-01

The study of naturally occurring isotopic variations of rare earth elements (REE) has a potentially significant influence in geochemical research fields with other traditional studies of REE. One of the key features of REE are their chemical similarities and gradual changes of ionic radius, which may make the isotopic variation of REE a potential tool to understand the mechanisms of isotopic fractionation in nature. Among the REE, geochemical and physicochemical features of Ce could be anomalous, because Ce could be present as the tetravalent (+IV) state as well as the common trivalent (+III) state of other REE. Since the oxidation state of Ce can change by reflecting the redox conditions of the environment, the measured differences in the degree of isotopic fractionation between Ce and other REE can provide unique information about the redox conditions. In this study, we developed a new analytical method to determine the mass-dependent isotopic fractionations of Ce and Nd in geochemical samples. The reproducibility of the isotopic ratio measurements on 142Ce/140Ce, 146Nd/144Nd and 148Nd/144Nd were 0.08‰ (2SD, n=25), 0.06‰ (2SD, n=39) and 0.12‰ (2SD, n=39), respectively. The present technique was applied to determine the variations of the Ce and Nd isotopic ratios for five geochemical reference materials (igneous rocks, JB-1a and JA-2; sedimentary rocks, JMn-1, JCh-1 and JDo-1). The resulting ratios for two igneous rocks (JB-1a and JA-2) and two sedimentary rocks (JMn-1 and JCh-1) did not vary significantly among the samples, whereas the Ce and Nd isotope ratios for the carbonate samples (JDo-1) were significantly higher than those for igneous and sedimentary rock samples. The 1:1 simple correlation between δ142Ce and δ146Nd indicates that there were no significant difference in the degree of isotopic fractionation between the Ce and Nd. This suggests that the isotopic fractionation for Ce found in the JDo-1 could be induced by physicochemical processes without changing the oxidation status of Ce, since the redox-reaction can produce larger isotopic fractionation than the reactions without changing the oxidation state. The variations in the Ce and Nd isotope ratios for geochemical samples could provide new information concerning the physico-chemical processes of the sample formation.

Self-gravity, self-consistency, and self-organization in geodynamics and geochemistry

NASA Astrophysics Data System (ADS)

Anderson, Don L.

The results of seismology and geochemistry for mantle structure are widely believed to be discordant, the former favoring whole-mantle convection and the latter favoring layered convection with a boundary near 650 km. However, a different view arises from recognizing effects usually ignored in the construction of these models, including physical plausibility and dimensionality. Self-compression and expansion affect material properties that are important in all aspects of mantle geochemistry and dynamics, including the interpretation of tomographic images. Pressure compresses a solid and changes physical properties that depend on volume and does so in a highly nonlinear way. Intrinsic, anelastic, compositional, and crystal structure effects control seismic velocities; temperature is not the only parameter, even though tomographic images are often treated as temperature maps. Shear velocity is not a good proxy for density, temperature, and composition or for other elastic constants. Scaling concepts are important in mantle dynamics, equations of state, and wherever it is necessary to extend laboratory experiments to the parameter range of the Earth's mantle. Simple volume-scaling relations that permit extrapolation of laboratory experiments, in a thermodynamically self-consistent way, to deep mantle conditions include the quasiharmonic approximation but not the Boussinesq formalisms. Whereas slabs, plates, and the upper thermal boundary layer of the mantle have characteristic thicknesses of hundreds of kilometers and lifetimes on the order of 100 million years, volume-scaling predicts values an order of magnitude higher for deep-mantle thermal boundary layers. This implies that deep-mantle features are sluggish and ancient. Irreversible chemical stratification is consistent with these results; plausible temperature variations in the deep mantle cause density variations that are smaller than the probable density contrasts across chemical interfaces created by accretional differentiation and magmatic processes. Deep-mantle features may be convectively isolated from upper-mantle processes. Plate tectonics and surface geochemical cycles appear to be entirely restricted to the upper ˜1,000 km. The 650-km discontinuity is mainly an isochemical phase change but major-element chemical boundaries may occur at other depths. Recycling laminates the upper mantle and also makes it statistically heterogeneous, in agreement with high-frequency scattering studies. In contrast to standard geochemical models and recent modifications, the deeper layers need not be accessible to surface volcanoes. There is no conflict between geophysical and geochemical data, but a physical basis for standard geochemical and geodynamic mantle models, including the two-layer and whole-mantle versions, and qualitative tomographic interpretations has been lacking.

Quality assurance and quality control of geochemical data—A primer for the research scientist

USGS Publications Warehouse

Geboy, Nicholas J.; Engle, Mark A.

2011-01-01

Geochemistry is a constantly expanding science. More and more, scientists are employing geochemical tools to help answer questions about the Earth and earth system processes. Scientists may assume that the responsibility of examining and assessing the quality of the geochemical data they generate is not theirs but rather that of the analytical laboratories to which their samples have been submitted. This assumption may be partially based on knowledge about internal and external quality assurance and quality control (QA/QC) programs in which analytical laboratories typically participate. Or there may be a perceived lack of time or resources to adequately examine data quality. Regardless of the reason, the lack of QA/QC protocols can lead to the generation and publication of erroneous data. Because the interpretations drawn from the data are primary products to U.S. Geological Survey (USGS) stakeholders, the consequences of publishing erroneous results can be significant. The principal investigator of a scientific study ultimately is responsible for the quality and interpretation of the project's findings, and thus must also play a role in the understanding, implementation, and presentation of QA/QC information about the data. Although occasionally ignored, QA/QC protocols apply not only to procedures in the laboratory but also in the initial planning of a research study and throughout the life of the project. Many of the tenets of developing a sound QA/QC program or protocols also parallel the core concepts of developing a good study: What is the main objective of the study? Will the methods selected provide data of enough resolution to answer the hypothesis? How should samples be collected? Are there known or unknown artifacts or contamination sources in the sampling and analysis methods? Assessing data quality requires communication between the scientists responsible for designing the study and those collecting samples, analyzing samples, treating data, and interpreting results. This primer has been developed to provide basic information and guidance about developing QA/QC protocols for geochemical studies. It is not intended to be a comprehensive guide but rather an introduction to key concepts tied to a list of relevant references for further reading. The guidelines are presented in stepwise order beginning with presampling considerations and continuing through final data interpretation. The goal of this primer is to outline basic QA/QC practices that scientists can use before, during, and after chemical analysis to ensure the validity of the data they collect with the goal of providing defendable results and conclusions.

Principal aquifers can contribute radium to sources of drinking water under certain geochemical conditions

USGS Publications Warehouse

Szabo, Zoltan; Fischer, Jeffrey M.; Hancock, Tracy Connell

2012-01-01

What are the most important factors affecting dissolved radium concentrations in principal aquifers used for drinking water in the United States? Study results reveal where radium was detected and how rock type and chemical processes control radium occurrence. Knowledge of the geochemical conditions may help water-resource managers anticipate where radium may be elevated in groundwater and minimize exposure to radium, which contributes to cancer risk. Summary of Major Findings: * Concentrations of radium in principal aquifers used for drinking water throughout the United States generally were below 5 picocuries per liter (pCi/L), the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) for combined radium - radium-226 (Ra-226) plus radium-228 (Ra-228) - in public water supplies. About 3 percent of sampled wells had combined radium concentrations greater than the MCL. * Elevated concentrations of combined radium were more common in groundwater in the eastern and central United States than in other regions of the Nation. About 98 percent of the wells that contained combined radium at concentrations greater than the MCL were east of the High Plains. * The highest concentrations of combined radium were in the Mid-Continent and Ozark Plateau Cambro-Ordovician aquifer system and the Northern Atlantic Coastal Plain aquifer system. More than 20 percent of sampled wells in these aquifers had combined radium concentrations that were greater than or equal to the MCL. * Concentrations of Ra-226 correlated with those of Ra-228. Radium-226 and Ra-228 occur most frequently together in unconsolidated sand aquifers, and their presence is strongly linked to groundwater chemistry. * Three common geochemical factors are associated with the highest radium concentrations in groundwater: (1) oxygen-poor water, (2) acidic conditions (low pH), and (3) high concentrations of dissolved solids.

Leaching of APC residues from secondary Pb metallurgy using single extraction tests: the mineralogical and the geochemical approach.

PubMed

Ettler, Vojtech; Mihaljevic, Martin; Sebek, Ondrej; Strnad, Ladislav

2005-05-20

Two air-pollution-control (APC) residues--one from flue gas cooling with alkaline water and one from deionized water cooling--from secondary lead metallurgy were submitted to two different standardized short-term leaching protocols: US EPA toxicity characteristic leaching procedure (TCLP) and static leaching according to Czech/European norm EN 12457-2. The experimental procedure was coupled with detailed mineralogical investigation of the solid material (SEM, XRPD) and speciation-solubility calculations using the PHREEQC-2 geochemical code. Both types of residues were considered as hazardous materials exhibiting substantial leaching of Pb (up to 7130 mg/l) and other inorganic contaminants. However, the APC residue produced by flue gas cooling with alkaline water (sample B) exhibits more favourable leaching and environmental characteristics than that produced by simple deionised water cooling (sample A). At pH < 5, primary caracolite (Na3Pb2(SO4)3Cl) and potassium lead chloride (KCl.2PbCl2) are completely or partially dissolved and transformed to residual anglesite (PbSO4), cotunnite (PbCl2) and laurionite (Pb(OH)Cl). At pH 5-6, anglesite is still the principal residual product, whereas at pH > 6, phosgenite (PbCl2.PbCO3) became the dominant secondary phase. The results are consistent with the mineralogical and geochemical studies focused on acidic forest soils highly polluted by smelter emissions, where anglesite, as a unique Pb-bearing phase, has been detected. From the technological point of view, the mixing of APC residue with alkaline water, followed by an increase in the suspension pH and equilibration with atmospheric CO2, may be used to ensure the precipitation of less soluble Pb carbonates, which are more easily recycled in the Pb recovery process in the metallurgical plant.

NATURAL ARSENIC CONTAMINATION OF HOLOCENE ALLUVIAL AQUIFERS BY LINKED TECTONIC, WEATHERING, AND MICROBIAL PROCESSES

EPA Science Inventory

Linked tectonic, geochemical, and biologic processes lead to natural arsenic contamination of groundwater in Holocene alluvial aquifers, which are the main threat to human health around the world. These groundwaters are commonly found a long distance from their ultimate source of...

THE FORMATION OF PB(IV) OXIDES IN CHLORINATED WATER - PRESENTATION

EPA Science Inventory

Recent research has shown that Pb(IV) oxides can play an important geochemical role in drinking water distribution systems. The basis of most guidance for lead control in drinking water, however, presumes that Pb(II) solids control lead solubility. Therefore, it is important that...

Geological investigation of the Socorro geothermal area. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chapin, C.E.; Sanford, A.R.; White, D.W.

1979-05-01

The results of a comprehensive geological and geochemical study of the Socorro geothermal area are presented. The following are discussed: geologic setting, structural controls, stratigraphic controls, an ancient geothermal system, modern magma bodies, geothermal potential of the Socorro area, and the Socorro transverse shear zone. (MHR)

Simulating the Incorporation of Geochemical Proxies into Scleractinian Coral Skeletons: Effects of Different Environmental and Biological Factors and Implications for Paleo-reconstruction

NASA Astrophysics Data System (ADS)

Guo, W.

2017-12-01

Chemical and isotopic compositions of scleractinian coral skeletons reflect the physicochemical condition of the seawater in which corals grow. This makes coral skeleton one of the best archives of ocean climate and biogeochemical changes. A number of coral-based geochemical proxies have been developed and applied to reconstruct past seawater conditions, such as temperature, pH, carbonate chemistry and nutrient concentrations. Detailed laboratory and field-based studies of these proxies, however, indicate interpretation of the geochemistry of coral skeletons is not straightforward, due to the presence of `vital effects' and the variations of empirical proxy calibrations among and within different species. This poses challenges for the broad application of many geochemical proxies in corals, and highlights the need to better understand the fundamental processes governing the incorporation of different proxies. Here I present a numerical model that simulates the incorporation of a suite of geochemical proxies into coral skeletons, including δ11B, Mg/Ca, Sr/Ca, U/Ca, B/Ca and Ba/Ca. This model, building on previous theoretical studies of coral calcification, combines our current understanding of coral calcification mechanism with experimental constraints on the isotope and element partition during carbonate precipitation. It enables quantitative evaluation of the effects of different environmental and biological factors on each proxy. Specifically, this model shows that (1) the incorporation of every proxy is affected by multiple seawater parameters (e.g. temperature, pH, DIC) as opposed to one single parameter, and (2) biological factors, particularly the interplay between enzymatic alkalinity pumping and the exchange of coral calcifying fluid with external seawater, also exert significant controls. Based on these findings, I propose an inverse method for simultaneously reconstructing multiple seawater physicochemical parameters, and compare the performance of this new method with conventional paleo-reconstruction methods that are based on empirical calibrations. In addition, the extension of this model to simulate carbon, oxygen and clumped isotope (δ13C, δ18O, Δ47) composition of coral skeletons will also be discussed at the meeting.

Influence of rock composition on the geochemistry of stream and spring waters from mountainous watersheds in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado

USGS Publications Warehouse

Miller, William Roger

2002-01-01

The ranges of geochemical baselines for stream and spring waters were determined and maps were constructed showing acid-neutralizing capacity and potential release of total dissolved solids for streams and spring waters for watersheds underlain by each of ten different rock composition types in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado (GMUG). Water samples were collected in mountainous headwater watersheds that have comparatively high precipitation and low evapotranspiration rates and that generally lack extensive ground-water reservoirs. Mountainous headwaters react quickly to changes in input of water from rain and melting snow and they are vulnerable to anthropogenic impact. Processes responsible for the control and mobility of elements in the watersheds were investigated. The geochemistry of water from the sampled watersheds in the GMUG, which are underlain by rocks that are relatively unmineralized, is compared to the geochemistry of water from the mineralized Redcloud Peak area. The water with the highest potential for release of total dissolved solids is from watersheds that are underlain by Paleozoic sedimentary rocks; that high potential is caused primarily by gypsum in those rocks. Water that has the highest acid-neutralizing capacity is from watersheds that are underlain by Paleozoic sedimentary rocks. The water from watersheds underlain by the Mancos Shale has the next highest acid-neutralizing capacity. Water that has the lowest acid-neutralizing capacity is from watersheds that are underlain by Tertiary ash-flow tuff. Tertiary sedimentary rocks containing oil shale, the Mesavede Formation containing coal, and the Mancos Shale all contain pyrite with elevated metal contents. In these mountainous head-water areas, water from watersheds underlain by these rock types is only slightly impacted by oxidation of pyrite, and over-all it is of good chemical quality. These geochemical baselines demonstrate the importance of rock composition in determining the types of waters that are in the headwater areas. The comparison of these geochemical baselines to later geochemical base-lines will allow recognition of any significant changes in water quality that may occur in the future.

Investigation of the relationship between CO2 reservoir rock property change and the surface roughness change originating from the supercritical CO2-sandstone-groundwater geochemical reaction at CO2 sequestration condition

NASA Astrophysics Data System (ADS)

Lee, Minhee; Wang, Sookyun; Kim, Seyoon; Park, Jinyoung

2015-04-01

Lab scale experiments were performed to investigate the property changes of sandstone slabs and cores, resulting from the scCO2-rock-groundwater reaction for 180 days under CO2 sequestration conditions (100 bar and 50 °C). The geochemical reactions, including the surface roughness change of minerals in the slab, resulted from the dissolution and the secondary mineral precipitation for the sandstone reservoir of the Gyeongsang basin, Korea were reproduced in laboratory scale experiments and the relationship between the geochemical reaction and the physical rock property change was derived, for the consideration of successful subsurface CO2 sequestration. The use of the surface roughness value (SRrms) change rate and the physical property change rate to quantify scCO2-rock-groundwater reaction is the novel approach on the study area for CO2 sequestration in the subsurface. From the results of SPM (Scanning Probe Microscope) analyses, the SRrms for each sandstone slab was calculated at different reaction time. The average SRrms increased more than 3.5 times during early 90 days reaction and it continued to be steady after 90 days, suggesting that the surface weathering process of sandstone occurred in the early reaction time after CO2 injection into the subsurface reservoir. The average porosity of sandstone cores increased by 8.8 % and the average density decreased by 0.5 % during 90 days reaction and these values slightly changed after 90 days. The average P and S wave velocities of sandstone cores also decreased by 10 % during 90 days reaction. The trend of physical rock property change during the geochemical reaction showed in a logarithmic manner and it was also correlated to the logarithmic increase in SRrms, suggesting that the physical property change of reservoir rocks originated from scCO2 injection directly comes from the geochemical reaction process. Results suggested that the long-term estimation of the physical property change for reservoir rocks in CO2 injection site could be possible from the extrapolation process of SRrms and rocks property change rates, acquired from laboratory scale experiments. It will be aslo useful to determine the favorite CO2 injection site from the viewpoint of the safety.

Geochemical Constraints for Mercury's PCA-Derived Geochemical Terranes

NASA Astrophysics Data System (ADS)

Stockstill-Cahill, K. R.; Peplowski, P. N.

2018-05-01

PCA-derived geochemical terranes provide a robust, analytical means of defining these terranes using strictly geochemical inputs. Using the end members derived in this way, we are able to assess the geochemical implications for Mercury.

Stable isotope monitoring of ionic trapping of CO2 in deep brines

NASA Astrophysics Data System (ADS)

Myrttinen, A.; Barth, J. A. C.; Becker, V.; Blum, P.; Grathwohl, P.

2009-04-01

CO2 injection into a depleted gas-reservoir is used as a combined method for Enhanced Gas Recovery (EGR) and CO2 storage. In order to safeguard this process, monitoring the degree of dissolution and potential further precipitation and mineral interactions are a necessity. Here a method is introduced, in which stable isotope and geochemical data can be used as a monitoring technique to quantify ionic trapping of injected CO2. Isotope and geochemical data of dissolved inorganic carbon (DIC) can be used to distinguish between already present and to be injected inorganic carbon. Injected CO2, for instance, is formed during combustion of former plant material and is expected to have a different isotope ratio (δ13C value) than the baseline data of the aquifer. This is because combusted CO2 originates from organic material, such as coal and oil with a predominant C3 plant signature. Mixing the injected CO2 with groundwater is therefore expected to change the isotope, as well as the geochemical composition of the groundwater. Mass balance calculations with stable isotope ratios can serve to quantify ionic trapping of CO2 as DIC in groundwater. However, depending on the composition of the aquifer, weathering of carbonate or silicates may occur. Enhanced weathering processes due to CO2 injection can also further influence the isotopic composition. Such interactions between dissolved CO2 and minerals depend on the temperature and pressure regimes applied. Field data, as well as laboratory experiments are planned to quantify isotope ratios of dissolved inorganic carbon as well as oxygen isotope ratios of the water. These are indicative of geochemical processes before, during and after EGR. The isotope method should therefore provide a new tool to quantify the efficiency of ionic trapping under various temperatures and pressures. Keywords: Enhanced Gas Recovery, monitoring of CO2 dissolution, stable isotopes

Crustal permeability

USGS Publications Warehouse

Gleeson, Tom; Ingebritsen, Steven E.

2016-01-01

Permeability is the primary control on fluid flow in the Earth’s crust and is key to a surprisingly wide range of geological processes, because it controls the advection of heat and solutes and the generation of anomalous pore pressures.  The practical importance of permeability – and the potential for large, dynamic changes in permeability – is highlighted by ongoing issues associated with hydraulic fracturing for hydrocarbon production (“fracking”), enhanced geothermal systems, and geologic carbon sequestration.  Although there are thousands of research papers on crustal permeability, this is the first book-length treatment.  This book bridges the historical dichotomy between the hydrogeologic perspective of permeability as a static material property and the perspective of other Earth scientists who have long recognized permeability as a dynamic parameter that changes in response to tectonism, fluid production, and geochemical reactions. 

Application of a flexible lattice Boltzmann method based simulation tool for modelling physico-chemical processes at different scales

NASA Astrophysics Data System (ADS)

Patel, Ravi A.; Perko, Janez; Jacques, Diederik

2017-04-01

Often, especially in the disciplines related to natural porous media, such as for example vadoze zone or aquifer hydrology or contaminant transport, the relevant spatial and temporal scales on which we need to provide information is larger than the scale where the processes actually occur. Usual techniques used to deal with these problems assume the existence of a REV. However, in order to understand the behavior on larger scales it is important to downscale the problem onto the relevant scale of the processes. Due to the limitations of resources (time, memory) the downscaling can only be made up to the certain lower scale. At this lower scale still several scales may co-exist - the scale which can be explicitly described and a scale which needs to be conceptualized by effective properties. Hence, models which are supposed to provide effective properties on relevant scales should therefor be flexible enough to represent complex pore-structure by explicit geometry on one side, and differently defined processes (e.g. by the effective properties) which emerge on lower scale. In this work we present the state-of-the-art lattice Boltzmann method based simulation tool applicable to advection-diffusion equation coupled to geochemical processes. The lattice Boltzmann transport solver can be coupled with an external geochemical solver which allows to account for a wide range of geochemical reaction networks through thermodynamic databases. The applicability to multiphase systems is ongoing. We provide several examples related to the calculation of an effective diffusion properties, permeability and effective reaction rate based on a continuum scale based on the pore scale geometry.

Geochemical results from stream-water and stream-sediment samples collected in Colorado and New Mexico

USGS Publications Warehouse

Hageman, Philip L.; Todd, Andrew S.; Smith, Kathleen S.; DeWitt, Ed; Zeigler, Mathew P.

2013-01-01

Scientists from the U.S. Geological Survey are studying the relationship between watershed lithology and stream-water chemistry. As part of this effort, 60 stream-water samples and 43 corresponding stream-sediment samples were collected in 2010 and 2011 from locations in Colorado and New Mexico. Sample sites were selected from small to midsize watersheds composed of a high percentage of one rock type or geologic unit. Stream-water and stream-sediment samples were collected, processed, preserved, and analyzed in a consistent manner. This report releases geochemical data for this phase of the study.

Spatial differences in hydrologic characteristics and water chemistry of a temperate coastal plain peatland: The Great Dismal Swamp, USA

USGS Publications Warehouse

Speiran, Gary K.; Wurster, Frederick C.

2016-01-01

Spatial differences in hydrologic processes and geochemistry across forested peatlands control the response of the wetland-community species and resiliency to natural and anthropogenic disturbances. Knowing these controls is essential to effectively managing peatlands as resilient wetland habitats. The Great Dismal Swamp is a 45,325 hectare peatland in the Atlantic Coastal Plain of Virginia and North Carolina, USA, managed by the U.S. Fish and Wildlife Service. The existing forest-species distribution is a product of timber harvesting, hydrologic alteration by canal and road construction, and wildfires. Since 2009, studies of hydrologic and geochemical controls have expanded knowledge of groundwater flow paths, water chemistry, response to precipitation events, and characteristics of the peat. Dominant hydrologic and geochemical controls include (1) the gradual slope in land surface, (2) vertical differences in the hydraulic characteristics of the peat, (3) the proximity of lateral groundwater and small stream inflows from uplands, (4) the presence of an extensive canal and road network, and (5) small, adjustable-height dams on the canals. Although upland sources provide some surface water and lateral groundwater inflow to western parts of the swamp, direct groundwater recharge by precipitation is the major source of water throughout the swamp and the only source in many areas. Additionally, the proximity and type of upland water sources affect water levels and nutrient concentrations in canal water and groundwater. Where streams are a dominant upland source, variations in groundwater levels and nutrient concentrations are greater than where recharge by precipitation is the primary water source. Where upland groundwater is a dominant source, water levels are more stable. Because the species distribution of forest communities in the Swamp is strongly influenced by these controls, swamp managers are beginning to incorporate this knowledge into forest, water, and fire management plans.

Hydrogeomorphic and ecological control on carbonate dissolution in a patterned landscape in South Florida

NASA Astrophysics Data System (ADS)

Dong, X.; Heffernan, J. B.; Murray, A. B.; Cohen, M. J.; Martin, J. B.

2016-12-01

The evolution of the critical zone both shapes and reflects hydrologic, geochemical, and ecological processes. These interactions are poorly understood in karst landscapes with highly soluble bedrock. In this study, we used the regular-dispersed wetland basins of Big Cypress National Preserve in Florida as a focal case to model the hydrologic, geochemical, and biological mechanisms that affect soil development in karst landscapes. We addressed two questions: (1) What is the minimum timescale for wetland basin development, and (2) do changes in soil depth feed back on dissolution processes and if so by what mechanism? We developed an atmosphere-water-soil model with coupled water-solute transport, incorporating major ion equilibria and kinetic non-equilibrium chemistry, and biogenic acid production via roots distributed through the soil horizon. Under current Florida climate, weathering to a depth of 2 m (a typical depth of wetland basins) would take 4000 6000 yrs, suggesting that landscape pattern could have origins as recent as the most recent stabilization of sea level. Our model further illustrates that interactions between ecological and hydrologic processes influence the rate and depth-dependence of weathering. Absent inundation, dissolution rate decreased exponentially with distance from the bedrock to groundwater table. Inundation generally increased bedrock dissolution, but surface water chemistry and residence time produced complex and non-linear effects on dissolution rate. Biogenic acidity accelerated the dissolution rate by 50 and 1,000 times in inundated and exposed soils. Phase portrait analysis indicated that exponential decreases in bedrock dissolution rate with soil depth could produce stable basin depths. Negative feedback between hydro-period and total basin volume could stabilize the basin radius, but the lesser strength of this mechanism may explain the coalescence of wetland basins observed in some parts of the Big Cypress Landscape.

Diagenetic susceptibility of carbonate archives - an experimental approach

NASA Astrophysics Data System (ADS)

Pederson, C.; Purgstaller, B.; Mavromatis, V.; Dietzel, M.; Jöns, N.; Buhl, D.; Neuser, R. D.; Breitenbach, S. F. M.; Hoffmann, R.; Kwiecien, O.; Riechelmann, S.; Immenhauser, A.

2017-12-01

Carbonate sediments and biominerals can record environmental conditions during both deposition and subsequent diagenesis, making them important archives of within the geologic record. Therefore, the alteration processes of these paleoenvironmental proxies are important to understand if one is to deduce environmental conditions based on their petrographic and geochemical signature. This study uses an experimental approach in order to best indicate the controls and effects of the diagenesis of various carbonate archives. Samples are hydrothermally altered at known conditions including pore water chemistry (meteoric and brine fluids), and temperature (100-200°C), and are directly compared to an unaltered subsample (same specimen) for petrographic and geochemical alteration, allowing for reduced heterogeneity, and a quantitative and systematic approach to determine the type, extent, and controls of diagenesis. Initial results indicate little-no alteration at the lower temperature experiments (100°C), and almost complete alteration observed at higher temperatures (175-200°C), while intermediate temperature ranges (130-160°C) prove promising for the evaluation of both diagenetic mechanisms, as well as rate limiting factors controlling alteration. Initial results indicate partial recrystallization of the bivalve A. Islandica, as well as other carbonates (corals, bivalves, gastropods, ammonites, and speleothems), with a visually distinct recrystallization front for select specimens. Results indicate that the diagenetic pathway preferentially follows organic distribution, and internal structures within the organo-sediments and minerals, possibly formed during initial formation. Alteration also suggests preferential movement of intercrystalline organics in some sample types, where they appear to be pushed away from the diagenetic front, causing concentration of the water insoluble organics, and the production of visually darker areas surrounding diagenetic fluid pathways.

Transfer of rare earth elements from natural metalliferous (copper and cobalt rich) soils into plant shoot biomass of metallophytes from Katanga (Democratic Republic of Congo)

NASA Astrophysics Data System (ADS)

Pourret, Olivier; Lange, Bastien; Jitaru, Petru; Mahy, Grégory; Faucon, Michel-Pierre

2014-05-01

The geochemical behavior of rare earth elements (REE) is generally assessed for the characterization of the geological systems where these elements represent the best proxies of processes involving the occurrence of an interface between different media. REE behavior is investigated according to their concentrations normalized with respect to the upper continental crust. In this study, the geochemical fingerprint of REE in plant shoot biomass of an unique metallicolous flora (i.e., Crepidorhopalon tenuis and Anisopappus chinensis) was investigated. The plants originate from extremely copper and cobalt rich soils, deriving from Cu and Co outcrops in Katanga, Democratic Republic of Congo. Some of the species investigated in this study are able to accumulate high amounts of Cu and Co in shoot hence being considered as Cu and Co hyperaccumulators. Therefore, assessing the behavior of REE may lead to a better understanding of the mechanisms of metal accumulation by this flora. The data obtained in this study indicate that REE uptake by plants is not primarily controlled by their concentration and speciation in the soil as previously shown in the literature (Brioschi et al. 2013). Indeed, the REE patterns in shoots are relatively flat whereas soils patterns are Middle REE enriched. In addition, it is worth noting that Eu enrichments occur in aerial parts of the plants. These positive Eu anomalies suggest that Eu3 + can form stable organic complexes replacing Ca2 + in several biological processes as in xylem fluids associated with the general nutrient flux. Therefore, is is possible that the Eu mobility in these fluids is enhanced by its reductive speciation as Eu2 +. Eventually, the geochemical behavior of REE illustrates that metals accumulation in aerial parts of C. tenuis and A. chinensis is mainly driven by dissolved complexation. Brioschi, L., Steinmann, M., Lucot, E., Pierret, M., Stille, P., Prunier, J., Badot, P., 2013. Transfer of rare earth elements (REE) from natural soil to plant systems: implications for the environmental availability of anthropogenic REE. Plant and Soil, 366, 143-163.

Synthetical Analysis for Morphology, biological Species, and stable Isotopes (SAMSI) of single-cell planktonic foraminifer

NASA Astrophysics Data System (ADS)

Ujiie, Y.; Kimoto, K.; Ishimura, T.

2017-12-01

Planktonic foraminifers are widely used in the studies of paleontology and paleoceanography, because the morphology of their calcareous shells is enough highly variable to identify the morphospecies and the chemical composition of the shells reflect ambient seawater condition. Although the morphospecies were believed to represent environments associating with latitudinal temperature range of the world ocean, molecular phylogeographic studies have unveiled the presence of multiple biological species in a single morphospecies and their species-specific distributions. This implicates the actual complexity of planktonic foraminiferal ecology. Conversely, these biological species have a high potential for providing novel ecological and environmental information to us. In order to reassess the morphological and geochemical characters of biological species, the DNA extraction method with the guanidium isothiocyanate buffer was developed to preserve the calcareous shells. The present study carefully tested the physical and chemical damages of the DNA extraction process to the shells, by our novel approaches with geochemical analysis of the shells after non-destructive analysis for morphometrics on a same specimen. First, we checked the changes of the shell densities between pre- and post-DNA extraction by using the micro-focus X-ray CT (MXCT) scanning. Based on the simultaneous measurement of a sample and the standard material, we confirmed no significant changes to the shell densities through the DNA extraction process. As a next step, we compared stable oxygen and carbon isotopes among individuals of three sample sets: (1) no chemical and incubation as control, (2) incubation in the DNA extraction buffer at 65-70°C for 40 minutes as standard way, and (3) incubation in the DNA extraction buffer at 65-70°C for 120 minutes, by using the microscale isotopic analytical system (MICAL3c). Consequently, there were no significant differences among the three sample sets. These examinations clearly certified that we define morphological and geochemical features from same specimens after genetic identification. Thus, our novel approach (SAMSI) provides future studies to establish the accurate ecological and environmental proxies both in the modern and past oceans.

Development and Application of a Paleomagnetic/Geochemical Method for Constraining the Timing of Burial Diagenetic Events

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmore, Richard D.; Engel, Michael H.

2006-01-05

Studies of diagenesis caused by fluid migration or other events are commonly hindered by a lack of temporal control. Our results to date demonstrate that a paleomagnetic/geochemical approach can be used to date fluid migration as well as burial diagenetic events. Our principal working hypothesis is that burial diagenetic processes (e.g., maturation of organic-rich sediments and clay diagenesis) and the migration of fluids can trigger the authigenesis of magnetic mineral phases. The ages of these events can be constrained by comparing chemical remanent magnetizations (CRMs) to independently established Apparent Polar Wander Paths. Whilst geochemical (e.g. stable isotope and organic analyses)more » and petrographic studies provide important clues for establishing these relationships, the ultimate test of this hypothesis requires the application of independent dating methods to verify the paleomagnetic ages. Towards this end, we have used K-Ar dating of illitization as an alternative method for constraining the ages of magnetic mineral phases in our field areas. We have made significant progress toward understanding the origin and timing of chemical remagnetization related to burial diagenetic processes. For example, a recently completed field study documents a relationship between remagnetization and the maturation of organic matter (Blumstein et al., 2004). We have tested the hypothesized connection between clay diagenesis and remagnetization by conducting K-Ar dating of authigenic illites in units in Scotland and Montana with CRMs (e.g., Elliott et al., 2006a; Elliott et al., 2006b). We have also developed a fluid related model for alteration and remagnetization of Appalachian red beds that involves reduction and mobilization of iron phases by hydrocarbons and precipitation of authigenic hematite as a result of the introduction of meteoric fluid recharge (Cox et al., 2005). In addition, our recent studies of fluid-related CRMs along faults in Scotland provide information on the timing and origin of fluid flow events along the Moine and Great Glen faults (Parnell et al., 2004; Blumstein et al., 2005; Elmore et al., 2006).« less

Geochemical evidence for pre- and syn-rifting lithospheric foundering in the East African Rift System

NASA Astrophysics Data System (ADS)

Nelson, W. R.; Furman, T.; Elkins-Tanton, L. T.

2015-12-01

The East African Rift System (EARS) is the archetypal active continental rift. The rift branches cut through the elevated Ethiopian and Kenyan domes and are accompanied by a >40 Myr volcanic record. This record is often used to understand changing mantle dynamics, but this approach is complicated by the diversity of spatio-temporally constrained, geochemically unique volcanic provinces. Various sources have been invoked to explain the geochemical variability across the EARS (e.g. mantle plume(s), both enriched and depleted mantle, metasomatized or pyroxenitic lithosphere, continental crust). Mantle contributions are often assessed assuming adiabatic melting of mostly peridotitic material due to extension or an upwelling thermal plume. However, metasomatized lithospheric mantle does not behave like fertile or depleted peridotite mantle, so this model must be modified. Metasomatic lithologies (e.g. pyroxenite) are unstable compared to neighboring peridotite and can founder into the underlying asthenosphere via ductile dripping. As such a drip descends, the easily fusible metasomatized lithospheric mantle heats conductively and melts at increasing T and P; the subsequent volcanic products in turn record this drip magmatism. We re-evaluated existing data of major mafic volcanic episodes throughout the EARS to investigate potential evidence for lithospheric drip foundering that may be an essential part of the rifting process. The data demonstrate clearly that lithospheric drip melting played an important role in pre-flood basalt volcanism in Turkana (>35 Ma), high-Ti "mantle plume-derived" flood basalts and picrites (HT2) from NW Ethiopia (~30 Ma), Miocene shield volcanism on the E Ethiopian Plateau and in Turkana (22-26 Ma), and Quaternary volcanism in Virunga (Western Rift) and Chyulu Hills (Eastern Rift). In contrast, there is no evidence for drip melting in "lithosphere-derived" flood basalts (LT) from NW Ethiopia, Miocene volcanism in S Ethiopia, or Quaternary within-rift lavas in Ethiopia, Turkana or Kivu. The evidence for widespread lithospheric removal across eastern Africa coincides with the timing of dome uplift (e.g. Gani et al., 2007; Wichura et al., 2015) and further demonstrates the controls of lithospheric mantle on volcano-tectonic processes throughout the evolving EARS.

Tidally driven water column hydro-geochemistry in a remediating acidic wetland

NASA Astrophysics Data System (ADS)

Johnston, Scott G.; Keene, Annabelle F.; Bush, Richard T.; Sullivan, Leigh A.; Wong, Vanessa N. L.

2011-10-01

SummaryManaged tidal inundation is a newly evolved technique for remediating coastal acid sulphate soil (CASS) wetlands. However, there remains considerable uncertainty regarding the hydro-geochemical pathways and spatiotemporal dynamics of residual H + and metal(loid) mobilisation into the tidal fringe surface waters of these uniquely iron-rich landscapes. Here, we examine the hydrology and water column chemistry across the intertidal slope of a remediating CASS wetland during several tide cycles. There was extreme spatial and temporal dynamism in water column chemistry, with pH fluctuating by ˜3 units (˜3.5-6.5) during a single tide cycle. Acute acidity was spatially confined to the upper intertidal slope, reflecting surface sediment properties, and tidal overtopping is an important pathway for mobilisation of residual H + and Al 3+ to the water column. Marine derived HCO3- was depleted from surface waters migrating across the intertidal slope and a strong gradient in HCO3- was observed from the tidal fringe to the adjacent tributary channel and nearby estuary. Tidal forcing generated oscillating hydraulic gradients in the shallow fringing aquifer, favouring ebb-tide seepage and driving rapid, heterogeneous advection of groundwater on the lower intertidal slope via surface connected macropores. A combination of diffusive and advective flux across the sediment-water interface led to persistent, elevated surface water Fe 2+ (˜10-1000 μM). The geochemical processes associated with Fe 2+ mobilisation displayed distinct spatial zonation, with low pH, proton-promoted desorption occurring on the upper intertidal slope, whilst circum-neutral pH, Fe(III)-reducing processes dominated the lower intertidal slope. Arsenic was also mobilised into surface waters on the lower intertidal slope under moderate pH (˜6.0) conditions and was strongly positively correlated with Fe 2+. Saturation index values for aragonite were substantially depressed (-1 to -5) and significantly negatively correlated with elevation, thereby presenting a barrier to re-colonisation of the upper intertidal slope by calcifying benthic organisms. These findings highlight the spatially complex hydrological and geochemical controls on surface water quality that can occur in tidally inundated acid sulphate soil environments.

U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

USGS Publications Warehouse

Manning, Andrew H.; Caine, Jonathan S.; Verplanck, Philip L.; Bove, Dana J.; Kahn, Katherine G.

2009-01-01

Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300– 1,200 ft deep), 4 bedrock (100–170 ft deep) and 5 shallow (10–30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of alpine watersheds. Additionally, despite the complexity of the fracture controlled aquifer system, it appears that it can be represented with a relatively simple conceptual model and can be treated as an equivalent porous medium at the watershed scale. Interpretation of existing data, collection of new monitoring data, and efforts to link geochemical and hydrologic processes through modeling are ongoing at the site.

Gemas: issues from the comparison of aqua regia and X-ray fluorescence results

NASA Astrophysics Data System (ADS)

Dinelli, Enrico; Birke, Manfred; Reimann, Clemens; Demetriades, Alecos; DeVivo, Benedetto; Flight, Dee; Ladenberger, Anna; Albanese, Stefano; Cicchella, Domenico; Lima, Annamaria

2014-05-01

The comparison of analytical results from aqua regia (AR) and X-ray fluorescence spectroscopy (XRF) can provide information on soil processes controlling the element distribution. The GEMAS (GEochemical Mapping of Agricultural and grazing land Soils) agricultural soil database is used for this comparison. Analyses for the same suite of elements and parameters were carried out in the same laboratory under strict quality control procedures. Sample preparation has been conducted at the laboratory of the The comparison of analytical results from aqua regia (AR) and X-ray fluorescence spectroscopy (XRF) can provide information on soil processes controlling the element distribution in soil. The GEMAS (GEochemical Mapping of Agricultural and grazing land Soils) agricultural soil database, consisting of 2 x ca. 2100 samples spread evenly over 33 European countries, is used for this comparison. Analyses for the same suite of elements and parameters were carried out in the same laboratory under strict quality control procedures. Sample preparation has been conducted at the laboratory of the Geological Survey of the Slovak Republic, AR analyses were carried out at ACME Labs, and XRF analyses at the Federal Institute for Geosciences and Natural Resources, Germany Element recovery by AR is very different, ranging from <1% (e.g. Na, Zr) to > 80% (e.g. Mn, P, Co). Recovery is controlled by mineralogy of the parent material, but geographic and climatic factors and the weathering history of the soils are also important. Nonetheless, even the very low recovery elements show wide ranges of variation and spatial patterns that are affected by other factors than soil parent material. For many elements soil pH have a clear influence on AR extractability: under acidic soil conditions almost all elements tend to be leached and their extractability is generally low. It progressively increases with increasing pH and is highest in the pH range 7-8. Critical is the clay content of the soil that almost for all elements correspond to higher extractability with increasing clay abundance. Also other factors such as organic matter content of soil, Fe and Mn occurrence are important for certain elements or in selected areas. This work illustrates that there are significant differences in the extractability of elements from soils and addresses important influencing factors related to soil properties, geology, climate.

Natural inactivation of Escherichia coli in anoxic and reduced groundwater

USGS Publications Warehouse

Lisle, John T.

2016-01-01

Aquifer recharge zones with geochemical characteristics observed in this study complement above ground engineered processes (e.g., filtration, disinfection), while increasing the overall indicator microorganism log-reduction rate of a facility.

Geochemical markers of sedimentary organic matter in Todos os Santos Bay, Bahia - Brazil. Indicators of sources and preservation.

PubMed

de Souza, José Roberto Bispo; do Rosário Zucchi, Maria; Costa, Alexandre Barreto; de Azevedo, Antonio Expedito Gomes; Spano, Saulo

2017-06-30

Natural stable isotopes, such as carbon (C) and nitrogen (N), are modern tools to assess geochemical processes. C and N in organic matter can carry fingerprints of their hydrologic flows and sedimentary processes, including any anthropogenic modification on the natural system. This study focuses on the determination of aliphatic and polycyclic aromatic hydrocarbons and isotopic ratio in the sediment of Todos os Santos Bay (TSB). The isotopic results of the total organic matter indicate varied contribution marine and terrigenous. Typical rates of PAHs mainly indicate a pyrogenic source and mixture between pyrogenic and petrogenic sources. Typical ratios for the n-alkanes indicate the presence of petroleum hydrocarbons. The isotopic composition of n-alkanes suggests a mixture of sources, with the possible contribution of petrogenic. Copyright © 2017. Published by Elsevier Ltd.

Uranium redox transition pathways in acetate-amended sediments

USGS Publications Warehouse

Bargar, John R.; Williams, Kenneth H.; Campbell, Kate M.; Long, Philip E.; Stubbs, Joanne E.; Suvorova, Elenal I.; Lezama-Pacheco, Juan S.; Alessi, Daniel S.; Stylo, Malgorzata; Webb, Samuel M.; Davis, James A.; Giammar, Daniel E.; Blue, Lisa Y.; Bernier-Latmani, Rizlan

2013-01-01

Redox transitions of uranium [from U(VI) to U(IV)] in low-temperature sediments govern the mobility of uranium in the environment and the accumulation of uranium in ore bodies, and inform our understanding of Earth’s geochemical history. The molecular-scale mechanistic pathways of these transitions determine the U(IV) products formed, thus influencing uranium isotope fractionation, reoxidation, and transport in sediments. Studies that improve our understanding of these pathways have the potential to substantially advance process understanding across a number of earth sciences disciplines. Detailed mechanistic information regarding uranium redox transitions in field sediments is largely nonexistent, owing to the difficulty of directly observing molecular-scale processes in the subsurface and the compositional/physical complexity of subsurface systems. Here, we present results from an in situ study of uranium redox transitions occurring in aquifer sediments under sulfate-reducing conditions. Based on molecular-scale spectroscopic, pore-scale geochemical, and macroscale aqueous evidence, we propose a biotic–abiotic transition pathway in which biomass-hosted mackinawite (FeS) is an electron source to reduce U(VI) to U(IV), which subsequently reacts with biomass to produce monomeric U(IV) species. A species resembling nanoscale uraninite is also present, implying the operation of at least two redox transition pathways. The presence of multiple pathways in low-temperature sediments unifies apparently contrasting prior observations and helps to explain sustained uranium reduction under disparate biogeochemical conditions. These findings have direct implications for our understanding of uranium bioremediation, ore formation, and global geochemical processes.

Evolution of geothermal fluids deduced from chemistry plots: Yellowstone National Park (U.S.A.)

USGS Publications Warehouse

Mazor, E.; Thompson, J.M.

1982-01-01

Large amounts of chemical data, obtained in geothermal fields, may readily be sorted-out by the aid of a simple set of graphs that provide a clear over-all picture and facilitate the understanding of geochemical processes taking place. As a case study, data from several hundred samples of the thermal springs at the well-known Yellowstone National Park are discussed. The pattern obtained seems to indicate: (1) geochemical similarity between the spring groups of Heart Lake, Shoshone, Upper, Midway, Lower and Norris Geyser Basins, i.e., a geochemical uniformity of major spring groups located over 40 km apart; (2) these groups may be described as originating from a common fluid, most resembling the composition of Norris waters, accompanied by CO2, and other volatiles, that react with igneous rocks, forming local variations; (3) the secondary reactions occur at (medium) depth, before the ascent to the surface; (4) extensive concentration-dilution processes occur during the ascent to the surface. The water of the Mammoth group may be described as originating from the same Norris-like fluid that has been diluted (low Na and Cl contents) and intensively reacted with carbonaceous rocks, thus gaining in Ca, Mg, SO4, and HCO3. ?? 1982.

Late Paleozoic-Early Mesozoic tectonic evolution of the Paleo-Asian Ocean: geochronological and geochemical evidence from granitoids in the northern margin of Alxa, Western China

NASA Astrophysics Data System (ADS)

Sha, Xin; Wang, Jinrong; Chen, Wanfeng; Liu, Zheng; Zhai, Xinwei; Ma, Jinlong; Wang, Shuhua

2018-03-01

The Paleo-Asian Ocean (Southern Mongolian Ocean) ophiolitic belts and massive granitoids are exposed in the Alxa block, in response to oceanic subduction processes. In this work, we report petrographic, geochemical, and zircon U-Pb age data of some granitoid intrusions from the northern Alxa. Zircon U-Pb dating for the quartz diorite, tonalite, monzogranite, and biotite granite yielded weighted mean 206Pb/238U ages of 302±9.2 Ma, 246.5±4.6 Ma, 235±4.4 Ma, and 229.5±5.6 Ma, respectively. The quartz diorites ( 302 Ma) exhibit geochemical similarities to adakites, likely derived from partial melting of the initially subducted Chaganchulu back-arc oceanic slab. The tonalites ( 246.5 Ma) display geochemical affinities of I-type granites. They were probably derived by fractional crystallization of the modified lithospheric mantle-derived basaltic magmas in a volcanic arc setting. The monzogranites ( 235 Ma) are characterized by low Al2O3, but high Y and Yb with notably negative Eu anomalies. In contrast, the biotite granites ( 229.5 Ma) show high Al2O3 but low Y and Yb with steep HREE patterns and the absence of negative Eu anomalies. Elemental data suggested that the biotite granites were likely derived from a thickened lower crust, but the monzogranites originated from a thin crust. Our data suggested that the initial subduction of the Chaganchulu oceanic slab towards the Alxa block occurred at 302 Ma. This subduction process continued to the Early Triassic ( 246 Ma) and the basin was finally closed before the Middle Triassic ( 235 Ma). Subsequently, the break-off of the subducted slab triggered asthenosphere upwelling (240-230 Ma).

A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling

USGS Publications Warehouse

Palandri, James L.; Kharaka, Yousif K.

2004-01-01

Geochemical reaction path modeling is useful for rapidly assessing the extent of water-aqueous-gas interactions both in natural systems and in industrial processes. Modeling of some systems, such as those at low temperature with relatively high hydrologic flow rates, or those perturbed by the subsurface injection of industrial waste such as CO2 or H2S, must account for the relatively slow kinetics of mineral-gas-water interactions. We have therefore compiled parameters conforming to a general Arrhenius-type rate equation, for over 70 minerals, including phases from all the major classes of silicates, most carbonates, and many other non-silicates. The compiled dissolution rate constants range from -0.21 log moles m-2 s-1 for halite, to -17.44 log moles m-2 s-1 for kyanite, for conditions far from equilibrium, at 25 ?C, and pH near neutral. These data have been added to a computer code that simulates an infinitely well-stirred batch reactor, allowing computation of mass transfer as a function of time. Actual equilibration rates are expected to be much slower than those predicted by the selected computer code, primarily because actual geochemical processes commonly involve flow through porous or fractured media, wherein the development of concentration gradients in the aqueous phase near mineral surfaces, which results in decreased absolute chemical affinity and slower reaction rates. Further differences between observed and computed reaction rates may occur because of variables beyond the scope of most geochemical simulators, such as variation in grain size, aquifer heterogeneity, preferred fluid flow paths, primary and secondary mineral coatings, and secondary minerals that may lead to decreased porosity and clogged pore throats.

Controls of bedrock geochemistry on soil and plant nutrients in Southeastern Utah

USGS Publications Warehouse

Neff, J.C.; Reynolds, R.; Sanford, R.L.; Fernandez, D.; Lamothe, P.

2006-01-01

The cold deserts of the Colorado Plateau contain numerous geologically and geochemically distinct sedimentary bedrock types. In the area near Canyonlands National Park in Southeastern Utah, geochemical variation in geologic substrates is related to the depositional environment with higher concentrations of Fe, Al, P, K, and Mg in sediments deposited in alluvial or marine environments and lower concentrations in bedrock derived from eolian sand dunes. Availability of soil nutrients to vegetation is also controlled by the formation of secondary minerals, particularly for P and Ca availability, which, in some geologic settings, appears closely related to variation of CaCO3 and Ca-phosphates in soils. However, the results of this study also indicate that P content is related to bedrock and soil Fe and Al content suggesting that the deposition history of the bedrock and the presence of P-bearing Fe and Al minerals, is important to contemporary P cycling in this region. The relation between bedrock type and exchangeable Mg and K is less clear-cut, despite large variation in bedrock concentrations of these elements. We examined soil nutrient concentrations and foliar nutrient concentration of grasses, shrubs, conifers, and forbs in four geochemically distinct field sites. All four of the functional plant groups had similar proportional responses to variation in soil nutrient availability despite large absolute differences in foliar nutrient concentrations and stoichiometry across species. Foliar P concentration (normalized to N) in particular showed relatively small variation across different geochemical settings despite large variation in soil P availability in these study sites. The limited foliar variation in bedrock-derived nutrients suggests that the dominant plant species in this dryland setting have a remarkably strong capacity to maintain foliar chemistry ratios despite large underlying differences in soil nutrient availability. ?? 2006 Springer Science+Business Media, Inc.

Geochemistry of groundwater in the Beaver and Camas Creek drainage basins, eastern Idaho

USGS Publications Warehouse

Rattray, Gordon W.; Ginsbach, Michael L.

2014-01-01

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is studying the fate and transport of waste solutes in the eastern Snake River Plain (ESRP) aquifer at the Idaho National Laboratory (INL) in eastern Idaho. This effort requires an understanding of the natural and anthropogenic geochemistry of groundwater at the INL and of the important physical and chemical processes controlling the geochemistry. In this study, the USGS applied geochemical modeling to investigate the geochemistry of groundwater in the Beaver and Camas Creek drainage basins, which provide groundwater recharge to the ESRP aquifer underlying the northeastern part of the INL. Data used in this study include petrology and mineralogy from 2 sediment and 3 rock samples, and water-quality analyses from 4 surface-water and 18 groundwater samples. The mineralogy of the sediment and rock samples was analyzed with X-ray diffraction, and the mineralogy and petrology of the rock samples were examined in thin sections. The water samples were analyzed for field parameters, major ions, silica, nutrients, dissolved organic carbon, trace elements, tritium, and the stable isotope ratios of hydrogen, oxygen, carbon, sulfur, and nitrogen. Groundwater geochemistry was influenced by reactions with rocks of the geologic terranes—carbonate rocks, rhyolite, basalt, evaporite deposits, and sediment comprised of all of these rocks. Agricultural practices near and south of Dubois and application of road anti-icing liquids on U.S. Interstate Highway 15 were likely sources of nitrate, chloride, calcium, and magnesium to groundwater. Groundwater geochemistry was successfully modeled in the alluvial aquifer in Camas Meadows and the ESRP fractured basalt aquifer using the geochemical modeling code PHREEQC. The primary geochemical processes appear to be precipitation or dissolution of calcite and dissolution of silicate minerals. Dissolution of evaporite minerals, associated with Pleistocene Lake Terreton, is an important contributor of solutes in the Mud Lake-Dubois area. Oxidation-reduction reactions are important influences on the chemistry of groundwater at Camas Meadows and the Camas National Wildlife Refuge. In addition, mixing of different groundwaters or surface water with groundwater appears to be an important physical process influencing groundwater geochemistry in much of the study area, and evaporation may be an important physical process influencing the groundwater geochemistry of the Camas National Wildlife Refuge. The mass-balance modeling results from this study provide an explanation of the natural geochemistry of groundwater in the ESRP aquifer northeast of the INL, and thus provide a starting point for evaluating the natural and anthropogenic geochemistry of groundwater at the INL.

Geochemical processes governing the compositional features of the crater fumarolic field at Mt. Etna

NASA Astrophysics Data System (ADS)

Liotta, Marcello; Paonita, Antonio; Caracausi, Antonio; Martelli, Mauro; Rizzo, Andrea; Favara, Rocco

2010-05-01

Mt Etna is one of the most-active volcanoes in the world. It is characterized by major eruptions, frequent Strombolian activity, and ash emissions. The volcano summit consists of the central crater of Voragine surrounded by the three active cones of the North-East Crater, Bocca Nuova, and the South-East Crater. They are characterized by very fractured and unstable edges. Under these conditions most of the fractures represent preferential degassing pathways for volcanic fluids, so that the main fumarolic fields develop in such fractured areas. The geochemistry of the fumaroles at the summit area of Mt. Etna was investigated. Fumarolic samples were collected between June 2008 and August 2009. Gas samples were usually collected as 'dry gas' and analyzed for the concentrations of He, H2, O2, N2, CO, CH4, and CO2. Fumarolic gases were also sampled a few times using the classical Giggenbach bottles and Giggenbach-type bottles filled with ammonia and silver nitrate in order to determine the SO2/H2S ratio. In addition a novel method was employed in order to sample fumaroles characterized by high content of atmospheric gases. Two types of fumaroles were identified: low-temperature fumaroles, which are dominated by CO2 with minor amounts of SO2 and H2S, and negligible halogen contents, and high-temperature fumaroles, which are strongly air-contaminated and characterized by appreciable amounts of volcanogenic carbon, sulfur, and chlorine. Our data clearly indicate that secondary processes modify the composition of the fluids once they leave the magma body. A model based on thermodynamic data is proposed to explore such postmagmatic processes. We computed the equilibrium composition of magmatic gases that cool starting from magmatic temperatures under several pressure conditions. The model, which uses Etnean plume geochemistry as starting composition of fluids exsolved from magma, shows that SO2 and H2S control the redox conditions of the gas mixture during the cooling, until the reactions involving CO/CO2 and H2/H2O ratios are fully quenched. The scrubbing processes occurring subsequent to condensation and gas-liquid water interaction allow total removal of HCl and partial removal of sulfur species. During the ascent toward the surface, the concentration of CH4 increases in all fumaroles due to a modest contribution from hydrothermal fluid. A geochemical model for the interaction of pristine magmatic fluids with shallower systems is proposed. The model explains geochemical changes at the crater fumaroles in terms of variable hydrothermal and magmatic contributions, and modified thermodynamic conditions.

Compilation of new and previously published geochemical and modal data for Mesoproterozoic igneous rocks of the St. Francois Mountains, southeast Missouri

USGS Publications Warehouse

du Bray, Edward A.; Day, Warren C.; Meighan, Corey J.

2018-04-16

The purpose of this report is to present recently acquired as well as previously published geochemical and modal petrographic data for igneous rocks in the St. Francois Mountains, southeast Missouri, as part of an ongoing effort to understand the regional geology and ore deposits of the Mesoproterozoic basement rocks of southeast Missouri, USA. The report includes geochemical data that is (1) newly acquired by the U.S. Geological Survey and (2) compiled from numerous sources published during the last fifty-five years. These data are required for ongoing petrogenetic investigations of these rocks. Voluminous Mesoproterozoic igneous rocks in the St. Francois Mountains of southeast Missouri constitute the basement buried beneath Paleozoic sedimentary rock that is over 600 meters thick in places. The Mesoproterozoic rocks of southeast Missouri represent a significant component of approximately 1.4 billion-year-old (Ga) igneous rocks that crop out extensively in North America along the southeast margin of Laurentia and subsequent researchers suggested that iron oxide-copper deposits in the St. Francois Mountains are genetically associated with ca. 1.4 Ga magmatism in this region. The geochemical and modal data sets described herein were compiled to support investigations concerning the tectonic setting and petrologic processes responsible for the associated magmatism.

Geochemical effects on the behavior of LLW radionuclides in soil/groundwater environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krupka, K.M.; Sterne, R.J.

1995-12-31

Assessing the migration potential of radionuclides leached from low-level radioactive waste (LLW) and decommissioning sites necessitates information on the effects of sorption and precipitation on the concentrations of dissolved radionuclides. Such an assessment requires that the geochemical processes of aqueous speciation, complexation, oxidation/reduction, and ion exchange be taken into account. The Pacific Northwest National Laboratory (PNNL) is providing technical support to the U.S. Nuclear Regulatory Commission (NRC) for defining the solubility and sorption behavior of radionuclides in soil/ground-water environments associated with engineered cementitious LLW disposal systems and decommissioning sites. Geochemical modeling is being used to predict solubility limits for radionuclidesmore » under geochemical conditions associated with these environments. The solubility limits are being used as maximum concentration limits in performance assessment calculations describing the release of contaminants from waste sources. Available data were compiled regarding the sorption potential of radionuclides onto {open_quotes}fresh{close_quotes} cement/concrete where the expected pH of the cement pore waters will equal to or exceed 10. Based on information gleaned from the literature, a list of preferred minimum distribution coefficients (Kd`s) was developed for these radionuclides. The K{sub d} values are specific to the chemical environments associated with the evolution of the compositions of cement/concrete pore waters.« less

Instrumenting caves to collect hydrologic and geochemical data: case study from James Cave, Virginia

USGS Publications Warehouse

Schreiber, Madeline E.; Schwartz, Benjamin F.; Orndorff, William; Doctor, Daniel H.; Eagle, Sarah D.; Gerst, Jonathan D.

2015-01-01

Karst aquifers are productive groundwater systems, supplying approximately 25 % of the world’s drinking water. Sustainable use of this critical water supply requires information about rates of recharge to karst aquifers. The overall goal of this project is to collect long-term, high-resolution hydrologic and geochemical datasets at James Cave, Virginia, to evaluate the quantity and quality of recharge to the karst system. To achieve this goal, the cave has been instrumented for continuous (10-min interval) measurement of the (1) temperature and rate of precipitation; (2) temperature, specific conductance, and rate of epikarst dripwater; (3) temperature of the cave air; and (4) temperature, conductivity, and discharge of the cave stream. Instrumentation has also been installed to collect both composite and grab samples of precipitation, soil water, the cave stream, and dripwater for geochemical analysis. This chapter provides detailed information about the instrumentation, data processing, and data management; shows examples of collected datasets; and discusses recommendations for other researchers interested in hydrologic and geochemical monitoring of cave systems. Results from the research, briefly described here and discussed in more detail in other publications, document a strong seasonality of the start of the recharge season, the extent of the recharge season, and the geochemistry of recharge.

Statistical geochemistry reveals disruption in secular lithospheric evolution about 2.5 Gyr ago.

PubMed

Keller, C Brenhin; Schoene, Blair

2012-05-23

The Earth has cooled over the past 4.5 billion years (Gyr) as a result of surface heat loss and declining radiogenic heat production. Igneous geochemistry has been used to understand how changing heat flux influenced Archaean geodynamics, but records of systematic geochemical evolution are complicated by heterogeneity of the rock record and uncertainties regarding selection and preservation bias. Here we apply statistical sampling techniques to a geochemical database of about 70,000 samples from the continental igneous rock record to produce a comprehensive record of secular geochemical evolution throughout Earth history. Consistent with secular mantle cooling, compatible and incompatible elements in basalts record gradually decreasing mantle melt fraction through time. Superimposed on this gradual evolution is a pervasive geochemical discontinuity occurring about 2.5 Gyr ago, involving substantial decreases in mantle melt fraction in basalts, and in indicators of deep crustal melting and fractionation, such as Na/K, Eu/Eu* (europium anomaly) and La/Yb ratios in felsic rocks. Along with an increase in preserved crustal thickness across the Archaean/Proterozoic boundary, these data are consistent with a model in which high-degree Archaean mantle melting produced a thick, mafic lower crust and consequent deep crustal delamination and melting--leading to abundant tonalite-trondhjemite-granodiorite magmatism and a thin preserved Archaean crust. The coincidence of the observed changes in geochemistry and crustal thickness with stepwise atmospheric oxidation at the end of the Archaean eon provides a significant temporal link between deep Earth geochemical processes and the rise of atmospheric oxygen on the Earth.

GEMAS: The Fennoscandian perspective

NASA Astrophysics Data System (ADS)

Katarzyna Ladenberger, Anna; Uhlbäck, Jo; Andersson, Madelen; Reimann, Clemens; Tarvainen, Timo; Sadeghi, Martiya; Morris, George; Eklund, Mikael

2014-05-01

The GEMAS Project (Geochemical Mapping of Agricultural and Grazing Land Soil in Europe) resulted in a large coherent data set displaying baseline levels of elements in agricultural and grazing land soil, on both a European and a regional scale. The geochemical mapping of agricultural and grazing land soil in Norway, Sweden and Finland revealed regional features, noticeably different from the general geochemical pattern in the rest of Europe. When looking at the European data set as a whole, Norway, Sweden and Finland stand out as geochemically distinct, mainly due to the old bedrock and the extent of the last glaciations. They were thus considered valuable for a study as a separate entity. The interpretation of element maps and statistics identified several factors responsible for the observed trends in the geochemical patterns in Norway, Sweden and Finland, with the most important factors being bedrock geology, the presence of ore deposits, the soil type and its properties, and climate. The soil of the Fennoscandian Shield is very young and the composition of parent material has a crucial influence on the soil chemical signature. On the other hand the occurrence of organic peaty soil and clayey varieties plays an important role in enrichment processes leading to enhanced levels of many elements. Anthropogenic impact on soils appears to have a minor influence on the soil geochemistry of both agricultural and grazing land. In mining regions, with the natural signal from the mineralisation, it is often difficult to discriminate between the original anomaly and any additional anthropogenic contamination. The results of this survey are available to the public and can be used by both local authorities and research groups.

Beyond the obvious limits of ore deposits: The use of mineralogical, geochemical, and biological features for the remote detection of mineralization

USGS Publications Warehouse

Kelley, D.L.; Kelley, K.D.; Coker, W.B.; Caughlin, B.; Doherty, M.E.

2006-01-01

Far field features of ore deposits include mineralogical, geochemical, or biological attributes that can be recognized beyond the obvious limits of the deposits. They can be primary, if formed in association with mineralization or alteration processes, or secondary, if formed from the interaction of ore deposits with the hydrosphere and biosphere. This paper examines a variety of far field features of different ore deposit types and considers novel applications to exploration and discovery. Primary far field features include mineral and rock chemistry, isotopic or element halos, fluid pathways and thermal anomalies in host-rock sequences. Examples include the use of apatite chemistry to distinguish intrusive rocks permissive for iron oxide copper gold (IOCG) and porphyry deposits; resistate mineral (e.g., rutile, tourmaline) chemistry in exploration for volcanogenic massive sulfide (VMS), orogenic gold, and porphyry deposits; and pyrite chemistry to vector toward sedimentary exhalative (sedex) deposits. Distinctive whole-rock geochemical signatures also can be recognized as a far field feature of porphyry deposits. For example, unique Sr/Y ratios in whole-rock samples, used to distinguish barren versus fertile magmas for Cu mineralization, result from the differentiation of oxidized hydrous melts. Anomalous concentrations of halogen elements (Cl, Br, and I) have been found for distances of up to 200 m away from some mineralized centers. Variations in isotopic composition between ore-bearing and barren intrusions and/or systematic vertical and lateral zonation in sulfur, carbon, or oxygen isotope values have been documented for some deposit types. Owing to the thermal aureole that extends beyond the area of mineralization for some deposits, detection of paleothermal effects through methods such as conodont alteration indices, vitrinite or bitumen reflectance, illite crystallinity, and apatite or zircon thermochronology studies also can be valuable, particularly for deposits with a low-temperature thermal history. A number of newly investigated secondary far field features include the development of reduced columns by electrochemical processes in transported overburden, geochemical dispersion related to the expulsion of groundwater from tectonic and seismic compression, dispersion of vapor above ore deposits, and geochemical dispersion related to biological processes. Redox gradients have been found between underlying reduced and overlying oxidized environments associated with sulfide bodies, which result in mass transfer through electro-chemical dispersion. Recent studies have characterized the pH, oxidation-reduction potential (ORP), and self potential (SP) in overburden overlying sulfide-hosted gold and VMS deposits. Lateral migration of metals in groundwater is well understood from normal groundwater flow, but the processes responsible for vertical mass transfer of groundwater and its dissolved components have been recognized only recently. One process, termed cyclical dilatancy pumping, expels groundwater during and after earthquake events, which can cause the redistribution of metals around deposits in some environments. Soil gases are of interest owing to their high degree of mobility through the vadose zone in transported overburden. Numerous soil gas species (CO2, O2, Hg, Rn, He, sulfur compounds, and light hydrocarbons) have been measured and interpreted as diagnostic of some buried mineral deposits, and some evidence suggests a possible link between vapor dispersion and metal enrichment in soil. Geochemical enrichment in plant material and soils through successive growth-death cycles is well established, but the important role of microorganisms is now increasingly evident. Microorganisms significantly enhance the kinetics of sulfide oxidation and influence the distribution of metals around ore deposits. The presence of metal-resistant bacteria and enhanced concentrations of sulfate-reducing bacteria in exotic overburd

Effects of thin-film accelerated carbonation on steel slag leaching.

PubMed

Baciocchi, R; Costa, G; Polettini, A; Pomi, R

2015-04-09

This paper discusses the effects of accelerated carbonation on the leaching behaviour of two types of stainless steel slags (electric arc furnace and argon oxygen decarburisation slag). The release of major elements and toxic metals both at the natural pH and at varying pH conditions was addressed. Geochemical modelling of the eluates was used to theoretically describe leaching and derive information about mineralogical changes induced by carbonation. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases; geochemical modelling indicated that the Ca/Si ratio of Ca-controlling minerals shifted from ∼ 1 for the untreated slag to 0.5-0.67 for the carbonated samples, thus showing that the carbonation process left some residual Ca-depleted silicate phases while the extracted Ca precipitated in the form of carbonate minerals. For toxic metals the changes in leaching induced by carbonation appeared to be mainly related to the resulting pH changes, which were as high as ∼ 2 orders of magnitude upon carbonation. Depending on the specific shape of the respective solubility curves, the extent of leaching of toxic metals from the slag was differently affected by carbonation. Copyright © 2014 Elsevier B.V. All rights reserved.

Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the iron mountain superfund site, California

USGS Publications Warehouse

Nordstrom, D. Kirk; Alpers, Charles N.

1999-01-01

The Richmond Mine of the Iron Mountain copper deposit contains some of the most acid mine waters ever reported. Values of pH have been measured as low as -3.6, combined metal concentrations as high as 200 g/liter, and sulfate concentrations as high as 760 g/liter. Copious quantities of soluble metal sulfate salts such as melanterite, chalcanthite, coquimbite, rhomboclase, voltaite, copiapite, and halotrichite have been identified, and some of these are forming from negative-pH mine waters. Geochemical calculations show that, under a mine-plugging remediation scenario, these salts would dissolve and the resultant 600,000-m3 mine pool would have a pH of 1 or less and contain several grams of dissolved metals per liter, much like the current portal effluent water. In the absence of plugging or other at-source control, current weathering rates indicate that the portal effluent will continue for approximately 3,000 years. Other remedial actions have greatly reduced metal loads into downstream drainages and the Sacramento River, primarily by capturing the major acidic discharges and routing them to a lime neutralization plant. Incorporation of geochemical modeling and mineralogical expertise into the decision-making process for remediation can save time, save money, and reduce the likelihood of deleterious consequences.

High contents of rare earth elements (REEs) in stream waters of a Cu-Pb-Zn mining area.

PubMed

Protano, G; Riccobono, F

2002-01-01

Stream waters draining an old mining area present very high rare earth element (REE) contents, reaching 928 microg/l as the maximum total value (sigmaREE). The middle rare earth elements (MREEs) are usually enriched with respect to both the light (LREEs) and heavy (HREEs) elements of this group, producing a characteristic "roof-shaped" pattern of the shale Post-Archean Australian Shales-normalized concentrations. At the Fenice Capanne Mine (FCM), the most important base metal mine of the study area, the REE source coincides with the mine tailings, mostly the oldest ones composed of iron-rich materials. The geochemical history of the REEs released into Noni stream from wastes in the FCM area is strictly determined by the pH, which controls the REE speciation and in-stream processes. The formation of Al-rich and mainly Fe-rich flocs effectively scavenges the REEs, which are readily and drastically removed from the solution when the pH approaches neutrality. Leaching experiments performed on flocs and waste materials demonstrate that Fe-oxides/oxyhydroxides play a key role in the release of lanthanide elements into stream waters. The origin of the "roof-shaped" REE distribution pattern as well as the peculiar geochemical behavior of some lanthanide elements in the aqueous system are discussed.

Solid phase evolution in the Biosphere 2 hillslope experiment as predicted by modeling of hydrologic and geochemical fluxes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dontsova, K.; Steefel, C.I.; Desilets, S.

2009-07-15

A reactive transport geochemical modeling study was conducted to help predict the mineral transformations occurring over a ten year time-scale that are expected to impact soil hydraulic properties in the Biosphere 2 (B2) synthetic hillslope experiment. The modeling sought to predict the rate and extent of weathering of a granular basalt (selected for hillslope construction) as a function of climatic drivers, and to assess the feedback effects of such weathering processes on the hydraulic properties of the hillslope. Flow vectors were imported from HYDRUS into a reactive transport code, CrunchFlow2007, which was then used to model mineral weathering coupled tomore » reactive solute transport. Associated particle size evolution was translated into changes in saturated hydraulic conductivity using Rosetta software. We found that flow characteristics, including velocity and saturation, strongly influenced the predicted extent of incongruent mineral weathering and neo-phase precipitation on the hillslope. Results were also highly sensitive to specific surface areas of the soil media, consistent with surface reaction controls on dissolution. Effects of fluid flow on weathering resulted in significant differences in the prediction of soil particle size distributions, which should feedback to alter hillslope hydraulic conductivities.« less

Source and dynamics of a volcanic caldera unrest: Campi Flegrei, 1983-84.

PubMed

De Siena, Luca; Chiodini, Giovanni; Vilardo, Giuseppe; Del Pezzo, Edoardo; Castellano, Mario; Colombelli, Simona; Tisato, Nicola; Ventura, Guido

2017-08-14

Despite their importance for eruption forecasting the causes of seismic rupture processes during caldera unrest are still poorly reconstructed from seismic images. Seismic source locations and waveform attenuation analyses of earthquakes in the Campi Flegrei area (Southern Italy) during the 1983-1984 unrest have revealed a 4-4.5 km deep NW-SE striking aseismic zone of high attenuation offshore Pozzuoli. The lateral features and the principal axis of the attenuation anomaly correspond to the main source of ground uplift during the unrest. Seismic swarms correlate in space and time with fluid injections from a deep hot source, inferred to represent geochemical and temperature variations at Solfatara. These swarms struck a high-attenuation 3-4 km deep reservoir of supercritical fluids under Pozzuoli and migrated towards a shallower aseismic deformation source under Solfatara. The reservoir became aseismic for two months just after the main seismic swarm (April 1, 1984) due to a SE-to-NW directed input from the high-attenuation domain, possibly a dyke emplacement. The unrest ended after fluids migrated from Pozzuoli to the location of the last caldera eruption (Mt. Nuovo, 1538 AD). The results show that the high attenuation domain controls the largest monitored seismic, deformation, and geochemical unrest at the caldera.

Geochemical and Hydrologic Factors Controlling Subsurface Transport of Poly- and Perfluoroalkyl Substances, Cape Cod, Massachusetts.

PubMed

Weber, Andrea K; Barber, Larry B; LeBlanc, Denis R; Sunderland, Elsie M; Vecitis, Chad D

2017-04-18

Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was to investigate geochemical and hydrological processes governing the subsurface transport of PFASs at a former fire training area (FTA) on Cape Cod, Massachusetts, where PFAS-containing aqueous film-forming foams were used historically. A total of 148 groundwater samples and 4 sediment cores were collected along a 1200-m-long downgradient transect originating near the FTA and analyzed for PFAS content. The results indicate that unsaturated zones at the FTA and at hydraulically downgradient former domestic wastewater effluent infiltration beds both act as continuous PFAS sources to the groundwater despite 18 and 20 years of inactivity, respectively. Historically different PFAS sources are evident from contrasting PFAS composition near the water table below the FTA and wastewater-infiltration beds. Results from total oxidizable precursor assays conducted using groundwater samples collected throughout the plume suggest that some perfluoroalkyl acid precursors at this site are transporting with perfluoroalkyl acids.

Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California

PubMed Central

Nordstrom, D. Kirk; Alpers, Charles N.

1999-01-01

The Richmond Mine of the Iron Mountain copper deposit contains some of the most acid mine waters ever reported. Values of pH have been measured as low as −3.6, combined metal concentrations as high as 200 g/liter, and sulfate concentrations as high as 760 g/liter. Copious quantities of soluble metal sulfate salts such as melanterite, chalcanthite, coquimbite, rhomboclase, voltaite, copiapite, and halotrichite have been identified, and some of these are forming from negative-pH mine waters. Geochemical calculations show that, under a mine-plugging remediation scenario, these salts would dissolve and the resultant 600,000-m3 mine pool would have a pH of 1 or less and contain several grams of dissolved metals per liter, much like the current portal effluent water. In the absence of plugging or other at-source control, current weathering rates indicate that the portal effluent will continue for approximately 3,000 years. Other remedial actions have greatly reduced metal loads into downstream drainages and the Sacramento River, primarily by capturing the major acidic discharges and routing them to a lime neutralization plant. Incorporation of geochemical modeling and mineralogical expertise into the decision-making process for remediation can save time, save money, and reduce the likelihood of deleterious consequences. PMID:10097057

Geochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts

USGS Publications Warehouse

Weber, Andrea K.; Barber, Larry B.; LeBlanc, Denis R.; Sunderland, Elsie M.; Vecitis, Chad D.

2017-01-01

Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was to investigate geochemical and hydrological processes governing the subsurface transport of PFASs at a former fire training area (FTA) on Cape Cod, Massachusetts, where PFAS-containing aqueous film-forming foams were used historically. A total of 148 groundwater samples and 4 sediment cores were collected along a 1200-m-long downgradient transect originating near the FTA and analyzed for PFAS content. The results indicate that unsaturated zones at the FTA and at hydraulically downgradient former domestic wastewater effluent infiltration beds both act as continuous PFAS sources to the groundwater despite 18 and 20 years of inactivity, respectively. Historically different PFAS sources are evident from contrasting PFAS composition near the water table below the FTA and wastewater-infiltration beds. Results from total oxidizable precursor assays conducted using groundwater samples collected throughout the plume suggest that some perfluoroalkyl acid precursors at this site are transporting with perfluoroalkyl acids.

Tracing water and suspended matter in Raritan and Lower New York Bays using dissolved and particulate elemental concentrations

USGS Publications Warehouse

Paulson, A.J.

2005-01-01

The concentrations of 22 elements also were measured in the suspended matter of Raritan and Lower New York Bays and brackish water sources. The elemental composition of the suspended matter in surface and bottom waters was correlated with Fe concentrations, which ranged between 50 and 900 μmol g− 1. Statistical differences among the geographical regions were detected in the relationships of Ti, Ni, Co, As, and U with Fe, with particulate As being an especially strong geochemical indicator of Raritan River particles. The geochemical signatures of Lower New York Bay particles were similar to those of Upper New York Bay. The geochemical signatures of Raritan River particles were distinctly different than those of the Upper New York Bay, but the influence of Raritan River particles appeared to be limited to only inner Raritan Bay. This study illustrates the utility of trace elements for characterization of physical processes in complex estuaries.

GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

DOE PAGES

Ostertag-Henning, C.; Risse, A.; Thomas, B.; ...

2014-12-31

Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

Orbital forcing of climate 1.4 billion years ago.

PubMed

Zhang, Shuichang; Wang, Xiaomei; Hammarlund, Emma U; Wang, Huajian; Costa, M Mafalda; Bjerrum, Christian J; Connelly, James N; Zhang, Baomin; Bian, Lizeng; Canfield, Donald E

2015-03-24

Fluctuating climate is a hallmark of Earth. As one transcends deep into Earth time, however, both the evidence for and the causes of climate change become difficult to establish. We report geochemical and sedimentological evidence for repeated, short-term climate fluctuations from the exceptionally well-preserved ∼1.4-billion-year-old Xiamaling Formation of the North China Craton. We observe two patterns of climate fluctuations: On long time scales, over what amounts to tens of millions of years, sediments of the Xiamaling Formation record changes in geochemistry consistent with long-term changes in the location of the Xiamaling relative to the position of the Intertropical Convergence Zone. On shorter time scales, and within a precisely calibrated stratigraphic framework, cyclicity in sediment geochemical dynamics is consistent with orbital control. In particular, sediment geochemical fluctuations reflect what appear to be orbitally forced changes in wind patterns and ocean circulation as they influenced rates of organic carbon flux, trace metal accumulation, and the source of detrital particles to the sediment.

Seasonal Drivers of Dissolved Metal Transport During Infiltration of Road Runoff in an Urban Roadside Environment

NASA Astrophysics Data System (ADS)

Mullins, A.; Bain, D.

2017-12-01

Infiltration-based green infrastructure (GI) is being increasingly applied in urban areas, systems characterized by substantial legacy contamination and complicated hydrology. However, it is not clear how the application of green infrastructure changes the geochemistry of urban roadside environments. Most current research on GI focuses on small sets of chemical parameters (e.g. road salt, nitrogen and phosphorous species) over relatively short time periods, limiting comprehensive understanding of geochemical function. This work measures changes in groundwater infiltration rate and dissolved metal concentrations in two infiltration trenches in Pittsburgh, PA to evaluate function and measure dissolved metal transport from the system over time. Two distinct geochemical regimes seem to be driven by seasonality: road de-icer exchange and microbial driven summer reducing conditions. Interactions between these geochemical regimes and variability in infiltration rate control the flux of different metals, varying with metal chemistry. These findings suggest the adoption of infiltration based green infrastructure will likely create complicated patterns of legacy contamination transport to downstream receptors.

Geochemical differences of magnetite from the Algoma- and Superior- type banded iron formations based on in situ LA-ICP-MS analysis

NASA Astrophysics Data System (ADS)

Moon, I.; Lee, I.; Park, J. W.; Yang, X.

2017-12-01

Precambrian banded iron formations (BIFs) have been highly attractive study issues for decades about their genesis. Recently, more detailed geochemical studies have been conducted on mineral chemistry of magnetite using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Magnetite geochemistry enables us to constrain the physicochemical controlling factors for abundance of trace elements in magnetite and understand depositional environment of BIFs. In this study, we provide results of magnetite trace elemental features from two representative types of BIFs which are Algoma- and Superior- type BIF in the world, with aims to understand systematic differences in magnetite compositions between Algoma- and Superior- type BIF. The magnetites are divided into two groups according to their Al, Mn, Ti, V, and Ni concentration. The magnetites from the Algoma-type BIFs are more enriched in trace elements than those from the Superior-type. The geochemical differences are caused by difference precipitation condition including oxygen fugacity, temperature and fluid source.

Geochemical and Isotopic Evidences of the Magmatic Sources in the Eastern Sector of the Trans-Mexican Volcanic Belt: Xihuingo-Chichicuautla Volcanic Field

NASA Astrophysics Data System (ADS)

Valadez, S.; Martinez-serrano, R.; Juarez-Lopez, K.; Solis-Pichardo, G.; Perez-Arvizu, O.

2011-12-01

The study of magmatism in the Trans-Mexican Volcanic Belt (TMVB) has great importance due to several features such as its obliquity with respect to the Middle American Trench and its petrological and geochemical variability, which are not common in most typical volcanic arcs. Although several papers have contributed significantly to the understanding of most important magmatic processes in this province, there are still several questions such as the characterization of magmatic sources. In the present work, we provide new stratigraphic, petrographic, geochemical and Sr, Nd and Pb isotopic data as well as some K-Ar age determinations from the Xihuingo-Chichicuautla volcanic field (XCVF), located at the eastern part of the TMVB, with the aim to identify the magmatic sources that produced the main volcanic rocks. The volcanic structures in the XCVF are divided in two main groups according to the petrographic and geochemical compositions: 1) dacitic domes, andesitic lava flows and some dacitic-rhyolitic ignimbrites and 2) scoria cones, shield volcanoes and associated lava flows of basalt to basaltic-andesite composition. Distribution of most volcanic structures is probably controlled by NE-SW fault and fractures system. This fault system was studied by other authors who established that volcanic activity started ca. 13.5 Ma ago, followed by a volcanic hiatus of ca. 10 Ma, and the late volcanic activity began ca. 3 to 1 Ma. In this work we dated 2 rock samples by K-Ar method, which yielded ages of 402 and 871 Ka, which correspond to the most recent volcanic activity in this study area. The volcanic rocks of the XCVF display compositions from basalts to rhyolites but in general all rocks show trace element patterns typical of magmatic arcs. However, we can identify two main magmatic sources: a depleted magmatic source represented by dacitic-andesitic rocks which present a LILE enrichment with respect to HFSE indicating that a magmatic source was modified by fluids derived from the subduction processes. These magmas probably suffered fractional crystallization and minor assimilation in the continental crust. Sr, Nd isotopic compositions for this first group display the most radiogenic values (87Sr/86Sr from 0.7046 to 0.7047 and ɛNd from 2.2 to 2.8). The second source for the basaltic-andesite and basalt could be associated with an enriched mantle. These rocks present a minor LILE enrichment with respect to HSFE, and Sr and Nd isotopic values less radiogenic than the felsic rocks of the first group (87Sr/86Sr from 0.7040 to 0.7045 and ɛNd from 3.1 to 4.8). According to these evidences we can establish that the magmas emplaced in the study area were produced from a heterogeneous mantle source with complex magmatic processes combined with different interaction degrees between the magmas and continental crust.

Compositional variation within thick (>10 m) flow units of Mauna Kea Volcano cored by the Hawaii Scientific Drilling Project

NASA Astrophysics Data System (ADS)

Huang, Shichun; Vollinger, Michael J.; Frey, Frederick A.; Rhodes, J. Michael; Zhang, Qun

2016-07-01

Geochemical analyses of stratigraphic sequences of lava flows are necessary to understand how a volcano works. Typically one sample from each lava flow is collected and studied with the assumption that this sample is representative of the flow composition. This assumption may not be valid. The thickness of flows ranges from <1 to >100 m. Geochemical heterogeneity in thin flows may be created by interaction with the surficial environment whereas magmatic processes occurring during emplacement may create geochemical heterogeneities in thick flows. The Hawaii Scientific Drilling Project (HSDP) cored ∼3.3 km of basalt erupted at Mauna Kea Volcano. In order to determine geochemical heterogeneities in a flow, multiple samples from four thick (9.3-98.4 m) HSDP flow units were analyzed for major and trace elements. We found that major element abundances in three submarine flow units are controlled by the varying proportion of olivine, the primary phenocryst phase in these samples. Post-magmatic alteration of a subaerial flow led to loss of SiO2, CaO, Na2O, K2O and P2O5, and as a consequence, contents of immobile elements, such as Fe2O3 and Al2O3, increase. The mobility of SiO2 is important because Mauma Kea shield lavas divide into two groups that differ in SiO2 content. Post-magmatic mobility of SiO2 adds complexity to determining if these groups reflect differences in source or process. The most mobile elements during post-magmatic subaerial and submarine alteration are K and Rb, and Ba, Sr and U were also mobile, but their abundances are not highly correlated with K and Rb. The Ba/Th ratio has been used to document an important role for a plagioclase-rich source component for basalt from the Galapagos, Iceland and Hawaii. Although Ba/Th is anomalously high in Hawaiian basalt, variation in Ba abundance within a single flow shows that it is not a reliable indicator of a deep source component. In contrast, ratios involving elements that are typically immobile, such as La/Nb, La/Th, Nb/Th, Ce/Pb, Sr/Nd, La/Sm, Sm/Yb, Nb/Zr, Nb/Y and La/Yb, are uniform within the units, and they can be used to constrain petrogenetic processes. Nevertheless all elements are mobile under some conditions. For example, a surprising result is that relative to other samples, the uppermost sample collected from subaerial flow Unit 70, less than 1 m below the flow surface, is depleted in P, HREE and Y relative to all other samples from this flow unit. This result is complementary to the P, REE and Y enrichment found in subaerial lava flows from several Hawaiian shields, e.g., Kahoolawe and Koolau Volcanoes. These enrichments require mobilization of REE and followed by deposition a P-rich mineral.

A Spatially Constrained Multi-autoencoder Approach for Multivariate Geochemical Anomaly Recognition

NASA Astrophysics Data System (ADS)

Lirong, C.; Qingfeng, G.; Renguang, Z.; Yihui, X.

2017-12-01

Separating and recognizing geochemical anomalies from the geochemical background is one of the key tasks in geochemical exploration. Many methods have been developed, such as calculating the mean ±2 standard deviation, and fractal/multifractal models. In recent years, deep autoencoder, a deep learning approach, have been used for multivariate geochemical anomaly recognition. While being able to deal with the non-normal distributions of geochemical concentrations and the non-linear relationships among them, this self-supervised learning method does not take into account the spatial heterogeneity of geochemical background and the uncertainty induced by the randomly initialized weights of neurons, leading to ineffective recognition of weak anomalies. In this paper, we introduce a spatially constrained multi-autoencoder (SCMA) approach for multivariate geochemical anomaly recognition, which includes two steps: spatial partitioning and anomaly score computation. The first step divides the study area into multiple sub-regions to segregate the geochemical background, by grouping the geochemical samples through K-means clustering, spatial filtering, and spatial constraining rules. In the second step, for each sub-region, a group of autoencoder neural networks are constructed with an identical structure but different initial weights on neurons. Each autoencoder is trained using the geochemical samples within the corresponding sub-region to learn the sub-regional geochemical background. The best autoencoder of a group is chosen as the final model for the corresponding sub-region. The anomaly score at each location can then be calculated as the euclidean distance between the observed concentrations and reconstructed concentrations of geochemical elements.The experiments using the geochemical data and Fe deposits in the southwestern Fujian province of China showed that our SCMA approach greatly improved the recognition of weak anomalies, achieving the AUC of 0.89, compared with the AUC of 0.77 using a single deep autoencoder approach.

Inferences from Microfractures and Geochemistry in Dynamic Shale-CO2 Packed Bed Experiments

NASA Astrophysics Data System (ADS)

Radonjic, M.; Olabode, A.

2016-12-01

Subsurface storage of large volumes of carbondioxide (CO2) is expected to have long term rock-fluid interactions impact on reservoir and seal rocks properties. Caprocks, particularly sedimentary types, are the ultimate hydraulic barrier in carbon sequestration. The mineralogical components of sedimentary rocks are geochemically active under enormous earth stresses, which generate high pressure and temperature conditions. It has been postulated that in-situ mineralization can lead to flow impedance in natural fractures in the presence of favorable geochemical and thermodynamic conditions. This experimental modelling research investigated the impact of in-situ geochemical precipitation on conductivity of fractures. Geochemical analyses were performed on four different samples of shale rocks, effluent fluids and recovered precipitates both before and after CO2-brine flooding of crushed shale rocks at moderately high temperature and pressure conditions. The results showed that most significant diagenetic changes in shale rocks after flooding with CO2-brine, reflected in the effluent fluid with predominantly calcium based minerals dissolving and precipitating under experimental conditions. Major and trace elements in the effluent (using ICP-OES analysis) indicated that multiple geochemical reactions are occurring with almost all of the constituent minerals participating. The geochemical composition of precipitates recovered after the experiments showed diagenetic carbonates and opal as the main constituents. The bulk rock showed little changes in composition except for sharper and more refined peaks on XRD analysis, suggesting that a significant portion of the amorphous content of the rocks have been removed via dissolution by the slightly acid CO2-brine fluid that was injected. Micro-indentation results captured slight reduction in the hardness of the shale rocks and this reduction appeared dependent on diagenetic quartz content. It can be inferred that convective reactive transport of dissolved minerals are involved in nanoscale precipitation-dissolution processes in shale. This reactive transport of dissolved minerals can occlude micro-fracture flow paths, thereby improving shale caprock seal integrity with respect to leakage risk under CO2 sequestration conditions.

Merging Hydrologic, Geochemical, and Geophysical Approaches to Understand the Regolith Architecture of a Deeply Weathered Piedmont Critical Zone

NASA Astrophysics Data System (ADS)

Cosans, C.; Moore, J.; Harman, C. J.

2017-12-01

Located in the deeply weathered Piedmont in Maryland, Pond Branch has a rich legacy of hydrological and geochemical research dating back to the first geochemical mass balance study published in 1970. More recently, geophysical investigations including seismic and electrical resistivity tomography have characterized the subsurface at Pond Branch and contributed to new hypotheses about critical zone evolution. Heterogeneity in electrical resistivity in the shallow subsurface may suggest disparate flow paths for recharge, with some regions with low hydraulic conductivity generating perched flow, while other hillslope sections recharge to the much deeper regolith boundary. These shallow and deep flow paths are hypothesized to be somewhat hydrologically and chemically connected, with the spatially and temporally discontinuous connections resulting in different hydraulic responses to recharge and different concentrations of weathering solutes. To test this hypothesis, we combined modeling and field approaches. We modeled weathering solutes along the hypothesized flow paths using PFLOTRAN. We measured hydrologic gradients in the hillslopes and riparian zone using piezometer water levels. We collected geochemical data including major ions and silica. Weathering solute concentrations were measured directly in the precipitation, hillslope springs, and the riparian zone for comparison to modeled concentration values. End member mixing methods were used to determine contributions of precipitation, hillslopes, and riparian zone to the stream. Combining geophysical, geochemical, and hydrological methods may offer insights into the source of stream water and controls on chemical weathering. Previous hypotheses that Piedmont critical zone architecture results from a balance of erosion, soil, and weathering front advance rates cannot account for the inverted regolith structure observed through seismic investigations at Pond Branch. Recent alternative hypotheses including weathering along tectonically-induced fractures and weathering front advance have been proposed, but additional data are needed to test them. Developing a thorough, nuanced understanding of the geochemical and hydrological behavior of Pond Branch may help test and refine hypotheses for Piedmont critical zone evolution.

Assessment of CO2-Induced Geochemical Changes in Soil/Mineral-Water Systems

NASA Astrophysics Data System (ADS)

Jeong, H. Y.; Choi, H. J.

2016-12-01

Although the storage of CO2 in deep geological formations is considered the most promising sequestration path, there is still a risk that it may leak into the atmosphere. To ensure the secure operation of CO2 storage sites, thus, it is necessary to implement CO2 leakage monitoring systems. Furthermore, the leakage may alter geochemical properties of overlying geological units to have adverse environmental consequences. By elucidating geochemical changes due to CO2 leakage, it is possible to develop effective CO2 monitoring techniques and predict the influence of CO2 leakage. A series of batch experiments were conducted to simulate CO2-induced geochemical changes in soil/mineral-water systems. Soil samples, obtained from Eumseong basin in Eumseong-gun, Chungcheongbuk-do, were dried for 6 hours at 60° and then divided into two size fractions: < 106 and 106-212 mm. Minerals including mica/illite, vermiculite, and feldspar were purchased and purified if necessary. Prior to batch experiments, soils and minerals were characterized for surface area, mineralogy, elemental composition, carbon and nitrogen contents, pH buffering capacity, and metal extractability. Batch experiments were initiated by reacting 100% CO2 atmosphere with aqueous suspensions of 120 g soils or 50 g minerals in 3,000 mL of 10 mM CsClO4 at room temperature. In parallel, the batches having the same soil/mineral compositions were run under the ambient air as controls. To prevent microbial activities, all batches were sterilized with 0.03% HCHO. To track geochemical changes, pH and electrical conductivity were monitored. Also, while solutions were regularly sampled and analyzed for trace metals as well as main cations and anions, solid phases were sampled to observe changes in mineralogical compositions. Geochemical changes in both solution and solid phases during the initial 6 month reaction will be presented. Acknowledgement: The "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003).

Review of simulation techniques for Aquifer Thermal Energy Storage (ATES)

NASA Astrophysics Data System (ADS)

Mercer, J. W.; Faust, C. R.; Miller, W. J.; Pearson, F. J., Jr.

1981-03-01

The analysis of aquifer thermal energy storage (ATES) systems rely on the results from mathematical and geochemical models. Therefore, the state-of-the-art models relevant to ATES were reviewed and evaluated. These models describe important processes active in ATES including ground-water flow, heat transport (heat flow), solute transport (movement of contaminants), and geochemical reactions. In general, available models of the saturated ground-water environment are adequate to address most concerns associated with ATES; that is, design, operation, and environmental assessment. In those cases where models are not adequate, development should be preceded by efforts to identify significant physical phenomena and relate model parameters to measurable quantities.

Geochemical processes controlling the distribution and concentration of metals in soils from a Patagonian (Argentina) salt marsh affected by mining residues.

PubMed

Idaszkin, Yanina L; Alvarez, María Del Pilar; Carol, Eleonora

2017-10-15

Heavy metal pollution that affects salt marshes is a major environmental concern due to its toxic nature, persistence, and potential risk to organisms and to human health. Mining waste deposits originated four decades ago, by the metallurgical extraction of heavy metals, are found near to the San Antonio salt marsh in Patagonia. The aim of the work was to determine the geochemical processes that control the distribution and concentration of Cu, Fe, Pb and Zn in the soils of this Patagonian salt marsh. A survey of the mining waste deposits was carried out where three dumps were identified. Samples were collected to determine soil texture, Eh pH, organic matter and metal contents and the soil mineralogical composition. The results shows that the soils developed over the mining waste deposits are predominantly reddish constituted mainly by iron oxide, hydroxide and highly soluble minerals such as Zn and Cu sulphates. The drainage from these deposits tends to move towards the salt marsh. Within the salt marsh, the highest concentrations of Cu, Pb and Zn occur in the sectors closest to the mining wastes deposits. The sulphide oxidation and the dissolution of the Cu, Pb and Zn sulphates could be the mainly source of these metals in the drainage water. The metals in solution that reach the salt marsh, are adsorbed by the organic matter and the fine fraction of the soils. These adsorbed metals are then remobilized by tides in the lower sectors of the marsh by desorption from the cations present in the tidal flow. On the other hand, Fe tends to form non soluble oxides, hydroxides and sulphates which remain as altering material within the mining waste deposit. Finally, the heavy metal pollutants recorded in the San Antonio salt marsh shows that the mining waste deposits that were abandoned four decades ago are still a source metal contamination. Copyright © 2017 Elsevier B.V. All rights reserved.

Investigating ebullition in a sand column using dissolved gas analysis and reactive transport modeling

USGS Publications Warehouse

Amos, Richard T.; Mayer, K. Ulrich

2006-01-01

Ebullition of gas bubbles through saturated sediments can enhance the migration of gases through the subsurface, affect the rate of biogeochemical processes, and potentially enhance the emission of important greenhouse gases to the atmosphere. To better understand the parameters controlling ebullition, methanogenic conditions were produced in a column experiment and ebullition through the column was monitored and quantified through dissolved gas analysis and reactive transport modeling. Dissolved gas analysis showed rapid transport of CH4 vertically through the column at rates several times faster than the bromide tracer and the more soluble gas CO2, indicating that ebullition was the main transport mechanism for CH4. An empirically derived formulation describing ebullition was integrated into the reactive transport code MIN3P allowing this process to be investigated on the REV scale in a complex geochemical framework. The simulations provided insights into the parameters controlling ebullition and show that, over the duration of the experiment, 36% of the CH4 and 19% of the CO2 produced were transported to the top of the column through ebullition.

Environmental tracers for elucidating the weathering process in a phosphogypsum disposal site: Implications for restoration

NASA Astrophysics Data System (ADS)

Pérez-López, Rafael; Nieto, José M.; de la Rosa, Jesús D.; Bolívar, Juan P.

2015-10-01

This study provides geochemical data with the aim of identifying and tracing the weathering of phosphogypsum wastes stack-piled directly on salt-marshes of the Tinto River (Estuary of Huelva, SW Spain). With that purpose, different types of highly-polluted acid solutions were collected in the stack. Connection between these solutions and the estuarine environment was studied by geochemical tracers, such as rare earth elements (REE) and their North American Shale Composite (NASC)-normalized patterns and Cl/Br ratios. Phosphogypsum-related wastewaters include process water stored on the surface, pore-water contained in the phosphogypsum profile and edge outflow water emerging from inside the stack. Edge outflow waters are produced by waterlogging at the contact between phosphogypsum and the nearly impermeable marsh surface and discharge directly into the estuary. Process water shows geochemical characteristics typical of phosphate fertilizers, i.e. REE patterns with an evident enrichment of heavy-REE (HREE) with respect to middle-REE (MREE) and light-REE (LREE). By contrast, REE patterns of deeper pore-water and edge outflows are identical to those of Tinto River estuary waters, with a clear enrichment of MREE relative to LREE and HREE denoting influence of acid mine drainage. Cl/Br ratios of these solutions are very close to that of seawater, which also supports its estuarine origin. These findings clearly show that process water is not chemically connected with edge outflows through pore-waters, as was previously believed. Phosphogypsum weathering likely occurs by an upward flow of seawater from the marsh because of overpressure and permeability differences. Several recommendations are put forward in this study to route restoration actions, such as developing treatment systems to improve the quality of the edge outflow waters before discharging to the receiving environment.

Numerical simulation of in-situ chemical oxidation (ISCO) and biodegradation of petroleum hydrocarbons using a coupled model for bio-geochemical reactive transport

NASA Astrophysics Data System (ADS)

Marin, I. S.; Molson, J. W.

2013-05-01

Petroleum hydrocarbons (PHCs) are a major source of groundwater contamination, being a worldwide and well-known problem. Formed by a complex mixture of hundreds of organic compounds (including BTEX - benzene, toluene, ethylbenzene and xylenes), many of which are toxic and persistent in the subsurface and are capable of creating a serious risk to human health. Several remediation technologies can be used to clean-up PHC contamination. In-situ chemical oxidation (ISCO) and intrinsic bioremediation (IBR) are two promising techniques that can be applied in this case. However, the interaction of these processes with the background aquifer geochemistry and the design of an efficient treatment presents a challenge. Here we show the development and application of BIONAPL/Phreeqc, a modeling tool capable of simulating groundwater flow, contaminant transport with coupled biological and geochemical processes in porous or fractured porous media. BIONAPL/Phreeqc is based on the well-tested BIONAPL/3D model, using a powerful finite element simulation engine, capable of simulating non-aqueous phase liquid (NAPL) dissolution, density-dependent advective-dispersive transport, and solving the geochemical and kinetic processes with the library Phreeqc. To validate the model, we compared BIONAPL/Phreeqc with results from the literature for different biodegradation processes and different geometries, with good agreement. We then used the model to simulate the behavior of sodium persulfate (NaS2O8) as an oxidant for BTEX degradation, coupled with sequential biodegradation in a 2D case and to evaluate the effect of inorganic geochemistry reactions. The results show the advantages of a treatment train remediation scheme based on ISCO and IBR. The numerical performance and stability of the integrated BIONAPL/Phreeqc model was also verified.

Quantification of CO2 generation in sedimentary basins through carbonate/clays reactions with uncertain thermodynamic parameters

NASA Astrophysics Data System (ADS)

Ceriotti, G.; Porta, G. M.; Geloni, C.; Dalla Rosa, M.; Guadagnini, A.

2017-09-01

We develop a methodological framework and mathematical formulation which yields estimates of the uncertainty associated with the amounts of CO2 generated by Carbonate-Clays Reactions (CCR) in large-scale subsurface systems to assist characterization of the main features of this geochemical process. Our approach couples a one-dimensional compaction model, providing the dynamics of the evolution of porosity, temperature and pressure along the vertical direction, with a chemical model able to quantify the partial pressure of CO2 resulting from minerals and pore water interaction. The modeling framework we propose allows (i) estimating the depth at which the source of gases is located and (ii) quantifying the amount of CO2 generated, based on the mineralogy of the sediments involved in the basin formation process. A distinctive objective of the study is the quantification of the way the uncertainty affecting chemical equilibrium constants propagates to model outputs, i.e., the flux of CO2. These parameters are considered as key sources of uncertainty in our modeling approach because temperature and pressure distributions associated with deep burial depths typically fall outside the range of validity of commonly employed geochemical databases and typically used geochemical software. We also analyze the impact of the relative abundancy of primary phases in the sediments on the activation of CCR processes. As a test bed, we consider a computational study where pressure and temperature conditions are representative of those observed in real sedimentary formation. Our results are conducive to the probabilistic assessment of (i) the characteristic pressure and temperature at which CCR leads to generation of CO2 in sedimentary systems, (ii) the order of magnitude of the CO2 generation rate that can be associated with CCR processes.

Parameter Sensitivity and Laboratory Benchmarking of a Biogeochemical Process Model for Enhanced Anaerobic Dechlorination

NASA Astrophysics Data System (ADS)

Kouznetsova, I.; Gerhard, J. I.; Mao, X.; Barry, D. A.; Robinson, C.; Brovelli, A.; Harkness, M.; Fisher, A.; Mack, E. E.; Payne, J. A.; Dworatzek, S.; Roberts, J.

2008-12-01

A detailed model to simulate trichloroethene (TCE) dechlorination in anaerobic groundwater systems has been developed and implemented through PHAST, a robust and flexible geochemical modeling platform. The approach is comprehensive but retains flexibility such that models of varying complexity can be used to simulate TCE biodegradation in the vicinity of nonaqueous phase liquid (NAPL) source zones. The complete model considers a full suite of biological (e.g., dechlorination, fermentation, sulfate and iron reduction, electron donor competition, toxic inhibition, pH inhibition), physical (e.g., flow and mass transfer) and geochemical processes (e.g., pH modulation, gas formation, mineral interactions). Example simulations with the model demonstrated that the feedback between biological, physical, and geochemical processes is critical. Successful simulation of a thirty-two-month column experiment with site soil, complex groundwater chemistry, and exhibiting both anaerobic dechlorination and endogenous respiration, provided confidence in the modeling approach. A comprehensive suite of batch simulations was then conducted to estimate the sensitivity of predicted TCE degradation to the 36 model input parameters. A local sensitivity analysis was first employed to rank the importance of parameters, revealing that 5 parameters consistently dominated model predictions across a range of performance metrics. A global sensitivity analysis was then performed to evaluate the influence of a variety of full parameter data sets available in the literature. The modeling study was performed as part of the SABRE (Source Area BioREmediation) project, a public/private consortium whose charter is to determine if enhanced anaerobic bioremediation can result in effective and quantifiable treatment of chlorinated solvent DNAPL source areas. The modelling conducted has provided valuable insight into the complex interactions between processes in the evolving biogeochemical systems, particularly at the laboratory scale.

Geochemistry of organic carbon and trace elements in boreal stratified lakes during different seasons

NASA Astrophysics Data System (ADS)

Moreva, O. Y.; Pokrovsky, O. S.; Shirokova, L. S.; Viers, J.

2008-12-01

Our knowledge of chemical fluxes in the system rock-soils-rivers-ocean of boreal and glacial landscapes is limited by the least studied part, i.e., the river water transformation between the lake and the river systems. Dissolved organic carbon (DOC), nutrients, major and trace elements are being leached from soil profile to the river but subjected to chemical transformation in the lakes due to phytoplankton and bacterial activity. As a result, many lakes in boreal regions are quite different in chemical composition compared to surrounding rivers and demonstrate important chemical stratification. The main processes responsible for chemical stratification in lakes are considered to be i) diffusion fluxes from the sediment to the bottom water accompanied by sulfate reduction and methanogenesis in the sediments and ii) dissolution/mineralization of precipitating organic matter (mineral fraction, detritus, plankton pellets) in the bottom layer horizons under anoxic conditions. Up to present time, distinguishing between two processes remains difficult. This paper is aimed at filling this gap via detailed geochemical analysis of DOC and trace elements in the water column profiles of three typical stratified lakes of Arkhangelsk region in Kenozersky National Parc (64° N) in winter (glacial) and in summer period. Concentration of most trace elements (Li, B, Al, Ti, V, Cr, Ni, Co, Zn, As, Rb, Sr, Y, Zr, Mo, Sb, Ba, REEs, Th, U) are not subjected to strong variations along the water column, despite the presence of strong or partial redox stratification. Apparently, these elements are not significantly controlled by production/mineralization processes and redox phenomena in the water column, or the influence of these processes is not pronounced under the control by the allochtonous river water input. In particularly, the stability of titanium and aluminum concentration along the depth profile and their independence of iron behavior suggest the important control by dissolved organic matter. Therefore, organo-ferric colloids controlling petrogenic elements speciation in soil and river waters are being replaced by autochthonous organic colloids in the lake system. The same observation is true for some heavy metals such as nickel, copper and zinc, whereas cobalt, as limiting component, is being strongly removed from the photic zone or it is coprecipitating with manganese hydroxide. Results of the present work allow quantitative evaluation of the role of redox processes in the bottom horizons and organic detritus degradation in the creation of chemical stratification of small lakes with high DOC concentration. Further insights on geochemical migration of trace elements in lakes require : i) study of colloidal speciation using in-situ dialysis; ii) monitoring the annual and seasonal dynamics of redox processes and TE concentration variation along the profile; iii) quantitative assessment of bacterial degradation of suspended OM and Mn and Fe redox reactions along the depth profile; iv) setting the sedimentary traps for evaluation of suspended material fluxes, and, v) thorough study of chemical composition of interstitial pore waters.

Deconvolving the Fate of Carbon in Coastal Sediments

NASA Astrophysics Data System (ADS)

Van der Voort, Tessa S.; Mannu, Utsav; Blattmann, Thomas M.; Bao, Rui; Zhao, Meixun; Eglinton, Timothy I.

2018-05-01

Coastal oceans play a crucial role in the global carbon cycle, and are increasingly affected by anthropogenic forcing. Understanding carbon cycling in coastal environments is hindered by convoluted sources and myriad processes that vary over a range of spatial and temporal scales. In this study, we deconvolve the complex mosaic of organic carbon manifested in Chinese Marginal Sea (CMS) sediments using a novel numerical clustering algorithm based on 14C and total OC content. Results reveal five regions that encompass geographically distinct depositional settings. Complementary statistical analyses reveal contrasting region-dependent controls on carbon dynamics and composition. Overall, clustering is shown to be highly effective in demarcating areas of distinct organic facies by disentangling intertwined organic geochemical patterns resulting from superimposed effects of OC provenance, reworking and deposition on a shelf region exhibiting pronounced spatial heterogeneity. This information will aid in constraining region-specific budgets of carbon burial and carbon cycle processes.

Final Report: Molecular mechanisms and kinetics of microbial anaerobic nitrate-dependent U(IV) and Fe(II) oxidation

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Day, Peggy A.; Asta, Maria P.; Kanematsu, Masakazu

2015-02-27

In this project, we combined molecular genetic, spectroscopic, and microscopic techniques with kinetic and reactive transport studies to describe and quantify biotic and abiotic mechanisms underlying anaerobic, nitrate-dependent U(IV) and Fe(II) oxidation, which influences the long-term efficacy of in situ reductive immobilization of uranium at DOE sites. In these studies, Thiobacillus denitrificans, an autotrophic bacterium that catalyzes anaerobic U(IV) and Fe(II) oxidation, was used to examine coupled oxidation-reduction processes under either biotic (enzymatic) or abiotic conditions in batch and column experiments with biogenically produced UIVO2(s). Synthesis and quantitative analysis of coupled chemical and transport processes were done with the reactivemore » transport modeling code Crunchflow. Research focused on identifying the primary redox proteins that catalyze metal oxidation, environmental factors that influence protein expression, and molecular-scale geochemical factors that control the rates of biotic and abiotic oxidation.« less

Groundwater geochemistry of Isla de Mona, Puerto Rico

USGS Publications Warehouse

Wicks, C.M.; Troester, J.W.

1998-01-01

In this study, we explore the differences between the hydrogeochemical processes observed in a setting that is open to input from the land surface and in a setting that is closed with respect to input from the land surface. The closed setting was a water-filled passage in a cave. Samples of groundwater and of a solid that appeared to be suspended in the relatively fresh region of saline-freshwater mixing zone were collected. The solid was determined to be aragonite. Based on the analyses of the composition and saturation state of the groundwater, the mixing of fresh and saline water and precipitation of aragonite are the controlling geochemical processes in this mixing zone. We found no evidence of sulfate reduction. Thus, this mixing zone is similar to that observed in Caleta Xel Ha, Quintana Roo, also a system that is closed with respect to input from the land surface. The open setting was an unconfined aquifer underlying the coastal plain along which four hand-dug wells are located. Two wells are at the downgradient ends of inferred flowpaths and one is along a flowpath. The composition of the groundwater in the downgradient wells is sulfide-rich and brackish. In contrast, at the well located along a flow line, the groundwater is oxygenated and brackish. All groundwater is oversaturated with respect to calcite, aragonite, and dolomite. The composition is attributed to mixing of fresh and saline groundwater, CO2 outgassing, and sulfate reduction. This mixing zone is geochemically similar to that observed in blue holes and cenotes.

Vivianite formation and distribution in Lake Baikal sediments

NASA Astrophysics Data System (ADS)

Fagel, N.; Alleman, L. Y.; Granina, L.; Hatert, F.; Thamo-Bozso, E.; Cloots, R.; André, L.

2005-04-01

In an effort to better understand vivianite formation processes, four Lake Baikal sediment cores spanning two to four interglacial stages in the northern, central and southern basins and under various biogeochemical environments are scrutinized. The vivianite-rich layers were detected by anomalous P-enrichments in bulk geochemistry and visually by observations on X-radiographs. The millimetric concretions of vivianite were isolated by sieving and analysed by X-ray diffraction, scanning electron microscope (SEM), microprobe, infrared spectroscopy, inductively coupled plasma atomic emission spectrometry and mass spectrometry (ICP-AES, ICP-MS). All the vivianites display similar morphological, mineralogical and geochemical signature, suggesting a common diagenetic origin. Their geochemical signature is sensitive to secondary alteration where vivianite concretions are gradually transformed from the rim to the center into an amorphous santabarbaraite phase with a decreasing Mn content. We analysed the spatial and temporal distribution of the concretions in order to determine the primary parameters controlling the vivianite formation, e.g., lithology, sedimentation rates, and porewater chemistry. We conclude that vivianite formation in Lake Baikal is mainly controlled by porewater chemistry and sedimentation rates, and it is not a proxy for lacustrine paleoproductivity. Vivianite accumulation is not restricted to areas of slow sedimentation rates (e.g., Academician and Continent ridges). At the site of relatively fast sedimentation rate, i.e., the Posolsky Bank near the Selenga Delta, vivianite production may be more or less related to the Selenga River inputs. It could be also indirectly related to the past intensive methane escapes from the sediments. While reflecting an early diagenetic signal, the source of P and Fe porewater for vivianites genesis is still unclear.

What do we really know about early diagenesis of non-marine carbonates?

NASA Astrophysics Data System (ADS)

De Boever, Eva; Brasier, Alexander T.; Foubert, Anneleen; Kele, Sándor

2017-11-01

Non-marine carbonate rocks including cave, spring, stream, calcrete and lacustrine-palustrine sediments, are susceptible to early diagenetic processes. These can profoundly alter the carbonate fabric and affect paleoclimatic proxies. This review integrates recent insights into diagenesis of non-marine carbonates and in particular the variety of early diagenetic processes, and presents a conceptual framework to address them. With ability to study at smaller and smaller scales, down to nanometers, one can now observe diagenesis taking place the moment initial precipitates have formed, and continuing thereafter. Diagenesis may affect whole rocks, but it typically starts in nano- and micro-environments. The potential for diagenetic alteration depends on the reactivity of the initial precipitate, commonly being metastable phases like vaterite, Ca-oxalates, hydrous Mg-carbonates and aragonite with regard to the ambient fluid. Furthermore, organic compounds commonly play a crucial role in hosting these early transformations. Processes like neomorphism (inversion and recrystallization), cementation and replacement generally result in an overall coarsening of the fabric and homogenization of the wide range of complex, primary microtextures. If early diagenetic modifications are completed in a short time span compared to the (annual to millennial) time scale of interest, then recorded paleoenvironmental signals and trends could still acceptably reflect original, depositional conditions. However, even compact, non-marine carbonate deposits may behave locally and temporarily as open systems to crystal-fluid exchange and overprinting of one or more geochemical proxies is not unexpected. Looking to the future, relatively few studies have examined the behaviour of promising geochemical records, such as clumped isotope thermometry and (non-conventional) stable isotopes, in well-constrained diagenetic settings. Ongoing and future in-vitro and in-situ experimental approaches will help to investigate and detangle sequences of intermediate, diagenetic products, processes and controls, and to quantify rates of early diagenesis, bridging a gap between nanoscale, molecular lab studies and the fossil field rock record of non-marine carbonates.

The pH-dependent leaching behavior of slags from various stages of a copper smelting process: Environmental implications.

PubMed

Jarošíková, Alice; Ettler, Vojtěch; Mihaljevič, Martin; Kříbek, Bohdan; Mapani, Ben

2017-02-01

The leaching behaviors of primary copper (Cu) slags originating from Ausmelt, reverbatory, and converter furnaces operating under a single technological process were compared to a residual slag tailing obtained by slag re-processing via flotation and metal recovery. The EN 12457-2 leaching test, used for assessment of the hazardous properties, was followed by the CEN/TS 14997 pH-static leaching test (pH range 3-12). Both leaching experiments were coupled with a mineralogical investigation of the primary and secondary phases as well as geochemical modeling. Metals (Cd, Cu, Pb, Zn) exhibit the highest leaching at low pH. Under acidic conditions (pH 3-6), Ausmelt slag and slag tailing exhibited higher metal leaching compared to other slag types. Very low leaching of metals (far below EU limits for non-hazardous waste) was observed at natural pH (7.9-9.0) for all the studied slag samples. In contrast, relatively high leaching of As was observed over the entire pH range, especially for Ausmelt slag (exceeding the EU limit for hazardous waste by 1.7×). However, geochemical modeling and scanning electron microscopy indicated that formation of stable Ca-Cu-Pb arsenates and the binding of As to newly formed Fe (oxyhydr)oxides play an important role in efficient As immobilization at the slag-water interface. In contrast, no controls were predicted for Sb, whose leaching was almost pH-independent. Nevertheless Sb leached concentrations at natural pH were below EU limit for hazardous waste. Re-processing of primary Cu slags for metal recovery, and subsequent co-disposal of the resulting slag tailing with dolomite-rich mine tailing and local laterite is suitable for stabilizing the remaining contaminants (except Sb) and limiting their leaching into the environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

Long-term ERT monitoring of biogeochemical changes of an aged hydrocarbon contamination.

PubMed

Caterina, David; Flores Orozco, Adrian; Nguyen, Frédéric

2017-06-01

Adequate management of contaminated sites requires information with improved spatio-temporal resolution, in particular to assess bio-geochemical processes, such as the transformation and degradation of contaminants, precipitation of minerals or changes in groundwater geochemistry occurring during and after remediation procedures. Electrical Resistivity Tomography (ERT), a geophysical method sensitive to pore-fluid and pore-geometry properties, permits to gain quasi-continuous information about subsurface properties in real-time and has been consequently widely used for the characterization of hydrocarbon-impacted sediments. However, its application for the long-term monitoring of processes accompanying natural or engineered bioremediation is still difficult due to the poor understanding of the role that biogeochemical processes play in the electrical signatures. For in-situ studies, the task is further complicated by the variable signal-to-noise ratio and the variations of environmental parameters leading to resolution changes in the electrical images. In this work, we present ERT imaging results for data collected over a period of two years on a site affected by a diesel fuel contamination and undergoing bioremediation. We report low electrical resistivity anomalies in areas associated to the highest contaminant concentrations likely due transformations of the contaminant due to microbial activity and accompanying release of metabolic products. We also report large seasonal variations of the bulk electrical resistivity in the contaminated areas in correlation with temperature and groundwater level fluctuations. However, the amplitude of bulk electrical resistivity variations largely exceeds the amplitude expected given existing petrophysical models. Our results suggest that the variations in electrical properties are mainly controlled by microbial activity which in turn depends on soil temperature and hydrogeological conditions. Therefore, ERT can be suggested as a promising tool to track microbial activity during bioremediation even though further research is still needed to completely understand the bio-geochemical processes involved and their impact on electrical signatures. Copyright © 2017 Elsevier B.V. All rights reserved.

Long-term ERT monitoring of biogeochemical changes of an aged hydrocarbon contamination

NASA Astrophysics Data System (ADS)

Caterina, David; Flores Orozco, Adrian; Nguyen, Frédéric

2017-06-01

Adequate management of contaminated sites requires information with improved spatio-temporal resolution, in particular to assess bio-geochemical processes, such as the transformation and degradation of contaminants, precipitation of minerals or changes in groundwater geochemistry occurring during and after remediation procedures. Electrical Resistivity Tomography (ERT), a geophysical method sensitive to pore-fluid and pore-geometry properties, permits to gain quasi-continuous information about subsurface properties in real-time and has been consequently widely used for the characterization of hydrocarbon-impacted sediments. However, its application for the long-term monitoring of processes accompanying natural or engineered bioremediation is still difficult due to the poor understanding of the role that biogeochemical processes play in the electrical signatures. For in-situ studies, the task is further complicated by the variable signal-to-noise ratio and the variations of environmental parameters leading to resolution changes in the electrical images. In this work, we present ERT imaging results for data collected over a period of two years on a site affected by a diesel fuel contamination and undergoing bioremediation. We report low electrical resistivity anomalies in areas associated to the highest contaminant concentrations likely due transformations of the contaminant due to microbial activity and accompanying release of metabolic products. We also report large seasonal variations of the bulk electrical resistivity in the contaminated areas in correlation with temperature and groundwater level fluctuations. However, the amplitude of bulk electrical resistivity variations largely exceeds the amplitude expected given existing petrophysical models. Our results suggest that the variations in electrical properties are mainly controlled by microbial activity which in turn depends on soil temperature and hydrogeological conditions. Therefore, ERT can be suggested as a promising tool to track microbial activity during bioremediation even though further research is still needed to completely understand the bio-geochemical processes involved and their impact on electrical signatures.

Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Li; Li, Li

2015-10-22

The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in naturalmore » systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport, water quality and water composition, and natural attenuation processes in natural systems.« less

Sr and U isotope ratios in soil waters as tracers of weathering dynamic in soils (Strengbach catchment - Vosges-mountains; France).

NASA Astrophysics Data System (ADS)

Chabaux, François; Prunier, Jonathan; Pierret, Marie-Claire; Stille, Peter

2013-04-01

It is proposed in this study to highlight the interest of multi-tracer geochemical approaches combining measurement of major and trace element concentrations along with U and Sr isotopic ratios to constrain the characterization of the present-day weathering processes controlling the chemical composition of waters and soils in natural ecosystems. This is important if we want to predict and to model correctly the response of ecosystems to recent environmental changes. The approach is applied to the small granitic Strengbah Catchment, located in the Vosges Mountain (France), used and equipped as a hydro-geochemical observatory since 1986 (Observatoire Hydro-Géochimique de l'Environnement; http://ohge.u-strasbg.fr). This study includes the analysis of major and trace element concentrations and (U-Sr) isotope ratios in soil solutions collected within two soil profiles located on two experimental plots of this watershed, along with the analysis of soil samples and vegetation samples from these two plots. The depth variation of elemental concentrations of soil solutions confirms the important influence of the vegetation cycling on the budget of Ca, K, Rb and Sr, whereas Mg and Si budget in soil solutions are quasi exclusively controlled by weathering processes. Variation of Sr, and U isotopic ratios with depth also demonstrates that the sources and biogeochemical processes controlling the Sr budget of soil solutions is different in the uppermost soil horizons and in the deeper ones, and clearly influence by the vegetation cycling. From the obtained data, it can be therefore proposed a scheme where in addition to the external flux associated to the decomposition of organic matter and throughfall, occurs a double lithogenic flux: a surface flux which can be associated to dissolution of secondary minerals contained in fine silt fractions and a deeper one, controlled by water-rock interactions which can mobilize elements from primary minerals like plagioclases or orthose. These results shows also that the Strengbach watershed is in a transient state of weathering with an important loss of nutriments such as Ca in soils solutions since 15years, associated with an increase of a lithogenic flux indicating a recent modification of weathering/dissolution reactions involved in the soil horizons. The origin of the weathering modification could be the consequence of the acid rains on weathering granitic bedrock or a consequence of forest exploitation incompatible with the nutriment reserve of soils with recent plantations of conifer, which impoverish soils.

SITE Technology Capsule. Demonstration of Rocky Mountain Remediation Services Soil Amendment

EPA Science Inventory

This report briefly summarizes the Rocky Mountain Remediation Services treatment technology demonstration of a soil amendment process for lead contaminated soil at Roseville, OH. The evaluation included leaching, bioavailability, geotechnical, and geochemical methods.

Role of aquitards in hydrogeochemical systems: a synopsis

USGS Publications Warehouse

Back, W.

1986-01-01

Aquitards exert significant influence on the hydrogeochemistry of aquifer systems. This influence is manifested somewhat differently depending on the relative position of aquitards within a system. In the deeper regimes, they are influential in the origin and distribution of brines and the development of geopressured zones. In intermediate regimes, they form multi-layered aquifer systems and provide a source of reactive minerals and exchangeable ions. In shallow regimes, aquitards can influence the topography and drainage patterns; this influences the relationship between the water table and the potentiometric surface of confined aquifers, controls the rates of infiltration and discharge, and controls whether the geochemical system is open or closed to exchange of carbon dioxide gas. In coastal areas, aquitards can determine the depth of the saltwater-freshwater interface, its distance from the shoreline, and the position of the mixing zone that causes geochemical alteration of minerals and development of porosity. ?? 1986.

Coupling between geochemical reactions and multicomponent gas and solute transport in unsaturated media: A reactive transport modeling study

USGS Publications Warehouse

Molins, S.; Mayer, K.U.

2007-01-01

The two‐way coupling that exists between biogeochemical reactions and vadose zone transport processes, in particular gas phase transport, determines the composition of soil gas. To explore these feedback processes quantitatively, multicomponent gas diffusion and advection are implemented into an existing reactive transport model that includes a full suite of geochemical reactions. Multicomponent gas diffusion is described on the basis of the dusty gas model, which accounts for all relevant gas diffusion mechanisms. The simulation of gas attenuation in partially saturated landfill soil covers, methane production, and oxidation in aquifers contaminated by organic compounds (e.g., an oil spill site) and pyrite oxidation in mine tailings demonstrate that both diffusive and advective gas transport can be affected by geochemical reactions. Methane oxidation in landfill covers reduces the existing upward pressure gradient, thereby decreasing the contribution of advective methane emissions to the atmosphere and enhancing the net flux of atmospheric oxygen into the soil column. At an oil spill site, methane oxidation causes a reversal in the direction of gas advection, which results in advective transport toward the zone of oxidation both from the ground surface and the deeper zone of methane production. Both diffusion and advection contribute to supply atmospheric oxygen into the subsurface, and methane emissions to the atmosphere are averted. During pyrite oxidation in mine tailings, pressure reduction in the reaction zone drives advective gas flow into the sediment column, enhancing the oxidation process. In carbonate‐rich mine tailings, calcite dissolution releases carbon dioxide, which partly offsets the pressure reduction caused by O2 consumption.

Geochemical variables as plausible aetiological cofactors in the incidence of some common environmental diseases in Africa

NASA Astrophysics Data System (ADS)

Davies, T. C.

2013-03-01

Over the last two decades, there has been a rapid growth in research in the field of medical geology around the world, and we continue to encounter “new” and important correlations between certain environmental health conditions and factors related to our interactions with geological materials and processes. A review of the possible role of geochemical factors such as the circulation of Mg, Se and F and the physico-chemical composition of volcanic soil particles, on the aetiology of some common diseases in Africa, is presented. Such studies till now, have tended to emphasise only the deleterious health impacts due to geoenvironmental factors. This is justifiable, since a proper understanding of the negative health impacts has contributed significantly towards improvement in diagnosis and therapy. But there are also beneficial effects accrued from judiciously exploiting geological materials and processes, exemplified in this review, by the several important medical applications of African clays, the therapeutic gains associated with hot springs, and balneology of peat deposits. The criticality of the “optimal range” of intake for the nutrient elements Mg, Se and F in metabolic processes is also emphasised, and illustrations given of illnesses such as cardiovascular disorders and various cancers (all major causes of mortality in Africa) that can possibly occur on either side of this range. It is hoped that this review would help generate ideas for the formulation of experimental studies that take into account the role of the geochemical environment, in an attempt to establish precisely the obscure aetiology of some of the diseases treated, and uncover new pathways in their pathogenesis.

Geochemical Processes During Managed Aquifer Recharge With Desalinated Seawater

NASA Astrophysics Data System (ADS)

Ganot, Y.; Holtzman, R.; Weisbrod, N.; Russak, A.; Katz, Y.; Kurtzman, D.

2018-02-01

We study geochemical processes along the variably-saturated zone during managed aquifer recharge (MAR) with reverse-osmosis desalinated seawater (DSW). The DSW, post-treated at the desalination plant by calcite dissolution (remineralization) to meet the Israeli water quality standards, is recharged into the Israeli Coastal Aquifer through an infiltration pond. Water quality monitoring during two MAR events using suction cups and wells inside the pond indicates that cation exchange is the dominant subsurface reaction, driven by the high Ca2+ concentration in the post-treated DSW. Stable isotope analysis shows that the shallow groundwater composition is similar to the recharged DSW, except for enrichment of Mg2+, Na+, Ca2+, and HCO3-. A calibrated variably-saturated reactive transport model is used to predict the geochemical evolution during 50 years of MAR for two water quality scenarios: (i) post-treated DSW (current practice) and (ii) soft DSW (lacking the remineralization post-treatment process). The latter scenario was aimed to test soil-aquifer-treatment (SAT) as an alternative post-treatment technique. Both scenarios provide an enrichment of ˜2.5 mg L-1 in Mg2+ due to cation exchange, compared to practically zero Mg2+ currently found in the Israeli DSW. Simulations of the alternative SAT scenario provide Ca2+ and HCO3- remineralization due to calcite dissolution at levels that meet the Israeli standard for DSW. The simulated calcite content reduction in the sediments below the infiltration pond after 50 years of MAR was low (<1%). Our findings suggest that remineralization using SAT for DSW is a potentially sustainable practice at MAR sites overlying calcareous sandy aquifers.

Only pick the right grains: Modelling the bias due to subjective grain-size interval selection for chronometric and fingerprinting approaches.

NASA Astrophysics Data System (ADS)

Dietze, Michael; Fuchs, Margret; Kreutzer, Sebastian

2016-04-01

Many modern approaches of radiometric dating or geochemical fingerprinting rely on sampling sedimentary deposits. A key assumption of most concepts is that the extracted grain-size fraction of the sampled sediment adequately represents the actual process to be dated or the source area to be fingerprinted. However, these assumptions are not always well constrained. Rather, they have to align with arbitrary, method-determined size intervals, such as "coarse grain" or "fine grain" with partly even different definitions. Such arbitrary intervals violate principal process-based concepts of sediment transport and can thus introduce significant bias to the analysis outcome (i.e., a deviation of the measured from the true value). We present a flexible numerical framework (numOlum) for the statistical programming language R that allows quantifying the bias due to any given analysis size interval for different types of sediment deposits. This framework is applied to synthetic samples from the realms of luminescence dating and geochemical fingerprinting, i.e. a virtual reworked loess section. We show independent validation data from artificially dosed and subsequently mixed grain-size proportions and we present a statistical approach (end-member modelling analysis, EMMA) that allows accounting for the effect of measuring the compound dosimetric history or geochemical composition of a sample. EMMA separates polymodal grain-size distributions into the underlying transport process-related distributions and their contribution to each sample. These underlying distributions can then be used to adjust grain-size preparation intervals to minimise the incorporation of "undesired" grain-size fractions.

Geochemical signatures of tsunami deposits - what do they tell us?

NASA Astrophysics Data System (ADS)

Chague-Goff, Catherine; Goff, James R.

2010-05-01

In the last two and half decades, but even more since the 2004 Indian Ocean Tsunami (IOT), there has been a significant increase in the amount of literature dealing with recent, historical and palaeotsunamis. Much has been written and debated about the diagnostic criteria of historical and palaeotsunami deposits. Most of the diagnostic criteria or proxies used reflect the expertise of the researchers involved and thus tend to be biased towards sedimentology, stratigraphy and micropalaeontology, with some reference to geomorphology, archaeology, anthropology and palynology. It should however be noted that all criteria have never been reported from one site, and neither are they all found in one single deposit. Thus, the lack of one or more proxies should not be taken as unique evidence to refute the tsunamigenic origin of a specific deposit. Although geochemical signatures have long been used as indicators for palaeosalinity in sedimentary sequences, there appears to have been some reluctance to use them to help in the identification of historical and palaeotsunami deposits. Like other proxies, geochemistry alone may not provide a definite answer to the origin of a deposit. Furthermore, poor preservation due to environmental conditions or as a result of post-diagenetic processes, might complicate the interpretation of geochemical signatures left by tsunami inundation. Similar taphonomic problems are also faced for microfossil proxies. However, geochemistry provides another piece to the puzzle, and together with other proxies, it can help identify palaeotsunami deposits. Geochemical signatures can also provide clues about the landward limit of runup of a tsunami, beyond the area of sediment deposition. This was recently documented following the 2004 IOT and the 2009 South Pacific tsunami. A summary of examples of geochemical signatures recorded in interstitial water and sediment of recent, historical and palaeotsunami deposits is presented.

Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Briggs, Brandon R; Graw, Michael; Brodie, Eoin L

2013-11-01

The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfate–methane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining themore » results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.« less

Impact of anaerobic oxidation of methane on the geochemical cycle of redox-sensitive elements at cold-seep sites of the northern South China Sea

NASA Astrophysics Data System (ADS)

Hu, Yu; Feng, Dong; Liang, Qianyong; Xia, Zhen; Chen, Linying; Chen, Duofu

2015-12-01

Cold hydrocarbon seepage is a frequently observed phenomenon along continental margins worldwide. However, little is known about the impact of seeping fluids on the geochemical cycle of redox-sensitive elements. Pore waters from four gravity cores (D-8, D-5, D-7, and D-F) collected from cold-seep sites of the northern South China Sea were analyzed for SO42-, Mg2+, Ca2+, Sr2+, dissolved inorganic carbon (DIC), δ13CDIC, dissolved Fe, Mn, and trace elements (e.g. Mo, U). The sulfate concentration-depth profiles, δ13CDIC values and (ΔDIC+ΔCa2++ΔMg2+)/ΔSO42- ratios suggest that organoclastic sulfate reduction (OSR) is the dominant process in D-8 core. Besides OSR, anaerobic oxidation of methane (AOM) is partially responsible for depletion of sulfate at D-5 and D-7 cores. The sulfate consumption at D-F core is predominantly caused by AOM. The depth of sulfate-methane interface (SMI) and methane diffusive flux of D-F core are calculated to be ~7 m and 0.035 mol m-2 yr-1, respectively. The relatively shallow SMI and high methane flux at D-F core suggest the activity of gas seepage in this region. The concentrations of dissolved uranium (U) were inferred to decrease significantly within the iron reduction zone. It seems that AOM has limited influence on the U geochemical cycling. In contrast, a good correlation between the consumption of sulfate and the removal of molybdenum (Mo) suggests that AOM has a significantly influence on the geochemical cycle of Mo at cold seeps. Accordingly, cold seep environments may serve as an important potential sink in the marine geochemical cycle of Mo.

Hydro-geochemical modeling of the spatial and the temporal geochemical variations of the granitic Strengbach catchment springs (Vosges massif, France)

NASA Astrophysics Data System (ADS)

Ackerer, Julien; Chabaux, François; Lucas, Yann; Pierret, Marie Claire; Viville, Daniel; Fritz, Bertrand; Clement, Alain; Beaulieu, Emilie; Negrel, Philippe

2017-04-01

Regular analysis of the major element concentrations in waters from springs emerging on the Strengbach catchment is made for more than 20 years (OHGE, Observatoire Hydro-Géochimique de l'Environnement). These data confirm the spatial variability of geochemical characteristics of the Strengbach springs linked, at least partly, to the lithological variability of the substratum (Pierret et al., 2014). The data also indicate that at the first order, the geochemical fluxes exported from each spring are mainly linked to the spring discharges, without significant variations of the relationships linking these two parameters between 1990 and 2010. There is also no observation of significant variations for the dissolved silica and for most of the cationic concentrations with time. Only a significant decrease of the Ca concentrations is observed for the Strengbach springs from 1990 to 2010. Numerical simulations, performed with the KIRMAT hydro-geochemical code, show that such a decrease can be considered as the response in the "bedrock" of the water-rock interactions to the variations of the soil solution chemical compositions recorded over the last 20 years, marked by a significant increase of pH and decrease of Ca concentrations. In particular, the modeling results show that the Ca concentration decrease is controlled by the couple apatite/clays, and that significant modifications of the apatite dissolution rate and clay compositions occurred between 1990 and 2010. This study shows that the temporal evolution of the Strengbach spring chemistry cannot be explained by the only variations of the clay mineral compositions, i.e. a modification of the chemical composition of the precipitated clays or a modification of the ionic exchange capacity of the clay minerals, but that it is definitely the interrelations between the apatite and the clay minerals that are involved.

Geochemical Characterization of the Upper and Middle Floridan Aquifer System, South Florida

NASA Astrophysics Data System (ADS)

Mirecki, J.; Richardson, E.; Bennett, M.; Hendel, J.

2008-05-01

Our study focus is to characterize the water quality and geochemical environment of the Floridan Aquifer System (FAS) throughout the regional flowpath. A synoptic survey of 21 wells (n=15, upper FAS; n=6 middle FAS) was supplemented by additional samples (n=11) obtained during exploratory well development at 4 aquifer storage recovery (ASR) pilot sites. Synoptic survey samples were analyzed intensively, yielding a dataset that consists of major and trace dissolved constituents (including metals), stable isotopes (δ18O, δ13C, δD, δ34S in sulfate and sulfide), carbon species (carbonate alkalinity and organic carbon), uranium-series radionuclides, nutrients, and selected microbes and pathogens. The objectives of this study are three-fold: 1) to provide baseline water-quality and geochemical information prior to initiation of ASR activities that are part of the Comprehensive Everglades Restoration Plan; 2) to quantify the major controls on geochemical evolution along upper and middle FAS flowpaths using geochemical modeling methods; and 3) to identify areas where water- quality may limit the feasibility of ASR methods in the FAS. Preliminary interpretations water quality changes along the regional FAS flowpath can be summarized as follows. Concentrations of dissolved constituents increase from north to south along the flow path; generally, the upper FAS has lower total dissolved solids than the middle FAS at locations where well pairs were analyzed. The redox environment changes from oxic to strongly anoxic, very close to the recharge area. Redox measurements, dissolved iron, sulfide, and sulfur isotope data are consistent with sulfate-reducing conditions. Uranium-series isotope concentrations and activities generally are below regulatory criteria, with few exceptions in both the upper and middle FAS. Areas with greater radionuclide activity occur primarily at distal flowpath locations or at the coast.

Produced water re-injection in a non-fresh water aquifer with geochemical reaction, hydrodynamic molecular dispersion and adsorption kinetics controlling: model development and numerical simulation

NASA Astrophysics Data System (ADS)

Obe, Ibidapo; Fashanu, T. A.; Idialu, Peter O.; Akintola, Tope O.; Abhulimen, Kingsley E.

2017-06-01

An improved produced water reinjection (PWRI) model that incorporates filtration, geochemical reaction, molecular transport, and mass adsorption kinetics was developed to predict cake deposition and injectivity performance in hydrocarbon aquifers in Nigeria oil fields. Thus, the improved PWRI model considered contributions of geochemical reaction, adsorption kinetics, and hydrodynamic molecular dispersion mechanism to alter the injectivity and deposition of suspended solids on aquifer wall resulting in cake formation in pores during PWRI and transport of active constituents in hydrocarbon reservoirs. The injectivity decline and cake deposition for specific case studies of hydrocarbon aquifers in Nigeria oil fields were characterized with respect to its well geometry, lithology, and calibrations data and simulated in COMSOL multiphysics software environment. The PWRI model was validated by comparisons to assessments of previous field studies based on data and results supplied by operator and regulator. The results of simulation showed that PWRI performance was altered because of temporal variations and declinations of permeability, injectivity, and cake precipitation, which were observed to be dependent on active adsorption and geochemical reaction kinetics coupled with filtration scheme and molecular dispersion. From the observed results and findings, transition time t r to cake nucleation and growth were dependent on aquifer constituents, well capacity, filtration coefficients, particle-to-grain size ratio, water quality, and more importantly, particle-to-grain adsorption kinetics. Thus, the results showed that injectivity decline and permeability damage were direct contributions of geochemical reaction, hydrodynamic molecular diffusion, and adsorption kinetics to the internal filtration mechanism, which are largely dependent on the initial conditions of concentration of active constituents of produced water and aquifer capacity.

Some electrical and magnetic studies of Kilauea Iki lava lake, Hawaii

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zablocki, C.J.

1976-01-01

In recent years, the U.S. Geological Survey has been applying various electrical-magnetic (E-M) geophysical techniques to the study of volcanologic processes at Kilauea Volcano, Hawaii. Some of these studies have been directed towards determining the responses of these E-M methods on the cooling and crystallizing lava lake that formed in Kilauea Iki pit crater in 1959. Over the years, this 111 meter-deep ponded body of basaltic magma has served as a natural laboratory for petrologic, geochemical, and geophysical investigations, and hence, has yielded some control for interpreting the resulting E-M data gathered in these studies. A brief discussion of themore » application results, and some tentative conclusions of these studies are presented.« less

Application of artificial neural networks to chemostratigraphy

NASA Astrophysics Data System (ADS)

Malmgren, BjöRn A.; Nordlund, Ulf

1996-08-01

Artificial neural networks, a branch of artificial intelligence, are computer systems formed by a number of simple, highly interconnected processing units that have the ability to learn a set of target vectors from a set of associated input signals. Neural networks learn by self-adjusting a set of parameters, using some pertinent algorithm to minimize the error between the desired output and network output. We explore the potential of this approach in solving a problem involving classification of geochemical data. The data, taken from the literature, are derived from four late Quaternary zones of volcanic ash of basaltic and rhyolithic origin from the Norwegian Sea. These ash layers span the oxygen isotope zones 1, 5, 7, and 11, respectively (last 420,000 years). The data consist of nine geochemical variables (oxides) determined in each of 183 samples. We employed a three-layer back propagation neural network to assess its efficiency to optimally differentiate samples from the four ash zones on the basis of their geochemical composition. For comparison, three statistical pattern recognition techniques, linear discriminant analysis, the k-nearest neighbor (k-NN) technique, and SIMCA (soft independent modeling of class analogy), were applied to the same data. All of these showed considerably higher error rates than the artificial neural network, indicating that the back propagation network was indeed more powerful in correctly classifying the ash particles to the appropriate zone on the basis of their geochemical composition.

Data for factor analysis of hydro-geochemical characteristics of groundwater resources in Iranshahr.

PubMed

Biglari, Hamed; Saeidi, Mehdi; Karimyan, Kamaleddin; Narooie, Mohammad Reza; Sharafi, Hooshmand

2018-08-01

Detection of Hydrogeological and Hydro-geochemical changes affecting the quality of aquifer water is very important. The aim of this study was to determine the factor analysis of the hydro-geochemical characteristics of Iranshahr underground water resources during the warm and cool seasons. In this study, 248 samples (two-time repetitions) of ground water resources were provided at first by cluster-random sampling method during 2017 in the villages of Iranshahr city. After transferring the samples to the laboratory, concentrations of 13 important chemical parameters in those samples were determined according to o water and wastewater standard methods. The results of this study indicated that 45.45% and 55.55% of the correlation between parameters has had a significant decrease and increase, respectively with the transition from warm seasons to cold seasons. According to the factor analysis method, three factors of land hydro-geochemical processes, supplying resources by surface water and sewage as well as human activities have been identified as influential on the chemical composition of these resources.The highest growth rate of 0.37 was observed between phosphate and nitrate ions while the lowest trend of - 0.33 was seen between fluoride ion and calcium as well as chloride ions. Also, a significant increase in the correlation between magnesium ion and nitrate ion from warm seasons to cold seasons indicates the high seasonal impact of the relation between these two parameters.

Biogeochemical Processes in Steppe Landscapes of the Ergeni Upland in the Holocene

NASA Astrophysics Data System (ADS)

Kalinin, P. I.; Kudrevatykh, I. Yu.; Vagapov, I. M.; Borisov, A. V.; Alekseev, A. O.

2018-05-01

A soil catena was studied on the Ergeni Upland; the soils and plants were sampled in five dependent points. The contents of macro- and microelements in them were determined. It was found that the radial (vertical) geochemical migration predominates in the eluvial positions of the catena, and the lateral geochemical migration predominates in the transeluvial and transeluvial-accumulative positions. Plants of the Poa L. genus intensely accumulated elements within the eluvial part of the catena, whereas plants of the Artemisia genus were element accumulators within the trans-superaquatic position. Plants of the Artemisia genus were generally characterized by a higher coefficient of the biological uptake of elements in all parts of the catena, except for the eluvial position, where this parameter was higher for plants from the Poa L genus. A rise in the magnetic susceptibility of the soil profile relative to the parent material was the highest in the eluvial position and the lowest in the trans-superaquatic position. A comparative analysis of geochemical ratios for modern soils showed that they are determined by the topographic position of the given point. However, the gradient of variations for surface soils is much smaller in comparison with that for buried soils indicative of the climatic fluctuations. The obtained geochemical indicators can be used for comparative analysis of buried soils found not only on the divides but also in the subordinate landscape positions.

Geochemical evidence for a brooks range mineral belt, Alaska

USGS Publications Warehouse

Marsh, S.P.; Cathrall, J.B.

1981-01-01

Geochemical studies in the central Brooks Range, Alaska, delineate a regional, structurally controlled mineral belt in east-west-trending metamorphic rocks and adjacent metasedimentary rocks. The mineral belt extends eastward from the Ambler River quadrangle to the Chandalar and Philip Smith quadrangles, Alaska, from 147?? to 156??W. longitude, a distance of more than 375 km, and spans a width from 67?? to 69??N. latitude, a distance of more than 222 km. Within this belt are several occurrences of copper and molybdenum mineralization associated with meta-igneous, metasedimentary, and metavolcanic rocks; the geochemical study delineates target areas for additional occurrences. A total of 4677 stream-sediment and 2286 panned-concentrate samples were collected in the central Brooks Range, Alaska, from 1975 to 1979. The -80 mesh ( 2.86) nonmagnetic fraction of the panned concentrates from stream sediment were analyzed by semiquantitative spectrographic methods. Two geochemical suites were recognized in this investigation; a base-metal suite of copper-lead-zinc and a molybdenum suite of molybdenum-tin-tungsten. These suites suggest several types of mineralization within the metamorphic belt. Anomalies in molybdenum with associated Cu and W suggest a potential porphyry molybdenum system associated with meta-igneous rocks. This regional study indicates that areas of metaigneous rocks in the central metamorphic belt are target areas for potential mineralized porphyry systems and that areas of metavolcanic rocks are target areas for potential massive sulfide mineralization. ?? 1981.

Application of geochemical techniques to deduce the reservoir performance of the Palinpinon Geothermal Field, Philippines - an update

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramos-Candelaria, M.N.; Garcia, S.E.; Hermoso, D.Z.

1997-12-31

Regular monitoring of various geochemical parameters in the water and vapor phases of the production wells at the Palinpinon I and II sectors of the Southern Negros Geothermal Field have been useful in the identification of the dominant reservoir processes occurring related to the present exploitation strategy. Observed geochemical and physical changes in the output of production wells have dictated production and injection strategies adopted to maximize production to meet the steam requirements of the power plant. Correlation of both physical and chemical data have identified the following reservoir processes: (1) Injection breakthrough via the Ticala Fault of the highlymore » mineralized (Cl {approximately}8,000-10,500 mg/kg), isotopically enriched ({delta}{sup 18}O = -3.00{per_thousand}, {delta}{sup 2} H = -39{per_thousand}), and gas depleted brine for wells in the SW and central Puhagan. Injection breakthrough is also occurring in Palinpinon II and has resulted in temperature drops of 5-10{degrees}C.2. Pressure drawdown enhanced boiling in the liquid reservoir with steam separation of 220-240{degrees}C, feeding wells tapping the natural steam zone. However, enhanced drawdown has induced the entry of shallow acid steam condensate fluids in some wells (e.g. OK-7, PN-29D, PN-18D), which if not arrested could reduce production.« less

Symplectite in spinel lherzolite xenoliths from the Little Hungarian Plain, Western Hungary: A key for understanding the complex history of the upper mantle of the Pannonian Basin

NASA Astrophysics Data System (ADS)

Falus, György; Szabó, Csaba; Kovács, István; Zajacz, Zoltán; Halter, Werner

2007-03-01

Two spinel lherzolite xenoliths from Hungary that contain pyroxene-spinel symplectites have been studied using EPMA, Laser ablation ICP-MS and universal stage. Based on their geochemical and structural characteristics, the xenoliths represent two different domains of the shallow subcontinental lithospheric mantle beneath the Pannonian Basin. The occurrence of symplectites is attributed to the former presence and subsequent breakdown of garnets due to significant pressure decrease related to lithospheric thinning. This implies that both mantle domains were once part of the garnet lherzolitic upper mantle and had a similar history during the major extension that formed the Pannonian Basin. Garnet breakdown resulted in distinct geochemical characteristics in the adjacent clinopyroxene crystals in both xenoliths. This is manifested by enrichment in HREE, Y, Zr and Hf towards the clinopyroxene porphyroclast rims and also in the neoblasts with respect to porphyroclast core compositions. This geochemical feature, together with the development and preservation of the texturally very sensitive symplectites, enables us to determine the relative timing of mantle processes. Our results indicate that garnets had been metastable in the spinel lherzolite environment and their breakdown to pyroxene and spinel is one of the latest processes that took place within the upper mantle before the xenoliths were brought to the surface.

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

NASA Astrophysics Data System (ADS)

Danczak, Robert; Yabusaki, Steven; Williams, Kenneth; Fang, Yilin; Hobson, Chad; Wilkins, Michael

2016-05-01

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Predicting Biological Information Flow in a Model Oxygen Minimum Zone

NASA Astrophysics Data System (ADS)

Louca, S.; Hawley, A. K.; Katsev, S.; Beltran, M. T.; Bhatia, M. P.; Michiels, C.; Capelle, D.; Lavik, G.; Doebeli, M.; Crowe, S.; Hallam, S. J.

2016-02-01

Microbial activity drives marine biochemical fluxes and nutrient cycling at global scales. Geochemical measurements as well as molecular techniques such as metagenomics, metatranscriptomics and metaproteomics provide great insight into microbial activity. However, an integration of molecular and geochemical data into mechanistic biogeochemical models is still lacking. Recent work suggests that microbial metabolic pathways are, at the ecosystem level, strongly shaped by stoichiometric and energetic constraints. Hence, models rooted in fluxes of matter and energy may yield a holistic understanding of biogeochemistry. Furthermore, such pathway-centric models would allow a direct consolidation with meta'omic data. Here we present a pathway-centric biogeochemical model for the seasonal oxygen minimum zone in Saanich Inlet, a fjord off the coast of Vancouver Island. The model considers key dissimilatory nitrogen and sulfur fluxes, as well as the population dynamics of the genes that mediate them. By assuming a direct translation of biocatalyzed energy fluxes to biosynthesis rates, we make predictions about the distribution and activity of the corresponding genes. A comparison of the model to molecular measurements indicates that the model explains observed DNA, RNA, protein and cell depth profiles. This suggests that microbial activity in marine ecosystems such as oxygen minimum zones is well described by DNA abundance, which, in conjunction with geochemical constraints, determines pathway expression and process rates. Our work further demonstrates how meta'omic data can be mechanistically linked to environmental redox conditions and biogeochemical processes.

Geochemical modeling of reactions and partitioning of trace metals and radionuclides during titration of contaminated acidic sediments.

PubMed

Zhang, Fan; Luo, Wensui; Parker, Jack C; Spalding, Brian P; Brooks, Scott C; Watson, David B; Jardine, Philip M; Gu, Baohua

2008-11-01

Many geochemical reactions that control aqueous metal concentrations are directly affected by solution pH. However, changes in solution pH are strongly buffered by various aqueous phase and solid phase precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior of the soil-solution system is thus critical to predict metal transport under variable pH conditions. This studywas undertaken to develop a practical generic geochemical modeling approach to predict aqueous and solid phase concentrations of metals and anions during conditions of acid or base additions. The method of Spalding and Spalding was utilized to model soil buffer capacity and pH-dependent cation exchange capacity by treating aquifer solids as a polyprotic acid. To simulate the dynamic and pH-dependent anion exchange capacity, the aquifer solids were simultaneously treated as a polyprotic base controlled by mineral precipitation/ dissolution reactions. An equilibrium reaction model that describes aqueous complexation, precipitation, sorption and soil buffering with pH-dependent ion exchange was developed using HydroGeoChem v5.0 (HGC5). Comparison of model results with experimental titration data of pH, Al, Ca, Mg, Sr, Mn, Ni, Co, and SO4(2-) for contaminated sediments indicated close agreement suggesting that the model could potentially be used to predictthe acid-base behavior of the sediment-solution system under variable pH conditions.

75 FR 57738 - Application(s) for Duty-Free Entry of Scientific Instruments

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-22

... neurological tissue and cells from mice, zebrafish, and fruit flies. The properties of the materials being...- geochemical and bio-engineering research. Many of the processes of interest are at or near the nano-scale so...

Biogeochemical Barriers: Redox Behavior of Metals and Metalloids

EPA Science Inventory

Redox conditions and pH are arguably the most important geochemical parameters that control contaminant transport and fate in groundwater systems. Oxidation-reduction (redox) reactions mediate the chemical behavior of both inorganic and organic chemical constituents by affecting...

Devonian volcanic rocks of the southern Chinese Altai, NW China: Petrogenesis and implication for a propagating slab-window magmatism induced by ridge subduction during accretionary orogenesis

NASA Astrophysics Data System (ADS)

Ma, Xiaomei; Cai, Keda; Zhao, Taiping; Bao, Zihe; Wang, Xiangsong; Chen, Ming; Buslov, M. M.

2018-07-01

Ridge-trench interaction is a common tectonic process of the present-day Pacific Rim accretionary orogenic belts, and this process may facilitate "slab-window" magmatism that can produce significant thermal anomalies and geochemically unusual magmatic events. However, ridge-trench interaction has rarely been well-documented in the ancient geologic record, leading to grossly underestimation of this process in tectonic syntheses of plate margins. The Chinese Altai was inferred to have undergone ridge subduction in the Devonian and a slab-window model is proposed to interpret its high-temperature metamorphism and geochemically unique magmatic rocks, which can serve as an excellent and unique place to refine the tectonic evolution associated with ridge subduction in an ancient accretionary orogeny. For this purpose, we carried out geochemical and geochronological studies on Devonian basaltic rocks in this region. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating results yield an age of 376.2 ± 2.4 Ma, suggesting an eruption at the time of Late Devonian. Geochemically, the samples in this study have variable SiO2 (43.3-58.3 wt%), low K2O (0.02-0.07 wt%) and total alkaline contents (2.16-5.41 wt%), as well as Fe2O3T/MgO ratios, showing typical tholeiitic affinity. On the other hand, the basaltic rocks display MORB-like REE patterns ((La/Yb)N = 0.90-2.57) and (Ga/Yb)N = 0.97-1.28), and have moderate positive εNd(t) values (+4.4 to +5.4), which collectively suggest a derivation from a mixing source comprising MORB-like mantle of a mature back-arc basin and subordinate arc mantle wedge. These basaltic rocks are characterized by Low La/Yb (1.26-3.69), Dy/Yb (1.51-1.77) and Sm/Yb (0.83-1.32) ratios, consistent with magmas derived from low degree (∼10%) partial melting of the spinel lherzolite source at a quite shallow mantle depth. Considering the distinctive petrogenesis of the basaltic rocks in this region, the Late Devonian basalts in the southern Chinese Altai is suggested to have witnessed the propagating process of slab-window magmatism that was induced by ridge subduction in a nascent rifting stage of a back-arc basin.

Geochemical soil sampling for deeply-buried mineralized breccia pipes, northwestern Arizona

USGS Publications Warehouse

Wenrich, K.J.; Aumente-Modreski, R. M.

1994-01-01

Thousands of solution-collapse breccia pipes crop out in the canyons and on the plateaus of northwestern Arizona; some host high-grade uranium deposits. The mineralized pipes are enriched in Ag, As, Ba, Co, Cu, Mo, Ni, Pb, Sb, Se, V and Zn. These breccia pipes formed as sedimentary strata collapsed into solution caverns within the underlying Mississippian Redwall Limestone. A typical pipe is approximately 100 m (300 ft) in diameter and extends upward from the Redwall Limestone as much as 1000 m (3000 ft). Unmineralized gypsum and limestone collapses rooted in the Lower Permian Kaibab Limestone or Toroweap Formation also occur throughout this area. Hence, development of geochemical tools that can distinguish these unmineralized collapse structures, as well as unmineralized breccia pipes, from mineralized breccia pipes could significantly reduce drilling costs for these orebodies commonly buried 300-360 m (1000-1200 ft) below the plateau surface. Design and interpretation of soil sampling surveys over breccia pipes are plagued with several complications. (1) The plateau-capping Kaibab Limestone and Moenkopi Formation are made up of diverse lithologies. Thus, because different breccia pipes are capped by different lithologies, each pipe needs to be treated as a separate geochemical survey with its own background samples. (2) Ascertaining true background is difficult because of uncertainties in locations of poorly-exposed collapse cones and ring fracture zones that surround the pipes. Soil geochemical surveys were completed on 50 collapse structures, three of which are known mineralized breccia pipes. Each collapse structure was treated as an independent geochemical survey. Geochemical data from each collapse feature were plotted on single-element geochemical maps and processed by multivariate factor analysis. To contrast the results between geochemical surveys (collapse structures), a means of quantifying the anomalousness of elements at each site was developed. This degree of anomalousness, named the "correlation value", was used to rank collapse features by their potential to overlie a deeply-buried mineralized breccia pipe. Soil geochemical results from the three mineralized breccia pipes (the only three of the 50 that had previously been drilled) show that: (1) Soils above the SBF pipe contain significant enrichment of Ag, Al, As, Ba, Ga, K, La, Mo, Nd, Ni, Pb, Sc, Th, U and Zn, and depletion in Ca, Mg and Sr, in contrast to soils outside the topographic and structural rim; (2) Soils over the inner treeless zone of the Canyon pipe show Mo and Pb enrichment anf As and Ga depletion, in contrast to soils from the surrounding forest; and (3) The soil survey of the Mohawk Canyon pipe was a failure because of the rocky terrane and lack of a B soil horizon, or because the pipe plunges. At least 11 of the 47 other collapse structures studied contain anomalous soil enrichments similar to the SBF uranium ore-bearing pipe, and thus have good potential as exploration targets for uranium. One of these 11, #1102, does contain surface mineralized rock. These surveys suggest that soil geochemical sampling is a useful tool for the recognition of many collapse structures with underlying ore-bearing breccia pipes. ?? 1994.

Provenance discrimination of sediments in the Zhejiang-Fujian mud belt, East China Sea: Implications for the development of the mud depocenter

NASA Astrophysics Data System (ADS)

Liu, Xiting; Li, Anchun; Dong, Jiang; Lu, Jian; Huang, Jie; Wan, Shiming

2018-01-01

In the past decade, the 800 km elongated mud belt off Zhejiang-Fujian coast, East China Sea (ECS), has been extensively studied for understanding the source to sink processes on the East Asian continental margin in the context of the Asian monsoon. However, to better understand the sediment source and dispersal pattern, the existing mineralogical and geochemical data of adjacent river systems, including the Changjiang River (CJR) and local rivers in Zhejiang, Fujian and Taiwan, need to be systematically reviewed. Therefore, various indicators from published literatures for the provenance discrimination in the mud belt have been summarised in this article. The results show that high diversity of clay mineral assemblages in fluvial sediments being supplied into the mud belt, e.g., dominant illite and chlorite in the CJR, absence of smectite in Taiwan rivers, similar amounts of the four clay mineral species in Zhejiang rivers, and dominant kaolinite in Fujian rivers. On heavy mineralogy, the CJR is dominated by dolomite, hornblende, and flaky minerals; and among of them, dolomite is distinctive for the CJR. For geochemical approaches, elemental compositions, combined with strontium and neodymium isotopes, reflect strong provenance control. However, geochemical and mineralogical compositions are found to vary with grain size, and thus extra caution should be taken when using these parameters as provenance indicator to discriminate the marine sediments with variety of grain-size fractions. In addition, pyrrhotite, occurred in fluvial sediments from western Taiwan, has not been found in sediments derived from mainland China, indicating that magnetic parameters could be used to discriminate sediment provenance. The mud belt formed during sea-level highstand, when modern current system in the ECS has been established, resulting in sediments derived from the CJR have been transported southward since 8 ka. In addition, sediment provenances have not been constant since initiation of the mud belt in response to climatic and oceanographic changes during the Holocene, which has been documented by mineral and geochemical signals. Nevertheless significant studies have been carried out, to better understand the formation mechanism for the mud belt and its implications for environmental changes, further studies on sediment provenance throughout the Holocene, in situ observation, and sedimentation dynamical modelling are required.

Early warning risk assessment for drinking water production: decoding subtle evidence

NASA Astrophysics Data System (ADS)

Merz, Christoph; Lischeid, Gunnar; Böttcher, Steven

2016-04-01

Due to increasing demands for high quality water for drinking water supply all over the world there is acute need for methods to detect possible threats to groundwater resources early. Especially drinking water production in complex geologic settings has a particularly high risk for unexpected degradation of the groundwater quality due to the unknown interplay between anthropogenically induced hydraulic changes and geochemical processes. This study investigates the possible benefit of the Principal Component Analysis (PCA) for groundwater and drinking water management using common sets of physicochemical monitoring data. The approach was used to identify the prevailing processes driving groundwater quality shifts and related threats, which might be masked in anthropogenically impacted aquifer systems. The approach was applied to a data set from a waterworks located in the state of Brandenburg, NE Germany, which has been operating since nearly four decades. The region faces confronting and increasing demands due to rising peri-urban settlements. The PCA subdivided the data set according to different strengths of effects induced by differing geochemical processes at different sites in the capture zone of the waterworks and varying in time. Thus a spatial assessment of these processes could be performed as well as a temporal assessment of long-term groundwater quality shifts in the extracted water. The analysis revealed that over the period of 16 years of water withdrawal the geochemistry of the extracted groundwater had become increasingly more dissimilar compared to the characteristics found at the majority of observation wells. This component could be identified as highly mineralized CaSO4 dominated water from unexamined deeper zones of the aquifer system. Due to the complex geochemical and hydraulic interactions in the system, this process was masked and was not evident in the data set without validation by the applied statistical analysis. The findings give a clear indication of a potential threat to the groundwater resources in this region with danger for drinking water contamination in a medium-term period.

SeSBench - An initiative to benchmark reactive transport models for environmental subsurface processes

NASA Astrophysics Data System (ADS)

Jacques, Diederik

2017-04-01

As soil functions are governed by a multitude of interacting hydrological, geochemical and biological processes, simulation tools coupling mathematical models for interacting processes are needed. Coupled reactive transport models are a typical example of such coupled tools mainly focusing on hydrological and geochemical coupling (see e.g. Steefel et al., 2015). Mathematical and numerical complexity for both the tool itself or of the specific conceptual model can increase rapidly. Therefore, numerical verification of such type of models is a prerequisite for guaranteeing reliability and confidence and qualifying simulation tools and approaches for any further model application. In 2011, a first SeSBench -Subsurface Environmental Simulation Benchmarking- workshop was held in Berkeley (USA) followed by four other ones. The objective is to benchmark subsurface environmental simulation models and methods with a current focus on reactive transport processes. The final outcome was a special issue in Computational Geosciences (2015, issue 3 - Reactive transport benchmarks for subsurface environmental simulation) with a collection of 11 benchmarks. Benchmarks, proposed by the participants of the workshops, should be relevant for environmental or geo-engineering applications; the latter were mostly related to radioactive waste disposal issues - excluding benchmarks defined for pure mathematical reasons. Another important feature is the tiered approach within a benchmark with the definition of a single principle problem and different sub problems. The latter typically benchmarked individual or simplified processes (e.g. inert solute transport, simplified geochemical conceptual model) or geometries (e.g. batch or one-dimensional, homogeneous). Finally, three codes should be involved into a benchmark. The SeSBench initiative contributes to confidence building for applying reactive transport codes. Furthermore, it illustrates the use of those type of models for different environmental and geo-engineering applications. SeSBench will organize new workshops to add new benchmarks in a new special issue. Steefel, C. I., et al. (2015). "Reactive transport codes for subsurface environmental simulation." Computational Geosciences 19: 445-478.

TOUGHREACT: a new code of the TOUGH Family for Non-Isothermal multiphase reactive geochemical transport in variably saturated geologic media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas

Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. We have developed a comprehensive numerical simulator, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. The code can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity.

Hawaiian lavas: a window into mantle dynamics

NASA Astrophysics Data System (ADS)

Jones, Tim; Davies, Rhodri; Campbell, Ian

2017-04-01

The emergence of double track volcanism at Hawaii has traditionally posed two problems: (i) the physical emergence of two parallel chains of volcanoes at around 3 Ma, named the Loa and Kea tracks after the largest volcanoes in their sequence, and (ii) the systematic geochemical differences between the erupted lavas along each track. In this study, we dissolve this distinction by providing a geodynamical explanation for the physical emergence of double track volcanism at 3 Ma and use numerical models of the Hawaiian plume to illustrate how this process naturally leads to each volcanic track sampling distinct mantle compositions, which accounts for much of the geochemical characteristics of the Loa and Kea trends.

Changes in sediment-associated trace element concentrations in the Seine river basin (1994-2001)

USGS Publications Warehouse

Meybeck, Michel; Horowitz, A.J.; Grosbois, C.; Gueguen, Y.; ,

2003-01-01

In the 1980's, based on the concentrations of particulate-associated Hg, Cd, Pb, Cu and Zn relative to very low natural background levels, the Seine River Basin was one of the most impacted in the world. Over the past 20 years, there has been a general decline in these elevated concentrations that parallels declines in Paris sewage sludge trace element levels. Within the basin, marked differences in spatial and temporal geochemical patterns have been observed: (1) between major tributaries, (2) between trace elements, and (3) with stream order and population density, all of which illustrate the complexity of the geochemical processes ongoing in the basin.

A stream sediment geochemical survey of the Ganga River headwaters in the Garhwal Himalaya

USGS Publications Warehouse

Mukherjee, P.K.; Purohit, K.K.; Saini, N.K.; Khanna, P.P.; Rathi, M.S.; Grosz, A.E.

2007-01-01

This study models geochemical and adjunct geologic data to define provinces that are favorable for radioactive-mineral exploration. A multi-element bed-sediment geochemical survey of streams was carried out in the headwaters region of the Ganga River in northern India. Overall median values for uranium and thorium (3.6 and 13.8 ppm; maxima of 4.8 and 19.0 ppm and minima of 3.1 and 12.3 ppm respectively) exceed average upper crustal abundances (2.8 and 10.7 ppm) for these radioactive elements. Anomalously high values reach up to 8.3 and 30.1 ppm in thrust zone rocks, and 11.4 and 22.5 ppm in porphyroids. At their maxima, these abundances are nearly four- and three-fold (respectively) enriched in comparison to average crustal abundances for these rock types. Deformed, metamorphosed and sheared rocks are characteristic of the main central thrust zone (MCTZ). These intensively mylonitized rocks override and juxtapose porphyritic (PH) and proterozoic metasedimentary rock sequences (PMS) to the south. Granitoid rocks, the major protoliths for mylonites, as well as metamorphosed rocks in the MCT zone are naturally enriched in radioelements; high values associated with sheared and mylonitized zones are coincident with reports of radioelement mineralization and with anomalous radon concentrations in soils. The radioelement abundance as well as REE abundance shows a northward enrichment trend consistent with increasing grade of metamorphism indicating deformation-induced remobilization of these elements. U and Th illustrate good correlation with REEs but not with Zr. This implies that zircon is not a principal carrier of U and Th within the granitoid-dominant thrust zone and that other radioelement-rich secondary minerals are present in considerable amounts. Thus, the relatively flat, less fractionated, HREE trend is also not entirely controlled by zircon. The spatial correlation of geologic boundary zones (faults, sheared zones) with geochemical and with geophysical (Rn) anomalies infers ore mineralization by hydrothermal processes generated during multiple episodes of deformation and thrusting. The geologic setting of the anomalies also suggests that crystalline rocks (MCT Zone) along the nearly 2500 km length of the LesserHimalayan belt, where in the vicinity of thrust and fault zones, have potential for radioelement mineralization. Zones of higher concentrations of radioelements delineated by this study and locations of anomalous radon discharge determined by other investigations may indicate a potential health hazard over the long term. However, the low human population density precludes direct manifestation of health effects attributable to chronic exposure to these radioelements; however, the magnitude of natural concentrations suggests the need for more detailed studies and monitoring. Copyright ?? 2007 by The Geochemical Society of Japan.

Geochemical and physical drivers of microbial community structure in hot spring ecosystems

NASA Astrophysics Data System (ADS)

Havig, J. R.; Hamilton, T. L.; Boyd, E. S.; Meyer-Dombard, D. R.; Shock, E.

2012-12-01

Microbial communities in natural systems are typically characterized using samples collected from a single time point, thereby neglecting the temporal dynamics that characterize natural systems. The composition of these communities obtained from single point samples is then related to the geochemistry and physical parameters of the environment. Since most microbial life is adapted to a relatively narrow ecological niche (multiplicity of physical and chemical parameters that characterize a local habitat), these assessments provide only modest insight into the controls on community composition. Temporal variation in temperature or geochemical composition would be expected to add another dimension to the complexity of niche space available to support microbial diversity, with systems that experience greater variation supporting a greater biodiversity until a point where the variability is too extreme. . Hot springs often exhibit significant temporal variation, both in physical as well as chemical characteristics. This is a result of subsurface processes including boiling, phase separation, and differential mixing of liquid and vapor phase constituents. These characteristics of geothermal systems, which vary significantly over short periods of time, provide ideal natural laboratories for investigating how i) the extent of microbial community biodiversity and ii) the composition of those communities are shaped by temporal fluctuations in geochemistry. Geochemical and molecular samples were collected from 17 temporally variable hot springs across Yellowstone National Park, Wyoming. Temperature measurements using data-logging thermocouples, allowing accurate determination of temperature maximums, minimums, and ranges for each collection site, were collected in parallel, along with multiple geochemical characterizations as conditions varied. There were significant variations in temperature maxima (54.5 to 90.5°C), minima (12.5 to 82.5°C), and range (3.5 to 77.5°C) for the hot spring environments that spanned ranges of pH values (2.2 to 9.0) and geochemical compositions. We characterized the abundance, composition, and phylogenetic diversity of bacterial and archaeal 16S rRNA gene assemblages in sediment/biofilm samples collected from each site. 16S data can be used as proxy for metabolic dissimilarity. We predict that temporally fluctuating environments should provide additional complexity to the system (additional niche space) capable of supporting additional taxa, which should lead to greater 16S rRNA gene diversity. However, systems with too much variability should collapse the diversity. Thus, one would expect an optimal system for variability, with respect to 16S phylogenetic diversity. Community ecology tools were then applied to model the relative influence of physical and chemical characteristics (including temperature dynamics) on the local biodiversity. The results reveal unique insight into the role of temporal environmental variation in the development of biodiverse communities and provide a platform for predicting the response of an ecosystem to temperature perturbation.

GEOCHEMICAL FACTORS GOVERNING METHYL MERCURY PRODUCTION IN MERCURY CONTAMINATED SEDIMENTS

EPA Science Inventory

Bench scale experiments were conducted to improve our understanding of aquatic mercury transformation processes (biotic and abiotic), specifically those factors which govern the production of methyl mercury (MeHg) in sedimentary environments. The greatest cause for concern regar...

ELECTRON TRANSFER MECHANISM AT THE SOLID-LIQUID INTERFACE OF PHYLLOSILICATES

EPA Science Inventory

Interfacial electron transfer processes on clay minerals have significant impact in natural environments and geochemical systems. Nitrobenzene was used as molecular probes to study the electron transfer mechanism at the solid-water interfaces of Fe-containing phyllosicates. For...

ASSESSING THE GEOCHEMICAL FATE OF DEEP-WELL-INJECTED HAZARDOUS WASTE: A REFERENCE GUIDE

EPA Science Inventory

The geochemical fate of deep-well-injected wastes must be thoroughly understood to avoid problems when incompatibility between the injected wastes and the injection-zone formation is a possibility. An understanding of geochemical fate will be useful when a geochemical no-migratio...

Geochemical variations of rare earth elements in Marcellus shale flowback waters and multiple-source cores in the Appalachian Basin

NASA Astrophysics Data System (ADS)

Noack, C.; Jain, J.; Hakala, A.; Schroeder, K.; Dzombak, D. A.; Karamalidis, A.

2013-12-01

Rare earth elements (REE) - encompassing the naturally occurring lanthanides, yttrium, and scandium - are potential tracers for subsurface groundwater-brine flows and geochemical processes. Application of these elements as naturally occurring tracers during shale gas development is reliant on accurate quantitation of trace metals in hypersaline brines. We have modified and validated a liquid-liquid technique for extraction and pre-concentration of REE from saline produced waters from shale gas extraction wells with quantitative analysis by ICP-MS. This method was used to analyze time-series samples of Marcellus shale flowback and produced waters. Additionally, the total REE content of core samples of various strata throughout the Appalachian Basin were determined using HF/HNO3 digestion and ICP-MS analysis. A primary goal of the study is to elucidate systematic geochemical variations as a function of location or shale characteristics. Statistical testing will be performed to study temporal variability of inter-element relationships and explore associations between REE abundance and major solution chemistry. The results of these analyses and discussion of their significance will be presented.

Temporal variations in parameters reflecting terminal-electron-accepting processes in an aquifer contaminated with waste fuel and chlorinated solvents

USGS Publications Warehouse

McGuire, Jennifer T.; Smith, Erik W.; Long, David T.; Hyndman, David W.; Haack, Sheridan K.; Klug, Michael J.; Velbel, Michael A.

2000-01-01

A fundamental issue in aquifer biogeochemistry is the means by which solute transport, geochemical processes, and microbiological activity combine to produce spatial and temporal variations in redox zonation. In this paper, we describe the temporal variability of TEAP conditions in shallow groundwater contaminated with both waste fuel and chlorinated solvents. TEAP parameters (including methane, dissolved iron, and dissolved hydrogen) were measured to characterize the contaminant plume over a 3-year period. We observed that concentrations of TEAP parameters changed on different time scales and appear to be related, in part, to recharge events. Changes in all TEAP parameters were observed on short time scales (months), and over a longer 3-year period. The results indicate that (1) interpretations of TEAP conditions in aquifers contaminated with a variety of organic chemicals, such as those with petroleum hydrocarbons and chlorinated solvents, must consider additional hydrogen-consuming reactions (e.g., dehalogenation); (2) interpretations must consider the roles of both in situ (at the sampling point) biogeochemical and solute transport processes; and (3) determinations of microbial communities are often necessary to confirm the interpretations made from geochemical and hydrogeological measurements on these processes.

Rock geochemistry related to mineralization processes in geothermal areas

NASA Astrophysics Data System (ADS)

Kausar, A. Al; Indarto, S.; Setiawan, I.

2018-02-01

Abundant geothermal systems in Indonesia suggest high heat and mass transfer associated with recent or paleovolcanic arcs. In the active geothermal system, the upflow of mixed fluid between late stage hydrothermal and meteoric water might contain mass of minerals associated with epithermal mineralisation process as exemplified at Lihir gold mine in Papua New Guinea. In Indonesia, there is a lack of study related to the precious metals occurrence within active geothermal area. Therefore, in this paper, we investigate the possibility of mineralization process in active geothermal area of Guci, Central Java by using geochemical analysis. There are a lot of conducted geochemical analysis of water, soil and gas by mapping the temperature, pH, Hg and CO2 distribution, and estimating subsurface temperature based on geothermometry approach. Then we also apply rock geochemistry to find minerals that indicate the presence of mineralization. The result from selected geothermal area shows the presence of pyrite and chalcopyrite minerals on the laharic breccias at Kali Putih, Sudikampir. Mineralization is formed within host rock and the veins are associated with gold polymetallic mineralization.

Video processing of remote sensor data applied to uranium exploration in Wyoming. [Roll-front U deposits

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levinson, R.A.; Marrs, R.W.; Crockell, F.

1979-06-30

LANDSAT satellite imagery and aerial photography can be used to map areas of altered sandstone associated with roll-front uranium deposits. Image data must be enhanced so that alteration spectral contrasts can be seen, and video image processing is a fast, low-cost, and efficient tool. For LANDSAT data, the 7/4 ratio produces the best enhancement of altered sandstone. The 6/4 ratio is most effective for color infrared aerial photography. Geochemical and mineralogical associations occur in unaltered, altered, and ore roll-front zones. Samples from Pumpkin Buttes show that iron is the primary coloring agent which makes alteration visually detectable. Eh and pHmore » changes associated with passage of a roll front cause oxidation of magnetite and pyrite to hematite, goethite, and limonite in the host sandstone, thereby producing the alteration. Statistical analysis show that the detectability of geochemical and color zonation in host sands is weakened by soil-forming processes. Alteration can only be mapped in areas of thin soil cover and moderate to sparse vegetative cover.« less

Archaeal and bacterial community analysis of several Yellowstone National Park hot springs

NASA Astrophysics Data System (ADS)

Colman, D. R.; Takacs-Vesbach, C. D.

2012-12-01

The hot springs of Yellowstone National Park (YNP) are home to a diverse assemblage of microorganisms. Culture-independent studies have significantly expanded our understanding of the diversity of both Bacteria and Archaea present in YNP springs as well as the geochemical and ecological controls on communities. While the ecological analysis of Bacteria among the physicochemically heterogenous springs of YNP has been previously conducted, less is known about the extent of diversity of Archaeal communities and the chemical and ecological controls on their populations. Here we report a culture-independent analysis of 31 hot spring archaeal and bacterial communities of YNP springs using next generation sequencing. We found the phylogenetic diversity of Archaea to be generally comparable to that of co-occurring bacterial communities although overall, in the springs we investigated, diversity was higher for Bacteria than Archaea. Chemical and physical controls were similar for both domains with pH correlating most strongly with community composition. Community differences reflected the partitioning of taxonomic groups in low or high pH springs for both domains. Results will be discussed in a geochemical and ecological context.

Rock Geochemistry and Mineralogy from Fault Zones and Polymetallic Fault Veins of the Central Front Range, Colorado

USGS Publications Warehouse

Caine, Jonathan S.; Bove, Dana J.

2010-01-01

During the 2004 to 2008 field seasons, approximately 200 hand samples of fault and polymetallic vein-related rocks were collected for geochemical and mineralogical analyses. The samples were collected by the U.S. Geological Survey as part of the Evolution of Brittle Structures Task under the Central Colorado Assessment Project (CCAP) of the Mineral Resources Program (http://minerals.cr.usgs.gov/projects/colorado_assessment/index.html). The purpose of this work has been to characterize the relation between epithermal, polymetallic mineral deposits, paleostress, and the geological structures that hosted fluid flow and localization of the deposits. The data in this report will be used to document and better understand the processes that control epithermal mineral-deposit formation by attempting to relate the geochemistry of the primary structures that hosted hydrothermal fluid flow to their heat and fluid sources. This includes processes from the scale of the structures themselves to the far field scale, inclusive of the intrusive bodies that have been thought to be the sources for the hydrothermal fluid flow. The data presented in this report are part of a larger assessment effort on public lands. The larger study area spans the region of the southern Rocky Mountains in Colorado from the Wyoming to New Mexico borders and from the eastern boundary of the Front Range to approximately the longitude of Vail and Leadville, Colorado. Although the study area has had an extensive history of geological mapping, the mapping has resulted in a number of hypotheses that are still in their infancy of being tested. For example, the proximity of polymetallic veins to intrusive bodies has been thought to reflect a genetic relation between the two features; however, this idea has not been well tested with geochemical indicators. Recent knowledge regarding the coupled nature of stress, strain, fluid flow, and geochemistry warrant new investigations and approaches to test a variety of ideas regarding the genetic processes associated with ore-deposit formation. The central part of the eastern Front Range has excellent exposures of fault zones and polymetallic fault veins, subsequently resulting in some of the most detailed mapping and associated data sets in the region. Thus, the area was chosen for detailed data compilation, new sample and data collection, and a variety of structural and geochemical analyses. The data presented in this report come from samples of fault-related exposures in the Front Range and include elemental chemistry and mineralogy from the outcrop-scale study localities within the larger CCAP study area.

Evidence and characteristics of hydrolytic disproportionation of organic matter during metasomatic processes

USGS Publications Warehouse

Price, L.C.; Dewitt, E.

2001-01-01

Petroleum-geochemical analyses of carbonaceous regionally metamorphosed rocks, carbonaceous rocks from ore deposits, and alkalic plutonic rocks from diverse settings, demonstrated the presence of very low to moderately low concentrations of solvent-extractable organic matter, this observation in spite of the fact that some of these rocks were exposed to extremely high metamorphic temperatures. Biomarker and ??13C analyses established that the extractable organic matter originated as sedimentary-derived hydrocarbons. However, the chemistry of the extractable bitumen has been fundamentally transformed from that found in sediment bitumen and oils. Asphaltenes and resins, as defined in the normal petroleum-geochemical sense, are completely missing. The principal aromatic hydrocarbons present in oils and sediment bitumens (especially the methylated naphthalenes) are either in highly reduced concentrations or are missing altogether, Instead, aromatic hydrocarbons typical of sediment bitumens and oils are very minor, and a number of unidentified compounds and oxygen-bearing compounds are dominant. Relatively high concentrations of alkylated benzenes are typical. The polar "resin" fraction, eluted during column chromatography, is the principal compound group, by weight, being composed of six to eight dominant peaks present in all samples, despite the great geologic diversity of the samples. These, and other, observations suggest that a strong drive towards equilibrium exists in the "bitumen." Gas chromatograms of the saturated hydrocarbons commonly have a pronounced hump in both the n-paraffins and naphthenes, centered near the C19 to C26 carbon numbers, and a ubiquitos minimum in the n-paraffin distribution near n-C12 to n-C14. Multiple considerations dictate that the bitumen in the samples is indigenous and did not originate from either surficial field contamination or from laboratory procedures. Our observations are consistent with the hydrolytic disproportion of organic matter (HDOM), in which water and organic matter, including hydrocarbons, easily exchange hydrogen or oxygen with one another under certain conditions (Helgeson et al., 1993). The process appears to take place via well-known organic-chemical redox reaction pathways and is most evident in open-fluid systems. The conclusion that HDOM took place in the analyzed samples, thus producing the chemistry of the extractable bitumen, is supported by numerous previously published organic-geochemical studies of metamorphic, volcanic, plutonic, and ore-deposit-related rocks by other investigators. HDOM is suggested as an unrecognized geologic agent of fundamental importance. The process appears to control major chemical reactions in diverse geologic environments including, but not limited to, petroleum geology and geochemistry, regional metamorphism, and base- and precious-metal ore deposition. Copyright ?? 2001 Elsevier Science Ltd.

Petrography and geochemistry of the primary ore zone of the Kenticha rare metal granite-pegmatite field, Adola Belt, Southern Ethiopia: Implications for ore genesis and tectonic setting

NASA Astrophysics Data System (ADS)

Mohammedyasin, Mohammed Seid; Desta, Zerihun; Getaneh, Worash

2017-10-01

The aim of this work is to evaluate the genesis and tectonic setting of the Kenticha rare metal granite-pegmatite deposit using petrography and whole-rock geochemical analysis. The samples were analysed for major elements, and trace and rare earth elements by ICP-AES and ICP-MS, respectively. The Kenticha rare metal granite-pegmatite deposit is controlled by the N-S deep-seated normal fault that allow the emplacement of the granite-pegmatite in the study area. Six main mineral assemblages have been identified: (a) alaskitic granite (quartz + microcline + albite with subordinate muscovite), (b) aplitic layer (quartz + albite), (c) muscovite-quartz-microcline-albite pegmatite, (d) spodumene-microcline-albite pegmatite, partly albitized or greisenized, (e) microcline-albite-green and pink spodumene pegmatite with quartz-microcline block, which is partly albitized and greisenized, and (f) quartz core. This mineralogical zonation is also accompanied by variation in Ta ore concentration and trace and rare earth elements content. The Kenticha granite-pegmatite is strongly differentiated with high SiO2 (72-84 wt %) and enriched with Rb (∼689 ppm), Be (∼196 ppm), Nb (∼129 ppm), Ta (∼92 ppm) and Cs (∼150 ppm) and depleted in Ba and Sr. The rare earth element (REE) patterns of the primary ore zone (below 60 m depth) shows moderate enrichment in light REE ((La/Yb)N = ∼8, and LREE/HREE = ∼9.96) and negative Eu-anomaly (Eu/Eu* = ∼0.4). The whole-rock geochemical data display the Within Plate Granite (WPG) and syn-Collisional Granite (syn-COLG) suites and interpret as its formation is crustal related melting. The mineralogical assemblage, tectonic setting and geochemical signatures implies that the Kenticha rare metal bearing granite pegmatite is formed by partial melting of metasedimentary rocks during post-Gondwana assembly and further tantalite enrichment through later hydrothermal-metasomatic processes.

Impact of hydrological alterations on river-groundwater exchange and water quality in a semi-arid area: Nueces River, Texas.

PubMed

Murgulet, Dorina; Murgulet, Valeriu; Spalt, Nicholas; Douglas, Audrey; Hay, Richard G

2016-12-01

There is a lack of understanding and methods for assessing the effects of anthropogenic disruptions, (i.e. river fragmentation due to dam construction) on the extent and degree of groundwater-surface water interaction and geochemical processes affecting the quality of water in semi-arid, coastal catchments. This study applied a novel combination of electrical resistivity tomography (ERT) and elemental and isotope geochemistry in a coastal river disturbed by extended drought and periodic flooding due to the operation of multiple dams. Geochemical analyses show that the saltwater barrier causes an increase in salinity in surface water in the downstream river as a result of limited freshwater inflows, strong evaporation effects on shallow groundwater and mostly stagnant river water, and is not due to saltwater intrusion by tidal flooding. Discharge from bank storage is dominant (~84%) in the downstream fragment and its contribution could increase salinity levels within the hyporheic zone and surface water. When surface water levels go up due to upstream freshwater releases the river temporarily displaces high salinity water trapped in the hyporheic zone to the underlying aquifer. Geochemical modeling shows a higher contribution of distant and deeper groundwater (~40%) in the upstream river and lower discharge from bank storage (~13%) through the hyporheic zone. Recharge from bank storage is a source of high salt to both upstream and downstream portions of the river but its contribution is higher below the dam. Continuous ERT imaging of the river bed complements geochemistry findings and indicate that while lithologically similar, downstream of the dam, the shallow aquifer is affected by salinization while fresher water saturates the aquifer in the upstream fragment. The relative contribution of flows (i.e. surface water releases or groundwater discharge) as related to the river fragmentation control changes of streamwater chemistry and likely impact the interpretation of seasonal trends. Copyright © 2016 Elsevier B.V. All rights reserved.

Arsenic: geochemical distribution and health risk in Italy

NASA Astrophysics Data System (ADS)

Zuzolo, Daniela; Cicchella, Domenico; Albanese, Stefano; Catani, Vittorio; Dinelli, Enrico; Lima, Annamaria; Valera, Paolo; De Vivo, Benedetto

2017-04-01

Characterization of risks to human health is determinant for risk management and population surveillance. This study represent the first work at national scale for Italy about arsenic occurrence, distribution and health impact. We analyzed the As geochemical distribution in different environmental matrices on the whole Italian territory, and assessed both carcinogenic and non-carcinogenic risks for different exposure routes and age groups. The results demonstrate that, in Italy, arsenic is present in significant concentrations both in water (up to 27.2 µg/L) and soils (up to 70 mg/kg). Its presence is mainly controlled by geological processes and locally reflects the industrial history of the Country. The population of the Central Italy, where high content of arsenic in the analyzed samples is due to the presence of alkaline volcanics, are the most exposed to the health risk. Based on the results of our work, it is clear that the consumption of tap water for potable use is the most impactful route for As daily exposure and play an important role in governing potential cancer and non-cancer risks for the considered population. It is interesting to observe that the Incremental Life Cancer Risk through water ingestion show that almost 80% of data falls above the internationally accepted benchmark value of 1 x 10-5. Moreover it was demonstrated that childhood is the most susceptible age stage to As exposure. Geochemical mapping provided a useful tool to spatially analyze and represent data and to highlight the most critic areas and the most exposed population to arsenic at national scale. In conclusion, this study improve knowledge about As occurrence for an entire Country, recognizing an health emerging problem. It might be a good starting point to support the urgently needed policy actions, in order to prevent and reduce the health risk. Moreover, the performed method in this case study research is potentially generalizable and applicable in other countries.

Inverse geochemical modeling of groundwater evolution with emphasis on arsenic in the Mississippi River Valley alluvial aquifer, Arkansas (USA)

USGS Publications Warehouse

Sharif, M.U.; Davis, R.K.; Steele, K.F.; Kim, B.; Kresse, T.M.; Fazio, J.A.

2008-01-01

Inverse geochemical modeling (PHREEQC) was used to identify the evolution of groundwater with emphasis on arsenic (As) release under reducing conditions in the shallow (25-30 m) Mississippi River Valley Alluvial aquifer, Arkansas, USA. The modeling was based on flow paths defined by high-precision (??2 cm) water level contour map; X-ray diffraction (XRD), scanning electron microscopic (SEM), and chemical analysis of boring-sediments for minerals; and detailed chemical analysis of groundwater along the flow paths. Potential phases were constrained using general trends in chemical analyses data of groundwater and sediments, and saturation indices data (MINTEQA2) of minerals in groundwater. Modeling results show that calcite, halite, fluorite, Fe oxyhydroxide, organic matter, H2S (gas) were dissolving with mole transfers of 1.40E - 03, 2.13E - 04, 4.15E - 06, 1.25E + 01, 3.11, and 9.34, respectively along the dominant flow line. Along the same flow line, FeS, siderite, and vivianite were precipitating with mole transfers of 9.34, 3.11, and 2.64E - 07, respectively. Cation exchange reactions of Ca2+ (4.93E - 04 mol) for Na+ (2.51E - 04 mol) on exchange sites occurred along the dominant flow line. Gypsum dissolution reactions were dominant over calcite dissolution in some of the flow lines due to the common ion effect. The concentration of As in groundwater ranged from <0.5 to 77 ??g/L. Twenty percent total As was complexed with Fe and Mn oxyhydroxides. The redox environment, chemical data of sediments and groundwater, and the results of inverse geochemical modeling indicate that reductive dissolution of Fe oxyhydroxide is the dominant process of As release in the groundwater. The relative rate of reduction of Fe oxyhydroxide over SO42 - with co-precipitation of As into sulfide is the limiting factor controlling dissolved As in groundwater. ?? 2007 Elsevier B.V. All rights reserved.

Authigenic carbonate formation at hydrocarbon seeps in continental margin sediments: A comparative study

USGS Publications Warehouse

Naehr, T.H.; Eichhubl, P.; Orphan, V.J.; Hovland, M.; Paull, C.K.; Ussler, W.; Lorenson, T.D.; Greene, H. Gary

2007-01-01

Authigenic carbonates from five continental margin locations, the Eel River Basin, Monterey Bay, Santa Barbara Basin, the Sea of Okhotsk, and the North Sea, exhibit a wide range of mineralogical and stable isotopic compositions. These precipitates include aragonite, low- and high-Mg calcite, and dolomite. The carbon isotopic composition of carbonates varies widely, ranging from -60??? to +26???, indicating complex carbon sources that include 13C-depleted microbial and thermogenic methane and residual, 13C-enriched, bicarbonate. A similarly large variability of ??18O values (-5.5??? to +8.9???) demonstrates the geochemical complexity of these sites, with some samples pointing toward an 18O-enriched oxygen source possibly related to advection of 18O-enriched formation water or to the decomposition of gas hydrate. Samples depleted in 18O are consistent with formation deeper in the sediment or mixing of pore fluids with meteoric water during carbonate precipitation. A wide range of isotopic and mineralogical variation in authigenic carbonate composition within individual study areas but common trends across multiple geographic areas suggest that these parameters alone are not indicative for certain tectonic or geochemical settings. Rather, the observed variations probably reflect local controls on the flux of carbon and other reduced ions, such as faults, fluid conduits, the presence or absence of gas hydrate in the sediment, and the temporal evolution of the local carbon reservoir. Areas with seafloor carbonates that indicate formation at greater depth below the sediment-water interface must have undergone uplift and erosion in the past or are still being uplifted. Consequently, the occurrence of carbonate slabs on the seafloor in areas of active hydrocarbon seepage is commonly an indicator of exhumation following carbonate precipitation in the shallow subsurface. Therefore, careful petrographic and geochemical analyses are critical components necessary for the correct interpretation of processes related to hydrocarbon seepage in continental margin environments and elsewhere. ?? 2007 Elsevier Ltd. All rights reserved.

Mineral Dissolution and Precipitation due to Carbon Dioxide-Water-Rock Interactions: The Significance of Accessory Minerals in Carbonate Reservoirs (Invited)

NASA Astrophysics Data System (ADS)

Kaszuba, J. P.; Marcon, V.; Chopping, C.

2013-12-01

Accessory minerals in carbonate reservoirs, and in the caprocks that seal these reservoirs, can provide insight into multiphase fluid (CO2 + H2O)-rock interactions and the behavior of CO2 that resides in these water-rock systems. Our program integrates field data, hydrothermal experiments, and geochemical modeling to evaluate CO2-water-rock reactions and processes in a variety of carbonate reservoirs in the Rocky Mountain region of the US. These studies provide insights into a wide range of geologic environments, including natural CO2 reservoirs, geologic carbon sequestration, engineered geothermal systems, enhanced oil and gas recovery, and unconventional hydrocarbon resources. One suite of experiments evaluates the Madison Limestone on the Moxa Arch, Southwest Wyoming, a sulfur-rich natural CO2 reservoir. Mineral textures and geochemical features developed in the experiments suggest that carbonate minerals which constitute the natural reservoir will initially dissolve in response to emplacement of CO2. Euhedral, bladed anhydrite concomitantly precipitates in response to injected CO2. Analogous anhydrite is observed in drill core, suggesting that secondary anhydrite in the natural reservoir may be related to emplacement of CO2 into the Madison Limestone. Carbonate minerals ultimately re-precipitate, and anhydrite dissolves, as the rock buffers the acidity and reasserts geochemical control. Another suite of experiments emulates injection of CO2 for enhanced oil recovery in the Desert Creek Limestone (Paradox Formation), Paradox Basin, Southeast Utah. Euhedral iron oxyhydroxides (hematite) precipitate at pH 4.5 to 5 and low Eh (approximately -0.1 V) as a consequence of water-rock reaction. Injection of CO2 decreases pH to approximately 3.5 and increases Eh by approximately 0.1 V, yielding secondary mineralization of euhedral pyrite instead of iron oxyhydroxides. Carbonate minerals also dissolve and ultimately re-precipitate, as determined by experiments in the Madison Limestone, but pyrite will persist and iron oxyhydroxides will not recrystallize.

Geochemistry and origin of regional dolomites

NASA Astrophysics Data System (ADS)

Hanson, G. N.; Meyers, W. J.

1989-12-01

The major goal of the carbonate research program at Stony Brook is to better understand the conditions and processes leading to regional diagenesis of carbonate rocks. Our research focuses on studies of ancient, massive dolostones, but we are also studying limestone diagenesis for its own importance, and as it relates to dolomitization. Our approach has been to carry out a very detailed petrographic and geochemical case study to the Mississippian Burlington-Keokuk Fms. of Iowa, Illinois and Missouri, and to develop this as a testing ground for new geochemical and modelling techniques, and for testing various models for regional dolomitization in epicontinental carbonates. The ideas and techniques developed in our Burlington-Keokuk studies are being expanded and applied to carbonate sequences of other ages (Devonian to Neogene), and other tectono-sedimentary settings. The emphasis of this report will be on new developments and results on the Burlington-Keokuk studies and on our diagenetic studies of other strata. Recent research on Burlington-Keokuk rocks include development and application of boron isotopes and the U--Th--Pb system to dolomite studies, investigations of porosity and permeability in the dolostones. Projects on other strata include dolomitization and limestones diagenesis of Devonian carbonates of Alberta and Western Australia, Miocene reefal carbonates of Spain, Neogene carbonates of Curacao and Bonaire, Waulsortian limestones of Ireland, modelling of trace elements and stable isotopes, and experimental growth of calcites to investigate crystallographic controls of trace element incorporation.

Subsurface conditions in hydrothermal vents inferred from diffuse flow composition, and models of reaction and transport

NASA Astrophysics Data System (ADS)

Larson, B. I.; Houghton, J. L.; Lowell, R. P.; Farough, A.; Meile, C. D.

2015-08-01

Chemical gradients in the subsurface of mid-ocean ridge hydrothermal systems create an environment where minerals precipitate and dissolve and where chemosynthetic organisms thrive. However, owing to the lack of easy access to the subsurface, robust knowledge of the nature and extent of chemical transformations remains elusive. Here, we combine measurements of vent fluid chemistry with geochemical and transport modeling to give new insights into the under-sampled subsurface. Temperature-composition relationships from a geochemical mixing model are superimposed on the subsurface temperature distribution determined using a heat flow model to estimate the spatial distribution of fluid composition. We then estimate the distribution of Gibb's free energies of reaction beneath mid oceanic ridges and by combining flow simulations with speciation calculations estimate anhydrite deposition rates. Applied to vent endmembers observed at the fast spreading ridge at the East Pacific Rise, our results suggest that sealing times due to anhydrite formation are longer than the typical time between tectonic and magmatic events. The chemical composition of the neighboring low temperature flow indicates relatively uniform energetically favorable conditions for commonly inferred microbial processes such as methanogenesis, sulfate reduction and numerous oxidation reactions, suggesting that factors other than energy availability may control subsurface microbial biomass distribution. Thus, these model simulations complement fluid-sample datasets from surface venting and help infer the chemical distribution and transformations in subsurface flow.

Hydrogeochemical processes in the Plio-Quaternary Remila aquifer (Khenchela, Algeria)

NASA Astrophysics Data System (ADS)

Aouidane, Laiche; Belhamra, Mohamed

2017-06-01

The Remila Plain is a synclinal structure in northeast Algeria, situated within a semi-arid climate zone and composed of Mio-Pliocene-Quaternary deposits. Within the syncline, the Plio-Quaternary aquifer is the main source of drinking water for cattle and for agricultural irrigation water. This work aims to investigate the origin of groundwater mineralization and to identify the primary hydrogeochemical processes controlling groundwater evolution in the Remila aquifer. A total of 86 water samples from boreholes were analyzed for major, minor and stable isotopes (18O, 2H) over three seasons: first during low water levels in 2013, second during high water levels in 2014 and third for stable isotopes during low water levels in 2015. The analysis showed that the aquifer is controlled by five principal geochemical processes: (I) the dissolution of evaporite rocks, (II) cation exchange and reverse exchange reactions, (III) congruent dissolution of carbonates (calcite, dolomite) coupled with the dissolution of gypsum and calcite precipitation, (IV) sulfate reduction under anaerobic conditions, and (V) saltwater intrusion in the northeastern Sabkha plains. The 18O and deuterium concentrations in groundwater are very low, indicating that the aquifer is recharged by evaporated rainfall originating from the north slope of the Aurès Mountains which confirms that the aquifer is recharged in the southern part of the plain.

Petrologic and chemical changes in ductile shear zones as a function of depth in the continental crust

NASA Astrophysics Data System (ADS)

Yang, Xin-Yue

Petrologic and geochemical changes in ductile shear zones are important for understanding deformational and geochemical processes of the continental crust. This study examines three shear zones that formed under conditions varying from lower greenschist facies to upper amphibolite facies in order to document the petrologic and geochemical changes of deformed rocks at various metamorphic grades. The studied shear zones include two greenschist facies shear zones in the southern Appalachians and an upper amphibolite facies shear zone in southern Ontario. The mylonitic gneisses and mylonites in the Roses Mill shear zone of central Virginia are derived from a ferrodiorite protolith and characterized by a lower greenschist facies mineral assemblage. Both pressure solution and recrystallization were operative deformation mechanisms during mylonitization in this shear zone. Strain-driven dissolution and solution transfer played an important role in the mobilization of felsic components (Si, Al, K, Na, and Ca). During mylonitization, 17% to 32% bulk rock volume losses of mylonites are mainly attributed to removal of these mobile felsic components by a fluid phase. Mafic components (Fe, Mg, Ti, Mn and P) and trace elements, REE, Y, V and Sc, were immobile. At Rosman, North Carolina, the Brevard shear zone (BSZ) shows a deformational transition from the coarse-grained Henderson augen gneiss (HAG) to proto-mylonite, mylonite and ultra-mylonite. The mylonites contain a retrograde mineral assemblage as a product of fluid-assisted chemical breakdown of K-feldspar and biotite at higher greenschist facies conditions. Recrystallization and intra-crystalline plastic deformation are major deformation mechanisms in the BSZ. Fluid-assisted mylonitization in the BSZ led to 6% to 23% bulk volume losses in mylonites. During mylonitization, both major felsic and mafic elements and trace elements, Rb, Sr, Zr, V, Sc, and LREE were mobile; however, the HREEs were likely immobile. A shear zone in the Parry Sound domain, Ontario, formed at upper amphibolite facies conditions. The deformation process of the shear zone involves fully plastic deformation and high-temperature dynamic recrystallization and annealing recovery of both quartz and plagioclase. Geochemical evidence indicates that the chemical changes in the deformed rocks resulted from mixing of mafic and felsic layers together with fluid-assisted mass transfer within the shear zone. A geochemical model that incorporates closed-system two-component mixing with open-system mass transfer can well explain the observed major and trace element data.

A geochemical study of the winonaites: Evidence for limited partial melting and constraints on the precursor composition

NASA Astrophysics Data System (ADS)

Hunt, Alison C.; Benedix, Gretchen K.; Hammond, Samantha J.; Bland, Philip A.; Rehkämper, Mark; Kreissig, Katharina; Strekopytov, Stanislav

2017-02-01

The winonaites are primitive achondrites which are associated with the IAB iron meteorites. Textural evidence implies heating to at least the Fe, Ni-FeS cotectic, but previous geochemical studies are ambiguous about the extent of silicate melting in these samples. Oxygen isotope evidence indicates that the precursor material may be related to the carbonaceous chondrites. Here we analysed a suite of winonaites for modal mineralogy and bulk major- and trace-element chemistry in order to assess the extent of thermal processing as well as constrain the precursor composition of the winonaite-IAB parent asteroid. Modal mineralogy and geochemical data are presented for eight winonaites. Textural analysis reveals that, for our sub-set of samples, all except the most primitive winonaite (Northwest Africa 1463) reached the Fe, Ni-FeS cotectic. However, only one (Tierra Blanca) shows geochemical evidence for silicate melting processes. Tierra Blanca is interpreted as a residue of small-degree silicate melting. Our sample of Winona shows geochemical evidence for extensive terrestrial weathering. All other winonaites studied here (Fortuna, Queen Alexander Range 94535, Hammadah al Hamra 193, Pontlyfni and NWA 1463) have chondritic major-element ratios and flat CI-normalised bulk rare-earth element patterns, suggesting that most of the winonaites did not reach the silicate melting temperature. The majority of winonaites were therefore heated to a narrow temperature range of between ∼1220 (the Fe, Ni-FeS cotectic temperature) and ∼1370 K (the basaltic partial melting temperature). Silicate inclusions in the IAB irons demonstrate partial melting did occur in some parts of the parent body (Ruzicka and Hutson, 2010), thereby implying heterogeneous heat distribution within this asteroid. Together, this indicates that melting was the result of internal heating by short-lived radionuclides. The brecciated nature of the winonaites suggests that the parent body was later disrupted by a catastrophic impact, which allowed the preservation of the largely unmelted winonaites. Despite major-element similarities to both ordinary and enstatite chondrites, trace-element analysis suggests the winonaite parent body had a carbonaceous chondrite-like precursor composition. The parent body of the winonaites was volatile-depleted relative to CI, but enriched compared to the other carbonaceous classes. The closest match are the CM chondrites; however, the specific precursor is not sampled in current meteorite collections.

Geochemistry of K/T boundaries in India and contributions of Deccan volcanism

NASA Technical Reports Server (NTRS)

Bhandari, N.; Gupta, M.; Pandey, J.; Shukla, P. N.

1988-01-01

Three possible Cretaceous/Tertiary (K/T) boundary sections in the Indian subcontinent were studied for their geochemical and fossil characteristics. These include two marine sections of Meghalaya and Zanskar and one continental section of Nagpur. The Um Sohryngkew river section of Meghalaya shows a high iridium, osmium, iron, cobalt, nickel and chromium concentration in a 1.5 cm thick limonitic layer about 30 cm below the planktonic Cretaceous-Palaeocene boundary identified by the characteristic fossils. The Bottaccione and Contessa sections at Gubbio were also analyzed for these elements. The geochemical pattern at the boundary at the Um Sohryngkew river and Gubbio sections are similar but the peak concentrations and the enrichment factors are different. The biological boundary is not as sharp as the geochemical boundary and the extinction appears to be a prolonged process. The Zanskar section shows, in general, similar concentration of the siderophile, lithophile and rare earth elements but no evidence of enrichment of siderophiles has so far been observed. The Takli section is a shallow inter-trappean deposit within the Deccan province, sandwiched between flow 1 and flow 2. The geochemical stratigraphy of the inter-trappeans is presented. The various horizons of ash, clay and marl show concentration of Fe and Co, generally lower than the adjacent basalts. Two horizons of slight enrichment of iridium are found within the ash layers, one near the contact of flow 1 and other near the contact of flow 2, where iridium occurs at 170 and 260 pg/g. These levels are lower by a factor of 30 compared to Ir concentration in the K/T boundary in Meghalaya section. If the enhanced level of some elements in a few horizons of the ash layer are considered as volcanic contribution by some fractionation processes than the only elements for which it occurs are REE, Ir and possibly Cr.

Investigation of severe water problem in urban areas of a developing country: the case of Dhaka, Bangladesh.

PubMed

Nahar, Mst Shamsun; Zhang, Jing; Ueda, Akira; Yoshihisa, Fujishiro

2014-12-01

The present study evaluated water supply geochemistry in Dhaka City, Bangladesh, to provide detailed trace level (subppb) water quality data that include major ions, low dissolved oxygen (DO) and toxic trace metals for sustainable development. Dhaka Groundwater, which almost uniformly meets the World Health Organization guideline, has become the preferred source. Due to groundwater depletion and an ever-increasing need to meet water demands by city residents, Dhaka water supply and sewerage authority has initiated the treatment of river water, despite the fact that very little is known about the geochemical structure, and trace metal content in the Dhaka water supply. Major ion composition of water samples was determined, and the results used to generate Stiff diagrams. The diagrams served to visually compare water from different sources based on units of mass/volume. Hydrochemical facies analysis showed supply ground and surface waters are comprised predominately of Ca-Na-Mg-HCO3 and Ca-Na-Mg-HCO3-Cl types. Spatial distribution of ions, and Na/Cl and Na/SiO2 molar ratio indicated that silicate weathering is the dominant geochemical process. Chemical data revealed that toxic Cr metal mobilization is associated with chemical hazards from the leather industry. The vulnerability of deep wells to contamination by As is governed by the geometry of induced groundwater flow paths and the geochemical conditions encountered between the shallow and deep regions of the aquifer. Quantifying total arsenic (As) and As from interlocking geochemical cycles (Fe, Mn) may assist in interpreting As dynamics in Dhaka well water. The surface source water was hypoxic to anoxic low DO associated with very high concentrations of biological oxygen demands, and electrical conductivity compared to industrial and non-industrial urban processes and standard activity guidelines. The results of this study should be applied to future research focused on the potential to improve water quality in urban and surrounding areas.

Alteration geochemistry of the volcanic-hosted Dedeninyurdu, Yergen and Fındıklıyar Cu-Fe mineralization, Northern part of Gökçedoǧan Village, Çorum-Kargi Region, Turkey: Implications for the rare earth elements geochemical characteristics

NASA Astrophysics Data System (ADS)

Ozturk, Sercan; Gumus, Lokman; Abdelnasser, Amr; Yalçin, Cihan; Kumral, Mustafa; Hanilçi, Nurullah

2016-04-01

This study deals with the rare earth element (REE) geochemical behavior the alteration zonesassociated with the volcanic-hosted Cu-Femineralization at the northern part of Gökçedoǧan village, Çorum-Kargi region (N Turkey) which are Dedeninyurdu, Yergen and Fındıklıyar mineralization. The study areacomprises Bekirli Formation, Saraycık Formation, Beşpınar Formation, and Ilgaz Formation. Saraycık Formation consists ofUpper Cretaceous KargıOphiolites, pelagic limestone, siltstone, chert and spilitic volcanic rocks. Fe-Cu mineralization occurred in the spiliticvolcanic rocks of Saraycık Formation representing the host rockand is related with the silicification and sericitizationalteration zones. Dedeninyurdu and Yergen mineralization zone directed nearly N75-80oEis following structural a line but Fındıklıyar mineralization zone has nearly NW direction. The ore mineralogy in these zonesinclude pyrite, chalcopyrite, covellite, hematite with malachite, goethite and a limonite as a result of oxidation. The geochemical characteristics of REE of the least altered spiliticbasalt show flat light and heavy REE with slight positive Eu- and Sr-anomalies according to their chondrite-, N-type MORB, and primitive mantle-normalized REE patterns. While the REE geochemical features of the altered rocks collected from the different alteration zones show that there are negative Eu and Sr anomalies as a result of leaching during the alteration processes.There are positive and negative correlations between K2O index with LREE and HREE, respectively. This is due to the additions of K and La during the alteration processes referring to the pervasive sericitization alteration is the responsible for the Cu-Fe mineralization at the study area. Keywords: Cu-Fe mineralization, Spilitic volcanic rocks, alteration, Rare earth elements (REE) geochemistry.

Integrating surrogate models into subsurface simulation framework allows computation of complex reactive transport scenarios

NASA Astrophysics Data System (ADS)

De Lucia, Marco; Kempka, Thomas; Jatnieks, Janis; Kühn, Michael

2017-04-01

Reactive transport simulations - where geochemical reactions are coupled with hydrodynamic transport of reactants - are extremely time consuming and suffer from significant numerical issues. Given the high uncertainties inherently associated with the geochemical models, which also constitute the major computational bottleneck, such requirements may seem inappropriate and probably constitute the main limitation for their wide application. A promising way to ease and speed-up such coupled simulations is achievable employing statistical surrogates instead of "full-physics" geochemical models [1]. Data-driven surrogates are reduced models obtained on a set of pre-calculated "full physics" simulations, capturing their principal features while being extremely fast to compute. Model reduction of course comes at price of a precision loss; however, this appears justified in presence of large uncertainties regarding the parametrization of geochemical processes. This contribution illustrates the integration of surrogates into the flexible simulation framework currently being developed by the authors' research group [2]. The high level language of choice for obtaining and dealing with surrogate models is R, which profits from state-of-the-art methods for statistical analysis of large simulations ensembles. A stand-alone advective mass transport module was furthermore developed in order to add such capability to any multiphase finite volume hydrodynamic simulator within the simulation framework. We present 2D and 3D case studies benchmarking the performance of surrogates and "full physics" chemistry in scenarios pertaining the assessment of geological subsurface utilization. [1] Jatnieks, J., De Lucia, M., Dransch, D., Sips, M.: "Data-driven surrogate model approach for improving the performance of reactive transport simulations.", Energy Procedia 97, 2016, p. 447-453. [2] Kempka, T., Nakaten, B., De Lucia, M., Nakaten, N., Otto, C., Pohl, M., Chabab [Tillner], E., Kühn, M.: "Flexible Simulation Framework to Couple Processes in Complex 3D Models for Subsurface Utilization Assessment.", Energy Procedia, 97, 2016 p. 494-501.

Investigation of active faults in the Ionian Sea through seismological, geochemical and bathymetric data: the SEISMOFAULTS project

NASA Astrophysics Data System (ADS)

Sgroi, T.; Beranzoli, L.; Caruso, C.; Corbo, A.; Costanza, A.; De Caro, M.; D'Anna, G.; Doglioni, C.; Embriaco, D.; Frugoni, F.; Italiano, F.; Lazzaro, G.; Monna, S.; Montuori, C.; Nigrelli, A.; Passafiume, G.; Billi, A.; Cuffaro, M.; Albano, M.; Bosman, A.; Gasperini, L.; Ligi, M.; Martorelli, E.; Petracchini, L.; Polonia, A.; Scrocca, D.; Serracino, M.; Bigi, S.; Conti, A.; Proietti, G.; Ruggiero, L.; Tartarello, M. C.

2017-12-01

In a past and recent time, the Western Ionian Sea and surrounding regions of south Calabria and eastern Sicily (southern Italy) have been the site of destructive earthquakes (e.g. 1908, Mw 7.2; 1783, Mw 6.9; 1693, Mw 7.4; 1169, Mw 6.6; 362, Mw 6.6), which caused damage, devastation, and death (more than 80,000 deaths in 1908) and were followed by strong tsunamis. Although such events have been studied by many authors, their sources and generation mechanisms are still heavily debated both for earthquakes and tsunamis. The faults that generated such earthquakes are not yet known as it is unknown whether the associated tsunamis were generated directly by earthquakes or indirectly by seismically-triggered landslides. The lack of an adequate network of seismic stations at the bottom of the Ionian Sea and of a continuous acquisition of geophysical and geochemical parameters on the medium and long term prevents the full understanding of the tectonic, seismological, and geomorphologic phenomena of the Western Ionian Sea. A seismological and geochemical experiment, also accompanied by a detailed bathymetric survey, is now ongoing in the Ionian Sea from May 2017. Eight Ocean Bottom Seismometers and Hydrophones (OBS/H) and two modules for geochemical monitoring (CH4, CO2 and O) were deployed on the sea bottom (www.seismofaults.it). They will record seismological and geochemical signals for a period of about 12 months with the aim to: - determine whether faults are seismically active and can be sources of possible seismic hazard; - observe eventual premonitory elements, such degassing processes from structures such as mud volcanoes, characterizing the seismic movements along faults; - determine whether gravitational movements (e.g. landslides) along the Sicilian-Calabrian margins can be triggered by low magnitude earthquakes, and thus to better evaluate the tsunamigenic potential of the western Ionian region. The analyses of the new seismological and geochemical data, combined with data previously collected in the same area, will contribute to deepen the understanding of the tectonic and volcanic activities of the Ionian Sea, permitting to focus on the geodynamic picture of eastern Sicily offshore area.

Multivariate statistical analysis and hydrogeochemical modelling of seawater-freshwater mixing along selected flow paths: Case of Korba coastal aquifer Tunisia

NASA Astrophysics Data System (ADS)

Slama, Fairouz; Bouhlila, Rachida

2017-11-01

Groundwater sampling and piezometric measurements were carried out along two flow paths (corresponding to two transects) in Korba coastal plain (Northeast of Tunisia). The study aims to identify hydrochemical processes occurring when seawater and freshwater mix. Those processes can be used as indicators of seawater intrusion progression and freshwater flushing into seawater accompanying Submarine Groundwater Discharge (SGD). Seawater fractions in the groundwater were calculated using the chloride concentration. Hierarchical cluster analysis (HCA) was applied to isolate wells potentially affected by seawater. In addition, PHREEQC was used to simulate the theoretical mixing between two end members: seawater and a fresh-brackish groundwater sample. Geochemical conventional diagrams showed that the groundwater chemistry is explained by a mixing process between two end members. Results also revealed the presence of other geochemical processes, correlated to the hydrodynamic flow paths. Direct cation exchange was linked to seawater intrusion, and reverse cation exchange was associated to the freshwater flushing into seawater. The presence of these processes indicated that seawater intrusion was in progress. An excess of Ca, that could not be explained by only cation exchange processes, was observed in both transects. Dedolomitization combined to gypsum leaching is the possible explanation of the groundwater Ca enrichment. Finally, redox processes were also found to contribute to the groundwater composition along flow paths.

SITE EVALUATION OF SOIL AMENDMENT TECHNOLOGIES AT THE CROOKSVILLE/ROSEVILLE POTTERY AREA OF CONCERN - STAR ORGANICS SOIL RESCUE CAPSULE

EPA Science Inventory

This report briefly summarizes Star Organics treatment technology demonstration of a soil amendment process for lead contaminated soil at Roseville, OH. The evaluation included leaching, bioavailability, geotechnical, and geochemical testing methods.

Ecohydrologic process modeling of mountain block groundwater recharge.

PubMed

Magruder, Ian A; Woessner, William W; Running, Steve W

2009-01-01

Regional mountain block recharge (MBR) is a key component of alluvial basin aquifer systems typical of the western United States. Yet neither water scientists nor resource managers have a commonly available and reasonably invoked quantitative method to constrain MBR rates. Recent advances in landscape-scale ecohydrologic process modeling offer the possibility that meteorological data and land surface physical and vegetative conditions can be used to generate estimates of MBR. A water balance was generated for a temperate 24,600-ha mountain watershed, elevation 1565 to 3207 m, using the ecosystem process model Biome-BGC (BioGeochemical Cycles) (Running and Hunt 1993). Input data included remotely sensed landscape information and climate data generated with the Mountain Climate Simulator (MT-CLIM) (Running et al. 1987). Estimated mean annual MBR flux into the crystalline bedrock terrain is 99,000 m(3) /d, or approximately 19% of annual precipitation for the 2003 water year. Controls on MBR predictions include evapotranspiration (radiation limited in wet years and moisture limited in dry years), soil properties, vegetative ecotones (significant at lower elevations), and snowmelt (dominant recharge process). The ecohydrologic model is also used to investigate how climatic and vegetative controls influence recharge dynamics within three elevation zones. The ecohydrologic model proves useful for investigating controls on recharge to mountain blocks as a function of climate and vegetation. Future efforts will need to investigate the uncertainty in the modeled water balance by incorporating an advanced understanding of mountain recharge processes, an ability to simulate those processes at varying scales, and independent approaches to calibrating MBR estimates. Copyright © 2009 The Author(s). Journal compilation © 2009 National Ground Water Association.

Investigating the Influence of Remedial Capping on the Hydrological, Geochemical, and Microbial Processes that Control Subsurface Contaminant Migration at WAG 5 on the Oak Ridge Reservation: Implications toward Long-Term Stewardship

NASA Astrophysics Data System (ADS)

Jardine, P. M.; Mehlhorn, T. L.

2006-05-01

The following research investigated the effectiveness of an aggressive, large scale remedial action that is occurring to subsurface waste trenches containing radioactive and organic waste at the Oak Ridge National Laboratory. The site is being remediated as one of the top cleanup prioritization for the Oak Ridge Accelerated Remediation endeavor. Site landlords, Bechtel Jacobs Co., LLC (BJC) are installing a minimal RCRA cap with the primary objective of controlling the infiltration of storm water into the hundreds of unconfined waste trenches containing radioactive and organic waste. The site now offers a unique scientific opportunity to track the kinetic evolution of post-cap processes influencing contaminant migration and immobilization, because we have many years of pre-cap coupled processes information and knowledge. Since the cap is certain to disrupt the near steady-state contaminant discharge profiles that have existed for many years from the site, we have been quantifying the influence of post-cap hydrological, geochemical, and microbial processes on contaminant discharge as a function of scale and time in an effort to assess local-scale cap influences versus regional scale groundwater flow influences on contaminant discharge. We have been allowed to maintain numerous groundwater monitoring wells at a field site and these have a rich historical data set with regard to hydrology, geochemistry, microbiology, and contaminant flux. Our objectives are to investigate cap induced changes in (1) groundwater and surface hydrology and contaminant flux, (2) geochemistry and contaminant speciation, and (3) microbial community structure and organic contaminant degradation and inorganic contaminant immobilization. Our approach monitors coupled processes during base-flow and during storm events in both the groundwater and surface water discharge from the site and the surrounding watershed. Pre- and post-cap data will than be modeled with a multiprocess, multicomponent, transport model which is linked to pre- and post-cap surface water hydrograph analysis from the site and the surrounding watershed. Our goal is to provide an improved fundamental understanding of the long-term fate and transport of contaminants and an improved ability to predict system response to remedial actions. The experimental and numerical results from this investigation will provide knowledge and information in previously unexplored areas of cap performance with regard to coupled hydrology, geochemistry, microbiology, and contaminant flux in humid regimes. The products will support DOE's mission of long-term stewardship of contaminated environments and be transferable to other site where similar remediation exists or is planned.

Probabilistic, sediment-geochemical parameterisation of the groundwater compartment of the Netherlands for spatially distributed, reactive transport modelling

NASA Astrophysics Data System (ADS)

Janssen, Gijs; Gunnink, Jan; van Vliet, Marielle; Goldberg, Tanya; Griffioen, Jasper

2017-04-01

Pollution of groundwater aquifers with contaminants as nitrate is a common problem. Reactive transport models are useful to predict the fate of such contaminants and to characterise the efficiency of mitigating or preventive measures. Parameterisation of a groundwater transport model on reaction capacity is a necessary step during building the model. Two Dutch, national programs are combined to establish a methodology for building a probabilistic model on reaction capacity of the groundwater compartment at the national scale: the Geological Survey program and the NHI Netherlands Hydrological Instrument program. Reaction capacity is considered as a series of geochemical characteristics that control acid/base condition, redox condition and sorption capacity. Five primary reaction capacity variables are characterised: 1. pyrite, 2. non-pyrite, reactive iron (oxides, siderite and glauconite), 3. clay fraction, 4. organic matter and 5. Ca-carbonate. Important reaction capacity variables that are determined by more than one solid compound are also deduced: 1. potential reduction capacity (PRC) by pyrite and organic matter, 2. cation-exchange capacity (CEC) by organic matter and clay content, 3. carbonate buffering upon pyrite oxidation (CPBO) by carbonate and pyrite. Statistical properties of these variables are established based on c. 16,000 sediment geochemical analyses. The first tens of meters are characterised based on 25 regions using combinations of lithological class and geological formation as strata. Because of both less data and more geochemical uniformity, the deeper subsurface is characterised in a similar way based on 3 regions. The statistical data is used as input in an algoritm that probabilistically calculates the reaction capacity per grid cell. First, the cumulative frequency distribution (cfd) functions are calculated from the statistical data for the geochemical strata. Second, all voxel cells are classified into the geochemical strata. Third, the cfd functions are used to put random reaction capacity variables into the hydrological voxel model. Here, the distribution can be conditioned on two variables. Two important variables are clay content and depth. The first is valid because more dense data is available for clay content than for geochemical variables as pyrite and probabilistic, lithological models are also built at TNO Geological Survey. The second is important to account for locally different depths at which the redox cline between NO3-rich and Fe(II)-rich groundwater occurs within the first tens of meters of the subsurface. An extensive data-set of groundwater quality analyses is used to derive criteria for depth variability of the redox cline. The result is a unique algoritm in order to obtain heterogeneous geochemical reaction capacity models of the entire groundwater compartment of the Netherlands.

Modeling Subsurface Behavior at the System Level: Considerations and a Path Forward

NASA Astrophysics Data System (ADS)

Geesey, G.

2005-12-01

The subsurface is an obscure but essential resource to life on Earth. It is an important region for carbon production and sequestration, a source and reservoir for energy, minerals and metals and potable water. There is a growing need to better understand subsurface possesses that control the exploitation and security of these resources. Our best models often fail to predict these processes at the field scale because of limited understanding of 1) the processes and the controlling parameters, 2) how processes are coupled at the field scale 3) geological heterogeneities that control hydrological, geochemical and microbiological processes at the field scale and 4) lack of data sets to calibrate and validate numerical models. There is a need for experimental data obtained at scales larger than those obtained at the laboratory bench that take into account the influence of hydrodynamics, geochemical reactions including complexation and chelation/adsorption/precipitation/ion exchange/oxidation-reduction/colloid formation and dissolution, and reactions of microbial origin. Furthermore, the coupling of each of these processes and reactions needs to be evaluated experimentally at a scale that produces data that can be used to calibrate numerical models so that they accurately describe field scale system behavior. Establishing the relevant experimental scale for collection of data from coupled processes remains a challenge and will likely be process-dependent and involve iterations of experimentation and data collection at different intermediate scales until the models calibrated with the appropriate date sets achieve an acceptable level of performance. Assuming that the geophysicists will soon develop technologies to define geological heterogeneities over a wide range of scales in the subsurface, geochemists need to continue to develop techniques to remotely measure abiotic reactions, while geomicrobiologists need to continue their development of complementary technologies to remotely measure microbial community parameters that define their key functions at a scale that accurately reflects their role in large scale subsurface system behavior. The practical questions that geomicrobiologist must answer in the short term are: 1) What is known about the activities of the dominant microbial populations or those of their closest relatives? 2) Which of these activities is likely to dominate under in situ conditions? In the process of answering these questions, researchers will obtain answers to questions of a more fundamental nature such as 1) How deep does "active" life extend below the surface of the seafloor and terrestrial subsurface? 2) How are electrons exchanged between microbial cells and solid phase minerals? 3) What is the metabolic state and mechanism of survival of "inactive" life forms in the subsurface? 4) What can genomes of life forms trapped in geological material tell us about evolution of life that current methods cannot? The subsurface environment represents a challenging environment to understand and model. As the need to understand subsurface processes increases and the technologies to characterize them become available, modeling subsurface behavior will approach the level of sophistication of models used today to predict behavior of other large scale systems such as the oceans.

Hydrogeochemical assessment of arsenic in groundwater and its policy implication: a case study in Terai Basin, Nepal

NASA Astrophysics Data System (ADS)

Gurung, J. K.; Upreti, B. N.; Kansakar, D. R.

2007-12-01

Arsenic contamination at levels above the WHO guideline (10 ìg/l) in groundwater is a worldwide problem due to its detrimental effects on health and now known to be a problem also in the Terai Basin of Nepal, posing a serious threat to more than 10 million people. The distribution of arsenic in the basin, however, is patchy. The study emphasizes on the three different types of research into an interdisciplinary package that can be immediately useful to government agencies in Nepal trying to deal with groundwater contamination. They are: hydrogeological assessment of water sources and flow, geochemical analysis of groundwater, and assessment of practical public policy. Basic geochemical analysis gives the abundance and distribution of arsenic along with other physico-chemical parameters of groundwater, whereas, the hydrogeological assessment as an integral part of this study that assist in determining process of mobilization or attenuation of arsenic. Arsenic levels and other key parameters mainly pH, electrical conductivity, chemical oxygen demand, iron, and biological parameter as E-coli were observed at the various locations with different transmissivity values. The study suggests that the flushing rate of an aquifer plays an important role in arsenic content. High flushing rates of an aquifer lead to low levels of arsenic, however the mechanism of this process is still under study. Transmissivity the property of an aquifer that measures the rate at which ground water moves horizontally through a unit is the main factor for controlling flushing. Concentration maps overlaying the base transmissivity map reveals relation of groundwater movement and arsenic concentration. Understanding the relationship between groundwater movement and arsenic content helps planners protect uncontaminated aquifers from future contamination. Also assessment of public policy related to groundwater has identified important changes needed in the existing policy.

The chemical evolution of a travertine-depositing stream: Geochemical processes and mass transfer reactions

USGS Publications Warehouse

Lorah, Michelle M.; Herman, Janet S.

1988-01-01

This field study focuses on quantitatively defining the chemical changes occurring in Falling Spring Creek, a travertine-depositing stream located in Alleghany County, Virginia. The processes of CO2outgassing and calcite precipitation or dissolution control the chemical evolution of the stream. The observed chemical composition of the water was used with the computerized geochemical model WATEQF to calculate aqueous speciation, saturation indices, and CO2 partial pressure values. Mass balance calculations were performed to obtain mass transfers of CO2 and calcite. Reaction times, estimated from stream discharge, were used with the mass transfer results to calculate rates of CO2, outgassing and calcite precipitation between consecutive sampling points. The stream, which is fed by a carbonate spring, is supersaturated with respect to CO2 along the entire 5.2-km flow path. Outgassing of CO2 drives the solution to high degrees of supersaturation with respect to calcite. Metabolic uptake of CO2 by photosynthetic plants is insignificant, because the high supply rate of dissolved carbon dioxide and the extreme agitation of the stream at waterfalls and rapids causes a much greater amount of inorganic CO2 outgassing to occur. Calcite precipitation is kinetically inhibited until near the crest of a 20-m vertical waterfall. Calcite precipitation rates then reach a maximum at the waterfall where greater water turbulence allows the most rapid escape of CO2. Physical evidence for calcite precipitation exists in the travertine deposits which are first observed immediately above the waterfall and extend for at least 1.0 km below the falls. Net calcite precipitation occurs at all times of the year but is greatest during low-flow conditions in the summer and early fall.

Symposium on 'Geographical and geological influences on nutrition': Factors controlling the distribution of selenium in the environment and their impact on health and nutrition.

PubMed

Johnson, Christopher C; Fordyce, Fiona M; Rayman, Margaret P

2010-02-01

Se is essential to human and animal health but can be toxic in excess. An interest in its geochemistry has developed alongside a greater understanding of its function in a number of health conditions. Geology exerts a strong control on the Se status of the surface environment; low-Se rock-types (0.05-0.09 mg Se/kg) make up the majority of rocks occurring at the Earth's surface, which in turn account for the generally low levels of Se in most soils. However, there are exceptions such as associations with sulfide mineralisation and in some types of sedimentary rocks (e.g. black shales) in which contents of Se can be much higher. Baseline geochemical data now enable a comparison to be made between environmental and human Se status, although a direct link is only likely to be seen if the population is dependent on the local environment for sustenance. This situation is demonstrated with an example from the work of the British Geological Survey in the Se-deficiency belt of China. The recent fall in the daily dietary Se intake in the UK is discussed in the context of human Se status and declining use of North American wheat in bread making. Generally, US wheat has ten times more Se than UK wheat, attributed to the fact that soils from the wheat-growing belt of America are more enriched in Se to a similar order of magnitude. In agriculture effective biofortification of crops with Se-rich fertilisers must be demonstrably safe to the environment and monitored appropriately and baseline geochemical data will enable this process to be done with confidence.

Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

USGS Publications Warehouse

Wong, C.I.; Mahler, B.J.; Musgrove, M.; Banner, J.L.

2012-01-01

Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

Critical shear stress measurement of cohesive soils in streams: identifying device-dependent variability using an in-situ jet test device and conduit flume

NASA Astrophysics Data System (ADS)

Mahalder, B.; Schwartz, J. S.; Palomino, A.; Papanicolaou, T.

2016-12-01

Cohesive soil erodibility and threshold shear stress for stream bed and bank are dependent on both soil physical and geochemical properties in association with the channel vegetative conditions. These properties can be spatially variable therefore making critical shear stress measurement in cohesive soil challenging and leads to a need for a more comprehensive understanding of the erosional processes in streams. Several in-situ and flume-type test devices for estimating critical shear stress have been introduced by different researchers; however reported shear stress estimates per device vary widely in orders of magnitude. Advantages and disadvantages exist between these devices. Development of in-situ test devices leave the bed and/or bank material relatively undisturbed and can capture the variable nature of field soil conditions. However, laboratory flumes provide a means to control environmental conditions that can be quantify and tested. This study was conducted to observe differences in critical shear stress using jet tester and a well-controlled conduit flume. Soil samples were collected from the jet test locations and tested in a pressurized flume following standard operational procedure to calculate the critical shear stress. The results were compared using statistical data analysis (mean-separation ANOVA procedure) to identify possible differences. In addition to the device comparison, the mini jet device was used to measure critical shear stress across geologically diverse regions of Tennessee, USA. Statistical correlation between critical shear stress and the soil physical, and geochemical properties were completed identifying that geological origin plays a significant role in critical shear stress prediction for cohesive soils. Finally, the critical shear stress prediction equations using the jet test data were examined with possible suggestions to modify based on the flume test results.

Leveling data in geochemical mapping: scope of application, pros and cons of existing methods

NASA Astrophysics Data System (ADS)

Pereira, Benoît; Vandeuren, Aubry; Sonnet, Philippe

2017-04-01

Geochemical mapping successfully met a range of needs from mineral exploration to environmental management. In Europe and around the world numerous geochemical datasets already exist. These datasets may originate from geochemical mapping projects or from the collection of sample analyses requested by environmental protection regulatory bodies. Combining datasets can be highly beneficial for establishing geochemical maps with increased resolution and/or coverage area. However this practice requires assessing the equivalence between datasets and, if needed, applying data leveling to remove possible biases between datasets. In the literature, several procedures for assessing dataset equivalence and leveling data are proposed. Daneshfar & Cameron (1998) proposed a method for the leveling of two adjacent datasets while Pereira et al. (2016) proposed two methods for the leveling of datasets that contain records located within the same geographical area. Each discussed method requires its own set of assumptions (underlying populations of data, spatial distribution of data, etc.). Here we propose to discuss the scope of application, pros, cons and practical recommendations for each method. This work is illustrated with several case studies in Wallonia (Southern Belgium) and in Europe involving trace element geochemical datasets. References: Daneshfar, B. & Cameron, E. (1998), Leveling geochemical data between map sheets, Journal of Geochemical Exploration 63(3), 189-201. Pereira, B.; Vandeuren, A.; Govaerts, B. B. & Sonnet, P. (2016), Assessing dataset equivalence and leveling data in geochemical mapping, Journal of Geochemical Exploration 168, 36-48.

Reactive transport modeling in fractured rock: A state-of-the-science review

NASA Astrophysics Data System (ADS)

MacQuarrie, Kerry T. B.; Mayer, K. Ulrich

2005-10-01

The field of reactive transport modeling has expanded significantly in the past two decades and has assisted in resolving many issues in Earth Sciences. Numerical models allow for detailed examination of coupled transport and reactions, or more general investigation of controlling processes over geologic time scales. Reactive transport models serve to provide guidance in field data collection and, in particular, enable researchers to link modeling and hydrogeochemical studies. In this state-of-science review, the key objectives were to examine the applicability of reactive transport codes for exploring issues of redox stability to depths of several hundreds of meters in sparsely fractured crystalline rock, with a focus on the Canadian Shield setting. A conceptual model of oxygen ingress and redox buffering, within a Shield environment at time and space scales relevant to nuclear waste repository performance, is developed through a review of previous research. This conceptual model describes geochemical and biological processes and mechanisms materially important to understanding redox buffering capacity and radionuclide mobility in the far-field. Consistent with this model, reactive transport codes should ideally be capable of simulating the effects of changing recharge water compositions as a result of long-term climate change, and fracture-matrix interactions that may govern water-rock interaction. Other aspects influencing the suitability of reactive transport codes include the treatment of various reaction and transport time scales, the ability to apply equilibrium or kinetic formulations simultaneously, the need to capture feedback between water-rock interactions and porosity-permeability changes, and the representation of fractured crystalline rock environments as discrete fracture or dual continuum media. A review of modern multicomponent reactive transport codes indicates a relatively high-level of maturity. Within the Yucca Mountain nuclear waste disposal program, reactive transport codes of varying complexity have been applied to investigate the migration of radionuclides and the geochemical evolution of host rock around the planned disposal facility. Through appropriate near- and far-field application of dual continuum codes, this example demonstrates how reactive transport models have been applied to assist in constraining historic water infiltration rates, interpreting the sealing of flow paths due to mineral precipitation, and investigating post-closure geochemical monitoring strategies. Natural analogue modeling studies, although few in number, are also of key importance as they allow the comparison of model results with hydrogeochemical and paleohydrogeological data over geologic time scales.

Diazotrophy in the Deep: An analysis of the distribution, magnitude, geochemical controls, and biological mediators of deep-sea benthic nitrogen fixation

NASA Astrophysics Data System (ADS)

Dekas, Anne Elizabeth

Biological nitrogen fixation (the conversion of N2 to NH3) is a critical process in the oceans, counteracting the production of N2 gas by dissimilatory bacterial metabolisms and providing a source of bioavailable nitrogen to many nitrogen-limited ecosystems. One currently poorly studied and potentially underappreciated habitat for diazotrophic organisms is the sediments of the deep-sea. Although nitrogen fixation was once thought to be negligible in non-photosynthetically driven benthic ecosystems, the present study demonstrates the occurrence and expression of a diversity of nifH genes (those necessary for nitrogen fixation), as well as a widespread ability to fix nitrogen at high rates in these locations. The following research explores the distribution, magnitude, geochemical controls, and biological mediators of nitrogen fixation at several deep-sea sediment habitats, including active methane seeps (Mound 12, Costa Rica; Eel River Basin, CA, USA; Hydrate Ridge, OR, USA; and Monterey Canyon, CA, USA), whale-fall sites (Monterey Canyon, CA), and background deep-sea sediment (off-site Mound 12 Costa Rica, off-site Hydrate Ridge, OR, USA; and Monterey Canyon, CA, USA). The first of the five chapters describes the FISH-NanoSIMS method, which we optimized for the analysis of closely associated microbial symbionts in marine sediments. The second describes an investigation of methane seep sediment from the Eel River Basin, where we recovered nifH sequences from extracted DNA, and used FISH-NanoSIMS to identify methanotrophic archaea (ANME-2) as diazotrophs, when associated with functional sulfate-reducing bacterial symbionts. The third and fourth chapters focus on the distribution and diversity of active diazotrophs (respectively) in methane seep sediment from Mound 12, Costa Rica, using a combination of 15N-labeling experiments, FISH-NanoSIMS, and RNA and DNA analysis. The fifth chapter expands the scope of the investigation by targeting diverse samples from methane seep, whale-fall, and background sediment collected along the Eastern Pacific Margin, and comparing the rates of nitrogen fixation observed to geochemical measurements collected in parallel. Together, these analyses represent the most extensive investigation of deep-sea nitrogen fixation to date, and work towards understanding the contribution of benthic nitrogen fixation to global marine nitrogen cycling.

Sedimentary Carbon, Sulfur, and Iron Relationships in Modern and Ancient Diagenetic Environments of the Eel River Basin (U.S.A.)

USGS Publications Warehouse

Sommerfield, C.K.; Aller, R.C.; Nittrouer, C.A.

2001-01-01

Depositional and diagenetic controls on the distributions of carbon, sulfur, and iron (C-S-Fe) in modern sediments and upper Pleistocene mudrocks of the Eel River Basin (ERB), northern California continental margin, were investigated using a combination of geochemical, radioisotopic, and sedimentological methods. A mass balance based on down-core profiles of porewater and solid-phase constituents and diagenetic modeling suggests that only 12-30% of the pyrite-S produced via SO4-2 reduction during burial is retained in modern shelf and upper slope deposits of the ERB. Bioturbational reoxidation of initially reduced S is inferred to be the major control on S preservation, on the basis of an observed inverse relationship between pyrite-S retention and biological mixing intensity, estimated from profiles of excess 234Th. Importantly, these findings argue that massive depositional episodes on the shelf following floods of the Eel River have a negligible long-term impact on bioturbating macrofauna and the potential to affect geochemical properties of the sediments. Down-core profiles of reactive Fe3+and Py-Fe(II) for the modern deposits suggest that highly reactive Fe phases are sulfidized well within ∼ 500-2000 years of burial, thereby limiting later pyritization, which could occur through sulfidation of less reactive phases. This result explains the low (≤ 0.4) degree of pyritization (DOP) values exhibited by both modern and ancient deposits of the ERB and lends support to the notion that pyritization in aerobic continental-margin sediments is largely associated with highly reactive detrital Fe oxides. Comparable mean C/S weight ratios for modern sediments (5.4 ± 3.3, 1σ) and mudrocks (6.9 ± 4.5) of the ERB suggest that the upper Pleistocene strata reflect a geochemical environment analogous to that of the modern margin. Specifically, the C-S-Fe signatures shared by the modern and ancient deposits are a consequence of similar detrital Fe mineralogies, initial organic-matter content (Corg ≤ 1%) and composition (C/N = 13 to 17, δ13Corg = -22 to -25‰), burial rate, and importantly, bioturbation intensity. The findings of this study have important implications for the use of C-S-Fe signatures as indicators of diagenetic processes in dynamic, continental-margin environments.

Alaska Geochemical Database - Mineral Exploration Tool for the 21st Century - PDF of presentation

USGS Publications Warehouse

Granitto, Matthew; Schmidt, Jeanine M.; Labay, Keith A.; Shew, Nora B.; Gamble, Bruce M.

2012-01-01

The U.S. Geological Survey has created a geochemical database of geologic material samples collected in Alaska. This database is readily accessible to anyone with access to the Internet. Designed as a tool for mineral or environmental assessment, land management, or mineral exploration, the initial version of the Alaska Geochemical Database - U.S. Geological Survey Data Series 637 - contains geochemical, geologic, and geospatial data for 264,158 samples collected from 1962-2009: 108,909 rock samples; 92,701 sediment samples; 48,209 heavy-mineral-concentrate samples; 6,869 soil samples; and 7,470 mineral samples. In addition, the Alaska Geochemical Database contains mineralogic data for 18,138 nonmagnetic-fraction heavy mineral concentrates, making it the first U.S. Geological Survey database of this scope that contains both geochemical and mineralogic data. Examples from the Alaska Range will illustrate potential uses of the Alaska Geochemical Database in mineral exploration. Data from the Alaska Geochemical Database have been extensively checked for accuracy of sample media description, sample site location, and analytical method using U.S. Geological Survey sample-submittal archives and U.S. Geological Survey publications (plus field notebooks and sample site compilation base maps from the Alaska Technical Data Unit in Anchorage, Alaska). The database is also the repository for nearly all previously released U.S. Geological Survey Alaska geochemical datasets. Although the Alaska Geochemical Database is a fully relational database in Microsoft® Access 2003 and 2010 formats, these same data are also provided as a series of spreadsheet files in Microsoft® Excel 2003 and 2010 formats, and as ASCII text files. A DVD version of the Alaska Geochemical Database was released in October 2011, as U.S. Geological Survey Data Series 637, and data downloads are available at http://pubs.usgs.gov/ds/637/. Also, all Alaska Geochemical Database data have been incorporated into the interactive U.S. Geological Survey Mineral Resource Data web portal, available at http://mrdata.usgs.gov/.

Geochemical Proxies for Enhanced Process Control of Underground Coal Gasification

NASA Astrophysics Data System (ADS)

Kronimus, A.; Koenen, M.; David, P.; Veld, H.; van Dijk, A.; van Bergen, F.

2009-04-01

Underground coal gasification (UCG) represents a strategy targeting at syngas production for fuel or power generation from in-situ coal seams. It is a promising technique for exploiting coal deposits as an energy source at locations not allowing conventional mining under economic conditions. Although the underlying concept has already been suggested in 1868 and has been later on implemented in a number of field trials and even at a commercial scale, UCG is still facing technological barriers, impeding its widespread application. Field UCG operations rely on injection wells enabling the ignition of the target seam and the supply with oxidants (air, O2) inducing combustion (oxidative conditions). The combustion process delivers the enthalpy required for endothermic hydrogen production under reduction prone conditions in some distance to the injection point. The produced hydrogen - usually accompanied by organic and inorganic carbon species, e.g. CH4, CO, and CO2 - can then be retrieved through a production well. In contrast to gasification of mined coal in furnaces, it is difficult to measure the combustion temperature directly during UCG operations. It is already known that geochemical parameters such as the relative production gas composition as well as its stable isotope signature are related to the combustion temperature and, consequently, can be used as temperature proxies. However, so far the general applicability of such relations has not been proven. In order to get corresponding insights with respect to coals of significantly different rank and origin, four powdered coal samples covering maturities ranging from Ro= 0.43% (lignite) to Ro= 3.39% (anthracite) have been gasified in laboratory experiments. The combustion temperature has been varied between 350 and 900 ˚ C, respectively. During gasification, the generated gas has been captured in a cryo-trap, dried and the carbon containing gas components have been catalytically oxidized to CO2. Thereafter, the generated CO2 has been analyzed with respect to its stable carbon isotope composition by mass spectrometry. All samples exhibited a similar trend: The ^13C signatures of initially produced CO2 revealed to be relatively light and linearly increasing with temperature until approaching the bulk stable carbon isotope composition of the coal at a certain temperature, where the isotope signature kept virtually constant during further temperature increase. The temperature introducing the range of constant isotope compositions of the produced gas increased with coal rank. Additionally, all coal samples were treated by Rock Eval pyrolysis up to 550 ˚ C in order to investigate temperature dependent generation of CO and CO2. The results exhibited a linear decrease of the CO2/CO ratio at increasing temperature. Both experimental approaches demonstrated dependencies between the qualitative and the isotope composition of the generated syngas on the one hand and the applied combustion temperature on the other hand and, consequently, the principal applicability of the considered geochemical parameters as temperature proxies for coals of significantly different rank and origin. Although the investigated samples revealed similar trends, the absolute characteristics of the correlation functions (e.g. linear gradients) between geochemical parameters and combustion temperatures differed on an individual sample base, implying a significant additional dependence of the considered geochemical parameters on the coal composition. As a consequence, corresponding experimental approaches are currently continued and refined by involving multi component compound specific isotope analysis, high temperature Rock Eval pyrolysis as well as an enforced consideration of initial coal and oxidant compositions.

Processes controlling trace element geochemistry of Arabian Sea sediments during the last 25,000 years

NASA Astrophysics Data System (ADS)

Sirocko, Frank; Garbe-Schönberg, Dieter; Devey, Colin

2000-11-01

Thirty seven deep-sea sediment cores from the Arabian Sea were studied geochemically (49 major and trace elements) for four time slices during the Holocene and the last glacial, and in one high sedimentation rate core (century scale resolution) to detect tracers of past variations in the intensity of the atmospheric monsoon circulation and its hydrographic expression in the ocean surface. This geochemical multi-tracer approach, coupled with additional information on the grain size composition of the clastic fraction, the bulk carbonate and biogenic opal contents makes it possible to characterize the sedimentological regime in detail. Sediments characterized by a specific elemental composition (enrichment) originated from the following sources: river suspensions from the Tapti and Narbada, draining the Indian Deccan traps (Ti, Sr); Indus sediments and dust from Rajasthan and Pakistan (Rb, Cs); dust from Iran and the Persian Gulf (Al, Cr); dust from central Arabia (Mg); dust from East Africa and the Red Sea (Zr/Hf, Ti/Al). C org, Cd, Zn, Ba, Pb, U, and the HREE are associated with the intensity of upwelling in the western Arabian Sea, but only those patterns that are consistently reproduced by all of these elements can be directly linked with the intensity of the southwest monsoon. Relying on information from a single element can be misleading, as each element is affected by various other processes than upwelling intensity and nutrient content of surface water alone. The application of the geochemical multi-tracer approach indicates that the intensity of the southwest monsoon was low during the LGM, declined to a minimum from 15,000-13,000 14C year BP, intensified slightly at the end of this interval, was almost stable during the Bölling, Alleröd and the Younger Dryas, but then intensified in two abrupt successions at the end of the Younger Dryas (9900 14C year BP) and especially in a second event during the early Holocene (8800 14C year BP). Dust discharge by northwesterly winds from Arabia exhibited a similar evolution, but followed an opposite course: high during the LGM with two primary sources—the central Arabian desert and the dry Persian Gulf region. Dust discharge from both regions reached a pronounced maximum at 15,000-13,000 14C year. At the end of this interval, however, the dust plumes from the Persian Gulf area ceased dramatically, whereas dust discharge from central Arabia decreased only slightly. Dust discharge from East Africa and the Red Sea increased synchronously with the two major events of southwest monsoon intensification as recorded in the nutrient content of surface waters. In addition to the tracers of past dust flux and surface water nutrient content, the geochemical multi-tracer approach provides information on the history of deep sea ventilation (Mo, S), which was much lower during the last glacial maximum than during the Holocene. The multi-tracer approach—i.e. a few sedimentological parameters plus a set of geochemical tracers widely available from various multi-element analysis techniques—is a highly applicable technique for studying the complex sedimentation patterns of an ocean basin, and, specifically in the case of the Arabian Sea, can even reveal the seasonal structure of climate change.

Trace elements assessment in agricultural and desert soils of Aswan area, south Egypt: Geochemical characteristics and environmental impacts

NASA Astrophysics Data System (ADS)

Darwish, Mohamed Abdallah Gad; Pöllmann, Hebert

2015-12-01

Determination of chemical elements, Al, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, P, Pb, Sc, Sr, Ti, Y, and Zn have been performed in agricultural and desert soils and alfalfa (Medicago sativa) at Aswan area. Consequently, the pollution indices, univariate and multivariate statistical methods have been applied, in order to assess the geochemical characteristics of these elements and their impact on soil environmental quality and plant, and to reach for their potential input sources. The investigation revealed that the mean and range values of all element concentrations in agricultural soil are higher than those in desert soil. Furthermore, the agricultural soil displayed various degrees of enrichment and pollution of Cd, Zn, Mo, Co, P, Ti, Pb. The geochemical pattern of integrated pollution indices gave a clear image of extreme and strong pollution in the agricultural soil stations, their poor quality with high risk to human health and considered as a tocsin for an alert. In contrast, the desert soil is the good environmental quality and safe for plant, animal and human health. Alfalfa is tolerant plant and considered as a biomarker for P and Mo in polluted agricultural soil. Four geochemical associations of analyzing elements in agricultural soil and three ones in desert soil have been generated, and their enhancements were essentially caused by various anthropogenic activities and geogenic sources. The investigation also revealed that the broad extended desert soil is fruitful and promising as cultivable lands for agricultural processes in the futures.

A bioenergetics-kinetics coupled modeling study on subsurface microbial metabolism in a field biostimulation experiment

NASA Astrophysics Data System (ADS)

Jin, Q.; Zheng, Z.; Zhu, C.

2006-12-01

Microorganisms in nature conserve energy by catalyzing various geochemical reactions. To build a quantitative relationship between geochemical conditions and metabolic rates, we propose a bioenergetics-kinetics coupled modeling approach. This approach describes microbial community as a metabolic network, i.e., fermenting microbes degrade organic substrates while aerobic respirer, nitrate reducer, metal reducer, sulfate reducer, and methanogen consume the fermentation products. It quantifies the control of substrate availability and biological energy conservation on the metabolic rates using thermodynamically consistent rate laws. We applied this simulation approach to study the progress of microbial metabolism during a field biostimulation experiment conducted in Oak Ridge, Tennessee. In the experiment, ethanol was injected into a monitoring well and groundwater was sampled to monitor changes in the chemistry. With time, concentrations of ethanol and SO42- decreased while those of NH4+, Fe2+, and Mn2+ increased. The simulation results fitted well to the observation, indicating simultaneous ethanol degradation and terminal electron accepting processes. The rates of aerobic respiration and denitrification were mainly controlled by substrate concentrations while those of ethanol degradation, sulfate reduction, and methanogenesis were controlled dominantly by the energy availability. The simulation results suggested two different microbial growth statuses in the subsurface. For the functional groups with significant growth, variations with time in substrate concentrations demonstrated a typical S curve. For the groups without significant growth, initial decreases in substrate concentrations were linear with time. Injecting substrates followed by monitoring environmental chemistry therefore provides a convenient approach to characterize microbial growth in the subsurface where methods for direct observation are currently unavailable. This research was funded by the NABIR program, DOE, under grant No. DE-FG02-04ER63740 to CZ. We thank J. Istok, David Watson, and Philip Jardine for their help. The views and opinions of authors expressed herein do not necessarily state or reflect those of the DOE.

Remote Sensing and Problems of the Hydrosphere

NASA Technical Reports Server (NTRS)

Goldberg, E. D. (Editor)

1979-01-01

A discussion of freshwater and marine systems is presented including areas of the classification of lakes, identification and quantification of major functional groups of phytoplankton, sources and sinks of biochemical factors, and temporal and regional variability of surface features. Atmospheric processes linked to hydrospheric process through the transfer of matter via aerosols and gases are discussed. Particle fluxes to the aquatic environment and global geochemical problems are examined.

To the bottom of carbon processing at the seafloor: towards integration of geological, geochemical and ecological concepts (Vladimir Ivanovich Vernadsky Medal Lecture)

NASA Astrophysics Data System (ADS)

Middelburg, Jack J.

2017-04-01

Marine sediments are a habitat for organisms, govern the partitioning of material being buried or recycled, and act as filter for the paleorecord. Processes in the surface sediment layer determine whether carbon is recycled within the biosphere (short-term cycle) or transferred to the geosphere (long-term cycle) and as such it function as key interface in the System Earth. Scientists from various disciplines with their own interests, paradigms and techniques have studied this pivotal role of the seafloor in processing material deposited. Marine geologists and paleoceanographers study sediments with the primary aim to extract information on past environmental conditions using down-core measurements of substances delivered to the seafloor and that have survived the processing at the seafloor. Biogeochemists quantify the fate of material delivered, in particular how much of the material is eventually buried and when and in what form is the remaining recycled to the water column, because recycling of key nutrients (e.g. N, P, Si, Fe) sustain primary production. Organic geochemists investigate how organic matter delivered to the seafloor is degraded, transformed or preserved using changes in the composition at the molecular level. Ecologists focus on the organisms, i.e. the actors consuming, producing and transporting the material deposited. Although these disciplines often study the same material, e.g. organic matter delivered to the seafloor, they focus on different aspect ignoring key concepts, findings and approaches from other disciplines. For example, ecologists and biogeochemist studying carbon flow at the seafloor normally ignore detailed molecular information available from organic geochemistry. Bioturbation, particle transport and mixing at the seafloor, is often ignored by paleocanographers, and biogeochemists have developed advanced transport-reaction models in which the actors, the animals, mix the particles but do so without consuming organic matter, their food. Here I present existing views on organic carbon processing at the seafloor, discuss where they agree and disagree and aim to arrive at an integrated view of carbon processing at the seafloor that is consistent with recent views within the organic geochemical, sediment geochemical, ecological and microbiological communities.

Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

DOE PAGES

Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.; ...

2016-05-11

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a 6-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species inmore » reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Thus, reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.« less

Reactive Transport of Petroleum Hydrocarbon Constituents in a Shallow Aquifer: Modeling Geochemical Interactions Between Organic and Inorganic Species

NASA Astrophysics Data System (ADS)

McNab, W. W.; Narasimhan, T. N.

1995-08-01

Dissolved organic contaminants such as petroleum hydrocarbon constituents are often observed to degrade in groundwater environments through biologically mediated transformation reactions into carbon dioxide, methane, or intermediate organic compounds. Such transformations are closely tied to local geochemical conditions. Favorable degradation pathways depend upon local redox conditions through thermodynamic constraints and the availability of appropriate mediating microbial populations. Conversely, the progress of the degradation reactions may affect the chemical composition of groundwater through changes in electron donor/acceptor speciation and pH, possibly inducing mineral precipitation/dissolution reactions. Transport of reactive organic and inorganic aqueous species through open systems may enhance the reaction process by mixing unlike waters and producing a state of general thermodynamic disequilibrium. In this study, field data from an aquifer contaminated by petroleum hydrocarbons have been analyzed using a mathematical model which dynamically couples equilibrium geochemistry of inorganic constituents, kinetically dominated sequential degradation of organic compounds, and advective-dispersive chemical transport. Simulation results indicate that coupled geochemical processes inferred from field data, such as organic biodegradation, iron reduction and dissolution, and methanogenesis, can be successfully modeled using a partial-redox-disequilibrium approach. The results of this study also suggest how the modeling approach can be used to study system sensitivity to various physical and chemical parameters, such as the effect of dispersion on the position of chemical fronts and the impact of alternative buffering mineral phases (e.g., goethite versus amorphous Fe(OH)3) on water chemistry.

Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a 6-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species inmore » reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Thus, reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.« less

Geochemical modeling of subsurface fluid generation in the Gulf of Cadiz

NASA Astrophysics Data System (ADS)

Schmidt, Christopher; Hensen, Christian; Wallmann, Klaus

2016-04-01

During RV METEOR cruise M86/5 in 2012 a number of deep-sea mud volcanoes were discovered at about 4500 m water depth west of the deformation front of the accretionary wedge in the Gulf of Cadiz (NE Atlantic). Fluid flow at these locations is mediated by an active strike-slip fault marking the transcurrent plate boundary between Africa and Eurasia. Geochemical signals of emanating fluids have been interpreted as being a mixture of various deep-sourced processes such as the alteration of oceanic crust, clay-mineral dehydration, and recrystallization of carbonaceous, Upper Jurassic sediments (Hensen et al. 2015). In the current study we present results of a geochemical reactive-transport model that was designed to simulate major fluid-affecting processes, such as the smectite to illite transformation or recrystallization of carbonates in order to provide a proof of concept. Preliminary results show that the model is able to reproduce pore water signatures (e.g. for chloride, strontium, 87Sr/86Sr) in subsurface sediments that are similar to those of MV fluids. Hensen, C., Scholz, F., Nuzzo, M., Valadares, V., Gràcia, E., Terrinha, P., Liebetrau, V., Kaul, N., Silva, S., Martínez-Loriente, S., Bartolome, R., Piñero, E., Magalhães, V.H., Schmidt, M., Weise, S.M., Cunha, M., Hilario, A., Perea, H., Rovelli, L. and Lackschewitz, K. (2015) Strike-slip faults mediate the rise of crustal-derived fluids and mud volcanism in the deep sea. Geology 43, 339-342.

Geochemical Modeling of Reactions and Partitioning of Trace Metals and Radionuclides during Titration of Contaminated Acidic Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Fan; Parker, Jack C.; Luo, Wensui

2008-01-01

Many geochemical reactions that control aqueous metal concentrations are directly affected by solution pH. However, changes in solution pH are strongly buffered by various aqueous phase and solid phase precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior of the soil-solution system is thus critical to predict metal transport under variable pH conditions. This study was undertaken to develop a practical generic geochemical modeling approach to predict aqueous and solid phase concentrations of metals and anions during conditions of acid or base additions. The method of Spalding and Spalding was utilized to model soil buffer capacity and pH-dependent cationmore » exchange capacity by treating aquifer solids as a polyprotic acid. To simulate the dynamic and pH-dependent anion exchange capacity, the aquifer solids were simultaneously treated as a polyprotic base controlled by mineral precipitation/dissolution reactions. An equilibrium reaction model that describes aqueous complexation, precipitation, sorption and soil buffering with pH-dependent ion exchange was developed using HydroGeoChem v5.0 (HGC5). Comparison of model results with experimental titration data of pH, Al, Ca, Mg, Sr, Mn, Ni, Co, and SO{sub 4}{sup 2-} for contaminated sediments indicated close agreement, suggesting that the model could potentially be used to predict the acid-base behavior of the sediment-solution system under variable pH conditions.« less

Late-paleozoic granitoid complexes of the southwest Primorye: geochemistry, age and typification

NASA Astrophysics Data System (ADS)

Veldemar, A. A.; Vovna, G. M.

2017-12-01

The article presents the first data of geochemical studies of the Late Permian granitoids of the Gamov Complex located in the southwestern part of the Voznesenskiy terrane. The purpose of the study was to identify the main geochemical features of the Late Paleozoic granitoids of the southwestern Primorye, which in the future will allow us to draw conclusions about the petrogenesis of these granitoids. Elemental analysis of 20 samples was carried out, conducted statistical and mathematical processing of the data, have been constructed representative diagrams and graphs for this group of rocks. Elemental analysis was performed by atomic emission (ICP-AES) and inductively-coupled-plasma (ICP-MS) mass spectrometry, at the Analytical Center FEGI FEB RAS.

Soil Geochemical Data for the Wyoming Landscape Conservation Initiative Study Area

USGS Publications Warehouse

Smith, David B.; Ellefsen, Karl J.

2010-01-01

In 2008, soil samples were collected at 139 sites throughout the Wyoming Landscape Conservation Initiative study area in southwest Wyoming. These samples, representing a density of 1 site per 440 square kilometers, were collected from a depth of 0-5 cm and analyzed for a suite of more than 40 major and trace elements following a near-total multi-acid extraction. In addition, soil pH, electrical conductivity, total nitrogen, total and organic carbon, and sodium adsorption ratio were determined. The resulting data set provides a baseline for detecting changes in soil composition that might result from natural processes or anthropogenic activities. This report describes the sampling and analytical protocols used, and makes available all the soil geochemical data generated in the study.

Geochemical bioenergetics during low-temperature serpentinization: An example from the Samail ophiolite, Sultanate of Oman

NASA Astrophysics Data System (ADS)

Canovas, Peter A.; Hoehler, Tori; Shock, Everett L.

2017-07-01

Various classes of microbial and biomolecular evidence from global studies in marine and continental settings are used to identify a set of reactions that appear to support microbial metabolism during serpentinization of ultramafic rocks. Geochemical data from serpentinizing ecosystems in the Samail ophiolite of Oman are used to evaluate the extent of disequilibria that can support this set of microbial metabolisms and to provide a ranking of potential metabolic energy sources in hyperalkaline fluids that are direct products of serpentinization. Results are used to construct hypotheses for how microbial metabolism may be supported in the subsurface for two cases: ecosystems hosted in rocks that have already undergone significant serpentinization and those hosted by deeper, active serpentinization processes.

3-D reservoir characterization of the House Creek oil field, Powder River Basin, Wyoming

USGS Publications Warehouse

Higley, Debra K.; Pantea, Michael P.; Slatt, Roger M.

1997-01-01

This CD-ROM is intended to serve a broad audience. An important purpose is to explain geologic and geochemical factors that control petroleum production from the House Creek Field. This information may serve as an analog for other marine-ridge sandstone reservoirs. The 3-D slide and movie images are tied to explanations and 2-D geologic and geochemical images to visualize geologic structures in three dimensions, explain the geologic significance of porosity/permeability distribution across the sandstone bodies, and tie this to petroleum production characteristics in the oil field. Movies, text, images including scanning electron photomicrographs (SEM), thin-section photomicrographs, and data files can be copied from the CD-ROM for use in external mapping, statistical, and other applications.

ITALIAN PEAK AND ITALIAN PEAK MIDDLE ROADLESS AREAS, IDAHO AND MONTANA.

USGS Publications Warehouse

Skipp, Betty; Lambeth, Robert H.

1984-01-01

The Italian Peak and Italian Peak Middle Roadless Areas, in southwestern Montana and east-central Idaho, contain areas of probable mineral-resource potential based on combined geologic, geophysical, and geochemical studies and prospect examination. Small areas along the western, southern, and northeastern boundaries of the roadless areas have probable mineral resource potential for zinc, lead, silver, and uranium. An area of probable resource potential just east of and including a part of the Birch Creek mining district, may contain stratabound and fault-controlled silver and base metals, even though geochemical anomalies are low, and extensive prospecting has not identified any significant mineralization. The roadless areas are a part of the overthrust belt, and oil and gas possibilities must be assessed.

QSAR ANALYSIS OF SORPTION-CORRECTED RATE CONSTANTS FOR REDUCTIVE BIOTRANSFORMATION OF HALOGENATED AROMATICS

EPA Science Inventory

The inherent coupling among geochemical and microbial reactions may have significant effects on the environmental fate of a containinant. For example, sorption processes may decrease the concentration of an organic compound in solution, thereby reducing the biodegradation rate of...

UNDERSTANDING VARIATION IN PARTITION COEFFICIENT KD, VALUES, VOLUME III: AMERICIUM, ARSENIC, CURIUM, IODINE, NEPTUNIUM, RADIUM, AND TECHNETIUM

EPA Science Inventory

This report describes the conceptualization, measurement, and use of the partition (or distribution) coefficient, Kd, parameter, and the geochemical aqueous solution and sorbent properties that are most important in controlling adsorption/retardation behavior of selected contamin...

Petrological and geochemical Highlights in the floating fragments of the October 2011 submarine eruption offshore El Hierro (Canary Islands): Relevance of submarine hydrothermal processes

NASA Astrophysics Data System (ADS)

Rodriguez-Losada, Jose A.; Eff-Darwich, Antonio; Hernandez, Luis E.; Viñas, Ronaldo; Pérez, Nemesio; Hernandez, Pedro; Melián, Gladys; Martinez-Frías, Jesús; Romero-Ruiz, M. Carmen; Coello-Bravo, Juan Jesús

2015-02-01

This paper describes the main physical, petrological and geochemical features of the floating fragments that were emitted in the initial stages of the 2011-2012 submarine eruption off the coast of the Canarian island of El Hierro, located 380 km from the Northwest African Coast. It attempts to assess the potential of radiometric analyses to discern the intriguing origin of the floating fragments and the differences between their constituent parts. In this regard, the material that conforms the core of the fragments contains the largest concentration of uranium (U) ever found in volcanic rocks of the Canary Islands. This enrichment in U is not found in the content of thorium (Th), hence the floating fragments have an unusual U/Th ratio, namely equal to or larger than 3. Although the origin of this material is under discussion, it is proposed that the enrichment in U is the result of hydrothermal processes.

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from homogeneous groundwaters in the Great Artesian Basin, Australia

NASA Astrophysics Data System (ADS)

O'Shea, Bethany; Jankowski, Jerzy

2006-12-01

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO2 input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright

Organic geochemical studies of the transformation of gymnospermous xylem during peatification and coalification to subbituminous coal

USGS Publications Warehouse

Hatcher, P.G.; Lerch, H. E.; Verheyen, Vincent T.

1989-01-01

Organic geochemical investigations of peatified and coalified xylem from gymnosperms have provided useful information on the organic transformational processes collectively known as coalification. The combined use of solid-state 13C nuclear magnetic resonance (NMR) and pyrolysis/gas chromatography/mass spectrometry (py/gc/ms) has allowed us to examine the organic composition of peatified and coalified xylem on both a bulk (average) compositional basis and on a detailed molecular basis. We conclude from our studies that coalification of gymnospermous xylem involves the following processes: 1. (1) early selective removal of cellulosic materials so that lignin, a primary constituent of xylem, is transformed to macromolecular aromatic components in coal; 2. (2) modification of gymnospermous lignin by demethylation to form catechol-like structures, and by condensation reactions to induce a high level of cross-linking at an early stage of coalification; and 3. (3) dehydroxylation during increasing coalification to subbituminous coal, the resultant xylem becomes more phenolic in character as the catechol-like structures decrease. ?? 1989.

Isotope and Chemical Methods in Support of the U.S. Geological Survey Science Strategy, 2003-2008

USGS Publications Warehouse

Rye, R.O.; Johnson, C.A.; Landis, G.P.; Hofstra, A.H.; Emsbo, P.; Stricker, C.A.; Hunt, A.G.; Rusk, B.G.

2008-01-01

Principal functions of the Mineral Resources Program are providing information to decision-makers related to mineral deposits on federal lands and predicting the environmental consequences of the mining or natural weathering of those deposits. Performing these functions requires that predictions be made of the likelihood of undiscovered deposits. The predictions are based on geologic and geoenvironmental models that are constructed for the various types of mineral deposits from detailed descriptions of actual deposits and detailed understanding of the processes that formed them. Over the past three decades the understanding of ore-forming processes has benefitted greatly from the integration of laboratory-based geochemical tools with field observations and other data sources. Under the aegis of the Evolution of Ore Deposits and Technology Transfer Project (EODTTP), a five-year effort that terminated in 2008, the Mineral Resources Program provided state-of-the-art analytical capabilities to support applications of several related geochemical tools.

Anatomy of a fumarolic system inferred from a multiphysics approach.

PubMed

Gresse, Marceau; Vandemeulebrouck, Jean; Byrdina, Svetlana; Chiodini, Giovanni; Roux, Philippe; Rinaldi, Antonio Pio; Wathelet, Marc; Ricci, Tullio; Letort, Jean; Petrillo, Zaccaria; Tuccimei, Paola; Lucchetti, Carlo; Sciarra, Alessandra

2018-05-15

Fumaroles are a common manifestation of volcanic activity that are associated with large emissions of gases into the atmosphere. These gases originate from the magma, and they can provide indirect and unique insights into magmatic processes. Therefore, they are extensively used to monitor and forecast eruptive activity. During their ascent, the magmatic gases interact with the rock and hydrothermal fluids, which modify their geochemical compositions. These interactions can complicate our understanding of the real volcanic dynamics and remain poorly considered. Here, we present the first complete imagery of a fumarolic plumbing system using three-dimensional electrical resistivity tomography and new acoustic noise localization. We delineate a gas reservoir that feeds the fumaroles through distinct channels. Based on this geometry, a thermodynamic model reveals that near-surface mixing between gas and condensed steam explains the distinct geochemical compositions of fumaroles that originate from the same source. Such modeling of fluid interactions will allow for the simulation of dynamic processes of magmatic degassing, which is crucial to the monitoring of volcanic unrest.

Use of an intact core and stable-metal isotopes to examine leaching characteristics of a fluvial tailings deposit

USGS Publications Warehouse

Ranville, James F.; Smith, Kathleen S.; Lamothe, Paul J.; Jackson, Brian P.; Walton-Day, Katherine

2003-01-01

In this paper, we use Cd as an example of the utility of stable-metal isotopes in geochemical studies. In the case of Cd, after the core was partially saturated, the 111Cd spike was released as evidenced by a change in the Cd isotope ratios in the effluent. This release continued during the fully saturated leaching phase, however, the total Cd concentration did not increase. These results suggest that the 111Cd spike was retained inside the core during the unsaturated leaching phase, and only partially released as reducing conditions developed. Results from this core-leaching experiment indicate there is a large reservoir of water-soluble material within the fluvial tailings deposit, which yields elevated metal concentrations and high acidity, and which may degrade adjacent ground- and surface-water quality. Use of stable metal isotopes in this study facilitated the determination of different metal-retention processes, metal-release processes, and metal sources in the fluvial tailings deposit in response to changing geochemical conditions.

Introduction to the special issue on ‘Frontiers in gas geochemistry’

USGS Publications Warehouse

Hilton, David R.; Fischer, Tobias P.; Kulongoski, Justin T.

2013-01-01

The study of the geochemistry of gases pervades the Earth and Environmental Sciences. This is due in no small measure to the well-established thermodynamic properties of gases which allow their application to a variety of processes occurring over a wide spectrum of natural conditions. In this respect, both major and associated minor gases have been proven useful: indeed, the trace gases have been particularly important given their role as sensitive geochemical tracers. Examples where gas geochemistry places key constraints on geochemical processes include the degassing history of the solid Earth to form the atmosphere and oceans, the origin and migration characteristics of hydrocarbon deposits, the scale of climate variability, the P–T characteristics of geothermal reservoirs, and the dynamics of the earthquake cycle and volcanic activity, to name but a few. This volume continues this rich tradition with an eclectic selection of papers aimed at exploring and exploiting gas geochemistry over a myriad set of research themes.

Oxalate secretion by ectomycorrhizal Paxillus involutus is mineral-specific and controls calcium weathering from minerals

PubMed Central

Schmalenberger, A.; Duran, A. L.; Bray, A. W.; Bridge, J.; Bonneville, S.; Benning, L. G.; Romero-Gonzalez, M. E.; Leake, J. R.; Banwart, S. A.

2015-01-01

Trees and their associated rhizosphere organisms play a major role in mineral weathering driving calcium fluxes from the continents to the oceans that ultimately control long-term atmospheric CO2 and climate through the geochemical carbon cycle. Photosynthate allocation to tree roots and their mycorrhizal fungi is hypothesized to fuel the active secretion of protons and organic chelators that enhance calcium dissolution at fungal-mineral interfaces. This was tested using 14CO2 supplied to shoots of Pinus sylvestris ectomycorrhizal with the widespread fungus Paxillus involutus in monoxenic microcosms, revealing preferential allocation by the fungus of plant photoassimilate to weather grains of limestone and silicates each with a combined calcium and magnesium content of over 10 wt.%. Hyphae had acidic surfaces and linear accumulation of weathered calcium with secreted oxalate, increasing significantly in sequence: quartz, granite < basalt, olivine, limestone < gabbro. These findings confirmed the role of mineral-specific oxalate exudation in ectomycorrhizal weathering to dissolve calcium bearing minerals, thus contributing to the geochemical carbon cycle. PMID:26197714

Oxalate secretion by ectomycorrhizal Paxillus involutus is mineral-specific and controls calcium weathering from minerals

NASA Astrophysics Data System (ADS)

Schmalenberger, A.; Duran, A. L.; Bray, A. W.; Bridge, J.; Bonneville, S.; Benning, L. G.; Romero-Gonzalez, M. E.; Leake, J. R.; Banwart, S. A.

2015-07-01

Trees and their associated rhizosphere organisms play a major role in mineral weathering driving calcium fluxes from the continents to the oceans that ultimately control long-term atmospheric CO2 and climate through the geochemical carbon cycle. Photosynthate allocation to tree roots and their mycorrhizal fungi is hypothesized to fuel the active secretion of protons and organic chelators that enhance calcium dissolution at fungal-mineral interfaces. This was tested using 14CO2 supplied to shoots of Pinus sylvestris ectomycorrhizal with the widespread fungus Paxillus involutus in monoxenic microcosms, revealing preferential allocation by the fungus of plant photoassimilate to weather grains of limestone and silicates each with a combined calcium and magnesium content of over 10 wt.%. Hyphae had acidic surfaces and linear accumulation of weathered calcium with secreted oxalate, increasing significantly in sequence: quartz, granite < basalt, olivine, limestone < gabbro. These findings confirmed the role of mineral-specific oxalate exudation in ectomycorrhizal weathering to dissolve calcium bearing minerals, thus contributing to the geochemical carbon cycle.

Geochemical modeling of leaching of Ca, Mg, Al, and Pb from cementitious waste forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martens, E., E-mail: evelien.martens@csiro.a; Jacques, D.; Van Gerven, T.

2010-08-15

Results from extraction tests on cement-waste samples were simulated with a thermodynamic equilibrium model using a consistent database, to which lead data were added. Subsequent diffusion tests were modeled by means of a 3D diffusive transport model combined with the geochemical model derived from the extraction tests. Modeling results of the leached major element concentrations for both uncarbonated and (partially) carbonated samples agreed well with the extraction test using the set of pure minerals and solid solutions present in the database. The observed decrease in Ca leaching with increasing carbonation level was qualitatively predicted. Simulations also revealed that Pb leachingmore » is not controlled by dissolution/precipitation only. The addition of the calcite-cerrusite solid solution and adsorption reactions on amorphous Fe- and Al-oxides improved the predictions and are considered to control the Pb leaching during the extractions tests. The dynamic diffusive leaching tests were appropriately modeled for Na, K, Ca and Pb.« less

Trace metals in upland headwater lakes in Ireland.

PubMed

Burton, Andrew; Aherne, Julian; Hassan, Nouri

2013-10-01

Trace elements (n = 23) in Irish headwater lakes (n = 126) were investigated to determine their ambient concentrations, fractionation (total, dissolved, and non-labile), and geochemical controls. Lakes were generally located in remote upland, acid-sensitive regions along the coastal margins of the country. Total trace metal concentrations were low, within the range of natural pristine surface waters; however, some lakes (~20 %) had inorganic labile aluminum and manganese at levels potentially harmful to aquatic organisms. Redundancy analysis indicated that geochemical weathering was the dominant controlling factor for total metals, compared with acidity for dissolved metals. In addition, many metals were positively correlated with dissolved organic carbon indicating their affinity (or complexation) with humic substances (e.g., aluminum, iron, mercury, lead). However, a number of trace metals (e.g., aluminum, mercury, zinc) were correlated with anthropogenic acidic deposition (i.e., non-marine sulfate), suggesting atmospheric sources or elevated leaching owing to acidic deposition. As transboundary air pollution continues to decline, significant changes in the cycling of trace metals is anticipated.

Groundwater contaminant science activities of the U.S. Geological Survey in New England

USGS Publications Warehouse

Weiskel, Peter K.

2016-03-23

Aquifers in New England provide water for human needs and natural ecosystems. In some areas, however, aquifers have been degraded by contaminants from geologic and human sources. In recent decades, the U.S. Geological Survey has been a leader in describing contaminant occurrence in the bedrock and surficial aquifers of New England. In cooperation with Federal, State, and local agencies, the U.S. Geological Survey has also studied the vulnerability of groundwater to contaminants, the factors affecting the geographic distribution of contaminants, and the geochemical processes controlling contaminant transport and fate. This fact sheet describes some of the major science needs in the region related to groundwater contaminants and highlights recent U.S. Geological Survey studies that provide a foundation for future investigations.

Soil microbial structure and function post-volcanic eruption on Kasatochi Island and regional controls on microbial heterogeneity

NASA Astrophysics Data System (ADS)

Zeglin, L. H.; Rainey, F.; Wang, B.; Waythomas, C.; Talbot, S. L.

2013-12-01

Microorganisms are abundant and diverse in soil and their integrated activity drives nutrient cycling on the ecosystem scale. Organic matter (OM) inputs from plant production support microbial heterotrophic life, and soil geochemistry constrains microbial activity and diversity. As vegetation and soil develops over time, these factors change, modifying the controls on microbial heterogeneity. Following a volcanic eruption, ash deposition creates new surfaces where both organismal growth and weathering processes are effectively reset. The trajectory of microbial community development following this disturbance depends on both organic matter accumulation and geochemical constraints. Also, dispersal of microbial cells to the sterile ash surface may determine microbial community succession. The Aleutian Islands (Alaska, USA) are a dynamic volcanic region, with active and dormant volcanoes distributed across the volcanic arc. One of these volcanoes, Kasatochi, erupted violently in August 2008, burying a small lush island in pryoclastic flows and fine ash. Since, plants and birds are beginning to re-establish on developing surfaces, including legacy soils exposed by rapid erosion of pyroclastic deposits, suggesting that recovery of microbial life is also proceeding. However, soil microbial diversity and function has not been examined on Kasatochi Island or across the greater Aleutian region. The project goal is to address these questions: How is soil microbial community structure and function developing following the Kasatochi eruption? What is the relative importance of dispersal, soil OM and geochemistry to microbial community heterogeneity across the Aleutians? Surface mineral soil (20-cm depth) samples were collected from Kasatochi Island in summer 2013, five years after the 2008 eruption, and from eight additional Aleutian islands. On Kasatochi, pryoclastic deposits, exposed legacy soils supporting regrowth of remnant dune wild-rye (Leymus mollis) and mesic meadow plant communities, and soils impacted by recovering seabird rookeries were sampled. On the other islands, soils supporting both Leymus and mesic meadow communities (representative of dominant vegetation types on Kasatochi pre-eruption) were sampled. For each soil category and island combination, three transects of soil cores at 10-cm, 50-cm, 1-m, 5-m and 10-m distance were collected; with distances between sites and islands included (up to >700 km), the range of geographic distance examined covers over 7 orders of magnitude. For all samples, data on fundamental geochemical and OM factors, bacterial and fungal biomass, activity and diversity (via QPCR, extracellular enzyme potential assays and T-RFLP) are being collected. Covariance analysis is being used to evaluate the scale of maximum spatial heterogeneity in microbial structure and function, and ordination and matrix correlation analyses are being used to identify the key environmental covariates with heterogeneity. We hypothesize that heterogeneity at small (cm) scales will reflect predominant geochemical controls, at medium (m) scales will reflect predominant OM (vegetation) controls and at large (km) scales will reflect dispersal-related controls on microbial community structure and function.

Ca cycling and isotopic fluxes in forested ecosystems in Hawaii

USGS Publications Warehouse

Wiegand, B.A.; Chadwick, O.A.; Vitousek, P.M.; Wooden, J.L.

2005-01-01

Biogeochemical processes fractionate Ca isotopes in plants and soils along a 4 million year developmental sequence in the Hawaiian Islands. We observed that plants preferentially take up 40Ca relative to 44Ca, and that biological fractionation and changes in the relative contributions from volcanic and marine sources produce a significant increase in 44Ca in soil exchangeable pools. Our results imply moderate fluxes enriched in 44Ca from strongly nutrient-depleted old soils, in contrast with high 40Ca fluxes in young and little weathered environments. In addition, biological fractionation controls divergent geochemical pathways of Ca and Sr in the plant-soil system. While Ca depletes progressively with increasing soil age, Sr/Ca ratios increase systematically. Sr isotope ratios provide a valuable tracer for provenance studies of alkaline earth elements in forested ecosystems, but its usefulness is limited when deciphering biogeochemical processes involved in the terrestrial Ca cycle. Ca isotopes in combination with Sr/ Ca ratios reveal more complex processes involved in the biogeochemistry of Ca and Sr. Copyright 2005 by the American Geophysical Union.

Data management for JGOFS: Theory and design

NASA Technical Reports Server (NTRS)

Flierl, Glenn R.; Bishop, James K. B.; Glover, David M.; Paranjpe, Satish

1992-01-01

The Joint Global Ocean Flux Study (JGOFS), currently being organized under the auspices of the Scientific Committee for Ocean Research (SCOR), is intended to be a decade long internationally coordinated program. The main goal of JGOFS is to determine and understand on a global scale the processes controlling the time-varying fluxes of carbon and associated biogenic elements in the ocean and to evaluate the related exchanges with the atmosphere, sea floor and continental boundaries. 'A long-term goal of JGOFS will be to establish strategies for observing, on long time scales, changes in ocean biogeochemical cycles in relation to climate change'. Participation from a large number of U.S. and foreign institutions is expected. JGOFS investigators have begun a set of time-series measurements and global surveys of a wide variety of biological, chemical and physical quantities, detailed process-oriented studies, satellite observations of ocean color and wind stress and modeling of the bio-geochemical processes. These experiments will generate data in amounts unprecedented in the biological and chemical communities; rapid and effortless exchange of these data will be important to the success of JGOFS.

Mineralogical controls on aluminum and magnesium in uranium mill tailings: Key Lake, Saskatchewan, Canada.

PubMed

Gomez, M A; Hendry, M J; Koshinsky, J; Essilfie-Dughan, J; Paikaray, S; Chen, J

2013-07-16

The mineralogy and evolution of Al and Mg in U mill tailings are poorly understood. Elemental analyses (ICP-MS) of both solid and aqueous phases show that precipitation of large masses of secondary Al and Mg mineral phases occurs throughout the raffinate neutralization process (pH 1-11) at the Key Lake U mill, Saskatchewan, Canada. Data from a suite of analytical methods (ICP-MS, EMPA, laboratory- and synchrotron-based XRD, ATR-IR, Raman, TEM, EDX, ED) and equilibrium thermodynamic modeling showed that nanoparticle-sized, spongy, porous, Mg-Al hydrotalcite is the dominant mineralogical control on Al and Mg in the neutralized raffinate (pH ≥ 6.7). The presence of this secondary Mg-Al hydrotalcite in mineral samples of both fresh and 15-year-old tailings indicates that the Mg-Al hydrotalcite is geochemically stable, even after >16 years in the oxic tailings body. Data shows an association between the Mg-Al hydrotalcite and both As and Ni and point to this Mg-Al hydrotalcite exerting a mineralogical control on the solubility of these contaminants.

Analyzing legacy U.S. Geological Survey geochemical databases using GIS: applications for a national mineral resource assessment

USGS Publications Warehouse

Yager, Douglas B.; Hofstra, Albert H.; Granitto, Matthew

2012-01-01

This report emphasizes geographic information system analysis and the display of data stored in the legacy U.S. Geological Survey National Geochemical Database for use in mineral resource investigations. Geochemical analyses of soils, stream sediments, and rocks that are archived in the National Geochemical Database provide an extensive data source for investigating geochemical anomalies. A study area in the Egan Range of east-central Nevada was used to develop a geographic information system analysis methodology for two different geochemical datasets involving detailed (Bureau of Land Management Wilderness) and reconnaissance-scale (National Uranium Resource Evaluation) investigations. ArcGIS was used to analyze and thematically map geochemical information at point locations. Watershed-boundary datasets served as a geographic reference to relate potentially anomalous sample sites with hydrologic unit codes at varying scales. The National Hydrography Dataset was analyzed with Hydrography Event Management and ArcGIS Utility Network Analyst tools to delineate potential sediment-sample provenance along a stream network. These tools can be used to track potential upstream-sediment-contributing areas to a sample site. This methodology identifies geochemically anomalous sample sites, watersheds, and streams that could help focus mineral resource investigations in the field.

Determination of premining geochemical background and delineation of extent of sediment contamination in Blue Creek downstream from Midnite Mine, Stevens County, Washington

USGS Publications Warehouse

Church, Stan E.; Kirschner, Frederick E.; Choate, LaDonna M.; Lamothe, Paul J.; Budahn, James R.; Brown, Zoe Ann

2008-01-01

Geochemical and radionuclide studies of sediment recovered from eight core sites in the Blue Creek flood plain and Blue Creek delta downstream in Lake Roosevelt provided a stratigraphic geochemical record of the contamination from uranium mining at the Midnite Mine. Sediment recovered from cores in a wetland immediately downstream from the mine site as well as from sediment catchments in Blue Creek and from cores in the delta in Blue Creek cove provided sufficient data to determine the premining geochemical background for the Midnite Mine tributary drainage. These data provide a geochemical background that includes material eroded from the Midnite Mine site prior to mine development. Premining geochemical background for the Blue Creek basin has also been determined using stream-sediment samples from parts of the Blue Creek, Oyachen Creek, and Sand Creek drainage basins not immediately impacted by mining. Sediment geochemistry showed that premining uranium concentrations in the Midnite Mine tributary immediately downstream of the mine site were strongly elevated relative to the crustal abundance of uranium (2.3 ppm). Cesium-137 (137Cs) data and public records of production at the Midnite Mine site provided age control to document timelines in the sediment from the core immediately downstream from the mine site. Mining at the Midnite Mine site on the Spokane Indian Reservation between 1956 and 1981 resulted in production of more than 10 million pounds of U3O8. Contamination of the sediment by uranium during the mining period is documented from the Midnite Mine along a small tributary to the confluence of Blue Creek, in Blue Creek, and into the Blue Creek delta. During the period of active mining (1956?1981), enrichment of base metals in the sediment of Blue Creek delta was elevated by as much as 4 times the concentration of those same metals prior to mining. Cadmium concentrations were elevated by a factor of 10 and uranium by factors of 16 to 55 times premining geochemical background determined upstream of the mine site. Postmining metal concentrations in sediment are lower than during the mining period, but remain elevated relative to premining geochemical background. Furthermore, the sediment composition of surface sediment in the Blue Creek delta is contaminated. Base-metal contamination by arsenic, cadmium, lead, and zinc in sediment in the delta in Blue Creek cove is dominated by suspended sediment from the Coeur d?Alene mining district. Uranium contamination in surface sediment in the delta of Blue Creek cove extends at least 500 meters downstream from the mouth of Blue Creek as defined by the 1,290-ft elevation boundary between lands administered by the National Park Service and the Spokane Indian Tribe. Comparisons of the premining geochemical background to sediment sampled during the period the mine was in operation, and to the sediment data from the postmining period, are used to delineate the extent of contaminated sediment in Blue Creek cove along the thalweg of Blue Creek into Lake Roosevelt. The extent of contamination out into Lake Roosevelt by mining remains open.

Somewhere, Beyond the Sea: Advancing Geochemical Sensor Technologies for Biological and Abiotic Analyses on Ocean Worlds

NASA Astrophysics Data System (ADS)

Girguis, P. R.; Hoer, D.; Michel, A.; Wankel, S. D.; Baker, I.; Farr, N.

2018-05-01

Here we present our data from recent efforts aimed at examining the relationships among abiotic and biological processes in our ocean. These technologies may help us address that enduring question as to whether life exists on other celestial bodies.

Uranium transport in a crushed granodiorite: Experiments and reactive transport modeling

DOE PAGES

Dittrich, T. M.; Reimus, P. W.

2015-02-12

The primary objective of this study was to develop and demonstrate an experimental method to refine and better parameterize process models for reactive contaminant transport in aqueous subsurface environments and to reduce conservatism in such models without attempting to fully describe the geochemical system.

Laboratory Determination of Molybdenum Accumulation Rates as a Measure of Hypoxic Conditions

EPA Science Inventory

Redox sensitive metals, such as molybdenum (Mo), are enriched in reducing sediments due to authigenic fixation in anoxic interstitial waters of sediments. This study tested whether the process of fixation and accumulation of Mo in sediments could provide a geochemical indicator o...

GEOCHEMICAL CONTROLS ON THE PRODUCTION AND DISTRIBUTION OF METHYLMERCURY IN NEAR-SHORE MARINE SEDIMENTS (R827635)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Searching for an Acidic Aquifer in the Rio Tinto Basin: First Geobiology Results of MARTE Project

NASA Technical Reports Server (NTRS)

Fernandez-Remolar, D. C.; Prieto-Ballesteros, O.; Stoker, C.

2004-01-01

Among the conceivable modern habitats to be explored for searching life on Mars are those potentially developed underground. Subsurface habitats are currently environments that, under certain physicochemical circumstances, have high thermal and hydrochemical stability [1, 2]. In planets like Mars lacking an atmospheric shield, such systems are obviously protected against radiation, which strongly alters the structure of biological macromolecules. Low porosity but fractured aquifers currently emplaced inside ancient volcano/sedimentary and hydrothermal systems act as excellent habitats [3] due to its thermal and geochemical properties. In these aquifers the temperature is controlled by a thermal balance between conduction and advection processes, which are driven by the rock composition, geological structure, water turnover of aquifers and heat generation from geothermal processes or chemical reactions [4]. Moreover, microbial communities based on chemolithotrophy can obtain energy by the oxidation of metallic ores that are currently associated to these environments. Such a community core may sustain a trophic web composed of non-autotrophic forms like heterotrophic bacteria, fungi and protozoa.

Total Mercury, Methylmercury, Methylmercury Production Potential, and Ancillary Streambed-Sediment and Pore-Water Data for Selected Streams in Oregon, Wisconsin, and Florida, 2003-04

USGS Publications Warehouse

Marvin-DiPasquale, Mark C.; Lutz, Michelle A.; Krabbenhoft, David P.; Aiken, George R.; Orem, William H.; Hall, Britt D.; DeWild, John F.; Brigham, Mark E.

2008-01-01

Mercury contamination of aquatic ecosystems is an issue of national concern, affecting both wildlife and human health. Detailed information on mercury cycling and food-web bioaccumulation in stream settings and the factors that control these processes is currently limited. In response, the U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) conducted detailed studies from 2002 to 2006 on various media to enhance process-level understanding of mercury contamination, biogeochemical cycling, and trophic transfer. Eight streams were sampled for this study: two streams in Oregon, and three streams each in Wisconsin and Florida. Streambed-sediment and pore-water samples were collected between February 2003 and September 2004. This report summarizes the suite of geochemical and microbial constituents measured, the analytical methods used, and provides the raw data in electronic form for both bed-sediment and pore-water media associated with this study.

Geochemical controls on vanadium accumulation in fossil fuels

USGS Publications Warehouse

Breit, G.N.; Wanty, R.B.

1989-01-01

High vanadium contents in petroleum and other fossil fuels have been attributed to organic-matter type, organisms, volcanic emanations, diffusion of sea water, and epigenetic enrichment. However, these factors are inadequate to account for the high abundance of vanadium in some fossil fuels and the paucity in others. By examining vanadium deposits in sedimentary rocks with sparse organic matter, constraints are placed on processes controlling vanadium accumulation in organic-rich sediments. Vanadium, as vanadate (V(V)), entered some depositional basins in oxidizing waters from dry, subaerial environments. Upon contact with organic matter in anoxic waters, V(V) is reduced to vanadyl (V(IV)), which can be removed from the water column by adsorption. H2S reduces V(IV) to V(III), which hydrolyzes and precipitates. The lack of V(III) in petroleum suggests that reduction of V(IV) to V(III) is inhibited by organic complexes. In the absence of strong complexing agents, V(III) forms and is incorporated in clay minerals.

Geochemical controls of vanadium accumulation in fossil fuels

USGS Publications Warehouse

Breit, G.N.; Wanty, R.B.

1989-01-01

High vanadium contents in petroleum and other fossil fuels have been attributed to organic-matter type, organisms, volcanic emanations, diffusion of sea water, and epigenetic enrichment. However, these factors are inadequate to account for the high abundance of vanadium in some fossil fuels and the paucity in others. By examining vanadium deposits in sedimentary rocks with sparse organic matter, constraints are placed on processes controlling vanadium accumulation in organic-rich sediments. Vanadium, as vanadate (V(V)), entered some depositional basins in oxidizing waters from dry, subaerial environments. Upon contact with organic matter in anoxic waters, V(V) is reduced to vanadyl (V(IV)), which can be removed from the water column by adsorption. H2S reduces V(IV) to V(III), which hydrolyzes and precipitates. The lack of V(III) in petroleum suggests that reduction of V(IV) to V(III) is inhibited by organic complexes. In the absence of strong complexing agents, V(III) forms and is incorporated in clay minerals.

Integrating Hydrogeological, Microbiological, and Geochemical Data Using a Multi-Component Reactive Transport Model: Quantifying the Biogeochemical Evolution of Redox Zones in a Contaminated Aquifer

NASA Astrophysics Data System (ADS)

McGuire, J. T.; Phanikumar, M. S.; Long, D. T.; Hyndman, D. W.

2003-12-01

Hydrogeological, microbiological, and geochemical processes operating in a shallow sandy aquifer contaminated by waste fuels and chlorinated solvents were integrated using high-resolution mechanistic models. A 3-D, transient, reactive transport model was developed to quantitatively describe coupled processes via thermodynamic and kinetic arguments. The model was created by linking the hydrodynamic model MODFLOW (McDonald and Harbaugh, 1988), with advection, dispersion and user defined kinetic reactions based on RT3D 2.0, (Clement and Jones, 1998) and geochemical model PHREEQC (Parkhurst and Appelo, 1999). This model, BGTK3D 2.0, describes 1) the biodegradation of organic matter based on the influence of transport processes on microbial growth, 2) the complex suite of biogeochemical reactions operating in the aquifer, and 3) sharp chemical gradients. Some key features of this model are an ability to incorporate realistic solid phases to test hypotheses regarding mineral-water interactions, and an ability to accurately describe small-scale biogeochemical cycling (cm variability) observed in the field without oscillations or excessive numerical damping. BGTK3D was used to test hypotheses regarding the evolution of redox chemistry in a contaminated aquifer. The conceptual model that terminal electron accepting processes (TEAPs) distribute themselves sequentially into redox zones down flow path in aqueous systems is often used to interpret how and at what rates organic compounds will be degraded in the environment. Geochemical and microbiological data collected from a mixed contaminant plume at the former Wurtsmith AFB in Oscoda, Michigan suggests that under steady-state, mature plume conditions, traditional redox zonation may not be a realistic model of the distribution of TEAPs and therefore may not be the best model to evaluate the potential degradation of organic compounds. Based on these data, a conceptual model of TEAP evolution in contaminated systems was established. This model proposes that during initial plume development terminal electron acceptors O2, Fe3+, NO3, and SO4, are consumed sequentially based on thermodynamic arguments until a balance between organic degradation rates and source inputs and thus a stable plume length can be achieved. Once this "mature" state has been achieved, distinct redox zones can no longer be sustained and methanogenesis will dominate except in portions of the aquifer impacted by recharge water and diffusion of TEAs from all sides. Under these conditions, TEAPs will not proceed sequentially.

Geographic Size Variation and Intra-Tektite Geochemical Heterogeneity of Muong Nong Tektites: Insights for Cratering Process and Fall Location.

NASA Astrophysics Data System (ADS)

Schonwalder, D. A.; Sieh, K.; Herrin, J. S.; Wiwegwin, W.; Charusiri, P.; Singsomboun, K.; Sihavong, V.

2017-12-01

Australasian tektites cover 10% of Earth's surface and are the result of a 790 ka meteorite impact [1]. We have suggested that the search of the impact crater has long been mysterious because it lies buried beneath the volcanic field of the Bolaven Plateau (BP), southern Laos. [2]. Here we report our initial textural and geochemical work on 700 Muong Nong (MN) tektites collected in Laos and Thailand, including physical inspections and geochemical point-analyses of selected samples using a Field Emission Electron Probe Microanalyzer. We integrated our results with published data to identify any geographic patterns related to proposed crater site on the BP. Mung Nong tektite masses display a clear pattern in relation to BP. Within 50 km of the BP source, they do not exceed 10 gr. Mass then increases with radius to peak of 1 to 10 kg between 100 and 600 km, beyond which mass decreases steadily. We also see large geochemical heterogeneities within single tektites (e.g. 72.80±4.38 wt. % SiO2), and intra-sample compositions consisting with mixing of three principal source rocks on the BP, basalt-sourced laterites, basalt and sandstone. We infer that the geographical pattern in mass distribution of the MN tektites result from fragmentation of brittle, partially molten material during crater excavation and by debris interactions occurring in the ejecta blanket. The smaller and closest-to-crater tektites experienced greater interactions with crater walls and other ejecta during crater excavation, whereas the larger tektites that fell farther from the impact site, experienced lesser fragmentation because they had higher ejection trajectories that had less involvement in crater excavation. Intra-tektite compositional trends suggest the involvement of three protoliths, all of them found at the BP. 1. Schwarz et al. (2016) Geochem. Cosmo. Acta 178 2. Sieh et al. (2015) AGU Fall Mtg. T54A-04

Geochemical modeling of iron, sulfur, oxygen and carbon in a coastal plain aquifer

NASA Astrophysics Data System (ADS)

Brown, C. J.; Schoonen, M. A. A.; Candela, J. L.

2000-11-01

Fe(III) reduction in the Magothy aquifer of Long Island, NY, results in high dissolved-iron concentrations that degrade water quality. Geochemical modeling was used to constrain iron-related geochemical processes and redox zonation along a flow path. The observed increase in dissolved inorganic carbon is consistent with the oxidation of sedimentary organic matter coupled to the reduction of O 2 and SO 42- in the aerobic zone, and to the reduction of SO 42- in the anaerobic zone; estimated rates of CO 2 production through reduction of Fe(III) were relatively minor by comparison. The rates of CO 2 production calculated from dissolved inorganic carbon mass transfer (2.55×10 -4 to 48.6×10 -4 mmol l -1 yr-1) generally were comparable to the calculated rates of CO 2 production by the combined reduction of O 2, Fe(III) and SO 42- (1.31×10 -4 to 15×10 -4 mmol l -1 yr-1). The overall increase in SO 42- concentrations along the flow path, together with the results of mass-balance calculations, and variations in δ34S values along the flow path indicate that SO 42- loss through microbial reduction is exceeded by SO 42- gain through diffusion from sediments and through the oxidation of FeS 2. Geochemical and microbial data on cores indicate that Fe(III) oxyhydroxide coatings on sediment grains in local, organic carbon- and SO 42--rich zones have been depleted by microbial reduction and resulted in localized SO 42--reducing zones in which the formation of iron disulfides decreases dissolved iron concentrations. These localized zones of SO 42- reduction, which are important for assessing zones of low dissolved iron for water-supply development, could be overlooked by aquifer studies that rely only on groundwater data from well-water samples for geochemical modeling.

Hydrogeochemical processes controlling changes in fluoride ion concentration within alluvial and hard rock aquifers in a part of a semi-arid region of Northern India

NASA Astrophysics Data System (ADS)

Singh, Priyadarshini; Ashthana, Harshita; Rena, Vikas; Kumar, Pardeep; Mukherjee, Saumitra

2017-04-01

Geochemical signatures from alluvial and hard rock aquifers in a part of Northern India elucidate the chemical processes controlling fluctuations in fluoride ion concentration linked to changes in major ion groundwater chemistry. Majority of samples from the hard rock and the alluvial aquifers for pre-monsoon show both carbonate and silicate weathering, ion exchange, evaporation and rock water interaction as the processes controlling major ion chemistry whereas for post monsoon samples, contribution of silicate weathering and ion exchange process were observed. Evaporative processes causing the increase in Na+ ion concentration in premonsoon enhance the reverse ion exchange processes causing increase in Ca2+ ions which impedes fluorite mineral dissolution in the premonsoon groundwater samples within the study area. Alternately, it is observed that the removal of Ca2+ ion from solution plays a key role in increase in fluorite mineral dissolution despite its saturation in groundwater in the postmonsoon samples. Also, ion exchange process on clay surfaces is more pronounced in the postmonsoon samples leading to the uptake of Ca2+ ion upon release of Na+ and K+ ion in solution. Ca2+ ion concentration is inversely correlated with F- ion concentration in both the aquifers in the postmonsoon season validating the role of calcite precipitation as a major reason for the fluoride ion increase. Moreover, increase in silicate weathering in the postmonsoon samples leads to increase in clay particles acting as suitable sites for ion exchange enhancing Ca2+ removal from groundwater. Cationic dominance of Na+ ion in the post monsoon samples also validates the occurrence of this process. Collectively, these processes set the ideal conditions for increase in the fluoride ion concentration particularly in the alluvium aquifer waters in the postmonsoon season Keywords: geochemistry, ion-exchange, rock-water interaction, mineral dissolution, weathering.

Regular patterns of Cs-137 distribution in natural conjugated elementary landscapes as a result of a balanced surface and depth water migration

NASA Astrophysics Data System (ADS)

Korobova, Elena; Romanov, Sergey

2016-04-01

Distribution of artificial radionuclides in the environment has long been used successfully for revealing migration pathways of their stable analogues. Migration of water in natural conjugated elementary landscapes characterizing the system of top-slope-resulting depression, has a specific structure and the radionuclide tracer is inevitably reflecting it by specific sorption and exchange processes. Other important issues are the concentration levels and the difference in characteristic time of chemical element dispersion. Modern biosphere has acquired its sustainable structure within a long period of time and is formed by basic macroelements allowing the water soluble portion of elements functioning as activators of chemical exchange. Water migration is controlled by gravitation, climate and relief while fixation depends upon the parameters of surfaces and chemical composition. The resulting structure depends on specificity and duration of the process. The long-term redistribution of chemical elements in terrestrial environment has led to a distinct geochemical structure of conjugated landscapes with a specific geometry of redistribution and accumulation of chemical elements. Migration of the newly born anthropogenic radionuclides followed natural pathways in biosphere. The initial deposition of the Chernobyl's radionuclides within the elementary landscape-geochemical system was even by condition of aerial deposition. But further exchange process is controlled by the strength of fixation and migration ability of the carriers. Therefore patterns of spatial distribution of artificial radionuclides in natural landscapes are considerably different as compared to those of the long-term forming the basic structure of chemical fields in biosphere. Our monitoring of Cs-137 radial and lateral distribution in the test plots characterizing natural undisturbed conjugated elementary landscapes performed in the period from 2005 until now has revealed a stable and specifically polycentric structure of radiocesium distribution believed to reflect the character of radial and lateral water body migration and a high sensitivity of water distribution to surface parameters. This leads to an unusual wavy type of Cs-137 distribution down, along and across all the slopes examined for surface Cs-137 activity at every measured point. The finding is believed to have an important practical outcome allowing much more detailed evaluation of micronutrients distribution and optimization of their application.